Broadband Nonlinear Signal Processing in Silicon Nanowires

DEFF Research Database (Denmark)

Yvind, Kresten; Pu, Minhao; Hvam, Jørn Märcher

The fast non-linearity of silicon allows Tbit/s optical signal processing. By choosing suitable dimensions of silicon nanowires their dispersion can be tailored to ensure a high nonlinearity at power levels low enough to avoid significant two-photon abso We have fabricated low insertion...

Ultrafast Nonlinear Signal Processing in Silicon Waveguides

DEFF Research Database (Denmark)

Oxenløwe, Leif Katsuo; Mulvad, Hans Christian Hansen; Hu, Hao

2012-01-01

We describe recent demonstrations of exploiting highly nonlinear silicon waveguides for ultrafast optical signal processing. We describe wavelength conversion and serial-to-parallel conversion of 640 Gbit/s data signals and 1.28 Tbit/s demultiplexing and all-optical sampling.......We describe recent demonstrations of exploiting highly nonlinear silicon waveguides for ultrafast optical signal processing. We describe wavelength conversion and serial-to-parallel conversion of 640 Gbit/s data signals and 1.28 Tbit/s demultiplexing and all-optical sampling....

Input saturation in nonlinear multivariable processes resolved by nonlinear decoupling

Directory of Open Access Journals (Sweden)

Jens G. Balchen

1995-04-01

Full Text Available A new method is presented for the resolution of the problem of input saturation in nonlinear multivariable process control by means of elementary nonlinear decoupling (END. Input saturation can have serious consequences particularly in multivariable control because it may lead to very undesirable system behaviour and quite often system instability. Many authors have searched for systematic techniques for designing multivariable control systems in which saturation may occur in any of the control variables (inputs, manipulated variables. No generally accepted method seems to have been presented so far which gives a solution in closed form. The method of elementary nonlinear decoupling (END can be applied directly to the case of saturation control variables by deriving as many control strategies as there are combinations of saturating control variables. The method is demonstrated by the multivariable control of a simulated Fluidized Catalytic Cracker (FCC with very convincing results.

Tuning the nonlinear optical absorption of reduced graphene oxide by chemical reduction.

Science.gov (United States)

Shi, Hongfei; Wang, Can; Sun, Zhipei; Zhou, Yueliang; Jin, Kuijuan; Redfern, Simon A T; Yang, Guozhen

2014-08-11

Reduced graphene oxides with varying degrees of reduction have been produced by hydrazine reduction of graphene oxide. The linear and nonlinear optical properties of both graphene oxide as well as the reduced graphene oxides have been measured by single beam Z-scan measurement in the picosecond region. The results reveal both saturable absorption and two-photon absorption, strongly dependent on the intensity of the pump pulse: saturable absorption occurs at lower pump pulse intensity (~1.5 GW/cm2 saturation intensity) whereas two-photon absorption dominates at higher intensities (≥5.7 GW/cm2). Intriguingly, we find that the two-photon absorption coefficient (from 1.5 cm/GW to 4.5cm/GW) and the saturation intensity (from 1 GW/cm2 to 2 GW/cm2) vary with chemical reduction, which is ascribed to the varying concentrations of sp2 domains and sp2 clusters in the reduced graphene oxides. Our results not only provide an insight into the evolution of the nonlinear optical coefficient in reduced graphene oxide, but also suggest that chemical engineering techniques may usefully be applied to tune the nonlinear optical properties of various nano-materials, including atomically thick graphene sheets.

Nonlinear partial least squares with Hellinger distance for nonlinear process monitoring

KAUST Repository

Harrou, Fouzi; Madakyaru, Muddu; Sun, Ying

2017-01-01

This paper proposes an efficient data-based anomaly detection method that can be used for monitoring nonlinear processes. The proposed method merges advantages of nonlinear projection to latent structures (NLPLS) modeling and those of Hellinger distance (HD) metric to identify abnormal changes in highly correlated multivariate data. Specifically, the HD is used to quantify the dissimilarity between current NLPLS-based residual and reference probability distributions. The performances of the developed anomaly detection using NLPLS-based HD technique is illustrated using simulated plug flow reactor data.

Nonlinear partial least squares with Hellinger distance for nonlinear process monitoring

KAUST Repository

Harrou, Fouzi

2017-02-16

This paper proposes an efficient data-based anomaly detection method that can be used for monitoring nonlinear processes. The proposed method merges advantages of nonlinear projection to latent structures (NLPLS) modeling and those of Hellinger distance (HD) metric to identify abnormal changes in highly correlated multivariate data. Specifically, the HD is used to quantify the dissimilarity between current NLPLS-based residual and reference probability distributions. The performances of the developed anomaly detection using NLPLS-based HD technique is illustrated using simulated plug flow reactor data.

Combined Noncyclic Scheduling and Advanced Control for Continuous Chemical Processes

Directory of Open Access Journals (Sweden)

Damon Petersen

2017-12-01

Full Text Available A novel formulation for combined scheduling and control of multi-product, continuous chemical processes is introduced in which nonlinear model predictive control (NMPC and noncyclic continuous-time scheduling are efficiently combined. A decomposition into nonlinear programming (NLP dynamic optimization problems and mixed-integer linear programming (MILP problems, without iterative alternation, allows for computationally light solution. An iterative method is introduced to determine the number of production slots for a noncyclic schedule during a prediction horizon. A filter method is introduced to reduce the number of MILP problems required. The formulation’s closed-loop performance with both process disturbances and updated market conditions is demonstrated through multiple scenarios on a benchmark continuously stirred tank reactor (CSTR application with fluctuations in market demand and price for multiple products. Economic performance surpasses cyclic scheduling in all scenarios presented. Computational performance is sufficiently light to enable online operation in a dual-loop feedback structure.

Fabrication of highly nonlinear germano-silicate glass optical fiber incorporated with PbTe semiconductor quantum dots using atomization doping process and its optical nonlinearity.

Science.gov (United States)

Ju, Seongmin; Watekar, Pramod R; Han, Won-Taek

2011-01-31

Germano-silicate glass optical fiber incorporated with PbTe semiconductor quantum dots (SQDs) in the core was fabricated by using the atomization process in modified chemical vapor deposition (MCVD) process. The absorption bands attributed to PbTe semiconductor quantum dots in the fiber core were found to appear at around 687 nm and 1055 nm. The nonlinear refractive index measured by the long-period fiber grating (LPG) pair method upon pumping with laser diode at 976.4 nm was estimated to be ~1.5 × 10(-16) m2/W.

Explosion of limit cycles and chaotic waves in a simple nonlinear chemical system

DEFF Research Database (Denmark)

Brøns, Morten; Sturis, Jeppe

2001-01-01

A model of an autocatalytic chemical reaction was employed to study the explosion of limit cycles and chaotic waves in a nonlinear chemical system. The bifurcation point was determined using asymptotic analysis and perturbations. Scaling laws for amplitude and period were derived. A strong sensit...... sensitivity was introduced due to bifurcation to infinity resulting in chaotic dynamics on adding diffusion....

Nonlinear Markov processes: Deterministic case

International Nuclear Information System (INIS)

Frank, T.D.

2008-01-01

Deterministic Markov processes that exhibit nonlinear transition mechanisms for probability densities are studied. In this context, the following issues are addressed: Markov property, conditional probability densities, propagation of probability densities, multistability in terms of multiple stationary distributions, stability analysis of stationary distributions, and basin of attraction of stationary distribution

Incorporation of chemical kinetic models into process control

International Nuclear Information System (INIS)

Herget, C.J.; Frazer, J.W.

1981-01-01

An important consideration in chemical process control is to determine the precise rationing of reactant streams, particularly when a large time delay exists between the mixing of the reactants and the measurement of the product. In this paper, a method is described for incorporating chemical kinetic models into the control strategy in order to achieve optimum operating conditions. The system is first characterized by determining a reaction rate surface as a function of all input reactant concentrations over a feasible range. A nonlinear constrained optimization program is then used to determine the combination of reactants which produces the specified yield at minimum cost. This operating condition is then used to establish the nominal concentrations of the reactants. The actual operation is determined through a feedback control system employing a Smith predictor. The method is demonstrated on a laboratory bench scale enzyme reactor

Optoelectronic and nonlinear optical processes in low dimensional ...

Indian Academy of Sciences (India)

Optoelectronic process; nonlinear optical process; semiconductor. Quest for ever faster and intelligent information processing technologies has sparked ..... Schematic energy level diagram for the proposed 4-level model. States other than the.

Identification of cow milk in goat milk by nonlinear chemical fingerprint technique.

Science.gov (United States)

Ma, Yong-Jie; Dong, Wen-Bin; Fan, Cheng; Wang, Er-Dan

2017-10-01

The objective of this paper was to develop a nonlinear chemical fingerprint technique for identifying and detecting adulteration of goat milk with cow milk. In this study, by taking the Belousov-Zhabotinsky oscillatory chemical reaction using acetone and substrates in goat milk or cow milk as main dissipative substances, when the same dosage of goat milk and cow milk was introduced to the "H +  + Mn 2+  + BrO 3 -  + acetone" oscillating system respectively, nonlinear chemical fingerprints were obtained for goat milk and cow milk from the same origin. The results showed that inductive time value and the content of cow milk in goat milk had a linear relationship in the range of 0-100% and the corresponding regression coefficient was 0.9991. A detection limit of 0.0107 g/g was obtained, and the content of cow milk in mixed milk was calculated. The proposed method in this study was simple, economical and effective. In addition, the method did not need the pretreatment and separation of samples for identifying and evaluating cow milk adulteration in goat milk. Copyright © 2017. Published by Elsevier B.V.

Image processing with a cellular nonlinear network

International Nuclear Information System (INIS)

Morfu, S.

2005-01-01

A cellular nonlinear network (CNN) based on uncoupled nonlinear oscillators is proposed for image processing purposes. It is shown theoretically and numerically that the contrast of an image loaded at the nodes of the CNN is strongly enhanced, even if this one is initially weak. An image inversion can be also obtained without reconfiguration of the network whereas a gray levels extraction can be performed with an additional threshold filtering. Lastly, an electronic implementation of this CNN is presented

Recent advances in nonlinear speech processing

CERN Document Server

Faundez-Zanuy, Marcos; Esposito, Antonietta; Cordasco, Gennaro; Drugman, Thomas; Solé-Casals, Jordi; Morabito, Francesco

2016-01-01

This book presents recent advances in nonlinear speech processing beyond nonlinear techniques. It shows that it exploits heuristic and psychological models of human interaction in order to succeed in the implementations of socially believable VUIs and applications for human health and psychological support. The book takes into account the multifunctional role of speech and what is “outside of the box” (see Björn Schuller’s foreword). To this aim, the book is organized in 6 sections, each collecting a small number of short chapters reporting advances “inside” and “outside” themes related to nonlinear speech research. The themes emphasize theoretical and practical issues for modelling socially believable speech interfaces, ranging from efforts to capture the nature of sound changes in linguistic contexts and the timing nature of speech; labors to identify and detect speech features that help in the diagnosis of psychological and neuronal disease, attempts to improve the effectiveness and performa...

A non-linear model of economic production processes

Science.gov (United States)

Ponzi, A.; Yasutomi, A.; Kaneko, K.

2003-06-01

We present a new two phase model of economic production processes which is a non-linear dynamical version of von Neumann's neoclassical model of production, including a market price-setting phase as well as a production phase. The rate of an economic production process is observed, for the first time, to depend on the minimum of its input supplies. This creates highly non-linear supply and demand dynamics. By numerical simulation, production networks are shown to become unstable when the ratio of different products to total processes increases. This provides some insight into observed stability of competitive capitalist economies in comparison to monopolistic economies. Capitalist economies are also shown to have low unemployment.

Hadron–Quark Combustion as a Nonlinear, Dynamical System

Science.gov (United States)

Ouyed, Amir; Ouyed, Rachid; Jaikumar, Prashanth

2018-03-01

The hadron-quark combustion front is a system that couples various processes, such as chemical reactions, hydrodynamics, diffusion, and neutrino transport. Previous numerical work has shown that this system is very nonlinear, and can be very sensitive to some of these processes. In these proceedings, we contextualize the hadron-quark combustion as a nonlinear system, subject to dramatic feedback triggered by leptonic weak decays and neutrino transport.

Discrete-time nonlinear sliding mode controller

African Journals Online (AJOL)

user

Keywords: Discrete-time delay system, Sliding mode control, nonlinear sliding ... of engineering systems such as chemical process control, delay in the actuator ...... instrumentation from Motilal Nehru National Institute of Technology (MNNIT),.

Ultra-Fast Optical Signal Processing in Nonlinear Silicon Waveguides

DEFF Research Database (Denmark)

Oxenløwe, Leif Katsuo; Galili, Michael; Pu, Minhao

2011-01-01

We describe recent demonstrations of exploiting highly nonlinear silicon nanowires for processing Tbit/s optical data signals. We perform demultiplexing and optical waveform sampling of 1.28 Tbit/s and wavelength conversion of 640 Gbit/s data signals.......We describe recent demonstrations of exploiting highly nonlinear silicon nanowires for processing Tbit/s optical data signals. We perform demultiplexing and optical waveform sampling of 1.28 Tbit/s and wavelength conversion of 640 Gbit/s data signals....

Quantum Information Processing using Nonlinear Optical Effects

DEFF Research Database (Denmark)

Andersen, Lasse Mejling

This PhD thesis treats applications of nonlinear optical effects for quantum information processing. The two main applications are four-wave mixing in the form of Bragg scattering (BS) for quantum-state-preserving frequency conversion, and sum-frequency generation (SFG) in second-order nonlinear......-chirping the pumps. In the high-conversion regime without the effects of NPM, exact Green functions for BS are derived. In this limit, separability is possible for conversion efficiencies up to 60 %. However, the system still allows for selective frequency conversion as well as re-shaping of the output. One way...

Hadron–Quark Combustion as a Nonlinear, Dynamical System

Directory of Open Access Journals (Sweden)

Amir Ouyed

2018-03-01

Full Text Available The hadron–quark combustion front is a system that couples various processes, such as chemical reactions, hydrodynamics, diffusion, and neutrino transport. Previous numerical work has shown that this system is very nonlinear, and can be very sensitive to some of these processes. In these proceedings, we contextualize the hadron–quark combustion as a nonlinear system, subject to dramatic feedback triggered by leptonic weak decays and neutrino transport.

A nonlinear isobologram model with Box-Cox transformation to both sides for chemical mixtures.

Science.gov (United States)

Chen, D G; Pounds, J G

1998-12-01

The linear logistical isobologram is a commonly used and powerful graphical and statistical tool for analyzing the combined effects of simple chemical mixtures. In this paper a nonlinear isobologram model is proposed to analyze the joint action of chemical mixtures for quantitative dose-response relationships. This nonlinear isobologram model incorporates two additional new parameters, Ymin and Ymax, to facilitate analysis of response data that are not constrained between 0 and 1, where parameters Ymin and Ymax represent the minimal and the maximal observed toxic response. This nonlinear isobologram model for binary mixtures can be expressed as [formula: see text] In addition, a Box-Cox transformation to both sides is introduced to improve the goodness of fit and to provide a more robust model for achieving homogeneity and normality of the residuals. Finally, a confidence band is proposed for selected isobols, e.g., the median effective dose, to facilitate graphical and statistical analysis of the isobologram. The versatility of this approach is demonstrated using published data describing the toxicity of the binary mixtures of citrinin and ochratoxin as well as a new experimental data from our laboratory for mixtures of mercury and cadmium.

Nonlinear Statistical Signal Processing: A Particle Filtering Approach

International Nuclear Information System (INIS)

Candy, J.

2007-01-01

A introduction to particle filtering is discussed starting with an overview of Bayesian inference from batch to sequential processors. Once the evolving Bayesian paradigm is established, simulation-based methods using sampling theory and Monte Carlo realizations are discussed. Here the usual limitations of nonlinear approximations and non-gaussian processes prevalent in classical nonlinear processing algorithms (e.g. Kalman filters) are no longer a restriction to perform Bayesian inference. It is shown how the underlying hidden or state variables are easily assimilated into this Bayesian construct. Importance sampling methods are then discussed and shown how they can be extended to sequential solutions implemented using Markovian state-space models as a natural evolution. With this in mind, the idea of a particle filter, which is a discrete representation of a probability distribution, is developed and shown how it can be implemented using sequential importance sampling/resampling methods. Finally, an application is briefly discussed comparing the performance of the particle filter designs with classical nonlinear filter implementations

Nonlinear process in the mode transition in typical strut-based and cavity-strut based scramjet combustors

Science.gov (United States)

Yan, Li; Liao, Lei; Huang, Wei; Li, Lang-quan

2018-04-01

The analysis of nonlinear characteristics and control of mode transition process is the crucial issue to enhance the stability and reliability of the dual-mode scramjet engine. In the current study, the mode transition processes in both strut-based combustor and cavity-strut based combustor are numerically studied, and the influence of the cavity on the transition process is analyzed in detail. The simulations are conducted by means of the Reynolds averaged Navier-Stokes (RANS) equations coupled with the renormalization group (RNG) k-ε turbulence model and the single-step chemical reaction mechanism, and this numerical approach is proved to be valid by comparing the predicted results with the available experimental shadowgraphs in the open literature. During the mode transition process, an obvious nonlinear property is observed, namely the unevenly variations of pressure along the combustor. The hysteresis phenomenon is more obvious upstream of the flow field. For the cavity-strut configuration, the whole flow field is more inclined to the supersonic state during the transition process, and it is uneasy to convert to the ramjet mode. In the scram-to-ram transition process, the process would be more stable, and the hysteresis effect would be reduced in the ram-to-scram transition process.

Chemical process hazards analysis

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-02-01

The Office of Worker Health and Safety (EH-5) under the Assistant Secretary for the Environment, Safety and Health of the US Department (DOE) has published two handbooks for use by DOE contractors managing facilities and processes covered by the Occupational Safety and Health Administration (OSHA) Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119), herein referred to as the PSM Rule. The PSM Rule contains an integrated set of chemical process safety management elements designed to prevent chemical releases that can lead to catastrophic fires, explosions, or toxic exposures. The purpose of the two handbooks, ``Process Safety Management for Highly Hazardous Chemicals`` and ``Chemical Process Hazards Analysis,`` is to facilitate implementation of the provisions of the PSM Rule within the DOE. The purpose of this handbook ``Chemical Process Hazards Analysis,`` is to facilitate, within the DOE, the performance of chemical process hazards analyses (PrHAs) as required under the PSM Rule. It provides basic information for the performance of PrHAs, and should not be considered a complete resource on PrHA methods. Likewise, to determine if a facility is covered by the PSM rule, the reader should refer to the handbook, ``Process Safety Management for Highly Hazardous Chemicals`` (DOE- HDBK-1101-96). Promulgation of the PSM Rule has heightened the awareness of chemical safety management issues within the DOE. This handbook is intended for use by DOE facilities and processes covered by the PSM rule to facilitate contractor implementation of the PrHA element of the PSM Rule. However, contractors whose facilities and processes not covered by the PSM Rule may also use this handbook as a basis for conducting process hazards analyses as part of their good management practices. This handbook explains the minimum requirements for PrHAs outlined in the PSM Rule. Nowhere have requirements been added beyond what is specifically required by the rule.

Nonlinear wave-mixing processes in the extreme ultraviolet

International Nuclear Information System (INIS)

Misoguti, L.; Christov, I. P.; Backus, S.; Murnane, M. M.; Kapteyn, H. C.

2005-01-01

We present data from two-color high-order harmonic generation in a hollow waveguide, that suggest the presence of a nonlinear-optical frequency conversion process driven by extreme ultraviolet light. By combining the fundamental and second harmonic of an 800 nm laser in a hollow-core fiber, with varying relative polarizations, and by observing the pressure and power scaling of the various harmonic orders, we show that the data are consistent with a picture where we drive the process of high-harmonic generation, which in turn drives four-wave frequency mixing processes in the extreme EUV. This work promises a method for extending nonlinear optics into the extreme ultraviolet region of the spectrum using an approach that has not previously been considered, and has compelling implications for generating tunable light at short wavelengths

Preface "Nonlinear processes in oceanic and atmospheric flows"

Directory of Open Access Journals (Sweden)

E. García-Ladona

2010-05-01

Full Text Available Nonlinear phenomena are essential ingredients in many oceanic and atmospheric processes, and successful understanding of them benefits from multidisciplinary collaboration between oceanographers, meteorologists, physicists and mathematicians. The present Special Issue on "Nonlinear Processes in Oceanic and Atmospheric Flows" contains selected contributions from attendants to the workshop which, in the above spirit, was held in Castro Urdiales, Spain, in July 2008. Here we summarize the Special Issue contributions, which include papers on the characterization of ocean transport in the Lagrangian and in the Eulerian frameworks, generation and variability of jets and waves, interactions of fluid flow with plankton dynamics or heavy drops, scaling in meteorological fields, and statistical properties of El Niño Southern Oscillation.

Ultrasound in chemical processes

International Nuclear Information System (INIS)

Baig, S.; Farooq, R.; Malik, A.H.

2009-01-01

The use of ultrasound to promote chemical reactions or sono chemistry is a field of chemistry which involves the process of acoustic cavitations i.e. the collapse of microscopic bubbles in liquid. There are two essential components for the application of sono chemistry, a liquid medium and a source of high-energy vibrations. The liquid medium is necessary because sono chemistry is driven by acoustic cavitations that can only occur in liquids. The source of the vibrational energy is the transducer. The chemical effects of ultrasound include the enhancement of reaction rates at ambient temperatures and striking advancements in stoichiometric and catalytic reactions In some cases, ultrasonic irradiation can increase reactivities by nearly million fold. The ultrasound has large number of applications not only in emending old chemical processes but also in developing new synthetic strategies. Ultrasound enhances all chemical and physical processes e.g., crystallization, vitamin synthesis, preparation of catalysts, dissolution of chemicals, organometallic reactions, electrochemical processes, etc. High-power ultrasonics is a new powerful technology that is not only safe and environmentally friendly in its application but is also efficient and economical. It can be applied to existing processes to eliminate the need for chemicals and/or heat application in a variety of industrial processes. (author)

Nonlinear processes of magnons in insulating ferromagnetic materials

International Nuclear Information System (INIS)

Araujo, C.B. de.

1975-04-01

The representation of coherent states is used to investigate the excitation of magnons by 'parallel pumping', 'perpendicular pumping' and 'phonon pumping'. The stationary regime of the processes is studied with respect to the magnon population and the statistic behavior of the system below and just above the threshold. Particular attention is given to the thermodynamic and the coherence properties of the parametric states. The results show that just above the threshold the generated states become coherent. Also, it is shown that the non-linear processes have characteristics of a second-order phase transition with the pumping power as the 'reservoir variable' and the transverse dynamical magnetization as the 'order parameter'. Finally, the possibilities to extend the theory, its experimental check, and its convenience to study the other nonlinear processes of magnons and phonons in magnetic insulators are discussed. (author) [pt

Cascading second-order nonlinear processes in a lithium niobate-on-insulator microdisk.

Science.gov (United States)

Liu, Shijie; Zheng, Yuanlin; Chen, Xianfeng

2017-09-15

Whispering-gallery-mode (WGM) microcavities are very important in both fundamental science and practical applications, among which on-chip second-order nonlinear microresonators play an important role in integrated photonic functionalities. Here we demonstrate resonant second-harmonic generation (SHG) and cascaded third-harmonic generation (THG) in a lithium niobate-on-insulator (LNOI) microdisk resonator. Efficient SHG in the visible range was obtained with only several mW input powers at telecom wavelengths. THG was also observed through a cascading process, which reveals simultaneous phase matching and strong mode coupling in the resonator. Cascading of second-order nonlinear processes gives rise to an effectively large third-order nonlinearity, which makes on-chip second-order nonlinear microresonators a promising frequency converter for integrated nonlinear photonics.

Chemical reaction for Carreau-Yasuda nanofluid flow past a nonlinear stretching sheet considering Joule heating

Science.gov (United States)

Khan, Mair; Shahid, Amna; Malik, M. Y.; Salahuddin, T.

2018-03-01

Current analysis has been made to scrutinize the consequences of chemical response against magneto-hydrodynamic Carreau-Yasuda nanofluid flow induced by a non-linear stretching surface considering zero normal flux, slip and convective boundary conditions. Joule heating effect is also considered. Appropriate similarity approach is used to convert leading system of PDE's for Carreau-Yasuda nanofluid into nonlinear ODE's. Well known mathematical scheme namely shooting method is utilized to solve the system numerically. Physical parameters, namely Weissenberg number We , thermal slip parameter δ , thermophoresis number NT, non-linear stretching parameter n, magnetic field parameter M, velocity slip parameter k , Lewis number Le, Brownian motion parameter NB, Prandtl number Pr, Eckert number Ec and chemical reaction parameter γ upon temperature, velocity and concentration profiles are visualized through graphs and tables. Numerical influence of mass and heat transfer rates and friction factor are also represented in tabular as well as graphical form respectively. Skin friction coefficient reduces when Weissenberg number We is incremented. Rate of heat transfer enhances for large values of Brownian motion constraint NB. By increasing Lewis quantity Le rate of mass transfer declines.

Internal Decoupling in Nonlinear Process Control

Directory of Open Access Journals (Sweden)

Jens G. Balchen

1988-07-01

Full Text Available A simple method has been investigated for the total or partial removal of the effect of non-linear process phenomena in multi-variable feedback control systems. The method is based upon computing the control variables which will drive the process at desired rates. It is shown that the effect of model errors in the linearization of the process can be partly removed through the use of large feedback gains. In practice there will be limits on how large gains can he used. The sensitivity to parameter errors is less pronounced and the transient behaviour is superior to that of ordinary PI controllers.

Nonlinear stochastic dynamics of mesoscopic homogeneous biochemical reaction systems—an analytical theory

International Nuclear Information System (INIS)

Qian, Hong

2011-01-01

The nonlinear dynamics of biochemical reactions in a small-sized system on the order of a cell are stochastic. Assuming spatial homogeneity, the populations of n molecular species follow a multi-dimensional birth-and-death process on Z n . We introduce the Delbrück–Gillespie process, a continuous-time Markov jump process, whose Kolmogorov forward equation has been known as the chemical master equation, and whose stochastic trajectories can be computed via the Gillespie algorithm. Using simple models, we illustrate that a system of nonlinear ordinary differential equations on R n emerges in the infinite system size limit. For finite system size, transitions among multiple attractors of the nonlinear dynamical system are rare events with exponentially long transit times. There is a separation of time scales between the deterministic ODEs and the stochastic Markov jumps between attractors. No diffusion process can provide a global representation that is accurate on both short and long time scales for the nonlinear, stochastic population dynamics. On the short time scale and near deterministic stable fixed points, Ornstein–Uhlenbeck Gaussian processes give linear stochastic dynamics that exhibit time-irreversible circular motion for open, driven chemical systems. Extending this individual stochastic behaviour-based nonlinear population theory of molecular species to other biological systems is discussed. (invited article)

Modeling Autoregressive Processes with Moving-Quantiles-Implied Nonlinearity

Directory of Open Access Journals (Sweden)

Isao Ishida

2015-01-01

Full Text Available We introduce and investigate some properties of a class of nonlinear time series models based on the moving sample quantiles in the autoregressive data generating process. We derive a test fit to detect this type of nonlinearity. Using the daily realized volatility data of Standard & Poor’s 500 (S&P 500 and several other indices, we obtained good performance using these models in an out-of-sample forecasting exercise compared with the forecasts obtained based on the usual linear heterogeneous autoregressive and other models of realized volatility.

Process/Equipment Co-Simulation on Syngas Chemical Looping Process

Energy Technology Data Exchange (ETDEWEB)

Zeng, Liang; Zhou, Qiang; Fan, Liang-Shih

2012-09-30

The chemical looping strategy for fossil energy applications promises to achieve an efficient energy conversion system for electricity, liquid fuels, hydrogen and/or chemicals generation, while economically separate CO{sub 2} by looping reaction design in the process. Chemical looping particle performance, looping reactor engineering, and process design and applications are the key drivers to the success of chemical looping process development. In order to better understand and further scale up the chemical looping process, issues such as cost, time, measurement, safety, and other uncertainties need to be examined. To address these uncertainties, advanced reaction/reactor modeling and process simulation are highly desired and the modeling efforts can accelerate the chemical looping technology development, reduce the pilot-scale facility design time and operating campaigns, as well as reduce the cost and technical risks. The purpose of this work is thus to conduct multiscale modeling and simulations on the key aspects of chemical looping technology, including particle reaction kinetics, reactor design and operation, and process synthesis and optimization.

Non-equilibrium condensation process in holographic superconductor with nonlinear electrodynamics

Energy Technology Data Exchange (ETDEWEB)

Liu, Yunqi; Gong, Yungui [School of Physics, Huazhong University of Science and Technology,Wuhan, Hubei 430074 (China); Wang, Bin [IFSA Collaborative Innovation Center, Department of Physics and Astronomy, Shanghai Jiao Tong University,Shanghai 200240 (China)

2016-02-17

We study the non-equilibrium condensation process in a holographic superconductor with nonlinear corrections to the U(1) gauge field. We start with an asymptotic Anti-de-Sitter(AdS) black hole against a complex scalar perturbation at the initial time, and solve the dynamics of the gravitational systems in the bulk. When the black hole temperature T is smaller than a critical value T{sub c}, the scalar perturbation grows exponentially till saturation, the final state of spacetime approaches to a hairy black hole. In the bulk theory, we find the clue of the influence of nonlinear corrections in the gauge filed on the process of the scalar field condensation. We show that the bulk dynamics in the non-equilibrium process is completely consistent with the observations on the boundary order parameter. Furthermore we examine the time evolution of horizons in the bulk non-equilibrium transformation process from the bald AdS black hole to the AdS hairy hole. Both the evolution of apparent and event horizons show that the original AdS black hole configuration requires more time to finish the transformation to become a hairy black hole if there is nonlinear correction to the electromagnetic field. We generalize our non-equilibrium discussions to the holographic entanglement entropy and find that the holographic entanglement entropy can give us further understanding of the influence of the nonlinearity in the gauge field on the scalar condensation.

Photonic single nonlinear-delay dynamical node for information processing

Science.gov (United States)

Ortín, Silvia; San-Martín, Daniel; Pesquera, Luis; Gutiérrez, José Manuel

2012-06-01

An electro-optical system with a delay loop based on semiconductor lasers is investigated for information processing by performing numerical simulations. This system can replace a complex network of many nonlinear elements for the implementation of Reservoir Computing. We show that a single nonlinear-delay dynamical system has the basic properties to perform as reservoir: short-term memory and separation property. The computing performance of this system is evaluated for two prediction tasks: Lorenz chaotic time series and nonlinear auto-regressive moving average (NARMA) model. We sweep the parameters of the system to find the best performance. The results achieved for the Lorenz and the NARMA-10 tasks are comparable to those obtained by other machine learning methods.

Nonlinear Analysis of Two-phase Circumferential Motion in the Ablation Circumstance

Science.gov (United States)

Xiao-liang, Xu; Hai-ming, Huang; Zi-mao, Zhang

2010-05-01

In aerospace craft reentry and solid rocket propellant nozzle, thermal chemistry ablation is a complex process coupling with convection, heat transfer, mass transfer and chemical reaction. Based on discrete vortex method (DVM), thermal chemical ablation model and particle kinetic model, a computational module dealing with the two-phase circumferential motion in ablation circumstance is designed, the ablation velocity and circumferential field can be thus calculated. The calculated nonlinear time series are analyzed in chaotic identification method: relative chaotic characters such as correlation dimension and the maximum Lyapunov exponent are calculated, fractal dimension of vortex bulbs and particles distributions are also obtained, thus the nonlinear ablation process can be judged as a spatiotemporal chaotic process.

Economic Benefit from Progressive Integration of Scheduling and Control for Continuous Chemical Processes

Directory of Open Access Journals (Sweden)

Logan D. R. Beal

2017-12-01

Full Text Available Performance of integrated production scheduling and advanced process control with disturbances is summarized and reviewed with four progressive stages of scheduling and control integration and responsiveness to disturbances: open-loop segregated scheduling and control, closed-loop segregated scheduling and control, open-loop scheduling with consideration of process dynamics, and closed-loop integrated scheduling and control responsive to process disturbances and market fluctuations. Progressive economic benefit from dynamic rescheduling and integrating scheduling and control is shown on a continuously stirred tank reactor (CSTR benchmark application in closed-loop simulations over 24 h. A fixed horizon integrated scheduling and control formulation for multi-product, continuous chemical processes is utilized, in which nonlinear model predictive control (NMPC and continuous-time scheduling are combined.

Photonic Crystal Nanocavity Devices for Nonlinear Signal Processing

DEFF Research Database (Denmark)

Yu, Yi

, membranization of InP/InGaAs structure and wet etching. Experimental investigation of the switching dynamics of InP photonic crystal nanocavity structures are carried out using short-pulse homodyne pump-probe techniques, both in the linear and nonlinear region where the cavity is perturbed by a relatively small......This thesis deals with the investigation of InP material based photonic crystal cavity membrane structures, both experimentally and theoretically. The work emphasizes on the understanding of the physics underlying the structures’ nonlinear properties and their applications for all-optical signal...... processing. Based on the previous fabrication recipe developed in our III-V platform, several processing techniques are developed and optimized for the fabrication of InP photonic crystal membrane structures. Several key issues are identified to ensure a good device quality such as air hole size control...

Modeling and optimization of CO2 capture processes by chemical absorption

International Nuclear Information System (INIS)

Neveux, Thibaut

2013-01-01

CO 2 capture processes by chemical absorption lead to a large energy penalty on efficiency of coal-fired power plants, establishing one of the main bottleneck to its industrial deployment. The objective of this thesis is the development and validation of a global methodology, allowing the precise evaluation of the potential of a given amine capture process. Characteristic phenomena of chemical absorption have been thoroughly studied and represented with state-of-the-art models. The e-UNIQUAC model has been used to describe vapor-liquid and chemical equilibria of electrolyte solutions and the model parameters have been identified for four solvents. A rate-based formulation has been adopted for the representation of chemically enhanced heat and mass transfer in columns. The absorption and stripping models have been successfully validated against experimental data from an industrial and a laboratory pilot plants. The influence of the numerous phenomena has been investigated in order to highlight the most limiting ones. A methodology has been proposed to evaluate the total energy penalty resulting from the implementation of a capture process on an advanced supercritical coal-fired power plant, including thermal and electric consumptions. Then, the simulation and process evaluation environments have been coupled with a non-linear optimization algorithm in order to find optimal operating and design parameters with respect to energetic and economic performances. This methodology has been applied to optimize five process flow schemes operating with an monoethanolamine aqueous solution at 30% by weight: the conventional flow scheme and four process modifications. The performance comparison showed that process modifications using a heat pump effect give the best gains. The use of technical-economic analysis as an evaluation criterion of a process performance, coupled with a optimization algorithm, has proved its capability to find values for the numerous operating and design

Instantaneous nonlinear assessment of complex cardiovascular dynamics by Laguerre-Volterra point process models.

Science.gov (United States)

Valenza, Gaetano; Citi, Luca; Barbieri, Riccardo

2013-01-01

We report an exemplary study of instantaneous assessment of cardiovascular dynamics performed using point-process nonlinear models based on Laguerre expansion of the linear and nonlinear Wiener-Volterra kernels. As quantifiers, instantaneous measures such as high order spectral features and Lyapunov exponents can be estimated from a quadratic and cubic autoregressive formulation of the model first order moment, respectively. Here, these measures are evaluated on heartbeat series coming from 16 healthy subjects and 14 patients with Congestive Hearth Failure (CHF). Data were gathered from the on-line repository PhysioBank, which has been taken as landmark for testing nonlinear indices. Results show that the proposed nonlinear Laguerre-Volterra point-process methods are able to track the nonlinear and complex cardiovascular dynamics, distinguishing significantly between CHF and healthy heartbeat series.

Using Simulation to Increase Yields in Chemical Engineering

Directory of Open Access Journals (Sweden)

William C. Conley

2003-06-01

Full Text Available Trying to increase the yields or profit or efficiency (less pollution of chemical processes is a central goal of the chemical engineer in theory and practice. Certainly sound training in chemistry, business and pollution control help the engineer to set up optimal chemical processes. However, the ever changing demands of customers and business conditions, plus the multivariate complexity of the chemical business can make optimization challenging. Mathematical tools such as statistics and linear programming have certainly been useful to chemical engineers in their pursuit of optimal efficiency. However, some processes can be modeled linearly and some can not. Therefore, presented here will be an industrial chemical process with potentially five variables affecting the yield. Data from over one hundred runs of the process has been collected, but it is not known initially whether the yield relationship is linear or nonlinear. Therefore, the CTSP multivariate correlation coefficient will be calculated for the data to see if a relationship exists among the variables. Then once it is proven that there is a statistically significant relationship, an appropriate linear or nonlinear equation can be fitted to the data, and it can be optimized for use in the chemical plant.

Noise removal in extended depth of field microscope images through nonlinear signal processing.

Science.gov (United States)

Zahreddine, Ramzi N; Cormack, Robert H; Cogswell, Carol J

2013-04-01

Extended depth of field (EDF) microscopy, achieved through computational optics, allows for real-time 3D imaging of live cell dynamics. EDF is achieved through a combination of point spread function engineering and digital image processing. A linear Wiener filter has been conventionally used to deconvolve the image, but it suffers from high frequency noise amplification and processing artifacts. A nonlinear processing scheme is proposed which extends the depth of field while minimizing background noise. The nonlinear filter is generated via a training algorithm and an iterative optimizer. Biological microscope images processed with the nonlinear filter show a significant improvement in image quality and signal-to-noise ratio over the conventional linear filter.

Corrugated Membrane Nonlinear Deformation Process Calculation

Directory of Open Access Journals (Sweden)

A. S. Nikolaeva

2015-01-01

Full Text Available Elastic elements are widely used in instrumentation. They are used to create a particular interference between the parts, for accumulating mechanical energy, as the motion transmission elements, elastic supports, and sensing elements of measuring devices. Device reliability and quality depend on the calculation accuracy of the elastic elements. A corrugated membrane is rather common embodiment of the elastic element.The corrugated membrane properties depend largely on its profile i.e. a generatrix of the meridian surface.Unlike other types of pressure elastic members (bellows, tube spring, the elastic characteristics of which are close to linear, an elastic characteristic of the corrugated membrane (typical movement versus external load is nonlinear. Therefore, the corrugated membranes can be used to measure quantities, nonlinearly related to the pressure (e.g., aircraft air speed, its altitude, pipeline fluid or gas flow rate. Another feature of the corrugated membrane is that significant movements are possible within the elastic material state. However, a significant non-linearity of membrane characteristics leads to severe complicated calculation.This article is aimed at calculating the corrugated membrane to obtain the elastic characteristics and the deformed shape of the membrane meridian, as well as at investigating the processes of buckling. As the calculation model, a thin-walled axisymmetric shell rotation is assumed. The material properties are linearly elastic. We consider a corrugated membrane of sinusoidal profile. The membrane load is a uniform pressure.The algorithm for calculating the mathematical model of an axisymmetric corrugated membrane of constant thickness, based on the Reissner’s theory of elastic thin shells, was realized as the author's program in C language. To solve the nonlinear problem were used a method of changing the subspace of control parameters, developed by S.S., Gavriushin, and a parameter marching method

Heterogeneous recurrence monitoring and control of nonlinear stochastic processes

Energy Technology Data Exchange (ETDEWEB)

Yang, Hui, E-mail: huiyang@usf.edu; Chen, Yun [Complex Systems Monitoring, Modeling and Analysis Laboratory, University of South Florida, Tampa, Florida 33620 (United States)

2014-03-15

Recurrence is one of the most common phenomena in natural and engineering systems. Process monitoring of dynamic transitions in nonlinear and nonstationary systems is more concerned with aperiodic recurrences and recurrence variations. However, little has been done to investigate the heterogeneous recurrence variations and link with the objectives of process monitoring and anomaly detection. Notably, nonlinear recurrence methodologies are based on homogeneous recurrences, which treat all recurrence states in the same way as black dots, and non-recurrence is white in recurrence plots. Heterogeneous recurrences are more concerned about the variations of recurrence states in terms of state properties (e.g., values and relative locations) and the evolving dynamics (e.g., sequential state transitions). This paper presents a novel approach of heterogeneous recurrence analysis that utilizes a new fractal representation to delineate heterogeneous recurrence states in multiple scales, including the recurrences of both single states and multi-state sequences. Further, we developed a new set of heterogeneous recurrence quantifiers that are extracted from fractal representation in the transformed space. To that end, we integrated multivariate statistical control charts with heterogeneous recurrence analysis to simultaneously monitor two or more related quantifiers. Experimental results on nonlinear stochastic processes show that the proposed approach not only captures heterogeneous recurrence patterns in the fractal representation but also effectively monitors the changes in the dynamics of a complex system.

Investigation on the effect of nonlinear processes on similarity law in high-pressure argon discharges

Science.gov (United States)

Fu, Yangyang; Parsey, Guy M.; Verboncoeur, John P.; Christlieb, Andrew J.

2017-11-01

In this paper, the effect of nonlinear processes (such as three-body collisions and stepwise ionizations) on the similarity law in high-pressure argon discharges has been studied by the use of the Kinetic Global Model framework. In the discharge model, the ground state argon atoms (Ar), electrons (e), atom ions (Ar+), molecular ions (Ar2+), and fourteen argon excited levels Ar*(4s and 4p) are considered. The steady-state electron and ion densities are obtained with nonlinear processes included and excluded in the designed models, respectively. It is found that in similar gas gaps, keeping the product of gas pressure and linear dimension unchanged, with the nonlinear processes included, the normalized density relations deviate from the similarity relations gradually as the scale-up factor decreases. Without the nonlinear processes, the parameter relations are in good agreement with the similarity law predictions. Furthermore, the pressure and the dimension effects are also investigated separately with and without the nonlinear processes. It is shown that the gas pressure effect on the results is less obvious than the dimension effect. Without the nonlinear processes, the pressure and the dimension effects could be estimated from one to the other based on the similarity relations.

Effects of noise, nonlinear processing, and linear filtering on perceived music quality.

Science.gov (United States)

Arehart, Kathryn H; Kates, James M; Anderson, Melinda C

2011-03-01

The purpose of this study was to determine the relative impact of different forms of hearing aid signal processing on quality ratings of music. Music quality was assessed using a rating scale for three types of music: orchestral classical music, jazz instrumental, and a female vocalist. The music stimuli were subjected to a wide range of simulated hearing aid processing conditions including, (1) noise and nonlinear processing, (2) linear filtering, and (3) combinations of noise, nonlinear, and linear filtering. Quality ratings were measured in a group of 19 listeners with normal hearing and a group of 15 listeners with sensorineural hearing impairment. Quality ratings in both groups were generally comparable, were reliable across test sessions, were impacted more by noise and nonlinear signal processing than by linear filtering, and were significantly affected by the genre of music. The average quality ratings for music were reasonably well predicted by the hearing aid speech quality index (HASQI), but additional work is needed to optimize the index to the wide range of music genres and processing conditions included in this study.

Reactive chemicals and process hazards

International Nuclear Information System (INIS)

Surianarayanan, M.

2016-01-01

Exothermic chemical reactions are often accompanied by significant heat release, and therefore, need a thorough investigation before they are taken to a plant scale. Sudden thermal energy releases from exothermic decompositions and runaway reactions have contributed to serious fire and explosions in several chemical process plants. Similarly, thermal runaway had also occurred in storage and transportation of reactive chemicals. The secondary events of thermal runaway reactions can be rupture of process vessel, toxic spills and release of explosive vapor clouds or combination of these also. The explosion hazards are governed by the system thermodynamics and kinetics of the thermal process. Theoretical prediction of limiting temperature is difficult due to process complexities. Further, the kinetic data obtained through classical techniques, at conditions far away from runaway situation, is often not valid for assessing the runaway behavior of exothermic processes. The main focus of this lecture is to discuss the causes and several contributing factors for thermal runaway and instability and present analyses of the methodologies of the new instrumental techniques for assessing the thermal hazards of reactive chemicals during processing, storage and transportation. (author)

Plasma-chemical processes and systems

International Nuclear Information System (INIS)

Castro B, J.

1987-01-01

The direct applications of plasma technology on chemistry and metallurgy are presented. The physical fundaments of chemically active non-equilibrium plasma, the reaction kinetics, and the physical chemical transformations occuring in the electrical discharges, which are applied in the industry, are analysed. Some plasma chemical systems and processes related to the energy of hydrogen, with the chemical technology and with the metallurgy are described. Emphasis is given to the optimization of the energy effectiveness of these processes to obtain reducers and artificial energetic carriers. (M.C.K.) [pt

A fuzzy model based adaptive PID controller design for nonlinear and uncertain processes.

Science.gov (United States)

Savran, Aydogan; Kahraman, Gokalp

2014-03-01

We develop a novel adaptive tuning method for classical proportional-integral-derivative (PID) controller to control nonlinear processes to adjust PID gains, a problem which is very difficult to overcome in the classical PID controllers. By incorporating classical PID control, which is well-known in industry, to the control of nonlinear processes, we introduce a method which can readily be used by the industry. In this method, controller design does not require a first principal model of the process which is usually very difficult to obtain. Instead, it depends on a fuzzy process model which is constructed from the measured input-output data of the process. A soft limiter is used to impose industrial limits on the control input. The performance of the system is successfully tested on the bioreactor, a highly nonlinear process involving instabilities. Several tests showed the method's success in tracking, robustness to noise, and adaptation properties. We as well compared our system's performance to those of a plant with altered parameters with measurement noise, and obtained less ringing and better tracking. To conclude, we present a novel adaptive control method that is built upon the well-known PID architecture that successfully controls highly nonlinear industrial processes, even under conditions such as strong parameter variations, noise, and instabilities. © 2013 Published by ISA on behalf of ISA.

Entropy and convexity for nonlinear partial differential equations.

Science.gov (United States)

Ball, John M; Chen, Gui-Qiang G

2013-12-28

Partial differential equations are ubiquitous in almost all applications of mathematics, where they provide a natural mathematical description of many phenomena involving change in physical, chemical, biological and social processes. The concept of entropy originated in thermodynamics and statistical physics during the nineteenth century to describe the heat exchanges that occur in the thermal processes in a thermodynamic system, while the original notion of convexity is for sets and functions in mathematics. Since then, entropy and convexity have become two of the most important concepts in mathematics. In particular, nonlinear methods via entropy and convexity have been playing an increasingly important role in the analysis of nonlinear partial differential equations in recent decades. This opening article of the Theme Issue is intended to provide an introduction to entropy, convexity and related nonlinear methods for the analysis of nonlinear partial differential equations. We also provide a brief discussion about the content and contributions of the papers that make up this Theme Issue.

