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Sample records for nonlinear viscoelastic properties

  1. Nonlinear viscoelastic properties of tissue assessed by ultrasound.

    Science.gov (United States)

    Sinkus, Ralph; Bercoff, Jeremy; Tanter, Mickaël; Gennisson, Jean-Luc; El-Khoury, Carl; Servois, Vincent; Tardivon, Anne; Fink, Mathias

    2006-11-01

    A technique to assess qualitatively the presence of higher-order viscoelastic parameters is presented. Low-frequency, monochromatic elastic waves are emitted into the material via an external vibrator. The resulting steady-state motion is detected in real time via an ultra fast ultrasound system using classical, one-dimensional (1-D) ultrasound speckle correlation for motion estimation. Total data acquisition lasts only for about 250 ms. The spectrum of the temporal displacement data at each image point is used for analysis. The presence of nonlinear effects is detected by inspection of the ratio of the second harmonics amplitude with respect to the total amplitude summed up to the second harmonic. Results from a polyacrylamide-based phantom indicate a linear response (i.e., the absence of higher harmonics) for this type of material at 65 Hz mechanical vibration frequency and about 100 microm amplitude. A lesion, artificially created by injection of glutaraldehyde into a beef specimen, shows the development of higher harmonics at the location of injection as a function of time. The presence of upper harmonics is clearly evident at the location of a malignant lesion within a mastectomy.

  2. Modelling nonlinear viscoelastic behaviours of loudspeaker suspensions-like structures

    Science.gov (United States)

    Maillou, Balbine; Lotton, Pierrick; Novak, Antonin; Simon, Laurent

    2018-03-01

    Mechanical properties of an electrodynamic loudspeaker are mainly determined by its suspensions (surround and spider) that behave nonlinearly and typically exhibit frequency dependent viscoelastic properties such as creep effect. The paper aims at characterizing the mechanical behaviour of electrodynamic loudspeaker suspensions at low frequencies using nonlinear identification techniques developed in recent years. A Generalized Hammerstein based model can take into account both frequency dependency and nonlinear properties. As shown in the paper, the model generalizes existing nonlinear or viscoelastic models commonly used for loudspeaker modelling. It is further experimentally shown that a possible input-dependent law may play a key role in suspension characterization.

  3. Viscoelastic Properties of Human Tracheal Tissues.

    Science.gov (United States)

    Safshekan, Farzaneh; Tafazzoli-Shadpour, Mohammad; Abdouss, Majid; Shadmehr, Mohammad B

    2017-01-01

    The physiological performance of trachea is highly dependent on its mechanical behavior, and therefore, the mechanical properties of its components. Mechanical characterization of trachea is key to succeed in new treatments such as tissue engineering, which requires the utilization of scaffolds which are mechanically compatible with the native human trachea. In this study, after isolating human trachea samples from brain-dead cases and proper storage, we assessed the viscoelastic properties of tracheal cartilage, smooth muscle, and connective tissue based on stress relaxation tests (at 5% and 10% strains for cartilage and 20%, 30%, and 40% for smooth muscle and connective tissue). After investigation of viscoelastic linearity, constitutive models including Prony series for linear viscoelasticity and quasi-linear viscoelastic, modified superposition, and Schapery models for nonlinear viscoelasticity were fitted to the experimental data to find the best model for each tissue. We also investigated the effect of age on the viscoelastic behavior of tracheal tissues. Based on the results, all three tissues exhibited a (nonsignificant) decrease in relaxation rate with increasing the strain, indicating viscoelastic nonlinearity which was most evident for cartilage and with the least effect for connective tissue. The three-term Prony model was selected for describing the linear viscoelasticity. Among different models, the modified superposition model was best able to capture the relaxation behavior of the three tracheal components. We observed a general (but not significant) stiffening of tracheal cartilage and connective tissue with aging. No change in the stress relaxation percentage with aging was observed. The results of this study may be useful in the design and fabrication of tracheal tissue engineering scaffolds.

  4. Non-linear Response and Viscoelastic Properties of Lipid-Coated Microbubbles: DSPC versus DPPC

    NARCIS (Netherlands)

    van Rooij, T.; Luan, Y.; Renaud, G.; van der Steen, A.F.W.; Versluis, Michel; de Jong, N.; Kooiman, K.

    2015-01-01

    For successful in vivo contrast-enhanced ultrasound imaging (CEUS) and ultrasound molecular imaging, detailed knowledge of stability and acoustical properties of the microbubbles is essential. Here, we compare these aspects of lipid-coated microbubbles that have either

  5. Nonlinear viscoelasticity of pre-compressed layered polymeric composite under oscillatory compression

    KAUST Repository

    Xu, Yangguang

    2018-05-03

    Describing nonlinear viscoelastic properties of polymeric composites when subjected to dynamic loading is essential for development of practical applications of such materials. An efficient and easy method to analyze nonlinear viscoelasticity remains elusive because the dynamic moduli (storage modulus and loss modulus) are not very convenient when the material falls into nonlinear viscoelastic range. In this study, we utilize two methods, Fourier transform and geometrical nonlinear analysis, to quantitatively characterize the nonlinear viscoelasticity of a pre-compressed layered polymeric composite under oscillatory compression. We discuss the influences of pre-compression, dynamic loading, and the inner structure of polymeric composite on the nonlinear viscoelasticity. Furthermore, we reveal the nonlinear viscoelastic mechanism by combining with other experimental results from quasi-static compressive tests and microstructural analysis. From a methodology standpoint, it is proved that both Fourier transform and geometrical nonlinear analysis are efficient tools for analyzing the nonlinear viscoelasticity of a layered polymeric composite. From a material standpoint, we consequently posit that the dynamic nonlinear viscoelasticity of polymeric composites with complicated inner structures can also be well characterized using these methods.

  6. Three-sphere swimmer in a nonlinear viscoelastic medium

    KAUST Repository

    Curtis, Mark P.; Gaffney, Eamonn A.

    2013-01-01

    are determined analytically in both a Newtonian Stokes fluid and a zero Reynolds number, nonlinear, Oldroyd-B viscoelastic fluid with Deborah numbers of order one (or less), highlighting the effects of viscoelasticity on the net displacement of swimmer

  7. Quasistatic nonlinear viscoelasticity and gradient flows

    OpenAIRE

    Ball, John M.; Şengül, Yasemin

    2014-01-01

    We consider the equation of motion for one-dimensional nonlinear viscoelasticity of strain-rate type under the assumption that the stored-energy function is λ-convex, which allows for solid phase transformations. We formulate this problem as a gradient flow, leading to existence and uniqueness of solutions. By approximating general initial data by those in which the deformation gradient takes only finitely many values, we show that under suitable hypotheses on the stored-energy function the d...

  8. LINEAR AND NONLINEAR VISCOELASTIC CHARACTERIZATION OF PROTON EXCHANGE MEMBRANES AND STRESS MODELING FOR FUEL CELL APPLICATIONS

    OpenAIRE

    Patankar, Kshitish A

    2009-01-01

    In this dissertation, the effect of temperature and humidity on the viscoelastic and fracture properties of proton exchange membranes (PEM) used in fuel cell applications was studied. Understanding and accurately modeling the linear and nonlinear viscoelastic constitutive properties of a PEM are important for making hygrothermal stress predictions in the cyclic temperature and humidity environment of operating fuel cells. In this study, Nafion® NRE 211, Gore-Select® 57, and Ion Power® N111...

  9. Nonlinear Viscoelastic Mechanism for Aftershock Triggering and Decay

    Science.gov (United States)

    Shcherbakov, R.; Zhang, X.

    2016-12-01

    Aftershocks are ubiquitous in nature. They are the manifestation of relaxation phenomena observed in various physical systems. In one prominent example, they typically occur after large earthquakes. They also occur in other natural or experimental systems, for example, in solar flares, in fracture experiments on porous materials and acoustic emissions, after stock market crashes, in the volatility of stock prices returns, in internet traffic variability and e-mail spamming, to mention a few. The observed aftershock sequences usually obey several well defined non-trivial empirical laws in magnitude, temporal, and spatial domains. In many cases their characteristics follow scale-invariant distributions. The occurrence of aftershocks displays a prominent temporal behavior due to time-dependent mechanisms of stress and/or energy transfer. In this work, we consider a slider-block model to mimic the behavior of a seismogenic fault. In the model, we introduce a nonlinear viscoelastic coupling mechanism to capture the essential characteristics of crustal rheology and stress interaction between the blocks and the medium. For this purpose we employ nonlinear Kelvin-Voigt elements consisting of an elastic spring and a dashpot assembled in parallel to introduce viscoelastic coupling between the blocks and the driving plate. By mapping the model into a cellular automaton we derive the functional form of the stress transfer mechanism in the model. We show that the nonlinear viscoelasticity plays a critical role in triggering of aftershocks. It explains the functional form of the Omori-Utsu law and gives physical interpretation of its parameters. The proposed model also suggests that the power-law rheology of the fault gauge and underlying lower crust and upper mantle control the decay rate of aftershocks. To verify this, we analyze several prominent aftershock sequences to estimate their decay rates and correlate with the rheological properties of the underlying lower crust and

  10. Stability of non-linear constitutive formulations for viscoelastic fluids

    CERN Document Server

    Siginer, Dennis A

    2014-01-01

    Stability of Non-linear Constitutive Formulations for Viscoelastic Fluids provides a complete and up-to-date view of the field of constitutive equations for flowing viscoelastic fluids, in particular on their non-linear behavior, the stability of these constitutive equations that is their predictive power, and the impact of these constitutive equations on the dynamics of viscoelastic fluid flow in tubes. This book gives an overall view of the theories and attendant methodologies developed independently of thermodynamic considerations as well as those set within a thermodynamic framework to derive non-linear rheological constitutive equations for viscoelastic fluids. Developments in formulating Maxwell-like constitutive differential equations as well as single integral constitutive formulations are discussed in the light of Hadamard and dissipative type of instabilities.

  11. Nonlinear Viscoelastic Rheology and the Occurrence of Aftershocks

    Science.gov (United States)

    Shcherbakov, R.; Zhang, X.

    2017-12-01

    Aftershocks are ubiquitous in nature. They are the manifestation of relaxation phenomena observed in various physical systems. In one prominent example, they typically occur after large earthquakes. The observed aftershock sequences usually obey several well defined non-trivial empirical laws in magnitude, temporal, and spatial domains. In many cases their characteristics follow scale-invariant distributions. The occurrence of aftershocks displays a prominent temporal behavior due to time-dependent mechanisms of stress and/or energy transfer. There are compelling evidences that the lower continental crust and upper mantle are governed by various solid state creep mechanisms. Among those mechanisms a power-law viscous flow was suggested to explain the postseismic surface deformation after large earthquakes. In this work, we consider a slider-block model to mimic the behavior of a seismogenic fault. In the model, we introduce a nonlinear viscoelastic coupling mechanism to capture the essential characteristics of crustal rheology and stress interaction between the blocks and the medium. For this purpose we employ nonlinear Kelvin-Voigt elements consisting of an elastic spring and a dashpot assembled in parallel to introduce viscoelastic coupling between the blocks and the driving plate. By mapping the model into a cellular automaton we derive the functional form of the stress transfer mechanism in the model. We show that the nonlinear viscoelasticity plays a critical role in triggering of aftershocks. It explains the functional form of the Omori-Utsu law and gives physical interpretation of its parameters. The proposed model also suggests that the power-law rheology of the fault gauge and underlying lower crust and upper mantle controls the decay rate of aftershocks. To verify this, we analyze several prominent aftershock sequences to estimate their decay rates and correlate with the rheological properties of the underlying lower crust and mantle, which were estimated

  12. Viscoelastic properties of cellular polypropylene ferroelectrets

    Czech Academy of Sciences Publication Activity Database

    Gaal, M.; Bovtun, Viktor; Stark, W.; Erhard, A.; Yakymenko, Y.; Kreutzbruck, M.

    2016-01-01

    Roč. 119, č. 12 (2016), s. 1-12, č. článku 125101. ISSN 0021-8979 R&D Projects: GA ČR GA15-08389S Institutional support: RVO:68378271 Keywords : ferroelectrets * viscoelastic properties * ultrasonic Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.068, year: 2016

  13. Nonlinear viscoelastic behavior of shells of revolution under arbitrary loading

    International Nuclear Information System (INIS)

    Leonard, J.W.; Arbaki-Kanjoori, F.

    1975-01-01

    The requirement of some structural components such as propulsion systems and gas turbines to operate at high temperatures and pressures make the accurate evaluation of the creep phenomenon exigent (in fast breeder reactor for example). For the expected increases in operating temperatures and pressures, it becomes necessary to perform a thorough analysis of integral structural components of nuclear power plants throughout their life span. Since a large class of structures operating at elevated temperatures are composed of rotationally symmetric shells, a solution technique can be developed which involves the numerical integration of the governing shell equations. This method has been successfully applied to the static and dynamic analysis of thin elastic shells of revolution and for some cases of inelastic material behavior. It has been shown to render solutions efficiently and accurately, usually with only a fraction of computer time and storage requirements and data manipulation that is required for other numerical schemes such as the finite element method. Furthermore, the numerical integration method allows more flexibility for varying the integration step lengths than does the finite difference method and can provide uniform accuracy throughout the analysis. For nonlinear viscoelastic behavior the numerical integration technique is expected to provide similar efficiency to that obtained for the elastic problems. The computer program developed can accept time variation of material properties. Since a single form for the material constitutive law cannot encompass all materials, provisions are made so that the analysis of a very large class of material behavior can be accomplished

  14. Three-sphere swimmer in a nonlinear viscoelastic medium

    KAUST Repository

    Curtis, Mark P.

    2013-04-10

    A simple model for a swimmer consisting of three colinearly linked spheres attached by rods and oscillating out of phase to break reciprocal motion is analyzed. With a prescribed forcing of the rods acting on the three spheres, the swimming dynamics are determined analytically in both a Newtonian Stokes fluid and a zero Reynolds number, nonlinear, Oldroyd-B viscoelastic fluid with Deborah numbers of order one (or less), highlighting the effects of viscoelasticity on the net displacement of swimmer. For instance, the model predicts that the three-sphere swimmer with a sinusoidal, but nonreciprocal, forcing cycle within an Oldroyd-B representation of a polymeric Boger fluid moves a greater distance with enhanced efficiency in comparison with its motility in a Newtonian fluid of the same viscosity. Furthermore, the nonlinear contributions to the viscoelastic constitutive relation, while dynamically nontrivial, are predicted a posteriori to have no effect on swimmer motility at leading order, given a prescribed forcing between spheres. © 2013 American Physical Society.

  15. Viscoelastic property identification from waveform reconstruction

    Science.gov (United States)

    Leymarie, N.; Aristégui, C.; Audoin, B.; Baste, S.

    2002-05-01

    An inverse method is proposed for the determination of the viscoelastic properties of material plates from the plane-wave transmitted acoustic field. Innovations lie in a two-step inversion scheme based on the well-known maximum-likelihood principle with an analytic signal formulation. In addition, establishing the analytical formulations of the plate transmission coefficient we implement an efficient and slightly noise-sensitive process suited to both very thin plates and strongly dispersive media.

  16. Development and validation of a viscoelastic and nonlinear liver model for needle insertion

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, Yo [Waseda University, Consolidated Research Institute for Advanced Science and Medical Care, Shinjuku, Tokyo (Japan); Onishi, Akinori; Hoshi, Takeharu; Kawamura, Kazuya [Waseda University, Graduate School of Science and Engineering, Shinjuku (Japan); Hashizume, Makoto [Kyushu University Hospital, Center for the Integration of Advanced Medicine and Innovative Technology, Fukuoka (Japan); Fujie, Masakatsu G. [Waseda University, Graduate School of Science and Engineering, Faculty of Science and Engineering, Shinjuku (Japan)

    2009-01-15

    The objective of our work is to develop and validate a viscoelastic and nonlinear physical liver model for organ model-based needle insertion, in which the deformation of an organ is estimated and predicted, and the needle path is determined with organ deformation taken into consideration. First, an overview is given of the development of the physical liver model. The material properties of the liver considering viscoelasticity and nonlinearity are modeled based on the measured data collected from a pig's liver. The method to develop the liver model using FEM is also shown. Second, the experimental method to validate the model is explained. Both in vitro and in vivo experiments that made use of a pig's liver were conducted for comparison with the simulation using the model. Results of the in vitro experiment showed that the model reproduces nonlinear and viscoelastic response of displacement at an internally located point with high accuracy. For a force up to 0.45 N, the maximum error is below 1 mm. Results of the in vivo experiment showed that the model reproduces the nonlinear increase of load upon the needle during insertion. Based on these results, the liver model developed and validated in this work reproduces the physical response of a liver in both in vitro and in vivo situations. (orig.)

  17. Nonlinear viscoelasticity of pre-compressed layered polymeric composite under oscillatory compression

    KAUST Repository

    Xu, Yangguang; Tao, Ran; Lubineau, Gilles

    2018-01-01

    remains elusive because the dynamic moduli (storage modulus and loss modulus) are not very convenient when the material falls into nonlinear viscoelastic range. In this study, we utilize two methods, Fourier transform and geometrical nonlinear analysis

  18. A phenomenological constitutive model for the nonlinear viscoelastic responses of biodegradable polymers

    KAUST Repository

    Khan, Kamran

    2012-11-09

    We formulate a constitutive framework for biodegradable polymers that accounts for nonlinear viscous behavior under regimes with large deformation. The generalized Maxwell model is used to represent the degraded viscoelastic response of a polymer. The large-deformation, time-dependent behavior of viscoelastic solids is described using an Ogden-type hyperviscoelastic model. A deformation-induced degradation mechanism is assumed in which a scalar field depicts the local state of the degradation, which is responsible for the changes in the material\\'s properties. The degradation process introduces another timescale (the intrinsic material clock) and an entropy production mechanism. Examples of the degradation of a polymer under various loading conditions, including creep, relaxation and cyclic loading, are presented. Results from parametric studies to determine the effects of various parameters on the process of degradation are reported. Finally, degradation of an annular cylinder subjected to pressure is also presented to mimic the effects of viscoelastic arterial walls (the outer cylinder) on the degradation response of a biodegradable stent (the inner cylinder). A general contact analysis is performed. As the stiffness of the biodegradable stent decreases, stress reduction in the stented viscoelastic arterial wall is observed. The integration of the proposed constitutive model with finite element software could help a designer to predict the time-dependent response of a biodegradable stent exhibiting finite deformation and under complex mechanical loading conditions. © 2012 Springer-Verlag Wien.

  19. The viscoelastic properties of the cervical mucus plug

    DEFF Research Database (Denmark)

    Kjær Bastholm, Sara; Becher, Naja; Stubbe, Peter Reimer

    2013-01-01

    The objective of this study was to characterize the viscoelastic properties of cervical mucus plugs (CMPs) shed during labor at term. Spontaneously shed cervical mucus plugs from healthy women in active labor, were tested. The viscoelastic properties of cervical mucus plugs were investigated...... with using frequency and stress sweep experiments within the linear viscoelastic region. Random-effects regression was used for statistical analysis. The CMPs are solid-like viscoelastic structures and the elastic modulus dominated the viscous modulus at all frequencies. These rheological characteristics...

  20. A phenomenological constitutive model for the nonlinear viscoelastic responses of biodegradable polymers

    KAUST Repository

    Khan, Kamran; El Sayed, Tamer S.

    2012-01-01

    We formulate a constitutive framework for biodegradable polymers that accounts for nonlinear viscous behavior under regimes with large deformation. The generalized Maxwell model is used to represent the degraded viscoelastic response of a polymer

  1. The viscoelastic properties of the cervical mucus plug

    DEFF Research Database (Denmark)

    Bastholm, Sara K.; Becher, Naja; Stubbe, Peter Reimer

    2014-01-01

    labor. MethodsViscoelastic properties of CMPs were investigated with a dynamic oscillatory rheometer using frequency and stress sweep experiments within the linear viscoelastic region. Main outcome measuresThe rheological variables obtained were as follows: elastic modulus (G), viscous modulus (G......ObjectiveTo characterize the viscoelastic properties of cervical mucus plugs (CMPs) shed during labor at term. DesignExperimental research. SettingDepartment of Obstetrics and Gynecology, Aarhus University Hospital, Denmark. Population/SampleSpontaneously shed CMPs from 18 healthy women in active...

  2. Time Domain Modeling and Simulation of Nonlinear Slender Viscoelastic Beams Associating Cosserat Theory and a Fractional Derivative Model

    Directory of Open Access Journals (Sweden)

    Adailton S. Borges

    Full Text Available Abstract A broad class of engineering systems can be satisfactory modeled under the assumptions of small deformations and linear material properties. However, many mechanical systems used in modern applications, like structural elements typical of aerospace and petroleum industries, have been characterized by increased slenderness and high static and dynamic loads. In such situations, it becomes indispensable to consider the nonlinear geometric effects and/or material nonlinear behavior. At the same time, in many cases involving dynamic loads, there comes the need for attenuation of vibration levels. In this context, this paper describes the development and validation of numerical models of viscoelastic slender beam-like structures undergoing large displacements. The numerical approach is based on the combination of the nonlinear Cosserat beam theory and a viscoelastic model based on Fractional Derivatives. Such combination enables to derive nonlinear equations of motion that, upon finite element discretization, can be used for predicting the dynamic behavior of the structure in the time domain, accounting for geometric nonlinearity and viscoelastic damping. The modeling methodology is illustrated and validated by numerical simulations, the results of which are compared to others available in the literature.

  3. Elastic and Viscoelastic Stresses of Nonlinear Rotating Functionally Graded Solid and Annular Disks with Gradually Varying Thickness

    Directory of Open Access Journals (Sweden)

    Allam M. N. M.

    2017-12-01

    Full Text Available Analytical and numerical nonlinear solutions for rotating variable-thickness functionally graded solid and annular disks with viscoelastic orthotropic material properties are presented by using the method of successive approximations.Variable material properties such as Young’s moduli, density and thickness of the disk, are first introduced to obtain the governing equation. As a second step, the method of successive approximations is proposed to get the nonlinear solution of the problem. In the third step, the method of effective moduli is deduced to reduce the problem to the corresponding one of a homogeneous but anisotropic material. The results of viscoelastic stresses and radial displacement are obtained for annular and solid disks of different profiles and graphically illustrated. The calculated results are compared and the effects due to many parameters are discussed.

  4. A constitutive model for developing blood clots with various compositions and their nonlinear viscoelastic behavior.

    Science.gov (United States)

    van Kempen, Thomas H S; Donders, Wouter P; van de Vosse, Frans N; Peters, Gerrit W M

    2016-04-01

    The mechanical properties determine to a large extent the functioning of a blood clot. These properties depend on the composition of the clot and have been related to many diseases. However, the various involved components and their complex interactions make it difficult at this stage to fully understand and predict properties as a function of the components. Therefore, in this study, a constitutive model is developed that describes the viscoelastic behavior of blood clots with various compositions. Hereto, clots are formed from whole blood, platelet-rich plasma and platelet-poor plasma to study the influence of red blood cells, platelets and fibrin, respectively. Rheological experiments are performed to probe the mechanical behavior of the clots during their formation. The nonlinear viscoelastic behavior of the mature clots is characterized using a large amplitude oscillatory shear deformation. The model is based on a generalized Maxwell model that accurately describes the results for the different rheological experiments by making the moduli and viscosities a function of time and the past and current deformation. Using the same model with different parameter values enables a description of clots with different compositions. A sensitivity analysis is applied to study the influence of parameter variations on the model output. The relative simplicity and flexibility make the model suitable for numerical simulations of blood clots and other materials showing similar behavior.

  5. Dynamic assessment of nonlinear typical section aeroviscoelastic systems using fractional derivative-based viscoelastic model

    Science.gov (United States)

    Sales, T. P.; Marques, Flávio D.; Pereira, Daniel A.; Rade, Domingos A.

    2018-06-01

    Nonlinear aeroelastic systems are prone to the appearance of limit cycle oscillations, bifurcations, and chaos. Such problems are of increasing concern in aircraft design since there is the need to control nonlinear instabilities and improve safety margins, at the same time as aircraft are subjected to increasingly critical operational conditions. On the other hand, in spite of the fact that viscoelastic materials have already been successfully used for the attenuation of undesired vibrations in several types of mechanical systems, a small number of research works have addressed the feasibility of exploring the viscoelastic effect to improve the behavior of nonlinear aeroelastic systems. In this context, the objective of this work is to assess the influence of viscoelastic materials on the aeroelastic features of a three-degrees-of-freedom typical section with hardening structural nonlinearities. The equations of motion are derived accounting for the presence of viscoelastic materials introduced in the resilient elements associated to each degree-of-freedom. A constitutive law based on fractional derivatives is adopted, which allows the modeling of temperature-dependent viscoelastic behavior in time and frequency domains. The unsteady aerodynamic loading is calculated based on the classical linear potential theory for arbitrary airfoil motion. The aeroelastic behavior is investigated through time domain simulations, and subsequent frequency transformations, from which bifurcations are identified from diagrams of limit cycle oscillations amplitudes versus airspeed. The influence of the viscoelastic effect on the aeroelastic behavior, for different values of temperature, is also investigated. The numerical simulations show that viscoelastic damping can increase the flutter speed and reduce the amplitudes of limit cycle oscillations. These results prove the potential that viscoelastic materials have to increase aircraft components safety margins regarding aeroelastic

  6. Characterization of a viscoelastic heterogeneous object with an effective model by nonlinear full waveform inversion

    Science.gov (United States)

    Mesgouez, A.

    2018-05-01

    The determination of equivalent viscoelastic properties of heterogeneous objects remains challenging in various scientific fields such as (geo)mechanics, geophysics or biomechanics. The present investigation addresses the issue of the identification of effective constitutive properties of a binary object by using a nonlinear and full waveform inversion scheme. The inversion process, without any regularization technique or a priori information, aims at minimizing directly the discrepancy between the full waveform responses of a bi-material viscoelastic cylindrical object and its corresponding effective homogeneous object. It involves the retrieval of five constitutive equivalent parameters. Numerical simulations are performed in a laboratory-scale two-dimensional configuration: a transient acoustic plane wave impacts the object and the diffracted fluid pressure, solid stress or velocity component fields are determined using a semi-analytical approach. Results show that the retrieval of the density and of the real parts of both the compressional and the shear wave velocities have been carried out successfully regarding the number and location of sensors, the type of sensors, the size of the searching space, the frequency range of the incident plane pressure wave, and the change in the geometric or mechanical constitution of the bi-material object. The retrieval of the imaginary parts of the wave velocities can reveal in some cases the limitations of the proposed approach.

  7. Linear viscoelastic properties of aging suspensions

    NARCIS (Netherlands)

    Purnomo, E.H.; Purnomo, E.H; van den Ende, Henricus T.M.; Mellema, J.; Mugele, Friedrich Gunther

    2006-01-01

    We have examined the linear viscoelastic behavior of poly-N-isopropylacrylamide (PNIPAM) microgel suspensions in order to obtain insight in the aging processes in these densely packed suspensions at various temperatures below the volume transition temperature. The system is found to display a strong

  8. A time-domain finite element model reduction method for viscoelastic linear and nonlinear systems

    Directory of Open Access Journals (Sweden)

    Antônio Marcos Gonçalves de Lima

    Full Text Available AbstractMany authors have shown that the effective design of viscoelastic systems can be conveniently carried out by using modern mathematical models to represent the frequency- and temperature-dependent behavior of viscoelastic materials. However, in the quest for design procedures of real-word engineering structures, the large number of exact evaluations of the dynamic responses during iterative procedures, combined with the typically high dimensions of large finite element models, makes the numerical analysis very costly, sometimes unfeasible. It is especially true when the viscoelastic materials are used to reduce vibrations of nonlinear systems. As a matter of fact, which the resolution of the resulting nonlinear equations of motion with frequency- and temperature-dependent viscoelastic damping forces is an interesting, but hard-to-solve problem. Those difficulties motivate the present study, in which a time-domain condensation strategy of viscoelastic systems is addressed, where the viscoelastic behavior is modeled by using a four parameter fractional derivative model. After the discussion of various theoretical aspects, the exact and reduced time responses are calculated for a three-layer sandwich plate by considering nonlinear boundary conditions.

  9. Viscoelastic properties of microfibrillated cellulose (MFC) produced from agricultural residue corn stover

    Science.gov (United States)

    The rheological properties of microfibrillated cellulose (MFC) produced from agricultural residue corn stover were investigated. The corn stover MFC gels exhibited concentration-dependent viscoelastic properties. Higher corn stover MFC concentrations resulted in stronger viscoelastic properties. Th...

  10. The development and validation of a numerical integration method for non-linear viscoelastic modeling

    Science.gov (United States)

    Ramo, Nicole L.; Puttlitz, Christian M.

    2018-01-01

    Compelling evidence that many biological soft tissues display both strain- and time-dependent behavior has led to the development of fully non-linear viscoelastic modeling techniques to represent the tissue’s mechanical response under dynamic conditions. Since the current stress state of a viscoelastic material is dependent on all previous loading events, numerical analyses are complicated by the requirement of computing and storing the stress at each step throughout the load history. This requirement quickly becomes computationally expensive, and in some cases intractable, for finite element models. Therefore, we have developed a strain-dependent numerical integration approach for capturing non-linear viscoelasticity that enables calculation of the current stress from a strain-dependent history state variable stored from the preceding time step only, which improves both fitting efficiency and computational tractability. This methodology was validated based on its ability to recover non-linear viscoelastic coefficients from simulated stress-relaxation (six strain levels) and dynamic cyclic (three frequencies) experimental stress-strain data. The model successfully fit each data set with average errors in recovered coefficients of 0.3% for stress-relaxation fits and 0.1% for cyclic. The results support the use of the presented methodology to develop linear or non-linear viscoelastic models from stress-relaxation or cyclic experimental data of biological soft tissues. PMID:29293558

  11. Fully coupled heat conduction and deformation analyses of nonlinear viscoelastic composites

    KAUST Repository

    Khan, Kamran

    2012-05-01

    This study presents an integrated micromechanical model-finite element framework for analyzing coupled heat conduction and deformations of particle-reinforced composite structures. A simplified micromechanical model consisting of four sub-cells, i.e., one particle and three matrix sub-cells is formulated to obtain the effective thermomechanical properties and micro-macro field variables due to coupled heat conduction and nonlinear thermoviscoelastic deformation of a particulate composite that takes into account the dissipation of energy from the viscoelastic constituents. A time integration algorithm for simultaneously solving the equations that govern heat conduction and thermoviscoelastic deformations of isotropic homogeneous materials is developed. The algorithm is then integrated to the proposed micromechanical model. A significant temperature generation due to the dissipation effect in the viscoelastic matrix was observed when the composite body is subjected to cyclic mechanical loadings. Heat conduction due to the dissipation of the energy cannot be ignored in predicting the factual temperature and deformation fields within the composite structure, subjected to cyclic loading for a long period. A higher creep resistant matrix material or adding elastic particles can lower the temperature generation. Our analyses suggest that using particulate composites and functionally graded materials can reduce the heat generation due to energy dissipation. © 2012 Elsevier Ltd.

  12. Earthquake Cycle Simulations with Rate-and-State Friction and Linear and Nonlinear Viscoelasticity

    Science.gov (United States)

    Allison, K. L.; Dunham, E. M.

    2016-12-01

    We have implemented a parallel code that simultaneously models both rate-and-state friction on a strike-slip fault and off-fault viscoelastic deformation throughout the earthquake cycle in 2D. Because we allow fault slip to evolve with a rate-and-state friction law and do not impose the depth of the brittle-to-ductile transition, we are able to address: the physical processes limiting the depth of large ruptures (with hazard implications); the degree of strain localization with depth; the relative partitioning of fault slip and viscous deformation in the brittle-to-ductile transition zone; and the relative contributions of afterslip and viscous flow to postseismic surface deformation. The method uses a discretization that accommodates variable off-fault material properties, depth-dependent frictional properties, and linear and nonlinear viscoelastic rheologies. All phases of the earthquake cycle are modeled, allowing the model to spontaneously generate earthquakes, and to capture afterslip and postseismic viscous flow. We compare the effects of a linear Maxwell rheology, often used in geodetic models, with those of a nonlinear power law rheology, which laboratory data indicates more accurately represents the lower crust and upper mantle. The viscosity of the Maxwell rheology is set by power law rheological parameters with an assumed a geotherm and strain rate, producing a viscosity that exponentially decays with depth and is constant in time. In contrast, the power law rheology will evolve an effective viscosity that is a function of the temperature profile and the stress state, and therefore varies both spatially and temporally. We will also integrate the energy equation for the thermomechanical problem, capturing frictional heat generation on the fault and off-fault viscous shear heating, and allowing these in turn to alter the effective viscosity.

  13. Design and numerical implementation of a 3-D non-linear viscoelastic constitutive model for brain tissue during impact

    NARCIS (Netherlands)

    Brands, D.W.A.; Peters, G.W.M.; Bovendeerd, P.H.M.

    2004-01-01

    Finite Element (FE) head models are often used to understand mechanical response of the head and its contents during impact loading in the head. CurrentFE models do not account for non-linear viscoelastic material behavior of brain tissue. We developed a new non-linear viscoelastic material model

  14. Nonlinear shear wave in a non Newtonian visco-elastic medium

    Energy Technology Data Exchange (ETDEWEB)

    Banerjee, D.; Janaki, M. S.; Chakrabarti, N. [Saha Institute of Nuclear Physics, 1/AF Bidhannagar, Calcutta 700 064 (India); Chaudhuri, M. [Max-Planck-Institut fuer extraterrestrische Physik, 85741 Garching (Germany)

    2012-06-15

    An analysis of nonlinear transverse shear wave has been carried out on non-Newtonian viscoelastic liquid using generalized hydrodynamic model. The nonlinear viscoelastic behavior is introduced through velocity shear dependence of viscosity coefficient by well known Carreau-Bird model. The dynamical feature of this shear wave leads to the celebrated Fermi-Pasta-Ulam problem. Numerical solution has been obtained which shows that initial periodic solutions reoccur after passing through several patterns of periodic waves. A possible explanation for this periodic solution is given by constructing modified Korteweg de Vries equation. This model has application from laboratory to astrophysical plasmas as well as in biological systems.

  15. Dilational viscoelastic properties of fluid interfaces - III mixed surfactant systems

    Energy Technology Data Exchange (ETDEWEB)

    Djabbarah, N.F.; Wasan, D.T.

    1982-01-01

    The surface viscosity and elasticity of solutions of mixed surfactants were determined using the longitudinal wave technique combined with tracer particle measurements. The recent analysis of Maru et al., which was restricted to insoluble monolayers and to monolayers adsorbed from a single surfactant solution, has now been extended to multicomponent solutions. This analysis can be used not only to estimate the ''net'' viscoelastic properties at gas-liquid interfaces but also to estimate the composition as well as the intrinsic viscoelastic properties. Furthermore, when accompanied by separate measurements of shear viscoelastic properties, the above analysis can be used for the determination of dilational viscosity and elasticity. Surface viscoelasticity measurements were conducted on aqueous solutions of sodium lauryl sulfate and sodium lauryl sulfate-lauryl alcohol. Net surface viscosity and elasticity of sodium lauryl sulfate solutions increased with bulk concentration and reached a maximum at a concentration in the neighborhood of the critical micelle concentration. The presence of small amount of lauryl alcohol caused almost an order of magnitude increase in intrinsic surface viscosity and a similar increase in compositional surface elasticity. A comparison between the values of intrinsic surface viscosity and those of surface shear viscosity indicated that surface dilational viscosity exceeds surface shear viscosity by at least two orders of magnitude. These appear to be the first set of data presented hitherto for the surface dilational properties in addition to surface shear properties for the same mixed surfactant systems.

  16. Nonlinear wave breaking in self-gravitating viscoelastic quantum fluid

    Energy Technology Data Exchange (ETDEWEB)

    Mitra, Aniruddha, E-mail: anibabun@gmail.com [Center for Plasma Studies, Department of Instrumentation Science, Jadavpur University, Kolkata, 700 032 (India); Roychoudhury, Rajkumar, E-mail: rajdaju@rediffmail.com [Advanced Centre for Nonlinear and Complex Phenomena, 1175 Survey Park, Kolkata 700075 (India); Department of Mathematics, Bethune College, Kolkata 700006 (India); Bhar, Radhaballav [Center for Plasma Studies, Department of Instrumentation Science, Jadavpur University, Kolkata, 700 032 (India); Khan, Manoranjan, E-mail: mkhan.ju@gmail.com [Center for Plasma Studies, Department of Instrumentation Science, Jadavpur University, Kolkata, 700 032 (India)

    2017-02-12

    The stability of a viscoelastic self-gravitating quantum fluid has been studied. Symmetry breaking instability of solitary wave has been observed through ‘viscosity modified Ostrovsky equation’ in weak gravity limit. In presence of strong gravitational field, the solitary wave breaks into shock waves. Response to a Gaussian perturbation, the system produces quasi-periodic short waves, which in terns predicts the existence of gravito-acoustic quasi-periodic short waves in lower solar corona region. Stability analysis of this dynamical system predicts gravity has the most prominent effect on the phase portraits, therefore, on the stability of the system. The non-existence of chaotic solution has also been observed at long wavelength perturbation through index value theorem. - Highlights: • In weak gravitational field, viscoelastic quantum fluid exhibits symmetry breaking instability. • Gaussian perturbation produces quasi-periodic gravito-acoustic waves into the system. • There exists no chaotic state of the system against long wavelength perturbations.

  17. Nonlinear dynamic analysis and state space representation of a manipulator under viscoelastic material conditions

    Directory of Open Access Journals (Sweden)

    Esfandiar, H.

    2013-05-01

    Full Text Available In this paper, based on the VoigtKelvin constitutive model, nonlinear dynamic modelling and state space representation of a viscoelastic beam acting as a flexible robotic manipulator is investigated. Complete nonlinear dynamic modelling of a viscoelastic beam without premature linearisation of dynamic equations is developed. The adopted method is capable of reproducing nonlinear dynamic effects, such as beam stiffening due to centrifugal and Coriolis forces induced by rotation of the joints. Structural damping effects on the models dynamic behaviour are also shown. A reliable model for a viscoelastic beam is subsequently presented. The governing equations of motion are derived using Hamiltons principle, and using the finite difference method, nonlinear partial differential equations are reduced to ordinary differential equations. For the purpose of flexible manipulator control, the standard form of state space equations for the viscoelastic link and the actuator is obtained. Simulation results indicate substantial improvements in dynamic behaviour, and a parameter sensitivity study is carried out to investigate the effect of structural damping on the vibration amplitude.

  18. Calculation of viscoelastic properties of edible films: application of three models

    Directory of Open Access Journals (Sweden)

    CHANDRA Prabir K.

    2000-01-01

    Full Text Available The viscoelastic properties of edible films can provide information at the structural level of the biopolymers used. The objective of this work was to test three simple models of linear viscoelastic theory (Maxwell, Generalized Maxwell with two units in parallel, and Burgers using the results of stress relaxation tests in edible films of myofibrillar proteins of Nile Tilapia. The films were elaborated according to a casting technique and pre-conditioned at 58% relative humidity and 22ºC for 4 days. The testing sample (15mm x 118mm was submitted to tests of stress relaxation in an equipment of physical measurements, TA.XT2i. The deformation, imposed to the sample, was 1%, guaranteeing the permanency in the domain of the linear viscoelasticity. The models were fitted to experimental data (stress x time by nonlinear regression. The Generalized Maxwell model with two units in parallel and the Burgers model represented the relaxation curves of stress satisfactorily. The viscoelastic properties varied in a way that they were less dependent on the thickness of the films.

  19. Viscoelastic properties of doped-ceria under reduced oxygen partial pressure

    DEFF Research Database (Denmark)

    Teocoli, Francesca; Esposito, Vincenzo

    2014-01-01

    The viscoelastic properties of gadolinium-doped ceria (CGO) powder compacts are characterized during sintering and cooling under reduced oxygen partial pressure and compared with conventional sintering in air. Highly defective doped ceria in reducing conditions shows peculiar viscoelastic...

  20. Real-time simulation of the nonlinear visco-elastic deformations of soft tissues.

    Science.gov (United States)

    Basafa, Ehsan; Farahmand, Farzam

    2011-05-01

    Mass-spring-damper (MSD) models are often used for real-time surgery simulation due to their fast response and fairly realistic deformation replication. An improved real time simulation model of soft tissue deformation due to a laparoscopic surgical indenter was developed and tested. The mechanical realization of conventional MSD models was improved using nonlinear springs and nodal dampers, while their high computational efficiency was maintained using an adapted implicit integration algorithm. New practical algorithms for model parameter tuning, collision detection, and simulation were incorporated. The model was able to replicate complex biological soft tissue mechanical properties under large deformations, i.e., the nonlinear and viscoelastic behaviors. The simulated response of the model after tuning of its parameters to the experimental data of a deer liver sample, closely tracked the reference data with high correlation and maximum relative differences of less than 5 and 10%, for the tuning and testing data sets respectively. Finally, implementation of the proposed model and algorithms in a graphical environment resulted in a real-time simulation with update rates of 150 Hz for interactive deformation and haptic manipulation, and 30 Hz for visual rendering. The proposed real time simulation model of soft tissue deformation due to a laparoscopic surgical indenter was efficient, realistic, and accurate in ex vivo testing. This model is a suitable candidate for testing in vivo during laparoscopic surgery.

  1. Bifurcations and chaos of the nonlinear viscoelastic plates subjected to subsonic flow and external loads

    International Nuclear Information System (INIS)

    An, Fengxian; Chen, Fangqi

    2016-01-01

    Highlights: • The subharmonic bifurcations and chaotic motions are studied by means of Melnikov method. • The critical conditions for the occurrence of chaotic motions and subharmonic bifurcations are obtained. • The chaotic features on the system parameters are discussed. • The theoretical predictions are confirmed by numerical simulations. - Abstract: The subharmonic bifurcations and chaotic motions of the nonlinear viscoelastic plates subjected to subsonic flow and external loads are studied by means of Melnikov method. The critical conditions for the occurrence of chaotic motions are obtained. The chaotic features on the system parameters are discussed in detail. The conditions for subharmonic bifurcations are also obtained. For the system with no structural damping, chaotic motions can occur through infinite subharmonic bifurcations of odd orders. Furthermore, we confirm our theoretical predictions by numerical simulations. The theoretical results obtained here can help us to eliminate or suppress large nonlinear vibrations and chaotic motions of the nonlinear viscoelastic plates. Based on Melnikov method, complex dynamical behaviors of the nonlinear viscoelastic plates can be controlled by modifying the system parameters.

  2. A micro-macro constitutive model for finite-deformation viscoelasticity of elastomers with nonlinear viscosity

    Science.gov (United States)

    Zhou, Jianyou; Jiang, Liying; Khayat, Roger E.

    2018-01-01

    Elastomers are known to exhibit viscoelastic behavior under deformation, which is linked to the diffusion processes of the highly mobile and flexible polymer chains. Inspired by the theories of polymer dynamics, a micro-macro constitutive model is developed to study the viscoelastic behaviors and the relaxation process of elastomeric materials under large deformation, in which the material parameters all have a microscopic foundation or a microstructural justification. The proposed model incorporates the nonlinear material viscosity into the continuum finite-deformation viscoelasticity theories which represent the polymer networks of elastomers with an elastic ground network and a few viscous subnetworks. The developed modeling framework is capable of adopting most of strain energy density functions for hyperelastic materials and thermodynamics evolution laws of viscoelastic solids. The modeling capacity of the framework is outlined by comparing the simulation results with the experimental data of three commonly used elastomeric materials, namely, VHB4910, HNBR50 and carbon black (CB) filled elastomers. The comparison shows that the stress responses and some typical behaviors of filled and unfilled elastomers can be quantitatively predicted by the model with suitable strain energy density functions. Particularly, the strain-softening effect of elastomers could be explained by the deformation-dependent (nonlinear) viscosity of the polymer chains. The presented modeling framework is expected to be useful as a modeling platform for further study on the performance of different type of elastomeric materials.

  3. Viscoelasticity and diffusional properties of colloidal model dispersions

    CERN Document Server

    Naegele, G

    2003-01-01

    We examine linear viscoelastic, and translational and rotational diffusion properties of colloidal model dispersions. Theoretical results are discussed, in comparison with experiments, for monodisperse suspensions of charged and neutral colloidal spheres, and for binary dispersions of differently sized tracer and host particles. The theoretical methods employed comprise a mode-coupling scheme for Brownian particles, and a rooted cluster expansion scheme of tracer diffusion with two- and three-body hydrodynamic interactions included. We analyse in particular the validity of various empirical generalized Stokes-Einstein-Debye (SED) relations between the (dynamic) shear viscosity and translational/rotational diffusion coefficients. Some of these generalized SED relations are basic to microrheological measurements aimed at characterizing the viscoelasticity of complex fluids on the basis of the diffusional properties of immersed tracer particles.

  4. Viscoelasticity and diffusional properties of colloidal model dispersions

    International Nuclear Information System (INIS)

    Naegele, Gerhard

    2003-01-01

    We examine linear viscoelastic, and translational and rotational diffusion properties of colloidal model dispersions. Theoretical results are discussed, in comparison with experiments, for monodisperse suspensions of charged and neutral colloidal spheres, and for binary dispersions of differently sized tracer and host particles. The theoretical methods employed comprise a mode-coupling scheme for Brownian particles, and a rooted cluster expansion scheme of tracer diffusion with two- and three-body hydrodynamic interactions included. We analyse in particular the validity of various empirical generalized Stokes-Einstein-Debye (SED) relations between the (dynamic) shear viscosity and translational/rotational diffusion coefficients. Some of these generalized SED relations are basic to microrheological measurements aimed at characterizing the viscoelasticity of complex fluids on the basis of the diffusional properties of immersed tracer particles

  5. Energy decay of a viscoelastic wave equation with supercritical nonlinearities

    Science.gov (United States)

    Guo, Yanqiu; Rammaha, Mohammad A.; Sakuntasathien, Sawanya

    2018-06-01

    This paper presents a study of the asymptotic behavior of the solutions for the history value problem of a viscoelastic wave equation which features a fading memory term as well as a supercritical source term and a frictional damping term: u_{tt}- k(0) Δ u - \\int \\limits _0^{&infty } k'(s) Δ u(t-s) ds +|u_t|^{m-1}u_t =|u|^{p-1}u, { in } Ω × (0,T), u(x,t)=u_0(x,t), \\quad { in } Ω × (-∞,0]), where Ω is a bounded domain in R^3 with a Dirichlét boundary condition and u_0 represents the history value. A suitable notion of a potential well is introduced for the system, and global existence of solutions is justified, provided that the history value u_0 is taken from a subset of the potential well. Also, uniform energy decay rate is obtained which depends on the relaxation kernel -k'(s) as well as the growth rate of the damping term. This manuscript complements our previous work (Guo et al. in J Differ Equ 257:3778-3812, 2014, J Differ Equ 262:1956-1979, 2017) where Hadamard well-posedness and the singularity formulation have been studied for the system. It is worth stressing the special features of the model, namely the source term here has a supercritical growth rate and the memory term accounts to the full past history that goes back to -∞.

  6. The nonlinear propagation of acoustic waves in a viscoelastic medium containing cylindrical micropores

    International Nuclear Information System (INIS)

    Yu-Lin, Feng; Xiao-Zhou, Liu; Jie-Hui, Liu; Li, Ma

    2009-01-01

    Based on an equivalent medium approach, this paper presents a model describing the nonlinear propagation of acoustic waves in a viscoelastic medium containing cylindrical micropores. The influences of pores' nonlinear oscillations on sound attenuation, sound dispersion and an equivalent acoustic nonlinearity parameter are discussed. The calculated results show that the attenuation increases with an increasing volume fraction of micropores. The peak of sound velocity and attenuation occurs at the resonant frequency of the micropores while the peak of the equivalent acoustic nonlinearity parameter occurs at the half of the resonant frequency of the micropores. Furthermore, multiple scattering has been taken into account, which leads to a modification to the effective wave number in the equivalent medium approach. We find that these linear and nonlinear acoustic parameters need to be corrected when the volume fraction of micropores is larger than 0.1%

  7. Nonlinear viscoelastic characterization of molten thermoplastic vulcanizates (TPV) through large amplitude harmonic experiments

    Energy Technology Data Exchange (ETDEWEB)

    Leblanc, Jean L. [University P. and M. Curie-Paris 6, Polymer Rheology and Processing, Vitry-sur-Seine (France)

    2007-10-15

    The so-called thermoplastic vulcanizates (TPV) are essentially blends of a crystalline thermoplastic polymer (e.g., polypropylene) and a vulcanizable rubber composition, prepared through a special process called dynamic vulcanization, which yields a fine dispersion of micron-size crosslinked rubber particles in a thermoplastic matrix. Such materials are by nature complex polymer systems, i.e., multiphase, heterogeneous, typically disordered materials for which structure is as important as composition. Correctly assessing their rheological properties is a challenging task for several reasons: first, even if the uniformity of their composition is taken for granted, TPV are indeed very complicated materials, not only heterogeneous but also with a morphology related to their composition; second, their morphology can be affected by the flow field used; third, the migration of small labile ingredients (e.g., oil, curative residue, etc.) can in the meantime significantly change the boundary flow conditions, for instance through self-lubrication due to phase separation of the oil, or wall slip, or both. The aims of the work reported were to investigate a series of commercial TPV through the so-called Fourier transform rheometry, a testing technique especially developed to accurately investigate the nonlinear viscoelastic domain. Results are tentatively interpreted in terms of material composition and structure. (orig.)

  8. General decay of solutions of a nonlinear system of viscoelastic wave equations

    KAUST Repository

    Said-Houari, Belkacem; Messaoudi, Salim A.; Guesmia, Aï ssa

    2011-01-01

    This work is concerned with a system of two viscoelastic wave equations with nonlinear damping and source terms acting in both equations. Under some restrictions on the nonlinearity of the damping and the source terms, we prove that, for certain class of relaxation functions and for some restrictions on the initial data, the rate of decay of the total energy depends on those of the relaxation functions. This result improves many results in the literature, such as the ones in Messaoudi and Tatar (Appl. Anal. 87(3):247-263, 2008) and Liu (Nonlinear Anal. 71:2257-2267, 2009) in which only the exponential and polynomial decay rates are considered. © 2011 Springer Basel AG.

  9. General decay of solutions of a nonlinear system of viscoelastic wave equations

    KAUST Repository

    Said-Houari, Belkacem

    2011-04-16

    This work is concerned with a system of two viscoelastic wave equations with nonlinear damping and source terms acting in both equations. Under some restrictions on the nonlinearity of the damping and the source terms, we prove that, for certain class of relaxation functions and for some restrictions on the initial data, the rate of decay of the total energy depends on those of the relaxation functions. This result improves many results in the literature, such as the ones in Messaoudi and Tatar (Appl. Anal. 87(3):247-263, 2008) and Liu (Nonlinear Anal. 71:2257-2267, 2009) in which only the exponential and polynomial decay rates are considered. © 2011 Springer Basel AG.

  10. The role of nonlinear viscoelasticity on the functionality of laminating shortenings

    Energy Technology Data Exchange (ETDEWEB)

    Macias-Rodriguez, Braulio A.; Peyronel, Fernanda; Marangoni, Alejandro G.

    2017-11-01

    The rheology of fats is essential for the development of homogeneous and continuous layered structures of doughs. Here, we define laminating shortenings in terms of rheological behavior displayed during linear-to-nonlinear shear deformations, investigated by large amplitude oscillatory shear rheology. Likewise, we associate the rheological behavior of the shortenings with structural length scales elucidated by ultra-small angle x-ray scattering and cryo-electron microscopy. Shortenings exhibited solid-like viscoelastic and viscoelastoplastic behaviors in the linear and nonlinear regimes respectively. In the nonlinear region, laminating shortenings dissipated more viscous energy (larger normalized dynamic viscosities) than a cake bakery shortening. The fat solid-like network of laminating shortening displayed a three-hierarchy structure and layered crystal aggregates, in comparison to two-hierarchy structure and spherical-like crystal aggregates of a cake shortening. We argue that the observed rheology, correlated to the structural network, is crucial for optimal laminating performance of shortenings.

  11. Nonlinear model for viscoelastic behavior of Achilles tendon.

    Science.gov (United States)

    Kahn, Cyril J F; Wang, Xiong; Rahouadj, Rachid

    2010-11-01

    Although the mechanical properties of ligament and tendon are well documented in research literature, very few unified mechanical formulations can describe a wide range of different loadings. The aim of this study was to propose a new model, which can describe tendon responses to various solicitations such as cycles of loading, unloading, and reloading or successive relaxations at different strain levels. In this work, experiments with cycles of loading and reloading at increasing strain level and sequences of relaxation were performed on white New Zealand rabbit Achilles tendons. We presented a local formulation of thermodynamic evolution outside equilibrium at a representative element volume scale to describe the tendon's macroscopic behavior based on the notion of relaxed stress. It was shown that the model corresponds quite well to the experimental data. This work concludes with the complexity of tendons' mechanical properties due to various microphysical mechanisms of deformation involved in loading such as the recruitment of collagen fibers, the rearrangement of the microstructure (i.e., collagens type I and III, proteoglycans, and water), and the evolution of relaxed stress linked to these mechanisms.

  12. A variational constitutive framework for the nonlinear viscoelastic response of a dielectric elastomer

    KAUST Repository

    Khan, Kamran

    2012-11-10

    We formulate a variational constitutive framework that accounts for nonlinear viscous behavior of electrically sensitive polymers, specifically Dielectric Elastomers (DEs), under large deformation. DEs are highly viscoelastic and their actuation response is greatly affected in dynamic applications. We used the generalized Maxwell model to represent the viscoelastic response of DE allowing the material to relax with multiple mechanisms. The constitutive updates at each load increment are obtained by minimizing an objective function formulated using the free energy and electrostatic energy of the elastomer, in addition to the viscous dissipation potential of the dashpots in each Maxwell branch. The model is then used to predict the electromechanical instability (EMI) of DE. The electro-elastic response of the DE is verified with available analytical solutions in the literature and then the material parameters are calibrated using experimental data. The model is integrated with finite element software to perform a variety of simulations on different types of electrically driven actuators under various electromechanical loadings. The electromechanical response of the DE and the critical conditions at which EMI occurs were found to be greatly affected by the viscoelasticity. Our model predicts that under a dead load EMI can be avoided if the DE operates at a high voltage rate. Subjected to constant, ramp and cyclic voltage, our model qualitatively predicts responses similar to the ones obtained from the analytical solutions and experimental data available in the literature. © 2012 Springer-Verlag Berlin Heidelberg.

  13. Viscoelastic and dynamic properties of embryonic stem cells

    DEFF Research Database (Denmark)

    Ritter, Christine

    Stem cells are often referred to as the ‘holy grail’ of regenerative medicine, because they possessthe ability to develop into any cell type. The use of stem cells within medicine is currently limited bythe effectivity of differentiation and cell reprogramming protocols, making it therefore...... imperative tounderstand stem cells’ differentiation mechanisms better. Studies have shown that mechanical cuescan have an influence on stem cell fate decision. However, in order to understand the reaction of stemcells to mechanical input, one should first investigate and understand the mechanical properties...... ofthe cells themselves. In this thesis, the viscoelastic properties of mouse embryonic stem cells primedeither toward the epiblast (Epi) or the primitive endoderm (PrE) lineage were investigated.Optical tweezers were used to measure the fluctuations of endogenous lipid granules and therebydraw...

  14. Analytical Analysis on Nonlinear Parametric Vibration of an Axially Moving String with Fractional Viscoelastic Damping

    Directory of Open Access Journals (Sweden)

    Ying Li

    2017-01-01

    Full Text Available The nonlinear parametric vibration of an axially moving string made by rubber-like materials is studied in the paper. The fractional viscoelastic model is used to describe the damping of the string. Then, a new nonlinear fractional mathematical model governing transverse motion of the string is derived based on Newton’s second law, the Euler beam theory, and the Lagrangian strain. Taking into consideration the fractional calculus law of Riemann-Liouville form, the principal parametric resonance is analytically investigated via applying the direct multiscale method. Numerical results are presented to show the influences of the fractional order, the stiffness constant, the viscosity coefficient, and the axial-speed fluctuation amplitude on steady-state responses. It is noticeable that the amplitudes and existing intervals of steady-state responses predicted by Kirchhoff’s fractional material model are much larger than those predicted by Mote’s fractional material model.

  15. New non-linear model of groundwater recharge: Inclusion of memory, heterogeneity and visco-elasticity

    Directory of Open Access Journals (Sweden)

    Spannenberg Jescica

    2017-09-01

    Full Text Available Fractional differentiation has adequate use for investigating real world scenarios related to geological formations associated with elasticity, heterogeneity, viscoelasticity, and the memory effect. Since groundwater systems exist in these geological formations, modelling groundwater recharge as a real world scenario is a challenging task to do because existing recharge estimation methods are governed by linear equations which make use of constant field parameters. This is inadequate because in reality these parameters are a function of both space and time. This study therefore concentrates on modifying the recharge equation governing the EARTH model, by application of the Eton approach. Accordingly, this paper presents a modified equation which is non-linear, and accounts for parameters in a way that it is a function of both space and time. To be more specific, herein, recharge and drainage resistance which are parameters within the equation, became a function of both space and time. Additionally, the study entailed solving the non-linear equation using an iterative method as well as numerical solutions by means of the Crank-Nicolson scheme. The numerical solutions were used alongside the Riemann-Liouville, Caputo-Fabrizio, and Atangana-Baleanu derivatives, so that account was taken for elasticity, heterogeneity, viscoelasticity, and the memory effect. In essence, this paper presents a more adequate model for recharge estimation.

  16. Non-linear analysis and the design of Pumpkin Balloons: stress, stability and viscoelasticity

    Science.gov (United States)

    Rand, J. L.; Wakefield, D. S.

    Tensys have a long-established background in the shape generation and load analysis of architectural stressed membrane structures Founded upon their inTENS finite element analysis suite these activities have broadened to encompass lighter than air structures such as aerostats hybrid air-vehicles and stratospheric balloons Winzen Engineering couple many years of practical balloon design and fabrication experience with both academic and practical knowledge of the characterisation of the non-linear viscoelastic response of the polymeric films typically used for high-altitude scientific balloons Both companies have provided consulting services to the NASA Ultra Long Duration Balloon ULDB Program Early implementations of pumpkin balloons have shown problems of geometric instability characterised by improper deployment and these difficulties have been reproduced numerically using inTENS The solution lies in both the shapes of the membrane lobes and also the need to generate a biaxial stress field in order to mobilise in-plane shear stiffness Balloons undergo significant temperature and pressure variations in flight The different thermal characteristics between tendons and film can lead to significant meridional stress Fabrication tolerances can lead to significant local hoop stress concentrations particularly adjacent to the base and apex end fittings The non-linear viscoelastic response of the envelope film acts positively to help dissipate stress concentrations However creep over time may produce lobe geometry variations that may

  17. Effect of Surface Modification of Nanosilica on the Viscoelastic Properties of Its Polystyrene Nanocomposite

    Directory of Open Access Journals (Sweden)

    M. Mortezaei

    2008-12-01

    Full Text Available The preparation and characterization of the vinyltriethoxysilane-modified silica nanoparticles were investigated. Also the surface tension of polystyrene, native (hydrophilic silica and silane-modified (hydrophobic silica were determined. Two kinds of polystyrene/silica (treated and non-treated nanocomposites were prepared with different filler loadings by solution method. Their viscoelastic properties were studied by dynamic stress controlled rotary shear rheometer. Solid-like response of polystyrene/native silica nanocomposites were observed in the terminal zone. Solid inclusionsincrease the storage modulus more than the loss modulus, hence decrease the material damping. By increasing filler volume fraction, the particles tend to agglomerate and build clusters. The presence of clusters increases the viscosity, the moduli and the viscoelastic non-linearity of the composites.Treating the filler surface reduces its tendency to agglomerate as well as the adhesion between the particles and the polystyrene, leading to lower viscosity and interfacial slippage. Also the loss modulus peak is affected significantly by the particle surface area and its surface property in silica-filled polystyrene, which corresponds to its glass transition.

  18. Dynamic rheological properties of viscoelastic magnetic fluids in uniform magnetic fields

    International Nuclear Information System (INIS)

    Yamaguchi, Hiroshi; Niu Xiaodong; Ye Xiaojiang; Li Mingjun; Iwamoto, Yuhiro

    2012-01-01

    The dynamic rheological properties of viscoelastic magnetic fluids in externally applied uniform magnetic fields are investigated by a laboratory-made cone-plate rheometer in this study. In particular, the effects of the magnetic field on the viscoelastic properties (the complex dynamic modulus) of the viscoelastic magnetic fluids are studied. In the investigation, three viscoelastic magnetic fluids are made by mixing a magnetic fluid and a viscoelastic fluid with different mass ratios. As a supplementation to the experimental investigation, a theoretical analysis is also presented. The present study shows that the viscosity and elasticity of the viscoelastic magnetic fluids are significantly influenced by the magnetic field and the concentrations of the magnetic particles in the test fluids. Theoretical analysis qualitatively explains the present findings. - Highlights: ► The dynamic rheological properties of the viscoelastic magnetic fluids in uniform magnetic fields are investigated. ► Both the magnetic field strength and the concentration of the magnetic particles in the fluids have significant effects on the viscosity and elasticity of the viscoelastic magnetic fluids. ► Theoretical prediction and analysis qualitatively explains the present findings.

  19. Modulating state transition and mechanical properties of viscoelastic resins from maize zein through interactions with plasticizers and co-proteins

    NARCIS (Netherlands)

    Erickson, D.P.; Renzetti, S.; Jurgens, A.; Campanella, O.H.; Hamaker, B.R.

    2014-01-01

    Viscoelastic properties have been observed in maize zein above its glass transition temperature; however, current understanding of how these viscoelastic polymers can be further manipulated for optimal performance is limited. Using resins formed via precipitation from aqueous ethanolic environments,

  20. Magnetohydrodynamic three-dimensional flow of viscoelastic nanofluid in the presence of nonlinear thermal radiation

    Energy Technology Data Exchange (ETDEWEB)

    Hayat, T. [Department of Mathematics, Quaid-I-Azam University 45320, Islamabad 44000 (Pakistan); Nonlinear Analysis and Applied Mathematics (NAAM) Research Group, Faculty of Science, King Abdulaziz University, P. O. Box 80203, Jeddah 21589 (Saudi Arabia); Muhammad, Taseer, E-mail: taseer_qau@yahoo.com [Department of Mathematics, Quaid-I-Azam University 45320, Islamabad 44000 (Pakistan); Alsaedi, A.; Alhuthali, M.S. [Nonlinear Analysis and Applied Mathematics (NAAM) Research Group, Faculty of Science, King Abdulaziz University, P. O. Box 80203, Jeddah 21589 (Saudi Arabia)

    2015-07-01

    Magnetohydrodynamic (MHD) three-dimensional flow of couple stress nanofluid in the presence of thermophoresis and Brownian motion effects is analyzed. Energy equation subject to nonlinear thermal radiation is taken into account. The flow is generated by a bidirectional stretching surface. Fluid is electrically conducting in the presence of a constant applied magnetic field. The induced magnetic field is neglected for a small magnetic Reynolds number. Mathematical formulation is performed using boundary layer analysis. Newly proposed boundary condition requiring zero nanoparticle mass flux is employed. The governing nonlinear mathematical problems are first converted into dimensionless expressions and then solved for the series solutions of velocities, temperature and nanoparticles concentration. Convergence of the constructed solutions is verified. Effects of emerging parameters on the temperature and nanoparticles concentration are plotted and discussed. Skin friction coefficients and Nusselt number are also computed and analyzed. It is found that the thermal boundary layer thickness is an increasing function of radiative effect. - Highlights: • Three-dimensional boundary layer flow of viscoelastic nanofluid is examined. • Nonlinear thermal radiation is analyzed. • Brownian motion and thermophoresis effects are present. • Recently developed condition requiring zero nanoparticle mass flux is implemented. • Construction of convergent solutions of nonlinear flow is possible.

  1. Assessment of the viscoelastic mechanical properties of polycarbonate urethane for medical devices.

    Science.gov (United States)

    Beckmann, Agnes; Heider, Yousef; Stoffel, Marcus; Markert, Bernd

    2018-06-01

    The underlying research work introduces a study of the mechanical properties of polycarbonate urethane (PCU), used in the construction of various medical devices. This comprises the discussion of a suitable material model, the application of elemental experiments to identify the related parameters and the numerical simulation of the applied experiments in order to calibrate and validate the mathematical model. In particular, the model of choice for the simulation of PCU response is the non-linear viscoelastic Bergström-Boyce material model, applied in the finite-element (FE) package Abaqus®. For the parameter identification, uniaxial tension and unconfined compression tests under in-laboratory physiological conditions were carried out. The geometry of the samples together with the applied loadings were simulated in Abaqus®, to insure the suitability of the modelling approach. The obtained parameters show a very good agreement between the numerical and the experimental results. Copyright © 2018 Elsevier Ltd. All rights reserved.

  2. Interrogating the viscoelastic properties of tissue using viscoelastic response (VISR) ultrasound

    Science.gov (United States)

    Selzo, Mallory Renee

    Affecting approximately 1 in 3,500 newborn males, Duchenne muscular dystrophy (DMD) is one of the most common lethal genetic disorders in humans. Boys with DMD suffer progressive loss of muscle strength and function, leading to wheelchair dependence, cardiac and respiratory compromise, and death during young adulthood. There are currently no treatments that can halt or reverse the disease progression, and translating prospective treatments into clinical trials has been delayed by inadequate outcome measures. Current outcome measures, such as functional and muscle strength assessments, lack sensitivity to individual muscles, require subjective effort of the child, and are impacted by normal childhood growth and development. The goal of this research is to develop Viscoelastic Response (VisR) ultrasound which can be used to delineate compositional changes in muscle associated with DMD. In VisR, acoustic radiation force (ARF) is used to produce small, localized displacements within the muscle. Using conventional ultrasound to track the motion, the displacement response of the tissue can be evaluated against a mechanical model. In order to develop signal processing techniques and assess mechanical models, finite element method simulations are used to model the response of a viscoelastic material to ARF excitations. Results are then presented demonstrating VisR differentiation of viscoelastic changes with progressive dystrophic degeneration in a dog model of DMD. Finally, clinical feasibility of VisR imaging is demonstrated in two boys with DMD.

  3. Viscoelastic and thermal properties of woven sisal fabric reinforced natural rubber biocomposites

    CSIR Research Space (South Africa)

    John, MJ

    2009-01-01

    Full Text Available This study explores the dynamic mechanical behavior of woven sisal fabric reinforced natural rubber composites. The influence of chemical modification on the viscoelastic properties has also been determined. Moreover, the effect of frequency...

  4. Estimation of piezoelastic and viscoelastic properties in laminated structures

    DEFF Research Database (Denmark)

    Araujo, A. L.; Soares, C. M. Mota; Herskovits, J.

    2009-01-01

    An inverse method for material parameter estimation of elastic, piezoelectric and viscoelastic laminated plate structures is presented. The method uses a gradient based optimization technique in order to solve the inverse problem, through minimization of an error functional which expresses...... the difference between experimental free vibration data and corresponding numerical data produced by a finite element model. The complex modulus approach is used to model the viscoelastic material behavior, assuming hysteretic type damping. Applications that illustrate the influence of adhesive material...

  5. Comparative study of viscoelastic properties using virgin yogurt

    International Nuclear Information System (INIS)

    Dimonte, G.; Nelson, D.; Weaver, S.; Schneider, M.; Flower-Maudlin, E.; Gore, R.; Baumgardner, J.R.; Sahota, M.S.

    1998-01-01

    We describe six different tests used to obtain a consistent set of viscoelastic properties for yogurt. Prior to yield, the shear modulus μ and viscosity η are measured nondestructively using the speed and damping of elastic waves. Although new to foodstuffs, this technique has been applied to diverse materials from metals to the earth's crust. The resultant shear modulus agrees with μ∼E/3 for incompressible materials, where the Young's modulus E is obtained from a stress - strain curve in compression. The tensile yield stress τ o is measured in compression and tension, with good agreement. The conventional vane and cone/plate rheometers measured a shear stress yield τ os ∼τ o /√ (3) , as expected theoretically, but the inferred 'apparent' viscosity from the cone/plate rheometer is much larger than the wave measurement due to the finite yield (τ os ≠0). Finally, we inverted an open container of yogurt for 10 6 s>η/μ and observed no motion. This demonstrates unequivocally that yogurt possesses a finite yield stress rather than a large viscosity. We present a constitutive model with a pre-yield viscosity to describe the damping of the elastic waves and use a simulation code to describe yielding in complex geometry. copyright 1998 Society of Rheology

  6. Global existence and nonexistence for the viscoelastic wave equation with nonlinear boundary damping-source interaction

    KAUST Repository

    Said-Houari, Belkacem

    2012-09-01

    The goal of this work is to study a model of the viscoelastic wave equation with nonlinear boundary/interior sources and a nonlinear interior damping. First, applying the Faedo-Galerkin approximations combined with the compactness method to obtain existence of regular global solutions to an auxiliary problem with globally Lipschitz source terms and with initial data in the potential well. It is important to emphasize that it is not possible to consider density arguments to pass from regular to weak solutions if one considers regular solutions of our problem where the source terms are locally Lipschitz functions. To overcome this difficulty, we use an approximation method involving truncated sources and adapting the ideas in [13] to show that the existence of weak solutions can still be obtained for our problem. Second, we show that under some restrictions on the initial data and if the interior source dominates the interior damping term, then the solution ceases to exist and blows up in finite time provided that the initial data are large enough.

