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Sample records for northern neotethys geochemical

  1. Petrogenesis and geodynamics of plagiogranites from Central Turkey (Ekecikdağ/Aksaray): new geochemical and isotopic data for generation in an arc basin system within the northern branch of Neotethys

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    Köksal, Serhat; Toksoy-Köksal, Fatma; Göncüoglu, M. Cemal

    2017-06-01

    In the Late Cretaceous, throughout the closure of the Neotethys Ocean, ophiolitic rocks from the İzmir-Ankara-Erzincan ocean branch were overthrusted the northern margin of the Tauride-Anatolide Platform. The ophiolitic rocks in the Ekecikdağ (Aksaray/Central Turkey) region typify the oceanic crust of the İzmir-Ankara-Erzincan branch of Neotethys. The gabbros in the area are cut by copious plagiogranite dykes, and both rock units are intruded by mafic dykes. The plagiogranites are leucocratic, fine- to medium-grained calc-alkaline rocks characterized mainly by plagioclase and quartz, with minor amounts of biotite, hornblende and clinopyroxene, and accessory phases of zircon, titanite, apatite and opaque minerals. They are tonalite and trondhjemite in composition with high SiO2 (69.9-75.9 wt%) and exceptionally low K2O (<0.5 wt%) contents. The plagiogranites in common with gabbros and mafic dykes show high large-ion lithophile elements/high-field strength element ratios with depletion in Nb, Ti and light rare-earth elements with respect to N-MORB. The plagiogranites together with gabbros and mafic dykes show low initial 87Sr/86Sr ratios (0.70419-0.70647), high ƐNd( T) (6.0-7.5) values with 206Pb/204Pb (18.199-18.581), 207Pb/204Pb (15.571-15.639) and 208Pb/204Pb (38.292-38.605) ratios indicating a depleted mantle source modified with a subduction component. They show similar isotopic characteristics to the other supra-subduction zone (SSZ) ophiolites in the Eastern Mediterranean to East Anatolian-Lesser Caucasus and Iran regions. It is suggested that the Ekecikdağ plagiogranite was generated in a short time interval from a depleted mantle source in a SSZ/fore-arc basin setting, and its nature was further modified by a subduction component during intra-oceanic subduction.

  2. High to ultrahigh potassic alkaline volcanic belt along the Ankara-Erzincan suture (northern Turkey): new geochemical and Ar-Ar data constraining petrogenesis with implications for the late Cretaceous subduction of the Neotethys Ocean

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    Genc, S. Can; Gulmez, Fatma; Tuysuz, Okan; Karacik, Zekiye; Roden, Michael F.; Zeki Billor, M.; Hames, Willis E.

    2013-04-01

    Remnants of some high- to ultrahigh-K alkaline volcanic rocks crop out as isolated small and discontinuous bodies along the Ankara-Erzincan suture belt in northern Turkey. These rocks are represented by leucite-bearing lavas (LB), basaltic andesites, trachytes, monzonite/syenites) and lamprophyres. Leucite-bearing rocks are small stocks, dikes and lava flows. Pebbles and blocks of the LB are found in the coeval volcanic debris avalanche deposits and volcanoclastic breccias. Leucite-bearing rocks are mainly phonotephrite, tephriphonolite, trachyandesite and basaltic trachyandesites (shoshonite) and have mineral assemblages of lct + cpx + ol + pl + Kfs + mag+ ap. Leucites were almost totally analcimized. Trachytes and monzonite/syenites, which are seen as small stocks and dikes, are characterized by amp + bt + pl + Kfs + spn + ap + opq paragenesis. Lamprophyres are mica-rich melanocratic dikes, and include cpx + mica (phlogopitic) + Kfs + ap + opq. Rarely leucite, olivine and plagioclase are also present. Ar-Ar data reveal that this volcanic activity occurred between 73.6±0.18 and 76.78±0.19 Ma, corresponding to latest Cretaceous. All the samples from the high- and ultrahigh-K volcanic belt are alkaline in nature. Leucite-bearing lavas are characterized by their MgO (2.70-5.81, av. 4.58 wt.%), K2O (0.79-4.81, av. 2.35 wt.%), Na2O (4.86-7.48, av. 3.58 wt.%) and K2O/Na2O (0.13-0.92, av. 0.42 wt.%). The low K2O and K2O/Na2O contents of these rocks are due to extensive analcimization of the leucites. Major oxide contents in lamprophyric rocks are 3.25-7.48 (MgO), 1.35-7.76 (K2O), 1.77-4.00 (Na2O) and 0.31-2.69 (K2O/Na2O). The silica content of these rocks are variable and range from 47.18-50.26 (wt.%) (LB) to 39.14-53.28 (lamprophyres). Based on their major element contents, these rocks are classified as plagioleucitites or ultrapotassic rocks of the active orogenic zones (Foley, 1992). Leucite-bearing rocks, lamprophyres and the trachytes (with their hypabyssal

  3. Middle Triassic back-arc basalts from the blocks in the Mersin Mélange, southern Turkey: Implications for the geodynamic evolution of the Northern Neotethys

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    Sayit, Kaan; Bedi, Yavuz; Tekin, U. Kagan; Göncüoglu, M. Cemal; Okuyucu, Cengiz

    2017-01-01

    The Mersin Mélange is a tectonostratigraphic unit within the allochthonous Mersin Ophiolitic Complex in the Taurides, southern Turkey. This chaotic structure consists of blocks and tectonic slices of diverse origins and ages set in a clastic matrix of Upper Cretaceous age. In this study, we examine two blocks at two different sections characterized by basaltic lava flows alternating with radiolarian-bearing pelagic sediments. The radiolarian assemblage extracted from the mudstone-chert alternation overlying the lavas yields an upper Anisian age (Middle Triassic). The immobile element geochemistry suggests that the lava flows are predominantly characterized by sub-alkaline basalts. All lavas display pronounced negative Nb anomalies largely coupled with normal mid-ocean basalt (N-MORB)-like high field strength element (HFSE) patterns. On the basis of geochemical modelling, the basalts appear to have dominantly derived from spinel-peridotite and pre-depleted spinel-peridotite sources, while some enriched compositions can be explained by contribution of garnet-facies melts from enriched domains. The overall geochemical characteristics suggest generation of these Middle Triassic lavas at an intra-oceanic back-arc basin within the northern branch of Neotethys. This finding is of significant importance, since these rocks may represent the presence of the oldest subduction zone found thus far from the Neotethyan branches. This, in turn, suggests that the rupturing of the Gondwanan lithosphere responsible for the opening of the northern branch of Neotethys should have occurred during the Lower Triassic or earlier.

  4. Early Late Triassic Subduction in the Northern Branch of Neotethys?: Petrological and Paleontological Constraints from the middle Carnian basalts in the Lycian Nappes

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    Sayit, K.; Göncüoglu, M. C.; Tekin, U. K.

    2015-12-01

    The Lycian Nappes, SW Anatolia, are represented by a stack of thrust sheets derived from the northern branch of Neotethys (i.e. Izmir-Ankara Ocean) and the northern margin of the Tauride-Anatolide platform. The Turunç Unit, which is now preserved within a tectonic slice of the Lycian Nappes, includes among others the Neotethys-derived basalt blocks with pelagic intra-pillow carbonate infillings of middle Carnian age (early Late Triassic). Here, we focus on the geochemistry of the Turunç basalts to shed light into their petrogenetic evolution within the Neotethyan framework. Immobile trace element systematics indicate that the Turunç lavas are sub-alkaline basalts, with geochemical signatures resembling to those generated above subduction zones. Detailed examination of the Turunç volcanics reveals two chemical groups. Both groups are variably enriched in Th and La relative to Nb, and exhibit depleted Zr and Hf contents relative to N-MORB. Of the two groups, however, Group 2 is more enriched in Th, but with a similar Nb content, which results in higher Th/Nb ratios (0.21-0.27) compared to those of Group 1 (0.08-0.11). Both groups reflect similar REE systematics; they display marked enrichment in LREE relative to HREE ([La/Yb]N = 4.8-8.9). Trace element characteristics of the Turunç basalts indicate that their mantle source has been modified by slab-derived component(s). Taking into account that the Turunc Unit includes no continent-derived detritus, we suggest that the Turunç lavas represent fragments of a Late Triassic island arc formed on the Neotethyan oceanic lithosphere. This may further imply that the Neotethyan oceanic lithosphere had already been formed by the early Late Triassic, thus suggesting a pre-early Late Triassic oceanization of the northern branch of Neotethys.

  5. Progressive Subduction-Accretion Growth of the Late Paleozoic-Cretaceous Izmir-Ankara Suture Zone Melange in Northern Anatolia, Turkey, and a New Tectonic Model for the Evolution of Northern Neotethys

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    Dilek, Y.; Sarifakioglu, E.; Sevin, M.

    2011-12-01

    Seamount-oceanic plateau remnants and ophiolite fragments with MORB-like and island arc tholeiite (IAT) affinities occur as blocks in the Ankara Mélange along the Izmir-Ankara-Erzincan suture zone in north-central Turkey, and provide temporal and geochemical evidence for magmatism associated with subduction initiation-evolution and convergent margin growth in the Northern Neotethys. Ophiolitic blocks and the serpentinite and/or greywacke matrix of the mélange are deformed and imbricated along generally south-directed thrust sheets as a result of the north-dipping subduction polarity and the continental collision tectonics in the early Paleogene. Plagiogranite dikes intruding the SSZ gabbros have revealed U/Pb zircon ages of 179 Ma; epi-ophiolitic pelitic rocks resting directly on various ophiolitic units, on the other hand, contain zircons with ages around 130 Ma. Upper Cretaceous flyschal deposits unconformably cover imbricate thrust sheets of the SSZ-type ophiolite and the ophiolitic mélange containing MORB-like ophiolitic slabs and seamount fragments. SSZ-type ophiolite blocks include upper mantle peridotites, cumulate to massive gabbros, sheeted diabase dykes, plagiogranite veins and stocks, and basalt-chert-radiolarite. MORB-like ophiolitic blocks mainly contain upper mantle peridotites, massive gabbros, basaltic lavas, and chert-radiolarite. TiO2 contents of the SSZ-type, diabasic dykes and basaltic lavas are between 0.2 - 0.93 wt.%, whereas those of the MORB-like basalts range between 0.85 - 5.05 wt.%. Nb contents of the SSZ-type diabasic dykes and basaltic lavas range between 0.1-2.5 ppm and of the MORB-like lavas between 3.7-5.4 ppm. SSZ-type basic rocks have Th/Yb ratios of 0.1-1 whereas the MORB-like basic rocks show Th/Yb values ranging from 0.01 to 0.3, suggesting enrichment by slab-derived fluids. The low TiO2 and Nb values, combined with higher Th/Yb ratios, indicate an IAT affinity of the SSZ rock suites in comparison to the tholeiitic features

  6. Geochemical and palaeontological characterization of a new K-Pg Boundary locality from the Northern branch of the Neo-Tethys: Mudurnu - Goynuk Basin, NW Turkey

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    Acikalin, S.; Vellekoop, J.; Ocakoglu, F.; Yilmaz, I.O.; Smit, J.; Altiner, S.O.; Goderis, S.; Vonhof, H.B.; Speijer, R.P.; Woelders, L.; Fornaciari, E.; Brinkhuis, H.

    2015-01-01

    A Cretaceous-Paleogene (K-Pg) succession is studied in detail in the Mudurnu-Göynük basin in northwestern Turkey. To characterize the K-Pg transition in this basin, two stratigraphic sections were measured and sampled at high resolution: the Okçular and the Göynük North sections. These sections were

  7. The Porretta thermal springs (Northern Apennines: seismogenic structures and long-term geochemical monitoring

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    F. Italiano

    2007-06-01

    Full Text Available The thermal springs of Porretta are located on a seismically active area of the Northern Apennines. In 19th Century a chemist identified anomalous behaviour of the thermal waters in concomitance with local seismic events. Recent studies assessed the geochemical features of the circulating fluids (e.g., waters carry a dissolved CH4-dominated gas phase with a radiogenic signature of the helium isotopic ratio and observed anomalous hydrologic and geochemical signals possibly related to crustal strain phenomena due to local seismic events. Long-term geochemical monitoring was carried out from 2001 to 2006 with the aim of detecting the behaviour of the circulating fluids possibly coinciding with seismic activity. The collected data reveal a sensitivity of the thermal waters to the activity of the main fault crossing the village of Porretta and identify a «seismogenic» structure crossing the village.

  8. Role of local to regional-scale collisions in the closure history of the Southern Neotethys, exemplified by tectonic development of the Kyrenia Range active margin/collisional lineament, N Cyprus

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    Robertson, Alastair; Kinnaird, Tim; McCay, Gillian; Palamakumbura, Romesh; Chen, Guohui

    2016-04-01

    Active margin processes including subduction, accretion, arc magmatism and back-arc extension play a key role in the diachronous, and still incomplete closure of the S Neotethys. The S Neotethys rifted along the present-day Africa-Eurasia continental margin during the Late Triassic and, after sea-floor spreading, began to close related to northward subduction during the Late Cretaceous. The northern, active continental margin of the S Neotethys was bordered by several of the originally rifted continental fragments (e.g. Taurides). The present-day convergent lineament ranges from subaqueous (e.g. Mediterranean Ridge), to subaerial (e.g. SE Turkey). The active margin development is partially obscured by microcontinent-continent collision and post-collisional strike-slip deformation (e.g. Tauride-Arabian suture). However, the Kyrenia Range, N Cyprus provides an outstanding record of convergent margin to early stage collisional processes. It owes its existence to strong localised uplift during the Pleistocene, which probably resulted from the collision of a continental promontory of N Africa (Eratosthenes Seamount) with the long-lived S Neotethyan active margin to the north. A multi-stage convergence history is revealed, mainly from a combination of field structural, sedimentological and igneous geochemical studies. Initial Late Cretaceous convergence resulted in greenschist facies burial metamorphism that is likely to have been related to the collision, then rapid exhumation, of a continental fragment (stage 1). During the latest Cretaceous-Palaeogene, the Kyrenia lineament was characterised by subduction-influenced magmatism and syn-tectonic sediment deposition. Early to Mid-Eocene, S-directed thrusting and folding (stage 2) is likely to have been influenced by the suturing of the Izmir-Ankara-Erzincan ocean to the north ('N Neotethys'). Convergence continued during the Neogene, dominated by deep-water terrigenous gravity-flow accumulation in a foredeep setting

  9. Hydro-geochemical appraisal of groundwater quality from weathered basement aquifers in Northern Malawi

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    Wanda, Elijah; Monjerezi, Maurice; Mwatseteza, Jonas F.; Kazembe, Lawrence N.

    The obligation to ensure adequate potable water supply to everyone, has necessitated the development of groundwater resources for reliable rural water supply in most developing countries. An understanding of spatial variation and processes affecting water quality is essential in sustaining usable water supplies under changing climate and local environmental pressures. In this study, an assessment of quality and dominant hydro-geochemical processes affecting the quality of groundwater from weathered basement aquifers in Mzimba district, Northern Malawi, has been conducted. Groundwater samples were collected from 172 hand-pumped boreholes, drilled for domestic rural water supply and analysed for major and minor ions, pH and total dissolved solids (TDS). In general, groundwater is of low mineralisation (TDS range: 29-1896 mg L -1 for the dry season), with hydro-geochemical facies dominated by Ca-HCO 3, which evolves to Ca-Cl water type. Multivariate statistical analysis (HCA and PCA) and geochemical interpretation showed that the Ca-HCO 3 groundwater type result from hydrolysis of silicate minerals, which causes the solution to reach equilibrium with kaolinite. The processes of cation exchange of Na + and K + in the groundwater for Ca 2+ and Mg 2+ on clay minerals, carbonate precipitation and evaporation, are shown to modify the chemical composition from Ca-HCO 3 types to Ca-Cl types. Groundwater is generally of good quality in both rainy and dry seasons, with little seasonal changes. The United States Salinity Laboratory Staff and Wilcox diagrams showed that most samples were also suitable for irrigation except for 4% (eight samples) of the groundwater samples (with EC > 2000 μS cm -1). These are located in alluviums and colluviums localised near river banks and in inter hill valleys.

  10. Characterization of geochemical alteration halo associated with gold mineralization at the Buzwagi mine, northern Tanzania

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    Manya, Shukrani

    2017-05-01

    Alteration halo geochemical study was carried out along one transect at the Buzwagi mine which is found in the Neoarchaean Nzega greenstone belt of northern Tanzania. The Buzwagi mine Au mineralization is hosted in quartz veins that are cross-cutting strongly sheared and hydrothermally altered K-granites. Mineralogical studies within the shear zone reveal that sericite, silica and sulphides are the most important hydrothermal mineral assemblages responsible for Au mineralization at the Buzwagi mine. The geochemical alteration halo is characterized by the addition of Au, Cu, Fe, K, Rb, Sn, W and U to wall rocks and simultaneous removal of Na, Sr, Ba, LREE and MREE from the host rocks. The concentrations of Cu (130-870 ppm) which show strong positive correlation with Au (R2 = 0.99) are so high in the alteration halo indicating that Cu is a strong Au pathfinder at the Buzwagi mine. Owing to their immobility during the post-emplacement processes, the HFSE (Zr, Hf, Th, Ta) remained unchanged during the hydrothermal alteration process. The addition of Fe and Cu is attributed to the presence of Fe- and Cu-sulphides (pyrite, chalcopyrite and chalcocite) whereas the addition of K, Rb, Sn, W and U is a function of both primary concentrations of these elements in the host rocks as well as the subsequent strong hydrothermal alteration evidenced by sericitization and silicification which involved the destruction of feldspars into sericites). The destruction of albite and its replacement by sericite accounts for the depletion of Na, Sr (and Ba). The Buzwagi mine Au mineralization mineral association do not include the more known pathfinders like Ag, As, Sb, Bi, Te and Tl and they seem not to have played a role in the mineralization process. These elements, therefore, should not be considered as pathfinders for Au exploration purposes at a Buzwagi-like deposit.

  11. Chemical Mineralogy, Geochemical Characterization and Petrography of the Cambumbia Stock, Northern Andes, South America, Colombia

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    Rojas Lequerica, Salvador; María Jaramillo Mejía, José; Concha Perdomo, Ana Elena; Jimenez Quintero, Camilo

    2013-04-01

    The Cambumbia Stock is located on the western flank of the Central Cordillera of the northern Andes, South America. The goals of this study were to characterize the mineral chemistry, the geochemical composition and the petrography of the Cambumbia igneous body and to establish its petrogenesis. We collected 41 samples, selected 28 for thin section petrographic analysis, 14 for whole rock elementary chemical determination by ICP-MS and 4 for chemical mineralogy by LA-ICP(JEOL JXA-8200). Petrographically the samples were classified as 30 % hornblende-gabbro, 30% pyroxene-gabbros, 10% diorites, 10% olivine-gabbro, 7% gabbronorites, 7% tonalities and 3% norite, 3% wehrlite, the rock varies from medium to coarse hipidiomorfic and holocristaline texture, with local microporfiritic texture. Spot elemental chemical analysis of the some minerals in 4 samples show the range of the major elemental composition is plagioclase (labradorite), clinopyroxene (augite), horblende (magnesiohornblende), olivine (fayalite())Chemical mineralogy shows the variety of minerals in this rock, essential minerals correspond to bytownite, augite, magnesio-honblende, fallaite and titanite. We conclude base on the SiO2 Vs Total Alkalis graph that the samples correspond to the sub-alkaline series with low K content, mainly in the calc-alkaline series. By using the SiO2 vs TiO2, Th/Yb vs Ta/Yb and Zr/117-Th-Nb/16 diagrams it was determined that these rocks were generated in two geotectonic environments: one type MOR (extension) and other island arc (subduction, compression). Recently, a U/Pb age was obtained by the Universidad de Caldas in zircon in 2009 (not published data), yielded an age of 233.41 ± 3.4 Ma (Carnian - Upper Triassic). Petrographic geochemical and geochronology comparisons between the rocks of Cambumbia Stock and Diorite and Gabbro El Pueblito (located about 25 km to the north-west) and with U/Pb age 231 ± 8 may postulate a possible genetic link between them. These ages are

  12. The geochemical landscape of northwestern Wisconsin and adjacent parts of northern Michigan and Minnesota (geochemical data files)

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    Cannon, William F.; Woodruff, Laurel G.

    2003-01-01

    This data set consists of nine files of geochemical information on various types of surficial deposits in northwestern Wisconsin and immediately adjacent parts of Michigan and Minnesota. The files are presented in two formats: as dbase files in dbaseIV form and Microsoft Excel form. The data present multi-element chemical analyses of soils, stream sediments, and lake sediments. Latitude and longitude values are provided in each file so that the dbf files can be readily imported to GIS applications. Metadata files are provided in outline form, question and answer form and text form. The metadata includes information on procedures for sample collection, sample preparation, and chemical analyses including sensitivity and precision.

  13. Geochemical evolution of Ngorongoro Caldera, Northern Tanzania: Implications for crust magma interaction

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    Mollel, Godwin F.; Swisher, Carl C.; Feigenson, Mark D.; Carr, Michael J.

    2008-07-01

    Ngorongoro Caldera is the largest and best-preserved of nine Plio-Pleistocene volcanoes that make-up the Ngorongoro Volcanic Highlands (NVH) complex situated at the southern bifurcation of Gregory Rift, part of the East African Rift system of northern Tanzania. We report here, major and trace element abundances, Sr-Nd-Pb isotope analyses and 40Ar/ 39Ar laser incremental-heating and total fusion ages on lava and tephra sampled from stratigraphic sections exposed within the Ngorongoro Caldera. Major and trace elements measured on samples collected from the Ngorongoro Caldera wall indicate a stratified magma chamber whose silicic top and basaltic bottom was inverted by sequential eruptions. Samples from the lower part of the exposed Ngorongoro Caldera wall are high in silica, alkalis and HFSE (High Field Strength Elements). The Zr, Nb and Hf concentrations are highly correlated with each other and decrease up-section, indicative of the extent of magma evolution. Modeling of major, trace as well as Sr, Nd and Pb isotope data suggests that assimilation fractional crystallization processes were essential in producing the observed geochemical variations. The Sr and Nd isotope ratios from the Ngorongoro samples are widely dispersed ( 87Sr/ 86Sr = 0.70405 to 0.70801, 143Nd/ 144Nd = 0.512205 to 0.512623) and Pb isotope ratios are consistent with previous studies: 206Pb/ 204Pb = 18.73 to 19.37, 207Pb/ 204Pb = 15.64 to 15.69, 208Pb/ 204Pb = 39.52 to 39.55. Although Sr isotopic ratios are similar to Oceanic Island Basalt (OIB), the more radiogenic samples ( 87Sr/ 86Sr > 0.705) from the lower part of the section suggest crust-magma interaction; this is supported by Ce/Pb ratios (Ngorongoro Caldera wall section yield 40Ar/ 39Ar ages of 2.25 ± 0.02 Ma to 2.01 ± 0.02 Ma, constraining a duration of volcanism of the order of ~ 240 kyr. These ages suggest correlation of a normal to reverse geomagnetic polarity transition measured in the Ngorongoro Caldera wall section with the ~ 2

  14. Large Early Permian eruptive complexes in northern Saxony, Germany: Volcanic facies analysis and geochemical characterization

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    Hübner, Marcel; Breitkreuz, Christoph; Repstock, Alexander; Heuer, Franziska

    2017-04-01

    In the course of formation of extensional basins during the Early Permian a widespread volcanic activity led to the deposition of volcanic and volcanosedimentary units in Saxony (Walter 2006, Hoffmann et al. 2013). Situated east of Leipzig, the North Saxonian Volcanic Complex (NSVC) hosts two large caldera complexes, the Rochlitz and Wurzen Volcanic Systems, with diameters of 90 and 52 km, respectively. Volume estimates (> 1000 km3) qualify these as supereruptions according to Mason et al. (2004). In addition to the large caldera systems, the NSVC hosts several small pyroclastic flow deposits ranging from crystal-poor (e.g. Cannewitz and vitrophyric Ebersbach ignimbrites) to crystal-rich units (Wermsdorf and Dornreichenbach ignimbrites). Additionally rhyolitic lava and subvolcanic units are present. The Chemnitz basin (Schneider et al. 2012), located to the south of the NSVC, harbours caldera-outflow facies deposits of the Rochlitz eruption (Fischer 1991), i.e. the partially vitrophyric Planitz ignimbrite. The Rochlitz and Wurzen caldera-fill ignimbrites exhibit relatively high crystal contents with maxima up to 52 and 58 vol.-%, for corresponding 66 and 68 wt.-% SiO2. This is comparable with the 'monotonous intermediates' (Hildreth 1981) in the Cenozoic western USA investigated by Huber et al. (2012). In contrast, the Planitz ignimbrite in the Chemnitz basin reveals predominantly crystal-poor pyroclastics ( 70 analyses), and mineral geochemistry to reconstruct the eruption history and magma genesis of this large Late Paleozoic magmatic complex in Central Europe. Volcanic textures and geochemical trends indicate magma mingling and mixing to have been important during the formation of the Wurzen caldera system. Geothermometric and -barometric calculations based on composition of pyroxene and feldspar suggest deeply seated crustal magma chambers for the NSVC and the Planitz ignimbrite. Fischer, F. (1991): Das Rotliegende des ostthüringisch-westsächsischen Raumes

  15. Geochemical, Sr-Nd isotopic investigations and U-Pb zircon chronology of the Takht granodiorite, west Iran: Evidence for post-collisional magmatism in the northern part of the Urumieh-Dokhtar magmatic assemblage

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    Haghighi Bardineh, Seyyed Nematollah; Zarei Sahamieh, Reza; Zamanian, Hassan; Ahmadi Khalaji, Ahmad

    2018-03-01

    Subduction of Neo-Tethys lithosphere beneath the Iranian plateau during Neogene led to the formation of a NW-SE trending volcano-plutonic zone called Urumieh-Dokhtar magmatic assemblage (UDMA). The Takht granodiorite (NE of Hamedan Province, western Iran) belongs to the UDMA and has geochemical properties of post-collisional granitoids that was formed after the collision of Arabian and Iranian plateaus. This body contains rounded mafic micro-granular enclaves with relatively gradational rims indicating the effect of magma mixing/mingling in formation of the granodiorite body. The determination of U-Pb zircon age proved the Takht granodiorite was formed at Miocene (16.8 ± 0.24 Ma). The Nd-Sr isotope ratios and Sr/Nd, Nb/La and Th/U ratios of the granodiorite confirmed the magma was formed mainly by melting of continental crust, and its enclaves originated from a mantle derived mafic magma. Samples show negative anomalies in Nb, Sr, Ti, P and Eu, whereas positive anomalies in Th, K, Zr, Yb and Rb that reveals contribution of mantle and crustal materials in their generation. The Takht granodiorite has geochemical features of A2-type granites and also shows properties of both the volcanic arc and within plate magmatism association granitoids (high levels of LILEs and HFSEs). Regarding this interpretation and also post-collisional tectonic regime, it can be concluded that post-collision extensions caused deep faults in the UDMA that let mantle derived magmas rise up to the thicken crust. Such magma triggered melting in the middle crustal levels and was contaminated with crustal materials to generate granodiorite and enclave magmas respectively. The results of the current study decipher collision between the Arabian and the Iranian plateaus occurred before Miocene and the magmatism in the UDMA continued after closure of Neo-Tethys.

  16. Low Carbon Black Shales of South and Parts of Central and Northern Urals: New Geochemical Characterization Data

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    A. V. Maslov

    2017-03-01

    Full Text Available We analyzed the distribution of wide range of trace elements in low-carbon shales of various Riphean, Vendian and Lower Paleozoic lithostratigraphic units of the South, Central, and southern part of the Northern Urals (Satka, Bolshoy Inzer, Suran, Yusha, ZigazinoKomarovo, Vels, Buton, Bezgodovo, and other suites. It was determined that they significantly differ in content of the trace elements. In the most cases, the concentration of trace elements in these shales is roughly comparable with those found in well-known geochemical units, such as the Post-Archean Australian Shale (PAAS, or is lower. Alternatively, obtained data showed significant differences between the Urals low-carbon black shales and the Vendian and Cambrian black shales from China, and other black shale formations, characterized by higher concentration of many trace elements. We consider the probable important role of the geodynamic position of black shale formation, variation in the bioproductivity, association with specific rock complexes, and extent of secondary transformations in variability of geochemical composition of the black shale sediments.

  17. Geological-geochemical characterization of the Semilus and upper Frasnian deposits of the northern part of the Timano-Pechorsk province. [USSR

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    Aminov, L.Z.; Peneva, A.Z.; Udot, V.F.

    1981-01-01

    A geochemical characterization of the semilux-upper-Frasnian sections of various Paleotectonic elements of the northern part of the Timano-Pechorsk province is presented. The distribution of oil and gas source rock is established and an assessment of the regions is given.

  18. Natural compositional variation of the river Meuse (Maas) suspended load: a 13 ka bulk geochemical record from the upper Kreftenheye and Betuwe Formations in northern Limburg

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    Tebbens, L.A.; Veldkamp, A.; Kroonenberg, S.B.

    2000-01-01

    Unambiguously pristine and largely unpolluted sediments from the Late Weichselian and Holocene infillings of the Meuse residual channels in northern Limburg (the Netherlands) have been sampled to determine the natural compositional variation of the river’s suspended load. Bulk geochemical and

  19. Mineralogical and Geochemical Studies of Bone Detritus of Pleistocene Mammals, Including the Earliest in Northern Eurasia Humans

    Directory of Open Access Journals (Sweden)

    V. I. Silaev

    2015-12-01

    Full Text Available Article presents the preliminary results of mineralogical and geochemical studies of the primary and epigenetic properties of the bio-mineral and protein components in the fossil bone detritus as an example of first step of continued interdisciplinary research program. During the further implementation of this program, it is expected not only to solve a set of interrelated mineralogical, paleontological, paleoecological, paleoclimatic, and archaeological problems, but also to obtain new knowledge about the coevolution of organic, organo-mineral and inorganic substances in the geological history. The main objects of study are the fossil remains of the large Pleistocene mammals (mammoths, woolly rhinoceroses, deer, elk, horses, bison, cave and brown bear found on the territory of the Pechora Urals (62-67 ° N , South Pri-Irtyshie in Western Siberia (57-58 ° N, and Northern Taymyr (75-77 ° N. The oldest bone of Homo sapiens (Ust-Ishim human found in Northern Eurasia and remains of medieval Tobol and Irtysh Turk will be investigated as well. The results of previous studies of skin and hair of biological material from today's wild fisheries (analogues Pleistocene mammals, wild and domestic animals are considered as the reliable prerequisites for planned isotopic and geochemical studies. Use of cutting-edge research techniques will allow determining the chemical composition of bones; the elemental composition of bone collagen and bone proteins; the degree of crystallinity of bone bioapatite, and phase composition of xenomineral impurities; the isotopic composition of carbon, oxygen, and nitrogen in bioapatite and collagen; the actual molecular and crystal structure of the protein biomineral, and bone substance; the concentration of trace elements; the conditions and duration of burial and reburial of bone detritus; bone collagen bacterial degradation at an early stage of fossilization. It is expected that the implementation of the proposed project

  20. Mineralogical, geochemical and hydrocarbon potential of subsurface Cretaceous shales, Northern Western Desert, Egypt

    Directory of Open Access Journals (Sweden)

    D.A. Mousa

    2014-03-01

    Full Text Available Twenty four Cretaceous shale core samples of Gibb Afia-1, Betty-1, Salam-1X and Mersa Matruh-1 wells were mineralogically and geochemically studied using XRD, XRF and Rock Eval Pyrolysis. Kaolinite, smectite and illite are the main clay minerals in addition to rare chlorite, while the non-clay minerals include quartz, calcite, dolomite and rare siderite. The shales were derived through intensive chemical weathering of mafic basement and older sedimentary rocks. These sediments were deposited in a near-shore shallow marine environment with some terrestrial material input. The shales have poor to fair organic content. It is marginally to rarely mature.

  1. Geochemical make-up of oceanic peridotites from NW Turkey and the multi-stage melting history of the Tethyan upper mantle

    Science.gov (United States)

    Uysal, İbrahim; Şen, A. Dündar; Ersoy, E. Yalçın; Dilek, Yildirim; Saka, Samet; Zaccarini, Federica; Escayola, Monica; Karslı, Orhan

    2014-02-01

    We present the whole-rock and the mineral chemical data for upper mantle peridotites from the Harmancık region in NW Turkey and discuss their petrogenetic-tectonic origin. These peridotites are part of a Tethyan ophiolite belt occurring along the İzmir-Ankara-Ercincan suture zone in northern Turkey, and include depleted lherzolites and refractory harzburgites. The Al2O3 contents in orthopyroxene and clinopyroxene from the depleted lherzolite are high, and the Cr-number in the coexisting spinel is low falling within the abyssal field. However, the orthopyroxene and clinopyroxene in the harzburgites have lower Al2O3 contents for a given Cr-number of spinel, and plot within the lower end of the abyssal field. The whole-rock geochemical and the mineral chemistry data imply that the Harmancık peridotites formed by different degrees of partial melting (~%10-27) of the mantle. The depleted lherzolite samples have higher MREE and HREE abundances than the harzburgitic peridotites, showing convex-downward patterns. These peridotites represent up to ~16 % melting residue that formed during the initial seafloor spreading stage of the Northern Neotethys. On the other hand, the more refractory harzburgites represent residues after ~4-11 % hydrous partial melting of the previously depleted MOR mantle, which was metasomatized by slab-derived fluids during the early stages of subduction. The Harmancık peridotites, hence, represent the fragments of upper mantle rocks that formed during different stages of the tectonic evolution of the Tethyan oceanic lithosphere in Northern Neotethys. We infer that the multi-stage melting history of the Harmancık peridotites reflect the geochemically heterogeneous character of the Tethyan oceanic lithosphere currently exposed along the İzmir-Ankara-Erzincan suture zone.

  2. Multi-Element Analysis and Geochemical Spatial Trends of Groundwater in Rural Northern New York

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    Michael O’Connor

    2010-05-01

    Full Text Available Samples from private wells (n = 169 throughout St. Lawrence County, NY were analyzed by ICP-MS multi-element techniques. St. Lawrence County spans three diverse bedrock terranes including Precambrian crystalline rocks of the Adirondack Lowlands (mostly paragneisses and Highlands (mostly orthogneisses, as well as Paleozoic sedimentary rocks of the St. Lawrence Valley. An ArcGIS database was constructed and used to generate contour plots for elements across the county. Strontium isotopes and unique geochemical signatures were used to distinguish water from various geologic units. The results were consistent with a large (7,309 km2, sparsely populated (~110,000, rural region with diverse bedrock and glacial cover.

  3. Gas discharges from four remote volcanoes in northern Chile (Putana, Olca, Irruputuncu and Alitar: a geochemical survey

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    Thomas Darrah

    2011-06-01

    Full Text Available We analyzed gas samples collected from fumaroles and bubbling pools at Irruputuncu, Putana, Olca and Alitar volcanoes located in the central Andes volcanic zone (northern Chile. The Irruputuncu and Putana fumarolic discharges showed outlet temperatures ranging from 83 ˚C to 240 ˚C and from 82 ˚C to 88 ˚C, respectively. The chemical and isotopic (3He/4He, d13C-CO2, d18O-H2O and dD-H2O compositions of these discharges were similar to medium-to-high temperature volcanic gases from other active volcanoes in this sector of the Andean volcanic chain (e.g. Lascar volcano. Inorganic and organic gas geothermometers for the H2O-CO2-CO-H2, CO2-CH4 and C2-C3 alkenes-alkanes systems indicated equilibrium temperatures that exceed 500 ˚C at the gas sources. These relatively high temperatures are in agreement with the presence of relevantly high concentrations of magmatic gas emissions, including SO2. Olca and Alitar volcano fluid chemistries indicated lower amounts of magmatic-derived gas species, while both the helium and the water isotopic compositions suggested significant fractions of shallow, crustal/meteoric-originated fluids. These indicate contributions from a hydrothermal environment with temperatures <400 ˚C. The geochemical and isotopic features derived from the present study show that the Irruputuncu, Putana, Olca and Alitar volcanoes should be considered as active and thus warrant periodic geochemical monitoring to determine the evolution of these systems and their potential hazards.

  4. Geochemical Constraints on the pre-Cenozoic Subduction History of two Margins of the Chortis Block (Northern Central America)

    Science.gov (United States)

    Geldmacher, J.; Martens, U.; Hoernle, K.; Hauff, F.; Bogaard, P.; Kluegel, A.

    2007-12-01

    The igneous forearc basement along the Pacific coast of northern Central America (between southern Mexico and Costa Rica) comprises a highly tectonized accretionary assemblage of igneous and ultramafic rocks. Volcanic and gabbroic rocks with primitive arc geochemical signatures formed between ~100 and ~180 Ma and are interpreted to have originated by arc magmatism resulting from subduction of the Pacific/Farallon plate. Additionally, the forearc contains geochemically enriched ocean island basalt (OIB)-like units that are interpreted as accreted seamounts and islands of a 100 to ~220 Ma old hotspot track, which most likely originated from a long-extinct hotspot located in the Pacific. Based on their combined Pb, Nd, Hf isotopic compositions an affiliation of these isotopically strongly enriched rocks with the Caribbean Large Igneous Province or the Galápagos hotspot appears unlikely. Rocks of similar age and geochemistry are exposed in the Santa Elena Peninsula of Costa Rica, suggesting that the same type of forearc basement is accreted to the continental Chortis block all the way from southern Mexico to Costa Rica. In contrast, gabbroic rocks of the Motagua suture zone in central Guatemala (El Tambor accretionary complex) show depleted MORB signatures and have igneous ages of ~130Ma. These MOR Gabbros were accreted on the current northern margin of the Chortis block during subduction of proto-Caribbean crust. In contrast, geochemistry of gabbros and diorites of the Sierra de Santa Cruz (SSC) indicate medium to high K-series arc affinity and their Ar/Ar ages range from ~75 to 130 Ma. The SSC is interpreted as the western extension of the early Cuban arc that collided with the Maya block in the latest Cretaceous. Arc-derived volcanic clasts were subsequently shed into the Paleocene Sepur Formation of the Maya block. No evidence of accretion of OIB-like material was found in the Motagua suture or the SSC so far. These new data suggest that proto-Caribbean crust

  5. Geochemical composition of permafrost-affected soils around the town Tiksi, Northern Yakutia, Russia

    Science.gov (United States)

    Antcibor, Iuliia; Eschenbach, Annette; Pfeiffer, Eva-Maria

    2014-05-01

    Northeastern Siberia represents an area remote from evident anthropogenic trace metal sources. However, a risk of airborne pollution by trace metals from anthropogenic sources connected to the settlements exists. The largest of these are the settlements Tiksi (71° 42' 55.6" N, 128° 48' 46.3" E) and Kyusyur (70° 45' 41.7" N, 127° 23' 04.7" E). The area of Tiksi is located between the Lena River and the Kharaulach River mouths. It covers parts of Primorsky Ridge and Kharaulach Mountains which are a part of the Verkhoyansk Range. The objective of this study was to investigate features of the spatial element distribution in representative landscape-geochemical units of the Tiksi area and to identify whether local pollution from the settlement takes place. The physical and chemical properties of soils were accessed at three sites located radially in the immediate vicinity to the town Tiksi and one control site remote 10 km south from the settlement. The elements measured were As, Cd, Co, Cu, Fe, Mn, Ni, Pb, and Zn in soils. Differences in the element content were found for various relief forms (depressions, slopes, and elevations). The coefficient of soil buffer capacity (Bf) for the surface soil horizons in depressions was the highest (Bf > 40 %) for the majority of elements indicating their intensive accumulation there. In the surface soil horizons of elevated landscape forms the coefficient, by contrast showed low to very low soil buffer capacity to accumulate metals (0 % acid-base barriers. No significant difference in metal distribution among studied sites was revealed, except for the western site which was characterized by the highest median Ni concentration. The data suggest that ecological impacts at the studied sites were low except for one site north to Tiksi where signs of local pollution probably as a result of local emissions of fuel and mining operations were detected. Keywords: Trace metals; Russian Arctic; Northeastern Siberia; Permafrost

  6. Hydrogeological modeling constraints provided by geophysical and geochemical mapping of a chlorinated ethenes plume in northern France

    Science.gov (United States)

    Razafindratsima, Stephen; Guérin, Roger; Bendjoudi, Hocine; de Marsily, Ghislain

    2014-09-01

    A methodological approach is described which combines geophysical and geochemical data to delineate the extent of a chlorinated ethenes plume in northern France; the methodology was used to calibrate a hydrogeological model of the contaminants' migration and degradation. The existence of strong reducing conditions in some parts of the aquifer is first determined by measuring in situ the redox potential and dissolved oxygen, dissolved ferrous iron and chloride concentrations. Electrical resistivity imaging and electromagnetic mapping, using the Slingram method, are then used to determine the shape of the pollutant plume. A decreasing empirical exponential relation between measured chloride concentrations in the water and aquifer electrical resistivity is observed; the resistivity formation factor calculated at a few points also shows a major contribution of chloride concentration in the resistivity of the saturated porous medium. MODFLOW software and MT3D99 first-order parent-daughter chain reaction and the RT3D aerobic-anaerobic model for tetrachloroethene (PCE)/trichloroethene (TCE) dechlorination are finally used for a first attempt at modeling the degradation of the chlorinated ethenes. After calibration, the distribution of the chlorinated ethenes and their degradation products simulated with the model approximately reflects the mean measured values in the observation wells, confirming the data-derived image of the plume.

  7. Natural background values for heavy metals in the sediments of a contaminated Northern Adriatic lagoon environment: a geochemical perspective

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    Covelli S.

    2013-04-01

    Full Text Available Major and trace elements were determined in 14 sediment cores collected from the Marano and Grado Lagoon (northern Adriatic sea. The lagoon is contaminated by several harmful priority substances, heavy metals included, and it has also been declared a “polluted site of national interest” (SIN mainly due to high Hg concentrations in sediments. Based on a normalization procedure involving predicted linear relationships for “metal vs Al” obtained from the core subsamples, background values for each metal were evaluated on a regional scale and according to the grain-size variability. Compared to Environmental Quality Standards reported in the Italian laws and regulations, the estimated background ranges show that bottom sediments are naturally “enriched” in some metals, such as Cr, Ni and Cd especially in sediments with a high percentage of the fine component. A correct evaluation on sediment quality status should be made on the basis of regional background values for each metal, taking into account local geochemical characteristics, i.e. mineralogical composition and grain-size variability of sediments.

  8. Patterns and variability in geochemical signatures and microbial activity within and between diverse cold seep habitats along the lower continental slope, Northern Gulf of Mexico

    Science.gov (United States)

    Bowles, Marshall; Hunter, Kimberley S.; Samarkin, Vladimir; Joye, Samantha

    2016-07-01

    We collected 69 sediment cores from distinct ecological and geological settings along the deep slope in the Northern Gulf of Mexico to evaluate whether specific geochemical- or habitat-related factors correlated with rates of microbial processes and geochemical signatures. By collecting replicate cores from distinct habitats across multiple sites, we illustrate and quantify the heterogeneity of cold seep geochemistry and microbial activity. These data also document the factors driving unique aspects of the geochemistry of deep slope gas, oil and brine seeps. Surprisingly little variation was observed between replicate (n=2-5) cores within sites for most analytes (except methane), implying that the common practice of collecting one core for geochemical analysis can capture the signature of a habitat in most cases. Depth-integrated concentrations of methane, dissolved inorganic carbon (DIC), and calcium were the predominant geochemical factors that correlated with a site's ecological or geological settings. Pore fluid methane concentration was related to the phosphate and DIC concentration, as well as to rates of sulfate reduction. While distinctions between seep habitats were identified from geochemical signatures, habitat specific geochemistry varied little across sites. The relative concentration of dissolved inorganic nitrogen versus phosphorus suggests that phosphorus availability limits biomass production at cold seeps. Correlations between calcium, chloride, and phosphate concentrations were indicative of brine-associated phosphate transport, suggesting that in addition to the co-migration of methane, dissolved organic carbon, and ammonium with brine, phosphate delivery is also associated with brine advection.

  9. A geochemical study of lithospheric mantle beneath Northern Victoria Land (Antarctica): main evidences from volatile content in ultramafic xenoliths

    Science.gov (United States)

    Correale, Alessandra; Pelorosso, Beatrice; Rizzo, Andrea Luca; Coltorti, Massimo; Italiano, Francesco; Bonadiman, Costanza

    2017-04-01

    A geochemical study of ultramafic xenoliths from Northern Victoria Land (Green Point, GP and Handler Ridge, HR), is carried out in order to investigate the features of the lithosphere mantle beneath the Western Antarctic Ridge System (WARS). The majority of samples is spinel anhydrous lherzolite with rare presence of secondary phases (secondary cpx and glass). Geothermobarometric calculations, based on the Fe/Mg distribution among the peridotite minerals reveal that Sub Continental Lithospheric Mantle (SCLM) beneath Handler Ridge records temperatures and redox conditions higher then Greene Point (P fixed at 15 Kbar). Moreover, geochemical models evidence that, GP mantle domain represents a residuum after ˜7 to 21 % of partial melting in the spinel stability field, which was variably affected by interaction with infiltrating melts, acting in different times, from at least Jurassic to Cenozoic (Pelorosso et al., 2016). Fluid inclusions (FI) entrapped in olivine and pyroxene crystals were investigated for elemental and isotopic contents of both, noble gases (He, Ne, Ar) and CO2. He, Ar and Ne concentrations range from 1.52×10-14 to 1.07×10-12, from 4.09×10-13 to 3.47×10-11and from 2.84×10-16 to 7.57×10-14 mol/g, respectively, while the CO2amounts are between 7.08×10-10 and 8.12×10-7 mol/g. The 3He/4He varies between 5.95 and 20.18 Ra (where Ra is the 3He/4He ratio of air), being the lowest and the highest values measured in the He-poorer samples. Post-eruptive input of cosmogenic 3He and radiogenic 4He seems to influence mainly the samples associated to a lower He concentrations, increasing and decreasing respectively their primordial 3He/4He values, that for all the other samples range between 6.76 and 7.45 Ra. This range reasonably reflects the isotope signature of mantle beneath the investigated areas. The 4He/40Ar* ratio corrected for atmospheric-derived contamination ranges between 0.004 and 0.39. The lowest 4He/40Ar* values (4He/40Ar*Land lithospheric

  10. Transition of microbiological and sedimentological features associated with the geochemical gradient in a travertine mound in northern Sumatra, Indonesia

    Science.gov (United States)

    Sugihara, Chiya; Yanagawa, Katsunori; Okumura, Tomoyo; Takashima, Chizuru; Harijoko, Agung; Kano, Akihiro

    2016-08-01

    Modern travertines, carbonate deposits in Ca-rich hydrothermal water with high pCO2, often display a changing environment along the water path, with corresponding variability in the microbial communities. We investigated a travertine-bearing hot spring at the Blue Pool in northern Sumatra, Indonesia. The thermal water of 62 °C with high H2S (200 μM) and pCO2 ( 1 atm) developed a travertine mound 70 m wide. The concentrations of the gas components H2S and CO2, decrease immediately after the water is discharged, while the dissolved oxygen, pH, and aragonite saturation increase in the downstream direction. Responding to the geochemical gradient in the water, the surface biofilms change color from white to pink, light-green, dark-green, and brown as the water flows from the vent; this corresponds to microbial communities characterized by chemolithoautotrophs (Halothiobacillaceae), purple sulfur bacteria (Chromatiaceae), Anaerolineaceae, and co-occurrence of green non-sulfur bacteria (Chloroflexales)-Cyanobacteria, and green sulfur bacteria (Chlorobiales), respectively. In an environment with a certain level of H2S (> 1 μM), sulfur digestion and anoxygenic photosynthesis can be more profitable than oxygenic photosynthesis by Cyanobacteria. The precipitated carbonate mineral consists of aragonite and calcite, with the proportion of aragonite increasing downstream due to the larger Mg2 +/Ca2 + ratio in the water or the development of thicker biofilm. Where the biofilm is well developed, the aragonite travertines often exhibit laminated structures that were likely associated with the daily metabolism of these bacteria. The microbiological and sedimentological features at the Blue Pool may be the modern analogs of geomicrobiological products in the early Earth. Biofilm of anoxygenic photosynthetic bacteria had the potential to form ancient stromatolites that existed before the appearance of cyanobacteria.

  11. Cross-correlation analysis of 2012-2014 seismic events in Central-Northern Italy: insights from the geochemical monitoring network of Tuscany

    Science.gov (United States)

    Pierotti, Lisa; Facca, Gianluca; Gherardi, Fabrizio

    2015-04-01

    Since late 2002, a geochemical monitoring network is operating in Tuscany, Central Italy, to collect data and possibly identify geochemical anomalies that characteristically occur before regionally significant (i.e. with magnitude > 3) seismic events. The network currently consists of 6 stations located in areas already investigated in detail for their geological setting, hydrogeological and geochemical background and boundary conditions. All these stations are equipped for remote, continuous monitoring of selected physicochemical parameters (temperature, pH, redox potential, electrical conductivity), and dissolved concentrations of CO2 and CH4. Additional information are obtained through in situ discrete monitoring. Field surveys are periodically performed to guarantee maintenance and performance control of the sensors of the automatic stations, and to collect water samples for the determination of the chemical and stable isotope composition of all the springs investigated for seismic precursors. Geochemical continuous signals are numerically processed to remove outliers, monitoring errors and aseismic effects from seasonal and climatic fluctuations. The elaboration of smoothed, long-term time series (more than 200000 data available today for each station) allows for a relatively accurate definition of geochemical background values. Geochemical values out of the two-sigma relative standard deviation domain are inspected as possible indicators of physicochemical changes related to regional seismic activity. Starting on November 2011, four stations of the Tuscany network located in two separate mountainous areas of Northern Apennines separating Tuscany from Emilia-Romagna region (Equi Terme and Gallicano), and Tuscany from Emilia-Romagna and Umbria regions (Vicchio and Caprese Michelangelo), started to register anomalous values in pH and CO2 partial pressure (PCO2). Cross-correlation analysis indicates an apparent relationship between the most important seismic

  12. Geodynamic evolution of the Sabzevar zone, northern central Iranian micro-continent

    Science.gov (United States)

    Omrani, Hadi; Moazzen, Mohssen; Oberhänsli, Roland

    2018-02-01

    The Northern Central Iranian Micro-continent (CIM) represents Neotethys-related oceanic crust remnants, emplaced due to convergence between CIM and Eurasia plates during Eocene. Mafic and ultramafic units are exposed along the northern part of the CIM in the Sabzevar area. The geology and field relation of Sabzevar ophiolite indicate northward subduction of the Sabzevar basin. The average whole rock chemistry of mafic (gabbros) and ultramafic samples (lherzolite, harzburgite and dunite) is characterized by a range of MgO of 11.16-31.88, CaO 5.22-11.53 and Al2O3 2.77-14.57, respectively. Low LREE/HREE ratio of ultramafic samples is accompanied by enrichment of large ion lithophile elements (LILE) such as Sr, Pb and K. Mafic samples show two distinct groups with low and high LREE/HREE ratios. The spider diagram of mafic samples indicates enrichment in Sr, Pb and K and depletion in REE. Petrological and geochemical evidence and field relations show that the mafic rocks formed in a supra-subduction zone setting. Petrological studies reveal the role of fractional crystallization and assimilation effect by released fluids during subduction related generation of the Sabzevar mafic rocks. We suggest that the studied mafic rocks likely represent the basement of an initial island arc, which was generated in a supra-subduction zone setting within the Neotethys branch of the Sabzevar Ocean at the north of CIM. Copper, gold and chromite mineralizations are studied in relation to island arc setting and supra-subduction environment. Similarities in lithology, ophiolite age and mineralization between Sabzevar ophiolite and Bardaskan-Torbat Heydariyeh ophiolites testify for their separation due to rotation (or faulting) of the Central Iranian Micro-continent.

  13. Detrital zircon provenance analysis in the Zagros Orogen, SW Iran: implications for the amalgamation history of the Neo-Tethys

    Science.gov (United States)

    Zhang, Zhiyong; Xiao, Wenjiao; Majidifard, Mahmoud Reza; Zhu, Rixiang; Wan, Bo; Ao, Songjian; Chen, Ling; Rezaeian, Mahnaz; Esmaeili, Rasoul

    2017-06-01

    The Zagros Orogen developed as a result of Arabia-Eurasia collision. New in situ detrital zircon U-Pb and Hf isotopic analyses from a Cenozoic sedimentary sequence in SW Iran are used to unravel the amalgamation history of Neo-Tethys. Data indicate that: (1) Paleocene and Eocene strata (58 and 45 Ma, respectively) were sourced from obducted ophiolite and Triassic volcanics, (2) Lower Miocene ( 18 Ma) strata indicate mixed provenance from obducted ophiolite and Iranian magmatic rocks, (3) Mid to Upper Miocene sediments ( 14 to 11.2 Ma) were mainly sourced from Sanandaj-Sirjan zone granitoids to the north, and (4) Lower Pliocene ( 5 Ma) sediments mainly show Arabian age characteristics, with a minor Eurasian affinity component. Two hypotheses are outlined to highlight the key events: Hypothesis A, previously published by several workers, suggests that the sequence studied lay on the Arabia passive margin and that initial collision occurred prior to 18 Ma; Hypothesis B, modified from the Makran model, which is here preferred, suggests that Paleogene to Upper Miocene sediments were sourced from the northern Neo-Tethyan accretionary complex or Eurasia, and carry no input from Arabia, whereas the Lower Pliocene sample shows a mixed provenance from both Arabia and Eurasia, suggesting that collision occurred between 11.2 and 5 Ma.

  14. Foraminiferal-based paleobiogeographic reconstructions in the Carboniferous of Iran and its implications for the Neo-Tethys opening time: a synthesis

    International Nuclear Information System (INIS)

    Arefifard, S.

    2017-01-01

    The biogeographic distribution of foraminifers and their belonging to either the southern or northern margins of the Paleo-Tethys are used here for paleogeographic reconstructions of Iran during the Carboniferous. Lower Carboniferous foraminiferal assemblages from northern and central Iran show a cosmopolitan character and affinities to both the southern and northern borders of the Paleo-Tethys. Hence, in the Early Carboniferous Iran occupied an intermediate southern latitude position, forming part of Gondwana. This conclusion is consistent with the Late Ordovician to Early Carboniferous drift history of Iran based on paleomagnetic data. In the Late Carboniferous, the foraminiferal affinities of northern and central Iran with the northern part of Paleo-Tethys suggest that Iran separated from Gondwana and moved northwards to a lower latitude. This separation is also evidenced by the Upper Carboniferous coal-bearing sandstones of the Sardar Formation and sandstones with high degree of chemical weathering, which would indicate warm and humid conditions. Considering the composition of foraminiferal fauna along with the evidence of magmatic activities in northwest Iran, it can be inferred that the commencement of the Neo-Tethys opening and continental break-up in Iran occurred sometime in the Late Carboniferous, which contradicts the previous claims that the separation of Iran from Gondwana occurred in Permian and/or Triassic times.

  15. Foraminiferal-based paleobiogeographic reconstructions in the Carboniferous of Iran and its implications for the Neo-Tethys opening time: a synthesis

    Energy Technology Data Exchange (ETDEWEB)

    Arefifard, S.

    2017-11-01

    The biogeographic distribution of foraminifers and their belonging to either the southern or northern margins of the Paleo-Tethys are used here for paleogeographic reconstructions of Iran during the Carboniferous. Lower Carboniferous foraminiferal assemblages from northern and central Iran show a cosmopolitan character and affinities to both the southern and northern borders of the Paleo-Tethys. Hence, in the Early Carboniferous Iran occupied an intermediate southern latitude position, forming part of Gondwana. This conclusion is consistent with the Late Ordovician to Early Carboniferous drift history of Iran based on paleomagnetic data. In the Late Carboniferous, the foraminiferal affinities of northern and central Iran with the northern part of Paleo-Tethys suggest that Iran separated from Gondwana and moved northwards to a lower latitude. This separation is also evidenced by the Upper Carboniferous coal-bearing sandstones of the Sardar Formation and sandstones with high degree of chemical weathering, which would indicate warm and humid conditions. Considering the composition of foraminiferal fauna along with the evidence of magmatic activities in northwest Iran, it can be inferred that the commencement of the Neo-Tethys opening and continental break-up in Iran occurred sometime in the Late Carboniferous, which contradicts the previous claims that the separation of Iran from Gondwana occurred in Permian and/or Triassic times.

  16. The Pushtashan juvenile suprasubduction zone assemblage of Kurdistan (northeastern Iraq: A Cretaceous (Cenomanian Neo-Tethys missing link

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    Sabah A. Ismail

    2017-09-01

    Full Text Available The Pushtashan suprasubduction zone assemblage of volcanic rocks, gabbros, norites and peridotites occurs in the Zagros suture zone, Kurdistan region, northeastern Iraq. Volcanic rocks are dominant in the assemblage and consist mainly of basalt and basaltic andesite flows with interlayered red shale and limestone horizons. Earlier lavas tend to be MORB-like, whereas later lavas display island arc tholeiite to boninitic geochemical characteristics. Tholeiitic gabbros intrude the norites and display fractionation trends typical of crystallisation under low-pressure conditions, whereas the norites display calc-alkaline traits, suggesting their source included mantle metasomatised by fluids released from subducted oceanic crust. Enrichment of Rb, Ba, Sr, Th and the presence of negative Nb anomalies indicate generation in a suprasubduction zone setting. Trondhjemite and granodiorite intrusions are present in the volcanic rocks, gabbros and norites. SHRIMP U-Pb dating of magmatic zircons from a granodiorite yields a mean 206Pb/238U age of 96.0 ± 2.0 Ma (Cenomanian. The initial ɛHf value for the zircons show a narrow range from +12.8 to +15.6, with a weighted mean of +13.90 ± 0.96. This initial value is within error of model depleted mantle at 96 Ma or slightly below that, in the field of arc rocks with minimal contamination by older continental crust. The compositional bimodality of the Pushtashan suprasubduction sequence suggests seafloor spreading during the initiation of subduction, with a lava stratigraphy from early-erupted MORB transitioning into calc-alkaline lavas and finally by 96 Ma intrusion of granodioritic and trondhjemitic bodies with juvenile crustal isotopic signatures. The results confirm another Cretaceous arc remnant preserved as an allochthon within the Iraqi segment of the Cenozoic Zagros suture zone. Implications for the closure of Neo-Tethys are discussed.

  17. Geochemical, mineralogical and Re-Os isotopic constraints on the origin of Tethyan oceanic mantle and crustal rocks from the Central Pontides, northern Turkey

    Science.gov (United States)

    Çelik, Ömer Faruk; Marzoli, Andrea; Marschik, Robert; Chiaradia, Massimo; Mathur, Ryan

    2018-02-01

    Chromite, ultramafic and mafic rocks from Eldivan, Yapraklı, Ayli Dağ, Küre, Elekdağ and Kızılırmak in northern Turkey have been studied to determine their mineral and whole-rock geochemical, and Re-Os isotope geochemical characteristics. Most of the studied peridotites display depleted but commonly V-shaped chondrite-normalized rare-earth element (REE) patterns while some peridotites as well as pyroxenites from all areas exhibit light REE depleted patterns. Olivine (forsterite 82 to 92 mol%) and spinel (chromium number 13 to 63) in the studied peridotites exhibit a wide range of compositions. Compositions of spinels suggest that peridotites from Eldivan, Ayli Dağ and Küre experienced relatively large degrees of partial melting ( 15 and 19 wt%), whereas those of the Kızılırmak area most likely reflect lower melting degrees ( 4-6 wt%). Whole-rock and mineral chemical data indicate that the ultramafic rocks are similar to abyssal and supra-subduction zone peridotites. The ultramafic rocks of the investigated areas exhibit a wide range of 187Re/188Os (0.12 to 6.6) and measured 187Os/188Os (0.122-1.14), while the basaltic rocks from Küre, Eldivan and Kızılırmak areas have high 187Re/188Os (128-562) and measured 187Os/188Os (0.724-1.943). On the other hand, chromite from Eldivan, Elekdağ and Kızılırmak show high Os contents (21.81-44.04 ppb) and low 187Re/188Os (0.015-0.818) and 187Os/188Os (0.122-0.133). Re-Os model ages (TChur) for all analyzed samples yielded scattered ages ranging from Jurassic to Proterozoic. Overall, geochemical data are interpreted to reflect different degrees of partial melting, melt - rock interactions and metasomatic effects that produced a heterogeneous mantle in a supra-subduction setting.

  18. Gas discharges from four remote volcanoes in northern Chile (Putana, Olca, Irruputuncu and Alitar): a geochemical survey

    OpenAIRE

    Thomas Darrah; Orlando Vaselli; Felipe Aguilera; Franco Tassi; Eduardo Medina

    2011-01-01

    We analyzed gas samples collected from fumaroles and bubbling pools at Irruputuncu, Putana, Olca and Alitar volcanoes located in the central Andes volcanic zone (northern Chile). The Irruputuncu and Putana fumarolic discharges showed outlet temperatures ranging from 83 ˚C to 240 ˚C and from 82 ˚C to 88 ˚C, respectively. The chemical and isotopic (3He/4He, d13C-CO2, d18O-H2O and dD-H2O) compositions of these discharges were similar to medium-to-high temperature volcanic gases from other active...

  19. Two contrasting modes of continental break-up associated with the formation of the Paleo- and Neo-Tethys in Iran: Implications for petrological and geodynamic evolution at a regional scale

    Science.gov (United States)

    Saccani, Emilio; Marroni, Michele; Pandolfi, Luca; Allahyari, Khalil; Azimzadeh, Zohreh

    2014-05-01

    contrast with the Ligurian Tethys model, the Neo-Tethys rift stage was also associated with volcanism featuring a marked influence of plume-type components. Nonetheless, no geological evidence (e.g. regional doming, anomalous thermal regime, basaltic plateaux, magmatic evolution from more depleted to more enriched rocks, etc.) supporting the existence of a Triassic mantle plume activity in this area has been documented. Therefore, the plume-type geochemical signature observed in the Kermanshah CMO sequences can likely be explained with the re-activation of portions of enriched mantle (mantle heterogeneities) that were inherited from the Paleozoic mantle plume associated with the opening of Paleo-Tethys.

  20. Geochemical and biomarker characteristics of crude oils and source rock hydrocarbon extracts: An implication to their correlation, depositional environment and maturation in the Northern Western Desert, Egypt

    Directory of Open Access Journals (Sweden)

    Mohamed M. El Nady

    2016-06-01

    Full Text Available Oil–oil and oil–source rock correlations are used in this study in order to achieve their relationship, depositional environments and diagenetic processes in the source rocks. Three oil samples and source rock hydrocarbon extracts were analyzed using relative geochemical analyses, and gas chromatography–mass spectrometry are used for this purpose. The results revealed that the extracts of the Alam El Bueib and Khatatba formations are derived from mixed organic sources in which terrestrial dominates marine sources, and deposited in transitional environments under less anoxic conditions. The extracts of Bahariya formation are derived from mixed marine inputs with a limited terrestrial contribution. The Alam El Bueib oil shows more contribution of terrestrial than marine sources. Also, a genetic close relation between them supported the indigenous mixed source of Alam El Bueib oil which related to different sources including the Khatatba, Alam El Bueib and Bahariya formations. Accordingly, the Alam El Bueib formation can be considered as an important source for petroleum generation in the Northern Western Desert.

  1. Geochemical significance of neoproterozoic rasimalai alkali syenite emplaced along Dharmapuri shear zone in the Northern part of Tamil Nadu

    International Nuclear Information System (INIS)

    Thangavel, S.; Balasubramani, S.; Nagaraju, M.; Bhattacharya, D.; Zakaulla, Syed; Rai, A.K.

    2015-01-01

    The Rasimalai alkali syenite complex is emplaced within Peninsular Gneissic complex and spatially associated with NE-SW trending major Dharmapuri shear zone (DSZ) in the northern part of Tamil Nadu. It is surrounded by epidote hornblend egneiss, which is the fenetised product of Charnockite and occurs about 20 km NE of Alangayam in Vellore district. It is mainly comprised of medium to coarse grained grey syenite (albite and orthoclase) and medium to micro grained pink syenite (orthoclase, microcline and perthite) at places porphyritic in nature with hornblende, riebeckitc, aegirine and acmite as accessory minerals. Grey syenite is non radioactive and uranium mineralisation is associated with pink syenite (syngenetic and disseminated type) and quartz-barite veins (hydrothermal type). Hydrothermal activity is manifested in the form of pyrite, chalcopyrite, galena, barite, calcite and calcian-strontianite which occur in the form of disseminations, stringers, lumps, aggregates, veinlets and veins. Presence of high silica (63.14-75.43%) with high field strength elements (U, Th, Nb and Pb) and large ion lithophile elements (Rb, Sr, K, Ba) possibly indicates that Rasimalai alkali syenite is the product of crustal communication and partial melting of protracted emplacement of parental alkali basaltic magma

  2. An organic geochemical multi-proxy study of the Paleocene-Eocene Thermal Maximum: Evidence from northern Spain

    Science.gov (United States)

    Manners, H. R.; Grimes, S.; Sutton, P.; Domingo, L.; Pancost, R. D.; Leng, M. J.; Twitchett, R. J.; Hart, M. B.; Taylor, K. W.

    2012-12-01

    The Paleocene - Eocene Thermal Maximum (PETM), a hyperthermal event that occurred ca. 56 Ma, has been attributed to the release of substantial amounts of isotopically light carbon, affecting the atmosphere, biosphere, and hydrosphere. Debate concerning the amount, duration and mechanism(s) of carbon release are topical, with the magnitude and profile of the Carbon Isotope Excursion (CIE) associated with this event proving pivotal as different records occur globally. Continental records generally record a higher CIE magnitude than marine records (continental δ13C 6 - 8‰, marine δ13C 2.5 - 4‰)1,2,3. This difference was recently proposed to be due to a change in plant communities from mixed angiosperm (flowering plants)/gymnosperm (evergreen plants) flora to a predominantly angiosperm flora4,5, believed to be coincident with the onset of the PETM, indicating that the continental realm may be recording an artificially large CIE due to a change in the plant isotopic fractionation pathway. High resolution organic carbon isotope profiles (δ13CTOC) of six PETM sections in northern Spain are presented that span a transect from continental (Claret, Tendrui, and Esplugafreda sections) to marine (Campo, Zumaia, and Ermua sections) environments. These data represent the highest resolution δ13CTOC records for these sections, and allow for comparison of the magnitude, profile shape, and relative timing of the onset of the CIE across a linked sediment routing system. Results indicate that no systematic variation in the magnitude of the CIE is recorded between the continental and marine realms, and profile shape varies across the sections, adding further data to debates around the rate and timing of the PETM carbon release and the mode and rapidity of carbon drawdown during the recovery phase. The continental section of Claret and the marine section of Zumaia have been further compared using δ13C values of higher plant-derived n-alkanes to further constrain the magnitude

  3. Geochemical evidence for Paleozoic crustal growth and tectonic conversion in the Northern Beishan Orogenic Belt, southern Central Asian Orogenic Belt

    Science.gov (United States)

    Yuan, Yu; Zong, Keqing; He, Zhenyu; Klemd, Reiner; Jiang, Hongying; Zhang, Wen; Liu, Yongsheng; Hu, Zhaochu; Zhang, Zeming

    2018-03-01

    The Beishan Orogenic Belt is located in the central southernmost part of the Central Asian Orogenic Belt (CAOB), which plays a key role in understanding the formation and evolution of the CAOB. Granitoids are the documents of crustal and tectonic evolution in orogenic belts. However, little is known regarding the petrogenesis and geodynamic setting of the widely distributed Paleozoic granitoids in the Northern Beishan Orogenic Belt (NBOB). The present study reveals significant differences concerning the petrogenesis and tectonic setting of early and late Paleozoic granitoids from the NBOB. The early Paleozoic granitoids from the 446-430 Ma Hongliuxia granite complex of the Mazongshan unit and the 466-428 Ma Shibanjing complex of the Hanshan unit show classic I-type granite affinities as revealed by the relative enrichment of LILEs and LREEs, pronounced depletions of Nb, Ta and Ti and the abundant presence of hornblende. Furthermore, they are characterized by strongly variable zircon εHf(t) values between - 16.7 and + 12.8 and evolved plagioclase Sr isotopic compositions of 0.7145-0.7253, indicating the involvement of both juvenile and ancient continental crust in the magma source. Thus, we propose that the early Paleozoic granitoids in the NBOB were generated in a subduction-related continental arc setting. In contrast, the late Paleozoic 330-281 Ma granitoids from the Shuangjingzi complex of the Hanshan unit exhibit positive zircon εHf(t) values between + 5.8 and + 13.2 and relatively depleted plagioclase Sr isotopic compositions of 0.7037-0.7072, indicating that they were mainly formed by remelting of juvenile crust. Thus, an intra-plate extensional setting is proposed to have occurred during formation of the late Paleozoic granitoids. Therefore, between the early and late Paleozoic, the magma sources of the NBOB granitoids converted from the reworking of both juvenile and ancient crusts during a subduction-induced compressional setting to the remelting of

  4. Field and geochemical constraints on the relationship between the Apoteri basalts (northern Brazil, southwestern Guyana) and the Central Atlantic Magmatic Province

    Science.gov (United States)

    Pinto, Viter M.; Santos, João Orestes S.; Ronchi, Luiz H.; Hartmann, Léo A.; Bicudo, Carlos Alberto; de Souza, Vladimir

    2017-11-01

    In northern Brazil, Roraima state and southwestern Guyana, basalt flows characterized by inflated pahoehoe structure occur along the margins of the Tacutu Rift Valley, dykes intrude the Paleoproterozoic basement close to the boundary of the rift system with concordant, NE-trend. The dykes and flows belong to Apoteri magmatism. New field, geochemical data (major, trace and rare-earth elements) and chemical stratigraphy of the Apoteri magmatism indicate petrographic and chemical homogeneity characteristic of continental tholeiitic basalts. The basalt flows of Morro Redondo and Nova Olinda sites show two distinct chemical groups: a) the lower flows with intermediate TiO2 content (ITi group) ranging from 1.09 to 1.41 wt%, MgO (5.64-6.46 wt%) and Ni (43-53 ppm) contents; and b) the upper flows with lower TiO2 content (LTi group) = 0.75 to 0.78 wt%, higher MgO = 7.95-8.85 wt% and Ni = 105-115 ppm. The two magma types share many characteristics in high field strength elements (HFSE) and rare earth elements (REE), but in detail significant differences exist in REE ratios, e.g. (La/Yb)N of ∼4.0 for ITi and 3.2 for LTi and this may be explained by fractional crystallization. The chemical compositions of the Apoteri dykes are similar the ITi group analyses, suggesting that they have the same origin. The La/Ba versus La/Nb diagram is indicative of large ion lithophile elements (LILE) enrichment and LILE/HFSE fractionation in the mantle source, and the data favor a dominant subcontinental lithospheric mantle (SCLM) component in the origin of the Apoteri flows and dykes. These data show consistent similar chemical characteristics and correspond to other tholeiitic flows from the large Central Atlantic Magmatic Province (CAMP), especially eastern USA.

  5. Stream sediments analysis for geochemical mapping of Romagna Apennines (Northern Italy): monitoring and management tool of environmental resources at various scales

    OpenAIRE

    Lancianese, Valerio

    2014-01-01

    Geochemical mapping is a valuable tool for the control of territory that can be used not only in the identification of mineral resources and geological, agricultural and forestry studies but also in the monitoring of natural resources by giving solutions to environmental and economic problems. Stream sediments are widely used in the sampling campaigns carried out by the world's governments and research groups for their characteristics of broad representativeness of rocks and soils, for ease o...

  6. Zagros Geodynamics, From Subduction to Collision: The Fate of the Neotethys

    Science.gov (United States)

    Omrani, J.; Agard, P.; Jolivet, L.; Whitechurch, H.; Monié, P.

    2008-12-01

    The Zagros orogen preserves the record of three main periods/regimes in the convergence history of the Neotethys: (1) Long-lasting subduction processes and arc magmatism (>150-35 Ma). Trace and rare-earth element systematics on the upper plate Sanandaj-Sirjan and Urumieh-Dokhtar magmatic arcs show that they originated from similar, subduction-related mantle sources. The inward shift of arc magmatism (~300 km) from the former to the latter at the end of the Tertiary likely resulted from a change in kinematics and was predated by the formation of the Paleocene-Eocene intraoceanic arc of Kermanshah (earlier thought to represent a remnant of the Peri-Arabic obduction). Oceanic subduction proper ended by 35-30 Ma and was followed by collision. (2) A distinctive period of pertubation of subduction processes (115-85 Ma). A sharp rise of convergence velocities across the Neotethys at ~115 Ma was followed by two regional- scale (i.e., > 3000 km along strike), coeval (~100-80 Ma), short-lived major tectonic phenomena: - the transient exhumation of oceanic blueschists all along the Neotethyan subduction zone, which testifies to a change in plate-slab coupling, - the development of intra-oceanic subduction ultimately leading to the obduction of oceanic crust onto Arabia. (3) Collision and slab tear at depths (~25-0 Ma). Collision started before ~25-23 Ma (in Lorestan) and resulted in 70 km of shortening in the internal zones alone over the last 20-15 My. Calc-alkaline magmatism resumed in the Urumieh-Dokhtar magmatic arc after collision, mainly from the Mio-Pliocene onwards. In Central Zagros this syn-collision magmatism shows a distinctive adakitic trend attributable to the melting at depths of mafic material in response to localized slab breakoff (i.e. 200-300 km along strike), as further supported by tomography. The timing of this event is thus broadly coeval with slab-breakoff below southern Turkey and supports the view that slab tearing propagated in the Neotethyan slab

  7. A geochemical and geophysical approach to derive a conceptual circulation model of CO2-rich mineral waters: A case study of Vilarelho da Raia, northern Portugal

    Science.gov (United States)

    Marques, J. M.; Santos, Monteiro; Graça, R. C.; Castro, R.; Aires-Barros, L.; Mendes Victor, L. A.

