WorldWideScience

Sample records for nuclear spin determination

  1. Dynamic nuclear spin polarization

    Energy Technology Data Exchange (ETDEWEB)

    Stuhrmann, H.B. [GKSS-Forschungszentrum Geesthacht GmbH (Germany)

    1996-11-01

    Polarized neutron scattering from dynamic polarized targets has been applied to various hydrogenous materials at different laboratories. In situ structures of macromolecular components have been determined by nuclear spin contrast variation with an unprecedented precision. The experiments of selective nuclear spin depolarisation not only opened a new dimension to structural studies but also revealed phenomena related to propagation of nuclear spin polarization and the interplay of nuclear polarisation with the electronic spin system. The observation of electron spin label dependent nuclear spin polarisation domains by NMR and polarized neutron scattering opens a way to generalize the method of nuclear spin contrast variation and most importantly it avoids precontrasting by specific deuteration. It also likely might tell us more about the mechanism of dynamic nuclear spin polarisation. (author) 4 figs., refs.

  2. The determination of the in situ structure by nuclear spin contrast variation

    International Nuclear Information System (INIS)

    Stuhrmann, H.B.; Nierhaus, K.H.

    1994-01-01

    Polarized neutron scattering from polarized nuclear spins in hydrogenous substances opens a new way of contrast variation. The enhanced contrast due to proton spin polarization was used for the in situ structure determination of tRNA of the functional complex of the E.coli ribosome

  3. Determination of nuclear spins of short-lived isotopes by laser induced fluorescence

    International Nuclear Information System (INIS)

    Buchinger, F.; Dabkiewicz, P.; Kremmling, H.; Kuehl, T.; Mueller, A.C.; Schuessler, H.A.

    1980-01-01

    The spins of several nuclear ground and isomeric states have been measured for a number of mercury isotopes. The fluorescent light from the 6s6p 3 P 1 state is observed at 2537 Angstroem after excitation with the frequency doubled output of a pulsed dye laser. Four different laser induced fluorescence techniques were tested for their applicability: double resonance, Hanle effect, time delayed integral Hanle beats, and time resolved quantum beats. The sensitivity and selectivity of these models are compared with emphasis on the determination of spins of nuclei far from beta-stability, where short half lives and low production yields restrict the number of available atoms. The experiments were carried out on-line with the ISOLDE isotope separator at CERN at densities as low as 10 6 atoms/cm 3 . Results for the very neutron deficient high spin mercury isomers with half lives of several seconds, but also for the ground states of the abundant low spin stable mercury isotopes, are given as examples. The test measurements determined the nuclear spins of the odd sup(185m-191m)Hg isomers to be I = 13/2. (orig.)

  4. Nuclear spins in nanostructures

    International Nuclear Information System (INIS)

    Coish, W.A.; Baugh, J.

    2009-01-01

    We review recent theoretical and experimental advances toward understanding the effects of nuclear spins in confined nanostructures. These systems, which include quantum dots, defect centers, and molecular magnets, are particularly interesting for their importance in quantum information processing devices, which aim to coherently manipulate single electron spins with high precision. On one hand, interactions between confined electron spins and a nuclear-spin environment provide a decoherence source for the electron, and on the other, a strong effective magnetic field that can be used to execute local coherent rotations. A great deal of effort has been directed toward understanding the details of the relevant decoherence processes and to find new methods to manipulate the coupled electron-nuclear system. A sequence of spectacular new results have provided understanding of spin-bath decoherence, nuclear spin diffusion, and preparation of the nuclear state through dynamic polarization and more general manipulation of the nuclear-spin density matrix through ''state narrowing.'' These results demonstrate the richness of this physical system and promise many new mysteries for the future. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

  5. Nuclear spin pumping and electron spin susceptibilities

    NARCIS (Netherlands)

    Danon, J.; Nazarov, Y.V.

    2011-01-01

    In this work we present a new formalism to evaluate the nuclear spin dynamics driven by hyperfine interaction with nonequilibrium electron spins. To describe the dynamics up to second order in the hyperfine coupling it suffices to evaluate the susceptibility and fluctuations of the electron spin.

  6. Nuclear spin-off

    International Nuclear Information System (INIS)

    1981-11-01

    This booklet gives examples of 'nuclear spin off', from research programmes carried out for the UKAEA, under the following headings; non destructive testing; tribology; environmental protection; flow measurement; material sciences; mechanical engineering; marine services; biochemical technology; electronic instrumentation. (U.K.)

  7. Determination of spins and radioactive widths of tellurium nuclear levels with capturre gamma rays

    International Nuclear Information System (INIS)

    Bianchini, F.G.

    1973-01-01

    Spins and levels widths of the tellurium, mainly 128 Te and 130 Te, were determinated by gamma spectroscopy. Measurements of inelastic and elastic scattering, angular distribution and scattering temperature dependence, were still made. Energy levels of this isotopes, were also determinated [pt

  8. Nuclear spin polarization of targets

    International Nuclear Information System (INIS)

    Happer, W.

    1990-01-01

    Lasers can be used to produce milligrams to grams of noble gas nuclei with spin polarizations in excess of 50%. These quantities are sufficient to be very useful targets in nuclear physics experiments. Alkali-metal atoms are used to capture the angular momentum of circularly polarized laser photons, and the alkali-metal atoms transfer their angular momentum to noble gas atoms in binary or three-body collisions. Non-radiative collisions between the excited alkali atoms and molecular quenching gases are essential to avoid radiation trapping. The spin exchange can involve gas-phase van der Waals molecules, consisting of a noble gas atom and an alkali metal atom. Surface chemistry is also of great importance in determining the wall-induced relaxation rates of the noble gases

  9. Nuclear Spins in Quantum Dots

    NARCIS (Netherlands)

    Erlingsson, S.I.

    2003-01-01

    The main theme of this thesis is the hyperfine interaction between the many lattice nuclear spins and electron spins localized in GaAs quantum dots. This interaction is an intrinsic property of the material. Despite the fact that this interaction is rather weak, it can, as shown in this thesis,

  10. Electron spin and nuclear spin manipulation in semiconductor nanosystems

    International Nuclear Information System (INIS)

    Hirayama, Yoshiro; Yusa, Go; Sasaki, Satoshi

    2006-01-01

    Manipulations of electron spin and nuclear spin have been studied in AlGaAs/GaAs semiconductor nanosystems. Non-local manipulation of electron spins has been realized by using the correlation effect between localized and mobile electron spins in a quantum dot- quantum wire coupled system. Interaction between electron and nuclear spins was exploited to achieve a coherent control of nuclear spins in a semiconductor point contact device. Using this device, we have demonstrated a fully coherent manipulation of any two states among the four spin levels of Ga and As nuclei. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  11. High-spin nuclear traps

    International Nuclear Information System (INIS)

    Walker, P.; Dracoulis, G.

    1994-01-01

    The reaction pathways in stars, where all the heavy elements in the Universe were formed, are inextricably linked with isomers that live long enough to capture a neutron or proton before they decay. These isomers usually have excitation energies below 0.1 MeV. It is also possible to find highly excited isomers, with several MeV of excitation energy, that are trapped because of their large angular momentum (or spin). But attempts to understand the long-lived highly excited isomers, sometimes known as ''spin traps'', have been hampered by the difficulty of producing this exotic form of nuclear matter. Now, a new generation of radioactive ion beams promises a revolution in the study of high-spin nuclear traps. (author)

  12. High-spin nuclear spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Diamond, R.M.

    1986-07-01

    High-spin spectroscopy is the study of the changes in nuclear structure, properties, and behavior with increasing angular momentum. It involves the complex interplay between collective and single-particle motion, between shape and deformation changes, particle alignments, and changes in the pairing correlations. A review of progress in theory, experimentation, and instrumentation in this field is given. (DWL)

  13. Nuclear Spin Relaxation

    Indian Academy of Sciences (India)

    IAS Admin

    In the context of nuclear magnetic resonance (NMR), the term relaxation indicates the process by which the magnetic atomic nuclei reach thermal equilibrium with the chaotic molecular environment. In NMR, this process can be very slow, requiring between a fraction of a second to many minutes, depending on the.

  14. Experimental energy-dependent nuclear spin distributions

    International Nuclear Information System (INIS)

    Egidy, T. von; Bucurescu, D.

    2009-01-01

    A new method is proposed to determine the energy-dependent spin distribution in experimental nuclear-level schemes. This method compares various experimental and calculated moments in the energy-spin plane to obtain the spin-cutoff parameter σ as a function of mass A and excitation energy using a total of 7202 levels with spin assignment in 227 nuclei between F and Cf. A simple formula, σ 2 =0.391 A 0.675 (E-0.5Pa ' ) 0.312 , is proposed up to about 10 MeV that is in very good agreement with experimental σ values and is applied to improve the systematics of level-density parameters.

  15. QED approach to the nuclear spin-spin coupling tensor

    International Nuclear Information System (INIS)

    Romero, Rodolfo H.; Aucar, Gustavo A.

    2002-01-01

    A quantum electrodynamical approach for the calculation of the nuclear spin-spin coupling tensor of nuclear-magnetic-resonance spectroscopy is given. Quantization of radiation fields within the molecule is considered and expressions for the magnetic field in the neighborhood of a nucleus are calculated. Using a generalization of time-dependent response theory, an effective spin-spin interaction is obtained from the coupling of nuclear magnetic moments to a virtual quantized magnetic field. The energy-dependent operators obtained reduce to usual classical-field expressions at suitable limits

  16. Nuclear Spin-Spin Coupling in HD, HT, and DT

    Science.gov (United States)

    Puchalski, Mariusz; Komasa, Jacek; Pachucki, Krzysztof

    2018-02-01

    The interaction between nuclear spins in a molecule is exceptionally sensitive to the physics beyond the standard model. However, all present calculations of the nuclear spin-spin coupling constant J are burdened by computational difficulties, which hinders the comparison to experimental results. Here, we present a variational approach and calculate the constant J in the hydrogen molecule with the controlled numerical precision, using the adiabatic approximation. The apparent discrepancy with experimental result is removed by an analysis of nonadiabatic effects based on the experimental values of the J constant for HD, HT, and DT molecules. This study significantly improves the reliability of the NMR theory for searching new physics in the spin-spin coupling.

  17. Controlling a nuclear spin in a nanodiamond

    Science.gov (United States)

    Knowles, Helena S.; Kara, Dhiren M.; Atatüre, Mete

    2017-09-01

    The sensing capability of a single optically bright electronic spin in diamond can be enhanced by making use of proximal dark nuclei as ancillary spins. Such systems, so far realized only in bulk diamond, can provide orders of magnitude higher sensitivity and spectral resolution in the case of magnetic sensing, as well as improved readout fidelity and state storage time in quantum information schemes. Nanodiamonds offer opportunities for scanning and embedded nanoscale probes, yet electronic-nuclear spin complexes have so far remained inaccessible. Here, we demonstrate coherent control of a 13C nuclear spin located 4 Å from a nitrogen-vacancy center in a nanodiamond and show coherent exchange between the two components of this hybrid spin system. We extract a free precession time T2* of 26 μ s for the nuclear spin, which exceeds the bare-electron free-precession time in nanodiamond by two orders of magnitude.

  18. Spin-off technologies developed through nuclear activities

    International Nuclear Information System (INIS)

    1993-01-01

    Given the changing role of government research establishments and the interest in maximizing return on capital and intellectual investment, determining the best way to apply or ''spin-off'' technologies from the nuclear field into other industrial and commercial sectors is of increasing concern. This study by the OECD Nuclear Energy Agency draws on expertise from numerous countries to determine what the spin-offs are, where they come from, and how they can best be fostered. It looks both at the results and process of spin-offs, and helps decision-makers in government and project leaders and managers in industry to maximize their benefits. (author)

  19. India's nuclear spin-off

    International Nuclear Information System (INIS)

    Kaul, Ravi.

    1974-01-01

    After examining world-wide reactions of the foreign governments and news media to the India's peaceful nuclear experiment (PNE) in the Rajasthan Desert on 18 May 1974, development of nuclear technology in India is assessed and its economic advantages are described. Implications of the Non-Proliferation Treaty are explained. Psychological impact of India's PNE on India's neighbours and superpowers and associated political problems in context of proliferation of nuclear weapons are discussed in detail. (M.G.B.)

  20. Detection and Control of Individual Nuclear Spins Using a Weakly Coupled Electron Spin

    NARCIS (Netherlands)

    Taminiau, T.H.; Wagenaar, J.J.T.; Van der Sar, T.; Jelezko, F.; Dobrovitski, V.V.; Hanson, R.

    2012-01-01

    We experimentally isolate, characterize, and coherently control up to six individual nuclear spins that are weakly coupled to an electron spin in diamond. Our method employs multipulse sequences on the electron spin that resonantly amplify the interaction with a selected nuclear spin and at the same

  1. Nuclear structure of Ra at high spin

    Indian Academy of Sciences (India)

    However, nuclear structure at high spin and excitation energies (∼ 6 MeV) would require a coupling of excited 1p–1h with 208Pb core. The coupling between single- particle orbitals and collective vibrations of core complicates the simple shell model picture. With increasing neutron number, Ra isotopes show an abrupt ...

  2. Quantum computing using nuclear spins

    International Nuclear Information System (INIS)

    Cejnar, P.

    2002-01-01

    In December 2001, a group of physicists at Stanford University and at the IBM research center in California announced the first experimental implementation of the Shor quantum factorization algorithm with 7 quantum bits. The nuclear magnetic resonance method applied appears to be a promising approach to the realization of quantum computers. Quantum computing, which is a very interesting field of application of the laws of the quantum world, is demonstrated on examples

  3. Nuclear spin relaxation of methane in solid xenon

    Science.gov (United States)

    Sugimoto, Takeru; Arakawa, Ichiro; Yamakawa, Koichiro

    2018-03-01

    Nuclear spin relaxation of methane in solid xenon has been studied by infrared spectroscopy. From the analysis of the temporal changes of the rovibrational peaks, the rates of the nuclear spin relaxation of I = 2 ← 1 correlated to the rotational relaxation of J = 0 ← 1 were obtained at temperatures of 5.1-11.5 K. On the basis of the temperature dependence of the relaxation rate, the activation energy of the indirect two-phonon process was determined to be 50 ± 6 K, which is in good agreement with the rotational transition energies of J = 2 ← 1 and J = 3 ← 1. Taking into account this result and the spin degeneracy, we argue that the lowest J = 3 level in which the I = 1 and I = 2 states are degenerate acts as the intermediate point of the indirect process.

  4. Spin determination of fission resonances

    International Nuclear Information System (INIS)

    Keyworth, G.A.

    1976-01-01

    The present status of available information on the channel quantum numbers for resonance fission and the most urgently needed additional experiments are examined. The role of spin in the 235 U + n system is emphasized. The discussion relies heavily on recent alignment measurements and polarization results

  5. Determination of the spin diffusion length in germanium by spin optical orientation and electrical spin injection

    Science.gov (United States)

    Rinaldi, C.; Bertoli, S.; Asa, M.; Baldrati, L.; Manzoni, C.; Marangoni, M.; Cerullo, G.; Bianchi, M.; Sordan, R.; Bertacco, R.; Cantoni, M.

    2016-10-01

    The measurement of the spin diffusion length and/or lifetime in semiconductors is a key issue for the realisation of spintronic devices, exploiting the spin degree of freedom of carriers for storing and manipulating information. In this paper, we address such parameters in germanium (0 0 1) at room temperature (RT) by three different measurement methods. Exploiting optical spin orientation in the semiconductor and spin filtering across an insulating MgO barrier, the dependence of the resistivity on the spin of photo-excited carriers in Fe/MgO/Ge spin photodiodes (spin-PDs) was electrically detected. A spin diffusion length of 0.9  ±  0.2 µm was obtained by fitting the photon energy dependence of the spin signal by a mathematical model. Electrical techniques, comprising non-local four-terminal and Hanle measurements performed on CoFeB/MgO/Ge lateral devices, led to spin diffusion lengths of 1.3  ±  0.2 µm and 1.3  ±  0.08 µm, respectively. Despite minor differences due to experimental details, the order of magnitude of the spin diffusion length is the same for the three techniques. Although standard electrical methods are the most employed in semiconductor spintronics for spin diffusion length measurements, here we demonstrate optical spin orientation as a viable alternative for the determination of the spin diffusion length in semiconductors allowing for optical spin orientation.

  6. Evolution of nuclear shapes at high spins

    International Nuclear Information System (INIS)

    Johnson, N.R.

    1985-01-01

    The dynamic electric quadrupole (E2) moments are a direct reflection of the collective aspects of the nuclear wave functions. For this, Doppler-shift lifetime measurements have been done utilizing primarily the recoil-distance technique. The nuclei with neutron number N approx. 90 possess many interesting properties. These nuclei have very shallow minima in their potential energy surfaces, and thus, are very susceptible to deformation driving influences. It is the evolution of nuclear shapes as a function of spin or rotational frequency for these nuclei that has commanded much interest in the lifetime measurements discussed here. There is growing evidence that many deformed nuclei which have prolate shapes in their ground states conform to triaxial or oblate shapes at higher spins. Since the E2 matrix elements along the yrast line are sensitive indicators of deformation changes, measurements of lifetimes of these states to provide the matrix elements has become the major avenue for tracing the evolving shape of a nucleus at high spin. Of the several nuclei we have studied with N approx. 90, those to be discussed here are /sup 160,161/Yb and 158 Er. In addition, the preliminary, but interesting and surprising results from our recent investigation of the N = 98 nucleus, 172 W are briefly discussed. 14 refs., 5 figs

  7. Nuclear spin polarized H and D by means of spin-exchange optical pumping

    Science.gov (United States)

    Stenger, Jörn; Grosshauser, Carsten; Kilian, Wolfgang; Nagengast, Wolfgang; Ranzenberger, Bernd; Rith, Klaus; Schmidt, Frank

    1998-01-01

    Optically pumped spin-exchange sources for polarized hydrogen and deuterium atoms have been demonstrated to yield high atomic flow and high electron spin polarization. For maximum nuclear polarization the source has to be operated in spin temperature equilibrium, which has already been demonstrated for hydrogen. In spin temperature equilibrium the nuclear spin polarization PI equals the electron spin polarization PS for hydrogen and is even larger than PS for deuterium. We discuss the general properties of spin temperature equilibrium for a sample of deuterium atoms. One result are the equations PI=4PS/(3+PS2) and Pzz=PSṡPI, where Pzz is the nuclear tensor polarization. Furthermore we demonstrate that the deuterium atoms from our source are in spin temperature equilibrium within the experimental accuracy.

  8. Robust techniques for polarization and detection of nuclear spin ensembles

    Science.gov (United States)

    Scheuer, Jochen; Schwartz, Ilai; Müller, Samuel; Chen, Qiong; Dhand, Ish; Plenio, Martin B.; Naydenov, Boris; Jelezko, Fedor

    2017-11-01

    Highly sensitive nuclear spin detection is crucial in many scientific areas including nuclear magnetic resonance spectroscopy, magnetic resonance imaging (MRI), and quantum computing. The tiny thermal nuclear spin polarization represents a major obstacle towards this goal which may be overcome by dynamic nuclear spin polarization (DNP) methods. The latter often rely on the transfer of the thermally polarized electron spins to nearby nuclear spins, which is limited by the Boltzmann distribution of the former. Here we utilize microwave dressed states to transfer the high (>92 % ) nonequilibrium electron spin polarization of a single nitrogen-vacancy center (NV) induced by short laser pulses to the surrounding 13C carbon nuclear spins. The NV is repeatedly repolarized optically, thus providing an effectively infinite polarization reservoir. A saturation of the polarization of the nearby nuclear spins is achieved, which is confirmed by the decay of the polarization transfer signal and shows an excellent agreement with theoretical simulations. Hereby we introduce the polarization readout by polarization inversion method as a quantitative magnetization measure of the nuclear spin bath, which allows us to observe by ensemble averaging macroscopically hidden polarization dynamics like Landau-Zener-Stückelberg oscillations. Moreover, we show that using the integrated solid effect both for single- and double-quantum transitions nuclear spin polarization can be achieved even when the static magnetic field is not aligned along the NV's crystal axis. This opens a path for the application of our DNP technique to spins in and outside of nanodiamonds, enabling their application as MRI tracers. Furthermore, the methods reported here can be applied to other solid state systems where a central electron spin is coupled to a nuclear spin bath, e.g., phosphor donors in silicon and color centers in silicon carbide.

  9. Inelastic electron tunneling spectroscopy of a single nuclear spin.

    Science.gov (United States)

    Delgado, F; Fernández-Rossier, J

    2011-08-12

    Detection of a single nuclear spin constitutes an outstanding problem in different fields of physics such as quantum computing or magnetic imaging. Here we show that the energy levels of a single nuclear spin can be measured by means of inelastic electron tunneling spectroscopy (IETS). We consider two different systems, a magnetic adatom probed with scanning tunneling microscopy and a single Bi dopant in a silicon nanotransistor. We find that the hyperfine coupling opens new transport channels which can be resolved at experimentally accessible temperatures. Our simulations evince that IETS yields information about the occupations of the nuclear spin states, paving the way towards transport-detected single nuclear spin resonance.

  10. Exploring Localization in Nuclear Spin Chains

    Science.gov (United States)

    Wei, Ken Xuan; Ramanathan, Chandrasekhar; Cappellaro, Paola

    2018-02-01

    Characterizing out-of-equilibrium many-body dynamics is a complex but crucial task for quantum applications and understanding fundamental phenomena. A central question is the role of localization in quenching thermalization in many-body systems and whether such localization survives in the presence of interactions. Probing this question in real systems necessitates the development of an experimentally measurable metric that can distinguish between different types of localization. While it is known that the localized phase of interacting systems [many-body localization (MBL)] exhibits a long-time logarithmic growth in entanglement entropy that distinguishes it from the noninteracting case of Anderson localization (AL), entanglement entropy is difficult to measure experimentally. Here, we present a novel correlation metric, capable of distinguishing MBL from AL in high-temperature spin systems. We demonstrate the use of this metric to detect localization in a natural solid-state spin system using nuclear magnetic resonance (NMR). We engineer the natural Hamiltonian to controllably introduce disorder and interactions, and observe the emergence of localization. In particular, while our correlation metric saturates for AL, it slowly keeps increasing for MBL, demonstrating analogous features to entanglement entropy, as we show in simulations. Our results show that our NMR techniques, akin to measuring out-of-time correlations, are well suited for studying localization in spin systems.

  11. Optical pump - nuclear resonance probe experiments on spin crossover complexes

    Science.gov (United States)

    Sakshath, S.; Jenni, K.; Scherthan, L.; Würtz, P.; Herlitschke, M.; Sergeev, I.; Strohm, C.; Wille, H.-C.; Röhlsberger, R.; Wolny, J. A.; Schünemann, V.

    2017-11-01

    A novel sample environment enabling optical pump - nuclear resonance probe experiments has been installed at the beamline P01, Petra III, DESY Hamburg. This set-up has been used to investigate optically induced spin state changes of spin crossover (SCO) complexes by nuclear resonant scattering immediately after excitation by an optical laser pulse. Here, we report the technical details as well as first results of the experiments performed at 290 K and 80 K on the SCO complexes [Fe (NH2trz)3]Cl2 and [Fe(PM-BiA)2(NCS)2], respectively. The 57Fe-enriched SCO complexes were excited by a 531 nm laser with a pulse length indicate the presence of high spin (HS) states when the complexes are excited by laser pulses and a pure low spin (LS) state in the absence of any laser pulse. Furthermore, the dependence of the optically excited HS-fraction has been determined as a function of the average optical power.

  12. Two methods for nuclear spin determination in collinear laser spectroscopy: classical r.f. magnetic resonance and observation of the Larmor precession

    International Nuclear Information System (INIS)

    Bendali, N.; Duong, H.T.; Saint-Jalm, J.M.; Vialle, J.L.

    1984-01-01

    Measurement of nuclear spin in the collinear laser spectroscopy method has been investigated using a fast sodium atomic beam excited collinearly by a C.W. single mode dye laser beam. The atomic magnetic moments are first aligned by optical pumping process, then they interact with a static magnetic field H 0 . The magnetic alignment of the atomic system just at the exit of the magnetic field is monitored by the laser induced fluorescence. Upon varying the amplitude of H 0 , the fluorescence signal presents a fringed structure. This structure is due to the Larmor precession of the aligned magnetic moments around H 0 , and therefore it is a signature of the spin involved. The modulation patterns corresponding to different relative orientations of H 0 and light polarization direction, are fitted by an analytical formula. In a second step, a classical magnetic resonance experiment with a static magnetic field and a radiofrequency field has been performed. The monocinetic character of our fast atomic beam allowed us to observe, even at high r.f. power, resonances line shapes in agreement with the Majorana formula

  13. Fast Electrical Control of Single Electron Spins in Quantum Dots with Vanishing Influence from Nuclear Spins

    Science.gov (United States)

    Yoneda, J.; Otsuka, T.; Nakajima, T.; Takakura, T.; Obata, T.; Pioro-Ladrière, M.; Lu, H.; Palmstrøm, C. J.; Gossard, A. C.; Tarucha, S.

    2014-12-01

    We demonstrate fast universal electrical spin manipulation with inhomogeneous magnetic fields. With fast Rabi frequency up to 127 MHz, we leave the conventional regime of strong nuclear-spin influence and observe a spin-flip fidelity >96 % , a distinct chevron Rabi pattern in the spectral-time domain, and a spin resonance linewidth limited by the Rabi frequency, not by the dephasing rate. In addition, we establish fast z rotations up to 54 MHz by directly controlling the spin phase. Our findings will significantly facilitate tomography and error correction with electron spins in quantum dots.

  14. Spin squeezing of atomic ensembles via nuclear-electronic spin entanglement

    DEFF Research Database (Denmark)

    Fernholz, Thomas; Krauter, Hanna; Jensen, Kasper

    2008-01-01

    quantum limit for quantum memory experiments and applications in quantum metrology and is thus a complementary alternative to spin squeezing obtained via inter-atom entanglement. Squeezing of the collective spin is verified by quantum state tomography.......We demonstrate spin squeezing in a room temperature ensemble of 1012 Cesium atoms using their internal structure, where the necessary entanglement is created between nuclear and electronic spins of each individual atom. This state provides improvement in measurement sensitivity beyond the standard...

  15. Thermodynamics of Rh nuclear spins calculated by exact diagonalization

    DEFF Research Database (Denmark)

    Lefmann, K.; Ipsen, J.; Rasmussen, F.B.

    2000-01-01

    We have employed the method of exact diagonalization to obtain the full-energy spectrum of a cluster of 16 Rh nuclear spins, having dipolar and RK interactions between first and second nearest neighbours only. We have used this to calculate the nuclear spin entropy, and our results at both positi...

  16. Atomic-Scale Nuclear Spin Imaging Using Quantum-Assisted Sensors in Diamond

    Directory of Open Access Journals (Sweden)

    A. Ajoy

    2015-01-01

    Full Text Available Nuclear spin imaging at the atomic level is essential for the understanding of fundamental biological phenomena and for applications such as drug discovery. The advent of novel nanoscale sensors promises to achieve the long-standing goal of single-protein, high spatial-resolution structure determination under ambient conditions. In particular, quantum sensors based on the spin-dependent photoluminescence of nitrogen-vacancy (NV centers in diamond have recently been used to detect nanoscale ensembles of external nuclear spins. While NV sensitivity is approaching single-spin levels, extracting relevant information from a very complex structure is a further challenge since it requires not only the ability to sense the magnetic field of an isolated nuclear spin but also to achieve atomic-scale spatial resolution. Here, we propose a method that, by exploiting the coupling of the NV center to an intrinsic quantum memory associated with the nitrogen nuclear spin, can reach a tenfold improvement in spatial resolution, down to atomic scales. The spatial resolution enhancement is achieved through coherent control of the sensor spin, which creates a dynamic frequency filter selecting only a few nuclear spins at a time. We propose and analyze a protocol that would allow not only sensing individual spins in a complex biomolecule, but also unraveling couplings among them, thus elucidating local characteristics of the molecule structure.

  17. Optically induced dynamic nuclear spin polarisation in diamond

    Science.gov (United States)

    Scheuer, Jochen; Schwartz, Ilai; Chen, Qiong; Schulze-Sünninghausen, David; Carl, Patrick; Höfer, Peter; Retzker, Alexander; Sumiya, Hitoshi; Isoya, Junichi; Luy, Burkhard; Plenio, Martin B.; Naydenov, Boris; Jelezko, Fedor

    2016-01-01

    The sensitivity of magnetic resonance imaging (MRI) depends strongly on nuclear spin polarisation and, motivated by this observation, dynamical nuclear spin polarisation has recently been applied to enhance MRI protocols (Kurhanewicz et al 2011 Neoplasia 13 81). Nuclear spins associated with the 13C carbon isotope (nuclear spin I = 1/2) in diamond possess uniquely long spin lattice relaxation times (Reynhardt and High 2011 Prog. Nucl. Magn. Reson. Spectrosc. 38 37). If they are present in diamond nanocrystals, especially when strongly polarised, they form a promising contrast agent for MRI. Current schemes for achieving nuclear polarisation, however, require cryogenic temperatures. Here we demonstrate an efficient scheme that realises optically induced 13C nuclear spin hyperpolarisation in diamond at room temperature and low ambient magnetic field. Optical pumping of a nitrogen-vacancy centre creates a continuously renewable electron spin polarisation which can be transferred to surrounding 13C nuclear spins. Importantly for future applications we also realise polarisation protocols that are robust against an unknown misalignment between magnetic field and crystal axis.

  18. Stimulated nuclear spin echos and spectral diffusion in glasses

    International Nuclear Information System (INIS)

    Borges, N.M.; Engelsberg, M.

    1984-01-01

    Experimental results of stimulated nuclear spin echos decay in glasses are presented. The measurements were performed in B 2 O 3 glasses, at the 23Na and 11 B resonance lines. The data analysis allows the study of Spectral diffusion at an inhomogeneous nuclear magnetic (NMR) resonance line, broadened for a desordered system of nuclear spins. A model is proposed to explain the time constants, and the particular form of the decay. (A.C.A.S.) [pt

  19. Statistical methods of spin assignment in compound nuclear reactions

    International Nuclear Information System (INIS)

    Mach, H.; Johns, M.W.

    1984-01-01

    Spin assignment to nuclear levels can be obtained from standard in-beam gamma-ray spectroscopy techniques and in the case of compound nuclear reactions can be complemented by statistical methods. These are based on a correlation pattern between level spin and gamma-ray intensities feeding low-lying levels. Three types of intensity and level spin correlations are found suitable for spin assignment: shapes of the excitation functions, ratio of intensity at two beam energies or populated in two different reactions, and feeding distributions. Various empirical attempts are examined and the range of applicability of these methods as well as the limitations associated with them are given. 12 references

  20. Statistical methods of spin assignment in compound nuclear reactions

    International Nuclear Information System (INIS)

    Mach, H.; Johns, M.W.

    1985-01-01

    Spin assignment to nuclear levels can be obtained from standard in-beam gamma-ray spectroscopy techniques and in the case of compound nuclear reactions can be complemented by statistical methods. These are based on a correlation pattern between level spin and gamma-ray intensities feeding low-lying levels. Three types of intensity and level spin correlations are found suitable for spin assignment: shapes of the excitation functions, ratio of intensity at two beam energies or populated in two different reactions, and feeding distributions. Various empirical attempts are examined and the range of applicability of these methods as well as the limitations associated with them are given

  1. An endohedral fullerene-based nuclear spin quantum computer

    International Nuclear Information System (INIS)

    Ju Chenyong; Suter, Dieter; Du Jiangfeng

    2011-01-01

    We propose a new scalable quantum computer architecture based on endohedral fullerene molecules. Qubits are encoded in the nuclear spins of the endohedral atoms, which posses even longer coherence times than the electron spins which are used as the qubits in previous proposals. To address the individual qubits, we use the hyperfine interaction, which distinguishes two modes (active and passive) of the nuclear spin. Two-qubit quantum gates are effectively implemented by employing the electronic dipolar interaction between adjacent molecules. The electron spins also assist in the qubit initialization and readout. Our architecture should be significantly easier to implement than earlier proposals for spin-based quantum computers, such as the concept of Kane [B.E. Kane, Nature 393 (1998) 133]. - Research highlights: → We propose an endohedral fullerene-based scalable quantum computer architecture. → Qubits are encoded on nuclear spins, while electron spins serve as auxiliaries. → Nuclear spins are individually addressed using the hyperfine interaction. → Two-qubit gates are implemented through the medium of electron spins.

  2. Calculations of the indirect nuclear spin-spin coupling constants of PbH4

    DEFF Research Database (Denmark)

    Kirpekar, Sheela; Sauer, Stephan P. A.

    1999-01-01

    We report ab initio calculations of the indirect nuclear spin-spin coupling constants of PbH4 using a basis set which was specially optimized for correlated calculations of spin-spin coupling constants. All nonrelativistic contributions and the most important part of the spin-orbit correction wer...

  3. Nuclear spin-lattice relaxation in carbon nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Panich, A.M., E-mail: pan@bgu.ac.i [Department of Physics, Ben-Gurion University of the Negev, P.O. Box 653, Beer Sheva 84105 (Israel); Sergeev, N.A. [Institute of Physics, University of Szczecin, 70-451 Szczecin (Poland)

    2010-04-15

    Interpretation of nuclear spin-lattice relaxation data in the carbon nanostructures is usually based on the analysis of fluctuations of dipole-dipole interactions of nuclear spins and anisotropic electron-nuclear interactions responsible for chemical shielding, which are caused by molecular dynamics. However, many nanocarbon systems such as fullerene and nanotube derivatives, nanodiamonds and carbon onions reveal noticeable amount of paramagnetic defects with unpaired electrons originating from dangling bonds. The interaction between nuclear and electron spins strongly influences the nuclear spin-lattice relaxation, but usually is not taken into account, thus the relaxation data are not correctly interpreted. Here we report on the temperature dependent NMR spectra and spin-lattice relaxation measurements of intercalated fullerenes C{sub 60}(MF{sub 6}){sub 2} (M=As and Sb), where nuclear relaxation is caused by both molecular rotation and interaction between nuclei and unpaired electron spins. We present a detailed theoretical analysis of the spin-lattice relaxation data taking into account both these contributions. Good agreement between the experimental data and calculations is obtained. The developed approach would be useful in interpreting the NMR relaxation data in different nanostructures and their intercalation compounds.

  4. Nuclear spin-lattice relaxation in nitroxide spin-label EPR

    DEFF Research Database (Denmark)

    Marsh, Derek

    2016-01-01

    that the definition of nitrogen nuclear relaxation rate Wn commonly used in the CW-EPR literature for 14N-nitroxyl spin labels is inconsistent with that currently adopted in time-resolved EPR measurements of saturation recovery. Redefinition of the normalised 14N spin-lattice relaxation rate, b = Wn/(2We), preserves...... of spin-lattice relaxation in this three-level system. Expressions for CW-saturation EPR with the revised definitions are summarised. Data on nitrogen nuclear spin-lattice relaxation times are compiled according to the three-level scheme for 14N-relaxation: T1 n = 1/Wn. Results are compared and contrasted...... the expressions used for CW-EPR, whilst rendering them consistent with expressions for saturation recovery rates in pulsed EPR. Furthermore, values routinely quoted for nuclear relaxation times that are deduced from EPR spectral diffusion rates in 14N-nitroxyl spin labels do not accord with conventional analysis...

  5. Nuclear spin-echo detection by means of perturbed angular correlations

    International Nuclear Information System (INIS)

    Kopvillem, U.H.; Shakhmuratova, L.N.

    1973-01-01

    Recent progress in theory and experiment of NMR detection by means of registration of angular distribution of nuclear radiation (NMR/RD) has stimulated us to consider the problem of spin-echo detection by means of nuclear radiation (s-E/RD). We have considered the case when each decaying radioactive nucleus suffers two pulses of magnetic radiofrequency field in its oriented excited state. The time-differential function of radiation's angular distribution is important in the S-E/RD problem, as it displays the motion of nuclear spins in time. The obtained results show that after the first pulse the anisotropy of radiation's angular distribution strongly decreases because of the dephasing of nuclear spins. After the second pulse there exist certain moments of time, determined by the nuclear spin and geometry of experiment, when the anisotropy of radiation's angular distribution sharply increases, whereas before and after these moments the function is swept. It is possible to observe the spin-echo by means of γ-γ angular correlations and by means of registration of γ-radiation's angular distribution after the nuclear reaction, for example after the bombardment of nuclei by a pulsed particle beam. The spin-echo nuclear radiation detection gives the possibility to explore the relaxation processes by the use of a relatively small number nuclei, as it is a microscopic method. (author)

  6. Electronic readout of a single nuclear spin using a molecular spin transistor

    Science.gov (United States)

    Vincent, R.; Klyastskaya, S.; Ruben, M.; Wernsdorfer, W.; Balestro, F.

    2012-02-01

    Quantum control of individual spins in condensed matter devices is an emerging field with a wide range of applications ranging from nanospintronics to quantum computing [1,2]. The electron, with its spin and orbital degrees of freedom, is conventionally used as carrier of the quantum information in the devices proposed so far. However, electrons exhibit a strong coupling to the environment leading to reduced relaxation and coherence times. Indeed quantum coherence and stable entanglement of electron spins are extremely difficult to achieve. We propose a new approach using the nuclear spin of an individual metal atom embedded in a single-molecule magnet (SMM). In order to perform the readout of the nuclear spin, the quantum tunneling of the magnetization (QTM) of the magnetic moment of the SMM in a transitor-like set-up is electronically detected. Long spin lifetimes of an individual nuclear spin were observed and the relaxation characteristics were studied. The manipulation of the nuclear spin state of individual atoms embedded in magnetic molecules opens a completely new world, where quantum logic may be integrated.[4pt] [1] L. Bogani, W. Wernsdorfer, Nature Mat. 7, 179 (2008).[0pt] [2] M. Urdampilleta, S. Klyatskaya, J.P. Cleuziou, M. Ruben, W. Wernsdorfer, Nature Mat. 10, 502 (2011).

  7. Quantum computation with nuclear spins in quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Christ, H.

    2008-01-24

    The role of nuclear spins for quantum information processing in quantum dots is theoretically investigated in this thesis. Building on the established fact that the most strongly coupled environment for the potential electron spin quantum bit are the surrounding lattice nuclear spins interacting via the hyperfine interaction, we turn this vice into a virtue by designing schemes for harnessing this strong coupling. In this perspective, the ensemble of nuclear spins can be considered an asset, suitable for an active role in quantum information processing due to its intrinsic long coherence times. We present experimentally feasible protocols for the polarization, i.e. initialization, of the nuclear spins and a quantitative solution to our derived master equation. The polarization limiting destructive interference effects, caused by the collective nature of the nuclear coupling to the electron spin, are studied in detail. Efficient ways of mitigating these constraints are presented, demonstrating that highly polarized nuclear ensembles in quantum dots are feasible. At high, but not perfect, polarization of the nuclei the evolution of an electron spin in contact with the spin bath can be efficiently studied by means of a truncation of the Hilbert space. It is shown that the electron spin can function as a mediator of universal quantum gates for collective nuclear spin qubits, yielding a promising architecture for quantum information processing. Furthermore, we show that at high polarization the hyperfine interaction of electron and nuclear spins resembles the celebrated Jaynes-Cummings model of quantum optics. This result opens the door for transfer of knowledge from the mature field of quantum computation with atoms and photons. Additionally, tailored specifically for the quantum dot environment, we propose a novel scheme for the generation of highly squeezed collective nuclear states. Finally we demonstrate that even an unprepared completely mixed nuclear spin

  8. Quantum computation with nuclear spins in quantum dots

    International Nuclear Information System (INIS)

    Christ, H.

    2008-01-01

    The role of nuclear spins for quantum information processing in quantum dots is theoretically investigated in this thesis. Building on the established fact that the most strongly coupled environment for the potential electron spin quantum bit are the surrounding lattice nuclear spins interacting via the hyperfine interaction, we turn this vice into a virtue by designing schemes for harnessing this strong coupling. In this perspective, the ensemble of nuclear spins can be considered an asset, suitable for an active role in quantum information processing due to its intrinsic long coherence times. We present experimentally feasible protocols for the polarization, i.e. initialization, of the nuclear spins and a quantitative solution to our derived master equation. The polarization limiting destructive interference effects, caused by the collective nature of the nuclear coupling to the electron spin, are studied in detail. Efficient ways of mitigating these constraints are presented, demonstrating that highly polarized nuclear ensembles in quantum dots are feasible. At high, but not perfect, polarization of the nuclei the evolution of an electron spin in contact with the spin bath can be efficiently studied by means of a truncation of the Hilbert space. It is shown that the electron spin can function as a mediator of universal quantum gates for collective nuclear spin qubits, yielding a promising architecture for quantum information processing. Furthermore, we show that at high polarization the hyperfine interaction of electron and nuclear spins resembles the celebrated Jaynes-Cummings model of quantum optics. This result opens the door for transfer of knowledge from the mature field of quantum computation with atoms and photons. Additionally, tailored specifically for the quantum dot environment, we propose a novel scheme for the generation of highly squeezed collective nuclear states. Finally we demonstrate that even an unprepared completely mixed nuclear spin

  9. Quantum description of nuclear spin cooling in a quantum dot

    Energy Technology Data Exchange (ETDEWEB)

    Giedke, Geza; Christ, H.; Cirac, I. [Max-Planck-Institut fuer Quantenoptik, Hans-Kopfermann-Strasse 1, D-85748 Garching (Germany)

    2007-07-01

    We study theoretically the cooling of an ensemble of nuclear spins coupled to the spin of a localized electron in a quantum dot. We obtain a master equation for the state of the nuclear spins interacting with a sequence of polarized electrons that allows to study quantitatively the cooling process including the effect of nuclear spin coherences, which can lead to 'dark states' of the nuclear system in which further cooling is inhibited. We show that the inhomogeneous Knight field mitigates this effect strongly and that the remaining dark state limitations can be overcome by very few shifts of the electron wave function, allowing for cooling far beyond the dark state limit. Numerical integration of the master equation indicates that polarizations larger than 90% can be achieved within a millisecond timescale.

  10. Distinction of nuclear spin states with the scanning tunneling microscope.

    Science.gov (United States)

    Natterer, Fabian Donat; Patthey, François; Brune, Harald

    2013-10-25

    We demonstrate rotational excitation spectroscopy with the scanning tunneling microscope for physisorbed H(2) and its isotopes HD and D(2). The observed excitation energies are very close to the gas phase values and show the expected scaling with the moment of inertia. Since these energies are characteristic for the molecular nuclear spin states we are able to identify the para and ortho species of hydrogen and deuterium, respectively. We thereby demonstrate nuclear spin sensitivity with unprecedented spatial resolution.

  11. Early spin determination at the LHC?

    Energy Technology Data Exchange (ETDEWEB)

    Moortgat-Pick, Gudrid [Hamburg Univ. (Germany). 2. Inst. fuer Theoretische Physik; Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Rolbiecki, Krzysztof [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Tattersall, Jamie [Bonn Univ. (Germany). Physikalisches Inst.

    2011-02-15

    If signals of new physics are discovered at the LHC it will be crucial to determine the spin structure of a new model. We discuss a method that can help to address this question with a low integrated luminosity L = 1 fb{sup -1}. Based on the differences in angular distributions of primarily produced particles we show that a significant difference can also be observed in final state jet-pairs rapidity distance. The additional advantage of the method is that it does not rely on any particular structure of the couplings in the decay chain. We simulate samples for models with supersymmetric and UED-like spin structure and show that the distinction can be made early on. (orig.)

  12. Relaxation of nuclear spin on holes in semiconductors

    International Nuclear Information System (INIS)

    Gr'ncharova, E.I.; Perel', V.I.

    1977-01-01

    The longitudienal relaxation time T 1 of nuclear spins due to dipole-dipole interaction with holes in semiconductors is calculated. Expressions for T 1 in cubic and uniaxial semiconductors are obtained for non-degenerate and degenerate cases. On the basis of comparison with available experimental data for silicon the agreement with the theoretical results is obtained. It is demonstrated that in uniaxial semiconductors the time of relaxation on holes for a nuclear spin directed along the c axis is considerably greater than that for a spin in the normal direction

  13. Model independent spin determination at hadron colliders

    International Nuclear Information System (INIS)

    Edelhaeuser, Lisa

    2012-01-01

    By the end of the year 2011, both the CMS and ATLAS experiments at the Large Hadron Collider have recorded around 5 inverse femtobarns of data at an energy of 7 TeV. There are only vague hints from the already analysed data towards new physics at the TeV scale. However, one knows that around this scale, new physics should show up so that theoretical issues of the standard model of particle physics can be cured. During the last decades, extensions to the standard model that are supposed to solve its problems have been constructed, and the corresponding phenomenology has been worked out. As soon as new physics is discovered, one has to deal with the problem of determining the nature of the underlying model. A first hint is of course given by the mass spectrum and quantum numbers such as electric and colour charges of the new particles. However, there are two popular model classes, supersymmetric models and extradimensional models, which can exhibit almost equal properties at the accessible energy range. Both introduce partners to the standard model particles with the same charges and thus one needs an extended discrimination method. From the origin of these partners arises a relevant difference: The partners constructed in extradimensional models have the same spin as their standard model partners while in Supersymmetry they differ by spin 1/2. These different spins have an impact on the phenomenology of the two models. For example, one can exploit the fact that the total cross sections are affected, but this requires a very good knowledge of the couplings and masses involved. Another approach uses angular distributions depending on the particle spins. A prevailing method based on this idea uses the invariant mass distribution of the visible particles in decay chains. One can relate these distributions to the spin of the particle mediating the decay since it reflects itself in the highest power of the invariant mass s ff of the adjacent particles. In this thesis we

  14. Model independent spin determination at hadron colliders

    Energy Technology Data Exchange (ETDEWEB)

    Edelhaeuser, Lisa

    2012-04-25

    By the end of the year 2011, both the CMS and ATLAS experiments at the Large Hadron Collider have recorded around 5 inverse femtobarns of data at an energy of 7 TeV. There are only vague hints from the already analysed data towards new physics at the TeV scale. However, one knows that around this scale, new physics should show up so that theoretical issues of the standard model of particle physics can be cured. During the last decades, extensions to the standard model that are supposed to solve its problems have been constructed, and the corresponding phenomenology has been worked out. As soon as new physics is discovered, one has to deal with the problem of determining the nature of the underlying model. A first hint is of course given by the mass spectrum and quantum numbers such as electric and colour charges of the new particles. However, there are two popular model classes, supersymmetric models and extradimensional models, which can exhibit almost equal properties at the accessible energy range. Both introduce partners to the standard model particles with the same charges and thus one needs an extended discrimination method. From the origin of these partners arises a relevant difference: The partners constructed in extradimensional models have the same spin as their standard model partners while in Supersymmetry they differ by spin 1/2. These different spins have an impact on the phenomenology of the two models. For example, one can exploit the fact that the total cross sections are affected, but this requires a very good knowledge of the couplings and masses involved. Another approach uses angular distributions depending on the particle spins. A prevailing method based on this idea uses the invariant mass distribution of the visible particles in decay chains. One can relate these distributions to the spin of the particle mediating the decay since it reflects itself in the highest power of the invariant mass s{sub ff} of the adjacent particles. In this thesis

  15. Relaxation of coupled nuclear spin systems

    International Nuclear Information System (INIS)

    Koenigsberger, E.

    1985-05-01

    The subject of the present work is the relaxation behaviour of scalarly coupled spin-1/2 systems. In the theoretical part the semiclassical Redfield equations are used. Dipolar (D), Chemical Shift Anisotropy (CSA) and Random Field (RF) interactions are considered as relaxation mechanisms. Cross correlations of dipolar interactions of different nuclei pairs and those between the D and the CSA mechanisms are important. The model of anisotropic molecular rotational relaxation and the extreme narrowing approximation are used to obtain the spectral density functions. The longitudinal relaxation data are analyzed into normal modes following Werbelow and Grant. The time evolution of normal modes is derived for the AX system with D-CSA cross terms. In the experimental part the hypothesis of dimerization in the cinnamic acid and the methyl cinnamate - AMX systems with DD cross terms - is corroborated by T 1 -time measurements and a calculation of the diffusion constants. In pentachlorobenzene - an AX system - taking into account of D-CSA cross terms enables the complete determination of movements anosotropy and the determination of the sign of the indirect coupling constant 1 Jsub(CH). (G.Q.)

  16. Fingerprints of single nuclear spin energy levels using STM - ENDOR

    Science.gov (United States)

    Manassen, Yishay; Averbukh, Michael; Jbara, Moamen; Siebenhofer, Bernhard; Shnirman, Alexander; Horovitz, Baruch

    2018-04-01

    We performed STM-ENDOR experiments where the intensity of one of the hyperfine components detected in ESR-STM is recorded while an rf power is irradiated into the tunneling junction and its frequency is swept. When the latter frequency is near a nuclear transition a dip in ESR-STM signal is observed. This experiment was performed in three different systems: near surface SiC vacancies where the electron spin is coupled to a next nearest neighbor 29Si nucleus; Cu deposited on Si(111)7x7 surface, where the unpaired electron of the Cu atom is coupled to the Cu nucleus (63Cu, 65Cu) and on Tempo molecules adsorbed on Au(111), where the unpaired electron is coupled to a Nitrogen nucleus (14N). While some of the hyperfine values are unresolved in the ESR-STM data due to linewidth we find that they are accurately determined in the STM-ENDOR data including those from remote nuclei, which are not detected in the ESR-STM spectrum. Furthermore, STM-ENDOR can measure single nuclear Zeeman frequencies, distinguish between isotopes through their different nuclear magnetic moments and detect quadrupole spectra. We also develop and solve a Bloch type equation for the coupled electron-nuclear system that facilitates interpretation of the data. The improved spectral resolution of STM - ENDOR opens many possibilities for nanometric scale chemical analysis.

  17. Fingerprints of single nuclear spin energy levels using STM - ENDOR.

    Science.gov (United States)

    Manassen, Yishay; Averbukh, Michael; Jbara, Moamen; Siebenhofer, Bernhard; Shnirman, Alexander; Horovitz, Baruch

    2018-04-01

    We performed STM-ENDOR experiments where the intensity of one of the hyperfine components detected in ESR-STM is recorded while an rf power is irradiated into the tunneling junction and its frequency is swept. When the latter frequency is near a nuclear transition a dip in ESR-STM signal is observed. This experiment was performed in three different systems: near surface SiC vacancies where the electron spin is coupled to a next nearest neighbor 29 Si nucleus; Cu deposited on Si(111)7x7 surface, where the unpaired electron of the Cu atom is coupled to the Cu nucleus ( 63 Cu, 65 Cu) and on Tempo molecules adsorbed on Au(111), where the unpaired electron is coupled to a Nitrogen nucleus ( 14 N). While some of the hyperfine values are unresolved in the ESR-STM data due to linewidth we find that they are accurately determined in the STM-ENDOR data including those from remote nuclei, which are not detected in the ESR-STM spectrum. Furthermore, STM-ENDOR can measure single nuclear Zeeman frequencies, distinguish between isotopes through their different nuclear magnetic moments and detect quadrupole spectra. We also develop and solve a Bloch type equation for the coupled electron-nuclear system that facilitates interpretation of the data. The improved spectral resolution of STM - ENDOR opens many possibilities for nanometric scale chemical analysis. Copyright © 2018 Elsevier Inc. All rights reserved.

  18. International conference on spin observables of nuclear probes: Summary talk

    International Nuclear Information System (INIS)

    Garvey, G.T.

    1988-01-01

    A selected summary of the presentation and discussions at the 4th Telluride Conference is presented. The summary deals mainly with the effects of nuclear spin and isospin on the interaction between nucleons and their consequences in nuclear structure. 11 figs

  19. The domestication of nuclear spins by chemists and biologists

    CERN Document Server

    Ernst, R

    1992-01-01

    The usage of nuclear spins in chemistry and biology for exploring the structure and dynamics of matter is discussed. The main emphasis is put on the methodological aspects of multidimensional nuclear magnetic resonance (NMR) spectroscopy that are responsible for the success of this powerful analytical technique.

  20. Nuclear structure at high spin using multidetector gamma array and ...

    Indian Academy of Sciences (India)

    2014-04-05

    Apr 5, 2014 ... Nuclear structure at high spin. Figure 1. Schematic of the orientation of HPGe detector in GDA [4]. These signals were fed to custom-made data acquisition system Freedom [10] which was later used for data reduction. We recorded γ-ray fold of nuclear reaction using multiplicity filter made of BGO scin-.

  1. Spin-orbit corrections to the indirect nuclear spin-spin coupling constants in XH4 (X=C, Si, Ge, and Sn)

    DEFF Research Database (Denmark)

    Kirpekar, Sheela; Jensen, Hans Jørgen Aagaard; Oddershede, Jens

    1997-01-01

    Using the quadratic response function at the ab initio SCF level of approximation we have calculated the relativistic corrections from the spin-orbit Hamiltonian, HSO, to the indirect nuclear spin-spin coupling constants of XH4 (X = C, Si, Ge, and Sn). We find that the spin-orbit contributions to...

  2. Polarization transfer from polarized nuclear spin to μ- spin in muonic atom

    International Nuclear Information System (INIS)

    Kuno, Yoshitaka; Nagamine, Kanetada; Yamazaki, Toshimitsu.

    1987-02-01

    A theoretical study of polarization transfer from an initially-polarized nuclear spin to a μ - spin in a muonic atom is given. The switching of the hyperfine interaction at excited muonic states as well as at the ground 1s state is taken into account. The upper state of hyperfine doublet at the muonic 1s state is considered to proceed down to the lower state. It is found that as the hyperfine interaction becomes effective at higher excited muonic orbitals, a less extent of polarization is transferred from the nuclear spin to the μ - spin. The theoretical values obtained are compared with the recent experiment of μ - repolarization in a polarized 209 Bi target. (author)

  3. Tilted Foils Nuclear Spin Polarization at REX-ISOLDE

    CERN Document Server

    Törnqvist, Hans Toshihide

    2013-08-08

    This thesis will explain and summarize my work and involvement in experiments aimed at producing nuclear spin polarization of post-accelerated beams of ions with the tilted-foils technique at the REX-ISOLDE linear accelerator at CERN. Polarizing the nuclear spin of radioactive beams in particular may provide access to observables which may be difficult to obtain otherwise. Currently, the techniques commonly employed for nuclear spin polarization are restricted to specific nuclides and experimental measurement techniques. Tilted foils polarization may provide a new tool to extend the range of nuclides that can be polarized and the types of experiments that can be performed. The experiments rely not only on the production but also on the method to measure the degree of attained polarization. Two methods will be treated, based on particle scattering in Coulomb excitation that may be utilized for stable beams, and the $\\beta$-NMR that requires $\\beta$-decaying nuclei. The experimental setups and measurements will...

  4. Determining Mechanical Parameters for Spin in Tennis Strings

    DEFF Research Database (Denmark)

    Bendtsen, Kaare; Rasmussen, Kasper; Hansen, Martin B.

    2015-01-01

    The ability to generate spin is a key element for any tennis player. However, the mechanical parameters of tennis strings which contribute to producing spin are poorly understood. This study attempted to determine some of these parameters through a spin test and a tensile test. Nine different...

  5. Nuclear paramagnetic spin relaxation theory. Paramagnetic spin probes in homogeneous and micro-heterogeneous solutions

    International Nuclear Information System (INIS)

    Westlund, P.O.

    1994-01-01

    Specific mechanisms of relaxation encountered in paramagnetic systems are described: the T1-NMRD curve and the paramagnetically enhanced nuclear spin relaxation (PER) are first discussed and a general theory of PER is proposed (nuclear paramagnetic spin relaxation theory, lattice operators, decomposition approximation, general expression of dipolar correlation functions for slow tumbling complexes, low-field approach). Numerically calculated NMRD curves are described (reorientation model, pseudo-rotation models, vibration models). Experimental studies are then analyzed: NMRD studies of paramagnetic species in an aqueous system, paramagnetic hydrated metal ions in poly-electrolytes and biochemical systems, lyotropic liquid crystalline phases, polymer solutions. 19 fig., 60 ref

  6. Generating highly polarized nuclear spins in solution using dynamic nuclear polarization

    DEFF Research Database (Denmark)

    Wolber, J.; Ellner, F.; Fridlund, B.

    2004-01-01

    A method to generate strongly polarized nuclear spins in solution has been developed, using Dynamic Nuclear Polarization (DNP) at a temperature of 1.2K, and at a field of 3.354T, corresponding to an electron spin resonance frequency of 94GHz. Trityl radicals are used to directly polarize 13C...... and other low-γ nuclei. Subsequent to the DNP process, the solid sample is dissolved rapidly with a warm solvent to create a solution of molecules with highly polarized nuclear spins. Two main applications are proposed: high-resolution liquid state NMR with enhanced sensitivity, and the use...

  7. Squeezing and entangling nuclear spins in helium 3

    DEFF Research Database (Denmark)

    Reinaudi, Gael; Sinatra, Alice; Dantan, Aurelien Romain

    2007-01-01

    We present a realistic model for transferring the squeezing or the entanglement of optical field modes to the collective ground state nuclear spin of 3He using metastability exchange collisions. We discuss in detail the requirements for obtaining good quantum state transfer efficiency and study...

  8. Increasing Spin Coherence in Nanodiamond via Dynamic Nuclear Polarization

    Science.gov (United States)

    Gaebel, Torsten; Rej, Ewa; Boele, Thomas; Waddington, David; Reilly, David

    Nanodiamonds are of interest for quantum information technology, as metrological sensors, and more recently as a probe of biological environments. Here we present results examining how intrinsic defects can be used for dynamic nuclear polarization that leads to a dramatic increase in both T1 and T2 for 13C spins in nanodiamond. Mechanisms to explain this enhancement are discussed.

  9. Nuclear moments of inertia at high spin

    International Nuclear Information System (INIS)

    Deleplanque, M.A.

    1982-10-01

    The competition between collective motion and alignment at high spin can be evaluated by measuring two complementary dynamic moments of inertia. The first, I band, measured in γ-γ correlation experiments, relates to the collective properties of the nucleus. A new moment of inertia I/sub eff/ is defined here, which contains both collective and alignment effects. Both of these can be measured in continuum γ-ray spectra of rotational nuclei up to high frequencies. The evolution of γ-ray spectra for Er nuclei from mass 160 to 154 shows that shell effects can directly be observed in the spectra of the lighter nuclei

  10. Fully Automated Quantum-Chemistry-Based Computation of Spin-Spin-Coupled Nuclear Magnetic Resonance Spectra.

    Science.gov (United States)

    Grimme, Stefan; Bannwarth, Christoph; Dohm, Sebastian; Hansen, Andreas; Pisarek, Jana; Pracht, Philipp; Seibert, Jakob; Neese, Frank

    2017-11-13

    We present a composite procedure for the quantum-chemical computation of spin-spin-coupled 1 H NMR spectra for general, flexible molecules in solution that is based on four main steps, namely conformer/rotamer ensemble (CRE) generation by the fast tight-binding method GFN-xTB and a newly developed search algorithm, computation of the relative free energies and NMR parameters, and solving the spin Hamiltonian. In this way the NMR-specific nuclear permutation problem is solved, and the correct spin symmetries are obtained. Energies, shielding constants, and spin-spin couplings are computed at state-of-the-art DFT levels with continuum solvation. A few (in)organic and transition-metal complexes are presented, and very good, unprecedented agreement between the theoretical and experimental spectra was achieved. The approach is routinely applicable to systems with up to 100-150 atoms and may open new avenues for the detailed (conformational) structure elucidation of, for example, natural products or drug molecules. © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

  11. Symmetry rules for the indirect nuclear spin-spin coupling tensor revisited

    Science.gov (United States)

    Buckingham, A. D.; Pyykkö, P.; Robert, J. B.; Wiesenfeld, L.

    The symmetry rules of Buckingham and Love (1970), relating the number of independent components of the indirect spin-spin coupling tensor J to the symmetry of the nuclear sites, are shown to require modification if the two nuclei are exchanged by a symmetry operation. In that case, the anti-symmetric part of J does not transform as a second-rank polar tensor under symmetry operations that interchange the coupled nuclei and may be called an anti-tensor. New rules are derived and illustrated by simple molecular models.

  12. Nuclear structure of Ra at high spin

    Indian Academy of Sciences (India)

    to such an aligned configuration in 216Ra, would be of the order of J ∼ 39 ¯h with a wave function of π(h2. 9/2 f 2 ... detectors at 99. ◦. In addition to these matrices, γ-gated γT matrices were generated for getting time spectrum between any two γ's of 216Ra which enabled lifetime measurement of isomeric nuclear levels. 3.

  13. Photoinduced nuclear spin conversion of methyl groups of single molecules

    International Nuclear Information System (INIS)

    Sigl, A.

    2007-01-01

    A methyl group is an outstanding quantum system due to its special symmetry properties. The threefold rotation around one of its bond is isomorphic to the group of even permutations of the remaining protons, a property which imposes severe quantum restrictions on the system, for instance a strict correlation of rotational states with nuclear spin states. The resulting long lifetimes of the rotational tunneling states of the methyl group can be exploited for applying certain high resolution optical techniques, like hole burning or single molecule spectroscopy to optically switch the methyl group from one tunneling state to another therebye changing the nuclear spin of the protons. One goal of the thesis was to perform this switching in single methyl groups. To this end the methyl group was attached to a chromophoric system, in the present case terrylene, which is well suited for single molecule spectroscopy as well as for hole burning. Experiments were performed with the bare terrylene molecule in a hexadecane lattice which served as a reference system, with alphamethyl terrylene and betamethyl terrylene, both embedded in hexadecane, too. A single molecular probe is a highly sensitive detector for dynamic lattice instabilities. Already the bare terrylene probe showed a wealth of interesting local dynamic effects of the hexadecane lattice which could be well acounted for by the assumption of two nearly degenerate sites with rather different optical and thermal properties, all of which could be determined in a quantitative fashion. As to the methylated terrylene systems, the experiments verified that for betamethyl terrylene it is indeed possible to measure rotational tunneling events in single methyl groups. However, the spectral patterns obtained was much more complicated than expected pointing to the presence of three spectroscopically different methyl groups. In order to achieve a definite assignement, molecular mechanics simulations of the terrylene probes in the

  14. Nuclear spin relaxation in liquids theory, experiments, and applications

    CERN Document Server

    Kowalewski, Jozef

    2006-01-01

    Nuclear magnetic resonance (NMR) is widely used across many fields because of the rich data it produces, and some of the most valuable data come from the study of nuclear spin relaxation in solution. While described to varying degrees in all major NMR books, spin relaxation is often perceived as a difficult, if not obscure, topic, and an accessible, cohesive treatment has been nearly impossible to find.Collecting relaxation theory, experimental techniques, and illustrative applications into a single volume, this book clarifies the nature of the phenomenon, shows how to study it, and explains why such studies are worthwhile. Coverage ranges from basic to rigorous theory and from simple to sophisticated experimental methods, and the level of detail is somewhat greater than most other NMR texts. Topics include cross-relaxation, multispin phenomena, relaxation studies of molecular dynamics and structure, and special topics such as relaxation in systems with quadrupolar nuclei and paramagnetic systems.Avoiding ove...