  7. Nonlinear Forced Vibration of a Viscoelastic Buckled Beam with 2 : 1 Internal Resonance

    Directory of Open Access Journals (Sweden)

    Liu-Yang Xiong

    2014-01-01

    Full Text Available Nonlinear dynamics of a viscoelastic buckled beam subjected to primary resonance in the presence of internal resonance is investigated for the first time. For appropriate choice of system parameters, the natural frequency of the second mode is approximately twice that of the first providing the condition for 2 : 1 internal resonance. The ordinary differential equations of the two mode shapes are established using the Galerkin method. The problem is replaced by two coupled second-order differential equations with quadratic and cubic nonlinearities. The multiple scales method is applied to derive the modulation-phase equations. Steady-state solutions of the system as well as their stability are examined. The frequency-amplitude curves exhibit the steady-state response in the directly excited and indirectly excited modes due to modal interaction. The double-jump, the saturation phenomenon, and the nonperiodic region phenomena are observed illustrating the influence of internal resonance. The validity range of the analytical approximations is assessed by comparing the analytical approximate results with a numerical solution by the Runge-Kutta method. The unstable regions in the internal resonance are explored via numerical simulations.

  8. Nonlinear waves in viscoelastic magnetized complex astroplasmas with polarized dust-charge variations

    Directory of Open Access Journals (Sweden)

    Papari Das

    2018-01-01

    Full Text Available A nonextensive nonthermal magnetized viscoelastic astrofluid, compositionally containing nonthermal electrons and ions together with massive polarized dust micro-spherical grains of variable electric charge, is allowed to endure weakly nonlinear perturbation around its equilibrium. The nonextensivity originating from the large-scale non-local effects is included via the Tsallis thermo-statistical distribution laws describing the lighter species. Assuming the equilibrium as a homogeneous hydrostatic one, the dust polarization effects are incorporated via the conventional homogeneous polarization force law. The perturbed fluid model evolves as a unique conjugate pair of coupled extended Korteweg-de Vries (e-KdV equations. A constructed numerical tapestry shows the collective excitations of a new pair of distinct classes of nonlinear mode structures in new parametric space. The first family indicates periodic electrostatic compressive eigenmodes in the form of soliton-chains. Likewise, the second one reveals gravitational rarefactive solitary patterns. Their microphysical multi-parametric dependencies of the eigen-patterns are illustratively analyzed and bolstered. The paper ends up with some promising implications and applications in the astro-cosmo-plasmic context of wave-induced accretive triggering processes responsible for gravitationally bounded (gravito-condensed astro-structure formation, such as stellesimals, planetsimals, etc.

  9. Global existence and nonexistence for the viscoelastic wave equation with nonlinear boundary damping-source interaction

    KAUST Repository

    Said-Houari, Belkacem; Nascimento, Flá vio A Falcã o

    2012-01-01

    The goal of this work is to study a model of the viscoelastic wave equation with nonlinear boundary/interior sources and a nonlinear interior damping. First, applying the Faedo-Galerkin approximations combined with the compactness method to obtain existence of regular global solutions to an auxiliary problem with globally Lipschitz source terms and with initial data in the potential well. It is important to emphasize that it is not possible to consider density arguments to pass from regular to weak solutions if one considers regular solutions of our problem where the source terms are locally Lipschitz functions. To overcome this difficulty, we use an approximation method involving truncated sources and adapting the ideas in [13] to show that the existence of weak solutions can still be obtained for our problem. Second, we show that under some restrictions on the initial data and if the interior source dominates the interior damping term, then the solution ceases to exist and blows up in finite time provided that the initial data are large enough.

  10. Nonlinear waves in viscoelastic magnetized complex astroplasmas with polarized dust-charge variations

    Science.gov (United States)

    Das, Papari; Karmakar, Pralay Kumar

    2018-01-01

    A nonextensive nonthermal magnetized viscoelastic astrofluid, compositionally containing nonthermal electrons and ions together with massive polarized dust micro-spherical grains of variable electric charge, is allowed to endure weakly nonlinear perturbation around its equilibrium. The nonextensivity originating from the large-scale non-local effects is included via the Tsallis thermo-statistical distribution laws describing the lighter species. Assuming the equilibrium as a homogeneous hydrostatic one, the dust polarization effects are incorporated via the conventional homogeneous polarization force law. The perturbed fluid model evolves as a unique conjugate pair of coupled extended Korteweg-de Vries (e-KdV) equations. A constructed numerical tapestry shows the collective excitations of a new pair of distinct classes of nonlinear mode structures in new parametric space. The first family indicates periodic electrostatic compressive eigenmodes in the form of soliton-chains. Likewise, the second one reveals gravitational rarefactive solitary patterns. Their microphysical multi-parametric dependencies of the eigen-patterns are illustratively analyzed and bolstered. The paper ends up with some promising implications and applications in the astro-cosmo-plasmic context of wave-induced accretive triggering processes responsible for gravitationally bounded (gravito-condensed) astro-structure formation, such as stellesimals, planetsimals, etc.

  11. Viscoelastic properties of graphene-based epoxy resins

    Science.gov (United States)

    Nobile, Maria Rossella; Fierro, Annalisa; Rosolia, Salvatore; Raimondo, Marialuigia; Lafdi, Khalid; Guadagno, Liberata

    2015-12-01

    In this paper the viscoelastic properties of an epoxy resin filled with graphene-based nanoparticles have been investigated in the liquid state, before curing, by means of a rotational rheometer equipped with a parallel plate geometry. Exfoliated graphite was prepared using traditional acid intercalation followed by a sudden treatment at high temperature (900°C). The percentage of exfoliated graphite was found to be 56%. The epoxy matrix was prepared by mixing a tetrafunctional precursor with a reactive diluent which produces a significant decrease in the viscosity of the epoxy precursor so that the dispersion step of nanofillers in the matrix can easily occur. The hardener agent, the 4,4-diaminodiphenyl sulfone (DDS), was added at a stoichiometric concentration with respect to all the epoxy rings. The inclusion of the partially exfoliated graphite (pEG) in the formulated epoxy mixture significantly modifies the rheological behaviour of the mixture itself. The epoxy mixture, indeed, shows a Newtonian behaviour while, at 3 wt % pEG content, the complex viscosity of the nanocomposite clearly shows a shear thinning behaviour with η* values much higher at the lower frequencies. The increase in complex viscosity with the increasing of the partially exfoliated graphite content was mostly caused by a dramatic increase in the storage modulus. All the graphene-based epoxy mixtures were cured by a two-stage curing cycles: a first isothermal stage was carried out at the lower temperature of 125°C for 1 hour while the second isothermal stage was performed at the higher temperature of 200°C for 3 hours. The mechanical properties of the cured nanocomposites show high values in the storage modulus and glass transition temperature.

  12. Two-dimensional nonlinear dynamics of an axially moving viscoelastic beam with time-dependent axial speed

    International Nuclear Information System (INIS)

    Ghayesh, Mergen H.; Amabili, Marco; Farokhi, Hamed

    2013-01-01

    In the present study, the coupled nonlinear dynamics of an axially moving viscoelastic beam with time-dependent axial speed is investigated employing a numerical technique. The equations of motion for both the transverse and longitudinal motions are obtained using Newton’s second law of motion and the constitutive relations. A two-parameter rheological model of the Kelvin–Voigt energy dissipation mechanism is employed in the modelling of the viscoelastic beam material, in which the material time derivative is used in the viscoelastic constitutive relation. The Galerkin method is then applied to the coupled nonlinear equations, which are in the form of partial differential equations, resulting in a set of nonlinear ordinary differential equations (ODEs) with time-dependent coefficients due to the axial acceleration. A change of variables is then introduced to this set of ODEs to transform them into a set of first-order ordinary differential equations. A variable step-size modified Rosenbrock method is used to conduct direct time integration upon this new set of first-order nonlinear ODEs. The mean axial speed and the amplitude of the speed variations, which are taken as bifurcation parameters, are varied, resulting in the bifurcation diagrams of Poincaré maps of the system. The dynamical characteristics of the system are examined more precisely via plotting time histories, phase-plane portraits, Poincaré sections, and fast Fourier transforms (FFTs)

  13. Identifying Mechanical Properties of Viscoelastic Materials in Time Domain Using the Fractional Zener Model

    Directory of Open Access Journals (Sweden)

    Ana Paula Delowski Ciniello

    Full Text Available Abstract The present paper aims at presenting a methodology for characterizing viscoelastic materials in time domain, taking into account the fractional Zener constitutive model and the influence of temperature through Williams, Landel, and Ferry’s model. To that effect, a set of points obtained experimentally through uniaxial tensile tests with different constant strain rates is considered. The approach is based on the minimization of the quadratic relative distance between the experimental stress-strain curves and the corresponding ones given by the theoretical model. In order to avoid the local minima in the process of optimization, a hybrid technique based on genetic algorithms and non-linear programming techniques is used. The methodology is applied in the characterization of two different commercial viscoelastic materials. The results indicate that the proposed methodology is effective in identifying thermorheologically simple viscoelastic materials.

  14. Investigating Linear and Nonlinear Viscoelastic behaviour and microstructures of Gelatine-Multiwalled carbon nanotubes composites

    KAUST Repository

    Yang, Zhi

    2015-12-01

    We have investigated the linear and nonlinear rheology of various gelatine-multiwalled carbon nanotube (gel-MWNT) composites, namely physically-crosslinked-gelatine gel-MWNT composites, chemically-crosslinked-gelatine gel-MWNT composites, and chemically-physically-crosslinked-gelatine gel-MWNT composites. Further, the internal structures of these gel-MWNT composites were characterized by ultra-small angle neutron scattering and scanning electron microscopy. The adsorption of gelatine onto the surface of MWNT is also investigated to understand gelatine-assisted dispersion of MWNT during ultrasonication. For all gelatine gels, addition of MWNT increases their complex modulus. The dependence of storage modulus with frequency for gelatine-MWNT composites is similar to that of the corresponding neat gelatine matrix. However, by incorporating MWNT, the dependence of the loss modulus on frequency is reduced. The linear viscoelastic region is decreased approximately linearly with the increase of MWNT concentration. The pre-stress results demonstrate that the addition of MWNT does not change the strain-hardening behaviour of physically-crosslinked gelatine gel. However, the addition of MWNT can increase the strain-hardening behaviour of chemically-crosslinked gelatine gel, and chemically-physically crosslinked gelatine gel. Results from light microscopy, cryo-SEM, and USANS demonstrate the hierarchical structures of MWNT, including that tens-of-micron scale MWNT agglomerates are present. Furthermore, the adsorption curve of gelatine onto the surface of MWNT follows two-stage pseudo-saturation behaviour.

  15. Quasi-static earthquake cycle simulation based on nonlinear viscoelastic finite element analyses

    Science.gov (United States)

    Agata, R.; Ichimura, T.; Hyodo, M.; Barbot, S.; Hori, T.

    2017-12-01

    To explain earthquake generation processes, simulation methods of earthquake cycles have been studied. For such simulations, the combination of the rate- and state-dependent friction law at the fault plane and the boundary integral method based on Green's function in an elastic half space is widely used (e.g. Hori 2009; Barbot et al. 2012). In this approach, stress change around the fault plane due to crustal deformation can be computed analytically, while the effects of complex physics such as mantle rheology and gravity are generally not taken into account. To consider such effects, we seek to develop an earthquake cycle simulation combining crustal deformation computation based on the finite element (FE) method with the rate- and state-dependent friction law. Since the drawback of this approach is the computational cost associated with obtaining numerical solutions, we adopt a recently developed fast and scalable FE solver (Ichimura et al. 2016), which assumes use of supercomputers, to solve the problem in a realistic time. As in the previous approach, we solve the governing equations consisting of the rate- and state-dependent friction law. In solving the equations, we compute stress changes along the fault plane due to crustal deformation using FE simulation, instead of computing them by superimposing slip response function as in the previous approach. In stress change computation, we take into account nonlinear viscoelastic deformation in the asthenosphere. In the presentation, we will show simulation results in a normative three-dimensional problem, where a circular-shaped velocity-weakening area is set in a square-shaped fault plane. The results with and without nonlinear viscosity in the asthenosphere will be compared. We also plan to apply the developed code to simulate the post-earthquake deformation of a megathrust earthquake, such as the 2011 Tohoku earthquake. Acknowledgment: The results were obtained using the K computer at the RIKEN (Proposal number

  16. Experimental study and constitutive modeling of the viscoelastic mechanical properties of the human prolapsed vaginal tissue.

    Science.gov (United States)

    Peña, Estefania; Calvo, B; Martínez, M A; Martins, P; Mascarenhas, T; Jorge, R M N; Ferreira, A; Doblaré, M

    2010-02-01

    In this paper, the viscoelastic mechanical properties of vaginal tissue are investigated. Using previous results of the authors on the mechanical properties of biological soft tissues and newly experimental data from uniaxial tension tests, a new model for the viscoelastic mechanical properties of the human vaginal tissue is proposed. The structural model seems to be sufficiently accurate to guarantee its application to prediction of reliable stress distributions, and is suitable for finite element computations. The obtained results may be helpful in the design of surgical procedures with autologous tissue or prostheses.

  17. Damping Analysis of Cylindrical Composite Structures with Enhanced Viscoelastic Properties

    Science.gov (United States)

    Kliem, Mathias; Høgsberg, Jan; Vanwalleghem, Joachim; Filippatos, Angelos; Hoschützky, Stefan; Fotsing, Edith-Roland; Berggreen, Christian

    2018-04-01

    Constrained layer damping treatments are widely used in mechanical structures to damp acoustic noise and mechanical vibrations. A viscoelastic layer is thereby applied to a structure and covered by a stiff constraining layer. When the structure vibrates in a bending mode, the viscoelastic layer is forced to deform in shear mode. Thus, the vibration energy is dissipated as low grade frictional heat. This paper documents the efficiency of passive constrained layer damping treatments for low frequency vibrations of cylindrical composite specimens made of glass fibre-reinforced plastics. Different cross section geometries with shear webs have been investigated in order to study a beneficial effect on the damping characteristics of the cylinder. The viscoelastic damping layers are placed at different locations within the composite cylinder e.g. circumferential and along the neutral plane to evaluate the location-dependent efficiency of constrained layer damping treatments. The results of the study provide a thorough understanding of constrained layer damping treatments and an improved damping design of the cylindrical composite structure. The highest damping is achieved when placing the damping layer in the neutral plane perpendicular to the bending load. The results are based on free decay tests of the composite structure.

  18. Viscoelastic properties of poly(butylene succinate)-co-adipate) nanocomposites

    CSIR Research Space (South Africa)

    Al-Thabaiti, SA

    2015-03-01

    Full Text Available and melt-state viscoelastic properties of neat PBSA and various nanocomposites were studied in detail. The dynamic mechanical studies demonstrated an increase in the storage modulus of PBSA matrix with organoclay loading. Melt-state rheological properties...

  19. Trefoil factor peptide 3 is positively correlated with the viscoelastic properties of the cervical mucus plug

    DEFF Research Database (Denmark)

    Bastholm, Sara Kjær; Samson, Mie Hesselund; Becher, Naja

    2017-01-01

    The viscoelastic properties of the cervical mucus plug are considered essential for the occlusion of the cervical canal and thereby for protection against ascending infections during pregnancy. Factors controlling this property are virtually unknown. This study explores a possible role of trefoil...

  20. Changes in the texture and viscoelastic properties of bread containing rice porridge during storage.

    Science.gov (United States)

    Tsai, Chia-Ling; Sugiyama, Junichi; Shibata, Mario; Kokawa, Mito; Fujita, Kaori; Tsuta, Mizuki; Nabetani, Hiroshi; Araki, Tetsuya

    2012-01-01

    The objective of this study was to investigate the effects of rice porridge on the texture and viscoelastic properties of bread during storage. Three types of bread, wheat flour bread, 15% rice flour bread, and 15% rice porridge bread, were prepared. After baking and storing the bread for 24 h, 48 h, and 72 h at room temperature, we measured the texture and viscoelastic properties of the bread crumbs by texture profile analysis (TPA) and creep test. The 15% rice porridge bread showed a significantly higher specific volume and maintained softer crumbs than the other two types (pbread crumbs during storage.

  1. Influence of viscoelastic property on laser-generated surface acoustic waves in coating-substrate systems

    International Nuclear Information System (INIS)

    Sun Hongxiang; Zhang Shuyi; Xu Baiqiang

    2011-01-01

    Taking account of the viscoelasticity of materials, the pulsed laser generation of surface acoustic waves in coating-substrate systems has been investigated quantitatively by using the finite element method. The displacement spectra of the surface acoustic waves have been calculated in frequency domain for different coating-substrate systems, in which the viscoelastic properties of the coatings and substrates are considered separately. Meanwhile, the temporal displacement waveforms have been obtained by applying inverse fast Fourier transforms. The numerical results of the normal surface displacements are presented for different configurations: a single plate, a slow coating on a fast substrate, and a fast coating on a slow substrate. The influences of the viscoelastic properties of the coating and the substrate on the attenuation of the surface acoustic waves have been studied. In addition, the influence of the coating thickness on the attenuation of the surface acoustic waves has been also investigated in detail.

  2. Effect of Age and Exercise on the Viscoelastic Properties of Rat Tail Tendon

    Science.gov (United States)

    LaCroix, Andrew S.; Duenwald-Kuehl, Sarah E.; Brickson, Stacey; Akins, Tiffany L.; Diffee, Gary; Aiken, Judd; Vanderby, Ray; Lakes, Roderic S.

    2013-01-01

    Tendon mechanical properties are thought to degrade during aging but improve with exercise. A remaining question is whether exercise in aged animals provides sufficient regenerative, systemic stimulus to restore younger mechanical behaviors. Herein we address that question with tail tendons from aged and exercised rats, which would be subject to systemic effects but not direct loading from the exercise regimen. Twenty-four month old rats underwent one of three treadmill exercise training protocols for 12 months: sedentary (walking at 0° incline for 5 min/day), moderate (running at 0° incline for 30 min/day), or high (running at 4° incline for 30 min/day). A group of 9 month old rats were used to provide an adult control, while a group of 3 month old rats provided a young control. Tendons were harvested at sacrifice and mechanically tested. Results show significant age-dependent differences in modulus, ultimate stress, relaxation rate, and percent relaxation. Relaxation rate was strain-dependent, consistent with nonlinear superposition or Schapery models but not with quasilinear viscoelasticity (QLV). Trends in exercise data suggest that with exercise, tendons assume the elastic character of younger rats (lower elastic modulus and ultimate stress). PMID:23549897

  3. Enhancing the Damping Properties of Viscoelastic Composites by Topology Optimization

    DEFF Research Database (Denmark)

    Andreasen, Casper Schousboe; Andreassen, Erik; Sigmund, Ole

    Vibrations, if undamped, might be annoying or even dangerous. Most often some kind of damping mechanism is applied in order to limit the vibration level. Vibration insulators, for instance of rubber material, have favorable damping characteristics but lack the structural stiffness often needed...... in engineering structures. Thus, materials or composites with high stiffness and high damping are of great interest to the industry. The inherent compromise between high stiffness and high damping in viscoelastic materials has been treated theoretically [2, 3] and experimentally [1]. It has been shown that high...

  4. Measuring cell viscoelastic properties using a force-spectrometer: influence of protein-cytoplasm interactions.

    Science.gov (United States)

    Canetta, Elisabetta; Duperray, Alain; Leyrat, Anne; Verdier, Claude

    2005-01-01

    Cell adhesive and rheological properties play a very important role in cell transmigration through the endothelial barrier, in particular in the case of inflammation (leukocytes) or cancer metastasis (cancer cells). In order to characterize cell viscoelastic properties, we have designed a force spectrometer (AFM) which can stretch cells thereby allowing measurement of their rheological properties. This custom-made force spectrometer allows two different visualizations, one lateral and one from below. It allows investigation of the effects of rheology involved during cell stretching. To test the ability of our system to characterize such viscoelastic properties, ICAM-1 transfected CHO cells were analyzed. Two forms of ICAM-1 were tested; wild type ICAM-1, which can interact with the cytoskeleton, and a mutant form which lacks the cytoplasmic domain, and is unable to associate with the cytoskeleton. Stretching experiments carried out on these cells show the formation of long filaments. Using a previous model of filament elongation, we could determine the viscoelastic properties of a single cell. As expected, different viscoelastic components were found between the wild type and the mutant, which reveal that the presence of interactions between ICAM-1 and the cytoskeleton increases the stiffness of the cell.

  5. Viscoelastic Properties of Extracellular Polymeric Substances Can Strongly Affect Their Washing Efficiency from Reverse Osmosis Membranes.

    Science.gov (United States)

    Ferrando Chavez, Diana Lila; Nejidat, Ali; Herzberg, Moshe

    2016-09-06

    The role of the viscoelastic properties of biofouling layers in their removal from the membrane was studied. Model fouling layers of extracellular polymeric substances (EPS) originated from microbial biofilms of Pseudomonas aeruginosa PAO1 differentially expressing the Psl polysaccharide were used for controlled washing experiments of fouled RO membranes. In parallel, adsorption experiments and viscoelastic modeling of the EPS layers were conducted in a quartz crystal microbalance with dissipation (QCM-D). During the washing stage, as shear rate was elevated, significant differences in permeate flux recovery between the three different EPS layers were observed. According to the amount of organic carbon remained on the membrane after washing, the magnitude of Psl production provides elevated resistance of the EPS layer to shear stress. The highest flux recovery during the washing stage was observed for the EPS with no Psl. Psl was shown to elevate the layer's shear modulus and shear viscosity but had no effect on the EPS adhesion to the polyamide surface. We conclude that EPS retain on the membrane as a result of the layer viscoelastic properties. These results highlight an important relation between washing efficiency of fouling layers from membranes and their viscoelastic properties, in addition to their adhesion properties.

  6. Effect of long-time immersion of soft denture liners in water on viscoelastic properties.

    Science.gov (United States)

    Iwasaki, Naohiko; Yamaki, Chisato; Takahashi, Hidekazu; Oki, Meiko; Suzuki, Tetsuya

    2017-09-26

    Aim of this study was to investigate the effect of long-time immersion of soft denture liners in 37°C water on viscoelastic properties. Six silicone-based and two acrylic resin-based soft denture liners were selected. Cylindrical specimens were stored in distilled water at 37°C for 6 months. Viscoelastic properties, which were instantaneous and delayed elastic displacements, viscous flow, and residual displacement, were determined using a creep meter, and analyzed with 2-way analysis of variance and Tukey's comparison (α=0.05). Viscoelastic properties and their time-dependent changes were varied among materials examined. The observed viscoelastic properties of three from six silicone-based liners did not significantly change after 6-month immersion, but those of two acrylic resin-based liners significantly changed with the increase of immersion time. However, the sum of initial instantaneous elastic displacement and delayed elastic displacement of two acrylic resin-based liners during 6-month immersion changed less than 10%, which might indicate clinically sufficient elastic performance.

  7. Normal age-related viscoelastic properties of chondrons and chondrocytes isolated from rabbit knee

    Institute of Scientific and Technical Information of China (English)

    DUAN Wang-ping; SUN Zhen-wei; LI Qi; LI Chun-jiang; WANG Li; CHEN Wei-yi; Jennifer Tickner; ZHENG Ming-hao; WEI Xiao-chun

    2012-01-01

    Background The mechanical microenvironment of the chondrocytes plays an important role in cartilage homeostasis and in the health of the joint.The pericellular matrix,cellular membrane of the chondrocytes,and their cytoskeletal structures are key elements in the mechanical environment.The aims of this study are to measure the viscoelastic properties of isolated chondrons and chondrocytes from rabbit knee cartilage using micropipette aspiration and to determine the effect of aging on these properties.Methods Three age groups of rabbit knees were evaluated:(1) young (2 months,n=10);(2) adult (8 months,n=10);and (3) old (31 months,n=10).Chondrocytes were isolated from the right knee cartilage and chondrons were isolated from left knees using enzymatic methods.Micropipette aspiration combined with a standard linear viscoelastic solid model was used to quantify changes in the viscoelastic properties of chondrons and chondrocytes within 2 hours of isolation.The morphology and structure of isolated chondrons were evaluated by optical microscope using hematoxylin and eosin staining and collagen-6 immunofluorescence staining.Results In response to an applied constant 0.3-0.4 kPa of negative pressure,all chondrocytes exhibited standard linear viscoelastic solid properties.Model predictions of the creep data showed that the average equilibrium modulus (E∞),instantaneous modulus (E0).and apparent viscosity (μ) of old chondrocytes was significantly lower than the young and adult chondrocytes (P<0.001);however,no difference was found between young and adult chondrocytes (P>0.05).The adult and old chondrons generally possessed a thicker pericellular matrix (PCM) with more enclosed cells.The young and adult chondrons exhibited the same viscoelastic creep behavior under a greater applied pressure (1.0-1.1kPa) without the deformation seen in the old chondrons.The viscoelastic properties (E∞,E0,and u) of young and adult chondrons were significantly greater than that observed

  8. Damping analysis of cylindrical composite structures with enhanced viscoelastic properties

    DEFF Research Database (Denmark)

    Kliem, Mathias; Høgsberg, Jan Becker; Vanwalleghem, Joachim

    2018-01-01

    is forced to deform in shear mode. Thus, the vibration energy is dissipated as low grade frictional heat. This paper documents the efficiency of passive constrained layer damping treatments for low frequency vibrations of cylindrical composite specimens made of glass fibre-reinforced plastics. Different cross...... section geometries with shear webs have been investigated in order to study a beneficial effect on the damping characteristics of the cylinder. The viscoelastic damping layers are placed at different locations within the composite cylinder e.g. circumferential and along the neutral plane to evaluate...... in the neutral plane perpendicular to the bending load. The results are based on free decay tests of the composite structure....

  9. Microscale characterization of the viscoelastic properties of hydrogel biomaterials using dual-mode ultrasound elastography.

    Science.gov (United States)

    Hong, Xiaowei; Stegemann, Jan P; Deng, Cheri X

    2016-05-01

    Characterization of the microscale mechanical properties of biomaterials is a key challenge in the field of mechanobiology. Dual-mode ultrasound elastography (DUE) uses high frequency focused ultrasound to induce compression in a sample, combined with interleaved ultrasound imaging to measure the resulting deformation. This technique can be used to non-invasively perform creep testing on hydrogel biomaterials to characterize their viscoelastic properties. DUE was applied to a range of hydrogel constructs consisting of either hydroxyapatite (HA)-doped agarose, HA-collagen, HA-fibrin, or preosteoblast-seeded collagen constructs. DUE provided spatial and temporal mapping of local and bulk displacements and strains at high resolution. Hydrogel materials exhibited characteristic creep behavior, and the maximum strain and residual strain were both material- and concentration-dependent. Burger's viscoelastic model was used to extract characteristic parameters describing material behavior. Increased protein concentration resulted in greater stiffness and viscosity, but did not affect the viscoelastic time constant of acellular constructs. Collagen constructs exhibited significantly higher modulus and viscosity than fibrin constructs. Cell-seeded collagen constructs became stiffer with altered mechanical behavior as they developed over time. Importantly, DUE also provides insight into the spatial variation of viscoelastic properties at sub-millimeter resolution, allowing interrogation of the interior of constructs. DUE presents a novel technique for non-invasively characterizing hydrogel materials at the microscale, and therefore may have unique utility in the study of mechanobiology and the characterization of hydrogel biomaterials. Copyright © 2016 Elsevier Ltd. All rights reserved.

  10. Combining adhesive contact mechanics with a viscoelastic material model to probe local material properties by AFM.

    Science.gov (United States)

    Ganser, Christian; Czibula, Caterina; Tscharnuter, Daniel; Schöberl, Thomas; Teichert, Christian; Hirn, Ulrich

    2017-12-20

    Viscoelastic properties are often measured using probe based techniques such as nanoindentation (NI) and atomic force microscopy (AFM). Rarely, however, are these methods verified. In this article, we present a method that combines contact mechanics with a viscoelastic model (VEM) composed of springs and dashpots. We further show how to use this model to determine viscoelastic properties from creep curves recorded by a probe based technique. We focus on using the standard linear solid model and the generalized Maxwell model of order 2. The method operates in the range of 0.01 Hz to 1 Hz. Our approach is suitable for rough surfaces by providing a defined contact area using plastic pre-deformation of the material. The very same procedure is used to evaluate AFM based measurements as well as NI measurements performed on polymer samples made from poly(methyl methacrylate) and polycarbonate. The results of these measurements are then compared to those obtained by tensile creep tests also performed on the same samples. It is found that the tensile test results differ considerably from the results obtained by AFM and NI methods. The similarity between the AFM results and NI results suggests that the proposed method is capable of yielding results comparable to NI but with the advantage of the imaging possibilities of AFM. Furthermore, all three methods allowed a clear distinction between PC and PMMA by means of their respective viscoelastic properties.

  11. Influence of the viscoelastic properties of the respiratory system on the energetically optimum breathing frequency.

    Science.gov (United States)

    Bates, J H; Milic-Emili, J

    1993-01-01

    We hypothesized that the viscoelastic properties of the respiratory system should have significant implications for the energetically optimal frequency of breathing, in view of the fact that these properties cause marked dependencies of overall system resistance and elastance on frequency. To test our hypothesis we simulated two models of canine and human respiratory system mechanics during sinusoidal breathing and calculated the inspiratory work (WI) and pressure-time integral (PTI) per minute under both resting and exercise conditions. The two models were a two-compartment viscoelastic model and a single-compartment model. Requiring minute alveolar ventilation to be fixed, we found that both models predicted almost identical optimum breathing frequencies. The calculated PTI was very insensitive to increases in breathing frequency above the optimal frequencies, while WI was found to increase slowly with frequency above its optimum. In contrast, both WI and PTI increased sharply as frequency decreased below their respective optima. A sensitivity analysis showed that the model predictions were very insensitive to the elastance and resistance values chosen to characterize tissue viscoelasticity. We conclude that the WI criterion for choosing the frequency of breathing is compatible with observations in nature, whereas the optimal frequency predictions of the PTI are rather too high. Both criteria allow for a fairly wide margin of choice in frequency above the optimum values without incurring excessive additional energy expenditure. Furthermore, contrary to our expectations, the viscoelastic properties of the respiratory system tissues do not pose a noticeable problem to the respiratory controller in terms of energy expenditure.

  12. Visco-Elastic Properties of Sodium Hyaluronate Solutions

    Science.gov (United States)

    Kulicke, Werner-Michael; Meyer, Fabian; Bingöl, Ali Ö.; Lohmann, Derek

    2008-07-01

    Sodium Hyaluronate (NaHA) is a member of the glycosaminoglycans and is present in the human organism as part of the synovial fluid and the vitreous body. HA is mainly commercialized as sodium or potassium salt. It can be extracted from cockscombs or can be produced by bacterial fermentation ensuring a low protein content. Because of its natural origin and toxicological harmlessness, NaHA is used to a great extent for pharmaceutical and cosmetic products. In medical applications, NaHA is already being used as a component of flushing and stabilizing fluids in the treatment of eye cataract and as a surrogate for natural synovial fluid. Another growing domain in the commercial utilization of NaHA is the field of skin care products like dermal fillers or moisturizers. In this spectrum, NaHA is used in dilute over semidilute up to concentrated (0viscoelastic behavior. We therefore present in this contribution the results of a comprehensive investigation of the viscous and elastic material functions of different NaHA samples. This includes, besides shear flow and oscillatory experiments, the performance of rheo-optical measurements in order to determine the elastic component in the range of low shear rates and low concentrations.

  13. 3D printing of an interpenetrating network hydrogel material with tunable viscoelastic properties.

    Science.gov (United States)

    Bootsma, Katherine; Fitzgerald, Martha M; Free, Brandon; Dimbath, Elizabeth; Conjerti, Joe; Reese, Greg; Konkolewicz, Dominik; Berberich, Jason A; Sparks, Jessica L

    2017-06-01

    Interpenetrating network (IPN) hydrogel materials are recognized for their unique mechanical properties. While IPN elasticity and toughness properties have been explored in previous studies, the factors that impact the time-dependent stress relaxation behavior of IPN materials are not well understood. Time-dependent (i.e. viscoelastic) mechanical behavior is a critical design parameter in the development of materials for a variety of applications, such as medical simulation devices, flexible substrate materials, cellular mechanobiology substrates, or regenerative medicine applications. This study reports a novel technique for 3D printing alginate-polyacrylamide IPN gels with tunable elastic and viscoelastic properties. The viscoelastic stress relaxation behavior of the 3D printed alginate-polyacrylamide IPN hydrogels was influenced most strongly by varying the concentration of the acrylamide cross-linker (MBAA), while the elastic modulus was affected most by varying the concentration of total monomer material. The material properties of our 3D printed IPN constructs were consistent with those reported in the biomechanics literature for soft tissues such as skeletal muscle, cardiac muscle, skin and subcutaneous tissue. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. Dominant role of wormlike micelles in temperature-responsive viscoelastic properties of their mixtures with polymeric chains

    KAUST Repository

    Molchanov, Vyacheslav S.; Philippova, Olga E.

    2013-01-01

    Temperature effects on the rheological properties of viscoelastic solutions containing entangled wormlike micelles of potassium oleate and hydrophobically modified polyacrylamide were studied in a wide range of polymer concentrations. A very

  15. Physico-chemical and viscoelastic properties of high pressure homogenized lemon peel fiber fraction suspensions obtained after sequential pectin extraction

    NARCIS (Netherlands)

    Willemsen, K.L.D.D.; Panozzo, A.; Moelants, K.; Debon, S.J.J.; Desmet, C.; Cardinaels, R.M.; Moldenaers, P.; Wallecan, J.; Hendrickx, M.E.G.

    2017-01-01

    The viscoelastic properties of high pressure homogenized lemon peel cell wall fiber suspensions, obtained after sequential selective pectin extraction, were investigated in the current study. For comparison, a general pectin extraction was additionally performed on lemon peel under acid thermal

  16. A New Approach for Studying Nonlinear Dynamic Response of a Thin Plate with Internal Resonance in a Fractional Viscoelastic Medium

    Directory of Open Access Journals (Sweden)

    Yury A. Rossikhin

    2015-01-01

    Full Text Available In the previous analysis, the dynamic behaviour of a nonlinear plate embedded into a fractional derivative viscoelastic medium has been studied by the method of multiple time scales under the conditions of the internal resonances two-to-one and one-to-one, as well as the internal combinational resonances for the case when the linear parts of nonlinear equations of motion occur to be coupled. A new approach proposed in this paper allows one to uncouple the linear parts of equations of motion of the plate, while the same method, the method of multiple time scales, has been utilized for solving nonlinear equations. The influence of viscosity on the energy exchange mechanism between interacting nonlinear modes has been analyzed. It has been shown that for some internal resonances there exist such particular cases when it is possible to obtain two first integrals, namely, the energy integral and the stream function, which allows one to reduce the problem to the calculation of elliptic integrals. The new approach enables one to solve the problems of vibrations of thin bodies more efficiently.

  17. Measurement of Viscoelastic Properties of Condensed Matter using Magnetic Resonance Elastography

    Science.gov (United States)

    Gruwel, Marco L. H.; Latta, Peter; Matwiy, Brendon; Sboto-Frankenstein, Uta; Gervai, Patricia; Tomanek, Boguslaw

    2010-01-01

    Magnetic resonance elastography (MRE) is a phase contrast technique that provides a non-invasive means of evaluating the viscoelastic properties of soft condensed matter. This has a profound bio-medical significance as it allows for the virtual palpation of areas of the body usually not accessible to the hands of a medical practitioner, such as the brain. Applications of MRE are not restricted to bio-medical applications, however, the viscoelastic properties of prepackaged food products can also non-invasively be determined. Here we describe the design and use of a modular MRE acoustic actuator that can be used for experiments ranging from the human brain to pre-packaged food products. The unique feature of the used actuator design is its simplicity and flexibility, which allows easy reconfiguration.

  18. Quasi-linear viscoelastic properties of the human medial patello-femoral ligament.

    Science.gov (United States)

    Criscenti, G; De Maria, C; Sebastiani, E; Tei, M; Placella, G; Speziali, A; Vozzi, G; Cerulli, G

    2015-12-16

    The evaluation of viscoelastic properties of human medial patello-femoral ligament is fundamental to understand its physiological function and contribution as stabilizer for the selection of the methods of repair and reconstruction and for the development of scaffolds with adequate mechanical properties. In this work, 12 human specimens were tested to evaluate the time- and history-dependent non linear viscoelastic properties of human medial patello-femoral ligament using the quasi-linear viscoelastic (QLV) theory formulated by Fung et al. (1972) and modified by Abramowitch and Woo (2004). The five constant of the QLV theory, used to describe the instantaneous elastic response and the reduced relaxation function on stress relaxation experiments, were successfully evaluated. It was found that the constant A was 1.21±0.96MPa and the dimensionless constant B was 26.03±4.16. The magnitude of viscous response, the constant C, was 0.11±0.02 and the initial and late relaxation time constants τ1 and τ2 were 6.32±1.76s and 903.47±504.73s respectively. The total stress relaxation was 32.7±4.7%. To validate our results, the obtained constants were used to evaluate peak stresses from a cyclic stress relaxation test on three different specimens. The theoretically predicted values fit the experimental ones demonstrating that the QLV theory could be used to evaluate the viscoelastic properties of the human medial patello-femoral ligament. Copyright © 2015 Elsevier Ltd. All rights reserved.

  19. The formation and deformation of protein structures with viscoelastic properties

    NARCIS (Netherlands)

    Riemsdijk, van L.E.

    2011-01-01

    This study describes the formation of a gluten substitute.

    Chapter 1 describes the properties that are necessary to obtain a gluten substitute.

    Chapter 2 describes the formation and properties of protein particle suspensions. Two proteins with different

  20. Evaluation of Heating and Shearing on the Viscoelastic Properties of Calcium Hydroxyapatite Used in Injection Laryngoplasty.

    Science.gov (United States)

    Mahboubi, Hossein; Mohraz, Ali; Verma, Sunil P

    2016-03-01

    To compare the viscoelastic properties of calcium hydroxyapatite (CaHA) to carboxymethylcellulose (CMC) injectables used for injection laryngoplasty and determine if they are affected by heating and shearing. Experimental. University laboratory. Vocal fold injection laryngoplasty with CaHA is oftentimes challenging due to the amount of pressure necessary to push the injectate through a needle. Anecdotal techniques, such as heating the product, have been suggested to facilitate injection. The viscoelastic properties of CaHA and CMC were measured with a rheometer. The effects of heating and shearing on sample viscoelasticity were recorded. CaHA was 9.5 times more viscous than CMC (43,100 vs 4540 Pa·s). Heating temporarily decreased the viscosity of CaHA by 32%. However, it also caused the viscosity to subsequently increase after time. Shearing of CaHA reduced its viscosity by 26%. Heating and shearing together temporarily reduced the viscosity of CaHA by 52%. A combination of heating and shearing had a more profound effect than heating or shearing alone on the viscosity of CaHA, potentially making it easier to inject temporarily. Long-term and in vivo studies are required to further analyze the effect of heating and shearing on CaHA injectables. © American Academy of Otolaryngology—Head and Neck Surgery Foundation 2016.

  1. Viscoelastic properties of tablets from Osborne fractions, pentosans, flour and bread evaluated by creep tests

    Science.gov (United States)

    Escalante-Aburto, Anayansi; de Dios Figueroa-Cárdenas, Juan; Véles-Medina, José Juan; Ponce-García, Néstor; Hernández-Estrada, Zorba Josué; Rayas-Duarte, Patricia; Simsek, Senay

    2017-07-01

    Little attention has been given to the influence of non-gluten components on the viscoelastic properties of wheat flour dough, bread making process and their products. The aim of this study was to evaluate by creep tests the viscoelastic properties of tablets manufactured from Osborne solubility fractions (globulins, gliadins, glutenins, albumins and residue), pentosans, flour and bread. Hard and soft wheat cultivars were used to prepare the reconstituted tablets. Sintered tablets (except flour and bread) showed similar values to those obtained from the sum of the regression coefficients of the fractions. Gliadins and albumins accounted for about 54% of the total elasticity. Gliadins contributed with almost half of the total viscosity (45.7%), and showed the highest value for the viscosity coefficient of the viscous element. When the effect of dilution was evaluated, the residue showed the highest instantaneous elastic modulus (788.2 MPa). Retardation times of the first element (λ1 3.5 s) were about 10 times lower than the second element (λ2 39.3 s). The analysis of compliance of data corrected by protein content in flour showed that the residue fraction presented the highest values. An important contribution of non-gluten components (starch, albumins and globulins) on the viscoelastic performance of sintered tablets from Osborne fractions, flour and bread was found.

  2. The viscoelastic standard nonlinear solid model: predicting the response of the lumbar intervertebral disk to low-frequency vibrations.

    Science.gov (United States)

    Groth, Kevin M; Granata, Kevin P

    2008-06-01

    Due to the mathematical complexity of current musculoskeletal spine models, there is a need for computationally efficient models of the intervertebral disk (IVD). The aim of this study is to develop a mathematical model that will adequately describe the motion of the IVD under axial cyclic loading as well as maintain computational efficiency for use in future musculoskeletal spine models. Several studies have successfully modeled the creep characteristics of the IVD using the three-parameter viscoelastic standard linear solid (SLS) model. However, when the SLS model is subjected to cyclic loading, it underestimates the load relaxation, the cyclic modulus, and the hysteresis of the human lumbar IVD. A viscoelastic standard nonlinear solid (SNS) model was used to predict the response of the human lumbar IVD subjected to low-frequency vibration. Nonlinear behavior of the SNS model was simulated by a strain-dependent elastic modulus on the SLS model. Parameters of the SNS model were estimated from experimental load deformation and stress-relaxation curves obtained from the literature. The SNS model was able to predict the cyclic modulus of the IVD at frequencies of 0.01 Hz, 0.1 Hz, and 1 Hz. Furthermore, the SNS model was able to quantitatively predict the load relaxation at a frequency of 0.01 Hz. However, model performance was unsatisfactory when predicting load relaxation and hysteresis at higher frequencies (0.1 Hz and 1 Hz). The SLS model of the lumbar IVD may require strain-dependent elastic and viscous behavior to represent the dynamic response to compressive strain.

  3. Impact of polymer modification on mechanical and viscoelastic properties.

    Science.gov (United States)

    2015-10-01

    This study was initiated with the aim of evaluating the relative impact of different cross-linking agents : on the rheological and morphological properties of polymer modified asphalt binders (PMAs). To : complete this objective, two cross-linking ag...

  4. Viscoelasticity and nonlinear simple shear flow behavior of an entangled asymmetric exact comb polymer solution

    KAUST Repository

    Snijkers, F.; Kirkwood, K. M.; Vlassopoulos, D.; Leal, L. G.; Nikopoulou, A.; Hadjichristidis, Nikolaos; Coppola, S.

    2016-01-01

    We report upon the characterization of the steady-state shear stresses and first normal stress differences as a function of shear rate using mechanical rheometry (both with a standard cone and plate and with a cone partitioned plate) and optical rheometry (with a flow-birefringence setup) of an entangled solution of asymmetric exact combs. The combs are polybutadienes (1,4-addition) consisting of an H-skeleton with an additional off-center branch on the backbone. We chose to investigate a solution in order to obtain reliable nonlinear shear data in overlapping dynamic regions with the two different techniques. The transient measurements obtained by cone partitioned plate indicated the appearance of overshoots in both the shear stress and the first normal stress difference during start-up shear flow. Interestingly, the overshoots in the start-up normal stress difference started to occur only at rates above the inverse stretch time of the backbone, when the stretch time of the backbone was estimated in analogy with linear chains including the effects of dynamic dilution of the branches but neglecting the effects of branch point friction, in excellent agreement with the situation for linear polymers. Flow-birefringence measurements were performed in a Couette geometry, and the extracted steady-state shear and first normal stress differences were found to agree well with the mechanical data, but were limited to relatively low rates below the inverse stretch time of the backbone. Finally, the steady-state properties were found to be in good agreement with model predictions based on a nonlinear multimode tube model developed for linear polymers when the branches are treated as solvent.

  5. Viscoelasticity and nonlinear simple shear flow behavior of an entangled asymmetric exact comb polymer solution

    KAUST Repository

    Snijkers, F.

    2016-03-31

    We report upon the characterization of the steady-state shear stresses and first normal stress differences as a function of shear rate using mechanical rheometry (both with a standard cone and plate and with a cone partitioned plate) and optical rheometry (with a flow-birefringence setup) of an entangled solution of asymmetric exact combs. The combs are polybutadienes (1,4-addition) consisting of an H-skeleton with an additional off-center branch on the backbone. We chose to investigate a solution in order to obtain reliable nonlinear shear data in overlapping dynamic regions with the two different techniques. The transient measurements obtained by cone partitioned plate indicated the appearance of overshoots in both the shear stress and the first normal stress difference during start-up shear flow. Interestingly, the overshoots in the start-up normal stress difference started to occur only at rates above the inverse stretch time of the backbone, when the stretch time of the backbone was estimated in analogy with linear chains including the effects of dynamic dilution of the branches but neglecting the effects of branch point friction, in excellent agreement with the situation for linear polymers. Flow-birefringence measurements were performed in a Couette geometry, and the extracted steady-state shear and first normal stress differences were found to agree well with the mechanical data, but were limited to relatively low rates below the inverse stretch time of the backbone. Finally, the steady-state properties were found to be in good agreement with model predictions based on a nonlinear multimode tube model developed for linear polymers when the branches are treated as solvent.

  6. Viscoelastic Properties of Dental Pulp Tissue and Ramifications on Biomaterial Development for Pulp Regeneration.

    Science.gov (United States)

    Erisken, Cevat; Kalyon, Dilhan M; Zhou, Jian; Kim, Sahng G; Mao, Jeremy J

    2015-10-01

    A critical step in biomaterial selection effort is the determination of material as well as the biological properties of the target tissue. Previously, the selection of biomaterials and carriers for dental pulp regeneration has been solely based on empirical experience. In this study, first, the linear viscoelastic material functions and compressive properties of miniature pig dental pulp were characterized using small-amplitude oscillatory shear and uniaxial compression at a constant rate. They were then compared with the properties of hydrogels (ie, agarose, alginate, and collagen) that are widely used in tissue regeneration. The comparisons of the linear viscoelastic material functions of the native pulp tissue with those of the 3 hydrogels revealed the gel-like behavior of the pulp tissue over a relatively large range of time scales (ie, over the frequency range of 0.1-100 rps). At the constant gelation agent concentration of 2%, the dynamic properties (ie, storage and loss moduli and the tanδ) of the collagen-based gel approached those of the native tissue. Under uniaxial compression, the peak normal stresses and compressive moduli of the agarose gel were similar to those of the native tissue, whereas alginate and collagen exhibited significantly lower compressive properties. The linear viscoelastic and uniaxial compressive properties of the dental pulp tissue reported here should enable the more appropriate selection of biogels for dental pulp regeneration via the better tailoring of gelation agents and their concentrations to better mimic the dynamic and compressive properties of native pulp tissue. Copyright © 2015 American Association of Endodontists. Published by Elsevier Inc. All rights reserved.

  7. A homogenization approach for the effective drained viscoelastic properties of 2D porous media and an application for cortical bone.

    Science.gov (United States)

    Nguyen, Sy-Tuan; Vu, Mai-Ba; Vu, Minh-Ngoc; To, Quy-Dong

    2018-02-01

    Closed-form solutions for the effective rheological properties of a 2D viscoelastic drained porous medium made of a Generalized Maxwell viscoelastic matrix and pore inclusions are developed and applied for cortical bone. The in-plane (transverse) effective viscoelastic bulk and shear moduli of the Generalized Maxwell rheology of the homogenized medium are expressed as functions of the porosity and the viscoelastic properties of the solid phase. When deriving these functions, the classical inverse Laplace-Carson transformation technique is avoided, due to its complexity, by considering the short and long term approximations. The approximated results are validated against exact solutions obtained from the inverse Laplace-Carson transform for a simple configuration when the later is available. An application for cortical bone with assumption of circular pore in the transverse plane shows that the proposed approximation fit very well with experimental data. Copyright © 2017 Elsevier Ltd. All rights reserved.

  8. Effect of temperature on viscoelastic properties of semisolid dairy desserts

    OpenAIRE

    Tárrega, Amparo; Durán, Luis; Costell, Elvira

    2003-01-01

    The “natillas”, semisolid dairy dessert of wide consumption in Spain, is composed of milk, starch, hydrocolloids, sugars, colorants and aromas. The particular characteristics of some ingredients, like fat content of milk, type of starch, and/or type and concentration of hydrocolloids, and their crossed interactions, will be reflected in notable differences in their rheological and sensory properties. Little information is available on the differences to be found in commercial samples of this ...

  9. Role of EVA viscoelastic properties in the protective performance of a sport shoe: computational studies.

    Science.gov (United States)

    Even-Tzur, Nurit; Weisz, Ety; Hirsch-Falk, Yifat; Gefen, Amit

    2006-01-01

    Modern sport shoes are designed to attenuate mechanical stress waves, mainly through deformation of the viscoelastic midsole which is typically made of ethylene vinyl acetate (EVA) foam. Shock absorption is obtained by flow of air through interconnected air cells in the EVA during shoe deformation under body-weight. However, when the shoe is overused and air cells collapse or thickness of the EVA is reduced, shock absorption capacity may be affected, and this may contribute to running injuries. Using lumped system and finite element models, we studied heel pad stresses and strains during heel-strike in running, considering the viscoelastic constitutive behavior of both the heel pad and EVA midsole. In particular, we simulated wear cases of the EVA, manifested in the modeling by reduced foam thickness, increased elastic stiffness, and shorter stress relaxation with respect to new shoe conditions. Simulations showed that heel pad stresses and strains were sensitive to viscous damping of the EVA. Wear of the EVA consistently increased heel pad stresses, and reduced EVA thickness was the most influential factor, e.g., for a 50% reduction in thickness, peak heel pad stress increased by 19%. We conclude that modeling of the heel-shoe interaction should consider the viscoelastic properties of the tissue and shoe components, and the age of the studied shoe.

  10. Effects of a Pseudophysiological Environment on the Elastic and Viscoelastic Properties of Collagen Gels

    Science.gov (United States)

    Meghezi, Sébastien; Couet, Frédéric; Chevallier, Pascale; Mantovani, Diego

    2012-01-01

    Vascular tissue engineering focuses on the replacement of diseased small-diameter blood vessels with a diameter less than 6 mm for which adequate substitutes still do not exist. One approach to vascular tissue engineering is to culture vascular cells on a scaffold in a bioreactor. The bioreactor establishes pseudophysiological conditions for culture (medium culture, 37°C, mechanical stimulation). Collagen gels are widely used as scaffolds for tissue regeneration due to their biological properties; however, they exhibit low mechanical properties. Mechanical characterization of these scaffolds requires establishing the conditions of testing in regard to the conditions set in the bioreactor. The effects of different parameters used during mechanical testing on the collagen gels were evaluated in terms of mechanical and viscoelastic properties. Thus, a factorial experiment was adopted, and three relevant factors were considered: temperature (23°C or 37°C), hydration (aqueous saline solution or air), and mechanical preconditioning (with or without). Statistical analyses showed significant effects of these factors on the mechanical properties which were assessed by tensile tests as well as stress relaxation tests. The last tests provide a more consistent understanding of the gels' viscoelastic properties. Therefore, performing mechanical analyses on hydrogels requires setting an adequate environment in terms of temperature and aqueous saline solution as well as choosing the adequate test. PMID:22844285

  11. Influence of gas injection on viscous and viscoelastic properties of Xanthan gum.

    Science.gov (United States)

    Bobade, Veena; Cheetham, Madalyn; Hashim, Jamal; Eshtiaghi, Nicky

    2018-05-01

    Xanthan gum is widely used as a model fluid for sludge to mimic the rheological behaviour under various conditions including impact of gas injection in sludge. However, there is no study to show the influence of gas injection on rheological properties of xanthan gum specifically at the concentrations at which it is used as a model fluid for sludge with solids concentration above 2%. In this paper, the rheological properties of aqueous xanthan gum solutions at different concentrations were measured over a range of gas injection flow rates. The effect of gas injection on both the flow and viscoelastic behaviour of Xanthan gum (using two different methods - a creep test and a time sweep test) was evaluated. The viscosity curve of different solid concentrations of digested sludge and waste activated sludge were compared with different solid concentrations of Xanthan gum and the results showed that Xanthan gum can mimic the flow behaviour of sludge in flow regime. The results in linear viscoelastic regime showed that increasing gas flow rate increases storage modulus (G'), indicating an increase in the intermolecular associations within the material structure leading to an increase in material strength and solid behaviour. Similarly, in creep test an increase in the gas flow rate decreased strain%, signifying that the material has become more resistant to flow. Both observed behaviour is opposite to what occurs in sludge under similar conditions. The results of both the creep test and the time sweep test indicated that choosing Xanthan gum aqueous solution as a transparent model fluid for sludge in viscoelastic regime under similar conditions involving gas injection in a concentration range studied is not feasible. However Xanthan gum can be used as a model material for sludge in flow regime; because it shows a similar behaviour to sludge. Copyright © 2018 Elsevier Ltd. All rights reserved.

  12. Viscoelastic properties of sweet potato complementary porridges as influenced by endogenous amylases.

    Science.gov (United States)

    Nabubuya, Agnes; Namutebi, Agnes; Byaruhanga, Yusuf; Schuller, Reidar B; Narvhus, Judith; Wicklund, Trude

    2017-11-01

    Sweet potato ( Ipomoea batatas L.) roots contain amylolytic enzymes, which hydrolyze starch thus having the potential to affect the viscosity of sweet potato porridges provided the appropriate working conditions for the enzymes are attained. In this study, the effect of sweet potato variety, postharvest handling conditions, freshly harvested and room/ambient stored roots (3 weeks), and slurry solids content on the viscoelastic properties of complementary porridges prepared using amylase enzyme activation technique were investigated. Five temperatures (55°C, 65°C, 70°C, 75°C, and 80°C) were used to activate sweet potato amylases and the optimum temperature was found to be 75°C. Stored sweet potato roots had higher soluble solids (⁰Brix) content in the pastes compared to fresh roots. In all samples, activation of amylases at 75°C caused changes in the viscoelastic parameters: phase angle (tan δ) and complex viscosity (η * ). Postharvest handling conditions and slurry solids content significantly affected the viscoelastic properties of the porridges with flours from stored roots yielding viscous (liquid-like) porridges and fresh roots producing elastic (solid-like) porridges. Increase in slurry solids content caused reduction in the phase angle values and increase in the viscosity of the sweet potato porridges. The viscosity of the porridges decreased with storage of sweet potato roots. These results provide a possibility for exploiting sweet potato endogenous amylases in the preparation of complementary porridges with both drinkable viscosities and appropriate energy and nutrient densities for children with varying energy needs.

  13. Study of normal and shear material properties for viscoelastic model of asphalt mixture by discrete element method

    DEFF Research Database (Denmark)

    Feng, Huan; Pettinari, Matteo; Stang, Henrik

    2015-01-01

    In this paper, the viscoelastic behavior of asphalt mixture was studied by using discrete element method. The dynamic properties of asphalt mixture were captured by implementing Burger’s contact model. Different ways of taking into account of the normal and shear material properties of asphalt mi...

  14. Statistical mapping of the effect of knee extension on thigh muscle viscoelastic properties using magnetic resonance elastography

    International Nuclear Information System (INIS)

    Barnhill, Eric; Kennedy, Paul; Van Beek, Edwin J R; Roberts, Neil; Hammer, Steven; Brown, Colin

    2013-01-01

    Skeletal muscle viscoelastic properties reflect muscle microstructure and neuromuscular activation. Elastographic methods, including magnetic resonance elastography, have been used to characterize muscle viscoelastic properties in terms of region of interest (ROI) measurements. The present study extended this approach to create thresholded pixel-by-pixel maps of viscoelastic properties of skeletal muscle during rest and knee extension in eleven subjects. ROI measurements were taken for individual quadricep muscles and the quadriceps region as a whole, and the viscoelastic parameter map pixels were statistically tested at positive false discovery rate q ⩽ 0.25. ROI measurements showed significant (p ⩽ 0.05) increase in storage modulus (G′) and loss modulus (G″), with G″ increasing more than G′, in agreement with previous findings. The q-value maps further identified the vastus intermedius as the primary driver of this change, with greater G″/G′ increase than surrounding regions. Additionally, a cluster of significant decrease in G″/G′ was found in the region of vastus lateralis below the fulcrum point of the lift. Viscoelastic parameter mapping of contracted muscle allows new insight into the relationship between physiology, neuromuscular activation, and human performance. (paper)

  15. The effect of rework content addition on the microstructure and viscoelastic properties of processed cheese.

    Science.gov (United States)

    Černíková, Michaela; Nebesářová, Jana; Salek, Richardos Nikolaos; Popková, Romana; Buňka, František

    2018-04-01

    The aim of this work was to add various amounts of rework (0.0 to 20.0% wt/wt) to processed cheeses with a dry matter content of 36% (wt/wt) and fat with a dry matter content of 45% (wt/wt). The effect of the rework addition on the viscoelastic properties and microstructure of the processed cheeses was observed. The addition of rework (in this case, to processed cheese with a spreadable consistency) in the amounts of 2.5, 5.0, and 10.0% (wt/wt) increased the firmness of the processed cheese. With the further addition of rework, the consistency of the processed cheeses no longer differed significantly. The conclusions obtained by the measurement of viscoelastic properties were supported by cryo-scanning electron microscopy, where fat droplets in samples with added rework of over 10.0% (wt/wt) were smaller than fat droplets in processed cheeses with lower additions of rework. Copyright © 2018 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

  16. Viscoelastic properties of PLA/PCL blends compatibilized with different methods

    Science.gov (United States)

    Shin, Boo Young; Han, Do Hung

    2017-11-01

    The aim of this study was to observe changes in the viscoelastic properties of PLA/PCL (80/20) blends produced using different compatibilization methods. Reactive extrusion and high-energy radiation methods were used for blend compatibilization. Storage and loss moduli, complex viscosity, transient stress relaxation modulus, and tan δ of blends were analyzed and blend morphologies were examined. All compatibilized PLA/PCL blends had smaller dispersed particle sizes than the non-compatibilized blend, and well compatibilized blends had finer morphologies than poorly compatibilized blends. Viscoelastic properties differentiated well compatibilized and poorly compatibilized blends. Well compatibilized blends had higher storage and loss moduli and complex viscosities than those calculated by the log-additive mixing rule due to strong interfacial adhesion, whereas poorly compatibilized blends showed negative deviations due to weak interfacial adhesion. Moreover, well compatibilized blends had much slower stress relaxation than poorly compatibilized blends and didn't show tan δ plateau region caused by slippage at the interface between continuous and dispersed phases.

  17. Viscoelasticity, nonlinear shear start-up, and relaxation of entangled star polymers

    KAUST Repository

    Snijkers, Frank

    2013-07-23

    We report on a detailed rheological investigation of well-defined symmetric entangled polymer stars of low functionality with varying number of arms, molar mass of the arms, and solvent content. Emphasis is placed on the response of the stars in simple shear, during start-up, and for relaxation upon flow cessation. To reduce experimental artifacts associated with edge fracture (primarily) and wall slip, we employ a homemade cone-partitioned plate fixture which was successfully implemented in recent studies. Reliable data for these highly entangled stars could be obtained for Weissenberg numbers below 300. The appearance of a stress overshoot during start-up with a corresponding strain approaching a value of 2 suggests that in the investigated shear regime the stars orient but do not stretch. This is corroborated by the fact that the empirical Cox-Merx rule appears to be validated, within experimental error. On the other hand, the (shear) rate dependent steady shear viscosity data exhibit a slope smaller than the convective constraint release slope of -1 (for linear polymers) for the investigated range of rates. The broadness of the stress overshoot reflects the broad linear relaxation spectrum of the stars. The initial stress relaxation rate, reflecting the initial loss of entanglements due to the action of convective constraint release in steady shear flow, increases with Weissenberg number. More importantly, when compared against the relevant rates for comb polymers with relatively short arms, the latter are slower at larger Weissenberg numbers. At long times, the relaxation data are consistent with the linear viscoelastic data on these systems. © 2013 American Chemical Society.

  18. Curating viscoelastic properties of icosahedral viruses, virus-based nanomaterials, and protein cages.

    Science.gov (United States)

    Kant, Ravi; Rayaprolu, Vamseedhar; McDonald, Kaitlyn; Bothner, Brian

    2018-06-01

    The beauty, symmetry, and functionality of icosahedral virus capsids has attracted the attention of biologists, physicists, and mathematicians ever since they were first observed. Viruses and protein cages assemble into functional architectures in a range of sizes, shapes, and symmetries. To fulfill their biological roles, these structures must self-assemble, resist stress, and are often dynamic. The increasing use of icosahedral capsids and cages in materials science has driven the need to quantify them in terms of structural properties such as rigidity, stiffness, and viscoelasticity. In this study, we employed Quartz Crystal Microbalance with Dissipation technology (QCM-D) to characterize and compare the mechanical rigidity of different protein cages and viruses. We attempted to unveil the relationships between rigidity, radius, shell thickness, and triangulation number. We show that the rigidity and triangulation numbers are inversely related to each other and the comparison of rigidity and radius also follows the same trend. Our results suggest that subunit orientation, protein-protein interactions, and protein-nucleic acid interactions are important for the resistance to deformation of these complexes, however, the relationships are complex and need to be explored further. The QCM-D based viscoelastic measurements presented here help us elucidate these relationships and show the future prospect of this technique in the field of physical virology and nano-biotechnology.

  19. A mixed-effects model approach for the statistical analysis of vocal fold viscoelastic shear properties.

    Science.gov (United States)

    Xu, Chet C; Chan, Roger W; Sun, Han; Zhan, Xiaowei

    2017-11-01

    A mixed-effects model approach was introduced in this study for the statistical analysis of rheological data of vocal fold tissues, in order to account for the data correlation caused by multiple measurements of each tissue sample across the test frequency range. Such data correlation had often been overlooked in previous studies in the past decades. The viscoelastic shear properties of the vocal fold lamina propria of two commonly used laryngeal research animal species (i.e. rabbit, porcine) were measured by a linear, controlled-strain simple-shear rheometer. Along with published canine and human rheological data, the vocal fold viscoelastic shear moduli of these animal species were compared to those of human over a frequency range of 1-250Hz using the mixed-effects models. Our results indicated that tissues of the rabbit, canine and porcine vocal fold lamina propria were significantly stiffer and more viscous than those of human. Mixed-effects models were shown to be able to more accurately analyze rheological data generated from repeated measurements. Copyright © 2017 Elsevier Ltd. All rights reserved.

  20. Viscoelastic properties of bovine orbital connective tissue and fat: constitutive models.

    Science.gov (United States)

    Yoo, Lawrence; Gupta, Vijay; Lee, Choongyeop; Kavehpore, Pirouz; Demer, Joseph L

    2011-12-01

    Reported mechanical properties of orbital connective tissue and fat have been too sparse to model strain-stress relationships underlying biomechanical interactions in strabismus. We performed rheological tests to develop a multi-mode upper convected Maxwell (UCM) model of these tissues under shear loading. From 20 fresh bovine orbits, 30 samples of connective tissue were taken from rectus pulley regions and 30 samples of fatty tissues from the posterior orbit. Additional samples were defatted to determine connective tissue weight proportion, which was verified histologically. Mechanical testing in shear employed a triborheometer to perform: strain sweeps at 0.5-2.0 Hz; shear stress relaxation with 1% strain; viscometry at 0.01-0.5 s(-1) strain rate; and shear oscillation at 1% strain. Average connective tissue weight proportion was 98% for predominantly connective tissue and 76% for fatty tissue. Connective tissue specimens reached a long-term relaxation modulus of 668 Pa after 1,500 s, while corresponding values for fatty tissue specimens were 290 Pa and 1,100 s. Shear stress magnitude for connective tissue exceeded that of fatty tissue by five-fold. Based on these data, we developed a multi-mode UCM model with variable viscosities and time constants, and a damped hyperelastic response that accurately described measured properties of both connective and fatty tissues. Model parameters differed significantly between the two tissues. Viscoelastic properties of predominantly connective orbital tissues under shear loading differ markedly from properties of orbital fat, but both are accurately reflected using UCM models. These viscoelastic models will facilitate realistic global modeling of EOM behavior in binocular alignment and strabismus.

  1. Characterization of the elastic and viscoelastic properties of dentin by a nanoindentation creep test.

    Science.gov (United States)

    Chuang, Shu-Fen; Lin, Shih-Yun; Wei, Pal-Jen; Han, Chang-Fu; Lin, Jen-Fin; Chang, Hsien-Chang

    2015-07-16

    Dentin is the main supporting structure of teeth, but its mechanical properties may be adversely affected by pathological demineralization. The purposes of this study were to develop a quantitative approach to characterize the viscoelastic properties of dentin after de- and re-mineralization, and to examine the elastic properties using a nanoindentation creep test. Dentin specimens were prepared to receive both micro- and nano-indentation tests at wet and dry states. These tests were repeatedly performed after demineralization (1% citric acid for 3 days) and remineralization (artificial saliva immersion for 28 days). The nanoindentation test was executed in a creep mode, and the resulting displacement-time responses were disintegrated into primary (transient) and secondary (viscous) creep. The structural changes and mineral densities of dentin were also examined under SEM and microCT, respectively. The results showed that demineralization removed superficial minerals of dentin to the depth of 400 μm, and affected its micro- and nano-hardness, especially in the hydrate state. Remineralization only repaired the minerals at the surface layer, and partially recovered the nanohardness. Both the primary the secondary creep increased in the demineralized dentin, while the hydration further enhanced creep deformation of untreated and remineralized dentin. Remineralization reduced the primary creep of dentin, but did not effectively increase the viscosity. In conclusion, water plasticization increases the transient and viscous creep strains of demineralized dentin and reduces load sustainability. The nanoindentation creep test is capable of analyzing the elastic and viscoelastic properties of dentin, and reveals crucial information about creep responses. Copyright © 2015 Elsevier Ltd. All rights reserved.

  2. A constitutive model for developing blood clots with various compositions and their nonlinear viscoelastic behavior

    NARCIS (Netherlands)

    van Kempen, T. H. S.; Donders, W. P.; van de Vosse, F. N.; Peters, G. W. M.

    2016-01-01

    The mechanical properties determine to a large extent the functioning of a blood clot. These properties depend on the composition of the clot and have been related to many diseases. However, the various involved components and their complex interactions make it difficult at this stage to fully

  3. Influence of Nanodisperse Metal Fillers on the Viscoelastic Properties and Processes of Mechanical Relaxation of Polymer Systems

    Science.gov (United States)

    Kolupav, B. B.; Kolupaev, B. S.; Levchuk, V. V.; Maksimtsev, Yu. R.; Sidletskii, V. A.

    2017-05-01

    The results of research into the viscoelastic properties and processes of mechanical relaxation of polyvinylchloride (PVC) containing Cu nanoparticles obtained by means of electroerosion crushing and electrohydraulic destruction of agglomerates of disperse Cu in the presence of an ultrasonic field are presented. It is shown that, in the case of longitudinal shear deformation at a frequency of 0.4 × 106 s-1 over a wide range of temperatures and content of ingredients, viscoelastic phenomena depending on structural changes in the PVC system occur. An analysis of quantitative results of the elastic and viscoelastic deformation of a body is carried out taking into account the energy and entropy components of interaction of the polymer and filler at their interface.

  4. Viscoelastic nanoscale properties of cuticle contribute to the high-pass properties of spider vibration receptor (Cupiennius salei Keys).

    Science.gov (United States)

    McConney, Michael E; Schaber, Clemens F; Julian, Michael D; Barth, Friedrich G; Tsukruk, Vladimir V

    2007-12-22

    Atomic force microscopy (AFM) and surface force spectroscopy were applied in live spiders to their joint pad material located distal of the metatarsal lyriform organs, which are highly sensitive vibration sensors. The surface topography of the material is sufficiently smooth to probe the local nanomechanical properties with nanometre elastic deflections. Nanoscale loads were applied in the proximad direction on the distal joint region simulating the natural stimulus situation. The force curves obtained indicate the presence of a soft, liquid-like epicuticular layer (20-40 nm thick) above the pad material, which has much higher stiffness. The Young modulus of the pad material is close to 15 MPa at low frequencies, but increases rapidly with increasing frequencies approximately above 30 Hz to approximately 70 MPa at 112 Hz. The adhesive forces drop sharply by about 40% in the same frequency range. The strong frequency dependence of the elastic modulus indicates the viscoelastic nature of the pad material, its glass transition temperature being close to room temperature (25 +/- 2 degrees C) and, therefore, to its maximized energy absorption from low-frequency mechanical stimuli. These viscoelastic properties of the cuticular pad are suggested to be at least partly responsible for the high-pass characteristics of the vibration sensor's physiological properties demonstrated earlier.

  5. Studies of the viscoelastic properties of water confined between surfaces of specified chemical nature.

    Energy Technology Data Exchange (ETDEWEB)

    Houston, Jack E.; Grest, Gary Stephen; Moore, Nathan W.; Feibelman, Peter J.