    2001-11-01

    The Vilarelho da Raia-Chaves region, located in northern Portugal adjacent to the Spanish border, is characterized by both hot and cold CO2-rich mineral waters issuing from springs and drilled wells. The present paper updates the conceptual circulation model of the Vilarelho da Raia cold CO2-rich mineral waters. Vilarelho da Raia mineral waters, dominated by Na and HCO3 ions, have formed mainly by interaction with CO2 of deep-seated mantle origin. The δ18O, δ2H and 3H values indicate that these waters are the result of meteoric waters infiltrating into Larouco Mountain, NW of Vilarelho da Raia, circulating at shallow depths in granitic rocks and moving into Vilarelho da Raia area. The conceptual geochemical and geophysical circulation model indicates that the hot and cold CO2-rich mineral waters of Chaves (76 °C) and Vilarelho da Raia (17 °C) should be considered manifestations of similar but not the same geohydrological systems. Résumé. La région de Vilarelho da Raia - Chaves, située au Portugal près de la frontière Espagnole, est caractérisée par des eaux carbogazeuses, chaudes et froides, émergeant à des sources et dans des puits. Ce travail constitue une mise au point du modèle conceptuel de circulation des eaux minérales carbogazeuses froides de Vilarelho da Raia. Les eaux minérales de Vilarelho da Raia, dans lesquelles les ions Na and HCO3 sont dominants, résultent principalement d'interactions avec du CO2 d'origine mantellique. Les δ18O, les δ2H, et les teneurs en 3H indiquent que ces eaux proviennent de l'infiltration d'eaux météoriques dans le Mont Larouco au NW de Vilarelho da Raia, circulant à faible profondeur dans les granites en direction de la région de Vilarelho da Raia. Le modèle de circulation géochimique et géophysique conduit à penser que les eaux minérales carbogazeuses chaudes et froides de Chaves (76 °C) et de Vilarelho da Raia (17 °C) doivent être considérées comme des manifestations de systèmes hydrog

  8. REEs geochemical characteristics of lower Cambrian phosphatic rocks in the Gorgan-Rasht Zone, northern Iran: Implications for diagenetic effects and depositional conditions

    Science.gov (United States)

    Abedini, Ali; Calagari, Ali Asghar

    2017-11-01

    The phosphatic rocks in the Gorgan-Rasht structural Zone (north of Iran) are widely developed within the Soltanieh Formation of Upper Neoproterozoic-Lower Cambrian age. These rocks extend in length over 60 km, vary in thickness from 2.2 m to 5 m, and lie along the boundary of the Middle Dolomite and the Upper Shale members (Lower Cambrian) of the Soltanieh Formation. In this research, the geochemical characteristics of 16 phosphatic samples using rare earth elements (REEs) within a section in the Soltanieh Formation were investigated. The entire phosphatic samples show characteristically typical hat-shaped distribution patterns of REEs, strong negative Ce anomalies (Ce/Ce* = 0.30-0.51), and slightly positive Eu anomalies (Eu/Eu* = 1.34-1.73). The geochemical evidence such as hat-shaped distribution patterns, MREEs enrichment relative to LREEs and HREEs, and values of Er/Nd, Y/Ho, La/Nd, and (La/Yb)N ratios together with positive correlation between pairs of Eu/Eu*-Ce/Ce* and REEs-Ce/Ce* and negative correlation between pair of (Dy/Sm)N-Ce/Ce* reveal the important role of diagenetic processes in the distribution and concentration of REEs in the phosphatic rocks. This study demonstrated that the strong negative Ce anomalies and weak positive Eu anomalies are valuable indicators for determining redox conditions of diagenetic fluids existing during the development of the phosphatic rocks, and also suggest upwelling and mixing of organic-rich anoxic bottom seawaters with aerobic oxic seawaters before the development and progression of phosphatization processes in the depositional site. The geochemical parameters like Y/Ho ratio and strong positive correlation between REEs-TOC suggest that terrigenous materials along with organic matters were the principal source of REEs in the phosphatic rocks.

  9. Mineralogical and geochemical constraints on the genesis of the carbonate - Hosted Jebel Ghozlane Pb–Zn deposit, Nappe zone, Northern Tunisia

    NARCIS (Netherlands)

    Jemmali, Nejib; Souissi, Fouad; Carranza, E.J.M; Vennemann, Torsten W.

    2013-01-01

    The Pb–Zn deposit at Jebel Ghozlane, in the Nappe zone (northern Tunisia), is hosted by Triassic dolostones and Eocene limestones and is located along faults and a thrust-sheet boundary. The sulfide mineralization of the deposit consists mainly of galena and sphalerite and occurs as vein, stockwork,

  10. Diachronous demise of the Neotethys Ocean as driver for non-cylindrical orogenesis in Anatolia

    Science.gov (United States)

    Van Hinsbergen, D. J. J.; Gurer, D.

    2017-12-01

    Continent-continent collision drives crustal deformation, topographic rise, and geodynamic change. Africa-Eurasia convergence accommodated in the Eastern Mediterranean involved subduction of the Neotethyan oceanic lithosphere in Anatolia. Subduction was followed by collision of Greater Adria continental crust with Eurasia forming the Izmir-Ankara-Erzincan suture zone. Discerning the effects of this collision from pre-collisional ophiolite obduction-related orogeny of Greater Adria is notoriously difficult, and estimates from Central Anatolia based on a forearc-to-foreland basin transition along the Eurasian margin suggest a 60 Ma initial collision. Here we assess whether this age is also representative for collision in eastern Anatolia across the Cenozoic Sivas basin that straddles the Greater Adria-Europe suture by retro-deforming regional block rotations in the Pontides, Kırşehir and Taurides, building a first-order regional `block circuit' around the Sivas basin. We show that up to 700 km of convergence must have been accommodated after central Anatolian Kırşehir-Pontide collision at 65-60 Ma across the Sivas Basin - an order of magnitude more than estimated crustal shortening. We consequently infer that oceanic subduction continued much longer in eastern Anatolia, perhaps into the Oligocene or beyond, demonstrating the a recently postulated greater paleogeographic width of the Neotethys in eastern Anatolia. Prolonged oceanic subduction likely resulted from a paleogeography with a sharp kink in the former Kırşehir-Tauride passive margin. The strong non-cylindricity of the Anatolian collisional orogen is explained continued slab pull during ongoing oceanic subduction in eastern Anatolia following central Anatolian collision.

  11. SIMS U-Pb, Sm-Nd isotope and geochemical study of an arkosite-amphibolite suite, Peräpohja Schist Belt: evidence for ca. 1.98 Ga A-type felsic magmatism in northern Finland

    Directory of Open Access Journals (Sweden)

    Eero Hanski

    2005-01-01

    Full Text Available In the northern and north-eastern part of the Peräpohja Schist Belt, northern Finland, an extensive supracrustal rock unit has been identified which is composed of alternating amphibolitic and arkositic components. The amphibolites form layers whose thickness varies from one millimeter to some tens of meters, being most often a few tens of centimeters. They represent mafic tuff beds deposited concurrently with more abundant arkositic rocks. Most of the arkosites have a modal and major and trace element compositionsimilar to that of A2-type granites. For example, they exhibit high LREE/HREE, negative Eu anomalies, and flat HREE and are moderately enriched in Nb, Zr, and Y. The genesis of the arkosites is enigmatic as they show features supporting either a volcaniclastic or an epiclastic origin. In the latter case, they were derived via erosion of a source dominated by A2-type granitic rocks. Previous conventional ID-TIMS and new SIMS U-Pb dating of zircons from two arkosite samples and one mica schist sample, all three picked from the northern part of the schist belt, indicate that these rocks contain a single population of zircons with an age of ca. 1975 Ma suggesting that they are among the youngest supracrustal rocks in the schist belt. In contrast, one mica schist sample from the western part of the belt revealed only the presence of Archean zircons. The samples do not differ markedly in terms of their Nd isotopecomposition as they all have a moderately negative εNd(1900 Ma. Regardless of the genesis of the arkosites, their isotopic and geochemical data suggest a previously unknown occurrence of extensive A-type felsic magmatism at ca. 1.98 Ga, contemporaneously withsome continental flood basalts. However, concrete evidence for this felsic A-type magmatism in the form of ca. 1.98 Ga felsic plutonic rocks is virtually absent in the presently exposed Fennoscandian Shield.

  12. Reconstructing geochemical conditions during dolomite formation in a Carnian coastal sabkha using 87Sr/86Sr isotopes - Travenanzes Formation, northern Italy

    Science.gov (United States)

    Rieder, Maximilian; Wegner, Wencke; Horschinegg, Monika; Preto, Nereo; Breda, Anna; Klötzli, Urs; Peckmann, Jörn; Meister, Patrick

    2017-04-01

    The geochemical conditions that were conducive to primary dolomite formation in extremely shallow evaporitic environments along the Triassic Tethyan margin are still poorly understood. While the massive Triassic dolomites in the Austroalpine and South Alpine realm are largely affected by diagenetic or hydrothermal overprint, Preto et al. (2015) provide evidence of primary dolomite based on nano-crystal aggregates observed under the transmission electron microscope. These dolomites are intercalated in a 100-m-thick sequence of clay (Travenanzes Formation, Southern Alps), deposited on a semi-arid coastal plain in the Late Carnian (Tuvalian II). They may serve as a geochemical archive of evaporative brine composition at the time of dolomite formation. Petrographic and field observations revealed that dolomites occur as three different types, (1) dm- to m-thick homogenous beds, (2) mm-scale laminated (stromatolitic) beds and (3) nodules associated with root traces and palaeosols. In all types, the dolomite is stoichiometrically and structurally well ordered. While the homogeneous dolomites occasionally show a peloidal structure, all types of dolomite are generally microcrystalline. Soft sediment deformation, or brittle deformation with mud infill indicates that the dolomitic sediment was largely unlithified at the time of deposition. We analysed the dolomites under the SEM in backscatter mode and observed largely anhedral structures with grain sizes in the μm-range. The laminated dolomites consist of mm- to cm-scale clay-dolomite alternations, whereby the dolomite often shows a spherulitic growth near the dolomite-clay interface, where further recrystallization was inhibited. We measured strontium isotope ratios (87Sr/86Sr) as an indicator for the source of alkalinity driving dolomite precipitation. Our data are in a range between 0.707672 (homogenous dolomite) and 0.707976 (both 2σ: 4*10-5) (nodular dolomite) indicating a similar trend as in Triassic seawater during

  13. Geochemical gradients within modern and fossil shells of Concholepas concholepas from northern Chile: an insight into U-Th systematics and diagenetic/authigenic isotopic imprints in mollusk shells

    Science.gov (United States)

    Labonne, Maylis; Hillaire-Marcel, Claude

    2000-05-01

    Seriate geochemical measurements through shells of one modern, one Holocene, and two Sangamonian Concholepas concholepas, from marine terraces of Northern Chile, were performed to document diagenetic vs. authigenic geochemical signatures, and to better interpret U-series ages on such material. Subsamples were recovered by drilling from the outer calcitic layer to the inner aragonitic layer of each of the studied shells. Unfortunately, this sampling procedure induces artifacts, notably the convertion of up to ˜20% of calcite into aragonite, and of up to ˜6% of aragonite into calcite, as well as in the epimerization of a few percent of isoleucine into D-alloisoleucine/ L-isoleucine. Negligible sampling artifacts were noticed for stable isotope and total amino acid contents. Diagenetic effects on the geochemical properties of the shells are particularly pronounced in the inner aragonitic layer and more discrete in the outer calcitic layer. The time-dependent decay of the organic matrix of the shell is illustrated by a one order of magnitude lower total amino acid content in the Sangamonian specimens by comparison with the modern shell. Conversely, the Sangamonian shells U contents increase by a similar factor and 13C- 18O enrichments as high as 2 to 3‰ seem also to occur through the same time interval possibly due to partial replacement of aragonite by gypsum. The decay of the organic matrix of the aragonitic layer of the shell is thought to play a major role with respect to U-uptake processes and stable isotope shifts. Nevertheless, asymptotic 230Th-ages (˜100 ka) in the inner U-rich layers of the Sangamonian shells, and 234U/ 238U ratios compatible with a marine origin for U, suggest U-uptake within a short diagenetic interval, when marine waters were still bathing the embedding sediment. Thus, U-series ages on fossil mollusks from such a hyper-arid environment should not differ much from the age of the corresponding marine unit deposition. However, the

  14. The formation of auriferous quartz-sulfide veins in the Pataz region, northern Peru: A synthesis of geological, mineralogical, and geochemical data

    Science.gov (United States)

    Schreiber, D. W.; Amstutz, G. C.; Fontboté, L.

    1990-12-01

    The Pataz region in the eastern part of the North Peruvian Department La Libertad hosts a number of important gold mining districts like La Lima, El Tingo, Pataz, Parcoy, and Buldibuyo. Economic gold mineralization occurs in quartz-sulfide veins at the margin of the calc-alkaline Pataz Batholith, that mainly consists of granites, granodiorites, and monzodiorites. The batholith is of Paleozoic age and cuts the Precambrian to Early Paleozoic low-grade metamorphic basement series. Its intrusion was controlled by a NNW-trending fault of regional importance. The gold-bearing veins are characterized by a two-stage sulfide mineralization. Bodies of massive pyrite and some arsenopyrite were formed in stage 1, and after subsequent fracturing they served as sites for deposition of gold, electrum, galena, sphalerite, and chalcopyrite. It is concluded that gold was transported as a AuCl{2/-}-complex by oxidizing chloride solutions and deposited near older pyrite by micro-scale redox changes and a slight temperature decrease. Mineralogical, textural, geochemical, and microthermometric features are interpreted as a consequence of mineralization at considerable depth produced by a hydrothermal system linked with the emplacement of the Pataz Batholith. acteristics in order to outline a general physicochemical model of the hydrothermal ore-forming processes.

  15. Kinematics of a former oceanic plate of the Neotethys revealed by deformation in the Ulukışla basin (Turkey)

    NARCIS (Netherlands)

    Gürer, Derya; van Hinsbergen, Douwe J J; Matenco, Liviu; Corfu, Fernando; Cascella, Antonio

    2016-01-01

    Kinematic reconstruction of modern ocean basins shows that since Pangea breakup a vast area in the Neotethyan realm was lost to subduction. Here we develop a first-order methodology to reconstruct the kinematic history of the lost plates of the Neotethys, using records of subducted plates accreted

  16. Geochemical characterisation of Tithonian-Berriasian Chia Gara organic-rich rocks in northern Iraq with an emphasis on organic matter enrichment and the relationship to the bioproductivity and anoxia conditions

    Science.gov (United States)

    Mohialdeen, Ibrahim M. J.; Hakimi, Mohammed Hail

    2016-02-01

    Tithonian-Berriasian Chia Gara organic-rich rocks, located in Kurdistan (northern Iraq), were analysed based on inorganic and organic geochemistry to define the origin, type of organic matter, and the influencing factors of organic matter (OM) enrichment, including the OM input and preservation, and their relationship to the paleoenvironment conditions. The δ13Corg values of the Chia Gara rocks range from -29.99‰ to -26.93‰, with average values of approximately -28.8‰, indicating that the organic matter has a predominantly marine origin. Enhanced biological productivity within the photic zone of the water column during deposition of the Chia Gara Fm. is indicated by consistently high organic carbon content in most samples (average 3 wt.%), as well as by bulk geochemical and biomarker characteristics. Major contributions by aquatic algae and microorganisms with a minor terrigenous organic matter contribution are indicated by the n-alkane distribution patterns and the composition of the hopanoids, steroids, and tricyclic terpenoids. Strongly reducing bottom water is indicated by low pristane/phytane ratios, homohopane distribution patterns, and the redox-sensitive trace elements geochemistry. Salinity stratification with alkaline bottom waters is indicated by high Sr/Ba ratios and the presence of gammacerane in the analysed Chia Gara samples. These data indicate that OM enrichment in the Tithonian-Berriasian Chia Gara rocks results from the combination of enhanced biological productivity and salinity stratification with anoxic bottom water conditions, which favoured OM preservation.

  17. Enzyme leaching of surficial geochemical samples for detecting hydromorphic trace-element anomalies associated with precious-metal mineralized bedrock buried beneath glacial overburden in northern Minnesota

    Science.gov (United States)

    Clark, Robert J.; Meier, A.L.; Riddle, G.; ,

    1990-01-01

    One objective of the International Falls and Roseau, Minnesota, CUSMAP projects was to develop a means of conducting regional-scale geochemical surveys in areas where bedrock is buried beneath complex glacially derived overburden. Partial analysis of B-horizon soils offered hope for detecting subtle hydromorphic trace-element dispersion patterns. An enzyme-based partial leach selectively removes metals from oxide coatings on the surfaces of soil materials without attacking their matrix. Most trace-element concentrations in the resulting solutions are in the part-per-trillion to low part-per-billion range, necessitating determinations by inductively coupled plasma/mass spectrometry. The resulting data show greater contrasts for many trace elements than with other techniques tested. Spatially, many trace metal anomalies are locally discontinuous, but anomalous trends within larger areas are apparent. In many instances, the source for an anomaly seems to be either basal till or bedrock. Ground water flow is probably the most important mechanism for transporting metals toward the surface, although ionic diffusion, electrochemical gradients, and capillary action may play a role in anomaly dispersal. Sample sites near the Rainy Lake-Seine River fault zone, a regional shear zone, often have anomalous concentrations of a variety of metals, commonly including Zn and/or one or more metals which substitute for Zn in sphalerite (Cd, Ge, Ga, and Sn). Shifts in background concentrations of Bi, Sb, and As show a trend across the area indicating a possible regional zoning of lode-Au mineralization. Soil anomalies of Ag, Co, and Tl parallel basement structures, suggesting areas that may have potential for Cobalt/Thunder Baytype silver viens. An area around Baudette, Minnesota, which is underlain by quartz-chlorite-carbonate-altered shear zones, is anomalous in Ag, As, Bi, Co, Mo, Te, Tl, and W. Anomalies of Ag, As, Bi, Te, and W tend to follow the fault zones, suggesting potential

  18. Geochemical assessment of fluoride enrichment and nitrate ...

    Indian Academy of Sciences (India)

    62

    minerals. By reducing the consumption of fertilizer and stress over groundwater, the water quality can be improved. Key Word- Hydro-geochemistry, Fluoride, ... source (industries effluent, fertilizer industry and fertilizer used in agriculture field) influences ...... groundwater of the Taiyuan basin, Northern China; J. Geochem.

  19. Wet and cold climate conditions recorded by coral geochemical proxies during the beginning of the first millennium CE in the northern South China Sea

    Science.gov (United States)

    Xiao, Hangfang; Deng, Wenfeng; Chen, Xuefei; Wei, Gangjian; Zeng, Ti; Zhao, Jian-xin

    2017-03-01

    The past two millennia include some distinct climate intervals, such as the Medieval Warm Period (MWP) and the Little Ice Age (LIA), which were caused by natural forcing factors, as well as the Current Warm Period (CWP) that has been linked to anthropogenic factors. Therefore, this period has been of great interest to climate change researchers. However, most studies are based on terrestrial proxy records, historical documentary data, and simulation results, and the ocean and the tropical record are very limited. The Eastern Han, Three Kingdoms, and Western Jin periods (25-316 CE) cover the beginning first millennium CE in China, and were characterized by a cold climate and frequent wars and regime changes. This study used paired Sr/Ca and δ18O series recovered from a fossil coral to reconstruct the sea surface water conditions during the late Eastern Han to Western Jin periods (167-309 CE) at Wenchang, eastern Hainan Island in the northern South China Sea (SCS), to investigate climate change at this time. The long-term sea surface temperature (SST) during the study interval was 25.1 °C, which is about 1.5 °C lower than that of the CWP (26.6 °C). Compared with the average value of 0.40‰ during the CWP, the long-term average seawater δ18O (-0.06‰) was more negative. These results indicate that the climate conditions during the study period were cold and wet and comparable with those of the LIA. This colder climate may have been associated with the weaker summer solar irradiance. The wet conditions were caused by the reduced northward shift of the intertropical convergence zone/monsoon rainbelt associated with the retreat of the East Asian summer monsoon. Interannual and interdecadal climate variability may also have contributed to the variations in SST and seawater δ18O recorded over the study period.

  20. Tectono-stratigraphic evolution and exhumation of the Haymana basin: Unravelling the subduction and collision history of Neotethys in Turkey

    Science.gov (United States)

    Gülyüz, Erhan; Özkaptan, Murat; Lefebvre, Côme; Kaymakci, Nuretdin; Persano, Cristina; Stuart, Finlay M.

    2014-05-01

    The Haymana basin straddles the Izmir-Ankara-Erzincan Suture Zone (IAESZ) in the north and Intra-Tauride Suture Zone (ITSZ) in the south. The two suture zones developed in response to the subduction and demise of Neotethys Ocean in Turkey during the late Cretaceous to early Tertiary; the tectonic significance of the basin and its relationship with the ITSZ are still poorly constrained. In order to unravel subduction and subsequent collision history of the Neotethys in the region, we have carried out a detailed analysis of the stratigraphy and sedimentology of the Haymana basin infill and, using a combination of palaeomagnetic and thermochronometric data we have unravelled its structural evolution since its formation. The basin developed on the IAESZ and comprises fore-arc late Cretaceous to foreland Middle Eocene sedimentary sequences. The analysis of the sedimentogical facies and depositional environments indicate four Late Cretaceous to Paleogene key sequences in the basin. These sequences grade laterally and vertically into each other and are continuous from the late Cretaceous to Eocene whereas local progressive syn-sedimentary unconformities and frequent depocenter migrations are common. Late Cretaceous sequences fine upward whereas coarsening upwards sequences are common in the later units. These characteristics possibly reflect the response to local uplift and subsidence in front of south-verging thrust faults associated with the transition from fore-arc to foreland basin settings, following the terminal subduction of the Neotethys at the end of Cretaceous. About 4000 paleomagnetic and magnetostratigraphic data from the basin infill units and the Neogene cover indicate large clockwise vertical axes rotations in the NW and counter-clockwise rotations in the SE part of the basin. We suggest that these rotations are related to the northward movement and indentation of the Gondwana-derived continental blocks into Eurasia. A model of southward thrust propagation

  1. Kinematics of Late Cretaceous subduction initiation in the Neo-Tethys Ocean reconstructed from ophiolites of Turkey, Cyprus, and Syria

    Science.gov (United States)

    Maffione, Marco; van Hinsbergen, Douwe J. J.; de Gelder, Giovanni I. N. O.; van der Goes, Freek C.; Morris, Antony

    2017-05-01

    Formation of new subduction zones represents one of the cornerstones of plate tectonics, yet both the kinematics and geodynamics governing this process remain enigmatic. A major subduction initiation event occurred in the Late Cretaceous, within the Neo-Tethys Ocean between Gondwana and Eurasia. Suprasubduction zone ophiolites (i.e., emerged fragments of ancient oceanic lithosphere formed at suprasubduction spreading centers) were generated during this subduction event and are today distributed in the eastern Mediterranean region along three E-W trending ophiolitic belts. Several models have been proposed to explain the formation of these ophiolites and the evolution of the associated intra-Neo-Tethyan subduction zone. Here we present new paleospreading directions from six Upper Cretaceous ophiolites of Turkey, Cyprus, and Syria, calculated by using new and published paleomagnetic data from sheeted dyke complexes. Our results show that NNE-SSW subduction zones were formed within the Neo-Tethys during the Late Cretaceous, which we propose were part of a major step-shaped subduction system composed of NNE-SSW and WNW-ESE segments. We infer that this subduction system developed within old (Triassic?) lithosphere, along fracture zones and perpendicular weakness zones, since the Neo-Tethyan spreading ridge formed during Gondwana fragmentation would have already been subducted at the Pontides subduction zone by the Late Cretaceous. Our new results provide an alternative kinematic model of Cretaceous Neo-Tethyan subduction initiation and call for future research on the mechanisms of subduction inception within old (and cold) lithosphere and the formation of metamorphic soles below suprasubduction zone ophiolites in the absence of nearby spreading ridges.

  2. Geochemical and stable isotopic data on barren and mineralized drill core in the Devonian Popovich Formation, Screamer sector of the Betze-Post gold deposit, northern Carlin trend, Nevada

    Science.gov (United States)

    Christiansen, William D.; Hofstra, Albert H.; Zohar, Pamela B.; Tousignant, Gilles

    2011-01-01

    The Devonian Popovich Formation is the major host for Carlin-type gold deposits in the northern Carlin trend of Nevada. The Popovich is composed of gray to black, thin-bedded, calcareous to dolomitic mudstone and limestone deposited near the carbonate platform margin. Carlin-type gold deposits are Eocene, disseminated, auriferous pyrite deposits characterized by acid leaching, sulfidation, and silicification that are typically hosted in Paleozoic calcareous sedimentary rocks exposed in windows through siliceous sedimentary rocks of the Roberts Mountains allochthon. The Carlin trend currently is the largest gold producer in the United States. The Screamer ore zone is a tabular body on the periphery of the huge Betze-Post gold deposit. Screamer is a good place to study both the original lithogeochemistry of the Popovich Formation and the effects of subsequent alteration and mineralization because it is below the level of supergene oxidation, mostly outside the contact metamorphic aureole of the Jurassic Goldstrike stock, has small, high-grade ore zones along fractures and Jurassic dikes, and has intervening areas with lower grade mineralization and barren rock. In 1997, prior to mining at Screamer, drill core intervals from barren and mineralized Popovich Formation were selected for geochemical and stable isotope analysis. The 332, five-foot core samples analyzed are from five holes separated by as much as 2000 feet (600 meters). The samples extend from the base of the Wispy unit up through the Planar and Soft sediment deformation units into the lower part of the upper Mud unit of the Popovich Formation.

  3. Radiolarian biochronology of upper Anisian to upper Ladinian (Middle Triassic) blocks and tectonic slices of volcano-sedimentary successions in the Mersin Mélange, southern Turkey: New insights for the evolution of Neotethys

    Science.gov (United States)

    Tekin, U. Kagan; Bedi, Yavuz; Okuyucu, Cengiz; Göncüoglu, M. Cemal; Sayit, Kaan

    2016-12-01

    The Mersin Ophiolitic Complex located in southern Turkey comprises two main structural units; the Mersin Mélange, and a well-developed ophiolite succession with its metamorphic sole. The Mersin Mélange is a sedimentary complex including blocks and tectonic slices of oceanic litosphere and continental crust in different sizes. Based on different fossil groups (Radiolaria, Conodonta, Foraminifera and Ammonoidea), the age of these blocks ranges from Early Carboniferous to early Late Cretaceous. Detailed fieldwork in the central part of the Mersin Mélange resulted in identification of a number of peculiar blocks of thick basaltic pillow-and massive lava sequences alternating with pelagic-clastic sediments and radiolarian cherts. The oldest ages obtained from the radiolarian assemblages from the pelagic sediments transitional to the volcano-sedimentary succession in some blocks are middle to late Late Anisian. These pelagic sediments are overlain by thick sandstones of latest Anisian to middle Early Ladinian age. In some blocks, sandstones are overlain by clastic and pelagic sediments with lower Upper to middle Upper Ladinian radiolarian fauna. Considering the litho- and biostratigraphical data from Middle Triassic successions in several blocks in the Mersin Mélange, it is concluded that they correspond mainly to the blocks/slices of the Beysehir-Hoyran Nappes, which were originated from the southern margin of the Neotethyan Izmir-Ankara Ocean. As the pre-Upper Anisian basic volcanics are geochemically evaluated as back-arc basalts, this new age finding suggest that a segment of the Izmir-Ankara branch of the Neotethys was already open prior to Middle Triassic and was the site of intraoceanic subduction.

  4. Ophiolitic detritus in Kimmeridgian resedimented limestones and its provenance from an eroded obducted ophiolitic nappe stack south of the Northern Calcareous Alps (Austria

    Directory of Open Access Journals (Sweden)

    Gawlick Hans-Jürgen

    2015-12-01

    Full Text Available The causes for the Middle to Late Jurassic tectonic processes in the Northern Calcareous Alps are still controversially discussed. There are several contrasting models for these processes, formerly designated “Jurassic gravitational tectonics”. Whereas in the Dinarides or the Western Carpathians Jurassic ophiolite obduction and a Jurassic mountain building process with nappe thrusting is widely accepted, equivalent processes are still questioned for the Eastern Alps. For the Northern Calcareous Alps, an Early Cretaceous nappe thrusting process is widely favoured instead of a Jurassic one, obviously all other Jurassic features are nearly identical in the Northern Calcareous Alps, the Western Carpathians and the Dinarides. In contrast, the Jurassic basin evolutionary processes, as best documented in the Northern Calcareous Alps, were in recent times adopted to explain the Jurassic tectonic processes in the Carpathians and Dinarides. Whereas in the Western Carpathians Neotethys oceanic material is incorporated in the mélanges and in the Dinarides huge ophiolite nappes are preserved above the Jurassic basin fills and mélanges, Jurassic ophiolites or ophiolitic remains are not clearly documented in the Northern Calcareous Alps. Here we present chrome spinel analyses of ophiolitic detritic material from Kimmeridgian allodapic limestones in the central Northern Calcareous Alps. The Kimmeridgian age is proven by the occurrence of the benthic foraminifera Protopeneroplis striata and Labyrinthina mirabilis, the dasycladalean algae Salpingoporella pygmea, and the alga incertae sedis Pseudolithocodium carpathicum. From the geochemical composition the analysed spinels are pleonastes and show a dominance of Al-chromites (Fe3+–Cr3+–Al3+ diagram. In the Mg/(Mg+ Fe2+ vs. Cr/(Cr+ Al diagram they can be classified as type II ophiolites and in the TiO2 vs. Al2O3 diagram they plot into the SSZ peridotite field. All together this points to a harzburgite

  5. Geochemical evidences for palaeoclimatic fluctuations at the Triassic-Jurassic boundary: southwestern margin of the Neotethys in the Salt Range, Pakistan

    Science.gov (United States)

    Iqbal, Shahid; Wagreich, Michael; Jan, Irfanullah; Kürschner, Wolfram Michael; Gier, Susanne

    2017-04-01

    The Triassic-Jurassic boundary interval reveals a change from warm-arid to a warm and humid climate in the Tethyan domain. Sea-level reconstruction records across the European basins during this interval reveal an end-Triassic global regression event and is linked to the Central Atlantic Magmatic Province (CAMP) activity and Pangaea breakup. In the Tethyan Salt Range of Pakistan a succession of Upper Triassic dolomites/green-black mudstones (Kingriali Formation), overlying quartzose sandstone, mudstones, laterites and Lower Jurassic conglomerates/pebbly sandstones (Datta Formation) provides information on the palaeoclimatic evolution of the area. Preliminary palynological results from the mudstones indicate a Rhaetian age for the Kingriali Formation and a Hettangian age for the Datta Formation. X-ray diffraction (XRD) analysis of the mudstones (upper part of the Kingriali Formation) indicates the presence of mainly illite while kaolinite is a minor component. The kaolinite content, a reflection of the advanced stage of chemical weathering and hence warm-humid conditions, increases up-section in the overlying sandstone-mudstone succession. The overlying laterite-bauxite horizons lack illite/smectite and are entirely composed of kaolinite, boehmite and haematite. At places these kaolinite rich horizons are mined in the area (Western Salt Range). The bulk rock geochemistry of the succession confirms a similar trend. The Chemical Index of Alteration (CIA) displays an increasing trend from the Upper Triassic shales (CIA 75-80) through the overlying sandstones/mudstones-laterites to the overlying quartz rich sandstones and mudstones (CIA 90-97). The overall results for the succession reveal an increasing chemical maturity trend (increase in the intensity of chemical weathering) from Rhaetian to Hettangian thereby supporting a change from warm-arid to a warm-humid palaeoclimate, probably extreme greenhouse conditions.

  6. Geochemical exploration for uranium

    International Nuclear Information System (INIS)

    1988-01-01

    This Technical Report is designed mainly to introduce the methods and techniques of uranium geochemical exploration to exploration geologists who may not have had experience with geochemical exploration methods in their uranium programmes. The methods presented have been widely used in the uranium exploration industry for more than two decades. The intention has not been to produce an exhaustive, detailed manual, although detailed instructions are given for a field and laboratory data recording scheme and a satisfactory analytical method for the geochemical determination of uranium. Rather, the intention has been to introduce the concepts and methods of uranium exploration geochemistry in sufficient detail to guide the user in their effective use. Readers are advised to consult general references on geochemical exploration to increase their understanding of geochemical techniques for uranium

  7. Deformation History of the Haymana Basin: Structural Records of Closure-Collision and Subsequent Convergence (Indentation) Events at the North-Central Neotethys (Central Anatolia, Turkey)

    Science.gov (United States)

    Gülyüz, Erhan; Özkaptan, Murat; Kaymakcı, Nuretdin

    2016-04-01

    Gondwana- (Tauride Platfrom and Kırşehir Block) and Eurasia (Pontides) - derived continental blocks bound the Haymana basin, in the south and north, respectively. Boundaries between these blocks are signed by İzmir-Ankara-Erzincan and debatable Intra-Tauride Suture zones which are straddled by the Haymana Basin in the region. In this regard, deformation recorded in the upper Cretaceous to middle Eocene deposits of the basin is mainly controlled by the relative movements of these blocks. Therefore, understanding the structural evolution of the Haymana Basin in a spatio-temporal concept is crucial to shed some light on some debatable issues such as ; (1) timing of late stage subduction histories of various branches of Neotethys and subsequent collision events, (2) effects of post-collisional tectonic activity in the Haymana region. Fault kinematic analyses (based on 623 fault-slip data from 73 stations) indicate that the basin was subjected to initially N-S to NNE-SSW extension until middle Paleocene and then N-S- to NNE-SSW- directed continuous compression and coeval E-W to ESE-WNW extension up to middle Miocene. These different deformation phases correspond to the fore-arc (closure) and foreland (collision and further convergence) stages of the basin. Additionally, fold analyses (based on 1017 bedding attitudes) and structural mapping studies show that development of folds and major faults are coeval and they can be explained by principle stress orientations of the second deformation phase. The Haymana basin is, based on the trends of E-W- and WNW-ESE- directed structures at the south-eastern and the north-western parts of the basin, respectively, divided into two structural segments. The balanced cross-sections also indicate ~4% and ~25% shortening at the north-western and south-eastern segments, respectively. The differences in amounts of shortenings are explained by reduce in effectiveness zone of basin-bounding thrust faults towards west. On the other hand

  8. THE GEOLOGICAL EVOLUTION OF SORGUN (YOZGAT)-YILDIZELİ (SİVAS) FORELAND BASIN, PETROGRAPHIC, GEOCHEMICAL ASPECTS AND GEOCHRONOLOGY OF VOLCANISM AFFECTING THE BASIN

    OpenAIRE

    Akçay, Ali Ekber; BEYAZPİRİNÇ, Metin

    2017-01-01

    Sorgun-Yıldızeli basin is an east-west trending asymmetric marginal foreland (peripheral forelandbasin) formed as a result of the consumption of oceanic crust of the northern branch of Neotethys dueto the collision of Sakarya continent in the north and Kırşehir Block in the south. It provides muchinformation about the geodynamic evolution of the region. The basement of the study area consists ofLate Palaeozoic-Mesozoic Akdağmadeni Massif. Akdağmadeni Massif was intruded by CenomanianMaastrich...

  9. A Review of Palaeomagnetic Constraints On Tectonic Reconstructions of Neotethys In Eastern Turkey

    Science.gov (United States)

    Morris, A.

    Intense debate continues concerning the Mesozoic and Tertiary configuration of con- tinental fragments and intervening ocean basins in the eastern Mediterranean. Key to this debate is the interpretation of several discontinuous lineaments of Late Cre- taceous ophiolites within the Turkish region, which geochemical evidence suggests formed in supra-subduction zone environments. Two types of model exist: Model 1 - each ophiolitic lineament was rooted in a separate Neotethyan ocean basin, with ophiolites being emplaced relatively short distances (10's km) on to the adjacent pas- sive continental margins during progressive African-Eurasian convergence; Model 2 - the ophiolites are remnants of a once continuous thrust sheet which was emplaced for over 400 km southwards from a root zone between the Pontides and the Sakarya microcontinent. A number of geological arguments favour Model 1 over the palaeo- geographically simpler but kinematically more problematic Model 2. An additional, related debate concerns the evolution of the microcontinental fragments which form the footwalls to the ophiolite thrust sheets. These rifted from the Gondwanan margin during the early Mesozoic and were later re-amalgamated as a result of subduction- accretion and collisional processes during convergence. Palaeomagnetism offers an attractive approach to resolving this debate. This prob- lem is, however, at the limit of the palaeolatitudinal resolution of the palaeomagnetic method because of the overall narrowness of the Tethys in this region. Useful data, therefore, must be subject to strict quality control in terms of assessment of palaeo- magnetic stability (e.g. through the application of detailed demagnetisation experi- ments and fold tests), structural corrections and assessment of inherent errors. With these provisos, a number of high-quality, robust palaeomagnetic constraints exist for the Late Cretaceous in this region. In particular, three points can be located with con- fidence at

  10. Methods for geochemical analysis

    Science.gov (United States)

    Baedecker, Philip A.

    1987-01-01

    The laboratories for analytical chemistry within the Geologic Division of the U.S. Geological Survey are administered by the Office of Mineral Resources. The laboratory analysts provide analytical support to those programs of the Geologic Division that require chemical information and conduct basic research in analytical and geochemical areas vital to the furtherance of Division program goals. Laboratories for research and geochemical analysis are maintained at the three major centers in Reston, Virginia, Denver, Colorado, and Menlo Park, California. The Division has an expertise in a broad spectrum of analytical techniques, and the analytical research is designed to advance the state of the art of existing techniques and to develop new methods of analysis in response to special problems in geochemical analysis. The geochemical research and analytical results are applied to the solution of fundamental geochemical problems relating to the origin of mineral deposits and fossil fuels, as well as to studies relating to the distribution of elements in varied geologic systems, the mechanisms by which they are transported, and their impact on the environment.

  11. Origin of the Eastern Mediterranean: Neo-Tethys Rifting Along a Cryptic Cadomian Suture with Afro-Arabia

    Science.gov (United States)

    Avigad, D.; Abbo, A.; Gerdes, A.

    2016-12-01

    The East Mediterranean is a land-locked basin, a remnant of Neo-Tethys. It was formed in the Permo-Triassic as a result of the drift of the Tauride block from the Afro-Arabian margin of Gondwana. Herein we show that rather than being a genuine Afro-Arabia crustal fragment, the Tauride block is underlain by a Late Neoproterozoic Cadomian basement, which differs significantly from the Neoproterozoic "Pan-African" basement of NE Africa from which it was detached. Resembling other Cadomian terranes of Western Europe, the Tauride basement is chiefly a greywacke succession deposited in a mid to late Ediacaran back-arc basin formed on the periphery of Afro-Arabia, above the southward subducting proto-Tethys. The back-arc region was deformed and metamorphosed to various degrees and intruded by latest Ediacaran-Cambrian granites and volcanics during the Cadomian orogeny. Unlike the protracted (ca .300 m.y.) Neoproterozoic crustal evolution recorded in Afro-Arabia, the Cadomian basement of the Taurides evolved briefly, over ca. 50 m.y. We show that the entire cycle of sedimentation, metamorphism and magmatism in the Tauribe basement took place in the late Ediacaran-Cambrian and lagged after Neoproterozoic Pan-African orogeny and igneous activity in Afro-Arabia. The Cadomian orogeny had accreted the Taurides, and adjoining peri-Gandwana Cadomian terranes, with an already-consolidated Afro-Arabian continent. Permo-Triassic rifting of the East Mediterranean occurred close to the transition between these two domains. Rifting has thus been inherited from, and superimposed on late Ediacaran structures formed in front of the current Afro-Arabia margin of Gondwana during Cadomian orogeny. The boundary between the Cadomian edifice and the Pan-African crust of Afro-Arabia appears to lie nowadays on the southern margin of the Mediterranean, extending from Morocco in the west to Arabia in the east. Hence, the continental margin of the East Mediterranean, including in the Levant basin

  12. Petrology of the shoshonitic Çambaşı pluton in NE Turkey and implications for the closure of the Neo-Tethys Ocean: Insights from geochemistry, geochronology and Sr-Nd isotopes

    Science.gov (United States)

    Özdamar, Şenel; Roden, Michael F.; Billor, Mehmet Z.

    2017-07-01

    the northern branch of Neo-Tethys Ocean in Lutetian time on the northern margin of Gondwanaland.

  13. Alligator Rivers Analogue project. Geochemical Data Bases

    International Nuclear Information System (INIS)

    Bennett, D.G.; Read, D.

    1992-01-01

    The Koongarra uranium deposit in the Northern Territory of Australia is being studied to evaluate the processes involved in the geochemical alteration of the ore body and the formation of the uranium dispersion fan. A broad range of research is being undertaken into the geochemistry and hydrology of the site with the aim of understanding the transport of radionuclides through the system. During the project a range of geochemical and hydrogeochemical models have been developed to account for measured data from the site and with which to predict site evolution. The majority of these models are based on the premise of thermodynamic chemical equilibrium and employ fundamental thermodynamic data to characterise the chemistry of the system. From the differences which exist between the thermodynamic data bases (Appendices I and II) it is possible to gain a view of the level of uncertainty associated with thermodynamic data in each set of calculations. This report gives a brief introduction to the geochemical processes underlying the models, and details the equations used to quantify the more common of these processes (e.g. aqueous speciation and mineral solubility). A description is given of the computer codes (EQ3/6, PHREEQE, MINTEQ) most commonly used during the project for geochemical modelling. Their key features are highlighted and comparisons made. It is concluded that the degree of uncertainty in geochemical modelling studies arising as a result of using one code rather than another is relatively insignificant when compared to that related to differences in the underlying data bases. 73 refs., 3 figs

  14. Geochemical prospecting in Guiana

    International Nuclear Information System (INIS)

    Coulomb, R.

    1957-01-01

    During the last few years geochemical prospecting techniques have become common usage in the field of mineral deposit prospecting. The real scope of these methods lies in their use in the prospecting of large areas. The most promising use of the geochemistry and hydro-geochemistry of uranium is in heavily forested tropical territories, with few outcrops, where radiometry is strongly handicapped. (author) [fr

  15. Reconnaissance Geochemical Study

    African Journals Online (AJOL)

    Geochemical exploration of Orle district within the Igarra schist belt in southwestern Nigeria was carried out using reconnaissance ... The occurrence of pathfinder elements such as As and W; and of rock units, such as amphibolites and pegmatites, within the schist belt that ...... house for national prosperity. Inaugural.

  16. The Eldivan ophiolite and volcanic rocks in the İzmir-Ankara-Erzincan suture zone, Northern Turkey: Geochronology, whole-rock geochemical and Nd-Sr-Pb isotope characteristics

    Science.gov (United States)

    Çelik, Ömer Faruk; Chiaradia, Massimo; Marzoli, Andrea; Billor, Zeki; Marschik, Robert

    2013-07-01

    Gabbros and dolerite dikes of the Eldivan ophiolite and basaltic volcanic rocks of the ophiolitic mélange in the central part of the İzmir-Ankara-Erzincan (IAE) suture zone were investigated for their 40Ar/39Ar age and whole-rock-major-trace element and Sr-Nd-Pb isotope compositions. Based on geological and geochemical characteristics basaltic volcanic rocks in the ophiolitic mélange are subdivided into two groups (Groups I and II) with ocean island basalts or enriched mid-ocean ridge basalt characteristics, respectively. Gabbros and dolerite dikes of the Eldivan ophiolite (Groups III and IV) have instead geochemical compositions indicative of a subduction-related environment. The volcanic rocks of Group I have 87Sr/86Sr(i) between 0.7037 and 0.7044, ƐNd(i)-DM of - 4.5 to - 5.6, and 206Pb/204Pb(i) ranging between 18.35 and 18.75. Group II volcanic rocks have higher 87Sr/86Sr(i) values (0.7049-0.7055), ƐNd(i)-DM ranging between - 5.4 and - 6.0, and 206Pb/204Pb(i) between 18.14 and 18.62. The Nd isotopic signatures and 207Pb/204Pb(i) values of the volcanic rocks of both groups point to a different source with respect to those of the Eldivan ophiolite. The low 206Pb/204Pb(i) values relative to the ophiolitic rocks seem to exclude a significant contribution from a HIMU reservoir, whereas the 207Pb/204Pb(i) values slightly above the NHRL might indicate some contribution from an EM2-type reservoir. Gabbros (Group III) of the Eldivan ophiolite and dolerite dikes (Group IV) cross-cutting the ultramafic part of the ophiolite show 87Sr/86Sr(i) between 0.7038 and 0.7053, ƐNd(i)-DM from - 2 to - 3.6 and 206Pb/204Pb(i) between 18.10 and 18.80. The gabbros yield ca. 150 Ma 40Ar/39Ar amphibole-plateau ages, which, together with the geochemical data, indicate that they were produced above subducted oceanic lithosphere in the IAE ocean domain in Late Jurassic times. Therefore, the Eldivan ophiolite in the IAE suture zone constitutes a link between the Hellenide

  17. Geochemical modeling: a review

    International Nuclear Information System (INIS)

    Jenne, E.A.

    1981-06-01

    Two general families of geochemical models presently exist. The ion speciation-solubility group of geochemical models contain submodels to first calculate a distribution of aqueous species and to secondly test the hypothesis that the water is near equilibrium with particular solid phases. These models may or may not calculate the adsorption of dissolved constituents and simulate the dissolution and precipitation (mass transfer) of solid phases. Another family of geochemical models, the reaction path models, simulates the stepwise precipitation of solid phases as a result of reacting specified amounts of water and rock. Reaction path models first perform an aqueous speciation of the dissolved constituents of the water, test solubility hypotheses, then perform the reaction path modeling. Certain improvements in the present versions of these models would enhance their value and usefulness to applications in nuclear-waste isolation, etc. Mass-transfer calculations of limited extent are certainly within the capabilities of state-of-the-art models. However, the reaction path models require an expansion of their thermodynamic data bases and systematic validation before they are generally accepted

  18. Organic geochemical a

    Indian Academy of Sciences (India)

    63

    Geological Settings. The Northern margin of the Indian plate is occupied by an active fold and thrust belt of the Salt ... light grey in color, nodular and occurs as interbeds with shale units. The sandstone is ..... under light microscope is known as amorphous organic matter (Plate 2, figures 7, 8 and 9; Tyson. 1995; Pacton et al.

  19. Geochemical signatures of tephras from Quaternary Antarctic Peninsula volcanoes

    OpenAIRE

    Kraus,Stefan; Kurbatov,Andrei; Yates,Martin

    2013-01-01

    In the northern Antarctic Peninsula area, at least 12 Late Plelstocene-Holocene volcanic centers could be potential sources of tephra layers in the region. We present unique geochemical fingerprints for ten of these volcanoes using major, trace, rare earth element, and isotope data from 95 samples of tephra and other eruption products. The volcanoes have predominantly basaltic and basaltic andesitic compositions. The Nb/Y ratio proves useful to distinguish between volcanic centers located on ...

  20. Geochemical Survey of Pernambuco

    International Nuclear Information System (INIS)

    Horowitz, A.; Duarte, P.J.; Almeida, M.G. de; Medeiros, M.O.

    1988-01-01

    The area studied i this work is located in a triangle formed by the Sibiro and Boca da Mata Sugar-Mills and Serinhaem country. In the Cabo Formation the search determinated conglomerates, arcos and clays. Although the highest geochemical activity have been done in the decomposed crystalin, and the values from Cabo Formation don't be encourager, this formation has lithology compatible with uranium mineralization. The Cabo Formation's sediments presents lithologic variations very expressives, with conglomerates, arcoses and clay silts, which determinate the choise of the area. This area presented favorable to uranium prospecting and to others elements interesting to ragional geochemistry. The atomic absorption analysis, fluorimetry and spectrometry were done for the following elements: Zn, V, Ti, Ni, Pb, Mn, Ga, Cu, Co, Bi, Ag, B, Mo, and U. (C.D.G.) [pt

  1. Early Neogene foreland of the Zagros, implications for the initial closure of the Neo-Tethys and kinematics of crustal shortening

    Science.gov (United States)

    Pirouz, Mortaza; Avouac, Jean-Philippe; Hassanzadeh, Jamshid; Kirschvink, Joseph L.; Bahroudi, Abbas

    2017-11-01

    We study the transition from passive margin to foreland basin sedimentation now exposed in the High Zagros belt to provide chronological constraints on the initial stage of Arabia-Eurasia collision and closure of the Neo-Tethys. We performed magnetostratigraphy and strontium isotope stratigraphy along two sections near the Zagros suture which expose the oldest preserved foreland deposits: the Shalamzar section in the west and the Dehmoord section in the east. The top of the passive margin Asmari formation has an age of 28-29 Ma in the High Zagros and is overlain by foreland deposits with a major basal unconformity representing 7 Myr of hiatus. The base of the foreland deposits has an age of 21.5 Ma at Dehmoord and ca. 26 Ma at Shalamzar. The sedimentation rate increased from 30 m/Myr in the passive margin to 247 m/Myr in the foreland. Combined with available age constraints across the Zagros, our results show that the unconformity is diachronous and records the southwestward migration of the flexural bulge within the Arabian plate at an average rate of 24 ± 2 mm/yr over the last 27 Ma. The time evolution of sediment accumulation in the Zagros foreland follows the prediction from a flexural model, as the foreland is thrust beneath the orogenic wedge and loaded by the wedge and basin fill. We detect the onset of forebulge formation within the Asmari Formation around 25 Ma. We conclude that closure of the Neo-Tethys formed the Zagros collisional wedge at 27 ± 2 Ma. Hence, the Arabia-Eurasia collision was probably not the main driver of global cooling which started near the Eocene-Oligocene boundary (ca. 33.7 Ma). We estimate 650 km of forebulge migration since the onset of the collision which consists of 350 km of shortening across the orogen, and 300 km of widening of the wedge and increasing flexural rigidity of Arabia. We conclude the average rate of shortening across the Zagros to be ca. 13 mm/yr over the last 27 Myr; a value comparable to the modern rate

  2. Statistical interpretation of geochemical data

    International Nuclear Information System (INIS)

    Carambula, M.

    1990-01-01

    Statistical results have been obtained from a geochemical research from the following four aerial photographies Zapican, Carape, Las Canias, Alferez. They have been studied 3020 samples in total, to 22 chemical elements using plasma emission spectrometry methods.

  3. Geochronology, geochemical and Sr-Nd-Hf-Pb isotopic compositions of the granitoids in the Yemaquan orefield, East Kunlun orogenic belt, northern Qinghai-Tibet Plateau: Implications for magmatic fractional crystallization and sub-solidus hydrothermal alteration

    Science.gov (United States)

    Yin, Shuo; Ma, Changqian; Xu, Jiannan

    2017-12-01

    A general consensus has emerged that high field strength elements (HFSE) can mobile to some extent in a hydrothermal fluid. However, there are hot debates on whether sub-solidus hydrothermal alteration can lower the Nb/Ta ratio in evolved melts. In this study, we present petrography, geochronology and geochemistry of the barren and mineralized rocks in the Yemaquan skarn iron deposit, northern Qinghai-Tibet Plateau, to probe magmatic-hydrothermal transition. The barren rocks consist of diorites, granodiorites, granites and syenogranites, whereas the porphyritic granodiorites are associated with mineralization for an excellent consistency between the magmatic zircon U-Pb age (225 ± 2 Ma) and the hydrothermal phlogopite 40Ar-39Ar age (225 ± 1.5 Ma). The Sr-Nd-Hf-Pb isotopic data demonstrate that the Yemaquan granitoids are originated from a relatively homogenous enriched mantle with different degrees of crust contamination (assimilation fractional crystallization, AFC). Trace elements signatures indicate that the porphyritic granodiorites related to mineralization display amphibole crystallization for high water contents, whereas the barren granites have gone through biotite crystallization due to potassium enrichment by continuous upper crust contamination, both of which are responsible for their Nb/Ta ratios, respectively. Modeling results suggest that a basaltic melt with Nb/Ta ratio of 15.3 can reach a minimum Nb/Ta ratio of 12 in the producing granodioritic melt by amphibole fractional crystallization based on partition coefficients of Nb and Ta between amphibole and melts from previous experiments. This may explain the average Nb/Ta ratio (13.7) of the barren granodiorites, while it cannot account for the average Nb/Ta ratio (8.4) of the mineralized porphyritic granodiorites, and it is even lower than that of the granites (10.3) with biotite fractional crystallization. Exsolution of a magmatic-hydrothermal fluid is inevitable when a water saturated magma

  4. Geochemical studies in watersheds expanded

    Science.gov (United States)

    Church, M. Robbins

    In the past, geochemical research in forested watersheds has focused on understanding the basic processes that occur in soils and rocks. Watershed geochemical processes, however, are greatly influenced by, and in turn, greatly influence, both organisms and biological process in soils, and hydrologic responses of catchments. To date, geochemical research has dealt principally with basic chemical processes in soils and rocks, and much less with questions concerning hydrologic routing through catchments and the effects such routing has on temporal variation in chemical composition of surface waters.Research on flow generation in catchments has focused on intensive field studies on plots, hillslope sections, and small catchments, with extension to larger scales necessarily involving the application of conceptual models that might (or might not) be valid. The acquisition of direct experimental evidence (for example, verifying flow generation mechanisms) on larger-scale watersheds has always been problematic. Although geochemists understand that the explanation of some geochemical observations requires that flow pathways be explicitly identified, and hydrologists understand that flow generation can be better elucidated if the geochemical history of waters is known, critical integrated communication between the disciplines is often lacking. In turn, biologists require physical and geochemical information to interpret biological effects in watersheds, and hydrologists and geochemists need to be aware of the effects of biological processes on hydrochemical response of catchments.

  5. Tectonic evolution of a part of the Tethyside orogenic collage: The Kargi Massif, northern Turkey

    Science.gov (United States)

    Tüysüz, Okan

    1990-02-01

    The central part of the Rhodope-Pontide fragment, one of the major tectonic units in Turkey, provides critical data for evaluating the Cimmeride and Alpide evolution of the Mediterranean Tethysides. Tectonic events that affected the central part of the Rhodope-Pontide fragment since the end of the Paleozoic, generated east-west trending belts with the event of every episode redeforming and partly obliterating the structures of previous episodes. This evolution may be conveniently described in terms of three major episodes: (1) Two different realms of pre-Dogger oceanic rocks are present in the area. The northern realm coincided with main branch of Paleo-Tethys that was being actively destroyed by south dipping subduction. The southern realm, the Karakaya ocean, a back arc basin related to this subduction, began opening by rifting of a retroarc carbonate platform during the Permo-Triassic. To the west a continental domain with sparse magmatism seperated the two oceanic areas. Toward the east the two oceans become united by the wedging out of the continental domain. These two pre-Dogger oceans closed during the Lias, and their remnants were emplaced between the southern margin of Laurasia and the fragments of the Cimmerian continent. (2) The second episode partly overlapped the first with rifting south of the Cimmerian continent fragment during the Lias. This rifting was followed by a transgression which covered the ruins of the Cimmeride orogenic belt by the Malm. This rifting concurrently led to the development of the northern branch of the Neo-Tethys and a south facing Atlantic-type continental margin. A southerly thickening sedimentary prism developed on this margin during the Lias to early Cretaceous interval. (3) The floor of the northern branch of Neo-Tethys began to be consumed along the north dipping subduction zone beneath the previosly constructed continental margin. This convergent margin generated a magmatic arc to the north and to the south a subduction

  6. Geochemical exploration for uranium

    International Nuclear Information System (INIS)

    Rose, A.W.

    1977-01-01

    The processes and types of dispersion that produce anomalies in stream water, stream sediment, and ground water, and the factors that must be considered in planning and interpreting geochemical surveys are reviewed. Examples of surveys near known deposits show the types of results to be expected. Background values depend mainly on the content of U in rocks of the drainage area. In igneous rocks, U tends to increase with potassium from ultramafic rocks (0.01 ppM) to granitic rocks (1 to 5 ppM). Some alkalic rocks have unusually high contents of U (15 to 100 ppM). Uranium-rich provinces marked by igneous rocks unusually rich in U are recognized in several areas and appear to have a deep crustal or mantle origin. In western U.S., many tertiary tuffaceous rocks have a high U content. Sandstones, limestones, and many shales approximate the crustal abundance at 0.5 to 4 ppM, but black shales, phosphates, and some organic materials are notably enriched in U. Uranium is very soluble in most oxidizing waters at the earth's surface, but is precipitated by reducing agents (organic matter, H 2 S) and adsorbed by organic material and some Fe oxides. In most surface and ground waters, U correlates approximately with the total dissolved solids, conductivity, and bicarbonate concentration of the water, and with the U content of rocks it comes into contact with. Most surveys of stream water near known districts show distinct anomalies extending a few km to tens of km downstream. A complication with water is the large variability with time, up to x 50, as a result of changes in the ratio of ground water to direct runoff, and changes in rate of oxidation and leaching. Collection and analysis of water samples also pose some difficulties

  7. Geochemical computer codes. A review

    International Nuclear Information System (INIS)

    Andersson, K.

    1987-01-01

    In this report a review of available codes is performed and some code intercomparisons are also discussed. The number of codes treating natural waters (groundwater, lake water, sea water) is large. Most geochemical computer codes treat equilibrium conditions, although some codes with kinetic capability are available. A geochemical equilibrium model consists of a computer code, solving a set of equations by some numerical method and a data base, consisting of thermodynamic data required for the calculations. There are some codes which treat coupled geochemical and transport modeling. Some of these codes solve the equilibrium and transport equations simultaneously while other solve the equations separately from each other. The coupled codes require a large computer capacity and have thus as yet limited use. Three code intercomparisons have been found in literature. It may be concluded that there are many codes available for geochemical calculations but most of them require a user that us quite familiar with the code. The user also has to know the geochemical system in order to judge the reliability of the results. A high quality data base is necessary to obtain a reliable result. The best results may be expected for the major species of natural waters. For more complicated problems, including trace elements, precipitation/dissolution, adsorption, etc., the results seem to be less reliable. (With 44 refs.) (author)

  8. Geochemical Arrays at Woolsey Mound Seafloor Observatory

    Science.gov (United States)

    Sleeper, K.; Wilson, R. M.; Chanton, J.; Lapham, L.; Farr, N.; Camilli, R.; Martens, C. S.; Pontbriand, C.

    2011-12-01

    A suite of geochemical monitoring arrays has been developed for the Woolsey Mound Seafloor Observatory in the northern Gulf of Mexico to evaluate the oceanographic and tectonic forcing factors on the formation and stability of gas hydrates. These arrays are designed to collect sustained, time-series data of chemical concentrations, gradients and fluxes from the subsurface to the seafloor and into the near bottom water column. A Pore Fluid Array provides time-series measurements of methane, sulfate and salinity in subsurface pore waters to evaluate microbial activity, hydrate formation and/or hydrate dissociation. A Chimney Sampler Array collects in situ chemical and physical readings at the benthic boundary. The array is designed around a vertical cylinder with a known volume and washout rate for measuring chemical gradients and flux at the seafloor. The Benthic Boundary Layer Array extends into the water column with a package of sensors in a node close to the seafloor and a similar node 20 m above the seafloor to evaluate upward, downward and transversely advecting fluids. The three arrays can be used in concert to evaluate a release of methane by the dissociation of gas hydrates: the Pore Fluid Array identifies the breakdown of gas hydrates in the subsurface, the Chimney Array determines the rate of flux at the seafloor and the Benthic Boundary Layer Array evaluates the fate of the release in the water column. Combining the data from the geochemical arrays with output from the geophysical arrays provides key information to evaluate the specific and relative importance of tectonic and oceanographic triggers for hydrate dissociation. New probes and deployment platforms have been developed for the installation and maintenance of the arrays and new systems are in place and under development for the recovery of the data. Generally, the complete array or its components have to be recovered to download the data. However, this summer 2011, a new optic modem system was

  9. Geochemical characterization of Parana Basin volcanic rocks: petrogenetic implications

    International Nuclear Information System (INIS)

    Marques, L.S.

    1988-01-01

    A detailed study of the geochemical characteristics of Parana Basin volcanic rocks is presented. The results are based on the analyses of major and trace elements of 158 samples. Ninety three of these volcanic samples belong to 8 flow sequences from Rio Grande do Sul and Santa Catarina States. The remaining sixty five samples are distributed over the entire basin. In order to study the influence of crustal contamination processes in changing chemical characteristics of the volcanic rocks, 47 samples representative of the crystalline basement of the southern and southeastern Parana Basin were also analysed. Several petrogenetic models were tested to explain the compocional variability of the volcanic rocks, in particular those of southern region. The results obtained sugest an assimilation-fractional crystallization process as viable to explain the differences of both the chemical characteristics and Sr isotope initial ratios observed in basic and intermediate rocks. A model involving melting processes of basic material, trapped at the base of the crust, with composition similar to low and high TiO 2 basalts appears to be a possibility to originate the Palmas and Chapeco acid melts, respectively. The study of ''uncontaminated'' or poorly contaminated low TiO 2 basic rocks from the southern, central and northern regions shows the existence of significant differences in the geochemical charactetistics according to their geographical occurrence. A similar geochemical diversity is also observed in high TiO 2 basalts and Chapeco volcanics. Differences in incompatible element ratios between low and high TiO 2 ''uncontaminated'' or poorly contaminated basalts suggest that they could have been produced by different degrees of melting in a garnet peridotite source. Geochemical and isotopic (Sr and Nd) data also support the view that basalts from northern and southern regions of Parana Basin originated from mantle source with different composition. (author) [pt

  10. NOAA and MMS Marine Minerals Geochemical Database

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Marine Minerals Geochemical Database was created by NGDC as a part of a project to construct a comprehensive computerized bibliography and geochemical database...

  11. Oak Ridge Geochemical Reconnaissance Program

    International Nuclear Information System (INIS)

    Arendt, J.W.

    1977-03-01

    The Oak Ridge reconnaissance program is responsible for the geochemical survey in a 12-state area covering Texas, Oklahoma, Kansas, Nebraska, South Dakota, North Dakota, Minnesota, Wisconsin, Michigan, Iowa, Indiana, and Illinois as part of the National Uranium Resource Evaluation Program. The program concept is outlined and the planning and organization of the program is discussed

  12. Early Cretaceous wedge extrusion in the Indo-Burma Range accretionary complex: implications for the Mesozoic subduction of Neotethys in SE Asia

    Science.gov (United States)

    Zhang, Ji'en; Xiao, Wenjiao; Windley, Brian F.; Cai, Fulong; Sein, Kyaing; Naing, Soe

    2017-06-01

    ± 3 Ma and 115 Ma, which are close to the zircon ages of nearby calc-alkaline granite and diorite, which belong to an active continental margin arc that extends along the western side of the Shan-Thai block. The IBR accretionary complex and the active continental margin arc were generated during Early Cretaceous (115-128 Ma) subduction of the Neotethys Ocean.

  13. Age and duration of intra-oceanic arc volcanism built on a suprasubduction zone type oceanic crust in southern Neotethys, SE Anatolia

    Directory of Open Access Journals (Sweden)

    Fatih Karaoğlan

    2013-07-01

    Full Text Available The southeastern Anatolia comprises numbers of tectono-magmatic/stratigraphic units such as the metamorphic massifs, the ophiolites, the volcanic arc units and the granitoid rocks. All of them play important role for the late Cretaceous evolution of the southern Neotethys. The spatial and temporal relations of these units suggest the progressive development of coeval magmatism and thrusting during the late Cretaceous northward subduction/accretion. Our new U-Pb zircon data from the rhyolitic rocks of the wide-spread volcanic arc unit show ages of (83.1 ± 2.2–(74.6 ± 4.4 Ma. Comparison of the ophiolites, the volcanic arc units and the granitoids suggest following late Cretaceous geological evolution. The ophiolites formed in a suprasubduction zone (SSZ setting as a result of northward intra-oceanic subduction. A wide-spread island-arc tholeiitic volcanic unit developed on the top of the SSZ-type crust during 83–75 Ma. Related to regional plate convergence, northward under-thrusting of SSZ-type ophiolites and volcanic arc units was initiated beneath the Tauride platform (Malatya-Keban and followed by the intrusion of I-type calc-alkaline volcanic arc granitoids during 84–82 Ma. New U-Pb ages from the arc-related volcanic-sedimentary unit and granitoids indicate that under-thrusting of ophiolites together with the arc-related units beneath the Malatya-Keban platform took place soon after the initiation of the volcanic arc on the top of the SSZ-type crust. Then the arc-related volcanic-sedimentary unit continued its development and lasted at ∼75 Ma until the deposition of the late Campanian–Maastrichtian shallow marine limestone. The subduction trench eventually collided with the Bitlis-Pütürge massif giving rise to HP-LT metamorphism of the Bitlis massif. Although the development of the volcanic arc units and the granitoids were coeval at the initial stage of the subduction/accretion both tectono-magmatic units were

  14. Geochemical Investigations of Groundwater Stability

    Energy Technology Data Exchange (ETDEWEB)

    Bath, Adrian [Intellisci Ltd., Loughborough (United Kingdom)

    2006-05-15

    The report describes geochemical parameters and methods that provide information about the hydrodynamic stability of groundwaters in low permeability fractured rocks that are potential hosts for radioactive waste repositories. Hydrodynamic stability describes the propensity for changes in groundwater flows over long timescales, in terms of flow rates and flow directions. Hydrodynamic changes may also cause changes in water compositions, but the related issue of geochemical stability of a potential repository host rock system is outside the scope of this report. The main approaches to assessing groundwater stability are numerical modelling, measurement and interpretation of geochemical indicators in groundwater compositions, and analyses and interpretations of secondary minerals and fluid inclusions in these minerals. This report covers the latter two topics, with emphasis on geochemical indicators. The extent to which palaeohydrogeology and geochemical stability indicators have been used in past safety cases is reviewed. It has been very variable, both in terms of the scenarios considered, the stability indicators considered and the extent to which the information was explicitly or implicitly used in assessing FEPs and scenarios in the safety cases. Geochemical indicators of hydrodynamic stability provide various categories of information that are of hydrogeological relevance. Information about groundwater mixing, flows and water sources is potentially provided by the total salinity of groundwaters, their contents of specific non-reactive solutes (principally chloride) and possibly of other solutes, the stable isotopic ratio of water, and certain characteristics of secondary minerals and fluid inclusions. Information pertaining directly to groundwater ages and the timing of water and solute movements is provided by isotopic systems including tritium, carbon-14, chlorine-36, stable oxygen and hydrogen isotopes, uranium isotopes and dissolved mobile gases in

  15. Field Analytical Techniques for Geochemical Surveys

    OpenAIRE

    Lemière, Bruno

    2015-01-01

    International audience; Obtaining geochemical results in the field has been a persistent dream for exploration geologists in the last century, and a few practical geochemical? tests were developed, but shipping samples to faraway labs and waiting weeks for results was the rule. This remained a dream until around 1990, when technology developments of portable instruments allowed on-site measurement of the first key metals in solids. This development progressed rapidly and by 2010, most geochem...

  16. Petrology and geochemistry of mafic magmatic rocks from the Sarve-Abad ophiolites (Kurdistan region, Iran): Evidence for interaction between MORB-type asthenosphere and OIB-type components in the southern Neo-Tethys Ocean

    Science.gov (United States)

    Saccani, Emilio; Allahyari, Khalil; Rahimzadeh, Bahman

    2014-05-01

    The Sarve-Abad (Sawlava) ophiolites crop out in the Main Zagros Thrust Zone and represent remnants of the Mesozoic southern Neo-Tethys Ocean that was located between the Arabian shield and Sanandaj-Sirjan continental block. They consist of several incomplete ophiolitic sequences including gabbroic bodies, a dyke complex, and pillow lava sequences. These rocks generally range from sub-alkaline to transitional character. Mineral chemistry and whole-rock geochemistry indicate that they have compositions akin to enriched-type mid-ocean ridge basalts (E-MORB) and plume-type MORB (P-MORB). Nonetheless, the different depletion degrees in heavy rare earth elements (HREE), which can be observed in both E-MORB like and P-MORB like rocks enable two main basic chemical types of rocks to be distinguished as Type-I and Type-II. Type-I rocks are strongly depleted in HREE (YbN 9.0). Petrogenetic modeling shows that Type-I rocks originated from 7 to 16% polybaric partial melting of a MORB-type mantle source, which was significantly enriched by plume-type components. These rocks resulted from the mixing of variable fractions of melts generated in garnet-facies and the spinel-facies mantle. In contrast, Type-II rocks originated from 5 to 8% partial melting in the spinel-facies of a MORB-type source, which was moderately enriched by plume-type components. A possible tectono-magmatic model for the generation of the southern Neo-Tethys oceanic crust implies that the continental rift and subsequent oceanic spreading were associated with uprising of MORB-type asthenospheric mantle featuring plume-type component influences decreasing from deep to shallow mantle levels. These deep plume-type components were most likely inherited from Carboniferous mantle plume activity that was associated with the opening of Paleo-Tethys in the same area.

  17. Status report on geochemical modelling

    International Nuclear Information System (INIS)

    Read, D.

    1991-12-01

    This report describes the findings of a review undertaken on behalf of the project management group of the programme 'Endlagersicherheit in der Nachbetriebsphase' based at GSF-IfT (Forschungszentrum fuer Umwelt und Gesundheit - Institut fuer Tieflagerung) to establish the current status of research into the simulation of geochemical processes relevant to radiological assessment. The review is intended to contribute to Stage 1 of a strategy formulated to enhance the use of geochemical models in Germany. Emphasis has been placed on processes deemed to be of greatest relevance to performance assessment for a HLW-repository in a salt dome principally, speciation-solubility in high salinity solutions, complexation by natural organics and generation-transport of colloids. For each of these and other topics covered, a summary is given of fundamental concepts, theoretical representations and their limitations, highlighting, where appropriate, the advantages and disadvantages of alternative approaches. The availability of data to quantify any given representation is addressed, taking into account the need for information at elevated temperatures and pressures. Mass transfer is considered in terms of aqueous, particulate and gas-mediated transport, respectively. (orig.) [de

  18. Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting

    International Nuclear Information System (INIS)

    Mani, Devleena; Kumar, T. Satish; Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V.

    2011-01-01

    The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana–Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r 2 < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

  19. Proceedings of the workshop on geochemical modeling

    International Nuclear Information System (INIS)

    1986-01-01

    The following collection of papers was presented at a workshop on geochemical modeling that was sponsored by the Office of Civilian Radioactive Waste Management Program at the Lawrence Livermore National Laboratory (LLNL). The LLNL Waste Management Program sponsored this conference based on their belief that geochemical modeling is particularly important to the radioactive waste disposal project because of the need to predict the consequences of long-term water-rock interactions at the proposed repository site. The papers included in this volume represent a subset of the papers presented at the Fallen Leaf Lake Conference and cover a broad spectrum of detail and breadth in a subject that reflects the diverse research interests of the conference participants. These papers provide an insightful look into the current status of geochemical modeling and illustrate how various geochemical modeling codes have been applied to problems of geochemical interest. The emphasis of these papers includes traditional geochemical modeling studies of individual geochemical systems, the mathematical and theoretical development and refinement of new modeling capabilities, and enhancements of data bases on which the computations are based. The papers in this proceedings volume have been organized into the following four areas: Geochemical Model Development, Hydrothermal and Geothermal Systems, Sedimentary and Low Temperature Environments, and Data Base Development. The participants of this symposium and a complete list of the talks presented are listed in the appendices

  20. Geochemical signatures of fluid paleo-transfer in fracture filling calcite from low permeability rock masses: examples taken from Bure's and Tournemire's site in France and northern Switzerland; Signatures geochimiques de paleocirculations aqueuses dans la calcite de remplissage de fracture de massifs argileux peu permeables et de leurs encaissants: exemples pris sur les sites de Bure, Tournemire et Suisse du nord

    Energy Technology Data Exchange (ETDEWEB)

    Lecocq, D

    2002-12-15

    Fractures in rock masses represent preferential path for fluid transfer and, as such, are the most efficient way for migration of radionuclides at a regional scale. The impact of fracturing on hydrogeological system is a major challenge for underground radioactive waste storage projects. In this context, geochemistry of fracture-filling calcite is used to better understand physical and chemical properties of palaeo-fluids. A new methodology has been developed to analyze Mg, Mn, Fe, Sr and Rare Earth Elements REE (La, Ce, Nd, Sm, Eu, Dy and Yb) in calcite by Secondary Ion Mass Spectrometry. Analyses of calcite crystals have been performed in fractures from Jurassic clays and limestones in France (Bure and Tournemire sites) and northern Switzerland (Mt Terri's tunnel and deep borehole). On each case, several geochemical signatures are observed, according to REE partitioning and Mn and Fe concentrations. In the Bure site, a dependence of calcite geochemistry from fracture host rock has been evidenced. On the other hand, speciation of REE in solution equilibrated with clayey or calcareous rocks at circum-neutral pH (7 to 8) is not significantly influenced by the media: speciation is dominated by carbonate species in both cases and phosphate complexes can modify heavy REE availability in relatively to light REE. These results point out that in fractures in clays, calcite crystallizes at equilibrium with a fluid expulsed during diagenesis from clay minerals, recording the effect of clays and accessory phases. In limestone fractures, calcite records a later event related to the past functioning of the present aquifer, and the fluid has reached equilibrium with the rock minerals. In secondary filling calcite from Toarcian Argilites faults close to Tournemire's tunnel, three successive generations of calcite are observed in an extensive fault, and a fourth in a compressive one. In Aalenian Opalinus Clays veins, comparison between existing isotopic data and Mn, Fe

  1. Geochemical constraints on the distribution of gas hydrates in the Gulf of Mexico

    Science.gov (United States)

    Paull, C.K.; Ussler, W.; Lorenson, T.; Winters, W.; Dougherty, J.

    2005-01-01

    Gas hydrates are common within near-seafloor sediments immediately surrounding fluid and gas venting sites on the continental slope of the northern Gulf of Mexico. However, the distribution of gas hydrates within sediments away from the vents is poorly documented, yet critical for gas hydrate assessments. Porewater chloride and sulfate concentrations, hydrocarbon gas compositions, and geothermal gradients obtained during a porewater geochemical survey of the northern Gulf of Mexico suggest that the lack of bottom simulating reflectors in gas-rich areas of the gulf may be the consequence of elevated porewater salinity, geothermal gradients, and microbial gas compositions in sediments away from fault conduits. 

  2. fracture systems in the younger granite rocks around fobur, northern ...

    African Journals Online (AJOL)

    Admin

    Bowden, P. and Turner, D.C., 1974. Peralkaline and associated ring complexes in the Nigerian-Niger. Province, West Africa. In: The Alkaline Rocks,. H. Serensen (ed) John Willey, New York. pp.330-351. Bowden, P., Whitley, J.E. and Van Breeman, O., 1989. Geochemical studies on the Younger Granites of northern Nigeria.

  3. Petrographic features, geochemical trends and mass balance ...

    African Journals Online (AJOL)

    Petrographic features, geochemical trends and mass balance computation, in relation to the evolution of anatectic migmatites in the granulite facies terrain of the Manalur area, Tamil Nadu, south India.

  4. Proceedings of 2. Brazilian Geochemical Congress

    International Nuclear Information System (INIS)

    1989-01-01

    Some works about geochemistry are presented, including themes about geochemical exploration, lithogeochemistry and isotope geochemistry, environmental geochemistry, analytical geochemistry, geochemistry of carbonatites and rare earth elements and organic geochemistry. (C.G.C.) [pt

  5. Collected radiochemical and geochemical procedures

    Energy Technology Data Exchange (ETDEWEB)

    Kleinberg, J [comp.

    1990-05-01

    This revision of LA-1721, 4th Ed., Collected Radiochemical Procedures, reflects the activities of two groups in the Isotope and Nuclear Chemistry Division of the Los Alamos National Laboratory: INC-11, Nuclear and radiochemistry; and INC-7, Isotope Geochemistry. The procedures fall into five categories: I. Separation of Radionuclides from Uranium, Fission-Product Solutions, and Nuclear Debris; II. Separation of Products from Irradiated Targets; III. Preparation of Samples for Mass Spectrometric Analysis; IV. Dissolution Procedures; and V. Geochemical Procedures. With one exception, the first category of procedures is ordered by the positions of the elements in the Periodic Table, with separate parts on the Representative Elements (the A groups); the d-Transition Elements (the B groups and the Transition Triads); and the Lanthanides (Rare Earths) and Actinides (the 4f- and 5f-Transition Elements). The members of Group IIIB-- scandium, yttrium, and lanthanum--are included with the lanthanides, elements they resemble closely in chemistry and with which they occur in nature. The procedures dealing with the isolation of products from irradiated targets are arranged by target element.

  6. Coupling of transport and geochemical models

    International Nuclear Information System (INIS)

    Noy, D.J.

