Report from the neutron diffraction work group

International Nuclear Information System (INIS)

1978-08-01

This progress report of the neutron diffraction group at the Hahn Meitner Institute in Berlin comprises the following contributions: Three-dimensional critical properties of CsNiF 3 around the Neel point; Spin waves in CsNiF 3 with an applied magnetic field; Solitons in CsNiF 3 : Their experimental evidence and their thermodynamics; Neutron diffraction study of DAG at very low temperatures and in external magnetic field; Neutron diffraction investigation of tricritical behaviour in DyPO 4 ; Crystalline modifications and structural phase transitions of NaOH; Gitterdynamik von Cerhydrid; Investigation of the ferroelectric-ferroelastic phase transition in KH 2 PO 4 and RbH 2 PO 4 by means of γ-ray diffractometry; A γ-ray diffractometer for systematic measurements of absolute structure factors; Electron density in pyrite by combined γ-ray and neutron diffraction measurements: Thermal parameters from short wavelength neutron data; Accurate determination of temperature parameters from neutron diffraction data: Direct observation of the thermal diffuse scattering from silicon using perfect crystals; A Compton spectrometer for momentum density studies using 412 keV γ-radiation; Investigation of the electronic structure of Niobiumhydrides by means of gamma-ray Compton scattering; Interpretation of Compton profile data in position space; High resolution neutron scattering measurements on single crystals using a horizontally bent monochromator and a multidetecter; Statistical analysis of neutron diffraction studies of proteins. (orig.) [de

Neutron diffraction on pulsed sources

International Nuclear Information System (INIS)

Aksenov, V.L.; Balagurov, A.M.

2016-01-01

The possibilities currently offered and major scientific problems solved by time-of-flight neutron diffraction are reviewed. The reasons for the rapid development of the method over the last two decades has been mainly the emergence of third generation pulsed sources with a MW time-averaged power and advances in neutron-optical devices and detector systems. The paper discusses some historical aspects of time-of-flight neutron diffraction and examines the contribution to this method by F.L.Shapiro whose 100th birth anniversary was celebrated in 2015. The state of the art with respect to neutron sources for studies on output beams is reviewed in a special section. [ru

Dynamical theory of neutron diffraction

International Nuclear Information System (INIS)

Sears, V.F.

1978-01-01

We present a review of the dynamical theory of neutron diffraction by macroscopic bodies which provides the theoretical basis for the study of neutron optics. We consider both the theory of dispersion, in which it is shown that the coherent wave in the medium satisfies a macroscopic one-body Schroedinger equation, and the theory of reflection, refraction, and diffraction in which the above equation is solved for a number of special cases of interest. The theory is illustrated with the help of experimental results obtained over the past 10 years by a number of new techniques such as neutron gravity refractometry. Pendelloesung interference, and neutron interferometry. (author)

Neutron diffraction and lattice defects

International Nuclear Information System (INIS)

Hamaguchi, Yoshikazu

1974-01-01

Study on lattice defects by neutron diffraction technique is described. Wave length of neutron wave is longer than that of X-ray, and absorption cross-section is small. Number of defects observed by ESR is up to several defects, and the number studied with electron microscopes is more than 100. Information obtained by neutron diffraction concerns the number of defects between these two ranges. For practical analysis, several probable models are selected from the data of ESR or electron microscopes, and most probable one is determined by calculation. Then, defect concentration is obtained from scattering cross section. It is possible to measure elastic scattering exclusively by neutron diffraction. Minimum detectable concentration estimated is about 0.5% and 10 20 - 10 21 defects per unit volume. A chopper and a time of flight system are used as a measuring system. Cold neutrons are obtained from the neutron sources inserted into reactors. Examples of measurements by using similar equipments to PTNS-I system of Japan Atomic Energy Research Institute are presented. Interstitial concentration in the graphite irradiated by fast neutrons is shown. Defects in irradiated MgO were also investigated by measuring scattering cross section. Study of defects in Ge was made by measuring total cross section, and model analysis was performed in comparison with various models. (Kato, T.)

Future directions in high-pressure neutron diffraction

Science.gov (United States)

Guthrie, M.

2015-04-01

The ability to manipulate structure and properties using pressure has been well known for many centuries. Diffraction provides the unique ability to observe these structural changes in fine detail on lengthscales spanning atomic to nanometre dimensions. Amongst the broad suite of diffraction tools available today, neutrons provide unique capabilities of fundamental importance. However, to date, the growth of neutron diffraction under extremes of pressure has been limited by the weakness of available sources. In recent years, substantial government investments have led to the construction of a new generation of neutron sources while existing facilities have been revitalized by upgrades. The timely convergence of these bright facilities with new pressure-cell technologies suggests that the field of high-pressure (HP) neutron science is on the cusp of substantial growth. Here, the history of HP neutron research is examined with the hope of gleaning an accurate prediction of where some of these revolutionary capabilities will lead in the near future. In particular, a dramatic expansion of current pressure-temperature range is likely, with corresponding increased scope for extreme-conditions science with neutron diffraction. This increase in coverage will be matched with improvements in data quality. Furthermore, we can also expect broad new capabilities beyond diffraction, including in neutron imaging, small angle scattering and inelastic spectroscopy.

Time-resolved Neutron Powder Diffraction

International Nuclear Information System (INIS)

Pannetier, J.

1986-01-01

The use of a high-flux neutron source together with a large position sensitive detector (PSD) allows a powder diffraction pattern to be recorded at a time-scale of a few minutes so that crystalline systems under non-equilibrium conditions may now conveniently be investigated. This introduces a new dimension into powder diffraction (the time and transient phenomena like heterogeneous chemical reactions can now be easily studied. The instrumental parameters relevant for the design of such time-dependent experiments are briefly surveyed and the current limits of the method are discussed. The applications are illustrated by two kinds of experiment in the field of inorganic solid state chemistry: true kinetic studies of heterogeneous chemical reactions and thermodiffractometry experiments

Extinction correction in white X-ray and neutron diffraction

International Nuclear Information System (INIS)

Tomiyoshi, S.; Yamada, M.; Watanabe, H.

1980-01-01

Extinction effects in white-beam X-ray and neutron diffraction are considered. In white-beam diffraction, a small deviation of the wavelength from the Bragg condition Δlambda is a variable which represents the line profile of the diffraction peaks, so that by using the new parameter Δlambda the theory is converted to one in white-beam diffraction. It is shown that for a convex crystal, primary extinction agrees with the results calculated already for monochromatic diffraction. The same relation is shown to hold in secondary extinction. It is concluded that extinction theory derived for monochromatic diffraction is applicable without any modification in white-beam diffraction. (Auth.)

DNA hydration studied by neutron fiber diffraction

Energy Technology Data Exchange (ETDEWEB)

Fuller, W.; Forsyth, V.T.; Mahendrasingam, A.; Langan, P.; Pigram, W.J. [Keele Univ. (United Kingdom)] [and others

1994-12-31

The development of neutron high angle fiber diffraction to investigate the location of water around the deoxyribonucleic acid (DNA) double-helix is described. The power of the technique is illustrated by its application to the D and A conformations of DNA using the single crystal diffractometer, D19, at the Institute Laue-Langevin, Grenoble and the time of flight diffractometer, SXD, at the Rutherford Appleton ISIS Spallation Neutron Source. These studies show the existence of bound water closely associated with the DNA. The patterns of hydration in these two DNA conformations are quite distinct and are compared to those observed in X-ray single crystal studies of two-stranded oligodeoxynucleotides. Information on the location of water around the DNA double-helix from the neutron fiber diffraction studies is combined with that on the location of alkali metal cations from complementary X-ray high angle fiber diffraction studies at the Daresbury Laboratory SRS using synchrotron radiation. These analyses emphasize the importance of viewing DNA, water and ions as a single system with specific interactions between the three components and provide a basis for understanding the effect of changes in the concentration of water and ions in inducing conformations] transitions in the DNA double-helix.

DNA hydration studied by neutron fiber diffraction

International Nuclear Information System (INIS)

Fuller, W.; Forsyth, V.T.; Mahendrasingam, A.; Langan, P.; Pigram, W.J.

1994-01-01

The development of neutron high angle fiber diffraction to investigate the location of water around the deoxyribonucleic acid (DNA) double-helix is described. The power of the technique is illustrated by its application to the D and A conformations of DNA using the single crystal diffractometer, D19, at the Institute Laue-Langevin, Grenoble and the time of flight diffractometer, SXD, at the Rutherford Appleton ISIS Spallation Neutron Source. These studies show the existence of bound water closely associated with the DNA. The patterns of hydration in these two DNA conformations are quite distinct and are compared to those observed in X-ray single crystal studies of two-stranded oligodeoxynucleotides. Information on the location of water around the DNA double-helix from the neutron fiber diffraction studies is combined with that on the location of alkali metal cations from complementary X-ray high angle fiber diffraction studies at the Daresbury Laboratory SRS using synchrotron radiation. These analyses emphasize the importance of viewing DNA, water and ions as a single system with specific interactions between the three components and provide a basis for understanding the effect of changes in the concentration of water and ions in inducing conformations] transitions in the DNA double-helix

Polarized neutron diffraction - a tool for testing extinction models: application to yttrium iron garnet

International Nuclear Information System (INIS)

Bonnet, M.; Delapalme, A.; Becker, P.

1976-01-01

This paper shows that polarized neutron experiments, which do not depend on any scale factor, are very dependent on extinction and provide original tests for extinction models. Moon, Koehler, Cable and Child (1972) have formulated the problem and proposed a first-order solution applicable only when the extinction is small. In the first part, some analytical derivations of secondary extinction corrections are discussed, using the formalism of Becker and Coppens (1974). In the second part, the main principles governing polarized neutron diffraction are briefly reviewed, with a special discussion of extinction problems. The method is then applied to the case of yttrium iron garnet (YIG). This experiment shows the technique of polarized neutrons to be very powerful for testing extinction models and for deciding whether the crystal behaves dynamically or kinematically (following Kato's criterion). (Auth.)

The early development of neutron diffraction: science in the wings of the Manhattan Project

Energy Technology Data Exchange (ETDEWEB)

Mason, T. E., E-mail: masont@ornl.gov; Gawne, T. J.; Nagler, S. E.; Nestor, M. B. [Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Carpenter, J. M. [Argonne National Laboratory, Argonne, IL 60439 (United States); Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States)

2013-01-01

Early neutron diffraction experiments performed in 1944 using the first nuclear reactors are described. Although neutron diffraction was first observed using radioactive decay sources shortly after the discovery of the neutron, it was only with the availability of higher intensity neutron beams from the first nuclear reactors, constructed as part of the Manhattan Project, that systematic investigation of Bragg scattering became possible. Remarkably, at a time when the war effort was singularly focused on the development of the atomic bomb, groups working at Oak Ridge and Chicago carried out key measurements and recognized the future utility of neutron diffraction quite independent of its contributions to the measurement of nuclear cross sections. Ernest O. Wollan, Lyle B. Borst and Walter H. Zinn were all able to observe neutron diffraction in 1944 using the X-10 graphite reactor and the CP-3 heavy water reactor. Subsequent work by Wollan and Clifford G. Shull, who joined Wollan’s group at Oak Ridge in 1946, laid the foundations for widespread application of neutron diffraction as an important research tool.

The early development of neutron diffraction: science in the wings of the Manhattan Project

International Nuclear Information System (INIS)

Mason, T. E.; Gawne, T. J.; Nagler, S. E.; Nestor, M. B.; Carpenter, J. M.

2013-01-01

Early neutron diffraction experiments performed in 1944 using the first nuclear reactors are described. Although neutron diffraction was first observed using radioactive decay sources shortly after the discovery of the neutron, it was only with the availability of higher intensity neutron beams from the first nuclear reactors, constructed as part of the Manhattan Project, that systematic investigation of Bragg scattering became possible. Remarkably, at a time when the war effort was singularly focused on the development of the atomic bomb, groups working at Oak Ridge and Chicago carried out key measurements and recognized the future utility of neutron diffraction quite independent of its contributions to the measurement of nuclear cross sections. Ernest O. Wollan, Lyle B. Borst and Walter H. Zinn were all able to observe neutron diffraction in 1944 using the X-10 graphite reactor and the CP-3 heavy water reactor. Subsequent work by Wollan and Clifford G. Shull, who joined Wollan’s group at Oak Ridge in 1946, laid the foundations for widespread application of neutron diffraction as an important research tool

Quantitative multiphase analysis of archaeological bronzes by neutron diffraction

CERN Document Server

Siano, S; Celli, M; Pini, R; Salimbeni, R; Zoppi, M; Kockelmann, W A; Iozzo, M; Miccio, M; Moze, O

2002-01-01

In this paper, we report the first investigation on the potentials of neutron diffraction to characterize archaeological bronze artifacts. The preliminary feasibility of phase and structural analysis was demonstrated on standardised specimens with a typical bronze alloy composition. These were realised through different hardening and annealing cycles, simulating possible ancient working techniques. The Bragg peak widths that resulted were strictly dependent on the working treatment, thus providing an important analytical element to investigate ancient making techniques. The diagnostic criteria developed on the standardised specimens were then applied to study two Etruscan museum pieces. Quantitative multiphase analysis by Rietveld refinement of the diffraction patterns was successfully demonstrated. Furthermore, the analysis of patterns associated with different artifact elements also yielded evidence for some peculiar perspective of the neutron diffraction diagnostics in archeometric applications. (orig.)

Fundamentals and applications of neutron diffraction. Applications 7. Crystal structure analysis of fuel cell materials by means of neutron diffractometry

International Nuclear Information System (INIS)

Itoh, Takanori

2010-01-01

Perovskite oxides, which have 'A' atoms of an alkaline earth metal and/or a rare earth metal and 'B' atoms of a transition metal, have considerable potential for use in electrochemical devices such as cathodes of solid oxide fuel cells (SOFC), oxygen pumps, oxygen sensors, catalysts, and other devices such as oxygen separation membranes. The oxygen ion behavior is studied with relation performance of electrochemical devices. I have analyzed the crystal structure of SOFC materials by neutron diffraction. Using the Rietveld refinement technique, I showed that the O1(4c) and O2(8d) sites in a perovskite oxide of SOFC cathode material has different oxygen site occupancies. Furthermore, oxygen diffusion behavior is associated with temperature dependence of oxygen anisotropic atomic displacement parameters. The maximum entropy method (MEM) analysis of neutron diffraction measurements revealed nuclear scattering length distribution at high temperature by three-dimensional images in detail, therefore 1 found oxygen diffusion pass and new proton site in SOFC materials. From these results, neutron diffraction is confirmed to be very useful tool for the study of light element behavior in fuel cell materials. (author)

The early development of neutron diffraction: science in the wings of the Manhattan Project.

Science.gov (United States)

Mason, T E; Gawne, T J; Nagler, S E; Nestor, M B; Carpenter, J M

2013-01-01

Although neutron diffraction was first observed using radioactive decay sources shortly after the discovery of the neutron, it was only with the availability of higher intensity neutron beams from the first nuclear reactors, constructed as part of the Manhattan Project, that systematic investigation of Bragg scattering became possible. Remarkably, at a time when the war effort was singularly focused on the development of the atomic bomb, groups working at Oak Ridge and Chicago carried out key measurements and recognized the future utility of neutron diffraction quite independent of its contributions to the measurement of nuclear cross sections. Ernest O. Wollan, Lyle B. Borst and Walter H. Zinn were all able to observe neutron diffraction in 1944 using the X-10 graphite reactor and the CP-3 heavy water reactor. Subsequent work by Wollan and Clifford G. Shull, who joined Wollan's group at Oak Ridge in 1946, laid the foundations for widespread application of neutron diffraction as an important research tool.

Application of 2-dimensional coordinate system conversion in stress measurements with neutron diffraction

International Nuclear Information System (INIS)

Wang, D.-Q.; Hubbard, C.R.; Spooner, S.

2000-01-01

This paper will present a method and program to precisely calculate the coordinates in a positioner coordinate system from given sample position coordinates with a minimum number of neutron surface scans for three possible circumstances in stress and texture measurement using neutron diffraction

ALADIN - Advanced Laue Diffraction Instruments using Neutrons

International Nuclear Information System (INIS)

Lemee-Cailleau, M.H.; Ouladdiaf, B.; McIntyre, G.J.

2011-01-01

Laue diffraction techniques have proven to be very attractive to a broad user community interested in obtaining detailed structural information on very small single-crystal samples or needing data collection speeds comparable to those available with the powder diffraction technique. However our experience has clearly demonstrated the negative effect of up-stream monochromatic instruments on the quality of Laue data. In order to obtain Laue diffraction data with a statistical accuracy similar to that achieved on a monochromatic instrument (neutron or X-rays), the project ALADIN (for Advanced Laue Diffraction Instruments using Neutrons) aims to: -) construct a Laue-dedicated thermal neutron guide, with m=2 super-mirror coating, providing access to the desirable wavelength bandwidth; -) installation of one of the ILL Laue diffractometers (VIVALDI or CYCLOPS) on this new guide. (authors)

Solving crystal structures from neutron diffraction data

International Nuclear Information System (INIS)

Wilson, C.C.

1987-07-01

In order to pursue crystal structure determination using neutron diffraction data, and given the wide experience available of solving structures using X-ray data, the codes used in X-ray structural analysis should be adapted to the different requirements of a neutron experiment. Modifications have been made to a direct methods program MITHRIL and to a Patterson methods program PATMET to incorporate into these the features of neutron rather than X-ray diffraction. While to date these modifications have been fairly straightforward and many sophistications remain to be exploited, results obtained from the neutron versions of both programs are promising. (author)

Neutron diffraction stress determination in W-laminates for structural divertor applications

Directory of Open Access Journals (Sweden)

R. Coppola

2015-07-01

Full Text Available Neutron diffraction measurements have been carried out to develop a non-destructive experimental tool for characterizing the crystallographic structure and the internal stress field in W foil laminates for structural divertor applications in future fusion reactors. The model sample selected for this study had been prepared by brazing, at 1085 °C, 13 W foils with 12 Cu foils. A complete strain distribution measurement through the brazed multilayered specimen and determination of the corresponding stresses has been obtained, assuming zero stress in the through-thickness direction. The average stress determined from the technique across the specimen (over both ‘phases’ of W and Cu is close to zero at −17 ± 32 MPa, in accordance with the expectations.

Modern techniques of structural neutron diffraction

International Nuclear Information System (INIS)

Aksenov, V.L.; )

1997-01-01

Modern techniques of neutron diffraction for structural investigations are analyzed. The time-of-flight method and the reverse time-of-flight method are considered briefly. Characteristics of two-crystal and time-of-flight neutron diffractometers are compared. It is pointed that in the future, the great importance will be possessed the development of high-resolution Fourier neutron diffractometers [ru

Automatic control unit for A neutron diffraction crystal spectrometer

Energy Technology Data Exchange (ETDEWEB)

Adib, M.; Abbas, Y.; Mostafa, M.; Hamouda, I.

1982-01-01

An automatic transistorized unit has been designed and constructed to control the operation of the double axis crystal spectrometer installed in front of one of the horizontal channels of the ET-RR-1 reactor. The function of the automatic unit is to store the diffracted neutrons at a certain angle with respect to the direction of the incident neutron beam in a selected channel of a 1024-multichannel analyzer for a certain preadjusted time period. AT the end of this time period the unit rotates the spectrometer's arm to another angle, selects the next channel of the MCA and provides the measurement of the diffracted neutron for the same time period. Such a sequence is repeated automatically over all angles required for the neutron diffraction pattern of the sample under investigation. As a result, the stored information at the MCA provides the neutron diffraction pattern as a function of channel number, where each channel corresponds to a certain scattering angle. The stored distribution at MCA can be obtained through the analyzer read out unit. The designed automatic unit has the possibility of providing the neutron diffraction pattern using a 6-digit scaler and a printer.

Experimental technique of stress analyses by neutron diffraction

International Nuclear Information System (INIS)

Sun, Guangai; Chen, Bo; Huang, Chaoqiang

2009-09-01

The structures and main components of neutron diffraction stress analyses spectrometer, SALSA, as well as functions and parameters of each components are presented. The technical characteristic and structure parameters of SALSA are described. Based on these aspects, the choice of gauge volume, method of positioning sample, determination of diffraction plane and measurement of zero stress do are discussed. Combined with the practical experiments, the basic experimental measurement and the related settings are introduced, including the adjustments of components, pattern scattering, data recording and checking etc. The above can be an instruction for stress analyses experiments by neutron diffraction and neutron stress spectrometer construction. (authors)

Engineering related neutron diffraction measurements probing strains, texture and microstructure

Energy Technology Data Exchange (ETDEWEB)

Clausen, Bjorn [Los Alamos National Laboratory; Brown, Donald W [Los Alamos National Laboratory; Tome, Carlos N [Los Alamos National Laboratory; Balogh, Levente [Los Alamos National Laboratory; Vogel, Sven C [Los Alamos National Laboratory

2010-01-01

Neutron diffraction has been used for engineering applications for nearly three decades. The basis of the technique is powder diffraction following Bragg's Law. From the measured diffraction patterns information about internal, or residual, strain can be deduced from the peak positions, texture information can be extracted from the peak intensities, and finally the peak widths can provide information about the microstructure, e.g. dislocation densities and grain sizes. The strains are measured directly from changes in lattice parameters, however, in many cases it is non-trivial to determine macroscopic values of stress or strain from the measured data. The effects of intergranular strains must be considered, and combining the neutron diffraction measurements with polycrystal deformation modeling has proven invaluable in determining the overall stress and strain values of interest in designing and dimensioning engineering components. Furthelmore, the combined use of measurements and modeling has provided a tool for elucidating basic material properties, such as critical resolved shear stresses for the active deformation modes and their evolution as a function of applied deformation.

High temperature neutron diffraction study of LaPO4

International Nuclear Information System (INIS)

Mishra, S.K.; Mittal, R.; Ningthoujam, R.S.; Vatsa, R.K.; Hansen, T.

2016-01-01

We report high temperature powder neutron diffractions study in LaPO 4 using high-flux D20 neutron diffractometer in the Institut Laue-Langevin, France. The measurements were carried out in high resolution mode (incident neutron wavelength 1.36 A) at various temperature upto 900°C. CarefuI inspection of temperature dependence of diffraction data showed appearance and disappearance of certain Bragg's reflections above 1273 K. It is a signature of structural phase transition. Rietveld refinement of the powder diffraction data revealed that diffraction patterns at and above 800°C could be indexed using the monoclinic structure with P21/n space group. Detail analysis for identify the water molecules is under investigation. (author)

The internal stress measurement the neutron diffraction bring happiness to your country

Energy Technology Data Exchange (ETDEWEB)

Minakawa, Nobuaki [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

2003-03-01

The neutron was discovered by Chadwick in 1932. The first reactor was constructed by the USA in 1942. After that, the research and development of reactors advanced. Numbers of reactors were constructed in Europe and in the US. The researches, which use the neutron, were performed actively and excellent results were obtained in wide fields. The penetrating power of the neutron and the neutron diffraction method began to attract attention for the application to the internal stress measurement, too. In Japan, the neutron diffractometer for the residual stress measurement exclusive was installed in the JRR-3M research reactor of JAERI in 1992, and the research was started. At present, we are using it for the stress measurements of the parts of aircrafts, railways, automobiles, buildings, machines, home electronics products and so on including nuclear reactors. Reliable science must be introduced in order to support safety and long life operation and to supply them at reasonable cost. Among the various scientific probes to find faults in materials, diffraction technique is used to measure the strain distribution in materials by observing the local changes of the distance between crystallographic planes and the stress distribution is computed to improve manufacturing processes. It is only neutron diffraction that can be used to measure the strain inside the materials. Here, I present an overview of the utilization of neutron scattering research for the industrial uses and the history of the neutron scattering research in JAERI briefly. (J.P.N.)

Final Technical Report: Application of in situ Neutron Diffraction to Understand the Mechanism of Phase Transitions

Energy Technology Data Exchange (ETDEWEB)

Chandran, Ravi [Univ. of Utah, Salt Lake City, UT (United States). Dept. of Metallurgical Engineering

2018-02-09

In this research, phase transitions in the bulk electrodes for Li-ion batteries were investigated using neutron diffraction (ND) as well as neutron imaging techniques. The objectives of this research is to design of a novel in situ electrochemical cell to obtain Rietveld refinable neutron diffraction experiments using small volume electrodes of various laboratory/research-scale electrodes intended for Li-ion batteries. This cell is also to be used to investigate the complexity of phase transitions in Li(Mg) alloy electrodes, either by diffraction or by neutron imaging, which occur under electrochemical lithiation and delithiation, and to determine aspects of phase transition that enable/limit energy storage capacity. Additional objective is to investigate the phase transitions in electrodes made of etched micro-columns of silicon and investigate the effect of particle/column size on phase transitions and nonequilibrium structures. An in situ electrochemical cell was designed successfully and was used to study the phase transitions under in-situ neutron diffraction in both the electrodes (anode/cathode) simultaneously in graphite/LiCoO₂ and in graphite/LiMn₂O₄ cells each with two cells. The diffraction patterns fully validated the working of the in situ cell. Additional experimental were performed using the Si micro-columnar electrodes. The results revealed new lithiation phenomena, as evidenced by mosaicity formation in silicon electrode. These experiments were performed in Vulcan diffractometer at SNS, Oak Ridge National Laboratory. In parallel, the spatial distribution of Li during lithiation and delithiation processes in Li-battery electrodes were investigated. For this purpose, neutron tomographic imaging technique has been used for 3D mapping of Li distribution in bulk Li(Mg) alloy electrodes. It was possible to observe the phase boundary of Li(Mg) alloy indicating phase transition from Li-rich BCC β-phase to Li-lean �

Thermal diffuse scattering in angular-dispersive neutron diffraction

International Nuclear Information System (INIS)

Popa, N.C.; Willis, B.T.M.

1998-01-01

The theoretical treatment of one-phonon thermal diffuse scattering (TDS) in single-crystal neutron diffraction at fixed incident wavelength is reanalysed in the light of the analysis given by Popa and Willis [Acta Cryst. (1994), (1997)] for the time-of-flight method. Isotropic propagation of sound with different velocities for the longitudinal and transverse modes is assumed. As in time-of-flight diffraction, there exists, for certain scanning variables, a forbidden range in the one-phonon TDS of slower-than-sound neutrons, and this permits the determination of the sound velocity in the crystal. A fast algorithm is given for the TDS correction of neutron diffraction data collected at a fixed wavelength: this algorithm is similar to that reported earlier for the time-of-flight case. (orig.)

An automatic control unit for A neutron diffraction crystal spectrometer

International Nuclear Information System (INIS)

Adib, M.; Abbas, Y.; Mostafa, M.; Hamouda, I.