  15. Nuclear spin: Fifty years of ups and downs

    Energy Technology Data Exchange (ETDEWEB)

    Pines, A. [Lawrence Berkeley National Lab., CA (United States)

    1996-12-31

    Rumors of its demise notwithstanding, nuclear magnetic resonance (NMR) continues to flourish fifty years after our birth. The lecture will be a reminiscence about moments of excitation, coherence and relaxation in the history of NMR which produced, among other developments, spin echoes and time reversal, Fourier transform and multidimensional spectroscopy, magnetic resonance imaging, and high resolution solid state NMR. Applications of modern NMR spectroscopy cut across the boundaries of physics, chemistry, materials, biology and medicine.

  16. NV-NV electron-electron spin and NV-N S electron - electron and electron-nuclear spin interaction in diamond

    Science.gov (United States)

    Armstrong, Seiji; Rogers, Lachlan J.; McMurtrie, Roger L.; Manson, Neil B.

    2010-02-01

    Features associated with the cross relaxation between spin of the ground electric state of the nitrogen vacancy centre (NV) and other impurity spins, mainly substitutional nitrogen, NS, are observed as changes of the emission intensity as a function of external magnetic field. The features are attributed to NV-NV electron-electron spin interaction, NV- NS electron-nuclear spin interaction and NV electron spin interaction with simultaneous change of an NS electron and nuclear spin change.

  17. Nuclear spin dynamics in double quantum dots : Fixed points, transients, and intermittency

    NARCIS (Netherlands)

    Rudner, M.S.; Koppens, F.H.L.; Folk, J.A.; Vandersypen, L.M.K.; Levitov, L.S.

    2011-01-01

    Transport through spin-blockaded quantum dots provides a means for electrical control and detection of nuclear spin dynamics in the host material. Although such experiments have become increasingly popular in recent years, interpretation of their results in terms of the underlying nuclear spin

  18. Long lived quantum memory with nuclear atomic spins

    International Nuclear Information System (INIS)

    Sinatra, A.; Reinaudi, G.; Dantan, A.; Giacobino, E.; Pinard, M.

    2005-01-01

    We propose store non-classical states of light into the macroscopic collective nuclear spin (10 18 atoms) of a 3 He vapor, using metastability exchange collisions. We show that these collisions currently used to transfer orientation from the metastable state 2 3 S 1 to the ground state state of 3 He, may conserve quantum correlations and give a possible experimental scheme to perfectly map a squeezed vacuum field state onto a nuclear spin state, which should allow for extremely long storage times (hours). In addition to the apparent interest for quantum information, the scheme offers the intriguing possibility to create a long-lived non classical state for spins. During a metastability exchange collision an atom in the ground state state and an atom in the metastable triplet state 2 3 S exchange their electronic spin variables. The ground state atom is then brought into the metastable state and vice-versa. A laser transition is accessible from the metastable state so that the metastable atoms are coupled with light. This, together with metastability exchange collisions, provides an effective coupling between ground state atoms and light. In our scheme, a coherent field and a squeezed vacuum field excite a Raman transition between Zeeman sublevels of the metastable state, after the system is prepared in the fully polarized state by preliminary optical pumping. According to the intensity of the coherent field, which acts as a control parameter, the squeezing of the field can be selectively transferred either to metastable or to ground state atoms. Once it is encoded in the purely nuclear spin of the ground state of 3 He, which is 20 eV apart from the nearest excited state and interacts very little with the environment, the quantum state can survive for times as long as several hours. By lighting up only the coherent field in the same configuration as for the 'writing' phase, the nuclear spin memory can be 'read' after a long delay, the squeezing being transferred

  19. Nuclear spin optical rotation and Faraday effect in gaseous and liquid water.

    Science.gov (United States)

    Pennanen, Teemu S; Ikäläinen, Suvi; Lantto, Perttu; Vaara, Juha

    2012-05-14

    Nuclear spin optical rotation (NSOR) of linearly polarized light, due to the nuclear spins through the Faraday effect, provides a novel probe of molecular structure and could pave the way to optical detection of nuclear magnetization. We determine computationally the effects of the liquid medium on NSOR and the Verdet constant of Faraday rotation (arising from an external magnetic field) in water, using the recently developed theory applied on a first-principles molecular dynamics trajectory. The gas-to-liquid shifts of the relevant antisymmetric polarizability and, hence, NSOR magnitude are found to be -14% and -29% for (1)H and (17)O nuclei, respectively. On the other hand, medium effects both enhance the local electric field in water and, via bulk magnetization, the local magnetic field. Together these two effects partially cancel the solvation influence on the single-molecular property. We find a good agreement for the hydrogen NSOR with a recent pioneering experiment on H(2)O(l).

  20. Nuclear structure at high-spin and large-deformation

    International Nuclear Information System (INIS)

    Shimizu, Yoshifumi R.

    2000-01-01

    Atomic nucleus is a finite quantal system and shows various marvelous features. One of the purposes of the nuclear structure study is to understand such features from a microscopic viewpoint of nuclear many-body problem. Recently, it is becoming possible to explore nuclear states under 'extreme conditions', which are far different from the usual ground states of stable nuclei, and new aspects of such unstable nuclei attract our interests. In this lecture, I would like to discuss the nuclear structure in the limit of rapid rotation, or the extreme states with very large angular momenta, which became accessible by recent advent of large arrays of gamma-ray detecting system; these devices are extremely useful to measure coincident multiple γ-rays following heavy-ion fusion reactions. Including such experimental aspects as how to detect the nuclear rotational states, I review physics of high-spin states starting from the elementary subjects of nuclear structure study. In would like also to discuss the extreme states with very large nuclear deformation, which are easily realized in rapidly rotating nuclei. (author)

  1. Nuclear spin-spin coupling in a van der Waals-bonded system: xenon dimer.

    Science.gov (United States)

    Vaara, Juha; Hanni, Matti; Jokisaari, Jukka

    2013-03-14

    Nuclear spin-spin coupling over van der Waals bond has recently been observed via the frequency shift of solute protons in a solution containing optically hyperpolarized (129)Xe nuclei. We carry out a first-principles computational study of the prototypic van der Waals-bonded xenon dimer, where the spin-spin coupling between two magnetically non-equivalent isotopes, J((129)Xe - (131)Xe), is observable. We use relativistic theory at the four-component Dirac-Hartree-Fock and Dirac-density-functional theory levels using novel completeness-optimized Gaussian basis sets and choosing the functional based on a comparison with correlated ab initio methods at the nonrelativistic level. J-coupling curves are provided at different levels of theory as functions of the internuclear distance in the xenon dimer, demonstrating cross-coupling effects between relativity and electron correlation for this property. Calculations on small Xe clusters are used to estimate the importance of many-atom effects on J((129)Xe - (131)Xe). Possibilities of observing J((129)Xe - (131)Xe) in liquid xenon are critically examined, based on molecular dynamics simulation. A simplistic spherical model is set up for the xenon dimer confined in a cavity, such as in microporous materials. It is shown that the on the average shorter internuclear distance enforced by the confinement increases the magnitude of the coupling as compared to the bulk liquid case, rendering J((129)Xe - (131)Xe) in a cavity a feasible target for experimental investigation.

  2. Nuclear spin relaxation/resonance of 8Li in Al

    Science.gov (United States)

    Wang, D.; Salman, Z.; Chow, K. H.; Fan, I.; Hossain, M. D.; Keeler, T. A.; Kiefl, R. F.; Levy, C. D. P.; Mansour, A. I.; Morris, G. D.; Pearson, M. R.; Parolin, T. J.; Saadaoui, H.; Smadella, M.; Song, Q.; MacFarlane, W. A.

    2009-04-01

    A low energy beam of spin polarized 8Li has been used to study the behaviour of isolated 8Li implanted into a 150 nm thick film of Al on an MgO substrate. The spin relaxation rate 1/T1 and β-NMR lineshape were measured as a function of temperature in a large magnetic field of 4.1 T. The resonances from different sites are unresolved due to the large nuclear dipolar interaction with the host 27Al magnetic dipole moments. Nevertheless the temperature variation of the site averaged 1/T1 and Knight shift show evidence for a transition between the octahedral O and substitutional S sites at about 150 K, as observed in other fcc metals.

  3. Subcriticality determination of nuclear reactor

    International Nuclear Information System (INIS)

    Borisenko, V.I.; Goranchuk, V.V.; Sidoruk, N.M.; Volokh, A.F.

    2014-01-01

    In this article the subcriticality determination of nuclear reactor is considered. Emphasized that, despite the requirements of regulatory documents on the subcriticality determination of WWER from the beginning of their operation, so far, this problem has not been solved. The results of subcriticality determination of Rossi-α method of the WWER-M is presented. The possibility of subcriticality determination of WWER is considered. The possibility of subcriticality determination of Rossi-α method with time resolution is of about 100 microseconds is also considered. The possible reasons for the error in subcriticality determination of the reactor are indicated

  4. Spin assignments of nuclear levels above the neutron binding energy in $^{88}$Sr

    CERN Multimedia

    Neutron resonances reveal nuclear levels in the highly excited region of the nucleus around the neutron binding energy. Nuclear level density models are therefore usually calibrated to the number of observed levels in neutron-induced reactions. The gamma-ray cascade from the decay of the highly excited compound nucleus state to the ground state show dierences dependent on the initial spin. This results in a dierence in the multiplicity distribution which can be exploited. We propose to use the 4${\\pi}$ total absorption calorimeter (TAC) at the n TOF facility to determine the spins of resonances formed by neutrons incident on a metallic $^{87}$Sr sample by measuring the gamma multiplicity distributions for the resolved resonances. In addition we would like to use the available enriched $^{87}$Sr target for cross section measurements with the C$\\scriptscriptstyle{6}$D$\\scriptscriptstyle{6}$ detector setup.

  5. Single-shot readout of multiple nuclear spin qubits in diamond under ambient conditions

    Science.gov (United States)

    Jacques, Vincent

    2013-03-01

    Nuclear spins are attractive candidates for solid-state quantum information storage and processing owing to their extremely long coherence time. However, since this appealing property results from a high level of isolation from the environment, it remains a challenging task to polarize, manipulate and readout with high fidelity individual nuclear spins. A promising approach to overcome this limitation consists in utilizing an ancillary single electronic spin to detect and control remote nuclear spins coupled by hyperfine interaction. In this talk, I will show how the electronic spin of a single Nitrogen-Vacancy (NV) defect in diamond can be used as a robust platform to observe the real-time evolution of surrounding single nuclear spins under ambient conditions. Using a diamond sample with a natural abundance of 13C isotopes, we first demonstrate high fidelity initialization and single-shot readout of an individual 13C nuclear spin. By including the intrinsic 14N nuclear spin of the NV defect in the quantum register, we then report the simultaneous observation of quantum jumps linked to both nuclear spin species, providing an efficient initialization of the two qubits. These results open up new avenues for diamond-based quantum information processing (QIP) including active feedback in quantum error correction protocols and tests of quantum correlations with solid-state single spins at room temperature.

  6. Quantum information processing with electronic and nuclear spins in semiconductors

    Science.gov (United States)

    Klimov, Paul Victor

    Traditional electronic and communication devices operate by processing binary information encoded as bits. Such digital devices have led to the most advanced technologies that we encounter in our everyday lives and they influence virtually every aspect of our society. Nonetheless, there exists a much richer way to encode and process information. By encoding information in quantum mechanical states as qubits, phenomena such as coherence and entanglement can be harnessed to execute tasks that are intractable to digital devices. Under this paradigm, it should be possible to realize quantum computers, quantum communication networks and quantum sensors that outperform their classical counterparts. The electronic spin states of color-center defects in the semiconductor silicon carbide have recently emerged as promising qubit candidates. They have long-lived quantum coherence up to room temperature, they can be controlled with mature magnetic resonance techniques, and they have a built-in optical interface operating near the telecommunication bands. In this thesis I will present two of our contributions to this field. The first is the electric-field control of electron spin qubits. This development lays foundation for quantum electronics that operate via electrical gating, much like traditional electronics. The second is the universal control and entanglement of electron and nuclear spin qubits in an ensemble under ambient conditions. This development lays foundation for quantum devices that have a built-in redundancy and can operate in real-world conditions. Both developments represent important steps towards practical quantum devices in an electronic grade material.

  7. Probing Nuclear Spin Effects on Electronic Spin Coherence via EPR Measurements of Vanadium(IV) Complexes.

    Science.gov (United States)

    Graham, Michael J; Krzyaniak, Matthew D; Wasielewski, Michael R; Freedman, Danna E

    2017-07-17

    Quantum information processing (QIP) has the potential to transform numerous fields from cryptography, to finance, to the simulation of quantum systems. A promising implementation of QIP employs unpaired electronic spins as qubits, the fundamental units of information. Though molecular electronic spins offer many advantages, including chemical tunability and facile addressability, the development of design principles for the synthesis of complexes that exhibit long qubit superposition lifetimes (also known as coherence times, or T 2 ) remains a challenge. As nuclear spins in the local qubit environment are a primary cause of shortened superposition lifetimes, we recently conducted a study which employed a modular spin-free ligand scaffold to place a spin-laden propyl moiety at a series of fixed distances from an S = 1 / 2 vanadium(IV) ion in a series of vanadyl complexes. We found that, within a radius of 4.0(4)-6.6(6) Å from the metal center, nuclei did not contribute to decoherence. To assess the generality of this important design principle and test its efficacy in a different coordination geometry, we synthesized and investigated three vanadium tris(dithiolene) complexes with the same ligand set employed in our previous study: K 2 [V(C 5 H 6 S 4 ) 3 ] (1), K 2 [V(C 7 H 6 S 6 ) 3 ] (2), and K 2 [V(C 9 H 6 S 8 ) 3 ] (3). We specifically interrogated solutions of these complexes in DMF-d 7 /toluene-d 8 with pulsed electron paramagnetic resonance spectroscopy and electron nuclear double resonance spectroscopy and found that the distance dependence present in the previously synthesized vanadyl complexes holds true in this series. We further examined the coherence properties of the series in a different solvent, MeCN-d 3 /toluene-d 8 , and found that an additional property, the charge density of the complex, also affects decoherence across the series. These results highlight a previously unknown design principle for augmenting T 2 and open new pathways for the

  8. Radioactive nuclear beams and the North American IsoSpin Laboratory (ISL) initiative

    International Nuclear Information System (INIS)

    Casten, R.F.

    1992-01-01

    Radioactive nuclear beams (RNBs) offer exciting new research opportunities in fields as diverse as nuclear structure, nuclear reactions, astrophysics atomic, materials, and applied science. Their realization in new accelerator complexes also offers important technical challenges. Some of the nuclear physics possibilities afforded by RNBs, with emphasis on low spin nuclear structure, are discussed, accompanied by an outline of the ISL initiative and its status

  9. Solid state nuclear magnetic resonance: investigating the spins of nuclear related materials

    International Nuclear Information System (INIS)

    Charpentier, Th.

    2007-10-01

    The author reviews his successive research works: his research thesis work on the Multiple Quantum Magic Angle Spinning (MQMAS) which is a quadric-polar nucleus multi-quanta correlation spectroscopy method, the modelling of NMR spectra of disordered materials, the application to materials of interest for the nuclear industry (notably the glasses used for nuclear waste containment). He presents the various research projects in which he is involved: storing glasses, nuclear magnetic resonance in paramagnetism, solid hydrogen storing matrices, methodological and instrument developments in high magnetic field and high resolution solid NMR, long range distance measurement by solid state Tritium NMR (observing the structure and dynamics of biological complex systems at work)

  10. Correlation functions of electronic and nuclear spins in a Heisenberg antiferromagnet semi-infinite media

    International Nuclear Information System (INIS)

    Sarmento, E.F.

    1980-01-01

    Results are found for the correlation dynamic functions (or the correspondent green functions) between any combination including pairs of electronic anel nuclear spin operators in an antiferromagnet semi-infinite media., at low temperature T N . These correlation functions, are used to investigate, at the same time, the properties of surface spin waves in volume and surface. The dispersion relatons of nuclear and electronic spin waves coupled modes, in surface are found, resolving a system of linearized equatons of spin operators a system of linearized equations of spin operators. (author) [pt

  11. Protocol for generating multiphoton entangled states from quantum dots in the presence of nuclear spin fluctuations

    Science.gov (United States)

    Denning, Emil V.; Iles-Smith, Jake; McCutcheon, Dara P. S.; Mork, Jesper

    2017-12-01

    Multiphoton entangled states are a crucial resource for many applications in quantum information science. Semiconductor quantum dots offer a promising route to generate such states by mediating photon-photon correlations via a confined electron spin, but dephasing caused by the host nuclear spin environment typically limits coherence (and hence entanglement) between photons to the spin T2* time of a few nanoseconds. We propose a protocol for the deterministic generation of multiphoton entangled states that is inherently robust against the dominating slow nuclear spin environment fluctuations, meaning that coherence and entanglement is instead limited only by the much longer spin T2 time of microseconds. Unlike previous protocols, the present scheme allows for the generation of very low error probability polarization encoded three-photon GHZ states and larger entangled states, without the need for spin echo or nuclear spin calming techniques.

  12. Corrections to nucleon spin structure asymmetries measured on nuclear polarized targets

    International Nuclear Information System (INIS)

    Rondon, O.A.

    1999-01-01

    The nucleon spin structure functions have been extracted from measurements of asymmetries in deep inelastic scattering of polarized leptons on polarized nuclei. The polarized nuclei present in practical targets: H, 2 H, 3 He, 14 N, 15 N, 6 Li, and 7 Li, are, with the exception of hydrogen, systems of bound nucleons, some of which can attain significant degrees of alignment. All the aligned nucleons contribute to the asymmetries. The contributions of each nuclear species to the asymmetry have to be carefully determined, before a reliable value for the net nucleon asymmetry is obtained. For this purpose, the spin component of the nuclear angular momentum for every nuclear state and the probability of each state have to be known with sufficient accuracy. In this paper I discuss the basic corrections used to estimate the contributions of the different nuclei, with emphasis on the A=6 and 7 Li isotopes present in the Li 2 H polarized target used during SLAC Experiment 155 to study the deuteron spin structure. copyright 1999 The American Physical Society

  13. Voltage switching technique for detecting nuclear spin polarization in a quantum dot

    International Nuclear Information System (INIS)

    Takahashi, Ryo; Kono, Kimitoshi; Tarucha, Seigo; Ono, Keiji

    2010-01-01

    We have introduced a source-drain voltage switching technique for studying nuclear spins in a vertical double quantum dot. Switching the source-drain voltage between the spin-blockade state and the zero-bias Coulomb blockade state can tune the energy difference between the spin singlet and triplet, and effectively turn on/off the hyperfine interaction. Since the change in the nuclear spin state affects the source-drain current, nuclear spin properties can only be detected by transport measurement. Using this technique, we have succeeded in measuring the timescale of nuclear spin depolarization. Furthermore, combining this technique and an RF ac magnetic field, we successfully detected continuous-wave NMR signals of 75 As, 69 Ga, and 71 Ga, which are contained in a quantum dot. (author)

  14. Novel nuclear laser spectroscopy method using superfluid helium for measurement of spins and moments of exotic nuclei

    International Nuclear Information System (INIS)

    Furukawa, Takeshi; Wakui, Takashi; Yang, Xiaofei; Fujita, Tomomi; Imamura, Kei; Yamaguchi, Yasuhiro; Tetsuka, Hiroki; Tsutsui, Yoshiki; Mitsuya, Yosuke; Ichikawa, Yuichi; Ishibashi, Yoko; Yoshida, Naoki; Shirai, Hazuki; Ebara, Yuta; Hayasaka, Miki; Arai, Shino; Muramoto, Sosuke

    2013-01-01

    Highlights: • Development of a novel nuclear laser spectroscopy method using superfluid helium. • Observation of the Zeeman resonance with the 85 Rb beam introduced into helium. • Demonstration of deducing the nuclear spins from the observed resonance spectrum. -- Abstract: We have been developing a novel nuclear laser spectroscopy method “OROCHI” for determining spins and moments of exotic radioisotopes. In this method, we use superfluid helium as a stopping material of energetic radioisotope beams and then stopped radioisotope atoms are subjected to in situ laser spectroscopy in superfluid helium. To confirm the feasibility of this method for rare radioisotopes, we carried out a test experiment using a 85 Rb beam. In this experiment, we have successfully measured the Zeeman resonance signals from the 85 Rb atoms stopped in superfluid helium by laser-RF double resonance spectroscopy. This method is efficient for the measurement of spins and moments of more exotic nuclei

  15. Novel nuclear laser spectroscopy method using superfluid helium for measurement of spins and moments of exotic nuclei

    Energy Technology Data Exchange (ETDEWEB)

    Furukawa, Takeshi, E-mail: takeshi@tmu.ac.jp [Department of Physics, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji, Tokyo 192-0397 (Japan); RIKEN Nishina Center, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Wakui, Takashi [Cyclotron and Radioisotope Center, Tohoku University, 6-3 Aoba, Aramaki, Aoba, Sendai, Miyagi 980-8578 (Japan); Yang, Xiaofei [RIKEN Nishina Center, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); School of Physics, Peking University, Chengfu Road, Haidian District, Beijing 100871 (China); Fujita, Tomomi [Department of Physics, Osaka University, 1-1 Machikaneyama, Toyonaka, Osaka 560-0043 (Japan); Imamura, Kei; Yamaguchi, Yasuhiro [Department of Physics, Meiji University, 1-1-1 Higashi-Mita, Tama, Kawasaki, Kanagawa 214-8571 (Japan); Tetsuka, Hiroki; Tsutsui, Yoshiki [Department of Physics, Tokyo Gakugei University, 4-1-1 Nukuikitamachi, Koganei, Tokyo 184-8501,Japan (Japan); Mitsuya, Yosuke [Department of Physics, Meiji University, 1-1-1 Higashi-Mita, Tama, Kawasaki, Kanagawa 214-8571 (Japan); Ichikawa, Yuichi [RIKEN Nishina Center, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Department of Physics, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro, Tokyo 152-8551 (Japan); Ishibashi, Yoko [RIKEN Nishina Center, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Department of Physics, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577 (Japan); Yoshida, Naoki; Shirai, Hazuki [RIKEN Nishina Center, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Department of Physics, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro, Tokyo 152-8551 (Japan); Ebara, Yuta; Hayasaka, Miki [Department of Physics, Tokyo Gakugei University, 4-1-1 Nukuikitamachi, Koganei, Tokyo 184-8501,Japan (Japan); Arai, Shino; Muramoto, Sosuke [Department of Physics, Meiji University, 1-1-1 Higashi-Mita, Tama, Kawasaki, Kanagawa 214-8571 (Japan); and others

    2013-12-15

    Highlights: • Development of a novel nuclear laser spectroscopy method using superfluid helium. • Observation of the Zeeman resonance with the {sup 85}Rb beam introduced into helium. • Demonstration of deducing the nuclear spins from the observed resonance spectrum. -- Abstract: We have been developing a novel nuclear laser spectroscopy method “OROCHI” for determining spins and moments of exotic radioisotopes. In this method, we use superfluid helium as a stopping material of energetic radioisotope beams and then stopped radioisotope atoms are subjected to in situ laser spectroscopy in superfluid helium. To confirm the feasibility of this method for rare radioisotopes, we carried out a test experiment using a {sup 85}Rb beam. In this experiment, we have successfully measured the Zeeman resonance signals from the {sup 85}Rb atoms stopped in superfluid helium by laser-RF double resonance spectroscopy. This method is efficient for the measurement of spins and moments of more exotic nuclei.

  16. Dark matter spin determination with directional direct detection experiments

    Science.gov (United States)

    Catena, Riccardo; Conrad, Jan; Döring, Christian; Ferella, Alfredo Davide; Krauss, Martin B.

    2018-01-01

    If dark matter has spin 0, only two WIMP-nucleon interaction operators can arise as leading operators from the nonrelativistic reduction of renormalizable single-mediator models for dark matter-quark interactions. Based on this crucial observation, we show that about 100 signal events at next generation directional detection experiments can be enough to enable a 2 σ rejection of the spin 0 dark matter hypothesis in favor of alternative hypotheses where the dark matter particle has spin 1 /2 or 1. In this context, directional sensitivity is crucial since anisotropy patterns in the sphere of nuclear recoil directions depend on the spin of the dark matter particle. For comparison, about 100 signal events are expected in a CF4 detector operating at a pressure of 30 torr with an exposure of approximately 26,000 cubic-meter-detector days for WIMPs of 100 GeV mass and a WIMP-fluorine scattering cross section of 0.25 pb. Comparable exposures require an array of cubic meter time projection chamber detectors.

  17. A NEW METHOD FOR EXTRACTING SPIN-DEPENDENT NEUTRON STRUCTURE FUNCTIONS FROM NUCLEAR DATA

    Energy Technology Data Exchange (ETDEWEB)

    Kahn, Y.F.; Melnitchouk, W.

    2009-01-01

    High-energy electrons are currently the best probes of the internal structure of nucleons (protons and neutrons). By collecting data on electrons scattering off light nuclei, such as deuterium and helium, one can extract structure functions (SFs), which encode information about the quarks that make up the nucleon. Spin-dependent SFs, which depend on the relative polarization of the electron beam and the target nucleus, encode quark spins. Proton SFs can be measured directly from electron-proton scattering, but those of the neutron must be extracted from proton data and deuterium or helium-3 data because free neutron targets do not exist. At present, there is no reliable method for accurately determining spin-dependent neutron SFs in the low-momentum-transfer regime, where nucleon resonances are prominent and the functions are not smooth. The focus of this study was to develop a new method for extracting spin-dependent neutron SFs from nuclear data. An approximate convolution formula for nuclear SFs reduces the problem to an integral equation, for which a recursive solution method was designed. The method was then applied to recent data from proton and deuterium scattering experiments to perform a preliminary extraction of spin-dependent neutron SFs in the resonance region. The extraction method was found to reliably converge for arbitrary test functions, and the validity of the extraction from data was verifi ed using a Bjorken integral, which relates integrals of SFs to a known quantity. This new information on neutron structure could be used to assess quark-hadron duality for the neutron, which requires detailed knowledge of SFs in all kinematic regimes.

  18. Determining the population properties of spinning black holes

    Science.gov (United States)

    Talbot, Colm; Thrane, Eric

    2017-07-01

    There are at least two formation scenarios consistent with the first gravitational-wave observations of binary black hole mergers. In field models, black hole binaries are formed from stellar binaries that may undergo common envelope evolution. In dynamic models, black hole binaries are formed through capture events in globular clusters. Both classes of models are subject to significant theoretical uncertainties. Nonetheless, the conventional wisdom holds that the distribution of spin orientations of dynamically merging black holes is nearly isotropic while field-model black holes prefer to spin in alignment with the orbital angular momentum. We present a framework in which observations of black hole mergers can be used to measure ensemble properties of black hole spin such as the typical black hole spin misalignment. We show how to obtain constraints on population hyperparameters using minimal assumptions so that the results are not strongly dependent on the uncertain physics of formation models. These data-driven constraints will facilitate tests of theoretical models and help determine the formation history of binary black holes using information encoded in their observed spins. We demonstrate that the ensemble properties of binary detections can be used to search for and characterize the properties of two distinct populations of black hole mergers.

  19. Electrical Initialization of Electron and Nuclear Spins in a Single Quantum Dot at Zero Magnetic Field.

    Science.gov (United States)

    Cadiz, Fabian; Djeffal, Abdelhak; Lagarde, Delphine; Balocchi, Andrea; Tao, Bingshan; Xu, Bo; Liang, Shiheng; Stoffel, Mathieu; Devaux, Xavier; Jaffres, Henri; George, Jean-Marie; Hehn, Michel; Mangin, Stephane; Carrere, Helene; Marie, Xavier; Amand, Thierry; Han, Xiufeng; Wang, Zhanguo; Urbaszek, Bernhard; Lu, Yuan; Renucci, Pierre

    2018-04-11

    The emission of circularly polarized light from a single quantum dot relies on the injection of carriers with well-defined spin polarization. Here we demonstrate single dot electroluminescence (EL) with a circular polarization degree up to 35% at zero applied magnetic field. The injection of spin-polarized electrons is achieved by combining ultrathin CoFeB electrodes on top of a spin-LED device with p-type InGaAs quantum dots in the active region. We measure an Overhauser shift of several microelectronvolts at zero magnetic field for the positively charged exciton (trion X + ) EL emission, which changes sign as we reverse the injected electron spin orientation. This is a signature of dynamic polarization of the nuclear spins in the quantum dot induced by the hyperfine interaction with the electrically injected electron spin. This study paves the way for electrical control of nuclear spin polarization in a single quantum dot without any external magnetic field.

  20. Determinant representations of spin-operator matrix elements in the XX spin chain and their applications

    Science.gov (United States)

    Wu, Ning

    2018-01-01

    For the one-dimensional spin-1/2 XX model with either periodic or open boundary conditions, it is shown by using a fermionic approach that the matrix element of the spin operator Sj- (Sj-Sj'+ ) between two eigenstates with numbers of excitations n and n +1 (n and n ) can be expressed as the determinant of an appropriate (n +1 )×(n +1 ) matrix whose entries involve the coefficients of the canonical transformations diagonalizing the model. In the special case of a homogeneous periodic XX chain, the matrix element of Sj- reduces to a variant of the Cauchy determinant that can be evaluated analytically to yield a factorized expression. The obtained compact representations of these matrix elements are then applied to two physical scenarios: (i) Nonlinear optical response of molecular aggregates, for which the determinant representation of the transition dipole matrix elements between eigenstates provides a convenient way to calculate the third-order nonlinear responses for aggregates from small to large sizes compared with the optical wavelength; and (ii) real-time dynamics of an interacting Dicke model consisting of a single bosonic mode coupled to a one-dimensional XX spin bath. In this setup, full quantum calculation up to N ≤16 spins for vanishing intrabath coupling shows that the decay of the reduced bosonic occupation number approaches a finite plateau value (in the long-time limit) that depends on the ratio between the number of excitations and the total number of spins. Our results can find useful applications in various "system-bath" systems, with the system part inhomogeneously coupled to an interacting XX chain.

  1. Hyperfine structure, nuclear spins and magnetic moments of some cesium isotopes

    International Nuclear Information System (INIS)

    Ekstroem, C.; Ingelman, S.; Wannberg, G.

    1977-03-01

    Using an atomic-beam magnetic resonance apparatus connected on-line with the ISOLDE isotope separator, CERN, hyperfine structure measurements have been performed in the 2 Ssub(1/2) electronic ground state of some cesium isotopes. An on-line oven system which efficiently converts a mass separated ion-beam of alkali isotopes to an atomic beam is described in some detail. Experimentally determined nuclear spins of sup(120, 121, 121m, 122, 122m, 123, 124, 126, 128, 130m, 135m)Cs and magnetic moments of sup(122, 123, 124, 126, 128, 130)Cs are reported and discussed in terms of different nuclear models. The experimental data indicate deformed nuclear shapes of the lightest cesium isotopes. (Auth.)

  2. Shape and spin determination of Barbarian asteroids

    Science.gov (United States)

    Devogèle, M.; Tanga, P.; Bendjoya, P.; Rivet, J. P.; Surdej, J.; Hanuš, J.; Abe, L.; Antonini, P.; Artola, R. A.; Audejean, M.; Behrend, R.; Berski, F.; Bosch, J. G.; Bronikowska, M.; Carbognani, A.; Char, F.; Kim, M.-J.; Choi, Y.-J.; Colazo, C. A.; Coloma, J.; Coward, D.; Durkee, R.; Erece, O.; Forne, E.; Hickson, P.; Hirsch, R.; Horbowicz, J.; Kamiński, K.; Kankiewicz, P.; Kaplan, M.; Kwiatkowski, T.; Konstanciak, I.; Kruszewki, A.; Kudak, V.; Manzini, F.; Moon, H.-K.; Marciniak, A.; Murawiecka, M.; Nadolny, J.; Ogłoza, W.; Ortiz, J. L.; Oszkiewicz, D.; Pallares, H.; Peixinho, N.; Poncy, R.; Reyes, F.; de los Reyes, J. A.; Santana-Ros, T.; Sobkowiak, K.; Pastor, S.; Pilcher, F.; Quiñones, M. C.; Trela, P.; Vernet, D.

    2017-11-01

    Context. The so-called Barbarian asteroids share peculiar, but common polarimetric properties, probably related to both their shape and composition. They are named after (234) Barbara, the first on which such properties were identified. As has been suggested, large scale topographic features could play a role in the polarimetric response, if the shapes of Barbarians are particularly irregular and present a variety of scattering/incidence angles. This idea is supported by the shape of (234) Barbara, that appears to be deeply excavated by wide concave areas revealed by photometry and stellar occultations. Aims: With these motivations, we started an observation campaign to characterise the shape and rotation properties of Small Main-Belt Asteroid Spectroscopic Survey (SMASS) type L and Ld asteroids. As many of them show long rotation periods, we activated a worldwide network of observers to obtain a dense temporal coverage. Methods: We used light-curve inversion technique in order to determine the sidereal rotation periods of 15 asteroids and the convergence to a stable shape and pole coordinates for 8 of them. By using available data from occultations, we are able to scale some shapes to an absolute size. We also study the rotation periods of our sample looking for confirmation of the suspected abundance of asteroids with long rotation periods. Results: Our results show that the shape models of our sample do not seem to have peculiar properties with respect to asteroids with similar size, while an excess of slow rotators is most probably confirmed. The light curves are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/607/A119

  3. Nuclear reactivity indices in the context of spin polarized density functional theory

    International Nuclear Information System (INIS)

    Cardenas, Carlos; Lamsabhi, Al Mokhtar; Fuentealba, Patricio

    2006-01-01

    In this work, the nuclear reactivity indices of density functional theory have been generalized to the spin polarized case and their relationship to electron spin polarized indices has been established. In particular, the spin polarized version of the nuclear Fukui function has been proposed and a finite difference approximation has been used to evaluate it. Applications to a series of triatomic molecules demonstrate the ability of the new functions to predict the geometrical changes due to a change in the spin multiplicity. The main equations in the different ensembles have also been presented

  4. Theoretical studies on nuclear spin selective quantum dynamics of non-linear molecules

    International Nuclear Information System (INIS)

    Grohmann, Thomas

    2012-01-01

    In this thesis the wave packet dynamics of nuclear spin isomers of polyatomic molecules after interaction with static and time-dependent magnetic fields and moderate intense nonresonant laser pulses is investigated. In particular, the process of inducing (internal) molecular rotation as well as alignment of molecules by manipulating their rotational or rotational-torsional degrees of freedom is studied. In the first part of the thesis all theoretical concepts for identifying nuclear spin isomers and for describing their quantum dynamics will be discussed. Especially the symmetrization postulate and themolecular symmetry group will be introduced and illustrated for some examples of molecules. These concepts will be extended to the case of identifying nuclear spin isomers in the presence of an external field. In the second part it is shown for nitromethane that magnetic fields are able to induce unidirectional rotations in opposite directions for different nuclear spin isomers of molecules containing methyl groups if the dipolar interaction is included. Additionally, it is demonstrated that different nuclear spin isomers of a chemical compound may show different alignment after the interaction with a moderate intense laser pulse. As shown for the rigid symmetric top propadien and the rigid asymmetric tops ethene and analogues, distinct pairs of nuclear spin isomers show at certain points in time a complementary behavior: while one isomer is showing alignment the partner isomer is showing anti-alignment. Moreover, it is illustrated that not every nuclear spin isomer can be aligned equally efficient. The alignment of non-rigid molecules is considered as well. As an example for a molecule with feasible torsion in the electronic ground state, the alignment of diboron tetrafluoride is investigated. It becomes apparent that not only rotational but also the torsional dynamics of the molecules is nuclear spin selective; different nuclear spin isomers have at distinct points

  5. Nuclear spin bath effects in molecular nanomagnets: Direct quantum mechanical simulations

    Science.gov (United States)

    Sinitsyn, N. A.; Dobrovitski, V. V.

    2004-11-01

    We investigate the influence of nuclear spins on the electronic spin tunneling in magnetic molecules such as Fe8 , focusing on the role of the spin diffusion in the nuclear spin bath. We simulate the quantum spin dynamics by numerically solving the time-dependent Schrödinger equation for the compound system (the electronic spin plus the bath spins). Our results demonstrate that the effect of the spin bath cannot always be modeled as a randomly varying magnetic field acting on the electronic spin. We consider two dynamical regimes: the spin relaxation in a constant magnetic field, and the spin tunneling in the linearly varying magnetic field passing the avoided level crossing, so-called Landau-Zener-Stückelberg (LZS) transition. For the first regime, we confirmed that the hole in the magnetization distribution has the width of the hyperfine fields distribution. For the second regime, we found that the transition probability for moderately slow sweeps deviates from the standard LZS prediction, while for the fast sweeps the deviation is negligible.

  6. High-spin nuclear target of 178m2Hf: creation and nuclear reaction studies

    International Nuclear Information System (INIS)

    Oganessyan, Yu.Ts.; Karamyan, S.A.; Gangrskij, Yu.P.

    1993-01-01

    A long-lived (31 years) four-quasiparticle isomer 178m 2 Hf(I,K π =16,16 + ) was produced in microweight quantities using the nuclear reaction 176 Yb( 4 He, 2n). Methods of precision chemistry and mass-separation for the purification of the produced Hf material have been developed. Thin targets of isomeric hafnium-178 on carbon backings were prepared and used in experiments on a neutron, proton and deuteron beams. First results on nuclear reactions on a high-spin exotic target were obtained. Experiments on electromagnetic interactions of the isomeric hafnium using methods of the collinear laser spectroscopy as well as of the nuclear orientation of hafnium implanted into a crystalline media were started. 11 refs.; 11 figs.; 2 tabs

  7. Protocol for generating multiphoton entangled states from quantum dots in the presence of nuclear spin fluctuations

    DEFF Research Database (Denmark)

    Denning, Emil Vosmar; Iles-Smith, Jake; McCutcheon, Dara P. S.

    2017-01-01

    Multiphoton entangled states are a crucial resource for many applications inquantum information science. Semiconductor quantum dots offer a promising route to generate such states by mediating photon-photon correlations via a confinedelectron spin, but dephasing caused by the host nuclear spin...... environment typically limits coherence (and hence entanglement) between photons to the spin T2* time of a few nanoseconds. We propose a protocol for the deterministic generation of multiphoton entangled states that is inherently robust against the dominating slow nuclear spin environment fluctuations, meaning...... that coherence and entanglement is instead limited only by the much longer spin T2 time of microseconds. Unlike previous protocols, the present schemeallows for the generation of very low error probability polarisation encoded three-photon GHZ states and larger entangled states, without the need for spin echo...

  8. Multispin-assisted optical pumping of bulk 13C nuclear spin polarization in diamond

    Science.gov (United States)

    Pagliero, Daniela; Rao, K. R. Koteswara; Zangara, Pablo R.; Dhomkar, Siddharth; Wong, Henry H.; Abril, Andrea; Aslam, Nabeel; Parker, Anna; King, Jonathan; Avalos, Claudia E.; Ajoy, Ashok; Wrachtrup, Joerg; Pines, Alexander; Meriles, Carlos A.

    2018-01-01

    One of the most remarkable properties of the nitrogen-vacancy (NV) center in diamond is that optical illumination initializes its electronic spin almost completely, a feature that can be exploited to polarize other spin species in their proximity. Here we use field-cycled nuclear magnetic resonance to investigate the mechanisms of spin-polarization transfer from NVs to 13C spins in diamond at room temperature. We focus on the dynamics near 51 mT, where a fortuitous combination of energy-matching conditions between electron and nuclear spin levels gives rise to alternative polarization transfer channels. By monitoring the 13C spin polarization as a function of the applied magnetic field, we show 13C spin pumping takes place via a multispin cross-relaxation process involving the N V- spin and the electronic and nuclear spins of neighboring P1 centers. Further, we find that this mechanism is insensitive to the crystal orientation relative to the magnetic field, although the absolute level of 13C polarization—reaching up to ˜3 % under optimal conditions—can vary substantially depending on the interplay between optical pumping efficiency, photogenerated carriers, and laser-induced heating.

  9. Probing the Nuclear Spin-Lattice Relaxation Time at the Nanoscale

    NARCIS (Netherlands)

    Wagenaar, J.C.; Den Haan, A. M J; de Voogd, J.M.; Bossoni, L; de Jong, T.A.; de Wit, M.; Bastiaans, K. M.; Thoen, D.J.; Endo, A.; Klapwijk, T.M.; Zaanen, J.; Oosterkamp, TH

    2016-01-01

    Nuclear spin-lattice relaxation times are measured on copper using magnetic-resonance force microscopy performed at temperatures down to 42 mK. The low temperature is verified by comparison with the Korringa relation. Measuring spin-lattice relaxation times locally at very low temperatures opens up

  10. Sealed magic angle spinning nuclear magnetic resonance probe and process for spectroscopy of hazardous samples

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Herman M.; Washton, Nancy M.; Mueller, Karl T.; Sears, Jr., Jesse A.; Townsend, Mark R.; Ewing, James R.

    2016-06-14

    A magic-angle-spinning (MAS) nuclear magnetic resonance (NMR) probe is described that includes double containment enclosures configured to seal and contain hazardous samples for analysis. The probe is of a modular design that ensures containment of hazardous samples during sample analysis while preserving spin speeds for superior NMR performance and convenience of operation.

  11. Robust quantum-network memory using decoherence-protected subspaces of nuclear spins

    NARCIS (Netherlands)

    Reiserer, A.A.; Kalb, N.; Blok, M.S.; van Bemmelen, Koen J M; Taminiau, T.H.; Hanson, R.; Twitchen, Daniel J.; Markham, Matthew

    2016-01-01

    The realization of a network of quantum registers is an outstanding challenge in quantum science and technology. We experimentally investigate a network node that consists of a single nitrogen-vacancy center electronic spin hyperfine coupled to nearby nuclear spins. We demonstrate individual

  12. Correlation functions of electronic and nuclear spins in a Heisenberg antiferromagnet semi-infinite medium

    International Nuclear Information System (INIS)

    Sarmento, E.F.

    1981-01-01

    Results are found for the dynamical correlation functions (or its corresponding Green's functions) among any combination including operator pairs of electronic and nuclear spins in an antiferromagnet semi-infinite medium, at low temperatures T [pt

  13. Nuclear-Spin Gyroscope Based on an Atomic Co-Magnetometer

    Science.gov (United States)

    Romalis, Michael; Komack, Tom; Ghost, Rajat

    2008-01-01

    An experimental nuclear-spin gyroscope is based on an alkali-metal/noblegas co-magnetometer, which automatically cancels the effects of magnetic fields. Whereas the performances of prior nuclear-spin gyroscopes are limited by sensitivity to magnetic fields, this gyroscope is insensitive to magnetic fields and to other external perturbations. In addition, relative to prior nuclear-spin gyroscopes, this one exhibits greater sensitivity to rotation. There is commercial interest in development of small, highly sensitive gyroscopes. The present experimental device could be a prototype for development of nuclear spin gyroscopes suitable for navigation. In comparison with fiber-optic gyroscopes, these gyroscopes would draw less power and would be smaller, lighter, more sensitive, and less costly.

  14. Determination of the Higgs boson spin at ATLAS

    CERN Document Server

    Sanchez Pineda, A; The ATLAS collaboration

    2013-01-01

    In 2012 ATLAS and CMS collaborations announced the discovery of a new resonance in the search for the Standard Model (SM) Higgs boson. The next step is the experimental determination of its properties in order to understand if it’s the SM Higgs Boson or “someone” beyond. This presentation will resume the state of the art of the ATLAS studies of the spin/parity (JP) quantum numbers of the new boson, due to its production and decay nature, is a neutral boson. To distinguishing between different hypotheses, including that from the Standard Model, ATLAS relies on discriminant observables chosen to be sensitive to the spin and parity of the signal for each channel considered, using data recorded in 2011 and 2012.

  15. Electrically tunable dynamic nuclear spin polarization in GaAs quantum dots at zero magnetic field

    Science.gov (United States)

    Manca, M.; Wang, G.; Kuroda, T.; Shree, S.; Balocchi, A.; Renucci, P.; Marie, X.; Durnev, M. V.; Glazov, M. M.; Sakoda, K.; Mano, T.; Amand, T.; Urbaszek, B.

    2018-04-01

    In III-V semiconductor nano-structures, the electron and nuclear spin dynamics are strongly coupled. Both spin systems can be controlled optically. The nuclear spin dynamics are widely studied, but little is known about the initialization mechanisms. Here, we investigate optical pumping of carrier and nuclear spins in charge tunable GaAs dots grown on 111A substrates. We demonstrate dynamic nuclear polarization (DNP) at zero magnetic field in a single quantum dot for the positively charged exciton X+ state transition. We tune the DNP in both amplitude and sign by variation of an applied bias voltage Vg. Variation of ΔVg on the order of 100 mV changes the Overhauser splitting (nuclear spin polarization) from -30 μeV (-22%) to +10 μeV (+7%) although the X+ photoluminescence polarization does not change sign over this voltage range. This indicates that absorption in the structure and energy relaxation towards the X+ ground state might provide favourable scenarios for efficient electron-nuclear spin flip-flops, generating DNP during the first tens of ps of the X+ lifetime which is on the order of hundreds of ps. Voltage control of DNP is further confirmed in Hanle experiments.

  16. All-electric control of donor nuclear spin qubits in silicon

    Science.gov (United States)

    Sigillito, Anthony J.; Tyryshkin, Alexei M.; Schenkel, Thomas; Houck, Andrew A.; Lyon, Stephen A.

    2017-10-01

    The electronic and nuclear spin degrees of freedom of donor impurities in silicon form ultra-coherent two-level systems that are potentially useful for applications in quantum information and are intrinsically compatible with industrial semiconductor processing. However, because of their smaller gyromagnetic ratios, nuclear spins are more difficult to manipulate than electron spins and are often considered too slow for quantum information processing. Moreover, although alternating current magnetic fields are the most natural choice to drive spin transitions and implement quantum gates, they are difficult to confine spatially to the level of a single donor, thus requiring alternative approaches. In recent years, schemes for all-electrical control of donor spin qubits have been proposed but no experimental demonstrations have been reported yet. Here, we demonstrate a scalable all-electric method for controlling neutral 31P and 75As donor nuclear spins in silicon. Using coplanar photonic bandgap resonators, we drive Rabi oscillations on nuclear spins exclusively using electric fields by employing the donor-bound electron as a quantum transducer, much in the spirit of recent works with single-molecule magnets. The electric field confinement leads to major advantages such as low power requirements, higher qubit densities and faster gate times. Additionally, this approach makes it possible to drive nuclear spin qubits either at their resonance frequency or at its first subharmonic, thus reducing device bandwidth requirements. Double quantum transitions can be driven as well, providing easy access to the full computational manifold of our system and making it convenient to implement nuclear spin-based qudits using 75As donors.

  17. Search for electric dipole moment in 129Xe atom using active nuclear spin maser

    Directory of Open Access Journals (Sweden)

    Ichikawa Y.

    2014-03-01

    Full Text Available An experimental search for an electric dipole moment in the diamagnetic atom 129Xe is in progress through the precision measurement of spin precession frequency using an active nuclear spin maser. A 3He comagnetometer has been incorporated into the active spin maser system in order to cancel out the long-term drifts in the external magnetic field. Also, a double-cell geometry has been adopted in order to suppress the frequency shifts due to interaction with polarized Rb atoms. The first EDM measurement with the 129Xe active spin maser and the 3He comagnetometer has been conducted.

  18. Tensor quasiparticle interaction and spin-isospin sound in nuclear matter

    International Nuclear Information System (INIS)

    Haensel, P.

    1979-01-01

    The effect of the tensor components of the quasiparticle interaction in nuclear matter on the spin-isospin sound type excitations is studied. Numerical results are obtained using a simplified model of the quasiparticle interaction in nuclear matter. The quasiparticle distribution matrix corresponding to the spin-isospin sound is found to be qualitatively different from that obtained for purely central quasiparticle interaction. The macroscopic effects, however, are restricted to a small change in the phase velocity of the spin-isospin sound. (Auth.)

  19. Noise-Resilient Quantum Computing with a Nitrogen-Vacancy Center and Nuclear Spins.

    Science.gov (United States)

    Casanova, J; Wang, Z-Y; Plenio, M B

    2016-09-23

    Selective control of qubits in a quantum register for the purposes of quantum information processing represents a critical challenge for dense spin ensembles in solid-state systems. Here we present a protocol that achieves a complete set of selective electron-nuclear gates and single nuclear rotations in such an ensemble in diamond facilitated by a nearby nitrogen-vacancy (NV) center. The protocol suppresses internuclear interactions as well as unwanted coupling between the NV center and other spins of the ensemble to achieve quantum gate fidelities well exceeding 99%. Notably, our method can be applied to weakly coupled, distant spins representing a scalable procedure that exploits the exceptional properties of nuclear spins in diamond as robust quantum memories.

  20. Observation of nuclear spin waves in spin-polarized atomic hydrogen gas

    Energy Technology Data Exchange (ETDEWEB)

    Johson, B.R.; Denker, J.S.; Bigelow, N.; Levy, L.P.; Freed, J.H.; Lee, D.M.

    1984-04-23

    We have observed narrow, distinct resonances in the NMR spectrum of dilute spin-polarized atomic hydrogen gas (nroughly-equal10/sup 16/ atoms/cm/sup 3/). The dependence of the observed spectra on temperature, density, polarization, and magnetic field gradient is consistent with theoretical predictions for spin-wave excitations damped by diffusion. We have measured the parameter ..mu.., which is a measure of the importance of exchange effects in spin transport processes, and the diffusion coefficient D/sub 0/, both of which are in reasonable agreement with theory.

  1. Solid-state nuclear-spin quantum computer based on magnetic resonance force microscopy

    International Nuclear Information System (INIS)

    Berman, G. P.; Doolen, G. D.; Hammel, P. C.; Tsifrinovich, V. I.

    2000-01-01

    We propose a nuclear-spin quantum computer based on magnetic resonance force microscopy (MRFM). It is shown that an MRFM single-electron spin measurement provides three essential requirements for quantum computation in solids: (a) preparation of the ground state, (b) one- and two-qubit quantum logic gates, and (c) a measurement of the final state. The proposed quantum computer can operate at temperatures up to 1 K. (c) 2000 The American Physical Society

  2. The MONSTER solves nuclear structure problems at low and high spins

    International Nuclear Information System (INIS)

    Hammaren, E.; Schmid, K.W.; Gruemmer, F.

    1984-01-01

    A microscopic, particle-number and spin conserving nuclear structure model is discussed. Within a unique theory the model can describe excitation energies, moments, transitions and spectroscopic factors at low and high spins of odd-mass and doubly-even nuclei in all mass regions. With a realistic two-body Hamiltonian extracted via a G-matric description from nucleon-nucleon scattering data. The model is here applied to nuclei in the A=130 region

  3. RPA spin-isospin nuclear response in the deep inelastic region

    International Nuclear Information System (INIS)

    Alberico, W.M.; Molinari, A.; De Pace, A.; Johnson, M.B.; Ericson, M.

    1985-11-01

    The spin-isospin volume responses of a finite nucleus are evaluated in the RPA frame, utilizing a harmonic oscillator basis. Particular emphasis is given to the mixing between the longitudinal and transverse couplings, which arise at the nuclear surface. We show that it reduces somewhat the contrast between the two spin responses. We compare the calculated transverse response with the experimental one extracted from deep inelastic electron scattering

  4. Polarized photoproduction from nuclear targets with arbitrary spin and relation to deep inelastic scattering

    International Nuclear Information System (INIS)

    Hoodbhoy, P.; Massachusetts Inst. of Tech., Cambridge; Quaid-i-Azam Univ., Islamabad

    1990-01-01

    Inclusive photo-production from polarized targets of arbitrary spin is analyzed by using multipoles. The Drell-Hearn-Gerasimov sum rule, which was originally fromulated for spin-1/2 targets, is generalized to all spins and multipoles, and shown to have some interesting consequences. Measurements to test the new rules, or to derive nuclear structure information from them, could be incorporated into existing plans at electron accelerator facilities. Finally, the possible relevance of these generalized sum rules to sum rules measurable in polarized lepton-polarized target deep inelastic inclusive scattering is discussed. (orig.)

  5. Nuclear inelastic scattering study of a dinuclear iron(II) complex showing a direct spin transition

    Energy Technology Data Exchange (ETDEWEB)

    Wolny, J. A., E-mail: wolny@physik.uni-kl.de [University of Kaiserslautern, Department of Physics (Germany); Garcia, Y. [Université Catholique de Louvain, Institute of Condensed Matter and Nanosciences, Molecules, Solids and Reactivity (IMCN/MOST) (Belgium); Faus, I.; Rackwitz, S. [University of Kaiserslautern, Department of Physics (Germany); Schlage, K.; Wille, H.-C. [DESY (Germany); Schünemann, V. [University of Kaiserslautern, Department of Physics (Germany)

    2016-12-15

    The results of the nuclear inelastic scattering (NIS)/nuclear resonance vibrational spectroscopy (NRVS) for the powder spectra of dimeric [Fe {sub 2}L{sub 5}(NCS) {sub 4}] (L = N-salicylidene-4-amino-1,2,4-triazole) complex are presented. This system is spin crossover (SCO) material tagged with a fluorophore that can sense or “feel” the SCO signal ripping through the molecular network and thereby providing an opportunity to register the SCO transition. The spectra have been measured for the low-spin and high-spin phases of the complex. The high-spin isomer reveals one broad band above 200 cm {sup −1}, while the low-spin one displays two intense bands in the range from 390 to 430 cm {sup −1}, accompanied by a number of weaker bands below this area and one at ca. 490 cm {sup −1}. A normal coordinate analysis based on density functional calculations yields the assignment of the spin marker bands to particular molecular modes. In addition the vibrational contribution to the spin transition has been estimated.

  6. Nuclear spin polarized alkali beams (Li and Na): Production and acceleration

    International Nuclear Information System (INIS)

    Jaensch, H.; Becker, K.; Blatt, K.; Leucker, H.; Fick, D.

    1987-01-01

    Recent improvements of the Heidelberg source for polarized heavy ions (PSI) are described. By means of optical pumping in combination with the existing multipole separation magnet the beam figure of merit (polarization 2 x intensity) was doubled. 7 Li and 23 Na atomic beams can now be produced in pure hyperfine magnetic substates. Fast switching of the polarization is achieved by an adiabatic medium field transition. The hyperfine magnetic substate population is determined by laser-induced fluorescence spectroscopy. In routine operation atomic beams with nuclear polarization p α ≥0.85 (α=z, zz) are obtained. The acceleration of polarized 23 Na - ions by a 12 MV tandem accelerator introduces a new problem: the energy at the terminal stripper foil is not sufficient to produce a usable yield of naked ions. For partially stripped ions hyperfine interaction of the remaining electrons with the nuclear spin reduces the nuclear polarization. Using in addition the Heidelberg postaccelerator 23 Na 9+ beams of energies between 49 and 184 MeV were obtained with an alignment on target of P zz ≅0.45. 7 Li beams have also been accelerated up to 45 MeV with an alignment of P zz =0.69. (orig.)

  7. Optimal control of the inversion of two spins in Nuclear Magnetic Resonance

    International Nuclear Information System (INIS)

    Assémat, E.; Attar, L.; Penouilh, M.-J.; Picquet, M.; Tabard, A.; Zhang, Y.; Glaser, S.J.; Sugny, D.

    2012-01-01

    Highlights: ► We investigate the simultaneous optimal control of the inversion of two spins. ► We examine the energy minimum solution. ► We compare this solution with the time-minimum one. ► Experimental implementation using techniques of Nuclear Magnetic Resonance. -- Abstract: We investigate the optimal control of the inversion of two spin 1/2 particles in Nuclear Magnetic Resonance. The two spins, which differ by their resonance offset, are controlled by the same radio frequency magnetic field. Using the Pontryagin Maximum Principle, we compute the optimal control sequence which allows to reach the target state in a given time, while minimizing the energy of the magnetic field. A comparison with the time-optimal solution for bounded control amplitude realizing the same control in the same time is made. An experimental illustration is done using techniques of Nuclear Magnetic Resonance.

  8. Nuclear-Spin-Induced Circular Dichroism in the Infrared Region for Liquids.

    Science.gov (United States)

    Chen, Fang; Yao, Guo-hua; Zhang, Zhen-lin; Liu, Fan-chen; Chen, Dong-ming

    2015-06-22

    Recently, the nuclear-spin-induced optical rotation (NSOR) and circular dichroism (NSCD) for liquids were discovered and extensively studied and developed. However, so far, nuclear-spin-induced magnetic circular dichroism in the IR region (IR-NSCD) has not been explored, even though all polyatomic molecules exhibit extensive IR spectra. Herein, IR-NSCD is proposed and discussed theoretically. The results indicate that in favorable conditions the IR-NSCD angle may be much larger than the NSOR angle in the UV/Vis region due to a vibrational resonance effect and can be measurable by using the NSOR experiment scheme. IR-NSCD can automatically combine and give NMR spectra and IRCD spectra of the nuclear spin prepolarized samples in liquids, which, in principle, could be developed to become a unique, novel analytical tool. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Correlated calculations of indirect nuclear spin-spin coupling constants using second-order polarization propagator approximations: SOPPA and SOPPA(CCSD)

    DEFF Research Database (Denmark)

    Enevoldsen, Thomas; Oddershede, Jens; Sauer, Stephan P. A.

    1998-01-01

    We present correlated calculations of the indirect nuclear spin-spin coupling constants of HD, HF, H2O, CH4, C2H2, BH, AlH, CO and N2 at the level of the second-order polarization propagator approximation (SOPPA) and the second-order polarization propagator approximation with coupled-cluster sing...

  10. On the Convergence of the ccJ-pVXZ and pcJ-n Basis Sets in CCSD Calculations of Nuclear Spin-Spin Coupling Constants

    DEFF Research Database (Denmark)

    Faber, Rasmus; Sauer, Stephan P. A.

    2018-01-01

    The basis set convergence of nuclear spin-spin coupling constants (SSCC) calculated at the coupled cluster singles and doubles (CCSD) level has been investigated for ten difficult molecules. Eight of the molecules contain fluorine atoms and nine contain double or triple bonds. Results obtained us...

  11. Nuclear orientation of radioactive nuclei the spin program

    Czech Academy of Sciences Publication Activity Database

    Dupák, Jan; Finger, M.; Finger jr., M.; Janata, A.; Kracíková, T. I.; Lebedev, N. A.; Nováková, D.; Ota, J.; Rotter, M.; Slunečka, M.; Slunečková, V.; Virus, M.; Yushkevich, Y. V.

    2000-01-01

    Roč. 50, Supp. S1 (2000), s. 253-268 ISSN 0011-4626. [Symmetry and Spin. Praha, 05.09.1999-12.09.1999] R&D Projects: GA AV ČR KSK1067601 Institutional research plan: CEZ:AV0Z2065902 Subject RIV: JR - Other Machinery Impact factor: 0.298, year: 2000

  12. Nuclear and hadronic reaction mechanisms producing spin asymmetry

    Indian Academy of Sciences (India)

    naka

    This may be possible in the framework of the QRC model by considering an annihilation and creation mechanism, as shown in figure 2, where the initial valence u quark, which carries the proton's spin information, annihilates with u in the target proton and then ss pair is created through the gluon propagation, and the s ...

  13. Chip-Scale Combinatorial Atomic Navigator (C-SCAN) Low Drift Nuclear Spin Gyroscope

    Science.gov (United States)

    2018-01-01

    AFRL-RY-WP-TR-2017-0199 CHIP-SCALE COMBINATORIAL ATOMIC NAVIGATOR (C-SCAN) Low Drift Nuclear Spin Gyroscope Michael Romalis...January 2018 Final 3 May 2013 – 31 July 2017 4. TITLE AND SUBTITLE CHIP-SCALE COMBINATORIAL ATOMIC NAVIGATOR (C-SCAN) Low Drift Nuclear Spin Gyroscope...gyroscope probed by ⁸⁷Rb atoms . We batch fabricated gyroscope cells with a yield exceeding 85% and achieved ¹²⁹Xe T₂ time of 300 sec and 3He T2 time of

  14. Nuclear spin-orbit interaction from chiral pion-nucleon dynamics

    International Nuclear Information System (INIS)

    Kaiser, N.

    2002-01-01

    Using the two-loop approximation of chiral perturbation theory, we calculate the momentum and density dependent nuclear spin-orbit strength U ls (p,k f ). This quantity is derived from the spin-dependent part of the interaction energy Σ spin =((i)/(2))σ→·(q→xp→)U ls (p,k f ) of a nucleon scattering off weakly inhomogeneous isospin symmetric nuclear matter. We find that iterated 1π-exchange generates at saturation density, k f0 =272.7 MeV, a spin-orbit strength at p=0 of U ls (0,k f0 )≅35 MeV fm 2 , in perfect agreement with the empirical value used in the shell model. This novel spin-orbit strength is neither of relativistic nor of short range origin. The potential V ls underlying the empirical spin-orbit strength Ubar ls =V ls r ls 2 becomes a rather weak one, V ls ≅17 MeV, after the identification r ls =m π -1 as suggested by the present calculation. We observe, however, a strong p-dependence of U ls (p,k f0 ) leading even to a sign change above p=200 MeV. This and other features of the emerging spin-orbit Hamiltonian which go beyond the usual shell model parametrization leave questions about the ultimate relevance of the spin-orbit interaction generated by 2π-exchange for a finite nucleus. We also calculate the complex-valued isovector single-particle potential U I (p,k f )+iW I (p,k f ) in isospin asymmetric nuclear matter proportional to τ 3 (N-Z)/(N+Z). For the real part we find reasonable agreement with empirical values and the imaginary part vanishes at the Fermi-surface p=k f

  15. A Determination of the Neutron Spin Structure Function

    Energy Technology Data Exchange (ETDEWEB)

    Hughes, Emlyn W

    2003-08-18

    The authors report the results of the experiment E142 which measured the spin dependent structure function of the neutron, g{sub 1}{sup n}(x, Q{sup 2}). The experiment was carried out at the Stanford Linear Accelerator Center by measuring an asymmetry in the deep inelastic scattering of polarized electrons from a polarized {sup 3}He target, at electron energies from 19 to 26 GeV. The structure function was determined over the kinematic range 0.03 < BJorken x < 0.6 and 1.0 < Q{sup 2} < 5.5 (GeV/c){sup 2}. An evaluation of the integral {integral}{sub 0}{sup 1} g{sub 1}{sup n}(x,Q{sup 2})dx at fixed Q{sup 2} = 2 (GeV/c){sup 2} yields the final result {Lambda}{sub 1}{sup n} = -0.032 {+-} 0.006 (stat.) {+-} 0.009 (syst.). This result, when combined with the integral of the proton spin structure function measured in other experiments, confirms the fundamental Bjorken sum rule with O({alpha}{sub s}{sup 3}) corrections to within one standard deviation. This is a major success for perturbative Quantum Chromodynamics. Some ancillary results include the findings that the Ellis-Jaffe sum rule for the neutron is violated at the 2 {sigma} level, and that the total contribution of the quarks to the helicity of the nucleon is 0.36 {+-} 0.10. The strange sea polarization is estimated to be small and negative, {Delta}s = -0.07 {+-} 0.04.