Modular Chemical Process Intensification: A Review.

Science.gov (United States)

Kim, Yong-Ha; Park, Lydia K; Yiacoumi, Sotira; Tsouris, Costas

2017-06-07

Modular chemical process intensification can dramatically improve energy and process efficiencies of chemical processes through enhanced mass and heat transfer, application of external force fields, enhanced driving forces, and combinations of different unit operations, such as reaction and separation, in single-process equipment. These dramatic improvements lead to several benefits such as compactness or small footprint, energy and cost savings, enhanced safety, less waste production, and higher product quality. Because of these benefits, process intensification can play a major role in industrial and manufacturing sectors, including chemical, pulp and paper, energy, critical materials, and water treatment, among others. This article provides an overview of process intensification, including definitions, principles, tools, and possible applications, with the objective to contribute to the future development and potential applications of modular chemical process intensification in industrial and manufacturing sectors. Drivers and barriers contributing to the advancement of process intensification technologies are discussed.

Simultaneous spatial and temporal focusing: a route towards confined nonlinear materials processing

Science.gov (United States)

Kammel, Robert; Bergner, Klaus; Thomas, Jens; Ackermann, Roland; Skupin, Stefan; Nolte, Stefan

2016-03-01

Ultrashort pulse lasers enable reliable and versatile high precision ablation and surface processing of various materials such as metals, polymers and semiconductors. However, when modifications deep inside the bulk of transparent media are required, nonlinear pulse material interactions can decrease the precision, since weak focusing and the long propagation of the intense pulses within the nonlinear media may induce Kerr self-focusing, filamentation and white light generation. In order to improve the precision of those modifications, simultaneous spatial and temporal focusing (SSTF) allows to reduce detrimental nonlinear interactions, because the ultrashort pulse duration is only obtained at the focus, while outside of the focal region the continuously increasing pulse duration strongly reduces the pulse intensity. In this paper, we review the fundamental concepts of this technology and provide an overview of its applications for purposes of multiphoton microscopy and laser materials processing. Moreover, numerical simulations on the nonlinear pulse propagation within transparent media illustrate the linear and nonlinear pulse propagation, highlighting the differences between conventional focusing and SSTF. Finally, fs-laser induced modifications in gelatine are presented to compare nonlinear side-effects caused by conventional focusing and SSTF. With conventional focusing the complex interplay of self-focusing and filamentation induces strongly inhomogeneous, elongated disruptions. In contrast, disruptions induced by SSTF are homogeneously located at the focal plane and reduced in length by a factor >2, which is in excellent agreement with the numerical simulations of the nonlinear pulse propagation and might favor SSTF for demanding applications such as intraocular fs-laser surgery.

Nonlinear identification of process dynamics using neural networks

International Nuclear Information System (INIS)

Parlos, A.G.; Atiya, A.F.; Chong, K.T.

1992-01-01

In this paper the nonlinear identification of process dynamics encountered in nuclear power plant components is addressed, in an input-output sense, using artificial neural systems. A hybrid feedforward/feedback neural network, namely, a recurrent multilayer perceptron, is used as the model structure to be identified. The feedforward portion of the network architecture provides its well-known interpolation property, while through recurrency and cross-talk, the local information feedback enables representation of temporal variations in the system nonlinearities. The standard backpropagation learning algorithm is modified, and it is used for the supervised training of the proposed hybrid network. The performance of recurrent multilayer perceptron networks in identifying process dynamics is investigated via the case study of a U-tube steam generator. The response of representative steam generator is predicted using a neural network, and it is compared to the response obtained from a sophisticated computer model based on first principles. The transient responses compare well, although further research is warranted to determine the predictive capabilities of these networks during more severe operational transients and accident scenarios

Noise-Induced Modulation of the Relaxation Kinetics around a Non-Equilibrium Steady State of Non-Linear Chemical Reaction Networks

OpenAIRE

Ramaswamy, Rajesh; Sbalzarini, Ivo F; González-Segredo, Nélido

2011-01-01

Stochastic effects from correlated noise non-trivially modulate the kinetics of non-linear chemical reaction networks. This is especially important in systems where reactions are confined to small volumes and reactants are delivered in bursts. We characterise how the two noise sources confinement and burst modulate the relaxation kinetics of a non-linear reaction network around a non-equilibrium steady state. We find that the lifetimes of species change with burst input and confinement. Confi...

Fault Detection for Nonlinear Process With Deterministic Disturbances: A Just-In-Time Learning Based Data Driven Method.

Science.gov (United States)

Yin, Shen; Gao, Huijun; Qiu, Jianbin; Kaynak, Okyay

2017-11-01

Data-driven fault detection plays an important role in industrial systems due to its applicability in case of unknown physical models. In fault detection, disturbances must be taken into account as an inherent characteristic of processes. Nevertheless, fault detection for nonlinear processes with deterministic disturbances still receive little attention, especially in data-driven field. To solve this problem, a just-in-time learning-based data-driven (JITL-DD) fault detection method for nonlinear processes with deterministic disturbances is proposed in this paper. JITL-DD employs JITL scheme for process description with local model structures to cope with processes dynamics and nonlinearity. The proposed method provides a data-driven fault detection solution for nonlinear processes with deterministic disturbances, and owns inherent online adaptation and high accuracy of fault detection. Two nonlinear systems, i.e., a numerical example and a sewage treatment process benchmark, are employed to show the effectiveness of the proposed method.

Nonlinear signal processing for ultrasonic imaging of material complexity

Czech Academy of Sciences Publication Activity Database

Dos Santos, S.; Vejvodová, Šárka; Převorovský, Zdeněk

2010-01-01

Roč. 59, č. 2 (2010), s. 108-117 ISSN 1736-6046 Institutional research plan: CEZ:AV0Z20760514 Keywords : nonlinear signal processing * TR-NEWS * symmetry analysis * DORT Subject RIV: BI - Acoustics Impact factor: 0.464, year: 2010 www.eap.ee/proceedings

Nonlinear Silicon Photonic Signal Processing Devices for Future Optical Networks

Directory of Open Access Journals (Sweden)

Cosimo Lacava

2017-01-01

Full Text Available In this paper, we present a review on silicon-based nonlinear devices for all optical nonlinear processing of complex telecommunication signals. We discuss some recent developments achieved by our research group, through extensive collaborations with academic partners across Europe, on optical signal processing using silicon-germanium and amorphous silicon based waveguides as well as novel materials such as silicon rich silicon nitride and tantalum pentoxide. We review the performance of four wave mixing wavelength conversion applied on complex signals such as Differential Phase Shift Keying (DPSK, Quadrature Phase Shift Keying (QPSK, 16-Quadrature Amplitude Modulation (QAM and 64-QAM that dramatically enhance the telecom signal spectral efficiency, paving the way to next generation terabit all-optical networks.

Advances and applications in nonlinear control systems

CERN Document Server

Volos, Christos

2016-01-01

The book reports on the latest advances and applications of nonlinear control systems. It consists of 30 contributed chapters by subject experts who are specialized in the various topics addressed in this book. The special chapters have been brought out in the broad areas of nonlinear control systems such as robotics, nonlinear circuits, power systems, memristors, underwater vehicles, chemical processes, observer design, output regulation, backstepping control, sliding mode control, time-delayed control, variables structure control, robust adaptive control, fuzzy logic control, chaos, hyperchaos, jerk systems, hyperjerk systems, chaos control, chaos synchronization, etc. Special importance was given to chapters offering practical solutions, modeling and novel control methods for the recent research problems in nonlinear control systems. This book will serve as a reference book for graduate students and researchers with a basic knowledge of electrical and control systems engineering. The resulting design proce...

Chemical radwaste solidification processes

International Nuclear Information System (INIS)

Malloy, C.W.

1979-01-01

Some of these processes and their problems are briefly reviewed: early cement systems; urea-formaldehyde; Dow solidification process; low-viscosity chemical agents (POLYPAC); and water-extensible polyester. 9 refs

Photo-physics of third-order nonlinear optical processes in organic dyes

International Nuclear Information System (INIS)

Delysse, Stephane

1997-01-01

We study some aspects of the nonlinear picosecond photo-physics in organic dyes using Kerr ellipsometry. The aim is to establish link between the photo-physics and nonlinear optics in these compounds. First, we study coherent processes directly linked to the third-order susceptibility. Thus, we measure two-photon absorption spectra of large internal charge transfer dyes. We take into account all coupling between three electronic states which can interfere to explain the particular response of some stilbene dyes. On the second hand, we expose a more photophysical approach to determine the S 1 → S n transition energies and moments using the measurement of excited state absorption cross sections. These results allow the prediction of the susceptibilities relevant to alternative nonlinear optical methods. Nevertheless, the stationary approach hides the complex relaxation processes which can take place in organic dyes. As an illustration, we study the formation and disappearance of a TICT (Twisted intramolecular charge transfer) in a pyrylium salt in solvents of increasing viscosity. (author) [fr

Nonlinear closure relations theory for transport processes in nonequilibrium systems

International Nuclear Information System (INIS)

Sonnino, Giorgio

2009-01-01

A decade ago, a macroscopic theory for closure relations has been proposed for systems out of Onsager's region. This theory is referred to as the thermodynamic field theory (TFT). The aim of this work was to determine the nonlinear flux-force relations that respect the thermodynamic theorems for systems far from equilibrium. We propose a formulation of the TFT where one of the basic restrictions, namely, the closed-form solution for the skew-symmetric piece of the transport coefficients, has been removed. In addition, the general covariance principle is replaced by the De Donder-Prigogine thermodynamic covariance principle (TCP). The introduction of TCP requires the application of an appropriate mathematical formalism, which is referred to as the entropy-covariant formalism. By geometrical arguments, we prove the validity of the Glansdorff-Prigogine universal criterion of evolution. A new set of closure equations determining the nonlinear corrections to the linear ('Onsager') transport coefficients is also derived. The geometry of the thermodynamic space is non-Riemannian. However, it tends to be Riemannian for high values of the entropy production. In this limit, we recover the transport equations found by the old theory. Applications of our approach to transport in magnetically confined plasmas, materials submitted to temperature, and electric potential gradients or to unimolecular triangular chemical reactions can be found at references cited herein. Transport processes in tokamak plasmas are of particular interest. In this case, even in the absence of turbulence, the state of the plasma remains close to (but, it is not in) a state of local equilibrium. This prevents the transport relations from being linear.

Chemical process safety at fuel cycle facilities

International Nuclear Information System (INIS)

Ayres, D.A.

1997-08-01

This NUREG provides broad guidance on chemical safety issues relevant to fuel cycle facilities. It describes an approach acceptable to the NRC staff, with examples that are not exhaustive, for addressing chemical process safety in the safe storage, handling, and processing of licensed nuclear material. It expounds to license holders and applicants a general philosophy of the role of chemical process safety with respect to NRC-licensed materials; sets forth the basic information needed to properly evaluate chemical process safety; and describes plausible methods of identifying and evaluating chemical hazards and assessing the adequacy of the chemical safety of the proposed equipment and facilities. Examples of equipment and methods commonly used to prevent and/or mitigate the consequences of chemical incidents are discussed in this document

Harnessing mode-selective nonlinear optics for on-chip multi-channel all-optical signal processing

Directory of Open Access Journals (Sweden)

Ming Ma

2016-11-01

Full Text Available All-optical signal processing based on nonlinear optical effects allows for the realization of important functions in telecommunications including wavelength conversion, optical multiplexing/demultiplexing, Fourier transformation, and regeneration, amongst others, on ultrafast time scales to support high data rate transmission. In integrated photonic subsystems, the majority of all-optical signal processing systems demonstrated to date typically process only a single channel at a time or perform a single processing function, which imposes a serious limitation on the functionality of integrated solutions. Here, we demonstrate how nonlinear optical effects can be harnessed in a mode-selective manner to perform simultaneous multi-channel (two and multi-functional optical signal processing (i.e., regenerative wavelength conversion in an integrated silicon photonic device. This approach, which can be scaled to a higher number of channels, opens up a new degree of freedom for performing a broad range of multi-channel nonlinear optical signal processing functions using a single integrated photonic device.

Nonlinear Hamiltonian mechanics applied to molecular dynamics theory and computational methods for understanding molecular spectroscopy and chemical reactions

CERN Document Server

Farantos, Stavros C

2014-01-01

This brief presents numerical methods for describing and calculating invariant phase space structures, as well as solving the classical and quantum equations of motion for polyatomic molecules. Examples covered include simple model systems to realistic cases of molecules spectroscopically studied. Vibrationally excited and reacting molecules are nonlinear dynamical systems, and thus, nonlinear mechanics is the proper theory to elucidate molecular dynamics by investigating invariant structures in phase space. Intramolecular energy transfer, and the breaking and forming of a chemical bond have now found a rigorous explanation by studying phase space structures.

NON-LINEAR FINITE ELEMENT MODELING OF DEEP DRAWING PROCESS

Directory of Open Access Journals (Sweden)

Hasan YILDIZ

2004-03-01

Full Text Available Deep drawing process is one of the main procedures used in different branches of industry. Finding numerical solutions for determination of the mechanical behaviour of this process will save time and money. In die surfaces, which have complex geometries, it is hard to determine the effects of parameters of sheet metal forming. Some of these parameters are wrinkling, tearing, and determination of the flow of the thin sheet metal in the die and thickness change. However, the most difficult one is determination of material properties during plastic deformation. In this study, the effects of all these parameters are analyzed before producing the dies. The explicit non-linear finite element method is chosen to be used in the analysis. The numerical results obtained for non-linear material and contact models are also compared with the experiments. A good agreement between the numerical and the experimental results is obtained. The results obtained for the models are given in detail.

Nonlinear Pulse Shaping in Fibres for Pulse Generation and Optical Processing

Directory of Open Access Journals (Sweden)

Sonia Boscolo

2012-01-01

Full Text Available The development of new all-optical technologies for data processing and signal manipulation is a field of growing importance with a strong potential for numerous applications in diverse areas of modern science. Nonlinear phenomena occurring in optical fibres have many attractive features and great, but not yet fully explored, potential in signal processing. Here, we review recent progress on the use of fibre nonlinearities for the generation and shaping of optical pulses and on the applications of advanced pulse shapes in all-optical signal processing. Amongst other topics, we will discuss ultrahigh repetition rate pulse sources, the generation of parabolic shaped pulses in active and passive fibres, the generation of pulses with triangular temporal profiles, and coherent supercontinuum sources. The signal processing applications will span optical regeneration, linear distortion compensation, optical decision at the receiver in optical communication systems, spectral and temporal signal doubling, and frequency conversion.

Unusual nonlinear absorption response of graphene oxide in the presence of a reduction process

International Nuclear Information System (INIS)

Karimzadeh, Rouhollah; Arandian, Alireza

2015-01-01

The nonlinear absorption responses of graphene, graphene oxide and reduced graphene oxide are investigated using the Z-scan technique and laser beams at 405, 532 and 635 nm in a continuous wave regime. Results show that graphene, graphene oxide and reduced graphene oxide do not show any open Z-scan signals at wavelengths of 532 and 635 nm. At the same time, fresh graphene oxide suspension is found to exhibit a nonlinear absorption process in the case of a laser light at 405 nm. Moreover, it can be observed that the reduction of graphene oxide by 405 nm laser irradiation decreases its nonlinear absorption value significantly. These findings highlight the important role of the reduction process on the nonlinear absorption performance of graphene oxide. (letter)

An ultra-efficient nonlinear planar integrated platform for optical signal processing and generation

DEFF Research Database (Denmark)

Pu, Minhao; Ottaviano, Luisa; Semenova, Elizaveta

2017-01-01

This paper will discuss the recently developed integrated platform: AlGaAs-oninsulator and its broad range of nonlinear applications. Recent demonstrations of broadband optical signal processing and efficient frequency comb generations in this platform will be reviewed.......This paper will discuss the recently developed integrated platform: AlGaAs-oninsulator and its broad range of nonlinear applications. Recent demonstrations of broadband optical signal processing and efficient frequency comb generations in this platform will be reviewed....

Nonlinear and Nonsymmetric Single-Molecule Electronic Properties Towards Molecular Information Processing.

Science.gov (United States)

Tamaki, Takashi; Ogawa, Takuji

2017-09-05

This review highlights molecular design for nonlinear and nonsymmetric single-molecule electronic properties such as rectification, negative differential resistance, and switching, which are important components of future single-molecule information processing devices. Perspectives on integrated "molecular circuits" are also provided. Nonlinear and nonsymmetric single-molecule electronics can be designed by utilizing (1) asymmetric molecular cores, (2) asymmetric anchoring groups, (3) an asymmetric junction environment, and (4) asymmetric electrode materials. This review mainly focuses on the design of molecular cores.

Markov chains of nonlinear Markov processes and an application to a winner-takes-all model for social conformity

Energy Technology Data Exchange (ETDEWEB)

Frank, T D [Center for the Ecological Study of Perception and Action, Department of Psychology, University of Connecticut, 406 Babbidge Road, Storrs, CT 06269 (United States)

2008-07-18

We discuss nonlinear Markov processes defined on discrete time points and discrete state spaces using Markov chains. In this context, special attention is paid to the distinction between linear and nonlinear Markov processes. We illustrate that the Chapman-Kolmogorov equation holds for nonlinear Markov processes by a winner-takes-all model for social conformity. (fast track communication)

Markov chains of nonlinear Markov processes and an application to a winner-takes-all model for social conformity

International Nuclear Information System (INIS)

Frank, T D

2008-01-01

We discuss nonlinear Markov processes defined on discrete time points and discrete state spaces using Markov chains. In this context, special attention is paid to the distinction between linear and nonlinear Markov processes. We illustrate that the Chapman-Kolmogorov equation holds for nonlinear Markov processes by a winner-takes-all model for social conformity. (fast track communication)

Nonlinear modeling and dynamic analysis of hydro-turbine governing system in the process of load rejection transient

International Nuclear Information System (INIS)

Zhang, Hao; Chen, Diyi; Xu, Beibei; Wang, Feifei

2015-01-01

Graphical abstract: Nonlinear dynamic transfer coefficients are introduced to the hydro-turbine governing system. In the process of load reject ion transient, the nonlinear dynamical behaviors of the system are studied in detail. - Highlights: • A novel mathematical model of a hydro-turbine governing system is established. • The process of load rejection transient is considered. • Nonlinear dynamic transfer coefficients are introduced to the system. • The bifurcation diagram with the variable t has better engineering significance. • The nonlinear dynamical behaviors of the system are studied in detail. - Abstract: This article pays attention to the mathematical modeling of a hydro-turbine governing system in the process of load rejection transient. As a pioneer work, the nonlinear dynamic transfer coefficients are introduced in a penstock system. Considering a generator system, a turbine system and a governor system, we present a novel nonlinear dynamical model of a hydro-turbine governing system. Fortunately, for the unchanged of PID parameters, we acquire the stable regions of the governing system in the process of load rejection transient by numerical simulations. Moreover, the nonlinear dynamic behaviors of the governing system are illustrated by bifurcation diagrams, Poincare maps, time waveforms and phase orbits. More importantly, these methods and analytic results will present theoretical groundwork for allowing a hydropower station in the process of load rejection transient

Nonlinear Lagrangian and the π N → π π π N process

International Nuclear Information System (INIS)

Pinto, F.A.

1976-02-01

A nonlinear Lagrangian is constructed involving only pions and nucleons consisting of a part invariant under the transformations of the group SU(2) (X) SU(2) and of a part which breaks this symmetry and contains an arbitrary parameter zeta introduced in order to allow the breaking of exact PCAC. The total cross-section for the process π N → π π π N at low incident energies of the incident pion, in the threshold approximation, is calculated utilizing this nonlinear Lagrangian. The parameter zeta appears in the total cross-section of the process π N → π π N also [pt

Chemical process control using Mat lab

International Nuclear Information System (INIS)

Kang, Sin Chun; Kim, Raeh Yeon; Kim, Yang Su; Oh, Min; Yeo, Yeong Gu; Jung, Yeon Su

2001-07-01

This book is about chemical process control, which includes the basis of process control with conception, function, composition of system and summary, change of laplace and linearization, modeling of chemical process, transfer function and block diagram, the first dynamic property of process, the second dynamic property of process, the dynamic property of combined process, control structure of feedback on component of control system, the dynamic property of feedback control loop, stability of closed loop control structure, expression of process, modification and composition of controller, analysis of vibration response and adjustment controller using vibration response.

Nonlinear transport processes in tokamak plasmas. I. The collisional regimes

International Nuclear Information System (INIS)

Sonnino, Giorgio; Peeters, Philippe

2008-01-01

An application of the thermodynamic field theory (TFT) to transport processes in L-mode tokamak plasmas is presented. The nonlinear corrections to the linear ('Onsager') transport coefficients in the collisional regimes are derived. A quite encouraging result is the appearance of an asymmetry between the Pfirsch-Schlueter (P-S) ion and electron transport coefficients: the latter presents a nonlinear correction, which is absent for the ions, and makes the radial electron coefficients much larger than the former. Explicit calculations and comparisons between the neoclassical results and the TFT predictions for Joint European Torus (JET) plasmas are also reported. It is found that the nonlinear electron P-S transport coefficients exceed the values provided by neoclassical theory by a factor that may be of the order 10 2 . The nonlinear classical coefficients exceed the neoclassical ones by a factor that may be of order 2. For JET, the discrepancy between experimental and theoretical results for the electron losses is therefore significantly reduced by a factor 10 2 when the nonlinear contributions are duly taken into account but, there is still a factor of 10 2 to be explained. This is most likely due to turbulence. The expressions of the ion transport coefficients, determined by the neoclassical theory in these two regimes, remain unaltered. The low-collisional regimes, i.e., the plateau and the banana regimes, are analyzed in the second part of this work

Linear and Nonlinear MHD Wave Processes in Plasmas. Final Report

International Nuclear Information System (INIS)

Tataronis, J. A.

2004-01-01

This program treats theoretically low frequency linear and nonlinear wave processes in magnetized plasmas. A primary objective has been to evaluate the effectiveness of MHD waves to heat plasma and drive current in toroidal configurations. The research covers the following topics: (1) the existence and properties of the MHD continua in plasma equilibria without spatial symmetry; (2) low frequency nonresonant current drive and nonlinear Alfven wave effects; and (3) nonlinear electron acceleration by rf and random plasma waves. Results have contributed to the fundamental knowledge base of MHD activity in symmetric and asymmetric toroidal plasmas. Among the accomplishments of this research effort, the following are highlighted: Identification of the MHD continuum mode singularities in toroidal geometry. Derivation of a third order ordinary differential equation that governs nonlinear current drive in the singular layers of the Alfven continuum modes in axisymmetric toroidal geometry. Bounded solutions of this ODE implies a net average current parallel to the toroidal equilibrium magnetic field. Discovery of a new unstable continuum of the linearized MHD equation in axially periodic circular plasma cylinders with shear and incompressibility. This continuum, which we named ''accumulation continuum'' and which is related to ballooning modes, arises as discrete unstable eigenfrequency accumulate on the imaginary frequency axis in the limit of large mode numbers. Development of techniques to control nonlinear electron acceleration through the action of multiple coherent and random plasmas waves. Two important elements of this program aye student participation and student training in plasma theory

Applications of Process Synthesis: Moving from Conventional Chemical Processes towards Biorefinery Processes

DEFF Research Database (Denmark)

Yuan, Zhihong; Chen, Bingzhen; Gani, Rafiqul

2013-01-01

Concerns about diminishing petroleum reserves, enhanced worldwide demand for fuels and fluctuations in the global oil market, together with climate change and national security have promoted many initiatives for exploring alternative, non-petroleum based processes. Among these initiatives......, biorefinery processes for converting biomass-derived carbohydrates into transportation fuels and chemicals are now gaining more and more attention from both academia and industry. Process synthesis, which has played a vital role for the development, design and operation of (petro) chemical processes, can...

Recombination Processes and Nonlinear Markov Chains.

Science.gov (United States)

Pirogov, Sergey; Rybko, Alexander; Kalinina, Anastasia; Gelfand, Mikhail

2016-09-01

Bacteria are known to exchange genetic information by horizontal gene transfer. Since the frequency of homologous recombination depends on the similarity between the recombining segments, several studies examined whether this could lead to the emergence of subspecies. Most of them simulated fixed-size Wright-Fisher populations, in which the genetic drift should be taken into account. Here, we use nonlinear Markov processes to describe a bacterial population evolving under mutation and recombination. We consider a population structure as a probability measure on the space of genomes. This approach implies the infinite population size limit, and thus, the genetic drift is not assumed. We prove that under these conditions, the emergence of subspecies is impossible.

Observations of linear and nonlinear processes in the foreshock wave evolution

Directory of Open Access Journals (Sweden)

Y. Narita

2007-07-01

Full Text Available Waves in the foreshock region are studied on the basis of a hypothesis that the linear process first excites the waves and further wave-wave nonlinearities distribute scatter the energy of the primary waves into a number of daughter waves. To examine this wave evolution scenario, the dispersion relations, the wave number spectra of the magnetic field energy, and the dimensionless cross helicity are determined from the observations made by the four Cluster spacecraft. The results confirm that the linear process is the ion/ion right-hand resonant instability, but the wave-wave interactions are not clearly identified. We discuss various reasons why the test for the wave-wave nonlinearities fails, and conclude that the higher order statistics would provide a direct evidence for the wave coupling phenomena.

Parallel processing for nonlinear dynamics simulations of structures including rotating bladed-disk assemblies

Science.gov (United States)

Hsieh, Shang-Hsien

1993-01-01

The principal objective of this research is to develop, test, and implement coarse-grained, parallel-processing strategies for nonlinear dynamic simulations of practical structural problems. There are contributions to four main areas: finite element modeling and analysis of rotational dynamics, numerical algorithms for parallel nonlinear solutions, automatic partitioning techniques to effect load-balancing among processors, and an integrated parallel analysis system.

Acoustic wave focusing in complex media using Nonlinear Time Reversal coded signal processing

Czech Academy of Sciences Publication Activity Database

Dos Santos, S.; Dvořáková, Zuzana; Lints, M.; Kůs, V.; Salupere, A.; Převorovský, Zdeněk

2014-01-01

Roč. 19, č. 12 (2014) ISSN 1435-4934. [European Conference on Non-Destructive Testing (ECNDT 2014) /11./. Praha, 06.10.2014-10.10.2014] Institutional support: RVO:61388998 Keywords : ultrasonic testing (UT) * signal processing * TR- NEWS * nonlinear time reversal * NDT * nonlinear acoustics Subject RIV: BI - Acoustics http://www.ndt.net/events/ECNDT2014/app/content/Slides/590_DosSantos_Rev1.pdf

Strategies for Enhancing Nonlinear Internal Model Control of pH Processes

Energy Technology Data Exchange (ETDEWEB)

Hu, Qiuping.; Rangaiah, G.P. [The National University of Singapore, Singapore (Singapore). Dept. of Chemical and Environmental Engineering

1999-02-01

Control of neutralization processes is very difficult due to nonlinear dynamics, different types of disturbances and modeling errors. The objective of the paper is to evaluate two strategies (augmented internal model control, AuIMC and adaptive internal model control, AdIMC) for enhancing pH control by nonlinear internal model control (NIMC). A NIMC controller is derived directly form input output linearization. The AuIMC is composed of NIMC and an additional loop through which the difference between the process and model outputs is fed back and added to the input of the controller. For the AdIMC, and adaptive law with two tuning parameters is proposed for estimating the unknown parameter. Both AuIMC and AdIMC are extensively tested via simulation for pH neutralization. The theoretical and simulation results show that both the proposed strategies can reduce the effect of modeling errors and disturbances, and thereby enhance the performance of NIMC for pH processes. (author)

Some applications of nonlinear diffusion to processing of dynamic evolution images

International Nuclear Information System (INIS)

Goltsov, Alexey N.; Nikishov, Sergey A.

1997-01-01

Model nonlinear diffusion equation with the most simple Landau-Ginzburg free energy functional was applied to locate boundaries between meaningful regions of low-level images. The method is oriented to processing images of objects that are a result of dynamic evolution: images of different organs and tissues obtained by radiography and NMR methods, electron microscope images of morphogenesis fields, etc. In the methods developed by us, parameters of the nonlinear diffusion model are chosen on the basis of the preliminary treatment of the images. The parameters of the Landau-Ginzburg free energy functional are extracted from the structure factor of the images. Owing to such a choice of the model parameters, the image to be processed is located in the vicinity of the steady-state of the diffusion equation. The suggested method allows one to separate distinct structures having specific space characteristics from the whole image. The method was applied to processing X-ray images of the lung

Azimuthal asymmetry in processes of nonlinear QED for linearly polarized photon

International Nuclear Information System (INIS)

Bajer, V.N.; Mil'shtejn, A.I.

1994-01-01

Cross sections of nonlinear QED processes (photon-photon scattering, photon splitting in a Coulomb field, and Delbrueck scattering) are considered for linearly polarized initial photon. The cross sections have sizeable azimuthal asymmetry. 15 refs.; 3 figs

Ultrafast nonlinear optical processes in metal-dielectric nanocomposites and nanostructures

Energy Technology Data Exchange (ETDEWEB)

Kim, Kwang-Hyon

2012-04-13

This work reports results of a theoretical study of nonlinear optical processes in metal-dielectric nanocomposites used for the increase of the nonlinear coefficients and for plasmonic field enhancement. The main results include the study of the transient saturable nonlinearity in dielectric composites doped with metal nanoparticles, its physical mechanism as well its applications in nonlinear optics. For the study of the transient response, a time-depending equation for the dielectric function of the nanocomposite using the semi-classical two-temperature model is derived. By using this approach, we study the transient nonlinear characteristics of these materials in comparison with preceding experimental measurements. The results show that these materials behave as efficient saturable absorbers for passive mode-locking of lasers in the spectral range from the visible to near IR. We present results for the modelocked dynamics in short-wavelength solid-state and semiconductor disk lasers; in this spectral range other efficient saturable absorbers do not exist. We suggest a new mechanism for the realization of slow light phenomenon by using glasses doped with metal nanoparticles in a pump-probe regime near the plasmonic resonance. Furthermore, we study femtosecond plasmon generation by mode-locked surface plasmon polariton lasers with Bragg reflectors and metal-gain-absorber layered structures. In the final part of the thesis, we present results for high-order harmonic generation near a metallic fractal rough surface. The results show a possible reduction of the pump intensities by three orders of magnitudes and two orders of magnitudes higher efficiency compared with preceding experimental results by using bow-tie nanostructures.

Mathematical models of non-linear phenomena, processes and systems: from molecular scale to planetary atmosphere

CERN Document Server

2013-01-01

This book consists of twenty seven chapters, which can be divided into three large categories: articles with the focus on the mathematical treatment of non-linear problems, including the methodologies, algorithms and properties of analytical and numerical solutions to particular non-linear problems; theoretical and computational studies dedicated to the physics and chemistry of non-linear micro-and nano-scale systems, including molecular clusters, nano-particles and nano-composites; and, papers focused on non-linear processes in medico-biological systems, including mathematical models of ferments, amino acids, blood fluids and polynucleic chains.

The second order extended Kalman filter and Markov nonlinear filter for data processing in interferometric systems

International Nuclear Information System (INIS)

Ermolaev, P; Volynsky, M

2014-01-01

Recurrent stochastic data processing algorithms using representation of interferometric signal as output of a dynamic system, which state is described by vector of parameters, in some cases are more effective, compared with conventional algorithms. Interferometric signals depend on phase nonlinearly. Consequently it is expedient to apply algorithms of nonlinear stochastic filtering, such as Kalman type filters. An application of the second order extended Kalman filter and Markov nonlinear filter that allows to minimize estimation error is described. Experimental results of signals processing are illustrated. Comparison of the algorithms is presented and discussed.

Bifurcation and stability analysis of a nonlinear milling process

Science.gov (United States)

Weremczuk, Andrzej; Rusinek, Rafal; Warminski, Jerzy

2018-01-01

Numerical investigations of milling operations dynamics are presented in this paper. A two degree of freedom nonlinear model is used to study workpiece-tool vibrations. The analyzed model takes into account both flexibility of the tool and the workpiece. The dynamics of the milling process is described by the discontinuous ordinary differential equation with time delay, which can cause process instability. First, stability lobes diagrams are created on the basis of the parameters determined in impact test of an end mill and workpiece. Next, the bifurcations diagrams are performed for different values of rotational speeds.

CHEMSIMUL: A simulator for chemical kinetics

DEFF Research Database (Denmark)

Kirkegaard, P.; Bjergbakke, E.

1999-01-01

CHEMSIMUL is a computer program system for numerical simulation of chemical reaction systems. It can be used for modeling complex kinetics in many contexts, in particular radiolytic processes. It contains a translator module and a module for solving theresulting coupled nonlinear ordinary...

Nonlinear dynamics in flow through unsaturated fractured porous media: Status and perspectives

International Nuclear Information System (INIS)

Faybishenko, Boris

2002-01-01

The need has long been recognized to improve predictions of flow and transport in partially saturated heterogeneous soils and fractured rock of the vadose zone for many practical applications, such as remediation of contaminated sites, nuclear waste disposal in geological formations, and climate predictions. Until recently, flow and transport processes in heterogeneous subsurface media with oscillating irregularities were assumed to be random and were not analyzed using methods of nonlinear dynamics. The goals of this paper are to review the theoretical concepts, present the results, and provide perspectives on investigations of flow and transport in unsaturated heterogeneous soils and fractured rock, using the methods of nonlinear dynamics and deterministic chaos. The results of laboratory and field investigations indicate that the nonlinear dynamics of flow and transport processes in unsaturated soils and fractured rocks arise from the dynamic feedback and competition between various nonlinear physical processes along with complex geometry of flow paths. Although direct measurements of variables characterizing the individual flow processes are not technically feasible, their cumulative effect can be characterized by analyzing time series data using the models and methods of nonlinear dynamics and chaos. Identifying flow through soil or rock as a nonlinear dynamical system is important for developing appropriate short- and long-time predictive models, evaluating prediction uncertainty, assessing the spatial distribution of flow characteristics from time series data, and improving chemical transport simulations. Inferring the nature of flow processes through the methods of nonlinear dynamics could become widely used in different areas of the earth sciences

Nonlinear dynamics in flow through unsaturated fractured-porous media: Status and perspectives

Energy Technology Data Exchange (ETDEWEB)

Faybishenko, Boris

2002-11-27

The need has long been recognized to improve predictions of flow and transport in partially saturated heterogeneous soils and fractured rock of the vadose zone for many practical applications, such as remediation of contaminated sites, nuclear waste disposal in geological formations, and climate predictions. Until recently, flow and transport processes in heterogeneous subsurface media with oscillating irregularities were assumed to be random and were not analyzed using methods of nonlinear dynamics. The goals of this paper are to review the theoretical concepts, present the results, and provide perspectives on investigations of flow and transport in unsaturated heterogeneous soils and fractured rock, using the methods of nonlinear dynamics and deterministic chaos. The results of laboratory and field investigations indicate that the nonlinear dynamics of flow and transport processes in unsaturated soils and fractured rocks arise from the dynamic feedback and competition between various nonlinear physical processes along with complex geometry of flow paths. Although direct measurements of variables characterizing the individual flow processes are not technically feasible, their cumulative effect can be characterized by analyzing time series data using the models and methods of nonlinear dynamics and chaos. Identifying flow through soil or rock as a nonlinear dynamical system is important for developing appropriate short- and long-time predictive models, evaluating prediction uncertainty, assessing the spatial distribution of flow characteristics from time series data, and improving chemical transport simulations. Inferring the nature of flow processes through the methods of nonlinear dynamics could become widely used in different areas of the earth sciences.

Chemical process and plant design bibliography 1959-1989

International Nuclear Information System (INIS)

Ray, M.S.

1991-01-01

This book is concerned specifically with chemical process in formation and plant equipment design data. It is a source for chemical engineers, students and academics involved in process and design evaluation. Over 500 chemical categories are included, from Acetaldehyde to zirconium Dioxide, with cross-referencing within the book to appropriate associated chemicals

From point process observations to collective neural dynamics: Nonlinear Hawkes process GLMs, low-dimensional dynamics and coarse graining.

Science.gov (United States)

Truccolo, Wilson

2016-11-01

This review presents a perspective on capturing collective dynamics in recorded neuronal ensembles based on multivariate point process models, inference of low-dimensional dynamics and coarse graining of spatiotemporal measurements. A general probabilistic framework for continuous time point processes reviewed, with an emphasis on multivariate nonlinear Hawkes processes with exogenous inputs. A point process generalized linear model (PP-GLM) framework for the estimation of discrete time multivariate nonlinear Hawkes processes is described. The approach is illustrated with the modeling of collective dynamics in neocortical neuronal ensembles recorded in human and non-human primates, and prediction of single-neuron spiking. A complementary approach to capture collective dynamics based on low-dimensional dynamics ("order parameters") inferred via latent state-space models with point process observations is presented. The approach is illustrated by inferring and decoding low-dimensional dynamics in primate motor cortex during naturalistic reach and grasp movements. Finally, we briefly review hypothesis tests based on conditional inference and spatiotemporal coarse graining for assessing collective dynamics in recorded neuronal ensembles. Published by Elsevier Ltd.

Seismic scoping evaluation of high level liquid waste tank vaults at the Idaho Chemical Processing Plant

International Nuclear Information System (INIS)

Hashimoto, P.S.; Uldrich, E.D.; McGee, W.D.

1991-01-01

A seismic scoping evaluation of buried vaults enclosing high level liquid waste storage tanks at the Idaho Chemical Processing Plant has been performed. The objective of this evaluation was to scope out which of the vaults could be demonstrated to be seismically adequate against the Safe Shutdown Earthquake (SSE). Using approximate analytical methods, earthquake experience data, and engineering judgement, this study determined that one vault configuration would be expected to meet ICPP seismic design criteria, one would not be considered seismically adequate against the SSE, and one could be shown to be seismically adequate against the SSE using nonlinear analysis

PLASMA EMISSION BY NONLINEAR ELECTROMAGNETIC PROCESSES

Energy Technology Data Exchange (ETDEWEB)

Ziebell, L. F.; Petruzzellis, L. T.; Gaelzer, R. [Instituto de Física, UFRGS, Porto Alegre, RS (Brazil); Yoon, P. H. [Institute for Physical Science and Technology, University of Maryland, College Park (United States); Pavan, J., E-mail: luiz.ziebell@ufrgs.br, E-mail: laripetruzzellis@yahoo.com.br, E-mail: rudi.gaelzer@ufrgs.br, E-mail: yoonp@umd.edu, E-mail: joel.pavan@ufpel.edu.br [Instituto de Física e Matemática, UFPel, Pelotas, RS (Brazil)

2015-06-20

The plasma emission, or electromagnetic (EM) radiation at the plasma frequency and/or its harmonic(s), is generally accepted as the radiation mechanism responsible for solar type II and III radio bursts. Identification and characterization of these solar radio burst phenomena were done in the 1950s. Despite many decades of theoretical research since then, a rigorous demonstration of the plasma emission process based upon first principles was not available until recently, when, in a recent Letter, Ziebell et al. reported the first complete numerical solution of EM weak turbulence equations; thus, quantitatively analyzing the plasma emission process starting from the initial electron beam and the associated beam-plasma (or Langmuir wave) instability, as well as the subsequent nonlinear conversion of electrostatic Langmuir turbulence into EM radiation. In the present paper, the same problem is revisited in order to elucidate the detailed physical mechanisms that could not be reported in the brief Letter format. Findings from the present paper may be useful for interpreting observations and full-particle numerical simulations.

Progress in nonlinear nano-optics

CERN Document Server

Lienau, Christoph; Grunwald, Rüdiger

2015-01-01

This book presents the state of the art in nonlinear nanostructures for ultrafast laser applications. Most recent results in two emerging fields are presented: (i) generation of laser-induced nanostructures in materials like metals, metal oxides and semiconductors, and (ii) ultrafast excitation and energy transfer in nanoscale physical, chemical and hybrid systems. Particular emphasis is laid on the up-to-date controversially discussed mechanisms of sub-wavelength ripple formation including models of self-organized material transport and multiphoton excitation channels, nonlinear optics of plasmonic structures (nanotips, nanowires, 3D-metamaterials), and energy localization and transport on ultrafast time scale and spatial nanoscale. High-resolution spectroscopy, simulation and characterization techniques are reported. New applications of ultrashort-pulsed lasers for materials processing and the use of nanostructured materials for characterizing laser fields and laser-matter-interactions are discussed.

Control of a nonlinear ice cream crystallization process

OpenAIRE

Casenave, Céline; Dochain, Denis; Alvarez, Graciela; Arellano, Marcela; Benkhelifa, Hayat; Leducq, Denis

2013-01-01

International audience; In the ice cream industry, the type of final desired product (large cartons (sqrounds) or ice creams on a stick) determine the viscosity at which the ice cream has to be produced. One of the objectives of the ice cream crystallization processes is therefore to produce an ice cream of specified viscosity. In this paper, a nonlinear control strategy is proposed for the control of the viscosity of the ice cream in a continuous crystallizer. It has been designed on the bas...

Textiles and clothing sustainability sustainable textile chemical processes

CERN Document Server

2017-01-01

This book highlights the challenges in sustainable wet processing of textiles, natural dyes, enzymatic textiles and sustainable textile finishes. Textile industry is known for its chemical processing issues and many NGO’s are behind the textile sector to streamline its chemical processing, which is the black face of clothing and fashion sector. Sustainable textile chemical processes are crucial for attaining sustainability in the clothing sector. Seven comprehensive chapters are aimed to highlight these issues in the book.

Parametric Investigation of the Isothermal Kinetics of Growth of Graphene on a Nickel Catalyst in the Process of Chemical Vapor Deposition of Hydrocarbons

Science.gov (United States)

Futko, S. I.; Shulitskii, B. G.; Labunov, V. A.; Ermolaeva, E. M.

2016-11-01

A kinetic model of isothermal synthesis of multilayer graphene on the surface of a nickel foil in the process of chemical vapor deposition, on it, of hydrocarbons supplied in the pulsed regime is considered. The dependences of the number of graphene layers formed and the time of their growth on the temperature of the process, the concentration of acetylene, and the thickness of the nickel foil were calculated. The regime parameters of the process of chemical vapor deposition, at which single-layer graphene and bi-layer graphene are formed, were determined. The dynamics of growth of graphene domains at chemical-vapor-deposition parameters changing in wide ranges was investigated. It is shown that the time dependences of the rates of growth of single-layer graphene and bi-layer graphene are nonlinear in character and that they are determined by the kinetics of nucleation and growth of graphene and the diffusion flow of carbon atoms in the nickel foil.

Chemical process safety management within the Department of Energy

International Nuclear Information System (INIS)

Piatt, J.A.

1995-07-01

Although the Department of Energy (DOE) is not well known for its chemical processing activities, the DOE does have a variety of chemical processes covered under OSHA's Rule for Process Safety Management of Highly Hazardous Chemicals (the PSM Standard). DOE, like industry, is obligated to comply with the PSM Standard. The shift in the mission of DOE away from defense programs toward environmental restoration and waste management has affected these newly forming process safety management programs within DOE. This paper describes the progress made in implementing effective process safety management programs required by the PSM Standard and discusses some of the trends that have supported efforts to reduce chemical process risks within the DOE. In June of 1994, a survey of chemicals exceeding OSHA PSM or EPA Risk Management Program threshold quantities (TQs) at DOE sites found that there were 22 processes that utilized toxic or reactive chemicals over TQs; there were 13 processes involving flammable gases and liquids over TQs; and explosives manufacturing occurred at 4 sites. Examination of the survey results showed that 12 of the 22 processes involving toxic chemicals involved the use of chlorine for water treatment systems. The processes involving flammable gases and liquids were located at the Strategic Petroleum Reserve and Naval petroleum Reserve sites

Nonlinear transformations of random processes

CERN Document Server

Deutsch, Ralph

2017-01-01

This concise treatment of nonlinear noise techniques encountered in system applications is suitable for advanced undergraduates and graduate students. It is also a valuable reference for systems analysts and communication engineers. 1962 edition.

Suppression of two-photon resonantly enhanced nonlinear processes in extended media

International Nuclear Information System (INIS)

Garrett, W.R.; Moore, M.A.; Payne, M.G.; Wunderlich, R.K.

1988-11-01

On the basis of combined experimental and theoretical studies of nonlinear processes associated with two-photon excitations near 3d and 4d states in Na, we show how resonantly enhanced stimulated hyper-Raman emission, parametric four-wave mixing processes and total resonant two-photon absorption can become severely suppressed through the actions of internally generated fields on the total atomic response in extended media. 7 refs., 3 figs

Predicting speech intelligibility in conditions with nonlinearly processed noisy speech

DEFF Research Database (Denmark)

Jørgensen, Søren; Dau, Torsten

2013-01-01

The speech-based envelope power spectrum model (sEPSM; [1]) was proposed in order to overcome the limitations of the classical speech transmission index (STI) and speech intelligibility index (SII). The sEPSM applies the signal-tonoise ratio in the envelope domain (SNRenv), which was demonstrated...... to successfully predict speech intelligibility in conditions with nonlinearly processed noisy speech, such as processing with spectral subtraction. Moreover, a multiresolution version (mr-sEPSM) was demonstrated to account for speech intelligibility in various conditions with stationary and fluctuating...

Sub-wavelength patterning of organic monolayers via nonlinear processing with continuous-wave lasers

Energy Technology Data Exchange (ETDEWEB)

Mathieu, Mareike; Hartmann, Nils, E-mail: nils.hartmann@uni-due.de [Fakultaet fuer Chemie, Universitaet Duisburg-Essen, 45117 Essen (Germany); CeNIDE-Center for Nanointegration Duisburg-Essen, 47048 Duisburg (Germany); NETZ-NanoEnergieTechnikZentrum, 47048 Duisburg (Germany)

2010-12-15

In recent years, nonlinear processing with continuous-wave lasers has been demonstrated to be a facile means of rapid nanopatterning of organic monolayers down to the sub-100 nm range. In this study, we report on laser patterning of thiol-based organic monolayers with sub-wavelength resolution. Au-coated silicon substrates are functionalized with 1-hexadecanethiol. Irradiation with a focused beam of an Ar{sup +} laser operating at {lambda}=514 nm allows one to locally remove the monolayer. Subsequently, the patterns are transferred into the Au film via selective etching in a ferri-/ferrocyanide solution. Despite a 1/e{sup 2} spot diameter of about 2.8 {mu}m, structures with lateral dimensions down to 250 nm are fabricated. The underlying nonlinear dependence of the patterning process on laser intensity is traced back to the interplay between the laser-induced transient local temperature rise and the thermally activated desorption of the thiol molecules. A simple thermokinetic analysis of the data allows us to determine the effective kinetic parameters. These results complement our previous work on photothermal laser patterning of ultrathin organic coatings, such as silane-based organic monolayers, organo/silicon interfaces and supported membranes. A general introduction to nonlinear laser processing of organic monolayers is presented.