1982-01-01

An automatic transistorized unit has been designed and constructed to control the operation of the double axis crystal spectrometer installed in front of one of the horizontal channels of the ET-RR-1 reactor. The function of the automatic unit is to store the diffracted neutrons at a certain angle with respect to the direction of the incident neutron beam in a selected channel of a 1024-multichannel analyzer for a certain preadjusted time period. AT the end of this time period the unit rotates the spectrometer's arm to another angle, selects the next channel of the MCA and provides the measurement of the diffracted neutron for the same time period. Such a sequence is repeated automatically over all angles required for the neutron diffraction pattern of the sample under investigation. As a result, the stored information at the MCA provides the neutron diffraction pattern as a function of channel number, where each channel corresponds to a certain scattering angle. The stored distribution at MCA can be obtained through the analyzer read out unit. The designed automatic unit has the possibility of providing the neutron diffraction pattern using a 6-digit scaler and a printer

Single-crystal neutron diffraction studies of hydrogen-bonded systems: Two recent examples from IPNS

Energy Technology Data Exchange (ETDEWEB)

Koetzle, Thomas F. [IPNS Division, Argonne National Laboratory, Argonne, IL 60439 (United States)], E-mail: tkoetzle@anl.gov; Piccoli, Paula M.B.; Schultz, Arthur J. [IPNS Division, Argonne National Laboratory, Argonne, IL 60439 (United States)

2009-02-21

Beginning with work in the 1950s at the first generation of research reactors, studies of hydrogen-bonded systems have been a prime application for single-crystal neutron diffraction. The range of systems studied was extended in the 1960s and 1970s, with the advent of high flux reactor sources, and beginning around 1980 studies at pulsed neutron sources have made increasingly important contributions. Recently at the Argonne Intense Pulsed Neutron Source (IPNS), working with collaborators, we completed two studies of hydrogen-bonded systems that will serve to illustrate topics of current interest. In the first study, on andrographolide, an active diterpenoid natural product, our neutron diffraction results definitively characterize the hydrogen-bonding interactions. The second IPNS study is on tetraacetylethane (TAE), a {beta}-diketone enol system with a very short, strong intramolecular O-H...O hydrogen bond. At IPNS, we have determined the neutron crystal structure of TAE at five temperatures between 20 and 298 K to investigate changes in the structure with temperature and to probe for disorder. Despite the successes illustrated by the two examples presented here and by many other studies, at present applications of single-crystal neutron diffraction continue to be extremely flux limited and constrained by the requirement for mm-size crystals for many problems. These limitations are being addressed through the realization of powerful instruments at a new generation of pulsed neutron sources, including in the USA the TOPAZ and MaNDi single-crystal diffractometers that are under development at the Spallation Neutron Source (SNS)

Single-crystal neutron diffraction studies of hydrogen-bonded systems: Two recent examples from IPNS

Science.gov (United States)

Koetzle, Thomas F.; Piccoli, Paula M. B.; Schultz, Arthur J.

2009-02-01

Beginning with work in the 1950s at the first generation of research reactors, studies of hydrogen-bonded systems have been a prime application for single-crystal neutron diffraction. The range of systems studied was extended in the 1960s and 1970s, with the advent of high flux reactor sources, and beginning around 1980 studies at pulsed neutron sources have made increasingly important contributions. Recently at the Argonne Intense Pulsed Neutron Source (IPNS), working with collaborators, we completed two studies of hydrogen-bonded systems that will serve to illustrate topics of current interest. In the first study, on andrographolide, an active diterpenoid natural product, our neutron diffraction results definitively characterize the hydrogen-bonding interactions. The second IPNS study is on tetraacetylethane (TAE), a β-diketone enol system with a very short, strong intramolecular O-H⋯O hydrogen bond. At IPNS, we have determined the neutron crystal structure of TAE at five temperatures between 20 and 298 K to investigate changes in the structure with temperature and to probe for disorder. Despite the successes illustrated by the two examples presented here and by many other studies, at present applications of single-crystal neutron diffraction continue to be extremely flux limited and constrained by the requirement for mm-size crystals for many problems. These limitations are being addressed through the realization of powerful instruments at a new generation of pulsed neutron sources, including in the USA the TOPAZ and MaNDi single-crystal diffractometers that are under development at the Spallation Neutron Source (SNS).

Single-crystal neutron diffraction studies of hydrogen-bonded systems: Two recent examples from IPNS

International Nuclear Information System (INIS)

Koetzle, Thomas F.; Piccoli, Paula M.B.; Schultz, Arthur J.

2009-01-01

Beginning with work in the 1950s at the first generation of research reactors, studies of hydrogen-bonded systems have been a prime application for single-crystal neutron diffraction. The range of systems studied was extended in the 1960s and 1970s, with the advent of high flux reactor sources, and beginning around 1980 studies at pulsed neutron sources have made increasingly important contributions. Recently at the Argonne Intense Pulsed Neutron Source (IPNS), working with collaborators, we completed two studies of hydrogen-bonded systems that will serve to illustrate topics of current interest. In the first study, on andrographolide, an active diterpenoid natural product, our neutron diffraction results definitively characterize the hydrogen-bonding interactions. The second IPNS study is on tetraacetylethane (TAE), a β-diketone enol system with a very short, strong intramolecular O-H...O hydrogen bond. At IPNS, we have determined the neutron crystal structure of TAE at five temperatures between 20 and 298 K to investigate changes in the structure with temperature and to probe for disorder. Despite the successes illustrated by the two examples presented here and by many other studies, at present applications of single-crystal neutron diffraction continue to be extremely flux limited and constrained by the requirement for mm-size crystals for many problems. These limitations are being addressed through the realization of powerful instruments at a new generation of pulsed neutron sources, including in the USA the TOPAZ and MaNDi single-crystal diffractometers that are under development at the Spallation Neutron Source (SNS).

Stress measurement by neutron diffraction method. Standard method using angular dispersion method and trial of using neutron IP

International Nuclear Information System (INIS)

Sasaki, Toshihiko; Takago, Shigeki

2016-01-01

This paper outlined a stress measurement method using neutrons, and introduced the application examples to stress measurement for metal-based composite materials. In the angular dispersion type measurement using a steady-state reactor type neutron source, the white beams taken out from a nuclear reactor are monochromatized (wavelength λ is a constant value) with a single crystal monochromator and utilized. As an example of measurement, there was the case as follows: the stress of a sintered material which has been put to practical use as valve seat part for automobiles was measured by the neutron method, and the deformation behavior during load was studied. This study performed neutron diffraction measurement using a residual stress analyzer (RESA: Diffractometer for Residual Stress Analysis) installed at JAEA's experimental reactor JRR-3. As a result, it was found that the stress state of the sintered composite material of Fe-Cr and TiN can be predicted with a micromechanics model. A neutron diffraction ring can be obtained using a neutron image plate (IP), where fine powder of gadolinium (Gd) was incorporated into IP for X-rays, and it can be used as an IP reader in the same way as the case of X-rays. A report has been introduced on the examination results of the highly accurate stress measurement by applying the cos α method devised for X-ray stress measurement to neutron diffraction ring. (A.O.)

Dynamical neutron diffraction by curved crystals in the Laue geometry

International Nuclear Information System (INIS)

Albertini, G.; Melone, S.; Lagomarsino, S.; Mazkedian, S.; Puliti, P.; Rustichelli, F.

1977-01-01

The Taupin dynamical theory of X-ray diffraction by deformed crystals which was previously extended to the neutron diffraction by curved crystals in the Bragg geometry, is applied to calculate neutron diffraction patterns in the Laue geometry. The theoretical results are compared with experimental data on curved silicon crystals. The agreement is quite satisfactory. In the second part a simple model recently presented to describe neutron diffraction properties in the Bragg case is extended to the Laue case. The predictions of such a model are in satisfactory agreement with the rigorous theory and the experimental results. (author)

Neutron diffraction studies of high-T/sub c/ superconductors

International Nuclear Information System (INIS)

Jorgensen, J.D.

1988-03-01

Neutron powder diffraction techniques have been used extensively for the study of high-T/sub c/ oxide superconductors because of the need to locate oxygen atoms and accurately determine the oxygen site occupancies, and the difficulty in obtaining single crystals. For example, in the case of YBa 2 Cu 3 O/sub 7-δ/, neutron powder diffraction and Rietveld structural refinement were used to obtain the first complete structural information. Subsequent experiments focussed on determining the relationship of superconducting properties to the number and distribution of oxygen vacancies on the Cu-O sublattice with measurements being done on samples in thermodynamic equilibrium, at high temperature in controlled oxygen atmospheres, and on metastable, oxygen-deficient samples produced by quenching. Neutron powder diffraction has also been used to determine the structures of compounds in which the properties have been modified by substitution on the Y, Ba, or Cu sites. This paper briefly reviews some of the neutron powder diffraction results in these areas. 17 refs

Applications of image plates in neutron radiography and neutron diffraction at BARC, Trombay

International Nuclear Information System (INIS)

Shaikh, A.M.

2013-01-01

Neutron radiography techniques based on Gd, Dy and In metallic foils and X-ray film have been used at this centre since early seventies for various NDT and R and D work in nuclear, defence and aerospace industries. In recent years use of photostimulated luminescence based phosphor imaging plate has been introduced in our work. This has enabled to achieve higher sensitivities and dynamic ranges of recording radiographs with acceptable spatial resolution. It also provides digital image information which is more convenient for quantitative evaluations. Neutron image plates have been used in variety of radiography techniques such as conventional neutron radiography (NR), neutron induced beta radiography (NIBR), hydrogen sensitive epithermal neutron radiography (HYSEN) and for neutron powder diffractometry using Apsara, CIRUS and Dhruva reactors as neutron sources. Recently the image plates have also been used for characterization of thermalized neutron beam from a plasma focus neutron source and recording neutron radiographs. Prior to the utilization image plates have been characterised for their performance. Details of the measurements and applications will be presented. (author)

Neutron diffraction from holographic gratings in PMMA

International Nuclear Information System (INIS)

Havermeyer, F.; Kraetzig, E.; Rupp, R.A.; Schubert, D.W.

1999-01-01

Complete text of publication follows. By definition photorefractive materials change the refractive index for light under the action of light. Using the spatially modulated light intensity pattern from the interference of two plane waves, volume phase gratings with accurately defined spacings can be produced. Depending on the material there are many physical origins for these gratings, but in most cases they are linked to a density modulation and, consequently, to a refractive index grating for neutrons. By diffraction of light or neutrons from such gratings even small refractive index changes down to Δn ∼ 10 -7 - 10 -9 can be measured. In our photopolymer system PMMA/MMA (poly(methyl methacrylate) with a content of 10-20% of the residual monomer methyl methacrylate) inhomogeneous illumination leads to local post-polymerisation processes of the residual monomer. The resulting light-optical refractive index grating is caused by the modulation of the monomer/polymer ratio as well as by the modulation of the total density. Only by the unique combination of methods for light and neutron diffraction, available at HOLONS (Holography and Neutron Scattering, instrument at the GKSS research centre), both contributions can be separated. We discuss the angular dependence of the neutron diffraction efficiency for weakly and strongly (efficiencies up to 60% have been achieved) modulated gratings and propose a simple model for the evaluation of the gratings. (author)

A new approach of quantum mechanics for neutron single-slit diffraction

International Nuclear Information System (INIS)

Wu Xiangyao; Yang Jinghai; Liu Xiaojing; Wang Li; Liu Bing; Fan Xihui; Guo Yiqing

2007-01-01

Phenomena of electron, neutron, atomic and molecular diffraction have been studied in many experiments, and these experiments are explained by many theoretical works. We study neutron single-slit diffraction with a quantum mechanical approach. It is found that the obvious diffraction patterns can be obtained when the single slit width a is in the range of 3λ-60λ. We also find a new quantum effect of the thickness of single-slit which can make a large impact on the diffraction pattern. The new quantum effect predicted in our work can be tested by the neutron single-slit diffraction experiment. (authors)

Neutron Powder Diffraction in Sweden

International Nuclear Information System (INIS)

Tellgren, R.

1986-01-01

Neutron powder diffraction in Sweden has developed around the research reactor R2 in Studsvik. The article describes this facility and presents a historical review of research results obtained. It also gives some ideas of plans for future development

Combined X-ray and neutron fibre diffraction studies of biological and synthetic polymers

International Nuclear Information System (INIS)

Parrot, I.M.; Urban, V.; Gardner, K.H.; Forsyth, V.T.

2005-01-01

The fibrous state is a natural one for polymer molecules which tend to assume regular helical conformations rather than the globular structures characteristic of many proteins. Fibre diffraction therefore has broad application to the study of a wide range of biological and synthetic polymers. The purpose of this paper is to illustrate the general scope of the method and in particular to demonstrate the impact of a combined approach involving both X-ray and neutron diffraction methods. While the flux of modern X-ray synchrotron radiation sources allows high quality datasets to be recorded with good resolution within a very short space of time, neutron studies can provide unique information through the ability to locate hydrogen or deuterium atoms that are often difficult or impossible to locate using X-ray methods. Furthermore, neutron fibre diffraction methods can, through the ability to selectively label specific parts of a structure, be used to highlight novel aspects of polymer structure that can not be studied using X-rays. Two examples are given. The first describes X-ray and neutron diffraction studies of conformational transitions in DNA. The second describes structural studies of the synthetic high-performance polymer poly(p-phenylene terephthalamide) (PPTA), known commercially as Kevlar[reg] or Twaron[reg

Combined X-ray and neutron fibre diffraction studies of biological and synthetic polymers.

Energy Technology Data Exchange (ETDEWEB)

Parrot, I. M. [Institut Laue-Langevin (ILL); Urban, Volker S [ORNL; Gardner, K. H. [DuPont Experimental Station; Forsyth, V. T. [Institut Laue Langevin and Keele University

2005-04-01

The fibrous state is a natural one for polymer molecules which tend to assume regular helical conformations rather than the globular structures characteristic of many proteins. Fibre diffraction therefore has broad application to the study of a wide range of biological and synthetic polymers. The purpose of this paper is to illustrate the general scope of the method and in particular to demonstrate the impact of a combined approach involving both X-ray and neutron diffraction methods. While the flux of modern X-ray synchrotron radiation sources allows high quality datasets to be recorded with good resolution within a very short space of time, neutron studies can provide unique information through the ability to locate hydrogen or deuterium atoms that are often difficult or impossible to locate using X-ray methods. Furthermore, neutron fibre diffraction methods can, through the ability to selectively label specific parts of a structure, be used to highlight novel aspects of polymer structure that can not be studied using X-rays. Two examples are given. The first describes X-ray and neutron diffraction studies of conformational transitions in DNA. The second describes structural studies of the synthetic high-performance polymer poly(p-phenylene terephthalamide) (PPTA), known commercially as Kevlar{reg_sign} or Twaron{reg_sign}.

Combined X-ray and neutron fibre diffraction studies of biological and synthetic polymers

Science.gov (United States)

Parrot, I. M.; Urban, V.; Gardner, K. H.; Forsyth, V. T.

2005-08-01

The fibrous state is a natural one for polymer molecules which tend to assume regular helical conformations rather than the globular structures characteristic of many proteins. Fibre diffraction therefore has broad application to the study of a wide range of biological and synthetic polymers. The purpose of this paper is to illustrate the general scope of the method and in particular to demonstrate the impact of a combined approach involving both X-ray and neutron diffraction methods. While the flux of modern X-ray synchrotron radiation sources allows high quality datasets to be recorded with good resolution within a very short space of time, neutron studies can provide unique information through the ability to locate hydrogen or deuterium atoms that are often difficult or impossible to locate using X-ray methods. Furthermore, neutron fibre diffraction methods can, through the ability to selectively label specific parts of a structure, be used to highlight novel aspects of polymer structure that can not be studied using X-rays. Two examples are given. The first describes X-ray and neutron diffraction studies of conformational transitions in DNA. The second describes structural studies of the synthetic high-performance polymer poly(p-phenylene terephthalamide) (PPTA), known commercially as Kevlar® or Twaron®.

Combined X-ray and neutron fibre diffraction studies of biological and synthetic polymers

Energy Technology Data Exchange (ETDEWEB)

Parrot, I.M. [Institut Laue Langevin, 6 Rue Jules Horowitz, 38042 Grenoble Cedex 9 (France); Institute of Science and Technology in Medicine, Keele University Medical School, Staffordshire ST4 7QB (United Kingdom); Urban, V. [Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN 37831-6100 (United States); Gardner, K.H. [Department of Materials Science and Engineering University of Delaware, Newark, DE 19719 (United States); Forsyth, V.T. [Institut Laue Langevin, 6 Rue Jules Horowitz, 38042 Grenoble Cedex 9 (France) and Institute of Science and Technology in Medicine, Keele University Medical School, Staffordshire ST4 7QB (United Kingdom)]. E-mail: tforsyth@ill.fr

2005-08-15

The fibrous state is a natural one for polymer molecules which tend to assume regular helical conformations rather than the globular structures characteristic of many proteins. Fibre diffraction therefore has broad application to the study of a wide range of biological and synthetic polymers. The purpose of this paper is to illustrate the general scope of the method and in particular to demonstrate the impact of a combined approach involving both X-ray and neutron diffraction methods. While the flux of modern X-ray synchrotron radiation sources allows high quality datasets to be recorded with good resolution within a very short space of time, neutron studies can provide unique information through the ability to locate hydrogen or deuterium atoms that are often difficult or impossible to locate using X-ray methods. Furthermore, neutron fibre diffraction methods can, through the ability to selectively label specific parts of a structure, be used to highlight novel aspects of polymer structure that can not be studied using X-rays. Two examples are given. The first describes X-ray and neutron diffraction studies of conformational transitions in DNA. The second describes structural studies of the synthetic high-performance polymer poly(p-phenylene terephthalamide) (PPTA), known commercially as Kevlar[reg] or Twaron[reg].

The internal stress measurement the neutron diffraction will bring happiness to your country

International Nuclear Information System (INIS)

Minakawa, Nobuaki

2003-01-01

The neutron was discovered by Chadwick in 1932. The first reactor was constructed by the USA in 1942. After that, the research and development of reactors advanced. Numbers of reactors were constructed in Europe and in the US. The researches, which use the neutron, were performed actively and excellent results were obtained in wide fields. The penetrating power of the neutron and the neutron diffraction method began to attract attention for the application to the internal stress measurement, too. In Japan, the neutron diffractometer for the residual stress measurement exclusive was installed in the JRR-3M research reactor of JAERI in 1992, and the research was started. At present, we are using it for the stress measurements of the parts of air crafts, railways, automobiles, buildings, machines, home electronics products and so on including nuclear reactors. Reliable science must be introduced in order to support safety and long life operation and to supply them at reasonable cost. Among the various scientific probes to find faults in materials, diffraction technique is used to measure the strain distribution in materials by observing the local changes of the distance between crystallographic planes and the stress distribution is computed to improve manufacturing processes. It is only neutron diffraction that can be used to measure the strain inside the materials. Here, I present an overview of the utilization of neutron scattering research for the industrial uses and the history of the neutron scattering research in JAERI briefly. (J.P.N.)

In situ high-pressure measurement of crystal solubility by using neutron diffraction

Science.gov (United States)

Chen, Ji; Hu, Qiwei; Fang, Leiming; He, Duanwei; Chen, Xiping; Xie, Lei; Chen, Bo; Li, Xin; Ni, Xiaolin; Fan, Cong; Liang, Akun

2018-05-01

Crystal solubility is one of the most important thermo-physical properties and plays a key role in industrial applications, fundamental science, and geoscientific research. However, high-pressure in situ measurements of crystal solubility remain very challenging. Here, we present a method involving high-pressure neutron diffraction for making high-precision in situ measurements of crystal solubility as a function of pressure over a wide range of pressures. For these experiments, we designed a piston-cylinder cell with a large chamber volume for high-pressure neutron diffraction. The solution pressures are continuously monitored in situ based on the equation of state of the sample crystal. The solubility at a high pressure can be obtained by applying a Rietveld quantitative multiphase analysis. To evaluate the proposed method, we measured the high-pressure solubility of NaCl in water up to 610 MPa. At a low pressure, the results are consistent with the previous results measured ex situ. At a higher pressure, more reliable data could be provided by using an in situ high-pressure neutron diffraction method.

Maximizing Macromolecule Crystal Size for Neutron Diffraction Experiments

Science.gov (United States)

Judge, R. A.; Kephart, R.; Leardi, R.; Myles, D. A.; Snell, E. H.; vanderWoerd, M.; Curreri, Peter A. (Technical Monitor)

2002-01-01

A challenge in neutron diffraction experiments is growing large (greater than 1 cu mm) macromolecule crystals. In taking up this challenge we have used statistical experiment design techniques to quickly identify crystallization conditions under which the largest crystals grow. These techniques provide the maximum information for minimal experimental effort, allowing optimal screening of crystallization variables in a simple experimental matrix, using the minimum amount of sample. Analysis of the results quickly tells the investigator what conditions are the most important for the crystallization. These can then be used to maximize the crystallization results in terms of reducing crystal numbers and providing large crystals of suitable habit. We have used these techniques to grow large crystals of Glucose isomerase. Glucose isomerase is an industrial enzyme used extensively in the food industry for the conversion of glucose to fructose. The aim of this study is the elucidation of the enzymatic mechanism at the molecular level. The accurate determination of hydrogen positions, which is critical for this, is a requirement that neutron diffraction is uniquely suited for. Preliminary neutron diffraction experiments with these crystals conducted at the Institute Laue-Langevin (Grenoble, France) reveal diffraction to beyond 2.5 angstrom. Macromolecular crystal growth is a process involving many parameters, and statistical experimental design is naturally suited to this field. These techniques are sample independent and provide an experimental strategy to maximize crystal volume and habit for neutron diffraction studies.

Neutron diffraction from lead germanate glasses

International Nuclear Information System (INIS)

Umesaki, Norimasa; Brunier, T.M.; Wright, A.C.; Hannon, A.C.; Scinclair, R.N.

1993-01-01

High resolution neutron diffraction data have been collected on the PbO-GeO 2 glasses and on GeO 2 for comparison. These neutron data have revealed the existence of 6-fold coordinated germanium (GeO 6 octahedra) by virtue of the shift in the first peak in the obtained total correlation function T(r) and increase in the coordination. The neutron results also indicate that PbO exits as PbO 4 pyramids, as found in the orthorhombic form of PbO crystal, in the studied PbO-GeO 2 glasses. (author)

Neutron forward diffraction by single crystal prisms

Indian Academy of Sciences (India)

We have derived analytic expressions for the deflection as well as transmitted fraction of monochromatic neutrons forward diffracted by a single crystal prism. In the vicinity of a Bragg reflection, the neutron deflection deviates sharply from that for an amorphous prism, exhibiting three orders of magnitude greater sensitivity to ...

Determination of textures by neutron diffraction

International Nuclear Information System (INIS)

Dervin, P.; Penelle, R.

1989-01-01

In virtue of the low absorption coefficient of most materials in regard to neutrons, neutron diffraction is particularly well adapted for high-precision characterizing of the gross texture of massive fine-grained or coarse-grained specimens of the order of the cubic centimeter. The firt part of this paper is devoted to a description of the distribution of crystalline orientations, and the second part to experimental identification of textures [fr

TOF neutron diffraction study of archaeological ceramics

International Nuclear Information System (INIS)

Kockelmann, W.; Kirfel, A.

1999-01-01

Complete text of publication follows. The time-of flight (TOF) neutron diffractometer ROTAX [1] at ISIS has been used for identification and quantitative phase analysis of archaeological pottery. Neutron diffraction yields mineral phase fractions which, in parallel with information obtained from other archaeometric examination techniques, can provide a fingerprint that can be used to identify provenance and reconstruct methods of manufacturing of an archaeological ceramic product. Phase fractions obtained from a 13th century Rhenish stoneware jar compare well with those obtained from a powder sample prepared from the same fragment. This indicates that reliable results can be obtained by illuminating a large piece or even an intact ceramic object making TOF neutron diffraction a truly non-destructive examination technique. In comparison to X-ray diffraction, information from the bulk sample rather than from surface regions is obtained. ROTAX allows for a simple experimental set-up, free of sample movements. Programmes of archaeological study on ROTAX involve Russian samples (Upper-Volga culture, 5000-2000 BC), Greek pottery, (Agora/Athens, 500-300 BC), and medieval German earthenware and stoneware ceramics (Siegburg waster heap, 13-15th century). (author)

Residual Stress Analysis for Engineering Applications by Means of Neutron Diffraction

International Nuclear Information System (INIS)

Gndupel-Herold, Thomas; Brand, Paul C.; Prask, Henry J.

1999-01-01

The economic and scientific importance of neutron diffraction residual stress analysis has led to an increasing number of suitable instruments worldwide. Recently, a dedicated state-of-the-art diffractometer has been installed at the National Institute of Standards and Technology reactor. It has been used for a variety of measurements on basic and engineering stress problems. Among the most prominent examples that have been investigated are residual stresses in rails, weldments, and plasma-sprayed coatings

A new bridge technique for neutron tomography and diffraction measurements

International Nuclear Information System (INIS)

Burca, G.; James, J.A.; Kockelmann, W.; Fitzpatrick, M.E.; Zhang, S.Y.; Hovind, J.; Langh, R. van

2011-01-01

An attractive feature of neutron techniques is the ability to identify hidden materials and structures inside engineering components and objects of art and archaeology. Bearing this in mind we are investigating a new technique, 'Tomography Driven Diffraction' (TDD), that exploits tomography data to guide diffraction experiments on samples with complex structures and shapes. The technique can be used utilising combinations of individual tomography and diffraction instruments, such as NEUTRA (PSI, CH) and ENGIN-X (ISIS, UK), but is also suitable for new combined imaging and diffraction instruments such as the JEEP synchrotron engineering instrument (DIAMOND, UK) and the proposed IMAT neutron imaging and diffraction instrument (ISIS, UK).

X-ray and neutron diffraction studies of crystallinity in hydroxyapatite coatings.

Science.gov (United States)

Girardin, E; Millet, P; Lodini, A

2000-02-01

To standardize industrial implant production and make comparisons between different experimental results, we have to be able to quantify the crystallinity of hydroxyapatite. Methods of measuring crystallinity ratio were developed for various HA samples before and after plasma spraying. The first series of methods uses X-ray diffraction. The advantage of these methods is that X-ray diffraction equipment is used widely in science and industry. In the second series, a neutron diffraction method is developed and the results recorded are similar to those obtained by the modified X-ray diffraction methods. The advantage of neutron diffraction is the ability to obtain measurements deep inside a component. It is a nondestructive method, owing to the very low absorption of neutrons in most materials. Copyright 2000 John Wiley & Sons, Inc.

Polycrystalline deformation in engineering materials: Insights from neutron diffraction during loading

International Nuclear Information System (INIS)

Bourke, M.; Brown, D.

1999-01-01

In-situ measurements using the non-destructive penetration of neutrons are commonplace at neutron sources and permit investigations within environmental chambers at stress, pressure, or temperature. Many of these studies explore the microstructural performance of engineering materials under service conditions. For example, by measuring phase strains during the application of static loads, neutron diffraction provides insight into failure, relaxation and load transfer mechanisms. Mechanical loading of a sample on a neutron spectrometer is usually performed with a customized load frame (small enough to fit into the typically limited available space) with the load axis horizontal. Diffraction data are recorded using detectors that surround the sample and strains are determined from changes in the measured interplanar lattice spacings in directions determined by the scattering geometry. These elastic strains indicate how the applied stress is shared throughout the microstructure. During a test, conventional strain gauges also record the macroscopic strain; that is the sum of the plastic and elastic contributions. Beyond yield the plastic contribution usually dominates the total strain but the elastic phase strains respond to the applied stress at any given load and provide clues about which phase (in a multiphase system) or which crystal orientation (in a single phase polycrystal) dictates failure

Dynamical theory of neutron diffraction. [One-body Schroedinger equation, review

Energy Technology Data Exchange (ETDEWEB)

Sears, V F [Atomic Energy of Canada Ltd., Chalk River, Ontario. Chalk River Nuclear Labs.

1978-10-01

We present a review of the dynamical theory of neutron diffraction by macroscopic bodies which provides the theoretical basis for the study of neutron optics. We consider both the theory of dispersion, in which it is shown that the coherent wave in the medium satisfies a macroscopic one-body Schroedinger equation, and the theory of reflection, refraction, and diffraction in which the above equation is solved for a number of special cases of interest. The theory is illustrated with the help of experimental results obtained over the past 10 years by a number of new techniques such as neutron gravity refractometry. Pendelloesung interference, and neutron interferometry.

Neutron diffraction technique as a method for material studies

International Nuclear Information System (INIS)

Belhorma, B.; Labrim, H.; Gandou, Z.