  16. Optical neural network system for pose determination of spinning satellites

    Science.gov (United States)

    Lee, Andrew; Casasent, David

    1990-01-01

    An optical neural network architecture and algorithm based on a Hopfield optimization network are presented for multitarget tracking. This tracker utilizes a neuron for every possible target track, and a quadratic energy function of neural activities which is minimized using gradient descent neural evolution. The neural net tracker is demonstrated as part of a system for determining position and orientation (pose) of spinning satellites with respect to a robotic spacecraft. The input to the system is time sequence video from a single camera. Novelty detection and filtering are utilized to locate and segment novel regions from the input images. The neural net multitarget tracker determines the correspondences (or tracks) of the novel regions as a function of time, and hence the paths of object (satellite) parts. The path traced out by a given part or region is approximately elliptical in image space, and the position, shape and orientation of the ellipse are functions of the satellite geometry and its pose. Having a geometric model of the satellite, and the elliptical path of a part in image space, the three-dimensional pose of the satellite is determined. Digital simulation results using this algorithm are presented for various satellite poses and lighting conditions.

  17. Determination of F-spin symmetry in deformed nuclei

    International Nuclear Information System (INIS)

    Ginocchio, J.N.; Kuyucak, S.

    1991-01-01

    The purity of a neutron-proton symmetry called F-spin is estimated in collective nuclei. Two simple formulae are shown to provide a quick and accurate estimate for F-spin admixtures in the ground band. Conclusions are also drawn about quadrupole effective charges in collective nuclei. 11 refs., 2 figs

  18. Canadian experience with spin-offs from nuclear technology

    International Nuclear Information System (INIS)

    Lennox, C.G.; Garvey, P.M.

    1989-01-01

    The innovation process introduced into AECL's research laboratories is described, with its achievements in increased commercial and spin-off businesses. In particular, the role of the champion or entrepreneur is emphasized in the manner in which he/she interacts within a dedicated team to pursue each opportunity. Examples are provided of several commercial and business development opportunities resulting from the background research programs

  19. Thermal mixing in multiple-pulse nuclear quadrupole resonance spin-locking

    International Nuclear Information System (INIS)

    Beltjukov, P A; Kibrik, G E; Furman, G B; Goren, S D

    2007-01-01

    We report on an experimental and theoretical nuclear quadrupole resonance (NQR) multiple-pulse spin-locking study of the thermal mixing process in solids containing nuclei of two different sorts, I>1/2 and S = 1/2, coupled by dipole-dipole interactions and influenced by an external magnetic field. Two coupled equations for the inverse spin temperatures of both the spin systems describing the mutual spin-lattice relaxation and the thermal mixing were obtained using the method of the nonequilibrium state operator. It is shown that the relaxation process is realized with non-exponential time dependence described by a sum of two exponents. The calculated relaxation time versus the multiple-pulse field parameters agrees well with the obtained experimental data in 1,4-dichloro-2-nitrobenzene. The calculated magnetization relaxation time versus the strength of the applied magnetic field agrees well with the obtained experimental data

  20. Towards the improvement of spin-isospin properties in nuclear energy density functionals

    International Nuclear Information System (INIS)

    Roca-Maza, X.; Colò, G.; Liang, H. Z.; Sagawa, H.; Meng, J.; Ring, P.; Zhao, P. W.

    2016-01-01

    We address the problem of improving existing nuclear Energy Density Functionals (EDFs) in the spin-isospin channel. For that, we propose two different ways. The first one is to carefully take into account in the fitting protocol some of the key ground state properties for an accurate description of the most studied spin-isospin resonances: the Gamow-Teller Resonance (GTR) [1]. The second consists in providing a strategy to build local covariant EDF keeping the main features from their non-local counterparts [2]. The RHF model based on a Lagrangian where heavy mesons carry the nuclear effective interaction have been shown to be successful in the description of spin-isospin resonances [3]. (paper)

  1. Shell structure at high spin and the influence on nuclear shapes

    International Nuclear Information System (INIS)

    Khoo, T.L.; Chowdhury, P.; Ahmad, I.

    1982-01-01

    Nuclear structure at high spin is influenced by a combination of liquid-drop and shell-structure effects. For N 90. The competition between oblate and prolate driving effects leads to a prolate-to-oblate shape transition in 154 Dy 88 . The role of rotation-aligned configurations in the shape change is discussed

  2. Phosphorus-doped thin silica films characterized by magic-angle spinning nuclear magnetic resonance spectroscopy

    DEFF Research Database (Denmark)

    Jacobsen, H.J.; Skibsted, J.; Kristensen, Martin

    2001-01-01

    Magic-angle spinning nuclear magnetic resonance spectra of 31P and 29Si have been achieved for a thin silica film doped with only 1.8% 31P and deposited by plasma enhanced chemical vapor deposition on a pure silicon wafer. The observation of a symmetric 31P chemical shift tensor is consistent...

  3. Nuclear spin dependence of the reaction of H(3)+ with H2. I. Kinetics and modeling.

    Science.gov (United States)

    Crabtree, Kyle N; Tom, Brian A; McCall, Benjamin J

    2011-05-21

    The chemical reaction H(3)(+) + H(2) → H(2) + H(3)(+) is the simplest bimolecular reaction involving a polyatomic, yet is complex enough that exact quantum mechanical calculations to adequately model its dynamics are still unfeasible. In particular, the branching fractions for the "identity," "proton hop," and "hydrogen exchange" reaction pathways are unknown, and to date, experimental measurements of this process have been limited. In this work, the nuclear-spin-dependent steady-state kinetics of the H(3)(+) + H(2) reaction is examined in detail, and employed to generate models of the ortho:para ratio of H(3)(+) formed in plasmas of varying ortho:para H(2) ratios. One model is based entirely on nuclear spin statistics, and is appropriate for temperatures high enough to populate a large number of H(3)(+) rotational states. Efforts are made to include the influence of three-body collisions in this model by deriving nuclear spin product branching fractions for the H(5)(+) + H(2) reaction. Another model, based on rate coefficients calculated using a microcanonical statistical approach, is appropriate for lower-temperature plasmas in which energetic considerations begin to compete with the nuclear spin branching fractions. These models serve as a theoretical framework for interpreting the results of laboratory studies on the reaction of H(3)(+) with H(2). © 2011 American Institute of Physics.

  4. Effects of tensor forces in nuclear spin-orbit splittings from ab initio calculations

    Science.gov (United States)

    Shen, Shihang; Liang, Haozhao; Meng, Jie; Ring, Peter; Zhang, Shuangquan

    2018-03-01

    A systematic and specific pattern due to the effects of the tensor forces is found in the evolution of spin-orbit splittings in neutron drops. This result is obtained from relativistic Brueckner-Hartree-Fock theory using the bare nucleon-nucleon interaction. It forms an important guide for future microscopic derivations of relativistic and nonrelativistic nuclear energy density functionals.

  5. Isotopic and spin-nuclear effects in solid hydrogens (Review Article)

    Science.gov (United States)

    Freiman, Yuri A.; Crespo, Yanier

    2017-12-01

    The multiple isotopic family of hydrogens (H2, HD, D2, HT, DT, T2) due to large differences in the de Boer quantum parameter and inertia moments displays a diversity of pronounced quantum isotopic solid-state effects. The homonuclear members of this family (H2, D2, T2) due to the permutation symmetry are subjects of the constraints of quantum mechanics which link the possible rotational states of these molecules to their total nuclear spin giving rise to the existence of two spin-nuclear modifications, ortho- and parahydrogens, possessing substantially different properties. Consequently, hydrogen solids present an unique opportunity for studying both isotope and spin-nuclear effects. The rotational spectra of heteronuclear hydrogens (HD, HT, DT) are free from limitations imposed by the permutation symmetry. As a result, the ground state of these species in solid state is virtually degenerate. The most dramatic consequence of this fact is an effect similar to the Pomeranchuk effect in 3He which in the case of the solid heteronuclear hydrogens manifests itself as the reentrant broken symmetry phase transitions. In this review article we discuss thermodynamic and kinetic effects pertaining to different isotopic and spin-nuclear species, as well as problems that still remain to be solved.

  6. Restricted magnetically balanced basis applied for relativistic calculations of indirect nuclear spin-spin coupling tensors in the matrix Dirac-Kohn-Sham framework

    International Nuclear Information System (INIS)

    Repisky, Michal; Komorovsky, Stanislav; Malkina, Olga L.; Malkin, Vladimir G.

    2009-01-01

    The relativistic four-component density functional approach based on the use of restricted magnetically balanced basis (mDKS-RMB), applied recently for calculations of NMR shielding, was extended for calculations of NMR indirect nuclear spin-spin coupling constants. The unperturbed equations are solved with the use of a restricted kinetically balanced basis set for the small component while to solve the second-order coupled perturbed DKS equations a restricted magnetically balanced basis set for the small component was applied. Benchmark relativistic calculations have been carried out for the X-H and H-H spin-spin coupling constants in the XH 4 series (X = C, Si, Ge, Sn and Pb). The method provides an attractive alternative to existing approximate two-component methods with transformed Hamiltonians for relativistic calculations of spin-spin coupling constants of heavy-atom systems. In particular, no picture-change effects arise in our method for property calculations

  7. Nuclear structure of 94,95Mo at high spins

    International Nuclear Information System (INIS)

    Kharraja, B.; Ghugre, S.S.; Garg, U.; Janssens, R.V.; Carpenter, M.P.; Crowell, B.; Khoo, T.L.; Lauritsen, T.; Nisius, D.; Reviol, W.; Mueller, W.F.; Riedinger, L.L.; Kaczarowski, R.

    1998-01-01

    The high-spin level structures of 94,95 Mo (N=52,53) have been investigated via the 65 Cu( 36 S, αp2n) 94 Mo and 65 Cu( 36 S, αpn) 95 Mo reactions at 142 MeV. The level schemes have been extended up to spin J∼19ℎ and excitation energies E x ∼12 MeV. Spherical shell-model calculations have been performed and compared with the experimental energy levels. The level structure of 94 Mo exhibits a single-particle nature and the higher-angular-momentum states are dominated by the excitation of a g 9/2 neutron across the N=50 shell gap. The level sequences observed in 95 Mo have been interpreted on the basis of the spherical shell model and weak coupling of a d 5/2 or a g 7/2 neutron to the 94 Mo core. copyright 1998 The American Physical Society

  8. Determination of uranium traces in nuclear cans of nuclear reactors

    International Nuclear Information System (INIS)

    Acosta L, E.; Benavides M, A.M.; Sanchez P, L.

    1996-01-01

    To quantify the uranium content as impurity can be found in zirconium alloys and zircaloy, utilized to construct the sheaths containing fuels of the reactors of nuclear plants. The determination by fluorescence spectroscopy was employed as quality control measurement, at once the corrosion resistance, diminish with the increase of the uranium content in the alloys. (Author)

  9. Magnetic pseudo-fields in a rotating electron-nuclear spin system

    Science.gov (United States)

    Wood, A. A.; Lilette, E.; Fein, Y. Y.; Perunicic, V. S.; Hollenberg, L. C. L.; Scholten, R. E.; Martin, A. M.

    2017-11-01

    Analogous to the precession of a Foucault pendulum observed on the rotating Earth, a precessing spin observed in a rotating frame of reference appears frequency-shifted. This can be understood as arising from a magnetic pseudo-field in the rotating frame that nevertheless has physically significant consequences, such as the Barnett effect. To detect these pseudo-fields, a rotating-frame sensor is required. Here we use quantum sensors, nitrogen-vacancy (NV) centres, in a rapidly rotating diamond to detect pseudo-fields in the rotating frame. Whereas conventional magnetic fields induce precession at a rate proportional to the gyromagnetic ratio, rotation shifts the precession of all spins equally, and thus primarily affect 13C nuclear spins in the sample. We are thus able to explore these effects via quantum sensing in a rapidly rotating frame, and define a new approach to quantum control using rotationally induced nuclear spin-selective magnetic fields. This work provides an integral step towards realizing precision rotation sensing and quantum spin gyroscopes.

  10. Advances and applications of dynamic-angle spinning nuclear magnetic resonance

    Energy Technology Data Exchange (ETDEWEB)

    Baltisberger, Jay Harvey [Univ. of California, Berkeley, CA (United States)

    1993-06-01

    This dissertation describes nuclear magnetic resonance experiments and theory which have been developed to study quadrupolar nuclei (those nuclei with spin greater than one-half) in the solid state. Primarily, the technique of dynamic-angle spinning (DAS) is extensively reviewed and expanded upon in this thesis. Specifically, the improvement in both the resolution (two-dimensional pure-absorptive phase methods and DAS angle choice) and sensitivity (pulse-sequence development), along with effective spinning speed enhancement (again through choice of DAS conditions or alternative multiple pulse schemes) of dynamic-angle spinning experiment was realized with both theory and experimental examples. The application of DAS to new types of nuclei (specifically the {sup 87}Rb and {sup 85}Rb nuclear spins) and materials (specifically amorphous solids) has also greatly expanded the possibilities of the use of DAS to study a larger range of materials. This dissertation is meant to demonstrate both recent advances and applications of the DAS technique, and by no means represents a comprehensive study of any particular chemical problem.

  11. Advances and applications of dynamic-angle spinning nuclear magnetic resonance

    International Nuclear Information System (INIS)

    Baltisberger, J.H.

    1993-06-01

    This dissertation describes nuclear magnetic resonance experiments and theory which have been developed to study quadrupolar nuclei (those nuclei with spin greater than one-half) in the solid state. Primarily, the technique of dynamic-angle spinning (DAS) is extensively reviewed and expanded upon in this thesis. Specifically, the improvement in both the resolution (two-dimensional pure-absorptive phase methods and DAS angle choice) and sensitivity (pulse-sequence development), along with effective spinning speed enhancement (again through choice of DAS conditions or alternative multiple pulse schemes) of dynamic-angle spinning experiment was realized with both theory and experimental examples. The application of DAS to new types of nuclei (specifically the 87 Rb and 85 Rb nuclear spins) and materials (specifically amorphous solids) has also greatly expanded the possibilities of the use of DAS to study a larger range of materials. This dissertation is meant to demonstrate both recent advances and applications of the DAS technique, and by no means represents a comprehensive study of any particular chemical problem

  12. Parametric excitation of nuclear spin waves in MnCO3 antiferromagnetic crystals

    International Nuclear Information System (INIS)

    Govorkov, S.A.; Tulin, V.A.

    1976-01-01

    Parametric excitation of nuclear spin waves in the antiferromagnetic crystal MnCO 3 is investigated at 1080 MHz by the parallel pumping technique. Two threshold processes are observed in the experiments. One refers to spin wave excitation in a nuclear magnetic system and the other to excitation of magneto-elastic waves. The post-threshold sample susceptibility in such processes is studied. After the second threshold a very pronounced overheating of the nuclear magnetic system of the sample with respect to the lattice is observed. The nature of these overheating phenomena shows that two magneto-elastic oscillation branches are excited in the second threshold process. The dependence of the threshold field on wave vector is more complicated in a small magnetic field due to magnetization processes in the sample. In a large magnetic field complications are evoked by the magneto-elastic coupling

  13. Spin Coherence in Semiconductor Nanostructures

    National Research Council Canada - National Science Library

    Flatte, Michael E

    2006-01-01

    ... dots, tuning of spin coherence times for electron spin, tuning of dipolar magnetic fields for nuclear spin, spontaneous spin polarization generation and new designs for spin-based teleportation and spin transistors...

  14. Nuclear structure at high spin using multidetector gamma array and ...

    Indian Academy of Sciences (India)

    2014-04-05

    Apr 5, 2014 ... A multidetector gamma array (GDA), for studying nuclear structure was built with ancillary devices namely gamma multiplicity filter and charged particle detector array. This facility was designed for in-beam gamma spectroscopy measurements in fusion evaporation reactions at Inter-University Accelerator ...

  15. Nuclear structure at high spin using multidetector gamma array and ...

    Indian Academy of Sciences (India)

    2014-04-05

    Apr 5, 2014 ... erator Centre, New Delhi. The rolled 209Bi target thickness was 3.5 mg/cm2. Beam was pulsed at 4 MHz to measure lifetimes of nuclear isomers by electronics method. GDA used in the present work has improved the quality of coincidence spectra, enabling us to identify and place several weak transitions ...

  16. Dynamic nuclear polarization of membrane proteins: covalently bound spin-labels at protein–protein interfaces

    International Nuclear Information System (INIS)

    Wylie, Benjamin J.; Dzikovski, Boris G.; Pawsey, Shane; Caporini, Marc; Rosay, Melanie; Freed, Jack H.; McDermott, Ann E.

    2015-01-01

    We demonstrate that dynamic nuclear polarization of membrane proteins in lipid bilayers may be achieved using a novel polarizing agent: pairs of spin labels covalently bound to a protein of interest interacting at an intermolecular interaction surface. For gramicidin A, nitroxide tags attached to the N-terminal intermolecular interface region become proximal only when bimolecular channels forms in the membrane. We obtained signal enhancements of sixfold for the dimeric protein. The enhancement effect was comparable to that of a doubly tagged sample of gramicidin C, with intramolecular spin pairs. This approach could be a powerful and selective means for signal enhancement in membrane proteins, and for recognizing intermolecular interfaces

  17. Contribution to the study of thermal mixing between nuclear spin systems; Contribution a l'etude du melange thermique entre systemes de spins nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Goldmann, M. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-02-15

    This work describes methods of dynamic nuclear polarization in solids based on the thermal mixing between nuclear spin systems. The description of the thermal mixing processes involves most of the fundamental aspects of the spin temperature theory. The experiments, conducted with paradichlorobenzene and para-dibromobenzene, yield a detailed confirmation of the theoretical predictions. (author) [French] Ce travail decrit des methodes de polarisation dynamique nucleaire dans les solides basees sur le melange thermique entre systemes de spins nucleaires. La description des processus de melange thermique met en jeu la plupart des aspects fondamentaux de la theorie de la temperature de spin. Les experiences, realisees avec du paradichlorobenzene et du paradibromobenzene, apportent une confirmation detaillee des previsions theoriques. (auteur)

  18. 55Mn nuclear spin relaxation and lifetime of magnons in MnF2 near the spin-flop transition

    International Nuclear Information System (INIS)

    Boucher, J.P.; King, A.R.

    1977-01-01

    A divergence in the nuclear relaxation rate (T 1 -1 ) of 55 Mn is observed in MnF 2 when the magnetic field approaches the field of the spin-flop transition (H=92.94Oe). The field dependence of T 1 -1 at 4.2 and 2K was studied together with its temperature dependence at 92.4 and 85 kOe. Near the transition, T 1 -1 is governed, below 8K, by the processes induced by the dipolar coupling and, above 8K, by those induced by exchange interactions. On the contrary, in weaker fields (H=85Oe), the only exchange induced processes are important [fr

  19. The Spin Structure of the Neutron Determined Using a Polarized He-3 Target

    Energy Technology Data Exchange (ETDEWEB)

    Middleton, H

    2004-01-06

    Described is a study of the internal spin structure of the neutron performed by measuring the asymmetry in spin-dependent deep inelastic scattering of polarized electrons from nuclear polarized {sup 3}He. Stanford Linear Accelerator experiment E142's sample of 400 million scattering events collected at beam energies between 19 and 26 GeV led to the most precise measurement of a nucleon spin structure function to date. The {sup 3}He target represents a major advance in polarized target technology, using the technique of spin exchange with optically pumped rubidium vapor to produce a typical {sup 3}He nuclear polarization of 34% in a 30cm long target cell with a gas density of 2.3 x 10{sup 20} cm{sup -3}. The target polarization was measured to {+-}7% using an Adiabatic Fast Passage NMR system calibrated with the thermal equilibrium polarization of the protons in a sample of water. The relatively high polarization and target thickness were the result of the development of large volume glass target cells which had inherent nuclear spin relaxation times for the {sup 3}He gas of as long as 70 hours. A target cell production procedure is presented which focuses on special glass blowing techniques to minimize surface interactions with the {sup 3}He nuclei and careful gas purification and vacuum system procedures to reduce relaxation inducing impurities.

  20. Effect of deformation and orientation on spin orbit density dependent nuclear potential

    Science.gov (United States)

    Mittal, Rajni; Kumar, Raj; Sharma, Manoj K.

    2017-11-01

    Role of deformation and orientation is investigated on spin-orbit density dependent part VJ of nuclear potential (VN=VP+VJ) obtained within semi-classical Thomas Fermi approach of Skyrme energy density formalism. Calculations are performed for 24-54Si+30Si reactions, with spherical target 30Si and projectiles 24-54Si having prolate and oblate shapes. The quadrupole deformation β2 is varying within range of 0.023 ≤ β2 ≤0.531 for prolate and -0.242 ≤ β2 ≤ -0.592 for oblate projectiles. The spin-orbit dependent potential gets influenced significantly with inclusion of deformation and orientation effect. The spin-orbit barrier and position gets significantly influenced by both the sign and magnitude of β2-deformation. Si-nuclei with β220. The possible role of spin-orbit potential on barrier characteristics such as barrier height, barrier curvature and on the fusion pocket is also probed. In reference to prolate and oblate systems, the angular dependence of spin-orbit potential is further studied on fusion cross-sections.

  1. Higgs Spin Determination and Unitarity of Vector-boson Scattering at the LHC

    CERN Document Server

    Frank, Jessica

    After the discovery of a new particle at the Large Hadron Collider (LHC), it is crucial to definitely verify or disprove whether this new 125 − 126 GeV resonance is the Higgs boson of the Standard Model (SM). Thus, its features, including its spin, have to be determined. In order to distinguish the two most likely spin hypotheses, spin-0 or spin-2, the phenomenology of light spin-2 resonances produced in different gluon-fusion and vectorboson-fusion processes at the LHC is studied. Starting from an effective model for the interaction of a spin-2 particle with SM gauge bosons, cross sections and differential distributions are calculated within the Monte Carlo program Vbfnlo. Whereas with specific model parameters, such a spin-2 resonance can mimic rates and transverse-momentum distributions of a SM Higgs boson in the main decay channels γγ, WW and ZZ, several distributions allow to separate spin-2 from spin-0, almost independently of model parameters. Since the SM Higgs boson ensures the unitarity of the S...

  2. Effects of nuclear spins on the transport properties of the edge of two-dimensional topological insulators

    Science.gov (United States)

    Hsu, Chen-Hsuan; Stano, Peter; Klinovaja, Jelena; Loss, Daniel

    2018-03-01

    The electrons in the edge channels of two-dimensional topological insulators can be described as a helical Tomonaga-Luttinger liquid. They couple to nuclear spins embedded in the host materials through the hyperfine interaction, and are therefore subject to elastic spin-flip backscattering on the nuclear spins. We investigate the nuclear-spin-induced edge resistance due to such backscattering by performing a renormalization-group analysis. Remarkably, the effect of this backscattering mechanism is stronger in a helical edge than in nonhelical channels, which are believed to be present in the trivial regime of InAs/GaSb quantum wells. In a system with sufficiently long edges, the disordered nuclear spins lead to an edge resistance which grows exponentially upon lowering the temperature. On the other hand, electrons from the edge states mediate an anisotropic Ruderman-Kittel-Kasuya-Yosida nuclear spin-spin interaction, which induces a spiral nuclear spin order below the transition temperature. We discuss the features of the spiral order, as well as its experimental signatures. In the ordered phase, we identify two backscattering mechanisms, due to charge impurities and magnons. The backscattering on charge impurities is allowed by the internally generated magnetic field, and leads to an Anderson-type localization of the edge states. The magnon-mediated backscattering results in a power-law resistance, which is suppressed at zero temperature. Overall, we find that in a sufficiently long edge the nuclear spins, whether ordered or not, suppress the edge conductance to zero as the temperature approaches zero.

  3. Discrimination of nuclear spin isomers exploiting the excited state dynamics of a quinodimethane derivative

    Energy Technology Data Exchange (ETDEWEB)

    Obaid, Rana [Institut für Theoretische Chemie, Universität Wien, Währinger Str. 17, 1090 Wien (Austria); Faculty of Pharmacy, Al-Quds University, Abu Dis, Palestine (Country Unknown); Kinzel, Daniel; Oppel, Markus, E-mail: markus.oppel@univie.ac.at; González, Leticia [Institut für Theoretische Chemie, Universität Wien, Währinger Str. 17, 1090 Wien (Austria)

    2014-10-28

    Despite the concept of nuclear spin isomers (NSIs) exists since the early days of quantum mechanics, only few approaches have been suggested to separate different NSIs. Here, a method is proposed to discriminate different NSIs of a quinodimethane derivative using its electronic excited state dynamics. After electronic excitation by a laser field with femtosecond time duration, a difference in the behavior of several quantum mechanical operators can be observed. A pump-probe experimental approach for separating these different NSIs is then proposed.

  4. Relativistic theory of nuclear spin-rotation tensor with kinetically balanced rotational London orbitals.

    Science.gov (United States)

    Xiao, Yunlong; Zhang, Yong; Liu, Wenjian

    2014-10-28

    Both kinetically balanced (KB) and kinetically unbalanced (KU) rotational London orbitals (RLO) are proposed to resolve the slow basis set convergence in relativistic calculations of nuclear spin-rotation (NSR) coupling tensors of molecules containing heavy elements [Y. Xiao and W. Liu, J. Chem. Phys. 138, 134104 (2013)]. While they perform rather similarly, the KB-RLO Ansatz is clearly preferred as it ensures the correct nonrelativistic limit even with a finite basis. Moreover, it gives rise to the same "direct relativistic mapping" between nuclear magnetic resonance shielding and NSR coupling tensors as that without using the London orbitals [Y. Xiao, Y. Zhang, and W. Liu, J. Chem. Theory Comput. 10, 600 (2014)].

  5. Nuclear spin singlet states as a contrast mechanism for NMR spectroscopy.

    Science.gov (United States)

    Devience, Stephen J; Walsworth, Ronald L; Rosen, Matthew S

    2013-10-01

    Nuclear magnetic resonance (NMR) spectra of complex chemical mixtures often contain unresolved or hidden spectral components, especially when strong background signals overlap weaker peaks. In this article we demonstrate a quantum filter utilizing nuclear spin singlet states, which allows undesired NMR spectral background to be removed and target spectral peaks to be uncovered. The quantum filter is implemented by creating a nuclear spin singlet state with spin quantum numbers j = 0, mz  = 0 in a target molecule, applying a continuous RF field to both preserve the singlet state and saturate the magnetization of undesired molecules and then mapping the target molecule singlet state back into an NMR observable state so that its spectrum can be read out unambiguously. The preparation of the target singlet state can be carefully controlled with pulse sequence parameters, so that spectral contrast can be achieved between molecules with very similar structures. We name this NMR contrast mechanism 'Suppression of Undesired Chemicals using Contrast-Enhancing Singlet States' (SUCCESS) and we demonstrate it in vitro for three target molecules relevant to neuroscience: aspartate, threonine and glutamine. Copyright © 2013 John Wiley & Sons, Ltd.

  6. Quantum cognition: The possibility of processing with nuclear spins in the brain

    Science.gov (United States)

    Fisher, Matthew P. A.

    2015-11-01

    The possibility that quantum processing with nuclear spins might be operative in the brain is explored. Phosphorus is identified as the unique biological element with a nuclear spin that can serve as a qubit for such putative quantum processing-a neural qubit-while the phosphate ion is the only possible qubit-transporter. We identify the "Posner molecule", Ca9(PO4)6, as the unique molecule that can protect the neural qubits on very long times and thereby serve as a (working) quantum-memory. A central requirement for quantum-processing is quantum entanglement. It is argued that the enzyme catalyzed chemical reaction which breaks a pyrophosphate ion into two phosphate ions can quantum entangle pairs of qubits. Posner molecules, formed by binding such phosphate pairs with extracellular calcium ions, will inherit the nuclear spin entanglement. A mechanism for transporting Posner molecules into presynaptic neurons during vesicle endocytosis is proposed. Quantum measurements can occur when a pair of Posner molecules chemically bind and subsequently melt, releasing a shower of intra-cellular calcium ions that can trigger further neurotransmitter release and enhance the probability of post-synaptic neuron firing. Multiple entangled Posner molecules, triggering non-local quantum correlations of neuron firing rates, would provide the key mechanism for neural quantum processing. Implications, both in vitro and in vivo, are briefly mentioned.

  7. Relation between molecular electronic structure and nuclear spin-induced circular dichroism

    DEFF Research Database (Denmark)

    Štěpánek, Petr; Coriani, Sonia; Sundholm, Dage

    2017-01-01

    with the spatial distribution of the excited states and couplings between them, reflecting changes in molecular structure and conformation. This constitutes a marked difference to the nuclear magnetic resonance (NMR) chemical shift, which only reflects the local molecular structure in the ground electronic state......The recently theoretically described nuclear spin-induced circular dichroism (NSCD) is a promising method for the optical detection of nuclear magnetization. NSCD involves both optical excitations of the molecule and hyperfine interactions and, thus, it offers a means to realize a spectroscopy...... with spatially localized, high-resolution information. To survey the factors relating the molecular and electronic structure to the NSCD signal, we theoretically investigate NSCD of twenty structures of the four most common nucleic acid bases (adenine, guanine, thymine, cytosine). The NSCD signal correlates...

  8. Pure spin-3/2 propagator for use in particle and nuclear physics

    Science.gov (United States)

    Kristiano, J.; Clymton, S.; Mart, T.

    2017-11-01

    We propose the use of a pure spin-3/2 propagator in the (3 /2 ,0 )⊕(0 ,3 /2 ) representation in particle and nuclear physics. To formulate the propagator in a covariant form we use the antisymmetric tensor spinor representation and we consider the Δ resonance contribution to the elastic π N scattering as an example. We find that the use of a conventional gauge-invariant interaction Lagrangian leads to a problem: the obtained scattering amplitude does not exhibit the resonance behavior. To overcome this problem we modify the interaction by adding a momentum dependence. As in the case of the Rarita-Schwinger formalism, we find that a perfect resonance description could be obtained in the pure spin-3/2 formulation only if hadronic form factors were considered in the interactions.

  9. Impact of hadronic and nuclear corrections on global analysis of spin-dependent parton distributions

    Energy Technology Data Exchange (ETDEWEB)

    Jimenez-Delgado, Pedro [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Accardi, Alberto [Hampton University, Hampton, VA (United States); Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Melnitchouk, Wally [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States)

    2014-02-01

    We present the first results of a new global next-to-leading order analysis of spin-dependent parton distribution functions from the most recent world data on inclusive polarized deep-inelastic scattering, focusing in particular on the large-x and low-Q^2 regions. By directly fitting polarization asymmetries we eliminate biases introduced by using polarized structure function data extracted under nonuniform assumptions for the unpolarized structure functions. For analysis of the large-x data we implement nuclear smearing corrections for deuterium and 3He nuclei, and systematically include target mass and higher twist corrections to the g_1 and g_2 structure functions at low Q^2. We also explore the effects of Q^2 and W^2 cuts in the data sets, and the potential impact of future data on the behavior of the spin-dependent parton distributions at large x.

  10. Nuclear spin relaxation/resonance of {sup 8}Li in Al

    Energy Technology Data Exchange (ETDEWEB)

    Wang, D. [Department of Physics and Astronomy, University of British Columbia, Vancouver, BC, V6T 1Z1 (Canada); Salman, Z. [Clarendon Laboratory, Department of Physics, Oxford University, Parks Road, Oxford OX1 3PU (United Kingdom); ISIS Facility, Rutherford-Appleton Laboratory, Chilton, Didcot, Oxon OX11 0QX (United Kingdom); Chow, K.H.; Fan, I. [Department of Physics, University of Alberta, Edmonton, AB, T6G 2G7 (Canada); Hossain, M.D.; Keeler, T.A. [Department of Physics and Astronomy, University of British Columbia, Vancouver, BC, V6T 1Z1 (Canada); Kiefl, R.F., E-mail: kiefl@triumf.c [Department of Physics and Astronomy, University of British Columbia, Vancouver, BC, V6T 1Z1 (Canada); TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, V6T 2A3 (Canada); Canadian Institute for Advanced Research (Canada); Levy, C.D.P. [TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, V6T 2A3 (Canada); Mansour, A.I. [Department of Physics, University of Alberta, Edmonton, AB, T6G 2G7 (Canada); Morris, G.D.; Pearson, M.R. [TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, V6T 2A3 (Canada); Parolin, T.J. [Department of Chemistry, University of British Columbia, Vancouver, BC, V6T 1Z3 (Canada); Saadaoui, H.; Smadella, M.; Song, Q. [Department of Physics and Astronomy, University of British Columbia, Vancouver, BC, V6T 1Z1 (Canada); MacFarlane, W.A. [Department of Chemistry, University of British Columbia, Vancouver, BC, V6T 1Z3 (Canada)

    2009-04-15

    A low energy beam of spin polarized {sup 8}Li has been used to study the behaviour of isolated {sup 8}Li implanted into a 150 nm thick film of Al on an MgO substrate. The spin relaxation rate 1/T{sub 1} and beta-NMR lineshape were measured as a function of temperature in a large magnetic field of 4.1 T. The resonances from different sites are unresolved due to the large nuclear dipolar interaction with the host {sup 27}Al magnetic dipole moments. Nevertheless the temperature variation of the site averaged 1/T{sub 1} and Knight shift show evidence for a transition between the octahedral O and substitutional S sites at about 150 K, as observed in other fcc metals.

  11. Spin disorder in maghemite nanoparticles investigated using polarized neutrons and nuclear resonant scattering

    Science.gov (United States)

    Herlitschke, M.; Disch, S.; Sergueev, I.; Schlage, K.; Wetterskog, E.; Bergström, L.; Hermann, R. P.

    2016-04-01

    The manuscript reports the investigation of spin disorder in maghemite nanoparticles of different shape by a combination of polarized small-angle neutron scattering (SANSPOL) and nuclear forward scattering (NFS) techniques. Both methods are sensitive to magnetization on the nanoscale. SANSPOL allows for investigation of the particle morphology and spatial magnetization distribution and NFS extends this nanoscale information to the atomic scale, namely the orientation of the hyperfine field experienced by the iron nuclei. The studied nanospheres and nanocubes with diameters of 7.4 nm and 10.6 nm, respectively, exhibit a significant spin disorder. This effect leads to a reduction of the magnetization to 44% and 58% of the theoretical maghemite bulk value, observed consistently by both techniques.

  12. Nuclear spin polarized alkali beams (Na, Li): Optical pumping with electro-optically modulated laser beam

    International Nuclear Information System (INIS)

    Reich, H.; Jaensch, H.J.

    1990-01-01

    An improvement of the Heidelberg source for polarized heavy ions (PSI) is described. To produce a nuclear spin polarized atomic Na beam an electro-optically modulated laser beam has been used for optical pumping. An electro-optic modulator (EOM) was constructed with a bandwidth of 1.8 GHz. Without a spin separating Stern-Gerlach magnet it is now possible to prepare a Na atomic beam in one single hyperfine magnetic substate. Thus the beam figure of merit (polarization 2 x intensity of the beam) has been improved by a factor of 4 as compared to the previous setup. Experiences with the new system collected from several beam times are discussed. (orig.)

  13. Determination of elements by nuclear analytical methods.

    Science.gov (United States)

    Weise, H P; Görner, W; Hedrich, M

    2001-01-01

    The working principle of nuclear analytical methods (NAMs) is not influenced by the chemical bond. Consequently, they are independent counterparts to the well-known chemical procedures. NAMs obey fundamental laws or can be described and understood thoroughly. This qualifies them as candidates for reference methods. Although following similar nuclear reaction schemes, they comprise bulk analyzing capability (neutron and photon activation analysis) as well as detection power in surface near regions of solids (ion beam techniques). Prominent features of NAMs are sensitivity, selectivity, multielement determination and linearity of the calibration function covering a concentration range of several orders of magnitude. Moreover, ion beam techniques allow depth profiling with nm-resolution in several cases while the ion microprobe additionally offers a lateral resolution in the micron-scale. As NAMs require expensive apparatus (nuclear reactor, accelerator in radioactive control areas) their availability is restricted to a small number of suitably equipped institutes. However, they are able to solve complex analytical tasks, take part in key comparisons and play an essential role in the certification of reference materials.

  14. Generalized nuclear Fukui functions in the framework of spin-polarized density-functional theory

    International Nuclear Information System (INIS)

    Chamorro, E.; Proft, F. de; Geerlings, P.

    2005-01-01

    An extension of Cohen's nuclear Fukui function is presented in the spin-polarized framework of density-functional theory (SP-DFT). The resulting new nuclear Fukui function indices Φ Nα and Φ Sα are intended to be the natural descriptors for the responses of the nuclei to changes involving charge transfer at constant multiplicity and also the spin polarization at constant number of electrons. These generalized quantities allow us to gain new insights within a perturbative scheme based on DFT. Calculations of the electronic and nuclear SP-DFT quantities are presented within a Kohn-Sham framework of chemical reactivity for a sample of molecules, including H 2 O, H 2 CO, and some simple nitrenes (NX) and phosphinidenes (PX), with X=H, Li, F, Cl, OH, SH, NH 2 , and PH 2 . Results have been interpreted in terms of chemical bonding in the context of Berlin's theorem, which provides a separation of the molecular space into binding and antibinding regions

  15. Measurements of the nuclear spin-spin relaxation times for commensurate {sup 3}He-Ne films adsorbed on hexagonal boron nitride

    Energy Technology Data Exchange (ETDEWEB)

    Parks, C; Sullivan, N S [Department of Physics, University of Florida, Gainesville, FL 32611 (United States); Stachowiak, P [Institute of Low Temperature and Structure Research, Polish Academy of Sciences, PO Box 1410, 50-950 Wroclaw (Poland)], E-mail: Sullivan@phys.ufl.edu

    2009-02-01

    Measurements of the {sup 3}He nuclear spin-spin relaxation time, T{sub 2}, have been carried out for commensurate layers of {sup 3}He-Ne mixtures adsorbed on hexagonal boron nitride for temperatures 0.2< T <10 K. A temperature independent relaxation is observed at low temperatures and is interpreted in terms of the effective exchange frequencies for {sup 3}He particle exchange on the surface. The results show a strong dependence on the fraction of neon in the adsorbed layer. This variation is discussed in terms of a multiple spin exchange model for {sup 3}He in a monolayer. The contributions to T{sub 2} from different components of the exchange, 2-spin exchange (J{sub 2}), 3-spin exchange (J{sub 3}), 4-spin exchange (J{sub 4}) and higher exchange permutations depend on the {sup 3}He coverage and thus permit the separation of the amplitudes of the different exchange rates, and in particular allow one to deduce the relative strengths of 2-atom and 3-atom exchange where other methods are sensitive only to the effective two-particle term J{sub eff} = J{sub 2} - 2J{sub 3}.

  16. Spectroscopical determination of impurities in nuclear graphite

    International Nuclear Information System (INIS)

    Lordello, A.R.; Tognini, R.P.

    1975-01-01

    A spectrochemical method for the direct determination of B, Cd, Si, Hg, Fe, Mg, Mn, Cr, Ni, Al, Mo, Ti, Sr, Na, Zn, and As in nuclear grade graphite is described. A 9:1 ratio of graphite to copper difluoride is used in the preparation of samples and standards. The excitation is carried out in a d-c at 10 amperes. The copper fluoride used as spectrographic buffer serves to increase the volatilization rate of the impurities and to diminish the differences in the nature of the analytical and calibration samples. The relative standard deviations for the determination of the 16 trace elements, except Sr, Fe, Cd, Al and Si, are in the range of 8 - 20% in their appropriate calibration levels. For the latter five elements they are approximately 20-40%

  17. To a better management of nuclear wastes. SPIN program: chemical separations

    International Nuclear Information System (INIS)

    Madic, C.

    1995-01-01

    This document is a compilation of transparencies for a conference about the techniques used in France for the reprocessing of spent fuels. A description of the different steps of the fuel cycle and of the Purex process (TBP extraction etc..) is given. According to December 30, 1991 nuclear waste policy acts, the ultimate disposal of long life radioactive wastes is prohibited. The SPIN program has been created to develop separation and transmutation processes for high activity radioactive wastes prior to their storage in surface facilities or disposal in deep geologic repositories. The two main axes of the SPIN program are the reduction of waste volume and the reduction of long-life radionuclides quantity using new chemical processes (Diamex) and extractants (diamides, picolinamides, calixarenes, ether-crown), and destruction processes. The principal targets of the SPIN program are the minor actinides (neptunium..) and the long-life fission products (technetium, zirconium..). The processes used are derived from Purex and involve additional hydrometallurgical (pyrometallurgical) operations in order to minimize the induced secondary waste fluxes. (J.S.). 20 figs., 2 tabs

  18. Quantum correlations in a system of nuclear s = 1/2 spins in a strong magnetic field

    International Nuclear Information System (INIS)

    Fel’dman, E B; Kuznetsova, E I; Yurishchev, M A

    2012-01-01

    Entanglement and quantum discord for a pair of nuclear spins s = 1/2 in a nanopore filled with a gas of spin-carrying molecules (atoms) are studied. The correlation functions describing dynamics of dipolar-coupled spins in a nanopore are found. The dependence of spin-pair entanglement on the temperature and the number of spins is obtained from the reduced density matrix, which is centrosymmetric (CS). An analytic expression for the concurrence is obtained for an arbitrary CS density matrix. It is shown that the quantum discord as a measure of quantum correlations attains a significant value at low temperatures. It is also shown that the discord in the considered model has ‘flickering’ character and disappears periodically in the course of time evolution of the system. The geometric discord is studied for arbitrary 4 × 4 CS density matrices. (paper)

  19. Restricted conformational flexibility of furanose derivatives: Ab initio interpretation of their nuclear spin-spin coupling constants

    Czech Academy of Sciences Publication Activity Database

    Bouř, Petr; Raich, I.; Kaminsky, J.; Hrabal, R.; Čejka, J.; Sychrovský, Vladimír

    2004-01-01

    Roč. 108, - (2004), s. 6365-6372 ISSN 1089-5639 R&D Projects: GA AV ČR IAA4055104; GA MŠk LN00A032 Institutional research plan: CEZ:AV0Z4055905 Keywords : spin-spin coupling Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 2.639, year: 2004

  20. Determination of leakage areas in nuclear piping

    International Nuclear Information System (INIS)

    Keim, E.

    1997-01-01

    For the design and operation of nuclear power plants the Leak-Before-Break (LBB) behavior of a piping component has to be shown. This means that the length of a crack resulting in a leak is smaller than the critical crack length and that the leak is safely detectable by a suitable monitoring system. The LBB-concept of Siemens/KWU is based on computer codes for the evaluation of critical crack lengths, crack openings, leakage areas and leakage rates, developed by Siemens/KWU. In the experience with the leak rate program is described while this paper deals with the computation of crack openings and leakage areas of longitudinal and circumferential cracks by means of fracture mechanics. The leakage areas are determined by the integration of the crack openings along the crack front, considering plasticity and geometrical effects. They are evaluated with respect to minimum values for the design of leak detection systems, and maximum values for controlling jet and reaction forces. By means of fracture mechanics LBB for subcritical cracks has to be shown and the calculation of leakage areas is the basis for quantitatively determining the discharge rate of leaking subcritical through-wall cracks. The analytical approach and its validation will be presented for two examples of complex structures. The first one is a pipe branch containing a circumferential crack and the second one is a pipe bend with a longitudinal crack

  1. Determination of leakage areas in nuclear piping

    Energy Technology Data Exchange (ETDEWEB)

    Keim, E. [Siemens/KWU, Erlangen (Germany)

    1997-04-01

    For the design and operation of nuclear power plants the Leak-Before-Break (LBB) behavior of a piping component has to be shown. This means that the length of a crack resulting in a leak is smaller than the critical crack length and that the leak is safely detectable by a suitable monitoring system. The LBB-concept of Siemens/KWU is based on computer codes for the evaluation of critical crack lengths, crack openings, leakage areas and leakage rates, developed by Siemens/KWU. In the experience with the leak rate program is described while this paper deals with the computation of crack openings and leakage areas of longitudinal and circumferential cracks by means of fracture mechanics. The leakage areas are determined by the integration of the crack openings along the crack front, considering plasticity and geometrical effects. They are evaluated with respect to minimum values for the design of leak detection systems, and maximum values for controlling jet and reaction forces. By means of fracture mechanics LBB for subcritical cracks has to be shown and the calculation of leakage areas is the basis for quantitatively determining the discharge rate of leaking subcritical through-wall cracks. The analytical approach and its validation will be presented for two examples of complex structures. The first one is a pipe branch containing a circumferential crack and the second one is a pipe bend with a longitudinal crack.

  2. Analytical Determination of the Confinement Potential and Coupling Constant of Spin--Orbit Interactions of Electrons in Nanostructures

    CERN Document Server

    Dineykhan, M; Zhaugasheva, S A; Al Farabi Kazakh State National University. Almaty

    2005-01-01

    Multilayer nanocrystalline structure is represented by the electrostatic field inducted by total image charge, and the confinement potential for electrons is determined. Assuming that at a given distance the confinement potential is equal to the Coulomb repulsion and an interaction between electrons becomes spin-orbit, the constant of the spin-orbit interaction of electrons in nanostructures is determined. The dependence of the constant of the spin-orbit interaction on environment parameters and the distance between electrons is studied.

  3. On the thermal properties of polarized nuclear matter

    International Nuclear Information System (INIS)

    Hassan, M.Y.M.; Montasser, S.S.; Ramadan, S.

    1979-08-01

    The thermal properties of polarized nuclear matter are calculated using Skyrme III interaction modified by Dabrowski for polarized nuclear matter. The temperature dependence of the volume, isospin, spin and spin isospin pressure and energies are determined. The temperature, isospin, spin and spin isospin dependence of the equilibrium Fermi momentum is also discussed. (author)

  4. Local electron-electron interaction strength in ferromagnetic nickel determined by spin-polarized positron annihilation.

    Science.gov (United States)

    Ceeh, Hubert; Weber, Josef Andreas; Weber, Josef Andreass; Böni, Peter; Leitner, Michael; Benea, Diana; Chioncel, Liviu; Ebert, Hubert; Minár, Jan; Vollhardt, Dieter; Hugenschmidt, Christoph

    2016-02-16

    We employ a positron annihilation technique, the spin-polarized two-dimensional angular correlation of annihilation radiation (2D-ACAR), to measure the spin-difference spectra of ferromagnetic nickel. The experimental data are compared with the theoretical results obtained within a combination of the local spin density approximation (LSDA) and the many-body dynamical mean-field theory (DMFT). We find that the self-energy defining the electronic correlations in Ni leads to anisotropic contributions to the momentum distribution. By direct comparison of the theoretical and experimental results we determine the strength of the local electronic interaction U in ferromagnetic Ni as 2.0 ± 0.1 eV.

  5. Determination of efficacy of nuclear medicine procedures

    International Nuclear Information System (INIS)

    Saenger, E.L.; Buncher, C.R.; Specker, B.; McDevitt, R.A.

    1984-01-01

    Nuclear medicine, a high technology field, is evaluated as to its usefulness. This paper describes the SNM study of 2023 patients comparing two methods evaluating efficacy for lung scanning (LS). Only the referring physicians determined the probabilities of the most important (MI) and most likely (ML) diagnoses and management before and after lung scanning. A logistic regression model was developed for probability of a signout diagnosis of PE. Equal patient groups tested the validity of the regression equations for the probability of PE as MI or ML. The models developed on Group I (G-I) and used on Group II (G-II) gave similar results. This shows that LS classifies PE and NOT PE categories where PE was considered both MI and ML. Entropy minimax pattern detection (EMPD) attempts prediction of signout diagnosis and management from prior patient attributes. In 2023 cases, attributes alone could not eliminate the use of LS for all patients. Comparing the two methods, the predictive values, sensitivity and specificity of each method are similar. EMPD predicts on a relatively small percent (40% before LS, 71% post LS) while the logistic equation predicts on 100% of the cases. An advantage of EMPD is that it does not require estimates of prior probability. However, LR, uses this estimate, thus incorporating intuitive knowledge not evaluated by EMPD. These methods are unique in showing that LS can direct the referring physician toward or away from anticoagulant therapy based on findings of the lung scan

  6. Instrumentation for cryogenic magic angle spinning dynamic nuclear polarization using 90L of liquid nitrogen per day.

    Science.gov (United States)

    Albert, Brice J; Pahng, Seong Ho; Alaniva, Nicholas; Sesti, Erika L; Rand, Peter W; Saliba, Edward P; Scott, Faith J; Choi, Eric J; Barnes, Alexander B

    2017-10-01

    Cryogenic sample temperatures can enhance NMR sensitivity by extending spin relaxation times to improve dynamic nuclear polarization (DNP) and by increasing Boltzmann spin polarization. We have developed an efficient heat exchanger with a liquid nitrogen consumption rate of only 90L per day to perform magic-angle spinning (MAS) DNP experiments below 85K. In this heat exchanger implementation, cold exhaust gas from the NMR probe is returned to the outer portion of a counterflow coil within an intermediate cooling stage to improve cooling efficiency of the spinning and variable temperature gases. The heat exchange within the counterflow coil is calculated with computational fluid dynamics to optimize the heat transfer. Experimental results using the novel counterflow heat exchanger demonstrate MAS DNP signal enhancements of 328±3 at 81±2K, and 276±4 at 105±2K. Copyright © 2017 Elsevier Inc. All rights reserved.

  7. Test of parity-conserving time-reversal invariance using polarized neutrons and nuclear spin aligned holmium

    International Nuclear Information System (INIS)

    Huffman, P.R.; Roberson, N.R.; Wilburn, W.S.; Gould, C.R.; Haase, D.G.; Keith, C.D.; Raichle, B.W.; Seely, M.L.; Walston, J.R.

    1997-01-01

    A test of parity-conserving, time-reversal noninvariance (PC TRNI) has been performed in 5.9 MeV polarized neutron transmission through nuclear spin aligned holmium. The experiment searches for the T-violating fivefold correlation via a double modulation technique emdash flipping the neutron spin while rotating the alignment axis of the holmium. Relative cross sections for spin-up and spin-down neutrons are found to be equal to within 1.2x10 -5 (80% confidence). This is a two orders of magnitude improvement compared to traditional detailed balance studies of time reversal, and represents the most precise test of PC TRNI in a dynamical process, to our knowledge. copyright 1997 The American Physical Society

  8. Contribution to the safety assessment of instrumentation and control software for nuclear power plants. Application to spin N4

    International Nuclear Information System (INIS)

    Soubies, B.; Boulc'h, J.; Elsensohn, O.; Le Meur, M.; Henry, J.Y.

    1994-01-01

    The process of licensing nuclear power plants for operation consists of mandatory steps featuring detailed examination of the instrumentation and control system. Significant changes were introduced by the operator in the process of designing and producing 1400 MWe pressurized water reactor safety systems and, in particular, in the case of the Digital Integrated Protection System, (French abbreviation SPIN). The methodology applied by the Institute of Protection and Nuclear Safety (IPSN) to examine the software of this system is described. It consists of the methods used by the manufacturer to develop SPIN software for the 1400 MWe PWRs, and the approach adopted by the IPSN to evaluate SPIN safety softwares of the protection system for the N4 series of reactors. (R.P.). 2 refs

  9. Modelling the molecular composition and nuclear-spin chemistry of collapsing prestellar sources

    Science.gov (United States)

    Hily-Blant, P.; Faure, A.; Rist, C.; Pineau des Forêts, G.; Flower, D. R.

    2018-04-01

    We study the gravitational collapse of prestellar sources and the associated evolution of their chemical composition. We use the University of Grenoble Alpes Astrochemical Network (UGAN), which includes reactions involving the different nuclear-spin states of H2, H+3, and of the hydrides of carbon, nitrogen, oxygen, and sulfur, for reactions involving up to seven protons. In addition, species-to-species rate coefficients are provided for the ortho/para interconversion of the H_3^+ + H2 system and isotopic variants. The composition of the medium is followed from an initial steady state through the early phase of isothermal gravitational collapse. Both the freeze-out of the molecules on to grains and the coagulation of the grains were incorporated in the model. The predicted abundances and column densities of the spin isomers of ammonia and its deuterated forms are compared with those measured recently towards the prestellar cores H-MM1, L16293E, and Barnard B1. We find that gas-phase processes alone account satisfactorily for the observations, without recourse to grain-surface reactions. In particular, our model reproduces both the isotopologue abundance ratios and the ortho:para ratios of NH2D and NHD2 within observational uncertainties. More accurate observations are necessary to distinguish between full scrambling processes—as assumed in our gas-phase network—and direct nucleus- or atom-exchange reactions.

  10. Signal interferences from turbulent spin dynamics in solution nuclear magnetic resonance spectroscopy

    Science.gov (United States)

    Huang, Susie Y.; Lin, Yung-Ya; Lisitza, Natalia; Warren, Warren S.

    2002-06-01

    Artifacts arising from aperiodic turbulent spin dynamics in gradient-based nuclear magnetic resonance (NMR) applications are comprehensively surveyed and numerically simulated by a nonlinear Bloch equation. The unexpected dynamics, triggered by the joint action of radiation damping and the distant dipolar field, markedly deteriorate the performance of certain pulse sequences incorporating weak pulsed-field gradients and long evolution times. The effects are demonstrated in three general classes of gradient NMR applications: solvent signal suppression, diffusion measurements, and coherence pathway selection. Gradient-modulated solvent transverse magnetization can be partially rephased in a series of self-refocusing gradient echoes that blank out solute resonances in the CHESS (chemical-shift-selective spectroscopy) and WATERGATE (gradient-tailored water suppression) solvent suppression schemes. In addition, the discovered dynamics contribute to erratic echo attenuation in pulsed gradient spin echo (PGSE) and PGSE stimulated echo diffusion measurements and produce coherence leakage in gradient-selected DQFCOSY and HMQC experiments. Specific remedies for minimizing unwanted effects are presented.

  11. 10 CFR 1017.9 - Nuclear material determinations.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 4 2010-01-01 2010-01-01 false Nuclear material determinations. 1017.9 Section 1017.9... special nuclear material, byproduct material, or source material as defined by the Atomic Energy Act is... material is used in the production, testing, utilization, or assembly of nuclear weapons or components of...

  12. Quantum non demolition measurement of a single nuclear spin in a room temperature solid

    Energy Technology Data Exchange (ETDEWEB)

    Neumann, Phillip; Beck, Johannes; Steiner, Matthias; Rathgen, Helmut; Rempp, Florian; Zarrabi, Navid; Dolde, Florian; Jelezko, Fedor; Wrachtrup, Joerg [Universitaet Stuttgart (Germany); Hemmer, Philip [A and M University, Texas (United States)

    2010-07-01

    The measurement process and its interpretation are in the focus of quantum mechanics since its early days. Today's ability to isolate single quantum objects allows experimental demonstration of former ''gedankenexperiments'' like measurement induced quantum state collaps. Rapidly growing quantum technologies explore fundamental aspects of measurements in quantum computing, however for solid state systems such experiments require operation at very low temperatures. Here we show that projective quantum measurement can be performed on a single nuclear spin in diamond under ambient conditions. Using quantum non demolition (QND) readout we are able to detect quantum jumps and the quantum Zeno effect emphasising the addressability of fundamental questions of quantum mechanics in solids. Single shot measurements with fidelities exceeding 0.9 enable efficient state initialization, quantum error correction and entanglement pumping that is crucial for quantum information processing including measurement based schemes and distributed quantum networks.

  13. Theory of radiative muon capture with applications to nuclear spin and isospin doublets

    International Nuclear Information System (INIS)

    Hwang, W.P.; Primakoff, H.

    1978-01-01

    A theory of radiative muon capture, with applications to nuclear spin and isospin doublets, is formulated on the basis of the conservation of the hadronic electromagnetic current, the conservation of the hadronic weak polar currents, the partial conservation of the hadronic weak axial-vector current, the SU(2) x SU(2) current algebra for the various hadronic current, and a simplifying dynamical approximation for the hadron-radiating part of the transition amplitude: the ''linearity hypothesis''. The resultant total transition amplitude, which also includes the muon-radiating part, is worked out explicitly and applied to treat the processes μ - p → ν/sub μ/nγ and μ - 3 He → ν/sub μ/ 3 Hγ

  14. Anisotropic Rotational Diffusion Studied by Nuclear Spin Relaxation and Molecular Dynamics Simulation: An Undergraduate Physical Chemistry Laboratory

    Science.gov (United States)

    Fuson, Michael M.

    2017-01-01

    Laboratories studying the anisotropic rotational diffusion of bromobenzene using nuclear spin relaxation and molecular dynamics simulations are described. For many undergraduates, visualizing molecular motion is challenging. Undergraduates rarely encounter laboratories that directly assess molecular motion, and so the concept remains an…

  15. Degradation of organochloride pesticides by molten salt oxidation at IPEN: spin-off nuclear activities

    International Nuclear Information System (INIS)

    Lainetti, Paulo E.O.

    2013-01-01

    Nuclear spin-off has at least two dimensions. It may provide benefits to the society such as enlarge knowledge base, strengthen infrastructure and benefit technology development. Besides this, to emphasize that some useful technologies elapsed from nuclear activities can affect favorably the public opinion about nuclear energy. In this paper is described a technology developed initially by the Rockwell Int. company in the USA more than thirty years ago to solve some problems of nuclear fuel cycle wastes. For different reasons the technology was not employed. In the last years the interest in the technology was renewed and IPEN has developed his version of the method applicable mainly to the safe degradation of hazardous wastes. This study was motivated by the world interest in the development of advanced processes of waste decomposition, due to the need of safer decomposition processes, particularly for the POPs - persistent organic pollutants and particularly for the organ chlorides. A tendency observed at several countries is the adoption of progressively more demanding legislation for the atmospheric emissions, resultants of the waste decomposition processes. The suitable final disposal of hazardous organic wastes such as PCBs (polychlorinated biphenyls), pesticides, herbicides and hospital residues constitutes a serious problem. In some point of their life cycles, these wastes should be destroyed, in reason of the risk that they represent for the human being, animals and plants. The process involves using a chemical reactor containing molten salts, sodium carbonate or some alkaline carbonates mixtures to decompose the organic waste. The decomposition is performed by submerged oxidation and the residue is injected below the surface of a turbulent salt bath along with the oxidizing agent. Decomposition of halogenated compounds, among which some pesticides, is particularly effective in molten salts. The process presents properties such as intrinsically safe

  16. Spin-specific heat determination of the ratio of competing first- and second-neighbor exchange interactions in frustrated spin-1/2 chains

    Science.gov (United States)

    Dey, Dayasindhu; Kumar, Manoranjan; Dutton, Siân E.; Cava, Robert J.; Soos, Zoltán G.

    2018-02-01

    The magnetic susceptibility χ (T ) of spin-1/2 chains is widely used to quantify exchange interactions, even though χ (T ) is similar for different combinations of ferromagnetic J1 between first neighbors and antiferromagnetic J2 between second neighbors. We point out that the spin-specific heat C (T ) directly determines the ratio α =J2/|J1| of competing interactions. The J1-J2 model is used to fit the isothermal magnetization M (T ,H ) and C (T ,H ) of spin-1/2 Cu(II) chains in LiCuSbO4. By fixing α ,C (T ) resolves the offsetting J1,α combinations obtained from M (T ,H ) in cuprates with frustrated spin chains.

  17. Nuclear moments, spins and charge radii of copper isotopes from N=28 to N=50 by collinear fast-beam laser spectroscopy

    CERN Document Server

    2002-01-01

    We aim at establishing an unambiguous spin determination of the ground and isomeric states in the neutron rich Cu-isotopes from A=72 up to A=78 and to measure the magnetic and quadrupole moments between the N=28 and N=50 shell closures. This study will provide information on the double-magicity of $^{56}$Ni and $^{78}$Ni, both at the extremes of nuclear stability. It will provide evidence on the suggested inversion of ground state spin around A$\\approx$74, due to the monopole migration of the $\\pi f_{5/2}$ level. The collinear laser spectroscopy technique will be used, which furthermore provides information on the changes in mean square charge radii between both neutron shell closures, probing a possible onset of deformation in this region.

  18. Demonstration of a Sensitive Method to Measure Nuclear-Spin-Dependent Parity Violation

    Science.gov (United States)

    Altuntaş, Emine; Ammon, Jeffrey; Cahn, Sidney B.; DeMille, David

    2018-04-01

    Nuclear-spin-dependent parity violation (NSD-PV) effects in atoms and molecules arise from Z0 boson exchange between electrons and the nucleus, and from the magnetic interaction between electrons and the parity-violating nuclear anapole moment. We demonstrate measurements of NSD-PV that use an enhancement of the effect in diatomic molecules, here using the test system 138Ba 19. Our sensitivity surpasses that of any previous atomic parity violation measurement. We show that systematic errors can be suppressed to at least the level of the present statistical sensitivity. We measure the matrix element W of the NSD-PV interaction with total uncertainty δ W /(2 π )<0.7 Hz , for each of two configurations where W must have different signs. This sensitivity would be sufficient to measure NSD-PV effects of the size anticipated across a wide range of nuclei including 137Ba in 137BaF, where |W |/(2 π )≈5 Hz is expected.

  19. Measuring nuclear-spin-dependent parity violation with molecules: Experimental methods and analysis of systematic errors

    Science.gov (United States)

    Altuntaş, Emine; Ammon, Jeffrey; Cahn, Sidney B.; DeMille, David

    2018-04-01

    Nuclear-spin-dependent parity violation (NSD-PV) effects in atoms and molecules arise from Z0 boson exchange between electrons and the nucleus and from the magnetic interaction between electrons and the parity-violating nuclear anapole moment. It has been proposed to study NSD-PV effects using an enhancement of the observable effect in diatomic molecules [D. DeMille et al., Phys. Rev. Lett. 100, 023003 (2008), 10.1103/PhysRevLett.100.023003]. Here we demonstrate highly sensitive measurements of this type, using the test system 138Ba19F. We show that systematic errors associated with our technique can be suppressed to at least the level of the present statistical sensitivity. With ˜170 h of data, we measure the matrix element W of the NSD-PV interaction with uncertainty δ W /(2 π )<0.7 Hz for each of two configurations where W must have different signs. This sensitivity would be sufficient to measure NSD-PV effects of the size anticipated across a wide range of nuclei.