    1986-01-01

    This report considers mass transport in the far-field of a radioactive waste repository, and detailed geochemical modelling of the ground-water in the near-field. A parallel approach to this problem of coupling transport and geochemical codes is the subject of another CEC report (ref. EUR 10226). Both studies were carried out in the framework of the CEC project MIRAGE. (Migration of radionuclides in the geosphere)

  7. The National Geochemical Survey; database and documentation

    Science.gov (United States)

    ,

    2004-01-01

    The USGS, in collaboration with other federal and state government agencies, industry, and academia, is conducting the National Geochemical Survey (NGS) to produce a body of geochemical data for the United States based primarily on stream sediments, analyzed using a consistent set of methods. These data will compose a complete, national-scale geochemical coverage of the US, and will enable construction of geochemical maps, refine estimates of baseline concentrations of chemical elements in the sampled media, and provide context for a wide variety of studies in the geological and environmental sciences. The goal of the NGS is to analyze at least one stream-sediment sample in every 289 km2 area by a single set of analytical methods across the entire nation, with other solid sample media substituted where necessary. The NGS incorporates geochemical data from a variety of sources, including existing analyses in USGS databases, reanalyses of samples in USGS archives, and analyses of newly collected samples. At the present time, the NGS includes data covering ~71% of the land area of the US, including samples in all 50 states. This version of the online report provides complete access to NGS data, describes the history of the project, the methodology used, and presents preliminary geochemical maps for all analyzed elements. Future editions of this and other related reports will include the results of analysis of variance studies, as well as interpretive products related to the NGS data.

  8. Contrasting Cu-Au and Sn-W Granite Metallogeny through the Zircon Geochemical and Isotopic Record

    Science.gov (United States)

    Gardiner, Nicholas; Hawkesworth, Chris; Robb, Laurence; Whitehouse, Martin; Roberts, Nick; Kirkland, Chris

    2017-04-01

    Magmatic genesis and evolution - mediated by geodynamic setting - exert a primary control on the propensity of granites to be metal fertile. A revolution in our understanding of these petrogenetic processes has been made through a range of mineral-based tools, most notably the common accessory mineral zircon. There is consequently considerable interest in whether the geochemical and isotopic compositions of zircon can be applied to metallogenic problems. The paired magmatic belts of Myanmar have broadly contrasting metallogenic affinities (Sn-W versus Cu-Au), and are interpreted to have formed on the accretionary margin of the subducting Neo-Tethys Ocean. They therefore present the opportunity to geochemically compare and contrast the zircon compositions in two end-member types of granite-hosted mineral deposits generated in collisional settings. We present an integrated zircon isotope (U-Pb, Lu-Hf, O) and trace element dataset that fingerprint: (a) source; (b) redox conditions; and (c) degree of fractionation. These variables all impact on magma fertility, and our key question to address is whether they can be reliably traced and calibrated within the Myanmar zircon record. Granitoid-hosted zircons from the I-type copper arc have juvenile ɛHf (+7 to +12) and mantle-like δ18O (5.3 ‰), whereas zircons from the S-type tin belt have low ɛHf (-7 to -13) and heavier δ18O (6.2-7.7 ‰). Plotting Hf versus U/Yb reaffirms that the tin belt magmas contain greater crustal contributions than the copper arc rocks. Links between whole rock Rb/Sr and zircon Eu/Eu* highlights that the latter can be used to monitor magma fractionation in systems that crystallize plagioclase (low Sr/Y). Ce/Ce* and Eu/Eu* in zircon are thus sensitive to redox and fractionation respectively, and can be used to evaluate the sensitivity of zircons to the metallogenic affinity of their host rocks. Tin contents that exceed the solubility limit are required in order to make a magmatic

  9. GEMAS: Geochemical Distribution of Thallium in European Soil

    Science.gov (United States)

    Demetriades, Alecos; Birke, Manfred; Reimann, Clemens; Mann, Alan; Kaminari, Maria

    2014-05-01

    Thallium concentrations are reported for the Portugal, Massif Central in France, and Bohemian Massif in Czechia). The median Tl concentration of Ap soil samples in the mobile metal ion (MMI®) partial extraction is 0.0006 mg/kg, and almost 50% of all samples report concentrations below detection. There is no pronounced difference between northern and southern Europe anymore, and the ice age limit of the last glaciation remains invisible. The main anomaly is related to the alkaline volcanic rocks in Italy. Many granitic intrusions are indicated by somewhat enhanced Tl concentrations (e.g., northern Portugal, north-western Spain, Massif Central in France, south-west England, and Bohemian Massif in Czechia). An interesting NE to SW anomalous pattern occurs in Scotland, partly following the Great Glen fault, and occurrences of granitic intrusions. Almost all of central Europe is marked by enhanced Tl values, and one wonders whether agriculture might have had an impact on this unusual pattern. Finally, the GEMAS data set defines the geochemical background variation of Tl in aqua regia and MMI® extraction for European agricultural and grazing land soil at the 2008 timeline.

  10. The formation of the Late Cretaceous Xishan Sn-W deposit, South China: Geochronological and geochemical perspectives

    Science.gov (United States)

    Zhang, Lipeng; Zhang, Rongqing; Hu, Yongbin; Liang, Jinlong; Ouyang, Zhixia; He, Junjie; Chen, Yuxiao; Guo, Jia; Sun, Weidong

    2017-10-01

    The Xishan Sn-W deposit is spatially related to K-feldspar granites in the Yangchun basin, western Guangdong Province, South China. LA-ICP-MS zircon U-Pb dating for the Xishan pluton defines an emplacement age of 79 Ma (78.1 ± 0.9 Ma; 79.0 ± 1.2 Ma; 79.3 ± 0.8 Ma), consistent with the mineralization age of the Xishan Sn-W deposit constrained by molybdenite Re-Os isochron age (79.4 ± 4.5 Ma) and LA-ICP-MS cassiterite U-Pb ages (78.1 ± 0.9 Ma and 79.0 ± 1.2 Ma) for the cassiterite-quartz vein. These indicate a close genetic relationship between the granite and Sn-W mineralization. The Xishan K-feldspar granites have geochemical characteristics of A-type granites, e.g., high total alkali (Na2O + K2O = 7.88-10.07 wt.%), high Ga/Al ratios (10000*Ga/Al > 2.6) and high Zr + Nb + Ce + Y concentrations (> 350 ppm). They are further classified as A2-type granites. The whole-rock isotopic compositions of K-feldspar granites (initial 87Sr/86Sr = 0.705256-0.706181; εNd(t) = - 5.4 to - 4.8) and zircon εHf(t) values (- 7.8 to 2.0) suggest a mixed magma source. The low zircon Ce4 +/Ce3 + ratios (12-88) of K-feldspar granites suggest low oxygen fugacities, which is key for enrichment of tin in primary magmas. The K-feldspar granites have experienced strong differentiation as indicated by their high Rb/Sr and K/Rb ratios, and low Nb/Ta and Zr/Hf ratios, which play an important role in ore-forming element transportation and concentration. A-type granite characteristics of the Xishan pluton show that it formed in an extensional environment. The high F and low Cl characteristics of the K-feldspar granite are most probably attributed to slab rollback. In the Late Cretaceous, the Xishan Sn-W deposit was located near the interaction of the circum-Pacific and the Tethys tectonic realms. Late Cretaceous Sn-W deposits, including the Xishan deposit, form an EW-trending belt from Guangdong to Yunnan Province in South China. This belt is in accordance with the direction of the Neo-Tethys

  11. The effects of physical and geochemical heterogeneities on hydro-geochemical transport and effective reaction rates

    Science.gov (United States)

    Atchley, Adam L.; Navarre-Sitchler, Alexis K.; Maxwell, Reed M.

    2014-09-01

    The role of coupled physical and geochemical heterogeneities in hydro-geochemical transport is investigated by simulating three-dimensional transport in a heterogeneous system with kinetic mineral reactions. Ensembles of 100 physically heterogeneous realizations were simulated for three geochemical conditions: 1) spatially homogeneous reactive mineral surface area, 2) reactive surface area positively correlated to hydraulic heterogeneity, and 3) reactive surface area negatively correlated to hydraulic heterogeneity. Groundwater chemistry and the corresponding effective reaction rates were calculated at three transverse planes to quantify differences in plume evolution due to heterogeneity in mineral reaction rates and solute residence time (τ). The model is based on a hypothetical CO2 intrusion into groundwater from a carbon capture utilization and storage (CCUS) operation where CO2 dissolution and formation of carbonic acid created geochemical dis-equilibrium between fluids and the mineral galena that resulted in increased aqueous lead (Pb2 +) concentrations. Calcite dissolution buffered the pH change and created conditions of galena oversaturation, which then reduced lead concentrations along the flow path. Near the leak kinetic geochemical reactions control the release of solutes into the fluid, but further along the flow path mineral solubility controls solute concentrations. Simulation results demonstrate the impact of heterogeneous distribution of geochemical reactive surface area in coordination with physical heterogeneity on the effective reaction rate (Krxn,eff) and Pb2 + concentrations within the plume. Dissimilarities between ensemble Pb2 + concentration and Krxn,eff are attributed to how geochemical heterogeneity affects the time (τeq) and therefore advection distance (Leq) required for the system to re-establish geochemical equilibrium. Only after geochemical equilibrium is re-established, Krxn,eff and Pb2 + concentrations are the same for all three

  12. The effects of physical and geochemical heterogeneities on hydro-geochemical transport and effective reaction rates.

    Science.gov (United States)

    Atchley, Adam L; Navarre-Sitchler, Alexis K; Maxwell, Reed M

    2014-09-01

    The role of coupled physical and geochemical heterogeneities in hydro-geochemical transport is investigated by simulating three-dimensional transport in a heterogeneous system with kinetic mineral reactions. Ensembles of 100 physically heterogeneous realizations were simulated for three geochemical conditions: 1) spatially homogeneous reactive mineral surface area, 2) reactive surface area positively correlated to hydraulic heterogeneity, and 3) reactive surface area negatively correlated to hydraulic heterogeneity. Groundwater chemistry and the corresponding effective reaction rates were calculated at three transverse planes to quantify differences in plume evolution due to heterogeneity in mineral reaction rates and solute residence time (τ). The model is based on a hypothetical CO2 intrusion into groundwater from a carbon capture utilization and storage (CCUS) operation where CO2 dissolution and formation of carbonic acid created geochemical dis-equilibrium between fluids and the mineral galena that resulted in increased aqueous lead (Pb(2+)) concentrations. Calcite dissolution buffered the pH change and created conditions of galena oversaturation, which then reduced lead concentrations along the flow path. Near the leak kinetic geochemical reactions control the release of solutes into the fluid, but further along the flow path mineral solubility controls solute concentrations. Simulation results demonstrate the impact of heterogeneous distribution of geochemical reactive surface area in coordination with physical heterogeneity on the effective reaction rate (Krxn,eff) and Pb(2+) concentrations within the plume. Dissimilarities between ensemble Pb(2+) concentration and Krxn,eff are attributed to how geochemical heterogeneity affects the time (τeq) and therefore advection distance (Leq) required for the system to re-establish geochemical equilibrium. Only after geochemical equilibrium is re-established, Krxn,eff and Pb(2+) concentrations are the same for all

  13. The geochemical atlas of Alaska, 2016

    Science.gov (United States)

    Lee, Gregory K.; Yager, Douglas B.; Mauk, Jeffrey L.; Granitto, Matthew; Denning, Paul; Wang, Bronwen; Werdon, Melanie B.

    2016-06-21

    A rich legacy of geochemical data produced since the early 1960s covers the great expanse of Alaska; careful treatment of such data may provide significant and revealing geochemical maps that may be used for landscape geochemistry, mineral resource exploration, and geoenvironmental investigations over large areas. To maximize the spatial density and extent of data coverage for statewide mapping of element distributions, we compiled and integrated analyses of more than 175,000 sediment and soil samples from three major, separate sources: the U.S. Geological Survey, the National Uranium Resource Evaluation program, and the Alaska Division of Geological & Geophysical Surveys geochemical databases. Various types of heterogeneity and deficiencies in these data presented major challenges to our development of coherently integrated datasets for modeling and mapping of element distributions. Researchers from many different organizations and disparate scientific studies collected samples that were analyzed using highly variable methods throughout a time period of more than 50 years, during which many changes in analytical techniques were developed and applied. Despite these challenges, the U.S. Geological Survey has produced a new systematically integrated compilation of sediment and soil geochemical data with an average sample site density of approximately 1 locality per 10 square kilometers (km2) for the entire State of Alaska, although density varies considerably among different areas. From that compilation, we have modeled and mapped the distributions of 68 elements, thus creating an updated geochemical atlas for the State.

  14. northern Tanzania

    African Journals Online (AJOL)

    Department of Zoology and Marine Biology, University of Dar es Salaam,. P O Box 35064, Dar es Salaam, Tanzania ... National Parks and neighbouring villages in northern Tanzania between 1993 and l996 (Kabigumila 1998a). Most of ..... International Congress ofChelonian Conservation. SOPTOM,. Gonfaron France. pp: ...

  15. A magmatic belt within the Neo-Tethyan suture zone and its role in the tectonic evolution of northern Turkey

    Science.gov (United States)

    Tüysüz, Okan; Dellaloǧlu, A. Aziz; Terzioǧlu, Nuri

    1995-03-01

    The Sakarya and Kırşehir continental fragments of Northern Turkey were separated by the Ankara-Erzincan ophiolitic suture zone, which is the remnant of the northern branch of the Neo-Tethys, namely the Ankara-Erzincan Ocean. This ocean branch opened during the Lias between these two continental fragments and started to close at the beginning of the Late Cretaceous, by the consumption of its floor, along two north-dipping subduction zones. The northern one was along the southern margin of the Sakarya Continent. As a result of this subduction zone, an ensialic magmatic arc, some fore-arc basins and a mélange belt developed from north to south on the Sakarya Continent. The second subduction zone, located to the south, gave rise to a mélange belt and an island arc developed with and on it. Hot-spot magmatics (seamounts), which were scraped from the subducting oceanic crust, also accreted into this ophiolitic-volcanic belt. At the end of the late Cretaceous, the central part of the Ankara-Erzincan Ocean closed due to the collision of the Kırşehir and the Sakarya continents. As a result of this collision, mélange belts and ensimatic arc volcanics formed the Ankara-Yozgat suture between these continental fragments.

  16. Robust statistics and geochemical data analysis

    International Nuclear Information System (INIS)

    Di, Z.

    1987-01-01

    Advantages of robust procedures over ordinary least-squares procedures in geochemical data analysis is demonstrated using NURE data from the Hot Springs Quadrangle, South Dakota, USA. Robust principal components analysis with 5% multivariate trimming successfully guarded the analysis against perturbations by outliers and increased the number of interpretable factors. Regression with SINE estimates significantly increased the goodness-of-fit of the regression and improved the correspondence of delineated anomalies with known uranium prospects. Because of the ubiquitous existence of outliers in geochemical data, robust statistical procedures are suggested as routine procedures to replace ordinary least-squares procedures

  17. Coupling of transport and geochemical models

    International Nuclear Information System (INIS)

    Noy, D.J.

    1985-01-01

    This contract stipulated separate pieces of work to consider mass transport in the far-field of a repository, and more detailed geochemical modelling of the groundwater in the near-field. It was envisaged that the far-field problem would be tackled by numerical solutions to the classical advection-diffusion equation obtained by the finite element method. For the near-field problem the feasibility of coupling existing geochemical equilibrium codes to the three dimensional groundwater flow codes was to be investigated. This report is divided into two sections with one part devoted to each aspect of this contract. (author)

  18. Northern Pintail

    Science.gov (United States)

    Clark, Robert G.; Fleskes, Joseph P.; Guyn, Karla L.; Haukos, David A.; Austin, Jane E.; Miller, Michael R.

    2014-01-01

    This medium-sized dabbling duck of slender, elegant lines and conservative plumage coloration is circumpolar in distribution and abundant in North America, with core nesting habitat in Alaska and the Prairie Pothole Region of southern Canada and the northern Great Plains. Breeders favor shallow wetlands interspersed throughout prairie grasslands or arctic tundra. An early fall migrant, the species arrives on wintering areas beginning in August, after wing molt, often forming large roosting and feeding flocks on open, shallow wetlands and flooded agricultural fields. The birds consume grains, marsh plant seeds, and aquatic invertebrates throughout fall and winter.Northern Pintails are among the earliest nesting ducks in North America, beginning shortly after ice-out in many northern areas. Individuals form new pair bonds each winter but are highly promiscuous during the nesting season, with mated and unmated males often involved in vigorous, acrobatic Pursuit Flights. Annual nest success and productivity vary with water conditions, predation, and weather. Females build nests on the ground, often far from water. Only the female incubates; her mate leaves shortly after incubation begins. Ducklings hatch together in one day, follow the female to water after a day in the nest, and fledge by July or August. Adults and ducklings consume mainly aquatic invertebrates during the breeding season.Predators and farming operations destroy many thousands of Northern Pintail nests annually; farming has also greatly reduced the amount of quality nesting cover available. Winter habitats are threatened by water shortages, agricultural development, contamination, and urbanization. Periods of extended drought in prairie nesting regions have caused dramatic population declines, usually followed by periods of recovery. Over the long term, however, the continental population of Northern Pintails has declined significantly from 6 million birds in the early 1970s to less than 3 million in

  19. An integrated geochemical and geoelectrical Investigation of an ...

    African Journals Online (AJOL)

    Ife Journal of Science ... Geochemical analysis of borehole soil samples for Total Petroleum Hydrocarbon (TPH), geoelectrical imaging and geotechnical sieve analysis were used to assess the ... Keywords: Geochemical Analysis, Geoelectric Imaging, Borehole Sampling, TPH Concentrations, Oil Spill, Contamination ...

  20. Taxonomic diversity dynamics of early cretaceous brachiopods and gastropods in the Azerbaijanian domains of the Lesser Caucasus (Neo-Tethys Ocean

    Directory of Open Access Journals (Sweden)

    Ruban Dmitry A.

    2014-01-01

    Full Text Available Palaeontological data available from the Azerbaijanian domains (Somkhit-Agdam, Sevan-Karabakh, and Miskhan-Kafan tectonic zones of the Lesser Caucasus permit reconstruction of the regional taxonomic diversity dynamics of two groups of Early Cretaceous marine benthic invertebrates. Stratigraphical ranges of 31 species and 14 genera of brachiopods and 40 species and 31 genera of gastropods are considered. The total number of species and genera of brachiopods was low in the Berriasian-Valanginian and then rose to peak in the Barremian. Then, the diversity declined in the Aptian, and brachiopods are not known regionally from the Albian. Gastropods appeared in the Hauterivian and experienced a strong radiation in the Barremian. The diversity of species and genera declined in the Aptian (with a minor radiation in the Middle Aptian, and no gastropods are reported from the Albian. Globally, the number of brachiopod genera remained stable through the Early Cretaceous, and the number of gastropod genera increased stepwise with the maximum in the Albian. The regional and global patterns of the diversity dynamics differed for the both groups of marine benthic invertebrates. The Barremian maximum of the taxonomic diversity coincided with the regional flourishing of reefal ecosystems. The taxonomic diversity dynamics of brachiopods in the Azerbaijanian domains of the Lesser Caucasus is very similar to those of the Northern Caucasus, which is an evidence of proximity of these regions during the Early Cretaceous.

  1. Appliance of geochemical engineering in radioactive waste disposal

    International Nuclear Information System (INIS)

    Li Shuang; Zhang Chengjiang; Ni Shijun; Li Kuanliang

    2008-01-01

    The basic foundation of applying geochemical engineering to control environment, common engineering models of disposal radioactive waste and the functions of the engineering barriers are introduced in this paper. The authors take the geochemical engineering barrier materiel research of a radioactive waste repository as an example to explain the appliance of geochemical engineering in the disposal of radioactive waste. And the results show that it can enhance the security of the nuclear waste repository if we use geochemical engineering barrier. (authors)

  2. Geochemical modelling baseline compositions of groundwater

    DEFF Research Database (Denmark)

    Postma, Diederik Jan; Kjøller, Claus; Andersen, Martin Søgaard

    2008-01-01

    dissolution (East Midlands, Valreas and Aveiro). Reactive transport models, employing the code PHREEQC, which included these geochemical processes and one-dimensional solute transport were able to duplicate the observed patterns in water quality. These models may provide a quantitative understanding...

  3. Geochemical fingerprints and pebbles zircon geochronology

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Earth System Science; Volume 125; Issue 7. Geochemical fingerprints and pebbles zircon geochronology: Implications for the provenance and tectonic setting of Lower Cretaceous sediments in the Zhucheng Basin (Jiaodong peninsula, North China). Jin-Long Ni Jun-Lai Liu Xiao-Ling Tang ...

  4. Kriging - a challenge in geochemical mapping

    Czech Academy of Sciences Publication Activity Database

    Štojdl, J.; Matys Grygar, Tomáš; Elznicová, J.; Popelka, J.; Váchová, T.; Hošek, Michal

    2017-01-01

    Roč. 19, APR (2017) ISSN 1607-7962. [EGU General Assembly 2017. 23.04.2017-28.04.2017, Vienna] Institutional support: RVO:61388980 Keywords : kriging * geochemical mapping Subject RIV: DD - Geochemistry http://meetingorganizer. copernicus .org/EGU2017/EGU2017-3615.pdf

  5. Discriminating four tectonic settings: Five new geochemical ...

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Earth System Science; Volume 115; Issue 5. Discriminating four tectonic settings: Five new geochemical diagrams for basic and ultrabasic volcanic rocks based on log–ratio transformation of major-element data. Surendra P Verma Mirna Guevara Salil Agrawal. Volume 115 Issue 5 October 2006 ...

  6. Association between physical and geochemical characteristics of ...

    African Journals Online (AJOL)

    ... as well as in waters relatively rich in uranium, rubidium, vanadium and manganese. It was clear that the occurrence of algae coincided with specific geological formations. These algae could act as indicator species of geology and heavy metals. Keywords: thermal springs, Limpopo Province, algae, diversity, geochemical ...

  7. Proceedings of 13. International Geochemical Exploration Symposium. 2. Brazilian Geochemical Congress

    International Nuclear Information System (INIS)

    1989-01-01

    Some works about geochemistry are presented, including themes about geochemical exploration, lithogeochemistry and isotope geochemistry, environmental geochemistry, analyical geochemistry, geochemistry of carbonatites and rare earth elements and organic geochemistry. (C.G.C.) [pt

  8. Alaska Geochemical Database (AGDB)-Geochemical data for rock, sediment, soil, mineral, and concentrate sample media

    Science.gov (United States)

    Granitto, Matthew; Bailey, Elizabeth A.; Schmidt, Jeanine M.; Shew, Nora B.; Gamble, Bruce M.; Labay, Keith A.

    2011-01-01

    The Alaska Geochemical Database (AGDB) was created and designed to compile and integrate geochemical data from Alaska in order to facilitate geologic mapping, petrologic studies, mineral resource assessments, definition of geochemical baseline values and statistics, environmental impact assessments, and studies in medical geology. This Microsoft Access database serves as a data archive in support of present and future Alaskan geologic and geochemical projects, and contains data tables describing historical and new quantitative and qualitative geochemical analyses. The analytical results were determined by 85 laboratory and field analytical methods on 264,095 rock, sediment, soil, mineral and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey (USGS) personnel and analyzed in USGS laboratories or, under contracts, in commercial analytical laboratories. These data represent analyses of samples collected as part of various USGS programs and projects from 1962 to 2009. In addition, mineralogical data from 18,138 nonmagnetic heavy mineral concentrate samples are included in this database. The AGDB includes historical geochemical data originally archived in the USGS Rock Analysis Storage System (RASS) database, used from the mid-1960s through the late 1980s and the USGS PLUTO database used from the mid-1970s through the mid-1990s. All of these data are currently maintained in the Oracle-based National Geochemical Database (NGDB). Retrievals from the NGDB were used to generate most of the AGDB data set. These data were checked for accuracy regarding sample location, sample media type, and analytical methods used. This arduous process of reviewing, verifying and, where necessary, editing all USGS geochemical data resulted in a significantly improved Alaska geochemical dataset. USGS data that were not previously in the NGDB because the data predate the earliest USGS geochemical databases, or were once excluded for programmatic reasons

  9. Geochemical characteristics and organic carbon sources within the ...

    Indian Academy of Sciences (India)

    This paper uses C isotopic methods coupled with other geochemical parameters to investigate differences in the geochemical characteristics and sources of organic C within the Nanpan and Beipan rivers, two upstream tributaries to the Xi River. 2. Geographic, hydrologic, and geochemical setting. The Nanpan and Beipan ...

  10. Geochemical baseline studies of soil in Finland

    Science.gov (United States)

    Pihlaja, Jouni

    2017-04-01

    The soil element concentrations regionally vary a lot in Finland. Mostly this is caused by the different bedrock types, which are reflected in the soil qualities. Geological Survey of Finland (GTK) is carrying out geochemical baseline studies in Finland. In the previous phase, the research is focusing on urban areas and mine environments. The information can, for example, be used to determine the need for soil remediation, to assess environmental impacts or to measure the natural state of soil in industrial areas or mine districts. The field work is done by taking soil samples, typically at depth between 0-10 cm. Sampling sites are chosen to represent the most vulnerable areas when thinking of human impacts by possible toxic soil element contents: playgrounds, day-care centers, schools, parks and residential areas. In the mine districts the samples are taken from the areas locating outside the airborne dust effected areas. Element contents of the soil samples are then analyzed with ICP-AES and ICP-MS, Hg with CV-AAS. The results of the geochemical baseline studies are published in the Finnish national geochemical baseline database (TAPIR). The geochemical baseline map service is free for all users via internet browser. Through this map service it is possible to calculate regional soil baseline values using geochemical data stored in the map service database. Baseline data for 17 elements in total is provided in the map service and it can be viewed on the GTK's web pages (http://gtkdata.gtk.fi/Tapir/indexEN.html).

  11. Geochemical Signature of Amazon Tropical Rainforest Soils

    Directory of Open Access Journals (Sweden)

    José João Lelis Leal de Souza

    2018-02-01

    Full Text Available ABSTRACT: Evaluating soil geochemical diversity in the Amazon Basin has been a challenge largely because most study sites have been at the edge of the basin and it is difficult to get samples in such a region. Here we show that even among the most weathered soils, physicochemical soil properties express lithology. Our results are based on topsoil samples collected from different locations in minimally disturbed areas in the state of Amazonas, Brazil. Soil properties were measured using methods which are suitable for highly developed soils. The Chemical Index Alteration and Weathering Index of Parker was calculated based on the content of metal(loids in soils determined by X-ray fluorescence. Descriptive statistics, Pearson correlation, and Principal Component Analysis (PCA were performed on data. In general, Amazon rainforest soils are more deeply weathered than soils in other Brazilian biomes and tropical rainforests in Asia and Africa. The high coefficient of variation of metal(loid contents express pedogenesis and parent material diversity. Correlation analysis indicated that the tri-pentavalent elements are strongly associated with Al and Fe contents in the topsoil. In contrast, mono-divalent elements are correlated with sand and silt fractions. According to PCA, five soil groups with defined geochemical compositions and degrees of weathering could be identified: i acidic sandy podzolized soils; ii acidic loamy ferralitic soils with the highest content of tri-pentavalent ions; iii acidic clayey kaolinitic soils with low metal(loid contents; iv acidic loamy kaolinitic soils with low metal(loid contents; and v silty neutral 2:1 clay soils. This study is the first effort to analyze the geochemical diversity in Amazon rainforest soils. These data are extremely valuable in determining the geochemical background for these soil types and this region. Geochemical variability can be predicted to some extent by lithology and pedogenesis, which can be

  12. Geochemical modelling: what phenomena are missing

    International Nuclear Information System (INIS)

    Jacquier, P.

    1989-12-01

    In the framework of safety assessment of radioactive waste disposal, retention phenomena are usually taken into account by the Kd concept. It is well recognized that this concept is not enough for safety assessment models, because of the several and strong assumptions which are involved in this kind of representation. One way to have a better representation of the retention phenomena, is to substitute for this Kd concept an explicit description of geochemical phenomena and then couple transport codes with geochemical codes in a fully or a two-step procedure. We use currently such codes, but the scope of this paper is to display the limits today of the geochemical modelling in connection with sites analysis for deep disposal. In this paper, we intend to give an overview of phenomena which are missing in the geochemical models, or which are not completely introduced in the models. We can distinguish, on one hand phenomena for which modelling concepts exist such as adsorption/desorption and, on the other hand, phenomena for which modelling concepts do not exist for the moment such as colloids, and complexation by polyelectrolyte solutions (organics). Moreover we have to take care of very low concentrations of radionuclides, which can be expected from the leaching processes in the repository. Under those conditions, some reactions may not occur. After a critical review of the involved phenomena, we intend to stress the main directions of the wishful evolution of the geochemical modelling. This evolution should improve substantially the quality of the above-mentioned site assessments

  13. Geochemical engineering problem identification and program description. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Crane, C.H.; Kenkeremath, D.C.

    1981-05-01

    The Geochemical Engineering Program has as its goal the improvement of geochemical fluid management techniques. This document presents the strategy and status of the Geochemical Engineering Program. The magnitude and scope of geochemical-related problems constraining geothermal industry productivity are described. The goals and objectives of the DGE Geochemical Engineering Program are defined. The rationale and strategy of the program are described. The structure, priorities, funding, and management of specific elements within the program are delineated, and the status of the overall program is presented.

  14. Application of cluster analysis to geochemical compositional data for identifying ore-related geochemical anomalies

    Science.gov (United States)

    Zhou, Shuguang; Zhou, Kefa; Wang, Jinlin; Yang, Genfang; Wang, Shanshan

    2017-12-01

    Cluster analysis is a well-known technique that is used to analyze various types of data. In this study, cluster analysis is applied to geochemical data that describe 1444 stream sediment samples collected in northwestern Xinjiang with a sample spacing of approximately 2 km. Three algorithms (the hierarchical, k-means, and fuzzy c-means algorithms) and six data transformation methods (the z-score standardization, ZST; the logarithmic transformation, LT; the additive log-ratio transformation, ALT; the centered log-ratio transformation, CLT; the isometric log-ratio transformation, ILT; and no transformation, NT) are compared in terms of their effects on the cluster analysis of the geochemical compositional data. The study shows that, on the one hand, the ZST does not affect the results of column- or variable-based (R-type) cluster analysis, whereas the other methods, including the LT, the ALT, and the CLT, have substantial effects on the results. On the other hand, the results of the row- or observation-based (Q-type) cluster analysis obtained from the geochemical data after applying NT and the ZST are relatively poor. However, we derive some improved results from the geochemical data after applying the CLT, the ILT, the LT, and the ALT. Moreover, the k-means and fuzzy c-means clustering algorithms are more reliable than the hierarchical algorithm when they are used to cluster the geochemical data. We apply cluster analysis to the geochemical data to explore for Au deposits within the study area, and we obtain a good correlation between the results retrieved by combining the CLT or the ILT with the k-means or fuzzy c-means algorithms and the potential zones of Au mineralization. Therefore, we suggest that the combination of the CLT or the ILT with the k-means or fuzzy c-means algorithms is an effective tool to identify potential zones of mineralization from geochemical data.

  15. Geochemical Investigation of Clay Minerals in Marte, Borno State, Nigeria

    Directory of Open Access Journals (Sweden)

    F. D. Adams

    2017-10-01

    Full Text Available Clay deposit collected from various locations in Marte (Northern Borno, were studied to determine their physical and chemical characteristics in order to evaluate their suitability for industrial uses. Major and trace element analyses were carried out on clay samples using Inductively Couple Plasma-Optical Emission Spectrometry (ICP-OES and X- Ray Fluorescence (XRF. The result of the chemical analysis of the ten (10 samples collected showed significant amounts of SiO2 and Al2O3. Silica content ranges from 51.48 to 62.44 % while alumina varies from 12.49 to 19.00 %. The calcium oxide ranges from 1.17 to 3.39 %, Na2O ranges from 1.1 to 8.61 %, K2O from 1.54 to 3.66 %, MgO varies from 0.04 to0.14 %, Fe2O3 varies from 0.3 to 2.7 % and MnO ranges from 0.01 to 1.03 %. The result showed that the clays are mainly smectite with quartz and felspar as the main non-clay minerals. Generally, the geochemical results of the samples do not meet the standard for industrial utilization when compared to the Industrial specifications. However, for industrial utilization, some of the clay samples may be used after necessary beneficiations.

  16. From palaeotectonics to neotectonics in the Neotethys realm: The importance of kinematic decoupling and inherited structural grain in SW Anatolia (Turkey)

    Science.gov (United States)

    ten Veen, J. H.; Boulton, S. J.; Alçiçek, M. C.

    2009-07-01

    In order to asses young, i.e. "neotectonic" fault kinematics and the relation with plate-tectonic processes in SW Turkey we focused on the questions: 1) what produced the structural grain, i.e. how and when are faults generated, 2) what was/is the kinematic behaviour of these faults and 3) during which period(s) were these faults active? Firstly, the distribution of faults has been investigated using a lineament analysis performed on satellite imagery and digital elevation models. We define five main tectonic domains in SW Turkey: 1 and 2) the Northern and Southern Western Anatolian extensional provinces; 3) the eastern Hellenic arc (including Rhodes Island and the submarine Anaximander mountains); 4) The Lycian Taurides and 5) the western limb of the Isparta Angle. Lineament analysis reveals dominance of three lineament groups, i.e. NNE-, ENE-, and WNW-trending, in all identified domains. Variations in the relative importance of lineament groups exist and are attributed to the specific tectonic evolution of each domain. A synthesis of recently published field data shows that the onset of activity of related fault groups is neither synchronous, nor uniform. The "structural grain" for the neotectonic deformation in SW Turkey is formed during the last stage of palaeotectonic deformation (stage 1), which is dominated by the onset of the Menderes Massif exhumation along a top-N major detachment, the Datça break-away fault [Seyitoğlu, G., Işık, V., and Çemen, İ., 2004. Complete Tertiary exhumation history of the Menderes massif, western Turkey: an alternative working hypothesis. Terra Nova, 16, 358-364.], and related SE-ward sliding of the Lycian Nappes in the footwall of this fault. This stage is characterized by spatially variable types of deformation that are delineated by, from NW to SE, the Datça Fault around the Menderes-Lycian contact zone and the Lycian frontal thrust zone, respectively. The kinematic decoupling along these structures explains the co

  17. Geochemical prospecting in Morrinhos area - Ceara

    International Nuclear Information System (INIS)

    Andrade, V.A. de; Campos, M. de; Braga, A. de P.G.

    1982-01-01

    Morrinhos ring-shaped structure has been considered by several authors as reflecting a non-rising pluton, related to the regional uranium mineralization. NUCLEBRAS carried out a geochemical prospecting in the area, (through soil and stream samples), to better understand the relationship between the structure and the ore bodies. The 229 samples were all analysed for 33 trace-elements, using optical spectrography and X-ray fluorescence methods. (Author) [pt

  18. Summary report on geochemical barrier special study

    International Nuclear Information System (INIS)

    1988-12-01

    Long-term management of uranium mill tailings must provide assurance that soluble contaminants will not migrate beyond the Point of Compliance. Conventional management alternatives provide containment through the use of physical barriers which are designed to prevent migration of water through the tailings pile. An alternative is to geochemically modify the tailings to immobilize the contaminants. This investigation examined three potential geochemical modifiers to determine their ability to immobilize inorganic groundwater contaminants found in uranium mill tailings. These modifiers were hydrated lime (Ca(OH) 2 ), limestone (CaCO 3 ), and a sphaegnum peat moss. This investigation focused on both the geochemical interactions between the tailings and the modifiers, and the effects the modifiers had on the physical strength of the tailings. The geochemical investigations began with characterization of the tailings by X-ray diffraction and scanning electron microscopy. This was followed by batch leaching experiments in which various concentrations of each modifier were added to tailings in shaker flasks and allowed to come to equilibrium. Finally, column experiments were conducted to simulate flow through a tailings pile. The results show that all of the modifiers were at least moderately effective at immobilizing most of the groundwater contaminants of concern at uranium mill tailings sites. Hydrated lime was able to achieve 90 percent concentration reduction of arsenic, cadmium, selenium, uranium, and sulfate when added at a two percent concentration. Limestone was somewhat less effective and peat removed greater than 90 percent of arsenic, lead, uranium, and sulfate at a one percent concentration. The column tests showed that kinetic and/or mass transfer limitations are important and that sufficient time must be allowed for the immobilization reactions to occur

  19. Synthesizing Earth's geochemical data for hydrogeochemical analysis

    Science.gov (United States)

    Brantley, S. L.; Kubicki, J.; Miller, D.; Richter, D.; Giles, L.; Mitra, P.

    2007-12-01

    For over 200 years, geochemical, microbiological, and chemical data have been collected to describe the evolution of the surface earth. Many of these measurements are data showing variations in time or in space. To forward predict hydrologic response to changing tectonic, climatic, or anthropogenic forcings requires synthesis of these data and utilization in hydrogeochemical models. Increasingly, scientists are attempting to synthesize such data in order to make predictions for new regions or for future time periods. However, to make such complex geochemical data accessible requires development of sophisticated cyberinfrastructures that both invite uploading as well as usage of data. Two such cyberinfrastructure (CI) initiatives are currently developing, one to invite and promote the use of environmental kinetics data (laboratory time course data) through ChemxSeer, and the other to invite and promote the use of spatially indexed geochemical data for the Earth's Critical Zone through CZEN.org. The vision of these CI initiatives is to provide cyber-enhanced portals that encourage domain scientists to upload their data before publication (in private cyberspace), and to make these data eventually publicly accessible (after an embargo period). If the CI can be made to provide services to the domain specialist - e.g. to provide data analysis services or data comparison services - we envision that scientists will upload data. In addition, the CI can promote the use and comparison of datasets across disciplines. For example, the CI can facilitate the use of spatially indexed geochemical data by scientists more accustomed to dealing with time-course data for hydrologic flow, and can provide user-friendly interfaces with CI established to facilitate the use of hydrologic data. Examples of the usage of synthesized data to predict soil development over the last 13ky and its effects on active hydrological flow boundaries in surficial systems will be discussed for i) a N

  20. Sharp fronts within geochemical transport problems

    International Nuclear Information System (INIS)

    Grindrod, P.

    1995-01-01

    The authors consider some reactive geochemical transport problems in groundwater systems. When incoming fluid is in disequilibrium with the mineralogy sharp transition fronts may develop. They show that this is a generic property for a class of systems where the timescales associated with reaction and diffusion phenomena are much shorter than those associated with advective transport. Such multiple timescale problems are relevant to a variety of processes in natural systems: mathematically methods of singular perturbation theory reduce the dimension of the problems to be solved locally. Furthermore, they consider how spatial heterogeneous mineralogy can impact upon the propagation of sharp geochemical fronts. The authors developed an asymptotic approach in which they solve equations for the evolving geometry of the front and indicate how the non-smooth perturbations due to natural heterogeneity of the mineralogy on underlying ground water flow field are balanced against the smoothing effect of diffusion/dispersive processes. Fronts are curvature damped, and the results here indicate the generic nature of separate front propagation within both model (idealized) and natural (heterogeneous) geochemical systems

  1. The role of geochemical prospecting in phased uranium exploration. A case history

    International Nuclear Information System (INIS)

    Smith, A.Y.; Armour-Brown, A.; Olsen, H.; Lundberg, B.; Niesen, P.L.

    1976-01-01

    The commencement of a UNDP/IAEA uranium exploration project in Northern Greece in 1971 offered the opportunity to test and apply an exploration strategy based on a phased use of geochemical exploration methods. The paper reviews the exploration task, the strategy selected, and some results obtained. The project area (22000 km 2 ) was explored by car-borne survey, covering 15000 km of road and track. Concurrently, a stream sediment geochemical survey was begun which aimed at a nominal sample density of one sample per square kilometre. Samples were analysed for copper, lead, zinc, silver, cobalt, nickel, molybdenum, mercury and manganese, in addition to uranium. At each site, a general reading of radioactivity was made, and treated like another element analysis. The reconnaissance programme succeeded in delineating a number of important target areas, varying in size from a few to several hundred square kilometres with significant uranium potential. Follow-up and detailed surveys have been carried out over a number of these, including a sedimentary basin of continental deposits which have been found to contain occurrences of secondary uranium minerals, and two areas in which granitic bodies have been found to have fracture systems and secondary uranium mineralization of economic interest. In no case has sufficient work been yet done to prove economic deposits of uranium. The phased strategy used has, however, already been demonstrated to be effective in the environment of northern Greece. (author)

  2. Landscape-geochemical factors of deposit formation

    International Nuclear Information System (INIS)

    Batulin, S.G.

    1980-01-01

    Effect of landscape-geochemical factors on hydrogenic formation of uranium ores is considered. The primary attention is paid to finding reasons for hydrogeochemical background increase in the regions of arid climate. Problems of uranium distribution in alluvial landscapes, hydrogeochemical regime of ground waters, reflecting the effect of waters of the zone of aeration are revealed. Chemical composition of porous solutions in the zone of aeration, as well as historical geochemindstry of landscape a its role from the view point of uranium solution formation in the arid zone are considered [ru

  3. sedimentological and geochemical characteristics of outcrop ...

    African Journals Online (AJOL)

    USER

    0.17. 0.70. 1.13. 1.37. -. CIA (%). 73.00. 76.00. 74.00. 85.00. 99.00. 95.00. 98.00. 90.00. 96.00. 77.00. 99.00. 96.00. 94.00. -. CIW (%). 78.00. 87.00. 83.00. 97.00. 100.00. 99.00. 100. 99.00. 99.00. 86.00. 00. 99.00. 100.00. -. Nton and Adamolekun: Sedimentological and Geochemical Characteristics of Outcrop Sediments ...

  4. DNA-based methods of geochemical prospecting

    Energy Technology Data Exchange (ETDEWEB)

    Ashby, Matthew [Mill Valley, CA

    2011-12-06

    The present invention relates to methods for performing surveys of the genetic diversity of a population. The invention also relates to methods for performing genetic analyses of a population. The invention further relates to methods for the creation of databases comprising the survey information and the databases created by these methods. The invention also relates to methods for analyzing the information to correlate the presence of nucleic acid markers with desired parameters in a sample. These methods have application in the fields of geochemical exploration, agriculture, bioremediation, environmental analysis, clinical microbiology, forensic science and medicine.

  5. Kriging - a challenge in geochemical mapping

    Science.gov (United States)

    Stojdl, Jiri; Matys Grygar, Tomas; Elznicova, Jitka; Popelka, Jan; Vachova, Tatina; Hosek, Michal

    2017-04-01

    Geochemists can easily provide datasets for contamination mapping thanks to recent advances in geographical information systems (GIS) and portable chemical-analytical instrumentation. Kriging is commonly used to visualise the results of such mapping. It is understandable, as kriging is a well-established method of spatial interpolation. It was created in 1950's for geochemical data processing to estimate the most likely distribution of gold based on samples from a few boreholes. However, kriging is based on the assumption of continuous spatial distribution of numeric data that is not realistic in environmental geochemistry. The use of kriging is correct when the data density is sufficient with respect to heterogeneity of the spatial distribution of the geochemical parameters. However, if anomalous geochemical values are focused in hotspots of which boundaries are insufficiently densely sampled, kriging could provide misleading maps with the real contours of hotspots blurred by data smoothing and levelling out individual (isolated) but relevant anomalous values. The data smoothing can thus it results in underestimation of geochemical extremes, which may in fact be of the greatest importance in mapping projects. In our study we characterised hotspots of contamination by uranium and zinc in the floodplain of the Ploučnice River. The first objective of our study was to compare three methods of sampling: random (based on stochastic generation of sampling points), systematic (square grid) and judgemental sampling (based on judgement stemming from principles of fluvial deposition) as the basis for pollution maps. The first detected problem in production of the maps was the reduction of the smoothing effect of kriging using appropriate function of empirical semivariogram and setting the variation of at microscales smaller than the sampling distances to minimum (the "nugget" parameter of semivariogram). Exact interpolators such as Inverse Distance Weighting (IDW) or Radial

  6. Is formamide a geochemically plausible prebiotic solvent?

    Science.gov (United States)

    Bada, Jeffrey L; Chalmers, John H; Cleaves, H James

    2016-07-27

    From a geochemical perspective, significant amounts of pure formamide (HCONH2) would have likely been rare on the early Earth. There may have been mixed formamide-water solutions, but even in the presence of catalyst, solutions with >20 weight% water in formamide would not have produced significant amounts of prebiotic compounds. It might be feasible to produce relatively pure formamide by a rare occurrence of freezing formamide/water mixtures at temperatures lower than formamide's freezing point (2.55 °C) but greater than the freezing point of water. Because of the high density of formamide ice it would have sunk and accumulated at the bottom of the solution. If the remaining water froze on the surface of this ice, and was then removed by a sublimation-ablation process, a small amount of pure formamide ice might have been produced. In addition a recent report suggested that ∼85 weight% formamide could be prepared by a geochemical type of fractional distillation process, offering another possible route for prebiotic formamide production.

  7. Geochemical signature of radioactive waste: oil NORM

    International Nuclear Information System (INIS)

    Costa, Gilberto T. de Paula; Costa-de-Moura, Jorge; Gomes, Carlos de Almeida; Sampaio, Emidio A. Lopes

    2017-01-01

    The Brazilian Nuclear Agency (CNEN) rules all nuclear activity in Brazil as demanded by the Federal Constitution, articles 21, XXIII, and 177, V, and by the Federal Acts 4.118/62 and 10.308/2001. Therefore, the CNEN is responsible for any radioactive waste disposal in the country. Oil Naturally Occurring Radioactive Materials (Oil NORM) in this paper refers to waste coming from oil exploration. Oil NORM has called much attention during the last decades, mostly because it is not possible to determine its primary source due to the actual absence of regulatory control mechanism. There is no efficient regulatory tool which allows determining the origin of such NORM wastes even among those facilities under regulatory control. This fact may encourage non-authorized radioactive material transportation, smuggling and terrorism. The aim of this project is to provide a geochemical signature for each oil NORM waste using its naturally occurring isotopic composition to identify its origin. The here proposed method is a specific geochemical modeling of oil sludge NORM samples which are analyzed for radioisotopes normally present in oil pipes, such as 228 Ac, 214 Bi and 214 Pb. The activity ratios are plotted in scatter diagrams. This method was successfully tested with data of different sources obtained from analysis reports from the Campos Basin/Brazil and from literature. (author)

  8. Forensic Analysis using Geological and Geochemical Techniques

    Science.gov (United States)

    Hoogewerff, J.

    2009-04-01

    Due to the globalisation of legal (and illegal) trade there is an increasing demand for techniques which can verify the geographical origin and transfer routes of many legal and illegal commodities and products. Although geological techniques have been used in forensic investigations since the emergence of forensics as a science in the late eighteen hundreds, the last decade has seen a marked increase in geo-scientists initiating concept studies using the latest analytical techniques, including studying natural abundance isotope variations, micro analysis with laser ablation ICPMS and geochemical mapping. Most of the concept studies have shown a good potential but uptake by the law enforcement and legal community has been limited due to concerns about the admissibility of the new methods. As an introduction to the UGU2009 session "Forensic Provenancing using Geological and Geochemical Techniques" I will give an overview of the state of the art of forensic geology and the issues that concern the admissibility of geological forensic evidence. I will use examples from the NITECRIME and FIRMS networks, the EU TRACE project and other projects and literature to illustrate the important issues at hand.

  9. Geochemical signature of radioactive waste: oil NORM

    Energy Technology Data Exchange (ETDEWEB)

    Costa, Gilberto T. de Paula; Costa-de-Moura, Jorge; Gomes, Carlos de Almeida; Sampaio, Emidio A. Lopes, E-mail: gilberto.costa@cnen.gov.br, E-mail: jcmoura@cnen.gov.br, E-mail: cgomes@cnen.gov.br [Comissao Nacional de Energia Nuclear (CNEN), Rio de Janeiro, RJ (Brazil). Div. de Controle de Rejeitos e Transporte de Materiais Radioativos

    2017-07-01

    The Brazilian Nuclear Agency (CNEN) rules all nuclear activity in Brazil as demanded by the Federal Constitution, articles 21, XXIII, and 177, V, and by the Federal Acts 4.118/62 and 10.308/2001. Therefore, the CNEN is responsible for any radioactive waste disposal in the country. Oil Naturally Occurring Radioactive Materials (Oil NORM) in this paper refers to waste coming from oil exploration. Oil NORM has called much attention during the last decades, mostly because it is not possible to determine its primary source due to the actual absence of regulatory control mechanism. There is no efficient regulatory tool which allows determining the origin of such NORM wastes even among those facilities under regulatory control. This fact may encourage non-authorized radioactive material transportation, smuggling and terrorism. The aim of this project is to provide a geochemical signature for each oil NORM waste using its naturally occurring isotopic composition to identify its origin. The here proposed method is a specific geochemical modeling of oil sludge NORM samples which are analyzed for radioisotopes normally present in oil pipes, such as {sup 228}Ac, {sup 214}Bi and {sup 214}Pb. The activity ratios are plotted in scatter diagrams. This method was successfully tested with data of different sources obtained from analysis reports from the Campos Basin/Brazil and from literature. (author)

  10. A geochemical atlas of North Carolina, USA

    Science.gov (United States)

    Reid, J.C.

    1993-01-01

    A geochemical atlas of North Carolina, U.S.A., was prepared using National Uranium Resource Evaluation (NURE) stream-sediment data. Before termination of the NURE program, sampling of nearly the entire state (48,666 square miles of land area) was completed and geochemical analyses were obtained. The NURE data are applicable to mineral exploration, agriculture, waste disposal siting issues, health, and environmental studies. Applications in state government include resource surveys to assist mineral exploration by identifying geochemical anomalies and areas of mineralization. Agriculture seeks to identify areas with favorable (or unfavorable) conditions for plant growth, disease, and crop productivity. Trace elements such as cobalt, copper, chromium, iron, manganese, zinc, and molybdenum must be present within narrow ranges in soils for optimum growth and productivity. Trace elements as a contributing factor to disease are of concern to health professionals. Industry can use pH and conductivity data for water samples to site facilities which require specific water quality. The North Carolina NURE database consists of stream-sediment samples, groundwater samples, and stream-water analyses. The statewide database consists of 6,744 stream-sediment sites, 5,778 groundwater sample sites, and 295 stream-water sites. Neutron activation analyses were provided for U, Br, Cl, F, Mn, Na, Al, V, Dy in groundwater and stream water, and for U, Th, Hf, Ce, Fe, Mn, Na, Sc, Ti, V, Al, Dy, Eu, La, Sm, Yb, and Lu in stream sediments. Supplemental analyses by other techniques were reported on U (extractable), Ag, As, Ba, Be, Ca, Co, Cr, Cu, K, Li, Mg, Mo, Nb, Ni, P, Pb, Se, Sn, Sr, W, Y, and Zn for 4,619 stream-sediment samples. A small subset of 334 stream samples was analyzed for gold. The goal of the atlas was to make available the statewide NURE data with minimal interpretation to enable prospective users to modify and manipulate the data for their end use. The atlas provides only

  11. mineralogical and geochemical trends in lateritic weathering profiles ...

    African Journals Online (AJOL)

    Three soil profiles on the basement rocks in Awa-Oru-Ijebu Igbo area of southwestern Nigeria were investigated for the ... Geochemical data further revealed significant enrichment of Al2O3 and Fe2O3 in the laterite profile compared with the parent rock, ...... Mineralogical, Geochemical and Economic. Appraisal of some clay ...

  12. Behaviour of nature and technogenic radioisotopes in buried geochemical barriers

    International Nuclear Information System (INIS)

    Kuznetsov, V.A.; Onoshko, M.P.; Generalova, V.A.

    1998-01-01

    Behaviour of potassium 40, radium 226, thorium 232, strontium 90 and cesium 137 on geochemical barriers connected with buried soils and cut-off meander sediments of the Holocene age of the Sozh river valley are examined. Some sides of the barrier geochemical structure caused by syngeneic and epigenetic processes have been taken into consideration

  13. Methodological approaches in estimating anomalous geochemical field structure

    International Nuclear Information System (INIS)

    Gavrilov, R; Rudmin, M

    2015-01-01

    Mathematical statistic methods were applied to analyze the core samples from vertical expendable wells in Chertovo Koryto gold ore field. The following methods were used to analyse gold in samples: assay tests and atomic absorption method (AAS), while emission spectrum semiquantative method was applied to identify traces. The analysis of geochemical association distribution in one central profile demonstrated that bulk metasomatic aureoles are characteristic of concentric zonal structure. The distribution of geochemical associations is correlated to the hydrothermal stages of mineral formation identified in this deposit. It was proved that the processed geochemical data by factor and cluster analyses provided additional information on the anomalous geochemical field structure in gold- bearing black-shale strata. Such methods are effective tools in interpretating specific features of geochemical field structures in analogous potential ore-bearing areas

  14. Geochemical characteristics of Proterozoic granite magmatism from ...

    Indian Academy of Sciences (India)

    T Yellappa

    2018-03-06

    Mar 6, 2018 ... rocks occur near the transition zone around Krish- nagiri in the northern part of Tamil Nadu ... Archean and Neoproterozoic high-grade metamor- phic and magmatic rocks. The important ... Western Dharwar Craton, EDC: Eastern Dharwar Craton, Tz: Transition Zone. Location of the granite plutons are also.

  15. Mineralogical and Geochemical Characterization of Clay and ...

    African Journals Online (AJOL)

    Abstract. The paper tries to characterize and evaluate clay, lacustrine and diatomaceous earth deposits of Lake Ashenge basin, near Koram, northern Ethiopia and comment on its industrial implications. The country rocks are dominantly basalts and basaltic agglomerates overlain by minor amounts of rhyolite and ignimbrite.

  16. Mineralogical and Geochemical Characterization of Clay and ...

    African Journals Online (AJOL)

    Bheema

    ABSTRACT. The paper tries to characterize and evaluate clay, lacustrine and diatomaceous earth deposits of. Lake Ashenge basin, near Koram, northern Ethiopia and comment on its industrial implications. The country rocks are dominantly basalts and basaltic agglomerates overlain by minor amounts of rhyolite and ...

  17. GEOCHEMICAL CONTROLS ON NUCLEAR MAGNETIC RESONANCE MEASUREMENTS

    International Nuclear Information System (INIS)

    Knight, Rosemary

    2008-01-01

    Proton nuclear magnetic resonance (NMR) is used in the Earth Sciences as a means of obtaining information about the molecular-scale environment of fluids in porous geological materials. Laboratory experiments were conducted to advance our fundamental understanding of the link between the NMR response and the geochemical properties of geological materials. In the first part of this research project, we studied the impact of both the surface-area-to-volume ratio (S/V) of the pore space and the surface relaxivity on the NMR response of fluids in sand-clay mixtures. This study highlighted the way in which these two parameters control our ability to use NMR measurements to detect and quantify fluid saturation in multiphase saturated systems. The second part of the project was designed to explore the way in which the mineralogic form of iron, as opposed to simply the concentration of iron, affects the surface relaxation rate and, more generally, the NMR response of porous materials. We found that the magnitude of the surface relaxation rate was different for the various iron-oxide minerals because of changes in both the surface-area-to-volume ratio of the pore space, and the surface relaxivity. Of particular significance from this study was the finding of an anomalously large surface relaxivity of magnetite compared to that of the other iron minerals. Differences in the NMR response of iron minerals were seen in column experiments during the reaction of ferrihydrite-coated quartz sand with aqueous Fe(II) solutions to form goethite, lepidocrocite and magnetite; indicating the potential use of NMR as a means of monitoring geochemical reactions. The final part of the research project investigated the impact of heterogeneity, at the pore-scale, on the NMR response. This work highlighted the way in which the geochemistry, by controlling the surface relaxivity, has a significant impact on the link between NMR data and the microgeometry of the pore space.

  18. Northern forests, Chapter 7

    Science.gov (United States)

    L.H. Pardo; C.L. Goodale; E.A. Lilleskov; L.H. Geiser

    2011-01-01

    The Northern Forests ecological region spans much of Canada, from Saskatchewan to Newfoundland; its southern portion extends into the northern United States (CEC 1997). The U.S. component includes the northern hardwood and spruce-fir forest types and encompasses parts of the Northeast (mountainous regions in Pennsylvania, New York, New Jersey, Connecticut,...

  19. Geochemical Trends are a Window on the Processes that Generate Volcano Fields

    Science.gov (United States)

    Smith, I. E.; McGee, L.; Brenna, M.

    2009-12-01

    A first order determinant of the nature of a magmatic system is magma flux rate. Small scale basaltic volcanic systems are characterized by low rates of magma production and dispersed plumbing leading to their expression at the surface as fields of small ‘monogenetic’ volcanoes. Because of the very small magma volumes and rapid ascent rates involved there is little interaction with conduit surroundings and this means that the chemical composition of magmas that reach the surface carry the signature of the deep seated process that formed them. Detailed sampling through the stratigraphic sequence in some monogenetic cones of the Auckland Volcanic Field in northern New Zealand and on Jeju Island in Korea has revealed systematic compositional variations that reflect fractionation process acting on magma bodies close to their source. We observe simple trends indicating unitary processes in some volcanoes while in others there are multiple trends suggesting two or more discrete magma batches, fractionation processes in a range of pressures and mixing of magmas. There is also evidence that some ‘monogenetic’ cones have produced eruptions of compositionally distinct magma in temporally discrete episodes separated by years or decades suggesting separate but linked melting events. In some volcanic sequences eruptions begin with relatively primitive compositions and in others evolved compositions precede the eruption of more primitive compositions. Clearly there exists a spectrum between a simple compositional trend in a monogenetic cone and the often chaotic geochemical patterns of large complex volcanoes. This reflects increasingly complex plumbing systems through which larger and larger magma volumes transit the lithospheric mantle and crust. Magmatic systems in which the plumbing system is re-used over significant time periods will show thermal evolution and ultimately geochemical evolution which is reflected in increasingly complicated petrographic and

  20. On the bioavailability of trace metals in surface sediments: a combined geochemical and biological approach.

    Science.gov (United States)

    Roosa, Stéphanie; Prygiel, Emilie; Lesven, Ludovic; Wattiez, Ruddy; Gillan, David; Ferrari, Benoît J D; Criquet, Justine; Billon, Gabriel

    2016-06-01

    The bioavailability of metals was estimated in three river sediments (Sensée, Scarpe, and Deûle Rivers) impacted by different levels of Cu, Cd, Pb, and Zn (Northern France). For that, a combination of geochemistry and biological responses (bacteria and chironomids) was used. The results obtained illustrate the complexity of the notion of "bioavailability." Indeed, geochemical indexes suggested a low toxicity, even in surface sediments with high concentrations of total metals and a predicted severe effect levels for the organisms. This was also suggested by the abundance of total bacteria as determined by DAPI counts, with high bacterial cell numbers even in contaminated areas. However, a fraction of metals may be bioavailable as it was shown for chironomid larvae which were able to accumulate an important quantity of metals in surface sediments within just a few days.We concluded that (1) the best approach to estimate bioavailability in the selected sediments is a combination of geochemical and biological approaches and that (2) the sediments in the Deûle and Scarpe Rivers are highly contaminated and may impact bacterial populations but also benthic invertebrates.

  1. Geochemical study on hot-spring water in West New Britain Province, Papua New Guinea

    Science.gov (United States)

    Lahan, M. M.; Verave, R. T.; Irarue, P. Y.

    2015-10-01

    West New Britain Province, which occupies the western part of New Britain Island in Papua New Guinea, is ideally located within an active tectonic region that influences volcanism creating an environment favourable for geothermal activity. Geothermal mapping of surface manifestations reveals high temperature geothermal prospects along the northern coastline of West New Britain Province that are further confirmed by geochemical analysis. The occurrence of geothermal features is confined to the Quaternary Kimbe Volcanics and alluvium in the lowland areas. The features in Talasea appear to be controlled by deep-seated northerly trending faults while structures in Hoskins also appear to be deep seated but have not been identified. The geothermal systems in West New Britain Province have not been drilled, but preliminary reconnaissance geothermal mapping and geochemical analysis reveals four high temperature geothermal prospects suitable for further investigation and development of geothermal energy. These are the Pangalu (Rabili) and Talasea Station geothermal prospects in Talasea and Kasiloli (Magouru) and Silanga (Bakama and Sakalu) geothermal prospects in Hoskins. The calculated reservoir temperatures for these fields are in the range of 245-310 °C. Recommendations are made for further follow-up exploratory investigations.

  2. Organic geochemical characterization of potential hydrocarbon source rocks in the upper Benue Trough

    International Nuclear Information System (INIS)

    Obaje, N. G.; Pearson, M. J.; Suh, C. E.; Dada, S. S.

    1999-01-01

    The Upper Benue Trough of Nigeria is the northeastern most portion of the Benue rift structure that extends from the northern limit of the Niger Delta in the south to the southern limit of the Chad basin int he northeast. this portion of the trough is made up of two arms: the Gongola Arm and the Yola Arm. Stratigraphic sequence in the Gongola Arm comprises the continental Albian Bima Sandstone, the transitional Cenomanian Yolde Formation and the marine Turonian - Santonian Gongila, Pindiga, and Fika Formations. Overlying these are the continental Campane - Maastrichtian Gombe Sandstone and the Tertiary Kerri - Kerri Formation. In the Yola Arm, the Turonian - Santonian sequence is replaced by the equally marine Dukul, Jessu, Sekuliye Formations, Numanha Shale, and the Lamja Sandstone. Organic geochemical studies have been carried on outcrop sample form the Gongila, Pindiga, Dukul Formations, the Fika shale and the shaly units of the Gombe Sandstone, with the aim of assessing their source rock potential. Gas Chromatography (GC), Gas Chromatography - Mass Spectrometry (C - MS), and Rock Eval Pyrolysis were the major organic geochemical tools employed. Biomaker hydrocarbon signatures obtained from the GC - MS and the Rock Eval Pyrolysis results indicate that all he formations studied, except the Dukul formation, are immature and are all lean in organic matter

  3. Source identification of volcanic ashes by geochemical analysis of well preserved lacustrine tephras in Nahuel Huapi National Park.

    Science.gov (United States)

    Daga, Romina; Ribeiro Guevara, Sergio; Sánchez, María Lidia; Arribére, María

    2008-10-01

    Well preserved volcanic ashes produced in recent events, recovered from sedimentary sequences extracted from three lakes belonging to Nahuel Huapi National Park, Northern Patagonia, were geochemically characterized in order to reveal patterns that allow the identification of the source. Two water bodies are situated in the direct impact area of volcanoes Calbuco and Puyehue-Cordón Caulle, while the third, lake Moreno, is situated in-between. The sedimentary sequences were dated by (210)Pb and (137)Cs techniques; the elemental composition was determined by Instrumental Neutron Activation Analysis. Distinctive patterns were found out when comparing glass shards, and also white pumice but in a lesser degree, of tephra layers extracted from lake Ilón, related mostly to volcano Calbuco events, and lake Nahuel Huapi (Brazo Rincón site), associated to Puyehue-Cordón Caulle eruptions. The geochemical parameters that showed decisive differences were SiO(2) and Na(2)O+K(2)O contents, the Eu anomaly, Rare Earth element ratios; the concentration of incompatible elements Cs, Rb, Th, Hf, Ta and Zr, and the compatible elements Cr and V. The six upper tephra layers extracted from lake Moreno showed geochemical patterns that allowed clear association with Calbuco and Puyehue-Cordón Caulle sources. These results set up the base for tephrochronological applications in historical periods in Nahuel Huapi National Park area.

  4. Source identification of volcanic ashes by geochemical analysis of well preserved lacustrine tephras in Nahuel Huapi National Park

    Energy Technology Data Exchange (ETDEWEB)

    Daga, Romina [Laboratorio de Analisis por Activacion Neutronica, Centro Atomico Bariloche, 8400 Bariloche (Argentina)], E-mail: romina@cab.cnea.gov.ar; Ribeiro Guevara, Sergio [Laboratorio de Analisis por Activacion Neutronica, Centro Atomico Bariloche, 8400 Bariloche (Argentina); Sanchez, Maria Lidia [Universidad Nacional de Rio Cuarto, 5800 Rio Cuarto (Argentina); Arribere, Maria [Laboratorio de Analisis por Activacion Neutronica, Centro Atomico Bariloche, 8400 Bariloche (Argentina)

    2008-10-15

    Well preserved volcanic ashes produced in recent events, recovered from sedimentary sequences extracted from three lakes belonging to Nahuel Huapi National Park, Northern Patagonia, were geochemically characterized in order to reveal patterns that allow the identification of the source. Two water bodies are situated in the direct impact area of volcanoes Calbuco and Puyehue-Cordon Caulle, while the third, lake Moreno, is situated in-between. The sedimentary sequences were dated by {sup 210}Pb and {sup 137}Cs techniques; the elemental composition was determined by Instrumental Neutron Activation Analysis. Distinctive patterns were found out when comparing glass shards, and also white pumice but in a lesser degree, of tephra layers extracted from lake Ilon, related mostly to volcano Calbuco events, and lake Nahuel Huapi (Brazo Rincon site), associated to Puyehue-Cordon Caulle eruptions. The geochemical parameters that showed decisive differences were SiO{sub 2} and Na{sub 2}O+K{sub 2}O contents, the Eu anomaly, Rare Earth element ratios; the concentration of incompatible elements Cs, Rb, Th, Hf, Ta and Zr, and the compatible elements Cr and V. The six upper tephra layers extracted from lake Moreno showed geochemical patterns that allowed clear association with Calbuco and Puyehue-Cordon Caulle sources. These results set up the base for tephrochronological applications in historical periods in Nahuel Huapi National Park area.

  5. GEOCHEM-EZ: a chemical speciation program with greater power and flexibility

    Science.gov (United States)

    GEOCHEM –EZ is a multi-functional chemical speciation program, which was designed to replace the existing GEOCHEM-PC, a program that can only be used on DOS consoles. Chemical speciation programs, such as GEOCHEM (Sposito and Mattigod, 1980) and GEOCHEM-PC (Parker et al., 1995), have been excellent ...

  6. Uruguay mining Inventory: Geochemical prospecting results of Valentines mapping

    International Nuclear Information System (INIS)

    Spangenberg, J.; Filippini, J.

    1985-01-01

    This work is about geochemical prospecting carried out into the Uruguay mining inventory framework. In this case the survey was in Valentines mapping. Florida, Durazno and Treinta y Tres provinces of Uruguay .

  7. Chlorine isotopes potential as geo-chemical tracers

    Digital Repository Service at National Institute of Oceanography (India)

    Shirodkar, P.V.; Pradhan, U.K.; Banerjee, R.

    The potential of chlorine isotopes as tracers of geo-chemical processes of earth and the oceans is highlighted based on systematic studies carried out in understanding the chlorine isotope fractionation mechanism, its constancy in seawater and its...

  8. Geochemical methodology for gold prospect ion in Uruguay

    International Nuclear Information System (INIS)

    Spangenber, J.

    1987-01-01

    This work is about the history of gold prospection in Uruguay. In this study there are considered the geochemical aspects, the gold performance, the applicability to mining prospection and the gold prospection aluvionar

  9. Geochemical prospect ion results of Mariscala aerial photo

    International Nuclear Information System (INIS)

    Filippini, J.

    1989-01-01

    This report shows the geochemical prospect ion results carried out within the framework of the metalical mining prospect ion in Mariscala aerial photo. Lavalleja district belong to the Mining inventory programme of Uruguay.

  10. The geochemical chararateristics of the marble deposits east of ...

    African Journals Online (AJOL)

    ), marbles were investigated with the view to establishing marble occurrences and their geochemical characteristics. Crystalline rocks of the Nigerian Basement Complex (migmatite – gneiss complex) underlie the area. Ten marble bodies were ...

  11. National Geochemical Survey Locations and Results for Iowa

    Data.gov (United States)

    Iowa State University GIS Support and Research Facility — The United States Geological Survey (USGS), in collaboration with other state and federal agencies, industry, and academia, is conducting a National Geochemical...

  12. Geochemical behavior of disposed radioactive waste

    International Nuclear Information System (INIS)

    Barney, G.S.; Navratil, J.D.; Schulz, W.W.

    1984-01-01

    The papers in this book are organized to cover the chemical aspects that are important to understanding the behavior of disposed radioactive wastes. These aspects include radionuclide sorption and desorption, solubility of radionuclide compounds, chemical species of radionuclides in natural waters, hydrothermal geochemical reactions, measurements of radionuclide migration, solid state chemistry of wastes, and waste-form leaching behavior. The information in each of the papers is necessary to predict the transport of radionuclides from wastes via natural waters and thus to predict the safety of the disposed waste. Radionuclide transport in natural waters is strongly dependent on sorption, desorption, dissolution, and precipitation processes. The first two papers discuss laboratory investigations of these processes. Descriptions of sorption and desorption behavior of important radionuclides under a wide range of environmental conditions are presented in the first section. Among the sorbents studied are basalt interbed solids, granites, clays, sediments, hydrous oxides, and pure minerals. Effects of redox conditions, groundwater composition and pH on sorption reactions are described

  13. LASL approach to uranium geochemical reconnaissance

    Energy Technology Data Exchange (ETDEWEB)

    Sharp, R.R. Jr.

    1977-01-01

    The US ERDA, as part of the NURE program, has initiated a nationwide Hydrogeochemical and Stream Sediment Reconnaissance (HSSR). The aims of the NURE program are to provide data on which to base more accurate estimates of US uranium reserves for long-range planning and to aid in meeting the nation's projected uranium demands into the next century. The HSSR objective is to complete, by 1980, a reconnaissance of the nation's surface waters, ground waters, and stream and lake sediments, to aid in assessment of uranium reserves and identification of areas of interest for exploration. Patterned after extensive uranium reconnaissance done in many other countries, the LASL project is comprised of the following five components: (1) organization and planning, which includes management, design, and execution; (2) field sampling, which includes orientation studies, generation of specifications, and contracting and inspection of field work; (3) sample receiving and analysis, which includes development of methods and hardware, quality assurance, and archival storage; (4) data handling and presentation, including verification, storage, output, and plotting; and (5) data evaluation and publication, which incorporates geochemical, geological, statistical, and empirical evaluation and report writing. The LASL approach to each component and the current status in each state are described.

  14. LASL approach to uranium geochemical reconnaissance

    International Nuclear Information System (INIS)

    Sharp, R.R. Jr.

    1977-01-01

    The US ERDA, as part of the NURE program, has initiated a nationwide Hydrogeochemical and Stream Sediment Reconnaissance (HSSR). The aims of the NURE program are to provide data on which to base more accurate estimates of US uranium reserves for long-range planning and to aid in meeting the nation's projected uranium demands into the next century. The HSSR objective is to complete, by 1980, a reconnaissance of the nation's surface waters, ground waters, and stream and lake sediments, to aid in assessment of uranium reserves and identification of areas of interest for exploration. Patterned after extensive uranium reconnaissance done in many other countries, the LASL project is comprised of the following five components: (1) organization and planning, which includes management, design, and execution; (2) field sampling, which includes orientation studies, generation of specifications, and contracting and inspection of field work; (3) sample receiving and analysis, which includes development of methods and hardware, quality assurance, and archival storage; (4) data handling and presentation, including verification, storage, output, and plotting; and (5) data evaluation and publication, which incorporates geochemical, geological, statistical, and empirical evaluation and report writing. The LASL approach to each component and the current status in each state are described

  15. Coupling R and PHREEQC: Efficient Programming of Geochemical Models

    OpenAIRE

    De Lucia, Marco; Kühn, Michael

    2013-01-01

    We present a new interface between the geochemical simulator PHREEQC and the open source language R. It represents a tool to flexibly and efficiently program and automate every aspect of geochemical modelling. The interface helps particularly to setup and run large numbers of simulations and visualise the results. Also profiting of numberless high-quality R extension packages, performing sensitivity analysis or Monte Carlo simulations becomes straightforward. Further, an algorithm to speedup ...

  16. Geochemical and Physical Characteristics of Iraqi Dust and Soil Samples

    Science.gov (United States)

    2004-10-08

    Report: Geochemical and Physical Characteristics of Iraqi Dust and Soil Samples iv ABBREVIATIONS LIST Acronyms ASTM American Society for Testing...gallons of Militec-1 gun lubricant were donated to DRI by 9 Militec, Inc. (11828 Pika Drive, Waldorf, Maryland). All three lubricants also serve as...Report: Geochemical and Physical Characteristics of Iraqi Dust and Soil Samples 37 REFERENCES ASTM ( American Society for Testing and Materials). 2000

  17. Geochemical, hydrological, and biological cycling of energy residual. Research plan

    International Nuclear Information System (INIS)

    Wobber, F.J.

    1983-03-01

    Proposed research goals and specific research areas designed to provide a base of fundamental scientific information so that the geochemical, hydrological, and biophysical mechanisms that contribute to the transport and long term fate of energy residuals in natural systems can be understood are described. Energy development and production have resulted in a need for advanced scientific information on the geochemical transformations, transport rates, and potential for bioaccumulation of contaminants in subsurface environments

  18. Geochemical modelling of groundwater evolution using chemical equilibrium codes

    International Nuclear Information System (INIS)

    Pitkaenen, P.; Pirhonen, V.

    1991-01-01

    Geochemical equilibrium codes are a modern tool in studying interaction between groundwater and solid phases. The most common used programs and application subjects are shortly presented in this article. The main emphasis is laid on the approach method of using calculated results in evaluating groundwater evolution in hydrogeological system. At present in geochemical equilibrium modelling also kinetic as well as hydrologic constrains along a flow path are taken into consideration

  19. Geochemical implications of gabbro from the slow-spreading Northern Central Indian Ocean Ridge, Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Ray, Dwijesh; Misra, S.; Banerjee, R.; Weis, D.

    crust. Dredged gabbroic samples, therefore, are studied to examine gabbro-basalt relationships (Tiezzi and Scott, 1980; Bloomer et al., 1989), conditions of crystallization (Elthon, 1987), compositions and diversity of parental melts (Bloomer et al...) the present gabbro may be the cumulate phase derived during fractionation of the NCIR parent magma; or (c) these gabbros may have a different magmatic history and are genetically related to the gabbroic rocks occurring along transform faults. Basalts...

  20. Geochemical mapping of Anheung, Wonju and Eomjeong sheets (1:50,000)

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jin Soo; Seo, Hyo Joon; Shin, Seong Cheon; Chi, Se Jung; Kim, Seong Jae [Korea Inst. of Geology Mining and Materials, Taejon (Korea, Republic of)

    1995-12-01

    A geochemical mapping was undertaken on the three quadrangles of the Anheung, Wonju and Eomjeong sheets (1:50,000, new edition) in the southwestern Taebaeg Mineralized Belt. The survey area, ca. 1,900 km{sup 2}, is covered mostly by Jurassic granites and Precambrian metamorphic rocks, and partly by Cambro-Ordovician limestones and the Cretaceous igneous and sedimentary rocks. Light mineral stream sediments and water samples, totally 751 for each media, were collected from active channels of primary or secondary order with a mean sampling density of 1/2.4 km{sup 2}. Geochemical maps were made on 17 elements (i.e., Ag, Al, As, Ba, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sr, V, W, Zn) for stream sediments. Geochemical distribution maps for water samples were independently made on major and minor components (i.e., Na, K, Li, Si, Ca, Mg, Al, As, B, Ba, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sr, V, Zn, F{sup -}, Cl{sup -}, NO{sub 3}{sup -}, NO{sub 2}{sup -}, PO{sub 4}{sup 3-}, SO{sub 4}{sup 2-}, HCO{sub 3}{sup -}) and other physico-chemical properties (i.e., Electric Conductivity, Total Dissolved Solids, pH, Dissolved Oxygen). Analysis was carried out by Ion Coupled Plasma Spectrometry and Ion Chromatography. Geochemical anomalies were evaluated based upon geological and other field information. The Ag-As, Cu-Pb-Zn and W-Mo anomalies of stream sediments in the northern Anheung and southern Eomjeong sheets indicate a contamination derived from mining districts. Pb-Zn anomalies from southeastern area in the Eomjeong sheet may suggest a potential of polymetallic deposits near Mesozoic granites intruding the Ogcheon strata. High concentrations of Ca, Na, K, Cl{sup -} and NO{sub 3}{sup -} in stream waters around Chungju and Wonju imply a strong pollution over urban districts and stock farms. (author). 57 refs., 70 figs.