2010-01-01

The Morocco's first Nuclear Research has been constructed in CNESTEN. The reactor divergence has been tested, and the nominal power of 2MW was successfully achieved. The reactor has 4 beam ports two of them are projected for neutron scattering. Such technique allows studying the crystallographic and magnetic structures of materials using the thermal neutrons produced in the reactor. the powder diffractometer has been designed. Component reception and installation procedures are in progress. The second experiment consists on small angle neutron scattering that allows the study of soft matter and polymers in the range of 1-50 nm. The third technique that can complete the two previous is the 4-circle neutron spectrometry which is designed mainly to study structural properties of the mono-crystalline material and texture.This technique is complementary to the X-ray diffraction already available in CNESTEN. Some applications of this technique are: --to determine the crystallographic and magnetic structure of polycrystalline materials.-- to study the texture in metals and alloys.-- to perform holography measurement

X-ray and Neutron Diffraction in the Study of Organic Crystalline Hydrates

Directory of Open Access Journals (Sweden)

Katharina Fucke

2010-07-01

Full Text Available A review. Diffraction methods are a powerful tool to investigate the crystal structure of organic compounds in general and their hydrates in particular. The laboratory standard technique of single crystal X-ray diffraction gives information about the molecular conformation, packing and hydrogen bonding in the crystal structure, while powder X-ray diffraction on bulk material can trace hydration/dehydration processes and phase transitions under non-ambient conditions. Neutron diffraction is a valuable complementary technique to X-ray diffraction and gives highly accurate hydrogen atom positions due to the interaction of the radiation with the atomic nuclei. Although not yet often applied to organic hydrates, neutron single crystal and neutron powder diffraction give precise structural data on hydrogen bonding networks which will help explain why hydrates form in the first place.

Neutrons in studies of phospholipid bilayers and bilayer–drug interaction. I. Basic principles and neutron diffraction

Directory of Open Access Journals (Sweden)

Belička M.

2014-12-01

Full Text Available In our paper, we demonstrate several possibilities of using neutrons in pharmaceutical research with the help of examples of scientific results achieved at our University. In this first part, basic properties of neutrons and elementary principles of elastic scattering of thermal neutrons are described. Results of contrast variation neutron diffraction on oriented phospholipid bilayers with intercalated local anaesthetic or cholesterol demonstrate the potential of this method at determination of their position in bilayers. Diffraction experiments with alkan-1-ols located in the bilayers revealed their influence on bilayer thickness as a function of their alkyl chain length.

Neutron diffraction measurements of residual stresses in NPP construction materials

International Nuclear Information System (INIS)

Hinca, R.; Bokuchava, G.

2001-01-01

Neutron diffraction is one of the most powerful methods for condensed matter studies. This method is used for non-destructive determination of residual stresses in material. The fundamental aspects of neutron diffraction are discussed, together with a brief description of the experimental facility. The principal advantage of using neutrons rather than the more conventional X-rays is the fact that neutron can penetrate deeply (2-4 cm for steel and more than 10 cm for aluminium) into metals to determine internal parameters within the bulk of materials. We present results of measurements residual stresses in NPP construction material - austenitic stainless steel (Cr-18%, Ni-10%, Ti-1%) coated with high-nickel alloy. (authors)

Neutron diffraction in a frustrated ferrite

International Nuclear Information System (INIS)

Mirebeau, I.; Iancu, G.; Gavoille, G.; Hubsch, J.

1994-01-01

The competition between a long range ordered ferrimagnetic lattice and small fluctuating clusters have been probed by neutron diffraction in a titanium magnesium frustrated ferrite. The description of the system is then compared to the predictions of several theoretical models for frustrated systems. 3 figs., 8 refs

Neutron powder diffraction under high pressure at J-PARC

International Nuclear Information System (INIS)

Utsumi, Wataru; Kagi, Hiroyuki; Komatsu, Kazuki; Arima, Hiroshi; Nagai, Takaya; Okuchi, Takuo; Kamiyama, Takashi; Uwatoko, Yoshiya; Matsubayashi, Kazuyuki; Yagi, Takehiko

2009-01-01

It is expected that high-pressure material science and the investigation of the Earth's interior will progress greatly using the high-flux pulse neutrons of J-PARC. In this article, we introduce our plans for in situ neutron powder diffraction experiments under high pressure at J-PARC. The use of three different types of high-pressure devices is planned; a Paris-Edinburgh cell, a new opposed-anvil cell with a nano-polycrystalline diamond, and a cubic anvil high-pressure apparatus. These devices will be brought to the neutron powder diffraction beamlines to conduct a 'day-one' high-pressure experiment. For the next stage of research, we propose construction of a dedicated beamline for high-pressure material science. Its conceptual designs are also introduced here.

Time-of-flight diffraction at pulsed neutron sources: An introduction to the symposium

International Nuclear Information System (INIS)

Jorgensen, J.D.

1994-01-01

In the 25 years since the first low-power demonstration experiments, pulsed neutron sources have become as productive as reactor sources for many types of diffraction experiments. The pulsed neutron sources presently operating in the United States, England, and Japan offer state of the art instruments for powder and single crystal diffraction, small angle scattering, and such specialized techniques as grazing-incidence neutron reflection, as well as quasielastic and inelastic scattering. In this symposium, speakers review the latest advances in diffraction instrumentation for pulsed neutron sources and give examples of some of the important science presently being done. In this introduction to the symposium, I briefly define the basic principles of pulsed neutron sources, review their development, comment in general terms on the development of time-of-flight diffraction instrumentation for these sources, and project how this field will develop in the next ten years

Study of quartz-glass using Roentgen- and neutron-diffraction

International Nuclear Information System (INIS)

Sikkenk, P.J.

1988-08-01

An X-ray diffraction measurement, with wavelength 0.0711 nm, is made of a vitreous silica to kappa of 200nm -1 . (faculty of materials science) A second X-ray diffraction measurement has been executed (National Laboratory Oak Ridge). For this research we also used neutron diffraction measurement (IRI), with wavelength 0.085 nm of a vitreous silica to kappa of 132 nm -1 . The intermolecular scattering functions derived from the X-ray measurements and neutron measurements by omitting the intramolecular scattering contribution. A theoretical model for the structure of vitreous silica is used, derived from a mixture of Si en SiO-4 units. The partial scattering functions i-S-i---S-i is determined with help of the model and the intermolecular X-ray scattering functions and intermolecular neutron scattering functions and intermolecular neutron scatteirng functions. The fouriertransform of the partial scattering function i-S-i---S-i leads to the partial radial correlation function. When this partial radial correlation function is compared to a correlation function directly obtained by the intermolecular scattering function, a considerable increase of the resolution is observed in the partial correlation function if r > 0.29 nm and r < 0.45 nm. (author). 16 refs.; 30 figs.; 9 tabs

Bainitic transformation behavior studied by simultaneous neutron diffraction and dilatometric measurement

International Nuclear Information System (INIS)

Koo, Minseo; Xu, Pingguang; Tomota, Yo; Suzuki, Hiroshi

2009-01-01

Bainitic transformation behavior has firstly been observed using in situ neutron diffraction with an angular dispersive method for a hard bainite steel. The dilatometric measurement was carried out simultaneously with the neutron experiment where changes in (1 1 1) austenite and (1 1 0) ferrite diffraction profiles were monitored during heating, cooling and holding at a transformation temperature. The neutron experiments results agree with dilatometry results. They appear to have found that the austenite peak broadening occurs after the onset of bainitic transformation but not before.

High-resolution neutron diffraction studies of biological and industrial fibres

Energy Technology Data Exchange (ETDEWEB)

Langan, P; Mason, S A [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France); Fuller, W; Forsyth, V T; Mahendrasingam, A; Shotton, M; Simpson, L [Keele Univ. (United Kingdom); Grimm, H [FZ, Juelich (Germany); Leberman, R [EMBL, (Country Unknown)

1997-04-01

Neutron diffraction is becoming an important tool for studying fibres due to its complementarity to X-ray diffraction. Unlike X-rays, scattering of neutrons by polymer atoms is not a function of their atomic number. In high-resolution studies (1.5-3 A) on D19 deuteration (replacing H by D) is being used to change the relative scattering power of chosen groups making them easier to locate. Recent studies on DNA and cellulose are described. (author). 6 refs.

Neutron diffraction measurements at the INES diffractometer using a neutron radiative capture based counting technique

Energy Technology Data Exchange (ETDEWEB)

Festa, G. [Centro NAST, Universita degli Studi di Roma Tor Vergata, Roma (Italy); Pietropaolo, A., E-mail: antonino.pietropaolo@roma2.infn.it [Centro NAST, Universita degli Studi di Roma Tor Vergata, Roma (Italy); Grazzi, F.; Barzagli, E. [CNR-ISC Firenze (Italy); Scherillo, A. [CNR-ISC Firenze (Italy); ISIS facility Rutherford Appleton Laboratory (United Kingdom); Schooneveld, E.M. [ISIS facility Rutherford Appleton Laboratory (United Kingdom)

2011-10-21

The global shortage of {sup 3}He gas is an issue to be addressed in neutron detection. In the context of the research and development activity related to the replacement of {sup 3}He for neutron counting systems, neutron diffraction measurements performed on the INES beam line at the ISIS pulsed spallation neutron source are presented. For these measurements two different neutron counting devices have been used: a 20 bar pressure squashed {sup 3}He tube and a Yttrium-Aluminum-Perovskite scintillation detector. The scintillation detector was coupled to a cadmium sheet that registers the prompt radiative capture gamma rays generated by the (n,{gamma}) nuclear reactions occurring in cadmium. The assessment of the scintillator based counting system was done by performing a Rietveld refinement analysis on the diffraction pattern from an ancient Japanese blade and comparing the results with those obtained by a {sup 3}He tube placed at the same angular position. The results obtained demonstrate the considerable potential of the proposed counting approach based on the radiative capture gamma rays at spallation neutron sources.

Lattice strain measurements on sandstones under load using neutron diffraction

Science.gov (United States)

Frischbutter, A.; Neov, D.; Scheffzük, Ch.; Vrána, M.; Walther, K.

2000-11-01

Neutron diffraction methods (both time-of-flight- and angle-dispersive diffraction) are applied to intracrystalline strain measurements on geological samples undergoing uniaxial increasing compressional load. The experiments were carried out on Cretaceous sandstones from the Elbezone (East Germany), consisting of >95% quartz which are bedded but without crystallographic preferred orientation of quartz. From the stress-strain relation the Young's modulus for our quartz sample was determined to be (72.2±2.9) GPa using results of the neutron time-of-flight method. The influence of different kinds of bedding in sandstones (laminated and convolute bedding) could be determined. We observed differences of factor 2 (convolute bedding) and 3 (laminated bedding) for the elastic stiffness, determined with angle dispersive neutron diffraction (crystallographic strain) and with strain gauges (mechanical strain). The data indicate which geological conditions may influence the stress-strain behaviour of geological materials. The influence of bedding on the stress-strain behaviour of a laminated bedded sandstone was indicated by direct residual stress measurements using neutron time-of-flight diffraction. The measurements were carried out six days after unloading the sample. Residual strain was measured for three positions from the centre to the periphery and within two radial directions of the cylinder. We observed that residual strain changes from extension to compression in a different manner for two perpendicular directions of the bedding plane.

Residual stress distribution in carbon steel pipe welded joint measured by neutron diffraction

International Nuclear Information System (INIS)

Hayashi, Makoto; Ishiwata, Masayuki; Morii, Yukio; Minakawa, Nobuaki

2000-01-01

In order to estimate crack growth behavior of fatigue and stress corrosion cracking in pipes, the residual stress distribution near the pipe weld region has to be measured through the wall thickness. Since the penetration depth of neutron is deep enough to pass through the thick pipe wall, the neutron diffraction technique for the residual stress measurement is effective for this purpose. At the first step the residual stress distribution near the weld region in a butt-welded carbon steel pipe was measured by the neutron diffraction. Significant stresses extended only to a distance of 30 mm from the center of the weld. The major tensile stresses occurred in the hoop direction in the fusion and heat affected zones of the weldment, and they attained a level greater than 200 MPa through the thickness. While the axial residual stress at the inside surface was 50 MPa, the stress at the outside surface was -100 MPa. The comparison of residual stress distributions measured by the neutron diffraction, the X-ray diffraction and the strain gauge method reveals that the neutron diffraction is the most effective for measuring the residual stress inside the structural components. (author)

Interphase microstress measurements in IN 718 by cold neutron diffraction

Energy Technology Data Exchange (ETDEWEB)

Repper, J.; Link, P.; Hofmann, M.; Petry, W. [TU Muenchen, Forschungsneutronenquelle Heinz Maier-Leibnitz (FRM II), Garching (Germany); Krempaszky, C. [TU Muenchen, Christian-Doppler-Labor fuer Werkstoffmechanik von Hochleistungslegierungen, Garching (Germany); Werner, E. [TU Muenchen, Lehrstuhl fuer Werkstoffkunde und Werkstoffmechanik, Garching (Germany)

2010-06-15

Thermal neutron diffraction is an important and reliable method for the investigation of microscopic stresses. The measurement of Bragg reflections caused by phases of small volume fractions, however, is often intricate due to low intensities and overlapping peaks. The wavelength range of cold neutrons allows to shift the Bragg reflections to larger scattering angles resulting in an increase of relative distances between Bragg reflections. The high resolution of cold neutron diffraction technique is demonstrated by in-situ load tests in which selected Bragg reflections caused by precipitates with small volume fractions in the precipitation strengthened alloy IN 718 are observed. The accumulated microstrains show marked differences in dependence of the precipitated phases within the matrix phase. (orig.)

Neutron Powder Diffraction and Constrained Refinement

DEFF Research Database (Denmark)

Pawley, G. S.; Mackenzie, Gordon A.; Dietrich, O. W.

1977-01-01

The first use of a new program, EDINP, is reported. This program allows the constrained refinement of molecules in a crystal structure with neutron diffraction powder data. The structures of p-C6F4Br2 and p-C6F4I2 are determined by packing considerations and then refined with EDINP. Refinement is...

Neutron diffraction on polymorphic phases of phospholipids

International Nuclear Information System (INIS)

Adachi, Tomohiro; Furusaka, Michihiro; Otomo, Toshiya; Hatta, Ichiro

2001-01-01

Small angle neutron diffraction experiments were performed in DPPC and DPPC/cholesterol systems. We investigated the DPPC-d62 bilayers without cholesterol and the DPPC-d75 bilayers with 5 and 15 mol% cholesterol. For DPPC-d62 systems, in the gel and fluid phase, the reflections up to third order from lamellar structure were observed. Scattering length density profiles of these systems were generated. They show that the packing density of hydrocarbon chain in gel phase is higher than in fluid phase. We show that the neutron diffraction experiment is effective on observing the packing and the scattering length density of the hydrocarbon chain. On the other hand, for DPPC-d75/cholesterol systems, only the reflection from the ripple structure was observed. It shows that cholesterol is periodically localized in accordance with ripple structure forming a periodic bandlike structure parallel to a ridge of the ripple structure. (author)

Neutron-diffraction measurements of stress

International Nuclear Information System (INIS)

Holden, T.M.

1995-01-01

Experiments on bent steam-generator tubing have shown that different diffraction peaks, (1 1 1) or (0 0 2), give different results for the sign and magnitude of the stress and strain. From an engineering standpoint, the macroscopic stress field cannot be both positive and negative in the same volume, so this difference must be due to intergranular effects superposed on the macroscopic stress field. Uniaxial tensile test experiments with applied stresses beyond the 0.2% offset yield stress, help to understand this anomaly, by demonstrating the different strain response to applied stress along different crystallographic axes.When Zr-alloys are cooled from elevated temperatures, thermal stresses always develop, so that it is difficult to obtain a stress-free lattice spacing from which residual strains may be derived. From measurements of the temperature dependence of lattice spacing, the temperature at which the thermal stresses vanish may be found. From the lattice spacing at this temperature the stress-free lattice spacings at room temperature can be obtained readily.To interpret the measured strains in terms of macroscopic stress fields it is necessary to know the diffraction elastic constants. Neutron diffraction measurements of the diffraction elastic constants in a ferritic steel for the [1 1 0], [0 0 2] and [2 2 2] crystallographic axes, in directions parallel and perpendicular to the applied stress are compared with theoretical diffraction elastic constants. (orig.)

Texture investigation in aluminium and iron - silicon samples by neutron diffraction technique

International Nuclear Information System (INIS)

Pugliese, R.; Yamasaki, J.M.

1988-09-01

By means of the neutron diffraction technique the texture of 5% and 98% rolled-aluminium and of iron-silicon steel used in the core of electric transformers, have been determined. The measurements were performed by using a neutron diffractometer installed at the IEA-R1 Nuclear Research Reactor, in the Beam-Hole n 0 . 6. To avoid corrections such as neutron absorption and sample luminosity the geometric form of the samples were approximated to spheric or octagonal prism, and its dimensions do not exceed that of the neutron beam. The texture of the samples were analysed with the help of a computer programme that analyses the intensity of the diffracted neutron beam and plot the pole figures. (author) [pt

Neutron irradiated uranium silicides studied by neutron diffraction and Rietveld analysis

International Nuclear Information System (INIS)

Birtcher, R.C.; Mueller, M.H.; Richardson, J.W. Jr.; Faber, J. Jr.

1989-11-01

Uranium silicides have been considered for use as reactor fuels in both high power and low enrichment applications. However, U 3 Si was found to become amorphous under irradiation and to become mechanically unstable to rapid growth by plastic flow. U 2 Si 2 appears to be stable against amorphization at low displacement rates, but the extent of this stability is uncertain. Although the mechanisms responsible for plastic flow in U 3 Si and other amorphous systems are unknown, as is the importance of crystal structure for amorphization, it may not be surprising that these materials amorphize, in light of the fact that many radioactive nuclide - containing minerals are known to metaminctize (lose crystallinity) under irradiation. The present experiment follows the detailed changes in the crystal structures of U 3 Si and U 3 Si 2 introduced by neutron bombardment and subsequent uranium fission at room temperature. U-Si seems the ideal system for a neutron diffraction investigation since the crystallographic and amorphous forms can be studied simultaneously by combining conventional Rietveld refinement of the crystallographic phases with Fourier-filtering of the non-crystalline scattering component

Neutron diffraction and Vitamin E

Energy Technology Data Exchange (ETDEWEB)

Harroun, T A; Marquardt, D; Katsaras, J; Atkinson, J, E-mail: tharroun@brocku.ca

2010-11-01

It is generally accepted that neutron diffraction from model membrane systems is an effective biophysical technique for determining membrane structure. Here we describe an example of how deuterium labelling can elucidate the location of specific membrane soluble molecules, including a brief discussion of the technique itself. We show that deuterium labelled {alpha}-tocopherol sits upright in the bilayer, as might be expected, but at very different locations within the bilayer, depending on the degree of lipid chain unsaturation.

Neutron diffraction of γ-aluminium oxynitride

NARCIS (Netherlands)

Willems, H.X.; With, de G.; Metselaar, R.; Helmholdt, R.B.; Petersen, K.K.

1993-01-01

Neutron diffraction expts. were performed on Al oxynitride (Alon) powders with compns. corresponding to 67.5, 73 and 77.5 mol.% Al2O3. The 73 mol.% powder was produced by reacting Al2O3 and AlN powders for 3 h at 1750 Deg. After reaction the resultant powder was ground with a mortar and pestle to

Crystallographic structures of absorbates and neutron diffraction

International Nuclear Information System (INIS)

Marti, C.; Thorel, P.

1975-01-01

The advantage of neutron diffraction is that it is possible to work at any pressure and therefore to study an adsorbant-adsorbate couple within a wide pressure and temperature range and at thermodynamic equilibrium. Nitrogen adsorbed on graphite and CF 4 adsorbed on graphite were measured [fr

Deformation processes in functional materials studied by in situ neutron diffraction and ultrasonic techniques

International Nuclear Information System (INIS)

Sittner, P.; Novak, V.; Landa, M.; Lukas, P.

2007-01-01

The unique thermomechanical functions of shape memory alloys (hysteretic stress-strain-temperature responses) not their structural properties (as strength, fatigue, corrosion resistance, etc.) are primarily utilized in engineering applications. In order to better understand and predict the functional behavior, we have recently employed two dedicated non-invasive in situ experimental methods capable to follow the deformation/transformation processes in thermomechanically loaded polycrystalline samples. The in situ neutron diffraction method takes advantage of the ability of thermal neutrons to penetrate bulk samples. As a diffraction technique sensitive to interplanar spacings in crystalline solids, it provides in situ information on the changes in crystal structure, phase composition, phase stress and texture in the transforming samples. The combined in situ ultrasonic and electric resistance method follows variations of the electric resistance as well as speed and attenuation of acoustic waves propagating through the transforming sample. The acoustic waves are mainly sensitive to changes of elastic properties accompanying the deformation/transformation processes. The latter method thus follows the changes in interatomic bonds rather than changes in the interplanar lattice spacings focused in the neutron diffraction method. The methods are thus complementary. They are briefly described and selected experimental results obtained recently on NiTi alloys are presented and discussed

The peak in neutron powder diffraction

International Nuclear Information System (INIS)

Laar, B. van; Yelon, W.B.

1984-01-01

For the application of Rietveld profile analysis to neutron powder diffraction data a precise knowledge of the peak profile, in both shape and position, is required. The method now in use employs a Gaussian shaped profile with a semi-empirical asymmetry correction for low-angle peaks. The integrated intensity is taken to be proportional to the classical Lorentz factor calculated for the X-ray case. In this paper an exact expression is given for the peak profile based upon the geometrical dimensions of the diffractometer. It is shown that the asymmetry of observed peaks is well reproduced by this expression. The angular displacement of the experimental profile with respect to the nominal Bragg angle value is larger than expected. Values for the correction to the classical Lorentz factor for the integrated intensity are given. The exact peak profile expression has been incorporated into a Rietveld profile analysis refinement program. (Auth.)

Structure analysis of liquids and disordered materials using pulsed neutron diffraction and total scattering

International Nuclear Information System (INIS)

Suzuya, Kentaro

2011-01-01

Neutron diffraction·total scattering at pulsed neutron source is a powerful method to analyze the complex structure of disordered materials: liquids, glasses, amorphous materials and disordered crystals. The basic idea of the structure of disordered materials, the fundamental diffraction theory for disordered materials, and structure analysis of disordered materials using pulsed neutron diffraction·total scattering technique (TOF method) are described in detail. In addition, the precise information of the world highest class J-PARC MLF spallation neutron source and typical J-PARC neutron total scattering instrument NOVA are also given. Recent structural modelling methods of disordered materials such like reverse Monte Carlo (RMC) simulation method is briefly described using an example of the analysis of a typical disordered material silica glass. (author)

Investigation of solid solution of hydrogen in α-manganese by neutron diffraction and inelastic neutron scattering

International Nuclear Information System (INIS)

Fedotov, V.K.; Antonov, V.E.; Kolesnikov, A.I.; Kornell, K.; Vipf, G.; Grosse, G.; Vagner, F.Eh.; Sikolenko, V.V.; Sumin, V.V.; )

1997-01-01

The FCC-lattice of the solid solution α-MnH 0.073 with the mass of 8.45 g is investigated by the neutron diffraction method and the inelastic neutron scattering technique. The neutron diffraction measurements are made by the diffractometer D1B with pyrographite monochromator and the high-resolution Fourier diffractometer HRFD at 300 K. The study of the inelastic incoherent neutron scattering is carried out by means of the inverse geometry spectrometer KDSOG-M at 90 K. The comparative analysis of α-MnH 0.073 and α-Mn spectra is fulfilled for the more correct separation of effects of hydrogen introduction. It is found out that the structure of the solid solution α-MnH 0.073 belongs to the same spatial group I-43m as the structure of α-Mn [ru

Study of FeC1{sub 2} by neutron diffraction; Etude de Fe C1{sub 2} par diffraction de neutrons

Energy Technology Data Exchange (ETDEWEB)

Herpin, A; Meriel, P [Commissariat a l' Energie Atomique, Saclay (France)

1959-07-01

Magnetic measurements have shown that anhydrous ferrous chloride behaves as a metamagnetic at temperatures below 24 deg. K, in other words as an antiferromagnetic sensitive to the action of an external field of moderate strength. The aim of the neutron diffraction study is to determine precisely the arrangement of the magnetic moments, and to follow its evolution as a function of the applied field. (author) [French] Des mesures magnetiques ont montre que le chlorure ferreux anhydre se comporte comme un metamagnetique a une temperature inferieure a 24 deg. K, c'est a dire comme un antiferromagnetique sensible a l'action d'un champ exterieur modere. L'etude par diffraction de neutrons a pour buts de preciser la disposition des moments magnetiques et de suivre son evolution en fonction du champ applique. (auteur)

Investigation of Acrylic Acid at High Pressure using Neutron Diffraction

DEFF Research Database (Denmark)

Johnston, Blair F.; Marshall, William G.; Parsons, Simon

2014-01-01

This article details the exploration of perdeuterated acrylic acid at high pressure using neutron diffraction. The structural changes that occur in acrylic acid-d4 are followed via diffraction and rationalised using the Pixel method. Acrylic acid undergoes a reconstructive phase transition to a new...

Powder Neutron Diffraction and Magnetic structures

International Nuclear Information System (INIS)

Vigneron, F.

1986-01-01

The determination of the magnetic structures of materials (ferromagnetic, antiferromagnetic, helimagnetic, .) can be achieved only by neutron diffraction. A general survey of the powder technique is given: 2-axis spectrometer and analysis of the magnetic data. For the REBe/sb13/ intermetallic compounds (RE = Rare Earth), commensurate and/or incommensurate magnetic structures are observed and discussed as a function of RE (Gd, Tb, Dy, Ho, Er)

Neutron diffraction experiments on ordered silver nuclei at Picokelvin temperatures

International Nuclear Information System (INIS)

Annila, A.J.; Hakonen, P.J.; Lounasmaa, O.V.; Nummila, K.K.; Oja, A.S.; Tuoriniemi, J.T.; Clausen, K.N.; Lindgaard, P.-A.; Siemensmeyer, K.; Steiner, M.; Weinfurter, H.; Viertioe, H.E.

1990-08-01

Nuclear spins in silver constitute an ideal antiferromagnetic spin - 1/2 model system in an fcc lattice. The nuclei are well localized and the interactions coupling the spins can be calculated from first principles. Strong quantum effects are expected owing to spin - 1/2. The magnetic phase diagram of the system has been investigated by several theoretical methods. In the present study the feasibility of neutron diffraction experiments on nuclear magnetic order in silver is discussed. The requirements for cryogenics and for neutron equipment are based on experience with current NMR measurements on sivler and with neutron diffraction work on copper. It is concluded that an experiment using an isotopically enriched specimen of either 107 Ag or 109 Ag is feasible but difficult. (author) 1 tab., 16 ills., 38 refs

Neutron diffraction tomography: a unique, 3D inspection technique for crystals using an intensifier TV system

International Nuclear Information System (INIS)

Davidson, J.B.; Case, A.L.

1978-01-01

The application of phosphor-intensifier-TV techniques to neutron topography and tomography of crystals is described. The older, analogous x-ray topography using wavelengths approximately 1.5A is widely used for surface inspection. However, the crystal must actually be cut in order to see diffraction anomalies beneath the surface. Because 1.5-A thermal neutrons are highly penetrating, much larger and thicker specimens can be used. Also, since neutrons have magnetic moments, they are diffracted by magnetic structures within crystals. In neutron volume topography, the entire crystal or a large part of it is irradiated, and the images obtained are superimposed reflections from the total volume. In neutron tomography (or section topography), a collimated beam irradiates a slice (0.5 to 10 mm) of the crystal. The diffracted image is a tomogram from this part only. A series of tomograms covering the crystal can be taken as the specimen is translated in steps across the narrow beam. Grains, voids, twinning, and other defects from regions down to 1 mm in size can be observed and isolated. Although at present poorer in resolution than the original neutron and film methods, the TV techniques are much faster and, in some cases, permit real-time viewing. Two camera systems are described: a counting camera having a 150 mm 6 Li-ZnS screen for low-intensity reflections which are integrated in a digital memory, and a 300-mm system using analog image storage. Topographs and tomograms of several crystals ranging in size from 4 mm to 80 mm are shown

Study of FeC1{sub 2} by neutron diffraction; Etude de Fe C1{sub 2} par diffraction de neutrons

Energy Technology Data Exchange (ETDEWEB)

Herpin, A.; Meriel, P. [Commissariat a l' Energie Atomique, Saclay (France)

1959-07-01

Magnetic measurements have shown that anhydrous ferrous chloride behaves as a metamagnetic at temperatures below 24 deg. K, in other words as an antiferromagnetic sensitive to the action of an external field of moderate strength. The aim of the neutron diffraction study is to determine precisely the arrangement of the magnetic moments, and to follow its evolution as a function of the applied field. (author) [French] Des mesures magnetiques ont montre que le chlorure ferreux anhydre se comporte comme un metamagnetique a une temperature inferieure a 24 deg. K, c'est a dire comme un antiferromagnetique sensible a l'action d'un champ exterieur modere. L'etude par diffraction de neutrons a pour buts de preciser la disposition des moments magnetiques et de suivre son evolution en fonction du champ applique. (auteur)

Non-destructive bulk analysis of the Buggenum sword by neutron resonance capture analysis and neutron diffraction

International Nuclear Information System (INIS)

Postma, H.; Clarijs, M.; Borella, A.; Schillebeeckx, P.; Kamermans, H.