  20. Constitutional determinants of nuclear power plant upgrading

    International Nuclear Information System (INIS)

    Mann, Thomas

    2013-01-01

    Around half a year ago the European stress test for nuclear power plants, a precautionary measure initiated by the European Council in March 2011 in response to the Fukushima disaster, revealed that while German nuclear power plants show a high degree of robustness compared with those in other European countries, they nevertheless required upgrading in one or the other respect (earthquake warning systems, protection against crashing civil passenger airplanes). The present article investigates whether this upgrading requirement can justify an injunction to carry out structural retrofitting measures or whether obligations to this end can be excluded on grounds of reasonability in view of the recent decision taken by the German parliament to phase out nuclear energy.

  1. Floquet-Magnus expansion for general N-coupled spins systems in magic-angle spinning nuclear magnetic resonance spectra

    Science.gov (United States)

    Mananga, Eugene Stephane; Charpentier, Thibault

    2015-04-01

    In this paper we present a theoretical perturbative approach for describing the NMR spectrum of strongly dipolar-coupled spin systems under fast magic-angle spinning. Our treatment is based on two approaches: the Floquet approach and the Floquet-Magnus expansion. The Floquet approach is well known in the NMR community as a perturbative approach to get analytical approximations. Numerical procedures are based on step-by-step numerical integration of the corresponding differential equations. The Floquet-Magnus expansion is a perturbative approach of the Floquet theory. Furthermore, we address the " γ -encoding" effect using the Floquet-Magnus expansion approach. We show that the average over " γ " angle can be performed for any Hamiltonian with γ symmetry.

  2. Determination of critical exponents in nuclear systems

    International Nuclear Information System (INIS)

    Mueller, W.F.J.; Bassini, R.; Begemann-Blaich, M.

    1996-07-01

    Signatures of critical behaviour in nuclear fragmentation are often based on arguments from percolation theory. We demonstrate with general thermodynamic considerations and studies of the Ising model that the reliance on percolation as a reference model bears the risk of missing parts of the essential physics. (orig.)

  3. Microwave field distribution in a magic angle spinning dynamic nuclear polarization NMR probe.

    Science.gov (United States)

    Nanni, Emilio A; Barnes, Alexander B; Matsuki, Yoh; Woskov, Paul P; Corzilius, Björn; Griffin, Robert G; Temkin, Richard J

    2011-05-01

    We present a calculation of the microwave field distribution in a magic angle spinning (MAS) probe utilized in dynamic nuclear polarization (DNP) experiments. The microwave magnetic field (B(1S)) profile was obtained from simulations performed with the High Frequency Structure Simulator (HFSS) software suite, using a model that includes the launching antenna, the outer Kel-F stator housing coated with Ag, the RF coil, and the 4mm diameter sapphire rotor containing the sample. The predicted average B(1S) field is 13μT/W(1/2), where S denotes the electron spin. For a routinely achievable input power of 5W the corresponding value is γ(S)B(1S)=0.84MHz. The calculations provide insights into the coupling of the microwave power to the sample, including reflections from the RF coil and diffraction of the power transmitted through the coil. The variation of enhancement with rotor wall thickness was also successfully simulated. A second, simplified calculation was performed using a single pass model based on Gaussian beam propagation and Fresnel diffraction. This model provided additional physical insight and was in good agreement with the full HFSS simulation. These calculations indicate approaches to increasing the coupling of the microwave power to the sample, including the use of a converging lens and fine adjustment of the spacing of the windings of the RF coil. The present results should prove useful in optimizing the coupling of microwave power to the sample in future DNP experiments. Finally, the results of the simulation were used to predict the cross effect DNP enhancement (ϵ) vs. ω(1S)/(2π) for a sample of (13)C-urea dissolved in a 60:40 glycerol/water mixture containing the polarizing agent TOTAPOL; very good agreement was obtained between theory and experiment. Copyright © 2011 Elsevier Inc. All rights reserved.

  4. Nuclear forensics and nuclear analytical chemistry - iridium determination in a referred forensic sample

    International Nuclear Information System (INIS)

    Basu, A.K.; Bhadkambekar, C.A.; Tripathi, A.B.R.; Chattopadhyay, N.; Ghosh, P.

    2010-01-01

    Nuclear approaches for compositional characterization has bright application prospect in forensic perspective towards assessment of nature and origin of seized material. The macro and micro physical properties of nuclear materials can be specifically associated with a process or type of nuclear activity. Under the jurisdiction of nuclear analytical chemistry as well as nuclear forensics, thrust areas of scientific endeavor like determination of radioisotopes, isotopic and mass ratios, analysis for impurity contents, arriving at chemical forms/species and physical parameters play supporting evidence in forensic investigations. The analytical methods developed for this purposes can be used in international safeguards as well for nuclear forensics. Nuclear material seized in nuclear trafficking can be identified and a profile of the nuclear material can be created

  5. Theoretical studies on nuclear spin selective quantum dynamics of non-linear molecules; Theoretische Untersuchung zur Quantendynamik der Kernspinisomere nicht-linearer Molekuele

    Energy Technology Data Exchange (ETDEWEB)

    Grohmann, Thomas

    2012-05-31

    In this thesis the wave packet dynamics of nuclear spin isomers of polyatomic molecules after interaction with static and time-dependent magnetic fields and moderate intense nonresonant laser pulses is investigated. In particular, the process of inducing (internal) molecular rotation as well as alignment of molecules by manipulating their rotational or rotational-torsional degrees of freedom is studied. In the first part of the thesis all theoretical concepts for identifying nuclear spin isomers and for describing their quantum dynamics will be discussed. Especially the symmetrization postulate and themolecular symmetry group will be introduced and illustrated for some examples of molecules. These concepts will be extended to the case of identifying nuclear spin isomers in the presence of an external field. In the second part it is shown for nitromethane that magnetic fields are able to induce unidirectional rotations in opposite directions for different nuclear spin isomers of molecules containing methyl groups if the dipolar interaction is included. Additionally, it is demonstrated that different nuclear spin isomers of a chemical compound may show different alignment after the interaction with a moderate intense laser pulse. As shown for the rigid symmetric top propadien and the rigid asymmetric tops ethene and analogues, distinct pairs of nuclear spin isomers show at certain points in time a complementary behavior: while one isomer is showing alignment the partner isomer is showing anti-alignment. Moreover, it is illustrated that not every nuclear spin isomer can be aligned equally efficient. The alignment of non-rigid molecules is considered as well. As an example for a molecule with feasible torsion in the electronic ground state, the alignment of diboron tetrafluoride is investigated. It becomes apparent that not only rotational but also the torsional dynamics of the molecules is nuclear spin selective; different nuclear spin isomers have at distinct points

  6. Use of isotopically labelled spin-traps to determine definitively the presence or absence of non-radical addition artefacts in EPR spin-trapping systems.

    Science.gov (United States)

    Timmins, G S; Barlow, G K; Silvester, J A; Wei, X; Whitwood, A C

    1997-04-01

    EPR spin-trapping, although a powerful, sensitive technique for the study of free radicals, can be susceptible to artefacts; one of the most intractable to determine has been the non-radical addition of a substrate to a spin-trap followed by oxidation of the product to an EPR-detectable nitroxide. This work details how differentially isotopically labelled spin-traps (either nitroso or nitrone) may be used to determine the presence (or absence) of such artefacts, and provide a semi-quantitative measure of the extent of their contribution to the total EPR spectra in spin-trapping reactions. Artefactual 'ene' addition of the nitroso spin-trap 3,5-dibromo-4-nitroso-benzenesulphonic acid (DBNBS) to tryptophan followed by oxidation to EPR-detectable products has been confirmed, as has its nucleophilic addition to the thiol of glutathione to give non-EPR detectable products. The nitrone α-phenyl-N-tert-butylnitrone (PBN) exhibited no such reactivity.

  7. Nuclear spin state-resolved cavity ring-down spectroscopy diagnostics of a low-temperature H3+ -dominated plasma

    International Nuclear Information System (INIS)

    Hejduk, Michal; Dohnal, Petr; Varju, Jozef; Rubovič, Peter; Plašil, Radek; Glosík, Juraj

    2012-01-01

    We have applied a continuous-wave near-infrared cavity ring-down spectroscopy method to study the parameters of a H 3 + -dominated plasma at temperatures in the range 77–200 K. We monitor populations of three rotational states of the ground vibrational state corresponding to para and ortho nuclear spin states in the discharge and the afterglow plasma in time and conclude that abundances of para and ortho states and rotational temperatures are well defined and stable. The non-trivial dependence of a relative population of para- H 3 + on a relative population of para-H 2 in a source H 2 gas is described. The results described in this paper are valuable for studies of state-selective dissociative recombination of H 3 + ions with electrons in the afterglow plasma and for the design of sources of H 3 + ions in a specific nuclear spin state. (paper)

  8. Nuclear spin state-resolved cavity ring-down spectroscopy diagnostics of a low-temperature H_3^+ -dominated plasma

    Science.gov (United States)

    Hejduk, Michal; Dohnal, Petr; Varju, Jozef; Rubovič, Peter; Plašil, Radek; Glosík, Juraj

    2012-04-01

    We have applied a continuous-wave near-infrared cavity ring-down spectroscopy method to study the parameters of a H_3^+ -dominated plasma at temperatures in the range 77-200 K. We monitor populations of three rotational states of the ground vibrational state corresponding to para and ortho nuclear spin states in the discharge and the afterglow plasma in time and conclude that abundances of para and ortho states and rotational temperatures are well defined and stable. The non-trivial dependence of a relative population of para- H_3^+ on a relative population of para-H2 in a source H2 gas is described. The results described in this paper are valuable for studies of state-selective dissociative recombination of H_3^+ ions with electrons in the afterglow plasma and for the design of sources of H_3^+ ions in a specific nuclear spin state.

  9. 14N Nuclear Quadrupole Resonance Signals in Paranitrotoluene and Trinitrotoluene. Spin-Lock Spin-Echo Off-Resonance Effects

    Science.gov (United States)

    Gregorovič, Alan; Apih, Tomaž; Lužnik, Janko; Pirnat, Janez; Trontelj, Zvone

    A simple, yet effective technique to enhance the 14N NQR trinitrotoluene notoriously low sensitivity is the use of multipulse sequences. Here we investigate the off-resonance effects of the Spin-Lock Spin-Echo multipulse sequence, a predecessor of many advanced pulse sequences used for the same enhancement. Two samples have been used: paranitrotoluene, with a single 14N site as a model compound for trinitrotoluene, and trinitrotoluene itself, with six 14N sites. Our main focus has been the irradiation frequency dependence of the NQR signal, which is important when 14N NQR is used for remote detection of explosives. The two related principal issues are: the target temperature uncertainty and the existence of multiplets with several closely spaced resonance frequencies. The first applies to any explosive, since in remote detection the temperature is only approximately known, whereas the second applies mainly to trinitrotoluene, with 12 resonance frequencies between 837 and 871 kHz. Our frequency dependent investigation shows that the signal intensity as well as the effective spinspin relaxation time varies substantially with irradiation frequency in both samples. We provide a theoretical explanation of this variation which describes very well the observations and can be useful for increasing the reliability of remote detection signal processing.

  10. Nuclear spin dynamics in solid {sup 3}He at ultralow temperatures; Kernspindynamik in festem {sup 3}He bei ultratiefen Temperaturen

    Energy Technology Data Exchange (ETDEWEB)

    Kath, Matthias

    2009-11-06

    In this thesis the experimental study of the spin dynamics of solid {sup 3}He is described. By means of magnetization measurements above 3 mK a Curie-Weiss behaviour was found with {theta}{sub W}{approx}2.1 mK and by this an order parameter of J={theta}{sub W}k{sub B}/{approx}-0.5 Kk{sub B} was observed, while in the range of 1 to 3 mK a pure Curie behaviour was found. By means of NMR measurements the values of {tau}{sub 1}(6 mK)=240 ms{+-}12 ms and {tau}{sub 1}(1 mK){approx} 40 ms were determined, while spin-echo measurements yielded the spin-spin relaxation time {tau}{sub 2}(6 mK)=4540 {mu}s{+-}140 {mu}s. Furthermore neutron scattering studies were performed. (HSI)

  11. The cosmic axion spin precession experiment (CASPEr): a dark-matter search with nuclear magnetic resonance

    Science.gov (United States)

    Garcon, Antoine; Aybas, Deniz; Blanchard, John W.; Centers, Gary; Figueroa, Nataniel L.; Graham, Peter W.; Kimball, Derek F. Jackson; Rajendran, Surjeet; Gil Sendra, Marina; Sushkov, Alexander O.; Trahms, Lutz; Wang, Tao; Wickenbrock, Arne; Wu, Teng; Budker, Dmitry

    2018-01-01

    The cosmic axion spin precession experiment (CASPEr) is a nuclear magnetic resonance experiment (NMR) seeking to detect axion and axion-like particles which could make up the dark matter present in the Universe. We review the predicted couplings of axions and axion-like particles with baryonic matter that enable their detection via NMR. We then describe two measurement schemes being implemented in CASPEr. The first method, presented in the original CASPEr proposal, consists of a resonant search via continuous-wave NMR spectroscopy. This method offers the highest sensitivity for frequencies ranging from a few Hz to hundreds of MHz, corresponding to masses {m}{{a}}∼ {10}-14–{10}-6 eV. Sub-Hz frequencies are typically difficult to probe with NMR due to the diminishing sensitivity of magnetometers in this region. To circumvent this limitation, we suggest new detection and data processing modalities. We describe a non-resonant frequency-modulation detection scheme, enabling searches from mHz to Hz frequencies ({m}{{a}}∼ {10}-17–{10}-14 eV), extending the detection bandwidth by three decades.

  12. Dynamical suppression of nuclear-spin decoherence time in Si and GaAs using inversion pulses

    International Nuclear Information System (INIS)

    Watanabe, S.; Harada, J.; Sasaki, S.; Hirayama, Y.

    2007-01-01

    We found that nuclear-spin decoherence is suppressed by applying inversion pulses such as alternating phase Carr-Purcell (APCP) and Carr-Purcell-Meiboom-Gill (CPMG) sequences in silicon and GaAs. The decoherence time reaches ∼1.3s by applying inversion pulses, which is ∼200 times as long as the characteristic decay time obtained from the Hahn echo sequence (∼6ms) in silicon

  13. Determination of the origin of unknown irradiated nuclear fuel.

    Science.gov (United States)

    Nicolaou, G

    2006-01-01

    An isotopic fingerprinting method is presented to determine the origin of unknown nuclear material with forensic importance. Spent nuclear fuel of known origin has been considered as the 'unknown' nuclear material in order to demonstrate the method and verify its prediction capabilities. The method compares, using factor analysis, the measured U, Pu isotopic compositions of the 'unknown' material with U, Pu isotopic compositions simulating well known spent fuels from a range of commercial nuclear power stations. Then, the 'unknown' fuel has the same origin as the commercial fuel with which it exhibits the highest similarity in U, Pu compositions.

  14. Determination of the origin of unknown irradiated nuclear fuel

    International Nuclear Information System (INIS)

    Nicolaou, G.

    2006-01-01

    An isotopic fingerprinting method is presented to determine the origin of unknown nuclear material with forensic importance. Spent nuclear fuel of known origin has been considered as the 'unknown' nuclear material in order to demonstrate the method and verify its prediction capabilities. The method compares, using factor analysis, the measured U, Pu isotopic compositions of the 'unknown' material with U, Pu isotopic compositions simulating well known spent fuels from a range of commercial nuclear power stations. Then, the 'unknown' fuel has the same origin as the commercial fuel with which it exhibits the highest similarity in U, Pu compositions

  15. Industrial co-determination and nuclear law

    International Nuclear Information System (INIS)

    Ziegler, E.

    1987-01-01

    The author deals with the question which consequences atomic security conditions have on industrial co-determination. With regard to the security purpose in sec. 1 no. 2 Atomic Energy Act he comes to the conclusion that only the operator is competent to make decisions and that in this respect the co-determination of the works council is excluded. (WG) [de

  16. Reference earthquakes determination. Regulations for nuclear installations

    International Nuclear Information System (INIS)

    Levret, A.; Mohammadioun, B.

    1988-03-01

    Regulations in effect in France for taking into account the seismic motion at a site to ensure the safety of nuclear installations is based upon a seismotectonic approach of deterministic nature. This approach is implemented by a vast number of observations compiled for the most part, in two banks of reliable and uniform data. The first of these contains macroseismic data over about a 1000-year period in France and neighbouring countries the second is made up of strong ground motion recorded in seismic regions the world over. During the first step of an analysis, a maximum reference earthquake is defined for the site, which, by drawing upon a statistical treatment of the strong motion data bank is subsequently matched up with a response spectrum that is representative of both the site intensity and the characteristics of the reference earthquake [fr

  17. A fast determination method for transverse relaxation of spin-exchange-relaxation-free magnetometer

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Jixi, E-mail: lujixi@buaa.edu.cn; Qian, Zheng; Fang, Jiancheng [School of Instrument Science and Opto-Electronics Engineering, Beihang University, Beijing 100191 (China)

    2015-04-15

    We propose a fast and accurate determination method for transverse relaxation of the spin-exchange-relaxation-free (SERF) magnetometer. This method is based on the measurement of magnetic resonance linewidth via a chirped magnetic field excitation and the amplitude spectrum analysis. Compared with the frequency sweeping via separate sinusoidal excitation, our method can realize linewidth determination within only few seconds and meanwhile obtain good frequency resolution. Therefore, it can avoid the drift error in long term measurement and improve the accuracy of the determination. As the magnetic resonance frequency of the SERF magnetometer is very low, we include the effect of the negative resonance frequency caused by the chirp and achieve the coefficient of determination of the fitting results better than 0.998 with 95% confidence bounds to the theoretical equation. The experimental results are in good agreement with our theoretical analysis.

  18. Determination of phthalate esters in physiological saline solution by monolithic silica spin column extraction method

    Directory of Open Access Journals (Sweden)

    Lu Lu

    2011-05-01

    Full Text Available Monolithic silica spin column extraction (MonoSpin-SPE was developed as a simple, sensitive, and eco-friendly pretreatment method which combined with ultra-fast liquid chromatography-mass spectrometry (UFLC-MS to determine the levels of six phthalate esters, dimethyl-(DMP, diethyl-(DEP, dipropyl- [DPrP], butyl-benzyl-(BBP, dicyclohexyl(DcHP, and di- n-octyl-(DOP phthalate in physiological saline samples. Under optimized experimental conditions, the method was linear in the following ranges: 0.2- 50 μ/L for DMP, DEP, DPrP, DcHP and DOP; 5 – 100 μ/L for BBP. The correlation coefficients (R2 were in the range of O. 9951 – O. 9995 for all the analytes and the limits of detection (LODs and limits of quantification (LOQs were in the ranges of 0.02 – 0.9 μ/L and 0.08 – 2.7 μ/L, respectively. The pretreatment process showed good reproducibility with inter-day and intra-day relative standard deviations (RSDs below 8.5% and 11.2%, respectively. This method was used to determine the levels of six phthalate esters in physiological saline samples and the recoveries ranged from 71.2% to 107. 3%. DMP and DEP were found in actual physical saline samples (brand A and brand B. Keywords: Monolithic silica spin column, Phthalate esters, Physiological saline samples, Ultra fast liquid chromatographymass spectrometry (UFLC-MS

  19. Nuclear shape transitions and some properties of aligned-particle configurations at high spin

    International Nuclear Information System (INIS)

    Koo, T.L.; Chowdhury, P.; Emling, H.

    1982-01-01

    Two topics are addressed in this paper. First, we discuss the variation of shapes with spin and neutron number for nuclei in the N approx. = 88 transitional region. Second, we present comments on the feeding times of very high spin single-particle yrast states

  20. Collective spin by linearization of the Schrodinger equation for nuclear collective motion

    International Nuclear Information System (INIS)

    Greiner, M.; Scheid, W.; Herrmann, R.

    1988-01-01

    The free Schrodinger equation for multipole degrees of freedom is linearized so that energy and momentum operators appear only in first order. As an example, the authors demonstrate the linearization procedure for quadrupole degrees of freedom. The wave function solving this equation carries a spin. The authors derive the operator of the collective spin and its eigen values depending on multipolarity

  1. Nuclear inelastic scattering of 1D polymeric Fe(II) complexes of 1,2,4-aminotriazole in their high-spin and low-spin state

    Energy Technology Data Exchange (ETDEWEB)

    Wolny, Juliusz A., E-mail: wolny@physik.uni-kl.de; Rackwitz, Sergej [University of Kaiserslautern, Department of Physics (Germany); Achterhold, Klaus [Technische Universitaet Muenchen, Department of Physics (Germany); Muffler, Kai; Schuenemann, Volker [University of Kaiserslautern, Department of Physics (Germany)

    2012-03-15

    The vibrational properties of Fe(II) 1D spin crossover polymers have been characterized by nuclear inelastic scattering (NIS). The complexes under study were the tosylate and perchlorate salts of ([Fe(4-amino-1,2,4-triazole){sub 3}] <{sup +2}){sub n} complexes. The complexes have LS (S = 0) marker bands in the range of 300-500 cm{sup - 1}, while the marker bands corresponding to the HS (S = 2) state are detected between 200 cm{sup - 1} and 300 cm{sup - 1}, in line with the decreasing Fe-N bond strengths during the transition from LS to HS. Accompanying DFT calculations using the functional B3LYP and the basis set CEP-31G confirm these assignments.

  2. In a spin at Brookhaven spin physics

    CERN Document Server

    Makdisi, Y I

    2003-01-01

    The mysterious quantity that is spin took centre stage at Brookhaven for the SPIN2002 meeting last September. The 15th biennial International Spin Physics Symposium (SPIN2002) was held at Brookhaven National Laboratory on 9-14 September 2002. Some 250 spin enthusiasts attended, including experimenters and theorists in both nuclear and high-energy physics, as well as accelerator physicists and polarized target and polarized source experts. The six-day symposium included 23 plenary talks and 150 parallel talks. SPIN2002 was preceded by a one-day spin physics tutorial for students, postdocs, and anyone else who felt the need for a refresher course. (2 refs).

  3. Landau-Zener tunneling of a single Tb3+ magnetic moment allowing the electronic read-out of a nuclear spin

    Science.gov (United States)

    Urdampilleta, M.; Klyatskaya, S.; Ruben, M.; Wernsdorfer, W.

    2013-05-01

    A multiterminal device based on a carbon nanotube quantum dot was used at very low temperature to probe a single electronic and nuclear spin embedded in a bis-(phthalocyaninato) terbium (III) complex (TbPc2). A spin-valve signature with large conductance jumps was found when two molecules were strongly coupled to the nanotube. The application of a transverse field separated the magnetic signal of both molecules and enabled single-shot read-out of the terbium nuclear spin. The Landau-Zener (LZ) quantum tunneling probability was studied as a function of field sweep rate, establishing a good agreement with the LZ equation and yielding the tunnel splitting Δ. It was found that Δ increased linearly as a function of the transverse field. These studies are an essential prerequisite for the coherent manipulation of a single nuclear spin in TbPc2.

  4. Theory of long-lived nuclear spin states in methyl groups and quantum-rotor induced polarisation

    International Nuclear Information System (INIS)

    Dumez, Jean-Nicolas; Håkansson, Pär; Mamone, Salvatore; Meier, Benno; Stevanato, Gabriele; Hill-Cousins, Joseph T.; Roy, Soumya Singha; Brown, Richard C. D.; Pileio, Giuseppe; Levitt, Malcolm H.

    2015-01-01

    Long-lived nuclear spin states have a relaxation time much longer than the longitudinal relaxation time T 1 . Long-lived states extend significantly the time scales that may be probed with magnetic resonance, with possible applications to transport and binding studies, and to hyperpolarised imaging. Rapidly rotating methyl groups in solution may support a long-lived state, consisting of a population imbalance between states of different spin exchange symmetries. Here, we expand the formalism for describing the behaviour of long-lived nuclear spin states in methyl groups, with special attention to the hyperpolarisation effects observed in 13 CH 3 groups upon rapidly converting a material with low-barrier methyl rotation from the cryogenic solid state to a room-temperature solution [M. Icker and S. Berger, J. Magn. Reson. 219, 1 (2012)]. We analyse the relaxation properties of methyl long-lived states using semi-classical relaxation theory. Numerical simulations are supplemented with a spherical-tensor analysis, which captures the essential properties of methyl long-lived states

  5. Nuclear yield determinations using isotope-separator-on-line arrangements

    International Nuclear Information System (INIS)

    Rudstam, G.

    1975-01-01

    The delay between the formation of a nuclear reaction product and its collection in front of measuring equipment in ISOL arrangements using integrated target-ion source systems has been analyzed. It is shown that a typical delay function takes the form const x (1-esup(-γt))esup(-μt) with γ >> μ. The results can be used for decay corrections in nuclear yield determinations. (Auth.)

  6. Nuclear magnetic relaxation by the dipolar EMOR mechanism: Multi-spin systems

    Science.gov (United States)

    Chang, Zhiwei; Halle, Bertil

    2017-08-01

    In aqueous systems with immobilized macromolecules, including biological tissues, the longitudinal spin relaxation of water protons is primarily induced by exchange-mediated orientational randomization (EMOR) of intra- and intermolecular magnetic dipole-dipole couplings. Starting from the stochastic Liouville equation, we have previously developed a rigorous EMOR relaxation theory for dipole-coupled two-spin and three-spin systems. Here, we extend the stochastic Liouville theory to four-spin systems and use these exact results as a guide for constructing an approximate multi-spin theory, valid for spin systems of arbitrary size. This so-called generalized stochastic Redfield equation (GSRE) theory includes the effects of longitudinal-transverse cross-mode relaxation, which gives rise to an inverted step in the relaxation dispersion profile, and coherent spin mode transfer among solid-like spins, which may be regarded as generalized spin diffusion. The GSRE theory is compared to an existing theory, based on the extended Solomon equations, which does not incorporate these phenomena. Relaxation dispersion profiles are computed from the GSRE theory for systems of up to 16 protons, taken from protein crystal structures. These profiles span the range from the motional narrowing limit, where the coherent mode transfer plays a major role, to the ultra-slow motion limit, where the zero-field rate is closely related to the strong-collision limit of the dipolar relaxation rate. Although a quantitative analysis of experimental data is beyond the scope of this work, it is clear from the magnitude of the predicted relaxation rate and the shape of the relaxation dispersion profile that the dipolar EMOR mechanism is the principal cause of water-1H low-field longitudinal relaxation in aqueous systems of immobilized macromolecules, including soft biological tissues. The relaxation theory developed here therefore provides a basis for molecular-level interpretation of endogenous soft

  7. Structure and spin density of ferric low-spin heme complexes determined with high-resolution ESEEM experiments at 35 GHz.

    Science.gov (United States)

    García-Rubio, Inés; Mitrikas, George

    2010-08-01

    The wide use of the heme group by nature is a consequence of its unusual "electronic flexibility." Major changes in the electronic structure of this molecule can result from small perturbations in its environment. To understand the way the electronic distribution is dictated by the structure of the heme site, it is extremely important to have methods to reliably determine both of them. In this work we propose a way to obtain this information in ferric low-spin heme centers via the determination of g, A, and Q tensors of the coordinated nitrogens using electron spin echo envelope modulation experiments at Q-band microwave frequencies. The results for two bisimidazole heme model complexes, namely, PPIX(Im)(2) and CPIII(Im)(2), where PPIX is protoporphyrin IX, CPIII is coproporphyrin III, and Im is imidazole, selectively labeled with (15)N on the heme or imidazole nitrogens are presented. The planes of the axial ligands were found to be parallel and oriented approximately along one of the N-Fe-N directions of the slightly ruffled porphyrin ring (approximately 10 degrees ). The spin density was determined to reside in an iron d orbital perpendicular to the heme plane and oriented along the other porphyrin N-Fe-N direction, perpendicular to the axial imidazoles. The benefit of the method presented here lies in the use of Q-band microwave frequencies, which improves the orientation selection, results in no/fewer combination lines in the spectra, and allows separation of the contributions of hyperfine and quadrupole interactions due to the fulfillment of the exact cancellation condition at g ( Z ) and the possibility of performing hyperfine decoupling experiments at the g ( X ) observer position. These experimental advantages make the interpretation of the spectra straightforward, which results in precise and reliable determination of the structure and spin distribution.

  8. Roll Attitude Determination of Spin Projectile Based on GPS and Magnetoresistive Sensor

    Directory of Open Access Journals (Sweden)

    Dandan Yuan

    2017-01-01

    Full Text Available Improvement in attack accuracy of the spin projectiles is a very significant objective, which increases the overall combat efficiency of projectiles. The accurate determination of the projectile roll attitude is the recent objective of the efficient guidance and control. The roll measurement system for the spin projectile is commonly based on the magnetoresistive sensor. It is well known that the magnetoresistive sensor produces a sinusoidally oscillating signal whose frequency slowly decays with time, besides the possibility of blind spot. On the other hand, absolute sensors such as GPS have fixed errors even though the update rates are generally low. To earn the benefit while eliminating weaknesses from both types of sensors, a mathematical model using filtering technique can be designed to integrate the magnetoresistive sensor and GPS measurements. In this paper, a mathematical model is developed to integrate the magnetoresistive sensor and GPS measurements in order to get an accurate prediction of projectile roll attitude in a real flight time. The proposed model is verified using numerical simulations, which illustrated that the accuracy of the roll attitude measurement is improved.

  9. Determination of incompressibility and saturation properties of nuclear matter from nuclear masses

    International Nuclear Information System (INIS)

    Satpathy, L.

    1996-01-01

    The binding energy, saturation density and compression modulus of infinite nuclear matter are fundamental constants of nature. We have determined these values from nuclear masses through our mass formula based on infinite nuclear matter (INM) model, developed over a number of years. Recently we have improved this model in which important terms Eke exchange coulomb, proton form factor, charge asymmetry and pairing cancel exactly, giving rise to a clean and reliable determination of saturation properties of INM from nuclear masses. Starting with two body effective interaction we first show at a microscopic level using the results of Hartree-Fock and energy density formalism study that INM and not Bethe-Weizsaecker model is the appropriate one for extraction of such properties. The saturation properties are obtained using 1371 masses of 1993 mass table in this improved INM model. The density thus obtained agrees with that of electron scattering data and the Hartree-Fock calculations, and for the first time, using nuclear mass formula, the radius constant r 0 = 1.138 fm and energy a ν = -16.11 MeV corresponding to infinite nuclear matter are consistently obtained from the same source. Thus the so-called longstanding r 0 -anomaly is satisfactorily resolved with. We are able to extract convincingly the nuclear matter incompressibility K ∞ to be 288 ± 28 MeV using the same source of nuclear masses as input. Thus all the three important properties are consistently obtained from a single source. (author). 17 refs., 5 tabs

  10. An approach for determining the acceptable levels of nuclear risk

    International Nuclear Information System (INIS)

    1978-03-01

    The objective of this study was to develop a methodology for determining the acceptable levels of risk with respect to nuclear energy. It was concluded that the Atomic Energy Control Board should identify the interest groups that affect its choice of an acceptable level of risk, determine their expectations, and balance the expectations of the various groups such that the resulting acceptable level of risk is still acceptable to the Board. This would be done by interviewing experts on the subject of nuclear safety, developing and pretesting a public questionnaire, and surveying the public on acceptable cost-risk combinations

  11. Using nuclear methods for analyzing materials and determining concentration gradients

    International Nuclear Information System (INIS)

    Darras, R.

    After reviewing the various type of nuclear chemical analysis methods, the possibilities of analysis by activation and direct observation of nuclear reactions are specifically described. These methods make it possible to effect analyses of trace-elements or impurities, even as traces, in materials, with selectivity, accuracy and great sensitivity. This latter property makes them advantageous too for determining major elements in small quantities of available matter. Furthermore, they lend themselves to carrying out superficial analyses and the determination of concentration gradients, given the careful choice of the nature and energy of the incident particles. The paper is illustrated with typical examples of analyses on steels, pure iron, refractory metals, etc [fr

  12. Determining diffusion coefficients of ionic liquids by means of field cycling nuclear magnetic resonance relaxometry

    Energy Technology Data Exchange (ETDEWEB)

    Kruk, D. [Faculty of Mathematics and Computer Science, University of Warmia and Mazury in Olsztyn, Słoneczna 54, PL-10710 Olsztyn (Poland); Universität Bayreuth, Experimentalphysik II, 95440 Bayreuth (Germany); Meier, R.; Rössler, E. A. [Universität Bayreuth, Experimentalphysik II, 95440 Bayreuth (Germany); Rachocki, A. [Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań (Poland); Korpała, A. [Department of Biophysics, Jagiellonian University Medical College, Łazarza 16, 31-530 Kraków, Poland and Institute of Physics, Jagiellonian University, Reymonta 4, 30-059 Kraków (Poland); Singh, R. K. [Ionic Liquid and Solid State Ionics Laboratory, Department of Physics, Banaras Hindu University, Varanasi 221 005 (India)

    2014-06-28

    Field Cycling Nuclear Magnetic Resonance (FC NMR) relaxation studies are reported for three ionic liquids: 1-ethyl-3- methylimidazolium thiocyanate (EMIM-SCN, 220–258 K), 1-butyl-3-methylimidazolium tetrafluoroborate (BMIM-BF{sub 4}, 243–318 K), and 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM-PF{sub 6}, 258–323 K). The dispersion of {sup 1}H spin-lattice relaxation rate R{sub 1}(ω) is measured in the frequency range of 10 kHz–20 MHz, and the studies are complemented by {sup 19}F spin-lattice relaxation measurements on BMIM-PF{sub 6} in the corresponding frequency range. From the {sup 1}H relaxation results self-diffusion coefficients for the cation in EMIM-SCN, BMIM-BF{sub 4}, and BMIM-PF{sub 6} are determined. This is done by performing an analysis considering all relevant intra- and intermolecular relaxation contributions to the {sup 1}H spin-lattice relaxation as well as by benefiting from the universal low-frequency dispersion law characteristic of Fickian diffusion which yields, at low frequencies, a linear dependence of R{sub 1} on square root of frequency. From the {sup 19}F relaxation both anion and cation diffusion coefficients are determined for BMIM-PF{sub 6}. The diffusion coefficients obtained from FC NMR relaxometry are in good agreement with results reported from pulsed- field-gradient NMR. This shows that NMR relaxometry can be considered as an alternative route of determining diffusion coefficients of both cations and anions in ionic liquids.

  13. Cross polarization, magic-angle spinning /sup 13/C nuclear magnetic resonance spectroscopy of soil humic fractions

    Energy Technology Data Exchange (ETDEWEB)

    Saiz-Jimenez, C.; Hawkins, B.L.; Maciel, G.E.

    1986-01-01

    Cross polarization, magic-angle spinning /sup 13/C nuclear magnetic resonance spectroscopy was used to characterize humic fractions isolated from different soils. The humic acid fractions are more aromatic than the humin fractions, probably due to the higher polysaccharide content of humins. However, fulvic acid fractions are more aromatic than the corresponding humic acid and humin fractions. These results can be interpreted in terms of the isolation procedure, because the high affinity of Polyclar AT for phenols results in higher aromaticities as compared with other isolation methods (e.g. charcoal).

  14. Nanoscale quantum gyroscope using a single 13C nuclear spin coupled with a nearby NV center in diamond

    Science.gov (United States)

    Song, Xuerui; Wang, Liujun; Feng, Fupan; Lou, Liren; Diao, Wenting; Duan, Chongdi

    2018-03-01

    Developing gyroscopes based on quantum systems are important for inertial sensing applications, and its underlying physics is of fundamental interest. In this paper, we proposed a new type of gyroscope based on the Berry phase generated during rotation of the quantum system by using a single 13C nuclear spin coupled with a nearby nitrogen-vacancy center in diamond. Due to the atom-scale size of the quantum system, rotation information can be obtained with high spatial resolution. The gyroscope can be manipulated at room temperature and without the need for a strong magnetic field, which is also beneficial to its further applications.

  15. Selectively dispersed isotope labeling for protein structure determination by magic angle spinning NMR

    Energy Technology Data Exchange (ETDEWEB)

    Eddy, Matthew T. [Massachusetts Institute of Technology, Department of Chemistry (United States); Belenky, Marina [Brandeis University, Department of Chemistry (United States); Sivertsen, Astrid C. [Massachusetts Institute of Technology, Francis Bitter Magnet Laboratory (United States); Griffin, Robert G. [Massachusetts Institute of Technology, Department of Chemistry (United States); Herzfeld, Judith, E-mail: herzfeld@brandeis.edu [Brandeis University, Department of Chemistry (United States)

    2013-10-15

    The power of nuclear magnetic resonance spectroscopy derives from its site-specific access to chemical, structural and dynamic information. However, the corresponding multiplicity of interactions can be difficult to tease apart. Complimentary approaches involve spectral editing on the one hand and selective isotope substitution on the other. Here we present a new 'redox' approach to the latter: acetate is chosen as the sole carbon source for the extreme oxidation numbers of its two carbons. Consistent with conventional anabolic pathways for the amino acids, [1-{sup 13}C] acetate does not label {alpha} carbons, labels other aliphatic carbons and the aromatic carbons very selectively, and labels the carboxyl carbons heavily. The benefits of this labeling scheme are exemplified by magic angle spinning spectra of microcrystalline immunoglobulin binding protein G (GB1): the elimination of most J-couplings and one- and two-bond dipolar couplings provides narrow signals and long-range, intra- and inter-residue, recoupling essential for distance constraints. Inverse redox labeling, from [2-{sup 13}C] acetate, is also expected to be useful: although it retains one-bond couplings in the sidechains, the removal of CA-CO coupling in the backbone should improve the resolution of NCACX spectra.

  16. Nuclear spin Hall and Klein tunneling effects during oxidation with electric and magnetic field inductions in graphene.

    Science.gov (United States)

    Little, Reginald B; McClary, Felicia; Rice, Bria; Jackman, Corine; Mitchell, James W

    2012-12-14

    The recent observation of the explosive oxidation of graphene with enhancement for decreasing temperature and the requirements for synchronizing oxidants for collective oxidation-reduction (redox) reactions presented a chemical scenario for the thermal harvesting by the magnetic spin Hall Effect. More experimental data are presented to demonstrate such spin Hall Effect by determining the influence of spins of so-called spectator fermionic cations. Furthermore, the so-called spectator bosonic cations are discovered to cause a Klein tunneling effect during the redox reaction of graphene. The Na(+) and K(+), fermionic cations and the Mg(2+) and Ca(2+), bosonic cations were observed and compared under a variety of experimental conditions: adiabatic reactions with initial temperatures (18-22 °C); reactions toward infinite dilution; isothermal reactions under nonadiabatic conditions at low temperature of 18 °C; reactions under paramagnetic O(2) or diamagnetic N(2) atmospheres of different permeabilities; reactions in applied and no applied external magnetic field; and reactions toward excess concentrations of common and uncommon Na(+) and Mg(2+) cations. The observed reaction kinetics and dynamics under these various, diverse conditions are consistent with the spin Hall mechanism, energy harvesting and short time violation of Second Law of Thermodynamics for redox reactions of graphene by the Na(+)K(+) mixture and are consistent with the Klein tunnel mechanism for the redox reactions of graphene by the Mg(2+)Ca(2+) mixture. Mixed spin Hall and Klein tunnel mechanisms are discovered to slow and modulate explosive redox reactions. Such spin Hall Effect also gives explanation of recent tunneling of electrons through boron nitride.

  17. Radiolysis of liquid cyclohexanol. Determination of yields and reactivity of radicals by spin traps method

    International Nuclear Information System (INIS)

    Val'ter, A.I.; Zubarev, V.E.; Bugaenko, L.T.

    1986-01-01

    Using C-phenyl-N-tretbutylnitron (PBN) spin trap total yield of radicals Gsub(σR)=3.2+-0.2 rad/100 eV during cyclohexanol radiolysis ( 60 Co) in liquid phase is measured. 1-hydroxycyclohexyl RC[OH)R radical yield is Gsub(RC(OH)R)=1.2+-0.1 rad/100 eV, RC-HR radicals of H atom scission from the ones of C 2 , C 3 , C 4 -cyclohexane ring are formed with the yield Gsub(RC-HR)=2.0+-0.1 rad/100 eV. RC-HR radicals react with cyclohexanol molecules forming RC[OH)R. The rate constant ratio of RC-HR reactions with alcohol and PBN:Rsub(al)/ksub(PBN)=(3.6+-0.4)x10sup(-4) is determined

  18. Efficient calculation of nuclear spin-rotation constants from auxiliary density functional theory

    Energy Technology Data Exchange (ETDEWEB)

    Zuniga-Gutierrez, Bernardo, E-mail: bzuniga.51@gmail.com [Departamento de Ciencias Computacionales, Universidad de Guadalajara, Blvd. Marcelino García Barragán 1421, C.P. 44430 Guadalajara, Jalisco (Mexico); Camacho-Gonzalez, Monica [Universidad Tecnológica de Tecámac, División A2, Procesos Industriales, Carretera Federal México Pachuca Km 37.5, Col. Sierra Hermosa, C.P. 55740 Tecámac, Estado de México (Mexico); Bendana-Castillo, Alfonso [Universidad Tecnológica de Tecámac, División A3, Tecnologías de la Información y Comunicaciones, Carretera Federal México Pachuca Km 37.5, Col. Sierra Hermosa, C.P. 55740 Tecámac, Estado de México (Mexico); Simon-Bastida, Patricia [Universidad Tecnlógica de Tulancingo, División Electromecánica, Camino a Ahuehuetitla No. 301, Col. Las Presas, C.P. 43642 Tulancingo, Hidalgo (Mexico); Calaminici, Patrizia; Köster, Andreas M. [Departamento de Química, CINVESTAV, Avenida Instituto Politécnico Nacional 2508, A.P. 14-740, México D.F. 07000 (Mexico)

    2015-09-14

    The computation of the spin-rotation tensor within the framework of auxiliary density functional theory (ADFT) in combination with the gauge including atomic orbital (GIAO) scheme, to treat the gauge origin problem, is presented. For the spin-rotation tensor, the calculation of the magnetic shielding tensor represents the most demanding computational task. Employing the ADFT-GIAO methodology, the central processing unit time for the magnetic shielding tensor calculation can be dramatically reduced. In this work, the quality of spin-rotation constants obtained with the ADFT-GIAO methodology is compared with available experimental data as well as with other theoretical results at the Hartree-Fock and coupled-cluster level of theory. It is found that the agreement between the ADFT-GIAO results and the experiment is good and very similar to the ones obtained by the coupled-cluster single-doubles-perturbative triples-GIAO methodology. With the improved computational performance achieved, the computation of the spin-rotation tensors of large systems or along Born-Oppenheimer molecular dynamics trajectories becomes feasible in reasonable times. Three models of carbon fullerenes containing hundreds of atoms and thousands of basis functions are used for benchmarking the performance. Furthermore, a theoretical study of temperature effects on the structure and spin-rotation tensor of the H{sup 12}C–{sup 12}CH–DF complex is presented. Here, the temperature dependency of the spin-rotation tensor of the fluorine nucleus can be used to identify experimentally the so far unknown bent isomer of this complex. To the best of our knowledge this is the first time that temperature effects on the spin-rotation tensor are investigated.

  19. The future of nuclear power determines tasks of Ukraines nuclear fuel cycle

    International Nuclear Information System (INIS)

    Paton, B.Ye.; Neklyudov, I.M.; Krasnorutskij, V.S.

    2013-01-01

    This study provides a brief analysis on the status and development of nuclear power in the world. The present results of physical and engineering development demonstrate that in the longer term, nuclear energy as a key macro energy source is able to secure the existence and development of mankind. Based on the demand for sustainable socioeconomic existence of Ukraine as a state, there have been determined major tasks for the development of nuclear fuel cycle of Ukraine that have to be implemented at present and in the medium term

  20. Determination of 36Cl in nuclear waste from reactor decommissioning

    DEFF Research Database (Denmark)

    Hou, Xiaolin; Frøsig, Lars; Nielsen, Sven Poul

    2007-01-01

    An analytical method for the determination of Cl-36 in nuclear waste such as graphite, heavy concrete, steel, aluminum, and lead was developed. Several methods were investigated for decomposing the samples. AgCl precipitation was used to separate Cl-36 from the matrix elements, followed by ion...

  1. Determination of 93Zr in nuclear power plant wastes

    DEFF Research Database (Denmark)

    Osváth, Szabolcs; Vajda, Nora; Molnar, Zsuzsa

    2017-01-01

    A radioanalytical method (based on separation using UTEVA columns and ICP-MS measurement) has been used for determination of 93Zr in 37 nuclear power plant samples. As 93Nb might affect the detection of 93Zr, Monte Carlo activation model was used to calculate the expected 93Zr/natZr mass ratio...

  2. Determining the "Half-Life" of Nuclear Education.

    Science.gov (United States)

    Lenda, Michael P.; Learn, George A., Jr.

    1980-01-01

    Described is a study to determine the long-range impact of the Pennsylvania Nuclear Science Prolect. Findings include that fewer than one-half participants are still teaching the pilot program, that school/teachers who "dropped out" averaged three years from initial involvement, and that student interest and scheduling problems are two…

  3. Pseudogap Behavior of the Nuclear Spin-Lattice Relaxation Rate in FeSe Probed by 77Se-NMR

    Science.gov (United States)

    Shi, Anlu; Arai, Takeshi; Kitagawa, Shunsaku; Yamanaka, Takayoshi; Ishida, Kenji; Böhmer, Anna E.; Meingast, Christoph; Wolf, Thomas; Hirata, Michihiro; Sasaki, Takahiko

    2018-01-01

    We conducted 77Se-nuclear magnetic resonance studies of the iron-based superconductor FeSe in magnetic fields of 0.6 to 19 T to investigate the superconducting and normal-state properties. The nuclear spin-lattice relaxation rate divided by the temperature (T1T)-1 increases below the structural transition temperature Ts but starts to be suppressed below T*, well above the superconducting transition temperature Tc(H), resulting in a broad maximum of (T1T)-1 at Tp(H). This is similar to the pseudogap behavior in optimally doped cuprate superconductors. Because T* and Tp(H) decrease in the same manner as Tc(H) with increasing H, the pseudogap behavior in FeSe is ascribed to superconducting fluctuations, which presumably originate from the theoretically predicted preformed pair above Tc(H).

  4. Study of nuclear isovector spin responses from polarization transfer in (p,n) reactions at intermediate energies

    International Nuclear Information System (INIS)

    Wakasa, Tomotsugu

    1997-01-01

    We have measured a complete set of polarization transfer observables has been measured for quasi-free (p vector, n vector) reactions on 2 H, 6 Li, 12 C, 40 Ca, and 208 Pb at a bombarding energy of 346MeV and a laboratory scattering angle of 22deg (q=1.7 fm -1 ). The polarization transfer observables for all five targets are remarkably similar. These polarization observables yield separated spin-longitudinal (σ·q) and spin-transverse (σxq) nuclear responses. These results are compared to the spin-transverse responses measured in deep-inelastic electron scattering as well as to nuclear responses based on the random phase approximation. Such a comparison reveals an enhancement in the (p vector, n vector) spin-transverse channel, which masks the effect of pionic correlations in the response ratio. Second, the double differential cross sections at θ lab between 0deg and 12.3deg and the polarization transfer D NN at 0deg for the 90 Zr(p,n) reaction are measured at a bombarding energy of 295MeV. The Gamow-Teller(GT) strength B(GT) in the continuum deduced from the L=0 cross section is compared both with the perturbative calculation by Bertsch and Hamamoto and with the second-order random phase approximation calculation by Drozdz et al. The sum of B(GT) values up to 50MeV excitation becomes S β- =28.0±1.6 after subtracting the contribution of the isovector spin-monopole strength. This S β- value of 28.0±1.6 corresponds to about (93±5)% of the minimum value of the sum-rule 3(N-Z)=30. Last, first measurements of D NN (0deg) for (p vector, n vector) reactions at 295MeV yield large negative values up to 50MeV excitation for the 6 Li, 11 B, 12 C, 13 C(p vector, n vector) reactions. DWIA calculations using the Franey and Love (FL) 270MeV interaction reproduce differential cross sections and D NN (0deg) values, while the FL 325MeV interaction yield D NN (0deg) values less negative than the experimental values. (J.P.N.)

  5. Determination of the Spin and Parity of the Z_{c}(3900).

    Science.gov (United States)

    Ablikim, M; Achasov, M N; Ai, X C; Albayrak, O; Albrecht, M; Ambrose, D J; Amoroso, A; An, F F; An, Q; Bai, J Z; Baldini Ferroli, R; Ban, Y; Bennett, D W; Bennett, J V; Bertani, M; Bettoni, D; Bian, J M; Bianchi, F; Boger, E; Boyko, I; Briere, R A; Cai, H; Cai, X; Cakir, O; Calcaterra, A; Cao, G F; Cetin, S A; Chang, J F; Chelkov, G; Chen, G; Chen, H S; Chen, H Y; Chen, J C; Chen, M L; Chen, S; Chen, S J; Chen, X; Chen, X R; Chen, Y B; Cheng, H P; Chu, X K; Cibinetto, G; Dai, H L; Dai, J P; Dbeyssi, A; Dedovich, D; Deng, Z Y; Denig, A; Denysenko, I; Destefanis, M; De Mori, F; Ding, Y; Dong, C; Dong, J; Dong, L Y; Dong, M Y; Dou, Z L; Du, S X; Duan, P F; Fan, J Z; Fang, J; Fang, S S; Fang, X; Fang, Y; Farinelli, R; Fava, L; Fedorov, O; Feldbauer, F; Felici, G; Feng, C Q; Fioravanti, E; Fritsch, M; Fu, C D; Gao, Q; Gao, X L; Gao, X Y; Gao, Y; Gao, Z; Garzia, I; Goetzen, K; Gong, L; Gong, W X; Gradl, W; Greco, M; Gu, M H; Gu, Y T; Guan, Y H; Guo, A Q; Guo, L B; Guo, R P; Guo, Y; Guo, Y P; Haddadi, Z; Hafner, A; Han, S; Hao, X Q; Harris, F A; He, K L; Held, T; Heng, Y K; Hou, Z L; Hu, C; Hu, H M; Hu, J F; Hu, T; Hu, Y; Huang, G S; Huang, J S; Huang, X T; Huang, X Z; Huang, Y; Huang, Z L; Hussain, T; Ji, Q; Ji, Q P; Ji, X B; Ji, X L; Jiang, L W; Jiang, X S; Jiang, X Y; Jiao, J B; Jiao, Z; Jin, D P; Jin, S; Johansson, T; Julin, A; Kalantar-Nayestanaki, N; Kang, X L; Kang, X S; Kavatsyuk, M; Ke, B C; Kiese, P; Kliemt, R; Kloss, B; Kolcu, O B; Kopf, B; Kornicer, M; Kuehn, W; Kupsc, A; Lange, J S; Lara, M; Larin, P; Leng, C; Li, C; Li, Cheng; Li, D M; Li, F; Li, F Y; Li, G; Li, H B; Li, H J; Li, J C; Li, Jin; Li, K; Li, K; Li, Lei; Li, P R; Li, Q Y; Li, T; Li, W D; Li, W G; Li, X L; Li, X M; Li, X N; Li, X Q; Li, Y B; Li, Z B; Liang, H; Liang, J J; Liang, Y F; Liang, Y T; Liao, G R; Lin, D X; Liu, B; Liu, B J; Liu, C X; Liu, D; Liu, F H; Liu, Fang; Liu, Feng; Liu, H B; Liu, H H; Liu, H H; Liu, H M; Liu, J; Liu, J B; Liu, J P; Liu, J Y; Liu, K; Liu, K Y; Liu, L D; Liu, P L; Liu, Q; Liu, S B; Liu, X; Liu, Y B; Liu, Z A; Liu, Zhiqing; Loehner, H; Lou, X C; Lu, H J; Lu, J G; Lu, Y; Lu, Y P; Luo, C L; Luo, M X; Luo, T; Luo, X L; Lyu, X R; Ma, F C; Ma, H L; Ma, L L; Ma, M M; Ma, Q M; Ma, T; Ma, X N; Ma, X Y; Ma, Y M; Maas, F E; Maggiora, M; Mao, Y J; Mao, Z P; Marcello, S; Messchendorp, J G; Min, J; Mitchell, R E; Mo, X H; Mo, Y J; Morales, C Morales; Muchnoi, N Yu; Muramatsu, H; Nefedov, Y; Nerling, F; Nikolaev, I B; Ning, Z; Nisar, S; Niu, S L; Niu, X Y; Olsen, S L; Ouyang, Q; Pacetti, S; Pan, Y; Patteri, P; Pelizaeus, M; Peng, H P; Peters, K; Pettersson, J; Ping, J L; Ping, R G; Poling, R; Prasad, V; Qi, H R; Qi, M; Qian, S; Qiao, C F; Qin, L Q; Qin, N; Qin, X S; Qin, Z H; Qiu, J F; Rashid, K H; Redmer, C F; Ripka, M; Rong, G; Rosner, Ch; Ruan, X D; Sarantsev, A; Savrié, M; Schoenning, K; Schumann, S; Shan, W; Shao, M; Shen, C P; Shen, P X; Shen, X Y; Sheng, H Y; Shi, M; Song, W M; Song, X Y; Sosio, S; Spataro, S; Sun, G X; Sun, J F; Sun, S S; Sun, X H; Sun, Y J; Sun, Y Z; Sun, Z J; Sun, Z T; Tang, C J; Tang, X; Tapan, I; Thorndike, E H; Tiemens, M; Ullrich, M; Uman, I; Varner, G S; Wang, B; Wang, B L; Wang, D; Wang, D Y; Wang, K; Wang, L L; Wang, L S; Wang, M; Wang, P; Wang, P L; Wang, S G; Wang, W; Wang, W P; Wang, X F; Wang, Y; Wang, Y D; Wang, Y F; Wang, Y Q; Wang, Z; Wang, Z G; Wang, Z H; Wang, Z Y; Wang, Z Y; Weber, T; Wei, D H; Wei, J B; Weidenkaff, P; Wen, S P; Wiedner, U; Wolke, M; Wu, L H; Wu, L J; Wu, Z; Xia, L; Xia, L G; Xia, Y; Xiao, D; Xiao, H; Xiao, Z J; Xie, Y G; Xiu, Q L; Xu, G F; Xu, J J; Xu, L; Xu, Q J; Xu, Q N; Xu, X P; Yan, L; Yan, W B; Yan, W C; Yan, Y H; Yang, H J; Yang, H X; Yang, L; Yang, Y X; Ye, M; Ye, M H; Yin, J H; Yu, B X; Yu, C X; Yu, J S; Yuan, C Z; Yuan, W L; Yuan, Y; Yuncu, A; Zafar, A A; Zallo, A; Zeng, Y; Zeng, Z; Zhang, B X; Zhang, B Y; Zhang, C; Zhang, C C; Zhang, D H; Zhang, H H; Zhang, H Y; Zhang, J; Zhang, J J; Zhang, J L; Zhang, J Q; Zhang, J W; Zhang, J Y; Zhang, J Z; Zhang, K; Zhang, L; Zhang, S Q; Zhang, X Y; Zhang, Y; Zhang, Y H; Zhang, Y N; Zhang, Y T; Zhang, Yu; Zhang, Z H; Zhang, Z P; Zhang, Z Y; Zhao, G; Zhao, J W; Zhao, J Y; Zhao, J Z; Zhao, Lei; Zhao, Ling; Zhao, M G; Zhao, Q; Zhao, Q W; Zhao, S J; Zhao, T C; Zhao, Y B; Zhao, Z G; Zhemchugov, A; Zheng, B; Zheng, J P; Zheng, W J; Zheng, Y H; Zhong, B; Zhou, L; Zhou, X; Zhou, X K; Zhou, X R; Zhou, X Y; Zhu, K; Zhu, K J; Zhu, S; Zhu, S H; Zhu, X L; Zhu, Y C; Zhu, Y S; Zhu, Z A; Zhuang, J; Zotti, L; Zou, B S; Zou, J H

    2017-08-18

    The spin and parity of the Z_{c}(3900)^{±} state are determined to be J^{P}=1^{+} with a statistical significance larger than 7σ over other quantum numbers in a partial wave analysis of the process e^{+}e^{-}→π^{+}π^{-}J/ψ. We use a data sample of 1.92  fb^{-1} accumulated at sqrt[s]=4.23 and 4.26 GeV with the BESIII experiment. When parametrizing the Z_{c}(3900)^{±} with a Flatté-like formula, we determine its pole mass M_{pole}=(3881.2±4.2_{stat}±52.7_{syst})  MeV/c^{2} and pole width Γ_{pole}=(51.8±4.6_{stat}±36.0_{syst})  MeV. We also measure cross sections for the process e^{+}e^{-}→Z_{c}(3900)^{+}π^{-}+c.c.→J/ψπ^{+}π^{-} and determine an upper limit at the 90% confidence level for the process e^{+}e^{-}→Z_{c}(4020)^{+}π^{-}+c.c.→J/ψπ^{+}π^{-}.

  6. Use of Nuclear Magnetic Resonance as an Experimental Probe in Multiphase Systems: Determination of the Instrument Weight Function for Measurements of Liquid-Phase Volume Fractions

    Science.gov (United States)

    Maneval, J. E.; McCarthy, M. J.; Whitaker, S.

    1990-11-01

    The relativist approach (Baveye and Sposito (1984)) to the interpretation of measurements in multiphase systems was proposed in order to incorporate the details of measurements into theoretical analyses of multiphase transport processes. To help establish the utility of this approach, the weight functions for actual experimental probes must be determined. In this paper we analyze the measurement of liquid-phase porosity in a model system by nuclear magnetic resonance imaging. We show how both nuclear magnetic resonance (NMR) physics and experimental technique combine to determine the weight function for the spin-warp spin-echo sequence. The analysis shows clearly what aspects of the weight function are determined by the experimental method and what aspects are determined by the system being studied. The results will help establish the utility of the relativist approach as well as improve understanding NMR measurements in multiphase systems.

  7. Devices and process for high-pressure magic angle spinning nuclear magnetic resonance

    Energy Technology Data Exchange (ETDEWEB)

    Hoyt, David W.; Sears, Jesse A.; Turcu, Romulus V. F.; Rosso, Kevin M.; Hu, Jian Zhi

    2017-12-05

    A high-pressure magic angle spinning (MAS) rotor is detailed that includes a high-pressure sample cell that maintains high pressures exceeding 150 bar. The sample cell design minimizes pressure losses due to penetration over an extended period of time.

  8. Characterization of Chemical Exchange Using Relaxation Dispersion of Hyperpolarized Nuclear Spins.

    Science.gov (United States)

    Liu, Mengxiao; Kim, Yaewon; Hilty, Christian

    2017-09-05

    Chemical exchange phenomena are ubiquitous in macromolecules, which undergo conformational change or ligand complexation. NMR relaxation dispersion (RD) spectroscopy based on a Carr-Purcell-Meiboom-Gill pulse sequence is widely applied to identify the exchange and measure the lifetime of intermediate states on the millisecond time scale. Advances in hyperpolarization methods improve the applicability of NMR spectroscopy when rapid acquisitions or low concentrations are required, through an increase in signal strength by several orders of magnitude. Here, we demonstrate the measurement of chemical exchange from a single aliquot of a ligand hyperpolarized by dissolution dynamic nuclear polarization (D-DNP). Transverse relaxation rates are measured simultaneously at different pulsing delays by dual-channel 19 F NMR spectroscopy. This two-point measurement is shown to allow the determination of the exchange term in the relaxation rate expression. For the ligand 4-(trifluoromethyl)benzene-1-carboximidamide binding to the protein trypsin, the exchange term is found to be equal within error limits in neutral and acidic environments from D-DNP NMR spectroscopy, corresponding to a pre-equilibrium of trypsin deprotonation. This finding illustrates the capability for determination of binding mechanisms using D-DNP RD. Taking advantage of hyperpolarization, the ligand concentration in the exchange measurements can reach on the order of tens of μM and protein concentration can be below 1 μM, i.e., conditions typically accessible in drug discovery.

  9. Quantum entanglement analysis of an optically excited coupling of two nuclear spins via a mediator: Combining the quantum concurrence and negativity

    Science.gov (United States)

    Fu, Chenghua; Hu, Zhanning

    2018-03-01

    In this paper, we investigate the characteristics of the nuclear spin entanglement generated by an intermedium with an optically excited triplet. Significantly, the interaction between the two nuclear spins presents to be a direct XY coupling in each of the effective subspace Hamiltonians which are obtained by applying a transformation on the natural Hamiltonian. The quantum concurrence and negativity are discussed to quantitatively describe the quantum entanglement, and a comparison between them can reveal the nature of their relationship. An innovative general equation describing the relationship between the concurrence and negativity is explicitly obtained.

  10. Determination of the spin Hamiltonian in the pyrochlore Lu{sub 2}V{sub 2}O{sub 7}

    Energy Technology Data Exchange (ETDEWEB)

    Riedl, Kira; Jeschke, Harald O.; Valenti, Roser [Institut fuer Theoretische Physik, Goethe-Universitaet Frankfurt am Main (Germany); Gingras, Michel J.P. [Department of Physics and Astronomy, University of Waterloo, ON (Canada); Perimeter Institute for Theoretical Physics, Waterloo, ON (Canada); Canadian Institute for Advanced Research, Toronto, ON (Canada)

    2016-07-01

    In the pyrochlore Lu{sub 2}V{sub 2}O{sub 7} the vanadium ions form corner-sharing spin 1/2 tetrahedra. In order to find the corresponding spin Hamiltonian which captures the essential physics of the investigated compound we performed a tight-binding fit on the vanadium d orbitals using density functional theory. Since there is evidence that the Dzyaloshinskii-Moriya interaction (DMI) is important in this system, we considered spin-orbit coupling effects within our calculations. A fitting procedure to the relativistic band structure enabled us to determine the strength of the spin-orbit coupling. In a second step, we calculated the energy parameters in the spin Hamiltonian with the method of exact diagonalization and projection on low energy states. We were therefore able to evaluate the Heisenberg exchange, the DMI, and the symmetric tensor, only using ab initio information and reasonable values for the Hubbard interaction as well as for the Hund's coupling. Comparison with recent experimental results will be discussed.

  11. US Nuclear Non-Proliferation Policy: impact on exports and nuclear industry could not be determined

    International Nuclear Information System (INIS)

    Staats, E.B.