  1. A stream sediment geochemical survey of the Ganga River headwaters in the Garhwal Himalaya

    Science.gov (United States)

    Mukherjee, P.K.; Purohit, K.K.; Saini, N.K.; Khanna, P.P.; Rathi, M.S.; Grosz, A.E.

    2007-01-01

    This study models geochemical and adjunct geologic data to define provinces that are favorable for radioactive-mineral exploration. A multi-element bed-sediment geochemical survey of streams was carried out in the headwaters region of the Ganga River in northern India. Overall median values for uranium and thorium (3.6 and 13.8 ppm; maxima of 4.8 and 19.0 ppm and minima of 3.1 and 12.3 ppm respectively) exceed average upper crustal abundances (2.8 and 10.7 ppm) for these radioactive elements. Anomalously high values reach up to 8.3 and 30.1 ppm in thrust zone rocks, and 11.4 and 22.5 ppm in porphyroids. At their maxima, these abundances are nearly four- and three-fold (respectively) enriched in comparison to average crustal abundances for these rock types. Deformed, metamorphosed and sheared rocks are characteristic of the main central thrust zone (MCTZ). These intensively mylonitized rocks override and juxtapose porphyritic (PH) and proterozoic metasedimentary rock sequences (PMS) to the south. Granitoid rocks, the major protoliths for mylonites, as well as metamorphosed rocks in the MCT zone are naturally enriched in radioelements; high values associated with sheared and mylonitized zones are coincident with reports of radioelement mineralization and with anomalous radon concentrations in soils. The radioelement abundance as well as REE abundance shows a northward enrichment trend consistent with increasing grade of metamorphism indicating deformation-induced remobilization of these elements. U and Th illustrate good correlation with REEs but not with Zr. This implies that zircon is not a principal carrier of U and Th within the granitoid-dominant thrust zone and that other radioelement-rich secondary minerals are present in considerable amounts. Thus, the relatively flat, less fractionated, HREE trend is also not entirely controlled by zircon. The spatial correlation of geologic boundary zones (faults, sheared zones) with geochemical and with geophysical (Rn

  2. Similarity in Evolutionary Histories of Eocene Sediments from Subathu and Cambay Basins: Geochemical and Palaeontological Studies

    Science.gov (United States)

    Chaudhuri, S.; Halder, K.; Sarkar, S.

    2017-12-01

    A systematic comparative study of microfaunal assemblage and representative geochemical elements from two Cenozoic basins of India, Mangrol-Valia Lignite Mine section (21°30'52''N:73°12'20.5''E) of Cambay Shale Formation, western India and Jigni section (33°14'45"N:74°22'0"E) from Subathu Formation in northern India was undertaken to infer the paleoenvironment, palaeobathymetry and paleoclimate of these successions. Despite a gamut of work already carried out in these two basins, the sedimentary successions still await a correlative-detailed process-based facies, geochemical characterization and paleoenvironmental analysis. With a view to fulfill this gap, the present work was carried out by studying bulk rock XRD, XRF, clay mineralogy and analyzing calcareous microfossil foraminifera from samples at equivalent depth of these two basins which are situated thousands of kilometers apart and in different tectonic settings. The faunal assemblage of Eocene sediments of Mangrol-Valia section is indicative of shallow marine and inner shelf deposition with medium oxygen supply, while that of the Jigni section suggests primarily a shallow marine condition, which gradually changes to open marine condition with time. It is pertinent to note that the two basins of Cenozoic India started their lithosuccession with coal bearing strata. Well preserved pectin aragonite shells also indicate that primarily these two basins experienced low energy lagoonal environment. The fossil assemblage in both basins also suggests a tropical moist to terrestrial lowland environment. Geochemical analysis shows that the Mangrol-Valia section mineralogically comprises of kaolinite, siderite, quartz, smectite and kaolinite with higher abundance throughout the succession indicating chemical weathering of Deccan basement and high erosional environment. Calcite is the main constituent of Jigni section that indicates intracratonic rift settings. Medium to high quartz content and other detrital

  3. Concerning evaluation of eco-geochemical background in remediation strategy

    Science.gov (United States)

    Korobova, Elena; Romanov, Sergey

    2015-04-01

    The geochemical concept of biosphere developed by V.I. Vernadsky states the geological role of the living organisms in the course of their active chemical interaction with the inert matter (Vernadsky, 1926, 1960). Basing on this theory it is reasonable to suggest that coevolution of living organisms and their environment led to development of the dynamically stable biogeocenoses precisely adequate to their geochemical environment. Soil cover was treated by V.I. Vernadsky as a balanced bio-inert matter resulting from this interaction. Appearance of human mind and then a civilization led to global expansion of human beings, first able to survive in unfavorable geochemical conditions and then starting chemical transformation of the environment to satisfy the growing demands of mankind in food and energy. The residence in unfavorable environment and local contamination was followed by appearance of endemic diseases of plants, animals and man. Therefore zonal, regional and local chemical composition of the soil cover formed in natural conditions may be used for estimation of the optimum geochemical background, most adequate for the corresponding zonal biogeocenoses and species. Moreover, the natural geochemical background and technogenic fields have unequal spatial structure and this facilitates their identification that may be relatively easy realized in remediation strategy. On the assumption of the foregoing, the adequate methodical approach to remediation of technogenically affected areas should account of the interaction of the existing natural and the newly formed technogenic geochemical fields and include the following steps: 1) the study and mapping of geochemical structure of the natural geochemical background basing on soil maps; 2) the study of contaminants and mapping spatial distribution of technogenic releases; 3) construction of risk maps for the target risk groups with due regard to natural ecological threshold concentration in context of risk degree for

  4. Development of thermodynamic databases for geochemical calculations

    Energy Technology Data Exchange (ETDEWEB)

    Arthur, R.C. [Monitor Scientific, L.L.C., Denver, Colorado (United States); Sasamoto, Hiroshi; Shibata, Masahiro; Yui, Mikazu [Japan Nuclear Cycle Development Inst., Tokai, Ibaraki (Japan); Neyama, Atsushi [Computer Software Development Corp., Tokyo (Japan)

    1999-09-01

    Two thermodynamic databases for geochemical calculations supporting research and development on geological disposal concepts for high level radioactive waste are described in this report. One, SPRONS.JNC, is compatible with thermodynamic relations comprising the SUPCRT model and software, which permits calculation of the standard molal and partial molal thermodynamic properties of minerals, gases, aqueous species and reactions from 1 to 5000 bars and 0 to 1000degC. This database includes standard molal Gibbs free energies and enthalpies of formation, standard molal entropies and volumes, and Maier-Kelly heat capacity coefficients at the reference pressure (1 bar) and temperature (25degC) for 195 minerals and 16 gases. It also includes standard partial molal Gibbs free energies and enthalpies of formation, standard partial molal entropies, and Helgeson, Kirkham and Flowers (HKF) equation-of-state coefficients at the reference pressure and temperature for 1147 inorganic and organic aqueous ions and complexes. SPRONS.JNC extends similar databases described elsewhere by incorporating new and revised data published in the peer-reviewed literature since 1991. The other database, PHREEQE.JNC, is compatible with the PHREEQE series of geochemical modeling codes. It includes equilibrium constants at 25degC and l bar for mineral-dissolution, gas-solubility, aqueous-association and oxidation-reduction reactions. Reaction enthalpies, or coefficients in an empirical log K(T) function, are also included in this database, which permits calculation of equilibrium constants between 0 and 100degC at 1 bar. All equilibrium constants, reaction enthalpies, and log K(T) coefficients in PHREEQE.JNC are calculated using SUPCRT and SPRONS.JNC, which ensures that these two databases are mutually consistent. They are also internally consistent insofar as all the data are compatible with basic thermodynamic definitions and functional relations in the SUPCRT model, and because primary

  5. Compilation of kinetic data for geochemical calculations

    International Nuclear Information System (INIS)

    Arthur, R.C.; Savage, D.; Sasamoto, Hiroshi; Shibata, Masahiro; Yui, Mikazu

    2000-01-01

    Kinetic data, including rate constants, reaction orders and activation energies, are compiled for 34 hydrolysis reactions involving feldspars, sheet silicates, zeolites, oxides, pyroxenes and amphiboles, and for similar reactions involving calcite and pyrite. The data are compatible with a rate law consistent with surface reaction control and transition-state theory, which is incorporated in the geochemical software package EQ3/6 and GWB. Kinetic data for the reactions noted above are strictly compatible with the transition-state rate law only under far-from-equilibrium conditions. It is possible that the data are conceptually consistent with this rate law under both far-from-equilibrium and near-to-equilibrium conditions, but this should be confirmed whenever possible through analysis of original experimental results. Due to limitations in the availability of kinetic data for mine-water reactions, and in order to simplify evaluations of geochemical models of groundwater evolution, it is convenient to assume local-equilibrium in such models whenever possible. To assess whether this assumption is reasonable, a modeling approach accounting for couple fluid flow and water-rock interaction is described that can be use to estimate spatial and temporal scale of local equilibrium. The approach is demonstrated for conditions involving groundwater flow in fractures at JNC's Kamaishi in-situ tests site, and is also used to estimate the travel time necessary for oxidizing surface waters to migrate to the level of a HLW repository in crystalline rock. The question of whether local equilibrium is a reasonable assumption must be addressed using an appropriate modeling approach. To be appropriate for conditions at the Kamaishi site using the modeling approach noted above, the fracture fill must closely approximate a porous mine, groundwater flow must be purely advective and diffusion of solutes across the fracture-host rock boundary must not occur. Moreover, the mineralogical and

  6. Compilation of kinetic data for geochemical calculations

    Energy Technology Data Exchange (ETDEWEB)

    Arthur, R.C. [Monitor Scientific, LLC., Denver, Colorado (United States); Savage, D. [Quintessa, Ltd., Nottingham (United Kingdom); Sasamoto, Hiroshi; Shibata, Masahiro; Yui, Mikazu [Japan Nuclear Cycle Development Inst., Tokai, Ibaraki (Japan). Tokai Works

    2000-01-01

    Kinetic data, including rate constants, reaction orders and activation energies, are compiled for 34 hydrolysis reactions involving feldspars, sheet silicates, zeolites, oxides, pyroxenes and amphiboles, and for similar reactions involving calcite and pyrite. The data are compatible with a rate law consistent with surface reaction control and transition-state theory, which is incorporated in the geochemical software package EQ3/6 and GWB. Kinetic data for the reactions noted above are strictly compatible with the transition-state rate law only under far-from-equilibrium conditions. It is possible that the data are conceptually consistent with this rate law under both far-from-equilibrium and near-to-equilibrium conditions, but this should be confirmed whenever possible through analysis of original experimental results. Due to limitations in the availability of kinetic data for mine-water reactions, and in order to simplify evaluations of geochemical models of groundwater evolution, it is convenient to assume local-equilibrium in such models whenever possible. To assess whether this assumption is reasonable, a modeling approach accounting for couple fluid flow and water-rock interaction is described that can be use to estimate spatial and temporal scale of local equilibrium. The approach is demonstrated for conditions involving groundwater flow in fractures at JNC's Kamaishi in-situ tests site, and is also used to estimate the travel time necessary for oxidizing surface waters to migrate to the level of a HLW repository in crystalline rock. The question of whether local equilibrium is a reasonable assumption must be addressed using an appropriate modeling approach. To be appropriate for conditions at the Kamaishi site using the modeling approach noted above, the fracture fill must closely approximate a porous mine, groundwater flow must be purely advective and diffusion of solutes across the fracture-host rock boundary must not occur. Moreover, the

  7. Geochemical Treasure Hunt for Primary School Children

    Science.gov (United States)

    Tesmer, Maja; Frick, Daniel; Gerrits, Ruben; des GFZ-GeoWunderWerkstatt, Schülerlabor

    2017-04-01

    How can you inspire school children for geochemistry, and scientific exploratory urge? The key is to raise their curiosity and make learning new things a hands-on experience. The Fellows of the European Marie Curie Initial Training Network IsoNose designed and established a "Geochemical Treasure Hunt" to excite children for scientific investigations. This workshop explains primary school children the research and scientific methods of isotopic geochemistry, and their use to understand processes on the Earth's surface. From obtaining 'samples', performing various experiments, the school children gather clues leading them to the hidden treasure on the Telegrafenberg (campus of the GFZ Potsdam). The course was designed for school children to learn hands-on the meaning of elements, atoms and isotopes. In small groups the children conduct experiments of simplified methods being indispensable to any isotope geochemist. However, prior to working in any laboratory environment, a security briefing is necessary. For the course, two stages were implemented; firstly the use of harmful substances and dangerous equipment was minimised, and secondly children were equipped with size-matched personal protective equipment (lab coats, gloves, and safety googles). The purification of elements prior to isotopic analysis was visualised using colour chromatography. However, instead of using delicate mass spectrometers for the isotope ratio measurements, the pupils applied flame spectroscopy to analyse their dissolved and purified mineral solutions. Depending on the specific element present, a different colour was observed in the flame. The children plotted their colours of the flame spectroscopy onto a map and by interpreting the emerging colour patterns they localized the treasure on the map. In small teams they swarmed out on the Telegrafenberg to recover the hidden treasure. The project leading to this outreach activity has received funding from the People Programme (Marie Curie

  8. Uncertainty in reactive transport geochemical modelling

    International Nuclear Information System (INIS)

    Oedegaard-Jensen, A.; Ekberg, C.

    2005-01-01

    Full text of publication follows: Geochemical modelling is one way of predicting the transport of i.e. radionuclides in a rock formation. In a rock formation there will be fractures in which water and dissolved species can be transported. The composition of the water and the rock can either increase or decrease the mobility of the transported entities. When doing simulations on the mobility or transport of different species one has to know the exact water composition, the exact flow rates in the fracture and in the surrounding rock, the porosity and which minerals the rock is composed of. The problem with simulations on rocks is that the rock itself it not uniform i.e. larger fractures in some areas and smaller in other areas which can give different water flows. The rock composition can be different in different areas. In additions to this variance in the rock there are also problems with measuring the physical parameters used in a simulation. All measurements will perturb the rock and this perturbation will results in more or less correct values of the interesting parameters. The analytical methods used are also encumbered with uncertainties which in this case are added to the uncertainty from the perturbation of the analysed parameters. When doing simulation the effect of the uncertainties must be taken into account. As the computers are getting faster and faster the complexity of simulated systems are increased which also increase the uncertainty in the results from the simulations. In this paper we will show how the uncertainty in the different parameters will effect the solubility and mobility of different species. Small uncertainties in the input parameters can result in large uncertainties in the end. (authors)

  9. Coal weathering and the geochemical carbon cycle

    Science.gov (United States)

    Chang, Soobum; Berner, Robert A.

    1999-10-01

    The weathering rate of sedimentary organic matter in the continental surficial environment is poorly constrained despite its importance to the geochemical carbon cycle. During this weathering, complete oxidation to carbon dioxide is normally assumed, but there is little proof that this actually occurs. Knowledge of the rate and mechanisms of sedimentary organic matter weathering is important because it is one of the major controls on atmospheric oxygen level through geologic time. We have determined the aqueous oxidation rates of pyrite-free bituminous coal at 24° and 50°C by using a dual-cell flow-through method. Coal was used as an example of sedimentary organic matter because of the difficulty in obtaining pyrite-free kerogen for laboratory study. The aqueous oxidation rate obtained in the present study for air-saturated water (270 μM O2) was found to be on the order of 2 × 10-12 mol O2/m2/s at 25°C, which is fast compared to other geologic processes such as tectonic uplift and exposure through erosion. The reaction order with respect to oxygen level is 0.5 on a several thousand hour time scale for both 24° and 50°C experiments. Activation energies, determined under 24° and 50°C conditions, were ≈40 kJ/mol O2 indicating that the oxidation reaction is surface reaction controlled. The oxygen consumption rate obtained in this study is two to three orders of magnitude smaller than that for pyrite oxidation in water, but still rapid on a geologic time scale. Aqueous coal oxidation results in the formation of dissolved CO2, dissolved organic carbon (DOC), and solid oxidation products, which are all quantitatively significant reaction products.

  10. Geochemical factors influencing vault design and layout

    International Nuclear Information System (INIS)

    Gascoyne, M.; Stroes-Gascoyne, S.; Sargent, F.P.

    1995-01-01

    The design and construction of a vault for used nuclear fuel in crystalline rock may be influenced by a number of geochemical factors. During the siting stage, information is needed regarding the rock type, heterogeneities in its composition and the mineralogy of permeable zones because these will cause variations in thermal conductivity, strength and radionuclide sorptive properties of the rock. These factors may affect decisions regarding depth of vault construction, tunnel dimensions and spacing of panels and waste containers. The decision on whether groundwaters are allowed to flow freely into a planned excavation may depend on measurements of their chemical compositions, microbiological contents and presence of hazardous or corrosive constituents. During site characterization, borehole drilling from the surface and subsequent hydraulic testing will introduce both chemical and microbiological contaminants that may further influence this decision. During vault construction, the geochemistry of the rock may cause changes to the characterization, design and construction of the vault. For example, high salinity fluids in micropores in the rock could prevent the use of radar surveys to detect fractures in the surrounding rock. High rock salinity may also cause unacceptably high total dissolved solids loadings in water discharged from the facility. Again, the presence of toxic, corrosive or radioactive constituents in inflowing groundwater may require grouting or, if inflow is needed for service operations, development of treatment facilities both above and below ground. In addition, the use of explosives will cause high organic and nitrate loadings in service water as well as the possible impregnation of these chemicals in the damaged wall-rock surrounding an excavation. These chemicals may remain despite cleaning efforts and act as nutrients to promote microbial activity in the post-closure phase. In the operational phase, further design and construction, changes

  11. Predictive geophysics: geochemical simulations to geophysical targets

    Science.gov (United States)

    Chopping, R. G.; Cleverley, J.

    2017-12-01

    With an increasing focus on deep exploration for covered targets, new methods are required to target mineral systems under cover. Geophysical responses are driven by physical property contrasts; for example, density contrasts provide a gravity signal, acoustic impedance contrasts provide a seismic reflection signal. In turn, the physical properties for basement, crystalline rocks which host the vast majority of mineral systems are determined almost wholly by the mineralogy of the rocks in question. Mineral systems, through the transport of heat and reactive fluids, will serve to modify the physical properties of country rock as they chemically alter the hosting strata. To understand these changes, we have performed 2D reactive transport modelling that simulates the formation of Archean gold deposits of the Yilgarn Craton, Western Australia. From this, we derive a model of mineralogy that we can use to predict the density, magnetic susceptibility and seismic reflection changes associated with ore formation. It is then possible to predict the gravity, magnetic and seismic reflection responses associated with these deposits. Scenario mapping, such as testing the ability to resolve buried ore bodies or the geophysical survey spacing required to resolve the mineral system, can be performed to produce geophysical targets from these geochemical simulations. We find that there is a gravity response of around 9% of the unaltered response for deposits even buried by 1km of cover, and there is a magnetic spike associated with proximal alteration of the ore system. Finally, seismic reflection response is mostly characterised by additional reflections along faults that plumb the alteration system.

  12. Using multifractal modeling as a standard tool in geochemical exploration for predicting mineralized areas

    Science.gov (United States)

    Gonçalves, Mario A.

    2015-04-01

    It has been 20 years since the pioneering work of Cheng et al (1994) first proposed a quantitative relationship for the areas enclosing concentration values of an element above given thresholds and their distribution in the field, known as concentration-area (CA) method, which is based in multifractal theory. The method allows the definition of geochemical anomalies in wide set of geological backgrounds but it took nearly 15 years before it became a widely used methodology for mineral exploration. The method was also extended to 1D and 3D data sets. It is worth noting the variety of methods that spanned from the theory of fractals. Building on previous models, including multiplicative cascades and size-grade relationships, increasing evidence points to the powerful tools of fractal theory to describe and model ore deposit distribution and formation. However, while much of these approaches become complex and not easy to use, the CA method is remarkable for its utter simplicity and disarming results obtained when confronted with the geological reality in the field. This is most valued by companies and professionals undertaking geochemical exploration surveys for the characterization or refining of potential ore targets or known mineralized areas. Several approaches have combined the CA method with geostatistic modeling and simulation and other established statistical techniques in order to enhance anomalous threshold identification. Examples are not restricted to geochemical exploration alone, other applications being studies on environmental change. Some of these examples will be addressed as they have been applied to different regions in the world, but particular emphasis will be put on geochemical exploration surveys in different geotectonic units of the Variscan basement in the Iberian Peninsula. These include quartz-vein gold mineralization in Northern Portugal and several surveys for base metals over two wide areas, which served to re-evaluate much of the

  13. Hydrocarbon potential of Altiplano and northern Subandean, Bolivia

    Energy Technology Data Exchange (ETDEWEB)

    Edman, J.D.; Kirkpatrick, J.R.; Lindsey, D.D.; Lowell, J.D.; Cirbian, M.; Lopez, M.

    1989-03-01

    Seismic, stratigraphic, structural, and geochemical data from the Altiplano, northern Subandean, and northern plains of Bolivia were interpreted in order to evaluate the exploration potential of each province. Identification of three possible source rock intervals, primarily the Devonian and secondarily the Permian and Cretaceous, was used as the basis for recognizing active hydrocarbon systems. For those areas containing source intervals, their analysis revealed that possible reservoir and seal units range in age from Paleozoic to Tertiary; the majority of structures, however, are Eocene or younger. With these general concepts in mind, traps were identified in all three sedimentary provinces. In the northern Altiplano, the most prospective area is along the eastern margin near a southwest and west-vergent thrust belt where hanging-wall anticlines and a warped Eocene-Oligocene(.) unconformity surface form the most likely potential traps. In the central and southern Altiplano, both thrust-related and wrench-related structures present possible exploration targets. In the northern Subandean and Beni plains north of the Isiboro-Chapare area, traps can be classified into two broad groups. First, there are a wide variety of structural traps within the northern Subandean thrust belt, the most attractive of which are footwall structures that have been shielded from surface flushing by hanging-wall strata. Second, in the plains just northeast of the thrust belt, hydrocarbons sourced from the remnant Paleozoic basin may have migrated onto the Isarsama and Madidi highs.

  14. Basic principles of forward and inverse geochemical modelization

    International Nuclear Information System (INIS)

    Gimeno, M.J.; Pena, J.

    1994-01-01

    Geochemical modeling consists in the application of thermodynamic and physicochemical principles in the hydrogeochemical systems interpretation. It has been developed following two different approaches: a) inverse modeling (or mass balance calculations), which uses observed chemical and isotopic data from waters and rocks to identify geochemical reactions responsible of them, in a quantitative way; and b) forward modeling, which attempts to predict water compositions and mass transfer that can result from hypothesized reactions, from observed initial conditions on water-rock system compositions. Both of them have intrinsic uses and limitations which drive to their use in specific problems. For systems with adequate chemical, isotopic, and mineralogic data, the inverse modeling approach of speciation and mass-balance modeling provides the most direct means of determining quantitative geochemical reaction models. In contrast, for systems with missing or inadequate data, reaction-path modeling provides an a priori method of predicting geochemical reactions. In some cases it is useful to combine forward modeling with the results from inverse models. The mass-balance results determine the net mass transfer along the flow path, but these results are only partially constrained by thermodynamics. The forward modeling can be used both, to prove thermodynamic consistency for them, and to predict water quality at points where there are no enough data. Recent advances in geochemical modeling are focused on finding the most efficient numerical procedures for coupling geochemical reactions (both equilibrium and kinetic) with the hydrodynamic transport equations in compositionally-complex systems, on uncertainty analysis, and on model validation for actual geochemical systems

  15. Geochemical anomalies in South Caspian sediments

    Science.gov (United States)

    Baturin, G. N.; Gordeev, V. V.; Lisitzin, A. P.

    2016-05-01

    Study of the element composition of ten samples of modern terrigenous and carbonate sediments from the northern part of the Caspian Sea by the ICP-MS method showed that these sediments were enriched in sulfur, nonferrous metals, and some related minor elements including Se, Te, Re, and others in comparison with the average composition of sedimentary rocks. It is assumed that local hydrothermal seeps similar to those known on the Cheleken Peninsula and which may be formed in other areas of this tectonically active zone are the sources of these elements. In addition, such a composition of sediments may indicate the sporadic contamination of bottom water with hydrogen sulfide, which has been observed in areas of the South and Middle Caspian by many researchers.

  16. Geological controls on soil parent material geochemistry along a northern Manitoba-North Dakota transect

    Science.gov (United States)

    Klassen, R.A.

    2009-01-01

    As a pilot study for mapping the geochemistry of North American soils, samples were collected along two continental transects extending east–west from Virginia to California, and north–south from northern Manitoba to the US–Mexican border and subjected to geochemical and mineralogical analyses. For the northern Manitoba–North Dakota segment of the north–south transect, X-ray diffraction analysis and bivariate relations indicate that geochemical properties of soil parent materials may be interpreted in terms of minerals derived from Shield and clastic sedimentary bedrock, and carbonate sedimentary bedrock terranes. The elements Cu, Zn, Ni, Cr and Ti occur primarily in silicate minerals decomposed by aqua regia, likely phyllosilicates, that preferentially concentrate in clay-sized fractions; Cr and Ti also occur in minerals decomposed only by stronger acid. Physical glacial processes affecting the distribution and concentration of carbonate minerals are significant controls on the variation of trace metal background concentrations.

  17. Geological controls on soil parent material geochemistry along a northern Manitoba-North Dakota transect

    International Nuclear Information System (INIS)

    Klassen, R.A.

    2009-01-01

    As a pilot study for mapping the geochemistry of North American soils, samples were collected along two continental transects extending east-west from Virginia to California, and north-south from northern Manitoba to the US-Mexican border and subjected to geochemical and mineralogical analyses. For the northern Manitoba-North Dakota segment of the north-south transect, X-ray diffraction analysis and bivariate relations indicate that geochemical properties of soil parent materials may be interpreted in terms of minerals derived from Shield and clastic sedimentary bedrock, and carbonate sedimentary bedrock terranes. The elements Cu, Zn, Ni, Cr and Ti occur primarily in silicate minerals decomposed by aqua regia, likely phyllosilicates, that preferentially concentrate in clay-sized fractions; Cr and Ti also occur in minerals decomposed only by stronger acid. Physical glacial processes affecting the distribution and concentration of carbonate minerals are significant controls on the variation of trace metal background concentrations.

  18. Hydrologic Regulation of Global Geochemical Cycles

    Science.gov (United States)

    Maher, K.

    2015-12-01

    understand the processes controlling marine isotopic weathering processes, the need to integrate solute and solid transport into Earth system models, and the need to understand the role of extreme physical and temporal heterogeneities in moderating geochemical fluxes.

  19. Paleozoic petroleum systems of northern Germany and adjacent areas : a 3D modeling study

    OpenAIRE

    Uffmann, Anna Kathrin

    2013-01-01

    This thesis presents the results of a large-scale 3D petroleum system basin model of northern Germany and adjacent areas as well as a detailed 3D modeling study of the Münsterland Basin. Furthermore, the geochemical characterization of several black shale horizons present in the study area is given. In the study the burial and thermal history of sediments in northern Germany and The Netherlands using predominantly 3D forward numerical basin modeling techniques (PetroMod® suite software) has b...

  20. Geochemistry and petrogenesis of the late Cretaceous potassic-alkaline volcanic rocks from the Amasya Region (northern Turkey)

    Science.gov (United States)

    Gülmez, Fatma; Genç, Can; Tüysüz, Okan; Karacık, Zekiye; Roden, Mike; Billor, Zeki; Hames, Willis

    2013-04-01

    elements. Mg# (44.78 - 62.24), FeO (4.74-7.80 wt.%), Nb (6.3-14.4 ppm) and Ni (20-81 ppm) contents of these rocks imply that these rocks were not originated directly from the primitive melts. The geochemical findings suggest a source that is similar with subduction-related magmas. The evaluation of the geological data and combined with the geochemical findings suggest that the high- to ultrahigh-K alkaline volcanic rocks of the Lokman formation were generated by the partial melting processes of a heterogeneous magma source that was modified by the subduction of the Neo-Tethys ocean during the late Cretaceous period.

  1. Petroleum potential of the northern Sinu-San Jacinto Basin, Colombia: an integrated petroleum system and basin modeling approach

    Energy Technology Data Exchange (ETDEWEB)

    Nino, Christian H.; Goncalves, Felix T.T.; Bedregal, Ricardo P. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Lab. de Modelagem de Bacias (LAB2M); Azevedo, Debora A. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Inst. de Quimica; Landau, Luis [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Lab. de Metodos Computacionais em Engenharia (LAMCE)

    2004-07-01

    The northern Sinu-San Jacinto basin, located in the northwestern corner of South America (Colombia), belongs to the accretionary prism that resulted from the collision and subduction of the Caribbean plate under the South America plate. Despite all the previous exploratory efforts, solely a few small sub-commercial oil and gas accumulation have been found up to now. The geological and geochemical information acquired by different companies during the lasts decades was integrated with new geochemical analysis and basin modeling to characterize the petroleum systems, to reconstruct the hydrocarbon charge history in the study area and to better assess the exploratory risk. (author)

  2. Geochemical Modeling of ILAW Lysimeter Water Extracts

    Energy Technology Data Exchange (ETDEWEB)

    Cantrell, Kirk J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2014-12-22

    Geochemical modeling results of water extracts from simulated immobilized low-activity waste (ILAW) glasses, placed in lysimeters for eight years suggest that the secondary phase reaction network developed using product consistency test (PCT) results at 90°C may need to be modified for field conditions. For sediment samples that had been collected from near the glass samples, the impact of glass corrosion could be readily observed based upon the pH of their water extracts. For unimpacted sediments the pH ranged from 7.88 to 8.11 with an average of 8.04. Sediments that had observable impacts from glass corrosion exhibited elevated pH values (as high as 9.97). For lysimeter sediment samples that appear to have been impacted by glass corrosion to the greatest extent, saturation indices determined for analcime, calcite, and chalcedony in the 1:1 water extracts were near equilibrium and were consistent with the secondary phase reaction network developed using PCT results at 90°C. Fe(OH)3(s) also appears to be essentially at equilibrium in extracts impacted by glass corrosion, but with a solubility product (log Ksp) that is approximately 2.13 units lower than that used in the secondary phase reaction network developed using PCT results at 90°C. The solubilities of TiO2(am) and ZrO2(am) also appear to be much lower than that assumed in the secondary phase reaction network developed using PCT results at 90°C. The extent that the solubility of TiO2(am) and ZrO2(am) were reduced relative to that assumed in the secondary phase reaction network developed using PCT results at 90°C could not be quantified because the concentrations of Ti and Zr in the extracts were below the estimated quantification limit. Gibbsite was consistently highly oversaturated in the extract while dawsonite was at or near equilibrium. This suggests that dawsonite might be a more suitable phase for the secondary phase reaction network

  3. Isotope-geochemical methods for investigating ores and enclosing rocks

    International Nuclear Information System (INIS)

    Berezovskij, F.I.; Gnatenko, O.V.; Zhukov, F.I.

    1985-01-01

    Isotope-geochemical methods for investigating ores and enclosing rocks as applied to uranium deposits are considered. Attention is paid to precision mass-spectrometric isotope analysis mass-spectrometric isotope analysis of light elements and to sample preparation for the analysis. Interpretation of the results of sulfur, carbon, oxygen and lead isotope investigations in uranium deposits of different genetic types allows to find definite regularities in isotope variations depending on phisico-chemical ore forming conditions. It is shown that the combination of isotope-geochemical investigations permits to make a reliable conclusion on the source of ore substance means of its transportation and deposition in the process of metamorphism

  4. Effect of source integration on the geochemical fluxes from springs

    International Nuclear Information System (INIS)

    Frisbee, Marty D.; Phillips, Fred M.; White, Art F.; Campbell, Andrew R.; Liu, Fengjing

    2013-01-01

    Geochemical fluxes from watersheds are typically defined using mass-balance methods that essentially lump all weathering processes operative in a watershed into a single flux of solute mass measured in streamflow at the watershed outlet. However, it is important that we understand how weathering processes in different hydrological zones of a watershed (i.e., surface, unsaturated, and saturated zones) contribute to the total geochemical flux from the watershed. This capability will improve understanding of how geochemical fluxes from these different zones may change in response to climate change. Here, the geochemical flux from weathering processes occurring solely in the saturated zone is investigated. This task, however, remains exceedingly difficult due to the sparsity of subsurface sampling points, especially in large, remote, and/or undeveloped watersheds. In such cases, springflow is often assumed to be a proxy for groundwater (defined as water residing in fully saturated geologic formations). However, springflow generation may integrate different sources of water including, but not limited to, groundwater. The authors’ hypothesis is that long-term estimates of geochemical fluxes from groundwater using springflow proxies will be too large due to the integrative nature of springflow generation. Two conceptual models of springflow generation are tested using endmember mixing analyses (EMMA) on observations of spring chemistries and stable isotopic compositions in a large alpine watershed in the San Juan Mountains of southwestern Colorado. In the “total springflow” conceptual model, springflow is assumed to be 100% groundwater. In the “fractional springflow” conceptual model, springflow is assumed to be an integration of different sources of water (e.g., groundwater, unsaturated flow, preferential flow in the soil, etc.) and groundwater is only a fractional component. The results indicate that groundwater contributions in springflow range from 2% to 100

  5. Geochemical characterization of oceanic basalts using artificial neural network

    Digital Repository Service at National Institute of Oceanography (India)

    Das, P.; Iyer, S.D.

    discrete geochemical traits of the OFB by using certain characteristic elemental concentration of these basalts. In order to classify the OFB we considered one major oxide (K 2 O),seventrace(Sc,Rb,Sr,Y,Zr,Nband Ba,),sixrareearthelements(REE)(La...,Ce,Nd,Sm,Eu, and Yb) and seven elemental ratios (Zr/Nb, Y/Nb, Ba/ Nb, Zr/Y, Sm/Nd, La/Yb and Ce/Y). A reason for utilizing the above mentioned elements and their ratios is because these carry the geochemical signatures of the individual OFB type i.e., N-MORB, E...

  6. Geochemical variability of copper and iron in Oman margin sediments

    Digital Repository Service at National Institute of Oceanography (India)

    Alagarsamy, R.

    .D.Thesis, University of Liverpool, 1984. [19] R.E. Sturgeon, C.L. Chakrabarti, Recent advances in electrothermal atomisation in a graphite furnace atomic adsorption spectrophotometer, Progr. Anal. Atom. Spectroscopy 1 (1978) 5-9. [20] C.R. Smith, L.A. Levin, D... in immature sediments along the continental margins of Peru and Oman. Part I: Results of petrographical and bulk geochemical data, Org. Geochem. 24 (1996) 437-451. [36] R. Raiswell, D.E. Canfield, Sources of iron for pyrite formation in marine sediments...

  7. Characterization of tephras dispersed by the recent eruptions of volcanoes Calbuco (1961), Chaitén (2008) and Cordón Caulle Complex (1960 and 2011), in Northern Patagonia

    Science.gov (United States)

    Daga, Romina; Ribeiro Guevara, Sergio; Poire, Daniel G.; Arribére, María

    2014-01-01

    Pyroclastic materials dispersed in recent volcanic eruptions in Northern Patagonia were analysed in order to characterize the volcanic provenance by the geochemical fingerprint. The volcanic products studied were dispersed by eruptions of volcanoes Calbuco in 1961, Chaitén in 2008, and Cordón Caulle Volcanic Complex (CCVC) in 1960 and 2011. The geochemical characterization was based on the determination of 35 major and trace elements by Instrumental Neutron Activation Analysis, including geochemical tracer such as Rare Earth Elements (REE). The study of the pyroclastic products also included the morphological analysis by petrographic and scanning electron microscopy, and the mineralogical characterization by X-ray diffraction.

  8. Initial geochemical characteristics of fluid fine tailings in an oil sands end pit lake

    Energy Technology Data Exchange (ETDEWEB)

    Dompierre, Kathryn A. [Department of Civil and Geological Engineering, University of Saskatchewan, Saskatoon, Saskatchewan, Canada S7N 5A9 (Canada); Lindsay, Matthew B.J., E-mail: matt.lindsay@usask.ca [Department of Geological Sciences, University of Saskatchewan, Saskatoon, Saskatchewan S7N 5E2 (Canada); Cruz-Hernández, Pablo [Department of Geology, University of Huelva, Campus ‘El Carmen’, E-21071 Huelva (Spain); Halferdahl, Geoffrey M. [Environmental Research and Development, Syncrude Canada Limited, Edmonton, Alberta T6N 1H4 (Canada)

    2016-06-15

    Geochemical characteristics of fluid fine tailings (FFT) were examined in Base Mine Lake (BML), which is the first full-scale demonstration oil sands end pit lake (EPL) in northern Alberta, Canada. Approximately 186 Mm{sup 3} of FFT was deposited between 1994 and 2012, before BML was established on December 31, 2012. Bulk FFT samples (n = 588) were collected in July and August 2013 at various depths at 15 sampling sites. Temperature, solid content, electrical conductivity (EC), pH, Eh and alkalinity were measured for all samples. Detailed geochemical analyses were performed on a subset of samples (n = 284). Pore-water pH decreased with depth by approximately 0.5 within the upper 10 m of the FFT. Major pore-water constituents included Na (880 ± 96 mg L{sup −1}) and Cl (560 ± 95 mg L{sup −1}); Ca (19 ± 4.1 mg L{sup −1}), Mg (11 ± 2.0 mg L{sup −1}), K (16 ± 2.3 mg L{sup −1}) and NH{sub 3} (9.9 ± 4.7 mg L{sup −1}) were consistently observed. Iron and Mn concentrations were low within FFT pore water, whereas SO{sub 4} concentrations decreased sharply across the FFT–water interface. Geochemical modeling indicated that FeS{sub (s)} precipitation was favoured under SO{sub 4}-reducing conditions. Pore water was also under-saturated with respect to gypsum [CaSO{sub 4}·2H{sub 2}O], and near saturation with respect to calcite [CaCO{sub 3}], dolomite [CaMg(CO{sub 3}){sub 2}] and siderite [FeCO{sub 3}]. X-ray diffraction (XRD) suggested that carbonate-mineral dissolution largely depleted calcite and dolomite. X-ray absorption near edge structure (XANES) spectroscopy revealed the presence of FeS{sub (s)}, pyrite [FeS{sub 2}], and siderite. Carbonate-mineral dissolution and secondary mineral precipitation have likely contributed to FFT dewatering and settlement. However, the long-term importance of these processes within EPLs remains unknown. These results provide a reference for assessing the long-term geochemical evolution of oil sands EPLs, and offer

  9. Northern star js plaskett

    CERN Document Server

    Broughton, R Peter

    2018-01-01

    Northern Star explores Plaskett's unorthodox and fascinating life from his rural roots near Woodstock through his days as a technician at the University of Toronto to his initiation in astronomy at the Dominion Observatory in Ottawa.

  10. Northern Lights Chase Tours : Experiences from Northern Norway

    OpenAIRE

    Bertella, Giovanna

    2013-01-01

    This study is focused on the development of northern lights chase tourism, a particular type of northern lights tourism consisting in guided tours that have the goal to find good views of the northern lights. The theoretical approach is based on the understanding of the northern lights experience as a visual experience, and on the recognition of the tourism practitioners as the driving force to new product development. The empirical case concerns the recent development of northern lights chas...

  11. Northern Dimension: Participant Strategies

    Directory of Open Access Journals (Sweden)

    Busygina Irina

    2009-03-01

    Full Text Available This article is devoted to the “Northern Dimension” initiative of the EU which also includes North-West Russia, Norway and Iceland. It is noted that the “Northern Dimension” in the theoretical perspective can be considered as part of strategic multi-level interactions between member-states of the EU and Russia. On this basis, the authors analyze implications and effects of the strategic interdependence of all the EU-Russia relation levels.

  12. Northern Ireland: an anomaly.

    Science.gov (United States)

    Simpson, A

    1989-01-01

    The British Abortion Act of 1967, which makes abortion legal up to 28 weeks, does not extend to Northern Ireland, where abortion is still regulated by the 1861 Offences Against the Person Act, which makes abortion a felony, and the 1929 Infant Life Preservation Act, which prohibits abortion after the 28th week of pregnancy. The Bourne Judgment of 1928, in which a court held in favor of one Dr. Alex Bourne, who performed an early abortion, may be cited as precedent, but not as law. A woman in Northern Ireland may have an abortion only on the National Health Service and only if pregnancy is life-threatening, if she is mentally retarded, or if the child is likely to be abnormal. How many abortions are actually performed in Northern Ireland each year is not known. Essentially, women with unwanted pregnancies have only 3 options: to have the baby, to risk a back street abortion, and to go to England. Since 1967, 20,000 Northern Irish women have had abortions in England, but it is a privilege reserved for the wealthy because the woman must bear the expenses of traveling to England, establishing residency there, and paying hospital fees. All of this takes time and results in many women having late abortions. The women also must bear the stigma of having done something of which neither church in Northern Ireland approves. Northern Irish women, quite simply, do not have the same rights as women in England, Scotland, and Wales.

  13. Geochemical regionalism of biržai area topsoil and technogenous ground

    OpenAIRE

    Stankevičius, Tadas

    2008-01-01

    Objectives: to perform Biržai region soil geochemical regionalism in accordance with geological-geophormalogical evidence, to establish geochemical field differences, evaluate resistance to polution technogenous chemical elements. Goals: 1. Summarize experience gained in previously accomplished geochemical regionalism in Lithuania. 2. Familiarize with geochemical mapping of Biržai region . 3. To explore geological (quaternary), geomorphologic and anthropocentric pollution conditions in Biržai...

  14. Geothermal investigations with isotope and geochemical techniques in Latin America

    International Nuclear Information System (INIS)

    1992-03-01

    The IAEA Co-ordinated Research Programme (CRP) for Latin America on the Use of Isotope and Geochemical Techniques in Geothermal Exploration started in 1984. The first activity carried out was a Seminar on isotope and geochemical techniques in geothermal exploration, which took place in June 1984 in Morelia, Mexico. During the seminar, which was attended by representatives of the institutions which later took part in the programme, the objectives, main research lines, and geothermal fields to be studied during the CRP were discussed. The first research contracts were awarded towards the end of 1984. The field work started in 1985 and continued through 1990. During the implementation of the CRP a considerable number of geothermal fields were studied in the nine participating countries. The investigations carried out were geochemically quite comprehensive in most cases, but in some others they were still in a reconnaissance stage when the CRP ended: the latter studies are not reported in these proceedings, but the data obtained are in principle available from the relevant national institutions. While investigations with conventional geochemical techniques had already started in several fields before 1985, isotope methods were applied for the first time in all cases during this CRP. Due to the remoteness and high elevation of many of the fields studied and the adverse meteorological conditions during long periods of the year, the investigations could not proceed rapidly: this is the main reason for the unusually long duration of the CRP, which could be concluded only after more than five years after its inception

  15. Mining inventory of Uruguay. Polanco fotoplano geochemical prospecting results

    International Nuclear Information System (INIS)

    Zeegers, H; Artignan, D; Vairon, P

    1982-01-01

    This work is about the geochemical prospecting carried out in Polanco fotoplano within the framework of Uruguay Mining inventory . In this work were covered 660 km2 obtaining 685 samples for study which were analyzed by Plasma Emission Spectrometry in Orleans BRGM laboratories

  16. Geochemical assessment of light gaseous hydrocarbons in near ...

    Indian Academy of Sciences (India)

    Light hydrocarbons in soil have been used as direct indicators in geochemical hydrocarbon exploration, which remains an unconventional path in the petroleum industry. The occurrence of adsorbed soil ... Kalpana1 D J Patil1 A M Dayal1. National Geophysical Research Institute, Uppal Road, Hyderabad 500606, India.

  17. Geochemical and isotopic signatures for the identification of ...

    Indian Academy of Sciences (India)

    The objective of this study is to identify the extent of seawater intruded area by major geochemical and isotopic signatures. A total of 102 groundwater samples were collected and analysed for major and minor ions. Groundwater samples with electrical conductivity (EC) greater than 5000 S/cm and a river mouth sample ...

  18. Statistical Evaluation of Geochemical Au Sample Quality | Affam ...

    African Journals Online (AJOL)

    The ANOVA and the t–Tests revealed no significant analytical error. However, the other tests indicated multimodality of the populations as well as batch effect which culminates into significant procedural error. The investigation concludes that these systematic procedural errors if unchecked could mask true geochemical ...

  19. geochemical characterization the waters of foggaras the continental

    African Journals Online (AJOL)

    B. Benaricha, A. Khaldi, A. Elouissi, S. Mouassa, M. Zaagane

    2017-01-01

    Jan 1, 2017 ... Journal of Fundamental and Applied Sciences is licensed under a Creative Commons Attribution-NonCommercial 4.0. International License. Libraries Resource Directory. We are listed under Research Associations category. GEOCHEMICAL CHARACTERIZATION THE WATERS OF FOGGARAS THE.

  20. Numerical modeling of geochemical variations caused by crustal relamination

    NARCIS (Netherlands)

    Vogt, Katharina|info:eu-repo/dai/nl/370618947; Castro, Antonio; Gerya, Taras

    2013-01-01

    Geochemical consequences of composite diapirs formed in subduction zones have been studied using a thermomechanical numerical model of an ocean-continent subduction zone. This model includes dehydration of subducted crust, aqueous fluid transport, partial melting, and melt emplacement. Subduction of

  1. Geochemical processes controlling the groundwater quality in lower ...

    Indian Academy of Sciences (India)

    Hydrogeochemical study of groundwater was carried out in a part of the lower Palar river basin, southern. India to determine the geochemical processes controlling the groundwater quality. Thirty-nine ground- water samples were collected from the study area and analysed for pH, Eh, EC, Ca, Mg, Na, K, HCO3,. CO3, Cl and ...

  2. Geochemical trends in the weathered profiles above granite gneiss ...

    African Journals Online (AJOL)

    Geochemical trends in the weathered profiles above granite gneiss and schist of Abeokuta area, southwestern Nigeria. Anthony T Bolarinwa, Anthony A Elueze. Abstract. No Abstract. Journal of Mining and Geology 2005, Vol. 41(1): 19-31. Full Text: EMAIL FULL TEXT EMAIL FULL TEXT · DOWNLOAD FULL TEXT ...

  3. Mineralogical and geochemical studies of phosphorite nodules in ...

    African Journals Online (AJOL)

    Mineralogical and geochemical studies of phosphorite nodules in the Dange Formation Sokoto Basin, Northwestern Niveria. OA Adekeye, SO Akande. Abstract. No Abstract Available Journal of Mining and Geology Vol.40(2) 2004: 101-106. Full Text: EMAIL FULL TEXT EMAIL FULL TEXT · DOWNLOAD FULL TEXT ...

  4. Comparison of thermodynamic databases used in geochemical modelling

    International Nuclear Information System (INIS)

    Chandratillake, M.R.; Newton, G.W.A.; Robinson, V.J.

    1988-05-01

    Four thermodynamic databases used by European groups for geochemical modelling have been compared. Thermodynamic data for both aqueous species and solid species have been listed. When the values are directly comparable any differences between them have been highlighted at two levels of significance. (author)

  5. Geochemical behaviour of vanadium in iron—titanium oxides

    NARCIS (Netherlands)

    Schuiling, R.D.; Feenstra, A.

    The following geochemical rules-of-thumb seem to hold for vanadium: 1. (1) Magnetites as a group have higher V contents than either hematites or ilmenites. 2. (2) In magnetite—hematite pairs, however, the hematite has the higher V content. 3. (3) In magnetite—ilmenite pairs, the magnetite

  6. Geochemical reactivity of rocks of the Czech Republic

    Czech Academy of Sciences Publication Activity Database

    Chuman, T.; Gürtlerová, P.; Hruška, Jakub; Adamová, M.

    2014-01-01

    Roč. 10, č. 2 (2014), s. 341-349 ISSN 1744-5647 R&D Projects: GA MŠk(CZ) ED1.1.00/02.0073 Institutional support: RVO:67179843 Keywords : geochemical reactivity * Czech Republic * susceptibility to weathering Subject RIV: EH - Ecology, Behaviour Impact factor: 1.193, year: 2014

  7. Geological and geochemical variations in Mid-Tertiary Ethiopian ...

    African Journals Online (AJOL)

    Mekelle University. Geological and geochemical variations in Mid-Tertiary Ethiopian Flood Basalt. Province, Maychew, Tigray Region, Ethiopia. Kurkura Kabeto*. Department of Earth Science, College of Natural and Computational Sciences, P.O. Box 231,. Mekelle University, Ethiopia (*kurkura57@yahoo.com). ABSTRACT.

  8. Uruguay Mining inventory. Las Animas fotoplano geochemical prospecting results

    International Nuclear Information System (INIS)

    Zeegers, H.; Spangenberg, J.

    1981-01-01

    This work is about the geochemical prospecting carried out in Las Animas fotoplano within the framework of Uruguay Mining inventory. In this work were covered 660 km2 obtaining 738 samples for study which were analyzed by Plasma Emission Spectrometry in Orleans BRGM laboratories.

  9. Geochemical processes controlling the groundwater quality in lower ...

    Indian Academy of Sciences (India)

    for few locations. The results of these analyses were used to identify the geochemical processes that are taking place in this region. Cation exchange and silicate ...... composition of groundwater from alluvial aquifers in the Wanaka and Wakatipu basins, central Otago, New. Zealand; Hydrogeol. J. 6 264–281. Rouxel M ...

  10. Geochemical processes controlling the groundwater quality in lower ...

    Indian Academy of Sciences (India)

    Hydrogeochemical study of groundwater was carried out in a part of the lower Palar river basin, southern India to determine the geochemical processes controlling the groundwater quality. Thirty-nine groundwater samples were collected from the study area and analysed for pH, Eh, EC, Ca, Mg, Na, K, HCO3, CO3, Cl and ...

  11. Geochemical and hydrodynamic phosphorus retention mechanisms in lowland catchments

    NARCIS (Netherlands)

    van der Grift, B.|info:eu-repo/dai/nl/373433484

    2017-01-01

    The release of phosphorus (P) to surface water from heavily fertilised agricultural fields is of major importance for surface water quality. The research reported in this thesis examined the role of geochemical and hydrodynamic processes controlling P speciation and transport in lowland catchments

  12. Uruguay Mining inventory. Florida fotoplano geochemical prospecting results

    International Nuclear Information System (INIS)

    Zeegers, H.; Artignan, D.; Vairon, P.

    1982-01-01

    This work is about the geochemical prospecting carried out in Florida fotoplano within the framework of Uruguay Mining inventory. In this work were covered 660 km2 obtaining 752 samples for study which were analyzed by Plasma Emission Spectrometry in Orleans BRGM laboratories

  13. Geochemical features of rare metal pegmatites in Nassarawa area ...

    African Journals Online (AJOL)

    Geochemical features of rare metal pegmatites in Nassarawa area, central Nigeria. JID Adekeye, OF Akintola. Abstract. No Abstract. Journal of Mining and Geology Vol. 43 (1) 2007: pp. 15-21. Full Text: EMAIL FULL TEXT EMAIL FULL TEXT · DOWNLOAD FULL TEXT DOWNLOAD FULL TEXT.

  14. Geochemical and petrogenetic trends of syenite and charnockitic ...

    African Journals Online (AJOL)

    Geochemical and petrogenetic trends of syenite and charnockitic rock of Ike Iho and Osuntedo areas, soutweastern Nigeria. AA Elueze, OO Kehinde-Phillips, OA Okunlola. Abstract. No Abstract. Journal of Mining and Geology Vol. 44 (1) 2008: pp. 21-36. Full Text: EMAIL FULL TEXT EMAIL FULL TEXT · DOWNLOAD FULL ...

  15. Uruguay Mining inventory. Minas fotoplano geochemical prospecting results

    International Nuclear Information System (INIS)

    Zeegers, H.; Artignan, D.; Vairon, P.

    1982-01-01

    This work is about the geochemical prospecting carried out in Minas fotoplano within the framework of Uruguay Mining inventory. In this work were covered 380 km2 obtaining with 433 samples for study which were analized by Plasma Emission Spectrometry in Orleans BRGM laboratories

  16. The geochemical behavior of protactinium 231 and its chosen geochemical analogue thorium in the biosphere

    International Nuclear Information System (INIS)

    Gillberg-Wickman, M.

    1983-03-01

    To be able to judge whether protactinium 231 might represent a major contribution to the human radiation risk from high level radioactive waste a literature study of the geochemical behavior of protactinium has been made. The interest in protactinium determinations has, as far, been in the field of marine geochemistry and geochronology. These investigations show that thorium may be used as a chemical analogue. The content of protactinium 231 is determined by the 235 U content and consequently the occurrence of protactinium in nature is directly associated to the geochemistry of uranium. The pronounced hydrolytic tendency of protactinium and its great sorption and coprecipitation capacity ought to prevent or at least appreciably delay its transport from a back-filled nuclear waste vault to the uppermost surface of the earth. It also has a tendency to form colloids or particulates which may be strongly fixed on a rock surface. In adsorption and desorption processes kinetics must play an important role. Our knowledge in this field is quite limited. Under the physico-chemical conditions in the sea, protactinium is rapidly scavenged from the water column by particulates. It accumulates in the sediments. (author)

  17. Geodynamic implications for zonal and meridional isotopic patterns across the northern Lau and North Fiji Basins

    Science.gov (United States)

    Price, Allison A.; Jackson, Matthew G.; Blichert-Toft, Janne; Kurz, Mark D.; Gill, Jim; Blusztajn, Jerzy; Jenner, Frances; Brens, Raul; Arculus, Richard

    2017-03-01

    We present new Sr-Nd-Pb-Hf-He isotopic data for 65 volcanic samples from the northern Lau and North Fiji Basins. This includes 47 lavas obtained from 40 dredge sites spanning an east-west transect across the Lau and North Fiji basins, 10 ocean island basalt (OIB)-type lavas collected from seven Fijian islands, and eight OIB lavas sampled on Rotuma. For the first time, we are able to map clear north-south and east-west geochemical gradients in 87Sr/86Sr across the northern Lau and North Fiji Basins: lavas with the most geochemically enriched radiogenic isotopic signatures are located in the northeast Lau Basin, while signatures of geochemical enrichment are diminished to the south and west away from the Samoan hot spot. Based on these geochemical patterns and plate reconstructions of the region, these observations are best explained by the addition of Samoa, Rurutu, and Rarotonga hot spot material over the past 4 Ma. We suggest that underplated Samoan material has been advected into the Lau Basin over the past ˜4 Ma. As the slab migrated west (and toward the Samoan plume) via rollback over time, younger and hotter (and therefore less viscous) underplated Samoan plume material was entrained. Thus, entrainment efficiency of underplated plume material was enhanced, and Samoan plume signatures in the Lau Basin became stronger as the trench approached the Samoan hot spot. The addition of subducted volcanoes from the Cook-Austral Volcanic Lineament first from the Rarotonga hot spot, then followed by the Rurutu hot spot, contributes to the extreme geochemical signatures observed in the northeast Lau Basin.

  18. Geological evolution of the Neoproterozoic Bemarivo Belt, northern Madagascar

    Science.gov (United States)

    Thomas, Ronald J.; De Waele, B.; Schofield, D.I.; Goodenough, K.M.; Horstwood, M.; Tucker, R.; Bauer, W.; Annells, R.; Howard, K. J.; Walsh, G.; Rabarimanana, M.; Rafahatelo, J.-M.; Ralison, A.V.; Randriamananjara, T.

    2009-01-01

    The broadly east-west trending, Late Neoproterozoic Bemarivo Belt in northern Madagascar has been re-surveyed at 1:100 000 scale as part of a large multi-disciplinary World Bank-sponsored project. The work included acquisition of 14 U-Pb zircon dates and whole-rock major and trace element geochemical data of representative rocks. The belt has previously been modelled as a juvenile Neoproterozoic arc and our findings broadly support that model. The integrated datasets indicate that the Bemarivo Belt is separated by a major ductile shear zone into northern and southern "terranes", each with different lithostratigraphy and ages. However, both formed as Neoproterozoic arc/marginal basin assemblages that were translated southwards over the north-south trending domains of "cratonic" Madagascar, during the main collisional phase of the East African Orogeny at ca. 540 Ma. The older, southern terrane consists of a sequence of high-grade paragneisses (Sahantaha Group), which were derived from a Palaeoproterozoic source and formed a marginal sequence to the Archaean cratons to the south. These rocks are intruded by an extensive suite of arc-generated metamorphosed plutonic rocks, known as the Antsirabe Nord Suite. Four samples from this suite yielded U-Pb SHRIMP ages at ca. 750 Ma. The northern terrane consists of three groups of metamorphosed supracrustal rocks, including a possible Archaean sequence (Betsiaka Group: maximum depositional age approximately 2477 Ma) and two volcano-sedimentary sequences (high-grade Milanoa Group: maximum depositional age approximately 750 Ma; low grade Daraina Group: extrusive age = 720-740 Ma). These supracrustal rocks are intruded by another suite of arc-generated metamorphosed plutonic rocks, known as the Manambato Suite, 4 samples of which gave U-Pb SHRIMP ages between 705 and 718 Ma. Whole-rock geochemical data confirm the calc-alkaline, arc-related nature of the plutonic rocks. The volcanic rocks of the Daraina and Milanoa groups also

  19. GEOBASI: The geochemical Database of Tuscany Region (Italy

    Directory of Open Access Journals (Sweden)

    Brunella Raco

    2015-03-01

    Full Text Available In this study the new Regional Geochemical Database (RGDB, called GEOBASI, is presented and illustrated in the framework of a joint collaboration among the three Tuscan universities (Florence, Pisa and Siena, CNR-IGG (Institute of Geosciences and Earth Resources of Pisa, ARPAT (Regional Agency for the Environmental Protection, LAMMA (Environmental Modelling and Monitoring Laboratory for Sustainable Development Consortium and S.I.R.A. (Territorial and Environmental Informative System of Tuscany. The database has permitted the construction of a repository where the geochemical information (compositional and isotopic has been stored in a structured way so that it can be available for different groups of users (e.g. institutional, public and private companies. The information contained in the database can in fact be downloaded freely and queried to correlate geochemistry to other non compositional variables. The first phase of the project was aimed at promoting the use of the geochemical data already available from previous investigations through a powerful Web-GIS interface to implement the exploratory statistics graphical-numerical tools used to: 1 analyse the spatial variability of the investigated context, 2 highlight the geographic location of data pertaining to classes of values or single cases, 3 compare the results of different analytical methodologies applied to the determination of the same element and/or chemical species, 4 extract the geochemical data related to specific monitoring plans and/or geographical areas, and finally 5 recover information about data below the detection limit to understand their impact on the behaviour of the investigated variable. Developments of this project will be focused on the definition of rules and standardized methods in a way that external users could also interactively pursue the RGDB. Furthermore, a detailed investigation of the Scarlino-Follonica plain will permit the improvement and test of

  20. Validation of the WATEQ4 geochemical model for uranium

    International Nuclear Information System (INIS)

    Krupka, K.M.; Jenne, E.A.; Deutsch, W.J.

    1983-09-01

    As part of the Geochemical Modeling and Nuclide/Rock/Groundwater Interactions Studies Program, a study was conducted to partially validate the WATEQ4 aqueous speciation-solubility geochemical model for uranium. The solubility controls determined with the WATEQ4 geochemical model were in excellent agreement with those laboratory studies in which the solids schoepite [UO 2 (OH) 2 . H 2 O], UO 2 (OH) 2 , and rutherfordine ((UO 2 CO 3 ) were identified as actual solubility controls for uranium. The results of modeling solution analyses from laboratory studies of uranyl phosphate solids, however, identified possible errors in the characterization of solids in the original solubility experiments. As part of this study, significant deficiencies in the WATEQ4 thermodynamic data base for uranium solutes and solids were corrected. Revisions included recalculation of selected uranium reactions. Additionally, thermodynamic data for the hydroxyl complexes of U(VI), including anionic (VI) species, were evaluated (to the extent permitted by the available data). Vanadium reactions were also added to the thermodynamic data base because uranium-vanadium solids can exist in natural ground-water systems. This study is only a partial validation of the WATEQ4 geochemical model because the available laboratory solubility studies do not cover the range of solid phases, alkaline pH values, and concentrations of inorganic complexing ligands needed to evaluate the potential solubility of uranium in ground waters associated with various proposed nuclear waste repositories. Further validation of this or other geochemical models for uranium will require careful determinations of uraninite solubility over the pH range of 7 to 10 under highly reducing conditions and of uranyl hydroxide and phosphate solubilities over the pH range of 7 to 10 under oxygenated conditions

  1. Geochemical Anomalies in the Sediments of Lake Druksiai

    International Nuclear Information System (INIS)

    Kleinas, A.

    1999-01-01

    In order to evaluate the impact of Ignalina Nuclear Power Plant (NPP) on natural processes in Lake Druksiai and accumulation of pollutants, in 19931997, carrying on the state scientific program, the Marine Geochemistry Division of the Institute of Geography performed lithological geochemical mapping of lake bottom sediments on a scale of 1 .50 000. The results obtained enabled to distinguish zones of higher anthropogenous geochemical load, where geochemical anomalies of pollutants, including oil hydrocarbons and heavy metals, had been taken into account. Applying concentration coefficients for oil hydrocarbons and heavy metals (Cr, Cu, Ni, Pb, and Zn) and their natural background, the attempt was made to differentiate natural and technogenous components in the geochemical anomalies As expected, the finer sediments -aleurite-pelite mud - showed amounts of oil hydrocarbons and heavy metals being 12.1 times higher than in fine sand - the most coarse of the sediments studied Sediments with organic mater exceeding 20% contained 11.7 times more pollutants than those with organic matter below 1 .5%. Calculations of concentration coefficients (CC) showed no elements in no stations exceeded 10 - the sediments did not reach the category of high pollution However, in many sites, the coefficients exceeded values of 1-2, thus, showing sediments attributable to the categories of weakly polluted or just polluted. Mapping model done by GIS methods (by superimposing schemes of pollutant CCs distribution in the lake and summing them) for geochemical anomalies two derivative map-schemes were obtained for oil hydrocarbons and heavy metals. They showed that clean sediments cover just 24.75% (according to the pollutant background for soil types) and 12.35% (according to the organic matter background for its amount intervals) lake bottom area. Zones slightly polluted by an element at least cover 69.7 and 80.29% of lake area, correspondingly; whereas zones slightly polluted by all

  2. Geochemical analysis of soils and sediments, Coeur d'Alene drainage basin, Idaho: sampling, analytical methods, and results

    Science.gov (United States)

    Box, Stephen E.; Bookstrom, Arthur A.; Ikramuddin, Mohammed; Lindsay, James

    2001-01-01

    This report presents the locations, descriptions, analytical procedures used, and an inter-lab comparison of over 1100 geochemical analyses of samples of soil and sediment in and downstream of a major lead-zinc-silver mining district in the Coeur d'Alene (CdA) drainage basin of northern Idaho. The samples fall in 3 broad categories: (1) samples from vertical profiles of floodplain soils in the valley of the main stem of the CdA River (767 samples) and of the South Fork of the CdA River (38 samples), (2) size fractionated surficial samples of sediment bedload within the channel of the South Fork of the CdA River (68 samples), and (3) samples from vertical profiles of sediment bedload within the channel of the main stem of the CdA River (260 samples). Five different laboratories contributed geochemical data for this report. Four of the five laboratories employed analytical methods that require sample dissolution prior to analysis; one laboratory (US Geological Survey) used analytical instrumentation (energy dispersive x-ray fluorescence [EDXRF]) that is applied to pulverized samples. Some dissolution procedures use four acids (hydrochloric, nitric, perchloric, and hydrofluoric; Eastern Washington University [EWU] Geochemical Laboratory and XRAL Laboratories, Inc.), others use two acids (nitric acid and aqua regia; CHEMEX Labs, Inc.), and some use only concentrated nitric acid (ACZ Laboratories, Inc.). Most analyses of dissolved samples were done by Inductively Coupled Plasma - Atomic Emission Spectroscopy (ICP-AES) or by ICP - MS (Mass Spectroscopy). Some analyses for Ag and K were done by Flame Atomic Absorption (FAA). Inter-laboratory comparisons are made for 6 elements: lead (Pb), zinc (Zn), iron

  3. Evidence for trench-parallel mantle flow in the northern Cascade Arc from basalt geochemistry

    Science.gov (United States)

    Mullen, Emily K.; Weis, Dominique

    2015-03-01

    Geochemical data for basalts from the Garibaldi Volcanic Belt (northern segment of the Cascade Arc) define arc-parallel gradients in trace elements and isotope ratios that extend at least 150 km into the arc from the northern margin of the subducting Juan de Fuca plate. Southerly increases in Zr/Nb, Ba/Nb, Th/La, Pb/Ce, 208Pb/204Pb and 176Hf/177Hf indicate greater mantle depletion and higher slab-derived contributions with distance from the slab edge. Temperatures and pressures of mantle melt segregation also decrease to the south. The gradients are most plausibly explained as a consequence of slab rollback-induced toroidal flow at the northern slab edge (Nootka fault zone), whereby enriched (OIB-type) NE Pacific asthenospheric mantle from beneath the slab is drawn into the mantle wedge in a trench-parallel southerly flow pattern. Melts of the enriched asthenosphere are progressively diluted to the south by melts of the slab-modified, depleted mantle wedge. Arc-parallel changes in slab thermal conditions cannot account for these gradients. Trench parallel geochemical gradients in the northern Cascade Arc are consistent with shear wave splitting data, numerical modeling, and experimental studies showing that trench-parallel mantle flow may be a common phenomenon near slab edges and slab gaps.

  4. Geochemical characteristics of an urban river: Geochemical contamination and urban stream syndrome

    Science.gov (United States)

    MacAvoy, S. E.; Connor, N.; Sarraino, S.; Frantz, D.; Bushaw-Newton, K. L.

    2013-12-01

    The Anacostia River in Washington, D.C. is among the 10 most contaminated rivers in the USA, containing sewage, metals, PAHs, and PCBs. The biogeochemical characteristics of urban rivers, including the Anacostia, remain largely unstudied. Here we examine the base-flow geochemistry of the tidal freshwater Anacostia over a two-year period (April 2010- April 2012), concentrating on water chemistry (pH, hardness, SAR, alkalinity, Ca, Mg, Na, K, Fe, Mn, Zn, Al, Ba, Ni, P, S, Sr, NO3, NH4, PO4) at 3 locations in the stream. Mean NO3was generally between 1.1 and 1.3 mg/L, although occasionally concentrations increased to 3-4 mg/L at all sites. NH4 was very low generally (0.0 to 0.3 mg/L) with occasional peaks of 1.5-3.9 mg/L downstream. A Principle Components Analysis of stream chemistry showed that the upstream site had two components that explained 34.2 and 29.2% of the data variance; PC1 was most strongly negatively correlated with Ca (-.896), Mg (-.585) and hardness (-.823), and was positively correlated with Ba (which is sometimes associated with disturbance), B, NO3, P, PO4, Sr and Al. PC2 was strongly correlated with Mg, K, S, Ni and NH4. Na was positively and significantly correlated with both components, but more so with PC1. At the middle and downstream sites, two components explained 41 to 44% (PC1) and 22 to 28% (PC2) of the data set variance respectively. The components were essentially the same as the upstream site, with the dominance switched. PC1 was positively and highly correlated with ions associated with bedrock components (Ca, Mg, K, Na, and pH but also S and NH4). PC2 was not positively correlated with any of the dominant geochemical variables, but was negatively correlated with Ca and K and positively correlated with NO3, Ba and Mn. The principle components analysis suggests that there is a strong geochemical component and weaker anion/nitrate component contributing to the ion distribution, and their relative dominance changes moving downstream

  5. Use of geochemical biomarkers in bottom sediment to track oil from a spill, San Francisco Bay, California

    Science.gov (United States)

    Hostettler, F.D.; Rapp, J.B.; Kvenvolden, K.A.

    1992-01-01

    In April 1988, approximately 1500 m3 of a San Joaquin Valley crude oil were accidentally released from a Shell Oil Co. refinery near Martinez, Californa. The oil flowed into Carquinez Strait and Suisun Bay in northern San Francisco Bay Sediment and oil samples were collected within a week and analysed for geochemical marker compounds in order to track the molecular signature of the oil spill in the bottom sediment. Identification of the spilled oil in the sediment was complicated by the degraded nature of the oil and the similarity of the remaining, chromatographically resolvable constituents to those already present in the sediments from anthropogenic petroleum contamination, pyrogenic sources, and urban drainage. Ratios of hopane and sterane biomarkers, and of polycyclic aromatic hydrocarbons and their alkylated derivatives best identified the oil impingement. They showed the oil impact at this early stage to be surficial only, and to be patchy even within an area of heavy oil exposure.

  6. Correlation of fluid properties and geochemical parameters with heavy oil viscosity and density on trans-regional scale

    Energy Technology Data Exchange (ETDEWEB)

    Lehne, E.; Rojas, K.; McCarthy, K.; Taylor, S.D. [Schlumberger (Canada)

    2011-07-01

    Heavy oils around the world are characterized by high specific gravity and high contents of heavy components but their viscosity differs from one reservoir to another. This research aimed at finding correlations of geochemical characteristics with oil viscosity for heavy oil from different basins. This study was conducted on 15 heavy oil samples from northern and southern America and from Asia; the samples were characterized using gas chromatography, capillarity viscometer, data from stable carbon isotopes, SARA analysis, GC-FID and freezing point depression. Results showed that the degradation-viscosity correlation observed on a regional scale cannot be applied to the worldwide scale, and determined that, at that scale, oil viscosity depends on the original oil maturity and organofacies characteristics. In addition, biomarkers were found to help limit potential oil viscosity although they did not show a direct correlation. This study showed that original oil maturity and organofacies characteristics have to be taken into account in predictive models of oil viscosity.

  7. Northern Plains 'Crater'

    Science.gov (United States)

    2004-01-01

    10 December 2004 The lower left (southwest) corner of this Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows the location of a somewhat filled and buried meteor impact crater on the northern plains of Mars. The dark dots are boulders. A portion of a similar feature is seen in the upper right (northeast) corner of the image. This picture, showing landforms (including the odd mound north/northeast of the crater) that are typical of the martian northern lowland plains, was obtained as part of the MGS MOC effort to support the search for a landing site for the Phoenix Mars Scout lander. Phoenix will launch in 2007 and land on the northern plains in 2008. This image is located near 68.0oN, 227.4oW, and covers an area approximately 3 km (1.9 mi) wide. The scene is illuminated by sunlight from the lower left.

  8. Geochemical Parameters Required from the SKB Site Characterisation Programme

    International Nuclear Information System (INIS)

    Bath, Adrian

    2002-01-01

    SKB has described its approach to site characterisation in a number of Technical Reports. One of the scientific topics in which specific information requirements and priorities are set out is geochemistry. This report for SKI examines critically whether the geochemical parameters identified in the SKB programme documents will be adequate for safety and regulatory requirements. It also examines some of the details of parameter requirements and interpretation tools that will be necessary to convert site investigation data into knowledge about chemical conditions and groundwater movements. The SKB strategy for geochemical data focuses on a small number of 'suitability indicators', primarily dissolved oxygen, pH and salinity. Their parameter requirements aim to assess those primary characteristics, as well as to acquire a wider range of data that will support those assessments and provide a broader understanding of candidate areas. An initial observation in this review that, though it is a primary suitability indicator, dissolved oxygen apparently will not be measured and instead will be inferred from other redox indicators. This raises a number of issues about sampling and monitoring measures, analytical data reliability and sensitivity, and the degree of confidence in geochemical understanding. A geochemical programme involves reconnaissance by desk study and acquisition of new data at levels of details that are appropriate to the stage of site investigations. As early as possible, a conceptual model of a candidate area should help to define the objectives of geochemical measurements on both rock and groundwater samples. It is recommended that parameters requirements should be defined and considered not only in terms of isolated measurements but more in terms of addressing broader objectives that relate to safety and also to geoscientific understanding. The safety priorities remain (e.g. dissolved oxygen) but will then be supported by an understanding of processes

  9. Geochemical Parameters Required from the SKB Site Characterisation Programme

    Energy Technology Data Exchange (ETDEWEB)

    Bath, Adrian [Intellisci Ltd., Loughborough (United Kingdom)

    2002-01-01

    SKB has described its approach to site characterisation in a number of Technical Reports. One of the scientific topics in which specific information requirements and priorities are set out is geochemistry. This report for SKI examines critically whether the geochemical parameters identified in the SKB programme documents will be adequate for safety and regulatory requirements. It also examines some of the details of parameter requirements and interpretation tools that will be necessary to convert site investigation data into knowledge about chemical conditions and groundwater movements. The SKB strategy for geochemical data focuses on a small number of 'suitability indicators', primarily dissolved oxygen, pH and salinity. Their parameter requirements aim to assess those primary characteristics, as well as to acquire a wider range of data that will support those assessments and provide a broader understanding of candidate areas. An initial observation in this review that, though it is a primary suitability indicator, dissolved oxygen apparently will not be measured and instead will be inferred from other redox indicators. This raises a number of issues about sampling and monitoring measures, analytical data reliability and sensitivity, and the degree of confidence in geochemical understanding. A geochemical programme involves reconnaissance by desk study and acquisition of new data at levels of details that are appropriate to the stage of site investigations. As early as possible, a conceptual model of a candidate area should help to define the objectives of geochemical measurements on both rock and groundwater samples. It is recommended that parameters requirements should be defined and considered not only in terms of isolated measurements but more in terms of addressing broader objectives that relate to safety and also to geoscientific understanding. The safety priorities remain (e.g. dissolved oxygen) but will then be supported by an understanding of

  10. Northern Plains Buried Craters

    Science.gov (United States)

    2004-01-01

    22 December 2003This Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows three circular features on the martian northern plains near 70.7oN, 311.7oW. These circular features are the locations of meteor impact craters that have been buried beneath the plains. Much of the northern plains shares this story, in which thousands of old craters have been filled or partially filled and then thinly buried beneath textured plains. The picture covers an area 3 km (1.9 mi) wide. Sunlight illuminates the scene from the lower left.

  11. The use of geochemical speciation modelling to predict the impact of uranium to freshwater biota

    International Nuclear Information System (INIS)

    Markich, S.J.; Brown, P.L.; Jeffree, R.A.

    1996-01-01

    Uranium is the prime potential contaminant in mine waste waters that may be released from the Ranger Uranium Mine (RUM) into the receiving waters of the Magela Creek, Alligator Rivers Region, Northern Australia. The potential ecological impact of the migration of uranium, that would result from an elevation in its concentration above background, in the Magela Creek downstream of the RUM, has been experimentally investigated by integrating biomonitoring with geochemical speciation modelling. The freshwater bivalve Velesunio angasi, abundant throughout the Magela Creek catchment, was exposed to a variety of uranium concentrations in a synthetic Magela Creek water, at four pH levels (5.0, 5.3, 5.5 and 6.0), in the presence (3.05 and 7.50 mg l -1 ) and absence of a model fulvic acid (FA), and its behavioural response was measured. Speciation modelling, using the HARPHRQ code, provided evidence that UO 2+ 2 and UO 2 OH + are the uranium species most responsible (ca. 96%) for eliciting an adverse behavioural response when UO 2+ 2 is assigned twice the toxic effect of UO 2 OH + . This finding rejects the notion that biota respond specifically to the sum total of inorganic uranyl species. (orig.)