2010-01-01

Two neutron based techniques, neutron resonance capture analysis (NRCA) and time-of-flight neutron-diffraction (TOF-ND) have been used to determine the elemental composition and structure of a precious and very well preserved all-metal sword from the Bronze Age. This Buggenum sword was on loan from the National Museum of Antiquities (NMA) in Leiden (NL). NRCA and TOF-ND experiments have been carried out at a number of more or less identical positions of the sword. The tin-bronze ratio and the relative amounts of some minor elements (Sb, As, Ag, In) have been determined. The results of neutron diffraction measurements showed considerable tin-segregation, and clear indications of hardening on the edges of the blade. In addition, radiographs using Bremsstrahlung revealed the construction of the hilt-blade connection. The work was carried out at the EC Joint Research Centre IRMM in Geel (B) and at the ISIS facility of the Rutherford Appleton Laboratory (UK). (author)

Applications of thermal neutron scattering in biology, biochemistry and biophysics

International Nuclear Information System (INIS)

Worcester, D.L.

1977-01-01

Biological applications of thermal neutron scattering have increased rapidly in recent years. The following categories of biological research with thermal neutron scattering are presently identified: crystallography of biological molecules; neutron small-angle scattering of biological molecules in solution (these studies have already included numerous measurements of proteins, lippoproteins, viruses, ribosomal subunits and chromatin subunit particles); neutron small-angle diffraction and scattering from biological membranes and membrane components; and neutron quasielastic and inelastic scattering studies of the dynamic properties of biological molecules and materials. (author)

Structure of amorphous selenium studied by neutron diffraction

DEFF Research Database (Denmark)

Hansen, Flemming Yssing; Knudsen, Torben Steen; Carneiro, K.

1975-01-01

Neutron diffraction measurements on amorphous selenium have been performed at 293 and 80 K. Careful analyses of the instrumental corrections were made to avoid systematic errors in the measured structure factor S (kappa) in the wave vector region 0 ? kappa ? 12 Å−1. As a result of the data...... treatment, the neutron scattering cross sections of selenium are determined to be sigmacoh = 8.4±0.1 b and sigmainc = 0.1±0.1 b. Using the fact that S (kappa) for large kappa's is determined by the short distances in the sample, a new method for extrapolation of the experimental S (kappa) until convergence....... Finally, we give a brief discussion of the different models for the structure of amorphous selenium, taking both diffraction measurements and thermodynamic considerations into account. The Journal of Chemical Physics is copyrighted by The American Institute of Physics....

Historical review of neutron spectrometry and diffraction in Brazil - 50 years

International Nuclear Information System (INIS)

Voi, Dante L.; Ferreira, Francisco J.O.; Stasiulevicius, Roberto; Rodrigues, Claudio; Parente, Carlos B.R.; Mazzocchi, Vera L.; Mestnik Filho, Jose; Pugliesi, Reinaldo

2011-01-01

Neutron Spectrometry and Diffraction techniques began to be studied in Brazil with the construction of the first research reactors in the years 50 and 60, and were developed with the participation of national and international scientists. In particular, we note the perseverance of the Brazilian pioneer of nuclear energy, Dr. Marcello Damy de Souza Santos, and from that time, with the involvement of some of the early pioneers, such as the physicist Roberto Stasiulevicius, who had the privilege of working in all three Brazilian nuclear research reactors. All these scientists shared half a century of acquired knowledge, helping in the training of a number of experts who are now working in national and international nuclear institutes. The present work reviews in chronological order, the testimony of the historical facts associated with the development and application of experimental techniques using neutrons as a tool for materials analysis and studies for many areas of the sciences and also with the training of personnel. IPEN, IEN and CDTN, all institutes of the CNEN-Brazil, are important in the national and international scene as a result of the research carried out there and the large number of publications produced in the field of neutron spectrometry and diffraction from experimental work carried out using the IEA (5MW), Argonauta (5kW) and more recently, the IPR (250kW) research reactors. An extensive bibliography is also presented and this can be disseminated to everyone interested. (author)

Dynamic theory of neutron diffraction from a moving grating

Energy Technology Data Exchange (ETDEWEB)

Bushuev, V. A., E-mail: vabushuev@yandex.ru [Moscow State University (Russian Federation); Frank, A. I.; Kulin, G. V. [Joint Institute for Nuclear Research (Russian Federation)

2016-01-15

A multiwave dynamic theory of diffraction of ultracold neutrons from a moving phase grating has been developed in the approximation of coupled slowly varying amplitudes of wavefunctions. The effect of the velocity, period, and height of grooves of the grating, as well as the spectral angular distribution of the intensity of incident neurons, on the discrete energy spectrum and the intensity of diffraction reflections of various orders has been analyzed.

Diffraction and single-crystal elastic constants of Inconel 625 at room and elevated temperatures determined by neutron diffraction

International Nuclear Information System (INIS)

Wang, Zhuqing; Stoica, Alexandru D.; Ma, Dong; Beese, Allison M.

2016-01-01

In this work, diffraction and single-crystal elastic constants of Inconel 625 have been determined by means of in situ loading at room and elevated temperatures using time-of-flight neutron diffraction. Theoretical models proposed by Voigt, Reuss, and Kroner were used to determine single-crystal elastic constants from measured diffraction elastic constants, with the Kroner model having the best ability to capture experimental data. The magnitude of single-crystal elastic moduli, computed from single-crystal elastic constants, decreases and the single crystal anisotropy increases as temperature increases, indicating the importance of texture in affecting macroscopic stress at elevated temperatures. The experimental data reported here are of great importance in understanding additive manufacturing of metallic components as: diffraction elastic constants are required for computing residual stresses from residual lattice strains measured using neutron diffraction, which can be used to validate thermomechanical models of additive manufacturing, while single-crystal elastic constants can be used in crystal plasticity modeling, for example, to understand mechanical deformation behavior of additively manufactured components.

Diffraction and single-crystal elastic constants of Inconel 625 at room and elevated temperatures determined by neutron diffraction

Energy Technology Data Exchange (ETDEWEB)

Wang, Zhuqing [Department of Materials Science and Engineering, Pennsylvania State University, University Park, PA 16802 (United States); Stoica, Alexandru D. [Chemical and Engineering Materials Division, Neutron Sciences Directorate, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Ma, Dong, E-mail: dongma@ornl.gov [Chemical and Engineering Materials Division, Neutron Sciences Directorate, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Beese, Allison M., E-mail: amb961@psu.edu [Department of Materials Science and Engineering, Pennsylvania State University, University Park, PA 16802 (United States)

2016-09-30

In this work, diffraction and single-crystal elastic constants of Inconel 625 have been determined by means of in situ loading at room and elevated temperatures using time-of-flight neutron diffraction. Theoretical models proposed by Voigt, Reuss, and Kroner were used to determine single-crystal elastic constants from measured diffraction elastic constants, with the Kroner model having the best ability to capture experimental data. The magnitude of single-crystal elastic moduli, computed from single-crystal elastic constants, decreases and the single crystal anisotropy increases as temperature increases, indicating the importance of texture in affecting macroscopic stress at elevated temperatures. The experimental data reported here are of great importance in understanding additive manufacturing of metallic components as: diffraction elastic constants are required for computing residual stresses from residual lattice strains measured using neutron diffraction, which can be used to validate thermomechanical models of additive manufacturing, while single-crystal elastic constants can be used in crystal plasticity modeling, for example, to understand mechanical deformation behavior of additively manufactured components.

Internal strain measurement using pulsed neutron diffraction at LANSCE

International Nuclear Information System (INIS)

Goldstone, J.A.; Bourke, M.A.M.; Shi, N.

1994-01-01

The presence of residual stress in engineering components can effect their mechanical properties and structural integrity. Neutron diffraction in the only technique that can make nondestructive measurements in the interior of components. By recording the change in crystalline lattice spacings, elastic strains can be measured for individual lattice reflections. Using a pulsed neutron source, all lattice reflections are recorded in each measurement, which allows for easy examination of heterogeneous materials such as metal matrix composites. Measurements made at the Manuel Lujan Jr. Neutron Scattering Center (LANSCE) demonstrate the potential at pulsed sources for in-situ stress measurements at ambient and elevated temperatures

Fabrication of vanadium cans for neutron diffraction experiments

Energy Technology Data Exchange (ETDEWEB)

Chung, Chin man; Baik, Sung Hoon; Park, Sun Kyu

1999-12-01

The laser weld technique of vanadium developed to experiment for neutron diffraction of HANARO. The demands for this laser welding technique were applied to process control in vanadium film welding and to fabricate various sizing vanadium cans. The vanadium can had a advantage to have less coherent in neutron. KAERI developed the fabrication jig of 6-12 mm diameter cans using 0.125 mm vanadium thin film, and investigated the laser welding procedure for making the various diameter and length of vanadium cans using the fabricated jigs and Nd:YAG laser. (author)

Polarised neutron diffraction studies on weak ferromagnetism - a survey

International Nuclear Information System (INIS)

Radhakrishna, P.

1982-10-01

The physical basis of the phenomenon of weak ferromagnetism in certain antiferromagnetic insulators is briefly discussed. A survey of the contributions of polarised neutron diffraction towards the elucidation of different aspects of this field is presented

Magnetostructural transition in Fe5SiB2 observed with neutron diffraction

Czech Academy of Sciences Publication Activity Database

Cedervall, J.; Kontos, S.; Hansen, T. C.; Balmes, O.; Martinez-Casado, F. J.; Matěj, Z.; Beran, Přemysl; Svedlindh, P.; Gunnarsson, K.; Sahlberg, M.

2016-01-01

Roč. 235, MAR (2016), s. 113-118 ISSN 0022-4596 Institutional support: RVO:61389005 Keywords : magnetism * X-ray diffraction * neutron diffraction Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.299, year: 2016

Residual stress in sprayed Ni+5%Al coatings determined by neutron diffraction

CERN Document Server

Matejicek, J; Gnaeupel-Herold, T; Prask, H J

2002-01-01

Coatings of nickel-based alloys are used in numerous high-performance applications. Their properties and lifetimes are influenced by factors such as residual stress. Neutron diffraction is a powerful tool for nondestructive residual stress determination. In this study, through-thickness residual stress profiles in Ni+5%Al coatings on steel substrates were determined. Two examples of significantly different spraying techniques - plasma spraying and cold spraying - are highlighted. Different stress-generation mechanisms are discussed with respect to process parameters and material properties. (orig.)

40-Tesla pulsed-field cryomagnet for single crystal neutron diffraction

Science.gov (United States)

Duc, F.; Tonon, X.; Billette, J.; Rollet, B.; Knafo, W.; Bourdarot, F.; Béard, J.; Mantegazza, F.; Longuet, B.; Lorenzo, J. E.; Lelièvre-Berna, E.; Frings, P.; Regnault, L.-P.

2018-05-01

We present the first long-duration and high duty cycle 40-T pulsed-field cryomagnet addressed to single crystal neutron diffraction experiments at temperatures down to 2 K. The magnet produces a horizontal field in a bi-conical geometry, ±15° and ±30° upstream and downstream of the sample, respectively. Using a 1.15 MJ mobile generator, magnetic field pulses of 100 ms length are generated in the magnet, with a rise time of 23 ms and a repetition rate of 6-7 pulses per hour at 40 T. The setup was validated for neutron diffraction on the CEA-CRG three-axis spectrometer IN22 at the Institut Laue Langevin.

Diffraction. Single crystal, magnetic

International Nuclear Information System (INIS)

Heger, G.

1999-01-01

The analysis of crystal structure and magnetic ordering is usually based on diffraction phenomena caused by the interaction of matter with X-rays, neutrons, or electrons. Complementary information is achieved due to the different character of X-rays, neutrons and electrons, and hence their different interactions with matter and further practical aspects. X-ray diffraction using conventional laboratory equipment and/or synchrotron installations is the most important method for structure analyses. The purpose of this paper is to discuss special cases, for which, in addition to this indispensable part, neutrons are required to solve structural problems. Even though the huge intensity of modern synchrotron sources allows in principle the study of magnetic X-ray scattering the investigation of magnetic structures is still one of the most important applications of neutron diffraction. (K.A.)

Preferred orientations in niobium determined by neutrons diffraction

International Nuclear Information System (INIS)

Ueno, S.I.N.

1979-01-01

Neutron diffraction has been utilized to study textures developed in polycrystalline niobium, cold rolled to 60%, 80% and 95% in tickness and cold rolled to 95% in thickness and annealed at 800 0 C for 15, 30, 60 and 120 minutes in a vacuum of 10 -4 TORR [pt

Magnetic structures: neutron diffraction studies

International Nuclear Information System (INIS)

Bouree-Vigneron, F.

1990-01-01

Neutron diffraction is often an unequivocal method for determining magnetic structures. Here we present some typical examples, stressing the sequence through experiments, data analysis, interpretation and modelisation. Two series of compounds are chosen: Tb Ni 2 Ge 2 and RBe 13 (R = Gd, Tb, Dy, Ho, Er). Depending on the nature of the elements, the magnetic structures produced can be commensurate, incommensurate or even show a transition between two such phases as a function of temperature. A model, taking magnetic exchange and anisotropy into account, will be presented in the case of commensurate-incommensurate magnetic transitions in RBe 13

Characterization of a polychromatic neutron beam diffracted by pyrolytic graphite crystals

CERN Document Server

Byun, S H; Choi, H D

2002-01-01

The beam spectrum for polychromatic neutrons diffracted by pyrolytic graphite crystals was characterized. The theoretical beam spectrum was obtained using the diffraction model for a mosaic crystal. The lattice vibration effects were included in the calculation using the reported vibration amplitude of the crystal and the measured time-of-flight spectra in the thermal region. The calculated beam spectrum was compared with the results obtained in the absence of thermal motion. The lattice vibration effects became more important for the higher diffraction orders and a large decrease in the neutron flux induced by the vibrations was identified in the epithermal region. The validity of the beam spectrum was estimated by comparing with the effective quantities determined from prompt gamma-ray measurements and Cd-ratios measured both for 1/nu and non-1/nu nuclides.

The measurement of internal stress fields in weldments and around cracks using high resolution neutron diffraction

International Nuclear Information System (INIS)

Allen, A.J.; Hutchings, M.T.; Windsor, C.G.

1987-01-01

The paper describes and illustrates the capability of neutron diffraction to measure the complete internal lattice macrostrain field, and hence the stress field, within steel components and weldments arising from their fabrication. A brief outline is given of the theory of the neutron method. The experimental considerations are discussed. The method is illustrated by its application to the measurement of the stress distribution in a:- uniaxially stressed mild steel rod, a double - V test weld, a tube-plate weld, and a cracked fatigue test specimen. (U.K.)

High resolution Neutron and Synchrotron Powder Diffraction

International Nuclear Information System (INIS)

Hewat, A.W.

1986-01-01

The use of high-resolution powder diffraction has grown rapidly in the past years, with the development of Rietveld (1967) methods of data analysis and new high-resolution diffractometers and multidetectors. The number of publications in this area has increased from a handful per year until 1973 to 150 per year in 1984, with a ten-year total of over 1000. These papers cover a wide area of solid state-chemistry, physics and materials science, and have been grouped under 20 subject headings, ranging from catalysts to zeolites, and from battery electrode materials to pre-stressed superconducting wires. In 1985 two new high-resolution diffractometers are being commissioned, one at the SNS laboratory near Oxford, and one at the ILL in Grenoble. In different ways these machines represent perhaps the ultimate that can be achieved with neutrons and will permit refinement of complex structures with about 250 parameters and unit cell volumes of about 2500 Angstrom/sp3/. The new European Synchotron Facility will complement the Grenoble neutron diffractometers, and extend the role of high-resolution powder diffraction to the direct solution of crystal structures, pioneered in Sweden

XRD and neutron diffraction analyses of heat treated U-Mo/Al dispersion fuel

Energy Technology Data Exchange (ETDEWEB)

Nam, Ji Min; Kim, Woo Jeong; Ryu, Ho Jin; Lee, Kyu Hong; Park, Jong Man [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2012-10-15

High density U Mo alloys are regarded as promising candidates for advanced research reactor fuel because they have shown stable irradiation performance when compared to other uranium alloys and compounds. However, interaction layer formation between the U Mo alloys and Al matrix degrades the irradiation performance of U Mo dispersion fuel. Therefore, addition of Ti in U Mo alloys, addition of Si in Al matrix and silicide or nitride coating on the surface of U Mo particles have been proposed in order to inhibit the interaction layer growth. In order to analyze the mechanisms of interaction layer growth inhibition by adding Ti in U Mo alloys or Si in Al matrix, accurate phase characterization of the interaction layers is required. While previous studies using X ray diffraction have been reported, laboratory X ray diffraction method has limitations such as low resolution and small measurement volume. Neutron diffraction method can be a more accurate analysis when compared with X ray diffraction method due to the large penetration depth of neutron. In this study, X ray diffraction and neutron diffraction experiments have been performed by using the laboratory X ray diffractometer and high resolution powder diffractometer (HRPD) of the HANARO research reactor in KAERI.

Crystal structure solution of hydrides containing natEu from neutron powder diffraction data

International Nuclear Information System (INIS)

Kohlmann, H.

1999-01-01

Complete text of publication follows. The location of hydrogen in crystal structures of metal hydrides usually requires neutron diffraction data. Some elements, however, show excessively high absorption cross sections, σ a , for neutrons, thus making this technique seemingly impractical. Therefore no complete, refined crystal structure data of europium hydrides (σ a ( nat Eu) = .4530 barns at λ = 179.8 pm [1]) have been reported so far. It is shown that the absorption can be reduced to a value reasonable for neutron diffraction experiments by taking advantage of the wavelength dependence of σ a combined with the use of annular samples at advanced diffractometers. Neutron powder diffraction data on several nat Eu containing deuterides suitable for the ab initio crystal structure solution and refinement have been taken at D20 and D4 (ILL, Grenoble). The crystal chemistry of these europium hydrides, among them the two new compounds EuMg 2 H 6 and EuMgH 4 [2], is discussed. (author) [1] V.F. Sears, Neutron News 1992, 3, 26-37.; [2] H. Kohlmann, F. Gingl, T. Hansen, K. Yvon, Angew. Chem. Int. Ed. Eng. 1999, 38, accepted

Neutron diffraction studies of magnetic materials

International Nuclear Information System (INIS)

James, W.J.

1987-01-01

The ability of neutron diffraction in determining the nature and extent of magnetic ordering is illustrated for the intermetallic compounds, Y/sub 6/(Fe,Mn)/sub 23/ and ErFe/sub 3/. Substitution with other 3d transition metals influences the Fe-Fe exchange forces such as to alter, sometimes considerably, the magnetic properties, e.g., local site magnetic anisotropies in Er)Fe,Ni)/sub 3/ and thermal expansion anomalies in the R/sub 2/)Fe,Co)/sub 14/B compounds. When the 3d atoms are near neighbors in the periodic chart, their nuclear scattering lengths for neutrons are sufficiently different to permit the detection of preferential occupation of the several nonequivalent crystallographic 3d metal sites, i.e., atomic ordering, present in the R/sub 6/M/sub 23/, and R/sub 2/Fe/sub 14/B structures

Residual stress measurements by X-ray and neutron diffractions in heat-treated SiCw/A2014 composites

International Nuclear Information System (INIS)

Ohnuki, Takahisa; Fujita, Motoo; Tomota, Yo; Ono, Masayoshi

1998-01-01

Residual stresses due to various heat treatments in a 22 volume percent SiC whisker/A2014 metal matrix composite (MMC) were measured by using X-ray and neutron diffractions. Micro residual stresses generated from the differences in thermal expansion coefficients of the constituents and macro residual stresses associated with different cooling rates in the outer and inner regions of an MMC specimen must be distinguished in X-ray stress measurements. The conventional sin 2 ψ method under an assumption of plane stress condition has been found not to be applicable to the present MMC, because interactions among whiskers in the X-ray penetrating area yields σ 33 where the x 3 -axis is normal with respect to specimen's surface. An average value of σ 33 can be measured by X-ray diffraction technique, but does not seem enough to evaluate micro residual stresses. It is found that neutron diffraction is the most powerful method to measure micro residual stresses in the constituents. Elastic residual strains obtained by neutron diffraction in solution treated or T6 heat treated samples show good agreements with predictions calculated by using Eshelby inclusion theory coupled with the Mori-Tanaka mean field concept, indicating that the influence of stress relaxation is negligible. In addition, internal stresses relaxations during holding at room temperature, slow cooling from solution treatment temperature, or subzero cooling are discussed. (author)

Neutron diffraction utilizing the T-O-F method

Energy Technology Data Exchange (ETDEWEB)

Niimura, N [Tohoku Univ., Sendai (Japan). Lab. of Nuclear Science

1974-12-01

Characteristic features of the TOF (time of flight) neutron diffraction are summarized. In this method, i) all the reciprocal points on the rod passing through the origin in the reciprocal space can be scanned by each burst of white neutrons, ii) it is easy to measure high index reflections at the large scattering angle, iii) each reflection is not affected by the higher-order harmonics, and iv) it is easy to measure the physical properties depending on the neutron wavelength. The pulse neutron generator as well as the data acquisition system in the Laboratory of Nuclear Science of Tohoku University is described. The TOF method seems to be very powerful if it is applied to accurate structure analysis. The data correction methods are discussed. The TOF method is prospective to the study of transient phenomena. In this method one can apply to the crystalline sample an external field pulsed with the same frequency as the neutrons. By using this method, the transient state of the polarization reversal of the ferroelectric NaNO/sub 2/ has been observed. The magnetically pulsed neutron TOF spectrometer is briefly introduced after a review of the chopper history.

Crystallization of porcine pancreatic elastase and a preliminary neutron diffraction experiment

Energy Technology Data Exchange (ETDEWEB)

Kinoshita, Takayoshi [Department of Biological Science, Graduate School of Science, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531 (Japan); Tamada, Taro [Molecular Structural Biology Group, Quantum Beam Science Directorate, Japan Atomic Energy Agency, 2-4 Shirakata-Shirane, Tokai, Ibaraki 319-1195 (Japan); Imai, Keisuke [Lead Discovery Research Laboratories, Astellas Pharma Inc., 21 Miyukigaoka, Tsukuba-shi, Ibaraki 305-8585 (Japan); Kurihara, Kazuo; Ohhara, Takashi [Molecular Structural Biology Group, Quantum Beam Science Directorate, Japan Atomic Energy Agency, 2-4 Shirakata-Shirane, Tokai, Ibaraki 319-1195 (Japan); Tada, Toshiji [Department of Biological Science, Graduate School of Science, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531 (Japan); Kuroki, Ryota, E-mail: kuroki.ryota@jaea.go.jp [Molecular Structural Biology Group, Quantum Beam Science Directorate, Japan Atomic Energy Agency, 2-4 Shirakata-Shirane, Tokai, Ibaraki 319-1195 (Japan); Department of Biological Science, Graduate School of Science, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531 (Japan)

2007-04-01

To investigate the structural characteristics of a covalent inhibitor bound to porcine pancreatic elastase (PPE), including H atoms and hydration by water, a crystal of porcine pancreatic elastase with its inhibitor was grown to a size of 1.6 mm{sup 3} for neutron diffraction study. The crystal diffracted to 2.3 Å resolution with sufficient quality for further structure determination owing to the similar atomic scattering properties of deuterium and carbon. Porcine pancreatic elastase (PPE) resembles the attractive drug target leukocyte elastase, which has been implicated in a number of inflammatory disorders. In order to investigate the structural characteristics of a covalent inhibitor bound to PPE, including H atoms and the hydration by water, a single crystal of PPE for neutron diffraction study was grown in D{sub 2}O containing 0.2 M sodium sulfate (pD 5.0) using the sitting-drop vapour-diffusion method. The crystal was grown to a size of 1.6 mm{sup 3} by repeated macroseeding. Neutron diffraction data were collected at room temperature using a BIX-3 diffractometer at the JRR-3 research reactor of the Japan Atomic Energy Agency (JAEA). The data set was integrated and scaled to 2.3 Å resolution in space group P2{sub 1}2{sub 1}2{sub 1}, with unit-cell parameters a = 51.2, b = 57.8, c = 75.6 Å.

High-resolution neutron-diffraction measurements to 8 kbar

Science.gov (United States)

Bull, C. L.; Fortes, A. D.; Ridley, C. J.; Wood, I. G.; Dobson, D. P.; Funnell, N. P.; Gibbs, A. S.; Goodway, C. M.; Sadykov, R.; Knight, K. S.

2017-10-01

We describe the capability to measure high-resolution neutron powder diffraction data to a pressure of at least 8 kbar. We have used the HRPD instrument at the ISIS neutron source and a piston-cylinder design of pressure cell machined from a null-scattering titanium zirconium alloy. Data were collected under hydrostatic conditions from an elpasolite perovskite La?NiMnO?; by virtue of a thinner cell wall on the incident-beam side of the cell, it was possible to obtain data in the instrument's highest resolution back-scattering detector banks up to a maximum pressure of 8.5 kbar.

On the neutron diffraction in a crystal in the field of a standing laser wave

International Nuclear Information System (INIS)

Grigoryan, K.K.; Hayrapetyan, A.G.; Petrosyan, R.G.

2010-01-01

The possibility of high-energy neutron diffraction in a crystal is shown by applying the solution of time-dependent Schroedinger equation for a neutron in the field of a standing laser wave. The scattering picture is examined within the framework of non-stationary S-matrix theory, where the neutron-laser field interaction is considered exactly and the neutron-crystal interaction is considered as a perturbation described by Fermi pseudopotential (Farri representation). The neutron-crystal interaction is elastic, and the neutron-laser field interaction has both inelastic and elastic behaviors which results in the observation of an analogous to the Kapitza-Dirac effect for neutrons. The neutron scattering probability is calculated and the analysis of the results are adduced. Both inelastic and elastic diffraction conditions are obtained and the formation of a 'sublattice' is illustrated in the process of neutron-photon-phonon elastic interaction.

Profile analysis of neutron powder diffraction data at ISIS

International Nuclear Information System (INIS)

David, W.I.F.; Ibberson, R.M.; Matthewman, J.C.