Some nonlinear processes relevant to the beat wave accelerator

International Nuclear Information System (INIS)

Bingham, R.; Mori, W.B.

1985-03-01

The beat wave accelerator depends on the generation of a large amplitude plasma wave with a phase velocity close to the velocity of light c. The plasma wave (ωsub(p), ksub(p)) is generated by beating colinear laser beams (ω 1 , k 1 ) and (ω 2 ,k 2 ) with ωsub(p) = ω 1 -ω 2 , ksub(p) = k 1 -k 2 . Since the process involves both large amplitude transverse and longitudinal waves, various nonlinear instabilities associated with either wave may occur. The object of the article is to discuss some of the processes that may compete with the beat wave generation listing their threshold and growth rate. (author)

Conceptual Chemical Process Design for Sustainability.

Science.gov (United States)

This chapter examines the sustainable design of chemical processes, with a focus on conceptual design, hierarchical and short-cut methods, and analyses of process sustainability for alternatives. The chapter describes a methodology for incorporating process sustainability analyse...

Lasers in chemical processing

International Nuclear Information System (INIS)

Davis, J.I.

1982-01-01

The high cost of laser energy is the crucial issue in any potential laser-processing application. It is expensive relative to other forms of energy and to most bulk chemicals. We show those factors that have previously frustrated attempts to find commercially viable laser-induced processes for the production of materials. Having identified the general criteria to be satisfied by an economically successful laser process and shown how these imply the laser-system requirements, we present a status report on the uranium laser isotope separation (LIS) program at the Lawrence Livermore National Laboratory

Mode-selective mapping and control of vectorial nonlinear-optical processes in multimode photonic-crystal fibers.

Science.gov (United States)

Hu, Ming-Lie; Wang, Ching-Yue; Song, You-Jian; Li, Yan-Feng; Chai, Lu; Serebryannikov, Evgenii; Zheltikov, Aleksei

2006-02-06

We demonstrate an experimental technique that allows a mapping of vectorial nonlinear-optical processes in multimode photonic-crystal fibers (PCFs). Spatial and polarization modes of PCFs are selectively excited in this technique by varying the tilt angle of the input beam and rotating the polarization of the input field. Intensity spectra of the PCF output plotted as a function of the input field power and polarization then yield mode-resolved maps of nonlinear-optical interactions in multimode PCFs, facilitating the analysis and control of nonlinear-optical transformations of ultrashort laser pulses in such fibers.

Polarization dependent dispersion and its impact on optical parametric process in high nonlinear microstructure fibre

International Nuclear Information System (INIS)

Xiao Li; Zhang Wei; Huang Yidong; Peng Jiangde

2008-01-01

High nonlinear microstructure fibre (HNMF) is preferred in nonlinear fibre optics, especially in the applications of optical parametric effects, due to its high optical nonlinear coefficient. However, polarization dependent dispersion will impact the nonlinear optical parametric process in HNMFs. In this paper, modulation instability (MI) method is used to measure the polarization dependent dispersion of a piece of commercial HNMF, including the group velocity dispersion, the dispersion slope, the fourth-order dispersion and group birefringence. It also experimentally demonstrates the impact of the polarization dependent dispersion on the continuous wave supercontinuum (SC) generation. On one axis MI sidebands with symmetric frequency detunings are generated, while on the other axis with larger MI frequency detuning, SC is generated by soliton self-frequency shift

All-optical signal processing in quadratic nonlinear materials

DEFF Research Database (Denmark)

Johansen, Steffen Kjær

2002-01-01

of materials with a second order nonlinearity, the so-called X(2) materials, is faster and stronger than that of more conventional materials with a cubic nonlinearity. The X(2) materials support spatial solitons consisting of two coupled components, the fundamental wave (FW) and its second harmonic (SH......). During this project the interaction between such spatial solitons has been investigated theoretically through perturbation theory and experimentally via numerical simulations. The outcome of this research isnew theoretical tools for quantitatively predicting the escape angle, i.e. the angle of incidence...... are dedicated to this part of the research. In chapter 4 the generality of the theoretical approach is emphasised with the derivation and verification of equivalent tools for media with a saturable nonlinearity. The strength of the X(2) nonlinearity strongly depends on the phase mismatch between the FW...

Predicting seizures in untreated temporal lobe epilepsy using point-process nonlinear models of heartbeat dynamics.

Science.gov (United States)

Valenza, G; Romigi, A; Citi, L; Placidi, F; Izzi, F; Albanese, M; Scilingo, E P; Marciani, M G; Duggento, A; Guerrisi, M; Toschi, N; Barbieri, R

2016-08-01

Symptoms of temporal lobe epilepsy (TLE) are frequently associated with autonomic dysregulation, whose underlying biological processes are thought to strongly contribute to sudden unexpected death in epilepsy (SUDEP). While abnormal cardiovascular patterns commonly occur during ictal events, putative patterns of autonomic cardiac effects during pre-ictal (PRE) periods (i.e. periods preceding seizures) are still unknown. In this study, we investigated TLE-related heart rate variability (HRV) through instantaneous, nonlinear estimates of cardiovascular oscillations during inter-ictal (INT) and PRE periods. ECG recordings from 12 patients with TLE were processed to extract standard HRV indices, as well as indices of instantaneous HRV complexity (dominant Lyapunov exponent and entropy) and higher-order statistics (bispectra) obtained through definition of inhomogeneous point-process nonlinear models, employing Volterra-Laguerre expansions of linear, quadratic, and cubic kernels. Experimental results demonstrate that the best INT vs. PRE classification performance (balanced accuracy: 73.91%) was achieved only when retaining the time-varying, nonlinear, and non-stationary structure of heartbeat dynamical features. The proposed approach opens novel important avenues in predicting ictal events using information gathered from cardiovascular signals exclusively.

Nonlinear and turbulent processes in physics. Volume 2. Nonlinear effects in various areas of science

Energy Technology Data Exchange (ETDEWEB)

Sagdeev, R Z

1984-01-01

The results of theoretical and experimental investigations of nonlinear and turbulent phenomena from a wide range of fields in physics are presented in reviews and reports. Topics examined include localized vortex formations in an ideal fluid, phase transitions in crystals, spatially nonuniform structures in condensed matter, solitons in molecular systems, the migration of quasi-particles in easily deformed crystals, bifurcations and dissipative structures in distributed kinetic systems, and structures in a nonlinear burning medium. Consideration is given to macroscopic motion generation in nonequilibrium media, the interaction of bulk and surface wave trains, near-threshold instabilities in hydrodynamics, solitons in nonlinear elastic rods with variable characteristics, the generation of solitons and vortices from chaos, and nonlinear electromagnetic-wave dissipation in an electron system.

Nonlinear dynamic processes in modified ionospheric plasma

Science.gov (United States)

Kochetov, A.; Terina, G.

Presented work is a contribution to the experimental and theoretical study of nonlinear effects arising on ionospheric plasma under the action of powerful radio emission (G.I. Terina, J. Atm. Terr. Phys., 1995, v.57, p.273; A.V. Kochetov et. al., Advances in Space Research, 2002, in press). The experimental results were obtained by the method of sounding of artificially disturbed ionosphere by short radio pulses. The amplitude and phase characteristics of scattered signal as of "caviton" type (CS) (analogy of narrow-band component of stimulation electromagnetic emission (SEE)) as the main signal (MS) of probing transmitter are considered. The theoretical model is based on numerical solution of driven nonlinear Shrödinger equation (NSE) in inhomogeneous plasma. The simulation allows us to study a self-consistent spatial-temporal dynamics of field and plasma. The observed evolution of phase characteristics of MS and CS qualitatively correspond to the results of numerical simulation and demonstrate the penetration processes of powerful electromagnetic wave in supercritical (in linear approach) plasma regions. The modeling results explain also the periodic generation of CS, the travel CS maximum down to density gradient, the aftereffect of CS. The obtained results show the excitation of strong turbulence and allow us to interpret CS, NC and so far inexplicable phenomena as "spikes" too. The work was supported in part by Russian Foundation for Basic Research (grants Nos. 99-02-16642, 99-02- 16399).

Chemical reagent and process for refuse disposal

International Nuclear Information System (INIS)

Somerville, R.B.; Fan, L.T.

1989-01-01

A process for treating refuse by mixing them with a reactive chemical and a puzzolana-type material. Said chemical includes a retarding agent which modifies the viscosity and an accelerating agent. (author)

Femtosecond laser studies of ultrafast intramolecular processes

Energy Technology Data Exchange (ETDEWEB)

Hayden, C. [Sandia National Laboratories, Livermore, CA (United States)

1993-12-01

The goal of this research is to better understand the detailed mechanisms of chemical reactions by observing, directly in time, the dynamics of fundamental chemical processes. In this work femtosecond laser pulses are used to initiate chemical processes and follow the progress of these processes in time. The authors are currently studying ultrafast internal conversion and subsequent intramolecular relaxation in unsaturated hydrocarbons. In addition, the authors are developing nonlinear optical techniques to prepare and monitor the time evolution of specific vibrational motions in ground electronic state molecules.

MRI of chemical reactions and processes.

Science.gov (United States)

Britton, Melanie M

2017-08-01

As magnetic resonance imaging (MRI) can spatially resolve a wealth of molecular information available from nuclear magnetic resonance (NMR), it is able to non-invasively visualise the composition, properties and reactions of a broad range of spatially-heterogeneous molecular systems. Hence, MRI is increasingly finding applications in the study of chemical reactions and processes in a diverse range of environments and technologies. This article will explain the basic principles of MRI and how it can be used to visualise chemical composition and molecular properties, providing an overview of the variety of information available. Examples are drawn from the disciplines of chemistry, chemical engineering, environmental science, physics, electrochemistry and materials science. The review introduces a range of techniques used to produce image contrast, along with the chemical and molecular insight accessible through them. Methods for mapping the distribution of chemical species, using chemical shift imaging or spatially-resolved spectroscopy, are reviewed, as well as methods for visualising physical state, temperature, current density, flow velocities and molecular diffusion. Strategies for imaging materials with low signal intensity, such as those containing gases or low sensitivity nuclei, using compressed sensing, para-hydrogen or polarisation transfer, are discussed. Systems are presented which encapsulate the diversity of chemical and physical parameters observable by MRI, including one- and two-phase flow in porous media, chemical pattern formation, phase transformations and hydrodynamic (fingering) instabilities. Lastly, the emerging area of electrochemical MRI is discussed, with studies presented on the visualisation of electrochemical deposition and dissolution processes during corrosion and the operation of batteries, supercapacitors and fuel cells. Crown Copyright © 2017. Published by Elsevier B.V. All rights reserved.

Low temperature radio-chemical energy conversion processes

International Nuclear Information System (INIS)

Gomberg, H.J.

1986-01-01

This patent describes a radio-chemical method of converting radiated energy into chemical energy form comprising the steps of: (a) establishing a starting chemical compound in the liquid phase that chemically reacts endothermically to radiation and heat energy to produce a gaseous and a solid constituent of the compound, (b) irradiating the compound in its liquid phase free of solvents to chemically release therefrom in response to the radiation the gaseous and solid constituents, (c) physically separating the solid and gaseous phase constituents from the liquid, and (d) chemically processing the constituents to recover therefrom energy stored therein by the irradiation step (b)

Green functions and Langevin equations for nonlinear diffusion equations: A comment on ‘Markov processes, Hurst exponents, and nonlinear diffusion equations’ by Bassler et al.

Science.gov (United States)

Frank, T. D.

2008-02-01

We discuss two central claims made in the study by Bassler et al. [K.E. Bassler, G.H. Gunaratne, J.L. McCauley, Physica A 369 (2006) 343]. Bassler et al. claimed that Green functions and Langevin equations cannot be defined for nonlinear diffusion equations. In addition, they claimed that nonlinear diffusion equations are linear partial differential equations disguised as nonlinear ones. We review bottom-up and top-down approaches that have been used in the literature to derive Green functions for nonlinear diffusion equations and, in doing so, show that the first claim needs to be revised. We show that the second claim as well needs to be revised. To this end, we point out similarities and differences between non-autonomous linear Fokker-Planck equations and autonomous nonlinear Fokker-Planck equations. In this context, we raise the question whether Bassler et al.’s approach to financial markets is physically plausible because it necessitates the introduction of external traders and causes. Such external entities can easily be eliminated when taking self-organization principles and concepts of nonextensive thermostatistics into account and modeling financial processes by means of nonlinear Fokker-Planck equations.

Nonlinear dynamics of regenerative cutting processes-Comparison of two models

International Nuclear Information System (INIS)

Wang, X.S.; Hu, J.; Gao, J.B.

2006-01-01

Understanding the nonlinear dynamics of cutting processes is essential for the improvement of machining technology. We study machine cutting processes by two different models, one has been recently introduced by Litak [Litak G. Chaotic vibrations in a regenerative cutting process. Chaos, Solitons and Fractals 2002;13:1531-5] and the other is the classic delay differential equation model. Although chaotic solutions have been found in both models, well known routes to chaos, such as period-doubling or quasi-periodic motion to chaos are not observed in either model. Careful analysis shows that the chaotic motion from the Litak's model has sharper spectral peaks, a smaller correlation dimension and a smaller value for the largest positive Lyapunov exponent. Implications to the control of chaos in cutting processes are discussed

Nonlinear acoustic/seismic waves in earthquake processes

International Nuclear Information System (INIS)

Johnson, Paul A.

2012-01-01

Nonlinear dynamics induced by seismic sources and seismic waves are common in Earth. Observations range from seismic strong ground motion (the most damaging aspect of earthquakes), intense near-source effects, and distant nonlinear effects from the source that have important consequences. The distant effects include dynamic earthquake triggering—one of the most fascinating topics in seismology today—which may be elastically nonlinearly driven. Dynamic earthquake triggering is the phenomenon whereby seismic waves generated from one earthquake trigger slip events on a nearby or distant fault. Dynamic triggering may take place at distances thousands of kilometers from the triggering earthquake, and includes triggering of the entire spectrum of slip behaviors currently identified. These include triggered earthquakes and triggered slow, silent-slip during which little seismic energy is radiated. It appears that the elasticity of the fault gouge—the granular material located between the fault blocks—is key to the triggering phenomenon.

Parametric amplification and cascaded-nonlinearity processes in common atomic system.

Science.gov (United States)

Zheng, Huaibin; Zhang, Xun; Zhang, Zhaoyang; Tian, Yaling; Chen, Haixia; Li, Changbiao; Zhang, Yanpeng

2013-01-01

For the first time, we study the parametric amplification process of multi-wave mixing (PA-MWM) signal and cascaded-nonlinearity process (CNP) in sodium vapors both theoretically and experimentally, based on a conventional phase-conjugate MWM and a self-diffraction four-wave mixing (SD-FWM) processes, which are pumped by laser or amplified spontaneous emission (ASE), respectively. For laser pumping case, SD-FWM process serves as a quantum linear amplifier (a CNP) out (inside) of the resonant absorption region. While for ASE case, only the CNP occurs and the output linewidth is much narrower than that of the MWM signal due to the second selected effect of its electromagnetically induced transparency window. In addition, the phase-sensitive amplifying process seeded by two MWM processes is discussed for the first time. Theoretical fittings agree well with the experiment. The investigations have important potential applications in quantum communication.

Study of a multivariable nonlinear process by the phase space method

International Nuclear Information System (INIS)

Tomei, Alain

1969-02-01

This paper concerns the study of the properties of a multivariate nonlinear process using the phase space method. Based on the example of the Rapsodie reactor, a fast sodium reactor, the authors have established the simplified differential equations with the analogical study of partial differential equations (in order to replace them with ordinary differential equations), a mathematical study of dynamic properties and stability of the simplified model by the phase space method, and the verification of the model properties using an analog calculator. The reactor, with all its thermal circuits, has been considered as a nonlinear system with two inputs and one output (reactor power). The great stability of a fast reactor such as Rapsodie, in the normal operating conditions, has been verified. The same method could be applied to any other type of reactor

Nonlinear friction dynamics on polymer surface under accelerated movement

Directory of Open Access Journals (Sweden)

Yuuki Aita

2017-04-01

Full Text Available Nonlinear phenomena on the soft material surface are one of the most exciting topics of chemical physics. However, only a few reports exist on the friction phenomena under accelerated movement, because friction between two solid surfaces is considered a linear phenomenon in many cases. We aim to investigate how nonlinear accelerated motion affects friction on solid surfaces. In the present study, we evaluate the frictional forces between two polytetrafluoroethylene (PTFE resins using an advanced friction evaluation system. On PTFE surfaces, the normalized delay time δ, which is the time lag in the response of the friction force to the accelerated movement, is observed in the pre-sliding friction process. Under high-velocity conditions, kinetic friction increases with velocity. Based on these experimental results, we propose a two-phase nonlinear model including a pre-sliding process (from the beginning of sliding of a contact probe to the establishment of static friction and a kinetic friction process. The present model consists of several factors including velocity, acceleration, stiffness, viscosity, and vertical force. The findings reflecting the viscoelastic properties of soft material is useful for various fields such as in the fabrication of clothes, cosmetics, automotive materials, and virtual reality systems as well as for understanding friction phenomena on soft material surfaces.

Data-driven design of fault diagnosis systems nonlinear multimode processes

CERN Document Server

Haghani Abandan Sari, Adel

2014-01-01

In many industrial applications early detection and diagnosis of abnormal behavior of the plant is of great importance. During the last decades, the complexity of process plants has been drastically increased, which imposes great challenges in development of model-based monitoring approaches and it sometimes becomes unrealistic for modern large-scale processes. The main objective of Adel Haghani Abandan Sari is to study efficient fault diagnosis techniques for complex industrial systems using process historical data and considering the nonlinear behavior of the process. To this end, different methods are presented to solve the fault diagnosis problem based on the overall behavior of the process and its dynamics. Moreover, a novel technique is proposed for fault isolation and determination of the root-cause of the faults in the system, based on the fault impacts on the process measurements. Contents Process monitoring Fault diagnosis and fault-tolerant control Data-driven approaches and decision making Target...

Dynamical processes and epidemic threshold on nonlinear coupled multiplex networks

Science.gov (United States)

Gao, Chao; Tang, Shaoting; Li, Weihua; Yang, Yaqian; Zheng, Zhiming

2018-04-01

Recently, the interplay between epidemic spreading and awareness diffusion has aroused the interest of many researchers, who have studied models mainly based on linear coupling relations between information and epidemic layers. However, in real-world networks the relation between two layers may be closely correlated with the property of individual nodes and exhibits nonlinear dynamical features. Here we propose a nonlinear coupled information-epidemic model (I-E model) and present a comprehensive analysis in a more generalized scenario where the upload rate differs from node to node, deletion rate varies between susceptible and infected states, and infection rate changes between unaware and aware states. In particular, we develop a theoretical framework of the intra- and inter-layer dynamical processes with a microscopic Markov chain approach (MMCA), and derive an analytic epidemic threshold. Our results suggest that the change of upload and deletion rate has little effect on the diffusion dynamics in the epidemic layer.

Book of abstracts Chemical Engineering: IV All-Russian Conference on chemical engineering, All-Russian Youth Conference on chemical engineering, All-Russian school on chemical engineering for young scientists and specialists. Chemical engineering of nanomaterials. Energy- and resource-saving chemical-engineering processes and problems of their intensification. Processes and apparatuses of chemical engineering, chemical cybernetics. Ecological problems of chemical engineering and related fields

International Nuclear Information System (INIS)

Zakhodyaeva, Yu.A.; Belova, V.V.

2012-01-01

In the given volume of abstracts of the IV All-Russian Conference on chemical engineering, All-Russian Youth Conference on chemical engineering, All-Russian school on chemical engineering for young scientists and specialists (Moscow, March 18-23, 2012) there are the abstracts of the reports concerning chemical engineering of nanomaterials, energy- and resource-saving chemical-engineering processes, processes and apparatuses of chemical engineering, chemical cybernetics, ecological problems of chemical engineering and related fields. The abstracts deal with state-of-the-art and future development of theoretical and experimental investigations as well as with experience in practical realization of development works in the field of chemical engineering and relative areas [ru

Nonlinear digital signal processing in mental health: characterization of major depression using instantaneous entropy measures of heartbeat dynamics.

Science.gov (United States)

Valenza, Gaetano; Garcia, Ronald G; Citi, Luca; Scilingo, Enzo P; Tomaz, Carlos A; Barbieri, Riccardo

2015-01-01

Nonlinear digital signal processing methods that address system complexity have provided useful computational tools for helping in the diagnosis and treatment of a wide range of pathologies. More specifically, nonlinear measures have been successful in characterizing patients with mental disorders such as Major Depression (MD). In this study, we propose the use of instantaneous measures of entropy, namely the inhomogeneous point-process approximate entropy (ipApEn) and the inhomogeneous point-process sample entropy (ipSampEn), to describe a novel characterization of MD patients undergoing affective elicitation. Because these measures are built within a nonlinear point-process model, they allow for the assessment of complexity in cardiovascular dynamics at each moment in time. Heartbeat dynamics were characterized from 48 healthy controls and 48 patients with MD while emotionally elicited through either neutral or arousing audiovisual stimuli. Experimental results coming from the arousing tasks show that ipApEn measures are able to instantaneously track heartbeat complexity as well as discern between healthy subjects and MD patients. Conversely, standard heart rate variability (HRV) analysis performed in both time and frequency domains did not show any statistical significance. We conclude that measures of entropy based on nonlinear point-process models might contribute to devising useful computational tools for care in mental health.

Mammalian Cell Culture Process for Monoclonal Antibody Production: Nonlinear Modelling and Parameter Estimation

Directory of Open Access Journals (Sweden)

Dan Selişteanu

2015-01-01

Full Text Available Monoclonal antibodies (mAbs are at present one of the fastest growing products of pharmaceutical industry, with widespread applications in biochemistry, biology, and medicine. The operation of mAbs production processes is predominantly based on empirical knowledge, the improvements being achieved by using trial-and-error experiments and precedent practices. The nonlinearity of these processes and the absence of suitable instrumentation require an enhanced modelling effort and modern kinetic parameter estimation strategies. The present work is dedicated to nonlinear dynamic modelling and parameter estimation for a mammalian cell culture process used for mAb production. By using a dynamical model of such kind of processes, an optimization-based technique for estimation of kinetic parameters in the model of mammalian cell culture process is developed. The estimation is achieved as a result of minimizing an error function by a particle swarm optimization (PSO algorithm. The proposed estimation approach is analyzed in this work by using a particular model of mammalian cell culture, as a case study, but is generic for this class of bioprocesses. The presented case study shows that the proposed parameter estimation technique provides a more accurate simulation of the experimentally observed process behaviour than reported in previous studies.

Chemicals Industry New Process Chemistry Roadmap

Energy Technology Data Exchange (ETDEWEB)

none,

2000-08-01

The Materials Technology I workshop was held in November 1998 to address future research needs for materials technology that will support the chemical industry. Areas covered included disassembly, recovery, reuse and renewable technology; new materials; and materials measurement and characterization. The Materials Technology II workshop was held in September 1999 and covered additives, modeling and prediction and an additional segment on new materials. Materials Technology Institute (MTI) for the Chemical Process Industries, Inc. and Air Products & Chemicals lead the workshops. The Materials Technology Roadmap presents the results from both workshops.

When high working memory capacity is and is not beneficial for predicting nonlinear processes.

Science.gov (United States)

Fischer, Helen; Holt, Daniel V

2017-04-01

Predicting the development of dynamic processes is vital in many areas of life. Previous findings are inconclusive as to whether higher working memory capacity (WMC) is always associated with using more accurate prediction strategies, or whether higher WMC can also be associated with using overly complex strategies that do not improve accuracy. In this study, participants predicted a range of systematically varied nonlinear processes based on exponential functions where prediction accuracy could or could not be enhanced using well-calibrated rules. Results indicate that higher WMC participants seem to rely more on well-calibrated strategies, leading to more accurate predictions for processes with highly nonlinear trajectories in the prediction region. Predictions of lower WMC participants, in contrast, point toward an increased use of simple exemplar-based prediction strategies, which perform just as well as more complex strategies when the prediction region is approximately linear. These results imply that with respect to predicting dynamic processes, working memory capacity limits are not generally a strength or a weakness, but that this depends on the process to be predicted.

Stereodynamics: From elementary processes to macroscopic chemical reactions

Energy Technology Data Exchange (ETDEWEB)

Kasai, Toshio [Department of Chemistry, National Taiwan University, Taipei 106, Taiwan (China); Graduate School of Science, Department of Chemistry, Osaka University, Toyonaka, 560-0043 Osaka (Japan); Che, Dock-Chil [Graduate School of Science, Department of Chemistry, Osaka University, Toyonaka, 560-0043 Osaka (Japan); Tsai, Po-Yu [Department of Chemistry, National Taiwan University, Taipei 106, Taiwan (China); Department of Chemistry, National Chung Hsing University, Taichung 402, Taiwan (China); Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan (China); Lin, King-Chuen [Department of Chemistry, National Taiwan University, Taipei 106, Taiwan (China); Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan (China); Palazzetti, Federico [Scuola Normale Superiore, Pisa (Italy); Dipartimento di Chimica Biologia e Biotecnologie, Università di Perugia, 06123 Perugia (Italy); Aquilanti, Vincenzo [Dipartimento di Chimica Biologia e Biotecnologie, Università di Perugia, 06123 Perugia (Italy); Istituto di Struttura della Materia, Consiglio Nazionale delle Ricerche, Roma (Italy); Instituto de Fisica, Universidade Federal da Bahia, Salvador (Brazil)

2015-12-31

This paper aims at discussing new facets on stereodynamical behaviors in chemical reactions, i.e. the effects of molecular orientation and alignment on reactive processes. Further topics on macroscopic processes involving deviations from Arrhenius behavior in the temperature dependence of chemical reactions and chirality effects in collisions are also discussed.

Reflow process stabilization by chemical characteristics and process conditions

Science.gov (United States)

Kim, Myoung-Soo; Park, Jeong-Hyun; Kim, Hak-Joon; Kim, Il-Hyung; Jeon, Jae-Ha; Gil, Myung-Goon; Kim, Bong-Ho

2002-07-01

With the shrunken device rule below 130nm, the patterning of smaller contact hole with enough process margin is required for mass production. Therefore, shrinking technology using thermal reflow process has been applied for smaller contact hole formation. In this paper, we have investigated the effects of chemical characteristics such as molecular weight, blocking ratio of resin, cross-linker amount and solvent type with its composition to reflow process of resist and found the optimized chemical composition for reflow process applicable condition. And several process conditions like resist coating thickness and multi-step thermal reflow method have been also evaluated to stabilize the pattern profile and improve CD uniformity after reflow process. From the experiment results, it was confirmed that the effect of crosslinker in resist to reflow properties such as reflow temperature and reflow rate were very critical and it controlled the pattern profile during reflow processing. And also, it showed stable CD uniformity and improved resist properties for top loss, film shrinkage and etch selectivity. The application of lower coating thickness of resist induced symmetric pattern profile even at edge with wider process margin. The introduction of two-step baking method for reflow process showed uniform CD value, also. It is believed that the application of resist containing crosslinker and optimized process conditions for smaller contact hole patterning is necessary for the mass production with a design rule below 130nm.

Process Security in Chemical Engineering Education

Science.gov (United States)

Piluso, Cristina; Uygun, Korkut; Huang, Yinlun; Lou, Helen H.

2005-01-01

The threats of terrorism have greatly alerted the chemical process industries to assure plant security at all levels: infrastructure-improvement-focused physical security, information-protection-focused cyber security, and design-and-operation-improvement-focused process security. While developing effective plant security methods and technologies…

Improving subjective pattern recognition in chemical senses through reduction of nonlinear effects in evaluation of sparse data

Science.gov (United States)

Assadi, Amir H.; Rasouli, Firooz; Wrenn, Susan E.; Subbiah, M.

2002-11-01

Artificial neural network models are typically useful in pattern recognition and extraction of important features in large data sets. These models are implemented in a wide variety of contexts and with diverse type of input-output data. The underlying mathematics of supervised training of neural networks is ultimately tied to the ability to approximate the nonlinearities that are inherent in network"s generalization ability. The quality and availability of sufficient data points for training and validation play a key role in the generalization ability of the network. A potential domain of applications of neural networks is in analysis of subjective data, such as in consumer science, affective neuroscience and perception of chemical senses. In applications of ANN to subjective data, it is common to rely on knowledge of the science and context for data acquisition, for instance as a priori probabilities in the Bayesian framework. In this paper, we discuss the circumstances that create challenges for success of neural network models for subjective data analysis, such as sparseness of data and cost of acquisition of additional samples. In particular, in the case of affect and perception of chemical senses, we suggest that inherent ambiguity of subjective responses could be offset by a combination of human-machine expert. We propose a method of pre- and post-processing for blind analysis of data that that relies on heuristics from human performance in interpretation of data. In particular, we offer an information-theoretic smoothing (ITS) algorithm that optimizes that geometric visualization of multi-dimensional data and improves human interpretation of the input-output view of neural network implementations. The pre- and post-processing algorithms and ITS are unsupervised. Finally, we discuss the details of an example of blind data analysis from actual taste-smell subjective data, and demonstrate the usefulness of PCA in reduction of dimensionality, as well as ITS.

Noise-induced modulation of the relaxation kinetics around a non-equilibrium steady state of non-linear chemical reaction networks.

Science.gov (United States)

Ramaswamy, Rajesh; Sbalzarini, Ivo F; González-Segredo, Nélido

2011-01-28

Stochastic effects from correlated noise non-trivially modulate the kinetics of non-linear chemical reaction networks. This is especially important in systems where reactions are confined to small volumes and reactants are delivered in bursts. We characterise how the two noise sources confinement and burst modulate the relaxation kinetics of a non-linear reaction network around a non-equilibrium steady state. We find that the lifetimes of species change with burst input and confinement. Confinement increases the lifetimes of all species that are involved in any non-linear reaction as a reactant. Burst monotonically increases or decreases lifetimes. Competition between burst-induced and confinement-induced modulation may hence lead to a non-monotonic modulation. We quantify lifetime as the integral of the time autocorrelation function (ACF) of concentration fluctuations around a non-equilibrium steady state of the reaction network. Furthermore, we look at the first and second derivatives of the ACF, each of which is affected in opposite ways by burst and confinement. This allows discriminating between these two noise sources. We analytically derive the ACF from the linear Fokker-Planck approximation of the chemical master equation in order to establish a baseline for the burst-induced modulation at low confinement. Effects of higher confinement are then studied using a partial-propensity stochastic simulation algorithm. The results presented here may help understand the mechanisms that deviate stochastic kinetics from its deterministic counterpart. In addition, they may be instrumental when using fluorescence-lifetime imaging microscopy (FLIM) or fluorescence-correlation spectroscopy (FCS) to measure confinement and burst in systems with known reaction rates, or, alternatively, to correct for the effects of confinement and burst when experimentally measuring reaction rates.

Nonlinear analysis and control of a continuous fermentation process

DEFF Research Database (Denmark)

Szederkényi, G.; Kristensen, Niels Rode; Hangos, K.M

2002-01-01

Different types of nonlinear controllers are designed and compared for a simple continuous bioreactor operating near optimal productivity. This operating point is located close to a fold bifurcation point. Nonlinear analysis of stability, controllability and zero dynamics is used to investigate o...... are recommended for the simple fermenter. Passivity based controllers have been found to be globally stable, not very sensitive to the uncertainties in the reaction rate and controller parameter but they require full nonlinear state feedback....

Coupling between solute transport and chemical reactions models

International Nuclear Information System (INIS)

Samper, J.; Ajora, C.

1993-01-01

During subsurface transport, reactive solutes are subject to a variety of hydrodynamic and chemical processes. The major hydrodynamic processes include advection and convection, dispersion and diffusion. The key chemical processes are complexation including hydrolysis and acid-base reactions, dissolution-precipitation, reduction-oxidation, adsorption and ion exchange. The combined effects of all these processes on solute transport must satisfy the principle of conservation of mass. The statement of conservation of mass for N mobile species leads to N partial differential equations. Traditional solute transport models often incorporate the effects of hydrodynamic processes rigorously but oversimplify chemical interactions among aqueous species. Sophisticated chemical equilibrium models, on the other hand, incorporate a variety of chemical processes but generally assume no-flow systems. In the past decade, coupled models accounting for complex hydrological and chemical processes, with varying degrees of sophistication, have been developed. The existing models of reactive transport employ two basic sets of equations. The transport of solutes is described by a set of partial differential equations, and the chemical processes, under the assumption of equilibrium, are described by a set of nonlinear algebraic equations. An important consideration in any approach is the choice of primary dependent variables. Most existing models cannot account for the complete set of chemical processes, cannot be easily extended to include mixed chemical equilibria and kinetics, and cannot handle practical two and three dimensional problems. The difficulties arise mainly from improper selection of the primary variables in the transport equations. (Author) 38 refs

Dynamical interactions between solute and solvent studied by nonlinear infrared spectroscopy

International Nuclear Information System (INIS)

Ohta, K.; Tominaga, K.

2006-01-01

Interactions between solute and solvent play an important role in chemical reaction dynamics and in many relaxation processes in condensed phases. Recently third-order nonlinear infrared (IR) spectroscopy has shown to be useful to investigate solute-solvent interaction and dynamics of the vibrational transition. These studies provide detailed information on the energy relaxation of the vibrationally excited state, and the time scale and the magnitude of the time correlation functions of the vibrational frequency fluctuations. In this work we have studied vibrational energy relaxation (VER) of solutions and molecular complexes by nonlinear IR spectroscopy, especially IR pump-probe method, to understand the microscopic interactions in liquids. (authors)

A Model Predictive Algorithm for Active Control of Nonlinear Noise Processes

Directory of Open Access Journals (Sweden)

Qi-Zhi Zhang

2005-01-01

Full Text Available In this paper, an improved nonlinear Active Noise Control (ANC system is achieved by introducing an appropriate secondary source. For ANC system to be successfully implemented, the nonlinearity of the primary path and time delay of the secondary path must be overcome. A nonlinear Model Predictive Control (MPC strategy is introduced to deal with the time delay in the secondary path and the nonlinearity in the primary path of the ANC system. An overall online modeling technique is utilized for online secondary path and primary path estimation. The secondary path is estimated using an adaptive FIR filter, and the primary path is estimated using a Neural Network (NN. The two models are connected in parallel with the two paths. In this system, the mutual disturbances between the operation of the nonlinear ANC controller and modeling of the secondary can be greatly reduced. The coefficients of the adaptive FIR filter and weight vector of NN are adjusted online. Computer simulations are carried out to compare the proposed nonlinear MPC method with the nonlinear Filter-x Least Mean Square (FXLMS algorithm. The results showed that the convergence speed of the proposed nonlinear MPC algorithm is faster than that of nonlinear FXLMS algorithm. For testing the robust performance of the proposed nonlinear ANC system, the sudden changes in the secondary path and primary path of the ANC system are considered. Results indicated that the proposed nonlinear ANC system can rapidly track the sudden changes in the acoustic paths of the nonlinear ANC system, and ensure the adaptive algorithm stable when the nonlinear ANC system is time variable.

Experimental photonic generation of chirped pulses using nonlinear dispersion-based incoherent processing.

Science.gov (United States)

Rius, Manuel; Bolea, Mario; Mora, José; Ortega, Beatriz; Capmany, José

2015-05-18

We experimentally demonstrate, for the first time, a chirped microwave pulses generator based on the processing of an incoherent optical signal by means of a nonlinear dispersive element. Different capabilities have been demonstrated such as the control of the time-bandwidth product and the frequency tuning increasing the flexibility of the generated waveform compared to coherent techniques. Moreover, the use of differential detection improves considerably the limitation over the signal-to-noise ratio related to incoherent processing.

A novel joint-processing adaptive nonlinear equalizer using a modular recurrent neural network for chaotic communication systems.

Science.gov (United States)

Zhao, Haiquan; Zeng, Xiangping; Zhang, Jiashu; Liu, Yangguang; Wang, Xiaomin; Li, Tianrui

2011-01-01

To eliminate nonlinear channel distortion in chaotic communication systems, a novel joint-processing adaptive nonlinear equalizer based on a pipelined recurrent neural network (JPRNN) is proposed, using a modified real-time recurrent learning (RTRL) algorithm. Furthermore, an adaptive amplitude RTRL algorithm is adopted to overcome the deteriorating effect introduced by the nesting process. Computer simulations illustrate that the proposed equalizer outperforms the pipelined recurrent neural network (PRNN) and recurrent neural network (RNN) equalizers. Copyright © 2010 Elsevier Ltd. All rights reserved.

Quality Assessment of Film Processing Chemicals in Dentistry

International Nuclear Information System (INIS)

Han, Mi Ra; Kang, Byung Chul

1999-01-01

The purpose of this study was to compare the qualities of the four different processing chemicals (solutions). With EP 21 films (Ektaspeed plus film, Kodak Co., USA), nine unexposed and nine exposed films of a step wedge were processed utilizing automatic film processor (XR 24, Durr Co., Germany) for 5 days. During 5 days, the total number of processed films including out-patient's intraoral films were about 400-500 for each brand. Base plus fog density, film density, contrast of processed films were measured with densitometer (model 07-443 digital densitometer, Victoreen Co., USA). These measurements were analyzed for comparison. The results were as follows,1. For the base plus fog density, there was significant difference among the four chemicals (p<0.05). The sequence of the base plus fog densities was in ascending order by Kodak, X-dol 90, Agfa and Konica. 2. For the film density, all chemicals showed useful range of photographic densities (0.25-2.5). The sequence of the film densities was in ascending order by Kodak, X-dol 90, Konica and Agfa. But there was no statistically significant difference of film density between X-dol and Kodak (p<0.05). 3. The sequence of the contrasts was in ascending order by Konica, X-dol 90, Kodak and Agfa. But there was no statistically significant difference of contrast between X-dol and Konica (p<0.05). These results indicated that the four processing chemicals had the clinically useful film density and contrast, but only Kodak processing chemical had useful base plus fog density.

Process Design and Evaluation for Chemicals Based on Renewable Resources

DEFF Research Database (Denmark)

Fu, Wenjing

. In addition, another characteristic of chemicals based on renewable feedstocks is that many alternative technologies and possible routes exist, resulting in many possible process flowsheets. The challenge for process engineers is then to choose between possible process routes and alternative technologies...... development of chemicals based on renewable feedstocks. As an example, this thesis especially focuses on applying the methodology in process design and evaluation of the synthesis of 5-hydroxymethylfurfural (HMF) from the renewable feedstock glucose/fructose. The selected example is part of the chemoenzymatic......One of the key steps in process design is choosing between alternative technologies, especially for processes producing bulk and commodity chemicals. Recently, driven by the increasing oil prices and diminishing reserves, the production of bulk and commodity chemicals from renewable feedstocks has...

Chemical Etching, AFM, Laser Damage Threshold, and Nonlinear Optical Studies of Potential Nonlinear Optical Crystal: Bis (L-Glutamine Potassium Nitrate

Directory of Open Access Journals (Sweden)

Redrothu Hanumantharao

2013-01-01

Full Text Available A novel semiorganic nonlinear optical crystal bis (L-glutamine potassium nitrate (BGPN grown by slow evaporation technique at ambient temperature. The grown crystal surface has been analyzed by chemical etching and atomic force microscopy (AFM studies. Amplitude parameters like area roughness, roughness average, valley height, valley depth, peak height, and peak valley height were measured successfully from AFM studies. Etching studies were carried out by various solvents like water, methanol and ethanol. The etching study indicates the occurrence of different types of etch pit patterns like striations and steplike pattern. The laser damage threshold energy has been measured by irradiating laser beam using a Q-switched Nd: YAG laser (1064 nm. Second harmonic generation (SHG studies have been performed by famous Kurtz powder technique with reference to standard potassium dihydrogen phosphate single crystals (KDP. It is found from this technique that SHG efficiency of BGPN is in comparison to that of standard KDP crystals.

Bubble nonlinear dynamics and stimulated scattering process

Science.gov (United States)

Jie, Shi; De-Sen, Yang; Sheng-Guo, Shi; Bo, Hu; Hao-Yang, Zhang; Shi-Yong, Hu

2016-02-01

A complete understanding of the bubble dynamics is deemed necessary in order to achieve their full potential applications in industry and medicine. For this purpose it is first needed to expand our knowledge of a single bubble behavior under different possible conditions including the frequency and pressure variations of the sound field. In addition, stimulated scattering of sound on a bubble is a special effect in sound field, and its characteristics are associated with bubble oscillation mode. A bubble in liquid can be considered as a representative example of nonlinear dynamical system theory with its resonance, and its dynamics characteristics can be described by the Keller-Miksis equation. The nonlinear dynamics of an acoustically excited gas bubble in water is investigated by using theoretical and numerical analysis methods. Our results show its strongly nonlinear behavior with respect to the pressure amplitude and excitation frequency as the control parameters, and give an intuitive insight into stimulated sound scattering on a bubble. It is seen that the stimulated sound scattering is different from common dynamical behaviors, such as bifurcation and chaos, which is the result of the nonlinear resonance of a bubble under the excitation of a high amplitude acoustic sound wave essentially. The numerical analysis results show that the threshold of stimulated sound scattering is smaller than those of bifurcation and chaos in the common condition. Project supported by the Program for Changjiang Scholars and Innovative Research Team in University, China (Grant No. IRT1228) and the Young Scientists Fund of the National Natural Science Foundation of China (Grant Nos. 11204050 and 11204049).

Self-Organized Biological Dynamics and Nonlinear Control

Science.gov (United States)

Walleczek, Jan

2006-04-01

The frontiers and challenges of biodynamics research Jan Walleczek; Part I. Nonlinear Dynamics in Biology and Response to Stimuli: 1. External signals and internal oscillation dynamics - principal aspects and response of stimulated rhythmic processes Friedemann Kaiser; 2. Nonlinear dynamics in biochemical and biophysical systems: from enzyme kinetics to epilepsy Raima Larter, Robert Worth and Brent Speelman; 3. Fractal mechanisms in neural control: human heartbeat and gait dynamics in health and disease Chung-Kang Peng, Jeffrey M. Hausdorff and Ary L. Goldberger; 4. Self-organising dynamics in human coordination and perception Mingzhou Ding, Yanqing Chen, J. A. Scott Kelso and Betty Tuller; 5. Signal processing in biochemical reaction networks Adam P. Arkin; Part II. Nonlinear Sensitivity of Biological Systems to Electromagnetic Stimuli: 6. Electrical signal detection and noise in systems with long-range coherence Paul C. Gailey; 7. Oscillatory signals in migrating neutrophils: effects of time-varying chemical and electrical fields Howard R. Petty; 8. Enzyme kinetics and nonlinear biochemical amplification in response to static and oscillating magnetic fields Jan Walleczek and Clemens F. Eichwald; 9. Magnetic field sensitivity in the hippocampus Stefan Engström, Suzanne Bawin and W. Ross Adey; Part III. Stochastic Noise-Induced Dynamics and Transport in Biological Systems: 10. Stochastic resonance: looking forward Frank Moss; 11. Stochastic resonance and small-amplitude signal transduction in voltage-gated ion channels Sergey M. Bezrukov and Igor Vodyanoy; 12. Ratchets, rectifiers and demons: the constructive role of noise in free energy and signal transduction R. Dean Astumian; 13. Cellular transduction of periodic and stochastic energy signals by electroconformational coupling Tian Y. Tsong; Part IV. Nonlinear Control of Biological and Other Excitable Systems: 14. Controlling chaos in dynamical systems Kenneth Showalter; 15. Electromagnetic fields and biological

Generalized Nonlinear Yule Models

OpenAIRE

Lansky, Petr; Polito, Federico; Sacerdote, Laura

2016-01-01

With the aim of considering models with persistent memory we propose a fractional nonlinear modification of the classical Yule model often studied in the context of macrovolution. Here the model is analyzed and interpreted in the framework of the development of networks such as the World Wide Web. Nonlinearity is introduced by replacing the linear birth process governing the growth of the in-links of each specific webpage with a fractional nonlinear birth process with completely general birth...

Nonlinearities in Drug Release Process from Polymeric Microparticles: Long-Time-Scale Behaviour

Directory of Open Access Journals (Sweden)

Elena Simona Bacaita

2012-01-01

Full Text Available A theoretical model of the drug release process from polymeric microparticles (a particular type of polymer matrix, through dispersive fractal approximation of motion, is built. As a result, the drug release process takes place through cnoidal oscillations modes of a normalized concentration field. This indicates that, in the case of long-time-scale evolutions, the drug particles assemble in a lattice of nonlinear oscillators occur macroscopically, through variations of drug concentration. The model is validated by experimental results.

Advanced Ultrafast Spectroscopy for Chemical Detection of Nuclear Fuel Cycle Materials

International Nuclear Information System (INIS)

Villa-Aleman, E.; Houk, A.; Spencer, W.

2017-01-01

The development of new signatures and observables from processes related to proliferation activities are often related to the development of technologies. In our physical world, the intensity of observables is linearly related to the input drivers (light, current, voltage, etc.). Ultrafast lasers with high peak energies, opens the door to a new regime where the intensity of the observables is not necessarily linear with the laser energy. Potential nonlinear spectroscopic applications include chemical detection via remote sensing through filament generation, material characterization and processing, chemical reaction specificity, surface phenomena modifications, X-ray production, nuclear fusion, etc. The National Security Directorate laser laboratory is currently working to develop new tools for nonproliferation research with femtosecond and picosecond lasers. Prior to this project, we could only achieve laser energies in the 5 nano-Joule range, preventing the study of nonlinear phenomena. To advance our nonproliferation research into the nonlinear regime we require laser pulses in the milli-Joule (mJ) energy range. We have procured and installed a 35 fs-7 mJ laser, operating at one-kilohertz repetition rate, to investigate elemental and molecular detection of materials in the laboratory with potential applications in remote sensing. Advanced, nonlinear Raman techniques will be used to study materials of interest that are in a matrix of many materials and currently with these nonlinear techniques we can achieve greater than three orders of magnitude signal enhancement. This work studying nuclear fuel cycle materials with nonlinear spectroscopies will advance SRNL research capabilities and grow a core capability within the DOE complex.

