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Sample records for ni okeru reaction

  1. Dissipative structure of mechanically stimulated reaction; Kikaiteki reiki hanno ni okeru san`itsu kozo

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    Hida, M. [Okayama Univ., Okayama (Japan). Faculty of Engineering

    1994-12-20

    Recently various studies have been conducted concerning the state changes of materials obtained through mechanical alloying (MA) or mechano-chemical (MC) processing. What is noticeable is the quasi-steady state of almost all the materials obtained through various processes including MA and MC, and that the super cooling, supersaturating and high residue distortion realized under unbalanced conditions have not been clarified. In other words, the tracing capability to the external binding conditions is low. In this report, the appearance of the high temperature phase and high pressure phase obtained through MA or MC processing, the forming of amorphous, the mesomerism of the amorphous materials, the interesting phenomena generated by combination between the mechanical disturbance and chemical reactions were discussed with concrete examples, and a steady dissipative organization theory was approached from the viewpoint of dissipative structure development which is equal to the forming process of the quasi-steady phase. 34 refs., 2 figs.

  2. Hydrogenolysis reactions characteristics of deashed coal under low temperature; Teionka ni okeru dakkai shoritan no suisoka bunkai hanno tokusei

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    Owada, T.; Mashimo, K.; Wainai, T. [Nihon University, Tokyo (Japan). College of Science and Technology

    1996-10-28

    In relation to coal liquefaction, the effect of inorganic minerals on liquefaction reactivity and the effect of hydrofluoric acid (HF) treatment on organic molecular structure of coals were studied by demineralization of low-rank coals in HCl or HF solution. In experiment, Taiheiyo coal specimen was deashed in HCl solution at 25-70{degree}C for 6 hours while agitating, and in addition, deashed in HF solution. Hydrogenolysis of the deashed coal specimen was conducted using tetralin or methylnaphthalene as solvent under initial hydrogen pressure of 1.96MPa at reaction temperature of 693K for 60min. The experimental results are as follows. The ash content of Taiheiyo coal hardly offers catalysis in hydrogenolysis reaction. Carboxyl group increases in demineralization of coal because of breakage of bridged bonds. Organic structure of coal changes by demineralization in dense HF solution. Change in organic structure of coal by demineralization in dense HF solution is dependent on treatment temperature. 2 refs., 4 figs., 1 tab.

  3. Autosolvent effect of bitumen in thermal cracking; Netsubunkai hanno ni okeru bitumen no jiko yobai koka

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    Mikuni, M.; Sato, M.; Hattori, H. [Hokkaido University, Sapporo (Japan). Center for Advanced Research of Energy Technology; Nagaishi, H.; Sasaki, M.; Yoshida, T. [Hokkaido National Industrial Research Institute, Sapporo (Japan)

    1996-10-28

    Tar sand bitumen is petroleum-based ultra-heavy oil, and has a great amount of reserve like coal. However, there are still a lot of problems for its highly effective utilization. This paper discusses whether the light components in bitumen show independent behavior during the thermal cracking of heavy components, or not. Solvent effect and reaction mechanism during the thermal cracking are also derived from the change of their chemical structures. Athabasca tar sand bitumen was separated into light and heavy fractions by vacuum distillation based on D-1660 of ASTM. Mixtures of the both fractions at various ratios were used as samples. Negative effect of the light fraction on cracking of the heavy fraction was observed with dealkylation and paraffin formation Polymerization of the dealkylated light fraction to the heavy fraction was suggested due to lack of hydrogen in the thermal cracking under nitrogen atmosphere, which resulted in the formation of polymer. 3 refs., 6 figs.

  4. Volatiles production from the coking of coal; Sekitan no netsubunkai ni okeru kihatsubun seisei

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    Yamashita, Y.; Saito, H.; Inaba, A. [National Institute for Resources and Environment, Tsukuba (Japan)

    1996-10-28

    In order to simplify the coke manufacturing process, a coke production mechanism in coal pyrolysis was discussed. Australian bituminous coal which can produce good coke was used for the discussion. At a temperature raising rate of 50{degree}C per minute, coal weight loss increases monotonously. However, in the case of 3{degree}C, the weight loss reaches a peak at a maximum ultimate temperature of about 550{degree}C. The reaction mechanism varies with the temperature raising rates, and in the case of 50{degree}C per minute, volatiles other than CO2 and propane increased. Weight loss of coal at 3{degree}C per minute was caused mainly by methane production at 550{degree}C or lower. When the temperature is raised to 600{degree}C, tar and CO2 increased, and so did the weight loss. Anisotropy was discerned in almost of all coke particles at 450{degree}C, and the anisotropy became remarkable with increase in the maximum ultimate temperature. Coke and volatiles were produced continuously at a temperature raising rate of 50{degree}C per minute, and at 3{degree}C per minute, the production of the coke and volatiles progressed stepwise as the temperature has risen. 7 refs., 6 figs.

  5. Improvement of magnetic properties of Fe-50mass%Ni in MIM process; MIM process ni okeru Fe-50mass%Ni no jiki tokusei kaizen

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    Miura, H. [Kumamoto University, Kumamoto (Japan). Faculty of Engineering; Fujita, S. [Kumamoto University, Kumamoto (Japan); Fujita, M.; Ninomiya, R. [Mitsuikinzoku Co. Ltd., Tokyo (Japan)

    2000-12-15

    Metal injection molding (MIM) process is hoped to be one of processing for required to more complicated parts of magnetic components. In this study, the effect of different types of powders (prealloyed and mixed elemental powders) on the magnetic properties of permalloy (Fe-50mass%Ni) through the MIM technique was investigated. Approximately 94% of theoretical density was obtained by using the prealloyed powder, and the retained carbon and oxygen contents were controlled to be low. On the other hand, 96% of theoretical density was obtained by using the mixed elemental powder, but the magnetic properties were inferior to that of prealloyed powder's because of high retained oxygen content. By using the carbonyl Fe powder with high carbon, the retained oxygen and carbon content could be controlled to be low, resulting in the improved magnetic properties. (author)

  6. Analysis of flame propagation phenomenon in simplified stratified charge conditions; Tanjunkasareta sojo kyukiba ni okeru kaen denpa gensho no kansatsu

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    Moriyoshi, Y.; Morikawa, H. [Chiba University, Chiba (Japan); Kamimoto, T. [Tokyo Institute of Technology, Tokyo (Japan)

    1997-10-01

    Since the local inhomogeneity of mixture concentration inside the cylinder affects the combustion characteristics, a basic research on combustion phenomenon in stratified charge conditions is required. The authors have made experiments with a constant-volume chamber, which can simulate an idealized stratified charge field by using a removable partition, to obtain the combustion characteristics. Also, numerical calculations are made using some combustion models. As a result, the important feature that the combustion speed is faster in stratified condition than in homogeneous condition can be predicted by the two-step reaction model. 4 refs., 8 figs.

  7. Studies on reactivity of coal surfaces at low temperature; Teion ni okeru sekitan hyomen no hannosei no kento

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    Yasuda, H.; Kaiho, M.; Yamada, O.; Soneda, Y.; Kobayashi, M.; Makino, M. [National Institute for Resources and Environment, Tsukuba (Japan)

    1996-10-28

    With an objective to learn reactivity of coal at its surface, surfaces of oxidized coal samples were investigated. Miike coal was oxidized by using {sup 18}O2 in a closed loop system. As the reaction progresses, proportion of CO2 including isotopes increased rapidly as a result of oxidation of CO sites existing in the coal and the newly generated C{sup 18}O sites. The oxidizing reaction progressed via oxygen adsorbing sites generated near the surface, and oxygen containing groups. An FT-IR analysis estimated the depth of the oxidized layer to be 10{mu}m or less from particle surface. The oxidized coal was pulverized to see its surface condition. Functional groups introduced by the oxidation enter into the vicinity of the surface in a form to desorb as CO. CO2 is trapped in inner pores. The coal surface was observed by using an atomic force microscope. No observable openings in the pore structure were discerned on the surface before the oxidation, and the structure agrees with a closed pore model. Surface image oxidized in-situ by oxygen for one hour had slight roundness, which led to a supposition of structural change, and changes in the functional group and adsorption species. 7 refs., 5 figs.

  8. Change of unit skeletons during an artificial coalification; Jinko sekitanka katei ni okeru tan`i kokkaku kozo no henka

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    Sugimoto, Y.; Miki, Y.; Hayamizu, K. [National Institute of Materials and Chemical Research, Tsukuba (Japan); Okada, K. [Coal Mining Research Center, Tokyo (Japan); Suzuki, Y. [Geological Survey of Japan, Tsukuba (Japan)

    1996-10-28

    In order to obtain knowledge about formation and growth of condensed ring structure in a coalification process, discussions were given on product skeleton structure by using hydrogenation and hydrocracking of heated cellulose. In underwater heating of cellulose, reaction of dehydration has occurred at 200{degree}C or lower, that of decarbonation at 250{degree}C or higher, and that of demethanizing at 300{degree}C, resulting in production of a dark-brown coal-like substance. The substance has lower H/C value and higher O/C value than coal. As the underwater heating temperature rises, the hydrogenation reactivity of the heated substance decreases, and so does the ratio of conversion into toluene solubles. These phenomena are related to strength of cross-linking bond between unit skeleton structures. A substance heated at an underwater heating temperature of 200{degree}C turns toluene-soluble almost completely even during the hydrogenation reaction (350{degree}C for 2 hours), but the soluble product decreases at underwater heating temperatures of 250 and 300{degree}C. However, soluble product of more than 90% was obtained when hydrocracking (at 425{degree}C for one hour) was performed. The toluene-soluble product in the heated substance is only 50% when the underwater heating temperature reaches 350{degree}C even if the hydrocracking is carried out. 3 refs., 5 figs.

  9. Numerical simulation of coal combustion in circulating fluidized beds; Junkan ryudoso ni okeru sekitan nensho no suchi simulation

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    Schoenfelder, H. [Technical University Hamburg, Hamburg (Germany); Suzuki, Y.; Hatano, H. [National Institute for Resources and Environment, Tsukuba (Japan)

    1997-09-25

    A numerical simulator has been developed, using a one-dimensional heterogeneous reaction model, for circulating fluidized bed combustors. The model is based on the Johnson`s method for modeling circulating fluidized bed combustors operating at low gas velocity, and involves kinetic models of combustion process and fluidization mechanisms in circulating fluidized bed risers. In order to determine rate parameters for coal combustion, Chinese coal is combusted by a circulating fluidized bed combustor of quartz, installed at the National Institute for Resources and Environment. The simulation after parameter-fitting indicates that char produced from coal shows a medium activity for NO reduction and very low activity for N2O reduction. It is also found that reduction of No by CO is very important. The simulator satisfactorily gives gas concentration at the combustor outlet and axial distributions of the vapor component concentrations. 19 refs., 11 figs., 5 tabs.

  10. Effects of solvent and catalysts on the hydrogenolysis of alkylnaphthalenes; Alkylnaphthalene no suisoka bunkai ni okeru yobai to shokubai no koka

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    Futamura, S. [National Institute for Resources and Environment, Tsukuba (Japan)

    1996-10-28

    Catalytic effects of metal and carbon materials, which promote hydrogen transfer from hydrogen donor solvents, are investigated during hydrogenolysis of benzyl-1-methylnaphthalenes (BMN) selected as a hydrogen acceptor. For the isomer distribution of BMN after the reaction, almost the same molecular ratio before the reaction was obtained independent of the presence of catalysts. Selectivity of position during the addition of hydrogen atoms from tetralin was not found. For the reaction of BMN in tetralin, 1-methylnaphthalene and toluene were obtained as products, but the formation of benzylnaphthalene was not found. As for the nuclear hydride of BMN, the trace amount formation was confirmed by gas chromatography. For the hydrogen transfer from tetralin progressed catalytically, it was found that the nuclear of naphthalene can not be hydrogenated easily. This was considered to be due to the obstruction of hydrogen transfer from tetralin by the strong adsorption of BMN on the Ni surface. 1 ref., 1 fig., 2 tabs.

  11. Study of the influence of microgravity on the biological cells and molecular level; Seitai saibo bunshi level ni okeru bisho juryoku no eikyo ni kansuru kenkyu

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    NONE

    1996-03-01

    The shape of osteoblast, gene appearance, gene of rice blast, cellular fusion of plants, gravity acceptance mechanism of unicellular organisms, and physiological and immunity functions of mice were investigated under the microgravity condition. The influence of gravity on the vital reaction and the influence of microgravity on the crystallization of vital substances were also investigated. For the observation of osteoblast, the fluorescence dye reacted with Ca was well taken in the cells. The microgravity affected the stability of rice blast, but hardly affected the protoplast culture of mushroom. The reaction of ciliate against the gravity related to the specific gravity difference between cells and outer liquid. The level of adrenaline in blood of mice increased during the drop. The moving speed of trigger waves of chemical parallel slit formed at the BZ reaction under the microgravity became 60% to 80% of that on the ground. In the case of crystallization at the deposition agent concentration of 1% to 4%, the turbidity showing the degree of crystallization changed complicatedly. Nine processes of crystal growth were recognized. 21 refs., 55 figs., 1 tab.

  12. Solid state SiC/Ni alloy reaction

    Science.gov (United States)

    Jackson, M. R.; Mehan, R. L.; Davis, A. M.; Hall, E. L.

    1983-02-01

    The solid state reaction between silicon carbide and a model superalloy consisting of 70 at. pct Ni, 20 at. pct Cr, and 10 at. pct Al was studied between 700 °C and 1150 °C for times ranging from “0” hours to 330 hours. Reaction couples consisting of SiC/Ni, SiC/Cr, and SiC/NiCr were also studied. The reactions were carried out in air with the materials, in the shape of discs, maintained in contact under a pressure of 7 MPa. A reaction was detected with SiC and the model alloy at all temperatures studied, and the reaction was diffusion controlled with an activation energy of 184 kJ/mole. In the ceramic the reaction was dominated by the diffusion of Ni into the ceramic forming a banded structure consisting of alternating layers of δ-Ni2Si and a two phase mixture of graphite and δ. On the metal side, the reaction was very dependent on the presence of alloying elements, with pure Ni reacting to the greatest extent, followed by the binary NiCr alloy, and finally by NiCrAl. The growth and presence of the phases detected in these reactions is consistent with phase equilibria concepts.

  13. Coal liquefaction in early stage of NEDOL process 1t/d PSU; 1t/d PSU ni okeru ekika shoki hanno ni kansuru kento

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    Ikeda, K.; Kawabata, M.; Mochizuki, M.; Imada, K. [Nippon Steel Corp., Tokyo (Japan); Nogami, Y.; Inokuchi, K. [Mitsui SRC Development Co. Ltd., Tokyo (Japan)

    1996-10-28

    To investigate the behavior of coal liquefaction reaction in early stage as a part of studies on the coal liquefaction characteristics using NEDOL process 1 t/d process supporting unit (PSU), coal slurry sample was taken from the outlet of slurry preheater located in the upflow of liquefaction reactors, and was tested. Tanito Harum coal was used for liquefaction. Preheater was operated under the condition of pressure of 170 kg/cm{sup 2}, gas flow rate of 64 Nm{sup 3}/hr, and at temperature up to 410{degree}C at the outlet, in response to the standard test condition. The slurry sample was discharged into a high temperature separator with temperature of 250{degree}C. Liquefaction was not proceeded at the outlet of preheater. Solid residue yielded around 80%, and liquid yielded around 15%. Gases, CO and CO2, and water yielded also small amount around 3%. The solid sample contained much IOM fraction (tetrahydrofuran-insoluble and ash), and the liquid contained much heavy oil fraction. Hydrogenation was not proceeded, and the hydrogen consumption was very low showing below one-tenth of that at the usual operation. Hydrogen sulfide gas was formed at early stage, which suggested that the change of iron sulfide catalyst occur at early stage of liquefaction. 1 ref., 5 figs., 2 tabs.

  14. Investigation of the deposit formation in pipelines connecting liquefaction reactors; 1t/d PSU ni okeru ekika hanno tokan fuchakubutsu no seisei yoin ni kansuru ichikosatsu

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    Okada, Y.; Nogami, Y.; Inokuchi, K. [Mitsui SRC Development Co. Ltd., Tokyo (Japan); Mochizuki, M.; Imada, K. [Nippon Steel Corp., Tokyo (Japan)

    1996-10-28

    The liquefaction reaction system of an NEDOL process coal liquefaction 1t/d PSU was opened and checked to investigate the cause of the rise of differential pressure between liquefaction reactors of the PSU. The liquefaction test at a coal concentration of 50 wt% using Tanito Harum coal was conducted, and it was found that the differential pressure between reactors was on the increase. By the two-phase flow pressure loss method, deposition thickness of deposit in pipelines was estimated at 4.4mm at the time of end operation, which agreed with a measuring value obtained from a {gamma} ray. The rise of differential pressure was caused by deposit formation in pipelines connecting reactors. The main component of the deposit is calcite (CaCO3 60-70%) and is the same as the usual one. It is also the same type as the deposit on the reactor wall. Ca in coal ash is concerned with this. To withdraw solid matters deposited in the reactor, there are installed pipelines for the withdrawal at the reactor bottom. The solid matters are regularly purged by reverse gas for prevention of clogging. As the frequency of purge increases, the deposit at the reactor bottom decreases, but the deposit attaches strongly to pipelines connecting reactors. It is presumed that this deposit is what Ca to be discharged out of the system as a form of deposition solid matter naturally in the Ca balance precipitated as calcite in the pipeline connecting the reactor. 3 refs., 5 figs., 4 tabs.

  15. Preparation of ZnNiMo/{gamma}-alumina catalysts from recycled Ni for hydrotreating reactions

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    Linares, Carlos F.; Lopez, Julio [Laboratorio de Catalisis y Metales de Transicion, Facultad de Ciencias y Tecnologia, Departamento de Quimica, Universidad de Carabobo, Valencia Edo Carabobo, Apartado Postal 3336 (Venezuela); Scaffidi, Adriana; Scott, Carlos E. [Centro de Catalisis, Petroleo y Petroquimica, Universidad Central de Venezuela, Facultad de Ciencias, Apartado 47102, Los Chaguaramos, Caracas (Venezuela)

    2005-09-18

    Ni, recovered from Ni-Cd cellular phone batteries, was used in the preparation of ZnNiMo/Al{sub 2}O{sub 3} catalysts. The catalysts were characterized by temperature programmed reductions (TPR), surface area determinations (BET) and chemical analysis. Vanadyl octaethyl porphyrin (VOOEP) hydrodeporphyrinization (HDP) and thiophene hydrodesulfurization (HDS) were used as catalytic tests. It was found that the addition of Zn increases the ratio between octahedral and tetrahedral Mo in ZnMo and ZnNiMo catalysts, and that Ni addition lowers the reduction temperature of Mo species. Both results induce a positive synergetic effect for HDP and HDS reactions. An activity maximum was found for the catalyst with a Zn/(Zn+Ni) atomic ratio equal to 0.29, for both reactions. Finally, the use of a possible pollutant (Ni-Cd batteries) to produce a catalyst to eliminate contaminants in fuels was shown to be feasible.

  16. Characterization of the various catalyst for solvent hydrogenation at 1t/d PSU; 1t/d PSU ni okeru kakushu yozai suisoka shokubai no seino hyoka

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    Kakebayashi, H.; Nogami, Y.; Inokuchi, K. [Mitsui SRC Development Co. Ltd., Tokyo (Japan); Aihara, Y.; Imada, K. [Nippon Steel Corp., Tokyo (Japan)

    1996-10-28

    Performance of various catalysts for hydrogenation of recycle solvent was evaluated for the operation of NEDOL process 1 t/d process supporting unit (PSU). Distillate between 220 and 538{degree}C derived from the liquefaction of Tanito Harum coal was used as recycle solvent. Deactivation behaviors of catalysts were compared using a prediction equation of catalyst life, by which aromatic carbon index (fa) after hydrogenation can be determined from the fa of recycle oil before hydrogenation, reaction temperature, and total hydrogenation time. Total hydrogenation time satisfying the {Delta}fa, 0.05 before and after hydrogenation were 8,000, 4,000, and 2,000 hours for NiMo-based catalysts C, A, and B, respectively. Catalyst C showed the longest life. Used catalysts were also characterized. The catalyst C showed larger mean pore size than those of the others, which resulted in the longer life due to the delay of pore blockage. From measurements by XPS and EPMA, relative atomic concentration of carbon increased remarkably after the use for all of catalysts, which was considered to be due to the adhesion of hydrocarbons. Increase of metal atoms, such as Fe and Cr, was also observed due to the contamination of entrainment residues. Deactivation of catalysts was caused by the adhesion of hydrocarbons, and metallic compounds, such as Fe and Cr. 3 refs., 1 fig., 5 tabs.

  17. Composite Ni/NiO-Cr2O3 Catalyst for Alkaline Hydrogen Evolution Reaction

    Energy Technology Data Exchange (ETDEWEB)

    Bates, MK; Jia, QY; Ramaswamy, N; Allen, RJ; Mukerjee, S

    2015-03-12

    We report a Ni-Cr/C electrocatalyst with unpreeedented massactivity for the hydrogen evolution reaction (HER). in alkaline electrolyte. The HER Oietics of numerous binary and ternary Ni-alloys and composite Ni/metal-euride/C samples were evaluated in aquebus 0.1 M KOH electrolyte. The highest HER mass-activity was observed for Ni-Cr materials which exhibit metallic Ni as well as NiOx and Cr2O3 phases as determined by X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) analysis. The onset of the HER is significantly improved compared to munerous binary dor ternary Ni-alloys, inCluding Ni Mg materials. It is likely that at adjacent Ni/NiOx sites, the oxide acts as a sink for OHads, while the metallic Ni acts as a, sink for the H-ads, intermediate of the HER, thus minimizing the high activation energy of hydrogen evolution via water reduction. This is confirmed by in situ XAS studies that show that the synergistic HER enhancement is due to NiO content and that the Cr2O3 appears to stabilize the composite NiO component-under HER conditions (where NiOx would typically be reduced to metallic Ni-0). Furthermore, in contrast to Pt, the Ni(O-x)/Cr2O3 catalyst appears resistant to poisoning by the anion.exchange ionomer (AEI), a serloua consideration when applied to an anionic polymer electrolyte interface. Furthermore, we report a: detailed model of the double layer interface which helps explain the observed ensemble effect in the presence of AEI.

  18. Solute element distribution and carbide formation in Ni-base superalloys fabricated by rheocasting. Kaiten kakuhan gyokoshita Ni ki chogokin ni okeru yoshitsu genso no bunpu to tankabutsu seisei

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    Okazaki, Y.; Ichikawa, K. (Mechanical Engineering Laboratory, Tsukuba (Japan)); Matsuo, M. (Nippon Steel Corp., Tokyo (Japan))

    1991-07-20

    An attention has begun being given on a method for manufacturing highly ductile metallic materials by means of mechanically stirring the materials in solid-liquid coexisting region and uniformly micronizing the structure. This study discussed effects of the rotation stirring on the microstructures, distribution of solute elements, carbide formation, phosphorous segregation and solid-liquid distribution coefficients in the Ni-base superalloy TMP-3. The results obtained may be summarized as: In the agitated structural material stirred at 70 rev/s in the solid-liquid coexisting region, the dendrite structure was broken up and equiaxed grain structure with the primary solid particle size of 65{plus minus}15{mu}m was formed; the element distribution of Ni, Cr, Co, Al, Ti, Mo, Nb, and W showed no noticeable difference by positions in the structure; the size of{gamma}{prime} phase precipitated on crystal boundaries decreases when cast by rheocasting than when cast stationarily; and the carbides of Nb, Ti and Mo precipitate uniformly along grain boundaries, different from that they precipitate in a plate form in stationary casting. 19 refs., 13 figs., 3 tabs.

  19. Application of new analytical techniques to the order-disorder transformation in Ni-Mo alloys; Ni-Mo gokin no kisoku-fukisoku hentai ni okeru atarashii kozo kaiseki no kokoromi

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    Oki, K.; Hata, S.; Kuwano, N. [Kyushu University, Fukuoka (Japan)

    1997-09-20

    This paper presents the analytical example of the ordering process of order-disorder transformation in Ni-Mo alloy using recent experimental techniques. Monte Carlo simulation clarified the fact that the ordering process in Ni4-Mo alloy is largely affected by short range interaction in the early stage of ordering, and forms D1a, D022 and Pt2Mo structure units with a similar atomic pair correlation. The ordering process is largely affected by long range interaction with an advance of ordering, and develops only D1a structure most stable in energy. In order to check the existence of SRO (short range order) structure obtained by Monte Carlo simulation, the analysis of high-resolution TEM images under SRO condition was carried out using the imaging plate recently developed for TEM. The analytical result showed that the observed N2M3 pattern is derived from not always the existence of N2M3 structure but superimposition of D1a, D022 and Pt2Mo structure units. 19 refs., 4 figs.

  20. Coal conversion rate in 1t/d PSU liquefaction reactor; 1t/d PSU ekika hannoto ni okeru sekitan tenka sokudo no kento

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    Ikeda, K.; Imada, K. [Nippon Steel Corp., Tokyo (Japan); Nogami, Y.; Inokuchi, K. [Mitsui SRC Development Co. Ltd., Tokyo (Japan)

    1996-10-28

    To investigate the coal liquefaction characteristics, coal slurry samples were taken from the outlets of the reactors and slurry preheater of NEDOL process 1 t/d process supporting unit (PSU), and were analyzed. Tanito Harum coal was used for liquefaction, and the slurry was prepared with recycle solvent. Liquefaction was performed using synthetic iron sulfide catalyst at reaction temperatures, 450 and 465{degree}C. Solubility of various solid samples was examined against n-hexane, toluene, and tetrahydrofuran (THF). When considering the decrease of IMO (THF-insoluble and ash) as a characteristic of coal conversion reaction, around 20% at the outlet of the slurry preheater, around 70% within the first reactor, and several percents within the successive second and third reactors were converted against supplied coal. Increase of reaction temperature led to the increase of evaporation of oil fraction, which resulted in the decrease of actual slurry flow rate and in the increase of residence time. Thus, the conversion of coal was accelerated by the synergetic effect of temperature and time. Reaction rate constant of the coal liquefaction was around 2{times}10{sup -1} [min{sup -1}], which increased slightly with increasing the reaction temperature from 450 to 465{degree}C. 3 refs., 5 figs., 1 tab.

  1. Experimental results of acetone hydrogenation on a heat exchanger type reactor for solar chemical heat pump; Solar chemical heat pump ni okeru acetone suisoka hanno netsu kaishu jikken

    Energy Technology Data Exchange (ETDEWEB)

    Takashima, T.; Doi, T.; Tanaka, T.; Ando, Y. [Electrotechnical Laboratory, Tsukuba (Japan); Miyahara, R.; Kamoshida, J. [Shibaura Institute of Technology, Tokyo (Japan)

    1996-10-27

    With the purpose of converting solar heat energy to industrial heat energy, an experiment of acetone hydrogenation was carried out using a heat exchanger type reactor that recovers heat generated by acetone hydrogenation, an exothermic reaction, and supplies it to an outside load. In the experiment, a pellet-like activated carbon-supported ruthenium catalyst was used for the acetone hydrogenation with hydrogen and acetone supplied to the catalyst layer at a space velocity of 400-1,200 or so. In the external pipe of the double-pipe type reactor, a heating medium oil was circulated in parallel with the flow of the reactant, with the heat of reaction recovered that was generated from the acetone hydrogenation. In this experiment, an 1wt%Ru/C catalyst and a 5wt%Ru/C catalyst were used so as to examine the effects of variation in the space velocity. As a result, from the viewpoint of recovering the heat of reaction, it was found desirable to increase the reaction speed by raising catalytic density and also to supply the reactant downstream inside the reaction pipe by increasing the space velocity. 1 ref., 6 figs., 1 tab.

  2. Cyanide formation by the cyanide distillation of nitrate. Zen shian joryuji ni okeru shosan ion ga kanyosuru shian kagobutsu ion no seisei

    Energy Technology Data Exchange (ETDEWEB)

    Ogura, H. (The Chiba Prefectural Lab. of Water Pollution, Chiba (Japan))

    1994-06-10

    Cyanide ion is formed by reacting disodium ethylenediamine-tetra-acetate (EDTA) with a sample containing nitrous ion. Further, it is known that cyanide ions are also generated from the reaction between EDTA and the product of the reaction of oxide and the substance like hydroxyl ammonium chloride which is added to reduce the oxide contained in the sample. In the present researches, the possibility of the formation of cyanide ions from the nitric acid used popularly in the manufactory of plating and surface-treatment is examined. It is expected that if nitric ion takes a part in the formation of cyanide ion, the reaction reducing the nitric ion into nitrous ion would happen as the former step thereof. Therefore, the cyanide distillation of nitric ions co-existing with the reducing agent is carried out, and it is confirmed that cyanide ion is formed with the participation of EDTA. 14 refs., 1 fig., 7 tabs.

  3. Effect of sulfur or hydrogen sulfide on initial stage of coal liquefaction in tetralin; Sekitan ekika shoki katei ni okeru io to ryuka suiso no hatasu yakuwari

    Energy Technology Data Exchange (ETDEWEB)

    Nakada, M. [Government Industrial Research Institute, Kyushu, Saga (Japan)

    1996-10-28

    It is well known that the solubilization of coal can be accelerated by adding sulfur or hydrogen sulfide during direct liquefaction of difficult coals. From the studies of authors on the coal liquefaction under the conditions at rather low temperatures between 300 and 400{degree}C, liquefaction products with high quality can be obtained by suppressing the aromatization of naphthene rings, but it was a problem that the reaction rate is slow. For improving this point, results obtained by changing solvents have been reported. In this study, to accelerate the liquefaction reaction, Illinois No.6 coal was liquefied in tetralin at temperature range from 300 to 400{degree}C by adding a given amount of sulfur or hydrogen sulfide at the initial stage of liquefaction. The addition of sulfur or hydrogen sulfide provided an acceleration effect of liquefaction reaction at temperature range between 300 and 400{degree}C. The addition of sulfur or hydrogen sulfide at 400{degree}C increased the oil products. At 370 and 400{degree}C, the liquid yield by adding sulfur was slightly higher than that by adding hydrogen sulfide, unexpectedly. The effects of sulfur and hydrogen sulfide were reversed when increasing the hydrogen pressure. 5 figs., 1 tab.

  4. Conversion of char nitrogen to N2 under incomplete combustion conditions; Fukanzen nensho jokenka ni okeru char chuchisso no N2 eno tenka

    Energy Technology Data Exchange (ETDEWEB)

    Zhuang, Q.; Yamauchi, A.; Oshima, Y.; Wu, Z.; Otsuka, Y. [Tohoku University, Sendai (Japan). Institute for Chemical Reaction Science

    1996-10-28

    The effect of combustion conditions on conversion of char nitrogen to N2 was studied in the combustion experiment of char obtained by pyrolysis of coal. Char specimen was prepared by holding ZN coal of Chinese lignite in Ar atmosphere at 1123K for one hour. A batch scale quartz-made fluidized bed reactor was used for combustion experiment. After the specimen was fluidized in reaction gas, it was rapidly heated to start combustion reaction. CO, CO2 and N2 in produced gases were online measured by gas chromatography (GC). As the experimental result, under the incomplete combustion condition where a large amount of CO was produced by consuming almost all of O2, no NOx and N2O produced from char were found, and almost all of N-containing gas was N2. At the final stage of combustion, pyridinic-N disappeared completely, and pyrrolic-N decreased, while O-containing nitrogen complexes became a main component. It was thus suggested that O-containing nitrogen complexes are playing the role of intermediate product in combustion reaction. 7 refs., 4 figs., 1 tab.

  5. Interfacial area between gases and liquid in a valve plate column and a bubble cap tray; Barubu danto oyobi hosho danto ni okeru kieki sesshoku menseki

    Energy Technology Data Exchange (ETDEWEB)

    Nakoua, M.; Dribika, M.; Besher, E

    1999-03-05

    A mathematical model has been developed for absorption accompanied by chemical reaction of H{sub 2}S and CO{sub 2} in alkanolamine solutions encountered in plants for natural gas sweetening in Libya. The model has been used to calculate actual number of plates in industrial columns. The model results errors in number of trays predictions due to the lack of procedures for estimating interfacial area for the in between flow regime that prevailed in two industrial plants. The developed correlation for interfacial area estimation for the in between flow regime gives zero error in number of trays prediction. (author)

  6. Numerical simulation of fuel sprays and combustion in a premixed lean diesel engine; Kihaku yokongo diesel kikan ni okeru nenryo funmu to nensho no suchi simulation

    Energy Technology Data Exchange (ETDEWEB)

    Miyamoto, T.; Harada, A.; Sasaki, S.; Shimazaki, N.; Hashizume, T.; Akagawa, H.; Tsujimura, K.

    1997-10-01

    Fuel sprays and combustion in a direct injection Premixed lean Diesel Combustion (PREDIC) engine, which can make smokeless combustion with little NOx emission, is studied numerically. Numerical simulation was carried out by means of KIVA II based computer code with a combustion submodel. The combustion submodel describes the formation of combustible fuel vapor by turbulent mixing and four-step chemical reaction which includes low temperature oxidation. Comparison between computation and experiment shows qualitatively good agreement in terms of heat release rate and NO emission. Computational results indicate that the combustion is significantly influenced by fuel spray characteristics and injection timing to vary NO emission. 10 refs., 8 figs., 1 tab.

  7. Sideward flow of $K^{+}$ mesons in Ru+Ru and Ni+Ni reactions near threshold

    CERN Document Server

    Crochet, Philippe; Wisniewski, K; Leifels, Y; Andronic, A; Averbeck, R; Devismes, A; Finck, C; Gobbi, A; Hartmann, O; Hildenbrand, K D; Koczón, P; Kress, T; Kutsche, R; Reisdorf, W; Schull, D; Alard, J P; Barret, V; Basrak, Z; Bastid, N; Belyaev, I; Bendarag, A; Berek, G; Caplar, R; Cindro, N; Dupieux, P; Dzelalija, M; Eskef, M; Fodor, Z; Grishkin, Yu L; Hong, B; Kecskeméti, J; Kim, Y J; Kirejczyk, M; Korolija, M; Kotte, R; Kowalczyk, M; Lebedev, A; Lee, K S; Man'ko, V I; Merlitz, H; Mohren, S; Moisa, D; Neubert, W; Nyanin, A; Pelte, D; Petrovici, M; Plettner, C; Rami, F; De Schauenburg, B; Seres, Z; Sikora, B; Sim, K S; Simion, V; Siwek-Wilczynska, K; Smolyankin, V T; Somov, A; Stockmeier, M R; Stoicea, G; Vasilev, M A; Wagner, P; Wohlfarth, D; Yang, J T; Yushmanov, I E; Zhilin, A V

    2000-01-01

    Experimental data on K+ meson and proton sideward flow measured with the FOPI detector at SIS/GSI in the reactions Ru+Ru at 1.69 AGeV and Ni+Ni at 1.93 AGeV are presented. The K+ sideward flow is found to be anti-correlated (correlated) with the one of protons at low (high) transverse momenta. When compared to the predictions of a transport model, the data favour the existence of an in-medium repulsive K+ nucleon potential.

  8. Effect of total pressure on sulfur capture of Ca-ion exchanged coal; Kaatsu jokenka ni okeru Ca-tanjitan no datsuryu koka

    Energy Technology Data Exchange (ETDEWEB)

    Lin, S.; Benjamin, G.; Abe, H.; Harano, A.; Takarada, T. [Gunma University, Gunma (Japan). Faculty of Engineering

    1996-10-28

    In relation to coal gasification and combustion under high pressure as highly efficient coal utilization, the effect of total pressure and sintering on the SO2 capture ability of Ca-ion exchanged coal and other desulfurizing agents were studied. In experiment, specimens were filled into a small pressurized reactor to heat them under high-pressure N2 atmosphere. After the completion of combustion reaction of char at 850{degree}C, SO2, CO2 and CO gases were measured at an outlet while flowing SO2/N2. As the experimental result, all of the S content in Ca-ion exchanged coal was not absorbed by Ca content in coal during pyrolysis and combustion, resulting in discharge of 36% of the S content. Since Ca-ion exchanged coal is fast in combustion reaction, most of the S content was desulfurized by coal ash. The ash content yielded from Ca-ion exchanged coal was more excellent in SO2 capture ability than limestone even under higher pressure. In the case of CO2 partial pressure lower than equilibrium CO2 pressure for CaCO3 decomposition, the capture ability decreased with an increase in total pressure, while in higher CO2 partial pressure, it was improved. 1 ref., 7 figs., 2 tabs.

  9. New utilization and recall of carbon dioxide in domestic and foreign countries; Saikin no naigai ni okeru tansan gas no riyo to kaishu

    Energy Technology Data Exchange (ETDEWEB)

    Hanada, M.

    1994-09-01

    This paper summarizes the utilization technologies and recovery of carbon dioxide. Carbon dioxide is manufactured from such inorganic materials as carbonates and cokes, and such organic materials as hydrocarbons and alcohols. Carbon dioxide used in refreshing beverages is manufactured by sulfuric acid decomposition of sodium bicarbonate or limestone, pyrolysis of carbonates, natural gushing, and alcohol fermentation. Sodium carbonate is obtained by using the Solvay process that uses NaCl, NH3 and CaCO3 as the raw materials, but CO2 from hydrocarbons is utilized recently. The sugar industry uses slaked lime and CO2 in cleaning raw sugar concentrates. Grain size, shape, and grain size distribution of the precipitated calcium carbonate light obtained from reaction of slaked lime and CO2 are affected by reaction temperatures and concentrations. This precipitated calcium carbonate light is used in rubber filling, paper manufacturing, and plastics. South Africa and other countries manufacture gypsum for cement by using limestone and sulfuric acid as the raw materials. The annual dispersion of CO2 from fossil fuel consumption amounts to 5.2 billion tons. Discussed as its reducing measures include fixation by sea algae, adsorption, absorption and clathration by zeolite and monoethanol amine. 8 refs., 2 figs., 6 tabs.

  10. Anodic Behavior of Semiconducting Diamond Thin-film Electrodes in the Electrolyte for Electrochemical Fluorination; Handotai daiamondo denkyoku no denkai fussokayokuchu ni okeru youkyoku kyodo

    Energy Technology Data Exchange (ETDEWEB)

    Shibata, Hirotake.; Kawasaki, Shinji. [Shinshu University, Nagano (Japan). Faculty of Textile Science and Technology; Momota, Kunitake. [Morita Chemical Industries, Osaka (Japan). Department of Research and Development; Okino, Fujio.; Touhara, Hidekazu. [Shinshu University, Nagano (Japan). Faculty of Technology]|[Core Research for Evolutional Science and Technology, Tokyo (Japan). Jaoan Science and Technology Corporation; Gamonishitani, Mika.; Sakaguchi, Isao.; Ando, Toshihiro. [National Institute for Research in Inorganic Materials, Ibaraki (Japan)]|[Core Research for Evolutional Science and Technology, Tokyo (Japan). Japan Science and Technology Corporation

    1998-12-31

    Electrochemical behavior of semiconducting diamond thin-film electrodes has been studied by measuring cyclic voltammograms for the anodic oxidation of 1,4-difluorobenzene in the electrolyte, neat Et{sub 4}NF{center_dot}4HF. A comparative study using a Pt-electrode establishes that the electrochemical fluorination of 1,4-difluorobenzene using the diamond electrode yields 3, 3, 6, 6-tetrafluoro-1, 4-cyclohexadiene. Furthermore no peaks corresponding to the redox reaction of Pt-electrode, i.e., the formation and reduction of PtO{sub 2}, are observed in the CVs obtained using the diamond electrode, suggesting that the diamond electrode is more stable than the Pt-electrode. The results suggests that electrochemical fluorination and the electrolytic production of elemental fluorine are possible at the dimensionally stable diamond electrode. (author)

  11. Morphology controlled synthesis of 2-D Ni-Ni3S2 and Ni3S2 nanostructures on Ni foam towards oxygen evolution reaction

    Science.gov (United States)

    Chaudhari, Nitin Kaduba; Oh, Aram; Sa, Young Jin; Jin, Haneul; Baik, Hionsuck; Kim, Sang Gu; Lee, Suk Joong; Joo, Sang Hoon; Lee, Kwangyeol

    2017-03-01

    Catalysts for oxygen evolution reactions (OER) are at the heart of key renewable energy technologies, and development of non-precious metal catalysts with high activity and stability remain a great challenge in this field. Among various material candidates, metal sulfides are receiving increasing attention. While morphology-dependent catalytic performances are well established in noble metal-based catalysts, relatively little is known for the morphology‒catalytic performance relationship in metal sulfide catalysts. In this study, uniform spider web-like Ni nanosheets-Ni3S2 and honeycomb-like Ni3S2 structures are deposited on nickel foam (Ni3S2/NF) by a facile one-step hydrothermal synthetic route. When used as an oxygen evolution electrode, the spider web-like Ni-Ni3S2/NF with the large exposed surface area shown excellent catalytic activity and stability with an overpotential of 310 mV to achieve at 10 mA/cm2 and a Tafel slope of 63 mV/dec in alkaline media, which is superior to the honeycomb-like structure without Ni nanosheet. The low Tafel slope of the spider web-like Ni-Ni3S2/NF represents one of the best OER kinetics among nickel sulfide-based OER catalysts. The results point to the fact that performance of the metal sulfide electrocatalysts might be fine-tuned and optimized with morphological controls.

  12. Formation of N2 in the fixed-bed pyrolysis of low rank coals and the mechanisms; Koteisho netsubunkai ni okeru teitankatan kara no N2 no sisei

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Z.; Otsuka, Y. [Tohoku University, Sendai (Japan). Institute for Chemical Reaction Science

    1996-10-28

    In order to establish coal NOx preventive measures, discussions were given on formation of N2 in the fixed-bed pyrolysis of low rank coals and the mechanisms thereof. Chinese ZN coal and German RB coal were used for the discussions. Both coals do not produce N2 at 600{degree}C, and the main product is volatile nitrogen. Conversion into N2 does not depend on heating rates, but increases linearly with increasing temperature, and reaches 65% to 70% at 1200{degree}C. In contrast, char nitrogen decreases linearly with the temperature. More specifically, these phenomena suggest that the char nitrogen or its precursor is the major supply source of N2. When mineral substances are removed by using hydrochloric acid, their catalytic action is lost, and conversion into N2 decreases remarkably. Iron existing in ion-exchanged condition in low-rank coal is reduced and finely diffused into metallic iron particles. The particles react with heterocyclic nitrogen compounds and turn into iron nitride. A solid phase reaction mechanism may be conceived, in which N2 is produced due to decomposition of the iron nitride. 5 refs., 4 figs., 1 tab.

  13. Research activities at thermo-fluid engineering laboratories in Takushoku University; Takushoku Daigaku kogakubu kikai system kogakuka ni okeru ryutai kogaku oyobi netsukogaku kankei no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Fujimoto, I.; Hori, M.; Matsunaga, N. [Takushoku University, Tokyo (Japan)

    1999-01-20

    This paper introduces general conditions of studies at the Machine System Engineering Department of the Faculty of Engineering at the Takushoku University. Studies related to transonic cascade flutters in fluid engineering include behavioral analysis of impact waves around vibrating blades. Behavior of impact waves making twisting vibration at high vibration frequency is elucidated by means of schlieren photography. In addition, the single blade vibration method is used to analyze aerodynamic decay properties of cascades. Elucidation is made on non-steady stalling properties of vibrating single blades (particularly, the hysteresis phenomenon of stalling elevation angles with restoring elevation angles). In the field of thermal engineering, studies are being made on effects of unburned components on NO-NO{sub 2} conversion using a fluidity reactor. Similar reactions are being studied by means of chemical dynamics calculations using the CHEMKIN-II/SENKIN program. A coaxial jet flow experimenting equipment is used to study NO{sub 2} generating mechanism in the field closer to real combustors. Data are accumulated to verify numerical computation by experiments and measurements of spraying flames produced by a model spray combustor. Measurements and experiments are also performed on absorption of NO{sub 2} into water, and on coefficient of diffusion between two kinds of gases. (NEDO)

  14. Synthesis and characterizations of Ni-NiO nanoparticles on PDDA-modified graphene for oxygen reduction reaction.

    Science.gov (United States)

    Yung, Tung-Yuan; Huang, Li-Ying; Chan, Tzu-Yi; Wang, Kuan-Syun; Liu, Ting-Yu; Chen, Po-Tuan; Chao, Chi-Yang; Liu, Ling-Kang

    2014-01-01

    We are presenting our recent research results about the Ni-NiO nanoparticles on poly-(diallyldimethylammonium chloride)-modified graphene sheet (Ni-NiO/PDDA-G) nanocomposites prepared by the hydrothermal method at 90°C for 24 h. The Ni-NiO nanoparticles on PDDA-modified graphene sheets are measured by transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), and selected area electron diffraction (SAED) pattern for exploring the structural evidence to apply in the electrochemical catalysts. The size of Ni-NiO nanoparticles is around 5 nm based on TEM observations. The X-ray diffraction (XRD) results show the Ni in the (012), (110), (110), (200), and (220) crystalline orientations, respectively. Moreover, the crystalline peaks of NiO are found in (111) and (220). The thermal gravimetric analysis (TGA) result represents the loading content of the Ni metal which is about 34.82 wt%. The electron spectroscopy for chemical analysis/X-ray photoelectron spectroscopy (ESCA/XPS) reveals the Ni(0) to Ni(II) ratio in metal phase. The electrochemical studies with Ni-NiO/PDDA-G in 0.5 M aqueous H2SO4 were studied for oxygen reduction reaction (ORR).

  15. Synthesis and characterizations of Ni-NiO nanoparticles on PDDA-modified graphene for oxygen reduction reaction

    Science.gov (United States)

    Yung, Tung-Yuan; Huang, Li-Ying; Chan, Tzu-Yi; Wang, Kuan-Syun; Liu, Ting-Yu; Chen, Po-Tuan; Chao, Chi-Yang; Liu, Ling-Kang

    2014-08-01

    We are presenting our recent research results about the Ni-NiO nanoparticles on poly-(diallyldimethylammonium chloride)-modified graphene sheet (Ni-NiO/PDDA-G) nanocomposites prepared by the hydrothermal method at 90°C for 24 h. The Ni-NiO nanoparticles on PDDA-modified graphene sheets are measured by transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), and selected area electron diffraction (SAED) pattern for exploring the structural evidence to apply in the electrochemical catalysts. The size of Ni-NiO nanoparticles is around 5 nm based on TEM observations. The X-ray diffraction (XRD) results show the Ni in the (012), (110), (110), (200), and (220) crystalline orientations, respectively. Moreover, the crystalline peaks of NiO are found in (111) and (220). The thermal gravimetric analysis (TGA) result represents the loading content of the Ni metal which is about 34.82 wt%. The electron spectroscopy for chemical analysis/X-ray photoelectron spectroscopy (ESCA/XPS) reveals the Ni0 to NiII ratio in metal phase. The electrochemical studies with Ni-NiO/PDDA-G in 0.5 M aqueous H2SO4 were studied for oxygen reduction reaction (ORR).

  16. Ni+ reactions with aminoacetonitrile, a potential prebiological precursor of glycine

    CERN Document Server

    Lamsabhi, Al Mokhtar; Yáñez, Manuel; Guillemin, Jean-Claude; Haldys, Violette; Tortajada, Jeanine; Salpin, Jean-Yves

    2008-01-01

    The gas-phase reactions between Ni+ (2D5/2) and aminoacetonitrile, a molecule of prebiological interest as possible precursor of glycine, have been investigated by means of mass spectrometry techniques. The mass-analyzed ion kinetic energy (MIKE) spectrum reveals that the adduct ions [NCCH2NH2, Ni+] spontaneously decompose by loosing HCN, H2, and H2CNH, the loss of hydrogen cyanide being clearly dominant. The structures and bonding characteristics of the aminoacetonitrile-Ni+ complexes as well as the different stationary points of the corresponding potential energy surface (PES) have been theoretically studied by density functional theory (DFT) calculations carried out at B3LYP/6-311G(d,p) level. A cyclic intermediate, in which Ni+ is bisligated to the cyano and the amino group, plays an important role in the unimolecular reactivity of these ions, because it is the precursor for the observed losses of HCN and H2CNH. In all mechanisms associated with the loss of H2, the metal acts as hydrogen carrier favoring ...

  17. Probing the semi-magicity of $^{68}$Ni via the $^{3}$H($^{66}$Ni,$^{68}$Ni)p two-neutron transfer reaction in inverse kinematics

    CERN Multimedia

    Reiter, P; Blazhev, A A; Kruecken, R; Franchoo, S; Mertzimekis, T; Darby, I G; Van de walle, J; Raabe, R; Elseviers, J; Gernhaeuser, R A; Sorlin, O H; Georgiev, G P; Bree, N C F; Habs, D; Chapman, R; Gaudefroy, L; Diriken, J V J; Jenkins, D G; Kroell, T; Axiotis, M; Huyse, M L; Patronis, N

    We propose to perform the two-neutron transfer reaction $^{3}$H($^{66}$Ni, $^{68}$Ni)$p$ using the ISOLDE radioactive ion beam at 2.7 $A$ MeV and the MINIBALL + T-REX setup to characterize the 0$^{+}$ and 2$^{+}$ states in $^{68}$Ni.

  18. Reaction mechanisms and staggering in S+Ni collisions

    Energy Technology Data Exchange (ETDEWEB)

    D' Agostino, M., E-mail: dagostino@bo.infn.it [Dipartimento di Fisica dell' Universita and INFN, Bologna (Italy); Bruno, M. [Dipartimento di Fisica dell' Universita and INFN, Bologna (Italy); Gulminelli, F. [LPC (IN2P3-CNRS/Ensicaen et Universite), F-14076 Caen cedex (France); Morelli, L. [Dipartimento di Fisica dell' Universita and INFN, Bologna (Italy); Baiocco, G. [Dipartimento di Fisica dell' Universita and INFN, Bologna (Italy); LPC (IN2P3-CNRS/Ensicaen et Universite), F-14076 Caen cedex (France); Bardelli, L. [INFN, Firenze (Italy); INFN, Catania (Italy); Barlini, S. [INFN, Firenze (Italy); Cannata, F. [Dipartimento di Fisica dell' Universita and INFN, Bologna (Italy); Casini, G. [INFN, Firenze (Italy); Geraci, E. [Dipartimento di Fisica dell' Universita, Catania (Italy); INFN, Catania (Italy); Gramegna, F.; Kravchuk, V.L. [INFN, Laboratori Nazionali di Legnaro (Italy); Marchi, T. [INFN, Laboratori Nazionali di Legnaro (Italy); Dipartimento di Fisica dell' Universita, Padova (Italy); Moroni, A. [INFN, Milano (Italy); Ordine, A. [INFN, Napoli (Italy); Raduta, Ad.R. [NIPNE, Bucharest-Magurele, POB-MG6 (Romania)

    2011-07-01

    The reactions {sup 32}S+{sup 58}Ni and {sup 32}S+{sup 64}Ni are studied at 14.5 A MeV. After a selection of the collision mechanism, we show that important even-odd effects are present in the isotopic fragment distributions when the excitation energy is small. Close to the multifragmentation threshold this staggering appears hidden by the rapid variation of the production yields with the fragment size. Once this effect is accounted for, the staggering appears to be a universal feature of fragment production, slightly enhanced when the emission source is neutron poor. A closer look at the behavior of the production yields as a function of the neutron excess N-Z, reveals that odd-even effects cannot be explained by pairing effects in the nuclear masses alone, but depend in a more complex way on the de-excitation chain.

  19. Reaction mechanisms and staggering in S+Ni collisions

    Science.gov (United States)

    D'Agostino, M.; Bruno, M.; Gulminelli, F.; Morelli, L.; Baiocco, G.; Bardelli, L.; Barlini, S.; Cannata, F.; Casini, G.; Geraci, E.; Gramegna, F.; Kravchuk, V. L.; Marchi, T.; Moroni, A.; Ordine, A.; Raduta, Ad. R.

    2011-07-01

    The reactions S32+Ni58 and S32+Ni64 are studied at 14.5 A MeV. After a selection of the collision mechanism, we show that important even-odd effects are present in the isotopic fragment distributions when the excitation energy is small. Close to the multifragmentation threshold this staggering appears hidden by the rapid variation of the production yields with the fragment size. Once this effect is accounted for, the staggering appears to be a universal feature of fragment production, slightly enhanced when the emission source is neutron poor. A closer look at the behavior of the production yields as a function of the neutron excess N-Z, reveals that odd-even effects cannot be explained by pairing effects in the nuclear masses alone, but depend in a more complex way on the de-excitation chain.

  20. Hydrogen evolution reaction measurements of dealloyed porous NiCu

    Science.gov (United States)

    Koboski, Kyla R.; Nelsen, Evan F.; Hampton, Jennifer R.

    2013-12-01

    Porous metals are of interest for their high surface area and potential for enhanced catalytic behavior. Electrodeposited NiCu thin films with a range of compositions were electrochemically dealloyed to selectively remove the Cu component. The film structure, composition, and reactivity of these samples were characterized both before and after the dealloying step using scanning electron microscopy, energy-dispersive spectroscopy, and electrochemical measurements. The catalytic behavior of the dealloyed porous Ni samples towards the hydrogen evolution reaction was measured and compared to that of the as-deposited samples. The dealloyed samples were generally more reactive than their as-deposited counterparts at low overpotentials, making the dealloying procedure a promising area of exploration for improved hydrogen evolution catalysts.

  1. Exploring dissipative processes at high angular momentum in 58Ni+60Ni reactions

    Directory of Open Access Journals (Sweden)

    Williams E.

    2016-01-01

    Full Text Available Current coupled channels (CC models treat fusion as a coherent quantum-mechanical process, in which coupling between the collective states of the colliding nuclei influences the probability of fusion in near-barrier reactions. While CC models have been used to successfully describe many experimental fusion barrier distribution (BD measurements, the CC approach has failed in the notable case of 16O+208Pb. The reason for this is poorly understood; however, it has been postulated that dissipative processes may play a role. Traditional BD experiments can only probe the physics of fusion for collisions at the top of the Coulomb barrier (L = 0ħ. In this work, we will present results using a novel method of probing dissipative processes inside the Coulomb barrier. The method exploits the predicted sharp onset of fission at L ~ 60ħ for reactions forming compound nuclei with A < 160. Using the ANU’s 14UD tandem accelerator and CUBE spectrometer, reaction outcomes have been measured for the 58Ni+60Ni reaction at a range of energies, in order to explore dissipative processes at high angular momentum. In this reaction, deep inelastic processes have been found to set in before the onset fission at high angular momentum following fusion. The results will be discussed in relation to the need for a dynamical model of fusion.

  2. Ni elemental neutron induced reaction cross-section evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Divadeenam, M.

    1979-03-01

    A completely new evaluation of the nickel neutron induced reaction cross sections was undertaken as a part of the ENDF/B-V effort. (n,xy) reactions and capture reaction time from threshold to 20 MeV were considered for /sup 58/ /sup 60/ /sup 61/ /sup 62/ /sup 64/Ni isotopes to construct the corresponding reaction cross section for natural nickel. Both experimental and theoretical calculated results were used in evaluating different partial cross sections. Precompound effects were included in calculating (n,xy) reaction cross sections. Experimentally measured total section data extending from 0.7 MeV to 20 MeV were used to generate smooth cross section. Below 0.7 to MeV elastic and capture cross sections are represented by resonance parameters. Inelastic angular distributions to the discrete isotopic levels and elemental elastic angular distributions are included in the evaluated data file. Gamma production cross sections and energy distribution due to capture and the (n,xy) reactions were evaluated from experimental data. Finally, error files are constructed for all partial cross sections.

  3. Density Functional Study on the Reaction Mechanism for the Reaction of Ni+ with Ethane

    Institute of Scientific and Technical Information of China (English)

    ZHANG,Dong-Ju(张冬菊); LIU,Cheng-Bu(刘成卜); LIU,Yong-Jun(刘永军); HU,Hai-Quan(胡海泉)

    2002-01-01

    The mechanism of the reaction of Ni+ (2D) with ethane in the gas-phase was studied by using density functional theory. Both the B3LYP and BLYP functionals with standard all-electron basis sets are used to give the detailed information of the potential energy surface (PES) of [Ni, C2, H6 ] +. Tne mechanisms forming the products CH4 and H2 in the reaction of Ni+with ethane are proposed. The reductive eliminations of CH4and H2 are typical addition-elimination reactions. Each of the two reactions consists of two elementary steps: C-C or CH bond activations to form inserted species followed by isomerizations to form product-like intermediate. The rate determining steps for the elimination reatcions of forming CH4 and H2 are the isomerizations of the inserted species rather than C-C or C-H bond activations. The elimination reaction of forming H2 was found to be thermodynamically favored compared to that of CH4.

  4. Experimental study of the $^{66}$Ni$(d,p)^{67}$Ni one-neutron transfer reaction

    CERN Document Server

    Diriken, J.; Andreyev, A.N.; Antalic, S.; Bildstein, V.; Blazhev, A.; Darby, I.G.; De Witte, H.; Eberth, J.; Elseviers, J.; Fedosseev, V.N.; Flavigny, F.; Fransen, Ch.; Georgiev, G.; Gernhauser, R.; Hess, H.; Huyse, M.; Jolie, J.; Kröll, Th.; Krücken, R.; Lutter, R.; Marsh, B.A.; Mertzimekis, T.; Muecher, D.; Orlandi, R.; Pakou, A.; Raabe, R.; Randisi, G.; Reiter, P.; Roger, T.; Seidlitz, M.; Seliverstov, M.; Sotty, C.; Tornqvist, H.; Van De Walle, J.; Van Duppen, P.; Voulot, D.; Warr, N.; Wenander, F.; Wimmer, K.

    2015-01-01

    The quasi-SU(3) sequence of the positive parity $νg_{9/2}, d_{5/2}, s_{1/2}$ orbitals above the N=40 shell gap are assumed to induce strong quadrupole collectivity in the neutron-rich Fe (Z=26) and Cr (Z=24) isotopes below the nickel region. In this paper the position and strength of these single-particle orbitals are characterized in the neighborhood of $^{68}$Ni (Z=28,N=40) through the $^{66}$Ni($d,p$)$^{67}$Ni one-neutron transfer reaction at 2.95 MeV/nucleon in inverse kinematics, performed at the REX-ISOLDE facility in CERN. A combination of the Miniball $\\gamma$-array and T-REX particle-detection setup was used and a delayed coincidence technique was employed to investigate the 13.3-$\\mu$s isomer at 1007 keV in $^{67}$Ni. Excited states up to an excitation energy of 5.8 MeV have been populated. Feeding of the $νg_{9/2}$ (1007 keV) and $νd_{5/2}$ (2207 keV and 3277 keV) positive-parity neutron states and negative parity ($νpf$) states have been observed at low excitation energy. The extracted relativ...

  5. Reaction dynamics studies for the system 7Be+58Ni

    Science.gov (United States)

    Torresi, D.; Mazzocco, M.; Acosta, L.; Boiano, A.; Boiano, C.; Diaz-Torres, A.; Fierro, N.; Glodariu, T.; Grilj, L.; Guglielmetti, A.; Keeley, N.; La Commara, M.; Martel, I.; Mazzocchi, C.; Molini, P.; Pakou, A.; Parascandolo, C.; Parkar, V. V.; Patronis, N.; Pierroutsakou, D.; Romoli, M.; Rusek, K.; Sanchez-Benitez, A. M.; Sandoli, M.; Signorini, C.; Silvestri, R.; Soramel, F.; Stiliaris, E.; Strano, E.; Stroe, L.; Zerva, K.

    2015-04-01

    The study of reactions induced by exotic weakly bound nuclei at energies around the Coulomb barrier had attracted a large interest in the last decade, since the features of these nuclei can deeply affect the reaction dynamics. The discrimination between different reaction mechanisms is, in general, a rather difficult task. It can be achieved by using detector arrays covering high solid angle and with high granularity that allow to measure the reaction products and, possibly, coincidences between them, as, for example, recently done for stable weakly bound nuclei [1, 2]. We investigated the collision of the weakly bound nucleus 7Be on a 58Ni target at the beam energy of 1.1 times the Coulomb barrier, measuring the elastic scattering angular distribution and the energy and angular distributions of 3He and 4He. The 7Be radioactive ion beam was produced by the facility EXOTIC at INFN-LNL with an energy of 22 MeV and an intensity of ~3×105 pps. Results showed that the 4He yeld is about 4 times larger than 3He yield, suggesting that reaction mechanisms other than the break-up mostly produce the He isotopes. Theoretical calculations for transfer channels and compound nucleus reactions suggest that complete fusion accounts for (41±5%) of the total reaction cross section extracted from optical model analysis of the elastic scattering data, and that 3He and 4He stripping are the most populated reaction channels among direct processes. Eventually estimation of incomplete fusion contributions to the 3,4He production cross sections was performed through semi-classical calculations with the code PLATYPUS [3].

  6. Reverse water gas shift reaction over Co-precipitated Ni-CeO2 catalysts

    Institute of Scientific and Technical Information of China (English)

    WANG Luhui; ZHANG Shaoxing; LIU Yuan

    2008-01-01

    The Ni-CeO2 catalysts with different Ni contents were prepared by a co-precipitation method and used for Reverse Water Gas Shift (RWGS) reaction. 2wt.%Ni-CeO2 showed excellent catalytic performance in terms of activity, selectivity, and stability for RWGS reaction. Characterizations of the catalyst samples were conducted by XRD and TPR. The results indicated that, in Ni-CeO2 catalysts, there were three kinds of nickel, nickel ions in ceria lattice, highly dispersed NiO and bulk NiO. Oxygen vacancies were formed in CeO2 lattice due to the incorporation of Ni2+ ions into ceria lattice. Oxygen vacancies formed in ceda lattice and highly dispersed Ni were key active components for RWGS, and bulk Ni was key active component for methanation of CO2.

  7. Study of the 66Ni(t,d)67Ni Transfer Reaction in Inverse Kinematics

    CERN Document Server

    Callens, Maarten

    The nickel isotopes with 28 protons are an interesting series in the study of nuclear structure. In the framework of the shell model nickel has a closed proton shell and the number of neutrons ranges from the magic numbers 20 to 50. The neutron-rich isotope $^{78}$Ni, is a waiting point in the nucleosynthesis r-process. In this process an intense neutron flux such as in supernovae results in the rapid capture of neutrons. The reaction sequence halts at $^{78}$Ni and waits for this nucleus to decay [Hea05]. For several decades the nickel isotopes have been studied extensively, particularly how the nuclear structure evolves when moving to the exotic boundaries of the nuclear chart. A remarkable feature was observed in $^{68}$Ni. This nucleus with 40 neutrons exhibits properties that are characteristic for doubly magic nuclei. Such as the energy of the first 2$^+$ state lies significantly higher than in neighbouring even-A isotopes, and is also higher than the energy of the second 0$^+$ state. Moreover also the ...

  8. Fe/Ni-N-CNFs electrochemical catalyst for oxygen reduction reaction/oxygen evolution reaction in alkaline media

    Science.gov (United States)

    Wang, Zhuang; Li, Mian; Fan, Liquan; Han, Jianan; Xiong, Yueping

    2017-04-01

    The novel of iron, nickel and nitrogen doped carbon nanofibers (Fe/Ni-N-CNFs) as bifunctional electrocatalysts are prepared by electrospinning technique. In alkaline media, the Fe/Ni-N-CNFs catalysts (especially for Fe1Ni1-N-CNFs) exhibit remarkable electrocatalytic performances of oxygen reduction reaction (ORR)/oxygen evolution reaction (OER). For ORR catalytic activity, Fe1Ni1-N-CNFs catalyst offers a higher onset potential of 0.903 V, a similar four-electron reaction pathway, and excellent stability. For OER catalytic activity, Fe1Ni1-N-CNFs catalyst possesses a lower onset potential of 1.528 V and a smaller charge transfer resistance of 48.14 Ω. The unparalleled catalytic activity of ORR and OER for the Fe1Ni1-N-CNFs is attributed to the 3D porous cross-linked microstructures of carbon nanofibers with Fe/Ni alloy, N dopant, and abundant M-Nx and NiOOH as catalytic active sites. Thus, Fe1Ni1-N-CNFs catalyst can be acted as one of the efficient and inexpensive catalysts of metal-air batteries.

  9. Interfacial Reactions in the Ni/Sn- xZn/Cu Sandwich Couples

    Science.gov (United States)

    Yen, Yee-Wen; Lin, Chung-Yung; Lai, Mei-Ting; Chen, Wan-Ching

    2016-01-01

    The interfacial reactions in Ni/Sn- xZn/Cu sandwich couples which were reflowed at 270°C for 1 h and then aged at 160°C for 1-1000 h were investigated. When the 1000- μm-thick Sn-Zn alloy reacted with Ni and Cu in this couple, the results indicated that the (Ni, Cu)3Sn4, (Ni, Cu)5Zn21, and Ni5Zn21 phases were formed at Sn-1Zn/Ni, Sn-5Zn/Ni, and Sn-9Zn/Ni interfaces for 1 h reflowing, respectively. After 1000 h aging, each intermetallic compound (IMC) was converted to (Cu, Ni, Zn)6Sn5, (Ni, Cu, Sn)5Zn21/Ni5Zn21, and Ni5Zn21 (two layers) phases in the related couples. On the Cu side, the Cu6Sn5 phase in the Sn-1Zn/Cu interface and the Cu5Zn8 phase in the Sn-5Zn/Cu and Sn-9Zn/Cu interfaces were observed when the couple was reflowed at 270°C for 1 h. After 100 h aging, the (Cu, Ni, Zn)6Sn5, Cu5Zn8/(Cu, Zn)6Sn5, and Cu5Zn8 phases were formed at the Sn-1Zn/Cu, Sn-5Zn/Cu and Sn-9Zn/Cu interfaces. When the Sn-Zn alloy thickness was decreased to 500 μm, the (Cu, Ni, Zn)6Sn5 phase at the Sn-1Zn/Ni interface and the (Ni, Cu, Sn)5Zn21 phase at the Sn-5Zn/Ni and Sn-9Zn/Ni interfaces were observed after 1 h reflowing. When the couple was aged at 160°C for 1000 h, each IMC was converted to (Cu, Ni, Zn)6Sn5 and Cu5Zn8/(Cu, Ni, Sn)Zn/Ni5Zn21 phases at the Sn-1Zn/Ni and Sn-(5, 9)Zn/Ni interfaces. (Cu, Ni, Zn)6Sn5 and Cu5Zn8 were, respectively, formed at the Sn-1Zn/Cu and Sn-(5, 9)Zn/Cu interfaces for 1 h reflowing. After 100 h aging, the IMCs were converted to (Cu, Ni, Zn)6Sn5 and Cu5Zn8/(Cu, Zn)6Sn5 phases. This current study reveals that the IMC formation in Ni/(Sn- xZn)/Cu sandwich couples are very sensitive to the Zn concentration and thickness in Sn- xZn alloys.

  10. Quantum analysis in the transition process to excited state of an oxygen molecule induced by electron collisions; Denshi shototsu ni tomonau sanso bunshi ni okeru reiki jotai sen`i no ryoshironteki kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Ishimaru, K. [Gifu National College of Technology, Gifu (Japan); Okazaki, K. [Tokyo Inst. of Technology, Tokyo (Japan)

    1996-06-25

    For understanding of fundamental chemical reactions under a highly non equilibrium condition which is quite often used in plasma processing, the relevant atomic and molecular processes must be clarified. In this study, an analysis of the transition process to the excited state of an oxygen molecule induced by electron collisions in the oxygen plasma has been carried out. First, the electron density distribution in an oxygen molecule has been calculated using the extended Huckel molecular orbital method. Then, the electron potential energy distribution in the transition process to the excited state has been estimated. The electron behavior has been calculated using the estimated unidimensional electron potential energy distribution and unsteady quantum mechanics. As a result, the transition process to the excited state of an oxygen molecule induced by electron collisions and its conditions have been clarified qualitatively. 9 refs., 9 figs.

  11. Synthesis Mechanism and Strengthening Effects of Laminated NiAl by Reaction Annealing

    Science.gov (United States)

    Du, Yan; Fan, Guohua; Wang, Qingwei; Geng, Lin

    2017-01-01

    N iA l with a laminated microstructure has been fabricated by reaction annealing of Ni-Al system at 1473 K (1200 °C). The laminated NiAl shows heterogeneity of chemical gradient and bimodal grain size distribution. The objective of this study is to investigate the synthesis mechanism and the strengthening effect of this laminated NiAl, therefore to promote further application of NiAl as a high-temperature structural material. Heat treatments at 1473 K (1200 °C) and subsequent characterization were utilized to study the synthesis mechanism. It shows that in original Al regions NiAl nuclei precipitate from Al(Ni) liquid phase and form fine-grained NiAl layers, whereas in original Ni regions NiAl nuclei precipitate from Ni(Al) saturated solution through diffusion and form coarse-grained NiAl layers. Moreover, heterogeneity of chemical gradient is generated through diffusion during annealing. The mechanical properties of laminated NiAl have also been studied via nanoindentation method. It shows that both chemical gradient and bimodal grain size distribution could strengthen the laminated NiAl.

  12. Effects of Cr and Ni on Interdiffusion and Reaction between U and Fe-Cr-Ni Alloys

    Energy Technology Data Exchange (ETDEWEB)

    K. Huang; Y. Park; L. Zhou; K.R. Coffey; Y.H. Sohn; B.H. Sencer; J. R. Kennedy

    2014-08-01

    Metallic U-alloy fuel cladded in steel has been examined for high temperature fast reactor technology wherein the fuel cladding chemical interaction is a challenge that requires a fundamental and quantitative understanding. In order to study the fundamental diffusional interactions between U with Fe and the alloying effect of Cr and Ni, solid-to-solid diffusion couples were assembled between pure U and Fe, Fe–15 wt.%Cr or Fe–15 wt.%Cr–15 wt.%Ni alloy, and annealed at high temperature ranging from 580 to 700 °C. The microstructures and concentration profiles that developed from the diffusion anneal were examined by scanning electron microscopy, and X-ray energy dispersive spectroscopy (XEDS), respectively. Thick U6Fe and thin UFe2 phases were observed to develop with solubilities: up to 2.5 at.% Ni in U6(Fe,Ni), up to 20 at.%Cr in U(Fe, Cr)2, and up to 7 at.%Cr and 14 at.% Ni in U(Fe, Cr, Ni)2. The interdiffusion and reactions in the U vs. Fe and U vs. Fe–Cr–Ni exhibited a similar temperature dependence, while the U vs. Fe–Cr diffusion couples, without the presence of Ni, yielded greater activation energy for the growth of intermetallic phases – lower growth rate at lower temperature but higher growth rate at higher temperature.

  13. Effects of Cr and Ni on interdiffusion and reaction between U and Fe–Cr–Ni alloys

    Energy Technology Data Exchange (ETDEWEB)

    Huang, K.; Park, Y.; Zhou, L.; Coffey, K.R. [Advanced Materials Processing and Analysis Center, Department of Materials Science and Engineering, University of Central Florida, Orlando, FL (United States); Sohn, Y.H., E-mail: Yongho.Sohn@ucf.edu [Advanced Materials Processing and Analysis Center, Department of Materials Science and Engineering, University of Central Florida, Orlando, FL (United States); Sencer, B.H.; Kennedy, J.R. [Fundamental Fuel Properties Department, Nuclear Fuel and Materials Division Idaho National Laboratory, Idaho Falls, ID (United States)

    2014-08-01

    Metallic U-alloy fuel cladded in steel has been examined for high temperature fast reactor technology wherein the fuel cladding chemical interaction is a challenge that requires a fundamental and quantitative understanding. In order to study the fundamental diffusional interactions between U with Fe and the alloying effect of Cr and Ni, solid-to-solid diffusion couples were assembled between pure U and Fe, Fe–15 wt.%Cr or Fe–15 wt.%Cr–15 wt.%Ni alloy, and annealed at high temperature ranging from 580 to 700 °C. The microstructures and concentration profiles that developed from the diffusion anneal were examined by scanning electron microscopy, and X-ray energy dispersive spectroscopy (XEDS), respectively. Thick U{sub 6}Fe and thin UFe{sub 2} phases were observed to develop with solubilities: up to 2.5 at.% Ni in U{sub 6}(Fe,Ni), up to 20 at.%Cr in U(Fe, Cr){sub 2}, and up to 7 at.%Cr and 14 at.% Ni in U(Fe, Cr, Ni){sub 2}. The interdiffusion and reactions in the U vs. Fe and U vs. Fe–Cr–Ni exhibited a similar temperature dependence, while the U vs. Fe–Cr diffusion couples, without the presence of Ni, yielded greater activation energy for the growth of intermetallic phases – lower growth rate at lower temperature but higher growth rate at higher temperature.

  14. Effects of Cr and Ni on interdiffusion and reaction between U and Fe-Cr-Ni alloys

    Science.gov (United States)

    Huang, K.; Park, Y.; Zhou, L.; Coffey, K. R.; Sohn, Y. H.; Sencer, B. H.; Kennedy, J. R.

    2014-08-01

    Metallic U-alloy fuel cladded in steel has been examined for high temperature fast reactor technology wherein the fuel cladding chemical interaction is a challenge that requires a fundamental and quantitative understanding. In order to study the fundamental diffusional interactions between U with Fe and the alloying effect of Cr and Ni, solid-to-solid diffusion couples were assembled between pure U and Fe, Fe-15 wt.%Cr or Fe-15 wt.%Cr-15 wt.%Ni alloy, and annealed at high temperature ranging from 580 to 700 °C. The microstructures and concentration profiles that developed from the diffusion anneal were examined by scanning electron microscopy, and X-ray energy dispersive spectroscopy (XEDS), respectively. Thick U6Fe and thin UFe2 phases were observed to develop with solubilities: up to 2.5 at.% Ni in U6(Fe,Ni), up to 20 at.%Cr in U(Fe, Cr)2, and up to 7 at.%Cr and 14 at.% Ni in U(Fe, Cr, Ni)2. The interdiffusion and reactions in the U vs. Fe and U vs. Fe-Cr-Ni exhibited a similar temperature dependence, while the U vs. Fe-Cr diffusion couples, without the presence of Ni, yielded greater activation energy for the growth of intermetallic phases - lower growth rate at lower temperature but higher growth rate at higher temperature.

  15. Reactions in Electrodeposited Cu/Sn and Cu/Ni/Sn Nanoscale Multilayers for Interconnects

    Directory of Open Access Journals (Sweden)

    Pay Ying Chia

    2016-05-01

    Full Text Available Miniaturization of electronic devices has led to the development of 3D IC packages which require ultra-small-scale interconnections. Such small interconnects can be completely converted into Cu-Sn based intermetallic compounds (IMCs after reflow. In an effort to improve IMC based interconnects, an attempt is made to add Ni to Cu-Sn-based IMCs. Multilayer interconnects consisting of stacks of Cu/Sn/Cu/Sn/Cu or Cu/Ni/Sn/Ni/Sn/Cu/Ni/Sn/Ni/Cu with Ni = 35 nm, 70 nm, and 150 nm were electrodeposited sequentially using copper pyrophosphate, tin methanesulfonic, and nickel Watts baths, respectively. These multilayer interconnects were investigated under room temperature aging conditions and for solid-liquid reactions, where the samples were subjected to 250 °C reflow for 60 s and also 300 °C for 3600 s. The progress of the reaction in the multilayers was monitored by using X-ray Diffraction, Scanning Electron Microscope, and Energy dispersive X-ray Spectroscopy. FIB-milled samples were also prepared for investigation under room temperature aging conditions. Results show that by inserting a 70 nanometres thick Ni layer between copper and tin, premature reaction between Cu and Sn at room temperature can be avoided. During short reflow, the addition of Ni suppresses formation of Cu3Sn IMC. With increasing Ni thickness, Cu consumption is decreased and Ni starts acting as a barrier layer. On the other hand, during long reflow, two types of IMC were found in the Cu/Ni/Sn samples which are the (Cu,Ni6Sn5 and (Cu,Ni3Sn, respectively. Details of the reaction sequence and mechanisms are discussed.

  16. Effect of Electromigration on Interfacial Reaction in Ni/Sn/Ni-P Solder Joint%电迁移对Ni/Sn/Ni-P焊点界面反应的影响

    Institute of Scientific and Technical Information of China (English)

    陈雷达; 周少明; 黄明亮

    2012-01-01

    The line-type Ni/Sn/Ni-P(Au) solder joints were used to determine the effect of electromigration (EM) on interfacial reaction under the current density of 5.0×103 A/cm2 at 150 ℃. For comparison, the Ni/Sn/Ni-P(Au) interconnects were aged at the same temperature for the same duration. The results show that the current direction plays an important rule on Ni-P layer consumption. When electrons flowed from Ni-P side to Ni side (Ni-P layer was the cathode), EM accelerated the Ni-P layer consumption. More Ni-P layer was consumed with increasing EM time. After EM for 100 h and 200 h, 5.88 μm and 13.46 urn Ni-P layer were consumed, respectively. Instead of Ni3Sn4, Ni2SnP IMC layer was observed at the Sn/Ni-P interface, and there was a porous Ni3P layer between Ni2SnP IMC and Ni-P. When electrons flowed from Ni side to Ni-P side (Ni-P layer was the anode), no obvious Ni-P layer consumption was observed during EM, and Ni3Sn4 IMC formed at the Sn/Ni-P interface. The thickness of the Ni3Sn4 IMC increased slowly with increasing EM time and reached to 1.81 μm after EM for 200 h.%研究了温度为150℃,电流密度为5.0×103A/cm2的条件下电迁移对Ni/Sn/Ni-P(Au)线性接头中界面反应的影响.结果表明电流方向对Ni-P层的消耗起着决定作用.当Ni-P层为阴极时,电迁移加速了Ni-P层的消耗,即随着电迁移时间的延长,Ni-P层的消耗显著增加;电迁移100 h后Ni-P层消耗了5.88 μm,电迁移200 h后Ni-P层消耗了13.46μm.在Sn/Ni-P的界面上形成了一层Ni2SnP化合物而没有观察到Ni3Sn4化合物的存在,多孔状的Ni3P层位于Ni2SnP化合物与Ni-P层之间.当Ni-P层为阳极时,在电迁移过程中并没有发现Ni-P层的明显消耗,在Sn/Ni-P的界面处生成层状的Ni3Sn4化合物,其厚度随着电迁移时间的延长而缓慢增加,电迁移200 h后Ni3Sn4层的厚度达到1.81 μm.

  17. Effects of Ga Addition on Interfacial Reactions Between Sn-Based Solders and Ni

    Science.gov (United States)

    Wang, Chao-Hong; Li, Kuan-Ting

    2016-07-01

    The use of Ga as a micro-alloying element in Sn-based solders can change the microstructure of solder joints to improve the mechanical properties, and even suppress the interfacial intermetallic compound (IMC) growth. This research investigated the effects of Ga addition (0.2-1 wt.%Ga) on the IMC formation and morphological evolution in the Sn-based solder joints with Ni substrate. In the soldering reaction at 250°C and with less than 0.2 wt.%Ga addition, the formed phase was Ni3Sn4. When the Ga addition increased to 0.5 wt.%, it changed to a thin Ni2Ga3 layer of ˜1 μm thick, which stably existed at the interface in the initial 1-h reaction. Subsequently, the whole Ni2Ga3 layer detached from the Ni substrate and drifted into the molten solder. The Ni3Sn4 phase became dominant in the later stage. Notably, the Ga addition significantly reduced the grain size of Ni3Sn4, resulting in the massive spalling of Ni3Sn4 grains. With 1 wt.%Ga addition, the Ni2Ga3 layer remained very thin with no significant growth, and it stably existed at the interface for more than 10 h. In addition, the solid-state reactions were examined at temperatures of 160°C to 200°C. With addition of 0.5 wt.%Ga, the Ni3Sn4 phase dominated the whole reaction. By contrast, with increasing to 1 wt.%Ga, only a thin Ni2Ga3 layer was found even after aging at 160°C for more than 1200 h. The 1 wt.%Ga addition in solder can effectively inhibit the Ni3Sn4 formation in soldering and the long-term aging process.