1992-05-01

The aim of this manual is to document the current suite of time-of-flight neutron powder diffraction profile refinement programs available to ISIS users. Aspects of data collation and normalisation specific to the individual diffraction instruments are dealt with elsewhere. It will be assumed the user has produced a suitable data file (.DAT file) containing the profile data consisting of point by point values of the corrected diffraction profile across the pattern. The analysis of neutron powder diffraction data at ISIS by profile refinement utilises a suite of ''in-house'' written and supported programs based on the Cambridge Crystallography Subroutine Library (CCSL). A quick scan through the CCSL manual will give the user a general feel for the procedure to adopt in the use of the library and hence of the profile codes. The instructions documented in this handbook are complementary to those in the more specialist CCSL manual, and consequently go into no great detail regarding technical details of any of the CCSL routines. The programs may be run from each individual user account, for example [USER01], once the appropriate login procedure has been set-up by the instrument scientists. The programs are mostly activated by one line commands and only a basic knowledge of a VAX editor should be required; details can be found in the ''VAX primer'' available from Computer Support. (Author)

Six-axis multi-anvil press for high-pressure, high-temperature neutron diffraction experiments

Energy Technology Data Exchange (ETDEWEB)

Sano-Furukawa, A., E-mail: sano.asami@jaea.go.jp; Hattori, T. [Quantum Beam Science Center, Japan Atomic Energy Agency, Ibaraki 319-1195 (Japan); J-PARC Center, Japan Atomic Energy Agency, Ibaraki 319-1195 (Japan); Arima, H. [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Yamada, A. [The University of Shiga Prefecture, Shiga 522-8533 (Japan); Tabata, S.; Kondo, M.; Nakamura, A. [Sumitomo Heavy Industries Co., Ltd., Ehime 792-0001 (Japan); Kagi, H.; Yagi, T. [Geochemical Research Center, Graduate School of Science, The University of Tokyo, Tokyo 113-0033 (Japan)

2014-11-15

We developed a six-axis multi-anvil press, ATSUHIME, for high-pressure and high-temperature in situ time-of-flight neutron powder diffraction experiments. The press has six orthogonally oriented hydraulic rams that operate individually to compress a cubic sample assembly. Experiments indicate that the press can generate pressures up to 9.3 GPa and temperatures up to 2000 K using a 6-6-type cell assembly, with available sample volume of about 50 mm{sup 3}. Using a 6-8-type cell assembly, the available conditions expand to 16 GPa and 1273 K. Because the six-axis press has no guide blocks, there is sufficient space around the sample to use the aperture for diffraction and place an incident slit, radial collimators, and a neutron imaging camera close to the sample. Combination of the six-axis press and the collimation devices realized high-quality diffraction pattern with no contamination from the heater or the sample container surrounding the sample. This press constitutes a new tool for using neutron diffraction to study the structures of crystals and liquids under high pressures and temperatures.

Physical methods for studying minerals and solid materials: X-ray, electron and neutron diffraction; scanning and transmission electron microscopy; X-ray, electron and ion spectrometry

International Nuclear Information System (INIS)

Eberhart, J.-P.

1976-01-01

The following topics are discussed: theoretical aspects of radiation-matter interactions; production and measurement of radiations (X rays, electrons, neutrons); applications of radiation interactions to the study of crystalline materials. The following techniques are presented: X-ray and neutron diffraction, electron microscopy, electron diffraction, X-ray fluorescence analysis, electron probe microanalysis, surface analysis by electron emission spectrometry (ESCA and Auger electrons), scanning electron microscopy, secondary ion emission analysis [fr

Molecular structure and correlations in liquid D-2-propanol through neutron diffraction

International Nuclear Information System (INIS)

Sahoo, A.; Sarkar, S.; Joarder, R.N.; Krishna, P.S.R.

2003-01-01

Like t-butanol, 2-propanol molecules are quite big with substantial amount of asymmetry in the structure and so the analysis of the neutron diffraction data is tricky. A modified method of analysis, similar to one for liquid t-butanol, enables extraction of the detailed molecular conformation and intermolecular correlations through neutron diffraction. The pre-peak in the structure function, a signature of chain molecular association together with partially identified inter-molecular correlations yield some information about the nature of possible H-bonded molecular clusters in the liquid state. (author)

Neutron diffraction on a large block mosaic crystal

International Nuclear Information System (INIS)

Kim Chir Sen; Nitts, V.V.

1985-01-01

The neutron diffraction by the mosaic single crystal with size of crystallites sufficient to achieve the primary extinction saturation is considered. Two cases where the proportionality between the reflection intensity and the structure amplitude is performed are analysed. Such a dependence is convenient for structure investigations. The difficulties connected with the accounting of the extinction are eliminated considerably

Fly's Eye: a counting camera for thermal neutrons, some applications, problems, and prospects

International Nuclear Information System (INIS)

Davidson, J.B.

1975-01-01

An area detector for thermal neutrons based on image intensification techniques is described and some capabilities and limitations of the detection system are discussed. Among the former are high spatial resolution high instantaneous counting rate, electronic zoom, time-gating, and integration. The detector is limited in that the maximum counting rate for a resolution element is 60 regularly spaced counts per second. Also, the nonuniformity of response over the detector limits the useful size and requires point-by-point calibration. In addition, a higher efficiency for neutron detection would be desirable. Some typical applications of the system are: crystal inspection, neutron magnetic diffraction topography, and searches for temperature induced changes in diffraction patterns. The future application of solid state television sensors and microchannel plate intensifiers to improve the system are briefly mentioned. (U.S.)

Fly's eye: a counting camera for thermal neutrons: some applications, problems, and prospects

International Nuclear Information System (INIS)

Davidson, J.B.

1976-01-01

An area detector for thermal neutrons based on image intensification techniques is described. Some capabilities and limitations of the detection system are discussed. Among the former are high spatial resolution, high instantaneous counting rate, electronic zoom, time-gating, and integration. The detector is limited in that the maximum counting rate for a resolution element is 60 regularly spaced counts per second. Also, the nonuniformity of response over the detector puts a limit on the useful size and necessitates point-by-point calibration. In addition, a higher efficiency for neutron detection would be desirable. Some typical applications of the system are crystal inspection, neutron magnetic diffraction topography, and searches for temperature-induced changes in diffraction patterns. The future application of solid-state television sensors and microchannel-plate intensifiers to improve the system is briefly mentioned

Residual stress measurements by means of neutron diffraction

International Nuclear Information System (INIS)

Pintschovius, L.; Jung, V.; Macherauch, E.; Voehringer, O.

1983-01-01

A new method for the analysis of multiaxial residual stress states is presented, which is based on high resolution neutron diffraction. It is analogous to X-ray stress analysis, but the use of neutrons instead of X-rays allows the analysis of the stress distributions also in the interior of technical components in a non-destructive way. To prove the feasibility of the method, investigations of the loading stress distributions of an aluminium bar subjected to purely elastic bending were performed. Limiting factors due to the volume of the internal probe region and the sample thickness are discussed. Complete neutron residual stress analyses were carried out for a plastically deformed bending bar and a transformation-free water-quenched steel cylinder. The results are in fairly good agreement with theoretical expectations and with X-ray control measurements at the surface of the objects. (Auth.)

A preliminary neutron diffraction study of rasburicase, a recombinant urate oxidase enzyme, complexed with 8-azaxanthin

Energy Technology Data Exchange (ETDEWEB)

Budayova-Spano, Monika, E-mail: spano@embl-grenoble.fr [European Molecular Biology Laboratory Grenoble Outstation, 6 Rue Jules Horowitz, 38042 Grenoble (France); Institut Laue-Langevin, 6 Rue Jules Horowitz, BP 156, 38042 Grenoble (France); Bonneté, Françoise; Ferté, Natalie [Centre de Recherche en Matière Condensée et Nanosciences, Campus de Luminy, Case 913, 13288 Marseille (France); El Hajji, Mohamed [Sanofi-Aventis, 371 Rue du Professeur Blayac, 34184 Montpellier (France); Meilleur, Flora [Institut Laue-Langevin, 6 Rue Jules Horowitz, BP 156, 38042 Grenoble (France); Blakeley, Matthew Paul [European Molecular Biology Laboratory Grenoble Outstation, 6 Rue Jules Horowitz, 38042 Grenoble (France); Castro, Bertrand [Sanofi-Aventis, 371 Rue du Professeur Blayac, 34184 Montpellier (France); European Molecular Biology Laboratory Grenoble Outstation, 6 Rue Jules Horowitz, 38042 Grenoble (France)

2006-03-01

Neutron diffraction data of hydrogenated recombinant urate oxidase enzyme (Rasburicase), complexed with a purine-type inhibitor 8-azaxanthin, was collected to 2.1 Å resolution from a crystal grown in D{sub 2}O by careful control and optimization of crystallization conditions via knowledge of the phase diagram. Deuterium atoms were clearly seen in the neutron-scattering density map. Crystallization and preliminary neutron diffraction measurements of rasburicase, a recombinant urate oxidase enzyme expressed by a genetically modified Saccharomyces cerevisiae strain, complexed with a purine-type inhibitor (8-azaxanthin) are reported. Neutron Laue diffraction data were collected to 2.1 Å resolution using the LADI instrument from a crystal (grown in D{sub 2}O) with volume 1.8 mm{sup 3}. The aim of this neutron diffraction study is to determine the protonation states of the inhibitor and residues within the active site. This will lead to improved comprehension of the enzymatic mechanism of this important enzyme, which is used as a protein drug to reduce toxic uric acid accumulation during chemotherapy. This paper illustrates the high quality of the neutron diffraction data collected, which are suitable for high-resolution structural analysis. In comparison with other neutron protein crystallography studies to date in which a hydrogenated protein has been used, the volume of the crystal was relatively small and yet the data still extend to high resolution. Furthermore, urate oxidase has one of the largest primitive unit-cell volumes (space group I222, unit-cell parameters a = 80, b = 96, c = 106 Å) and molecular weights (135 kDa for the homotetramer) so far successfully studied with neutrons.

Neutron magnetic multiple diffraction in a natural magnetite crystal

International Nuclear Information System (INIS)

Mazzocchi, V.L.; Parente, C.B.R.

1988-09-01

Neutron multiple diffraction has been employed in the study of the magnetism in magnetite (Fe 3 O 4 ). Magnetite has a crystallographic structure of an inverted spinel with tetrahedral A sites occupied solely by trivalent Fe 3+ ions and octahedral B sites occupied both by divalent Fe 2+ ions and the remaining Fe 3+ ions in random distribution. At room temperature magnetite is a Neel A-B ferrimagnet where the ions on the A, B sites are coupled antiferromagneticaly. This coupling disappears at T sup c approx. or approx.= 580 0 C. Employing a natural single crystal of magnetite experimental neutron multiple diffraction patterns were obtained for the primary reflection 111 at room temperature and 703 0 C. This reflection is almost entirely magnetic in origin resulting in 'Aufhellung' patterns below T c and mixed 'Aufhellung-Umweganregung' patterns above T c . Theoretical patterns were calculated employing the iterative method for the approximation of intensities by a Taylor series and compared to the experimental results. (author) [pt

Rietveld refinement with time-of-flight powder diffraction data from pulsed neutron sources

International Nuclear Information System (INIS)

David, W.I.F.; Jorgensen, J.D.

1990-10-01

The recent development of accelerator-based pulsed neutron sources has led to the widespread use of the time-of-flight technique for neutron powder diffraction. The properties of the pulsed source make possible unusually high resolution over a wide range of d spacings, high count rates, and the ability to collect complete data at fixed scattering angles. The peak shape and other instrument characteristics can be accurately modelled, which make Rietveld refinement possible for complex structures. In this paper we briefly review the development of the Rietveld method for time-of-flight diffraction data from pulsed neutron sources and discuss the latest developments in high resolution instrumentation and advanced Rietveld analysis methods. 50 refs., 12 figs., 14 tabs

Locations of oxygen, nitrogen and carbon atoms in vanadium determined by neutron diffraction

International Nuclear Information System (INIS)

Hiraga, K.; Onozuka, T.; Hirabayashi, M.

1977-01-01

The occupation sites of oxygen, nitrogen, and carbon atoms dissolved interstitially in vanadium have been determined by means of neutron diffraction with use of single crystals of VOsub(0.032), VNsub(0.013) and VCsub(0.006). It is revealed that the interstitial atoms occupy, randomly, the octahedral sites in the b.c.c. host lattice of the three crystals. Neutron diffraction is advantageous for the present purpose, since the coherent scattering amplitudes of the solute atoms are much larger than that of the vanadium atom. (Auth.)

Proceedings of the 1986 workshop on advanced time-of-flight neutron powder diffraction

International Nuclear Information System (INIS)

Lawson, A.C.; Smith, K.

1986-09-01

This report contains abstracts of talks and summaries of discussions from a small workshop held to discuss the future of time-of-flight neutron powder diffraction and its implementation at the Los Alamos Neutron Scattering Center. 47 refs., 3 figs

Proceedings of the 1986 workshop on advanced time-of-flight neutron powder diffraction

Energy Technology Data Exchange (ETDEWEB)

Lawson, A.C.; Smith, K. (comps.)

1986-09-01

This report contains abstracts of talks and summaries of discussions from a small workshop held to discuss the future of time-of-flight neutron powder diffraction and its implementation at the Los Alamos Neutron Scattering Center. 47 refs., 3 figs.

Neutron Diffraction Investigation of MnAs under High Pressure

DEFF Research Database (Denmark)

Andresen, A.F; Fjellvag, H; Lebech, Bente

1984-01-01

Powdered MnAs has been investigated by neutron diffraction in a pressure cryostat, at hydrostatic pressures up to 13 kbar and temperatures down to 4.2 K. It has been found that in the orthorhombic MnP type structure, which under pressure is retained at low temperature, a spiral magnetic structure...

Investigation of Methacrylic Acid at High Pressure Using Neutron Diffraction

DEFF Research Database (Denmark)

Marshall, William G.; Urquhart, Andrew; Oswald, Iain D. H.

2015-01-01

This article shows that pressure can be a low-intensity route to the synthesis of polymethacrylic acid. The exploration of perdeuterated methacrylic acid at high pressure using neutron diffraction reveals that methacrylic acid exhibits two polymorphic phase transformations at relatively low...

Polarized neutron powder diffraction studies of antiferromagnetic order in bulk and nanoparticle NiO

DEFF Research Database (Denmark)

Brok, Erik; Lefmann, Kim; Deen, Pascale P.

2015-01-01

surface contribution to the magnetic anisotropy. Here we explore the potential use of polarized neutron diffraction to reveal the magnetic structure in NiO bulk and nanoparticle powders by applying the XYZ-polarization analysis method. Our investigations address in particular the spin orientation in bulk....... The results show that polarization analyzed neutron powder diffraction is a viable method to investigate magnetic order in powders of antiferromagnetic nanoparticles.......In many materials it remains a challenge to reveal the nature of magnetic correlations, including antiferromagnetism and spin disorder. Revealing the spin structure in magnetic nanoparticles is further complicated by the large incoherent neutron scattering cross section from water adsorbed...

Refractive and diffractive neutron optics with reduced chromatic aberration

Energy Technology Data Exchange (ETDEWEB)

Poulsen, S.O., E-mail: stefan.poulsen@northwestern.edu [NEXMAP, Department of Physics, Technical University of Denmark, Anker Engelunds Vej 1, 2800 Kgs. Lyngby (Denmark); Department of Materials Science and Engineering, Northwestern University, Evanston, IL 60208 (United States); Poulsen, H.F. [NEXMAP, Department of Physics, Technical University of Denmark, Anker Engelunds Vej 1, 2800 Kgs. Lyngby (Denmark); Bentley, P.M. [European Spallation Source ESS AB, Box 176, 221 00 Lund (Sweden)

2014-12-11

Thermal neutron beams are an indispensable tool in physics research. The spatial and the temporal resolution attainable in experiments are dependent on the flux and collimation of the neutron beam which remain relatively poor, even for modern neutron sources. These difficulties may be mitigated by the use of optics for focusing and imaging. Refractive and diffractive optical elements, e.g. compound refractive lenses and Fresnel zone plates, are attractive due to their low cost, and simple alignment. These optical elements, however, suffer from chromatic aberration, which limit their effectiveness to highly monochromatic beams. This paper presents two novel concepts for focusing and imaging non-monochromatic thermal neutron beams with well-known optical elements: (1) a fast mechanical transfocator based on a compound refractive lens, which actively varies the number of individual lenses in the beam path to focus and image a time-of-flight beam, and (2) a passive optical element consisting of a compound refractive lens, and a Fresnel zone plate, which may focus and image both continuous and pulsed neutron beams.

Ultra-low-temperature neutron diffraction. Final report, July 1, 1983-June 30, 1985. Final report

International Nuclear Information System (INIS)

Halperin, W.P.; Ketterson, J.B.

1985-07-01

An ultra-low-temperature neutron diffraction facility has been constructed at Argonne National Laboratory. The initial and primary purpose of this facility is to study nuclear magnetic ordering phenomenon. Magnetic structure information is commonly recognized as being fundamental to the progress in theoretical and experimental efforts in the field of magnetism. We have initiated study of the nuclear spin in solid 3 He and in metals. In 3 He the nuclear spins order at 1.1 mK. Structure information for neutron diffraction would contribute significantly to this problem of nuclear magnetism. Despite substantial experimental difficulties, careful evaluation suggests that examination of the nuclear structure in this unique quantum crystal is indeed feasible by neutron diffraction. Substantial progress has been made in growing single crystals of 3 He and establishing its temperature in the presence of a neutron flux. We have also initiated investigation of nuclear ordering in copper and PrCu 6

New developments of TOF neutron diffraction at the IBR-2 pulsed reactor

International Nuclear Information System (INIS)

Balagurov, Anatoli M.

2001-01-01

Development of high-resolution RTOF Fourier technique for powder neutron diffraction studies is being continued at the IBR-2 pulsed reactor in Dubna. Besides some technical improvements in the operating HRFD instrument, a new dedicated instrument, Fourier Strain Diffractometer (FSD), for investigation of residual stresses in bulk materials has been constructed at IBR-2 in 1999. With a new HRFD Fourier chopper smaller than 10 μs TOF contribution in a resolution function was obtained in the experiment with perfect Si single crystal. A series of diffraction experiments with the beams from a new methane cold neutron moderator installed at the IBR-2 in 1999 is discussed. A comparison with the results obtained with the conventional water comb-like moderator shows that for various types of experiments, which are performed at HRFD and DN-2 diffractometers, the methane cold neutron source provides better conditions. (author)

Precise structural analysis of methane hydrate by neutron diffraction

International Nuclear Information System (INIS)

Igawa, Naoki; Hoshikawa, Akinori; Ishii, Yoshinobu

2006-01-01

Methane hydrate has attracted great interest as an energy resource to replace natural gas since this material is deposited in the seafloor and the deposits are estimated to exceed those of natural gas. Understanding the physical proprieties, such as the temperature dependence of the crystal structure, helps to specify the optimum environmental temperature and pressure during drilling, transport, and storage of methane hydrate. Clathrate hydrates consisted of encaging atomic and/or molecular species as a guest and host water formed by a hydrogen bonding. Although many studies on the clathrate hydrate including methane hydrate were reported, no detailed crystallographic property has yet been cleared. We focused on the motion of methane in the clathrate hydrate by the neutron diffraction. The crystal structure of the methane hydrate was analyzed by the applying the combination of the Rietveld refinement and the maximum entropy method (MEM) to neutron powder diffraction. Temperature dependence of the scattering-length density distribution maps revealed that the motion of methane molecules differs between the shapes of dodecahedron and tetrakaidecahedron. (author)

Analysis of neutron diffraction peak broadening caused by internal stresses in composite materials

International Nuclear Information System (INIS)

Todd, R.I.; Borsa, C.; Derby, B.

1994-01-01

Neutron diffraction is an essential tool in the study of internal stresses in composite materials. In most work only the peak shifts caused by the related elastic strains are considered, but other valuable information exists in the form of peak shape changes. The conditions under which the pure diffraction profile of the composite (i.e. the profile when all sources of broadening not caused by the residual stresses are removed) represents the probability distribution of the peak shifts corresponding to the strains are examined. It is shown that in these conditions, the pure diffraction profile has no attributes of particle size broadening (and vice versa), thereby providing a test for the validity of results interpreted in this way. The experimental derivation of measured strain distributions in Al 2 O 3 /SiCp composites using neutron diffraction is described. No apparent particle size broadening was detected, demonstrating the validity of the results, which also satisfied other tests for consistency

Magnetic neutron diffraction of MnO thin films

International Nuclear Information System (INIS)

Neubeck, W.; Vettier, C.; Mannix, D.; Bernhoeft, N.; Hiess, A.; Ranno, L.; Givord, D.

1999-01-01

We report on magnetic neutron diffraction carried out on various epitaxial MnO(III) thin films grown on sapphire and MgO substrates. In all samples, of masses between 5 and 50 μg, magnetic Bragg peaks have been observed. The films exhibit what appears to be continuous phase-transitions in contrast to the strongly discontinuous transition exhibited by bulk samples. In addition, the Neel temperature of films prepared on sapphire substrates is strongly enhanced above that of the bulk whilst that of the film grown on MgO is depressed. The possibility to measure magnetic excitations in such thin film systems is discussed in the light of promising test results obtained from an inelastic magnetic neutron scattering experiment on the IN8 spectrometer. (authors)

Neutron diffraction study of α-iron titanium cerium hydride

International Nuclear Information System (INIS)

Lin Hong; Niu Shiwen; Gou Cheng

1987-01-01

The results of the neutron scattering method shows that the crystal structure of Fe 0.94 TiCe 0.06 H 0.03 is the same as that of the FeTiH 0.02 . However, its diffraction peak intensities drop by 47-58%, the background increased markedly about 2 times and the lattice constant increase by 5%

Incident spectrum determination for time-of-flight neutron powder diffraction data analysis

International Nuclear Information System (INIS)

Hodges, J. P.

1998-01-01

Accurate characterization of the incident neutron spectrum is an important requirement for precise Rietveld analysis of time-of-flight powder neutron diffraction data. Without an accurate incident spectrum the calculated model for the measured relative intensities of individual Bragg reflections will possess systematic errors. We describe a method for obtaining an accurate numerical incident spectrum using data from a transmitted beam monitor

Direct observation of crystal texture by neutron diffraction topography

International Nuclear Information System (INIS)

Tomimitsu, Hiroshi

1982-02-01

This document reports the development and the applications of the neutron diffraction topography (NDT), which have been carried out at JAERI in these 10 years. This describes how the substructure of Cu-5%Ge single crystal of large-scale (3 cm in diameter and 10 cm in length) was revealed by the NDT-observation. It was discovered that the specimen crystal was made up from the layer-substructures parallel to (001) and to the [110] growth direction, and that each (001) layer-substructure mentioned above was further subdivided into the central thin sublayer parallel to (001) and thick plates of [100] and [010] directions, attached symmetrically to both sides of the central (001) sublayer with regular intervals. The model of the substructure described above was supported by the calculation of the diffraction intensities. The model of the layer-substructure described above, on the other hand, suggested a simple mechanism of crystal growth of the specimen. This document also reports the NDT-observation of the three-dimensional distribution of the lattice strains within a hot-pressed Ge single crystal, and the equal thickness fringes and the coherent boundaries of a twinned Si crystal. The powerfulness and the reliability of the NDT-technique were thus demonstrated. (author)

Pulsed Neutron Powder Diffraction for Materials Science

Science.gov (United States)

Kamiyama, T.

2008-03-01

The accelerator-based neutron diffraction began in the end of 60's at Tohoku University which was succeeded by the four spallation neutron facilities with proton accelerators at the High Energy Accelerator Research Organization (Japan), Argonne National Laboratory and Los Alamos Laboratory (USA), and Rutherford Appleton Laboratory (UK). Since then, the next generation source has been pursued for 20 years, and 1MW-class spallation neutron sources will be appeared in about three years at the three parts of the world: Japan, UK and USA. The joint proton accelerator project (J-PARC), a collaborative project between KEK and JAEA, is one of them. The aim of the talk is to describe about J-PARC and the neutron diffractometers being installed at the materials and life science facility of J-PARC. The materials and life science facility of J-PARC has 23 neutron beam ports and will start delivering the first neutron beam of 25 Hz from 2008 May. Until now, more than 20 proposals have been reviewed by the review committee, and accepted proposal groups have started to get fund. Those proposals include five polycrystalline diffractometers: a super high resolution powder diffractometer (SHRPD), a 0.2%-resolution powder diffractometer of Ibaraki prefecture (IPD), an engineering diffractometers (Takumi), a high intensity S(Q) diffractometer (VSD), and a high-pressure dedicated diffractometer. SHRPD, Takumi and IPD are being designed and constructed by the joint team of KEK, JAEA and Ibaraki University, whose member are originally from the KEK powder group. These three instruments are expected to start in 2008. VSD is a super high intensity diffractometer with the highest resolution of Δd/d = 0.3%. VSD can measure rapid time-dependent phenomena of crystalline materials as well as glass, liquid and amorphous materials. The pair distribution function will be routinely obtained by the Fourier transiformation of S(Q) data. Q range of VSD will be as wide as 0.01 Å-1stress mapping inside

Physics and chemistry of materials from neutron diffraction and spectroscopy

International Nuclear Information System (INIS)

Dahlborg, U.; Lovesey, S.W.; Uppsala Univ.

1990-11-01

A short introduction to the powerful techniques of neutron diffraction and spectroscopy is illustrated largely with achievements by Swedish researchers in the past few years. Background material on sources and instrumentation is included, together with a directory of facilities routinely available to the Swedish scientific community. (author)

Neutron scattering. Lectures

Energy Technology Data Exchange (ETDEWEB)

Brueckel, Thomas; Heger, Gernot; Richter, Dieter; Roth, Georg; Zorn, Reiner [eds.

2010-07-01

The following topics are dealt with: Neutron sources, symmetry of crystals, diffraction, nanostructures investigated by small-angle neutron scattering, the structure of macromolecules, spin dependent and magnetic scattering, structural analysis, neutron reflectometry, magnetic nanostructures, inelastic scattering, strongly correlated electrons, dynamics of macromolecules, applications of neutron scattering. (HSI)

Neutron scattering. Lectures

International Nuclear Information System (INIS)

Brueckel, Thomas; Heger, Gernot; Richter, Dieter; Roth, Georg; Zorn, Reiner

2010-01-01

The following topics are dealt with: Neutron sources, symmetry of crystals, diffraction, nanostructures investigated by small-angle neutron scattering, the structure of macromolecules, spin dependent and magnetic scattering, structural analysis, neutron reflectometry, magnetic nanostructures, inelastic scattering, strongly correlated electrons, dynamics of macromolecules, applications of neutron scattering. (HSI)

X – ray and neutron diffraction of TiAl alloys

International Nuclear Information System (INIS)

Valkov, Stefan; Petrov, Peter; Neov, Dimitar; Beskrovny, Anatoly; Kozlenko, Denis

2015-01-01

TiAl alloys were prepared by electron beam hybrid method. Composite Ti-Al film, from composite target, was deposited on Ti substrate by electron beam evaporation, followed by electron beam treatment with scanning electron beam. Experiments were made using Leybold Heraus (EWS 300/ 15 - 60) with the following technological parameters : accelerating voltage U = 60kV; beam current I=40 mA, speed of movement of specimens V=5 cm/s, current of the focusing lens If =512mA, specimen distance D0 = 38cm. X- ray and neutron diffraction methods were used to determine the phase composition on the surface and at the volume, respectively. Time of flight neutron diffraction study of TiAl specimens was performed on DN-2 diffractometer at fast pulsed IBR-2 reactor in FLNP JINR (Dubna, Russia).We found that intermetallic TiAl phases were successfully obtained on the surface, as well as in the volume.

The magnetic structure of GdNi2B2C investigated by neutron powder diffraction

International Nuclear Information System (INIS)

Barcza, A.; Rotter, M.; Doerr, M.; Beuneu, B.

2005-01-01

Full text: The group of ReT 2 B 2 C (Re=rare earth, T=transition metal) shows a very interesting interplay between magnetism and superconductivity due to the rare earth metals. In this work the magnetism of GdNi 2 B 2 C was studied with neutron diffraction. Previous investigations with x-ray diffraction methods have determined the crystal structure as a body centered tetragonal structure (I 4/mmm). Hot neutrons were used for the diffraction experiment, because the absorption cross section of Gd is significantly smaller for short wavelengths. The investigated compound orders magnetically at TN=19.5 K, and so the experiment was carried out at two temperatures, namely 30 K and 2.2 K. The results show a incommensurate spin structure with a propagation vector of (0.55 0 0). To confirm this results additional simulations of the spin structure were done based on the Standard Model of rare earth magnetism. A neutron diffraction pattern was calculated using the McPhase program package and is compared to the experimental data. (author)

Neutron scattering. Lectures

International Nuclear Information System (INIS)

Brueckel, Thomas; Heger, Gernot; Richter, Dieter; Roth, Georg; Zorn, Reiner

2012-01-01

The following topics are dealt with: Neutron scattering in contemporary research, neutron sources, symmetry of crystals, diffraction, nanostructures investigated by small-angle neutron scattering, the structure of macromolecules, spin dependent and magnetic scattering, structural analysis, neutron reflectometry, magnetic nanostructures, inelastic scattering, strongly correlated electrons, dynamics of macromolecules, applications of neutron scattering. (HSI)

Residual stress analysis for engineering applications by means of neutron diffraction

International Nuclear Information System (INIS)

Gnaeupel-Herold, T.; Brand, P.C.; Prask, H.J.