Advanced Ultrafast Spectroscopy for Chemical Detection of Nuclear Fuel Cycle Materials

Energy Technology Data Exchange (ETDEWEB)

Villa-Aleman, E. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Houk, A. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Spencer, W. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2017-09-29

The development of new signatures and observables from processes related to proliferation activities are often related to the development of technologies. In our physical world, the intensity of observables is linearly related to the input drivers (light, current, voltage, etc.). Ultrafast lasers with high peak energies, opens the door to a new regime where the intensity of the observables is not necessarily linear with the laser energy. Potential nonlinear spectroscopic applications include chemical detection via remote sensing through filament generation, material characterization and processing, chemical reaction specificity, surface phenomena modifications, X-ray production, nuclear fusion, etc. The National Security Directorate laser laboratory is currently working to develop new tools for nonproliferation research with femtosecond and picosecond lasers. Prior to this project, we could only achieve laser energies in the 5 nano-Joule range, preventing the study of nonlinear phenomena. To advance our nonproliferation research into the nonlinear regime we require laser pulses in the milli-Joule (mJ) energy range. We have procured and installed a 35 fs-7 mJ laser, operating at one-kilohertz repetition rate, to investigate elemental and molecular detection of materials in the laboratory with potential applications in remote sensing. Advanced, nonlinear Raman techniques will be used to study materials of interest that are in a matrix of many materials and currently with these nonlinear techniques we can achieve greater than three orders of magnitude signal enhancement. This work studying nuclear fuel cycle materials with nonlinear spectroscopies will advance SRNL research capabilities and grow a core capability within the DOE complex.

Identification of low order models for large scale processes

NARCIS (Netherlands)

Wattamwar, S.K.

2010-01-01

Many industrial chemical processes are complex, multi-phase and large scale in nature. These processes are characterized by various nonlinear physiochemical effects and fluid flows. Such processes often show coexistence of fast and slow dynamics during their time evolutions. The increasing demand

Environmentally benign chemical synthesis and processing

International Nuclear Information System (INIS)

Hancock, K.G.

1992-01-01

A new era of university-industry-government partnership is required to address the intertwined problems of industrial economic competitiveness and environmental quality. Chemicals that go up the stacks and down the drains are simultaneously a serious detriment to the environment, a waste of natural resources, and a threat to industrial profitability. Recently, the NSF Divisions of Chemistry and chemical and Thermal Systems have joined with the Council for Chemical research in a new grant program to reduce pollution at the source by underwriting research aimed at environmentally benign chemical synthesis and processing. Part of a broader NSF initiative on environmental science research, this new program serves as a model for university-industry-government joint action and technology transfer. Other features of this program and related activities will be described in this paper

Energy conversion technology by chemical processes

Energy Technology Data Exchange (ETDEWEB)

Oh, I W; Yoon, K S; Cho, B W [Korea Inst. of Science and Technology, Seoul (Korea, Republic of); and others

1996-12-01

The sharp increase in energy usage according to the industry development has resulted in deficiency of energy resources and severe pollution problems. Therefore, development of the effective way of energy usage and energy resources of low pollution is needed. Development of the energy conversion technology by chemical processes is also indispensable, which will replace the pollutant-producing and inefficient mechanical energy conversion technologies. Energy conversion technology by chemical processes directly converts chemical energy to electrical one, or converts heat energy to chemical one followed by heat storage. The technology includes batteries, fuel cells, and energy storage system. The are still many problems on performance, safety, and manufacturing of the secondary battery which is highly demanded in electronics, communication, and computer industries. To overcome these problems, key components such as carbon electrode, metal oxide electrode, and solid polymer electrolyte are developed in this study, followed by the fabrication of the lithium secondary battery. Polymer electrolyte fuel cell, as an advanced power generating apparatus with high efficiency, no pollution, and no noise, has many applications such as zero-emission vehicles, on-site power plants, and military purposes. After fabricating the cell components and operating the single cells, the fundamental technologies in polymer electrolyte fuel cell are established in this study. Energy storage technology provides the safe and regular heat energy, irrespective of the change of the heat energy sources, adjusts time gap between consumption and supply, and upgrades and concentrates low grade heat energy. In this study, useful chemical reactions for efficient storage and transport are investigated and the chemical heat storage technology are developed. (author) 41 refs., 90 figs., 20 tabs.

Perturbation and characterization of nonlinear processes: Progress report, November 15, 1983-June 1, 1987

International Nuclear Information System (INIS)

Swinney, H.L.; Swift, J.

1987-01-01

This progress report summarizes the principal accomplishments dealing with perturbation and characterization of nonlinear processes. Topics of research include Lyapunov equations, mutual information and metric entropy, the dimensions, complex dynamics and transition sequences and spatial patterns

NONLINEAR REFLECTION PROCESS OF LINEARLY POLARIZED, BROADBAND ALFVÉN WAVES IN THE FAST SOLAR WIND

Energy Technology Data Exchange (ETDEWEB)

Shoda, M.; Yokoyama, T., E-mail: shoda@eps.s.u-tokyo.ac.jp [Department of Earth and Planetary Science, The University of Tokyo, Bunkyo-ku, Tokyo 113-0033 (Japan)

2016-04-01

Using one-dimensional numerical simulations, we study the elementary process of Alfvén wave reflection in a uniform medium, including nonlinear effects. In the linear regime, Alfvén wave reflection is triggered only by the inhomogeneity of the medium, whereas in the nonlinear regime, it can occur via nonlinear wave–wave interactions. Such nonlinear reflection (backscattering) is typified by decay instability. In most studies of decay instabilities, the initial condition has been a circularly polarized Alfvén wave. In this study we consider a linearly polarized Alfvén wave, which drives density fluctuations by its magnetic pressure force. For generality, we also assume a broadband wave with a red-noise spectrum. In the data analysis, we decompose the fluctuations into characteristic variables using local eigenvectors, thus revealing the behaviors of the individual modes. Different from the circular-polarization case, we find that the wave steepening produces a new energy channel from the parent Alfvén wave to the backscattered one. Such nonlinear reflection explains the observed increasing energy ratio of the sunward to the anti-sunward Alfvénic fluctuations in the solar wind with distance against the dynamical alignment effect.

A numerical analysis for non-linear radiation in MHD flow around a cylindrical surface with chemically reactive species

Directory of Open Access Journals (Sweden)

Junaid Ahmad Khan

2018-03-01

Full Text Available Boundary layer flow around a stretchable rough cylinder is modeled by taking into account boundary slip and transverse magnetic field effects. The main concern is to resolve heat/mass transfer problem considering non-linear radiative heat transfer and temperature/concentration jump aspects. Using conventional similarity approach, the equations of motion and heat transfer are converted into a boundary value problem whose solution is computed by shooting method for broad range of slip coefficients. The proposed numerical scheme appears to improve as the strengths of magnetic field and slip coefficients are enhanced. Axial velocity and temperature are considerably influenced by a parameter M which is inversely proportional to the radius of cylinder. A significant change in temperature profile is depicted for growing wall to ambient temperature ratio. Relevant physical quantities such as wall shear stress, local Nusselt number and local Sherwood number are elucidated in detail. Keywords: Stretchable boundary, Thermal radiation, Chemical reaction, Mathematical modeling, Non-linear differential system, Mass transfer

Parametric Phase-sensitive and Phase-insensitive All-optical Signal Processing on Multiple Nonlinear Platforms - Invited talk

DEFF Research Database (Denmark)

Peucheret, Christophe; Da Ros, Francesco; Vukovic, Dragana

Parametric processes in materials presenting a second- or third-order nonlinearity have been widely used to demonstrate a wide range of all-optical signal processing functionalities, including amplication, wavelength conversion, regeneration, sampling, switching, modulation format conver- sion, o...

Noise-induced modulation of the relaxation kinetics around a non-equilibrium steady state of non-linear chemical reaction networks.

Directory of Open Access Journals (Sweden)

Rajesh Ramaswamy

2011-01-01

Full Text Available Stochastic effects from correlated noise non-trivially modulate the kinetics of non-linear chemical reaction networks. This is especially important in systems where reactions are confined to small volumes and reactants are delivered in bursts. We characterise how the two noise sources confinement and burst modulate the relaxation kinetics of a non-linear reaction network around a non-equilibrium steady state. We find that the lifetimes of species change with burst input and confinement. Confinement increases the lifetimes of all species that are involved in any non-linear reaction as a reactant. Burst monotonically increases or decreases lifetimes. Competition between burst-induced and confinement-induced modulation may hence lead to a non-monotonic modulation. We quantify lifetime as the integral of the time autocorrelation function (ACF of concentration fluctuations around a non-equilibrium steady state of the reaction network. Furthermore, we look at the first and second derivatives of the ACF, each of which is affected in opposite ways by burst and confinement. This allows discriminating between these two noise sources. We analytically derive the ACF from the linear Fokker-Planck approximation of the chemical master equation in order to establish a baseline for the burst-induced modulation at low confinement. Effects of higher confinement are then studied using a partial-propensity stochastic simulation algorithm. The results presented here may help understand the mechanisms that deviate stochastic kinetics from its deterministic counterpart. In addition, they may be instrumental when using fluorescence-lifetime imaging microscopy (FLIM or fluorescence-correlation spectroscopy (FCS to measure confinement and burst in systems with known reaction rates, or, alternatively, to correct for the effects of confinement and burst when experimentally measuring reaction rates.

Rock fracture processes in chemically reactive environments

Science.gov (United States)

Eichhubl, P.

2015-12-01

Rock fracture is traditionally viewed as a brittle process involving damage nucleation and growth in a zone ahead of a larger fracture, resulting in fracture propagation once a threshold loading stress is exceeded. It is now increasingly recognized that coupled chemical-mechanical processes influence fracture growth in wide range of subsurface conditions that include igneous, metamorphic, and geothermal systems, and diagenetically reactive sedimentary systems with possible applications to hydrocarbon extraction and CO2 sequestration. Fracture processes aided or driven by chemical change can affect the onset of fracture, fracture shape and branching characteristics, and fracture network geometry, thus influencing mechanical strength and flow properties of rock systems. We are investigating two fundamental modes of chemical-mechanical interactions associated with fracture growth: 1. Fracture propagation may be aided by chemical dissolution or hydration reactions at the fracture tip allowing fracture propagation under subcritical stress loading conditions. We are evaluating effects of environmental conditions on critical (fracture toughness KIc) and subcritical (subcritical index) fracture properties using double torsion fracture mechanics tests on shale and sandstone. Depending on rock composition, the presence of reactive aqueous fluids can increase or decrease KIc and/or subcritical index. 2. Fracture may be concurrent with distributed dissolution-precipitation reactions in the hostrock beyond the immediate vicinity of the fracture tip. Reconstructing the fracture opening history recorded in crack-seal fracture cement of deeply buried sandstone we find that fracture length growth and fracture opening can be decoupled, with a phase of initial length growth followed by a phase of dominant fracture opening. This suggests that mechanical crack-tip failure processes, possibly aided by chemical crack-tip weakening, and distributed solution-precipitation creep in the

Nonlinear theory of diffusive acceleration of particles by shock waves

Energy Technology Data Exchange (ETDEWEB)

Malkov, M.A. [University of California at San Diego, La Jolla, CA (United States)]. E-mail: mmalkov@ucsd.edu; Drury, L. O' C. [Dublin Institute for Advanced Studies, 5 Merrion Square, Dublin 2 (Ireland)

2001-04-01

Among the various acceleration mechanisms which have been suggested as responsible for the nonthermal particle spectra and associated radiation observed in many astrophysical and space physics environments, diffusive shock acceleration appears to be the most successful. We review the current theoretical understanding of this process, from the basic ideas of how a shock energizes a few reactionless particles to the advanced nonlinear approaches treating the shock and accelerated particles as a symbiotic self-organizing system. By means of direct solution of the nonlinear problem we set the limit to the test-particle approximation and demonstrate the fundamental role of nonlinearity in shocks of astrophysical size and lifetime. We study the bifurcation of this system, proceeding from the hydrodynamic to kinetic description under a realistic condition of Bohm diffusivity. We emphasize the importance of collective plasma phenomena for the global flow structure and acceleration efficiency by considering the injection process, an initial stage of acceleration and, the related aspects of the physics of collisionless shocks. We calculate the injection rate for different shock parameters and different species. This, together with differential acceleration resulting from nonlinear large-scale modification, determines the chemical composition of accelerated particles. The review concentrates on theoretical and analytical aspects but our strategic goal is to link the fundamental theoretical ideas with the rapidly growing wealth of observational data. (author)

Method for innovative synthesis-design of chemical process flowsheets

DEFF Research Database (Denmark)

Kumar Tula, Anjan; Gani, Rafiqul

Chemical process synthesis-design involve the identification of the processing route to reach a desired product from a specified set of raw materials, design of the operations involved in the processing route, the calculations of utility requirements, the calculations of waste and emission...... to the surrounding and many more. Different methods (knowledge-based [1], mathematical programming [2], hybrid, etc.) have been proposed and are also currently employed to solve these synthesis-design problems. D’ Anterroches [3] proposed a group contribution based approach to solve the synthesis-design problem...... of chemical processes, where, chemical process flowsheets could be synthesized in the same way as atoms or groups of atoms are synthesized to form molecules in computer aided molecular design (CAMD) techniques [4]. That, from a library of building blocks (functional process-groups) and a set of rules to join...

Neurobiologically Inspired Approaches to Nonlinear Process Control and Modeling

Science.gov (United States)

1999-12-31

incorporates second messenger reaction kinetics and calcium dynamics to represent the nonlinear dynamics and the crucial role of neuromodulation in local...reflex). The dynamic neuromodulation as a mechanism for the nonlinear attenuation is the novel result of this study. Ear- lier simulations have shown

Systematic methods for synthesis and design of sustainable chemical and biochemical processes

DEFF Research Database (Denmark)

Gani, Rafiqul

Chemical and biochemical process design consists of designing the process that can sustainably manufacture an identified chemical product through a chemical or biochemical route. The chemical product tree is potentially very large; starting from a set of basic raw materials (such as petroleum...... for process intensification, sustainable process design, identification of optimal biorefinery models as well as integrated process-control design, and chemical product design. The lecture will present the main concepts, the decomposition based solution approach, the developed methods and tools together...

Third Conference on nonlinear science and complexity (NSC)

CERN Document Server

Machado, José; Baleanu, Dumitru; Dynamical Systems and Methods

2012-01-01

Nonlinear Systems and Methods For Mechanical, Electrical and Biosystems presents topics observed at the 3rd Conference on Nonlinear Science and Complexity(NSC), focusing on energy transfer and synchronization in hybrid nonlinear systems. The studies focus on fundamental theories and principles,analytical and symbolic approaches, computational techniques in nonlinear physical science and mathematics. Broken into three parts, the text covers:\\ Parametrical excited pendulum, nonlinear dynamics in hybrid systems, dynamical system synchronization and (N+1) body dynamics as well as new views different from the existing results in nonlinear dynamics. Mathematical methods for dynamical systems including conservation laws, dynamical symmetry in nonlinear differential equations and invex energies. Nonlinear phenomena in physical problems such as solutions, complex flows, chemical kinetics, Toda lattices and parallel manipulator. This book is useful to scholars, researchers and advanced technical members of industrial l...

The chemistry and physics of nonlinear optical materials

International Nuclear Information System (INIS)

Velsko, S.P.; Eimerl, D.

1989-01-01

Recent efforts to engineer new nonlinear optical materials with specific desired characteristics has engendered a need for a theoretical description of optical properties which is readily accessible to chemists, yet correctly treats the essential physics of dielectric response. This paper describes a simple empirical molecular orbital model which gives useful insights into the relationship between chemical composition, crystalline structure, and optical susceptibilities. The authors compare the probabilities of finding new harmonic generators in various chemical classes. Rigorous bounds on the magnitudes of linear and nonlinear optical coefficients and their anisotropies are also discussed

Corner-point criterion for assessing nonlinear image processing imagers

Science.gov (United States)

Landeau, Stéphane; Pigois, Laurent; Foing, Jean-Paul; Deshors, Gilles; Swiathy, Greggory

2017-10-01

Range performance modeling of optronics imagers attempts to characterize the ability to resolve details in the image. Today, digital image processing is systematically used in conjunction with the optoelectronic system to correct its defects or to exploit tiny detection signals to increase performance. In order to characterize these processing having adaptive and non-linear properties, it becomes necessary to stimulate the imagers with test patterns whose properties are similar to the actual scene image ones, in terms of dynamic range, contours, texture and singular points. This paper presents an approach based on a Corner-Point (CP) resolution criterion, derived from the Probability of Correct Resolution (PCR) of binary fractal patterns. The fundamental principle lies in the respectful perception of the CP direction of one pixel minority value among the majority value of a 2×2 pixels block. The evaluation procedure considers the actual image as its multi-resolution CP transformation, taking the role of Ground Truth (GT). After a spatial registration between the degraded image and the original one, the degradation is statistically measured by comparing the GT with the degraded image CP transformation, in terms of localized PCR at the region of interest. The paper defines this CP criterion and presents the developed evaluation techniques, such as the measurement of the number of CP resolved on the target, the transformation CP and its inverse transform that make it possible to reconstruct an image of the perceived CPs. Then, this criterion is compared with the standard Johnson criterion, in the case of a linear blur and noise degradation. The evaluation of an imaging system integrating an image display and a visual perception is considered, by proposing an analysis scheme combining two methods: a CP measurement for the highly non-linear part (imaging) with real signature test target and conventional methods for the more linear part (displaying). The application to

Insight into the effect of screw dislocations and oxygen vacancy defects on the optical nonlinear refraction response in chemically grown ZnO/Al2O3 films

Science.gov (United States)

Agrawal, Arpana; Saroj, Rajendra K.; Dar, Tanveer A.; Baraskar, Priyanka; Sen, Pratima; Dhar, Subhabrata

2017-11-01

We report the effect of screw dislocations and oxygen vacancy defects on the optical nonlinear refraction response of ZnO films grown on a sapphire substrate at various oxygen flow rates using the chemical vapor deposition technique. The nonlinear refraction response was investigated in the off-resonant regime using a CW He-Ne laser source to examine the role of the intermediate bandgap states. It has been observed that the structural defects strongly influence the optical nonlinearity in the off-resonant regime. Nonlinearity has been found to improve as the oxygen flow rate is lowered from 2 sccm to 0.3 sccm. From photoluminescence studies, we observe that the enhanced defect density of the electronic defect levels due to the increased concentration of structural defects (with the decrease in the oxygen flow rate) is responsible for this improved optical nonlinearity along with the thermal effect. This suggests that defect engineering is an effective way to tailor the nonlinearity of ZnO films and their utility for optoelectronic device applications.

The Havriliak-Negami susceptibility as a nonlinear and nonlocal process

International Nuclear Information System (INIS)

Miskinis, Paulius

2009-01-01

A theoretical substantiation of the Cole-Cole, Cole-Davidson and Havriliak-Negami types of susceptibilities is presented. These types of susceptibility are shown to be a manifestation of weak nonlocality and nonlinearity. The Debye susceptibility corresponds to linear and local relaxation, the Cole-Cole susceptibility being linear and nonlocal; the Cole-Davidson susceptibility is nonlinear and local and the Havriliak-Negami susceptibility corresponds to nonlinear and nonlocal relaxation.

ACToR Chemical Structure processing using Open Source ...

Science.gov (United States)

ACToR (Aggregated Computational Toxicology Resource) is a centralized database repository developed by the National Center for Computational Toxicology (NCCT) at the U.S. Environmental Protection Agency (EPA). Free and open source tools were used to compile toxicity data from over 1,950 public sources. ACToR contains chemical structure information and toxicological data for over 558,000 unique chemicals. The database primarily includes data from NCCT research programs, in vivo toxicity data from ToxRef, human exposure data from ExpoCast, high-throughput screening data from ToxCast and high quality chemical structure information from the EPA DSSTox program. The DSSTox database is a chemical structure inventory for the NCCT programs and currently has about 16,000 unique structures. Included are also data from PubChem, ChemSpider, USDA, FDA, NIH and several other public data sources. ACToR has been a resource to various international and national research groups. Most of our recent efforts on ACToR are focused on improving the structural identifiers and Physico-Chemical properties of the chemicals in the database. Organizing this huge collection of data and improving the chemical structure quality of the database has posed some major challenges. Workflows have been developed to process structures, calculate chemical properties and identify relationships between CAS numbers. The Structure processing workflow integrates web services (PubChem and NIH NCI Cactus) to d

Dynamics of a photorefractive response and competition of nonlinear processes in self-pumping double phase-conjugate mirrors

International Nuclear Information System (INIS)

Mogaddam, Mehran Wahdani; Shuvalov, Vladimir V

2005-01-01

The dynamics of formation of a nonlinear response of a double phase-conjugate (PC) BaTiO 3 mirror is calculated. It is shown that because of competition between processes of different types (related to the presence of several PC channels, the local and nonlocal components of the photorefractive nonlinearity), the transient and dynamic lasing regimes for this mirror can be substantially different. It is found that the development of lasing begins with the successive formation and phasing of dynamic holograms of two different types (two PC channels). It is shown that even under optimal conditions, the lasing regime is not stationary due to competition between processes of different types, and the parameters of output fields fluctuate in time in a nontrivial way (due to the presence of the in-phase and out-of-phase components). Several scenarios of transition to the dynamic chaos are described. (nonlinear optical phenomena)

New Vistas in Chemical Product and Process Design

DEFF Research Database (Denmark)

Zhang, Lei; Babi, Deenesh Kavi; Gani, Rafiqul

2016-01-01

Design of chemicals-based products is broadly classified into those that are process centered and those that are product centered. In this article, the designs of both classes of products are reviewed from a process systems point of view; developments related to the design of the chemical product......, its corresponding process, and its integration are highlighted. Although significant advances have been made in the development of systematic model-based techniques for process design (also for optimization, operation, and control), much work is needed to reach the same level for product design....... Timeline diagrams illustrating key contributions in product design, process design, and integrated product-process design are presented. The search for novel, innovative, and sustainable solutions must be matched by consideration of issues related to the multidisciplinary nature of problems, the lack...

Sustainable Chemical Processes and Products. New Design Methodology and Design Tools

OpenAIRE

Korevaar, G.

2004-01-01

The current chemical industry is not sustainable, which leads to the fact that innovation of chemical processes and products is too often hazardous for society in general and the environment in particular. It really is a challenge to implement sustainability considerations in the design activities of chemical engineers. Therefore, the main question of this thesis is: how can a trained chemical engineer develop a conceptual design of a chemical process or a chemical product in such a way that ...

Chemical kinetics and oil shale process design

Energy Technology Data Exchange (ETDEWEB)

Burnham, A.K.

1993-07-01

Oil shale processes are reviewed with the goal of showing how chemical kinetics influences the design and operation of different processes for different types of oil shale. Reaction kinetics are presented for organic pyrolysis, carbon combustion, carbonate decomposition, and sulfur and nitrogen reactions.

Linear and Nonlinear Impairment Compensation in Coherent Optical Transmission with Digital Signal Processing

DEFF Research Database (Denmark)

Porto da Silva, Edson

Digital signal processing (DSP) has become one of the main enabling technologies for the physical layer of coherent optical communication networks. The DSP subsystems are used to implement several functionalities in the digital domain, from synchronization to channel equalization. Flexibility...... nonlinearity compensation, (II) spectral shaping, and (III) adaptive equalization. For (I), original contributions are presented to the study of the nonlinearity compensation (NLC) with digital backpropagation (DBP). Numerical and experimental performance investigations are shown for different application...... scenarios. Concerning (II), it is demonstrated how optical and electrical (digital) pulse shaping can be allied to improve the spectral confinement of a particular class of optical time-division multiplexing (OTDM) signals that can be used as a building block for fast signaling single-carrier transceivers...

Idaho Chemical Processing Plant Process Efficiency improvements

International Nuclear Information System (INIS)

Griebenow, B.

1996-03-01

In response to decreasing funding levels available to support activities at the Idaho Chemical Processing Plant (ICPP) and a desire to be cost competitive, the Department of Energy Idaho Operations Office (DOE-ID) and Lockheed Idaho Technologies Company have increased their emphasis on cost-saving measures. The ICPP Effectiveness Improvement Initiative involves many activities to improve cost effectiveness and competitiveness. This report documents the methodology and results of one of those cost cutting measures, the Process Efficiency Improvement Activity. The Process Efficiency Improvement Activity performed a systematic review of major work processes at the ICPP to increase productivity and to identify nonvalue-added requirements. A two-phase approach was selected for the activity to allow for near-term implementation of relatively easy process modifications in the first phase while obtaining long-term continuous improvement in the second phase and beyond. Phase I of the initiative included a concentrated review of processes that had a high potential for cost savings with the intent of realizing savings in Fiscal Year 1996 (FY-96.) Phase II consists of implementing long-term strategies too complex for Phase I implementation and evaluation of processes not targeted for Phase I review. The Phase II effort is targeted for realizing cost savings in FY-97 and beyond

Embedded algorithms within an FPGA-based system to process nonlinear time series data

Science.gov (United States)

Jones, Jonathan D.; Pei, Jin-Song; Tull, Monte P.

2008-03-01

This paper presents some preliminary results of an ongoing project. A pattern classification algorithm is being developed and embedded into a Field-Programmable Gate Array (FPGA) and microprocessor-based data processing core in this project. The goal is to enable and optimize the functionality of onboard data processing of nonlinear, nonstationary data for smart wireless sensing in structural health monitoring. Compared with traditional microprocessor-based systems, fast growing FPGA technology offers a more powerful, efficient, and flexible hardware platform including on-site (field-programmable) reconfiguration capability of hardware. An existing nonlinear identification algorithm is used as the baseline in this study. The implementation within a hardware-based system is presented in this paper, detailing the design requirements, validation, tradeoffs, optimization, and challenges in embedding this algorithm. An off-the-shelf high-level abstraction tool along with the Matlab/Simulink environment is utilized to program the FPGA, rather than coding the hardware description language (HDL) manually. The implementation is validated by comparing the simulation results with those from Matlab. In particular, the Hilbert Transform is embedded into the FPGA hardware and applied to the baseline algorithm as the centerpiece in processing nonlinear time histories and extracting instantaneous features of nonstationary dynamic data. The selection of proper numerical methods for the hardware execution of the selected identification algorithm and consideration of the fixed-point representation are elaborated. Other challenges include the issues of the timing in the hardware execution cycle of the design, resource consumption, approximation accuracy, and user flexibility of input data types limited by the simplicity of this preliminary design. Future work includes making an FPGA and microprocessor operate together to embed a further developed algorithm that yields better

Development of chemical process for synthesis of polyunsaturated esters

OpenAIRE

Vera LÃcia Viana do Nascimento

2014-01-01

This work aimed to develop refining processes, chemical alcoholysis followed by separation of fatty acids using the complexation with urea technique for the synthesis of poly-unsaturated esters from waste of fish oils. The special crude fish oil was purchased from Company Campestre - SÃo Paulo. Initially this oil has undergone a process of physical and chemical refining. From the refined oil, an alcoholysis process was carried out to obtain the mixture of free fatty acids. From the hydrolyzed...

Physical and chemical characterization of bioaerosols - Implications for nucleation processes

Science.gov (United States)

Ariya, P. A.; Sun, J.; Eltouny, N. A.; Hudson, E. D.; Hayes, C. T.; Kos, G.

The importance of organic compounds in the oxidative capacity of the atmosphere, and as cloud condensation and ice-forming nuclei, has been recognized for several decades. Organic compounds comprise a significant fraction of the suspended matter mass, leading to local (e.g. toxicity, health hazards) and global (e.g. climate change) impacts. The state of knowledge of the physical chemistry of organic aerosols has increased during the last few decades. However, due to their complex chemistry and the multifaceted processes in which they are involved, the importance of organic aerosols, particularly bioaerosols, in driving physical and chemical atmospheric processes is still very uncertain and poorly understood. Factors such as solubility, surface tension, chemical impurities, volatility, morphology, contact angle, deliquescence, wettability, and the oxidation process are pivotal in the understanding of the activation processes of cloud droplets, and their chemical structures, solubilities and even the molecular configuration of the microbial outer membrane, all impact ice and cloud nucleation processes in the atmosphere. The aim of this review paper is to assess the current state of knowledge regarding chemical and physical characterization of bioaerosols with a focus on those properties important in nucleation processes. We herein discuss the potential importance (or lack thereof) of physical and chemical properties of bioaerosols and illustrate how the knowledge of these properties can be employed to study nucleation processes using a modeling exercise. We also outline a list of major uncertainties due to a lack of understanding of the processes involved or lack of available data. We will also discuss key issues of atmospheric significance deserving future physical chemistry research in the fields of bioaerosol characterization and microphysics, as well as bioaerosol modeling. These fundamental questions are to be addressed prior to any definite conclusions on the

The benefits of noise and nonlinearity: Extracting energy from random vibrations

Energy Technology Data Exchange (ETDEWEB)

Gammaitoni, Luca, E-mail: luca.gammaitoni@pg.infn.it [NiPS Laboratory, Universita di Perugia, I-06100 Perugia (Italy); Neri, Igor; Vocca, Helios [NiPS Laboratory, Universita di Perugia, I-06100 Perugia (Italy)

2010-10-05

Nonlinear behavior is the ordinary feature of the vast majority of dynamical systems and noise is commonly present in any finite temperature physical and chemical system. In this article we briefly review the potentially beneficial outcome of the interplay of noise and nonlinearity by addressing the novel field of vibration energy harvesting. The role of nonlinearity in a piezoelectric harvester oscillator dynamics is modeled with nonlinear stochastic differential equation.

Laser isotope separation - a new class of chemical process

International Nuclear Information System (INIS)

Woodall, K.B.; Mannik, L.; O'Neill, J.A.; Mader, D.L.; Nickerson, S.B.; Robins, J.R.; Bartoszek, F.E.; Gratton, D.

1983-01-01

Lasers may soon find several applications in chemical processing. The applications that have attracted the most research funding to date involve isotope separation for the nuclear industry. These isotopes have an unusually high value (≥$1000/kg) compared to bulk chemicals (∼$1/kg) and are generally required in very large quantities. In a laser isotope separation process, light is used to convert a separation that is very difficult or even impossible by conventional chemical engineering techniques to one that is readily handled by conventional separation technology. For some isotopes this can result in substantial capital and energy savings. A uranium enrichment process developed at the Lawrence Livermore National Laboratory is the closest to commercialization of the large scale laser isotope separation processes. Of particular interest to the Canadian nuclear industry are the laser separation of deuterium, tritium, zirconium-90 and carbon-14. In this paper, the basic principles behind laser isotope separation are reviewed and brief dscriptions of the more developed processes are given

Chemical-cleaning process evaluation: Westinghouse steam generators. Final report

International Nuclear Information System (INIS)

Cleary, W.F.; Gockley, G.B.

1983-04-01

The Steam Generator Owners Group (SGOG)/Electric Power Research Institute (EPRI) Steam Generator Secondary Side Chemical Cleaning Program, under develpment since 1978, has resulted in a generic process for the removal of accumulated corrosion products and tube deposits in the tube support plate crevices. The SGOG/EPRI Project S150-3 was established to obtain an evaluation of the generic process in regard to its applicability to Westinghouse steam generators. The results of the evaluation form the basis for recommendations for transferring the generic process to a plant specific application and identify chemical cleaning corrosion guidelines for the materials in Westinghouse Steam Generators. The results of the evaluation, recommendations for plant-specific applications and corrosion guidelines for chemical cleaning are presented in this report

Biochemical methane potential prediction of plant biomasses: Comparing chemical composition versus near infrared methods and linear versus non-linear models.

Science.gov (United States)

Godin, Bruno; Mayer, Frédéric; Agneessens, Richard; Gerin, Patrick; Dardenne, Pierre; Delfosse, Philippe; Delcarte, Jérôme

2015-01-01

The reliability of different models to predict the biochemical methane potential (BMP) of various plant biomasses using a multispecies dataset was compared. The most reliable prediction models of the BMP were those based on the near infrared (NIR) spectrum compared to those based on the chemical composition. The NIR predictions of local (specific regression and non-linear) models were able to estimate quantitatively, rapidly, cheaply and easily the BMP. Such a model could be further used for biomethanation plant management and optimization. The predictions of non-linear models were more reliable compared to those of linear models. The presentation form (green-dried, silage-dried and silage-wet form) of biomasses to the NIR spectrometer did not influence the performances of the NIR prediction models. The accuracy of the BMP method should be improved to enhance further the BMP prediction models. Copyright © 2014 Elsevier Ltd. All rights reserved.

Process safety management for highly hazardous chemicals

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-02-01

Purpose of this document is to assist US DOE contractors who work with threshold quantities of highly hazardous chemicals (HHCs), flammable liquids or gases, or explosives in successfully implementing the requirements of OSHA Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119). Purpose of this rule is to prevent releases of HHCs that have the potential to cause catastrophic fires, explosions, or toxic exposures.

Sustainability assessment of novel chemical processes at early stage: application to biobased processes

NARCIS (Netherlands)

Patel, A.D.; Meesters, K.; Uil, H. den; Jong, E. de; Blok, K.; Patel, M.K.

2012-01-01

Chemical conversions have been a cornerstone of industrial revolution and societal progress. Continuing this progress in a resource constrained world poses a critical challenge which demands the development of innovative chemical processes to meet our energy and material needs in a sustainable way.

Multi-order nonlinear diffraction in second harmonic generation

DEFF Research Database (Denmark)

Saltiel, S. M.; Neshev, D.; Krolikowski, Wieslaw

We analyze the emission patterns in the process of second harmonic (SH) generation in χ(2) nonlinear gratings and identify for the first time, to the best of our knowledge, the evidence of Raman-Nath type nonlinear diffraction in frequency doubling processes.......We analyze the emission patterns in the process of second harmonic (SH) generation in χ(2) nonlinear gratings and identify for the first time, to the best of our knowledge, the evidence of Raman-Nath type nonlinear diffraction in frequency doubling processes....

Nonlinear photonic metasurfaces

Science.gov (United States)

Li, Guixin; Zhang, Shuang; Zentgraf, Thomas

2017-03-01

Compared with conventional optical elements, 2D photonic metasurfaces, consisting of arrays of antennas with subwavelength thickness (the 'meta-atoms'), enable the manipulation of light-matter interactions on more compact platforms. The use of metasurfaces with spatially varying arrangements of meta-atoms that have subwavelength lateral resolution allows control of the polarization, phase and amplitude of light. Many exotic phenomena have been successfully demonstrated in linear optics; however, to meet the growing demand for the integration of more functionalities into a single optoelectronic circuit, the tailorable nonlinear optical properties of metasurfaces will also need to be exploited. In this Review, we discuss the design of nonlinear photonic metasurfaces — in particular, the criteria for choosing the materials and symmetries of the meta-atoms — for the realization of nonlinear optical chirality, nonlinear geometric Berry phase and nonlinear wavefront engineering. Finally, we survey the application of nonlinear photonic metasurfaces in optical switching and modulation, and we conclude with an outlook on their use for terahertz nonlinear optics and quantum information processing.

Perturbation and characterization of nonlinear processes. Progress report, November 15, 1984-November 14, 1985

International Nuclear Information System (INIS)

Swinney, H.L.; Swift, J.

1985-01-01

Methods of characterizing nonperiodic processes in nonlinear systems are being developed and tested on low dimensional mathematical models and applied to laboratory data for nonequilibrium systems, particularly the Belousov--Zhabotinskii (BZ) reaction. Methods developed for characterizing dynamical behavior are described first, followed by a discussion of the experimental work

Scene matching based on non-linear pre-processing on reference image and sensed image

Institute of Scientific and Technical Information of China (English)

Zhong Sheng; Zhang Tianxu; Sang Nong

2005-01-01

To solve the heterogeneous image scene matching problem, a non-linear pre-processing method for the original images before intensity-based correlation is proposed. The result shows that the proper matching probability is raised greatly. Especially for the low S/N image pairs, the effect is more remarkable.

Effects of coupled thermal, hydrological and chemical processes on nuclide transport

International Nuclear Information System (INIS)

Carnahan, C.L.

1987-03-01

Coupled thermal, hydrological and chemical processes can be classified in two categories. One category consists of the ''Onsager'' type of processes driven by gradients of thermodynamic state variables. These processes occur simultaneously with the direct transport processes. In particular, thermal osmosis, chemical osmosis and ultrafiltration may be prominent in semipermeable materials such as clays. The other category consists of processes affected indirectly by magnitudes of thermodynamic state variables. An important example of this category is the effect of temperature on rates of chemical reactions and chemical equilibria. Coupled processes in both categories may affect transport of radionuclides. Although computational models of limited extent have been constructed, there exists no model that accounts for the full set of THC-coupled processes. In the category of Onsager coupled processes, further model development and testing is severely constrained by a deficient data base of phenomenological coefficients. In the second category, the lack of a general description of effects of heterogeneous chemical reactions on permeability of porous media inhibits progress in quantitative modeling of hydrochemically coupled transport processes. Until fundamental data necessary for further model development have been acquired, validation efforts will be limited necessarily to testing of incomplete models of nuclide transport under closely controlled experimental conditions. 34 refs., 2 tabs

Brain signal variability as a window into the bidirectionality between music and language processing: moving from a linear to a nonlinear model.

Science.gov (United States)

Hutka, Stefanie; Bidelman, Gavin M; Moreno, Sylvain

2013-12-30

There is convincing empirical evidence for bidirectional transfer between music and language, such that experience in either domain can improve mental processes required by the other. This music-language relationship has been studied using linear models (e.g., comparing mean neural activity) that conceptualize brain activity as a static entity. The linear approach limits how we can understand the brain's processing of music and language because the brain is a nonlinear system. Furthermore, there is evidence that the networks supporting music and language processing interact in a nonlinear manner. We therefore posit that the neural processing and transfer between the domains of language and music are best viewed through the lens of a nonlinear framework. Nonlinear analysis of neurophysiological activity may yield new insight into the commonalities, differences, and bidirectionality between these two cognitive domains not measurable in the local output of a cortical patch. We thus propose a novel application of brain signal variability (BSV) analysis, based on mutual information and signal entropy, to better understand the bidirectionality of music-to-language transfer in the context of a nonlinear framework. This approach will extend current methods by offering a nuanced, network-level understanding of the brain complexity involved in music-language transfer.

Brain signal variability as a window into the bidirectionality between music and language processing: Moving from a linear to a nonlinear model

Directory of Open Access Journals (Sweden)

Stefanie Andrea Hutka

2013-12-01

Full Text Available There is convincing empirical evidence for bidirectional transfer between music and language, such that experience in either domain can improve mental processes required by the other. This music-language relationship has been studied using linear models (e.g., comparing mean neural activity that conceptualize brain activity as a static entity. The linear approach limits how we can understand the brain’s processing of music and language because the brain is a nonlinear system. Furthermore, there is evidence that the networks supporting music and language processing interact in a nonlinear manner. We therefore posit that the neural processing and transfer between the domains of language and music are best viewed through the lens of a nonlinear framework. Nonlinear analysis of neurophysiological activity may yield new insight into the commonalities, differences, and bidirectionality between these two cognitive domains not measurable in the local output of a cortical patch. We thus propose a novel application of brain signal variability (BSV analysis, based on mutual information and signal entropy, to better understand the bidirectionality of music-to-language transfer in the context of a nonlinear framework. This approach will extend current methods by offering a nuanced, network-level understanding of the brain complexity involved in music-language transfer.

Computer-Aided Multiscale Modelling for Chemical Process Engineering

DEFF Research Database (Denmark)

Morales Rodriguez, Ricardo; Gani, Rafiqul

2007-01-01

Chemical processes are generally modeled through monoscale approaches, which, while not adequate, satisfy a useful role in product-process design. In this case, use of a multi-dimensional and multi-scale model-based approach has importance in product-process development. A computer-aided framework...

Multi-Model Adaptive Fuzzy Controller for a CSTR Process

Directory of Open Access Journals (Sweden)

Shubham Gogoria

2015-09-01

Full Text Available Continuous Stirred Tank Reactors are intensively used to control exothermic reactions in chemical industries. It is a very complex multi-variable system with non-linear characteristics. This paper deals with linearization of the mathematical model of a CSTR Process. Multi model adaptive fuzzy controller has been designed to control the reactor concentration and temperature of CSTR process. This method combines the output of multiple Fuzzy controllers, which are operated at various operating points. The proposed solution is a straightforward implementation of Fuzzy controller with gain scheduler to control the linearly inseparable parameters of a highly non-linear process.

Chemical oxygen demand reduction in coffee wastewater through chemical flocculation and advanced oxidation processes

Institute of Scientific and Technical Information of China (English)

ZAYAS Pérez Teresa; GEISSLER Gunther; HERNANDEZ Fernando

2007-01-01

The removal of the natural organic matter present in coffee processing wastewater through chemical coagulation-flocculatio and advanced oxidation processes(AOP)had been studied.The effectiveness of the removal of natural organic matter using commercial flocculants and UV/H202,UVO3 and UV/H-H202/O3 processes was determined under acidic conditions.For each of these processes,different operational conditions were explored to optimize the treatment efficiency of the coffee wastewater.Coffee wastewater is characterized by a high chemical oxygen demand(COD)and low total suspended solids.The outcomes of coffee wastewater reeatment using coagulation-flocculation and photodegradation processes were assessed in terms of reduction of COD,color,and turbidity.It was found that a reductiOn in COD of 67%could be realized when the coffee wastewater was treated by chemical coagulation-flocculatlon witll lime and coagulant T-1.When coffee wastewater was treated by coagulation-flocculation in combination with UV/H202,a COD reduction of 86%was achieved,although only after prolonged UV irradiation.Of the three advanced oxidation processes considered,UV/H202,uv/03 and UV/H202/03,we found that the treatment with UV/H2O2/O3 was the most effective,with an efficiency of color,turbidity and further COD removal of 87%,when applied to the flocculated coffee wastewater.

Chemical Processing Department monthly report, May 1957

Energy Technology Data Exchange (ETDEWEB)

1957-06-21

The May, 1957 monthly report for the Chemical Processing Department of the Hanford Atomic Products Operation includes information regarding research and engineering efforts with respect to the Purex and Redox process technology. Also discussed is the production operation, finished product operation, power and general maintenance, financial operation, engineering and research operations, and employee operation.(MB)

Chemical Processing Department monthly report, September 1957

Energy Technology Data Exchange (ETDEWEB)

1957-10-22

The September, 1957 monthly report for the Chemical Processing Department of the Hanford Atomic Products Operation includes information regarding research and engineering efforts with respect to the Purex and Redox process technology. Also discussed is the production operation, finished product operation, power and general maintenance, financial operation, engineering and research operations, and employee operation.

The forced nonlinear Schroedinger equation

International Nuclear Information System (INIS)

Kaup, D.J.; Hansen, P.J.

1985-01-01

The nonlinear Schroedinger equation describes the behaviour of a radio frequency wave in the ionosphere near the reflexion point where nonlinear processes are important. A simple model of this phenomenon leads to the forced nonlinear Schroedinger equation in terms of a nonlinear boundary value problem. A WKB analysis of the time evolution equations for the nonlinear Schroedinger equation in the inverse scattering transform formalism gives a crude order of magnitude estimation of the qualitative behaviour of the solutions. This estimation is compared with the numerical solutions. (D.Gy.)

Application of Nonlinear Elastic Resonance Spectroscopy For Damage Detection In Concrete: An Interesting Story

Energy Technology Data Exchange (ETDEWEB)

Byers, Loren W. [Los Alamos National Laboratory; Ten Cate, James A. [Los Alamos National Laboratory; Johnson, Paul A. [Los Alamos National Laboratory

2012-06-28

Nonlinear resonance ultrasound spectroscopy experiments conducted on concrete cores, one chemically and mechanically damaged by alkali-silica reactivity, and one undamaged, show that this material displays highly nonlinear wave behavior, similar to many other damaged materials. They find that the damaged sample responds more nonlinearly, manifested by a larger resonant peak and modulus shift as a function of strain amplitude. The nonlinear response indicates that there is a hysteretic influence in the stress-strain equation of state. Further, as in some other materials, slow dynamics are present. The nonlinear response they observe in concrete is an extremely sensitive indicator of damage. Ultimately, nonlinear wave methods applied to concrete may be used to guide mixing, curing, or other production techniques, in order to develop materials with particular desired qualities such as enhanced strength or chemical resistance, and to be used for damage inspection.

Modeling human auditory evoked brainstem responses based on nonlinear cochlear processing

DEFF Research Database (Denmark)

Harte, James; Rønne, Filip Munch; Dau, Torsten

2010-01-01

. To generate AEPs recorded at remote locations, a convolution was made on an empirically obtained elementary unit waveform with the instantaneous discharge rate function for the corresponding AN unit. AEPs to click-trains, as well as to tone pulses at various frequencies, were both modelled and recorded...... at different stimulation levels and repetition rates. The observed nonlinearities in the recorded potential patterns, with respect to ABR wave V latencies and amplitudes, could be largely accounted for by level-dependent BM processing as well as effects of short-term neural adaptation. The present study...

Microbial production of bulk chemicals: development of anaerobic processes

NARCIS (Netherlands)

Weusthuis, R.A.; Lamot, I.; Oost, van der J.; Sanders, J.P.M.

2011-01-01

nnovative fermentation processes are necessary for the cost-effective production of bulk chemicals from renewable resources. Current microbial processes are either anaerobic processes, with high yield and productivity, or less-efficient aerobic processes. Oxygen utilization plays an important role

[Recent results in research on oscillatory chemical reactions].

Science.gov (United States)

Poros, Eszter; Kurin-Csörgei, Krisztina

2014-01-01

The mechanisms of the complicated periodical phenomenas in the nature (e.g. hearth beat, sleep cycle, circadian rhythms, etc) could be understood with using the laws of nonlinear chemical systems. In this article the newest result in the research of the subfield of nonlinear chemical dynamics aimed at constructing oscillatory chemical reactions, which are novel either in composition or in configuration, are presented. In the introductory part the concept of chemical periodicity is defined, then the forms as it can appear in time and space and the methods of their study are discussed. Detailed description of the experimental work that has resulted in two significant discoveries is provided. A method was developed to design pH-oscillators which are capable of operating under close conditions. The batch pH-oscillators are more convenient to use in some proposed applications than the equivalent CSTR variant. A redox oscillator that is new in composition was found. The permanganate oxidation of some amino acids was shown to take place according to oscillatory kinetics in a narrow range of the experimental parameters. The KMnO4 - glycine - Na2HPO4 system represents the first example in the family of manganese based oscillators where amino acids is involved. In the conclusion formal analogies between the simple chemical and some more complicated biological oscillatory phenomena are mentioned and the possibility of modeling periodic processes with the use of information gained from the studies of chemical oscillations is pointed out.