  18. Effects of Ga Addition on Interfacial Reactions Between Sn-Based Solders and Ni

    Science.gov (United States)

    Wang, Chao-Hong; Li, Kuan-Ting

    2016-12-01

    The use of Ga as a micro-alloying element in Sn-based solders can change the microstructure of solder joints to improve the mechanical properties, and even suppress the interfacial intermetallic compound (IMC) growth. This research investigated the effects of Ga addition (0.2-1 wt.%Ga) on the IMC formation and morphological evolution in the Sn-based solder joints with Ni substrate. In the soldering reaction at 250°C and with less than 0.2 wt.%Ga addition, the formed phase was Ni3Sn4. When the Ga addition increased to 0.5 wt.%, it changed to a thin Ni2Ga3 layer of ˜1 μm thick, which stably existed at the interface in the initial 1-h reaction. Subsequently, the whole Ni2Ga3 layer detached from the Ni substrate and drifted into the molten solder. The Ni3Sn4 phase became dominant in the later stage. Notably, the Ga addition significantly reduced the grain size of Ni3Sn4, resulting in the massive spalling of Ni3Sn4 grains. With 1 wt.%Ga addition, the Ni2Ga3 layer remained very thin with no significant growth, and it stably existed at the interface for more than 10 h. In addition, the solid-state reactions were examined at temperatures of 160°C to 200°C. With addition of 0.5 wt.%Ga, the Ni3Sn4 phase dominated the whole reaction. By contrast, with increasing to 1 wt.%Ga, only a thin Ni2Ga3 layer was found even after aging at 160°C for more than 1200 h. The 1 wt.%Ga addition in solder can effectively inhibit the Ni3Sn4 formation in soldering and the long-term aging process.

  19. Neutron spectroscopic factors of 55Ni hole-states from (p,d transfer reactions

    Directory of Open Access Journals (Sweden)

    A. Sanetullaev

    2014-09-01

    Full Text Available Spectroscopic information has been extracted on the hole-states of 55Ni, the least known of the quartet of nuclei (55Ni, 57Ni, 55Co and 57Cu, one nucleon away from 56Ni, the N=Z=28 double magic nucleus. Using the H1(Ni56,dNi55 transfer reaction in inverse kinematics, neutron spectroscopic factors, spins and parities have been extracted for the f7/2, p3/2 and the s1/2 hole-states of 55Ni. These new data provide a benchmark for large basis calculations that include nucleonic orbits in both the sd and pf shells. State of the art calculations have been performed to describe the excitation energies and spectroscopic factors of the s1/2 hole-state below Fermi energy.

  20. Neutron spectroscopic factors of {sup 55}Ni hole-states from (p,d) transfer reactions

    Energy Technology Data Exchange (ETDEWEB)

    Sanetullaev, A. [National Superconducting Cyclotron Laboratory and Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States); Tsang, M.B., E-mail: tsang@nscl.msu.edu [National Superconducting Cyclotron Laboratory and Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States); Lynch, W.G.; Lee, Jenny; Bazin, D. [National Superconducting Cyclotron Laboratory and Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States); Chan, K.P. [National Superconducting Cyclotron Laboratory and Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States); Physics Department, Hong Kong Chinese University, Shatin, Hong Kong (China); Coupland, D.; Henzl, V.; Henzlova, D.; Kilburn, M.; Rogers, A.M. [National Superconducting Cyclotron Laboratory and Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States); Sun, Z.Y. [National Superconducting Cyclotron Laboratory and Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States); Institute of Modern Physics, CAS, Lanzhou 730000 (China); Youngs, M. [National Superconducting Cyclotron Laboratory and Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States); Charity, R.J.; Sobotka, L.G. [Department of Chemistry, Washington University, St. Louis, MO 63130 (United States); Famiano, M. [Department of Physics, Western Michigan University, Kalamazoo, MI 49008 (United States); Hudan, S. [Department of Chemistry, Indiana University, Bloomington, IN 47405 (United States); Shapira, D. [Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Peters, W.A. [Rutgers University, Piscataway, NJ 08854 (United States); Barbieri, C. [Department of Physics, University of Surrey, Guildford GU2 7XH (United Kingdom); and others

    2014-09-07

    Spectroscopic information has been extracted on the hole-states of {sup 55}Ni, the least known of the quartet of nuclei ({sup 55}Ni, {sup 57}Ni, {sup 55}Co and {sup 57}Cu), one nucleon away from {sup 56}Ni, the N=Z=28 double magic nucleus. Using the {sup 1}H({sup 56}Ni,d){sup 55}Ni transfer reaction in inverse kinematics, neutron spectroscopic factors, spins and parities have been extracted for the f{sub 7/2}, p{sub 3/2} and the s{sub 1/2} hole-states of {sup 55}Ni. These new data provide a benchmark for large basis calculations that include nucleonic orbits in both the sd and pf shells. State of the art calculations have been performed to describe the excitation energies and spectroscopic factors of the s{sub 1/2} hole-state below Fermi energy.

  1. Neutron spectroscopic factors of $^{55}$Ni hole-states from (p,d) transfer reactions

    CERN Document Server

    Sanetullaev, A; Lynch, W G; Lee, Jenny; Bazin, D; Chan, K P; Coupland, D; Henzl, V; Henzlova, D; Kilburn, M; Rogers, A M; Sun, Z Y; Youngs, M; Charity, R J; Sobotka, L G; Famiano, M; Hudan, S; Shapira, D; Peters, W A; Barbieri, C; Hjorth-Jensen, M; Horoi, M; Otsuka, T; Suzuki, T; Utsuno, Y

    2014-01-01

    Spectroscopic information has been extracted on the hole-states of $^{55}$Ni, the least known of the quartet of nuclei ($^{55}$Ni, $^{57}$Ni, $^{55}$Co and $^{57}$Co), one neutron away from $^{56}$Ni, the N=Z=28 double magic nucleus. Using the $^{1}$H($^{56}$Ni,d)$^{55}$Ni transfer reaction in inverse kinematics, neutron spectroscopic factors, spins and parities have been extracted for the f$_{7/2}$, p$_{3/2}$ and the s$_{1/2}$ hole-states of $^{55}$Ni. This new data provides a benchmark for large basis calculations that include nucleonic orbits in both the sd and pf shells. State of the art calculations have been performed to describe the excitation energies and spectroscopic factors of the s$_{1/2}$ hole-state below Fermi energy.

  2. Neutron spectroscopic factors of 55Ni hole-states from (p,d) transfer reactions

    Science.gov (United States)

    Sanetullaev, A.; Tsang, M. B.; Lynch, W. G.; Lee, Jenny; Bazin, D.; Chan, K. P.; Coupland, D.; Henzl, V.; Henzlova, D.; Kilburn, M.; Rogers, A. M.; Sun, Z. Y.; Youngs, M.; Charity, R. J.; Sobotka, L. G.; Famiano, M.; Hudan, S.; Shapira, D.; Peters, W. A.; Barbieri, C.; Hjorth-Jensen, M.; Horoi, M.; Otsuka, T.; Suzuki, T.; Utsuno, Y.

    2014-09-01

    Spectroscopic information has been extracted on the hole-states of 55Ni, the least known of the quartet of nuclei (55Ni, 57Ni, 55Co and 57Cu), one nucleon away from 56Ni, the N=Z=28 double magic nucleus. Using the H1(Ni56,d)Ni55 transfer reaction in inverse kinematics, neutron spectroscopic factors, spins and parities have been extracted for the f7/2, p3/2 and the s1/2 hole-states of 55Ni. These new data provide a benchmark for large basis calculations that include nucleonic orbits in both the sd and pf shells. State of the art calculations have been performed to describe the excitation energies and spectroscopic factors of the s1/2 hole-state below Fermi energy.

  3. Effect of low and high heating rates on reaction path of Ni(V)/Al multilayer

    Energy Technology Data Exchange (ETDEWEB)

    Maj, Łukasz, E-mail: l.maj@imim.pl [Institute of Metallurgy and Materials Science, Polish Academy of Sciences, 25 Reymonta St., 30-059 Kraków (Poland); Morgiel, Jerzy; Szlezynger, Maciej [Institute of Metallurgy and Materials Science, Polish Academy of Sciences, 25 Reymonta St., 30-059 Kraków (Poland); Bała, Piotr; Cios, Grzegorz [AGH University of Science and Technology, Academic Centre for Materials and Nanotechnology, 30 Kawiory St., 30-055 Kraków (Poland)

    2017-06-01

    The effect of heating rates of Ni(V)/Al NanoFoils{sup ®} was investigated with transmission electron microscopy (TEM). The Ni(V)/Al were subjected to heating by using differential scanning calorimetry (DSC), in-situ TEM or electric pulse. Local chemical analysis was carried out using energy dispersive X-ray spectroscopy (EDS). Phase analysis was done with X-ray diffractions (XRD) and selected area electron diffractions (SAED). The experiments showed that slow heating in DSC results in development of separate exothermic effects at ∼230 °C, ∼280 °C and ∼390 °C, corresponding to precipitation of Al{sub 3}Ni, Al{sub 3}Ni{sub 2} and NiAl phases, respectively, i.e. like in vanadium free Ni/Al multilayers. Further heating to 700 °C allowed to obtain a single phase NiAl foil. The average grain size (g.s.) of NiAl phase produced in the DSC heat treated foil was comparable with the Ni(V)/Al multilayer period (∼50 nm), whereas in the case of reaction initiated with electric pulse the g.s. was in the micrometer range. Upon slow heating vanadium tends to segregate to zones parallel to the original multilayer internal interfaces, while in SHS process vanadium-rich phases precipitates at grain boundaries of the NiAl phase. - Highlights: • Peaks in DSC heating of Ni(V)/Al were explained by in-situ TEM observations. • Nucleation of Al{sub 3}Ni, Al{sub 3}Ni{sub 2} and NiAl at slow heating of Ni(V)/Al was documented. • Near surface NiAl obtained from NanoFoil show Ag precipitates at grain boundaries.

  4. Coupled-channels description of the 40Ca+58,64Ni transfer and fusion reactions

    CERN Document Server

    Scamps, G; Hagino, K; Haas, F; Courtin, S

    2016-01-01

    Preliminary experimental data for nucleon transfer reactions of the 40Ca+58Ni and 40Ca+64Ni systems are analyzed with the coupled- channels approach. It is shown that a simple treatment for the transfer in the coupled-channels method cannot reproduce simultaneously the transfer probabilities and the sub-barrier enhancement of fusion cross sections.

  5. Microstructural evolution of NiFe2O4-10NiO powder prepared by high temperature solid state reaction

    Institute of Scientific and Technical Information of China (English)

    ZHANG Lei; ZHOU Ke-chao; LI Zhi-you; YANG Wen-jie

    2006-01-01

    The NiFe2O4-10NiO powder for inert anode of aluminium electrolysis was prepared by high temperature solid state reaction. The microstructural evolution from the raw materials NiO and Fe2O3 to the NiFe2O4-10NiO powder was studied by SEM. The results show that the domain structure making up of the agglomerate particles of Fe2O3 remains after high temperature solid state reaction, and the diffusion of Ni2+ into Fe2O3 structure is the control step of the reaction process. A microstructure with compact structure and fine grain inside the particle results from the sintering of NiFe2O4-10NiO powder.

  6. Shaped Ir-Ni bimetallic nanoparticles for minimizing Ir utilization in oxygen evolution reaction.

    Science.gov (United States)

    Lim, Jinkyu; Yang, Sungeun; Kim, Chanyeon; Roh, Chi-Woo; Kwon, Yongwoo; Kim, Yong-Tae; Lee, Hyunjoo

    2016-04-25

    Shaped Ir-Ni bimetallic nanoparticles were synthesized and used for electrocatalytic oxygen evolution reaction (OER). The obtained bimetallic nanoparticles showed significantly enhanced Ir mass activity and durability compared with Ir nanoparticles.

  7. Interfacial reactions between solid Ni and liquid Sn-Zn alloys

    Directory of Open Access Journals (Sweden)

    Gandova V.

    2015-01-01

    Full Text Available The limitation of the harmful lead-containing solders used in the electronics and other industry applications change lead with another metals. Interfacial reactions between Sn-Zn alloys and Ni substrate after annealing at 400 and 450°C were studied. Three intermetallic compounds Ni3Sn4, T1, γ-Ni5Zn21 and liquid Sn were observed in the Ni/Sn-Zn diffusion couples. Scanning electron microscope was used for the investigation of the microstructure. The microhardness measurement of the intermetallic layers was also performed.

  8. The effect of urea on microstructures of Ni3S2 on nickel foam and its hydrogen evolution reaction

    Science.gov (United States)

    Jinlong, Lv; Tongxiang, Liang

    2016-11-01

    The effects of urea concentration on microstructures of Ni3S2formed on nickel foam and its hydrogen evolution reaction were investigated. The Ni3S2 nanosheets with porous structure were formed on nickel foam during hydrothermal process due to low urea concentration. While high urea concentration facilitated the forming of Ni3S2 nanotube arrays. The resulting Ni3S2 nanotube arrays exhibited higher catalytic activity than Ni3S2nanosheets for hydrogen evolution reaction. This was mainly attributed to a fact that Ni3S2 nanotube arrays facilitated diffusion of electrolyte for hydrogen evolution reaction.

  9. Study of shell evolution in the Ni isotopes via one-neutron transfer reaction in $^{70}$Ni

    CERN Multimedia

    This proposal aims at the study of the single particle properties of the neutron-rich nickel isotopes, specifically of the $^{71}$Ni isotope via a $^{70}$Ni(d,p) $^{71}$Ni reaction. The $^{70}$Ni beam will be delivered by HIE-ISOLDE at 5.5 MeV/u onto a 1.0 mg/cm$^{2}$ CD$_{2}$ target. The protons produced in the (d,p) reaction will be detected with the T-REX silicon array either in singles or in coincidence with $\\gamma$- rays recorded by MINIBALL. The experimental results will be compared with large-scale shell-model calculations using effective interactions that involve large valence spaces for protons and neutrons, with excitations beyond the Z =28 and N=50 shell gap. This comparison will permit the study of the single-particle orbital d$_{5/2}$ that together with the quasi-SU3 partner g$_{9/2}$ gives rise to the collectivity in this region and has direct implications on the $^{78}$Ni.

  10. Embedding the Ni-SOD mimetic Ni-NCC within a polypeptide sequence alters the specificity of the reaction pathway.

    Science.gov (United States)

    Krause, Mary E; Glass, Amanda M; Jackson, Timothy A; Laurence, Jennifer S

    2013-01-07

    The unique metal abstracting peptide asparagine-cysteine-cysteine (NCC) binds nickel in a square planar 2N:2S geometry and acts as a mimic of the enzyme nickel superoxide dismutase (Ni-SOD). The Ni-NCC tripeptide complex undergoes rapid, site-specific chiral inversion to dld-NCC in the presence of oxygen. Superoxide scavenging activity increases proportionally with the degree of chiral inversion. Characterization of the NCC sequence within longer peptides with absorption, circular dichroism (CD), and magnetic CD (MCD) spectroscopies and mass spectrometry (MS) shows that the geometry of metal coordination is maintained, though the electronic properties of the complex are varied to a small extent because of bis-amide, rather than amine/amide, coordination. In addition, both Ni-tripeptide and Ni-pentapeptide complexes have charges of -2. This study demonstrates that the chiral inversion chemistry does not occur when NCC is embedded in a longer polypeptide sequence. Nonetheless, the superoxide scavenging reactivity of the embedded Ni-NCC module is similar to that of the chirally inverted tripeptide complex, which is consistent with a minor change in the reduction potential for the Ni-pentapeptide complex. Together, this suggests that the charge of the complex could affect the SOD activity as much as a change in the primary coordination sphere. In Ni-NCC and other Ni-SOD mimics, changes in chirality, superoxide scavenging activity, and oxidation of the peptide itself all depend on the presence of dioxygen or its reduced derivatives (e.g., superoxide), and the extent to which each of these distinct reactions occurs is ruled by electronic and steric effects that emenate from the organization of ligands around the metal center.

  11. In vitro bioactivity and osteoblast response of porous NiTi synthesized by SHS using nanocrystalline Ni-Ti reaction agent.

    Science.gov (United States)

    Gu, Y W; Li, H; Tay, B Y; Lim, C S; Yong, M S; Khor, K A

    2006-08-01

    Porous NiTi with an average porosity of 55 vol % and a general pore size of 100-600 microm was synthesized by self-propagating high temperature synthesis (SHS) with the addition of mechanically alloyed nanocrystalline Ni-Ti as the reaction agent. The SHS of porous NiTi using elemental powders was also performed for comparison. To enhance the bioactivity of the metal surface, porous NiTi synthesized by nanocrystalline Ni-Ti was subjected to chemical treatment to form a layer of TiO(2) coating. The porous NiTi with TiO(2) coating was subsequently immersed in a simulated body fluid (SBF) to investigate its apatite forming ability. The effects of the addition of nanocrystalline Ni-Ti as reaction agent and the application of apatite coating on osteoblastic behavior were studied in primary cultures of human osteoblast cells. Results showed that the main phases in porous NiTi synthesized by elemental powders were NiTi, Ti(2)Ni, and unreacted free Ni. By using nanocrystalline Ni-Ti as reaction agent, the secondary intermetallic phase of Ti(2)Ni was significantly reduced and the free Ni was eliminated. TiO(2) coating with anatase phase was formed on the surface of porous NiTi after the chemical treatment. A layer consisting of nanocrystalline carbonate-containing apatite was formed on the surface of TiO(2) coating after soaking in SBF. The preliminary cell culture studies showed that the porous NiTi synthesized with the addition of nanocrystalline Ni-Ti attracted marked attachment and proliferation of the osteoblast cells. This gives the evidence of the potential biomedical applications of the porous NiTi.

  12. Influences of reaction conditions on methane decomposition over non-supported Ni catalyst

    Institute of Scientific and Technical Information of China (English)

    Wei Zhang; Qingjie Ge; Hengyong Xu

    2011-01-01

    Effects of reaction temperature and methane gas hourly space velocity (GHSV) on methane decomposition over non-supported Ni catalyst havebeen investigated in this work.Methane molecules activation,Ni particles growth and nano-carbon diffusion were the main factors influencing methane decomposition stability of non-supported Ni.The results of methane decomposition activity test on the non-supported Ni catalyst showed that the prepared non-supported Ni could exhibit a good methane decomposition performance with 273 gC/gNi and 2667 molH2/molNi at 500 ℃ and 45000 mL/(gcat·h).Scanning electron microscope (SEM),X-ray powder diffraction (XRD) and temperature-programmed oxidation (TPO) have been carried out to characterize the used catalysts.The deposited carbon was carbon nanofibers,among which graphitic carbon formation increased with the reaction time of methane decomposition.Ni particle size was not the decisive factor during the carbon growing stage.

  13. A Self-Propagating Foaming Process of Porous Al-Ni Intermetallics Assisted by Combustion Reactions

    Directory of Open Access Journals (Sweden)

    Makoto Kobashi

    2009-12-01

    Full Text Available The self-propagating foaming process of porous Al-Ni intermetallics was investigated. Aluminum and nickel powders were blended, and titanium and boron carbide powders were added as reactive exothermic agents. The blended powder was extruded to make a rod-shape precursor. Only one end of the rod precursor was heated to ignite the reaction. The reaction propagated spontaneously throughout the precursor. Pore formation took place at the same time as the reaction occurred. Adding the exothermic agent was effective to increase the porosity. Preheating the precursor before the ignition was also very effective to produce porous Al-Ni intermetallics with high porosity.

  14. Experimental determination of proton induced reaction cross sections on {sup nat}Ni near threshold energy

    Energy Technology Data Exchange (ETDEWEB)

    Uddin, Md. Shuza [Atomic Energy Research Establishment, Dhaka (Bangladesh). Tandem Accelerator Facilities; Forschungszentrum Juelich GmbH (Germany). Inst. fuer Neurowissenschaften und Medizin, INM-5: Nuklearchemie; Chakraborty, Animesh Kumer [Atomic Energy Research Establishment, Dhaka (Bangladesh). Tandem Accelerator Facilities; Chittagong University of Engineering and Technology (Bangladesh). Dept. of Physics; Spellerberg, Stefan; Spahn, Ingo; Qaim, Syed M. [Forschungszentrum Juelich GmbH (Germany). Inst. fuer Neurowissenschaften und Medizin, INM-5: Nuklearchemie; Shariff, Md. Asad; Das, Sopan [Atomic Energy Research Establishment, Dhaka (Bangladesh). Tandem Accelerator Facilities; Rashid, Md. Abdur [Chittagong University of Engineering and Technology (Bangladesh). Dept. of Physics

    2016-08-01

    A newly developed facility at the 3 MV Tandem Accelerator at Dhaka for measurement of proton induced reaction cross sections in the energy region below 5 MeV is outlined and tests for the beam characterization are described. The results were validated by comparison with the well-known excitation function of the {sup 64}Ni(p, n){sup 64}Cu reaction. Excitation functions of the reactions {sup nat}Ni(p, x){sup 60,61}Cu, {sup nat}Ni(p, x){sup 55,57,58m+g}Co and {sup nat}Ni(p, x){sup 57}Ni were also measured from threshold to 16 MeV using the stacked-foil technique, whereby irradiations were performed with 5 MeV protons available at the Tandem Accelerator and 16.7 MeV protons at the BC 1710 cyclotron at Juelich, Germany. The radioactivity was measured using HPGe γ-ray detectors. A few results are new, the others strengthen the database. In particular, the results of the reaction {sup nat}Ni(p, x){sup 61}Cu below 3 MeV could serve as beam monitor.

  15. Effect of Ni Loading and Reaction Conditions on Partial Oxidation of Methane to Syngas

    Institute of Scientific and Technical Information of China (English)

    Haitao Wang; Zhenhua Li; Shuxun Tian

    2003-01-01

    The partial oxidation of methane to synthesis gas is studied in this paper over Ni/Al2O3 catalysts under atmospheric pressure. The effects of Ni loading on the activity and stability of catalysts with 5 mm α-Al2O3 and θ-Al2O3 pellets as supports were measured in a continuous fixed bed reactor. It is found that the optimum Ni loading is 10%. And the effect of reaction conditions on partial oxidation of methane is also studied. The methane conversion and CO selectivity increase with the increase of the reaction temperature and the space velocity on 10%Ni/α-Al2O3 catalysts. The best CH4/O2 mole ratio is 2 for CO selectivity, and the optimum space velocity is 5.4×105 h-1.

  16. Hollow mesoporous NiCo2O4 nanocages as efficient electrocatalysts for oxygen evolution reaction.

    Science.gov (United States)

    Lv, Xiaoming; Zhu, Yihua; Jiang, Hongliang; Yang, Xiaoling; Liu, Yanyan; Su, Yunhe; Huang, Jianfei; Yao, Yifan; Li, Chunzhong

    2015-03-07

    The design and fabrication of efficient and inexpensive electrodes for oxygen evolution reaction (OER) is essential for energy-conversion technologies. Herein, high OER activity is achieved using hollow mesoporous NiCo2O4 nanocages synthesized via a Cu2O-templated strategy combined with coordination reaction. The NiCo2O4 nanostructures with a hollow cavity, large roughness and high porosity show only a small overpotential of ∼0.34 V at the current density of 10 mA cm(-2) and a Tafel slope of 75 mV per decade, which is comparable with the performance of the best reported transition metal oxide based OER catalysts in the literature. Meanwhile, the positive impacts of the nanocage structure and the Ni incorporation on the electrocatalytic performance are also demonstrated by comparing the OER activities of NiCo2O4 nanocages with Co3O4 nanocages, NiCo2O4 nanoparticles and 20 wt% Pt/C. Moreover, the NiCo2O4 nanocages also manifest superior stability to other materials. All these merits indicate that the hollow mesoporous NiCo2O4 nanocages are promising electrocatalysts for water oxidation.

  17. Effect of defects on reaction of NiO surface with Pb-contained solution

    Science.gov (United States)

    Kim, Jongjin; Hou, Binyang; Park, Changyong; Bahn, Chi Bum; Hoffman, Jason; Black, Jennifer; Bhattacharya, Anand; Balke, Nina; Hong, Hawoong; Kim, Ji Hyun; Hong, Seungbum

    2017-01-01

    In order to understand the role of defects in chemical reactions, we used two types of samples, which are molecular beam epitaxy (MBE) grown NiO(001) film on Mg(001) substrate as the defect free NiO prototype and NiO grown on Ni(110) single crystal as the one with defects. In-situ observations for oxide-liquid interfacial structure and surface morphology were performed for both samples in water and Pb-contained solution using high-resolution X-ray reflectivity and atomic force microscopy. For the MBE grown NiO, no significant changes were detected in the high-resolution X-ray reflectivity data with monotonic increase in roughness. Meanwhile, in the case of native grown NiO on Ni(110), significant changes in both the morphology and atomistic structure at the interface were observed when immersed in water and Pb-contained solution. Our results provide simple and direct experimental evidence of the role of the defects in chemical reaction of oxide surfaces with both water and Pb-contained solution. PMID:28317881

  18. One nucleon transfer reactions around $^{68}$Ni at REX-ISOLDE

    CERN Multimedia

    Blazhev, A A; Kruecken, R; Mertzimekis, T; Darby, I G; Lagogiannis, A; Habs, D; Diriken, J V J; Patronis, N

    2008-01-01

    We intend to investigate the single particle properties of the neutron-rich Ni isotopes in the mass region around $^{68}$Ni and at a later stage towards the doubly-magic $^{78}$Ni. As a first experiment we propose to study the single particle character of the ground and first excited states of $^{67}$Ni. This nucleus will be the projectile-like reaction product for the one-neutron transfer reaction. A $^{66}$Ni beam at 3A MeV delivered from REX-ISOLDE will be directed on a CD$_{2}$ target. Protons produced from the (d,p) reaction will be detected either in singles or in coincidence with ${\\gamma}$-rays recorded by the MINIBALL array. The particles will be detected by the newly-built Si position-sensitive barrel configuration. The objectives of this work are the unambiguous determination of the spins and parities of the first excited states of $^{67}$Ni and measurement of the relative spectroscopic factors of those states as well as of the ground state. The experimental results will be compared with those from...

  19. Preparation and Oxygen Evolution Reaction Performance of Ni/NiCo2O4 Electrode%Ni/NiCo2O4电极的制备及其析氧反应性能

    Institute of Scientific and Technical Information of China (English)

    王森林; 王丽品; 张振洪

    2013-01-01

      采用溶胶-凝胶法制备NiCo2O4尖晶石粉体,然后以多孔Ni为基体,通过复合溶胶涂覆结合烧结制备Ni/NiCo2O4涂层电极.运用扫描电子显微镜(SEM)、能量色散谱(EDS)和X射线衍射(XRD)表征粉体以及Ni/NiCo2O4涂层电极的组成和结构.采用循环伏安(CV),稳态极化(LSV),电化学阻抗谱(EIS),恒电位阶跃以及恒电位长时间电解研究涂层电极在5 mol·L-1 KOH溶液中的电催化析氧反应(OER).结果表明:Ni/NiCo2O4涂层电极与多孔Ni电极对比,具有低的析氧过电位、高的比表面积和高的稳定性能;其中比表面积增大了28.69倍,表观活化能在不同过电位分别降低了166.78和162.15 kJ·mol-1.%Spinel-type NiCo2O4 powders were prepared by a sol-gel method, and Ni/NiCo2O4 electrode was prepared through composite sol method combined with sintering. The composition and structure of Ni/NiCo2O4 were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy-dispersive X-ray spectroscopy (EDS). Electrocatalytic properties of the Ni/NiCo2O4 electrode in the oxygen evolution reaction (OER) were studied in 5 mol·L-1 KOH solution, using cyclic voltammertry (CV), linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS), chronoamperometry, and extended duration constant potential electrolysis. The Ni/NiCo2O4 electrode exhibited a lower OER over-potential, higher specific surface area, and better stability than a porous Ni electrode. The specific surface area of the Ni/NiCo2O4 electrode was 28.69 times greater than that of the porous Ni electrode, and its apparent activation energies decrease 166.78 and 162.15 kJ·mol-1 at different overpotentials, respectively.

  20. Solid Phase Reactions of Ni-GaAs Alloys for High Mobility Ⅲ-Ⅴ MOSFET Applications

    Institute of Scientific and Technical Information of China (English)

    LU Li; CHANG Hu-Dong; SUN Bing; WANG Hong; XUE Bai-Qing; ZHAO We; LIU Hong-Gang

    2012-01-01

    The solid phase reactions of Ni with GaAs substrates are investigated.The experimental results reveal that the Ni-GaAs solid phase reaction forms a ternary phase of Ni2GaAs when annealing temperatures are in the range 250 300℃.As the annealing temperature increases to 400℃,the Ni2GaAs phase starts to decompose due to NiAs phase precipitation.Ni-GaAs alloys processed at 400℃ with a 3min annealing time demonstrate a sheet resistance of 30Ω/square after unreacted Ni removal in hot diluted-HCl solutions.Therefore,Ni-GaAs alloys formed by solid phase reaction could be promising metallic source/drain structures with significant low series resistance for high mobility Ⅲ-Ⅴ metal-oxide-semiconductor field effect transistor (MOSFET) applications.%The solid phase reactions of Ni with GaAs substrates are investigated. The experimental results reveal that the Ni-GaAs solid phase reaction forms a ternary phase of Ni2GaAs when annealing temperatures are in the range 250-300℃. As the annealing temperature increases to 400℃, the Ni2GaAs phase starts to decompose due to NiAs phase precipitation. Ni-GaAs alloys processed at 400℃ with a 3 min annealing time demonstrate a sheet resistance of 30Ω/square after unreacted Ni removal in hot diluted-HCl solutions. Therefore, Ni-GaAs alloys formed by solid phase reaction could be promising metallic source/drain structures with significant low series resistance for high mobility III-V metal-oxide-semiconductor field effect transistor (MOSFET) applications.

  1. Enhancement of the Hydrogen Evolution Reaction from Ni-MoS2 Hybrid Nanoclusters

    Science.gov (United States)

    2016-01-01

    This report focuses on a novel strategy for the preparation of transition metal–MoS2 hybrid nanoclusters based on a one-step, dual-target magnetron sputtering, and gas condensation process demonstrated for Ni-MoS2. Aberration-corrected STEM images coupled with EDX analysis confirms the presence of Ni and MoS2 in the hybrid nanoclusters (average diameter = 5.0 nm, Mo:S ratio = 1:1.8 ± 0.1). The Ni-MoS2 nanoclusters display a 100 mV shift in the hydrogen evolution reaction (HER) onset potential and an almost 3-fold increase in exchange current density compared with the undoped MoS2 nanoclusters, the latter effect in agreement with reported DFT calculations. This activity is only reached after air exposure of the Ni-MoS2 hybrid nanoclusters, suggested by XPS measurements to originate from a Ni dopant atoms oxidation state conversion from metallic to 2+ characteristic of the NiO species active to the HER. Anodic stripping voltammetry (ASV) experiments on the Ni-MoS2 hybrid nanoclusters confirm the presence of Ni-doped edge sites and reveal distinctive electrochemical features associated with both doped Mo-edge and doped S-edge sites which correlate with both their thermodynamic stability and relative abundance.

  2. A fascinating combination of Co, Ni and Al nanomaterial for oxygen evolution reaction

    Science.gov (United States)

    Khan, Sher Bahadar; Khan, Shahid Ali; Asiri, Abdullah M.

    2016-05-01

    Interesting combination of Co, Ni and Al have been assessed for oxygen evolution reaction (OER). Layered double hydroxide (LDH) nanosheets of NiCoAl, Co-Al oxide nanoparticles and Co-Ni oxide nanoparticles were prepared and studied for the first time as OER catalyst. Among all the subjected catalysts, the binary LDH comprise of NiCoAl showed comparatively high catalytic activity than Co-Al oxide nanoparticles and Co-Ni oxide nanoparticles. The Co-Al and Co-Ni oxide nanoparticles showed current densities of 34.6 and 24.5 mA cm-2, respectively at 1 V in 0.3 M KOH solution. However at the same conditions, NiCoAl-LDH showed comparatively low overpotential, high current density (40.8 mA cm-2) and lower Tafel slope. The low overpotential and high catalytic activity of NiCoAl-LDH stipulate the possibility to reduce the demand of precious, rare earth and expensive transition metal catalyst in electrochemical water splitting for OER.

  3. A fascinating combination of Co, Ni and Al nanomaterial for oxygen evolution reaction

    Energy Technology Data Exchange (ETDEWEB)

    Khan, Sher Bahadar, E-mail: sbkhan@kau.edu.sa [Center of Excellence for Advanced Materials Research, King Abdulaziz University, P.O. Box 80203, Jeddah, 21589 (Saudi Arabia); Chemistry Department, Faculty of Science, King Abdulaziz University, P. O. Box 80203, Jeddah, 21589 (Saudi Arabia); Khan, Shahid Ali; Asiri, Abdullah M. [Center of Excellence for Advanced Materials Research, King Abdulaziz University, P.O. Box 80203, Jeddah, 21589 (Saudi Arabia); Chemistry Department, Faculty of Science, King Abdulaziz University, P. O. Box 80203, Jeddah, 21589 (Saudi Arabia)

    2016-05-01

    Graphical abstract: - Highlights: • Cobalt based nanomaterials. • Water splitting. • Low overpotential. • Plausible self-repair electrocatalyst. - Abstract: Interesting combination of Co, Ni and Al have been assessed for oxygen evolution reaction (OER). Layered double hydroxide (LDH) nanosheets of NiCoAl, Co-Al oxide nanoparticles and Co-Ni oxide nanoparticles were prepared and studied for the first time as OER catalyst. Among all the subjected catalysts, the binary LDH comprise of NiCoAl showed comparatively high catalytic activity than Co-Al oxide nanoparticles and Co-Ni oxide nanoparticles. The Co-Al and Co-Ni oxide nanoparticles showed current densities of 34.6 and 24.5 mA cm{sup −2}, respectively at 1 V in 0.3 M KOH solution. However at the same conditions, NiCoAl-LDH showed comparatively low overpotential, high current density (40.8 mA cm{sup −2}) and lower Tafel slope. The low overpotential and high catalytic activity of NiCoAl-LDH stipulate the possibility to reduce the demand of precious, rare earth and expensive transition metal catalyst in electrochemical water splitting for OER.

  4. The (n, $\\gamma$) reaction in the s-process branching point $^{59}$Ni

    CERN Multimedia

    We propose to measure the $^{59}$Ni(n,$\\gamma$)$^{56}$Fe cross section at the neutron time of flight (n TOF) facility with a dedicated chemical vapor deposition (CVD) diamond detector. The (n, ) reaction in the radioactive $^{59}$Ni is of relevance in nuclear astrophysics as it can be seen as a rst branching point in the astrophysical s-process. Its relevance in nuclear technology is especially related to material embrittlement in stainless steel. There is a strong discrepancy between available experimental data and the evaluated nuclear data les for this isotope. The aim of the measurement is to clarify this disagreement. The clear energy separation of the reaction products of neutron induced reactions in $^{59}$Ni makes it a very suitable candidate for a rst cross section measurement with the CVD diamond detector, which should serve in the future for similar measurements at n_TOF.

  5. Microscopic study of $^{40}$Ca+$^{58,64}$Ni fusion reactions

    CERN Document Server

    Bourgin, D; Courtin, S; Haas, F

    2016-01-01

    Background: Heavy-ion fusion reactions at energies near the Coulomb barrier are influenced by couplings between the relative motion and nuclear intrinsic degrees of freedom of the colliding nuclei. The time-dependent Hartree-Fock (TDHF) theory, incorporating the couplings at the mean-field level, as well as the coupled-channels (CC) method are standard approaches to describe low energy nuclear reactions. Purpose: To investigate the effect of couplings to inelastic and transfer channels on the fusion cross sections for the reactions $^{40}$Ca+$^{58}$Ni and $^{40}$Ca+$^{64}$Ni. Methods: Fusion cross sections around and below the Coulomb barrier have been obtained from coupled-channels (CC) calculations, using the bare nucleus-nucleus potential calculated with the frozen Hartree-Fock method and coupling parameters taken from known nuclear structure data. The fusion thresholds and neutron transfer probabilities have been calculated with the TDHF method. Results: For $^{40}$Ca+$^{58}$Ni, the TDHF fusion threshold ...

  6. Temperature dependence of electrocatalytic and photocatalytic oxygen evolution reaction rates using NiFe oxide

    KAUST Repository

    Nurlaela, Ela

    2016-01-25

    The present work compares oxygen evolution reaction (OER) in electrocatalysis and photocatalysis in aqueous solutions using nanostructured NiFeOx as catalysts. The impacts of pH and reaction temperature on the electrocatalytic and photocatalytic OER kinetics were investigated. For electrocatalysis, a NiFeOx catalyst was hydrothermally decorated on Ni foam. In 1 M KOH solution, the NiFeOx electrocatalyst achieved 10 mA cm-2 at an overpotential of 260 mV. The same catalyst was decorated on the surface of Ta3N5 photocatalyst powder. The reaction was conducted in the presence of 0.1 M Na2S2O8 as a strong electron scavenger, thus likely leading to the OER being kinetically relevant. When compared with the bare Ta3N5, NiFeOx/Ta3N5 demonstrated a 5-fold improvement in photocatalytic activity in the OER under visible light irradiation, achieving a quantum efficiency of 24 % at 480 nm. Under the conditions investigated, a strong correlation between the electrocatalytic and photocatalytic performances was identified: an improvement in electrocatalysis corresponded with an improvement in photocatalysis without altering the identity of the materials. The rate change at different pH was likely associated with electrocatalytic kinetics that accordingly influenced the photocatalytic rates. The sensitivity of the reaction rates with respective to the reaction temperature resulted in an apparent activation energy of 25 kJ mol-1 in electrocatalysis, whereas that in photocatalysis was 16 kJ mol-1. The origin of the difference in these activation energy values is likely attributed to the possible effects of temperature on the individual thermodynamic and kinetic parameters of the reaction process. The work described herein demonstrates a method of “transferring the knowledge of electrocatalysis to photocatalysis” as a strong tool to rationally and quantitatively understand the complex reaction schemes involved in photocatalytic reactions.

  7. Probing the semi-magicity of $^{68}$Ni via the $^{66}$Ni(t,p)$^{68}$Ni two-neutron transfer reaction in inverse kinematics

    CERN Document Server

    AUTHOR|(CDS)2079390; Van Duppen, Piet

    The region around the nucleus $^{68}$Ni, with a shell closure for its protons at Z=28 and a harmonic oscillator shell gap for its neutrons at N=40, has drawn considerable interest over the past decades. $^{68}$Ni has properties that are typical for a doubly-magic nucleus, such as a high excitation energy and low B($E2:2^{+} \\rightarrow 0^{+}$) transition probability for the first excited 2$^{+}$ level and a 0$^{+}$ level as the first excited state. However, it has been suggested that the magic properties of $^{68}$Ni arise due to the fact that the N=40 separates the negative parity $pf$-shell from the positive parity 1$g_{9/2}$ orbital, and indeed, recent mass measurements have not revealed a clear N = 40 energy gap. Despite all additional information that was acquired over the last decade the specific role of the N=40 is not yet understood and a new experimental approach to study $^{68}$Ni was proposed. Namely, a two-neutron transfer reaction on $^{66}$Ni to characterize and disentangle the structure of the ...

  8. Magnetic Ni-Co alloys induced by water gas shift reaction, Ni-Co oxides by CO oxidation and their supercapacitor applications

    Science.gov (United States)

    Lee, Seungwon; Kang, Jung-Soo; Leung, Kam Tong; Kim, Seog K.; Sohn, Youngku

    2016-11-01

    Ni-Co alloys and oxides have attracted considerable attention in diverse fields, such as magnetic materials, energy storage and environmental/energy producing catalysts. Herein, the formation of magnetic Ni-Co alloys was induced by the water-gas shift reaction (WGSR) and the oxides were prepared by post-annealing and a CO oxidation reaction. The materials were characterized using a range of techniques. The annealed and post-CO oxidation Ni and Co-rich samples showed the crystal structures of NiCo2O4(Co3O4)/NiO and NiCo2O4/Co3O4, respectively. The Ni-Co oxides showed better supercapacitor performance than the corresponding Ni-Co alloys. The Co-rich samples exhibited better supercapacitor performance and CO oxidation activity than the Ni-rich sample. In addition, the Co-rich alloy showed a magnetization of 114 emu/g, which was approximately 2× larger than that of the Ni-rich alloy. The WGS reaction and the wide application tests are useful for designing new materials applicable to a wide range of areas.

  9. Electrodeposition of Ni on Bi2Te3 and Interfacial Reaction Between Sn and Ni-Coated Bi2Te3

    Science.gov (United States)

    Tseng, Yu-Chen; Lee, Hsuan; Hau, Nga Yu; Feng, Shien-Ping; Chen, Chih-Ming

    2017-09-01

    Bismuth-telluride (Bi2Te3)-based compounds are common thermoelectric materials used for low-temperature applications, and nickel (Ni) is usually deposited on the Bi2Te3 substrates as a diffusion barrier. Deposition of Ni on the p-type (Sb-doped) and n-type (Se-doped) Bi2Te3 substrates using electroplating and interfacial reactions between Sn and Ni-coated Bi2Te3 substrates are investigated. Electrodeposition of Ni on different Bi2Te3 substrates is characterized based on cyclic voltammetry and Tafel measurements. Microstructural characterizations of the Ni deposition and the Sn/Ni/Bi2Te3 interfacial reactions are performed using scanning electron microscopy. A faster growth rate is observed for the Ni deposition on the n-type Bi2Te3 substrate which is attributed to a lower activation energy of reduction due to a higher density of free electrons in the n-type Bi2Te3 material. The common Ni3Sn4 phase is formed at the Sn/Ni interfaces on both the p-type and n-type Bi2Te3 substrates, while the NiTe phase is formed at a faster rate at the interface between Ni and n-type Bi2Te3 substrates.

  10. Influence of M-B (M = Fe, Co, Ni) on aluminum-water reaction

    Science.gov (United States)

    Meng, H. X.; Wang, N.; Dong, Y. M.; Jia, Z. L.; Gao, L. J.; Chai, Y. J.

    2014-12-01

    In this work, the aluminum-water reaction induced by Fe-B, Co-B and Ni-B particles was studied. The catalysts were mixtures of the metal boride and metallic particles. The chainlike Fe-B catalyst forms a network structure under the influence of an external magnetic field and has a large specific surface area. Aggregated particles of Co-B and Ni-B catalyst have small specific surface area. Catalytic activity in the initial corrosion of aluminum increases with increasing Fe-B content because of the large specific surface area and the formation of a micro galvanic cell. However, the amount of hydrogen generated slowly decreases with increasing amount of Co-B and Ni-B. The activity of Fe-B, Co-B and Ni-B in the initial Al/H2O reaction decreases in the order Fe-B > Ni-B > Co-B. The calculated apparent activation energies in the presence of Fe-B, Co-B and Ni catalysts are 38.2, 39 and 29.6 kJ mol-1, respectively. Aluminum is rapidly and completely corroded in a weakly alkaline solution (pH < 10) after consecutive additions of Al batches because of high concentrations of OH- in the local domain and an increase in the amount of Al(OH)3 precipitate.

  11. Unique Sandwiched Carbon Sheets@Ni-Mn Nanoparticles for Enhanced Oxygen Evolution Reaction.

    Science.gov (United States)

    Zhang, Yan; Zhang, Huijuan; Yang, Jiao; Bai, Yuanjuan; Qiu, Huajun; Wang, Yu

    2016-05-11

    A unique sandwich-like architecture, where Ni-Mn nanoparticles are enveloped in coupled carbon sheets (CS@Ni-Mn), has been successfully fabricated. In the synthesis process, a great quantity of uniform NiMnO3 nanosheets generated by a universal hydrothermal method acts as precursors and templates and the cheap, environmentally friendly and recyclable glucose functions as a green carbon source. Via subsequent hydrothermal reaction and thermal annealing, sandwiched nanocomposites with Ni-Mn nanoparticles embedded inside and carbon sheets encapsulating outside can be massively prepared. The novel sandwich-like CS@Ni-Mn possesses numerous advantages, such as an intrinsic porous feature, large specific surface area, and enhanced electronic conductivity. Moreover, as a promising NiMn-based oxygen evolution reaction (OER) catalyst, the special sandwiched nanostructure demonstrates improved electrochemical properties in 1 M KOH, including a low overpotential of about 250 mV, a modest Tafel slope of 40 mV dec(-1), excellent stability over 2000 cycles, and durability for 40 h.

  12. Solid State Reaction Mechanism and Microstructure Evolution of Ni-Al Powders during High Energy Ball Milling Revisited by TEM.

    Science.gov (United States)

    Fan, Guohua; Geng, Lin; Feng, Yicheng; Cui, Xiping; Yan, Xudong

    2015-08-01

    Microstructure evolution during the formation of B2-NiAl by high energy ball milling of equiatomic elemental mixtures was studied by X-ray diffractometer, scanning electron microscopy, and transmission electron microscopy (TEM). The crystallite size, lattice defects and ordering of the B2-NiAl were monitored via TEM as function of milling time. The diffusion reaction, Ni+Al→NiAl3 or/and Ni2Al3, occurred during high energy ball milling, and to a certain extent offered the stored energy for the explosive exothermic reaction, Ni+Al→B2-NiAl. The fine microstructure of newly formed B2-NiAl after 5 h milling involved high density defects, e.g. antiphase boundary, long range ordering domains, vacancies, and dislocations.

  13. The (n, α) Reaction in the s-process Branching Point 59Ni

    CERN Document Server

    Weiß, C; Griesmayer, E.; Andrzejewski, J.; Badurek, G.; Chiaveri, E.; Dressler, R.; Ganesan, S.; Jericha, E.; Käppeler, F.; Koehler, P.; Lederer, C.; Leeb, H.; Marganiec, J.; Pavlik, A.; Perkowski, J.; Rauscher, T.; Reifarth, R.; Schumann, D.; Tagliente, G.; Vlachoudis, V.; Altstadt, S.; Audouin, L.; Barbagallo, M.; Bécares, V.; Bečvář, F.; Belloni, F.; Berthoumieux, E.; Billowes, J.; Boccone, V.; Bosnar, D.; Brugger, M.; Calviani, M.; Calviño, F.; Cano-Ott, D.; Carrapiço, C.; Cerutti, F.; Chin, M.; Colonna, N.; Cortés, G.; Cortés-Giraldo, M.A.; Diakaki, M.; Domingo-Pardo, C.; Duran, I.; Dzysiuk, N.; Eleftheriadis, C.; Ferrari, A.; Fraval, K.; García, A.R.; Giubrone, G.; Gómez-Hornillos, M.B.; Gonçalves, I.F.; González-Romero, E.; Gunsing, F.; Gurusamy, P.; Hernández-Prieto, A.; Jenkins, D.G.; Kadi, Y.; Karadimos, D.; Kivel, N.; Kokkoris, M.; Krtička, M.; Kroll, J.; Lampoudis, C.; Langer, C.; Leal-Cidoncha, E.; Leong, L.S.; Losito, R.; Mallick, A.; Manousos, A.; Martínez, T.; Massimi, C.; Mastinu, P.F.; Mastromarco, M.; Meaze, M.; Mendoza, E.; Mengoni, A.; Milazzo, P.M.; Mingrone, F.; Mirea, M.; Mondalaers, W.; Paradela, C.; Plompen, A.; Praena, J.; Quesada, J.M.; Riego, A.; Robles, M.S.; Roman, F.; Rubbia, C.; Sabaté-Gilarte, M.; Sarmento, R.; Saxena, A.; Schillebeeckx, P.; Schmidt, S.; Tain, J.L.; Tarrío, D.; Tassan-Got, L.; Tsinganis, A.; Valenta, S.; Vannini, G.; Variale, V.; Vaz, P.; Ventura, A.; Versaci, R.; Vermeulen, M.J.; Vlastou, R.; Wallner, A.; Ware, T.; Weigand, M.; Wright, T.; Žugec, P.

    The (n, α) reaction in the radioactive 59Ni is of relevance in nuclear astrophysics as 59Ni can be considered as the first branching point in the astrophysical s-process. Its relevance in nuclear technology is especially related to material embrittlement in stainless steel. However, there is a discrepancy between available experimental data and the evaluated nuclear data files for this reaction. At the n_TOF facility at CERN, a dedicated system based on sCVD diamond diodes was set up to measure the 59Ni(n, α)56Fe cross section. The results of this measurement, with special emphasis on the dominant resonance at 203 eV, are presented here.

  14. Combustion Synthesis Reaction Behavior of Cold-Rolled Ni/Al and Ti/Al Multilayers

    Science.gov (United States)

    2011-04-01

    pulse. Such exothermic reactions in multilayers can be used as local heat sources to melt solders or brazes and thus join components in a variety of...4 Figure 1. Schematic of the cold-rolling procedure. diffraction (XRD) examination using Cu Kα radiation. The unreacted as-cold-rolled Ni/Al

  15. Influence of additives on microstructures, mechanical properties and shock-induced reaction characteristics of Al/Ni composites

    Energy Technology Data Exchange (ETDEWEB)

    Xiong, Wei; Zhang, Xianfeng, E-mail: lynx@mail.njust.edu.cn; Wu, Yang; He, Yong; Wang, Chuanting; Guo, Lei

    2015-11-05

    Granular composites containing aluminum (Al) and nickel (Ni) are typical structural energetic materials, which possess ideal combination of both mechanical properties and energy release capability. The influence of two additives, namely Teflon (PTFE) and copper (Cu), on mechanical properties and shock-induced chemical reaction (SICR) characteristics of Al/Ni material system has been investigated. Three composites, namely Al/Ni, Al/Ni/PTFE and Al/Ni/Cu with same volumetric ratio of Al powder to Ni powder, were processed by means of static pressing. Scanning electron microscopy was used to study the microstructure of the mentioned three composites. Quasi static compression tests were also conducted to determine the mechanical properties and fracture behavior of the mentioned three composites. It was shown that the additives affected both compressive strength and fracture mode of the three composites. Impact initiation experiments on the mentioned three composites were performed to determine their shock-induced chemical reaction characteristics by considering pressure histories measured in the test chamber. The experimental results showed that the additives had significant effects on critical initiation velocity, reaction rate, reaction efficiency and post-reaction behavior. - Highlights: • .Al/Ni, Al/Ni/PTFE and Al/Ni/Cu were processed by means of static pressing. • .Microstructures, mechanical properties and shock-induced reactions were studied. • .Microstructures affect both compressive strength and fracture mode. • .Impact velocity is an important factor in shock-induced chemical characteristics. • .Each additive has significant effects on energy release behavior.

  16. Experimental results of 2-propanol dehydrogenation with a falling-liquid film reactor for solar chemical heat pump; Solar chemical heat pump ni okeru ryuka ekimakushiki 2-propanol bunkai hanno jikken

    Energy Technology Data Exchange (ETDEWEB)

    Doi, T.; Tanaka, T.; Ando, Y.; Takashima, T. [Electrotechnical Laboratory, Tsukuba (Japan); Koike, M.; Kamoshida, J. [Shibaura Institute of Technology, Tokyo (Japan)

    1997-11-25

    A solar chemical heat pump is intended to attempt multi-purposed effective utilization of solar energy by raising low temperature solar heat of about 100 degC to 150 to 200 degC by utilizing chemical reactions. The chemical heat pump under the present study uses a 2-propanol (IPA)/acetone/hydrogen system which can utilize low-temperature solar heat and has large temperature rising degree. It was found from the result of experiments and analyses that IPA dehydrogenation reaction can improve more largely the heat utilization rate in using a falling-liquid film reactor than using a liquid phase suspended system. As an attempt to improve further the heat utilization rate, this paper reports the result of experimental discussions on inclination angles of a reaction vessel and feed liquid flow rate which would affect the fluid condition of the liquid film. As a result of the experiments, the initial deterioration in the catalyst has settled in about 15 hours, and its activity has decreased to about 60% of the initial activity. It was made clear that the influence of the inclination angle of the reaction vessel on the reaction is small. 5 refs., 7 figs.

  17. Tholeiitic and calc-alkaline magma series at Adatara volcano, northesast Japan. ; Evolution mechanisms and genetic relationship. Tohoku Nippon, Adatara kazan ni okeru soreaito, karuku alkaline magma keiretsu. ; Sono shinka mechanism to seiin kankei

    Energy Technology Data Exchange (ETDEWEB)

    Fujinawa, A. (Ibaraki University, Ibaraki (Japan). Faculty of Science)

    1991-07-15

    In this report, the generation and evolution processes of coexisting low-alkali tholeiitic and calc-alkaline magmas at Adatara volcano is discussed on the basis of petrological data, and a reasonable petrological model is proposed. For the tholeiitic suite, variations of major-, trace- and rare earth-elements and Sr isotopic compositions are explained with the fractional crystallization hypothesis. These are mineralogical observations supporting this hypothesis. In contrast, for calc-alkaline suite, compositional variations of considerable numbers of major-elements and trace-elements are explained with the fractional crystallization model, but wide variations of Ni and Cr, and light REE heavy-REE ratios are inconsistent with this model. It is considered that other processes, such as mixing of magmas, assimilation and gaseous transfer, may have operated as additional processes. Also, mineralogical data are compatible with this view. 62 refs., 8 figs., 2 tabs.

  18. Interfacial reactions in the Sb-Sn/(Cu, Ni) systems: Wetting experiments

    Energy Technology Data Exchange (ETDEWEB)

    Novakovic, R., E-mail: r.novakovic@ge.ieni.cnr.it [National Research Council (CNR) - Institute for Energetics and Interphases (IENI), Via De Marini, 6-16149 Genoa (Italy); Lanata, T. [National Research Council (CNR) - Institute for Energetics and Interphases (IENI), Via De Marini, 6-16149 Genoa (Italy); Delsante, S.; Borzone, G. [DCCI-University of Genoa, Via Dodecaneso, 31 - 16146-Genoa (Italy)

    2012-12-14

    Interfacial reactions in the Sb-Sn/Cu and Sb-Sn/Ni systems have been investigated by means of wetting experiments. The wetting behaviour of two lead-free alloys, namely, Sb{sub 2.5}Sn{sub 97.5} and Sb{sub 14.5}Sn{sub 85.5} (at.%), in contact with Cu and Ni-substrates has been studied in view of possible applications as high-temperature solders in the electronics industry. The contact angle measurements on Cu and Ni plates were performed by using a sessile drop apparatus. The solder/substrate interface was characterised by the SEM-EDS analyses. -- Highlights: Black-Right-Pointing-Pointer Sb-Sn alloys are used as high temperature lead-free solders. Black-Right-Pointing-Pointer Sb-Sn alloys have good wetting properties on Cu and Ni substrates. Black-Right-Pointing-Pointer Interfacial reactions and products are important for joint properties. Black-Right-Pointing-Pointer Interfacial reactions/products data can be used to study the phase diagrams.

  19. Elastic scattering and transfer reactions for the system 7Be + 58Ni at Coulomb barrier energies

    Science.gov (United States)

    Mazzocco, M.; Torresi, D.; Acosta, L.; Boiano, A.; Boiano, C.; Glodariu, T.; Guglielmetti, A.; Keeley, N.; La Commara, M.; Lay, J. A.; Martel, I.; Mazzocchi, C.; Molini, P.; Parascandolo, C.; Parkar, V. V.; Pierroutsakou, D.; Romoli, M.; Rusek, K.; Sanchez-Benitez, A. M.; Sandoli, M.; Signorini, C.; Silvestri, R.; Soramel, F.; Strano, E.; Stroe, L.

    2015-09-01

    We investigated the reaction induced by the Radioactive Ion Beam 7Be on the closed proton shell nucleus 58Ni at 22.0 MeV bombarding energy. The 7Be beam was produced by means of the in-flight technique with the facility EXOTIC at INFN-LNL (Italy). Charged reaction products were mass and charge identified in a rather wide angular range and their energy distributions were analyzed to infer some information on the production mechanism. The relevance of direct processes, especially 3He- and 4He-stripping, as well as compound nucleus reactions is critically reviewed.

  20. Deuteron-induced reactions on Ni isotopes up to 60 MeV

    Science.gov (United States)

    Avrigeanu, M.; Šimečková, E.; Fischer, U.; Mrázek, J.; Novak, J.; Štefánik, M.; Costache, C.; Avrigeanu, V.

    2016-07-01

    Background: The high complexity of the deuteron-nucleus interaction from the deuteron weak binding energy of 2.224 MeV is also related to a variety of reactions induced by the deuteron-breakup (BU) nucleons. Thus, specific noncompound processes as BU and direct reactions (DR) make the deuteron-induced reactions so different from reactions with other incident particles. The scarce consideration of only pre-equilibrium emission (PE) and compound-nucleus (CN) mechanisms led to significant discrepancies with experimental results so that recommended reaction cross sections of high-priority elements as, e.g., Ni have mainly been obtained by fit of the data. Purpose: The unitary and consistent BU and DR account in deuteron-induced reactions on natural nickel may take advantage of an extended database for this element, including new accurate measurements of particular reaction cross sections. Method: The activation cross sections of 64,61,60Cu, Ni,5765, and 55,56,57,58,59m,60Co nuclei for deuterons incident on natural Ni at energies up to 20 MeV, were measured by the stacked-foil technique and high-resolution gamma spectrometry using U-120M cyclotron of CANAM, NPI CAS. Then, within an extended analysis of deuteron interactions with Ni isotopes up to 60 MeV, all processes from elastic scattering until the evaporation from fully equilibrated compound system have been taken into account while an increased attention is paid especially to the BU and DR mechanisms. Results: The deuteron activation cross-section analysis, completed by consideration of the PE and CN contributions corrected for decrease of the total-reaction cross section from the leakage of the initial deuteron flux towards BU and DR processes, is proved satisfactory for the first time to all available data. Conclusions: The overall agreement of the measured data and model calculations validates the description of nuclear mechanisms taken into account for deuteron-induced reactions on Ni, particularly the BU and

  1. Synthesis of CuNi/C and CuNi/γ-Al2O3 Catalysts for the Reverse Water Gas Shift Reaction

    Directory of Open Access Journals (Sweden)

    Maxime Lortie

    2015-01-01

    Full Text Available A new polyol synthesis method is described in which CuNi nanoparticles of different Cu/Ni atomic ratios were supported on both carbon and gamma-alumina and compared with Pt catalysts using the reverse water gas shift, RWGS, reaction. All catalysts were highly selective for CO formation. The concentration of CH4 was less than the detection limit. Cu was the most abundant metal on the CuNi alloy surfaces, as determined by X-ray photoelectron spectroscopy, XPS, measurements. Only one CuNi alloy catalyst, Cu50Ni50/C, appeared to be as thermally stable as the Pt/C catalysts. After three temperature cycles, from 400 to 700°C, the CO yield at 700°C obtained using the Cu50Ni50/C catalyst was comparable to that obtained using a Pt/C catalyst.

  2. Effects of Ni2+ toxicity on Hill reaction and membrane functionality in maize

    Directory of Open Access Journals (Sweden)

    Ghasemi F.

    2012-11-01

    Full Text Available Soil contamination with heavy metals has become a worldwide problem, leading to losses in agricultural yield and hazardous health effects as they enter the food chain . Nickel as an essential trace element, affect a number of biochemical and physiological processes in plants in toxic levels. The most common symptoms are chlorosis, and inhibited photosynthesis and respiration. Zea mays seeds were germinated and cultured on nutrient solution with nickel concentrations of 50-200 μmol for a period of two weeks. Studied physiological makers included photosynthetic pigments content, the rate of Hill reaction, K+ efflux and carbohydrate leakage from the roots to the external solution and cell death as a Ni-induced membrane damage. By increasing Ni concentration up to 100 μmol, the content of chlorophyll a increased, but decreased at 200 μmol Ni. No significant changes in chlorophyll b and carotinoids content observed.The rate of Hill reaction as an ability of chlorophyll a in the reaction center of PSII680 to split water, decreased by increasing Ni concentration. Different concentrations of nickel increased the K+ efflux and sugar leakage from roots to the culture and the cell death of root tips. The present results suggested that the disruption of photosynthesis by Ni cannot be attributed to any single factor and appears to result from its combined effects on chloroplast structure, chlorophyll content and photosynthetic protein complexes and treatment with different levels of nickel may induce structural damage and alterations in membrane properties by generation of reactive oxygen species.

  3. 17O+58Ni scattering and reaction dynamics around the Coulomb barrier

    Science.gov (United States)

    Strano, E.; Torresi, D.; Mazzocco, M.; Keeley, N.; Boiano, A.; Boiano, C.; Di Meo, P.; Guglielmetti, A.; La Commara, M.; Molini, P.; Manea, C.; Parascandolo, C.; Pierroutsakou, D.; Signorini, C.; Soramel, F.; Filipescu, D.; Gheorghe, A.; Glodariu, T.; Grebosz, J.; Jeong, S.; Kim, Y. H.; Lay, J. A.; Miyatake, H.; Nicoletto, M.; Pakou, A.; Rusek, K.; Sgouros, O.; Soukeras, V.; Stroe, L.; Toniolo, N.; Vitturi, A.; Watanabe, Y.; Zerva, K.

    2016-08-01

    This work aims at investigating the projectile binding energy influence on the reaction dynamics, introducing new results and new data analysis methods in order to overcome some typically encountered problems, such as the identification of reaction products differing by few mass units and the discrimination of direct reaction processes. The 17O+58Ni collision was studied at five near-barrier energies employing a compact experimental setup consisting of four double-sided silicon strip detectors (DSSSDs). Different reaction processes, namely the elastic and inelastic scattering and the 1 n stripping, were discriminated by means of a detailed analysis of the experimental energy spectra based on Monte Carlo simulations. The elastic scattering angular distributions were investigated within the framework of the optical model using Woods-Saxon and double-folding potentials. The total reaction cross sections were extracted and the reduced cross sections compared with those obtained for 17F (Sp=0.600 MeV), the mirror nucleus of 17O (Sn=4.143 MeV), and for the tightly bound 16O projectile. The 17O+58Ni total reaction cross sections were larger than those for 16O on the same target at the lowest energies studied, becoming identical, within errors, as the incident energy increased above the Coulomb barrier. This behavior was related to a strong contribution from the 1 n -stripping channel at the lowest energies.

  4. Three-dimensional PtNi Hollow Nanochains as Enhanced Electrocatalyst for Oxygen Reduction Reaction

    Energy Technology Data Exchange (ETDEWEB)

    Fu, Shaofang; Zhu, Chengzhou; Song, Junhua; Engelhard, Mark H.; He, Yang; Du, Dan; Wang, Chong M.; Lin, Yuehe

    2016-05-05

    Three-dimensional porous PtNi hollow nanochains are successfully synthesized via galvanic replacement method using Ni nanosponges as sacrificial templates in an aqueous solution. It is found that the composition and shell thickness of the 3D PtNi hollow nanochains can be easily controlled by tuning the concentration of Pt precursors. The as-prepared PtNi hollow nanochains with optimized composition present high electrochemical surface area (70.8 m2 g-1), which is close to that of commercial Pt/C (83 m2 g-1). Moreover, the PtNi catalyst with Pt content of ~77% presents superior electrocatalytic performance for oxygen reduction reaction compared to commercial Pt/C. It shows a mass activity of 0.58 A mgPt-1, which is around 3 times higher than that of Pt/C. This strategy may be extended to the preparation of other multimetallic nanocrystals with 3D hollow nanostructures, which are expected to present high catalytic properties.

  5. Electro-deposition of Pd on carbon paper and Ni foam via surface limited redox-replacement reaction for oxygen reduction reaction

    CSIR Research Space (South Africa)

    Modibedi, RM

    2014-05-01

    Full Text Available Pd nanostructured catalysts were electrodeposited by surface-limited redox replacement reactions usingthe electrochemical atomic layer deposition technique. Carbon paper and Ni foam were used as substratesfor the electrodeposition of the metal...

  6. Evaluation of the autonomic neuropathy function immediately after a change to upright posture using the impulse response function; Impulse oto kansu wo mochiita shisei henkan katoki ni okeru jiritsu shinkei kino hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Yokoyama, K. [Nagoya City University, Nagoya (Japan); Moyoshi, M.; Takata, K. [Daido Institute of Technology, Nagoya (Japan); Watanabe, Y. [Toyota College of Technology, Aichi (Japan)

    1997-05-20

    Autonomic neuropathy function immediately after a change to upright posture has been evaluated by applying transient response function of the system to the blood regulation system. The impulse response function was determined from the change in heart rate before postural change to the upright posture, and was compared with the transient change immediately after a change to the upright posture. The time series of R-R interval of electrocardiogram was used as the time series of the change in heart rate. To determine the impulse response function, an autoregressive model was applied to the R-R interval time series. The impulse response function at the steady state is a transient reaction at the impulse stimulation added to the blood regulation system. The R-R interval decreases rapidly by the autonomic neuropathy reaction in which the blood is rapidly transferred into the legs immediately after a change to upright posture. There is a close correlation between the initial temporary decrease in R-R interval and the impulse response function derived from the change in heart rate immediately after a change to the upright posture. Accordingly, the blood regulation and autonomic neuropathy functions can be evaluated by the impulse response function without actual standing test and load of tested persons. 9 refs., 3 figs., 1 tab.

  7. Layered structure of Ni-Al multi-layered metal-intermetallic composites fabricated by in-situ reactions

    Institute of Scientific and Technical Information of China (English)

    张佼; 孙宝德; 夏振海

    2004-01-01

    Systematical experiments were done at five temperature levels: 500 ℃, 630 ℃, 900 ℃, 1 000 ℃ and 1 100 ℃ to illuminate the layer structure of the multi-layered metal-intermetallic composites of Ni-Al system that were fabricated by a previously reported simple and cost-effective method. The analysis of back scattering photos and XRD examination of specimens reveal that the look like single compound layer is composed of several different components. The primary phase produced during reaction is Ni2 Al3 and there exists a like two-phase field between NiAl3 and Ni2 Al3. The high temperature phases like NiAl and Ni3 Al are also found at low temperature. The results indicate that the key driving force of in-situ reaction is not temperature, but the atom concentration.

  8. Compressive properties of a reaction milled NiAl-AlN composite

    OpenAIRE

    Whittenberger, J. Daniel; Arzt, Eduard; Luton, Michael J.

    1990-01-01

    Cryomilling (high intensity mechanical ball milling in a liquid nitrogen bath) of the B2 crystal structure nickel aluminide leads to a NiAl composite containing about 10 vol. % of AlN particles. This is the result of a reaction milling process, where nitrogen incorporated into the matrix during cryomilling reacts with Al during subsequent thermomechanical processing to form the composite. Compressive testing at 1300 K of such materials densified by 1505 K extrusion or isostatic pressing at 13...

  9. Effect of intermolecular cohesion on coal liquefaction. 3. Reactivity of oxygen methylated coal; Sekitan teibunshika hanno ni okeru bunshikan gyoshuryoku no koka. 3. O-methyl ka tan no hanno tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Sasaki, M.; Nagaishi, H.; Yoshida, T. [Hokkaido National Industrial Research Institute, Sapporo (Japan)

    1996-10-28

    The reactivity of oxygen methylated coal was studied to control hydrogen bond in bituminous coal liquefaction and intermolecular cohesion such as van der Waals force. In experiment, crushed and dried Illinois coal of 100mesh or less was used as specimen, and oxygen methylated coal was prepared by Liotta`s method using tetrabutylammonium halide. Coal liquefaction was conducted in an electromagnetic agitation autoclave using tetralin solvent under initial hydrogen pressure of 100kg/cm{sup 2} while heating. The molecular weight distribution of the products obtained was measured by gel permeation chromatography (GPC) analysis. The experimental results are as follows. The effect of intermolecular cohesion in bituminous coal on the reactivity is mainly derived from decomposing reaction from preasphaltene to oil. Yields of oil fraction by methylation increase corresponding to release of intermolecular cohesion. Since the thermal release is promoted with temperature rise, the difference in yield due to different treatments decreases. 5 refs., 3 figs., 1 tab.

  10. Dissolution and Interfacial Reactions of (Cu,Ni)6Sn5 Intermetallic Compound in Molten Sn-Cu-Ni Solders

    Science.gov (United States)

    Wang, Chao-hong; Lai, Wei-han; Chen, Sinn-wen

    2014-01-01

    (Cu,Ni)6Sn5 is an important intermetallic compound (IMC) in lead-free Sn-Ag-Cu solder joints on Ni substrate. The formation, growth, and microstructural evolution of (Cu,Ni)6Sn5 are closely correlated with the concentrations of Cu and Ni in the solder. This study reports the interfacial behaviors of (Cu,Ni)6Sn5 IMC (Sn-31 at.%Cu-24 at.%Ni) with various Sn-Cu, Sn-Ni, and Sn-Cu-Ni solders at 250°C. The (Cu,Ni)6Sn5 substrate remained intact for Sn-0.7 wt.%Cu solder. When the Cu concentration was decreased to 0.3 wt.%, (Cu,Ni)6Sn5 significantly dissolved into the molten solder. Moreover, (Cu,Ni)6Sn5 dissolution and (Ni,Cu)3Sn4 formation occurred simultaneously for the Sn-0.1 wt.%Ni solder. In Sn-0.5 wt.%Cu-0.2 wt.%Ni solder, many tiny (Cu,Ni)6Sn5 particulates were formed and dispersed in the solder matrix, while in Sn-0.3 wt.%Cu-0.2 wt.%Ni a lot of (Ni,Cu)3Sn4 grains were produced. Based on the local equilibrium hypothesis, these results are further discussed based on the liquid-(Cu, Ni)6Sn5-(Ni,Cu)3Sn4 tie-triangle, and the liquid apex is suggested to be very close to Sn-0.4 wt.%Cu-0.2 wt.%Ni.

  11. Excitation function of alpha-particle-induced reactions on {sup nat}Ni from threshold to 44 MeV

    Energy Technology Data Exchange (ETDEWEB)

    Uddin, M.S. [Atomic Energy Research Establishment, Tandem Accelerator Facilities, Institute of Nuclear Science and Technology, Savar, Dhaka (Bangladesh); Kim, K.S.; Nadeem, M.; Kim, G.N. [Kyungpook National University, Department of Physics, Buk-gu, Daegu (Korea, Republic of); Sudar, S. [Debrecen University, Institute of Experimental Physics, Debrecen (Hungary)

    2017-05-15

    Excitation functions of the {sup nat}Ni(α,x){sup 62,63,65}Zn, {sup nat}Ni(α,x){sup 56,57}Ni and {sup nat}Ni(α,x){sup 56,57,58m+g}Co reactions were measured from the respective thresholds to 44MeV using the stacked-foil activation technique. The tests for the beam characterization are described. The radioactivity was measured using HPGe γ-ray detectors. Theoretical calculations on α-particles-induced reactions on {sup nat}Ni were performed using the nuclear model code TALYS-1.8. A few results are new, the others strengthen the database. Our experimental data were compared with results of nuclear model calculations and described the reaction mechanism. (orig.)

  12. Kinetic study of the annealing reactions in Cu-Ni-Fe alloys; Estudio cinetico de las reacciones de recocido en aleaciones de Cu-Ni-Fe

    Energy Technology Data Exchange (ETDEWEB)

    Donoso, E.

    2014-07-01

    The thermal aging of a Cu-45Ni-4Fe, Cu-34Ni-11Fe and Cu-33Ni-22Fe alloys tempered from 1173 K have been studied from Differential Scanning Calorimetry (DSC) and microhardness measurements. The analysis of DSC curves, from room temperature to 950 K, shows the presence of one exothermic reaction associated to the formation of FeNi{sub 3} phase nucleating from a modulate structure, and one endothermic peak attributed to dissolution of this phase. Kinetic parameters were obtained using the usual Avrami-Erofeev equation, modified Kissinger method and integrated kinetic functions. Microhardness measurements confirmed the formation and dissolution of the FeNi{sub 3} phase. (Author)

  13. Ionization current in N2 gas. Part 7. ; Diffusion and reflection of metastable particles. N2 gas chu ni okeru denri denryu. 7. ; Jun antei reiki ryushi no kakusan to hansha

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, S.; Ito, H.; Sekizawa, H. (Chiba Inst. of Technology, Chiba (Japan)); Ikuta, N. (Tokushima Univ., Tokushima (Japan))

    1993-06-20

    The energy loss process in quenching of excited particles by collision to other ones and solid surfaces was investigated with metastable excited particles formed in weakly ionized gases. The measured lifetime of N2 metastable particles in N2, N2/CO, N2/CH3 gases during Townsent discharge did not agree with the Molnar's theoretical value which was obtained by solving diffusion equations using the boundary condition that assumes the density of excited particles to be zero at electrodes and tube walls. Strange behavior was observed too, that is, coefficients of diffusion and reaction rate determined by the theoretical lifetime change systematically with the distance between electrodes. Then, the novel boundary condition that takes reflection coefficient into account was applied to solve diffusion equations. The results obtained could account for experimental results without any discrepancy. The analysis of results clarified the dependence of various parameters of metastable excited particles on the reflection coefficient. The increase of reflection coefficient decreases the surface quenching of excited particles at electrodes and elongs effectively excited lifetime and increases the number of collisional quenching in gas phases. 16 refs., 8 figs.

  14. Coliquefaction of coal, tar sand bitumen and plastic (interaction among coal, bitumen and plastic); Sekitan/tar sand bitumen/plastic no kyoekika ni okeru kyozon busshitsu no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Yamaguchi, H.; Okuyama, Y.; Matsubara, K. [NKK Corp., Tokyo (Japan); Kamo, T.; Sato, Y. [National Institute for Resources and Environment, Tsukuba (Japan)

    1996-10-28

    For the improvement of economy, coliquefaction of coal, tar sand bitumen and plastic was performed under low hydrogen pressure, to investigate the influence of interaction among these on the liquefaction characteristics. For comparison, coliquefaction was also performed under the hydrogen pressure same as the NEDOL process. In addition, for clarifying its reaction mechanism, coliquefaction of dibenzyl and plastic was performed as a model experiment, to illustrate the distribution of products and composition of oil, and to discuss the interaction between dibenzyl and various plastics, and between various plastics. Under direct coal liquefaction conditions, coprocessing of Tanito Harum coal, Athabasca tar sand and plastic was carried out under low hydrogen pressure with an autoclave. The observed value of oil yield was higher than the calculated value based on the values from separate liquefaction of coal and plastic, which suggested the interaction between coal and the mixed plastic. The results of coliquefaction of coal, tar sand bitumen and plastic could be explained from the obtained oil yield and its composition by the coliquefaction of dibenzyl and plastic. 2 refs., 3 tabs.

  15. Time series analysis of the CO sub 2 exchange rate in the one-year-old leaves of laelia anceps lindl. Laelia anceps lindl no ichinen shiyo ni okeru CO sub 2 kokan sokudo no jikeiretsu kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Dogane, Yuji; Ando, Toshio (Chiba Univ., Chiba, (Japan). Faculty of Horticulture)

    1990-01-31

    Concerning the carbon-fixing patterns in the dark reaction of plant photosynthesis, it has been known that there are 3 kinds, namely C {sub 3}, C {sub 4}, and CAM types, most of green plants fix CO {sub 2} by their C {sub 3} circuits and those with {C sub 4} and CAM circuits are rather small in number. However, CAM plants can switch from the CAM type to the C {sub 3} type or vice versa depending upon the external as well as internal factors and have capability of changing the balance between the two circuits, often making analysis of quantitative and qualitative changes of photosynthesis difficult, hence the analysis of photosynthesis rate of CAM plants dealt with in the studies which have so far been made has been limited to a quantitative grasp. This study used Laelia anceps Lindl. as sample material, classified several conditions whose photosynthesis rates differ recognizably and succeeded to analyze qualitative differences of these conditions by the mathematical measure. For analyzing photosynthesis rates, the time series analysis was newly adopted. 11 refs., 4 figs., 1 tab.

  16. Combustion characteristics in a municipal solid waste incinerator. 1st Report. ; Field test and computer simulation for combustion characterization. Toshi gomi shokyakuro ni okeru nensho tokusei. 1. ; Nensho jotai haaku no tame no jikken to simulation

    Energy Technology Data Exchange (ETDEWEB)

    Ishimi, T.; Higashimura, K. (Kubota Corp., Osaka (Japan)); Koyama, M.; Hirayama, N. (Chiba Institute of Technology, Chiba (Japan))

    1994-05-25

    For suppressing and controlling the emission of dioxins in the flue gas from the city garbage incinerator, it is necessary to perform the complete combustion. The combustion state in the incinerator was investigated to understand the influence of combustion factors on the combustion. A computer simulation analysis on the gas flow in the incinerator was also carried out. The concentration of CO and O2 in the combustion gas leaving the incinerator and the temperature distribution in the incinerator were measured. The results showed that the atmosphere in the incinerator was distinctly separated into two zones, i.e., the high temperature zone where the O2 concentration was extremely low while the CO concentration exhibited its peak value and the low temperature zone where the CO concentration was relatively low and O2 concentration was excessively high. The effect of combustion gas temperature on the combustion reaction of unburnt gas was found to be high. When the combustion gas temperature was elevated, the CO concentration in the exhaust gas leaving the electrostatic precipitator was exponentially decreased. The relationship between the CO concentration and the O2 concentration could be expressed in a quadratic equation. There was a certain optimum O2 optimal concentration range for reducing the CO concentration. The O2 concentration was an important factor for controlling the combustion. The result of computer simulation proved to be shown well the combustion gas flow in the incinerator. 8 refs., 10 figs., 4 tabs.

  17. Impact of Mn(II)-Manganese Oxide Reactions on Ni and Zn Speciation.

    Science.gov (United States)

    Hinkle, Margaret A G; Dye, Katherine G; Catalano, Jeffrey G

    2017-03-01

    Layered Mn oxide minerals (phyllomanganates) often control trace metal fate in natural systems. The strong uptake of metals such as Ni and Zn by phyllomanganates results from adsorption on or incorporation into vacancy sites. Mn(II) also binds to vacancies and subsequent comproportionation with structural Mn(IV) may alter sheet structures by forming larger and distorted Mn(III)O6 octahedra. Such Mn(II)-phyllomanganate reactions may thus alter metal uptake by blocking key reactive sites. Here we investigate the effect of Mn(II) on Ni and Zn binding to phyllomanganates of varying initial vacancy content (δ-MnO2, hexagonal birnessite, and triclinic birnessite) at pH 4 and 7 under anaerobic conditions. Dissolved Mn(II) decreases macroscopic Ni and Zn uptake at pH 4 but not pH 7. Extended X-ray absorption fine structure spectroscopy demonstrates that decreased uptake at pH 4 corresponds with altered Ni and Zn adsorption mechanisms. These metals transition from binding in the interlayer to sheet edges, with Zn increasing its tetrahedrally coordinated fraction. These effects on metal uptake and binding correlate with Mn(II)-induced structural changes, which are more substantial at pH 4 than 7. Through these structural effects and the pH-dependence of Mn(II)-metal competitive adsorption, system pH largely controls metal binding to phyllomanganates in the presence of dissolved Mn(II).

  18. The oxidation of Ni(II) N-confused porphyrins (NCPs) with azo radical initiators and an unexpected intramolecular nucleophilic substitution reaction via a proposed Ni(III) NCP intermediate.