    2010-09-01

    This report summarizes the work completed under the Laboratory Directed Research and Development (LDRD) project 10-0973 of the same title. Understanding the molecular origin of the no-slip boundary condition remains vitally important for understanding molecular transport in biological, environmental and energy-related processes, with broad technological implications. Moreover, the viscoelastic properties of fluids in nanoconfinement or near surfaces are not well-understood. We have critically reviewed progress in this area, evaluated key experimental and theoretical methods, and made unique and important discoveries addressing these and related scientific questions. Thematically, the discoveries include insight into the orientation of water molecules on metal surfaces, the premelting of ice, the nucleation of water and alcohol vapors between surface asperities and the lubricity of these molecules when confined inside nanopores, the influence of water nucleation on adhesion to salts and silicates, and the growth and superplasticity of NaCl nanowires.

  6. Regionally variant collagen alignment correlates with viscoelastic properties of the disc of the human temporomandibular joint.

    Science.gov (United States)

    Gutman, Shawn; Kim, Daniel; Tarafder, Solaiman; Velez, Sergio; Jeong, Julia; Lee, Chang H

    2018-02-01

    To determine the regionally variant quality of collagen alignment in human TMJ discs and its statistical correlation with viscoelastic properties. For quantitative analysis of the quality of collagen alignment, horizontal sections of human TMJ discs with Pricrosirius Red staining were imaged under circularly polarized microscopy. Mean angle and angular deviation of collagen fibers in each region were analyzed using a well-established automated image-processing for angular gradient. Instantaneous and relaxation moduli of each disc region were measured under stress-relaxation test both in tensile and compression. Then Spearman correlation analysis was performed between the angular deviation and the moduli. To understand the effect of glycosaminoglycans on the correlation, TMJ disc samples were treated by chondroitinase ABC (C-ABC). Our imaging processing analysis showed the region-variant direction of collagen alignment, consistently with previous findings. Interestingly, the quality of collagen alignment, not only the directions, was significantly different in between the regions. The angular deviation of fiber alignment in the anterior and intermediate regions were significantly smaller than the posterior region. Medial and lateral regions showed significantly bigger angular deviation than all the other regions. The regionally variant angular deviation values showed statistically significant correlation with the tensile instantaneous modulus and the relaxation modulus, partially dependent on C-ABC treatment. Our findings suggest the region-variant degree of collagen fiber alignment is likely attributed to the heterogeneous viscoelastic properties of TMJ disc that may have significant implications in development of regenerative therapy for TMJ disc. Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. Mathematical modelling of nonlinear thermal radiation effects on EMHD peristaltic pumping of viscoelastic dusty fluid through a porous medium duct

    Directory of Open Access Journals (Sweden)

    M.M. Bhatti

    2017-06-01

    Full Text Available Biologically-inspired propulsion systems are currently receiving significant interest in the aerospace sector. Since many spacecraft propulsion systems operate at high temperatures, thermal radiation is important as a mode of heat transfer. Motivated by these developments, in the present article, the influence of nonlinear thermal radiation (via the Rosseland diffusion flux model has been studied on the laminar, incompressible, dissipative EMHD (Electro-magneto-hydrodynamic peristaltic propulsive flow of a non-Newtonian (Jefferys viscoelastic dusty fluid containing solid particles through a porous planar channel. The fluid is electrically-conducting and a constant static magnetic field is applied transverse to the flow direction (channel walls. Slip effects are also included. Magnetic induction effects are neglected. The mathematical formulation is based on continuity, momentum and energy equations with appropriate boundary conditions, which are simplified by neglecting the inertial forces and taking the long wavelength and lubrication approximations. The boundary value problem is then rendered non-dimensional with appropriate variables and the resulting system of reduced ordinary differential equations is solved analytically. The impact of various emerging parameters dictating the non-Newtonian propulsive flow i.e. Prandtl number, radiation parameter, Hartmann number, permeability parameter, Eckert number, particle volume fraction, electric field and slip parameter are depicted graphically. Increasing particle volume fraction is observed to suppress temperature magnitudes. Furthermore the computations demonstrate that an increase in particle volume fraction reduces the pumping rate in retrograde pumping region whereas it causes the opposite effect in the co-pumping region. The trapping mechanism is also visualized with the aid of streamline contour plots. Increasing thermal radiation elevates temperatures. Increasing Hartmann (magnetic body

  8. Correlation between the viscoelastic properties of the gel layer of swollen HPMC matrix tablets and their in vitro drug release.

    Science.gov (United States)

    Hamed, Rania; Al Baraghthi, Tamadur; Sunoqrot, Suhair

    2016-11-21

    Drug release from hydroxypropyl methylcellulose (HPMC) hydrophilic matrix tablets is controlled by drug diffusion through the gel layer of the matrix-forming polymer upon hydration, matrix erosion or combination of diffusion and erosion mechanisms. In this study, the relationship between viscoelastic properties of the gel layer of swollen intact matrix tablets and drug release was investigated. Two sets of quetiapine fumarate (QF) matrix tablets were prepared using the high viscosity grade HPMC K4M at low (70 mg/tablet) and high (170 mg/tablet) polymer concentrations. Viscoelastic studies using a controlled stress rheometer were performed on swollen matrices following hydration in the dissolution medium for predetermined time intervals. The gel layer of swollen tablets exhibited predominantly elastic behavior. Results from the in vitro release study showed that drug release was strongly influenced by the viscoelastic properties of the gel layer of K4M tablets, which was further corroborated by results from water uptake studies conducted on intact tablets. The results provide evidence that the viscoelastic properties of the gel layer can be exploited to guide the selection of an appropriate matrix-forming polymer, to better understand the rate of drug release from matrix tablets in vitro and to develop hydrophilic controlled-release formulations.

  9. Thermomechanical earthquake cycle simulations with rate-and-state friction and nonlinear viscoelasticity

    Science.gov (United States)

    Allison, K. L.; Dunham, E. M.

    2017-12-01

    We simulate earthquake cycles on a 2D strike-slip fault, modeling both rate-and-state fault friction and an off-fault nonlinear power-law rheology. The power-law rheology involves an effective viscosity that is a function of temperature and stress, and therefore varies both spatially and temporally. All phases of the earthquake cycle are simulated, allowing the model to spontaneously generate earthquakes, and to capture frictional afterslip and postseismic and interseismic viscous flow. We investigate the interaction between fault slip and bulk viscous flow, using experimentally-based flow laws for quartz-diorite in the crust and olivine in the mantle, representative of the Mojave Desert region in Southern California. We first consider a suite of three linear geotherms which are constant in time, with dT/dz = 20, 25, and 30 K/km. Though the simulations produce very different deformation styles in the lower crust, ranging from significant interseismc fault creep to purely bulk viscous flow, they have almost identical earthquake recurrence interval, nucleation depth, and down-dip coseismic slip limit. This indicates that bulk viscous flow and interseismic fault creep load the brittle crust similarly. The simulations also predict unrealistically high stresses in the upper crust, resulting from the fact that the lower crust and upper mantle are relatively weak far from the fault, and from the relatively small role that basal tractions on the base of the crust play in the force balance of the lithosphere. We also find that for the warmest model, the effective viscosity varies by an order of magnitude in the interseismic period, whereas for the cooler models it remains roughly constant. Because the rheology is highly sensitive to changes in temperature, in addition to the simulations with constant temperature we also consider the effect of heat generation. We capture both frictional heat generation and off-fault viscous shear heating, allowing these in turn to alter the

  10. Unequal diffusivities case of homogeneous–heterogeneous reactions within viscoelastic fluid flow in the presence of induced magnetic-field and nonlinear thermal radiation

    Directory of Open Access Journals (Sweden)

    I.L. Animasaun

    2016-06-01

    Full Text Available This article presents the effects of nonlinear thermal radiation and induced magnetic field on viscoelastic fluid flow toward a stagnation point. It is assumed that there exists a kind of chemical reaction between chemical species A and B. The diffusion coefficients of the two chemical species in the viscoelastic fluid flow are unequal. Since chemical species B is a catalyst at the horizontal surface, hence homogeneous and heterogeneous schemes are of the isothermal cubic autocatalytic reaction and first order reaction respectively. The transformed governing equations are solved numerically using Runge–Kutta integration scheme along with Newton’s method. Good agreement is obtained between present and published numerical results for a limiting case. The influence of some pertinent parameters on skin friction coefficient, local heat transfer rate, together with velocity, induced magnetic field, temperature, and concentration profiles is illustrated graphically and discussed. Based on all of these assumptions, results indicate that the effects of induced magnetic and viscoelastic parameters on velocity, transverse velocity and velocity of induced magnetic field are almost the same but opposite in nature. The strength of heterogeneous reaction parameter is very helpful to reduce the concentration of bulk fluid and increase the concentration of catalyst at the surface.

  11. Effect of Solar Radiation on Viscoelastic Properties of Bovine Leather: Temperature and Frequency Scans

    Science.gov (United States)

    Nalyanya, Kallen Mulilo; Rop, Ronald K.; Onyuka, Arthur S.

    2017-04-01

    This work presents both analytical and experimental results of the effect of unfiltered natural solar radiation on the thermal and dynamic mechanical properties of Boran bovine leather at both pickling and tanning stages of preparation. Samples cut from both pickled and tanned pieces of leather of appropriate dimensions were exposed to unfiltered natural solar radiation for time intervals ranging from 0 h (non-irradiated) to 24 h. The temperature of the dynamic mechanical analyzer was equilibrated at 30°C and increased to 240°C at a heating rate of 5°C \\cdot Min^{-1}, while its oscillation frequency varied from 0.1 Hz to 100 Hz. With the help of thermal analysis (TA) control software which analyzes and generates parameter means/averages at temperature/frequency range, the graphs were created by Microsoft Excel 2013 from the means. The viscoelastic properties showed linear frequency dependence within 0.1 Hz to 30 Hz followed by negligible frequency dependence above 30 Hz. Storage modulus (E') and shear stress (σ ) increased with frequency, while loss modulus (E''), complex viscosity (η ^{*}) and dynamic shear viscosity (η) decreased linearly with frequency. The effect of solar radiation was evident as the properties increased initially from 0 h to 6 h of irradiation followed by a steady decline to a minimum at 18 h before a drastic increase to a maximum at 24 h. Hence, tanning industry can consider the time duration of 24 h for sun-drying of leather to enhance the mechanical properties and hence the quality of the leather. At frequencies higher than 30 Hz, the dynamic mechanical properties are independent of the frequency. The frequency of 30 Hz was observed to be a critical value in the behavior in the mechanical properties of bovine hide.

  12. How preservation time changes the linear viscoelastic properties of porcine liver.

    Science.gov (United States)

    Wex, C; Stoll, A; Fröhlich, M; Arndt, S; Lippert, H

    2013-01-01

    The preservation time of a liver graft is one of the crucial factors for the success of a liver transplantation. Grafts are kept in a preservation solution to delay cell destruction and cellular edema and to maximize organ function after transplantation. However, longer preservation times are not always avoidable. In this paper we focus on the mechanical changes of porcine liver with increasing preservation time, in order to establish an indicator for the quality of a liver graft dependent on preservation time. A time interval of 26 h was covered and the rheological properties of liver tissue studied using a stress-controlled rheometer. For samples of 1 h preservation time 0.8% strain was found as the limit of linear viscoelasticity. With increasing preservation time a decrease in the complex shear modulus as an indicator for stiffness was observed for the frequency range from 0.1 to 10 Hz. A simple fractional derivative representation of the Kelvin Voigt model was applied to gain further information about the changes of the mechanical properties of liver with increasing preservation time. Within the small shear rate interval of 0.0001-0.01 s⁻¹ the liver showed Newtonian-like flow behavior.

  13. Effects of Wheat Flour Dough’s Viscoelastic Level by Adding Glucose Oxidase on its Dynamic Shear Properties whatever the Strain Modes

    Directory of Open Access Journals (Sweden)

    Jean Didier Koffi Kouassi

    2014-05-01

    Full Text Available The objective of this work was to study the effects of wheat flour dough’s viscoelastic level by adding glucose oxidase (Gox on its rheological properties at dynamic shear strain mode to predict the final product quality. Dough does display a linear viscoelastic domain. Glucose oxidase (Gox was added to dough in order to enhance its viscoelasticity and to take into account the possible effects of this viscoelasticity on the results. Whatever the types of dough strain used G’ increased, tan δ decreased and led to less sticky dough. Wheat flour dough, an increase in G’ with extension may be associated to a strain-hardening phenomenon but the role of dough viscoelasticity is discussed.

  14. Viscoelastic properties of orthodontic adhesives used for lingual fixed retainer bonding.

    Science.gov (United States)

    Papadogiannis, D; Iliadi, A; Bradley, T G; Silikas, N; Eliades, G; Eliades, T

    2017-01-01

    To evaluate the viscoelastic properties of two experimental BPA-free and one BisGMA-based orthodontic resin composite adhesives for bonding fixed retainers. A commercially available BisGMA-based (TXA: Transbond LR) and two bisphenol A-free experimental adhesives (EXA and EXB) were included in the study. The viscoelastic behavior of the adhesives was evaluated under static and dynamic conditions at dry and wet states and at various temperatures (21, 37, 50°C). The parameters determined were shear modulus (G), Young's modulus (E) under static testing and storage modulus (G 1 ), loss tangent (tanδ) and dynamic viscosity (n*) under dynamic testing. Statistical analysis was performed by 2-way ANOVA and Bonferroni post-hoc tests (α=0.05). For static testing, a significant difference was found within material and storage condition variables and a significant interaction between the two independent variables (p<0.001 for G and E). EXA demonstrated the highest G and E values at 21°C/dry group. Dry specimens showed the highest G and E values, but with no significant difference from 21°C/wet specimens, except EXA in G. Wet storage at higher temperatures (37°C and 50°C) adversely affected all the materials to a degree ranging from 40 to 60% (p<0.001). For dynamic testing, a significant difference was also found in material and testing condition groups, with a significant interaction between the two independent variables (p<0.001 for G 1 and n*, p<0.01 for tanδ). Reduction in G 1 , and n* values, and increase in tanδ values were encountered at increased water temperatures. The apparent detrimental effect of high temperature on the reduction of properties of adhesives may contribute to the loss of stiffness of the fixed retainer configuration under ordinary clinical conditions with unfavorable effects on tooth position and stability of the orthodontic treatment result. Copyright © 2016 The Academy of Dental Materials. All rights reserved.

  15. Effective properties of linear viscoelastic heterogeneous media: Internal variables formulation and extension to ageing behaviours

    International Nuclear Information System (INIS)

    Ricaud, J.M.; Masson, R.; Masson, R.

    2009-01-01

    The Laplace-Carson transform classically used for homogenization of linear viscoelastic heterogeneous media yields integral formulations of effective behaviours. These are far less convenient than internal variables formulations with respect to computational aspects as well as to theoretical extensions to closely related problems such as ageing viscoelasticity. Noticing that the collocation method is usually adopted to invert the Laplace-Carson transforms, we first remark that this approximation is equivalent to an internal variables formulation which is exact in some specific situations. This result is illustrated for a two-phase composite with phases obeying a compressible Maxwellian behaviour. Next, an incremental formulation allows to extend at each time step the previous general framework to ageing viscoelasticity. Finally, with the help of a creep test of a porous viscoelastic matrix reinforced with elastic inclusions, it is shown that the method yields accurate predictions (comparing to reference results provided by periodic cell finite element computations). (authors)

  16. Postseismic Deformations of the Aceh, Nias and Benkulu Earthquakes and the Viscoelastic Properties of the Mantle

    Science.gov (United States)

    Fleitout, L.; Garaud, J.; Cailletaud, G.; Vigny, C.; Simons, W. J.; Ambrosius, B. A.; Trisirisatayawong, I.; Satirapod, C.; Geotecdi Song

    2011-12-01

    The giant seism of Aceh (december 2004),followed by the Nias and Bengkulu earthquakes, broke a large portion of the boundary between the Indian ocean and the Sunda block. For the first time in history, the deformations associated with a very large earthquake can be followed by GPS, in particular by the SEAMERGE (far-field) and SUGAR (near-field) GPS networks. A 3D finite element code (Zebulon-Zset) is used to model both the cosismic and the postseismic deformations. The modeled zone is a large portion of spherical shell around Sumatra extanding over more than 60 degrees in latitude and longitude and from the Earth's surface to the core-mantle boundary. The mesh is refined close to the subduction zone. First, the inverted cosismic displacements on the subduction plane are inverted for and provide a very good fit to the GPS data for the three seisms. The observed postseismic displacements, non-dimensionalized by the cosismic displacements, present three very different patterns as function of time: For GPS stations in the far-field, the total horizontal post-seismic displacement after 4 years is as large as the cosismic displacement. The velocities vary slowly over 4 years. A large subsidence affects Thailand and Malaysia. In the near-field, the postseismic displacement reaches only some 15% of the cosismic displacement and it levels off after 2 years. In the middle-field (south-west coast of Sumatra), the postseismic displacement also levels-off with time but more slowly and it reaches more than 30% of the cosismic displacement after four years. In order to fit these three distinct displacement patterns, we need to invoke both viscoelastic deformation in the asthenosphere and a low-viscosity wedge: Neither the vertical subsidence nor the amplitude of the far-field horizontal velocities could be explained by postseismic sliding on the subduction interface. The low viscosity wedge permits to explain the large middle-field velocities. The viscoelastic properties of the

  17. The effect of addition of selected carrageenans on viscoelastic properties of model processed cheese spreads

    Directory of Open Access Journals (Sweden)

    Michaela Černíková

    2007-01-01

    Full Text Available The effect of 0.25% w/w κ-carrageenan and ι‑carrageenan on viscoelastic properties of processed cheese were studied using model samples containing 40% w/w dry matter and 45 and 50% w/w fat in dry matter. Experimental samples of processed cheese were evaluated after 14 days of storage at the temperature of 6 ± 2 °C. Basic parameters of processed cheese samples under study (i.e. their dry matter content and pH were not different (P ≥ 0.05. There were no statistically significant differences in values of storage modulus G´ [Pa], loss modulus G'' [Pa] and tangent of phase shift angle tan δ [-] for the reference frequency of 1 Hz between processed cheese with κ‑carrageenan applied in the form of powder and in the form of aqueous dispersion (P ≥ 0.05. The addition of 0.25% w/w κ‑carrageenan and ι‑carrageenan (in the powder form resulted in an increase in storage (G´ and loss (G'' moduli and a decrease in values of tan δ (P < 0.05. As compared with control (i.e. without added carrageenans, samples of processed cheese became firmer. Iota-carrageenan added in the powder form in concentration of 0.25% w/w showed a more intensive effect on the increase in firmness of processed cheese under study than κ‑carrageenan (P < 0.05.

  18. Viscoelastic and Functional Properties of Cod-Bone Gelatin in the Presence of Xylitol and Stevioside

    Directory of Open Access Journals (Sweden)

    Linyu Nian

    2018-05-01

    Full Text Available The physical, rheological, structural and functional properties of cod bone gelatin (CBG with various concentrations (0, 2, 4, 6, 10, and 15% of low-calorie sweeteners [xylitol (X and stevioside (S] to form gels were investigated. The gel strength of CBGX increased with increased xylitol due presumably to hydrogen bonds between xylitol and gelatin, but with CBGS the highest gel strength occurred when S concentration was 4%. Viscosity of CBGS samples were higher than CBGX due to S's high molecular mass. The viscoelasticity (G′ and G′′, foaming capacity and fat binding capacity of CBGX were higher while foam stability was lower. The emulsion activity and emulsion stability of CBGX were a little lower than CBGS at the same concentration. The structure of X is linear making it easier to form a dense three-dimensional network structure, while the complex cyclic structure of S had more difficulty forming a network structure with cod bone gelatin. Therefore, X may be a better choice for sweetening gelatin gels.

  19. Viscoelastic characteristics and phytochemical properties of purple-rice drinks following ultrahigh pressure and pasteurization

    Science.gov (United States)

    Worametrachanon, Srivilai; Apichartsrangkoon, Arunee

    2014-10-01

    This study investigated how pressure (500, 600 MPa/20 min) altered the viscoelastic characteristics and phytochemical properties of germinated and non-germinated purple-rice drinks in comparison with pasteurization. Accordingly, color parameters, storage and loss moduli, anthocyanin content, γ-oryzanol, γ-aminobutyric acid (GABA), total phenolic compounds and 2,2-diphenyl-1-picrylthydrazyl (DPPH) capacity of the processed drinks were determined. The finding showed that germinated and pressurized rice drink had lower Browning Index than the non-germinated and pasteurized rice drink. The plots of storage and loss moduli for processed rice drinks indicated that time of pressurization had greater impact on gel structural modification than the level of pressure used. The phytochemicals, including total phenolics, and DPPH capacity in pressurized rice drinks retained higher quantity than those in pasteurized drink, despite less treatment effects on anthocyanin. On the contrary, both γ-oryzanol and GABA were found in high amounts in germinated rice drink with little variation among processing effects.

  20. Viscoelastic Properties of Hyaluronan in Physiological Conditions [version 1; referees: 2 approved

    Directory of Open Access Journals (Sweden)

    Mary K. Cowman

    2015-08-01

    Full Text Available Hyaluronan (HA is a high molecular weight glycosaminoglycan of the extracellular matrix (ECM, which is particularly abundant in soft connective tissues. Solutions of HA can be highly viscous with non-Newtonian flow properties. These properties affect the movement of HA-containing fluid layers within and underlying the deep fascia. Changes in the concentration, molecular weight, or even covalent modification of HA in inflammatory conditions, as well as changes in binding interactions with other macromolecules, can have dramatic effects on the sliding movement of fascia. The high molecular weight and the semi-flexible chain of HA are key factors leading to the high viscosity of dilute solutions, and real HA solutions show additional nonideality and greatly increased viscosity due to mutual macromolecular crowding. The shear rate dependence of the viscosity, and the viscoelasticity of HA solutions, depend on the relaxation time of the molecule, which in turn depends on the HA concentration and molecular weight. Temperature can also have an effect on these properties. High viscosity can additionally affect the lubricating function of HA solutions. Immobility can increase the concentration of HA, increase the viscosity, and reduce lubrication and gliding of the layers of connective tissue and muscle. Over time, these changes can alter both muscle structure and function. Inflammation can further increase the viscosity of HA-containing fluids if the HA is modified via covalent attachment of heavy chains derived from Inter-α-Inhibitor. Hyaluronidase hydrolyzes HA, thus reducing its molecular weight, lowering the viscosity of the extracellular matrix fluid and making outflow easier. It can also disrupt any aggregates or gel-like structures that result from HA being modified. Hyaluronidase is used medically primarily as a dispersion agent, but may also be useful in conditions where altered viscosity of the fascia is desired, such as in the treatment of

  1. Effect of annealing conditions on the molecular properties and wetting of viscoelastic bitumen substrates by liquids

    Directory of Open Access Journals (Sweden)

    Salomé dos Santos

    2017-01-01

    Full Text Available Typically, in the production of asphalt concrete, bitumen and mineral aggregates are heated and mixed at temperatures above 100 °C. After the mixing process bitumen ideally coats the mineral aggregates and remains in the form of thin films. Because bitumen is highly temperature sensitive, the study of its properties in terms of chemistry, microstructure and rheology as a function of different annealing conditions is very relevant. The resultant molecular properties have a direct correlation to bitumen macroscopic response to liquids such as water, which is of extreme relevance to the understanding of the detrimental effect of water on asphalt pavements. The wetting characteristics play a crucial role on the extension of detachment of bitumen from the mineral aggregates when asphalt is exposed to wet conditions. Therefore, in this work, the effect of the annealing temperature and cooling history on the chemistry, microstructure and wetting of bitumen films was studied. Crystalline microstructures were identified in bulk and on the surface of the bitumen films. Larger crystals presenting higher crystallinity degree were identified when the annealed bitumen films were cooled slowly. Moreover, higher annealing temperatures increased the oxidation level. The change of the rheological properties due to the alterations of the annealing conditions produced changes in the wetting characteristics. For instance, the advancing motion of a liquid drop on the viscoelastic bitumen substrate presented an intermittent behaviour due to the deformation of bitumen at the liquid-bitumen-air contact line. Consequently, changes in the contact angles were also observed. Keywords: Bitumen, Crystallization, Oxidation, Advancing contact angle, Wetting

  2. Mixed-mode fatigue fracture of adhesive joints in harsh environments and nonlinear viscoelastic modeling of the adhesive

    Science.gov (United States)

    Arzoumanidis, Alexis Gerasimos

    A four point bend, mixed-mode, reinforced, cracked lap shear specimen experimentally simulated adhesive joints between load bearing composite parts in automotive components. The experiments accounted for fatigue, solvent and temperature effects on a swirled glass fiber composite adherend/urethane adhesive system. Crack length measurements based on compliance facilitated determination of da/dN curves. A digital image processing technique was also utilized to monitor crack growth from in situ images of the side of the specimen. Linear elastic fracture mechanics and finite elements were used to determine energy release rate and mode-mix as a function of crack length for this specimen. Experiments were conducted in air and in a salt water bath at 10, 26 and 90°C. Joints tested in the solvent were fully saturated. In air, both increasing and decreasing temperature relative to 26°C accelerated crack growth rates. In salt water, crack growth rates increased with increasing temperature. Threshold energy release rate is shown to be the most appropriate design criteria for joints of this system. In addition, path of the crack is discussed and fracture surfaces are examined on three length scales. Three linear viscoelastic properties were measured for the neat urethane adhesive. Dynamic tensile compliance (D*) was found using a novel extensometer and results were considerably more accurate and precise than standard DMTA testing. Dynamic shear compliance (J*) was determined using an Arcan specimen. Dynamic Poisson's ratio (nu*) was extracted from strain gage data analyzed to include gage reinforcement. Experiments spanned three frequency decades and isothermal data was shifted by time-temperature superposition to create master curves spanning thirty decades. Master curves were fit to time domain Prony series. Shear compliance inferred from D* and nu* compared well with measured J*, forming a basis for finding the complete time dependent material property matrix for this

  3. Non linear viscoelastic models

    DEFF Research Database (Denmark)

    Agerkvist, Finn T.

    2011-01-01

    Viscoelastic eects are often present in loudspeaker suspensions, this can be seen in the displacement transfer function which often shows a frequency dependent value below the resonance frequency. In this paper nonlinear versions of the standard linear solid model (SLS) are investigated....... The simulations show that the nonlinear version of the Maxwell SLS model can result in a time dependent small signal stiness while the Kelvin Voight version does not....

  4. Effect of ionizing radiation on visco-elastic properties of polymethyl-methacrylate and poly-4-methylpentene-1

    International Nuclear Information System (INIS)

    Perepechko, I.I.; Mar'yasin, B.Ya.

    1978-01-01

    The effect of γ radiation on visco-elastic properties of polymethylmethacrylate (PMMA) and poly-4-methylpentene-1 (P4MPI) has been investigated by the method of the forced resonance oscillations of a cantilevered specimen. It has been shown, that the variation of the dynamic elasticity modulus of amorphous polymer when the irradiation dose increases, considerable depends on the polymer physical state during the measurement. The irradiated polymer is a binary mixture of radiolysis low-molecular products and polymer itself. The value of elasticity modulus in such a mixture is defined by the modules of different components. More complex than in PMMA in the effect of γ-radiation upon the P4MPI visco-elastic behaviour. During the P4MPI irradiation, the rebuilding of polymer supermolecular structure takes place, which results in the variation of the dynamic elasticity modulus values and in the intensity of peaks of mechanical losses

  5. Lyotropic chromonic liquid crystals: From viscoelastic properties to living liquid crystals

    Science.gov (United States)

    Zhou, Shuang

    Lyotropic chromonic liquid crystal (LCLC) represents a broad range of molecules, from organic dyes and drugs to DNA, that self-assemble into linear aggregates in water through face-to-face stacking. These linear aggregates of high aspect ratio are capable of orientational order, forming, for example nematic phase. Since the microscopic properties (such as length) of the chromonic aggregates are results of subtle balance between energy and entropy, the macroscopic viscoelastic properties of the nematic media are sensitive to change of external factors. In the first part of this thesis, by using dynamic light scattering and magnetic Frederiks transition techniques, we study the Frank elastic moduli and viscosity coefficients of LCLC disodium cromoglycate (DSCG) and sunset yellow (SSY) as functions of concentration c , temperature T and ionic contents. The elastic moduli of splay (K1) and bend (K3) are in the order of 10pN, about 10 times larger than the twist modulus (K2). The splay modulus K1 and the ratio K1/K3 both increase substantially as T decreases or c increases, which we attribute to the elongation of linear aggregates at lower T or higher c . The bend viscosity is comparable to that of thermotropic liquid crystals, while the splay and twist viscosities are several orders of magnitude larger, changing exponentially with T . Additional ionic additives into the system influence the viscoelastic properties of these systems in a dramatic and versatile way. For example, monovalent salt NaCl decreases bend modulus K3 and increases twist viscosity, while an elevated pH decreases all the parameters. We attribute these features to the ion-induced changes in length and flexibility of building units of LCLC, the chromonic aggregates, a property not found in conventional thermotropic and lyotropic liquid crystals form by covalently bound units of fixed length. The second part of the thesis studies a new active bio-mechanical hybrid system called living liquid crystal

  6. Viscoelastic property tuning for reducing noise radiated by switched-reluctance machines

    Science.gov (United States)

    Millithaler, Pierre; Dupont, Jean-Baptiste; Ouisse, Morvan; Sadoulet-Reboul, Émeline; Bouhaddi, Noureddine

    2017-10-01

    Switched-reluctance motors (SRM) present major acoustic drawbacks that hinder their use for electric vehicles in spite of widely-acknowledged robustness and low manufacturing costs. Unlike other types of electric machines, a SRM stator is completely encapsulated/potted with a viscoelastic resin. By taking advantage of the high damping capacity that a viscoelastic material has in certain temperature and frequency ranges, this article proposes a tuning methodology for reducing the noise emitted by a SRM in operation. After introducing the aspects the tuning process will focus on, the article details a concrete application consisting in computing representative electromagnetic excitations and then the structural response of the stator including equivalent radiated power levels. An optimised viscoelastic material is determined, with which the peak radiated levels are reduced up to 10 dB in comparison to the initial state. This methodology is implementable for concrete industrial applications as it only relies on common commercial finite-element solvers.

  7. Application of Linear Viscoelastic Properties in Semianalytical Finite Element Method with Recursive Time Integration to Analyze Asphalt Pavement Structure

    Directory of Open Access Journals (Sweden)

    Pengfei Liu

    2018-01-01

    Full Text Available Traditionally, asphalt pavements are considered as linear elastic materials in finite element (FE method to save computational time for engineering design. However, asphalt mixture exhibits linear viscoelasticity at small strain and low temperature. Therefore, the results derived from the elastic analysis will inevitably lead to discrepancies from reality. Currently, several FE programs have already adopted viscoelasticity, but the high hardware demands and long execution times render them suitable primarily for research purposes. Semianalytical finite element method (SAFEM was proposed to solve the abovementioned problem. The SAFEM is a three-dimensional FE algorithm that only requires a two-dimensional mesh by incorporating the Fourier series in the third dimension, which can significantly reduce the computational time. This paper describes the development of SAFEM to capture the viscoelastic property of asphalt pavements by using a recursive formulation. The formulation is verified by comparison with the commercial FE software ABAQUS. An application example is presented for simulations of creep deformation of the asphalt pavement. The investigation shows that the SAFEM is an efficient tool for pavement engineers to fast and reliably predict asphalt pavement responses; furthermore, the SAFEM provides a flexible, robust platform for the future development in the numerical simulation of asphalt pavements.

  8. Order, viscoelastic, and dielectric properties of symmetric and asymmetric alkyl[1]benzothieno[3,2-b][1]benzothiophenes.

    Science.gov (United States)

    Grigoriadis, Christos; Niebel, Claude; Ruzié, Christian; Geerts, Yves H; Floudas, George

    2014-02-06

    The morphology, the viscoelastic, the dielectric properties and the dynamics of phase transformation are studied in symmetrically and asymmetrically substituted alkyl[1]benzothieno[3,2-b][1]benzothiophenes (C8-BTBT) by X-ray scattering, rheology, and dielectric spectroscopy. The interlayer spacing reflects the molecular and supramolecular ordering, respectively, in the symmetrically and asymmetrically substituted BTBTs. In the asymmetric BTBT, the core layer is double in size with a broader network of intermolecular interactions though the increased S-S contacts that is prerequisite for the development of high performance OFET devices. Two crystal states with elastic and viscoelastic responses were identified in the symmetric compound. In contrast, the SmA phase in the asymmetric compound is a viscoelastic solid. A path-dependent dielectric environment with a switchable dielectric permittivity was found in both compounds by cooling below 0 °C with possible implications to charge transport. The kinetics of phase transformation to the crystalline and SmA phases revealed a nucleation and growth mechanism with rates dominated by the low activation barriers.

  9. Hydrophilicity, Viscoelastic, and Physicochemical Properties Variations in Dental Bone Grafting Substitutes.

    Science.gov (United States)

    Trajkovski, Branko; Jaunich, Matthias; Müller, Wolf-Dieter; Beuer, Florian; Zafiropoulos, Gregory-George; Houshmand, Alireza

    2018-01-30

    The indication-oriented Dental Bone Graft Substitutes (DBGS) selection, the correct bone defects classification, and appropriate treatment planning are very crucial for obtaining successful clinical results. However, hydrophilic, viscoelastic, and physicochemical properties' influence on the DBGS regenerative potential has poorly been studied. For that reason, we investigated the dimensional changes and molecular mobility by Dynamic Mechanical Analysis (DMA) of xenograft (cerabone ® ), synthetic (maxresorb ® ), and allograft (maxgraft ® , Puros ® ) blocks in a wet and dry state. While no significant differences could be seen in dry state, cerabone ® and maxresorb ® blocks showed a slight height decrease in wet state, whereas both maxgraft ® and Puros ® had an almost identical height increase. In addition, cerabone ® and maxresorb ® blocks remained highly rigid and their damping behaviour was not influenced by the water. On the other hand, both maxgraft ® and Puros ® had a strong increase in their molecular mobility with different damping behaviour profiles during the wet state. A high-speed microscopical imaging system was used to analyze the hydrophilicity in several naturally derived (cerabone ® , Bio-Oss ® , NuOss ® , SIC ® nature graft) and synthetic DBGS granules (maxresorb ® , BoneCeramic ® , NanoBone ® , Ceros ® ). The highest level of hydrophilicity was detected in cerabone ® and maxresorb ® , while Bio-Oss ® and BoneCeramic ® had the lowest level of hydrophilicity among both naturally derived and synthetic DBGS groups. Deviations among the DBGS were also addressed via physicochemical differences recorded by Micro Computed Tomography, Scanning Electron Microscopy, Fourier Transform Infrared Spectroscopy, X-ray powder Diffractometry, and Thermogravimetric Analysis. Such DBGS variations could influence the volume stability at the grafting site, handling as well as the speed of vascularization and bone regeneration. Therefore, this

  10. SYNTHESIS OF VISCOELASTIC MATERIAL MODELS (SCHEMES

    Directory of Open Access Journals (Sweden)

    V. Bogomolov

    2014-10-01

    Full Text Available The principles of structural viscoelastic schemes construction for materials with linear viscoelastic properties in accordance with the given experimental data on creep tests are analyzed. It is shown that there can be only four types of materials with linear visco-elastic properties.

  11. Asphalt Pavement Aging and Temperature Dependent Properties Using Functionally Graded Viscoelastic Model

    Science.gov (United States)

    Dave, Eshan V.

    2009-01-01

    Asphalt concrete pavements are inherently graded viscoelastic structures. Oxidative aging of asphalt binder and temperature cycling due to climatic conditions being the major cause of non-homogeneity. Current pavement analysis and simulation procedures dwell on the use of layered approach to account for these non-homogeneities. The conventional…

  12. Properties of Love waves in a piezoelectric layered structure with a viscoelastic guiding layer

    International Nuclear Information System (INIS)

    Liu, Jiansheng; Wang, Lijun; Lu, Yanyan; He, Shitang

    2013-01-01

    A theoretical method is developed for analyzing Love waves in a structure with a viscoelastic guiding layer bounded on a piezoelectric substrate. The dispersion equation previously derived for piezoelectric Love waves propagating in the layered structure with an elastic layer is adopted for analyzing a structure with a viscoelastic layer. A Maxwell–Weichert model is introduced to describe the shear stiffness of a polymeric material. Newton’s method is employed for the numerical calculation. The dispersion equation for piezoelectric–elastic Love waves is proved suitable for solving a structure with a viscoelastic layer on a piezoelectric substrate. The theoretical results indicate that the propagation velocity of the Love wave is mainly decided by the shear stiffness of the guiding layer, whereas the propagation loss is approximately proportional to its viscosity. A detailed experimental study was conducted on a Love wave delay line fabricated on an ST-90° X quartz substrate and overlaid with various thicknesses of SU-8 guiding layers. A tail-raising caused by the viscosity of the guiding layer existed in both the calculated and the measured propagation velocities. The calculated insertion loss of the Love wave delay lines was in good agreement with the measured results. The method and the results presented in this paper are beneficial to the design of Love wave sensors with a viscoelastic guiding layer. (paper)

  13. Extensional rheometer based on viscoelastic catastrophes outline

    DEFF Research Database (Denmark)

    2014-01-01

    The present invention relates to a method and a device for determining viscoelastic properties of a fluid. The invention resides inter alia in the generation of viscoelastic catastrophes in confined systems for use in the context of extensional rheology. The viscoelastic catastrophe is according ...... to the invention generated in a bistable fluid system, and the flow conditions for which the catastrophe occurs can be used as a fingerprint of the fluid's viscoelastic properties in extensional flow....

  14. Linear and nonlinear properties of segmented waveguides

    International Nuclear Information System (INIS)

    Katz, M.

    1998-07-01

    This dissertation deals with Periodically Segmented Waveguides (PSW), which are applied on KTiOP0 4 (KTP) crystals, by chemical ion-exchange process. In these waveguides, the crystal polarity and refractive index are periodically modulated to obtain Quasi Phase Matching (QPM) between the fundamental and second-harmonic waves. PSW is a relatively new optical device which exhibits unique optical properties in comparison with a continuous waveguide. The possibility of utilizing the KTP-PSW as a compact, cw, blue-violet, source by doubling infra-red light, is the main motivation for studying the optical properties of KTP segmented waveguides. Nevertheless, much attention in this work is also given to the study of linear optical properties of KTP-PSW, most of which, to my best knowledge, has not been studied yet. Controlling and understanding the linear optical properties of KTP-PSW, are required, for applying the PSW as an optical device by its own, and for control and characterization of the non-linear optical properties of the waveguide. In this work the dependence of the linear optical properties of KTP-PSW on geometrical parameters (period size, duty cycle and waveguide width) were studied. The experimental measured parameters include the PSW near field and the Bragg reflections, which appear due lo the grating structure of the waveguide. The possibility of controlling the wavelength and intensity, of the segmented waveguide Bragg reflections of regular period and super-period, is shown theoretically and experimentally. An unexpected dependence was found, by the experimental measurement, between the index profile and the ion-exchanged segment area,. The segmented waveguide dispersion curve, n eff (λ) in the infra-red region was found, A main part of the research work is dedicated to the study of nonlinear characteristics of PSW. The different factors, which effect the Second Harmonic Generation (SHG), are measured experimentally and analyzed. The experimental

  15. Nonlinear optical properties of silicon waveguides

    International Nuclear Information System (INIS)

    Tsang, H K; Liu, Y

    2008-01-01

    Recent work on two-photon absorption (TPA), stimulated Raman scattering (SRS) and optical Kerr effect in silicon-on-insulator (SOI) waveguides is reviewed and some potential applications of these optical nonlinearities, including silicon-based autocorrelation detectors, optical amplifiers, high speed optical switches, optical wavelength converters and self-phase modulation (SPM), are highlighted. The importance of free carriers generated by TPA in nonlinear devices is discussed, and a generalized definition of the nonlinear effective length to cater for nonlinear losses is proposed. How carrier lifetime engineering, and in particular the use of helium ion implantation, can enhance the nonlinear effective length for nonlinear devices is also discussed

  16. Nonlinear Properties of Soft Glass Waveguides

    DEFF Research Database (Denmark)

    Steffensen, Henrik

    -infrared applications and the THz applications. In the mid-infrared, it is investigated whether soft glasses are a suitable candidate for supercontinuum generation (SCG). A few commercially available fluoride fibers are tested for their zero dispersion wavelength (ZDW), a key property when determining the possibility......This thesis builds around the investigation into using soft glass materials for midinfrared and THz applications. Soft glasses is a term that cov ers a wide range of chemical compositions where many are yet to be fully investigated. The work in this thesis is separated in two parts, the mid...... of SCG in a fiber. A group of soft glasses, namely the chalcogenides, are known to display two photon absorption (TPA) which could potentially limit the SCG when this is initiated within the frequency range where this nonlinear process occur. An analytic model is presented to estimate the soliton self...

  17. Relation between EPS adherence, viscoelastic properties, and MBR operation: Biofouling study with QCM-D.

    Science.gov (United States)

    Sweity, Amer; Ying, Wang; Ali-Shtayeh, Mohammed S; Yang, Fei; Bick, Amos; Oron, Gideon; Herzberg, Moshe

    2011-12-01

    Membrane fouling is one of the main constraints of the wide use of membrane bioreactor (MBR) technology. The biomass in MBR systems includes extracellular polymeric substances (EPS), metabolic products of active microbial secretion that adversely affect the membrane performance. Solids retention time (SRT) in the MBR is one of the most important parameters affecting membrane fouling in MBR systems, where fouling is minimized at optimal SRT. Among the operating parameters in MBR systems, SRT is known to strongly influence the ratio of proteins to polysaccharides in the EPS matrix. In this study, we have direct evidence for changes in EPS adherence and viscoelastic properties due to changes in the sludge removal rate that strongly correlate with the membrane fouling rate and EPS composition. EPS were extracted from a UF membrane in a hybrid growth MBR operated at sludge removal rates of 59, 35.4, 17.7, and 5.9 L day(-1) (corresponding SRT of 3, 5, 10, and 30 days, respectively). The EPS adherence and adsorption kinetics were carried out in a quartz crystal microbalance with dissipation monitoring (QCM-D) technology in several adsorption measurements to a gold sensor coated with Polyvinylidene Fluoride (PVDF). EPS adsorption to the sensor surface is characterized by a decrease of the oscillation frequency and an increase in the dissipation energy of the sensor during parallel flow of aqueous media, supplemented with EPS, above the sensor surface. The results from these experiments were further modeled using the Voigt based model, in which the thickness, shear modulus, and shear viscosity values of the adsorbed EPS layers on the PVDF crystal were calculated. The observations in the QCM-D suggested that the elevated fouling of the UF membrane is due to higher adherence of the EPS as well as reduction in viscosity and elasticity of the EPS adsorbed layer and elevation of the EPS fluidity. These results corroborate with confocal laser scanning microscopy (CLSM) image

  18. Quantitative evaluation of the viscoelastic properties of the ankle joint complex in patients suffering from ankle sprain by the anterior drawer test.

    Science.gov (United States)

    Lin, Che-Yu; Shau, Yio-Wha; Wang, Chung-Li; Chai, Huei-Ming; Kang, Jiunn-Horng

    2013-06-01

    Biological tissues such as ligaments exhibit viscoelastic behaviours. Injury to the ligament may induce changes of these viscoelastic properties, and these changes could serve as biomarkers to detect the injury. In the present study, a novel instrument was developed to non-invasive quantify the viscoelastic properties of the ankle in vivo by the anterior drawer test. The purpose of the study was to investigate the reliability of the instrument and to compare the viscoelastic properties of the ankle between patients suffering from ankle sprain and controls. Eight patients and eight controls participated in the present study. The reliability test was performed on three randomly chosen subjects. In patient and control test, both ankles of each subject were tested to evaluate the viscoelastic properties of the ankle. The viscosity index was defined for quantitatively evaluating the viscosity of the ankle. Greater viscosity index was associated with lower viscosity. Injured and uninjured ankles of patient and both ankles of controls were compared. The instrument exhibited excellent test-retest reliability (r > 0.9). Injured ankles exhibited significantly less viscosity than uninjured ankles, since injured ankles of patients had significantly higher viscosity index (8,148 ± 5,266) compared with uninjured ankles of patients (948 ± 617; p = 0.008) and controls (1,326 ± 613; p ankle can serve as sensitive and useful clinical biomarkers to differentiate between injured and uninjured ankles. The method may provide a clinical examination for objectively evaluating lateral ankle ligament injuries.

  19. Human amniotic epithelial cell transplantation for the repair of injured brachial plexus nerve: evaluation of nerve viscoelastic properties

    Directory of Open Access Journals (Sweden)

    Hua Jin

    2015-01-01

    Full Text Available The transplantation of embryonic stem cells can effectively improve the creeping strength of nerves near an injury site in animals. Amniotic epithelial cells have similar biological properties as embryonic stem cells; therefore, we hypothesized that transplantation of amniotic epithelial cells can repair peripheral nerve injury and recover the creeping strength of the brachial plexus nerve. In the present study, a brachial plexus injury model was established in rabbits using the C 6 root avulsion method. A suspension of human amniotic epithelial cells was repeatedly injected over an area 4.0 mm lateral to the cephal and caudal ends of the C 6 brachial plexus injury site (1 × 10 6 cells/mL, 3 μL/injection, 25 injections immediately after the injury. The results showed that the decrease in stress and increase in strain at 7,200 seconds in the injured rabbit C 6 brachial plexus nerve were mitigated by the cell transplantation, restoring the viscoelastic stress relaxation and creep properties of the brachial plexus nerve. The forepaw functions were also significantly improved at 26 weeks after injury. These data indicate that transplantation of human amniotic epithelial cells can effectively restore the mechanical properties of the brachial plexus nerve after injury in rabbits and that viscoelasticity may be an important index for the evaluation of brachial plexus injury in animals.

  20. Lecithin-based emulsions for potential use as saliva substitutes in patients with xerostomia--viscoelastic properties.

    Science.gov (United States)

    Hanning, Sara M; Yu, Tao; Jones, David S; Andrews, Gavin P; Kieser, Jules A; Medlicott, Natalie J

    2013-11-18

    The purpose of the present study was to investigate lecithin-rice bran oil rheological properties with the view to consider these as potential saliva substitutes in patients with severe xerostomia and salivary hypofunction. Pseudo-ternary phase diagrams of rice bran oil, lecithin and water mixtures were constructed and characterised using polarising light microscopy. Viscoelastic properties, which we hypothesise are important determinants in product performance, were analysed using both flow and oscillatory rheology. Rheological properties were influenced by composition, frequency and shear stress. Frequency-dependent viscoelasticity was observed in some formulations where viscosity dominated (tanδ>1) at frequencies under 5 Hz and elasticity dominated (tanδ<1) at higher frequencies. Threshold frequencies were determined for each formulation, where a peak in loss tangent was observed, coinciding with a reduction in the storage modulus and increase in loss modulus. The frequency-dependent behaviour of emulsions are of interest because these combinations exhibit viscous behaviour at low frequencies, which may improve lubrication of the oral cavity at rest, whereas increased elasticity at higher frequencies may improve retention during higher-shear tasks such as swallowing and speaking. Copyright © 2013 Elsevier B.V. All rights reserved.

  1. The viscoelastic properties of the protein-rich materials from the fermented hard wheat, soft wheat and barley flours

    Science.gov (United States)

    The linear and non-linear rheological properties of the suspensions for the hard red spring wheat (HRS) flour, soft wheat (Pastry) flour, barley flour, as well as the remain residues of HRS flour, Pastry flour, and barley flour after fermentation were investigated. The linear and non-linear rheologi...

  2. MEASUREMENT OF THE VISCOELASTIC PROPERTIES OF WATER-SATURATED CLAY SEDIMENTS.

    Science.gov (United States)

    The complex shear modulus of both kaolin -water and bentonite-water mixtures has been determined in the laboratory. The method involved measuring the...range two to forty-three kHz. Dispersed sediments behaved like Newtonian liquids. Undispersed sediments, however, were viscoelastic in character, and...their shear moduli exhibited no dependence on frequency. For undispersed kaolin mixtures, a typical result is (21.6 + i 1.2) x 1,000 dynes per square

  3. Dominant role of wormlike micelles in temperature-responsive viscoelastic properties of their mixtures with polymeric chains

    KAUST Repository

    Molchanov, Vyacheslav S.

    2013-03-01

    Temperature effects on the rheological properties of viscoelastic solutions containing entangled wormlike micelles of potassium oleate and hydrophobically modified polyacrylamide were studied in a wide range of polymer concentrations. A very pronounced drop of viscosity by four orders of magnitude was observed at heating from 20 to 78 °C both in the presence and in the absence of polymer indicating that the wormlike micelles are mainly responsible for this effect. The highly thermosensitive behavior was attributed to the shortening of micellar chains induced by heating. Although the decrease in viscosity is almost the same for both surfactant and surfactant/polymer systems, the absolute values of the viscosity in the presence of polymer are by few orders of magnitude higher, which is due to the formation of a common network of entangled polymer and micellar chains. As a result, the added polymer allows one to get highly temperature responsive system that keeps viscoelastic properties in a much wider range of temperatures, which makes it very promising for various practical applications. © 2012 Elsevier Inc.

  4. Modeling Non-Linear Material Properties in Composite Materials

    Science.gov (United States)

    2016-06-28

    Technical Report ARWSB-TR-16013 MODELING NON-LINEAR MATERIAL PROPERTIES IN COMPOSITE MATERIALS Michael F. Macri Andrew G...REPORT TYPE Technical 3. DATES COVERED (From - To) 4. TITLE AND SUBTITLE MODELING NON-LINEAR MATERIAL PROPERTIES IN COMPOSITE MATERIALS ...systems are increasingly incorporating composite materials into their design. Many of these systems subject the composites to environmental conditions

  5. Engineering viscoelasticity

    CERN Document Server

    Gutierrez-Lemini, Danton

    2014-01-01

    Engineering Viscoelasticity covers all aspects of the thermo- mechanical response of viscoelastic substances that a practitioner in the field of viscoelasticity would need to design experiments, interpret test data, develop stress-strain models, perform stress analyses, design structural components, and carry out research work. The material in each chapter is developed from the elementary to the advanced, providing the background in mathematics and mechanics that are central to understanding the subject matter being presented. The book examines how viscoelastic materials respond to the application of loads, and provides practical guidelines to use them in the design of commercial, military and industrial applications. This book also: ·         Facilitates conceptual understanding by progressing in each chapter from elementary to challenging material ·         Examines in detail both differential and integral constitutive equations, devoting full chapters to each type and using both forms in ...

  6. 5B.05: MARFAN SYNDROME: ASSESSMENT OF AORTIC DISSECTION RISK BY ANALYSIS OF AORTIC VISCOELASTIC PROPERTIES.

    Science.gov (United States)

    Grillo, A; Pini, A; Marelli, S; Gan, L; Giuliano, A; Trifirò, G; Santini, F; Salvi, L; Salvi, P; Viecca, F; Carretta, R; Parati, G

    2015-06-01

    Marfan syndrome is an autosomal dominant genetic disorder characterized by an abnormal fibrillin-1 synthesis. Aortic root dilation and dissection are the main problems affecting patients prognosis in these patients. Their pharmacological prophylaxis with losartan or with a beta-blocker counteracts the aortic root dilation, but a close follow-up is required to assess therapeutic response rate and to identify non-responders. Unfortunately genotype-phenotype studies do not allow to determine the exact risk profile in these patients and there is no reliable method to accurately predict their risk of aortic dissection. Aim of this study was to evaluate non-invasive markers for identification of Marfan patients at higher risk of aortic complications. We studied 187 Marfan patients (identified according to 2010 Revised Ghent Criteria and positive genetic analysis), age 32.3 ± 16.5 yrs (mean ± SD). 52 patients (27.8%) had undergone surgical ascending aorta replacement (David or Bentall procedure). Central pressure curves were recorded by PulsePen tonometer, and the aortic viscoelastic aortic properties were studied by determination of carotid-femoral pulse wave velocity (PWV). With reference to the age related distribution of PWV values in a normal population, defined according to Arterial-Stiffness-Collaboration, PWV mean values in Marfan patients corresponded to 60th percentile in non- operated patients and to the 67th percentile in those operated. Adult Marfan patients (n = 146) generally displayed a low blood pressure, because of the pharmacological prophylaxis, and were compared with a population of 189 adult healthy subjects (81 males), matched by age (38 ± 13 vs 38 ± 16 yrs.), heart rate (64 ± 9 bpm vs 64 ± 11 bpm) and blood pressure (mean BP = 78 ± 9 mmHg vs 79 ± 4 mmHg) values. Average PWV value was higher than in healthy controls (PWV = 7.0 ± 1.7) both in not operated (PWV = 7.6 ± 1.6; p = 0

  7. Global solutions to the initial-boundary value problem for the quasilinear viscoelastic equation with a derivative nonlinearity

    Directory of Open Access Journals (Sweden)

    Mitsuhiro Nakao

    2014-01-01

    Full Text Available We prove the existence and uniqueness of a global decaying solution to the initial boundary value problem for the quasilinear wave equation with Kelvin-Voigt dissipation and a derivative nonlinearity. To derive the required estimates of the solutions we employ a 'loan' method and use a difference inequality on the energy.

  8. Effect of pH and salts on microstructure and viscoelastic properties of lemon peel acid insoluble fiber suspensions upon high pressure homogenization

    NARCIS (Netherlands)

    Willemsen, Katleen L.D.D.; Panozzo, Agnese; Moelants, Katlijn; Cardinaels, Ruth; Wallecan, Joël; Moldenaers, Paula; Hendrickx, Marc

    2018-01-01

    In the present paper the effect of pH and salts on microstructural and viscoelastic properties of lemon peel acid insoluble fiber residue (AR) suspensions upon mild and intense shearing was investigated. To this aim, AR suspensions were adjusted to a pH of 2.5 (as is), 4.5, 5.5, 7 or 10 prior to or

  9. Nonlinear optical properties of ultrathin metal layers

    DEFF Research Database (Denmark)

    Lysenko, Oleg

    2016-01-01

    This thesis presents experimental and theoretical studies of nonlinear propagation of ultrashort long-range surface plasmon polaritons in gold strip waveguides. The strip plasmonic waveguides are fabricated in house, and contain a gold layer, adhesion layers, and silicon dioxide cladding. The opt......This thesis presents experimental and theoretical studies of nonlinear propagation of ultrashort long-range surface plasmon polaritons in gold strip waveguides. The strip plasmonic waveguides are fabricated in house, and contain a gold layer, adhesion layers, and silicon dioxide cladding......-order nonlinear susceptibility of the plasmonic mode in the gold strip waveguides significantly depends on the metal layer thickness and laser pulse duration. This dependence is explained in detail in terms of the free-electron temporal dynamics in gold. The third-order nonlinear susceptibility of the gold layer...

  10. Enhancement of nonlinear optical properties of compounds of silica

    Indian Academy of Sciences (India)

    The aim of this paper is to introduce a method for enhancing the nonlinear optical properties in silica glass by using metallic nanoparticles. First, the T-matrix method is developed to calculate the effective dielectric constant for the compound of silica glass and metallic nanoparticles, both of which possess nonlinear dielectric ...

  11. Computational Viscoelasticity

    CERN Document Server

    Marques, Severino P C

    2012-01-01

    This text is a guide how to solve problems in which viscoelasticity is present using existing commercial computational codes. The book gives information on codes’ structure and use, data preparation  and output interpretation and verification. The first part of the book introduces the reader to the subject, and to provide the models, equations and notation to be used in the computational applications. The second part shows the most important Computational techniques: Finite elements formulation, Boundary elements formulation, and presents the solutions of Viscoelastic problems with Abaqus.

  12. Insoluble elastin reduces collagen scaffold stiffness, improves viscoelastic properties, and induces a contractile phenotype in smooth muscle cells.

    Science.gov (United States)

    Ryan, Alan J; O'Brien, Fergal J

    2015-12-01

    Biomaterials with the capacity to innately guide cell behaviour while also displaying suitable mechanical properties remain a challenge in tissue engineering. Our approach to this has been to utilise insoluble elastin in combination with collagen as the basis of a biomimetic scaffold for cardiovascular tissue engineering. Elastin was found to markedly alter the mechanical and biological response of these collagen-based scaffolds. Specifically, during extensive mechanical assessment elastin was found to reduce the specific tensile and compressive moduli of the scaffolds in a concentration dependant manner while having minimal effect on scaffold microarchitecture with both scaffold porosity and pore size still within the ideal ranges for tissue engineering applications. However, the viscoelastic properties were significantly improved with elastin addition with a 3.5-fold decrease in induced creep strain, a 6-fold increase in cyclical strain recovery, and with a four-parameter viscoelastic model confirming the ability of elastin to confer resistance to long term deformation/creep. Furthermore, elastin was found to result in the modulation of SMC phenotype towards a contractile state which was determined via reduced proliferation and significantly enhanced expression of early (α-SMA), mid (calponin), and late stage (SM-MHC) contractile proteins. This allows the ability to utilise extracellular matrix proteins alone to modulate SMC phenotype without any exogenous factors added. Taken together, the ability of elastin to alter the mechanical and biological response of collagen scaffolds has led to the development of a biomimetic biomaterial highly suitable for cardiovascular tissue engineering. Copyright © 2015 Elsevier Ltd. All rights reserved.

  13. Linear and nonlinear optical properties of borate crystals as ...

    Indian Academy of Sciences (India)

    Unknown

    crystal series, with an accuracy acceptable for materials development/design, and answer the questions often ... Optical property; nonlinear optical crystals; first principles calculation. 1. ..... system, and is not in concept suitable to excitation pro-.

  14. Transient thermal effect, nonlinear refraction and nonlinear absorption properties of graphene oxide sheets in dispersion.

    Science.gov (United States)

    Zhang, Xiao-Liang; Liu, Zhi-Bo; Li, Xiao-Chun; Ma, Qiang; Chen, Xu-Dong; Tian, Jian-Guo; Xu, Yan-Fei; Chen, Yong-Sheng

    2013-03-25

    The nonlinear refraction (NLR) properties of graphene oxide (GO) in N, N-Dimethylformamide (DMF) was studied in nanosecond, picosecond and femtosecond time regimes by Z-scan technique. Results show that the dispersion of GO in DMF exhibits negative NLR properties in nanosecond time regime, which is mainly attributed to transient thermal effect in the dispersion. The dispersion also exhibits negative NLR in picosecond and femtosecond time regimes, which are arising from sp(2)- hybridized carbon domains and sp(3)- hybridized matrix in GO sheets. To illustrate the relations between NLR and nonlinear absorption (NLA), NLA properties of the dispersion were also studied in nanosecond, picosecond and femtosecond time regimes.

  15. A micromechanical approach to elastic and viscoelastic properties of fiber reinforced concrete

    International Nuclear Information System (INIS)

    Pasa Dutra, V.F.; Maghous, S.; Campos Filho, A.; Pacheco, A.R.

    2010-01-01

    Some aspects of the constitutive behavior of fiber reinforced concrete (FRC) are investigated within a micromechanical framework. Special emphasis is put on the prediction of creep of such materials. The linear elastic behavior is first examined by implementation of a Mori-Tanaka homogenization scheme. The micromechanical predictions for the overall stiffness prove to be very close to finite element solutions obtained from the numerical analysis of a representative elementary volume of FRC modeled as a randomly heterogeneous medium. The validation of the micromechanical concepts based on comparison with a set of experiments, shows remarkable predictive capabilities of the micromechanical representation. The second part of the paper is devoted to non-ageing viscoelasticity of FRC. Adopting a Zener model for the behavior of the concrete matrix and making use of the correspondence principle, the homogenized relaxation moduli are derived analytically. The validity of the model is established by mean of comparison with available experiment measurements of creep strain of steel fiber reinforced concrete under compressive load. Finally, the model predictions are compared to those derived from analytical models formulated within a one-dimensional setting.

  16. Large particles increase viscosity and yield stress of pig cecal contents without changing basic viscoelastic properties.

    Science.gov (United States)

    Takahashi, Toru; Sakata, Takashi

    2002-05-01

    The viscosity of gut contents should influence digestion and absorption. Earlier investigators measured the viscosity of intestinal contents after the removal of solid particles. However, we previously found that removal of solid particles from pig cecal contents dramatically lowered the viscosity of the contents. Accordingly, we examined the contribution of large solid particles to viscoelastic parameters of gut contents in the present study. We removed large particles from pig cecal contents by filtration through surgical gauze. Then, we reconstructed the cecal contents by returning all, one half or none of the original amount of the large particles to the filtrate. We measured the viscosity, shear stress and shear rate of these reconstructed cecal contents using a tube-flow viscometer. The coefficient of viscosity was larger when the large-particle content was higher (P Bingham plastic nature irrespective of large-particle content. We calculated the yield stress of these fluids assuming that the fluids behave as Bingham plastic. The yield stress of the cecal contents was greater (P Bingham plastic characteristics to pig cecal contents.

  17. Effect of viscoelastic properties of plantar soft tissues on plantar pressures at the first metatarsal head in diabetics with peripheral neuropathy

    International Nuclear Information System (INIS)

    Jan, Yih-Kuen; Rong, Daqian; Lung, Chi-Wen; Cuaderes, Elena; Boyce, Kari

    2013-01-01

    Diabetic foot ulcers are one of the most serious complications associated with diabetes mellitus. Current research studies have demonstrated that biomechanical alterations of the diabetic foot contribute to the development of foot ulcers. However, the changes of soft tissue biomechanical properties associated with diabetes and its influences on the development of diabetic foot ulcers have not been investigated. The purpose of this study was to investigate the effect of diabetes on the biomechanical properties of plantar soft tissues and the relationship between biomechanical properties and plantar pressure distributions. We used the ultrasound indentation tests to measure force-deformation relationships of plantar soft tissues and calculate the effective Young's modulus and quasi-linear viscoelastic parameters to quantify biomechanical properties of plantar soft tissues. We also measured plantar pressures to calculate peak plantar pressure and plantar pressure gradient. Our results showed that diabetics had a significantly greater effective Young's modulus and initial modulus of quasi-linear viscoelasticity compared to non-diabetics. The plantar pressure gradient and biomechanical properties were significantly correlated. Our findings indicate that diabetes is linked to an increase in viscoelasticity of plantar soft tissues that may contribute to a higher peak plantar pressure and plantar pressure gradient in the diabetic foot. (paper)

  18. Linear viscoelastic characterization from filament stretching rheometry

    DEFF Research Database (Denmark)

    Wingstrand, Sara Lindeblad; Alvarez, Nicolas J.; Hassager, Ole

    to measure both linear and nonlinear dynamics on a single apparatus. With a software modification to the FSR motor control, we show that linear viscoelasticity can be measured via small amplitude squeeze flow (SASF). Squeeze flow is a combination of both shear and extensional flow applied by axially......Traditionally, linear viscoelasticity is measured using small amplitude oscillatory shear flow. Due to experimental difficulties, shear flows are predominately confined to the linear and mildly nonlinear regime. On the other hand, extensional flows have proven more practical in measuring...... viscoelasticity well into the nonlinear regime. Therefore at present, complete rheological characterization of a material requires two apparatuses: a shear and an extensional rheometer. This work is focused on developing a linear viscoelastic protocol for the filament stretching rheometer (FSR) in order...

  19. Computational studies of third-order nonlinear optical properties of ...

    Indian Academy of Sciences (India)

    Anuj Kumar

    2017-06-20

    Jun 20, 2017 ... Department of Physics, Jaypee University of Engineering and Technology, Raghogarh,. Guna 473 226, India. ∗ ... properties and other molecular properties of the organic nonlinear optical crystal 2-aminopyridinium p- toluenesulphonate ... nal processing, optical limiting, optical logic gates, laser radiation ...

  20. Viscoelasticity of biomaterials

    International Nuclear Information System (INIS)

    Glasser, W.G.; Hatakeyama, H.

    1992-01-01

    Viscoelasticity of Biomaterials is divided into three sections. The first offers a materials design lesson on the architectural arrangement of biopolymers in collagen. Included also are reviews on solution properties of polysacchardies, chiral and liquid crystalline solution characteristics of cellulose derivatives, and viscoelastic properties of wood and wood fiber reinforced thermoplastics. The second section, Biogels and Gelation, discusses the molecular arrangements of highly hydrated biomaterials such as mucus, gums, skinlike tissue, and silk fibroin. The physical effects that result from the transition from a liquid to a solid state are the subject of the third section, which focuses on relaxation phenomena. Gel formation, the conformation of domain structures, and motional aspects of complex biomaterials are described in terms of recent experimental advances in various fields. A relevant chapter on the effects of ionizing radiation on connective tissue is abstracted separately

  1. A review on melt-state viscoelastic properties of polymer nanocomposites

    CSIR Research Space (South Africa)

    Hyoung, JC

    2011-10-01

    Full Text Available The mixing of polymer matrices with nanoparticles to form composite materials has been an area of great research interest. The mechanical and rheological properties of such composite materials are directly related to the properties of the matrix...

  2. Hydrophilicity, Viscoelastic, and Physicochemical Properties Variations in Dental Bone Grafting Substitutes

    Directory of Open Access Journals (Sweden)

    Branko Trajkovski

    2018-01-01

    Full Text Available The indication-oriented Dental Bone Graft Substitutes (DBGS selection, the correct bone defects classification, and appropriate treatment planning are very crucial for obtaining successful clinical results. However, hydrophilic, viscoelastic, and physicochemical properties’ influence on the DBGS regenerative potential has poorly been studied. For that reason, we investigated the dimensional changes and molecular mobility by Dynamic Mechanical Analysis (DMA of xenograft (cerabone®, synthetic (maxresorb®, and allograft (maxgraft®, Puros® blocks in a wet and dry state. While no significant differences could be seen in dry state, cerabone® and maxresorb® blocks showed a slight height decrease in wet state, whereas both maxgraft® and Puros® had an almost identical height increase. In addition, cerabone® and maxresorb® blocks remained highly rigid and their damping behaviour was not influenced by the water. On the other hand, both maxgraft® and Puros® had a strong increase in their molecular mobility with different damping behaviour profiles during the wet state. A high-speed microscopical imaging system was used to analyze the hydrophilicity in several naturally derived (cerabone®, Bio-Oss®, NuOss®, SIC® nature graft and synthetic DBGS granules (maxresorb®, BoneCeramic®, NanoBone®, Ceros®. The highest level of hydrophilicity was detected in cerabone® and maxresorb®, while Bio-Oss® and BoneCeramic® had the lowest level of hydrophilicity among both naturally derived and synthetic DBGS groups. Deviations among the DBGS were also addressed via physicochemical differences recorded by Micro Computed Tomography, Scanning Electron Microscopy, Fourier Transform Infrared Spectroscopy, X-ray powder Diffractometry, and Thermogravimetric Analysis. Such DBGS variations could influence the volume stability at the grafting site, handling as well as the speed of vascularization and bone regeneration. Therefore, this study initiates a new

  3. Geometric properties of Banach spaces and nonlinear iterations

    CERN Document Server

    Chidume, Charles

    2009-01-01

    Nonlinear functional analysis and applications is an area of study that has provided fascination for many mathematicians across the world. This monograph delves specifically into the topic of the geometric properties of Banach spaces and nonlinear iterations, a subject of extensive research over the past thirty years. Chapters 1 to 5 develop materials on convexity and smoothness of Banach spaces, associated moduli and connections with duality maps. Key results obtained are summarized at the end of each chapter for easy reference. Chapters 6 to 23 deal with an in-depth, comprehensive and up-to-date coverage of the main ideas, concepts and results on iterative algorithms for the approximation of fixed points of nonlinear nonexpansive and pseudo-contractive-type mappings. This includes detailed workings on solutions of variational inequality problems, solutions of Hammerstein integral equations, and common fixed points (and common zeros) of families of nonlinear mappings. Carefully referenced and full of recent,...

  4. Effect of viscoelastic and dielectric relaxing matrix on ferroelastic behaviour of 1-3 piezocomposites

    Directory of Open Access Journals (Sweden)

    R. Jayendiran

    2015-02-01

    Full Text Available This work focuses on evaluating the time-dependent non-linear ferroelastic behaviour of 1-3 piezocomposites under pure uni-axial compressive stress loading condition. An experimental setup is developed to study the influence of high-stress levels on the stress-strain and stress-polarization behaviour of 1-3 piezocomposites. The electro-elastic effective properties of 1-3 piezocomposites are measured experimentally based on IEEE standard and compared with the proposed numerical model using finite-element software ABAQUS. The time-dependent effective properties are evaluated using viscoelastic model and it is incorporated into a 3D micromechanical model to predict the viscoelastic behaviour of 1-3 piezocomposites under mechanical loading. The simulated results are compared with the viscoelastic behaviour of 1-3 piezocomposites obtained from experiments.

  5. Studies on Solid Wood. II. The Influence of Chemical Modifications on Viscoelastic Properties

    DEFF Research Database (Denmark)

    Bjørkmann, Anders; Salmén, Lennart

    2000-01-01

    The relation between the properties of wood polymers and those of the composite material of wood is a subject that has been of interest for a long time. In order to increase oar knowledge in this matter, changes of wood properties have been studied on samples of spruce and birch, subjected to var...

  6. Nonlinear Electrostatic Properties of Lunar Dust

    Science.gov (United States)

    Irwin, Stacy A.