    1980-01-01

    The Nuclear Non-Proliferation Act of 1978 established new measures to prevent the diversion to weapons use of peaceful nuclear exports. It also created a policy to confirm US reliability as a nuclear supplier. GAO did not identify any export sales lost as a result of the Act, but did find indications that nonprofileration policies can influence export sales. Based on avavailable data, GAO could not determine the impact of the Act on the competitiveness of US nuclear exports. However, US companies are at some disadvantage because importers perceive that implementation of the Act may result in delayed export licenses. The United States dominated the nuclear export market through the early 1970s. However, foreign competitors, some aided by US technology transfers, emerged to monopolize home markets and complete for third-country business. Further, the market has been depressed since 1974 and prospects for US nuclear power plant exports have dimmed greatly. However, US companies continue to view exports as important to sustain production capacity

  12. Determination of chlorine in nuclear-grade uranium compounds

    International Nuclear Information System (INIS)

    Yang Chunqing; Liu Fuyun; Huang Dianfan

    1988-01-01

    The determination of chlorine in nuclear-grade uranium compounds is discribed. Chlorine is separated from uranium oxide pyrohydrolytically with stream of wet oxygen in a furnace at 800 ∼ 900 deg C. Chlorine is volatilized as hydrochloric acid, absorbed in a dilute alkaline solution and measured with chlorine-selective electrode. This method covers the concentration range of 10 ∼ 500 pm chlorine in uranium oxide. Precision of at least ± 10% and recovery of 85 ∼ 108% have been reported

  13. Research program in nuclear and solid state physics. [including pion absorption spectra and muon spin precession

    Science.gov (United States)

    1974-01-01

    The survey of negative pion absorption reactions on light and medium nuclei was continued. Muon spin precession was studied using an iron target. An impulse approximation model of the pion absorption process implied that the ion will absorb almost exclusively on nucleon pairs, single nucleon absorption being suppressed by energy and momentum conservation requirements. For measurements on both paramagnetic and ferromagnetic iron, the external magnetic field was supplied by a large C-type electromagnet carrying a current of about 100 amperes.

  14. The possibility to determine a constant of spin-orbit interaction by scanning tunneling microscopy method

    International Nuclear Information System (INIS)

    Khotkevich, N.V.; Kolesnichenko, Yu.A.; Vovk, N.P.

    2016-01-01

    The electron tunneling from the quasi-two-dimensional (surface) states with the spin-orbit interaction into bulk-mode states is studied in the framework of a model of an infinitely thin inhomogeneous tunnel magnetic barrier. The influence of the scattering of quasi-two-dimensional electrons by a single magnetic defect on the tunnel current is analyzed. Analytic formulas for the conductance of a tunnel point-contact as a function of its distance from the defect are obtained. It is shown that the analysis of the local magnetization density around the defect by means of spin-polarized scanning tunneling microscopy allows finding the constant of spin orbit interaction.

  15. Determination of boron in silicon related nuclear materials by spectrophotometry

    International Nuclear Information System (INIS)

    Ramanjaneyulu, P.S.; Sayi, Y.S.; Ramakumar, K.L.

    2007-01-01

    Boron is one of the important specifications in all-nuclear materials. The present paper describes in detail about the determination of boron in U-Al-Si and SILUMIN. The sample is treated with H 2 O 2 and 3 M HCl. Silicon will be left as precipitate. It was removed by centrifugation. Boron was selectively separated by solvent extraction with 10% 2-ethyl hexane 1,3-diol and was quantitatively determined by spectrophotometry using curcumin as complexing agent. Since standard reference materials are not available, standard addition method was employed to confirm the results. (author)

  16. A new problem in the correlation of nuclear-spin relaxation and ionic conductivity in superionic glasses

    Science.gov (United States)

    Tatsumisago, M.; Angell, C. A.; Martin, S. W.

    1992-11-01

    Following the recent resolution of the longstanding problem of reconciling constant frequency nuclear-spin lattice relaxation (SLR) activation energies and d.c. conductivity activity energies in ion conducting glasses, we point out a new problem which seems not to have been discussed previously. We report conductivity data measured at a series of fixed frequencies and variable temperatures on a lithium chloroborate glass and compare them with SLR data on identically prepared samples, also using different fixed frequencies. While phenomenological similarities due to comparable departures from exponential relaxation are found in each case, pronounced differences in the most probable relaxation times themselves are observed. The conductivity relaxation at 500 K occurs on a time scale shorter by some 2 orders of magnitude than the 7Li SLR correlation, and has a significantly lower activation energy. We show from a literature review that this distinction is a common but unreported finding for highly decoupled (fast-ion conducting) systems, and that an inverse relationship is found in supercoupled salt/polymer ``solid'' electrolytes. In fast-ion conducting glasses, the slower SLR process would imply special features in the fast-ion motion which permit spin correlations to survive many more successive ion displacements than previously expected. It is conjectured that the SLR in superionic glasses depends on the existence of a class of low-lying traps infrequently visited by migrating ions.

  17. Model for the determination of the nuclear fuel

    International Nuclear Information System (INIS)

    Azevedo, J.B.L. de.

    1979-09-01

    The Nuclear Fuel Cost Determination Model, MDCN, is a computer program written in FORTRAN IV, meant to calculate the nuclear fuel cost employed in nuclear power plants for heat or electrical energy generation. The economic principles employed are: capital recovery proportional to the energy generation, present worth method for the equivalence of costs and levelized fuel cost calculation. This model presents some inovations in comparasion with other models already in use, since it takes into account refueling and maintenance outages and it does not fix the fuel cycle steps (industrial processes and services). The first inovation leads to a more realistic cost determination and permits the model to be employed together with hydrothermal power system simulators; the second permits a more flexible use of the model, like economical comparison of fuel cycles. Complementing the main body of the work, where the theoretical fundamentals and methodology necessary to the calculation developments are discussed, annexes are included treating in greater detail some specific itens; the more important ones refer to the FORTRAN program, input data preparation and example. (Author) [pt

  18. Contrast generation in the nuclear-spin tomography by pulsed ultrasound; Kontrasterzeugung in der Kernspintomographie durch gepulsten Ultraschall

    Energy Technology Data Exchange (ETDEWEB)

    Oehms, Ole Benjamin

    2009-07-10

    In the framework of this thesis a combined method of ultrasound and nuclear-spin tomography is presented. Via ultrasound pulses by the sound-radiation force in liquids and tissue phantoms motions are generated, which depend on ther viscoelastic properties. This motions are made visible by a motion-sensitive tomograph sequence in the phase image of the tomograph in form of a phase change. The first measurements on simple phantoms and liquids are presented. [German] Im Rahmen dieser Arbeit wird eine kombinierte Methode aus Ultraschall und Kernspintomographie vorgestellt. Ueber Ultraschallpulse werden durch die Schallstrahlungskraft in Fluessigkeiten und Gewebephantomen Bewegungen erzeugt, die von den viskoelastischen Eigenschaften abhaengen. Diese Bewegungen werden mit einer bewegungssensitiven Tomographensequenz im Phasenbild des Tomographen in Form einer Phasenaenderung sichtbar gemacht. Die ersten Messungen an einfachen Phantomen und Fluessigkeiten werden praesentiert. (orig.)

  19. Spin-lattice relaxation attenuation coefficients for on-line nuclear orientation experiments

    CERN Document Server

    Vénos, D; Severijns, N

    2003-01-01

    In on-line nuclear orientation experiments the relaxation process is of great importance. During implantation of the radioactive beam, the nuclear sublevel populations attain a secular equilibrium. For this case secular orientation parameters are introduced: B sublambda(sec)=rho sublambda B sublambda(th). Previously attenuation coefficients rho sublambda have already been tabulated, but only for lambda=2,4. In the last few years the number of nuclear orientation experiments in which beta or alpha particles are studied has increased. For these experiments the terms with lambda=1,3,6, and 8 are also necessary. Therefore, we have calculated the values of rho sublambda in full scope.

  20. Electron spin resonance and nuclear magnetic resonance of sodium macrostructures in strongly irradiated NaCl-K crystals: Manifestation of quasi-one-dimensional behavior of electrons

    NARCIS (Netherlands)

    Cherkasov, FG; Mustafin, RG; L'vov, SG; Denisenko, GA; den Hartog, HW; Vainshtein, D. I.

    1998-01-01

    Data from an investigation of electron spin resonance and nuclear magnetic resonance of NaCl-K (similar to 1 mole%) crystals strongly irradiated with electrons imply the observation of a metal-insulator transition with decreasing temperature and the manifestation of quasi-one-dimensional electron

  1. Spin-orbit ZORA and four-component Dirac-Coulomb estimation of relativistic corrections to isotropic nuclear shieldings and chemical shifts of noble gas dimers

    DEFF Research Database (Denmark)

    Jankowska, Marzena; Kupka, Teobald; Stobiński, Leszek

    2016-01-01

    corrections were calculated with the scalar and spin-orbit zeroth-order regular approximation Hamiltonian in combination with the large Slater-type basis set QZ4P as well as with the 4-component Dirac-Coulomb Hamiltonian using Dyall’s acv4z basis sets. The relativistic corrections to the nuclear magnetic...

  2. Magic Angle Spinning NMR Structure Determination of Proteins from Pseudocontact Shifts

    KAUST Repository

    Li, Jianping

    2013-06-05

    Magic angle spinning solid-state NMR is a unique technique to study atomic-resolution structure of biomacromolecules which resist crystallization or are too large to study by solution NMR techniques. However, difficulties in obtaining sufficient number of long-range distance restraints using dipolar coupling based spectra hamper the process of structure determination of proteins in solid-state NMR. In this study it is shown that high-resolution structure of proteins in solid phase can be determined without the use of traditional dipolar-dipolar coupling based distance restraints by combining the measurements of pseudocontact shifts (PCSs) with Rosetta calculations. The PCSs were generated by chelating exogenous paramagnetic metal ions to a tag 4-mercaptomethyl-dipicolinic acid, which is covalently attached to different residue sites in a 56-residue immunoglobulin-binding domain of protein G (GB1). The long-range structural restraints with metal-nucleus distance of up to ∼20 Å are quantitatively extracted from experimentally observed PCSs, and these are in good agreement with the distances back-calculated using an X-ray structure model. Moreover, we demonstrate that using several paramagnetic ions with varied paramagnetic susceptibilities as well as the introduction of paramagnetic labels at different sites can dramatically increase the number of long-range restraints and cover different regions of the protein. The structure generated from solid-state NMR PCSs restraints combined with Rosetta calculations has 0.7 Å root-mean-square deviation relative to X-ray structure. © 2013 American Chemical Society.

  3. Thermal coupling in low fields between the nuclear and electronic spins in Tm2+ doped CaF2

    International Nuclear Information System (INIS)

    Urbina, Cristian.

    1977-01-01

    It is shown that in a CaF 2 crystal doped with divalent thulium ions there is in low fields, a thermal coupling between the electron magnetic moments of Tm 2+ and the nuclear moments of 19 F. When these ones have been lowered down to temperature through dynamical high-field polarization and adiabatic demagnetization in succession the resulting polarisation of the formed ones can overstep their original polarization in high field. A trial is given to explain this Zeeman electronic energy cooling through nuclear Zeeman energy with invoking a thermal coupling between both systems through the spin-spin electronic interaction but no theoretical model is developed in view of a quantitative explanation of the dynamics of such a process. The magnetic resonance spectrum of Tm 2 + in low field is also investigated: an important shift and narrowing of the electron resonance line in low field are obtained when 19 F nuclei are very cold. This special spectral characters are explained as due to magnetic interactions between electronic impurities and the neighbouring 19 F nuclei and a theoretical model is developed (based on the local Weiss field approximation) which explains rather well the changes in the spectral shift as a function of the 19 F nucleus temperature. A second theoretical model has also been developed in view of a quantitative explanation of both the narrowing and shift of the spectrum, but its prediction disagree with the experimental results. It is shown that in low fieldsx it is possible to get rid of paramagnetic impurities after they have been reused as reducing agents for 19 F nucleus entropy populating at about 80%, a non magnetic metastable state with these impurities [fr

  4. Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations

    Science.gov (United States)

    Hu, Jian Zhi; Sears, Jr., Jesse A.; Hoyt, David W.; Mehta, Hardeep S.; Peden, Charles H. F.

    2015-11-24

    A continuous-flow (CF) magic angle sample spinning (CF-MAS) NMR rotor and probe are described for investigating reaction dynamics, stable intermediates/transition states, and mechanisms of catalytic reactions in situ. The rotor includes a sample chamber of a flow-through design with a large sample volume that delivers a flow of reactants through a catalyst bed contained within the sample cell allowing in-situ investigations of reactants and products. Flow through the sample chamber improves diffusion of reactants and products through the catalyst. The large volume of the sample chamber enhances sensitivity permitting in situ .sup.13C CF-MAS studies at natural abundance.

  5. Spin-Mechatronics

    Science.gov (United States)

    Matsuo, Mamoru; Saitoh, Eiji; Maekawa, Sadamichi

    2017-01-01

    We investigate the interconversion phenomena between spin and mechanical angular momentum in moving objects. In particular, the recent results on spin manipulation and spin-current generation by mechanical motion are examined. In accelerating systems, spin-dependent gauge fields emerge, which enable the conversion from mechanical angular momentum into spins. Such a spin-mechanical effect is predicted by quantum theory in a non-inertial frame. Experiments which confirm the effect, i.e., the resonance frequency shift in nuclear magnetic resonance, the stray field measurement of rotating metals, and electric voltage generation in liquid metals, are discussed.

  6. chemical determination of burnup ratio in nuclear fuels

    International Nuclear Information System (INIS)

    Guereli, L.

    1997-01-01

    Measurements of the extent of fission are important to determine the irradiation performance of a nuclear fuel. The energy released per unit mass of uranium (burnup) can be determined from measurement of the percent of heavy atoms that have fissioned during irradiation.The preferred method for this determination is choosing a suitable fission monitor (usually ''1''4''8Nd) and its determination after separation from the fuel matrix. In thermal reactor fuels where the only heavy element in the starting material is uranium, uranium depletion can be used for burnup determination. ''2''3''5U depletion method requires measurement of uranium isotopic ratios of both irradiated and unirradiated fuel. Isotopic ratios can be determined by thermal ionization mass spectrometer following separation of uranium from the fuel matrix. Separation procedures include solvent extraction, ion exchange and anion exchange chromatography. Another fission monitor used is ''1''3''9La determination by HPLC. Because La is monoisotopic (''1''3''9La) in the fuel, it can be determined by chemical analysis techniques

  7. Experimental determination of levy flight distributions of the energy barriers in spin glasses

    International Nuclear Information System (INIS)

    Gorham, N.T.; Woodward, R.C.; St Pierre, T.G.; Stamps, R.L.; Walker, M.J.; Greig, D.; Matthew, J.A.D.

    2004-01-01

    Full text: 'Spin glass' was a term originally developed to describe certain magnetic alloys in which there was observed a freezing transition to a low temperature phase where the magnetic moments (or spins) are aligned in fixed but random directions. Although the study of spin glasses is at least three decades old, our current understanding of some very basic issues is still quite limited. Observable characteristics associated with spin glasses are thought to result from the complex dynamics associated with a large number of metastable magnetic states separated by a broad distribution of energy barriers to magnetic reversal. To date, a number of models have been developed which produce this type of energy landscape including the random energy model and the hierarchical energy model. In this study we use a technique previously developed for the study of magnetic nanoparticles to characterise the apparent magnetic energy barrier distribution that results from this complex energy landscape for a series of Pd 40 Ni 40 - x Fe x P 20 (x=10-20) alloys. The distributions observed are best described by a stretched exponential in the form of a truncated Levy flight distribution. This form would appear to suggest a hierarchical landscape of apparent energy barriers arising from interactions between randomly oriented magnetic clusters of spins within the material. The degree of stretching of the exponential form of the energy barrier distributions is found to increase with decreasing iron concentration

  8. Determination of air pollutants by nuclear chemical analysis

    International Nuclear Information System (INIS)

    Lesny, J.; Toelgyessy, J.

    1975-01-01

    Nuclear analytical methods are discussed with a view to their applicability in the determination of air pollutants. It is shown that some methods (use of radioactive kryptonates in automatic analyzers, application of activation analysis, X-ray fluorescence methods) are developed in theory and proven in practice in such an extent to be widely used in the near future in the control of the environment. Many other methods are becoming increasingly important for the solution of specific problems of environmental protection (such as the control of sudden environmental contamination in the proximity of chemical plants and industrial centers). (author)

  9. Electron-nuclear spin dynamics of Ga centers in GaAsN dilute nitride semiconductors probed by pump-probe spectroscopy

    Science.gov (United States)

    Sandoval-Santana, J. C.; Ibarra-Sierra, V. G.; Azaizia, S.; Carrère, H.; Bakaleinikov, L. A.; Kalevich, V. K.; Ivchenko, E. L.; Marie, X.; Amand, T.; Balocchi, A.; Kunold, A.

    2018-03-01

    We propose an experimental procedure to track the evolution of electronic and nuclear spins in Ga2+ centers in GaAsN dilute semiconductors. The method is based on a pump-probe scheme that enables to monitor the time evolution of the three components of the electronic and nuclear spin variables. In contrast to other characterization methods, as nuclear magnetic resonance, this one only needs moderate magnetic fields (B≈ 10 mT), and does not require microwave irradiation. Specifically, we carry out a series of tests for different experimental conditions in order to optimize the procedure for maximum sensitivity in the measurement of the circular degree of polarization. Based on previous experimental results and the theoretical calculations presented here, we estimate that the method could yield a time resolution of about 10ps.

  10. Angular velocity determination of spinning solar sails using only a sun sensor

    Directory of Open Access Journals (Sweden)

    Kun Zhai

    2017-02-01

    Full Text Available The direction of the sun is the easiest and most reliable observation vector for a solar sail running in deep space exploration. This paper presents a new method using only raw measurements of the sun direction vector to estimate angular velocity for a spinning solar sail. In cases with a constant spin angular velocity, the estimation equation is formed based on the kinematic model for the apparent motion of the sun direction vector; the least-squares solution is then easily calculated. A performance criterion is defined and used to analyze estimation accuracy. In cases with a variable spin angular velocity, the estimation equation is developed based on the kinematic model for the apparent motion of the sun direction vector and the attitude dynamics equation. Simulation results show that the proposed method can quickly yield high-precision angular velocity estimates that are insensitive to certain measurement noises and modeling errors.

  11. Spin motion determination of the Envisat satellite through laser ranging measurements from a single pass measured by a single station

    Science.gov (United States)

    Pittet, Jean-Noël; Šilha, Jiří; Schildknecht, Thomas

    2018-02-01

    The Satellite Laser Ranging (SLR) technology is used to accurately determine the position of space objects equipped with so-called retro-reflectors or retro-reflector arrays (RRA). This type of measurement allows to measure the range to the spacecraft with high precision, which leads to determination of very accurate orbits for these targets. Non-active spacecraft, which are not attitude controlled any longer, tend to start to spin or tumble under influence of the external and internal torques and forces. If the return signal is measured for a non-spherical non-active rotating object, the signal in the range residuals with respect to the reference orbit is more complex. For rotating objects the return signal shows an oscillating pattern or patterns caused by the RRA moving around the satellite's centre of mass. This behaviour is projected onto the radial component measured by the SLR. In our work, we demonstrate how the SLR ranging technique from one sensor to a satellite equipped with a RRA can be used to precisely determine its spin motion during one passage. Multiple SLR measurements of one target over time allow to accurately monitor spin motion changes which can be further used for attitude predictions. We show our solutions of the spin motion determined for the non-active ESA satellite Envisat obtained from measurements acquired during years 2013-2015 by the Zimmerwald SLR station, Switzerland. All the necessary parameters are defined for our own so-called point-like model which describes the motion of a point in space around the satellite centre of mass.

  12. Persistent Optical Nuclear Spin Narrowing in a Singly Charged InAs Quantum Dot

    Science.gov (United States)

    2012-02-01

    hole envelope wave function, Ah is the hyper- fine coupling constant, and c0 is the lattice parameter. Since the external magnetic field is in the x̂...February 2012 / J. Opt. Soc. Am. B A121 where γs (γt) is the spin (trion) dephasing rate, χ is half the pump Rabi frequency ΩR (ΩR # μEℏ , where μ is...probe ab- sorption at the dark state dip (αdip) and the Rabi sideband (αpeak): αdip # α0 χ2γs & γt$γ2s% χ4 & 2χ2γtγs & γ2t γ2s ; (11) αpeak # α0 χ2γs

  13. Effect of nuclear spin on chemical reactions and internal molecular rotation

    International Nuclear Information System (INIS)

    Sterna, L.L.

    1980-12-01

    Part I of this dissertation is a study of the magnetic isotope effect, and results are presented for the separation of 13 C and 12 C isotopes. Two models are included in the theoretical treatment of the effect. In the first model the spin states evolve quantum mechanically, and geminate recombination is calculated by numerically integrating the collision probability times the probability the radical pair is in a singlet state. In the second model the intersystem crossing is treated via first-order rate constants which are average values of the hyperfine couplings. Using these rate constants and hydrodynamic diffusion equations, an analytical solution, which accounts for all collisions, is obtained for the geminate recombination. The two reactions studied are photolysis of benzophenone and toluene and the photolytic decomposition of dibenzylketone (1,3-diphenyl-2-propanone). No magnetic isotope effect was observed in the benzophenone reaction. 13 C enrichment was observed for the dibenzylketone reaction, and this enrichment was substantially enhanced at intermediate viscosities and low temperatures. Part II of this dissertation is a presentation of theory and results for the use of Zeeman spin-lattice relaxation as a probe of methyl group rotation in the solid state. Experimental results are presented for the time and angular dependences of rotational polarization, the methyl group magnetic moment, and methyl-methyl steric interactions. The compounds studied are 2,6-dimethylphenol, methyl iodide, 1,4,5,8-tetramethylanthracene, 1,4,5,8-tetramethylnaphthalene, 1,2,4,5-tetramethylbenzene, and 2,3-dimethylmaleicanhydride

  14. Nuclear spin-lattice relaxation of Cu-62 at low temperatures in iron

    Czech Academy of Sciences Publication Activity Database

    Golovko, V. V.; Zákoucký, Dalibor; Srnka, Dušan; Honusek, Milan

    2006-01-01

    Roč. 74, č. 4 (2006), 044313 ISSN 0556-2813 R&D Projects: GA ČR GA202/02/0848 Institutional research plan: CEZ:AV0Z10480505 Keywords : orientation experiments * HPGE detectors * ionization Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 3.327, year: 2006

  15. Determination of acceptable risk criteria for nuclear waste management

    International Nuclear Information System (INIS)

    Cohen, J.J.

    1977-01-01

    The initial phase of the work performed during FY 1977 consisted of performing a ''scoping'' study to define issues, determine an optimal methodology for their resolution, and compile a data base for acceptable risk criteria development. The issues, spanning technical, psychological, and ethical dimensions, were categorized in seven major areas: (1) unplanned or accidental events, (2) present vs future risks, (3) institutional controls and retrievability, (4) dose-response mechanism and uncertainty, (5) spatial distribution of exposed populations, (6) different types of nuclear wastes, and (7) public perception. The optimum methodology for developing ARC was determined to be multi-attribute decision analysis encompassing numerous specific techniques for choosing, from among several alternatives, the optimal course of action when the alternatives are constrained to meet specified attributes. The data base developed during the study comprises existing regulations and guidelines, maximum permissible dose, natural geologic hazards, nonradioactive hazardous waste practices, bioethical perspectives, and data from an opinion survey

  16. Determination of soluble carbon in nuclear grade boron carbide

    International Nuclear Information System (INIS)

    Vega Bustillos, J.O.; Gomes, R.; Camaro, J.; Zorzetto, F.; Domingues, P.; Riella, H.

    1990-05-01

    The present work describes two different techniques (manometric and wet chemical) for the soluble carbon determination in nuclear grade boron carbide. The techniques are based on the reaction of the boron carbide with a sulfocromic mixture, generating CO 2 . The techniques differ on the mode they do the measurement of CO 2 produced. By wet chemical technique the CO 2 is absorved in a barium hydroxide solution and is determinated by titration. In the manometric technique the CO 2 gas is measured using a McLeod gauge. The gas produced by the latter technique is analysed by mass spectrometry. The details of the analytical technique and the data obtained are discussed. (author) [pt

  17. Determination of acceptable risk criteria for nuclear waste management

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, J.J.

    1977-10-21

    The initial phase of the work performed during FY 1977 consisted of performing a ''scoping'' study to define issues, determine an optimal methodology for their resolution, and compile a data base for acceptable risk criteria development. The issues, spanning technical, psychological, and ethical dimensions, were categorized in seven major areas: (1) unplanned or accidental events, (2) present vs future risks, (3) institutional controls and retrievability, (4) dose-response mechanism and uncertainty, (5) spatial distribution of exposed populations, (6) different types of nuclear wastes, and (7) public perception. The optimum methodology for developing ARC was determined to be multi-attribute decision analysis encompassing numerous specific techniques for choosing, from among several alternatives, the optimal course of action when the alternatives are constrained to meet specified attributes. The data base developed during the study comprises existing regulations and guidelines, maximum permissible dose, natural geologic hazards, nonradioactive hazardous waste practices, bioethical perspectives, and data from an opinion survey.

  18. Determination of the physical parameters distribution in spin transition compounds using experimental FORC diagram

    International Nuclear Information System (INIS)

    Tanasa, Radu; Linares, Jorge; Enachescu, Cristian; Varret, Francois; Stancu, Alexandru

    2006-01-01

    Spin transitions materials are characterized with an innovative experimental method, i.e. first-order reversal curve (FORC) diagram. The interpretation of the results is performed in the framework of two different Ising-like models: a mean-field approach and the exact solution done by the Monte Carlo entropic sampling (MCES) method

  19. Criteria for accurate determination of the magnon relaxation length from the nonlocal spin Seebeck effect

    NARCIS (Netherlands)

    Shan, Juan; Cornelissen, Ludo Johannes; Liu, Jing; Ben Youssef, J.; Liang, Lei; van Wees, Bart

    2017-01-01

    The nonlocal transport of thermally generated magnons not only unveils the underlying mechanism of the spin Seebeck effect, but also allows for the extraction of the magnon relaxation length (λm) in a magnetic material, the average distance over which thermal magnons can propagate. In this study, we

  20. Influence of intramolecular f-f interactions on nuclear spin driven quantum tunneling of magnetizations in quadruple-decker phthalocyanine complexes containing two terbium or dysprosium magnetic centers.

    Science.gov (United States)

    Fukuda, Takamitsu; Matsumura, Kazuya; Ishikawa, Naoto

    2013-10-10

    Nuclear spin driven quantum tunneling of magnetization (QTM) phenomena, which arise from admixture of more than two orthogonal electronic spin wave functions through the couplings with those of the nuclear spins, are one of the important magnetic relaxation processes in lanthanide single molecule magnets (SMMs) in the low temperature range. Although recent experimental studies have indicated that the presence of the intramolecular f-f interactions affects their magnetic relaxation processes, little attention has been given to their mechanisms and, to the best of our knowledge, no rational theoretical models have been proposed for the interpretations of how the nuclear spin driven QTMs are influenced by the f-f interactions. Since quadruple-decker phthalocyanine complexes with two terbium or dysprosium ions as the magnetic centers show moderate f-f interactions, these are appropriate to investigate the influence of the f-f interactions on the dynamic magnetic relaxation processes. In the present paper, a theoretical model including ligand field (LF) potentials, hyperfine, nuclear quadrupole, magnetic dipolar, and the Zeeman interactions has been constructed to understand the roles of the nuclear spins for the QTM processes, and the resultant Zeeman plots are obtained. The ac susceptibility measurements of the magnetically diluted quadruple-decker monoterbium and diterbium phthalocyanine complexes, [Tb-Y] and [Tb-Tb], have indicated that the presence of the f-f interactions suppresses the QTMs in the absence of the external magnetic field (H(dc)) being consistent with previous reports. On the contrary, the faster magnetic relaxation processes are observed for [Tb-Tb] than [Tb-Y] at H(dc) = 1000 Oe, clearly demonstrating that the QTMs are rather enhanced in the presence of the external magnetic field. Based on the calculated Zeeman diagrams, these observations can be attributed to the enhanced nuclear spin driven QTMs for [Tb-Tb]. At the H(dc) higher than 2000 Oe, the

  1. Determination of the 14N quadrupole coupling constant of nitroxide spin probes by W-band ELDOR-detected NMR

    Science.gov (United States)

    Florent, Marc; Kaminker, Ilia; Nagarajan, Vijayasarathi; Goldfarb, Daniella

    2011-06-01

    Nitroxide spin probe electron paramagnetic resonance (EPR) has proven to be a very successful method to probe local polarity and solvent hydrogen bonding properties at the molecular level. The g xx and the 14N hyperfine A zz principal values are the EPR parameters of the nitroxide spin probe that are sensitive to these properties and are therefore monitored experimentally. Recently, the 14N quadrupole interaction of nitroxides has been shown to be also highly sensitive to polarity and H-bonding (A. Savitsky et al., J. Phys. Chem. B 112 (2008) 9079). High-field electron spin echo envelope modulation (ESEEM) was used successfully to determine the P xx and P yy principal components of the 14N quadrupole tensor. The P zz value was calculated from the traceless character of the quadrupole tensor. We introduce here high-field (W-band, 95 GHz, 3.5 T) electron-electron double resonance (ELDOR)-detected NMR as a method to obtain the 14N P zz value directly, together with A zz. This is complemented by W-band hyperfine sublevel correlation (HYSCORE) measurements carried out along the g xx direction to determine the principal P xx and P yy components. Through measurements of TEMPOL dissolved in solvents of different polarities, we show that A zz increases, while | P zz| decreases with polarity, as predicted by Savitsky et al.

  2. Electron spin resonance of Gd in the nuclear cooling agent: PrNi5 single crystals

    International Nuclear Information System (INIS)

    Levin, R.; Davidov, D.; Grayevsky, A.; Shaltiel, D.; Zevin, V.

    1980-01-01

    The ESR of Gd in single crystals of PrNi 5 is observed to exhibit significant angular dependence of the resonance position and linewidth at low temperatures. This is interpreted in terms of the axial spin Hamiltonian which takes the anisotropic susceptibility and the Gd-Pr exchange into consideration. From lineshape analysis the axial crystal field parameter and isotropic Gd-Pr exchange are derived. The Gd ESR linewidth increases with temperature; the thermal broadening is angularly dependent. This is similar to that observed for the Pr NMR in PrNi 5 single crystals. Both the NMR and ESR thermal broadenings are attributed to low-frequency fluctuations of the Pr ions induced by the Pr-Pr exchange coupling. A model for hexagonal Van-Vleck compounds is given and with the linewidth enables the Pr-Pr exchange coupling, under the assumption of a Gaussian or a Lorenzian distribution of the low-frequency fluctuation spectra, to be extracted. It is suggested that the angular dependence of the ESR thermal broadening is due to the Gd-Pr exchange coupling. (UK)

  3. Difusão de spins nucleares em meios porosos - uma abordagem computacional da RMN

    OpenAIRE

    Éverton Lucas-Oliveira

    2015-01-01

    A Ressonância Magnética Nuclear (RMN) é uma importante técnica empregada nas principais áreas de conhecimento, tais como, Física, Química e Medicina. Importantes trabalhos da RMN aplicada ao estudo da dinâmica de moléculas em fluidos presentes em meios porosos permitiram que esta técnica ganhasse também notoriedade na indústria do petróleo. O presente projeto é fundamentado em alguns destes trabalhos seminais, reproduzindo, através de modelos físico-computacionais, os principais efeitos físic...

  4. Determination of shell energies. Nuclear deformations and fission barriers

    International Nuclear Information System (INIS)

    Koura, Hiroyuki; Tachibana, Takahiro; Uno, Masahiro; Yamada, Masami.

    1996-01-01

    We have been studying a method of determining nuclear shell energies and incorporating them into a mass formula. The main feature of this method lies in estimating shell energies of deformed nuclei from spherical shell energies. We adopt three assumptions, from which the shell energy of a deformed nucleus is deduced to be a weighted sum of spherical shell energies of its neighboring nuclei. This shell energy should be called intrinsic shell energy since the average deformation energy also acts as an effective shell energy. The ground-state shell energy of a deformed nucleus and its equilibrium shape can be obtained by minimizing the sum of these two energies with respect to variation of deformation parameters. In addition, we investigate the existence of fission isomers for heavy nuclei with use of the obtained shell energies. (author)

  5. Determination of seismic reference motions on nuclear sites in France

    International Nuclear Information System (INIS)

    Levret, A.; Mohammadioun, B.

    1982-08-01

    For the assessment of seismic hazard on a site, the Nuclear Safety Department makes use a seismotectonic method which entails the definition of specific reference motions on each site. It includes two steps: 1. As thorough an analysis as possible of macro-seismic data to define the characteristics (intensity, magnitude, focal distance) of reference earthquakes. 2. The calculation of ground motion from statistical study of strong motion records collected in a data bank. Particular attention has recently been drawn to determining the appropriate manner for taking nearby, low-magnitude earthquarkes into account. The application of this method to an actual case (the July 15, 1980 Kembs earthquake) makes it possible to verify the validity of the method [fr

  6. Determination of 129I in liquid effluent of nuclear facility

    International Nuclear Information System (INIS)

    Zhang Caihong; Song Hailong; Ren Xiaona

    2002-01-01

    An analytical method for 129 I in liquid effluent of nuclear facility is studied. Anion exchange resin is used to concentrated the iodine in water sample, it is extracted by CCl 4 and stripped by NaHSO 3 solution, 129 I is measured by HPGe γ spectrometer in the form of AgI precipitation, it can also be determined by liquid scintillation analyzer directly after purification. For γ spectrometer measurement, the counting efficiency is deduced with the increasing of mass thickness. For liquid scintillation analyzer, it has counting efficiency of 85%. The lowest detective limits of the method is 0.016 Bq/L and 0.037 Bq/L for γ spectrometer and liquid scintillation analyzer, respectively, while the counting time is 1000 min and 100 min respectively. The whole process recovery is range of 60%-85%

  7. Determining the orientation and spin period of TOPEX/Poseidon satellite by a photometric method

    Science.gov (United States)

    Kudak, V. I.; Epishev, V. P.; Perig, V. M.; Neybauer, I. F.

    2017-07-01

    We present the results of photometric observations of the TOPEX/Poseidon satellite performed during 2008-2016. The satellite become space debris after a failure in January, 2006, in a low Earth orbit. In the Laboratory of Space Research of Uzhhorod National University 73 light curves of the spacecraft were obtained. Standardization of photometric light curves is briefly explained. We have calculated the color indices of reflecting surfaces and the spin rate change. The general tendency of the latter is described by an exponential decay function. The satellite spin periods based on 126 light curves (including 53 light curves from the MMT-9 project operating since 2014) were taken into account. In 2016 the period of its own rotation reached its minimum of 10.6 s. A method to derive the direction of the spin axis of an artificial satellite and the angles of the light scattered by its surface has been developed in the Laboratory of Space Research of Uzhhorod National University. We briefly describe the "Orientation" program used for these purposes. The orientation of the TOPEX/Poseidon satellite in mid-2016 is given. The angle of precession β = 45°-50° and period of precession P pr = 141.5 s have been defined. The reasons for the identified nature of the satellite's own rotation have been found. They amount to the perturbation caused by a deviation of the Earth gravity field from a central-symmetric shape and the presence of moving parts on the satellite.

  8. Photoinduced nuclear spin conversion of methyl groups of single molecules; Photoinduzierte Kernspinkonversion von Methylgruppen an einzelnen Molekuelen. Lochbrenn- und Einzelmolekuelspektroskopie an Terrylen und Methylderivaten

    Energy Technology Data Exchange (ETDEWEB)

    Sigl, A.

    2007-12-28

    A methyl group is an outstanding quantum system due to its special symmetry properties. The threefold rotation around one of its bond is isomorphic to the group of even permutations of the remaining protons, a property which imposes severe quantum restrictions on the system, for instance a strict correlation of rotational states with nuclear spin states. The resulting long lifetimes of the rotational tunneling states of the methyl group can be exploited for applying certain high resolution optical techniques, like hole burning or single molecule spectroscopy to optically switch the methyl group from one tunneling state to another therebye changing the nuclear spin of the protons. One goal of the thesis was to perform this switching in single methyl groups. To this end the methyl group was attached to a chromophoric system, in the present case terrylene, which is well suited for single molecule spectroscopy as well as for hole burning. Experiments were performed with the bare terrylene molecule in a hexadecane lattice which served as a reference system, with alphamethyl terrylene and betamethyl terrylene, both embedded in hexadecane, too. A single molecular probe is a highly sensitive detector for dynamic lattice instabilities. Already the bare terrylene probe showed a wealth of interesting local dynamic effects of the hexadecane lattice which could be well acounted for by the assumption of two nearly degenerate sites with rather different optical and thermal properties, all of which could be determined in a quantitative fashion. As to the methylated terrylene systems, the experiments verified that for betamethyl terrylene it is indeed possible to measure rotational tunneling events in single methyl groups. However, the spectral patterns obtained was much more complicated than expected pointing to the presence of three spectroscopically different methyl groups. In order to achieve a definite assignement, molecular mechanics simulations of the terrylene probes in the

  9. Seismic methodology in determining basis earthquake for nuclear installation

    International Nuclear Information System (INIS)

    Ameli Zamani, Sh.

    2008-01-01

    Design basis earthquake ground motions for nuclear installations should be determined to assure the design purpose of reactor safety: that reactors should be built and operated to pose no undue risk to public health and safety from earthquake and other hazards. Regarding the influence of seismic hazard to a site, large numbers of earthquake ground motions can be predicted considering possible variability among the source, path, and site parameters. However, seismic safety design using all predicted ground motions is practically impossible. In the determination of design basis earthquake ground motions it is therefore important to represent the influences of the large numbers of earthquake ground motions derived from the seismic ground motion prediction methods for the surrounding seismic sources. Viewing the relations between current design basis earthquake ground motion determination and modem earthquake ground motion estimation, a development of risk-informed design basis earthquake ground motion methodology is discussed for insight into the on going modernization of the Examination Guide for Seismic Design on NPP

  10. Floating Characteristics of Rudders and Elevators in Spinning Attitudes as Determined From Hinge-Moment-Coefficient Data With Application to Personal-Owner-Type Airplanes

    National Research Council Canada - National Science Library

    Bihrle, William

    1950-01-01

    A study was made of available rudder and elevator hinge-moment-coefficient-coefficient data in order to determine the floating characteristics of various types of rudders and elevators in spinning attitudes...

  11. Spin-polarized 3He nuclear targets and metastable 4He atoms by optical pumping with a tunable, Nd:YAP laser

    International Nuclear Information System (INIS)

    Bohler, C.L.; Schearer, L.D.; Leduc, M.; Nacher, P.J.; Zachorowski, L.; Milner, R.G.; McKeown, R.D.; Woodward, C.E.

    1988-01-01

    Several Nd:YAP lasers were constructed which could be broadly tuned in the 1083-nm region which includes the helium 2 3 S-2 3 P transition, using a Lyot filter and thin, uncoated etalons within the laser cavity. 1 W of power could be extracted at 1083 nm through a 1% transmitting output coupler. This laser beam was used to optically pump metastable 4 He and 3 He 2 3 S helium atoms in a weak discharge cell, spin polarizing the metastable ensemble. In a 3 He cell the polarization is transferred to the nuclear spin system. A 3 He target cell at 0.3 Torr was polarized to 52% in a few minutes. We describe the application of this system to the design of polarized targets for experiments in nuclear physics

  12. Spin-engineered quantum dots

    OpenAIRE

    Fleurov, V.; Ivanov, V. A.; Peeters, F. M.; Vagner, I. D.

    2001-01-01

    Spatially nonhomogeneously spin polarized nuclei are proposed as a new mechanism to monitor electron states in a nanostructure, or as a means to createn and, if necessary, reshape such nanostructures in the course of the experiment. We found that a polarization of nulear spins may lift the spin polarization of the electron states in a nanostructure and, if sufficiently strong, leads to a polarization of the electron spins. Polarized nuclear spins may form an energy landscape capable of bindin...

  13. Development of Millimeter Wave Fabry-Pérot Resonator for Simultaneous Electron-Spin and Nuclear Magnetic Resonance Measurement

    Science.gov (United States)

    Ishikawa, Yuya; Ohya, Kenta; Fujii, Yutaka; Fukuda, Akira; Miura, Shunsuke; Mitsudo, Seitaro; Yamamori, Hidetomo; Kikuchi, Hikomitsu

    2018-04-01

    We report a Fabry-Pérot resonator with spherical and flat mirrors to allow simultaneous electron-spin resonance (ESR) and nuclear magnetic resonance (NMR) measurements that could be used for double magnetic resonance (DoMR). In order to perform simultaneous ESR and NMR measurements, the flat mirror must reflect millimeter wavelength electromagnetic waves and the resonator must have a high Q value ( Q > 3000) for ESR frequencies, while the mirror must simultaneously let NMR frequencies pass through. This requirement can be achieved by exploiting the difference of skin depth for the two frequencies, since skin depth is inversely proportional to the square root of the frequency. In consideration of the skin depth, the optimum conditions for conducting ESR and NMR using a gold thin film are explored by examining the relation between the Q value and the film thickness. A flat mirror with a gold thin film was fabricated by sputtering gold on an epoxy plate. We also installed a Helmholtz radio frequency coil for NMR and tested the system both at room and low temperatures with an optimally thick gold film. As a result, signals were obtained at 0.18 K for ESR and at 1.3 K for NMR. A flat-mirrored resonator with a thin gold film surface is an effective way to locate NMR coils closer to the sample being examined with DoMR.

  14. Anomalous 125Te Nuclear Spin Relaxation Coincident with Charge Kondo Behavior in Superconducting Pb1-xTlxTe

    Science.gov (United States)

    Mukuda, Hidekazu; Matsumura, Takashi; Maki, Shota; Yashima, Mitsuharu; Kitaoka, Yoshio; Miyake, Kazumasa; Murakami, Hironaru; Giraldo-Gallo, Paula; Geball, Theodore H.; Fisher, Ian R.

    2018-02-01

    We report the results of a 125Te NMR study of single crystalline Pb1-xTlxTe (x = 0, 0.35, 1.0%) as a window on the novel electronic states associated with the thallium impurities in PbTe. The Knight shift is enhanced as x increases, corresponding to an increase in the average density of states (DOS) coupled to a strong spatial variation in the local DOS surrounding each Tl dopant. Remarkably, for the superconducting composition (x = 1.0%), the 125Te nuclear spin relaxation rate (1/T1T) for Te ions that are close to the Tl dopants is unexpectedly enhanced in the normal state below a characteristic temperature of ˜10 K, below which the resistivity experiences an upturn. Such a simultaneous upturn in both the resistivity and (1/T1T) was not suppressed in the high magnetic field. We suggest that these observations are consistently accounted for by dynamical charge fluctuations in the absence of paramagnetism, which is anticipated by the charge Kondo scenario associated with the Tl dopants. In contrast, such anomalies were not detected in the non-superconducting samples (x = 0 and 0.35%), suggesting a connection between dynamical valence fluctuations and the occurrence of superconductivity in Pb1-xTlxTe.

  15. Direct observation of low energy nuclear spin excitations in HoCrO3 by high resolution neutron spectroscopy.

    Science.gov (United States)

    Chatterji, T; Jalarvo, N; Kumar, C M N; Xiao, Y; Brückel, Th

    2013-07-17

    We have investigated low energy nuclear spin excitations in the strongly correlated electron compound HoCrO3. We observe clear inelastic peaks at E = 22.18 ± 0.04 μeV in both energy loss and gain sides. The energy of the inelastic peaks remains constant in the temperature range 1.5-40 K at which they are observed. The intensity of the inelastic peak increases at first with increasing temperature and then decreases at higher temperatures. The temperature dependence of the energy and intensity of the inelastic peaks is very unusual compared to that observed in other Nd, Co, V and also simple Ho compounds. Huge quasielastic scattering appears at higher temperatures presumably due to the fluctuating electronic moments of the Ho ions that get increasingly disordered at higher temperatures. The strong quasielastic scattering may also originate in the first Ho crystal-field excitations at about 1.5 meV.

  16. Near-Surface Structural Phase Transition of SrTiO3 Studied with Zero-Field β-Detected Nuclear Spin Relaxation and Resonance

    Science.gov (United States)

    Salman, Z.; Kiefl, R. F.; Chow, K. H.; Hossain, M. D.; Keeler, T. A.; Kreitzman, S. R.; Levy, C. D. P.; Miller, R. I.; Parolin, T. J.; Pearson, M. R.; Saadaoui, H.; Schultz, J. D.; Smadella, M.; Wang, D.; Macfarlane, W. A.

    2006-04-01

    We demonstrate that zero-field β-detected nuclear quadrupole resonance and spin relaxation of low energy Li8 can be used as a sensitive local probe of structural phase transitions near a surface. We find that the transition near the surface of a SrTiO3 single crystal occurs at Tc˜150K, i.e., ˜45K higher than Tcbulk, and that the tetragonal domains formed below Tc are randomly oriented.

  17. Recycling of radioactively contaminated scrap from the nuclear cycle and spin-off for other application

    Directory of Open Access Journals (Sweden)

    Quade, U.

    2005-12-01

    Full Text Available In the 1980ies, Siempelkamp foundry in Krefeld, Germany, developed a process to melt medium and slightly radioactive metals from decommissioning and maintenance works in nuclear power plants. Since 1989, in the CARLA melting plant which is licensed according to the German radiation protection ordinance (StrlSchV, metals are being molten which, for the largest part, can be reused. Since 1998, in a second plant, the GERTA melting plant, metals with a content of mercury up to 1 weight %, natural radioactivity up to 500 Bq/g and other chemical contaminations are being molten and completely decontaminated, so that these metals can be reused in the steel cycle. The following text is describing the melting process, acceptance criteria for contaminated scrap and recycling paths for the produced ingots and slags.

    La fundición Siempelkamp en Krefeld, Alemania, desarrolló, en los años 80, un proceso para fundir metales mediana y levemente radioactivos, procedentes de reparaciones o desmantelamiento de plantas nucleares. En la planta de fundición CARLA, que cumple los requisitos del decreto de protección contra radiaciones de la República Federal de Alemania, se funden metales desde 1989, de los cuales la mayor parte puede ser utilizada nuevamente. Desde 1998, en una segunda planta, fundición GERTA, se funden y descontaminan totalmente, metales de hasta un 1 % de peso de mercurio, con una radioactividad natural de hasta 500 Bq/g y con otros contaminantes químicos. De este modo los metales pueden ser nuevamente utilizados en el ciclo metálico. El texto adjunto describe el método para el fundido, los criterios para aceptar chatarra contaminada y las vías de utilización para los bloques de metal y escorias generadas en el proceso.

  18. Effects of strain and quantum confinement in optically pumped nuclear magnetic resonance in GaAs: Interpretation guided by spin-dependent band structure calculations

    Science.gov (United States)

    Wood, R. M.; Saha, D.; McCarthy, L. A.; Tokarski, J. T.; Sanders, G. D.; Kuhns, P. L.; McGill, S. A.; Reyes, A. P.; Reno, J. L.; Stanton, C. J.; Bowers, C. R.

    2014-10-01

    A combined experimental-theoretical study of optically pumped nuclear magnetic resonance (OPNMR) has been performed in a GaAs /A l0.1G a0.9As quantum well film epoxy bonded to a Si substrate with thermally induced biaxial strain. The photon energy dependence of the Ga OPNMR signal was recorded at magnetic fields of 4.9 and 9.4 T at a temperature of 4.8-5.4 K. The data were compared to the nuclear spin polarization calculated from the electronic structure and differential absorption to spin-up and spin-down states of the electron conduction band using a modified k .p model based on the Pidgeon-Brown model. Comparison of theory with experiment facilitated the assignment of features in the OPNMR energy dependence to specific interband Landau level transitions. The results provide insight into how effects of strain and quantum confinement are manifested in optical nuclear polarization in semiconductors.

  19. Determination of E and G Observables in n Photoproduction on the CLAS Frozen Spin Target (FROST)

    Energy Technology Data Exchange (ETDEWEB)

    Senderovich, Igor [University of Connecticut, Storrs, CT (United States); Morrison, Brian T. [Arizona State University, Tempe, AZ (United States); Dugger, Michael R. [Arizona State University, Tempe, AZ (United States); Ritchie, Barry G. [Arizona State University, Tempe, AZ (United States); Tucker, Ross J. [Arizona State University, Tempe, AZ (United States)

    2014-01-01

    Polarization observables are vital for disentangling overlapping resonances in the baryon spectrum. Extensive data have been collected at Jefferson Lab in Hall B with circularly and linearly polarized tagged photon beam incident on longitudinally polarized protons provided by the Frozen Spin Target (FROST). The focus of the described work is on η photoproduction, which acts as an "isospin filter", isolating the N*(I = 1/2) resonances. Preliminary results for the double-polarization observables E and G are presented. There are currently no data on these in the world database for η photoproduction.

  20. Single-Spin Polarization Effects and the Determination of Timelike Proton Form Factors

    Energy Technology Data Exchange (ETDEWEB)

    Brodsky, S

    2003-10-24

    We show that measurements of the proton's polarization in e{sup +}e{sup -} {yields} p{bar p} strongly discriminate between analytic forms of models which fit the proton form factors in the spacelike region. In particular, the single-spin asymmetry normal to the scattering plane measures the relative phase difference between the timelike G{sub E} and G{sub M} form factors. The expected proton polarization in the timelike region is large, of order of several tens of percent.

  1. Observation of the decay eta/sub c/. -->. phiphi and determination of the eta/sub c/ spin and parity

    Energy Technology Data Exchange (ETDEWEB)

    Baltrusaitis, R.M.; Becker, J.J.; Blaylock, G.T.; Brown, J.S.; Bunnell, K.O.; Burnett, T.H.; Cassell, R.E.; Coffman, D.; Cook, V.; Coward, D.H.

    1984-06-11

    In a study of 2.7 million J/psi decays with the Mark III, a new magnetic detector at SPEAR, we have observed the sequential decay J/psi..--> gamma..eta/sub c/, eta/sub c/..-->..phiphi. The product branching fraction is (1.02 +- 0.25 +- 0.14) x 10/sup -4/, where the quoted errors are statistical and systematic, respectively. Analysis of the final-state angular distributions provides the first experimental determination that the spin and parity of the eta/sub c/ are 0/sup -/.

  2. Three-stage decoherence dynamics of an electron spin qubit in an optically active quantum dot

    Science.gov (United States)

    Bechtold, Alexander; Rauch, Dominik; Li, Fuxiang; Simmet, Tobias; Ardelt, Per-Lennart; Regler, Armin; Müller, Kai; Sinitsyn, Nikolai A.; Finley, Jonathan J.

    2015-12-01

    The control of solid-state qubits requires a detailed understanding of the decoherence mechanisms. Despite considerable progress in uncovering the qubit dynamics in strong magnetic fields, decoherence at very low magnetic fields remains puzzling, and the role of quadrupole coupling of nuclear spins is poorly understood. For spin qubits in semiconductor quantum dots, phenomenological models of decoherence include two basic types of spin relaxation: fast dephasing due to static but randomly distributed hyperfine fields (~2 ns) and a much slower process (>1 μs) of irreversible monotonic relaxation due either to nuclear spin co-flips or other complex many-body interaction effects. Here we show that this is an oversimplification; the spin qubit relaxation is determined by three rather than two distinct stages. The additional stage corresponds to the effect of coherent precession processes that occur in the nuclear spin bath itself, leading to a relatively fast but incomplete non-monotonic relaxation at intermediate timescales (~750 ns).

  3. Factors determining the UK's back-end nuclear fuel cycle strategy and future nuclear systems

    International Nuclear Information System (INIS)

    Dunn, M.J.; Ainsworth, Z.E.

    2002-01-01

    Nuclear generating capacity in the UK is static with no units currently under construction. The AGRs and the UK's only PWR, Sizewell B, are operated by British Energy Generation Ltd (BEGL) and British Energy Generation (UK) Ltd (BEG(UK)L), who are subsidiaries of British Energy plc (BE) which was privatised in July 1996. Ownership of the Magnox stations, which were excluded from this privatisation, has now been transferred to BNFL.Government policy on spent fuel management in the UK is that it is for the owners of the spent fuel to decide on the appropriate spent fuel management options, based on their own commercial judgement, subject to meeting the necessary regulatory requirements. The main factors which have predominantly determined UK utility decisions on spent fuel management, to date, have been based on the technical considerations of the spent fuel characteristics, economic attractiveness of the options and at reactor site spent fuel storage capacities. To date, reprocessing has been the dominant form of spent fuel treatment in the UK. Spent fuel storage facilities consist of a mixture of at-reactor stores and large, centralised ponds associated with the reprocessing activities which take place at the Sellafield site. BEGL and BEG(UK)L have contracts for the lifetime arisings of AGR fuel which allow for all AGR spent fuel to be sent to Sellafield for reprocessing or long-term storage. The prompt reprocessing of all Magnox fuel will continue, and spent PWR fuel will continue to be stored at the reactor site in the short to medium term. It is likely that a combination of factors, which are discussed later in this paper, will continue to affect back-end nuclear fuel cycle strategy and future nuclear systems. (author)

  4. Quantum communication through a spin chain with interaction determined by a Jacobi matrix

    International Nuclear Information System (INIS)

    Chakrabarti, R; Van der Jeugt, J

    2010-01-01

    We obtain the time-dependent correlation function describing the evolution of a single spin excitation state in a linear spin chain with isotropic nearest-neighbour XY coupling, where the Hamiltonian is related to the Jacobi matrix of a set of orthogonal polynomials. For the Krawtchouk polynomial case, an arbitrary element of the correlation function is expressed in a simple closed form. Its asymptotic limit corresponds to the Jacobi matrix of the Charlier polynomial, and may be understood as a unitary evolution resulting from a Heisenberg group element. Correlation functions for Hamiltonians corresponding to Jacobi matrices for the Hahn, dual Hahn and Racah polynomials are also studied. For the Hahn polynomials we obtain the general correlation function, some of its special cases and the limit related to the Meixner polynomials, where the su(1, 1) algebra describes the underlying symmetry. For the cases of dual Hahn and Racah polynomials, the general expressions of the correlation functions contain summations which are not of hypergeometric type. Simplifications, however, occur in special cases.

  5. Determination of BWR Spent Nuclear Fuel Assembly Effective Thermal Conductivity

    Energy Technology Data Exchange (ETDEWEB)

    Matthew D. Hinds

    2001-10-17

    The purpose of this calculation is to provide an effective thermal conductivity for use in predicting peak cladding temperatures in boiling water reactor (BWR) fuel assemblies with 7x7,8x8, and 9x9 rod arrays. The first objective of this calculation is to describe the development and application of a finite element representation that predicts peak spent nuclear fuel temperatures for BWR assemblies. The second objective is to use the discrete representation to develop a basis for determining an effective thermal conductivity (described later) for a BWR assembly with srneared/homogeneous properties and to investigate the thermal behavior of a spent fuel assembly. The scope of this calculation is limited to a steady-state two-dimensional representation of the waste package interior region. This calculation is subject to procedure AP-3.124, Calculations (Ref. 27) and guided by the applicable technical work plan (Ref. 14). While these evaluations were originally developed for the thermal analysis of conceptual waste package designs emplaced in the potential repository at Yucca Mountain, the methodology applies to storage and transportation thermal analyses as well. Note that the waste package sketch in Attachment V depicts a preliminary design, and should not be interpreted otherwise.

  6. Some studies about conformal invariance in the determination of Schroedinger relativistic equation for free zero mass particles and arbitrary spin

    International Nuclear Information System (INIS)

    Siqueira, J.R.R.

    1984-01-01

    The question of how far the requirement of invariance under the continuous conformal group determines relativistic Schroedinger wave equations for (free) zero mass particles of arbitrary spin is rised. First, the conditions to be satisfied by the Hamiltonian operator appearing in the Schroedinger wave equation i∂Ψ/∂t= H Ψ (with Ψ transforming locally under homogeneous Lorentz transformations) are derived such that the wave equation is invariant individually under boosts, dilatations and special conformal transformations of the conformal group whose generators are in the local forms given by Mack and Salam for Type Ia fields. Then starting with the most general form of the Hamiltonian for the spin s case, invariant under translations and rotations, the boost, dilatational and special conformal invariance conditions are applied on H so as to make an explicit determination of the solutions for H when ψ transforms according (i) D(o,s) (ii) D(s,o) and (iii) D(o,s) + D(s,o) representation of the Homogeneous Lorentz group. (E.G.) [pt

  7. A nuclear magnetic resonance and electron spin resonance study on the dynamics of pentacoordinated organophosphorus compounds

    International Nuclear Information System (INIS)

    Keijzer, A.E.H. de.

    1988-01-01

    In this thesis the role of the steric and electronic effects on the fundamental dynamic behaviour of pentacoordinated phosporus compounds is further elaborated. In chapter 2 a variable temperature 13 C NMR study, performed on a series of monocyclic oxyphosphoranes, is presented. The investigations were carried out to determine the influence of the conformational transmission effect on the barriers to pseudorotation in pentacoordinated phosphorus compounds. Chapter 3 also comprises a variable temperature 13 C NMR study on pentacoordinated phosphorus compounds. In this chapter, however, an additional high-resolution 1 H NMR study on the conformational equilibria around the P-O-C-C-O fragments is included. These studies were performed in order to determine whether the enhancement of the reorganization rates around phosphorus is brought about by accelerated pseudorotation or by the involvement of hexacoordinated zwitterionic phosphorus intermediates. In chapter 4, a 31 P NMR study on the solvolysis rate of several phosphinate esters is described. This study was performed in order to determine the influence of the conformational transmission effect on the solvolysis rate of phosphate esters. A number of phosphates is examined in which, during the course of the solvolysis reaction, the conformational transmission effect is bound to be present or absent respectively. Moreover, it is discussed in which way the concept of conformational transmission induced differences in solvolysis rates can be used as a probe to examine the reactions of biologically important phosphate esters. In chapters 5 and 6 ESR studies on the influence of steric and electronic factors on phosphoranyl formation in solution, and on the intramolecular electron transfer in phosphoranyl radicals are presented. (author). 121 refs.; 33 figs.; 17 figs

  8. ESR (electron spin resonance)-determined osmotic behavior of bull spermatozoa

    Energy Technology Data Exchange (ETDEWEB)

    Du, J.; Kleinhans, F.W.; Spitzer, V.J.; Critser, J.K. (Methodist Hospital, Indianapolis, IN (USA). Dept. of Medical Research); Horstman, L. (Purdue Univ., Lafayette, IN (USA). School of Veterinary Medicine); Mazur, P. (Oak Ridge National Lab., TN (USA))

    1990-01-01

    Our laboratories are pursuing a fundamental approach to the problems of semen cryopreservation. For many cell types (human red cells, yeast, HeLa) it has been demonstrated that there is an optimum cooling rate for cryopreservation. Faster rates allow insufficient time for cell dehydration and result in intracellular ice formation and cell death. It is possible to predict this optimal rate provided that the cell acts as an ideal osmometer and several other cell parameters are known such as the membrane hydraulic conductivity. It is the purpose of this work to examine the osmotic response of bull sperm to sucrose and NaCl utilizing electron spin resonance (ESR) to measure cell volume. For calibration purposes we also measured the ESR response of human red cells (RBC), the osmotic response of which is well documented with other methods. 15 refs., 1 fig.

  9. Design of a triple resonance magic angle sample spinning probe for high field solid state nuclear magnetic resonance

    Science.gov (United States)

    Martin, Rachel W.; Paulson, Eric K.; Zilm, Kurt W.

    2003-06-01

    Standard design and construction practices used in building nuclear magnetic resonance (NMR) probes for the study of solid state samples become difficult if not entirely impractical to implement as the 1H resonance frequency approaches the self resonance frequency of commercial capacitors. We describe an approach that utilizes short variable transmission line segments as tunable reactances. Such an approach effectively controls stray reactances and provides a higher Q alternative to ceramic chip capacitors. The particular probe described is built to accommodate a 2.5 mm magic angle spinning rotor system, and is triply tuned to 13C, 15N, and 1H frequencies for use at 18.8 T (200, 80, and 800 MHz, respectively). Isolation of the three radio frequency (rf) channels is achieved using both a rejection trap and a transmission line notch filter. The compact geometry of this design allows three channels with high power handling capability to fit in a medium bore (63 mm) magnet. Extended time variable temperature operation is integral to the mechanical design, enabling the temperature control necessary for investigation of biological macromolecules. Accurate measurement of the air temperature near the sample rotor is achieved using a fiber optic thermometer, which does not interfere with the rf electronics. We also demonstrate that acceptable line shapes are only readily achieved using zero magnetic susceptibility wire in construction of the sample coil. Computer simulation of the circuit aided in the physical design of the probe. Representative data illustrating the efficiency, rf homogeneity, and signal to noise factor of the probe are presented.

  10. A study on the improvement of spin-off effectiveness of national nuclear R and D activities

    International Nuclear Information System (INIS)

    Yang, Maeng Ho; Lee, T. J.

    1997-02-01

    This study consists of two parts. One is to identify factors affecting technological effectiveness of the spin-off process that is defined as the technology transfer process from government sponsored research institutes (GRI's) to the civilian sector. The other is to analyze the environment of the spin-off process and to suggest guidelines for addition, this study also examines spin-off effectiveness with technology transfer types. To validate the conceptual model and hypotheses of the spin-off process, data are collected from 12 cases through in-depth interviews and questionnaires. Spearman correlation analysis is employed in order to test the hypotheses on the spin-off process. (author). 50 refs., 17 tabs., 12 figs

  11. Nuclear spin relaxation of 8Li in a thin film of La 0.67Ca 0.33MnO 3

    Science.gov (United States)

    Miller, R. I.; Arseneau, D.; Chow, K. H.; Daviel, S.; Engelbertz, A.; Hossain, MD.; Keeler, T.; Kiefl, R. F.; Kreitzman, S.; Levy, C. D. P.; Morales, P.; Morris, G. D.; MacFarlane, W. A.; Parolin, T. J.; Poutissou, R.; Saadaoui, H.; Salman, Z.; Wang, D.; Wei, J. Y. T.

    2006-03-01

    We report β-NMR measurements of the nuclear spin relaxation rate (1/T1) in a thin film of La 0.67Ca 0.33MnO 3 (LCMO) using a low-energy beam of spin-polarized 8Li. In a small magnetic field of 150 G, there is a broad peak in 1/T1 near the Curie temperature (Tc=259 K) and a dramatic decrease in 1/T1 at lower temperatures. This is attributed to a critical slowing down of the spin fluctuations near Tc and freezing of the magnetic excitations at low temperatures, respectively. In addition, there is a small amplitude, slow relaxing component at high temperatures, which we attribute to 8Li in the SrTiO 3 substrate. There is an indication that the spin relaxation rate in the substrate is also peaked at Tc due to close proximity to the magnetic film. These results establish that low-energy β-NMR can be used as a probe of magnetic fluctuations in magnetic thin films over a wide range of temperatures.

  12. Nuclear spin effect on recombination of H₃⁺ ions with electrons at 77 K.

    Science.gov (United States)

    Varju, J; Hejduk, M; Dohnal, P; Jílek, M; Kotrík, T; Plašil, R; Gerlich, D; Glosík, J

    2011-05-20

    Utilizing different ratios of para to ortho H₂ in normal and para enriched hydrogen, we varied the population of para-H₃⁺ in an H₃⁺ dominated plasma at 77 K. Absorption spectroscopy was used to measure the densities of the two lowest rotational states of H₃⁺. Monitoring plasma decays at different populations of para-H₃⁺ allowed us to determine the rate coefficients for binary recombination of para-H₃⁺ and ortho-H₃⁺ ions: (p)α(bin)(77 K) = (1.9 ± 0.4) × 10⁻⁷ cm³ s⁻¹ and (o)α(bin)(77 K) = (0.2 ± 0.2) × 10⁻⁷ cm³ s⁻¹.