1999-01-01

Residual stresses originate from spatial differences in plastic deformation, temperature, or phase distribution, introduced by manufacturing processes or during service. Engineering parts and materials experience mechanical, thermal, and chemical loads during their service, and most of these loads introduce stresses that are superimposed on the already existing residual stresses. Residual stresses can therefore limit or improve life and strength of engineering parts; knowledge and understanding of these stresses is therefore critical for optimizing strength and durability. The economic and scientific importance of neutron diffraction residual stress analysis has led to an increasing number of suitable instruments worldwide. All of the major sources due in the next several years will have instruments for the sole purpose of performing residual stress and texture measurements. Recently, a dedicated, state-of-the-art diffractometer has been installed at the National Institute of Standards and Technology reactor. It has been used for a variety of measurements on basic and engineering stress problems. Among the most prominent examples that have been investigated in collaboration with industrial and academic partners are residual stresses in rails, weldments, and plasma-sprayed coatings

Neutron scattering and diffraction instrument for structural study on biology in Japan

Energy Technology Data Exchange (ETDEWEB)

Niimura, Nobuo [Japan Atomic Energy Research Inst., Ibaraki-ken (Japan)

1994-12-31

Neutron scattering and diffraction instruments in Japan which can be used for structural studies in biology are briefly introduced. Main specifications and general layouts of the instruments are shown.

Study on Destructuring effect of trehalose on water by neutron diffraction

CERN Document Server

Branca, C; Migliardo, F; Magazù, V; Soper, A K

2002-01-01

In this work results on trehalose/water solutions by neutron diffraction are reported. The study of the partial structure factors and spatial distribution functions gives evidence of a decreasing tetrahedrality degree of water and justifies its cryoprotectant effectiveness. (orig.)

Study on Destructuring effect of trehalose on water by neutron diffraction

Energy Technology Data Exchange (ETDEWEB)

Branca, C.; Maisano, G.; Migliardo, F. [Dipartimento di Fisica and INFM, Universita' di Messina, PO Box 55, 98166 Messina (Italy); Magazu' , V. [Facolta di Ingeeneria, Universita' di Messina, 98166 Messina (Italy); Soper, A.K. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxon OX11 0QX (United Kingdom)

2002-07-01

In this work results on trehalose/water solutions by neutron diffraction are reported. The study of the partial structure factors and spatial distribution functions gives evidence of a decreasing tetrahedrality degree of water and justifies its cryoprotectant effectiveness. (orig.)

Neutron diffraction studies of water in meso- and micro-pores

International Nuclear Information System (INIS)

Steytler, D.C.; Dore, J.C.; Wright, C.J.

1982-07-01

Neutron diffraction studies have been made for D 2 O water in two high surface-area silica samples, Spherisorb and Gasil. The results show that the structural arrangement is similar to that of bulk water and that the modification due to the interface is restricted to a range of the order of 10 A or less. Measurements also indicate that the dispersed water undergoes significant structural changes with temperature variation but the behaviour is similar to that of the bulk liquid. The differences observed in the diffraction patterns can be partially described in terms of diffraction broadening due to the small volume of the dispersed water but there remains a significant variation which appears to be related to the hydrogen-bonding interactions. (author)

First observation of new effects at the set-up for searching for a neutron electric dipole moment by a crystal-diffraction method

CERN Document Server

Fedorov, V V; Semenikhin, S Y; Voronin, V V

2002-01-01

First observation of new effects was carried out using the set-up created for searching for a neutron electric dipole moment (EDM) by a crystal-diffraction method. For the first time the neutron dynamical Laue diffraction for the Bragg angles close to a right angle (up to 87 ) was studied, using the direct diffraction beam and a thick (propor to 3.5-cm) crystal. The effect of an essential time delay of diffracting neutrons inside the crystal for Bragg angles close to 90 was experimentally observed, using a time-of-flight method. The phenomenon of neutron-beam depolarization was first experimentally observed for the case of Laue diffraction in a noncentrosymmetric alpha-quartz crystal. It is experimentally proved that the interplanar electric field, affecting a neutron in a crystal, maintains its value up to Bragg angles equal to 87 . These results confirm the opportunity to increase by more than an order of magnitude the sensitivity of the method to the neutron EDM, using the diffraction angles close to 90 , ...

The use of pulsed neutron diffraction to measure strain in composites

International Nuclear Information System (INIS)

Bourke, M.A.M.; Goldstone, J.A.; Shi, N.; Gray, G.T. III; James, M.R.

1994-01-01

Neutron diffraction is a technique for measuring strain in crystalline materials. It is non destructive, phase discriminatory and more penetrating than X rays. Pulsed neutron sources (in contrast with steady state reactor sources) are particularly appropriate for examining heterogeneous materials or for recording the polycrystalline response of all lattice reflections. Several different aspects of composite behavior can be characterized and examples are given of residual strain measurements, strain relaxation during heating, applied loading, and determination of the strain distribution function

Structural characterisation of 1- and 2-dimensional transition metal polymers using powder neutron diffraction

International Nuclear Information System (INIS)

James, M.

1999-01-01

Powder neutron diffraction provides an alternate technique for the structural study of transition metal polymers and finds utility over standard X-ray methods in two significant ways. Firstly, due to a different instrument geometry, preferred orientation effects are removed from the system. The second advantage gained by utilising neutrons is that H atoms in the sample contribute much more to the nuclear scattering of the diffraction profile - allowing their atomic position to be accurately determined. In X-ray diffraction studies, where H atoms typically account for only ∼3-5% of the scattering from the sample, it is essentially impossible to refine their position in the molecular structure. The structures of several transition metal polymers have been determined using neutrons from the HIFAR reactor at ANSTO and the Powder Diffractometers HRPD and MRPD, along with Rietveld refinement methods. The 1-dimensional polymer dibromobis(thiazole)nickel(II) illustrated in the paper is characteristic of these types of systems which are comprised of transition metal centres bridged by halogen atoms with pendant amine side groups

Development of a large area, curved two-dimensional detector for single-crystal neutron diffraction studies

International Nuclear Information System (INIS)

Moon, Myung-Kook; Lee, Chang-Hee; Kim, Shin-Ae; Noda, Yukio

2013-01-01

A new type of two-dimensional curved position-sensitive neutron detector has been developed for a high-throughput single-crystal neutron diffractometer, which was designed to cover 110° horizontally and 56° vertically. The prototype curved detector covering 70° horizontally and 45° vertically was first developed to test the technical feasibility of the detector parameters, the internal anode and cathode structures for the curved shape, technical difficulties in the assembly procedure, and so on. Then, based on this experience, a full-scale curved detector with twice the active area of the prototype was fabricated with newly modified anode and cathode planes and optimized design parameters in terms of mechanical and electric properties. The detector was installed in a dedicated diffractometer at the ST3 beam port of the research reactor HANARO. In this paper, the fabrication and application of the prototype and a new larger-area curved position-sensitive neutron detector for single crystal diffraction is presented

Neutron diffraction analysis of the structure of rod photoreceptor membranes in intact retinas

Energy Technology Data Exchange (ETDEWEB)

Yaeger, M; Schoenborn, B; Engelman, D; Moore, P; Stryer, L

1980-01-01

Neutron diffraction data have been collected from samples containing ten dark-adapted Rana catesbiana bullfrog retinas in 100, 80, 60, 40, and 30% D/sub 2/O Ringer's solution using a step-scanning Soller slit diffractometer. Diffraction was also recorded from retinas equilibrated in D/sub 2/O solutions with varying osmolarity. Rocking curve experiments demonstrated that the rods are disoriented in a cylindrically symmetrical fashion. Structure factor amplitudes were obtained using semi-automated curve-fitting procedures, and phases were obtained by interpreting the D/sub 2/O-H/sub 2/O and osmotic Patterson maps. In D/sub 2/O Ringer's solution the first four structure factors are -353 +- 25, 246 +- 19, 434 +- 13 and 383 +- 19. Neutron scattering density profiles were calculated to 75 A resolution using these structure factors. These neutron diffraction data are consistent with the view that the lipid bilayer is a major structural motif of the rod outer segment disc membrane. Neutron Fourier syntheses in different mixtures of D/sub 2/O and H/sub 2/O indicate that the intradisc and extradisc spaces are predominantly aqueous, consistent with the increase in the intradisc and extradisc volumes as the Ringer's solution is made more hypotomic. In isotonic Ringer's solution, the thicknesses of the intradisc and extradisc spaces are about 36 A and 160 A, respectively, and the center-to-center separation between the 50 A thick lipid bilayer is 88 A.

Dehydration reactions of gypsum: A neutron and X-ray diffraction study

Science.gov (United States)

Abriel, W.; Reisdorf, K.; Pannetier, J.

1990-03-01

The kinetics of the dehydration of gypsum was investigated by powder diffraction methods. Using the incoherent scattering effect of H with the neutron beam, the background intensity as a measure of the water content was checked in the temperature range 295-623 K. The superposed Bragg peaks yielded four major phases: Gypsum, subhydratesCaSO 4(H 2O) x (1 > x > 0),AIII-CaSO 4, AII-CaSO 4. For the subhydrates a maximum water content of x > = 0.74was determined. A different kinetic was found using Guinier X-ray technique with the heated sample prepared on a thin foil. Only with high local H 2O steam pressure, produced in the comparable larger sample container of the neutron diffraction experiment, could this high H 2O occupation of the subhydrate tunnel structure be found. A topotactic mechanism can describe the phase transitions for this reaction.

The structure of liquid water by polarized neutron diffraction and reverse Monte Carlo modelling.

Science.gov (United States)

Temleitner, László; Pusztai, László; Schweika, Werner

2007-08-22

The coherent static structure factor of water has been investigated by polarized neutron diffraction. Polarization analysis allows us to separate the huge incoherent scattering background from hydrogen and to obtain high quality data of the coherent scattering from four different mixtures of liquid H(2)O and D(2)O. The information obtained by the variation of the scattering contrast confines the configurational space of water and is used by the reverse Monte Carlo technique to model the total structure factors. Structural characteristics have been calculated directly from the resulting sets of particle coordinates. Consistency with existing partial pair correlation functions, derived without the application of polarized neutrons, was checked by incorporating them into our reverse Monte Carlo calculations. We also performed Monte Carlo simulations of a hard sphere system, which provides an accurate estimate of the information content of the measured data. It is shown that the present combination of polarized neutron scattering and reverse Monte Carlo structural modelling is a promising approach towards a detailed understanding of the microscopic structure of water.

In-situ neutron diffraction characterization of temperature dependence deformation in α-uranium

Science.gov (United States)

Calhoun, C. A.; Garlea, E.; Sisneros, T. A.; Agnew, S. R.

2018-04-01

In-situ strain neutron diffraction measurements were conducted at temperature on specimens coming from a clock-rolled α-uranium plate, and Elasto-Plastic Self-Consistent (EPSC) modeling was employed to interpret the findings. The modeling revealed that the active slip systems exhibit a thermally activated response, while deformation twinning remains athermal over the temperature ranges explored (25-150 °C). The modeling also allowed assessment of the effects of thermal residual stresses on the mechanical response during compression. These results are consistent with those from a prior study of room-temperature deformation, indicating that the thermal residual stresses strongly influence the internal strain evolution of grain families, as monitored with neutron diffraction, even though accounting for these residual stresses has little effect on the macroscopic flow curve, except in the elasto-plastic transition.

Residual stress measurement of the jacket material for ITER coil by neutron diffraction

Energy Technology Data Exchange (ETDEWEB)

Tsuchiya, Yoshinori [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

1998-03-01

Nickel-Iron based super alloy INCOLOY 908 is used for the jacket of a central solenoid coil (CS coil) of the International Thermonuclear Experimental Reactor (ITER). INCOLOY 908, however, has a possibility of fracture due to Stress Accelerated Grain Boundary Oxidation (SAGBO) under a tensile residual stress beyond 200MPa. Therefore it is necessary to measure the residual stress of the jacket to avoid SAGBO. We performed residual stress measurement of the jacket by neutron diffraction using the neutron diffractometer for residual stress analysis (RESA) installed at JRR-3M in JAERI. A sample depth dependence of internal strain was obtained from the (111) plane spacing. A residual stress distribution was calculated from the strain using Young`s modulus and Poisson`s ratio that were evaluated by a tensile test with neutron diffraction. The result shows that the tensile residual stress exceeds 200MPa of the SAGBO condition in some regions inside the jacket. (author)

Comparative study of structural properties of trehalose water solutions by neutron diffraction, synchrotron radiation and simulation

Energy Technology Data Exchange (ETDEWEB)

Cesaro, A.; Magazu, V.; Migliardo, F.; Sussich, F.; Vadala, M

2004-07-15

Neutron diffraction measurements combined with H/D substitution have been performed on trehalose aqueous solutions as a function of temperature and concentration by using the SANDALS diffractometer at ISIS Facility (UK). The findings point out a high capability of trehalose to strongly affect the tetrahedral hydrogen bond network of water. The neutron diffraction results are also compared with simulation and experimental data obtained by synchrotron radiation on the phospholipid bilayer membranes (DPPC)/trehalose/H{sub 2}O ternary system.

Time-of-Flight Three Dimensional Neutron Diffraction in Transmission Mode for Mapping Crystal Grain Structures

DEFF Research Database (Denmark)

Cereser, Alberto; Strobl, Markus; Hall, Stephen A.

2017-01-01

constituting the material. This article presents a new non-destructive 3D technique to study centimeter-sized bulk samples with a spatial resolution of hundred micrometers: time-of-flight three-dimensional neutron diffraction (ToF 3DND). Compared to existing analogous X-ray diffraction techniques, ToF 3DND......-of-flight neutron beamline. The technique was developed and tested with data collected at the Materials and Life Science Experimental Facility of the Japan Proton Accelerator Complex (J-PARC) for an iron sample. We successfully reconstructed the shape of 108 grains and developed an indexing procedure...

Non-destructive Quantitative Phase Analysis and Microstructural Characterization of Zirconium Coated U-10Mo Fuel Foils via Neutron Diffraction

Energy Technology Data Exchange (ETDEWEB)

Cummins, Dustin Ray [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Vogel, Sven C. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Hollis, Kendall Jon [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Brown, Donald William [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dombrowski, David E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2016-10-18

This report uses neutron diffraction to investigate the crystal phase composition of uranium-molybdenum alloy foils (U-10Mo) for the CONVERT MP-1 Reactor Conversion Project, and determines the effect on alpha-uranium contamination following the deposition of a Zr metal diffusion layer by various methods: plasma spray deposition of Zr powders at LANL and hot co-rolling with Zr foils at BWXT. In summary, there is minimal decomposition of the gamma phase U-10Mo foil to alpha phase contamination following both plasma spraying and hot co-rolling. The average unit cell volume, i.e. lattice spacing, of the Zr layer can be mathematically extracted from the diffraction data; co-rolled Zr matches well with literature values of bulk Zr, while plasma sprayed Zr shows a slight increase in the lattice spacing, indicative of interstitial oxygen in the lattice. Neutron diffraction is a beneficial alternative to conventional methods of phase composition, i.e. x ray diffraction (XRD) and destructive metallography. XRD has minimal penetration depth in high atomic number materials, particularly uranium, and can only probe the first few microns of the fuel plate; neutrons pass completely through the foil, allowing for bulk analysis of the foil composition and no issues with addition of cladding layers, as in the final, aluminum-clad reactor fuel plates. Destructive metallography requires skilled technicians, cutting of the foil into small sections, hazardous etching conditions, long polishing and microscopy times, etc.; the neutron diffraction system has an automated sample loader and can fit larger foils, so there is minimal analysis preparation; the total spectrum acquisition time is ~ 1 hour per sample. The neutron diffraction results are limited by spectra refinement/calculation times and the availability of the neutron beam source. In the case of LANSCE at Los Alamos, the beam operates ~50% of the year. Following the lessons learned from these preliminary results, optimizations to

Non-destructive Quantitative Phase Analysis and Microstructural Characterization of Zirconium Coated U-10Mo Fuel Foils via Neutron Diffraction

International Nuclear Information System (INIS)

Cummins, Dustin Ray; Vogel, Sven C.; Hollis, Kendall Jon; Brown, Donald William; Dombrowski, David E.

2016-01-01

This report uses neutron diffraction to investigate the crystal phase composition of uranium-molybdenum alloy foils (U-10Mo) for the CONVERT MP-1 Reactor Conversion Project, and determines the effect on alpha-uranium contamination following the deposition of a Zr metal diffusion layer by various methods: plasma spray deposition of Zr powders at LANL and hot co-rolling with Zr foils at BWXT. In summary, there is minimal decomposition of the gamma phase U-10Mo foil to alpha phase contamination following both plasma spraying and hot co-rolling. The average unit cell volume, i.e. lattice spacing, of the Zr layer can be mathematically extracted from the diffraction data; co-rolled Zr matches well with literature values of bulk Zr, while plasma sprayed Zr shows a slight increase in the lattice spacing, indicative of interstitial oxygen in the lattice. Neutron diffraction is a beneficial alternative to conventional methods of phase composition, i.e. x ray diffraction (XRD) and destructive metallography. XRD has minimal penetration depth in high atomic number materials, particularly uranium, and can only probe the first few microns of the fuel plate; neutrons pass completely through the foil, allowing for bulk analysis of the foil composition and no issues with addition of cladding layers, as in the final, aluminum-clad reactor fuel plates. Destructive metallography requires skilled technicians, cutting of the foil into small sections, hazardous etching conditions, long polishing and microscopy times, etc.; the neutron diffraction system has an automated sample loader and can fit larger foils, so there is minimal analysis preparation; the total spectrum acquisition time is ~ 1 hour per sample. The neutron diffraction results are limited by spectra refinement/calculation times and the availability of the neutron beam source. In the case of LANSCE at Los Alamos, the beam operates ~50% of the year. Following the lessons learned from these preliminary results, optimizations to

Study of the ferrimagnetic and paramagnetic phases of magnetite measured by multiple neutron diffraction

International Nuclear Information System (INIS)

Mazzocchi, V.L.

1992-01-01

Structural parameters of the ferrimagnetic and paramagnetic phases of magnetite have been refined from neutron multiple diffraction data. Experimental multiple diffraction patterns used in the refinement, were obtained by measuring the 111 primary reflection of a natural single crystal of this compound, at room temperature for the ferrimagnetic phase and 703 0 C for the paramagnetic phase. Corresponding theoretical patterns for both phases have been calculated by the program MULTI which uses the iterative method for the intensity calculations in neutron multiple diffraction. In this method intensities are calculated as Taylor series expansions summed up to a order sufficient for a good approximation. A step by step process has been used in the refinements according to the parameter-shift method. Both isotropic and anisotropic thermal parameters were used in the calculation of the temperature factor. (author)

Diffraction plane dependency of elastic constants in ferritic steel in neutron stress measurement

International Nuclear Information System (INIS)

Hayashi, M.; Ishiwata, M.; Minakawa, N.; Funahashi, S.

1993-01-01

Neutron diffraction measurements have been made to investigate the elastic properties of the ferritic steel obtained from socket weld. The Kroner elastic model is found to account for the [hkl]-dependence of Young's modulus and Poisson's ratio in the material. Maps of residual stress are later to be made by measuring lattice strain from shifts in the (112) diffraction peak, for which the diffraction elastic constants the herein found to be E=243±5GPa and ν=0.28±0.01. (author)

Influence of multiple small-angle neutron scattering on diffraction peak broadening in ferritic steel

Czech Academy of Sciences Publication Activity Database

Woo, W.; Em, V.; Shin, E.; Mikula, Pavol; Ryukhtin, Vasyl

2015-01-01

Roč. 48, APR (2015), s. 350-356 ISSN 0021-8898 R&D Projects: GA ČR GB14-36566G; GA MŠk(CZ) LM2011019 Institutional support: RVO:61389005 Keywords : peak broadening * small-angle neutron scattering * neutron diffraction * magnetic domain Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.720, year: 2014

Neutron diffraction studies on structural and magnetic properties of RE2NiGe3 (RE=La, Ce)

International Nuclear Information System (INIS)

Kalsi, Deepti; Rayaprol, S.; Siruguri, V.; Peter, Sebastian C.

2014-01-01

We report the crystallographic properties of RE 2 NiGe 3 (RE=La, Ce) synthesized by arc melting. Rietveld refinement on the powder neutron diffraction (ND) data suggest both compounds are isostructural and crystallize in the non-centrosymmetric Er 2 RhSi 3 type structure having hexagonal space group P6 ¯ 2c. In the crystal structure of RE 2 NiGe 3 , two dimensional arrangements of nickel and germanium atoms lead to the formation of hexagonal layers with rare earth atoms sandwiched between them. Magnetic susceptibility measurements performed in low fields exhibit antiferromagnetic ordering in cerium compound around (T o =) 3.2 K. Neutron diffraction measurements at 2.8 K (i.e., at Tdiffraction lines nor indicate the appearance of any new diffraction lines in the Q-range of 0.47–7.34 Å −1 , thus ruling out any long-range magnetic order. - Graphical abstract: The compounds La 2 NiGe 3 and Ce 2 NiGe 3 crystallize in the Er 2 RhSi 3 type. Magnetic susceptibility show antiferromagnetic ordering for Ce 2 NiGe 3 at 3.2 K and neutron diffraction confirms the absence of long range ordering. - Highlights: RE 2 NiGe 3 (RE=La, Ce) crystallize in the ordered superstructure of the AlB 2 type. Magnetic susceptibility measurements exhibit antiferromagnetic ordering in Ce 2 NiGe 3 . Structure and magnetism of RE 2 NiGe 3 (RE=La, Ce) are studied by neutron diffraction

In-situ neutron diffraction measurements of temperature and stresses during friction stir welding of 6061-T6 aluminum alloy

International Nuclear Information System (INIS)

Woo, Wan Chuck; Feng, Zhili; Wang, Xun-Li; Brown, D.W.; Clausen, B.; An, Ke; Choo, Hahn; Hubbard, Camden R.; David, Stan A.

2007-01-01

The evolution of temperature and thermal stresses during friction stir welding of Al6061-T6 was investigated by means of in-situ, time-resolved neutron diffraction technique. A method is developed to deconvolute the temperature and stress from the lattice spacing changes measured by neutron diffraction. The deep penetration capability of neutrons made it possible for the first time to obtain the temperature and thermal stresses inside a friction stir weld

Textures of iron oxide ores by neutron diffraction and topotactical relation

International Nuclear Information System (INIS)

Wagner, F.; Esling, C.; Baro, R.; Englander, M.

1977-01-01

Two samples are cut from a polycrystalline haematite block. The first one is directly submitted to texture analysis by neutron diffraction, whereas the second one is first reduced into magnetite. The comparison of both textures is in agreement with a topotactical relationship previously reported for monocrystals. (orig.) [de

Experimental evaluation of a polycrystal deformation modeling scheme using neutron diffraction measurements

DEFF Research Database (Denmark)

Clausen, Bjørn; Lorentzen, Torben

1997-01-01

The uniaxial behavior of aluminum polycrystals is simulated using a rate-independent incremental self-consistent elastic-plastic polycrystal deformation model, and the results are evaluated by neutron diffraction measurements. The elastic strains deduced from the model show good agreement...

Implementation of neutron diffraction technique at Nuclear Center of National Institute of Nuclear Research for study of materials

International Nuclear Information System (INIS)

Macias Betanzos, L.R.

1993-01-01

The Neutron Diffraction technique, it's a helpful tool for the study of materials. The purpose, was to verify that such technique works with the Neutron Diffractometer of National Institute of Nuclear Research. The scope, is to study crystalline materials by the Neutron Diffraction Method, that means it completion with Bragg's Law. There exist a lot of diffraction techniques that depend on the kind of study to do. In this case the study was to measure known samples to have a correlation between parameters such a extinction factor and dislocation density. Known copper deformed samples were measured to observe the extinction effect and it could be observed. We had to calibrate the Neutron Diffractometer, the detection system and to have an optimal movement control of diffractometer devices by mean of a microcomputer. Also, was necessary to control the Reactor TRIGA operation to minimize the neutron flux oscillation. It was not possible the quantification of dislocation density in the samples because the relation signal/background was about one and it gives high inaccuracy. To correct this problem, it's necessary to have a better shielding to minimize the contribution of the background. The conclusion is that the Neutron Diffractometer is in conditions to carry out investigation on the material field, today it can be lattice constants, crystalline phases and measurements of metallic textures. For such studies, it's necessary to have samples with 2 cm 3 or higher to increase the relation signal/background. At present, we have the process software to give the interpretation of the Neutron Diffraction process. (Author). 12 refs, 16 figs

Neutron diffraction measurements of residual stress in a powder metallurgy component

International Nuclear Information System (INIS)

Schneider, L.C.R.; Hainsworth, S.V.; Cocks, A.C.F.; Fitzpatrick, M.E.

2005-01-01

Residual stresses in a typical industrial green component were determined using neutron diffraction. The measured residual stresses were found to correlate with cross-sectional variations. Residual stress at the edge of the compact in contact with the die wall during compaction reached up to +80 MPa (tension) and -100 MPa (compression)

Neutron beam applications - Development of single crystal structure analysis technique using the HANARO neutron four circle diffractometer

Energy Technology Data Exchange (ETDEWEB)

Suh, Il Hwan; Kim, Moon Jib; Kim, Jin Gyu [Chungnam National University, Taejon (Korea)

2000-04-01

As the four circle diffractometer (FCD) has been set up in HANARO, it has become possible to study the single crystal structures by means of the neutron diffraction. Taking account of the geometry of the FCD, a program for the control of te FCD and neutron data acquisition operating under Windows' circumstance has been accomplished. Also, a computer program which can automatically measure the diffraction intensity data has been developed. All data obtained from the FCD are processed automatically for further work and a software for the single crystal structure analyses has been prepared. A KC1 single crystal was selected as first test sample for a structure analysis had been successfully performed on the FCD using in-house developed program and accordingly their functionings with precision were confirmed. For regular single crystal diffraction experiments, the structure analyses of chrysoberyl and Zr(Y)0{sub 1.87} single crystals were performed using both neutron and X-ray diffraction methods, and the result showed that the neutron diffraction work is superior to the X-ray one from the viewpoint of certain crystallographic information obtainable only from the former one. 24 refs., 15 figs., 15 tabs. (Author)

Texture analysis using angle dispersive neutron nuclear scattering

International Nuclear Information System (INIS)

Brokmeier, H.G.

1995-01-01

This paper describes in detail the method of texture determination using neutron diffraction. The main advantages of neutron diffraction arise from the high penetration depth for most materials which is a factor of 10 2 -10 4 higher than for X-ray diffraction. Consequently neutron diffraction is an efficient tool for the investigation of global textures and coarse grained materials. Moreover, the measurement of large sample volumes gives excellent grain statistics, allows the influence of texture inhomogeneities to be neglected and allows the measurement of complete pole figures even of minority phases. A number of examples show the application of neutron diffraction to measure textures of metals, alloys, composites, intermetallic compounds and rocks. A detailed description of TEX-2 the neutron texture diffractometer at GKSS Research Centre is given which is completed by a comparison to other neutron texture diffractometers. (orig.) [de

Neutron Diffraction from the Second Layer of 4He on Graphite

DEFF Research Database (Denmark)

da Costa Carneiro, Kim; Passell, L.; Thomlinson, W.

1981-01-01

Neutron diffraction has been used to study the second atomic layer of **4He adsorbed on graphite. As the **4He-coverage exceeds the first layer, the second initially forms a fluid phase. But when there is enough **4He in the third layer to compress the second, this layer solidifies. The structure...