    2012-01-01

    A laboratory experiment was designed to study the induction charging and charge decay characteristics of small dielectric particles, or glass beads. Initially, the goal of the experiment was further understanding of induction charging of lunar dust particles. However, the mechanism of charging became a point of greater interest as the project continued. Within an environmentally-controlled acrylic glove box was placed a large parallel plate capacitor at high-voltage (HV) power supply with reversible polarity. Spherical 1-mm and 0.5-mm glass beads, singly, were placed between the plates, and their behaviors recorded on video and quantified. Nearly a hundred trials at various humidities were performed. The analysis of the results indicated a non-linear relationship between humidity and particle charge exchange time (CET), for both sizes of beads. Further, a difference in CET for top-resting beads and bottom-resting beads hinted at a different charging mechanism than that of simple induction. Results from the I-mm bead trials were presented at several space science and physics conferences in 2008 and 2009, and were published as a Master's thesis in August 2009. Tangential work stemming from this project resulted in presentations at other international conferences in 2010, and selection to attend workshop on granular matter flow 2011.

  7. Fully coupled heat conduction and deformation analyses of visco-elastic solids

    KAUST Repository

    Khan, Kamran

    2012-04-21

    Visco-elastic materials are known for their capability of dissipating energy. This energy is converted into heat and thus changes the temperature of the materials. In addition to the dissipation effect, an external thermal stimulus can also alter the temperature in a viscoelastic body. The rate of stress relaxation (or the rate of creep) and the mechanical and physical properties of visco-elastic materials, such as polymers, vary with temperature. This study aims at understanding the effect of coupling between the thermal and mechanical response that is attributed to the dissipation of energy, heat conduction, and temperature-dependent material parameters on the overall response of visco-elastic solids. The non-linearly viscoelastic constitutive model proposed by Schapery (Further development of a thermodynamic constitutive theory: stress formulation, 1969,Mech. Time-Depend. Mater. 1:209-240, 1997) is used and modified to incorporate temperature- and stress-dependent material properties. This study also formulates a non-linear energy equation along with a dissipation function based on the Gibbs potential of Schapery (Mech. Time-Depend. Mater. 1:209-240, 1997). A numerical algorithm is formulated for analyzing a fully coupled thermo-visco-elastic response and implemented it in a general finite-element (FE) code. The non-linear stress- and temperature-dependent material parameters are found to have significant effects on the coupled thermo-visco-elastic response of polymers considered in this study. In order to obtain a realistic temperature field within the polymer visco-elastic bodies undergoing a non-uniform heat generation, the role of heat conduction cannot be ignored. © Springer Science+Business Media, B. V. 2012.

  8. Impact of the Ageing on Viscoelastic Properties of Bitumen with the Liquid Surface Active Agent at Operating Temperatures

    Science.gov (United States)

    Iwański, Marek; Cholewińska, Malgorzata; Mazurek, Grzegorz

    2017-10-01

    The paper presents the influence of the ageing on viscoelastic properties of the bitumen at road pavement operating temperatures. The ageing process of bituminous binders causes changes in physical and mechanical properties of the bitumen. This phenomenon takes place in all stages of bituminous mixtures manufacturing, namely: mixing, storage, transport, placing. Nevertheless, during the service life it occurs the increase in stiffness of asphalt binder that is caused by the physical hardening of bitumen as well as the influence of oxidation. Therefore, it is important to identify the binder properties at a high and low operating temperatures of asphalt pavement after simulation of an ageing process. In the experiment as a reference bitumen, the polymer modified bitumen PMB 45/80-65 was used. The liquid surface active agent FA (fatty amine) was used as a bitumen viscosity-reducing modifier. It was added in the amount of 0,2%, 0,4% and 0,6% by the bitumen mass. All binder properties have been determined before ageing (NEAT) and after long-term ageing simulated by the Pressure Ageing Vessel method (PAV). To determine the binder properties at high temperatures the dynamic viscosity at 60°C was tested. On the basis of test results coming from the dynamic viscosity test it was calculated the binder hardening index. The properties at a low temperature were determined by measuring the creep modulus using Bending Beam Rheometer (BBR) at four temperatures: -10°C, -16°C, -22°C and -28°C. The stiffness creep modulus “S” and parameter “m” were determined. On the basis of dynamic viscosity test it was found that the ageing process caused a slight decrease in a dynamic viscosity. The level of a hardening index considerably increased at 0.6% fatty amine content. The long-term ageing process had a minor effect on stiffening of a polymer modified bitumen with FA additive regardless of a low temperature and an amount of fatty amine content.

  9. Nonlinear Multigrid solver exploiting AMGe Coarse Spaces with Approximation Properties

    DEFF Research Database (Denmark)

    Christensen, Max la Cour; Villa, Umberto; Engsig-Karup, Allan Peter

    The paper introduces a nonlinear multigrid solver for mixed finite element discretizations based on the Full Approximation Scheme (FAS) and element-based Algebraic Multigrid (AMGe). The main motivation to use FAS for unstructured problems is the guaranteed approximation property of the AMGe coarse...... properties of the coarse spaces. With coarse spaces with approximation properties, our FAS approach on unstructured meshes has the ability to be as powerful/successful as FAS on geometrically refined meshes. For comparison, Newton’s method and Picard iterations with an inner state-of-the-art linear solver...... are compared to FAS on a nonlinear saddle point problem with applications to porous media flow. It is demonstrated that FAS is faster than Newton’s method and Picard iterations for the experiments considered here. Due to the guaranteed approximation properties of our AMGe, the coarse spaces are very accurate...

  10. Enhancement of nonlinear optical properties of compounds of silica ...

    Indian Academy of Sciences (India)

    Enhancement of nonlinear optical properties of compounds of silica glass and metallic nanoparticle. A GHARAATI1,∗ and A KAMALDAR1,2. 1Department of Physics, Payame Noor University, P.O. Box 19395-3697, Tehran, Iran. 2Department of Education 1, Shiraz, Iran. ∗. Corresponding author. E-mail: agharaati@pnu.ac.

  11. Symmetry properties of some nonlinear field theory models

    International Nuclear Information System (INIS)

    Shvachka, A.B.

    1984-01-01

    Various approaches towards the study of symmetry properties of some nonlinear evolution equations as well as possible ways of their computer implementation using the computer algebra systems langage are discussed. Special attention is paid to the method of pseudopotential investigation of formal integrability and isovector method for the equations of balance

  12. Viscoelastic behaviour of pumpkin balloons

    Science.gov (United States)

    Gerngross, T.; Xu, Y.; Pellegrino, S.

    2008-11-01

    The lobes of the NASA ULDB pumpkin-shaped super-pressure balloons are made of a thin polymeric film that shows considerable time-dependent behaviour. A nonlinear viscoelastic model based on experimental measurements has been recently established for this film. This paper presents a simulation of the viscoelastic behaviour of ULDB balloons with the finite element software ABAQUS. First, the standard viscoelastic modelling capabilities available in ABAQUS are examined, but are found of limited accuracy even for the case of simple uniaxial creep tests on ULDB films. Then, a nonlinear viscoelastic constitutive model is implemented by means of a user-defined subroutine. This approach is verified by means of biaxial creep experiments on pressurized cylinders and is found to be accurate provided that the film anisotropy is also included in the model. A preliminary set of predictions for a single lobe of a ULDB is presented at the end of the paper. It indicates that time-dependent effects in a balloon structure can lead to significant stress redistribution and large increases in the transverse strains in the lobes.

  13. Structure, Electronic and Nonlinear Optical Properties of Furyloxazoles and Thienyloxazoles

    International Nuclear Information System (INIS)

    Dagli, Ozlem; Gok, Rabia; Bahat, Mehmet; Ozbay, Akif

    2016-01-01

    Geometry optimization, electronic and nonlinear optical properties of isomers of furyloxazole and thienyloxazole molecules are carried out at the B3LYP/6-311++G(2d,p) level. The conformational analysis of 12 compounds have been studied as a function of torsional angle between rings. Electronic and NLO properties such as dipole moment, energy gap, polarizability and first hyperpolarizability were also calculated. (paper)

  14. Quantitative sonoelastography for the in vivo assessment of skeletal muscle viscoelasticity

    International Nuclear Information System (INIS)

    Hoyt, Kenneth; Kneezel, Timothy; Castaneda, Benjamin; Parker, Kevin J

    2008-01-01

    A novel quantitative sonoelastography technique for assessing the viscoelastic properties of skeletal muscle tissue was developed. Slowly propagating shear wave interference patterns (termed crawling waves) were generated using a two-source configuration vibrating normal to the surface. Theoretical models predict crawling wave displacement fields, which were validated through phantom studies. In experiments, a viscoelastic model was fit to dispersive shear wave speed sonoelastographic data using nonlinear least-squares techniques to determine frequency-independent shear modulus and viscosity estimates. Shear modulus estimates derived using the viscoelastic model were in agreement with that obtained by mechanical testing on phantom samples. Preliminary sonoelastographic data acquired in healthy human skeletal muscles confirm that high-quality quantitative elasticity data can be acquired in vivo. Studies on relaxed muscle indicate discernible differences in both shear modulus and viscosity estimates between different skeletal muscle groups. Investigations into the dynamic viscoelastic properties of (healthy) human skeletal muscles revealed that voluntarily contracted muscles exhibit considerable increases in both shear modulus and viscosity estimates as compared to the relaxed state. Overall, preliminary results are encouraging and quantitative sonoelastography may prove clinically feasible for in vivo characterization of the dynamic viscoelastic properties of human skeletal muscle

  15. How preconditioning affects the measurement of poro-viscoelastic mechanical properties in biological tissues

    NARCIS (Netherlands)

    Hosseini, S.M.; Wilson, W.; Ito, K.; Donkelaar, van C.C.

    2014-01-01

    It is known that initial loading curves of soft biological tissues are substantially different from subsequent loadings. The later loading curves are generally used for assessing the mechanical properties of a tissue, and the first loading cycles, referred to as preconditioning, are omitted.

  16. Nonlinear multigrid solvers exploiting AMGe coarse spaces with approximation properties

    DEFF Research Database (Denmark)

    Christensen, Max la Cour; Vassilevski, Panayot S.; Villa, Umberto

    2017-01-01

    discretizations on general unstructured grids for a large class of nonlinear partial differential equations, including saddle point problems. The approximation properties of the coarse spaces ensure that our FAS approach for general unstructured meshes leads to optimal mesh-independent convergence rates similar...... to those achieved by geometric FAS on a nested hierarchy of refined meshes. In the numerical results, Newton’s method and Picard iterations with state-of-the-art inner linear solvers are compared to our FAS algorithm for the solution of a nonlinear saddle point problem arising from porous media flow...

  17. Stability properties of nonlinear dynamical systems and evolutionary stable states

    Energy Technology Data Exchange (ETDEWEB)

    Gleria, Iram, E-mail: iram@fis.ufal.br [Instituto de Física, Universidade Federal de Alagoas, 57072-970 Maceió-AL (Brazil); Brenig, Leon [Faculté des Sciences, Université Libre de Bruxelles, 1050 Brussels (Belgium); Rocha Filho, Tarcísio M.; Figueiredo, Annibal [Instituto de Física and International Center for Condensed Matter Physics, Universidade de Brasília, 70919-970 Brasília-DF (Brazil)

    2017-03-18

    Highlights: • We address the problem of equilibrium stability in a general class of non-linear systems. • We link Evolutionary Stable States (ESS) to stable fixed points of square quasi-polynomial (QP) systems. • We show that an interior ES point may be related to stable interior fixed points of QP systems. - Abstract: In this paper we address the problem of stability in a general class of non-linear systems. We establish a link between the concepts of asymptotic stable interior fixed points of square Quasi-Polynomial systems and evolutionary stable states, a property of some payoff matrices arising from evolutionary games.

  18. Using nonlinearity and spatiotemporal property modulation to control effective structural properties: dynamic rods

    DEFF Research Database (Denmark)

    Thomsen, Jon Juel; Blekhman, Iliya I.

    2007-01-01

    What are the effective properties of a generally nonlinear material or structure, whose local properties are modulated in both space and time? It has been suggested to use spatiotemporal modulation of structural properties to create materials and structures with adjustable effective properties......, and to call these dynamic materials or spatiotemporal composites. Also, according to theoretical predictions, structural nonlinearity enhances the possibilities of achieving specific effective properties. For example, with an elastic rod having cubical elastic nonlinearities, it seems possible to control......, and exemplified. Then simple approximate analytical expressions are derived for the effective wave speed and natural frequencies for one-dimensional wave propagation in a nonlinear elastic rod, where the spatiotemporal modulation is imposed as a high-frequency standing wave, supposed to be given. Finally the more...

  19. Age-dependent effects of systemic administration of oxytetracycline on the viscoelastic properties of rat tail tendons as a mechanistic basis for pharmacological treatment of flexural limb deformities in foals.

    Science.gov (United States)

    Wintz, Leslie R; Lavagnino, Michael; Gardner, Keri L; Sedlak, Aleksa M; Arnoczky, Steven P

    2012-12-01

    To describe the effect of systemically administered oxytetracycline on the viscoelastic properties of rat tail tendon fascicles (TTfs) to provide a mechanistic rationale for pharmacological treatment of flexural limb deformities in foals. TTfs from ten 1-month-old and ten 6-month-old male Sprague-Dawley rats. 5 rats in each age group were administered oxytetracycline (50 mg/kg, IP, q 24 h) for 4 days. The remaining 5 rats in each age group served as untreated controls. Five days after initiation of oxytetracycline treatment, TTfs were collected and their viscoelastic properties were evaluated via a stress-relaxation protocol. Maximum modulus and equilibrium modulus were compared via a 2-way ANOVA. Collagen fibril size, density, and orientation in TTfs were compared between treated and control rats. Viscoelastic properties were significantly decreased in TTfs from 1-month-old oxytetracycline-treated rats, compared with those in TTfs from 1-month-old control rats. Oxytetracycline had no effect on the viscoelastic properties of TTfs from 6-month-old rats. Collagen fibril size, density, and orientation in TTfs from 1-month-old rats did not differ between oxytetracycline-treated and control rats. Results confirmed that systemically administered oxytetracycline decreased the viscoelastic properties of TTfs from 1-month-old rats but not those of TTfs from 6-month-old rats. The decrease in viscoelastic properties associated with oxytetracycline treatment does not appear to be caused by altered collagen fibril diameter or organization. The age-dependent effect of oxytetracycline on the viscoelastic properties of tendons may be related to its effect on the maturation of the extracellular matrix of developing tendons.

  20. Direct measurement of nonlinear properties of bipartite quantum states.

    Science.gov (United States)

    Bovino, Fabio Antonio; Castagnoli, Giuseppe; Ekert, Artur; Horodecki, Paweł; Alves, Carolina Moura; Sergienko, Alexander Vladimir

    2005-12-09

    Nonlinear properties of quantum states, such as entropy or entanglement, quantify important physical resources and are frequently used in quantum-information science. They are usually calculated from a full description of a quantum state, even though they depend only on a small number of parameters that specify the state. Here we extract a nonlocal and a nonlinear quantity, namely, the Renyi entropy, from local measurements on two pairs of polarization-entangled photons. We also introduce a "phase marking" technique which allows the selection of uncorrupted outcomes even with nondeterministic sources of entangled photons. We use our experimental data to demonstrate the violation of entropic inequalities. They are examples of nonlinear entanglement witnesses and their power exceeds all linear tests for quantum entanglement based on all possible Bell-Clauser-Horne-Shimony-Holt inequalities.

  1. Characterization of site-specific biomechanical properties of human meniscus-Importance of collagen and fluid on mechanical nonlinearities.

    Science.gov (United States)

    Danso, E K; Mäkelä, J T A; Tanska, P; Mononen, M E; Honkanen, J T J; Jurvelin, J S; Töyräs, J; Julkunen, P; Korhonen, R K

    2015-06-01

    Meniscus adapts to joint loads by depth- and site-specific variations in its composition and structure. However, site-specific mechanical characteristics of intact meniscus under compression are poorly known. In particular, mechanical nonlinearities caused by different meniscal constituents (collagen and fluid) are not known. In the current study, in situ indentation testing was conducted to determine site-specific elastic, viscoelastic and poroelastic properties of intact human menisci. Lateral and medial menisci (n=26) were harvested from the left knee joint of 13 human cadavers. Indentation tests, using stress-relaxation and dynamic (sinusoidal) loading protocols, were conducted for menisci at different sites (anterior, middle, posterior, n=78). Sample- and site-specific axisymmetric finite element models with fibril-reinforced poroelastic properties were fitted to the corresponding stress-relaxation curves to determine the mechanical parameters. Elastic moduli, especially the instantaneous and dynamic moduli, showed site-specific variation only in the medial meniscus (pmeniscus. The phase angle showed no statistically significant variation between the sites (p>0.05). The values for the strain-dependent fibril network modulus (nonlinear behaviour of collagen) were significantly different (pmeniscus only between the middle and posterior sites. For the strain-dependent permeability coefficient, only anterior and middle sites showed a significant difference (pmeniscus. This parameter demonstrated a significant difference (pmeniscus shows more site-dependent variation in the mechanical properties as compared to lateral meniscus. In particular, anterior horn of medial meniscus was the stiffest and showed the most nonlinear mechanical behaviour. The nonlinearity was related to both collagen fibrils and fluid. Copyright © 2015 Elsevier Ltd. All rights reserved.

  2. Growth and decay of weak disturbances in visco-elastic arteries

    International Nuclear Information System (INIS)

    Gaur, M.; Rai, S.K.

    1996-01-01

    In non-linear mathematical models of the arterial circulation, the visco-elasticity of the vessel walls has generally been neglected or only taken into account in a highly approximate manner. The object of the present paper is to provide a mathematical model for the propagation of weak disturbances in visco-elastic arteries. A differential equation governing the growth and decay of the waves has been obtained and solved analytically. It is observed that compressive pulses may grow into shock waves. A mathematical model which is based on geometrical and mechanical properties of arteries admits disturbances in the propagating pulses which are not observed in human beings under normal physiological conditions. It is also predicted that visco-elasticity delays the shock wave formation in the model. The shock wave may appear in periphery in the case of aortic insufficiency due to increased pressure at the root of aorta. The corresponding predictions are in much better agreement with in vivo measurements

  3. Relativistic viscoelastic fluid mechanics

    International Nuclear Information System (INIS)

    Fukuma, Masafumi; Sakatani, Yuho

    2011-01-01

    A detailed study is carried out for the relativistic theory of viscoelasticity which was recently constructed on the basis of Onsager's linear nonequilibrium thermodynamics. After rederiving the theory using a local argument with the entropy current, we show that this theory universally reduces to the standard relativistic Navier-Stokes fluid mechanics in the long time limit. Since effects of elasticity are taken into account, the dynamics at short time scales is modified from that given by the Navier-Stokes equations, so that acausal problems intrinsic to relativistic Navier-Stokes fluids are significantly remedied. We in particular show that the wave equations for the propagation of disturbance around a hydrostatic equilibrium in Minkowski space-time become symmetric hyperbolic for some range of parameters, so that the model is free of acausality problems. This observation suggests that the relativistic viscoelastic model with such parameters can be regarded as a causal completion of relativistic Navier-Stokes fluid mechanics. By adjusting parameters to various values, this theory can treat a wide variety of materials including elastic materials, Maxwell materials, Kelvin-Voigt materials, and (a nonlinearly generalized version of) simplified Israel-Stewart fluids, and thus we expect the theory to be the most universal description of single-component relativistic continuum materials. We also show that the presence of strains and the corresponding change in temperature are naturally unified through the Tolman law in a generally covariant description of continuum mechanics.

  4. Relativistic viscoelastic fluid mechanics.

    Science.gov (United States)

    Fukuma, Masafumi; Sakatani, Yuho

    2011-08-01

    A detailed study is carried out for the relativistic theory of viscoelasticity which was recently constructed on the basis of Onsager's linear nonequilibrium thermodynamics. After rederiving the theory using a local argument with the entropy current, we show that this theory universally reduces to the standard relativistic Navier-Stokes fluid mechanics in the long time limit. Since effects of elasticity are taken into account, the dynamics at short time scales is modified from that given by the Navier-Stokes equations, so that acausal problems intrinsic to relativistic Navier-Stokes fluids are significantly remedied. We in particular show that the wave equations for the propagation of disturbance around a hydrostatic equilibrium in Minkowski space-time become symmetric hyperbolic for some range of parameters, so that the model is free of acausality problems. This observation suggests that the relativistic viscoelastic model with such parameters can be regarded as a causal completion of relativistic Navier-Stokes fluid mechanics. By adjusting parameters to various values, this theory can treat a wide variety of materials including elastic materials, Maxwell materials, Kelvin-Voigt materials, and (a nonlinearly generalized version of) simplified Israel-Stewart fluids, and thus we expect the theory to be the most universal description of single-component relativistic continuum materials. We also show that the presence of strains and the corresponding change in temperature are naturally unified through the Tolman law in a generally covariant description of continuum mechanics.

  5. NONLINEAR MULTIGRID SOLVER EXPLOITING AMGe COARSE SPACES WITH APPROXIMATION PROPERTIES

    Energy Technology Data Exchange (ETDEWEB)

    Christensen, Max La Cour [Technical Univ. of Denmark, Lyngby (Denmark); Villa, Umberto E. [Univ. of Texas, Austin, TX (United States); Engsig-Karup, Allan P. [Technical Univ. of Denmark, Lyngby (Denmark); Vassilevski, Panayot S. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2016-01-22

    The paper introduces a nonlinear multigrid solver for mixed nite element discretizations based on the Full Approximation Scheme (FAS) and element-based Algebraic Multigrid (AMGe). The main motivation to use FAS for unstruc- tured problems is the guaranteed approximation property of the AMGe coarse spaces that were developed recently at Lawrence Livermore National Laboratory. These give the ability to derive stable and accurate coarse nonlinear discretization problems. The previous attempts (including ones with the original AMGe method, [5, 11]), were less successful due to lack of such good approximation properties of the coarse spaces. With coarse spaces with approximation properties, our FAS approach on un- structured meshes should be as powerful/successful as FAS on geometrically re ned meshes. For comparison, Newton's method and Picard iterations with an inner state-of-the-art linear solver is compared to FAS on a nonlinear saddle point problem with applications to porous media ow. It is demonstrated that FAS is faster than Newton's method and Picard iterations for the experiments considered here. Due to the guaranteed approximation properties of our AMGe, the coarse spaces are very accurate, providing a solver with the potential for mesh-independent convergence on general unstructured meshes.

  6. Viscoelastic material properties' identification using high speed full field measurements on vibrating plates

    Science.gov (United States)

    Giraudeau, A.; Pierron, F.

    2010-06-01

    The paper presents an experimental application of a method leading to the identification of the elastic and damping material properties of isotropic vibrating plates. The theory assumes that the searched parameters can be extracted from curvature and deflection fields measured on the whole surface of the plate at two particular instants of the vibrating motion. The experimental application consists in an original excitation fixture, a particular adaptation of an optical full-field measurement technique, a data preprocessing giving the curvature and deflection fields and finally in the identification process using the Virtual Fields Method (VFM). The principle of the deflectometry technique used for the measurements is presented. First results of identification on an acrylic plate are presented and compared to reference values. Details about a new experimental arrangement, currently in progress, is presented. It uses a high speed digital camera to over sample the full-field measurements.

  7. Development of a stress-mode sensitive viscoelastic constitutive relationship for asphalt concrete: experimental and numerical modeling

    Science.gov (United States)

    Karimi, Mohammad M.; Tabatabaee, Nader; Jahanbakhsh, H.; Jahangiri, Behnam

    2017-08-01

    Asphalt binder is responsible for the thermo-viscoelastic mechanical behavior of asphalt concrete. Upon application of pure compressive stress to an asphalt concrete specimen, the stress is transferred by mechanisms such as aggregate interlock and the adhesion/cohesion properties of asphalt mastic. In the pure tensile stress mode, aggregate interlock plays a limited role in stress transfer, and the mastic phase plays the dominant role through its adhesive/cohesive and viscoelastic properties. Under actual combined loading patterns, any coordinate direction may experience different stress modes; therefore, the mechanical behavior is not the same in the different directions and the asphalt specimen behaves as an anisotropic material. The present study developed an anisotropic nonlinear viscoelastic constitutive relationship that is sensitive to the tension/compression stress mode by extending Schapery's nonlinear viscoelastic model. The proposed constitutive relationship was implemented in Abaqus using a user material (UMAT) subroutine in an implicit scheme. Uniaxial compression and indirect tension (IDT) testing were used to characterize the viscoelastic properties of the bituminous materials and to calibrate and validate the proposed constitutive relationship. Compressive and tensile creep compliances were calculated using uniaxial compression, as well as IDT test results, for different creep-recovery loading patterns at intermediate temperature. The results showed that both tensile creep compliance and its rate were greater than those of compression. The calculated deflections based on these IDT test simulations were compared with experimental measurements and were deemed acceptable. This suggests that the proposed viscoelastic constitutive relationship correctly demonstrates the viscoelastic response and is more accurate for analysis of asphalt concrete in the laboratory or in situ.

  8. Anisotropic viscoelastic properties of quartz and quartzite in the vicinity of the α- β phase transition

    Science.gov (United States)

    Klumbach, Steffen; Schilling, Frank R.

    2017-10-01

    In this study we performed high-temperature, dynamic (i.e. sinusoidal), three-point bending experiments of quartz single crystals and quartzite samples within the frequency range of seismic surveys (i.e. 0.1-20 Hz). At constant temperature close to the α- β phase transition we observed a unique complex elastic behaviour of both quartz and quartzite. We find a frequency dependence of the complex Young's modulus of α-quartz, including a dissipation maximum at ≈1 Hz supposedly related to the formation and variation of Dauphiné twin domains. Based on our experimental results for different crystallographic directions and additional modelling, we are able to describe the complex Young's modulus of quartz at its α- β phase transition in a 3D diagram. We derive a frequency-dependent elasticity tensor, using a three-element equivalent circuit, composed of two springs E 1 and E 2 as well as a dashpot η. E 1 and η are connected parallel to each other, E 2 is added in series. Compliance coefficients yield ( S 11) E 1 = 572 GPa, E 2 = 70.0 GPa, η = 64.6 GPa·s, ( S 33) E 1 = 127 GPa, E 2 = 52.1 GPa, η = 22.9 GPa·s, ( S 44) E 1 = 204 GPa, E 2 = 37.5 GPa, η = 26.4 GPa·s, ( S 12) E 1 = 612 GPa, E 2 = 106.7 GPa, η = 78.5 GPa·s, ( S 13) E 1 = 1546 GPa, E 2 = 284 GPa, η = 200 GPa·s; S 14 ≈-0.0024 GPa-1. We use the derived direction-dependent coefficients to predict the frequency-dependent complex elastic properties of isotropic polycrystalline quartz. These predictions agree well with the experimental results of the investigated quartzite. Finally, we explore the potential of using the anomalous frequency-dependent complex elastic properties of quartz at the α- β phase transition that we observed as an in situ temperature probe for seismic studies of the Earth's continental crust.

  9. Reversibility and Viscoelastic Properties of Micropillar Supported and Oriented Magnesium Bundled F-Actin.

    Directory of Open Access Journals (Sweden)

    Timo Maier

    Full Text Available Filamentous actin is one of the most important cytoskeletal elements. Not only is it responsible for the elastic properties of many cell types, but it also plays a vital role in cellular adhesion and motility. Understanding the bundling kinetics of actin filaments is important in the formation of various cytoskeletal structures, such as filopodia and stress fibers. Utilizing a unique pillar-structured microfluidic device, we investigated the time dependence of bundling kinetics of pillar supported free-standing actin filaments. Microparticles attached to the filaments allowed the measurement of thermal motion, and we found that bundling takes place at lower concentrations than previously found in 3-dimensional actin gels, i.e. actin filaments formed bundles in the presence of 5-12 mM of magnesium chloride in a time-dependent manner. The filaments also displayed long term stability for up to hours after removing the magnesium ions from the buffer, which suggests that there is an extensive hysteresis between cation induced crosslinking and decrosslinking.

  10. Nonlinear transport properties of non-ideal systems

    International Nuclear Information System (INIS)

    Pavlov, G A

    2009-01-01

    The theory of nonlinear transport is elaborated to determine the Burnett transport properties of non-ideal multi-element plasma and neutral systems. The procedure for the comparison of the phenomenological conservation equations of a continuous dense medium and the microscopic equations for dynamical variable operators is used for the definition of these properties. The Mori algorithm is developed to derive the equations of motion of dynamical value operators of a non-ideal system in the form of the generalized nonlinear Langevin equations. In consequence, the microscopic expressions of transport coefficients corresponding to second-order thermal disturbances (temperature, mass velocity, etc) have been found in the long wavelength and low frequency limits

  11. Structure/property relationships in non-linear optical materials

    Energy Technology Data Exchange (ETDEWEB)

    Cole, J M [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France); [Durham Univ. (United Kingdom); Howard, J A.K. [Durham Univ. (United Kingdom); McIntyre, G J [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France)

    1997-04-01

    The application of neutrons to the study of structure/property relationships in organic non-linear optical materials (NLOs) is described. In particular, charge-transfer effects and intermolecular interactions are investigated. Charge-transfer effects are studied by charge-density analysis and an example of one such investigation is given. The study of intermolecular interactions concentrates on the effects of hydrogen-bonding and an example is given of two structurally similar molecules with very disparate NLO properties, as a result of different types of hydrogen-bonding. (author). 3 refs.

  12. Magnetodynamic non-linearity of electric properties of uncompensated metals

    International Nuclear Information System (INIS)

    Sobol', V.R.; Mazurenko, O.N.

    2001-01-01

    Magnetodynamic non-linearity of electric properties of normal metals is investigated both experimentally and analytically provided that the drift of charge carriers of high density in crossed electric and magnetic fields results in generation of a self current field. The measurements were made on high purity polycrystalline aluminium cylindrical conductors under the action of the magnetic field, coaxial the sample axis, on the radial current. The electric potential and its nonlinear correction are determined in a wide range of energy dissipation values up to the levels corresponding to the crisis of liquid helium boiling. In the approximation of contribution additivity to the resistive effect of both the external and self magnetic field agreement between the experimental data and the results calculated using the macroscopic field equations is attained. The problems of magnetic energy concentration for cylindrical conductors is discussed in the approximation of long and short solenoids

  13. Causal properties of nonlinear gravitational waves in modified gravity

    Science.gov (United States)

    Suvorov, Arthur George; Melatos, Andrew

    2017-09-01

    Some exact, nonlinear, vacuum gravitational wave solutions are derived for certain polynomial f (R ) gravities. We show that the boundaries of the gravitational domain of dependence, associated with events in polynomial f (R ) gravity, are not null as they are in general relativity. The implication is that electromagnetic and gravitational causality separate into distinct notions in modified gravity, which may have observable astrophysical consequences. The linear theory predicts that tachyonic instabilities occur, when the quadratic coefficient a2 of the Taylor expansion of f (R ) is negative, while the exact, nonlinear, cylindrical wave solutions presented here can be superluminal for all values of a2. Anisotropic solutions are found, whose wave fronts trace out time- or spacelike hypersurfaces with complicated geometric properties. We show that the solutions exist in f (R ) theories that are consistent with Solar System and pulsar timing experiments.

  14. Gravitational Instability of Cylindrical Viscoelastic Medium ...

    Indian Academy of Sciences (India)

    similar to that of viscoelastic fluid where both properties work together. They also ... cylindrical gravitational waves provides a strong motivation in this regard. .... which represents the solenoidal character of the magnetic field and the total stress.

  15. A Thermodynamic Theory Of Solid Viscoelasticity. Part 1: Linear Viscoelasticity.

    Science.gov (United States)

    Freed, Alan D.; Leonov, Arkady I.

    2002-01-01

    The present series of three consecutive papers develops a general theory for linear and finite solid viscoelasticity. Because the most important object for nonlinear studies are rubber-like materials, the general approach is specified in a form convenient for solving problems important for many industries that involve rubber-like materials. General linear and nonlinear theories for non-isothermal deformations of viscoelastic solids are developed based on the quasi-linear approach of non-equilibrium thermodynamics. In this, the first paper of the series, we analyze non-isothermal linear viscoelasticity, which is applicable in a range of small strains not only to all synthetic polymers and bio-polymers but also to some non-polymeric materials. Although the linear case seems to be well developed, there still are some reasons to implement a thermodynamic derivation of constitutive equations for solid-like, non-isothermal, linear viscoelasticity. The most important is the thermodynamic modeling of thermo-rheological complexity , i.e. different temperature dependences of relaxation parameters in various parts of relaxation spectrum. A special structure of interaction matrices is established for different physical mechanisms contributed to the normal relaxation modes. This structure seems to be in accord with observations, and creates a simple mathematical framework for both continuum and molecular theories of the thermo-rheological complex relaxation phenomena. Finally, a unified approach is briefly discussed that, in principle, allows combining both the long time (discrete) and short time (continuous) descriptions of relaxation behaviors for polymers in the rubbery and glassy regions.

  16. Assisted heterogeneous multinucleation and bubble growth in semicrystalline ethylene-vinyl acetate copolymer/expanded graphite nanocomposite foams: Control of morphology and viscoelastic properties

    Directory of Open Access Journals (Sweden)

    O. Yousefzade

    2015-10-01

    Full Text Available Nanocomposite foams of ethylene-vinyl acetate copolymer (EVA reinforced by expanded graphite (EG were prepared using supercritical nitrogen in batch foaming process. Effects of EG particle size, crosslinking of EVA chains and foaming temperature on the cell morphology and foam viscoelastic properties were investigated. EG sheet surface interestingly provide multiple heterogeneous nucleation sites for bubbles. This role is considerably intensified by incorporating lower loadings of EG with higher aspect ratio. The amorphous and non-crosslinked domains of EVA matrix constitute denser bubble areas. Higher void fraction and more uniform cell structure is achieved for non-crosslinked EVA/EG nanocomposites foamed at higher temperatures. With regard to the structural variation, the void fraction of foam samples decreases with increasing the EG content. Storage and loss moduli were analyzed to study the viscoelastic properties of nanocomposite foams. Surprisingly, the foaming process of EVA results in a drastic reduction in loss and storage moduli regardless of whether the thermoplastic matrix contains EG nanofiller or not. For the EVA/EG foams with the same composition, the nanocomposite having higher void fraction shows relatively lower loss modulus and more restricted molecular movements. The study findings have verified that the dynamics of polymer chains varies after foaming EVA matrix in the presence of EG.

  17. DIFFERENTIAL EQUATION SIMULATION IN CALCULATION OF LATERAL AND TRANSVERSE-LONGITUDINAL BENDING OF FRAME STRUCTURES WITHOUT AND WITH DUE ACCOUNT OF VISCOELASTIC MATERIAL PROPERTIES

    Directory of Open Access Journals (Sweden)

    V. M. Ovsianko

    2012-01-01

    Full Text Available The paper reveals a brand-new direction in simulation of frame and continual structures while calculating static and dynamic loads and stability.  An electronic model has been synthesized  for an investigated object and then it has been analyzed not with the help of  specialized analog computing techniques but by means of high-performance software package for electronic circuit calculation using a personal computer.The given paper contains exact algebraic equations corresponding to differential equations for lateral bending calculation of frame structures without and with due account of viscoelastic material properties in compliance with the Kelvin model.The exact algebraic equation for a beam on elastic supports (or elastic Winkler foundation has been derived for quartic differential equation.The paper presents a number of exact algebraic equations which are equivalent to differential equations for transverse-longitudinal bending calculation of frame structures without and with due account of viscoelastic material properties when lateral and longitudinal loads are applied in the form of  impulses with any periods of their duration and any interchangeability. 

  18. Frequency Response of Synthetic Vocal Fold Models with Linear and Nonlinear Material Properties

    Science.gov (United States)

    Shaw, Stephanie M.; Thomson, Scott L.; Dromey, Christopher; Smith, Simeon

    2012-01-01

    Purpose: The purpose of this study was to create synthetic vocal fold models with nonlinear stress-strain properties and to investigate the effect of linear versus nonlinear material properties on fundamental frequency (F[subscript 0]) during anterior-posterior stretching. Method: Three materially linear and 3 materially nonlinear models were…

  19. Linear Viscoelasticity, Reptation, Chain Stretching and Constraint Release

    DEFF Research Database (Denmark)

    Neergaard, Jesper; Schieber, Jay D.; Venerus, David C.

    2000-01-01

    A recently proposed self-consistent reptation model - alreadysuccessful at describing highly nonlinear shearing flows of manytypes using no adjustable parameters - is used here to interpretthe linear viscoelasticity of the same entangled polystyrenesolution. Using standard techniques, a relaxatio...

  20. Viscoelastic nanoscale properties of cuticle contribute to the high-pass properties of spider vibration receptor (Cupiennius salei Keys)

    OpenAIRE

    McConney, Michael E; Schaber, Clemens F; Julian, Michael D; Barth, Friedrich G; Tsukruk, Vladimir V

    2007-01-01

    Atomic force microscopy (AFM) and surface force spectroscopy were applied in live spiders to their joint pad material located distal of the metatarsal lyriform organs, which are highly sensitive vibration sensors. The surface topography of the material is sufficiently smooth to probe the local nanomechanical properties with nanometre elastic deflections. Nanoscale loads were applied in the proximad direction on the distal joint region simulating the natural stimulus situation. The force curve...

  1. Nonlinear electrical properties of Si three-terminal junction devices

    DEFF Research Database (Denmark)

    Fantao, Meng; Jie, Sun; Graczyk, Mariusz

    2010-01-01

    This letter reports on the realization and characterization of silicon three-terminal junction devices made in a silicon-on-insulator wafer. Room temperature electrical measurements show that the fabricated devices exhibit pronounced nonlinear electrical properties inherent to ballistic electron...... transport in a three-terminal ballistic junction (TBJ) device. The results show that room temperature functional TBJ devices can be realized in a semiconductor material other than high-mobility III-V semiconductor heterostructures and provide a simple design principle for compact silicon devices...

  2. Nonclassical properties of a contradirectional nonlinear optical coupler

    Energy Technology Data Exchange (ETDEWEB)

    Thapliyal, Kishore [Jaypee Institute of Information Technology, A-10, Sector-62, Noida, UP-201307 (India); Pathak, Anirban, E-mail: anirban.pathak@gmail.com [Jaypee Institute of Information Technology, A-10, Sector-62, Noida, UP-201307 (India); RCPTM, Joint Laboratory of Optics of Palacky University and Institute of Physics of Academy of Science of the Czech Republic, Faculty of Science, Palacky University, 17. listopadu 12, 771 46 Olomouc (Czech Republic); Sen, Biswajit [Department of Physics, Vidyasagar Teachers' Training College, Midnapore 721101 (India); Perřina, Jan [RCPTM, Joint Laboratory of Optics of Palacky University and Institute of Physics of Academy of Science of the Czech Republic, Faculty of Science, Palacky University, 17. listopadu 12, 771 46 Olomouc (Czech Republic); Department of Optics, Palacky University, 17. listopadu 12, 771 46 Olomouc (Czech Republic)

    2014-10-24

    We investigate the nonclassical properties of output fields propagated through a contradirectional asymmetric nonlinear optical coupler consisting of a linear waveguide and a nonlinear (quadratic) waveguide operated by second harmonic generation. In contrast to the earlier results, all the initial fields are considered weak and a completely quantum-mechanical model is used here to describe the system. Perturbative solutions of Heisenberg's equations of motion for various field modes are obtained using Sen–Mandal technique. Obtained solutions are subsequently used to show the existence of single-mode and intermodal squeezing, single-mode and intermodal antibunching, two-mode and multi-mode entanglement in the output of contradirectional asymmetric nonlinear optical coupler. Further, existence of higher order nonclassicality is also established by showing the existence of higher order antibunching, higher order squeezing and higher order entanglement. Variation of observed nonclassical characters with different coupling constants and phase mismatch is discussed. - Highlights: • Nonclassicalities in fields propagating through a directional coupler is studied. • Completely quantum-mechanical description of the coupler is provided. • Analytic solutions of Heisenberg equations of motion for various modes are obtained. • Existence of lower order and higher order entanglement is shown. • Variation of nonclassicalities with phase-mismatch and coupling constants is studied.

  3. Nonlinear Quantum Optical Springs and Their Nonclassical Properties

    International Nuclear Information System (INIS)

    Faghihi, M.J.; Tavassoly, M.K.

    2011-01-01

    The original idea of quantum optical spring arises from the requirement of quantization of the frequency of oscillations in the Hamiltonian of harmonic oscillator. This purpose is achieved by considering a spring whose constant (and so its frequency) depends on the quantum states of another system. Recently, it is realized that by the assumption of frequency modulation of ω to ω√1+μa † a the mentioned idea can be established. In the present paper, we generalize the approach of quantum optical spring with particular attention to the dependence of frequency to the intensity of radiation field that naturally observes in the nonlinear coherent states, from which we arrive at a physical system has been called by us as nonlinear quantum optical spring. Then, after the introduction of the generalized Hamiltonian of nonlinear quantum optical spring and it's solution, we will investigate the nonclassical properties of the obtained states. Specially, typical collapse and revival in the distribution functions and squeezing parameters, as particular quantum features, will be revealed. (electromagnetism, optics, acoustics, heat transfer, classical mechanics, and fluid dynamics)

  4. Numerical study of propagation properties of surface plasmon polaritons in nonlinear media

    KAUST Repository

    Sagor, Rakibul Hasan; Ghulam Saber, Md.; Alsunaidi, Mohammad

    2016-01-01

    We present a time-domain algorithm for simulating nonlinear propagation of surface plasmon polaritons (SPPs) in chalcogenide glass. Due to the high non-linearity property and strong dispersion and confinement chalcogenide glasses are widely known

  5. Effect of enzymatic hydrolysis of starch on pasting, rheological and viscoelastic properties of milk-barnyard millet (Echinochloa frumentacea) blends meant for spray drying.

    Science.gov (United States)

    Kumar, P Arun; Pushpadass, Heartwin A; Franklin, Magdaline Eljeeva Emerald; Simha, H V Vikram; Nath, B Surendra

    2016-10-01

    The influence of enzymatic hydrolysis of starch on the pasting properties of barnyard millet was studied using a rheometer. The effects of blending hydrolyzed barnyard millet wort with milk at different ratios (0:1, 1:1, 1:1.5 and 1:2) on flow and viscoelastic behavior were investigated. From the pasting curves, it was evident that enzymatically-hydrolyzed starch did not exhibit typical pasting characteristics expected of normal starch. The Herschel-Bulkley model fitted well to the flow behaviour data, with coefficient of determination (R(2)) ranging from 0.942 to 0.988. All milk-wort blends demonstrated varying degree of shear thinning with flow behavior index (n) ranging from 0.252 to 0.647. Stress-strain data revealed that 1:1 blend of milk to wort had the highest storage modulus (7.09-20.06Pa) and an elastically-dominant behavior (phase angle <45°) over the tested frequency range. The crossover point of G' and G" shifted to higher frequencies with increasing wort content. From the flow and viscoelastic behavior, it was concluded that the 1:1 blend of milk to wort would have least phase separation and better flowability during spray drying. Copyright © 2016 Elsevier B.V. All rights reserved.

  6. Nonlinear Optical Properties of Aluminum Doped Zinc Oxide

    Science.gov (United States)

    Otieno, Calford O.

    Nonlinear optical (NLO) materials are crucial to future progress in industrial and technological applications that involve intense light-matter interaction. While ZnO-related materials are known to possess good NLO properties, existing results on ZnO and AZO (Al-doped ZnO) are mostly available at a single wavelength or limited ranges. Therefore, NLO dispersions (wavelength dependences) are not entirely studied, especially at longer wavelengths far below the bandgap. It is important to explore wavelength dependences since doping can induce a drastic change in the NLO responses at varied spectral ranges via doping-induced subgap-state contributions. We present results of our studies on nonlinear harmonic generation from our samples, which include 1) second harmonic generation and 2) third harmonic generation precisely characterized by Maker fringes as a function of both Al doping and wavelength. We exhaustively discuss the possible cause for the modified optical nonlinearities observed in our AZO thin films and give detailed comparisons of our observations with the previous studies. We also present the results of open- and close-aperture Z-scans to characterize the two-photon absorption coefficient (TPA) and the nonlinear refractive index (NLR), respectively, of the AZO films. There was no clearcut evidence of monotonic dependence of TPA and NLR on doping. This presumably indicates that the overall effect is nontrivial and should be understood in terms of combined effects of bandgap shift and crystallinity upon varying the doping level. Most intriguingly, we found that NLR values from the closed-aperture Z-scan are very large by orders of magnitude when compared with the bulk counterparts. Similar observation was made for TPA values from the open-aperture Z-scan. To countercheck very large NLO absorption, we conducted simple intensity scan by varying the incident photon number on each sample but fixing the beam area to eliminate any possible errors related to optical

  7. Nonlinear mean field theory for nuclear matter and surface properties

    International Nuclear Information System (INIS)

    Boguta, J.; Moszkowski, S.A.

    1983-01-01

    Nuclear matter properties are studied in a nonlinear relativistic mean field theory. We determine the parameters of the model from bulk properties of symmetric nuclear matter and a reasonable value of the effective mass. In this work, we stress the nonrelativistic limit of the theory which is essentially equivalent to a Skyrme hamiltonian, and we show that most of the results can be obtained, to a good approximation, analytically. The strength of the required parameters is determined from the binding energy and density of nuclear matter and the effective nucleon mass. For realistic values of the parameters, the nonrelativistic approximation turns out to be quite satisfactory. Using reasonable values of the parameters, we can account for other key properties of nuclei, such as the spin-orbit coupling, surface energy, and diffuseness of the nuclear surface. Also the energy dependence of the nucleon-nucleus optical model is accounted for reasonably well except near the Fermi surface. It is found, in agreement with empirical results, that the Landau parameter F 0 is quite small in normal nuclear matter. Both density dependence and momentum dependence of the NN interaction, but especially the former, are important for nuclear saturation. The required scalar and vector coupling constants agree fairly well with those obtained from analyses of NN scattering phase shifts with one-boson-exchange models. The mean field theory provides a semiquantitative justification for the weak Skyrme interaction in odd states. The strength of the required nonlinear term is roughly consistent with that derived using a new version of the chiral mean field theory in which the vector mass as well as the nucleon mass is generated by the sigma-field. (orig.)

  8. Statistical properties of nonlinear one-dimensional wave fields

    Directory of Open Access Journals (Sweden)

    D. Chalikov

    2005-01-01

    Full Text Available A numerical model for long-term simulation of gravity surface waves is described. The model is designed as a component of a coupled Wave Boundary Layer/Sea Waves model, for investigation of small-scale dynamic and thermodynamic interactions between the ocean and atmosphere. Statistical properties of nonlinear wave fields are investigated on a basis of direct hydrodynamical modeling of 1-D potential periodic surface waves. The method is based on a nonstationary conformal surface-following coordinate transformation; this approach reduces the principal equations of potential waves to two simple evolutionary equations for the elevation and the velocity potential on the surface. The numerical scheme is based on a Fourier transform method. High accuracy was confirmed by validation of the nonstationary model against known solutions, and by comparison between the results obtained with different resolutions in the horizontal. The scheme allows reproduction of the propagation of steep Stokes waves for thousands of periods with very high accuracy. The method here developed is applied to simulation of the evolution of wave fields with large number of modes for many periods of dominant waves. The statistical characteristics of nonlinear wave fields for waves of different steepness were investigated: spectra, curtosis and skewness, dispersion relation, life time. The prime result is that wave field may be presented as a superposition of linear waves is valid only for small amplitudes. It is shown as well, that nonlinear wave fields are rather a superposition of Stokes waves not linear waves. Potential flow, free surface, conformal mapping, numerical modeling of waves, gravity waves, Stokes waves, breaking waves, freak waves, wind-wave interaction.

  9. Statistical properties of nonlinear one-dimensional wave fields

    Science.gov (United States)

    Chalikov, D.

    2005-06-01

    A numerical model for long-term simulation of gravity surface waves is described. The model is designed as a component of a coupled Wave Boundary Layer/Sea Waves model, for investigation of small-scale dynamic and thermodynamic interactions between the ocean and atmosphere. Statistical properties of nonlinear wave fields are investigated on a basis of direct hydrodynamical modeling of 1-D potential periodic surface waves. The method is based on a nonstationary conformal surface-following coordinate transformation; this approach reduces the principal equations of potential waves to two simple evolutionary equations for the elevation and the velocity potential on the surface. The numerical scheme is based on a Fourier transform method. High accuracy was confirmed by validation of the nonstationary model against known solutions, and by comparison between the results obtained with different resolutions in the horizontal. The scheme allows reproduction of the propagation of steep Stokes waves for thousands of periods with very high accuracy. The method here developed is applied to simulation of the evolution of wave fields with large number of modes for many periods of dominant waves. The statistical characteristics of nonlinear wave fields for waves of different steepness were investigated: spectra, curtosis and skewness, dispersion relation, life time. The prime result is that wave field may be presented as a superposition of linear waves is valid only for small amplitudes. It is shown as well, that nonlinear wave fields are rather a superposition of Stokes waves not linear waves. Potential flow, free surface, conformal mapping, numerical modeling of waves, gravity waves, Stokes waves, breaking waves, freak waves, wind-wave interaction.

  10. Topological and statistical properties of nonlinear force-free fields

    Science.gov (United States)

    Mangalam, A.; Prasad, A.

    2018-01-01

    We use our semi-analytic solution of the nonlinear force-free field equation to construct three-dimensional magnetic fields that are applicable to the solar corona and study their statistical properties for estimating the degree of braiding exhibited by these fields. We present a new formula for calculating the winding number and compare it with the formula for the crossing number. The comparison is shown for a toy model of two helices and for realistic cases of nonlinear force-free fields; conceptually the formulae are nearly the same but the resulting distributions calculated for a given topology can be different. We also calculate linkages, which are useful topological quantities that are independent measures of the contribution of magnetic braiding to the total free energy and relative helicity of the field. Finally, we derive new analytical bounds for the free energy and relative helicity for the field configurations in terms of the linking number. These bounds will be of utility in estimating the braided energy available for nano-flares or for eruptions.

  11. Third-order nonlinear optical properties of ADP crystal

    Science.gov (United States)

    Wang, Mengxia; Wang, Zhengping; Chai, Xiangxu; Sun, Yuxiang; Sui, Tingting; Sun, Xun; Xu, Xinguang

    2018-05-01

    By using the Z-scan method, we investigated the third-order nonlinear optical (NLO) properties of ADP crystal at different wavelengths (355, 532, and 1064 nm) and different orientations ([001], [100], [110], I and II). The experimental data were fitted by NLO theory, to give out the two photon absorption (TPA) coefficient β 2 and the nonlinear refractive index n 2. When the light source changed from a 40 ps, 1064 nm fundamental laser to a 30 ps, 355 nm third-harmonic-generation (THG) laser, the β 2 value increased about 5 times (0.2 × 10‑2 → 1 × 10‑2 cm GW‑1), and the n 2 value increased about 1.5 times (1.5 × 10‑16 → 2.2 × 10‑16 cm2 W‑1). Among all of the orientations, the [110] sample exhibits the smallest β 2, and the second smallest n 2. It indicates that this orientation and its surroundings will be the preferred directions for high-power laser applications of ADP crystal.

  12. Influence of Structure and Composition on Dynamic Viscoelastic Property of Cartilaginous Tissue: Criteria for Classification between Hyaline Cartilage and Fibrocartilage Based on Mechanical Function

    Science.gov (United States)

    Miyata, Shogo; Tateishi, Tetsuya; Furukawa, Katsuko; Ushida, Takashi

    Recently, many types of methodologies have been developed to regenerate articular cartilage. It is important to assess whether the reconstructed cartilaginous tissue has the appropriate mechanical functions to qualify as hyaline (articular) cartilage. In some cases, the reconstructed tissue may become fibrocartilage and not hyaline cartilage. In this study, we determined the dynamic viscoelastic properties of these two types of cartilage by using compression and shear tests, respectively. Hyaline cartilage specimens were harvested from the articular surface of bovine knee joints and fibrocartilage specimens were harvested from the meniscus tissue of the same. The results of this study revealed that the compressive energy dissipation of hyaline cartilage showed a strong dependence on testing frequency at low frequencies, while that of fibrocartilage did not. Therefore, the compressive energy dissipation that is indicated by the loss tangent could become the criterion for the in vitro assessment of the mechanical function of regenerated cartilage.

  13. Numerical study of propagation properties of surface plasmon polaritons in nonlinear media

    KAUST Repository

    Sagor, Rakibul Hasan

    2016-03-29

    We present a time-domain algorithm for simulating nonlinear propagation of surface plasmon polaritons (SPPs) in chalcogenide glass. Due to the high non-linearity property and strong dispersion and confinement chalcogenide glasses are widely known as ultrafast nonlinear materials. We have used the finite difference time domain (FDTD) method to develop the simulation algorithm for the current analysis. We have modeled the frequency dependent dispersion properties and third order nonlinearity property of chalcogenide glass utilizing the general polarization algorithm merged in the auxiliary differential equation (ADE) method. The propagation dynamics of the whole structure with and without third order nonlinearity property of chalcogenide glass have been simulated and the effect of nonlinearity on the propagation properties of SPP has been investigated. © 2016 EDP Sciences, SIF, Springer-Verlag Berlin Heidelberg.

  14. Complexity in modeling of residual stresses and strains during polymerization of bone cement: effects of conversion, constraint, heat transfer, and viscoelastic property changes.

    Science.gov (United States)

    Gilbert, Jeremy L

    2006-12-15

    Aseptic loosening of cemented joint prostheses remains a significant concern in orthopedic biomaterials. One possible contributor to cement loosening is the development of porosity, residual stresses, and local fracture of the cement that may arise from the in-situ polymerization of the cement. In-situ polymerization of acrylic bone cement is a complex set of interacting processes that involve polymerization reactions, heat generation and transfer, full or partial mechanical constraint, evolution of conversion- and temperature-dependent viscoelastic material properties, and thermal and conversion-driven changes in the density of the cement. Interactions between heat transfer and polymerization can lead to polymerization fronts moving through the material. Density changes during polymerization can, in the presence of mechanical constraint, lead to the development of locally high residual strain energy and residual stresses. This study models the interactions during bone cement polymerization and determines how residual stresses develop in cement and incorporates temperature and conversion-dependent viscoelastic behavior. The results show that the presence of polymerization fronts in bone cement result in locally high residual strain energies. A novel heredity integral approach is presented to track residual stresses incorporating conversion and temperature dependent material property changes. Finally, the relative contribution of thermal- and conversion-dependent strains to residual stresses is evaluated and it is found that the conversion-based strains are the major contributor to the overall behavior. This framework provides the basis for understanding the complex development of residual stresses and can be used as the basis for developing more complex models of cement behavior.

  15. Viscoelastic properties of soft gels: comparison of magnetic resonance elastography and dynamic shear testing in the shear wave regime

    Science.gov (United States)

    Okamoto, R. J.; Clayton, E. H.; Bayly, P. V.

    2011-10-01

    Magnetic resonance elastography (MRE) is used to quantify the viscoelastic shear modulus, G*, of human and animal tissues. Previously, values of G* determined by MRE have been compared to values from mechanical tests performed at lower frequencies. In this study, a novel dynamic shear test (DST) was used to measure G* of a tissue-mimicking material at higher frequencies for direct comparison to MRE. A closed-form solution, including inertial effects, was used to extract G* values from DST data obtained between 20 and 200 Hz. MRE was performed using cylindrical 'phantoms' of the same material in an overlapping frequency range of 100-400 Hz. Axial vibrations of a central rod caused radially propagating shear waves in the phantom. Displacement fields were fit to a viscoelastic form of Navier's equation using a total least-squares approach to obtain local estimates of G*. DST estimates of the storage G' (Re[G*]) and loss modulus G'' (Im[G*]) for the tissue-mimicking material increased with frequency from 0.86 to 0.97 kPa (20-200 Hz, n = 16), while MRE estimates of G' increased from 1.06 to 1.15 kPa (100-400 Hz, n = 6). The loss factor (Im[G*]/Re[G*]) also increased with frequency for both test methods: 0.06-0.14 (20-200 Hz, DST) and 0.11-0.23 (100-400 Hz, MRE). Close agreement between MRE and DST results at overlapping frequencies indicates that G* can be locally estimated with MRE over a wide frequency range. Low signal-to-noise ratio, long shear wavelengths and boundary effects were found to increase residual fitting error, reinforcing the use of an error metric to assess confidence in local parameter estimates obtained by MRE.

  16. Viscoelastic response of hydrogel materials at finite strains

    OpenAIRE

    Skovly, Martin Johannessen

    2015-01-01

    Hydrogel materials are very soft materials consisting of polymer networks and solvent molecules. The materials may exhibit large volume changes depending on its external chemical and mechanical environment and have viscoelastic properties which is common for many polymeric materials. In order to model the material response with the finite element method, a hydrogel constitutive model have been combined with finite viscoelastic theory and the resulting viscoelastic hydrogel constitutive model ...

  17. Influence of Chemical Extraction on Rheological Behavior, Viscoelastic Properties and Functional Characteristics of Natural Heteropolysaccharide/Protein Polymer from Durio zibethinus Seed

    Directory of Open Access Journals (Sweden)

    Hamed Mirhosseini

    2012-11-01

    Full Text Available In recent years, the demand for a natural plant-based polymer with potential functions from plant sources has increased considerably. The main objective of the current study was to study the effect of chemical extraction conditions on the rheological and functional properties of the heteropolysaccharide/protein biopolymer from durian (Durio zibethinus seed. The efficiency of different extraction conditions was determined by assessing the extraction yield, protein content, solubility, rheological properties and viscoelastic behavior of the natural polymer from durian seed. The present study revealed that the soaking process had a more significant (p < 0.05 effect than the decolorizing process on the rheological and functional properties of the natural polymer. The considerable changes in the rheological and functional properties of the natural polymer could be due to the significant (p < 0.05 effect of the chemical extraction variables on the protein fraction present in the molecular structure of the natural polymer from durian seed. The natural polymer from durian seed had a more elastic (or gel like behavior compared to the viscous (liquid like behavior at low frequency. The present study revealed that the natural heteropolysaccharide/protein polymer from durian seed had a relatively low solubility ranging from 9.1% to 36.0%. This might be due to the presence of impurities, insoluble matter and large particles present in the chemical structure of the natural polymer from durian seed.

  18. Voltage-Induced Nonlinear Conduction Properties of Epoxy Resin/Micron-Silver Particles Composites

    Science.gov (United States)

    Qu, Zhaoming; Lu, Pin; Yuan, Yang; Wang, Qingguo

    2018-01-01

    The nonlinear conduction properties of epoxy resin (ER)/micron-silver particles (MP) composites were investigated. Under sufficient high intensity applied constant voltage, the obvious nonlinear conduction properties of the samples with volume fraction 25% were found. With increments in the voltage, the conductive switching effect was observed. The nonlinear conduction mechanism of the ER/MP composites under high applied voltages could be attributed to the electrical current conducted via discrete paths of conductive particles induced by the electric field. The test results show that the ER/MP composites with nonlinear conduction properties are of great potential application in electromagnetic protection of electron devices and systems.

  19. Analysis of nonlinear optical properties in donor–acceptor materials

    Energy Technology Data Exchange (ETDEWEB)

    Day, Paul N. [Air Force Research Laboratory, Wright-Patterson Air Force Base, Ohio 45433 (United States); General Dynamics Information Technology, Inc., Dayton, Ohio 45431 (United States); Pachter, Ruth [Air Force Research Laboratory, Wright-Patterson Air Force Base, Ohio 45433 (United States); Nguyen, Kiet A. [Air Force Research Laboratory, Wright-Patterson Air Force Base, Ohio 45433 (United States); UES, Inc., Dayton, Ohio 45432 (United States)

    2014-05-14

    Time-dependent density functional theory has been used to calculate nonlinear optical (NLO) properties, including the first and second hyperpolarizabilities as well as the two-photon absorption cross-section, for the donor-acceptor molecules p-nitroaniline and dimethylamino nitrostilbene, and for respective materials attached to a gold dimer. The CAMB3LYP, B3LYP, PBE0, and PBE exchange-correlation functionals all had fair but variable performance when compared to higher-level theory and to experiment. The CAMB3LYP functional had the best performance on these compounds of the functionals tested. However, our comprehensive analysis has shown that quantitative prediction of hyperpolarizabilities is still a challenge, hampered by inadequate functionals, basis sets, and solvation models, requiring further experimental characterization. Attachment of the Au{sub 2}S group to molecules already known for their relatively large NLO properties was found to further enhance the response. While our calculations show a modest enhancement for the first hyperpolarizability, the enhancement of the second hyperpolarizability is predicted to be more than an order of magnitude.

  20. A Scanning Hologram Recorded by Phase Conjugate Property of Nonlinear Crystals

    DEFF Research Database (Denmark)

    Zi-Liang, Ping; Dalsgaard, Erik

    1996-01-01

    A methode of recording a scanning hologram with phase conjugate property of nonlinear crystal is provided. The principle of recording, setup and experiments are given.......A methode of recording a scanning hologram with phase conjugate property of nonlinear crystal is provided. The principle of recording, setup and experiments are given....

  1. Implementation of viscoelastic Hopkinson bars

    Directory of Open Access Journals (Sweden)

    Govender R.

    2012-08-01

    Full Text Available Knowledge of the properties of soft, viscoelastic materials at high strain rates are important in furthering our understanding of their role during blast or impact events. Testing these low impedance materials using a metallic split Hopkinson pressure bar setup results in poor signal to noise ratios due to impedance mismatching. These difficulties are overcome by using polymeric Hopkinson bars. Conventional Hopkinson bar analysis cannot be used on the polymeric bars due to the viscoelastic nature of the bar material. Implementing polymeric Hopkinson bars requires characterization of the viscoelastic properties of the material used. In this paper, 30 mm diameter Polymethyl Methacrylate bars are used as Hopkinson pressure bars. This testing technique is applied to polymeric foam called Divinycell H80 and H200. Although there is a large body of of literature containing compressive data, this rarely deals with strain rates above 250s−1 which becomes increasingly important when looking at the design of composite structures where energy absorption during impact events is high on the list of priorities. Testing of polymeric foams at high strain rates allows for the development of better constitutive models.

  2. Nonlinear Changes in Soil Properties and Their Impact on Ecosystems

    Science.gov (United States)

    Chadwick, O. A.; Chorover, J. D.

    2001-12-01

    Soils are open systems that act as a membrane at Earth's surface. Water and dissolved acids are the main materials transferred into soils, whereas water and lithogenic solutes dominate the output with the net result being depletion of rock forming constituents such as silica and base cations that are also ecosystem nutrients. The time-dependent coupling of water flux and chemical reactions determines the nature of the colloidal phase that is responsible for nutrient retention. Pedogenesis is a biogeochemical process that is constrained by thermodynamics, but still maintains considerable flexibility as a result of parallel reaction kinetics and a spatially heterogeneous matrix. In the open system, there are many processes that are governed by nonlinear response to changes in environmental variables and/or internal soil properties. From a thermodynamic perspective, the chemistry of pedogenesis is characterized by a number of thresholds. Simultaneous acid-base, ion exchange, redox and mineral transformation reactions interact to determine the direction and rate of change. Over time, the reaction of atmospheric acids with soil bases changes the acid neutralizing capacity of soil to an extent that is controlled by the prevailing buffering reactions. The amount of buffering reaction and effect on pH depend on the nature of the reactive species, their relative amounts, and their respective rates of reaction. Ion exchange and surface complexation reactions consume protons in the short term but long-term buffering derives from mineral weathering. The nature of the governing reactions is such that soils are well buffered to pH change in the alkaline and acid regions but far less so in the neutral to slightly acid zones. In an analogous fashion, organic matter may drive oxidation-reduction processes through a stepwise consumption of electron acceptors (thereby producing thresholds). Mineralogical change tends to occur in a serial, irreversible fashion that, under favorable

  3. Large deflection of viscoelastic beams using fractional derivative model

    International Nuclear Information System (INIS)

    Bahranini, Seyed Masoud Sotoodeh; Eghtesad, Mohammad; Ghavanloo, Esmaeal; Farid, Mehrdad

    2013-01-01

    This paper deals with large deflection of viscoelastic beams using a fractional derivative model. For this purpose, a nonlinear finite element formulation of viscoelastic beams in conjunction with the fractional derivative constitutive equations has been developed. The four-parameter fractional derivative model has been used to describe the constitutive equations. The deflected configuration for a uniform beam with different boundary conditions and loads is presented. The effect of the order of fractional derivative on the large deflection of the cantilever viscoelastic beam, is investigated after 10, 100, and 1000 hours. The main contribution of this paper is finite element implementation for nonlinear analysis of viscoelastic fractional model using the storage of both strain and stress histories. The validity of the present analysis is confirmed by comparing the results with those found in the literature.

  4. Viscoelastic material inversion using Sierra-SD and ROL

    Energy Technology Data Exchange (ETDEWEB)

    Walsh, Timothy [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Aquino, Wilkins [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Ridzal, Denis [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Kouri, Drew Philip [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); van Bloemen Waanders, Bart Gustaaf [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Urbina, Angel [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2014-11-01

    In this report we derive frequency-domain methods for inverse characterization of the constitutive parameters of viscoelastic materials. The inverse problem is cast in a PDE-constrained optimization framework with efficient computation of gradients and Hessian vector products through matrix free operations. The abstract optimization operators for first and second derivatives are derived from first principles. Various methods from the Rapid Optimization Library (ROL) are tested on the viscoelastic inversion problem. The methods described herein are applied to compute the viscoelastic bulk and shear moduli of a foam block model, which was recently used in experimental testing for viscoelastic property characterization.

  5. The influence of time dependent flight and maneuver velocities and elastic or viscoelastic flexibilities on aerodynamic and stability derivatives

    Energy Technology Data Exchange (ETDEWEB)

    Cochrane, Alexander P. [Aerospace Engineering Department, University of Glasgow, University Avenue, Glasgow, Lanarkshire (United Kingdom); Merrett, Craig G. [Mechanical and Aerospace Engineering Department, Carleton Univ., 1125 Col. By Dr., Ottawa, ON (Canada); Hilton, Harry H. [Aerospace Engineering Department in the College of Engineering and Private Sector Program Division at the National Center for Supercomputing Applications, University of Illinois at Urbana-Champaign, 104 South Wright Street, Urbana, IL 61801 (United States)

    2014-12-10

    which control reversal takes place (V{sub REV}{sup E}). Since elastic formulations constitute viscoelastic initial conditions, viscoelastic reversal may occur at speeds V{sub REV<}{sup ≧}V{sub REV}{sup E}, but furthermore does so in time at 0 < t{sub REV} ≤ ∞. This paper reports on analytical analyses and simulations of the effects of flexibility and time dependent material properties (viscoelasticity) on aerodynamic derivatives and on lateral, longitudinal, directional and spin stability derivatives. Cases of both constant and variable flight and maneuver velocities are considered. Analytical results for maneuvers involving constant and time dependent rolling velocities are analyzed, discussed and evaluated. The relationships between rolling velocity p and aileron angular displacement β as well as control effectiveness are analyzed and discussed in detail for elastic and viscoelastic wings. Such analyses establish the roll effectiveness derivatives (∂[p(t)])/(V{sub ∞}∂β(t)) . Similar studies involving other stability and aerodynamic derivatives are also undertaken. The influence of the twin effects of viscoelastic and elastic materials and of variable flight, rolling, pitching and yawing velocities on longitudinal, lateral and directional are also investigated. Variable flight velocities, encountered during maneuvers, render the usually linear problem at constant velocities into a nonlinear one.

  6. The influence of time dependent flight and maneuver velocities and elastic or viscoelastic flexibilities on aerodynamic and stability derivatives

    International Nuclear Information System (INIS)

    Cochrane, Alexander P.; Merrett, Craig G.; Hilton, Harry H.

    2014-01-01

    (V REV E ). Since elastic formulations constitute viscoelastic initial conditions, viscoelastic reversal may occur at speeds V REV< ≧ V REV E , but furthermore does so in time at 0 < t REV ≤ ∞. This paper reports on analytical analyses and simulations of the effects of flexibility and time dependent material properties (viscoelasticity) on aerodynamic derivatives and on lateral, longitudinal, directional and spin stability derivatives. Cases of both constant and variable flight and maneuver velocities are considered. Analytical results for maneuvers involving constant and time dependent rolling velocities are analyzed, discussed and evaluated. The relationships between rolling velocity p and aileron angular displacement β as well as control effectiveness are analyzed and discussed in detail for elastic and viscoelastic wings. Such analyses establish the roll effectiveness derivatives (∂[p(t)])/(V ∞ ∂β(t)) . Similar studies involving other stability and aerodynamic derivatives are also undertaken. The influence of the twin effects of viscoelastic and elastic materials and of variable flight, rolling, pitching and yawing velocities on longitudinal, lateral and directional are also investigated. Variable flight velocities, encountered during maneuvers, render the usually linear problem at constant velocities into a nonlinear one

  7. Feasibility of Residual Stress Nondestructive Estimation Using the Nonlinear Property of Critical Refraction Longitudinal Wave

    Directory of Open Access Journals (Sweden)

    Yu-Hua Zhang

    2017-01-01

    Full Text Available Residual stress has significant influence on the performance of mechanical components, and the nondestructive estimation of residual stress is always a difficult problem. This study applies the relative nonlinear coefficient of critical refraction longitudinal (LCR wave to nondestructively characterize the stress state of materials; the feasibility of residual stress estimation using the nonlinear property of LCR wave is verified. The nonlinear ultrasonic measurements based on LCR wave are conducted on components with known stress state to calculate the relative nonlinear coefficient. Experimental results indicate that the relative nonlinear coefficient monotonically increases with prestress and the increment of relative nonlinear coefficient is about 80%, while the wave velocity only decreases about 0.2%. The sensitivity of the relative nonlinear coefficient for stress is much higher than wave velocity. Furthermore, the dependence between the relative nonlinear coefficient and deformation state of components is found. The stress detection resolution based on the nonlinear property of LCR wave is 10 MPa, which has higher resolution than wave velocity. These results demonstrate that the nonlinear property of LCR wave is more suitable for stress characterization than wave velocity, and this quantitative information could be used for residual stress estimation.