  13. Nuclear Spin Effect on Recombination of H3+ Ions with Electrons at 77 K

    Science.gov (United States)

    Varju, J.; Hejduk, M.; Dohnal, P.; Jílek, M.; Kotrík, T.; Plašil, R.; Gerlich, D.; Glosík, J.

    2011-05-01

    Utilizing different ratios of para to ortho H2 in normal and para enriched hydrogen, we varied the population of para-H3+ in an H3+ dominated plasma at 77 K. Absorption spectroscopy was used to measure the densities of the two lowest rotational states of H3+. Monitoring plasma decays at different populations of para-H3+ allowed us to determine the rate coefficients for binary recombination of H3+ and ortho-H3+ ions: αbinp(77K)=(1.9±0.4)×10-7cm3s-1 and αbino(77K)=(0.2±0.2)×10-7cm3s-1.

  14. Nuclear Spin Effect on Recombination of H3+ Ions with Electrons at 77 K

    International Nuclear Information System (INIS)

    Varju, J.; Hejduk, M.; Dohnal, P.; Jilek, M.; Kotrik, T.; Plasil, R.; Gerlich, D.; Glosik, J.

    2011-01-01

    Utilizing different ratios of para to ortho H 2 in normal and para enriched hydrogen, we varied the population of para-H 3 + in an H 3 + dominated plasma at 77 K. Absorption spectroscopy was used to measure the densities of the two lowest rotational states of H 3 + . Monitoring plasma decays at different populations of para-H 3 + allowed us to determine the rate coefficients for binary recombination of H 3 + and ortho-H 3 + ions: p α bin (77 K)=(1.9±0.4)x10 -7 cm 3 s -1 and o α bin (77 K)=(0.2±0.2)x 10 -7 cm 3 s -1 .

  15. Comparison of different techniques to determine long spin lifetimes in slightly n-doped GaAs bulk and GaAs/AlGaAs quantum wells

    Energy Technology Data Exchange (ETDEWEB)

    Griesbeck, Michael; Maurer, Andreas; Fehringer, Sebastian; Schulz, Robert; Korn, Tobias; Schuh, Dieter; Wegscheider, Werner; Schueller, Christian [Universitaet Regensburg (Germany)

    2009-07-01

    A key issue of spintronics research is the search for materials with long spin lifetime. The commonly used technique for the determination of spin lifetimes, ultrafast time-resolved Faraday/Kerr rotation (TRFR/TRKR), is limited to a short time window of a few ns by some reasons like the pulse repetition rate of the used pulsed laser or the length of the available delay line.Here we present a study about the comparison of the well-known TRFR technique with two other optical techniques, the so-called resonant spin amplification technique (RSA) on the one hand and Hanle-MOKE measurements on the other hand. The measurements are done on samples of slightly n-doped GaAs bulk and Mn-doped GaAs/AlGaAs quantum wells, where long spin lifetimes were detected earlier. We compare the results for spin lifetime from the different techniques in 3D and 2D systems. Spin lifetimes were extracted for different excitation and probing intensities for different Laser spot sizes, partially using a microscope setup, focussing the spot down to a few microns. The observed spin lifetimes range from about 1 ns to 120 ns and could be measured with an accuracy of a few percent.

  16. Determination of nuclear moments in experiments on charged particle beams

    International Nuclear Information System (INIS)

    Hrynkiewicz, A.Z.

    Nuclear magnetic moment measurements by in-beam perturbed angular correlation method are discussed, with special emphasis on the use of transient fields. Measurements on states in several sd and dsup(5/2) nuclei are reported [fr

  17. Determination Public Acceptance Segmentation for Nuclear Power Program Interest

    International Nuclear Information System (INIS)

    Syirrazie Che Soh; Aini Wahidah Abdul Wahab

    2012-01-01

    This paper is focus to discuss segmentation aspect among inter-disciplinary group of public. This discussion is the pre-stage to ensure the right initiative strategies are implemented to gain public interest and acceptance towards on developing nuclear power plant. The applied strategies are implemented based on different interest among the different groups of public. These strategies may increase public acceptance level towards developing nuclear power plant. (author)

  18. Spin-analyzed SANS for soft matter applications

    Science.gov (United States)

    Chen, W. C.; Barker, J. G.; Jones, R.; Krycka, K. L.; Watson, S. M.; Gagnon, C.; Perevozchivoka, T.; Butler, P.; Gentile, T. R.

    2017-06-01

    The small angle neutron scattering (SANS) of nearly Q-independent nuclear spin-incoherent scattering from hydrogen present in most soft matter and biology samples may raise an issue in structure determination in certain soft matter applications. This is true at high wave vector transfer Q where coherent scattering is much weaker than the nearly Q-independent spin-incoherent scattering background. Polarization analysis is capable of separating coherent scattering from spin-incoherent scattering, hence potentially removing the nearly Q-independent background. Here we demonstrate SANS polarization analysis in conjunction with the time-of-flight technique for separation of coherent and nuclear spin-incoherent scattering for a sample of silver behenate back-filled with light water. We describe a complete procedure for SANS polarization analysis for separating coherent from incoherent scattering for soft matter samples that show inelastic scattering. Polarization efficiency correction and subsequent separation of the coherent and incoherent scattering have been done with and without a time-of-flight technique for direct comparisons. In addition, we have accounted for the effect of multiple scattering from light water to determine the contribution of nuclear spin-incoherent scattering in both the spin flip channel and non-spin flip channel when performing SANS polarization analysis. We discuss the possible gain in the signal-to-noise ratio for the measured coherent scattering signal using polarization analysis with the time-of-flight technique compared with routine unpolarized SANS measurements.

  19. Solvent Effects on Nuclear Magnetic Resonance 2J(C,Hf and 1J(C,Hf Spin–Spin Coupling Constants in Acetaldehyde

    Directory of Open Access Journals (Sweden)

    Angel Esteban

    2003-02-01

    Full Text Available Abstract: The known solvent dependence of 1J(Cc,Hf and 2J(C1,Hf couplings in acetaldehyde is studied from a theoretical viewpoint based on the density functional theory approach where the dielectric solvent effect is taken into account with the polarizable continuum model. The four terms of scalar couplings, Fermi contact, paramagnetic spin orbital, diamagnetic spin orbital and spin dipolar, are calculated but the solvent effect analysis is restricted to the first term since for both couplings it is by far the dominant contribution. Experimental trends of Δ1J(Cc,Hf and Δ2J(C1,Hf Vs ε (the solvent dielectric constant are correctly reproduced although they are somewhat underestimated. Specific interactions between solute and solvent molecules are studied for dimethylsulfoxide, DMSO, solutions considering two different one-to-one molecular complexes between acetaldehyde and DMSO. They are determined by interactions of type C=O---H---C and S=O---H---C, and the effects of such interactions on 1J(Cc,Hf and 2J(C1,Hf couplings are analyzed. Even though only in a semiquantitative way, it is shown that the effect of such interactions on the solvent effects, of Δ1J(Cc,Hf and Δ2J(C1,Hf, tend to improve the agreement between calculated and experimental values. These results seem to indicate that a continuum dielectric model has not enough flexibility for describing quantitatively solvent effects on spin-spin couplings. Apparently, even for relatively weak hydrogen bonding, the contribution from “direct” interactions is of the same order of magnitude as the “dielectric” effect.

  20. Nuclear magnetic relaxation by the dipolar EMOR mechanism: General theory with applications to two-spin systems.

    Science.gov (United States)

    Chang, Zhiwei; Halle, Bertil

    2016-02-28

    In aqueous systems with immobilized macromolecules, including biological tissue, the longitudinal spin relaxation of water protons is primarily induced by exchange-mediated orientational randomization (EMOR) of intra- and intermolecular magnetic dipole-dipole couplings. We have embarked on a systematic program to develop, from the stochastic Liouville equation, a general and rigorous theory that can describe relaxation by the dipolar EMOR mechanism over the full range of exchange rates, dipole coupling strengths, and Larmor frequencies. Here, we present a general theoretical framework applicable to spin systems of arbitrary size with symmetric or asymmetric exchange. So far, the dipolar EMOR theory is only available for a two-spin system with symmetric exchange. Asymmetric exchange, when the spin system is fragmented by the exchange, introduces new and unexpected phenomena. Notably, the anisotropic dipole couplings of non-exchanging spins break the axial symmetry in spin Liouville space, thereby opening up new relaxation channels in the locally anisotropic sites, including longitudinal-transverse cross relaxation. Such cross-mode relaxation operates only at low fields; at higher fields it becomes nonsecular, leading to an unusual inverted relaxation dispersion that splits the extreme-narrowing regime into two sub-regimes. The general dipolar EMOR theory is illustrated here by a detailed analysis of the asymmetric two-spin case, for which we present relaxation dispersion profiles over a wide range of conditions as well as analytical results for integral relaxation rates and time-dependent spin modes in the zero-field and motional-narrowing regimes. The general theoretical framework presented here will enable a quantitative analysis of frequency-dependent water-proton longitudinal relaxation in model systems with immobilized macromolecules and, ultimately, will provide a rigorous link between relaxation-based magnetic resonance image contrast and molecular parameters.

  1. Nuclear Spin Relaxation

    Indian Academy of Sciences (India)

    IAS Admin

    Nuclei occur in many different species, called nuclides, which are defined by the numbers of protons and neutrons they contain. The chemical nature of an atom is defined by the number of protons in its nucleus. For example, all atoms of carbon have six protons in the nucleus, and all atoms of hydrogen have a single proton ...

  2. Pairwise NMR experiments for the determination of protein backbone dihedral angle Φ based on cross-correlated spin relaxation

    International Nuclear Information System (INIS)

    Takahashi, Hideo; Shimada, Ichio

    2007-01-01

    Novel cross-correlated spin relaxation (CCR) experiments are described, which measure pairwise CCR rates for obtaining peptide dihedral angles Φ. The experiments utilize intra-HNCA type coherence transfer to refocus 2-bond J NCα coupling evolution and generate the N (i)-C α (i) or C'(i-1)-C α (i) multiple quantum coherences which are required for measuring the desired CCR rates. The contribution from other coherences is also discussed and an appropriate setting of the evolution delays is presented. These CCR experiments were applied to 15 N- and 13 C-labeled human ubiquitin. The relevant CCR rates showed a high degree of correlation with the Φ angles observed in the X-ray structure. By utilizing these CCR experiments in combination with those previously established for obtaining dihedral angle Ψ, we can determine high resolution structures of peptides that bind weakly to large target molecules

  3. Near-surface structural phase transition of SrTiO3 studied with zero-field beta-detected nuclear spin relaxation and resonance.

    Science.gov (United States)

    Salman, Z; Kiefl, R F; Chow, K H; Hossain, M D; Keeler, T A; Kreitzman, S R; Levy, C D P; Miller, R I; Parolin, T J; Pearson, M R; Saadaoui, H; Schultz, J D; Smadella, M; Wang, D; MacFarlane, W A

    2006-04-14

    We demonstrate that zero-field beta-detected nuclear quadrupole resonance and spin relaxation of low energy (8)Li can be used as a sensitive local probe of structural phase transitions near a surface. We find that the transition near the surface of a SrTiO(3) single crystal occurs at T(c) approximately 150K, i.e., approximately 45K higher than T(c)bulk, and that the tetragonal domains formed below T(c) are randomly oriented.

  4. Nuclear Spin Lattice Relaxation and Conductivity Studies of the Non-Arrhenius Conductivity Behavior in Lithium Fast Ion Conducting Sulfide Glasses

    Energy Technology Data Exchange (ETDEWEB)

    Meyer, Benjamin Michael [Iowa State Univ., Ames, IA (United States)

    2003-01-01

    As time progresses, the world is using up more of the planet's natural resources. Without technological advances, the day will eventually arrive when these natural resources will no longer be sufficient to supply all of the energy needs. As a result, society is seeing a push for the development of alternative fuel sources such as wind power, solar power, fuel cells, and etc. These pursuits are even occurring in the state of Iowa with increasing social pressure to incorporate larger percentages of ethanol in gasoline. Consumers are increasingly demanding that energy sources be more powerful, more durable, and, ultimately, more cost efficient. Fast Ionic Conducting (FIC) glasses are a material that offers great potential for the development of new batteries and/or fuel cells to help inspire the energy density of battery power supplies. This dissertation probes the mechanisms by which ions conduct in these glasses. A variety of different experimental techniques give a better understanding of the interesting materials science taking place within these systems. This dissertation discusses Nuclear Magnetic Resonance (NMR) techniques performed on FIC glasses over the past few years. These NMR results have been complimented with other measurement techniques, primarily impedance spectroscopy, to develop models that describe the mechanisms by which ionic conduction takes place and the dependence of the ion dynamics on the local structure of the glass. The aim of these measurements was to probe the cause of a non-Arrhenius behavior of the conductivity which has been seen at high temperatures in the silver thio-borosilicate glasses. One aspect that will be addressed is if this behavior is unique to silver containing fast ion conducting glasses. more specifically, this study will determine if a non-Arrhenius correlation time, τ, can be observed in the Nuclear Spin Lattice Relaxation (NSLR) measurements. If so, then can this behavior be modeled with a new single

  5. Determination of parameters of a nuclear reactor through noise measurements

    International Nuclear Information System (INIS)

    Cohn, C.E.

    1975-01-01

    A method of measuring parameters of a nuclear reactor by noise measurements is described. Noise signals are developed by the detectors placed in the reactor core. The polarity coincidence between the noise signals is used to develop quantities from which various parameters of the reactor can be calculated

  6. Neutral-beam species determination from nuclear reaction products

    Science.gov (United States)

    Ruby, Lawrence; Stearns, J. Warren; Pyle, Robert V.

    1986-08-01

    Recent measurements designed to measure neutral-beam species by nuclear reaction analysis are reported. The detection system and several experiments intended to improve resolution and reduce noise are described. Results obtained at the LBL neutral-beam engineering test facility are discussed and compared with the predictions of optical Doppler-shift spectroscopy.

  7. Study of the nuclear structure far from stability: Coulomb excitation of neutron-rich Rb isotopes around N=60; Production of nuclear spin polarized beams using the tilted foils technique

    International Nuclear Information System (INIS)

    Sotty, C.

    2013-01-01

    The underlying structure in the region A ∼ 100, N ∼ 60 has been under intensive and extensive investigation, mainly by β-decay and γ-ray spectroscopy from fission processes. Around N ∼ 60, by adding just few neutrons, protons a rapid shape change occurs from spherical-like to well deformed g.s. shape. Shape coexistence has been observed in the Sr and Zr nuclei, and is expected to take place in the whole region. The mechanisms involved in the appearance of the deformation is not well understood. The interplay between down-sloping and up-sloping neutron Nilsson orbital is evoked as one of the main reasons for the sudden shape change. However, a clear identification of the active proton and neutron orbitals was still on-going. For that purpose, the neutron rich 93;95;97;99 Rb isotopes have been studied by Coulomb excitation at CERN (ISOLDE) using the REX-ISOLDE post-accelerator and the MINIBALL setup. The completely unknown structures of 97;99 Rb have been populated and observed. Prompt γ-ray coincidences of low-lying states have been observed and time-correlated in order to build level schemes. The associated transition strengths have been extracted with the GOSIA code. The observed matrix elements of the electromagnetic operator constituted new inputs of further theoretical calculations giving new insight on the involved orbitals. The sensitivity of such experiment can be increased using nuclear spin polarized radioactive ion beam. For that purpose the Tilted Foils Technique (TFT) of polarization has been investigated at CERN. This technique consists to spin polarize the ion beam, passing through thin foils tilted at an oblique angle with respect to the beam direction. The initially obtained atomic polarization is transferred to the nucleus by hyperfine interaction. This technique does not depend on the chemical nature of the element. Short lived nuclei can be polarized in-flight without any need to be stopped in a catcher. It opens up the possibility to

  8. Mesoporous Silica Nanoparticles Loaded with Surfactant: Low Temperature Magic Angle Spinning 13C and 29Si NMR Enhanced by Dynamic Nuclear Polarization

    Energy Technology Data Exchange (ETDEWEB)

    Lafon, Olivier [Universite de Lille Nord de France; Thankamony, Aany S. Lilly [Universite de Lille Nord de France; Kokayashi, Takeshi [Ames Laboratory; Carnevale, Diego [Ecole Polytechnique Federale de Lausanne; Vitzthum, Veronika [Ecole Polytechnique Federale de Lausanne; Slowing, Igor I. [Ames Laboratory; Kandel, Kapil [Ames Laboratory; Vezin, Herve [Universite de Lille Nord de France; Amoureux, Jean-Paul [Universite de Lille Nord de France; Bodenhausen, Geoffrey [Ecole Polytechnique Federale de Lausanne; Pruski, Marek [Ames Laboratory

    2012-12-21

    We show that dynamic nuclear polarization (DNP) can be used to enhance NMR signals of 13C and 29Si nuclei located in mesoporous organic/inorganic hybrid materials, at several hundreds of nanometers from stable radicals (TOTAPOL) trapped in the surrounding frozen disordered water. The approach is demonstrated using mesoporous silica nanoparticles (MSN), functionalized with 3-(N-phenylureido)propyl (PUP) groups, filled with the surfactant cetyltrimethylammonium bromide (CTAB). The DNP-enhanced proton magnetization is transported into the mesopores via 1H–1H spin diffusion and transferred to rare spins by cross-polarization, yielding signal enhancements εon/off of around 8. When the CTAB molecules are extracted, so that the radicals can enter the mesopores, the enhancements increase to εon/off ≈ 30 for both nuclei. A quantitative analysis of the signal enhancements in MSN with and without surfactant is based on a one-dimensional proton spin diffusion model. The effect of solvent deuteration is also investigated.

  9. Determining the flare dispensing program effectiveness against conical-scan and spin-scan reticle systems via Gaussian mixture models

    Science.gov (United States)

    Şahingil, Mehmet C.; Aslan, Murat Ş.

    2013-05-01

    The reticle systems which are considered as the classical approach for determining the angular position of radiating targets in infrared band are widely used in early generation surface-to-air and air-to-air infrared guided missile seekers. One of the cost-effective ways of protecting aircrafts against these missiles is to dispense flare decoys from the countermeasure dispensing system (CMDS) integrated into the aircraft platform. Although this counter-measuring technique seems very simple, if not optimized carefully, it may not be effective for protecting the aircraft. Flares should be dispensed in accordance with a specific dispensing program which determines the number of flares to be dispensed from each dispenser of the CMDS and timing sequence of dispensing. Optimizing the parameters of the dispensing program is not trivial. It requires a good understanding of the operating principle of the threat seeker, operational capabilities of own platform and engagement scenario between them. In the present paper, we propose a complete simulation-based procedure to form an effectiveness boundary of flare dispensing programs against the spin-scan and conical-scan reticle seekers. The region of effectiveness is determined via Gaussian mixture models. The raw data is collected via extensive number of simulations using a MATLAB-coded simulator which models reticle-based seeker, aircraft radiation, aircraft motion, aircraft CMDS system, flare motion and flare radiation.

  10. Nuclear magnetic resonance in high magnetic fields: Study of singlet-ground-state due to 1-D quantum spin effect

    Science.gov (United States)

    Chiba, Meiro; Ajiro, Yoshitami; Satoh, Eiji; Kubo, Takeji

    1996-02-01

    In one-dimensional (1-D) magnets the singlet-ground-state (SGS) due to the quantum spin effect is one of the most interesting phenomena. The temperature and the field dependences of the proton spin-lattice relaxation under magnetic fields up to 15 T have been observed for SGS materials, namely, NENP (Haldane system) and CuCI 2(γ-picoline) 2 (alternating antiferromagnetic chain). The results clearly show the excitation of SGS with a characteristic energy gap in the magnetic excited state. The observed relaxation rate is discussed in terms of the number of magnetic excitons in focussing on the dissimilarity between two systems.

  11. Dynamically Decoupled 13C Spins in Hyperpolarized Nanodiamond

    Science.gov (United States)

    Rej, Ewa; Gaebel, Torsten; Boele, Thomas; Waddington, David; Reilly, David

    The spin-spin relaxation time, T2, which determines how long a quantum state remains coherent, is an important factor for many applications ranging from MRI to quantum computing. A common technique used in quantum information technology to extend the T2, involves averaging out certain noise spectra via dynamical decoupling sequences. Depending on the nature of the noise in the system, specific sequences, such as CPMG, UDD or KDD, can be tailored to optimize T2. Here we combine hyperpolarization techniques and dynamical decoupling sequences to extend the T2 of 13C nuclear spins in nanodiamond by three orders of magnitude.

  12. Determination of the magnetic impurities contribution to the nuclear relaxation in metals

    International Nuclear Information System (INIS)

    Cohen, A.M.

    1982-01-01

    The renormalization group techniques developed by Wilson for the Kondo problem are applied, for the first time, to the calculation of nuclear spin relaxation rates in dilute magnetic alloys. A procedure that calculates the longitudinal relaxation time T 1 over the entire temperature range 0 B T 1 is derived; for distances R between the impurity and the nucleus large compared to the inverse Fermi momentum H f , the result is identical to Korringa's expression for the nuclear spin relaxation rate in the pure metal. For smaller k F R, T 1 increases and becomes infinite as k F R→0. A numerical approach, capable of calculating T 1 at finite temperatures, is presented and tested by calculating T 1 for T→0; the numerical results are in excellent agreement with the analytical expression discussed above. Only for k F R→ infinity do the results for T 1 at T=0 agree with those found by Roshen and Saam, who recently analysed this problem in the light of Nozieres's Fermi liquid theory. The reasons for the discrepancy for finite k F R are discussed. (author) [pt

  13. Ab initio determination of the nuclear quadrupole moments of 114In, 115In, and 117In

    International Nuclear Information System (INIS)

    Errico, Leonardo A.; Renteria, Mario

    2006-01-01

    We present here ab initio determinations of the nuclear-quadrupole moment Q of hyperfine-probe-nuclear states of three different In isotopes: the 5 + 192 keV excited state of 114 In (probe for nuclear quadrupole alignment spectroscopy), the 9/2 + ground state of 115 In (nuclear magnetic and nuclear quadrupole resonance probe), and the 3/2 + 659 keV excited state of 117 In (perturbed angular correlations probe). These nuclear-quadrupole moments were determined by comparing experimental nuclear-quadrupole frequencies to the electric field gradient tensor calculated with high accuracy at In sites in metallic indium within the density functional theory. These ab initio calculations were performed with the full-potential linearized augmented plane wave method. The results obtained for the quadrupole moments of 114 In [Q( 114 In)=-0.14(1) b] are in clear discrepancy with those reported in the literature [Q( 114 In)=+0.16(6) b and +0.739(12) b]. For 115 In and 117 In our results are in excellent agreement with the literature and in the last case Q( 117 In) is determined with more precision. In the case of Q( 117 In), its sign cannot be determined because standard γ-γ perturbed angular correlations experiments are not sensitive to the sign of the nuclear-quadrupole frequency

  14. Absolute nondestructive quantitative determination of uranium in special nuclear materials

    International Nuclear Information System (INIS)

    Dragnev, T.; Damyanov, B.; Grozev, G.; Karamanova, J.

    1985-01-01

    An absolute nondestructive method for quantitative measurement of uranium concentration and enrichment in special nuclear materials is proposed. The method uses intrinsic calibration and portable instrumentation and the particularly suitable for IAEA safequards applications. The intrinsic calibration accumulates the positive experience of the previous measurements and the results will be continuously improving. It is possible to measure standards in laboratories and use the results for analysis at different time and places. The tests show a good agreement with known classical methods and better results in some cases

  15. Nuclear parameters determination of the 127Te β - decay: a proposal for teaching nuclear physics

    International Nuclear Information System (INIS)

    Batista, Wagner Fonseca

    2011-01-01

    A study of the 127 Te β - decay was carried out by means of gamma spectroscopy measurements using high resolution HPGe detector, in the region from 30 keV to 1.0 MeV, aiming to get a better understanding of the 127 Te nuclear structure. The radioactive sources of 12 7Te were obtained from the 126 Te(n,γ) 1 '2 7 Te nuclear reaction produced in the IEA- R1 nuclear reactor at IPEN/CNEN-SP. Five gamma t ransitions previously attributed to this decay were confirmed with a better precision than previously. The half-life of 127 Te was also studied resulting in data with lower uncertainty. Using a set of data selected from gamma spectroscopy measurements was developed and applied a didactic proposal for high school students using the Excel software. (author)

  16. Roundtable discussion of nuclear spectroscopic quantities - Their determination and use

    International Nuclear Information System (INIS)

    Wood, J.L.

    1986-01-01

    The tools now available for nuclear spectroscopy permit studies of extraordinary breadth and detail. Capabilities generally lie considerably beyond the existing data base for any nucleus. When extended mass regions are considered, one finds that there are essentially no regions studied with the full spectroscopic potential at hand. The main reason for this is that such undertakings place heavy demands on manpower. They have reached a point in the study of low-energy nuclear structure where it is necessary to be highly selective in the problems chose for study. To ensure that the best problems are selected, strong interaction between theory and experiment is needed. Experimentalists need to be aware of the kind of structure problems that can be posed. Theoreticians need to be aware of the potential for generating new spectroscopic information with the available state-of-the-art techniques. With this in mind, the status of the topics covered in this symposium will be discussed with an eye on where the experiments and theoretical developments need to be directed in near future studies

  17. Critical comparison of radiometric and mass spectrometric methods for the determination of radionuclides in environmental, biological and nuclear waste samples

    DEFF Research Database (Denmark)

    Hou, Xiaolin; Roos, Per

    2008-01-01

    spectrometry, and glow discharge mass spectrometry are reviewed for the determination of radionuclides. These methods are critically compared for the determination of long-lived radionuclides important for radiation protection, decommissioning of nuclear facilities, repository of nuclear waste, tracer...

  18. Determination of radionuclides. Fingerprint determination on protection clothing from the controlled areas in nuclear facilities

    International Nuclear Information System (INIS)

    Scholand, Soeren

    2014-01-01

    ENS (Euro Nuclear Services) in Coevorden, Netherlands, is decontaminating und providing protection clothing for the personnel in nuclear facilities. The capacity of the laundry is about 750 kg/h. The clean laundry section is cleaning non-contaminated or very low contaminated articles, i.e. socks or underwear. Fingerprint is defined as the activity of certain radionuclides that differs in the different nuclear facilities. For the reception inspection the dose rate measured with scintillation detectors is compared with the customer specific fingerprint. The total activity is usually 2000 Bq/g. The dose rate limit is 0.3 mSv/h.

  19. Determination of spin, magnetic moment and isotopic shift of neutron rich 205Hg by optical pumping

    International Nuclear Information System (INIS)

    Rodriguez, J.; Bonn, J.; Huber, G.; Kluge, H.J.; Otten, E.W.; European Organisation for Nuclear Research, Geneva

    1975-01-01

    Neutron rich 205 Hg(Tsub(1/2) = 5.2 min) was produced and on-line mass separated at the ISOLDE facility at CERN. The polarization achieved by optical pumping via the atomic line (6s 21 S 0 - 6s6p 3 P 1 , lambda = 2,537 A) was monitored by the β decay asymmetry. Hyperfine structure and isotopic shift of the 205 Hg absorption line was determined by Zeeman scanning. In addition a magnetic resoncance was performed on the polarized 205 Hg nuclei in the atomic ground state. The results are: I( 205 Hg) = 1/2 (confirmed); μ(I, 205 Hg) = 0.5915(1)μ(N) (uncorrected for diamagnetism); isotopic shift deltaν(204/205) = ν( 205 Hg) - ν( 204 Hg) = -1.8(1)GHz. μ(I) and IS are discussed briefly in the frame of current literature. (orig.) [de

  20. A review of flow analysis methods for determination of radionuclides in nuclear wastes and nuclear reactor coolants.

    Science.gov (United States)

    Trojanowicz, Marek; Kołacińska, Kamila; Grate, Jay W

    2018-06-01

    The safety and security of nuclear power plant operations depend on the application of the most appropriate techniques and methods of chemical analysis, where modern flow analysis methods prevail. Nevertheless, the current status of the development of these methods is more limited than it might be expected based on their genuine advantages. The main aim of this paper is to review the automated flow analysis procedures developed with various detection methods for the nuclear energy industry. The flow analysis methods for the determination of radionuclides, that have been reported to date, are primarily focused on their environmental applications. The benefits of the application of flow methods in both monitoring of the nuclear wastes and process analysis of the primary circuit coolants of light water nuclear reactors will also be discussed. The application of either continuous flow methods (CFA) or injection methods (FIA, SIA) of the flow analysis with the β-radiometric detection shortens the analysis time and improves the precision of determination due to mechanization of certain time-consuming operations of the sample processing. Compared to the radiometric detection, the mass spectrometry (MS) detection enables one to perform multicomponent analyses as well as the determination of transuranic isotopes with much better limits of detection. Copyright © 2018 Elsevier B.V. All rights reserved.

  1. Measuring the spin polarization of alkali-metal atoms using nuclear magnetic resonance frequency shifts of noble gases

    Directory of Open Access Journals (Sweden)

    X. H. Liu

    2015-10-01

    Full Text Available We report a novel method of measuring the spin polarization of alkali-metal atoms by detecting the NMR frequency shifts of noble gases. We calculated the profile of 87Rb D1 line absorption cross sections. We then measured the absorption profile of the sample cell, from which we calculated the 87Rb number densities at different temperatures. Then we measured the frequency shifts resulted from the spin polarization of the 87Rb atoms and calculated its polarization degrees at different temperatures. The behavior of frequency shifts versus temperature in experiment was consistent with theoretical calculation, which may be used as compensative signal for the NMRG closed-loop control system.

  2. Density determination of sintered ceramic nuclear fuel materials

    International Nuclear Information System (INIS)

    Landspersky, H.; Medek, J.

    1980-01-01

    The feasibility was tested of using solids for pycnometric determination of the density of uranium dioxide-based sintered ceramic fuel materials manufactured by the sol-gel method in the shape of spherical particles of 0.7 to 1.0 mm in size and of particles smaller than 200 μm. For fine particles, this is the only usable method of determining their density which is a very important parameter of the fine fraction when it is employed for the manufacture of fuel elements by vibration compacting. The method consists in compacting a mixture of pycnometric material and dispersed particles of uranium dioxide, determining the size and weight of the compact, and in calculating the density of the material measured from the weight of the oxide sample in the mixture. (author)

  3. Determination of uranium traces in fuel cans of nuclear reactors

    International Nuclear Information System (INIS)

    Acosta L, C.E.; Benavides M, A.M.; Sanchez P, L.A.; Nava S, G.F.

    1997-01-01

    The objective of this work is to quantify the uranium content that as impurity can be found in zircon and zircaloy alloys which are used in the construction of fuel cans. The determination of this serves as a quality control measure due to that the increment of uranium content in alloy, diminishing the corrosion resistance. The fluorimetric method was used to do this determination. It is a very sensitive, reliable, rapid method also high reproducibility and repeatability as well as low detection limits (0.25 mg/kg). (Author)

  4. Spin current

    CERN Document Server

    Valenzuela, Sergio O; Saitoh, Eiji; Kimura, Takashi

    2012-01-01

    In a new branch of physics and technology called spin-electronics or spintronics, the flow of electrical charge (usual current) as well as the flow of electron spin, the so-called 'spin current', are manipulated and controlled together. This book provides an introduction and guide to the new physics and application of spin current.

  5. Spin and parity determinations of excited 15N based on polarized and unpolarized 12C(7Li, α)15N reaction data at E lab = 34 MeV

    International Nuclear Information System (INIS)

    Rodriguez, F.J.; Liendo, J.A.; Roeder, B.T.; Weintraub, W.; Kemper, K.W.; Keeley, N.; Marechal, F.

    2007-01-01

    From an experiment conducted at the Florida State University Accelerator Laboratory with a 34 MeV polarized 7 Li beam bombarding a 12 C target, we have obtained angular distributions and analyzing powers for states of 15 N up to 20 MeV in excitation energy. This study not only offers the possibility to assign spin and parity to several states in 15 N, but also serves to obtain nuclear potential parameters used in Distorted Wave Born (DWBA) and Coupled Channel Born (CCBA) Approximations to generate theoretical angular distributions and vector analyzing powers that give the best description of the experimental data. Under the assumption that the reaction mechanism is a three nucleon transfer, the determination of shell model nucleonic configurations and spectroscopic factors is possible for the 15 N states studied

  6. Characterization of the sp sup 2 bonds network in a-C:H layers with nuclear magnetic resonance, electron energy loss spectroscopy and electron spin resonance

    Energy Technology Data Exchange (ETDEWEB)

    Kleber, R.; Jung, K.; Ehrhardt, H. (Fachbereich Physik, Univ. Kaiserslautern (Germany)); Muehling, I.; Breuer, K. (Technische Univ. Chemnitz, Sektion Physik/Elektronische Bauelemente (Germany)); Metz, H.; Engelke, F. (Karl-Marx-Univ., Sektion Physik, Leipzig (Germany))

    1991-12-01

    a-C:H layers prepared at different ion energies have been investigated by several methods including {sup 13}C nuclear magnetic resonance (NMR), electron energy loss spectroscopy (EELS) and electron spin resonance (ESR). The sp{sup 2} fraction of the samples rose from 27% to about 60 at.% with increasing ion energies from 30 eV to 170 eV. In the EELS spectra of these layers the intensity of the {pi}{yields}{pi}{sup *} transition between 4 and 7 eV showed no significant variation. But a shift of the peak is observed from 7 eV to lower energy losses with increasing ion energies indicating an enhanced formation of larger sp{sup 2} cluster sizes. This shift is accompanied by a broadening of the energy loss peak, suggesting a broadening of the cluster size distribution. The ESR spectra showed an increase of the spin density by more than one order of magnitude with increasing ion energies. Simultaneously the linewidth of the ESR signal gets narrower. This can also be interpreted as an increasing cluster size from single benzene rings to three and four fused six-fold rings. Hence, the EELS and ESR spectra lead to the same conclusions with respect to the microstructure of the a-C:H network. (orig.).

  7. Determination of iron 55 in nuclear wastes and effluents

    International Nuclear Information System (INIS)

    Raymond, A.; Revy, D.

    1989-01-01

    The methods for iron 55 analysis, described in this report allows measurement in different types of radioactive wastes after a specific chemical separation. Detection limit is near 1 Bq/l and the concentration factor can reach 100. Activity level found show that iron 55 is a major activation product, then the chemical determination is indispensable for a complete inventory of radionuclides in radioactive wastes [fr

  8. Determination of the fission coefficients in thermal nuclear reactors for antineutrino detection

    Energy Technology Data Exchange (ETDEWEB)

    Araujo, Lenilson M. [Coordenacao dos Programas de Pos-Graduacao de Engenharia (PEN/COPPE/UFRJ), Rio de Janeiro, RJ (Brazil). Programa de Engenharia Nuclear; Cabral, Ronaldo G., E-mail: rgcabral@ime.eb.b [Instituto Militar de Engenharia (IME), Rio de Janeiro, RJ (Brazil); Anjos, Joao C.C. dos, E-mail: janjos@cbpf.b [Centro Brasileiro de Pesquisas Fisicas (CBPF), Rio de Janeiro, RJ (Brazil). Dept. GLN - G

    2011-07-01

    The nuclear reactors in operation periodically need to change their fuel. It is during this process that these reactors are more vulnerable to occurring of several situations of fuel diversion, thus the monitoring of the nuclear installations is indispensable to avoid events of this nature. Considering this fact, the most promissory technique to be used for the nuclear safeguard for the nonproliferation of nuclear weapons, it is based on the detection and spectroscopy of antineutrino from fissions that occur in the nuclear reactors. The detection and spectroscopy of antineutrino, they both depend on the single contribution for the total number of fission of each actinide in the core reactor, these contributions receive the name of fission coefficients. The goal of this research is to show the computational and mathematical modeling used to determinate these coefficients for PWR reactors. (author)

  9. Uranium Determination in Samples from Decommissioning of Nuclear facilities Related to the First Stage of Nuclear Fuel Cycle

    International Nuclear Information System (INIS)

    Alvarez, A.; Correa, E.; Navarro, N.; Sancho, C.; Angeles, A.

    2000-01-01

    An adequate workplace monitoring must be carried out during the decommissioning activities, to ensure the protection of workers involved in these tasks. In addition, a large amount of waste materials are generated during the decommissioning of nuclear facilities. Clearance levels are established by regulatory authorities and are normally quite low. The determination of those activity concentration levels become more difficult when it is necessary to quantify alpha emitters such as uranium, especially when complex matrices are involved. Several methods for uranium determination in samples obtained during the decommissioning of a facility related to the first stage of the nuclear fuel cycle are presented in this work. Measurements were carried out by laboratory techniques. In situ gamma spectrometry was also used to perform measurements on site. A comparison among the different techniques was also done by analysing the results obtained in some practical applications. (Author)

  10. Spin coherence in phosphorescent triplet states

    International Nuclear Information System (INIS)

    Hof, C.A. van 't

    1977-01-01

    The electron spin echo is studied on the dephasing mechanism in the photo-excited triplet state of quinoline in a durene host. First, a comparative investigation of the merits of the different spin echo techniques is presented. It turns out that the rotary echo generally yields a longer phase memory time than the two-pulse echo, whereas in the Carr-Purcell experiment, the dephasing can even be largely suppressed. Secondly, it is shown that the dephasing mechanism is determined by the nuclear spins of the guest molecules as well as those in the host material. A theoretical basis for interpreting the effect of vibronic relaxation on the decay rate of the rotary echo, as observed in parabenzoquinone, is given. Similar experiments in aniline reveal also that in this molecule, two close-lying triplet states exist, which is attributed to an inversion vibration analogous to the well-known example in ammonia

  11. Towards real-time metabolic profiling of a biopsy specimen during a surgical operation by 1H high resolution magic angle spinning nuclear magnetic resonance: a case report

    Directory of Open Access Journals (Sweden)

    Piotto Martial

    2012-01-01

    Full Text Available Abstract Introduction Providing information on cancerous tissue samples during a surgical operation can help surgeons delineate the limits of a tumoral invasion more reliably. Here, we describe the use of metabolic profiling of a colon biopsy specimen by high resolution magic angle spinning nuclear magnetic resonance spectroscopy to evaluate tumoral invasion during a simulated surgical operation. Case presentation Biopsy specimens (n = 9 originating from the excised right colon of a 66-year-old Caucasian women with an adenocarcinoma were automatically analyzed using a previously built statistical model. Conclusions Metabolic profiling results were in full agreement with those of a histopathological analysis. The time-response of the technique is sufficiently fast for it to be used effectively during a real operation (17 min/sample. Metabolic profiling has the potential to become a method to rapidly characterize cancerous biopsies in the operation theater.

  12. Crocus sativus Petals: Waste or Valuable Resource? The Answer of High-Resolution and High-Resolution Magic Angle Spinning Nuclear Magnetic Resonance.

    Science.gov (United States)

    Righi, Valeria; Parenti, Francesca; Tugnoli, Vitaliano; Schenetti, Luisa; Mucci, Adele

    2015-09-30

    Intact Crocus sativus petals were studied for the first time by high-resolution magic angle spinning nuclear magnetic resonance (HR-MAS NMR) spectroscopy, revealing the presence of kinsenoside (2) and goodyeroside A (3), together with 3-hydroxy-γ-butyrolactone (4). These findings were confirmed by HR-NMR analysis of the ethanol extract of fresh petals and showed that, even though carried out rapidly, partial hydrolysis of glucopyranosyloxybutanolides occurs during extraction. On the other hand, kaempferol 3-O-sophoroside (1), which is "NMR-silent" in intact petals, is present in extracts. These results suggest to evaluate the utilization of saffron petals for phytopharmaceutical and nutraceutical purposes to exploit a waste product of massive production of commercial saffron and point to the application of HR-MAS NMR for monitoring bioactive compounds directly on intact petals, avoiding the extraction procedure and the consequent hydrolysis reaction.

  13. Structural analysis of mixed alkali borosilicate glasses containing Cs+ and Na+ using strong magnetic field magic angle spinning nuclear magnetic resonance

    Directory of Open Access Journals (Sweden)

    S. Kaneko

    2017-03-01

    Full Text Available We have investigated the local structure of alkali atoms in mixed alkali silicate, borate, and borosilicate glasses, which contain Cs+ and Na+, using strong magnetic field magic angle spinning nuclear magnetic resonance (MAS NMR spectroscopy of 133Cs and 23Na. The spectral peaks of 133Cs in borosilicate (Si:B = 1:1 and Si-rich borosilicate (Si:B = 2:1 glasses shifted to upfield with increasing Cs+/(Na+ + Cs+ ratio, which implies that the coordination number of Cs+ decreased as in the case of silicate and borate glasses. However, this trend was not observed in the 23Na spectra of either borosilicate glass. This might be because the chemical shift of 23Na in borosilicate glass is strongly affected by nearby species such as Si or B, and not by the coordination number of Na+.

  14. Contribution to the evaluation of safety of software used in command control systems in nuclear plants: application to the SPIN N4

    International Nuclear Information System (INIS)

    Soubies, B.; Boulc'h, J.; Elsensohn, O.; Le Meur, M.; Henry, J.Y.

    1994-06-01

    The licensing procedures process of nuclear plants features compulsory steps which bring about a thorough exam of the commands control system. This analysis accounts for the aspects linked to technologies (integrated circuits, software packages) which have been chosen by the manufacturer for the programmed systems in charge of safety functions. Important innovations have been introduced in terms of design and manufacturing processes of safety systems of 1400 MWe pressurized water reactors, more precisely for the integrated numerical protection system (SPIN). The methodology used by the IPSN for the exam of the software of this system is presented in the communication. This methodology leads the IPSN to carry out studies and developments of tools keeping in sight as their main goal to bring substantial help to analysis. (authors). 2 refs

  15. Aluminum and gallium nuclei as microscopic probes for pulsed electron-nuclear double resonance diagnostics of electric-field gradient and spin density in garnet ceramics doped with paramagnetic ions

    Science.gov (United States)

    Uspenskaya, Yu. A.; Mamin, G. V.; Babunts, R. A.; Badalyan, A. G.; Edinach, E. V.; Asatryan, H. R.; Romanov, N. G.; Orlinskii, S. B.; Khanin, V. M.; Wieczorek, H.; Ronda, C.; Baranov, P. G.

    2018-03-01

    The presence of aluminum and gallium isotopes with large nuclear magnetic and quadrupole moments in the nearest environment of impurity ions Mn2+ and Ce3+ in garnets made it possible to use hyperfine and quadrupole interactions with these ions to determine the spatial distribution of the unpaired electron and the gradient of the electric field at the sites of aluminum and gallium in the garnet lattice. High-frequency (94 GHz) electron spin echo detected electron paramagnetic resonance and electron-nuclear double resonance measurements have been performed. Large difference in the electric field gradient and quadrupole splitting at octahedral and tetrahedral sites allowed identifying the positions of aluminum and gallium ions in the garnet lattice and proving that gallium first fills tetrahedral positions in mixed aluminum-gallium garnets. This should be taken into account in the development of garnet-based scintillators and lasers. It is shown that the electric field gradient at aluminum nuclei near Mn2+ possessing an excess negative charge in the garnet lattice is ca. 2.5 times larger than on aluminum nuclei near Ce3+.

  16. ANL calculational methodologies for determining spent nuclear fuel source term

    International Nuclear Information System (INIS)

    McKnight, R. D.

    2000-01-01

    Over the last decade Argonne National Laboratory has developed reactor depletion methods and models to determine radionuclide inventories of irradiated EBR-II fuels. Predicted masses based on these calculational methodologies have been validated using available data from destructive measurements--first from measurements of lead EBR-II experimental test assemblies and later using data obtained from processing irradiated EBR-II fuel assemblies in the Fuel Conditioning Facility. Details of these generic methodologies are described herein. Validation results demonstrate these methods meet the FCF operations and material control and accountancy requirements

  17. Determining the sizes of micropores in activated charcoals by the pulsed NMR method

    Science.gov (United States)

    Gogelashvili, G. Sh.; Khozina, E. V.; Vartapetyan, R. Sh.; Ladychuk, D. V.; Grunin, Yu. B.

    2011-07-01

    The pulsed NMR method was used to measure the nuclear spin-spin relaxation of protons of water adsorbed in micropores of activated charcoal (AC) samples with different porous structures. A correlation was found between the spin-spin relaxation time of water protons in AC with completely filled micropores and the volume density of water primary adsorption centers in the AC samples. An equation for approximating obtained dependences is proposed that allows us to determine the volume of micropores in AC.

  18. Determination of leveled costs of electric generation for gas plants, coal and nuclear

    International Nuclear Information System (INIS)

    Alonso V, G.; Palacios H, J.C.; Ramirez S, J.R.; Gomez, A.

    2005-01-01

    The present work analyzes the leveled costs of electric generation for different types of nuclear reactors known as Generation III, these costs are compared with the leveled costs of electric generation of plants with the help of natural gas and coal. In the study several discount rates were used to determine their impact in the initial investment. The obtained results are comparable with similar studies and they show that it has more than enough the base of the leveled cost the nuclear option it is quite competitive in Mexico. Also in this study it is also thinks about the economic viability of a new nuclear power station in Mexico. (Author)

  19. High-pressure, high-temperature magic angle spinning nuclear magnetic resonance devices and processes for making and using same

    Science.gov (United States)

    Hu, Jian Zhi; Hu, Mary Y.; Townsend, Mark R.; Lercher, Johannes A.; Peden, Charles H. F.

    2015-10-06

    Re-usable ceramic magic angle spinning (MAS) NMR rotors constructed of high-mechanic strength ceramics are detailed that include a sample compartment that maintains high pressures up to at least about 200 atmospheres (atm) and high temperatures up to about least about 300.degree. C. during operation. The rotor designs minimize pressure losses stemming from penetration over an extended period of time. The present invention makes possible a variety of in-situ high pressure, high temperature MAS NMR experiments not previously achieved in the prior art.

  20. Determinants of Nuclear Energy Consumption in South Asia: Economic and Energy Security Issues

    OpenAIRE

    Zaman, Khalid

    2015-01-01

    The objective of the study is to examine the causal relationship between i) nuclear energy consumption and economic determinants (i.e. labor force, gross fixed capital formation and GDP per capita), and ii) nuclear consumption and energy security issues (i.e., technology infrastructure, energy sources, conditions of land, concern of energy security and political stability) in the context of South Asia. The study brings an annual aggregate data for South Asia from the period of 1960-2012. The ...

  1. Electron spin resonance as a high sensitivity technique for environmental magnetism: determination of contamination in carbonate sediments

    Science.gov (United States)

    Crook, Nigel P.; Hoon, Stephen R.; Taylor, Kevin G.; Perry, Chris T.

    2002-05-01

    This study investigates the application of high sensitivity electron spin resonance (ESR) to environmental magnetism in conjunction with the more conventional techniques of magnetic susceptibility, vibrating sample magnetometry (VSM) and chemical compositional analysis. Using these techniques we have studied carbonate sediment samples from Discovery Bay, Jamaica, which has been impacted to varying degrees by a bauxite loading facility. The carbonate sediment samples contain magnetic minerals ranging from moderate to low concentrations. The ESR spectra for all sites essentially contain three components. First, a six-line spectra centred around g = 2 resulting from Mn2+ ions within a carbonate matrix; second a g = 4.3 signal from isolated Fe3+ ions incorporated as impurities within minerals such as gibbsite, kaolinite or quartz; third a ferrimagnetic resonance with a maxima at 230 mT resulting from the ferrimagnetic minerals present within the bauxite contamination. Depending upon the location of the sites within the embayment these signals vary in their relative amplitude in a systematic manner related to the degree of bauxite input. Analysis of the ESR spectral components reveals linear relationships between the amplitude of the Mn2+ and ferrimagnetic signals and total Mn and Fe concentrations. To assist in determining the origin of the ESR signals coral and bauxite reference samples were employed. Coral representative of the matrix of the sediment was taken remote from the bauxite loading facility whilst pure bauxite was collected from nearby mining facilities. We find ESR to be a very sensitive technique particularly appropriate to magnetic analysis of ferri- and para-magnetic components within environmental samples otherwise dominated by diamagnetic (carbonate) minerals. When employing typical sample masses of 200 mg the practical detection limit of ESR to ferri- and para-magnetic minerals within a diamagnetic carbonate matrix is of the order of 1 ppm and 1 ppb

  2. Sequential determination of important ecotoxic radionuclides in nuclear waste samples

    International Nuclear Information System (INIS)

    Bilohuscin, J.

    2016-01-01

    In the dissertation thesis we focused on the development and optimization of a sequential determination method for radionuclides 93 Zr, 94 Nb, 99 Tc and 126 Sn, employing extraction chromatography sorbents TEVA (R) Resin and Anion Exchange Resin, supplied by Eichrom Industries. Prior to the attestation of sequential separation of these proposed radionuclides from radioactive waste samples, a unique sequential procedure of 90 Sr, 239 Pu, 241 Am separation from urine matrices was tried, using molecular recognition sorbents of AnaLig (R) series and extraction chromatography sorbent DGA (R) Resin. On these experiments, four various sorbents were continually used for separation, including PreFilter Resin sorbent, which removes interfering organic materials present in raw urine. After the acquisition of positive results of this sequential procedure followed experiments with a 126 Sn separation using TEVA (R) Resin and Anion Exchange Resin sorbents. Radiochemical recoveries obtained from samples of radioactive evaporate concentrates and sludge showed high efficiency of the separation, while values of 126 Sn were under the minimum detectable activities MDA. Activity of 126 Sn was determined after ingrowth of daughter nuclide 126m Sb on HPGe gamma detector, with minimal contamination of gamma interfering radionuclides with decontamination factors (D f ) higher then 1400 for 60 Co and 47000 for 137 Cs. Based on the acquired experiments and results of these separation procedures, a complex method of sequential separation of 93 Zr, 94 Nb, 99 Tc and 126 Sn was proposed, which included optimization steps similar to those used in previous parts of the dissertation work. Application of the sequential separation method for sorbents TEVA (R) Resin and Anion Exchange Resin on real samples of radioactive wastes provided satisfactory results and an economical, time sparing, efficient method. (author)

  3. Nuclear inelastic scattering and density functional theory studies of a one-dimensional spin crossover [Fe(1,2,4-triazole)2(1,2,4-triazolato)](BF4) molecular chain.

    Science.gov (United States)

    Jenni, Kevin; Scherthan, Lena; Faus, Isabelle; Marx, Jennifer; Strohm, Cornelius; Herlitschke, Marcus; Wille, Hans-Christian; Würtz, Peter; Schünemann, Volker; Wolny, Juliusz A

    2017-07-26

    Nuclear inelastic scattering (NIS) experiments have been performed in order to study the vibrational dynamics of the low- and high-spin states of the polynuclear 1D spin crossover compound [Fe(1,2,4-triazole) 2 (1,2,4-triazolato)](BF 4 ) (1). Density functional theory (DFT) calculations using the functional B3LYP* and the basis set CEP-31G for heptameric and nonameric models of the compound yielded the normal vibrations and electronic energies for high-spin and low-spin isomers of three models differing in the distribution of anionic trz - ligands and BF 4 - anions. On the basis of the obtained energies a structural model with a centrosymmetric Fe(trzH) 4 (trz - ) 2 coordination core of the mononuclear unit of the chain is proposed. The obtained distribution of the BF 4 - counteranions in the proposed structure is similar to that obtained on the basis of X-ray powder diffraction studies by Grossjean et al. (Eur. J. Inorg. Chem., 2013, 796). The NIS data of the system diluted to 10% Fe(ii) content in a 90% Zn(ii) matrix (compound (2)) show a characteristic change of the spectral pattern of the low-spin centres, compared to the low-spin phase of the parent Fe(ii) complex (1). DFT calculations reveal that this is caused by a change of the structure of the neighbours of the low-spin centres. The spectral pattern of the high-spin centres in (2) is within a good approximation identical to that of the high-spin Fe(ii) isomer of (1). The inspection of the molecular orbitals of the monomeric model systems of [Fe(trzH) 4 (trz - ) 2 ] and [Fe(trzH) 6 ], together with calculations of spin transition energies, point towards the importance of an electrostatic effect caused by the negatively charged ligands. This results in the stabilisation of the low-spin state of the complex containing the anionic ligand and shortening of the Fe-N(trz - ) compared to the Fe-N(trzH) bond in high-spin, but not in low-spin [Fe(trzH) 4 (trz - ) 2 ].

  4. Determination of the Fe magnetic anisotropies and the CoO frozen spins in epitaxial CoO/Fe/Ag(001)

    Energy Technology Data Exchange (ETDEWEB)

    Meng, J. Li, Y.; Park, J. S.; Jenkins, C. A.; Arenholz, E.; Scholl, A.; Tan, A.; Son, H.; Zhao, H. W.; Hwang, Chanyong; Qiu, Z. Q.

    2011-04-28

    CoO/Fe/Ag(001) films were grown epitaxially and studied by X-ray Magnetic Circular Dichroism (XMCD) and X-ray Magnetic Linear Dichroism (XMLD). After field cooling along the Fe[100] axis to 80 K, exchange bias, uniaxial anisotropy, and 4-fold anisotropy of the films were determined by hysteresis loop and XMCD measurements by rotating the Fe magnetization within the film plane. The CoO frozen spins were determined by XMLD measurement as a function of CoO thickness.We find that among the exchange bias, uniaxial anisotropy, and 4-fold anisotropy, only the uniaxial magnetic anisotropy follows thickness dependence of the CoO frozen spins.

  5. Determination of the probability of an aircraft falling on a nuclear power plant

    International Nuclear Information System (INIS)

    Kostikov, V.A.; Smol'nikov, V.L.; Baranaev, Yu.D.; Viktorov, A.N.; Vladykov, G.M.; Dolgov, V.V.; Shvedenko, I.M.

    1993-01-01

    Significant possible external actions at nuclear power plants are events associated with aviation accidents, in which, for one reason or another, an airplane or a fragment of an airplane can fall on the building and destroy the reactor or important safety systems. Measures for preventing an aircraft from striking a nuclear power plant include flight limitations and siting of airports, and flight corridors are created near nuclear power plants. The reactor itself can be placed in a special strong protective envelope. The specific technical measures are determined, to a significant degree, by the type of accident and the type of aircraft. It is now acknowledged, including in documents published by the IAEA, that assessment of the adequacy of measures for protecting a nuclear power plant from aircraft is most efficiently done by means of a probability analysis. We expound below briefly the methodology and the results obtained by its application to the South Ural nuclear power plant and the Bilibinskaya nuclear heat and electricity station. Falling of an aircraft (jet or helicopter) on a nuclear power plant is an extreme event, whose probability is determined mainly by flight safety measures, the intensity of flights in the region, and the distribution of aviation accidents by type and characteristic consequences. Flight safety is determined by the frequency with which aviation accidents occur per hour of flight and mainly depends on the sophistication of the aviation technology. The intensity of flights near a nuclear power plant is estimated taking into account the administrative and organizational measures for limiting flights and is a characteristic of the region where the power plant is located, as is the distribution of aviation accidents by type

  6. Kinetic Isotope Effect Determination Probes the Spin of the Transition State, Its Stereochemistry, and Its Ligand Sphere in Hydrogen Abstraction Reactions of Oxoiron(IV) Complexes.

    Science.gov (United States)

    Mandal, Debasish; Mallick, Dibyendu; Shaik, Sason

    2018-01-16

    This Account outlines interplay of theory and experiment in the quest to identify the reactive-spin-state in chemical reactions that possess a few spin-dependent routes. Metalloenzymes and synthetic models have forged in recent decades an area of increasing appeal, in which oxometal species bring about functionalization of hydrocarbons under mild conditions and via intriguing mechanisms that provide a glimpse of Nature's designs to harness these reactions. Prominent among these are oxoiron(IV) complexes, which are potent H-abstractors. One of the key properties of oxoirons is the presence of close-lying spin-states, which can mediate H-abstractions. As such, these complexes form a fascinating chapter of spin-state chemistry, in which chemical reactivity involves spin-state interchange, so-called two-state reactivity (TSR) and multistate reactivity (MSR). TSR and MSR pose mechanistic challenges. How can one determine the structure of the reactive transition state (TS) and its spin state for these mechanisms? Calculations can do it for us, but the challenge is to find experimental probes. There are, however, no clear kinetic signatures for the reactive-spin-state in such reactions. This is the paucity that our group has been trying to fill for sometime. Hence, it is timely to demonstrate how theory joins experiment in realizing this quest. This Account uses a set of the H-abstraction reactions of 24 synthetic oxoiron(IV) complexes and 11 hydrocarbons, together undergoing H-abstraction reactions with TSR/MSR options, which provide experimentally determined kinetic isotope effect (KIE exp ) data. For this set, we demonstrate that comparing KIE exp results with calculated tunneling-augmented KIE (KIE TC ) data leads to a clear identification of the reactive spin-state during H-abstraction reactions. In addition, generating KIE exp data for a reaction of interest, and comparing these to KIE TC values, provides the mechanistic chemist with a powerful capability to

  7. Nuclear techniques for the determination of protein content in plant material

    International Nuclear Information System (INIS)

    Niemann, E.G.

    1980-01-01

    Elemental analysis for nitrogen has gained in importance over the last decade, as protein improvement and protein control in food and feed has come to be recognized as one of the most promising ways of overcoming deficiencies in food production and distribution. The need for fast and reliable screening methods has stimulated the improvement and automation of classic chemical methods for protein and nitrogen determination and, on the other hand, the development and adaptation of physical and nuclear analysis procedures. After about ten years of work this process has come to a stage where a critical evaluation of the existing methods seems necessary and justified. The present review describes and compares nuclear techniques for nitrogen determination in plant material. These include activation analysis techniques, based on various nuclear reactions, initiated by fast and thermal neutrons, energetic photons, protons, deuterons and α-particles. Other nuclear methods have been applied for nitrogen or protein determination, like ESCA, PIXE, NMR, NQR and Moessbauer spectroscopy, some of which possess good potential as screening methods. Depending on the needs, such as sample size, analysis rate and postulated accuracy, different nuclear techniques may be selected today for nitrogen screening. Some of the techniques discussed have additional potential for carbon or oxygen determination, for measuring depth or lateral N distribution, or for the recognition of the type of chemical N binding. Though most if not all techniques need further development for routine application, they are able to compete with chemical techniques in cost, rate and accuracy. (author)

  8. Some practical limits on achievable precision of determination of nuclear-physics parameters

    OpenAIRE

    Sukhovoj, A. M.; Khitrov, V. A.

    2011-01-01

    The status of experiments on determination of level density and partial widths of the nuclear reaction products emission in diapason of nucleon binding energy is presented. There are analyzed the sources and magnitude of probable systematical uncertainties of their determination. The maximally achievable precision of these parameters is estimated, as well. There is considered ability of new method for determination of distribution parameters of neutron resonances reduced widths in order to di...

  9. Spin dynamics of the itinerant helimagnet MnSi studied by positive muon spin relaxation

    International Nuclear Information System (INIS)

    Kadono, R.; Matsuzaki, T.; Yamazaki, T.; Kreitzman, S.R.; Brewer, J.H.

    1990-03-01

    The local magnetic fields and spin dynamics of the itinerant helimagnet MnSi(T c ≅ 29.5 K) have been studied experimentally using positive muon spin rotation/relaxation (μ + SR) methods. In the ordered phase (T c ), zero-field μSR was used to measure the hyperfine fields at the muon sites as well as the muon spin-lattice relaxation time T 1 μ . Two magnetically inequivalent interstitial μ + sites were found with hyperfine coupling constants A hf (1) = -3.94 kOe/μ B and A hf (2) = -6.94 kOe/μ B , respectively. In the paramagnetic phase (T > T c ), the muon-nuclear spin double relaxation technique was used to simultaneously but independently determine the spin-lattice relaxation time T 1 Mn of 55 Mn spins and that of positive muons (T 1 μ ) over a wide temperature range (T c 1 Mn and T 1 μ in both phases shows systematic deviations from the predictions of self-consistent renormalization (SCR) theory. (author)

  10. Spin Transport in Bose Gases

    NARCIS (Netherlands)

    van Driel, H.J.

    2012-01-01

    In this Thesis, we show that in a rotating two-component Bose mixture, the spin drag between the two different spin species shows a Hall effect. This spin drag Hall effect can be observed experimentally by studying the out-of-phase dipole mode of the mixture. We determine the damping of this mode

  11. Standard practice for determining coating contractor qualifications for nuclear powered electric generation facilities

    International Nuclear Information System (INIS)

    Anon.

    1984-01-01

    This practice provides a criteria guide and procedural method to assist utility owners, architects, engineers, constructors, and other selection agencies in determining the overall qualifications of a coating contractor to execute coating work for the primary containment and other safety-related facilities of light-water nuclear power plants. The qualification criteria and requirements address the essential basic capability of a contractor to execute nuclear coating work. Obviously, the specific capability to execute those requirements unique to a given project must also be carefully considered. The evaluation procedure contained in this practice is designed to be adaptive to this detailed final qualification process. Variation or simplification of the practice is appropriate for non safety-related areas of nuclear power plants, fossil fueled facilities, and other industrial projects. The overall capability of a contractor to successfully execute the varied and complex requirements of nuclear coating work is dependent upon competency in a variety of essential categories

  12. Determination of bound and unbound water in dental alginate irreversible hydrocolloid by nuclear magnetic resonance spectroscopy.

    Science.gov (United States)

    Fellows, C M; Thomas, G A

    2009-04-01

    Alginate materials are considered unsuitable for precise fixed prosthetic rehabilitation due to their tendency to undergo spontaneous syneresis. Commercial alginate impression materials were investigated using Nuclear Magnetic Resonance (NMR) Spectroscopy to probe the relation between changes in the microscopic water environment and dimensional change to obtain a better understanding of spontaneous syneresis. NMR was used to measure the spin-lattice relaxation times (T(1)) of (1)H nuclei in water in alginate matrices to characterize changes in gel structure over time. These results were related to the dimensional stabilities of the alginate impression materials, their chemical compositions, and the Moisture Sorption Isotherms (MSI) obtained by incubation at fixed relative humidities. The rate of change of T(1) with time was found to be a better predictor of dimensional stability than MSI. The greatest dimensional stability for the alginate powders investigated was associated with a high filler:alginate ratio and a high Ca:Na ratio. Nuclear magnetic resonance spectroscopy may used to measure changes in alginate impression materials under conditions where no dimensional change can be observed directly. Changes occurred rapidly even at 100% humidity, suggesting the dimensional stability of alginate impression materials is partially independent of the rate of dehydration. The results may open a way to formulate alginate impression materials more suitable for precise fabrication of dental prostheses.