    Science.gov (United States)

    Jiang, Hua-Wei; Chen, Qing-Yun; Xiao, Ji-Chang; Gu, Yu-Cheng

    2009-07-01

    The oxidation of Ni(II) N-confused porphyrins (NCPs) with azo radical initiators resulted in an unexpected intramolecular nucleophilic substitution reaction via a proposed Ni(III) NCP intermediate, which could be detected by HRMS.

  19. Water-Gas Shift and CO Methanation Reactions over Ni-CeO2(111) Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    S Senanayake; J Evans; S Agnoli; L Barrio; T Chen; J Hrbek; J Rodriguez

    2011-12-31

    X-ray and ultraviolet photoelectron spectroscopies were used to study the interaction of Ni atoms with CeO{sub 2}(111) surfaces. Upon adsorption on CeO{sub 2}(111) at 300 K, nickel remains in a metallic state. Heating to elevated temperatures (500-800 K) leads to partial reduction of the ceria substrate with the formation of Ni{sup 2+} species that exists as NiO and/or Ce{sub 1-x}Ni{sub x}O{sub 2-y}. Interactions of nickel with the oxide substrate significantly reduce the density of occupied Ni 3d states near the Fermi level. The results of core-level photoemission and near-edge X-ray absorption fine structure point to weakly bound CO species on CeO{sub 2}(111) which are clearly distinguishable from the formation of chemisorbed carbonates. In the presence of Ni, a stronger interaction is observed with chemisorption of CO on the admetal. When the Ni is in contact with Ce{sup +3} cations, CO dissociates on the surface at 300 K forming NiC{sub x} compounds that may be involved in the formation of CH{sub 4} at higher temperatures. At medium and large Ni coverages (>0.3 ML), the Ni/CeO{sub 2}(111) surfaces are able to catalyze the production of methane from CO and H{sub 2}, with an activity slightly higher than that of Ni(100) or Ni(111). On the other hand, at small coverages of Ni (<0.3 ML), the Ni/CeO{sub 2}(111) surfaces exhibit a very low activity for CO methanation but are very good catalysts for the water-gas shift reaction.

  20. Exploring possible reaction pathways for the o-atom transfer reactions to unsaturated substrates catalyzed by a [Ni-NO2 ] ↔ [Ni-NO] redox couple using DFT methods.

    Science.gov (United States)

    Tsipis, Athanassios C

    2017-07-15

    The (nitro)(N-methyldithiocarbamato)(trimethylphospane)nickel(II), [Ni(NO2 )(S2 CNHMe)(PMe3 )] complex catalyses efficiently the O-atom transfer reactions to CO and acetylene. Energetically feasible sequence of elementary steps involved in the catalytic cycle of the air oxidation of CO and acetylene are proposed promoted by the Ni(NO2 )(S2 CNHMe)(PMe3 )] ↔ Ni(NO2 )(S2 CNHMe)(PMe3 ) redox couple using DFT methods both in vacuum and dichloromethane solutions. The catalytic air oxidation of HC≡CH involves formation of a five-member metallacycle intermediate, via a [3 + 2] cyclo-addition reaction of HC≡CH to the Ni-N = O moiety of the Ni(NO2 )(S2 CNHMe)(PMe3 )] complex, followed by a β H-atom migration toward the Cα carbon atom of the coordinated acetylene and release of the oxidation product (ketene). The geometric and energetic reaction profile for the reversible [Ni( κN1-NO2 )(S2 CNHMe)(PMe3 )] ⇌ [Ni( κO,O2-ONO)(S2 CNHMe)(PMe3 )] linkage isomerization has also been modeled by DFT calculations. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

  1. Single Photon Initiated Decomposition Rearrangement Reactions (spidrr) of Organic Molecules Mediated by the Ni+ Cation

    Science.gov (United States)

    Bellert, Darrin; Mansell, Adam; Theis, Zachary; Gutierrez, Michael

    2016-06-01

    The Bellert group at Baylor University has developed a novel method for performing single photon initiated decomposition rearrangement reactions (SPIDRR) of organic molecules mediated by a transition metal cation. The advantage that SPIDRR affords is the direct measurement of first order microcanonical rate constants, k(E), determined at resolved internal energies. Furthermore, the SPIDRR technique measures kinetic details of exothermic reactions where product production is limited only by submerged activation barriers (kinetic barriers that are at energies below the separated reactant limit). Thus, such reactions approach unit efficiency, are thermodynamically driven, and are of greater relevance to catalytic research. Direct measurements of k(E) values extend to isotopically labelled species that provide direct measurement of the kinetic isotope effect (KIE), furnishing unique insight into the mechanistic details of a reaction. This talk presents results from the visible photon initiated, Ni+ induced decarbonylation reaction of propionaldehyde. Here a rather unique energy dependent behavior of the measured rate constants was observed and attributed to a dynamic competition between parallel reaction coordinates available to the photo-excited precursor. RRKM calculations in concert with high level DFT is used to support and further experimental results.

  2. nihon no iryo jujisha ni okeru shokugyosei sutoresu

    OpenAIRE

    伊藤, 慎也

    2014-01-01

    主査 : 水野雅文 /タイトル : Occupational stress among healthcare workers in Japan /著者 : Shinya Ito, Shigeru Fujita, Kanako Seto, Takefumi Kitazawa, Kunichika Matsumoto, Tomonori Hasegawa /掲載誌 : Work: A Journal of Prevention, Assessment and Rehabilitation /巻号・発行年等 : 49(2):225-234, 2014 /本文ファイル : 出版者版

  3. Bonded structure application for aircraft. Kokuki ni okeru secchaku gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, O. (Japan Airlines Co. Ltd., Tokyo (Japan))

    1991-01-05

    Adhesives play an important role in a technology of the aircraft structure for which lightness and strength are required. The paper explains the present situation of bonding technology employed for aircraft, the honeycomb structure, production of composite materials and the related problems. Advantages and purposes of employing adhesives as substitutes for fasteners like screws, rivets, etc. are as follows: decreases in stress concentration, weight reduction, smoothing of surfaces, improvement of acoustic fatigue by adhesives flexibility, prevention of gas-liquid leakage. Epoxide adhesives are mainly used for aircraft. Together with tear straps, which are metal-metal bonded to the rear fuselage plate of aircraft, and waffle doublers, an aluminium honeycomb sandwich structure, whose weight is 1/7 of an aluminium plate same in rigidity, is used in such parts of aircraft as spoilers, outer plates of flaps, etc. The problem of the bonded structure is detachment. Therefore, how to prevent, discover and repair it is most important. 3 figs.

  4. The borohydride oxidation reaction on La-Ni-based hydrogen-storage alloys.

    Science.gov (United States)

    Paschoalino, Waldemir J; Thompson, Stephen J; Russell, Andrea E; Ticianelli, Edson A

    2014-07-21

    This work provides insights into the processes involved in the borohydride oxidation reaction (BOR) in alkaline media on metal hydride alloys formed by LaNi(4.7)Sn(0.2)Cu(0.1) and LaNi(4.78)Al(0.22) with and without deposited Pt, Pd, and Au. The results confirm the occurrence of hydrolysis of the borohydride ions when the materials are exposed to BH(4)(-) and a continuous hydriding of the alloys during BH(4)(-) oxidation measurements at low current densities. The activity for the direct BOR is low in both bare metal hydride alloys, but the rate of the BH(4)(-) hydrolysis and the hydrogen-storage capacity are higher, while the rate of H diffusion is slower for bare LaNi(4.78) Al(0.22). The addition of Pt and Pd to both alloys results in an increase of the BH(4)(-) hydrolysis, but the H(2) formed is rapidly oxidized at the Pt-modified catalysts. In the case of Au modification, a small increase in the BH(4)(-) hydrolysis is observed as compared to the bare alloys. The presence of Au and Pd also leads to a reduction of the rates of alloy hydriding/de-hydriding. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Depletion and phase transformation of a submicron Ni(P) film in the early stage of soldering reaction between Sn-Ag-Cu and Au/Pd(P)/Ni(P)/Cu

    Science.gov (United States)

    Ho, Cheng-En; Hsieh, Wan-Zhen; Yang, Tsung-Hsun

    2015-01-01

    The early stage of soldering reaction between Sn-3Ag-0.5Cu solder and ultrathin-Ni(P)-type Au/Pd(P)/Ni(P)/Cu pad was investigated by field-emission scanning electron microscopy (FE-SEM) in conjunction with field-emission electron probe microanalysis (FEEPMA) and high-resolution transmission electron microscopy (HRTEM). FE-SEM, FE-EPMA, and HRTEM investigations showed that Ni2SnP and Ni3P were the predominant P-containing intermetallic compounds (IMCs) in the soldering reaction and that their growth behaviors strongly depended on the depletion of Ni(P). The growth of Ni3P dominated over that of Ni2SnP in the early stage of soldering, whereas the Ni3P gradually transformed into Ni2SnP after Ni(P) depletion. This Ni(P)-depletion-induced Ni2SnP growth behavior is different from the reaction mechanisms reported in the literature. Detailed analyses of the microstructural evolution of the IMC during Ni(P) depletion were conducted, and a two-stage reaction mechanism was proposed to rationalize the unique IMC growth behavior.

  6. Measurement of the $^{58}$Ni($\\alpha$,$\\gamma$)$^{62}$Zn reaction and its astrophysical impact

    CERN Document Server

    Quinn, S J; Bravo, E; Rauscher, T; Simon, A; Battaglia, A; Bowers, M; Bucher, B; Casarella, C; Couder, M; DeYoung, P A; Dombos, A C; Görres, J; Kontos, A; Li, Q; Long, A; Moran, M; Paul, N; Pereira, J; Robertson, D; Smith, K; Smith, M K; Stech, E; Talwar, R; Tan, W P; Wiescher, M

    2014-01-01

    Cross section measurements of the $^{58}$Ni($\\alpha$,$\\gamma$)$^{62}$Zn reaction were performed in the energy range $E_{\\alpha}=5.5-9.5$ MeV at the Nuclear Science Laboratory of the University of Notre Dame, using the NSCL Summing NaI(Tl) detector and the $\\gamma$-summing technique. The measurements are compared to predictions in the statistical Hauser-Feshbach model of nuclear reactions using the SMARAGD code. It is found that the energy dependence of the cross section is reproduced well but the absolute value is overestimated by the prediction. This can be remedied by rescaling the $\\alpha$ width by a factor of 0.45. Stellar reactivities were calculated with the rescaled $\\alpha$ width and their impact on nucleosynthesis in type Ia supernovae has been studied. It is found that the resulting abundances change by up to 5\\% when using the new reactivities.

  7. Mo/MCM-41-Type mesoporous materials doubly promoted with Fe and Ni for hydrotreating reactions

    Energy Technology Data Exchange (ETDEWEB)

    Carlos F. Linares; Patricia Amezqueta; Carlos Scott [Universidad de Carabobo, Carabobo (Venezuela). Laboratorio de Catalisis y Metales de Transicion

    2008-09-15

    A Si-MCM-41-type material was synthesized and impregnated with a Mo solution in order to get a 15% MoO{sub 3} by weight. Then, it was doubly promoted with Ni and Fe in different proportions. Information on the structure of the precursors was revealed by XRD, TPR and surface area techniques. XRD results showed that the mesoporous materials were not affected for the successive impregnations carried out; while, their specific surface areas was partially blocked. These solids were tested for vanadyl octaethyl porphyrin hydrodeporphirinization (HDP), and individual and competitive reactions of dibenzothiophene (DBT) hydrodesulfurization (HDS) and 2-methyl naphthalene (2MN) hydrogenation (HYD). The DBT HDS activity was higher than 2MN HYD, and the presence of Fe in the catalysts did not produce a synergetic effect for this reactions. However, HDP activities of doubly promoted catalysts were superior to the monopromoted ones. 28 refs., 8 figs., 5 tabs.

  8. Electrocatalytic oxygen evolution reaction at a FeNi composite on a carbon nanofiber matrix in alkaline media

    Institute of Scientific and Technical Information of China (English)

    Xianghua An; Dongyoon Shin; Joey D. Ocon; Jae Kwang Lee; Young-il Son; Jaeyoung Lee

    2014-01-01

    Non-noble metals such as Fe and Ni have comparable electrocatalytic activity and stability to that of Ir and Ru in an oxygen evolution reaction (OER). In this study, we synthesized carbon nanofibers with embedded FeNi composites (FeNi-CNFs) as OER electrocatalysts by a facile route comprising electrospinning and the pyrolysis of a mixture of metal precursors and a polymer solution. FeNi-CNFs demonstrated catalytic activity and stability that were better than that of 20 wt%Ir on Vulcan carbon black in oxidizing water to produce oxygen in an alkaline media. Physicochemical and electrochemical characterization revealed that Fe and Ni had synergistic roles that enhanced OER activity by the uniform formation and widening of pores in the carbon structure, while the CNF matrix also contributed to the increased stability of the catalyst.

  9. Effect of RE-Doped and RE Quantity of Ni-Based Catalysts on CH4/CO2 Reforming Reaction

    Institute of Scientific and Technical Information of China (English)

    Yang Yifeng; Li Xiancai; Dai Chao; Wang Chunfeng; Chen Juanrong

    2004-01-01

    RE-doped Ni-based catalysts were prepared by sol-gel method.These catalysts were applied to the reaction of CO2 reforming CH4 to syngas.The studies reveal that RE-doped ( RE = La, Ce, Sm, Yb) Ni-based catalysts show higher catalytic activity than undoped Ni-based catalyst, and with the increasing of RE-doped quantity, the catalytic activity of catalysts exhibits regular changes.When RE-doped quantity is 0.2% ( molar ratio), the catalysts show the best catalytic activity.

  10. Combined Thermodynamic-Kinetic Analysis of the Interfacial Reactions between Ni Metallization and Various Lead-Free Solders

    Directory of Open Access Journals (Sweden)

    Tomi Laurila

    2009-11-01

    Full Text Available In this paper we will demonstrate how a thermodynamic-kinetic method can be utilized to rationalize a wide range of interfacial phenomena between Sn-based lead-free solders and Ni metallizations. First, the effect of P on the interfacial reactions, and thus on the reliability, between Sn-based solders and electroless Ni/immersion Au (ENIG metallizations, will be discussed. Next, the effect of small amounts of Cu in Sn-based solders on the intermetallic compound (IMC, which forms first on top of Ni metallization, will be covered. With the help of thermodynamic arguments a so called critical Cu concentration for the formation of (Cu,Ni6Sn5 can be determined as a function of temperature. Then the important phenomenon of redeposition of (Au,NiSn4 layer on top of Ni3Sn4 IMC will be discussed in detail. The reasons leading to this behaviour will be rationalized with the help of thermodynamic information and an explanation of why this phenomenon does not occur when an appropriate amount of Cu is present in the soldering system will be given. Finally, interfacial reaction issues related to low temperature Sn-Zn and Sn-Bi based solders and Ni metallization will be discussed.

  11. Effect of massive transformation on formation of acicular structure in austenitic stainless steel weld metal solidified as ferritic single phase. Report 5. Study on solidification and subsequent transformation of Cr-Ni stainless steel weld metals; Feraito tanso de gyokosuru osutenaito kei sutenresu ko yosetsu kinzoku ni okeru ashikyura jo soshiki no keisei ni oyobosu masshibu hentai no eikyo.5. Cr-Ni kei sutenresu ko yosetsu kinzoku no gyoko/hentai ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, H.; Koseki, T.; Okita, S.; Fuji, M. [Nippon Steel Corp., Tokyo (Japan)

    1997-05-05

    The authors clarified that massive transformation occurs at two phase region under To temperature and there is K-S relation between the massive formation phase and base phase using {gamma} stainless steel that solidifies at F mode and forms acicular structure at room temperature structure. There is a possibility of massive transformation in weld metals because the cooling rate below the high temperature To was high even for normal welding process. Thereupon, in this report, whether the massive transformation effects the formation of acicular structure or not was studied as for {gamma} stainless steel weld metal that solidifies at F mode and room temperature structure becomes acicular form of two {delta} and {gamma} phase. As a result, it was clarified that massive transformation occurs at two phase region with temperature below To, and the room temperature structure was acicular form structure irrespective to massive transformation in case of composition with small Cr/Ni ratio even in case of stainless steel that solidifies at F mode. 20 refs., 15 figs., 1 tab.

  12. Ni nanoparticles supported on graphene layers: An excellent 3D electrode for hydrogen evolution reaction in alkaline solution

    Science.gov (United States)

    Wang, Lixin; Li, Yao; Xia, Meirong; Li, Zhiping; Chen, Zhouhao; Ma, Zhipeng; Qin, Xiujuan; Shao, Guangjie

    2017-04-01

    Metal Ni is a plentiful resource that can actively split water toward hydrogen evolution reaction (HER) in alkaline solution, but exploiting high-efficiency Ni-based composite catalysts is still a significant assignment. Therefore, we design a catalytic material with one-step approach to co-electrodeposit Ni nanoparticles and reduced graphene oxide (rGO) sheets on a three-dimensional Ni foam. When the carbon content existed in Ni-rGO composite catalyst is 3.335 at%, the catalyst exhibits excellent activity on HER with a low Tafel slope (b = 77 mV dec-1), a high exchange current density (j0 = 3.408 mA cm-2), small overpotentials of only 36, 129, and 183 mV to drive 10, 60, and 100 mA cm-2 respectively, and high stability under the different current densities. Such remarkable hydrogen evolution performance is attributed to good electrical conductivity, large specific surface area and harmonious synergistic effect between Ni particles and rGO sheets. In addition, density functional theory (DFT) calculations explain that Ni-rGO composite material presents superior interfacial activity in adsorption/desorption of H* compared with pure Ni and rGO sheet.

  13. Enhanced Reaction Kinetics and Structure Integrity of Ni/SnO2 Nanocluster toward High-Performance Lithium Storage.

    Science.gov (United States)

    Jiang, Yinzhu; Li, Yong; Zhou, Peng; Yu, Shenglan; Sun, Wenping; Dou, Shixue

    2015-12-09

    SnO2 is regarded as one of the most promising anodes via conversion-alloying mechanism for advanced lithium ion batteries. However, the sluggish conversion reaction severely degrades the reversible capacity, Coulombic efficiency and rate capability. In this paper, through constructing porous Ni/SnO2 composite electrode composed of homogeneously distributed SnO2 and Ni nanoparticles, the reaction kinetics of SnO2 is greatly enhanced, leading to full conversion reaction, superior cycling stability and improved rate capability. The uniformly distributed Ni nanoparticles provide a fast charge transport pathway for electrochemical reactions, and restrict the direct contact and aggregation of SnO2 nanoparticles during cycling. In the meantime, the void space among the nanoclusters increases the contact area between the electrolyte and active materials, and accommodates the huge volume change during cycling as well. The Ni/SnO2 composite electrode possesses a high reversible capacity of 820.5 mAh g(-1) at 1 A g(-1) up to 100 cycles. More impressively, large capacity of 841.9, 806.6, and 770.7 mAh g(-1) can still be maintained at high current densities of 2, 5, and 10 A g(-1) respectively. The results demonstrate that Ni/SnO2 is a high-performance anode for advanced lithium-ion batteries with high specific capacity, excellent rate capability, and cycling stability.

  14. Producing laminated NiAl with bimodal distribution of grain size by solid–liquid reaction treatment

    DEFF Research Database (Denmark)

    Fan, G.H.; Wang, Q.W.; Du, Y.

    2014-01-01

    The prospect of combining laminated structure design and grain size tailoring to toughen brittle materials is examined. Laminated NiAl consisting of coarse-grained layers and fine-grained layers was fabricated by solid–liquid reaction treatment of stacking Ni and Al foils. The fracture toughness...... at ambient temperature has been improved 2–3 times. It is of great potential to extend this approach to other binary alloys, such as Ti–Al, Fe–Al, Nb–Al, etc., where solid–liquid reaction occurs readily at high temperature....

  15. Thermodynamics of formation reactions of intermetallides Ni/sub 3/Ta and Ni/sub 2/Ta

    Energy Technology Data Exchange (ETDEWEB)

    Lyakishev, N.P.; Snitko, Yu.P.; Alekseev, V.I.; Levshin, G.A. (Tsentral' nyj Nauchno-Issledovatel' skij Inst. Chernoj Metallurgii, Moscow (USSR))

    1981-01-01

    Thermodynamical functions of the formation of Ni/sub 3/Ta and Ni/sub 2/Ta intermetallides are studied when investigating the electromotive force of the cell MoVertical BarTa/sub 2/O/sub 5/, Nisub(x)Tasub(y)Vertical Bar0.99ThOsub(2)i0.01 CaOVertical Bar Fe, Fesub(0.95)OVertical BarMo in the temperature range of 1173-1323 K. Thermodynamical functions of Ni/sub 3/Ta and Ni/sub 2/Ta formation are equal to: ..delta..Gsub(f)sup(0) (1273 K) 31.70 and 28.86; ..delta..Hsub(f)sup(0) (1173-1323 K) 27.88, 07.9 kcal/mol; ..delta..Ssub(f)sup(0) (1173-1323 K) 3,U and 0.75 cal/molxdegree, respectively.

  16. NiSe@NiOOH Core-Shell Hyacinth-like Nanostructures on Nickel Foam Synthesized by in Situ Electrochemical Oxidation as an Efficient Electrocatalyst for the Oxygen Evolution Reaction.

    Science.gov (United States)

    Li, Xiao; Han, Guan-Qun; Liu, Yan-Ru; Dong, Bin; Hu, Wen-Hui; Shang, Xiao; Chai, Yong-Ming; Liu, Chen-Guang

    2016-08-10

    NiSe@NiOOH core-shell hyacinth-like nanostructures supported on nickel foam (NF) have been successfully synthesized by a facile solvothermal selenization and subsequent in situ electrochemical oxidation (ISEO). First, the unique NiSe/NF nanopillar arrays were prepared in N,N-dimethylformamide (DMF) as a precursor template that can provide a large surface area, excellent conductivity, and robust support. Next, amorphous NiOOH covering the surface of NiSe nanopillars was fabricated by ISEO, as confirmed by XPS andEDX spectroscopy. SEM images revealed the hyacinth-like morphology of NiSe@NiOOH/NF with NiOOH as the shell and NiSe as the core. The electrochemical performance of NiSe@NiOOH/NF for the oxygen evolution reaction (OER) was investigated. NiSe@NiOOH/NF demonstrates an obviously enhanced OER activity with much lower overpotential of 332 mV at 50 mA cm(-2) compared to other Ni-based electrocatalysts. The low charge-transfer resistance (Rct), large electrochemical double-layer capacitance (Cdl) of electrochemically active surface areas (ECSAs), and excellent long-term stability of NiSe@NiOOH/NF confirm the enhancement of its electrochemical performance for the OER, which can be ascribed to the large amount of active sites derived from the amorphous NiOOH shell and the good conductivity and stability derived from the NiSe core. In addition, the synergistic effect between the NiSe core and NiOOH shell could serve for a highly efficient OER electrocatalyst.

  17. Carbon-carbon cross-coupling reactions catalyzed by a two-coordinate nickel(II)-bis(amido) complex via observable Ni(I) , Ni(II) , and Ni(III) intermediates.

    Science.gov (United States)

    Lipschutz, Michael I; Tilley, T Don

    2014-07-01

    Recently, the development of more sustainable catalytic systems based on abundant first-row metals, especially nickel, for cross-coupling reactions has attracted significant interest. One of the key intermediates invoked in these reactions is a Ni(III) -alkyl species, but no such species that is part of a competent catalytic cycle has yet been isolated. Herein, we report a carbon-carbon cross-coupling system based on a two-coordinate Ni(II) -bis(amido) complex in which a Ni(III) -alkyl species can be isolated and fully characterized. This study details compelling experimental evidence of the role played by this Ni(III) -alkyl species as well as those of other key Ni(I) and Ni(II) intermediates. The catalytic cycle described herein is also one of the first examples of a two-coordinate complex that competently catalyzes an organic transformation, potentially leading to a new class of catalysts based on the unique ability of first-row transition metals to accommodate two-coordinate complexes.

  18. Reaction pathways of furfural, furfuryl alcohol and 2-methylfuran on Cu(111) and NiCu bimetallic surfaces

    Science.gov (United States)

    Xiong, Ke; Wan, Weiming; Chen, Jingguang G.

    2016-10-01

    Hydrodeoxygenation (HDO) is an important reaction for converting biomass-derived furfural to value-added 2-methylfuran, which is a promising fuel additive. In this work, the HDO of furfural to produce 2-methylfuran occurred on the NiCu bimetallic surfaces prepared on either Ni(111) or Cu(111). The reaction pathways of furfural were investigated on Cu(111) and Ni/Cu(111) surfaces using density functional theory (DFT) calculations, temperature-programmed desorption (TPD) and high-resolution electron energy loss spectroscopy (HREELS) experiments. These studies provided mechanistic insights into the effects of bimetallic formation on enhancing the HDO activity. Specifically, furfural weakly adsorbed on Cu(111), while it strongly adsorbed on Ni/Cu(111) through an η2(C,O) configuration, which led to the HDO of furfural on Ni/Cu(111). The ability to dissociate H2 on Ni/Cu(111) is also an important factor for enhancing the HDO activity over Cu(111).

  19. Steam reforming of methane over Ni catalysts prepared from hydrotalcite-type precursors:Catalytic activity and reaction kinetics

    Institute of Scientific and Technical Information of China (English)

    Yang Qi; Zhenmin Cheng; Zhiming Zhou

    2015-01-01

    Ni/Mg–Al catalysts derived from hydrotalcite-type precursors were prepared by a co-precipitation technique and applied to steam reforming of methane. By comparison with Ni/γ-Al2O3 and Ni/α-Al2O3 catalysts prepared by in-cipient wetness impregnation, the Ni/Mg–Al catalyst presented much higher activity as a result of higher specific surface area and better Ni dispersion. The Ni/Mg–Al catalyst with a Ni/Mg/Al molar ratio of 0.5:2.5:1 exhibited the highest activity for steam methane reforming and was selected for kinetic investigation. With external and inter-nal diffusion limitations eliminated, kinetic experiments were carried out at atmospheric pressure and over a temperature range of 823–973 K. The results demonstrated that the overal conversion of CH4 and the conversion of CH4 to CO2 were strongly influenced by reaction temperature, residence time of reactants as wel as molar ratio of steam to methane. A classical Langmuir–Hinshelwood kinetic model proposed by Xu and Froment (1989) fitted the experimental data with excellent agreement. The estimated adsorption parameters were consistent thermodynamical y.

  20. Formation of magnetic microstructure of the nanosized NiFe2O4 synthesized via solid-state reaction

    Directory of Open Access Journals (Sweden)

    Žák T.

    2012-01-01

    Full Text Available Magnetic NiFe2O4 structure formation was studied through structural, compositional and magnetic characterization of obtained reaction products of a simple, high yielding and low-cost solid-state reaction. Initial annealing of the starting oxides mixture at 700ºC did not allow us to observe formation of the desired magnetic phase. In contrast, subsequent thermomagnetic measurements up to 800ºC indicated the considerable increase of the magnetic moment, which can be reasonably assigned to the changes in phase composition and formation of magnetic NiFe2O4 structure during the heating cycle of measurements. Nanosized NiFe2O4 phase formation has been confirmed by the following XRD and MS phase analyses and its nanocrystalline structure by XRD and SEM/TEM techniques. The obtained hysteresis loop taken after TM measurements suggest the increased volume of magnetically active material and thus additionally support the previous findings.

  1. Cross-section measurement for Ni(n,x)58(m+g)Co,Ni(n,x)60mCo,Ni(n,x)61Co and Ni(n,x)62mCo reactions induced by neutrons around 14MeV

    Institute of Scientific and Technical Information of China (English)

    FANG Kai-Hong; XU Xiao-San; LAN Chang-Lin; UAN Ji-Long; KONG Xiang-Zhong

    2008-01-01

    The cross sections of Ni(n,x)58(m+g)CO,Ni(n,x)80mCo,Ni(n,x)61Co and Ni(n,x)62mCo reactions induced by neutrons around [14]MeV were measured in this work and calculated by a previously developed formula in this work.The neutron flux was determined using the monitor reaction 27Al(n,α)24Na and the neutron energies were measured with the method of cross-section ratios for 89Zr(n,2n)89Zr to 93Nb(n,2n)92mNbreactions.

  2. Oxygen reduction reaction on a highly-alloyed Pt-Ni supported carbon electrocatalyst in acid solution

    CSIR Research Space (South Africa)

    Zheng, H

    2010-08-31

    Full Text Available Alloyed electrocatalysts such as PtNi/C[1-2], PtCo/C[3], PtCr/C[4], PtFe/C [5-6], and non-alloyed Pt-TiO2/C were reportedly investigated for methanol tolerance during Oxygen reduction reaction (ORR). The high methanol tolerance...

  3. Degradation of aniline by heterogeneous Fenton's reaction using a Ni-Fe oxalate complex catalyst.

    Science.gov (United States)

    Liu, Yucan; Zhang, Guangming; Fang, Shunyan; Chong, Shan; Zhu, Jia

    2016-11-01

    A Ni-Fe oxalate complex catalyst was synthesized and characterized by means of Brunauer-Emmet-Teller (BET) method, scanning electron microscope (SEM) and X-ray photo-electron spectroscopy (XPS). The catalyst showed good catalytic activity for aniline degradation by heterogeneous Fenton's reaction, in which the synergetic index was 9.3. The effects of reaction temperature, catalyst dosage, hydrogen peroxide concentration and initial pH were investigated. Under the optimum conditions (T = 293 K, catalyst dosage = 0.2 g/L, H2O2 concentration = 4 mmol/L and initial pH = 5.4), 100% aniline could be removed within 35 min, and approximately 88% deamination efficiency was achieved in 60 min. The aniline degradation process followed the pseudo-first-order kinetic (k = 0.177 min(-1)) with activation energy (Ea) of 49.4 kJ mol(-1). Aniline could be removed in a broad initial pH (3-8) due to the excellent pH-tolerance property of the catalyst. The detected ammonium ion indicated that deamination occurred during aniline degradation. It was proposed that deamination synchronized with aniline removal, and aniline was attacked by free radicals to generate benzoquinonimine and phenol. This system is promising for the removal of aniline from water.

  4. Carbon Supported Engineering NiCo2O4 Hybrid Nanofibers with Enhanced Electrocatalytic Activity for Oxygen Reduction Reaction

    Directory of Open Access Journals (Sweden)

    Diab Hassan

    2016-09-01

    Full Text Available The design of cheap and efficient oxygen reduction reaction (ORR electrocatalysts is of a significant importance in sustainable and renewable energy technologies. Therefore, ORR catalysts with superb electrocatalytic activity and durability are becoming a necessity but still remain challenging. Herein, we report C/NiCo2O4 nanocomposite fibers fabricated by a straightforward electrospinning technique followed by a simple sintering process as a promising ORR electrocatalyst in alkaline condition. The mixed-valence oxide can offer numerous accessible active sites. In addition, the as-obtained C/NiCo2O4 hybrid reveals significantly remarkable electrocatalytic performance with a highly positive onset potential of 0.65 V, which is only 50 mV lower than that of commercially available Pt/C catalysts. The analyses indicate that C/NiCo2O4 catalyst can catalyze O2-molecules via direct four electron pathway in a similar behavior as commercial Pt/C catalysts dose. Compared to single NiCo2O4 and carbon free NiCo2O4, the C/NiCo2O4 hybrid displays higher ORR current and more positive half-wave potential. The incorporated carbon matrices are beneficial for fast electron transfer and can significantly impose an outstanding contribution to the electrocatalytic activity. Results indicate that the synthetic strategy hold a potential as efficient route to fabricate highly active nanostructures for practical use in energy technologies.

  5. Time-dependent Hartree-Fock calculations for multinucleon transfer and quasifission processes in $^{64}$Ni+$^{238}$U reaction

    CERN Document Server

    Sekizawa, Kazuyuki

    2016-01-01

    Background: Multinucleon transfer (MNT) and quasifission (QF) processes are dominant processes in low-energy collisions of two heavy nuclei. They are expected to be useful to produce neutron-rich unstable nuclei. Nuclear dynamics leading to these processes depends sensitively on nuclear properties such as deformation and shell structure. Purpose: We elucidate reaction mechanisms of MNT and QF processes involving heavy deformed nuclei, making detailed comparisons between microscopic TDHF calculations and measurements for $^{64}$Ni+$^{238}$U reaction. Methods: Three-dimensional Skyrme-TDHF calculations are performed. Particle-number projection method is used to evaluate MNT cross sections from the TDHF wave function after collision. Results: Fragment masses, total kinetic energy (TKE), scattering angle, contact time, and MNT cross sections are investigated for $^{64}$Ni+$^{238}$U reaction. They show reasonable agreements with measurements. At small impact parameters, collision dynamics depends sensitively on th...

  6. Facile synthesis of ultrathin Ni(OH)2-Cu2S hexagonal nanosheets hybrid for oxygen evolution reaction

    Science.gov (United States)

    Yang, Duo; Gao, Li; Yang, Jing-He

    2017-08-01

    The development of non-noble metal water oxidation catalyst has been a challenge in oxygen evolution reaction. A two-dimensional (2D) ultrathin Ni(OH)2-Cu2S hexagonal nanosheet hybrid is in situ synthesized by hydrothermal reaction as electrocatalyst for oxygen evolution reaction. The 2D ultrathin hexagonal Ni(OH)2-Cu2S nanosheets are homogeneous in size with edge lengths of 20-30 nm. This catalyst exhibits a current density of 10 mA cm-2 at an over-potential of 0.5 V and Tafel slope of 89 mV dec-1 for water oxidation in 0.1 M KOH. Moreover, the nanosheets are stable and no deactivation is observed during the following cyclic voltammetry cycles, even up to 3500 cycles.

  7. In-operando elucidation of bimetallic CoNi nanoparticles during high-temperature CH 4 /CO 2 reaction

    KAUST Repository

    AlSabban, Bedour

    2017-05-02

    Dry reforming of methane (DRM) proceeds via CH4 decomposition to leave surface carbon species, followed by their removal with CO2-derived species. Reactivity tuning for stoichiometric CH4/CO2 reactants was attempted by alloying the non-noble metals Co and Ni, which have high affinity with CO2 and high activity for CH4 decomposition, respectively. This study was focused on providing evidence of the capturing surface coverage of the reactive intermediates and the associated structural changes of the metals during DRM at high temperature using in-operando X-ray absorption spectroscopy (XAS). On the Co catalysts, the first-order effects with respect to CH4 pressure and negative-order effects with respect to CO2 pressure on the DRM rate are consistent with the competitive adsorption of the surface oxygen species on the same sites as the CH4 decomposition reaction. The Ni surface provides comparatively higher rates of CH4 decomposition and the resultant DRM than the Co catalyst but leaves some deposited carbon on the catalyst surface. In contrast, the bimetallic CoNi catalyst exhibits reactivity towards the DRM but with kinetic orders resembling Co catalyst, producing negligible carbon deposition by balancing CH4 and CO2 activation. The in-operando X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) measurements confirmed that the Co catalyst was progressively oxidized from the surface to the bulk with reaction time, whereas CoNi and Ni remained relatively reduced during DRM. Density functional theory (DFT) calculation considering the high reaction temperature for DRM confirmed the unselective site arrangement between Co and Ni atoms in both the surface and bulk of the alloy nanoparticle (NP). The calculated heat of oxygen chemisorption became more exothermic in the order of Ni, CoNi, Co, consistent with the catalytic behavior. The comprehensive experimental and theoretical evidence provided herein clearly suggests

  8. Ternary mixed metal Fe-doped NiCo2O4 nanowires as efficient electrocatalysts for oxygen evolution reaction

    Science.gov (United States)

    Yan, Kai-Li; Shang, Xiao; Li, Zhen; Dong, Bin; Li, Xiao; Gao, Wen-Kun; Chi, Jing-Qi; Chai, Yong-Ming; Liu, Chen-Guang

    2017-09-01

    Designing mixed metal oxides with unique nanostructures as efficient electrocatalysts for water electrolysis has been an attractive approach for the storage of renewable energies. The ternary mixed metal spinel oxides FexNi1-xCo2O4 (x = 0, 0.1, 0.25, 0.5, 0.75, 0.9, 1) have been synthesized by a facile hydrothermal approach and calcination treatment using nickel foam as substrate. Fe/Ni ratios have been proved to affect the nanostructures of FexNi1-xCo2O, which imply different intrinsic activity for oxygen evolution reaction (OER). SEM images show that Fe0.5Ni0.5Co2O4 has the uniform nanowires morphology with about 30 nm of the diameter and 200-300 nm of the length. The OER measurements show that Fe0.5Ni0.5Co2O4 exhibits the better electrocatalytic performances with lower overpotential of 350 mV at J = 10 mA cm-2. In addition, the smaller Tafel slope of 27 mV dec-1 than other samples with different Fe/Ni ratios for Fe0.5Ni0.5Co2O4 is obtained. The improved OER activity of Fe0.5Ni0.5Co2O4 may be attributed to the synergistic effects from ternary mixed metals especially Fe-doping and the uniform nanowires supported on NF. Therefore, synthesizing Fe-doped multi-metal oxides with novel nanostructures may be a promising strategy for excellent OER electrocatalysts and it also provides a facile way for the fabrication of high-activity ternary mixed metal oxides electrocatalysts.

  9. NiCo2O4/N-doped graphene as an advanced electrocatalyst for oxygen reduction reaction

    Science.gov (United States)

    Zhang, Hui; Li, Huiyong; Wang, Haiyan; He, Kejian; Wang, Shuangyin; Tang, Yougen; Chen, Jiajie

    2015-04-01

    Developing low-cost catalyst for high-performance oxygen reduction reaction (ORR) is highly desirable. Herein, NiCo2O4/N-doped reduced graphene oxide (NiCo2O4/N-rGO) hybrid is proposed as a high-performance catalyst for ORR for the first time. The well-formed NiCo2O4/N-rGO hybrid is studied by cyclic voltammetry (CV) curves and linear-sweep voltammetry (LSV) performed on the rotating-ring-disk-electrode (RDE) in comparison with N-rGO-free NiCo2O4 and the bare N-rGO. Due to the synergistic effect, the NiCo2O4/N-rGO hybrid exhibits significant improvement of catalytic performance with an onset potential of -0.12 V, which mainly favors a direct four electron pathway in ORR process, close to the behavior of commercial carbon-supported Pt. Also, the benefits of N-incorporation are investigated by comparing NiCo2O4/N-rGO with NiCo2O4/rGO, where higher cathodic currents, much more positive half-wave potential and more electron transfer numbers are observed for the N-doping one, which should be ascribed to the new highly efficient active sites created by N incorporation into graphene. The NiCo2O4/N-rGO hybrid could be used as a promising catalyst for high power metal/air battery.

  10. Effect of Ca, Ce or K oxide addition on the activity of Ni/SiO{sub 2} catalysts for the methane decomposition reaction

    Energy Technology Data Exchange (ETDEWEB)

    Zapata, Beatriz; Torres-Garcia, Enelio [Instituto Mexicano del Petroleo, Programa de Procesos y Reactores, Eje C. 152, Mexico, D.F., C.P. 07730 (Mexico); Valenzuela, Miguel A.; Palacios, Jorge [Instituto Politecnico Nacional-ESIQIE, Lab. Catalisis y Materiales, Zacatenco, Mexico, D.F., C.P. 07738 (Mexico)

    2010-11-15

    To increase the activity and stability of Ni/SiO{sub 2} catalysts, a series of Ni-Ca, Ni-K and Ni-Ce promoted catalysts were prepared by successive impregnations. The textural properties, reducibility and catalytic performance in the methane decomposition reaction were investigated. The catalyst containing 30 wt.% Ni and 30 wt.% cerium oxide greatly increased the conversion of methane (90% of equilibrium value) and improved the stability, whereas the Ni-K and Ni-Ca were less active and stable than the Ni/SiO{sub 2} catalyst. The results suggest that Ce addition prevents the sintering of nickel particles during reduction process maintaining a random distribution between the silica and cerium oxide improving the distribution and migration of deposited carbon. (author)

  11. Synthesis of Ni3S2 nanotube arrays on nickel foam by catalysis of thermal reduced graphene for hydrogen evolution reaction

    Science.gov (United States)

    Jinlong, Lv; Miura, Hideo; Meng, Yang; Tongxiang, Liang

    2017-03-01

    The thermal reduced graphene oxide deposition on nickel foam was successfully synthesized by ultrasonic and subsequent thermal reduction process. Ultrathin mesoporous Ni3S2 was formed on the bare nickel foam after hydrothermal process, while Ni3S2 nanotube arrays were formed on the surface of nickel foam with the thermal reduced graphene oxide due to catalysis action of thermal reduced graphene oxide. The resulting Ni3S2 nanotube arrays exhibited higher catalytic activity than ultrathin mesoporous Ni3S2 for hydrogen evolution reaction. In addition, and excellent stability was also obtained in Ni3S2 nanotube arrays.

  12. The dissociative chemisorption of methane on Ni(100) and Ni(111): classical and quantum studies based on the reaction path Hamiltonian.

    Science.gov (United States)

    Mastromatteo, Michael; Jackson, Bret

    2013-11-21

    Electronic structure methods based on density functional theory are used to construct a reaction path Hamiltonian for CH4 dissociation on the Ni(100) and Ni(111) surfaces. Both quantum and quasi-classical trajectory approaches are used to compute dissociative sticking probabilities, including all molecular degrees of freedom and the effects of lattice motion. Both approaches show a large enhancement in sticking when the incident molecule is vibrationally excited, and both can reproduce the mode specificity observed in experiments. However, the quasi-classical calculations significantly overestimate the ground state dissociative sticking at all energies, and the magnitude of the enhancement in sticking with vibrational excitation is much smaller than that computed using the quantum approach or observed in the experiments. The origin of this behavior is an unphysical flow of zero point energy from the nine normal vibrational modes into the reaction coordinate, giving large values for reaction at energies below the activation energy. Perturbative assumptions made in the quantum studies are shown to be accurate at all energies studied.

  13. Structure and properties of porous TiNi(Co, Mo)-based alloy produced by the reaction sintering

    Science.gov (United States)

    Artyukhova, Nadezda; Yasenchuk, Yuriy; Chekalkin, Timofey; Gunther, Victor; Kim, Ji-Soon; Kang, Ji-Hoon

    2016-10-01

    Modern medical technologies have developed many new devices that can be implanted into humans to repair, assist or take the place of diseased or defective bones, arteries and even organs. The materials, especially porous ones, used for these devices have evolved steadily over the past twenty years with TiNi-based alloys replacing stainless steels and titanium. The aim of the paper is to presents results for examination of porous TiNi(Co,Mo)-based alloys intended further to be used in clinical practice. The structure and properties of porous TiNi-based alloys obtained by reaction sintering of Ti and Ni powders with additions of Co and Mo have been studied. It has been shown that alloying additions both Co and Mo inhibit the compaction of nickel powders in the initial stage of sintering. The maximum irreversible strain of porous samples under loading in the austenitic state is fixed with the Co addition, and the minimum one is fixed with the Mo addition. The Co addition leads to the fact that the martensite transformation in the TiNi phase becomes close to a one-step, and the Mo addition leads to the fact that the martensite transformation becomes more uniform. Both Co and Mo lead to an increase in the maximum accumulated strain as a result of the formation of temperature martensite. The additional increase in the maximum accumulated strain of the Ti50Ni49Co1 alloy is caused by decreased resistance of the porous Ni γ -based mass during the load.

  14. Tiny crystalline grain nanocrystal NiCo2O4/N-doped graphene composite for efficient oxygen reduction reaction

    Science.gov (United States)

    Wan, Li-li; Zang, Guo-long; Wang, Xin; Zhou, Le-an; Li, Tian; Zhou, Qi-xing

    2017-03-01

    Oxygen reduction reaction (ORR) plays an important role in green energy conversion, although catalysts are necessary for overcoming its sluggish kinetic. Herein, a nanocrystal NiCo2O4/N-doped graphene composite material showing high ORR electrocatalytic activity is prepared. The resulting NiCo2O4/N-doped graphene composite (NiCo2O4-NG/C) combines the advantages of both component materials and shows enhanced ORR electrocatalytic activity (i.e., more positive peak potential and half-wave potential compared with NiCo2O4) while having higher diffusion-limited current density values (-5.7 mA cm-2, 1600 rpm), better tolerance to methanol, and improved stability than 20 wt% Pt/C. NiCo2O4 anchored on N-doped graphene are demonstrated to be nanocrystal with tiny crystalline grain (diameter < 5 nm) and result in large surface area, thereby allowing more active sites to be exposed. Moreover, the potential exposure of high-index planes may be also responsible for the observed high activity of these materials.

  15. Ultrathin Two-Dimensional Free-Standing Sandwiched NiFe/C for High-Efficiency Oxygen Evolution Reaction.

    Science.gov (United States)

    Feng, Yangyang; Zhang, Huijuan; Zhang, Yan; Li, Xiao; Wang, Yu

    2015-05-06

    A NiFe-based compound is considered one of the most promising candidates for the highest oxygen evolution reaction (OER) electrocatalytic activities among all nonprecious metal-based electrocatalysts. In this report, a unique catalyst of free-standing sandwiched NiFe nanoparticles encapsulated by graphene sheets is first devised and fabricated. In this method, we use low-cost, sustainable, and environmentally friendly glucose as a carbon source, ultrathin Fe-doped Ni(OH)2 nanosheets as a precursor, and a sacrificial template. This special nanoarchitecture with a conductive network around active catalysts can accelerate electron transfer and prevent NiFe nanoparticles from aggregation and peeling off during long-time electrochemical reactions, thereby exhibiting an excellent OER activity and stability in basic solutions. In this work, our sandwiched catalyst presents well activities of a low onset of ∼1.44 V (vs RHE) and Tafel slope of ∼30 mV/decade in 1 M KOH at a scan rate of 5 mV/s.

  16. Tuning crystal phase of NiSx through electro-oxidized nickel foam: A novel route for preparing efficient electrocatalysts for oxygen evolution reaction

    Science.gov (United States)

    Li, Xiao; Shang, Xiao; Rao, Yi; Dong, Bin; Han, Guan-Qun; Hu, Wen-Hui; Liu, Yan-Ru; Yan, Kai-Li; Chi, Jing-Qi; Chai, Yong-Ming; Liu, Chen-Guang

    2017-02-01

    A facile solvothermal sulfurization using electro-oxidized nickel foam (NF(Ox)) as support has been applied to prepare NiSx/NF(Ox) electrocatalyst with highly efficient activity for oxygen evolution reaction (OER). XRD patterns confirm the composition of NiSx/NF(Ox): two kinds of crystal phase including β-NiS and Ni3S2. While using bare NF as support under identical conditions, only Ni3S2 phase can be detected. SEM images reveal two kinds of morphologies of NiSx/NF(Ox) including pyramids structure of β-NiS and nanorod-like structure of Ni3S2, which implies the tuning effect of electro-pretreatment of NF on the selective preparation of NiSx crystal phase. It can be speculated that Ni(OH)2 layer derived from electro-oxidized NF is responsible for the growth of β-NiS while metallic Ni is transformed into Ni2S3 during sulfurization. Electrochemical measurements for OER indicate the enhanced electrocatalytic activity of NiSx/NF(Ox) with a small overpotential of 72 mV to reach 10 mA cm-2 compared with Ni3S2/NF, which may be ascribed to the improved electron-transfer kinetics relating to the unique atomic configurations and crystalline structures of β-NiS. The electro-oxidation pretreatment of nickel foam provides a simple and convenient method by tuning different NiSx crystal phases for preparing excellent OER eletrocatalysts.

  17. $K^+$ production in the reaction $^{58}Ni + ^{58}Ni$ at incident energies from 1 to 2 AGeV

    CERN Document Server

    Best, D; Hong, B; Kirejczyk, M; Ritman, J; Wisniewski, K; Zhilin, A; Gobbi, A; Hildenbrand, K D; Leifels, Y; Pinkenburg, C; Reisdorf, W; Schull, D; Sodan, U; Wang, G S; Wienold, T; Alard, J P; Amouroux, V; Bastid, N; Belyaev, I; Berek, G; Biegansky, J; Cherbachev, R; Coffin, J P; Crochet, P; Dupieux, P; Fodor, Z; Genoux-Lubain, A; Goebels, G; Guillaume, G; Hafele, E; Jundt, F; Kecskeméti, J; Korchagin, Y; Kotte, R; Kuhn, C; Lebedev, A; Legrand, I; Maazouzi, C; Man'ko, V; Mösner, J; Mohren, S; Moisa, D; Neubert, W; Pelte, D; Petrovici, M; Pras, P; Rami, F; Roy, C; Seres, Z; Sikora, B; Simion, V; Siwek-Wilczynska, K; Smolyankin, V T; Somov, A; Tizniti, L; Trzaska, M; Vasilev, M A; Wagner, P; Wohlfarth, D; Yushmanov, I E

    1997-01-01

    Semi-inclusive triple differential multiplicity distributions of positively charged kaons have been measured over a wide range in rapidity and transverse mass for central collisions of $^{58}$Ni with $^{58}$Ni nuclei. The transverse mass ($m_t$) spectra have been studied as a function of rapidity at a beam energy 1.93 AGeV. The $m_t$ distributions of K^+ mesons are well described by a single Boltzmann-type function. The spectral slopes are similar to that of the protons indicating that rescattering plays a significant role in the propagation of the kaon. Multiplicity densities have been obtained as a function of rapidity by extrapolating the Boltzmann-type fits to the measured distributions over the remaining phase space. The total K^+ meson yield has been determined at beam energies of 1.06, 1.45, and 1.93 AGeV, and is presented in comparison to existing data. The low total yield indicates that the K^+ meson can not be explained within a hadro-chemical equilibrium scenario, therefore indicating that the yiel...

  18. Facile synthesis of magnetic metal (Mn, Fe, Co, and Ni) oxides nanocrystals via a cation-exchange reaction.

    Science.gov (United States)

    Ning, Jiajia; Xiao, Guanjun; Wang, Li; Zou, Bo; Liu, Bingbing; Zou, Guangtian

    2011-02-01

    Magnetic metal (Mn, Fe, Co, and Ni) oxides nanocrystals with small size and uniform size distribution are synthesized via a cation-exchange reaction. Two experimental stages are included in the synthesis of metal oxides nanocrystals. Firstly, Cu(OH)2 decomposes to CuO nanocrystals, induced by free metal cations. Compared to CuO nanocrystals produced without any free metal cation, the free metal cation has an important influence on the shape and size of CuO. Secondly, free metal cations exchange with the Cu2+ cation in the CuO nanocrystals to get Mn3O4, Fe2O3, CoO and NiO nanocrystals by cation-exchange reactions. The magnetic properties of these metal oxides nanocrystals have been investigated, all the nanocrystals are superparamagnetic at room temperature.

  19. Hydrogen oxidation reaction at the Ni/YSZ anode of solid oxide fuel cells from first principles.

    Science.gov (United States)

    Cucinotta, Clotilde S; Bernasconi, Marco; Parrinello, Michele

    2011-11-11

    By means of ab initio simulations we here provide a comprehensive scenario for hydrogen oxidation reactions at the Ni/zirconia anode of solid oxide fuel cells. The simulations have also revealed that in the presence of water chemisorbed at the oxide surface, the active region for H oxidation actually extends beyond the metal/zirconia interface unraveling the role of water partial pressure in the decrease of the polarization resistance observed experimentally.

  20. N-doped carbon@Ni-Al2O3 nanosheet array@graphene oxide composite as an electrocatalyst for hydrogen evolution reaction in alkaline medium

    Science.gov (United States)

    Wang, Juan; Qiu, Tian; Chen, Xu; Lu, Yanluo; Yang, Wensheng

    2015-10-01

    An NiAl-layered double-hydroxide (NiAl-LDH) nanosheet array is grown on a graphene oxide (GO) substrate (NiAl-LDH@GO) by the hydrothermal method. The NiAl-LDH@GO is used as the precursor to synthetize an N-doped carbon@Ni-Al2O3 nanosheet array@GO composite (N-C@Ni-Al2O3@GO) by coating with dopamine followed by calcination. The N-C@Ni-Al2O3@GO is used as a non-noble metal electrocatalyst for hydrogen evolution reaction in alkaline medium, and exhibits high electrocatalytic activity with low onset overpotential (-75 mV). The improved electrocatalytic performance of N-C@Ni-Al2O3@GO arises from its intrinsic features. First, it has a high specific surface area with the Ni nanoparticles in the composite dispersed well and the sizes of Ni nanoparticles are small, which lead to the exposure of more active sites for electrocatalysis. Second, there is a synergistic effect between the Ni nanoparticles and the N-C coating layer, which is beneficial to reduce the activation energy of the Volmer step and improve the electrocatalytic activity. Third, the N-C coating layer and the XC-72 additive can form an electrically conductive network, which serves as a bridge for the transfer of electrons from the electrode to the Ni nanoparticles.

  1. Reaction Mechanism of Al and N in Diamond Growth from a FeNiCo-C System

    Institute of Scientific and Technical Information of China (English)

    LI Shang-Sheng; LI Xiao-Lei; MA Hong-An; SU Tai-Chao; XIAO Hong-Yu; HUANG Guo-Feng; LI Yong; ZHANG Yi-Shun; JIA Xiao-Peng

    2011-01-01

    @@ It is significant to investigate the action of nitrogen getters, which are used to synthesize type-Ⅱa large diamond single crystals under high pressure and high temperature (HPHT).The reaction mechanism of A1 as a nitrogen getter and N in the HPHT alloy solvent is still indeterminate at present.In order to investigate the reaction of Al and N in the HPHT alloy solvent, Al and AlN are respectively added to the system of FeNiCo-C (wt%, abbr.FeNiCo-C) for the synthesis of diamonds at about 5.5 GPa and 1600 K.The concentration of nitrogen in the diamonds is characterized by a micro Fourier transform infrared (micro-FTIR) spectrometer.The experimental results show that c decreases when Al is added to the FeNiCo-C system.However, it increases when AlN is added.A reversible reaction confirms that Al and N can react and form AlN, simultaneously A1N can be decomposed into Al and N in the HPHT alloy solvent.Therefore the mechanism of eliminating the nitrogen of nitrogen getter Al is realized in detail.%It is significant to investigate the action of nitrogen getters, which are used to synthesize type-Iia large diamond single crystals under high pressure and high temperature (HPHT). The reaction mechanism of Al as a nitrogen getter and N in the HPHT alloy solvent is still indeterminate at present. In order to investigate the reaction of Al and N in the HPHT alloy solvent, Al and A1N are respectively added to the system of FessiNfogCoie-C (wt%, abbr. FeNiCo-C) for the synthesis of diamonds at about 5.5 Gpa and 1600K. The concentration of nitrogen in the diamonds is characterized by a micro Fourier transform infrared (micro-FTIR) spectrometer. The experimental results show that cn decreases when Al is added to the FeNiCo-C system. However, it increases when AIN is added. A reversible reaction confirms that Al and N can react and form AIN, simultaneously AIN can be decomposed into Al and N in the HPHT alloy solvent. Therefore the mechanism of eliminating the nitrogen of

  2. Search for proton emission in {sup 54}Ni and multi-nucleon transfer reactions in the actinide region

    Energy Technology Data Exchange (ETDEWEB)

    Geibel, Kerstin

    2012-06-15

    The first part of the thesis presents the investigation of fusion-evaporation reactions in order to verify one-proton emission from the isomeric 10{sup +} state in the proton rich nucleus {sup 54}Ni. Between the years 2006 and 2009 a series of experimental studies were performed at the Tandem accelerator in the Institut fuer Kernphysik (IKP), University of Cologne. These experiments used fusion-evaporation reactions to populate {sup 54}Ni via the two-neutron-evaporation channel of the compound nucleus {sup 56}Ni. The cross section for the population of the ground state of {sup 54}Ni was predicted to be in orders of microbarn. This required special care with respect to the sensitivity of the experimental setup, which consisted of a double-sided silicon-strip detector (DSSSD), a neutron-detector array and HPGe detectors. In two experiments the excitation functions of the reactions ({sup 32}S+{sup 24}Mg) and ({sup 28}Si+{sup 28}Si) were determined to find the optimal experimental conditions for the population of {sup 54}Ni. A final experiment employed a {sup 28}Si beam at an energy of 70 MeV, impinging on a {sup 28}Si target. With a complex analysis it is possible to obtain a background-free energy spectrum of the DSSSD. An upper cross section limit for the population of the 10{sup +} state in {sup 54}Ni is established at σ({sup 54}Ni(10{sup +})) ≤ (13.9 ± 7.8) nbarn. In the second part of the thesis the population of actinide nuclei by multi-nucleon transfer reactions is investigated. Two experiments, performed in 2007 and 2008 at the CLARA-PRISMA setup at the Laboratori Nazionali di Legnaro, are analyzed with respect to the target-like reaction products. In both experiments {sup 238}U was used as target. A {sup 70}Zn beam with 460 MeV and a {sup 136}Xe beam with 926 MeV, respectively, impinged on the target, inducing transfer reactions. Kinematic correlations between the reaction partners are used to obtain information on the unobserved target-like reaction

  3. NiCo2O4 spinel/ordered mesoporous carbons as noble-metal free electrocatalysts for oxygen reduction reaction and the influence of structure of catalyst support on the electrochemical activity of NiCo2O4

    Science.gov (United States)

    Bo, Xiangjie; Zhang, Yufan; Li, Mian; Nsabimana, Anaclet; Guo, Liping

    2015-08-01

    Three ordered mesoporous carbons (OMCs) with different structures are used as catalyst supports for growth of NiCo2O4 spinel. The high surface area of OMCs provides more active sites to adsorb metal precursors. The porous structure confines the growth of NiCo2O4 and supplies more efficient transport passage for reactant molecules to access the active sites. Due to the structural characteristics of OMCs and catalytic properties of NiCo2O4, NiCo2O4/OMCs composites are highly active, cheap, and selective noble metal-free electrocatalysts for the oxygen reduction reaction (ORR) in alkaline solution. The electrochemical activity of NiCo2O4 supported on three OMCs with different structures, surface areas, pore sizes, pore volumes, and defective sites is studied. NiCo2O4/OMCs composites may be further used as efficient and inexpensive noble metal-free ORR catalysts in alkaline solution.

  4. Isospin Diffusion in $^{58}$Ni-Induced Reactions at Intermediate Energies

    CERN Document Server

    Galichet, E; Borderie, B; Colonna, M; Bougault, R; Durand, D; Neindre, N Le; Lopez, O; Manduci, L; Vient, E; Chbihi, A; Frankland, J D; Wieleczko, J P; Dayras, R; Volant, C; Guinet, D C R; Lautesse, P; Parlog, M; Rosato, E; Vigilante, M

    2010-01-01

    Isospin diffusion is probed as a function of the dissipated energy by studying two systems $^{58}$Ni+$^{58}$Ni and $^{58}$Ni+$^{197}$Au, over the incident energy range 52-74\\AM. Experimental data are compared with the results of a microscopic transport model with two different parameterizations of the symmetry energy term. A better overall agreement between data and simulations is obtained when using a symmetry term with a potential part linearly increasing with nuclear density. The isospin equilibration time at 52 \\AM{} is estimated to 130$\\pm$10 fm/$c$.

  5. Study of thermal threshold and counter-measures for human body in oceanic working environment. 1st Report. Heat balance model and heat storage index; Shonetsu kankyoka no kaiyo sagyo ni okeru netsuteki genkai to onnetsu taisaku ni kansuru kenkyu. 1. Netsu shushi model to onnetsu shisu

    Energy Technology Data Exchange (ETDEWEB)

    Fukuchi, N. [Kyushu University, Fukuoka (Japan). Faculty of Engineering; Nakamura, M. [Tokyo Gakugei University, Tokyo (Japan); Murayama, M.

    1996-12-31

    Identification was intended on effects of such thermal factors as metabolic amount, environmental temperature and humidity, and clothing resistance on human body temperatures during works under hot environments. Therefore, measurements were carried out on human skin temperatures, rectum temperatures and humidity inside clothing, while amount of motion, environmental temperature, and clothing are changed in a constant temperature room and under a sun irradiation environment. Furthermore, a heat balance model was prepared, which divides the objects into an outer shell layer whose temperature changes depending on the result of this experiment and into a core having constant temperature characteristics. An equation to derive skin temperatures was introduced from the model. The equation formulated a calculation formula for heat accumulation in human body, which can be used as a hot heat index. Relationship between thermal factors and heat storage amount was investigated to consider a thermal limit for a physical work. An equation to derive skin temperatures was confirmed capable of expressing general change in skin temperatures, being proved by comparison with experiments. Calculation formulas for amount of heat stored in human body were shown capable of expressing influence of different thermal factors, the expression being useful as a hot heat index. Calculating the human body heat storage is very largely affected by effect of sweat to dissipate heat, hence it is necessary to improve the accuracy including that for body temperature adjusting reactions. 17 refs., 17 figs., 5 tabs.

  6. Effect of Ni+2-substituted Fe2TiO5 on the H2-reduction and CO2 Catalytic Decomposition Reactions at 500℃

    Institute of Scientific and Technical Information of China (English)

    M.H.Khedr

    2006-01-01

    CO2 is a major component of the greenhouse gases, which causes the global warming. To reduce CO2 gas,high activity nanosized Ni+2 substituted Fe2TiO5 samples were synthesized by conventional ceramic method.The effect of the composition of the synthesized ferrite on the H2-reduction and CO2-catalytic decomposition was investigated. Fe2TiO5 (iron titanate) phase that has a nanocrystallite size of ~80 nm is formed as a result of heating Fe2O3 and TiO2 while the addition of NiO leads to the formation of new phases (~80 nm)NiTiO3 and NiFe2O4, but the mixed solid of NiO and Fe2O3 results in the formation of NiFe2O4 only.Samples with Ni+2=0 shows the lowest reduction extent (20%); as the extent of Ni+2 increases, the extent of reduction increases. The increase in the reduction percent is attributed to the presence of NiTiO3 and NiFe2O4 phases, which are more reducible phases than Fe2TiO5. The CO2 decomposition reactions were monitored by thermogravimetric analysis (TGA) experiments. The oxidation of the H2-reduced Ni+2 substituted Fe2TiO5 at 500℃ was investigated. As Ni+2 increases, the rate of reoxidation increases. Samples with the highest reduction extents gave the highest reoxidation extent, which is attributed to the highly porous nature and deficiency in oxygen due to the presence of metallic Fe, Ni and/or FeNi alloy. X-ray diffraction (XRD) and transmission electron microscopy (TEM) of oxidized samples show also the presence of carbon in the sample containing Ni+2>0, which appears in the form of nanotubes (25 nm).

  7. Ni-CeO2/C Catalysts with Enhanced OSC for the WGS Reaction

    Directory of Open Access Journals (Sweden)

    Laura Pastor-Pérez

    2015-03-01

    Full Text Available In this work, the WGS performance of a conventional Ni/CeO2 bulk catalyst is compared to that of a carbon-supported Ni-CeO2 catalyst. The carbon-supported sample resulted to be much more active than the bulk one. The higher activity of the Ni-CeO2/C catalyst is associated to its oxygen storage capacity, a parameter that strongly influences the WGS behavior. The stability of the carbon-supported catalyst under realistic operation conditions is also a subject of this paper. In summary, our study represents an approach towards a new generation of Ni-ceria based catalyst for the pure hydrogen production via WGS. The dispersion of ceria nanoparticles on an activated carbon support drives to improved catalytic skills with a considerable reduction of the amount of ceria in the catalyst formulation.

  8. Exploring reaction mechanisms and their competition in 58Ni+48Ca collisions at E = 25 AMeV

    Directory of Open Access Journals (Sweden)

    Francalanza L.

    2014-03-01

    Full Text Available Latest results concerning the study of central collisions in 58Ni+48Ca reactions at Elab(Ni=25 AMeV are presented. The experimental data, collected with the CHIMERA 4π device, have been analyzed in order to investigate the competition among different reaction mechanisms for central collisions in the Fermi energy domain. The method adopted to perform the centrality selection refers to the global variable “flow angle”, that is related to the event shape in momentum space, as it is determined by the eigenvectors of the experimental kinetic-energy tensor. The main features of the reaction products were explored by using different constraints on some of the relevant observables, such as mass and velocity distributions and their correlations. Much emphasis was devoted to the competition between fusion-evaporation processes with subsequent identification of a heavy residue and a prompt multifragmentation mechanism. The reaction mechanism was simulated in the framework of transport theories (dynamical stochastic BNV calculations, followed by sequential SIMON code and further comparison with dynamical calculations from transport model (QMD, CoMD are in progress. Moreover, an extension of this study taking into account for the light particles has been envisaged.

  9. Exploring reaction mechanisms and their competition in 58Ni+48Ca collisions at E = 25 AMeV

    Science.gov (United States)

    Francalanza, L.; Abbondanno, U.; Amorini, F.; Barlini, S.; Bini, M.; Bougault, R.; Bruno, M.; Cardella, G.; Casini, G.; Colonna, M.; D'Agostino, M.; De Filippo, E.; De Sanctis, J.; Geraci, E.; Giussani, A.; Gramegna, F.; Guiot, B.; Kravchuk, V.; La Guidara, E.; Lanzalone, G.; Le Neindre, N.; Maiolino, C.; Marini, P.; Morelli, L.; Olmi, A.; Pagano, A.; Papa, M.; Piantelli, S.; Pirrone, S.; Politi, G.; Poggi, G.; Porto, F.; Russotto, P.; Rizzo, F.; Vannini, G.; Vannucci, L.

    2014-03-01

    Latest results concerning the study of central collisions in 58Ni+48Ca reactions at Elab(Ni)=25 AMeV are presented. The experimental data, collected with the CHIMERA 4π device, have been analyzed in order to investigate the competition among different reaction mechanisms for central collisions in the Fermi energy domain. The method adopted to perform the centrality selection refers to the global variable "flow angle", that is related to the event shape in momentum space, as it is determined by the eigenvectors of the experimental kinetic-energy tensor. The main features of the reaction products were explored by using different constraints on some of the relevant observables, such as mass and velocity distributions and their correlations. Much emphasis was devoted to the competition between fusion-evaporation processes with subsequent identification of a heavy residue and a prompt multifragmentation mechanism. The reaction mechanism was simulated in the framework of transport theories (dynamical stochastic BNV calculations, followed by sequential SIMON code) and further comparison with dynamical calculations from transport model (QMD, CoMD) are in progress. Moreover, an extension of this study taking into account for the light particles has been envisaged.

  10. NiFe layered double hydroxide/reduced graphene oxide nanohybrid as an efficient bifunctional electrocatalyst for oxygen evolution and reduction reactions

    Science.gov (United States)

    Zhan, Tianrong; Zhang, Yumei; Liu, Xiaolin; Lu, SiSi; Hou, Wanguo

    2016-11-01

    Highly active and low-cost bifunctional electrocatalysts for oxygen evolution and reduction reactions (OER and ORR) hold a heart position for the renewable energy technologies such as metal-air batteries and fuel cells. Here, we reported the synthesis of NiFe layered double hydroxide/reduced graphene oxide (NiFe-LDH/rGO) nanohybrid via the facile solvothermal method followed by chemical reduction. The template role of surfactant and the hybridization of rGO supplied the NiFe-LDH/rGO catalyst with a porous nanostructure and an enhanced conductivity, favoring both mass transport and charge communication of electrocatalytic reactions. The NiFe-LDH/rGO composite not only displayed highly efficient OER activity in alkaline solution with a low onset overpotential of 240 mV, but also only needed an overpotential of 250 mV to reach the 10 mA cm-2 current density. The NiFe-LDH/rGO nanohybrid also offered excellent ORR catalytic activity with onset potential at 0.796 V in alkaline media. The rotating-disk and rotating-ring-disk electrodes both revealed that the ORR on NiFe-LDH/rGO mainly involved a direct four-electron reaction pathways accompanying part of the two-electron process. The excellent bifunctional activity of the NiFe-LDH/rGO nanohybrid could be attributed to the synergistic effects of rGO and NiFe-LDH components due to the strongly coupled interactions.

  11. Mass-dependent and -independent fractionation of isotopes in Ni and Pb chelate complex formation reactions

    Energy Technology Data Exchange (ETDEWEB)

    Nomura, Masao; Kudo, Takashi; Adachi, Atsuhiko; Aida, Masao; Fujii, Yasuhiko [Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, O-okayama Meguroku, Tokyo, 152-8550 (Japan)

    2013-11-13

    Mass independent fractionation (MIF) has been a very interesting topic in the field of inorganic isotope chemistry, in particular, geo- and cosmo- chemistry. In the present work, we studied the isotope fractionation of Ni(II) and Pb(II) ions in complex formation with chelating reagent EDTA. To obtain clear results on the mass dependence of the isotope fractionation, we have conducted long-distance ion exchange chromatography of Ni(II) and Pb(II), using chelate complex reagent EDTA. The results apparently show that the isotope fractionation in Ni complex formation system is governed by the mass dependent rule. On the other hand the isotope fractionation in the Pb complex system is governed by the mass independent rule or the nuclear volume effect.

  12. Reaction diffusion in the NiCrAl and CoCrAl systems

    Science.gov (United States)

    Levine, S. R.

    1978-01-01

    The paper assesses the effect of overlay coating and substrate composition on the kinetics of coating depletion by interdiffusion. This is accomplished by examining the constitution, kinetics and activation energies for a series of diffusion couples primarily of the NiCrAl/Ni-10Cr or CoCrAl/Ni-10Cr type annealed at temperatures in the range 1000-1205 C for times up to 500 hr. A general procedure is developed for analyzing diffusion in multicomponent multiphase systems. It is shown that by introducing the concept of beta-source strength, which can be determined from appropriate phase diagrams, the Wagner solution for consumption of a second phase in a semiinfinite couple is successfully applied to the analysis of MCrAl couples. Thus, correlation of beta-recession rate constants with couple composition, total and diffusional activation energies, and interdiffusion coefficients are determined.

  13. Mass-dependent and -independent fractionation of isotopes in Ni and Pb chelate complex formation reactions

    Science.gov (United States)

    Nomura, Masao; Kudo, Takashi; Adachi, Atsuhiko; Aida, Masao; Fujii, Yasuhiko

    2013-11-01

    Mass independent fractionation (MIF) has been a very interesting topic in the field of inorganic isotope chemistry, in particular, geo- and cosmo- chemistry. In the present work, we studied the isotope fractionation of Ni(II) and Pb(II) ions in complex formation with chelating reagent EDTA. To obtain clear results on the mass dependence of the isotope fractionation, we have conducted long-distance ion exchange chromatography of Ni(II) and Pb(II), using chelate complex reagent EDTA. The results apparently show that the isotope fractionation in Ni complex formation system is governed by the mass dependent rule. On the other hand the isotope fractionation in the Pb complex system is governed by the mass independent rule or the nuclear volume effect.

  14. Size and morphology controlled NiSe nanoparticles as efficient catalyst for the reduction reactions

    Science.gov (United States)

    Subbarao, Udumula; Marakatti, Vijaykumar S.; Amshumali, Mungalimane K.; Loukya, B.; Singh, Dheeraj Kumar; Datta, Ranjan; Peter, Sebastian C.

    2016-12-01

    Facile and efficient ball milling and polyol methods were employed for the synthesis of nickel selenide (NiSe) nanoparticle. The particle size of the NiSe nanoparticle has been controlled mechanically by varying the ball size in the milling process. The role of the surfactants in the formation of various morphologies was studied. The compounds were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray energy dispersive spectroscopy (EDS). The efficiency of the NiSe nanoparticle as a catalyst was tested for the reduction of para-nitroaniline (PNA) to para-phenyldiamine (PPD) and para-nitrophenol (PNP) to para-aminophenol (PAP) using NaBH4 as the reducing agent. Particle size, morphology and the presence of surfactant played a crucial role in the reduction process.

  15. Reactions sup 58,64 Ni( p ,. pi. sup + ) at 201 MeV

    Energy Technology Data Exchange (ETDEWEB)

    Badala, A.; Barbera, R.; Palmeri, A.; Pappalardo, G.S.; Bonasera, A. (Istituto Nazionale di Fisica Nucleare, Corso Italia 57, 95129 Catania (Italy)); Riggi, F.; Adorno, A. (Istituto Nazionale di Fisica Nucleare and Dipartimento di Fisica dell' Universita di Catania, Corso Italia 57, 95129 Catania (Italy)); Bimbot, L. (Institut de Physique Nucleaire, Boite Postale 1, 91406 Orsay CEDEX (France))

    1992-08-01

    The production of positive and negative pions induced by 201 MeV protons on {sup 58}Ni and {sup 64}Ni isotopes has been studied. The double differential cross sections have been measured at the laboratory angles 22{degree}, 35{degree}, 55{degree}, 72{degree}, 90{degree}, 105{degree}, 120{degree}, 138{degree}, 155{degree} and from 20 MeV kinetic energy up to the kinematical limit. Features of the double differential cross sections relative to the two targets are discussed and compared to results obtained at higher incident energies.

  16. One-pot synthesis of hierarchical Ni2P/MoS2 hybrid electrocatalysts with enhanced activity for hydrogen evolution reaction

    Science.gov (United States)

    Liu, Yan-Ru; Hu, Wen-Hui; Li, Xiao; Dong, Bin; Shang, Xiao; Han, Guan-Qun; Chai, Yong-Ming; Liu, Yun-Qi; Liu, Chen-Guang

    2016-10-01

    A simple one-pot synthesis method has been used to fabricate novel Ni2P/MoS2 hybrid electrocatalysts for hydrogen evolution reaction (HER). Owing to the weak conductivity and layered structure of MoS2, Ni2P nanoparticles with excellent conductivity and activity have been doped into MoS2 for improving the electrocatalytic performances for HER. The structure and morphology of the as-prepared Ni2P/MoS2 hybrid nanostructures are characterized. XRD and XPS show the elemental composition and valence of Ni2P/MoS2. SEM and TEM confirm that the close interaction of the hybrid materials and good dispersion of Ni2P nanoparticles. The as-synthesized Ni2P/MoS2 hybrid electrocatalysts exhibit excellent activity with onset overpotential of 75 mV and Tafle slope of 76 mV dec-1, which are much better than that of pure MoS2. The enhanced stability of the as-prepared Ni2P/MoS2 for HER has also been observed. The improved performances for HER may be ascribed to the better conductivity and dispersion of MoS2 nanosheets in Ni2P/MoS2 hybrid electrocatalysts. The small size and good dispersion of Ni2P nanoparticles also contributed to the enhancement of HER activity. Compared with mechanically mixed MoS2 and Ni2P (Ni2P-MoS2), Ni2P/MoS2 hybrid materials demonstrate better electrochemical performances for HER, implying the existence of synergistic effect between Ni2P and MoS2 on HER activity.

  17. Reactions of Ni-B on printed Ag pattern by using nearly neutral electroless bath.

    Science.gov (United States)

    Rha, Sa-Kyun; Kim, Hyung Chul; Lee, Youn-Seoung

    2014-11-01

    In this study, we investigated the characteristics of a nearly neutral Ni source solution including dimethylamine borane (DMAB) used to develop the metal PCB (printed circuit board) of high power LED (light-emitting diode) package. In accordance with the bath temperature ranging from 50 degrees C to 75 degrees C, an electroless Ni-B plating on a screen-printed Ag pattern with an anodized Al substrate was carried out. The depositon rate of the electroless plated Ni-B film at bath temperature ranging from 50 degrees C to 75 degrees C was estimated by measurements of the thickness and the mass. The deposition rates by change of thickness and mass of the electroless plated Ni-B film at 50 degrees C were - 58 nm/min and 0.113 mg/min respectively. The activation energy obtained from slope of Arrhenius plot using these deposition rates was - 59 kJ/mol. Finally, selectively the film growth was achieved at all plating temperatures, without a damage of anodized Al substrate.

  18. Molecular Dynamics Simulation of the Kinetic Reaction of Ni and Al Nanoparticles

    Science.gov (United States)

    2008-12-01

    of formation of the Ni– Al intermetallic compounds”, Journal of Alloys and Compounds , 364, 121–126, 2004. Delogu, F. “Numerical simulation of the...formation of NiAl”, Journal of Alloys and Compounds , 321, 228–231, 2001. Nizhenko, V. I. “Free Surface Energy as a Criterion for the Sequence of

  19. [NiFe]-hydrogenases: spectroscopic and electrochemical definition of reactions and intermediates.

    NARCIS (Netherlands)

    F.A. Armstrong; S.P.J. Albracht

    2005-01-01

    Production and usage of di-hydrogen, H2, in micro-organisms is catalysed by highly active, 'ancient' metalloenzymes known as hydrogenases. Based on the number and identity of metal atoms in their active sites, hydrogenases fall into three main classes, [NiFe]-, [FeFe]- and [Fe]-. All contain the unu

  20. Study on the time-domain electromagnetic responses; TDEM ho ni okeru denji oto ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Noguchi, K.; Endo, M. [Waseda University, Tokyo (Japan). School of Science and Engineering

    1997-05-27

    With an objective to perform three-dimensional analysis with high accuracy in using the electromagnetic exploration method, characteristics in electromagnetic response were analyzed, and conditions for acquiring necessary data were discussed. The discussion defined a parameter called `response anomaly` which uses response from media to standardize response only from substances with abnormal resistivity. The receivers were located uniformly on the same plane, and the response anomaly was derived from electromagnetic response from each of the three horizontal and vertical components at each receiving point, which was expressed as a contour map. The parameter for the abnormal body was consisted of location and resistivity contrast with media. Discussions using the contour map were given on the response when these factors for the parameter were varied. As a result, it was found that the response anomaly appears in the form that reflects the abnormal body, and the response anomaly of the horizontal component is superior in terms of being large. It was also referred that, as a requirement for the abnormal body which gives larger impact from the electromagnetic response, the abnormal body should have lower resistivity than that in the media, and resistivity contrast with the media should be greater. 2 refs., 7 figs., 1 tab.

  1. Noise characterization in SWD survey; SWD ni okeru noise ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Tsuru, T.; Ozawa, T. [Japan National Oil Corp., Tokyo (Japan)

    1998-02-01

    SWD (Seismic While Drilling) is located as one kind of the reverse VSP (Vertical Seismic Profiling) technology, and a working drill-bit is used as its energy-source. The SWD is carried out for a check-shot survey as well as a prediction ahead of the bit. The largest advantage of the SWD technology may be a prediction, while drilling, of a drilling hazard such as an abnormal pressure zone. On the other hand, a serious disadvantage exists in the data quality due to a contamination by large noises generated from a working rig, because the SWD survey is done `while drilling`. Regarding the characteristics of these noises, especially the noise received by surface geophones has not been clarified quantitatively yet. Through several field experiments, the authors have evaluated the characteristics. In this paper, the dominant frequency range of the surface geophone noise is discussed. Furthermore, the noise from the mud motor is also discussed. 9 refs., 13 figs.

  2. Robotics in port construction. Kowan kensetsu ni okeru roboto ka gijutsu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Sakai, Hiroshi (Ministry of Transport, Tokyo (Japan))

    1990-02-15

    To cope positively with the problems of securing labor, improving work environment, etc., mechanization and robotics in port and marine development are the urgent subjects. Technologies for robotics of various levels are being developed, coverning data acquisition, processing, display, recording simple automation, and high inteligent fuction which can automatically make such judgement as having been done by man. Some representative cases of technological development in the fields of robotics and mechnization being carried on by the Ports and Harbors Bureau in the Ministry of Transportaion are introduced. Technological develpment required for the mechanization of rubble mound foundation construction work has been carried on. A demonstration test was carried out at Kamaishi Port, proving the practicability of the technology. Robots are developed which can walk on the sea bottom to perform underwater investigation and unmanned operation. Underwater visual device and underwater position measurement device are provided as the supporing systems. Several tests were already performed in actual sea areas and the success of the development was verified. 3 figs.