  8. Use of high-temperature, high-torque rheometry to study the viscoelastic properties of coal during carbonization

    Energy Technology Data Exchange (ETDEWEB)

    Diaz, M.C.; Duffy, J.J.; Snape, C.E.; Steel, K.M. [University of Nottingham, Nottingham (United Kingdom)

    2007-09-15

    When coal is heated in the absence of oxygen it softens at approximately 400 degrees C, becomes viscoelastic, and volatiles are driven off. With further heating, the viscous mass reaches a minimum viscosity in the range of 10{sup 3}-10{sup 5} Pa s and then begins to resolidify. A high-torque, high-temperature, controlled-strain rheometer with parallel plates has been used to study the theology during this process. Under shear, the viscosity of the softening mass decreases with increasing shear rate. During resolidification, the viscosity increases as C-C bond formation and physical interactions gives rise to an aromatic network, but, under shear, the network breaks apart and flows. This is viewed as a yielding of the structure. The higher the shear rate, the earlier the yielding occurs, such that if the shear rate is low enough, the structure is able to build. Also, further into resolidification lower shear rates are able to break the structure. It is proposed that resolidification occurs through the formation of aromatic clusters that grow and become crosslinked by non-covalent interactions. As the clusters grow, the amount of liquid surrounding them decreases and it is thought that the non-covalent interactions between clusters and liquid could decrease and the ability of growing clusters to move past each other increases, which would explain the weakening of the structure under shear. This work is part of a program of work aimed at attaining a greater understanding of microstructural changes taking place during carbonization for different coals, in order to understand the mechanisms that give rise to good quality cokes and coke oven problems such as excessive wall pressure.

  9. Pulse splitting in nonlinear media with anisotropic dispersion properties

    DEFF Research Database (Denmark)

    Bergé, L.; Juul Rasmussen, J.; Schmidt, M.R.

    1998-01-01

    The nonlinear self-focusing of beams in media with anisotropic (mix-signed) dispersion is investigated. Theoretical predictions employing virial-type arguments and self-similar techniques suggest that a pulse propagating in a nonlinear medium with anisotropic dispersion will not collapse...

  10. Characterization of the Nonlinear Viscoelastic and Adhesive Properties of Polyurea and Characterization of Polyurea-Clad Metallic Structures

    Science.gov (United States)

    2009-10-14

    abrasive resistance, insensitivity to solvents, and low or zero volatile organic compounds) ( Takas , 2004). These features are superior to most, if...of a glass/epoxy interface. Journal of Applied Mechanics 65(1), 25-29. Takas . T.P., 2004. 100% solids aliphatic polyurea coatings for direct-metal

  11. Nonlinear optical properties of colloidal silver nanoparticles produced by laser ablation in liquids

    International Nuclear Information System (INIS)

    Karavanskii, V A; Krasovskii, V I; Ivanchenko, P V; Simakin, Aleksandr V

    2004-01-01

    The optical and nonlinear optical properties of colloidal solutions of silver obtained by laser ablation in water and ethanol are studied. It is shown that freshly prepared colloids experience a full or partial sedimentation by changing their nonlinear optical properties. Aqueous colloids undergo a partial sedimentation and their nonlinear optical absorption changes to nonlinear optical transmission. The obtained results are interpreted using the Drude model for metal particles taking the particle size into account and can be explained by the sedimentation of larger silver particles accompanied by the formation of a stable colloid containing silver nanoparticles with a tentatively silver oxide shell. The characteristic size of particles forming such a stable colloid is determined and its optical nonlinearity is estimated. (nonlinear optical phenomena)

  12. Numerical studies on the electromagnetic properties of the nonlinear Lorentz Computational model for the dielectric media

    International Nuclear Information System (INIS)

    Abe, H.; Okuda, H.

    1994-06-01

    We study linear and nonlinear properties of a new computer simulation model developed to study the propagation of electromagnetic waves in a dielectric medium in the linear and nonlinear regimes. The model is constructed by combining a microscopic model used in the semi-classical approximation for the dielectric media and the particle model developed for the plasma simulations. It is shown that the model may be useful for studying linear and nonlinear wave propagation in the dielectric media

  13. Nonlinear acoustic properties of the B95 aluminum alloy and the B95/nanodiamond composite

    Science.gov (United States)

    Korobov, A. I.; Prokhorov, V. M.

    2016-11-01

    Research results for the nonlinear acoustic properties of the B95 polycrystalline aluminum alloy and the B95/nanodiamond composite have been described. The nonlinear properties of the alloys have been studied by the spectral method that measures the efficiency of generation of the second harmonic of a bulk acoustic wave at a frequency of 2 f = 10 MHz in the field of a finite-amplitude longitudinal acoustic wave at a frequency of f = 5 MHz. The results derived by this method have been compared with the results of studies of the nonlinear acoustic properties of the test alloys using the Thurston-Brugger quasi-static method.

  14. Field-enhanced nonlinear optical properties of organic nanofibers

    DEFF Research Database (Denmark)

    Kostiučenko, Oksana; Fiutowski, Jacek; Brewer, Jonathan R.

    2014-01-01

    Second harmonic generation in nonlinearly optically active organic nanofibers, generated via self-assembled surface growth from nonsymmetrically functionalized para-quarterphenylene (CNHP4) molecules, has been investigated. After the growth on mica templates, nanofibers have been transferred onto...

  15. Integrating viscoelastic mass spring dampers into position-based dynamics to simulate soft tissue deformation in real time.

    Science.gov (United States)

    Xu, Lang; Lu, Yuhua; Liu, Qian

    2018-02-01

    We propose a novel method to simulate soft tissue deformation for virtual surgery applications. The method considers the mechanical properties of soft tissue, such as its viscoelasticity, nonlinearity and incompressibility; its speed, stability and accuracy also meet the requirements for a surgery simulator. Modifying the traditional equation for mass spring dampers (MSD) introduces nonlinearity and viscoelasticity into the calculation of elastic force. Then, the elastic force is used in the constraint projection step for naturally reducing constraint potential. The node position is enforced by the combined spring force and constraint conservative force through Newton's second law. We conduct a comparison study of conventional MSD and position-based dynamics for our new integrating method. Our approach enables stable, fast and large step simulation by freely controlling visual effects based on nonlinearity, viscoelasticity and incompressibility. We implement a laparoscopic cholecystectomy simulator to demonstrate the practicality of our method, in which liver and gallbladder deformation can be simulated in real time. Our method is an appropriate choice for the development of real-time virtual surgery applications.

  16. Nonlinear optical properties measurement of polypyrrole -carbon nanotubes prepared by an electrochemical polymerization method

    Directory of Open Access Journals (Sweden)

    Shahriari

    2017-02-01

    Full Text Available In this work, the optical properties dependence of Multi-Walled Carbon Nanotubes (MWNT on concentration was discussed. MWNT samples were prepared in polypyrrole by an electrochemical polymerization of monomers, in the presence of different concentrations of MWNTs, using Sodium Dodecyl-Benzen-Sulfonate (SDBS as surfactant at room temperature. The nonlinear refractive and nonlinear absorbtion indices were measured using a low power CW laser beam operated at 532 nm using z-scan method. The results show that nonlinear refractive and nonlinear absorbtion indices tend to be increased with increasing the concentration of carbon nanotubes. Optical properties of  carbone nanotubes indicate that they are good candidates for nonlinear optical devices

  17. 3D Viscoelastic Traction Force Microscopy

    Science.gov (United States)

    Toyjanova, Jennet; Hannen, Erin; Bar-Kochba, Eyal; Darling, Eric M.; Henann, David L.; Franck, Christian

    2014-01-01

    Native cell-material interactions occur on materials differing in their structural composition, chemistry, and physical compliance. While the last two decades have shown the importance of traction forces during cell-material interactions, they have been almost exclusively presented on purely elastic in-vitro materials. Yet, most bodily tissue materials exhibit some level of viscoelasticity, which could play an important role in how cells sense and transduce tractions. To expand the realm of cell traction measurements and to encompass all materials from elastic to viscoelastic, this paper presents a general, and comprehensive approach for quantifying 3D cell tractions in viscoelastic materials. This methodology includes the experimental characterization of the time-dependent material properties for any viscoelastic material with the subsequent mathematical implementation of the determined material model into a 3D traction force microscopy (3D TFM) framework. Utilizing this new 3D viscoelastic TFM (3D VTFM) approach, we quantify the influence of viscosity on the overall material traction calculations and quantify the error associated with omitting time-dependent material effects, as is the case for all other TFM formulations. We anticipate that the 3D VTFM technique will open up new avenues of cell-material investigations on even more physiologically relevant time-dependent materials including collagen and fibrin gels. PMID:25170569

  18. Properties of some nonlinear Schroedinger equations motivated through information theory

    International Nuclear Information System (INIS)

    Yuan, Liew Ding; Parwani, Rajesh R

    2009-01-01

    We update our understanding of nonlinear Schroedinger equations motivated through information theory. In particular we show that a q-deformation of the basic nonlinear equation leads to a perturbative increase in the energy of a system, thus favouring the simplest q = 1 case. Furthermore the energy minimisation criterion is shown to be equivalent, at leading order, to an uncertainty maximisation argument. The special value η = 1/4 for the interpolation parameter, where leading order energy shifts vanish, implies the preservation of existing supersymmetry in nonlinearised supersymmetric quantum mechanics. Physically, η might be encoding relativistic effects.

  19. Stability properties of a general class of nonlinear dynamical systems

    Science.gov (United States)

    Gléria, I. M.; Figueiredo, A.; Rocha Filho, T. M.

    2001-05-01

    We establish sufficient conditions for the boundedness of the trajectories and the stability of the fixed points in a class of general nonlinear systems, the so-called quasi-polynomial vector fields, with the help of a natural embedding of such systems in a family of generalized Lotka-Volterra (LV) equations. A purely algebraic procedure is developed to determine such conditions. We apply our method to obtain new results for LV systems, by a reparametrization in time variable, and to study general nonlinear vector fields, originally far from the LV format.

  20. Stability properties of a general class of nonlinear dynamical systems

    Energy Technology Data Exchange (ETDEWEB)

    Gleria, I.M. [Filho Instituto de Fisica, Universidade de Brasilia, Campus Universitario Darcy Ribeiro, Brasilia (Brazil). E-mail: iram@ucb.br; Figueiredo, A. [Filho Instituto de Fisica, Universidade de Brasilia, Campus Universitario Darcy Ribeiro, Brasilia (Brazil). E-mail: annibal@helium.fis.unb.br; Rocha, T.M. [Filho Instituto de Fisica, Universidade de Brasilia, Campus Universitario Darcy Ribeiro, Brasilia (Brazil). E-mail: marciano@helium.fis.unb.br

    2001-05-04

    We establish sufficient conditions for the boundedness of the trajectories and the stability of the fixed points in a class of general nonlinear systems, the so-called quasi-polynomial vector fields, with the help of a natural embedding of such systems in a family of generalized Lotka-Volterra (LV) equations. A purely algebraic procedure is developed to determine such conditions. We apply our method to obtain new results for LV systems, by a reparametrization in time variable, and to study general nonlinear vector fields, originally far from the LV format. (author)

  1. Linear analysis using secants for materials with temperature dependent nonlinear elastic modulus and thermal expansion properties

    Science.gov (United States)

    Pepi, John W.

    2017-08-01

    Thermally induced stress is readily calculated for linear elastic material properties using Hooke's law in which, for situations where expansion is constrained, stress is proportional to the product of the material elastic modulus and its thermal strain. When material behavior is nonlinear, one needs to make use of nonlinear theory. However, we can avoid that complexity in some situations. For situations in which both elastic modulus and coefficient of thermal expansion vary with temperature, solutions can be formulated using secant properties. A theoretical approach is thus presented to calculate stresses for nonlinear, neo-Hookean, materials. This is important for high acuity optical systems undergoing large temperature extremes.

  2. Viscoelastic behavior of discrete human collagen fibrils

    DEFF Research Database (Denmark)

    Svensson, Rene; Hassenkam, Tue; P, Hansen

    2010-01-01

    Whole tendon and fibril bundles display viscoelastic behavior, but to the best of our knowledge this property has not been directly measured in single human tendon fibrils. In the present work an atomic force microscopy (AFM) approach was used for tensile testing of two human patellar tendon fibr...

  3. Experimental Viscoelastic Characterization of Corn Cob Composited ...

    African Journals Online (AJOL)

    The nature of viscoelasticity in biomateria1s and the techniques for characterizing their rheological properties were reviewed. Relaxation tests were performed with cylindrical samples of corn cob composites which were initially subjected to radial compression. It was found that a Maxwell model composed of two simple ...

  4. Topology optimization of viscoelastic rectifiers

    DEFF Research Database (Denmark)

    Jensen, Kristian Ejlebjærg; Szabo, Peter; Okkels, Fridolin

    2012-01-01

    An approach for the design of microfluidic viscoelastic rectifiers is presented based on a combination of a viscoelastic model and the method of topology optimization. This presumption free approach yields a material layout topologically different from experimentally realized rectifiers...

  5. Several Dynamical Properties for a Nonlinear Shallow Water Equation

    Directory of Open Access Journals (Sweden)

    Ls Yong

    2014-01-01

    Full Text Available A nonlinear third order dispersive shallow water equation including the Degasperis-Procesi model is investigated. The existence of weak solutions for the equation is proved in the space L1(R∩BV (R under certain assumptions. The Oleinik type estimate and L2N(R  (N is a natural number estimate for the solution are obtained.

  6. Energia total de ruptura: um teste biomecânico para avaliação de material biológico com propriedade viscoelástica não linear Total energy of rupture: a biomechanical test to evaluate non-linear viscoelastic biological material

    Directory of Open Access Journals (Sweden)

    Feng Chung Wu

    2004-12-01

    Full Text Available Objetivo: Apresentação do teste biomecânico Energia Total de Ruptura para o estudo da resistência intrínseca de material biológico com propriedade viscoelástica não-linear representado neste trabalho por segmento íntegro de cólon descendente de rato. Métodos: Implementação do teste biomecânico Energia Total de Ruptura e do Sistema de Aquisição e Análise de dados Biomecânicos - SABI 2.0. Para esse fim, foram utilizados conceitos físico-mecânicos, computacionais e biomecânicos e como corpos de teste, 15 espécimes de cólon descendente de ratos. Resultados: O teste biomecânico Energia Total de Ruptura permitiu o cálculo da energia total acumulada necessária para promover a ruptura dos corpos de prova durante os ensaios mecânicos. Por meio da automatização e gerenciamento da aquisição e análise dos dados capturados foi possível a geração de gráficos e relatórios descritivos e estatísticos. Conclusão: Fundamentado em conceitos físico-mecânicos, computacionais e biomecânicos, o teste Energia Total de Ruptura pôde proporcionar análise matemática do comportamento dos segmentos de cólon descendente de ratos durante os ensaios, demonstrando ser um possível método de medição da resistência intrínseca desse material biológico com propriedade viscoelástica não-linear.Purpose: Presentation of the Total Energy of Rupture biomechanical test to evaluate the intrinsic resistance of the rat’s left colon which presents a non-linear viscoelastic property. Methods: Implementation of Total Energy of Rupture test (ETR and the Biomechanical Data Acquisition and Analysis System (SABI 2.0 based on physic-mechanical, computational and biomechanical concepts. Fifteen specimens of Wistar adults rat’s left colon where considered for experiments. Results: Using the TER biomechanical test it was possible calculate the accumulated total energy necessary to promote the specimens rupture during the mechanical trial. It was

  7. Effect of Sodium Salicylate on the Viscoelastic Properties and Stability of Polyacrylate-Based Hydrogels for Medical Applications

    Directory of Open Access Journals (Sweden)

    Zuzana Kolarova Raskova

    2016-01-01

    Full Text Available Investigation was made into the effect exerted by the presence of sodium salicylate (0–2 wt.%, in Carbomer-based hydrogel systems, on processing conditions, rheological and antimicrobial properties in tests against Gram-positive (Staphylococcus aureus and Gram-negative (Escherichia coli bacterial strains, and examples of yeast (Candida albicans and mould (Aspergillus niger. In addition, the work presents an examination of long-term stability by means of aging over one year the given hydrogels at 8°C and 25°C. The results show that 0.5 wt.% NaSal demonstrated a noticeable effect on the hydrogel neutralization process, viscosity, and antimicrobial properties against all of the tested microorganisms. The long-term stability studies revealed that hydrogels can maintain antimicrobial activity as well as viscosity to a degree that would be sufficient for practical use.

  8. Output Feedback Stabilization with Nonlinear Predictive Control: Asymptotic properties

    Directory of Open Access Journals (Sweden)

    Lars Imsland

    2003-07-01

    Full Text Available State space based nonlinear model predictive control (NM PC needs the state for the prediction of the system behaviour. Unfortunately, for most applications, not all states are directly measurable. To recover the unmeasured states, typically a stable state observer is used. However, this implies that the stability of the closed-loop should be examined carefully, since no general nonlinear separation principle exists. Recently semi-global practical stability results for output feedback NMPC using a high-gain observer for state estimation have been established. One drawback of this result is that (in general the observer gain must be increased, if the desired set the state should converge to is made smaller. We show that under slightly stronger assumptions, not only practical stability, but also convergence of the system states and observer error to the origin for a sufficiently large but bounded observer gain can be achieved.

  9. Investigation of nonlinear optical properties of various organic materials by the Z-scan method

    Science.gov (United States)

    Ganeev, R. A.; Boltaev, G. S.; Tugushev, R. I.; Usmanov, T.

    2012-06-01

    We have studied the nonlinear optical properties of various organic materials (vegetable oil, juice, wine, cognac, Coca-Cola and Fanta drinks, Nescafé coffee, tea, gasoline, clock oil, glycerol, and polyphenyl ether) that are used in everyday life. Their nonlinearities have been studied by the Z-scan method in the near-IR and visible spectral ranges. We have shown that the majority of samples possess a nonlinear absorption; however, some of the studied materials show a strong saturated absorption and nonlinear refraction. Red wine and glycerol proved to be the most interesting materials. For these samples, we have observed a change in the sign of the nonlinear absorption with increasing laser intensity, which was attributed to the competition between two-photon absorption and saturated absorption.

  10. Measurements of nonlinear optical properties of PVDF/ZnO using Z-scan technique

    Energy Technology Data Exchange (ETDEWEB)

    Shanshool, Haider Mohammed, E-mail: haidshan62@gmail.com [Ministry of Science and Technology, Baghdad (Iraq); Yahaya, Muhammad [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, Selangor (Malaysia); Yunus, Wan Mahmood Mat [Department of Physics, Faculty of Science, University Putra Malaysia, Serdang (Malaysia); Abdullah, Ibtisam Yahya [Department of Physics, College of Science, University of Mosul, Mosul (Iraq)

    2015-10-15

    The nonlinear optical properties of ZnO nanoparticles dispersed in poly (vinylidene fluoride) (PVDF) polymer are investigated. PVDF/ZnO nanocomposites were prepared by mixing different concentrations of ZnO nanoparticles, as the filler, with PVDF, as the polymer matrix, using casting method. Acetone was used as a solvent for the polymer. FTIR spectra of the samples were analyzed thus confirming the formation of α and β phases. The absorbance spectra of the samples were obtained, thereby showing high absorption in the UV region. The linear absorption coefficient was calculated. The single-beam Z-scan technique was used to measure the nonlinear refractive index and the nonlinear absorption coefficient of the PVDF/ZnO nanocomposite samples. We observed that the nonlinear refractive index is in the order of 10{sup -13} cm{sup 2}/W with the negative sign, whereas the nonlinear absorption coefficient is in the order of 10{sup -8} cm/W. (author)

  11. A boundary integral method for a dynamic, transient mode I crack problem with viscoelastic cohesive zone

    KAUST Repository

    Leise, Tanya L.; Walton, Jay R.; Gorb, Yuliya

    2009-01-01

    interpenetration, in contrast to the usual mode I boundary conditions that assume all unloaded crack faces are stress-free. The nonlinear viscoelastic cohesive zone behavior is motivated by dynamic fracture in brittle polymers in which crack propagation

  12. Bifurcation and chaos of an axially accelerating viscoelastic beam

    International Nuclear Information System (INIS)

    Yang Xiaodong; Chen Liqun

    2005-01-01

    This paper investigates bifurcation and chaos of an axially accelerating viscoelastic beam. The Kelvin-Voigt model is adopted to constitute the material of the beam. Lagrangian strain is used to account for the beam's geometric nonlinearity. The nonlinear partial-differential equation governing transverse motion of the beam is derived from the Newton second law. The Galerkin method is applied to truncate the governing equation into a set of ordinary differential equations. By use of the Poincare map, the dynamical behavior is identified based on the numerical solutions of the ordinary differential equations. The bifurcation diagrams are presented in the case that the mean axial speed, the amplitude of speed fluctuation and the dynamic viscoelasticity is respectively varied while other parameters are fixed. The Lyapunov exponent is calculated to identify chaos. From numerical simulations, it is indicated that the periodic, quasi-periodic and chaotic motions occur in the transverse vibrations of the axially accelerating viscoelastic beam

  13. Viscoelastic Surface Waves

    Science.gov (United States)

    Borcherdt, R. D.

    2007-12-01

    General theoretical solutions for Rayleigh- and Love-Type surface waves in viscoelastic media describe physical characteristics of the surface waves in elastic as well as anelastic media with arbitrary amounts of intrinsic absorption. In contrast to corresponding physical characteristics for Rayleigh waves in elastic media, Rayleigh- Type surface waves in anelastic media demonstrate; 1) tilt of the particle motion orbit that varies with depth, and 2) amplitude and volumetric strain distributions with superimposed sinusoidal variations that decay exponentially with depth. Each characteristic is dependent on the amount of intrinsic absorption and the chosen model of viscoelasticity. Distinguishing characteristics of anelastic Love-Type surface waves include: 1) dependencies of the wave speed and absorption coefficient on the chosen model and amount of intrinsic absorption and frequency, and 2) superimposed sinusoidal amplitude variations with an exponential decay with depth. Numerical results valid for a variety of viscoelastic models provide quantitative estimates of the physical characteristics of both types of viscoelastic surface waves appropriate for interpretations pertinent to models of earth materials ranging from low-loss in the crust to moderate- and high-loss in water-saturated soils.

  14. Nonlinear optical properties of an electromagnetically induced transparency medium interacting with two quantized fields

    CERN Document Server

    Kuang-Leman; Wu Yong Shi

    2003-01-01

    We study linear and nonlinear optical properties of an electromagnetically induced transparency (EIT) medium interacting with two quantized laser fields in the adiabatic EIT case. We show that the EIT medium exhibits normal dispersion. Kerr and higher-order nonlinear refractive index coefficients are also calculated in a completely analytical form. It is indicated that the EIT medium exhibits giant resonantly enhanced nonlinearities. We discuss the response of the EIT medium to nonclassical light fields and find that the polarization vanishes when the probe laser is initially in a nonclassical state of no single-photon coherence.

  15. Nonlinear and Nonsymmetric Single-Molecule Electronic Properties Towards Molecular Information Processing.

    Science.gov (United States)

    Tamaki, Takashi; Ogawa, Takuji

    2017-09-05

    This review highlights molecular design for nonlinear and nonsymmetric single-molecule electronic properties such as rectification, negative differential resistance, and switching, which are important components of future single-molecule information processing devices. Perspectives on integrated "molecular circuits" are also provided. Nonlinear and nonsymmetric single-molecule electronics can be designed by utilizing (1) asymmetric molecular cores, (2) asymmetric anchoring groups, (3) an asymmetric junction environment, and (4) asymmetric electrode materials. This review mainly focuses on the design of molecular cores.

  16. DYNAMIC DEFORMATION THE VISCOELASTIC TWOCOMPONENT MEDIUM

    Directory of Open Access Journals (Sweden)

    V. S. Polenov

    2015-01-01

    Full Text Available Summary. In the article are scope harmonious warping of the two-component medium, one component which are represent viscoelastic medium, hereditary properties which are described by the kernel aftereffect Abel integral-differential ratio BoltzmannVolterr, while second – compressible liquid. Do a study one-dimensional case. Use motion equation of two-component medium at movement. Look determination system these equalization in the form of damped wave. Introduce dimensionless coefficient. Combined equations happen to homogeneous system with complex factor relatively waves amplitude in viscoelastic component and in fluid. As a result opening system determinant receive biquadratic equation. Elastic operator express through kernel aftereffect Abel for space Fourier. With the help transformation and symbol series biquadratic equation reduce to quadratic equation. Come to the conclusion that in two-component viscoelastic medium exist two mode sonic waves. As a result solution of quadratic equation be found description advance of waves sonic in viscoelastic two-component medium, which physical-mechanical properties represent complex parameter. Velocity determination advance of sonic waves, attenuation coefficient, mechanical loss tangent, depending on characteristic porous medium and circular frequency formulas receive. Graph dependences of description advance of waves sonic from the temperature logarithm and with the fractional parameter γ are constructed.

  17. Dynamical Properties in a Fourth-Order Nonlinear Difference Equation

    OpenAIRE

    Xianyi Li; Yunxin Chen

    2010-01-01

    The rule of trajectory structure for fourth-order nonlinear difference equation xn+1=(xan−2+xn−3)/(xan−2xn−3+1), n=0,1,2,…, where a∈[0,1) and the initial values x−3,x−2,x−1,x0∈[0,∞), is described clearly out in this paper. Mainly, the lengths of positive and negative semicycles of its nontrivial solutions are found to occur periodically with prime period 15. The rule is 4+,3−,1+,2−,2+,1−,1+, 1&#x...

  18. Influence of storage in the texture and viscoelasticity of buns of corn variety white Cariaco

    Directory of Open Access Journals (Sweden)

    José David Torres-González

    2016-09-01

    Full Text Available The objective was to determine the influence of storage time on the variation of texture and visco-elasticity of buns of corn of the white Cariaco variety. The samples were stored refrigerated at 15 °C during 15 days. Textural parameters were determined every two days, using a texture analyzer; viscoelastic properties were set by a test of relaxation and com-pression effort, adjusting the experimental data to the generalized Maxwell model. Also, to determine the model parameters described, an iterative process was performed by non-linear regression using least squares techniques damped by the Solver add-on in Excel 2013. The storage time influenced the texture profile of buns, and the increase of hardness from the eleventh day, which was attributed to moisture loss of the product during cooling. Chewiness was higher for longer storage time. Cohesiveness, adhesiveness and elasticity reported no significant differences with respect to storage time. Statistical differences were presented at initial and final relaxation speeds expressed in the Maxwell model. The experimental data were successfully fitted to the model (R2 > 0.95 which was statistically significant (p < 0.05 and the performance of the elastic module indicated that buns from the white Cariaco variety showed a characteristic behavior of a viscoelastic material, increasing its hardness during the days of storage.

  19. Viscoelastic characterization of carbon fiber-epoxy composites by creep and creep rupture tests

    International Nuclear Information System (INIS)

    Farina, Luis Claudio

    2009-01-01

    One of the main requirements for the use of fiber-reinforced polymer matrix composites in structural applications is the evaluation of their behavior during service life. The warranties of the integrity of these structural components demand a study of the time dependent behavior of these materials due to viscoelastic response of the polymeric matrix and of the countless possibilities of design configurations. In the present study, creep and creep rupture test in stress were performed in specimens of unidirectional carbon fiber-reinforced epoxy composites with fibers orientations of 60 degree and 90 degree, at temperatures of 25 and 70 degree C. The aim is the viscoelastic characterization of the material through the creep curves to some levels of constant tension during periods of 1000 h, the attainment of the creep rupture envelope by the creep rupture curves and the determination of the transition of the linear for non-linear behavior through isochronous curves. In addition, comparisons of creep compliance curves with a viscoelastic behavior prediction model based on Schapery equation were also performed. For the test, a modification was verified in the behavior of the material, regarding the resistance, stiffness and deformation, demonstrating that these properties were affected for the time and tension level, especially in work temperature above the ambient. The prediction model was capable to represent the creep behavior, however the determination of the equations terms should be considered, besides the variation of these with the applied tension and the elapsed time of test. (author)

  20. Hydrogels from feather keratin show higher viscoelastic properties and cell proliferation than those from hair and wool keratins.

    Science.gov (United States)

    Esparza, Yussef; Bandara, Nandika; Ullah, Aman; Wu, Jianping

    2018-09-01

    Hydrogel prepared from keratin shows potential applications in tissue engineering. However, the importance of the keratin sources has not been considered. The objectives of this study were to characterize and compare the rheological (storage modulus), physical (porosity, pore size, swelling capacity, and water contact angle) and in vitro cell compatibility of hydrogel scaffolds prepared from various keratin sources. Keratins were characterized by means of their molecular weight, amino acid composition, thermal and conformational properties. Hydrogels from chicken feather keratins demonstrated substantially higher storage modulus (G') than hair and wool keratin hydrogels. However, higher swelling capacity (>3000%) was determined in hair and wool over feather keratin (1500%) hydrogels. Our results suggest that small molecular weight and β-sheet conformation of feather keratin (~10 kDa) facilitated the self-assembly of rigid hydrogels through disulfide bond re-oxidation. Whereas, high molecular weight (10-75 kDa) stretchable α-helix conformation in hair and wool keratins resulted in weaker hydrogels. The cell cultures using fibroblasts showed the highest proliferation rate on chicken feather keratin hydrogel scaffolds. After 15 days of culture, partial breakdown of keratin fibers was observed. Results indicate that stiffer avian keratins can be used to fabricate more mechanically robust biomaterials than mammalian keratins. Copyright © 2018 Elsevier B.V. All rights reserved.

  1. Investigation of Thermal and Viscoelastic Properties of Polymers Relevant to Hot Melt Extrusion, IV: Affinisol™ HPMC HME Polymers.

    Science.gov (United States)

    Gupta, Simerdeep Singh; Solanki, Nayan; Serajuddin, Abu T M

    2016-02-01

    Most cellulosic polymers cannot be used as carriers for preparing solid dispersion of drugs by hot melt extrusion (HME) due to their high melt viscosity and thermal degradation at high processing temperatures. Three HME-grade hydroxypropyl methylcelluloses, namely Affinisol™ HPMC HME 15 cP, Affinisol™ HPMC HME 100 cP, and Affinisol™ HPMC HME 4 M, have recently been introduced by The Dow Chemical Co. to enable the preparation of solid dispersion at lower and more acceptable processing temperatures. In the present investigation, physicochemical properties of the new polymers relevant to HME were determined and compared with that of Kollidon(®) VA 64. Powder X-ray diffraction (PXRD), modulated differential scanning calorimetry (mDSC), thermogravimetric analysis (TGA), moisture sorption, rheology, and torque analysis by melt extrusion were applied. PXRD and mDSC showed that the Affinisol™ polymers were amorphous in nature. According to TGA, the onset of degradation for all polymers was >220°C. The Affinisol™ polymers exhibited less hygroscopicity than Kollidon(®) VA 64 and another HPMC polymer, Methocel™ K100LV. The complex viscosity profiles of the Affinisol™ polymers as a function of temperature were similar. The viscosity of the Affinisol™ polymers was highly sensitive to the shear rate applied, and unlike Kollidon(®) VA 64, the viscosity decreased drastically when the angular frequency was increased. Because of the very high shear rate encountered during melt extrusion, Affinisol™ polymers showed capability of being extruded at larger windows of processing temperatures as compared to that of Kollidon(®) VA 64.

  2. Experimental Correlation between Nonlinear Optical and Magnetotransport Properties Observed in Au-Co Thin Films

    Directory of Open Access Journals (Sweden)

    Kaida Yang

    2016-01-01

    Full Text Available Magnetic materials where at least one dimension is in the nanometer scale typically exhibit different magnetic, magnetotransport, and magnetooptical properties compared to bulk materials. Composite magnetic thin films where the matrix composition, magnetic cluster size, and overall composite film thickness can be experimentally tailored via adequate processing or growth parameters offer a viable nanoscale platform to investigate possible correlations between nonlinear magnetooptical and magnetotransport properties, since both types of properties are sensitive to the local magnetization landscape. It has been shown that the local magnetization contrast affects the nonlinear magnetooptical properties as well as the magnetotransport properties in magnetic-metal/nonmagnetic metal multilayers; thus, nanocomposite films showcase another path to investigate possible correlations between these distinct properties which may prove useful for sensing applications.

  3. Linear and Nonlinear Optical Properties of Micrometer-Scale Gold Nanoplates

    International Nuclear Information System (INIS)

    Liu Xiao-Lan; Peng Xiao-Niu; Yang Zhong-Jian; Li Min; Zhou Li

    2011-01-01

    Micrometer-scale gold nanoplates have been synthesized in high yield through a polyol process. The morphology, crystal structure and linear optical extinction of the gold nanoplates have been characterized. These gold nanoplates are single-crystalline with triangular, truncated triangular and hexagonal shapes, exhibiting strong surface plasmon resonance (SPR) extinction in the visible and near-infrared (NIR) region. The linear optical properties of gold nanoplates are also investigated by theoretical calculations. We further investigate the nonlinear optical properties of the gold nanoplates in solution by Z-scan technique. The nonlinear absorption (NLA) coefficient and nonlinear refraction (NLR) index are measured to be 1.18×10 2 cm/GW and −1.04×10 −3 cm 2 /GW, respectively. (condensed matter: electronic structure, electrical, magnetic, and optical properties)

  4. Nonlinear Dielectric Properties of Yeast Cells Cultured in Different Environmental Conditions

    Science.gov (United States)

    Kawanishi, Gomon; Fukuda, Naoki; Muraji, Masafumi

    The harmonics of the electric current through yeast suspensions, the nonlinear dielectric properties of yeast cells, have particular patterns according to the biological activity of the cells and the measurement of these patterns is a technique for determining the activity of living cells. The concentration of glucose and oxygen in yeast culture medium influences the manifestation of fermentation or respiration of yeast cells. Measurements were made with yeast cells (Saccharomyces cerevisiae) cultured aerobically and anaerobically in sufficient glucose concentration, aerobic fermentation and anaerobic fermentation, and aerobically in limited glucose concentration, respiration. The results showed that the harmonics were barely apparent for yeast cells in aerobic fermentation and respiratory; however, cells in the anaerobic fermentation displayed substantial third and fifth harmonics. We can say that environmental condition affects the yeast cells' nonlinear properties, from another viewpoint, the measurements of the nonlinear properties are available to determine the activity of yeast cells adjusted to the conditions of their cultivation.

  5. Linear and nonlinear optical properties of Sb-doped GeSe2 thin films

    Science.gov (United States)

    Zhang, Zhen-Ying; Chen, Fen; Lu, Shun-Bin; Wang, Yong-Hui; Shen, Xiang; Dai, Shi-Xun; Nie, Qiu-Hua

    2015-06-01

    Sb-doped GeSe2 chalcogenide thin films are prepared by the magnetron co-sputtering method. The linear optical properties of as-deposited films are derived by analyzing transmission spectra. The refractive index rises and the optical band gap decreases from 2.08 eV to 1.41 eV with increasing the Sb content. X-ray photoelectron spectra further confirm the formation of a covalent Sb-Se bond. The third-order nonlinear optical properties of thin films are investigated under femtosecond laser excitation at 800 nm. The results show that the third-order nonlinear optical properties are enhanced with increasing the concentration of Sb. The nonlinear refraction indices of these thin films are measured to be on the order of 10-18 m2/W with a positive sign and the nonlinear absorption coefficients are obtained to be on the order of 10-10 m/W. These excellent properties indicate that Sb-doped Ge-Se films have a good prospect in the applications of nonlinear optical devices. Project supported by the National Key Basic Research Program of China (Grant No. 2012CB722703), the National Natural Science Foundation of China (Grant No. 61377061), the Young Leaders of Academic Climbing Project of the Education Department of Zhejiang Province, China (Grant No. pd2013092), the Program for Innovative Research Team of Ningbo City, China (Grant No. 2009B217), and the K. C. Wong Magna Fund in Ningbo University, China.

  6. A Nonlinear Hyperbolic Volterra Equation in Viscoelasticity.

    Science.gov (United States)

    1980-06-01

    states that k(t) e L (0,-) if -nd only if (3.7) P(Z) def .’’(3.7) P(z) d ;’(0) + ’(0)a’(z) = X( 0 ) + (0)za(z) does not vanish on the half plane Rez ; 0...For w(t,x) e X(M,T), (2.5) and the Poincare inequality yield (2.6) w 2 (t,x) + w2x(t,x) + w 2(t,x) ( M , 0 4 t ( T, 0 4 x ( I x tx xx We now consider...2.6), the Poincare inequality and Schwarz’s inequality, every term on the right-hand side of (2.12), (2.15), and (2.16) can be majorized by one of p

  7. Third order nonlinear optical properties of a paratellurite single crystal

    Science.gov (United States)

    Duclère, J.-R.; Hayakawa, T.; Roginskii, E. M.; Smirnov, M. B.; Mirgorodsky, A.; Couderc, V.; Masson, O.; Colas, M.; Noguera, O.; Rodriguez, V.; Thomas, P.

    2018-05-01

    The (a,b) plane angular dependence of the third-order nonlinear optical susceptibility, χ(3) , of a c-cut paratellurite (α-TeO2) single crystal was quantitatively evaluated here by the Z-scan technique, using a Ti:sapphire femtosecond laser operated at 800 nm. In particular, the mean value Re( ⟨χ(3)⟩a,b )(α-TeO2) of the optical tensor has been extracted from such experiments via a direct comparison with the data collected for a fused silica reference glass plate. A R e (⟨χ(3)⟩(a,b )(α-TeO2)):R e (χ(3))(SiO2 glass) ratio roughly equal to 49.1 is found, and our result compares thus very favourably with the unique experimental value (a ratio of ˜50) reported by Kim et al. [J. Am. Ceram. Soc. 76, 2486 (1993)] for a pure TeO2 glass. In addition, it is shown that the angular dependence of the phase modulation within the (a,b) plane can be fully understood in the light of the strong dextro-rotatory power known for TeO2 materials. Taking into account the optical activity, some analytical model serving to estimate the diagonal and non-diagonal components of the third order nonlinear susceptibility tensor has been thus developed. Finally, Re( χxxxx(3) ) and Re( χxxyy(3) ) values of 95.1 ×10-22 m 2/V2 and 42.0 ×10-22 m2/V2 , respectively, are then deduced for a paratellurite single crystal, considering fused silica as a reference.

  8. Viscoelastic gravel-pack carrier fluid

    International Nuclear Information System (INIS)

    Nehmer, W.L.

    1988-01-01

    The ability of a fluid to flow adequately into the formation during gravel-pack treatments is critical to achieving a good pack. Recent studies have indicated ''fish-eyes'' and/or ''microgels'' present in many polymer gelled carrier fluids will plug pore throats, leading to impaired leakoff and causing formation damage. Intensive manipulation of the polymer gelled fluid using shear and filter devices will help remove the particles, but it adds to the cost of the treatment in terms of equipment and manpower. Excessive shear will degrade the polymer leading to poor gravel suspension, while too little shear will cause filtration problems. A gelled carried fluid using a viscoelastic surfactant system has been found to leak off very efficiently to the formation, and cause no formation damage, without the use of shear/filter devices. Viscoelastic surfactant-base gelled fluids develop viscosity because of the association of surfactant moloecules into large rod-shaped aggregates. There is no hydration of polymer involved, so fish-eyes and microgels will not be formed in the viscoelastic fluid. A surfactant-base system having a yield point allows the gravel carrying properties to be much better than fluids gelled with conventional polymer systems (hydroxyethylcellulose [HEC]). For example, a gravel carried fluid gelled with 80 lb HEC/1,000 gal has a viscosity of about 400 cp at 170 sec/sup -1/; a viscoelastic surfactant-base system having only one-half the viscosity still flows into cores about four times more efficiently than the HEC-base fluid. The rheology, leakoff, formation damage and mixing properties of a viscoelastic, surfactant-base, gravel-pack carrier fluid are discussed

  9. Impact load time histories for viscoelastic missiles

    International Nuclear Information System (INIS)

    Stoykovich, M.

    1977-01-01

    Generation of the impact load time history at the contact point between a viscoelastic missile and its targets is presented. In the past, in the case of aircraft striking containment shell structure, the impact load history was determined on the basis of actual measurements by subjecting a rigid wall to aircraft crash. The effects of elastic deformation of the target upon the impact load time history is formulated in this paper. The missile is idealized by a linear mass-spring-dashpot combination using viscoelastic models. These models can readily be processed taking into account the elastic as well as inelastic deformations of the missiles. The target is assumed to be either linearly elastic or rigid. In the case of the linearly elastic target, the normal mode theory is used to express the time-dependent displacements of the target which is simulated by lumped masses, elastic properties and dashpots in discrete parts. In the case of Maxwell viscoelastic model, the time-dependent displacements of the missile and the target are given in terms of the unknown impact load time history. This leads to an integral equation which may be solved by Laplace transformation. The normal mode theory is provided. Examples are given for bricks with viscoelastic materials as missiles against a rigid target. (Auth.)

  10. Spectral dependence of third-order nonlinear optical properties in InN

    International Nuclear Information System (INIS)

    Ahn, H.; Lee, M.-T.; Chang, Y.-M.

    2014-01-01

    We report on the nonlinear optical properties of InN measured in a wide near-infrared spectral range with the femtosecond Z-scan technique. The above-bandgap nonlinear absorption in InN is found to originate from the saturation of absorption by the band-state-filling and its cross-section increases drastically near the bandgap energy. With below-bandgap excitation, the nonlinear absorption undergoes a transition from saturation absorption (SA) to reverse-SA (RSA), attributed to the competition between SA of band-tail states and two-photon-related RSA. The measured large nonlinear refractive index of the order of 10 −10 cm 2 /W indicates InN as a potential material for all-optical switching and related applications

  11. Nonlinear optical properties of Nd3+-Li+ co-doped ZnS-PVP thin films

    Science.gov (United States)

    Talwatkar, S. S.; Sunatkari, A. L.; Tamgadge, Y. S.; Muley, G. G.

    2018-04-01

    The nonlinear optical properties of Nd3+-Li+ co-doped ZnS-PVP nanocomposite were studied using a continuous wave (CW) He-Ne laser (λ = 632.8 nm)by z-scan technique. The nonlinear refractive index (n2), absorption coefficient (β) and third order nonlinear susceptibility (χ(3)) of PVP thin films embedded with Nd3+-Li+ co-doped ZnS NPs was found in the order of 10-7 cm2/W, 10-6 cm/W and 10-7 esu respectively. The nonlinearity found increasing with Nd3+-Li+ co-dopant concentration. Based on the results, it is proposed that this material is a new class of luminescent material suitable in optoelectronics devices application, especially in light-emitting devices, electroluminescent devices, display devices, etc.

  12. Viscoelasticity evaluation of rubber by surface reflection of supersonic wave.

    Science.gov (United States)

    Omata, Nobuaki; Suga, Takahiro; Furusawa, Hirokazu; Urabe, Shinichi; Kondo, Takeru; Ni, Qing-Qing

    2006-12-22

    The main characteristic of rubber is a viscoelasticity. So it is important to research the characteristic of the viscoelasticity of the high frequency band for the friction between a rubber material and the hard one with roughness, for instance, the tire and the road. As for the measurement of the viscoelasticity of rubber, DMA (dynamic mechanical analysis) is general. However, some problems are pointed out to the measurement of the high frequency band by DMA. Then, we evaluated the viscoelasticity characteristic by the supersonic wave measurement. However, attenuation of rubber is large, and when the viscoelasticity is measured by the supersonic wave therefore, it is inconvenient and limited in a past method by means of bottom reflection. In this report, we tried the viscoelasticity evaluation by the method of using complex surface reflection coefficient and we compared with the friction coefficient under wide-range friction velocity. As a result, some relationships had been found for two properties. We report the result that character of viscoelasticity of rubber was comparable to friction coefficient.

  13. Seasonality Effects on Nonlinear Properties of Hydrometeorological Records: A New Method of Data Analysis

    Science.gov (United States)

    Livina, V. N.; Ashkenazy, Y.; Bunde, A.; Havlin, S.

    2007-12-01

    Climatic time series in general, and hydrological time series in particular, exhibit pronounced annual periodicity. This periodicity and its corresponding harmonics affect the nonlinear properties of the relevant time series (i.e., the long-range volatility correlations and width of multifractal spectrum) and thus have to be filtered out before studying fractal and volatility properties. We compare several filtering techniques (one of them proposed here) and find that in order to eliminate the periodicity effect on the nonlinear properties of the time series (i.e., the volatility and multifractal properties) it is necessary to filter out the seasonal standard deviation in addition to the filtering of the seasonal mean. The obtained results indicate weak volatility correlations (weak nonlinearity) in the river data, and this can be seen using different filterings approaches. [1] Livina~V.~N., Y.~Ashkenazy, A.~Bunde, and S.~Havlin, Seasonality effects on nonlinear properties of hydrometeorological records, in Extremes, Trends, and Correlations in Hydrology and Climate (ed. by J.P.Kropp & H.-J.Schellnhuber), Springer, Berlin, submitted.

  14. Nonlinear electroelasticity: material properties, continuum theory and applications.

    Science.gov (United States)

    Dorfmann, Luis; Ogden, Ray W

    2017-08-01

    In the last few years, it has been recognized that the large deformation capacity of elastomeric materials that are sensitive to electric fields can be harnessed for use in transducer devices such as actuators and sensors. This has led to the reassessment of the mathematical theory that is needed for the description of the electromechanical (in particular, electroelastic) interactions for purposes of material characterization and prediction. After a review of the key experiments concerned with determining the nature of the electromechanical interactions and a discussion of the range of applications to devices, we provide a short account of the history of developments in the nonlinear theory. This is followed by a succinct modern treatment of electroelastic theory, including the governing equations and constitutive laws needed for both material characterization and the analysis of general electroelastic coupling problems. For illustration, the theory is then applied to two simple representative boundary-value problems that are relevant to the geometries of activation devices; in particular, (a) a rectangular plate and (b) a circular cylindrical tube, in each case with compliant electrodes on the major surfaces and a potential difference between them. In (a), an electric field is generated normal to the major surfaces and in (b), a radial electric field is present. This is followed by a short section in which other problems addressed on the basis of the general theory are described briefly.

  15. Nonlinear optical properties of Sn+ ion-implanted silica glass

    International Nuclear Information System (INIS)

    Takeda, Y.; Hioki, T.; Motohiro, T.; Noda, S.; Kurauchi, T.

    1994-01-01

    The absolute value of the third-order nonlinear optical susceptibility, vertical stroke χ (3) vertical stroke , of Sn + ion-implanted silica glass was found to be similar 10 -6 esu. This value is as large as those reported for semiconductor-doped glasses. Silica glass substrates were implanted with Sn + ions at an acceleration energy of 400 keV to a dose of 2x10 17 ions/cm 2 at room temperature. Metallic Sn microcrystallites of 4-20 nm in diameter were found to be embedded in the silica glass matrix. The average volume fraction of the Sn microcrystallites was evaluated to be 28%. vertical stroke χ (3) vertical stroke and the imaginary part of the dielectric function, Im ε, had peaks at the same wavelength of 500 nm owing to surface plasmon resonance. The peak width of vertical stroke χ (3) vertical stroke was nearly half of that of Im ε, which can be explained by an effective medium theory. ((orig.))

  16. Nonlinear electroelasticity: material properties, continuum theory and applications

    Science.gov (United States)

    Dorfmann, Luis; Ogden, Ray W.

    2017-08-01

    In the last few years, it has been recognized that the large deformation capacity of elastomeric materials that are sensitive to electric fields can be harnessed for use in transducer devices such as actuators and sensors. This has led to the reassessment of the mathematical theory that is needed for the description of the electromechanical (in particular, electroelastic) interactions for purposes of material characterization and prediction. After a review of the key experiments concerned with determining the nature of the electromechanical interactions and a discussion of the range of applications to devices, we provide a short account of the history of developments in the nonlinear theory. This is followed by a succinct modern treatment of electroelastic theory, including the governing equations and constitutive laws needed for both material characterization and the analysis of general electroelastic coupling problems. For illustration, the theory is then applied to two simple representative boundary-value problems that are relevant to the geometries of activation devices; in particular, (a) a rectangular plate and (b) a circular cylindrical tube, in each case with compliant electrodes on the major surfaces and a potential difference between them. In (a), an electric field is generated normal to the major surfaces and in (b), a radial electric field is present. This is followed by a short section in which other problems addressed on the basis of the general theory are described briefly.

  17. Modeling electrically active viscoelastic membranes.

    Directory of Open Access Journals (Sweden)

    Sitikantha Roy

    Full Text Available The membrane protein prestin is native to the cochlear outer hair cell that is crucial to the ear's amplification and frequency selectivity throughout the whole acoustic frequency range. The outer hair cell exhibits interrelated dimensional changes, force generation, and electric charge transfer. Cells transfected with prestin acquire unique active properties similar to those in the native cell that have also been useful in understanding the process. Here we propose a model describing the major electromechanical features of such active membranes. The model derived from thermodynamic principles is in the form of integral relationships between the history of voltage and membrane resultants as independent variables and the charge density and strains as dependent variables. The proposed model is applied to the analysis of an active force produced by the outer hair cell in response to a harmonic electric field. Our analysis reveals the mechanism of the outer hair cell active (isometric force having an almost constant amplitude and phase up to 80 kHz. We found that the frequency-invariance of the force is a result of interplay between the electrical filtering associated with prestin and power law viscoelasticity of the surrounding membrane. Paradoxically, the membrane viscoelasticity boosts the force balancing the electrical filtering effect. We also consider various modes of electromechanical coupling in membrane with prestin associated with mechanical perturbations in the cell. We consider pressure or strains applied step-wise or at a constant rate and compute the time course of the resulting electric charge. The results obtained here are important for the analysis of electromechanical properties of membranes, cells, and biological materials as well as for a better understanding of the mechanism of hearing and the role of the protein prestin in this mechanism.

  18. Extinction and Ergodic Property of Stochastic SIS Epidemic Model with Nonlinear Incidence Rate

    Directory of Open Access Journals (Sweden)

    Qixing Han

    2013-01-01

    Full Text Available We investigate a stochastic SIS model with nonlinear incidence rate. We show that there exists a unique nonnegative solution to the system, and condition for the infectious individuals I(t to be extinct is given. Moreover, we prove that the system has ergodic property. Finally, computer simulations are carried out to verify our results.

  19. Using strong nonlinearity and high-frequency vibrations to control effective properties of discrete elastic waveguides

    DEFF Research Database (Denmark)

    Lazarov, Boyan Stefanov; Thomsen, Jon Juel; Snaeland, Sveinn Orri

    2008-01-01

    The aim of this article is to investigate how highfrequency (HF) excitation, combined with strong nonlinear elastic material behavior, influences the effective material or structural properties for low-frequency excitation and wave propagation. The HF effects are demonstrated on discrete linear s...

  20. Studies of biaxial mechanical properties and nonlinear finite element modeling of skin.

    Science.gov (United States)

    Shang, Xituan; Yen, Michael R T; Gaber, M Waleed

    2010-06-01

    The objective of this research is to conduct mechanical property studies of skin from two individual but potentially connected aspects. One is to determine the mechanical properties of the skin experimentally by biaxial tests, and the other is to use the finite element method to model the skin properties. Dynamic biaxial tests were performed on 16 pieces of abdominal skin specimen from rats. Typical biaxial stress-strain responses show that skin possesses anisotropy, nonlinearity and hysteresis. To describe the stress-strain relationship in forms of strain energy function, the material constants of each specimen were obtained and the results show a high correlation between theory and experiments. Based on the experimental results, a finite element model of skin was built to model the skin's special properties including anisotropy and nonlinearity. This model was based on Arruda and Boyce's eight-chain model and Bischoff et al.'s finite element model of skin. The simulation results show that the isotropic, nonlinear eight-chain model could predict the skin's anisotropic and nonlinear responses to biaxial loading by the presence of an anisotropic prestress state.

  1. Effects of non-linearity of material properties on the coupled mechanical-hydraulic-thermal behavior in rock mass

    International Nuclear Information System (INIS)

    Kobayashi, Akira; Ohnishi, Yuzo

    1986-01-01

    The nonlinearity of material properties used in the coupled mechanical-hydraulic-thermal analysis is investigated from the past literatures. Some nonlinearity that is respectively effective for the system is introduced into our computer code for analysis such a coupling problem by using finite element method. And the effects of nonlinearity of each material property on the coupled behavior in rock mass are examined for simple model and Stripa project model with the computer code. (author)

  2. Nonlinear absorption and transmission properties of Ge, Te and InAs using tuneable IR FEL

    Energy Technology Data Exchange (ETDEWEB)

    Amirmadhi, F.; Becker, K.; Brau, C.A. [Vanderbilt Univ., Nashville, TN (United States)

    1995-12-31

    Nonlinear absorption properties of Ge, Te and InAs are being investigated using the transmission of FEL optical pulses through these semiconductors (z-scan method). Wavelength, intensity and macropulse dependence are used to differentiate between two-photon and free-carrier absorption properties of these materials. Macropulse dependence is resolved by using a Pockles Cell to chop the 4-{mu}s macropulse down to 100 ns. Results of these experiments will be presented and discussed.

  3. Natural Silk as a Photonics Component: a Study on Its Light Guiding and Nonlinear Optical Properties

    OpenAIRE

    Kujala, Sami; Mannila, Anna; Karvonen, Lasse; Kieu, Khanh; Sun, Zhipei

    2016-01-01

    Silk fibers are expected to become a pathway to biocompatible and bioresorbable waveguides, which could be used to deliver localized optical power for various applications, e.g., optical therapy or imaging inside living tissue. Here, for the first time, the linear and nonlinear optical properties of natural silk fibers have been studied. The waveguiding properties of silk fibroin of largely unprocessed Bombyx mori silkworm silk are assessed using two complementary methods, and found to be on ...

  4. Nonlinear optical properties of poly(methyl methacrylate) thin films doped with Bixa Orellana dye

    Energy Technology Data Exchange (ETDEWEB)

    Zongo, S., E-mail: sidiki@tlabs.ac.za [UNESCO-UNISA Africa Chair in Nanosciences/Nanotechnology, College of Graduate Studies, University of South Africa, Muckleneuk ridge, POBox 392, Pretoria (South Africa); Nanosciences African Network (NANOAFNET), iThemba LABS-National Research Foundation, 1 OldFaure road, Somerset West 7129, POBox 722, Somerset West, Western Cape Province (South Africa); Kerasidou, A.P. [LUNAM Université, Université d’Angers, CNRS UMR 6200, Laboratoire MOLTECH-Anjou, 2 Bd Lavoisier, 49045 Angers Cedex (France); Sone, B.T.; Diallo, A. [UNESCO-UNISA Africa Chair in Nanosciences/Nanotechnology, College of Graduate Studies, University of South Africa, Muckleneuk ridge, POBox 392, Pretoria (South Africa); Nanosciences African Network (NANOAFNET), iThemba LABS-National Research Foundation, 1 OldFaure road, Somerset West 7129, POBox 722, Somerset West, Western Cape Province (South Africa); Mthunzi, P. [Council for Scientific and Industrial Research, P O Box 395, Pretoria 0001 (South Africa); Iliopoulos, K. [LUNAM Université, Université d’Angers, CNRS UMR 6200, Laboratoire MOLTECH-Anjou, 2 Bd Lavoisier, 49045 Angers Cedex (France); Institute of Chemical Engineering Sciences, Foundation for Research and Technology Hellas (FORTH/ICE-HT), 26504 Patras (Greece); Nkosi, M. [Nanosciences African Network (NANOAFNET), iThemba LABS-National Research Foundation, 1 OldFaure road, Somerset West 7129, POBox 722, Somerset West, Western Cape Province (South Africa); and others

    2015-06-15

    Highlights: • We studied the linear and nonlinear optical properties of hybrid Bixa Orellana dye doped PMMA thin film. • We investigated the linear optical properties by means of UV/Vis, FTIR and Fluorescence. • We used Tauc - Lorentz model to evaluate linear optical parameters (n &k) with relative maximum of 1.456 at 508.5, 523.79 and 511.9 nm for n is observed while the maximum of k varies from 0.070 to 0.080. • We evaluated nonlinear third order susceptibility which was found to be 1.00 × 10{sup −21} m{sup 2} V{sup −2} or 0.72 × 10{sup −13} esu. - Abstract: Natural dyes with highly delocalized π-electron systems are considered as promising organic materials for nonlinear optical applications. Among these dyes, Bixa Orellana dye with extended π-electron delocalization is one of the most attractive dyes. Bixa Orellana dye-doped Poly(methyl methacrylate) (PMMA) thin films were prepared through spin coating process for linear and nonlinear optical properties investigation. Atomic force microscopy (AFM) was used to evaluate the roughness of the thin films. The optical constants n and k were evaluated by ellipsometric spectroscopy. The refractive index had a maximum of about 1.456 at 508.5, 523.79 and 511.9 nm, while the maximum of k varies from 0.070 to 0.080 with the thickness. The third order nonlinear optical properties of the hybrid Bixa Orellana dye-PMMA polymer were investigated under 30 ps laser irradiation at 1064 nm with a repetition rate of 10 Hz. In particular the third-order nonlinear susceptibility has been determined by means of the Maker Fringes technique. The nonlinear third order susceptibility was found to be 1.00 × 10{sup −21} m{sup 2} V{sup −2} or 0.72 × 10{sup −13} esu. Our studies provide concrete evidence that the hybrid-PMMA composites of Bixa dye are prospective candidates for nonlinear material applications.

  5. Structural, Linear, and Nonlinear Optical and Mechanical Properties of New Organic L-Serine Crystal

    Directory of Open Access Journals (Sweden)

    K. Rajesh

    2014-01-01

    Full Text Available Nonlinear optical single crystal of organic amino acid L-Serine (LS was grown by slow evaporation technique. Solubility study of the compound was measured and metastable zone width was found. Single crystal X-ray diffraction study was carried out for the grown crystal. The linear and nonlinear optical properties of the crystal were confirmed by UV-Vis analysis and powder SHG tester. FT-IR spectrum was recorded and functional groups were analyzed. Vickers’ microhardness studies showed the mechanical strength of the grown crystal. Laser damage threshold value of the crystal was calculated. Photoconductivity studies reveal the conductivity of the crystal.

  6. Uniform Decay for Solutions of an Axially Moving Viscoelastic Beam

    Energy Technology Data Exchange (ETDEWEB)

    Kelleche, Abdelkarim, E-mail: kellecheabdelkarim@gmail.com [Université des Sciences et de la Technologie Houari Boumediene, Faculté des Mathématiques (Algeria); Tatar, Nasser-eddine, E-mail: tatarn@Kfupm.edu.sa [King Fahd University of Petroleum and Minerals, Department of Mathematics and Statistics (Saudi Arabia)

    2017-06-15

    The paper deals with an axially moving viscoelastic structure modeled as an Euler–Bernoulli beam. The aim is to suppress the transversal displacement (transversal vibrations) that occur during the axial motion of the beam. It is assumed that the beam is moving with a constant axial speed and it is subject to a nonlinear force at the right boundary. We prove that when the axial speed of the beam is smaller than a critical value, the dissipation produced by the viscoelastic material is sufficient to suppress the transversal vibrations. It is shown that the rate of decay of the energy depends on the kernel which arise in the viscoelastic term. We consider a general kernel and notice that solutions cannot decay faster than the kernel.

  7. Investigation of transient cavitating flow in viscoelastic pipes

    International Nuclear Information System (INIS)

    Keramat, A; Tijsseling, A S; Ahmadi, A

    2010-01-01

    A study on water hammer in viscoelastic pipes when the fluid pressure drops to liquid vapour pressure is performed. Two important concepts including column separation and the effects of retarded strains in the pipe wall on the fluid response have been investigated separately in recent works, but there is some curiosity as to how the results for pressure and discharge are when column separation occurs in a viscoelastic pipe. For pipes made of plastic such as polyethylene (PE) and polyvinyl chloride (PVC), viscoelasticity is a crucial mechanical property which changes the hydraulic and structural transient responses. Based on previous developments in the analysis of water hammer, a model which is capable of analysing column separation in viscoelastic pipes is presented and used for solving the selected case studies. For the column-separation modelling the Discrete Vapour Cavity Model (DVCM) is utilised and the viscoelasticity property of the pipe wall is modelled by Kelvin-Voigt elements. The effects of viscoelasticity play an important role in the column separation phenomenon because it changes the water hammer fundamental frequency and so affects the time of opening or collapse of the cavities. Verification of the implemented computer code is performed for the effects of viscoelasticity and column separation - separately and simultaneously - using experimental results from the literature. In the provided examples the focus is placed on the simultaneous effect of viscoelasticity and column separation on the hydraulic transient response. The final conclusions drawn are that if rectangular grids are utilised the DVCM gives acceptable predictions of the phenomenon and that the pipe wall material's retarded behaviour strongly dampens the pressure spikes caused by column separation.

  8. Investigation of transient cavitating flow in viscoelastic pipes

    Science.gov (United States)

    Keramat, A.; Tijsseling, A. S.; Ahmadi, A.

    2010-08-01

    A study on water hammer in viscoelastic pipes when the fluid pressure drops to liquid vapour pressure is performed. Two important concepts including column separation and the effects of retarded strains in the pipe wall on the fluid response have been investigated separately in recent works, but there is some curiosity as to how the results for pressure and discharge are when column separation occurs in a viscoelastic pipe. For pipes made of plastic such as polyethylene (PE) and polyvinyl chloride (PVC), viscoelasticity is a crucial mechanical property which changes the hydraulic and structural transient responses. Based on previous developments in the analysis of water hammer, a model which is capable of analysing column separation in viscoelastic pipes is presented and used for solving the selected case studies. For the column-separation modelling the Discrete Vapour Cavity Model (DVCM) is utilised and the viscoelasticity property of the pipe wall is modelled by Kelvin-Voigt elements. The effects of viscoelasticity play an important role in the column separation phenomenon because it changes the water hammer fundamental frequency and so affects the time of opening or collapse of the cavities. Verification of the implemented computer code is performed for the effects of viscoelasticity and column separation - separately and simultaneously - using experimental results from the literature. In the provided examples the focus is placed on the simultaneous effect of viscoelasticity and column separation on the hydraulic transient response. The final conclusions drawn are that if rectangular grids are utilised the DVCM gives acceptable predictions of the phenomenon and that the pipe wall material's retarded behaviour strongly dampens the pressure spikes caused by column separation.

  9. Thickness-dependent nonlinear optical properties of CsPbBr3 perovskite nanosheets.

    Science.gov (United States)

    Zhang, Jun; Jiang, Tian; Zheng, Xin; Shen, Chao; Cheng, Xiang'ai

    2017-09-01

    Halide perovskite has attracted significant attention because of excellent optical properties. Here, we study the optical properties of CsPbBr 3 perovskite nanosheets and observe that the nonlinear optical properties can be tuned by the thickness. The photoluminescence (PL) properties and nonlinear absorption effects induced by saturation absorption (SA) and two-photon absorption (TPA) in CsPbBr 3 nanosheets with different thicknesses (from 104.6 to 195.4 nm) have been studied. The PL intensity increases nearly three times with changing from the thinnest one to the thinnest under the same excitation condition. Moreover, the same phenomenon takes place no matter when SA or TPA effects happen. The PL lifetime (τ) varies inversely with the thickness. When SA happens, τ decreases from 11.54 to 9.43 ns while when TPA happens new decay channels emerge with the increase of the thickness. Besides, both saturation intensity (I sat ) and the modulation depth are proportional to the thickness (I sat rises from 3.12 to 4.79  GW/cm 2 , the modulation depth increases from 18.6% to 32.3%), while the TPA coefficient (β) is inversely proportional with the thickness (decreases from 10.94 to 4.73  cm/GW). In addition, quantum yields and thicknesses are in the direct ratio. This Letter advocates great promise for nonlinear optical property related photonics devices.

  10. Nonlinear and anisotropic tensile properties of graft materials used in soft tissue applications.

    Science.gov (United States)

    Yoder, Jonathon H; Elliott, Dawn M

    2010-05-01

    The mechanical properties of extracellular matrix grafts that are intended to augment or replace soft tissues should be comparable to the native tissue. Such grafts are often used in fiber-reinforced tissue applications that undergo multi-axial loading and therefore knowledge of the anisotropic and nonlinear properties are needed, including the moduli and Poisson's ratio in two orthogonal directions within the plane of the graft. The objective of this study was to measure the tensile mechanical properties of several marketed grafts: Alloderm, Restore, CuffPatch, and OrthADAPT. The degree of anisotropy and non-linearity within each graft was evaluated from uniaxial tensile tests and compared to their native tissue. The Alloderm graft was anisotropic in both the toe- and linear-region of the stress-strain response, was highly nonlinear, and generally had low properties. The Restore and CuffPatch grafts had similar stress-strain responses, were largely isotropic, had a linear-region modulus of 18MPa, and were nonlinear. OrthADAPT was anisotropic in the linear-region (131 MPA vs 47MPa in the toe-region) and was highly nonlinear. The Poisson ratio for all grafts was between 0.4 and 0.7, except for the parallel orientation of Restore which was greater than 1.0. Having an informed understanding of how the available grafts perform mechanically will allow for better assessment by the physician for which graft to apply depending upon its application. Copyright 2010 Elsevier Ltd. All rights reserved.

  11. Forward and inverse viscoelastic wave scattering by irregular inclusions for shear wave elastography.

    Science.gov (United States)

    Bernard, Simon; Cloutier, Guy

    2017-10-01

    Inversion methods in shear wave elastography use simplifying assumptions to recover the mechanical properties of soft tissues. Consequently, these methods suffer from artifacts when applied to media containing strong stiffness contrasts, and do not provide a map of the viscosity. In this work, the shear wave field recorded inside and around an inclusion was used to estimate the viscoelastic properties of the inclusion and surrounding medium, based on an inverse problem approach assuming local homogeneity of both media. An efficient semi-analytical method was developed to model the scattering of an elastic wave by an irregular inclusion, based on a decomposition of the field by Bessel functions and on a decomposition of the boundaries as Fourier series. This model was validated against finite element modeling. Shear waves were experimentally induced by acoustic radiation force in soft tissue phantoms containing stiff and soft inclusions, and the displacement field was imaged at a high frame rate using plane wave imaging. A nonlinear least-squares algorithm compared the model to the experimental data and adjusted the geometrical and mechanical parameters. The estimated shear storage and loss moduli were in good agreement with reference measurements, as well as the estimated inclusion shape. This approach provides an accurate estimation of geometry and viscoelastic properties for a single inclusion in a homogeneous background in the context of radiation force elastography.

  12. Modelling of Asphalt Concrete Stiffness in the Linear Viscoelastic Region

    Science.gov (United States)

    Mazurek, Grzegorz; Iwański, Marek

    2017-10-01

    Stiffness modulus is a fundamental parameter used in the modelling of the viscoelastic behaviour of bituminous mixtures. On the basis of the master curve in the linear viscoelasticity range, the mechanical properties of asphalt concrete at different loading times and temperatures can be predicted. This paper discusses the construction of master curves under rheological mathematical models i.e. the sigmoidal function model (MEPDG), the fractional model, and Bahia and co-workers’ model in comparison to the results from mechanistic rheological models i.e. the generalized Huet-Sayegh model, the generalized Maxwell model and the Burgers model. For the purposes of this analysis, the reference asphalt concrete mix (denoted as AC16W) intended for the binder coarse layer and for traffic category KR3 (5×105 controlled strain mode. The fixed strain level was set at 25με to guarantee that the stiffness modulus of the asphalt concrete would be tested in a linear viscoelasticity range. The master curve was formed using the time-temperature superposition principle (TTSP). The stiffness modulus of asphalt concrete was determined at temperatures 10°C, 20°C and 40°C and at loading times (frequency) of 0.1, 0.3, 1, 3, 10, 20 Hz. The model parameters were fitted to the rheological models using the original programs based on the nonlinear least squares sum method. All the rheological models under analysis were found to be capable of predicting changes in the stiffness modulus of the reference asphalt concrete to satisfactory accuracy. In the cases of the fractional model and the generalized Maxwell model, their accuracy depends on a number of elements in series. The best fit was registered for Bahia and co-workers model, generalized Maxwell model and fractional model. As for predicting the phase angle parameter, the largest discrepancies between experimental and modelled results were obtained using the fractional model. Except the Burgers model, the model matching quality was

  13. Transient photoconductivity and femtosecond nonlinear optical properties of a conjugated polymer-graphene oxide composite

    Energy Technology Data Exchange (ETDEWEB)

    Nalla, Venkatram; Ji Wei [Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Polavarapu, Lakshminarayana; Manga, Kiran Kumar; Goh, Bee Min; Loh, Kian Ping; Xu Qinghua, E-mail: chmxqh@nus.edu.sg, E-mail: phyjiwei@nus.edu.sg [Department of Chemistry, National University of Singapore, Singapore 117543 (Singapore)

    2010-10-15

    A water soluble conjugated thiophene polymer, sodium salt of poly[2-(3-thienyl)ethoxy-4-butylsulfonate] (TPP), and graphene oxide (GO) composite film (GO-TPP) device was prepared. Transient photoconductivity measurements were carried out on the GO-TPP composite film using 150 ns laser pulses of 527 nm wavelength. Highly efficient photocurrent generation was observed from the GO-TPP film. The relationships of the film photoconductivity, photocurrent decay time and electron decay times with the incident light intensity were investigated. The photoconductive gain of the film was determined to be greater than 40% and to be independent of the light intensity. Furthermore, the femtosecond nonlinear optical properties of the GO-TPP film were measured using 800 nm femtosecond laser pulses and the composite film exhibited high nonlinear absorption and nonlinear refraction coefficients.