  12. ANISIAN TERRESTRIAL SEDIMENTS IN THE BÜKK MOUNTAINS (NE HUNGARY AND THEIR ROLE IN THE TRIASSIC RIFTING OF THEVARDAR-MELIATA BRANCH OF THE NEO-TETHYS OCEAN

    Directory of Open Access Journals (Sweden)

    FELICITÁSZ VELLEDITS

    2004-11-01

    Full Text Available In recent years detailed sedimentological and biostratigraphical investigations have revealed Anisian terrestrial sediments in three sections of the Bükk Mountains. In the northern part of the mountains fluviatile sediments were recognised while in the southern part lake deposits were observed. Based on the stratigraphical position and microfacies analyses of the resedimented grains, two terrestrial events can be reconstructed. The age of the younger is late Pelsonian-early Illyrian?. This can be correlated with the Richthofen Conglomerate in the Dolomites. The age of the older terrestrial event could not be established exactly but it must have happened either in the Pelsonian or in the Aegean-Bithynian; consequently it may correlate either with the Voltago or with the Piz de Peres Conglomerate in the Dolomites. The terrestrial sediments in the Bükk Mountains are parts of a volcano-sedimentary succession, which is characteristic of the updoming part of a rifting area. Terrestrial sediments in the southern part of the mountains represent the deepest part of the half-grabens, which originated during the course of the rifting. The present paper gives an overview of the Anisian-Lower Ladinian terrestrial sediments in the Southern Alps-Dinarides and considers their formation during the Triassic rifting of the Vardar-Meliata branch of the Neo-Tethys. 

  13. Status report on geochemical field results from Atlantic study sites

    International Nuclear Information System (INIS)

    Wilson, T.R.S.; Thomson, J.; Hydes, D.J.; Colley, S.

    1983-01-01

    This report summarises the results of preliminary geochemical investigations at three North Atlantic study areas. The two eastern sites, on the Cape Verde abyssal plain (CV2) and east of Great Meteor Seamount (GME) were visited during 1982. The results presented are preliminary. Studies in the western Atlantic, close to the Nares Abyssal Plain study site are more detailed and are presented in a separate paper. The report shows for the first time the relative redox status of the three sites. The differences are unexpectedly large, the most reduced cores being recovered at GME and the most oxidised at CV2. The sporadic nature of Recent sediment accumulation at these sites is also emphasised. In order to place these preliminary results in context their relevance to the production of mathematical system models is discussed in a closing section. The necessity for such models to rest on sound foundations of geochemical understanding is noted. Suggestions on future research priorities are offered for discussion. (author)

  14. Version 4. 00 of the MINTEQ geochemical code

    Energy Technology Data Exchange (ETDEWEB)

    Eary, L.E.; Jenne, E.A.

    1992-09-01

    The MINTEQ code is a thermodynamic model that can be used to calculate solution equilibria for geochemical applications. Included in the MINTEQ code are formulations for ionic speciation, ion exchange, adsorption, solubility, redox, gas-phase equilibria, and the dissolution of finite amounts of specified solids. Since the initial development of the MINTEQ geochemical code, a number of undocumented versions of the source code and data files have come into use at the Pacific Northwest Laboratory (PNL). This report documents these changes, describes source code modifications made for the Aquifer Thermal Energy Storage (ATES) program, and provides comprehensive listings of the data files. A version number of 4.00 has been assigned to the MINTEQ source code and the individual data files described in this report.

  15. Version 4.00 of the MINTEQ geochemical code

    Energy Technology Data Exchange (ETDEWEB)

    Eary, L.E.; Jenne, E.A.

    1992-09-01

    The MINTEQ code is a thermodynamic model that can be used to calculate solution equilibria for geochemical applications. Included in the MINTEQ code are formulations for ionic speciation, ion exchange, adsorption, solubility, redox, gas-phase equilibria, and the dissolution of finite amounts of specified solids. Since the initial development of the MINTEQ geochemical code, a number of undocumented versions of the source code and data files have come into use at the Pacific Northwest Laboratory (PNL). This report documents these changes, describes source code modifications made for the Aquifer Thermal Energy Storage (ATES) program, and provides comprehensive listings of the data files. A version number of 4.00 has been assigned to the MINTEQ source code and the individual data files described in this report.

  16. Geochemical normalization of magnetic susceptibility for investigation of floodplain sediments

    Czech Academy of Sciences Publication Activity Database

    Faměra, Martin; Matys Grygar, Tomáš; Elznicová, J.; Grison, Hana

    2018-01-01

    Roč. 77, č. 5 (2018), č. článku 189. ISSN 1866-6280 R&D Projects: GA ČR(CZ) GA15-00340S Institutional support: RVO:61388980 ; RVO:67985530 Keywords : Background functions * Geochemical normalization * Mass-specific magnetic susceptibility * Post-depositional processes * Provenance Subject RIV: DD - Geochemistry OBOR OECD: Environmental sciences (social aspects to be 5.7); Geology (GFU-E) Impact factor: 1.569, year: 2016

  17. Content analysis of ecosystems and geochemical cycles in portuguese textbooks

    OpenAIRE

    Tracana, Rosa Branca; Ferreira, Maria Eduarda; Carvalho, Graça Simões de

    2014-01-01

    There are many studies in recent times, on the theme Ecosystems and geochemical cycles. All authors expressed consensus in terms of the need to work content with our children and youth, to foster the development of skills that promote sustainable development. Our study is based on the teaching of science and also in the area of social pedagogy in the context of social representations. Thus, we intend to analyze the didactic transposition of the topic Ecosystems and Cycles, in terms of textboo...

  18. Geochemical prospecting for rare earth elements using termite mound materials

    Science.gov (United States)

    Horiuchi, Yu; Ohno, Tetsuji; Hoshino, Mihoko; Shin, Ki-Cheol; Murakami, Hiroyasu; Tsunematsu, Maiko; Watanabe, Yasushi

    2014-12-01

    The Blockspruit fluorite prospect, located in North West State of the Republic of South Africa, occurs within an actinolite rock zone that was emplaced into the Kenkelbos-type granite of Proterozoic age. There are a large number of termite mounds in the prospect. For geochemical prospecting for rare earth elements (REEs), in total, 200 samples of termite mound material were collected from actinolite rock and granite zones in the prospect. Geochemical analyses of these termite mound materials were conducted by two methods: portable X-ray fluorescence (XRF) spectrometry and inductively coupled plasma-mass spectrometry (ICP-MS). Comparison of the two methods broadly indicates positive correlations of REEs (La, Ce, Pr, Nd, and Y), in particular Y and La having a strong correlation. As the result of modal abundance analyses, the actinolite rock at surface mainly consists of ferro-actinolite (89.89 wt%) and includes xenotime (0.26 wt%) and monazite (0.21 wt%) grains as REE minerals. Termite mound materials from actinolite rock also contain xenotime (0.27 wt%) and monazite (0.41 wt%) grains. In addition, termite mound materials from the actinolite rock zone have high hematite and Fe silicate contents compared to those from granite zone. These relationships suggest that REE minerals in termite mound materials originate form actinolite rock. Geochemical anomaly maps of Y, La, and Fe concentrations drawn based on the result of the portable XRF analyses show that high concentrations of these elements trend from SW to NE which broadly correspond to occurrences of actinolite body. These results indicate that termite mounds are an effective tool for REE geochemical prospection in the study area for both light REEs and Y, but a more detailed survey is required to establish the distribution of the actinolite rock body.

  19. Northern blotting analysis

    DEFF Research Database (Denmark)

    Josefsen, Knud; Nielsen, Henrik

    2011-01-01

    Northern blotting analysis is a classical method for analysis of the size and steady-state level of a specific RNA in a complex sample. In short, the RNA is size-fractionated by gel electrophoresis and transferred by blotting onto a membrane to which the RNA is covalently bound. Then, the membrane...... the gap to the more laborious nuclease protection experiments....

  20. insurgencies in northern Uganda

    African Journals Online (AJOL)

    insurgency, the RUF would attack villages, hacking civilians to death, while those who would be abducted would have their arms and limbs hacked off. The LRA uses similar tactics on civilians (Apuuli 2004). The question that arises then is: In view of the LRA's continued atrocities against the people of northern Uganda, ...

  1. Northern blotting analysis

    DEFF Research Database (Denmark)

    Josefsen, Knud; Nielsen, Henrik

    2011-01-01

    is analysed by hybridization to one or more specific probes that are labelled for subsequent detection. Northern blotting is relatively simple to perform, inexpensive, and not plagued by artefacts. Recent developments of hybridization membranes and buffers have resulted in increased sensitivity closing...

  2. NORTHERN REGION OF GHANA

    African Journals Online (AJOL)

    2004-12-02

    Dec 2, 2004 ... It is recommended that deforestation and bush burning that will reduce vegetation cover and enhance evaporation from the soils should be checked through education of the citizens. Northern Region has vast areas of arable land which prospective farmers take advantage off. Such people cultivate the land ...

  3. Northern blotting analysis

    DEFF Research Database (Denmark)

    Josefsen, Knud; Nielsen, Henrik

    2011-01-01

    Northern blotting analysis is a classical method for analysis of the size and steady-state level of a specific RNA in a complex sample. In short, the RNA is size-fractionated by gel electrophoresis and transferred by blotting onto a membrane to which the RNA is covalently bound. Then, the membran...

  4. The role of atomic absorption spectrometry in geochemical exploration

    Science.gov (United States)

    Viets, J.G.; O'Leary, R. M.

    1992-01-01

    In this paper we briefly describe the principles of atomic absorption spectrometry (AAS) and the basic hardware components necessary to make measurements of analyte concentrations. Then we discuss a variety of methods that have been developed for the introduction of analyte atoms into the light path of the spectrophotometer. This section deals with sample digestion, elimination of interferences, and optimum production of ground-state atoms, all critical considerations when choosing an AAS method. Other critical considerations are cost, speed, simplicity, precision, and applicability of the method to the wide range of materials sampled in geochemical exploration. We cannot attempt to review all of the AAS methods developed for geological materials but instead will restrict our discussion to some of those appropriate for geochemical exploration. Our background and familiarity are reflected in the methods we discuss, and we have no doubt overlooked many good methods. Our discussion should therefore be considered a starting point in finding the right method for the problem, rather than the end of the search. Finally, we discuss the future of AAS relative to other instrumental techniques and the promising new directions for AAS in geochemical exploration. ?? 1992.

  5. Northern Pintail (Anas acuta)

    Science.gov (United States)

    Austin, J.E.; Miller, M.R.; Poole, A.; Gill, F.

    1995-01-01

    The Northern Pintail is a medium-sized dabbling duck of slender, elegant lines and conservative plumage coloration. It is circumpolar in distribution and abundant in North America, with core nesting habitat in Alaska and the Prairie Pothole Region of southern Canada and the northern Great Plains. Breeders favor shallow wetlands interspersed throughout prairie grasslands or arctic tundra. An early fall migrant, the species arrives on wintering areas beginning in August, after wing molt, often forming large roosting and feeding flocks on open, shallow wetlands and flooded agricultural fields. The birds consume grains, marsh plant seeds, and aquatic invertebrates throughout the fall and winter. Northern Pintails are among the earliest nesting ducks in North America, beginning shortly after ice-out in many northern areas. Individuals form new pair bonds each winter but are highly promiscuous during the nesting season, with mated and unmated males often involved in vigorous, acrobatic Pursuit Flights. Annual nest success and productivity vary with water conditions, predation, and weather. Females build nests on the ground, often long distances from water. Only the female incubates; her mate leaves shortly after incubation begins. Ducklings hatch together in one day, follow the female to water after a day in the nest, and fledge by July or August. Adults and ducklings consume mainly aquatic invertebrates during the breeding season. Predators and farming operations destroy many thousands of Northern Pintail nests annually; farming has also greatly reduced the amount of quality nesting cover available. Winter habitats are threatened by water shortages, agricultural development, contamination, and urbanization. Periods of extended drought in prairie nesting regions have caused dramatic population declines, usually followed by periods of recovery. Over the long term, however, the continental population of Northern Pintails has declined significantly from 6 million birds in

  6. Adaptive Multiscale Modeling of Geochemical Impacts on Fracture Evolution

    Science.gov (United States)

    Molins, S.; Trebotich, D.; Steefel, C. I.; Deng, H.

    2016-12-01

    Understanding fracture evolution is essential for many subsurface energy applications, including subsurface storage, shale gas production, fracking, CO2 sequestration, and geothermal energy extraction. Geochemical processes in particular play a significant role in the evolution of fractures through dissolution-driven widening, fines migration, and/or fracture sealing due to precipitation. One obstacle to understanding and exploiting geochemical fracture evolution is that it is a multiscale process. However, current geochemical modeling of fractures cannot capture this multi-scale nature of geochemical and mechanical impacts on fracture evolution, and is limited to either a continuum or pore-scale representation. Conventional continuum-scale models treat fractures as preferential flow paths, with their permeability evolving as a function (often, a cubic law) of the fracture aperture. This approach has the limitation that it oversimplifies flow within the fracture in its omission of pore scale effects while also assuming well-mixed conditions. More recently, pore-scale models along with advanced characterization techniques have allowed for accurate simulations of flow and reactive transport within the pore space (Molins et al., 2014, 2015). However, these models, even with high performance computing, are currently limited in their ability to treat tractable domain sizes (Steefel et al., 2013). Thus, there is a critical need to develop an adaptive modeling capability that can account for separate properties and processes, emergent and otherwise, in the fracture and the rock matrix at different spatial scales. Here we present an adaptive modeling capability that treats geochemical impacts on fracture evolution within a single multiscale framework. Model development makes use of the high performance simulation capability, Chombo-Crunch, leveraged by high resolution characterization and experiments. The modeling framework is based on the adaptive capability in Chombo

  7. Advantage of Chernobyl radionuclides at modelling of geochemical landscape

    International Nuclear Information System (INIS)

    Samsonenka, I.P.

    2002-01-01

    Any human activity causes a chemical alteration of environment. It occurs as a result of both the immediate emission of pollutants, and of violation of the ecosystems homeostasis. Under technogenic effect a geochemical field becomes still more variegated. This phenomenon is formed by subjective processes. In this case the unconditional application of statistical methods is not correct. Efficiently a contamination patchiness is scrutinised by method of a radioactive label, as some pollutants are allocated on a surface similarly artificial radionuclides. During 10 years the radioecological investigation like this was carried out in the moderate contamination area of Chernobyl zone. Nuclide 137Cs predominant on this terrain was used as a tracer. It turned out that the pollution field heterogeneity is depended on structure of landscape most intimately. The modelling of 137Cs allocation allowed to establish the attitude of background and anomalous zone. Principal premise of beginnings of an anomaly is the interplay of migration streams with geochemical barriers. Combination of these factors determines the radiological and geochemical parameters. The behaviour of other pollutants (Sr, Pb, Cu, Zn, Ni, Cr, Co) in discrete segments of elementary landscape also rather differs. Within test area six types of positive going local geochemical anomalies are being discovered. The detailed analysis of them has resulted in creation of new technique of account of pollutants total inventory. This parameter is computed with the use of correction for a natural patchiness. For example the stoichiometric relationship show that an average of 0.73 % of the total 137Cs inventory was involved in the processes of secondary redistribution. More than on third of this value (0.26 %) was fixed at local geochemical barriers within eluvial landscapes and formed radiogeochemical anomalies at the intra facies level. The other portion of 137Cs inventory (0.47 %) was removed outside the boundaries of

  8. A Spatially Constrained Multi-autoencoder Approach for Multivariate Geochemical Anomaly Recognition

    Science.gov (United States)

    Lirong, C.; Qingfeng, G.; Renguang, Z.; Yihui, X.

    2017-12-01

    Separating and recognizing geochemical anomalies from the geochemical background is one of the key tasks in geochemical exploration. Many methods have been developed, such as calculating the mean ±2 standard deviation, and fractal/multifractal models. In recent years, deep autoencoder, a deep learning approach, have been used for multivariate geochemical anomaly recognition. While being able to deal with the non-normal distributions of geochemical concentrations and the non-linear relationships among them, this self-supervised learning method does not take into account the spatial heterogeneity of geochemical background and the uncertainty induced by the randomly initialized weights of neurons, leading to ineffective recognition of weak anomalies. In this paper, we introduce a spatially constrained multi-autoencoder (SCMA) approach for multivariate geochemical anomaly recognition, which includes two steps: spatial partitioning and anomaly score computation. The first step divides the study area into multiple sub-regions to segregate the geochemical background, by grouping the geochemical samples through K-means clustering, spatial filtering, and spatial constraining rules. In the second step, for each sub-region, a group of autoencoder neural networks are constructed with an identical structure but different initial weights on neurons. Each autoencoder is trained using the geochemical samples within the corresponding sub-region to learn the sub-regional geochemical background. The best autoencoder of a group is chosen as the final model for the corresponding sub-region. The anomaly score at each location can then be calculated as the euclidean distance between the observed concentrations and reconstructed concentrations of geochemical elements.The experiments using the geochemical data and Fe deposits in the southwestern Fujian province of China showed that our SCMA approach greatly improved the recognition of weak anomalies, achieving the AUC of 0.89, compared

  9. Geochemical and isotopic characterization of the ground water of Oued Laya

    International Nuclear Information System (INIS)

    Hkiri, Sabrine

    2010-01-01

    salinity. The study of the flow direction does not verify the hypothesis of seawater intrusion by cons lithostratigraphic study illustrates the event of dissolution of evaporite existing in some geological formations. This hypothesis was verified mainly by geochemical study suggests a geological origin of salinity. 1- This was confirmed by the interpretation of salinity maps and diagrams as well as chemical relationships between the main key elements. 2- The return of irrigation water remains to be confirmed by other analytical approaches such as isotope geochemistry (stable isotopes of nitrogen 15N coupled with nitrate levels). 3- In response to the decline of groundwater level and increased salinity of the water, the possibility of artificial recharge from the northern waters, is a plausible solution.

  10. Geochemical Study on an Abandoned Copper Smelting Plant Using Rare Earth Elements

    Science.gov (United States)

    Sun, S. H.

    2017-12-01

    The Shuei Nan Dong Copper Smelting Plant smelting is located on the northern coast of New Taipei City, Taiwan. The plant built in 1906 for but has been shut down since 1987. However, the watershed is continuing to discharge acid mine water into the sea; and, the acid mine drainage releases high amounts of sulfate, heavy metals without any treatment. In this study, the water samples were sequentially collected along the main channel and its tributaries in the watershed. The results of hydrochemical analysis show that the untreated inflow water can be characterized with low pH value of water is much less contaminated in the upstream area until a major tributary converge. The results of principal component analysis (PCA) demonstrate that the first principal component (PC) can explain >80% of the total variance and almost all chemical components have high loadings in the PC. Therefore, the hydrochemical properties in the watershed are mainly dominated by the mixing process between main channel and the major tributary but the geochemical reactions during flow down the channel is insignificant. Rare earth elements (REE) are an excellent tracer, which can indicate sources of chemical components and geochemical reactions in water. The analysis results demonstrate two distinct REE patterns. The water with low REE can be characterized by prominent Eu positive anomaly and Ce negative anomaly, which may result from the alteration of Na-plagioclase in sandstone and oxidation reaction when contact with air, respectively. On the contrary, the water with high REE shows only minor Ce negative anomaly and insignificant Eu positive anomaly. In addition, there is an enrichment of middle REE in high-REE water, which is quite different with the REE pattern of pyrite. According to the Grawunder's study (2014), it corresponds to the complexation to sulphite during pyrite oxidation. It is worth noting that REE show no considerable fractionation along the channel and confirms the results

  11. Geology of the Ulugh Muztagh area, northern Tibet

    International Nuclear Information System (INIS)

    Burchfiel, B.C.; Molnar, P.

    1989-01-01

    Within the Ulugh Muztagh area, north central Tibet, an east-west-trending ophiolitic melange marks a suture that apparently was formed during a late Triassic or slightly younger collision between a continental fragment to the south and the rest of Asia. The southern continental fragment carries a thick sequence of upper Triassic sandstone, but the contact between the sandstone and the ophiolitic melange is covered by a younger redbed sequence of unknown age. A suite of 2-mica, tourmaline-bearing leucogranite plutons and dikes intruded the Triassic sandstone at shallow crustal levels 10.5 to 8.4 Ma. These rocks range from granite to tonalite in composition, are geochemically very similar to slightly older High Himalayan leucogranite and are interpreted to have been derived by the partial melting of crustal material. We interpret this to mean that crustal thickening began in this part of the Tibetan plateau at least by 10.5 Ma. Welded rhyolitic tuff rests on a conglomerate that consists of abundant debris from the Ulugh Muztagh intrusive rocks and has yielded Ar/Ar ages of about 4 Ma. The tuffs are geochemically identical to the intrusive rocks suggesting that crustal thickening may have continued to 4 Ma. Crustal thickening probably occurred by distributed crustal shortening similar to shortening now occurring north of Ulugh Muztagh along the northern margin of the Tibetan Plateau. (orig.)

  12. Geological environments of the uranium occurrences of the northern region

    International Nuclear Information System (INIS)

    Singh, Jagmer

    1997-01-01

    The areas covered under the northern region comprise parts of the three physiographic divisions, namely, the peninsular region, the Indo-Gangetic plains and the extra-peninsular regions. For exploring the concealed type of uranium mineralisation, more and more emphasis is being attached to geochemical and geophysical methods followed by exploratory drilling. These efforts are providing positive information which is being gradually tested by drilling. Likewise the occurrences the extra peninsular region have experienced multiphase deformation histories leading to truncation and breaking of the mineralised horizons. This is leading to problems of correlation and location of large sized mineralised bodies. The areas which have experienced comparatively lesser deformation are the basins which have been constricted by way of the basement configuration and concealment by the younger sediments are expected to be important target areas for large sized uranium deposits

  13. Northern pipelines : backgrounder

    International Nuclear Information System (INIS)

    2002-04-01

    Most analysts agree that demand for natural gas in North America will continue to grow. Favourable market conditions created by rising demand and declining production have sparked renewed interest in northern natural gas development. The 2002 Annual Energy Outlook forecasted U.S. consumption to increase at an annual average rate of 2 per cent from 22.8 trillion cubic feet to 33.8 TCF by 2020, mostly due to rapid growth in demand for electric power generation. Natural gas prices are also expected to increase at an annual average rate of 1.6 per cent, reaching $3.26 per thousand cubic feet in 2020. There are currently 3 proposals for pipelines to move northern gas to US markets. They include a stand-alone Mackenzie Delta Project, the Alaska Highway Pipeline Project, and an offshore route that would combine Alaskan and Canadian gas in a pipeline across the floor of the Beaufort Sea. Current market conditions and demand suggest that the projects are not mutually exclusive, but complimentary. The factors that differentiate northern pipeline proposals are reserves, preparedness for market, costs, engineering, and environmental differences. Canada has affirmed its role to provide the regulatory and fiscal certainty needed by industry to make investment decisions. The Government of the Yukon does not believe that the Alaska Highway Project will shut in Mackenzie Delta gas, but will instead pave the way for development of a new northern natural gas industry. The Alaska Highway Pipeline Project will bring significant benefits for the Yukon, the Northwest Territories and the rest of Canada. Unresolved land claims are one of the challenges that has to be addressed for both Yukon and the Northwest Territories, as the proposed Alaska Highway Pipeline will travel through traditional territories of several Yukon first Nations. 1 tab., 4 figs

  14. Hydrologic and geochemical factors governing chemical evolution of discharges from an abandoned, flooded, underground coal mine network

    Energy Technology Data Exchange (ETDEWEB)

    McDonough, K.M.; Lambert, D.C.; Mugunthan, P.; Dzombak, D.A. [Carnegie Mellon University, Pittsburgh, PA (US). Dept. of Civil and Environmental Engineering

    2005-04-01

    Discharges from some underground flooded coal mines have exhibited increases in pH and reductions in contaminant loadings with time. Data from a study of mine water quality evolution in interconnected, flooded mines of the Uniontown syncline, Southwestern Pennsylvania were evaluated with the aid of modeling to elucidate the hydrologic and geochemical factors responsible for such changes. Coal barriers left in place from mining operations define three hydraulically distinct but interconnected zones: the southern, central, and northern pools. Assuming each mine pool to behave as a completely mixed tank reactor, a steady-state, tanks-in-series model was developed to describe system hydraulics. Chemical modeling components were coupled with the tank reactor hydraulic model to simulate inputs to the mine voids, acid generation from pyrite dissolution, and discharge water quality. Empirical in-mine chemical production terms were estimated for each of the mine pools based on discharge data from 1974 to 1975 and 1998 to 2000. The production terms were then used to simulate discharge water quality for each of the mine pools over a 50 year period. Simulated water quality in the northern and central mine pools reached steady-state conditions approximately 25-30 years after the mine pools flooded, evolving over time to reflect the recharge water quality. The simulation results indicate that the evolution of mine water quality in the flooded mine voids has been governed by alkaline recharge water slowly displacing acidic 'first flush' water.

  15. Factor analysis of rock, soil and water geochemical data from Salem magnesite mines and surrounding area, Salem, southern India

    Science.gov (United States)

    Satyanarayanan, M.; Eswaramoorthi, S.; Subramanian, S.; Periakali, P.

    2017-09-01

    Geochemical analytical data of 15 representative rock samples, 34 soil samples and 55 groundwater samples collected from Salem magnesite mines and surrounding area in Salem, southern India, were subjected to R-mode factor analysis. A maximum of three factors account for 93.8 % variance in rock data, six factors for 84 % variance in soil data, five factors for 71.2 % in groundwater data during summer and six factors for 73.7 % during winter. Total dissolved solids are predominantly contributed by Mg, Na, Cl and SO4 ions in both seasons and are derived from the country rock and mining waste by dissolution of minerals like magnesite, gypsum, halite. The results also show that groundwater is enriched in considerable amount of minor and trace elements (Fe, Mn, Ni, Cr and Co). Nickel, chromium and cobalt in groundwater and soil are derived from leaching of huge mine dumps deposited by selective magnesite mining activity. The factor analysis on trivalent, hexavalent and total Cr in groundwater indicates that most of the Cr in summer is trivalent and in winter hexavalent. The gradational decrease in topographical elevation from northern mine area to the southern residential area, combined regional hydrogeological factors and distribution of ultramafic rocks in the northern part of the study area indicate that these toxic trace elements in water were derived from mine dumps.

  16. Semi-detailed uranium geochemical survey in Northwestern Samar (27 March 1979 - 4 July 1979)

    International Nuclear Information System (INIS)

    Santos, G. Jr.; Ogena, M.; Tauli, G.

    1980-04-01

    A uranium geochemical survey was conducted to delineate in detail the uranium prospective area(s) in northwestern Samar. A total of 805 stream sediments and 1.115 water samples were obtained from the target areas from uranium analysis. Geochemical anomalies were indicated in San Isidro and Mauo. Geochemical correlations between uranium and trace elements (Pb, Ag, Ni, Cu, Co, Zn and Mn) were generally poor. (ELC)

  17. Postcards from Mars: Insights into Martian Geochemical Processes from the Curiosity Rover

    OpenAIRE

    Leshin, L. A.; Grotzinger, J. P.; Blake, D. F.; Gellert, R.; Mahaffy, P. R.; Wiens, R. C.; Maurice, S.

    2013-01-01

    With the successful landing of the Mars Curiosity Rover in August 2012, we now have the most capable geochemical laboratory ever to travel to another planet roving Mars’ Gale crater. The geochemical instrument suite includes the Chemistry Camera (ChemCam), which uses a laser to vaporize geologic targets and performs atomic emission spectroscopy on the vapor from distances of up to 7m. This provides a geochemical surveying capability that enables rapid identification of...

  18. A Guide for Using Geochemical Methods in Dredged Material, Sediment Tracking, and Sediment Budget Studies

    Science.gov (United States)

    2017-06-26

    ER D C TR -1 7- 3 Dredging Operations and Environmental Research Program A Guide for Using Geochemical Methods in Dredged Material ...June 2017 A Guide for Using Geochemical Methods in Dredged Material , Sediment Tracking, and Sediment Budget Studies Heidi M. Wadman Coastal and...and Development Center Vicksburg, MS 39180-6199 Under Project 449021, “Geochemical and Other Tracers for Dredged Material Fate” ERDC TR-17-3 ii

  19. Geochemical investigation of UMTRAP designated site at Durango, Colorado

    International Nuclear Information System (INIS)

    Markos, G.; Bush, K.J.

    1983-09-01

    This report is the result of a geochemical investigation of the former uranium mill and tailings site at Durango, Colorado. This is one in a series of site specific geochemical investigations performed on the inactive uranium mill tailings included in the UMTRA Project. The objectives of the investigation are to characterize the geochemistry, to determine the contaminant distribution resulting from the former milling activities and tailings, and to infer chemical pathways and transport mechanisms from the contaminant distribution. The results will be used to model contaminant migration and to develop criteria for long-term containment media such as a cover system which is impermeable to contaminant migration. This report assumes a familiarity with the hydrologic conditions of the site and the geochemical concepts underlying the investigation. The results reported are based on a one-time sampling of waters and solid material from the background, the area adjacent to the site, and the site. The solid samples are water extracted remove easily soluble salts and acids extracted to remove cabonates and hydroxides. The water extracts and solid samples were analyzed for the major and trace elements. A limited number of samples were analyzed for radiological components. The report includes the methods of sampling, sample processing, analysis, and data interpretation. Three major conclusions are: (1) carbonate salts and low TDS characterize the tailings; (2) the adjacent area and raffinate ponds contain contaminants deposited by a single event of fluid permeation of the soils; and (3) the Animas River adjacent to the site has elevated gross alpha activity attributed to 226 Ra in the sediments derived from the tailings or milling activities

  20. Leveling data in geochemical mapping: scope of application, pros and cons of existing methods

    Science.gov (United States)

    Pereira, Benoît; Vandeuren, Aubry; Sonnet, Philippe

    2017-04-01

    Geochemical mapping successfully met a range of needs from mineral exploration to environmental management. In Europe and around the world numerous geochemical datasets already exist. These datasets may originate from geochemical mapping projects or from the collection of sample analyses requested by environmental protection regulatory bodies. Combining datasets can be highly beneficial for establishing geochemical maps with increased resolution and/or coverage area. However this practice requires assessing the equivalence between datasets and, if needed, applying data leveling to remove possible biases between datasets. In the literature, several procedures for assessing dataset equivalence and leveling data are proposed. Daneshfar & Cameron (1998) proposed a method for the leveling of two adjacent datasets while Pereira et al. (2016) proposed two methods for the leveling of datasets that contain records located within the same geographical area. Each discussed method requires its own set of assumptions (underlying populations of data, spatial distribution of data, etc.). Here we propose to discuss the scope of application, pros, cons and practical recommendations for each method. This work is illustrated with several case studies in Wallonia (Southern Belgium) and in Europe involving trace element geochemical datasets. References: Daneshfar, B. & Cameron, E. (1998), Leveling geochemical data between map sheets, Journal of Geochemical Exploration 63(3), 189-201. Pereira, B.; Vandeuren, A.; Govaerts, B. B. & Sonnet, P. (2016), Assessing dataset equivalence and leveling data in geochemical mapping, Journal of Geochemical Exploration 168, 36-48.

  1. Geochemical evolution of magmatism in Archean granite-greenstone terrains

    Science.gov (United States)

    Samsonov, A. V.; Larionova, Yu. O.

    2006-05-01

    Evolution of Archean magmatism is one of the key problems concerning the early formation stages of the Earth crust and biosphere, because that evolution exactly controlled variable concentrations of chemical elements in the World Ocean, which are important for metabolism. Geochemical evolution of magmatism between 3.5 and 2.7 Ga is considered based on database characterizing volcanic and intrusive rock complexes of granite-greenstone terrains (GGT) studied most comprehensively in the Karelian (2.9-2.7 Ga) and Kaapvaal (3.5-2.9 Ga) cratons and in the Pilbara block (3.5-2.9 Ga). Trends of magmatic geochemical evolution in the mentioned GGTs were similar in general. At the early stage of their development, tholeiitic magmas were considerably enriched in chalcophile and siderophile elements Fe2O3, MgO, Cr, Ni, Co, V, Cu, and Zn. At the next stage, calc-alkaline volcanics of greenstone belts and syntectonic TTG granitoids were enriched in lithophile elements Rb, Cs, Ba, Th, U, Pb, Nb, La, Sr, Be and others. Elevated concentrations of both the “crustal” and “mantle-derived” elements represented a distinctive feature of predominantly intrusive rocks of granitoid composition, which were characteristic of the terminal stage of continental crust formation in the GGTs, because older silicic rocks and lithospheric mantle were jointly involved into processes of magma generation. On the other hand, the GGTs different in age reveal specific trends in geochemical evolution of rock associations close in composition and geological position. First, the geochemical cycle of GGT evolution was of a longer duration in the Paleoarchean than in the Meso-and Neoarchean. Second, the Paleoarche an tholeiitic associations had higher concentrations of LREE and HFSE (Zr, Ti, Th, Nb, Ta, Hf) than their Meso-and Neoarchean counterparts. Third, the Y and Yb concentrations in Paleoarchean calc-alkaline rock associations are systematically higher than in Neoarchean rocks of the same type

  2. Geochemical association of plutonium in marine sediments from Palomares (Spain)

    International Nuclear Information System (INIS)

    Anton, M.P.; Gasco, C.; Sanchez-Cabeza, J.A.; Pujol, L.

    1994-01-01

    The geochemical association of plutonium in sediments from the marine ecosystem of Palomares has been studied. A sequential leaching technique using selective extractants has been employed to determine the percentages of Pu in the following forms: (a) readily available, (b) exchangeable and adsorbed to specific sites, (c) associated with organic matter, (d) sesquioxides, (e) residual. Plutonium was found to be associated mainly with phases (c), (d) and (e), and therefore, appears to be relatively immobile and not readily available to bottom feeding biota. The effect of different source terms on Pu distribution is also discussed. (orig.)

  3. Experimental insights into geochemical changes in hydraulically fractured Marcellus Shale

    International Nuclear Information System (INIS)

    Marcon, Virginia; Joseph, Craig; Carter, Kimberly E.; Hedges, Sheila W.; Lopano, Christina L.; Guthrie, George D.; Hakala, J. Alexandra

    2017-01-01

    Hydraulic fracturing applied to organic-rich shales has significantly increased the recoverable volume of methane available for U.S. energy consumption. Fluid-shale reactions in the reservoir may affect long-term reservoir productivity and waste management needs through changes to fracture mineral composition and produced fluid chemical composition. We performed laboratory experiments with Marcellus Shale and lab-generated hydraulic fracturing fluid at elevated pressures and temperatures to evaluate mineral reactions and the release of trace elements into solution. Results from the experiment containing fracturing chemicals show evidence for clay and carbonate dissolution, secondary clay and anhydrite precipitation, and early-stage (24–48 h) fluid enrichment of certain elements followed by depletion in later stages (i.e. Al, Cd, Co, Cr, Cu, Ni, Sc, Zn). Other elements such as As, Fe, Mn, Sr, and Y increased in concentration and remained elevated throughout the duration of the experiment with fracturing fluid. Geochemical modeling of experimental fluid data indicates primary clay dissolution, and secondary formation of smectites and barite, after reaction with fracturing fluid. Changes in aqueous organic composition were observed, indicating organic additives may be chemically transformed or sequestered by the formation after hydraulic fracturing. The NaCl concentrations in our fluids are similar to measured concentrations in Marcellus Shale produced waters, showing that these experiments are representative of reservoir fluid chemistries and can provide insight on geochemical reactions that occur in the field. These results can be applied towards evaluating the evolution of hydraulically-fractured reservoirs, and towards understanding geochemical processes that control the composition of produced water from unconventional shales. - Highlights: • Metal concentrations could be at their peak in produced waters recovered 24–48 after fracturing. • Carbonate

  4. Preliminary study of volcano monitoring using geochemical composition of lichen

    Science.gov (United States)

    KUAN, S.

    2012-12-01

    Taipei City, the capital of Taiwan, is bounded with Tatun Volcano Group (TVG), which is not active since 200 ka. However, some evidences indicate that the latest explosion of volcanic ash was dated to 5-6 ka as well as TVG is so close to metropolis. The monitoring on TVG is crucial for crisis management. For monitoring TVG, changes of geochemical signal in some volcanic gases and hot springs are currently assessed by monthly sampling. The geochemistry of volcanic gas and hot spring represents a short-term condition on sampling time and is highly controlled by temperature and precipitation on the surface. A long-term average geochemistry will be very helpful to be compared with the results of volcanic gas and hot spring. A bioindicator not only has the ability to store geochemical compositions in their tissues but also has a wide geographical distribution. It is very suitable in this kind of study and lichen is one of the best bioindicators mainly because lichens grow slowly and have a large-scale dependence upon the environment for their nutrition, In TVG, the high SO2 content in the atmosphere results in the absence of fruticose lichen. On the contrary, crustos lichen is the most common species in the study area. For the preliminary analysis, one fruticose, four foliose and four crustos lichens were collected around the major emission centers of volcanic gas. According to the results of ICP-MS analysis, the abundances of heavy metals are generally in the order of Zn, Fe, Mn, Cu, Cr, Pb, Cd, Ni, V, Co and U. Factor analysis (FA) demonstrates that most of the metals show very high loadings in the first factor. This means that the fractionation of metals among different lichen species is minor and the geochemical compositions of lichen are possibly controlled by the same source (atmosphere). The second factor of FA includes Mn, Sr and Ba, which share the same oxidation state of +2 in acidic environment. This factor can describe the variation of Mn, Sr and Ba in the

  5. Overview of geochemical modeling needs for nuclear waste management

    International Nuclear Information System (INIS)

    Isherwood, D.; Wolery, T.

    1984-01-01

    Research needs include, but are not limited to: measurement of basic thermodynamic data at elevated temperatures for species identified by modelers as potentially important; evaluation of substances which control or limit precipitation and/or nucleation kinetics; sorption studies specifically designed to provide data needed for modeling. This includes the rate of sorption, desorption, and the characterization of the solid and aqueous phases; site-mixing models and thermodynamic data for secondary minerals that form solid solutions; the development of standard techniques for measuring rate laws for precipitation and dissolution kinetics; and measurement of rate laws describing redox kinetics, dissolution, and precipitation involving aqueous species and solid phases of interest to geochemical modelers

  6. Jurassic-Paleogene intraoceanic magmatic evolution of the Ankara Mélange, north-central Anatolia, Turkey

    Science.gov (United States)

    Sarifakioglu, E.; Dilek, Y.; Sevin, M.

    2014-02-01

    Neotethys was an open ocean with its MORB-type oceanic lithosphere by the early Triassic (or earlier). The latest Cretaceous-early Paleocene island arc volcanic, dike and plutonic rocks with subalkaline to alkaline geochemical affinities represent intraoceanic magmatism that developed on and across the subduction-accretion complex above a N-dipping, southward-rolling subducted lithospheric slab within the northern Neotethys. The Ankara Mélange thus exhibits the record of ∼ 120-130 million years of oceanic magmatism in geological history of the northern Neotethys.

  7. Geochemical and isotopic investigations on the thermal and mineral underground waters from the Republic of Moldova

    Science.gov (United States)

    Nisi, Barbara; Bogdevich, Oleg; Vaselli, Orlando; Nicoara, Igor; Tassi, Franco; Culighin, Elena; Mogorici, Cristina; Jeleapov, Victor; Mussi, Mario

    2017-04-01

    Republic of Moldova (RM) has a large spectrum of underground mineral waters (16 reservoirs) of eight principal aquifers, most of which affected by contaminants originated by natural sources and anthropogenic activities. Inorganic natural tracers and stable isotopes are useful tools to fingerprint the water source and solutes, respectively. The aim of this investigation was to determine the geochemical and isotopic features of the most important thermo- and mineral waters from RM to trace their flow pathways and evaluate the presence of deep fluid sources discharging from fault systems, developed in response to the structural setting of the area. To the best of our knowledge, no systematic geochemical investigations were previously carried out in this area. RM has an area of 33,840 km2 and lies within the East European Precambrian Platform, two structural and/or stratigraphic layers, which are distinguishable in basement and sedimentary cover in the northern and central part of country. The basement rocks include granites, gneisses and gabbros. The sedimentary cover, overlying the crystalline basement, is almost undeformed and consists of Upper Proterozoic, Mesozoic and Cenozoic rocks. The geological structure is like a matrix formed from different layers of rocks consisting of permeable and impermeable strata. The deep aquifers are situated down to 1,000 m depth from the bottom to the top: Vendian (Ediocariam) and crystalline basement rocks, Silurian crystalline limestone, Cretaceous limestone, Baden-Sarmatian limestone and clay-sand deposits, middle Sarmatian limestone and clay-sand layers. Other younger aquifers were not investigated. In this framework, 54 samples from the most important underground reservoirs of RM were collected and analyzed for major, trace species and dissolved gases. An inventory of isotopic (18O/16O and 2H/1H ratios in water and 13C/12C in dissolved CO2) features (including tritium units in selected samples) was also provided. By a

  8. Geochemical databases. Part 1. Pmatch: a program to manage thermochemical data. Part 2. The experimental validation of geochemical computer models

    International Nuclear Information System (INIS)

    Pearson, F.J. Jr.; Avis, J.D.; Nilsson, K.; Skytte Jensen, B.

    1993-01-01

    This work is carried out under cost-sharing contract with European Atomic Energy Community in the framework of its programme on Management and Storage of Radioactive Wastes. Part 1: PMATCH, A Program to Manage Thermochemical Data, describes the development and use of a computer program, by means of which new thermodynamic data from literature may be referenced to a common frame and thereby become internally consistent with an existing database. The report presents the relevant thermodynamic expressions and their use in the program is discussed. When there is not sufficient thermodynamic data available to describe a species behaviour under all conceivable conditions, the problems arising are thoroughly discussed and the available data is handled by approximating expressions. Part II: The Experimental Validation of Geochemical Computer models are the results of experimental investigations of the equilibria established in aqueous suspensions of mixtures of carbonate minerals (Calcium, magnesium, manganese and europium carbonates) compared with theoretical calculations made by means of the geochemical JENSEN program. The study revealed that the geochemical computer program worked well, and that its database was of sufficient validity. However, it was observed that experimental difficulties could hardly be avoided, when as here a gaseous component took part in the equilibria. Whereas the magnesium and calcium carbonates did not demonstrate mutual solid solubility, this produced abnormal effects when manganese and calcium carbonates were mixed resulting in a diminished solubility of both manganese and calcium. With tracer amounts of europium added to a suspension of calcite in sodium carbonate solutions long term experiments revealed a transition after 1-2 months, whereby the tracer became more strongly adsorbed onto calcite. The transition is interpreted as the nucleation and formation of a surface phase incorporating the 'species' NaEu(Co 3 ) 2

  9. Multivariate analysis relating oil shale geochemical properties to NMR relaxometry

    Science.gov (United States)

    Birdwell, Justin E.; Washburn, Kathryn E.

    2015-01-01

    Low-field nuclear magnetic resonance (NMR) relaxometry has been used to provide insight into shale composition by separating relaxation responses from the various hydrogen-bearing phases present in shales in a noninvasive way. Previous low-field NMR work using solid-echo methods provided qualitative information on organic constituents associated with raw and pyrolyzed oil shale samples, but uncertainty in the interpretation of longitudinal-transverse (T1–T2) relaxometry correlation results indicated further study was required. Qualitative confirmation of peaks attributed to kerogen in oil shale was achieved by comparing T1–T2 correlation measurements made on oil shale samples to measurements made on kerogen isolated from those shales. Quantitative relationships between T1–T2 correlation data and organic geochemical properties of raw and pyrolyzed oil shales were determined using partial least-squares regression (PLSR). Relaxometry results were also compared to infrared spectra, and the results not only provided further confidence in the organic matter peak interpretations but also confirmed attribution of T1–T2 peaks to clay hydroxyls. In addition, PLSR analysis was applied to correlate relaxometry data to trace element concentrations with good success. The results of this work show that NMR relaxometry measurements using the solid-echo approach produce T1–T2 peak distributions that correlate well with geochemical properties of raw and pyrolyzed oil shales.

  10. Geochemical factors in borehole-shaft plug longevity

    International Nuclear Information System (INIS)

    Roy, D.M.

    1981-01-01

    Geochemical investigations that address factors controlling the longevity of repository sealing materials in a geochemical environment are discussed. Studies are being made of cement-based materials as major candidates for seals for borehole plugging, and shaft and tunnel sealing in certain potential repository environments. Factors controlling the extent of attainment of equilibrium of the plug components with time and the rate of approach to a state of stable equilibrium of the plug component chemical subsystem within the total system are discussed. The effect of these factors on changes in physical, mechanical and thermal properties of a seal system, and the consequent effectiveness of the seal in preventing transport of radioactive waste species are the dominant features to be determined. Laboratory experiments on the effects of anticipated temperature, pressure, and environmental factors (including chemical composition and specific rock type) are described. Thermodynamic studies are used to determine the potentially stable reaction products under conditions similar to those anticipated for the repository boreholes, shafts, and tunnels during and after the operating stage. Multitemperature reaction series are studied, and reaction kinetics are investigated for the purpose of predicting the course of likely reactions. Detailed studies of permeability, diffusion, and interfacial properties and chemical and microphase characterization of the products of experiments are carried out. Characterization studies of old and ancient cements, mortars, and concretes and prototype man-made seal materials are performed to further assess the factors associated with longevity

  11. Geochemical dispersion of uranium near prospects in Pennsylvania

    International Nuclear Information System (INIS)

    Rose, A.W.; Schmiermund, R.L.; Mahar, D.L.

    1977-06-01

    The geochemical dispersion of U was investigated near sedimentary uranium prospects in eastern and north-central Pennsylvania. Near Jim Thorpe, known uranium occurrences in the Catskill Fm. are limited to the base of the Duncannon member. At Penn Haven Junction, roll-type U deposits with appreciable Pb and Se are localized adjacent to an oxidized tongue of channel-filling conglomeratic sandstone. The channel and encircling U occurrences furnish a large target for geochemical exploration. Selective extractions show that the organic, Fe-oxide, sand and silt fractions of stream sediments are the major hosts for U in stream sediments. Fe-oxides have a greater affinity for U than organic matter but are less abundant. The U content of organic matter is about 10 5 times the U content of stream water. Stream sediments furnish a representative sample of the average content of U, Zn, Cu, and major elements in soils of a drainage basin in north-central Pennsylvania, so a semiquantitative appraisal of weathering uranium occurrences can be made from stream sediments in climates and topography like Pennsylvania. The flux of uranium leaving the basin in solution is about equal to that leaving as sediment. Uranium is considerably less mobile than Ca and Na. A new method of extracting uranium from water samples, using a liquid ion exchanger (Amberlite LA-1), shows promise for simple field application

  12. Microstructural and geochemical evolution of sliding surfaces in landslides

    Science.gov (United States)

    Schaebitz, M.; Janssen, C.; Wirth, R.; Dresen, G. H.

    2014-12-01

    The formation of basal sliding surfaces in mass movements is known to be associated with chemical and physical alteration of rock and regolith. To evaluate its microstructural and geochemical evolution we collected samples from the host rock to the sliding surface and adjacent deposits within landslides in Kirgizstan and central China. The sample locations represent different morphological and geological conditions to evaluate if the weakness of the sliding surface derives from general factors such as (micro)structural or mineralogical changes within the landslide body. Based on qualitative and quantitative geochemical analysis we could not find neither indication for notable weathering of the parent bedrock nor accumulation of clay minerals along the sliding surface to explain its reduced shear strength in the investigated near-surface landslides. The cataclasites are mainly composed of quartz, illite, calcite, kaolinite and feldspar with grain sizes between 5 μm down to contents towards the sliding surface, pointing to alteration processes. Transmission electron microscopy and focused ion beam technique for TEM sample preparation were used to compare the microstructures. It clearly revealed a severe reduction of grain size, and increase of pore space due to grain comminution by creeping and moving processes, indicating that elevated pore pressures are the main reason for the weakness of the sliding surfaces in shallow landslides. The comminution process within sliding surface formation seems to be comparable to fault gauge formation.

  13. Evolution of geochemical conditions in SFL 3-5

    International Nuclear Information System (INIS)

    Karlsson, Fred; Lindgren, M.; Skagius, K.; Wiborgh, M.; Engkvist, I.

    1999-12-01

    The evolution of geochemical conditions in the repository for long-lived low- and intermediate-level waste, SFL 3-5, and in the vicinity of the repository are important when predicting the retention of radionuclides and the long-term stability of engineered barriers. In this study the initial conditions at different repository sites at 300 - 400 m depth, the influence of repository construction and operation, the expected conditions after repository closure and saturation, and the evolution in a long-term perspective are discussed. Groundwaters that are found at these depths have near-neutral pH and are reducing in character, but the composition can vary from saline to non-saline water. The water chemistry in the near-field will mainly be influenced by the composition of the groundwater and by the large amounts of cementitious material that can be found in the repository. Disturbances caused during construction and operation are not expected to be permanent. Studies of old concrete indicate that leaching of concrete is a slow process. The geochemical conditions in the repository are therefore expected to be stable and prevail for hundreds of thousand years. However, the evolution of the surrounding environment may influence the conditions in long-term perspective

  14. The Nasca and Palpa geoglyphs: geophysical and geochemical data

    Science.gov (United States)

    Hartsch, Kerstin; Weller, Andreas; Rosas, Silvia; Reppchen, Gunter

    2009-10-01

    The Nasca geoglyphs in the stone desert in southern Peru are part of our world cultural heritage. These remarkable drawings have roused the interest of scientists from different disciplines. Here we report the results of integrated geophysical, petrophysical, mineralogical, and geochemical investigations of the geoglyphs at six test sites in the stone desert around Nasca and Palpa. The geomagnetic measurements revealed clear indications of subsurface structures that differ from the visible surface geoglyphs. The high-resolution geoelectrical images show unexpected resistivity anomalies underneath the geoglyphs down to a depth of about 2 m. Remarkable structures were revealed in both vertical and lateral directions. No evidence was found of geochemical or mineralogical alterations of the natural geogenic materials (desert pavement environment versus geoglyphs). Neither salts nor other mineral materials were used by the Nasca people to alter or prepare the surfaces of geoglyphs. This supports the hypothesis that the Nasca people simply removed stone material down to the natural hard pan horizon to create the geoglyphs.

  15. Evolution of geochemical conditions in SFL 3-5

    Energy Technology Data Exchange (ETDEWEB)

    Karlsson, Fred [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden); Lindgren, M.; Skagius, K.; Wiborgh, M. [Kemakta Konsult AB, Stockholm (Sweden); Engkvist, I. [Barsebaeck Kraft AB (Sweden)

    1999-12-01

    The evolution of geochemical conditions in the repository for long-lived low- and intermediate-level waste, SFL 3-5, and in the vicinity of the repository are important when predicting the retention of radionuclides and the long-term stability of engineered barriers. In this study the initial conditions at different repository sites at 300 - 400 m depth, the influence of repository construction and operation, the expected conditions after repository closure and saturation, and the evolution in a long-term perspective are discussed. Groundwaters that are found at these depths have near-neutral pH and are reducing in character, but the composition can vary from saline to non-saline water. The water chemistry in the near-field will mainly be influenced by the composition of the groundwater and by the large amounts of cementitious material that can be found in the repository. Disturbances caused during construction and operation are not expected to be permanent. Studies of old concrete indicate that leaching of concrete is a slow process. The geochemical conditions in the repository are therefore expected to be stable and prevail for hundreds of thousand years. However, the evolution of the surrounding environment may influence the conditions in long-term perspective.

  16. Testing geochemical modeling codes using New Zealand hydrothermal systems

    International Nuclear Information System (INIS)

    Bruton, C.J.; Glassley, W.E.; Bourcier, W.L.

    1993-12-01

    Hydrothermal systems in the Taupo Volcanic Zone, North Island, New Zealand are being used as field-based modeling exercises for the EQ3/6 geochemical modeling code package. Comparisons of the observed state and evolution of selected portions of the hydrothermal systems with predictions of fluid-solid equilibria made using geochemical modeling codes will: (1) ensure that we are providing adequately for all significant processes occurring in natural systems; (2) determine the adequacy of the mathematical descriptions of the processes; (3) check the adequacy and completeness of thermodynamic data as a function of temperature for solids, aqueous species and gases; and (4) determine the sensitivity of model results to the manner in which the problem is conceptualized by the user and then translated into constraints in the code input. Preliminary predictions of mineral assemblages in equilibrium with fluids sampled from wells in the Wairakei geothermal field suggest that affinity-temperature diagrams must be used in conjunction with EQ6 to minimize the effect of uncertainties in thermodynamic and kinetic data on code predictions. The kinetics of silica precipitation in EQ6 will be tested using field data from silica-lined drain channels carrying hot water away from the Wairakei borefield

  17. Northern Pintail Telemetry [ds231

    Data.gov (United States)

    California Department of Resources — Using radio-telemetry, female northern pintail (Anas acuta) survival, distribution, and movements during late August-March in Central California were determined...

  18. A geochemical appraisal of oil generation in the Taranaki Basin, New Zealand

    Energy Technology Data Exchange (ETDEWEB)

    Killops, S.D.; Woolhouse, A.D.; Weston, R.J.; Cook, R.A. (Institute of Geology and Nuclear Science, Lower Hutt (New Zealand). Hydrocarbon Resources and Basin Studies Group)

    1994-10-01

    From a basin-wide evaluation of organic geochemical data, it has been possible to characterize and differentiate various source rock units and to establish the genetic relationships of oils. Most of the oils are primarily terrestrially sourced, and it is possible to recognize varying contributions from source rocks within the Paleogene Kapuni Group and late Cretaceous Pakawau Group. This distinction is attributable to the rise to dominance of angiosperm over gymnosperms in coastal plain swamp communities by the Eocene. Apart from the Maui family oils, the inferred relative contributions from the main source rock types generally correlate with the relative proportions of suitably thick and mature units near reservoirs, given that most Cretaceous-sourced oil appears to have escaped prior to trap development. Maui family oils do appear to be primarily sourced by Rakopi Formation (late Cretaceous) coals. In the northern part of the Taranaki Peninsula, where heat flows are highest, Mangahewa/Kaimiro formation (Eocene) coals are the chief sources of oils. Farther south, in the Kapuni and Kupe south fields, Farewell Formation (Paleocene) coals appear to be the main oil source rocks. Biomarkers suggest that the onset of oil expulsion from coals occurs at a maturity level corresponding to a vitrinite reflectance of ca. 0.8%R[sub 0], and may be aided by the evolution of large volumes of carbon dioxide. The terrestrial influence on Paleogene source rocks diminishes to the north-northwest of the basin and increasing marine contributions to oils are observed. A large Paleocene marine black shale is the source of oil in the Kora volcanic structure. It is possible that shales interbedded with coals, reflecting periodic marine incursions of coastal flood plains, also contribute to oil generation throughout much of the basin.

  19. Geochemical differences between along-arc and across-arc volcanics in west-central Nicaragua

    Science.gov (United States)

    Geilert, Sonja; Freundt, Armin; Wörner, Gerhard; Kutterolf, Steffen

    2012-04-01

    The La Paz Centro - Malpaisillo Lineament (LPML) in west-central Nicaragua is a north-south striking, 20 km long chain of maars and cinder cones, which intersects the northwest-southeast striking main volcanic front. A tectonic control of LPML volcanism is likely but only evident for the Malpaisillo fissure at the northern end of the LPML. Previous work demonstrated geochemical variations implying changes in mantle-source composition (i.e., added slab components) along the Central American Volcanic Arc at spatial scales of some 10's of kilometers. Our study of the LPML shows that minor but systematic changes also occur across the arc within 20 km distance. Variations in trace element ratios such as Zr/Nb, Ba/Th, Ba/La, Th/Zr, U/La and La/Yb along the LPML, i.e. across the volcanic front indicate little change in the degree of partial melting but an increase particularly in the hemipelagic sediment component in the mantle source from the fore arc towards the arc front, followed by a decrease behind the arc. Interestingly, the slab component is most prominent just in front of the arc. About 60 km southeast of the LPML, the Nejapa-Miraflores volcanic and tectonic lineament, which marks a 20 km north-south offset in the arc, differs substantially from the LPML. There is a wide scatter in incompatible trace element ratios indicating a heterogeneous mantle source at small spatial scales (c. 1 km). This mantle heterogeneity may represent vertical rather than across-arc variations and is probably related to the arc offset, because in the absence of such offset at the LPML mantle source conditions vary much less but more systematically.

  20. Classification and Geochemical Characterization of Igneous Rocks: Southern Part of Chihuahua City, Mexico

    Science.gov (United States)

    Fontes, I. D.; Espejel-Garcia, V. V.; Villalobos-Aragon, A.

    2013-05-01

    Chihuahua City is the capital of the state with the same name, located in northern Mexico. The city was established near the Chuviscar River, but in the last decades it has been extended to the nearby areas (mountains), with volcanic (rhyolitic tuffs), and sedimentary rocks (limestone). The study area includes areas in the south part of Chihuahua City, where we can still find unbuilt lands and it is possible to appreciate outcrops of igneous rocks. This project includes 5 study spots, which are located about 9 km. far from the south extreme of the city. This research is developed in order to complement the geological information in this area, as there is no is detailed record of it. In the geological map H13-10 (SGM, 1997), it is said that the urban area is covered by Quaternary conglomerates, while exploring the region we have located several igneous rocks outcrops. In three of the sampling points, dark colored intrusive igneous rocks with large crystals appear in blocks without noticeable fractures. While in the other two sampling points, highly fractured blocks of pink aphanitic igneous rocks, showing traces of pyrolusite were observed. The petrographic study shows the two different textures that classify these rocks as extrusive (aphanitic) or intrusive (phaneritic), both with quartz and feldspars being the dominant minerals. Geochemical analyses confirm the felsic composition of the rocks, varying form trachytes to rhyolites. The trace element results show high contents of Sr, Ba, V, Rb, and Zr in trachytic compositions, while there are high concentrations of Mn, W, Rb and Co for rhyolitic compositions.

  1. Geochemical and Petrological Studies of Peralkaline Rocks from Laborcita de San Javier, Chihuahua, Mexico

    Science.gov (United States)

    Lozano, J. E.; Espejel-Garcia, V. V.; Villalobos-Aragon, A.

    2013-05-01

    Peralkaline igneous rocks are characterized by a lower total aluminum content in comparison to the total alkalis content (Na + K), and are important to determine the tectonic environment in which they formed. The majority of the volcanic activity in Chihuahua State, northern Mexico, is mostly related to the formation of the Sierra Madre Occidental (SMO), product of the subduction of the Farallon plate. Volcanic activity of Paleogene age (late Oligocene) to the SW of Chihuahua city, specifically in the towns of Laborcita de San Javier and Cusihuiriachic, includes 27.5 M.a. peralkaline tuffs, capping the older rhyolites and andesites of the SMO. This sequence becomes thicker and more prominent towards the west. A volcanic section of more than 1,000 m thick is exposed in the Laborcita area, which ranges in age from 27 to 35 Ma. The oldest (bottom) unit is a calc-alkaline felsic ash-flow tuff and rhyolitic lavas interbedded with flows of mafic to intermediate composition. Overlying this unit, there is a basaltic andesite with an age of 30 to 33 Ma. Right at the top of this sequence, there is the widespread peralkaline ash-flow tuff (27.5 M.a.), focus of this study. Geochemical analyses performed to rhyolitic tuffs by Mauger and Dayvault (1983), have a peralkalinity index ranging from 0.94 to 1.20, while analyses prepared for this project only reach an index of 0.60. The appearance of peralkaline rocks in the Chihuahua State indicates the change of tectonic regime from compression (Farallon plate subduction) to distension (Basin and Range and/or Rio Grande Rift), about 27 M.a. ago.

  2. Combined geophysical, geochemical and geological investigations of geothermal reservoir characteristics in Lower Saxony, Germany

    Science.gov (United States)

    Hahne, B.; Thomas, R.

    2012-04-01

    The North German basin provides a significant geothermal potential, although temperature gradients are moderate. However, deep drilling up to several thousand meters is required to reach temperatures high enough for efficient generation of geothermal heat and electric power. In these depths we have not much information yet about relevant physical properties like porosity or permeability of the rock formations. Therefore the costs of developing a geothermal reservoir and the risk of missing the optimum drilling location are high. The collaborative research association "Geothermal Energy and High Performance Drilling" (gebo) unites several universities and research institutes in Lower Saxony, Germany. It aims at a significant increase of economic efficiency by introducing innovative technology and high tech materials resisting temperatures up to 200 °C in the drilling process. Furthermore, a better understanding of the geothermal reservoir is essential. gebo is structured into four main fields: Drilling Technology, Materials, Technical Systems and Geosystem. Here, we show the combined work of the Geosystem group, which focuses on the exploration of geological fault zones as a potential geothermal reservoir as well as on modeling the stress field, heat transport, coupled thermo-hydro-mechanical processes, geochemical interactions and prediction of the long-term behavior of the reservoir. First results include combined seismic and geoelectric images of the Leinetalgraben fault system, a comparison of seismic images from P- and S-wave measurements, mechanical properties of North German rocks from field and laboratory measurements as well as from drill cores, seismological characterization of stimulated reservoirs, a thermodynamic "gebo" database for modeling hydrogeochemical processes in North German formation waters with high salinity and at high temperatures, stress models for specific sites in northern Germany, and modeling results of permeability and heat transport

  3. Application of radon time series data for seismo - geochemical studies along different fault zones of Taiwan

    International Nuclear Information System (INIS)

    Walia, Vivek; Arvind Kumar; Lin, Shih-Jung; Liao, Yu-Tzu; Wen, Kuo-Liang; Yang, Tsanyao Frank; Fu, Ching-Chou; Chen, Cheng-Hong

    2015-01-01

    The Island of Taiwan is a product of the collision between Philippine Sea plate and Eurasian plate which makes it a region of high seismicity. In the southern part of the island the Eurasian plate is subducting under the Philippine Sea plate while in the northern area of the island the Philippine Sea plate bounded by the Ryukyu trench is subducting beneath the Eurasian plate. Behind the Ryukyu trench, the spreading Okinawa trough has developed. The northern part of Taiwan Island is located at the western extrapolation of the Okinawa trough. Over the last few years, we focused on the temporal variations of soil-gas composition at established geochemical observatories along the Hsincheng fault in the Hsinchu area, Hsinhua fault in the Tainan areas, and at Jaosi in the Ilan areas of Taiwan. As per the present practice, the data from various stations are examined synoptically to evaluate earthquake precursory signals against the backdrop of rainfall and other environmental factors. For the earthquake prediction the efficiency of an operation system depends not only upon its logical correctness, but also upon the response time. The database has been developed by the established network of continuous soil-gas monitoring stations along different faults covering NW, SW and eastern Taiwan. The data processing includes a low-pass filter to reduce the noise level. It filters out the high frequency noise and daily variation caused by different parameters like measurement uncertainty, background noise, environmental parameters and earth tides. The rolling average and normalization were used to quantify the probability distribution of variation in the data. In recent years manually operating real-time database had been developed and efforts were made to improve data processing system for earthquake precursory studies by changing the operating system from manual to automatic. We tried to replace the business package software 'Visual Signal' to an open source programming

  4. Jurassic-Paleogene intra-oceanic magmatic evolution of the Ankara Mélange, North-Central Anatolia, Turkey

    Science.gov (United States)

    Sarifakioglu, E.; Dilek, Y.; Sevin, M.

    2013-11-01

    subalkaline to alkaline geochemical affinities represent intraoceanic magmatism that developed on and across the subduction-accretion complex above a N-dipping, southward-rolling subducted lithospheric slab within the Northern Neotethys. The Ankara Mélange thus exhibits the record of ~120-130 million years of oceanic magmatism in geological history of the Northern Neotethys.

  5. Geochemical and Isotopic Interpretations of Groundwater Flow in the Oasis Valley Flow System, Southern Nevada

    Energy Technology Data Exchange (ETDEWEB)

    J.M. Thomas; F.C. Benedict, Jr.; T.P. Rose; R.L. Hershey; J.B. Paces; Z.E. Peterman; I.M. Farnham; K.H. Johannesson; A.K. Singh; K.J. Stetzenbach; G.B. Hudson; J.M. Kenneally; G.F. Eaton; D.K. Smith

    2003-01-08

    This report summarizes the findings of a geochemical investigation of the Pahute Mesa-Oasis Valley groundwater flow system in southwestern Nevada. It is intended to provide geochemical data and interpretations in support of flow and contaminant transport modeling for the Western and Central Pahute Mesa Corrective Action Units.

  6. Geochemical Distribution of Lead and Chromium in River Getsi-Kano

    African Journals Online (AJOL)

    Geochemical forms of lead (Pb) and Chromium (Cr) from the sediment of River Getsi Kano-Nigeria were determined using Atomic Absorption spectrometer for eighteen months. Apart from determination of the metals in water, geochemical forms of the metals were also evaluated into five fractions. Exchangeable, bound to ...

  7. Geochemical and Isotopic Interpretations of Groundwater Flow in the Oasis Valley Flow System, Southern Nevada

    International Nuclear Information System (INIS)

    Thomas, J.M.; Benedict, F.C. Jr.; Rose, T.P.; Hershey, R.L.; Paces, J.B.; Peterman, Z.E.; Farnham, I.M.; Johannesson, K.H.; Singh, A.K.; Stetzenbach, K.J.; Hudson, G.B.; Kenneally, J.M.; Eaton, G.F.; Smith, D.K.

    2003-01-01

    This report summarizes the findings of a geochemical investigation of the Pahute Mesa-Oasis Valley groundwater flow system in southwestern Nevada. It is intended to provide geochemical data and interpretations in support of flow and contaminant transport modeling for the Western and Central Pahute Mesa Corrective Action Units

  8. Geochemical evaluation of CO2 injection and containment in a depleted gas field

    NARCIS (Netherlands)

    Tambach, T.J.; Koenen, M.; Wasch, L.J.; Bergen, F. van

    2015-01-01

    The short- and long-term geochemical impact of CO2 injection into a depleted gas reservoir (DGR) is investigated using reservoir/geochemical modeling with TOUGH2/TOUGHREACT and 1D kinetic diffusion modeling with PHREEQC (caprock/well-cement). Simulations of CO2 injection into the reservoir predict

  9. Development of geophysical and geochemical data processing software based on component GIS

    International Nuclear Information System (INIS)

    Ke Dan; Yu Xiang; Wu Qubo; Han Shaoyang; Li Xi

    2013-01-01

    Based on component GIS and mixed programming techniques, a software which combines the basic GIS functions, conventional and unconventional data process methods for the regional geophysical and geochemical data together, is designed and developed. The software has many advantages, such as friendly interface, easy to use and utility functions and provides a useful platform for regional geophysical and geochemical data processing. (authors)

  10. Geochemical and mineralogical fingerprints of the sediments supply and early diagenetic processes in the Bizerte Lagoon (Tunisia

    Directory of Open Access Journals (Sweden)

    Noureddine Zaaboub

    2016-10-01

    Full Text Available The Bizerte Lagoon (Tunisia functions as a sedimentation environment characterized by receiving allochthonous sediments mainly transported by the Ben Hassine, Rharek and Guenich streams, as well as marine sediments from the Mediterranean Sea. It is subjected to significant environmental changes due to the natural and anthropic influences altering the natural patterns of circulation, extraction and/or deposition of mineralogical materials. The aim of this investigation is to analyze the sediments supply and early diagenetic processes in Bizerte Lagoon. The physicochemical parameter of the sediment pore water, as well as their texture, mineralogical composition (X-Ray diffraction technique - XRD, magnetic susceptibility and their geochemical composition (namely lithogenic and biogenic chemical elements analyzed by ICP-MS were analyzed in 10 sampling stations. The water temperature with an average of 15.2°C was stable in the study area. The sediments were generally characterized by fine granulometry, mainly mud and sandy mud, poorly to very poorly sorted, and constituted by two or more granulometric particle modes. The mineralogical results revealed the presence of phyllosilicates, quartz, pyrite, calcite, anatase and K-feldspar, and other minerals in smaller proportions. The fine sediment and high phyllosilicates and Al contents indicate the presence of weak currents in most part of the studied area. The results of sorting, skewness and kurtosis suggest that the currents are more active in the northern region of the lagoon, near the channel of communication with the Mediterranean Sea. They also evidence a coarser particle contribution of the Ben Hassine stream to the lagoon. The other streams seem to introduce mostly fine-grained sediments in the lagoon. The currents circulation, the water residence time and the biological productivity influence the mineralogical and geochemical characteristics of the bottom sediments. The industrial activity is

  11. Geochemical modelling of groundwater chemistry in the Tono area

    International Nuclear Information System (INIS)

    Arthur, R.C.

    2003-03-01

    This report summarizes the research result about geochemical modelling of the groundwater during H14 financial year. JNC-TGC have built the geochemical conceptual models of groundwater by using the chemical data of the groundwater of the Mizunami group and Toki granite. Although this models are extremely useful as interpretive tools, they lack the quantitative basis necessary to evaluate coupled processes of fluid-flow and water-rock interaction driving the chemical evolution of groundwater systems. In this research, the following three items have been considered for the purpose of construction of the geochemical model which can express the chemical reaction in groundwater correctly. Evaluation of the quality of the previous analytical data in the Tono region. Grasp of the chemical character of groundwaters. Consideration about the influence between Eh, pH and CO 2 (g) parameter, and which the change has. Evaluation of the quality of the previous analytical data are important because deficiencies in sampling technique, sample-preservation procedures or analytical method may adversely affect the overall quality of groundwater chemical and isotopic analysis. In addition, the effects of borehole drilling and logging, hydraulic testing inappropriate sampling strategies or inadequate sampling tools may perturb groundwater compositions to such an extent that they are unrepresentative of in-situ conditions. The quality of water analysis is indicated by its charge balance. The charge balance of many of the analysis lies within the strictly acceptable range of 0±5%, but charge imbalances exceeding these limits are calculated for many other samples. These reasons are examined in the following. Analytical errors (e.q., of alkalinity). Errors arising from the use of IC values that are unrepresentative because CO 2 was gained by or lost from the sample during storage and (or) analysis. Errors arising from the invalid assumption that non-carbonate contributions to the

  12. Groundwater sources and geochemical processes in a crystalline fault aquifer

    Science.gov (United States)

    Roques, Clément; Aquilina, Luc; Bour, Olivier; Maréchal, Jean-Christophe; Dewandel, Benoît; Pauwels, Hélène; Labasque, Thierry; Vergnaud-Ayraud, Virginie; Hochreutener, Rebecca

    2014-11-01

    The origin of water flowing in faults and fractures at great depth is poorly known in crystalline media. This paper describes a field study designed to characterize the geochemical compartmentalization of a deep aquifer system constituted by a graben structure where a permeable fault zone was identified. Analyses of the major chemical elements, trace elements, dissolved gases and stable water isotopes reveal the origin of dissolved components for each permeable domain and provide information on various water sources involved during different seasonal regimes. The geochemical response induced by performing a pumping test in the fault-zone is examined, in order to quantify mixing processes and contribution of different permeable domains to the flow. Reactive processes enhanced by the pumped fluxes are also identified and discussed. The fault zone presents different geochemical responses related to changes in hydraulic regime. They are interpreted as different water sources related to various permeable structures within the aquifer. During the low water regime, results suggest mixing of recent water with a clear contribution of older water of inter-glacial origin (recharge temperature around 7 °C), suggesting the involvement of water trapped in a local low-permeability matrix domain or the contribution of large scale circulation loops. During the high water level period, due to inversion of the hydraulic gradient between the major permeable fault zone and its surrounding domains, modern water predominantly flows down to the deep bedrock and ensures recharge at a local scale within the graben. Pumping in a permeable fault zone induces hydraulic connections with storage-reservoirs. The overlaid regolith domain ensures part of the flow rate for long term pumping (around 20% in the present case). During late-time pumping, orthogonal fluxes coming from the fractured domains surrounding the major fault zone are dominant. Storage in the connected fracture network within the

  13. Structural Style and Lead Identification, Northern Depobelt, Niger Delta, Nigeria

    International Nuclear Information System (INIS)

    Ola, P. S.; Adekoya, J. A.

    2003-01-01

    By interpreting biofacies data, wire line log and grid of 2D seismic sections in an integrated manner in some portions of the northern depobelt, Niger delta, the sequence stratigraphic framework of the area was established. This enabled the structural style and genetic sequences of the area to be inferred. Results showed that the depobelt could be I subdivided into minibasins that trend in a NW SE direction and are bounded by synthetic faults in the proximal end and shale diapers in the distal end. All the exploration wells in the area of study, which were drilled on structural highs and were very close to the synthetic faults, turned out to be dry whereas the synclinal lows that resulted from local deposition of sands of the first genetic sequences in each of the minibasins could contain hydrocarbon. Such areas of synclinal lows are hereby proposed, as lead in this study. The intervals are untested and occur faraway from existing wells. By projection the geochemical data of well Oben-1 in the area suggest that the intervals fall within the oil generative window. Characteristic seismic reflection termination patterns, which are predominantly down laps and on laps suggest existence of structural closure for hydrocarbon accumulation within the synclinal lows. This study therefore recommends a reappraisal of these leads using a more focused 3D seismic study. The northern delta depobelt is less risky and inexpensive for oil exploration and exploitation compared with the offshore Niger delta that is gaining more prominence

  14. Virginia Tech To Showcase Northern Virginia Research

    OpenAIRE

    Cunningham, Deborah

    2003-01-01

    Virginia Tech graduate students and faculty members in Northern Virginia will display and explain their most current research at the first Virginia Tech at Northern Virginia Research Exposition April 17 at the Northern Virginia Center in Fairfax.

  15. The hydrogeologic-geochemical model of Cerro Prieto revisited

    Energy Technology Data Exchange (ETDEWEB)

    Lippmann, M.J.; Halfman, S.E.; Truesdell, A.H.; Manon M., A.

    1989-01-01

    As the exploitation of the Cerro Prieto, Mexico, geothermal field continues, there is increasing evidence that the hydrogeologic model developed by Halfman et al. (1984, 1986) presents the basic features controlling the movement of geothermal fluids in the system. At the present time the total installed capacity at Cerro Prieto is 620 MWe requiring the production of more than 10,500 tonnes/hr of a brine-steam mixture. This significant rate of fluid production has resulted in changes in reservoir thermodynamic conditions and in the chemistry of the produced fluids. After reviewing the hydrogeologic-geochemical model of Cerro Prieto, some of the changes observed in the field due to its exploitation are discussed and interpreted on the basis of the model. 21 refs., 11 figs., 1 tab.

  16. Geochemical exploration for phosphate in the State of Acre

    International Nuclear Information System (INIS)

    Costa, M.L. da; Melo Costa, W.A. de; Santos, A.J.M. dos

    1989-01-01

    The geochemical prospecting conducted for phosphates in Acre which could explain the good fertility of the region was charged to discover this material. The phosphates are strictly built of all the bone structures and coprolites of the several fragments of vertebrate fossils, which are widespread in the region. The phosphatic fossils are bedded in the Solimoes Formation, especially its basal to intermediary conglomeratic bed. The fossils are constituted of low crystallinity apatite, and their matrix sediments include quartz, feldspars, smectite, halloysite and calcite. The P 2 O 5 content reaches up to 5% in the sediments and up to 32% in the fragments. The fossils are enriched in U 3 O 8 and rare earth elements. There is no perspect of classic or mineral deposits but the geological knowlwdge will permit the improvement of the use of the soils in Acre. (author) [pt

  17. Geochemical characterisation of Elbe river high flood sediments

    Energy Technology Data Exchange (ETDEWEB)

    Krueger, F. [UFZ - Umweltforschungszentrum Leipzig-Halle GmbH, Falkenberg (Germany). Sektion Boden-/Gewaesserforschung]|[UFZ - Umweltforschungszentrum Leipzig-Halle GmbH, Magdeburg (Germany). Sektion Gewaesserforschung; Rupp, H.; Meissner, R. [UFZ - Umweltforschungszentrum Leipzig-Halle GmbH, Falkenberg (Germany). Sektion Boden-/Gewaesserforschung; Lohse, M.; Buettner, O.; Friese, K. [UFZ - Umweltforschungszentrum Leipzig-Halle GmbH, Magdeburg (Germany). Sektion Gewaesserforschung; Miehlich, G. [Hamburg Univ. (Germany). Inst. fuer Bodenkunde

    2001-07-01

    Quality aims for land usage in flood plains have to be worked out in the Russian-German research project 'Effects of floods on the pollution of agricultural used flood plain soils of the Oka River and the Elbe River'. It is financed by the Germany Ministry of Education and Research (FKZ 02 WT 9617/0). Beside the characterisation of the present pollution of soils for the middle Elbe, it is necessary to prognosticate the current pollutant input. At the examination site nearby Wittenberge, Elbe River kilometers 435 and 440, natural deposited flood sediments were sampled by artificial lawn mats. By the geochemical characterisation it is possible to record the metal input into the flood plain and to win knowledge about the sedimentation process. The results of sediment investigation of the high flood in spring 1997 are presented. (orig.)