  3. Interfacial reactions and compound formation of Sn-Ag-Cu solders by mechanical alloying on electroless Ni-P/Cu under bump metallization

    Science.gov (United States)

    Kao, Szu-Tsung; Duh, Jenq-Gong

    2005-08-01

    Electroless Ni-P under bump metallization (UBM) has been widely used in electronic interconnections due to the good diffusion barrier between Cu and solder. In this study, the mechanical alloying (MA) process was applied to produce the SnAgCu lead-free solder pastes. Solder joints after annealing at 240°C for 15 min were employed to investigate the evolution of interfacial reaction between electroless Ni-P/Cu UBM and SnAgCu solder with various Cu concentrations ranging from 0.2 to 1.0 wt.%. After detailed quantitative analysis with an electron probe microanalyzer, the effect of Cu content on the formation of intermetallic compounds (IMCs) at SnAgCu solder/electroless Ni-P interface was evaluated. When the Cu concentration in the solder was 0.2 wt.%, only one (Ni, Cu)3Sn4 layer was observed at the solder/electroless Ni-P interface. As the Cu content increased to 0.5 wt.%, (Cu, Ni)6Sn5 formed along with (Ni, Cu)3Sn4. However, only one (Cu, Ni)6Sn5 layer was revealed, if the Cu content was up to 1 wt.%. With the aid of microstructure evolution, quantitative analysis, and elemental distribution by x-ray color mapping, the presence of the Ni-Sn-P phase and P-rich layer was evidenced.

  4. Asymmetric pathways in the electrochemical conversion reaction of NiO as battery electrode with high storage capacity

    Science.gov (United States)

    Boesenberg, Ulrike; Marcus, Matthew A.; Shukla, Alpesh K.; Yi, Tanghong; McDermott, Eamon; Teh, Pei Fen; Srinivasan, Madhavi; Moewes, Alexander; Cabana, Jordi

    2014-11-01

    Electrochemical conversion reactions of transition metal compounds create opportunities for large energy storage capabilities exceeding modern Li-ion batteries. However, for practical electrodes to be envisaged, a detailed understanding of their mechanisms is needed, especially vis-à-vis the voltage hysteresis observed between reduction and oxidation. Here, we present such insight at scales from local atomic arrangements to whole electrodes. NiO was chosen as a simple model system. The most important finding is that the voltage hysteresis has its origin in the differing chemical pathways during reduction and oxidation. This asymmetry is enabled by the presence of small metallic clusters and, thus, is likely to apply to other transition metal oxide systems. The presence of nanoparticles also influences the electrochemical activity of the electrolyte and its degradation products and can create differences in transport properties within an electrode, resulting in localized reactions around converted domains that lead to compositional inhomogeneities at the microscale.

  5. Direct and compound-nucleus reaction mechanisms in the 7Be+58Ni system at near-barrier energies

    Science.gov (United States)

    Mazzocco, M.; Torresi, D.; Pierroutsakou, D.; Keeley, N.; Acosta, L.; Boiano, A.; Boiano, C.; Glodariu, T.; Guglielmetti, A.; La Commara, M.; Lay, J. A.; Martel, I.; Mazzocchi, C.; Molini, P.; Parascandolo, C.; Pakou, A.; Parkar, V. V.; Romoli, M.; Rusek, K.; Sánchez-Benítez, A. M.; Sandoli, M.; Sgouros, O.; Signorini, C.; Silvestri, R.; Soramel, F.; Soukeras, V.; Stiliaris, E.; Strano, E.; Stroe, L.; Zerva, K.

    2015-08-01

    The energy and angular distributions of 3He and 4He ions produced in the 7Be +58Ni reaction at a bombarding energy of 22 MeV have been measured for the first time. The yield of the heavier helium isotope was four to five times more abundant than that of its lighter counterpart, ruling out the possibility that in this energy range the 7Be reaction dynamics is dominated by the exclusive breakup process 7Be→3He +4He (Sα=1.586 MeV). Extensive kinematic and theoretical calculations suggest that the 3He ions mostly originate from the 4He-stripping process and the 4He production is mainly triggered by the fusion-evaporation channel. The role played by the breakup, 3He-stripping, 1 n -stripping, and 1 n -pickup processes is also discussed.

  6. Asymmetric pathways in the electrochemical conversion reaction of NiO as battery electrode with high storage capacity.

    Science.gov (United States)

    Boesenberg, Ulrike; Marcus, Matthew A; Shukla, Alpesh K; Yi, Tanghong; McDermott, Eamon; Teh, Pei Fen; Srinivasan, Madhavi; Moewes, Alexander; Cabana, Jordi

    2014-11-20

    Electrochemical conversion reactions of transition metal compounds create opportunities for large energy storage capabilities exceeding modern Li-ion batteries. However, for practical electrodes to be envisaged, a detailed understanding of their mechanisms is needed, especially vis-à-vis the voltage hysteresis observed between reduction and oxidation. Here, we present such insight at scales from local atomic arrangements to whole electrodes. NiO was chosen as a simple model system. The most important finding is that the voltage hysteresis has its origin in the differing chemical pathways during reduction and oxidation. This asymmetry is enabled by the presence of small metallic clusters and, thus, is likely to apply to other transition metal oxide systems. The presence of nanoparticles also influences the electrochemical activity of the electrolyte and its degradation products and can create differences in transport properties within an electrode, resulting in localized reactions around converted domains that lead to compositional inhomogeneities at the microscale.

  7. Preparation of the Ni/NiCo2O4 Composite Electrode and Its Properties toward the Oxygen Evolution Reaction in Alkaline Media%Ni/NiCo2O4复合电极的制备及其在碱性介质中的析氧性能

    Institute of Scientific and Technical Information of China (English)

    鲍晋珍; 王森林

    2011-01-01

    采用共沉淀法制备尖晶石型复合氧化物NiCo2O4,然后将其加入瓦特镀镍液中,复合电沉积了Ni/NiCo2O4复合镀层.通过改变镀液pH值、阴极电流密度jk等条件,探索复合电沉积的最佳工艺条件.运用扫描电子显微镜(SEM)、能谱分析(EDS)和X射线衍射(XRD)表征了复合镀层的表面形貌、颗粒含量和结构.结果表明:在镀液pH=6.2 和jk=100 mA·cm-2的条件下所得Ni/NiCo2O4复合镀层中,NiCo2O4的含量达到最高(30.6%,w).在5 mol·L-1的KOH溶液中,采用循环伏安、稳态极化和电化学阻抗法研究了电极的电催化析氧性能.与镍电极对比,Ni/NiCo2O4复合电极的电催化析氧性能更高,表观活化自由能降低了53.2 kJ·mol-1,其析氧反应的表观交换电流密度是镍电极的7倍.电化学阻抗谱分析表明,Ni/NiCo2O4复合电极在碱性溶液中析氧反应由电化学步骤和扩散步骤联合控制.恒电位长时间电解析氧实验表明,该Ni/NiCo2O4复合电极在碱性溶液中的析氧具有高的稳定性.%A NiCo2O4 spinel composite oxide was obtained by co-precipitation. A Ni/NiCo204 composite coating was prepared by composite electrodeposition in a Ni plating solution by mixing with NiCo2O4 powder. The best plating conditions for the composite electrodeposition were investigated by changing factors such as the plating bath pH and the cathode current density >. The surface morphology, the NiCo2O4 content, and the structure of the Ni/NiCo2O4 composite coating were characterized by scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), and X-ray diffraction (XRD). As a result, the NiCo2O4 content in the Ni/NiCo204 composite coating was found to be the highest (30.6%, w) for a bath pH of 6.2 and a cathodic current density jk of 100 mA ? Cm2. In 5 mol ? L-1 KOH solution the electrocatalytic properties toward the oxygen evolution reaction (OER) of the Ni/NiCo2O4 composite electrode was studied using cyclic voltammetry

  8. Functional MoS2 by the Co/Ni doping as the catalyst for oxygen reduction reaction

    Science.gov (United States)

    Xiao, B. B.; Zhang, P.; Han, L. P.; Wen, Z.

    2015-11-01

    Since the discovery of the oxygen reduction reaction (ORR) activity of the metal phthalocyanine, the great enthusiasm is ignited for searching the catalysts with low price replacing Pt-based catalysts. Here, the catalytic activities for the ORR on the Co or Ni doped MoS2 are studied by using density-functional theory (DFT). It is found that Co/MoS2 resembles FeN4 active site while Ni/MoS2 is similar with CoN4 active site. In details, for Co/MoS2, under the acid medium, the rate-determining step (RDS) is located at the second H2O formation with a barrier of 1.49 eV. While under the alkaline medium, RDS is the final OH- formation with the barrier of 0.94 eV. For Ni/MoS2, under the acid medium, the RDS is the same as that of Co/MoS2 with a barrier of 0.87 eV. However, RDS is the O formation with the barrier of 0.92 eV under the alkaline medium. Furthermore, due to the intact HOOH adsorption, it is expected that the 2e- ORR is present on Ni/MoS2, which means inferior activity compared with Co/MoS2. Our calculation demonstrates the ability to functionalize inert materials for the ORR and provides new materials to design effective Pt-free catalysts for fuel-cell technology.

  9. Fission and quasifission of composite systems with Z =108 -120 : Transition from heavy-ion reactions involving S and Ca to Ti and Ni ions

    Science.gov (United States)

    Kozulin, E. M.; Knyazheva, G. N.; Novikov, K. V.; Itkis, I. M.; Itkis, M. G.; Dmitriev, S. N.; Oganessian, Yu. Ts.; Bogachev, A. A.; Kozulina, N. I.; Harca, I.; Trzaska, W. H.; Ghosh, T. K.

    2016-11-01

    Background: Suppression of compound nucleus formation in the reactions with heavy ions by a quasifission process in dependence on the reaction entrance channel. Purpose: Investigation of fission and quasifission processes in the reactions 36S,48Ca,48Ti , and 64Ni+238U at energies around the Coulomb barrier. Methods: Mass-energy distributions of fissionlike fragments formed in the reaction 48Ti+238U at energies of 247, 258, and 271 MeV have been measured using the double-arm time-of-flight spectrometer CORSET at the U400 cyclotron of the Flerov Laboratory of Nuclear Reactions and compared with mass-energy distributions for the reactions 36S,48Ca,64Ni+238U . Results: The most probable fragment masses as well as total kinetic energies and their dispersions in dependence on the interaction energies have been investigated for asymmetric and symmetric fragments for the studied reactions. The fusion probabilities have been deduced from the analysis of mass-energy distributions. Conclusion: The estimated fusion probability for the reactions S, Ca, Ti, and Ni ions with actinide nuclei shows that it depends exponentially on the mean fissility parameter of the system. For the reactions with actinide nuclei leading to the formation of superheavy elements the fusion probabilities are of several orders of magnitude higher than in the case of cold fusion reactions.

  10. Unusual Physical and Chemical Properties of Ni in Ce1-xNixO2-y Oxides: Structural Characterization and Catalytic Activity for the Water Gas Shift Reaction

    Energy Technology Data Exchange (ETDEWEB)

    Barrio, L.; Kubacka, A; Zhou, G; Estrella, M; Martinez-Arias, A; Hanson, J; Fernandez-Garcia, M; Rodriguez, J

    2010-01-01

    The structural and electronic properties of Ce{sub 1-x}Ni{sub x}O{sub 2-y} nanosystems prepared by a reverse microemulsion method were characterized with synchrotron-based X-ray diffraction, X-ray absorption spectroscopy, Raman spectroscopy, and density functional calculations. The Ce{sub 1-x}Ni{sub x}O{sub 2-y} systems adopt a lattice with a fluorite-type structure with an acute local order where Ni displays a strongly distorted (oxygen) nearest-neighbor coordination and the presence of Ni atoms as first cation distances, pointing to the existence of Ni-O-Ni entities embedded into the ceria lattice. A Ni {leftrightarrow} Ce exchange within the CeO{sub 2} leads to a charge redistribution and the appearance of O vacancies. The Ni-O bonds in Ce{sub 1-x}Ni{sub x}O{sub 2-y} are more difficult to reduce than the bonds in pure NiO. The specific structural configuration of Ni inside the mixed-metal oxide leads to a unique catalyst with a high activity for the water gas shift (CO + H{sub 2}O {yields} H{sub 2} + CO{sub 2}) reaction and a simultaneous reduction of the methanation activity of nickel. Characterization results indicate that small particles of metallic Ni at the interface position of a ceria network may be the key for high WGS activity and that the formate-carbonate route is operative for the production of hydrogen.

  11. Unusual Physical and Chemical Properties of Ni in Ce1-xNixO2-y Oxides: Structural Characterization and Catalytic Activity for the Water Gas Shift Reaction

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, J.A.; Barrio, L.; Kubacka, A.; Zhou, G.; Estrella, M.; Mart& #305; nez-Arias, A.; Hanson, J.C.; Fernandez-Garc& #305; a, M.

    2010-07-29

    The structural and electronic properties of Ce{sub 1-x}Ni{sub x}O{sub 2-y} nanosystems prepared by a reverse microemulsion method were characterized with synchrotron-based X-ray diffraction, X-ray absorption spectroscopy, Raman spectroscopy, and density functional calculations. The Ce{sub 1-x}Ni{sub x}O{sub 2-y} systems adopt a lattice with a fluorite-type structure with an acute local order where Ni displays a strongly distorted (oxygen) nearest-neighbor coordination and the presence of Ni atoms as first cation distances, pointing to the existence of Ni-O-Ni entities embedded into the ceria lattice. A Ni {leftrightarrow} Ce exchange within the CeO{sub 2} leads to a charge redistribution and the appearance of O vacancies. The Ni?O bonds in Ce{sub 1-x}Ni{sub x}O{sub 2-y} are more difficult to reduce than the bonds in pure NiO. The specific structural configuration of Ni inside the mixed-metal oxide leads to a unique catalyst with a high activity for the water gas shift (CO + H{sub 2}O {yields} H{sub 2} + CO{sub 2}) reaction and a simultaneous reduction of the methanation activity of nickel. Characterization results indicate that small particles of metallic Ni at the interface position of a ceria network may be the key for high WGS activity and that the formate?carbonate route is operative for the production of hydrogen.

  12. Reversible hydrogen storage in the Ni-rich pseudo-binary Mg{sub 6}Pd{sub 0.25}Ni{sub 0.75} intermetallic compound: Reaction pathway, thermodynamic and kinetic properties

    Energy Technology Data Exchange (ETDEWEB)

    Ponthieu, M. [Dpto. Fisica de Materiales, Facultad de Ciencias, Universidad Autonoma de Madrid, 28049 Madrid (Spain); ICMPE/CNRS-UPEC UMR 7182, 2-8 rue Henri Dunant, 94320 Thiais (France); Fernandez, J.F., E-mail: josefrancisco.fernandez@uam.es [Dpto. Fisica de Materiales, Facultad de Ciencias, Universidad Autonoma de Madrid, 28049 Madrid (Spain); Cuevas, F. [ICMPE/CNRS-UPEC UMR 7182, 2-8 rue Henri Dunant, 94320 Thiais (France); Ares, J.R.; Leardini, F.; Bodega, J.; Sanchez, C. [Dpto. Fisica de Materiales, Facultad de Ciencias, Universidad Autonoma de Madrid, 28049 Madrid (Spain)

    2013-01-25

    Highlights: Black-Right-Pointing-Pointer Mg{sub 6.2}Pd{sub 0.25}Ni{sub 0.65} reversibly absorbs 5.6 wt.% H in a two plateau pressure PCI. Black-Right-Pointing-Pointer The ternary phase depletes in Mg and Ni at low hydrogen pressure to form Mg{sub 2}Ni. Black-Right-Pointing-Pointer Reaction pathway of hydrogenation has been determined. Black-Right-Pointing-Pointer Enthalpy of the high pressure plateau is less negative than the one of pure Mg. Black-Right-Pointing-Pointer Low activation energy for desorption has been found for highly hydrided material. - Abstract: To improve the hydrogen storage properties of Mg{sub 6}Pd and to reduce its cost, Pd has been partly substituted by Ni at the solubility limit of the Mg{sub 6}(Pd,Ni) {rho}-phase. The attained composition is Mg{sub 6.2}Pd{sub 0.25}Ni{sub 0.65} as determined by Energy Dispersive X-Ray (EDX) and X-Ray Diffraction (XRD). Hydrogenation of this compound has been investigated by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM-EDX), Pressure-Composition-Isotherms (PCI) and thermal desorption analysis. On absorption, it decomposes in two steps as evidenced by two distinct plateau pressures. At low pressure, a partial segregation of Mg and Ni out of the pseudo-binary Mg{sub 6.2}Pd{sub 0.25}Ni{sub 0.65} {rho}-phase occurs leading to the formation of MgH{sub 2}, Mg{sub 2}Ni and Mg{sub 6}Pd{sub 0.7}Ni{sub 0.3} phases. At high pressure, the Mg{sub 6}Pd{sub 0.7}Ni{sub 0.3} phase disproportionates into MgH{sub 2}, Mg{sub 2}NiH{sub 4}, MgPd and Mg{sub 5}Pd{sub 2} phases. The hydrogenation reaction is reversible providing a hydrogen capacity of 5.6 wt.% H. The reaction enthalpy of the high pressure plateau is less negative than for pure Mg. Furthermore, the activation energy for H-desorption exhibits a dramatic decrease for hydrogen contents above 4 wt.% H, i.e. after the alloy disproportionation.

  13. 通过镍(II)-硫键和碘离子基元反应有理合成碘-二硫醇盐桥联的双核镍-镍配合物%Rational preparation of iodide-dithiolate-bridged binuclear Ni-Ni complex from the reaction between nickel(II)-sulfur bond and iodide moiety

    Institute of Scientific and Technical Information of China (English)

    王强; 安德鲁·马; 朱文锋; 亚力山大·布雷克; 克莱尔·威尔森; 斯蒂芬·戴维斯; 马丁·施罗德

    2008-01-01

    The reaction between Fe(CO)412 and Ni(SR)2(dppe) affords NiI2(dppe) due to the necleophilic attack of iodide on the labile N-S(aryl thiolate) bonds.The iodide-dithiolate-bridged binuclear Ni-Ni complexes[(dppe)Ni(μ-I)(μ-pdt)Ni(dppe)]I and[(dppe)Ni(μ-I)(μ-edt)Ni(dppe)]I can be readily prepared by reaction between[NiI2(dppe)]and[Ni(pdt)(dppe)] or[Ni(edt)(dppe)][dppe=1,2-bis (diphenyl phosphino)-ethane;pdt=1,3-propane-dithiolate;edt=1,2-ethane-dithiolate]in CH2C12 as a result of the attack on the Ni-I bond by the lone pairs of electrons on thiolato sulfur donors.On the other hand,the reaction between[FeCp(CO)2I] and [Ni(pdt)(dppe)] or[Ni(edt)(dppe)]in CH2C12 processes extremely slow.However, upon the metathesis with NH4PF6 for these reaction,the iodide-thiolate-bridged binuclear Ni-Ni complexes [(dppe)Ni(μ-I)(μ-pdt)Ni(dppe)]PF6 and [(dppe)Ni(μ-I)(μ-edt)Ni(dppe)]PF6 have been prepared due to the reaction of iodide and the Ni(II)-S bonds.These results suggest that the reactivity of Ni-SR bonds in such Ni-thiolate-phosphine complexes is tuneable with regard to the second metal ion and the different reactivity of iodide moiety.%本文报道由于碘离子对不稳定的Ni(II)-S(芳基硫醇盐)键的亲核作用,使得Fe(CO)412和Ni(SR)2(dppe(SR=芳基硫醇盐)之间的反应生成NiI2(dppe).含碘和二芳基硫醇盐离子桥联的Ni-Ni双核配合物[(dppe)Ni(μ-I)(μ-pdt)Ni(dppe)]I和[(dppe)Ni(μ-I)(μ-edt)Ni(dppe)]I可方便地由[NiI2(dppe)]和[Ni(pdt)(dppe)]或[Ni(edt)(dppe)]在二氯甲烷的溶液中的反应制得;该类反应可认为是由于硫醇盐离子基团中S-供体上的孤对电子对Ni-I键的进攻所致.另一方面,我们观察到[FeCp(CO)2I]和[Ni(pdt)(dppe)]或[Ni(edt)(dppe)]在二氯甲烷中的反应极其缓慢;但当向上述反应体系中加入NH4PF6进行复分解置换后,源于碘离子和Ni(II)-S键的作用同样可得到含碘与二芳基硫醇盐离子桥联的Ni-Ni双核配合物[(dppe)Ni(μ-I)(μ-pdt)Ni(dppe)]PF6

  14. Au-NiCo2O4 supported on three-dimensional hierarchical porous graphene-like material for highly effective oxygen evolution reaction

    Science.gov (United States)

    Xia, Wei-Yan; Li, Nan; Li, Qing-Yu; Ye, Kai-Hang; Xu, Chang-Wei

    2016-03-01

    A three-dimensional hierarchical porous graphene-like (3D HPG) material was synthesized by a one-step ion-exchange/activation combination method using a cheap metal ion exchanged resin as carbon precursor. The 3D HPG material as support for Au-NiCo2O4 gives good activity and stability for oxygen evolution reaction (OER). The 3D HPG material is induced into NiCo2O4 as conductive support to increase the specific area and improve the poor conductivity of NiCo2O4. The activity of and stability of NiCo2O4 significantly are enhanced by a small amount of Au for OER. Au is a highly electronegative metal and acts as an electron adsorbate, which is believed to facilitate to generate and stabilize Co4+ and Ni3+ cations as the active centres for the OER.

  15. Self-assembly growth of alloyed NiPt nanocrystals with holothuria-like shape for oxygen evolution reaction with enhanced catalytic activity

    Directory of Open Access Journals (Sweden)

    Tao Ding

    2016-01-01

    Full Text Available Self-assembly growth of alloyed NiPt nanocrystals with holothuria-like wire shape has been achieved via a facile and moderate hydrothermal process at 120 °C for 1 h from the reaction of nickel nitrate and chloroplatinic acid in alkaline solution in the presence of ethanediamine and hydrazine hydrate. The holothuria-like alloyed NiPt wires are Ni-rich in composition (Ni23.6Pt and uniform in diameter with many tiny tips outstretched from the wires surface. The holothuria-like wires are assembled from granular subunits with the assistance of capping molecular of ethanediamine and the wires display an improved oxygen evolution reaction catalytic activity.

  16. Neutron Capture Reactions on Fe and Ni Isotopes for the Astrophysical s-process

    CERN Document Server

    Lederer, C; Massimi, C; Žugec, P; Barbagallo, M; Colonna, N; Domingo-Pardo, C; Guerrero, C; Gunsing, F; Käppeler, F; Tain, J L; Altstadt, S; Andrzejewski, J; Audouin, L; Bécares, V; Bečvář, F; Belloni, F; Berthoumieux, E; Billowes, J; Boccone, V; Bosnar, D; Brugger, M; Calviani, M; Calviño, F; Cano-Ott, D; Carrapiço, C; Cerutti, F; Chiaveri, E; Chin, M; Cortés, G; Cortés-Giraldo, M A; Diakaki, M; Duran, I; Dressler, R; Dzysiuk, N; Eleftheriadis, C; Ferrari, A; Fraval, K; Ganesan, S; García, A R; Gómez-Hornillos, M B; Gonçalves, I F; González-Romero, E; Griesmayer, E; Gurusamy, P; Jenkins, D G; Jericha, E; Kadi, Y; Karadimos, D; Kivel, N; Koehler, P; Kokkoris, M; Korschinek, G; Krtička, M; Kroll, J; Langer, C; Leeb, H; Leong, L S; Losito, R; Manousos, A; Marganiec, J; Martínez, T; Mastinu, P F; Mastromarco, M; Meaze, M; Mendoza, E; Mengoni, A; Milazzo, P M; Mingrone, F; Mirea, M; Mondelaers, W; Paradela, C; Pavlik, A; Perkowski, J; Pignatari, M; Plompen, A; Praena, J; Quesada, J M; Rauscher, T; Reifarth, R; Riego, A; Roman, F; Rubbia, C; Sarmento, R; Schillebeeckx, P; Schmidt, S; Schumann, D; Tagliente, G; Tarrío, D; Tassan-Got, L; Tsinganis, A; Valenta, S; Vannini, G; Variale, V; Vaz, P; Ventura, A; Versaci, R; Vermeulen, M J; Vlachoudis, V; Vlastou, R; Wallner, A; Ware, T; Weigand, M; Weiß, C; Wright, T J

    2014-01-01

    Neutron capture cross sections in the keV neutron energy region are the key nuclear physics input to study the astrophysical slow neutron capture process. In the past years, a series of neutron capture cross section measurements has been performed at the neutron time-of-flight facility n\\_TOF at CERN focussing on the Fe/Ni mass region. Recent results and future developments in the neutron time-of-flight technique are discussed.

  17. New insights into the effects of alloying Pt with Ni on oxygen reduction reaction mechanisms in acid medium: a first-principles study.

    Science.gov (United States)

    Ou, Li-Hui

    2015-11-01

    The effects of alloying Pt with transition metal Ni on oxygen reduction reaction (ORR) mechanisms was investigated based on a systematic density functional theory (DFT) calculation explored in the present work. New insights into the ORR mechanisms were reported at the atomic level on Pt-segregated Pt3Ni(111). Only one molecular chemisorption state with the end-on OOH configuration was identified through geometry optimization and minimum energy path (MEP) analysis; top-bridge-top configuration as observed on pure Pt(111) was not identified on Pt-segregated Pt3Ni(111), indicating that alloying Pt with Ni influences the intermediates of ORR, and leads to only the dissociation mechanism of chemisorption state OOH species being involved in acid medium on Pt-segregated Pt3Ni(111). By contrast, the dissociation mechanisms of chemisorbed O2 molecule with top-bridge-top configuration and OOH species both were involved on pure Pt(111). The rds of the entire four-electron ORR was changed after Pt alloying with Ni. The rds of the entire ORR is the proton and electron transfer to O2 to form OOH on Pt-segregated Pt3Ni(111), whereas it is the reaction of O atom protonation to form OH species on pure Pt(111), indicating that sublayer Ni strongly influences the rds of ORR. The comparison of the ORR mechanisms explained that Pt3Ni alloy enhanced the ORR electrocatalytic activity more than pure Pt. The effect of electrode potential on ORR pathway on the pure Pt and Pt3Ni alloy was considered to obtain further insights into the electrochemical reduction of O2. Results showed that the proton and electron transfer becomes difficult at high potential. The ORR can easily proceed when the electrode potential lowers. For pure Pt- and Pt-based alloys, this phenomenon may imply the origin of the overpotential.

  18. Au-NiCo2O4 supported on three-dimensional hierarchical porous graphene-like material for highly effective oxygen evolution reaction

    OpenAIRE

    Wei-Yan Xia; Nan Li; Qing-Yu Li; Kai-Hang Ye; Chang-Wei Xu

    2016-01-01

    A three-dimensional hierarchical porous graphene-like (3D HPG) material was synthesized by a one-step ion-exchange/activation combination method using a cheap metal ion exchanged resin as carbon precursor. The 3D HPG material as support for Au-NiCo2O4 gives good activity and stability for oxygen evolution reaction (OER). The 3D HPG material is induced into NiCo2O4 as conductive support to increase the specific area and improve the poor conductivity of NiCo2O4. The activity of and stability of...

  19. Ni-Cu Hydrotalcite-Derived Mixed Oxides as Highly Selective and Stable Catalysts for the Synthesis of β-Branched Bioalcohols by the Guerbet Reaction.

    Science.gov (United States)

    Hernández, Willinton Y; De Vlieger, Kevin; Van Der Voort, Pascal; Verberckmoes, An

    2016-11-23

    A series of Ni-Cu hydrotalcite-derived mixed oxides have been synthesized and evaluated as heterogeneous catalysts for the dimerization of linear aliphatic alcohols to afford β-branched Guerbet alcohols. The use of the hydrotalcite-structured catalyst precursor highly favors the catalyst stability. This Cu/Ni catalyst has an enhanced reducibility of Ni(2+) species under reaction conditions, favoring the hydrogen transfer and hydrogenation capacity of the catalyst system. Catalytic results are reported for C8 , mixed C8 /C10 , and C18 alcohol feeds, with full conversions and Guerbet product purities of 72.5-96 %.

  20. Characterization of nanostructured photosensitive (NiS){sub x}(CdS){sub (1-x)} composite thin films grown by successive ionic layer adsorption and reaction (SILAR) route

    Energy Technology Data Exchange (ETDEWEB)

    Ubale, A.U., E-mail: ashokuu@yahoo.com [Nanostructured Thin Film Materials Laboratory, Department of Physics, Govt. Vidarbha Institute of Science and Humanities, Amravati 444604, Maharashtra (India); Bargal, A.N. [Nanostructured Thin Film Materials Laboratory, Department of Physics, Govt. Vidarbha Institute of Science and Humanities, Amravati 444604, Maharashtra (India)

    2011-07-15

    Highlights: {yields} Thin films of (NiS){sub x}(CdS){sub (1-x)} with variable composition (x = 1 to 0) were deposited onto glass substrates by the successive ionic layer adsorption and reaction (SILAR) method. {yields} The structural, surface morphological and electrical characterizations of the as deposited and annealed films were studied. {yields} The bandgap and activation energy of annealed (NiS){sub x}(CdS){sub (1-x)} film decrease with improvement in photosensitive nature. -- Abstract: Recently ternary semiconductor nanostructured composite materials have attracted the interest of researchers because of their photovoltaic applications. Thin films of (NiS){sub x}(CdS){sub (1-x)} with variable composition (x = 1-0) had been deposited onto glass substrates by the successive ionic layer adsorption and reaction (SILAR) method. As grown and annealed films were characterised by X-ray diffraction, scanning electron microscopy and EDAX to investigate structural and morphological properties. The (NiS){sub x}(CdS){sub (1-x)} films were polycrystalline in nature having mixed phase of rhombohedral and hexagonal crystal structure due to NiS and CdS respectively. The optical and electrical properties of (NiS){sub x}(CdS){sub (1-x)} thin films were studied to determine compsition dependent bandgap, activation energy and photconductivity. The bandgap and activation energy of annealed (NiS){sub x}(CdS){sub (1-x)} film decrease with improvement in photosensitive nature.

  1. Epitaxial Growth of Large-Grain NiSe Films by Solid-State Reaction for High-Responsivity Photodetector Arrays.

    Science.gov (United States)

    Cai, Caoyuan; Ma, Yang; Jeon, Jaeho; Huang, Fan; Jia, Feixiang; Lai, Shen; Xu, Zhihao; Wu, Congjun; Zhao, Ruiqi; Hao, Yufeng; Chen, Yiqing; Lee, Sungjoo; Wang, Min

    2017-05-01

    Film-based photodetectors have shown superiority for the fabrication of photodetector arrays, which are desired for integrating photodetectors into sensing and imaging systems, such as image sensors. But they usually possess a low responsivity due to low carrier mobility of the film consisting of nanocrystals. Large-grain semiconductor films are expected to fabricate superior-responsivity photodetector arrays. However, the growth of large-grain semiconductor films, normally with a nonlayer structure, is still challenging. Herein, this study introduces a solid-state reaction method, in which the growth rate is supposed to be limited by diffusion and reaction rate, for interface-confined epitaxial growth of nonlayer structured NiSe films with grain size up to micrometer scale on Ni foil. Meanwhile, patterned growth of NiSe films allows the fabrication of NiSe film based photodetector arrays. More importantly, the fabricated photodetector based on as-grown high-quality NiSe films shows a responsivity of 150 A W(-1) in contrast to the value of 0.009 A W(-1) from the photodetector based on as-deposited NiSe film consisting of nanocrystals, indicating a huge responsivity-enhancement up to four orders of magnitude. It is ascribed to the enhanced charge carrier mobility in as-grown NiSe films by dramatically decreasing the amount of grain boundary leading to scattering of charge carrier. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. OXIDATIVE-REFORMING OF METHANE AND PARTIAL OXIDATION OF METHANE REACTIONS OVER NiO/PrO2/ZrO2 CATALYSTS: EFFECT OF NICKEL CONTENT

    Directory of Open Access Journals (Sweden)

    Y. J. O. Asencios

    Full Text Available Abstract In this work the behavior of NiO-PrO2-ZrO2 catalysts containing various nickel loadings was evaluated in the partial oxidation of methane and oxidative-reforming reactions of methane. The catalysts were characterized by X-Ray Diffraction Analysis (in situ-XRD, Temperature Programmed Reduction (H2-TPR, Scanning Electron Microscopy (SEM/EDX and Adsorption-Desorption of nitrogen (BET area. The reactions were carried out at 750 °C and 1 atm for 5 hours. The catalysts were studied with different nickel content: 0, 5, 10 and 15% (related to total weight of catalyst, wt%. In both reactions, the catalyst containing the mixture of the three oxides (NiO/PrO2/ZrO2 with 15% nickel (15NiPrZr catalyst showed the best activity for the conversion of the reactants into Syngas and showed high selectivity for H2 and CO. The results suggest that the promoter PrO2 and the Niº centers are in a good proportion in the catalyst with 15% Ni. Our results showed that low nickel concentrations in the catalyst led to high metallic dispersion; however, very low nickel concentrations did not favor the methane transformation into Syngas. The catalyst containing only NiO/ZrO2 in the mixture was not sufficient for the catalysis. The presence of the promoter PrO2 was very important for the catalysis of the POM.

  3. Dynamic transformation of small Ni particles during methanation of CO2 under fluctuating reaction conditions monitored by operando X-ray absorption spectroscopy

    Science.gov (United States)

    Mutz, B.; Carvalho, H. W. P.; Kleist, W.; Grunwaldt, J.-D.

    2016-05-01

    A 10 wt.-% Ni/Al2O3 catalyst with Ni particles of about 4 nm was prepared and applied in the methanation of CO2 under dynamic reaction conditions. Fast phase transformations between metallic Ni, NiO and NiCO3 were observed under changing reaction atmospheres using operando X-ray absorption spectroscopy (XAS). Removing H2 from the feed gas and, thus, simulating a H2 dropout during the methanation reaction led to oxidation of the active sites. The initial reduced state of the Ni particles could not be recovered under methanation atmosphere (H2/CO2 = 4); this was only possible with an effective reactivation step applying H2 at increased temperatures. Furthermore, the cycling of the gas atmospheres resulted in a steady deactivation of the catalyst. Operando XAS is a powerful tool to monitor these changes and the behavior of the catalyst under working conditions to improve the understanding of the catalytic processes and deactivation phenomena.

  4. The Use of Tertiary Alkylmagnesium Nucleophiles in Ni-Catalyzed Cross-Coupling Reactions.

    Science.gov (United States)

    Joshi-Pangu, Amruta; Biscoe, Mark R

    2012-05-14

    Nickel-catalyzed cross-coupling reactions of unactivated tertiary alkyl nucleophiles and aryl bromides have been developed using N-heterocyclic carbene ligands. These processes are reviewed alongside earlier attempts to employ unactivated tertiary alkyl nucleophiles in cross-coupling reactions. Potential mechanisms for the transformations, and future challenges in this field are discussed.

  5. Effect of precipitants on Ni-CeO2 catalysts prepared by a co-precipitation method for the reverse water-gas shift reaction

    Institute of Scientific and Technical Information of China (English)

    王路辉; 刘辉; 刘源; 陈英; 杨淑清

    2013-01-01

    A series of Ni-CeO2 catalysts were prepared by co-precipitation method with Na2CO3, NaOH, and mixed precipitant (Na2CO3:NaOH;1:1 ratio) as precipitant, respectively. The effect of the precipitants on the catalytic performance, physical and chemical properties of Ni-CeO2 catalysts was investigated with the aid of X-ray diffraction (XRD), Brumauer-Emmett-Teller method (BET), Fou-rier-transform infrared spectroscopy (FT-IR), thermogravimetry (TG), and H2-TPR characterizations. The Ni-CeO2 catalysts were exam-ined with respect to their catalytic performance for the reverse water-gas shift reaction, and their catalytic activities were ranked as:Ni-CeO2-CP (Na2CO3:NaOH=1:1)>Ni-CeO2-CP(Na2CO3)>Ni-CeO2-CP(NaOH). Correlating to the characteristic results, it was found that the catalyst prepared by co-precipitation with mixed precipitant (Na2CO3:NaOH; 1:1 ratio) as precipitant had the most amount of oxygen vacancies accompanied with highly dispersed Ni particles, which made the corresponding Ni-CeO2-CP(Na2CO3:NaOH=1:1) catalyst exhibit the highest catalytic activity. While the precipitant of Na2CO3 or NaOH resulted in less or no oxygen vacancies in Ni-CeO2 catalysts. As a result, Ni-CeO2-CP(Na2CO3) and Ni-CeO2-CP(NaOH) catalysts presented poor catalytic performance.

  6. Using ionic liquid as the solvent to prepare Pd–Ni bimetallic nanoparticles by a pyrolysis method for ethanol oxidation reaction

    Energy Technology Data Exchange (ETDEWEB)

    Ding, Keqiang, E-mail: dkeqiang@263.net [College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050024 (China); Yang, Hongwei; Cao, Yanli; Zheng, Chunbao [College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050024 (China); Rapole, Sowjanya B. [Integrated Composites Laboratory (ICL), Dan F. Smith Department of Chemical Engineering, Lamar University, Beaumont, TX 77710 (United States); Guo, Zhanhu, E-mail: zhanhu.guo@lamar.edu [Integrated Composites Laboratory (ICL), Dan F. Smith Department of Chemical Engineering, Lamar University, Beaumont, TX 77710 (United States)

    2013-10-01

    Room temperature ionic liquids (RTILs) of 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIBF4) is used as the solvent for the first time to prepare multi-walled carbon nanotubes (MWCNTs) supported nanocomposite catalysts of Pd{sub x}Ni{sub y} (atomic ratios of Pd to Ni are 1:1, 1:1.5, 1:2, and 1:2.5) nanoparticles (denoted as Pd{sub x}Ni{sub y}/MWCNTs) by using a simple pyrolysis process. The Pd{sub x}Ni{sub y}/MWCNTs catalysts are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Results show that the Pd{sub x}Ni{sub y} nanoparticles (NPs) are quite uniformly dispersed on the surface of MWCNTs with an average crystallite size of ∼7.0 nm. The electro-catalytic activity of the Pd{sub x}Ni{sub y}/MWCNTs catalysts for ethanol oxidation reaction (EOR) is examined by cyclic voltammetry (CV). It is revealed that the onset potential is ∼80 mV lower and the peak current is about three times higher for ethanol oxidation for MWCNT catalysts with Pd{sub 1}Ni{sub 1.5} compared to those of Pd/MWCNTs. The catalytic mechanisms of the Pd{sub 1}Ni{sub 1.5}/MWCNTs towards EOR are also proposed and discussed. - Highlights: • Introducing ionic liquids to the pyrolysis process for the preparation of Pd{sub x}Ni{sub y} nanoparticles. • Pd{sub x}Ni{sub y} nanoparticles with an average particle size of ∼7.0 nm were fabricated. • The peak current of EOR was about three times higher at Pd{sub 1}Ni{sub 1.5} compared to those of Pd.

  7. Catalisadores Ni/Al2O3 promovidos com molibdênio para a reação de reforma a vapor de metano Mo-Ni/AL2O3 catalysts for the methane steam reforming reaction

    Directory of Open Access Journals (Sweden)

    Silvia Sálua Maluf

    2003-03-01

    Full Text Available Mo-promoted Ni/Al2O3 catalysts for the methane steam reforming reaction were studied in this work. The Ni/Al2O3 catalysts were prepared by precipitation and molibdenum was added by impregnation up to 2%wt. The solids were tested using a micro-reactor under two H2Ov/C conditions and were characterized by ICP-OES, XRD, N2 adsoption, H2 chemisorption and TPR. NiO and NiAl2O4 phases were observed and the metallic area decreased with the increase of the Mo content. From the catalytic tests high stability was verified for H2Ov/C=4.0. On the other hand, only the catalyst containing 0,05% Mo stayed stable during 30 hours of the test at H2Ov/C=2.0.

  8. Synthesis and characterization of NiFe{sub 2}O{sub 4}–Pd magnetically recyclable catalyst for hydrogenation reaction

    Energy Technology Data Exchange (ETDEWEB)

    Karaoğlu, E., E-mail: ekaraoglu@fatih.edu.tr [Department of Chemistry, Faculty of Arts and Sciences, Fatih University, 34500 B. Cekmece, Istanbul (Turkey); Özel, U.; Caner, C.; Baykal, A.; Summak, M.M. [Department of Chemistry, Faculty of Arts and Sciences, Fatih University, 34500 B. Cekmece, Istanbul (Turkey); Sözeri, H. [TUBITAK-UME, National Metrology Institute, PO Box 54, 41470 Gebze-Kocaeli (Turkey)

    2012-12-15

    Graphical abstract: Display Omitted Highlights: ► Novel superparamagnetic NiFe{sub 2}O{sub 4}–Pd magnetically recyclable catalyst was fabricated through co-precipitation. ► It could be reused several times without significant loss in catalytic activity for hydrogenation reaction. ► No further modification of the NiFe{sub 2}O{sub 4}–Pd magnetically recyclable catalyst is necessary for utilization as catalyst. -- Abstract: Herein we report the fabrication and characterization magnetically recyclable catalysts of NiFe{sub 2}O{sub 4}–Pd nanocomposite as highly effective catalysts for reduction reactions in liquid phase. The reduction Pd{sup 2+} was accomplished with polyethylene glycol 400 (PEG-400) instead of sodium borohydride (NaBH{sub 4}) and NiFe{sub 2}O{sub 4} nanoparticles was prepared by sonochemically using FeCI{sub 3}·6H{sub 2}O and NiCl{sub 2}. The chemical characterization of the product was done with X-ray diffractometry, Infrared spectroscopy, transmission electron microscopy, UV–Vis spectroscopy, thermal gravimetry and inductively coupled plasma. Thus formed NiFe{sub 2}O{sub 4}–Pd MRCs showed a very high activity in reduction reactions of 4-nitro aniline and 1,3-dinitrobenzene in liquid phase. It was found out that the catalytic activity of NiFe{sub 2}O{sub 4}–Pd MRCs on the reduction of 4-nitro aniline and 1,3-dinitrobenzene in liquid phase are between 99–93% and 98–93%, respectively. Magnetic character of this system allowed recovery and multiple use without significant loss of its catalytic activity. It is found that NiFe{sub 2}O{sub 4}–Pd MRCs showed very efficient catalytic activity and multiple usability.

  9. The influence of transfer reactions on the sub-barrier fusion enhancement in the systems {sup 58.64}Ni +, {sup 92,100}Mo

    Energy Technology Data Exchange (ETDEWEB)

    Rehm, K.E.; Jiang, C.L.; Esbensen, H. [and others

    1995-08-01

    High resolution experiments performed during the past few years demonstrated that the various reaction modes occurring in heavy ion collisions can strongly influence each other. This interrelation of the different reaction modes brings a nuclear structure dependence to the fusion and deep-inelastic channels that were previously described in the framework of pure statistical models. In order to fully understand the interrelation between these reaction channels, a complete set of measurements including elastic and inelastic scattering, few-nucleon transfer and fusion is required. In continuation of our earlier measurements of the fusion cross sections in the system {sup 58,64}Ni + {sup 92,100}Mo we finished the studies of the quasielastic process in these systems. The experiments were done in inverse reaction kinematics using the split-pole spectrograph with its hybrid focal-plane detector for particle identification. The experiments with {sup 100}Mo beams were performed previously. First test runs with {sup 92}Mo showed the possible interference with {sup 98}Mo ions which could be eliminated by using the 13{sup +} charge state from the ECR source. The data from these experiments were completely analyzed. The smallest transfer cross sections are observed for the systems {sup 64}Ni + {sup 100}Mo and {sup 58}Ni + {sup 92}Mo, i.e., the most neutron-rich and neutron-deficient systems, respectively. For the other systems, {sup 64}Ni + {sup 92}Mo and {sup 58}Ni + {sup 100}Mo, the transfer cross sections at energies close to the barrier are about of equal magnitude. This observation does not correlate with the deviation of the experimental fusion cross sections from the coupled-channels predictions. While for {sup 58}Ni + {sup 100}Mo discrepancies between the experimental and theoretical fusion cross sections are observed, the system {sup 64}Ni + {sup 92}Mo which shows about the same transfer yields, is quite well described by the coupled-channels calculations.

  10. Nuclear reactions of the system {sup 6} Li on {sup 58} Ni near the Coulomb barrier; Reacciones nucleares del sistema {sup 6} Li sobre {sup 58} Ni cerca de la barrera de Coulomb

    Energy Technology Data Exchange (ETDEWEB)

    Lizcano, D.; Aguilera, E.F.; Garcia M, H.; Martinez Q, E. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    2004-07-01

    Protons, alpha particles and deuterons coming from the reactions {sup 6} Li + {sup 58} Ni are detected to three different energy around the Coulomb barrier. The possible effects of the weakly bound character of the projectile are studied and the results are compared with previous data for the system {sup 6} Li + {sup 59} Co. (Author)

  11. Low-lying electric-dipole strengths of Ca, Ni, and Sn isotopes imprinted on total reaction cross sections

    Science.gov (United States)

    Horiuchi, W.; Hatakeyama, S.; Ebata, S.; Suzuki, Y.

    2017-08-01

    Low-lying electric-dipole (E 1 ) strength of a neutron-rich nucleus contains information on neutron-skin thickness, deformation, and shell evolution. We discuss the possibility of making use of total reaction cross sections on 40Ca, 120Sn, and 208Pb targets to probe the E 1 strength of neutron-rich Ca, Ni, and Sn isotopes. They exhibit large enhancement of the E 1 strength at neutron number N >28 , 50, and 82, respectively, due to a change of the single-particle orbits near the Fermi surface participating in the transitions. The density distributions and the electric-multipole strength functions of those isotopes are calculated by the Hartree-Fock+BCS and the canonical-basis-time-dependent-Hartree-Fock-Bogoliubov methods, respectively, using three kinds of Skyrme-type effective interaction. The nuclear and Coulomb breakup processes are respectively described with the Glauber model and the equivalent photon method in which the effect of finite-charge distribution is taken into account. The three Skyrme interactions give different results for the total reaction cross sections because of different Coulomb breakup contributions. The contribution of the low-lying E 1 strength is amplified when the low-incident energy is chosen. With an appropriate choice of the incident energy and target nucleus, the total reaction cross section can be complementary to the Coulomb excitation for analyzing the low-lying E 1 strength of unstable nuclei.

  12. Recycling of CO2: Probing the Chemical State of the Ni(111) Surface during the Methanation Reaction with Ambient-Pressure X-Ray Photoelectron Spectroscopy.

    Science.gov (United States)

    Heine, Christian; Lechner, Barbara A J; Bluhm, Hendrik; Salmeron, Miquel

    2016-10-12

    Using ambient-pressure X-ray photoelectron spectroscopy (AP-XPS), we studied the adsorption and reactions of CO2 and CO2 + H2 on the Ni(111) surface to identify the surface chemical state and the nature of the adsorbed species during the methanation reaction. In 200 mTorr CO2, we found that NiO is formed from CO2 dissociation into CO and atomic oxygen. Additionally, carbonate (CO3(2-)) is present on the surface from further reaction of CO2 with NiO. The addition of H2 into the reaction environment leads to reduction of NiO and the disappearance of CO3(2-). At temperatures >160 °C, CO adsorbed on hollow sites, and atomic carbon and OH species are present on the surface. We conclude that the methanation reaction proceeds via dissociation of CO2, followed by reduction of CO to atomic carbon and its hydrogenation to methane.

  13. Light charged particles from low-energy {sup 58}Ni+{sup 112}Sn fusion-evaporation reactions

    Energy Technology Data Exchange (ETDEWEB)

    Fineman, B.J.; Brinkmann, K.; Caraley, A.L.; Gan, N.; Kernan, W.J.; McGrath, R.L.; Savas, T.A. [Physics Department, State University of New York at Stony Brook, Stony Brook, New York 11794 (United States)

    1995-06-01

    Proton and {alpha}-particle energy spectra were measured in coincidence with evaporation residues from 252 and 295 MeV {sup 58}Ni+{sup 112}Sn fusion reactions. Residues were separated from the beam using an electrostatic deflector and detected with surface barrier detectors. Light charged particles were detected with arrays of NaI detectors. Statistical model calculations based on standard parameter choices reproduce the spectra from the cold, low spin {sup 170}Pt{sup *} system. The effects of employing different methods of calculating transmission coefficients were explored. The optical model, ingoing wave boundary condition model, and a simple one-dimensional barrier penetration model from a fusion systematics analysis produce comparable satisfactory predictions. The Hill-Wheeler approximation for transmission coefficients gives unrealistic results for protons.

  14. Multi-Fragment Production in the 32S+58,64Ni Reactions at 11 A MeV

    Science.gov (United States)

    Gramegna, F.; Abbondanno, U.; Bonasera, A.; Bruno, M.; Casini, G.; Cavallaro, S.; Chiari, M.; D'Agostino, M.; Lanchais, A.; Margagliotti, G. V.; Mastinu, P. F.; Milazzo, P. M.; Moroni, A.; Nannini, A.; Ordine, A.; Ricci, R. A.; Tonetto, F.; Travaglini, L.; Vannini, G.; Vannucci, L.

    The characteristic features of the 32S+58,64Ni reaction at 11AMeV have been investigated to evidence the possible rise of multi-fragmentation processes at low excitation energies. The importance of such phenomena consists in the fact that they could represent the signature of a nuclear phase transition from a liquid to a gas region. Evidence of multi-fragment production is displayed by the present data; even if the yield of such events is compatible with the predictions of statistical models, the partition of the mass of the decaying system cannot be easily reproduced. Some preliminary indications of isospin effects are suggested by looking at the differences between the two reacting systems.

  15. The effect of noble metals on catalytic methanation reaction over supported Mn/Ni oxide based catalysts

    Directory of Open Access Journals (Sweden)

    Wan Azelee Wan Abu Bakar

    2015-09-01

    Full Text Available Carbon dioxide (CO2 in sour natural gas can be removed using green technology via catalytic methanation reaction by converting CO2 to methane (CH4 gas. Using waste to wealth concept, production of CH4 would increase as well as creating environmental friendly approach for the purification of natural gas. In this research, a series of alumina supported manganese–nickel oxide based catalysts doped with noble metals such as ruthenium and palladium were prepared by wetness impregnation method. The prepared catalysts were run catalytic screening process using in-house built micro reactor coupled with Fourier Transform Infra Red (FTIR spectroscopy to study the percentage CO2 conversion and CH4 formation analyzed by GC. Ru/Mn/Ni(5:35:60/Al2O3 calcined at 1000 °C was found to be the potential catalyst which gave 99.74% of CO2 conversion and 72.36% of CH4 formation at 400 °C reaction temperature. XRD diffractogram illustrated that the supported catalyst was in polycrystalline with some amorphous state at 1000 °C calcination temperature with the presence of NiO as active site. According to FESEM micrographs, both fresh and used catalysts displayed spherical shape with small particle sizes in agglomerated and aggregated mixture. Nitrogen Adsorption analysis revealed that both catalysts were in mesoporous structures with BET surface area in the range of 46–60 m2/g. All the impurities have been removed at 1000 °C calcination temperature as presented by FTIR, TGA–DTA and EDX data.

  16. PdM nanoparticles (M = Ni, Co, Fe, Mn) with high activity and stability in formic acid oxidation synthesized by sonochemical reactions

    Science.gov (United States)

    Matin, Md. Abdul; Jang, Ji-Hoon; Kwon, Young-Uk

    2014-09-01

    Bimetallic alloy PdnM (n = 1 for M = Mn, Fe, and Co; n = 1, 2, and 3 for M = Ni) nanoparticles (NPs) are synthesized on carbon supports by sonochemical reactions of Pd(acac)2 (acac = acetylacetonate) with M(acac)2 (M = Ni, Co, Mn) or Fe(acac)3 in ethylene glycol. The NPs are characterized by powder X-ray diffractometry, transmission electron microscopy (TEM), and inductively coupled plasma-atomic emission spectroscopy to determine their crystal structures, particle sizes, morphology, and elemental compositions. Alloy formation of the NPs is proven by energy dispersive X-ray spectroscopy line profiles using scanning TEM. The electronic structures and the surface compositions of NPs are analyzed using X-ray photoelectron spectroscopy, and Fourier-transform infrared spectroscopy, respectively. PdnM NPs are applied as electrocatalysts for formic acid oxidation. The incorporation of M in Pd reduces the poisoning by surface hydroxyl groups. Activities based on the current densities are in the order of PdNi > PdFe > PdCo > PdMn. Within the PdnNi series, the activity is in the order of PdNi > Pd2Ni > Pd3Ni. The PdnM NP electrocatalysts show higher activity by a factor of 2-3.5 and improved durability than similarly prepared Pd NP electrocatalyst.

  17. Hierarchical hybrid of Ni3N/N-doped reduced graphene oxide nanocomposite as a noble metal free catalyst for oxygen reduction reaction

    Science.gov (United States)

    Zhao, Qi; Li, Yingjun; Li, Yetong; Huang, Keke; Wang, Qin; Zhang, Jun

    2017-04-01

    Novel nickel nitride (Ni3N) nanoparticles supported on nitrogen-doped reduced graphene oxide nanosheets (N-RGOs) are synthesized via a facile strategy including hydrothermal and subsequent calcination methods, in which the reduced graphene oxide nanosheets (RGOs) are simultaneously doped with nitrogen species. By varying the content of the RGOs, a series of Ni3N/N-RGO nanocomposites are obtained. The Ni3N/N-RGO-30% hybrid nanocomposite exhibits superior catalytic activity towards oxygen reduction reaction (ORR) under alkaline condition (0.1 M KOH). Furthermore, this hybrid catalyst also demonstrates high tolerance to methanol poisoning. The RGO containing rich N confers the nanocomposite with large specific surface area and high electronic conduction ability, which can enhance the catalytic efficiency of Ni3N nanoparticles. The enhanced catalytic activity can be attributed to the synergistic effect between Ni3N and nitrogen doped reduced graphene oxide. In addition, the sufficient contact between Ni3N nanoparticles and the N-RGO nanosheets simultaneously promotes good nanoparticle dispersion and provides a consecutive activity sites to accelerate electron transport continuously, which further enhance the ORR performance. The Ni3N/N-RGO may be further an ideal candidate as efficient and inexpensive noble metal-free ORR electrocatalyst in fuel cells.

  18. Asymmetric synthesis of α-amino acids via homologation of Ni(II) complexes of glycine Schiff bases. Part 3: Michael addition reactions and miscellaneous transformations.

    Science.gov (United States)

    Aceña, José Luis; Sorochinsky, Alexander E; Soloshonok, Vadim

    2014-09-01

    The major goal of this review is a critical discussion of the literature data on asymmetric synthesis of α-amino acids via Michael addition reactions involving Ni(II)-complexes of amino acids. The material covered is divided into two conceptually different groups dealing with applications of: (a) Ni(II)-complexes of glycine as C-nucleophiles and (b) Ni(II)-complexes of dehydroalanine as Michael acceptors. The first group is significantly larger and consequently subdivided into four chapters based on the source of stereocontrolling element. Thus, a chiral auxiliary can be used as a part of nucleophilic glycine Ni(II) complex, Michael acceptor or both, leading to the conditions of matching vs. mismatching stereochemical preferences. The particular focus of the review is made on the practical aspects of the methodology under discussion and mechanistic considerations.

  19. Characterization of Ni and W co-loaded SBA-15 catalyst and its hydrogen production catalytic ability on ethanol steam reforming reaction

    Science.gov (United States)

    Kim, Dongjin; Kwak, Byeong Sub; Min, Bong-Ki; Kang, Misook

    2015-03-01

    This study evaluated the application of advanced bimetallic catalytic species of Ni and W to effectively produce hydrogen gases from ethanol steam reforming. The highest reactivity was achieved using the Ni0.95W0.05/SBA-15 catalyst. The maximum H2 production and ethanol conversion of 90% and 85%, respectively, were obtained for 0.4 g catalyst at 600 °C after 10 h with a EtOH:H2O ratio of 1:3 and a gas hourly space velocity of 6000 h-1. This highlights a synergy between the Ni and W loading on SBA-15 during ethanol steam reforming that occurs through the inhibition of Ni particle agglomeration and consequent decrease in catalytic deactivation. Additionally, the supplied W ingredients promoted CO2 selectivity, which was generated from the CO-water gas shift reaction.

  20. From Mixed-Metal MOFs to Carbon-Coated Core-Shell Metal Alloy@Metal Oxide Solid Solutions: Transformation of Co/Ni-MOF-74 to CoxNi1-x@CoyNi1-yO@C for the Oxygen Evolution Reaction.

    Science.gov (United States)

    Sun, Dengrong; Ye, Lin; Sun, Fangxiang; García, Hermenegildo; Li, Zhaohui

    2017-05-01

    Calcination of the mixed-metal species Co/Ni-MOF-74 leads to the formation of carbon-coated CoxNi1-x@CoyNi1-yO with a metal core diameter of ∼3.2 nm and a metal oxide shell thickness of ∼2.4 nm embedded uniformly in the ligand-derived carbon matrix. The close proximity of Co and Ni in the mixed-metal Co/Ni-MOF-74 promotes the metal alloying and the formation of a solid solution of metal oxide during the calcination process. The presence of the tightly coated carbon shell prohibits particle agglomeration and stabilizes the CoxNi1-x@CoyNi1-yO nanoparticles in small size. The CoxNi1-x@CoyNi1-yO@C derived from Co/Ni-MOF-74 nanocomposites show superior performance for the oxygen evolution reaction (OER). The use of mixed-metal MOFs as precursors represents a powerful strategy for the fabrication of metal alloy@metal oxide solid solution nanoparticles in small size. This method also holds great promise in the development of multifunctional carbon-coated complex core-shell metal/metal oxides owing to the diversified MOF structures and their flexible chemistry.

  1. Electrodeposition of magnetic, superhydrophobic, non-stick, two-phase Cu-Ni foam films and their enhanced performance for hydrogen evolution reaction in alkaline water media

    Science.gov (United States)

    Zhang, J.; Baró, M. D.; Pellicer, E.; Sort, J.

    2014-10-01

    Two-phase Cu-Ni magnetic metallic foams (MMFs) with tunable composition have been prepared by electrodeposition taking advantage of hydrogen co-evolution as a source of porosity. It is observed that Ni tends to deposit inside the porous network defined by the Cu building blocks. Contact angle measurements reveal that the prepared porous films show a remarkable superhydrophobicity (contact angle values larger than 150°) and a non-sticking property to aqueous droplets. This behavior is predominately ascribed to the morphology of the films - hierarchical micro/nanoporosity, wall thickness, and spatial arrangement. The electrochemical activity and stability towards hydrogen evolution reaction of the Cu-Ni MMFs has been investigated by cyclic voltammetry in 1 M KOH at 298 K, and the optimal Ni content is found to be 15 at%. Furthermore, all the foam-like films exhibit ferromagnetic behaviour due to the presence of the Ni-rich phase, with coercivity values ranging from 114 Oe to 300 Oe. From the technological point of view, the Cu-Ni MMFs are promising candidates for magnetically-actuated micro/nano-electromechanical systems (MEMS/NEMS) and micro/nanorobotic platforms with a large surface-area to volume ratio or in magnetic sensors or separators.Two-phase Cu-Ni magnetic metallic foams (MMFs) with tunable composition have been prepared by electrodeposition taking advantage of hydrogen co-evolution as a source of porosity. It is observed that Ni tends to deposit inside the porous network defined by the Cu building blocks. Contact angle measurements reveal that the prepared porous films show a remarkable superhydrophobicity (contact angle values larger than 150°) and a non-sticking property to aqueous droplets. This behavior is predominately ascribed to the morphology of the films - hierarchical micro/nanoporosity, wall thickness, and spatial arrangement. The electrochemical activity and stability towards hydrogen evolution reaction of the Cu-Ni MMFs has been investigated

  2. Surface photo reaction processes using synchrotron radiation; Hoshako reiki ni yoru hyomenko hanno process

    Energy Technology Data Exchange (ETDEWEB)

    Imaizumi, Y. [Tohoku University, Sendai (Japan). Institute for Materials Research; Yoshigoe, A. [Toyohashi University of Technology, Aichi (Japan); Urisu, T. [Toyohashi University of Technology, Aichi (Japan). Institute for Molecular Science

    1997-08-20

    This paper introduces the surface photo reaction processes using synchrotron radiation, and its application. A synchrotron radiation process using soft X-rays contained in electron synchrotron radiated light as an excited light source has a possibility of high-resolution processing because of its short wave length. The radiated light can excite efficiently the electronic state of a substance, and can induce a variety of photochemical reactions. In addition, it can excite inner shell electrons efficiently. In the aspect of its application, it has been found that, if radiated light is irradiated on surfaces of solids under fluorine-based reaction gas or Cl2, the surfaces can be etched. This technology is utilized practically. With regard to radiated light excited CVD process, it may be said that anything that can be deposited by the ordinary plasma CVD process can be deposited. Its application to epitaxial crystal growth may be said a nano processing application in thickness direction, such as forming an ultra-lattice structure, the application being subjected to expectation. In micromachine fabricating technologies, a possibility is searched on application of a photo reaction process of the radiated light. 5 refs., 6 figs.

  3. Influence of catalytic activity and reaction conditions on the product distribution in coal liquefaction; Sekitan ekikayu no seiseibutsu bunpu ni taisuru shokubai kassei oyobi hanno joken no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Hasuo, H.; Sakanishi, K.; Mochida, I. [Kyushu University, Fukuoka (Japan). Institute of Advanced Material Study

    1996-10-28

    The NiMo sulfide supported on Ketjen Black (KB) was more effective and yielded lighter oil products containing light fractions with their boiling point below 300{degree}C during the two stage liquefaction combining low temperature and high temperature hydrogenation the conventional NiMo/alumina catalyst and FeS2 catalyst. Although the NiMo/alumina yielded increased oil products during the two stage liquefaction, the lighter oil fractions did not increase and the heavier fractions increased mainly. This suggests that the hydrogenation of aromatic rings and successive cleavage of the rings are necessary for producing the light oil, which is derived from the sufficient hydrogenation of aromatic rings using catalysts. For the two stage reaction with NiMo/KB catalyst, it was considered that sufficient hydrogen was directly transferred to coal molecules at the first stage of the low temperature reaction, which promoted the solubilization of coal and the successive hydrogenation at the high temperature reaction. Thus, high activity of the catalyst must be obtained. It is expected that further high quality distillates can be produced through the optimization of catalysts and solvents at the two stage reaction. 1 ref., 4 figs., 1 tab.

  4. Preparation and use of samarium diiodide (SmI(2)) in organic synthesis: the mechanistic role of HMPA and Ni(II) salts in the samarium Barbier reaction.

    Science.gov (United States)

    Sadasivam, Dhandapani V; Choquette, Kimberly A; Flowers, Robert A

    2013-02-04

    Although initially considered an esoteric reagent, SmI(2) has become a common tool for synthetic organic chemists. SmI(2) is generated through the addition of molecular iodine to samarium metal in THF.(1,2-3) It is a mild and selective single electron reductant and its versatility is a result of its ability to initiate a wide range of reductions including C-C bond-forming and cascade or sequential reactions. SmI(2) can reduce a variety of functional groups including sulfoxides and sulfones, phosphine oxides, epoxides, alkyl and aryl halides, carbonyls, and conjugated double bonds.(2-12) One of the fascinating features of SmI-(2)-mediated reactions is the ability to manipulate the outcome of reactions through the selective use of cosolvents or additives. In most instances, additives are essential in controlling the rate of reduction and the chemo- or stereoselectivity of reactions.(13-14) Additives commonly utilized to fine tune the reactivity of SmI(2) can be classified into three major groups: (1) Lewis bases (HMPA, other electron-donor ligands, chelating ethers, etc.), (2) proton sources (alcohols, water etc.), and (3) inorganic additives (Ni(acac)(2), FeCl(3), etc).(3) Understanding the mechanism of SmI(2) reactions and the role of the additives enables utilization of the full potential of the reagent in organic synthesis. The Sm-Barbier reaction is chosen to illustrate the synthetic importance and mechanistic role of two common additives: HMPA and Ni(II) in this reaction. The Sm-Barbier reaction is similar to the traditional Grignard reaction with the only difference being that the alkyl halide, carbonyl, and Sm reductant are mixed simultaneously in one pot.(1,15) Examples of Sm-mediated Barbier reactions with a range of coupling partners have been reported,(1,3,7,10,12) and have been utilized in key steps of the synthesis of large natural products.(16,17) Previous studies on the effect of additives on SmI(2) reactions have shown that HMPA enhances the

  5. Direct reforming of biogas on Ni-based SOFC anodes: Modelling of heterogeneous reactions and validation with experiments

    Science.gov (United States)

    Santarelli, Massimo; Quesito, Francesco; Novaresio, Valerio; Guerra, Cosimo; Lanzini, Andrea; Beretta, Davide

    2013-11-01

    This work focuses on the heterogeneous reactions taking place in a tubular anode-supported solid oxide fuel cell (SOFC) when the designated fuel is biogas from anaerobic digestion directly feeding the fuel cell. Operational maps of the fuel cell running on direct reforming of biogas were first obtained. Hence a mathematical model incorporating the kinetics of reforming reactions on Ni catalyst was used to predict the gas composition profile along the fuel channel. The model was validated against experimental data based on polarization curves. Also, the anode off-gas composition was collected and analyzed through a gas chromatograph. Finally, the model has been used to predict and analyze the gas composition change along the anode channel to evaluate effectiveness of the direct steam reforming when varying cell temperature, inlet fuel composition and the type of reforming process. The simulations results confirmed that thermodynamic-equilibrium conditions are not fully achieved inside the anode channel. It also outlines that a direct biogas utilization in an anode-supported SOFC is able to provide good performance and to ensure a good conversion of the methane even though when the cell temperature is far from the nominal value.

  6. Detachment of CVD-grown graphene from single crystalline Ni films by a pure gas phase reaction

    Science.gov (United States)

    Zeller, Patrick; Henß, Ann-Kathrin; Weinl, Michael; Diehl, Leo; Keefer, Daniel; Lippmann, Judith; Schulz, Anne; Kraus, Jürgen; Schreck, Matthias; Wintterlin, Joost

    2016-11-01

    Despite great previous efforts there is still a high need for a simple, clean, and upscalable method for detaching epitaxial graphene from the metal support on which it was grown. We present a method based on a pure gas phase reaction that is free of solvents and polymer supports and avoids mechanical transfer steps. The graphene was grown on 150 nm thick, single crystalline Ni(111) films on Si(111) wafers with YSZ buffer layers. Its quality was monitored by using low energy electron diffraction and scanning tunneling microscopy. The gas phase etching uses a chemical transport reaction, the so-called Mond process, based on the formation of gaseous nickel tetracarbonyl in ~ 1 bar of CO at ~ 75 °C and by adding small amounts of sulfide catalysts. X-ray photoelectron spectroscopy, Raman spectroscopy and scanning electron microscopy were used to characterize the detached graphene. It was found that the method successfully removes the nickel from underneath the graphene layer, so that the graphene lies on the insulating oxide buffer layer. Small residual particles of nickel sulfide and cracks in the obtained graphene layer were identified. The defect concentrations were comparable to graphene samples obtained by wet chemical etching and by the bubbling transfer.

  7. Effect of al content on reaction laser sintering of Ni-Al powder

    Directory of Open Access Journals (Sweden)

    Qin L.

    2008-01-01

    Full Text Available Laser reactive sintering, i.e., laser-induced self-propagating reaction sintering synthesis was used for the preparation of nickel aluminide intermetallic compounds. The experimental parameters controlling the ignition step such as ignition time and adiabatic temperature were calculated as a function of initial stoichiometry. Al mole ratio in initial powder mixture was varied from 25% to 50% for controlling adiabatic temperature. The increase in Al powder content resulted in the rise in adiabatic temperature and the morphology change of nickel aluminide compounds from needle-like to blocky.

  8. Ni/LaNi5多孔复合电极的制备及其析氢电催化性能%Preparation and Electrocatalytic Performance for Hydrogen Evolution Reaction of the Ni/LaNi5 Porous Composite Electrode

    Institute of Scientific and Technical Information of China (English)

    张艺; 王森林; 李彩彩

    2012-01-01

    At first, the Ni-Zn coating was electroplated, then, the coating was immersed in concentrated alkali solution to remove zinc and the porous nickel was obtained. Finally, the Ni/LaNis porous composite electrode was prepared on this porous nickel surface by means of the composite electro-deposition. The electro-catalytic properties for hydrogen evolution reaction of the electrode were evaluated by electrochemical steady-state polarization curve and electrochemical impendence spectroscopy (EIS). And the stability of the electrode was studied by open circuit potential and constant potential electrolysis technology for long time and discontinuity electrolysis. Results show that the apparent exchange current density of the porous composite electrode is 172 and 26 times as much as that of the nickel electrode and the porous nickel electrode, respectively. Because LaNi5 possesses the effect of electrode protection, the stability of the porous composite electrode is better than that of the porous nickel.%先电沉积Ni-Zn合金镀层,然后用浓碱将镀层中的锌脱溶,得到多孔镍,最后采用复合电沉积将LaNi5镶嵌到多孔镍表面,制备成Ni/LaNi5多孔复合电极.采用稳态极化曲线和交流阻抗谱对电极的电催化析氢性能进行了评价,并运用恒电位间歇电解和长时间电解,开路电位等研究了电极的电析氢稳定性.结果表明:Ni/LaNi5多孔复合电极的析氢表观交换电流密度分别是镍和多孔镍的172倍和26倍;多孔复合电极中的LaNi5具有稳定电极的作用,该电极比多孔镍具有更优异的抗断电性能.

  9. Electrochemical behavior of Ni{sub x}W{sub 1-x} materials as catalyst for hydrogen evolution reaction in alkaline media

    Energy Technology Data Exchange (ETDEWEB)

    Oliver-Tolentino, Miguel A. [UPIBI-IPN, Departamento de Ciencias Basicas, Av. Acueducto s/n, Barrio La Laguna, Col. Ticoman, Mexico D.F. 07340 (Mexico); Arce-Estrada, Elsa M. [ESIQIE-IPN Departamento de Ingenieria en Metalurgia y Materiales, UPALM, UPALM, Mexico D.F. 07738 (Mexico); Cortes-Escobedo, Claudia A. [Centro de Investigacion e Innovacion Tecnologica del IPN, Cda. Cecati s/n, Col. Sta. Catarina, CP 02250 Azcapotzalco D.F. (Mexico); Bolarin-Miro, Ana M.; Sanchez-De Jesus, Felix [Area Academica de Ciencias de la Tierra y Materiales, Universidad Autonoma del Estado de Hidalgo, CU, Carr. Pachuca-Tulancingo Km. 4.5, Mineral de la Reforma, CP 42184 Hidalgo (Mexico); Gonzalez-Huerta, Rosa de G. [ESIQIE-IPN, Departamento de Ingenieria Quimica - Laboratorio de Electroquimica y Corrosion, Edif. Z-5 3er piso, UPALM, Mexico D.F. 07738 (Mexico); Manzo-Robledo, Arturo, E-mail: amanzor@ipn.mx [ESIQIE-IPN, Departamento de Ingenieria Quimica - Laboratorio de Electroquimica y Corrosion, Edif. Z-5 3er piso, UPALM, Mexico D.F. 07738 (Mexico)

    2012-09-25

    Highlights: Black-Right-Pointing-Pointer The electrochemical techniques used in this study elucidated the Ni-W surface state. Black-Right-Pointing-Pointer The Ni-W materials were effective for the hydrogen evolution reaction. Black-Right-Pointing-Pointer The prepared alloys exhibited higher catalytic activity than their precursors. Black-Right-Pointing-Pointer The preparation method is relatively simple and effective procedure. - Abstract: In the present work, results of electrochemical evaluation, as well as morphological and structural characterization of Ni{sub x}W{sub 1-x} materials with x = 0.77, 0.64, 0.4, 0.19 and 0.07 processed by means of high energy ball milling from high purity powders are presented. Also, the electrocatalytic performance on the hydrogen evolution reaction (HER) of the Ni{sub x}W{sub 1-x} materials evaluated by linear polarization and cyclic voltammetry techniques in alkaline media at room temperature is discussed. The structural and morphological characterization of the as-prepared materials was carried out using X-ray diffraction (XRD) and scanning electron microscopy (SEM). Results indicated a small-particle clusters and solid solution formation. According to the kinetics parameters the best electrocatalytic activity was observed at Ni{sub 64}W{sub 36}.

  10. Catalytic activity of pyrite for coal liquefaction reaction; Tennen pyrite no shokubai seino ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Hirano, K.; Kozu, M.; Okada, T.; Kobayashi, M. [Nippon Coal Oil Co. Ltd., Tokyo (Japan)

    1996-10-28

    Since natural pyrite is easy to obtain and cheap as coal liquefaction catalyst, it is to be used for the 150 t/d scale NEDOL process bituminous coal liquefaction pilot plant. NEDO and NCOL have investigated the improvement of catalytic activity of pulverized natural pyrite for enhancing performance and economy of the NEDOL process. In this study, coal liquefaction tests were conducted using natural pyrite catalyst pulverized by dry-type bowl mill under nitrogen atmosphere. Mechanism of catalytic reaction of the natural pyrite was discussed from relations between properties of the catalyst and liquefaction product. The natural pyrite provided an activity to transfer gaseous hydrogen into the liquefaction product. It was considered that pulverized pyrite promotes the hydrogenation reaction of asphaltene because pulverization increases its contact rate with reactant and the amount of active points on its surface. It was inferred that catalytic activity of pyrite is affected greatly by the chemical state of Fe and S on its surface. 3 refs., 4 figs., 1 tab.

  11. Liquid and solid state interfacial reactions of Sn-Ag-Cu and Sn-In-Ag-Cu solders with Ni-P under bump metallization

    Energy Technology Data Exchange (ETDEWEB)

    Sharif, Ahmed [Department of Electronic Engineering, City University of Hong Kong, Tat Chee Avenue, Kowloon Tong, Hong Kong (China); Chan, Y.C. [Department of Electronic Engineering, City University of Hong Kong, Tat Chee Avenue, Kowloon Tong, Hong Kong (China)]. E-mail: EEYCCHAN@cityu.edu.hk

    2006-05-10

    In this study, interfacial reactions of electroless Ni(P) metallization of the ball-grid-array (BGA) substrate with the Sn-4 Ag-0.5 Cu (SAC405), Sn-3 Ag-0.5 Cu (SAC305) and Sn-9 In-3.5 Ag-0.5 Cu (SIAC) (wt.%) solder alloy were investigated, focusing on identification of the intermetallic compound (IMC) phases, the IMC growth rates and the consumption rate of the metallization layer at various liquid and solid state heat treatment conditions, e.g. extended reflow and solid state aging. A fixed volume of BGA solder ball (760 {mu}m diameter) was used on a substrate metallization pad with a diameter of 650 {mu}m. The consumption of the electroless Ni(P) in SIAC solder was also lower than in the SAC solders. The presence of indium in the solder played a major role in inhibiting the consumption of Ni(P) in the soldering reaction. The stable IMCs initially formed at the interface of the Ni(P)/In-containing solder system was the (Cu, Ni){sub 6} (Sn, In){sub 5} phase. During further reflow, the (Cu, Ni){sub 3} (Sn, In){sub 4} IMC started forming because of the limited Cu content in the solder. Bulk of the SIAC solder also contained Cu{sub 6}(Sn, In){sub 5} and Ag-In-Sn precipitates embedded in the Sn-rich matrix. It was also found that more Ag-containing SAC405 solder shows higher Ni(P) consumption than SAC305 solder at the same heat treatment condition.

  12. Fabrication of intermetallic NiAl by self-propagating high-temperature synthesis reaction using aluminium nanopowder under high pressure

    CERN Document Server

    Dong Shu Shan; Cheng Hai Yong; Yang Hai Bin; Zou Guang Tian

    2002-01-01

    By using aluminium nanopowder prepared by wire electrical explosion, pure monophase NiAl compound with fine crystallites (<=10 mu m) and good densification (98% of the theoretical green density) was successfully fabricated by means of self-propagating high-temperature synthesis (SHS) under a high pressure of 50 MPa. Investigation shows that, due to the physical and chemical characteristics of the nanoparticles, the SHS reaction mode and mechanism are distinct from those when using conventional coarse-grained reactants. The SHS reaction process depends on the thermal conditions related to pressure and can occur at a dramatically low temperature of 308 sup o C, which cannot be expected in conventional SHS reaction. With increasing pressure, the SHS explosive ignition temperature (T sub i sub g) of forming NiAl decreases due to thermal and kinetic effects.

  13. Effect of reaction conditions and kinetic study on the Fischer-Tropsch synthesis over fused Co-Ni/Al2 O3 catalyst

    Institute of Scientific and Technical Information of China (English)

    P.Nikparsa; A.A Mirzaei; H.Atashi

    2014-01-01

    Co-Ni/Al2O3 catalyst was prepared by the fusion method and used in Fischer-Tropsch synthesis (FTS). The catalysts were characterized by means of nitrogen sorption and scanning electron microscopy. The effect of some reaction conditions such as temperature, pressure and H2/CO feed ratio on the catalytic performance of Co-Ni/Al2O3 in CO hydrogenation was investigated in a fixed-bed reactor. The results indicate that the optimum reaction conditions are 250℃, 0. 3 MPa, H2/CO feed ratio of 2. 0, and GHSV of 3 000 h-1 . Kinetically, the reaction rate was correlated with the Langmuir-Hinshelwood-Hougen-Watson type models. The activation energy for the best fitted model is 88. 41 kJ/mol, suggesting that the intra-particle mass transport is not significant.

  14. Competition between fusion-evaporation and multifragmentation in central collisions in 58Ni + 48Ca reaction at 25 AMeV

    Science.gov (United States)

    Francalanza, L.; Abbondanno, U.; Amorini, F.; Barlini, S.; Bini, M.; Bougault, R.; Bruno, M.; Cardella, G.; Casini, G.; D'Agostino, M.; De Filippo, E.; De Sanctis, J.; Geraci, E.; Giussani, A.; Gramegna, F.; Guiot, B.; Kravchuk, V.; La Guidara, E.; Lanzalone, G.; Le Neindre, N.; Maiolino, C.; Marini, P.; Morelli, L.; Olmi, A.; Pagano, A.; Papa, M.; Piantelli, S.; Pirrone, S.; Politi, G.; Poggi, G.; Porto, F.; Russotto, P.; Rizzo, F.; Vannini, G.; Vannucci, L.

    2013-03-01

    The experimental data concerning the 58Ni+48Ca reaction at Elab(Ni)=25A MeV, collected by the CHIMERA 4π device, have been analyzed in order to investigate the competition among different reaction mechanisms for central collisions in the Fermi energy domain. The method adopted to select such central collisions, by means of construction of the kinetic energy tensor and, consequently, the evaluation of the "flow angle" event by event is presented. Some global variables, able to characterize the pattern of central collisions, have been constructed, and the main features of the reaction products are analyzed in terms of some observable, like mass and velocity distributions, as well as their correlations. Much emphasis was devoted to the competition between fusion-evaporation processes with consequent identification of a heavy residue and multifragmentation of a well defined (if any) transient nuclear system formed in central collisions.