  13. A scientific model to determine the optimal radiographer staffing component in a nuclear medicine department

    International Nuclear Information System (INIS)

    Shipanga, A.N.; Ellmann, A.

    2004-01-01

    Full text: Introduction: Nuclear medicine in South Africa is developing fast. Much has changed since the constitution of a scientific model for determining an optimum number of radiographer posts in a Nuclear Medicine department in the late 1980's. Aim: The aim of this study was to ascertain whether the number of radiographers required by a Nuclear Medicine department can still be determined according to the norms established in 1988. Methods: A quantitative study using non-experimental evaluation design was conducted to determine the ratios between current radiographer workload and staffing norms. The workload ratios were analysed using the procedures statistics of the Nuclear Medicine department at Tygerberg Hospital. Radiographers provided data about their activities related to patient procedures, including information about the condition of the patients, activities in the radiopharmaceutical laboratory, and patient related administrative tasks. These were factored into an equation relating this data to working hours, including vacation and sick leave. The calculation of Activity Standards and an annual Standard Workload was used to finally calculate the staffing requirements for a Nuclear Medicine department. Results: Preliminary data confirmed that old staffing norms cannot be used in a modern Nuclear Medicine department. Protocols for several types of study have changed, including the additional acquisition of tomographic studies. Interest in the use of time-consuming non-imaging studies has been revived and should be factored Into the equation. Conclusions: All Nuclear Medicine departments In South Africa, where the types of studies performed have changed over the past years, should look carefully at their radiographer staffing ratio to ascertain whether the number of radiographers needed is adequate for the current workload. (author)

  14. Nuclear medicine technologists are able to accurately determine when a myocardial perfusion rest study is necessary.

    Science.gov (United States)

    Trägårdh, Elin; Johansson, Liselott; Olofsson, Camilla; Valind, Sven; Edenbrandt, Lars

    2012-09-04

    In myocardial perfusion scintigraphy (MPS), typically a stress and a rest study is performed. If the stress study is considered normal, there is no need for a subsequent rest study. The aim of the study was to determine whether nuclear medicine technologists are able to assess the necessity of a rest study. Gated MPS using a 2-day 99mTc protocol for 121 consecutive patients were studied. Visual interpretation by 3 physicians was used as gold standard for determining the need for a rest study based on the stress images. All nuclear medicine technologists performing MPS had to review 82 training cases of stress MPS images with comments regarding the need for rest studies, and thereafter a test consisting of 20 stress MPS images. After passing this test, the nuclear medicine technologists in charge of a stress MPS study assessed whether a rest study was needed or not or if he/she was uncertain and wanted to consult a physician. After that, the physician in charge interpreted the images and decided whether a rest study was required or not. The nuclear medicine technologists and the physicians in clinical routine agreed in 103 of the 107 cases (96%) for which the technologists felt certain regarding the need for a rest study. In the remaining 14 cases the technologists were uncertain, i.e. wanted to consult a physician. The agreement between the technologists and the physicians in clinical routine was very good, resulting in a kappa value of 0.92. There was no statistically significant difference in the evaluations made by technicians and physicians (P = 0.617). The nuclear medicine technologists were able to accurately determine whether a rest study was necessary. There was very good agreement between nuclear medicine technologists and physicians in the assessment of the need for a rest study. If the technologists can make this decision, the effectiveness of the nuclear medicine department will improve.

  15. Limitations of optically pumped spin-exchange-polarized targets

    Science.gov (United States)

    Walker, T.; Anderson, L. W.

    1993-12-01

    The effects of spin-exchange collisions on the polarization of dense spin-polarized samples of hydrogen and deuterium are analyzed. It is shown that even in large magnetic fields spin-exchange collisions transfer angular momentum between the electrons and the nuclei. This effect has important implications for the operation of spin-polarized targets and sources of hydrogen and deuterium. For the specific case of sources that are spin-polarized by spin-exchange collisions with optically pumped alkali atoms, spin-exchange not only polarizes the hydrogen and deuterium electron spins, but polarizes the nuclear spins as well.

  16. Report to the Nuclear Regulatory Commission from the staff panel on the Commission's determination of an Extraordinary Nuclear Occurrence (ENO)

    International Nuclear Information System (INIS)

    1980-01-01

    The Panel finds that the first criterion, pertaining to whether the accident caused a discharge of radioactive material or levels of radiation offsite as defined in 10 CFR 140.84, has not been met. It further finds that there is presently insufficient information to support any definitive finding as to whether or not the second criterion, relating to damage to persons or property offsite as defined in 10 CFR 140.85, has been met. Since the Panel has not found that both criteria have been met, it recommends that the Commission determine that the accident at Three Mile Island did not constitute an extraordinary nuclear occurrence

  17. Report to the Nuclear Regulatory Commission from the staff panel on the Commission's determination of an Extraordinary Nuclear Occurrence (ENO)

    Energy Technology Data Exchange (ETDEWEB)

    None

    1980-01-01

    The Panel finds that the first criterion, pertaining to whether the accident caused a discharge of radioactive material or levels of radiation offsite as defined in 10 CFR 140.84, has not been met. It further finds that there is presently insufficient information to support any definitive finding as to whether or not the second criterion, relating to damage to persons or property offsite as defined in 10 CFR 140.85, has been met. Since the Panel has not found that both criteria have been met, it recommends that the Commission determine that the accident at Three Mile Island did not constitute an extraordinary nuclear occurrence.

  18. Development of nuclear methods for determining fluid-dynamic parameters in fluid catalyst cracking reactors

    International Nuclear Information System (INIS)

    Santos, V.A. dos; Dantas, C.C.

    1986-01-01

    Flow parameters of circulating fluidized bed in a simulated Fluid Catalyst Cracking reactor were determined by means of nuclear methods. The parameters were: residence time, density, inventory, circulation rate and radial distribution, for the catalyst; residence time for the gaseous phase. The nuclear methods where the gamma attenuation and the radiotracer. Two tracer techniques were developed, one for tagging of the catalyst by the 59 Fe as intrinsic tracer and another for tagging of the gaseous phase by the CH 3 82 Br as tracer. A detailed description of each measuring technique for all the investigated parameters is included. To carry out the determination for some of parameters a combination of the two methods was also applied. The results and the nuclear data are given in a table. (Author) [pt

  19. Determination of the source rate released into the environment from a nuclear power plant

    International Nuclear Information System (INIS)

    Jeong, H. J.; Kim, E. H.; Suh, K. S.; Hwang, W. T.; Han, M. H.; Lee, H. K.

    2005-01-01

    A study was carried out to determine the source rate from a nuclear power plant using the tracer experimental data conducted at the Yeoung-Kwang nuclear site. The least squares method optimises the agreement between the released source rate and the calculated source rate by minimising the errors between the measured concentrations and the calculated ones using the Gaussian plume model. The least squares estimator generally estimates the source rate to be within a factor of 2. The forecasting ability of the source rate is improved by applying the modified dispersion coefficients that are calculated using the experimental data. Determination of the source rate in an early phase nuclear emergency will be helpful for the decision making when taking appropriate and prompt countermeasures in the case of a radiological emergency. (authors)

  20. Applications of pulsed nuclear magnetic resonance to chemistry: multiple-pulse NMR, cross polarization, magic-angle spinning annd instrumental design

    Energy Technology Data Exchange (ETDEWEB)

    Murphy, P.D.

    1979-07-01

    Pulsed Nuclear Magnetic Resonance (NMR) has been applied to: (1) Measurements of the prinicpal components of the proton shielding tensors of the hydrides of zirconium chloride and zirconium bromide. Multiple-Pulse techniques have been used to remove static homonuclear dipolar coupling. The anisotropies and isotropic shifts of these tensors have been used to infer the possible locations of the hydrogen within the sandwich-like layers of these unusual compounds. (2) Studies of the oscillatory transfer of magnetic polarization between /sup 1/H and /sup 29/Si in substituted silanes. The technique of J Cross Polarization has been used to enhance sensitivity. The /sup 29/Si NMR shifts of -Si-O- model compounds have been investigated as a possible probe for future studies of the environment of bound oxygen in coal-derived liquids. (3) Measurements of the aromatic fraction of /sup 13/C in whole coals. The techniques of /sup 1/H-/sup 13/C Cross Polarization and Magic-Angle Spinning have been used to enhance sensitivity and remove shift anisotropy. Additional topics described are: (4) Calculation and properties of the broadened lineshape of the shileding Powder Pattern. (5) Calculation of the oscillatory transfer of magnetic polarization for an I-S system. (6) Numerical convolution and its uses. (7) The technique of digital filtering applied in the frequency domain. (8) The designs and properties of four NMR probe-circuits. (9) The design of a single-coil double-resonance probe for combined Magic-Angle Spinning and Cross Polarization. (10) The designs of low Q and high Q rf power amplifiers with emphasis on the rf matching circuitry.

  1. Determining the potential volume of industrial process steam to be generated in nuclear facilities

    International Nuclear Information System (INIS)

    Jobsky, T.

    1990-01-01

    The present study serves to determine the market potential of nuclear energy for industrial process steam supply according to branches and sites in the Federal Republic of Germany (excluding the new East German Laender). On the nuclear plant side two HTR reference plants with different unit powers of 200 MWth (HTR-Modul) and 100 MWth are investigated. An essential result in analysing the nuclear market potential is the finding that the number of potential users and sites will triple if smaller unit sizes were introduced. This corresponds to an increase in nuclear plant potential from 28 units of 200 MWth each to 91 units of 100 MWth on the assumptions made in this study. A comparison of economic efficiency between fossil-fired power production plants and the HTR-Modul shows the competitiveness of nuclear process steam and electricity production in the base load range. A single-site evaluation for the centres of energy demand competes conceptually with a combined heat supply by nuclear long-distance energy. This integrated supply concept makes it possible to supply considerably more industrial companies with process steam while reducing the number of sites, since the heat requirements of smaller sites can also be covered by the integrated system. (orig.) [de

  2. Determination of activation level energy of nuclear isomers by calibration of microspectra of radioactive sources

    International Nuclear Information System (INIS)

    Veres, A.; Pavlicsek, I.

    1980-01-01

    Nuclear isomers with unknown activation level were irradiated by calibrated radioactive sources. The integral cross sections were calculated for different energies of the sources. The activation energy was given by values coinciding with each other within the limits of error. The method made the determination of the unknown level of 1180+-10 keV of 195 Pt nucleus possible. (author)

  3. Reserve seismic capacity determination of a nuclear power plant braced frame with piping

    International Nuclear Information System (INIS)

    Nelson, T.A.

    1979-01-01

    The Lawrence Livermore Laboratory has been asked by the U.S. Nuclear Regulatory Commission to investigate the inelastic behavior of a representative non-category I structure to determine the amount of reserve seismic capacity that is available beyond elastic design levels. This reserve capacity can be an important consideration when evaluating the ability of existing structures to withstand upgraded seismic hazards. (orig.)

  4. Quantitative determination of impurities in nuclear grade aluminum by Flame-Atomic Absorption Spectrometry

    International Nuclear Information System (INIS)

    Jat, J.R.; Nayak, A.K.; Balaji Rao, Y.; Ravindra, H.R.

    2013-01-01

    The paper deals with quantitative determination of impurity elements in nuclear grade aluminum, used as fin tubes in research reactors, by Flame-Atomic Absorption Spectrometry (F-AAS). The results have been compared with those obtained by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES) method. Experimental conditions used in both the methods are given in the paper. (author)

  5. Acceptance criteria for determining armed response force size at nuclear power plants

    International Nuclear Information System (INIS)

    1983-02-01

    This guidance document contains acceptance criteria to be used in the NRC license review process. It consists of a scored worksheet and guidelines for interpreting the worksheet score that can be used in determining the adequacy of the armed response force size at a nuclear power reactor facility

  6. Determination of strontium transfer coefficients in soil-plant system at nuclear power plant sites

    International Nuclear Information System (INIS)

    Szabova, T.; Bartha, S.; Mitro, A.; Sipko, J.

    1985-01-01

    In the surroundings of the Mochovce and Dukovany nuclear power plants samples were taken of soils and some plants, namely wheat, barley, clover and lucerne. Strontium was determined by flame emission spectrometry. The found strontium transfer coefficients and discrimination factors in the soil-plant system are tabulated for both localities. (E.S.)

  7. Determination of metallic impurities in nuclearly pure uranium compounds by electrothermal spectrophotometry

    International Nuclear Information System (INIS)

    Franco, M.B.

    1986-01-01

    Atomic absorption spectrometry, with electrothermal atomization, has been used for the determination of Al, Cd, Cr, Fe, Mn and Ni in uranium oxide standards. The analysis were performed without sample dissolution and without uranium chemical separation. This technique is adequate for the qualification of nuclearly pure uranium, according to the standard specifications. (Author) [pt

  8. Neutron spin precession in samples of polarised nuclei and neutron spin phase imaging

    Energy Technology Data Exchange (ETDEWEB)

    Piegsa, Florian Michael

    2009-07-09

    The doublet neutron-deuteron (nd) scattering length b{sub 2,d}, which is at present only known with an accuracy of 5%, is particularly well suited to fix three-body forces in novel effective field theories at low energies. The understanding of such few-nucleon systems is essential, e.g. for predictions of element abundances in the big-bang and stellar fusion. b{sub 2,d} can be obtained via a linear combination of the spin-independent nd scattering length b{sub c,d} and the spin-dependent one, b{sub i,d}. The aim of this thesis was to perform a high-accuracy measurement of the latter to improve the relative accuracy of b{sub 2,d} below 1%. The experiment was performed at the fundamental neutron physics beam line FUNSPIN at the Paul Scherrer Institute in Switzerland. It utilises the effect that the spin of a neutron passing through a target with polarised nuclei performs a pseudomagnetic precession proportional to the spin-dependent scattering length of the nuclei. An ideal method to measure this precession angle very accurately is Ramsey's atomic beam technique, adapted to neutrons. The most crucial part of the experimental setup is the so-called frozen spin target, which consists of a specially designed dilution refrigerator and contains a sample with dynamically polarised nuclear spins. The polarisation of the sample is determined by nuclear magnetic resonance (NMR) techniques. It turned out that the relaxation of the nuclear spins during the necessary ''cross-calibration'' of the two employed NMR systems is ultimately limiting the achievable accuracy of b{sub i,d}. During the extensive use of the Ramsey resonance method in the neutron-deuteron experiment, an idea emerged that the applied technique could be exploited in a completely different context, namely polarised neutron radiography. Hence, the second part of the thesis covers the development of a novel neutron radiography technique, based on the spin-dependent interaction of the

  9. Development and implementation of methods for determination of the origin of nuclear materials

    International Nuclear Information System (INIS)

    Wallenius, M.; Pajo, L.; Mayer, K.

    2001-01-01

    The determination of the origin of seized nuclear material is important for authorities in the context of the criminal investigation, in order to return the material to its last legal owner and to help preventing any further diversion of material from this source. Origin determination is based on a complex pattern of parameters obtained through analytical measurements. The information required to determine the origin of nuclear materials may be divided into two categories: endogenous information (e.g. age or mode of production of the material) which is self-explanatory; whereas exogenous information (e.g. dimensions, surface roughness, impurities) requires a database to which the parameters can be compared. The Institute for Transuranium Elements has developed methods to determine characteristic parameters like impurities, surface roughness, or microstructural information. Furthermore, a database was set up containing relevant information on reactor fuels. (author)

  10. Experimental determination of the spin-rotation coupling constant in the Cs129Xe and K129Xe molecules

    International Nuclear Information System (INIS)

    Wu, Z.; Happer, W.

    1984-01-01

    Since alkali-noble gas van der Waals molecules are involved in the spin transfer process, the physics can be naturally divided into two parts. One of them is to study the formation and break-up rates of the molecules, the chemical equilibrium constant, etc. The other aspect of this problem is to study how the individual angular momenta evolve during the lifetime of the molecule. The experiments described address the second aspect

  11. A simple technique to determine the size distribution of nuclear crater fallback and ejecta

    International Nuclear Information System (INIS)

    Anderson, Brooks D. II

    1970-01-01

    This report describes the results of an investigation to find an economic method for determining the block size distribution of nuclear crater fallback and ejecta. It is shown that the modal analysis method of determining relative proportions can be applied with the use of a special sampling technique, to provide a size distribution curve for clastic materials similar to one obtainable by sieving and weighing the same materials

  12. Determination of plutonium oxidation states at trace levels pertinent to nuclear waste disposal

    International Nuclear Information System (INIS)

    Nitsche, H.; Lee, S.C.; Gatti, R.C.

    1987-04-01

    A scheme was developed for the determination of oxidation states of plutonium in environmental samples. The method involves a combination of solvent extractions and coprecipitation. It was tested on solutions with both high-level and trace-level concentrations. The scheme was used to determine Pu oxidation states in solutions from solubility experiments in groundwater from a potential nuclear waste disposal site. At steady-state conditions, Pu was found to be soluble predominantly as Pu(V) and Pu(VI)

  13. Volumetric determination of hydroxide, aluminate, and carbonate in alkaline solutions of nuclear waste

    International Nuclear Information System (INIS)

    Baumann, E.W.

    1975-06-01

    An integrated procedure was developed for determining OH - , Al(OH) 4 - , and CO 3 2- in alkaline nuclear waste. The free alkali, the hydroxide released when Al(OH) 3 is complexed with oxalate, and the precipitated BaCO 3 were determined by acidimetric titration. With a 50-μl sample, the relative standard deviations were 1 to 2 percent for nonradioactive test solutions and 2 to 5 percent for radioactive process solutions. (U.S.)

  14. Determination of internationally controlled materials according to provisions of the law for the regulations of nuclear source materials, nuclear fuel materials and reactors

    International Nuclear Information System (INIS)

    1984-01-01

    The internationally controlled materials determined according to the law for nuclear source materials, etc. are the following: nuclear source materials, nuclear fuel materials, moderating materials, facilities including reactors, etc. sold, transferred, etc. to Japan according to the agreements for peaceful uses of atomic energy between Japan, and the United States, the United Kingdom, Canada, Australia and France by the respective governments and those organs under them; nuclear fuel materials resulting from usage of the above sold and transferred materials, facilities; nuclear fuel materials sold to Japan according to agreements set by the International Atomic Energy Agency; nuclear fuel materials involved with the safeguards in nuclear weapons non-proliferation treaty with IAEA. (Mori, K.)

  15. The use of voltammetry for determining uranium and associated elements in compounds of nuclear interest

    International Nuclear Information System (INIS)

    Carvalho, F.M.S. de.

    1988-01-01

    The determination of uranium and some trace elements found as impurities in nuclear materials by the voltammetric technique using the hanging mercury drop electrode is presented. Emphasis is given to the determination of uranium, of major interest. Europium and ytterbium are simultaneously determined in fractions of individual lanthanides. A procedure for the simultaneous determination of copper, cadmium, nickel and zinc in water, industrial effluents and uranium compounds is discussed. The advantage of the procedure is its simplicity and easiness of execution, with excellent precision and accuracy. (author) [pt

  16. Electron Spin Dynamics in Semiconductor Quantum Dots

    International Nuclear Information System (INIS)

    Marie, X.; Belhadj, T.; Urbaszek, B.; Amand, T.; Krebs, O.; Lemaitre, A.; Voisin, P.

    2011-01-01

    An electron spin confined to a semiconductor quantum dot is not subject to the classical spin relaxation mechanisms known for free carriers but it strongly interacts with the nuclear spin system via the hyperfine interaction. We show in time resolved photoluminescence spectroscopy experiments on ensembles of self assembled InAs quantum dots in GaAs that this interaction leads to strong electron spin dephasing.

  17. Compartment modelling in nuclear medicine: a new program for the determination of transfer coefficients

    International Nuclear Information System (INIS)

    Hallstadius, L.

    1986-01-01

    In many investigations concerning transport/exchange of matter in a natural system, e.g. functional studies in nuclear medicine, it is advantageous to relate experimental results to a model of the system. A new computer program is presented for the determination of linear transfer coefficients in a compartment model from experimentally observed time-compartment content curves. The program performs a least-square fit with the specified precision of the observed values as weight factors. The resulting uncertainty in the calculated transfer coefficients may also be assessed. The application of the program in nuclear medicine is demonstrated and discussed. (author)

  18. A method for determining the content of knowledge training for nuclear professionals

    International Nuclear Information System (INIS)

    Scott, C.K.

    2004-01-01

    A developer of knowledge training materials for nuclear professionals is faced with the challenge of determining the appropriate scope and depth of training. This paper presents a method for establishing the content starting from overall objectives of the activity and breaking it down into the job and task level of an individual's specific jobs and tasks. Nuclear safety training is used as an example. In this case there are four stages of break down in the knowledge base before its implementation in jobs and tasks of the station's work processes. This process also satisfies the training principles for enabling effective operational decision making. (author)

  19. Antiferromagnetic spin fluctuations and unconventional nodeless superconductivity in an iron-based new superconductor (Ca4Al2O(6-y))(Fe2As2): 75As nuclear quadrupole resonance study.

    Science.gov (United States)

    Kinouchi, H; Mukuda, H; Yashima, M; Kitaoka, Y; Shirage, P M; Eisaki, H; Iyo, A

    2011-07-22

    We report 75As nuclear quadrupole resonance studies on (Ca4Al2O(6-y))(Fe2As2) with T(c) = 27  K. Measurement of nuclear-spin-relaxation rate 1/T1 has revealed a significant development of two-dimensional antiferromagnetic spin fluctuations down to T(c) in association with the smallest As-Fe-As bond angle. Below T(c), the temperature dependence of 1/T1 without any trace of the coherence peak is well accounted for by a nodeless s(±)-wave multiple-gaps model. From the fact that its T(c) is comparable to T(c) = 28  K in the optimally doped LaFeAsO(1-y) in which antiferromagnetic spin fluctuations are not dominant, we remark that antiferromagnetic spin fluctuations are not a unique factor for enhancing T(c) among Fe-based superconductors, but a condition for optimizing superconductivity should be addressed from the lattice structure point of view.

  20. Application of a methodology to determine priorities for nuclear power plant safety issues

    International Nuclear Information System (INIS)

    Daling, P.M.

    1988-01-01

    The Nuclear Regulatory Commission (NRC) Office of Nuclear Regulatory Research (RES) is sponsoring a research program to determine priorities of nuclear power plant safety issues. A methodology has been developed at the Pacific Northwest Laboratory (PNL) to provide technical assistance in the development of risk and cost estimates for implementing resolutions to the safety issues. The information development methods are intended to provide the NRC with a consistent level of information for use in ranking the issues. The NRC uses this information, along with judgmental factors, to rank the issues for further consideration by the NRC staff. The primary purpose of the priority rankings are to assist in the allocation of resources to issues that have high potential for reducing public risk as well as to remove issues from further consideration that have little safety significance

  1. Sub-minute kinetics of human red cell fumarase: 1 H spin-echo NMR spectroscopy and 13 C rapid-dissolution dynamic nuclear polarization.

    Science.gov (United States)

    Shishmarev, Dmitry; Wright, Alan J; Rodrigues, Tiago B; Pileio, Giuseppe; Stevanato, Gabriele; Brindle, Kevin M; Kuchel, Philip W

    2018-03-01

    Fumarate is an important probe of metabolism in hyperpolarized magnetic resonance imaging and spectroscopy. It is used to detect the release of fumarase in cancer tissues, which is associated with necrosis and drug treatment. Nevertheless, there are limited reports describing the detailed kinetic studies of this enzyme in various cells and tissues. Thus, we aimed to evaluate the sub-minute kinetics of human red blood cell fumarase using nuclear magnetic resonance (NMR) spectroscopy, and to provide a quantitative description of the enzyme that is relevant to the use of fumarate as a probe of cell rupture. The fumarase reaction was studied using time courses of 1 H spin-echo and 13 C-NMR spectra. 1 H-NMR experiments showed that the fumarase reaction in hemolysates is sufficiently rapid to make its kinetics amenable to study in a period of approximately 3 min, a timescale characteristic of hyperpolarized 13 C-NMR spectroscopy. The rapid-dissolution dynamic nuclear polarization (RD-DNP) technique was used to hyperpolarize [1,4- 13 C]fumarate, which was injected into concentrated hemolysates. The kinetic data were analyzed using recently developed FmR α analysis and modeling of the enzymatic reaction using Michaelis-Menten equations. In RD-DNP experiments, the decline in the 13 C-NMR signal from fumarate, and the concurrent rise and fall of that from malate, were captured with high spectral resolution and signal-to-noise ratio, which allowed the robust quantification of fumarase kinetics. The kinetic parameters obtained indicate the potential contribution of hemolysis to the overall rate of the fumarase reaction when 13 C-NMR RD-DNP is used to detect necrosis in animal models of implanted tumors. The analytical procedures developed will be applicable to studies of other rapid enzymatic reactions using conventional and hyperpolarized substrate NMR spectroscopy. Copyright © 2018 John Wiley & Sons, Ltd.

  2. Self-diffusion of electrolyte species in model battery electrodes using Magic Angle Spinning and Pulsed Field Gradient Nuclear Magnetic Resonance

    Science.gov (United States)

    Tambio, Sacris Jeru; Deschamps, Michaël; Sarou-Kanian, Vincent; Etiemble, Aurélien; Douillard, Thierry; Maire, Eric; Lestriez, Bernard

    2017-09-01

    Lithium-ion batteries are electrochemical storage devices using the electrochemical activity of the lithium ion in relation to intercalation compounds owing to mass transport phenomena through diffusion. Diffusion of the lithium ion in the electrode pores has been poorly understood due to the lack of experimental techniques for measuring its self-diffusion coefficient in porous media. Magic-Angle Spinning, Pulsed Field Gradient, Stimulated-Echo Nuclear Magnetic Resonance (MAS-PFG-STE NMR) was used here for the first time to measure the self-diffusion coefficients of the electrolyte species in the LP30 battery electrolyte (i.e. a 1 M solution of LiPF6 dissolved in 1:1 Ethylene Carbonate - Dimethyl Carbonate) in model composites. These composite electrodes were made of alumina, carbon black and PVdF-HFP. Alumina's magnetic susceptibility is close to the measured magnetic susceptibility of the LP30 electrolyte thereby limiting undesirable internal field gradients. Interestingly, the self-diffusion coefficient of lithium ions decreases with increasing carbon content. FIB-SEM was used to describe the 3D geometry of the samples. The comparison between the reduction of self-diffusion coefficients as measured by PFG-NMR and as geometrically derived from FIB/SEM tortuosity values highlights the contribution of specific interactions at the material/electrolyte interface on the lithium transport properties.

  3. Determination of discharge authorizations for French basic nuclear installations 58 and public information

    International Nuclear Information System (INIS)

    Tabard, Laurence; Conte, Dorothee

    2013-01-01

    The determination of discharge authorized limits for a French nuclear site is initiated by the request of the operator, based on the maximum nuclear and chemical inventory that could be released during normal operating conditions, accompanied with justifications. Request and justifications are analyzed and discussed by the ASN and the IRSN, taking into account nuclear and chemical inventories expected inside BNI, current regulations (BNI specific regulation, environment code, public health code), operating feedback (release feedback for an operating BNI, feedback coming from other nuclear sites or installations, etc.) and best available technologies that can be used to treat liquid or gaseous waste before release. After taking into account potential suggestions coming from public information or public enquiry concerning the operator request, the discharge authorized limits are settled down in specific ASN prescriptions that have to be ratified by the State secretaries in charge of nuclear safety. The whole process runs through 2 or 3 years to be achieved. Communication has revealed to be quite an uneasy task, even for administrative procedures. This aspect is mostly tested while communicating about events. Consequences of this communication can hardly be foreseen because of multiple external parameters like: news on the front pages at the same moment; historic communication difficulties still in the public mind; technical vocabulary not easily understood; public fear of things being hidden; power of ecologist or non-governmental associations. (authors)

  4. Determining the nuclear data uncertainty on MONK10 and WIMS10 criticality calculations

    Directory of Open Access Journals (Sweden)

    Ware Tim

    2017-01-01

    Full Text Available The ANSWERS Software Service is developing a number of techniques to better understand and quantify uncertainty on calculations of the neutron multiplication factor, k-effective, in nuclear fuel and other systems containing fissile material. The uncertainty on the calculated k-effective arises from a number of sources, including nuclear data uncertainties, manufacturing tolerances, modelling approximations and, for Monte Carlo simulation, stochastic uncertainty. For determining the uncertainties due to nuclear data, a set of application libraries have been generated for use with the MONK10 Monte Carlo and the WIMS10 deterministic criticality and reactor physics codes. This paper overviews the generation of these nuclear data libraries by Latin hypercube sampling of JEFF-3.1.2 evaluated data based upon a library of covariance data taken from JEFF, ENDF/B, JENDL and TENDL evaluations. Criticality calculations have been performed with MONK10 and WIMS10 using these sampled libraries for a number of benchmark models of fissile systems. Results are presented which show the uncertainty on k-effective for these systems arising from the uncertainty on the input nuclear data.

  5. Determining the nuclear data uncertainty on MONK10 and WIMS10 criticality calculations

    Science.gov (United States)

    Ware, Tim; Dobson, Geoff; Hanlon, David; Hiles, Richard; Mason, Robert; Perry, Ray

    2017-09-01

    The ANSWERS Software Service is developing a number of techniques to better understand and quantify uncertainty on calculations of the neutron multiplication factor, k-effective, in nuclear fuel and other systems containing fissile material. The uncertainty on the calculated k-effective arises from a number of sources, including nuclear data uncertainties, manufacturing tolerances, modelling approximations and, for Monte Carlo simulation, stochastic uncertainty. For determining the uncertainties due to nuclear data, a set of application libraries have been generated for use with the MONK10 Monte Carlo and the WIMS10 deterministic criticality and reactor physics codes. This paper overviews the generation of these nuclear data libraries by Latin hypercube sampling of JEFF-3.1.2 evaluated data based upon a library of covariance data taken from JEFF, ENDF/B, JENDL and TENDL evaluations. Criticality calculations have been performed with MONK10 and WIMS10 using these sampled libraries for a number of benchmark models of fissile systems. Results are presented which show the uncertainty on k-effective for these systems arising from the uncertainty on the input nuclear data.

  6. Nuclear spintronics

    OpenAIRE

    Vagner, Israel D.

    2003-01-01

    The electron spin transport in condensed matter, Spintronics, is a subject of rapidly growing interest both scientifically and from the point of view of applications to modern and future electronics. In many cases the electron spin transport cannot be described adequately without accounting for the hyperfine interaction between electron and nuclear spins. Here, the progress in physics and applications of these phenomena will be reviewed.

  7. An investigation on technical bases of emergency plan zone determination of Qinshan Nuclear Power Base

    International Nuclear Information System (INIS)

    Duan Xuyi

    2000-01-01

    According to the general principal and the basic method of determination of emergency zone and safety criteria and in the light of the environmental and accidental release characteristic of Qinshan Nuclear Power Base, the expectation dose of assumed accident of each plant was compared and analyzed. In consideration of the impact factor of the size of emergency plan zone and referring to the information of emergency plan zone determination of other country in the world, the suggestions of determination method of emergency plan zone are proposed

  8. Use of nuclear methods for the analysis of materials and the determination of concentration profiles

    International Nuclear Information System (INIS)

    Darras, R.

    1976-01-01

    The possibilities of the activation analysis and nuclear reaction analysis are presented. These methods allow the oligo-elements and impurities (in trace amounts) to be determined in materials with accuracy and a high sensitivity. They can also be applied to the determination of major elements in a small amount of materials. Surface analysis and concentration profile determination are possible when the nature and energy of the incident particles are judiciously selected. Exemples of analysis of steels, pure iron and refractories are given [fr

  9. Determination of karst collapse intensity indicator in area of nuclear power plant construction using incomplete data

    International Nuclear Information System (INIS)

    Sharapov, R

    2014-01-01

    The paper deals with the definition of karst collapse intensity. The technique for determining the intensity of karst formation and collapse on the basis of calculation and probabilistic method is given. Karst collapse formation is affected by a great variety of natural and anthropogenic factors. Each factor can vary quite widely. The paper describes a technique for determining karst collapse intensity from incomplete data. It uses karst processes monitoring data in the area and monitoring data of areas with similar values of the most significant factors leading to the karst collapses. The method used for determination of karst collapse intensity indicator in area of Nizhny Novgorod nuclear power plant construction

  10. Determination of the spin orbit coupling and crystal field splitting in wurtzite InP by polarization resolved photoluminescence

    Science.gov (United States)

    Chauvin, Nicolas; Mavel, Amaury; Jaffal, Ali; Patriarche, Gilles; Gendry, Michel

    2018-02-01

    Excitation photoluminescence spectroscopy is usually used to extract the crystal field splitting (ΔCR) and spin orbit coupling (ΔSO) parameters of wurtzite (Wz) InP nanowires (NWs). However, the equations expressing the valence band splitting are symmetric with respect to these two parameters, and a choice ΔCR > ΔSO or ΔCR silicon. The experimental results combined with a theoretical model and finite difference time domain calculations allow us to conclude that ΔCR > ΔSO in Wz InP.

  11. Spin current

    CERN Document Server

    Valenzuela, Sergio O; Saitoh, Eiji; Kimura, Takashi

    2017-01-01

    Since the discovery of the giant magnetoresistance effect in magnetic multilayers in 1988, a new branch of physics and technology, called spin-electronics or spintronics, has emerged, where the flow of electrical charge as well as the flow of electron spin, the so-called “spin current,” are manipulated and controlled together. The physics of magnetism and the application of spin current have progressed in tandem with the nanofabrication technology of magnets and the engineering of interfaces and thin films. This book aims to provide an introduction and guide to the new physics and applications of spin current, with an emphasis on the interaction between spin and charge currents in magnetic nanostructures.

  12. Spin-polarized free electron beam interaction with radiation and superradiant spin-flip radiative emission

    Directory of Open Access Journals (Sweden)

    A. Gover

    2006-06-01

    Full Text Available The problems of spin-polarized free-electron beam interaction with electromagnetic wave at electron-spin resonance conditions in a magnetic field and of superradiant spin-flip radiative emission are analyzed in the framework of a comprehensive classical model. The spontaneous emission of spin-flip radiation from electron beams is very weak. We show that the detectivity of electron spin resonant spin-flip and combined spin-flip/cyclotron-resonance-emission radiation can be substantially enhanced by operating with ultrashort spin-polarized electron beam bunches under conditions of superradiant (coherent emission. The proposed radiative spin-state modulation and the spin-flip radiative emission schemes can be used for control and noninvasive diagnostics of polarized electron/positron beams. Such schemes are of relevance in important scattering experiments off nucleons in nuclear physics and off magnetic targets in condensed matter physics.

  13. Spin Electronics

    Science.gov (United States)

    2003-08-01

    applications, a ferromagnetic metal may be used as a source of spin-polarized electronics to be injected into a semiconductor, a superconductor or a...physical phenomena in II-VI and III-V semiconductors. In II-VI systems, the Mn2+ ions act to boost the electron spin precession up to terahertz ...conductors, proximity effect between ferromagnets and superconductors , and the effects of spin injection on the physical properties of the

  14. Spin doctoring

    OpenAIRE

    Vozková, Markéta

    2011-01-01

    1 ABSTRACT The aim of this text is to provide an analysis of the phenomenon of spin doctoring in the Euro-Atlantic area. Spin doctors are educated people in the fields of semiotics, cultural studies, public relations, political communication and especially familiar with the infrastructure and the functioning of the media industry. Critical reflection of manipulative communication techniques puts spin phenomenon in historical perspective and traces its practical use in today's social communica...

  15. On the determination of the spin of the black hole in Cyg X-1 from X-ray reflection spectra

    Science.gov (United States)

    Fabian, A. C.; Wilkins, D. R.; Miller, J. M.; Reis, R. C.; Reynolds, C. S.; Cackett, E. M.; Nowak, M. A.; Pooley, G. G.; Pottschmidt, K.; Sanders, J. S.; Ross, R. R.; Wilms, J.

    2012-07-01

    The spin of Cygnus X-1 is measured by fitting reflection models to Suzaku data covering the energy band 0.9-400 keV. The inner radius of the accretion disc is found to lie within 2 gravitational radii (rg=GM/c2), and a value of ? is obtained for the dimensionless black hole spin. This agrees with recent measurements using the continuum fitting method by Gou et al. and of the broad iron line by Duro et al. The disc inclination is measured at ?, which is consistent with the recent optical measurement of the binary system inclination by Orosz et al. of 27°± 0?8. We pay special attention to the emissivity profile caused by irradiation of the inner disc by the hard power-law source. The X-ray observations and simulations show that the index q of that profile deviates from the commonly used, Newtonian, value of 3 within 3rg, steepening considerably within 2rg, as expected in the strong gravity regime.

  16. On the Determination of the Spin of the Black Hole in Cyg X-1 from X-Ray Reflection Spectra

    Science.gov (United States)

    Fabian, A. C.; Wilkins, D.; Miller, J. M.; Reis, R. C.; Reynolds, C. S.; Cackett, E. M.; Nowak, M. A.; Pooley, G.; Pottschmidt, K.; Sanders, J. S.; hide

    2012-01-01

    The spin of Cygnus X-I is measured by fitting reflection models to Suzaku data covering the energy band 0.9-400 keY. The inner radius of the accretion disc is found to lie within 2 gravitational radii (rg = GM/c(exp 2)) and a value for the dimensionless black hole spin is obtained of 0.97(sup .0.14) (sup -0.02). This agrees with recent measurements using the continuum fitting method by Gou et al. and of the broad iron line by Duro et al. The disc inclination is measured at 23.7(sup +6.7) (sup -5.4) deg. which is consistent with the recent optical measurement of the binary system inclination by Orosz et al of 27+/- 0.8 deg. We pay special attention to the emissivity profile caused by irradiation of the inner disc by the hard power-law source. 1be X-ray observations and simulations show that the index q of that profile deviates from the commonly used, Newtonian, value of 3 within 3r(sub g), steepening considerably within 2r(sub g). as expected in the strong gravity regime.

  17. Gross shell structure at high spin in heavy nuclei

    International Nuclear Information System (INIS)

    Deleplanque, Marie-Agnes; Frauendorf, Stefan; Pashkevich, Vitaly V.; Chu, S.Y.; Unzhakova, Anja

    2003-01-01

    Experimental nuclear moments of inertia at high spins along the yrast line have been determined systematically and found to differ from the rigid-body values. The difference is attributed to shell effect and these have been calculated microscopically. The data and quantal calculations are interpreted by means of the semiclassical Periodic Orbit Theory. From this new perspective, features in the moments of inertia as a function of neutron number and spin, as well as their relation to the shell energies can be understood. Gross shell effects persist up to the highest angular momenta observed

  18. Level spin assignment of superdeformed bands for A ∼ 190 region

    International Nuclear Information System (INIS)

    Zhou Chunmei; Liu Tong

    1994-01-01

    About 50 superdeformed (SD) bands in nuclei with A∼190, 150, and 130 regions have been observed in recent years. The level spins of SD bands can not be fully determined from the experimental measurements. The level energy formula of nuclear rotational bands can be used to fit transition γ-ray energies within SD band to assign the level spin. The level spins extracted from these fits of 27 SD bands in nuclei of A∼190 region are obtained and compared with those of others

  19. Low-field cross spin relaxation of L8i in superconducting NbSe2

    Science.gov (United States)

    Hossain, M. D.; Salman, Z.; Wang, D.; Chow, K. H.; Kreitzman, S.; Keeler, T. A.; Levy, C. D. P.; Macfarlane, W. A.; Miller, R. I.; Morris, G. D.; Parolin, T. J.; Pearson, M.; Saadaoui, H.; Kiefl, R. F.

    2009-04-01

    A low energy beam of spin polarized L8i has been used to investigate nuclear spin relaxation in the multiband superconductor NbSe2 . In low magnetic fields there is significant cross relaxation between the L8i and the host N93b spins, which is driven by low frequency fluctuations in the nuclear magnetic dipolar interaction. The rate of cross relaxation is strongly field dependent and thus the 1/T1 spin relaxation rate of the L8i is a sensitive monitor of the static local magnetic field B just below the surface. This in turn is used to determine the absolute value of the magnetic penetration depth λ in the Meissner state. The temperature variations in 1/T1 and λ are consistent with a wide distribution of superconducting gaps expected for a multiband superconductor.

  20. Bioactive conformation of stromelysin inhibitors determined by transferred nuclear Overhauser effects.

    OpenAIRE

    Gonnella, N C; Bohacek, R; Zhang, X; Kolossváry, I; Paris, C G; Melton, R; Winter, C; Hu, S I; Ganu, V

    1995-01-01

    The transferred nuclear Overhauser effect has been used to determine the biologically active conformations of two stromelysin inhibitors. Both inhibitors used in this study were hydroxamic acids generated via chemical synthesis. These structures, representing the conformation of each inhibitor bound to stromelysin, superimposed with excellent agreement. The study also provided information on the shape and orientation of the S2' and S1' pockets of the enzyme relative to thermolysin. Comparison...

  1. Spectrographic determination of metallic impurities in organic coolants for nuclear reactors

    International Nuclear Information System (INIS)

    Martin Munoz, M.; Alvarez Gonzalez, F.

    1969-01-01

    A spectrochemical method for determining metallic impurities in organic coolants for nuclear reactors is given. The organic matter in solid samples is eliminated by controlled distillation and dry ashing in the presence of magnesium oxide as carrier. Liquid, samples are vacuum distillated. The residue is analyzed by carrier distillation and by total burning techniques. The analytical results are discussed and compared with those obtained destroying the organic matter without carrier and using the copper spark technique. (Author) 12 refs

  2. Determination of nuclear cross-section of 81Br (n,,,) Br82 reaction by ...

    African Journals Online (AJOL)

    ... flux of 4.2 x 1013 n cm-2 s-1. The BaBr2 was chemically processed and measured as Hydrogen Bromide (HBr82). The value of nuclear cross-section was determined to be 2.1 0.2 barns, which falls within the range of values as previously reported elsewhere. (Journal of Applied Science and Technology: 2001 6(1-2): 4-6) ...

  3. APPLICATION OF FUZZY COGNITIVE MAPS ON POLICY ANALYSIS: DETERMINING THE POLICY OF SUPPORTING THE ACADEMIC SPIN OFFS

    Directory of Open Access Journals (Sweden)

    Danny P. Soetanto

    2002-01-01

    Full Text Available Fuzzy Cognitive Map (FCM is a type of artificial neural network. It can be viewed as a weighted directed graph in which vertices represent concepts and edges represent causal links between them. An FCM can be used as an intelligent decision support system (DSS tool. It works by representing important issues in a given situation and their causal relationships. The evolution of a dynamic system with time can be simulated and the behavior of the systems can be predicted and explained using an FCM. In this case FCM is used to ditermine the policy to support the academic spin off. Simulation brings forth some conclusions and the best policy can be chosen.

  4. Isolation and activity determination of 99Tc in nuclear waste by liquid scintillation counting

    International Nuclear Information System (INIS)

    Reis Junior, Aluisio S.; Temba, Eliane S.C.; Kastner, Geraldo F.; Monteiro, Roberto P.G.

    2011-01-01

    A radiochemical separation and purification for technetium was proposed for radioactive waste in which rhenium is to be used as a yield monitor. The separation was performed by anion exchange chromatography and the purification was performed by extraction chromatography using a TEVA resin.The determination of 99 Tc was by liquid scintillation counting and rhenium was activated by Triga Mark 1 research reactor and measured by gamma spectrometry. Some real samples of nuclear waste such as evaporator concentrate and filter were analysed. The chemical recovery determined using rhenium as tracer was around 90 %. (author)

  5. In-flow technology for the determination of Sr-90 concentrations in nuclear power plants

    International Nuclear Information System (INIS)

    Dissing, E.

    1982-01-01

    Outlines for a future work concerning in-flow surveillance of Sr-90 in nuclear plant process treams have been studied. The many problems involved with the task of on-line Sr-90 determination were approached in two different ways, one applying β-counting of the 64-hour daughter Y-60 with the use of the process stream itself as a Cerenkov scintillator and the other - indirect - using simultaneous measurement of the concentrations of Sr-91 and Sr-92 for the determination of the leakage route for strontium. (Author)

  6. System for determining the type of nuclear radiation from detector output pulse shape

    Science.gov (United States)

    Miller, William H.; Berliner, Ronald R.

    1994-01-01

    A radiation detection system determines the type of nuclear radiation received in a detector by producing a correlation value representative of the statistical cross correlation between the shape of the detector signal and pulse shape data previously stored in memory and characteristic of respective types of radiation. The correlation value is indicative of the type of radiation. The energy of the radiation is determined from the detector signal and is used to produce a spectrum of radiation energies according to radiation type for indicating the nature of the material producing the radiation.

  7. Determination of water in nuclear materials by means of the Karl Fischer method

    International Nuclear Information System (INIS)

    Pereira, W.; Rocha, S.M.R.; Atalla, L.T.; Abrao, A.

    1987-06-01

    Karl Fischer Method was adapted for water determination in uranium coumpounds and substances of nuclear interest, by using a comercial equipment. The experimental conditions for the analysis of U 3 O 8 , UO 3 , UO 2 , UF 4 KFnHF and (NH 4 ) 4 UO 2 (CO 3 ) 3 were established. The influence of the agitation and contact time between sample and solvent, of the sample weight, of the reaction end point determination and of the sample granulometry on the precision and accuracy of results was also studied. (Author) [pt

  8. Precise determination of comparison base lines at the Paks nuclear power station site

    International Nuclear Information System (INIS)

    Horvath, K.; L'Aune, O.

    1983-01-01

    An exact length-determination of five comparator bases performed on the site of the Paks nuclear power station is presented. Preliminary accuracy tests were carried out regarding the instruments applied, the repetition number used in the measurements and the measuring methods. The applied statistical calibration method is discussed in detail. The measuring series was repeated under different atmospheric conditions in summer and winter. The precision numbers obtained make the reference lines suitable for the traditional calibration of the measuring tapes and for the determination of the constants in the electrooptical distance measuring devices with small and medium range, especially those in the MEKOMETER that offers the highest accuracy. (author)

  9. Determination of 93Zr in medium and low level radioactive wastes from Brazilian nuclear power plants

    International Nuclear Information System (INIS)

    Oliveira, Thiago C.; Oliveira, Arno H.

    2015-01-01

    The majority of long-lived radionuclides produced in the nuclear power plants can be regarded as difficult-to-measure radionuclides (RDM), hence chemical separation is necessary before the nuclear measurement of them. The zirconium isotope 93 Zr is a long-lived pure β-particle-emitting radionuclide produced from 235 U fission and from neutron activation of the stable isotope 92 Zr and thus occurring as one of the radionuclides found in nuclear reactors. Due to its long half-life, 93 Zr is one of the radionuclides of interest for the performance of assessment studies of waste storage or disposal. Two different methodologies based on extractive resins and LSC and ICP-MS techniques that enables the 93 Zr determination in medium (ILW) and low level (LLW) radioactive wastes samples from Brazilian nuclear power plants has been developed in our laboratory. Analyzing real samples 65% and 75% chemical yields for 93 Zr recovery were achieved for ICP-MS and LSC techniques, respectively. The detection limits were 0.045 μg.L -1 for ICP-MS and 0.05 Bq.L -1 for LSC techniques. (author)

  10. Spin glasses

    CERN Document Server

    Bovier, Anton

    2007-01-01

    Spin glass theory is going through a stunning period of progress while finding exciting new applications in areas beyond theoretical physics, in particular in combinatorics and computer science. This collection of state-of-the-art review papers written by leading experts in the field covers the topic from a wide variety of angles. The topics covered are mean field spin glasses, including a pedagogical account of Talagrand's proof of the Parisi solution, short range spin glasses, emphasizing the open problem of the relevance of the mean-field theory for lattice models, and the dynamics of spin glasses, in particular the problem of ageing in mean field models. The book will serve as a concise introduction to the state of the art of spin glass theory, usefull to both graduate students and young researchers, as well as to anyone curious to know what is going on in this exciting area of mathematical physics.

  11. Range of Applicability and Bias Determination for Postclosure Criticality of Commercial Spent Nuclear Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Radulescu, Georgeta [ORNL; Mueller, Don [ORNL; Goluoglu, Sedat [ORNL; Hollenbach, Daniel F [ORNL; Fox, Patricia B [ORNL

    2007-10-01

    The purpose of this calculation report, Range of Applicability and Bias Determination for Postclosure Criticality of Commercial Spent Nuclear Fuel, is to validate the computational method used to perform postclosure criticality calculations. The validation process applies the criticality analysis methodology approach documented in Section 3.5 of the Disposal Criticality Analysis Methodology Topical Report. The application systems for this validation consist of waste packages containing transport, aging, and disposal canisters (TAD) loaded with commercial spent nuclear fuel (CSNF) of varying assembly types, initial enrichments, and burnup values that are expected from the waste stream and of varying degree of internal component degradation that may occur over the 10,000-year regulatory time period. The criticality computational tool being evaluated is the general-purpose Monte Carlo N-Particle (MCNP) transport code. The nuclear cross-section data distributed with MCNP 5.1.40 and used to model the various physical processes are based primarily on the Evaluated Nuclear Data File/B Version VI (ENDF/B-VI) library. Criticality calculation bias and bias uncertainty and lower bound tolerance limit (LBTL) functions for CSNF waste packages are determined based on the guidance in ANSI/ANS 8.1-1998 (Ref. 4) and ANSI/ANS 8.17-2004 (Ref. 5), as described in Section 3.5.3 of Ref. 1. The development of this report is consistent with Test Plan for: Range of Applicability and Bias Determination for Postclosure Criticality. This calculation report has been developed in support of licensing activities for the proposed repository at Yucca Mountain, Nevada, and the results of the calculation may be used in the criticality evaluation for CSNF waste packages based on a conceptual TAD canister.

  12. Spin correlations in Ho2Ti2O7: A dipolar spin ice system

    DEFF Research Database (Denmark)

    Bramwell, S.T.; Harris, M.J.; Hertog, B.C. den

    2001-01-01

    described by a nearest neighbor spin ice model and very accurately described by a dipolar spin ice model. The heat capacity is well accounted for by the sum of a dipolar spin ice contribution and an expected nuclear spin contribution, known to exist in other Ho(3+) salts. These results settle the question......The pyrochlore material Ho(2)Ti(2)O(7) has been suggested to show "spin ice" behavior. We present neutron scattering and specific heat results that establish unambiguously that Ho(2)Ti(2)O(7) exhibits spin ice correlations at low temperature. Diffuse magnetic neutron scattering is quite well...

  13. ON THE INFERENCE OF THE COSMIC-RAY IONIZATION RATE ζ FROM THE HCO{sup +}-to-DCO{sup +} ABUNDANCE RATIO: THE EFFECT OF NUCLEAR SPIN

    Energy Technology Data Exchange (ETDEWEB)

    Shingledecker, Christopher N.; Le Gal, Romane; Hincelin, Ugo; Herbst, Eric [Department of Chemistry, University of Virginia, Charlottesville, VA 22904 (United States); Bergner, Jennifer B. [Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138 (United States); Öberg, Karin I., E-mail: shingledecker@virginia.edu [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)

    2016-10-20

    The chemistry of dense interstellar regions was analyzed using a time-dependent gas–grain astrochemical simulation and a new chemical network that incorporates deuterated chemistry, taking into account nuclear spin states for the hydrogen chemistry and its deuterated isotopologues. With this new network, the utility of the [HCO{sup +}]/[DCO{sup +}] abundance ratio as a probe of the cosmic-ray ionization rate has been re-examined, with special attention paid to the effect of the initial value of the ortho-to-para ratio (OPR) of molecular hydrogen. After discussing the use of the probe for cold cores, we compare our results with previous theoretical and observational results for a molecular cloud close to the supernova remnant W51C, which is thought to have an enhanced cosmic-ray ionization rate ζ caused by the nearby γ -ray source. In addition, we attempt to use our approach to estimate the cosmic-ray ionization rate for L1174, a dense core with an embedded star. Beyond the previously known sensitivity of [HCO{sup +}]/[DCO{sup +}] to ζ , we demonstrate its additional dependence on the initial OPR and, secondarily, on the age of the source, its temperature, and its density. We conclude that the usefulness of the [HCO{sup +}]/[DCO{sup +}] abundance ratio in constraining the cosmic-ray ionization rate in dense regions increases with the age of the source and the ionization rate as the ratio becomes far less sensitive to the initial value of the OPR.

  14. Nuclear spin relaxation of {sup 8}Li in a thin film of La{sub 0.67}Ca{sub 0.33}MnO{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Miller, R.I. [TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, Canada V6T 2A3 (Canada); Arseneau, D. [TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, V6T 2A3 (Canada); Chow, K.H. [Department of Physics, University of Alberta, Edmonton, Alta., T6G 2J1 (Canada); Daviel, S. [TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, V6T 2A3 (Canada); Engelbertz, A. [TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, V6T 2A3 (Canada); Hossain, MD. [Department of Physics and Astronomy, University of British Columbia, Vancouver, BC, V6T 1Z1 (Canada); Keeler, T. [Department of Physics and Astronomy, University of British Columbia, Vancouver, BC, V6T 1Z1 (Canada); Kiefl, R.F. [TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, V6T 2A3 (Canada)]|[Department of Physics and Astronomy, University of British Columbia, Vancouver, BC, Canada V6T 1Z1 (Canada)]|[Canadian Institute for Advanced Research, Toronto, Ont., Canada M5G 1Z8 (Canada)]. E-mail: kiefl@triumf.ca; Kreitzman, S. [TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, V6T 2A3 (Canada); Levy, C.D.P. [TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, V6T 2A3 (Canada); Morales, P. [Department of Physics, University of Toronto, Toronto, Ont., M5S 1A7 (Canada); Morris, G.D. [TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, V6T 2A3 (Canada); MacFarlane, W.A. [TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, V6T 2A3 (Canada): Department of Chemistry, University of British Columbia, Vancouver, BC, V6T 1Z1 (Canada); Parolin, T.J. [Department of Chemistry, University of British Columbia, Vancouver, BC, V6T 1Z1 (Canada); Poutissou, R. [TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, V6T 2A3 (Canada); Saadaoui, H.; Wang, D. [Department of Physics and Astronomy, University of British Columbia, Vancouver, BC, V6T 1Z1 (Canada); Salman, Z. [TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, V6T 2A3 (Canada); Wei, J.Y.T. [Canadian Institute for Advanced Research, Toronto, Ont., M5G 1Z8 (Canada)]|[Department of Physics, University of Toronto, Toronto, Ont., M5S 1A7 (Canada)

    2006-03-31

    We report {beta}-NMR measurements of the nuclear spin relaxation rate (1/T{sub 1}) in a thin film of La{sub 0.67}Ca{sub 0.33}MnO{sub 3} (LCMO) using a low-energy beam of spin-polarized {sup 8}Li. In a small magnetic field of 150G, there is a broad peak in 1/T{sub 1} near the Curie temperature (T{sub c}=259K) and a dramatic decrease in 1/T{sub 1} at lower temperatures. This is attributed to a critical slowing down of the spin fluctuations near T{sub c} and freezing of the magnetic excitations at low temperatures, respectively. In addition, there is a small amplitude, slow relaxing component at high temperatures, which we attribute to {sup 8}Li in the SrTiO{sub 3} substrate. There is an indication that the spin relaxation rate in the substrate is also peaked at T{sub c} due to close proximity to the magnetic film. These results establish that low-energy {beta}-NMR can be used as a probe of magnetic fluctuations in magnetic thin films over a wide range of temperatures.

  15. Selective One-Dimensional Total Correlation Spectroscopy Nuclear Magnetic Resonance Experiments for a Rapid Identification of Minor Components in the Lipid Fraction of Milk and Dairy Products: Toward Spin Chromatography?

    Science.gov (United States)

    Papaemmanouil, Christina; Tsiafoulis, Constantinos G; Alivertis, Dimitrios; Tzamaloukas, Ouranios; Miltiadou, Despoina; Tzakos, Andreas G; Gerothanassis, Ioannis P

    2015-06-10

    We report a rapid, direct, and unequivocal spin-chromatographic separation and identification of minor components in the lipid fraction of milk and common dairy products with the use of selective one-dimensional (1D) total correlation spectroscopy (TOCSY) nuclear magnetic resonance (NMR) experiments. The method allows for the complete backbone spin-coupling network to be elucidated even in strongly overlapped regions and in the presence of major components from 4 × 10(2) to 3 × 10(3) stronger NMR signal intensities. The proposed spin-chromatography method does not require any derivatization steps for the lipid fraction, is selective with excellent resolution, is sensitive with quantitation capability, and compares favorably to two-dimensional (2D) TOCSY and gas chromatography-mass spectrometry (GC-MS) methods of analysis. The results of the present study demonstrated that the 1D TOCSY NMR spin-chromatography method can become a procedure of primary interest in food analysis and generally in complex mixture analysis.

  16. Characteristics of the tomato nuclear genome as determined by sequencing undermethylated EcoRI digested fragments

    DEFF Research Database (Denmark)

    Wang, Y.; van der Hoeven, R. S.; Nielsen, Rasmus

    2005-01-01

    A collection of 9,990 single-pass nuclear genomic sequences, corresponding to 5 Mb of tomato DNA, were obtained using methylation filtration (MF) strategy and reduced to 7,053 unique undermethylated genomic islands (UGIs) distributed as follows: (1) 59% non-coding sequences, (2) 28% coding...... sequences, (3) 12% transposons-96% of which are class I retroelements, and (4) 1% organellar sequences integrated into the nuclear genome over the past approximately 100 million years. A more detailed analysis of coding UGIs indicates that the unmethylated portion of tomato genes extends as far as 676 bp...... upstream and 766 bp downstream of coding regions with an average of 174 and 171 bp, respectively. Based on the analysis of the UGI copy distribution, the undermethylated portion of the tomato genome is determined to account for the majority of the unmethylated genes in the genome and is estimated...

  17. Determination of internal pressure and the backfill gas composition of nuclear fuel rods

    International Nuclear Information System (INIS)

    Garcia C, M.A.; Cota S, G.; Merlo S, L.; Fernandez T, F.

    1997-01-01

    An important consideration in the nuclear fuel manufacturing is the measurement of the helium atmosphere pressure and its composition analysis inside the nuclear fuel rod. In this work it is presented a system used to measure the internal pressure and to determine the backfill gas composition of fuel rods. The system is composed of an expansion chamber provided of a seals system to assure that when rod is drilled, the gas stays contained inside the expansion chamber. The system is connected to a pressure measurement digital system: Baratron MKS 310-AHS-1000. Range 1000 mm Hg from which the pressure readings are taken when this is stabilized in all the system. After a gas sample is sent toward a Perkin Elmer gas chromatograph, model 8410 with thermal conductivity detector to get the corresponding chromatogram and doing the necessary calculations for obtaining the backfill gas composition of the rod in matter. (Author)

  18. Vanadium in organic fossils as determined by nuclear-physical methods of analysis

    International Nuclear Information System (INIS)

    Nadirov, N.N.; Solodukhin, V.P.

    1998-01-01

    Results are presented of several year investigation to study possibilities of the NPMA for the determination of vanadium in organic fossils and applications of these methods to scientific and practical tasks. For these purposes, various versions of activation analysis (AA), X-ray fluorescence analysis (XRFA), electron spin resonance (ESR) spectroscopy and atomic emission with inductively coupled plasma spectroscopy (AES-ICP). Advantages and pitfalls of individual methods are discussed. The techniques developed can be used for estimation and calculation of stocks of vanadium in organic fossils at the territories of Kazakstan, Tatarstan and along the Volga-river. Analysis results helped in discovering new, industrially important deposits of this valuable metal. Quantitative determination of vanadium was carried out at different stages of technological processes of its extraction from high-viscous oils and oil-bitumen rocks. Results of analyses allowed to reveal the most effective versions of technologies of demetallization of these fossils. Content of vanadium was also studied in different locations of high-viscous oil deposits being explored by the method of inside-stratum burning. Results of analyses showed that the concentration of vanadium in oil decreases considerably with increasing temperature, that is, a considerable part of vanadium (up to 60 percent) may be lost irretrievably. Thus, for the exploration of these deposits a method of vapor-thermal influence onto the stratum was recommended, by using of which the loss of vanadium is insignificant

  19. Determination of leveled costs of electric generation for gas plants, coal and nuclear; Determinacion de costos nivelados de generacion electrica para plantas de gas, carbon y nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Alonso V, G.; Palacios H, J.C.; Ramirez S, J.R.; Gomez, A. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)]. e-mail: galonso@nuclear.inin.mx

    2005-07-01

    The present work analyzes the leveled costs of electric generation for different types of nuclear reactors known as Generation III, these costs are compared with the leveled costs of electric generation of plants with the help of natural gas and coal. In the study several discount rates were used to determine their impact in the initial investment. The obtained results are comparable with similar studies and they show that it has more than enough the base of the leveled cost the nuclear option it is quite competitive in Mexico. Also in this study it is also thinks about the economic viability of a new nuclear power station in Mexico. (Author)

  20. Porosity of silica Stöber particles determined by spin-echo small angle neutron scattering.

    Science.gov (United States)

    Parnell, S R; Washington, A L; Parnell, A J; Walsh, A; Dalgliesh, R M; Li, F; Hamilton, W A; Prevost, S; Fairclough, J P A; Pynn, R

    2016-05-25

    Stöber silica particles are used in a diverse range of applications. Despite their widespread industrial and scientific uses, information on the internal structure of the particles is non-trivial to obtain and is not often reported. In this work we have used spin-echo small angle neutron scattering (SESANS) in conjunction with ultra small angle X-ray scattering (USAXS) and pycnometry to study an aqueous dispersion of Stöber particles. Our results are in agreement with models which propose that Stöber particles have a porous core, with a significant fraction of the pores inaccessible to solvent. For samples prepared from the same master sample in a range of H2O : D2O ratio solutions we were able to model the SESANS results for the solution series assuming monodisperse, smooth surfaced spheres of radius 83 nm with an internal open pore volume fraction of 32% and a closed pore fraction of 10%. Our results are consistent with USAXS measurements. The protocol developed and discussed here shows that the SESANS technique is a powerful way to investigate particles much larger than those studied using conventional small angle scattering methods.