  18. Nuclear probes in physical and geochemical studies of natural diamonds

    International Nuclear Information System (INIS)

    Sellschop, J.P.F.

    In this review the emphasis is directed to the use of nuclear particles for the analysis of impurities in diamond from an interest in both the observed physical properties and genesis of diamond and the inter-relation between these two aspects. However (nuclear) radiation can be used more specifically: from the inter-relation of elemental impurities chemical and geochemical information can be deduced, from energy variation depth distributions of selected impurities can be determined, the prospect of lattice location of impurities exists from the use of extremely finely collimated beams of nuclear particles, which are used also for probing the inter-atomic fields, and finally all nuclear probes excite luminescence in diamonds

  19. Hydrogeological and geochemical studies in the Perch Lake basin

    International Nuclear Information System (INIS)

    Barry, P.J.

    1979-08-01

    The Perch Lake basin is a small drainage system along the Ottawa River about 200 km west of Ottawa on the Canadian Shield. Since 1975, groups of scientists from several Canadian universities and government departments have been studying the hydrological, geological and geochemical properties of the basin. The object of these studies is to develop and test simulation models used to describe the time-dependent mass flow rates of water and dissolved and suspended substances through the basin. To review progress, a symposium/workshop was held at Chalk Rier in 1978 April. This report contains 24 extended summaries of the material presented verbally at the workshop. Subject matters include atmospheric sources and sinks, mass flows through the surface and subsurface regimes in the drainage basins and interactions occurring in the lake. (author)

  20. Geochemical isotope compartment model of the nitrogen cycle

    International Nuclear Information System (INIS)

    Weise, G.; Wetzel, K.; Stiehl, G.

    1981-01-01

    A model of the global cycle of nitrogen and its isotopes is described. It takes into account geochemical reservoirs (nitrogen in magmatic metamorphic, and sedimentary rocks and in the atmosphere) and the nitrogen exchange between magmatic rocks and the outer mantle, the transition of nitrogen exchange between sedimentary rocks and the atmosphere. With the aid of the mathematical formalisms of the compartment theory and on the basis of all available delta 11 N values assumptions regarding the isotope effects in forming these nitrogen fluxes data have been obtained on the degree of the nitrogen exchange between the earth crust and the outer mantle and on other nitrogen fluxes characterizing the global nitrogen cycle. (author)

  1. Radiochemical neutron activation analysis of gold in geochemical samples

    International Nuclear Information System (INIS)

    Zilliacus, R.

    1983-01-01

    A fast method for the radiochemical neutron activation analysis of gold in geochemical samples is described. The method is intended for samples having background concentrations of gold. The method is based on the dissolution of samples with hydrofluoric acid and aqua regia followed by the dissolution of the fluorides with boric acid and hydrochloric acid. Gold is then adsorbed on activated carbon by filtrating the solution through a thin carbon layer. The activity measurements are carried out using a Ge(Li)-detector and a multichannel analyzer. The chemical yields of the separation determined by reirradiation vary between 60 and 90%. The detection limit of the method is 0.2 ng/g gold in rock samples. USGS standard rocks and exploration reference materials are analyzed and the results are presented and compared with literature data. (author)

  2. The Earth's heterogeneous mantle a geophysical, geodynamical, and geochemical perspective

    CERN Document Server

    Khan, Amir

    2015-01-01

    This book highlights and discusses recent developments that have contributed to an improved understanding of observed mantle heterogeneities and their relation to the thermo-chemical state of Earth's mantle, which ultimately holds the key to unlocking the secrets of the evolution of our planet. This series of topical reviews and original contributions address 4 themes. Theme 1 covers topics in geophysics, including global and regional seismic tomography, electrical conductivity and seismic imaging of mantle discontinuities and heterogeneities in the upper mantle, transition zone and lower mantle. Theme 2 addresses geochemical views of the mantle including lithospheric evolution from analysis of mantle xenoliths, composition of the deep Earth and the effect of water on subduction-zone processes. Theme 3 discusses geodynamical perspectives on the global thermo-chemical structure of the deep mantle. Theme 4 covers application of mineral physics data and phase equilibrium computations to infer the regional-scale ...

  3. Petrological and geochemical characteristics of Shuixigou group in Yili basin

    International Nuclear Information System (INIS)

    Wang Jinping; Min Maozhong

    2003-01-01

    The Shuixigou Group, Lower-Middle Jurassic is the uranium-hosting formation of in-situ leachable sandstone-type uranium deposits in Yili basin. Rocks of the Shuixigou Group were extensively corroded during the diagenesis by the CO 2 -and organic acid-rich water derived from the organic matter existing in the strata. As a result, sandstones became loose and porous. Data of geochemical background such as uranium, organic carbon and major element contents in this paper are the achievement of authors. The results indicate that the distribution of uranium, organic matter and major elements is closely associated with the formation of epigenetic interlayer oxidation zone sandstone-type uranium deposits, and with the discrimination of ore-hosting and barren interlayer oxidation zones

  4. The 'glass earth' - geochemical frontiers in exploration through cover

    International Nuclear Information System (INIS)

    Carr, G.; Denton, G.; Giblin, A.; Korsch, M.; Andrew, A.; Whitford, D.

    1999-01-01

    'Glass Earth' represents a number of current and planned projects within CSIRO aimed at making 'transparent' the top 1000 m of the Earth's crust It builds upon current technologies developed within a number of CSIRO divisions as well as the Australian Mineral Exploration Technologies CRC (AMET CRC), the Australian Geodynamics CRC (AG CRC) and the CRC for Landscape Evolution and Mineral Exploration (CRC LEME). New geophysical and geochemical technologies will be developed to complement these, together with new capabilities in modelling, data integration and visualisation, including hydrogeochemistry, hydrogeology, surface geochemistry and isotope geochemistry, modelling of chemical, fluid and heat flows in rock and regolith, advanced visualisation and data fusion. This paper describes some recent work in the field of isotope geochemistry, with the principal aim of 'seeing through' cover to understand basement geology and detect hidden ore systems

  5. A Low-Li Geochemical Province in the NE Atlantic

    DEFF Research Database (Denmark)

    Bailey, J. C.; Gwozdz, R.

    1978-01-01

    Lithium was analysed in 392 basalts and related igneous rocks from the North Atlantic Tertiary-Recent province using activation analysis and Čerenkov counting. Monotonous Li values of 5.5±2 ppm in NE Atlantic basalts define a low-Li geochemical province which has persisted for 60 million years......, over 20° of latitude and regardless of basalt type and chemistry. This low-Li province and the increasing Li contents of ocean-ridge tholeiites into the S Atlantic are believed to monitor Li heterogeneity in the underlying mantle. Li, like Na, increases gently during the differentiation of several...... basalt series. No whole-rock coherence is observed between Li and Mg, K, Rb or Ca. Mantle phlogopite is considered to play an insignificant rôle in controlling the Li levels of NE Atlantic basalts....

  6. Mineralogical and geochemical tracers of terrigenous supply in the Gulf of Mexico: new insights on ocean-atmosphere-continent interactions

    Science.gov (United States)

    Bout-Roumazeilles, V.; Montero Serrano, J.; Sionneau, T.; Meunier, G.; Bory, A. J.; Tribovillard, N.

    2011-12-01

    The mineralogical and geochemical signatures of sediments deposited in the Gulf of Mexico (GOM) are valuable proxies to retrace the provenance of terrigenous particles transported by the Mississippi River during the last climatic cycle (Sionneau et al., 2008). The Mississippi River flow is mainly controlled by precipitations intensity and distribution during interglacial periods whereas meltwater discharges are the most prominent processes during the deglaciation. Using this approach on a series of sediment cores from the northern GOM, our research group recently gave some new insights on the connection between high-latitude climate and the subtropical hydrology and on atmosphere-ocean-continent transfers: - The clay mineral composition of sediments deposited in the GOM allows constraining the spatial evolution of the Laurentide ice sheet (LIS) southern margin during the major meltwater discharges of the last deglaciation, pinpointing the continental domains successively submitted to erosion during the ice-sheet retreat (Sionneau et al., 2010; Montero et al., 2009); - A high-resolution analysis of the most prominent meltwater discharge provides a detailed chronology of the multi-phased discharge with an initial flooding preceding the main erosional pulse and the final decantation phase (Montero et al., 2009); - The impact of a main freshwater supply on the GOM hydrology was investigated using the peculiar mineralogical signature of the main meltwater event (14.6-14 ka cal BP). The spatial propagation of the detrital flow associated with this event was constrained in the northern GOM. This result, together with the deposit sedimentological characteristics, allows estimating the terrigenous flux and checking its consistency with previously published hypotheses (Bout-Roumazeilles et al., submitted); - Recurrent modifications of the clay mineral fraction during the late Holocene allow assessing some major changes in precipitation regimes over North America resulting

  7. Geochemical processes during managed aquifer recharge with desalinated seawater

    Science.gov (United States)

    Ganot, Y.; Holtzman, R.; Weisbrod, N.; Russak, A.; Katz, Y.; Kurtzman, D.

    2017-12-01

    In this work we study the geochemical processes along the variably-saturated zone during managed aquifer recharge (MAR) with reverse-osmosis desalinated seawater (DSW) to an infiltration pond at the Menashe site, located above the Israeli coastal aquifer. The DSW is post-treated by calcite dissolution (remineralization) in order to meet the Israeli desalinated water quality criteria. Suction cups and monitoring wells inside the pond were used to monitor water quality during two MAR events on 2015 and 2016. Results show that cation exchange is dominant, driven by the high Ca2+ concentration in the post-treated DSW. Stable isotope analysis shows that the composition of the shallow groundwater is similar to the recharged DSW, but with enrichment of Mg2+, Na+, Ca2+ and HCO3-. A calibrated variably-saturated reactive transport model was used to predict the geochemical evolution during 50 years of MAR with two water quality scenarios: post-treated DSW and soft DSW (without post-treatment). The latter scenario was aimed to test soil-aquifer-treatment as an alternative post-treatment technique. In terms of water quality, the results of the two scenarios were found within the range of the desalinated water criteria. Mg2+ enrichment was stable ( 2.5 mg L-1), higher than the zero concentration found in the Israeli DSW. Calcite content reduction was low (<1%) along the variably-saturated profile, after 50 years of MAR. This suggests that using soil-aquifer-treatment as a remineralization technique for DSW is potentially a sustainable practice, which is limited only by the current hydraulic capacity of the Menashe MAR site.

  8. Geochemical Constraints on Archaeal Diversity in the Vulcano Hydrothermal System

    Science.gov (United States)

    Rogers, K. L.; Amend, J. P.

    2006-12-01

    The shallow marine hydrothermal system of Vulcano, Italy hosts a wide diversity of cultured thermophilic Archaea, including Palaeococcus helgesonii, Archaeoglobus fulgidus, and Pyrococcus furiosus, to name a few. However, recent studies have revealed a plethora of uncultured archaeal lineages in the Vulcano system. For example, a 16S rRNA gene survey of an onshore geothermal well identified a diverse archaeal community including deeply-branching uncultured Crenarchaeota, Korarchaeota, and Euryarchaeota. Additionally, culture-independent hybridization techniques suggested that Archaea account for nearly half of the microbial community in the Vulcano system. Furthermore, geochemical characterization of fluids revealed numerous lithotrophic and heterotrophic exergonic reactions that could support as yet uncultured organisms. Archaeal diversity throughout the Vulcano hydrothermal system was investigated using 16S rRNA gene surveys at five submarine vents and an onshore sediment seep. Overall, archaeal diversity was higher (10 groups) at submarine vents with moderate temperatures (59°C) compared with higher temperature (94°C) vents (4 groups). Archaeal communities at the moderately thermal vents were dominated by Thermococcales and also contained Archaeoglobales, Thermoproteales, and uncultured archaea among the Korarchaeota, Marine Group I, and the Deep-sea Hydrothermal Vent Euryarchaeota (DHVE). Fluid composition also affects the microbial community structure. At two high-temperature sites variations in archaeal diversity can be attributed to differences in iron and hydrogen concentrations, and pH. Comparing sites with similar temperature and pH conditions suggests that the presence of Desulfurococcales is limited to sites at which metabolic energy yields exceed 10 kJ per mole of electrons transferred. The Vulcano hydrothermal system hosts diverse archaeal communities, containing both cultured and uncultured species, whose distribution appears to be constrained by

  9. Gas quality and geochemical studies in gas-stimulation experiments

    International Nuclear Information System (INIS)

    Taylor, R.W.

    1976-01-01

    Gas produced following the Gasbuggy and Rulison gas-stimulation nuclear explosions had a different composition than the natural gas produced in the same areas before nuclear stimulation. The principal difference was the presence of substantial amounts of CO 2 , CO, H 2 , and H 2 O in the post-explosion gas. There also were changes in ratios of hydrocarbons. Because CO 2 reduces the heating value of the gas, and steam presents a troublesome disposal problem due to the trace of tritium it carries, an understanding of the geochemical effects produced by these types of nuclear explosions is needed. Samples of gas-bearing shales were heated under a variety of conditions evolving CO 2 at temperatures as low as 500 0 C, even under a CO 2 pressure of 50 atm, due to reactions between fine-grained carbonates and silicates. In other experimental studies evidence was obtained that regions of high temperature (approximately 400 0 C), rather than radiation, caused the changes in gas composition observed in the Gasbuggy chimney during the 6-mo ''shut-in'' period. In looking ahead to the geochemical effects that occur when multiple explosions are used to form interconnecting chimneys, it is concluded that less CO 2 will be produced per unit yield than for a single explosion in the same rock. This is because the intensely heated rock is cooled rapidly by convecting gas before it can heat the adjacent rubble, which results in less rubble being heated hot enough to release CO 2 . Steam production, however, will be greater in the case of multiple explosions than for single explosions because a higher fraction of the total yield is deposited as heat in the chimney, thus increasing the average chimney temperature. The average chimney temperature, and thus the steam pressure, increases as the distance between multiple explosions is decreased. The steam pressure will also increase as the depth of nuclear explosions is increased

  10. Arsenic: geochemical distribution and health risk in Italy

    Science.gov (United States)

    Zuzolo, Daniela; Cicchella, Domenico; Albanese, Stefano; Catani, Vittorio; Dinelli, Enrico; Lima, Annamaria; Valera, Paolo; De Vivo, Benedetto

    2017-04-01

    Characterization of risks to human health is determinant for risk management and population surveillance. This study represent the first work at national scale for Italy about arsenic occurrence, distribution and health impact. We analyzed the As geochemical distribution in different environmental matrices on the whole Italian territory, and assessed both carcinogenic and non-carcinogenic risks for different exposure routes and age groups. The results demonstrate that, in Italy, arsenic is present in significant concentrations both in water (up to 27.2 µg/L) and soils (up to 70 mg/kg). Its presence is mainly controlled by geological processes and locally reflects the industrial history of the Country. The population of the Central Italy, where high content of arsenic in the analyzed samples is due to the presence of alkaline volcanics, are the most exposed to the health risk. Based on the results of our work, it is clear that the consumption of tap water for potable use is the most impactful route for As daily exposure and play an important role in governing potential cancer and non-cancer risks for the considered population. It is interesting to observe that the Incremental Life Cancer Risk through water ingestion show that almost 80% of data falls above the internationally accepted benchmark value of 1 x 10-5. Moreover it was demonstrated that childhood is the most susceptible age stage to As exposure. Geochemical mapping provided a useful tool to spatially analyze and represent data and to highlight the most critic areas and the most exposed population to arsenic at national scale. In conclusion, this study improve knowledge about As occurrence for an entire Country, recognizing an health emerging problem. It might be a good starting point to support the urgently needed policy actions, in order to prevent and reduce the health risk. Moreover, the performed method in this case study research is potentially generalizable and applicable in other countries.

  11. Petrographic and geochemical characteristics of the Cypress Creek salt core

    International Nuclear Information System (INIS)

    1983-07-01

    Law Engineering Testing Company supervised the drilling of a corehole into the stock of Cypress Creek Dome, located in Perry County, Mississippi. A total of 170 ft of caprock and 501 ft of salt stock was recovered for physical examination and chemical analysis. This report describes the types of analyses performed and summarizes the data developed. The entire caprock and salt core were described and photographed prior to selection of samples for petrologic and geochemical analysis. Transmitted light techniques were used to determine gross structural and compositional variations in the core. The core lithologies are presented graphically, at a scale of 1 in. to 2 ft. In addition to the detailed field descriptions and photographs, petrologic studies performed on selected caprock and salt samples included: thin-section examination, scanning-electron microscope studies, energy-dispersion analysis, and x-ray-diffraction analysis. Geochemical analyses were performed to determine the average elemental composition of the salt core and amounts of methane and carbon dioxide gases contained within the salt grains. Except for two thin (3 and 6 ft thick) gypsum zones in the top 27 ft of the caprock, the core is predominantly anhydrite (generally 80%). Minor amounts of dolomite and calcite are also present. The salt core consists predominantly of crystalline halite, fine- to medium-grained (0.25 to 1 in.) with few megacrysts. Anhydrite occurs in the salt core as disseminated grains, ranging in length from <0.1 in. to 12 in. Discrete zones exist within the salt core, distinguished from one another primarily by the character of the anhydrite inclusions

  12. Integrated Geochemical-Petrographic Insights on Neoproterozoic Ocean Oxygenation

    Science.gov (United States)

    Hood, A.; Planavsky, N.; Wallace, M. W.; Wang, X.; Gueguen, B.

    2015-12-01

    Novel isotope systems have the potential to provide new insights into biogeochemical cycling in Earth's evolving oceans. However, much recent paleo-redox work has been done without extensive consideration of sample preservation or paleoenvironmental setting. Neoproterozoic reef complexes from South Australia provide a perfect setting to test geochemical redox proxies (e.g. uranium isotopes and trace metal chemistry) within a well-defined sedimentological and petrographic context. These reefs developed significant frameworks over ~1km of steep platform relief from the seafloor, and contain a variety of carbonate components including primary dolomite marine cements. Analysis of a variety of components within these reefs reveals significant variation in uranium isotope composition and trace metal chemistry between components, even within a single sample. Marine cements, which precipitated directly from seawater, have much lower contamination element concentrations (e.g. Al, Zr, Th) than depositional micrites, and appear to represent the best archive of ancient ocean conditions. These cements have high levels of Fe, Mn in shallow and deep reef facies (e.g. 2-3wt% Fe), but only Fe-oxide inclusions in peritidal settings. This distribution suggests ferruginous conditions under a surficial chemocline in this Neoproterozoic seawater. Uranium isotopes from pristine marine cements have relatively heavy values compared to modern seawater (median = -0.22 δ238U). These values are essentially unfractionated from riverine inputs, which we interpret as tracking extensive near quantitative low-T reduction of U(VI) to U(IV) by abundant soluble iron in seawater. Depositional components and late stage cements have a much lighter and more variable U isotope compositions (-0.71 to -0.08 δ238U). This work highlights the need for fundamental petrographic constraints on the preservation of depositional geochemical signatures in the future use and development of sedimentary redox proxies.

  13. Baseline and premining geochemical characterization of mined sites

    Science.gov (United States)

    Nordstrom, D. Kirk

    2015-01-01

    A rational goal for environmental restoration of new, active, or inactive mine sites would be ‘natural background’ or the environmental conditions that existed before any mining activities or other related anthropogenic activities. In a strictly technical sense, there is no such thing as natural background (or entirely non-anthropogenic) existing today because there is no part of the planet earth that has not had at least some chemical disturbance from anthropogenic activities. Hence, the terms ‘baseline’ and ‘pre-mining’ are preferred to describe these conditions. Baseline conditions are those that existed at the time of the characterization which could be pre-mining, during mining, or post-mining. Protocols for geochemically characterizing pre-mining conditions are not well-documented for sites already mined but there are two approaches that seem most direct and least ambiguous. One is characterization of analog sites along with judicious application of geochemical modeling. The other is reactive-transport modeling (based on careful synoptic sampling with tracer-injection) and subtracting inputs from known mining and mineral processing. Several examples of acidic drainage are described from around the world documenting the range of water compositions produced from pyrite oxidation in the absence of mining. These analog sites provide insight to the processes forming mineralized waters in areas untouched by mining. Natural analog water-chemistry data is compared with the higher metal concentrations, metal fluxes, and weathering rates found in mined areas in the few places where comparisons are possible. The differences are generally 1–3 orders of magnitude higher for acid mine drainage.

  14. Geochemical investigation of UMTRAP designated site at Grand Junction, Colorado

    International Nuclear Information System (INIS)

    Markos, G.; Bush, K.J.

    1983-09-01

    This report is the result of a geochemical investigation of the former uranium mill and tailings site at Grand Junction, Colorado. The objectives of the investigation are to characterize the geochemistry, to determine the contaminant distribution resulting from the former milling activities and tailings, and to infer chemical pathways and transport mechanisms from the contaminant distribution. The results should be used to model contaminant migration and to develop criteria for long-term containment media, such as a cover system which is impermeable to contaminant migration. This report assumes a familiarity with the hydrologic conditions of the site and the geochemical concepts underlying the investigation. The results reported are based on a sampling of waters in two seasons and solid material from the background, the area adjacent to the site, and the site. The solid samples were water extracted to remove easily soluble salts and acid extracted to remove carbonates and hydroxides. The water extracts and solid samples were analyzed for the major and trace elements. A limited number of samples were analyzed for radiological components. The report includes the methods of sampling, sample processing, analysis, and data interpretation. Four major conclusions are: (1) trace element concentrations in shallow subsurface waters adjacent to the tailings temporally vary up to an order of magnitude; (2) the riverbank soils and borehole waters are contaminated with uranium, radium, and trace elements from discharge of tailings solids and solutions during the active time of the mill; however, the movement of contaminants toward the Colorado River does not appear to be significant; (3) the Colorado River adjacent to the tailings is not contaminated; and (4) trace metals have accumulated at both the tailings/cover and tailings/soil interface because of precipitation reactions caused by chemical differences between the two materials

  15. WATEQ3 geochemical model: thermodynamic data for several additional solids

    International Nuclear Information System (INIS)

    Krupka, K.M.; Jenne, E.A.

    1982-09-01

    Geochemical models such as WATEQ3 can be used to model the concentrations of water-soluble pollutants that may result from the disposal of nuclear waste and retorted oil shale. However, for a model to competently deal with these water-soluble pollutants, an adequate thermodynamic data base must be provided that includes elements identified as important in modeling these pollutants. To this end, several minerals and related solid phases were identified that were absent from the thermodynamic data base of WATEQ3. In this study, the thermodynamic data for the identified solids were compiled and selected from several published tabulations of thermodynamic data. For these solids, an accepted Gibbs free energy of formation, ΔG 0 /sub f,298/, was selected for each solid phase based on the recentness of the tabulated data and on considerations of internal consistency with respect to both the published tabulations and the existing data in WATEQ3. For those solids not included in these published tabulations, Gibbs free energies of formation were calculated from published solubility data (e.g., lepidocrocite), or were estimated (e.g., nontronite) using a free-energy summation method described by Mattigod and Sposito (1978). The accepted or estimated free energies were then combined with internally consistent, ancillary thermodynamic data to calculate equilibrium constants for the hydrolysis reactions of these minerals and related solid phases. Including these values in the WATEQ3 data base increased the competency of this geochemical model in applications associated with the disposal of nuclear waste and retorted oil shale. Additional minerals and related solid phases that need to be added to the solubility submodel will be identified as modeling applications continue in these two programs

  16. Hydrological and geochemical consequences of river regulation - hyporheic perspective

    Science.gov (United States)

    Siergieiev, Dmytro; Lundberg, Angela; Widerlund, Anders

    2014-05-01

    River-aquifer interfaces, essential for ecosystem functioning in terms of nutrient exchange and biological habitat, appear greatly threatened worldwide. Although river regulation is a vast pressure on river-aquifer interaction, influencing entire watersheds, knowledge about hyporheic exchange in regulated rivers is rather limited. In this study, we combine two decades of research on hydrological and geochemical impacts of hydropower regulation on river water and hyporheic zone in two large boreal rivers, unregulated Kalix River and regulated Lule River. Altered river discharge, with reduced spring peaks, daily summer fluctuations and elevated winter base flow severely modified Lule River water geochemistry and thus the transport of solutes to the Bothnian Bay (Baltic Sea). Further, these river modifications changed the river-aquifer exchange on both daily and seasonal scale, which resulted in deteriorated hyporheic conditions with reduced riverbed hydraulic conductivity (formation of a clogging layer) reflected in a declined hyporheic flux. Altered hydrological regime of the hyporheic zone created quasi-stagnant conditions beneath the river-aquifer interface and promoted the formation of geochemically suboxic environment. Taken that hyporheic water is a mixture of river water and groundwater, mixing models for the regulated site demonstrate a considerable addition of Fe, Mn, Al, NH4 and removal of dissolved oxygen and nitrate, which suggests the hyporheic zone in the Lule River to be a source of solutes. This contradicts the observations from the hyporheic zone in the unregulated river, with opposite behaviour functioning as a barrier. These results suggest that the hyporheic zone function is dependent on the river discharge and the state of the river-aquifer connectivity. Improved knowledge about the latter on a watershed scale will substantially increase our understanding about the status and potential pressures of riverine ecosystems and assist management and

  17. Geophysical and geochemical signatures of Gulf of Mexico seafloor brines

    Directory of Open Access Journals (Sweden)

    S. B. Joye

    2005-01-01

    Full Text Available Geophysical, temperature, and discrete depth-stratified geochemical data illustrate differences between an actively venting mud volcano and a relatively quiescent brine pool in the Gulf of Mexico along the continental slope. Geophysical data, including laser-line scan mosaics and sub-bottom profiles, document the dynamic nature of both environments. Temperature profiles, obtained by lowering a CTD into the brine fluid, show that the venting brine was at least 10°C warmer than the bottom water. At the brine pool, thermal stratification was observed and only small differences in stratification were documented between three sampling times (1991, 1997 and 1998. In contrast, at the mud volcano, substantial temperature variability was observed, with the core brine temperature being slightly higher than bottom water (by 2°C in 1997 but substantially higher than bottom water (by 19°C in 1998. Detailed geochemical samples were obtained in 2002 using a device called the 'brine trapper' and concentrations of dissolved gases, major ions and nutrients were determined. Both brines contained about four times as much salt as seawater and steep concentration gradients of dissolved ions and nutrients versus brine depth were apparent. Differences in the concentrations of calcium, magnesium and potassium between the two brine fluids suggest that the fluids are derived from different sources, have different dilution/mixing histories, or that brine-sediment reactions are more important at the mud volcano. Substantial concentrations of methane, ammonium, and silicate were observed in both brines, suggesting that fluids expelled from deep ocean brines are important sources of these constituents to the surrounding environment.

  18. Formation of hydrothermal deposits at Kings Triple Junction, northern Lau back-arc basin, SW Pacific: The geochemical perspectives

    Digital Repository Service at National Institute of Oceanography (India)

    Paropkari, A.L.; Ray, D.; Balaram, V.; Prakash, L.S.; Mirza, I.H.; Satyanarayana, M.; Rao, T.G.; Kaisary, S.

    termed as ‘Christmas Tree’ Field. The basal pedestal, the peripheral chimneys and small ‘Christmas Tree’ like growths (samples collected by MIR submersibles), though parts of the same hydrothermal field differ significantly in their mineralogy...

  19. Geochemical site-selection criteria for HLW repositories in Europe and North America

    International Nuclear Information System (INIS)

    Savage, David; Arthur, Randolph C.; Sasamoto, Hiroshi; Shibata, Masahiro; Yui, Mikazu

    2000-01-01

    Geochemical as well as socio-economic issues associated with the selection of potential sites to host a high-level nuclear waste repository have received considerable attention in repository programs in Europe (Belgium, Finland, France, Germany, Spain, Sweden, Switzerland and the U.K.) and North America (Canada and the United States). The objective of the present study is to summarize this international experience with particular emphasis on geochemical properties that factor into the adopted site-selection strategies. Results indicate that the geochemical properties of a site play a subordinate role, at best, to other geotechnical properties in the international site-selection approaches. In countries where geochemical properties are acknowledged in the site-selection approach, requirements are stated qualitatively and tend to focus on associated impacts on the stability of the engineered barrier system and on radionuclide transport. Site geochemical properties that are likely to control the long-term stability of geochemical conditions and radionuclide migration behavior are unspecified, however. This non-prescriptive approach may be reasonable for purposes of screening among potential sites, but a better understanding of site properties that are most important in controlling the long-term geochemical evolution of the site over a range of possible scenarios would enable the potential sites to be ranked in terms of their suitability to host a repository. (author)

  20. A novel two-dimensional model for colloid transport in physically and geochemically heterogeneous porous media.

    Science.gov (United States)

    Sun, N; Elimelech, M; Sun, N Z; Ryan, J N

    2001-06-01

    A two-dimensional model for colloid transport in geochemically and physically heterogeneous porous media is presented. The model considers patchwise geochemical heterogeneity, which is suitable to describe the chemical variability of many surficial aquifers with ferric oxyhydroxide-coated porous matrix, as well as spatial variability of hydraulic conductivity, which results in heterogeneous flow field. The model is comprised of a transient fluid flow equation, a transient colloid transport equation, and an equation for the dynamics of colloid deposition and release. Numerical simulations were carried out with the model to investigate the colloid transport behavior in layered and randomly heterogeneous porous media. Results demonstrate that physical and geochemical heterogeneities markedly affect the colloid transport behavior. Layered physical or geochemical heterogeneity can result in distinct preferential flow paths of colloidal particles. Furthermore, the combined effect of layered physical and geochemical heterogeneity may result in enhanced or reduced preferential flow of colloids. Random distribution of physical heterogeneity (hydraulic conductivity) results in a random flow field and an irregularly distributed colloid concentration profile in the porous medium. Contrary to random physical heterogeneity, the effect of random patchwise geochemical heterogeneity on colloid transport behavior is not significant. It is mostly the mean value of geochemical heterogeneity rather than its distribution that governs the colloid transport behavior.

  1. Hydrogeology and hydrogeochemistry of an alkaline volcanic area: the NE Mt. Meru slope (East African Rift – Northern Tanzania

    Directory of Open Access Journals (Sweden)

    G. Oggiano

    2012-02-01

    Full Text Available The objective of this study is to analyze the geochemical conditions associated with the presence of fluoride (F− in the groundwater of an area of Northern Tanzania. The studied aquifers are composed of volcanic rocks such as phonolitic and nephelinitic lavas, basalts, lahars of various ages and mantling ash. Sedimentary rocks consisting of fine-grained alluvial and lacustrine deposits occur as well. Samples collected from springs, borehole and surface water, during two monitoring surveys, were analyzed for the various physico-chemical and isotopic parameters. The geochemical composition of water is typically sodium bicarbonate. High values of F− (up to 68 mg l−1 were recorded. The highest values of fluoride agreed with the highest values of pH, sodium and bicarbonate. Dissolution of major ions, exchange processes and precipitation of Ca2+ from super-saturated solutions joined with the local permeability and hydraulic gradients, control the fluoride mobilization and the contamination of the area.

  2. Geochemistry, petrology, and palynology of the Pond Creek coal bed, northern Pike and southern Martin counties, Kentucky

    Science.gov (United States)

    Hower, J.C.; Ruppert, L.F.; Eble, C.F.; Clark, W.L.

    2005-01-01

    The geochemistry, petrology, and palynology of the Duckmantian-age Pond Creek coal bed were investigated in northern Pike and southern Martin counties, eastern Kentucky. The coal bed exhibits significant vertical variation in the investigated geochemical parameters, with many diagenetic overprints of the original geochemistry. Included in the range of geochemical signatures are the presence of elements, particularly TiO2 and Zr, suggesting the detrital influences at the time of deposition of a low-vitrinite durain; a high CaO zone with elevated B/Be, both suggesting marine influence, in a lithotype in the middle of the coal bed; and the postdepositional emplacement of pyrite in the uppermost lithotype. Individual lithotypes, each representing distinct depositional environments, all complicated to some degree by diagentic overprints, comprise the complex history of the coal bed. ?? 2004 Elsevier B.V. All rights reserved.

  3. Central Colorado Assessment Project (CCAP)-Geochemical data for rock, sediment, soil, and concentrate sample media

    Science.gov (United States)

    Granitto, Matthew; DeWitt, Ed H.; Klein, Terry L.

    2010-01-01

    This database was initiated, designed, and populated to collect and integrate geochemical data from central Colorado in order to facilitate geologic mapping, petrologic studies, mineral resource assessment, definition of geochemical baseline values and statistics, environmental impact assessment, and medical geology. The Microsoft Access database serves as a geochemical data warehouse in support of the Central Colorado Assessment Project (CCAP) and contains data tables describing historical and new quantitative and qualitative geochemical analyses determined by 70 analytical laboratory and field methods for 47,478 rock, sediment, soil, and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey (USGS) personnel and analyzed either in the analytical laboratories of the USGS or by contract with commercial analytical laboratories. These data represent analyses of samples collected as part of various USGS programs and projects. In addition, geochemical data from 7,470 sediment and soil samples collected and analyzed under the Atomic Energy Commission National Uranium Resource Evaluation (NURE) Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) program (henceforth called NURE) have been included in this database. In addition to data from 2,377 samples collected and analyzed under CCAP, this dataset includes archived geochemical data originally entered into the in-house Rock Analysis Storage System (RASS) database (used by the USGS from the mid-1960s through the late 1980s) and the in-house PLUTO database (used by the USGS from the mid-1970s through the mid-1990s). All of these data are maintained in the Oracle-based National Geochemical Database (NGDB). Retrievals from the NGDB and from the NURE database were used to generate most of this dataset. In addition, USGS data that have been excluded previously from the NGDB because the data predate earliest USGS geochemical databases, or were once excluded for programmatic reasons

  4. A New Sample Transect through the Sierra Madre Occidental Silicic Large Igneous Province in Southern Chihuahua State, Mexico: First Stratigraphic, Petrologic, and Geochemical Results

    Science.gov (United States)

    Andrews, G. D.; Davila Harris, P.; Brown, S. R.; Anderson, L.; Moreno, N.

    2014-12-01

    We completed a field sampling transect across the northern Sierra Madre Occidental silicic large igneous province (SMO) in December 2013. Here we present the first stratigraphic, petrological, and geochemical data from the transect between Hidalgo del Parral and Guadalupe y Calvo, Chihuahua, Mexico. This is the first new transect across the SMO in 25 years and the only one between existing NE - SW transects at Chihuahua - Hermosillo and Durango - Mazatlan. The 245 km-long transect along Mexican Highway 24 crosses the boundary between the extended (Basin and Range) and non-extended (Sierra Madre Occidental plateau) parts of the SMO, and allows sampling of previously undescribed Oligocene (?) - early Miocene (?) rhyolitic ignimbrites and lavas, and occasional post-rhyolite, Miocene (?) SCORBA basaltic andesite lavas. 54 samples of rhyolitic ignimbrites (40) and lavas (7), and basaltic andesite lavas (7) were sampled along the transect, including 8 canyon sections with more than one unit. The ignimbrites are overwhelming rhyodacitic (plagioclase and hornblende or biotite phyric) or rhyolitic (quartz (+/- sanidine) in additon to plagioclase and hornblende or biotite phyric) and sparsely to highly phyric. Preliminary petrographic (phenocryst abundances) and geochemical (major and trace element) will be presented and compared to existing data from elsewhere in the SMO. Future work will include U-Pb zircon dating and whole rock and in-zircon radiogenic isotopes analyses.

  5. Source identification of fine-grained suspended sediment in the Kharaa River basin, northern Mongolia

    Energy Technology Data Exchange (ETDEWEB)

    Theuring, Philipp [Department of Aquatic Ecosystem Analysis and Management — ASAM, Helmholtz Centre for Environmental Research — UFZ, Brückstrasse 3a, D-39114 Magdeburg (Germany); Collins, Adrian L. [Sustainable Soils and Grassland Systems Department, Rothamsted Research, North Wyke, Okehampton, Devon EX20 2SB (United Kingdom); Rode, Michael [Department of Aquatic Ecosystem Analysis and Management — ASAM, Helmholtz Centre for Environmental Research — UFZ, Brückstrasse 3a, D-39114 Magdeburg (Germany)

    2015-09-01

    Fine sediment inputs into river systems can be a major source of nutrients and heavy metals and have a strong impact on water quality and ecosystem functions of rivers and lakes, including those in semiarid regions. However, little is known to date about the spatial distribution of sediment sources in most large scale river basins in Central Asia. Accordingly, a sediment source fingerprinting technique was used to assess the spatial sources of fine-grained (< 10 μm) sediment in the 15 000 km{sup 2} Kharaa River basin in northern Mongolia. Variation in geochemical composition (e.g. in Ti, Sn, Mo, Mn, As, Sr, B, U, Ca and Sb) was used for sediment source discrimination with geochemical composite fingerprints based on Genetic Algorithm (GA)-driven Discriminant Function Analysis, the Kruskal–Wallis H-test and Principal Component Analysis. All composite fingerprints yielded a satisfactory GOF (> 0.97) and were subsequently used for numerical mass balance modelling with uncertainty analysis. The contributions of the individual sub-catchment spatial sediment sources varied from 6.4% (the headwater sub-catchment of Sugnugur Gol) to 36.2% (the Kharaa II sub-catchment in the middle reaches of the study basin), generally showing higher contributions from the sub-catchments in the middle, rather than the upstream, portions of the study area. The importance of river bank erosion is shown to increase from upstream to midstream tributaries. The source tracing procedure provides results in reasonable accordance with previous findings in the study region and demonstrates the applicability and associated uncertainties of the approach for fine-grained sediment source investigation in large scale semi-arid catchments. - Highlights: • Applied statistical approach for selecting composite fingerprints in Mongolia. • Geochemical fingerprinting for the definition of source areas in semiarid catchment. • Test of applicability of sediment sourcing in large scale semi-arid catchments

  6. Source identification of fine-grained suspended sediment in the Kharaa River basin, northern Mongolia

    International Nuclear Information System (INIS)

    Theuring, Philipp; Collins, Adrian L.; Rode, Michael

    2015-01-01

    Fine sediment inputs into river systems can be a major source of nutrients and heavy metals and have a strong impact on water quality and ecosystem functions of rivers and lakes, including those in semiarid regions. However, little is known to date about the spatial distribution of sediment sources in most large scale river basins in Central Asia. Accordingly, a sediment source fingerprinting technique was used to assess the spatial sources of fine-grained (< 10 μm) sediment in the 15 000 km 2 Kharaa River basin in northern Mongolia. Variation in geochemical composition (e.g. in Ti, Sn, Mo, Mn, As, Sr, B, U, Ca and Sb) was used for sediment source discrimination with geochemical composite fingerprints based on Genetic Algorithm (GA)-driven Discriminant Function Analysis, the Kruskal–Wallis H-test and Principal Component Analysis. All composite fingerprints yielded a satisfactory GOF (> 0.97) and were subsequently used for numerical mass balance modelling with uncertainty analysis. The contributions of the individual sub-catchment spatial sediment sources varied from 6.4% (the headwater sub-catchment of Sugnugur Gol) to 36.2% (the Kharaa II sub-catchment in the middle reaches of the study basin), generally showing higher contributions from the sub-catchments in the middle, rather than the upstream, portions of the study area. The importance of river bank erosion is shown to increase from upstream to midstream tributaries. The source tracing procedure provides results in reasonable accordance with previous findings in the study region and demonstrates the applicability and associated uncertainties of the approach for fine-grained sediment source investigation in large scale semi-arid catchments. - Highlights: • Applied statistical approach for selecting composite fingerprints in Mongolia. • Geochemical fingerprinting for the definition of source areas in semiarid catchment. • Test of applicability of sediment sourcing in large scale semi-arid catchments.

  7. Evolution of hillslope soils: The geomorphic theater and the geochemical play

    Energy Technology Data Exchange (ETDEWEB)

    Yoo, Kyungsoo, E-mail: kyoo@umn.edu [Dept. of Soil, Water, and Climate, University of Minnesota, 439 Borlaug Hall, 1991 Upper Buford Circle, St. Paul, MN, 55108-6028 (United States); Weinman, Beth [Dept. of Soil, Water, and Climate, University of Minnesota, 439 Borlaug Hall, 1991 Upper Buford Circle, St. Paul, MN, 55108-6028 (United States); Mudd, Simon Marius; Hurst, Martin; Attal, Mikael [School of GeoSciences, University of Edinburgh, Drummond Street, Edinburgh EH8 9XP, Scotland (United Kingdom); Maher, Kate [Dept. of Geological and Environmental Sciences, Braun Hall 118, 450 Serra Mall, Bldg. 320, Stanford, CA 94305-2115 (United States)

    2011-06-15

    Highlights: > We ask 'how and how fast do hillslope soils form as the landscape's morphology changes over time?'. > Over wide range of denudation rates, soil thicknesses do not vary significantly. > Colluvial soils with lower denudation rates (above the knick point) are enriched in fine size fractions, Zr, and pedogenic crystalline Fe oxides. > In the two steep hillslopes below the knickpoint, no systematic topgraphic trends were found for soil geochemistry. > Soils show increasing Zr enrichment in the downslope direction only in the hillslope above the knickpoint. - Abstract: How and how fast do hillslope soils form as the landscape's morphology changes over time? Here results are shown from an ongoing study that simultaneously examines the morphologic and geochemical evolution of soil mantled hillslopes that have been exposed to distinctively different denudation history. In Northern Sierra Nevada, California, the authors are investigating a tributary basin to the Middle Fork Feather River. A major incision signal from the river is well marked in a knickpoint within the tributary basin which stretches from its mouth to the Feather River at an elevation of {approx}700 m to the plateau at an elevation of {approx}1500 m. Hillslopes are significantly steeper below the knickpoint. The area's total denudation rates are currently being constrained using cosmogenic radio nuclides, but a previous study suggested an order of magnitude difference in total denudation rates below and above the knickpoint. When compared with topographic attributes calculated from LIDAR data, physical erosion rates can be modeled as a linear function of ridge top curvature. Surprisingly, over the wide range of total denudation rates, soil thicknesses do not vary significantly until a threshold point where soil mantled landscapes abruptly shift to bedrock dominated landscapes. Bioturbation by tree falls appear to buffer soil thickness over the wide range of physical soil

  8. Geothermal regimes of the Clearlake region, northern California

    Energy Technology Data Exchange (ETDEWEB)

    Amador, M. [ed.; Burns, K.L.; Potter, R.M.

    1998-06-01

    The first commercial production of power from geothermal energy, at The Geysers steamfield in northern California in June 1960, was a triumph for the geothermal exploration industry. Before and since, there has been a search for further sources of commercial geothermal power in The Geysers--Clear Lake geothermal area surrounding The Geysers. As with all exploration programs, these were driven by models. The models in this case were of geothermal regimes, that is, the geometric distribution of temperature and permeability at depth, and estimates of the physical conditions in subsurface fluids. Studies in microseismicity and heat flow, did yield geophysical information relevant to active geothermal systems. Studies in stable-element geochemistry found hiatuses or divides at the Stoney Creek Fault and at the Collayomi Fault. In the region between the two faults, early speculation as to the presence of steamfields was disproved from the geochemical data, and the potential existence of hot-water systems was predicted. Studies in isotope geochemistry found the region was characterized by an isotope mixing trend. The combined geochemical data have negative implications for the existence of extensive hydrothermal systems and imply that fluids of deep origin are confined to small, localized systems adjacent to faults that act as conduits. There are also shallow hot-water aquifers. Outside fault-localized systems and hot-water aquifers, the area is an expanse of impermeable rock. The extraction of energy from the impermeable rock will require the development and application of new methods of reservoir creation and heat extraction such as hot dry rock technology.

  9. Upper Cretaceous source rocks of northern and northwestern South America

    Energy Technology Data Exchange (ETDEWEB)

    Talukdar, S.; Gallango, O.; Cassani, F.; Vallejos, C.

    1989-03-01

    Organic carbon-rich, laminated, calcareous shales and limestones of Cenomanian to Campanian age are widespread in the polyhistory basins of Venezuela, Colombia, and Trinidad and are identified as the most important oil-generating source rocks in these basins. Available data on sedimentological, geochemical, and organic petrographic characteristics demonstrate that these source rocks are characterized by predominantly marine organic matter deposited in anoxic to near-anoxic marine environments. Marine transgressions due to eustatic sea level rise, with consequent flooding of available shelves of the northern and northwestern passive margin of the Cretaceous South American continent and resulting upwelling conditions, appears to be the key geologic control for the deposition of these laterally extensive source rocks. Significant vertical variations in geochemical properties are observed. These variations were caused by temporal changes in the influx of terrestrial organic matter and/or alternations of relatively oxic and anoxic conditions. Regional variations in organic carbon content, organic matter type, and oil potential broadly reflect the paleogeographic setting of the Cretaceous continental margin. The regionally extensive oil-prone source rocks became largely mature for hydrocarbon generation during the Tertiary, consequent to the development of the individual polyhistory basins. Rock-Eval pyrolysis data from several samples and results from hydrous pyrolysis experiments on some selected immature samples from the Venezuelan basins are used to define the oil-generating capacity, and kinetic parameters obtained from Rock-Eval experiments on the same samples are considered to outline the oil generation under the geological heating rates encountered in the sedimentary basins.

  10. Flight tracks, Northern California TRACON

    Data.gov (United States)

    National Aeronautics and Space Administration — This dataset contains the records of all the flights in the Northern California TRACON. The data was provided by the aircraft noise abatement office...

  11. Northern Fur Seal Food Habits

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This data set contains food habits samples, usually scats, collected opportunistically on northern fur seal rookeries and haulouts in Alaska from 1987 to present....

  12. Geochemical databases: minding the pitfalls to avoid the pratfalls

    Science.gov (United States)

    Goldstein, S. L.; Hofmann, A. W.

    2011-12-01

    The field of geochemistry has been revolutionized in recent years by the advent of databases (PetDB, GEOROC, NAVDAT, etc). A decade ago, a geochemical synthesis required major time investments in order to compile relatively small amounts of fragmented data from large numbers of publications, Now virtually all of the published data on nearly any solid Earth topic can be downloaded to nearly any desktop computer with a few mouse clicks. Most solid Earth talks at international meetings show data compilations from these databases. Applications of the data are playing an increasingly important role in shaping our thinking about the Earth. They have changed some fundamental ideas about the compositional structure of the Earth (for example, showing that the Earth's "trace element depleted upper mantle" is not so depleted in trace elements). This abundance of riches also poses new risks. Until recently, important details associated with data publication (adequate metadata and quality control information) were given low priority, even in major journals. The online databases preserve whatever has been published, irrespective of quality. "Bad data" arises from many causes, here are a few. Some are associated with sample processing, including incomplete dissolution of refractory trace minerals, or inhomogeneous powders, or contamination of key elements during preparation (for example, this was a problem for lead when gasoline was leaded, and for niobium when tungsten-carbide mills were used to powder samples). Poor analytical quality is a continual problem (for example, when elemental abundances are at near background levels for an analytical method). Errors in published data tables (more common than you think) become bad data in the databases. The accepted values of interlaboratory standards change with time, while the published data based on old values stay the same. Thus the pitfalls associated with the new data accessibility are dangerous in the hands of the inexperienced

  13. Geochemical Signatures as a Tool for Vermiculite Provenance Determination

    Energy Technology Data Exchange (ETDEWEB)

    Karen E. Wright; Carl D. Palmer

    2008-09-01

    Thirty-eight samples of known origin (China, Libby MT, South Africa, South Carolina) and 6 vermiculite product samples of unknown origin were analyzed for major and trace elements, including rare earth elements to determine the feasibility of distinguishing the provenance of the samples based upon a geochemical signature. Probability plots suggest that two of the four groups (Libby, South Carolina) were comprised of two subgroups. Results of hierarchical cluster analysis are highly sensitive to the linkage method chosen. Ward’s method is the most useful for this data and suggests that there are five groups within the data set (South African samples, two subsets of the Libby samples, a subset of the South Carolina samples, and a second subset of the South Carolina samples combined with the China samples). Similar results were obtained using k-cluster analysis. Neither clustering method was able to distinguish samples from China from the South Carolina samples. Discriminant analysis was used on a four-category model comprised of the original four groups and on a six-category model comprised of the five categories identified from the cluster analysis but with the China samples grouped into a sixth category. The discriminant/classification model was able to distinguish all of the groups including the China samples from one another for both the four- and six-category models with 100% of the samples properly classified. The 6 unknown product samples were classified with a probability of consistency of 99%. Both discriminant models were also run with a subset of our analyte set to be consistent with the smaller Gunter et al., (2005) analyte set. Twenty vermiculite samples (nine of known origin and eleven of unknown origin) from their study were classified based on our discriminant models with the reduced set of analytes. Of the twenty samples, Gunter et al. (2005) was able to classify 16 with cluster analysis while our 4-category discriminant analysis model allowed us

  14. Baseline Geochemical Data for Medical Researchers in Kentucky

    Science.gov (United States)

    Anderson, W.

    2017-12-01

    According to the Centers for Disease Control, Kentucky has the highest cancer incidence and death rates in the country. New efforts by geochemists and medical researchers are examining ways to diagnose the origin and sources of carcinogenesis. In an effort to determine if naturally occurring geochemical or mineral elements contributes to the cancer causation, the Kentucky Geological Survey has established a Minerals and Geochemical Database that is available to medical researchers for examination of baseline geochemistry and determine if naturally occurring mineral or chemical elements contribute to the high rate of cancers in the state. Cancer causation is complex, so if natural sources can be accounted for, then researchers can focus on the true causation. Naturally occurring minerals, metals and elements occur in many parts of the state, and their presence is valuable for evaluating causation. For example, some data in the database contain maps showing (a) statewide elemental geochemistry, (b) areas of black shale oxidation occurrence, which releases metals in soil and surface waters, (c) some clay deposits in the state that can contain high content of rare earth elements, and (d) site-specific uranium occurrences. Knowing the locations of major ore deposits in the state can also provide information related to mineral and chemical anomalies, such as for base metals and mercury. Radionuclide data in soil and water analyses are limited, so future research may involve obtaining more analyses to determine radon potential. This database also contains information on faulting and geology in the state. Although the metals content of trees may not seem relevant, the ash and humus content of degraded trees affects soil, stream sediment and water geochemistry. Many rural homes heat with wood, releasing metals into the surrounding biosphere. Stressed vegetation techniques can be used to explore for ore deposits and look for high metal contents in soils and rocks. These

  15. Geochemical evaluation of the middle Magdalena basing Colombia

    International Nuclear Information System (INIS)

    Ramon, J.C; Dzou, L; Giraldo, B

    1997-01-01

    The chemical composition of 25 crude oils from Tertiary reservoirs and 12 rock extracts from five organic-rich Cretaceous formations in the middle Magdalena Basin, Colombia were studied in detail by geochemical methods in order to understand their genetic relationships. The oils have been geochemically classified into four main groups based on the sulfur content, pristane/phytane, dibenzothiophene /phenanthrene, concentrations of oleanane and terpane distributions. Each group occurs in different geographic locations. Oils were mainly derived from calcareous, siliciclastic and mixture of these two facies of the Upper Cretaceous La Luna Formation. Source-oil correlation is supported by sterane and terpane distributions of and carbon isotope ratios. Some oils in the eastern margin contain relatively higher concentrations of higher plant indicators than the remaining oil samples. The molecular compositions of the oils observed in this study appear to be consistent with the inferred depositional sequence of anoxic marine/pelagic carbonate facies in the north/western sector of the Middle Magdalena, while the eastern sector received a higher proportion of clastic input. This documentation supports the interpretation that the Middle Magdalena oils have been generated 'locally', as opposed to have migrated from the region of the Eastern Cordillera. Biomarker maturity parameters indicate that the majority of oils were generated in the early thermal maturity oil window except the Colorado-38 oil, which was generated in the middle thermal maturity oil window. Oil maturity data also supports the short migration distances of oils from the early-mature source rocks to the reservoir rocks. The composition of some oils (e.g., La Cira, Infantas, Conde and Bonanza) is unusual in that gas chromatographic data contains an n-alkane and isoprenoid distribution normally associated with moderately degraded oils, but they also contain a relatively high abundance of gasoline hydrocarbons

  16. Petrographic and geochemical analyisis for determination of provenance of the Slovenj Gradec Miocene Basin fill (Western Central Paratethys)

    Science.gov (United States)

    Ivančič, Kristina; Trajanova, Mirka; Skaberne, Dragomir; Šmuc, Andrej

    2017-04-01

    The Slovenj Gradec Basin (SGB) is located in northern Slovenia between eastern margin of the Northern Karavanke and the western Pohorje Mts. Structurally, it belongs to Eastern Alps. It is filled with Miocene clastic sediments. Modal composition of sandstones was determined on thin sections by point-counter and presented with the QFL and QmFLt diagrams. Their geochemical composition was determined by classical method and by Inductively Coupled Plasma-Mass Spectrometry. Based on petrography, sedimentary fill of the SGB consists mostly of lithic grains and quartz, derived from metamorphic and carbonate rocks. Locally, fragments of granitoids occur. Binder consists of carbonate, subordinately quartz cement, and carbonate matrix. Recycled orogen (lithic and transitional recycled) provenance of the grains was determined. Geochemical composition shows that: - Sandstones from the SGB belong to the fields of shale, wacke, litharenite, arkose and subarkose (Pettijohn, 1972). - In the ternary diagram of weathering trends (cf. Nesbitt & Young 1984), the samples group near the CaO+Na2OAl2O3 conjunctive. Calculated minimum CIA (Fedo et al., 1995) is 40.06, indicating that the source rocks were not subjected to considerable weathering. - According to discriminant function (cf. Roser & Korsch, 1988) all samples from SGB originate from quartzose sedimentary rocks. - For determination of tectonic setting of source rocks (Verma & Armstrong-Altrin, 2013) the studied samples plot in the field of collision zone. - In the multidimensional discriminant function diagram for the discrimination of active and passive margin after Verma and Armstrong (2016), the samples plot into the field of passive margin. The data indicate that source rocks of the SGB sedimentary fill were derived from Eastern Alps and Southern Alps. It is suggested that SGB was detached from the Styrian and Mura-Zala Basins in the course of the Pohorje Mts. oblique transpressive uplift during the late Miocene to Pliocene

  17. Potential accumulation of contaminated sediments in a reservoir of a high-Andean watershed: Morphodynamic connections with geochemical processes

    Science.gov (United States)

    Contreras, María. Teresa; Müllendorff, Daniel; Pastén, Pablo; Pizarro, Gonzalo E.; Paola, Chris; Escauriaza, Cristián.

    2015-05-01

    Rapid changes due to anthropic interventions in high-altitude environments, such as the Altiplano region in South America, require new approaches to understand the connections between physical and geochemical processes. Alterations of the water quality linked to the river morphology can affect the ecosystems and human development in the long term. The future construction of a reservoir in the Lluta River, located in northern Chile, will change the spatial distribution of arsenic-rich sediments, which can have significant effects on the lower parts of the watershed. In this investigation, we develop a coupled numerical model to predict and evaluate the interactions between morphodynamic changes in the Lluta reservoir, and conditions that can potentially desorb arsenic from the sediments. Assuming that contaminants are mobilized under anaerobic conditions, we calculate the oxygen concentration within the sediments to study the interactions of the delta progradation with the potential arsenic release. This work provides a framework for future studies aimed to analyze the complex connections between morphodynamics and water quality, when contaminant-rich sediments accumulate in a reservoir. The tool can also help to design effective risk management and remediation strategies in these extreme environments. This article was corrected on 15 JUNE 2015. See the end of the full text for details.

  18. Variations of the Antarctic Circumpolar Current (ACC) in the Kerguelen Sector during the Last Deglaciation : sedimentological and geochemical evidences

    Science.gov (United States)

    Bout-Roumazeilles, V.; Beny, F.; Mazaud, A.; Michel, E.; Crosta, X.; Davies, G. R.; Bory, A. J. M.

    2017-12-01

    High-resolution sedimentological and geochemical records were obtained from two sediment cores recovered by the French R/V Marion Dufresne during the INDIEN-SUD-ACC cruises near the sub-Antarctic Kerguelen Islands (49°S). This area is ideal to record past oceanic and atmospheric changes in the Southern Ocean because they are currently located in the northern branch of the Antarctic Circumpolar Current and under the direct influence of Southern Hemisphere Westerly wind belt. This study focuses on the last termination, with specific emphasis on the impact of severe climatic events (Heinrich Stadial 1, Antarctic Cold Reversal, Younger Dryas) onto the ocean-atmospheric exchange. Results indicates that most of the sediment is derived from the Kerguelen Plateau, characterized by high smectite content. Periodically, a minor contribution of Antarctica is noticeable. In particular, illite variations suggest fast and short northward incursions of Antarctic Bottom Water, probably formed in the Prydz Bay during the last glaciation. Grainsize repartition combined to magnetic parameters show a southward migration of the ACC and the fronts associated from the beginning of the deglaciation, which is consistent with Southern Hemisphere climate variations. On the opposite, it highlights an asynchronous decrease of the ACC strength, with a large drop during the Antarctic Cold Reversal when atmospheric CO2 increase was slowed down. Thus, at least in the studied area, the ACC strength and the Antarctic Climate were not synchronous during the last deglaciation.

  19. A case study of long-term geochemical evolution of coal waste rock drainage and its remediation

    Energy Technology Data Exchange (ETDEWEB)

    Jarvis, A.P.; Gandy, C.J. [Newcastle Univ. (United Kingdom). School of Civil Engineering and Geosciences, Hydrogeochemical Engineering Research and Outreach Group

    2010-07-01

    The geochemical evolution of drainage from an 35 hectare orphan waste rock pile over a 15-year period was described. Spoil material at the site was generated during coal mining at 2 collieries between 1922 and 1970, and was comprised of grey and black shale, ash, coal, and coal dust. The heap was founded on an impermeable clay layer. Located in northern England, drainage from the rock heap was intercepted by a small compost wetland system installed in 1997. The waste rock heap was selectively capped in 1998. Water samples were collected and analyzed. Anion concentrations were determined using an ion chromatograph. The samples were filtered periodically. Acidity concentrations and flow rates were determined. Results of the study showed measurable improvements in water quality as a result of capping the heap. The study demonstrated that a combination of selective spoil capping and wetland treatment can serve as a low-cost solution to acid mine drainage at some abandoned mine sites. 9 refs., 1 tab., 1 fig.

  20. Isotopic and geochemical evidence of recharge sources and water quality in the Quaternary aquifer beneath Jinchang city, NW China

    International Nuclear Information System (INIS)

    Ma Jinzhu; Pan Feng; Chen Lihua; Edmunds, W. Mike; Ding Zhenyu; He Jianhua; Zhou Kunpeng; Huang Tianming

    2010-01-01

    Multiple isotopic and hydrogeochemical tracers were utilized to understand the recharge sources and geochemical evolution of groundwater in the Quaternary aquifer beneath Jinchang city and the adjacent Gobi desert area. The groundwater shows markedly depleted stable isotopic composition compared to modern rainfall. The signature of groundwaters from Jinchang and the northern Gobi desert area differ clearly from that of the alluvial fan in the south Yongchang basin and modern rainfall, and has lower or non-detectable 3 H activity, implying that the aquifer is likely maintained by palaeowater. This groundwater in the Gobi desert has a 14 C age older than 12 ka, indicating that the groundwater resources are non-renewable. The build-up of dissolved solids through evaporation is a major control on groundwater composition, and the dominant anion species change systematically from HCO 3 - , SO 4 2- to Cl - , but cations from weathering of albite, calcite, dolomite and gypsum also make a significant contribution. The scientific results have important implications for groundwater management in Jinchang city and as well as in the Shiyang River basin under China's West Development Strategy. It is recommended that the water allocation program of diverting water from the Dongda river to the Minqin basin be reconsidered.

  1. Isotopic (U-Pb, Nd) and geochemical constraints on the origins of the Aileu and Gondwana sequences of Timor

    Science.gov (United States)

    Boger, S. D.; Spelbrink, L. G.; Lee, R. I.; Sandiford, M.; Maas, R.; Woodhead, J. D.

    2017-02-01

    Detrital zircon U-Pb age data collected from the argillitic sedimentary rocks of the Timorese Aileu Complex and Gondwana Sequence indicate that both units were derived from a common source containing 200-600 Ma, 900-1250 Ma and 1450-1900 Ma zircon. The modally most significant age population within this range of ages dates to c. 260 Ma. The observed spectrum of ages can be traced to the eastern active margin of Pangaea and its immediate foreland, which today is best exposed along the northeast coast of Australia. Compared to the relative homogeneity of the detrital zircon age data, geochemical and Nd isotopic data show that the mudstones of the Aileu Complex are on average more siliceous, have higher K2O/Na2O, Rb/Sr, Th/Sc and yield notably older Nd TDM model ages when compared to those from the Gondwana Sequence. These data are interpreted to suggest that, although both sequences share a common east Pangaea provenance, they were eroded from different sections of this active margin and deposited in spatially separated basins. The present proximity of these units is a result of their tectonic juxtaposition during the Pliocene to Recent collision between the northern edge of the Indo-Australia plate and the Banda Arc.

  2. Early Cretaceous Tertiary magmatism in Eastern Paraguay (western Paraná basin): geological, geophysical and geochemical relationships

    Science.gov (United States)

    Comin-Chiaramonti, P.; Cundari, A.; DeGraff, J. M.; Gomes, C. B.; Piccirillo, E. M.

    1999-11-01

    Structural characteristics of Eastern Paraguay, at the westernmost side of the Paraná basin, show that the tectonics in the region is extensional. This tectonics controlled the emplacement of the alkaline rocks in Early Cretaceous-Tertiary times. Major structures are NW-trending zones of tectonic subsidence, i.e. the 'Asunción-Sapucai-Villarrica' and 'Amambay' grabens of the central and northeastern regions of Eastern Paraguay, respectively. Early Cretaceous potassic magmatism is widespread in the 'gravity lows', and predates the tholeiitic Early Cretaceous magmatism in the northern areas, whereas in central Paraguay it postdates the tholeiitic flood basalts. Sodic alkaline rocks (late Early Cretaceous-Tertiary) are widespread in cratonized areas of the La Plata Craton. The Early Cretaceous uncontaminated potassic rocks (and tholeiites) have geochemical features of 'subduction type' (e.g. Ta-Nb negative anomaly), while the contrary occurs for the closely associated younger sodic magmatism. This implies different mantle sources consistently with Sr-Nd isotopes which are Rb-Nd enriched and depleted for the potassic and sodic rocks, respectively. T DM(Nd) model ages point to two notional distinct metasomatic events occurred in Middle and Late Proterozoic times. A contribution of asthenospheric melts from Tristan da Cunha Plume is not appreciable. We suggest that the source(s) of the recurrent potassic magmatism and interposed tholeiitic event may not be easily accounted for by the Tristan da Cunha plume hypothesis.

  3. Tornadoes Strike Northern Wisconsin

    Science.gov (United States)

    2007-01-01

    A series of tornadoes ripped through the Upper Midwest region of the United States in the evening of June 7, 2007. At least five different tornadoes touched down in Wisconsin, according to the Associated Press, one of which tore through the Bear Paw Resort in northern Wisconsin. Despite dropping as much as fifteen centimeters (six inches) of rain in some places and baseball-size hail in others, authorities were reporting no deaths attributable to the storm system, and only a smattering of injuries, but considerable property damage in some areas. When the MODIS instrument on NASA's Terra satellite observed the area on June 9, 2007, the track torn through the woods by one of the tornadoes stands out quite clearly. This photo-like image uses data collected by MODIS in the normal human vision range to give a familiar natural-looking appearance. The landscape is largely a checkerboard of farms, towns, roads, and cities. The pale land is predominantly farmland where crops have not fully grown in yet. Dark blue shows the winding path of rivers and lakes dotting the landscape. The large blue lake on the east (right) side of the image is Lake Michigan. Towns and cities, including the city of Green Bay, are gray. To the north side, farmland gives way to dark green as land use shifts from agriculture to the Menominee Indian Reservation and Nicolet National Forest. The diagonal slash through the dark green forested land shows the tornado track. Bare land was revealed where the tornado tore down trees or stripped vegetation off the branches. The high-resolution image provided above is at MODIS' full spatial resolution (level of detail) of 250 meters per pixel. The MODIS Rapid Response System provides this image at additional resolutions.

  4. Geochemical correlations between uranium and other components in U-bearing formations of Ogcheon belt

    International Nuclear Information System (INIS)

    Lee, M.S.; Chon, H.T.

    1980-01-01

    Some components in uranium-bearing formations which consist mainly of black shale, slate and low grade coal-bearing formation of Ogcheon Belt were processed statistically in order to find out the geochemical correlations with uranium. Geochemical enrichment of uranium, vanadium and molybdenum in low grade coal-bearing formations and surrounding rocks is remarkable in the studied area. Geochemical correlation coefficient of uranium and molybdenum in the rocks displays about 0.6 and that of uranium and fixed carbon about 0.4. Uranium and vanadium in uranium-bearing low grade coals denote very high correlation with fixed carbon, which is considered to be responsible for enrichment of metallic elements, especially molybdenum. Close geochemical correlation of uranium-molybdenum couple in the rocks can be applied as a competent exploration guide to low grade uranium deposits of this area. (author)

  5. Some geochemical characteristics of the Pachuca Obsidian Region: a strategy for interpreting artifact groups

    Energy Technology Data Exchange (ETDEWEB)

    Neivens, M.; Harbottle, G.; Kimberlin, J.

    1981-01-01

    Obsidian research has revealed geochemical anomalies. Neutron activation analysis was used to analyze the samples. Correlations were made between element pairs (Sc and Fe, Ba and Co). Tests were made for homogeneity. 5 figures. (DLC)

  6. Uruguay mining Inventory: geochemical prospecting results of Cerro de las Cuentas mapping

    International Nuclear Information System (INIS)

    Spangenberg, J.; Filippini, J.

    1986-01-01

    This work is about the geochemical prospecting carried out into the Uruguay mining inventory framework. In this case the survey was in Cerro de las Cuentas mapping. Cerro Largo department. Scale 1 / 50000.

  7. Establishing nursery estuary otolith geochemical tags for Sea Bass (Dicentrarchus labrax): Is temporal stability estuary dependent?

    Science.gov (United States)

    Ryan, Diarmuid; Wögerbauer, Ciara; Roche, William

    2016-12-01

    The ability to determine connectivity between juveniles in nursery estuaries and adult populations is an important tool for fisheries management. Otoliths of juvenile fish contain geochemical tags, which reflect the variation in estuarine elemental chemistry, and allow discrimination of their natal and/or nursery estuaries. These tags can be used to investigate connectivity patterns between juveniles and adults. However, inter-annual variability of geochemical tags may limit the accuracy of nursery origin determinations. Otolith elemental composition was used to assign a single cohort of 0-group sea bass Dicentrarchus labrax to their nursery estuary thus establishing an initial baseline for stocks in waters around Ireland. Using a standard LDFA model, high classification accuracies to nursery sites (80-88%) were obtained. Temporal stability of otolith geochemical tags was also investigated to assess if annual sampling is required for connectivity studies. Geochemical tag stability was found to be strongly estuary dependent.

  8. Quantitative determination of 210Po in geochemical samples

    International Nuclear Information System (INIS)

    Dyck, W.; Bristow, Q.

    1984-01-01

    To test the usefulness of 210 Po in soils as a means of detecting buried U mineralization, methods for the determination of 210 Po were investigated and adapted for routine production of 210 Po data from geochemical samples. A number of conditions affecting autodeposition and detection of 210 Po were investigated. The optimum area of deposition with a 450 mm 2 solid state detector was found to be 300 mm 2 . Convenience dictated room temperature over-night deposition times, although increased temperature increased speed and efficiency of deposition. A clear inverse relationship was observed between volume of solution and deposition efficiency with stirring times of less than 2 hours. For routine analysis, soil and rock powders were dissolved by leaching 1 g samples in teflon beakers successively with conc. HNO 3 , HF, and HNO 3 -HClO 4 , evaporating the solution to dryness between leaches, and taking the residue up in 20 mL 0.5 M HCl. The 210 Po was deposited on 19 mm diameter Ni discs and counted with an alpha spectrometer system employing 450 mm 2 ruggedized surface barrier detectors. The method achieved 90 percent recovery of 210 Po from solution and a detection efficiency of 30 percent. With a counting time of 3 hours, the method is capable of detecting 0.2 pCi of 210 Po per gram of sample

  9. Modeling Background Radiation in our Environment Using Geochemical Data

    Energy Technology Data Exchange (ETDEWEB)

    Malchow, Russell L.; Marsac, Kara [University of Nevada, Las Vegas; Burnley, Pamela [University of Nevada, Las Vegas; Hausrath, Elisabeth [Uniiversity of Nevada, Las Vegas; Haber, Daniel [University of Nevada, Las Vegas; Adcock, Christopher [University of Nevada, Las Vegas

    2015-02-01

    Radiation occurs naturally in bedrock and soil. Gamma rays are released from the decay of the radioactive isotopes K, U, and Th. Gamma rays observed at the surface come from the first 30 cm of rock and soil. The energy of gamma rays is specific to each isotope, allowing identification. For this research, data was collected from national databases, private companies, scientific literature, and field work. Data points were then evaluated for self-consistency. A model was created by converting concentrations of U, K, and Th for each rock and soil unit into a ground exposure rate using the following equation: D=1.32 K+ 0.548 U+ 0.272 Th. The first objective of this research was to compare the original Aerial Measurement System gamma ray survey to results produced by the model. The second objective was to improve the method and learn the constraints of the model. Future work will include sample data analysis from field work with a goal of improving the geochemical model.

  10. Fracture Sealing in Shales: Geological and Geochemical Factors

    International Nuclear Information System (INIS)

    Cathelineau, Michel

    2001-01-01

    The so-called self-sealing processes can be re-examined at the light of geological and geochemical consideration about the past history of the rocks. The concept of 'self sealing' needs to consider the formation and the sealing of fractures, especially three main stages: (i) the initiation of the fracture (development of micro-cracks initiated from previous heterogeneities up to fracturing), ii) the fracturing processes which occur generally at depth in presence of a fluid phase, iii) the healing or sealing of the fractures which corresponds basically to two main processes: a restoration of the initial permeability of the rock block by reducing the transmissivity of the discontinuity down to values equivalent to that of the homogeneous medium before fracturing, or the sealing of the open discontinuity by precipitation of newly formed minerals. In the latter case, the evolution of the open fracture is driven by re-arrangement of particles or precipitation of newly formed material, either by dissolution/crystallisation processes or by crystallisation from the percolating fluids (advective processes). Such processes are governed by chemical processes, especially the rate of precipitation of minerals which depends of the degree of saturation with respect to the mineral, and the kinetics of precipitation. (author)

  11. Application of geochemical methods in earthquake prediction in China

    Energy Technology Data Exchange (ETDEWEB)

    Fong-liang, J.; Gui-ru, L.

    1981-05-01

    Several geochemical anomalies were observed before the Haichen, Longling, Tangshan, and Songpan earthquakes and their strong aftershocks. They included changes in groundwater radon levels; chemical composition of the groundwater (concentration of Ca/sup + +/, Mg/sup + +/, Cl/sup -/, So/sub 4//sup , and HCO/sub 3//sup -/ ions); conductivity; and dissolved gases such as H/sub 2/, CO/sub 2/, etc. In addition, anomalous changes in water color and quality were observed before these large earthquakes. Before some events gases escaped from the surface, and there were reports of ''ground odors'' being smelled by local residents. The large amount of radon data can be grouped into long-term and short-term anomalies. The long-term anomalies have a radon emission build up time of from a few months to more than a year. The short-term anomalies have durations from a few hours or less to a few months.

  12. Rock Weathering and Geochemical Characteristics in the KURT

    International Nuclear Information System (INIS)

    Lee, Seung Yeop; Baik, Min Hoon; Cho, Won Jin; Hahn, Pil Soo

    2006-01-01

    A basic research was conducted on the mineral weathering and geochemical characteristics in the KURT (KAERI Underground Research Tunnel), which was recently constructed at a site in KAERI. Some rock samples exposed during the KURT construction were examined using a microscope and chemical analysis for some micro-changes of the rocks caused by the chemical weathering. The weathered granite has some small and fine cracks around the rock-forming minerals. In particular, there are a characteristic weathering of feldspar mineral and a preferential leaching of Ca component from the mineral dissolution. In addition, by the dissolution of biotite containing Fe 2- component there were iron-oxides precipitates as secondary products into the microcracks of around minerals. The results also show that the micro-cracks initiated from the mineral interior are extended and connected into the larger cracks along the grain boundary with the progress of the weathering. Thus, it is considered that some chemicals dissolved from the fresh rock would be involved in the formation of secondary minerals and migrate interacting with them.

  13. Leaching and geochemical behavior of fired bricks containing coal wastes.

    Science.gov (United States)

    Taha, Yassine; Benzaazoua, Mostafa; Edahbi, Mohamed; Mansori, Mohammed; Hakkou, Rachid

    2018-03-01

    High amounts of mine wastes are continuously produced by the mining industry all over the world. Recycling possibility of some wastes in fired brick making has been investigated and showed promising results. However, little attention is given to the leaching behavior of mine wastes based fired bricks. The objective of this paper is to evaluate the geochemical behavior of fired bricks containing different types of coal wastes. The leachates were analyzed for their concentration of As, Ba, Cd, Co, Cr, Cu, Mo, Ni, Pb, Zn and sulfates using different leaching tests; namely Tank Leaching tests (NEN 7375), Toxicity Characteristic Leaching Procedure (TCLP) and pH dependence test (EPA, 1313). The results showed that the release of constituents of potential interest was highly reduced after thermal treatment and were immobilized within the glassy matrix of the fired bricks. Moreover, it was also highlighted that the final pH of all fired samples changed and stabilized around 8-8.5 when the initial pH of leaching solution was in the range 2.5-11.5. The release of heavy metals and metalloids (As) tended to decrease with the increase of pH from acidic to alkaline solutions while Mo displayed a different trend. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. Cool seafloor hydrothermal springs reveal global geochemical fluxes

    Science.gov (United States)

    Wheat, C. Geoffrey; Fisher, Andrew T.; McManus, James; Hulme, Samuel M.; Orcutt, Beth N.

    2017-10-01

    We present geochemical data from the first samples of spring fluids from Dorado Outcrop, a basaltic edifice on 23 M.y. old seafloor of the Cocos Plate, eastern Pacific Ocean. These samples were collected from the discharge of a cool hydrothermal system (CHS) on a ridge flank, where typical reaction temperatures in the volcanic crust are low (2-20 °C) and fluid residence times are short. Ridge-flank hydrothermal systems extract 25% of Earth's lithospheric heat, with a global discharge rate equivalent to that of Earth's river discharge to the ocean; CHSs comprise a significant fraction of this global flow. Upper crustal temperatures around Dorado Outcrop are ∼15 °C, the calculated residence time is concentrations in spring fluids are indistinguishable from those of bottom seawater; however, concentrations of Rb, Mo, V, U, Mg, phosphate, Si and Li are different. Applying these observed differences to calculated global CHS fluxes results in chemical fluxes for these ions that are ≥15% of riverine fluxes. Fluxes of K and B also may be significant, but better analytical resolution is required to confirm this result. Spring fluids also have ∼50% less dissolved oxygen (DO) than bottom seawater. Calculations of an analytical model suggest that the loss of DO occurs primarily (>80%) within the upper basaltic crust by biotic and/or abiotic consumption. This calculation demonstrates that permeable pathways within the upper crust can support oxic water-rock interactions for millions of years.