Practical conditions in the neutron diffraction under high pressure

International Nuclear Information System (INIS)

Kamigaki, Kazuo; Ohashi, Masayoshi

1993-01-01

Practical analysis is made on some conditions in utilizing neutrons for the study of atomistic structure of materials under high pressure. Investigation is made on the geometrical conditions; size of the specimen, width of slits, and the rate of extra-scattering. Experiments are performed on the effects of absorption by high pressure cell and the disturbance due to an overlapping of diffraction peaks. An observation is presented on the pressure-induced transformation in RbBr. (author)

Deformation behavior of Mg-alloy-based composites at different temperatures studied by neutron diffraction

Energy Technology Data Exchange (ETDEWEB)

Farkas, Gergely [Department of Metal Physics, Charles University, Ke Karlovu, 5, CZ-121 16 Prague (Czech Republic); Nuclear Physics Institute, v. v. i., 250 68 Řež (Czech Republic); Máthis, Kristian [Department of Metal Physics, Charles University, Ke Karlovu, 5, CZ-121 16 Prague (Czech Republic); Pilch, Ján [Nuclear Physics Institute, v. v. i., 250 68 Řež (Czech Republic); Minárik, Peter [Department of Metal Physics, Charles University, Ke Karlovu, 5, CZ-121 16 Prague (Czech Republic); Lukáš, Petr [Nuclear Physics Institute, v. v. i., 250 68 Řež (Czech Republic); Vinogradov, Alexei, E-mail: alexei.vinogradov@ntnu.no [Department of Mechanical and Industrial Engineering, Norwegian University of Science and Technology - NTNU, Trondheim N-7491 (Norway); Institute of Advanced Technologies, Togliatti State University, 445020 (Russian Federation)

2017-02-08

The influence of the reinforcement short Saffil fibers on the deformation behavior of Mg-Al-Ca alloy-based composite with two different fiber plane orientations is investigated and clarified using in-situ neutron diffraction at room and elevated temperatures. The measured lattice strain evolution points to a more efficient reinforcing effect of fibers at parallel fiber plane orientation, which decreases at elevated temperature. A significant decrement of compressive lattice strain was incidentally observed in the matrix in the direction of load axis when deformation due to the elevated temperature occurred. Electron microscopy revealed the influence of the temperature and fiber orientation on fiber cracking. The EBSD observations corroborated neutron diffraction results highlighting significant twin growth at elevated testing temperatures.

Commercial applications of neutron scattering

International Nuclear Information System (INIS)

Hutchings, M.T.

1993-01-01

The fact that industry is now willing to pay the full commercial cost for certain neutron scattering experiments aimed at solving its urgent materials - related problems is a true testimony to the usefulness of neutrons as microscopic probes. This paper gives examples of such use of three techniques drawn mainly from our experience at AEA Technology Harwell Laboratory. These are diffraction to measure residual stress, small angle neutron scattering to examine hardening precipitates in ferritic steels brought about by irradiation, and reflectivity to study amorphous diamond layers deposited on silicon. In most cases it is the penetrative power of the neutron which proves to be its best asset for commercial industrial applicaitons. (author)

Neutron sources and applications

Energy Technology Data Exchange (ETDEWEB)

Price, D.L. [ed.] [Argonne National Lab., IL (United States); Rush, J.J. [ed.] [National Inst. of Standards and Technology, Gaithersburg, MD (United States)

1994-01-01

Review of Neutron Sources and Applications was held at Oak Brook, Illinois, during September 8--10, 1992. This review involved some 70 national and international experts in different areas of neutron research, sources, and applications. Separate working groups were asked to (1) review the current status of advanced research reactors and spallation sources; and (2) provide an update on scientific, technological, and medical applications, including neutron scattering research in a number of disciplines, isotope production, materials irradiation, and other important uses of neutron sources such as materials analysis and fundamental neutron physics. This report summarizes the findings and conclusions of the different working groups involved in the review, and contains some of the best current expertise on neutron sources and applications.

Neutron sources and applications

International Nuclear Information System (INIS)

Price, D.L.; Rush, J.J.

1994-01-01

Review of Neutron Sources and Applications was held at Oak Brook, Illinois, during September 8--10, 1992. This review involved some 70 national and international experts in different areas of neutron research, sources, and applications. Separate working groups were asked to (1) review the current status of advanced research reactors and spallation sources; and (2) provide an update on scientific, technological, and medical applications, including neutron scattering research in a number of disciplines, isotope production, materials irradiation, and other important uses of neutron sources such as materials analysis and fundamental neutron physics. This report summarizes the findings and conclusions of the different working groups involved in the review, and contains some of the best current expertise on neutron sources and applications

Neutron Diffraction Residual Strain Tensor Measurements Within The Phase IA Weld Mock-up Plate P-5

Energy Technology Data Exchange (ETDEWEB)

Hubbard, Camden R [ORNL

2011-09-01

Oak Ridge National Laboratory (ORNL) has worked with NRC and EPRI to apply neutron and X-ray diffraction methods to characterize the residual stresses in a number of dissimilar metal weld mockups and samples. The design of the Phase IA specimens aimed to enable stress measurements by several methods and computational modeling of the weld residual stresses. The partial groove in the 304L stainless steel plate was filled with weld beads of Alloy 82. A summary of the weld conditions for each plate is provided in Table 1. The plates were constrained along the long edges during and after welding by bolts with spring-loaded washers attached to the 1-inch thick Al backing plate. The purpose was to avoid stress relief due to bending of the welded stainless steel plate. The neutron diffraction method was one of the methods selected by EPRI for non-destructive through thickness strain and stress measurement. Four different plates (P-3 to P-6) were studied by neutron diffraction strain mapping, representing four different welding conditions. Through thickness neutron diffraction strain mappings at NRSF2 for the four plates and associated strain-free d-zero specimens involved measurement along seven lines across the weld and at six to seven depths. The mountings of each plate for neutron diffraction measurements were such that the diffraction vector was parallel to each of the three primary orthogonal directions of the plate: two in-plane directions, longitudinal and transverse, and the direction normal to the plate (shown in left figure within Table 1). From the three orthogonal strains for each location, the residual stresses along the three plate directions were calculated. The principal axes of the strain and stress tensors, however, need not necessarily align with the plate coordinate system. To explore this, plate P-5 was selected for examination of the possibility that the principal axes of strain are not along the sample coordinate system axes. If adequate data could

Characterization of neutron-irradiated HT-UPS steel by high-energy X-ray diffraction microscopy

Energy Technology Data Exchange (ETDEWEB)

Zhang, Xuan, E-mail: xuanzhang@anl.gov [Nuclear Engineering Division, Argonne National Laboratory, Lemont, IL 60439 (United States); Park, Jun-Sang; Almer, Jonathan [Advanced Photon Source, Argonne National Laboratory, Lemont, IL 60439 (United States); Li, Meimei [Nuclear Engineering Division, Argonne National Laboratory, Lemont, IL 60439 (United States)

2016-04-01

This paper presents the first measurement of neutron-irradiated microstructure using far-field high-energy X-ray diffraction microscopy (FF-HEDM) in a high-temperature ultrafine-precipitate-strengthened (HT-UPS) austenitic stainless steel. Grain center of mass, grain size distribution, crystallographic orientation (texture), diffraction spot broadening and lattice constant distributions of individual grains were obtained for samples in three different conditions: non-irradiated, neutron-irradiated (3dpa/500 °C), and irradiated + annealed (3dpa/500 °C + 600 °C/1 h). It was found that irradiation caused significant increase in grain-level diffraction spot broadening, modified the texture, reduced the grain-averaged lattice constant, but had nearly no effect on the average grain size and grain size distribution, as well as the grain size-dependent lattice constant variations. Post-irradiation annealing largely reversed the irradiation effects on texture and average lattice constant, but inadequately restored the microstrain.

High pressure sample container for thermal neutron spectroscopy and diffraction on strongly scattering fluids

International Nuclear Information System (INIS)

Verkerk, P.; Pruisken, A.M.M.

1979-01-01

A description is presented of the construction and performance of a container for thermal neutron scattering on a fluid sample with about 1.5 cm -1 macroscopic cross section (neglecting absorption). The maximum pressure is about 900 bar. The container is made of 5052 aluminium capillary with inner diameter 0.75 mm and wall thickness 0.25 mm; it covers a neutron beam with a cross section of 9 X 2.5 cm 2 . The container has been successfully used in neutron diffraction and time-of-flight experiments on argon-36 at 120 K and several pressures up to 850 bar. It is shown that during these measurements the temperature gradient over the sample as well as the error in the absolute temperature were both less than 0.05 K. Subtraction of the Bragg peaks due to container scattering in diffraction experiments may be dfficult, but seems feasible because of the small amount of aluminium in the neutron beam. Correction for container scattering and multiple scattering in time-of-flight experiments may be difficult only in the case of coherently scattering samples and small scattering angles. (Auth.)

Location of adsorbed species in NO-reduction catalysts by high resolution neutron powder diffraction

International Nuclear Information System (INIS)

Fowkes, A.J.; Rosseinsky, M.J.

1999-01-01

Complete text of publication follows. Catalysts containing copper ion exchanged into zeolites are attracting considerable attention due to their efficiency for both NO decomposition and the selective catalytic reduction of NO x in so-called lean-burn conditions in automotive exhausts. This presentation will describe the application of in-situ high resolution neutron powder diffraction to study active sites in a Cu-zeolite Y catalyst active for NO decomposition. The study under NO pressure reveals the location of two distinct copper sites for sorption. The influence of copper oxidation state on the structure of both the pristine and NO-loaded zeolites will be discussed. (author)

Structure solution from powder neutron and x-ray diffraction data: getting the best of both worlds

International Nuclear Information System (INIS)

Hunter, B.A.

2000-01-01

Full text: Powder diffraction methods have traditionally been used in three main areas: phase identification and quantification, lattice parameter determination and structure refinement. Until recently structure solution has been the almost exclusive domain of single crystal diffraction methods, predominantly using x-rays. The increasing use of synchrotron and neutron sources, and the unrelenting advances in computing hardware and software means that powder methods are challenging single crystal methods as a practical method for structure solution, especially when single crystal method can not be applied. It is known that structural refinements from a known starting structure using combined X-ray and neutron data sets are capable of providing highly accurate structures. Likewise, using combined x-ray and neutron powder diffraction data in the structure solution process should also be a powerful technique, although to date no one is pursuing this methodology. This paper present examples of solutions to the problem. Namely we are using high resolution powder X-ray and neutron methods to solve the structures of molecular materials and minerals, then refining the structures using both sets of data. In this way we exploit the advantages of both methods while minimising the disadvantages. We present our solution for a small amino acid structure, a metalorganic and a mineral structure

Analytical model for neutron diffraction peak shifts due to the surface effect

Czech Academy of Sciences Publication Activity Database

Šaroun, Jan; Kornmeier, J. R.; Hofmann, M.; Mikula, Pavol; Vrána, Miroslav

2013-01-01

Roč. 46, č. 6 (2013), s. 628-638 ISSN 0021-8898 R&D Projects: GA ČR GAP204/10/0654 Institutional support: RVO:61389005 Keywords : residual-stress * neutron diffraction * Monte Carlo simulation Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.950, year: 2013

Use of neutron diffraction in determining strains in high-temperaure superconducting composites

International Nuclear Information System (INIS)

Hitterman, R.L.; Faber, J. Jr.; Kupperman, D.S.; Singh, J.P.; Majumdar, S.

1990-01-01

The Argonne Intense Pulsed Neutron Source and General Purpose Powder Diffractometer have been used to study high T c metal oxide composites composed of yttrium barium copper oxide and silver. Neutron diffraction techniques were applied to composites with 15, 20 and 30% silver content by volume. The authors have observed that after hot pressing, the 30% Ag specimens contained both orthorhombic high T c and tetragonal, non-superconducting phases near the center of the specimens but only tetragonal near the surface. The relationship of shifts in Bragg peaks to strains of the constituents is discussed

Neutron-diffraction measurement of residual stresses in Al-Cu cold-cut welding

Science.gov (United States)

Fiori, F.; Marcantoni, M.

Usually, when it is necessary to join different materials with a large difference in their melting points, welding should be avoided. To overcome this problem we designed and built a device to obtain cold-cut welding, which is able to strongly decrease oxidation problems of the surfaces to be welded. Thanks to this device it is possible to achieve good joining between different pairs of materials (Al-Ti, Cu-Al, Cu-Al alloys) without reaching the material melting point. The mechanical and microstructural characterisation of the joining and the validation of its quality were obtained using several experimental methods. In particular, in this work neutron-diffraction experiments for the evaluation of residual stresses in Cu-Al junctions are described, carried out at the G5.2 diffractometer of LLB, Saclay. Neutron-diffraction results are presented and related to other experimental tests such as microstructural characterisation (through optical and scanning electron microscopy) and mechanical characterisation (tensile-strength tests) of the welded interface.

Neutron-diffraction measurement of residual stresses in Al-Cu cold-cut welding

CERN Document Server

Fiori, F

2002-01-01

Usually, when it is necessary to join different materials with a large difference in their melting points, welding should be avoided. To overcome this problem we designed and built a device to obtain cold-cut welding, which is able to strongly decrease oxidation problems of the surfaces to be welded. Thanks to this device it is possible to achieve good joining between different pairs of materials (Al-Ti, Cu-Al, Cu-Al alloys) without reaching the material melting point. The mechanical and microstructural characterisation of the joining and the validation of its quality were obtained using several experimental methods. In particular, in this work neutron-diffraction experiments for the evaluation of residual stresses in Cu-Al junctions are described, carried out at the G5.2 diffractometer of LLB, Saclay. Neutron-diffraction results are presented and related to other experimental tests such as microstructural characterisation (through optical and scanning electron microscopy) and mechanical characterisation (ten...

Single-crystal neutron diffraction at the Australian Replacement Research Reactor

International Nuclear Information System (INIS)

Klooster, W.T.

2001-01-01

The purpose of the workshop was to: identify the future needs and opportunities for single-crystal neutron diffraction, and specify instrument requirements. important number of experiments. The conclusion of the workshop deliberation was that Australia has a diverse community of users of single-crystal neutron diffraction. A (quasi)-Laue image-plate diffractometer allows the fastest throughput by far, but would exclude an important number of experiments. Most of these could be covered by the additional possibility to locate the image-plate detector on a monochromatic beam. Therefore it was recommend both a white thermal beam and a monochromatic beam (λ= 1 to 2.4 Angstroms) for an image-plate detector. At little additional cost the existing 2TanA instrument could be located semi-permanently on the same monochromatic beam, thus offering three quite different types of single-crystal instruments. Small improvements could be made to the 2TanA instrument to cater for the remaining experiments not suited to an image-plate diffractometer: exchange of the Eulerian cradle for an automated tilt goniometer for extremely bulky sample environment (cryomagnets, large pressure cells), optional larger area detector, analyser crystal. It was recommended that an Instrument Advisory Team will be assembled, and will help in specifying, designing and commissioning the instrument

Direct observation of the near-surface layer in Pb(Mg1/3Nb2/3)O3 using neutron diffraction

International Nuclear Information System (INIS)

Conlon, K.H.; Whan, T.; Fox, J.H.; Luo, H.; Viehland, D.; Li, J.F.; Stock, C.; Shirane, G.

2004-01-01

Spatially resolved neutron diffraction as a function of crystal depth in Pb(Mg 1/3 Nb 2/3 )O 3 reveals the presence of a distinct near-surface region where a strong distortion in the lattice exists. A dramatic change in both the lattice constant and the Bragg peak intensity as a function of crystal depth is observed to occur in this region over a length scale ∼100 μm. This confirms a previous assertion, based on a comparison between high-energy x rays and neutrons, that such a near surface region exists in the relaxors. Consequences to both single crystal and powder diffraction measurements and previous bulk neutron diffraction measurements on large single crystals are discussed

Neutron und X-ray diffraction study on the superstructure of a sodium-rich low plagioclase An sub(16.5)

International Nuclear Information System (INIS)

Joswig, W.; Korekawa, M.

1977-01-01

Neutron and X-ray diffraction experiments had been carried out on a sodium-rich low plagioclase Ansub(16.5) from Sultan Hamud, Kenya. In constrast to previous work very weak (g) reflections (satellites) for all reflections Okl, except reflections 001, could be observed. It is shown that the neutron diffraction method is advantageous to study on submicroscopic periodic domain structure as reported here. (orig.) [de

Through-thickness Residual Stress Measurement by Neutron Diffraction in Cu+W Plasma Spray Coatings

Czech Academy of Sciences Publication Activity Database

Luzin, V.; Matějíček, Jiří; Gnäupel-Herold, T.

2010-01-01

Roč. 652, č. 652 (2010), s. 50-56 ISSN 1662-9752. [International Conference on Mechanical Stress Evaluation by Neutrons and Synchrotron Radiation/5th./. Mito, 10.11.2009-12.11.2009] R&D Projects: GA MŠk ME 901 Institutional research plan: CEZ:AV0Z20430508 Keywords : fusion materials * plasma sprayed coatings * residual stress * neutron diffraction Subject RIV: JG - Metallurgy http://www.scientific.net/MSF.652.50

Neutron diffraction studies on cobalt substituted BiFeO3

Science.gov (United States)

Ray, J.; Biswal, A. K.; Acharya, S.; Babu, P. D.; Siruguri, V.; Vishwakarma, P. N.

2013-02-01

A dilute concentration of single phase Cobalt substituted Bismuth ferrite, BiFe1-XCoXO3; (x=0, 0.02) is prepared by sol-gel auto combustion method. Room temperature neutron diffraction patterns show no change in the crystal and magnetic structure upon cobalt doping. The calculation of magnetic moments shows 3.848 μB for Fe+ and 2.85 μB for Co3+. The cobalt is found to be in intermediate spin state.

Nanocrystallite characterization of milled simulated dry process fuel powders by neutron diffraction

International Nuclear Information System (INIS)

Ryu, Ho Jin; Kang, Kwon Ho; Moon, Je Sun; Song, Kee Chan; Choi, Yong Nam

2003-01-01

The nano-scale crystallite sizes of simulated spent fuel powders were measured by the neutron diffraction line broadening method in order to analyze the sintering behavior of the dry process fuel. The mixed U0 2 and fission product oxide powders were dry-milled in an attritor for 30, 60, and 120 min. The diffraction patterns of the powders were obtained by using the high resolution powder diffractometer in the HANARO research reactor. Diffraction line broadening due to crystallite size was measured using various techniques such as the Stokes' deconvolution, profile fitting methods using Cauchy function, Gaussian function, and Voigt function, and the Warren-Averbach method. The r.m.s. strain, stacking fault, twin and dislocation density were measured using the information from the diffraction pattern. The realistic crystallite size can be obtained after separation of the contribution from the non-uniform strain, stacking fault and twin

Investigation of TbMn2O5 by polarized neutron diffraction.

Science.gov (United States)

Zobkalo, I A; Gavrilov, S V; Sazonov, A; Hutanu, V

2018-05-23

In order to make a new approach to the elucidation of the microscopic mechanisms of multiferroicity in the RMn 2 O 5 family, experiments with different methods of polarized neutrons scattering were performed on a TbMn 2 O 5 single crystal. We employed three different techniques of polarized neutron diffraction without the analysis after scattering, the XYZ-polarization analysis, and technique of spherical neutron polarimetry (SNP). Measurements with SNP were undertaken both with and without external electric field. A characteristic difference in the population of 'right' and 'left' helix domains in all magnetically ordered phases of TbMn 2 O 5 , was observed. This difference can be controlled by an external electric field in the field-cooled mode. The analysis of the results gives an evidence that antisymmetric Dzyaloshinsky-Moria exchange is effective in all the magnetic phases in TbMn 2 O 5 .

Investigation of TbMn2O5 by polarized neutron diffraction

Science.gov (United States)

Zobkalo, I. A.; Gavrilov, S. V.; Sazonov, A.; Hutanu, V.

2018-05-01

In order to make a new approach to the elucidation of the microscopic mechanisms of multiferroicity in the RMn2O5 family, experiments with different methods of polarized neutrons scattering were performed on a TbMn2O5 single crystal. We employed three different techniques of polarized neutron diffraction without the analysis after scattering, the XYZ-polarization analysis, and technique of spherical neutron polarimetry (SNP). Measurements with SNP were undertaken both with and without external electric field. A characteristic difference in the population of ‘right’ and ‘left’ helix domains in all magnetically ordered phases of TbMn2O5, was observed. This difference can be controlled by an external electric field in the field-cooled mode. The analysis of the results gives an evidence that antisymmetric Dzyaloshinsky-Moria exchange is effective in all the magnetic phases in TbMn2O5.

Neutron powder diffraction and theory-aided structure refinement of rubidium and cesium ureate

Energy Technology Data Exchange (ETDEWEB)

Sterri, Kjersti B.; Deringer, Volker L.; Houben, Andreas; Jacobs, Philipp [RWTH Aachen Univ. (Germany). Inst. of Inorganic Chemistry; Kumar, Chogondahalli M.N. [Forschungszentrum Juelich GmbH, Juelich Centre for Neutron Science (JCNS), Outstation at SNS, Oak Ridge National Laboratory, Oak Ridge, TN (United States); Oak Ridge National Laboratory, TN (United States). Chemical and Engineering Materials Div.; Dronskowski, Richard [RWTH Aachen Univ. (Germany). Inst. of Inorganic Chemistry; RWTH Aachen Univ. (Germany). Juelich-Aachen Research Alliance (JARA-HPC)

2016-08-01

Urea (CN{sub 2}H{sub 4}O) is a fundamental biomolecule whose derivatives are abundant throughout chemistry. Among the latter, rubidium ureate (RbCN{sub 2}H{sub 3}O) and its cesium analog (CsCN{sub 2}H{sub 3}O) have been described only very recently and form the first structurally characterized salts of deprotonated urea. Here, we report on a neutron diffraction study on the aforementioned alkaline-metal ureates, which affords the positions for all hydrogen atoms (including full anisotropic displacement tensors) and thus allows us to gain fundamental insights into the hydrogen-bonding networks in the title compounds. The structure refinements of the experimental neutron data proceeded successfully using starting parameters from ab initio simulations of atomic positions and anisotropic displacement parameters. Such joint experimental-theoretical refinement procedures promise significant practical potential in cases where complex solids (organic, organometallic, framework materials) are studied by powder diffraction.

Neutron diffraction study of the β1-β2 transformation in Ta2D

International Nuclear Information System (INIS)

Kaneko, H.; Kajitani, T.; Hirabayashi, M.

1984-01-01

The β 1 -β 2 phase transformation in Ta 2 D was studied by neutron diffraction using the pulsed source at the Tohoku Linac and the Intense Pulsed Neutron Source, Argonne National Laboratory. It was found that the hhO reflections almost disappear in the β 2 phase, whereas the 00l reflections are the same as those in the β 1 phase. The diffraction data show that the β 2 phase has an orthorhombic unit cell which is identical with that of the β 1 phase and contains four tantalum and two deuterium atoms in a volume which is approximately 2sup(1/2) X 1 X 2sup(1/2) that of the b.c.c. host lattice. The deuterium atoms fractionally occupy the tetrahedral sites in alternate (002)sub(orth) planes. (Auth.)

Investigation of the neutron diffraction anomaly and electrical behaviour of α-LiIO3 single crystal under AC field

International Nuclear Information System (INIS)

Wang Guang; Yang Zhen

1990-01-01

A systematic study of the unique neutron diffraction and electric behaviour of α-LiIO 3 single crystal under AC field is reported. A frequency dependent rectification effect was observed and can be explained as the relaxation process in the ionic conduction. Theoretical treatment using Boltzmann equation gives satisfactory agreement with experimental results. The neutron diffraction anomaly can be attributed to the effect of the rectified DC current in the sample

Levitation apparatus for neutron diffraction investigations on high temperature liquids

International Nuclear Information System (INIS)

Hennet, Louis; Pozdnyakova, Irina; Bytchkov, Aleksei; Cristiglio, Viviana; Palleau, Pierre; Fischer, Henry E.; Cuello, Gabriel J.; Johnson, Mark; Melin, Philippe; Zanghi, Didier; Brassamin, Severine; Brun, Jean-Francois; Price, David L.; Saboungi, Marie-Louise

2006-01-01

We describe a new high temperature environment based on aerodynamic levitation and laser heating designed for neutron scattering experiments up to 3000 deg. C. The sample is heated to the desired temperature with three CO 2 lasers from different directions in order to obtain a homogeneous temperature distribution. The apparent temperature of the sample is measured with an optical pyrometer, and two video cameras are employed to monitor the sample behavior during heating. The levitation setup is enclosed in a vacuum-tight chamber, enabling a high degree of gas purity and a reproducible sample environment for structural investigations on both oxide and metallic melts. High-quality neutron diffraction data have been obtained on liquid Y 3 Al 5 O 12 and ZrNi alloy for relatively short counting times (1.5 h)

The chemical reactivity and structure of collagen studied by neutron diffraction

Energy Technology Data Exchange (ETDEWEB)

Wess, T.J.; Wess, L.; Miller, A. [Univ. of Stirling (United Kingdom)

1994-12-31

The chemical reactivity of collagen can be studied using neutron diffraction (a non-destructive technique), for certain reaction types. Collagen contains a number of lysine and hydroxylysine side chains that can react with aldehydes and ketones, or these side chains can themselves be converted to aldehydes by lysyl oxidase. The reactivity of these groups not only has an important role in the maintenance of mechanical strength in collagen fibrils, but can also manifest pathologically in the cases of aging, diabetes (reactivity with a variety of sugars) and alcoholism (reactivity with acetaldehyde). The reactivity of reducing groups with collagen can be studied by neutron diffraction, since the crosslink formed in the adduction process is initially of a Schiff base or keto-imine nature. The nature of this crosslink allows it to be deuterated, and the position of this relatively heavy scattering atom can be used in a process of phase determination by multiple isomorphous replacement. This process was used to study the following: the position of natural crosslinks in collagen; the position of adducts in tendon from diabetic rats in vivo and the in vitro position of acetaidehyde adducts in tendon.

Neutron diffraction study of single crystalline ErCo10Mo2

International Nuclear Information System (INIS)

Janssen, Y.; De Boer, F.R.; Brueck, E.; Tegus, O.; Ma, L.; Buschow, K.H.J.; Reehuis, M.

1999-01-01

Complete text of publication follows. The ferrimagnetic intermetallic compound ErCo 10 Mo 2 (Tc = 600 K) crystallizes in the tetragonal ThMn 12 -type structure (space group 14/mmm). The Co and Mo atoms may share three crystallographic sites (8f, 8i and 8j). Earlier neutron powder diffraction experiments show that Mo has a strong preference for the 8i-site and that the magnetic ordering at low temperature is planar. Furthermore ErCo 10 Mo 2 has been reported to show one [2] or more [3] spin-reorientation transitions from planar to axial magnetic ordering. Recently we succeeded in growing a single-crystalline sample of ErCo 10 Mo 2 . Magnetic measurements in 1T show one spin-reorientation transition at about 135 K. Neutron diffraction experiments were performed to investigate a possible link between the magnetic properties and the site occupation by Mo. Our results show that our sample has the Mo atoms exclusively occupying half the 8i-sites. There is no evidence for a crystallographic superstructure. Furthermore, below 150 K some reflections strongly increase due to the growing Er magnetic moment. (author)

In situ observation and neutron diffraction of NiTi powder sintering

International Nuclear Information System (INIS)

Chen, Gang; Liss, Klaus-Dieter; Cao, Peng

2014-01-01

This study investigated NiTi powder sintering behaviour from elemental powder mixtures of Ni/Ti and Ni/TiH 2 using in situ neutron diffraction and in situ scanning electron microscopy. The sintered porous alloys have open porosities ranging from 2.7% to 36.0%. In comparison to the Ni/Ti compact, dehydrogenation occurring in the Ni/TiH 2 compact leads to less densification yet higher chemical homogenization only after high-temperature sintering. For the first time, direct evidence of the eutectoid phase transformation of NiTi at 620 °C is reported by in situ neutron diffraction. A comparative study of cyclic stress–strain behaviours of the porous NiTi alloys made from Ni/Ti and Ni/TiH 2 compacts indicate that the samples sintered from the Ni/TiH 2 compact exhibited a much higher porosity, larger pore size, lower fracture strength, lower close-to-overall porosity ratio and lower Young’s modulus. Instead of enhanced densification by the use of TiH 2 as reported in the literature, this study shows an adverse effect of TiH 2 on powder densification in NiTi

The chemical reactivity and structure of collagen studied by neutron diffraction

International Nuclear Information System (INIS)

Wess, T.J.; Wess, L.; Miller, A.