  15. Roles of phosphorous in Sn{sub 4}Ag{sub 0.5}Cu solder reaction with electrolytic Ni-Au

    Energy Technology Data Exchange (ETDEWEB)

    Key Chung, C. [Department of Materials Science and Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan (China); Assembly Test Global Materials, Intel Microelectronics Asia Ltd., B1, No. 205, Tun-Hwa North Road, Taipei 10595, Taiwan (China); Huang, T.C. [Department of Materials Science and Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan (China); Shia, R. [Assembly Test Global Materials, Intel Microelectronics Asia Ltd., B1, No. 205, Tun-Hwa North Road, Taipei 10595, Taiwan (China); Yang, T.L. [Department of Materials Science and Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan (China); Kao, C.R., E-mail: crkao@ntu.edu.tw [Department of Materials Science and Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan (China)

    2012-10-25

    Graphical abstract: The reaction of P-doped Sn{sub 4}Ag{sub 0.5}Cu solder with electrolytic Ni-Au forms a layer of nano crystallites in between (Cu,Ni){sub 6}Sn{sub 5} and (Ni,Cu){sub 3}Sn{sub 4}. This layer effectively suppresses the growth of intermetallic compound. Highlights: Black-Right-Pointing-Pointer P-doped solder changed the intermetallic compounds from chunky to planar structure. Black-Right-Pointing-Pointer P-doped solder suppressed the growth of intermetallic and tensile strain. Black-Right-Pointing-Pointer Nano crystallites were found in between (Ni,Cu){sub 6}Sn{sub 5} and (Cu,Ni){sub 3}Sn{sub 4}. Black-Right-Pointing-Pointer P-doped solder strengthened the interface initially but not multiple reflows. Black-Right-Pointing-Pointer P-doped solder increased the activation energy of intermetallic compounds. - Abstract: In this study, the interfacial reactions of different P-doped and undoped Sn{sub 4}Ag{sub 0.5}Cu solders with electrolytic Ni-Au were investigated. The solder joints were reflowed once and then subjected to two more reflow cycles. The thickness of the intermetallic compound (IMC) layer and the IMC composition were analyzed by scanning electron microscopy and transmission electron microscopy (TEM). The tensile properties of the solder joint were measured using a Dage 4000 instrument. The results showed that the P content of the solder was inversely proportional to the IMC layer thickness and maximum tensile strain. TEM observations showed that a nanocrystallite layer existed between (Ni,Cu){sub 6}Sn{sub 5} and (Cu,Ni){sub 3}Sn{sub 4}. This nanocrystallite layer was responsible for the abovementioned relationship. This layer not only suppressed the growth of the IMC layer effectively but also decreased the pull strength of the solder joint after three reflow cycles. Energy-dispersive X-ray spectra of this interfacial layer were recorded to determine the P, Ni, Cu, and Sn contents. As the P content of the P-doped Sn{sub 4}Ag{sub 0.5}Cu solder

  16. Energy-filtered environmental transmission electron microscopy for the assessment of solid-gas reactions at elevated temperature: NiO/YSZ-H2 as a case study

    DEFF Research Database (Denmark)

    Jeangros, Q.; Hansen, Thomas Willum; Wagner, Jakob Birkedal

    2016-01-01

    A novel approach, which is based on the analysis of sequences of images recorded using energy-filtered transmission electron microscopy and can be used to assess the reaction of a solid with a gas at elevated temperature, is illustrated for the reduction of a NiO/ceramic solid oxide fuel cell anode...... in 1.3mbar of H2. Three-window elemental maps and jump-ratio images of the O K edge and total inelastic mean free path images are recorded as a function of temperature and used to provide local and quantitative information about the reaction kinetics and the volume changes that result from the reaction...

  17. Studies on Pd/NiFe2O4 catalyzed ligand-free Suzuki reaction in aqueous phase: synthesis of biaryls, terphenyls and polyaryls

    Directory of Open Access Journals (Sweden)

    Suresh B. Waghmode

    2011-03-01

    Full Text Available Palladium supported on nickel ferrite (Pd/NiF2O4 was found to be a highly active catalyst for the Suzuki coupling reaction between various aryl halides and arylboronic acids. The reaction gave excellent yields (70–98% under ligand free conditions in a 1:1 DMF/H2O solvent mixture, in short reaction times (10–60 min. The catalyst could be recovered easily by applying an external magnetic field. The polyaryls were similarly synthesized.

  18. Effects of reaction conditions on hydrogen production and carbon nanofiber properties generated by methane decomposition in a fixed bed reactor using a NiCuAl catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Suelves, I.; Pinilla, J.L.; Lazaro, M.J.; Moliner, R. [Instituto de Carboquimica CSIC, Miguel Luesma Castan, 4, 50015 Zaragoza (Spain); Palacios, J.M. [Instituto de Catalisis y Petroleoquimica, CSIC, Cantoblanco, Marie Curie 2, 28049 Madrid (Spain)

    2009-07-01

    In this paper, the results obtained in the catalytic decomposition of methane in a fixed bed reactor using a NiCuAl catalyst prepared by the fusion method are presented. The influences of reaction temperature and space velocity on hydrogen concentration in the outlet gases, as well as on the properties of the carbon produced, have been investigated. Reaction temperature and the space velocity both increase the reaction rate of methane decomposition, but also cause an increase in the rate of catalyst deactivation. Under the operating conditions used, the carbon product is mainly deposited as nanofibers with textural properties highly correlated with the degree of crystallinity. (author)

  19. Mechanistic Study of Ni/CeO{sub 2}-catalyzed CO{sub 2}/CH{sub 4} Reaction Using Flow and Static Methods

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Jin-Gyu; Roh, Joong-Seok; Kim, Ji-Yeong; Lee, Sung-Han; Choi, Jonng-Gill [Yonsei University, Seoul (Korea, Republic of)

    2016-08-15

    Ni/CeO{sub 2} catalysts with different Ni loadings (5, 7, 10, 12, and 14 wt% Ni) were prepared by an impregnation method and examined for the CO{sub 2} reforming of methane using flow and static reactors. Their catalytic activities and selectivities were measured under CO{sub 2}/CH{sub 4}/Ar (=5/5/40 cm{sup 3}/min) flow at 450-800 .deg. C using a flow reactor system with an on-line gas chromatography. At flexed temperature, the CO{sub 2} and CH{sub 4} conversions varied only slightly with the Ni wt%, whereas the H{sub 2}/CO ratio increased with increasing Ni wt%. The conversions increased with temperature, reaching 98% at 800 .deg. C. The H{sub 2}/CO ratio varied with temperature in the range of 450-800 .deg. C, from less than 1 below 550 .deg. C to close to 1 at 550-600 .deg. C and then back to less than 1 above 600 .deg. C. The apparent activation energies were determined to be 43.1 kJ/mol for the CO{sub 2} consumption and 50.2 kJ/mol for the CH{sub 4} consumption based on the rates measured for the reforming reaction over 5 wt% Ni/CeO{sub 2} catalyst at 550-750 .deg. C. Additionally, the catalytic reforming reaction at low pressure (40 Torr) was investigated by a static reactor system by using a differential photoacoustic cell, in which the rates were measured from the CO{sub 2} photoacoustic signal data at early reaction times over the temperature range of 460-610 .deg. C. Apparent activation energies of 25.5-30.1 kJ/mol were calculated from the CO{sub 2} disappearance rates. The CO{sub 2} adsorption on the Ni/CeO{sub 2} catalyst was investigated by the CO{sub 2} photoacoustic spectroscopy and Fourier transform infrared spectroscopy. Feasible side reactions during the catalytic CO{sub 2}/CH{sub 4} reaction were suggested on the basis of the kinetic and spectroscopic results.

  20. Features on various monitoring for laser welding and their application. 3. Correspondence of detective signals to the welds on plate with artificial defects; Laser yosetsu no tame no monitoring ho no tokucho to sono oyo. 3. Laser yosetsu ni okeru keisoku shingo tokusei to kako seijo no sokan

    Energy Technology Data Exchange (ETDEWEB)

    Matsunawa, A. [Osaka University, Osaka (Japan); Watanabe, M.; Nakabayashi, T.; Hiraga, H.; Inoue, T.

    1998-05-05

    Artificial defects are made initially on test pieces, and they are laser-welded. Discussions were given on correspondence of welding quality such as failures generated during the welding to signal behavior. In a joint recognition test, specimen joints were recognized in both of light emitting intensity and plasma potential. Insufficient penetration due to abnormal absorption of beam energy by Ar shield gas was also recognized by measuring simultaneously the light emitting intensity signal and the plasma potential signal. In a longitudinal hole recognition test, longitudinal holes were recognized by using the light emission, sound and plasma potential. It was also found that the key hole is disturbed because the molten pool is disturbed by the hole before laser beam reaches the hole, which caused change in output morphology of the sound, light emission and plasma potential before they reach the hole. In a lateral hole recognition, melting morphology of a concentrated layer of Ni powder was observed, by which data were derived on melting behavior in the bead longitudinal direction. It was found that the plasma potential signal has high plasma existence sensitivity, and the light emission signal has high sensitivity on movement of the plasma, including that of the key hole. 16 refs., 16 figs., 1 tab.

  1. On the kinetics of the hydrogen evolution reaction on Ni-MoOx composite catalysts in alkaline solutions

    Directory of Open Access Journals (Sweden)

    Jović Borka M.

    2012-01-01

    Full Text Available MoO3 particles were co-deposited with Ni onto smooth or rough Ni supports from modified Watt’s baths of different compositions. Morphology and composition of the electrodeposits were characterized by means of cyclic voltammetry, X-ray diffraction, scanning electron microscopy, transmission electron microscopy and energy dispersive X-ray spectroscopy. The electrocatalytic activity of the composite catalysts for H2 evolution in alkaline solutions was determined by quasi-stationary polarization curves. Activity increases with MoOx content in the Ni deposit up to a limiting value. Composite Ni-MoOx catalyst performed high catalytic activity, similar to that of commercial Ni-RuO2 catalyst. Stability tests showed that Ni-MoOx codeposits are stable under condition of constant current and exhibit excellent tolerance to repeated short-circuiting.

  2. [NiFe]Hydrogenase from Citrobacter sp. S-77 surpasses platinum as an electrode for H2 oxidation reaction.

    Science.gov (United States)

    Matsumoto, Takahiro; Eguchi, Shigenobu; Nakai, Hidetaka; Hibino, Takashi; Yoon, Ki-Seok; Ogo, Seiji

    2014-08-18

    Reported herein is an electrode for dihydrogen (H2) oxidation, and it is based on [NiFe]Hydrogenase from Citrobacter sp. S-77 ([NiFe]S77). It has a 637 times higher mass activity than Pt (calculated based on 1 mg of [NiFe]S77 or Pt) at 50 mV in a hydrogen half-cell. The [NiFe]S77 electrode is also stable in air and, unlike Pt, can be recovered 100 % after poisoning by carbon monoxide. Following characterization of the [NiFe]S77 electrode, a fuel cell comprising a [NiFe]S77 anode and Pt cathode was constructed and shown to have a a higher power density than that achievable by Pt.

  3. Preparation, characterization of Mo catalysts supported on Ni- containing calcium deficient hydroxyapatite and reactivity for the thiophene HDS reaction

    Directory of Open Access Journals (Sweden)

    Cherif A.

    2013-09-01

    Full Text Available Ni-containing Calcium Hydroxyapatite (NiCaHAp; 3.31 wt.% Ni was synthesized by coprecipitation and used as catalyst support. Molybdenum was supported on NiCaHAp by impregnation using ammonium heptamolybdate. The prepared catalysts Mo(x/NiCaHAp (x: 2 to 8 wt % in Mo were characterized by elemental analysis, XRD, FT-IR, N2 adsorption-desorption and TEM-EDX. The catalysts were sulfided in-situ at 673 K under flowing H2S/H2 (15 Vol.% H2S and tested in hydrodesulfurization (HDS of thiophene at 673 K. The main XRD peaks of hydroxyapatite CaHAp phase were observed in all samples and a peak due probably to crystalline MoO3 phase was also identified from the results. However, no crystalline phase of NiO was found for the catalysts, which showed its Ni species were highly dispersed. The sulfided catalysts Mo(x/NiCaHAp presented are active in HDS of thiophene, despite the presence of some large MoO3 crystallites and incomplete sulfidation. This activity may be due to interaction of NiO and MoO3 on CaHAp resulting in the formation of Ni-Mo-S phase under flowing H2S/H2. When the molybdenum content increased the HDS activity increasead slightly, which was caused by the agglomeration of MoO3. The Mo(8/NiCaHAp catalyst is about two times less active for thiophene HDS than the commercial NiMoP/Al2O3.

  4. Formation of reacted interfacial zone and improvement of bonding strength in aluminum alloy clad stainless steel and aluminum alloy clad copper plateusing explosive welding technique. Al gokin no stainless ko oyobi do eno bakuhatsu assetsu ni okeru kaimen hannoso no keisei to setsugo kyodo

    Energy Technology Data Exchange (ETDEWEB)

    Hokamoto, K.; Fujita, M. (Kumamoto University, Kumamoto (Japan). Faculty of Engineering); Izuma, T. (Asahi Chemical Industry Co. Ltd., Tokyo (Japan))

    1993-10-31

    Explosive welding experiments using intermediate materials have been performed on combinations of aluminum alloy with stainless steel, and aluminum alloy with copper that are difficult of explosive welding with an ordinary method. The experiments have investigated interfacial reaction layers and bonding strength. The drive plates have used four kinds of aluminum alloy plates with a thickness of 4 mm and a base material of stainless steel (SUS 304) or copper having a thickness of 9 mm. Investigation has been given on how the interfacial structure and the bonding strength change as a result of using intermediate materials of the similar kind with the base material. The composition in the generated reaction layers has higher aluminum concentration than that has been predicted. This is because more aluminum component has been dissolved because of transformation having converged on the side of the aluminum alloy with smaller transformation resistance. Use of the intermediate materials can reduce energy of collision given on the interface, thus controlling the formation of reactive layers on the interface. This has improved the bonding strength largely, leading to a possibility of fabricating clad materials that have good interface properties. 10 refs., 9 figs., 3 tabs.

  5. One-Step Growth of Iron-Nickel Bimetallic Nanoparticles on FeNi Alloy Foils: Highly Efficient Advanced Electrodes for the Oxygen Evolution Reaction.

    Science.gov (United States)

    Qazi, Umair Yaqub; Yuan, Cheng-Zong; Ullah, Naseeb; Jiang, Yi-Fan; Imran, Muhammad; Zeb, Akif; Zhao, Sheng-Jie; Javaid, Rahat; Xu, An-Wu

    2017-08-30

    Electrochemical water splitting is an important process to produce hydrogen and oxygen for energy storage and conversion devices. However, it is often restricted by the oxygen evolution reaction (OER) due to its sluggish kinetics. To overcome the problem, precious metal oxide-based electrocatalysts, such as RuO2 and IrO2, are widely used. The lack of availability and the high cost of precious metals compel researchers to find other resources for the development of cost-effective, environmentally friendly, earth-abundant, nonprecious electrocatalysts for OER. Such catalysts should have high OER performance and good stability in comparison to those of available commercial precious metal-based electrocatalysts. Herein, we report an inexpensive fabrication of bimetallic iron-nickel nanoparticles on FeNi-foil (FeNi4.34@FeNi-foil) as an integrated OER electrode using a one-step calcination process. FeNi4.34@FeNi-foil obtained at 900 °C shows superior OER activity in alkaline solution with an overpotential as low as 283 mV to achieve a current density of 10 mA cm(-2) and a small Tafel slope of 53 mV dec(-1). The high performance and durability of the as-prepared nonprecious metal electrode even exceeds those of the available commercial RuO2 and IrO2 catalysts, showing great potential in replacing the expensive noble metal-based electrocatalysts for OER.

  6. Effect of Reaction Period on Stoichiometry, Phase Purity, and Morphology of Hydrothermally Synthesized Cu2NiSnS4 Nanopowder

    Science.gov (United States)

    Babu, G. Sahaya Dennish; Shajan, X. Sahaya; Alwin, S.; Ramasubbu, V.; Balerao, Gopal M.

    2017-09-01

    The effect of reaction period on the phase purity, morphology, and stoichiometry of Cu2NiSnS4 (CNTS) nanopowder prepared by hydrothermal method has been investigated. Polyvinylpyrrolidone (PVP) and thioglycolic acid were used as capping agent and sulfur source, respectively. The presence of cubic stannite crystal structure and its phase purity were confirmed by powder x-ray diffraction analysis and Raman spectroscopy. Furthermore, the morphological, crystallographic, and optical features of the prepared CNTS nanopowder were characterized by field-emission scanning electron microscopy, transmission electron microscopy, and ultraviolet-visible (UV-Vis) spectrophotometry. The elemental ratios of Cu/(Ni + Sn) and Ni/Sn showed that the stoichiometry of CNTS was maintained for the compounds synthesized at 230°C with reaction period of 24 h. The occurrence of Cu+, Ni2+, Sn4+, and S2- was evaluated by x-ray photoelectron spectroscopy. The prepared material was used as counter electrode in a dye-sensitized solar cell (DSSC) as an alternative to platinum (Pt), resulting in conversion efficiency of 0.92%. These results indicate that CNTS is a prospective material to replace conventional Pt-based counter electrodes in DSSCs.

  7. Epitaxial Growth of Multimetallic Pd@PtM (M = Ni, Rh, Ru) Core-Shell Nanoplates Realized by in Situ-Produced CO from Interfacial Catalytic Reactions.

    Science.gov (United States)

    Yan, Yucong; Shan, Hao; Li, Ge; Xiao, Fan; Jiang, Yingying; Yan, Youyi; Jin, Chuanhong; Zhang, Hui; Wu, Jianbo; Yang, Deren

    2016-12-14

    Pt-based multimetallic core-shell nanoplates have received great attention as advanced catalysts, but the synthesis is still challenging. Here we report the synthesis of multimetallic Pd@PtM (M = Ni, Rh, Ru) nanoplates including Pd@Pt nanoplates, in which Pt or Pt alloy shells with controlled thickness epitaxially grow on plate-like Pd seeds. The key to achieve high-quality Pt-based multimetallic nanoplates is in situ generation of CO through interfacial catalytic reactions associated with Pd nanoplates and benzyl alcohol. In addition, the accurate control in a trace amount of CO is also of great importance for conformal growth of multimetallic core-shell nanoplates. The Pd@PtNi nanoplates exhibit substantially improved activity and stability for methanol oxidation reaction (MOR) compared to the Pd@Pt nanoplates and commercial Pt catalysts due to the advantages arising from plate-like, core-shell, and alloy structures.

  8. Electronic structure aspects of the complete O2 transfer reaction between Ni(II) and Mn(II) complexes with cyclam ligands.

    Science.gov (United States)

    Zapata-Rivera, Jhon; Caballol, Rosa; Calzado, Carmen J

    2015-01-28

    This work explores the electronic structure aspects involving the complete intermolecular O2 transfer between Ni(ii) and Mn(ii) complexes, both containing N-tetramethylated cyclams (TMC). The energy of the low-lying states of reactants, intermediates and products is established at the CASSCF level and also the DDCI level when possible. The orthogonal valence bond analysis of the wave functions obtained from CASSCF and DDCI calculations indicates the dominant superoxide nature of all the adducts participating in the reaction, and consequently that the whole reaction can be described as the transfer of the superoxide O2(-) between Ni(ii) and Mn(ii) complexes, without any additional change in the electronic structure of the fragments.

  9. Observation of high energy electromagnetic dipole radiation in /sup 14/N + Ni reactions at Esub(lab)/A = 35 MeV

    Energy Technology Data Exchange (ETDEWEB)

    Alamanos, N.; Braun-Munzinger, P.; Freifelder, R.F.; Paul, P.; Stachel, J.; Awes, T.C.; Ferguson, R.L.; Obenshain, F.E.; Plasil, F.; Young, G.R.

    1986-06-19

    High energy photons (20 < Esub(..gamma..) < 150 MeV) produced in inclusive /sup 14/N+Ni->..gamma..+X reactions were unambiguously observed in a Pb-glass detector array. The measured angular distributions exhibit a predominant dipole pattern. This rules out statistical and/or nucleon-nucleon production mechanisms. The data indicate instead a more coherent production mechanism reflecting the direction of relative motion of target and projectile.

  10. Wetting Behavior and Interfacial Reactions in (Sn-9Zn)-2Cu/Ni Joints during Soldering and Isothermal Aging

    Institute of Scientific and Technical Information of China (English)

    Ning Zhao; Haitao Ma; Haiping Xie; Lai Wang

    2009-01-01

    The wetting property of (Sn-9Zn)-2Cu (wt pct) on Ni substrate and the evolution of interfacial microstructure in (Sn-9Zn)-2Cu/Ni joints during soldering as well as isothermal aging were studied.The wetting ability of eutectic Sn-9Zn solder on Ni substrate was markedly improved by adding 2 wt pct Cu into this solder alloy.Plate-like Cu5Zn8 intermetallic compounds (IMCs) were detected in (Sn-9Zn)-2Cu solder matrix.A continuous Ni5Zn21 IMC layer was formed at (Sn-9Zn)-2Cu/Ni interface after soldering.This IMC layer kept its type and integrality even after aging at 170℃ for up to 1000 h.At the early aging stage (before 500 h), the IMC layer grew fast and its thickness followed a linear relationship with the square root of aging time.Thereafter,however, the thickness increased very slowly with longer aging time.When the joints were aged for 1000 h,a new IMC phase, (Cu,Ni)5Zn8, was found in the matrix near the interface.The formation of (Cu,Ni)5Zn8phase can be attributed to the diffusion of Ni atoms into the solder matrix from the substrate.

  11. Fiscal 2000 information collection/analysis project on basic research for coal resource exploitation. Research on technology of low-concentration methane gas recovery from underground coal mine; 2000 nendo sekitan shigen kaihatsu kiso chosa joho shushu kaiseki jigyo. Konaikutsu tanko ni okeru teinodo methane kaishu gijutsu chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Technical trends were surveyed concerning the recovery and the use as fuel of low-concentration methane gas or the like contained in the air ventilated out of coal mines. Methane gas recovery technologies include high-temperature incinerators and catalytic incinerators designed to collect heat, method of conversion of methane to CO2 using microbes named methanotrophs, and adsorption methods using activated charcoal, zeolite, or the like. Among technologies that have reached a practical level in the utilization of mine methane gas, there are the temperature regenerative flow-reversal reactor (TFRR) and the catalytic flow-reversal reactor (CFRR) utilizing high-temperature oxidation reaction. TFRR has been reported effective by MEGTEC System after a 6-month operational test of a 3.0m{sup 3}/s plant at a British coal mine. Test and research are over with CFRR, which is now ready for a commercial scale verification test. Recovery by adsorption, though worth further research efforts, is economically away from commercialization at the present stage, and wants more studies of adsorbents, etc. (NEDO)

  12. International seminar in fiscal 1998 on the development and promotion of global environment-related industrial technologies. Report on International Workshops on CO{sub 2} Cycling and Metabolism in Coral Reef; 1998 nendo chikyu sangyo gijutsu kaihatsu suishin jigyo. 'Sangosho ni okeru busshitsu ido to tanso junkan' kokusai workshop hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    For the study of CO{sub 2} absorption and fixation in the marine ecosystem, studies of coral reefs by RITE (Research Institute of Innovative Technology for the Earth) were subjected to discussion at the above-named workshops. It is after the elapse of a long geological time on the earth that CO2 in the atmosphere has arrived at the current level of concentration thanks to fixation and calcification by living organisms and to dissolution into the seawater. In the formation of CaCO{sub 3} that constitutes the coral skeleton, 1 mol Ca combines with 2 mol bicarbonates for the production of 1 mol CaCO{sub 3} and 1 mol CO{sub 2}. The reaction may suggests a consequential increase of CO2 in the atmosphere but such CO{sub 2} is in reality consumed by being converted into organic substances in a photosynthetic process performed by symbiotic algae. Calculation was made for the whole of Bora Bay, Miyakojima Island, and the result was that 700kg-C/day comes to be stored in the form of organic matters in the community of coral reef organisms. In a coral reef, even when it emits CO2 into the atmosphere, there is organic matter production which exceeds the lost CO{sub 2}. Coral reefs fix carbon out of the seawater at the rate of 0.42Gt-C/year, which is the aggregate of 0.3Gt organic matters and 0.12Gt CaCO{sub 3}. (NEDO)

  13. Effects of lithium content on the electrochemical lithium intercalation reaction into LiNiO 2 and LiCoO 2 electrodes

    Science.gov (United States)

    Choi, Young-Min; Pyun, Su-Il; Bae, Joon-Sung; Moon, Seong-In

    The electrochemical lithium intercalation reaction into LiNiO 2 and LiCoO 2 electrodes in 1 M LiClO 4—propylene carbonate solution is investigated as a function of lithium content in the oxide electrodes by using X-ray diffractometry (XRD), electrochemical impedance spectroscopy (EIS), and a galvanostatic intermittent titration technique (GITT). Li 1-δNiO 2 shows a greater loss in capacity during the first intermittent discharge, as well as a higher resistance for the electrochemical intercalation reaction, in comparison with Li 1-δCoO 2. This is attributed to a partial cation mixing in Li 1-δNiO 2 which is substantiated by XRD studies. The electrochemical impedance spectra of the Li 1-δNiO 2 electrode reveals that the magnitude of the intermediate frequency arc that is associated with the absorption reaction decreases with increasing lithium content, (1 — δ), in the range from 0.5 to 0.7. By contrast, Li 1-δCoO 2 exhibits the reverse behaviour.—The component diffusivities of lithium ions display a nearly constant value, in the order of 10 -11 cm 2 s -1, for both electrodes at room temperature, irrespective of the value of (1 — δ) over the range 0.5-0.7. It is suggested that lithium-ion diffusion through both the layered oxides is affected by the number of empty sites within the lithium-ion layer, and not by the lattice parameter.

  14. Reaction heterogeneity in LiNi0.8Co0.15Al0.05O2 induced by surface layer

    Energy Technology Data Exchange (ETDEWEB)

    Grenier, Antonin; Liu, Hao; Wiaderek, Kamila M.; Lebens-Higgins, Zachary W.; Borkiewicz, Olaf J.; Piper, Louis F. J.; Chupas, Peter J.; Chapman, Karena W.

    2017-08-14

    Through operando synchrotron powder X-ray diffraction (XRD) analysis of layered transition metal oxide electrodes of composition LiNi0.8Co0.15Al0.05O2 (NCA), we decouple the intrinsic bulk reaction mechanism from surface-induced effects. For identically prepared and cycled electrodes stored in different environments, we demonstrate that the intrinsic bulk reaction for pristine NCA follows solid-solution mechanism, not a two-phase as suggested previously. By combining high resolution powder X-ray diffraction, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and surface sensitive X-ray photoelectron spectroscopy (XPS), we demonstrate that adventitious Li2CO3 forms on the electrode particle surface during exposure to air, through reaction with atmospheric CO2. This surface impedes ionic and electronic transport to the underlying electrode, with progressive erosion of this layer during cycling giving rise to different reaction states in particles with an intact vs an eroded Li2CO3 surface-coating. This reaction heterogeneity, with a bimodal distribution of reaction states, has previously been interpreted as a “two-phase” reaction mechanism for NCA, as an activation step that only occurs during the first cycle. Similar surface layers may impact the reaction mechanism observed in other electrode materials using bulk probes such as operando powder XRD.

  15. Novel one-step synthesis of wool-ball-like Ni-carbon nanotubes composite cathodes with favorable electrocatalytic activity for hydrogen evolution reaction in alkaline solution

    Science.gov (United States)

    Chen, Zhouhao; Ma, Zhipeng; Song, Jianjun; Wang, Lixin; Shao, Guangjie

    2016-08-01

    In this work, supergravity fields are performed to prepare Ni-CNTs composite cathodes with wool-ball-like morphology from the Watts bath containing well-distributed functionalized CNTs. The prepared Ni-CNTs composite cathodes are used as noble metal-free electrocatalyst with favorable electrocatalytic activity for hydrogen evolution reaction (HER) in alkaline solutions. The crystal structure and morphology of the composite cathodes are characterized by XRD and SEM measurements. The electrochemical activities of the cathodes are characterized through Tafel polarization measurement, electrochemical impedance spectroscopy and cyclic voltammetric study in 1.0 M NaOH solution. The results indicate that catalytic activities of the Ni-CNTs cathodes prepared under supergravity fields are enhanced significantly, and the sample prepared at rotating speed 3000 rpm from the bath containing 1 g dm-3 CNTs exhibits the highest HER activity with smallest Tafel slope and largest exchange current density of 823.9 μA cm-2. Furthermore, the effects of both the CNTs concentrations and the intensities of supergravity fields on the properties of the Ni-CNTs cathodes are investigated.

  16. N-doped graphene layers encapsulated NiFe alloy nanoparticles derived from MOFs with superior electrochemical performance for oxygen evolution reaction

    Science.gov (United States)

    Feng, Yi; Yu, Xin-Yao; Paik, Ungyu

    2016-01-01

    Water splitting, an efficient approach for hydrogen production, is often hindered by unfavorable kinetics of oxygen evolution reaction (OER). In order to reduce the overpotential, noble metal oxides-based electrocatalysts like RuO2 and IrO2 are usually utilized. However, due to their scarcity, the development of cost-effective non-precious OER electrocatalysts with high efficiency and good stability is urgently required. Herein, we report a facile one-step annealing of metal-organic frameworks (MOFs) strategy to synthesize N-doped graphene layers encapsulated NiFe alloy nanoparticles (NiFe@C). Through tuning the nanoparticle size and calcination temperature, NiFe@C with an average size of around 16 nm obtained at 700 °C exhibits superior OER performance with an overpotential of only 281 mV at 10 mA cm−2 and high durability. The facile synthesis method and excellent electrochemical performance show great potential of NiFe@C in replacing the precious metal-based electrocatalysts in the OER. PMID:27658968

  17. Quantitative Analysis of Homogeneous Electrocatalytic Reactions at IDA Electrodes: The Example of [Ni(PPh2NBn2)2]2+

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Fei; Parkinson, B. A.; Divan, Ralu; Roberts, John; Liang, Yanping

    2016-12-01

    Interdigitated array (IDA) electrodes have been applied to study the EC’ (electron transfer reaction followed by a catalytic reaction) reactions and a new method of quantitative analysis of IDA results was developed. In this new method, currents on IDA generator and collector electrodes for an EC’ mechanism are derived from the number of redox cycles and the contribution of non-catalytic current. And the fractions of bipotential recycling species and catalytic-active species are calculated, which helps understanding the catalytic reaction mechanism. The homogeneous hydrogen evolution reaction catalyzed by [Ni(PPh2NBn2)2]2+ (where PPh2NBn2 is 1,5-dibenzyl-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane) electrocatalyst was examined and analyzed with IDA electrodes. Besides, the existence of reaction intermediates in the catalytic cycle is inferred from the electrochemical behavior of a glassy carbon disk electrodes and carbon IDA electrodes. This quantitative analysis of IDA electrode cyclic voltammetry currents can be used as a simple and straightforward method for determining reaction mechanism in other catalytic systems as well.

  18. Fine-sized LiNi 0.8Co 0.15Mn 0.05O 2 cathode powders prepared by combined process of gas-phase reaction and solid-state reaction methods

    Science.gov (United States)

    Ju, Seo Hee; Kang, Yun Chan

    The Ni-rich precursor powders with spherical shape and filled morphologies were prepared by spray pyrolysis from the spray solution with citric acid, ethylene glycol and a drying control chemical additive. The precursor powders with controlled morphologies formed the LiNi 0.8Co 0.15Mn 0.05O 2 cathode powders with spherical shape and fine size by solid-state reaction with lithium hydroxide. However, the cathode powders prepared from the spray solution without additives had irregular morphologies and were large in size. The precursor powders with hollow and porous morphologies formed cathode powders with irregular and aggregated morphologies. The composition ratios of the nickel, cobalt and manganese components were maintained in the as-prepared, precursor and cathode powders. The initial discharge capacity of the LiNi 0.8Co 0.15Mn 0.05O 2 cathode powders with spherical shape and fine size tested at a temperature of 55 °C under a constant current density of 0.5 C was 215 mAh g -1. The discharge capacity of the LiNi 0.8Co 0.15Mn 0.05O 2 cathode powders decreased to 81% of the initial value after 30 cycles.

  19. Does the breakup process affect the reaction dynamics for the systems 17O, 17F + 58Ni at Coulomb barrier energies?

    Directory of Open Access Journals (Sweden)

    Parascandolo C.

    2011-10-01

    Full Text Available The scattering processes of two mirror projectiles, the well bound 17O (Sn = 4.143 MeV and the loosely bound radioactive 17F (Sp = 0.600 MeV, on the proton closed shell target 58Ni were measured at several energies around the Coulomb barrier. The experimental data were analyzed within the framework of the optical model to extract the reaction cross section and to investigate the role played by direct reaction channels at near-barrier energies. The comparison shows a similar behaviour for the two A = 17 projectiles despite their very different binding energies and suggests a rather small effect of the 17F breakup channel on the reaction dynamics.

  20. Synthesis and electrochemical performance of 5V spinel LiNi0.5Mn1.5O4 prepared by solid-state reaction

    Institute of Scientific and Technical Information of China (English)

    SUN Qiang; LI Xin-hai; WANG Zhi-xing; JI Yong

    2009-01-01

    Spinel compound LiNi0.5Mn1.5O4 with high capacity and high rate capability was synthesized by solid-state reaction. At first, MnCl2·4H2O and NiCl2·6H2O were reacted with (NH4)2C2O4·H2O to produce a precursor via a low-temperature solid-state route, then the precursor was reacted with Li2CO3 to synthesize LiNi0.5Mn1.5O4. The effects of calcination temperature and time on the physical properties and electrochemical performance of the products were investigated. Samples were characterized by thermal gravimetric analysis(TGA), scanning electron microscopy(SEM), X-ray diffractometry(XRD), charge-discharge tests and cyclic voltammetry measurements. Scanning electron microscopy(SEM) image shows that as calcination temperature and time increase, the crystallinity of the samples is improved, and their grain sizes are obviously increased. It is found that LiNi0.5Mn1.5O4 calcined at 800 ℃ for 6 h exhibits a typical cubic spinel structure with a space group of Fd3m. Electrochemical tests demonstrate that the sample obtained possesses high capacity and excellent rate capability. When being discharged at a rate as high as 5C after 30 cycles, the as-prepared LiNi0.5Mn1.5O4 powders can still deliver a capacity of 101 mA-h/g, which shows to be a potential cathode material for high power batteries.

  1. Biochar supported Ni/Fe bimetallic nanoparticles to remove 1,1,1-trichloroethane under various reaction conditions.

    Science.gov (United States)

    Li, Hui; Qiu, Yue-Feng; Wang, Xiao-Li; Yang, Jie; Yu, Yun-Jiang; Chen, Ya-Qin; Liu, Yong-di

    2017-02-01

    In this study, Ni/Fe nanoparticles supported by biochar to stimulate the reduction of 1,1,1-trichloroethane (1,1,1-TCA) in groundwater remediation was investigated. In order to enhance the reactivity of ZVI (zero valent iron) nanoparticles, surface modification of ZVI was performed using nickel and biochar. The removal efficiency of 1,1,1-TCA increased from 42.3% to 99.3% as the biochar-to-Ni/Fe mass ratio increased from 0 to 1.0. However a higher biochar-to-Ni/Fe ratio showed little difference in the 1,1,1-TCA degradation efficiency. In the presence of Ni, atomic hydrogen generated by ZVI corrosion could be absorbed in the metal additive's lattice and then produce a hydride-like species (H) that represented the primary redox-active entity. The effects of various factors were evaluated, including pH, humic acid (HA) and inorganic matters (Cl(-), CO3(2-), HCO3(-), NO3(-) and SO4(2-)). The degradation of 1,1,1-TCA was greatly affected by pH. The presence of Cl(-), CO3(2-), HCO3(-) and SO4(2-) had negligible effects, but NO3(-) and HA showed a significant inhibitory effects on 1,1,1-TCA degradation. In conclusion, biochar supported Ni/Fe nanoparticles could be highly effective for 1,1,1-TCA degradation. Copyright © 2016 Elsevier Ltd. All rights reserved.

  2. Low content of Pt supported on Ni-MoCx/carbon black as a highly durable and active electrocatalyst for methanol oxidation, oxygen reduction and hydrogen evolution reactions in acidic condition

    Science.gov (United States)

    Zhang, Yan; Zang, Jianbing; Jia, Shaopei; Tian, Pengfei; Han, Chan; Wang, Yanhui

    2017-08-01

    Nickel and molybdenum carbide modified carbon black (Ni-MoCx/C) was synthesized by a two-step microwave-assisted deposition/carbonthermal reduction method and characterized by X-ray diffraction, transmission electron microscopy, energy dispersive spectroscopy and X-ray photoelectron spectroscopy. The as-prepared Ni-MoCx/C supported Pt (10 wt%) electrocatalyst (10Pt/Ni-MoCx/C) was synthesized through a microwave-assisted reduction method and 10Pt/Ni-MoCx/C exhibited high electrocatalytic activity for methanol oxidation, oxygen reduction and hydrogen evolution reactions. Results showed that 10Pt/Ni-MoCx/C electrocatalyst had better electrocatalytic activity and stability performance than 20 wt% Pt/C (20Pt/C) electrocatalyst. Among them, the electrochemical surface area of 10Pt/Ni-MoCx/C reached 68.4 m2 g-1, which was higher than that of 20Pt/C (63.2 m2 g-1). The enhanced stability and activity of 10Pt/Ni-MoCx/C electrocatalyst were attributed to: (1) an anchoring effect of Ni and MoCx formed during carbonthermal reduction process; (2) a synergistic effect among Pt, Ni, MoOx and MoCx. These findings indicated that 10Pt/Ni-MoCx/C was a promising electrocatalyst for direct methanol fuel cells.

  3. Annual energy review-1996; 1996 nen ni okeru juyona energy kankei jiko

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-07-20

    This paper reviews the important items concerned with energy in 1996. Primary energy supply sums to 529times10{sup 13}kcal increasing by 2.4% over last year. The growth rates of demand over last year are 2.5% in industry use, 3.7% in transport use, 3.7% in home use, and 1.3% in business use. On R & D trend of use technologies of energy resources, the following are described: (1) Petroleum: resource exploitation, transport, stock, refining, and petrochemistry, (2) Coal: resource exploitation, coal structure and property, processing, transport, liquefaction, gasification, carbonization, tar industry, carbon industry, and coal ash utilization, (3) Natural gas: resource exploitation, transport, storage, and conversion technology, (4) Natural energy: hydraulic, solar, geothermal, wind power, oceanic and biomass energies, and (5) Others: waste resources, hydrogen and alcohol. On R & D trend of energy conversion technology, combustion theory, boiler, engine, thermal energy system, and high-efficiency power generation technology are described. Environmental problems and their protective technologies are also described

  4. Technology of latent-heat recovery for boiler system; Boira ni okeru sennetsu kaishu gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Moriyama, T. [Tokyo Gas Co. Ltd. (Japan)

    1996-08-01

    The boiler has reached the highest degree of completion among combustion equipment and is highly efficient. In order to enhance its efficiency further, it is ordinary to recover the retention heat of the combustion exhaust gas, but due to the problem of low temperature corrosion caused by the sulfur content in fuel resulted from a temperature drop of the exhaust gas, heat recovery has been done not sufficiently. In this article, an example is introduced to plan the betterment of efficiency by application of a latent heat recovering economizer to a sugar manufactory and a report is made on the energy saving effect by recovering the latent heat and a study on the quality of the material for the latent heat reclaimer. The above latent heat reclaimer is a system which takes advantage of the feature of the natural gas reportedly having no sulfur content, brings down the temperature at the outlet of a heat exchanger of the boiler exhaust gas to below the dew point, thereby recovers the condensed latent heat of the vapor in the exhaust gas and utilizes it for heating up the boiler feed water. In this example, the line of an already installed boiler has been partially modified and only a latent heat reclaimer has been installed newly. The increase of efficiency has been as high as 5.28%. 5 figs., 5 tabs.

  5. Survey of Joint Implementation activities in China; Chugoku ni okeru kyodo jisshi katsudo kanren chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    It is a large task for Japan to positively promote the Joint Implementation activities related to the United Nations Framework Convention on Climate Change. Rapid increase in the emission of greenhouse-effect gases, especially CO2, is predicted in China with remarkable economic growth and population of 1.2 billion. It is essential to promote the Joint Implementation activities in China. In this survey, framework, organization, problems and tasks were investigated to effectively promote the Joint Implementation activities in China. Construction of framework for the real Joint Implementation activities has been proposed. Current problems for promoting the Joint Implementation activities in China are that the distinct guideline for the Joint Implementation is not established in the government, that the receiving system including receiving, planning and arranging sections is not established, and that the burden problems for the costs of project evaluation, data acquisition, monitoring, and verification are not solved. 5 refs., 21 figs., 6 tabs.

  6. Present status of geothermal power development in Kyushu; Kyushu ni okeru chinetsu hatsuden no genjo

    Energy Technology Data Exchange (ETDEWEB)

    Akiyoshi, M. [Kyushu Electric Power Co. Inc., Fukuoka (Japan)

    1997-10-20

    The present situation was introduced of the geothermal power generation in Kyushu. In Kyushu, where there are lots of volcanos and abundant geothermal resources, the geothermal exploration has been made since long ago. Three non-utility use units at three geothermal power generation points and six commercial use units at five points are now in operation in Kyushu. The total output is approximately 210 MW, about 40% of the domestic geothermal power generation. At Otake and Hacchobaru geothermal power plants, the Kyushu Electric Power Company made the geothermal resource exploration through the installation/operation of power generation facilities. At the Otake power plant, a geothermal water type single flashing system was adopted first in the country because of its steam mixed with geothermal water. At the Hacchobaru power plant, adopted were a two-phase flow transportation system and a double flashing system in which the geothermal water separated from primary steam by separator is more reduced in pressure to take out secondary steam. Yamakawa, Ogiri and Takigami power plants are all for the joint exploration. Geothermal developers drill steam wells and generate steam, and the Kyushu Electric Power Company buys the steam and uses it for power generation. 5 figs., 1 tab.

  7. Radio communication for motor sports; Motor sports ni okeru musen tsushin

    Energy Technology Data Exchange (ETDEWEB)

    Ota, K. [Kenwood Corp., Tokyo (Japan)

    2000-02-01

    This paper describes general radio communication, and radio telephone and data communication for motor sports. The radio communication for racing cars is largely disturbed by car noises and peripheral noises. The adverse effect of noises caused by on-board computer on communication, and that of radio waves on a computer are unavoidable. The radio communication is also disturbed by various radio devices in a racing circuit. As disturbance measures, change of radio frequency and filtering are necessary. For the radio telephone communication between a driver and a manager or a manager and team staffs, a close-talking microphone or a microphone with a noise canceler are used to pick up proper voices from strong roaring. However, although the frequency band of engine noises is nearly equal to that of human voices, separation of voices is extremely difficult. The car data during racing are transmitted rapidly to a pit by microwave communication, and used for the planning of a race strategy in a pit. (NEDO)

  8. Role of advanced technology in mechanical engineering. Kikai kogaku ni okeru cho no yakuwari

    Energy Technology Data Exchange (ETDEWEB)

    Koda, T. (Mechanical Engineering Lab., Tsukuba, Ibaraki (Japan))

    1992-10-05

    Since technology prefixed with 'super' is ultra-technology in another word, two kinds of work are introduced, that are on-going in the ultra-technology section in Mechanical Engineering Lab., the Ministry of International Trade and Industry. It is noted therewith that in order to realize 'super', introduction of knowledge of unfamiliar fields to mechanical engineering is one of ways. The first is a research on ion-injection onto solid surfaces by introducing quantum mechanics to mechanical engineering. Possibility of rotating new materials and physical properties is under investigation using MeV ion injection equipment. The second is a research on named 'cozy machine'. This is an example of introduction of physiological knowledge and is based on the concept that an operator can handle his machine pleasantly if it is controlled with his proper biorhythm. The possibility to form 1/f sway related to being cozy is shown using electrocardiographic signals upon which the interval of an R wave showing the largest amplitude is determined. Rotating machines are controlled in proportion to the potential. 13 refs., 3 figs.

  9. Improvement works of water quality in the enclosed area. Heisasei kaiiki ni okeru suishitsu kaizen jigyo

    Energy Technology Data Exchange (ETDEWEB)

    Sega, Y. (Ministry of Transport, Tokyo (Japan))

    1993-08-10

    This paper introduces specific examples of measures to preserve and improve water quality as adopted in the harbor environment administration to prevent pollution and create comfortable environments. In the investigation of ocean bottom purification, a test construction has been carried out using a sand covering method at Mikawa Bay. The sand covering method uses good quality sand to cover sludge on the ocean bottom to suppress dissolution of nutrients that have been revolving from the ocean bottom sludge into sea water. The method also reduces dissolved oxygen consumption in sea water by the ocean bottom sludge and improves the water quality in the area and the ecosystems. In the change of ocean bottom sludge quality in vertical distribution in the sand covered area, the COD content decreased more largely than in the current ocean bottom, but it increased more largely with lapse of time during which floating mud has precipitated. The 'sea blue' technology development project intends to implement the following activities compositely: advancement of environment improving technologies that utilize natural purification ability; environmental improvement including sludge dredging, and improving water quality and ocean bottom quality; improvement of green areas that are highly friendly with water; and application of measures to form amenity spaces. 8 figs., 3 tabs.

  10. Wood bioindustry in the 21st century. 21 seki ni okeru mokuzai bio kogyo

    Energy Technology Data Exchange (ETDEWEB)

    Haraguchi, T. (Research Association for systematic Utilization of Wood Components, Tokyo (Japan))

    1991-09-01

    For these about ten tears, technology has remarkably made progress to convert chemical contents of wood, i.e., cellulose, hemicellulose and lignin into effective materials. As for the fractionation of wood contents, a mutual bonding is noted to be physically or chemically made respectively among all cellulose, hemicellulose and lignin which are structural contents of wood cell wall. Therefore, each of those contents must be fractionated and separated to be converted and utilized, which methods comprise, among others, digestion and explosive crushing method, acetic acid digestion method, and fine powder saccharification method. For the chemical and biochemical conversion of fractionated contents, it was introduced that the hemicellulose is thoroughly hydrolyzed, converted into monosaccharide xylose, further reduced to xylitol and finally converted into xylooligosaccharide and reduced xylooligosaccharide. Also, butanediol can be biologically produced by conversion. As for the chemical and biochemical conversion and utilization of cellulose, the cellulose can be hydrolyzed to glucose with enzyme to derive sorbitol, acetone and acetic acid by fermentation, and many other kinds of material. 7 refs., 10 figs., 8 tabs.

  11. Wind turbine power generation projects supported by NEDO; NEDO ni okeru furyoku hatsuden shien jigyo

    Energy Technology Data Exchange (ETDEWEB)

    Higashino, M. [New Energy and Industrial Technology Development Organization, Tokyo, (Japan)

    1998-09-01

    The long-term energy supply/demand balance prospects, reviewed in 1998, revise the wind turbine power generation target greatly upward to 300,000kW by 2010. Outlined herein are the national wind turbine power generation projects promoted by NEDO. The wind power development field test projects investigated wind conditions in detail at 94 sites, designed systems for 31 sites and installed/operated the systems at 13 sites during the FY1995 - 1998 period. The new energy enterpriser support projects tend to be concentrated in the coastal areas facing the Sea of Japan, from Hokkaido to Tohoku/Hokuriku districts, having an annual average wind velocity in a range from 5.3 to 6.2m/s at a height of 20m from the ground. The wind turbine capacity ranges from 800kW as the minimum eligible level for the national project to 20,000kW. It is expected that the project produces relatively good results at each site. The local new energy introduction promotion projects, supported by local autonomies, have been spreading throughout Japan since FY1997. The locally supported projects are expected to be more profitable than the national projects. 4 figs., 6 tabs.

  12. Exploration under pavement by electromagnetic subsurface profiling. Hosoka ni okeru roban rosho heno haaku

    Energy Technology Data Exchange (ETDEWEB)

    Kaneko, C.; Miyatsu, Y.; Seki, M. (Construction Project Consultant Co. Ltd., Osaka (Japan))

    1994-05-01

    This paper reports explorations on change in roadbeds and subgrades under pavement by means of an electromagnetic wave method (underground radar method). The paper summarizes the measurement principle of this exploration method, the measurement equipment (consisting of a control unit, an antenna unit, and an image output unit), and data analysis and processing. It is indicated that the quality of the exploration result is governed by the antenna used, whereas a reference is shown for selecting antennas according to the exploration objects (embedded pipes, underground cavities, and pavement thickness) and depths of the explorations. The paper then lists examples of explorations conducted by using antennas with a frequency of 500 MHz. The explorations include the following cases: cavities directly below concrete seals (with a thickness of 10 cm), hume pipes (with a diameter of 10 cm) embedded in a depth of 1.1 m under asphalt pavement, clearances existing in subgrades, loosened ground bed believed to have been caused by immersion, and clearances (depth of 70 cm) existing in ground beds behind bridge piers. 5 refs., 9 figs., 2 tabs.

  13. Geophysical exploration in environmental engineering; Kankyo engineering ni okeru butsuri tansa

    Energy Technology Data Exchange (ETDEWEB)

    Shima, H. [OYO Corp., Tokyo (Japan)

    1997-12-01

    This paper describes underground environmental issues to which geophysical exploration can be applied. Especially, ground pollution, waste treatment and unexploded ordnance (mine) detection are discussed by considering worldwide technology trends through examples in Japan and the USA. Since environmental surveys are generally conducted for regional and rather shallow ground, rapidity, economy and high resolution are required for geophysical exploration. In response to these demands, a mapping system using capacitor electrodes and a complex resistivity method for detecting organic compounds are promising for the electrical prospecting. A shallow electromagnetic method is being standardized for the electromagnetic prospecting. A cesium magnetic gradient meter is also being standardized for the magnetic prospecting. An underground radar, seismic prospecting, and gravitational prospecting are also applied to some grounds. Prospecting of pollution sources, high- and low-concentration ground pollution, monitoring of pollutant removal, soundness survey of water barrier in management-type waste treatment place, and detection of unexploded ordnance are illustrated for the examples. 15 refs., 10 figs., 4 tabs.

  14. Education for hydraulics and pneumatics in Nihon University; Nihon Daigaku ni okeru yukuatsu kyoiku

    Energy Technology Data Exchange (ETDEWEB)

    Ouchi, M. [Nihon Univ., Chiba (Japan). Coll. of Industrial Technology

    2000-03-15

    Described herein is education of hydraulics and pneumatics in Nihon University. Department of Mechanical Engineering of Faculty of Production Engineering has been holding up the educational aims of bringing up engineers and researchers who have ability and intelligence to cope with internationalization and contribute to society, and of bringing about creativity, among others. Control equipment is an optional subject for the sophomore class in the second semester, and is centered by mechatronics, including hydraulic and pneumatic control systems and equipment. The related subjects include fluid dynamics, control engineering, system controlling, hydraulic machines, robotics and automobile engineering. The drill course includes disassembling and assembling gear pumps, drills on pneumatic devices, system behavior and mechatronics, experiments on fan and hydraulic control circuits and on servo mechanisms, and machinery designs and drawings. Seminars are led by full-time or part-time lecturers for the themes related to hydraulic power. Many students are interested in hydraulic and pneumatic themes for their graduation theses, because of their relations with control, environments, energy saving and so on. We are now in the age of composite technologies, and hydraulic power basics are prerequisite for engineers, and important for education of students. (NEDO)

  15. Development of a platoon driving AHS; AHS jikkensha ni okeru gunsoko seigyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Seto, Y.; Inoue, H. [Nissan Motor Co. Ltd., Tokyo (Japan)

    1997-10-01

    Nissan and the Public Work Research Institute of the Ministry of Construction are developing an Automated Highway System. We are investigating a longitudinal control system in AHS. In this paper, a vehicle control method using two actuators an engine and a brake, is described. Experimental and simulated results are shown. A Platoon driving control method using road-to-vehicle and vehicle-to-vehicle communication is described. And the influence of the communication on the control performance is shown by experiments and simulation. The effects of the communication device and control device mentioned above are verified by experimental results in an AHS field test conducted in September 1996 on a dosed highway. 5 refs., 8 figs.

  16. Magnetic prospecting in Kaibuki-yama ancient tomb; Kaibukiyama kofun ni okeru zenjiryoku sokutei

    Energy Technology Data Exchange (ETDEWEB)

    Nishitani, T. [Akita University, Akita (Japan). Mining College

    1996-10-01

    Kaibuki-yama ancient tomb located in Kumeda, Kishiwada City, Osaka has a square shape in the front and an orbicular shape in the rear, which was considered to be made in the 4th century. This ancient tomb has a total length about 135 m, a diameter of orbicular shape in the rear about 82 m, and a height about 9 m, which is a symbolical existence of the Kumeda ancient tombs. Stone chamber and stone casket made of Sanbagawa crystalline schist or rhyolitic-andesitic tuff are expected in this tomb. Magnetic prospecting in this study is accompanied with this survey. A differential type proton magnetometer was used for the measurements, which were conducted using meshes with 1 m edges. A pair of distinct positive and negative magnetic anomalies were observed in the center of orbicular shape in the rear. This coincides with a location of main body buried, which is archaeologically estimated. The magnetic anomaly might be caused by the article buried in the tomb, such as ironware, based on the measurement of magnetic intensity. From the calculated values of magnetic anomaly using a model, the buried article with magnetic anomaly was considered to have a size with length of 1 m, width of 0.1 m, and height of 0.2m. The negative magnetic anomaly could not be explained only by this. It is necessary to consider the other reasons. 8 refs., 8 figs.

  17. Characteristics of microtremors in Hanshin area; Hanshin chiiki ni okeru bido no kihon tokusei nitsuite

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, H.; Suzuki, K.; Yamanaka, H.; Seo, K. [Tokyo Institute of Technology, Tokyo (Japan)

    1996-10-01

    To increase general understandings of fundamental characteristics of microtremors in Hanshin area, microtremors have been observed at Sumiyoshi River-side, Rokko Island, and Nishinomiya. Relations were discussed among the stability of predominant period, successive fluctuation and meteorological conditions. For the analysis, cosine-type taper was conducted before and after 10% of the observed records, and Fourier spectrum was calculated by smoothing using Parzen window with a band width 0.3 Hz. Geometrical mean of two components was used as a horizontal component. At the observation points except Sumiyoshi River-side, predominance in the short period side was not distinct, and was not stable due to the successive fluctuation of predominant period. However, there was less successive fluctuation of spectrum ratio between different two points in the band with period more than 1 sec. Since there was a close correlation between the successive fluctuation in this band and the wind velocity or air pressure, the microtremors in this band was affected by a single vibration source. Ground characteristics could be illustrated by the averages of ratio against base points of moving observation. 14 refs.

  18. Detailed seismic intensity in Morioka area; Moriokashi ni okeru shosai shindo bunpu

    Energy Technology Data Exchange (ETDEWEB)

    Saito, T.; Yamamoto, H.; Settai, H. [Iwate University, Iwate (Japan). Faculty of Engineering; Yamada, T. [Obayashi Road Construction Co. Ltd., Tokyo (Japan)

    1996-10-01

    To reveal a seismic intensity distribution in individual areas, a large-scale detailed seismic intensity survey was conducted in Morioka City through questionnaire, as to the Hokkaido Toho-oki (HE) earthquake occurred on October 4, 1994 with a record of seismic intensity 4 at Morioka, and the Sanriku Haruka-oki (SH) earthquake occurred on December 28, 1994 with a record of seismic intensity 5 at Morioka. A relationship was also examined between the seismic intensity distribution and the properties of shallow basement in Morioka City. The range of seismic intensity was from 2.9 to 4.6 and the difference was 1.7 in the case of HE earthquake, and the range was from 3.1 to 5.0 and the difference was 1.9 in the case of SH earthquake. There were large differences in the seismic intensity at individual points. Morioka City has different geological structures in individual areas. There were differences in the S-wave velocity in the surface layer ranging from 150 to 600 m/sec, which were measured using a plate hammering seismic source at 76 areas in Morioka City. These properties of surface layers were in harmony with the seismic intensity distribution obtained from the questionnaire. For the observation of short frequency microtremors at about 490 points in the city, areas with large amplitudes, mean maximum amplitudes of vertical motion components more than 0.1 mkine were distributed in north-western region and a part of southern region. 4 refs., 9 figs., 1 tab.

  19. Mechatronization of rotating machines in plant; Plant ni okeru kaiten kikai no mechatronics ka

    Energy Technology Data Exchange (ETDEWEB)

    Kikuchi, H. [Chiyoda Corp., Tokyo (Japan)

    1993-10-01

    This paper introduces mechatronization of rotating machines in a plant, with application examples of electronic governors as the main subject. For centrifugal compressors, design and fabrication of anti surging control system have become possible by using a programmable logic controller (PLC) and a distributed control system (DCS) with fine scanning time. An electronic governor for turbine control has been added with a function to control amount of power generated by a motive force recovery device in a flowing catalytic cracking equipment by means of an expander inlet valve. This has made possible to operate the motive force recovery device automatically even under a low load operation. With an electronic governor to control supply and receipt amount of steam to and from an existing plant, the governor valve opening angles were so controlled that actual steam header pressure matches the setting, whereas the steam has become possible to be utilized without waste under normal operation. Operation of a comprehensive compressor/turbine monitoring system on DCS, operation of centrifugal compressors of two casings by using electromagnetic bearings, and motor speed control with use of an inverter heve also become possible. 8 figs., 2 tabs.

  20. Cogeneration system at the Showa Shell Sagamihara shopping center. Sagamihara shopping center ni okeru sekiyu cogeneration

    Energy Technology Data Exchange (ETDEWEB)

    Kameda, H. (Showa Shell Sekiyu K.K., Tokyo (Japan))

    1994-03-31

    This paper introduces a cogeneration system at the Showa Shell Sagamihara Shopping Center. The Center assumes a peak power demand of 4000 kW, thereby using utility power (not connected to the cogeneration system) at 2000 kW, and generating power by using three 1000-kW diesel engine generators. The waste heat utilizing facility consists of three steam waste heat boilers with a capacity of 614 kg/h and a pressure of 9 kg/cm[sup 2]. The steam is used as a heat source for absorption type freezers, and to recover hot water through plate-type heat exchangers. Two after-burning boilers of 2.5 tons/hour are also used to supplement shortage of steam at power peaks for room cooling with the number of boilers adjusted. The absorption-type freezer consists of two steam double-effect 500RTs which perform air conditioning by circulating cold water. A 150 RT motor-driven turbo freezer has also been installed to cover peak power demand in the summer season. All the facilities have been installed in the basement to minimize influence of vibration and noise to the surrounding districts. NOx emission has been suppressed to 400 ppm or lower by means of ammonia reducing denitrification. Low-sulfur heavy oil A is used to reduce SOx emission. The Center has obtained a specific supply permission to supply excess power of 2850 kW after in-house consumption of the power generated in the cogeneration system to the tenant shops in the Center. 7 figs., 2 tabs.

  1. Challenge of the global warming-JAMA. Chikyu ondanka mondai to jidosha sangyo ni okeru torikumi

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Y. (Japan Automobile Manufactures Association Inc., Tokyo (Japan))

    1993-04-01

    This paper summarizes the global warming problem challenged by the Japan Automobile Manufacturers Association. An investigative analysis was carried out on CO2 related data. Its gists are described as follows: The rate of contribution to CO2 emission in the automotive sector is about 17%; fuel consumption improvement has long been discussed, but is in a trend of hitting the ceiling because of the needs of mounting gears for safety improvement and of vehicle upsizing; amount of fuels used is increasing year after year; the rate of the increase correlates with the economy growth; the growth of CO2 emission from automobiles would be smaller than the values given in several reports as a result of the Japanese economic growth lower than the anticipation; effects of the fuel consumption improvement are assumed to reduce CO2 emission by several percentage points in 2000; electric vehicles could reduce CO2 emission by 40% per car if nuclear power generation is partly used; fluorocarbon used in the automobile industry is for foaming, rinsing and air conditioners, with its use in the former two applications being planned to be totally abolished; and the problem thereof exists in air conditioners, for which recovery, leakage measures, and conversion to new coolants are being discussed. 12 refs., 9 figs., 1 tab.

  2. Study of active noise control in ducts. Kanrokei ni okeru nodoteki soon seigyo hoho no kento

    Energy Technology Data Exchange (ETDEWEB)

    Nakao, Yoshiatsu

    1988-08-01

    On an active control to reduce noise in ducts, the theoretical and experimental studies of the energies ratio of the noise and the cancelling sound which should be produced by a speaker, were carried out. In case the cancelling sound was produced by the speaker which was set in the branch duct, the energies ratio varied with the setting position, the length and the cross section of the branch duct and the frequency of the noise. As the non-dimensional length of the branch duct was drawing near 0.5, the energies ratio became small. But when the non-dimensional length was 0, the ratio did not become smaller than 1. The experimental test confirmed that it was possible to reduce the noise by the cancelling sound which energies ratio was as small as about one hundredth of the noise. In case the noise was the pure sound, and the wave-length was over one fourth of the duct diameter, it was possible to reduce the noise more than 40 dB. And in case the wave-length was one eighth the reduction quantity was about 20 dB. Therefore, in case the noise is the pure sound or close to the pure sound, it is possible to apply the active noise control. 5 references, 23 figures.

  3. Refraction experiment in the Kobe-Hanshin area; Kobe Hanshin kan ni okeru kussetsuho tansa

    Energy Technology Data Exchange (ETDEWEB)

    Koketsu, K. [The University of Tokyo, Tokyo (Japan). Earthquake Research Institute

    1996-05-01

    The refraction experiments were conducted to investigate the underground structures reaching the basement by analyzing the results of the artificial earthquakes the explosion earthquake research group produced in City of Kobe and the Hanshin District on December 12 to 15, 1995. Considering that noise level can exceed 1 mkine in an urban area even in the mid-night, the courses of traverse were drawn focusing on Points S2 through S4 and U1. The earthquake waves from Points S2 through S4 are generally low in amplitude. However, the major components of the signals have a dominant frequency exceeding 10Hz, which makes them distinguishable from urban noise having a lower frequency, contrary to the previous indication that such a low-amplitude wave might not be distinguishable. On the other hand, the signals from the explosion at Point 4 in Awaji Island cannot be distinguished in the urban area, even on the nearby course of traverse D. At present, the analytical group is organized to read various phases running and analyze the P-velocity structures. 2 refs., 10 figs., 1 tab.

  4. Load averaging system for co-generation plant; Jikayo hatsuden setsubi ni okeru fuka heijunka system

    Energy Technology Data Exchange (ETDEWEB)

    Ueno, Y. [Fuji Electric Co. Ltd., Tokyo (Japan)

    1995-07-30

    MAZDA Motor Corp. planed the construction of a 20.5MW co-generation plant in 1991 for responding to an increase in power demand due to expansion of the Hofu factory. On introduction of this co-generation plant, it was decided that the basic system would adopt the following. (1) A circulating fluidized bed boiler which can be operated by burning multiple kinds of fuels with minimum environmental pollution. (2) A heat accumulation system which can be operated through reception of a constant power from electric power company despite a sudden and wide range change in power demand. (3) A circulating-water exchange heat recovery system which recovers exhaust heat of the turbine plant as the hot water to be utilized for heating and air-conditioning of the factory mainly in winter. Power demand in MAZDA`s Hofu factory changes 15% per minute within a maximum range from 20MW to 8MW. This change is difficult to be followed even by an oil burning boiler excellent in load follow-up. The circulating Fluidized bed boiler employed this time is lower in the follow-up performance than the oil boiler. For the newly schemed plant, however, load averaging system named a heat accumulation system capable of responding fully to the above change has been developed. This co-generation plant satisfied the official inspection before commercial operation according the Ministerial Ordinance in 1993. Since then, with regard to the rapid load following, which was one of the initial targets, operation is now performed steadily. This paper introduces an outline of the system and operation conditions. 10 refs.

  5. Guarantee of property right in opean access systems; Open access ni okeru zaisanken no hosho

    Energy Technology Data Exchange (ETDEWEB)

    Maruyama, M. [Central Research Institute of Electric Power Industry, Tokyo (Japan)

    1996-12-25

    This paper describes discussions in California of the USA and in Germany concerning the separation of transmission department and forced liberation of transmission network in private electric power companies and the guarantee of property right. In California, the state public utility committee does not have an authority to order the separation of transmission department against electric power companies. It is only the legislature that can conduct the separation of transmission department and the third party access of transmission network based on the expropriation provisions of the constitution. In Germany, the order of separation of transmission department by the readjusting authority contradicts the guarantee of property right in the constitution. The order of third party access also exceeds the range of duty accompanied with the property right, and the procedure of expropriation is necessary for its enforcement. Problems are pointed out in the case when these discussions are applied to the separation of transmission department, third party access, and distribution system in Japan. 3 refs.

  6. Role of geophysical exploration for civil engineering; Doboku chosa ni okeru butsuri tansa no yakuwari

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, S.; Sato, S. [OYO Corp., Tokyo (Japan)

    1997-12-01

    This paper describes the current status of applying geophysical exploration to civil engineering works, application examples of latest geophysical exploration technologies in typical civil engineering fields (dams, tunnels, banks, and civil engineering works in urban areas), and of geophysical exploration technologies specially devised at civil engineering work sites. The applications include utilization in rock classification and weathering division, estimation of grouting effect and its injection scope, determination of loosening as a result of tunnel excavation, utilization of the relationship between S-wave velocity and N-value revealed by the standard penetration test, and tunnel front exploration. A well logging technique utilizing boring holes is available as a latest technology. Tomography technology using elastic waves, specific resistance and radar has its application increased as it is used in dams, tunnels, and foundations of other important structures. Attempts are made on application of explorations using the shallow bed reflection method and three-dimensional exploration method. Frequently used technologies include seismic exploration using the refraction method for dams, high-density electric exploration for tunnels, electric exploration for banking, and PS logging using the suspension method for structure foundations. 30 refs., 13 figs., 5 tabs.

  7. Petroleum exploration and production in Japan; Nihon kokunai ni okeru sekiyu tanko to seisan

    Energy Technology Data Exchange (ETDEWEB)

    Kamon, M.

    2000-02-01

    The production of crude oil was started even in Japan from the nineteenth century to the twentieth century beginning in Niigata Prefecture, and the real petroleum industry was produced. The production has been started even in Akita Prefecture in the age in Taisho and Showa. The petroleum industry in Japan developed from the comparatively old like this. However, it is not very much known generally. Because of the oil of output is fewer than an amount of import from foreign countries. This paper describes oil gas rice pad in Japan and the production situation. (NEDO)

  8. SWD experiment at Southwest Andrews oil field; Nansei Andrews yuden ni okeru SWD jikken

    Energy Technology Data Exchange (ETDEWEB)

    Kozawa, T.; Tsuru, T. [Japan National Oil Corp., Tokyo (Japan)

    1998-04-01

    Seismic while drilling (SWD) is an accurate drilling method by which time-to-depth (T-D) information for determining the accurate bit location and information of bedding boundaries below the bit can be obtained. However, the signal level is rather low compared with the noise generated from the rig during drilling. It is required for improving the S/N ratio to calculate a correlation using reference signals simultaneously acquired using a pilot sensor which is a geophone attached to the rig. Some experiments were conducted in the Southwest Andrews Oil Field. Deterioration of data quality due to the noise particular to the SWD in this oil field could be reduced by proper data acquisition geometry including the minimum offset distance using a geophone array. In order to correct the time, a velocity of P-wave propagating the drill pipe was estimated using auto-correlation of the pilot traces. The S/N ratio was improved by the VSP deconvolution and the stacking effect during VSP-CDP conversion. Thus, could be obtained the accurate T-D information and reflection wave information below the bit. 12 refs., 19 figs., 1 tab.

  9. Steps of radioisotope separation in Japan; Nihon ni okeru doitai bunri no ayumi

    Energy Technology Data Exchange (ETDEWEB)

    Nakane, Ryohei [Institute of Physical and Chemical Research, Wako, Saitama (Japan); Kitamoto, Asashi; Shimizu, Masami [eds.

    1998-03-01

    The Extraordinary Specialist Committee on Radioisotope Separation of the Atomic Energy Society of Japan has supported various actions on foundation, application and industrialization of the radioisotope separation over past 30 years to continue wide range of actions at a standpoint of specialist, since established in Showa 44 (1969). On June 1993 (Heisei 5), a memorial lecture meeting, as the 100th committee was held at the Institute of Physical and Chemical Research (RIKEN) of Wako-city in Saitama prefecture. At that time, a planning to publish an impressive memorial issue, to prepare orbits and episodes of actions, painful stories and fault examples of developments, and so forth like novels and to use for a future foundation, was determined. For its writing principle, it was settled to the base not to use mathematical equation as possible, to collect the essence like a tale, to collect actual and historical reports, and so on. And, for its writing content, it was determined to report on actual, painful and fault experiences in research and development, on data, topics and human relation, and on what to be remained for references. This book can be used not only for data collected on traces from fundamental to applied studies, technical development for industrialization, and so forth on radioisotope concentration, but also for a knowledge bag to give some hints to a man aiming to overcome a new problem. (G.K.)

  10. Moored observation of the Indonesia throughflow; Indonesia tsuka ryuiki ni okeru keiryu kansoku kekka

    Energy Technology Data Exchange (ETDEWEB)

    Kashino, Y. [Japan Marine Science and Technology Center, Kanagawa (Japan); Watanabe, H.; Yamaguchi, H. [Sanyo Techno Marine Inc., Tokyo (Japan); Aoyama, M. [Meteorological Research Inst., Tsukuba (Japan); Herunadi, B.; Hartoyo, D.

    1998-10-16

    This paper partially reports the observation in the southern part of the Philippine Sea of the Indonesian throughflow that JAMSTEC performed jointly with the Applied Agency of Indonesian Engineering Evaluation. From February 1994 to June 1995, two mooring systems were established between the Talaud Island and Morotai Islands to examine the ocean variability of the Indonesian throughflow. As a result, a strong northwestward flow (that carries the mixed sea water of intermediate water in the North Pacific and high salt water in the South Pacific) of which the maximum flow velocity reaches 60 m/s in the southern mooring system with the water depth of 300 to 700 m was observed in each winter of 1994 and 1995. A westward flow that carries the South Pacific water toward the Maluku Sea in summer was observed in the southern mooring system. In both mooring systems, oscillation was detected at intervals of approximately 50 days. 36 refs., 15 figs., 2 tabs.

  11. Report of radioactivity survey in Kanagawa Prefecture, in 1996; Kanagawaken ni okeru hoshanochosa hokokusho, 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This report summarizes the results of 1-year survey on the radioactivities in foods and environments in Kanagawa Prefecture and the uranium level in the surroundings of Japan Nuclear Fuel Co., Ltd. (JNF), a nuclear fuel processing plant. The survey of radioactivity or radiation level was made in environments and foods including rain water, tap water, agricultural and livestock products, marine products, etc. For these subjects, analysis of nuclides and determination of spatial radiation dose rate were performed using {gamma}-ray spectrometer. Only for rain water, the general {beta} level was also determined. The uranium levels was monitored in river water and bottom materials, soil, Undaria pinnatifida, a seagrass in river mouths, etc. The present results show that there was no problem for all subjects tested in respect of radioactivity. And the uranium level around JNF was also within the normal range. The mean intake of {sup 137}Cs was 0.085 Bq/Kg/day for the residents in the district of Hiratsuka Health Center and 0.077 Bq/Kg/day for those in the Yokohama city. Both levels were slightly higher than the previous ones. The survey results before and after the returns of nuclear powered ship were also within the normal range. (M.N.)

  12. Array TDEM survey at the Yufuin fault; Yufuin danso ni okeru array shiki TDEM tansa

    Energy Technology Data Exchange (ETDEWEB)

    Mogi, T. [Kyushu University, Fukuoka (Japan). Faculty of Engineering; Tanaka, Y.; Fukuda, Y. [Kyoto University, Kyoto (Japan). Faculty of Science; Jomori, N. [Chiba Electric Research Institute Co., Chiba (Japan)

    1996-10-01

    The array arrangement of receivers was studied to improve the resolution of LOTEM (long offset transient electromagnetics) survey. To eliminate the effect of underground structure from a source to a receiving point, continuous array arrangement from a source site is desirable. The survey at the Yufuin fault was carried out by arranging TEM receivers at intervals of 100m from the source. Since the synchronization between transmitting and receiving points by high-precision clock is essential, an amplifier for a flux gate magnetometer capable of measuring at four points at the same time was used. In the south plateau of the Yufuin basin, a relatively high resistivity stratum more than several tens ohm m exists at depth less than several hundreds meter, and a low resistivity stratum less than 10 ohm m exists under that. Those boundary depth increases toward the north up to 950m, and the depth subsequently decreases toward the north until the low resistivity stratum disappears. In addition, the uniform stratum of 1000m deep continues toward the north. Such precise resistivity structure around the fault was obtained by dense arrangement of measuring points. 4 refs., 7 figs.

  13. Fate of dioxins in aquatic environment; Mizukankyo ni okeru dioxin rui no dotai

    Energy Technology Data Exchange (ETDEWEB)

    Sakurai, T. [National Inst. for Environmental Studies, Tsukuba (Japan)

    1998-07-10

    Described herein is fate of dioxins in aquatic environments, from their estimated origins to behavior in the food chains. It is considered that dioxins and their congeners generally follow principle of superposition in aquatic environments, although reflecting changed environments they have underwent, in consideration of varying sources from which they originate, and their stability and transport-related properties. Therefore, the multivariable analysis is applied to correspondence of the four major dioxin compounds, which can explain the major concentration changes of the dioxins found in the sediments and soil in Lake Kasumi-ga-ura and the Bay of Tokyo and their peripheries, to their origins. Different dioxins behave differently in the food chains, as revealed by isotope ratios in the ecology. Mathematical models have been developed to estimate concentrations of the various media, and are expected to clarify their behavior in the environments. 32 refs., 3 figs., 1 tab.

  14. Evaluation technology of lead-free solders; Namari free handa zairyo ni okeru hyoka gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Yamashita, M.; Shiokawa, K. [Fuji Electric Co. Ltd., Tokyo (Japan); Ueda, A. [Fuji Electric Corporate Research and Development,Ltd., Kanagawa (Japan)

    2000-09-10

    Solders mainly composed of tin and lead are currently in widespread use in semiconductor devices. However, in view of lead influences on the human body and environmental problems, lead-free solders have been in urgent demand. In this study, aiming to improve the solderability and reliability of a tin-silver solder, one of most promising lead-free solder materials, we have investigated elements to be added. Focusing on typical lead-free tin-silver solders and tin-lead eutectic solders, this paper describes the result of investigations into the mechanical properties solderability, micro structures of the solder materials and gas analysis in soldering. (author)

  15. Problems of adhering organisms in power stations. Hatsudensho ni okeru fuchaku seibutsu no mondai

    Energy Technology Data Exchange (ETDEWEB)

    Sakaguchi, Isamu (Central Research Inst. of Electric Power Industry, Tokyo (Japan))

    1989-01-05

    Much seawater is used in thermal power station in Japan to cool condensers but organisms adhered on the water channel system result many troubles such as increase of flowing resistance, reduction of thermal transfer efficiendy, corrosion or erosion-corrosion of condenser pipes, and cleaning difficulty for periodic inspection. Living organisms range from micro bacteria of 2 mum to oysters and others of about 10cm size. For these reasons, the intake open channel is previously designed to larger size and this margin is called the shellfish allowance. Mussels which adhere most on circulating water channels, are one of Bivalvia, grow to 3-6cm and in maximum case to 9cm in a year. These adhere on the surface base by secreting adhesive disc consisting of byssus. Barnacles are one of Crustacea and their larvas search preferable places as to light, roughness and water flow and can adhere on a place in considerably rapid water flow. Other organisms are bacteria and Hydrozoa. Many problems are caused by these organisms even now. 8 refs., 3 figs., 2 tabs.

  16. Measures taken for recycling at beer breweries; Beer kojo ni okeru saishigenka eno torikumi

    Energy Technology Data Exchange (ETDEWEB)

    Yamazaki, M. [Kirin Breweri Company, Tokyo (Japan)

    1999-08-05

    Full recycling of waste was achieved in our all breweries in 1998. This paper introduces the history to solve the problems relating to waste in our beer brewerise, our basic consideration for recycling, the status of waste generation and recycling activities, our measures taken for recycling and its relating cost, and in addition, the general measures taken by our industry as a whole. (author)

  17. Human physiology and psychology in space flight; Uchu hiko ni okeru ningen no seiri to shinri

    Energy Technology Data Exchange (ETDEWEB)

    Murai, T. [National Space Development Agency of Japan, Tokyo (Japan)

    1999-10-05

    Human beings' adaptation to space and the effects on them of a prolonged stay in space are discussed. Some effects may be detrimental to crewmen even when they are medically judged as 'normal' and 'adaptable.' Bone deliming, muscular atrophy, and hypodynamia may be physiologically 'normal' and 'adaptable' in the zero-gravity environment where no strength is required to hold a position or attitude, and they will not cause any serious problems if crewmen are to stay in the zero-gravity environment permanently. Astronauts work on conditions that they return to the earth, however, and they have to stand on their own legs when back on the ground. Such being the case, they in the space vehicle are forced to make efforts at having their bone density and muscular strength sustained. It is inevitable for a space station to be a closed, isolated system, and the crewmen have to live in multinational, multicultural, and multilingual circumstances in case the flight is an international project. They will be exposed to great social and psychological stresses, and their adaptability to such stresses presents an important task. (NEDO)

  18. Use of natural energy in hyper-skyscrapers. Chocho koso kenchiku ni okeru shizen energy riyo

    Energy Technology Data Exchange (ETDEWEB)

    Unno, K. (Takenaka Komuten Co. Ltd., Osaka (Japan))

    1992-05-30

    Construction of large scale hyper-skyscrapers( more than 500 m high ) by next century is coming to inevitable stage, and the problems regarding supply and consumption of energy/resources together with the use of natural energy in such construction are described. Transport of water at high direction, conformity of supply and save energy are pointed out as problems for supplying water energy. Calculated amount of required electrical energy used by electrical appliances of sky-city ( 1000 m high ) has been about 440,000 KVA, and necessity of autonomous supply network system for electric power and heat supply is stressed. For sky-city, 1000 m, use of new energy( supply of 20% of total electric power is possible with optical generation, wind power generation) and the use of unused energy ( draft generations, generation from refuse incineration, pumped storage generation ) are emphasized. Effective supply of water resource like refuse of waste water is cited. 3 refs., 4 figs., 1 tab.

  19. Port construction projects in Sabah, Malaysia; Malaysia Sabah shu ni okeru kowan koji

    Energy Technology Data Exchange (ETDEWEB)

    Fukuwaka, M.; Ichinose, Y. [Kawasaki Steel Corp., Tokyo (Japan)

    1996-04-15

    This paper introduces civil engineering circumstances in Sabah, Malaysia through harbor constructions in the past decade. The state of Sabah has a large number of good natural harbors with coast lines formed complexly, and these harbors are managed and operated by the Sabah Harbor Department since 1968. The first two-decade long-term plan (1976 to date) has developed major harbors, and the second two-decade plan (1992 to 2012) has selected important harbors and is moving new improvements forward. Export of woods and imports of general consumer goods and industrial products had been the major activities of the ports before the 1980`s, while wood export has changed from logs to lumbers, and palm oil export and fertilizer import have increased after the 1990`s. The paper describes renewal and expansion constructions of harbor facilities at Kota Kinabalu Port, and constructions at the harbor for rationalization in containerization, and for building a movable pier for ferry use. At Lahad Datu Port, constructions for building container yards and new piers are in progress as the expansion constructions as of 1996. Because the construction sites are located in maritime tropical rain forest climate with high temperature and much rainfall, attentions are paid on concrete placement temperatures and quality control. 7 figs.