  14. Transient photoconductivity and femtosecond nonlinear optical properties of a conjugated polymer-graphene oxide composite

    International Nuclear Information System (INIS)

    Nalla, Venkatram; Ji Wei; Polavarapu, Lakshminarayana; Manga, Kiran Kumar; Goh, Bee Min; Loh, Kian Ping; Xu Qinghua

    2010-01-01

    A water soluble conjugated thiophene polymer, sodium salt of poly[2-(3-thienyl)ethoxy-4-butylsulfonate] (TPP), and graphene oxide (GO) composite film (GO-TPP) device was prepared. Transient photoconductivity measurements were carried out on the GO-TPP composite film using 150 ns laser pulses of 527 nm wavelength. Highly efficient photocurrent generation was observed from the GO-TPP film. The relationships of the film photoconductivity, photocurrent decay time and electron decay times with the incident light intensity were investigated. The photoconductive gain of the film was determined to be greater than 40% and to be independent of the light intensity. Furthermore, the femtosecond nonlinear optical properties of the GO-TPP film were measured using 800 nm femtosecond laser pulses and the composite film exhibited high nonlinear absorption and nonlinear refraction coefficients.

  15. Static viscoelasticity of biomass polyethylene composites

    Directory of Open Access Journals (Sweden)

    Keyan Yang

    Full Text Available The biomass polyethylene composites filled with poplar wood flour, rice husk, cotton stalk or corn stalk were prepared by extrusion molding. The static viscoelasticity of composites was investigated by the dynamic thermal mechanical analyzer (DMA. Through the stress-strain scanning, it is found that the linear viscoelasticity interval of composites gradually decreases as the temperature rises, and the critical stress and strain values are 0.8 MPa and 0.03% respectively. The experiment shows that as the temperature rises, the creep compliance of biomass polyethylene composites is increased; under the constant temperature, the creep compliance decreases with the increase of content of biomass and calcium carbonate. The biomass and calcium carbonate used to prepare composites as filler can improve damping vibration attenuation and reduce stress deformation of composites. The stress relaxation modulus of composites is reduced and the relaxation rate increases at the higher temperature. The biomass and calcium carbonate used to prepare composites as filler not only can reduce costs, but also can increase stress relaxation modulus and improve the size thermostability of composites. The corn stalk is a good kind of biomass raw material for composites since it can improve the creep resistance property and the stress relaxation resistance property of composites more effectively than other three kinds of biomass (poplar wood flour, rice husk and cotton stalk. Keywords: Biomass, Composites, Calcium carbonate, Static viscoelasticity, Creep, Stress relaxation

  16. Chaotic properties between the nonintegrable discrete nonlinear Schroedinger equation and a nonintegrable discrete Heisenberg model

    International Nuclear Information System (INIS)

    Ding Qing

    2007-01-01

    We prove that the integrable-nonintegrable discrete nonlinear Schroedinger equation (AL-DNLS) introduced by Cai, Bishop and Gronbech-Jensen (Phys. Rev. Lett. 72 591(1994)) is the discrete gauge equivalent to an integrable-nonintegrable discrete Heisenberg model from the geometric point of view. Then we study whether the transmission and bifurcation properties of the AL-DNLS equation are preserved under the action of discrete gauge transformations. Our results reveal that the transmission property of the AL-DNLS equation is completely preserved and the bifurcation property is conditionally preserved to those of the integrable-nonintegrable discrete Heisenberg model

  17. Skin mechanical properties and modeling: A review.

    Science.gov (United States)

    Joodaki, Hamed; Panzer, Matthew B

    2018-04-01

    The mechanical properties of the skin are important for various applications. Numerous tests have been conducted to characterize the mechanical behavior of this tissue, and this article presents a review on different experimental methods used. A discussion on the general mechanical behavior of the skin, including nonlinearity, viscoelasticity, anisotropy, loading history dependency, failure properties, and aging effects, is presented. Finally, commonly used constitutive models for simulating the mechanical response of skin are discussed in the context of representing the empirically observed behavior.

  18. Parameter estimation of a nonlinear Burger's model using nanoindentation and finite element-based inverse analysis

    Science.gov (United States)

    Hamim, Salah Uddin Ahmed

    Nanoindentation involves probing a hard diamond tip into a material, where the load and the displacement experienced by the tip is recorded continuously. This load-displacement data is a direct function of material's innate stress-strain behavior. Thus, theoretically it is possible to extract mechanical properties of a material through nanoindentation. However, due to various nonlinearities associated with nanoindentation the process of interpreting load-displacement data into material properties is difficult. Although, simple elastic behavior can be characterized easily, a method to characterize complicated material behavior such as nonlinear viscoelasticity is still lacking. In this study, a nanoindentation-based material characterization technique is developed to characterize soft materials exhibiting nonlinear viscoelasticity. Nanoindentation experiment was modeled in finite element analysis software (ABAQUS), where a nonlinear viscoelastic behavior was incorporated using user-defined subroutine (UMAT). The model parameters were calibrated using a process called inverse analysis. In this study, a surrogate model-based approach was used for the inverse analysis. The different factors affecting the surrogate model performance are analyzed in order to optimize the performance with respect to the computational cost.

  19. Modelling and properties of a nonlinear autonomous switching system in fed-batch culture of glycerol

    Science.gov (United States)

    Wang, Juan; Sun, Qingying; Feng, Enmin

    2012-11-01

    A nonlinear autonomous switching system is proposed to describe the coupled fed-batch fermentation with the pH as the feedback parameter. We prove the non-Zeno behaviors of the switching system and some basic properties of its solution, including the existence, uniqueness, boundedness and regularity. Numerical simulation is also carried out, which reveals that the proposed system can describe the factual fermentation process properly.

  20. VISCOELASTIC MODELS OF TIDALLY HEATED EXOMOONS

    Energy Technology Data Exchange (ETDEWEB)

    Dobos, Vera [Konkoly Thege Miklos Astronomical Institute, Research Centre of Astronomy and Earth Sciences, Hungarian Academy of Sciences, H-1121 Konkoly Thege Miklós út 15-17, Budapest (Hungary); Turner, Edwin L., E-mail: dobos@konkoly.hu [Department of Astrophysical Sciences, Princeton University, 08544, 4 Ivy Lane, Peyton Hall, Princeton, NJ (United States)

    2015-05-01

    Tidal heating of exomoons may play a key role in their habitability, since the elevated temperature can melt the ice on the body even without significant solar radiation. The possibility of life has been intensely studied on solar system moons such as Europa or Enceladus where the surface ice layer covers a tidally heated water ocean. Tidal forces may be even stronger in extrasolar systems, depending on the properties of the moon and its orbit. To study the tidally heated surface temperature of exomoons, we used a viscoelastic model for the first time. This model is more realistic than the widely used, so-called fixed Q models because it takes into account the temperature dependence of the tidal heat flux and the melting of the inner material. Using this model, we introduced the circumplanetary Tidal Temperate Zone (TTZ), which strongly depends on the orbital period of the moon and less on its radius. We compared the results with the fixed Q model and investigated the statistical volume of the TTZ using both models. We have found that the viscoelastic model predicts 2.8 times more exomoons in the TTZ with orbital periods between 0.1 and 3.5 days than the fixed Q model for plausible distributions of physical and orbital parameters. The viscoelastic model provides more promising results in terms of habitability because the inner melting of the body moderates the surface temperature, acting like a thermostat.

  1. VISCOELASTIC MODELS OF TIDALLY HEATED EXOMOONS

    International Nuclear Information System (INIS)

    Dobos, Vera; Turner, Edwin L.

    2015-01-01

    Tidal heating of exomoons may play a key role in their habitability, since the elevated temperature can melt the ice on the body even without significant solar radiation. The possibility of life has been intensely studied on solar system moons such as Europa or Enceladus where the surface ice layer covers a tidally heated water ocean. Tidal forces may be even stronger in extrasolar systems, depending on the properties of the moon and its orbit. To study the tidally heated surface temperature of exomoons, we used a viscoelastic model for the first time. This model is more realistic than the widely used, so-called fixed Q models because it takes into account the temperature dependence of the tidal heat flux and the melting of the inner material. Using this model, we introduced the circumplanetary Tidal Temperate Zone (TTZ), which strongly depends on the orbital period of the moon and less on its radius. We compared the results with the fixed Q model and investigated the statistical volume of the TTZ using both models. We have found that the viscoelastic model predicts 2.8 times more exomoons in the TTZ with orbital periods between 0.1 and 3.5 days than the fixed Q model for plausible distributions of physical and orbital parameters. The viscoelastic model provides more promising results in terms of habitability because the inner melting of the body moderates the surface temperature, acting like a thermostat

  2. Fully coupled heat conduction and deformation analyses of visco-elastic solids

    KAUST Repository

    Khan, Kamran; Muliana, Anastasia Hanifah

    2012-01-01

    the temperature in a viscoelastic body. The rate of stress relaxation (or the rate of creep) and the mechanical and physical properties of visco-elastic materials, such as polymers, vary with temperature. This study aims at understanding the effect of coupling

  3. A viscoelastic model for the prediction of transcranial ultrasound propagation: application for the estimation of shear acoustic properties in the human skull

    Science.gov (United States)

    Pichardo, Samuel; Moreno-Hernández, Carlos; Drainville, Robert Andrew; Sin, Vivian; Curiel, Laura; Hynynen, Kullervo

    2017-09-01

    A better understanding of ultrasound transmission through the human skull is fundamental to develop optimal imaging and therapeutic applications. In this study, we present global attenuation values and functions that correlate apparent density calculated from computed tomography scans to shear speed of sound. For this purpose, we used a model for sound propagation based on the viscoelastic wave equation (VWE) assuming isotropic conditions. The model was validated using a series of measurements with plates of different plastic materials and angles of incidence of 0°, 15° and 50°. The optimal functions for transcranial ultrasound propagation were established using the VWE, scan measurements of transcranial propagation with an angle of incidence of 40° and a genetic optimization algorithm. Ten (10) locations over three (3) skulls were used for ultrasound frequencies of 270 kHz and 836 kHz. Results with plastic materials demonstrated that the viscoelastic modeling predicted both longitudinal and shear propagation with an average (±s.d.) error of 9(±7)% of the wavelength in the predicted delay and an error of 6.7(±5)% in the estimation of transmitted power. Using the new optimal functions of speed of sound and global attenuation for the human skull, the proposed model predicted the transcranial ultrasound transmission for a frequency of 270 kHz with an expected error in the predicted delay of 5(±2.7)% of the wavelength. The sound propagation model predicted accurately the sound propagation regardless of either shear or longitudinal sound transmission dominated. For 836 kHz, the model predicted accurately in average with an error in the predicted delay of 17(±16)% of the wavelength. Results indicated the importance of the specificity of the information at a voxel level to better understand ultrasound transmission through the skull. These results and new model will be very valuable tools for the future development of transcranial applications of

  4. Characterization of electrosynthesized conjugated polymer-carbon nanotube composite: optical nonlinearity and electrical property.

    Science.gov (United States)

    Bahrami, Afarin; Talib, Zainal Abidin; Shahriari, Esmaeil; Yunus, Wan Mahmood Mat; Kasim, Anuar; Behzad, Kasra

    2012-01-01

    The effects of multi-walled carbon nanotube (MWNT) concentration on the structural, optical and electrical properties of conjugated polymer-carbon nanotube composite are discussed. Multi-walled carbon nanotube-polypyrrole nanocomposites were synthesized by electrochemical polymerization of monomers in the presence of different amounts of MWNTs using sodium dodecylbenzensulfonate (SDBS) as surfactant at room temperature and normal pressure. Field emission scanning electron microscopy (FESEM) indicates that the polymer is wrapped around the nanotubes. Measurement of the nonlinear refractive indices (n(2)) and the nonlinear absorption (β) of the samples with different MWNT concentrations measurements were performed by a single Z-scan method using continuous wave (CW) laser beam excitation wavelength of λ = 532 nm. The results show that both nonlinear optical parameters increased with increasing the concentration of MWNTs. The third order nonlinear susceptibilities were also calculated and found to follow the same trend as n(2) and β. In addition, the conductivity of the composite film was found to increase rapidly with the increase in the MWNT concentration.

  5. Theory of viscoelasticity an introduction

    CERN Document Server

    Christensen, R

    1982-01-01

    Theory of Viscoelasticity: An Introduction, Second Edition discusses the integral form of stress strain constitutive relations. The book presents the formulation of the boundary value problem and demonstrates the separation of variables condition.The text describes the mathematical framework to predict material behavior. It discusses the problems to which integral transform methods do not apply. Another topic of interest is the thermoviscoelastic stress analysis. The section that follows describes the heat conduction, glass transition criterion, viscoelastic Rayleigh waves, optimal str

  6. Noise Reduction Evaluation of Multi-Layered Viscoelastic Infinite Cylinder under Acoustical Wave Excitation

    Directory of Open Access Journals (Sweden)

    M.R. Mofakhami

    2008-01-01

    Full Text Available In this paper sound transmission through the multilayered viscoelastic air filled cylinders subjected to the incident acoustic wave is studied using the technique of separation of variables on the basis of linear three dimensional theory of elasticity. The effect of interior acoustic medium on the mode maps (frequency vs geometry and noise reduction is investigated. The effects of internal absorption and external moving medium on noise reduction are also evaluated. The dynamic viscoelastic properties of the structure are rigorously taken into account with a power law technique that models the viscoelastic damping of the cylinder. A parametric study is also performed for the two layered infinite cylinders to obtain the effect of viscoelastic layer characteristics such as thickness, material type and frequency dependency of viscoelastic properties on the noise reduction. It is shown that using constant and frequency dependent viscoelastic material with high loss factor leads to the uniform noise reduction in the frequency domain. It is also shown that the noise reduction obtained for constant viscoelastic material property is subjected to some errors in the low frequency range with respect to those obtained for the frequency dependent viscoelastic material.

  7. Nonlinear acoustic properties of ex vivo bovine liver and the effects of temperature and denaturation

    International Nuclear Information System (INIS)

    Jackson, E J; Coussios, C-C; Cleveland, R O

    2014-01-01

    Thermal ablation by high intensity focused ultrasound (HIFU) has a great potential for the non-invasive treatment of solid tumours. Due to the high pressure amplitudes involved, nonlinear acoustic effects must be understood and the relevant medium property is the parameter of nonlinearity B/A. Here, B/A was measured in ex vivo bovine liver, over a heating/cooling cycle replicating temperatures reached during HIFU ablation, adapting a finite amplitude insertion technique, which also allowed for measurement of sound-speed and attenuation. The method measures the nonlinear progression of a plane wave through liver and B/A was chosen so that numerical simulations matched the measured waveforms. To create plane-wave conditions, sinusoidal bursts were transmitted by a 100 mm diameter 1.125 MHz unfocused transducer and measured using a 15 mm diameter 2.25 MHz broadband transducer in the near field. Attenuation and sound-speed were calculated using a reflected pulse from the smaller transducer using the larger transducer as the reflecting interface. Results showed that attenuation initially decreased with heating then increased after denaturation, the sound-speed initially increased with temperature and then decreased, and B/A showed an increase with temperature but no significant post-heating change. The B/A data disagree with other reports that show a significant change and we suggest that any nonlinear enhancement in the received ultrasound signal post-treatment is likely due to acoustic cavitation rather than changes in tissue nonlinearity. (paper)

  8. Second order nonlinear optical properties of zinc oxide films deposited by low temperature dual ion beam sputtering

    International Nuclear Information System (INIS)

    Larciprete, M.C.; Passeri, D.; Michelotti, F.; Paoloni, S.; Sibilia, C.; Bertolotti, M.; Belardini, A.; Sarto, F.; Somma, F.; Lo Mastro, S.

    2005-01-01

    We investigated second order optical nonlinearity of zinc oxide thin films, grown on glass substrates by the dual ion beam sputtering technique under different deposition conditions. Linear optical characterization of the films was carried out by spectrophotometric optical transmittance and reflectance measurements, giving the complex refractive index dispersion. Resistivity of the films was determined using the four-point probe sheet resistance method. Second harmonic generation measurements were performed by means of the Maker fringes technique where the fundamental beam was originated by nanosecond laser at λ=1064 nm. We found a relatively high nonlinear optical response, and evidence of a dependence of the nonlinear coefficient on the deposition parameters for each sample. Moreover, the crystalline properties of the films were investigated by x-ray diffraction measurements and correlation with second order nonlinearity were analyzed. Finally, we investigated the influence of the oxygen flow rate during the deposition process on both the second order nonlinearity and the structural properties of the samples

  9. Syntheses, structures and third-order non-linear optical properties of homometal clusters containing molybdenum

    International Nuclear Information System (INIS)

    Li Yong; Lu Jing; Cui Xiaobing; Xu Jiqing; Li Kechang; Sun Huaying; Li Guanghua; Pan Lingyun; Yang Qingxin

    2005-01-01

    Both the homometal cluster [P(ph 4 )] 2 [Mo 2 O 2 (μ-S) 2 (S 2 ) 2 ] (1) and [Mo 2 O 2 (μ-S) 2 (Et 2 dtc) 2 ] (2) (Et 2 dtc=diethyl-dithiocarbamate) were successfully synthesized by low-temperature solid-state reactions. X-ray single-crystal diffraction studies suggest that compound (1) is a dinuclear anion cluster, and compound (2) is a dinuclear neutral cluster. The two compounds were characterized by elemental analyses, IR spectra and UV-Vis spectra. The third-order non-linear optical (NLO) properties of the clusters were also investigated and all exhibited nice non-linear absorption and self-defocusing performance with moduli of the hyperpolarizabilities 5.145x10 -30 esu for (1) and 5.428x10 -30 esu for (2)

  10. Nonlinear impulsive system of fed-batch culture in fermentative production and its properties

    International Nuclear Information System (INIS)

    Gao Caixia; Li Kezan; Feng Enmin; Xiu Zhilong

    2006-01-01

    In this study, the nonlinear dynamical system of fed-batch fermentation is investigated in the process of bio-dissimilation of glycerol to 1,3-propanediol by Klebsiella pneumoniae. Considering the abrupt increase of glycerol in fed-batch culture, this paper proposes a nonlinear impulsive system of the culture process, which is fit for formulating the factual fermentation better than the continuous models in being. We study the questions of existence and properties of mild solutions for the system and the continuous dependence of solutions on initial values and the controllable variable. Finally, the numerical simulations show that the errors between experimental and computational values using the impulsive system are less than those using the previous continuous system

  11. Synthesis and nonlinear optical property of polycrystalline MnTeMoO{sub 6}

    Energy Technology Data Exchange (ETDEWEB)

    Jin, Chengguo [Yibin University, Key Laboratory of Computational Physics of Sichuan Province, Yibin (China); Yibin University, School of Physics and Electronic Engineering, Yibin (China)

    2017-04-15

    Polycrystalline MnTeMoO{sub 6} powder has been synthesized by a new approach that MnO{sub 2} is used as the manganese source. The transformation mechanism of manganese ions in the new approach has been discussed. The nonlinear optical property of polycrystalline MnTeMoO{sub 6} has been investigated, and compared with single-crystalline samples. The transformation Mn{sup 4+} → Mn{sup 2+} may be formed directly without stable intermediates, and TeO{sub 2} may serve as catalyst. The SHG response of polycrystalline MnTeMoO{sub 6} powder is worse than that of single-crystalline powder in the same particle size distribution as its pseudo-size. The results indicate that it should pay special attention with the pseudo-size of polycrystalline powder when the potential nonlinear optical materials are screened by powder second harmonic generation measurements. (orig.)

  12. Nonlinearity and Fractal Properties of Climate Change during the Past 500 Years in Northwestern China

    Directory of Open Access Journals (Sweden)

    Shiquan Wan

    2016-01-01

    Full Text Available By using detrended fluctuation analysis (DFA, the present paper analyzed the nonlinearity and fractal properties of tree-ring records from two types of trees in northwestern China, and then we disclosed climate change characteristics during the past 500 years in this area. The results indicate that climate change in northwestern China displayed a long-range correlation (LRC, which can exist over time span of 100 years or longer. This conclusion provides a theoretical basis for long-term climate predictions. Combining the DFA results obtained from daily temperatures records at the Xi’an meteorological observation station, which is near the southern peak of the Huashan Mountains, self-similarities widely existed in climate change on monthly, seasonal, annual, and decadal timescales during the past 500 years in northwestern China, and this change was a typical nonlinear process.

  13. Tuning the dielectric properties of thiourea analog crystals for efficient nonlinear optical applications

    International Nuclear Information System (INIS)

    Sabari Girisun, T.C.; Dhanuskodi, S.

    2010-01-01

    Materials with low dielectric constant have attracted a great deal of interest in the field of nonlinear applications and microelectronic industry. Metal complexes of thiourea with group II transition metals (Zn, Cd) as central atom and period III elements (S, Cl) were synthesized by chemical reaction method and single crystals were grown from aqueous solution by slow evaporation method. By parallel plate capacitor technique, the dielectric response, dissipation factor, ac conductivity and impedance of virgin and metal complexes have been studied in the frequency (100 Hz to 5 MHz) and temperature (303-423 K) ranges. Metal complexes of thiourea with cadmium substitute have a low dielectric constant less than 10. Also the presence of chlorine in the metal complex induces noncentro symmetric structure. Hence the role of group II transition metals and period III elements in tuning the dielectric properties for efficient nonlinear applications has been studied.

  14. Synthesis and nonlinear optical property of polycrystalline MnTeMoO_6

    International Nuclear Information System (INIS)

    Jin, Chengguo

    2017-01-01

    Polycrystalline MnTeMoO_6 powder has been synthesized by a new approach that MnO_2 is used as the manganese source. The transformation mechanism of manganese ions in the new approach has been discussed. The nonlinear optical property of polycrystalline MnTeMoO_6 has been investigated, and compared with single-crystalline samples. The transformation Mn"4"+ → Mn"2"+ may be formed directly without stable intermediates, and TeO_2 may serve as catalyst. The SHG response of polycrystalline MnTeMoO_6 powder is worse than that of single-crystalline powder in the same particle size distribution as its pseudo-size. The results indicate that it should pay special attention with the pseudo-size of polycrystalline powder when the potential nonlinear optical materials are screened by powder second harmonic generation measurements. (orig.)

  15. Investigation on the properties of the formation and coherence of intense fringe near nonlinear medium slab

    Directory of Open Access Journals (Sweden)

    Yonghua Hu

    2018-03-01

    Full Text Available Near medium intense (NMI fringe is a kind of intense fringe which can be formed near Kerr medium in high-power laser beam propagation. The formation properties of NMI fringe and the relations between NMI fringe and related important parameters are systematically investigated. It is found that it is the co-existence of two wirelike phase-typed scatterers in the incident beam spot which is mainly responsible for the high intensity of NMI fringe. From the viewpoint of coherent superposition, the formation process of NMI fringe is analyzed, and the mechanism that NMI fringe is formed by the coherent superposition of the localized bright fringes in the exit field of Kerr medium slab is demonstrated. The fluctuations of NMI fringe properties with beam wavelength, scatterer spacing and object distance are studied, the coherence of NMI fringe are revealed, and the approximate periodicity of the appearance of remarkable NMI fringe for these parameters are obtained. Especially, it is found that the intensity of NMI fringe is very sensitive to scatterer spacing. Besides, the laws about how NMI fringe properties will be changed by the modulation properties of scatterers and the medium thickness are demonstrated. Keywords: High-power laser beam, Nonlinear propagation, Kerr medium, Small-scale scatterer, Nonlinear imaging

  16. Indentation analysis of active viscoelastic microplasmodia of P. polycephalum

    Science.gov (United States)

    Fessel, Adrian; Oettmeier, Christina; Wechsler, Klaus; Döbereiner, Hans-Günther

    2018-01-01

    Simple organisms like Physarum polycephalum realize complex behavior, such as shortest path optimization or habituation, via mechanochemical processes rather than by a network of neurons. A full understanding of these phenomena requires detailed investigation of the underlying mechanical properties. To date, micromechanical measurements on P. polycephalum are sparse and lack reproducibility. This prompts study of microplasmodia, a reproducible and homogeneous form of P. polycephalum that resembles the plasmodial ectoplasm responsible for mechanical stability and generation of forces. We combine investigation of ultra-structure and dimension of P. polycephalum with the analysis of data obtained by indentation of microplasmodia, employing a novel nonlinear viscoelastic scaling model that accounts for finite dimension of the sample. We identify the multi-modal distribution of parameters such as Young’s moduls, Poisson’s ratio, and relaxation times associated with viscous processes that cover five orders of magnitude. Results suggest a characterization of microplasmodia as porous, compressible structures that act like elastic solids with high Young’s modulus on short time scales, whereas on long time-scales and upon repeated indentation viscous behavior dominates and the effective modulus is significantly decreased. Furthermore, Young’s modulus is found to oscillate in phase with shape of microplasmodia, emphasizing that modeling P. polycephalum oscillations as a driven oscillator with constant moduli is not practicable.

  17. Analysis on nonlinear optical properties of Cd (Zn) Se quantum dots synthesized using three different stabilizing agents

    Science.gov (United States)

    J, Joy Sebastian Prakash; G, Vinitha; Ramachandran, Murugesan; Rajamanickam, Karunanithi

    2017-10-01

    Three different stabilizing agents, namely, L-cysteine, Thioglycolic acid and cysteamine hydrochloride were used to synthesize Cd(Zn)Se quantum dots (QDs). It was characterized using UV-vis spectroscopy, x-ray diffraction (XRD) and transmission electron microscopy (TEM). The non-linear optical properties (non-linear absorption and non-linear refraction) of synthesized Cd(Zn)Se quantum dots were studied with z-scan technique using diode pumped continuous wavelaser system at a wavelength of 532 nm. Our (organic) synthesized quantum dots showed optical properties similar to the inorganic materials reported elsewhere.

  18. Generalized Fractional Derivative Anisotropic Viscoelastic Characterization

    Directory of Open Access Journals (Sweden)

    Harry H. Hilton

    2012-01-01

    Full Text Available Isotropic linear and nonlinear fractional derivative constitutive relations are formulated and examined in terms of many parameter generalized Kelvin models and are analytically extended to cover general anisotropic homogeneous or non-homogeneous as well as functionally graded viscoelastic material behavior. Equivalent integral constitutive relations, which are computationally more powerful, are derived from fractional differential ones and the associated anisotropic temperature-moisture-degree-of-cure shift functions and reduced times are established. Approximate Fourier transform inversions for fractional derivative relations are formulated and their accuracy is evaluated. The efficacy of integer and fractional derivative constitutive relations is compared and the preferential use of either characterization in analyzing isotropic and anisotropic real materials must be examined on a case-by-case basis. Approximate protocols for curve fitting analytical fractional derivative results to experimental data are formulated and evaluated.

  19. A computational study on the electronic and nonlinear optical properties of graphyne subunit

    Energy Technology Data Exchange (ETDEWEB)

    Bahat, Mehmet, E-mail: bahat@gazi.edu.tr; Güney, Merve Nurhan, E-mail: merveng87@gmail.com; Özbay, Akif, E-mail: aozbay@gazi.edu.tr [Department of Physics, Gazi University, Ankara, 06500 (Turkey)

    2016-03-25

    After discovery of graphene, it has been considered as basic material for the future nanoelectronic devices. Graphyne is a two- dimensional carbon allotropes as graphene which expected that its electronic properties is potentialy superior to graphene. The compound C{sub 24}H{sub 12} (tribenzocyclyne; TBC) is a substructure of graphyne. The electronic, and nonlinear optical properties of the C{sub 24}H{sub 12} and its some fluoro derivatives were calculated. The calculated properties are electric dipole moment, the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) energies, polarizability and first hyperpolarizability. All calculations were performed at the B3LYP/6-31+G(d,p) level.

  20. Pearling Instabilities of a Viscoelastic Thread

    Science.gov (United States)

    Deblais, A.; Velikov, K. P.; Bonn, D.

    2018-05-01

    Pearling instabilities of slender viscoelastic threads have received much attention, but remain incompletely understood. We study the instabilities in polymer solutions subject to uniaxial elongational flow. Two distinctly different instabilites are observed: beads on a string and blistering. The beads-on-a-string structure arises from a capillary instability whereas the blistering instability has a different origin: it is due to a coupling between stress and polymer concentration. By varying the temperature to change the solution properties we elucidate the interplay between flow and phase separation.

  1. Direct and inverse scattering for viscoelastic media

    International Nuclear Information System (INIS)

    Ammicht, E.; Corones, J.P.; Krueger, R.J.

    1987-01-01

    A time domain approach to direct and inverse scattering problems for one-dimensional viscoelastic media is presented. Such media can be characterized as having a constitutive relation between stress and strain which involves the past history of the strain through a memory function, the relaxation modulus. In the approach in this article, the relaxation modulus of a material is shown to be related to the reflection properties of the material. This relation provides a constructive algorithm for direct and inverse scattering problems. A numerical implementation of this algorithm is tested on several problems involving realistic relaxation moduli

  2. Viscoelastic behavior of discrete human collagen fibrils

    DEFF Research Database (Denmark)

    Svensson, René; Hassenkam, Tue; Hansen, Philip

    2010-01-01

    Whole tendon and fibril bundles display viscoelastic behavior, but to the best of our knowledge this property has not been directly measured in single human tendon fibrils. In the present work an atomic force microscopy (AFM) approach was used for tensile testing of two human patellar tendon...... saline, cyclic testing was performed in the pre-yield region at different strain rates, and the elastic response was determined by a stepwise stress relaxation test. The elastic stress-strain response corresponded to a second-order polynomial fit, while the viscous response showed a linear dependence...

  3. Postseismic viscoelastic surface deformation and stress. Part 1: Theoretical considerations, displacement and strain calculations

    Science.gov (United States)

    Cohen, S. C.

    1979-01-01

    A model of viscoelastic deformations associated with earthquakes is presented. A strike-slip fault is represented by a rectangular dislocation in a viscoelastic layer (lithosphere) lying over a viscoelastic half-space (asthenosphere). Deformations occur on three time scales. The initial response is governed by the instantaneous elastic properties of the earth. A slower response is associated with viscoelastic relaxation of the lithosphere and a yet slower response is due to viscoelastic relaxation of the asthenosphere. The major conceptual contribution is the inclusion of lithospheric viscoelastic properties into a dislocation model of earthquake related deformations and stresses. Numerical calculations using typical fault parameters reveal that the postseismic displacements and strains are small compared to the coseismic ones near the fault, but become significant further away. Moreover, the directional sense of the deformations attributable to the elastic response, the lithospheric viscoelastic softening, and the asthenospheric viscoelastic flow may differ and depend on location and model details. The results and theoretical arguments suggest that the stress changes accompanying lithospheric relaxation may also be in a different sense than and be larger than the strain changes.

  4. Structural, electronic, linear, and nonlinear optical properties of ZnCdTe{sub 2} chalcopyrite

    Energy Technology Data Exchange (ETDEWEB)

    Ouahrani, Tarik [Laboratoire de Physique Theorique, Universite de Tlemcen, B.P. 230, Tlemcen 13000 (Algeria); Reshak, Ali H. [Institute of Physical Biology, South Bohemia University, Nove Hrady 37333 (Czech Republic); School of Microelectronic Engineering, University of Malaysia Perlis (UniMAP), Block A, Kompleks Pusat Pengajian, 02600 Arau Jejawi, Perlis (Malaysia); Khenata, R. [Laboratoire de Physique Quantique et de Modelisation Mathematique, Universite de Mascara, Mascara 29000 (Algeria); Department of Physics and Astronomy, Faculty of Science, King Saud University, P.O. Box 2455, Riyadh 11451 (Saudi Arabia); Baltache, H.; Amrani, B. [Laboratoire de Physique Quantique et de Modelisation Mathematique, Universite de Mascara, Mascara 29000 (Algeria); Bouhemadou, A. [Department of Physics and Astronomy, Faculty of Science, King Saud University, P.O. Box 2455, Riyadh 11451 (Saudi Arabia); Faculty of Sciences, Department of Physics, University of Setif, Setif 19000 (Algeria)

    2011-03-15

    We report results of first-principles density functional calculations using the full-potential linearized augmented plane wave method. The generalized gradient approximation (GGA) and the Engel-Vosko-GGA (EV-GGA) formalism were used for the exchange-correlation energy to calculate the structural, electronic, linear, and nonlinear optical properties of the chalcopyrite ZnCdTe{sub 2} compound. The valence band maximum and the conduction band minimum are located at the {gamma}-point, resulting in a direct band gap of about 0.71 eV for GGA and 1.29 eV for EV-GGA. The results of bulk properties, such as lattice parameters (a, c, and u), bulk modulus B, and its pressure derivative B' are evaluated. The optical properties of this compound, namely the real and the imaginary parts of the dielectric function, reflectivity, and refractive index, show a considerable anisotropy as a consequence ZnCdTe{sub 2} posseses a strong birefringence. In addition, the extinction coefficient, the electron energy loss function, and the nonlinear susceptibility are calculated and their spectra are analyzed. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  5. Non-linear optical techniques and optical properties of condensed molecular systems

    Science.gov (United States)

    Citroni, Margherita

    2013-06-01

    Structure, dynamics, and optical properties of molecular systems can be largely modified by the applied pressure, with remarkable consequences on their chemical stability. Several examples of selective reactions yielding technologically attractive products can be cited, which are particularly efficient when photochemical effects are exploited in conjunction with the structural conditions attained at high density. Non-linear optical techniques are a basic tool to unveil key aspects of the chemical reactivity and dynamic properties of molecules. Their application to high-pressure samples is experimentally challenging, mainly because of the small sample dimensions and of the non-linear effects generated in the anvil materials. In this talk I will present results on the electronic spectra of several aromatic crystals obtained through two-photon induced fluorescence and two-photon excitation profiles measured as a function of pressure (typically up to about 25 GPa), and discuss the relationship between the pressure-induced modifications of the electronic structure and the chemical reactivity at high pressure. I will also present the first successful pump-probe infrared measurement performed as a function of pressure on a condensed molecular system. The system under examination is liquid water, in a sapphire anvil cell, up to 1 GPa along isotherms at 298 and 363 K. These measurements give a new enlightening insight into the dynamical properties of low- and high-density water allowing a definition of the two structures.

  6. Application of nonlinear rheology to assess the effect of secondary nanofiller on network structure of hybrid polymer nanocomposites

    Science.gov (United States)

    Kamkar, Milad; Aliabadian, Ehsan; Shayesteh Zeraati, Ali; Sundararaj, Uttandaraman

    2018-02-01

    Carbon nanotube (CNT)/polymer nanocomposites exhibit excellent electrical properties by forming a percolated network. Adding a secondary filler can significantly affect the CNTs' network, resulting in changing the electrical properties. In this work, we investigated the effect of adding manganese dioxide nanowires (MnO2NWs) as a secondary nanofiller on the CNTs' network structure inside a poly(vinylidene fluoride) (PVDF) matrix. Incorporating MnO2NWs to PVDF/CNT samples produced a better state of dispersion of CNTs, as corroborated by light microscopy and transmission electron microscopy. The steady shear and oscillatory shear flows were employed to obtain a better insight into the nanofiller structure and viscoelastic behavior of the nanocomposites. The transient response under steady shear flow revealed that the stress overshoot of hybrid nanocomposites (two-fillers), PVDF/CNT/MnO2NWs, increased dramatically in comparison to binary nanocomposites (single-filler), PVDF/CNT and PVDF/MnO2NWs. This can be attributed to microstructural changes. Large amplitude oscillatory shear characterization was also performed to further investigate the effect of the secondary nanofiller on the nonlinear viscoelastic behavior of the samples. The nonlinear rheological observations were explained using quantitative nonlinear parameters [strain-stiffening ratio (S) and shear-thickening ratio (T)] and Lissajous-Bowditch plots. Results indicated that a more rigid nanofiller network was formed for the hybrid nanocomposites due to the better dispersion state of CNTs and this led to a more nonlinear viscoelastic behavior.

  7. Nonlinear properties of double and triple barrier resonant tunneling structures in the sub-THz range

    International Nuclear Information System (INIS)

    Karuzskij, A.L.; Perestoronin, A.V.; Volchkov, N.A.

    2012-01-01

    The high-frequency nonlinear properties of GaAs/AlAs resonant tunneling diode (RTD) nanostructures and perspectives of implementation of the quantum regime of amplification in such structures, which is especially efficient in the range of sub-THz and THz ranges, are investigated. It is shown that in a triple barrier RTD the symmetry between the processes of amplification and dissipation can be avoided because of the interaction of an electromagnetic wave with both of resonant states in two quantum wells, that results in the significant growth of an RTD efficiency [ru

  8. Phase Properties of Photon-Added Coherent States for Nonharmonic Oscillators in a Nonlinear Kerr Medium

    Science.gov (United States)

    Jahanbakhsh, F.; Honarasa, G.

    2018-04-01

    The potential of nonharmonic systems has several applications in the field of quantum physics. The photon-added coherent states for annharmonic oscillators in a nonlinear Kerr medium can be used to describe some quantum systems. In this paper, the phase properties of these states including number-phase Wigner distribution function, Pegg-Barnett phase distribution function, number-phase squeezing and number-phase entropic uncertainty relations are investigated. It is found that these states can be considered as the nonclassical states.

  9. The cardiorespiratory interaction: a nonlinear stochastic model and its synchronization properties

    Science.gov (United States)

    Bahraminasab, A.; Kenwright, D.; Stefanovska, A.; McClintock, P. V. E.

    2007-06-01

    We address the problem of interactions between the phase of cardiac and respiration oscillatory components. The coupling between these two quantities is experimentally investigated by the theory of stochastic Markovian processes. The so-called Markov analysis allows us to derive nonlinear stochastic equations for the reconstruction of the cardiorespiratory signals. The properties of these equations provide interesting new insights into the strength and direction of coupling which enable us to divide the couplings to two parts: deterministic and stochastic. It is shown that the synchronization behaviors of the reconstructed signals are statistically identical with original one.

  10. Nonlinear-Optical and Fluorescent Properties of Ag Aqueous Colloid Prepared by Silver Nitrate Reduction

    Directory of Open Access Journals (Sweden)

    Xiaoqiang Zhang

    2010-01-01

    Full Text Available The nonlinear-optical properties of metal Ag colloidal solutions, which were prepared by the reduction of silver nitrate, were investigated using Z-scan method. Under picosecond 532 nm excitation, the Ag colloidal solution exhibited negative nonlinear refractive index (n2=−5.17×10−4 cm2/W and reverse saturable absorption coefficient (β=4.32 cm/GW. The data fitting result of optical limiting (OL response of metal Ag colloidal solution indicated that the nonlinear absorption was attributed to two-photon absorption effect at 532 nm. Moreover, the fluorescence emission spectra of Ag colloidal solution were recorded under excitations at both 280 nm and 350 nm. Two fluorescence peaks, 336 nm and 543 nm for 280 nm excitation, while 544 nm and 694 nm for 350 nm excitation, were observed.

  11. Investigation on the structural and nonlinear optical properties of Pt doped TiO2 nanoparticles

    International Nuclear Information System (INIS)

    Rahulan, K. Mani; Padmanathan, N.; Vinitha, G.; Kanakam, Charles Christopher

    2013-01-01

    Graphical abstract: The open aperture Z-scan traces of Pt doped TiO 2 nanoparticles at different Pt concentrations were carried out at an irradiation wavelength of 532 nm. It was numerically found that, two photon absorption (TPA) type process gives the best fit to the obtained open aperture Z-scan data. The nonlinear transmission was found to be of third order as it fits to a two-photon absorption. The optical limiting performances of nanoparticles were greatly enhanced with increased volume ratio of Pt. Increasing particle size reduced the limiting threshold and enhanced the optical limiting performance. - Highlights: • Pt doped TiO 2 nanoparticles with different concentrations of Pt have been synthesized by sol–gel method. • The average fluorescence lifetime decreases as the volume fraction of Pt dopant increases. • The effects of Pt content on the optical limiting property were investigated by open aperture Z-scan measurements done at 532 nm using 5 ns laser pulses. • The values of the third-order nonlinearities of nanoparticles are interesting from the application point of view which could be used as a potential candidate for the application of nonlinear optical device. - Abstract: Pt doped TiO 2 nanoparticles with different concentrations of Pt were prepared by sol–gel method. X-ray diffraction (XRD) study reveals that the samples have a homogeneous anatase phase tetragonal system and the lattice parameter analysis indicates that Pt ions substitute into the lattice of TiO 2 . The addition of dopant increases the growth of TiO 2 grains, agglomerates them and shifts the absorption band of TiO 2 from ultraviolet to visible region. The incorporation of Pt in TiO 2 is also confirmed by fluorescence quenching and the fluorescence lifetime decreases as the volume fraction of Pt dopant increases. Open aperture Z-scan measurements done at 532 nm using 7 ns laser pulses show nonlinear absorption which arises from an effective two photon absorption process

  12. Impact load time histories for viscoelastic missiles

    International Nuclear Information System (INIS)

    Stoykovich, M.

    1977-01-01

    Generation of the impact load time history at the contact point between a viscoelastic missile and its targets is presented. In the past, in the case of aircraft striking containment shell structure, the impact load time history was determined on the basis of actual measurements by subjecting a rigid wall to aircraft crash. The effects of elastic deformation of the target upon the impact load time history is formulated in this paper. The missile is idealized by a linear mass-spring-dashpot combination using viscoelastic models. These models can readily be processed taking into account the elastic as well as inelastic deformations of the missiles. The target is assumed to be either linearly elastic or rigid. In the case of the linearly elastic target, the normal mode theory is used to express the time-dependent displacements of the target which is simulated by lumped masses, elastic properties and dashpots in discrete parts. In the case of Maxwell viscoelastic model, the time-dependent displacements of the missile and the target are given in terms of the unknown impact load time history. This leads to an integral equation which may be solved by Laplace transformation. The normal mode theory is provided. The target structure may be composed of different materials with different components. Concrete and steel structural components have inherently different viscous friction damping properties. Hence, the equivalent modal damping depends on the degree of participation of these components in the modal response. An approximate rule for determining damping in any vibration mode by weighting the damping of each component according to the modal energy stored in each component is considered

  13. Cutting edge science: Laser surgery illuminates viscoelasticity of merotelic kinetochores.

    Science.gov (United States)

    Cabello, Simon; Gachet, Yannick; Tournier, Sylvie

    2016-03-28

    Increasing evidence in eukaryotic cells suggests that mechanical forces are essential for building a robust mitotic apparatus and correcting inappropriate chromosome attachments. In this issue, Cojoc et al. (2016. J. Cell Biol., http://dx.doi.org/10.1083/jcb.201506011) use laser microsurgery in vivo to measure and study the viscoelastic properties of kinetochores. © 2016 Cabello.

  14. Third-order nonlinear optical properties of the poly(methyl methacrylate)-phenothiazinium dye hybrid thin films

    International Nuclear Information System (INIS)

    Sun, Ru; Lu, Yue-Ting; Yan, Bao-Long; Lu, Jian-Mei; Wu, Xing-Zhi; Song, Ying-Lin; Ge, Jian-Feng

    2014-01-01

    The third-order nonlinear optical properties of poly(methyl methacrylate) films doped with charge flowable 3,7-di(piperidinyl)phenothiazin-5-ium chloride, which tested by Z-scan method with nanosecond laser beam at 532 nm, are reported. Large third-order nonlinear optical susceptibilities (up to 10 −7 esu) and high second hyperpolarizabilities (up to 10 −27 esu) are found. The third-order nonlinear absorptions change from reverse saturated absorptions to saturated absorptions with different percentage of the phenothiazinium dye in the poly(methyl methacrylate) films, which can be explained by the accumulation phenomenon of the phenothiazinium. The results suggest that the phenothiazinium salt is a promising material for third order non-linear applications. - Highlights: • Phenothiazinium containing optical films • Strong third-order nonlinear optical (NLO) absorption • Large third-order NLO susceptibilities

  15. Calculations on nonlinear optical properties for large systems the elongation method

    CERN Document Server

    Gu, Feng Long; Springborg, Michael; Kirtman, Bernard

    2014-01-01

    For design purposes one needs to relate the structure of proposed materials to their NLO (nonlinear optical) and other properties, which is a situation where theoretical approaches can be very helpful in providing suggestions for candidate systems that subsequently can be synthesized and studied experimentally. This brief describes the quantum-mechanical treatment of the response to one or more external oscillating electric fields for molecular and macroscopic, crystalline systems. To calculate NLO properties of large systems, a linear scaling generalized elongation method for the efficient and accurate calculation is introduced. The reader should be aware that this treatment is particularly feasible for complicated three-dimensional and/or delocalized systems that are intractable when applied to conventional or other linear scaling methods.

  16. Alfven wave. [Book on linear and nonlinear properties for fusion applications

    Energy Technology Data Exchange (ETDEWEB)

    Hasegawa, A.; Uberoi, C.

    1978-11-01

    Seven chapters are included. Chapters 1 and 2 introduce the Alfven wave and describe its linear properties in a homogeneous medium. Chapters 3 and 4 cover the effects of inhomogeneities on these linear properties. Particular emphasis is placed on the appearance of a continuum spectrum and the associated absorption of the Alfven wave which arise due to the inhomogeneity. The explanation of the physical origin of absorption is given using kinetic theory. Chapter 5 is devoted to the associated plasma instabilities. Nonlinear effects discussed in Chapter 6 include quasilinear diffusion, decay, a solitary wave, and a modulational instability. The principles of Alfven wave heating, a design example and present-day experimental results are described in Chapter 7.

  17. Nonlinear optical properties of systems based on ruthenium(II) tetra-15-crown-5-phthalocyaninate

    International Nuclear Information System (INIS)

    Grishina, A.D.; Gorbunova, Yu.G.; Enakieva, Yu.Yu.; Krivenko, T.V.; Savel'ev, V.V.; Vannikov, A.V.; Tsivadze, A.Yu.

    2008-01-01

    The third-order nonlinear optical properties of the ruthenium (II) complex with tetra-15-crown-5-phthalocyanine and axially coordinated triethylenediamine molecules (R 4 Pc)Ru(TED) 2 were analyzed by means of the z-scanning technique. A solution of (R 4 Pc)Ru(TED) 2 in tetrachloroethane was exposed to nanosecond laser pulses at a wavelength of 1064 nm. It was found that the third-order molecular polarizability of the Ru(II) complex is 4.5 x 10 -32 cm 4 /C (esu). The polarizability per molecule increases by a factor of 3.6 when the single molecule occurs in a supramolecular assembly of (R 4 Pc)Ru(TED) 2 complexes. The photoelectric and photorefractive properties at 1064 nm of polymer composites, determined by the supramolecular assemblies that exhibits optical absorption and photoelectric sensitivity in the near IR region, are reported [ru

  18. Calibration of trapping force and response function of optical tweezers in viscoelastic media

    DEFF Research Database (Denmark)

    Fischer, Mario; Berg-Sørensen, Kirstine

    2007-01-01

    , 594) is not possible as the viscoelastic properties of the bio-active medium are a priori unknown. Here, we present an approach that neither requires explicit assumptions about the size of the trapped particle nor about the viscoelastic properties of the medium. Instead, the interaction between...... the medium and the trapped particle is described in a general manner, through velocity and acceleration memory. Our method is applicable to general, at least locally homogeneous, viscoelastic media. The procedure combines active and passive approaches by the application of Onsager's regression hypothesis...

  19. Characterization of cell mechanical properties by computational modeling of parallel plate compression.

    Science.gov (United States)

    McGarry, J P

    2009-11-01

    A substantial body of work has been reported in which the mechanical properties of adherent cells were characterized using compression testing in tandem with computational modeling. However, a number of important issues remain to be addressed. In the current study, using computational analyses, the effect of cell compressibility on the force required to deform spread cells is investigated and the possibility that stiffening of the cell cytoplasm occurs during spreading is examined based on published experimental compression test data. The effect of viscoelasticity on cell compression is considered and difficulties in performing a complete characterization of the viscoelastic properties of a cell nucleus and cytoplasm by this method are highlighted. Finally, a non-linear force-deformation response is simulated using differing linear viscoelastic properties for the cell nucleus and the cell cytoplasm.

  20. Measurement of tissue viscoelasticity with ultrasound

    Science.gov (United States)

    Greenleaf, J. F.; Alizad, A.

    2017-02-01

    Tissue properties such as elasticity and viscosity have been shown to be related to such tissue conditions as contraction, edema, fibrosis, and fat content among others. Magnetic Resonance Elastography has shown outstanding ability to measure the elasticity and in some cases the viscosity of tissues, especially in the liver, providing the ability to stage fibrotic liver disease similarly to biopsy. We discuss ultrasound methods of measuring elasticity and viscosity in tissues. Many of these methods are becoming widely available in the extant ultrasound machines distributed throughout the world. Some of the methods to be discussed are in the developmental stage. The advantages of the ultrasound methods are that the imaging instruments are widely available and that many of the viscoelastic measurements can be made during a short addition to the normal ultrasound examination time. In addition, the measurements can be made by ultrasound repetitively and quickly allowing evaluation of dynamic physiologic function in circumstances such as muscle contraction or artery relaxation. Measurement of viscoelastic tissue mechanical properties will become a consistent part of clinical ultrasound examinations in our opinion.

  1. Local linear viscoelasticity of confined fluids.

    Science.gov (United States)

    Hansen, J S; Daivis, P J; Todd, B D

    2007-04-14

    In this paper the authors propose a novel method to study the local linear viscoelasticity of fluids confined between two walls. The method is based on the linear constitutive equation and provides details about the real and imaginary parts of the local complex viscosity. They apply the method to a simple atomic fluid undergoing zero mean oscillatory flow using nonequilibrium molecular dynamics simulations. The method shows that the viscoelastic properties of the fluid exhibit dramatic spatial changes near the wall-fluid boundary due to the high density in this region. It is also shown that the real part of the viscosity converges to the frequency dependent local shear viscosity sufficiently far away from the wall. This also provides valuable information about the transport properties in the fluid, in general. The viscosity is compared with predictions from the local average density model. The two methods disagree in that the local average density model predicts larger viscosity variations near the wall-fluid boundary than what is observed through the method presented here.

  2. Nonlinear absorption properties of some 1,4,8,11,15,18,22,25-octaalkylphthalocyanines and their metallated derivatives

    OpenAIRE

    BLAU, WERNER

    2003-01-01

    PUBLISHED The third-order nonlinear optical properties of a series of 15 unmetallated and metallated 1,4,8,11,15,18,22,25-octaalkylphthalocyanines have been investigated. The palladium-metallated compound is the strongest nonlinear absorber of the series, but, due to its comparatively high linear absorption coefficient, it exhibits a relatively low ratio of excited- to ground-state absorption cross-sections (?) when compared to the other compounds. The highest values for ? were found for d...

  3. Experimental Characterization of Innovative Viscoelastic Foams

    Directory of Open Access Journals (Sweden)

    Massimo Viscardi

    2016-05-01

    Full Text Available The evolutionary trend in the automotive industry has produced over time numerous performance and aesthetic innovations, however, the exponential development related to transportation technologies also introduced new requirements concerning the environmental impact [1]. The awareness of ecological issues has led to a reorganization of the evaluations and the vehicle design, currently aimed at reducing the problems that have emerged in empirical investigations and the parallel increase in environmental solutions. The vehicle renewal process involves targeted technical mutations both to observance of ecology as to the safety and comfort of the driver. New recyclable materials and more resistant have been developed in order to minimize the environmental impact of the vehicle even at the end of the operating life of its components, as well as solutions relating to the reduction of noise pollution generated as a response to the requirements of comfort. Modern research programs on a global scale have set themselves the objective of exploiting the potentiality of innovative technologies in the optimization of vehicles efficiency, the noise reduction and in the consequent reduction of fuel burn. One of the crucial topics in the greening of the new generation automotive sector is therefore the use and development of high vibro-acoustic performance materials. The goal of this research is properly focused on the analysis of viscoelastic materials appointed to increase the damping of the vibrations generated in a vehicle. The use of a viscoelastic material in this context is due to its high property to convert vibrational energy into heat, providing a significant dissipation of the vibrations. Trade-off analyses are performed in order define the stiffness and damping capacity of several viscoelastic foams with different thickness and density.

  4. Viscoelasticity of biofilms and their recalcitrance to mechanical and chemical challenges

    Science.gov (United States)

    Peterson, Brandon W.; He, Yan; Ren, Yijin; Zerdoum, Aidan; Libera, Matthew R.; Sharma, Prashant K.; van Winkelhoff, Arie-Jan; Neut, Danielle; Stoodley, Paul; van der Mei, Henny C.; Busscher, Henk J.

    2015-01-01

    We summarize different studies describing mechanisms through which bacteria in a biofilm mode of growth resist mechanical and chemical challenges. Acknowledging previous microscopic work describing voids and channels in biofilms that govern a biofilms response to such challenges, we advocate a more quantitative approach that builds on the relation between structure and composition of materials with their viscoelastic properties. Biofilms possess features of both viscoelastic solids and liquids, like skin or blood, and stress relaxation of biofilms has been found to be a corollary of their structure and composition, including the EPS matrix and bacterial interactions. Review of the literature on viscoelastic properties of biofilms in ancient and modern environments as well as of infectious biofilms reveals that the viscoelastic properties of a biofilm relate with antimicrobial penetration in a biofilm. In addition, also the removal of biofilm from surfaces appears governed by the viscoelasticity of a biofilm. Herewith, it is established that the viscoelasticity of biofilms, as a corollary of structure and composition, performs a role in their protection against mechanical and chemical challenges. Pathways are discussed to make biofilms more susceptible to antimicrobials by intervening with their viscoelasticity, as a quantifiable expression of their structure and composition. PMID:25725015

  5. Synthesis, multi-nonlinear dielectric resonance and electromagnetic absorption properties of hcp-cobalt particles

    International Nuclear Information System (INIS)

    Wen, Shulai; Liu, Ying; Zhao, Xiuchen; Cheng, Jingwei; Li, Hong

    2014-01-01

    Hcp-cobalt particles were successfully prepared by a liquid phase reduction method, and the microstructure, static magnetic properties, electromagnetic and microwave absorption properties of the cobalt particles with irregular shape were investigated in detail. The measured results indicate that the saturation magnetization was less than that of hcp-Co single crystals, and the coercivity was larger than that of bulk cobalt crystal. The permittivity presents multi-nonlinear dielectric resonance, which may result from the irregular shape containing parts of cutting angle of dodecahedron of cobalt particles. The real part of permeability decreases with the frequency, and the imaginary part has a wide resonant peak. The paraffin-based composite containing 70 wt% cobalt particles possessed strong absorption characteristics with a minimum RL of −38.97 dB at 10.81 GHz and an absorption band with RL under −10 dB from 8.72 to 13.26 GHz when the thickness is 1.8 mm, which exhibits excellent microwave absorption in middle and high frequency. The architectural design of material morphologies is important for improving microwave absorption properties toward future application. - Highlights: • Hcp-cobalt particles were prepared by a liquid phase reduction method. • The saturation magnetization was less than that of hcp-Co single crystals. • The permittivity presents multi-nonlinear dielectric resonance. • The real part of permeability decreases with frequency, and the imaginary part presents a wide resonant peak. • The paraffin-based composite possessed a minimum RL of −38.97 dB at 10.81 GHz

  6. Effect of dielectric medium on the nonclassical properties of nonlinear sphere coherent states

    Directory of Open Access Journals (Sweden)

    E Amooghorban

    2014-04-01

    Full Text Available In order to investigate the effect of a medium with dissipation and dispersion and also the curvature of the physical space on the properties of the incident quantum states, we use the quantization of electromagnetic field based on phenomenological approach to obtain input-output relations between radiations on both sides of dielectric slab. By using these relations the fidelity, the Wigner function, and also the quantum correlation of the outgoing state through dielectric slab are obtained for a situation in which the rightward incident state is a nonlinear coherent state on a sphere and the leftward incident state is a vacuum state. Here, the incident states are considered monochromatic and the modeling of the medium is given by the Lorentz' model. Accordingly, we study nonclassical properties of the output states such as the quantum entanglement. It will be observed that the nonclassical properties of the outgoing states depend strongly on the optical property of the medium and also on the curvature of the physical state.

  7. Finite element method for viscoelastic medium with damage and the application to structural analysis of solid rocket motor grain

    Science.gov (United States)

    Deng, Bin; Shen, ZhiBin; Duan, JingBo; Tang, GuoJin

    2014-05-01

    This paper studies the damage-viscoelastic behavior of composite solid propellants of solid rocket motors (SRM). Based on viscoelastic theories and strain equivalent hypothesis in damage mechanics, a three-dimensional (3-D) nonlinear viscoelastic constitutive model incorporating with damage is developed. The resulting viscoelastic constitutive equations are numerically discretized by integration algorithm, and a stress-updating method is presented by solving nonlinear equations according to the Newton-Raphson method. A material subroutine of stress-updating is made up and embedded into commercial code of Abaqus. The material subroutine is validated through typical examples. Our results indicate that the finite element results are in good agreement with the analytical ones and have high accuracy, and the suggested method and designed subroutine are efficient and can be further applied to damage-coupling structural analysis of practical SRM grain.

  8. A strain-hardening bi-power law for the nonlinear behaviour of biological soft tissues.

    Science.gov (United States)

    Nicolle, S; Vezin, P; Palierne, J-F

    2010-03-22

    Biological soft tissues exhibit a strongly nonlinear viscoelastic behaviour. Among parenchymous tissues, kidney and liver remain less studied than brain, and a first goal of this study is to report additional material properties of kidney and liver tissues in oscillatory shear and constant shear rate tests. Results show that the liver tissue is more compliant but more strain hardening than kidney. A wealth of multi-parameter mathematical models has been proposed for describing the mechanical behaviour of soft tissues. A second purpose of this work is to develop a new constitutive law capable of predicting our experimental data in the both linear and nonlinear viscoelastic regime with as few parameters as possible. We propose a nonlinear strain-hardening fractional derivative model in which six parameters allow fitting the viscoelastic behaviour of kidney and liver tissues for strains ranging from 0.01 to 1 and strain rates from 0.0151 s(-1) to 0.7s(-1). Copyright (c) 2009 Elsevier Ltd. All rights reserved.

  9. Dynamical problem of micropolar viscoelasticity

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging Solutions)

    gen (1964) and Tomar and Kumar (1999) discussed different types of problems in micropolar elastic medium. Eringen (1967) extended the theory of micropolar elasticity to obtain linear constitutive theory for micropolar material possessing inter- nal friction. A problem on micropolar viscoelastic waves has been discussed by ...

  10. Viscoelastic behavior of rubbery materials

    CERN Document Server

    Roland, C M

    2011-01-01

    The gigantic size of polymer molecules makes them viscoelastic - their behavior changes depending on how fast and for how long the material is used. This book looks at the latest discoveries in the field from a fundamental molecular perspective, in order to guide the development of better and new applications for soft materials.

  11. Electrospun microcrimped fibers with nonlinear mechanical properties enhance ligament fibroblast phenotype.

    Science.gov (United States)

    Grace Chao, Pen-hsiu; Hsu, Hsiang-Yi; Tseng, Hsiao-Yun

    2014-09-01

    Fiber structure and order greatly impact the mechanical behavior of fibrous materials. In biological tissues, the nonlinear mechanics of fibrous scaffolds contribute to the functionality of the material. The nonlinear mechanical properties of the wavy structure (crimp) in collagen allow tissue flexibility while preventing over-extension. A number of approaches have tried to recreate this complex mechanical functionality. We generated microcrimped fibers by briefly heating electrospun parallel fibers over the glass transition temperature or by ethanol treatment. The crimp structure is similar to those of collagen fibers found in native aorta, intestines, or ligaments. Using poly-L-lactic acid fibers, we demonstrated that the bulk materials exhibit changed stress-strain behaviors with a significant increase in the toe region in correlation to the degree of crimp, similar to those observed in collagenous tissues. In addition to mimicking the stress-strain behavior of biological tissues, the microcrimped fibers are instructive in cell morphology and promote ligament phenotypic gene expression. This effect can be further enhanced by dynamic tensile loading, a physiological perturbation in vivo. This rapid and economical approach for microcrimped fiber production provides an accessible platform to study structure-function relationships and a novel functional scaffold for tissue engineering and cell mechanobiology studies.

  12. Electrospun microcrimped fibers with nonlinear mechanical properties enhance ligament fibroblast phenotype

    International Nuclear Information System (INIS)

    Grace Chao, Pen-hsiu; Hsu, Hsiang-Yi; Tseng, Hsiao-Yun

    2014-01-01

    Fiber structure and order greatly impact the mechanical behavior of fibrous materials. In biological tissues, the nonlinear mechanics of fibrous scaffolds contribute to the functionality of the material. The nonlinear mechanical properties of the wavy structure (crimp) in collagen allow tissue flexibility while preventing over-extension. A number of approaches have tried to recreate this complex mechanical functionality. We generated microcrimped fibers by briefly heating electrospun parallel fibers over the glass transition temperature or by ethanol treatment. The crimp structure is similar to those of collagen fibers found in native aorta, intestines, or ligaments. Using poly-L-lactic acid fibers, we demonstrated that the bulk materials exhibit changed stress–strain behaviors with a significant increase in the toe region in correlation to the degree of crimp, similar to those observed in collagenous tissues. In addition to mimicking the stress–strain behavior of biological tissues, the microcrimped fibers are instructive in cell morphology and promote ligament phenotypic gene expression. This effect can be further enhanced by dynamic tensile loading, a physiological perturbation in vivo. This rapid and economical approach for microcrimped fiber production provides an accessible platform to study structure–function relationships and a novel functional scaffold for tissue engineering and cell mechanobiology studies. (papers)

  13. A theoretical study of structural, opto-electronic and nonlinear properties of arylboroxine derivatives

    Science.gov (United States)

    Islam, Nasarul; Pandith, Altaf Hussain

    2018-01-01

    Density functional theory at CAM-B3LYP/6-311G++ (2d, 2p) level was employed to study the Triphenylboroxine derivatives ( TB) containing electron donating and electron substituents, for their charge transfer and nonlinear optical properties. The results reveal that electron donating groups facilitate the rapid electron injection as compared to unsubstituted TB. It was observed that upon substitution with electron donating groups, the TB derivatives show an increased double bond character in the B3-C18 bond indicating an increase in the degree of conjugation. The Frontier molecular orbital studies indicate that highest occupied molecular orbitals of the neutral molecules delocalize primarily over the three phenyl rings and bridging oxygen atoms, whereas the lowest unoccupied molecular orbitals localize largely on the two phenyl rings and the boron atoms. Further, the TD-DFT studies indicate that the maximum absorption band results from the electron transitions from the initial states that are contributed by the HOMO and HOMO-1 to the final states that are mainly contributed by the LUMOs. In addition, we have observed that the introduction of electron donating group to the TB-7 leads to more active nonlinear performance.

  14. A nonlinear structural subgrid-scale closure for compressible MHD. I. Derivation and energy dissipation properties

    Energy Technology Data Exchange (ETDEWEB)

    Vlaykov, Dimitar G., E-mail: Dimitar.Vlaykov@ds.mpg.de [Institut für Astrophysik, Universität Göttingen, Friedrich-Hund-Platz 1, D-37077 Göttingen (Germany); Max-Planck-Institut für Dynamik und Selbstorganisation, Am Faßberg 17, D-37077 Göttingen (Germany); Grete, Philipp [Institut für Astrophysik, Universität Göttingen, Friedrich-Hund-Platz 1, D-37077 Göttingen (Germany); Max-Planck-Institut für Sonnensystemforschung, Justus-von-Liebig-Weg 3, D-37077 Göttingen (Germany); Schmidt, Wolfram [Hamburger Sternwarte, Universität Hamburg, Gojenbergsweg 112, D-21029 Hamburg (Germany); Schleicher, Dominik R. G. [Departamento de Astronomía, Facultad Ciencias Físicas y Matemáticas, Universidad de Concepción, Av. Esteban Iturra s/n Barrio Universitario, Casilla 160-C (Chile)

    2016-06-15

    Compressible magnetohydrodynamic (MHD) turbulence is ubiquitous in astrophysical phenomena ranging from the intergalactic to the stellar scales. In studying them, numerical simulations are nearly inescapable, due to the large degree of nonlinearity involved. However, the dynamical ranges of these phenomena are much larger than what is computationally accessible. In large eddy simulations (LESs), the resulting limited resolution effects are addressed explicitly by introducing to the equations of motion additional terms associated with the unresolved, subgrid-scale dynamics. This renders the system unclosed. We derive a set of nonlinear structural closures for the ideal MHD LES equations with particular emphasis on the effects of compressibility. The closures are based on a gradient expansion of the finite-resolution operator [W. K. Yeo (CUP, 1993)] and require no assumptions about the nature of the flow or magnetic field. Thus, the scope of their applicability ranges from the sub- to the hyper-sonic and -Alfvénic regimes. The closures support spectral energy cascades both up and down-scale, as well as direct transfer between kinetic and magnetic resolved and unresolved energy budgets. They implicitly take into account the local geometry, and in particular, the anisotropy of the flow. Their properties are a priori validated in Paper II [P. Grete et al., Phys. Plasmas 23, 062317 (2016)] against alternative closures available in the literature with respect to a wide range of simulation data of homogeneous and isotropic turbulence.

  15. Viscoelastic Flow Modelling for Polymer Flooding

    Science.gov (United States)

    de, Shauvik; Padding, Johan; Peters, Frank; Kuipers, Hans; Multi-scale Modelling of Multi-phase Flows Team

    2015-11-01

    Polymer liquids are used in the oil industry to improve the volumetric sweep and displacement efficiency of oil from a reservoir. Surprisingly, it is not only the viscosity but also the elasticity of the displacing fluid that determine the displacement efficiency. The main aim of our work is to obtain a fundamental understanding of the effect of fluid elasticity, by developing an advanced computer simulation methodology for the flow of non-Newtonian fluids through porous media. We simulate a 3D unsteady viscoelastic flow through a converging diverging geometry of realistic pore dimension using computational fluid dynamics (CFD).The primitive variables velocity, pressure and extra stresses are used in the formulation of models. The viscoelastic stress part is formulated using a FENE-P type of constitutive equation, which can predict both shear and elongational stress properties during this flow. A Direct Numerical Simulation (DNS) approach using Finite volume method (FVM) with staggered grid has been applied. A novel second order Immersed boundary method (IBM) has been incorporated to mimic porous media. The effect of rheological parameters on flow characteristics has also been studied. The simulations provide an insight into 3D flow asymmetry at higher Deborah numbers. Micro-Particle Image Velocimetry experiments are carried out to obtain further insights. These simulations present, for the first time, a detailed computational study of the effects of fluid elasticity on the imbibition of an oil phase.

  16. Viscoelastic effect on acoustic band gaps in polymer-fluid composites

    International Nuclear Information System (INIS)

    Merheb, B; Deymier, P A; Muralidharan, K; Bucay, J; Jain, M; Aloshyna-Lesuffleur, M; Mohanty, S; Berker, A; Greger, R W

    2009-01-01

    In this paper, we present a theoretical analysis of the propagation of acoustic waves through elastic and viscoelastic two-dimensional phononic crystal structures. Numerical calculations of transmission spectra are conducted by extending the finite-difference-time-domain method to account for linear viscoelastic materials with time-dependent moduli. We study a phononic crystal constituted of a square array of cylindrical air inclusions in a solid viscoelastic matrix. The elastic properties of the solid are those of a silicone rubber. This system exhibits very wide band gaps in its transmission spectrum that extend to frequencies in the audible range of the spectrum. These gaps are characteristic of fluid matrix/air inclusion systems and result from the very large contrast between the longitudinal and transverse speeds of sound in rubber. By treating the matrix as a viscoelastic medium within the standard linear solid (SLS) model, we demonstrate that viscoelasticity impacts the transmission properties of the rubber/air phononic crystal not only by attenuating the transmitted acoustic waves but also by shifting the passing bands frequencies toward lower values. The ranges of frequencies exhibiting attenuation or frequency shift are determined by the value of the relaxation time in the SLS model. We show that viscoelasticity can be used to decrease the frequency of pass bands (and consequently stop bands) in viscoelastic/air phononic crystals

  17. Chiral supramolecular gold-cysteine nanoparticles: Chiroptical and nonlinear optical properties

    Directory of Open Access Journals (Sweden)

    Isabelle Russier-Antoine

    2016-10-01

    Full Text Available Cysteine is a sulfur-containing amino acid that easily coordinates to soft metal ions and grafts to noble metal surfaces. We report a simple synthetic approach for the production of chiral gold-cysteine polymeric nanoparticles soluble in water. Conjugation of cysteine with gold in a polymeric way, leading to ~50 nm diameter nanoparticles, resulted in the generation of new characteristic circular dichroism (CD signals in the region of 250–400 nm, whereas no CD signal changes were found with cysteine alone. We also investigate their nonlinear optical properties after two-photon absorption. Two-photon emission spectra and first hyper-polarizabilities, as obtained by the hyper-Rayleigh scattering technique, of these particles are presented.