  15. Geochemical effects of electro-osmosis in clays

    KAUST Repository

    Loch, J. P. Gustav

    2010-02-13

    Geochemical effects of electro-osmosis in bentonite clay are studied in the laboratory, where a 6 mm thick bentonite layer is subjected to direct current. Acidification and alkalization near anode and cathode are expected, possibly causing mineral deterioration, ion mobilization and precipitation of new solids. Afterwards the clay is analysed by XRF and anolyte and catholyte are analysed by ICP-MS. In addition, as a preliminary experiment treated bentonite is analysed by high resolution μ-XRF. Electro-osmotic flow is observed. Due to its carbonate content the bentonite is pH-buffering. Alkalization in the catholyte is substantial. Ca, Na and Sr are significantly removed from the clay and accumulate in the catholyte. Recovery in the catholyte accounts for a small fraction of the element-loss from the clay. The rest will have precipitated in undetected solid phases. μ-XRF indicates the loss of Ca-content throughout the bentonite layer. © The Author(s) 2010.

  16. MINTEQ2 geochemical code: provisionary organic data base

    International Nuclear Information System (INIS)

    Morrey, J.R.; Krupka, K.M.; Dove, F.H.

    1985-10-01

    Organic components in aqueous radioactive chemical sources, surface waters, and ground waters could substantially alter the mobility of radioactive and other important nonradioactive elements released from a defense waste disposal system. It is therefore important to be able to predict, as accurately as possible, the effects of selected organic components on the solubilities of radionuclides and important nonradioactive elements. The geochemical code MINTEQ2 can be used to assess solubilities provided that appropriate thermochemical data for organic and inorganic aqueous species and solids are available for its use. The code accepts an assemblage of gaseous and solid phases in contact with an aqueous phase and calculates the thermochemical equilibrium between these phases. Unlike typical hydrologic flow and transport codes where the data base is entirely site specific (i.e., parameters particular to the specific site), MINTEQ2 requires an additional generic thermochemical data base. This report discusses the addition of provisionary organic reactions and associated equilibrium constants to the generic data base that can be used by MINTEQ2 in scoping calculations or preliminary performance assessments

  17. Evaporation of J13 water: laboratory experiments and geochemical modeling

    International Nuclear Information System (INIS)

    Dibley, M.J.; Knauss, K.G.; Rosenberg, N.D.

    1999-01-01

    We report results from experiments on the evaporative chemical evolution of synthetic J13 water, representative of water from well J13, a common reference water in the Yucca Mountain Project. Data include anion and cation analysis and qualitative mineral identification for a series of open system experiments, with and without crushed tuff present, conducted at sub-boiling temperatures. Ca and Mg precipitated readily as carbonates and anions Cl, F, NO 3 and SO 4 remained in solution in nearly identical ratios. The pH stabilized at about 10. After ∼ 1000x concentration, the minerals formed were amorphous silica, aragonite and calcite. The presence of tuff appears to have very little effect on the relative distribution of the anions in solution, except for possibly F, which had a relatively lower concentration ratio. The Si was lower in the solutions with tuff present suggesting that the tuff enhances SiO 2 precipitation. Even though the tools to model highly-concentrated salt solutions are limited, we compare our experimental results with the results of geochemical models, with (perhaps) surprising good results. In response to different assumed CO 2 levels, pH varied, but anion concentrations were not greatly affected

  18. Uranium(VI) transport modeling: geochemical data and submodels

    International Nuclear Information System (INIS)

    Tripathi, V.S.

    1984-01-01

    Understanding the geochemical mobility of U(VI) and modeling its transport is important in several contexts including ore genesis, uranium exploration, nuclear and mill-tailings waste management, and solution mining of uranium ores. Adsorption is a major control on partitioning of solutes at the mineral/solution interface. The effect of carbonate, fluoride, and phosphate complexing on adsorption of uranium was investigated. A critical compilation of stability constants of inorganic complexes and solid compounds of U(VI) necessary for proper design of experiment and for modeling transport of uranium was prepared. The general features of U(VI) adsorption in ligand-free systems are similar to those characteristic of other hydrolyzable metal ions. The adsorption processes studied were found to be reversible. The adsorption model developed in ligand-free systems, when solution complexing is taken into account, proved remarkably successful in describing adsorption of uranium in the presence of carbonate and fluoride. The presence of phosphate caused a much smaller decrease in the extent of adsorption than expected; however, a critical reassessment of the stability of UO 2 2+ .HPO 4 2- complexes, showed that phosphato complexes, if any, are extremely weak under experimental conditions. Removal of uranium may have occurred due to precipitation of sodium uranyl phosphates in addition to adsorption

  19. New geochemical investigations in Platanares and Azacualpa geothermal sites (Honduras)

    Science.gov (United States)

    Barberi, Franco; Carapezza, Maria Luisa; Cioni, Roberto; Lelli, Matteo; Menichini, Matia; Ranaldi, Massimo; Ricci, Tullio; Tarchini, Luca

    2013-05-01

    Platanares and Azacualpa geothermal sites of Honduras are located in an inner part of the Caribbean Plate far from the active volcanic front of Central America. Here geology indicates that there are not the conditions for the occurrence of shallow magmatic heat sources for high-enthalpy geothermal resources. Geothermal perspectives are related to the possibility of a deep circulation of meteoric water along faults and the storage of the heated fluid in fractured permeable reservoirs. Geochemical geothermometers indicate a temperature for the deeper part of the geothermal reservoir close to 200 °C for Platanares and of 150-170 °C for Azacualpa. Calcite scaling, with subordinate silica deposition has to be expected in both sites. CO2 soil flux investigations have been carried out in both areas and reveal the presence of positive anomalies likely corresponding to the presence at depth of fractured degassing geothermal reservoirs. Compared with the geothermal areas of Central Italy whose reservoirs are hosted in carbonate rocks, e.g. Latera (Chiodini et al., 2007), the CO2 soil flux measured in Honduras is significantly lower (mean of 17 g/m2day at Platanares and of 163 g/m2day at Azacualpa) probably because of the dominant silicate nature of the deep reservoirs.

  20. Alaska Geochemical Database - Mineral Exploration Tool for the 21st Century - PDF of presentation

    Science.gov (United States)

    Granitto, Matthew; Schmidt, Jeanine M.; Labay, Keith A.; Shew, Nora B.; Gamble, Bruce M.

    2012-01-01

    The U.S. Geological Survey has created a geochemical database of geologic material samples collected in Alaska. This database is readily accessible to anyone with access to the Internet. Designed as a tool for mineral or environmental assessment, land management, or mineral exploration, the initial version of the Alaska Geochemical Database - U.S. Geological Survey Data Series 637 - contains geochemical, geologic, and geospatial data for 264,158 samples collected from 1962-2009: 108,909 rock samples; 92,701 sediment samples; 48,209 heavy-mineral-concentrate samples; 6,869 soil samples; and 7,470 mineral samples. In addition, the Alaska Geochemical Database contains mineralogic data for 18,138 nonmagnetic-fraction heavy mineral concentrates, making it the first U.S. Geological Survey database of this scope that contains both geochemical and mineralogic data. Examples from the Alaska Range will illustrate potential uses of the Alaska Geochemical Database in mineral exploration. Data from the Alaska Geochemical Database have been extensively checked for accuracy of sample media description, sample site location, and analytical method using U.S. Geological Survey sample-submittal archives and U.S. Geological Survey publications (plus field notebooks and sample site compilation base maps from the Alaska Technical Data Unit in Anchorage, Alaska). The database is also the repository for nearly all previously released U.S. Geological Survey Alaska geochemical datasets. Although the Alaska Geochemical Database is a fully relational database in Microsoft® Access 2003 and 2010 formats, these same data are also provided as a series of spreadsheet files in Microsoft® Excel 2003 and 2010 formats, and as ASCII text files. A DVD version of the Alaska Geochemical Database was released in October 2011, as U.S. Geological Survey Data Series 637, and data downloads are available at http://pubs.usgs.gov/ds/637/. Also, all Alaska Geochemical Database data have been incorporated into

  1. Evaluation of uranium geochemical anomalies in the Charlotte 10 x 20 NTMS quadrangle

    International Nuclear Information System (INIS)

    Carpenter, R.H.

    1981-11-01

    This report contains a synthesis of published geological, geophysical, and geochemical information for portions of Cabarrus and Rowan Counties, NC, where uranium geochemical anomalies have been described by Heffner and Ferguson (1978). The results of a ground radiation survey in selected areas are also described. Based on an evaluation of published information and the data obtained in the field study, conclusions are made regarding the possible occurrence of uranium concentration. Recommendations for detailed surveys in certain areas are also presented

  2. Applications of geochemical modeling to site characterization and radionuclide transport in the NNWSI project

    International Nuclear Information System (INIS)

    Kerrisk, J.F.

    1985-01-01

    The Nevada Nuclear Waste Storage Investigations project (NNWSI) is studying a site at Yucca Mountain, in southern Nevada, as a possible nuclear waste repository. Los Alamos National Laboratory is responsible for the geochemical aspects of site characterization at Yucca Mountain. Geochemical models are being used in site characterization to help understand (a) local water chemistry, (b) local mineralogy, (c) the relation between water chemistry and mineralogy, and (d) the effects of water chemistry and mineralogy on waste-element solubility and transport

  3. Comparison of results analyzed by Chinese and European laboratories for FOREGS geochemical baselines mapping samples

    Directory of Open Access Journals (Sweden)

    Wensheng Yao

    2011-04-01

    This study demonstrates that consistent analytical data for certain elements of global geochemical mapping samples can be achieved by different qualified laboratories, such as China’s IGGE laboratory and some European laboratories. For some elements, such as Ag, further research on the selection of the proper analytical methods and on the development of quality control methods should be undertaken — with final recommendations adhered to by all participants of the global geochemical mapping program.

  4. Environmental and geochemical assessment of surface sediments on irshansk ilmenite deposit area

    Directory of Open Access Journals (Sweden)

    Наталия Олеговна Крюченко

    2015-03-01

    Full Text Available It is revealed the problem of pollution of surface sediments of Irshansk ilmenite deposit area of various chemical elements hazard class (Mn, V, Ba, Ni, Co, Cr, Mo, Cu, Pb, Zn. It is determined its average content in surface sediments of various functional areas (forest and agricultural land, flood deposits, reclaimed land, calculated geochemical criteria, so given ecological and geochemical assessment of area

  5. Geochemical translocation of thallium in the sediments from the North River, China

    Science.gov (United States)

    Liu, J.

    2016-12-01

    Thallium (Tl) is a highly toxic rare heavy metal. As a sulphophile element, it usually occurs in numerous sulphide minerals (such as pyrite, galena, sphlerite). Guangdong north region, known as the hometown of nonferrous metals, has abundant containing Tl mineral resources. Numerous industrial activities, such as mining, smelting, and electroplating are also flourishing. In 2010, a serious Tl pollution in the North River (a major river in the Northern Guangdong Province) shocked the society. The Tl pollution in water appeared to be under control after that incident. But in fact, even if the wastewater discharge of pollution sources has been controlled, the potential risk of heavy metal pollution in the sediments of the North River still exists, for the metals are easy to precipitate and accumulate into sediment from water. So far, Tl pollution in sediments has been studied to a very limited extent. In this paper, we investigated the content and vertical distribution characteristics of Tl and some other related heavy metals in a typical sediment profile from the North River by using inductively coupled plasma mass spectrometry (ICP-MS). Then the Pb isotopic compositions in the sediments were measured by using multi-inductively coupled plasma mass spectrometry (MC-ICP-MS). Several sediments from typical layers were also subjected to sequential extraction procedure for investigating the geochemical fractions of Tl. The risk of Tl and other metal pollution was finally assessed by calculating geo-accumulation indexes (Igeo) and potential ecological risk. The results showed that: (1) Tl concentrations range 1.03 mg/kg to 3.13 mg/kg with a mean of 1.89 mg/kg, three times higher than that in local background soil; (2) Tl content generally increased with depth with some fluctuations and significant correlations were found between Tl and Pb, Zn, Cd, Cu, and Ni; (3) About 46 % to 70 % in sediment cores were resided in the residual fraction; (4) Igeo showed that the studied

  6. Metagenomic and geochemical characterization of pockmarked sediments overlaying the Troll petroleum reservoir in the North Sea.

    Science.gov (United States)

    Håvelsrud, Othilde Elise; Haverkamp, Thomas H A; Kristensen, Tom; Jakobsen, Kjetill S; Rike, Anne Gunn

    2012-09-11

    Pockmarks (depressions in the seabed) have been discovered throughout the world's oceans and are often related to hydrocarbon seepage. Although high concentrations of pockmarks are present in the seabed overlaying the Troll oil and gas reservoir in the northern North Sea, geological surveys have not detected hydrocarbon seepage in this area at the present time. In this study we have used metagenomics to characterize the prokaryotic communities inhabiting the surface sediments in the Troll area in relation to geochemical parameters, particularly related to hydrocarbon presence. We also investigated the possibility of increased potential for methane oxidation related to the pockmarks. Five metagenomes from pockmarks and plain seabed sediments were sequenced by pyrosequencing (Roche/454) technology. In addition, two metagenomes from seabed sediments geologically unlikely to be influenced by hydrocarbon seepage (the Oslofjord) were included. The taxonomic distribution and metabolic potential of the metagenomes were analyzed by multivariate analysis and statistical comparisons to reveal variation within and between the two sampling areas. The main difference identified between the two sampling areas was an overabundance of predominantly autotrophic nitrifiers, especially Nitrosopumilus, and oligotrophic marine Gammaproteobacteria in the Troll metagenomes compared to the Oslofjord. Increased potential for degradation of hydrocarbons, especially aromatic hydrocarbons, was detected in two of the Troll samples: one pockmark sample and one from the plain seabed. Although presence of methanotrophic organisms was indicated in all samples, no overabundance in pockmark samples compared to the Oslofjord samples supports no, or only low level, methane seepage in the Troll pockmarks at the present time. Given the relatively low content of total organic carbon and great depths of hydrocarbon containing sediments in the Troll area, it is possible that at least part of the carbon

  7. Geochemical processes in a calcareous sandstone aquifer during managed aquifer recharge with desalinated seawater

    Science.gov (United States)

    Ganot, Yonatan; Russak, Amos; Siebner, Hagar; Bernstein, Anat; Katz, Yoram; Guttman, Jospeh; Kurtzman, Daniel

    2017-04-01

    In the last three years we monitor Managed Aquifer Recharge (MAR) of post-treated desalinated seawater (PTDES) in an infiltration pond, at the Menashe site that overlies the northern part of the Israeli Coastal Aquifer. The PTDES are stabilized with CaCO3 during post-treatment in the desalination plant and their chemical composition differs from those of any other water recharged to the aquifer and of the natural groundwater. We use suction cups in the unsaturated zone, shallow observation wells within the pond and production wells that encircles the MAR Menashe site, to study the geochemical processes during MAR with PTDES. Ion-enrichment (remineralization) of the recharged water was observed in both unsaturated zone and shallow observation wells samples. Enrichment occurs mainly in the first few meters below the pond surface by ion-exchange processes. Mg2+ enrichment is most prominent due to its deficiency in the PTDES. It is explained by ion-exchange with Ca2+, as the PTDES (enriched with Ca2+) infiltrates through a calcareous-sandstone aquifer with various amount of adsorbed Mg2+ (3-27 meq/kg). Hence, the higher concentration of Ca+2 in the PTDES together with its higher affinity to the sediments promotes the release of Mg2+ ions to the recharged water. Water isotopes analysis of the production wells were used to estimate residence time and mixing with local groundwater. At the end of 2016, it was found that the percentage of PTDES in adjacent down-gradient production wells was around 10%, while more distant or up-gradient wells show no mixing with PTDES. The distinct isotope contrast between the recharged desalinated seawater (δ2H=+11.2±0.2‰) and the local groundwater (δ2H ranged from -22.7 to -16.7‰) is a promising tool to evaluate future mixing processes at the Menshae MAR site. Using the Menashe MAR system for remineralization could be beneficial as a primary or complementary post-treatment technique. However, the sustainability of this process is

  8. High-resolution geochemical record of Petaluma Marsh from the San Francisco bay area

    Science.gov (United States)

    Fard, E.; Brown, L. N.; MacDonald, G. M.

    2017-12-01

    The San Francisco Bay has the largest concentration of salt marshes in the state of California, representing a diversity of marsh habitat. Protecting these environments is critical, as salt marshes provide refuge to endangered species, absorb carbon from the atmosphere, and preserve detailed evidence of past climatic, hydrologic, geomorphic, and ecologic conditions. However, much of the marshes have been impacted by pollutants, altered or lost entirely due to human activity over the past 150 years, making their prehistoric conditions, ecological trajectories and resilience to disturbance uncertain. In this study, we collected data from Petaluma Marsh, one of the oldest marshes in the Bay Area, to document the sedimentological and accretionary history, geochemical changes including heavy metal concentrations, and patterns and shifts in productivity and C sequestration as a response to climatic and anthropogenic changes since the mid-Holocene. Loss-on ignition, pXRF, and magnetic susceptibility data were collected at high resolution from a 12-meter, 6000 year old, sedimentary core recovered from this tidal marsh located along the Petaluma river in the northern Bay region. Average rate of sediment accretion was 3.6 ± 0.8 mm/yr. Preliminary results confirm dramatic anthropogenic impacts on the Petaluma watershed, particularly over the last 150-200 years. However, based on statistical time-series analysis of long-core elemental concentrations, results show that modern conditions are not so far removed compared to prehistoric conditions, as often suggested by century-scale analyses. Modern heavy metal concentrations (e.g., Cr, Fe, Sr, Ba, Zr, Rb and Ni) match concentration levels from 4000-5000 yr BP. However, Pb levels in the marsh post-European land use are higher now than ever before. Average carbon content, as determined from LOI (Craft, 1991), is 22.3 ± 7.5 % over the length of the core, but decreased with European land modification and increased in recent years

  9. Comparison of Magnetic, Geochemical and Biological Proxies Signals in a ca. 2,000 yr Record from the Tropical Lowlands of Eastern Mexico.

    Science.gov (United States)

    Caballero, M.; Beatriz, O.; Ma. Del Socorro, L.; Rodríguez, A.

    2007-05-01

    Pollen, diatoms, geochemical, magnetic and non-magnetic mineral analyses were conducted on a lacustrine sequence from a maar lake on the tropical lowlands of eastern Mexico. Chronological framework for this lake is based on age determinations by 210-Pb, 137-Cs and 14-C. The studied sequence covers the last ca. 2000 yr, a time of important environmental transformations in the area due to climatic variability as well as human impact since the early Olmec societies until the recent forest clearance of the 20th century. Through these analyses we investigated the processes that affected the magnetic mineralogy in order to construct a model of past environmental changes, and compare it with the biological proxy records (diatoms and pollen) and the archeological record. Inferred climatic changes for this area are further compared with the documented climatic changes in the northern hemisphere of tropical America. Volcanic activity has played a major influence on sediment magnetic properties, as a purveyor of Ti-magnetites/Ti-maghemites, and as a factor of instability in the environment. Moisture availability has been determinant for the diatom and pollen records, and human impact is mostly reflected in the pollen and geochemical records. Direct observations of magnetic minerals and ratios of geochemical (Fe, Ti), and ferrimagnetic (χ f ) and paramagnetic (χ p) susceptibility (χ) data, are used as parameters for magnetite dissolution (χ p/χ, Fe/χ f ), and precipitation (χ f/Ti) of magnetic minerals. Evidence of agricultural practices associated with increased erosion, deforestation, higher evaporation rates, lower lake levels, anoxia and reductive diagenesis in non-sulphidic conditions are inferred for laminated sediments between A.D. 20-850. This deposit matches the period of historical crisis and multiyear droughts that contributed to the collapse of the Maya civilization. Dissolution of magnetite, a high organic content, framboidal pyrite and a change in the

  10. On the application of contemporary bulk sediment organic carbon isotope and geochemical datasets for Holocene sea-level reconstruction in NW Europe

    Science.gov (United States)

    Wilson, Graham P.

    2017-10-01

    Bulk organic stable carbon isotope (δ13C) and element geochemistry (total organic carbon (TOC) and organic carbon to total nitrogen (C/N)) analysis is a developing technique in Holocene relative sea-level (RSL) research. The uptake of this technique in Northern Europe is limited compared to North America, where the common existence of coastal marshes with isotopically distinctive C3 and C4 vegetation associated with well-defined inundation tolerance permits the reconstruction of RSL in the sediment record. In Northern Europe, the reduced range in δ13C values between organic matter sources in C3 estuaries can make the identification of elevation-dependent environments in the Holocene sediment record challenging and this is compounded by the potential for post-depositional alteration in bulk δ13C values. The use of contemporary regional δ13C, C/N and TOC datasets representing the range of physiographic conditions commonly encountered in coastal wetland sediment sequences opens up the potential of using absolute values of sediment geochemistry to infer depositional environments and associated reference water levels. In this paper, the application of contemporary bulk organic δ13C, C/N and TOC to reconstruct Holocene RSL is further explored. An extended contemporary regional geochemical dataset of published δ13C, C/N and TOC observations (n = 142) from tidal-dominated C3 wetland deposits (representing tidal flat, saltmarsh, reedswamp and fen carr environments) in temperate NW Europe is compiled, and procedures implemented to correct for the 13C Suess effect on contemporary δ13C are detailed. Partitioning around medoids analysis identifies two distinctive geochemical groups in the NW European dataset, with tidal flat/saltmarsh and reedswamp/fen carr environments exhibiting characteristically different sediment δ13C, C/N and TOC values. A logistic regression model is developed from the NW European dataset in order to objectively identify in the sediment record

  11. Role of geochemical background at evaluation of investment attractiveness of recreational territories

    Directory of Open Access Journals (Sweden)

    Vdovina Ol'ga Konstantinovna

    2014-09-01

    Full Text Available The article shows the role of natural geochemical background when estimating investment attractiveness of recreational areas. It is noted, that geochemical background influence on people's sickness rate isn't considered now. Though it's understood, that even insignificant increase of geochemical background in relation to percentage abundance of Earth crest may lead to endemic diseases of people, animals and plants. An indicator of geochemical endemicity areas was proposed for assessing the impact of storage elements and of a lack of geological environment on human health. Thanks to this measure, and taking into account landscape features of the area, the authors allocated lands, dangerous and potentially dangerous in terms of endemicity. The importance of ratings was achieved by the use of those factors that could have a great influence on the cost of land development. This includes, first of all, the factors that affect population health, and economic and geographic factors that minimize the cost of the territory development and the factors that give rise to financial risks and risks of human losses. The main risk factors include: potential ecological and geochemical risk; high absolute heights, development and activity of dangerous geological processes and phenomena. Systemacity of researches was reached by using factors, that characterize the object from different aspects; readiness of area infrastructure to its exploration and possible risks. Objectivity was achieved by the use of figures obtained from the results of geochemical and engineering surveys with their metrological support.

  12. Reconnaissance of Macondo-1 well oil in sediment and tarballs from the northern Gulf of Mexico shoreline, Texas to Florida

    Science.gov (United States)

    Rosenbauer, Robert J.; Campbell, Pamela L.; Lam, Angela; Lorenson, T.D.; Hostettler, Frances D.; Thomas, Burt; Wong, Florence L.

    2010-01-01

    Hydrocarbons were extracted and analyzed from sediment and tarballs collected from the northern Gulf of Mexico (nGOM) coast that is potentially impacted by Macondo-1 (M-1) well oil. The samples were analyzed for a suite of diagnostic geochemical biomarkers. Aided by multivariate statistical analysis, the M-1 well oil has been identified in sediment and tarballs collected from Louisiana, Alabama, Mississippi, and Florida. None of the sediment hydrocarbon extracts from Texas correlated with the M-1 well oil. Oil-impacted sediments are confined to the shoreline adjacent to the cumulative oil slick of the Deepwater Horizon oil spill, and no impact was observed outside of this area.

  13. Geological and geochemical data for seamounts and associated ferromanganese crusts in the Ratak Chain, Marshall Islands

    Science.gov (United States)

    Schwab, W.C.; Hein, J.R.; Davis, A.S.; Morgenson, L.A.; Daniel, C.L.; Haggerty, J.A.

    1986-01-01

    In 1984, the U.S. Geological Survey (USGS) conducted a reconnaissance cruise L9-84-CP aboard the R/V S.P. LEE along the northern Ratak Ridge, Marshall Islands (Fig. 1). Preliminary geochemical results from the cruise show that ferromanganese crusts (Mn crusts) on the submarine slopes of seamounts, and islands may have potential for commercial exploitation (Schwab and others, 1985). In this report we present shipboard data and laboratory analyses for rock samples collected on cruise L9-84-CP. This report should supplement the reports of Schwab and Bailey (1985) and Schwab and others (1985). A total of 5410 km of 12-kHz and 3.5-kHz seismic-reflection data, and q O 730 km of 80-in3 and 148-in3 airgun seismic-reflection data were collected on cruise L9-84-CP (Schwab and Bailey, 1985). Eighteen sample stations were occupied; 13 dredge hauls and 3 box cores were collected (Table 1). These samples are available at the USGS Branch of Pacific Marine Geology offices in Menlo Park, California. Data presented in this report should encourage a more extensive field investigation and serious economic and technical evaluation of Mn crusts within the Marshall Islands area. Ferromanganese-oxide precipitates that encrust hard substrate on the submarine flanks of seamounts, guyots, atolls, islands, and linear volcanic ridges, have been known for several decades (Cronan, 1977; Frazer and Fisk, 1980) but were not studied in a systematic way until the West German MIDPAC expedition of 1981 (Halbach and others, 1982). Unlike abyssal ferromanganese nodules, Mn crusts contain higher concentrations of the economically attractive metals, cobalt and platinum (Toth, 1980; Craig and others, 1982; Halbach and others, 1984; Hein and others, 1985). Mn crusts are predominantly hydrogenous in origin, in contrast to abyssal ferromanganese nodules which also have a substantial diagenetic input (Halbach and others, 1981). In order for a Mn crust deposit to be economically attractive, it must be of high

  14. Geochemical Modeling Of F Area Seepage Basin Composition And Variability

    International Nuclear Information System (INIS)

    Millings, M.; Denham, M.; Looney, B.

    2012-01-01

    From the 1950s through 1989, the F Area Seepage Basins at the Savannah River Site (SRS) received low level radioactive wastes resulting from processing nuclear materials. Discharges of process wastes to the F Area Seepage Basins followed by subsequent mixing processes within the basins and eventual infiltration into the subsurface resulted in contamination of the underlying vadose zone and downgradient groundwater. For simulating contaminant behavior and subsurface transport, a quantitative understanding of the interrelated discharge-mixing-infiltration system along with the resulting chemistry of fluids entering the subsurface is needed. An example of this need emerged as the F Area Seepage Basins was selected as a key case study demonstration site for the Advanced Simulation Capability for Environmental Management (ASCEM) Program. This modeling evaluation explored the importance of the wide variability in bulk wastewater chemistry as it propagated through the basins. The results are intended to generally improve and refine the conceptualization of infiltration of chemical wastes from seepage basins receiving variable waste streams and to specifically support the ASCEM case study model for the F Area Seepage Basins. Specific goals of this work included: (1) develop a technically-based 'charge-balanced' nominal source term chemistry for water infiltrating into the subsurface during basin operations, (2) estimate the nature of short term and long term variability in infiltrating water to support scenario development for uncertainty quantification (i.e., UQ analysis), (3) identify key geochemical factors that control overall basin water chemistry and the projected variability/stability, and (4) link wastewater chemistry to the subsurface based on monitoring well data. Results from this study provide data and understanding that can be used in further modeling efforts of the F Area groundwater plume. As identified in this study, key geochemical factors affecting basin

  15. Predictive Analysis of Geochemical Controls in an Alpine Stream

    Science.gov (United States)

    Jochems, A. P.; Sherson, L. R.; Crossey, L. J.; Karlstrom, K. E.

    2010-12-01

    Alpine watersheds are increasingly relied upon for use in the American West, necessitating a more complete understanding of annual hydrologic patterns and geologic influences on water chemistry. The Jemez River is a fifth order stream in central New Mexico that flows from its source in the Jemez Mountains to its confluence with the Rio Grande north of the town of Bernalillo. Designated uses of the Jemez River include domestic water supply, recreation, and agriculture. Geothermal uses are currently being considered as well. The river recharges shallow aquifer waters used by several communities, including tribal lands of the Jemez Pueblo. The hydrogeology of the Jemez system is characterized by geothermal inputs from the Baca hydrothermal system associated with the 1.2Ma Valles caldera, as well as groundwater and surface water interactions. Freshwater input from the Rio Guadalupe and several ephemeral tributaries also influences the water chemistry of the Jemez system. Fifteen sites along a 35 km reach of the river were sampled between 2006 and 2010. Discharge of the Jemez River ranged from 10-876 cfs over the study period. The annual hydrograph is affected by annual snowmelt in the Jemez Mountains as well as surges due to monsoonal rains in July and August. Geochemical data collected over this period include temperature, conductivity, pH, dissolved oxygen (D.O.), major ions, trace elements, and stable isotopes. Continuous records of temperature, conductivity, pH, D.O. and turbidity data were collected from a water quality sonde installed in March 2010. Geochemical modeling and time series analysis were performed using PHREEQC, Geochemist’s Workbench, and MATLAB. Empirical data collected during this study gave rise to several models describing the hydrology and geochemistry of the Jemez system. Our data suggest that springs are the primary contributors to dissolved load, and that solute loading from geothermal inputs is intensified by low flows observed on

  16. Comparison on humus and soil geochemical baselines in Southern Finland

    Science.gov (United States)

    Minolfi, Giulia; Tarvainen, Timo; Jarva, Jaana

    2016-04-01

    Humus has been recognized since a survey in 1977 (Allen and Steinnes, 1980) as one of the best sampling media for mapping regional environmental contamination because of the strong geochemical contrast between anomalous and background concentrations resulting from its capacity to accumulate high levels of trace metals. This study is in the framework of the comparison between humus, topsoil and moss deposition data, in order to analyze the humus behavior and to find possible similarities to underlying geology and long-range atmospheric deposition. The analyzed samples are part of a geochemical mapping programme carried out by the Geological Survey of Finland (GTK); subsoil, topsoil and humus samples have been collected in a large area in Southern Finland since 2002. 816 sample pairs (humus and topsoil samples) were selected for statistical analysis. Statistical graphs, like histograms, CP plots and box plots, were realized for 31 elements, and showed that most of the elements have completely different distribution of concentrations in humus and in topsoil samples. Then the correlation between the element concentrations in humus and minerogenic topsoil has been evaluated measuring the Spearman rank correlation value and elaborating scatter plots between the element concentrations in humus and minerogenic topsoil, and between the content of the element vs. the content of organic C. The concentrations of some elements, like K, Mg, Fe, Al, in humus samples are controlled by the content of mineral matter, derived by the soil dust. Other elements, such as As, Bi, Cd, Co, Cu, Mn, Mo, Ni, Pb, Rb, Th, V and Zn showed evident outliers, with probable anthropogenic origin. In order to explain these anomalous high values in humus, the geographic distributions of these elements in humus and topsoil were analyzed and then compared to the deposition data obtained by the national moss data. High values appear in areas where the anthropogenic impact is strong, like the Harjavalta

  17. Geochemical water signature in the Bahariya Depression, Western Desert, Egypt

    Science.gov (United States)

    Sciarra, Alessandra; Mazzini, Adriano; Lupi, Matteo; Hammed, Mohammed S.

    2017-04-01

    The Bahariya Oasis is located about 200 km SW of Cairo in the central part of the Western Desert of Egypt. It occupies a sub-elliptic 40 km wide depression stretching NE-SW for approximately 90 km. The Bahariya Oasis has been targeted for numerous geological studies on structural geology, stratigraphy, and iron ore deposits. The oasis was characterized since the Roman times by the presence of natural hydrothermal springs venting water from the relatively shallow Nubia Sandstone formation. Inside the depression are visible numerous circular concentric features that morphologically resemble the hydrothermal vent complexes observed at igneous provinces in other localities of the planet. In order to investigate the origin and the mechanisms of formation of these features, we conducted a fieldwork survey as well as fluids sampling from the available well sites. The aim was to constrain the origin of the fluids that potentially triggered or facilitated the formation of the concentric structures observed on the field. This study presents the geochemical results of groundwaters and soil gas samples. Ten samples were collected from deep wells present in the area. In particular, 8 warm waters were collected by wells between 800 m and 1200 m deep. The measured temperatures at these sites range from 36.5 °C to 52.3°C, while the coldest wells have temperatures ranging from 27.9 °C to 36.5°C. For each sample collected from the wells we analyzed the major, minor and trace elements, dissolved gases (He, Ne, H2, O2, N2, CH4, CO2, Rn), and relative isotopic values. In the areas around the wells we measured CO2 and CH4 fluxes as well as radon activity. Overall, the water showed a high value of dissolved Rn, ranging from 9 to 43 Bq/l, and dissolved CO2 ranging from 5.9 to 17.4 cc/l. The waters show a radiogenic signature of isotopic helium, highlighting very prolonged interaction with local crust enriched in radiogenic elements. The isotopic values of δ18O and δD show a clear

  18. SITE-94. Geochemical characterization of Simpevarp ground waters near the Aespoe Hard Rock Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Glynn, P.D.; Voss, C.I. [US Geological Survey, Reston, VA (United States)

    1999-09-01

    possible range of values that need to be considered. Tritium measurements confirm that the recent ground water type, originally identified on the basis of deuterium and chloride measurements, contains a significant proportion of recent, post-1950, water. Better tritium analyses, together with a greater number of carbon-13 analyses on dissolved inorganic carbon, would have helped interpret the carbon-14 analyses that were obtained primarily from relatively shallow ground waters (< 500 m depth). The SITE-94 Central Scenario climate model suggests that three glaciations may occur in the Northern Hemisphere during the next 120,000 years. If such glaciations do occur, possible climate-driven changes in ground-water geochemistry, particularly in redox conditions, could occur in the Fennoscandian shield. During two of these glaciations, 2- to3-km high ice sheets are predicted to form over the Fennoscandian shield, extending over Aespoe island and further south. Modeling of ground-water flow and transport suggests the possibility of deep and fast penetration of glacial melt waters during periods of glacial advance. The intruding melt waters have a median travel time of less than 100 years to 500 m depth. Ice composition data from the base of the Greenland ice sheet suggests that the melt waters will be highly enriched in dissolved oxygen, with concentrations at least 3 to 5 times higher than would be obtained at atmospheric equilibrium. The relative scarcity of fast-reacting pyrite in hydraulically conductive fractures, and the expected scarcity of organic carbon that would be exposed to the intruding melt waters, implies that Fe(II)-rich silicate minerals would be the primary reductants for the intruding dissolved oxygen. Current information suggests that the reaction rates would not be sufficiently fast to prevent penetration of oxygenated melt waters to a depth of at least 500 m. Despite clear evidence of past, deep, glacial meltwater penetration, convincing geochemical

  19. Geochemical Fate and Transport of Sildenafil and Vardenafil

    Science.gov (United States)

    Richter, L.; Boudinot, G.; Vulava, V. M.; Cory, W. C.

    2015-12-01

    The geochemical fate of pharmaceuticals and their degradation products is a developing environmental field. The geologic, chemical, and biological fate of these pollutants has become very relevant with the increase in human population and the resulting increase in pollutant concentrations in the environment. In this study, we focus on sildenafil (SDF) and vardenafil (VDF), active compounds in Viagra and Levitra, respectively, two commonly used erectile dysfunction drugs. The main objective is to determine the sorption potential and transport behavior of these two compounds in natural soils. Both SDF and VDF are complex organic molecules with multiple amine functional groups in their structures. Two types of natural acidic soils (pH≈4.5), an organic-rich soil (7.6% OM) and clay-rich soil (5.1% clay) were used in this study to determine which soil components influence sorption behavior of both compounds. Sorption isotherms measured using batch reactors were nearly linear, but sorption was stronger in soil that contained higher clay content. Both compounds have multiple pKas due to the amine functional groups, the relevant pKas of SDF are 5.97 and 7.27, and those of VDF's are 4.72 and 6.21. These values indicate that these compounds likely behave as cations in soil suspensions and hence were strongly sorbed to negatively-charged clay minerals present in both soils. The clay composition in both soils is predominantly kaolinite with smaller amount of montmorillonite, both of which have a predominantly negative surface charge. Transport experiments using glass chromatography columns indicated that both compounds were more strongly retarded in the clay-rich soils. Breakthrough curves from the transport experiments were modeled using convection-dispersion transport equations. The organic matter in the soil seemed to play a less dominant role in the geochemistry in this study, but is likely to transform both compounds into derivative compounds as seen in other studies.

  20. Geochemical assessment of sediment in Cape Town harbour, South Africa

    Directory of Open Access Journals (Sweden)

    H. K. Okoro

    2014-01-01

    Full Text Available Geochemical assessment of marine sediments collected from Cape Town harbour was carried out using inductively coupled plasma-mass spectrometry, Fourier-Transform-infrared and X-ray diffractrometry techniques. The clay mineral phase consists of biotites, kaolinites and halites. The ranges of concentrations (mg/kg of trace metals were: Cd (1.69±0.075 – 0.080±0.002, Si (0.37±0.11 – 0.023±0.012, Fe (30.01±2.04 – 2.23±0.12, Cu (1462±39 – 1.51±0.11, Al (19.92±2.24 – 1.25±0.13, Sn (63.98±4.97 – 1.15±0.38, Pb (252±29 – 8.73±1.06, Hg (1.002±0.168 – 0.049±0.005 and Zn (1.26±0.07 – 0.022±0.004 mg kg-1. The enrichment factors of Sn, Pb, Zn, Fe, Cd, Al and Hg revealed anthropogenic inputs of these metals into the marine environment. The enrichment factor of Cu was less than 1 and this suggests that its presence was largely due to natural changes. The results are indications of the contributions of trace metals contained in the runoffs from the domestic and urban drains, as well as the inflow storm water. Ship repair activities appeared to constitute a major factor responsible for the higher metal contamination in the dockyard areas. The geomineral analyses revealed the presence of quartz, pyrite, and calcite and carrolite minerals as the main constituents of the marine sediments. DOI: http://dx.doi.org/10.4314/bcse.v28i1.3

  1. Geochemical interpretation of Kings Mountain, North Carolina, orientation area

    International Nuclear Information System (INIS)

    Price, V.; Ferguson, R.B.

    1977-01-01

    An orientation study has been made of uranium occurrences in the area of Kings Mountain, North Carolina. This is one of the orientation studies of known uranium occurrences that are being conducted in several geologic provinces and under various climatic (weathering) conditions to provide the technical basis for design and interpretation of NURE geochemical reconnaissance programs. The Kings Mountain area was chosen for study primarily because of the reported presence of high-uranium monazite. This 750-mi 2 area is in the deeply weathered southern Appalachian Piedmont and spans portions of the Inner Piedmont, Kings Mountain, and Charlotte geologic belts. Uranium concentration maps for ground and surface water samples clearly outline the outcrop area of the Cherryville Quartz Monzonite with highs up to 10 ppb uranium near the reported uraninite. Several surface water samples appear to be anomalous because of trace industrial contamination. Uranium concentration maps for -100 to +200 mesh stream sediments indicate the area of monazite abundance. Several samples with >100 ppM uranium content appear to be high in uranium-rich resistate minerals. When the uranium content of sediment samples is ratioed to the sum of Hf, Dy, and Th, the anomaly pattern shifts to coincide with uranium highs in ground and surface water samples. False anomalies from concentrations of monazite (Ce,ThPO 4 ), xenotime (Y,DyPO 4 ), and zircon (Zr,HfSiO 4 ) in stream sediment samples can thus be eliminated. Residual anomalies should be related to unusual uranium enrichment of these common minerals or to the presence of an uncommon uranium-rich mineral. Tantalum, beryllium, and tin in stream sediments correspond to high concentrations of uranium in stream and ground water but not to uranium in sediments. In an initial reconnaissance, several media should be sampled, and it is essential to correct uranium in sediments for the sample mineralogy

  2. The Alto Paraguay Alkaline Province: petrographic, geochemical and geochronological characteristics

    International Nuclear Information System (INIS)

    Velazquez Fernandez, Victor

    1996-01-01

    The Alto Paraguay Province is located at the border of the State of Mato Grosso do Sul and Paraguay, between the coordinates 21 deg 10 ' to 23 deg 25 ' of Southern latitude and 57 deg 10 ' to 58 deg 00 ' , having the city of Porto Murtinho as the main reference point. The geotectonic domain of the area is governed by the precambric units of the Southern extreme of the Amazonic craton which developed a long and accentuated activity, giving rise to folds and important faults, that in several cases seem to have exerted an effective control of the magmatic manifestations. Radiometric data indicate that the emplacement of the syenitic bodies took place in the Permo-Triassic period, with a major incidence in the interval 260-240 Ma, representing thus, an important phase of alkaline magmatic affinity associated to the Parana Basin which is believed is to be unique, since the other known areas (Central, Amambay and Rio Apa Provinces, Paraguay, Velasco Province, Bolivia) are considerably younger (140-120 Ma). Syenitic rocks from the Alto Paraguay Province show wide variation in the ratio 87 Sr/ 86 Sr (0.703361 - 0.707734). Excluding the Cerro Boggiani rocks (0.703837-0.707734), values for the nepheline syenites (0.703361-0.703672) general lower than those of the other syenites types. Alkaline syenites cover the interval 0.703510- 0.703872, while quartz syenites and syenogranites are 0.704562 and 0.707076, respectively. geologic evidence, in addition to petrographic, geochemical and isotopic (Sr) data, suggest that the syenitic rocks have been derived from an unique mantelic parental liquid, by fractional crystallization and assimilation processes, which are assumed to be occurred during the emplacement of the magma in the crust. (author)

  3. Barnacles - recorders of environmental conditions with unique geochemical signatures

    Science.gov (United States)

    Vinzenz Ullmann, Clemens; Gale, Andy; Korte, Christoph; Frei, Robert; Huggett, Jenny; Wray, Dave

    2017-04-01

    Barnacles are calcite-forming arthropods that occur in a wide range of habitats in modern times and are found in sedimentary successions reaching back to the Paleozoic. Despite potential use of their mostly low-Mg calcite hard parts for palaeoenvironmental reconstructions, their geochemical composition has been little studied. Here, we present the first comprehensive overview of barnacle geochemistry, with C and O isotope, as well as Mg/Ca, Sr/Ca, Mn/Ca and Fe/Ca data for multiple samples of 42 species covering the orders Sessilia, Scalpelliformes, and Lepadiformes. XRD analyses confirm calcite as the only significant carbonate mineral of the studied barnacle shell material. Apart from one species, median Mg/Ca ratios fall below 50 mmol/mol, the approximate limit for low-Mg-calcite. In the order Sessilia, the scuta and terga are on average enriched in Mg by 36 % over the unmoveable plates. Amongst the calcite-forming marine animals, barnacles have very high Sr/Ca ratios of 2.6 to 5.9 mmol/mol, amongst the highest known for calcite secreting animals. Mn/Ca and Fe/Ca ratios are commonly low and compatible with other modern shell calcite, but can be strongly enriched to > 1 mmol/mol in proximal habitats, particularly close to areas strongly affected by human activity. Carbon and oxygen isotope data indicate formation of the calcite in or near isotopic equilibrium with ambient water conditions. Apart from species showing δ18O values below 0 ‰ V-PDB, a negative correlation of oxygen isotope ratios with Sr/Ca ratios is observed, which may be related to metabolic activity. Compositional patterns in barnacle shell material, particularly high Sr concentrations and Mg distribution in shell plates of the Sessilia, point to a great potential of barnacles for high fidelity reconstruction of past seawater chemistry and environmental conditions complementary to other archives.

  4. A Mobile App for Geochemical Field Data Acquisition

    Science.gov (United States)

    Klump, J. F.; Reid, N.; Ballsun-Stanton, B.; White, A.; Sobotkova, A.

    2015-12-01

    We have developed a geochemical sampling application for use on Android tablets. This app was developed together with the Federated Archaeological Information Management Systems (FAIMS) at Macquarie University and is based on the open source FAIMS mobile platform, which was originally designed for archaeological field data collection. The FAIMS mobile platform has proved valuable for hydrogeochemical, biogeochemical, soil and rock sample collection due to the ability to customise data collection methodologies for any field research. The module we commissioned allows for using inbuilt or external GPS to locate sample points, it incorporates standard and incremental sampling names which can be easily fed into the International Geo-Sample Number (IGSN). Sampling can be documented not only in metadata, but also accompanied by photographic documentation and sketches. The module is augmented by dropdown menus for fields specific for each sample type and user defined tags. The module also provides users with an overview of all records from a field campaign in a records viewer. We also use basic mapping functionality, showing the current location, sampled points overlaid on preloaded rasters, and allows for drawing of points and simple polygons to be later exported as shape files. A particular challenge is the remoteness of the sampling locations, hundreds of kilometres away from network access. The first trial raised the issue of backup without access to the internet, so in collaboration with the FAIMS team and Solutions First, we commissioned a vehicle mounted portable server. This server box is constantly syncing with the tablets in the field via Wi-Fi, it has an uninterruptible power supply that can run for up to 45 minutes when the vehicle is turned off, and a 1TB hard drive for storage of all data and photographs. The server can be logged into via any of the field tablets or laptop to download all the data collected to date or to just view it on the server.

  5. The geochemical transformation of soils by agriculture and its dependence on soil erosion: An application of the geochemical mass balance approach.

    Science.gov (United States)

    Yoo, Kyungsoo; Fisher, Beth; Ji, Junling; Aufdenkampe, Anthony; Klaminder, Jonatan

    2015-07-15

    Agricultural activities alter elemental budgets of soils and thus their long-term geochemical development and suitability for food production. This study examined the utility of a geochemical mass balance approach that has been frequently used for understanding geochemical aspect of soil formation, but has not previously been applied to agricultural settings. Protected forest served as a reference to quantify the cumulative fluxes of Ca, P, K, and Pb at a nearby tilled crop land. This comparison was made at two sites with contrasting erosional environments: relatively flat Coastal Plain in Delaware vs. hilly Piedmont in Pennsylvania. Mass balance calculations suggested that liming not only replenished the Ca lost prior to agricultural practice but also added substantial surplus at both sites. At the relatively slowly eroding Coastal Plain site, the agricultural soil exhibited enrichment of P and less depletion of K, while both elements were depleted in the forest soil. At the rapidly eroding Piedmont site, erosion inhibited P enrichment. In similar, agricultural Pb contamination appeared to have resulted in Pb enrichment in the relatively slowly eroding Coastal Plain agricultural soil, while not in the rapidly eroding Piedmont soils. We conclude that agricultural practices transform soils into a new geochemical state where current levels of Ca, P, and Pb exceed those provided by the local soil minerals, but such impacts are significantly offset by soil erosion. Copyright © 2015 Elsevier B.V. All rights reserved.

  6. Gas seepage in the Northern Adriatic Sea

    Science.gov (United States)

    Matilde Ferrante, Giulia; Donda, Federica; Volpi, Valentina; Tinivella, Umberta

    2017-04-01

    In the Northern Adriatic Sea, the occurrence of gas seepage has been widely documented. However, the origin of seeping gas was not clearly constrained. Geophysical data with different scale of resolution, i.e. multichannel seismic profiles, CHIRP and morpho-bathymetry data collected in 2009 and 2014 by OGS reveal that several the gas-enriched fluid vents are deeply rooted. In fact, the entire Plio-Quaternary succession is characterized by widespread seismic anomalies represented by wipe-out zones and interpreted as gas chimneys. They commonly root at the base of the Pliocene sequence but also within the Paleogene succession, where they appear to be associated to deep-seated, Mesozoic-to-Paleogene faults. These chimneys originate and terminate at different stratigraphic levels; they also commonly reach the seafloor, where rock outcrops interpreted as authigenic carbonate deposits have been recognized. In places, gas is then capable to escape in the water column as shown by numerous gas flares. On going studies are addressed to: 1. re-examining the structural setting of the study area, in order to verify a possible structural control on chimney distribution and gas migration; 2. performing geochemical analysis on gas which have been sampled in some key emission points; 3. a quantitative analysis of some selected boreholes well logs (made available through the public VidePi database (www.videpi.com)) aimed to estimate the amount of gas present in sediments. This work presents the preliminary results regarding the latter aspect of our research. In a first instance, for each selected borehole the geophysical logs have been digitized. This procedure consists in a manual picking of curves, in a set system of reference. Static corrections for vertical offset are made at this stage. Logs are then divided by type and converted in common scales, amplifications and units. Every log is resampled in order to cut high frequencies not useful in the comparison with seismic data

  7. Northern Eurasia Future Initiative (NEFI)

    DEFF Research Database (Denmark)

    Groisman, Pavel; Shugart, Herman; Kicklighter, David

    2017-01-01

    prepare societies for future developments. A key principle of NEFI is that these developments must now be secured through science-based strategies codesigned with regional decision-makers to lead their societies to prosperity in the face of environmental and institutional challenges. NEESPI scientific......During the past several decades, the Earth system has changed significantly, especially across Northern Eurasia. Changes in the socio-economic conditions of the larger countries in the region have also resulted in a variety of regional environmental changes that can have global consequences....... The Northern Eurasia Future Initiative (NEFI) has been designed as an essential continuation of the Northern Eurasia Earth Science Partnership Initiative (NEESPI), which was launched in 2004. NEESPI sought to elucidate all aspects of ongoing environmental change, to inform societies and, thus, to better...

  8. A geochemical study of the Ediacaran discoidal fossil Aspidella preserved in limestones: Implications for its taphonomy and paleoecology.

    Science.gov (United States)

    Bykova, N; Gill, B C; Grazhdankin, D; Rogov, V; Xiao, S

    2017-07-01

    The Ediacara biota features the rise of macroscopic complex life immediately before the Cambrian explosion. One of the most abundant and widely distributed elements of the Ediacara biota is the discoidal fossil Aspidella, which is interpreted as a subsurface holdfast possibly anchoring a frondose epibenthic organism. It is a morphologically simple fossil preserved mainly in siliciclastic rocks, which are unsuitable for comprehensive stable isotope geochemical analyses to decipher its taphonomy and paleoecology. In this regard, three-dimensionally preserved Aspidella fossils from upper Ediacaran limestones of the Khatyspyt Formation in the Olenek Uplift of northern Siberia offer a rare opportunity to leverage geochemistry for insights into their taphonomy and paleoecology. To take advantage of this opportunity, we analyzed δ 13 C carb , δ 18 O carb , δ 13 C org , δ 34 S pyr , and iron speciation of the Khatyspyt Aspidella fossils and surrounding sediment matrix in order to investigate whether they hosted microbial symbionts, how they were fossilized, and the redox conditions of their ecological environments. Aspidella holdfasts and surrounding sediment matrix show indistinguishable δ 13 C org values, suggesting they did not host and derive significant amount of nutrients from microbial symbionts such as methanogens, methylotrophs, or sulfide-oxidizing bacteria. δ 13 C carb , δ 18 O carb , and δ 34 S pyr data, along with petrographic observations, suggest that microbial sulfate reduction facilitated the preservation of Aspidella by promoting early authigenic calcite cementation in the holdfasts before matrix cementation and sediment compaction. Iron speciation data are equivocal, largely because of the low total iron concentrations. However, consideration of published sulfur isotope and biomarker data suggests that Aspidella likely lived in non-euxinic waters. It is possible that Aspidella was an opportunistic organism, colonizing the seafloor in large

  9. A geochemical approach for the evaluation of water availability and salinity in closed basins: the Draa Basin, Morocco

    Science.gov (United States)

    Warner, N.; Lgourna, Z.; Boutaleb, S.; Tagma, T.; Vinson, D. S.; Ettayfi, N.; Bouchaou, L.; Vengosh, A.

    2010-12-01

    In the sub-Saharan Draa Basin of southern Morocco, winter snowmelt from the Atlas Mountains is captured in a reservoir, stored, and discharged downstream for irrigation in six oases. The combined imported surface water and shallow groundwater exploitation for sustaining local agriculture is a common practice in many worldwide arid basins.. Like in many basins, the salinization of groundwater in the Draa Basin has become a limiting factor for agricultural development and long-term sustainability. .Since most of the IPCC climate models predict a significant decrease in precipitation in Northern Africa over the next few decades, water shortage and salinization induced from climate change are expected to exacerbate the existing water crisis. Evaluating the sources and mechanisms of this salinization can provide the necessary tools for sustainable water management in the Draa Basin that may be applied to many similarly arid basins. Here we present new geochemical results from 98 shallow groundwater and four surface water samples collected in May 2009 and April 2010. The samples were collected from upstream tributaries to the reservoir, the reservoir, and groundwater from in six oases downstream of the reservoir. The goal of the survey was to identify the sources of salinity using geochemical and isotopic (87Sr/86Sr, δ2H, and δ18O) signatures in the groundwater, which could derive from three possible sources (1) evaporation and recycling of the irrigation water; (2) dissolution of salts that were entrapped in the unsaturated zone; and (3) lateral flow of adjacent groundwater. The data show a large salinity range from fresh water to highly brackish water with total dissolved salts (TDS) exceeding 12,000 mg/L. The salinity increases with downstream flow between successive oases. Br/Cl and B/Cl ratios decrease with TDS, which suggests that the main mechanism of salinization in the Draa Basin is derived salt dissolution in the unsaturated zone and salinization of the

  10. Geochemical Data Package for Performance Assessment Calculations Related to the Savannah River Site

    Energy Technology Data Exchange (ETDEWEB)

    Kaplan, Daniel I. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2016-07-22

    The Savannah River Site (SRS) disposes of low-level radioactive waste (LLW) and stabilizes high-level radioactive waste (HLW) tanks in the subsurface environment. Calculations used to establish the radiological limits of these facilities are referred to as Performance Assessments (PA), Special Analyses (SA), and Composite Analyses (CA). The objective of this document is to revise existing geochemical input values used for these calculations. This work builds on earlier compilations of geochemical data (2007, 2010), referred to a geochemical data packages. This work is being conducted as part of the on-going maintenance program of the SRS PA programs that periodically updates calculations and data packages when new information becomes available. Because application of values without full understanding of their original purpose may lead to misuse, this document also provides the geochemical conceptual model, the approach used for selecting the values, the justification for selecting data, and the assumptions made to assure that the conceptual and numerical geochemical models are reasonably conservative (i.e., bias the recommended input values to reflect conditions that will tend to predict the maximum risk to the hypothetical recipient). This document provides 1088 input parameters for geochemical parameters describing transport processes for 64 elements (>740 radioisotopes) potentially occurring within eight subsurface disposal or tank closure areas: Slit Trenches (ST), Engineered Trenches (ET), Low Activity Waste Vault (LAWV), Intermediate Level (ILV) Vaults, Naval Reactor Component Disposal Areas (NRCDA), Components-in-Grout (CIG) Trenches, Saltstone Facility, and Closed Liquid Waste Tanks. The geochemical parameters described here are the distribution coefficient, Kd value, apparent solubility concentration, ks value, and the cementitious leachate impact factor.

  11. Geochemical evaluation of Niger Delta sedimentary organic rocks: a new insight

    Science.gov (United States)

    Akinlua, Akinsehinwa; Torto, Nelson

    2010-05-01

    A geochemical evaluation of Niger Delta organic matter was carried out using supercritical fluid extraction (SFE) sample preparation procedure. Comparison of geochemical significance of gas chromatographic data of rock extracts of SFE with those of Soxhlet extraction method from previous studies was made in order to establish the usefulness of SFE in geochemical exploration. The assessment of geochemical character of the rock samples from the comparison and interpretation of other geochemical parameters were used to give more insights into understanding the source rocks characteristics of onshore and shelf portions of the Niger Delta Basin. The results of the gas chromatographic (GC) analysis of the rock extracts across the lithostratigraphic units show that Pr/Ph, Pr/nC17, Pr/nC18, CPI and odd/even preference ranged from 0.07 to 12.39, 0.04 to 6.66, 0.05 to 13.80, 0.12 to 8.4 and 0.06 to 8.12, respectively. The Rock-Eval pyrolysis data and geochemical ratios and parameters calculated from the GC data showed that most of the samples are mature and have strong terrestrial provenance while a few samples have strong marine provenance. The few marine source rocks are located in the deeper depth horizon. Pr/Ph and standard geochemical plots indicate that most of samples were derived from organic matter deposited in less reducing conditions, i.e. more of oxidizing conditions while a few samples have predominantly influence of reducing conditions. The results of trace metal analysis of older samples from Agbada Formation also indicate marine and mixed organic matter input deposited in less reducing conditions. The results obtained in this study are comparable with those obtained from previous studies when Soxhlet extraction method was used and also indicated the presence of more than one petroleum systems in the Niger Delta.

  12. Uranium exploration data and global geochemical baselines: The need for co-ordinated action

    International Nuclear Information System (INIS)

    Darnley, A.G.

    1997-01-01

    Public concern about environmental problems continues. In order to assess the magnitude of potential problems it is necessary to have comprehensive information. The absence of quantitative geochemical data to map the surface composition of the earth is one of the major information gaps in present day environmental science. An IAEA Technical Committee meeting held in November 1993 reviewed the uses of uranium exploration data for environmental purposes. Most attention was focussed on data involving radiation measurements. Uranium exploration programmes conducted since 1970 in many countries collected a considerable amount of geochemical survey data, providing information about the distribution of non-radioactive elements in the natural environment. Canada is one of several countries where such data provided the foundation for national geochemical mapping; other countries could benefit from similar actions. Increasing importance is being attached by governments to the need to enact effective environmental legislation concerning ''safe levels'' of many chemical substances. Such legislation requires geochemical variations in the natural environment. It is becoming necessary to make quantitative comparisons of element abundances across national boundaries, and from continent to continent. In 1995 the IAEA, with other organizations, supported UNESCO to publish a report concerned with the establishment of a Global Geochemical Reference Network. This is designed to provide a framework to connect all types of geochemical survey, to move towards international compatibility of data. The report contains recommendations relating to the standardization of field and laboratory methods; the use of the most sensitive analytical techniques; and standardization of data management. Ground and airborne gamma ray spectrometry, and nuclear laboratory techniques are all discussed. Following the publication of the report, the International Union of Geological Sciences has now established a

  13. Geochemical impacts of groundwater heat pump systems in an urban alluvial aquifer with evaporitic bedrock

    International Nuclear Information System (INIS)

    Garrido Schneider, Eduardo A.; García-Gil, Alejandro; Vázquez-Suñè, Enric; Sánchez-Navarro, José Á.

    2016-01-01

    In the last decade, there has been an extensive use of shallow geothermal exploitations in urban environments. Although the thermal interference between exploitations has been recently studied, there is a lack of knowledge regarding the geochemical impacts of those systems on the aquifers where they are installed. Groundwater flow line scale and well-doublet scale research work has been conducted at city scale to quantify the geochemical interaction of shallow geothermal exploitations with the environment. A comprehensive analysis was conducted on data obtained from a monitoring network specifically designed to control and develop aquifer policies related to thermal management of the aquifer. The geochemical impacts were evaluated from a thermodynamic point of view by means of saturation index (SI) calculations with respect to the different mineral species considered in the system. The results obtained indicate limited geochemical interaction with the urban environment in most of the situations. However, there are some cases where the interaction of the groundwater heat pump installations with the evaporitic bedrock resulted in the total disablement of the exploitation system operation wells. The application of the tool proposed proved to be pragmatic in the evaluation of geochemical impacts. Injection of water into the aquifer can trigger an important bedrock gypsum and halite dissolution process that is partly responsible for scaling in well casing pipes and collapse of the terrain in the vicinity of injection wells. - Highlights: • We studied geochemical impacts of groundwater heat pump systems. • We have sampled a monitoring network in an energetically exploited urban aquifer. • A limited geochemical interaction has been found in most of the exploitations. • Reinjection into the aquifer produces an important bedrock gypsum dissolution. • Scaling in well casing pipes and collapse of the terrain have been observed.

  14. Titan's Stratospheric Condensibles at High Northern Latitudes During Northern Winter

    Science.gov (United States)

    Anderson, Carrie; Samuelson, R.; Achterberg, R.

    2012-01-01

    The Infrared Interferometer Spectrometer (IRIS) instrument on board Voyager 1 caught the first glimpse of an unidentified particulate feature in Titan's stratosphere that spectrally peaks at 221 per centimeter. Until recently, this feature that we have termed 'the haystack,' has been seen persistently at high northern latitudes with the Composite Infrared Spectrometer (CIRS) instrument onboard Cassini, The strength of the haystack emission feature diminishes rapidly with season, becoming drastically reduced at high northern latitudes, as Titan transitions from northern winter into spring, In contrast to IRIS whose shortest wavenumber was 200 per centimeter, CIRS extends down to 10 per centimeter, thus revealing an entirely unexplored spectral region in which nitrile ices have numerous broad lattice vibration features, Unlike the haystack, which is only found at high northern latitudes during northern winter/early northern spring, this geometrically thin nitrile cloud pervades Titan's lower stratosphere, spectrally peaking at 160 per centimeter, and is almost global in extent spanning latitudes 85 N to 600 S, The inference of nitrile ices are consistent with the highly restricted altitude ranges over which these features are observed, and appear to be dominated by a mixture of HCN and HC3N, The narrow range in altitude over which the nitrile ices extend is unlike the haystack, whose vertical distribution is significantly broader, spanning roughly 70 kilometers in altitude in Titan's lower stratosphere, The nitrile clouds that CIRS observes are located in a dynamically stable region of Titan's atmosphere, whereas CH4 clouds, which ordinarily form in the troposphere, form in a more dynamically unstable region, where convective cloud systems tend to occur. In the unusual situation where Titan's tropopause cools significantly from the HASI 70.5K temperature minimum, CH4 should condense in Titan's lower stratosphere, just like the aforementioned nitrile clouds, although

  15. Drowning in Geochemical Data: The Good, the bad, and the Ugly

    Science.gov (United States)

    Hofmann, A. W.; Goldstein, S. L.

    2008-12-01

    Geochemical databases are placing unprecedented amounts of geochemical data at the fingertips of professionals and students. How these data are being used is taking an increasingly important role in shaping our thinking about the Earth. Databases have helped to expose (and eventually kill?) some long- cherished myths, such as the idea of the well-homogenized upper-mantle reservoir, and and they have made geochemical data accessible to geophysicists and enabled them to look at geochemistry with fresh eyes, leading to genuinely new insights. Yet, their very accessibility also makes them "dangerous tools" in the hands of the inexperienced. Statistical treatment of masses of geochemical data without, or with excessive, filtering can yield all sorts of "answers" we would probably be better off without. Data that are severely flawed (due to alteration or poor analytical quality, errors in published data, or errors during data entry) might not be easily identified by, say, a geodynamicist. Other dangers stem from overrepresentation of over-sampled locations and the general, but faulty, assumption of random sampling of the Earth. We will show examples where raw downloads of data from databases without extensive screening can yield data collections where the garbage swamps the useful information. We will also show impressive but meaningless correlations, e.g. upper-mantle temperature versus atmospheric temperature. The lesson is that screening is necessary. On the other hand, sound database compilations now demonstrate that average incompatible-element concentrations in global MORB are two to five times higher than published estimates. This fundamentally changes 30-year-old geochemical mass balance estimates of the mantle. OIBs are fundamentally similar to MORBs but are isotopically shifted, on average, to more "enriched" values. Mantle geochemistry is now fully consistent with dynamic models of "whole-mantle" circulation, with the likely exception of a relatively small

  16. Linking the climatic and geochemical controls on global soil carbon cycling

    Science.gov (United States)

    Doetterl, Sebastian; Stevens, Antoine; Six, Johan; Merckx, Roel; Van Oost, Kristof; Casanova Pinto, Manuel; Casanova-Katny, Angélica; Muñoz, Cristina; Boudin, Mathieu; Zagal Venegas, Erick; Boeckx, Pascal

    2015-04-01

    Climatic and geochemical parameters are regarded as the primary controls for soil organic carbon (SOC) storage and turnover. However, due to the difference in scale between climate and geochemical-related soil research, the interaction of these key factors for SOC dynamics have rarely been assessed. Across a large geochemical and climatic transect in similar biomes in Chile and the Antarctic Peninsula we show how abiotic geochemical soil features describing soil mineralogy and weathering pose a direct control on SOC stocks, concentration and turnover and are central to explaining soil C dynamics at larger scales. Precipitation and temperature had an only indirect control by regulating geochemistry. Soils with high SOC content have low specific potential CO2 respiration rates, but a large fraction of SOC that is stabilized via organo-mineral interactions. The opposite was observed for soils with low SOC content. The observed differences for topsoil SOC stocks along this transect of similar biomes but differing geo-climatic site conditions are of the same magnitude as differences observed for topsoil SOC stocks across all major global biomes. Using precipitation and a set of abiotic geochemical parameters describing soil mineralogy and weathering status led to predictions of high accuracy (R2 0.53-0.94) for different C response variables. Partial correlation analyses revealed that the strength of the correlation between climatic predictors and SOC response variables decreased by 51 - 83% when controlling for geochemical predictors. In contrast, controlling for climatic variables did not result in a strong decrease in the strength of the correlations of between most geochemical variables and SOC response variables. In summary, geochemical parameters describing soil mineralogy and weathering were found to be essential for accurate predictions of SOC stocks and potential CO2 respiration, while climatic factors were of minor importance as a direct control, but are

  17. The Geochemical Behavior and Transport Characteristics of Xenoestrogens

    Science.gov (United States)

    Wallace, T. C.; Bennett, P. C.

    2003-12-01

    Xenoestrogens are estrogenic active synthetic chemicals that mimic the actions of female sex hormones. Xenoestrogens can be produced synthetically and naturally, and exposure can occur from a variety of sources- food additives, plastics, pesticides, or pharmaceuticals. These environmental chemicals are also known as endocrine disruptors because exposure to low doses (ng/L) have been linked to adverse effects in the reproductive and developmental stages in aquatic species (i.e. reproductive anomalies, feminization, infertility, alterations in growth during life cycles, and changes in community structures). Determining the exposure risks of these toxicological compounds, however, requires a better understanding of the geochemical behavior and transport of synthetic estrogens it is discharged to. Estrogen and its metabolites are also useful tracers because of their specific medical usage (sources from birth control pills, estrogen replacement therapy, and livestock farming), slow degradation before excretion, and unique physiochemical properties (low volatility, hydrophobicity, and high Kow). Estradiol concentrations analyzed by an enzyme-linked immunoassay (ELISA) show that xenoestrogens become associated with solid phases. A series of batch sorption experiments using sediment collected from Walnut Creek downstream of an Austin waste water treatment plant and synthetic estrogen standards (Simga@ Estrone, 17B-Estradiol, and Estriol), examined the distribution of estrogen between solid and aqueous phases. Analysis of the concentrations sorbed to sediment result in Freundlich sorption isotherms using HPLC/UV techniques (High Performance Liquid Chromatography with UV detectors- 220 and 280nm). Sorption occurs rapidly with 98% of 17B-Estradiol sorbed within 30 minutes (Estriol=80%, Estrone=95%), which is compared to photolysis degradation rates under UV and a broader spectrum sun lamp. Ultraviolet/Visible (UV/VIS) spectroscopy of the estrogen standards with dilute fulvic

  18. Geochemical and Geophysical Signatures of Poas Volcano, Costa Rica

    Science.gov (United States)

    Martinez, M.; van Bergen, M.; Fernandez, E.; Takano, B.; Barboza, V.; Saenz, W.

    2007-05-01

    still remains open to a question if they will play a helpful role as a geophysical monitoring tool in determining the commencement of volcanic events. A range of Poas volcano geochemical and geophysical parameters have been combined to envisage relationships between them and to gain a better insight in the understanding of the Poas volcanic system.

  19. A Multi-Proxy Analysis of two Loess-Paleosol Sequences in the Northern Harz Foreland

    Science.gov (United States)

    Krauss, Lydia; Zens, Joerg; Zeeden, Christian; Schulte, Philipp; Eckmeier, Eileen; Lehmkuhl, Frank

    2016-04-01

    Within the second phase of the "Collaborative Research Centre 806 (CRC806) - Our Way to Europe - Culture-Environment Interaction and Human Mobility in the Late Quaternary" two loess-paleosol sections in the northern Harz foreland are being investigated. The region is part of the Northern European loess belt. The northern edge of the loess distribution is characterized by an interlocking of Weichselian silt and sand sized aeolian sediments. To the south the Northern European loess belt is limited by the central German uplands (Mittelgebirge). Here the continuous loess cover disperses into separated loess basins. In comparison to relatively long, continuous and intensively studied sections, e.g. along the Rhine river, investigations on loess-paleosol sequences in the northern Harz foreland have been sparse so far. In 2006 REINECKE created an overview of Pleistocene landscape developments by investigating terrace sequences and loess sections in this area. Due to improvements of research methods over the last ten years, the two loess-paleosol sequences Hecklingen and Zilly are being reinvestigated. Aiming towards a better understanding of the paleoenvironmental conditions during the Weichselian in an area close to the Scandinavian ice sheet, results from grain size, geochemical (XRF, CNS) and color measurements are combined. The results show an increased input of aeolian material during the last glacial maximum and the last cover loess period, supporting the theory of dryer and colder conditions during this time frame. Further, we can see a stronger short distant input within the recent soil and during the last glacial maximum in both profiles. In Hecklingen this is also observed within the MIS 3 soil material. Since soil material dating to the MIS 3 is present, we can assume that surface processes where less intrusive during the MIS 3 and 2 as in e.g. the Lower Rhine Embayment. REINECKE, V. (2006): Untersuchungen zur mittel- und jungpleistozänen Reliefentwicklung und

  20. The outlook for northern forests

    Science.gov (United States)

    Stephen R. Shifley; W. Keith Moser; Sherri Wormstead; Francisco X. Aguilar

    2016-01-01

    The forests of the Northern United States have been remarkably resilient to nearly four centuries of immigration and settlement with associated anthropogenic disturbances caused by farming, logging, burning, urbanization, trade, and many other factors. Although resilient, forests conditions have been significantly impacted by humans as is illustrated by the extent of...

  1. NUMA: A Northern Paiute History.

    Science.gov (United States)

    Inter-Tribal Council of Nevada, Reno.

    One in a series of four histories of native Nevadans, this volume presents the story of the Northern Paiute people, or Numa, who lived, hunted, and travelled in the Great Basin area which occupies one-third of present day Nevada and parts of Oregon, Idaho, and California. Based on interviews with tribal elders and research conducted at numerous…

  2. Mitigating Radicalism in Northern Nigeria

    Science.gov (United States)

    2013-08-01

    protectorates through indigenous rulers—merely institutionalized existing divisions. With the building of infrastructure—such as new railway lines— immigrant ...laborers and traders from the south settled into can- tonments in most major northern cities. The effect of these sabon gari (“ strangers ’ quarters” in

  3. June 1990 Northern, Iran Images

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A magnitude 7.7 earthquake occurred in the Gilan Province between the towns of Rudbar and Manjil in northern Iran on Thursday, June 21, 1990 (June 20 at 21:00 GMT)....

  4. Neuropsychiatric perspectives on nodding syndrome in northern ...

    African Journals Online (AJOL)

    trauma and the emergence of epidemic NS in Northern Uganda. ... NS could present as an association of childhood complex PTSD, (called Developmental Trauma Disorder), occurring in the chronically war-traumatised children of Northern Uganda, ...

  5. Applications of geochemical modeling to high-level nuclear waste disposal at the Hanford site, Washington

    International Nuclear Information System (INIS)

    Early, T.O.; Myers, J.; Jenne, E.A.

    1985-01-01

    The current and projected uses of geochemical models by the Basalt Waste Isolation Project (BWIP) focus on two segments of the repository system and their associated long-term goals. These segments are the waste package and far-field environments. The long-term goals relative to the waste package environment are to: understand important solid/water reactions which control the waste package environment (Eh, pH, groundwater composition) during the thermal period; and to understand the controls on steady-state solution concentrations of key radionuclides to provide a source term for waste package radionuclide release modeling. The long-term goals relative to the far-field environment are to: understand important geochemical controls on dissolved constituents of the preemplacement groundwater flow system; provide geochemical support for conceptual groundwater flow models; and to obtain bounding information relative to the geochemical fate of radionuclides along likely flow paths to the accessible environment. Geochemical modeling applications in both areas are discussed

  6. The Northern Lights Experience - Negotiation strategies

    OpenAIRE

    Smedseng, Nina

    2014-01-01

    With rapidly increasing tourist numbers, the potential in commercialising the Northern Lights has grown immensely over the last few years, and one can only imagine what possibilities the future holds for professional Northern Lights experience providers. One of the biggest challenges of the Northern Lights experiences is how to deal with the natural conditions and constraints of this ever shifting phenomenon. The experience providers cannot guarantee sightings of the Northern Lights eve...

  7. Geochemical investigation of iron transport into bentonite as steel corrodes

    International Nuclear Information System (INIS)

    Hunter, Fiona; Bate, Fiona; Heath, Tim; Hoch, Andrew

    2007-09-01

    some experiments. Using the experimental data as a guide, a modelling investigation has been carried out. The objectives of the modelling investigation were: To develop a geochemical model of the transport of iron into bentonite based on the clear experimental evidence of the penetration of iron into bentonite. To improve our understanding of the desaturation of the bentonite as water is consumed during the corrosion process and the resultant gas(es) escapes. The production of iron from the corroding source was modelled using a rate of gas evolution that had been fitted. It was shown that ion exchange and surface complexation processes do not provide sufficient sorption to predict the high amount of iron observed in the solid phase. Therefore alternative processes, such as iron-containing mineral formation or mineral transformations, were also suggested to account for the amount of iron observed within the bentonite phase. Magnetite was identified as the most thermodynamically stable solubility limiting phase under the experimental conditions. A one-dimensional transport model was constructed to include all relevant processes. The simulations considered the diffusive transport of Fe 2+ ions away from a corroding source, using the rate of gas evolution resulting from the corrosion process. Ion exchange and surface complexation processes were allowed within the bentonite which would provide sorption of iron onto and within the bentonite solid. The pH was buffered by allowing protonation and deprotonation of the surface sites of the bentonite solid. In addition, saturation of iron-containing minerals was permitted. The base case model suggests that about 4.4 wt % of iron could form in the bentonite if the formation of magnetite was allowed. However, the maximum theoretical amount of iron available from the source term is limited to 4.5 wt % of iron by the cumulative gas evolution rate, which is lower than the observed amount of iron in the bulk bentonite (6.6 wt %). A

  8. Geochemical evolution of the L/ILW near-field

    International Nuclear Information System (INIS)

    Kosakowski, G.; Berner, U.; Wieland, E.; Glaus, M.; Degueldre, C.