  1. Precision Determination of the Neutron Spin Structure Function {ital g}{sup {ital n}}{sub {ital 1}}

    Energy Technology Data Exchange (ETDEWEB)

    Arnold, R.G.; Bosted, P.E.; Fellbaum, J.N.; Reyna, D.; Rock, S.E.; Sorrell, L.; Szalata, Z.M.; Toole, T. [American University, Washington, D.C. 20016 (United States); Shapiro, G. [University of California, Berkeley, California 94720 (United States); Breton, V.; Fonvieille, H.; Incerti, S. [LPC IN2P3/CNRS, Univ. Blaise Pascal, F-63170 Aubiere Cedex (France); Meyer, W. [University of Bonn, Nussallee 12, D-5300 Bonn (Germany); Averett, T.; Hughes, E.W. [California Institute of Technology, Pasadena, California 91125 (United States); Borel, H.; Lombard-Nelsen, R.; Marroncle, J.; Sabatie, F.; Staley, F.; Terrien, Y. [DAPNIA, Saclay, 91191 Gif-sur-Yvette Cedex (France); Anderson, B.D.; Khayat, M.; Manley, D.M.; Olson, M.; Petratos, G.G.; Watson, J.W.; Zhang, W. [Kent State University, Kent, Ohio 44242 (United States); Ghazikhanian, V.; Igo, G. [University of California, Los Angeles, California 90024-1547 (United States); Berisso, C.M.; Churchwell, S.; Hicks, R.S.; Kolomensky, Y.G.; Peterson, G.A.; Shaw, J. [University of Massachusetts, Amherst, Massachusetts 01003 (United States); Chupp, T.E.; Coulter, K.P.; Smith, T.B.; Welsh, R.C. [University of Michigan, Ann Arbor, Michigan 48109 (United States); Thompson, A.K. [National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Miller, D. [Northwestern University, Evanston, Illinois 60201 (United States); Kuhn, S.E.; Raue, B.; Wesselmann, F. [Old Dominion University, Norfolk, Virginia 23529 (United States); Raines, P. [University of Pennsylvania, Philadelphia, Pennsylvania 19104-6317 (United States); Bogorad, P.; Cates, G.D.; Kumar, K.; Romalis, M.V. [Princeton University, Princeton, New Jersey 08544 (United States); Marvin, T. [Southern Oregon State College, Ashland, Oregon 97520 (United States); Decowski, P. [Smith College, Northampton, Massachusetts 01063 (United States); Akagi, T.; Anthony, P.L.; Buenerd, M.J.; Daoudi, M.; Erickson, R.; and others

    1997-07-01

    We report on a precision measurement of the neutron spin structure function g{sup n}{sub 1} using deep inelastic scattering of polarized electrons by polarized {sup 3}He . For the kinematic range 0.014{lt}x{lt}0.7 and 1{lt}Q{sup 2}{lt}17(GeV /c){sup 2} , we obtain {integral}{sub 0.014}{sup 0.7}g{sup n}{sub 1}(x)dx={minus}0.036{plus_minus}0.004(stat){plus_minus}0.005(syst) at an average Q{sup 2}=5(GeV/c){sup 2}. We find relatively large negative values for g{sup n}{sub 1} at low x . The results call into question the usual Regge theory method for extrapolating to x=0 to find the full neutron integral {integral}{sub 0}{sup 1}g{sup n}{sub 1}(x)dx, needed for testing the quark-parton model and QCD sum rules. {copyright} {ital 1997} {ital The American Physical Society}

  2. Determination of 90Sr in waters of discharge of nuclear power plants

    International Nuclear Information System (INIS)

    Campos, J.M.; Equillor, H.E.

    2010-01-01

    The determination of 90 Sr has some problems because it is a pure beta emitter, and despite the specificity of radiochemical techniques used, their full identification is not always easy, especially when detected low activities. In addition, samples water discharge presents a matrix consisting of a series of fission or activation products, beta / gamma emitters, several of which may interfere with the determination of 90 Sr. This paper describes a simple method for the determination of 90 Sr in water of discharge of nuclear power plants, which is based on the purification of 90 Y, which is used in the ARN since 2009 and has yielded good results to the present, as no interferences were detected in the analysis of the decay of 90 Y. (authors) [es

  3. TOPICAL REVIEW: Spin current, spin accumulation and spin Hall effect

    Directory of Open Access Journals (Sweden)

    Saburo Takahashi and Sadamichi Maekawa

    2008-01-01

    Full Text Available Nonlocal spin transport in nanostructured devices with ferromagnetic injector (F1 and detector (F2 electrodes connected to a normal conductor (N is studied. We reveal how the spin transport depends on interface resistance, electrode resistance, spin polarization and spin diffusion length, and obtain the conditions for efficient spin injection, spin accumulation and spin current in the device. It is demonstrated that the spin Hall effect is caused by spin–orbit scattering in nonmagnetic conductors and gives rise to the conversion between spin and charge currents in a nonlocal device. A method of evaluating spin–orbit coupling in nonmagnetic metals is proposed.

  4. Novel nuclear phenomena in quantum chromodynamics

    International Nuclear Information System (INIS)

    Brodsky, S.J.

    1987-08-01

    Many of the key issues in understanding quantum chromodynamics involve processes in nuclear targets at intermediate energies. A range of hadronic and nuclear phenomena-exclusive processes, color transparency, hidden color degrees of freedom in nuclei, reduced nuclear amplitudes, jet coalescence, formation zone effects, hadron helicity selection rules, spin correlations, higher twist effects, and nuclear diffraction were discussed as tools for probing hadron structure and the propagation of quark and gluon jets in nuclei. Several areas were also reviewed where there has been significant theoretical progress determining the form of hadron and nuclear wave functions, including QCD sum rules, lattice gauge theory, and discretized light-cone quantization. A possible interpretation was also discussed of the large spin correlation A/sub NN/ in proton-proton scattering, and how relate this effect to an energy and angular dependence of color transparency in nuclei. 76 refs., 24 figs

  5. Determination of curium-242 by α spectrometry and mass spectrometry in spent nuclear fuels

    International Nuclear Information System (INIS)

    Chartier, F.; Aubert, M.; Degros, J.P.; Duda, J.M.

    2004-01-01

    Curium-242 is a particularly important isotope in spent nuclear fuels due to its contribution to the residual power and also of its radioactive decrease chain. The determination of its content is therefore essential to improve the knowledge of the nuclear data. According to the nature and the cooling time of the spent fuel, the 242 Cm content can be lower than the detection limit of the classically used mass spectrometric techniques. To overcome this limitation, alpha spectrometry can be advantageously used for this radionuclide of short period (T = 162.9 days). From dilute solutions of MOX fuels of short time of cooling and for which the content of 242 Cm is about a few tens of pg, the development of different successive chemical separations permitted to get sufficiently pure curium fractions to perform curium isotopic analysis by thermal ionization mass spectrometry but also the determination of the 242 Cm/ 244 Cm ratio by alpha spectrometry. The agreement on the ratios determined by the two techniques has allowed to spread the measure by alpha spectrometry to a UOX fuel of content in 242 Cm even lower. The association of the 242 Cm/ 244 Cm ratio measurement with the 244 Cm/ 238 U ratio obtained by thermal ionization mass spectrometry and isotope dilution, with a 248 Cm/ 233 U spike, permits to know the content in curium-242 in relation to uranium-238 which is used as a reference in the fuel. (author)

  6. {sup 129}I level in seawater near a nuclear power plant determined by accelerator mass spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    He Chaohui, E-mail: hechaohui@mail.xjtu.edu.c [School of Nuclear Science and Technology, Xi' an JiaoTong University, No. 28 Xianning West Road, Xi' an, Shaanxi 710049 (China); Xi' an AMS center, No. 99 Yanxiang Road, Yanta Zone, Xi' an, Shaanxi 710054 (China); Hou Xiaolin [State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi' an 710075 (China); Xi' an AMS center, No. 99 Yanxiang Road, Yanta Zone, Xi' an, Shaanxi 710054 (China); Zhao Yaolin; Wang Zhiwen; Li Huaibin [School of Nuclear Science and Technology, Xi' an JiaoTong University, No. 28 Xianning West Road, Xi' an, Shaanxi 710049 (China); Xi' an AMS center, No. 99 Yanxiang Road, Yanta Zone, Xi' an, Shaanxi 710054 (China); Chen Ning; Liu Qi; Zhang Luyuan [State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi' an 710075 (China); Xi' an AMS center, No. 99 Yanxiang Road, Yanta Zone, Xi' an, Shaanxi 710054 (China); Luo Maoyi [School of Nuclear Science and Technology, Xi' an JiaoTong University, No. 28 Xianning West Road, Xi' an, Shaanxi 710049 (China); Xi' an AMS center, No. 99 Yanxiang Road, Yanta Zone, Xi' an, Shaanxi 710054 (China); Liang Wangguo [School of Nuclear Science and Technology, Xi' an JiaoTong University, No. 28 Xianning West Road, Xi' an, Shaanxi 710049 (China); State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi' an 710075 (China); Xi' an AMS center, No. 99 Yanxiang Road, Yanta Zone, Xi' an, Shaanxi 710054 (China); Fan Yukun; Zhao Xiaolei [State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi' an 710075 (China); Xi' an AMS center, No. 99 Yanxiang Road, Yanta Zone, Xi' an, Shaanxi 710054 (China)

    2011-03-11

    {sup 129}I concentration in the seawater samples near a nuclear power plant was determined in the Xi'an Accelerator Mass Spectrometer (AMS) Center. Isotope dilution method was used via addition of excessive amount of stable iodine ({sup 127}I) in the sample before separation, and iodine in the seawater was separated by solvent extraction, and the back extracted iodine in iodide form was precipitated as AgI, which was used as AMS target for {sup 129}I measurement. {sup 125}I tracer was added to monitor the recovery of iodine in the whole separation process. {sup 129}I/{sup 127}I ratios in the prepared target were determined by AMS. The concentration of {sup 127}I in seawater samples was determined by inductively coupled plasma mass spectrometry. The results show that the {sup 129}I/{sup 127}I atomic ratios in the seawater range from 8.29x10{sup -11} to 9.45x10{sup -10}, approximately one order of magnitude higher than that in seaweed collected in the pre-nuclear era, but fall in the environmental level of global fallout.

  7. Spin electronics

    CERN Document Server

    Buhrman, Robert; Daughton, James; Molnár, Stephan; Roukes, Michael

    2004-01-01

    This report is a comparative review of spin electronics ("spintronics") research and development activities in the United States, Japan, and Western Europe conducted by a panel of leading U.S. experts in the field. It covers materials, fabrication and characterization of magnetic nanostructures, magnetism and spin control in magnetic nanostructures, magneto-optical properties of semiconductors, and magnetoelectronics and devices. The panel's conclusions are based on a literature review and a series of site visits to leading spin electronics research centers in Japan and Western Europe. The panel found that Japan is clearly the world leader in new material synthesis and characterization; it is also a leader in magneto-optical properties of semiconductor devices. Europe is strong in theory pertaining to spin electronics, including injection device structures such as tunneling devices, and band structure predictions of materials properties, and in development of magnetic semiconductors and semiconductor heterost...

  8. Spin glasses

    International Nuclear Information System (INIS)

    Fischer, K.H.; Hertz, J.A.

    1993-01-01

    Spin glasses, simply defined by the authors as a collection of spins (i.e., magnetic moments) whose low-temperature state is a frozen disordered one, represent one of the fascinating new fields of study in condensed matter physics, and this book is the first to offer a comprehensive account of the subject. Included are discussions of the most important developments in theory, experimental work, and computer modeling of spin glasses, all of which have taken place essentially within the last two decades. The first part of the book gives a general introduction to the basic concepts and a discussion of mean field theory, while the second half concentrates on experimental results, scaling theory, and computer simulation of the structure of spin glasses

  9. Spin current through quantum-dot spin valves

    International Nuclear Information System (INIS)

    Wang, J; Xing, D Y

    2006-01-01

    We report a theoretical study of the influence of the Coulomb interaction on the equilibrium spin current in a quantum-dot spin valve, in which the quantum dot described by the Anderson impurity model is coupled to two ferromagnetic leads with noncollinear magnetizations. In the Kondo regime, electrons transmit through the quantum dot via higher-order virtual processes, in which the spin of either lead electrons or a localized electron on the quantum dot may reverse. It is found that the magnitude of the spin current decreases with increasing Coulomb interactions due to spin flip effects on the dot. However, the spatial direction of the spin current remains unchanged; it is determined only by the exchange coupling between two noncollinear magnetizations

  10. A set of enhanced green fluorescent protein concatemers for quantitative determination of nuclear localization signal strength.

    Science.gov (United States)

    Böhm, Jennifer; Thavaraja, Ramya; Giehler, Susanne; Nalaskowski, Marcus M

    2017-09-15

    Regulated transport of proteins between nucleus and cytoplasm is an important process in the eukaryotic cell. In most cases, active nucleo-cytoplasmic protein transport is mediated by nuclear localization signal (NLS) and/or nuclear export signal (NES) motifs. In this study, we developed a set of vectors expressing enhanced GFP (EGFP) concatemers ranging from 2 to 12 subunits (2xEGFP to 12xEGFP) for analysis of NLS strength. As shown by in gel GFP fluorescence analysis and αGFP Western blotting, EGFP concatemers are expressed as fluorescent full-length proteins in eukaryotic cells. As expected, nuclear localization of concatemeric EGFPs decreases with increasing molecular weight. By oligonucleotide ligation this set of EGFP concatemers can be easily fused to NLS motifs. After determination of intracellular localization of EGFP concatemers alone and fused to different NLS motifs we calculated the size of a hypothetic EGFP concatemer showing a defined distribution of EGFP fluorescence between nucleus and cytoplasm (n/c ratio = 2). Clear differences of the size of the hypothetic EGFP concatemer depending on the fused NLS motif were observed. Therefore, we propose to use the size of this hypothetic concatemer as quantitative indicator for comparing strength of different NLS motifs. Copyright © 2017 Elsevier Inc. All rights reserved.

  11. Strontium and calcium determination in sea fishes in neighborhood of Angra nuclear power plant

    International Nuclear Information System (INIS)

    Ferreira, L.M.J.

    1985-01-01

    Strontium-90 is an important radionuclide present in the liquid effluents of the Angra Nuclear Power Plant, located in the coastline of Rio de Janeiro State. It has a long effective half-life, easy entry into food chain due to its chemical similarity to calcium and stays for a long time in solution. With the aim of calculating the concentration factor (CF) for 90 Sr and observed ratio (OR) in the most abundant local fish, it was determined the strontium and calcium content in the edible fraction of nine species and in sea water by atomic absorption spectrophotometry. (author)

  12. Determination of the nuclear scattering amplitude of uranium-235 isotope by neutron diffraction method

    International Nuclear Information System (INIS)

    Bayvas, F.

    1980-05-01

    The nuclear scattering amplitude of uranium-235 isotope has been determined by the neutron diffraction method. Although the scattering cross section for slow neutrons of uranium-235 is very small (16.33 barns), the coherent scattering can be observed. The scattering amplitude of this isotope has been calculated from the measured diffraction intensities of the enriched metallic uranium as b=(1.05+-0.05)x10 -12 cm. It may possibly give some more idea about the neutron-nucleus interactions of uranium-235 and some other elements which show the same scattering length for slow neutrons. (author)

  13. Determination of hydrogen and sodium profiles at the glass surfaces by nuclear methods

    International Nuclear Information System (INIS)

    Engelmann, C.; Nens, B.; Trocellier, P.

    1981-01-01

    A description of the methods used is given. They are based on direct observation of nuclear reactions produced by nitrogen-15 ions of 6.38 to 10 MeV energy and protons of 1 to 1.1 MeV energy. The performances of these techniques which are particularly interesting to explore the first few microns of the glass surface, non destructively, are presented. It is shown that the migration of hydrogen and sodium, during the determination is negligible when appropriate experimental conditions are used. Examples of application to glasses submitted to lixiviation are given [fr

  14. Gadolinium and fission neodymium isotopic analyses and determinations in irradiated nuclear fuels

    International Nuclear Information System (INIS)

    Lucas, M.; Chevalier, C.

    1975-01-01

    A separation method of rare earths on an ion exchange resin is described: it enables the gadolinium and fission neodymium contained in irradiated nuclear fuels to be separated and analyzed by isotopic dilution and mass spectrometry. The principle of the chemical separation and its efficiency and reproducibility are reported. This technique was applied to a series of spent fuels from a pressurized water reactor, with an initial gadolinium content of 2% and final fission neodymium 148 concentrations of a few hundred ppm. These results confirm the validity of the separation method studied, which can be easily adapted to the determination of other rare earths in spent fuels [fr

  15. Radiometric determination of density of fresh shielding concrete (in situ) in the nuclear industry

    International Nuclear Information System (INIS)

    Honig, A.

    1985-01-01

    Methods of radiometric determination of density have been in recent years elaborated in detail and successfully. But on the market no instruments are available for measuring fresh concrete when it is possible to repair inhomogeneities, if any, even before hardening, and thus to guarantee safety of biological protection of nuclear reactors. The paper describes an analog and digital radiation density meter and their application in the inspection of radiation protection concrete walls. By repairing defective, insufficiently dense locations still in the course of concrete placement it is possible to attain a laboratory quality of the concrete even under on-site conditions

  16. Determination of chlorine in nuclear-grade uranium compounds by ion-selective electrode

    International Nuclear Information System (INIS)

    Yang Chunqing; Liu Fuyun; Huang Dianfan.

    1989-01-01

    The determination of microamount chlorine in nuclear-grade uranium compounds is described. Chlorine is separated from uranium oxide pyrohydrolytically with stream of wet oxygen in a furnace at 800-900 deg C. Chlorine is volatilized as hydrochloric acid, which then is absorbed in a dilute alkaline solution and measured with chlorine selective electrode. This method covers the concentration range of 10-500 ppm chlorine in uranium oxide. The relative standard diviation is better than 10% and recovery of 85-108% has been reported

  17. Nuclear structure

    International Nuclear Information System (INIS)

    Diamond, R.M.; Stephens, F.S.; Deleplanque, M.A.; Draper, J.E.; Dines, E.L.; Davis, U.C.; Macchiavelli, A.O.

    1984-01-01

    Essentially the whole range of spins possible for many nuclei in the periodic table is available with the use of the 88-Inch cyclotron and SuperHILAC accelerators. Nuclei carry angular momentum principally in two ways: by aligning individual high j nucleons, and by a collective rotation of the nucleus as a whole. Deformed nuclei use both modes and it is the interplay between the single-particle and collective modes that leads to the great diversity of nuclear properties at high spin. Information about these states and their properties is obtained only by detailed γ-ray spectroscopy of their de-exciting transitions. But for the higher spins the population is usually spread over so many states that only average values of continuum properties can be determined. So one of the goals of present-day research is to push discrete spectroscopic studies to higher spin states, reducing the continuum region. To do this requires that the number of cascade pathways observed be reduced to a small enough number so that individual transitions can show. One way is to use a combination of sum-energy and multiplicity selection, that is, to define a smaller entry region. This is what the NaI crystal balls can do. Another technique is to set gates on the highest-lying discrete transitions observed and look at what is in coincidence (ahead) of them. Either method requires a drastic decrease in the number of cascades selected, so very good statistics are needed and this means many detectors as close as possible to the target. The authors use both techniques simultaneously. Current and planned experiments are described

  18. Determinação da quantidade de DNA nuclear em plantas Nuclear DNA content determination in plants

    Directory of Open Access Journals (Sweden)

    Maria Teresa Schifino-Wittmann

    2001-10-01

    Full Text Available O valor C de DNA é um caráter de significado biológico fundamental e o conhecimento da quantidade de DNA nuclear de um grupo de organismos pode ser útil em vários campos da ciência. Do ponto de vista prático, a determinação da quantidade de DNA nuclear, que é mais comumente realizada por microdensitometria de Feulgen e citometria de fluxo, pode substituir a contagem de cromossomos, especialmente quando se trabalha com um número muito grande de indivíduos. A microdensitometria por Feulgen baseia-se na ligação específica do DNA a esse corante, havendo uma proporcionalidade entre a quantidade de DNA existente e a quantidade de corante que o núcleo incorporou. A citometria de fluxo envolve a análise das propriedades óticas de partículas em fluxo. Em plantas, basicamente consiste no isolamento dos núcleos, coloração destes com um fluorocromo e leitura da fluorescência emitida. As grandes vantagens desta técnica, em relação à microdensitometria de Feulgen, são a relativa facilidade e a rapidez da preparação das amostras, o grande número de núcleos que podem ser analisados, a necessidade de pequenas quantidades de tecido e a possibilidade de detecção de pequenas diferenças na quantidade de DNA. Relatos de resultados conflitantes entre determinações de diferentes autores mostram a necessidade de uma criteriosa padronização das técnicas, para que problemas metodológicos não venham a ser interpretados como eventuais diferenças reais na quantidade de DNA.The DNA C value is an important biological characteristic and the knowledge of DNA content may be applied to several branches of science. Nuclear DNA content determinations, normally performed by Feulgen microdensitometry and flow cytometry, may replace chromosome counts especially when a high number of individuals are being analysed. Feulgen microdensitometry is based on the affinity of this dye and the DNA: the amount of DNA is proportional to the amount of dye

  19. Climate change benefits and energy supply benefits as determinants of acceptance of nuclear power stations: Investigating an explanatory model

    International Nuclear Information System (INIS)

    Visschers, Vivianne H.M.; Keller, Carmen; Siegrist, Michael

    2011-01-01

    Several countries are currently discussing whether they will rebuild their nuclear power stations in order to continue this type of energy production in the future. The public, with its own opinion about nuclear power stations, has an influential voice in this discussion. As a result, policy makers and nuclear scientists are interested in the public's perception of nuclear power and in what determines this perception. We therefore examined an explanatory model of the public's acceptance of nuclear power based on a telephone survey among a representative sample in Switzerland. The model included such factors as risk perception, benefit perception, affective feelings, and social trust. Moreover, we distinguished between two types of benefit perception: benefit for the climate and a secure energy supply. The model fitted very well to our data and explained acceptance very well. Acceptance was mainly influenced by perceived benefits for a secure energy supply and, to a lesser extent, both by perceived benefits for the climate and by risk perception. Affective feelings about nuclear power appeared to be a central factor in the model. Implications for communication about nuclear power stations and for further research are discussed. - Highlights: → Explanatory model of determinants of nuclear power acceptance was studied in the representative survey. → Perceived benefits for a secure energy supply had the largest influence on acceptance. → Perceived benefits for the climate seemed less influential on acceptance. → Affect had a central role in the explanatory model. → Implications for communication about nuclear power plants are discussed.

  20. MDMA ‘ecstasy’ increases cerebral cortical perfusion determined by bolus-tracking arterial spin labelling (btASL) MRI

    Science.gov (United States)

    Rouine, J; Gobbo, O L; Campbell, M; Gigliucci, V; Ogden, I; McHugh Smith, K; Duffy, P; Behan, B; Byrne, D; Kelly, M E; Blau, C W; Kerskens, C M; Harkin, A

    2013-01-01

    Background and Purpose The purpose of this study was to assess cerebral perfusion changes following systemic administration of the recreational drug 3,4-methylendioxymethamphetamine (MDMA ‘ecstasy’) to rats. Experimental Approach Cerebral perfusion was quantified using bolus-tracking arterial spin labelling (btASL) MRI. Rats received MDMA (20 mg·kg−1; i.p.) and were assessed 1, 3 or 24 h later. Rats received MDMA (5 or 20 mg·kg−1; i.p.) and were assessed 3 h later. In addition, rats received MDMA (5 or 10 mg·kg−1; i.p.) or saline four times daily over 2 consecutive days and were assessed 8 weeks later. Perfusion-weighted images were generated in a 7 tesla (7T) MRI scanner and experimental data was fitted to a quantitative model of cerebral perfusion to generate mean transit time (MTT), capillary transit time (CTT) and signal amplitude. Key Results MDMA reduces MTT and CTT and increases amplitude in somatosensory and motor cortex 1 and 3 h following administration, indicative of an increase in perfusion. Prior exposure to MDMA provoked a long-term reduction in cortical 5-HT concentration, but did not produce a sustained effect on cerebral cortical perfusion. The response to acute MDMA challenge (20 mg·kg−1; i.p.) was attenuated in these animals indicating adaptation in response to prior MDMA exposure. Conclusions and Implications MDMA provokes changes in cortical perfusion, which are quantifiable by btASL MRI, a neuroimaging tool with translational potential. Future studies are directed towards elucidation of the mechanisms involved and correlating changes in cerebrovascular function with potential behavioural deficits associated with drug use. PMID:23517012

  1. Determination of correlation times from selective and non-selective spin-lattice relaxation rates and their use in drug-drug and drug-albumin interaction studies

    Directory of Open Access Journals (Sweden)

    Tinoco Luzineide Wanderley

    1999-01-01

    Full Text Available The effects of the changes in sample concentration on the NMR chemical shifts and on the selective and non-selective spin-lattice relaxation rates (R1S and R1NS of the three isomers of nitrobenzaldeyde guanyl hydrazone (NBGH pure and with bovine serum albumin (BSA were measured in solution. The results wereused to determine the correlation times (tauc, showing that the degree of intermolecular drug-drug association varies with the nitro group position on the ring and that this degree of association interferes with the interaction of these drugs with BSA. The results suggest that the degree of drug-drug and drug-BSA association are related to the in vitro anti-Trypanosoma cruzi activity of these compounds.

  2. A study on determinants of risk perception and attitude structures concerning nuclear power technology

    International Nuclear Information System (INIS)

    Tsuchida, Shoji; Kitada, Atsuko; Ato, Kazunori

    2000-01-01

    attitude structures, in order to manage the risks of mega-technologies, especially the risk of nuclear technology. Social surveys on people's attitudes toward nuclear power plants carried out in Japan showed that cognition of necessity and safety of them and fear of them had strong effects on the attitudes, and that the female had more negative attitudes than the male, and that people on administrative positions by occupation had most affirmative attitudes. However, there are few social survey researches that focus on the people's tendencies to zero-risk perception or comparative-risk perception to clarify the nature and determinants of attitude structures toward nuclear power technology. In this presentation we try to point out the factors which should be considered to manage the risks of mega-technologies in the social decision making processes by describing the survey data of zero-risk perception, comparative-risk perception, and over-sensibility to hazards relating to the attitude structures toward nuclear power technology. (author)

  3. Automatic ultrasonic inspection system for wear determination in calandria tubes of Embalse Nuclear Power Plant

    Energy Technology Data Exchange (ETDEWEB)

    Katchadjian, Pablo, E-mail: katcha@cnea.gov.ar; Desimone, Carlos, E-mail: katcha@cnea.gov.ar; Garcia, Alejandro, E-mail: katcha@cnea.gov.ar [Comisión Nacional de Energía Atómica, Depto. ENDE - INEND, Av. Gral. Paz 1499, Buenos Aires (Argentina); Antonaccio, Carlos; Schroeter, Fernando; Molina, Héctor [Nucleoeléctrica Argentina-SA, Arribeños 3619, Buenos Aires (Argentina)

    2015-03-31

    Embalse Nuclear Power Plant (CNE) (CANDU design) is reaching its end of life and due to elapsed operating time the problem of deformation by accelerated creep occurs in the pressure tubes (PT), leading to a possible contact between calandria tubes (CT), concentric to the PT, and some Liquid Injection Shutdown System (LISS) nozzles that pass underneath them. With determination of CT wear, after the predicted contact occurs, the wear rate of the TC could be determined and thus take less conservative measures over the remaining life of the component. This paper presents the development of an ultrasonic technique for measuring wear in CT, with nominal thickness of 1.34 mm. Because the only access is through the interior of PT, to perform this measurement it is necessary to pass through three different interfaces.

  4. Automatic ultrasonic inspection system for wear determination in calandria tubes of Embalse Nuclear Power Plant

    Science.gov (United States)

    Katchadjian, Pablo; Desimone, Carlos; Garcia, Alejandro; Antonaccio, Carlos; Schroeter, Fernando; Molina, Héctor

    2015-03-01

    Embalse Nuclear Power Plant (CNE) (CANDU design) is reaching its end of life and due to elapsed operating time the problem of deformation by accelerated creep occurs in the pressure tubes (PT), leading to a possible contact between calandria tubes (CT), concentric to the PT, and some Liquid Injection Shutdown System (LISS) nozzles that pass underneath them. With determination of CT wear, after the predicted contact occurs, the wear rate of the TC could be determined and thus take less conservative measures over the remaining life of the component. This paper presents the development of an ultrasonic technique for measuring wear in CT, with nominal thickness of 1.34 mm. Because the only access is through the interior of PT, to perform this measurement it is necessary to pass through three different interfaces.

  5. Bioactive conformation of stromelysin inhibitors determined by transferred nuclear Overhauser effects.

    Science.gov (United States)

    Gonnella, N C; Bohacek, R; Zhang, X; Kolossváry, I; Paris, C G; Melton, R; Winter, C; Hu, S I; Ganu, V

    1995-01-01

    The transferred nuclear Overhauser effect has been used to determine the biologically active conformations of two stromelysin inhibitors. Both inhibitors used in this study were hydroxamic acids generated via chemical synthesis. These structures, representing the conformation of each inhibitor bound to stromelysin, superimposed with excellent agreement. The study also provided information on the shape and orientation of the S2' and S1' pockets of the enzyme relative to thermolysin. Comparisons were made between stromelysin and thermolysin inhibitors to critically examine thermolysin as a template for stromelysin-inhibitor design. The enzyme-bound conformations of these stromelysin inhibitors were determined for use as a template in conformationally restricted drug design. Images Fig. 4 Fig. 5 Fig. 6 Fig. 7 PMID:7831311

  6. Plutonium determination by spectrophotometry of plutonium (VI): control of the nuclear fuel reprocessing plant

    International Nuclear Information System (INIS)

    Grison, J.

    1980-01-01

    The plutonium (VI) spectrophotometric determination, after AgO oxidation in 3 M nitric acid medium, is used for the running-control of the nuclear fuel reprocessing plant at La Hague. Analytical device used in glove-box or shielded-cell is briefly described. This method is fast, sensitive, unfailing and gives simple effluents. It is applied by day and night shifts, during Light Water Reactor fuel reprocessing campaign, for 0.5 mg/l up to 20 g/l plutonium solutions. Reference solution measurements have a 0.8 to 1.4 % relative standard deviation; duplicate plutonium determinations give a 0.3% relative standard deviation for sample analysis. There is a discrepancy (- 0.3% to - 0.9%) between the spectrophotometric method results and the isotopic dilution analysis [fr

  7. Spin properties of dense near-surface ensembles of nitrogen-vacancy centers in diamond

    Science.gov (United States)

    Tetienne, J.-P.; de Gille, R. W.; Broadway, D. A.; Teraji, T.; Lillie, S. E.; McCoey, J. M.; Dontschuk, N.; Hall, L. T.; Stacey, A.; Simpson, D. A.; Hollenberg, L. C. L.

    2018-02-01

    We present a study of the spin properties of dense layers of near-surface nitrogen-vacancy (NV) centers in diamond created by nitrogen ion implantation. The optically detected magnetic resonance contrast and linewidth, spin coherence time, and spin relaxation time, are measured as a function of implantation energy, dose, annealing temperature, and surface treatment. To track the presence of damage and surface-related spin defects, we perform in situ electron spin resonance spectroscopy through both double electron-electron resonance and cross-relaxation spectroscopy on the NV centers. We find that, for the energy (4 -30 keV) and dose (5 ×1011-1013ions/cm 2 ) ranges considered, the NV spin properties are mainly governed by the dose via residual implantation-induced paramagnetic defects, but that the resulting magnetic sensitivity is essentially independent of both dose and energy. We then show that the magnetic sensitivity is significantly improved by high-temperature annealing at ≥1100 ∘C . Moreover, the spin properties are not significantly affected by oxygen annealing, apart from the spin relaxation time, which is dramatically decreased. Finally, the average NV depth is determined by nuclear magnetic resonance measurements, giving ≈10 -17 nm at 4-6 keV implantation energy. This study sheds light on the optimal conditions to create dense layers of near-surface NV centers for high-sensitivity sensing and imaging applications.

  8. Measuring the spins of accreting black holes

    International Nuclear Information System (INIS)

    McClintock, Jeffrey E; Narayan, Ramesh; Gou, Lijun; Kulkarni, Akshay; Penna, Robert F; Steiner, James F; Davis, Shane W; Orosz, Jerome A; Remillard, Ronald A

    2011-01-01

    A typical galaxy is thought to contain tens of millions of stellar-mass black holes, the collapsed remnants of once massive stars, and a single nuclear supermassive black hole. Both classes of black holes accrete gas from their environments. The accreting gas forms a flattened orbiting structure known as an accretion disk. During the past several years, it has become possible to obtain measurements of the spins of the two classes of black holes by modeling the x-ray emission from their accretion disks. Two methods are employed, both of which depend upon identifying the inner radius of the accretion disk with the innermost stable circular orbit, whose radius depends only on the mass and spin of the black hole. In the Fe Kα method, which applies to both classes of black holes, one models the profile of the relativistically broadened iron line with a special focus on the gravitationally redshifted red wing of the line. In the continuum-fitting (CF) method, which has so far only been applied to stellar-mass black holes, one models the thermal x-ray continuum spectrum of the accretion disk. We discuss both methods, with a strong emphasis on the CF method and its application to stellar-mass black holes. Spin results for eight stellar-mass black holes are summarized. These data are used to argue that the high spins of at least some of these black holes are natal, and that the presence or absence of relativistic jets in accreting black holes is not entirely determined by the spin of the black hole.

  9. Vibration dependence of the tensor spin-spin and scalar spin-spin hyperfine interactions by precision measurement of hyperfine structures of 127I2 near 532 nm

    International Nuclear Information System (INIS)

    Hong Fenglei; Zhang Yun; Ishikawa, Jun; Onae, Atsushi; Matsumoto, Hirokazu

    2002-01-01

    Hyperfine structures of the R(87)33-0, R(145)37-0, and P(132)36-0 transitions of molecular iodine near 532 nm are measured by observing the heterodyne beat-note signal of two I 2 -stabilized lasers, whose frequencies are bridged by an optical frequency comb generator. The measured hyperfine splittings are fit to a four-term Hamiltonian, which includes the electric quadrupole, spin-rotation, tensor spin-spin, and scalar spin-spin interactions, with an accuracy of ∼720 Hz. High-accurate hyperfine constants are obtained from this fit. Vibration dependences of the tensor spin-spin and scalar spin-spin hyperfine constants are determined for molecular iodine, for the first time to our knowledge. The observed hyperfine transitions are good optical frequency references in the 532-nm region

  10. QCD SPIN PHYSICS IN HADRONIC INTERACTIONS.

    Energy Technology Data Exchange (ETDEWEB)

    VOGELSANG,W.

    2007-06-19

    We discuss spin phenomena in high-energy hadronic scattering, with a particular emphasis on the spin physics program now underway at the first polarized proton-proton collider, RHIC. Experiments at RHIC unravel the spin structure of the nucleon in new ways. Prime goals are to determine the contribution of gluon spins to the proton spin, to elucidate the flavor structure of quark and antiquark polarizations in the nucleon, and to help clarify the origin of transverse-spin phenomena in QCD. These lectures describe some aspects of this program and of the associated physics.

  11. Determination of Kr-85 in environmental samples and gaseous effluents from nuclear industries using the standard method

    International Nuclear Information System (INIS)

    Heras Iniquez, M.C.; Perez Garcia, M.M.

    1983-01-01

    The determination of the Kr-85 activity in environmental samples and gaseous effluents from Spanish Nuclear Power Stations is described. The method employed has been published elsewhere. The determinations has been carried out in environmental samples token at JEN Laboratories (Madrid) and the Nuclear Power Stations, Jose Cabrera (Zorita), Garona and Vandellos. Also samples of gaseous effluents of the three plants has been analyzed. Values of the Kr-85 environmental background activity in the Almaraz Nuclear Power Stations, has been determined, before the beginning of its nuclear activity. In this paper the sampling equipment used is described and the values found of Kr-85 activity in all the samples in given. (Author) 29 refs

  12. T violating neutron spin rotation asymmetry

    International Nuclear Information System (INIS)

    Masuda, Yasushiro.

    1993-01-01

    A new experiment on T-violation is proposed, where a spin-rotating-neutron transmission through a polarized nuclear target is measuered. The method to control the neutron spin is discussed for the new T-violation experiment. The present method has possibility to provide us more accurate T-violation information than the neutron EDM measurement

  13. Spin dynamics in high-Tc cuprates

    International Nuclear Information System (INIS)

    Fukuyama, H.; Kohno, H.; Normand, B.; Tanamoto, T.

    1995-01-01

    Characteristic features of the spin excitations in high-T c cuprates revealed by neutron scattering and nuclear magnetic resonance experiments are summarised, and analysed on the basis of the slave-boson mean-field theory for the extended t-J model, placing special emphasis on the spin-gap phenomenon. (orig.)

  14. Determination of the Schottky barrier height of ferromagnetic contacts to few-layer phosphorene

    Energy Technology Data Exchange (ETDEWEB)

    Anugrah, Yoska; Robbins, Matthew C.; Koester, Steven J. [Department of Electrical and Computer Engineering, University of Minnesota-Twin Cities, Minneapolis, Minnesota 55455 (United States); Crowell, Paul A. [School of Physics and Astronomy, University of Minnesota-Twin Cities, Minneapolis, Minnesota 55455 (United States)

    2015-03-09

    Phosphorene, the 2D analogue of black phosphorus, is a promising material for studying spin transport due to its low spin-orbit coupling and its ½ nuclear spin, which could allow the study of hyperfine effects. In this work, the properties of permalloy (Py) and cobalt (Co) contacts to few-layer phosphorene are presented. The Schottky barrier height was extracted and determined as a function of gate bias. Flat-band barrier heights, relative to the valence band edge, of 110 meV and 200 meV were determined for Py and Co, respectively. These results are important for future studies of spin transport in phosphorene.

  15. Methodology for determining acceptable residual radioactive contamination levels at decommissioned nuclear facilities/sites

    International Nuclear Information System (INIS)

    Watson, E.C.; Kennedy, W.E. Jr.; Hoenes, G.R.; Waite, D.A.

    1979-01-01

    The ultimate disposition of decommissioned nuclear facilities and their surrrounding sites depends upon the degree and type of residual contamination. Examination of existing guidelines and regulations has led to the conclusion that there is a need for a general method to derive residual radioactive contamination levels that are acceptable for public use of any decommissioned nuclear facility or site. This paper describes a methodology for determining acceptable residual radioactive contamination levels based on the concept of limiting the annual dose to members of the public. It is not the purpose of this paper to recommend or even propose dose limits for the exposure of the public to residual radioactive contamination left at decommissioned nuclear facilities or sites. Unrestricted release of facilities and/or land is based on the premise that the potential annual dose to any member of the public using this property from all possible exposure pathways will not exceed appropriate limits as may be defined by Federal regulatory agencies. For decommissioned land areas, consideration should be given to people living directly on previously contaminated areas, growing crops, grazing food animals and using well water. Mixtures of radionuclides in the residual contamination representative of fuel reprocessing plants, light water reactors and their respective sites are presented. These mixtures are then used to demonstrate the methodology. Example acceptable residual radioactive contamination levels, based on an assumed maximum annual dose of one millirem, are calculated for several selected times following shutdown of a facility. It is concluded that the methodology presented in this paper results in defensible acceptable residual contamination levels that are directly relatable to risk assessment with the proviso that an acceptable limit to the maximum annual dose will be established. (author)

  16. Fast electrical switching of spin injection in nonlocal spin transport devices

    Science.gov (United States)

    Fuhrer, A.; Alvarado, S. F.; Salis, G.; Allenspach, R.

    2011-05-01

    We present spin-injection experiments in a nonlocal spin transport device where spin is injected from a ferromagnetic FeCo electrode into a GaAs epilayer. The magnetization of the injection contact is switched by Oersted fields generated by alternating current pulses. This enables fast and offset-free measurements of nonlocal spin signals. Due to a negligible time-averaged electron spin polarization, dynamic nuclear polarization effects are small and Hanle curves measured down to T =3 K can be fit very accurately by drift-diffusion theory if a small constant Overhauser field BN=0.4 mT is accounted for.

  17. Determination of scutellarin in breviscapine preparations using quantitative proton nuclear magnetic resonance spectroscopy

    Directory of Open Access Journals (Sweden)

    Zhenzuo Jiang

    2016-04-01

    Full Text Available The objective of the present study was to develop the selection criteria of proton signals for the determination of scutellarin using quantitative nuclear magnetic resonance (qNMR, which is the main bioactive compound in breviscapine preparations for the treatment of cerebrovascular disease. The methyl singlet signal of 3-(trimethylsilylpropionic-2,2,3,3-d4 acid sodium salt was selected as the internal standard for quantification. The molar concentration of scutellarin was determined by employing different proton signals. To obtain optimum proton signals for the quantification, different combinations of proton signals were investigated according to two selection criteria: the recovery rate of qNMR method and quantitative results compared with those obtained with ultra-performance liquid chromatography. As a result, the chemical shift of H-2′ and H-6′ at δ 7.88 was demonstrated as the most suitable signal with excellent linearity range, precision, and recovery for determining scutellarin in breviscapine preparations from different manufacturers, batch numbers, and dosage forms. Hierarchical cluster analysis was employed to evaluate the determination results. The results demonstrated that the selection criteria of proton signals established in this work were reliable for the qNMR study of scutellarin in breviscapine preparations.

  18. U.S. nuclear non-proliferation policy: impact on exports and nuclear industry could not be determined. Report to the Congress

    International Nuclear Information System (INIS)

    1980-01-01

    The Nuclear Non-Proliferation Act of 1978 established new measures to prevent the diversion to weapons use of peaceful nuclear exports. It also created a policy to confirm U.S. reliability as a nuclear supplier. GAO did not identify any export sales lost as a result of the Act, but did find indications that nonproliferation policies can influence export sales. Based on available data, GAO could not determine the impact of the Act on the competitiveness of U.S. nuclear exports. However, U.S. companies are at some disadvantage because importers perceive that implementation of the Act may result in delayed export licenses. The United States dominated the nuclear export market through the early 1970s. However, foreign competitors, some aided by U.S. technology transfers, emerged to monopolize home markets and compete for third-country business. Further, the market has been depressed since 1974 and prospects for U.S. nuclear power plant exports have dimmed greatly. However, U.S. companies continue to view exports as important to sustain production capacity

  19. Adiabatic quantum computing with spin qubits hosted by molecules.

    Science.gov (United States)

    Yamamoto, Satoru; Nakazawa, Shigeaki; Sugisaki, Kenji; Sato, Kazunobu; Toyota, Kazuo; Shiomi, Daisuke; Takui, Takeji

    2015-01-28

    A molecular spin quantum computer (MSQC) requires electron spin qubits, which pulse-based electron spin/magnetic resonance (ESR/MR) techniques can afford to manipulate for implementing quantum gate operations in open shell molecular entities. Importantly, nuclear spins, which are topologically connected, particularly in organic molecular spin systems, are client qubits, while electron spins play a role of bus qubits. Here, we introduce the implementation for an adiabatic quantum algorithm, suggesting the possible utilization of molecular spins with optimized spin structures for MSQCs. We exemplify the utilization of an adiabatic factorization problem of 21, compared with the corresponding nuclear magnetic resonance (NMR) case. Two molecular spins are selected: one is a molecular spin composed of three exchange-coupled electrons as electron-only qubits and the other an electron-bus qubit with two client nuclear spin qubits. Their electronic spin structures are well characterized in terms of the quantum mechanical behaviour in the spin Hamiltonian. The implementation of adiabatic quantum computing/computation (AQC) has, for the first time, been achieved by establishing ESR/MR pulse sequences for effective spin Hamiltonians in a fully controlled manner of spin manipulation. The conquered pulse sequences have been compared with the NMR experiments and shown much faster CPU times corresponding to the interaction strength between the spins. Significant differences are shown in rotational operations and pulse intervals for ESR/MR operations. As a result, we suggest the advantages and possible utilization of the time-evolution based AQC approach for molecular spin quantum computers and molecular spin quantum simulators underlain by sophisticated ESR/MR pulsed spin technology.

  20. Determination of velocity and flow direction of ground water by using nuclear techniques

    International Nuclear Information System (INIS)

    Santos Ferreira, L. dos.

    1976-06-01

    The dynamics of water in an aquifer with the purpose of determining the filtration velocity and the direction of groundwater flow with radioactive tracers was studied. Field equipment for the purposes of the study was built in the Laboratory of Tracers in Hydrology in collaboration with the Institute of Nuclear Engineering (IEN/NUCLEBRAS). The equipment was designed to minimize the possible vertical flows, loss and molecular diffusion of the tracer out of the studied region. The performance of the nuclear detectors and the constructional details of the field equipament were examined. The selection of the radioactive tracers was made taking into account its availibility and radiation facilities, cost of the inactive material and their physical and chemical properties. The tracers used were 82 Br and 198 Au. The results are discussed with the help of auxiliary informations such as plots of water levels in time and space, profiles and grain analysis. In order to obtain a physical explanation of the results, a qualitative model of the flow in the aquifer is also presented. (Author) [pt

  1. A nuclear DNA-based species determination and DNA quantification assay for common poultry species.

    Science.gov (United States)

    Ng, J; Satkoski, J; Premasuthan, A; Kanthaswamy, S

    2014-12-01

    DNA testing for food authentication and quality control requires sensitive species-specific quantification of nuclear DNA from complex and unknown biological sources. We have developed a multiplex assay based on TaqMan® real-time quantitative PCR (qPCR) for species-specific detection and quantification of chicken (Gallus gallus), duck (Anas platyrhynchos), and turkey (Meleagris gallopavo) nuclear DNA. The multiplex assay is able to accurately detect very low quantities of species-specific DNA from single or multispecies sample mixtures; its minimum effective quantification range is 5 to 50 pg of starting DNA material. In addition to its use in food fraudulence cases, we have validated the assay using simulated forensic sample conditions to demonstrate its utility in forensic investigations. Despite treatment with potent inhibitors such as hematin and humic acid, and degradation of template DNA by DNase, the assay was still able to robustly detect and quantify DNA from each of the three poultry species in mixed samples. The efficient species determination and accurate DNA quantification will help reduce fraudulent food labeling and facilitate downstream DNA analysis for genetic identification and traceability.

  2. Nuclear order in silver at pico-Kelvin temperature

    DEFF Research Database (Denmark)

    Siemensmeyer, K.; Clausen, K.N.; Lefmann, K.

    1997-01-01

    Nuclear order in silver is observed by neutron diffraction at pico-Kelvin temperatures. The structure is a type-I antiferromagnet with critical field of 100 mu T. The entropy-field phase diagram was determined using the spin-dependent absorption.......Nuclear order in silver is observed by neutron diffraction at pico-Kelvin temperatures. The structure is a type-I antiferromagnet with critical field of 100 mu T. The entropy-field phase diagram was determined using the spin-dependent absorption....

  3. Nuclear order in silver at pico-Kelvin temperature

    DEFF Research Database (Denmark)

    Siemensmeyer, K.; Clausen, K.N.; Lefmann, K.

    1997-01-01

    Nuclear order in silver is observed by neutron diffraction at pico-Kelvin temperatures. The structure is a type-I antiferromagnet with critical field of 100 μT. The entropy-field phase diagram was determined using the spin-dependent absorption.......Nuclear order in silver is observed by neutron diffraction at pico-Kelvin temperatures. The structure is a type-I antiferromagnet with critical field of 100 μT. The entropy-field phase diagram was determined using the spin-dependent absorption....

  4. Overview of spin physics

    Energy Technology Data Exchange (ETDEWEB)

    Yokosawa, A.

    1992-12-23

    Spin physics activities at medium and high energies became significantly active when polarized targets and polarized beams became accessible for hadron-hadron scattering experiments. My overview of spin physics will be inclined to the study of strong interaction using facilities at Argonne ZGS, Brookhaven AGS (including RHIC), CERN, Fermilab, LAMPF, an SATURNE. In 1960 accelerator physicists had already been convinced that the ZGS could be unique in accelerating a polarized beam; polarized beams were being accelerated through linear accelerators elsewhere at that time. However, there was much concern about going ahead with the construction of a polarized beam because (i) the source intensity was not high enough to accelerate in the accelerator, (ii) the use of the accelerator would be limited to only polarized-beam physics, that is, proton-proton interaction, and (iii) p-p elastic scattering was not the most popular topic in high-energy physics. In fact, within spin physics, [pi]-nucleon physics looked attractive, since the determination of spin and parity of possible [pi]p resonances attracted much attention. To proceed we needed more data beside total cross sections and elastic differential cross sections; measurements of polarization and other parameters were urgently needed. Polarization measurements had traditionally been performed by analyzing the spin of recoil protons. The drawbacks of this technique are: (i) it involves double scattering, resulting in poor accuracy of the data, and (ii) a carbon analyzer can only be used for a limited region of energy.

  5. Spin Waves in Terbium

    DEFF Research Database (Denmark)

    Jensen, J.; Houmann, Jens Christian Gylden

    1975-01-01

    The selection rules for the linear couplings between magnons and phonons propagating in the c direction of a simple basal-plane hcp ferromagnet are determined by general symmetry considerations. The acoustic-optical magnon-phonon interactions observed in the heavy-rare-earth metals have been...... explained by Liu as originating from the mixing of the spin states of the conduction electrons due to the spin-orbit coupling. We find that this coupling mechanism introduces interactions which violate the selection rules for a simple ferromagnet. The interactions between the magnons and phonons propagating...... in the c direction of Tb have been studied experimentally by means of inelastic neutron scattering. The magnons are coupled to both the acoustic- and optical-transverse phonons. By studying the behavior of the acoustic-optical coupling, we conclude that it is a spin-mixed-induced coupling as proposed...

  6. Internal exposure in nuclear medicine: application of IAEA criteria to determine the need for internal monitoring

    Directory of Open Access Journals (Sweden)

    Bernardo Maranhão Dantas

    2008-12-01

    Full Text Available The manipulation of unsealed sources in nuclear medicine poses significant risks of internal exposure to the staff. According to the International Atomic Energy Agency, the radiological protection program should include an evaluation of such risks and an individual monitoring plan, assuring acceptable radiological safety conditions in the workplace. The IAEA Safety Guide RS-G-1.2 recommends that occupational monitoring should be implemented whenever it is likely that committed effective doses from annual intakes of radionuclides would exceed 1 mSv. It also suggests a mathematical criterion to determine the need to implement internal monitoring. This paper presents a simulation of the IAEA criteria applied to commonly used radionuclides in nuclear medicine, taking into consideration usual manipulated activities and handling conditions. It is concluded that the manipulation of 131I for therapy presents the higher risk of internal exposure to the workers, requiring the implementation of an internal monitoring program by the Nuclear Medicine Centers.A manipulação de fontes abertas em Serviços de Medicina Nuclear envolve riscos de exposição externa e contaminação interna. O plano de proteção radiológica das Instalações licenciadas pela CNEN deve incluir a avaliação de tais riscos e propor um programa de monitoração individual de forma a controlar as exposições e garantir a manutenção das condições de segurança radiológica. As recomendações da AIEA apresentadas no Safety Guide RS-G-1.2 sugerem que seja implementado um programa de monitoração interna do trabalhador sempre que houver possibilidade da contaminação interna conduzir a valores de dose efetiva comprometida anual igual ou superior a 1 mSv. Este trabalho apresenta a simulação da aplicação de tais critérios para os radionuclídeos mais utilizados na área de Medicina Nuclear, levando-se em consideração as condições usuais de manipulação das fontes e as

  7. Determination of chemical forms of 14C in liquid discharges from nuclear power plants.

    Science.gov (United States)

    Svetlik, I; Fejgl, M; Povinec, P P; Kořínková, T; Tomášková, L; Pospíchal, J; Kurfiřt, M; Striegler, R; Kaufmanová, M

    2017-10-01

    Developments of radioanalytical methods for determination of radiocarbon in wastewaters from nuclear power plants (NPP) with pressurized light water reactors, which would distinguish between the dissolved organic and inorganic forms have been carried out. After preliminary tests, the method was used to process pilot samples from wastewater outlets from the Temelín and Dukovany NPPs (Czech Republic). The results of analysis of pilot water samples collected in 2015 indicate that the instantaneous 14 C releases into the water streams would be about 7.10 -5 (Temelín) and 4.10 -6 (Dukovany) of the total quantity of the 14 C liberated into the environment. Copyright © 2017 Elsevier Ltd. All rights reserved.

  8. Determination of nuclear fuel burnup by non-destructive gamma spectroscopy

    International Nuclear Information System (INIS)

    Soares, A.J.

    1979-01-01

    The determination of nuclear fuel burnup by the non-destructive gamma spectroscopy method is studied. A MTR (Materials Testing Reactor) -type fuel element is used in the measurement. The fuel element was removed from the reactor core in 1958 and, because of the long decay time, show only one peak in is gamma spectrum at 661.6 Kev. Corresponding to 137 Cs. Measurements are made at 330 points of the element using a Nal detector and the final result revealed that the quantity of 235 U consumed was 3.3 +- 0,8 milligram in the entire element. The effect of the migration of 137 Cs in the element is neglected in view of the fact that it occurs only when the temperature is above 1000 0 C, which is not the case in IEAR-1. (Author)

  9. Determination of trace metals in nuclear-grade uranium dioxide by X-ray fluorescence spectrometry

    International Nuclear Information System (INIS)

    Salvador, V.L.R.; Imakuma, K.

    1988-04-01

    A method is described for the simultaneous determination of low concentrations of Ca, Cr, Cu, Fe, Mn and Ni in nuclear-grade uranium dioxide by X-ray fluorescence spectrometry, without the use of chemical treatment. The lower limits of detection range from 2 μg g -1 for nickel and manganese to 5 μg g -1 for copper. Samples are prepared in the form of double-layer pellets with boric acid as a binding agent. Standards are prepared in a U 3 O 8 matrix, which is more chemically stable than UO 2 and has similar matrix behaviour. The correlation coefficients for calibration curves are better than 0.999. Erros range from 2.4 % for chromium to 6.8 % for nickel. (author) [pt

  10. Development of high performance liquid chromatography for rapid determination of burn-up of nuclear fuels

    International Nuclear Information System (INIS)

    Joseph, M.; Karunasagar, D.; Saha, B.

    1996-01-01

    Burn-up an important parameter during evaluation of the performance of any nuclear fuel. Among the various techniques available, the preferred one for its determination is based on accurate measurement of a suitable fission product monitor and the residual heavy elements. Since isotopes of rare earth elements are generally used as burn-up monitors, conditions were standardized for rapid separation (within 15 minutes) of light rare earths using high performance liquid chromatography based on either anion exchange (Partisil 10 SAX) in methanol-nitric acid medium or by cation exchange on a reverse phase column (Spherisorb 5-ODS-2 or Supelcosil LC-18) dynamically modified with 1-octane sulfonate or camphor-10-sulfonic acid (β). Both these methods were assessed for separation of individual fission product rare earths from their mixtures. A new approach has been examined in detail for rapid assay of neodymium, which appears promising for faster and accurate measurement of burn-up. (author)

  11. The quantum brachistochrone problem for an arbitrary spin in a magnetic field

    Science.gov (United States)

    Kuzmak, A. R.; Tkachuk, V. M.

    2015-06-01

    We consider quantum brachistochrone evolution for a spin-s system on rotational manifolds. Such manifolds are determined by the rotation of the eigenstates of the operator of projection of spin-s on some direction. The Fubini-Study metrics of these manifolds are those of spheres with radii dependent on the value of the spin and on the value of the spin projection. The conditions for optimal evolution of the spin-s system on rotational manifolds are obtained.

  12. Determination of a Wear Initiation Cycle by using a Contact Resistance Measurement in Nuclear Fuel Fretting

    International Nuclear Information System (INIS)

    Lee, Young Ho; Kim, Hyung Kyu

    2008-01-01

    In nuclear fuel fretting, the improving of the contact condition with a modified spring shape is a useful method for increasing the wear resistance of the nuclear fuel rod. This is because the fretting wear resistance between the fuel rod and grid spring is mainly affected by the grid spring shape rather than the environment, the contact modes, etc. In addition, the wear resistance is affected by the wear debris behavior between contact surfaces. So, it is expected that the wear initiation of each spring shape should be determined in order to evaluate a wear resistance. However, it is almost impossible to measure the wear behavior in contact surfaces on a real time basis because the contact surfaces are always hidden. Besides, the results of the worn surface observation after the fretting wear tests are restricted to archive the information on the wear debris behavior and the formation mechanism of the wear scar. In order to evaluate the wear behavior during the fretting wear tests, it is proposed that the contact resistance measurement is a useful method for examining the wear initiation cycle and modes. Generally, fretting wear damages are rapidly progressed by a localized plastic deformation between the contact surfaces, crack initiation and fracture of the deformed surface with a strain hardening difference between a surface and a subsurface and finally a detachment of wear debris. After this, wear debris is easily oxidized by frictional heat, test environment, etc. At this time, a small amount of electric current applied between the contact surfaces will be influenced by the wear debris, which could be an obstacle to an electric current flow. So, it is possible to archive the information on the wear behavior by measuring the contact resistance. In order to determine the wear initiation cycle during the fretting wear tests, in this study, fretting wear tests have been performed by applying a constant electric current in room temperature air

  13. Interference Spins

    DEFF Research Database (Denmark)

    Popovski, Petar; Simeone, Osvaldo; Nielsen, Jimmy Jessen

    2015-01-01

    on traffic load and interference condition leads to performance gains. In this letter, a general network of multiple interfering two-way links is studied under the assumption of a balanced load in the two directions for each link. Using the notion of interference spin, we introduce an algebraic framework...

  14. Spinning worlds

    NARCIS (Netherlands)

    Schwarz, H.

    2017-01-01

    The thesis "Spinning Worlds" is about the characterisation of two types of gas-giant exoplanets: Hot Jupiters, with orbital periods of fewer than five days, and young, wide-orbit gas giants, with orbital periods as long as thousands of years. The thesis is based on near-infrared observations of 1

  15. Determination of radiochemistry purity and pH of radiopharmaceutical in Northeast nuclear medicine services

    International Nuclear Information System (INIS)

    Andrade, Wellington; Santos, Poliane; Lima, Fernando de Andrade; Lima, Fabiana Farias de

    2013-01-01

    The radiopharmaceutical is a chemical compound associated with a radionuclide, which is selected so that meets the need cf diagnosis and capable of producing quality images. Drugs labeled with 99m Tc radionuclide kits consist of lyophilized, and be handled by the nuclear medicine services (NMS) must pass tests as the resolution of ANVISA (RDC 38) published in 2008. Among these tests are those of radiochemical purity and pH determination. This study evaluated the radiochemical purity of radiopharmaceuticals and pH SMN manipulated in the Northeast. The radiochemical purity (RCP) was determined by thin layer chromatography, which were used Whatman ® and silica gel, with dimensions of 1 x 10 cm, as stationary phase, and solvents indicated in the inserts of manufacturers. The chromatographic strips were placed in sealed containers so as not to touch the walls thereof. After the chromatographic run, the tape was cut every centimeter and the activities determined in doses of each calibrator NMS. The pH of the radiopharmaceutical was assessed through the use of universal pH paper (Merck®) and obtained staining compared with its color scale. The results showed (hat 82.6% and 100% of the radiopharmaceuticals of the samples were within the limits recommended by international pharmacopoeias for radiochemical purity and pl-l, respectively. There is then the need to include in routine tests indicated SMN by ANVISA. Well, they can detect possible problems in the marking of radiopharmaceuticals administered to the patient and avoid inappropriate material. (author)

  16. Possibilities of rapid determination of 14C in gaseous discharges from nuclear power facilities

    International Nuclear Information System (INIS)

    Svetlik, Ivo; Tomaskova, Lenka; Pospichal, Jiri; Fejgl, Michal

    2011-01-01

    Two methods of determination of 14 C in stack air accumulated samples from nuclear power plants captured as carbonate are compared and discussed. The usual analytical routine is based on BaCO 3 precipitation and subsequent liquid scintillation (LS) measurement of the resulting suspension in the scintillation mixture. The presented method of 14 C determination applies direct LS counting of accumulated samples containing dissolved carbonates in the scintillation mixture. This method is applicable only to samples with small/negligible amounts of interfering radionuclides (below 10% of 14 C activity). However, during authors' several year experience, significant presence of interfering radionuclides has not been observed (except tritium with E(max) below the low edge of the 14 C measuring window). A disadvantage of the method with direct measurement is a slightly higher limit of determination, about 3 Bq m -3 (TriCarb 3170, measuring time 120 minutes in normal mode). From the point of view of the 14 C discharge balance, the activities of several orders of magnitude Bq do not contribute to the total C budget significantly. The method using direct 14 C measurement facilitates time resolution in the case of rapid changes in 14 C activities in the stack air and reduces costs of the analyses. With use of this method the risk of laboratory contamination is strongly reduced even in the case of samples with elevated 14 C activities. (author)

  17. Determining the short-range spin correlations in the spin-chain Li.sub.2./sub.CuO.sub.2./sub. and CuGeO.sub.3./sub. compounds using resonant Inelastic X-ray scattering

    Czech Academy of Sciences Publication Activity Database

    Monney, C.; Bisogni, V.; Zhou, K.J.; Kraus, R.; Strocov, V.N.; Behr, G.; Málek, Jiří; Kuzian, R.; Drechsler, S.-L.; Johnston, S.; Revcolevschi, A.; Büchner, B.; Ronnow, H.M.; van den Brink, J.; Geck, J.; Schmitt, T.

    2013-01-01

    Roč. 110, č. 8 (2013), "087403-1"-"087403-5" ISSN 0031-9007 Institutional support: RVO:68378271 Keywords : RIXS * spin correlations * temperature dependence of Zhang-Rice singlet Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 7.728, year: 2013

  18. Dynamical nuclear polarization and confinement effects in ZnO quantum dots

    NARCIS (Netherlands)

    Baranov, P.G.; Orlinskii, S.B.; Hofmann, D.M.; de Mello Donega, C.; Meijerink, A.; Schmidt, J.

    2010-01-01

    The spatial distribution of the electronic wave function of a shallow donor (SD) in a ZnO semiconductor quantum dots (QD's) has been determined in the regime of quantum confinement by using the nuclear spins as probes. Hyperfine (HF) interactions as monitored by electron nuclear double resonance

  19. 21st International Symposium on Spin Physics

    CERN Document Server

    Ma, Bo-Qiang; SPIN 2014; SPIN2014

    2016-01-01

    This special volume collected important papers written by leading experts, highlighting the latest research findings in various topics of spin phenomena in particle and nuclear physics. The contents are originated from the plenary talks at the latest symposium of the Spin Physics series (SPIN2014) which was held in Beijing, China, October 20-24, 2014.The volume also comprises a special collection of contributions in memory of the late Professor Michel Borghini, an outstanding physicist well remembered for his great contributions to the progress of high energy spin physics.

  20. Band head spin assignment of superdeformed bands in 133Pr using two-parameter formulae

    Science.gov (United States)

    Sharma, Honey; Mittal, H. M.

    2018-03-01

    The two-parameter formulae viz. the power index formula, the nuclear softness formula and the VMI model are adopted to accredit the band head spin (I0) of four superdeformed rotational bands in 133Pr. The technique of least square fitting is used to accredit the band head spin for four superdeformed rotational bands in 133Pr. The root mean deviation among the computed transition energies and well-known experimental transition energies are attained by extracting the model parameters from the two-parameter formulae. The determined transition energies are in excellent agreement with the experimental transition energies, whenever exact spins are accredited. The power index formula coincides well with the experimental data and provides minimum root mean deviation. So, the power index formula is more efficient tool than the nuclear softness formula and the VMI model. The deviation of dynamic moment of inertia J(2) against the rotational frequency is also examined.