  20. Advanced technology trend survey of micromachines in Europe; Oshu ni okeru micromachine sentan gijutsu doko chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-01

    In this research survey, the development trend of micromachine technology in Europe was surveyed, development level of micromachine technology of European companies was grasped, and practical application fields of their target were investigated. Technology development level of private companies in Japan`s national projects and practical application fields of Japan`s target were arranged. Trends of micromachine technology development are compared between Japanese companies and European companies. Among micromachine technology development projects in Europe, ``8520 MUST`` is a part of the ESPRIT Project. About 40,000 companies among about 170,000 companies in whole Europe are relating to the MUST Project. The main fields include the manufacturing technology, process control of machines, technology of safety, sensor technology in environmental fields, and automotive technology. The marketing fields of application include the automobile, military technology, home automation, industrial process, medical technology, environmental technology, and games. The results can be compared with the direction of research and development in Japan. 22 figs., 8 tabs.

  1. Solar energy drying for agricultural products. Nosanbutsu kanso ni okeru taiyonetsu riyo

    Energy Technology Data Exchange (ETDEWEB)

    Sato, Jun' ichi (National Grassland Research Inst., Tochigi, (Japan))

    1989-09-30

    Natural drying was previously used to dry agricultral products but artificial drying is widely used today with the diffusion of agricultural machines. Therefore, solar energy utilization to dry agricultural products depends on how effective solar energy is utilized in addition to the mechanized artificial drying. Further, drying of agricaltural products varies in respective countries and local areas because water content in products varies on weather conditions. Wheats harvested in U.S. contain fewer water content and can be dried for 3 months in a large storing bin by natural ventilation and cn be shortened to 1 month by placing a solar collector before the blower. Many Japanese farmers utilize vinyl houses and drying is made by combining vinyl house, and flat floor type dryer, circulating dryer or rotary stirring dryer. Moreover, 100% utilization of solar enegy results higher cost, so that in many cases, combined utilization with oil firing is made. Moderate heat such as solar energy is suitable for drying of agricultural products to maintain the quality and it is desirable to develop any reasonal technique. 14 refs., 12 fig.

  2. Investigations on an environment friendly chemical reaction process (eco-chemistry). 2; Kankyo ni yasashii kagaku hanno process (eko chemistry) ni kansuru chosa. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    In order to structure a chemical reaction process that does not discharge a large amount of waste by-products or harmful chemical substances, or so-called environment friendly process, investigations and discussions were given based on the results derived in the previous fiscal year. A proposal was made to reduce environmental load on development of oxidized and dehydrogenated catalysts that can produce selectively ethylene, propylene and isobutylene in an oxidation process. In liquid phase oxidation, redox-based oxidation and solid catalyzation of automatic oxidation reaction were enumerated. In acid base catalyst reaction, development of ultra strong solid acid was described to structure no pollution discharging process. In the fine chemical and pharmaceutical fields, the optical active substance method and the position-selective aromatics displacement reaction were evaluated to reduce environmental load. A questionnaire survey performed on major chemical corporations inside and outside the country revealed the following processes as the ones that can cause hidden environmental problems: processes discharging large amount of wastes, processes treating dangerous materials, and processes consuming large amount of energy. Development of catalysts is important that can realize high yield, high selectivity and reactions under mild conditions as a future environment harmonizing chemical process. 117 refs., 23 figs., 22 tabs.

  3. Interface Physical Chemistry of Enamel (3). Action of Cobalt at Enamel Reaction; Horo ni kansuru kaimen butsurikagakuteki kenkyu (3). Horo kaimen ni oyobosu kabaruto no sayo

    Energy Technology Data Exchange (ETDEWEB)

    Shirasaki, Masahiro.; Shimizu, Tadao.; Kozuka, Tatsuya. [Chiba Institute of Technology, Chiba (Japan), Department of Industrial Chemistry; Jiang, Zhaohua. [Harbi Institute of Technology, Harbin (China), Department of Applied Chemistry

    1999-02-01

    The effect of cobalt on enamel reaction was studied using Co-vitreous enamel. Observation and analysis of Co-vitreous enamel interface were performed with scanning electron microscope, X-ray photoelectron spectrometer and X-ray diffractometer. The following results were obtained. (1) The sunken parts of Co-vitreous enamel interface were formed by erosion of the base iron. Cobalt and iron deposited on the base iron and formed convex parts. Further, the convex parts grew by firing from the initial interface towards the glass (enamel layer) side. (2) Interface layer of Co-vitreous enamel was consisted of two layers. The first interface layer was very thin and consisted of CoFe{sub 2}O{sub 4} or FeFe{sub 2}O{sub 4}. The second interface layer was the iron solid solution containing cobalt. The thickness of Co-vitreous enamel reaction layer was thicker than the rough parts (3) The Co-vitreous enamel reaction was a galvanic cell reaction between base iron and cobalt ion in glass. Cobalt circulate by reaction as deposition, oxidation and dissolution. (author)

  4. Electrochemical performance in the hydrogen evolution reaction of Ni-TR (TR= La, Ce) materials synthesized using the solid state reaction method; Desempeno electroquimico en la reaccion de evolucion de hidrogeno de materiales de electrodo Ni-TR (TR = La, Ce) sintetizados por el metodo de reaccion de estado solido

    Energy Technology Data Exchange (ETDEWEB)

    Torres-Huerta, A. M.; Dominguez-Crespo, M. A.; Ramirez-Meneses, E.; Yanez-Zamora, C. [CICATA, IPN, Altamira, Tamaulipas (Mexico); Avila-Garcia, I. [IPN, ESIQIE, UPALM, Mexico, D.F. (Mexico)]. E-mail: mdominguezc@ipn.mx; adcrespo2000@yahoo.com.mx

    2009-09-15

    At the industrial level, the use of fuel cell technology is still limited because of the high costs of its parts and costs related to its operations. Although the electrode material with greater electroactivity is Pt, because of its high cost, alternative electrocatalysts have been sought that balance cost and activity. One of the materials that have been most widely used is nickel, along with some of its alloys. This material has shown good performance using low overpotentials in traditional reactions such as hydrogen (HER) and oxygen (OER) evolution, as well as high resistance to corrosion and low costs. In particular, binary and ternary alloys have shown significant increases in HER activity when compared to materials in the pure or massive state. Therefore, in the search for new alternatives with acceptable efficiency and low-cost, this work obtained Ni-TR (TR = La, Ce) using solid-state reaction with metallic acetylacetonates and metallic powder. These materials were synthesized for 3 h at different temperatures (795 or 920, 1000 and 1200 degrees Celsius) in order to evaluate the effect on the electrochemical performance of the electrocatalysts. The structural and morphological characterization of materials was performed with XRD and SEM techniques, respectively. In addition, the electrochemical performance of electrode materials was evaluated with HER using cyclic voltametry (CV) and potentiodynamic curves. The results obtained show that a combination of oxides was obtained (NiO, CeO{sub 2} and LaNiO{sub 3}) at low temperatures; nonetheless, as the synthesis temperatures increase, NiO-CeO{sub 2} and NiO-LaNiO{sub 3} alloys are formed, respectively. A clear dependence was also observed between electrocatalytic activity and the source for obtaining these materials(Ni-TR). [Spanish] A nivel industrial, el uso de la tecnologia de celdas de combustible esta todavia limitada debido sobre todo a los altos costos de las partes que la constituyen y los costos

  5. Combustion synthesis by reaction and characterization of structural Ni-Zn ferrite doped with copper; Sintese por reacao de combustao e caracterizacao estrutural de ferritas Ni-Zn dopadas com cobre

    Energy Technology Data Exchange (ETDEWEB)

    Dantas, J.; Santos, J.R.D.; Cunha, R.B.L.; Feitosa, C.A.; Costa, A.C.F.M., E-mail: joeldadantas@yahoo.com.br, E-mail: jakelineedm@gmail.com [Universidade Federal de Campina Grande (LabSMac/UFCG), PB (Brazil). Lab. de Sintese de Materiais Ceramicos

    2012-07-01

    The present stud aims to evaluate the effect of doping with Cu{sup 2+} ions concentrations of 0.0, 0.1, 0.2, 0.3 and 0.4 mol in the synthesis and structure of Ni-Zn ferrite. Samples were synthesized by the method of the combustion reaction and characterized by measuring the temperature as a function of reaction time, X-ray diffraction (XRD) and infrared spectroscopy in Fourier transform (FTIR). The combustion temperature and time were 646, 900, 989, 975 and 735°C and 210, 175, 220, 210 and 110 seconds for the sample doped with 0.0, 0.1, 0.2, 0.3 and 0.4 mol of copper, respectively. XRD results show that all concentrations of copper evaluated, there was only a training phase inverse spinel ferrite and Ni-Zn FTIR spectra show absorption bands below 1000cm{sup -1}, which are characteristics of the spinel type AB{sub 2}O{sub 4-} (author)

  6. LaNiO3-based catalyst in gas diffusion electrodes: activity and stability for oxigen reactions

    OpenAIRE

    R.A. Silva; Soares, C. O.; CARVALHO, M. D. de; Jorge, M. E. Melo; Gomes, A.; C. M. Rangel; Pereira, M. I. da Silva

    2013-01-01

    Perovskite-type oxides are potential catalysts for next generation of regenerative fuel cells. In particular, LaNiO3 has been recognised as one of the most promising oxygen electrodes. In this work LaNiO3 perovskite-type oxides, prepared by a self-combustion method [1, 2], have been used for the preparation of porous gas-diffusion electrodes (GDE). Electrodes were prepared on Toray carbon paper (CP) substrates, consisting of a diffusion layer, a catalyst layer and a Nafion® layer. The gas...

  7. Ni(0-CMC-Na Nickel Colloids in Sodium Carboxymethyl-Cellulose: Catalytic Evaluation in Hydrogenation Reactions

    Directory of Open Access Journals (Sweden)

    Abdallah Karim

    2011-01-01

    Full Text Available A recyclable catalyst, Ni(0-CMC-Na, composed of nickel colloids dispersed in a water soluble bioorganic polymer, sodium carboxymethylcellulose (CMC-Na, was synthesized by a simple procedure from readily available reagents. The catalyst thus obtained is stable and highly active in alkene hydrogenations.

  8. Characterization of quasi-nano-sized TiCx-Ni-Fe thin composite sheet prepared by using self-propagating high-temperature synthesis reaction and electroforming

    Science.gov (United States)

    Choi, Yong

    2014-05-01

    Thin TiCx-Ni-Fe composites sheet was prepared by self-propagating high-temperature synthesis (SHS) and electroforming. The quasi-nano-sized titanium carbide particles were prepared by self-propagating high temperature synthesis (SHS) followed by mechanical milling and ultrasonic floating agitation for classifying particles. The composite sheet was fabricated by co-deposition of the classified titanium carbide particles in a modified Watts nickel bath containing iron chloride during nickel-iron electro-forming. Neutron diffraction showed that the non-stoichiometric number of titanium carbides formed by the SHS reaction were in the range of 0.68 to 0.97, which depended on the initial carbon sources. X-ray diffraction and electron probe micro-analysis revealed that co-deposition of the carbides in Ni-Fe bath during the electroforming process produced a thin TiCx-Ni-Fe composite sheet, in which quasi-nano-sized titanium carbides were embedded about 7 at.%. The average surface resistance of the thin composite sheet was 1.053 ohm/sq. The corrosion potential and rate of the composites in a 50% NaOH solution were -920.6 mVSHE and 8.4×10-6 Acm-2, respectively.

  9. Structural, dielectric and conductivity studies of LiNi0.75Mg0.25-xCuxPO4 synthesized by solid state reaction method

    Directory of Open Access Journals (Sweden)

    Kotamalige Anand

    2016-03-01

    Full Text Available The olivine structured LiNi0.75Mg0.25-xCuxPO4 (x = 0, 0.05 and 0.1 cathode materials were synthesized by solid state reaction method. The XRD, FTIR and FESEM studies were conducted to investigate the phase purity, crystal structure, lattice parameters and morphology, respectively. The powder X-ray diffraction studies confirmed the single phase formation of the pure and doped compounds which are found to be orthorhombic with the parent LiNiPO4. Morphology and grain sizes of the materials were investigated through FESEM. The FTIR technique was used to characterize the stretching and bending vibrational modes of different functional groups existing in the materials. The cathode properties were analysed through impedance spectroscopy and indicated on improved electrical properties of the doped samples as compared to the pure LiNiPO4. The conductivity and modulus analyses of the samples were carried out at different temperatures and frequencies using the complex impedance spectroscopy technique.

  10. Mesoporous NiCo2O4 Nanoplates on Three-Dimensional Graphene Foam as an Efficient Electrocatalyst for the Oxygen Reduction Reaction.

    Science.gov (United States)

    Tong, Xili; Chen, Shuai; Guo, Congxiu; Xia, Xinhui; Guo, Xiang-Yun

    2016-01-21

    Catalysts for the oxygen reduction reaction (ORR) are highly important in fuel cells and metal-air batteries. Cheap ORR catalysts with ultrahigh electrochemical activity, selectivity, and stability are extremely desirable but still remain challenging. Herein, mesoporous NiCo2O4 nanoplate (NP) arrays on three-dimensional (3D) graphene foam are shown to be a highly economical ORR catalyst. This mesoporous mixed-valence oxide can provide more electrocatalytic active sites with increased accessible surface area. In addition, graphene-foam-supported NiCo2O4 NP arrays have a 3D hierarchical porous structure, which is of great benefit to ion diffusion and electron transfer. As a result, the mesoporous NiCo2O4 NP arrays/graphene foam catalyst exhibits outstanding ORR performance with the four-electron reduction of O2 to H2O in alkaline media. Furthermore, the mesoporous catalyst shows enhanced electrocatalytic activity with a half-wave potential of 0.86 V vs RHE and better stability compared with a commercial Pt/C catalyst.

  11. Chelator profiling in Deschampsia cespitosa (L.) Beauv. Reveals a Ni reaction, which is distinct from the ABA and cytokinin associated response to Cd.

    Science.gov (United States)

    Hayward, Allison R; Coates, Kahlan E; Galer, Amy L; Hutchinson, Thomas C; Emery, R J Neil

    2013-03-01

    Plant hormones, including abscisic acid (ABA) and cytokinins (CKs), fluctuate as a result of excess metal exposure. Changes in hormonal concentration regulate plant growth and may also signal activation of metal chelators. The grass Deschampsia cespitosa was dosed with either Ni or Cd or pulsed with exogenous ABA. The roots were analyzed for ABA and CKs and for multiple potential metal chelators including: amino acids, nicotianamine (NA), and phytochelatins (PCs). They were quantified after 3 h and after 7 days, using LC-ESI MS/MS. The Ni treatment caused no measurable change in ABA or CK concentration; however, an increase in NA was documented. The Cd treatment resulted in a short-term ABA increase followed by a reduction in CKs and an increase in PC concentration. An exogenous ABA pulse in non-metal challenged plants induced changes in CKs and PCs that followed those of Cd treatment. Ni and Cd stress resulted in distinctly different detoxification responses. Since the reaction of CKs and putative metal chelators to Cd stress can be mimicked by an exogenous ABA pulse, it is suggested that ABA acts as a stress signal, resulting in reduced growth by way of decreased CK concentration and reduced metal toxicity through increased PC production.

  12. A new synthesis of enantiomerically pure syn-(S)-β-hydroxy-α-amino acids via asymmetric aldol reactions of aldehydes with a homochiral Ni(II)-glycine/(S)-BPB Schiff base complex

    NARCIS (Netherlands)

    Belokon, Yuri N.; Kochetkov, Konstantin A.; Ikonnikov, Nikolai S.; Strelkova, Tatiana V.; Harutyunyan, Syuzanna R.; Saghiyan, Ashot S.

    2001-01-01

    syn-(S)-β-Hydroxy-α-amino acids were synthesised stereoselectively via elaboration of the asymmetric aldol reactions of aldehydes with a chiral Ni(II)-(S)-BPB/glycine Schiff base complex in the presence of equimolar NaH in THF. The stereoselectivity of the reaction was studied as a function of time,

  13. Effects of CeO2 on structure and properties of Ni-Mn-K/bauxite catalysts for water-gas shift reaction

    Institute of Scientific and Technical Information of China (English)

    JIANG Lilong; YE Binghuo; WEI Kemei

    2008-01-01

    Multiple-metal catalysts (Ni-Mn-Ce-K/bauxite) for Water-Gas Shift (WGS) reaction were prepared by impregnation, and the catalytic structure and properties were investigated by N2 physical, XRD, H2-TPR, and CO-TPD. The results indicated that the addition of 7.5% CeO2 improved the activity of the WGS reaction obviously, and also increased the specific surface area and pore volume of the catalysts. The addition of CeO2 decreases the reduction temperature, enhanced the adsorption and activation of H2O, and improved the adsorption content of CO. Besides, active sites were not changed and the number of active sites on catalysts did not increase obviously.

  14. Ni/MgAlO regeneration for catalytic wet air oxidation of an azo-dye in trickle-bed reaction

    Energy Technology Data Exchange (ETDEWEB)

    Vallet, Ana [Grupo de Catálisis y Procesos de Separación (CyPS), Departamento de Ingeniería Química, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Avda. Complutense s/n, 28040 Madrid (Spain); Ovejero, Gabriel, E-mail: govejero@quim.ucm.es [Grupo de Catálisis y Procesos de Separación (CyPS), Departamento de Ingeniería Química, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Avda. Complutense s/n, 28040 Madrid (Spain); Rodríguez, Araceli [Grupo de Catálisis y Procesos de Separación (CyPS), Departamento de Ingeniería Química, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Avda. Complutense s/n, 28040 Madrid (Spain); Peres, José A. [Centro de Química de Vila Real, Universidade de Trás-os-Montes e Alto Douro, Apartado 1013, 5001-801 Vila Real (Portugal); García, Juan, E-mail: juangcia@quim.ucm.es [Grupo de Catálisis y Procesos de Separación (CyPS), Departamento de Ingeniería Química, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Avda. Complutense s/n, 28040 Madrid (Spain)

    2013-01-15

    Highlights: ► Ni supported over hydrotalcite calcined precursors as catalyst. ► Catalytic wet air oxidation in trickle bed reactor for Chromotrope 2R removal. ► Dye removal depends on temperature, initial dye concentration and flow rate. ► The catalyst proved to bare-usable after in situ regeneration. -- Abstract: Active nickel catalysts (7 wt%) supported over Mg–Al mixed oxides have been recently developed and it has also been demonstrated that they are also highly selective in Catalytic Wet air Oxidation (CWAO) of dyes. CWAO of Chromotrope 2R (C2R) has been studied using a trickle bed reactor employing temperatures from 100 to 180 °C, liquid flow rates from 0.1 to 0.7 mL min{sup −1} and initial dye concentration from 10 to 50 ppm. Total pressure and air flow were 25 bar and 300 mL min{sup −1}, respectively. The catalyst showed a very stable activity up to 24 h on stream with an average TOC conversion of 82% at 150 °C and T{sub r} = 0.098 g{sub Ni} min mL{sup −1}. After the reaction, a 1.1 wt% C of carbonaceous deposit is formed onto the catalyst and a diminution of 30% of the surface area with respect of the fresh catalyst was observed. An increase in the space time gave higher TOC conversions up to T{sub r} = 0.098 g{sub Ni} min mL{sup −1}, attaining values of 80% at 180 °C. The performance of TOC and dye removal does not decrease after two regeneration cycles. In total, a 57 h effective reaction has been carried out with no loss of catalytic activity.

  15. Ni/MgAlO regeneration for catalytic wet air oxidation of an azo-dye in trickle-bed reaction.

    Science.gov (United States)

    Vallet, Ana; Ovejero, Gabriel; Rodríguez, Araceli; Peres, José A; García, Juan

    2013-01-15

    Active nickel catalysts (7 wt%) supported over Mg-Al mixed oxides have been recently developed and it has also been demonstrated that they are also highly selective in Catalytic Wet air Oxidation (CWAO) of dyes. CWAO of Chromotrope 2R (C2R) has been studied using a trickle bed reactor employing temperatures from 100 to 180 °C, liquid flow rates from 0.1 to 0.7 mL min(-1) and initial dye concentration from 10 to 50 ppm. Total pressure and air flow were 25 bar and 300 mL min(-1), respectively. The catalyst showed a very stable activity up to 24 h on stream with an average TOC conversion of 82% at 150 °C and T(r)=0.098 g(Ni) min mL(-1). After the reaction, a 1.1 wt% C of carbonaceous deposit is formed onto the catalyst and a diminution of 30% of the surface area with respect of the fresh catalyst was observed. An increase in the space time gave higher TOC conversions up to T(r)=0.098 g(Ni) min mL(-1), attaining values of 80% at 180 °C. The performance of TOC and dye removal does not decrease after two regeneration cycles. In total, a 57 h effective reaction has been carried out with no loss of catalytic activity.

  16. Ferritas Ni-Zn: síntese por reação de combustão e sinterização Ni-Zn ferrites: combustion reaction synthesis and sintering

    Directory of Open Access Journals (Sweden)

    A. C. F. M. Costa

    2003-09-01

    Full Text Available Este trabalho apresenta o estudo da síntese por reação de combustão e sinterização de pós nanométricos de ferritas Ni-Zn. O efeito da concentração de Zn2+ no sistema Ni1-xZn xFe2O4 foi investigado. Os pós resultantes da combustão foram caracterizados por DRX, BET, MEV, picnometria de hélio e sedimentação (Horiba. Em seguida foram prensados uniaxialmente e sinterizados com taxa constante de aquecimento (TCA de 5,0 ºC/min de 600 ºC até a temperatura de 1200 ºC, em um dilatômetro horizontal. Os compactos foram caracterizados por microscopia eletrônica de varredura. Os resultados mostram que foi possível obter pós de ferritas Ni-Zn com tamanho de partícula entre 18 - 27 nm usando a síntese por reação de combustão. Durante sinterização dos pós nanométricos observou-se três estágios distintos, os quais foram identificados através da Teoria de Bannister. A adição do Zn2+ não modificou o mecanismo de sinterização nos três estágios. Para os estágios inicial e final o mecanismo predominante foi por fluxo viscoso, atribuído ao rearranjo estrutural das nanopartículas e para o estágio intermediário foi difusão volumétrica.This work presents the study of the synthesis for combustion reaction and sintering of Ni-Zn nanometric ferrite powders. The effect of the concentration of Zn2+ in the system Ni1-xZn xFe2O4 was investigated. The resulting powders of the combustion were characterized by DRX, BET, MEV, picnometry of helium and sedimentation (Horiba. Uniaxially pressed samples were sintered with constant heating rate (TCA of 5.0 ºC/min from 600 ºC to the temperature of 1200 ºC, in a horizontal dilatometer. The compact ones were characterized by scanning electron microscopy. The results show that was possible to obtain Ni-Zn ferrite powders with particle size among 18 - 27 nm using combustion reaction synthesis. During sintering of the nanometric powders it was observed three different stages, which were

  17. Waste gas treatment technology at steelmaking plants. Seitetsu setsubi ni okeru hai gas shori gijutsu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, M.; Shimizu, K.; Deshimaru, K.; Watari, S. (Nihon Univ., Narashino, Chiba (Japan). Coll. of Industrial Technology)

    1992-11-30

    A variety of furnaces are employed for steelmaking. The waste gases from these furnaces are used as fuel gases or flared to the atmosphere. For the enhancement of energy efficiency at these plants and the improvement of environment, it is essential to remove the impurities contained in the waste gases, such as soot, dust, NOx and SOx with high efficiency at the lowest possible cost. In coke oven and sintering furnace, soot and dust consisting of sulphuric element, cyanogenic element and fume of alkali metals as main constituents are the subject of treatment, because these elements were contained in the raw materials. And, in blast furnace and LD converter, soot and dust are the subject of treatment because the materials have already been treated under high-temperature and the waste gases contain little chemical impurities consequently. On the other hand, in various combustion furnaces, purified by-product gases, such as the above mentioned BFG (blast furnace gas), LDG (LD converter gas) and COG (coke oven gas), etc., are used frequently and NOx generated by the high-temperature combustion is often the subject of treatment. In this report, the waste gas treatment technology developed by Nippon Steel Corporation for these various furnaces was described. 10 figs., 2 tabs.

  18. Trends in developing alternative energies in Sweden. Sweden ni okeru daitai energy kaihatsu no doko ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Maruyama, S. (The Kansai Electric Power Co. Inc., Osaka (Japan))

    1992-07-10

    This paper introduces a summary of the survey made on the Swedish policies on alternative energies. The country has a characteristic that the alternative energy policies have a great importance for each political party as its reigning strategy. The largest weight for the alternative energies is placed on bioenergies. Sweden has been already depending on bioenergies at 15% of the country[prime]s total energy supply. Nearly half amount of the budget in the new five-year alternative energy plan approved in 1991 is bioenergy related. The budget of 3.76 billion kronor can be broken down into 1 billion kronor for effective energy utilization, 1.92 billion kronor for bio-fuel utilization, and 800 million kronor for bio-fuel utilizing plants. The bio-fuel utilizing plants include improved CFB utilizing steam cycle power generation, gasified compound cycle power generation, a bio-fuel/natural gas compounding plan, and a bio-fuel/caustics recovery boiler compounding plan, each having merits and demerits. Thirty-five wind power generating plants are in operation producing a total power of about 10,000 MWh in 1990. 3 figs., 4 tabs.

  19. Review on departure time choice theory for highway traffic; Doro kotsu ni okeru shuppatsu jikoku sentaku ni kansuru kenkyu kaisetsu

    Energy Technology Data Exchange (ETDEWEB)

    Kuwahara, M. [The University of Tokyo, Tokyo (Japan). Institute of Industrial Science

    1998-04-01

    This paper explains theoretical results achieved to date on the fundamental theory for time smoothing which is drawing attention as a measure to mitigate traffic congestion, that is departure time choice theory for highway traffic. If a trip having a definite restriction on arrival time is used as an object of the discussion, the travel expense for a traveler consists of an expense for travel time when a car was driven at free speeds, an expense for waiting time at bottlenecks, and an expense incurred by schedule delay (s). Under an assumption that the traveler selects departure time to minimize the expense, a time-based equilibrium condition can be introduced. If a schedule expense function (f(s)) to convert `s` into an expense is convex with regard to the `s`, the first in first work (FIFW) principle can be established, that the bottleneck is reached in the order of earlier departure time that is desired. Thus, starting from handling numerically the relationship between queuing expense function in the bottleneck and the f(s), the theory developed to the multiple bottleneck and random effect theory. 19 refs., 8 figs.

  20. On noise, traffic and factory vibrations in Akita city; Akitashi ni okeru soon oyobi kotsu kojo shindo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Nogoshi, M.; Kikuchi, T.; Morino, T.; Sannohe, M. [Akita University, Akita (Japan). College of Education

    1996-05-01

    Noise and vibration were measured in Akita City. In 1994, noise and traffic-caused vibration were measured along the trunk lines and other roads across the entire Akita City area. In 1995, the effort centered on the Ibarashima manufacturing quarters, the important source of noise and vibration in Akita city. The general-purpose noise meter LA-220S was used to measure noise and the vibration level meter VR-5100 was used to measure vibration. The results of noise measurement carried out at 122 points in Akita City indicated that the noise level was high along Route 7, Route 13, and the southern line belonging to the newly built national highway, marking the highest of approximately 74dB. As compared with the measurement made in 1968, the value was higher by 3-13dB. A roughly similar trend was seen in vibration. The noise level measurement of 1995 accomplished at 100 points in the vicinity of Ibarashima district indicated that the factories were responsible for high levels of noise and vibration. It was found that the levels lowered in proportion to the increase in the distance from the factories. 11 figs., 1 tab.

  1. Estimation of course stability at initial design stage; Shoki sekkeiji ni okeru shinro anteisei no suitei ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Yukawa, K. [Ministry of Transportation, Tokyo (Japan)] Kijima, K. [Kyushu Univ., Fukuoka (Japan)

    1998-12-31

    The theoretical prediction method for the hydrodynamic forces acting on the ship hull in maneuvering motion in consideration of effect of frame line configuration is proposed, selecting six types of model ships as the calculation objects. The prediction results show that the hydrodynamic forces can be predicted with reasonable accuracy in the ordinary maneuvering motion range, though the large drift angle and high dimensionless rotation angular speed give some errors. Using the linear differential coefficient obtained from the prediction of hydrodynamic force acting on ship hull, the decrease in the course instability is investigated. It is found that the method is able to be used for predicting the course stability of ships with relatively good accuracy. This method will be useful to decrease the course instability due to the difference in change in local shape of ships. Study will be continued on estimation calculation of hydrodynamic force on ship hull having various kinds of types. 13 refs., 15 figs., 2 tabs.

  2. Measurement of organic carbon quantity at chemoautorophic bacterium; Kagaku dokuritsu eiyo saikin ni okeru yuki tansoryo no sokutei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Tsuda, I.; Kato, K.; Nozaki, K. [Electrotechnical Laboratory, Tsukuba (Japan); Kurokawa, K. [Tokyo University of Agriculture and Technology, Tokyo (Japan)

    1996-10-27

    Described herein is the method for analyzing quantity of organic carbon synthesized by chemoautotrophic bacterium. It is based on the combustion-infrared spectroscopy, which is normally adopted for quantitative analysis of organic carbon. The problems involved in the measurement of organic compounds synthesized by iron-oxidizing bacteria are noise by culture medium components, aging of gas analyzer and contamination with organic compounds from a silicon plug. The measures taken in this study against these problems include comparison of the results with a medium containing iron-oxidizing bacteria with those with a medium free of these bacteria, calibration with the standard solution for each measurement, and replacement of a silicone plug by a silicon cap. Organic carbon is measured by a TOC-5000 analyzer equipped with an automatic sample feeder ASI-5000. Biomass density is determined by the MPN method. It is confirmed that organic carbon quantity is almost in proportion to biomass density, a phenomenon which can be used to determine organic carbon quantity. 7 refs., 6 figs., 1 tab.

  3. Correlations between emission timescale of fragments and isospin dynamics in $^{124}$Sn+$^{64}$Ni and $^{112}$Sn+$^{58}$Ni reactions at 35 AMeV

    CERN Document Server

    De Filippo, E; Russotto, P; Amorini, F; Anzalone, A; Auditore, L; Baran, V; Berceanu, I; Borderie, B; Bougault, R; Bruno, M; Cap, T; Cardella, G; Cavallaro, S; Chatterjee, M B; Chbihi, A; Colonna, M; D'Agostino, M; Dayras, R; Di Toro, M; Frankland, J; Galichet, E; Gawlikowicz, W; Geraci, E; Grzeszczuk, A; Guazzoni, P; Kowalski, S; La Guidara, E; Lanzalone, G; Lanzanò, G; Neindre, N Le; Lombardo, I; Maiolino, C; Papa, M; Piasecki, E; Pirrone, S; Planeta, R; Politi, G; Pop, A; Porto, F; Rivet, M F; Rizzo, F; Rosato, E; Schmidt, K; Siwek-Wilczynska, K; Skwira-Chalot, I; Trifirò, A; Trimarchi, M; Verde, G; Vigilante, M; Wieleczko, J P; Wilczynski, J; Zetta, L; Zipper, W

    2012-01-01

    We present a new experimental method to correlate the isotopic composition of intermediate mass fragments (IMF) emitted at mid-rapidity in semi-peripheral collisions with the emission timescale: IMFs emitted in the early stage of the reaction show larger values of $$ isospin asymmetry, stronger angular anisotropies and reduced odd-even staggering effects in neutron to proton ratio $$ distributions than those produced in sequential statistical emission. All these effects support the concept of isospin "migration", that is sensitive to the density gradient between participant and quasi-spectator nuclear matter, in the so called neck fragmentation mechanism. By comparing the data to a Stochastic Mean Field (SMF) simulation we show that this method gives valuable constraints on the symmetry energy term of nuclear equation of state at subsaturation densities. An indication emerges for a linear density dependence of the symmetry energy.

  4. Synthesis and sintering Ni-Zn ferrite obtained for combustion reaction in large scale; Sintese e sinterizacao de ferrita Ni-Zn obtida por reacao de combustao em larga escala

    Energy Technology Data Exchange (ETDEWEB)

    Vieira, D.A., E-mail: debora.vieira@cear.ufpb.br [Universidade Federal da Paraiba (UFPB), Joao Pessoa, PB (Brazil). Centro de Energias Alternativas e Renovaveis; Diniz, V.C.S.; Costa, A.C.F.M. [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Departamento de Ciencias e Engenharia de Materiais; Cornejo, D.R. [Universidade de Sao Paulo (USP), SP (Brazil). Instituto de Fisica; Kiminami, R.H.G.A. [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil). Departamento de Ciencias e Engenharia de Materiais

    2014-07-01

    This research proposes to evaluate the magnetic properties of ferrite Ni-Zn synthesized by combustion reaction on a large scale and sintered at 1250 deg C in resistive furnace. The sample was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and magnetic measurements. The results show that the synthesized product in large scale resulted in soft magnetic material with saturation magnetization of 40 emu·g{sup -1} and coercivity of 0.080 kOe, after sintering it was observed an increase to 68 emu·g{sup -1} in the magnetization and a reduction to 0.016 kOe in coercivity, indicating that the obtained material has promising characteristics for applications in electro-electronic devices. (author)

  5. Evaluation of the nuclear data on ({alpha}, n) reaction for F, Na, Al, Cr, Fe, Ni, and Cu

    Energy Technology Data Exchange (ETDEWEB)

    Matsunobu, Hiroyuki [Data Engineering, Inc., Fujisawa, Kanagawa (Japan); Yamamuro, Nobuhiro

    2002-08-01

    Evaluation of the nuclear data on ({alpha}, n) reaction, which are very important in analyzing radiation shielding and criticality safety relating to storage, transport, and handling of spent fuel was carried out for 18 nuclides, and the results were compared with the experimental data for ({alpha}, n) reaction cross section and thick target neutron yield. (author)

  6. The kinetics of the O2/CO2 reaction in molten carbonate - Reaction orders for O2 and CO2 on NiO. [in fuel cells

    Science.gov (United States)

    Winnick, J.; Ross, P. N.

    1980-01-01

    The kinetics of the O2/CO2 reaction in molten carbonate is investigated using paste electrolytes and nickel sinter electrodes. A two-step approach to the determination of reaction orders is employed. First, exchange currents at various P(CO2) and P(O2) were measured using the low polarization method. Second, alpha(+) and alpha(-) values were obtained from the slope of the Allen-Hickling plot for current densities low enough so that concentration polarization within the electrode can be neglected. The reaction orders are + 1/4 in CO2 and + 5/8 in O2 in the cathodic direction, and - 3/4 in CO2 and + 1/8 in O2 in the anodic direction.

  7. Reactions of H2, CO, and O2 with active [NiFe]-hydrogenase from Allochromatium vinosum. A stopped-flow infrared study.

    NARCIS (Netherlands)

    George, S.J.; Kurkin, S.; Thorneley, R.N.; Albracht, S.P.J.

    2004-01-01

    The Ni-Fe site in the active membrane-bound [NiFe]-hydrogenase from Allochromatium Vinosum can exist in three different redox states. In the most oxidized state (Nia-S) the nickel is divalent. The most reduced state (Nia-SR) likewise has Ni2+, while the intermediate state (Nia-C*) has Ni3+. The tran

  8. Isobaric yield ratio difference between the 140 $A$ MeV $^{58, 64}$Ni + $^{9}$Be reactions studied by antisymmetric molecular dynamics model

    CERN Document Server

    Qiao, C Y; Ma, C W; Zhang, Y L; Wang, S S

    2015-01-01

    \\item[Background] The isobaric yield ratio difference (IBD) method is found to be sensitive to the density difference of neutron-rich nucleus induced reaction around the Fermi energy. \\item[Purpose] An investigation is performed to study the IBD results in the transport model. \\item[Methods] The antisymmetric molecular dynamics (AMD) model plus the sequential decay model GEMINI are adopted to simulate the 140$A$ MeV $^{58, 64}$Ni + $^{9}$Be reactions. A relative small coalescence radius R$_c =$ 2.5 fm is used for the phase space at $t =$ 500 fm/c to form the hot fragment. Two limitations on the impact parameter ($b1 = 0 - 2$ fm and $b2 = 0 - 9$ fm) are used to study the effect of central collisions in IBD. \\item[Results] The isobaric yield ratios (IYRs) for the large--$A$ fragments are found to be suppressed in the symmetric reaction. The IBD results for fragments with neutron-excess $I = $ 0 and 1 are obtained. A small difference is found in the IBDs with the $b1$ and $b2$ limitations in the AMD simulated re...

  9. On the ortho-positronium quenching reactions promoted by Fe(II), Fe(III), Co(III), Ni(II), Zn(II) and Cd(II) cyanocomplexes

    Science.gov (United States)

    Fantola Lazzarini, Anna L.; Lazzarini, Ennio

    The o-Ps quenching reactions promoted in aqueous solutions by the following six cyanocomplexes: [Fe(CN) 6] 4-; [Co(CN) 6] 3-; [Zn(CN) 4] 2-; [Cd(CN) 6] 2-; [Fe(CN) 6] 3-; [Ni(CN) 4] 2- were investigated. The first four reactions probably consist in o-Ps addition across the CN bond, their rate constants at room temperature, Tr, being ⩽(0.04±0.02) × 10 9 M -1 s -1, i.e. almost at the limit of experimental errors. The rate constant of the fifth reaction, in o-Ps oxydation, at Tr is (20.3±0.4) × 10 9 M -1 s -1. The [Ni(CN) 4] 2-k value at Tr, is (0.27±0.01) × 10 9 M -1 s -1, i.e. 100 times less than the rate constants of o-Ps oxydation, but 10 times larger than those of the o-Ps addition across the CN bond. The [Ni(CN) 4] 2- reaction probably results in formation of the following positronido complex: [Ni(CN) 4Ps] 2-. However, it is worth noting that the existence of such a complex is only indirectly deduced. In fact it arises from comparison of the [Ni(CN) 4] 2- rate constant with those of the Fe(II), Zn(II), Cd(II), and Co(III) cyanocomplexes, which, like the Ni(II) cyanocomplex, do not promote o-Ps oxydation or spin exchange reactions.

  10. Joining of Si3N4 ceramic using PdCo(NiSiB)-V system brazing filler alloy and interfacial reactions

    Institute of Scientific and Technical Information of China (English)

    Huaping Xiong; Bo Chen; Yu Pan; Wanlin Guo; Wei Mao; Qingsong Ma

    2014-01-01

    The wettability of V-active PdCo-based alloys on Si3N4 ceramic was studied with the sessile drop method. And the alloy of Pd50.0-Co33.7-Ni4.0-Si2.0-B0.7-V9.6 (wt%), was developed for Si3N4 ceramic joining in the present investigation. The rapidly-solidified brazing foils were fabricated by the alloy Pd50.0-Co33.7-Ni4.0-Si2.0-B0.7-V9.6. The average room-temperature three-point bend strength of the Si3N4/Si3N4 joints brazed at 1453 K for 10 min was 205.6 MPa, and the newly developed braze gives joint strengths of 210.9 MPa, 206.6 MPa and 80.2 MPa at high temperatures of 973 K, 1073 K and 1173 K respectively. The interfacial reaction products in the Si3N4/Si3N4 joint brazed at 1453 K for 10 min were identified to be VN and Pd2Si by XRD analysis. Based on the XEDS analysis result, the residual brazing alloy existing at the central part of the joint was verified as Co-rich phases, in which the concentration of element Pd was high up to 18.0-19.1 at%. The mechanism of the interfacial reactions was discussed. Pd should be a good choice as useful alloying element in newer high-temperature braze candidates for the joining of Si-based ceramics.

  11. Joining of Si3N4 ceramic using PdCo(NiSiB–V system brazing filler alloy and interfacial reactions

    Directory of Open Access Journals (Sweden)

    Huaping Xiong

    2014-02-01

    Full Text Available The wettability of V-active PdCo-based alloys on Si3N4 ceramic was studied with the sessile drop method. And the alloy of Pd50.0–Co33.7–Ni4.0–Si2.0–B0.7–V9.6 (wt%, was developed for Si3N4 ceramic joining in the present investigation. The rapidly-solidified brazing foils were fabricated by the alloy Pd50.0–Co33.7–Ni4.0–Si2.0–B0.7–V9.6. The average room-temperature three-point bend strength of the Si3N4/Si3N4 joints brazed at 1453 K for 10 min was 205.6 MPa, and the newly developed braze gives joint strengths of 210.9 MPa, 206.6 MPa and 80.2 MPa at high temperatures of 973 K, 1073 K and 1173 K respectively. The interfacial reaction products in the Si3N4/Si3N4 joint brazed at 1453 K for 10 min were identified to be VN and Pd2Si by XRD analysis. Based on the XEDS analysis result, the residual brazing alloy existing at the central part of the joint was verified as Co-rich phases, in which the concentration of element Pd was high up to 18.0–19.1 at%. The mechanism of the interfacial reactions was discussed. Pd should be a good choice as useful alloying element in newer high-temperature braze candidates for the joining of Si-based ceramics.

  12. Microwave assisted solid state reaction method: Investigations on electrical and magnetic properties NiMgZn ferrites

    Energy Technology Data Exchange (ETDEWEB)

    Chandra Babu Naidu, K.; Madhuri, W., E-mail: madhuriw12@gmail.com

    2016-09-15

    The spinel ferrite of compositions Ni{sub 0.2}Mg{sub 0.8−x} Zn{sub x}Fe{sub 2}O{sub 4} (x = 0.2, 0.4, 0.6, 0.8) are synthesized using microwave double sintering technique. X-ray diffraction study reveals formation of single phase spinel cubic structure. The lattice parameter (a), average crystallite size (D) and bulk density (ρ{sub b}) are increasing with zinc content. Fourier-transform infrared spectra are recorded to locate octahedral and tetrahedral sites. The dielectric constant (ε{sub r}), loss tangent (tanδ), ac, dc-electrical conductivities (σ{sub ac} and σ{sub dc}) are increasing while Curie transition temperature (T{sub c}) and activation energies (E{sub a}) are decreasing with zinc substitution. Power law fit is applied to logσ versus logω plots to evaluate dc-electrical conductivity and exponent (n) at room temperature. Electrical conduction mechanism and relaxation time (τ) are reported from impedance analysis. Hysteresis loop attributes that saturation magnetization (M{sub s}), anisotropy constant (K{sub 1}) and coercivity (H{sub c}) are decreasing with substituent. Low coercivity of 1.96–2.89 G obtained is suitable for magnetic recording applications. - Highlights: • M-H loop attributes ferri to paramagnetic transition of Microwave sintered NiMgZn ferrites. • M{sub r} ∼3 × 10{sup −4}–2.4 × 10{sup −2} emu/g reveal the weak super para magnetic particles. • Cation distribution is made from magnetic moment of all samples. • High ε{sub r} and low H{sub c} attribute super capacitors and recording applications. • Nyquist plots confirm the semiconducting nature of all compositions.

  13. Coverage profile simulation in proportion to the nonlinear surface reaction; Hisenkei hyomen hanno ni taio shita kabarejji keijo shumyureshon

    Energy Technology Data Exchange (ETDEWEB)

    Akiyama, Yasunobu; Imaishi, Nobuyuki [Kyushu University, Fukuoka (Japan)

    1999-06-05

    The simulation algorithm of step/hole coverage shape which could be applied at the Chemical Vapor Deposition (CVD) system with the nonlinear surface reaction speed was devised. By combining with the conventional simple Monte Carlo calculation technique, the code which could simulate the coverage shape at high speed was made. It was quantitatively explainable in respect of raw material density dependence (fluoridation tungsten (6); WF{sub 6}) of the coverage shape, when this code was applied to the thermal CVD of tungsten (W) with nonlinear surface reaction. (translated by NEDO)

  14. Effect of calcination temperature on structural properties and catalytic activity in oxidation reactions of LaNiO3 perovskite prepared by Pechini method

    Institute of Scientific and Technical Information of China (English)

    K.Rida; M.A.Pe(n)a; E.Sastre; A.Martínez-Arias

    2012-01-01

    The study presented the preparation of the perovskite oxide LaNiO3 by the complex citrate method,paying particular attention to evolution of its formation from the amorphous precursor with varied calcination temperatures.The products obtained after heat treatment under air between 200 and 800 ℃ were characterized by X-ray diffraction (XRD),thermogravimetric and differential thermal analysis (TG-DTA),Fourier transform infrared spectroscopy (FTIR),SBET measurements and X-ray photoelectron spectroscopy (XPS).The results showed the formation of a single phase with perovskite structure from ca.550 ℃.Tests on the two catalytic oxidation reactions of C3H6 and CO over the system calcined between mentioned temperatures were examined on the basis of characterization results and showed that optimum catalytic properties for such reactions were achieved for the perovskite calcined at 600 ℃.In turn,correlations between redox and catalytic properties were established on the basis of thermogravimetric temperature programmed reduction (TPR) analysis.

  15. Guarantee of property right in open access systems. Legal study of property right of electric utilities and expropriation; Open access ni okeru zaisanken no hosho. Denki jigyo ni okeru zaisanken to shuyo ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Maruyama, M. [Central Research Institute of Electric Power Industry, Tokyo (Japan)

    1996-03-01

    A study has been made about the relationship between open access, which has now become an important element of the electric utilities renovation efforts in the U.S. and Europe, and property right. The meaning of open access is to guarantee free access to suppliers by securing fair competition between them through separation of the vertical integration in power transmission and opening the transmission network to final customers. In case of Japan, the U.S., and Germany where private sector suppliers run electric utilities, however, a need arises to consider the property right that such suppliers enjoy as guaranteed by their Constitutions. The outcomes of discussions made in Germany and the State of California were complied, and some conclusions were reached. It constitutes an infringement of their property right for the authorities to order them to allow open access without compensation. In case the authorities use expropriation for the same purpose, they have to make it known clearly that the separation and opening is to the benefit of the public and must compensate fully for their action. There is no problem in giving the authorities the power to force the electric utilities to sign a wheeling contract in case the latter unlawfully rejects to sign one proposed by a wheeling-requesting party. 24 refs., 3 figs., 4 tabs.

  16. Study on the optimal control of the ground thermal storage system in the greenhouse. Part 4; Onshitsu ni okeru taiyo energy dochu chikunetsu system ni okeru saiteki seigyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, M. [Sanko Air Conditioning Co. Ltd., Osaka (Japan); Nakahara, N. [Kanagawa University, Yokohama (Japan)

    1996-10-27

    Three types of weight in both energy saving and optimum room temperature environment were changed to obtain the optimal control solution of the ground thermal storage system in a greenhouse. The relation diagram between the optimal solution of a performance function, and the state constraints and control function constraints was created in consideration of the energy term in a control function value area and the room temperature environment. As a result, the whole image of the performance function could be grasped in consideration of the energy term with inequality constraints and the room temperature environmental term in this study. The rate of a weighting factor in the performance function significantly influences the optimal solution. The influence on the optimal solution also changes when the optimal room temperature schedule differs. The influence that three types of rising algorithm exert on the convergence and converging speed was investigated. Superiority or inferiority occurs according to the space properties of a performance function. A zigzag method is most disadvantageous. The constraints can be converged to the optimal solution using an SUMT outer point method irrespective of the initial value. 6 refs., 6 figs., 4 tabs.

  17. Synthesis NiAl{sub 1,0}Fe{sub 1,0}O{sub 4} catalyst by the combustion reaction to their use in the shift reaction (WGSR); Sintese do catalisador de NiAl{sub 1,0}Fe{sub 1,0}O{sub 4} por reacao de combustao visando sua utilizacao na reacao de shift (WGSR)

    Energy Technology Data Exchange (ETDEWEB)

    Santos, P.T.A.; Costa, A.C.F.M.; Neiva, L.S.; Gama, L. [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Dept. de Engenharia de Materiais; Argolo, F.; Andrade, H.M.C. [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Inst. de Quimica

    2009-07-01

    This work aims at the synthesis of catalyst NiAl{sub 1,0}Fe{sub 1,0}O{sub 4} by combustion reaction using urea as fuel, to evaluate its performance in the production of hydrogen by the reaction of displacement of water vapor (WGSR). The initial composition of the solution was based on valencia total oxidizing and reducing reagents based on the concepts of the chemistry of propellants, using container as a crucible of glassy silica. The resulting powder was characterized by X-ray diffraction, infrared spectroscopy, nitrogen adsorption isotherms (BET), scanning electronic microscope and catalytic tests. The DRX results reveal the presents majoritary phase NiAl{sub 1,0}Fe{sub 1,0}O{sub 4} spinel, the catalyst presents surface area 28 m{sup 2}/g and isotherms type III. Higher conversion CO/CO{sub 2} of 75% CO conversion observed at 500 deg C and catalytic activity of 43 mmolg{sup -1}.h{sup -1} at 450 deg C. (author)

  18. Hierarchical hollow urchin-like NiCo2O4 nanomaterial as electrocatalyst for oxygen evolution reaction in alkaline medium

    Science.gov (United States)

    Wang, Juan; Qiu, Tian; Chen, Xu; Lu, Yanluo; Yang, Wensheng

    2014-12-01

    Hierarchical hollow urchins of NiCo2O4 (HU-NiCo2O4) were synthesized by a hard templating method followed by thermal decomposition. The structure consists of three levels of hierarchy i.e., zero-dimensional nanoparticle with a diameter of about 6 nm, one-dimensional chain, and three-dimensional hollow urchin, respectively. Nanoparticle aggregates of NiCo2O4 (NA-NiCo2O4) were also synthesized by the same procedure in the absence of the hard template. Relative to NA-NiCo2O4, HU-NiCo2O4 features a well-connected three-dimensional porous structure, which is beneficial for diffusion of oxygen. Consequently, HU-NiCo2O4 displayed superior electrocatalytic activity towards oxygen evolution processes with lower overpotential, higher current density, and higher stability than NA-NiCo2O4.

  19. Hydrogen generation arising from the {sup 59}Ni(n,p) reaction and its impact on fission-fusion correlations

    Energy Technology Data Exchange (ETDEWEB)

    Greenwood, L.R.; Garner, A.F.

    1996-04-01

    Whilte the influence of transmutant helium on radiation-induced microstructural evolution has often been studied, there is a tendency to overlook the influence of concurrently-generated hydrogen. There have been some recent speculation and studies, however, that suggest that the influence of hydrogen may be enhanced in the presence of large amounts of helium, especially at lower irradiation temperatures typical of projected ITER operation. The impact of the (n,p) reaction on both hydrogen generation rates and displacement rates are evaluated in this paper for a variety of neutron spectra employed in fission-fusion correlation.

  20. Asymmetric synthesis of α-amino acids via homologation of Ni(II) complexes of glycine Schiff bases. Part 2: aldol, Mannich addition reactions, deracemization and (S) to (R) interconversion of α-amino acids.

    Science.gov (United States)

    Sorochinsky, Alexander E; Aceña, José Luis; Moriwaki, Hiroki; Sato, Tatsunori; Soloshonok, Vadim

    2013-11-01

    This review provides a comprehensive treatment of literature data dealing with asymmetric synthesis of α-amino-β-hydroxy and α,β-diamino acids via homologation of chiral Ni(II) complexes of glycine Schiff bases using aldol and Mannich-type reactions. These reactions proceed with synthetically useful chemical yields and thermodynamically controlled stereoselectivity and allow direct introduction of two stereogenic centers in a single operation with predictable stereochemical outcome. Furthermore, new application of Ni(II) complexes of α-amino acids Schiff bases for deracemization of racemic α-amino acids and (S) to (R) interconversion providing additional synthetic opportunities for preparation of enantiomerically pure α-amino acids, is also reviewed. Origin of observed diastereo-/enantioselectivity in the aldol, Mannich-type and deracemization reactions, generality and limitations of these methodologies are critically discussed.

  1. Effect of electromigration on interfacial reaction in Ni/Sn3.0Ag0.5Cu/Au/Pd/Ni-P flip chip solder joints%电迁移对Ni/Sn3.0Ag0.5Cu/Au/Pd/Ni—P倒装焊点界面反应的影响

    Institute of Scientific and Technical Information of China (English)

    黄明亮; 陈雷达; 周少明; 赵宁

    2012-01-01

    本文研究了150℃,1.0×104A/cm2条件下电迁移对Ni/Sn3.0Ag0.5Cu/Au/Pd/Ni-P倒装焊点界面反应的影响.回流后在solder/Ni和solder/NiP的界面上均形成(Cu,Ni)6Sn5类型金属间化合物.时效过程中两端界面化合物都随时间延长而增厚,且化合物类型都由(Cu,Ni)6Sn5转变为(Ni,Cu)3Sn4.电迁移过程中电子的流动方向对Ni—P层的消耗起着决定性作用.当电子从基板端流向芯片端时,电迁移促进了Ni—P层的消耗,600h后阴极端Ni-P层全部转变为Ni2SnP层.阴极界面处由于Ni2SnP层的存在,使界面Cu-Sn—Ni三元金属间化合物发生电迁移脱落溶解,而且由于Ni2SnP层与Cu焊盘的结合力较差,在Ni2SnP/Cu界面处会形成裂纹.当电子从芯片端流向基板端时,阳极端Ni—P层并没有发生明显的消耗.电流拥挤效应导致了阴极芯片端Ni层和Cu焊盘均发生了局部快速溶解,溶解到钎料中的Cu和Ni原子沿电子运动的方向往阳极运动并在钎料中形成了大量的化合物颗粒.电迁移过程中(Au,Pd,Ni)Sn4的聚集具有方向性,即(Au,Pd,Ni)Sn4因电流作用而在阳极界面处聚集.%The effect of electromigration (EM) on the interracial reaction in the Ni/Sn3.0Ag0.5Cu/Au/Pd/Ni-P flip chip solder joint is investigated under a current density of 1.0 ×104 A/cm2 at 150℃. The (Cu,Ni)6Sn5 intermetallic compounds (IMCs) form at both solder/Ni and solder/Ni-P interfaces in the as-reflowed state. During aging at 150℃, the (Cu,Ni)6Sn5 interfacial IMCs grow thicker and transform into (Ni,Cu)3Sn4 type after 200 h at solder/Ni interface and 600 h at solder/Ni-P interface, respectively. During EM, the current direction plays an important role in Ni-P layer consumption. When electrons flow from Ni-P to Ni, EM enhances the consumption of Ni-P, i.e., the Ni-P s completely consumed and transforms into Ni2SnP after EM for 600 h. There is

  2. INTERFACE REACTION IN MAGNETIC MULTILAYERS

    Institute of Scientific and Technical Information of China (English)

    G.H. Yu; M.H. Li; F.W. Zhu; X.F. Cui; J.L. Jin

    2001-01-01

    Ta/NiO/NiFe/Ta multilayers were prepared by rf reactive and dc magnetron sputter-ing. The exchange coupling field (Hex) between NiO and NiFe reached 120Oe. Thecomposition and chemical states at the interface region of NiO/NiFe were studied us-ing the x-ray photoelectron spectroscopy (XPS) and peak decomposition technique. Theresults show that there are two thermodynamically favorable reactions at NiO/NiFeinterface: NiO+Fe = Ni+FeO and 3NiO+2Fe 3Ni+Fe2 O3. The thickness of thechemical reaction as estimated by angle-resolved XPS was about 1-1.5nm. These in-terrace reaction products are magnetic defects, and we believe that the Hex and thecoereivity (He) of NiO/NiFe ave affected by these defects. Moreover, the results alsoshow that there is an "intermixing layer" at the Ta/NiO (and NiO/Ta) interface dueto a thermodynamically favorable reaction: 2Ta+5NiO=5Ni+Ta2O5. This interfacereaction has an effect on the exchange coupling as well. The thickness of the "inter-mixing layer" as estimated by XPS depth-profiles was about 8-10nm.

  3. Evaporation residue cross sections for the {sup 64}Ni + {sup 144,154}Sm reaction -- Energy dissipation in hot nuclei

    Energy Technology Data Exchange (ETDEWEB)

    Back, B.B.; Blumenthal, D.J.; Davids, C.N. [and others

    1995-08-01

    The fission hindrance of hot nuclei was deduced recently from an enhanced emission of GDR {gamma} rays, neutrons and charged particles prior to scission of heavy nuclei. In the most recent experiments addressing this topic, namely new measurements of the pre-scission {gamma} rays and evaporation residues from the {sup 32}S + {sup 184}W reaction, a rather sharp transition from negligible to full one-body dissipation occurs over the excitation energy region E{sub exc} = 60-100 MeV. However, the cross section does not appear to level out or start to decline again at the upper end of the energy range as expected in this interpretation. It is therefore clearly desirable to extend the excitation energy range to look for such an effect in order to either corroborate or refute this interpretation.

  4. Development of Fe-Ni/YSZ-GDC electro-catalysts for application as SOFC anodes. XRD and TPR characterization, and evaluation in ethanol steam reforming reaction

    Energy Technology Data Exchange (ETDEWEB)

    Paz Fiuza, Raigenis da; Silva, Marcos Aurelio da; Boaventura, Jaime Soares [UFBA, Salvador, Bahia (Brazil). Energy and Materials Science Group

    2010-07-01

    Electro-catalysts based on Fe-Ni alloys were prepared using physical mixture and modified Pechini methods; they were supported on a composite of Yttria Stabilized Zirconia (YSZ) and Gadolinia Doped Ceria (GDC). The composites had compositions of 35% metal load and 65% support (70% wt. YSZ and 30% wt. GDC mixture) (cermets). The samples were characterized by Temperature-Programmed Reduction (TPR) and X-Ray Diffraction (XRD) and evaluated in ethanol steam reforming at 650 C for six hours and in the temperature range 300 - 900 C. The XRD results showed that the bimetallic sample calcined at 800 C formed a mixed oxide (NiFe{sub 2}O{sub 4}) in spinel structure; after reducing the sample in hydrogen, Ni-Fe alloys were formed. The presence of Ni decreased the final reduction temperature of the NiFe{sub 2}O{sub 4} species. The addition of Fe to Ni anchored to YSZ-GDC increased the hydrogen production and inhibits the carbon deposition. The bimetallic 30Fe5Ni samples reached an ethanol conversion of about 95%, and a hydrogen yield up to 48% at 750 C. In general, the ethanol conversion and hydrogen production were independent of the metal content in the electro-catalyst. However, the substitution of Ni for Fe significantly reduced the carbon deposition on the electro-catalyst: 74, 31 and 9 wt. % in the 35Ni, 20Fe15Ni, and 30Fe5Ni samples, respectively. (orig.)

  5. Solid-state reactions during mechanical alloying of ternary Fe-Al-X (X=Ni, Mn, Cu, Ti, Cr, B, Si) systems: A review

    Science.gov (United States)

    Hadef, Fatma

    2016-12-01

    The last decade has witnessed an intensive research in the field of nanocrystalline materials due to their enhanced properties. A lot of processing techniques were developed in order to synthesis these novel materials, among them mechanical alloying or high-energy ball milling. In fact, mechanical alloying is one of the most common operations in the processing of solids. It can be used to quickly and easily synthesize a variety of technologically useful materials which are very difficult to manufacture by other techniques. One advantage of MA over many other techniques is that is a solid state technique and consequently problems associated with melting and solidification are bypassed. Special attention is being paid to the synthesis of alloys through reactions mainly occurring in solid state in many metallic ternary Fe-Al-X systems, in order to improve mainly Fe-Al structural and mechanical properties. The results show that nanocrystallization is the common result occurring in all systems during MA process. The aim of this work is to illustrate the uniqueness of MA process to induce phase transformation in metallic Fe-Al-X (X=Ni, Mn, Cu, Ti, Cr, B, Si) systems.

  6. Carbon- and Binder-Free NiCo2O4 Nanoneedle Array Electrode for Sodium-Ion Batteries: Electrochemical Performance and Insight into Sodium Storage Reaction

    Science.gov (United States)

    Lee, Jong-Won; Shin, Hyun-Sup; Lee, Chan-Woo; Jung, Kyu-Nam

    2016-02-01

    Sodium (Na)-ion batteries (NIBs) have attracted significant interest as an alternative chemistry to lithium (Li)-ion batteries for large-scale stationary energy storage systems. Discovering high-performance anode materials is a great challenge for the commercial success of NIB technology. Transition metal oxides with tailored nanoarchitectures have been considered as promising anodes for NIBs due to their high capacity. Here, we demonstrate the fabrication of a nanostructured oxide-only electrode, i.e., carbon- and binder-free NiCo2O4 nanoneedle array (NCO-NNA), and its feasibility as an anode for NIBs. Furthermore, we provide an in-depth experimental study of the Na storage reaction (sodiation and desodiation) in NCO-NNA. The NCO-NNA electrode is fabricated on a conducting substrate by a hydrothermal method with subsequent heat treatment. When tested in an electrochemical Na half-cell, the NCO-NNA electrode exhibits excellent Na storage capability: a charge capacity as high as 400 mAh g-1 is achieved at a current density of 50 mA g-1. It also shows a greatly improved cycle life (~215 mAh g-1 after 50 cycles) in comparison to a conventional powder-type electrode (~30 mAh g-1). However, the Na storage performance is still inferior to that of Li, which is mainly due to sluggish kinetics of sodiation-desodiation accompanied by severe volume change.

  7. Strengthened Synergistic Effect of Metallic Mx Py (M = Co, Ni, and Cu) and Carbon Layer via Peapod-Like Architecture for Both Hydrogen and Oxygen Evolution Reactions.

    Science.gov (United States)

    Bai, Yuanjuan; Fang, Ling; Xu, Haitao; Gu, Xiao; Zhang, Huijuan; Wang, Yu

    2017-02-06

    The smooth electric transmission is crucial for the high-efficient electrocatalysis. Herein, a series of peapod-like metallic Mx Py /C (M = Co, Ni, and Cu) composites is developed as bifunctional catalysts toward hydrogen and oxygen evolution reactions. For the first time, the metallic property of Cu3 P is confirmed through the theoretical calculation. The in-depth composition, structural and catalytic mechanism analysis of Mx Py /C discloses that the comparable activity and considerable durability of these catalysts mainly result from the strengthened synergistic effect between metallic Mx Py and carbon layer based on the unique peapod-like architecture. Especially, the atomic contact between Mx Py and carbon not only provides an open channel for electronic transmission but also ensures the integrity of peapod-like structure. Furthermore, the high electric conductivity of the inner metallic Mx Py and the outer carbon layer endows the Mx Py /C catalyst with rapid charge migration during the electrocatalytic pathway. These findings shed light on the origin of high catalytic activity of Mx Py /C and open a path for purposefully rationally synthesizing superior electrocatalysts.

  8. Solid-state reactions during mechanical alloying of ternary Fe–Al–X (X=Ni, Mn, Cu, Ti, Cr, B, Si) systems: A review

    Energy Technology Data Exchange (ETDEWEB)

    Hadef, Fatma, E-mail: hadef77@yahoo.fr [Laboratoire de Recherche sur la Physico-Chimie des Surfaces et Interfaces, LRPCSI, Université 20 Août 1955, BP 26, Route d’El-Haddaiek, Skikda 21000 (Algeria); Département de Physique, Faculté des Sciences, Université 20 Août 1955, BP 26, Route d’El-Haddaiek, Skikda 21000 (Algeria)

    2016-12-01

    The last decade has witnessed an intensive research in the field of nanocrystalline materials due to their enhanced properties. A lot of processing techniques were developed in order to synthesis these novel materials, among them mechanical alloying or high-energy ball milling. In fact, mechanical alloying is one of the most common operations in the processing of solids. It can be used to quickly and easily synthesize a variety of technologically useful materials which are very difficult to manufacture by other techniques. One advantage of MA over many other techniques is that is a solid state technique and consequently problems associated with melting and solidification are bypassed. Special attention is being paid to the synthesis of alloys through reactions mainly occurring in solid state in many metallic ternary Fe–Al–X systems, in order to improve mainly Fe–Al structural and mechanical properties. The results show that nanocrystallization is the common result occurring in all systems during MA process. The aim of this work is to illustrate the uniqueness of MA process to induce phase transformation in metallic Fe–Al–X (X=Ni, Mn, Cu, Ti, Cr, B, Si) systems. - Highlights: • A review of state of the art on binary Fe–Al alloys was presented. • Structural and microstructural properties of MA ternary Fe–Al–X alloys were summerized. • MA process is a powerful tool for producing metallic alloys at the nanometer scale.

  9. Magnetic property and interface structure of Ta/NiO/NiFe/Ta

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Ta/NiO/NiFe/Ta multilayers, utilizing Ta as buffer layer, were prepared by rf reactive and dc magnetron sputtering. The exchange coupling field between NiO and NiFe reached a maximum value of 9.6×103 A/m at a NiO film thickness of 50 nm. The composition and chemical states at interface region of Ta/NiO/Ta were studied by using the X-ray photoelectron spectroscopy (XPS) and peak decomp- osition technique. The results show that there is an "inter- mixing layer" at the Ta/NiO (and NiO/Ta) interface due to a thermodynamically favorable reaction 2Ta + 5NiO = 5Ni + Ta2O5. This interface reaction has a great effect on exchange coupling. The thickness of Ni+NiO estimated by XPS depth- profiles is about 8-10 nm.

  10. Colloidal stability of Ni(OH){sub 2} in water and its dispersion into a ceramic matrix from the reaction media to obtain Ni/Al{sub 2}O{sub 3} materials

    Energy Technology Data Exchange (ETDEWEB)

    Cabanas-Polo, S.; Ferrari, B.; Sanchez-Herencia, A. J.

    2014-07-01

    Ni/Al{sub 2}O{sub 3} composites have been fabricated by slip casting of concentrated Ni(OH){sub 2}/Al{sub 2}O{sub 3} suspensions and subsequent in situ reduction to metallic nickel during sintering. For that, the synthesis assisted by ultrasound of both α- and β-Ni(OH){sub 2} polymorphs, as well as their colloidal stability, have been studied. The structural differences between both polymorphs have been thoroughly studied by means of XRD, FTIR, DTA-TG, SSA, SEM and TEM, in order to optimize the starting suspensions. This way, the IEP of both polymorphs have been established (9.7 y 12 for β- and α-Ni(OH){sub 2}, respectively), as well as the optimal content of an anionic dispersant (PAA) to stabilize the particles (0.8 wt. % for beta phase and 3.0 wt. % for alpha phase). Three different Ni/Al{sub 2}O{sub 3} composites, with a high dispersion degree of the metallic phase, have been obtained considering the potential vs. particles distance curve of the Ni(OH){sub 2}, and their structure has been discussed in terms of the strength of the agglomerates and/or aggregates of the Ni(OH){sub 2}. (Author)

  11. Structure and electrochemical properties of Li(Ni0.5Mn0.5)1-xTixO2 prepared by one-step solid state reaction

    Institute of Scientific and Technical Information of China (English)

    CAO Si-hai; WANG Zhi-xing; LI Xin-hai; GUO Hua-jun; PENG Wen-jie; YIN Zhou-lan

    2006-01-01

    The layered compound Li(Ni0.5Mn0.5)1-xTixO2 powders were prepared with Ni(OH)2, MnCO3, Li2CO3 and TiO2 by one-step solid state reaction. The effect of doping Ti on the structure and electrochemical properties was studied. The XRD results indicate that the powders with 0≤x≤0.05 have good layered structure and trace of impurity appears in the samples with x≥0.1. The SEM photographs show that the particle size distributes homogeneously and the sample with x=0.15 has larger particle size than other samples. The charge-discharge tests show that Li(Ni0.5Mn0.5)0.95Ti0.05O2 synthesized at 800 ℃ for 36 h exhibits good electrochemical properties. It firstly delivers 173 mA.h/g and maintains 90% of the initial discharge capacity after 30 cycles. The cyclic voltammetry and differential capacity vs voltage curves show that the major oxidation and reduction peaks are around 3.95 V and 3.75 V, respectively, assigned to Ni2+/Ni4+ oxidation-reduction process. A weak peak around 4.5 V is found during the oxidation process in the first cycle, which can be regarded as the main reason of the large drop of discharge capacity in the initial cycle.

  12. Self-assembled NiO-ZrO2 nanocrystals with mesoscopic void space: an efficient and green catalyst for C-S cross-coupling reaction in water.

    Science.gov (United States)

    Pal, Nabanita; Bhaumik, Asim

    2012-08-14

    New NiO-ZrO(2) nanocrystals (MNZ-1) with mesoscopic self-assembly have been synthesized by using a non-ionic surfactant as the structure directing agent (SDA) via evaporation induced self-assembly (EISA) method. Powder X-ray diffraction (PXRD), N(2) sorption study and transmission electron microscopic (TEM) image analyses revealed the cubic structure, mesoporosity and mesoscopic self-assembly of ca. 7.0 nm sized tiny nanocrystals in the material. MNZ-1 catalyzes the aerobic aryl-sulfur cross-coupling reactions for a series of aryl-iodides with 4-chlorothiophenol in environment friendly water medium at elevated as well as room temperature. Pure ZrO(2) mesoporous nanocrystals are inactive, whereas pure NiO nanocrystals showed much lower catalytic activity under similar reaction conditions. The MNZ-1 nanocatalyst is completely non-air sensitive, inexpensive and effective for the synthesis of a series of essential biomolecules derived from diaryl sulfides.

  13. Hydrogen Production for Fuel Cell via Ethanol Steam Reforming Reaction over Ni-Co Catalysts%Ni-Co催化剂上乙醇水蒸气重整制氢

    Institute of Scientific and Technical Information of China (English)

    魏文良; 张利峰

    2015-01-01

    Ni-Co catalysts supported on γ-Al2 O3 , SiO2 and Al2 O3 · SiO2 were prepared using precipitation-impregnation method. The performance was studied, the structure and surface characteristics of the catalysts were measured by XRD and TPR. It was revealed that Ni-Co catalysts supported Al2 O3 ·SiO2 had much higher H2 selectivity than others in the range of 400~450 ℃. Ni-Co catalysts supported Al2 O3 had much higher H2 selectivity than others in the range of 500~600 ℃. XRD and TPR revealed that different species NiO-Al2 O3 and CoOx-Al2 O3 phases existed in Ni-Co catalysts, and the interaction between metal and support can increase the dispersion of Ni and Co, it can improve the catalytic performance.%采用沉积-沉淀法制备出γ-Al2 O3、 SiO2和Al2 O3·SiO2负载的Ni-Co催化剂,对催化剂进行性能测试,并用XRD和TPR等手段对催化剂进行了表征。结果表明:Al2 O3·SiO2负载的Ni-Co催化剂在400~450℃时的氢气选择性最高, Al2 O3负载的Ni-Co催化剂在500~600℃时的氢气选择性最高。 XRD结合TPR可知:γ-Al2 O3、 SiO2和Al2 O3·SiO2负载Ni-Co催化剂中都存在不同种类NiO-Al2 O3相和CoOx-Al2 O3相,金属-载体之间的相互作用可以提高活性金属组分Ni和Co的分散度,有利于提高催化剂的性能。

  14. Methanol oxidation reaction activity of microwave irradiated and heat-treated Pt/Co and Pt/Ni nano-electrocatalysts

    CSIR Research Space (South Africa)

    Mathe, NR

    2014-11-01

    Full Text Available Bimetallic Pt nanoparticles were prepared by alloying Pt with the non-noble transition metals, Co and Ni, using a conventional heat-treatment (HT) method and microwaveirradiation (MW). The resulting samples were PteCo-Ht, PteNi-HT, PteCo, MW and Pt...

  15. Quantifying the dependence of Ni(P) thickness in ultrathin-ENEPIG metallization on the growth of Cu–Sn intermetallic compounds in soldering reaction

    Energy Technology Data Exchange (ETDEWEB)

    Ho, Cheng-Ying; Duh, Jenq-Gong, E-mail: jgd@mx.nthu.edu.tw

    2014-11-14

    A new multilayer metallization, ENEPIG (Electroless Ni(P)/Electroless Pd/Immersion Au) with ultrathin Ni(P) deposit (ultrathin-ENEPIG), was designed to be used in high frequency electronic packaging in this study because of its ultra-low electrical impedance. Sequential interfacial microstructures of commercial Sn–3.0Ag–0.5Cu solders reflowed on ultarthin-ENEPIG with Ni(P) deposit thickness ranged from 4.79 μm to 0.05 μm were first investigated. Accelerated thermal aging test was then conducted to evaluate the long-term thermal stabilization of solder joints. The results showed that P-rich intermetallic compound (IMC) layer formed when the Ni(P) thickness was greater than a critical vale (about 0.18 μm). Besides, it is interesting to mention that the growth of (Cu,Ni){sub 6}Sn{sub 5} and (Cu,Ni){sub 3}Sn IMCs was suppressed with the formation of P-rich layer, i.e., Ni{sub 3}P and Ni{sub 2}Sn{sub 1+x}P{sub 1−x} phase, even though the electroless-plated Ni(P) layer was exhausted at initial stage of reflow process. The atomic Cu flux in solder joints without P-rich layer was calculated to be several times larger than that with P-rich layer formation after calculation, which implies that the P-rich layer and ultrathin Ni(P) deposit in ENEPIG served as diffusion barrier against rapid Cu diffusion. - Highlights: • Microstructures in ultrathin-ENEPIG with various Ni(P) thickness are investigated. • P-rich IMC layer formed when the Ni(P) thickness is greater than 0.18 μm. • Secondary (Cu,Ni){sub 6}Sn{sub 5} formed when the Ni(P) thickness is between 0.18 and 0.31 μm. • Cu diffusion flux without P-rich layer is larger than those with P-rich layer. • P-rich layer in ultrathin-ENEPIG exhibits good diffusion barrier characteristic.

  16. Development of Fe-Ni/YSZ-GDC electrocatalysts for application as SOFC anodes: XRD and TPR characterization and evaluation in the ethanol steam reforming reaction

    Energy Technology Data Exchange (ETDEWEB)

    da Paz Fiuza, Raigenis; Aurelio da Silva, Marcos; Boaventura, Jaime Soares [Energy and Materials Science Group - GECIM, Institute of Chemistry, Physical Chemistry Department, Universidade Federal da Bahia, 41170290 Salvador, Bahia (Brazil)

    2010-10-15

    Electrocatalysts based on Fe-Ni alloys were prepared by means of modified Pechini and physical mixture methods and using on a composite of Yttria Stabilized Zirconia (YSZ) and Gadolinia-Doped Ceria (GDC) as support. The former method was based on the formation a polymeric precursor that was subsequently calcined; the later method was based on the mixture of NiO and the support. The resulting composites had 35 wt.% metal load and 65 wt.% support (70 wt.% YSZ and 30 wt.% GDC mixture) (cermets). The samples were then characterized by Temperature-Programmed Reduction (TPR) and X-Ray Diffraction (XRD) and evaluated in the ethanol steam reforming at 650 C for 6 h in the temperature range of 300-900 C. The XRD results showed that the bimetallic sample calcined at 800 C formed a mixed oxide (NiFe{sub 2}O{sub 4}) with a spinel structure, which, after reduction in hydrogen, formed Ni-Fe alloys. The presence of Ni was observed to decrease the final reduction temperature of the NiFe{sub 2}O{sub 4} species. The addition of iron to the nickel anchored to YSZ-GDC increased the hydrogen production and inhibited carbon deposition. The resulting bimetallic 30Fe5Ni sample reached an ethanol conversion of about 95% and a hydrogen yield up to 48% at 750 C. In general, ethanol conversion and hydrogen production were independent of the metal content in the electrocatalyst. However, the substitution of nickel for iron significantly reduced carbon deposition on the electrocatalyst: 74, 31, and 9 wt.% in the 35Ni, 20Fe15Ni, and 30Fe5Ni samples, respectively. (author)

  17. Effect of the kind of fuel in the synthesis of the catalyzer NiFe{sub 2}O{sub 4} to displacement reaction of water gas (WGRS); Efeito do tipo de combustivel na sintese do catalisador NiFe{sub 2}O{sub 4} para reacao de deslocamento do gas agua (WGRS)

    Energy Technology Data Exchange (ETDEWEB)

    Santos, P.T.A.; Barros, B.S.; Costa, A.C.F.M.; Gama, L. [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Dept. de Engenharia de Materiais], e-mail: anacristina@dema.ufcg.edu.br; Jesus, A.A.; Andrade, H.M.C. [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Inst. de Quimica

    2006-07-01

    This work has as objective synthesizes and to characterize the NiFe{sub 2}O{sub 4} catalyst by combustion reaction using different fuels: urea and glycine seeking your application in the water gas shift reaction (WGSR), promoting the purification of the methane for the elimination of the carbon monoxide. The powders were prepared in agreement with the chemistry of the propellants using as recipient a vitreous silica crucible; the maximum temperature and the medium time of flame were verified. The powders were characterized by X-ray diffraction (DRX), Scanning electronic microscopy and catalytic tests. The results show that the catalysts presented inverse spinel structure as majority phase for the two types of fuels. However, it was observed that using the urea, there was the presence of a second phase of NiO and when the glycine was used, there was the presence of lines of Ni. The catalyst NiFe{sub 2}O{sub 4} using urea as fuel, presented better catalytic acting. (author)

  18. Combustion synthesis by reaction and characterization of nano ferrites: study of fuel aniline, citric and its mixture; Sintese por reacao de combustao e caracterizacao de nanoferritas Ni-Zn: estudo dos combustiveis anilina, acido citrico e sua mistura

    Energy Technology Data Exchange (ETDEWEB)

    Silva, M.C. da; Coutinho, J.P.; Costa, A.C.F.M., E-mail: normanda@ufcg.edu.br [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Engenharia de Materiais; Kiminami, R.H.G.A. [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil). Departamento de Engenharia de Materiais; Freitas, N.L. de [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Tecnologia do Desenvolvimento

    2012-07-01

    The present study aims to evaluate the influence of aniline and citric acid used alone and combined in a ratio of 50% each in the characterization of NiZn ferrite synthesized by combustion reaction method in a muffle furnace. Measurements were made of temperature and reaction time. The nano-powders were characterized by XRD, EDX, textural analysis and SEM. The highest temperature was achieved by the reaction using the mixture of fuel and increased reaction time using citric acid. The nano ferrites using different fuels, and the mixture changed phases, the crystallite size and decreased surface area of the samples with aniline, citric acid and a mixture of both, respectively. The powder morphology ranged from presenting the formation of irregular blocks for the use of citric agglomerated in the form of skeins with aniline and a mixture to agglomerate larger particles. (author)

  19. 基于Ni/β-Mo2C的MFC阴极催化剂机理研究%Mechanism analysis of Ni/β-Mo2C based catalyst for microbial fuel cell cathode reaction

    Institute of Scientific and Technical Information of China (English)

    曾丽珍

    2012-01-01

    Ni/β-Mo2C是一种类铂的催化剂,作为微生物燃料电池(Microbial fuel cell,MFC)阳极催化剂时有很高的催化活性,可以高效催化氧化MFCs一般发酵产物,Ni/β-Mo2C作为MFC阳极材料在中性条件下对电池性能也有很大的提高.在此基础上,本研究以线性扫描伏安法(LSV)考察Ni/β-Mo2C对氧还原反应(ORR)的催化行为,并采用Ni/β-Mo2C作为双边催化剂构建MFC.结果表明,Ni/β-Mo2C对ORR有显著的催化作用,而且其催化效果随负载量增加而增强;当以肺炎克雷伯氏菌(L17)为产电微生物、2 g/L葡萄糖为燃料,双边催化剂的载量为6.0 mg/cm2 Mo2C时,该MFC产电量相当于载0.5 mg/cm2 Pt催化剂MFC产电量的78.3%.

  20. Improvement of hydrogen-storage properties of MgH2 by addition of Ni and Ti via reactive mechanical grinding and a rate-controlling step in its dehydriding reaction

    Science.gov (United States)

    Song, Myoung Youp; Kwak, Young Jun; Lee, Seong Ho; Park, Hye Ryoung; Kim, Byoung-Goan

    2013-07-01

    In a shift from prior work, MgH2, instead of Mg, was used as a starting material in this work. A sample with a composition of 86 wt% MgH2-10 wt% Ni-4 wt% Ti was prepared by reactive mechanical grinding. Activation of the sample was completed after the first hydriding cycle. The effects of reactive mechanical grinding of Mg with Ni and Ti were discussed. The formation of Mg2Ni increased the hydriding and dehydriding rates of the sample. The addition of Ti increased the hydriding rate and greatly increased the dehydriding rate of the sample. The titanium hydride, TiH1.924, was formed during reactive mechanical grinding. This titanium hydride, which is brittle, is thought to help the mixture pulverized by being pulverized during reactive mechanical grinding and further to prevent agglomeration of the magnesium by staying as a hydride among Mg particles. A rate-controlling step for the dehydriding reaction of the hydrided MgH2-10Ni-4Ti was analyzed by using a spherical moving boundary model on an assumption that particles have a spherical shape with a uniform diameter.