    2014-10-01

    The deep geological repository for low- and intermediate-level radioactive waste (L/ILW) contains large amounts of cement based materials used for waste conditioning, tunnel support and the backfill of cavities. The waste inventory is composed of a wide range of organic and inorganic materials. This study describes the spatial and temporal geochemical evolution of the cementitious near-field, and the interactions with the technical barriers and the surrounding host rock. This evolution is governed by several coupled processes, an important one being the development of saturation by groundwater ingress from the host rock. Saturation of the near-field is controlled by the inflow of water from the host rock, by the transport of dissolved gases from the near-field into the host rock and in the engineered gas transport system, and by the transport of humidity in the gas phase. The production of gas by anoxic corrosion of metals and by microbial degradation of organic wastes consumes water. The mineral reactions which give rise to concrete degradation, such as carbonation or alkali-silica-aggregate reactions may also consume or produce water. The first phase of cementitious near-field degradation, which persists only for a short period of time, is related to the hydration of cement minerals. The pore water has a pH of 13 or even higher because of the high content of dissolved alkali hydroxides. A constant pH of 12.5 determines the second phase of the cement degradation. The alkali concentration is reduced by mineral reactions and/or solute transport. This phase persists for a long time. In the third phase the portlandite is completely dissolved due to the reaction with silicates/aluminates present in the near-field and carbonate in the groundwater of the host rock or associated with reactive waste materials. The pore water is in equilibrium with calcium-silicate-hydrates (C-S-H) which gives rise to a pH value near 11 or lower. The Ca/Si ratio of C-S-H changes towards

  9. Geochemical evolution of the L/ILW near-field

    Energy Technology Data Exchange (ETDEWEB)

    Kosakowski, G.; Berner, U.; Wieland, E.; Glaus, M.; Degueldre, C.

    2014-10-15

    The deep geological repository for low- and intermediate-level radioactive waste (L/ILW) contains large amounts of cement based materials used for waste conditioning, tunnel support and the backfill of cavities. The waste inventory is composed of a wide range of organic and inorganic materials. This study describes the spatial and temporal geochemical evolution of the cementitious near-field, and the interactions with the technical barriers and the surrounding host rock. This evolution is governed by several coupled processes, an important one being the development of saturation by groundwater ingress from the host rock. Saturation of the near-field is controlled by the inflow of water from the host rock, by the transport of dissolved gases from the near-field into the host rock and in the engineered gas transport system, and by the transport of humidity in the gas phase. The production of gas by anoxic corrosion of metals and by microbial degradation of organic wastes consumes water. The mineral reactions which give rise to concrete degradation, such as carbonation or alkali-silica-aggregate reactions may also consume or produce water. The first phase of cementitious near-field degradation, which persists only for a short period of time, is related to the hydration of cement minerals. The pore water has a pH of 13 or even higher because of the high content of dissolved alkali hydroxides. A constant pH of 12.5 determines the second phase of the cement degradation. The alkali concentration is reduced by mineral reactions and/or solute transport. This phase persists for a long time. In the third phase the portlandite is completely dissolved due to the reaction with silicates/aluminates present in the near-field and carbonate in the groundwater of the host rock or associated with reactive waste materials. The pore water is in equilibrium with calcium-silicate-hydrates (C-S-H) which gives rise to a pH value near 11 or lower. The Ca/Si ratio of C-S-H changes towards

  10. Seismic and Geophysical Characterization of Northern Asia

    Science.gov (United States)

    2010-09-01

    SEISMIC AND GEOPHYSICAL CHARACTERIZATION OF NORTHERN ASIA Kevin Mackey1, Hans Hartse2, Kazuya Fujita1, Michael Pasyanos3, and Michael Begnaud2...improve the calibration of northern Asia for nuclear explosion monitoring purposes. This project builds off previous work, and is a cooperative...propagation characteristics in northern Asia . Our work will further improve location and detection and discrimination capabilities, crustal and upper

  11. Geochemical monitoring using noble gases and carbon isotopes: study of a natural reservoir

    International Nuclear Information System (INIS)

    Jeandel, E.

    2008-12-01

    To limit emissions of greenhouse gases in the atmosphere, CO 2 geological sequestration appears as a solution in the fight against climate change. The development of reliable monitoring tools to ensure the sustainability and the safety of geological storage is a prerequisite for the implementation of such sites. In this framework, a geochemical method using noble gas and carbon isotopes geochemistry has been tested on natural and industrial analogues. The study of natural analogues from different geological settings showed systematic behaviours of the geochemical parameters, depending on the containment sites, and proving the effectiveness of these tools in terms of leak detection and as tracers of the behaviour of CO 2 . Moreover, an experience of geochemical tracing on a natural gas storage has demonstrated that it is possible to identify the physical-chemical processes taking place in the reservoir to a human time scale, increasing interest in the proposed tool and providing general information on its use. (author)

  12. Some methodical questions of study of vertical geochemical zoning of ore deposits

    International Nuclear Information System (INIS)

    Sochevanov, N.N.; Gorelova, E.K.

    1975-01-01

    Taking a hydrothermal uranium deposit as an example, the advisability of dividing ore-localizing structures (for the purpose of making a calculation for a single geochemical zonality) into five zones, a supra-, an upper, a central, a lower and an infra-ore one, has been shown. It is recommended to determine the place of elements in the geochemical zonality sequence by taking into account the productivity of their aureoles and the location of the centre of gravity of their reserves in the ore, supra- and infra-ore horizons. When considering the peculiarities of a zonality, it is irrational to take account of elements determined with an insufficient sensitivity as well as of low-contrast or unstable ones. When calculating tracer ratios the most contrasting data can be obtained by using the most distant elements in the geochemical zonality sequence

  13. Acceptance of the 2014 Geochemical Society Distinguished Service Award by Carla Koretsky

    Science.gov (United States)

    Koretsky, Carla

    2015-06-01

    I am deeply touched to have received the Geochemical Society Distinguished Service Award. It was a great surprise when I received the notice that I had been chosen for the award. It has been a tremendous pleasure to work on behalf of student members of the Geochemical Society, Japanese Geochemical Society and the European Association of Geochemists to organize the student travel grants over the past few years. Certainly, this is not an effort that I undertook on my own. Many, many members of the GS, the JGS and the EAG generously donated their time and expertise to serve as reviewers for the many travel grant applicants we receive each year. Seth Davis, the GS Chief Operating Officer, spent countless hours helping to organize applications, the website, distribution of funds and many other aspects of the competition. Without Seth and the many expert reviewers, we could not run the travel grant program each year and provide this important financial support to allow more students to experience the Goldschmidt Conference. I also enjoyed my time as Geochemical News co-editor, and I should point out that GN during those years was ably co-edited by Johnson Haas. It has been a pleasure to see Elements take off, and GN evolve into a timely source of important announcements and information about cutting-edge science since I stepped down as co-editor. I feel very fortunate to work with so many outstanding colleagues in the global geochemical community, and I am a little embarrassed, and also very grateful, to have been selected for the Geochemical Society Distinguished Service Award. Thank you!

  14. An integrated geophysical and geochemical exploration of critical zone weathering on opposing montane hillslope

    Science.gov (United States)

    Singha, K.; Navarre-Sitchler, A.; Bandler, A.; Pommer, R. E.; Novitsky, C. G.; Holbrook, S.; Moore, J.

    2017-12-01

    Quantifying coupled geochemical and hydrological properties and processes that operate in the critical zone is key to predicting rock weathering and subsequent transmission and storage of water in the shallow subsurface. Geophysical data have the potential to elucidate geochemical and hydrologic processes across landscapes over large spatial scales that are difficult to achieve with point measurements alone. Here, we explore the connections between weathering and fracturing, as measured from integrated geochemical and geophysical borehole data and seismic velocities on north- and south-facing aspects within one watershed in the Boulder Creek Critical Zone Observatory. We drilled eight boreholes up to 13 m deep on north- and south-facing aspects within Upper Gordon Gulch, and surface seismic refraction data were collected near these wells to explore depths of regolith and bedrock, as well as anisotropic characteristics of the subsurface material due to fracturing. Optical televiewer data were collected in these wells to infer the dominant direction of fracturing and fracture density in the near surface to corroborate with the seismic data. Geochemical samples were collected from four of these wells and a series of shallow soil pits for bulk chemistry, clay fraction, and exchangeable cation concentrations to identify depths of chemically altered saprolite. Seismic data show that depth to unweathered bedrock, as defined by p-wave seismic velocity, is slightly thicker on the north-facing slopes. Geochemical data suggest that the depth to the base of saprolite ranges from 3-5 m, consistent with a p-wave velocity value of 1200 m/s. Based on magnitude and anisotropy of p-wave velocities together with optical televiewer data, regolith on north-facing slopes is thought to be more fractured than south-facing slopes, while geochemical data indicate that position on the landscape is another important characteristic in determining depths of weathering. We explore the importance

  15. Statistical treatment of geochemical data and its application in the geologic mapping and in the definition of the geochemical anomalies in the Alvo 2-Corpo 4 -Provincia Mineral de Carajas

    International Nuclear Information System (INIS)

    Moura, C.A.V.

    1982-01-01

    It was given a statistical treatment for the geochemical data about soil in the are named Alvo2 - Corpo4- in the Provincia Mineral de Carajas, Para, Brazil, for application of the geological mapping and definition of geochemical anomalies. (A.B.) [pt

  16. The geochemical evolution of syncollisional magmatism and the implications for significant magmatic-hydrothermal lead-zinc mineralization (Gangdese, Tibet)

    Science.gov (United States)

    Zhou, Jinsheng; Yang, Zhusen; Hou, Zengqian; Liu, Yingchao; Zhao, Xiaoyan; Zhang, Xiong; Zhao, Miao; Ma, Wang

    2017-09-01

    In addition to well-known subduction processes, the collision of two continents also generates abundant ore deposits, as in the case of the Tibetan Plateau, which is the youngest and most spectacular collisional belt on Earth. During the building history of the Gangdese magmatic belt, several magmatic flare-up events developed, however, significant magmatic-hydrothermal lead-zinc mineralization dominantly accompanied the magmatism during the syncollisional period ( 65-41 Ma). Based on integrated geochemical and isotopic data, we provide insights into the genesis and evolution of syncollisional magmas, and their implications for significant magmatic-hydrothermal lead-zinc mineralization. The Sr-Nd isotopic compositions of most syncollisional igneous rocks (87Sr/86Sr = 0.7034-0.7123; εNd(t) = - 9.0 to + 1.8) indicate a mixing origin between mantle-derived basaltic magmas and ancient crustal melts, and fractional crystallization is a fundamental mechanism by which syncollisional magmas evolve towards intermediate to silicic compositions. Most lead-zinc mineralization-related plutons are high silica (76.14% wt.% SiO2 on average), high oxygen fugacity (average ΔFMQ + 2.5) granites with highly evolved chemical signatures [average Eun/Eun* = 0.33, high Rb/Sr (average = 3.9)], and they represent the final products from primary magmas. Due to the contribution of ancient crustal melts to the genesis of mineralization-related parent magmas, the spatial distribution of Pb-Zn deposits within the northern Gangdese magmatic belt is controlled by the lithospheric architecture. In compressional environments, magmas have low evacuation efficiency and long magma chamber lifespan, which is favorable for basaltic parents evolved to high silica granites through sufficient fractional crystallization. This scenario contributes to our understanding of the significant magmatic-hydrothermal lead-zinc mineralization that occurred in the syncollisional period.

  17. Geochemical interactions between process-affected water from oil sands tailings ponds and North Alberta surficial sediments.

    Science.gov (United States)

    Holden, A A; Donahue, R B; Ulrich, A C

    2011-01-25

    In Northern Alberta, the placement of out-of-pit oil sands tailings ponds atop natural buried sand channels is becoming increasingly common. Preliminary modeling of such a site suggests that process-affected (PA) pond water will infiltrate through the underlying clay till aquitard, reaching the sand channel. However, the impact of seepage upon native sediments and groundwater resources is not known. The goal of this study is to investigate the role of adsorption and ion exchange reactions in the clay till and their effect on the attenuation or release of inorganic species. This was evaluated using batch sorption experiments (traditional and a recent modification using less disturbed sediment samples) and geochemical modeling with PHREEQC. The results show that clay till sediments have the capacity to mitigate the high concentrations of ingressing sodium (600 mg L(-1)), with linear sorption partitioning coefficients (K(d)) of 0.45 L kg(-1). Ion exchange theory was required to account for all other cation behaviour, precluding the calculation of such coefficients for other species. Qualitative evidence suggests that chloride will behave conservatively, with high concentrations remaining in solution (375 mg L(-1)). As a whole, system behaviour was found to be controlled by a combination of competitive ion exchange, dissolution and precipitation reactions. Observations, supported by PHREEQC simulations, suggest that the influx of PA water will induce the dissolution of pre-existing sulphate salts. Sodium present in the process-affected water will exchange with sediment-bound calcium and magnesium, increasing the divalent ions' pore fluid concentrations, and leading to the precipitation of a calcium-magnesium carbonate mineral phase. Thus, in similar tailings pond settings, particularly if the glacial till coverage is thin or altogether absent, it is reasonable to expect that high concentrations of sodium and chloride will remain in solution, while sulphate

  18. Geochemical characterization of basalts from west of Khash (SE Iran: an approach to the nature of the mantle source

    Directory of Open Access Journals (Sweden)

    Zahra Firouzkouhi

    2017-07-01

    Full Text Available Monogenic basaltic cinder cones and lava flows from west of Khash are part of volcanic arc of northern Makran, formed as a result of subduction of Oman oceanic lithosphere beneath the Eurasian plate. The basalts belong to medium-K calc-alkaline series as they contain high Al2O3 (16.5- 19.04 wt. % and CaO (8.4- 12.0 wt. % and moderate amounts of K2O (0.5- 1.1 wt. %. They share arc geochemical features such as high LILE/HFSE ([Rb/Zr]N-MORB up to 19 LILE/LREE ([Ba/La]N-MORB up to 4.86 and LREE/HREE ([La/Yb]N-MORB up to 10, and depletion of Ta, Nb, Zr, and Ti relative to N-MORB. Partial melting models indicate that near-primary basalts were derived from an enriched source type mantle wedge peridotite after low to medium degrees (2-10% of partial melting. This source peridotite was enriched in LREE and LILE, by subduction derived fluids in the supra-subduction zone. Negative correlation of Th/La vs. Sm/La, and relationships between Pb/Ce and Th/Nb values of the studied basalts which are between two end compositions of global subducting sediment (GLOSS and N-MORB are indicative of significant contribution of subducting sediments to the genesis of the basaltic rocks. Estimates made using binary mixing model are indicative of about 16% of sediment participation in the magma genesis. Low Pb/Ce ratio (1.6 - 11.1, compared to OIB (>20 may be a signature of participation of fluids resulted from dehydration of the subducting slab

  19. Post-Eocene volcanics of the Abazar district, Qazvin, Iran: Mineralogical and geochemical evidence for a complex magmatic evolution

    Science.gov (United States)

    Asiabanha, A.; Bardintzeff, J. M.; Kananian, A.; Rahimi, G.

    2012-02-01

    The style of volcanism of post-Eocene volcanism in the Alborz zone of northern Iran is different to that of Eocene volcanism (Karaj Formation). Indeed, the volcanic succession of the Abazar district, located in a narrow volcanic strip within the Alborz magmatic assemblage, is characterized by distinct mineralogical and chemical compositions linked to a complex magmatic evolution. The succession was produced by explosive eruptions followed by effusive eruptions. Two main volcanic events are recognized: (1) a thin rhyolitic ignimbritic sheet underlain by a thicker lithic breccia, and (2) lava flows including shoshonite, latite, and andesite that overlie the first event across a reddish soil horizon. Plagioclase in shoshonite (An 48-92) shows normal zoning, whereas plagioclase in latite and andesite (An 48-75) has a similar composition but shows reverse and oscillatory zoning. QUILF temperature calculations for shoshonites and andesites yield temperatures of 1035 °C and 1029 °C, respectively. The geothermometers proposed by Ridolfi et al. (2010) and Holland and Blundy (1994) yield temperatures of 960 °C and 944 °C for latitic lava, respectively. The samples of volcanic rock show a typical geochemical signature of the continental arc regime, but the andesites clearly differ from the shoshonites, the latites and the rhyolites. The mineralogical and chemical characteristics of these rocks are explained by the following petrogenesis: (1) intrusion of a hot, mantle-depth mafic (shoshonitic) magma, which differentiated in the magma chamber to produce a latitic and then a rhyolitic liquid; (2) rhyolitic ignimbritic eruptions from the top of the magma chamber, following by shoshonitic and then latitic extrusions; (3) magma mingling between the latitic and andesitic magmas, as indicated by the occurrence of andesite clasts within the latite; and (4) andesitic effusions. The youngest volcanic events in the Alborz zone show a close chemical relationship with continental arc

  20. Coal inclusions in sedimentary rocks. A geochemical phenomenon. A review

    Energy Technology Data Exchange (ETDEWEB)

    Yudovich, Ya. E. [Institute of Geology, Komi Scientific Center, Ural Division of the Russian Academy of Sciences, Morozova st., 100, ap. 49, 167023 Syktyvkar (Russian Federation)

    2003-12-01

    summary, the review shows that coal inclusions are unique geochemical phenomenon, sharply different from even neighboring coal beds in trace element content. Among the most extreme elements is germanium, its mean concentration in the ash of coal inclusions being up to 220 times higher than in the ash of coal beds. The most important peculiarity of the coalified wood is the good preservation of the original lignin structures, which may effectively scavenge Ge from solutions, whereas peat-born coals (in beds) contained such structures in far fewer amounts. In addition, a reservoir of dissolved germanium in peat bog waters was of lower concentration than in sediments, which buried the coal inclusions. Finally, the peat bog acidic environment may act as an unfavorable factor.Ge-enrichment can be completed in a time ranging from a few thousand years up to tens of million years. However, if the waters are enriched in Ge, the process can proceed more rapidly and would be completed even under the most unfavorable parameters (compared to the model conditions). This implies that enrichment can take place during the early diagenetic stage. Such a scenario was supported by geologic considerations.Some Canadian and Soviet works performed from 1950 to 1960 along with some recent Russian studies show that Ge in coal inclusions can be of economic interest. Geochemistry and mineralogy of coal inclusions are of great interest and need further detailed study.

  1. Risk evaluation of uranium mining: A geochemical inverse modelling approach

    Science.gov (United States)

    Rillard, J.; Zuddas, P.; Scislewski, A.

    2011-12-01

    It is well known that uranium extraction operations can increase risks linked to radiation exposure. The toxicity of uranium and associated heavy metals is the main environmental concern regarding exploitation and processing of U-ore. In areas where U mining is planned, a careful assessment of toxic and radioactive element concentrations is recommended before the start of mining activities. A background evaluation of harmful elements is important in order to prevent and/or quantify future water contamination resulting from possible migration of toxic metals coming from ore and waste water interaction. Controlled leaching experiments were carried out to investigate processes of ore and waste (leached ore) degradation, using samples from the uranium exploitation site located in Caetité-Bahia, Brazil. In experiments in which the reaction of waste with water was tested, we found that the water had low pH and high levels of sulphates and aluminium. On the other hand, in experiments in which ore was tested, the water had a chemical composition comparable to natural water found in the region of Caetité. On the basis of our experiments, we suggest that waste resulting from sulphuric acid treatment can induce acidification and salinization of surface and ground water. For this reason proper storage of waste is imperative. As a tool to evaluate the risks, a geochemical inverse modelling approach was developed to estimate the water-mineral interaction involving the presence of toxic elements. We used a method earlier described by Scislewski and Zuddas 2010 (Geochim. Cosmochim. Acta 74, 6996-7007) in which the reactive surface area of mineral dissolution can be estimated. We found that the reactive surface area of rock parent minerals is not constant during time but varies according to several orders of magnitude in only two months of interaction. We propose that parent mineral heterogeneity and particularly, neogenic phase formation may explain the observed variation of the

  2. Organic geochemical study of domanik deposits, Tatarstan Republic.

    Science.gov (United States)

    Nosova, F. F.; Pronin, N. V.

    2010-05-01

    High-bituminous argillo-siliceous carbonate deposits of domanik formation (DF) occurring within pale depressions and down warps in the east of the Russian platform are treated by many investigators as a main source of oil and gas in the Volga-Ural province. In this study a special attention was turned to organic-rich rocks DF witch outcrop in the central part (Uratminskaya area 792, 806 boreholes) and in the west part (Sviyagskaya, 423) of the Tatarstan Republic. The aim of the present paper is to characterize the organic matter: origin, depositional environments, thermal maturity and biodegradation-weathering effects. Nowadays the most informative geochemical parameters are some biomarkers which qualitatively and are quantitatively defined from distributions of n-alkanes and branched alkanes. Biomarkers - it's original fingerprints of biomass of organic matter, that reflect molecular hydrocarbonic structure. The bulk, molecular composition of oil is initially a function of the type and maturity of the source rock from which it has been expelled, while the source rock type reflects both the nature of precursor organisms and the conditions of its deposition. Methodology used in this study included sampling, bitumen extraction, liquid-column chromatography and gas chromatography/mass spectrometry analyses. The bitumen was fractionated by column chromatography on silica gel. Non-aromatic or alifatics, aromatics and polar compounds were obtained. Alifatic were analysed by gas chromatography/mass spectrometry Percin Elmer. The hydrocarbons present in the sediments of DF and have a carbon numbers ranging from 12 through 38. The samples contain variably inputs from both terrigenous and non-terrigenous (probably marine algal) organic matter as evident in bimodal GC fingerprints of some samples. Pristane and phytane, also, occur in very high concentration in sample extracts. The relatively low Pr/Ph ratios, CPI and OEPbiomarkers distribution of the domanic samples generally

  3. PHREEQCI; a graphical user interface for the geochemical computer program PHREEQC

    Science.gov (United States)

    Charlton, Scott R.; Macklin, Clifford L.; Parkhurst, David L.

    1997-01-01

    PhreeqcI is a Windows-based graphical user interface for the geochemical computer program PHREEQC. PhreeqcI provides the capability to generate and edit input data files, run simulations, and view text files containing simulation results, all within the framework of a single interface. PHREEQC is a multipurpose geochemical program that can perform speciation, inverse, reaction-path, and 1D advective reaction-transport modeling. Interactive access to all of the capabilities of PHREEQC is available with PhreeqcI. The interface is written in Visual Basic and will run on personal computers under the Windows(3.1), Windows95, and WindowsNT operating systems.

  4. Surface and Subsurface Geochemical Monitoring of an EOR-CO2 Field: Buracica, Brazil.

    OpenAIRE

    Magnier, Caroline,; Rouchon, Virgile; Bandeira, Carlos; Goncalves, R.; Miller, D.; Dino, R.

    2012-01-01

    This paper presents a surface and subsurface geochemical survey of the Buracica EOR-CO2 field onshore Brazil. We adopted a methodology coupling the stable isotopes of carbon with noble gases to investigate the adequacy of geochemical monitoring to track deep fluid leakage at the surface. Three campaigns of CO2 flux and concentration in soils were performed to understand the CO2 variability across the field. The distribution of the CO2 soil contents between 0.8 and 14% is in great part c...

  5. Some isotopic and geochemical anomalies observed in Mexico prior to large scale earthquakes and volcanic eruptions

    Energy Technology Data Exchange (ETDEWEB)

    Cruz R, S. de la; Armienta, M.A.; Segovia A, N

    1992-05-15

    A brief account of some experiences obtained in Mexico, related with the identification of geochemical precursors of volcanic eruptions and isotopic precursors of earthquakes and volcanic activity is given. The cases of three recent events of volcanic activity and one large earthquake are discussed in the context of an active geological environment. The positive results in the identification of some geochemical precursors that helped to evaluate the eruptive potential during two volcanic crises (Tacana 1986 and Colima 1991), and the significant radon-in-soil anomalies observed during a volcanic catastrophic eruption (El Chichon, 1982) and prior to a major earthquake (Michoacan, 1985) are critically analysed. (Author)

  6. Some geochemical considerations for a potential repository site in tuff at Yucca Mountain, Nevada

    International Nuclear Information System (INIS)

    Erdal, B.R.; Bish, D.L.; Crowe, B.M.; Daniels, W.R.; Ogard, A.E.; Rundberg, R.S.; Vaniman, D.T.; Wolfsberg, K.

    1982-01-01

    The Nevada Nuclear Waste Storage Investigations, which is evaluating potential locations for a high-level waste repository at the Nevada Test Site and environs, is currently focusing its investigations on tuff, principally in Yucca Mountain, as a host rock. This paper discusses some of the geochemical investigations. Particular emphasis is placed on definition of some basic elements and necessary technical approaches for the geochemistry data acquisition and modeling program. Some site-specific tuff geochemical information that is important for site selection and repository performance will be identified and the current status of knowledge will then be discussed

  7. Geochemical aspects of environmental problems of protection of the surrounding natural environment

    International Nuclear Information System (INIS)

    Azadaliev, Dzh.A.; Azadalieva, S.Dzh.; Azadalieva, F.G.

    2004-01-01

    Full text :This article is devoted to consideration of geochemical aspects of geological problems of preservation of the environment. With this purpose various methods of the analytical geochemistry are considered here, which promote to define of a wide spectrum of geochemical parameters and characteristics. The important attention is given to consideration of radioactive elements and heavy metals, representing considerable danger to an environment, i.e. biosphere. Further the connection of a physical condition with contents of any element with environmental contamination is explained and also further methods on elimination of harmful consequences of influence of the specified elements on environment and vital functions were given [ru

  8. Basic concepts and formulations for isotope geochemical modelling of groundwater systems

    International Nuclear Information System (INIS)

    Kalin, R.M.

    1996-01-01

    This chapter describes the basic chemical principles and methodologies for geochemical models and their use in the field of isotope hydrology. Examples of calculation procedures are given on actual field data. Summary information on available PC software for geochemical modeling is included. The specific software, NETPATH, which can be used for chemical speciation, mass balance and isotope balance along a flow path in groundwater systems, is discussed at some length with an illustrative example of its application to field data. (author). Refs, 14 figs, 15 tabs

  9. Actual stage of organic geochemical knowledge from Campos and Espirito Santo basins, Brazil

    International Nuclear Information System (INIS)

    Gaglianone, P.C.; Trindade, L.A.F.

    1987-01-01

    Campos and Espirito Santo basins display several similar geochemical aspects. The microbial and other degradation processes caused changes in the composition of the oils in the reservoir rocks. The oils are biodegraded in different degrees, with the reservoir temperature developing an important role in the control of the biodegradation process. The migration pathway model is similar for Campos and Espirito Santo basins, involving the upward secondary migration through a window in the evaporitic seals. The oils passed to the marine sequence where migration and accumulation were controlled by faults, regional unconformities and by reservoirs. The geochemical correlation of oils are realized by gaseous and liquid chromatography analysis, carbon isotopes and biolabelled compounds. (author)

  10. Some isotopic and geochemical anomalies observed in Mexico prior to large scale earthquakes and volcanic eruptions

    International Nuclear Information System (INIS)

    Cruz R, S. de la; Armienta, M.A.; Segovia A, N.

    1992-05-01

    A brief account of some experiences obtained in Mexico, related with the identification of geochemical precursors of volcanic eruptions and isotopic precursors of earthquakes and volcanic activity is given. The cases of three recent events of volcanic activity and one large earthquake are discussed in the context of an active geological environment. The positive results in the identification of some geochemical precursors that helped to evaluate the eruptive potential during two volcanic crises (Tacana 1986 and Colima 1991), and the significant radon-in-soil anomalies observed during a volcanic catastrophic eruption (El Chichon, 1982) and prior to a major earthquake (Michoacan, 1985) are critically analysed. (Author)

  11. Geochemical studies of potential source minerals of radon: case studies in Hungary

    Energy Technology Data Exchange (ETDEWEB)

    Rajnai, G.; Nagy-Balogh, J.; Gal-Solymos, K.; Konc, Z.; Breitner, D.; Barabas, A.; Szabo, C. [Eotvos Univ., Lithosphere Fluid Research Lab, Dept. of Petrology and Geochemistry, Budapest (Hungary); Barabas, A. [Eotvos Univ., Dept. of Geophysics, Budapest (Hungary)

    2006-07-01

    In Hungary, during the past decade five distinct regions have been chosen to find possible explanations of the uncommonly high radon background radiation values. The main aim of the research is to study U- and Th-bearing minerals in petrographic and geochemical characters. Besides the microscopic techniques, whole rock and in situ geochemical analytical methods were applied to determine the bulk U and Th content of the studied geological samples. We assume that some of the radon measured is related to the U and Th contents of the samples. (authors)

  12. Possible uses of geochemical and isotopical investigations of ground waters in oil and gas prospecting

    International Nuclear Information System (INIS)

    Mercado, A.; Kahanovitz, Y.

    1978-07-01

    This work describes the use of geochemical investigation of ground waters for finding deep organic accumulations. It is based on the identification of abnormal values of chemical and isotopical parameters: bicarbonates, CO 2 , sulfates, carbon 13 and carbon 14. Further improvements will make this method a useful tool in oil and gas prospecting and detection as well as in the detection of geochemical anomalies. The advantages of the method are its low cost and relative rapidity; the disadvantage is that it can be carried out only when water sources are present in the exploration field. (B.G.)

  13. Rock magnetic and geochemical proxies for iron mineral diagenesis in a tropical lake: Lago Verde, Los Tuxtlas, East Central Mexico

    Science.gov (United States)

    Ortega, Beatriz; Caballero, Margarita; Lozano, Socorro; Vilaclara, Gloria; Rodríguez, Alejandro

    2006-10-01

    Magnetic and non-magnetic mineral analyses were conducted on a lacustrine sequence from Lago Verde in the tropical coast along the Gulf of Mexico that covers the last 2000 years. The site witnessed the transformation of the environment since the early Olmec societies until forest clearance in the last century. Through these analyses we investigated the processes that affected the magnetic mineralogy in order to construct a model of past environmental changes, and compare this model with the archeological record and inferred climatic changes in the northern hemisphere of tropical America. Volcanic activity has played a major influence on sediment magnetic properties, as a purveyor of Ti-magnetites/Ti-maghemites, and as a factor of instability in the environment. Anoxic reductive conditions are evident in most of Lago Verde's sedimentary record. Direct observations of magnetic minerals and ratios of geochemical (Fe, Ti), and ferrimagnetic ( χf) and paramagnetic ( χp) susceptibility ( χ) data, are used as parameters for magnetite dissolution ( χp/ χ, Fe/ χf), and precipitation ( χf/Ti) of magnetic minerals. Intense volcanic activity and anoxia are recorded before A.D. 20, leading to the formation of framboidal pyrite. Increased erosion, higher evaporation rates, lower lake levels, anoxia and reductive diagenesis in non-sulphidic conditions are inferred for laminated sediments between A.D. 20-850. This deposit matches the period of historical crisis and multiyear droughts that contributed to the collapse of the Maya civilization. Dissolution of magnetite, a high organic content and framboidal pyrite point to anoxic, sulphidic conditions and higher lake levels after A.D. 850. Higher lake levels in Lago Verde broadly coincide with the increased precipitation documented during the Medieval Warm Period (A.D. 950-1350) in the northern tropical and subtropical regions of the American continent. For the Little Ice Age (A.D. 1400-1800), the relatively moist conditions

  14. Thermal maturity of northern Appalachian Basin Devonian shales: Insights from sterane and terpane biomarkers

    Science.gov (United States)

    Hackley, Paul C.; Ryder, Robert T.; Trippi, Michael H.; Alimi, Hossein

    2013-01-01

    To better estimate thermal maturity of Devonian shales in the northern Appalachian Basin, eleven samples of Marcellus and Huron Shale were characterized via multiple analytical techniques. Vitrinite reflectance, Rock–Eval pyrolysis, gas chromatography (GC) of whole rock extracts, and GC–mass spectrometry (GCMS) of extract saturate fractions were evaluated on three transects that lie across previously documented regional thermal maturity isolines. Results from vitrinite reflectance suggest that most samples are immature with respect to hydrocarbon generation. However, bulk geochemical data and sterane and terpane biomarker ratios from GCMS suggest that almost all samples are in the oil window. This observation is consistent with the presence of thermogenic gas in the study area and higher vitrinite reflectance values recorded from overlying Pennsylvanian coals. These results suggest that vitrinite reflectance is a poor predictor of thermal maturity in early mature areas of Devonian shale, perhaps because reported measurements often include determinations of solid bitumen reflectance. Vitrinite reflectance interpretations in areas of early mature Devonian shale should be supplanted by evaluation of thermal maturity information from biomarker ratios and bulk geochemical data.

  15. Export of nutrient rich Northern Component Water preceded early Oligocene Antarctic glaciation

    Science.gov (United States)

    Coxall, Helen K.; Huck, Claire E.; Huber, Matthew; Lear, Caroline H.; Legarda-Lisarri, Alba; O'Regan, Matt; Sliwinska, Kasia K.; van de Flierdt, Tina; de Boer, Agatha M.; Zachos, James C.; Backman, Jan

    2018-03-01

    The onset of the North Atlantic Deep Water formation is thought to have coincided with Antarctic ice-sheet growth about 34 million years ago (Ma). However, this timing is debated, in part due to questions over the geochemical signature of the ancient Northern Component Water (NCW) formed in the deep North Atlantic. Here we present detailed geochemical records from North Atlantic sediment cores located close to sites of deep-water formation. We find that prior to 36 Ma, the northwestern Atlantic was stratified, with nutrient-rich, low-salinity bottom waters. This restricted basin transitioned into a conduit for NCW that began flowing southwards approximately one million years before the initial Antarctic glaciation. The probable trigger was tectonic adjustments in subarctic seas that enabled an increased exchange across the Greenland-Scotland Ridge. The increasing surface salinity and density strengthened the production of NCW. The late Eocene deep-water mass differed in its carbon isotopic signature from modern values as a result of the leakage of fossil carbon from the Arctic Ocean. Export of this nutrient-laden water provided a transient pulse of CO2 to the Earth system, which perhaps caused short-term warming, whereas the long-term effect of enhanced NCW formation was a greater northward heat transport that cooled Antarctica.

  16. Sources, extent and history of methane seepage on the continental shelf off northern Norway

    Science.gov (United States)

    Sauer, Simone; Lepland, Aivo; Chand, Shyam; Schubert, Carsten J.; Eichinger, Florian; Knies, Jochen

    2014-05-01

    Active natural hydrocarbon gas seepage was recently discovered in the Hola area on the continental shelf off Vesterålen, northern Norway. We conducted acoustic and geochemical investigations to assess the modern and past extent, source and pathways of the gas seepage . Water column echosounder surveys showed bubble plumes up to several tens of metres above the seafloor. Analyses of dissolved methane in the water column indicated slightly elevated concentrations (50 nM) close to the seafloor. To identify fluxes and origin of methane in the sediments we analysed sediment pore water chemistry, the isotopic composition of methane and of dissolved inorganic carbon (d13CCH4, d2HCH4, d13CDIC) in three closely spaced (

  17. Offshore northern Europe, the challenges

    International Nuclear Information System (INIS)

    Bergseth, S.

    1996-01-01

    This paper relates to challenges of the offshore activity in the North Sea. It is appropriate to address these challenges in the context of generating values through efficient management of resources, markets, safety and technology, as the challenges lie therein. The petroleum industry is built to turn natural resources into market value, assuring broad benefits to stake holders and shareholders. In the following, the challenges facing the industry the industry offshore Northern Europe is examined on this background

  18. Royal villas in Northern Europe

    OpenAIRE

    Iversen, Frode

    2009-01-01

    This paper concerns land use and peasant society relating to settlements, power, and state formation in Northern Europe in the period 500–1200 AD, combining archaeological and written evidence in spatial landscape studies. In the mainly rural society in the Middle Ages, political and economic power seems to have been based on control over land, including people, land, and estates. The king and his followers travelled between a limited numbers of royal villas, located in the coastal areas ...

  19. Northern Security and Global Politics

    DEFF Research Database (Denmark)

    -unipolar", indicating a period of flux and of declining US unipolar hegemony. Drawing together contributions from key thinkers in the field, Northern Security and Global Politics explores how this situation has affected the Nordic-Baltic area by addressing two broad sets of questions. First, it examines what impact....... This book will be of much interest to students of Nordic and Baltic politics, international security, foreign policy and IR....

  20. Adapting consociation to Northern Ireland

    OpenAIRE

    Coakley, John

    2010-01-01

    This paper looks at the concept of consociational government (or the principle of fully-fledged power sharing) as it has evolved in recent comparative studies of the politics of divided societies. It describes the stages through which this concept moved to the centre of the political agenda in Northern Ireland, based on contributions by policy makers, academics, journalists and others. It reviews the difficult history of efforts to translate this principle into practice, noting the challenge ...

  1. Asset dynamics in Northern Nigeria:

    OpenAIRE

    Dillon, Andrew; Quiñones, Esteban J.

    2010-01-01

    This paper examines household asset dynamics and gender-differentiated asset inequality over a 20-year period (1988–2008) in northern Nigeria. We show that the initial endowments of both household capital and livestock holdings are inconsistent with the poverty trap hypothesis but that tracking rules for households in panel surveys may lead to differences in empirical results on poverty traps. We also investigate whether initial household endowments contributed to gender-differentiated future...

  2. Computer analysis to the geochemical interpretation of soil and stream sediment data in an area of Southern Uruguay

    International Nuclear Information System (INIS)

    Spangenberg, J.

    2010-01-01

    In southern Uruguay there are several known occurrences of base metal sulphide mineralization within an area of Precambrian volcanic sedimentary rocks. Regional geochemical stream sediment reconnaissance surveys revealed new polymetallic anomalies in the same stratigraphic zone. Geochemical interpretation of multi-element data from a soil and stream sediment survey carried out in one of these anomalous areas is presented.

  3. Evaluation of the Single Dilute (0.43 M) Nitric Acid Extraction to Determine Geochemically Reactive Elements in Soil

    NARCIS (Netherlands)

    Groenenberg, Jan E.; Römkens, Paul F.A.M.; Zomeren, van André; Rodrigues, S.M.; Comans, Rob N.J.

    2017-01-01

    Recently a dilute nitric acid extraction (0.43 M) was adopted by ISO (ISO-17586:2016) as standard for extraction of geochemically reactive elements in soil and soil like materials. Here we evaluate the performance of this extraction for a wide range of elements by mechanistic geochemical

  4. Chemical pollution of northern seas

    International Nuclear Information System (INIS)

    Savinova, T.N.

    1991-01-01

    An extensive review is presented on petroleum and chlorinated hydrocarbon pollution in waters and marine organisms of the North Atlantic and of the North, Baltic, Norwegian, and Barents Seas. Data are presented on the bioaccumulation of those pollutants in the organs and tissues of sea birds and of marine biota at various trophic levels. The effects of pollutants on plankton in northern seas are discussed. Factors affecting the bioaccumulation of toxic substances in fish are also examined. It has been discovered that residual quantities of polychlorinated biphenyls, chlorinated pesticides and their metabolites, and petroleum hydrocarbons are present everywhere at all water levels in northern seas. Of particular concern is the fact that maximum concentrations of contaminants have been recorded in the most productive regions, including shelf and estuary zones, the euphotic zone, and areas of upwelling. Both individual toxic substances and their combinations disrupt normal functioning of ecosystems in northern seas, causing a change in the level of primary production and a decline in fish productivity. Pollutant accumulation in commercially valuable organisms represents a serious threat to human health. 424 refs., 13 figs., 15 tabs

  5. Cenozoic Climate Change: Geochemical Proxy Records from Deep Ocean Sediments

    Science.gov (United States)

    Billups, K.; Venti, N.

    2009-04-01

    Cenozoic climate evolved from a the warm Paleocene and Eocene ( 16 Ma) to the relatively cold conditions of the modern world via three major ice growth events first on Antarctica at the Eocene/Oligocene boundary then during the middle Miocene and finally in the Northern Hemisphere during the late Pliocene. Much of what we know about past climate change comes from the oxygen isotopic composition of benthic foraminifera. Although this proxy outlines large scale changes in the degree of polar glaciation, the absolute magnitude and the relationship between ice extent and ocean temperature cannot be uniquely determined. The recent development of foraminiferal Mg/Ca ratios as a proxy for paleotemperatures provides an opportunity to improve our understanding of climate change on both tectonic and orbital time scales. For example, paired delta18O and Mg/Ca deep water records show that expansion of ice at the Eocene/Oligocene boundary occurred in steps and was accompanied by cooling of water temperatures by about 2-3C (Lear et al., 2008; Katz et al.2008). During the middle Miocene expansion of ice predates cooling of Southern Ocean surface waters providing evidence for the importance of heat and moisture transport in Antarctic ice growth (Shevenell and Kennett, 2007). Relatively few deep sea studies have focused on late Miocene climate, and foraminiferal delta18O records do not support major oceanographic and climatic changes. Although, the late Miocene may have been a time of global cooling, especially in the circum-Antarctic region, with the establishment of a grounded West Antarctic ice sheet. The early Pliocene, in contrast, has been the focus of much research because of the relevance to understanding intervals of sustained global climatic warmth with near modern-day tectonic configuration, warm upwelling regions, and elevated CO2 levels with respect to the pre-industrial atmosphere. The deep sea delta18O record, however, suggests that Antarctic ice sheet size remained

  6. Provenance of Austroalpine basement metasediments: tightening up Early Palaeozoic connections between peri-Gondwanan domains of central Europe and Northern Africa

    Science.gov (United States)

    Siegesmund, S.; Oriolo, S.; Heinrichs, T.; Basei, M. A. S.; Nolte, N.; Hüttenrauch, F.; Schulz, B.

    2018-03-01

    New U-Pb and Lu-Hf detrital zircon data together with whole-rock geochemical and Sm-Nd data were obtained for paragneisses of the Austroalpine basement south of the Tauern Window. Geochemically immature metasediments of the Northern-Defereggen-Petzeck (Ötztal-Bundschuh nappe system) and Defereggen (Drauzug-Gurktal nappe system) groups contain zircon age populations which indicate derivation mainly from Pan-African orogens. Younger, generally mature metasediments of the Gailtal Metamorphic Basement (Drauzug-Gurktal nappe system), Thurntaler Phyllite Group (Drauzug-Gurktal nappe system) and Val Visdende Formation (South Alpine Basement) were possibly derived from more distant sources. Their significantly larger abundances of pre-Pan-African zircons record a more advanced stage of downwearing of the Pan-African belts and erosion of older basement when the Austroalpine terrane was part of the Early Palaeozoic Northern Gondwana passive margin. Most zircon age spectra are dominated by Ediacaran sources, with lesser Cryogenian, Tonian and Stenian contributions and subordinate Paleoproterozoic and Neoarchean ages. These age patterns are similar to those recorded by Cambro-Ordovician sedimentary sequences in northeastern Africa between Libya and Jordan, and in some pre-Variscan basement inliers of Europe (e.g. Dinarides-Hellenides, Alboran microplate). Therefore, the most likely sources seem to be in the northeastern Saharan Metacraton and the Northern Arabian-Nubian Shield (Sinai), further supported by whole-rock Sm-Nd and zircon Lu-Hf data.

  7. Geochemical baseline level and function and contamination of phosphorus in Liao River Watershed sediments of China.

    Science.gov (United States)

    Liu, Shaoqing; Wang, Jing; Lin, Chunye; He, Mengchang; Liu, Xitao

    2013-10-15

    The quantitative assessment of P contamination in sediments is a challenge due to sediment heterogeneity and the lacking of geochemical background or baseline levels. In this study, a procedure was proposed to determine the average P background level and P geochemical baseline level (GBL) and develop P geochemical baseline functions (GBF) for riverbed sediments of the Liao River Watershed (LRW). The LRW has two river systems - the Liao River System (LRS) and the Daliao River System (DRS). Eighty-eight samples were collected and analyzed for P, Al, Fe, Ca, organic matter, pH, and texture. The results show that Fe can be used as a better particle-size proxy to construct the GBF of P (P (mg/kg) = 39.98 + 166.19 × Fe (%), R(2) = 0.835, n = 66). The GBL of P was 675 mg/kg, while the average background level of P was 355 mg/kg. Noting that many large cities are located in the DRS watershed, most of the contaminated sites were located within the DRS and the riverbed sediments were more contaminated by P in the DRS watershed than in the LRS watershed. The geochemical background and baseline information of P are of great importance in managing P levels within the LRW. Copyright © 2013 Elsevier Ltd. All rights reserved.

  8. Influence of ammonia on leaching behaviors of incineration fly ash and its geochemical modeling

    DEFF Research Database (Denmark)

    Astrup, Thomas Fruergaard; Guan, Zhen Zhen; Chen, De Zhen

    2013-01-01

    of dissolved organic carbon (DOC) and metals from incineration fly ash in the pH range of 3.66-12.44 with an active ammonia spike. A geochemical modeling software Visual MINTEQ was adopted to calculate the chemical speciation of metals under the leaching conditions to reveal the mechanism behind the impacts...

  9. Geochemical assessment of nuclear waste isolation. Report of activities during fiscal year 1982

    Energy Technology Data Exchange (ETDEWEB)

    1983-07-01

    The status of the following investigations is reported: canister/overpack-backfill chemical interactions and mechanisms; backfill and near-field host rock chemical interactions mechanisms; far-field host rock geochemical interactions; verification and improvement of predictive algorithms for radionuclide migration; and geologic systems as analogues for long-term radioactive waste isolation.

  10. Secondary geochemical reactions in hydrothermal energy harnessing; Geochemische Folgereaktionen bei der hydrogeothermalen Energiegewinnung

    Energy Technology Data Exchange (ETDEWEB)

    Kuehn, M.

    1996-12-01

    This thesis is in six parts: description of geothermal energy harnessing, analytics, geochemical-thermodynamic modellings, experimental investigations, discussion of results, summary. (HW) [Deutsch] Die vorliegende Dissertationsschrift gliedert sich in 6 Teile: - Beschreibung der geothermischen Energienutzung - Analytik - geochemische-thermodynamische Modellierungen - experimentelle Untersuchungen - Diskussion der Ergebnisse - Zusammenfassung. (HW)

  11. Geochemical modeling of the nuclear-waste repository system. A status report

    International Nuclear Information System (INIS)

    Deutsch, W.J.

    1980-12-01

    The primary objective of the geochemical modeling task is to develop an understanding of the waste-repository geochemical system and provide a valuable tool for estimating future states of that system. There currently exists a variety of computer codes which can be used in geochemical modeling studies. Some available codes contain the framework for simulating a natural chemical system and estimating, within limits, the response of that system to environmental changes. By data-base enhancement and code development, this modeling technique can be even more usefully applied to a nuclear-waste repository. In particular, thermodynamic data on elements not presently in the data base but identified as being of particular hazard in the waste-repository system, need to be incorporated into the code to estimate the near-field as well as the far-field reactions during a hypothetical breach. A reaction-path-simulation code, which estimates the products of specific rock/water reactions, has been tested using basalt and ground water. Results show that the mass-transfer capabilities of the code will be useful in chemical-evolution studies and scenario analyses. The purpose of this report is to explain the status of geochemical modeling as it currently applies to the chemical system of a hypothetical nuclear-waste repository in basalt and to present the plan proposed for further developmet and application

  12. Geochemical constraints on the evolution of mafic and felsic rocks in ...

    Indian Academy of Sciences (India)

    Granites are emplaced later, crosscutting the volcanic sequence and are probably products of fractional crystallization of basaltic magma. The present work characterizes the geochemical characteristics of the magmatic rocks comprising of basalt, andesite, rhyolite, tuff, and granite of the area. Tholeiitic trend for basalt and ...

  13. The alkali-silica reaction: mineralogical and geochemical aspects of some Dutch concretes and Norwegian mylonites

    NARCIS (Netherlands)

    Broekmans, M.A.T.M.

    2002-01-01

    Maarten Broekmans has studied the alkali-silica reaction in two Dutch concretes by means of optical microscopy, geochemical analyses on bulk material and after selective digestion in acid, and with element mapping in polished thin sections. He furthermore characterized the nature of the

  14. Interaction of density flow and geochemical processes on islands in the Okavanga Delta, Botswana

    DEFF Research Database (Denmark)

    Bauer-Gottwein, Peter; Langer, T.; Prommer, H.

    2006-01-01

    This paper analyses the interactions of density driven flow and geochemical reactions under evapo-concentration. A multi-species hydrodynamic flow and transport simulation model (SEAWAT) is coupled to a batch reaction model (PHREEQC) to analyze densitydriven flow on islands in the Okavango Delta,...

  15. Estimation of Supraglacial Dust and Debris Geochemical Composition via Satellite Reflectance and Emissivity

    Directory of Open Access Journals (Sweden)

    Kimberly Casey

    2012-09-01

    Full Text Available We demonstrate spectral estimation of supraglacial dust, debris, ash and tephra geochemical composition from glaciers and ice fields in Iceland, Nepal, New Zealand and Switzerland. Surface glacier material was collected and analyzed via X-ray fluorescence spectroscopy (XRF and X-ray diffraction (XRD for geochemical composition and mineralogy. In situ data was used as ground truth for comparison with satellite derived geochemical results. Supraglacial debris spectral response patterns and emissivity-derived silica weight percent are presented. Qualitative spectral response patterns agreed well with XRF elemental abundances. Quantitative emissivity estimates of supraglacial SiO2 in continental areas were 67% (Switzerland and 68% (Nepal, while volcanic supraglacial SiO2 averages were 58% (Iceland and 56% (New Zealand, yielding general agreement. Ablation season supraglacial temperature variation due to differing dust and debris type and coverage was also investigated, with surface debris temperatures ranging from 5.9 to 26.6 C in the study regions. Applications of the supraglacial geochemical reflective and emissive characterization methods include glacier areal extent mapping, debris source identification, glacier kinematics and glacier energy balance considerations.

  16. The potential of lacquer-peel soil profiles for palaeo-geochemical analysis using XRF analysis

    NARCIS (Netherlands)

    Arnoldussen, Stijn; van Os, B.J.H.

    2015-01-01

    This paper discusses the suitability of hand-held XRF analysis to extract palaeo-geochemical information from lacquer-peel soil sections that have been taken to document pedological information at geological and archaeological sites. This not only allows the study of sections from archaeological and

  17. A Novel Field Apparatus for Conducting Linked Geochemical-Microbiological Experiments in Shallow Sediments

    Science.gov (United States)

    Smith, E. W.; Voytek, M. A.; McGuire, J. T.; Cozzarelli, I. M.; Kneeshaw, T. A.; Baez-Cazull, S. E.

    2008-12-01

    Collecting in-situ experimental data for microbially mediated geochemical reactions is complex because it is difficult to assess the impact of the heterogeneity of natural systems. Specifically it is often difficult to constrain the degree of interaction between the pore water collected for geochemical analysis and a sampled microbial population. The newly developed apparatus, called a Native Organism Geochemical Experimentation Enclosure (NOGEE), provides the means to measure changes in well defined geochemical solutions that have been in direct contact with a known in-situ microbial population. The sampling apparatus is similar to a drive-point well. A short screened chamber (~60 ml) at the tip houses a polycarbonate sponge, which serves as a substrate for colonization by native microorganisms when it is open to the surrounding sediment. Following a colonization period dependent on season and temperature, the sponge chamber is closed to the surrounding environment by lowering an inner pipe and amended test solutions are introduced from the surface via tubing. An advantage to this method over laboratory microcosms is that the in-situ setting provides a natural, intrinsic control over environmental variables and minimizes disturbance to the system. To date, NOGEE's have been used to evaluate kinetic controls on sulfate reduction. Experimental results showed changing rates of sulfate reduction coincident with changes in microbial population and demonstrate the utility of using NOGEEs to quantify linkages between geochemistry and microbiology in complex natural environments.

  18. Data for the geochemical investigation of UMTRAP designated site at Green River, Utah

    International Nuclear Information System (INIS)

    Markos, G.; Bush, K.J.

    1983-09-01

    This report contains the geochemical data and the methods of data collection from the former tailings site at Green River, Utah. Data are from a one-time sampling of waters and solid material from the background, the area adjacent to the site, and the site. The water samples were analyzed for selected major and trace elements. 3 refs., 2 figs., 1 tab

  19. Instrumental neutron and photon activation analyses of selected geochemical reference materials

    Czech Academy of Sciences Publication Activity Database

    Mizera, Jiří; Řanda, Z.

    2010-01-01

    Roč. 284, č. 1 (2010), s. 157-163 ISSN 0236-5731 Institutional research plan: CEZ:AV0Z30460519 Keywords : neutron activation analysis * photon activation analysis * geochemical reference materials Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders OBOR OECD: Analytical chemistry Impact factor: 0.777, year: 2010

  20. Instrumental neutron and photon activation analyses of selected geochemical reference materials

    Czech Academy of Sciences Publication Activity Database

    Mizera, Jiří; Řanda, Zdeněk

    2010-01-01

    Roč. 284, č. 1 (2010), s. 157-163 ISSN 0236-5731 R&D Projects: GA AV ČR IAA300130706 Institutional research plan: CEZ:AV0Z10480505 Keywords : neutron activation analysis * photon activation analysis * geochemical reference materials Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 0.777, year: 2010

  1. Geochemical mapping in polluted floodplains using handheld XRF, geophysical imaging, and geostatistics

    Czech Academy of Sciences Publication Activity Database

    Hošek, Michal; Matys Grygar, Tomáš; Popelka, J.; Kiss, T.; Elznicová, J.; Faměra, Martin

    2017-01-01

    Roč. 19, APR (2017) ISSN 1607-7962. [EGU General Assembly 2017. 23.04.2017-28.04.2017, Vienna] Institutional support: RVO:61388980 Keywords : Dipole electromagneting profilling * electric resistivity tomography * floodplain contamination * geochemical mapping Subject RIV: DD - Geochemistry http://meetingorganizer.copernicus.org/EGU2017/EGU2017-3573-3.pdf

  2. Geochemical modelling of hydrogen gas migration in an unsaturated bentonite buffer

    NARCIS (Netherlands)

    Sedighi, M.; Thomas, H.R.; Al Masum, S.; Vardon, P.J.; Nicholson, D.; Chen, Q.

    2014-01-01

    This paper presents an investigation of the transport and fate of hydrogen gas through compacted bentonite buffer. Various geochemical reactions that may occur in the multiphase and multicomponent system of the unsaturated bentonite buffer are considered. A reactive gas transport model, developed

  3. Establishing geochemical background variation and threshold values for 59 elements in Australian surface soil.

    Science.gov (United States)

    Reimann, Clemens; de Caritat, Patrice

    2017-02-01

    During the National Geochemical Survey of Australia over 1300 top (0-10cm depth) and bottom (~60-80cm depth) sediment samples (including ~10% field duplicates) were collected from the outlet of 1186 catchments covering 81% of the continent at an average sample density of 1 site/5200km 2 . The Australian surface soil. Different methods of obtaining geochemical threshold values, which differentiate between background and those samples with unusually high element concentrations and requiring attention, are presented and compared to Western Australia's 'ecological investigation levels' (EILs) established for 14 PTEs. For Mn and V these EILs are so low that an unrealistically large proportion (~24%) of the sampled sites would need investigation in Australia. For the 12 remaining elements (As, Ba, Cd, Co, Cr, Cu, Hg, Mo, Ni, Pb, Sn and Zn) few sample sites require investigation and as most of these are located far from human activity centres, they potentially suggest either minor local contamination or mineral exploration potential rather than pollution. No major diffuse source of contamination by PTEs affects Australian soil at the continental scale. Of the statistical methods used to establish geochemical threshold values, the most pertinent results come from identifying breaks in cumulative probability distributions, the Tukey inner fence and the 98th percentile. Geochemical threshold values for 59 elements, including emerging 'high-tech' critical elements such as lanthanides, Be, Ga or Ge, for which no EILs currently exist, are presented. Crown Copyright © 2016. Published by Elsevier B.V. All rights reserved.

  4. Geochemical indicators for use in the computation of critical loads and dynamic risk assessments

    NARCIS (Netherlands)

    Vries, de W.; Posch, M.; Sverdrup, H.U.; Larssen, T.; Wit, H.A.; Bobbink, R.; Hettelingh, J.P.

    2015-01-01

    This chapter provides an overview of geochemical indicators for nitrogen (N), acidity, and metals in soil and water (soil solution, ground water and surface water) in view of their impacts on different endpoints (tree growth/health, human health, soil biodiversity etc.). Relevant indicators for N

  5. Geochemical landscape strategy in monitoring the areas contaminated by the Chernobyl radionuclides

    International Nuclear Information System (INIS)

    Korobova, E.M.; Linnik, V.G.

    1993-01-01

    The Chernobyl accident led to radionuclide contamination of vast areas that now need to be monitored; the development of a regional land use strategy is now needed. Landscape geochemistry enables us to structure, classify and map the environmental factors responsible for the redistribution of radionuclides (i.e. soil-forming rocks and soil properties, vegetation cover, types of ground water migration, and vertical and lateral geochemical barriers). Combined with land use information, regional geochemical landscape maps serve as the basis to map in toposequence conditions of mass migration and accumulation in natural and cultivated landscapes. Such mapping makes it easier to choose representative monitoring sites. This type of mapping is also helpful to interrelate and extrapolate the data already obtained on radionuclides' environmental migration for different groups of geochemical landscapes with similar types of contamination, migration and accumulation patterns. A geochemical landscape approach is demonstrated using the example of part of the Bryansk region (Russia), which is considerably contaminated with 134 Cs and 137 Cs

  6. Stream sediment geochemical survey of an area around Dass, N.E. ...

    African Journals Online (AJOL)

    Stream sediment geochemical survey was carried out in Dass area to determine possible dispersion train for Pb, Cu, Co, Ni and Zn. A total of 114 active stream sediment samples were collected over an area of 60km2. The samples were treated with hot HNO3 and analysed for Pb, Cu, Co, Ni, Zn, Mn, Mg, Ca, and Fe.

  7. An evaluation of geochemical models of bentonite pore water evolution

    International Nuclear Information System (INIS)

    Savage, D.; Watson, C.E.; Wilson, J.C.; Arthur, R.C.; Stroemberg, B.

    2010-01-01

    (Donnan exclusion?) which inhibited diffusion of solutes to greater depths in the experiments. In conclusion, the modelling does not support the view that because smectite dissolution is slow, it is a process of minor importance in the geochemical evolution of the EBS. The effects of smectite dissolution on the chemistry of bentonite pore waters would be essentially undetectable over time scales of a few years, but when both reaction kinetics and precipitation of secondary phases are included in the simulations, significant changes in solution chemistry and mineralogy are predicted to occur over time scales that are relevant to EBS evolution (hundreds to thousands of years). The simulations are of a scoping nature and do not fully account for uncertainties related to the variable chemistry of the smectite clays, the nature of porosity in compacted clays, the reactive surface area of smectite, and the thermodynamic properties of clay minerals. Studies of natural systems could provide a new perspective on these uncertainties, and provide approaches that could be used to resolve them. (authors)

  8. Devonian alkaline magmatic belt along the northern margin of the North China Block: Petrogenesis and tectonic implications

    Science.gov (United States)

    Zhang, Qi-Qi; Zhang, Shuan-Hong; Zhao, Yue; Liu, Jian-Min

    2018-03-01

    Some Devonian magmatic rocks have been identified from the northern margin of the North China Block (NCB) in recent years. However, their petrogenesis and tectonic setting are still highly controversial. Here we present new geochronological, Sr-Nd-Hf isotopic and whole-rock chemical data on several newly identified and previously reported Devonian alkaline complexes, including mafic-ultramafic rocks (pyroxenites and gabbros), alkaline rocks (syenites, monzonites) and alkaline granites in the northern NCB. We firstly identified some mafic-ultramafic rocks coeval with monzonite and quartz monzonite in the Sandaogou and Wulanhada alkaline intrusions. New zircon U-Pb dating of 16 samples from the Baicaigou, Gaojiacun, Sandaogou, Wulanhada and Chifeng alkaline intrusions combined with previous geochronological results indicate that the Devonian alkaline rocks emplaced during the early-middle Devonian at around 400-380 Ma and constitute an E-W-trending alkaline magmatic belt that extend ca. 900 km long along the northern margin of the NCB. Whole-rock geochemical and Sr-Nd-Hf isotopic data reveal that the Devonian alkaline rocks were mainly originated from partial melting of a variably enriched lithospheric mantle with different involvement of ancient lower crustal component and fractional crystallization. The Devonian alkaline magmatic belt rocks in the northern NCB are characterized by very weak or no deformations and were most likely related to post-collision extension after arc-continent collision between the Bainaimiao island arc and the northern margin of North China Craton during the latest Silurian. Partial melting of subcontinental lithospheric mantle to produce the Devonian alkaline magmatic rocks suggests that the northern North China Craton has an inhomogeneous, variably enriched subcontinental lithospheric mantle and was characterized by significant vertical crustal growth during the Devonian period.

  9. Pteridophyta collected in Northern Nigeria and Northern Cameroon

    Directory of Open Access Journals (Sweden)

    Jan kornaś

    2014-01-01

    Full Text Available 25 species of Pteridophyta were collected in Northern Nigeria (mainly the Lake Chad Basin and the Mandara Mts. and in the neighbouring parts of Cameroon. 11 of them have not been recorded previously from this area: Isoetes schweinfurthii A. Br. in Bak., Selaginella tenerrima A. Br. ex Kuhn, Ophioglossum gomenzianum Welw. ex A. Br., Marsilea coromandeliana Willd., M. distorta A. Br., M. nubica A. Br., M. subterranea Lepr. ex A. Br., Azolla africana Desv., Ceratopteris richardii Brogn., Adiantum capillus-veneris Linn., and Actiniopleris semiflabellata Pic. Ser.

  10. Geochemical processes assessed by Rare Earth Elements fractionation at “Laguna Verde” acidic-sulphate crater lake (Azufral volcano, Colombia)

    International Nuclear Information System (INIS)

    Inguaggiato, Claudio; Burbano, Viviana; Rouwet, Dmitri; Garzón, Gustavo

    2017-01-01

    The geochemical behaviour of major elements, Fe, Al, Mn, and Rare Earth Elements (REE) was investigated in the “Laguna Verde” acidic crater lake of Azufral volcano (Colombia). The cold lake water (T close to 10 °C) is sulphate-dominated, due to absorption and oxidation of H 2 S (pH 2.1–2.7, Eh 196–260 mV), and Na-enriched (Total Dissolved Solids 0.79 g L −1 ). The total amount of REE dissolved in the lake ranges from 3.3 to 9.1 ppb. The REE patterns normalized to the local rocks show a Light Rare Earth Elements (LREE) depletion quite constant in the 15 samples. Similar patterns were already found in the acidic sulphate springs of Nevado del Ruiz volcano-hydrothermal system, caused by the precipitation of alunite and jarosite, absorbing LREE and hence removing them from solution. Alunite and jarosite minerals are not oversaturated at chemical-physical conditions within the lake itself, but alunite becomes oversaturated for temperatures above ≈100 °C, reigning in the underlying hydrothermal system. Water temperatures close to 75 °C were found in the northern part of the lake. Coupling the distribution of REE in lake water (LREE depleted) and the saturation indexes, we suggest that the distribution of REE in the lake water is the result of the alunite precipitation in the northern part of the lake and/or in the deeper hydrothermal system. The acidic hydrothermal fluids mobilize the REE with contents up to ≈5 orders of magnitude higher than seawater; acidic-hydrothermal systems, such as acidic crater lakes, can hence be considered potential REE “reservoirs”. - Highlights: • Acidic crater lakes can be considered potential Rare Earth Elements reservoirs. • Alunite precipitation removes Light Rare Earth Elements. • Rare Earth Elements identify geochemical processes in volcano-hydrothermal systems.

  11. New soil composition data for Europe and Australia: demonstrating comparability, identifying continental-scale processes and learning lessons for global geochemical mapping.

    Science.gov (United States)

    Reimann, Clemens; de Caritat, Patrice

    2012-02-01

    New geochemical data from two continental-scale soil surveys in Europe and Australia are compared. Internal project standards were exchanged to assess comparability of analytical results. The total concentration of 26 oxides/elements (Al2O3, As, Ba, CaO, Ce, Co, Cr, Fe2O3, Ga, K2O, MgO, MnO, Na2O, Nb, Ni, P2O5, Pb, Rb, SiO2, Sr, Th, TiO2, V, Y, Zn, and Zr), Loss On Ignition (LOI) and pH are demonstrated to be comparable. Additionally, directly comparable data for 14 elements in an aqua regia extraction (Ag, As, Bi, Cd, Ce, Co, Cs, Cu, Fe, La, Li, Mn, Mo, and Pb) are provided for both continents. Median soil compositions are close, though generally Australian soils are depleted in all elements with the exception of SiO2 and Zr. This is interpreted to reflect the generally longer and, in places, more intense weathering in Australia. Calculation of the Chemical Index of Alteration (CIA) gives a median value of 72% for Australia compared to 60% for Europe. Element concentrations vary over 3 (and up to 5) orders of magnitude. Several elements (total As and Ni; aqua regia As, Co, Bi, Li, Pb) have a lower element concentration by a factor of 2-3 in the soils of northern Europe compared to southern Europe. The break in concentration coincides with the maximum extent of the last glaciation. The younger soils of northern Europe are more similar to the Australian soils than the older soils from southern Europe. In Australia, the central region with especially high SiO2 concentrations is commonly depleted in many elements. The new data define the natural background variation for two continents on both hemispheres based on real data. Judging from the experience of these two continental surveys, it can be concluded that analytical quality is the key requirement for the success of global geochemical mapping. Copyright © 2011 Elsevier B.V. All rights reserved.

  12. A geostatistical method applied to the geochemical study of the Chichinautzin Volcanic Field in Mexico

    Science.gov (United States)

    Robidoux, P.; Roberge, J.; Urbina Oviedo, C. A.

    2011-12-01

    The origin of magmatism and the role of the subducted Coco's Plate in the Chichinautzin volcanic field (CVF), Mexico is still a subject of debate. It has been established that mafic magmas of alkali type (subduction) and calc-alkali type (OIB) are produced in the CVF and both groups cannot be related by simple fractional crystallization. Therefore, many geochemical studies have been done, and many models have been proposed. The main goal of the work present here is to provide a new tool for the visualization and interpretation of geochemical data using geostatistics and geospatial analysis techniques. It contains a complete geodatabase built from referred samples over the 2500 km2 area of CVF and its neighbour stratovolcanoes (Popocatepetl, Iztaccihuatl and Nevado de Toluca). From this database, map of different geochemical markers were done to visualise geochemical signature in a geographical manner, to test the statistic distribution with a cartographic technique and highlight any spatial correlations. The distribution and regionalization of the geochemical signatures can be viewed in a two-dimensional space using a specific spatial analysis tools from a Geographic Information System (GIS). The model of spatial distribution is tested with Linear Decrease (LD) and Inverse Distance Weight (IDW) interpolation technique because they best represent the geostatistical characteristics of the geodatabase. We found that ratio of Ba/Nb, Nb/Ta, Th/Nb show first order tendency, which means visible spatial variation over a large scale area. Monogenetic volcanoes in the center of the CVF have distinct values compare to those of the Popocatepetl-Iztaccihuatl polygenetic complex which are spatially well defined. Inside the Valley of Mexico, a large quantity of monogenetic cone in the eastern portion of CVF has ratios similar to the Iztaccihuatl and Popocatepetl complex. Other ratios like alkalis vs SiO2, V/Ti, La/Yb, Zr/Y show different spatial tendencies. In that case, second

  13. Geochemical orientation for mineral exploration in the Hashemite Kingdom of Jordan

    Science.gov (United States)

    Overstreet, W.C.; Grimes, D.J.; Seitz, J.F.

    1982-01-01

    This report is a supplement to previous accounts of geochemical exploration conducted in the Hashemite Kingdom of Jordan by the Natural Resources Authority of the Royal Government of Jordan and the U.S. Geological Survey. The field work on which this report is based was sponsored by the U.S. Agency for International Development, U.S. Department of State. Procedures used in collecting various kinds of rocks, ores, slags, eluvial and alluvial sediments, heavy-mineral concentrates, and organic materials for use as geochemical sample media are summarized, as are the laboratory procedures followed for the analysis of these sample materials by semiquantitative spectrographic, atomic absorption, fluorometric, and X-ray diffraction methods. Geochemical evaluations of the possibilities for economic mineral deposits in certain areas are presented. The results of these preliminary investigations open concepts for further use in geochemical exploration in the search for metallic mineral deposits in Jordan. Perhaps the most desirable new activity would be hydrogeochemical exploration for uranium and base metals, accompanied by interpretation of such remote-sensing data as results of airborne radiometric surveys and computer-enhanced LANDSAT imagery. For more conventional approaches to geochemical exploration, however, several fundamental problems regarding proper choice of geochemical sample media for different geologic and geographic parts of the Country must be solved before effective surveys can be made. The present results also show that such common geochemical exploration techniques as the determination of the trace-element contents of soils, plant ash, and slags have direct application also toward the resolution of several archaeological problems in Jordan. These include the relation of trace-elements chemistry of local soils to the composition of botanic remains, the trace-elements composition of slags to the technological development of the extractive metallurgy of

  14. Relationships between Cd and Zn partitioning and geochemical composition in sediments from Chinese rivers.

    Science.gov (United States)

    Peng, Shu-Heng; Wang, Wen-xiong; Chen, Jingsheng

    2005-02-01

    Adsorption isotherm experiments were conducted to determine the distribution coefficients (Kd) for Cd and Zn between water and sediments from twelve rivers in eastern China. The low metal concentration (sediment-water system enabled the direct measurements of linear adsorption isotherms. When other solution parameters, such as ionic strength, were controlled, sediment geochemical characteristics were the major factors affecting metal distribution. The Kd was highly dependent on the total organic carbon contents and Fe-Mn oxide at pH = 7.0, and was affected significantly by the carbonate content in the sediments due to its control of pH. The Kd of the Huanghe sediments, which had the highest carbonate concentration (13.1%), increased sharply for both Cd and Zn when the pH increased. A quantitative model using the experimentally obtained phase distribution coefficients (Kd)i was applied to study the effects of different geochemical phases in the sediment on metal distributions. The (Kd)i of carbonate was correlated significantly with the carbonate content in the sediment, whereas the (Kd)i of total organic carbon (TOC) and Fe-Mn oxide phases were highly pH dependent. Using the (Kd)i for each geochemical phase, the calculation showed that about 91% and 85% of sorbed Cd and Zn, respectively, added to the batch reactors were distributed among the three major geochemical phases: TOC, Fe-Mn oxide, and carbonate. Total organic carbon was the most important binding phase for Cd, and Fe-Mn oxide for Zn. Furthermore, adsorption experiments with simulated sediments show the importance of interactions between different geochemical phases on metal partitioning.

  15. A Geochemical Reaction Model for Titration of Contaminated Soil and Groundwater at the Oak Ridge Reservation

    Science.gov (United States)

    Zhang, F.; Parker, J. C.; Gu, B.; Luo, W.; Brooks, S. C.; Spalding, B. P.; Jardine, P. M.; Watson, D. B.

    2007-12-01

    This study investigates geochemical reactions during titration of contaminated soil and groundwater at the Oak Ridge Reservation in eastern Tennessee. The soils and groundwater exhibits low pH and high concentrations of aluminum, calcium, magnesium, manganese, various trace metals such as nickel and cobalt, and radionuclides such as uranium and technetium. The mobility of many of the contaminant species diminishes with increasing pH. However, base additions to increase pH are strongly buffered by various precipitation/dissolution and adsorption/desorption reactions. The ability to predict acid-base behavior and associated geochemical effects is thus critical to evaluate remediation performance of pH manipulation strategies. This study was undertaken to develop a practical but generally applicable geochemical model to predict aqueous and solid-phase speciation during soil and groundwater titration. To model titration in the presence of aquifer solids, an approach proposed by Spalding and Spalding (2001) was utilized, which treats aquifer solids as a polyprotic acid. Previous studies have shown that Fe and Al-oxyhydroxides strongly sorb dissolved Ni, U and Tc species. In this study, since the total Fe concentration is much smaller than that of Al, only ion exchange reactions associated with Al hydroxides are considered. An equilibrium reaction model that includes aqueous complexation, precipitation, ion exchange, and soil buffering reactions was developed and implemented in the code HydroGeoChem 5.0 (HGC5). Comparison of model results with experimental titration curves for contaminated groundwater alone and for soil- water systems indicated close agreement. This study is expected to facilitate field-scale modeling of geochemical processes under conditions with highly variable pH to develop practical methods to control contaminant mobility at geochemically complex sites.

  16. An overview of the geochemical code MINTEQ: Applications to performance assessment for low-level wastes

    International Nuclear Information System (INIS)

    Peterson, S.R.; Opitz, B.E.; Graham, M.J.; Eary, L.E.

    1987-03-01

    The MINTEQ geochemical computer code, developed at the Pacific Northwest Laboratory (PNL), integrates many of the capabilities of its two immediate predecessors, MINEQL and WATEQ3. The MINTEQ code will be used in the Special Waste Form Lysimeters-Arid program to perform the calculations necessary to simulate (model) the contact of low-level waste solutions with heterogeneous sediments of the interaction of ground water with solidified low-level wastes. The code can calculate ion speciation/solubilitya, adsorption, oxidation-reduction, gas phase equilibria, and precipitation/dissolution of solid phases. Under the Special Waste Form Lysimeters-Arid program, the composition of effluents (leachates) from column and batch experiments, using laboratory-scale waste forms, will be used to develop a geochemical model of the interaction of ground water with commercial, solidified low-level wastes. The wastes being evaluated include power-reactor waste streams that have been solidified in cement, vinyl ester-styrene, and bitumen. The thermodynamic database for the code was upgraded preparatory to performing the geochemical modeling. Thermodynamic data for solid phases and aqueous species containing Sb, Ce, Cs, or Co were added to the MINTEQ database. The need to add these data was identified from the characterization of the waste streams. The geochemical model developed from the laboratory data will then be applied to predict the release from a field-lysimeter facility that contains full-scale waste samples. The contaminant concentrations migrating from the waste forms predicted using MINTEQ will be compared to the long-term lysimeter data. This comparison will constitute a partial field validation of the geochemical model

  17. The Northern Manitoba Mining Academy

    Science.gov (United States)

    Alexandre, Paul

    2017-04-01

    The Northern Manitoba Mining Academy (NMMA, miningacademy.ca) is a new educational institution located in Flin Flon, Manitoba. It is associated with the University College of the North and is specifically intended to serve the needs of the Northern Manitoban communities with regards to job creation by providing training in a variety of mining, construction, and exploration related areas. NMMA's mission is to provide innovative and responsible solutions for the creation of a knowledgeable, skilled, and sustainable workforce within a vibrant, mineral-rich resource industry. It facilitates strategic training initiatives and research activities in order to strengthen the social, economic, and environmental benefits of a robust mining and resources sector. In terms of education, NMMA offers its own programs, mostly short courses in health and safety, courses organized by the University College of the North (wilderness safety, prospecting, and exploration), and courses organized in association with provincial Industries-Based Safety Programs and Associations (a variety of construction-related trades). However, the programming is not limited to those courses already on the syllabus: the Academy operates on open-doors policy and welcomes people with their unique and diverse needs; it prides itself in its ability to tailor or create specific on-demand courses and deliver them locally in the North. The Northern Manitoba Mining Academy also provides access to its world-class facilities for field-based undergraduate courses, as well as graduate students and researchers doing field work. Full sample preparation facilities are offered to students and scientists in all natural and environmental sciences.

  18. Earliest Urbanism in Northern Mesopotamia

    DEFF Research Database (Denmark)

    Skuldbøl, Tim Boaz Bruun

    fieldwork on the mound of Tell Brak and in its immediate surroundings, as well as the author’s own new comparative ceramic studies, which provide the basis for improvements in chronology of the Late Chalcolithic period in northern Mesopotamia. This extensive empirical material is presented as archaeological...... reports, which are integrated to form Part 1 of the dissertation. In Part 2, a set of theoretical approaches to the rise of cities is considered, in light of the new information from Tell Brak, with a view to suggesting future approaches towards the urbanization process. Total printed: 470 pages incl...

  19. Calculating competition in thinned northern hardwoods.

    Science.gov (United States)

    Sharon A. Winsauer; James A. Mattson

    1992-01-01

    Describes four methods of calculating competition to individual trees and compares their effectiveness in explaining the 3-year growth response of northern hardwoods after various mechanized thinning practices.

  20. Giant Reed Distribution - Northern California [ds333

    Data.gov (United States)

    California Department of Resources — The Arundo Distribution layer is a compilation of Arundo donax observations in northern and central California, obtained from several sources, including Arundo...