Chemical Processing Department monthly report, June 1958

Energy Technology Data Exchange (ETDEWEB)

1958-07-22

This report for June 1958, from the Chemical Processing Department at HAPO, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance; Financial operations; facilities engineering; research; and employee relations.

Chemical Processing Division monthly report, January 1966

Energy Technology Data Exchange (ETDEWEB)

Reed, P.E.

1966-02-21

This report, from the Chemical Processing Department at HAPO for January 1966, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance; Financial operations; facilities engineering; research; and employee relations.

Chemical Processing Department monthly report, March 1961

Energy Technology Data Exchange (ETDEWEB)

1961-04-21

This report for March 1961, from the Chemical Processing Department at HAPO, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance: Financial operations; facilities engineering; research; and employee relations.

A Conic Sector-Based Methodology for Nonlinear Control Design

OpenAIRE

Doyle, Francis J., III; Morari, Manfred

1990-01-01

A design method is presented for the analysis and synthesis of robust nonlinear controllers for chemical engineering systems. The method rigorously treats the effect of unmeasured disturbances and unmodeled dynamics on the stability and performance properties of a nonlinear system. The results utilise new extensions of structured singular value theory for analysis and recent synthesis results for approximate linearisation.

Coherent control of photoabsorption processes and calculation of nonlinear optical processes. Final technical report

International Nuclear Information System (INIS)

Lambropoulos, P.

1998-01-01

The work on the grant for the entire period of its duration concentrated on two different but related areas, namely coherent control of photoabsorption processes and the calculation of non linear optical processes with short wavelength radiation. On the first topic, the work dealt with the problem of controlling the population transfer from one to another bound state of a system in a route that passes through a continuum. This question is most important in the context of transferring populations between vibrational states of a molecule through a sequence of two pulses taking the system via the dissociation continuum. On the second topic, their work was motivated by the availability of XUV and soft X-ray coherent radiation sources obtained through high order harmonic generation. In addition, a few other techniques based on schemes of photo-pumped X-ray lasers promise to provide in the near-future similarly coherent sources. It is thus important to have an assessment of the possibility of extending non-linear optical processes to this range of wavelengths. This means assessing the relevant magnitude of the susceptibilities for third harmonic generation, stimulated Raman scattering, two-photon absorption, etc

Two-stage nonlinear filter for processing of scintigrams

International Nuclear Information System (INIS)

Pistor, P.; Hoener, J.; Walch, G.

1973-01-01

Linear filters which have been successfully used to process scintigrams can be modified in a meaningful manner by a preceding non-linear point operator, the Anscombe-transform. The advantages are: The scintigraphic noise becomes quasi-stationary and thus independent of the image. By these means the noise can be readily allowed for in the design of the convolutional operators. Transformed images with a stationary signal-to-noise ratio and a non-constant background t correspond to untransformed images with a signal-to-noise ratio that varies in certain limits. The filter chain automatically adapts to these changes. Our filter has the advantage over the majority of space-varying filters of being realizable by Fast Fourier Transform techniques. These advantages have to be paid for by reduced signal amplitude to background ratios. If the background is known, this shortcoming can be easily by-passed by processing trendfree scintigrams. If not, the filter chain should be completed by a third operator which reverses the Anscombe-transform. The Anscombe-transform influences the signal-to-noise ratio of cold spots and of hot spots in a different way. It remains an open question if this fact can be utilized to directly influence the detectability of the different kinds of spots

Rayleigh-type parametric chemical oscillation

Energy Technology Data Exchange (ETDEWEB)

Ghosh, Shyamolina; Ray, Deb Shankar, E-mail: pcdsr@iacs.res.in [Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032 (India)

2015-09-28

We consider a nonlinear chemical dynamical system of two phase space variables in a stable steady state. When the system is driven by a time-dependent sinusoidal forcing of a suitable scaling parameter at a frequency twice the output frequency and the strength of perturbation exceeds a threshold, the system undergoes sustained Rayleigh-type periodic oscillation, wellknown for parametric oscillation in pipe organs and distinct from the usual forced quasiperiodic oscillation of a damped nonlinear system where the system is oscillatory even in absence of any external forcing. Our theoretical analysis of the parametric chemical oscillation is corroborated by full numerical simulation of two well known models of chemical dynamics, chlorite-iodine-malonic acid and iodine-clock reactions.

Rayleigh-type parametric chemical oscillation.

Science.gov (United States)

Ghosh, Shyamolina; Ray, Deb Shankar

2015-09-28

We consider a nonlinear chemical dynamical system of two phase space variables in a stable steady state. When the system is driven by a time-dependent sinusoidal forcing of a suitable scaling parameter at a frequency twice the output frequency and the strength of perturbation exceeds a threshold, the system undergoes sustained Rayleigh-type periodic oscillation, wellknown for parametric oscillation in pipe organs and distinct from the usual forced quasiperiodic oscillation of a damped nonlinear system where the system is oscillatory even in absence of any external forcing. Our theoretical analysis of the parametric chemical oscillation is corroborated by full numerical simulation of two well known models of chemical dynamics, chlorite-iodine-malonic acid and iodine-clock reactions.

New Vistas in Chemical Product and Process Design.

Science.gov (United States)

Zhang, Lei; Babi, Deenesh K; Gani, Rafiqul

2016-06-07

Design of chemicals-based products is broadly classified into those that are process centered and those that are product centered. In this article, the designs of both classes of products are reviewed from a process systems point of view; developments related to the design of the chemical product, its corresponding process, and its integration are highlighted. Although significant advances have been made in the development of systematic model-based techniques for process design (also for optimization, operation, and control), much work is needed to reach the same level for product design. Timeline diagrams illustrating key contributions in product design, process design, and integrated product-process design are presented. The search for novel, innovative, and sustainable solutions must be matched by consideration of issues related to the multidisciplinary nature of problems, the lack of data needed for model development, solution strategies that incorporate multiscale options, and reliability versus predictive power. The need for an integrated model-experiment-based design approach is discussed together with benefits of employing a systematic computer-aided framework with built-in design templates.

Collapse of nonlinear Langmuir waves

International Nuclear Information System (INIS)

Malkin, V.M.

1986-01-01

The dispersion of sufficiently intensive Langmuir waves is determined by intrinsic (electron) nonlinearity. During Langmuir collapse the wave energy density required for the appearance of electron nonlinearity is attained, generally speaking, prior to the development of dissipative processes. Up to now, the effect of electron nonlinearity on the collapse dynamics and spectrum of strong Langmuir turbulence ( which may be very appreciable ) has not been studied extensively because of the difficulty of describing nonlinear Langmuir waves. In the present paper the positive determinacy of the electron nonlinear hamiltonian is proven, the increment of modulation instability of a nonlinear Langmuir wave cluster localized in a cavity is calculated, and the universal law of their collapse is found

Neural Generalized Predictive Control of a non-linear Process

DEFF Research Database (Denmark)

Sørensen, Paul Haase; Nørgård, Peter Magnus; Ravn, Ole

1998-01-01

The use of neural network in non-linear control is made difficult by the fact the stability and robustness is not guaranteed and that the implementation in real time is non-trivial. In this paper we introduce a predictive controller based on a neural network model which has promising stability qu...... detail and discuss the implementation difficulties. The neural generalized predictive controller is tested on a pneumatic servo sys-tem.......The use of neural network in non-linear control is made difficult by the fact the stability and robustness is not guaranteed and that the implementation in real time is non-trivial. In this paper we introduce a predictive controller based on a neural network model which has promising stability...... qualities. The controller is a non-linear version of the well-known generalized predictive controller developed in linear control theory. It involves minimization of a cost function which in the present case has to be done numerically. Therefore, we develop the numerical algorithms necessary in substantial...

Evaluation of third order nonlinear optical parameters of CdS/PVA nanocomposite

International Nuclear Information System (INIS)

Sharma, Mamta; Tripathi, S. K.

2015-01-01

CdS nanoparticles dispersed in PVA are prepared by Chemical method at room temperature. The nonlinear optical parameters such as nonlinear absorption (β), nonlinear refractive index (n 2 ) and nonlinear susceptibility (χ 3 ) are calculated for this sample by using Z-scan technique. CdS/PVA samples show the two photon absorption mechanism. The third order nonlinear susceptibility is calculated from n 2 and β and is found to be of the order of 10 −7 – 10 −8 m 2 /V 2 . The larger value of third order nonlinear susceptibility is due to dielectric and quantum confinement effect

Chemical Processing Division monthly report, November 1966

Energy Technology Data Exchange (ETDEWEB)

Reed, P.E.

1966-12-21

This report, from the Chemical Processing Department at HAPO for November 1966, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance; Financial operations; facilities engineering; research; and employee-relations, and waste management.

Chemical Changes in Carbohydrates Produced by Thermal Processing.

Science.gov (United States)

Hoseney, R. Carl

1984-01-01

Discusses chemical changes that occur in the carbohydrates found in food products when these products are subjected to thermal processing. Topics considered include browning reactions, starch found in food systems, hydrolysis of carbohydrates, extrusion cooking, processing of cookies and candies, and alterations in gums. (JN)

Nonlinear Decoupling Control With ANFIS-Based Unmodeled Dynamics Compensation for a Class of Complex Industrial Processes.

Science.gov (United States)

Zhang, Yajun; Chai, Tianyou; Wang, Hong; Wang, Dianhui; Chen, Xinkai

2018-06-01

Complex industrial processes are multivariable and generally exhibit strong coupling among their control loops with heavy nonlinear nature. These make it very difficult to obtain an accurate model. As a result, the conventional and data-driven control methods are difficult to apply. Using a twin-tank level control system as an example, a novel multivariable decoupling control algorithm with adaptive neural-fuzzy inference system (ANFIS)-based unmodeled dynamics (UD) compensation is proposed in this paper for a class of complex industrial processes. At first, a nonlinear multivariable decoupling controller with UD compensation is introduced. Different from the existing methods, the decomposition estimation algorithm using ANFIS is employed to estimate the UD, and the desired estimating and decoupling control effects are achieved. Second, the proposed method does not require the complicated switching mechanism which has been commonly used in the literature. This significantly simplifies the obtained decoupling algorithm and its realization. Third, based on some new lemmas and theorems, the conditions on the stability and convergence of the closed-loop system are analyzed to show the uniform boundedness of all the variables. This is then followed by the summary on experimental tests on a heavily coupled nonlinear twin-tank system that demonstrates the effectiveness and the practicability of the proposed method.

Nonlinear optics at interfaces

International Nuclear Information System (INIS)

Chen, C.K.

1980-12-01

Two aspects of surface nonlinear optics are explored in this thesis. The first part is a theoretical and experimental study of nonlinear intraction of surface plasmons and bulk photons at metal-dielectric interfaces. The second part is a demonstration and study of surface enhanced second harmonic generation at rough metal surfaces. A general formulation for nonlinear interaction of surface plasmons at metal-dielectric interfaces is presented and applied to both second and third order nonlinear processes. Experimental results for coherent second and third harmonic generation by surface plasmons and surface coherent antiStokes Raman spectroscopy (CARS) are shown to be in good agreement with the theory

Neural Networks for Non-linear Control

DEFF Research Database (Denmark)

Sørensen, O.

1994-01-01

This paper describes how a neural network, structured as a Multi Layer Perceptron, is trained to predict, simulate and control a non-linear process.......This paper describes how a neural network, structured as a Multi Layer Perceptron, is trained to predict, simulate and control a non-linear process....

Global Controllability of Chemical Reactions

OpenAIRE

Drexler, Dániel András; Tóth, János

2015-01-01

Controllability of chemical reactions is an important problem in chemical engineering science. In control theory, analysis of the controllability of linear systems is well-founded, however the dynamics of chemical reactions is usually nonlinear. Global controllability properties of chemical reactions are analyzed here based on the Lie-algebra of the vector fields associated to elementary reactions. A chemical reaction is controllable almost everywhere if all the reaction rate coefficients can...

A non-linear decision making process for public involvement in environmental management activities

International Nuclear Information System (INIS)

Harper, M.R.; Kastenberg, W.

1995-01-01

The international industrial and governmental institutions involved in radioactive waste management and environmental remediation are now entering a new era in which they must significantly expand public involvement. Thus the decision making processes formerly utilized to direct and guide these institutions must now be shifted to take into consideration the needs of many more stakeholders than ever before. To meet this challenge, they now have the job of developing and creating a new set of accurate, sufficient and continuous self-regulating and self-correcting information pathways between themselves and the many divergent stakeholder groups in order to establish sustainable, trusting and respectful relationships. In this paper the authors introduce a new set of non-linear, practical and effective strategies for interaction. These self-regulating strategies provide timely feedback to a system, establishing trust and creating a viable vehicle for staying open and responsive to the needs out of which change and balanced adaptation can continually emerge for all stakeholders. The authors present a decision making process for public involvement which is congruent with the non-linear ideas of holographic and fractal relationships -- the mutual influence between related parts of the whole and the self-symmetry of systems at every level of complexity

Nonlinear diffraction from a virtual beam

DEFF Research Database (Denmark)

Saltiel, Solomon M.; Neshev, Dragomir N.; Krolikowski, Wieslaw

2010-01-01

We observe experimentally a novel type of nonlinear diffraction in the process of two-wave mixing on a nonlinear quadratic grating.We demonstrate that when the nonlinear grating is illuminated simultaneously by two noncollinear beams, a second-harmonic diffraction pattern is generated by a virtual...... beam propagating along the bisector of the two pump beams. The observed iffraction phenomena is a purely nonlinear effect that has no analogue in linear diffraction...

Chemical Processing Department monthly report, October 1963

Energy Technology Data Exchange (ETDEWEB)

Young, J. F.; Johnson, W. E.; Reinker, P. H.; Warren, J. H.; McCullugh, R. W.; Harmon, M. K.; Gartin, W. J.; LaFollette, T. G.; Shaw, H. P.; Frank, W. S.; Grim, K. G.; Warren, J. H.

1963-11-21

This report, for October 1963 from the Chemical Processing Department at HAPO, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance; Financial operations; facilities engineering; research; employee relations; weapons manufacturing operation; and safety and security.

Nonlinear wave equation in frequency domain: accurate modeling of ultrafast interaction in anisotropic nonlinear media

DEFF Research Database (Denmark)

Guo, Hairun; Zeng, Xianglong; Zhou, Binbin

2013-01-01

We interpret the purely spectral forward Maxwell equation with up to third-order induced polarizations for pulse propagation and interactions in quadratic nonlinear crystals. The interpreted equation, also named the nonlinear wave equation in the frequency domain, includes quadratic and cubic...... nonlinearities, delayed Raman effects, and anisotropic nonlinearities. The full potential of this wave equation is demonstrated by investigating simulations of solitons generated in the process of ultrafast cascaded second-harmonic generation. We show that a balance in the soliton delay can be achieved due...

Nonlinear Growth Curves in Developmental Research

Science.gov (United States)

Grimm, Kevin J.; Ram, Nilam; Hamagami, Fumiaki

2011-01-01

Developmentalists are often interested in understanding change processes and growth models are the most common analytic tool for examining such processes. Nonlinear growth curves are especially valuable to developmentalists because the defining characteristics of the growth process such as initial levels, rates of change during growth spurts, and asymptotic levels can be estimated. A variety of growth models are described beginning with the linear growth model and moving to nonlinear models of varying complexity. A detailed discussion of nonlinear models is provided, highlighting the added insights into complex developmental processes associated with their use. A collection of growth models are fit to repeated measures of height from participants of the Berkeley Growth and Guidance Studies from early childhood through adulthood. PMID:21824131

Convergence to equilibrium of renormalised solutions to nonlinear chemical reaction–diffusion systems

Science.gov (United States)

Fellner, Klemens; Tang, Bao Quoc

2018-06-01

The convergence to equilibrium for renormalised solutions to nonlinear reaction-diffusion systems is studied. The considered reaction-diffusion systems arise from chemical reaction networks with mass action kinetics and satisfy the complex balanced condition. By applying the so-called entropy method, we show that if the system does not have boundary equilibria, i.e. equilibrium states lying on the boundary of R_+^N, then any renormalised solution converges exponentially to the complex balanced equilibrium with a rate, which can be computed explicitly up to a finite-dimensional inequality. This inequality is proven via a contradiction argument and thus not explicitly. An explicit method of proof, however, is provided for a specific application modelling a reversible enzyme reaction by exploiting the specific structure of the conservation laws. Our approach is also useful to study the trend to equilibrium for systems possessing boundary equilibria. More precisely, to show the convergence to equilibrium for systems with boundary equilibria, we establish a sufficient condition in terms of a modified finite-dimensional inequality along trajectories of the system. By assuming this condition, which roughly means that the system produces too much entropy to stay close to a boundary equilibrium for infinite time, the entropy method shows exponential convergence to equilibrium for renormalised solutions to complex balanced systems with boundary equilibria.

Effect of channel aspect ratio on chemical recuperation process in advanced aeroengines

International Nuclear Information System (INIS)

Zhang, Silong; Cui, Naigang; Xiong, Yuefei; Feng, Yu; Qin, Jiang; Bao, Wen

2017-01-01

The working process of an advanced aeroengine such as scramjet with endothermic hydrocarbon fuel cooling is a chemical recuperative cycle. The design of cooling channel in terms of engine real working conditions is very important for the chemical recuperation process. To study the effects of channel aspect ratio (AR) on chemical recuperation process of advanced aeroengines, three dimensional model of pyrolysis coolant flow inside asymmetrical rectangular cooling channels with fins is introduced and validated through experiments. Cases when AR varies from 1 to 8 are carried out. In the pyrolysis zone of the cooling channel, decreasing the channel aspect ratio can reduce the temperature difference and non-uniformity of fuel conversion in the channel cross section, and it can also increase the final conversion and corresponding chemical heat absorption. A small channel aspect ratio is beneficial for the chemical recuperation process and can guarantee the engine cooling performance in the pyrolysis zone of the cooling channel. - Highlights: • Large non-uniformity of conversion is bad for the chemical recuperation. • Small channel aspect ratio is beneficial for improving the chemical recuperation effectiveness. • Small channel aspect ratio is also beneficial for reducing the engine wall temperature.

Approximate method for stochastic chemical kinetics with two-time scales by chemical Langevin equations

International Nuclear Information System (INIS)

Wu, Fuke; Tian, Tianhai; Rawlings, James B.; Yin, George

2016-01-01

The frequently used reduction technique is based on the chemical master equation for stochastic chemical kinetics with two-time scales, which yields the modified stochastic simulation algorithm (SSA). For the chemical reaction processes involving a large number of molecular species and reactions, the collection of slow reactions may still include a large number of molecular species and reactions. Consequently, the SSA is still computationally expensive. Because the chemical Langevin equations (CLEs) can effectively work for a large number of molecular species and reactions, this paper develops a reduction method based on the CLE by the stochastic averaging principle developed in the work of Khasminskii and Yin [SIAM J. Appl. Math. 56, 1766–1793 (1996); ibid. 56, 1794–1819 (1996)] to average out the fast-reacting variables. This reduction method leads to a limit averaging system, which is an approximation of the slow reactions. Because in the stochastic chemical kinetics, the CLE is seen as the approximation of the SSA, the limit averaging system can be treated as the approximation of the slow reactions. As an application, we examine the reduction of computation complexity for the gene regulatory networks with two-time scales driven by intrinsic noise. For linear and nonlinear protein production functions, the simulations show that the sample average (expectation) of the limit averaging system is close to that of the slow-reaction process based on the SSA. It demonstrates that the limit averaging system is an efficient approximation of the slow-reaction process in the sense of the weak convergence.

Chemical precipitation processes for the treatment of aqueous radioactive waste

International Nuclear Information System (INIS)

1992-01-01

Chemical precipitation by coagulation-flocculation and sedimentation has been commonly used for many years to treat liquid (aqueous) radioactive waste. This method allows the volume of waste to be substantially reduced for further treatment or conditioning and the bulk of the waste to de discharged. Chemical precipitation is usually applied in combination with other methods as part of a comprehensive waste management scheme. As with any other technology, chemical precipitation is constantly being improved to reduce cost to increase the effectiveness and safety on the entire waste management system. The purpose of this report is to review and update the information provided in Technical Reports Series No. 89, Chemical Treatment of Radioactive Wastes, published in 1968. In this report the chemical methods currently in use for the treatment of low and intermediate level aqueous radioactive wastes are described and illustrated. Comparisons are given of the advantages and limitations of the processes, and it is noted that good decontamination and volume reduction are not the only criteria according to which a particular process should be selected. Emphasis has been placed on the need to carefully characterize each waste stream, to examine fully the effect of segregation and the importance of looking at the entire operation and not just the treatment process when planning a liquid waste treatment facility. This general approach includes local requirements and possibilities, discharge authorization, management of the concentrates, ICRP recommendations and economics. It appears that chemical precipitation process and solid-liquid separation techniques will continue to be widely used in liquid radioactive waste treatment. Current research and development is showing that combining different processes in one treatment plant can provide higher decontamination factors and smaller secondary waste arisings. Some of these processes are already being incorporated into new and

Evaluation of third order nonlinear optical parameters of CdS/PVA nanocomposite

Energy Technology Data Exchange (ETDEWEB)

Sharma, Mamta [Department of Physics, Center of Advanced Study in Physics, Panjab University, Chandigarh-160014 (India); Department of Applied Sciences (Physics), UIET, Panjab University, Chandigarh-160014 (India); Tripathi, S. K., E-mail: surya@pu.ac.in, E-mail: surya-tr@yahoo.com [Department of Physics, Center of Advanced Study in Physics, Panjab University, Chandigarh-160014 (India)

2015-06-24

CdS nanoparticles dispersed in PVA are prepared by Chemical method at room temperature. The nonlinear optical parameters such as nonlinear absorption (β), nonlinear refractive index (n{sub 2}) and nonlinear susceptibility (χ{sup 3}) are calculated for this sample by using Z-scan technique. CdS/PVA samples show the two photon absorption mechanism. The third order nonlinear susceptibility is calculated from n{sub 2} and β and is found to be of the order of 10{sup −7} – 10{sup −8} m{sup 2}/V{sup 2}. The larger value of third order nonlinear susceptibility is due to dielectric and quantum confinement effect.

Integrated Process Design, Control and Analysis of Intensified Chemical Processes

DEFF Research Database (Denmark)

Mansouri, Seyed Soheil

chemical processes; for example, intensified processes such as reactive distillation. Most importantly, it identifies and eliminates potentially promising design alternatives that may have controllability problems later. To date, a number of methodologies have been proposed and applied on various problems......, that the same principles that apply to a binary non-reactive compound system are valid also for a binary-element or a multi-element system. Therefore, it is advantageous to employ the element based method for multicomponent reaction-separation systems. It is shown that the same design-control principles...

Study of the nonlinear imperfect software debugging model

International Nuclear Information System (INIS)

Wang, Jinyong; Wu, Zhibo

2016-01-01

In recent years there has been a dramatic proliferation of research on imperfect software debugging phenomena. Software debugging is a complex process and is affected by a variety of factors, including the environment, resources, personnel skills, and personnel psychologies. Therefore, the simple assumption that debugging is perfect is inconsistent with the actual software debugging process, wherein a new fault can be introduced when removing a fault. Furthermore, the fault introduction process is nonlinear, and the cumulative number of nonlinearly introduced faults increases over time. Thus, this paper proposes a nonlinear, NHPP imperfect software debugging model in consideration of the fact that fault introduction is a nonlinear process. The fitting and predictive power of the NHPP-based proposed model are validated through related experiments. Experimental results show that this model displays better fitting and predicting performance than the traditional NHPP-based perfect and imperfect software debugging models. S-confidence bounds are set to analyze the performance of the proposed model. This study also examines and discusses optimal software release-time policy comprehensively. In addition, this research on the nonlinear process of fault introduction is significant given the recent surge of studies on software-intensive products, such as cloud computing and big data. - Highlights: • Fault introduction is a nonlinear changing process during the debugging phase. • The assumption that the process of fault introduction is nonlinear is credible. • Our proposed model can better fit and accurately predict software failure behavior. • Research on fault introduction case is significant to software-intensive products.

Waste processing of chemical cleaning solutions

International Nuclear Information System (INIS)

Peters, G.A.

1991-01-01

This paper reports on chemical cleaning solutions containing high concentrations of organic chelating wastes that are difficult to reduce in volume using existing technology. Current methods for evaporating low-level radiative waste solutions often use high maintenance evaporators that can be costly and inefficient. The heat transfer surfaces of these evaporators are easily fouled, and their maintenance requires a significant labor investment. To address the volume reduction of spent, low-level radioactive, chelating-based chemical cleaning solutions, ECOSAFE Liquid Volume Reduction System (LVRS) has been developed. The LVRS is based on submerged combustion evaporator technology that was modified for treatment of low-level radiative liquid wastes. This system was developed in 1988 and was used to process 180,000 gallons of waste at Oconee Nuclear Station

Second-order nonlinearity induced transparency.

Science.gov (United States)

Zhou, Y H; Zhang, S S; Shen, H Z; Yi, X X

2017-04-01

In analogy to electromagnetically induced transparency, optomechanically induced transparency was proposed recently in [Science330, 1520 (2010)SCIEAS0036-807510.1126/science.1195596]. In this Letter, we demonstrate another form of induced transparency enabled by second-order nonlinearity. A practical application of the second-order nonlinearity induced transparency is to measure the second-order nonlinear coefficient. Our scheme might find applications in quantum optics and quantum information processing.

Safety Considerations in the Chemical Process Industries

Science.gov (United States)

Englund, Stanley M.

There is an increased emphasis on chemical process safety as a result of highly publicized accidents. Public awareness of these accidents has provided a driving force for industry to improve its safety record. There has been an increasing amount of government regulation.

Nonlinear PI Control with Adaptive Interaction Algorithm for Multivariable Wastewater Treatment Process

Directory of Open Access Journals (Sweden)

S. I. Samsudin

2014-01-01

Full Text Available The wastewater treatment plant (WWTP is highly known with the nonlinearity of the control parameters, thus it is difficult to be controlled. In this paper, the enhancement of nonlinear PI controller (ENon-PI to compensate the nonlinearity of the activated sludge WWTP is proposed. The ENon-PI controller is designed by cascading a sector-bounded nonlinear gain to linear PI controller. The rate variation of the nonlinear gain kn is automatically updated based on adaptive interaction algorithm. Initiative to simplify the ENon-PI control structure by adapting kn has been proved by significant improvement under various dynamic influents. More than 30% of integral square error and 14% of integral absolute error are reduced compared to benchmark PI for DO control and nitrate in nitrogen removal control. Better average effluent qualities, less number of effluent violations, and lower aeration energy consumption resulted.

Chemical Processing effects on the radiation doses measured by Film Dosimeter System

International Nuclear Information System (INIS)

Mihai, F.

2009-01-01

Halide film dosimetry is a quantitative method of measurement of the radiation doses. The fog density and chemical processing of the dosimeter film affect the radiation dose measurement accuracy. This work presents the effect of the developer solution concentration on the response of the dosimetric film which different fog densities. Thus, three batches of film, dosimeters with following fog density 0.312 ± 1.31 %, 0.71 ± 0.59% and 0.77 ± 0.81 %, were irradiated to 137 Cs standard source to dose value of 1mSv. The halide films have been chemical processed at different concentrations of the developer solution: 20 %; 14.29 %; 11.11%; all other physics-chemical conditions in baths of development have been kept constants. Concentration of 20% is considered to be chemical processed standard conditions of the films. In case of the films exposed to 1 mSv dose, optical density recorded on the low fog films processed at 20% developer solution is rather closed of high fog film optical densities processed at 11.11% developer solution concentration. Also, the chemical processing effect on the image contrast was taken into consideration

Catechol-Based Hydrogel for Chemical Information Processing

Directory of Open Access Journals (Sweden)

Eunkyoung Kim

2017-07-01

Full Text Available Catechols offer diverse properties and are used in biology to perform various functions that range from adhesion (e.g., mussel proteins to neurotransmission (e.g., dopamine, and mimicking the capabilities of biological catechols have yielded important new materials (e.g., polydopamine. It is well known that catechols are also redox-active and we have observed that biomimetic catechol-modified chitosan films are redox-active and possess interesting molecular electronic properties. In particular, these films can accept, store and donate electrons, and thus offer redox-capacitor capabilities. We are enlisting these capabilities to bridge communication between biology and electronics. Specifically, we are investigating an interactive redox-probing approach to access redox-based chemical information and convert this information into an electrical modality that facilitates analysis by methods from signal processing. In this review, we describe the broad vision and then cite recent examples in which the catechol–chitosan redox-capacitor can assist in accessing and understanding chemical information. Further, this redox-capacitor can be coupled with synthetic biology to enhance the power of chemical information processing. Potentially, the progress with this biomimetic catechol–chitosan film may even help in understanding how biology uses the redox properties of catechols for redox signaling.

Outline of the Chemical Processing Facility (CPF)

International Nuclear Information System (INIS)

Arita, Katsuhiko

1978-01-01

Concerning the Chemical Processing Facility (CPF), a high level radioactive material research facility, to be installed in Tokai Works of Power Reactor and Nuclear Fuel Development Corporation (PNC), the detailed design and the governmental safety inspection were finished. The construction has been already started, and it will be completed in 1980. Under the national policy of establishing a nuclear fuel cycle, PNC is now carrying out the development of its downstream technology. The objects of the Chemical Processing Facility are the researches of the treatment techniques of high level radioactive liquid wastes from fuel reprocessing and of the reprocessing of fast reactor fuel. The following matters are described: purpose of the CPF, i.e. fast reactor fuel reprocessing and high-level liquid waste treatment; construction of the CPF, i.e. buildings, cells and an exhaust stack; test systems, i.e. fuel reprocessing and liquid waste vitrification; and facility safety. (Mori, K.)

Manipulating acoustic wave reflection by a nonlinear elastic metasurface

Science.gov (United States)

Guo, Xinxin; Gusev, Vitalyi E.; Bertoldi, Katia; Tournat, Vincent

2018-03-01

The acoustic wave reflection properties of a nonlinear elastic metasurface, derived from resonant nonlinear elastic elements, are theoretically and numerically studied. The metasurface is composed of a two degree-of-freedom mass-spring system with quadratic elastic nonlinearity. The possibility of converting, during the reflection process, most of the fundamental incoming wave energy into the second harmonic wave is shown, both theoretically and numerically, by means of a proper design of the nonlinear metasurface. The theoretical results from the harmonic balance method for a monochromatic source are compared with time domain simulations for a wave packet source. This protocol allows analyzing the dynamics of the nonlinear reflection process in the metasurface as well as exploring the limits of the operating frequency bandwidth. The reported methodology can be applied to a wide variety of nonlinear metasurfaces, thus possibly extending the family of exotic nonlinear reflection processes.

An integrated nonlinear optical loop mirror in silicon photonics for all-optical signal processing

Directory of Open Access Journals (Sweden)

Zifei Wang

2018-02-01

Full Text Available The nonlinear optical loop mirror (NOLM has been studied for several decades and has attracted considerable attention for applications in high data rate optical communications and all-optical signal processing. The majority of NOLM research has focused on silica fiber-based implementations. While various fiber designs have been considered to increase the nonlinearity and manage dispersion, several meters to hundreds of meters of fiber are still required. On the other hand, there is increasing interest in developing photonic integrated circuits for realizing signal processing functions. In this paper, we realize the first-ever passive integrated NOLM in silicon photonics and demonstrate its application for all-optical signal processing. In particular, we show wavelength conversion of 10 Gb/s return-to-zero on-off keying (RZ-OOK signals over a wavelength range of 30 nm with error-free operation and a power penalty of less than 2.5 dB, we achieve error-free nonreturn to zero (NRZ-to-RZ modulation format conversion at 10 Gb/s also with a power penalty of less than 2.8 dB, and we obtain error-free all-optical time-division demultiplexing of a 40 Gb/s RZ-OOK data signal into its 10 Gb/s tributary channels with a maximum power penalty of 3.5 dB.

Results of nonlinear and nonstationary image processing

International Nuclear Information System (INIS)

Pizer, S.M.; Correla, J.A.; Chesler, D.A.; Metz, C.E.

1973-01-01

A nonstationary method, multiple z-divided filtering, and a nonlinear method, biased smearing have been applied to scintigrams. Biased smearing does not appear to hold much promise. Multiple z-divided filtering, on the other hand, appears to be justified, and initial results at minimum encourage further research into the possibility that this technique may become a method of choice

Defense Waste Processing Facility Nitric- Glycolic Flowsheet Chemical Process Cell Chemistry: Part 2

Energy Technology Data Exchange (ETDEWEB)

Zamecnik, J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Edwards, T. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2017-06-06

The conversions of nitrite to nitrate, the destruction of glycolate, and the conversion of glycolate to formate and oxalate were modeled for the Nitric-Glycolic flowsheet using data from Chemical Process Cell (CPC) simulant runs conducted by Savannah River National Laboratory (SRNL) from 2011 to 2016. The goal of this work was to develop empirical correlation models to predict these values from measureable variables from the chemical process so that these quantities could be predicted a-priori from the sludge or simulant composition and measurable processing variables. The need for these predictions arises from the need to predict the REDuction/OXidation (REDOX) state of the glass from the Defense Waste Processing Facility (DWPF) melter. This report summarizes the work on these correlations based on the aforementioned data. Previous work on these correlations was documented in a technical report covering data from 2011-2015. This current report supersedes this previous report. Further refinement of the models as additional data are collected is recommended.

Adaptive PI Controller for a Nonlinear System

Directory of Open Access Journals (Sweden)

D. Rathikarani

2009-10-01

Full Text Available Most of the industrial processes are inherently nonlinear in their behaviour. Designs of controllers for these nonlinear processes are difficult, as they do not follow superposition theorem. Adaptive controller can change its behaviour in response to changes in the dynamics of the process and disturbances. Hence adaptive controller can be used to control nonlinear processes. Direct Model Reference Adaptive Control is a technique, in which a reference model involving the desired performances is specified. In the present work, a DMRAC is designed and implemented to achieve satisfactory control of a nonlinear system in all its local linear operating regions. The closed loop system is made BIBO stable by proper control techniques. The controller is designed through simulation in Matlab platform and is validated in real time by conducting experiments on the laboratory Air Flow Control System using the dSPACE interface.

Textual and chemical information processing: different domains but similar algorithms

Directory of Open Access Journals (Sweden)

Peter Willett

2000-01-01

Full Text Available This paper discusses the extent to which algorithms developed for the processing of textual databases are also applicable to the processing of chemical structure databases, and vice versa. Applications discussed include: an algorithm for distribution sorting that has been applied to the design of screening systems for rapid chemical substructure searching; the use of measures of inter-molecular structural similarity for the analysis of hypertext graphs; a genetic algorithm for calculating term weights for relevance feedback searching for determining whether a molecule is likely to exhibit biological activity; and the use of data fusion to combine the results of different chemical similarity searches.

Advances in chemical engineering in nuclear and process industries

Energy Technology Data Exchange (ETDEWEB)

NONE

1994-06-01

Symposium on Advances in Chemical Engineering in Nuclear and Process Industries dealt with a wide spectrum of areas encompassing various industries such as nuclear, fertilizer, petrochemical, refinery and cement. The topics covered in the symposium dealt with the advancements in the existing fields of science and technologies as well as in some of the emerging technologies such as membrane technology, bio-chemical and photo-chemical engineering etc. with a special emphasis on nuclear related aspects. Papers relevant to INIS are indexed separately.

Advances in chemical engineering in nuclear and process industries

International Nuclear Information System (INIS)

1994-06-01

Symposium on Advances in Chemical Engineering in Nuclear and Process Industries dealt with a wide spectrum of areas encompassing various industries such as nuclear, fertilizer, petrochemical, refinery and cement. The topics covered in the symposium dealt with the advancements in the existing fields of science and technologies as well as in some of the emerging technologies such as membrane technology, bio-chemical and photo-chemical engineering etc. with a special emphasis on nuclear related aspects. Papers relevant to INIS are indexed separately

Material compatibility and corrosion control of the KWU chemical cleaning process

International Nuclear Information System (INIS)

Odar, S.

1994-01-01

The concentrations of salt impurities within the deposits on the tube sheet and in the tube to tube-support-plate crevices can induce a variety of corrosion mechanisms on steam generator tubes. One of the most effective ways of counteracting corrosion mechanisms and thus of improving steam generator performance is to clean the steam generators and keep them in a clean condition. As shown by field results chemical cleaning is a way of removing hazardous deposits from steam generators. All available chemical cleaning processes use inhibitors to control the corrosion except the KWU chemical cleaning process. In this article the corrosion control technique of KWU Chemical Cleaning Process without using conventional inhibitors will be explained and the state of the field experience with respect to material compatibility will be presented. (author). 4 figs., 1 tab., 8 refs

Processes for converting biomass-derived feedstocks to chemicals and liquid fuels

Science.gov (United States)

Held, Andrew; Woods, Elizabeth; Cortright, Randy; Gray, Matthew

2018-04-17

The present invention provides processes, methods, and systems for converting biomass-derived feedstocks to liquid fuels and chemicals. The method generally includes the reaction of a hydrolysate from a biomass deconstruction process with hydrogen and a catalyst to produce a reaction product comprising one of more oxygenated compounds. The process also includes reacting the reaction product with a condensation catalyst to produce C.sub.4+ compounds useful as fuels and chemicals.

Processes for converting biomass-derived feedstocks to chemicals and liquid fuels

Science.gov (United States)

Held, Andrew; Woods, Elizabeth; Cortright, Randy; Gray, Matthew

2017-05-23

The present invention provides processes, methods, and systems for converting biomass-derived feedstocks to liquid fuels and chemicals. The method generally includes the reaction of a hydrolysate from a biomass deconstruction process with hydrogen and a catalyst to produce a reaction product comprising one of more oxygenated compounds. The process also includes reacting the reaction product with a condensation catalyst to produce C.sub.4+ compounds useful as fuels and chemicals.

Non-linear processes in the Earth atmosphere boundary layer

Science.gov (United States)

Grunskaya, Lubov; Valery, Isakevich; Dmitry, Rubay

2013-04-01

The work is connected with studying electromagnetic fields in the resonator Earth-Ionosphere. There is studied the interconnection of tide processes of geophysical and astrophysical origin with the Earth electromagnetic fields. On account of non-linear property of the resonator Earth-Ionosphere the tides (moon and astrophysical tides) in the electromagnetic Earth fields are kinds of polyharmonic nature. It is impossible to detect such non-linear processes with the help of the classical spectral analysis. Therefore to extract tide processes in the electromagnetic fields, the method of covariance matrix eigen vectors is used. Experimental investigations of electromagnetic fields in the atmosphere boundary layer are done at the distance spaced stations, situated on Vladimir State University test ground, at Main Geophysical Observatory (St. Petersburg), on Kamchatka pen., on Lake Baikal. In 2012 there was continued to operate the multichannel synchronic monitoring system of electrical and geomagnetic fields at the spaced apart stations: VSU physical experimental proving ground; the station of the Institute of Solar and Terrestrial Physics of Russian Academy of Science (RAS) at Lake Baikal; the station of the Institute of volcanology and seismology of RAS in Paratunka; the station in Obninsk on the base of the scientific and production society "Typhoon". Such investigations turned out to be possible after developing the method of scanning experimental signal of electromagnetic field into non- correlated components. There was used a method of the analysis of the eigen vectors ofthe time series covariance matrix for exposing influence of the moon tides on Ez. The method allows to distribute an experimental signal into non-correlated periodicities. The present method is effective just in the situation when energetical deposit because of possible influence of moon tides upon the electromagnetic fields is little. There have been developed and realized in program components

Emissions model of waste treatment operations at the Idaho Chemical Processing Plant

International Nuclear Information System (INIS)

Schindler, R.E.

1995-03-01

An integrated model of the waste treatment systems at the Idaho Chemical Processing Plant (ICPP) was developed using a commercially-available process simulation software (ASPEN Plus) to calculate atmospheric emissions of hazardous chemicals for use in an application for an environmental permit to operate (PTO). The processes covered by the model are the Process Equipment Waste evaporator, High Level Liquid Waste evaporator, New Waste Calcining Facility and Liquid Effluent Treatment and Disposal facility. The processes are described along with the model and its assumptions. The model calculates emissions of NO x , CO, volatile acids, hazardous metals, and organic chemicals. Some calculated relative emissions are summarized and insights on building simulations are discussed

Chemical processes in neutron capture therapy

International Nuclear Information System (INIS)

Brown, B.J.

1975-01-01

Research into the radiation chemical effects of neutron capture therapy are described. In the use of neutron capture therapy for the treatment of brain tumours, compounds containing an activatable nuclide are selectively concentrated within tumour tissue and irradiated with neutrons. Target compounds for use in therapy must accumulate selectively in high concentrations in the tumour and must be non toxic to the patient. The most suitable of these are the boron hydrides. Radiation dosages, resulting from neutron capture in normal tissue constituents are tabulated. As part of the program to study the radiation-induced chemical processes undergone by boron target compounds, the radiolytic degredation of boron hydride and phenyl boric acid system was investigated. No direct dependence between the yield of the transient radiolytic species and the concentration of the B-compound was observed. (author)

Life cycle sustainability assessment of chemical processes

DEFF Research Database (Denmark)

Xu, Di; Lv, Liping; Ren, Jingzheng

2017-01-01

In this study, an integrated vector-based three-dimensional (3D) methodology for the life cycle sustainability assessment (LCSA) of chemical process alternatives is proposed. In the methodology, a 3D criteria assessment system is first established by using the life cycle assessment, the life cycl...

Nonlinear plasma waves excited near resonance

International Nuclear Information System (INIS)

Cohen, B.I.; Kaufman, A.N.

1977-01-01

The nonlinear resonant response of a uniform plasma to an external plane-wave field is formulated in terms of the mismatch Δ/sub n l/ between the driving frequency and the time-dependent, complex, nonlinear normal mode frequency at the driving wavenumber. This formalism is applied to computer simulations of this process, yielding a deduced nonlinear frequency shift. The time dependence of the nonlinear phenomena, at frequency Δ/sub n l/ and at the bounce frequency of the resonant particles, is analyzed. The interdependence of the nonlinear features is described by means of energy and momentum relations

Nonlinear electromagnetic susceptibilities of unmagnetized plasmas

International Nuclear Information System (INIS)

Yoon, Peter H.

2005-01-01

Fully electromagnetic nonlinear susceptibilities of unmagnetized plasmas are analyzed in detail. Concrete expressions of the second-order nonlinear susceptibility are found in various forms in the literature, usually in connection with the discussions of various three-wave decay processes, but the third-order susceptibilities are rarely discussed. The second-order susceptibility is pertinent to nonlinear wave-wave interactions (i.e., the decay/coalescence), whereas the third-order susceptibilities affect nonlinear wave-particle interactions (i.e., the induced scattering). In the present article useful approximate analytical expressions of these nonlinear susceptibilities that can be readily utilized in various situations are derived

Rapid assessment of nonlinear optical propagation effects in dielectrics

Science.gov (United States)

Hoyo, J. Del; de La Cruz, A. Ruiz; Grace, E.; Ferrer, A.; Siegel, J.; Pasquazi, A.; Assanto, G.; Solis, J.

2015-01-01

Ultrafast laser processing applications need fast approaches to assess the nonlinear propagation of the laser beam in order to predict the optimal range of processing parameters in a wide variety of cases. We develop here a method based on the simple monitoring of the nonlinear beam shaping against numerical prediction. The numerical code solves the nonlinear Schrödinger equation with nonlinear absorption under simplified conditions by employing a state-of-the art computationally efficient approach. By comparing with experimental results we can rapidly estimate the nonlinear refractive index and nonlinear absorption coefficients of the material. The validity of this approach has been tested in a variety of experiments where nonlinearities play a key role, like spatial soliton shaping or fs-laser waveguide writing. The approach provides excellent results for propagated power densities for which free carrier generation effects can be neglected. Above such a threshold, the peculiarities of the nonlinear propagation of elliptical beams enable acquiring an instantaneous picture of the deposition of energy inside the material realistic enough to estimate the effective nonlinear refractive index and nonlinear absorption coefficients that can be used for predicting the spatial distribution of energy deposition inside the material and controlling the beam in the writing process.

Maglev Train Signal Processing Architecture Based on Nonlinear Discrete Tracking Differentiator.

Science.gov (United States)

Wang, Zhiqiang; Li, Xiaolong; Xie, Yunde; Long, Zhiqiang

2018-05-24

In a maglev train levitation system, signal processing plays an important role for the reason that some sensor signals are prone to be corrupted by noise due to the harsh installation and operation environment of sensors and some signals cannot be acquired directly via sensors. Based on these concerns, an architecture based on a new type of nonlinear second-order discrete tracking differentiator is proposed. The function of this signal processing architecture includes filtering signal noise and acquiring needed signals for levitation purposes. The proposed tracking differentiator possesses the advantages of quick convergence, no fluttering, and simple calculation. Tracking differentiator's frequency characteristics at different parameter values are studied in this paper. The performance of this new type of tracking differentiator is tested in a MATLAB simulation and this tracking-differentiator is implemented in Very-High-Speed Integrated Circuit Hardware Description Language (VHDL). In the end, experiments are conducted separately on a test board and a maglev train model. Simulation and experiment results show that the performance of this novel signal processing architecture can fulfill the real system requirement.

Maglev Train Signal Processing Architecture Based on Nonlinear Discrete Tracking Differentiator

Directory of Open Access Journals (Sweden)

Zhiqiang Wang

2018-05-01

Full Text Available In a maglev train levitation system, signal processing plays an important role for the reason that some sensor signals are prone to be corrupted by noise due to the harsh installation and operation environment of sensors and some signals cannot be acquired directly via sensors. Based on these concerns, an architecture based on a new type of nonlinear second-order discrete tracking differentiator is proposed. The function of this signal processing architecture includes filtering signal noise and acquiring needed signals for levitation purposes. The proposed tracking differentiator possesses the advantages of quick convergence, no fluttering, and simple calculation. Tracking differentiator’s frequency characteristics at different parameter values are studied in this paper. The performance of this new type of tracking differentiator is tested in a MATLAB simulation and this tracking-differentiator is implemented in Very-High-Speed Integrated Circuit Hardware Description Language (VHDL. In the end, experiments are conducted separately on a test board and a maglev train model. Simulation and experiment results show that the performance of this novel signal processing architecture can fulfill the real system requirement.

Desulphurization of exhaust gases in chemical processes

Energy Technology Data Exchange (ETDEWEB)

Asperger, K.; Wischnewski, W.

1981-01-01

The sulfur content of exhaust gases can be reduced by: desulphurization of fuels; modification of processes; or treatment of resultant gases. In this paper a few selected examples from the chemical industry in the German Democratic Republic are presented. Using modified processes and treating the resultant gases, the sulphuric content of exhaust gases is effectively reduced. Methods to reduce the sulfur content of exhaust gases are described in the field of production of: sulphuric acid; viscose; fertilizers; and paraffin.