  1. Synthesis of carbon supported ordered tetragonal pseudo-ternary Pt 2 M'M'' (M = Fe, Co, Ni) nanoparticles and their activity for oxygen reduction reaction

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Minh T.; Wakabayashi, Ryo H.; Yang, Minghui; Abruña, Héctor D.; DiSalvo, Francis J.

    2015-04-01

    Alloying Pt with 3d transition metals has attracted much attention due to their reduced Pt content and reports of enhanced electrocatalytic activity for proton exchange membrane fuel cell applications. However, synthesizing ordered nanocrystalline intermetallics in the sub-10 nm range can be challenging. Here, we report on the co-reduction synthesis of ordered ternary Pt-base transition metal intermetallics with particle sizes in the regime of 3–5 nm. Since differences in the activity of PtM (M = Fe, Co, Ni) for oxygen reduction reaction (ORR) have been reported, we explored their combinations: Pt2FeCo, Pt2FeNi, and Pt2CoNi. These ternary intermetallic nanoparticles crystallized in P4/mmm space group upon annealing in a protective KCl matrix. The electrocatalysts were prepared by dispersing these intermetallics onto a carbon support using ethylene glycol and various sonication techniques. A combination of analytical techniques including powder X-ray diffraction, thermogravimetric analysis, electron microscopy and electrochemical methods have been used in this study. The oxygen reduction reaction activity and stability of the catalysts were tested in 0.1 M HClO4 and 0.1 M H2SO4 using cyclic voltammetry and rotating disk electrode voltammetry. The correlations between the composition, structure, morphology and activity of the intermetallics have been established and are discussed.

  2. Looking for mine of the petroleum in China, especially, looking for mine activities in the foreign enterprise; Chukajinminkyowokoku ni okeru sekiyu no tanko. Tokuni gaikokukigyo ni okeru tanko katsudo

    Energy Technology Data Exchange (ETDEWEB)

    Hirai, Makoto

    1999-01-01

    Modern petroleum industry after the Chinese establishment (1950) rose mainly by the Russian cooperation, and main discovery such as oil field 1959 was made as to the discovery in 1955 oil field. After that, that activities range was limited to middle Kunisaki department land stage by a master though looking for mine which is characteristic of China, development were made by Russian withdrawal and there was discovery such as a task hill oil field in the victory oil field and 1964 big port oil field for 1962 and for 1976. (NEDO)

  3. 3D seismic survey in Honjo, Akita. Problems and struggles in acquisition and processing; Akitaken Honjo koku ni okeru sanjigen jishin tansa. Genba sagyo to data shori ni okeru mondaiten

    Energy Technology Data Exchange (ETDEWEB)

    Imahori, S.; Kotera, Y.; Nakanishi, T. [Japan Energy Development Co. Ltd., Tokyo (Japan)

    1997-05-27

    Honjo mining area where investigations are conducted is hilly and has a complicated terrain with gas pipes buried in the ground just under the access road disabling the proper positioning of shock-generating large excavators or vibrators. Auger`s shallow hole shooting method is used in this survey to execute blastings at 639 points. In this method using charge depths of 4m, different from the conventional method using deeper charge depths (20-25m), surface waves prevail in the shot records giving rise to a new problem of removing them in the stage of data processing. The 2D filter that is a powerful tool in 2D data processing is not available in a 3D-survey where the tracing intervals are irregular in the shot records. In the effort of this time, a window length as a parameter in the direction of time is specified, and the F-X dip filtering method is employed in which any event that linearly continues beyond a certain number of traces in the said window is eliminated as a linear noise. It is recommended that the weighting function be changed in the direction of space since surface wave velocities are different at different locations. 1 fig., 1 tab.

  4. Interface chemical states of NiO/NiFe films and their effects on magnetic properties

    Institute of Scientific and Technical Information of China (English)

    于广华; 柴春林; 朱逢吾; 赖武彦

    2002-01-01

    Ta/NiOx/Ni81Fe19/Ta multilayers were prepared by rf reactive and dc magnetron sputtering.The exchange coupling field (Hex) and the coercivity (Hc) of NiOx/Ni81Fe19 as a function of the ratio of Ar to O2 during the deposition process were studied.The composition and chemical states at the interface region of NiOx/NiFe were also investigated using the X-ray photoelectron spectroscopy (XPS) and peak decomposition technique.The results show that the ratio of Ar to O2 has great effect on the nickel chemical states in NiOx film.When the ratio of Ar to O2 is equal to 7 and the argon sputtering pressure is 0.57 Pa,the x value is approximately 1 and the valence of nickel is +2.At this point,NiOx is antiferromagnetic NiO and the corresponding Hex is the largest.As the ratio of Ar/O2 deviates from 7,the exchange coupling field (Hex) will decrease due to the presence of magnetic impurities such as Ni+3 or metallic Ni at the interface region of NiOx/NiFe,while the coercivity (Hc) will increase due to the metallic Ni.XPS studies also show that there are two thermodynamically favorable reactions at the NiO/NiFe interface: NiO+Fe=Ni+FeO and 3NiO+2Fe=3Ni+Fe2O3.These interface reaction products are magnetic impurities at the interface region of NiO/NiFe.It is believed that these magnetic impurities would have effect on the exchange coupling field (Hex) and the coercivity (Hc) of NiO/NiFe.

  5. Prevention countermeasure for breeding of iron bacteria in ion-exchanged water. Junsui ni okeru tetsu bakuteria hassei boshi taisaku

    Energy Technology Data Exchange (ETDEWEB)

    Yoshimura, S. (Nippon Steel Corp., Tokyo (Japan))

    1994-06-01

    The wear troubles of the water-supplying pump as well as water-supplying control valve due to the blocking-up of the strainer caused by the abnormal breeding of iron bacteria in ion-exchanged water have been occurring frequently since several years before in Oita Manufactory of Nippon Steel Corporation. The strainer provided in front of the pumps for supplying the water to each users are blocked up by the iron bacteria bred abnormally in the tanks of ion-exchanged water. Consequently, the cavitation phenomenon of water-supplying pump happens and the inside wear occurs. It is revealed by the results of the examination on the prevention countermeasure for breeding of iron bacteria carried out by the present authors that the destruction and the extinction of the cells are brought about by the concentrated electrification of the iron bacteria due to the electrification in the ion-exchanged water. In this paper, the principles, progress of study and development, the results of the practical tests in respect of prevention countermeasure for breeding of iron bacteria in ion-exchanged water by turning on electricity are described. The conventional means of frequency transformation are used in the experiment, and the betterment such as the increase of capacity of condenser is added because of the high electricity-resistance of ion-exchanged water. 13 figs., 1 tab.

  6. Deep sedimentary structure model beneath the Osaka plain; Osaka heiya ni okeru shinbu chika kozo no model ka

    Energy Technology Data Exchange (ETDEWEB)

    Miyakoshi, K.; Kagawa, T.; Echigo, T. [Osaka Soil Test, Osaka (Japan)

    1997-05-27

    Restructuring was carried out on a sedimentary basin structure model of the Osaka plain including Osaka Bay by using newly obtained underground structural data. After the Hygoken-nanbu Earthquake of 1995, a large number of underground structure investigations have been performed in Osaka Bay and urban areas of Kobe and Osaka. However, very few surveys have been done in areas peripheral to Osaka Prefecture, such as the Ikoma area. Therefore, an attempt has been made to increase the number of measuring points to acquire underground structural data of these areas. Estimation of basic rock depths has utilized the dominant cycles in H/V spectra obtained from micro vibration survey, and good correlation of the base rock depths derived by a refraction exploration and a deep-bed boring investigation. With regard to bed division and P- and S- wave velocities in sedimentary beds in the Osaka sedimentary basin, an underground structure model was prepared, which was divided into four beds according to the refraction exploration and the micro vibration investigation. Data obtained by using this model agreed well with depth data acquired from physical exploration and other types of investigations. However, no good agreement was recognized in the data for such areas where the basic depth changes abruptly as the Rokko fault and the Osaka bay fault. 6 refs., 8 figs., 2 tabs.

  7. Magnetic susceptibility measurements in Yellowstone National Park, USA; Beikoku Yellowstone kokuritsu koen ni okeru genchi jikaritsu sokutei

    Energy Technology Data Exchange (ETDEWEB)

    Okuma, S. [Geological Survey of Japan, Tsukuba (Japan)

    1997-05-27

    For the purpose of interpreting data of the aeromagnetic anomalies in Yellowstone National Park in the U.S.A., in-situ magnetization intensity measurements have been carried out in 1994 and 1995 on geological outcrops of rocks in that area. Comparisons and discussions were given on the measurement results, and existing rock magnetic data and aeromagnetic anomaly data available for the area. Outside the Yellowstone caldera, part of granitic gneisses among the Precambrian granitic gneisses and crystalline schists distributed to the north has an abnormally high magnetization intensity of 1 {times} 10 {sup -2} SI. This could be a powerful anomaly source for the high magnetic anomaly in this area. Paleogene volcanic rocks distributed widely in the eastern part of the park also have magnetization intensity as high as 1 {times} 10 {sup -2} SI or higher, which are also thought a powerful anomaly source in this area. Part of Pleistocene basalts which are exposed partially in the western part of the park has also very high magnetization intensity at 1 {times} 10 {sup -2} SI or higher. This suggests correlation with the magnetic anomaly in the east-west direction distributed in this area. Quaternary rhyolites are more magnetic than Quaternary welded tuffs, which should give greater effects to the magnetic anomaly. 10 refs., 5 figs.

  8. Examination of poisonous gas in Matsumoto city, Nagano Pref.; Matsumotoshi ni okeru yudoku gas chudoku jiko eno taio

    Energy Technology Data Exchange (ETDEWEB)

    Furuhata, A. [Nagano Research Inst. for Health and Pollution, Nagano (Japan)

    1996-02-10

    This report explains how the Sanitation and Pollution Laboratory of Nagano Prefecture came to isolate sarin and describes some examples of information gathering efforts which played a very important role in the sarin isolating process. The Matsumoto sarin incident took place late at night of June 27, 1994. The laboratory acting upon a request of the prefectural pollution control section completed its specimen collecting in the afternoon of June 28. In its efforts to search for the casualty-causing substance, the laboratory gathered information from the National Institute of Hygienic Sciences, Japan Poison Information Center, JICST, Matsumoto Health Center, and Professor Naito of the Tsukuba University. Next, the analysis/retrieval team started collecting data from the GC-FPD and GC-MS. The peak in the curve pointed to sarin, and this also made it clear that the substance was neither soman nor tabun. A question remained unanswered as to why sarin, a nerve gas which is a weapon of war, existed in a peaceful castle town of Matsumoto. The greatest difficulty in the sarin isolating process came from the lack of the standard substance to which sarin was to be referred to. Sarin was determined to be the responsible substance only after a general judgement based on the results of comparison with the retention indexes, analysis using the GC-MS (EI) and then GC-MS (CI), and experiments using Japanese cyprinodont. 8 refs., 1 tab.

  9. Decay of weak pressure waves in a low pressure tube; Teiatsu kannai ni okeru bisho atsuryokuha no gensui

    Energy Technology Data Exchange (ETDEWEB)

    Takiya, T.; Terada, Y.; Komura, A. [Hitachi Zosen Corp., Osaka (Japan); Higashino, F.; Abe, H. [Tokyo Univ. of Agriculture and Technology, Tokyo (Japan). Faculty of Technology; Abe, M. [National Lab. for High Energy Physics, Tsukuba (Japan)

    1996-04-25

    The characteristics of pressure wave propagation in a vacuum tube have been investigated experimentally from the viewpoint of vacuum protection in the beam lines of a synchrotrons radiation facility. Baffle plates having a single orifice of 5, 10 or 15 mm in diameter were installed in shock tubes 5 m in length, and 36.6 or 68.8 mm in diameter, in order to show the pressure wave or shock wave propagation as a model for the beam line. To evaluate the decay of pressure waves pressure changes with time at several locations along the side wall as well as at the end wall of the tube were measured. The results show that the effect of the orifices on pressure wave propagation and its decay is significant. The present investigation may contribute to the design and construction of high energy synchrotrons radiation facilities with long beam lines. 11 refs., 9 figs., 2 tabs.

  10. Ebara`s environmental management system and ISO14001; Ebara ni okeru kankyo management system to ISO14001

    Energy Technology Data Exchange (ETDEWEB)

    Umeda, M. [Ebara Corp., Tokyo (Japan)

    1999-04-20

    Situations encompassing environmental problems are recently undergoing drastic changes on a worldwide scale. The number of business locations which have been certified as ISO14001 sites in Japan has exceeded 1,392 by the end of November 1998, a surge which is expected to outrun that experienced regarding ISO9000 sites. In December 1997, the United Nations Frame Work Convention on Climate Change (COP3) was held in Kyoto, Japan to discuss the prevention of the global warming effect. The following discusses how Ebara`s environmental management system is related to problems and solutions discussed in this symposium. Discussion is also made on the impact of environmental management on enthusiastically carried out environment-related businesses. Finally, discussion is made on Ebara`s future environmental management system, i.e. as an outcome of past and current efforts in Ebara`s continuous improvement on environmental management, including Ebara`s 5 areas which have attained the ISO14001 standard. (author)

  11. Feasibility study of various geophysical methods at the Nojima fault; Nojima danso ni okeru kakushu butsuri tansaho no tekiyo jikken

    Energy Technology Data Exchange (ETDEWEB)

    Takahashi, T.; Nozaki, K.; Shima, H.; Yamane, M.; Igarashi, T. [OYO Corp., Tokyo (Japan)

    1996-05-01

    This paper reports a feasibility study of various geophysical methods at the Nojima fault. A shallow bed investigation (to a depth of several ten meters) was performed at the Nojima-Hirabayashi area, a very shallow bed investigation (to a depth of several meters), a shallow bed investigation and a medium depth bed investigation (to a depth of several hundred meters) at the Kokura area, and a very shallow bed investigation at the Nashimoto area. Combinations of two to four investigation methods were used according to the objectives and depths of the investigations at each area. The combinations were selected from the following methods: seismic investigations (P-wave reflection and N-wave reflection methods), electric investigation using the IP image method, electromagnetic investigation using the VLF method, underground radar investigation, micro-gravity investigation, and gravity investigation. The result may be summarized as follows: in places where a fault forms a boundary between base rocks and a sedimentation bed, it was possible to identify clearly position of the fault, and estimate inclination angles and vertical shift; and during the medium depth investigation at the Kokura area, identification was made on a geological structure (deformation of a sedimentation bed above the base bed) which is important in verifying the nature of an active fault. 2 refs., 5 figs., 1 tab.

  12. Using of the geophysical methods to an investigation in city; Toshi ni okeru butsuri tansaho no tekiyo

    Energy Technology Data Exchange (ETDEWEB)

    Sato, S. [Oyo Corp., Tokyo (Japan)

    1995-02-10

    Some of the exploration methods are taken up out of the geophysical methods, which have made drastic change by technological advancement, to discuss their technological development and application in cities. The elastic wave exploration is classified into the refraction method which uses refracted waves and the reflection method which utilizes reflected waves. Shallow reflection method allows visual observation of the complex underground structure, and is an excellent exploration method which provides highly accurate data. There are many types in the electrical exploration. New exploration methods have been developed as a result of improvement in the computer performance, advancement in the technology of numerical analysis, and improvement in the performance of exploration equipment, and they are being applied to the electrical exploration in many fields including tunnel and dam construction works. Geotomography is an application of the technology of medical tomography to ground exploration. Underground radar method is a method of investigating the ground structure by radiating electromagnetic waves from the ground surface in similar way to that of the reflection method and capturing the reflected waves from underground. 8 refs., 7 figs.

  13. Global Environment, human activity, and recycling of resources. Chikyu kankyo to ningen katsudo ni okeru shigen recycling

    Energy Technology Data Exchange (ETDEWEB)

    Nakahiro, Y.; Wakamatsu, T. (Kyoto Univ., Kyoto (Japan). Faculty of Engineering)

    1991-04-18

    Discussion is made on the recycling of resources which is one the very important problems for the global environment and human activity. In consideration of the limited natural resources and utilization by the human race of the resources for long, recycling of resources'' for saving resources is extremely important. The scale of the waste treatment industry in Japan is estimated to be between 4 to 5 trillion yen which exceeds 1% of the GNP with the trend of increase year by year, and the industrial waste treatment industry is taking root in Japan. Recycling'' can be grouped in three methods, i.e. recovery of materials, conversion of materials, and conversion of energy. The primary object of recycling is to spare resources and save energy. Recycling is of deep significance from the viewpoint of energy saving. There is a big merit in the conservation of dumping sites. Making best use of the useful secondary resources in the wastes is directly connected with the solution to the problems of prolongation of resources'' and conservation of global environment'' with which the human race is now confronted. 7 refs., 7 figs., 2 tabs.

  14. Education for hydraulics and pneumatics in Nara National College of Technology; Nara Kogyo Koto Senmon Gakko ni okeru yukuatsu kyoiku

    Energy Technology Data Exchange (ETDEWEB)

    Hayakawa, Y. [Nara Technical Coll., Nara (Japan)

    2000-03-15

    In the electronic control engineering course, basic knowledge is taught for mechanics, electronics/electricity, control, robotics, information processing, etc., with the purpose of bringing up practical mechatronics engineers, and then, training is conducted so that the students are able to deal with these subjects comprehensively. In the subject of hydraulics and pneumatics for the special course, a lecture on hydraulic and pneumatic control is given in the second year, where structures of hydraulic and pneumatic actuators are explained as well as the principle of operation and the control method. As the related experiment, measurement of liquid viscosity coefficient and flow measurement by a Venturi tube are carried out in the fourth year of the regular course. In addition, carried out in the fifth year are the measurement of stress by trailing velocity distribution of an object and the measurement of pressure distribution around a column. As a subject for graduation theses, a mobile carrier for welfare nursing is being developed using a pneumatic actuator. Development of a suitable actuator is also being developed simultaneously. In the education of electronic control engineering, it is essential to give the students understanding of hydraulic and pneumatic actuator control centering on the role of mechatronics. (NEDO)

  15. Water quality and water pollution sources in Poyang lake, China; Poyang ko ni okeru suishitsu chosa to odakugen kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Ito, M. [Shin-Nippon Meteorological and Oceanographical Consultant Co. Ltd., Tokyo (Japan)

    1996-01-10

    This paper summarizes the current status of water quality and pollution sources in Poyang Lake in China. The lake is located in Chianghsi Province of China, and a largest fresh water lake in China that flows out into the Yangtze river. The basin is surrounded by mountains on three sides and faces the Yangtze on one side, whereas the plains formed by the lake and the rivers flowing in extends in the center of the basin. The plains around the lake has the city of Nanchang, the capital of the province, the city of Jiujiang (both cities have a population of about 4 million, respectively), and four other cities with a size of one million people including Jingdezhen. Water supply system in the basin is used in a 37% area of the urban areas, and no sewage facilities of whatsoever are available as of 1991. The lake has COD of about 3 mg{times}1/l. No severe pollution by organic matters is seen. While the T-P concentration is at a high level, PO4-P is low. Majority of phosphorus flowing into the basin exists in the form trapped in soil particles. In order to maintain the current water quality in the future, waste water treatment is required in the basin. Construction of an oxidation pond in the vast land exposed during the drought period is a measure that can be tackled relatively easily. 1 fig., 4 tabs.

  16. Measurement improvements of heat flux probes for internal combustion engine; Nainen kikan ni okeru netsuryusokukei no kaihatsu to kento

    Energy Technology Data Exchange (ETDEWEB)

    Tajima, H.; Tasaka, H. [Miyazaki University, Miyazaki (Japan)

    1997-10-01

    In heat flux measurement in engines, material properties of a heat flux probe and numerical prediction of those influence have been discussed rather than practical measurement accuracy. This study featured the process for the quantitative examination of heat flux probes. Although the process required direct comparison among all the probes and additional measurements in a constant volume bomb, precision of heat flux measurement was greatly improved so that the essential characteristics of heat transfer in engines can be detected. 9 refs., 8 figs., 1 tab.

  17. Simulation of speed control in acceleration mode of a heavy duty vehicle; Ogatasha no kasokuji ni okeru shasoku seigyo simulation

    Energy Technology Data Exchange (ETDEWEB)

    Endo, S.; Ukawa, H. [Isuzu Advanced Engineering Center, Ltd., Tokyo (Japan); Sanada, K.; Kitagawa, A. [Tokyo Institute of Technology, Tokyo (Japan)

    1997-10-01

    A control law of speed of a heavy duty vehicle in acceleration mode is presented, which is an extended version of a control law in deceleration mode proposed by the authors. The control law is based on constant acceleration strategy. Using the control law, target velocity and target distance can be performed. Both control laws for acceleration and deceleration mode can be represented by a unified mathematical formulae. Some simulation results are shown to demonstrate the control performance. 7 refs., 9 figs., 2 tabs.

  18. Improvement of vehicle stability in cornering on uneven road; Akuro senkaiji ni okeru sharyo no anzensei kojo

    Energy Technology Data Exchange (ETDEWEB)

    Tobimatsu, K.; Harada, M.; Harada, H. [National Defense Academy, Kanagawa (Japan)

    1997-10-01

    The active control of vehicle suspensions and rear wheel steering systems in turning on uneven roads is analyzed by means of LQR control theory, assuming that cornering forces depend on tire normal loads in addition to tire slip angles. The authors quantitatively investigated the effectiveness of the integrated control of the active suspension and the rear wheel steering, comparing the contributions of each individual system. Furthermore, in this paper, the role of the chassis control and driver control are studied in order to improve the stability of vehicle motion disturbed by the road surface. 4 refs., 9 figs.

  19. Seismic reflection survey in Omama fan area, Gunma prefecture; Gunma Omama senjochi ni okeru hanshaho jishin tansa

    Energy Technology Data Exchange (ETDEWEB)

    Yamaguchi, K.; Kano, N.; Yokokura, T.; Kiguchi, T.; Yokota, T.; Matsushima, J. [Geological Survey of Japan, Tsukuba (Japan)

    1996-10-01

    Seismic reflection survey was performed for the Medial Tectonic Line, an important geological tectonic line in the Kanto plains, at Kushibiki district, Saitama prefecture in the north-western part of the Kanto plains. It was estimated that movements of the basement were different in the individual sides of the active fault. In this study, the seismic reflection survey was performed at the Omama fan area, Gunma prefecture, which is located at the north-eastern extension of the Kushibiki plateau, to grasp the structure of basement to the depth of about 1.0 s of return travel time, and the upper sediments. Two traverse lines passing Ota city, Kiryu city, and Nitta town were used. Southern part of the traverse line-1 was in the bottom land in the middle of Tone river, and northern part was in the Omama fan area. The ground surface along the traverse line was flat. Hachioji heights are the heights elongating in the NW-SE direction and having relative height of 100 to 200 m against the surrounding plain. Another traverse line-2 was set on the steep slope having relative height more than 100 m. The Brute stack time section of each traverse line was characterized by the gradient reflection surface AA of the traverse line-1. It was suggested that the AA or intermittent parts of reflection surfaces deeper than AA may relate to the tectonic lines in the more ancient geological ages. 2 figs., 1 tab.

  20. Fault analysis in the very shallow seismic reflection method; Gokusenso jishin hanshaho ni okeru danso kaiseki. 1

    Energy Technology Data Exchange (ETDEWEB)

    Nagumo, S.; Muraoka, S.; Kaida, Y.; Takahashi, T. [OYO Corp., Tokyo (Japan)

    1996-10-01

    To effectively use the very shallow seismic reflection for active fault survey, a method has been investigated by which fault structures can be appropriately reconstructed from the fault information detected in the original records. The first step of reconstructing the fault system from the travel time reflection curve was to grasp an outline of fault structure from the patterns of travel time curve observed in the original record. For the very shallow seismic reflection method, especially, the low velocity layers in a shallow part succeeding from the ground surface made the issue complicated. Then, the travel time reflection curves were calculated in the case of existing several horizontal reflection surfaces in the surface layer. The constant values, mean velocities to the depth at individual reflection surfaces were used for the approximation of velocities. The outline of fault structure was grasped from the observation of original record. Then, the structure was reconstructed from the travel time curves. When the mean velocity in the medium was known, reconstruction of the feature of reflection surfaces from the travel time curves could be determined by simple mapping. When the mean velocity was unknown, it was calculated using the reciprocal travel time from the common reflection surface for individual reflection surfaces. 7 figs.

  1. Study of evaluation for grouting effect in a borehole; Yakueki chunyu koka hyoka gijutsu ni okeru ichikosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, H.; Matsuo, T. [Fukuoka Municipal Transportation Bureau, Fukuoka (Japan); Yamauchi, Y.; Imanishi, H. [Osaka Soil Test, Osaka (Japan)

    1996-10-01

    For the foundation improvement works by grouting in a borehole, evaluation of grouting effect is one of the most important management items. The grouting design and works are sometimes reconsidered depending on the evaluation of grouting effect during the test injection. The purpose of the evaluation of grouting effect is to grasp the range of improvement and consolidation after the injection, and to judge and estimate the strength and permeability of the consolidation part. This paper describes the judgment method of the strength using PS logging results and borehole televiewer (BHTV) logging results. The reflection intensity (Ir) by the BHTV logging increased after the grouting, which showed a same tendency as that using S-wave and P-wave velocities (Vs and Vp) before and after the grouting. This was considered to demonstrate the grouting effect. A relation was obtained between the Vs, Vp and Ir before and after the grouting, which was expressed by following equation. Ir=0.143{times}Vs-70=0.093{times}Vp-110. The relation with the dynamic elastic coefficient (Ed) was also obtained as follow; Ir=0.0013{times}Ed. 9 figs.

  2. Interaction effects on combustion of alcohol droplet pairs; Alcohol kei nenryo niekiteki no nensho ni okeru kansho koka

    Energy Technology Data Exchange (ETDEWEB)

    Okai, K.; Ono, Y.; Moriue, O.; Shiba, S.; Araki, M.; Tsue, M.; Kono, M. [The University of Tokyo, Tokyo (Japan); Nomura, H. [Nihon Univ., Chiba (Japan). Coll. of Industrial Technology; Shiga, S. [Gunma University, Gunma (Japan). Faculty of Engineering

    2000-02-25

    Experimental investigation was conducted on two droplet-array combustion of methanol and methanol/dodecanol mixture fuels in microgravity. For methanol, effects of ambient pressure and droplet spacing were examined. Results show that the droplet lifetime decreases with increasing spacing at relatively low pressure and the droplet lifetime becomes independent of spacing at higher-subcritical and supercritical pressures. For methanol/dodecanol mixture, effects of pressure, fuel composition were investigated in terms of occurrence of disruption. Disruption of droplet during combustion was demonstrated both for single droplet and droplet pairs. (author)

  3. 1000m depth boring at Inagawa, Hyogo prefecture. 1. Overviews; Hyogoken Inagawamachi ni okeru 1000m boring chosa. 1. Gaiyo

    Energy Technology Data Exchange (ETDEWEB)

    Sato, T.; Kusunose, K.; Cho, A.; Tosha, T. [Geological Survey of Japan, Tsukuba (Japan); Kiyama, T.; Yamada, F. [Mitsui Construction Co. Ltd., Tokyo (Japan); Aizawa, T. [Sancoh Consultants Co. Ltd., Tokyo (Japan)

    1996-05-01

    Various field experiments were carried out using a 1000m deep borehole at Inagawa town, about 10km north of the focus of the Hanshin-Awaji Great Earthquake and directly above the area where shallow earthquake activities have intermittently occurred. These experiments included stress measurement by hydraulic fracturing, hydrophone-aided VSP, permeability tests and observation of various types of logging. The laboratory experiments were also carried out, including measurement of various properties and stresses of the core samples. The stress-depth relationship, determined by the hydraulic fracturing method, shows that the stress gradient well coincides with the Western Japan standard at a depth up to 700m, whereas it is approximately twice as high as the standard at a depth of 946m, at which core disking and borehole break-out are clearly observed, and hence stresses conceivably concentrate locally. Orientation of the maximum horizontal compressive stress is E-W at a depth of around 600m, but greatly changes to NNW-SSE at a deeper position. 4 refs., 5 figs.

  4. Cut down the peak daytime demand for electricity at the residence; Jutaku ni okeru denryoku fuka heijunka

    Energy Technology Data Exchange (ETDEWEB)

    Ishihara, O. [Kumamoto University, Kumamoto (Japan). Faculty of Engineering

    1996-09-05

    For leveling of power load in small-scale buildings and houses, a test house with actual size was constructed in order to examine soil heat storage system using photovoltaic power generation system and nighttime power. A hundred of polycrystal silicone solar cells with about 5 kW and twenty of amorphous ones were fixed on the roof, to connect with commercial power source by the system interconnection having inverse power flow. For leveling of power load in the periods of heating and cooling, soil heat storage system was applied using nighttime power. Pipes for circulating cooling and heating water were embedded. Heat pump was operated only in the time zone of nighttime power, to obtain cooling and heating source for fan coil unit in the daytime. The sold power was larger than purchased power under continuous cooling condition for twelve hours in summer. Since cooling load was supplied from nighttime power with lower price, there was a large peak cut effect in the daytime. As a result of the tests using a house with actual size, the system was found to be applied practically both in summer and in winter. Effectiveness of peak cut of power load in summer was also provided. 7 refs., 10 figs., 2 tabs.

  5. Future vision of advanced telecommunication networks for electric utilities; Denki jigyo ni okeru joho tsushin network no shorai vision

    Energy Technology Data Exchange (ETDEWEB)

    Tonaru, S.; Ono, K.; Sakai, S.; Kawai, Y.; Tsuboi, A. [Central Research Institute of Electric Power Industry, Tokyo (Japan); Manabe, S. [Shikoku Electric Power Co., Inc., Kagawa (Japan); Miki, Y. [Kansai Electric Power Co. Inc., Osaka (Japan)

    1995-06-01

    The vision of an advanced information system is proposed to cope with the future social demand and business environmental change in electric utilities. At the large turning point such as drastic reconsideration of Electricity Utilities Industry Law, further improvement of efficiency and cost reduction are requested as well as business innovation such as proposal of a new business policy. For that purpose utilization of information and its technology is indispensable, and use of multimedia and common information in organization are the future direction for improving information basis. Consequently, free information networks without any limitation due to person and media are necessary, and the following are important: high-speed, high-frequency band, digital, easily connectable and multimedia transmission lines, and cost reduction and high reliability of networks. Based on innovation of information networks and the clear principle on advanced information system, development of new applications by multimedia technologies, diffusion of communication terminals, and promotion of standardization are essential. 60 refs., 30 figs., 5 tabs.

  6. Future petroleum geophysicists and SEGJ; Sekiyu gyokai ni okeru butsuri tansa gijutsusha no shoraizo to Butsuri Tansa Gakkai eno kitai

    Energy Technology Data Exchange (ETDEWEB)

    Takahashi, A. [Japan Petroleum Exploration Corp., Tokyo (Japan)

    1998-08-01

    This paper describes future petroleum geophysicists and an anticipation to SEGJ (The Society of Exploration Geophysicists of Japan). Among various elemental technologies, it is undoubted that three-dimensional seismic exploration would be a main technology for prospecting petroleum gas. In the early stage of three-dimensional exploration, an improvement of accuracy for geological evaluation was a major purpose based on the successful exploratory drilling. In the 1990`s, some companies have a policy in which three-dimensional exploration is initially employed especially for the marine seismic prospecting as a major exploration technology. Since simple structures have been already prospected, it is required to prospect more complicated traps with higher accuracy. It is also required to shorten the turnaround time from the initial prospecting to the start of production. Furthermore, the three-dimensional exploration is used as a control technology for advancing the recovery by improving the accuracy of reservoir management. It is required for the geophysicists to have wide knowledge with keeping original exploration technologies. 2 refs.

  7. Feasibility study on introducing new energy systems into Asian villages; Asia sonraku ni okeru shin energy donyu kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    For improvement of living standards in unelectrified areas of Asia, the feasibility of new energy power generation systems was surveyed. The degree of electrification of local areas is different every country, and Thailand is ahead of other countries, while Laos and Cambodia are most unelectrified. Power supply of 100W/house seems to be adequate for local areas because of weather condition, housing situation and life-style. Economic support and education on electricity are necessary for poor areas. Although needs for new energy is increasing, the priority is given to industrial and urbanized areas because of cost and investment effects, and remote areas are dependent on grant- in-aid. Resources of photovoltaic, wind power and micro- hydraulic energies are abundant, however, selection of energy and verification of its usability are important, and the local energy density maps were thus prepared. In introduction of new energy, after selection of energy suitable for an area concerned, such geographical and social conditions should be surveyed as road condition, water rights, land utilization, economic support system, policy and intention of inhabitants. 76 refs., 68 figs., 91 tabs.

  8. Rejection of salts in nanofiltration of skim milk; Dasshinyu no nano roka ni okeru enrui no soshiritsu

    Energy Technology Data Exchange (ETDEWEB)

    Sato, I.; Kikuchi, M.; Sakurai, K. [Morinaga Milk Industry Co., Ltd., Tokyo (Japan)

    2000-11-10

    The authors carried out nanofiltration of skim milk and analyzed the salt rejection data using the extended Nernst-Planck equation. The following observed rejections of major constituents in salts were obtained. Na and K: 50 to 60 %, Cl: -5 to 15 %, Ca, Mg and P: > 97 %. It is considered that since Ca and Mg are mostly combined with phosphate and citrate in milk, they were rejected by a sieving effect, thus producing high rejections. Electroneutrality in permeate, and no-electric-current condition in solute flux are observed, respectively. In the subsequent analysis, the authors used a set of proposed assumptions, (1) a complete rejection of solute except Na, K and Cl by the membrane, (2) existence of a fixed charge in skim milk due to impermeable ions of proteins, etc. Rejection of Na, K and Cl calculated from the analysis are in good agreement with those of the experimental data. (author)

  9. Interphase boundary structure and transformation mechanism in diffusional phase transformations; Kakusan hentai ni okeru iso kaimen kozo to hentai kiko

    Energy Technology Data Exchange (ETDEWEB)

    Furuhara, T.; Maki, T. [Kyoto University, Kyoto (Japan)

    1997-05-20

    This paper discusses a lattice changing mechanism in diffusional phase transformations (atom diffusion rate determination) based on observations through a high-resolution electron microscope. If a parent phase and a generated phase have different crystal structures, change in lamination occurs as a result of a step generated on a terrace with good consistency moving in the horizontal direction. In addition, it has been thought that removal of atoms occurs due to random diffusion jump in a riser or a kink which has a locally inconsistent structure, and no surface undulations will occur. On the other hand, growth interfaces are consistent in martensite transformation, and atomic correspondence is univocal in the parent phase and the generated phase. Also in diffusion transformation accompanying distribution of displacement type elements, the surface undulations will appear as in the case of the martensite transformation. This fact suggests that, also in the diffusional transformation, not only the terrace interface, but also the riser or kink interface having been thought inconsistent conventionally are all consistent or semi-consistent as in the martensite transformation. It also suggests that lattice correspondence exists between the parent phase and the generated phase. 30 refs., 16 figs., 1 tab.

  10. Superplasticity of low carbon HSLA steel during bainite transformation. Teitanso teigokinko no beinaito hentai ni okeru chososei kyodo

    Energy Technology Data Exchange (ETDEWEB)

    Nakajima, H.; Yamamoto, S.; Miyaji, H.; Furubayashi, E. (National Research Inst. for Metals, Tsukuba, Ibaraki (Japan))

    1993-12-01

    Recently, the development of high strength low alloy steel (HSLA steel) of untempered type is advanced by using the comparatively high strength and excellent tenacity of the bainite or martensite of carbon remained being transformed. In the present researches, the superplasticity during the bainite transformation due to the continuous cooling and changes of the structure as well as the mechanical properties due to the superplastic deformation are examined with the samples of Mn-Cr-Mo system HSLA steel. The results obtained therefrom are shown as follows. The temperatre range of B[sub S] and bainite transformation is moving to the higher temperature side along with the increasing of the applied stress when it is over 60 MPa. The bainitic structure is composed of the mixture lath-like bainitic ferrite and granular bainitic ferrite in the use of having no applied stress, while the percentage of the latter increases simultaneously with the increasing of the applied stress. Transformation superplastic strain is increasing together with the increasing of the applied stress, and its increasing is over the linear function when the applied stress is above about 50 MPa. 22 refs., 9 figs., 2 tabs.

  11. Education for hydraulics and pneumatics in Nippon Institute of Technology, Department of Mechanical Engineering; Nippon Kogyo Daigaku ni okeru yukuatsukyoiku

    Energy Technology Data Exchange (ETDEWEB)

    Terashima, Y. [Nippon Institute of Technology, Saitama (Japan)

    2000-03-15

    Described herein is education of hydraulics and pneumatics in Nippon Institute of Technology. Department of Mechanical Engineering has fluid dynamics, mechatronics II, air conditioning, heat transfer engineering, and facility and equipment engineering as the themes related to hydraulics and pneumatics. The control engineering courses have the pneumatics-related themes of supply of pneumatic pressure for a short time and methods for cutting off pneumatic pressure when the piston reaches the dead center, as the energy-saving type driving methods for pneumatic cylinders; measurement of frictional force by the experiments on low-friction cylinders; and researches on improvement of stiffness of pneumatic cylinder type actuators for control valves, among others. Students are directly involved in equipment designs, fabrication and experiments. Many machines and facilities are now easily handled, and operated according to manuals. To prepare graduation theses only by the aid of personal computers is not adequate for education of students in this age, when they have less chances for education through experiences in affluent environments. The mechanical engineering students are given chances for practical education through experiments and graduation thesis preparation. However, it is necessary for general engineering students to be more exposed to technical practices. (NEDO)

  12. Non-linear mechanical simulations in space structures engineering; Uchu kozobutsu kogaku ni okeru hisenkei kikai rikigaku simulation

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, K. [Kinki Univ Osaka (Japan)

    1997-08-05

    Space structure engineering comes under the combination of different engineering fields. Role of numerical analysis and simulation is large in space structure engineering. Considering space structure engineering as an application of non-linear mechanical simulation, constrains with simulation technology and analysis examples are explained in this paper. Following important points are confirmed by simulating the motion of membrane under external force acting on inner and outer surfaces at a particular point of square satellite model which rotates in tension membrane. When the external force is removed, each material point and membrane centre move with vibration, however centre of gravity of satellite moves very rapidly along the vertical direction of membrane centre. Further external disturbance (which develops on material points) propagates at all material points and membrane centre as a twisted wave. Maximum relative displacement between inner surface and outer surface decreases with the increment of initial angular velocity but not on the points of upper membrane. Fluctuation of position motion of satellite resulted from external disturbance is become small as initial rotation angular velocity increases. 10 refs., 6 figs., 2 tabs.

  13. Education for fluid power in department of mechanical engineering of Sophia University; Jochi Daigaku Kikai kogakuka ni okeru yukuatsu kyooiku

    Energy Technology Data Exchange (ETDEWEB)

    Tsukiji, T. [Sophia University, Tokyo (Japan). Faculty of Faculty of Science and Technology

    2000-03-15

    Curricular guidelines are that importance be attached in the educating policy to the primary subjects of study and that compulsory subjects are to be acquired through practice. Out of primary subjects, those which should better be learned by all the students are set as compulsory subjects. Related subjects are divided into fluid-related subjects and control-related subjects. Experiments are conducted of the 'inspection of orifice flowmeter and Bourdon tube pressure gage,' 'fluid friction in round tube,' and 'servo-mechanism.' In a lesson on drafting, hydraulic equipment provided by business corporations is used. It is hoped that educating units be provided. Subjects of research for graduation and master's theses are the turbine-driven pump, constant pressure source system, hydraulic drive system, application of control theory to an injection molding machine, highly intelligent fluid, noise reduction for an automotive compressor, state of fluid in a hydraulic control valve, analysis of flow in pneumatic equipment elements, and cavitation in a vane pump. More than half of these subjects are pursued in collaboration with industrial or Government circles. It is expected that the Society will be an organization to benefit the students. (NEDO)

  14. Optimal control of reflux ratio for batch distillation; Bacchi joryu ni okeru kanryuhi no saiteki kido to seigyo

    Energy Technology Data Exchange (ETDEWEB)

    Morimoto, Jun [Sankyo Corp., Tokyo (Japan); Suzuki, Mutsumi [Tohoku University, Miyagi (Japan). Department of Chemical Engineering

    1999-03-10

    To obtain maximum production under minimum utility-cost, the optimal operation of reflux ratio is considered for a batch distillation process. Pontryagin's maximum principle is one of the solutions to calculate such an optimal operation, but it requires extensive trial and error. In this paper, a faster algorithm is proposed to modify the initial values of Hamilton's multiplier. With the rapid growth of computer power, this algorithm will provide a way to realize the real-time optimization and control of the reflux ratio. To reduce the on-line calculation, a control table for the optimal operation can by calculated off-line as a function of state variables. These control methods provide the real optimal operation for a given evaluation function. (author)

  15. Analysis of fuel spray characteristics for premixed lean diesel combustion; Kihaku yokongo diesel kikan ni okeru nenryo funmu kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Sasaki, S.; Harada, a.; Miyamoto, T.; Akagawa, H.; Tsujimura, K.

    1997-10-01

    Premixed lean diesel combustion (PREDIC) makes it possible to achieve low NOx emission. It is an important factor to make the homogeneous spray formation for PREDIC. In this paper presents I the effect of the spray dispersion on emission characteristic were analyzed with the spray observation and engine test. Pintle type nozzle, which has different feature from orifice type nozzle, are used to form the hollow cone spray. As a result, the pintle type nozzle having grooves to generate the swirl flow, makes the reduced penetration in comparison with the hole nozzle under low ambient gas pressure. And it could improve THC, CO emissions at low NOx emission condition. 7 refs., 12 figs., 1 tab.

  16. Water monitoring and its information management system in China; Chugoku ni okeru suishitsu monitoring to joho kanri system

    Energy Technology Data Exchange (ETDEWEB)

    Quan, H.

    1996-01-10

    This paper summarizes the water monitoring system (WMS) in China applied mainly to surface water and operated within the competence of the Environmental Protection Agency. The WMS consists of a national water monitoring network and a water information system that monitors surface water periodically. The WMS comprises water monitoring stations classified from class 1 to class 4, which are located in 2,222 locations. Stations from class 1 to class 3 are operated by using computers, but class 4 stations are still incapable to use floppy disks to perform information transmission. When an information management system is completed at the China-Japan Friendship Environmental Protection Center being constructed by gratis assistance from the Japanese Government, transmission of water quality data will become possible by means of the cable line system in addition to the table system and the floppy system. The water quality data are published to general people in the forms of Chinese gazette for the environmental conditions, the environment yearbook, and the reports on environmental quality. However, the more important is to publish more publications to make people aware of the actual state of water pollution and have them cooperate in environment preservation. 4 refs., 1 fig.

  17. Needs for intelligent field sensors in petrochemical plants. Sekiyu kagaku plant ni okeru intelligentter dot fieldter dot sensor eno needs

    Energy Technology Data Exchange (ETDEWEB)

    Tsukahara, T. (Idemitsu Kosan Co. Ltd., Tokyo (Japan))

    1990-08-05

    This report explains the process sensors used in petrochemical plants. To establish a safety and accident preventing systems, the function of a sensor to substitute the five senses of an operator is demanded. A man inspects using the senses of seeing, hearing, touch and smell, and takes measures judging from all factors, not from the state of one point. For a wide-range monitoring function, there is a need for a robot which is loaded with sensors of various intelligences and which moves freely at the field. When many sensors are configurated for the wide-range monitoring, the maintenance of system comes into question. The sensor with intelligent functions recently developed can contribute to the maintenance because it is highly accurate and it has the function of self-diagnosis. If it becomes possible to process data with the sensor at the field utilizing the intelligent function, the central control room will be miniaturized and automatization will be pushed forward remarkably. 3 refs., 2 figs.

  18. Polymer-based matrix composites in general industries. Ippan sangyo bun'ya ni okeru kobunshiki fukugo zairyo

    Energy Technology Data Exchange (ETDEWEB)

    Kenmochi, K. (National Institute of Materials and Chemical Research, Tsukuba (Japan))

    1994-02-15

    This paper summarizes the course of development of polymer-based matrix composites (PMC) begun in the 1950's, their future problems, and prospects. Because of PMC being a petroleum product, the changing period before and after the first and second oil crises (1974-1983) has seen even a negative growth from the declined product price out of increased material cost. However, the materials have been continuing expansion in such applications year after year for two decades since then as plant, marine vessel, and housing materials. The course of their development to date has included such proliferation impeding factors as unproved reliability, high production cost, and legal regulations because of being new materials. However, the ardent technical development efforts having produced a number of products including hybrid FRP, particularly the fundamental technology development studies sponsored by the Ministry of International Trade and Industry, have improved properties and reliability and contributed largely to expanding practical applications. Sought in different functions expected in PMC in the future would be application of bionic designs, transfer from functional quality to sensitive quality, and development of material recycling techniques. 8 refs., 11 figs., 1 tab.

  19. Engineering technologies for steel structure applied to Trans-Tokyo bay highway project; Tokyowan odan doro ni okeru kokozo gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Furumuro, K.; Kobayashi, T.; Kanda, K. [Kawasaki Steel Corp., Tokyo (Japan)

    1996-03-01

    The Trans-Tokyo Bay Highway is a 15.1 km toll road that spans the Tokyo Bay from Kawasaki City in Kanagawa Prefecture to Kisarazu City in Chiba Prefecture by a bridge, an undersea shield tunnel, and two man-made islands. Many new technologies and methods were introduced to construct a large-scale structure safely, rationally, and in a short time on the weak ground under the depth of water in a seismic region such as Tokyo Bay. Kawasaki Steel participated in this project in: (1) development and construction of a revetment structure to which the technology of an oil drilling jacket was applied, (2) design and construction of a large-sized bridge with long-span and multi-span continuous girders on the sea, and (3) design and installation of a mud water treatment module for the shield tunnel constructed on the sea. As a result, the bearing-capacity measurement technology based on the dynamic method of a large diameter steel pipe pile was developed in item (1). The long-term corrosion-proof method using titanium clad steel was developed in item (2), and the way to construct the treatment facilities of approximately 5100 tons in item (3). 3 refs., 12 figs.

  20. Steel structure (bridge and building); Doboku/kenchiku bun`ya ni okeru yosetsu gijutsu no tenkai

    Energy Technology Data Exchange (ETDEWEB)

    Fukazawa, M. [Yokogawa Bridge Corp., Tokyo (Japan)

    1996-01-05

    In this article, the trends of welding engineering are discussed in two groups, namely bridges and steel frames. First of all, in the field of bridges, as the themes of technical innovation of steel bridges, the challenge to build long span bridges, coping with new structural forms, and rationalization of general bridges are selected. Concerning very long bridges, considerable elongation of its spans and technological development for materials, design, construction and erection relating to improvement of profitability become inevitable. Besides, in addition to the functions of bridges, the bridges playing the roles of environmental and/or artistic structures become many, thereby the cases of using welding for the site joints increase. As the measure for rationalize bridge construction, it is to reduce steel weight and working costs for increasing profitability, and the progress of welding technology therefor has been observed. With regard to the manufacture of bridge portions in a factory, labor saving, automatization and robotization of in-house welding have been made, and bridge maintenance as well as pursuance of attaining the state of maintenance free are also important. The trend that the bridge load is becoming larger and enhancement of earthquake resistance are also important. Regarding steel frames, functionalization of steel, making steel very thick, various automatization of manufacturing, and pursuance of earthquake resistant safety are being made. 14 refs., 7 figs.

  1. NEDO`s solar energy program in developing countries; Hatten tojokoku ni okeru NEDO no taiyo energy project

    Energy Technology Data Exchange (ETDEWEB)

    Honda, T. [New Energy and Industrial Technology Development Organization, Tokyo, (Japan)

    1998-05-31

    This paper describes the solar energy program promoted in developing countries by NEDO. Research of photovoltaic power generation systems for middle-scale villages has been conducted in Indonesia between FY 1984 and FY 1989. International cooperative demonstration development for photovoltaic power generation systems has been conducted in Nepal, Mongolia, Thailand and Malaysia for five to six years since FY 1994. For the research of solar heat, air heat collection type drying systems using solar heat has been promoted between FY 1993 and FY 1998. Employment of solar micro hydraulic power hybrid systems is planned in regions with rainy and dry seasons. In FY 1997, photovoltaic power generation systems were constructed in Gansu, Sinkiang Uighur, and Hopeh in China for operation researches. Durability tests have been conducted in Oman. A plan of construction of photovoltaic power generation systems with a capacity from a few MW to 1 GW at maximum in deserts is to be promoted as international cooperative activities with PVPS of IEA and CTI. Japan will play a major role on the activities as a proposal country based on the achievement of PVTEC. 6 figs., 2 tabs.

  2. Possibility of EV with solar cells on the new traffic system; Shinkotsu system ni okeru solar car no kanosei

    Energy Technology Data Exchange (ETDEWEB)

    Fujii, I.; Kojima, S. [Meiji University, Tokyo (Japan)

    1997-11-25

    A possibility of a new traffic system was studied for a solar car which is light in weight, small in size and low in speed (cruising speed: 20 km/h) and does not need so much power because of the use for short distance. In the new traffic system, people travel short distance in city by solar car, and use trains for travel between cities. By installing solar cells on roofs, etc. of houses and buildings such as garages around stations, power needed for solar car and incidentally required can be supplied. Assuming the short distance transportation, the car is for one person with a height of luggage space of 70cm, mean length of 165cm, and floor height of 50cm above the ground. In case that the power generation by solar cells (256.5W) is at maximum with no shading during travel on conditions of load weight of 10kg, personnel weight of 70kg, and total weight of 250kg, it was found that solar cells can supply 89% of the required output under test road travel at speed of 20 km/h. A viability of the solar car proposed here is great. A possibility at the time of mode road travel is also studied. 10 refs., 3 figs., 1 tab.

  3. Desiliconization process of hot metal at blast furnance casthouse. Koro chusho ni okeru yosen no tatsukei shori

    Energy Technology Data Exchange (ETDEWEB)

    Uchiyama, T.; Takeda, K.; Taguchi, S.; Shinohara, K.; Kato, H.; Matsumoto, T. (Kawasaki Steel Corp., Tokyo (Japan))

    1990-09-01

    The Kawasaki Steel has developed several types of desiliconization facilities at blast furnace runner and applied to blast furnaces according to their individual local conditions. In response to the restriction in the maximum feed rate and mass velocity of desiliconization reagent by the slag foaming and splash formations for the desiliconization method without slag removal at the casthouse, three methods, i.e., a top feed method, a blasting by one stage, and a blasting by two stages were developed, according to increases in the required feeding rate of the desiliconization reagent. In the case that the desiliconization slag is removed at the blast furnace runner, it was demonstrated that the injection method by use of an immersion lance was effective because of its high oxygen efficiency in desiliconization. An simulation model of desiliconization was also developed, and the effect of the lance shape on oxygen efficiency in desiliconization was evaluated. On the basis of the simulation results, the oxygen efficiency in desiliconization was able to be increased to 60% by the improvement of the injection conditions. 8 refs., 18 figs., 3 tabs.

  4. Present status and amendable subjects of brewery CIM. Beer kojo ni okeru CIM no genjo to kadai

    Energy Technology Data Exchange (ETDEWEB)

    Eguchi, T.; Kimura, T. (Asahi Breweries, Ltd., Tokyo (Japan))

    1991-12-10

    Though the beer consumption is being smoothly increased, there has been a considerable change in consumers prime taste of beer for these several years. The present report exhibits the computer integrated manufacturing system introduced in Ibaraki Brewery, Asahi Beer to be operated as per the target. The introduction of that system aimed at an execution of integrated administration, high particularly in quality control, to integrate the information and control of total production activities from the production planning to the product delivery. Together with the structuring of information system for the integrated production, aim was taken also at the heightening in quality control, heightening in administration level, labor saving and newly conceived distribution system. As for the structuring of hardware, the system was functionally classified into production planning level, administration level for the manufacturing and distribution, and control level for the processing and distribution. Each of those levels was accommodated with the most suitable machinery thereon. The future problems are about the quality control data measurement and widened application of database. 5 figs.

  5. Application of membrane technology to food industry; Shokuhin kogyo bun'ya ni okeru maku riyo

    Energy Technology Data Exchange (ETDEWEB)

    Kamata, T.; Nakajima, M. [Univ. of Tsukuba, Tsukuba (Japan)

    2000-08-05

    In the food industry, the membrane technologies are used practically for concentration of fruit juice and milk, etc. as reverse osmosis, for decolorization and desalination of liquid seasoning as nanofiltration, for bacteria elimination, etc. as micro-filtration, for recovery and purification of the protein as ultra-filtration, and for kitchen salt manufacturing and desalination as electrodialysis. In this paper, the state of utilization of membranes and the trend of recent research and development in the food industry are described. At first, a utilization of membranes in the dairy industry field, the fruit juice processing field, the alcoholic beverage field, the seasoning field, the honey purification field, the protein field and the fats and oils processing field are described. Next, as a film emulsification technology, a preparing process of W/O emulsion in which the pressurized water phase is penetrated through a hydrophobic membrane into the oil phase of the opposite side, and a preparing process of W/O emulsion in which the pressurized oil phase is penetrated through a hydrophilic film are described. The emulsification technology using the micro-channel made of the silicon chip, which is developed by the author is introduced. (NEDO)

  6. Dream of future on human-machine cooperative system; Ningen robot system ni okeru fluid power gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, Y. [Hosei University, Tokyo (Japan). Faculty of Engineering

    2000-01-15

    This paper describes the human-machine cooperative system and fluid power technology. Most of Japanese robot R and D activities shifted from early R and D on hydraulic or pneumatic driving to that on simple electric driving, and development of fluid power technology as actuator and control technology is retarded. For creating an artificial work environment with a presence by virtual reality formation technology, an equipment (actuator) directly acting such five senses (sensor) of operators as visual, auditory, pressure and contact senses is essential. Pneumatic actuator is extremely suitable for such one because of its small size, light weight, safety and high power density. Robocup has been held as the soccer game of many autonomous robots. For the soccer game of human beings and robots, development of such technologies for advanced autonomous robots is necessary as realtime processing, advanced intelligence, human friendliness, safety, high-efficiency high-power actuator equivalent to human muscle, and energy source. (NEDO)

  7. Magnetic constraints of basement structure offshore of western Kyushu, Japan; Kyushu seiho kaiiki ni okeru jiki ijo no kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Okuma, S.; Nakatsuka, T. [Geological Survey of Japan, Tsukuba (Japan); Ishihara, T. [Japan National Oil Corp., Tokyo (Japan)

    1996-05-01

    This paper describes the results from the qualitative analysis of magnetic anomalies offshore of western Kyushu and from an analysis by a three-dimensional two-layer model inversion. The analysis ranged from Kyushu on the east to Jeju Island on the west and from the southern part of the Korean Peninsula on the north to Tanegashima and Yakushima Islands on the south, namely, the area of 580km from east to west and 580km from south to north. The analytical data used was Magnetic Anomaly Map of Asia (GSJ and CCOP, 1994). In the qualitative analysis, a pseudogravity anomaly map and a pole gravity anomaly map were prepared from the total magnetic force anomaly map by means of a frequency filter operation. As a result, it was noted that two distinctive magnetic high belts existed in the margin of the Tunghai Shelf, extending from the sea area to the west of the Nansei Islands continuously to NNE, and being distributed transversely through the Goto sedimentary basin. Additionally, in the inversion analysis, it was demonstrated that the magnetic basement became shallow at the margin of the Tunghai Shelf north of latitude 31 degrees north, extending nearly in the NNE direction through west of the Goto Islands, west of Tsushima Island, and continuing to the southern coast of the Korean Peninsula. 6 refs., 4 figs.

  8. MT2-D inversion analysis in Kakkonda geothermal field; Kakkonda chinetsu chiiki ni okeru MT ho nijigen kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Yamane, K.; Takasugi, S. [Geothermal Energy Research and Development Co. Ltd., Tokyo (Japan); Miyazaki, S. [Japan Metals and Chemicals Co. Ltd., Tokyo (Japan); Uchida, T. [New Energy and Industrial Technology Development Organization, Tokyo, (Japan)

    1996-05-01

    Data, collected from an MT method-assisted survey conducted in the Kakkonda geothermal region in 1987, was re-examined, and a new structure was found. The review was carried out by use of a 2D analysis in the TM mode. According to the 1D analysis of 1987 and the geological data gathered then, it is estimated that the resistivity structure of this region runs in the northwest-southeast direction. A northeast-southwest traverse line was set for this analysis, orthogonal to the strike, and the impedance at each observation spot was caused to rotate to this direction across the whole range of frequency. Furthermore, in 1994-95, surveys were conducted using arrayed CSMT/MT methods. All these sum up to indicate that a high-resistivity region extends northwest in the southwestern part of the Kakkonda river but that there exists a low-resistivity region of several 10 Ohm m centering about the B traverse line. The high-resistivity region deep in the ground being the target of excavation in the Kakkonda region, to collect knowledge about this high-resistivity is important, and here the effectiveness of the 2d analysis has been verified. 5 refs., 11 figs.

  9. Remote reference processing in MT survey using GPS clock; MT ho ni okeru GPS wo mochiita jikoku doki system

    Energy Technology Data Exchange (ETDEWEB)

    Yamane, K.; Inoue, J.; Takasugi, S. [Geothermal Energy Research and Development Co. Ltd., Tokyo (Japan); Kosuge, S. [DRICO Co. Ltd., Tokyo (Japan)

    1996-05-01

    A report is given about the application of a synchronizing system using clock signals from GPS satellites to a remote reference method which is a technique to reject noise from the MT method. This system uses the C/A code out of the L1 band waves from NAVSTAR/GPS satellites. The new system was operated in MT method-using investigations conducted at China Peninsula, Aichi Prefecture, and Izu Peninsula, Shizuoka Prefecture, with the reference points placed several 100km away in Iwate Prefecture on both occasions. It was found as the result that it is basically possible to catch signals from the GPS at any place, that the signals are accurate enough to be applied to time synchronization for the MT method, and that the signals assure a far remote reference method with a separation of several 100km between the sites involved. The referencing process at high frequencies whose feasibility had been doubted proved a success when highly correlated signals were exchanged between two stations over a distance of several 100km. 5 refs., 9 figs.

  10. Noise and vibration reduction technology in hybrid vehicle development; Hybrid sha kaihatsu ni okeru shindo soon teigen gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Yoshioa, T.; Sugita, H. [Toyota Motor Corp., Aichi (Japan)

    2000-03-01

    Accomplishing both environmental protection and good NVH performance has become a significant task in automotive development The first-in-the-world hybrid passenger car of mass production. 'Prius', has achieved superior NV performance compared with conventional vehicles with a 1.5-liter engine along with 50% reduction of fuel consumption and CO{sub 2} emissions. low HC, CO and NO{sub x} emissions. This paper describes NV reduction technology for solving problems peculiar to the hybrid vehicle such as engine start/stop vibration, drone noise at low engine speed and motor/generator noise and vibration. It also mentions application technology of low rolling resistance tires with light weight wheels and recycled material for sound proofing. (author)

  11. Function of Regenerator in the multi staged regenerative refrigerator; Tadan chikureigata reitoki ni okeru chokureiki no kino

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, T.; Nogawa, M.; Zhu, S. [Aisin Seiki Co., Ltd., Aichi (Japan)

    1999-11-10

    On the function of regeneration vessel, which is the base element of regeneration type refrigerating machine, there is two of viewpoint as a heat exchanger greatly separate and viewpoint as an energy converter. Here, to begin with, the function of regeneration vessel as energy converter is arranged, and especially, both expression is compared on the expression of the regeneration vessel efficiency. In addition, the essence of multistage used in the cooling of the regeneration type refrigerating machine is examined from the viewpoint of the function of the regeneration vessel. (NEDO)

  12. Design method for heat exchanger of stirling cycle machines; Sutaringu saikuru kikan ni okeru netsu kokanki no sekkei shuho

    Energy Technology Data Exchange (ETDEWEB)

    Sekiya, H. [Sanyo Electric Co., Ltd., Tokyo (Japan)

    1999-11-10

    Recently, the Stirling cycle organization attracts the attention as 1 of the countermeasure to the global environmental problem, and the tendency of various application equipment developments heightens. The main factor is in constructing CFC elimination refrigeration air conditioner, and the development example as an engine for power source of refrigerating machine used in the ultra-low-temperature region and equipment variously is reported. In this paper, practical design tool and design examination case are introduced, while design technique of heat exchanger, which is the most important in design development of these, ST refrigerating machine and ST engines is described. (NEDO)

  13. Power feeding to terminal devices in optical subscriber network; Hikari fuaiba tsushin ni okeru tanmatsu kiki eno kyuden

    Energy Technology Data Exchange (ETDEWEB)

    Yamasaki, M

    1998-09-01

    This paper outlines present state of the feeding system in the light access system in consideration of backup in case of home power failure. In the optical communication, equipment with bilateral conversion function for light and electricity has to be installed both on communication service side and home side. Outline of the light access system and equipment requiring backup are shown. The following items are explained: main types of the light access system, such as FTTC (fiber to the curb), FTTP (fiber to the pole), FTTH (fiber to the home) and HFC (hybrid fiber coax), and the feeding system; problems on feeding system for the light access system. Key elements of ONU (optical network unit) for FTTH and construction of the ONU power source are illustrated. The ONU power source is composed of a backup power supply unit and main body supply unit. Backup power is indispensable to the ONU and analog telephones: output is supplied by the backup batteries in power failure. For miniaturization of the backup power source, power supply circuits and backup batteries have to be miniaturized simultaneously. History of miniaturization is explained on the experimental models. 6 refs., 7 figs., 1 tab.

  14. Reinstatement of material research in the 21st century; 21 seiki ni okeru zairyo kenkyu no fukken

    Energy Technology Data Exchange (ETDEWEB)

    Shinbara, K. [Osaka Univercity, Osaka (Japan). Institute of Scientific and Industrial Research

    2000-03-10

    Just before the 21st century, Japan is demanded most importantly of reforming the industrial structures, breeding new industries, and working on global environment and energy problems. To solve these problems, emergence of material technologies based on original ideas is indispensable. However, Japan lacks a temperament to value original ideas and support them in positive manners. Structuring unique ideas and concepts with high originality is one of the most important intellectual production activities for human being. Understanding that these activities require incessant challenging spirit and accumulation of exhaustive efforts, a system should be structured to give the highest honor to researchers and groups who have made successes in this respect. It should be understood that development of the material technologies requires huge amount of fund, human resources and time, and national strategies should be established as required. Habitat segregation is to be moved forward in research and development, and a system will be built that links effectively the seed oriented research by universities and national research institutes with the need oriented research by business enterprises. The 21st century will be an age that many people can dream of their own success. (NEDO)

  15. Measurement results of BHTV logging at the geothermal well. 1; Chinetsusei ni okeru BHTV kenso no sokutei kekka. 1

    Energy Technology Data Exchange (ETDEWEB)

    Lin, S. [Geophysical Surveying and Consulting Co. Ltd., Tokyo (Japan); Nakanishi, S.; Shimizu, I. [Electric Power Development Co. Ltd., Tokyo (Japan)

    1997-05-27

    In association with excavation of the No. 135 steam producing well in the Onikubi geothermal power plant in Miyagi Prefecture, shapes of production zones and drilling-induced fracture (DIF) were acquired from the borehole televiewer (BHTV) data. The BHTV logging shoots sound waves onto well walls of wells filled with fluid and detects the reflection waves to investigate the state of the well walls. Vertical fracture with opening lengths from 2 to 3 m were found at depths of about 1232 m and 1312 m. Water run-off has occurred at a depth of about 1312 m during the excavation, to which these vertical fractures might have contributed possibly. In depths of about 1232 m and 1312 m, fractures inclining toward north-east direction and south-west direction are predominant. Some fractures in the depth of about 1333 m incline toward east-south-east direction and west-north-west direction. Fracture inclination azimuth in all of the present logging sections is predominantly in north-east direction and south-west direction. When the DIF is considered to show the maximum compression azimuth, the earth`s crust stress azimuth is generally in east-west direction, which crosses slightly obliquely with the running direction of the predominant fracture in this well. 1 ref., 7 figs.

  16. Shallow seismic reflection prospecting in Hachiro-kata reclaimed land; Hachirogata kantakuchi ni okeru senbu hanshaho jishin tansa

    Energy Technology Data Exchange (ETDEWEB)

    Kitsunezaki, C.; Fukutome, T.; Matsumoto, S.; Noda, K.; Sato, T. [Akita University, Akita (Japan). Mining College; Hayashi, H.; Ishii, E.; Yamanaka, Y.; Matsuno, K.; Mikuni, S. [Suncoh Consultant Co. Ltd., Tokyo (Japan)

    1997-05-27

    Along the Japan Sea coast in Akita Prefecture and in the vicinity, there exist active fault groups, such as the Kitayuri thrust fault group in the south and Noshiro thrust fault group in the north. It is estimated that there is another fault, running from Akita City located between the above-said two thrust fault groups into the Hachiro-kata reclaimed land, roughly connecting the two thrust fault groups. This third fault is supposed to be related to the hypocenter of Tencho Earthquake of 830, but its location and structural configuration are not known, and it is not known whether it is an active fault, either. Investigations are conducted using S- and P-waves. The greatest problem in the use of P-waves is that there exists a layer in which signal attenuation is high and transmission is anomalously slow. This problem is ascribed to the layer pore water rendered unsaturated though slightly by the inclusion of air bubbles, and is explained for the most part by the White model. A survey using S-waves is advantageous in that it does not experience no difficulty of this kind. In the P-wave cross section, a structure supposed to be an inversion layer is observed at a level deeper than 200m. In the case of the S-wave method, more details of the shallow structure will be available when the degree of CMP stacking is augmented as usual. 2 refs., 9 figs., 1 tab.

  17. 3D seismic experiment in difficult area in Japan; Kokunai nanchiiki ni okeru sanjigen jishin tansa jikken

    Energy Technology Data Exchange (ETDEWEB)

    Minegishi, M.; Nakagami, K.; Tanaka, H. [Japan National Oil Corp., Tokyo (Japan). Technology Research Center

    1997-05-27

    Difficult area in this context means an exploration-difficult area supposed to store oil/gas but retarded in exploration for the lack of knowledge about the geological structure due to poor quality of available seismic survey records. Discussed in this paper is a survey conducted into an area covering the southern part of Noshiro-shi, Akita-ken, and Yamamoto-cho, Yamamoto-gun, Akita-ken. An area size suitable for data collection at a target depth of 2500m is determined using an interpretation structure compiled on the basis of available well data and 2D seismic survey data. The plan for siting shock points and receiving points is modified case by case as restrictive factors come to the surface (resulting from the complicated hilly terrain, presence of pipes for agricultural water, etc.). The peculiarities of seismic waves in the terrain are studied through the interpretation of the available well data and 2D seismic survey data for the construction of a 3D velocity model for the confirmation of the appropriateness of the plan for siting shock points and receiving points. Efforts are exerted through enhanced coordination with the contractor to acquire data so that a technologically best design may be won within the limits of the budget. The quality of the data obtained from this experiment is in general better than those obtained from previous experiments, yet many problems remain to be settled in future studies about exploration-difficult areas. 4 refs., 4 figs., 1 tab.

  18. Relation between frequency of seismic wave and resolution of tomography; Danseiha tomography kaiseki ni okeru shuhasu to bunkaino no kankei

    Energy Technology Data Exchange (ETDEWEB)

    Fujimoto, M.; Watanabe, T.; Ashida, Y.; Sassa, K. [Kyoto University, Kyoto (Japan). Faculty of Engineering

    1997-05-27

    With regard to the elastic wave exploration, discussions have been given on the relationship between frequency and resolution in P-wave velocity tomography using the initial travel time. The discussions were carried out by using a new analysis method which incorporates the concept of Fresnel volume into tomography analysis. The following two arrangements were used in the calculation: a cross hole arrangement, in which seismic source and vibration receiving points were arranged so as to surround the three directions of a region extending 250 m in the horizontal direction and 500 m in the vertical direction, and observation is performed between two wells, and a permeation VSP arrangement in which the seismic source is installed on the ground surface and receiving points installed in wells. Restructuring was performed on the velocity structure by using a total of 819 observation travel times. This method has derived results of the restructuring according to frequencies of the seismic source used for the exploration. The resolution shown in the result of the restructuring has become higher as elastic waves with higher frequency are used, and the size of the structure identified from the restructuring result has decreased. This fact reveals that sufficient considerations must be given on frequencies of elastic waves used according to size of objects to be explored. 4 refs., 4 figs.

  19. Fault analysis in the very shallow seismic reflection method. 2; Gokusenso hanshaho ni okeru danso kaiseki. 2

    Energy Technology Data Exchange (ETDEWEB)

    Nagumo, S.; Muraoka, S.; Takahashi, T. [Oyo Corp., Tokyo (Japan)

    1997-05-27

    Fault analysis is required in addition to the ordinary process of structural analysis (CDP stacking) for the examination of discontinuity in the reflection horizon in question. The fault shape restoration principle is that the reflection point of a reflection wave observed at a certain receiving point is on an ellipse with the shock point and receiving point at its focal points and that the sum of the distances between the reflection point and the focal points is equal to the reflection wave propagation time. The DMO velocity is worked out by calculation using the positive travel time and inverse travel time from the common reflection surface. When the reflection surface is inclined by {theta}, the average interval velocity/cos{theta} is called the DMO velocity. When the reflection surface inclination and the average interval velocities are determined separately in this way, the position of the reflection point may be worked out, and this enables the calculation of the amount of migration (lateral movement). The reflection wave lineups carried by the original record are picked up one by one, and the average interval velocities are treated very prudently. After such a basic DMO conversion treatment, the actualities of the fault are described fairly correctly. 3 figs.

  20. Transition of wind power utilization technology in the 20th century; 20 seiki ni okeru furyoku riyo gijutsu no hensen

    Energy Technology Data Exchange (ETDEWEB)

    Ushiyama, I. [Ashikaga Inst. of Tech., Tochigi (Japan)

    2000-04-01

    Windmills are one of the oldest prime movers and have been used for more than 700 years in Europe. The transition from low speed windmills for grain grinding and water pumping to high speed wind turbines for electric power generation had occurred at the end of 19{sup th} century. This paper, at first, reviews the windmill technologies and the researchers before 20th century. Then describes the back ground of how the wind power generator has existed and how the four pioneers developed their wind power generator. The historical developments of windmills to wind turbines in this century are studied focusing mainly on Danish activities. Then, the effort of the development of large wind turbine such as Smith-Putnum's first MW machine in U.S.A. and other mammoth machine concept are introduced. The new concept machines such as Savonius and Darrieus wind turbines in 1920s to 1930s are also explained. Finally, the novel technologies of wind turbine covering larger machines, variable speed generators, special wing sections for wind turbines, theoretical analysis method of wind turbine performance, offshore wind turbines, and wind turbine control technologies are stated. (author)

  1. Properties and decay modes of hot nuclei produced in the reaction: {sup 36}Ar on {sup 58}Ni and detected with INDRA device; Proprietes et modes de desexcitation des noyaux chauds observes dans la reaction {sup 36}Ar sur {sup 58}Ni avec le detecteur INDRA

    Energy Technology Data Exchange (ETDEWEB)

    Nalpas, L. [CEA Centre d`Etudes de Saclay, 91 - Gif-sur-Yvette (France). Dept. d`Astrophysique, de la Physique des Particules, de la Physique Nucleaire et de l`Instrumentation Associee]|[Paris-11 Univ., 91 - Orsay (France)

    1997-01-01

    Hot nuclei are formed in heavy ion collisions covering the Fermi energy domain. According to the excitation energy deposited into these nuclei, several de-excitation processes can be observed, in particular the emission of complex fragments (Z {>=} 3) which remains poorly understood. The GANIL facility offers the possibility to cover the excitation function for the Ar on Ni reaction over a broad energy range from 32 to 95 MeV/u where the hot nuclei evolve from classical `evaporation` to complete `vaporization` into light particles (neutrons, isotopes of H, He). The study of reaction mechanisms shows that from peripheral to central collisions the total cross section is dominated by binary dissipative collisions. Both partners coming from well-characterized events with the INDRA detector are reconstructed using the `Minimum Spanning Tree` method. Thus excitation energy up to 20 MeV/A are reached in the most violent collisions at the highest bombarding energy. The deposited energy is not shared in the mass ratio between the quasi-projectile and the quasi-target, the quasi-projectile being hotter. For total excitation energies ranging roughly from 2 to 8 MeV/A, the proportion of `multifragmentation` events increases to reach a plateau at about 10 MeV/A due to the rising probability to have complete `vaporization` of the system above 8 MeV/A. The steady increase of the temperature extracted from the double isotopic He-Li ratios with excitation energy for the quasi-projectile suggests a progressive evolution of the de-excitation processes as predicted by statistical models. No signal of first order liquid-gas phase transition is seen in our data. (author) 124 refs.

  2. Reaction of bis(o-phosphinophenyl)silane with M(PPh3)4 (M = Ni, Pd, Pt): synthesis and structural analysis of η2-(Si-H) metal(0) and pentacoordinate silyl metal(II) hydride complexes of the Ni triad bearing a PSiP-pincer ligand.

    Science.gov (United States)

    Takaya, Jun; Iwasawa, Nobuharu

    2011-09-21

    Reactions of bis(o-(diphenylphosphino)phenyl)methylsilane with M(PPh(3))(4) (M = Ni, Pd, Pt) were investigated. When M = Ni or Pd, synthesis and isolation of η(2)-(Si-H) complexes of mononuclear Ni(0) and Pd(0) were achieved for the first time as frozen intermediates for oxidative addition of the Si-H bond. Structural analysis by X-ray and NMR spectroscopy disclosed that their η(2)-(Si-H) structures were maintained in both solid and solution states and coordination of the Si-H bond to the metal center was relatively weak. On the other hand, reaction with a platinum(0) complex afforded two kinds of pentacoordinate silyl platinum(II) hydride complexes having a PSiP-pincer ligand, which underwent unique thermal isomerization from a square-pyramidal cis-H-Pt-Si to a trigonal-bipyramidal trans-H-Pt-Si isomer. Mechanistic investigations revealed that this isomerization proceeded via an intramolecular rearrangement process probably through a turnstile rotation.

  3. 纳米Ni-Al2O3体相催化剂的TEM和TPR表征及反应机理探讨%TEM and TPR of Nanosized Ni-Al2 O3 Bulk Catalysts and Reaction Mechanism

    Institute of Scientific and Technical Information of China (English)

    闫玉玲; 宋锦玉; 王鼎聪

    2014-01-01

    Using the Super-Solubilization Nanometer Self-Assembly method, bulk Ni-Al2 O3 catalyst is prepared with nickelnitratehexahydrate as the precursor and urea as precipitation agent,the mixture of the surfactant-gather isobutylene maleic acid triethanolamine esters and petroleum hydrocarbon-150SN as template agent.The Ni-Al2 O3 catalysts were characterized by TEM and TPR,and reaction mechanism of precipitation was studied.The results indicate that nanosized Ni-Al2 O3 bulk catalyst has a crystalline form with not only spherical shape,but also nanorod and nanometer silk,etc.Particles prepared by this method have good dispersion and uniform size,and narrow diameter distribution is observed between 10~50 nm.The Ni-Al2 O3 reduced by hydrogen also has a crystalline form,and nanostructure of reduced Ni-Al2 O3 is more orderly than before.Particles size after reduction is still in the nanoparticles scope.TPR results show that there are two reduction peak appeared in the structure of nanometer bulk Ni-Al2 O3 catalyst,and the low-temperature peak is NiO,high temperature reduction peak attributes to spinel structure which produced by the interaction of nickel and aluminum oxide.%以尿素为沉淀剂、六水硝酸镍为前躯体、表面活性剂(聚异丁烯马来酸三乙醇胺酯)和石油烃-150SN混合物作为模板剂,采用超增溶自组装法制得纳米 Ni-Al2 O3体相催化剂。对 Ni-Al2 O3体相催化剂进行了 TEM表征和氢气还原曲线(TPR)分析,并对沉淀反应的机理进行了探讨。结果表明,超增溶自组装纳米Ni-Al2 O3体相催化剂是晶体结构,形状除了球形,还有纳米棒、纳米丝等其他形状;通过超增溶自组装法制备出的微粒分散性良好,颗粒均匀、粒径分布(10~50 nm)较窄。Ni-Al2 O3经过 H2还原后仍是规整有序的晶体,而且还原后比还原前的晶体结构要规整有序,还原后的颗粒的粒径仍在纳米粒子范围内,属于纳米颗粒。TPR 分析结果表

  4. Barrier distributions and signatures of transfer channels in the Ca40+Ni58,64 fusion reactions at energies around and below the Coulomb barrier

    Science.gov (United States)

    Bourgin, D.; Courtin, S.; Haas, F.; Stefanini, A. M.; Montagnoli, G.; Goasduff, A.; Montanari, D.; Corradi, L.; Fioretto, E.; Huiming, J.; Scarlassara, F.; Rowley, N.; Szilner, S.; Mijatović, T.

    2014-10-01

    Background: The nuclear structure of colliding nuclei is known to influence the fusion process. Couplings of the relative motion to nuclear shape deformations and vibrations lead to an enhancement of the sub-barrier fusion cross section in comparison with the predictions of one-dimensional barrier penetration models. This enhancement is explained by coupled-channels calculations including these couplings. The sub-barrier fusion cross section is also affected by nucleon transfer channels between the colliding nuclei. Purpose: The aim of the present experiment is to investigate the influence of the projectile and target nuclear structures on the fusion cross sections in the Ca40+Ni58 and Ca40+Ni64 systems. Methods: The experimental and theoretical fusion excitation functions as well as the barrier distributions were compared for these two systems. Coupled-channels calculations were performed using the ccfull code. Results: Good agreement was found between the measured and calculated fusion cross sections for the Ca40+Ni58 system. The situation is different for the Ca40+Ni64 system where the coupled-channels calculations with no nucleon transfer clearly underestimate the fusion cross sections below the Coulomb barrier. The fusion excitation function was, however, well reproduced at low and high energies by including the coupling to the neutron pair-transfer channel in the calculations. Conclusions: The nuclear structure of the colliding nuclei influences the fusion cross sections below the Coulomb barrier for both Ca40+Ni58,64 systems. Moreover, we highlighted the effect of the neutron pair-transfer channel on the fusion cross sections in Ca40+Ni64.