  18. Introduction of Nonlinear Properties Into Hierachical Models of Nb3Sn Strands

    International Nuclear Information System (INIS)

    Collins, B.; Krishnan, J.; Arbelaez, D.; Ferracin, P.; Prestemon, S.O.; Godeke, A.; Dietderich, D.R.; Zohdi, T.I.

    2011-01-01

    The development of computational models representing Rutherford cable formation and deformation is necessary to investigate the strain state in the superconducting filaments in Nb 3 Sn magnets. The wide variety of length scales within accelerator magnets suggests usage of a hierarchical structure within the model. As part of an ongoing investigation at LBNL, a three-dimensional simplified nonlinear multiscale model is developed as a way to extend previous linear elastic versions. The inclusion of plasticity models into the problem formulation allows an improved representation of strand behavior compared to the linear elastic model. This formulation is applied to a single Nb 3 Sn strand to find its effective properties as well as the strain state in the conductor under loading.

  19. A numerical method for reorientation of rotating tidally deformed viscoelastic bodies

    NARCIS (Netherlands)

    Hu, H.; van der Wal, W.; Vermeersen, L.L.A.

    2017-01-01

    Existing approaches for simulating the true polar wander (TPW) of a viscoelastic body can be divided into three categories: (i) a linear dynamic approach which uses the linearized Liouville equation (e.g., Wu and Peltier (1984) and Mitrovica et al. (2005)); (ii) a nonlinear dynamic approach which

  20. Lossless synthesis of graphene nanosheets decorated with tiny cadmium sulfide quantum dots with excellent nonlinear optical properties

    International Nuclear Information System (INIS)

    Feng Miao; Zhan Hongbing; Sun Ruiqing; Chen Yu

    2010-01-01

    The implantation and growth of metal nanoparticles on graphene nanosheets (GNS) leads directly to severe damage to the regular structure of the graphene sheets, which disrupts the extended π conjugation, resulting in an impaired device performance. In this paper, we describe a facile approach for achieving the lossless formation of graphene composite decorated with tiny cadmium sulfide quantum dots (QDs) with excellent nonlinear optical properties by using benzyl mercaptan (BM) as the interlinker. The mercapto substituent of BM binds to the CdS QDs during their nucleation and growth process, and then the phenyl comes into contact with the GNS via the π-π stacking interaction. Using this strategy, CdS QDs with an average diameter of 3 nm are uniformly dispersed over the surface of graphene, and the resulting QD-graphene composite exhibits excellent optical limiting properties, mainly contributed by nonlinear scattering and nonlinear absorption, upon both 532 and 1064 nm excitations, in the nanosecond laser pulse regime.

  1. Linear and nonlinear optical properties of multilayered spherical quantum dots: Effects of geometrical size, hydrogenic impurity, hydrostatic pressure and temperature

    International Nuclear Information System (INIS)

    Karimi, M.J.; Rezaei, G.; Nazari, M.

    2014-01-01

    Based on the effective mass and parabolic one band approximations, simultaneous effects of the geometrical size, hydrogenic impurity, hydrostatic pressure, and temperature on the intersubband optical absorption coefficients and refractive index changes in multilayered spherical quantum dots are studied. Energy eigenvalues and eigenvectors are calculated using the fourth-order Runge–Kutta method and optical properties are obtained using the compact density matrix approach. The results indicate that the hydrogenic impurity, hydrostatic pressure, temperature and geometrical parameters such as the well and barrier widths have a great influence on the linear, the third-order nonlinear and the total optical absorption coefficients and refractive index changes. -- Highlights: • Hydrogenic impurity effects on the optical properties of a MSQD are investigated. • Hydrostatic pressure and temperature effects are also studied. • Hydrogenic impurity has a great influence on the linear and nonlinear ACs and RICs. • Hydrostatic pressure and temperature change the linear and nonlinear ACs and RICs

  2. On the Asymptotic Properties of Nonlinear Third-Order Neutral Delay Differential Equations with Distributed Deviating Arguments

    Directory of Open Access Journals (Sweden)

    Youliang Fu

    2016-01-01

    Full Text Available This paper is concerned with the asymptotic properties of solutions to a third-order nonlinear neutral delay differential equation with distributed deviating arguments. Several new theorems are obtained which ensure that every solution to this equation either is oscillatory or tends to zero. Two illustrative examples are included.

  3. Intensity-dependent nonlinear optical properties in a modulation-doped single quantum well

    International Nuclear Information System (INIS)

    Ungan, F.

    2011-01-01

    In the present work, the changes in the intersubband optical absorption coefficients and the refractive index in a modulation-doped quantum well have been investigated theoretically. Within the envelope function approach and the effective mass approximation, the electronic structure of the quantum well is calculated from the self-consistent numerical solution of the coupled Schroedinger-Poisson equations. The analytical expressions of optical properties are obtained by using the compact density-matrix approach. The numerical results GaAs/Al x Ga 1-x As are presented for typical modulation-doped quantum well system. The linear, third-order nonlinear and total absorption and refractive index changes depending on the doping concentration are investigated as a function of the incident optical intensity and structure parameters, such as quantum well width and stoichiometric ratio. The results show that the doping concentration, the structure parameters and the incident optical intensity have a great effect on the optical characteristics of these structures. - Highlights: → The doping concentration has a great effect on the optical characteristics of these structures. → The structure parameters have a great effect on the optical properties of these structures. → The total absorption coefficients reduced as the incident optical intensity increases. → The RICs reduced as the incident optical intensity increases.

  4. Time-dependent density functional theory for nonlinear properties of open-shell systems.

    Science.gov (United States)

    Rinkevicius, Zilvinas; Jha, Prakash Chandra; Oprea, Corneliu I; Vahtras, Olav; Agren, Hans

    2007-09-21

    This paper presents response theory based on a spin-restricted Kohn-Sham formalism for computation of time-dependent and time-independent nonlinear properties of molecules with a high spin ground state. The developed approach is capable to handle arbitrary perturbations and constitutes an efficient procedure for evaluation of electric, magnetic, and mixed properties. Apart from presenting the derivation of the proposed approach, we show results from illustrating calculations of static and dynamic hyperpolarizabilities of small Si(3n+1)H(6n+3) (n=0,1,2) clusters which mimic Si(111) surfaces with dangling bond defects. The results indicate that the first hyperpolarizability tensor components of Si(3n+1)H(6n+3) have an ordering compatible with the measurements of second harmonic generation in SiO2/Si(111) interfaces and, therefore, support the hypothesis that silicon surface defects with dangling bonds are responsible for this phenomenon. The results exhibit a strong dependence on the quality of basis set and exchange-correlation functional, showing that an appropriate set of diffuse functions is required for reliable predictions of the first hyperpolarizability of open-shell compounds.

  5. Measuring the linear and nonlinear elastic properties of brain tissue with shear waves and inverse analysis.

    Science.gov (United States)

    Jiang, Yi; Li, Guoyang; Qian, Lin-Xue; Liang, Si; Destrade, Michel; Cao, Yanping

    2015-10-01

    We use supersonic shear wave imaging (SSI) technique to measure not only the linear but also the nonlinear elastic properties of brain matter. Here, we tested six porcine brains ex vivo and measured the velocities of the plane shear waves induced by acoustic radiation force at different states of pre-deformation when the ultrasonic probe is pushed into the soft tissue. We relied on an inverse method based on the theory governing the propagation of small-amplitude acoustic waves in deformed solids to interpret the experimental data. We found that, depending on the subjects, the resulting initial shear modulus [Formula: see text] varies from 1.8 to 3.2 kPa, the stiffening parameter [Formula: see text] of the hyperelastic Demiray-Fung model from 0.13 to 0.73, and the third- [Formula: see text] and fourth-order [Formula: see text] constants of weakly nonlinear elasticity from [Formula: see text]1.3 to [Formula: see text]20.6 kPa and from 3.1 to 8.7 kPa, respectively. Paired [Formula: see text] test performed on the experimental results of the left and right lobes of the brain shows no significant difference. These values are in line with those reported in the literature on brain tissue, indicating that the SSI method, combined to the inverse analysis, is an efficient and powerful tool for the mechanical characterization of brain tissue, which is of great importance for computer simulation of traumatic brain injury and virtual neurosurgery.

  6. MECHANICAL BEHAVIOR OF PRESTRESSED VISCOELASTIC ADHESIVE AREAS UNDER COMBINING LOADINGS

    Directory of Open Access Journals (Sweden)

    Halil Murat Enginsoy

    2017-12-01

    Full Text Available In this article, mechanical behaviors of adhesive tape VHB 4950 elastomeric material, which is an element of acrylic polymer group and which is in viscoelastic behavior, under different pre-stress conditions and complex forces of different geometric parameters created by combining loadings have been experimentally and numerically investigated. In experimental studies, loading-unloading cyclic tests, one of the different standardized tests for the mechanical characterization of viscoelastic material, have been applied which give the most suitable convergent optimization parameters for the finite element model. Different material models were also investigated by using the data obtained from loading-unloading test results in all numerical models. According to the experimental results, the most suitable material parameters were determined with the Abaqus Parallel Rheological Framework Model (PRF for 4 Yeoh Networks with Bergstrom-Boyce Flow model created in the Mcalibration software for finite element analysis. Subsequently, using these material parameters, finite element analysis was performed as three dimension non-linear viscoelastic with a commercial finite element software Abaqus. The finite element analysis results showed good correlation to the Force (N-Displacement (mm experimental data for maximum load-carrying capacity of structural specimens.

  7. Floquet stability analysis of viscoelastic flow over a cylinder

    KAUST Repository

    Richter, David

    2011-06-01

    A Floquet linear stability analysis has been performed on a viscoelastic cylinder wake. The FENE-P model is used to represent the non-Newtonian fluid, and the analysis is done using a modified version of an existing nonlinear code to compute the linearized initial value problem governing the growth of small perturbations in the wake. By measuring instability growth rates over a wide range of disturbance spanwise wavenumbers α, the effects of viscoelasticity were identified and compared directly to Newtonian results.At a Reynolds number of 300, two unstable bands exist over the range 0. ≤ α≤ 10 for Newtonian flow. For the low α band, associated with the "mode A" wake instability, a monotonic reduction in growth rates is found for increasing polymer extensibility L. For the high α band, associated with the "mode B" instability, first a rise, then a significant decrease to a stable state is found for the instability growth rates as L is increased from L= 10 to L= 30. The mechanism behind this stabilization of both mode A and mode B instabilities is due to the change of the base flow, rather than a direct effect of viscoelasticity on the perturbation. © 2011 Elsevier B.V.

  8. Floquet stability analysis of viscoelastic flow over a cylinder

    KAUST Repository

    Richter, David; Shaqfeh, Eric S.G.; Iaccarino, Gianluca

    2011-01-01

    A Floquet linear stability analysis has been performed on a viscoelastic cylinder wake. The FENE-P model is used to represent the non-Newtonian fluid, and the analysis is done using a modified version of an existing nonlinear code to compute the linearized initial value problem governing the growth of small perturbations in the wake. By measuring instability growth rates over a wide range of disturbance spanwise wavenumbers α, the effects of viscoelasticity were identified and compared directly to Newtonian results.At a Reynolds number of 300, two unstable bands exist over the range 0. ≤ α≤ 10 for Newtonian flow. For the low α band, associated with the "mode A" wake instability, a monotonic reduction in growth rates is found for increasing polymer extensibility L. For the high α band, associated with the "mode B" instability, first a rise, then a significant decrease to a stable state is found for the instability growth rates as L is increased from L= 10 to L= 30. The mechanism behind this stabilization of both mode A and mode B instabilities is due to the change of the base flow, rather than a direct effect of viscoelasticity on the perturbation. © 2011 Elsevier B.V.

  9. A Note on the Invariance Properties and Conservation Laws of the Kadomstev—Petviashvili Equation with Power Law Nonlinearity

    International Nuclear Information System (INIS)

    Bokhari A H; Zaman F D; Fakhar K; Kara A H

    2011-01-01

    First, we studied the invariance properties of the Kadomstev—Petviashvili equation with power law nonlinearity. Then, we determined the complete class of conservation laws and stated the corresponding conserved densities which are useful in finding the conserved quantities of the equation. The point symmetry generators were also used to reduce the equation to an exact solution and to verify the invariance properties of the conserved flows. (general)

  10. Magnetic field induced changes in linear and nonlinear optical properties of Ti incorporated Cr2O3 nanostructured thin film

    Science.gov (United States)

    Baraskar, Priyanka; Chouhan, Romita; Agrawal, Arpana; Choudhary, R. J.; Sen, Pranay K.; Sen, Pratima

    2018-03-01

    We report the magnetic field effect on the linear and nonlinear optical properties of pulse laser ablated Ti-incorporated Cr2O3 nanostructured thin film. Optical properties have been experimentally analyzed under Voigt geometry by performing ultraviolet-visible spectroscopy and closed aperture Z-scan technique using a continuous wave He-Ne laser source. Nonlinear optical response reveals a single peak-valley feature in the far field diffraction pattern in absence of magnetic field (B = 0) confirming self-defocussing effect. This feature switches to a valley-peak configuration for B = 5000G, suggesting self-focusing effect. For B ≤ 750G, oscillations were observed revealing the occurrence of higher order nonlinearity. Origin of nonlinearity is attributed to the near resonant d-d transitions observed from the broad peak occurring around 2 eV. These transitions are of magnetic origin and get modified under the application of external magnetic field. Our results suggest that magnetic field can be used as an effective tool to monitor the sign of optical nonlinearity and hence the thermal expansion in Ti-incorporated Cr2O3 nanostructured thin film.

  11. Estimation of viscoelastic parameters in Prony series from shear wave propagation

    Energy Technology Data Exchange (ETDEWEB)

    Jung, Jae-Wook; Hong, Jung-Wuk, E-mail: j.hong@kaist.ac.kr, E-mail: jwhong@alum.mit.edu [Department of Civil and Environmental Engineering, KAIST, 291 Deahak-ro, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Lee, Hyoung-Ki; Choi, Kiwan [Health and Medical Equipment, Samsung Electronics, 1003 Daechi-dong, Gangnam-gu, Seoul 135-280 (Korea, Republic of)

    2016-06-21

    When acquiring accurate ultrasonic images, we must precisely estimate the mechanical properties of the soft tissue. This study investigates and estimates the viscoelastic properties of the tissue by analyzing shear waves generated through an acoustic radiation force. The shear waves are sourced from a localized pushing force acting for a certain duration, and the generated waves travel horizontally. The wave velocities depend on the mechanical properties of the tissue such as the shear modulus and viscoelastic properties; therefore, we can inversely calculate the properties of the tissue through parametric studies.

  12. Sensitivity Analysis of Viscoelastic Structures

    Directory of Open Access Journals (Sweden)

    A.M.G. de Lima

    2006-01-01

    Full Text Available In the context of control of sound and vibration of mechanical systems, the use of viscoelastic materials has been regarded as a convenient strategy in many types of industrial applications. Numerical models based on finite element discretization have been frequently used in the analysis and design of complex structural systems incorporating viscoelastic materials. Such models must account for the typical dependence of the viscoelastic characteristics on operational and environmental parameters, such as frequency and temperature. In many applications, including optimal design and model updating, sensitivity analysis based on numerical models is a very usefull tool. In this paper, the formulation of first-order sensitivity analysis of complex frequency response functions is developed for plates treated with passive constraining damping layers, considering geometrical characteristics, such as the thicknesses of the multi-layer components, as design variables. Also, the sensitivity of the frequency response functions with respect to temperature is introduced. As an example, response derivatives are calculated for a three-layer sandwich plate and the results obtained are compared with first-order finite-difference approximations.

  13. Characterization and modeling of performance of Polymer Composites Reinforced with Highly Non-Linear Cellulosic Fibers

    International Nuclear Information System (INIS)

    Rozite, L; Joffe, R; Varna, J; Nyström, B

    2012-01-01

    The behaviour of highly non-linear cellulosic fibers and their composite is characterized. Micro-mechanisms occurring in these materials are identified. Mechanical properties of regenerated cellulose fibers and composites are obtained using simple tensile test. Material visco-plastic and visco-elastic properties are analyzed using creep tests. Two bio-based resins are used in this study – Tribest and EpoBioX. The glass and flax fiber composites are used as reference materials to compare with Cordenka fiber laminates.

  14. Characterization and modeling of performance of Polymer Composites Reinforced with Highly Non-Linear Cellulosic Fibers

    Science.gov (United States)

    Rozite, L.; Joffe, R.; Varna, J.; Nyström, B.

    2012-02-01

    The behaviour of highly non-linear cellulosic fibers and their composite is characterized. Micro-mechanisms occurring in these materials are identified. Mechanical properties of regenerated cellulose fibers and composites are obtained using simple tensile test. Material visco-plastic and visco-elastic properties are analyzed using creep tests. Two bio-based resins are used in this study - Tribest and EpoBioX. The glass and flax fiber composites are used as reference materials to compare with Cordenka fiber laminates.

  15. Viscoelastic characterization of soft biological materials

    Science.gov (United States)

    Nayar, Vinod Timothy

    Progressive and irreversible retinal diseases are among the primary causes of blindness in the United States, attacking the cells in the eye that transform environmental light into neural signals for the optic pathway. Medical implants designed to restore visual function to afflicted patients can cause mechanical stress and ultimately damage to the host tissues. Research shows that an accurate understanding of the mechanical properties of the biological tissues can reduce damage and lead to designs with improved safety and efficacy. Prior studies on the mechanical properties of biological tissues show characterization of these materials can be affected by environmental, length-scale, time, mounting, stiffness, size, viscoelastic, and methodological conditions. Using porcine sclera tissue, the effects of environmental, time, and mounting conditions are evaluated when using nanoindentation. Quasi-static tests are used to measure reduced modulus during extended exposure to phosphate-buffered saline (PBS), as well as the chemical and mechanical analysis of mounting the sample to a solid substrate using cyanoacrylate. The less destructive nature of nanoindentation tests allows for variance of tests within a single sample to be compared to the variance between samples. The results indicate that the environmental, time, and mounting conditions can be controlled for using modified nanoindentation procedures for biological samples and are in line with averages modulus values from previous studies but with increased precision. By using the quasi-static and dynamic characterization capabilities of the nanoindentation setup, the additional stiffness and viscoelastic variables are measured. Different quasi-static control methods were evaluated along with maximum load parameters and produced no significant difference in reported reduced modulus values. Dynamic characterization tests varied frequency and quasi-static load, showing that the agar could be modeled as a linearly

  16. Spectral properties of a confined nonlinear quantum oscillator in one and three dimensions

    International Nuclear Information System (INIS)

    Schulze-Halberg, Axel; Gordon, Christopher R.

    2013-01-01

    We analyze the spectral behaviour of a nonlinear quantum oscillator model under confinement. The underlying potential is given by a harmonic oscillator interaction plus a nonlinear term that can be weakened or strengthened through a parameter. Numerical eigenvalues of the model in one and three dimensions are presented. The asymptotic behaviour of the eigenvalues for confinement relaxation and for vanishing nonlinear term in the potential is investigated. Our findings are compared with existing results.

  17. Linear and nonlinear intraband optical properties of ZnO quantum dots embedded in SiO2 matrix

    Directory of Open Access Journals (Sweden)

    Deepti Maikhuri

    2012-03-01

    Full Text Available In this work we investigate some optical properties of semiconductor ZnO spherical quantum dot embedded in an amorphous SiO2 dielectric matrix. Using the framework of effective mass approximation, we have studied intraband S-P, and P-D transitions in a singly charged spherical ZnO quantum dot. The optical properties are investigated in terms of the linear and nonlinear photoabsorption coefficient, the change in refractive index, and the third order nonlinear susceptibility and oscillator strengths. Using the parabolic confinement potential of electron in the dot these parameters are studied with the variation of the dot size, and the energy and intensity of incident radiation. The photoionization cross sections are also obtained for the different dot radii from the initial ground state of the dot. It is found that dot size, confinement potential, and incident radiation intensity affects intraband optical properties of the dot significantly.

  18. Nonlinear systems

    CERN Document Server

    Palmero, Faustino; Lemos, M; Sánchez-Rey, Bernardo; Casado-Pascual, Jesús

    2018-01-01

    This book presents an overview of the most recent advances in nonlinear science. It provides a unified view of nonlinear properties in many different systems and highlights many  new developments. While volume 1 concentrates on mathematical theory and computational techniques and challenges, which are essential for the study of nonlinear science, this second volume deals with nonlinear excitations in several fields. These excitations can be localized and transport energy and matter in the form of breathers, solitons, kinks or quodons with very different characteristics, which are discussed in the book. They can also transport electric charge, in which case they are known as polarobreathers or solectrons. Nonlinear excitations can influence function and structure in biology, as for example, protein folding. In crystals and other condensed matter, they can modify transport properties, reaction kinetics and interact with defects. There are also engineering applications in electric lattices, Josephson junction a...

  19. Effect of mechanical damage and wound healing on the viscoelastic properties of stems of flax cultivars (Linum usitatissimum L. cv. Eden and cv. Drakkar).

    Science.gov (United States)

    Paul-Victor, Cloé; Dalle Vacche, Sara; Sordo, Federica; Fink, Siegfried; Speck, Thomas; Michaud, Véronique; Speck, Olga

    2017-01-01

    As plant fibres are increasingly used in technical textiles and their composites, underlying principles of wound healing in living plant fibres are relevant to product quality, and provide inspiration for biomimetic healing in synthetic materials. In this work, two Linum usitatissimum cultivars differing in their stem mechanical properties, cv. Eden (stems resistant to lodging) and cv. Drakkar (with more flexible stems), were grown without wound or with stems previously wounded with a cut parallel or transversal to the stem. To investigate wound healing efficiency, growth traits, stem biomechanics with Dynamic Mechanical Analysis and anatomy were analysed after 25-day recovery. Longitudinal incisions formed open wounds while transversal incisions generated stem growth restoring the whole cross-section but not the original stem organisation. In the case of transversal wound healing, all the bast fibre bundles in the perturbed area became lignified and pulled apart by parenchyma cells growth. Both Linum cultivars showed a healing efficiency from 79% to 95% with higher scores for transversal healing. Morphological and anatomical modifications of Linum were related to mechanical properties and healing ability. Alongside with an increased understanding of wound healing in plants, our results highlight their possible impact on textile quality and fibre yield.

  20. Synthesis, characterization, and nonlinear optical properties of graphene oxide functionalized with tetra-amino porphyrin

    Science.gov (United States)

    Yamuna, R.; Ramakrishnan, S.; Dhara, Keerthy; Devi, R.; Kothurkar, Nikhil K.; Kirubha, E.; Palanisamy, P. K.

    2013-01-01

    The synthesis of a porphyrin-graphene oxide hybrid (GO-TAP) was carried out by covalently functionalizing graphene oxide (GO) with 5,10,15,20 mesotetra (4-aminophenyl) porphyrin (TAP) through an amide linkage. The GO-TAP hybrid has been characterized by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and UV-visible spectroscopy. The peak intensity of the Soret band of the material was suppressed compared to neat TAP. This indicates a strong interaction between the electronic energy level of TAP and GO in the GO-TAP hybrid. The functionalization of GO with TAP significantly improved its solubility and dispersion stability in organic solvents. Scanning electron micrographs reveal that the hybrid was found to be similar to the unmodified GO but slightly more wrinkled. Transmission electron micrographs also demonstrate that GO sheet in the hybrid is more wrinkled with some dark spot due to functionalization. Atomic force microscopy results also reveal that the TAP functionalization increases the thickness of GO sheet to 2.0-3.0 nm from 1.2 to 1.8 nm. We observed improved nonlinear optical and optical limiting properties for the hybrid compared to both graphene oxide and porphyrin. GO-TAP shows fluorescence quenching compared with porphyrin, indicating excellent electron and/or energy transfer to GO from TAP. Thermogravimetric analysis confirms that the GO-TAP hybrid has outstanding thermal stability.

  1. Synthesis, characterization, and nonlinear optical properties of graphene oxide functionalized with tetra-amino porphyrin

    International Nuclear Information System (INIS)

    Yamuna, R.; Ramakrishnan, S.; Dhara, Keerthy; Devi, R.; Kothurkar, Nikhil K.; Kirubha, E.; Palanisamy, P. K.

    2013-01-01

    The synthesis of a porphyrin–graphene oxide hybrid (GO–TAP) was carried out by covalently functionalizing graphene oxide (GO) with 5,10,15,20 mesotetra (4-aminophenyl) porphyrin (TAP) through an amide linkage. The GO–TAP hybrid has been characterized by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and UV–visible spectroscopy. The peak intensity of the Soret band of the material was suppressed compared to neat TAP. This indicates a strong interaction between the electronic energy level of TAP and GO in the GO–TAP hybrid. The functionalization of GO with TAP significantly improved its solubility and dispersion stability in organic solvents. Scanning electron micrographs reveal that the hybrid was found to be similar to the unmodified GO but slightly more wrinkled. Transmission electron micrographs also demonstrate that GO sheet in the hybrid is more wrinkled with some dark spot due to functionalization. Atomic force microscopy results also reveal that the TAP functionalization increases the thickness of GO sheet to 2.0–3.0 nm from 1.2 to 1.8 nm. We observed improved nonlinear optical and optical limiting properties for the hybrid compared to both graphene oxide and porphyrin. GO–TAP shows fluorescence quenching compared with porphyrin, indicating excellent electron and/or energy transfer to GO from TAP. Thermogravimetric analysis confirms that the GO–TAP hybrid has outstanding thermal stability.

  2. Structural, linear and nonlinear optical properties of co-doped ZnO thin films

    Science.gov (United States)

    Shaaban, E. R.; El-Hagary, M.; Moustafa, El Sayed; Hassan, H. Shokry; Ismail, Yasser A. M.; Emam-Ismail, M.; Ali, A. S.

    2016-01-01

    Different compositions of Co-doped zinc oxide [(Zn(1- x)Co x O) ( x = 0, 0.02, 0.04, 0.06, 0.08 and 0.10)] thin films were evaporated onto highly clean glass substrates by thermal evaporation technique using a modified source. The structural properties investigated by X-ray diffraction revealed hexagonal wurtzite ZnO-type structure. The crystallite size of the films was found to decrease with increasing Co content. The optical characterization of the films has been carried out using spectral transmittance and reflectance obtained in the wavelength range from 300 to 2500 nm. The refractive index has been found to increase with increasing Co content. It was further found that optical energy gap decreases from 3.28 to 3.03 eV with increasing Co content from x = 0 to x = 0.10, respectively. The dispersion of refractive index has been analyzed in terms of Wemple-DiDomenico (WDD) single-oscillator model. The oscillator parameters, the single-oscillator energy ( E o), the dispersion energy ( E d), and the static refractive index ( n 0), were determined. The nonlinear refractive index of the Zn(1- x)Co x O thin films was calculated and revealed well correlation with the linear refractive index and WDD parameters which in turn depend on the density and molar volume of the system.

  3. Broadband femtosecond nonlinear optical properties of CsPbBr3 perovskite nanocrystals.

    Science.gov (United States)

    Krishnakanth, Katturi Naga; Seth, Sudipta; Samanta, Anunay; Rao, Soma Venugopal

    2018-02-01

    We report the broadband nonlinear optical (NLO) properties of CsPbBr 3 perovskite films achieved from colloidal nanocrystals prepared following a room temperature and open atmosphere anti-solvent precipitation method. The NLO studies were performed on the films of nanocubes (NCs) and nanorods (NRs) using the Z-scan technique with 1 kHz femtosecond pulses at 600, 700, and 800 nm. Large two-photon absorption cross sections (∼10 5   GM) were retrieved by fitting the open-aperture Z-scan data. Strong third-order NLO susceptibility (∼10 -10   esu) was observed in these films. At higher peak intensities a switching of sign (in both NCs and NRs) in the real and imaginary parts of the NLO susceptibility was observed from the studies on these CsPbBr 3 nanocrystals. The obtained NLO coefficients clearly suggest that these materials are promising for ultrafast photonic applications.

  4. Viscoelastic and thermal behavior of structural concrete with reference to containment vessels

    International Nuclear Information System (INIS)

    Stefanou, G.D.

    1981-01-01

    A method of numerical viscoelastic stress analysis is described suitable for concrete structures operating at elevated temperatures. The paper describes how approximate numerical methods of elastic analysis of the finite element type can be extended to incorporate the viscoelastic behavior of structural concrete of the quasi-static type. A new eight parameter viscoelastic model is proposed to represent concrete behavior in the loaded and unloaded stage. The deformational expressions for the proposed viscoelastic analogue are also developed. Finally, as a result of courve-fitting procedures, the evaluation of the creep law coefficients are obtained for creep laws appropriate to a test regime. The proposed method is of general application providing that the properties of concrete are assessed reasonably well. The analytical predictions are compared with experimental results obtained on concrete model specimens loaded for 3 1/2 months, at a temperature of 80 0 C. (author)

  5. Stationary responses of a Rayleigh viscoelastic system with zero barrier impacts under external random excitation.

    Science.gov (United States)

    Wang, Deli; Xu, Wei; Zhao, Xiangrong

    2016-03-01

    This paper aims to deal with the stationary responses of a Rayleigh viscoelastic system with zero barrier impacts under external random excitation. First, the original stochastic viscoelastic system is converted to an equivalent stochastic system without viscoelastic terms by approximately adding the equivalent stiffness and damping. Relying on the means of non-smooth transformation of state variables, the above system is replaced by a new system without an impact term. Then, the stationary probability density functions of the system are observed analytically through stochastic averaging method. By considering the effects of the biquadratic nonlinear damping coefficient and the noise intensity on the system responses, the effectiveness of the theoretical method is tested by comparing the analytical results with those generated from Monte Carlo simulations. Additionally, it does deserve attention that some system parameters can induce the occurrence of stochastic P-bifurcation.

  6. Structural, vibrational and theoretical studies of anilinium trichloroacetate: New hydrogen bonded molecular crystal with nonlinear optical properties

    Science.gov (United States)

    Tanak, H.; Pawlus, K.; Marchewka, M. K.; Pietraszko, A.

    2014-01-01

    In this work, we report a combined experimental and theoretical study on molecular structure, vibrational spectra and NBO analysis of the potential nonlinear optical (NLO) material anilinium trichloroacetate. The FT-IR and FT-Raman spectra of the compound have been recorded together between 4000-80 cm-1 and 3600-80 cm-1 regions, respectively. The compound crystallizes in the noncentrosymmetric space group of monoclinic system. The optimized molecular structure, vibrational wavenumbers, IR intensities and Raman activities have been calculated by using density functional method (B3LYP) with 6-311++G(d,p) as higher basis set. The obtained vibrational wavenumbers and optimized geometric parameters were seen to be in good agreement with the experimental data. DSC measurements on powder samples do not indicate clearly on the occurrence of phase transitions in the temperature 113-293 K. The Kurtz and Perry powder reflection technique appeared to be very effective in studies of second-order nonlinear optical properties of the molecule. The non-linear optical properties are also addressed theoretically. The predicted NLO properties of the title compound are much greater than ones of urea. In addition, DFT calculations of the title compound, molecular electrostatic potential, frontier orbitals and thermodynamic properties were also performed at 6-311++G(d,p) level of theory. For title crystal the SHG efficiency was estimated by Kurtz-Perry method to be deff = 0.70 deff (KDP).

  7. Synthesis, growth, crystal structure, optical and third order nonlinear optical properties of quinolinium derivative single crystal: PNQI

    Science.gov (United States)

    Karthigha, S.; Krishnamoorthi, C.

    2018-03-01

    An organic quinolinium derivative nonlinear optical (NLO) crystal, 1-ethyl-2-[2-(4-nitro-phenyl)-vinyl]-quinolinium iodide (PNQI) was synthesized and successfully grown by slow evaporation solution growth technique. Formation of a crystalline compound was confirmed by single crystal X-ray diffraction. The quinolinium compound PNQI crystallizes in the triclinic crystal system with a centrosymmetric space group of P-1 symmetry. The molecular structure of PNQI was confirmed by 1H NMR and 13C NMR spectral studies. The thermal properties of the crystal have been investigated by thermogravimetric (TG) and differential scanning calorimetry (DSC) studies. The optical characteristics obtained from UV-Vis-NIR spectral data were described and the cut-off wavelength observed at 506 nm. The etching study was performed to analyse the growth features of PNQI single crystal. The third order NLO properties such as nonlinear refractive index (n2), nonlinear absorption coefficient (β) and nonlinear susceptibility (χ (3)) of the crystal were investigated using Z-scan technique at 632.8 nm of Hesbnd Ne laser.

  8. Viscoelastic modes in chiral liquid crystals

    Indian Academy of Sciences (India)

    amit@fs.rri.local.net (Amit Kumar Agarwal)

    our studies on the viscoelastic modes of some chiral liquid crystals using dynamic light scattering. We discuss viscoelastic ... In the vicinity of the direct beam for a sample aligned in the Bragg mode and. 297 ... experimental investigations on these modes. Duke and Du ..... scattering volume is not true in practice. In an actual ...

  9. The visco-elastic multilayer program VEROAD

    NARCIS (Netherlands)

    Hopman, P.C.

    1996-01-01

    The mathematical principles and derivation of a linear visco-elastic multilayer computer program are described. The mathematical derivation is based on Fourier Transformation. The program is called VEROAD, which is an acronym for Visco-Elastic ROad Analysis Delft. The program allows calculation of

  10. A study on creep properties of laminated rubber bearings. Pt. 1. Creep properties and numerical simulations of thick rubber bearings

    International Nuclear Information System (INIS)

    Matsuda, Akihiro; Yabana, Shuichi

    2000-01-01

    In this report, to evaluate creep properties and effects of creep deformation on mechanical properties of thick rubber bearings for three-dimensional isolation system, we show results of compression creep test for rubber bearings of various rubber materials and shapes and development of numerical simulation method. Creep properties of thick rubber bearings were obtained from compression creep tests. The creep strain shows steady creep that have logarithmic relationships between strain and time and accelerated creep that have linear relationships. We make numerical model of a rubber material with nonlinear viscoelastic constitutional equations. Mechanical properties after creep loading test are simulated with enough accuracy. (author)

  11. Process-induced viscoelastic stress in composite laminates

    International Nuclear Information System (INIS)

    Stango, R.J.

    1985-01-01

    In recent years, considerable interest has developed in evaluating the stress response of composite laminates which is associated with cooling the material system from the cure temperature to room temperature. This research examines the fundamental nature of time-dependent residual-thermal stresses in composite laminates which are caused by the extreme temperature reduction encountered during the fabrication process. Viscoelastic stress in finite-width, symmetric composite laminates is examined on the basis of a formulation that employs an incremental hereditary integral approach in conjunction with a quasi-three dimensional finite element analysis. A consistent methodology is developed and employed for the characterization of lamina material properties. Special attention is given to the time-dependent stress response at ply-interface locations near the free-edge. In addition, the influence of cooling path on stress history is examined. Recently published material property data for graphite-epoxy lamina is employed in the analysis. Results of the investigation generally indicate that nominal differences between the thermoelastic and viscoelastic solutions are obtained. Slight changes of the final stress state are observed to result when different cooling paths are selected for the temperature history. The methodology employed is demonstrated to result in an accurate, efficient, and consistent approach for the viscoelastic analysis of advanced composite laminates

  12. Magnetic and viscoelastic response of elastomers with hard magnetic filler

    International Nuclear Information System (INIS)

    Kramarenko, E Yu; Chertovich, A V; Semisalova, A S; Makarova, L A; Perov, N S; Khokhlov, A R; Stepanov, G V

    2015-01-01

    Magnetic elastomers (MEs) based on a silicone matrix and magnetically hard NdFeB particles have been synthesized and their magnetic and viscoelastic properties have been studied depending on the size and concentration of magnetic particles and the magnetizing field. It has been shown that magnetic particles can rotate in soft polymer matrix under applied magnetic field, this fact leading to some features in both magnetic and viscoelastic properties. In the maximum magnetic field used magnetization of MEs with smaller particles is larger while the coercivity is smaller due to higher mobility of the particles within the polymer matrix. Viscoelastic behavior is characterized by long relaxation times due to restructuring of the magnetic filler under the influence of an applied mechanical force and magnetic interactions. The storage and loss moduli of magnetically hard elastomers grow significantly with magnetizing field. The magnetic response of the magnetized samples depends on the mutual orientation of the external magnetic field and the internal sample magnetization. Due to the particle rotation within the polymer matrix, the loss factor increases abruptly when the magnetic field is turned on in the opposite direction to the sample magnetization, further decreasing with time. Moduli versus field dependences have minimum at non-zero field and are characterized by a high asymmetry with respect to the field direction. (paper)

  13. Anisotropy in the viscoelastic response of knee meniscus cartilage.

    Science.gov (United States)

    Coluccino, Luca; Peres, Chiara; Gottardi, Riccardo; Bianchini, Paolo; Diaspro, Alberto; Ceseracciu, Luca

    2017-01-26

    The knee meniscus is instrumental to stability, shock absorption, load transmission and stress distribution within the knee joint. Such functions are mechanically demanding, and replacement constructs used in meniscus repair often fail because of a poor match with the surrounding tissue. This study focused on the native structure-mechanics relationships and on their anisotropic behavior in meniscus, to define the target biomechanical viscoelastic properties required by scaffolds upon loading. To show regional orientation of the collagen fibers and their viscoelastic behavior, bovine lateral menisci were characterized by second harmonic generation microscopy and through time-dependent mechanical tests. Furthermore, their dynamic viscoelastic response was analyzed over a wide range of frequencies. Multilevel characterization aims to expand the biomimetic approach from the structure itself, to include the mechanical characteristics that give the meniscus its peculiar properties, thus providing tools for the design of novel, effective scaffolds. An example of modeling of anisotropic open-cell porous material tailored to fulfill the measured requirements is presented, leading to a definition of additional parameters for a better understanding of the load transmission mechanism and for better scaffold functionality.

  14. Viscoelastic behavior of multiwalled carbon nanotubes into phenolic resin

    Energy Technology Data Exchange (ETDEWEB)

    Botelho, Edson Cocchieri; Costa, Michelle Leali; Braga, Carlos Isidoro, E-mail: ebotelho@feg.unesp.br [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Guaratingueta, SP (Brazil). Dept. de Materiais e Tecnologia; Burkhart, Thomas [Institut fuer Verbundwerkstoffe GmbH, Kaiserslautern, (Germany); Lauke, Bernd [Leibniz-Institut fuer Polymerforschung, Dresden (Germany)

    2013-11-01

    Nanostructured polymer composites have opened up new perspectives for multi-functional materials. In particular, carbon nanotubes (CNTs) have the potential applications in order to improve mechanical and electrical performance in composites with aerospace application. This study focuses on the viscoelastic evaluation of phenolic resin reinforced carbon nanotubes, processed by using two techniques: aqueous-surfactant solution and three roll calender (TRC) process. According to our results a relative small amount of CNTs in a phenolic resin matrix is capable of enhancing the viscoelastic properties significantly and to modify the thermal stability. Also has been observed that when is used TRC process, the incorporation and distribution of CNT into phenolic resin is more effective when compared with aqueous solution dispersion process. (author)

  15. Non-linear properties of R-R distributions as a measure of heart rate variability

    International Nuclear Information System (INIS)

    Irurzun, I.M.; Bergero, P.; Cordero, M.C.; Defeo, M.M.; Vicente, J.L.; Mola, E.E.

    2003-01-01

    We analyze the dynamic quality of the R-R interbeat intervals of electrocardiographic signals from healthy people and from patients with premature ventricular contractions (PVCs) by applying different measure algorithms to standardised public domain data sets of heart rate variability. Our aim is to assess the utility of these algorithms for the above mentioned purposes. Long and short time series, 24 and 0.50 h respectively, of interbeat intervals of healthy and PVC subjects were compared with the aim of developing a fast method to investigate their temporal organization. Two different methods were used: power spectral analysis and the integral correlation method. Power spectral analysis has proven to be a powerful tool for detecting long-range correlations. If it is applied in a short time series, power spectra of healthy and PVC subjects show a similar behavior, which disqualifies power spectral analysis as a fast method to distinguish healthy from PVC subjects. The integral correlation method allows us to study the fractal properties of interbeat intervals of electrocardiographic signals. The cardiac activity of healthy and PVC people stems from dynamics of chaotic nature characterized by correlation dimensions d f equal to 3.40±0.50 and 5.00±0.80 for healthy and PVC subjects respectively. The methodology presented in this article bridges the gap between theoretical and experimental studies of non-linear phenomena. From our results we conclude that the minimum number of coupled differential equations to describe cardiac activity must be six and seven for healthy and PVC individuals respectively. From the present analysis we conclude that the correlation integral method is particularly suitable, in comparison with the power spectral analysis, for the early detection of arrhythmias on short time (0.5 h) series

  16. Synthesis, crystal structure, spectroscopic characterization and nonlinear optical properties of Co(II)- picolinate complex

    Energy Technology Data Exchange (ETDEWEB)

    Tamer, Ömer, E-mail: omertamer@sakarya.edu.tr; Avcı, Davut; Atalay, Yusuf

    2015-11-15

    A cobalt(II) complex of picolinate was synthesized, and its structure was fully characterized by the applying of X-ray diffraction method as well as FT-IR, FT-Raman and UV–vis spectroscopies. In order to both support the experimental results and convert study to more advanced level, density functional theory calculations were performed by using B3LYP level. Single crystal X-ray structural analysis shows that cobalt(II) ion was located to the center of distorted octahedral geometry. The C=O, C=C and C=N stretching vibrations were found as highly active and strong peaks, inducing the molecular charge transfer within Co(II) complex. The small energy gap between frontier molecular orbital energies was another indicator of molecular charge transfer interactions within Co(II) complex. The nonlinear optical properties of Co(II) complex were investigated at DFT/B3LYP level, and the hypepolarizability parameter was found to be decreased due to the presence of inversion symmetry. The natural bond orbital (NBO) analysis was performed to investigate molecular stability, hyperconjugative interactions, intramolecular charge transfer (ICT) and bond strength for Co(II) complex. Finally, molecular electrostatic potential (MEP) and spin density distributions for Co(II) complex were evaluated. - Highlights: • Co(II) complex of picolinate was prepared. • Its FT-IR, FT-Raman and UV–vis spectra were measured. • DFT calculations were performed to support experimental results. • Small HOMO-LUMO energy gap is an indicator of molecular charge transfer. • Spin density localized on Co(II) as well as O and N atoms.

  17. Z-scan measurement for nonlinear absorption property of rGO/ZnO:Al thin film

    Science.gov (United States)

    Sreeja, V. G.; Anila, E. I.

    2018-04-01

    We report the fabrication of reduced graphene oxide integrated aluminium doped zinc oxide (rGO/ZnO:Al) composite thin film on a glass substrate by spin coating technique. The effect of rGO on structural and linear optical properties of rGO/ZnO:Al composite thin film was explored with the help of X-Ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and UV-Vis absorption spectroscopy. Structural studies reveals that the composite film has hexagonal wurtzite structure with a strong bonding between rGO and ZnO:Al material. The band gap energy of ZnO:Al thin film was red shifted by the addition of rGO. The Nonlinear absorption property was investigated by open aperture Z-scan technique by using Q switched Nd-YAG laser at 532nm. The Z-scan results showed that the composite film demonstrates reverse saturable absorption property with a nonlinear absorption coefficient, β, of 12.75×10-7m/w. The results showed that investigated rGO/ZnO:Al thin film is a promising material suitable for the applications in absorbing type optical devices such as optical limiters, optical switches and protection of the optical sensors in the field of nonlinear optics.

  18. Effect of linear and non-linear components in the temperature dependences of thermoelectric properties on the energy conversion efficiency

    International Nuclear Information System (INIS)

    Yamashita, Osamu

    2009-01-01

    The new thermal rate equations were built up by taking the linear and non-linear components in the temperature dependences of the Seebeck coefficient α, the electrical resistivity ρ and thermal conductivity κ of a thermoelectric (TE) material into the thermal rate equations on the assumption that their temperature dependences are expressed by a quadratic function of temperature T. The energy conversion efficiency η for a single TE element was formulated using the new thermal rate ones proposed here. By applying it to the high-performance half-Heusler compound, the non-linear component in the temperature dependence of α among those of the TE properties has the greatest effect on η, so that η/η 0 was increased by 11% under the condition of T = 510 K and ΔT = 440 K, where η 0 is a well-known conventional energy conversion efficiency. It was thus found that the temperature dependences of TE properties have a significant influence on η. When one evaluates the accurate achievement rate of η exp obtained experimentally for a TE generator, therefore, η exp should be compared with η the estimated from the theoretical expression proposed here, not with η 0 , particularly when there is a strong non-linearity in the temperature dependence of TE properties.

  19. On Lamb and Rayleigh wave convergence in viscoelastic tissues

    Energy Technology Data Exchange (ETDEWEB)

    Nenadic, Ivan Z; Urban, Matthew W; Aristizabal, Sara; Mitchell, Scott A; Humphrey, Tye C; Greenleaf, James F, E-mail: Nenadic.Ivan@mayo.edu [Department of Biomedical Engineering, Mayo Clinic College of Medicine, Rochester, MN, 55905 (United States)

    2011-10-21

    Characterization of the viscoelastic material properties of soft tissue has become an important area of research over the last two decades. Our group has been investigating the feasibility of using a shear wave dispersion ultrasound vibrometry (SDUV) method to excite Lamb waves in organs with plate-like geometry to estimate the viscoelasticity of the medium of interest. The use of Lamb wave dispersion ultrasound vibrometry to quantify the mechanical properties of viscoelastic solids has previously been reported. Two organs, the heart wall and the spleen, can be readily modeled using plate-like geometries. The elasticity of these two organs is important because they change in pathological conditions. Diastolic dysfunction is the inability of the left ventricle (LV) of the heart to supply sufficient stroke volumes into the systemic circulation and is accompanied by the loss of compliance and stiffening of the LV myocardium. It has been shown that there is a correlation between high splenic stiffness in patients with chronic liver disease and strong correlation between spleen and liver stiffness. Here, we investigate the use of the SDUV method to quantify the viscoelasticity of the LV free-wall myocardium and spleen by exciting Rayleigh waves on the organ's surface and measuring the wave dispersion (change of wave velocity as a function of frequency) in the frequency range 40-500 Hz. An equation for Rayleigh wave dispersion due to cylindrical excitation was derived by modeling the excised myocardium and spleen with a homogenous Voigt material plate immersed in a nonviscous fluid. Boundary conditions and wave potential functions were solved for the surface wave velocity. Analytical and experimental convergence between the Lamb and Rayleigh waves is reported in a finite element model of a plate in a fluid of similar density, gelatin plate and excised porcine spleen and left-ventricular free-wall myocardium.

  20. Computational Study of Chalcopyrite Semiconductors and Their Non-Linear Optical Properties

    National Research Council Canada - National Science Library

    Lambrecht, Walter R

    2007-01-01

    ... (Including cation antisites, cation and anion vacancies) and CdGeAs2; a study of the feasibility of nonciritical phase matching and associated nonlinear optical parameters in CdSiP2 and CdSIAs2...

  1. Contractivity properties of a class of linear multistep methods for nonlinear neutral delay differential equations

    International Nuclear Information System (INIS)

    Wang Wansheng; Li Shoufu; Wang Wenqiang

    2009-01-01

    In this paper, we show that under identical conditions which guarantee the contractivity of the theoretical solutions of general nonlinear NDDEs, the numerical solutions obtained by a class of linear multistep methods are also contractive.

  2. Continuum mechanics elasticity, plasticity, viscoelasticity

    CERN Document Server

    Dill, Ellis H

    2006-01-01

    FUNDAMENTALS OF CONTINUUM MECHANICSMaterial ModelsClassical Space-TimeMaterial BodiesStrainRate of StrainCurvilinear Coordinate SystemsConservation of MassBalance of MomentumBalance of EnergyConstitutive EquationsThermodynamic DissipationObjectivity: Invariance for Rigid MotionsColeman-Mizel ModelFluid MechanicsProblems for Chapter 1BibliographyNONLINEAR ELASTICITYThermoelasticityMaterial SymmetriesIsotropic MaterialsIncompressible MaterialsConjugate Measures of Stress and StrainSome Symmetry GroupsRate Formulations for Elastic MaterialsEnergy PrinciplesGeometry of Small DeformationsLinear ElasticitySpecial Constitutive Models for Isotropic MaterialsMechanical Restrictions on the Constitutive RelationsProblems for Chapter 2BibliographyLINEAR ELASTICITYBasic EquationsPlane StrainPlane StressProperties of SolutionsPotential EnergySpecial Matrix NotationThe Finite Element Method of SolutionGeneral Equations for an Assembly of ElementsFinite Element Analysis for Large DeformationsProblems for Chapter 3Bibliograph...

  3. Nonlinear optical properties of TeO$_2$ crystalline phases from first principles

    OpenAIRE

    Berkaine, Nabil; Orhan, Emmanuelle; Masson, Olivier; Thomas, Philippe; Junquera, Javier

    2010-01-01

    We have computed second and third nonlinear optical susceptibilities of two crystalline bulk tellurium oxide polymorphs: $\\alpha$-TeO$_{2}$ (the most stable crystalline bulk phase) and $\\gamma$-TeO$_{2}$ (the crystalline phase that ressembles the more to the glass phase. Third order nonlinear susceptibilities of the crystalline phases are two orders of magnitude larger than $\\alpha$-SiO$_{2}$ cristoballite, thus extending the experimental observations on glasses to the case of crystalline com...

  4. Properties of entangled proton pairs generated in periodically poled nonlinear crystals

    Czech Academy of Sciences Publication Activity Database

    Svozilík, Jiří; Peřina ml., Jan

    2009-01-01

    Roč. 80, č. 2 (2009), 023819/1-023819/9 ISSN 1050-2947 R&D Projects: GA MŠk(CZ) OC09026; GA AV ČR IAA100100713; GA MŠk(CZ) 1M06002 Institutional research plan: CEZ:AV0Z10100522 Keywords : photon pairs * nonlinear crystals * nonlinear optics * quantum optics Subject RIV: BH - Optics, Masers, Lasers Impact factor: 2.866, year: 2009

  5. An optimized transversely isotropic, hyper-poro-viscoelastic finite element model of the meniscus to evaluate mechanical degradation following traumatic loading

    Science.gov (United States)

    Wheatley, Benjamin B.; Fischenich, Kristine M.; Button, Keith D.; Haut, Roger C.; Haut Donahue, Tammy L.

    2015-01-01

    Inverse finite element (FE) analysis is an effective method to predict material behavior, evaluate mechanical properties, and study differences in biological tissue function. The meniscus plays a key role in load distribution within the knee joint and meniscal degradation is commonly associated with the onset of osteoarthritis. In the current study, a novel transversely isotropic hyper-poro-viscoelastic constitutive formulation was incorporated in a FE model to evaluate changes in meniscal material properties following tibiofemoral joint impact. A non-linear optimization scheme was used to fit the model output to indentation relaxation experimental data. This study is the first to investigate rate of relaxation in healthy versus impacted menisci. Stiffness was found to be decreased (p=0.003), while the rate of tissue relaxation increased (p=0.010) at twelve weeks post impact. Total amount of relaxation, however, did not change in the impacted tissue (p=0.513). PMID:25776872

  6. MgB_{2} nonlinear properties investigated under localized high rf magnetic field excitation

    Directory of Open Access Journals (Sweden)

    Tamin Tai

    2012-12-01

    Full Text Available The high transition temperature and low surface resistance of MgB_{2} attracts interest in its potential application in superconducting radio frequency accelerating cavities. However, compared to traditional Nb cavities, the viability of MgB_{2} at high rf fields is still open to question. Our approach is to study the nonlinear electrodynamics of the material under localized rf magnetic fields. Because of the presence of the small superconducting gap in the π band, the nonlinear response of MgB_{2} at low temperature is potentially complicated compared to a single-gap s-wave superconductor such as Nb. Understanding the mechanisms of nonlinearity coming from the two-band structure of MgB_{2}, as well as extrinsic sources of nonlinearity, is an urgent requirement. A localized and strong rf magnetic field, created by a magnetic write head, is integrated into our nonlinear-Meissner-effect scanning microwave microscope [T. Tai et al., IEEE Trans. Appl. Supercond. 21, 2615 (2011ITASE91051-822310.1109/TASC.2010.2096531]. MgB_{2} films with thickness 50 nm, fabricated by a hybrid physical-chemical vapor deposition technique on dielectric substrates, are measured at a fixed location and show a strongly temperature-dependent third harmonic response. We propose that several possible mechanisms are responsible for this nonlinear response.

  7. Third-order nonlinear optical properties of GeSe2-Ga2Se3-PbI2 glasses

    International Nuclear Information System (INIS)

    Tang Gao; Liu Cunming; Luo Lan; Chen Wei

    2010-01-01

    The third-order nonlinear optical (NLO) properties of new selenium-based GeSe 2 -Ga 2 Se 3 -PbI 2 glasses have been measured using the optical Kerr effect (OKE) technique, with picosecond and femtosecond laser pulses. The 0.70GeSe 2 -0.15Ga 2 Se 3 -0.15PbI 2 glass has the largest third-order optical nonlinear susceptibility in GeSe 2 -Ga 2 Se 3 -PbI 2 glass system with χ (3) of 5.28x10 12 esu. In addition, the response time of glasses is sub-picosecond, which is predominantly associated with electron cloud. Local structure of the glasses has been identified by using Raman studies, while the origins of the observed nonlinear optical response are discussed. The [Ge(Ga)Se 4 ] tetrahedral and lone-pair electrons from highly polarizable Pb atom in glasses play an important role in enhanced NLO response. These results as well as their good chemical stability indicate that GeSe 2 -Ga 2 Se 3 -PbI 2 glasses are promising materials for photonic applications of third-order nonlinear optical signal processing.

  8. Viscoelastic characterization of carbon fiber-epoxy composites by creep and creep rupture tests; Caracterizacao viscoelastica por meio de ensaios de fluencia e ruptura por fluencia de compositos polimericos de matriz de matriz de resina epoxidica e fibra de carbono

    Energy Technology Data Exchange (ETDEWEB)

    Farina, Luis Claudio

    2009-07-01

    One of the main requirements for the use of fiber-reinforced polymer matrix composites in structural applications is the evaluation of their behavior during service life. The warranties of the integrity of these structural components demand a study of the time dependent behavior of these materials due to viscoelastic response of the polymeric matrix and of the countless possibilities of design configurations. In the present study, creep and creep rupture test in stress were performed in specimens of unidirectional carbon fiber-reinforced epoxy composites with fibers orientations of 60 degree and 90 degree, at temperatures of 25 and 70 degree C. The aim is the viscoelastic characterization of the material through the creep curves to some levels of constant tension during periods of 1000 h, the attainment of the creep rupture envelope by the creep rupture curves and the determination of the transition of the linear for non-linear behavior through isochronous curves. In addition, comparisons of creep compliance curves with a viscoelastic behavior prediction model based on Schapery equation were also performed. For the test, a modification was verified in the behavior of the material, regarding the resistance, stiffness and deformation, demonstrating that these properties were affected for the time and tension level, especially in work temperature above the ambient. The prediction model was capable to represent the creep behavior, however the determination of the equations terms should be considered, besides the variation of these with the applied tension and the elapsed time of test. (author)

  9. Analysis of Blood Flow Through a Viscoelastic Artery using the Cosserat Continuum with the Large-Amplitude Oscillatory Shear Deformation Model

    DEFF Research Database (Denmark)

    Sedaghatizadeh, N.; Atefi, G.; Fardad, A. A.

    2011-01-01

    In this investigation, semiempirical and numerical studies of blood flow in a viscoelastic artery were performed using the Cosserat continuum model. The large-amplitude oscillatory shear deformation model was used to quantify the nonlinear viscoelastic response of blood flow. The finite differenc...... method was used to solve the governing equations, and the particle swarm optimization algorithm was utilized to identify the non-Newtonian coefficients (kυ and γυ). The numerical results agreed well with previous experimental results....

  10. Visco-elastic properties of biofilms

    NARCIS (Netherlands)

    Peterson, Brandon Wade

    2013-01-01

    Microbiële biofilms aanpakken door ze te laten resoneren Naar schatting tachtig procent van alle bacteriële infecties die door dokters behandeld worden, wordt veroorzaakt door biofilms, dunne laagjes micro-organismen. Brandon Peterson stelt in preklinisch onderzoek de hypothese op dat de hechting

  11. Vibration analysis of viscoelastic single-walled carbon nanotubes resting on a viscoelastic foundation

    International Nuclear Information System (INIS)

    Zhang, Da Peng; Lei, Yong Jun; Shen, Zhi Bin; Wang, Cheng Yuan

    2017-01-01

    Vibration responses were investigated for a viscoelastic Single-walled carbon nanotube (visco-SWCNT) resting on a viscoelastic foundation. Based on the nonlocal Euler-Bernoulli beam model, velocity-dependent external damping and Kelvin viscoelastic foundation model, the governing equations were derived. The Transfer function method (TFM) was then used to compute the natural frequencies for general boundary conditions and foundations. In particular, the exact analytical expressions of both complex natural frequencies and critical viscoelastic parameters were obtained for the Kelvin-Voigt visco-SWCNTs with full foundations and certain boundary conditions, and several physically intuitive special cases were discussed. Substantial nonlocal effects, the influence of geometric and physical parameters of the SWCNT and the viscoelastic foundation were observed for the natural frequencies of the supported SWCNTs. The study demonstrates the efficiency and robustness of the developed model for the vibration of the visco-SWCNT-viscoelastic foundation coupling system

  12. Transient waves in visco-elastic media

    CERN Document Server

    Ricker, Norman

    1977-01-01

    Developments in Solid Earth Geophysics 10: Transient Waves in Visco-Elastic Media deals with the propagation of transient elastic disturbances in visco-elastic media. More specifically, it explores the visco-elastic behavior of a medium, whether gaseous, liquid, or solid, for very-small-amplitude disturbances. This volume provides a historical overview of the theory of the propagation of elastic waves in solid bodies, along with seismic prospecting and the nature of seismograms. It also discusses the seismic experiments, the behavior of waves propagated in accordance with the Stokes wave

  13. Nonlinear optical properties of polyaniline and poly (o-toluidine) composite thin films with multi walled carbon nano tubes

    Energy Technology Data Exchange (ETDEWEB)

    Nagaraja, K.K. [National University of Science and Technology “MISiS”, Leninskii pr. 4, Moscow 119049 (Russian Federation); Pramodini, S. [Department of Physics, School of Engineering and Technology, Jain University, Jakkasandra Post, Bengaluru 5621112, Karnataka (India); Poornesh, P., E-mail: poorneshp@gmail.com [Nonlinear Optics Research Laboratory, Department of Physics, Manipal Institute of Technology, Manipal University, Manipal 576 104, Karnataka (India); Telenkov, M.P. [National University of Science and Technology “MISiS”, Leninskii pr. 4, Moscow 119049 (Russian Federation); Kityk, I.V. [Electrical Engineering Department, Czestochowa University Technology, Czestochowa (Poland)

    2017-05-01

    We report the improved third-order nonlinear optical properties of polyaniline and poly (o-toluidine) with different doping concentrations of multi walled carbon nano tube (MWCNTs) composite thin films investigated using z-scan technique and continuous wave He–Ne laser at 633 nm wavelength was used as source of excitation. Thin films were prepared by spin coating technique on glass substrate. The structural properties of the composite films were analysed by X-ray diffraction studies and the characteristic peaks corresponding to MWCNTs and polymers have been observed. The surface morphology of the deposited films was analysed using scanning electron microscopy and it confirms that the polymer in the composites has been coated on the MWCNTs homogeneously. The z-scan results reveal that the films exhibit reverse saturable absorption and self-defocusing nonlinearity. The third-order nonlinear optical susceptibility χ{sup (3)} is found to be of the order of 10{sup −3} esu. Also, optical power limiting and clamping experiment was performed. The clamping values increases with increase in concentration and the lowest clamping observed for composite films are 1 mW and 0.7 mW.

  14. Nonlinear dynamics of structures

    CERN Document Server

    Oller, Sergio

    2014-01-01

    This book lays the foundation of knowledge that will allow a better understanding of nonlinear phenomena that occur in structural dynamics.   This work is intended for graduate engineering students who want to expand their knowledge on the dynamic behavior of structures, specifically in the nonlinear field, by presenting the basis of dynamic balance in non‐linear behavior structures due to the material and kinematics mechanical effects.   Particularly, this publication shows the solution of the equation of dynamic equilibrium for structure with nonlinear time‐independent materials (plasticity, damage and frequencies evolution), as well as those time dependent non‐linear behavior materials (viscoelasticity and viscoplasticity). The convergence conditions for the non‐linear dynamic structure solution  are studied, and the theoretical concepts and its programming algorithms are presented.  

  15. NONLINEAR PROPERTIES OF MEASLES EPIDEMIC DATA ASSESSED WITH A KERNEL NONPARAMETRIC IDENTIFICATION APPROACH

    Directory of Open Access Journals (Sweden)

    Luis García Domínguez

    2006-03-01

    Full Text Available ABSTRACTKernel nonparametric nonlinear autoregression was applied to measles data from the pre-vaccination era (1944-1966. A slowly sliding time window covered 20 overlapping segments of the series. In the case of data from Birmingham the order of the model was higher than 22 for all windows and the reconstructed noise free realizations were periodic with the most probable period being equal to 3 years, though values of 2, 4 and 6 years were also obtained.For London data 6 windows were with low orders (below 5. Low order noise free realizations were chaotic. The rest presented periodic solutions corresponding to 1, 2, and 3-years cycles. Our results are consistent with views about dynamical transitions among measles data. The method is reliable and puts practically no restrictions regarding data properties. We recommend its use for further exploration of epidemic data from different origin. RESUMENPROPIEDADES NO LINEALES DE DATOS EPIDEMIOLÓGICOS DE SARAMPIÓN EVALUADAS MEDIANTE UN ENFOQUE DE IDENTIFICACIÓN NO LINEAL POR NÚCLEOS.Se aplicó un método de auto-regresión no lineal por núcleos a datos de incidencia de sarampión correspondientes a la época previa a la vacunación (1944-1966. Una ventana de tiempo que se desplazaba lentamente cubrió 20 segmentos de serie temporal que se solapaban. En el caso de los datos correspondientes a Birmingham el orden del modelo era mayor de 22 para todas las ventanas y las realizaciones libres de ruido reconstruidas eran periódicas con la duración del periodo más probable igual a 3 años, aunque también se obtuvieron valores de 2, 4 y 6 años.Para los datos de Londres, se observaron 6 ventanas con órdenes inferiores a 5. Las realizaciones libres de ruido con órdenes bajos eran caóticas. El resto de las ventanas mostraron ciclos de 1, 2 y tres años. Nuestros resultados son concordantes con la idea de la presencia de transiciones de fase en series de sarampión. El método es confiable y no

  16. Effect of lime concentration on gelatinized maize starch dispersions properties.

    Science.gov (United States)

    Lobato-Calleros, C; Hernandez-Jaimes, C; Chavez-Esquivel, G; Meraz, M; Sosa, E; Lara, V H; Alvarez-Ramirez, J; Vernon-Carter, E J

    2015-04-01

    Maize starch was lime-cooked at 92 °C with 0.0-0.40% w/w Ca(OH)2. Optical micrographs showed that lime disrupted the integrity of insoluble remnants (ghosts) and increased the degree of syneresis of the gelatinized starch dispersions (GSD). The particle size distribution was monomodal, shifting to smaller sizes and narrower distributions with increasing lime concentration. X-ray patterns and FTIR spectra showed that crystallinity decreased to a minimum at lime concentration of 0.20% w/w. Lime-treated GSD exhibited thixotropic and viscoelastic behaviour. In the linear viscoelastic region the storage modulus was higher than the loss modulus, but a crossover between these moduli occurred in the non-linear viscoelastic region. The viscoelastic properties decreased with increased lime concentration. The electrochemical properties suggested that the amylopectin-rich remnants and the released amylose contained in the continuous matrix was firstly attacked by calcium ions at low lime levels (<0.20% w/w), disrupting the starch gel microstructure. Copyright © 2014 Elsevier Ltd. All rights reserved.

  17. pH-induced contrast in viscoelasticity imaging of biopolymers

    International Nuclear Information System (INIS)

    Yapp, R D; Insana, M F

    2009-01-01

    Understanding contrast mechanisms and identifying discriminating features is at the heart of diagnostic imaging development. This paper focuses on how pH influences the viscoelastic properties of biopolymers to better understand the effects of extracellular pH on breast tumour elasticity imaging. Extracellular pH is known to decrease as much as 1 pH unit in breast tumours, thus creating a dangerous environment that increases cellular mutatation rates and therapeutic resistance. We used a gelatin hydrogel phantom to isolate the effects of pH on a polymer network with similarities to the extracellular matrix in breast stroma. Using compressive unconfined creep and stress relaxation measurements, we systematically measured the viscoelastic features sensitive to pH by way of time-domain models and complex modulus analysis. These results are used to determine the sensitivity of quasi-static ultrasonic elasticity imaging to pH. We found a strong elastic response of the polymer network to pH, such that the matrix stiffness decreases as pH was reduced; however, the viscous response of the medium to pH was negligible. While physiological features of breast stroma such as proteoglycans and vascular networks are not included in our hydrogel model, observations in this study provide insight into viscoelastic features specific to pH changes in the collagenous stromal network. These observations suggest that the large contrast common in breast tumours with desmoplasia may be reduced under acidic conditions, and that viscoelastic features are unlikely to improve discriminability.

  18. A boundary integral method for a dynamic, transient mode I crack problem with viscoelastic cohesive zone

    KAUST Repository

    Leise, Tanya L.

    2009-08-19

    We consider the problem of the dynamic, transient propagation of a semi-infinite, mode I crack in an infinite elastic body with a nonlinear, viscoelastic cohesize zone. Our problem formulation includes boundary conditions that preclude crack face interpenetration, in contrast to the usual mode I boundary conditions that assume all unloaded crack faces are stress-free. The nonlinear viscoelastic cohesive zone behavior is motivated by dynamic fracture in brittle polymers in which crack propagation is preceeded by significant crazing in a thin region surrounding the crack tip. We present a combined analytical/numerical solution method that involves reducing the problem to a Dirichlet-to-Neumann map along the crack face plane, resulting in a differo-integral equation relating the displacement and stress along the crack faces and within the cohesive zone. © 2009 Springer Science+Business Media B.V.

  19. Non-Linear Rheological Properties and Neutron Scattering Investigation on Dilute Ring-Linear Blends

    DEFF Research Database (Denmark)

    Pyckhout-Hintzen, W.; Bras, A.R.; Wischnewski, A.

    in a filament stretching rheometer, followed by quenching, strong anisotropic scattering patterns were obtained which were described by affinely deformed rings which function as giant, polymeric chemical crosslinks or sliplinks and more or less isotropic topological contributions from the entangling...... with interpenetrating linear chains. At the same time the non-linear rheological and mechanical data fit to a non-affine slip-tube model as for moderately crosslinked networks and to interchain pressure models or a modified non-linear Doi-Edwards description for the observed strain hardening during the extensional...

  20. Propagation of the Stress Wave Through the Filled Joint with Linear Viscoelastic Deformation Behavior Using Time-Domain Recursive Method

    Science.gov (United States)

    Wang, Rui; Hu, Zhiping; Zhang, Dan; Wang, Qiyao

    2017-12-01

    The dynamic behavior of filled joints is mostly controlled by the filled medium. In addition to nonlinear elastic behavior, viscoelastic behavior of filled joints is also of great significance. Here, a theoretical study of stress wave propagation through a filled rock joint with linear viscoelastic deformation behavior has been carried out using a modified time-domain recursive method (TDRM). A displacement discontinuity model was extended to form a displacement and stress discontinuity model, and the differential constitutive relationship of viscoelastic model was adopted to introduce the mass and viscoelastic behavior of filled medium. A standard linear solid model, which can be degenerated into the Kelvin and Maxwell models, was adopted in deriving this method. Transmission and reflection coefficients were adopted to verify this method. Besides, the effects of some parameters on wave propagation across a filled rock joint with linear viscoelastic deformation behavior were discussed. Then, a comparison of the time-history curves calculated by the present method with those by frequency-domain method (FDM) was performed. The results indicated that change tendencies of the transmission and reflection coefficients for these viscoelastic models versus incident angle were the same as each other but not frequency. The mass and viscosity coupling of filled medium did not fundamentally change wave propagation. The modified TDRM was found to be more efficient than the FDM.

  1. Understanding viscoelasticity an introduction to rheology

    CERN Document Server

    Phan-Thien, Nhan

    2017-01-01

    This book presents an introduction to viscoelasticity, in particular, to the theories of dilute polymer solutions and dilute suspensions of rigid particles in viscous and incompressible fluids. These theories are important, not just because they apply to practical problems of industrial interest, but because they form a solid theoretical base upon which mathematical techniques can be built, from which more complex theories can be constructed, to better mimic material behaviour. The emphasis of this book is not on the voluminous current topical research, but on the necessary tools to understand viscoelasticity. This is a compact book for a first year graduate course in viscoelasticity and modelling of viscoelastic multiphase fluids. The Dissipative Particle Dynamics (DPD) is introduced as a particle-based method, relevant in modelling of complex-structured fluids. All the basic ideas in DPD are reviewed. The third edition has been updated and expanded with new results in the meso-scale modelling, links between...