Recent Advances in Explicit Multiparametric Nonlinear Model Predictive Control

KAUST Repository

Domínguez, Luis F.

2011-01-19

In this paper we present recent advances in multiparametric nonlinear programming (mp-NLP) algorithms for explicit nonlinear model predictive control (mp-NMPC). Three mp-NLP algorithms for NMPC are discussed, based on which novel mp-NMPC controllers are derived. The performance of the explicit controllers are then tested and compared in a simulation example involving the operation of a continuous stirred-tank reactor (CSTR). © 2010 American Chemical Society.

DYNSIR; A dynamic simulator for the chemical process

International Nuclear Information System (INIS)

Park, Hyun Soo; Yoo, Jae Hyung; Byeon, Kee Hoh; Park, Jeong Hwa; Park, Seong Won

1990-03-01

A program code for dynamic simulation of arbitrary chemical process, called DYNSIR, is developed. The code can simulate rather arbitrary arrangements of individual chemical processing units whose models are described by ordinary differential equations. The code structure to handle input/output, memory and data management, numerical interactive or predetermined changes in parameter values during the simulation. Individual model is easy to maintain since the modular approach is used. The integration routine is highly effective because of the development of algorithm for modular integration method using the cubic spline. DYNSIR's data structures are not the index but the pointer structure. This pointer structure allows the dynamic memory allocation for the memory management. The dynamic memory allocation methods is to minimize the amount of memories and to overcome the limitation of the number of variables to be used. Finally, it includes various functions, such as the input preprocessor, the effective error processing, and plotting and reporting routines. (author)

Third-order nonlinear optical response of Ag-CdSe/PVA hybrid nanocomposite

Energy Technology Data Exchange (ETDEWEB)

Tripathi, S.K.; Kaur, Ramneek; Kaur, Jaspreet; Sharma, Mamta [Panjab University, Department of Physics, Center of Advanced Study in Physics, Chandigarh (India)

2015-09-15

Hybrid nanocomposites of II-VI semiconductor nanoparticles are gaining great interest in nonlinear optoelectronic devices. Present work includes the characterization of CdSe polymer nanocomposite prepared by chemical in situ technique. From X-ray diffraction, the hexagonal wurtzite structure of nanoparticles has been confirmed with spherical morphology from transmission electron microscopy. Ag-CdSe hybrid polymer nanocomposite has been prepared chemically at different Ag concentrations. The presence of Ag in hybrid nanocomposite has been confirmed with energy-dispersive X-ray spectroscopy. The effect of varying Ag concentration on the linear and nonlinear optical properties of the nanocomposites has been studied. In linear optical parameters, the linear absorption coefficient, refractive index, extinction coefficient and optical conductivity have been calculated. The third-order nonlinear optical properties have been observed with open- and closed-aperture Z-scan technique. The large nonlinear refractive index ∝10{sup -5} cm{sup 2}/W with self-focusing behaviour is due to the combined effect of quantum confinement and thermo-optical effects. The enhanced nonlinearity with increasing Ag content is due to the surface plasmon resonance, which enhances the local electric field near the nanoparticle surface. Thus, Ag-CdSe hybrid polymer nanocomposite has favourable nonlinear optical properties for various optoelectronic applications. (orig.)

Third-order nonlinear optical response of Ag-CdSe/PVA hybrid nanocomposite

International Nuclear Information System (INIS)

Tripathi, S.K.; Kaur, Ramneek; Kaur, Jaspreet; Sharma, Mamta

2015-01-01

Hybrid nanocomposites of II-VI semiconductor nanoparticles are gaining great interest in nonlinear optoelectronic devices. Present work includes the characterization of CdSe polymer nanocomposite prepared by chemical in situ technique. From X-ray diffraction, the hexagonal wurtzite structure of nanoparticles has been confirmed with spherical morphology from transmission electron microscopy. Ag-CdSe hybrid polymer nanocomposite has been prepared chemically at different Ag concentrations. The presence of Ag in hybrid nanocomposite has been confirmed with energy-dispersive X-ray spectroscopy. The effect of varying Ag concentration on the linear and nonlinear optical properties of the nanocomposites has been studied. In linear optical parameters, the linear absorption coefficient, refractive index, extinction coefficient and optical conductivity have been calculated. The third-order nonlinear optical properties have been observed with open- and closed-aperture Z-scan technique. The large nonlinear refractive index ∝10 -5 cm 2 /W with self-focusing behaviour is due to the combined effect of quantum confinement and thermo-optical effects. The enhanced nonlinearity with increasing Ag content is due to the surface plasmon resonance, which enhances the local electric field near the nanoparticle surface. Thus, Ag-CdSe hybrid polymer nanocomposite has favourable nonlinear optical properties for various optoelectronic applications. (orig.)

Chemical Processing Department monthly report for July 1957

Energy Technology Data Exchange (ETDEWEB)

McCune, F. K.; Johnson, W. E.; MacCready, W. K.; Warren, J. H.; Schroeder, O. C.; Groswith, C. T.; Mobley, W. N.; LaFollette, T. G.; Grim, K. G.; Shaw, H. P.; Richards, R. B.; Roberts, D. S.

1957-08-22

This report, for July 1957 from the Chemical Processing Department at HAPO, discusses the following; Production operation; Purex and Redox operation; Finished products operation; maintenance; Financial operations; facilities engineering; research; and employee relations.

Chemical Processing Department monthly report for December 1958

Energy Technology Data Exchange (ETDEWEB)

1959-01-21

This report for December 1958, from the Chemical Processing Department at HAPO, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance: Financial operations; facilities engineering; research; and employee relations.

Chemical Processing Department monthly report for February 1959

Energy Technology Data Exchange (ETDEWEB)

1959-03-20

This report for February 1959, from the Chemical Processing Department at HAPO, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance: Financial operations; facilities engineering; research; and employee relations.

Definition of distance for nonlinear time series analysis of marked point process data

Energy Technology Data Exchange (ETDEWEB)

Iwayama, Koji, E-mail: koji@sat.t.u-tokyo.ac.jp [Research Institute for Food and Agriculture, Ryukoku Univeristy, 1-5 Yokotani, Seta Oe-cho, Otsu-Shi, Shiga 520-2194 (Japan); Hirata, Yoshito; Aihara, Kazuyuki [Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505 (Japan)

2017-01-30

Marked point process data are time series of discrete events accompanied with some values, such as economic trades, earthquakes, and lightnings. A distance for marked point process data allows us to apply nonlinear time series analysis to such data. We propose a distance for marked point process data which can be calculated much faster than the existing distance when the number of marks is small. Furthermore, under some assumptions, the Kullback–Leibler divergences between posterior distributions for neighbors defined by this distance are small. We performed some numerical simulations showing that analysis based on the proposed distance is effective. - Highlights: • A new distance for marked point process data is proposed. • The distance can be computed fast enough for a small number of marks. • The method to optimize parameter values of the distance is also proposed. • Numerical simulations indicate that the analysis based on the distance is effective.

A ''master key'' to chemical separation processes

International Nuclear Information System (INIS)

Madic, Ch.; Hill, C.

2002-01-01

One of the keys to sorting nuclear waste is extracting minor actinides - the most troublesome long-lived elements - from the flow of waste by separating them from lanthanides, which have very similar chemical properties to actinides, for possible transmutation into shorter-lived elements. Thanks to a European initiative coordinated by CEA, this key is now available: its name is Sanex. There now remains to develop tough, straightforward industrial processes to integrate it into a new nuclear waste management approach by 2005. Sanex joins the Diamex process, used for the combined separation of lanthanides and minor actinides from fission products. A third process, Sesame, designed to separate americium, completes the list of available separation processes. (authors)

Ultrafast nonlinear optics

CERN Document Server

Leburn, Christopher; Reid, Derryck

2013-01-01

The field of ultrafast nonlinear optics is broad and multidisciplinary, and encompasses areas concerned with both the generation and measurement of ultrashort pulses of light, as well as those concerned with the applications of such pulses. Ultrashort pulses are extreme events – both in terms of their durations, and also the high peak powers which their short durations can facilitate. These extreme properties make them powerful experiment tools. On one hand, their ultrashort durations facilitate the probing and manipulation of matter on incredibly short timescales. On the other, their ultrashort durations can facilitate high peak powers which can drive highly nonlinear light-matter interaction processes. Ultrafast Nonlinear Optics covers a complete range of topics, both applied and fundamental in nature, within the area of ultrafast nonlinear optics. Chapters 1 to 4 are concerned with the generation and measurement of ultrashort pulses. Chapters 5 to 7 are concerned with fundamental applications of ultrasho...

Highly nonlinear sub-micron silicon nitride trench waveguide coated with gold nanoparticles

Science.gov (United States)

Huang, Yuewang; Zhao, Qiancheng; Sharac, Nicholas; Ragan, Regina; Boyraz, Ozdal

2015-05-01

We demonstrate the fabrication of a highly nonlinear sub-micron silicon nitride trench waveguide coated with gold nanoparticles for plasmonic enhancement. The average enhancement effect is evaluated by measuring the spectral broadening effect caused by self-phase-modulation. The nonlinear refractive index n2 was measured to be 7.0917×10-19 m2/W for a waveguide whose Wopen is 5 μm. Several waveguides at different locations on one wafer were measured in order to take the randomness of the nanoparticle distribution into consideration. The largest enhancement is measured to be as high as 10 times. Fabrication of this waveguide started with a MEMS grade photomask. By using conventional optical lithography, the wide linewidth was transferred to a wafer. Then the wafer was etched anisotropically by potassium hydroxide (KOH) to engrave trapezoidal trenches with an angle of 54.7º. Side wall roughness was mitigated by KOH etching and thermal oxidation that was used to generate a buffer layer for silicon nitride waveguide. The guiding material silicon nitride was then deposited by low pressure chemical vapor deposition. The waveguide was then patterned with a chemical template, with 20 nm gold particles being chemically attached to the functionalized poly(methyl methacrylate) domains. Since the particles attached only to the PMMA domains, they were confined to localized regions, therefore forcing the nanoparticles into clusters of various numbers and geometries. Experiments reveal that the waveguide has negligible nonlinear absorption loss, and its nonlinear refractive index can be greatly enhanced by gold nano clusters. The silicon nitride trench waveguide has large nonlinear refractive index, rendering itself promising for nonlinear applications.

The main chemical safety problems in main process of nuclear fuel reprocessing plant

International Nuclear Information System (INIS)

Song Fengli; Zhao Shangui; Liu Xinhua; Zhang Chunlong; Lu Dan; Liu Yuntao; Yang Xiaowei; Wang Shijun

2014-01-01

There are many chemical reactions in the aqueous process of nuclear fuel reprocessing. The reaction conditions and the products are different so that the chemical safety problems are different. In the paper the chemical reactions in the aqueous process of nuclear fuel reprocessing are described and the main chemical safety problems are analyzed. The reference is offered to the design and accident analysis of the nuclear fuel reprocessing plant. (authors)

Generalized Nonlinear Yule Models

Science.gov (United States)

Lansky, Petr; Polito, Federico; Sacerdote, Laura

2016-11-01

With the aim of considering models related to random graphs growth exhibiting persistent memory, we propose a fractional nonlinear modification of the classical Yule model often studied in the context of macroevolution. Here the model is analyzed and interpreted in the framework of the development of networks such as the World Wide Web. Nonlinearity is introduced by replacing the linear birth process governing the growth of the in-links of each specific webpage with a fractional nonlinear birth process with completely general birth rates. Among the main results we derive the explicit distribution of the number of in-links of a webpage chosen uniformly at random recognizing the contribution to the asymptotics and the finite time correction. The mean value of the latter distribution is also calculated explicitly in the most general case. Furthermore, in order to show the usefulness of our results, we particularize them in the case of specific birth rates giving rise to a saturating behaviour, a property that is often observed in nature. The further specialization to the non-fractional case allows us to extend the Yule model accounting for a nonlinear growth.

Chemical aspects of nuclear fuel fabrication processes

Energy Technology Data Exchange (ETDEWEB)

Naylor, A; Ellis, J F; Watson, R H

1986-04-01

Processes used by British Nuclear Fuels plc for the conversion of uranium ore concentrates to uranium metal and uranium hexafluoride, are reviewed. Means of converting the latter compound, after enrichment, to sintered UO/sub 2/ fuel bodies are also described. An overview is given of the associated chemical engineering technology.

Best practices in incident investigation in the chemical process industries with examples from the industry sector and specifically from Nova Chemicals

International Nuclear Information System (INIS)

Morrison, Lisa M.

2004-01-01

This paper will summarize best practices in incident investigation in the chemical process industries and will provide examples from both the industry sector and specifically from NOVA Chemicals. As a sponsor of the Center for Chemical Process Safety (CCPS), an industry technology alliance of the American Institute of Chemical Engineers, NOVA Chemicals participates in a number of working groups to help develop best practices and tools for the chemical process and associated industries in order to advance chemical process safety. A recent project was to develop an update on guidelines for investigating chemical process incidents. A successful incident investigation management system must ensure that all incidents and near misses are reported, that root causes are identified, that recommendations from incident investigations identify appropriate preventive measures, and that these recommendations are resolved in a timely manner. The key elements of an effective management system for incident investigation will be described. Accepted definitions of such terms as near miss, incident, and root cause will be reviewed. An explanation of the types of incident classification systems in use, along with expected levels of follow-up, will be provided. There are several incident investigation methodologies in use today by members of the CCPS; most of these methodologies incorporate the use of several tools. These tools include: timelines, sequence diagrams, causal factor identification, brainstorming, checklists, pre-defined trees, and team-defined logic trees. Developing appropriate recommendations and then ensuring their resolution is the key to prevention of similar events from recurring, along with the sharing of lessons learned from incidents. There are several sources of information on previous incidents and lessons learned available to companies. In addition, many companies in the chemical process industries use their own internal databases to track recommendations from

Stability analysis of embedded nonlinear predictor neural generalized predictive controller

Directory of Open Access Journals (Sweden)

Hesham F. Abdel Ghaffar

2014-03-01

Full Text Available Nonlinear Predictor-Neural Generalized Predictive Controller (NGPC is one of the most advanced control techniques that are used with severe nonlinear processes. In this paper, a hybrid solution from NGPC and Internal Model Principle (IMP is implemented to stabilize nonlinear, non-minimum phase, variable dead time processes under high disturbance values over wide range of operation. Also, the superiority of NGPC over linear predictive controllers, like GPC, is proved for severe nonlinear processes over wide range of operation. The necessary conditions required to stabilize NGPC is derived using Lyapunov stability analysis for nonlinear processes. The NGPC stability conditions and improvement in disturbance suppression are verified by both simulation using Duffing’s nonlinear equation and real-time using continuous stirred tank reactor. Up to our knowledge, the paper offers the first hardware embedded Neural GPC which has been utilized to verify NGPC–IMP improvement in realtime.

A kernel-based approach to MIMO LPV state-space identification and application to a nonlinear process system

NARCIS (Netherlands)

Rizvi, S.Z.; Mohammadpour, J.; Toth, R.; Meskin, N.

2015-01-01

This paper first describes the development of a nonparametric identification method for linear parameter-varying (LPV) state-space models and then applies it to a nonlinear process system. The proposed method uses kernel-based least-squares support vector machines (LS-SVM). While parametric

Linear and nonlinear dynamics of heart rate variability in the process of exposure to 3600 m in 10 min.

Science.gov (United States)

Zhang, Da; She, Jin; Yang, Jun; Yu, Mengsun

2015-06-01

Acute hypoxia activates several autonomic mechanisms, mainly in cardiovascular system and respiratory system. The influence of acute hypoxia on linear and nonlinear heart rate variability (HRV) has been studied, but the parameters in the process of hypoxia are still unclear. Although the changes of HRV in frequency domain are related to autonomic responses, how nonlinear dynamics change with the decrease of ambient atmospheric pressure is unknown either. Eight healthy male subjects were exposed to simulated altitude from sea level to 3600 m in 10 min. HRV parameters in frequency domain were analyzed by wavelet packet transform (Daubechies 4, 4 level) followed by Hilbert transform to assess the spectral power of modified low frequency (0.0625-0.1875 Hz, LFmod), modified high frequency (0.1875-0.4375 Hz, HFmod), and the LFmod/HFmod ratio in every 1 min. Nonlinear parameters were also quantified by sample entropy (SampEn) and short term fractal correlation exponent (α1) in the process. Hypoxia was associated with the depression of both LFmod and HFmod component. They were significantly lower than that at sea level at 3600 m and 2880 m respectively (both p nonlinear HRV parameters continuously in the process of hypoxia would be an effective way to evaluate the different regulatory mechanisms of autonomic nervous system.

Nonlinear Michelson interferometer for improved quantum metrology

OpenAIRE

Luis, Alfredo; Rivas, Ángel

2015-01-01

We examine quantum detection via a Michelson interferometer embedded in a gas with Kerr nonlinearity. This nonlinear interferometer is illuminated by pulses of classical light. This strategy combines the robustness against practical imperfections of classical light with the improvement provided by nonlinear processes. Regarding ultimate quantum limits, we stress that, as a difference with linear schemes, the nonlinearity introduces pulse duration as a new variable into play along with the ene...

A Comparative Study of Applying Active-Set and Interior Point Methods in MPC for Controlling Nonlinear pH Process

Directory of Open Access Journals (Sweden)

Syam Syafiie

2014-06-01

Full Text Available A comparative study of Model Predictive Control (MPC using active-set method and interior point methods is proposed as a control technique for highly non-linear pH process. The process is a strong acid-strong base system. A strong acid of hydrochloric acid (HCl and a strong base of sodium hydroxide (NaOH with the presence of buffer solution sodium bicarbonate (NaHCO3 are used in a neutralization process flowing into reactor. The non-linear pH neutralization model governed in this process is presented by multi-linear models. Performance of both controllers is studied by evaluating its ability of set-point tracking and disturbance-rejection. Besides, the optimization time is compared between these two methods; both MPC shows the similar performance with no overshoot, offset, and oscillation. However, the conventional active-set method gives a shorter control action time for small scale optimization problem compared to MPC using IPM method for pH control.

Nonlinear laser-plasma interactions

Science.gov (United States)

Kaw, P. K.

2017-12-01

Soon after lasers were invented, there was tremendous curiosity on the nonlinear phenomena which would result in their interaction with a fully ionized plasma. Apart from the basic interest, it was realized that it could be used for the achievement of nuclear fusion in the laboratory. This led us to a paper on the propagation of a laser beam into an inhomogeneous fusion plasma, where it was first demonstrated that light would go up to the critical layer (where the frequency matches the plasma frequency) and get reflected from there with a reflection coefficient of order unity. The reflection coefficient was determined by collisional effects. Since the wave was expected to slow down to near zero group speed at the reflection point, the dominant collision frequency determining the reflection coefficient was the collision frequency at the reflection point. It turned out that the absorption of light was rather small for fusion temperatures. This placed a premium on investigation of nonlinear phenomena which might contribute to the absorption and penetration of the light into high-density plasma. An early investigation showed that electron jitter with respect to ions would be responsible for the excitation of decay instabilities which convert light waves into electrostatic plasma waves and ion waves near the critical frequency. These electrostatic waves would then get absorbed into the plasma even in the collisionless case and lead to plasma heating which is nonlinear. Detailed estimates of this heating were made. Similar nonlinear processes which could lead to stimulated scattering of light in the underdense region (ω >ω _p) were investigated together with a number of other workers. All these nonlinear processes need a critical threshold power for excitation. Another important process which was discovered around the same time had to do with filamentation and trapping of light when certain thresholds were exceeded. All of this work has been extensively verified in

Nonlinear optics of liquid crystalline materials

International Nuclear Information System (INIS)

Khoo, Iam Choon

2009-01-01

Liquid crystals occupy an important niche in nonlinear optics as a result of their unique physical and optical properties. Besides their broadband birefringence and transparency, abilities to self-assemble into various crystalline phases and to conform to various flexible forms and shapes, liquid crystals are compatible with almost all other optoelectronic materials and technology platforms. In both isotropic and ordered phases, liquid crystals possess extraordinarily large optical nonlinearities that stretch over multiple time scales. To date, almost all conceivable nonlinear optical phenomena have been observed in a very broad spectrum spanning the entire visible to infrared and beyond. In this review, we present a self-contained complete discussion of the optical nonlinearities of liquid crystals, and a thorough review of a wide range of nonlinear optical processes and phenomena enabled by these unique properties. Starting with a brief historical account of the development of nonlinear optical studies of the mesophases of liquid crystals, we then review various liquid crystalline materials and structures, and their nonlinear optical properties. Emphasis is placed on the nematic phase, which best exemplifies the dual nature of liquid crystals, although frequent references to other phases are also made. We also delve into recent work on novel structures such as photonic crystals, metamaterials and nanostructures and their special characteristics and emergent properties. The mechanisms and complex nonlocal dynamics of optical nonlinearities associated with laser induced director axis reorientation, thermal, density, and order parameter fluctuations, space charge field formation and photorefractivity are critically reviewed as a foundation for the discussions of various nonlinear optical processes detailed in this paper

Nonlinear control of a multicomponent distillation process coupled with a binary distillation model as an EKF predictor.

Science.gov (United States)

Jana, Amiya Kumar; Ganguly, Saibal; Samanta, Amar Nath

2006-10-01

The work is devoted to design the globally linearizing control (GLC) strategy for a multicomponent distillation process. The control system is comprised with a nonlinear transformer, a nonlinear closed-loop state estimator [extended Kalman filter (EKF)], and a linear external controller [conventional proportional integral (PI) controller]. The model of a binary distillation column has been used as a state predictor to avoid huge design complexity of the EKF estimator. The binary components are the light key and the heavy key of the multicomponent system. The proposed GLC-EKF (GLC in conjunction with EKF) control algorithm has been compared with the GLC-ROOLE [GLC coupled with reduced-order open-loop estimator (ROOLE)] and the dual-loop PI controller based on set point tracking and disturbance rejection performance. Despite huge process/predictor mismatch, the superiority of the GLC-EKF has been inspected over the GLC-ROOLE control structure.

Naturally stable Sagnac-Michelson nonlinear interferometer.

Science.gov (United States)

Lukens, Joseph M; Peters, Nicholas A; Pooser, Raphael C

2016-12-01

Interferometers measure a wide variety of dynamic processes by converting a phase change into an intensity change. Nonlinear interferometers, making use of nonlinear media in lieu of beamsplitters, promise substantial improvement in the quest to reach the ultimate sensitivity limits. Here we demonstrate a new nonlinear interferometer utilizing a single parametric amplifier for mode mixing-conceptually, a nonlinear version of the conventional Michelson interferometer with its arms collapsed together. We observe up to 99.9% interference visibility and find evidence for noise reduction based on phase-sensitive gain. Our configuration utilizes fewer components than previous demonstrations and requires no active stabilization, offering new capabilities for practical nonlinear interferometric-based sensors.

Applications of nonlinear fiber optics

CERN Document Server

Agrawal, Govind

2008-01-01

* The only book describing applications of nonlinear fiber optics * Two new chapters on the latest developments: highly nonlinear fibers and quantum applications* Coverage of biomedical applications* Problems provided at the end of each chapterThe development of new highly nonlinear fibers - referred to as microstructured fibers, holey fibers and photonic crystal fibers - is the next generation technology for all-optical signal processing and biomedical applications. This new edition has been thoroughly updated to incorporate these key technology developments.The bo

Inferring Instantaneous, Multivariate and Nonlinear Sensitivities for the Analysis of Feedback Processes in a Dynamical System: Lorenz Model Case Study

Science.gov (United States)

Aires, Filipe; Rossow, William B.; Hansen, James E. (Technical Monitor)

2001-01-01

A new approach is presented for the analysis of feedback processes in a nonlinear dynamical system by observing its variations. The new methodology consists of statistical estimates of the sensitivities between all pairs of variables in the system based on a neural network modeling of the dynamical system. The model can then be used to estimate the instantaneous, multivariate and nonlinear sensitivities, which are shown to be essential for the analysis of the feedbacks processes involved in the dynamical system. The method is described and tested on synthetic data from the low-order Lorenz circulation model where the correct sensitivities can be evaluated analytically.

Influence of surface coverage on the chemical desorption process

Energy Technology Data Exchange (ETDEWEB)

Minissale, M.; Dulieu, F., E-mail: francois.dulieu@obspm.fr [LERMA, Université de Cergy Pontoise et Observatoire de Paris, UMR 8112 du CNRS. 5, mail Gay Lussac, 95031 Cergy Pontoise (France)

2014-07-07

In cold astrophysical environments, some molecules are observed in the gas phase whereas they should have been depleted, frozen on dust grains. In order to solve this problem, astrochemists have proposed that a fraction of molecules synthesized on the surface of dust grains could desorb just after their formation. Recently the chemical desorption process has been demonstrated experimentally, but the key parameters at play have not yet been fully understood. In this article, we propose a new procedure to analyze the ratio of di-oxygen and ozone synthesized after O atoms adsorption on oxidized graphite. We demonstrate that the chemical desorption efficiency of the two reaction paths (O+O and O+O{sub 2}) is different by one order of magnitude. We show the importance of the surface coverage: for the O+O reaction, the chemical desorption efficiency is close to 80% at zero coverage and tends to zero at one monolayer coverage. The coverage dependence of O+O chemical desorption is proved by varying the amount of pre-adsorbed N{sub 2} on the substrate from 0 to 1.5 ML. Finally, we discuss the relevance of the different physical parameters that could play a role in the chemical desorption process: binding energy, enthalpy of formation, and energy transfer from the new molecule to the surface or to other adsorbates.

Fault detection for nonlinear systems - A standard problem approach

DEFF Research Database (Denmark)

Stoustrup, Jakob; Niemann, Hans Henrik

1998-01-01

The paper describes a general method for designing (nonlinear) fault detection and isolation (FDI) systems for nonlinear processes. For a rich class of nonlinear systems, a nonlinear FDI system can be designed using convex optimization procedures. The proposed method is a natural extension...

Noninvasive label-free monitoring of cosmetics and pharmaceuticals in human skin using nonlinear optical microscopy (Conference Presentation)

Science.gov (United States)

Osseiran, Sam; Wang, Hequn; Evans, Conor L.

2017-02-01

Over the past decade, nonlinear optical microscopy has seen a dramatic rise in its use in research settings due to its noninvasiveness, enhanced penetration depth, intrinsic optical sectioning, and the ability to probe chemical compounds with molecular specificity without exogenous contrast agents. Nonlinear optical techniques including two-photon excitation fluorescence (2PEF), fluorescence lifetime imaging microscopy (FLIM), second harmonic generation (SHG), coherent anti-Stokes and stimulated Raman scattering (CARS and SRS, respectively), as well as transient and sum frequency absorption (TA and SFA, respectively), have been widely used to explore the physiology and microanatomy of skin. Recently, these modalities have shed light on dermal processes that could not have otherwise been observed, including the spatiotemporal monitoring of cosmetics and pharmaceuticals. However, a challenge quickly arises when studying such chemicals in a dermatological context: many exogenous compounds have optical signatures that can interfere with the signals that would otherwise be acquired from intact skin. For example, oily solvents exhibit strong signals when probing CH2 vibrations with CARS/SRS; chemical sun filters appear bright in 2PEF microscopy; and darkly colored compounds readily absorb light across a broad spectrum, producing strong TA/SFA signals. Thus, this discussion will first focus on the molecular contrast in skin that can be probed using the aforementioned nonlinear optical techniques. This will be followed by an overview of strategies that take advantage of the exogenous compounds' optical signatures to probe spatiotemporal dynamics while preserving endogenous information from skin.

Statistical process control support during Defense Waste Processing Facility chemical runs

International Nuclear Information System (INIS)

Brown, K.G.

1994-01-01

The Product Composition Control System (PCCS) has been developed to ensure that the wasteforms produced by the Defense Waste Processing Facility (DWPF) at the Savannah River Site (SRS) will satisfy the regulatory and processing criteria that will be imposed. The PCCS provides rigorous, statistically-defensible management of a noisy, multivariate system subject to multiple constraints. The system has been successfully tested and has been used to control the production of the first two melter feed batches during DWPF Chemical Runs. These operations will demonstrate the viability of the DWPF process. This paper provides a brief discussion of the technical foundation for the statistical process control algorithms incorporated into PCCS, and describes the results obtained and lessons learned from DWPF Cold Chemical Run operations. The DWPF will immobilize approximately 130 million liters of high-level nuclear waste currently stored at the Site in 51 carbon steel tanks. Waste handling operations separate this waste into highly radioactive sludge and precipitate streams and less radioactive water soluble salts. (In a separate facility, soluble salts are disposed of as low-level waste in a mixture of cement slag, and flyash.) In DWPF, the precipitate steam (Precipitate Hydrolysis Aqueous or PHA) is blended with the insoluble sludge and ground glass frit to produce melter feed slurry which is continuously fed to the DWPF melter. The melter produces a molten borosilicate glass which is poured into stainless steel canisters for cooling and, ultimately, shipment to and storage in a geologic repository

Performance of Globally Linearized Controller and Two Region Fuzzy Logic Controller on a Nonlinear Process

Directory of Open Access Journals (Sweden)

N. Jaya

2008-10-01

Full Text Available In this work, a design and implementation of a Conventional PI controller, single region fuzzy logic controller, two region fuzzy logic controller and Globally Linearized Controller (GLC for a two capacity interacting nonlinear process is carried out. The performance of this process using single region FLC, two region FLC and GLC are compared with the performance of conventional PI controller about an operating point of 50 %. It has been observed that GLC and two region FLC provides better performance. Further, this procedure is also validated by real time experimentation using dSPACE.

Nonlinear dynamics of three-magnon process driven by ferromagnetic resonance in yttrium iron garnet

Energy Technology Data Exchange (ETDEWEB)

Cunha, R. O. [Departamento de Física, Universidade Federal de Pernambuco, 50670-901 Recife, PE (Brazil); Centro Interdisciplinar de Ciências da Natureza, Universidade Federal da Integração Latino-Americana, 85867-970 Foz do Iguaçu, PR (Brazil); Holanda, J.; Azevedo, A.; Rezende, S. M., E-mail: rezende@df.ufpe.br [Departamento de Física, Universidade Federal de Pernambuco, 50670-901 Recife, PE (Brazil); Vilela-Leão, L. H. [Departamento de Física, Universidade Federal de Pernambuco, 50670-901 Recife, PE (Brazil); Centro Acadêmico do Agreste, Universidade Federal de Pernambuco, 55002-970 Caruaru, PE (Brazil); Rodríguez-Suárez, R. L. [Facultad de Física, Pontificia Universidad Católica de Chile, Casilla 306, Santiago (Chile)

2015-05-11

We report an investigation of the dynamics of the three-magnon splitting process associated with the ferromagnetic resonance (FMR) in films of the insulating ferrimagnet yttrium iron garnet (YIG). The experiments are performed with a 6 μm thick YIG film close to a microstrip line fed by a microwave generator operating in the 2–6 GHz range. The magnetization precession is driven by the microwave rf magnetic field perpendicular to the static magnetic field, and its dynamics is observed by monitoring the amplitude of the FMR absorption peak. The time evolution of the amplitude reveals that if the frequency is lowered below a critical value of 3.3 GHz, the FMR mode pumps two magnons with opposite wave vectors that react back on the FMR, resulting in a nonlinear dynamics of the magnetization. The results are explained by a model with coupled nonlinear equations describing the time evolution of the magnon modes.

Enrichment of 15N and 10B isotopes by chemical exchange process

International Nuclear Information System (INIS)

D'Souza, A.B.; Sonwalkar, A.S.; Subrahmanyam, B.V.; Valladares, B.A.

1994-01-01

Many processes are available for separation of stable isotopes like distillation, chemical exchange, thermal diffusion, gaseous diffusion, centrifuge etc. Chemical exchange process is eminently suitable for separation of isotopes of light elements. Work done on separation and enrichment of two of the stable isotopes viz. 15 N and 10 B in Chemical Engineering Division is presented. 15 N is widely used as a tracer in agricultural research and 10 B is used in nuclear industry as control rod material, soluble reactor poison, neutron detector etc. The work on 15 N isotope resulted in a pilot plant, which was the only source of this material in the country for many years and later it was translated into a production plant as M/s. RCF Ltd. The work done on the ion-exchange process for enrichment of 10 B isotope which is basically a chemical exchange process, is now being updated into a pilot plant to produce enriched 10 B to be used as soluble reactor poison. (author)

A Quasi-Dynamic Optimal Control Strategy for Non-Linear Multivariable Processes Based upon Non-Quadratic Objective Functions

Directory of Open Access Journals (Sweden)

Jens G. Balchen

1984-10-01

Full Text Available The problem of systematic derivation of a quasi-dynamic optimal control strategy for a non-linear dynamic process based upon a non-quadratic objective function is investigated. The wellknown LQG-control algorithm does not lead to an optimal solution when the process disturbances have non-zero mean. The relationships between the proposed control algorithm and LQG-control are presented. The problem of how to constrain process variables by means of 'penalty' - terms in the objective function is dealt with separately.

Brain Emotional Learning Based Intelligent Decoupler for Nonlinear Multi-Input Multi-Output Distillation Columns

Directory of Open Access Journals (Sweden)

M. H. El-Saify

2017-01-01

Full Text Available The distillation process is vital in many fields of chemical industries, such as the two-coupled distillation columns that are usually highly nonlinear Multi-Input Multi-Output (MIMO coupled processes. The control of MIMO process is usually implemented via a decentralized approach using a set of Single-Input Single-Output (SISO loop controllers. Decoupling the MIMO process into group of single loops requires proper input-output pairing and development of decoupling compensator unit. This paper proposes a novel intelligent decoupling approach for MIMO processes based on new MIMO brain emotional learning architecture. A MIMO architecture of Brain Emotional Learning Based Intelligent Controller (BELBIC is developed and applied as a decoupler for 4 input/4 output highly nonlinear coupled distillation columns process. Moreover, the performance of the proposed Brain Emotional Learning Based Intelligent Decoupler (BELBID is enhanced using Particle Swarm Optimization (PSO technique. The performance is compared with the PSO optimized steady state decoupling compensation matrix. Mathematical models of the distillation columns and the decouplers are built and tested in simulation environment by applying the same inputs. The results prove remarkable success of the BELBID in minimizing the loops interactions without degrading the output that every input has been paired with.

All-optical image processing with nonlinear liquid crystals

Science.gov (United States)

Hong, Kuan-Lun

Liquid crystals are fascinating materials because of several advantages such as large optical birefringence, dielectric anisotropic, and easily compatible to most kinds of materials. Compared to the electro-optical properties of liquid crystals widely applied in displays and switching application, transparency through most parts of wavelengths also makes liquid crystals a better candidate for all-optical processing. The fast response time of liquid crystals resulting from multiple nonlinear effects, such as thermal and density effect can even make real-time processing realized. In addition, blue phase liquid crystals with spontaneously self-assembled three dimensional cubic structures attracted academic attention. In my dissertation, I will divide the whole contents into six parts. In Chapter 1, a brief introduction of liquid crystals is presented, including the current progress and the classification of liquid crystals. Anisotropy and laser induced director axis reorientation is presented in Chapter 2. In Chapter 3, I will solve the electrostrictive coupled equation and analyze the laser induced thermal and density effect in both static and dynamic ways. Furthermore, a dynamic simulation of laser induced density fluctuation is proposed by applying finite element method. In Chapter 4, two image processing setups are presented. One is the intensity inversion experiment in which intensity dependent phase modulation is the mechanism. The other is the wavelength conversion experiment in which I can read the invisible image with a visible probe beam. Both experiments are accompanied with simulations to realize the matching between the theories and practical experiment results. In Chapter 5, optical properties of blue phase liquid crystals will be introduced and discussed. The results of grating diffractions and thermal refractive index gradient are presented in this chapter. In addition, fiber arrays imaging and switching with BPLCs will be included in this chapter

International Conference on Applications in Nonlinear Dynamics

CERN Document Server

Longhini, Patrick; Palacios, Antonio

2017-01-01

This book presents collaborative research works carried out by experimentalists and theorists around the world in the field of nonlinear dynamical systems. It provides a forum for applications of nonlinear systems while solving practical problems in science and engineering. Topics include: Applied Nonlinear Optics, Sensor, Radar & Communication Signal Processing, Nano Devices, Nonlinear Biomedical Applications, Circuits & Systems, Coupled Nonlinear Oscillator, Precision Timing Devices, Networks, and other contemporary topics in the general field of Nonlinear Science. This book provides a comprehensive report of the various research projects presented at the International Conference on Applications in Nonlinear Dynamics (ICAND 2016) held in Denver, Colorado, 2016. It can be a valuable tool for scientists and engineering interested in connecting ideas and methods in nonlinear dynamics with actual design, fabrication and implementation of engineering applications or devices.

The implications of non-linear biological oscillations on human electrophysiology for electrohypersensitivity (EHS) and multiple chemical sensitivity (MCS).

Science.gov (United States)

Sage, Cindy

2015-01-01

The 'informational content' of Earth's electromagnetic signaling is like a set of operating instructions for human life. These environmental cues are dynamic and involve exquisitely low inputs (intensities) of critical frequencies with which all life on Earth evolved. Circadian and other temporal biological rhythms depend on these fluctuating electromagnetic inputs to direct gene expression, cell communication and metabolism, neural development, brainwave activity, neural synchrony, a diversity of immune functions, sleep and wake cycles, behavior and cognition. Oscillation is also a universal phenomenon, and biological systems of the heart, brain and gut are dependent on the cooperative actions of cells that function according to principles of non-linear, coupled biological oscillations for their synchrony. They are dependent on exquisitely timed cues from the environment at vanishingly small levels. Altered 'informational content' of environmental cues can swamp natural electromagnetic cues and result in dysregulation of normal biological rhythms that direct growth, development, metabolism and repair mechanisms. Pulsed electromagnetic fields (PEMF) and radiofrequency radiation (RFR) can have the devastating biological effects of disrupting homeostasis and desynchronizing normal biological rhythms that maintain health. Non-linear, weak field biological oscillations govern body electrophysiology, organize cell and tissue functions and maintain organ systems. Artificial bioelectrical interference can give false information (disruptive signaling) sufficient to affect critical pacemaker cells (of the heart, gut and brain) and desynchronize functions of these important cells that orchestrate function and maintain health. Chronic physiological stress undermines homeostasis whether it is chemically induced or electromagnetically induced (or both exposures are simultaneous contributors). This can eventually break down adaptive biological responses critical to health

Engineering high-order nonlinear dissipation for quantum superconducting circuits

Science.gov (United States)

Mundhada, S. O.; Grimm, A.; Touzard, S.; Shankar, S.; Minev, Z. K.; Vool, U.; Mirrahimi, M.; Devoret, M. H.

Engineering nonlinear driven-dissipative processes is essential for quantum control. In the case of a harmonic oscillator, nonlinear dissipation can stabilize a decoherence-free manifold, leading to protected quantum information encoding. One possible approach to implement such nonlinear interactions is to combine the nonlinearities provided by Josephson circuits with parametric pump drives. However, it is usually hard to achieve strong nonlinearities while avoiding undesired couplings. Here we propose a scheme to engineer a four-photon drive and dissipation in a harmonic oscillator by cascading experimentally demonstrated two-photon processes. We also report experimental progress towards realization of such a scheme. Work supported by: ARO, ONR, AFOSR and YINQE.

Nonlinear physics of shear Alfvén waves

International Nuclear Information System (INIS)

Zonca, Fulvio; Chen, Liu

2014-01-01

Shear Alfvén waves (SAW) play fundamental roles in thermonuclear plasmas of fusion interest, since they are readily excited by energetic particles in the MeV range as well as by the thermal plasma components. Thus, understanding fluctuation induced transport in burning plasmas requires understanding nonlinear SAW physics. There exist two possible routes to nonlinear SAW physics: (i) wave-wave interactions and the resultant spectral energy transfer; (ii) nonlinear wave-particle interactions of SAW instabilities with energetic particles. Within the first route, it is advantageous to understand and describe nonlinear processes in term of proximity of the system to the Alfvénic state, where wave-wave interactions are minimized due to the cancellation of Reynolds and Maxwell stresses. Here, various wave-wave nonlinear dynamics are elucidated in terms of how they break the Alfvénic state. In particular, we discuss the qualitative and quantitative modification of the SAW parametric decay process due to finite ion compressibility and finite ion Larmor radius. We also show that toroidal geometry plays a crucial role in the nonlinear excitation of zonal structures by Alfvén eigenmodes. Within the second route, the coherent nonlinear dynamics of structures in the energetic particle phase space, by which secular resonant particle transport can occur on meso- and macro-scales, must be addressed and understood. These 'nonlinear equilibria' or 'phase-space zonal structures' dynamically evolve on characteristic (fluctuation induced) turbulent transport time scales, which are generally of the same order of the nonlinear time scale of the underlying fluctuations. In this work, we introduce the general structure of nonlinear Schrödinger equations with complex integro-differential nonlinear terms, which govern these physical processes. To elucidate all these aspects, theoretical analyses are presented together with numerical simulation results

Nonlinear physics of shear Alfvén waves

Science.gov (United States)

Zonca, Fulvio; Chen, Liu

2014-02-01

Shear Alfvén waves (SAW) play fundamental roles in thermonuclear plasmas of fusion interest, since they are readily excited by energetic particles in the MeV range as well as by the thermal plasma components. Thus, understanding fluctuation induced transport in burning plasmas requires understanding nonlinear SAW physics. There exist two possible routes to nonlinear SAW physics: (i) wave-wave interactions and the resultant spectral energy transfer; (ii) nonlinear wave-particle interactions of SAW instabilities with energetic particles. Within the first route, it is advantageous to understand and describe nonlinear processes in term of proximity of the system to the Alfvénic state, where wave-wave interactions are minimized due to the cancellation of Reynolds and Maxwell stresses. Here, various wave-wave nonlinear dynamics are elucidated in terms of how they break the Alfvénic state. In particular, we discuss the qualitative and quantitative modification of the SAW parametric decay process due to finite ion compressibility and finite ion Larmor radius. We also show that toroidal geometry plays a crucial role in the nonlinear excitation of zonal structures by Alfvén eigenmodes. Within the second route, the coherent nonlinear dynamics of structures in the energetic particle phase space, by which secular resonant particle transport can occur on meso- and macro-scales, must be addressed and understood. These "nonlinear equilibria" or "phase-space zonal structures" dynamically evolve on characteristic (fluctuation induced) turbulent transport time scales, which are generally of the same order of the nonlinear time scale of the underlying fluctuations. In this work, we introduce the general structure of nonlinear Schrödinger equations with complex integro-differential nonlinear terms, which govern these physical processes. To elucidate all these aspects, theoretical analyses are presented together with numerical simulation results.

Chemical Processing Department monthly report for February 1957

Energy Technology Data Exchange (ETDEWEB)

1957-03-21

This report from the Chemical Processing Department at HAPO, discusses the following: Production operation, purex operation, redox operation, finished products operation, power and general maintenance operation, financial operation, facilities engineering operation, research and engineering operation, and employee relations operation.

Alternative Processes for Water Reclamation and Solid Waste Processing in a Physical/chemical Bioregenerative Life Support System

Science.gov (United States)

Rogers, Tom D.

1990-01-01

Viewgraphs on alternative processes for water reclamation and solid waste processing in a physical/chemical-bioregenerative life support system are presented. The main objective is to focus attention on emerging influences of secondary factors (i.e., waste composition, type and level of chemical contaminants, and effects of microorganisms, primarily bacteria) and to constructively address these issues by discussing approaches which attack them in a direct manner.

Quantification of chemical transport processes from the soil to surface runoff.

Science.gov (United States)

Tian, Kun; Huang, Chi-Hua; Wang, Guang-Qian; Fu, Xu-Dong; Parker, Gary

2013-01-01

There is a good conceptual understanding of the processes that govern chemical transport from the soil to surface runoff, but few studies have actually quantified these processes separately. Thus, we designed a laboratory flow cell and experimental procedures to quantify the chemical transport from soil to runoff water in the following individual processes: (i) convection with a vertical hydraulic gradient, (ii) convection via surface flow or the Bernoulli effect, (iii) diffusion, and (iv) soil loss. We applied different vertical hydraulic gradients by setting the flow cell to generate different seepage or drainage conditions. Our data confirmed the general form of the convection-diffusion equation. However, we now have additional quantitative data that describe the contribution of each individual chemical loading process in different surface runoff and soil hydrological conditions. The results of this study will be useful for enhancing our understanding of different geochemical processes in the surface soil mixing zone. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Nonlinear Optics and Applications

Science.gov (United States)

Abdeldayem, Hossin A. (Editor); Frazier, Donald O. (Editor)

2007-01-01

Nonlinear optics is the result of laser beam interaction with materials and started with the advent of lasers in the early 1960s. The field is growing daily and plays a major role in emerging photonic technology. Nonlinear optics play a major role in many of the optical applications such as optical signal processing, optical computers, ultrafast switches, ultra-short pulsed lasers, sensors, laser amplifiers, and many others. This special review volume on Nonlinear Optics and Applications is intended for those who want to be aware of the most recent technology. This book presents a survey of the recent advances of nonlinear optical applications. Emphasis will be on novel devices and materials, switching technology, optical computing, and important experimental results. Recent developments in topics which are of historical interest to researchers, and in the same time of potential use in the fields of all-optical communication and computing technologies, are also included. Additionally, a few new related topics which might provoke discussion are presented. The book includes chapters on nonlinear optics and applications; the nonlinear Schrodinger and associated equations that model spatio-temporal propagation; the supercontinuum light source; wideband ultrashort pulse fiber laser sources; lattice fabrication as well as their linear and nonlinear light guiding properties; the second-order EO effect (Pockels), the third-order (Kerr) and thermo-optical effects in optical waveguides and their applications in optical communication; and, the effect of magnetic field and its role in nonlinear optics, among other chapters.

Nonlinearities in Periodic Structures and Metamaterials

CERN Document Server

Denz, Cornelia; Kivshar, Yuri S

2010-01-01

Optical information processing of the future is associated with a new generation of compact nanoscale optical devices operating entirely with light. Moreover, adaptive features such as self-guiding, reconfiguration and switching become more and more important. Nonlinear devices offer an enormous potential for these applications. Consequently, innovative concepts for all-optical communication and information technologies based on nonlinear effects in photonic-crystal physics and nanoscale devices as metamaterials are of high interest. This book focuses on nonlinear optical phenomena in periodic media, such as photonic crystals, optically-induced, adaptive lattices, atomic lattices or metamaterials. The main purpose is to describe and overview new physical phenomena that result from the interplay between nonlinearities and structural periodicities and is a guide to actual and future developments for the expert reader in optical information processing, as well as in the physics of cold atoms in optical lattices.