  5. Production and characterization of a Fe-Ni alloy by aqueous coloidal processing and solid state reaction; Producao e caracterizacao de uma liga Fe-Ni obtida por processamento coloidal aquoso e reacao de estado solido

    Energy Technology Data Exchange (ETDEWEB)

    Vieira Junior, Luiz Eloi; Rodrigues Neto, Joao Batista; Klein, AloIsio Nelmo; Hotza, Dachamir, E-mail: eloi_junior@hotmail.com, E-mail: jbrn.ufsc@gmail.com, E-mail: a.n.klein@ufsc.br, E-mail: d.hotza@ufsc.br [Universidade Federal de Santa Catarina (UFSC), Florianopolis, (Brazil); Moreno, Rodrigo, E-mail: rmoreno@icv.csic.es [Instituto de Ceramica y Vidrio (ICV/CSIC), Madri (Spain)

    2016-10-15

    Colloidal processing is a widely used technique to produce ceramic components. Several papers have been published in the last decade presenting the possibility to obtain aqueous concentrate stable suspension of metallic particles from their pH control and using dispersants. This paper aims to study the production of a steel with austenitic microstructure using elemental iron (Fe) and nickel (Ni) powders via colloidal route. For this, Zeta potential measurements were performed between pH 2 and 12 to Fe30Ni wt% composition. Aqueous suspensions reached solids concentrations of up to 45% v/v and processed by slip casting. The compacts were characterized by density (Archimedes), differential thermal analysis (DTA) and dilatometry. After sintering at 900°C to 1100°C/1h, the sintered bodies presented a microstructure with of annealing twins, porosity less than 10 %v/v approximate Vickers microhardness of 160 HV. (author)

  6. Kinetics of Ni sorption in soils: roles of soil organic matter and Ni precipitation.

    Science.gov (United States)

    Shi, Zhenqing; Peltier, Edward; Sparks, Donald L

    2012-02-21

    The kinetics of Ni sorption to two Delaware agricultural soils were studied to quantitatively assess the relative importance of Ni adsorption on soil organic matter (SOM) and the formation of Ni layered double hydroxide (Ni-LDH) precipitates using both experimental studies and kinetic modeling. Batch sorption kinetic experiments were conducted with both soils at pH 6.0, 7.0, and 7.5 from 24 h up to 1 month. Time-resolved Ni speciation in soils was determined by X-ray absorption spectroscopy (XAS) during the kinetic experiments. A kinetics model was developed to describe Ni kinetic reactions under various reaction conditions and time scales, which integrated Ni adsorption on SOM with Ni-LDH precipitation in soils. The soil Ni speciation (adsorbed phases and Ni-LDH) calculated using the kinetics model was consistent with that obtained through XAS analysis during the sorption processes. Under our experimental conditions, both modeling and XAS results demonstrated that Ni adsorption on SOM was dominant in the short term and the formation of Ni-LDH precipitates accounted for the long-term Ni sequestration in soils, and, more interestingly, that the adsorbed Ni may slowly transfer to Ni-LDH phases with longer reaction times.

  7. Electrocatalytic Behavior of Ni-S-Mn Alloy Electrode for Hydrogen Evolution Reaction%非晶态Ni-S-Mn三元合金电极析氢行为

    Institute of Scientific and Technical Information of China (English)

    单忠强; 刘彦杰; 田建华; 吴锋; 周振芳; 李军

    2006-01-01

    采用电沉积法在镍网上制备了电解水用非晶态Ni-S-Mn合金电极,用电极的阴极极化曲线和电极的析氢反应动力学参数评价了电极的析氢电化学活性. 实验结果表明,该合金电极对氢的析出反应具有较高电催化活性,在200 mA电流时析氢过电位分别比Ni电极和Ni-S电极降低了180和80 mV. 采用小三角波电位扫描、扫描电镜、能谱分析、X射线衍射等测试技术,考察了Ni-S-Mn合金电极表面粗糙度、表面形貌、镀层的组成及电极合金的结构等因素,并对Mn元素的作用进行了解释.

  8. Photocatalytic Property and Reaction Mechanism of (Ni-Mo)/TiO2Nano Thin Film Evaluated with Congo Red%(Ni-Mo)/TiO2纳米薄膜光催化降解刚果红的性能与机理

    Institute of Scientific and Technical Information of China (English)

    李爱昌; 李桂花; 郑琰; 冯玲玲; 郑彦俊

    2012-01-01

    50-100 nm and nanocrystalline grains of Ni-Mo in solid solution. The (Ni-Mo)/TiO2 films are photocatalytically more active than a TiO2/ITO (indium tin oxide) reference film. Under halogen light irradiation, the photocatalytic degradation rate of the (Ni-Mo)/TiO2 films is 2.43 times as much as that of a porous TiO2 (Degussa P25)/ ITO film. The improvement in photocatalytic activity for the composite films could be mainly attributed to the heterojunction of (Ni-Mo)/TiO2, the electronic passageway of Ni-Mo in the composite films, and the catalysis of Ni-Mo in the composite film for the reaction of excited electrons with dissolved oxygen. The photocatalytic reaction mechanisms of the (Ni-Mo)/TiO2 films evaluated with Congo red are given under visible and UV light irradiation, respectively.

  9. First application of core-shell Ag@Ni magnetic nanocatalyst for transfer hydrogenation reactions of aromatic nitro and carbonyl compounds

    Science.gov (United States)

    A magnetic separable core-shell Ag@Ni nanocatalyst was prepared by a simple one-pot synthetic route using oleylamine both as solvent and reducing agent and triphenylphosphine as surfactant. The synthesized nanoparticles were characterized by several techniques such as X-ray diffr...

  10. One-Step Synthesis of Pd-M/ZnO (M=Ag, Cu, and Ni Catalysts by γ-Irradiation and Their Use in Hydrogenation and Suzuki Reaction

    Directory of Open Access Journals (Sweden)

    Mi-Ran Kim

    2009-01-01

    Full Text Available ZnO-supported Pd, Pd-Ag, Pd-Cu, and Pd-Ni catalysts (Pd-M/ZnO were prepared in MeOH/H2O mixture (4/1, v/v-% by γ-irradiation at room temperature. Small mono- and bimetallic nanoparticles were loaded on the surface of ZnO nanopowder as confirmed with TEM, TEM-EDXS, XRD, and ICP-AES data. The catalytic efficiency against Pd-M/ZnO was determined in hydrogenation and Suzuki reaction and compared with the commercial Pd/C catalyst. The Pd-Ag/ZnO showed the highest catalytic efficiency in the Suzuki reaction.

  11. Novel active heterogeneous Fenton system based on Fe3-xMxO4 (Fe, Co, Mn, Ni): the role of M2+ species on the reactivity towards H2O2 reactions.

    Science.gov (United States)

    Costa, Regina C C; Lelis, M F F; Oliveira, L C A; Fabris, J D; Ardisson, J D; Rios, R R V A; Silva, C N; Lago, R M

    2006-02-28

    In this work, the effect of incorporation of M2+ species, i.e. Co2+, Mn2+ and Ni2+, into the magnetite structure to increase the reactivity towards H2O2 reactions was investigated. The following magnetites Fe3-xMnxO4, Fe3-xCoxO4 and Fe3-xNixO4 and the iron oxides Fe3O4, gamma-Fe2O3 and alpha-Fe2O3 were prepared and characterized by Mössbauer spectroscopy, XRD, BET surface area, magnetization and chemical analyses. The obtained results showed that the M2+ species at the octahedral site in the magnetite strongly affects the reactivity towards H2O2, i.e. (i) the peroxide decomposition to O2 and (ii) the oxidation of organic molecules, such as the dye methylene blue and chlorobenzene in aqueous medium. Experiments with maghemite, gamma-Fe2O3 and hematite, alpha-Fe2O3, showed very low activities compared to Fe3O4, suggesting that the presence of Fe2+ in the oxide plays an important role for the activation of H2O2. The presence of Co or Mn in the magnetite structure produced a remarkable increase in the reactivity, whereas Ni inhibited the H2O2 reactions. The obtained results suggest a surface initiated reaction involving Msurf2+ (Fe, Co or Mn), producing HO radicals, which can lead to two competitive reactions, i.e. the decomposition of H2O2 or the oxidation of organics present in the aqueous medium. The unique effect of Co and Mn is discussed in terms of the thermodynamically favorable Cosurf3+ and Mnsurf3+ reduction by Femagnetite2+ regenerating the active species M2+.

  12. Ligand and substrate effects in gas-phase reactions of NiX(+)/RH couples (X=F, Cl, Br, I; R=CH3, C2H5, nC3H7, nC4H9).

    Science.gov (United States)

    Schlangen, Maria; Schröder, Detlef; Schwarz, Helmut

    2007-01-01

    The reactions of small saturated hydrocarbons by gaseous nickel cations NiX+ (X=F, Cl, Br, I) are investigated by means of electrospray ionization mass spectrometry. The halide cations are obtained from solutions of the corresponding Ni(II) salts in water or methanol as solvents. NiF+ is the only Ni(II) halide complex that brings about thermal activation of methane. The branching ratios of the observed reactions with C2H6, C3H8, and nC4H10 are shifted systematically by changing the nature of both the ligand X and the substrate RH. In the elimination of HX (X=F, Cl, Br, I), the formal oxidation state of the metal ion appears to be conserved, and the importance of this reaction channel decreases in going from NiF+ to NiI+. A reversed trend is observed in the losses of small closed-shell neutral molecules, that is, H2, CH4 and C2H6, which dominate the gas-phase ion chemistry of NiI+/RH couples. Additionally, inner-sphere electron-transfer reactions take place for a few systems, that is, the delivery of hydride or methanide ions from the hydrocarbon to NiX+ in the course of which the hydrocarbon is converted to a carbenium ion and the cationic metal complex gives rise to a neutral RNiX molecule (R=H, CH3). This process gains importance with decreasing atomic number of the halides and with increasing the size of the alkane. Thus, it constitutes the major pathway in the reactions of NiF+ with propane and n-butane, whereas it is not observed for any of the NiI+/RH couples investigated. Concerning the regioselectivity of the reactions with propane and n-butane, heterolytic cleavage of secondary carbon--hydrogen bonds is clearly preferred compared to that of primary ones, as revealed by deuterium labeling studies. For the NiF+/C3H8 couple, the selectivity of the hydride transfer is as large as 360 in favor of the secondary positions. Though smaller, large preferences for the activation of secondary C--H bonds are also operative in homolytic bond activation of RH (R=nC3H7, n

  13. Activity and Stability of Ruddlesden-Popper-Type La(n+1) Ni(n) O(3n+1) (n=1, 2, 3, and ∞) Electrocatalysts for Oxygen Reduction and Evolution Reactions in Alkaline Media.

    Science.gov (United States)

    Yu, Jie; Sunarso, Jaka; Zhu, Yinlong; Xu, Xiaomin; Ran, Ran; Zhou, Wei; Shao, Zongping

    2016-02-18

    Increasing energy demands have stimulated intense research activity on cleaner energy conversion such as regenerative fuel cells and reversible metal-air batteries. It is highly challenging but desirable to develop low-cost bifunctional catalysts for both the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER), the lack of which is currently one of the major limiting components towards commercialization of these technologies. Here, we have conducted a systematic study on the OER and ORR performances of the Ruddlesden-Popper family of La(n+1)Ni(n) O(3n+1) (n=1, 2, 3, and ∞) in an alkaline medium for the first time. It is apparent that the Ni-O bond lengths and the hyperstoichiometric oxides in the rock-salt layers correlate with the ORR activities, whereas the OER activities appear to be influenced by the OH(-) content on the surface of the compounds. In our case, the electronic configuration fails to predict the electrocatalytic activity of these compounds. This work provides guidelines to develop new electrocatalysts with improved performances.

  14. Desulfurization reactions on Ni2P(001) and alpha-Mo2C(001) surfaces: complex role of P and C sites.

    Science.gov (United States)

    Liu, Ping; Rodriguez, José A; Asakura, Takeshi; Gomes, João; Nakamura, Kenichi

    2005-03-17

    X-ray photoelectron spectroscopy and first-principles density-functional calculations were used to study the interaction of thiophene, H(2)S, and S(2) with Ni(2)P(001), alpha-Mo(2)C(001), and polycrystalline MoC. In general, the reactivity of the surfaces increases following the sequence MoC P charge transfer) that allows a high activity for the dissociation of thiophene and molecular hydrogen. Second, the number of active Ni sites present in the surface decreases due to an "ensemble effect" of P, which prevents the system from deactivation induced by high coverages of strongly bound S. Third, the P sites are not simple spectators and provide moderate bonding to the products of the decomposition of thiophene and the H adatoms necessary for hydrogenation.

  15. Evaluation of the urea content in the synthesis by combustion reaction of the NiAl{sub 2}O{sub 4} catalysts; Avaliacao do teor de ureia na sintese por reacao de combustao do catalisador NiAl{sub 2}O{sub 4}

    Energy Technology Data Exchange (ETDEWEB)

    Leal, E.; Sousa, J.-P.L.M.L.; Costa, A.C.F.M.; Gama, L. [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Engenharia de Materiais; Argolo, F. [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Inst. de Quimica; Sasaki, J.M. [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Dept. de Fisica

    2009-07-01

    The aim of this work is to evaluate the influence of the urea fuel in the structure and morphology of the NiAl{sub 2}O{sub 4} prepared by combustion reaction. The powders were prepared according to the propellants and explosives theory, using urea in the stoichiometric composition, with 10% of excess and deficiency of this fuel. The samples were characterized by XRD, FTIR, particle size distribution and textural analysis by nitrogen adsorption (BET/BJH). The DRX results showed the presence of NiAl{sub 2}O{sub 4} as major phase and traces of NiO for all the samples. Also show crystallites size between 13 and 21 nm. All the samples showed large agglomerates size distribution, with D{sub 50%} between 18.6 and 20.4 {mu}m, and morphology with irregular plates shape. The increase of the urea content caused an increase in the particle size and a reduction in the surface area, from 270 to 52 m{sup 2}/g. (author)

  16. Electrodeposition of Ni-Mo nanoparticles for the electrocatalytic hydrogen evolution reaction; Electrodepositacion de nanoparticulas de Ni-Mo para la electrocatalisis de la reaccion de evolucion de hidrogeno

    Energy Technology Data Exchange (ETDEWEB)

    Videa, M.; Crespo, D.; Casillas, G.; Zavala, G. [Tecnologico de Monterrey Campus Monterrey, Monterrey, Nuevo Leon (Mexico)]. E-mail: mvidea@eitesm.mx

    2009-09-15

    This work reports on the generation of nickel- molybdenum deposits from the application of direct current in an electrolytic bath composed of a basic solution of NiSO{sub 4}, Na{sub 2}MoO{sub 4} and Na{sub 3}C{sub 6}H5O7. The working electrodes used were 1mm diameter vitreous carbon discs and carbon felt. The catalytic activity of the deposits was evaluated with cyclic voltamperometry in a 0.72M solution of H{sub 2}SO{sub 4}. Deposits were generated on the vitreous carbon discs, which showed catalytic activity for the HER. Deposits were obtained with better properties, showing a pulse of 200 mA/cm{sup 2}. The 42 mA/cm{sup 2} pulse experiments with varying durations showed that their catalytic capacities are better than expected, in spite of the use of small quantities of charge obtained with 90 ms and 300s. Low activity was observed in the absence of MoO{sub 4}{sup 2-} in the electrolytic bath during the electrodeposition process, indicating the importance of the presence of Mo to the catalytic activity. The deposits were inspected using atomic force microscopy (AFM). Though the electrodeposition on carbon felt is possible, the experiments were not reproducible because control over the active area of the electrode is difficult to achieve. NiMo nanoparticles on carbon filter fibers can be obtained using pulses with sufficient intensity and duration. [Spanish] En este trabajo se reporta la generacion de depositos de niquel-molibdeno mediante la aplicacion de corriente directa en un bano electrolitico compuesto por una solucion basica de NiSO{sub 4}, Na{sub 2}MoO{sub 4} y Na{sub 3}C{sub 6}H5O7. Se utilizaron como electrodos de trabajo discos de carbon vitreo de 1mm de diametro y fieltro de carbono. La actividad catalitica de los depositos fue evaluada mediante voltamperometria ciclica en una solucion 0.72M de H{sub 2}SO{sub 4}. Sobre los electrodos de carbon vitreo se generaron depositos que mostraron actividad catalitica para la REH. Depositos con mejores propiedades

  17. Study of the deformation-driving νd5/2 orbital in 6728Ni39 using one-neutron transfer reactions

    Directory of Open Access Journals (Sweden)

    J. Diriken

    2014-09-01

    Full Text Available The νg9/2,d5/2,s1/2 orbitals are assumed to be responsible for the swift onset of collectivity observed in the region below 68Ni. Especially the single-particle energies and strengths of these orbitals are of importance. We studied such properties in the nearby 67Ni nucleus, by performing a (d,p-experiment in inverse kinematics employing a post-accelerated radioactive ion beam (RIB at the REX-ISOLDE facility. The experiment was performed at an energy of 2.95 MeV/u using a combination of the T-REX particle detectors, the Miniball γ-detection array and a newly-developed delayed-correlation technique as to investigate μs-isomers. Angular distributions of the ground state and multiple excited states in 67Ni were obtained and compared with DWBA cross-section calculations, leading to the identification of positive-parity states with substantial νg9/2 (1007 keV and νd5/2 (2207 keV and 3277 keV single-particle strengths up to an excitation energy of 5.8 MeV. 50% of the νd5/2 single-particle strength relative to the νg9/2-orbital is concentrated in and shared between the first two observed 5/2+ levels. A comparison with extended Shell Model calculations and equivalent (3He, d studies in the region around 9040Zr50 highlights similarities for the strength of the negative-parity pf and positive-parity g9/2 state, but differences are observed for the d5/2 single-particle strength.

  18. Acetate self-mixing and direct thermal reaction for preparation of LiNi{sub 0.7}Co{sub 0.3}O{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Sun Woo; Jung, Bum Young; Han, Kyoo Seung [Chungnam National Univ., Taejeon (Korea). Dept. of Fine Chemicals Engineering and Chemistry; Lee, Youngil; Kim, Dongmin [Dongbu Advanced Research Council, Taejeon (Korea); Kim, Min Gyu [Pohang Univ. of Science and Technology (Korea). Accelerator Lab.; Ryu, Kwang Sun [Electronics and telecommunications Research Inst., Yaejeon (Korea); Kang, Eun Young [JESE-Chem Co., Shihung (Korea); Jeong, Jin Heung [Digital-Tech. Co., Seoul (Korea)

    2004-11-30

    Well-crystallized LiNi{sub 0.7}Co{sub 0.3}O{sub 2} was prepared, simply and economically, by the acetate self-mixing method. This method gave spontaneous and homogeneous mixing of molten reactants, as well as steady intermediate phase translation without using any artificial mixing procedures. This led to good battery performance, initial discharge capacity of 172.8 mA h/g and discharge capacity retention of 98.7% over 20 cycles. Spectroscopic evidence for spontaneous and homogeneous mixing is provided.

  19. Numerical study of the mechanism of wavy interface generation in explosive welding; Bakuhatsu yosetsu ni okeru hajo kaimen keisei kiko ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Abe, A. [Kobe University of Mercantile Marine, Kobe (Japan)

    1996-07-21

    Wavy interface generation is an interesting characteristic of explosive welding. There have been many theoretical and experimental discussions of the mechanism of wavy interface generation but there is no consensus of opinion as yet. We report a numerical approach to the analysis of the mechanism of interface wave generation in explosive welding. The phenomena of the interface wave generation are calculated using a two-dimensional finite difference scheme for elastic-plastic materials. In this simulation the equations for a symmetric collision between copper plates are solved. The concept behind this study is that the wavy interface and vortex streets are caused by the velocity distribution of shear flow and periodic disturbances at the interface. The calculation results show the deformation process of the wavy interface and we obtain qualitative agreements between numerical and experimental results. 13 refs., 10 figs., 1 tab.

  20. Experimental studies on performance of tandem hydrofoils in high speed regions; Kosokuiki ni okeru tandem suichuyoku no seino ni kansuru jikkenteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Nakatake, K.; Oda, K.; Kataoka, K. [Kyushu University, Fukuoka (Japan). Faculty of Engineering; Okada, S. [Mitsubishi Heavy Industries, Ltd., Tokyo (Japan); Mizuno, S. [Hitachi Zosen Corp., Osaka (Japan)

    1996-10-01

    With an objective to clarify basic performance of hydrofoils, a towing experiment was carried out on single hydrofoil and tandem hydrofoils, whose results are reported in this paper. In the experiment, the tandem hydrofoils are supported on two stays on the left and right sides, and the whole lifting power and the whole drag including those of the stays were measured by using strain gauges placed on four plate springs. Results of the experiment may be summarized as follows: in the case of the single hydrofoil, the lifting power constant varied as a result of strong impact on free surface as the shallower the hydrofoil, but corresponds to the size of the lifting power coefficient in high speed regions; in the case of the tandem hydrofoils, the smaller the submersion depth, the effects grew larger on the lifting power coefficient and the drag coefficient, similarly to the case of the single hydrofoil; and the lifting power coefficient for the leading hydrofoils changes very little as a result of change in horizontal distance between the tandem hydrofoils, but the lifting power coefficient of the rear hydrofoils vibrates due to influence from the leading hydrofoils, with the peak of the value thereof transferring to the higher speed side as the horizontal distance increases. 3 refs., 10 figs., 2 tabs.

  1. Detection of bit location by acoustic emission technique in horizontal directional drilling. Kojo sakushin koho ni okeru bit ichi no AE ho ni yoru hyotei

    Energy Technology Data Exchange (ETDEWEB)

    Abe, M.; Niitsuma, H. (Tohoku Univ., Sendai (Japan). Faculty of Engineering); Sugimori, S. (Tohoku Univ., Sendai (Japan). Grauduate School); Nakajima, T. (NKK Corp., Tokyo (Japan))

    1991-09-20

    The accuracy of the bit location in the excavation of pilot holes with horizontal drilling technique must be kept less than several tens of centimeters. Such an accuracy is hard to be achieved by the existing controlling technology. The depth of the bit tip can be measured comparatively accurately using a clinometer and the like. The azimuth meter, gyroscope, underground radar, locator, etc. are used for the detection of azimuth of the bit, but every one of them has its own problem. Therefore, new measuring methods to be used in combination with the conventional methods are required which can cover up the shortcomings of the conventional methods. Acoustic emission (AE) technique is employed for the detection of the bit location, and the accompanying problems as well as detecting performance are investigated. It is used for the measurement in the drilling test performed at the reclaimed land on the premises of Keihin ironworks of NKK Corp. In connection with the detection of the bit location in horizontal pilot drilling, a study is made on the zone detection technique for AE signals generated by the bit when striking ground and those generated during drilling. 7 refs., 17 figs., 1 tab.

  2. Effects of heat release rate on NOx time history in diesel combustion; Diesel nensho ni okeru netsu hasseiritsu keika ga NOx nodo rireki ni oyobosu eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Ishiyama, T.; Miwa, K.; Higashida, M. [Tokushima Univ., Tokushima (Japan). Faculty of Engineering; Watanabe, S. [Kawasaki Heavy Industries, Ltd., Kobe (Japan)

    1996-06-25

    For determining the optimum combination of combustion control techniques to reduce NOx emission from diesel engines, it is important to clarify the effects of each technique not only on the NOx emission but also on its time history during combustion. In this paper, NOx concentration in the combustion chamber of a rapid compression machine has been measured by using a total gas sampling method. In order to elucidate the relation between NOx history and heat release rate, air temperatures nozzle hole size and air motion are varied to control the heat release process. The results show that NOx emission is not solely dependent upon initial combustion. Air utilization in the main diffusive combustion phase has great influence on NOx formation and its decay. NOx formation is accelerated by activation of the initial stage of the main combustion when using a nozzle with small holes. 9 refs., 13 figs.

  3. Aiming at information sharing. Standardization trend of data exchange in construction equipment; Joho kyoyuka ni mukete. Kenchiku setsubi ni okeru data kokan no hyojunka doko

    Energy Technology Data Exchange (ETDEWEB)

    Terai, T. [Chiba Inst. of Tech., Narashino (Japan)

    1998-09-05

    In a construction project, various information concerning the whole life cycle of construction production from plan, design to maintenance, preservation, abandonment etc. are involved. In this paper, standardization trend of data exchange in construction equipment and actions aiming at realizing information sharing conducted by each relating groups, are explained. At first, in connection to the needs and seeds of the information sharing, progress of information technology such as computer network and personal computer, and globalism of the information system including transformation of CALDS environment are pointed out. Then, in connection to the conditions and questions for the information sharing, the most suitability of communication, integration of the construction production and standardization of common rules are described. As for the actions conducted by each groups, the actions conducted by ISO, IAI, the Construction and Housing International Organization, the Japan Construction Society and CI-NET conducted by the Construction Promotion Foundation are described. 1 fig.

  4. Pseudo-random data acquisition geometry in 3D seismic survey; Sanjigen jishin tansa ni okeru giji random data shutoku reiauto ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Minegishi, M.; Tsuburaya, Y. [Japan National Oil Corp., Tokyo (Japan). Technology Research Center

    1996-10-01

    Influence of pseudo-random geometry on the imaging for 3D seismic exploration data acquisition has been investigate using a simple model by comparing with the regular geometry. When constituting wave front by the interference of elemental waves, pseudo-random geometry data did not always provide good results. In the case of a point diffractor, the imaging operation, where the constituted wave front was returned to the point diffractor by the interference of elemental waves for the spatial alias records, did not always give clear images. In the case of multi point diffractor, good images were obtained with less noise generation in spite of alias records. There are a lot of diffractors in the actual geological structures, which corresponds to the case of multi point diffractors. Finally, better images could be obtained by inputting records acquired using the pseudo-random geometry rather than by inputting spatial alias records acquired using the regular geometry. 7 refs., 6 figs.

  5. Bacterial cultivation in high magnetic fields by 7-tesla superconducting magnet; 7T chodendo magnet ni yori hasseishita kojiba ni okeru biseibutsu no baiyo

    Energy Technology Data Exchange (ETDEWEB)

    Okuda, M.; Saito, I.; Kamikado, T.; Ito, S. [Kobe Steel, Ltd., Kobe (Japan); Matsumoto, K. [Japan Magnet Technology Inc., Kobe (Japan); Liuno, K.; Tsuchiya, K.; Ano, T.; Shoda, M. [Tokyo Institute of Technology, Tokyo (Japan). Research Laboratory of Resources Utilization

    1994-12-20

    Although a large number of studies on effects of magnetic fields on living organisms was reported, no definite results were obtained in many cases because the related conditions are non-uniform and uncertain, such that the uniform magnetic space is smaller than test samples, and temperature control is insufficient. Therefore, the present study developed a microorganism cultivation system that is applied with a 7-T superconducting magnet. This system has the following features: it generates homogeneous magnetic fields of 0.5 to 7 T {plus_minus} 0.5% in the space with a diameter of 100 mm and a length of 200 mm in a normal temperature bore (with a diameter of 160 mm); it can cultivate microorganisms aerobically at temperatures of 10 to 70{degree}C {plus_minus} 0.1{degree}C; it can perform the cultivation simultaneously with a control cultivation in a small magnetic field weaker than the geomagnetism; and a gradient magnetic field and a variable magnetic field can also be applied. As a result of cultivating colibacillus by using the system, a proliferation effect greater by 40% to 80% than the control was obtained in a uniform magnetic field of 7 T, and a proliferation effect greater by several times in variable magnetic fields of 5.2 to 6.1 T was attained with good reproducibility. 22 refs., 8 figs., 1 tab.

  6. On the muscle activity control in the hierarchy motor systems. Hierarchy undo system ni okeru kin no kassei seigyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Akiba, M.; Miyamoto, Y. (Osaka Industrial University, Osaka (Japan). Faculty of Engineering)

    1991-10-31

    Excitory impulses for motor systems are controlled by the psychophysiological nervous systems in the body either autonomically or voluntarily. Involved in the voluntary control loop are motor cortex, basal gangalia, thalamus, cerebellum, etc. The purpose of this study is to confirm whether it is possible to reduce or emphasize the muscle contraction voluntarily through electromyogram (EMG) feedback training. EMG can indicate the excitory impulses of motor units. In the experiments, electrodes were placed on the skin above muscles. A significant reduction effect was observed for subjects trained in relaxation of the forehead musculature through EMG feedback. Results of the experiments suggested that biofeedback training for relaxation of the forehead tensional muscle might be effective in eliminating muscle contraction, and that feedback training for activation of damaged muscles might be effective in emphasizing muscle contraction. 4 refs., 9 figs.

  7. Pitting corrosion of copper in aqueous solutions containing phosphonic acid as an inhibitor. Hosuhon san wo inhibita toshite fukumu suiyoekichu ni okeru do no koshiku ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Yamada, Y. (Muroran Univ., Hokkaido (Japan). Graduate School); Seri, O.; Tagashira, K. (Muroran Univ., Hokkaido (Japan)); Nagata, K. (Sumitomo Light Metal Co. Ltd., Tokyo (Japan). Technical Research Lab.)

    1993-09-15

    Phosphonic acid-based inhibitors that are poured into cooling water for copper-tube circulation systems for open heat-accumulators were studied on their influence on pitting corrosion of copper. Amino trimethylene phosphonic acid (ATMP) dissolved into distilled water to 50 ppm was used for the immersion corrosion test. The corrosion-proof effect of additives such as ZnSO4, benzotriazole (BTA) was tested too. 0.5 mm thick phosphate-treated copper plates with a hole of 5 mm in diameter were used as test specimens. Pitting corrosion on the copper plate occurred when ATMP, BTA and ZnSO4 coexisted. It was proved that SO4 [sup 2-] is essential since Na2SO4 in stead of ZnSO4 induced also corrosion. The pitting took place when 0.6 ppm or more of SO4 [sup 2-] was present in a BTA-added ATMP solution. It was observed that the pitting is prone to occur with increase of SO4 [sup 2-] and the number of pitting increases. The following relationship is established when pitting corrosion occurs; E[sub b] [le] E[sub corr], where the former is a potential value at which current density shows a steep increase and the latter is an average value of spontaneous electrode potential showing a plateau. 8 refs., 11 figs., 1 tab.

  8. Investigational study on the development, production and wide spread of welfare apparatus in north Europe; Hokuo ni okeru fukushi yogu no kaihatsu seisan fukyu ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    For the purpose of grasping the present situation of the development/production/spread of welfare apparatus in north Europe, an investigation was conducted paying visits to Sweden and Denmark. Basically in the Swedish policy for handicapped persons, disablement is defined not only as features which belong to each individual, but as problems arising when the environment surrounding each individual touches one another. Moreover, characteristics of their policies on welfare apparatus are that major welfare apparatus can be provided for the disabled free of charge, and that the government and public organs play a major role in each step of the development, evaluation, distribution and provision of welfare apparatus. Features of the market of welfare apparatus are that users and buyers of the apparatus are different persons, that a public corporation called SUB participates in determining selling prices, etc., and that the market reflects needs and requests from users comparatively naturally. The needs for welfare apparatus at the Research Institute of Handicapped Persons are grasped through opinion exchanges with groups of handicapped persons or information exchanges with the technical aid center. 3 refs., 11 figs., 10 tabs.

  9. Results of geophysical survey on Hanaore-fault in the Kyoto urban area; Butsuri tansa ni yoru Kyoto shigaichi ni okeru Hanaore danso chosa

    Energy Technology Data Exchange (ETDEWEB)

    Yoshioka, T. [Geological Survey of Japan, Tsukuba (Japan); Echigo, T. [Osaka Soil Test, Osaka (Japan); Toshioka, T.; Matsubara, Y. [Oyo Corp., Tokyo (Japan)

    1997-05-27

    This paper reports results of gravity survey and seismic survey using the shallow bed reflection method to identify distribution of the Hanaore fault in the Kyoto urban area. In the gravity survey, level differential structure caused by the fault was identified as an abrupt change in Bouger anomalous values. The continuity therefrom made the estimation possible on existence and positions of such faults as the Hanaore fault belonging to the Hanaore fault system, the Shishigaya fault, the Kaguraoka fault, and the Okazaki fault. The estimation as a result of the gravity survey include the following findings: the Hanaore fault runs from south of the Yoshidayama in the south-north direction; the distribution of the Okazaki fault has a level differential structure falling on the east side; the structure shows low Bouger anomaly distribution; and this area forms a rift valley belt. In the seismic survey using the shallow bed reflection method, no distinct reflection plane considered as the basement was verified because of influence from urban area noise. However, it was possible to estimate such an underground structure as a monoclinal fold from shapes of the reflection plane and the distribution depths. 7 refs., 5 figs.

  10. Questionnaire investigation for the earthquake in Honjo city and Yazawa city, Akita Prefecture; Jishin ni kansuru ishiki chosa (Akitaken Honjoshi oyobi Yuzawashi ni okeru anketo kara)

    Energy Technology Data Exchange (ETDEWEB)

    Nogoshi, M. [Akita University, Akita (Japan). College of Education; Kabutoya, S.

    1996-05-01

    Consciousness for the earthquake was investigated by questionnaire surveys made in Honjo City and Yuzawa City, Akita Pref. in October 1995 twelve years after the Nihonkai Chubu Earthquake (M=7.7) in May 1983. The survey was conducted in terms of 27 items including personality, memory, knowledge/interest, psychology/action, mental attitude/preparations, wishes for researchers and administration, etc. Also included were the items on the Great Hanshin-Awaji Earthquake and the earthquake blank areas. The number of distributed questionnaires and the recovery rate of them are 1500 and 79.2% in Honjo City, and 1700 and 84.7% in Yuzawa City. From the survey, it was found that people have a lot of knowledge of and high interest in the earthquake and well remember it, and a lot of people know of tsunami, liquefaction phenomena, and the earthquake blank area. Further, they are afraid of earthquakes and think of their actions to be taken in case of earthquake. However, most people are little prepared for earthquakes. Important future subjects were suggested for the study of disaster prevention measures. 13 figs.

  11. Regional unification of energy in North America. ; NAFTA and its related matters. Hokubei ni okeru energy no chiiki togo. ; NAFTA to sono kanren ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    1993-08-01

    The present paper reported energy-related items in the NAFTA. Being discussed among the US, Canada and Mexico, the NAFTA aims at withdrawing the trade barrier, relaxing the investment limitation and protecting the right of intellectual ownership. The foreign enterprises are influenced in both import tax cutdown and original home regulation. Main points which are related to the energy in Mexico are as follows: Mexico reserves the property rights of natural gas and pipelines while the PEMEX maintains the oil export/import and transport rights. In the power generation field, the CFE (Committee for Federal Electricity) owns the power generation and selling rights while the NAFTA approves the foreign investment in the power generation facilities. As per performance contract which forms a special field, incentive is given to the foreign enterprises when succeeding in oil exploration. In the petrochemical field, there exist basic petrochemical products in which the foreign investment is prohibited. A 100% participation of foreign capital is allowed in all other products than the above ones. How the foregoing changes influence the foreign investment is uncertain.

  12. Survey of the trend of technical development and industrial policies in Asian countries; Asia shokoku ni okeru gijutsu kaihatsu no doko to sangyo gijutsu seisaku ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    A sharp rise in industrial productivity in Asia countries indicates a rising level of R and D technology. Since Japan has not clearly grasped the R and D ability in these countries, it has not given appropriate personnel/material R and D support to them. Therefore, for the purpose of exactly grasping the R and D ability of Asian countries (Korea, Taiwan, the Philippines, Indonesia and India) and studying an effective and appropriate method for R and D cooperation, a survey was conducted of R and D potentials in Asia and R and D support policies of the countries. As a result of the survey, the following are taken up as items to be considered: promotion of exchanges between Tsukuba, etc. in Japan and research/university towns and science parks being constructed in lots of countries, participation of private companies in high-tech joint work in cooperation with Japan, sending information from Japan using internet, etc. and exact grasp of needs at partner side, cooperation given to new comers without asking for research results (use of OB researchers, etc.) 25 refs., 39 figs., 59 tabs.

  13. Horizontal wells in the Daleel field 2nd development campaign; Dariru yuden no niji kaihatsu ni okeru suihei koi ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Yanagisawa, K. [Japex Oman Ltd., Tokyo (Japan)

    1995-11-01

    The horizontal wells excavated at various places in the world have been carried out at an increasing tempo during recent some years. In particular, Oman has a number of small scale petroleum wells and a task on what means their oil production should be increased, therefore the horizontal excavation is judged to be much optimum. In this Daleed field 2nd development mainly consisting the prolonged region development ranged from north to south, all developing oil wells were determined to excavate with the horizontal excavation method and 10 wells were planned to excavate from the judgement of the possibility of low cost, in addition to the advance of the horizontal excavation technique. The excavating operation was conducted from July 1st, 1994 to March 22nd, 1995, and was finished without any failures. Test results of all oil wells are good, and the mean value of the initial production indices of the horizontal wells were about 3 times to that of vertical wells. And, it made possible to produce petroleum from the areas impossible in the vertical wells, because of presence of gas gap. Adoption of the horizontal well increased early oil production rate, which brought a lot of contribution to economics of the project. 3 refs., 9 figs., 1 tab.

  14. Study on the swirling flow field in a rotating cylinder. 3rd Report. Experiment; Kaiten kannai ni okeru senkai nagareba ni kansuru kenkyu. 3. Jikken

    Energy Technology Data Exchange (ETDEWEB)

    Kishibe, T. [Hitachi, Ltd., Tokyo (Japan); Kaji, S. [The University of Tokyo, Tokyo (Japan). Faculty of Engineering

    2000-02-25

    In the previous papers, the swirling flow field in a rotating hollow turbine shaft was solved using computational fluid dynamics. It was observed that a large-scale spiral vortex existed at a place where the swirling flow turned radially outward. In this report, the pressure fluctuations in the swirling flow field are measured. The main part of the internal cooling air system of a gas turbine is used as the experimental apparatus. A specially devised liner in inserted inside the hollow turbine shaft and ten pressure sensors are embedded axially and circumferentially in the liner to measure the unsteady wall pressures. The pressure fluctuations which have the same characteristics as the rotating spiral vortex predicted in the numerical results are captured. The amplitude is great at the sensors near the place where the vortex was predicted in the numerical results and the precession frequency of the rotating spiral vortex is in close agreement with the calculated frequency. (author)

  15. Study on the impact assessment for the life cycle assessment (LCA); Kankyo fuka bunseki ni okeru impact assessment ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This report describes the impact assessment which is an important step for LCA. For classification of the impact assessment, the existing literature was reviewed and a skeleton for the classification was proposed. The weighting factors for nine selected impact categories, which were used to calculate environmental load point (ELP) for the valuation, were obtained for two overseas groups, i.e., students of Amsterdam University and SETAC Europe members. It was found that the former provided the similar trends to general Japanese, however that the latter gave high weighting in the global warming and depletion of ozone layer. The ELP was proposed and applied to automatic washing machine, coffee maker, waste incineration power generation system, and co-generation system. As a result, its effectiveness was demonstrated. This report also describes problems for the LCA of thermal and material recycling of PS trays. 99 refs., 96 figs., 73 tabs.

  16. Investigation into the analysis method of total ecobalance in chemical industry products. 3; Kagaku kogyo seihin ni okeru total eko balance no bunseki shuho ni kansuru chosa. 3

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    For the purpose of establishing a total life-cycle ecobalance analysis (LCA) method, the paper studied making of a general computer program for chemical industry products. The study has been made on general-purpose plastics (PET/PSP (polystyrene paper)) since fiscal 1993 aiming at making the CO2 emission computing program covering the entire process of production from extraction of raw materials through waste disposal. In fiscal 1995, the following were conducted for enhancement of generalization of the method: expansion of environmental load items and increase in validity of the concept, and expansion of database. Notice was taken of not only CO2 but SOx, NOx and water quality load items. The survey was made on the recycling situation in Japan and abroad and the PET recycling plant , and environmental load item data are collected to expand database. The program was verified by analyzing an example of reusing PET bottle to carpet, and one-step development can be made toward the establishment of the method. Moreover, an analysis was made for the environmental assessment of the related programs abroad, and a tentative original plan can be proposed for the standardization of environmental load analysis and the integrated assessment method. 39 refs., 130 figs., 76 tabs.

  17. Investigational study of the CO2 balance in high temperature CO2 separation technology; Nisanka tanso koon bunri gijutsu ni okeru CO2 balance ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    An investigational study was conducted to clarify the adaptable environment and effectivity of technologies of high temperature separation/recovery/reutilization of CO2. In the study, data collection, arrangement and comparison were made of various separation technologies such as the membrane method, absorption method, adsorption method, and cryogenic separation method. With the LNG-fired power generation as an example, the adaptable environment and effectivity were made clear by making models by a process simulator, ASPEN PLUS. Moreover, using this simulator, effects of replacing the conventional steam reforming of hydrocarbon with the CO2 reforming were made clear with the methanol synthesis as an example. As to the rock fixation treatment of high temperature CO2, collection/arrangement were made of the data on the fixation treatment of the CO2 separated at high temperature into basic rocks such as peridotite and serpentinite in order to clarify the adaptable environment and effectivity of the treatment. Besides, a potentiality of the fixation to concrete waste was made clear. 57 refs., 57 figs., 93 tabs.

  18. Application of information theory to the sensitivity analysis of cogeneration system performance; Johoryo no gainen ni yoru kojenereshon system ni okeru fuka deta eikyo bunseki

    Energy Technology Data Exchange (ETDEWEB)

    Takahashi, K.; Ishizaka, T.; Honnma, I. [Tokyo Electric Power Co., Inc. (Japan)

    1996-01-05

    Cogeneration system (CGS) is anticipated by department of energy to play an important role in environment preservation. Cogeneration system`s estimation is depended on the preconditions, heat and electricity load data. Since the recognition of heat and electricity load is difficult, efficiency in load data is demanded repeatedly for the evaluation of cogeneration system. Necessary load factors for the estimation of cogeneration system from the energy department`s point of view as well as what measure may become good while recognizing load factors are investigated in this paper. Based on this, a proposal is made by considering load factors of buildings as a standard for estimation of the system. Further fixed quantity assessment is made with the results of computer simulation. From the obtained results, following observations are noted. Recognization of total load capacity is become very important when base load is introduced considerable amount for houses. Load factor`s information is very important for hotel when heat and electricity are used in balance. It is concluded that irrespective of motor capacity, whole day load factor information is necessary for office buildings. 6 refs., 15 figs., 2 tabs.

  19. Improvement of performance of non-equilibrium MHD disk generator by means of segmented loads; Hiheiko disk gata MHD hatsudenki ni okeru bunkatsu fuka ni yoru seino kaizen

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, H.; Okuno, Y.; Kabashima, S. [Tokyo Institute of Technology, Tokyo (Japan)

    1995-08-20

    The performance of non-equilibrium MHD disk generator with segmented loads is examined with {gamma}-{theta} two dimensional numerical simulations. The use of segmented loads is found to improve the generator performance when a low electron temperature plasma is introduced to the channel. The simulation results reveal the desired values of load resistances connected in upstream and downstream regions, respectively. The concept of the segmented loads is considered to be superior to rearranging seed fractions and load resistances. 10 refs., 6 figs., 2 tabs.

  20. Study of installation of PV systems at campus; Campus ni okeru taiyoko hatsuden donyu ni kansuru kenkyu (taiyo denchi nomi wo secchishita baai no yobi kento)

    Energy Technology Data Exchange (ETDEWEB)

    Tsuboi, N.; Tanaka, H.; Okumiya, M. [Nagoya University, Nagoya (Japan)

    1997-11-25

    In terms of energy consumption, environmentality and economical efficiency in the case of installing the photovoltaic power system on the rooftop of the university campus, a comparative study was conducted with other power generation systems. As objects to be comparatively studied, selected were the all-electric type centralized space heating/cooling system, cogeneration system, nighttime heat storage system and centralized system with solar cells installed. The panel area of the PV system is 10,000m{sup 2} on the rooftop and 7,000{sup 2} on the outer wall. About data on solar radiation, average values obtained in Nagoya were used. Assessment was made in terms of energy consumption amount at the time of operation, system COP, emission amounts of CO2, NOx and SOx at the time of manufacturing and operation, initial cost, running cost, etc. As a result of the study, an effect of reducing global warming gas was admitted in the PV system. However, the initial cost of the solar cell panel was high, and the life cycle cost of the PV system was lower than other systems. 1 ref., 7 figs., 3 tabs.

  1. Starting and stopping control on power conditioner in photovoltaic power system; Taiyoko hatsuden system ni okeru power conditioner no kido teishi seigyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Hirose, M.; Ishihara, Y.; Todaka, T.; Harada, K. [Doshisha University, Kyoto (Japan); Oshiro, H.; Nakamura, H. [Japan Quality Assurance Organization, Tokyo (Japan)

    1997-11-25

    Studies are made about the control of the power conditioner over the maximum power point tracking (MPPT) function in a photovoltaic power generation system. The analysis is conducted by means of computer simulation into the effect of a start/stop function added to the control of MPPT and the effect on the generation of power of the setting of parameters in the start/stop function. The reduction in output power due to difference between the actual operation point and the optimum operation point is evaluated by use of a load matching correction factor. In this simulation, it is assumed that the solar cell array consists of 13 rows in 5 parallel columns, is capable of a normal output of 3.149kW, has a panel tilted at 30 degrees, and faces due south. The power conditioner is assumed to be a system rated at 3kVA, equipped with system interconnection and back flow features. As a result, it is learned that the stop voltage should be set at 180V or lower and the steady voltage near 185.5V for a good result and that there is not much need after all for the start/stop technique. 2 refs., 8 figs., 2 tabs.

  2. Necessity of irrigation for revegetation on reclaimed land with fly ash. Sekitanbai umetatechi ni okeru ryokuka no tameno kangai no hitsuyosei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Sekiyama, Tetsuo; Kozakai, Kazuki; Okabe, Katsumi.

    1989-02-01

    In view of the growing importance of revegetation measures of a reclaimed land with fly ash discharged from a coal burning thermal power plant, a study was made on necessity of irrigation in case of the positive execution of the above revegetation. This is a report of the above study. The conclusions of the study are as follows: (1) Comparing the available moisture amounts in terms of volume percentage of moisture, about 36% is for fly ash and about 34% for volcanic ash soil, but when fly ash is solidified, the above figure for fly ash becomes about 90% of that for volcanic ash soil. (2) The maximum water infiltration capacity of fly ash is 1/10-1/50 of that of volcanic ash soil and the surface run-off is much. The furrow or drip irrigation system is suitable. (3) The evaporation in fly ash is almost same as that in volcanic ash soil and the designed duty of water irrigation is considered to be 7-8mm/day (in case of cultivation of tangerine and pasture). (4) In case when the above reclaimed land is covered with volcanic ash soil, an aquifer is observed at the boundary layer between the surface soil coverage and the land. Hence draining measures such as underdrainage systems are desirable from the viewpoint of the growth of plants. 8 refs., 8 figs., 2 tabs.

  3. Fixed position holding control for self-propulsion barges under disturbance condition; Gairanka ni okeru jiko baji no teiten hoji seigyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kijima, K.; Murata, W.; Furukawa, Y. [Kyushu University, Fukuoka (Japan). Faculty of Engineering

    1996-04-10

    In direct hoisting work in suspension bridge construction, since a cable crane directly hoists a bridge beam block put on a barge on the sea, precise fixed position holding function is required for a barge. The control system was then designed on the basis of an ILQ control theory, and the effect of change in time constant as design parameter on fixed position holding performance was studied. In addition, the critical disturbance for fixed position holding control was studied through numerical simulation under various disturbance conditions using the above designed control system. As a result, in the design of control systems on the basis of an ILQ control theory, the precise control system could be designed by diminishing, in particular, the time constant for state variable around a z axis among time constants according to the extent of disturbance. The control performance was largely affected by response delay period from sensing of disturbance to beginning of control. 3 refs., 7 figs., 2 tabs.

  4. Analysis of the pressure response of high angle multiple (HAM) fractures intersecting a welbore; Kokeisha multi fracture (HAM) kosei ni okeru atsuryoku oto kaiseki ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Ujo, S.; Osato, K. [Geothermal Energy Research and Development Co. Ltd., Tokyo (Japan); Arihara, N. [Waseda University, Tokyo (Japan); Schroeder, R.

    1996-05-01

    This paper reports pressure response analysis on wells piercing a high angle multi (HAM) fracture model. In this model which is defined on a three-dimensional space, a plurality of slanted fractures intersect with wells at high angles (however, intersection of fractures with each other is not considered). With respect to the pressure response analysis method using this model, the paper presents a basic differential equation on pressure drawdown and boundary conditions in the wells taking flows in the fractures pseudo-linear, as well as external boundary conditions in calculation regions (a reservoir spreads to an infinite distance, and its top and bottom are closed by non-water permeating beds). The paper also indicates that results of calculating a single vertical fracture model and a slanted fracture model by using a numerical computation program (MULFRAC) based on the above equations agree well respectively with the existing calculation results (calculations performed by Erlougher and Cinco et al). 5 refs., 6 figs.

  5. Study on the effect of measurement points upon reduced added mass matrix; Shukusho fuka shitsuryo matrix ni okeru kansokuten no eikyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Funaki, T.; Hayashi, S. [Osaka University, Osaka (Japan). Faculty of engineering

    1996-12-31

    It is known in estimating vibration characteristics of a ship that fluid range affects largely a structure. A parameter calculation was performed on node vibration in the vertical direction of a rotating elliptic body such as a ship to investigate the effect of an arranging method of the measurement points upon the result of the analysis. As a result, it is thought that equivalent interval arrangement of 21 measurement points would be sufficient in a lower order side mode of vibrations with less than four nodes. An analysis of calculations performed by arranging measurement points in experimental measurement points revealed that analysis accuracy would not increase even if the number of measurement points is increased if it is done so without considering rotation vector. An experiment was carried out with the number of measurement points increased to verify the above fact, with which the analysis was verified correct. Therefore, as has been forecasted in the previous report, the cause for the analysis accuracy deterioration in a high order mode may be estimated as the effect of the rotation vector. However, since it is not the situation that an analysis considering the rotation vector has been conducted, it cannot be concluded yet that the effect of the rotation vector is the sole cause. 4 refs., 14 figs., 7 tabs.

  6. Maneuvering response of slender ship with sinusoidal steering in shallow waters; Sensuiiki ni okeru saichosen no seigen soda ni yoru soju oto

    Energy Technology Data Exchange (ETDEWEB)

    Yasukawa, H. [Mitsubishi Heavy Industries, Ltd., Tokyo (Japan)

    1997-09-04

    In order to grasp memory effect of wake vortices on the maneuvering hydrodynamic characteristics and motions in shallow waters, this paper discusses maneuvering performance of ship advancing with sinusoidal steering. The unsteady slender body theory is used for analyzing the hydrodynamic characteristics acting the hull obliquely advancing or turning around, and hinge-flap model is employed for analyzing the rudder force characteristics. A method has been proposed by which variable components of bearing and transverse displacement of ship advancing with sinusoidal steering in shallow waters can be calculated. Differential coefficient of hull and rudder was calculated by varying the frequency. It was confirmed that the differential coefficient of hull agreed with the test results using cistern. Using this method, maneuvering response using hydrodynamic coefficient in the actual motion frequency was compared with that near the zero frequency. As a result, it was found that memory effect of wake vortices on the maneuvering response of ship can not be ignored in very shallow waters. 12 refs., 7 figs., 2 tabs.

  7. Results of photovoltaic power generation system operation in Tokyo Electric Power Company; Tokyo Denryoku ni okeru taiyoko hatsuden setsubi no unten jisseki ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Fukuda, H.; Itokawa, K. [Tokyo Electric Power Co. Inc., Tokyo (Japan)

    1996-10-27

    A report was made on the measurement of data and the results of the analysis at 14 sites of photovoltaic power generation facilities operated under system interconnection by Tokyo Electric Power Company. This type of system is provided in 40 sites as of the end of fiscal 1995, generating 479kw. The items measured were the generated electric energy at all 14 sites, and the quantity of solar radiation, outside air temperature, panel temperature, etc., at limited sites; and the capacity of each equipment, azimuth and inclination of the panel were also recorded simultaneously. Hourly values were used for the analysis. Five minute values were utilized, however, in the examination of the cause of lowered output and in the situation recognition of the influence of the shade or the change of weather. The utilization factor of the facilities was in the average 10.8% in fiscal 1994 and 10.7% in fiscal 1995. The factor decreased slightly unless the panel azimuth faced due south. The utilization factor at the panel inclination of 35 degrees and 45 degrees showed both 10.4% through the year making no difference. The system seemed to show no overwhelming possibilities in coping with electric power demand. The reason was that deviation existed for 2 hours or so in the peak and that reliability was low as basic power facilities. However, it was determined that the system be continuously examined in future. 9 figs., 1 tab.

  8. 电迁移对Ni/Sn3.0Ag0.5Cu/Cu焊点界面反应的影响%EFFECT OF ELECTROMIGRATION ON INTERFACIAL REACTION IN Ni/Sn3.0Ag0.5Cu/Cu FLIP CHIP SOLDER JOINTS

    Institute of Scientific and Technical Information of China (English)

    黄明亮; 陈雷达; 周少明

    2012-01-01

    The effect of electromigration (EM) on the interfacial reaction in Ni/Sn3.0Ag0.5Cu/Cu solder joints was investigated under a current density of 5.0 ×l03 A/cm2 at 150 ℃ All solder joints were aged at 150 ℃ for comparison purpose. It has been found that the (Cu,Ni)6Sn5 intermetallic compounds (IMCs) form at both soIder/Ni and solder/Cu interfaces in the as-reflowed state. During aging at 150 ℃, the thickness of interfacial IMC increases with increasing aging time, and no interfacial IMC transformation occurs even after aging for 800 h. The flowing direction of electrons plays an important role in Cu consumption. When electrons flow from printed circuit board (PCB) to chip, the current crowding effect induces a rapid and localized dissolution of Cu pad on PCB and a formation of microcrack at the Sn3.0Ag0.5Cu/(Cu, Ni)6Sn5 interface. The dissolved Cu atoms are driven towards anode by EM, and a large amount of Cu6Sn5 IMC particles form in solder matrix along the flowing direction of electrons. When electrons flow from chip to PCB, no obvious consumption of Ni underbump metallogy (UBM) has been observed and few Cu6Sn5 IMC particles form in solder matrix near the anode interface. There is no evidence of failure induced by EM in solder joints even after EM for 800 h. To sum up, EM enhances the growth of interfacial (Cu, Ni)6Sn5 at anode side, no matter how the direction of electrons is. The interfacial IMC at anode side is thicker than that at cathode side. The Ni/Sn3.0Ag0.5Cu/Cu solder joint is prone to fail when electrons flowing from Cu to Ni.%研究了温度为150℃,电流密度为5.0×103 A/cm2的条件下电迁移对Ni/Sn3.0Ag0.5Cu/Cu焊点界面反应的影响.回流焊后在Sn3.0Ag0.5Cu/Ni和Sn3.0Ag0.5Cu/Cu的界面上均形成了(Cu,Ni)6Sn5型化合物.时效过程中界面化合物随时效时间增加而增厚,时效800 h后两端的化合物并没有发生转变,仍为(Cu,Ni)6Sn5型.电流方向对Cu基板的消耗起着决定作用.当电子从基板

  9. Study on Reaction Mechanism of Reducing Dephosphorization of Fe-Ni-Si Melt by CaO-CaF2 Slag

    Science.gov (United States)

    Chen, Pei-Xian; Zhang, Guo-Hua; Chu, Shao-Jun

    2016-02-01

    In the present study, the dephosphorization of Fe-Ni-Si melt by CaO-saturated CaO-CaF2 slag was investigated, from which it was found that the dephosphorization efficiency increases as increasing the silicon content, meanwhile the increase rate becomes rapid when the silicon content is more than 10 mass pct. By analyzing the phase compositions of the dephosphorization slag of a high silicon Fe-Ni-Si melt, it was first found the dephosphorization products change with the silicon content. When Si contents are 10.5, 31.48, 34.71, and 43.15 mass pct, the de-P products are Ca2P2, Ca10+ x Si12-2 x P16, Ca4SiP4, and Ca10+ x Si12-2 x P16, as well as Ca4SiP4, respectively. The corresponding dephosphorization mechanism can be described as (2x)(CaO) + (x + 2y)[Si] + 2z[P] = x(SiO2 ) + 2(Cax Siy Pz ).

  10. Quaternary Pt{sub 2}Ru{sub 1}Fe{sub 1}M{sub 1}/C (M=Ni, Mo, or W) catalysts for methanol electro-oxidation reaction

    Energy Technology Data Exchange (ETDEWEB)

    Jeon, Min Ku; Lee, Ki Rak; Kang, Kweon Ho; Park, Geun Il [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Jeon, Hyung Joon [Kyoto University, Kyoto (Japan); McGinn, Paul J. [University of Notre Dame, Indiana (United States)

    2015-02-15

    Quaternary Pt{sub 2}Ru{sub 1}Fe{sub 1}M{sub 1}/C (M=Ni, Mo, or W) catalysts were investigated for the methanol electro-oxidation reaction (MOR). Electrocatalytic activities of the quaternary catalysts for CO electro-oxidation were studied via CO stripping experiments, and the Pt{sub 2}Ru{sub 1}Fe{sub 1}Ni{sub 1}/C and Pt{sub 2}Ru{sub 1}Fe{sub 1}W{sub 1}/C catalysts exhibited lowered on-set potential compared to that of a commercial PtRu/C catalyst. MOR activities of the quaternary catalysts were determined by linear sweep voltammetry (LSV) experiments, and the Pt{sub 2}Ru{sub 1}Fe{sub 1}W{sub 1}/C catalyst outperformed the commercial PtRu/C catalyst by 170 and 150% for the mass and specific activities, respectively. X-ray photoelectron spectroscopy (XPS) was employed to analyze surface oxidation states of constituent atoms, and it was identified that the structure of the synthesized catalysts are close to a nano-composite of Pt and constituent metal hydroxides and oxides. In addition, the XPS results suggested that the bi-functional mechanism accounts for the improved performance of the Pt{sub 2}Ru{sub 1}Fe{sub 1}Ni{sub 1}/C and Pt{sub 2}Ru{sub 1} Fe{sub 1}W{sub 1}/C catalysts.

  11. Pt, PtCo and PtNi electrocatalysts prepared by mechanical alloying for the oxygen reduction reaction in 0.5 M H{sub 2}SO{sub 4}

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Contreras, M.A. [Instituto Nacional de Investigaciones Nucleares, Depto. de Quimica, Apdo. Postal 18-1027 Col. Escandon, C.P.11801 Mexico D.F. (Mexico); Instituto Politecnico Nacional, Depto. de Ing. Metalurgica, 07300 Mexico D.F. (Mexico); Fernandez-Valverde, S.M. [Instituto Nacional de Investigaciones Nucleares, Depto. de Quimica, Apdo. Postal 18-1027 Col. Escandon, C.P.11801 Mexico D.F. (Mexico); Vargas-Garcia, J.R. [Instituto Politecnico Nacional, Depto. de Ing. Metalurgica, 07300 Mexico D.F. (Mexico); Cortes-Jacome, M.A.; Toledo-Antonio, J.A.; Angeles-Chavez, C. [Instituto Mexicano del Petroleo, Programa de Ingenieria Molecular, Eje Central Lazaro Cardenas 152, Mexico, D.F.,0 7730 (Mexico)

    2008-11-15

    Electrocatalysts of Pt, PtCo and PtNi powders for the oxygen reduction reaction (ORR) were processed by Mechanical Alloying. Physical characterization was made by X-ray diffraction, scanning electron microscopy and scanning transmission electron microscopy. It was found that milled powders formed agglomerates in the range of 0.2-20 {mu}m formed by nanometric size crystallites. The synthesized powders were alloys of PtFe, PtCoFe and PtNiFe due to iron incorporation during the milling process. The binding energies of Pt in the alloys were determined by XPS. Polarization curves were obtained by Rotating Disk Electrode technique in 0.5 M H{sub 2}SO{sub 4} to determine the electrocatalytic activity of the mechanically alloyed powders. Tafel curves were plotted and kinetic parameters for the ORR were calculated. The PtFe alloy showed the highest electrocatalytic activity for the ORR. However, the lowest overpotential was found for the PtCoFe alloy and it also showed a higher current exchange density. A linear relationship was found between the Pt-binding energy in the alloys and the overpotential at the same current density independent of the Pt alloy composition. (author)

  12. Electrochemical Performance of LiNi0.5Mn1.5O4 by Sol-gel Self-combustion Reaction Method in Different Kinds of Electrolyte for High-voltage Rechargeable Lithium Cells

    Science.gov (United States)

    Liang, Xinghua; Shi, Lin; Liu, Yusi; Zeng, Shuaibo; Ye, Chaochao

    2015-07-01

    LiNi0.5Mn1.5O4 cathode material was synthesized through sol-gel self-combustion reaction method. LiNi0.5Mn1.5O4 powders were subsequently characterized as cathode materials in a Li-ion coin cell comprising a Li anode with electrolyte A or electrolyte B. 1.0 mol/L Lithium Hexafluorophosphate (LiPF6) dissolved in volume ration of ethylene carbonate (EC) to ethyl methyl carbonate (EMC) to diethyl carbonate (DEC) corresponded to 4:3:3as electrolyte A, 1.0 mol/L LiPF6 dissolved in volume ration of EC to EMC to DEC corresponded to 4:2:4 as electrolyte B. Electrochemical performance of lithium cells was evaluated. These tests showed that no matter the cells with electrolyte A or electrolyte B has good discharge platform in 4.7V range (3.5V-4.75V) at the rate of 0.1C, the initial discharge capacity of cell with electrolyte B was higher than that with electrolyte A.

  13. Synthesis and catalytic performance of SiO2@Ni and hollow Ni microspheres

    Science.gov (United States)

    Liu, Xin; Liu, Yanhua; Shi, Xueting; Yu, Zhengyang; Feng, Libang

    2016-11-01

    Nickel (Ni) catalyst has been widely used in catalytic reducing reactions such as catalytic hydrogenation of organic compounds and catalytic reduction of organic dyes. However, the catalytic efficiency of pure Ni is low. In order to improve the catalytic performance, Ni nanoparticle-loaded microspheres can be developed. In this study, we have prepared Ni nanoparticle-loaded microspheres (SiO2@Ni) and hollow Ni microspheres using two-step method. SiO2@Ni microspheres with raspberry-like morphology and core-shell structure are synthesized successfully using SiO2 microsphere as a template and Ni2+ ions are adsorbed onto SiO2 surfaces via electrostatic interaction and then reduced and deposited on surfaces of SiO2 microspheres. Next, the SiO2 cores are removed by NaOH etching and the hollow Ni microspheres are prepared. The NaOH etching time does no have much influence on the crystal structure, shape, and surface morphology of SiO2@Ni; however, it can change the phase composition evidently. The hollow Ni microspheres are obtained when the NaOH etching time reaches 10 h and above. The as-synthesized SiO2@Ni microspheres exhibit much higher catalytic performance than the hollow Ni microspheres and pure Ni nanoparticles in the catalytic reduction of methylene blue. Meanwhile, the SiO2@Ni catalyst has high stability and hence it can be recycled for reuse.

  14. Towards Single-component Molecular Conductor [Ni(dmit)2] by Charge Disproportionation:2[Ni(dmit)2]-0.5 →[Ni(dmit)2 ]+ [Ni(dmit)2]-

    Institute of Scientific and Technical Information of China (English)

    Qi FANG; Hong LEI; Wen XU

    2003-01-01

    A new method of synthesizing single-component molecular conductor [Ni(dmit)2] by the reaction 2(Me4N)[Ni(dmit)2]2→[Ni(dmit)2] + (Me4N)[Ni(dmit)2] is reported. [Ni(dmit)2] exhibits a semiconductive behavior above 167 K, while from 167 K down to the measuring limit of 60 K, it exhibits metallic conductivity.

  15. 纳米结晶体Ni0.5Zn0.5Fe2O4对高氯酸铵热行为及分解反应动力学的影响%Effect of Nanocrystal Ni0.5Zn0.5Fe2O4 on Thermal Behavior and Decomposition Reaction Kinetics of Ammonium Perchlorate

    Institute of Scientific and Technical Information of China (English)

    仪建华; 赵凤起; 胡荣祖; Gurdip Singh

    2008-01-01

    采用差示扫描量热法(DSC)、热重和微分热重(TG-DTG)及固相原位反应池/快速扫描傅立叶变换红外联用技术(hyphenated in situ thermolysis/RSFTIR)研究了纳米结晶体Ni0.5Zn0.5Fe2O4与高氯酸铵(AP)组成的混合物的热行为和分解反应动力学.结果表明:Ni0.5Zn0.5Fe2O4使得AP的低、高温分解放热峰温分别提前17.44 K和27.74 K,并使得对应的分解热分别增加3.7 J·g-1和193.7 J·g-1.Ni0.5Zn0.5Fe2O4并不影响AP的晶转温度和晶转热.Ni0.5Zn0.5Fe2O4使得AP的TG曲线出现3个阶段,并使得后2个失重阶段的初始和终止温度都有所提前.凝聚相分解产物分析表明Ni0.5Zn0.5Fe2O4加速了凝聚相AP的分解及氨气的释放.含Ni0.5Zn0.5Fe2O4的AP的高温分解反应的动力学参数Ea=238.88 kJ·mol-1,A=1018.59 s-1,动力学方程可表示为dα/dt=1018.99(1-α)[-ln(1-α)]3/5e-2.87.始点温度(Te)和峰顶温度(Tp)计算得出AP的热爆炸临界温度值分别为:574.83 K和595.41 K.分解反应的活化熵(△S≠)、活化焓(△H≠)和活化能(△G≠)分别为:109.61 J·mol-1·K-1、236.49 kJ·mol-1及172.58 kJ·mol-1.%The thermal behavior and non-isothermal decomposition reaction kinetics of the mixture of the nanocrystal Ni0.5Zn0.5Fe2O4 and ammonium perchlorate (AP) were investigated by differential scanning calorimetry(DSC), thermogravimetry and differential thermogravimetry (TG-DTG), and the hyphenated technique of in situ thermolysis cell with rapid-scan Fourier transform infrared spectroscopy (in situ thermolysis/RSFTIR). The results show that Ni0.5Zn0.5Fe2O4 can decrease the low-temperature and the high-temperature exothermic peak temperatures of AP by 17.44 K and 27.74 K, respectively, and increase the decomposition heats of the two exothermic peaks by of AP. Ni0.5Zn0.5Fe2O4 makes AP shown three mass-loss processes, and it can decrease the initial and terminated temperatures of the last two mass-loss stages. The condensed phase decomposition product

  16. Measurement of the $^{232}$Th (n, $\\gamma$ )/$^{58}$Ni (n, p) reaction rate ratio in the leakage neutron field of CFBR-II fast burst reactor

    CERN Document Server

    Qiang, Wang; Zihui, Ai; Chun, Zheng; Jian, Gong

    2016-01-01

    A ThO$_{2}$ sample with a nickel activation foil attached was irradiated in the leakage neutron field of CFBR-II reactor. The activities of the active products were measured after irradiation to obtain the reaction rates. The normalized reaction rates were also calculated based on the ENDF/B-VII.1, CENDL-3.1, JENDL-4.0, BROND-2.2 databases. The experimental reaction rate ratio is 4.37 with an uncertainty of 3.9\\% which is coincident with the ratios calculated based on the ENDFB-VII. 1, JENDL-4.0, BROND-2.2 databases, but is 11.2\\% larger than that based on CENDL-3.1 database.

  17. Observation of high energy electromagnetic dipole radiation in 14N+Ni reactions at Elab/A = 35 MeV

    Science.gov (United States)

    Alamanos, N.; Braun-Munzinger, P.; Freifelder, R. F.; Paul, P.; Stachel, J.; Awes, T. C.; Ferguson, R. L.; Obenshain, F. E.; Plasil, F.; Young, G. R.

    1986-06-01

    High energy photons (20γ+X reactions were unambiguously observed in a Pb-glass detector array. The measured angular distributions exhibit a predominant dipole pattern. This rules out statistical and/or nucleon-nucleon production mechanisms. The data indicate instead a more coherent production mechanism reflecting the direction of relative motion of target and projectile.

  18. Kinetics of hydrogen evolution reaction on Zr0.5Ti0.5V0.6Cr0.2Ni1.2 alloy in KOH electrolyte

    Indian Academy of Sciences (India)

    Shalini Rodrigues; N Munichandraiah; A K Shukla

    2000-10-01

    A hydrogen-storage alloy of the composition Zr0.5Ti0.5V0.6Cr0.2Ni1.2 has been investigated for corrosion resistance and hydrogen-evolution reaction (HER) in KOH electrolyte of varying concentrations. Activation of the electrode by absorption of hydrogen takes place after prolonged cathodic polarization in the potential range of HER. Prior to activation, the open-circuit potential is about – 0.4 V vs Hg/HgO, OH– , at which the alloy electrode tends to undergo corrosion with oxygen-reduction reaction (ORR) as the conjugate reaction. The corrosion–current density measured from Tafel polarization of ORR is found to be independent of KOH concentration and has an average value of about 30 A cm–2 . Subsequent to activation, the open circuit potential of the electrode is shifted to about – 0.93 V vs Hg/HgO, OH– , which is equal to the reversible potential of HER. The exchange current density values measured from Tafel polarization of HER are marginally higher in relation to the values obtained before the electrode is activated. Alternating-current impedance spectra in the Nyquist form contain two overlapped semicircles. The high-frequency semicircle is attributed to the electrode geometry, while the low-frequency semicircle is due to the charge-transfer reaction and double–layer capacitance. The impedance data are analyzed by a non-linear least square curve fitting technique and impedance parameters are evaluated.

  19. Influence of cobalt and manganese content on the dehydrogenation capacity and kinetics of air-exposed LaNi{sub 5+x}-type alloys in solid gas and electrochemical reactions

    Energy Technology Data Exchange (ETDEWEB)

    Raekelboom, E.; Cuevas, F.; Percheron-Guegan, A. [Laboratoire de Chimie Metallurgique des Terres Rares CNRS, 2-8 rue Henri Dunant, 94320 Thiais (France); Knosp, B. [SAFT, 111 bd. Alfred Daney, 33074 Bordeaux (France)

    2007-07-10

    The effect of cobalt and manganese content on the dehydrogenation properties of air-exposed MmB{sub 5+x}-type (Mm = mischmetal; B = Ni, Al, Co and Mn) alloys was investigated both in solid gas and electrochemical reactions. The cobalt and manganese content were varied separately while keeping constant the plateau pressure of the hydrides. The increase of the cobalt content leads to a decrease of the hydrogen capacity whereas the manganese content has no much effect. In solid gas reactions, the kinetics were found to be limited by the hydrogen diffusion through the surface oxidation layer. As for the electrochemistry, the kinetics are limited by a corrosion layer formed in alkaline medium. The desorption rates for both processes increase as the cobalt or manganese content decreases. This is thought to be due to an enhancement of the hydrogen diffusivity through the oxidation layer. As a result, a low cobalt or manganese content in MmB{sub 5+x} alloys is found to be beneficial for the hydrogen desorption kinetics in both processes. (author)

  20. Chemical reactions during sintering of Fe-Cr-Mn-Si-Ni-Mo-C-steels with special reference to processing in semi-closed containers

    Directory of Open Access Journals (Sweden)

    Cias A.

    2015-01-01

    Full Text Available Sintering of Cr, Mn and Si bearing steels has recently attracted both experimental and theoretical attention and processing in semiclosed containers has been reproposed. This paper brings together relevant thermodynamic data and considers the kinetics of some relevant chemical reactions. These involve iron and carbon, water vapour, carbon monoxide and dioxide, hydrogen and nitrogen of the sintering atmospheres and the alloying elements Cr, Mn, Mo and Si. The paper concludes by presenting mechanical properties data for three steels sintered in local microatmosphere with nitrogen, hydrogen, nitrogen-5% hydrogen and air as the furnace gas.

  1. Study of initial stage in coal liquefaction. Increase in oil yield with suppression of retrogressive reaction during initial stage; Ekika hanno no shoki katei ni kansuru kenkyu. 1.

    Energy Technology Data Exchange (ETDEWEB)

    Uesugi, K.; Kanaji, M.; Kaneko, T.; Shimasaki, K. [Nippon Brown Coal Liquefaction Co. Ltd., Tokyo (Japan)

    1996-10-28

    For the coal liquefaction, improvement of liquefaction conditions and increase of liquefied oil yield are expected by suppressing the recombination through rapid stabilization of pyrolytic radicals which are formed at the initial stage of liquefaction. Two-stage liquefaction combining prethermal treatment and liquefaction was performed under various conditions, to investigate the effects of reaction conditions on the yields and properties of products as well as to increase liquefied oil yield. Consequently, it was found that the catalyst contributes greatly to the hydrogen transfer to coal at the prethermal treatment. High yield of n-hexane soluble fraction with products having low condensation degree could be obtained by combining the prethermal treatment in the presence of hydrogen and catalyst with the concentration of slurry after the treatment. This was considered to be caused by the synergetic effect between the improvement of liquefaction by suppressing polymerization/condensation at the initial stage of reaction through the prethermal treatment and the effective hydrogen transfer accompanied with the improvement of contact efficiency of coal/catalyst by the concentration of slurry at the stage of liquefaction. 4 refs., 8 figs.

  2. Pt, PtCo and PtNi electrocatalysts prepared with mechanical alloying for oxygen reduction reaction in alkaline medium; Electrocatalizadores de Pt, PtCo y PtNi preparados por aleado mecanico para la reaccion de reduccion de oxigeno en medio alcalino

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Contreras, M.A.; Fernandez-Valverde, S.M. [Instituto Nacional de Investigaciones Nucleares, Ocoyoacac, Estado de Mexico (Mexico)]. E-mail: miguel.garcia@inin.gob.mx; Vargas-Garcia, J.R. [ESIQIE-IPN, Mexico D.F. (Mexico

    2009-09-15

    Pt, PtCo and PtNi electrocatalysts were prepared using mechanical alloying and their electrocatalytic activity was investigated for oxygen reduction reaction (ORR) in KOH 0.5 M using cyclic voltametry and rotary disc electrode (RDE) techniques. The electrocatalysts were characterized using x-ray diffraction, sweep electron microscopy, dispersive x-ray transmission and chemical analysis. The physical characterization indicated that all the electrocatalysts are alloys formed by agglomerated particles composed of nanocrystals. The chemical analysis showed the presence of iron in the alloys. For the electrocatalytic evaluation, polarization curves and Koutecky-Levich and Tafel graphs were obtained to determine the kinetic parameters of the electrocatalysts in the study. With the same experimental conditions, the PtCo presented better electrocatalytic performance with a higher exchange current density. [Spanish] Se prepararon electrocatalizadores de Pt, PtCo y PtNi por aleado mecanico y se investigo su actividad electrocatalitica para la reaccion de reduccion de oxigeno (RRO) en KOH 0.5 M utilizando las tecnicas de Voltametria ciclica y Electrodo de Disco Rotatorio. Los electrocatalizadores se caracterizaron por difraccion de rayos X, Microscopia electronica de Barrido, de Transmision y analisis quimico por dispersion de rayos X. La caracterizacion fisica indico que todos los electrocatalizadores son aleaciones formadas de particulas aglomeradas, compuestas de nanocristales. El analisis quimico mostro la presencia de hierro en las aleaciones. Para la evaluacion electrocatalitica se obtuvieron curvas de polarizacion, graficas de Koutecky-Levich y de Tafel para determinar los parametros cineticos de los electrocatalizadores en estudio. En las mismas condiciones experimentales, el PtCo presento el mejor desempeno electrocatalitico con la densidad de corriente de intercambio mas alta.

  3. Mixing behaviors in Cu/Ni and Ni/V multilayers induced by cold rolling

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Z. [Department of Materials Science and Engineering, University of Wisconsin-Madison, 1509 University Avenue, Madison, WI 53706 (United States); Perepezko, J.H., E-mail: perepezk@engr.wisc.edu [Department of Materials Science and Engineering, University of Wisconsin-Madison, 1509 University Avenue, Madison, WI 53706 (United States); Larson, D.; Reinhard, D. [CAMECA Instruments Inc., 5500 Nobel Drive, Madison, WI 53711 (United States)

    2015-09-15

    Highlights: • The composition profiles of Cu/Ni and Ni/V multilayers were investigated. • A compositional oscillation was observed in the Cu/Ni composition profile. • The Ni/V composition profile varies smoothly and continuously between end members. • The effective diffusion coefficients were enhanced by about 30 order of magnitudes. • The effective temperature were estimated as 946 K for Cu/Ni and 936 K for Ni/V. - Abstract: Multilayers of Cu60/Ni40 and Ni70/V30 foil arrays were cold rolled in order to study the transformation reactions and mixing behaviors induced by deformation. Upon cold rolling, the layer thicknesses were refined to about 20 nm and solid solution phases were induced from pure end members (i.e. Cu, Ni and V) in both cases. The composition profiles for Cu/Ni and Ni/V multilayer samples at the deformation level where the solid solution phases coexist with end members were investigated by means of atom probe tomography and electron energy loss spectrum, respectively. An oscillation in the composition of Cu–Ni solid solution phase was observed, however the composition profile of Ni/V shows a smoothly varying curve between the end members. The effective diffusion coefficients were promoted by about 30 orders of magnitude for both Cu/Ni and Ni/V compared to room temperature diffusion. The effective temperature for Cu/Ni multilayers after 36 passes and Ni/V after 60 passes are estimated as 946 K and 936 K respectively.

  4. Ni clay neoformation on montmorillonite surface.

    Science.gov (United States)

    Dähn, R; Scheidegger, A; Manceau, A; Schlegel, M; Baeyens, B; Bradbury, M H

    2001-03-01

    Polarized extended X-ray absorption fine structure spectroscopy (P-EXAFS) was used to study the sorption mechanism of Ni on the aluminous hydrous silicate montmorillonite at high ionic strength (0.3 M NaClO4), pH 8 and a Ni concentration of 0.66 mM. Highly textured self-supporting clay films were obtained by slowly filtrating a clay suspension after a reaction time of 14 days. P-EXAFS results indicate that sorbed Ni has a Ni clay-like structural environment with the same crystallographic orientation as montmorillonite layers.

  5. Crystallographic Orientation Effect on Electromigration in Ni-Sn Microbump

    Science.gov (United States)

    Huang, Yi-Ting; Chen, Chih-Hao; Chakroborty, Subhendu; Wu, Albert T.

    2017-09-01

    This article addresses the reliability challenges regarding electromigration in developing three-dimensional integrated circuits (3D-ICs). The line-type sandwich structure of Ni/Sn3.5Ag(15 μm)/Ni was used to simulate microbumps to examine the reliability of electromigration in 3D-IC technology. The solder strip of Ni/Sn3.5Ag(15 μm)/Ni was stressed with a current density of 1.0 × 104 A/cm2 at 150°C. The current stressing enhanced the reaction between the solder and Ni to form Ni3Sn4, which occupied the entire joint and transformed into a Ni/Ni3Sn4/Ni structure when the solder was completely consumed. Electron backscatter diffraction was used to analyze the crystallographic characteristics of Sn and Ni3Sn4 as related to the electromigration effect. The results indicated that the crystallographic orientation of Sn plays a significant role in the Ni/Sn3.5Ag/Ni, whereas the orientation of Ni3Sn4 is the dominant factor of diffusion behavior in the Ni/Ni3Sn4/Ni.

  6. Crystallographic Orientation Effect on Electromigration in Ni-Sn Microbump

    Science.gov (United States)

    Huang, Yi-Ting; Chen, Chih-Hao; Chakroborty, Subhendu; Wu, Albert T.

    2017-07-01

    This article addresses the reliability challenges regarding electromigration in developing three-dimensional integrated circuits (3D-ICs). The line-type sandwich structure of Ni/Sn3.5Ag(15 μm)/Ni was used to simulate microbumps to examine the reliability of electromigration in 3D-IC technology. The solder strip of Ni/Sn3.5Ag(15 μm)/Ni was stressed with a current density of 1.0 × 104 A/cm2 at 150°C. The current stressing enhanced the reaction between the solder and Ni to form Ni3Sn4, which occupied the entire joint and transformed into a Ni/Ni3Sn4/Ni structure when the solder was completely consumed. Electron backscatter diffraction was used to analyze the crystallographic characteristics of Sn and Ni3Sn4 as related to the electromigration effect. The results indicated that the crystallographic orientation of Sn plays a si