  2. Understanding Viscoelasticity An Introduction to Rheology

    CERN Document Server

    Phan-Thien, Nhan

    2013-01-01

    This book presents an introduction to viscoelasticity; in particular, to the theories of dilute polymer solutions and dilute suspensions of rigid particles in viscous and incompressible fluids. These theories are important, not just because they apply to practical problems of industrial interest, but because they form a solid theoretical base upon which mathematical techniques can be built, from which more complex theories can be constructed, to better mimic material behaviour. The emphasis is not on the voluminous current topical research, but on the necessary tools to understand viscoelasticity at a first year graduate level. The main aim is to provide a still compact book, sufficient at the level of first year graduate course for those who wish to understand viscoelasticity and to embark in modeling of viscoelastic multiphase fluids. To this end, a new chapter on Dissipative Particle Dynamics (DPD) was introduced which is relevant to model complex-structured fluids. All the basic ideas in DPD are reviewed,...

  3. Viscoelastic model of tungsten 'fuzz' growth

    International Nuclear Information System (INIS)

    Krasheninnikov, S I

    2011-01-01

    A viscoelastic model of fuzz growth is presented. The model describes the main features of tungsten fuzz observed in experiments. It gives estimates of fuzz growth rate and temperature range close to experimental ones.

  4. Dynamics and Stability of Rolling Viscoelastic Tires

    Energy Technology Data Exchange (ETDEWEB)

    Potter, Trevor [Univ. of California, Berkeley, CA (United States)

    2013-04-30

    Current steady state rolling tire calculations often do not include treads because treads destroy the rotational symmetry of the tire. We describe two methodologies to compute time periodic solutions of a two-dimensional viscoelastic tire with treads: solving a minimization problem and solving a system of equations. We also expand on work by Oden and Lin on free spinning rolling elastic tires in which they disovered a hierachy of N-peak steady state standing wave solutions. In addition to discovering a two-dimensional hierarchy of standing wave solutions that includes their N-peak hiearchy, we consider the eects of viscoelasticity on the standing wave solutions. Finally, a commonplace model of viscoelasticity used in our numerical experiments led to non-physical elastic energy growth for large tire speeds. We show that a viscoelastic model of Govindjee and Reese remedies the problem.

  5. Enhanced nonlinear optical absorption and optical limiting properties of superparamagnetic spinel zinc ferrite decorated reduced graphene oxide nanostructures

    International Nuclear Information System (INIS)

    Saravanan, M.; Sabari Girisun, T.C.

    2017-01-01

    Highlights: • Nanospindle and nanosphere ZnFe_2O_4 were decorated upon GO by hydrothermal method. • All the samples show superparamagnetism with almost zero coercivity and remanence. • The observed nonlinearity arises due to effective two photon absorption process. • Tuning of NLO behavior with variation in amount of ZnFe_2O_4 upon GO were achieved. • ZnFe_2O_4-(15 wt%)GO show higher NLO coefficients and superior limiting actions. - Abstract: Nonlinear absorption and optical limiting properties of ZnFe_2O_4-rGO magnetic nanostructures was investigated by the Z-scan technique using Q-switched Nd:YAG laser (5 ns, 532 nm, 10 Hz) as an excitation source. Excited state absorption was the dominant process responsible for the observed nonlinearity in ZnFe_2O_4 decorated rGO which arises due to photo-generated charge carriers in the conduction band of zinc ferrite and increases in defects at the surface of rGO due to the incorporation of ZnFe_2O_4. The magnitude of the nonlinear absorption co-efficient was found to be in the order of 10"−"1"0 m/W. A noteworthy enhancement in the third-order NLO properties in ZnFe_2O_4-(15 wt%) rGO with those of individual counter parts and well known graphene composites was reported. Role of induced defects states (sp"3) arising from the functionalization of rGO in the enhancement of NLO response was explained through Raman studies. Earlier incorporation and distribution of ZnFe_2O_4 upon GO through one-step hydrothermal method was analyzed by XRD and FTIR. Formation of (nanospheres/nanospindles) ZnFe_2O_4 along with reduction of graphene oxide was confirmed through TEM analysis. VSM studies showed zinc ferrite decorated rGO posseses superparamagnetic behavior. The tuning of nonlinear optical and magnetic behavior with variation in the content of spinel ferrites upon reduced graphene oxide provides an easy way to attain tunable properties which are exceedingly required in both optoelectronics and photothermal therapy

  6. Enhanced nonlinear optical absorption and optical limiting properties of superparamagnetic spinel zinc ferrite decorated reduced graphene oxide nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Saravanan, M.; Sabari Girisun, T.C., E-mail: sabarigirisun@bdu.ac.in

    2017-01-15

    Highlights: • Nanospindle and nanosphere ZnFe{sub 2}O{sub 4} were decorated upon GO by hydrothermal method. • All the samples show superparamagnetism with almost zero coercivity and remanence. • The observed nonlinearity arises due to effective two photon absorption process. • Tuning of NLO behavior with variation in amount of ZnFe{sub 2}O{sub 4} upon GO were achieved. • ZnFe{sub 2}O{sub 4}-(15 wt%)GO show higher NLO coefficients and superior limiting actions. - Abstract: Nonlinear absorption and optical limiting properties of ZnFe{sub 2}O{sub 4}-rGO magnetic nanostructures was investigated by the Z-scan technique using Q-switched Nd:YAG laser (5 ns, 532 nm, 10 Hz) as an excitation source. Excited state absorption was the dominant process responsible for the observed nonlinearity in ZnFe{sub 2}O{sub 4} decorated rGO which arises due to photo-generated charge carriers in the conduction band of zinc ferrite and increases in defects at the surface of rGO due to the incorporation of ZnFe{sub 2}O{sub 4}. The magnitude of the nonlinear absorption co-efficient was found to be in the order of 10{sup −10} m/W. A noteworthy enhancement in the third-order NLO properties in ZnFe{sub 2}O{sub 4}-(15 wt%) rGO with those of individual counter parts and well known graphene composites was reported. Role of induced defects states (sp{sup 3}) arising from the functionalization of rGO in the enhancement of NLO response was explained through Raman studies. Earlier incorporation and distribution of ZnFe{sub 2}O{sub 4} upon GO through one-step hydrothermal method was analyzed by XRD and FTIR. Formation of (nanospheres/nanospindles) ZnFe{sub 2}O{sub 4} along with reduction of graphene oxide was confirmed through TEM analysis. VSM studies showed zinc ferrite decorated rGO posseses superparamagnetic behavior. The tuning of nonlinear optical and magnetic behavior with variation in the content of spinel ferrites upon reduced graphene oxide provides an easy way to attain tunable

  7. Nonlinear optical properties of poly(methyl methacrylate) thin films doped with Bixa Orellana dye

    CSIR Research Space (South Africa)

    Zongo, S

    2015-06-01

    Full Text Available Natural dyes with highly delocalized p-electron systems are considered as promising organic materials for nonlinear optical applications. Among these dyes, Bixa Orellana dye with extended p-electron delocalization is one of the most attractive dyes...

  8. Guanylurea(1+) hydrogen phosphite: study of linear and nonlinear optical properties

    Czech Academy of Sciences Publication Activity Database

    Fridrichová, M.; Kroupa, Jan; Němec, I.; Císařová, I.; Chvostová, Dagmar

    2010-01-01

    Roč. 83, 10-11 (2010), s. 761-767 ISSN 0141-1594 R&D Projects: GA ČR GA203/09/0878 Institutional research plan: CEZ:AV0Z10100520 Keywords : non-centrosymmetric * guanylurea * refractive indices * nonlinear optics Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.006, year: 2010

  9. Estimating marginal properties of quantitative real-time PCR data using nonlinear mixed models

    DEFF Research Database (Denmark)

    Gerhard, Daniel; Bremer, Melanie; Ritz, Christian

    2014-01-01

    A unified modeling framework based on a set of nonlinear mixed models is proposed for flexible modeling of gene expression in real-time PCR experiments. Focus is on estimating the marginal or population-based derived parameters: cycle thresholds and ΔΔc(t), but retaining the conditional mixed mod...

  10. Nonlinear optical properties of natural laccaic acid dye studied using Z-scan technique

    CSIR Research Space (South Africa)

    Zongo, S

    2015-08-01

    Full Text Available . The experiments were performed by using single beam Z-scan technique at 532 nm with 10 ns, 10 Hz Nd:YAG laser pulses excitation. From the open-aperture Z-scan data, we derived that the laccaic dye samples exhibit strong two photon absorption (2PA). The nonlinear...

  11. Stability properties of solutions to nonlinear models possessing a sign-undefined metric

    International Nuclear Information System (INIS)

    Barashenkov, I.V.

    1983-01-01

    Multicomponent field systems possessing a sign-undefined internal space metric, in particular models with a noncompact global invariance group are investigated. It is shown that the energy cannot have even a conditional relative minimum. It is demonstrated, nevertheless, that the corresponding nonlinear equations of motion are permitted to possess stable particle-like solutions

  12. Stability properties of solutions to nonlinear models possessing a sign-undefined metric

    International Nuclear Information System (INIS)

    Barashenkov, I.V.

    1983-01-01

    Multicomponent field systems possessing a sign-undefined internal space metric, in particular models with a noncompact global invariance group, are investigated. It is shown that the energy cannot have even a conditional relative minimum. It is demonstrated, nevertheless, that the corresponding nonlinear equations of motion are permitted to possess stable particle-like solutions. (Auth.)

  13. A nonlinear theory for elastic plates with application to characterizing paper properties

    Science.gov (United States)

    M. W. Johnson; Thomas J. Urbanik

    1984-03-01

    A theory of thin plates which is physically as well as kinematically nonlinear is, developed and used to characterize elastic material behavior for arbitrary stretching and bending deformations. It is developed from a few clearly defined assumptions and uses a unique treatment of strain energy. An effective strain concept is introduced to simplify the theory to a...

  14. VISCOELASTIC STRUCTURAL MODEL OF ASPHALT CONCRETE

    Directory of Open Access Journals (Sweden)

    V. Bogomolov

    2016-06-01

    Full Text Available The viscoelastic rheological model of asphalt concrete based on the generalized Kelvin model is offered. The mathematical model of asphalt concrete viscoelastic behavior that can be used for calculation of asphalt concrete upper layers of non-rigid pavements for strength and rutting has been developed. It has been proved that the structural model of Burgers does not fully meet all the requirements of the asphalt-concrete.

  15. Recent advances in elasticity, viscoelasticity and inelasticity

    CERN Document Server

    Rajagopal, KR

    1995-01-01

    This is a collection of papers dedicated to Prof T C Woo to mark his 70th birthday. The papers focus on recent advances in elasticity, viscoelasticity and inelasticity, which are related to Prof Woo's work. Prof Woo's recent work concentrates on the viscoelastic and viscoplastic response of metals and plastics when thermal effects are significant, and the papers here address open questions in these and related areas.

  16. Rough viscoelastic sliding contact: Theory and experiments

    Science.gov (United States)

    Carbone, G.; Putignano, C.

    2014-03-01

    In this paper, we show how the numerical theory introduced by the authors [Carbone and Putignano, J. Mech. Phys. Solids 61, 1822 (2013), 10.1016/j.jmps.2013.03.005] can be effectively employed to study the contact between viscoelastic rough solids. The huge numerical complexity is successfully faced up by employing the adaptive nonuniform mesh developed by the authors in Putignano et al. [J. Mech. Phys. Solids 60, 973 (2012), 10.1016/j.jmps.2012.01.006]. Results mark the importance of accounting for viscoelastic effects to correctly simulate the sliding rough contact. In detail, attention is, first, paid to evaluate the viscoelastic dissipation, i.e., the viscoelastic friction. Fixed the sliding speed and the normal load, friction is completely determined. Furthermore, since the methodology employed in the work allows to study contact between real materials, a comparison between experimental outcomes and numerical prediction in terms of viscoelastic friction is shown. The good agreement seems to validate—at least partially—the presented methodology. Finally, it is shown that viscoelasticity entails not only the dissipative effects previously outlined, but is also strictly related to the anisotropy of the contact solution. Indeed, a marked anisotropy is present in the contact region, which results stretched in the direction perpendicular to the sliding speed. In the paper, the anisotropy of the deformed surface and of the contact area is investigated and quantified.

  17. Experimental and Computational Investigation of Viscoelasticity of Native and Engineered Ligament and Tendon

    Science.gov (United States)

    Ma, J.; Narayanan, H.; Garikipati, K.; Grosh, K.; Arruda, E. M.

    The important mechanisms by which soft collagenous tissues such as ligament and tendon respond to mechanical deformation include non-linear elasticity, viscoelasticity and poroelasticity. These contributions to the mechanical response are modulated by the content and morphology of structural proteins such as type I collagen and elastin, other molecules such as glycosaminoglycans, and fluid. Our ligament and tendon constructs, engineered from either primary cells or bone marrow stromal cells and their autogenous matricies, exhibit histological and mechanical characteristics of native tissues of different levels of maturity. In order to establish whether the constructs have optimal mechanical function for implantation and utility for regenerative medicine, constitutive relationships for the constructs and native tissues at different developmental levels must be established. A micromechanical model incorporating viscoelastic collagen and non-linear elastic elastin is used to describe the non-linear viscoelastic response of our homogeneous engineered constructs in vitro. This model is incorporated within a finite element framework to examine the heterogeneity of the mechanical responses of native ligament and tendon.

  18. Viscoelastic response of a model endothelial glycocalyx

    International Nuclear Information System (INIS)

    Nijenhuis, Nadja; Spaan, Jos A E; Mizuno, Daisuke; Schmidt, Christoph F

    2009-01-01

    Many cells cover themselves with a multifunctional polymer coat, the pericellular matrix (PCM), to mediate mechanical interactions with the environment. A particular PCM, the endothelial glycocalyx (EG), is formed by vascular endothelial cells at their luminal side, forming a mechanical interface between the flowing blood and the endothelial cell layer. The glycosaminoglycan (GAG) hyaluronan (HA) is involved in the main functions of the EG, mechanotransduction of fluid shear stress and molecular sieving. HA, due to its length, is the only GAG in the EG or any other PCM able to form an entangled network. The mechanical functions of the EG are, however, impaired when any one of its components is removed. We here used microrheology to measure the effect of the EG constituents heparan sulfate, chondroitin sulfate, whole blood plasma and albumin on the high-bandwidth mechanical properties of a HA solution. Furthermore, we probed the effect of the hyaldherin aggrecan, a constituent of the PCM of chondrocytes, and very similar to versican (present in the PCM of various cells, and possibly in the EG). We show that components directly interacting with HA (chondroitin sulfate and aggrecan) can increase the viscoelastic shear modulus of the polymer composite

  19. Role of Mn2+ concentration in the linear and nonlinear optical properties of Ni1-xMnxSe nanoparticles

    Science.gov (United States)

    Anugop, B.; Prasanth, S.; Rithesh Raj, D.; Vineeshkumar, T. V.; Pranitha, S.; Mahadevan Pillai, V. P.; Sudarsanakumar, C.

    2016-12-01

    Ni1-xMnxSe nanoparticles (x = 0.1, 0.3, 0.5, 0.7, 0.9) were successfully synthesized by chemical co-precipitation method and their structural and optical properties were studied using X-ray diffraction, transmission electron microscopy, UV-Visible absorption and photo luminescence spectroscopy. XRD pattern reveals the hexagonal structure of the particles and the peak positions were shifted to higher 2θ values with increase in Mn2+ concentration. The average particle size determined from XRD varies from 6 to 11 nm. The UV-Visible absorption spectrum shows absorption edge around the blue region and is red-shifted with increasing Mn2+ concentration consequently the optical bandgap energy is decreasing. The PL emission spectrum shows a broad emission around 380 nm, and the intensity of the emission decreases with increase in Mn2+ concentration. The nonlinear optical properties of the samples were analysed using Z-scan technique and the samples show optical limiting behaviour and the 2 PA coefficient increases with increasing Mn2+ concentration. Overall, manganese concentration influences the linear and nonlinear optical properties of Ni1-xMnxSe nanoparticles.

  20. Effects of applied electromagnetic fields on the linear and nonlinear optical properties in an inverse parabolic quantum well

    International Nuclear Information System (INIS)

    Ungan, F.; Yesilgul, U.; Kasapoglu, E.; Sari, H.; Sökmen, I.

    2012-01-01

    In this present work, we have investigated theoretically the effects of applied electric and magnetic fields on the linear and nonlinear optical properties in a GaAs/Al x Ga 1−x As inverse parabolic quantum well for different Al concentrations at the well center. The Al concentration at the barriers was always x max =0.3. The energy levels and wave functions are calculated within the effective mass approximation and the envelope function approach. The analytical expressions of optical properties are obtained by using the compact density-matrix approach. The linear, third-order nonlinear and total absorption and refractive index changes depending on the Al concentration at the well center are investigated as a function of the incident photon energy for the different values of the applied electric and magnetic fields. The results show that the applied electric and magnetic fields have a great effect on these optical quantities. - Highlights: ► The x c concentration has a great effect on the optical characteristics of these structures. ► The EM fields have a great effect on the optical properties of these structures. ► The total absorption coefficients increased as the electric and magnetic field increases. ► The RICs reduced as the electric and magnetic field increases.

  1. Non-linear Membrane Properties in Entorhinal Cortical Stellate Cells Reduce Modulation of Input-Output Responses by Voltage Fluctuations

    Science.gov (United States)

    Fernandez, Fernando R.; Malerba, Paola; White, John A.

    2015-01-01

    The presence of voltage fluctuations arising from synaptic activity is a critical component in models of gain control, neuronal output gating, and spike rate coding. The degree to which individual neuronal input-output functions are modulated by voltage fluctuations, however, is not well established across different cortical areas. Additionally, the extent and mechanisms of input-output modulation through fluctuations have been explored largely in simplified models of spike generation, and with limited consideration for the role of non-linear and voltage-dependent membrane properties. To address these issues, we studied fluctuation-based modulation of input-output responses in medial entorhinal cortical (MEC) stellate cells of rats, which express strong sub-threshold non-linear membrane properties. Using in vitro recordings, dynamic clamp and modeling, we show that the modulation of input-output responses by random voltage fluctuations in stellate cells is significantly limited. In stellate cells, a voltage-dependent increase in membrane resistance at sub-threshold voltages mediated by Na+ conductance activation limits the ability of fluctuations to elicit spikes. Similarly, in exponential leaky integrate-and-fire models using a shallow voltage-dependence for the exponential term that matches stellate cell membrane properties, a low degree of fluctuation-based modulation of input-output responses can be attained. These results demonstrate that fluctuation-based modulation of input-output responses is not a universal feature of neurons and can be significantly limited by subthreshold voltage-gated conductances. PMID:25909971

  2. Nonlinear viscoelastic behaviour of shells of revolution under arbitrary loading

    International Nuclear Information System (INIS)

    Leonard, J.W.; Arbabi-Kanjoori, F.

    1975-01-01

    A formulation and solution technique are presented for the creep analysis of shells of revolution subjected to arbitrary loads and temperature changes. Arbitrary creep laws are admitted in the formulation with specific attention given to the two common laws, i.e. strain hardening and time hardening. The governing equations for creep of shells of revolution are derived. The solution method requires the quasi-static linearization of the equations: linear incremental behaviour is assumed during each time step. The incremental equations are expanded in Fourier series and solved by a numerical integration technique. (Auth.)

  3. Investigation on nonlinear optical properties of MoS2 nanoflakes grown on silicon and quartz substrates

    Science.gov (United States)

    Bayesteh, Samaneh; Zahra Mortazavi, Seyedeh; Reyhani, Ali

    2018-05-01

    In this study, MoS2 nanoflakes were directly grown on different substrates—Si/SiO2 and quartz—by one-step thermal chemical vapor deposition using MoO3 and sulfide powders as precursors. Scanning electron microscopy and x-ray diffraction patterns demonstrated the formation of MoS2 structures on both substrates. Moreover, UV-visible and photoluminescence analysis confirmed the formation of MoS2 few-layer structures. According to Raman spectroscopy, by assessment of the line width and frequency shift differences between the and A 1g, it was inferred that the MoS2 grown on the silicon substrate was monolayer and that grown on the quartz substrate was multilayer. In addition, open-aperture and close-aperture Z-scan techniques were employed to study the nonlinear optical properties including nonlinear absorption and nonlinear refraction of the grown MoS2. All experiments were performed using a diode laser with a wavelength of 532 nm as the light source. It is noticeable that both samples demonstrate obvious self-defocusing behavior. The monolayer MoS2 grown on the silicon substrate displayed considerable two-photon absorption while, the multilayer MoS2 synthesized on the quartz exhibited saturable absorption. In general, few-layered MoS2 would be useful for the development of nanophotonic devices like optical limiters, optical switchers, etc.

  4. Investigation on nonlinear optical properties of MoS2 nanoflake, grown on silicon and quartz substrates

    Science.gov (United States)

    Bayesteh, S.; Mortazavi, S. Z.; Reyhani, A.

    2018-03-01

    In this study, MoS2 was directly synthesized by one-step thermal chemical vapour deposition (TCVD), on different substrates including Si/SiO2 and quartz, using MoO3 and sulfide powders as precursor. The XRD patterns demonstrate the high crystallinity of MoS2 on Si/SiO2 and quartz substrates. SEM confirmed the formation of MoS2 grown on both substrates. According to line width and frequency difference between the E1 2g and A1g in Raman spectroscopy, it is inferred that the MoS2 grown on Si/SiO2 substrate is monolayer and the MoS2 grown on quartz substrate is multilayer. Moreover, by assessment of MoS2 nanoflake band gap via UV-visible analysis, it verified the formation of few layer structures. In addition, the open-aperture and close-aperture Z-scan techniques were employed to study the nonlinear optical properties including nonlinear absorption and nonlinear refraction of the synthesized MoS2. All experiments were performed using a diode laser with a wavelength of 532 nm as light source. The monolayer MoS2 synthesized on Si/SiO2, display considerable two-photon absorption. However, the multilayer MoS2 synthesized on quartz displayed saturable absorption (SA). It is noticeable that both samples demonstrate obvious self-defocusing behaviour.

  5. Enhanced linear and nonlinear optical properties of thermally stable ZnO/poly(styrene)–poly(methyl methacrylate) nanocomposite films

    International Nuclear Information System (INIS)

    Jeeju, P.P.; Jayalekshmi, S.; Chandrasekharan, K.; Sudheesh, P.

    2013-01-01

    Highly transparent and thermally stable zinc oxide (ZnO)/poly(styrene)–poly(methyl methacrylate) (PS–PMMA) nanocomposite films have been deposited on glass substrates, from the ZnO incorporated (PS–PMMA) solutions in toluene, using spin coating technique. A chemical route at room temperature is used to synthesize the ZnO nanoparticles. Transmission electron microscope and high-resolution transmission electron microscope images show that the ZnO nanoparticles are of size around 10 nm. The composite films have been characterized by X-ray diffraction, Fourier transform infrared spectroscopy, atomic force microscopy, Ultraviolet–visible–Near Infrared (UV–vis–NIR) spectroscopy, Thermo-gravimetric analysis, photoluminescence (PL) spectroscopy and Z-scan technique. From the UV–vis–NIR spectra it is observed that the ZnO/PS–PMMA nanocomposite films with 10 wt.% ZnO content exhibit excellent shielding property in the UV region and, high transparency in the visible region. The PL spectrum of the composite films is different from that of ZnO and PS–PMMA blend and exhibits an excitonic emission peak at ∼ 375 nm. The optical absorptive nonlinearity in the nanocomposite films is investigated using open aperture Z-scan technique. The results indicate optical limiting type nonlinearity in the films due to two photon absorption. A transmittance minimum of around 0.25 has been observed in the ZnO/PS–PMMA nanocomposite films which is much lower compared to that in ZnO/PMMA and ZnO/PS nanocomposite films. The ZnO/PS–PMMA nanocomposite films also show a self-defocusing type negative nonlinear refraction in closed aperture Z-scan experiment. These nanocomposite films extend ample scope of applications as excellent optical limiters and efficient UV protectors. - Highlights: ► Transparent, ZnO/poly(styrene)–poly(methyl methacrylate) composite films are prepared. ► The nanocomposite films with 10 wt.% ZnO content exhibit good UV-shielding property.

  6. Enhanced linear and nonlinear optical properties of thermally stable ZnO/poly(styrene)–poly(methyl methacrylate) nanocomposite films

    Energy Technology Data Exchange (ETDEWEB)

    Jeeju, P.P., E-mail: jeejupp@gmail.com [Division for Research in Advanced Materials, Department of Physics, Cochin University of Science and Technology, Kochi 682 022, Kerala (India); Jayalekshmi, S., E-mail: jayalekshmi@cusat.ac.in [Division for Research in Advanced Materials, Department of Physics, Cochin University of Science and Technology, Kochi 682 022, Kerala (India); Chandrasekharan, K.; Sudheesh, P. [Department of Physics, National Institute of Technology, Calicut, Kerala (India)

    2013-03-01

    Highly transparent and thermally stable zinc oxide (ZnO)/poly(styrene)–poly(methyl methacrylate) (PS–PMMA) nanocomposite films have been deposited on glass substrates, from the ZnO incorporated (PS–PMMA) solutions in toluene, using spin coating technique. A chemical route at room temperature is used to synthesize the ZnO nanoparticles. Transmission electron microscope and high-resolution transmission electron microscope images show that the ZnO nanoparticles are of size around 10 nm. The composite films have been characterized by X-ray diffraction, Fourier transform infrared spectroscopy, atomic force microscopy, Ultraviolet–visible–Near Infrared (UV–vis–NIR) spectroscopy, Thermo-gravimetric analysis, photoluminescence (PL) spectroscopy and Z-scan technique. From the UV–vis–NIR spectra it is observed that the ZnO/PS–PMMA nanocomposite films with 10 wt.% ZnO content exhibit excellent shielding property in the UV region and, high transparency in the visible region. The PL spectrum of the composite films is different from that of ZnO and PS–PMMA blend and exhibits an excitonic emission peak at ∼ 375 nm. The optical absorptive nonlinearity in the nanocomposite films is investigated using open aperture Z-scan technique. The results indicate optical limiting type nonlinearity in the films due to two photon absorption. A transmittance minimum of around 0.25 has been observed in the ZnO/PS–PMMA nanocomposite films which is much lower compared to that in ZnO/PMMA and ZnO/PS nanocomposite films. The ZnO/PS–PMMA nanocomposite films also show a self-defocusing type negative nonlinear refraction in closed aperture Z-scan experiment. These nanocomposite films extend ample scope of applications as excellent optical limiters and efficient UV protectors. - Highlights: ► Transparent, ZnO/poly(styrene)–poly(methyl methacrylate) composite films are prepared. ► The nanocomposite films with 10 wt.% ZnO content exhibit good UV-shielding property.

  7. Preparation, characterization, and nonlinear optical properties of hybridized graphene @ gold nanorods nanocomposites

    Science.gov (United States)

    Guo, Jia; Ning, Tingyin; Han, Yanshun; Sheng, Yingqiang; Li, Chonghui; Zhao, Xiaofei; Lu, Zhengyi; Man, Baoyuan; Jiao, Yang; Jiang, Shouzhen

    2018-03-01

    The methods of chemical vapor deposition (CVD) and seed-mediated growth were used to obtain graphene and gold nanorods (GNRs), respectively. We fabricate graphene @ gold nanorods (G@GNRs) nanocomposites by successively using dropping and transferring methods Through SEM, Raman spectra and TEM analysis, the number of graphene layers is 6-7. The diameter of gold nanorods (GNRs) is about 10 nm and the average aspect ratio is 6.5. In addition, we systematically investigate their nonlinear optical responses by using open-aperture Z-scan technique. In contrast with graphene and GNRs, the G@GNRs nanocomposites exhibit excellent nonlinear optical response with a modulation depth of about 51% and a saturable intensity of about 6.23 GW/cm2. The results suggest that the G@GNRs nanocomposites could potentially be used as an optical modulator in pulsed laser generation.

  8. Nanoparticles and nonlinear thermal radiation properties in the rheology of polymeric material

    Directory of Open Access Journals (Sweden)

    M. Awais

    2018-03-01

    Full Text Available The present analysis is related to the dynamics of polymeric liquids (Oldroyd-B model with the presence of nanoparticles. The rheological system is considered under the application of nonlinear thermal radiations. Energy and concentration equations are presented when thermophoresis and Brownian motion effects are present. Bidirectional form of stretching is considered to interpret the three-dimensional flow dynamics of polymeric liquid. Making use of the similarity transformations, problem is reduced into ordinary differential system which is approximated by using HAM. Influence of physical parameters including Deborah number, thermophoresis and Brownian motion on velocity, temperature and mass fraction expressions are plotted and analyzed. Numerical values for local Sherwood and Nusselt numbers are presented and discussed. Keywords: Nanoparticles, Polymeric liquid, Oldroyd-B model, Nonlinear thermal radiation

  9. Non-linear optical properties of SiO2 with synthesized by implantation copper nanoparticles

    International Nuclear Information System (INIS)

    Stepanov, A.L.; Olivares, J.; Requejo-Isidro, J.; Del Coso, R.; De Nalda, R.; Solis, J.; Afonso, C.N.; Hole, D.; Townsend, P.D.; Naudon, A.

    2001-01-01

    In recent years there has been a growing interest in composite dielectrics containing metal nanoparticles for their potential application in wave-guide integrated all-optical non-linear switching devices. In present work, low energy high current ion implantation (50 keV) in silica at a well controlled substrate temperature (20 0 C) at a dose of 8·10 16 ion/cm 2 has been used to produce novel composites containing a large concentration of spherical Cu clusters with an average diameter of 4 nm and a very narrow size distribution. A very large value for the third order optical susceptibility, χ (3) = 10 -7 esu, has been measured in the vicinity of the surface plasmon resonance by degenerate four wave mixing at 585 nm. This value is among the largest values ever reported for Cu nano composites. Additionally, the response time of the non-linearity has been found to be shorter than 2 ps. The superior non-linear optical response of these implants is discussed in terms of the implantation conditions

  10. A frictional contact problem for an electro-viscoelastic body

    Directory of Open Access Journals (Sweden)

    Mircea Sofonea

    2007-12-01

    Full Text Available A mathematical model which describes the quasistatic frictional contact between a piezoelectric body and a deformable conductive foundation is studied. A nonlinear electro-viscoelastic constitutive law is used to model the piezoelectric material. Contact is described with the normal compliance condition, a version of Coulomb's law of dry friction, and a regularized electrical conductivity condition. A variational formulation of the model, in the form of a coupled system for the displacements and the electric potential, is derived. The existence of a unique weak solution of the model is established under a smallness assumption on the surface conductance. The proof is based on arguments of evolutionary variational inequalities and fixed points of operators.

  11. Effect of structure on nonlinear optical properties in CaCu{sub 3}Ti{sub 4}O{sub 12} films

    Energy Technology Data Exchange (ETDEWEB)

    Ning, Tingyin [School of Physics and Electronics, Shandong Normal University, Jinan 250014 (China); Zhou, Yueliang, E-mail: ylzhou@iphy.ac.cn [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

    2015-12-21

    We report the third-order nonlinear optical properties of CaCu{sub 3}Ti{sub 4}O{sub 12} films with different preferred growth orientations on MgO and fused silica substrates. The films have (310)- and (220)-orientation on MgO and fused silica, respectively, due to the lattice-mismatch. Raman spectra further indicate different atom-bonding states in the films. The nonlinear optical measurements show the films possess the same self-defocusing behavior but with different values of nonlinear refraction, and changed signs of nonlinear absorption. The difference of optical nonlinearity in CaCu{sub 3}Ti{sub 4}O{sub 12} films is ascribed to different lattice parameters and intermediate levels induced by structure.

  12. Approximation of Viscoelastic Stresses from Newtonian Turbulent Kinematics

    Science.gov (United States)

    1988-09-01

    birefringence of polyethylene oxide solutions in a four roll mill. J.Poly.Sci.:Poly.Phys.Ed. 14, 1111-1119. Dandridge, A., Meeten , G.H., Layec-Raphalen, M.N...flows. Poly. Comm. 25, 144-146. Metzner, A.B., & Astarita, G . 1967 External flow of viscoelastic materials: fluid property restrictions on the use of...dumbbell model for dilute solutions. Rheol.Acta 23, 151-162. Philippoff, W. 1956 Flow-birefringence and stress. Nature 178 , 811-812. Ryskin, G . 1987a

  13. Nonlinear optical properties of ZnO/poly (vinyl alcohol) nanocomposite films

    International Nuclear Information System (INIS)

    Jeeju, P. P.; Jayalekshmi, S.; Chandrasekharan, K.

    2014-01-01

    Extensive studies have already been reported on the optical characteristics of ZnO/polymer nanocomposite films, using a variety of polymers including transparent polymers such as polystyrene, polymethyl methacrylate etc and many interesting results have been established regarding the non linear optical characteristics of these systems. Poly (vinyl alcohol)(PVA) is a water soluble polymer. Though the structural and optical studies of ZnO/PVA nanocomposite films have already been investigated, there are no detailed reports on the nonlinear optical characteristics of ZnO/PVA nanocomposite films, irrespective of the fact that these nanocomposite films can be synthesized using quite easy and cost effective methods. The present work is an attempt to study in detail the nonlinear optical behaviour of ZnO/PVA nanocomposite films using Z-scan technique. Highly transparent ZnO/PVA nanocomposite films were prepared from the ZnO incorporated PVA solution in water using spin coating technique. The ZnO nanoparticles were synthesized by the simple chemical route at room temperature. High-resolution transmission electron microscopy studies show that the ZnO nanoparticles are of size around 10 nm. The ZnO/PVA nanocomposite films were structurally characterized by X-ray diffraction technique, from which the presence of both PVA and ZnO in the nanocomposite was established. The optical absorptive nonlinearity in the nanocomposite films was investigated using open aperture Z-scan technique. The results indicate optical limiting type nonlinearity in the films due to two photon absorption in ZnO with efficiency more than 50%. These films also show a self defocusing type negative nonlinear refraction in closed aperture Z-scan experiment. The present studies indicate that, highly transparent and homogeneous films of ZnO/PVA nanocomposite can be obtained on glass substrates using simple methods, in a highly cost effective way, since PVA is water soluble. These nanocomposite films offer

  14. A Solution Method for Linear and Geometrically Nonlinear MDOF Systems with Random Properties subject to Random Excitation

    DEFF Research Database (Denmark)

    Micaletti, R. C.; Cakmak, A. S.; Nielsen, Søren R. K.

    structural properties. The resulting state-space formulation is a system of ordinary stochastic differential equations with random coefficient and deterministic initial conditions which are subsequently transformed into ordinary stochastic differential equations with deterministic coefficients and random......A method for computing the lower-order moments of randomly-excited multi-degree-of-freedom (MDOF) systems with random structural properties is proposed. The method is grounded in the techniques of stochastic calculus, utilizing a Markov diffusion process to model the structural system with random...... initial conditions. This transformation facilitates the derivation of differential equations which govern the evolution of the unconditional statistical moments of response. Primary consideration is given to linear systems and systems with odd polynomial nonlinearities, for in these cases...

  15. Nonlinear optical properties of a three-electron quantum dot with account of the Rashba spin-orbit interaction

    Energy Technology Data Exchange (ETDEWEB)

    Hassanabadi, Hassan, E-mail: h.hasanabadi@shahroodut.ac.ir [Physics Department, Shahrood University of Technology, P.O. Box 3619995161-316, Shahrood (Iran, Islamic Republic of); Rahimov, Hamed [Physics Department, Shahrood University of Technology, P.O. Box 3619995161-316, Shahrood (Iran, Islamic Republic of); Lu Liangliang [Department of Physics, College of Physics and Electronic Engineering, Guangzhou University, Guangzhou 510006 (China); Wang Chao [Institute of Public Administration, Guangzhou University, Guangzhou 510006 (China)

    2012-05-15

    In this study, a detailed investigation of the nonlinear optical properties such as optical absorption and refractive index change associated with intersubband transitions in a three-electron quantum dot in two dimensions in the presence of the Rashba spin-orbit interaction has been carried out. We present the exact wave functions and energy levels of the system. Numerical results on typical GaAs/AlGaAs materials show that the decrease of the quantum dot radius blueshifts and amplifies the absorption coefficients as well as the refractive index changes, as expected. Additionally, an increase of the optical intensity and relaxation time considerably changes the absorption coefficients and the refractive index changes. - Highlights: Black-Right-Pointing-Pointer We consider a three-electron quantum dot in 2D in the presence of the Rashba spin-orbit interaction. Black-Right-Pointing-Pointer We present the exact wave functions and energy levels of the system. Black-Right-Pointing-Pointer We apply this model for GaAs/AlGaAs materials. Black-Right-Pointing-Pointer The detailed nonlinear optical properties have been investigated.

  16. An Image-Based Finite Element Approach for Simulating Viscoelastic Response of Asphalt Mixture

    Directory of Open Access Journals (Sweden)

    Wenke Huang

    2016-01-01

    Full Text Available This paper presents an image-based micromechanical modeling approach to predict the viscoelastic behavior of asphalt mixture. An improved image analysis technique based on the OTSU thresholding operation was employed to reduce the beam hardening effect in X-ray CT images. We developed a voxel-based 3D digital reconstruction model of asphalt mixture with the CT images after being processed. In this 3D model, the aggregate phase and air void were considered as elastic materials while the asphalt mastic phase was considered as linear viscoelastic material. The viscoelastic constitutive model of asphalt mastic was implemented in a finite element code using the ABAQUS user material subroutine (UMAT. An experimental procedure for determining the parameters of the viscoelastic constitutive model at a given temperature was proposed. To examine the capability of the model and the accuracy of the parameter, comparisons between the numerical predictions and the observed laboratory results of bending and compression tests were conducted. Finally, the verified digital sample of asphalt mixture was used to predict the asphalt mixture viscoelastic behavior under dynamic loading and creep-recovery loading. Simulation results showed that the presented image-based digital sample may be appropriate for predicting the mechanical behavior of asphalt mixture when all the mechanical properties for different phases became available.

  17. Finite element reduction strategy for composite sandwich plates with viscoelastic layers

    Directory of Open Access Journals (Sweden)

    Adriana Amaro Diacenco

    2013-04-01

    Full Text Available Composite materials have been regarded as a convenient strategy in various types of engineering systems such as aeronautical and space structures, as well as architecture and light industry products due to their advantages over the traditional engineering materials, such as their high strength/stiffness relation characteristics and their anti-corrosion properties. This paper is devoted to the finite element modeling of composite laminated structures incorporating viscoelastic materials to the problem of vibration attenuation. However, the typically high dimension of large finite element models of composite structures incorporating viscoelastic materials makes the numerical processes sometimes unfeasible. Within this context, emphasis is placed on a general condensation strategy specially adapted for the case of viscoelastically damped structures, in which a constant (frequency- and temperature-independent reduction basis to be enriched by static residues associated to the applied loads and the viscoelastic forces is used. After presenting the theoretical foundations, the numerical applications of composite plates treated by viscoelastic materials are addressed, and the main features of the methodology are discussed.

  18. Finite element reduction strategy for composite sandwich plates with viscoelastic layers

    Directory of Open Access Journals (Sweden)

    Adriana Amaro Diacenco

    2012-01-01

    Full Text Available Composite materials have been regarded as a convenient strategy in various types of engineering systems such as aeronautical and space structures, as well as architecture and light industry products due to their advantages over the traditional engineering materials, such as their high strength/stiffness relation characteristics and their anti-corrosion properties. This paper is devoted to the finite element modeling of composite laminated structures incorporating viscoelastic materials to the problem of vibration attenuation. However, the typically high dimension of large finite element models of composite structures incorporating viscoelastic materials makes the numerical processes sometimes unfeasible. Within this context, emphasis is placed on a general condensation strategy specially adapted for the case of viscoelastically damped structures, in which a constant (frequency- and temperature-independent reduction basis to be enriched by static residues associated to the applied loads and the viscoelastic forces is used. After presenting the theoretical foundations, the numerical applications of composite plates treated by viscoelastic materials are addressed, and the main features of the methodology are discussed.

  19. Simulating Seismic Wave Propagation in Viscoelastic Media with an Irregular Free Surface

    Science.gov (United States)

    Liu, Xiaobo; Chen, Jingyi; Zhao, Zhencong; Lan, Haiqiang; Liu, Fuping

    2018-05-01

    In seismic numerical simulations of wave propagation, it is very important for us to consider surface topography and attenuation, which both have large effects (e.g., wave diffractions, conversion, amplitude/phase change) on seismic imaging and inversion. An irregular free surface provides significant information for interpreting the characteristics of seismic wave propagation in areas with rugged or rapidly varying topography, and viscoelastic media are a better representation of the earth's properties than acoustic/elastic media. In this study, we develop an approach for seismic wavefield simulation in 2D viscoelastic isotropic media with an irregular free surface. Based on the boundary-conforming grid method, the 2D time-domain second-order viscoelastic isotropic equations and irregular free surface boundary conditions are transferred from a Cartesian coordinate system to a curvilinear coordinate system. Finite difference operators with second-order accuracy are applied to discretize the viscoelastic wave equations and the irregular free surface in the curvilinear coordinate system. In addition, we select the convolutional perfectly matched layer boundary condition in order to effectively suppress artificial reflections from the edges of the model. The snapshot and seismogram results from numerical tests show that our algorithm successfully simulates seismic wavefields (e.g., P-wave, Rayleigh wave and converted waves) in viscoelastic isotropic media with an irregular free surface.

  20. Efeito do uso de cultura adjunta (Lactobacillus helveticus na proteólise, propriedades viscoelásticas e aceitação sensorial de queijo prato light Effect of adjunct culture (Lactobacillus helveticus on proteolysis, viscoelastic properties and sensory acceptance of reduced fat prato cheese

    Directory of Open Access Journals (Sweden)

    Christiane Maciel V. Barros

    2006-03-01

    Full Text Available A proteólise, as propriedades viscoelásticas e a aceitação sensorial de queijo prato light fabricado com e sem adição de cultura adjunta (CAD foram avaliadas. Os queijos foram fabricados a partir de leite microfiltrado. Dois tratamentos foram testados em duplicata: o queijo controle foi fabricado apenas com cultura mesófila tradicional (acidificante e aromatizante, e o outro foi fabricado com adição de CAD (Lactobacillus helveticus, além da cultura tradicional. A composição dos queijos foi determinada no quinto dia após a fabricação. A proteólise e as propriedades reológicas foram avaliadas nos dias 5, 25 e 45 após a fabricação. Os parâmetros viscoelásticos foram obtidos a partir de testes de relaxação. As amostras foram avaliadas sensorialmente por meio de testes de aceitação. Não houve diferença significativa (p>0,05 na composição dos queijos. Os índices de profundidade de proteólise foram significativamente (p0,05. Nos testes de aceitação sensorial, o queijo produzido com CAD obteve notas significativamente (pProteolysis, viscoelastic properties and sensory acceptance of reduced fat Prato cheeses made with and without adjunt culture (AC were evaluated. The cheeses were made from microfiltered milk. Two different treatments were replicated twice: control cheese was made only with traditional starter, while the other was made with the addition of both AC (Lactobacillus helveticus and traditional starter. Cheese composition was determined after 5 days of manufacture. Proteolysis and rheological properties were evaluated after 5, 25 and 45 days. Viscoelastic parameters were obtained using relaxation tests. Cheese sensory properties were evaluated using acceptability tests. There was no statistical difference (p>0,05 in cheese composition. The proteolysis depth indexes were significantly higher (p0.05 in viscoelastic parameters for cheeses made with and without AC. Sensory acceptability tests indicated significant

  1. Diagnostic study of the roughness surface effect of zirconium on the third-order nonlinear-optical properties of thin films based on zinc oxide nanomaterials

    International Nuclear Information System (INIS)

    Bahedi, K.; Addou, M.; El Jouad, M.; Sofiani, Z.; Alaoui Lamrani, M.; El Habbani, T.; Fellahi, N.; Bayoud, S.; Dghoughi, L.; Sahraoui, B.; Essaidi, Z.

    2009-01-01

    Zinc oxide (ZnO) and zirconium doped zinc oxide (ZnO:Zr) thin films were deposited by reactive chemical pulverization spray pyrolysis technique on heated glass substrates at 500 deg. C using zinc and zirconium chlorides as precursors. Effects of zirconium doping agent and surface roughness on the nonlinear optical properties were investigated in detail using atomic force microscopy (AFM) and third harmonic generation (THG) technique. The best value of nonlinear optical susceptibility χ (3) was obtained from the doped films with less roughness. A strong third order nonlinear optical susceptibility χ (3) = 20.12 x 10 -12 (esu) of the studied films was found for the 3% doped sample.

  2. Modeling Asymmetric Flow of Viscoelastic Fluid in Symmetric Planar Sudden Expansion Geometry Based on User-Defined Function in FLUENT CFD Package

    Directory of Open Access Journals (Sweden)

    Zhi-Ying Zheng

    2013-01-01

    Full Text Available Through embedding an in-house subroutine into FLUENT code by utilizing the functionalization of user-defined function provided by the software, a new numerical simulation methodology on viscoelastic fluid flows has been established. In order to benchmark this methodology, numerical simulations under different viscoelastic fluid solution concentrations (with solvent viscosity ratio varied from 0.2 to 0.9, extensibility parameters (100≤L2≤500, Reynolds numbers (0.1 ≤ Re ≤ 100, and Weissenberg numbers (0 ≤ Wi ≤ 20 are conducted on unsteady laminar flows through a symmetric planar sudden expansion with expansion ratio of 1: 3 for viscoelastic fluid flows. The constitutive model used to describe the viscoelastic effect of viscoelastic fluid flow is FENE-P (finitely extensive nonlinear elastic-Peterlin model. The numerical simulation results show that the influences of elasticity, inertia, and concentration on the flow bifurcation characteristics are more significant than those of extensibility. The present simulation results including the critical Reynolds number for which the flow becomes asymmetric, vortex size, bifurcation diagram, velocity distribution, streamline, and pressure loss show good agreements with some published results. That means the newly established method based on FLUENT software platform for simulating peculiar flow behaviors of viscoelastic fluid is credible and suitable for the study of viscoelastic fluid flows.

  3. Brain viscoelasticity alteration in chronic-progressive multiple sclerosis.

    Directory of Open Access Journals (Sweden)

    Kaspar-Josche Streitberger

    Full Text Available INTRODUCTION: Viscoelastic properties indicate structural alterations in biological tissues at multiple scales with high sensitivity. Magnetic Resonance Elastography (MRE is a novel technique that directly visualizes and quantitatively measures biomechanical tissue properties in vivo. MRE recently revealed that early relapsing-remitting multiple sclerosis (MS is associated with a global decrease of the cerebral mechanical integrity. This study addresses MRE and MR volumetry in chronic-progressive disease courses of MS. METHODS: We determined viscoelastic parameters of the brain parenchyma in 23 MS patients with primary or secondary chronic progressive disease course in comparison to 38 age- and gender-matched healthy individuals by multifrequency MRE, and correlated the results with clinical data, T2 lesion load and brain volume. Two viscoelastic parameters, the shear elasticity μ and the powerlaw exponent α, were deduced according to the springpot model and compared to literature values of relapsing-remitting MS. RESULTS: In chronic-progressive MS patients, μ and α were reduced by 20.5% and 6.1%, respectively, compared to healthy controls. MR volumetry yielded a weaker correlation: Total brain volume loss in MS patients was in the range of 7.5% and 1.7% considering the brain parenchymal fraction. All findings were significant (P<0.001. CONCLUSIONS: Chronic-progressive MS disease courses show a pronounced reduction of the cerebral shear elasticity compared to early relapsing-remitting disease. The powerlaw exponent α decreased only in the chronic-progressive stage of MS, suggesting an alteration in the geometry of the cerebral mechanical network due to chronic neuroinflammation.

  4. Linear and nonlinear optical properties of a hydrogenic donor in lens-shaped quantum dots

    International Nuclear Information System (INIS)

    Vahdani, M.R.K.; Rezaei, G.

    2009-01-01

    Optical transitions in a Lens-Shaped Quantum Dot (LSD) are investigated in the presence of a hydrogenic impurity. The electronic wave functions are obtained analytically and the energy eigenvalues are calculated numerically. The density matrix formulation with the intersubband relaxation are used to evaluate the (linear and third order nonlinear) absorption coefficient (AC) and the change in the refractive indices (RI) analytically. The effect of the size of the LSD and optical intensity on the AC and RI are investigated. It is found that AC and RI are strongly affected by the optical intensity and the size of the LSD.

  5. Properties of Energy Spectra of Molecular Crystals Investigated by Nonlinear Theory

    Science.gov (United States)

    Pang, Xiao-Feng; Zhang, Huai-Wu

    We calculate the quantum energy spectra of molecular crystals, such as acetanilide, by using discrete nonlinear Schrodinger equation, containing various interactions, appropriate to the systems. The energy spectra consist of many energy bands, in each energy band there are a lot of energy levels including some higher excited states. The result of energy spectrum is basically consistent with experimental values obtained by infrared absorption and Raman scattering in acetanilide and can also explain some experimental results obtained by Careri et al. Finally, we further discuss the influences of variously characteristic parameters on the energy spectra of the systems.

  6. Linear and nonlinear optical properties of a hydrogenic donor in lens-shaped quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Vahdani, M.R.K. [Department of Physics, College of Sciences, Shiraz University, Shiraz 71454 (Iran, Islamic Republic of); Rezaei, G., E-mail: grezaei@mail.yu.ac.i [Department of Physics, College of Sciences, Yasouj University, Yasouj 75914 (Iran, Islamic Republic of)

    2009-08-17

    Optical transitions in a Lens-Shaped Quantum Dot (LSD) are investigated in the presence of a hydrogenic impurity. The electronic wave functions are obtained analytically and the energy eigenvalues are calculated numerically. The density matrix formulation with the intersubband relaxation are used to evaluate the (linear and third order nonlinear) absorption coefficient (AC) and the change in the refractive indices (RI) analytically. The effect of the size of the LSD and optical intensity on the AC and RI are investigated. It is found that AC and RI are strongly affected by the optical intensity and the size of the LSD.

  7. Coefficient of restitution in fractional viscoelastic compliant impacts using fractional Chebyshev collocation

    Science.gov (United States)

    Dabiri, Arman; Butcher, Eric A.; Nazari, Morad

    2017-02-01

    Compliant impacts can be modeled using linear viscoelastic constitutive models. While such impact models for realistic viscoelastic materials using integer order derivatives of force and displacement usually require a large number of parameters, compliant impact models obtained using fractional calculus, however, can be advantageous since such models use fewer parameters and successfully capture the hereditary property. In this paper, we introduce the fractional Chebyshev collocation (FCC) method as an approximation tool for numerical simulation of several linear fractional viscoelastic compliant impact models in which the overall coefficient of restitution for the impact is studied as a function of the fractional model parameters for the first time. Other relevant impact characteristics such as hysteresis curves, impact force gradient, penetration and separation depths are also studied.

  8. Stress-based viscoelastic master curve construction of model tire tread compounds

    NARCIS (Netherlands)

    Maghami, S.; Dierkes, W.; Noordermeer, J.W.M.; Tolpekina, T.; Schultz, S.; Gögelein, C.; Wrana, C.; Gil-Negrete, Nere; Asier, Alonso

    2013-01-01

    One of the important aspects in the development of new tire compounds is the correlation between the dynamic mechanical properties of the rubber, measured on laboratory scale, and the actual tire performance. In order to predict wet traction, the viscoelastic behavior of the rubber materials at high

  9. Correlating non-linear properties with spectral states of RXTE data: possible observational evidences for four different accretion modes around compact objects

    Science.gov (United States)

    Adegoke, Oluwashina; Dhang, Prasun; Mukhopadhyay, Banibrata; Ramadevi, M. C.; Bhattacharya, Debbijoy

    2018-05-01

    By analysing the time series of RXTE/PCA data, the non-linear variabilities of compact sources have been repeatedly established. Depending on the variation in temporal classes, compact sources exhibit different non-linear features. Sometimes they show low correlation/fractal dimension, but in other classes or intervals of time they exhibit stochastic nature. This could be because the accretion flow around a compact object is a non-linear general relativistic system involving magnetohydrodynamics. However, the more conventional way of addressing a compact source is the analysis of its spectral state. Therefore, the question arises: What is the connection of non-linearity to the underlying spectral properties of the flow when the non-linear properties are related to the associated transport mechanisms describing the geometry of the flow? This work is aimed at addressing this question. Based on the connection between observed spectral and non-linear (time series) properties of two X-ray binaries: GRS 1915+105 and Sco X-1, we attempt to diagnose the underlying accretion modes of the sources in terms of known accretion classes, namely, Keplerian disc, slim disc, advection dominated accretion flow and general advective accretion flow. We explore the possible transition of the sources from one accretion mode to others with time. We further argue that the accretion rate must play an important role in transition between these modes.

  10. Parametric imaging of viscoelasticity using optical coherence elastography

    Science.gov (United States)

    Wijesinghe, Philip; McLaughlin, Robert A.; Sampson, David D.; Kennedy, Brendan F.

    2015-03-01

    We demonstrate imaging of soft tissue viscoelasticity using optical coherence elastography. Viscoelastic creep deformation is induced in tissue using step-like compressive loading and the resulting time-varying deformation is measured using phase-sensitive optical coherence tomography. From a series of co-located B-scans, we estimate the local strain rate as a function of time, and parameterize it using a four-parameter Kelvin-Voigt model of viscoelastic creep. The estimated viscoelastic strain and time constant are used to visualize viscoelastic creep in 2D, dual-parameter viscoelastograms. We demonstrate our technique on six silicone tissue-simulating phantoms spanning a range of viscoelastic parameters. As an example in soft tissue, we report viscoelastic contrast between muscle and connective tissue in fresh, ex vivo rat gastrocnemius muscle and mouse abdominal transection. Imaging viscoelastic creep deformation has the potential to provide complementary contrast to existing imaging modalities, and may provide greater insight into disease pathology.

  11. Viscoelastic love-type surface waves

    Science.gov (United States)

    Borcherdt, Roger D.

    2008-01-01

    The general theoretical solution for Love-Type surface waves in viscoelastic media provides theoreticalexpressions for the physical characteristics of the waves in elastic as well as anelastic media with arbitraryamounts of intrinsic damping. The general solution yields dispersion and absorption-coefficient curves for the waves as a function of frequency and theamount of intrinsic damping for any chosen viscoelastic model.Numerical results valid for a variety of viscoelastic models provide quantitative estimates of the physicalcharacteristics of the waves pertinent to models of Earth materials ranging from small amounts of damping in the Earth’s crust to moderate and large amounts of damping in soft soils and water-saturated sediments. Numerical results, presented herein, are valid for a wide range of solids and applications.

  12. Preparation and nonlinear optical properties of indium nanocrystals in sodium borosilicate glass by the sol–gel route

    International Nuclear Information System (INIS)

    Zhong, Jiasong; Xiang, Weidong; Zhao, Haijun; Chen, Zhaoping; Liang, Xiaojuan; Zhao, Wenguang; Chen, Guoxin

    2012-01-01

    Graphical abstract: The sodium borosilicate glass doped with indium nanocrystals have been successfully prepared by sol–gel methods. And the indium nanocrystals in tetragonal crystal system have formed uniformly in the glass, and the average diameter of indium nanocrystals is about 30 nm. The third-order optical nonlinear refractive index γ, absorption coefficient β, and susceptibility χ (3) of the glass are determined to be −4.77 × 10 −16 m 2 /W, 2.67 × 10 −9 m/W, and 2.81 × 10 −10 esu, respectively. Highlights: ► Indium nanocrystals embedded in glass matrix have been prepared by sol–gel route. ► The crystal structure and composition are investigated by XRD and XPS. ► Size and distribution of indium nanocrystals is determined by TEM. ► The third-order optical nonlinearity is investigated by using Z-scan technique. -- Abstract: The sodium borosilicate glass doped with indium nanocrystals have been successfully prepared by sol–gel route. The thermal stability behavior of the stiff gel is investigated by thermogravimetric (TG) and differential thermal (DTA) analysis. The crystal structure of the glass is characterized by X-ray powder diffraction (XRD). Particle composition is determined by X-ray photoelectron spectroscopy (XPS). Size and distribution of the nanocrystals are characterized by transmission electron microscopy (TEM) as well as high-resolution transmission electron microscopy (HRTEM). Results show that the indium nanocrystals in tetragonal crystal structure have formed in glass, and the average diameter is about 30 nm. Further, the glass is measured by Z-scan technique to investigate the nonlinear optical (NLO) properties. The third-order NLO coefficient χ (3) of the glass is determined to be 2.81 × 10 −10 esu. The glass with large third-order NLO coefficient is promising materials for applications in optical devices.

  13. Infrared reduction, an efficient method to control the non-linear optical property of graphene oxide in femtosecond regime

    Science.gov (United States)

    Bhattacharya, S.; Maiti, R.; Saha, S.; Das, A. C.; Mondal, S.; Ray, S. K.; Bhaktha, S. B. N.; Datta, P. K.

    2016-04-01

    Graphene Oxide (GO) has been prepared by modified Hummers method and it has been reduced using an IR bulb (800-2000 nm). Both as grown GO and reduced graphene oxide (RGO) have been characterized using Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). Raman spectra shows well documented Dband and G-band for both the samples while blue shift of G-band confirms chemical functionalization of graphene with different oxygen functional group. The XPS result shows that the as-prepared GO contains 52% of sp2 hybridized carbon due to the C=C bonds and 33% of carbon atoms due to the C-O bonds. As for RGO, increment of the atomic % of the sp2 hybridized carbon atom to 83% and rapid decrease in atomic % of C=O bonds confirm an efficient reduction with infrared radiation. UV-Visible absorption spectrum also confirms increment of conjugation with increased reduction. Non-linear optical properties of both GO and RGO are measured using single beam open aperture Z-Scan technique in femtosecond regime. Intensity dependent nonlinear phenomena are observed. Depending upon the intensity, both saturable absorption and two photon absorption contribute to the non-linearity of both the samples. Saturation dominates at low intensity (~ 127 GW/cm2) while two photon absorption become prominent at higher intensities (from 217 GW/cm2 to 302 GW/cm2). We have calculated the two-photon absorption co-efficient and saturation intensity for both the samples. The value of two photon absorption co-efficient (for GO~ 0.0022-0.0037 cm/GW and for RGO~ 0.0128-0.0143 cm/GW) and the saturation intensity (for GO~57 GW/cm2 and for RGO~ 194GW/cm2) is increased with reduction. Increase in two photon absorption coefficient with increasing intensity can also suggest that there may be multi-photon absorption is taking place.

  14. Structural characterizations, Hirshfeld surface analyses, and third-order nonlinear optical properties of two novel chalcone derivatives

    Science.gov (United States)

    Maidur, Shivaraj R.; Jahagirdar, Jitendra R.; Patil, Parutagouda Shankaragouda; Chia, Tze Shyang; Quah, Ching Kheng

    2018-01-01

    We report synthesis, characterizations, structure-property relationships, and third-order nonlinear optical studies for two new chalcone derivatives, (2E)-1-(anthracen-9-yl)-3-(4-bromophenyl)prop-2-en-1-one (Br-ANC) and (2E)-1-(anthracen-9-yl)-3-(4-chlorophenyl)prop-2-en-1-one (Cl-ANC). These derivatives were crystallized in the centrosymmetric monoclinic P21/c crystal structure. The intermolecular interactions of both the crystals were visualized by Hirshfeld surface analyses (HSA). The crystals are thermally stable up to their melting points (180.82 and 191.16 °C for Cl-ANC and Br-ANC, respectively). The geometry optimizations, FT-IR spectra, 1H and 13C NMR spectra, electronic absorption spectra, electronic transitions, and HOMO-LUMO energy gaps were studied by Density Functional Theory (DFT) at B3LYP/6-311+G(d, p) level. The theoretical results provide excellent agreement with experimental findings. The electric dipole moments, static polarizabilities, molecular electrostatic potentials (MEP) and global chemical reactivity descriptors (GCRD) were also theoretically computed. The materials exhibited good nonlinear absorption (NLA), nonlinear refraction (NLR) and optical limiting (OL) behavior under diode-pumped solid-state (DPSS) continuous wave (CW) laser excitation (532 nm and 200 mW). The NLO parameters such as NLA coefficient (β∼10-5 cmW-1), NLR index (n2∼10-10 cm2 W-1) and third-order NLO susceptibilities (χ(3) ∼10-7 esu) were measured. Further, we estimated one-photon and two-photon figures of merit, which satisfy the demands (W > 1 and T < 1) for all-optical switching. Thus, the present chalcone derivatives with anthracene moiety are potential materials for OL and optical switching applications.

  15. Nanostructured pyronin Y thin films as a new organic semiconductor: Linear/nonlinear optics, band gap and dielectric properties

    Energy Technology Data Exchange (ETDEWEB)

    Zahran, H.Y. [Metallurgical Lab.1, Nanoscience Laboratory for Environmental and Bio-medical Applications (NLEBA), Semiconductor Lab., Department of Physics, Faculty of Education, Ain Shams University, Roxy, 11757 Cairo (Egypt); Advanced Functional Materials & Optoelectronic Laboratory (AFMOL), Department of Physics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha (Saudi Arabia); Yahia, I.S., E-mail: dr_isyahia@yahoo.com [Metallurgical Lab.1, Nanoscience Laboratory for Environmental and Bio-medical Applications (NLEBA), Semiconductor Lab., Department of Physics, Faculty of Education, Ain Shams University, Roxy, 11757 Cairo (Egypt); Advanced Functional Materials & Optoelectronic Laboratory (AFMOL), Department of Physics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha (Saudi Arabia); Alamri, F.H. [Advanced Functional Materials & Optoelectronic Laboratory (AFMOL), Department of Physics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha (Saudi Arabia)

    2017-05-15

    Pyronin Y dye (PY) is a kind of xanthene derivatives. Thin films of pyronin Y were deposited onto highly cleaned glass substrates using low-cost/spin coating technique. The structure properties of pyronin Y thin films with different thicknesses were investigated by using X-ray diffraction (XRD) and atomic force microscope (AFM). PY thin films for all the studied thicknesses have an amorphous structure supporting the short range order of the grain size. AFM supports the nanostructure with spherical/clusters morphologies of the investigated thin films. The optical constants of pyronin Y thin films for various thicknesses were studied by using UV–vis–NIR spectrophotometer in the wavelength range 350–2500 nm. The transmittance T(λ), reflectance R(λ) spectral and absorbance (abs(λ)) were obtained for all film thicknesses at room temperature and the normal light incident. These films showed a high transmittance in the wide scale wavelengths. For different thicknesses of the studied thin films, the optical band gaps were determined and their values around 2 eV. Real and imaginary dielectric constants, dissipation factor and the nonlinear optical parameters were calculated in the wavelengths to the range 300–2500 nm. The pyronin Y is a new organic semiconductor with a good optical absorption in UV–vis regions and it is suitable for nonlinear optical applications. - Highlights: • Pyronin Y (PY) nanostructured thin films were deposited by using spin coating technique. • XRD/AFM were used to study the structure of PY films. • The optical band gap was calculated on the basis of Tauc's model. • Linear/nonlinear optical parameters are calculated and interpreted via the applied optical theories. • PY thin films is a new organic semiconductor for its application in optoelectronic devices.

  16. Effect of rotation on the onset of thermal convection in a viscoelastic fluid layer

    Energy Technology Data Exchange (ETDEWEB)

    Swamy, Mahantesh S [Department of Mathematics, Government College, Gulbarga 585 105 (India); Sidram, W, E-mail: mahantesh_swamy@yahoo.co.in [Department of Mathematics, Gulbarga University, Jnana Ganga, Gulbarga 585 106 (India)

    2013-02-15

    A rotating viscoelastic fluid layer heated from below is studied analytically using both linear and nonlinear stability analyses. The Oldroyd-B fluid model is employed to describe the rheological behaviour of the fluid. The Coriolis term is included in the momentum equation and the Oberbeck-Boussinesq approximation is invoked. The onset criterion for both stationary and oscillatory convection is derived as a function of Taylor number, Prandtl number and viscoelastic parameters. There is competition between the processes of rotation, viscous relaxation and thermal diffusion that causes the convection to set in through oscillatory rather than stationary modes. The rotation inhibits the onset of convection in both stationary and oscillatory modes. The stress relaxation parameter destabilizes the system towards the oscillatory mode, while the strain retardation parameter enhances the stability and this stabilization is reinforced by the rotation effect. The nonlinear theory is based on a truncated representation of the Fourier series method. The effect of rotation, viscoelastic parameters and also the Prandtl number on the transient heat transfer is presented graphically. (paper)

  17. Third-order nonlinear optical properties of thin sputtered gold films

    Science.gov (United States)

    Xenogiannopoulou, E.; Aloukos, P.; Couris, S.; Kaminska, E.; Piotrowska, A.; Dynowska, E.

    2007-07-01

    Au films of thickness ranging between 5 and 52 nm were prepared by sputtering on quartz substrates and their third-order nonlinear optical response was investigated by Optical Kerr effect (OKE) and Z-scan techniques using 532 nm, 35 ps laser pulses. All prepared films were characterized by XRD, AFM and UV-VIS-NIR spectrophotometry while their third-order susceptibility χ(3) was measured and found to be of the order of 10 -9 esu. The real and imaginary parts of the third-order susceptibility were found in very good agreement with experimental results and theoretical predictions reported by Smith et al. [D.D. Smith, Y. Yoon, R.W. Boyd, Y.K. Cambell, L.A. Baker, R.M. Crooks, M. George, J. Appl. Phys. 86 (1999) 6200].

  18. Impurity-related nonlinear optical properties in delta-doped quantum rings: Electric field effects

    Energy Technology Data Exchange (ETDEWEB)

    Restrepo, R.L., E-mail: rrestre@gmail.com [Escuela de Ingeniería de Antioquia-EIA, Medellín (Colombia); Grupo de Materia Condensada-UdeA, Instituto de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia); Morales, A.L. [Grupo de Materia Condensada-UdeA, Instituto de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia); Martínez-Orozco, J.C. [Unidad Académica de Física, Universidad Autónoma de Zacatecas, CP 98060, Zacatecas (Mexico); Baghramyan, H.M.; Barseghyan, M.G. [Department of Solid State Physics, Yerevan State University, Al. Manookian 1, 0025 Yerevan (Armenia); Mora-Ramos, M.E. [Grupo de Materia Condensada-UdeA, Instituto de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia); Facultad de Ciencias, Universidad Autónoma del Estado de Morelos, Ave. Universidad 1001, CP 62209, Cuernavaca, Morelos (Mexico); Duque, C.A. [Grupo de Materia Condensada-UdeA, Instituto de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia)

    2014-11-15

    Using a variational procedure within the effective mass approximation, we have calculated the donor impurity binding energy for the ground (1s-like) and the excited (2p{sub z}-like) states as well as the impurity-related nonlinear optical absorption and relative changes in the refraction index in a GaAs single quantum ring with axial n-type delta-doping. The delta-like potential along the z-direction is an approximate model analytically described using a Lorentzian function with two parameters. Additionally we consider the application of an electric field along the z-direction. It is found that the changes in the geometry of the quantum ring, the change in the 2D impurity density of the delta-like doping, and different values of the electric field lead to a shifting of the resonant peaks of the optical responses spectrum.

  19. Nanoparticles and nonlinear thermal radiation properties in the rheology of polymeric material

    Science.gov (United States)

    Awais, M.; Hayat, T.; Muqaddass, N.; Ali, A.; Aqsa; Awan, Saeed Ehsan

    2018-03-01

    The present analysis is related to the dynamics of polymeric liquids (Oldroyd-B model) with the presence of nanoparticles. The rheological system is considered under the application of nonlinear thermal radiations. Energy and concentration equations are presented when thermophoresis and Brownian motion effects are present. Bidirectional form of stretching is considered to interpret the three-dimensional flow dynamics of polymeric liquid. Making use of the similarity transformations, problem is reduced into ordinary differential system which is approximated by using HAM. Influence of physical parameters including Deborah number, thermophoresis and Brownian motion on velocity, temperature and mass fraction expressions are plotted and analyzed. Numerical values for local Sherwood and Nusselt numbers are presented and discussed.

  20. Properties of entangled photon pairs generated in one-dimensional nonlinear photonic-band-gap structures

    International Nuclear Information System (INIS)

    Perina, Jan Jr.; Centini, Marco; Sibilia, Concita; Bertolotti, Mario; Scalora, Michael

    2006-01-01

    We have developed a rigorous quantum model of spontaneous parametric down-conversion in a nonlinear 1D photonic-band-gap structure based upon expansion of the field into monochromatic plane waves. The model provides a two-photon amplitude of a created photon pair. The spectra of the signal and idler fields, their intensity profiles in the time domain, as well as the coincidence-count interference pattern in a Hong-Ou-Mandel interferometer are determined both for cw and pulsed pumping regimes in terms of the two-photon amplitude. A broad range of parameters characterizing the emitted down-converted fields can be used. As an example, a structure composed of 49 layers of GaN/AlN is analyzed as a suitable source of photon pairs having high efficiency