Chemical Processing Department monthly report for September 1963

Energy Technology Data Exchange (ETDEWEB)

1963-10-21

This report, from the Chemical Processing Department at HAPO for September 1963, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance; Financial operations, facilities engineering; research; employee relations; weapons manufacturing operation; and power and crafts operation.

DWPF nitric-glycolic flowsheet chemical process cell chemistry. Part 1

Energy Technology Data Exchange (ETDEWEB)

Zamecnik, J. R. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Edwards, T. B. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2016-02-01

The conversions of nitrite to nitrate, the destruction of glycolate, and the conversion of glycolate to formate and oxalate were modeled for the Nitric-Glycolic flowsheet using data from Chemical Process Cell (CPC) simulant runs conducted by SRNL from 2011 to 2015. The goal of this work was to develop empirical correlations for these variables versus measureable variables from the chemical process so that these quantities could be predicted a-priori from the sludge composition and measurable processing variables. The need for these predictions arises from the need to predict the REDuction/OXidation (REDOX) state of the glass from the Defense Waste Processing Facility (DWPF) melter. This report summarizes the initial work on these correlations based on the aforementioned data. Further refinement of the models as additional data is collected is recommended.

Nonlinear switching dynamics in a photonic-crystal nanocavity

International Nuclear Information System (INIS)

Yu, Yi; Palushani, Evarist; Heuck, Mikkel; Vukovic, Dragana; Peucheret, Christophe; Yvind, Kresten; Mork, Jesper

2014-01-01

We report the experimental observation of nonlinear switching dynamics in an InP photonic crystal nanocavity. Usually, the regime of relatively small cavity perturbations is explored, where the signal transmitted through the cavity follows the temporal variation of the cavity resonance. When the cavity is perturbed by strong pulses, we observe several nonlinear effects, i.e., saturation of the switching contrast, broadening of the switching window, and even initial reduction of the transmission. The effects are analyzed by comparison with nonlinear coupled mode theory and explained in terms of large dynamical variations of the cavity resonance in combination with nonlinear losses. The results provide insight into the nonlinear optical processes that govern the dynamics of nanocavities and are important for applications in optical signal processing, where one wants to optimize the switching contrast.

Nonlinear switching dynamics in a photonic-crystal nanocavity

DEFF Research Database (Denmark)

Yu, Yi; Palushani, Evarist; Heuck, Mikkel

2014-01-01

We report the experimental observation of nonlinear switching dynamics in an InP photonic crystal nanocavity. Usually, the regime of relatively small cavity perturbations is explored, where the signal transmitted through the cavity follows the temporal variation of the cavity resonance. When...... of large dynamical variations of the cavity resonance in combination with nonlinear losses. The results provide insight into the nonlinear optical processes that govern the dynamics of nanocavities and are important for applications in optical signal processing, where one wants to optimize the switching...... the cavity is perturbed by strong pulses, we observe several nonlinear effects, i.e., saturation of the switching contrast, broadening of the switching window, and even initial reduction of the transmission. The effects are analyzed by comparison with nonlinear coupled mode theory and explained in terms...

Nonlinear quantum electrodynamic and electroweak processes in strong laser fields

Energy Technology Data Exchange (ETDEWEB)

Meuren, Sebastian

2015-06-24

Various nonlinear electrodynamic and electroweak processes in strong plane-wave laser fields are considered with an emphasis on short-pulse effects. In particular, the momentum distribution of photoproduced electron-positron pairs is calculated numerically and a semiclassical interpretation of its characteristic features is established. By proving the optical theorem, compact double-integral expressions for the total pair-creation probability are obtained and numerically evaluated. The exponential decay of the photon wave function in a plane wave is included by solving the Schwinger-Dyson equations to leading-order in the quasistatic approximation. In this respect, the polarization operator in a plane wave is investigated and its Ward-Takahashi identity verified. A classical analysis indicates that a photoproduced electron-positron pair recollides for certain initial conditions. The contributions of such recollision processes to the polarization operator are identified and calculated both analytically and numerically. Furthermore, the existence of nontrivial electron-spin dynamics induced by quantum fluctuations is verified for ultra-short laser pulses. Finally, the exchange of weak gauge bosons is considered, which is essential for neutrino-photon interactions. In particular, the axial-vector-vector coupling tensor is calculated and the so-called Adler-Bell-Jackiw (ABJ) anomaly investigated.

RESEARCH OF LINEAR AND NONLINEAR PROCESSES AT FEMTOSECOND LASER RADIATION PROPAGATION IN THE MEDIUM SIMULATING THE HUMAN EYE VITREOUS

Directory of Open Access Journals (Sweden)

P. Y. Rogov

2015-09-01

Full Text Available The paper deals with mathematical model of linear and nonlinear processes occurring at the propagation of femtosecond laser pulses in the vitreous of the human eye. Methods of computing modeling are applied for the nonlinear spectral equation solution describing the dynamics of a two-dimensional TE-polarized radiation in a homogeneous isotropic medium with cubic fast-response nonlinearity without the usage of slowly varying envelope approximation. Environments close to the optical media parameters of the eye were used for the simulation. The model of femtosecond radiation propagation takes into account the process dynamics for dispersion broadening of pulses in time and the occurence of the self-focusing near the retina when passing through the vitreous body of the eye. Dependence between the pulse duration on the retina has been revealed and the duration of the input pulse and the values of power density at which there is self-focusing have been found. It is shown that the main mechanism of radiation damage with the use of titanium-sapphire laser is photoionization. The results coincide with those obtained by the other scientists, and are usable for creation Russian laser safety standards for femtosecond laser systems.

Identification of Nonlinear Dynamic Systems Possessing Some Non-linearities

Directory of Open Access Journals (Sweden)

Y. N. Pavlov

2015-01-01

system of the second-order with nonlinearity of the type "quadratic friction" in combination with nonlinearity of the type "dry friction", was developed a software to simulate a process for providing pseudo experimental data containing random accuracy and to determine the parameters of the system. A conducted computational experiment enabled an estimate of the accuracy with which the proposed algorithm determines the parameters of the system. The illustrative numerical simulation has demonstrated that with using the proposed nonlinear dynamic system identification algorithm in frequency hodograph the accuracy of determining the coefficient values of the frequency transfer function of the second order system with a dry and quadratic friction is comparable with the range of measurement accuracy of experimental samples of this system hodograph. Well-known publications do not mention this identification method of the nonlinear dynamic systems. The nonlinear dynamical systems identification method the article describes can find application when determining parameters of various kinds of actuators. The using method of harmonic linearization and identification of dynamical systems by hodographs is promising for solving the problem of the identification of nonlinear systems with different types of nonlinearities.

Determinants of job stress in chemical process industry: A factor analysis approach.

Science.gov (United States)

Menon, Balagopal G; Praveensal, C J; Madhu, G

2015-01-01

Job stress is one of the active research domains in industrial safety research. The job stress can result in accidents and health related issues in workers in chemical process industries. Hence it is important to measure the level of job stress in workers so as to mitigate the same to avoid the worker's safety related problems in the industries. The objective of this study is to determine the job stress factors in the chemical process industry in Kerala state, India. This study also aims to propose a comprehensive model and an instrument framework for measuring job stress levels in the chemical process industries in Kerala, India. The data is collected through a questionnaire survey conducted in chemical process industries in Kerala. The collected data out of 1197 surveys is subjected to principal component and confirmatory factor analysis to develop the job stress factor structure. The factor analysis revealed 8 factors that influence the job stress in process industries. It is also found that the job stress in employees is most influenced by role ambiguity and the least by work environment. The study has developed an instrument framework towards measuring job stress utilizing exploratory factor analysis and structural equation modeling.

Secondary cleanup of Idaho Chemical Processing Plant solvent

International Nuclear Information System (INIS)

Mailen, J.C.

1985-01-01

Solvent from the Idaho Chemical Processing Plant (ICPP) (operated by Westinghouse Idaho Nuclear Company, Inc.) has been tested to determine the ability of activated alumina to remove secondary degradation products - those degradation products which are not removed by scrubbing with sodium carbonate

Sustainable chemical processing and energy-carbon dioxide management: review of challenges and opportunities

DEFF Research Database (Denmark)

Frauzem, Rebecca; Vooradi, Ramsagar; Bertran, Maria-Ona

2018-01-01

This paper presents a brief review of the available energy sources for consumption, their effects in terms of CO2-emission and its management, and sustainable chemical processing where energy-consumption, CO2-emission, as well as economics and environmental impacts are considered. Not all available...... energy sources are being utilized efficiently, while, the energy source causing the largest emission of CO2 is being used in the largest amount. The CO2 management is therefore looking at "curing" the problem rather than "preventing" it. Examples highlighting the synthesis, design and analysis...... of sustainable chemical processing in the utilization of biomass-based energy-chemicals production, carbon-capture and utilization with zero or negative CO2-emission to produce value added chemicals as well as retrofit design of energy intensive chemical processes with significant reduction of energy consumption...

IN-SITU IONIC CHEMICAL ANALYSIS OF FRESH WATER VIA A NOVEL COMBINED MULTI-SENSOR / SIGNAL PROCESSING ARCHITECTURE

Science.gov (United States)

Mueller, A. V.; Hemond, H.

2009-12-01

The capability for comprehensive, real-time, in-situ characterization of the chemical constituents of natural waters is a powerful tool for the advancement of the ecological and geochemical sciences, e.g. by facilitating rapid high-resolution adaptive sampling campaigns and avoiding the potential errors and high costs related to traditional grab sample collection, transportation and analysis. Portable field-ready instrumentation also promotes the goals of large-scale monitoring networks, such as CUASHI and WATERS, without the financial and human resources overhead required for traditional sampling at this scale. Problems of environmental remediation and monitoring of industrial waste waters would additionally benefit from such instrumental capacity. In-situ measurement of all major ions contributing to the charge makeup of natural fresh water is thus pursued via a combined multi-sensor/multivariate signal processing architecture. The instrument is based primarily on commercial electrochemical sensors, e.g. ion selective electrodes (ISEs) and ion selective field-effect transistors (ISFETs), to promote low cost as well as easy maintenance and reproduction,. The system employs a novel architecture of multivariate signal processing to extract accurate information from in-situ data streams via an "unmixing" process that accounts for sensor non-linearities at low concentrations, as well as sensor cross-reactivities. Conductivity, charge neutrality and temperature are applied as additional mathematical constraints on the chemical state of the system. Including such non-ionic information assists in obtaining accurate and useful calibrations even in the non-linear portion of the sensor response curves, and measurements can be made without the traditionally-required standard additions or ionic strength adjustment. Initial work demonstrates the effectiveness of this methodology at predicting inorganic cations (Na+, NH4+, H+, Ca2+, and K+) in a simplified system containing

Modelling Dietary Exposure to Chemical Components in Heat-Processed Meats

DEFF Research Database (Denmark)

Georgiadis, Stylianos; Jakobsen, Lea Sletting; Nielsen, Bo Friis

Several chemical compounds that potentially increase the risk of developing cancer in humans are formed during heat processing of meat. Estimating the overall health impact of these compounds in the population requires accurate estimation of the exposure to the chemicals, as well as the probabili.......g. the Poisson-Lognormal approach, are promising tools to address this obstacle. The exposure estimates can then be applied to dose-response models to quantify the cancer risk.......Several chemical compounds that potentially increase the risk of developing cancer in humans are formed during heat processing of meat. Estimating the overall health impact of these compounds in the population requires accurate estimation of the exposure to the chemicals, as well as the probability...... that different levels of exposure result in disease. The overall goal of this study was to evaluate the impact of variability of exposure patterns and uncertainty of exposure data in burden of disease estimates. We focus on the first phase of burden of disease modelling, i.e. the estimation of exposure...

Nonlinear excitations in biomolecules

International Nuclear Information System (INIS)

Peyrard, M.

1995-01-01

The aim of the workshop entitled ''Nonlinear Excitations in Biomolecules'' is to attempt to bridge the gap between the physicists and biologists communities which is mainly due to language and cultural barriers. The progress of nonlinear science in the last few decades which have shown that the combination of nonlinearity, which characterize most biological phenomena, and cooperative effects in a system having a large number of degrees of freedom, can give rise to coherent excitations with remarkable properties. New concepts, such as solitons nd nonlinear energy localisation have become familiar to physicists and applied mathematicians. It is thus tempting to make an analogy between these coherent excitations and the exceptional stability of some biological processes, such as for instance DNA transcription, which require the coordination of many events in the ever changing environment of a cell. Physicists are now invoking nonlinear excitations to describe and explain many bio-molecular processes while biologists often doubt that the seemingly infinite variety of phenomena that they are attempting to classify can be reduced to such simple concepts. A large part of the meeting is devoted to tutorial lectures rather than to latest research results. The book provides a pedagogical introduction to the two topics forming the backbone of the meeting: the theory of nonlinear excitations and solitons, and their application in biology; and the structure and function of biomolecules, as well as energy and charge transport in biophysics. In order to emphasize the link between physics and biology, the volume is not divided along these two topics but according to biological subjects. Each chapter starts with a short introduction attempting to help the reader to find his way among the contributions and point out the connection between them. 23 lectures over the 32 presented have been selected and refers to quantum properties of macro-molecules. (J.S.)

Historical events of the Chemical Processing Department

Energy Technology Data Exchange (ETDEWEB)

Lane, W.A.

1965-11-12

The purpose of this report is to summarize and document the significant historical events pertinent to the operation of the Chemical Processing facilities at Hanford. The report covers, in chronological order, the major construction activities and historical events from 1944 to September, 1965. Also included are the production records achieved and a history of the department`s unit cost performance.

EGS Richardson AGU Chapman NVAG3 Conference: Nonlinear Variability in Geophysics: scaling and multifractal processes

OpenAIRE

D. Schertzer; S. Lovejoy; S. Lovejoy

1994-01-01

1. The conference The third conference on "Nonlinear VAriability in Geophysics: scaling and multifractal processes" (NVAG 3) was held in Cargese, Corsica, Sept. 10-17, 1993. NVAG3 was joint American Geophysical Union Chapman and European Geophysical Society Richardson Memorial conference, the first specialist conference jointly sponsored by the two organizations. It followed NVAG1 (Montreal, Aug. 1986), NVAG2 (Paris, June 1988; Schertzer and Lovejoy, 1991), five consecutive annual ...

EGS Richardson AGU Chapman NVAG3 Conference: Nonlinear Variability in Geophysics: scaling and multifractal processes

OpenAIRE

Schertzer , D; Lovejoy , S.

1994-01-01

International audience; 1. The conference The third conference on "Nonlinear VAriability in Geophysics: scaling and multifractal processes" (NVAG 3) was held in Cargese, Corsica, Sept. 10-17, 1993. NVAG3 was joint American Geophysical Union Chapman and European Geophysical Society Richardson Memorial conference, the first specialist conference jointly sponsored by the two organizations. It followed NVAG1 (Montreal, Aug. 1986), NVAG2 (Paris, June 1988; Schertzer and Lovejoy, 1991), five conse...

Method of operating a thermal engine powered by a chemical reaction

Science.gov (United States)

Ross, J.; Escher, C.

1988-06-07

The invention involves a novel method of increasing the efficiency of a thermal engine. Heat is generated by a non-linear chemical reaction of reactants, said heat being transferred to a thermal engine such as Rankine cycle power plant. The novel method includes externally perturbing one or more of the thermodynamic variables of said non-linear chemical reaction. 7 figs.

Nonlinear light scattering in a two component medium: optical limiting application

International Nuclear Information System (INIS)

Joudrier, Valerie

1998-01-01

Scattering is a fundamental manifestation of the interaction between matter and radiation, resulting from inhomogeneities in the refractive index, which decrease transmission. This phenomenon is then especially attractive for sensor protection from laser light by optical limiting. One of the methods to induce scattering at high incident energy is to make use of the Kerr effect where the index of refraction is intensity dependent. Thus, the idea is to use a two component medium with a good index matching between the two components at low intensity, resulting in the medium transparency, and to modify it, at high intensity, due to the non linearity of one component making the medium highly scattering. Some of the experimental and theoretical investigations concerning a new material (here, a cell containing some liquid with small silica particles as inclusion in it) are presented in the visible domain (I=532 nm), for the nanosecond protection regime, beginning, with the chemical synthesis of the sample. The experimental results concerning the optical limiting process are presented, showing that nonlinear scattering is clearly the dominant mechanism in confrontation with other potential nonlinear effects. Several complementary experiments are then performed to complete the nonlinear scattering characterization, involving the measurement of the angular distribution of scattered energy and the integrating sphere measurement. Further information are also gained by studying the time response of the nonlinearities with a dual-beam (pulsed-pump, cw probe) technique. The previous experimental data is also analyzed with some simple theoretical models to evaluate the nonlinearity of the material from optical limiting, the angular scattering and the total scattering energy measurements. The good match between all the analytical results permits to delineate the physical mechanisms responsible for the nonlinear scattering effect and to direct the final conclusion. (author) [fr

Models and Modelling Tools for Chemical Product and Process Design

DEFF Research Database (Denmark)

Gani, Rafiqul

2016-01-01

The design, development and reliability of a chemical product and the process to manufacture it, need to be consistent with the end-use characteristics of the desired product. One of the common ways to match the desired product-process characteristics is through trial and error based experiments......-based framework is that in the design, development and/or manufacturing of a chemical product-process, the knowledge of the applied phenomena together with the product-process design details can be provided with diverse degrees of abstractions and details. This would allow the experimental resources...... to be employed for validation and fine-tuning of the solutions from the model-based framework, thereby, removing the need for trial and error experimental steps. Also, questions related to economic feasibility, operability and sustainability, among others, can be considered in the early stages of design. However...

Integrating chemical engineering fundamentals in the capstone process design project

DEFF Research Database (Denmark)

von Solms, Nicolas; Woodley, John; Johnsson, Jan Erik

2010-01-01

Reaction Engineering. In order to incorporate reactor design into process design in a meaningful way, the teachers of the respective courses need to collaborate (Standard 9 – Enhancement of Faculty CDIO skills). The students also see that different components of the chemical engineering curriculum relate......All B.Eng. courses offered at the Technical University of Denmark (DTU) must now follow CDIO standards. The final “capstone” course in the B.Eng. education is Process Design, which for many years has been typical of chemical engineering curricula worldwide. The course at DTU typically has about 30...... of the CDIO standards – especially standard 3 – Integrated Curriculum - means that the course projects must draw on competences provided in other subjects which the students are taking in parallel with Process Design – specifically Process Control and Reaction Engineering. In each semester of the B...

Chemical and physicochemical characteristics changes during passion fruit juice processing

Directory of Open Access Journals (Sweden)

Aline Gurgel Fernandes

2011-09-01

Full Text Available Passion fruit is widely consumed due to its pleasant flavour and aroma acidity, and it is considered very important a source of minerals and vitamins. It is used in many products such as ice-cream, mousses and, especially, juices. However, the processing of passion fruit juice may modify the composition and biodisponibility of the bioactive compounds. Investigations of the effects of processing on nutritional components in tropical juices are scarce. Frequently, only losses of vitamin C are evaluated. The objective of this paper is to investigate how some operations of passion fruit juice processing (formulation/homogeneization/thermal treatment affect this product's chemical and physicochemical characteristics. The results showed that the chemical and physicochemical characteristics are little affected by the processing although a reduction in vitamin C contents and anthocyanin, large quantities of carotenoids was verified even after the pasteurization stage.

Methods and tools for sustainable chemical process design

DEFF Research Database (Denmark)

Loureiro da Costa Lira Gargalo, Carina; Chairakwongsa, Siwanat; Quaglia, Alberto

2015-01-01

As the pressure on chemical and biochemical processes to achieve a more sustainable performance increases, the need to define a systematic and holistic way to accomplish this is becoming more urgent. In this chapter, a multilevel computer-aided framework for systematic design of more sustainable...

MIMO Self-Tuning Control of Chemical Process Operation

DEFF Research Database (Denmark)

Hallager, L.; Jørgensen, S. B.; Goldschmidt, L.

1984-01-01

The problem of selecting a feasible model structure for a MIMO self-tuning controller (MIMOSC) is addressed. The dependency of the necessary structure complexity in relation to the specific process operating point is investigated. Experimental results from a fixed-bed chemical reactor are used...

Nonlinear acoustic waves in micro-inhomogeneous solids

CERN Document Server

Nazarov, Veniamin

2014-01-01

Nonlinear Acoustic Waves in Micro-inhomogeneous Solids covers the broad and dynamic branch of nonlinear acoustics, presenting a wide variety of different phenomena from both experimental and theoretical perspectives. The introductory chapters, written in the style of graduate-level textbook, present a review of the main achievements of classic nonlinear acoustics of homogeneous media. This enables readers to gain insight into nonlinear wave processes in homogeneous and micro-inhomogeneous solids and compare it within the framework of the book. The subsequent eight chapters covering: Physical m

Comprehensive Mass Analysis for Chemical Processes, a Case Study on L-Dopa Manufacture

Science.gov (United States)

To evaluate the “greenness” of chemical processes in route selection and process development, we propose a comprehensive mass analysis to inform the stakeholders from different fields. This is carried out by characterizing the mass intensity for each contributing chemical or wast...

Subfemtosecond directional control of chemical processes in molecules

Science.gov (United States)

Alnaser, Ali S.; Litvinyuk, Igor V.

2017-02-01

Laser pulses with a waveform-controlled electric field and broken inversion symmetry establish the opportunity to achieve directional control of molecular processes on a subfemtosecond timescale. Several techniques could be used to break the inversion symmetry of an electric field. The most common ones include combining a fundamental laser frequency with its second harmonic or with higher -frequency pulses (or pulse trains) as well as using few-cycle pulses with known carrier-envelope phase (CEP). In the case of CEP, control over chemical transformations, typically occurring on a timescale of many femtoseconds, is driven by much faster sub-cycle processes of subfemtosecond to few-femtosecond duration. This is possible because electrons are much lighter than nuclei and fast electron motion is coupled to the much slower nuclear motion. The control originates from populating coherent superpositions of different electronic or vibrational states with relative phases that are dependent on the CEP or phase offset between components of a two-color pulse. In this paper, we review the recent progress made in the directional control over chemical processes, driven by intense few-cycle laser pulses a of waveform-tailored electric field, in different molecules.

Nonlinearities in the quantum measurement process of superconducting qubits

Energy Technology Data Exchange (ETDEWEB)

Serban, Ioana

2008-05-15

The work described in this thesis focuses on the investigation of decoherence and measurement backaction, on the theoretical description of measurement schemes and their improvement. The study presented here is centered around quantum computing implementations using superconducting devices and most important, the Josephson effect. The measured system is invariantly a qubit, i. e. a two-level system. The objective is to study detectors with increasing nonlinearity, e. g. coupling of the qubit to the frequency a driven oscillator, or to the bifurcation amplifier, to determine the performance and backaction of the detector on the measured system and to investigate the importance of a strong qubit-detector coupling for the achievement of a quantum non-demolition type of detection. The first part gives a very basic introduction to quantum information, briefly reviews some of the most promising physical implementations of a quantum computer before focusing on the superconducting devices. The second part presents a series of studies of different qubit measurements, describing the backaction of the measurement onto the measured system and the internal dynamics of the detector. Methodology adapted from quantum optics and chemical physics (master equations, phase-space analysis etc.) combined with the representation of a complex environment yielded a tool capable of describing a nonlinear, non-Markovian environment, which couples arbitrarily strongly to the measured system. This is described in chapter 3. Chapter 4 focuses on the backaction on the qubit and presents novel insights into the qubit dephasing in the strong coupling regime. Chapter 5 uses basically the same system and technical tools to explore the potential of a fast, strong, indirect measurement, and determine how close such a detection would ideally come to the quantum non-demolition regime. Chapter 6 focuses on the internal dynamics of a strongly driven Josephson junction. The analytical results are based on

Nonlinearities in the quantum measurement process of superconducting qubits

International Nuclear Information System (INIS)

Serban, Ioana

2008-05-01

The work described in this thesis focuses on the investigation of decoherence and measurement backaction, on the theoretical description of measurement schemes and their improvement. The study presented here is centered around quantum computing implementations using superconducting devices and most important, the Josephson effect. The measured system is invariantly a qubit, i. e. a two-level system. The objective is to study detectors with increasing nonlinearity, e. g. coupling of the qubit to the frequency a driven oscillator, or to the bifurcation amplifier, to determine the performance and backaction of the detector on the measured system and to investigate the importance of a strong qubit-detector coupling for the achievement of a quantum non-demolition type of detection. The first part gives a very basic introduction to quantum information, briefly reviews some of the most promising physical implementations of a quantum computer before focusing on the superconducting devices. The second part presents a series of studies of different qubit measurements, describing the backaction of the measurement onto the measured system and the internal dynamics of the detector. Methodology adapted from quantum optics and chemical physics (master equations, phase-space analysis etc.) combined with the representation of a complex environment yielded a tool capable of describing a nonlinear, non-Markovian environment, which couples arbitrarily strongly to the measured system. This is described in chapter 3. Chapter 4 focuses on the backaction on the qubit and presents novel insights into the qubit dephasing in the strong coupling regime. Chapter 5 uses basically the same system and technical tools to explore the potential of a fast, strong, indirect measurement, and determine how close such a detection would ideally come to the quantum non-demolition regime. Chapter 6 focuses on the internal dynamics of a strongly driven Josephson junction. The analytical results are based on

The periodic structure of the natural record, and nonlinear dynamics.

Science.gov (United States)

Shaw, H.R.

1987-01-01

This paper addresses how nonlinear dynamics can contribute to interpretations of the geologic record and evolutionary processes. Background is given to explain why nonlinear concepts are important. A resume of personal research is offered to illustrate why I think nonlinear processes fit with observations on geological and cosmological time series data. The fabric of universal periodicity arrays generated by nonlinear processes is illustrated by means of a simple computer mode. I conclude with implications concerning patterns of evolution, stratigraphic boundary events, and close correlations of major geologically instantaneous events (such as impacts or massive volcanic episodes) with any sharply defined boundary in the geologic column. - from Author

Physico-chemical, functional and processing attributes of some ...

African Journals Online (AJOL)

A study was generated from six commercial potato varieties and studied for their physical, chemical, functional and processing attributes. Lady Rosetta followed by Hermes was the most appreciable varieties concerning their physical attributes. A positive correlation (R = 0.765) existed between tuber firmness and specific ...

Modeling the effects of cohesive energy for single particle on the material removal in chemical mechanical polishing at atomic scale

International Nuclear Information System (INIS)

Wang Yongguang; Zhao Yongwu; An Wei; Wang Jun

2007-01-01

This paper proposes a novel mathematical model for chemical mechanical polishing (CMP) based on interface solid physical and chemical theory in addition to energy equilibrium knowledge. And the effects of oxidation concentration and particle size on the material removal in CMP are investigated. It is shown that the mechanical energy and removal cohesive energy couple with the particle size, and being a cause of the non-linear size-removal rate relation. Furthermore, it also shows a nonlinear dependence of removal rate on removal cohesive energy. The model predictions are in good qualitative agreement with the published experimental data. The current study provides an important starting point for delineating the micro-removal mechanism in the CMP process at atomic scale

CHEMSIMUL: A simulator for chemical kinetics

International Nuclear Information System (INIS)

Kirkegaard, P.; Bjergbakke, E.

1999-01-01

CHEMSIMUL is a computer program system for numerical simulation of chemical reaction systems. It can be used for modeling complex kinetics in many contexts, in particular radiolytic processes. It contains a translator module and a module for solving the resulting coupled nonlinear ordinary differential equations. An overview of the program system is given, and its use is illustrated by examples. A number of special features are described, in particular a method for verifying the mass balance. Moreover, the document contains a complete User's Guide for running CHEMSIMUL on a PC or another computer. Finally, the mathematical implementation is discussed. (au)

A document processing pipeline for annotating chemical entities in scientific documents.

Science.gov (United States)

Campos, David; Matos, Sérgio; Oliveira, José L

2015-01-01

The recognition of drugs and chemical entities in text is a very important task within the field of biomedical information extraction, given the rapid growth in the amount of published texts (scientific papers, patents, patient records) and the relevance of these and other related concepts. If done effectively, this could allow exploiting such textual resources to automatically extract or infer relevant information, such as drug profiles, relations and similarities between drugs, or associations between drugs and potential drug targets. The objective of this work was to develop and validate a document processing and information extraction pipeline for the identification of chemical entity mentions in text. We used the BioCreative IV CHEMDNER task data to train and evaluate a machine-learning based entity recognition system. Using a combination of two conditional random field models, a selected set of features, and a post-processing stage, we achieved F-measure results of 87.48% in the chemical entity mention recognition task and 87.75% in the chemical document indexing task. We present a machine learning-based solution for automatic recognition of chemical and drug names in scientific documents. The proposed approach applies a rich feature set, including linguistic, orthographic, morphological, dictionary matching and local context features. Post-processing modules are also integrated, performing parentheses correction, abbreviation resolution and filtering erroneous mentions using an exclusion list derived from the training data. The developed methods were implemented as a document annotation tool and web service, freely available at http://bioinformatics.ua.pt/becas-chemicals/.

Sustainable Chemical Processes and Products. New Design Methodology and Design Tools

NARCIS (Netherlands)

Korevaar, G.

2004-01-01

The current chemical industry is not sustainable, which leads to the fact that innovation of chemical processes and products is too often hazardous for society in general and the environment in particular. It really is a challenge to implement sustainability considerations in the design activities

Detoxifying of high strength textile effluent through chemical and bio-oxidation processes.

Science.gov (United States)

Manekar, Pravin; Patkar, Guarav; Aswale, Pawan; Mahure, Manisha; Nandy, Tapas

2014-04-01

Small-scale textile industries (SSTIs) in India struggled for the economic and environmental race. A full-scale common treatment plant (CETP) working on the principle of destabilising negative charge colloidal particles and bio-oxidation of dissolved organic failed to comply with Inland Surface Waters (ISW) standards. Thus, presence of intense colour and organics with elevated temperature inhibited the process stability. Bench scale treatability studies were conducted on chemical and biological processes for its full-scale apps to detoxify a high strength textile process effluent. Colour, SS and COD removals from the optimised chemical process were 88%, 70% and 40%, respectively. Heterotrophic bacteria oxidised COD and BOD more than 84% and 90% at a loading rate 0.0108kgm(-3)d(-1) at 3h HRT. The combined chemical and bio-oxidation processes showed a great promise for detoxifying the toxic process effluent, and implemented in full-scale CETP. The post-assessment of the CETP resulted in detoxify the toxic effluent. Copyright © 2014 Elsevier Ltd. All rights reserved.

Chemical kinetics, stochastic processes, and irreversible thermodynamics

CERN Document Server

Santillán, Moisés

2014-01-01

This book brings theories in nonlinear dynamics, stochastic processes, irreversible thermodynamics, physical chemistry, and biochemistry together in an introductory but formal and comprehensive manner.  Coupled with examples, the theories are developed stepwise, starting with the simplest concepts and building upon them into a more general framework.  Furthermore, each new mathematical derivation is immediately applied to one or more biological systems.  The last chapters focus on applying mathematical and physical techniques to study systems such as: gene regulatory networks and ion channels. The target audience of this book are mainly final year undergraduate and graduate students with a solid mathematical background (physicists, mathematicians, and engineers), as well as with basic notions of biochemistry and cellular biology.  This book can also be useful to students with a biological background who are interested in mathematical modeling, and have a working knowledge of calculus, differential equatio...

Nonequilibrium thermodynamics transport and rate processes in physical, chemical and biological systems

CERN Document Server

Demirel, Yasar

2014-01-01

Natural phenomena consist of simultaneously occurring transport processes and chemical reactions. These processes may interact with each other and may lead to self-organized structures, fluctuations, instabilities, and evolutionary systems. Nonequilibrium Thermodynamics, 3rd edition emphasizes the unifying role of thermodynamics in analyzing the natural phenomena. This third edition updates and expands on the first and second editions by focusing on the general balance equations for coupled processes of physical, chemical, and biological systems. The new edition contains a new chapte

Temporal cross-correlation asymmetry and departure from equilibrium in a bistable chemical system.

Science.gov (United States)

Bianca, C; Lemarchand, A

2014-06-14

This paper aims at determining sustained reaction fluxes in a nonlinear chemical system driven in a nonequilibrium steady state. The method relies on the computation of cross-correlation functions for the internal fluctuations of chemical species concentrations. By employing Langevin-type equations, we derive approximate analytical formulas for the cross-correlation functions associated with nonlinear dynamics. Kinetic Monte Carlo simulations of the chemical master equation are performed in order to check the validity of the Langevin equations for a bistable chemical system. The two approaches are found in excellent agreement, except for critical parameter values where the bifurcation between monostability and bistability occurs. From the theoretical point of view, the results imply that the behavior of cross-correlation functions cannot be exploited to measure sustained reaction fluxes in a specific nonlinear system without the prior knowledge of the associated chemical mechanism and the rate constants.

Model-Based Integrated Process Design and Controller Design of Chemical Processes

DEFF Research Database (Denmark)

Abd Hamid, Mohd Kamaruddin Bin

that is typically formulated as a mathematical programming (optimization with constraints) problem is solved by the so-called reverse approach by decomposing it into four sequential hierarchical sub-problems: (i) pre-analysis, (ii) design analysis, (iii) controller design analysis, and (iv) final selection......This thesis describes the development and application of a new systematic modelbased methodology for performing integrated process design and controller design (IPDC) of chemical processes. The new methodology is simple to apply, easy to visualize and efficient to solve. Here, the IPDC problem...... are ordered according to the defined performance criteria (objective function). The final selected design is then verified through rigorous simulation. In the pre-analysis sub-problem, the concepts of attainable region and driving force are used to locate the optimal process-controller design solution...

Status summary of chemical processing development in plutonium-238 supply program

Energy Technology Data Exchange (ETDEWEB)

Collins, Emory D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Benker, Dennis [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Wham, Robert M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); DePaoli, David W. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Delmau, Laetitia Helene [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Sherman, Steven R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

2017-10-01

This document summarizes the status of development of chemical processing in the Plutonium-238 Supply Program (PSP) near the end of Demonstration 1. The objective of the PSP is “to develop, demonstrate, and document a production process that meets program objectives and to prepare for its operation” (Frazier et al. 2016). Success in the effort includes establishing capability using the current infrastructure to produce Np targets for irradiation in Department of Energy research reactors, chemically processing the irradiated targets to separate and purify the produced Pu and transferring the PuO₂ product to Los Alamos National Laboratory (LANL) at an average rate of 1.5 kg/y.

Qualitative aspects of nonlinear wave motion: Complexity and simplicity

International Nuclear Information System (INIS)

Engelbrecht, J.

1993-01-01

The nonlinear wave processes possess many qualitative properties which cannot be described by linear theories. In this presentation, an attempt is made to systematize the main aspects of this fascinating area. The sources of nonlinearities are analyzed in order to understand why and how the nonlinear mathematical models are formulated. The technique of evolution equations is discussed then as a main mathematical tool to separate multiwave processes into single waves. The evolution equations give concise but in many cases sufficient description of wave processes in solids permitting to analyze spectral changes, phase changes and velocities, coupling of waves, and interaction of nonlinearities with other physical effects of the same order. Several new problems are listed. Knowing the reasons, the seemingly complex problems can be effectively analyzed. 61 refs

Nonlinear Phononic Periodic Structures and Granular Crystals

Science.gov (United States)

2012-02-10

and boron-nitride nanotubes, and attributed the rectification to nonlinear processes [21]. Based on these studies, several following works have...nonlinear mass-spring lattices by E. Fermi, J. Pasta , and S. Ulam in 1955 [27], there has been a wealth of interest in the dynamics of nonlinear...lattices. Using one of the first modern computers, Fermi, Pasta , and Ulam (FPU) studied a system where the restoring (spring) force between two adjacent

Influence of chemical processing on the imaging properties of microlenses

International Nuclear Information System (INIS)

Vasiljevic, Darko; Muric, Branka; Pantelic, Dejan; Panic, Bratimir

2009-01-01

Microlenses are produced by irradiation of a layer of tot'hema and eosin sensitized gelatin (TESG) by using a laser beam (Nd:YAG 2nd harmonic; 532 nm). All the microlenses obtained are concave with a parabolic profile. After the production, the microlenses are chemically processed with various concentrations of alum. The following imaging properties of microlenses were calculated and analyzed: the root mean square (rms) wavefront aberration, the geometric encircled energy and the spot diagram. The microlenses with higher concentrations of alum in solution had a greater effective focal length and better image quality. The microlenses chemically processed with 10% alum solution had near-diffraction-limited performance.

Stochastic processes in chemical physics

CERN Document Server

Shuler, K E

2009-01-01

The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics.

Security risk assessment and protection in the chemical and process industry

OpenAIRE

Reniers, Genserik; van Lerberghe, Paul; van Gulijk, Coen

2014-01-01

This article describes a security risk assessment and protection methodology that was developed for use in the chemical- and process industry in Belgium. The approach of the method follows a risk-based approach that follows desing principles for chemical safety. That approach is beneficial for workers in the chemical industry because they recognize the steps in this model from familiar safety models .The model combines the rings-of-protection approach with generic security practices including...

Nonlinear Properties of Soft Glass Waveguides

DEFF Research Database (Denmark)

Steffensen, Henrik

-infrared applications and the THz applications. In the mid-infrared, it is investigated whether soft glasses are a suitable candidate for supercontinuum generation (SCG). A few commercially available fluoride fibers are tested for their zero dispersion wavelength (ZDW), a key property when determining the possibility......This thesis builds around the investigation into using soft glass materials for midinfrared and THz applications. Soft glasses is a term that cov ers a wide range of chemical compositions where many are yet to be fully investigated. The work in this thesis is separated in two parts, the mid...... of SCG in a fiber. A group of soft glasses, namely the chalcogenides, are known to display two photon absorption (TPA) which could potentially limit the SCG when this is initiated within the frequency range where this nonlinear process occur. An analytic model is presented to estimate the soliton self...

Mathematical modeling and applications in nonlinear dynamics

CERN Document Server

Merdan, Hüseyin

2016-01-01

The book covers nonlinear physical problems and mathematical modeling, including molecular biology, genetics, neurosciences, artificial intelligence with classical problems in mechanics and astronomy and physics. The chapters present nonlinear mathematical modeling in life science and physics through nonlinear differential equations, nonlinear discrete equations and hybrid equations. Such modeling can be effectively applied to the wide spectrum of nonlinear physical problems, including the KAM (Kolmogorov-Arnold-Moser (KAM)) theory, singular differential equations, impulsive dichotomous linear systems, analytical bifurcation trees of periodic motions, and almost or pseudo- almost periodic solutions in nonlinear dynamical systems. Provides methods for mathematical models with switching, thresholds, and impulses, each of particular importance for discontinuous processes Includes qualitative analysis of behaviors on Tumor-Immune Systems and methods of analysis for DNA, neural networks and epidemiology Introduces...

Multi-frequency Defect Selective Imaging via Nonlinear Ultrasound

Science.gov (United States)

Solodov, Igor; Busse, Gerd

The concept of defect-selective ultrasonic nonlinear imaging is based on visualization of strongly nonlinear inclusions in the form of localized cracked defects. For intense excitation, the ultrasonic response of defects is affected by mechanical constraint between their fragments that makes their vibrations extremely nonlinear. The cracked flaws, therefore, efficiently generate multiple new frequencies, which can be used as a nonlinear "tag" to detect and image them. In this paper, the methodologies of nonlinear scanning laser vibrometry (NSLV) and nonlinear air-coupled emission (NACE) are applied for nonlinear imaging of various defects in hi-tech and constructional materials. A broad database obtained demonstrates evident advantages of the nonlinear approach over its linear counterpart. The higher-order nonlinear frequencies provide increase in signal-to-noise ratio and enhance the contrast of imaging. Unlike conventional ultrasonic instruments, the nonlinear approach yields abundant multi-frequency information on defect location. The application of image recognition and processing algorithms is described and shown to improve reliability and quality of ultrasonic imaging.

Survey of knowledge of hazards of chemicals potentially associated with the advanced isotope separation processes

International Nuclear Information System (INIS)

Chester, R.O.; Kirkscey, K.A.; Randolph, M.L.

1979-09-01

Hazards of chemical potentially associated with the advanced isotope separation processes are estimated based on open literature references. The tentative quantity of each chemical associated with the processes and the toxicity of the chemical are used to estimate this hazard. The chemicals thus estimated to be the most potentially hazardous to health are fluorine, nitric acid, uranium metal, uranium hexafluoride, and uranium dust. The estimated next most hazardous chemicals are bromine, hydrobromic acid, hydrochloric acid, and hydrofluoric acid. For each of these chemicals and for a number of other process-associated chemicals the following information is presented: (1) any applicable standards, recommended standards and their basis; (2) a brief discussion to toxic effects including short exposure tolerance, atmospheric concentration immediately hazardous to life, evaluation of exposures, recommended control procedures, chemical properties, and a list of any toxicology reviews; and (3) recommendations for future research

Survey of knowledge of hazards of chemicals potentially associated with the advanced isotope separation processes

Energy Technology Data Exchange (ETDEWEB)

Chester, R.O.; Kirkscey, K.A.; Randolph, M.L.

1979-09-01

Hazards of chemical potentially associated with the advanced isotope separation processes are estimated based on open literature references. The tentative quantity of each chemical associated with the processes and the toxicity of the chemical are used to estimate this hazard. The chemicals thus estimated to be the most potentially hazardous to health are fluorine, nitric acid, uranium metal, uranium hexafluoride, and uranium dust. The estimated next most hazardous chemicals are bromine, hydrobromic acid, hydrochloric acid, and hydrofluoric acid. For each of these chemicals and for a number of other process-associated chemicals the following information is presented: (1) any applicable standards, recommended standards and their basis; (2) a brief discussion to toxic effects including short exposure tolerance, atmospheric concentration immediately hazardous to life, evaluation of exposures, recommended control procedures, chemical properties, and a list of any toxicology reviews; and (3) recommendations for future research.

A survey of process control computers at the Idaho Chemical Processing Plant

International Nuclear Information System (INIS)

Dahl, C.A.

1989-01-01

The Idaho Chemical Processing Plant (ICPP) at the Idaho National Engineering Laboratory is charged with the safe processing of spent nuclear fuel elements for the United States Department of Energy. The ICPP was originally constructed in the late 1950s and used state-of-the-art technology for process control at that time. The state of process control instrumentation at the ICPP has steadily improved to keep pace with emerging technology. Today, the ICPP is a college of emerging computer technology in process control with some systems as simple as standalone measurement computers while others are state-of-the-art distributed control systems controlling the operations in an entire facility within the plant. The ICPP has made maximal use of process computer technology aimed at increasing surety, safety, and efficiency of the process operations. Many benefits have been derived from the use of the computers for minimal costs, including decreased misoperations in the facility, and more benefits are expected in the future

Nonlinear responses of chiral fluids from kinetic theory

Science.gov (United States)

Hidaka, Yoshimasa; Pu, Shi; Yang, Di-Lun

2018-01-01

The second-order nonlinear responses of inviscid chiral fluids near local equilibrium are investigated by applying the chiral kinetic theory (CKT) incorporating side-jump effects. It is shown that the local equilibrium distribution function can be nontrivially introduced in a comoving frame with respect to the fluid velocity when the quantum corrections in collisions are involved. For the study of anomalous transport, contributions from both quantum corrections in anomalous hydrodynamic equations of motion and those from the CKT and Wigner functions are considered under the relaxation-time (RT) approximation, which result in anomalous charge Hall currents propagating along the cross product of the background electric field and the temperature (or chemical-potential) gradient and of the temperature and chemical-potential gradients. On the other hand, the nonlinear quantum correction on the charge density vanishes in the classical RT approximation, which in fact satisfies the matching condition given by the anomalous equation obtained from the CKT.

Evidence for a chemical clock in oscillatory formation of UiO-66

Science.gov (United States)

Goesten, M. G.; de Lange, M. F.; Olivos-Suarez, A. I.; Bavykina, A. V.; Serra-Crespo, P.; Krywka, C.; Bickelhaupt, F. M.; Kapteijn, F.; Gascon, Jorge

2016-06-01

Chemical clocks are often used as exciting classroom experiments, where an induction time is followed by rapidly changing colours that expose oscillating concentration patterns. This type of reaction belongs to a class of nonlinear chemical kinetics also linked to chaos, wave propagation and Turing patterns. Despite its vastness in occurrence and applicability, the clock reaction is only well understood for liquid-state processes. Here we report a chemical clock reaction, in which a solidifying entity, metal-organic framework UiO-66, displays oscillations in crystal dimension and number, as shown by X-ray scattering. In rationalizing this result, we introduce a computational approach, the metal-organic molecular orbital methodology, to pinpoint interaction between the tectonic building blocks that construct the metal-organic framework material. In this way, we show that hydrochloric acid plays the role of autocatalyst, bridging separate processes of condensation and crystallization.

Nonlinear Multiantenna Detection Methods

Directory of Open Access Journals (Sweden)

Chen Sheng

2004-01-01

Full Text Available A nonlinear detection technique designed for multiple-antenna assisted receivers employed in space-division multiple-access systems is investigated. We derive the optimal solution of the nonlinear spatial-processing assisted receiver for binary phase shift keying signalling, which we refer to as the Bayesian detector. It is shown that this optimal Bayesian receiver significantly outperforms the standard linear beamforming assisted receiver in terms of a reduced bit error rate, at the expense of an increased complexity, while the achievable system capacity is substantially enhanced with the advent of employing nonlinear detection. Specifically, when the spatial separation expressed in terms of the angle of arrival between the desired and interfering signals is below a certain threshold, a linear beamformer would fail to separate them, while a nonlinear detection assisted receiver is still capable of performing adequately. The adaptive implementation of the optimal Bayesian detector can be realized using a radial basis function network. Two techniques are presented for constructing block-data-based adaptive nonlinear multiple-antenna assisted receivers. One of them is based on the relevance vector machine invoked for classification, while the other on the orthogonal forward selection procedure combined with the Fisher ratio class-separability measure. A recursive sample-by-sample adaptation procedure is also proposed for training nonlinear detectors based on an amalgam of enhanced -means clustering techniques and the recursive least squares algorithm.

Introduction to nonlinear acoustics

Science.gov (United States)

Bjørnø, Leif

2010-01-01

A brief review of the basic principles of fluid mechanics needed for development of linear and nonlinear ultrasonic concepts will be given. The fundamental equations of nonlinear ultrasonics will be derived and their physical properties explained. It will be shown how an originally monochromatic finite-amplitude ultrasonic wave, due to nonlinear effects, will distort during its propagation in time and space to form higher harmonics to its fundamental frequency. The concepts of shock formation will be presented. The material nonlinearity, described by the nonlinearity parameter B/A of the material, and the convective nonlinearity, described by the ultrasonic Mach Number, will be explained. Two procedures for determination of B/A will briefly be described and some B/A-values characterizing biological materials will be presented. Shock formation, described by use of the Goldberg Number,and Ultrasonic Saturation will be discussed.. An introduction to focused ultrasonic fields will be given and it will be shown how the ultrasonic intensity will vary axially and laterally in and near the focal region and how the field parameters of interest to biomedical applications may be described by use of the KZK-Model. Finally, an introduction will be given to the parametric acoustic array formed by mixing and interaction of two monochromatic, finite-amplitude ultrasonic waves in a liquid and the potentials of this mixing process in biomedical ultrasound will briefly be mentioned.

Coherent Nonlinear Longitudinal Phenomena in Unbunched Synchrotron Beams

Energy Technology Data Exchange (ETDEWEB)

Spentzouris, Linda Klamp [Northwestern U.

1996-12-01

Coherent nonlinear longitudinal phenomena are studied in proton and antiproton synchrotron beams. Theoretical development done in the eld of plasma physics for resonant wave-wave coupling is applied to the case of a particle beam. Results are given from experiments done to investigate the nature of the weakly nonlinear three-wave coupling processes known as parametric coupling and echoes. Storage ring impedances are shown to amplify the parametric coupling process, underlining the possibility that machine impedances might be extracted from coupling events instigated by external excitation. Echo amplitudes are demonstrated to be sensitive to diusion processes, such as intrabeam scattering, which degrade a beam. The result of a fast diusion rate measurement using echo amplitudes is presented. In addition to the wave-wave interactions, observations of moderately nonlinear waveparticle interactions are also included. The manifestations of these interactions that are documented include nonlinear Landau damping, higher harmonic generation, and signs of the possible formation of solitons.

Impact of Salt Waste Processing Facility Streams on the Nitric-Glycolic Flowsheet in the Chemical Processing Cell

Energy Technology Data Exchange (ETDEWEB)

Martino, C. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2017-08-08

An evaluation of the previous Chemical Processing Cell (CPC) testing was performed to determine whether the planned concurrent operation, or “coupled” operations, of the Defense Waste Processing Facility (DWPF) with the Salt Waste Processing Facility (SWPF) has been adequately covered. Tests with the nitricglycolic acid flowsheet, which were both coupled and uncoupled with salt waste streams, included several tests that required extended boiling times. This report provides the evaluation of previous testing and the testing recommendation requested by Savannah River Remediation. The focus of the evaluation was impact on flammability in CPC vessels (i.e., hydrogen generation rate, SWPF solvent components, antifoam degradation products) and processing impacts (i.e., acid window, melter feed target, rheological properties, antifoam requirements, and chemical composition).

The new risk paradigm for chemical process security and safety.

Science.gov (United States)

Moore, David A

2004-11-11

The world of safety and security in the chemical process industries has certainly changed since 11 September, but the biggest challenges may be yet to come. This paper will explain that there is a new risk management paradigm for chemical security, discuss the differences in interpreting this risk versus accidental risk, and identify the challenges we can anticipate will occur in the future on this issue. Companies need to be ready to manage the new chemical security responsibilities and to exceed the expectations of the public and regulators. This paper will outline the challenge and a suggested course of action.

Topics in Nonlinear Dynamics

DEFF Research Database (Denmark)

Mosekilde, Erik

Through a significant number of detailed and realistic examples this book illustrates how the insights gained over the past couple of decades in the fields of nonlinear dynamics and chaos theory can be applied in practice. Aomng the topics considered are microbiological reaction systems, ecological...... food-web systems, nephron pressure and flow regulation, pulsatile secretion of hormones, thermostatically controlled radiator systems, post-stall maneuvering of aircrafts, transfer electron devices for microwave generation, economic long waves, human decision making behavior, and pattern formation...... in chemical reaction-diffusion systems....

Nonlinear optical microscopy for histology of fresh normal and cancerous pancreatic tissues.

Directory of Open Access Journals (Sweden)

Wenyan Hu

Full Text Available BACKGROUND: Pancreatic cancer is a lethal disease with a 5-year survival rate of only 1-5%. The acceleration of intraoperative histological examination would be beneficial for better management of pancreatic cancer, suggesting an improved survival. Nonlinear optical methods based on two-photon excited fluorescence (TPEF and second harmonic generation (SHG of intrinsic optical biomarkers show the ability to visualize the morphology of fresh tissues associated with histology, which is promising for real-time intraoperative evaluation of pancreatic cancer. METHODOLOGY/PRINCIPAL FINDINGS: In order to investigate whether the nonlinear optical imaging methods have the ability to characterize pancreatic histology at cellular resolution, we studied different types of pancreatic tissues by using label-free TPEF and SHG. Compared with other routine methods for the preparation of specimens, fresh tissues without processing were found to be most suitable for nonlinear optical imaging of pancreatic tissues. The detailed morphology of the normal rat pancreas was observed and related with the standard histological images. Comparatively speaking, the preliminary images of a small number of chemical-induced pancreatic cancer tissues showed visible neoplastic differences in the morphology of cells and extracellular matrix. The subcutaneous pancreatic tumor xenografts were further observed using the nonlinear optical microscopy, showing that most cells are leucocytes at 5 days after implantation, the tumor cells begin to proliferate at 10 days after implantation, and the extracellular collagen fibers become disordered as the xenografts grow. CONCLUSIONS/SIGNIFICANCE: In this study, nonlinear optical imaging was used to characterize the morphological details of fresh pancreatic tissues for the first time. We demonstrate that it is possible to provide real-time histological evaluation of pancreatic cancer by the nonlinear optical methods, which present an

Nonlinear optomechanical measurement of mechanical motion

DEFF Research Database (Denmark)

Brawley, G.A.; Vanner, M R; Larsen, Peter Emil

2016-01-01

Precision measurement of nonlinear observables is an important goal in all facets of quantum optics. This allows measurement-based non-classical state preparation, which has been applied to great success in various physical systems, and provides a route for quantum information processing with oth......Precision measurement of nonlinear observables is an important goal in all facets of quantum optics. This allows measurement-based non-classical state preparation, which has been applied to great success in various physical systems, and provides a route for quantum information processing...... with otherwise linear interactions. In cavity optomechanics much progress has been made using linear interactions and measurement, but observation of nonlinear mechanical degrees-of-freedom remains outstanding. Here we report the observation of displacement-squared thermal motion of a micro-mechanical resonator...... by exploiting the intrinsic nonlinearity of the radiation-pressure interaction. Using this measurement we generate bimodal mechanical states of motion with separations and feature sizes well below 100 pm. Future improvements to this approach will allow the preparation of quantum superposition states, which can...

Yellow phosphorus process to convert toxic chemicals to non-toxic products

Science.gov (United States)

Chang, S.G.

1994-07-26

The present invention relates to a process for generating reactive species for destroying toxic chemicals. This process first contacts air or oxygen with aqueous emulsions of molten yellow phosphorus. This contact results in rapid production of abundant reactive species such as O, O[sub 3], PO, PO[sub 2], etc. A gaseous or liquid aqueous solution organic or inorganic chemicals is next contacted by these reactive species to reduce the concentration of toxic chemical and result in a non-toxic product. The final oxidation product of yellow phosphorus is phosphoric acid of a quality which can be recovered for commercial use. A process is developed such that the byproduct, phosphoric acid, is obtained without contamination of toxic species in liquids treated. A gas stream containing ozone without contamination of phosphorus containing species is also obtained in a simple and cost-effective manner. This process is demonstrated to be effective for destroying many types of toxic organic, or inorganic, compounds, including polychlorinated biphenyls (PCB), aromatic chlorides, amines, alcohols, acids, nitro aromatics, aliphatic chlorides, polynuclear aromatic compounds (PAH), dyes, pesticides, sulfides, hydroxyamines, ureas, dithionates and the like. 20 figs.

Activities of the Institute of Chemical Processing of Coal at Zabrze

Energy Technology Data Exchange (ETDEWEB)

Dreszer, K.

1995-12-31

The Institute of Chemical Processing of Coal at Zabrze was established in 1955. The works on carbochemical technologies have been, therefore, carried out at the Institute for 40 years. The targets of the Institute`s activities are research, scientific and developing works regarding a sensible utilization of fuels via their processing into more refined forms, safe environment, highly efficient use of energy carriers and technological products of special quality. The Institute of Chemical Processing of Coal has been dealing with the following: optimized use of home hard coals; improvement of classic coal coking technologies, processing and utilization of volatile coking products; production technologies of low emission rate fuels for communal management; analyses of coal processing technologies; new technologies aimed at increasing the efficiency of coal utilization for energy-generating purposes, especially in industry and studies on the ecological aspects of these processes; production technologies of sorbents and carbon activating agents and technologies of the utilization; rationalization of water and wastes management in the metallurgical and chemical industries in connection with removal of pollution especially dangerous to the environment from wastes; utilization technologies of refined materials (electrode cokes, binders, impregnating agents) for making electrodes, refractories and new generation construction carbon materials; production technologies of high quality bituminous and bituminous and resin coating, anti-corrosive and insulation materials; environmentally friendly utilization technologies for power station, mine and other wastes, and dedusting processes in industrial gas streams.

All-Optical Control of Linear and Nonlinear Energy Transfer via the Zeno Effect

Science.gov (United States)

Guo, Xiang; Zou, Chang-Ling; Jiang, Liang; Tang, Hong X.

2018-05-01

Microresonator-based nonlinear processes are fundamental to applications including microcomb generation, parametric frequency conversion, and harmonics generation. While nonlinear processes involving either second- (χ(2 )) or third- (χ(3 )) order nonlinearity have been extensively studied, the interaction between these two basic nonlinear processes has seldom been reported. In this paper we demonstrate a coherent interplay between second- and third- order nonlinear processes. The parametric (χ(2 ) ) coupling to a lossy ancillary mode shortens the lifetime of the target photonic mode and suppresses its density of states, preventing the photon emissions into the target photonic mode via the Zeno effect. Such an effect is then used to control the stimulated four-wave mixing process and realize a suppression ratio of 34.5.

Nonlinear effects in water waves

International Nuclear Information System (INIS)

Janssen, P.A.E.M.

1989-05-01

This set of lecture notes on nonlinear effects in water waves was written on the occasion of the first ICTP course on Ocean Waves and Tides held from 26 September until 28 October 1988 in Trieste, Italy. It presents a summary and unification of my knowledge on nonlinear effects of gravity waves on an incompressible fluid without vorticity. The starting point of the theory is the Hamiltonian for water waves. The evolution equations of both weakly nonlinear, shallow water and deep water gravity waves are derived by suitable approximation of the energy of the waves, resulting in the Korteweg-de Vries equation and the Zakharov equation, respectively. Next, interesting properties of the KdV equation (solitons) and the Zakharov equation (instability of a finite amplitude wave train) are discussed in some detail. Finally, the evolution of a homogeneous, random wave field due to resonant four wave processes is considered and the importance of this process for ocean wave prediction is pointed out. 38 refs, 21 figs

Nonlinear Elliptic Differential Equations with Multivalued Nonlinearities

Indian Academy of Sciences (India)

In this paper we study nonlinear elliptic boundary value problems with monotone and nonmonotone multivalued nonlinearities. First we consider the case of monotone nonlinearities. In the first result we assume that the multivalued nonlinearity is defined on all R R . Assuming the existence of an upper and of a lower ...

Down Select Report of Chemical Hydrogen Storage Materials, Catalysts, and Spent Fuel Regeneration Processes

Energy Technology Data Exchange (ETDEWEB)

Ott, Kevin; Linehan, Sue; Lipiecki, Frank; Aardahl, Christopher L.

2008-08-24

The DOE Hydrogen Storage Program is focused on identifying and developing viable hydrogen storage systems for onboard vehicular applications. The program funds exploratory research directed at identifying new materials and concepts for storage of hydrogen having high gravimetric and volumetric capacities that have the potential to meet long term technical targets for onboard storage. Approaches currently being examined are reversible metal hydride storage materials, reversible hydrogen sorption systems, and chemical hydrogen storage systems. The latter approach concerns materials that release hydrogen in endothermic or exothermic chemical bond-breaking processes. To regenerate the spent fuels arising from hydrogen release from such materials, chemical processes must be employed. These chemical regeneration processes are envisioned to occur offboard the vehicle.

Nonlinear optics quantum computing with circuit QED.

Science.gov (United States)

Adhikari, Prabin; Hafezi, Mohammad; Taylor, J M

2013-02-08

One approach to quantum information processing is to use photons as quantum bits and rely on linear optical elements for most operations. However, some optical nonlinearity is necessary to enable universal quantum computing. Here, we suggest a circuit-QED approach to nonlinear optics quantum computing in the microwave regime, including a deterministic two-photon phase gate. Our specific example uses a hybrid quantum system comprising a LC resonator coupled to a superconducting flux qubit to implement a nonlinear coupling. Compared to the self-Kerr nonlinearity, we find that our approach has improved tolerance to noise in the qubit while maintaining fast operation.

Chemical sensors and gas sensors for process control in biotechnology

International Nuclear Information System (INIS)

Williams, D.E.

1988-04-01

This paper is concerned with the possibilities for chemical measurement of the progress of biotechnological processes which are offered by devices already developed for other demanding applications. It considers the potential use of ultrasonic instrumentation originally developed for the nuclear industry, gas measurement methods from the fields of environmental monitoring and combustion control, nuclear instruments developed for the oil, mining and chemical industries, robotic systems and advanced control techniques. (author)

Chemical process measurements in PWR-type nuclear power plants

International Nuclear Information System (INIS)

Glaeser, E.

1978-01-01

In order to achieve high levels of availability of nuclear power plants equipped with pressurized water reactors, strict standards have to be applied to the purity of coolant and of other media. Chemical process measurements can meet these requirements only if programmes are established giving maximum information with minimum expenditure and if these programmes are realized with effective analytical methods. Analysis programmes known from literature are proved for their usefulness, and hints are given for establishing rational programmes. Analytical techniques are compared with each other taking into consideration both methods which have already been introduced into nuclear power plant practice and methods not yet generally used in practice, such as atomic absorption spectrophotometry, gas chromatography, etc. Finally, based on the state of the art of chemical process measurements in nuclear power plants, the trends of future development are pointed out. (author)

In-can melting demonstration of wastes from the Idaho Chemical Processing Plant

International Nuclear Information System (INIS)

Bjorklund, W.J.; Chick, L.A.; Hollis, H.H.; Mellinger, G.B.; Nelson, T.A.; Petkus, L.L.

1980-07-01

The immobilization of Idaho Chemical Processing Plant (ICPP) zirconia calcine using Idaho glass composition (ICPP-127) was evaluated at Pacific Northwest Laboratory (PNL) in two engineering-scale in-can melter tests. The glass was initially characterized in the laboratory to verify processing parameters. Glass was then produced in a pilot-scale melter and then in a full-scale melter to evaluate the processing and the resultant product. Potential corrosion problems were identified with the glass and some processing problems were encountered, but neither is insurmountable. The product is a durable leach-resistant glass. The glass appears to be nonhomogeneous, but chemically it is quite uniform

The General Laws of Chemical Elements Composition Dynamics in the Biosphere

Science.gov (United States)

Korzh, Vyacheslav D.

2013-04-01

The key point of investigation of the specificity of the biosphere elemental composition formation is determination of patterns of redistribution of elemental average concentrations among various phases, like solid - liquid ( the lithosphere - the hydrosphere), which occurs as a result of a global continuous processing of inert matter by living substances. Our task here is to investigate this process in the system "lithosphere - hydrosphere" in view of the integrated involvement of living material in it. This process is most active in biogeochemical barriers, i.e. in places of "the life condensation" and runs under a nonlinear regularity that has been unknown before. It is established that this process results in a general relative increase in concentrations of chemical elements in the solid phase in proportion as their prevalence in the environment is reduced. This process running in various natural systems has practically the same parameter of nonlinearity (v) approximately equal to 0.7. For proto-lithosphere -"living material" - soil v = 0.75. For river - "living material" - ocean v = 0.67. For the contemporary factual awareness level these estimations of nonlinearity indices are practically negligible. Hence, it is for the first time that the existence of a universal constant of nonlinearity of elemental composition evolution in the biosphere has been proved and its quantitative evaluation has been made. REFERENCES 1. Korzh V.D. 1974. Some general laws governing the turnover of substance within the ocean-atmosphere-continent-ocean cycle. // Journal de Recherches Atmospheriques. Vol. 8. P. 653-660. 2. Korzh V.D. 2008. The general laws in the formation of the elemental composition of the Hydrosphere and Biosphere.// J. Ecologica, Vol. XV, P. 13-21. 3. Korzh V.D. 2012. Determination of general laws of elemental composition in Hydrosphere // Water: chemistry & ecology, Journal of water science and its practical application. # 1, P.56-62.

40 CFR 63.443 - Standards for the pulping system at kraft, soda, and semi-chemical processes.

Science.gov (United States)

2010-07-01

... Paper Industry § 63.443 Standards for the pulping system at kraft, soda, and semi-chemical processes. (a... operator of each pulping system using a semi-chemical or soda process subject to the requirements of this... kraft, soda, and semi-chemical processes. 63.443 Section 63.443 Protection of Environment ENVIRONMENTAL...

Third-order nonlinear optical properties of GeSe2-Ga2Se3-PbI2 glasses

International Nuclear Information System (INIS)

Tang Gao; Liu Cunming; Luo Lan; Chen Wei

2010-01-01

The third-order nonlinear optical (NLO) properties of new selenium-based GeSe 2 -Ga 2 Se 3 -PbI 2 glasses have been measured using the optical Kerr effect (OKE) technique, with picosecond and femtosecond laser pulses. The 0.70GeSe 2 -0.15Ga 2 Se 3 -0.15PbI 2 glass has the largest third-order optical nonlinear susceptibility in GeSe 2 -Ga 2 Se 3 -PbI 2 glass system with χ (3) of 5.28x10 12 esu. In addition, the response time of glasses is sub-picosecond, which is predominantly associated with electron cloud. Local structure of the glasses has been identified by using Raman studies, while the origins of the observed nonlinear optical response are discussed. The [Ge(Ga)Se 4 ] tetrahedral and lone-pair electrons from highly polarizable Pb atom in glasses play an important role in enhanced NLO response. These results as well as their good chemical stability indicate that GeSe 2 -Ga 2 Se 3 -PbI 2 glasses are promising materials for photonic applications of third-order nonlinear optical signal processing.

A systems engineering approach to manage the complexity in sustainable chemical product-process design

DEFF Research Database (Denmark)

Gani, Rafiqul

This paper provides a perspective on model-data based solution approaches for chemical product-process design, which consists of finding the identity of the candidate chemical product, designing the process that can sustainably manufacture it and verifying the performance of the product during...... application. The chemical product tree is potentially very large and a wide range of options exist for selecting the product to make, the raw material to use as well as the processing route to employ. It is shown that systematic computer-aided methods and tools integrated within a model-data based design...

Supercritical Fluids Processing of Biomass to Chemicals and Fuels

Energy Technology Data Exchange (ETDEWEB)

Olson, Norman K. [Iowa State Univ., Ames, IA (United States)

2011-09-28

The main objective of this project is to develop and/or enhance cost-effective methodologies for converting biomass into a wide variety of chemicals, fuels, and products using supercritical fluids. Supercritical fluids will be used both to perform reactions of biomass to chemicals and products as well as to perform extractions/separations of bio-based chemicals from non-homogeneous mixtures. This work supports the Biomass Program’s Thermochemical Platform Goals. Supercritical fluids are a thermochemical approach to processing biomass that, while aligned with the Biomass Program’s interests in gasification and pyrolysis, offer the potential for more precise and controllable reactions. Indeed, the literature with respect to the use of water as a supercritical fluid frequently refers to “supercritical water gasification” or “supercritical water pyrolysis.”

Nonlinear radiation generation processes in the auroral acceleration region

Directory of Open Access Journals (Sweden)

R. Pottelette

2017-11-01

Full Text Available It is known from laboratory plasma experiments that double layers (DLs radiate in the electromagnetic spectrum; but this is only known qualitatively. In these experiments, it was shown that the electron beam created on the high-potential side of a DL generates nonlinear structures which couple to electromagnetic waves and act as a sender antenna. In the Earth auroral region, observations performed by auroral spacecraft have shown that DLs occur naturally in the source region of intense radio emissions called auroral kilometric radiation (AKR. Very high time-, spatial-, and temporal-resolution measurements are needed in order to characterize waves and particle distributions in the vicinity of DLs, which are moving transient structures. We report observations from the FAST satellite of a localized large-amplitude parallel electric field (∼ 300 mV m−1 recorded at the edges of the auroral density cavity. In agreement with laboratory experiments, on the high-potential side of the DL, elementary radiation events are detected. They occur substantially above the local electron gyrofrequency and are associated with the presence of electron holes. The velocity of these nonlinear structures can be derived from the measurement of the Doppler-shifted AKR frequency spectrum above the electron gyrofrequency. The generated electron holes appear as the nonlinear evolution of electrostatic waves generated by the electron–electron two-stream instability because they propagate at about half the beam velocity. It is pointed out that, in the vicinity of a DL, the shape of the electron distribution gives rise to a significant power recorded in the left-hand polarized ordinary (LO mode.

Topological approximation of the nonlinear Anderson model

Science.gov (United States)

Milovanov, Alexander V.; Iomin, Alexander

2014-06-01

We study the phenomena of Anderson localization in the presence of nonlinear interaction on a lattice. A class of nonlinear Schrödinger models with arbitrary power nonlinearity is analyzed. We conceive the various regimes of behavior, depending on the topology of resonance overlap in phase space, ranging from a fully developed chaos involving Lévy flights to pseudochaotic dynamics at the onset of delocalization. It is demonstrated that the quadratic nonlinearity plays a dynamically very distinguished role in that it is the only type of power nonlinearity permitting an abrupt localization-delocalization transition with unlimited spreading already at the delocalization border. We describe this localization-delocalization transition as a percolation transition on the infinite Cayley tree (Bethe lattice). It is found in the vicinity of the criticality that the spreading of the wave field is subdiffusive in the limit t →+∞. The second moment of the associated probability distribution grows with time as a power law ∝ tα, with the exponent α =1/3 exactly. Also we find for superquadratic nonlinearity that the analog pseudochaotic regime at the edge of chaos is self-controlling in that it has feedback on the topology of the structure on which the transport processes concentrate. Then the system automatically (without tuning of parameters) develops its percolation point. We classify this type of behavior in terms of self-organized criticality dynamics in Hilbert space. For subquadratic nonlinearities, the behavior is shown to be sensitive to the details of definition of the nonlinear term. A transport model is proposed based on modified nonlinearity, using the idea of "stripes" propagating the wave process to large distances. Theoretical investigations, presented here, are the basis for consistency analysis of the different localization-delocalization patterns in systems with many coupled degrees of freedom in association with the asymptotic properties of the

Chemical Assessment of White Wine during Fermentation Process

Directory of Open Access Journals (Sweden)

Teodora Coldea

2014-05-01

Full Text Available There were investigated chemical properties of indigenous white wine varieties (Fetească albă, Fetească regală and Galbenă de Odobeşti during fermentation. The white wine making process took place at Wine Pilot Station of University of Agricultural Sciences and Veterinary Medicine Cluj-Napoca. We aimed to monitorize the evolution of fermentation process parameters (temperature, alcohol content, and real extract and the quality of the bottled white wine (total acidity, alcohol content, total sulfur dioxide, total dry extract. The results obtained were in accordance to Romanian Legislation.

A process for treatment of mixed waste containing chemical plating wastes

International Nuclear Information System (INIS)

Anast, K.R.; Dziewinski, J.; Lussiez, G.

1995-01-01

The Waste Treatment and Minimization Group at Los Alamos National Laboratory has designed and will be constructing a transportable treatment system to treat low-level radioactive mixed waste generated during plating operations. The chemical and plating waste treatment system is composed of two modules with six submodules, which can be trucked to user sites to treat a wide variety of aqueous waste solutions. The process is designed to remove the hazardous components from the waste stream, generating chemically benign, disposable liquids and solids with low level radioactivity. The chemical and plating waste treatment system is designed as a multifunctional process capable of treating several different types of wastes. At this time, the unit has been the designated treatment process for these wastes: Destruction of free cyanide and metal-cyanide complexes from spent plating solutions; destruction of ammonia in solution from spent plating solutions; reduction of Cr VI to Cr III from spent plating solutions, precipitation, solids separation, and immobilization; heavy metal precipitation from spent plating solutions, solids separation, and immobilization, and acid or base neutralization from unspecified solutions

Preisach hysteresis model for non-linear 2D heat diffusion

International Nuclear Information System (INIS)

Jancskar, Ildiko; Ivanyi, Amalia

2006-01-01

This paper analyzes a non-linear heat diffusion process when the thermal diffusivity behaviour is a hysteretic function of the temperature. Modelling this temperature dependence, the discrete Preisach algorithm as general hysteresis model has been integrated into a non-linear multigrid solver. The hysteretic diffusion shows a heating-cooling asymmetry in character. The presented type of hysteresis speeds up the thermal processes in the modelled systems by a very interesting non-linear way

Thermally stimulated nonlinear refraction in gelatin stabilized Cu-PVP nanocomposite thin films

Energy Technology Data Exchange (ETDEWEB)

Tamgadge, Y. S., E-mail: ystamgadge@gmail.com; Atkare, D. V. [Department of Physics, Mahatma Fule Arts, Commerce & SitaramjiChoudhari Science College, Warud, Dist. Amravati (MS), India-444906 (India); Pahurkar, V. G.; Muley, G. G., E-mail: gajananggm@yahoo.co.in [Department of Physics, SantGadge Baba Amravati University, Amravati (MS), India-444602 (India); Talwatkar, S. S. [Department of Physics, D K Marathe and N G Acharya College, Chembur, Mumbai (MS), India-440071 (India); Sunatkari, A. L. [Department of Physics, Siddharth College of Arts, Science and Commerce, Fort, Mumbai (MS), India-440001 (India)

2016-05-06

This article illustrates investigations on thermally stimulated third order nonlinear refraction of Cu-PVP nanocomposite thin films. Cu nanoparticles have been synthesized using chemical reduction method and thin films in PVP matrix have been obtained using spin coating technique. Thin films have been characterized by X-ray diffraction (XRD) and Ultraviolet-visible (UV-vis) spectroscopyfor structural and linear optical studies. Third order nonlinear refraction studies have been performed using closed aperture z-scan technique under continuous wave (CW) He-Ne laser. Cu-PVP nanocomposites are found to exhibit strong nonlinear refractive index stimulated by thermal lensing effect.

Digital signals processing using non-linear orthogonal transformation in frequency domain

Directory of Open Access Journals (Sweden)

Ivanichenko E.V.

2017-12-01

Full Text Available The rapid progress of computer technology in recent decades led to a wide introduction of methods of digital information processing practically in all fields of scientific research. In this case, among various applications of computing one of the most important places is occupied by digital processing systems signals (DSP that are used in data processing remote solution tasks of navigation of aerospace and marine objects, communications, radiophysics, digital optics and in a number of other applications. Digital Signal Processing (DSP is a dynamically developing an area that covers both technical and software tools. Related areas for digital signal processing are theory information, in particular, the theory of optimal signal reception and theory pattern recognition. In the first case, the main problem is signal extraction against a background of noise and interference of a different physical nature, and in the second - automatic recognition, i.e. classification and signal identification. In the digital processing of signals under a signal, we mean its mathematical description, i.e. a certain real function, containing information on the state or behavior of a physical system under an event that can be defined on a continuous or discrete space of time variation or spatial coordinates. In the broad sense, DSP systems mean a complex algorithmic, hardware and software. As a rule, systems contain specialized technical means of preliminary (or primary signal processing and special technical means for secondary processing of signals. Means of pretreatment are designed to process the original signals observed in general case against a background of random noise and interference of a different physical nature and represented in the form of discrete digital samples, for the purpose of detecting and selection (selection of the useful signal and evaluation characteristics of the detected signal. A new method of digital signal processing in the frequency

Chemically etched sharpened tip of transparent crystallized glass fibers with nonlinear optical Ba2TiSi2O8 nanocrystals

International Nuclear Information System (INIS)

Enomoto, Itaru; Benino, Yasuhiko; Komatsu, Takayuki; Fujiwara, Takumi

2007-01-01

Glass fibers with a diameter of ∼100 μm are drawn by just pulling up melts of 40BaO·20TiO 2 ·40SiO 2 glass, and transparent crystallized glass fibers consisting of nonlinear optical fresnoite Ba 2 TiSi 2 O 8 nanocrystals (particle size: ∼100-200 nm) are fabricated by crystallization of glass fibers. Precursor glass fibers and nanocrystallized glass fibers are etched chemically using a meniscus method, in which an etching solution of 0.1wt%-HF/hexane is used. Glass fibers with sharpened tips (e.g., the taper length is ∼L=200 μm and the tip angle is ∼θ=23deg) are obtained. It is found that etched nanocrystallized glass fibers also have sharpened tips (L=50 μm, θ=80deg). Compared with precursor glass fibers, nanocrystallized glass fibers show a high resistance against chemical etching in a 0.1 wt%HF solution. Although sharpened tips in nanocrystallized glass fibers do not have nanoscaled apertures, the present study suggests that nanocrystallized glass fibers showing second harmonic generations would have a potential for fiber-type light control optical devices. (author)

Non-Linear Behaviour Of Gelatin Networks Reveals A Hierarchical Structure

KAUST Repository

Yang, Zhi; Hemar, Yacine; Hilliou, loic; Gilbert, Elliot P.; McGillivray, Duncan James; Williams, Martin A. K.; Chaieb, Saharoui

2015-01-01

We investigate the strain hardening behaviour of various gelatin networks - namely physically-crosslinked gelatin gel, chemically-crosslinked gelatin gels, and a hybrid gels made of a combination of the former two - under large shear deformations using the pre-stress, strain ramp, and large amplitude oscillation shear protocols. Further, the internal structures of physically-crosslinked gelatin gel and chemically-crosslinked gelatin gels were characterized by small angle neutron scattering (SANS) to enable their internal structures to be correlated with their nonlinear rheology. The Kratky plots of SANS data demonstrate the presence of small cross-linked aggregates within the chemically-crosslinked network, whereas in the physically-crosslinked gels a relatively homogeneous structure is observed. Through model fitting to the scattering data, we were able to obtain structural parameters, such as correlation length (ξ), cross-sectional polymer chain radius (Rc), and the fractal dimension (df) of the gel networks. The fractal dimension df obtained from the SANS data of the physically-crosslinked and chemically crosslinked gels is 1.31 and 1.53, respectively. These values are in excellent agreement with the ones obtained from a generalized non-linear elastic theory we used to fit our stress-strain curves. The chemical crosslinking that generates coils and aggregates hinders the free stretching of the triple helices bundles in the physically-crosslinked gels.

Non-Linear Behaviour Of Gelatin Networks Reveals A Hierarchical Structure

KAUST Repository

Yang, Zhi

2015-12-14

We investigate the strain hardening behaviour of various gelatin networks - namely physically-crosslinked gelatin gel, chemically-crosslinked gelatin gels, and a hybrid gels made of a combination of the former two - under large shear deformations using the pre-stress, strain ramp, and large amplitude oscillation shear protocols. Further, the internal structures of physically-crosslinked gelatin gel and chemically-crosslinked gelatin gels were characterized by small angle neutron scattering (SANS) to enable their internal structures to be correlated with their nonlinear rheology. The Kratky plots of SANS data demonstrate the presence of small cross-linked aggregates within the chemically-crosslinked network, whereas in the physically-crosslinked gels a relatively homogeneous structure is observed. Through model fitting to the scattering data, we were able to obtain structural parameters, such as correlation length (ξ), cross-sectional polymer chain radius (Rc), and the fractal dimension (df) of the gel networks. The fractal dimension df obtained from the SANS data of the physically-crosslinked and chemically crosslinked gels is 1.31 and 1.53, respectively. These values are in excellent agreement with the ones obtained from a generalized non-linear elastic theory we used to fit our stress-strain curves. The chemical crosslinking that generates coils and aggregates hinders the free stretching of the triple helices bundles in the physically-crosslinked gels.

Dynamic Processes of Conceptual Change: Analysis of Constructing Mental Models of Chemical Equilibrium.

Science.gov (United States)

Chiu, Mei-Hung; Chou, Chin-Cheng; Liu, Chia-Ju

2002-01-01

Investigates students' mental models of chemical equilibrium using dynamic science assessments. Reports that students at various levels have misconceptions about chemical equilibrium. Involves 10th grade students (n=30) in the study doing a series of hands-on chemical experiments. Focuses on the process of constructing mental models, dynamic…

A comparison of two different processing chemicals for mammography: Repercussion on dose to patients

International Nuclear Information System (INIS)

Sendra-Portero, F.; Ristori-Bogajo, E.; Buch-Tome, P.; Martinez-Morillo, M.; Nava-Baro, E.

2001-01-01

The main technical objective of screen-film mammography is to reach the best image quality with the lowest dose to the breast. Sensitometric gradient and speed are factors related to both subjects respectively. For a given choice of film, these factors are affected by processing variables. For this reason, manufacturers have developed different types of films that are recommended for particular processing conditions. The purpose of this work is to compare the variations of both sensitometric characteristics of mammographic screen and film systems induced by two different manufactured chemicals: RPX-Omat EX/LO (Kodak) and G139/G334 (Agfa). A comparison of thirteen mammographic films by means of light sensitometry was performed at different processing conditions: 90s/Kodak, 120s/Kodak, 180s/Kodak, 90s/Agfa, 120s/Agfa and 180s/Agfa. Secondly, 99 combinations of screens and films were evaluated by X-ray sensitometry at 120s/Kodak and 120s/Agfa processing. At light sensitometry, variations in processing time led to different modifications in film speed, depending on the chemicals used. At X-Ray sensitometry, Agfa chemicals induced higher values of sensitivity for almost all combinations, while Kodak chemicals gave higher gradient/speed quotient. The results show that dose to patients in mammography and image contrast are highly dependent on the chemicals selected at medium cycle (120s) processing. (author)

Coarse grain model for coupled thermo-mechano-chemical processes and its application to pressure-induced endothermic chemical reactions

International Nuclear Information System (INIS)

Antillon, Edwin; Banlusan, Kiettipong; Strachan, Alejandro

2014-01-01

We extend a thermally accurate model for coarse grain dynamics (Strachan and Holian 2005 Phys. Rev. Lett. 94 014301) to enable the description of stress-induced chemical reactions in the degrees of freedom internal to the mesoparticles. Similar to the breathing sphere model, we introduce an additional variable that describes the internal state of the particles and whose dynamics is governed both by an internal potential energy function and by interparticle forces. The equations of motion of these new variables are derived from a Hamiltonian and the model exhibits two desired features: total energy conservation and Galilean invariance. We use a simple model material with pairwise interactions between particles and study pressure-induced chemical reactions induced by hydrostatic and uniaxial compression. These examples demonstrate the ability of the model to capture non-trivial processes including the interplay between mechanical, thermal and chemical processes of interest in many applications. (paper)

Slaughterhouse wastewater treatment by combined chemical coagulation and electrocoagulation process.

Science.gov (United States)

Bazrafshan, Edris; Kord Mostafapour, Ferdos; Farzadkia, Mehdi; Ownagh, Kamal Aldin; Mahvi, Amir Hossein

2012-01-01

Slaughterhouse wastewater contains various and high amounts of organic matter (e.g., proteins, blood, fat and lard). In order to produce an effluent suitable for stream discharge, chemical coagulation and electrocoagulation techniques have been particularly explored at the laboratory pilot scale for organic compounds removal from slaughterhouse effluent. The purpose of this work was to investigate the feasibility of treating cattle-slaughterhouse wastewater by combined chemical coagulation and electrocoagulation process to achieve the required standards. The influence of the operating variables such as coagulant dose, electrical potential and reaction time on the removal efficiencies of major pollutants was determined. The rate of removal of pollutants linearly increased with increasing doses of PACl and applied voltage. COD and BOD(5) removal of more than 99% was obtained by adding 100 mg/L PACl and applied voltage 40 V. The experiments demonstrated the effectiveness of chemical and electrochemical techniques for the treatment of slaughterhouse wastewaters. Consequently, combined processes are inferred to be superior to electrocoagulation alone for the removal of both organic and inorganic compounds from cattle-slaughterhouse wastewater.

Slaughterhouse Wastewater Treatment by Combined Chemical Coagulation and Electrocoagulation Process

Science.gov (United States)

Bazrafshan, Edris; Kord Mostafapour, Ferdos; Farzadkia, Mehdi; Ownagh, Kamal Aldin; Mahvi, Amir Hossein

2012-01-01

Slaughterhouse wastewater contains various and high amounts of organic matter (e.g., proteins, blood, fat and lard). In order to produce an effluent suitable for stream discharge, chemical coagulation and electrocoagulation techniques have been particularly explored at the laboratory pilot scale for organic compounds removal from slaughterhouse effluent. The purpose of this work was to investigate the feasibility of treating cattle-slaughterhouse wastewater by combined chemical coagulation and electrocoagulation process to achieve the required standards. The influence of the operating variables such as coagulant dose, electrical potential and reaction time on the removal efficiencies of major pollutants was determined. The rate of removal of pollutants linearly increased with increasing doses of PACl and applied voltage. COD and BOD5 removal of more than 99% was obtained by adding 100 mg/L PACl and applied voltage 40 V. The experiments demonstrated the effectiveness of chemical and electrochemical techniques for the treatment of slaughterhouse wastewaters. Consequently, combined processes are inferred to be superior to electrocoagulation alone for the removal of both organic and inorganic compounds from cattle-slaughterhouse wastewater. PMID:22768233

Improved ADM1 model for anaerobic digestion process considering physico-chemical reactions.

Science.gov (United States)

Zhang, Yang; Piccard, Sarah; Zhou, Wen

2015-11-01

The "Anaerobic Digestion Model No. 1" (ADM1) was modified in the study by improving the bio-chemical framework and integrating a more detailed physico-chemical framework. Inorganic carbon and nitrogen balance terms were introduced to resolve the discrepancies in the original bio-chemical framework between the carbon and nitrogen contents in the degraders and substrates. More inorganic components and solids precipitation processes were included in the physico-chemical framework of ADM1. The modified ADM1 was validated with the experimental data and used to investigate the effects of calcium ions, magnesium ions, inorganic phosphorus and inorganic nitrogen on anaerobic digestion in batch reactor. It was found that the entire anaerobic digestion process might exist an optimal initial concentration of inorganic nitrogen for methane gas production in the presence of calcium ions, magnesium ions and inorganic phosphorus. Copyright © 2015 Elsevier Ltd. All rights reserved.

Investigations on an environment friendly chemical reaction process (eco-chemistry). 2; Kankyo ni yasashii kagaku hanno process (eko chemistry) ni kansuru chosa. 2

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-03-01

In order to structure a chemical reaction process that does not discharge a large amount of waste by-products or harmful chemical substances, or so-called environment friendly process, investigations and discussions were given based on the results derived in the previous fiscal year. A proposal was made to reduce environmental load on development of oxidized and dehydrogenated catalysts that can produce selectively ethylene, propylene and isobutylene in an oxidation process. In liquid phase oxidation, redox-based oxidation and solid catalyzation of automatic oxidation reaction were enumerated. In acid base catalyst reaction, development of ultra strong solid acid was described to structure no pollution discharging process. In the fine chemical and pharmaceutical fields, the optical active substance method and the position-selective aromatics displacement reaction were evaluated to reduce environmental load. A questionnaire survey performed on major chemical corporations inside and outside the country revealed the following processes as the ones that can cause hidden environmental problems: processes discharging large amount of wastes, processes treating dangerous materials, and processes consuming large amount of energy. Development of catalysts is important that can realize high yield, high selectivity and reactions under mild conditions as a future environment harmonizing chemical process. 117 refs., 23 figs., 22 tabs.

Non-linear multivariable predictive control of an alcoholic fermentation process using functional link networks

Directory of Open Access Journals (Sweden)

Luiz Augusto da Cruz Meleiro

2005-06-01

Full Text Available In this work a MIMO non-linear predictive controller was developed for an extractive alcoholic fermentation process. The internal model of the controller was represented by two MISO Functional Link Networks (FLNs, identified using simulated data generated from a deterministic mathematical model whose kinetic parameters were determined experimentally. The FLN structure presents as advantages fast training and guaranteed convergence, since the estimation of the weights is a linear optimization problem. Besides, the elimination of non-significant weights generates parsimonious models, which allows for fast execution in an MPC-based algorithm. The proposed algorithm showed good potential in identification and control of non-linear processes.Neste trabalho um controlador preditivo não linear multivariável foi desenvolvido para um processo de fermentação alcoólica extrativa. O modelo interno do controlador foi representado por duas redes do tipo Functional Link (FLN, identificadas usando dados de simulação gerados a partir de um modelo validado experimentalmente. A estrutura FLN apresenta como vantagem o treinamento rápido e convergência garantida, já que a estimação dos seus pesos é um problema de otimização linear. Além disso, a eliminação de pesos não significativos gera modelos parsimoniosos, o que permite a rápida execução em algoritmos de controle preditivo baseado em modelo. Os resultados mostram que o algoritmo proposto tem grande potencial para identificação e controle de processos não lineares.

Chemical Vapor Deposition of Photocatalyst Nanoparticles on PVDF Membranes for Advanced Oxidation Processes

Directory of Open Access Journals (Sweden)

Giovanni De Filpo

2018-06-01

Full Text Available The chemical binding of photocatalytic materials, such as TiO2 and ZnO nanoparticles, onto porous polymer membranes requires a series of chemical reactions and long purification processes, which often result in small amounts of trapped nanoparticles with reduced photocatalytic activity. In this work, a chemical vapor deposition technique was investigated in order to allow the nucleation and growth of ZnO and TiO2 nanoparticles onto polyvinylidene difluoride (PVDF porous membranes for application in advanced oxidation processes. The thickness of obtained surface coatings by sputtered nanoparticles was found to depend on process conditions. The photocatalytic efficiency of sputtered membranes was tested against both a model drug and a model organic pollutant in a small continuous flow reactor.

NONLINEAR EVOLUTION OF BEAM-PLASMA INSTABILITY IN INHOMOGENEOUS MEDIUM

International Nuclear Information System (INIS)

Ziebell, L. F.; Pavan, J.; Yoon, P. H.; Gaelzer, R.

2011-01-01

The problem of electron-beam propagation in inhomogeneous solar wind is intimately related to the solar type II and/or type III radio bursts. Many scientists have addressed this issue in the past by means of quasi-linear theory, but in order to fully characterize the nonlinear dynamics, one must employ weak-turbulence theory. Available numerical solutions of the weak-turbulence theory either rely on only one nonlinear process (either decay or scattering), or when both nonlinear terms are included, the inhomogeneity effect is generally ignored. The present paper reports the full solution of weak-turbulence theory that includes both decay and scattering processes, and also incorporating the effects of density gradient. It is found that the quasi-linear effect sufficiently accounts for the primary Langmuir waves, but to properly characterize the back-scattered Langmuir wave, which is important for eventual radiation generation, it is found that both nonlinear decay and scattering processes make comparable contributions. Such a finding may be important in the quantitative analysis of the plasma emission process with application to solar type II and/or type III radio bursts.

Numerical simulation study on rolling-chemical milling process of aluminum-lithium alloy skin panel

Science.gov (United States)

Huang, Z. B.; Sun, Z. G.; Sun, X. F.; Li, X. Q.

2017-09-01

Single curvature parts such as aircraft fuselage skin panels are usually manufactured by rolling-chemical milling process, which is usually faced with the problem of geometric accuracy caused by springback. In most cases, the methods of manual adjustment and multiple roll bending are used to control or eliminate the springback. However, these methods can cause the increase of product cost and cycle, and lead to material performance degradation. Therefore, it is of significance to precisely control the springback of rolling-chemical milling process. In this paper, using the method of experiment and numerical simulation on rolling-chemical milling process, the simulation model for rolling-chemical milling process of 2060-T8 aluminum-lithium alloy skin was established and testified by the comparison between numerical simulation and experiment results for the validity. Then, based on the numerical simulation model, the relative technological parameters which influence on the curvature of the skin panel were analyzed. Finally, the prediction of springback and the compensation can be realized by controlling the process parameters.

Single-step emulation of nonlinear fiber-optic link with gaussian mixture model

DEFF Research Database (Denmark)

Borkowski, Robert; Doberstein, Andy; Haisch, Hansjörg

2015-01-01

We use a fast and low-complexity statistical signal processing method to emulate nonlinear noise in fiber links. The proposed emulation technique stands in good agreement with the numerical NLSE simulation for 32 Gbaud DP-16QAM nonlinear transmission.......We use a fast and low-complexity statistical signal processing method to emulate nonlinear noise in fiber links. The proposed emulation technique stands in good agreement with the numerical NLSE simulation for 32 Gbaud DP-16QAM nonlinear transmission....

Study on microwave assisted process in chemical extraction

International Nuclear Information System (INIS)

Amer Ali; Rosli Mohd Yunus; Ramlan Abd Aziz

2001-01-01

The microwave assisted process is a revolutionary method of extraction that reduces the extraction time to as little as a few seconds, with up to a ten-fold decrease in the use of solvents. The target material is immersed in solvent that is transparent to microwaves, so only the target material is heated, and because of the microwaves tend to heat the inside of the material quickly, the target chemical are expelled in a few seconds. benefits from this process include significant reductions in the amount of energy required and substantial reductions in the cost and dispose of hazardous solvents. A thorough review has been displayed on: using the microwave in extraction, applications of microwave in industry, process flow diagram, mechanism of the process and comparison between microwave process and other extraction techniques (soxhlet, steam distillation and supercritical fluid). This review attempts to summarize the studies about microwave assisted process as a very promising technique. (Author)

Essentials of water systems design in the oil, gas, and chemical processing industries

CERN Document Server

Bahadori, Alireza; Boyd, Bill

2013-01-01

Essentials of Water Systems Design in the Oil, Gas and Chemical Processing Industries provides valuable insight for decision makers by outlining key technical considerations and requirements of four critical systems in industrial processing plants—water treatment systems, raw water and plant water systems, cooling water distribution and return systems, and fire water distribution and storage facilities. The authors identify the key technical issues and minimum requirements related to the process design and selection of various water supply systems used in the oil, gas, and chemical processing industries. This book is an ideal, multidisciplinary work for mechanical engineers, environmental scientists, and oil and gas process engineers.