1994-01-01

The chemical reactivity of collagen can be studied using neutron diffraction (a non-destructive technique), for certain reaction types. Collagen contains a number of lysine and hydroxylysine side chains that can react with aldehydes and ketones, or these side chains can themselves be converted to aldehydes by lysyl oxidase. The reactivity of these groups not only has an important role in the maintenance of mechanical strength in collagen fibrils, but can also manifest pathologically in the cases of aging, diabetes (reactivity with a variety of sugars) and alcoholism (reactivity with acetaldehyde). The reactivity of reducing groups with collagen can be studied by neutron diffraction, since the crosslink formed in the adduction process is initially of a Schiff base or keto-imine nature. The nature of this crosslink allows it to be deuterated, and the position of this relatively heavy scattering atom can be used in a process of phase determination by multiple isomorphous replacement. This process was used to study the following: the position of natural crosslinks in collagen; the position of adducts in tendon from diabetic rats in vivo and the in vitro position of acetaidehyde adducts in tendon

Neutron-diffraction studies of the nuclear magnetic phase diagram of copper

DEFF Research Database (Denmark)

Annila, A.J.; Clausen, Kurt Nørgaard; Oja, A.S.

1992-01-01

We have studied the spontaneous antiferromagnetic (AF) order in the nuclear spin system of copper by use of neutron-diffraction experiments at nanokelvin temperatures. Copper is an ideal model system as a nearest-neighbor-dominated spin-3/2 fcc antiferromagnet. The phase diagram has been investig......We have studied the spontaneous antiferromagnetic (AF) order in the nuclear spin system of copper by use of neutron-diffraction experiments at nanokelvin temperatures. Copper is an ideal model system as a nearest-neighbor-dominated spin-3/2 fcc antiferromagnet. The phase diagram has been...... investigated by measuring the magnetic-field dependence of the (100) reflection, characteristic of a type-I AF structure, and of a Bragg peak at (0 2/3 2/3). The results suggest the presence of high-field (100) phases at 0.12 less-than-or-equal-to B less-than-or-equal-to B(c) almost-equal-to 0.26 mT, for B...... compared with results of earlier susceptibility measurements in order to identify the translational periods of the three previously found antiferromagnetic phases for B parallel-to [100]. Recent theoretical work has yielded results in agreement with our experimental data....

Neutron activation analysis (NAA), radioisotope production via neutron activation (PNA) and fission product gas-jet (GJA)

Energy Technology Data Exchange (ETDEWEB)

Gaeggeler, H W [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

1996-11-01

Three different non-diffractive applications of neutrons are outlined, neutron activation analysis, production of radionuclides, mostly for medical applications, and production of short-lived fission nuclides with a so-called gas-jet. It is shown that all three devices may be incorporated into one single insert at SINQ due to their different requests with respect to thermal neutron flux. Some applications of these three facilities are summarized. (author) 3 figs., 1 tab., 8 refs.

Neutron activation analysis (NAA), radioisotope production via neutron activation (PNA) and fission product gas-jet (GJA)

International Nuclear Information System (INIS)

Gaeggeler, H.W.

1996-01-01

Three different non-diffractive applications of neutrons are outlined, neutron activation analysis, production of radionuclides, mostly for medical applications, and production of short-lived fission nuclides with a so-called gas-jet. It is shown that all three devices may be incorporated into one single insert at SINQ due to their different requests with respect to thermal neutron flux. Some applications of these three facilities are summarized. (author) 3 figs., 1 tab., 8 refs

Condensed matter and materials research using neutron diffraction and spectroscopy: reactor and pulsed neutron sources

International Nuclear Information System (INIS)

Bisanti, Paola; Lovesey, S.W.

1987-05-01

The paper provides a short, and partial view of the neutron scattering technique applied to condensed matter and materials research. Reactor and accelerator-based neutron spectrometers are discussed, together with examples of research projects that illustrate the puissance and modern applications of neutron scattering. Some examples are chosen to show the range of facilities available at the medium flux reactor operated by Casaccia ENEA, Roma and the advanced, pulsed spallation neutron source at the Rutherford Appleton Laboratory, Oxfordshire. (author)

Applications of neutron irradiation

International Nuclear Information System (INIS)

Ito, Yasuo

1999-01-01

The present state of art of applications of neutron irradiation is overviewed taking neutron activation analysis, prompt gamma-ray analysis, fission/alpha track methods, boron neutron capture therapy as examples. What is common among them is that the technologies are nearly matured for wide use by non- nuclear scientists. But the environment around research reactors is not prospective. These applications should be encouraged by incorporating in the neutron science society. (author)

Neutron diffraction by monocrystals of inorganic and elementary organic compounds

International Nuclear Information System (INIS)

Becker, G.; Hauser, H.D.

1992-01-01

The phase of preparation and X-ray structural analysis of the compounds has been completed following the synthetical preparation of compounds sensitive to oxidation and pyrolysis, in this case: phosphonic acid, potassium silanide, lithium dihydrogenphosphide * DME, bis[lithium-tri(tert.butyl)alanate], dibromophenylbismuthate, potassium tetrahydride aluminate, and phosphinic acid. The work was started is neutron diffraction experiments for detecting the positions of the hydrogen and carbon atoms, in order to analyse space group problems. (BBR) [de

Sample positioning in neutron diffraction experiments using a multi-material fiducial marker

Energy Technology Data Exchange (ETDEWEB)

Marais, D., E-mail: Deon.Marais@necsa.co.za [Research and Development Division, South African Nuclear Energy Corporation (Necsa) SOC Limited, PO Box 582, Pretoria 0001 (South Africa); School of Mechanical and Nuclear Engineering, North-West University, Potchefstroom 2520 (South Africa); Venter, A.M., E-mail: Andrew.Venter@necsa.co.za [Research and Development Division, South African Nuclear Energy Corporation (Necsa) SOC Limited, PO Box 582, Pretoria 0001 (South Africa); Faculty of Agriculture Science and Technology, North-West University, Mahikeng 2790 (South Africa); Markgraaff, J., E-mail: Johan.Markgraaff@nwu.ac.za [School of Mechanical and Nuclear Engineering, North-West University, Potchefstroom 2520 (South Africa); James, J., E-mail: Jon.James@open.ac.uk [Faculty of Mathematics, Computing and Technology, The Open University, Milton Keynes, MK76AA England (United Kingdom)

2017-01-01

An alternative sample positioning method is reported for use in conjunction with sample positioning and experiment planning software systems deployed on some neutron diffraction strain scanners. In this approach, the spherical fiducial markers and location trackers used with optical metrology hardware are replaced with a specifically designed multi-material fiducial marker that requires one diffraction measurement. In a blind setting, the marker position can be determined within an accuracy of ±164 µm with respect to the instrument gauge volume. The scheme is based on a pre-determined relationship that links the diffracted peak intensity to the absolute positioning of the fiducial marker with respect to the instrument gauge volume. Two methods for establishing the linking relationship are presented, respectively based on fitting multi-dimensional quadratic functions and a cross-correlation artificial neural network.

Evaluation of material properties of SiC particle reinforced aluminum alloy composite using neutron and X-ray diffraction

International Nuclear Information System (INIS)

Akiniwa, Yoshiaki; Machiya, Shutaro; Kimura, Hidehiko; Tanaka, Keisuke; Minakawa, Nobuaki; Morii, Yukio; Kamiyama, Takashi

2006-01-01

The phase stresses under loading in a monolithic aluminum alloy and an aluminum alloy reinforced with silicon carbide particles were measured by the neutron diffraction method. Under uniaxial loading, the longitudinal and transverse strains in each constituent phase were measured. The diffraction elastic constants for each diffraction plane were investigated as a function of the diffraction intensity by TOF. Single peak analysis was carried out for each diffraction profile. The measured results were compared with the theoretical micromechanical models such as the self-consistent and Mori-Tanaka method using the Eshelby theory (MTE). The accuracy of the elastic constant strongly depends on the diffraction intensity. In order to confirm the rule of mixture, the phase stress was measured by the X-ray method. The macrostress calculated by the rule of mixture agreed very well with the applied stress. Finally, fatigue damage was evaluated by the neutron method. The change of the full width at half maximum in the aluminum phase during fatigue is small. On the other hand, the value in the SiC phase increased steeply just before fracture

Application of a high-temperature neutron diffraction apparatus to the study of refractory oxides

International Nuclear Information System (INIS)

Aldebert, P.; Badie, J.-M.; Buevoz, J.-L.; Roult, G.

1975-01-01

A furnace allowing studies of refractory materials by neutron diffraction in situ up to 2500 deg C is described. It is fitted on to a new type of time of flight spectrometer the pulsed source of which is given by a correlation chopper. The advantages of this technique in comparison with fixed-wavelength goniometers are developped. The examination at high temperature of several refractory oxides has been carried out with this experimental device. The thermal expansion curve of α alumina has been established with accuracy up to near the melting point. Several high temperature cristalline forms, X form La 2 O 3 , the tetragonal and cubic ZrO 2 , tetragonal HfO 2 , have been studied. Concerning the latter two, the case of their solid solutions 2MO 2 -M' 2 O 3 (with M=Hf or Zr and M'=La or Y) has also been considered, at room temperature only [fr

In situ neutron diffraction study of grain-orientation-dependent phase transformation in 304L stainless steel at a cryogenic temperature

International Nuclear Information System (INIS)

Tao Kaixiang; Wall, James J.; Li, Hongqi; Brown, Donald W.; Vogel, Sven C.; Choo, Hahn

2006-01-01

In situ time-of-flight neutron diffraction was performed to investigate the martensitic phase transformation during quasistatic uniaxial compression testing of 304L stainless steel at 300 and 203 K. In situ neutron diffraction enabled the bulk measurement of intensity evolution for various hkl atomic planes during the austenite (fcc) to martensite (hcp and bcc) phase transformation. Based on the neutron diffraction patterns, the martensite phases were observed from the very beginning of the plastic deformation at 203 K. However, at 300 K, no newly formed martensite, except a small amount of preexisting hcp phase, was observed throughout the test. From the changes in the relative intensities of individual hkl atomic planes, the grain-orientation-dependent phase transformation was investigated. The preferred orientation of the newly formed martensite grains was also investigated for the sample deformed at 203 K using neutron diffraction. The results reveal the orientation relationships between the austenite and the newly formed martensites. The fcc grain family diffracting with (200) plane normal parallel to the loading axis is favored for the fcc to bcc transformation and the bcc (200) plane normals are primarily aligned along the loading direction. For the fcc to hcp transformation, the fcc grains with (111) plane normals at an angle in between about 10 deg. and 50 deg. to the loading direction are favored

Diffraction. Powder, amorphous, liquid

International Nuclear Information System (INIS)

Sosnowska, I.M.

1999-01-01

Neutron powder diffraction is a unique tool to observe all possible diffraction effects appearing in crystal. High-resolution neutron diffractometers have to be used in this study. Analysis of the magnetic structure of polycrystalline materials requires the use of high-resolution neutron diffraction in the range of large interplanar distances. As distinguished from the double axis diffractometers (DAS), which show high resolution only at small interplanar distances, TOF (time-of-flight) diffractometry offers the best resolution at large interplanar distances. (K.A.)

Crystallite Size and Microstrain Measurement of Cathode Material after Mechanical Milling using Neutron Diffraction Technique

Directory of Open Access Journals (Sweden)

A. Fajar

2010-12-01

Full Text Available The measurements of neutron diffraction patterns of commercially product and 10 hour mechanically milled cathode material lithium cobaltites (LiCoO2 have been performed. Rietveld analysis using FullProf does not show the change of crystal structure due to milling process, but the diffraction pattern has a lower intensity and the diffraction-line was broadening. The results of line-broadening study on milled sample using Rietveld methods detected that the microstrain was occurred in the sample with value 0.127080(35 % and the average crystallite size was 424.78(20 Å.

Diffractive optics for industrial and commercial applications

Energy Technology Data Exchange (ETDEWEB)

Turunen, J. [Joensuu Univ. (Finland); Wyrowski, F. [eds.] [Jena Univ. (Germany)

1997-12-31

The following topics were dealt with: diffractive optics, diffraction gratings, optical system design with diffractive optics, continuous-relief diffractive lenses and microlens arrays, diffractive bifocal intraocular lenses, diffractive laser resonators, diffractive optics for semiconductor lasers, diffractive elements for optical image processing, photorefractive crystals in optical measurement systems, subwavelenth-structured elements, security applications, diffractive optics for solar cells, holographic microlithography. 999 refs.

A short note on physical properties to irradiated nuclear fuel by means of X-ray diffraction and neutron scattering techniques

Energy Technology Data Exchange (ETDEWEB)

Abdullah, Yusof, E-mail: yusofabd@nuclearmalaysia.gov.my; Husain, Hishamuddin; Hak, Cik Rohaida Che; Alias, Nor Hayati; Yusof, Mohd Reusmaazran; Kasim, Norasiah Ab; Zali, Nurazila Mat [Malaysian Nuclear Agency, Bangi, Kajang 43000, Selangor (Malaysia); Mohamed, Abdul Aziz [College of Engineering, Universiti Tenaga National, Jalan Ikram-Uniten, 43000 Kajang, Selangor (Malaysia)

2015-04-29

For nuclear reactor applications, understanding the evolution of the fuel materials microstructure during irradiation are of great importance. This paper reviews the physical properties of irradiated nuclear fuel analysis which are considered to be of most importance in determining the performance behavior of fuel. X-rays diffraction was recognize as important tool to investigate the phase identification while neutron scattering analyses the interaction between uranium and other materials and also investigation of the defect structure.

Preliminary neutron diffraction analysis of challenging human manganese superoxide dismutase crystals.

Science.gov (United States)

Azadmanesh, Jahaun; Trickel, Scott R; Weiss, Kevin L; Coates, Leighton; Borgstahl, Gloria E O

2017-04-01

Superoxide dismutases (SODs) are enzymes that protect against oxidative stress by dismutation of superoxide into oxygen and hydrogen peroxide through cyclic reduction and oxidation of the active-site metal. The complete enzymatic mechanisms of SODs are unknown since data on the positions of hydrogen are limited. Here, methods are presented for large crystal growth and neutron data collection of human manganese SOD (MnSOD) using perdeuteration and the MaNDi beamline at Oak Ridge National Laboratory. The crystal from which the human MnSOD data set was obtained is the crystal with the largest unit-cell edge (240 Å) from which data have been collected via neutron diffraction to sufficient resolution (2.30 Å) where hydrogen positions can be observed.

Neutron diffraction study of TiCxNyHz

International Nuclear Information System (INIS)

Khidirov, I.

1996-01-01

Neutron diffraction study of titanium carbonitridohydride is carried out. It is shown that TiC x N y H z may have a disordered, on ordered and a partially ordered structure depending on the composition. Both in the ordered and in the disordered structure the atoms of carbon and nitrogen are located in octahedron interstices only. Under (C+N)/Ti > 0.70 the atoms of hydrogen are located in octahedron interstices only. Under (C+N)/Ti < 0.50 and under high temperatures the atoms of hydrogen occupy both octahedron and tetrahedron interstices; under low temperatures the transition of some hydrogen atoms from tetrahedron into octahedron interstices is observed. 15 refs.; 1 fig.; 1 tab

A neutron diffraction study of ancient Greek ceramics

International Nuclear Information System (INIS)

Siouris, I.M.; Walter, J.

2006-01-01

Non-destructive neutron diffraction studies were performed on three 2nd-century BC archaeological pottery fragments from the excavation site of Neos Scopos, Serres, in North Greece. In all the 273 K diagrams quartz and feldspars phase fractions are dominant. Diopside and iron oxide phases were also identifiable. The diopside content is found to decrease with increasing quartz-feldspar compositions. Iron oxides containing minerals were found to be present and the phase compositions reflect upon the coloring of the samples. However, the different content compositions of the phases may suggest different regions of the original clay materials as well as different preparation techniques. The firing temperatures were determined to be in the range of 900-1000 deg. C

Characterisation of polycrystal deformation by numerical modelling and neutron diffraction measurements

International Nuclear Information System (INIS)

Clausen, B.

1997-09-01

The deformation of polycrystals are modelled using three micron mechanic models; the Taylor model, the Sachs model and Hutchinson's self-consistent (SC) model. The predictions of the rigid plastic Taylor and Sachs models are compared with the predictions of the SC model. As expected, the results of the SC model is about half-way between the upper- and lower-bound models. The influence of the elastic anisotropy is investigated by comparing the SC predictions for aluminium, copper and a hypothetical material (Hybrid) with the elastic anisotropy of copper and the Young's modulus and hardening behaviour of aluminium. It is concluded that the effect of the elastic anisotropy is limited to the very early stages of plasticity, as the deformation pattern is almost identical for the three materials at higher strains. The predictions of the three models are evaluated by neutron diffraction measurements of elastic lattice strains in grain sub-sets within the polycrystal. The two rigid plastic models do not include any material parameters and therefore the predictions of the SC model is more accurate and more detailed than the predictions of the Taylor and Sachs models. The SC model is used to determine the most suitable reflection for technological applications of neutron diffraction, where focus is on the volume average stress state in engineering components. To be able to successfully to convert the measured elastic lattice strains for a specific reflection into overall volume average stresses, there must be a linear relation between the lattice strain of the reflection and the overall stress. According to the model predictions the 311-reflection is the most suitable reflection as it shows the smallest deviations from linearity and thereby also the smallest build-up of residual strains. The model predictions have pin pointed that the selection of the reflection is crucial for the validity of stresses calculated from the measured elastic lattice strains. (au) 14 tabs., 41

Membrane structure: neutron diffraction and small angle scattering studies

International Nuclear Information System (INIS)

Zaccai, G.

1985-01-01

The author considers a molecule in a beam of radiation of wavelength lambda. Two extreme ways are shown in which on can have many identical molecules in a sample: a crystal in which they are related to each other by the symmetry of a lattice, and complete disorder in which there is no correlation between molecules. The detailed crystallographic analysis of isomorphous replacement is examined. Neutron diffraction experiments with specific deuteration are performed to characterize interactions of cholesterol with lipid bilayers. Retinal rod outer segment disk membranes and the purple membrane of H. halobium are examined

Neutrons for materials science

International Nuclear Information System (INIS)

Windsor, C.G.; Allen, A.J.; Hutchings, M.T.; Sayers, C.M.; Sinclair, R.N.; Schofield, P.; Wright, C.J.

1984-12-01

The discussion will be limited to applied materials research performed on a customer/contractor basis. The information obtained using neutrons must therefore compete both scientifically and financially with information obtained using other techniques, particularly electron microscopy, X-ray, NMR, infra-red and Raman spectroscopy. It will be argued that the unique nature of the information gained from neutrons often outweighs the undoubted difficulties of access to neutron beams. Examples are given. Small angle scattering has emerged as the neutron technique of widest application in applied materials research. The penetration of neutron beams through containment vessels, as well as through the sample, allows the measurement of 'in situ' time dependent experiments within a furnace, cryostat, pressure vessel or chemical reactor vessel. High resolution powder diffraction is another technique with wide applications. Structural studies are possible on increasing complex phases. The structure and volume fraction of minority phases can be measured at levels appreciably below that possible by X-ray diffraction. A rapidly growing field at present is the measurement of internal strains through the small shifts in lattice spacing. Inelastic scattering measurements exploit the unique property of neutrons to measure the orientations of vibrating molecules. (author)

Structure of molten TbCl sub 3 measured by neutron diffraction

CERN Document Server

Martin, R A; Barnes, A C; Cuello, G J

2002-01-01

The total structure factor of molten TbCl sub 3 at 617 deg. C was measured by using neutron diffraction. The data are in agreement with results from previous experimental work but the use of a diffractometer having an extended reciprocal-space measurement window leads to improved resolution in real space. Significant discrepancies with the results obtained from recent molecular dynamics simulations carried out using a polarizable ion model, in which the interaction potentials were optimized to enhance agreement with previous diffraction data, are thereby highlighted. It is hence shown that there is considerable scope for the development of this model for TbCl sub 3 and for other trivalent metal halide systems spanning a wide range of ion size ratios. (letter to the editor)

Neutron Optics: Towards Applications for Hot Neutrons

International Nuclear Information System (INIS)

Schanzer, C; Schneider, M; Böni, P

2016-01-01

Supermirrors with large critical angles of reflection, i.e. large index m are an essential ingredient to transport, focus and polarise neutrons over a wide range of energy. Here we summarise the recent developments of supermirror with very large critical angles of reflection and high reflectivity that were conducted at SwissNeutronics as well as their implementation in devices. Approaching critical angles m = 8 times the critical angle of natural nickel makes new applications possible and extends the use of reflection optics towards the regime of hot and epithermal neutrons. Based on comparisons of simulations with experiment we demonstrate future possibilities of applications of large-m supermirrors towards devices for neutrons with short wavelength. (paper)

Neutrons for materials science

International Nuclear Information System (INIS)

Windsor, C.G.; Allen, A.J.; Hutchings, M.T.; Sayers, C.M.; Sinclair, R.N.; Schofield, P.; Wright, C.J.

1985-01-01

The discussion will be limited to applied materials research performed on a customer/contractor basis. The information obtained using neutrons must therefore compete both scientifically and financially with information obtained using other techniques, particular electron microscopy, X-ray, NMR, infra-red and Raman spectroscopy. It will be argued that the unique nature of the information gained from neutrons often outweighs the undoubted difficulties of access to neutron beams. Small-angle scattering has emerged as the neutron technique of widest application in applied materials research. The penetration of neutron beams through containment vessels, as well as through the sample, allows the measurement of in situ time-dependent experiments within a furnace, cryostat, pressure vessel or chemical reactor vessel. Examples will be given of small-angle scattering projects from the nuclear metallurgy, coal, oil, cement, detergent and plastics industries. High-resolution powder diffraction is another technique with wide applications. Structural studies are possible on increasingly complex phases. The structure and volume fraction of minority phase can be measured at levels appreciably below that possible by X-ray diffraction. A rapidly growing field at present is the measurement of internal strains through the small shifts in lattice spacing. Neutron diffraction is unique in being able to measure the full strain tensor from a specified volume within a bulk specimen. Inelastic scattering measurements exploit the unique property of neutrons to measure the orientations of vibrating molecules. Examples will be chosen from the field of catalysis where inelastic spectroscopy has revealed the nature of the bonding of hydrocarbon molecules. (author)

Phase separation and magnetic ordering studied by high resolution neutron diffraction

International Nuclear Information System (INIS)

Caspi, E.N.; Melamud, M.; Pinto, H.; Shaked, H.; Chmaissem, O.; Jorgensen, J.D.; Short, S.

1999-01-01

Complete text of publication follows. In a previous work on the (U 1-x Nd x )Co 2 Ge 2 system, two magnetic transitions were observed in the temperature dependencies of the magnetic susceptibility and in the intensity of the magnetic reflections in neutron diffraction [1]. Because of insufficient resolution, it was not clear whether this is due to clustering or phase separation. In both cases the U-rich regions are expected to order magnetically at higher temperature than the U-poor ones, resulting in two magnetic transitions. In order to resolve this question a temperature dependent TOF neutron diffraction of the x = 0.25 compound has been performed on the SEPD at Argonne's IPNS [2]. The temperature dependent diffractograms were refined by the Rietveld method. It was found that the compound separates into two phases: x = 0.4 (55 wt%) and x = 0.1 (45 wt%). The temperature dependence of the magnetic moment was obtained for each phase, with the transition temperatures: T N (x=0.4) = 130 K, and T N (x=0.1) = 165 K. (author) [1] E. Caspi et al., Phys. Rev. B, 57 (198) 449.; [2] J.D. Jorgensen et al., J. Appl. Cryst. 22 (1989) 321

Measurement of the velocity of sound in crystals by pulsed neutron diffraction

International Nuclear Information System (INIS)

Willis, B.T.M.; Carlile, C.J.; Ward, R.C.; David, W.I.F.; Johnson, M.W.

1986-03-01

The diffraction method of observing elementary excitations in crystals has been applied to the study of one-phonon thermal diffuse scattering from pyrolytic graphite on a high resolution pulsed neutron diffractometer. The variation of the phase velocity of sound as a function of direction in the crystal and efficient method of determining sound velocities in crystals under extreme conditions. (author)

Neutron diffraction study on the medium and short-range order of ternary chalcogenide glasses

Czech Academy of Sciences Publication Activity Database

Neov, S.; Gerasimova, I.; Skordeva, E.; Arsova, D.; Pamukchieva, V.; Mikula, Pavol; Lukáš, Petr; Sonntag, R.

1999-01-01

Roč. 34, - (1999), s. 3669-3676 ISSN 0022-2461 R&D Projects: GA ČR GV202/97/K038 Keywords : neutron diffraction * short-range order * chalcogenide glasses Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 0.786, year: 1999

Kinetic neutron diffraction and SANS studies of phase formation in bioactive machinable glass ceramics

International Nuclear Information System (INIS)

Bentley, P M; Kilcoyne, S H; Bubb, N L; Ritter, C; Dewhurst, C D; Wood, D J

2007-01-01

Bioactive fluormica-fluorapatite glass-ceramic materials offer a very encouraging solution to the problem of efficient restoration and reconstruction of hard tissues. To produce material with the desired crystalline phases, a five-stage heat treatment must be performed. This thermal processing has a large impact on the microstructure and ultimately the final mechanical properties of the materials. We have examined the thermal processing of one of our most promising machinable biomaterials, using time-resolved small angle neutron scattering and neutron diffraction to study the nucleation and growth of crystallites. The processing route had already been optimized by studying the properties of quenched samples using x-ray diffraction, mechanical measurements and differential thermal analysis. However these results show that the heat treatment can be further optimized in terms of crystal nucleation, and we show that these techniques are the only methods by which a truly optimized thermal processing route may be obtained

A flow-through hydrothermal cell for in situ neutron diffraction studies of phase transformations

International Nuclear Information System (INIS)

O'Neill, Brian; Tenailleau, Christophe; Nogthai, Yung; Studer, Andrew; Brugger, Joel; Pring, Allan

2006-01-01

A flow-through hydrothermal cell for the in situ neutron diffraction study of crystallisation and phase transitions has been developed. It can be used for kinetic studies on materials that exhibit structural transformations under hydrothermal conditions. It is specifically designed for use on the medium-resolution powder diffractometer (MRPD) at ANSTO, Lucas Heights, Sydney. But it is planned to adapt the design for the Polaris beamline at ISIS and the new high-intensity powder diffractometer (Wombat) at the new Australian reactor Opal. The cell will operate in a flow-through mode over the temperature range from 25-300 deg. C and up to pressures of 100 bar. The first results of a successful transformation of pentlandite (Fe,Ni) 9 S 8 to violarite (Fe,Ni) 3 S 4 under mild conditions (pH∼4) at 120 deg. C and 3 bar using in situ neutron diffraction measurements are presented

Determination of the hexagonal network parameters of the quartz β using neutron multiple diffraction

International Nuclear Information System (INIS)

Campos, L.C.; Parente, C.B.R.; Mazzocchi, V.L.; Helene, O.

2000-01-01

In this work, neutron multiple diffraction is employed for the determination of the parameters a and c of the β-quartz hexagonal cell. This crystalline phase of silica (SiO 2 ) occurs in temperatures between ca. 846 and 1143 K. A β-quartz neutron multiple diffraction pattern has been used in the determinations. This pattern was obtained with a natural quartz single crystal heated to 1003 K. During the indexing of the pattern it was verified that most of the pairs of secondary reflections, which are responsible for the formation of peaks, could be classified as 'good for the determination of a' or 'good for the determination of c'. With this classification, it became possible to employ an iterative method for the determination of both parameters. After 8 cycles of iteration the values found for the parameters were a = 4.9964 +- 0.0018 and c = 5.46268 +- 0.00052 A. (author)

Thermodynamic modelling and in-situ neutron diffraction investigation of the (Ce + Mg + Zn) system

International Nuclear Information System (INIS)

Zhu, Zhijun; Gharghouri, Michael A.; Medraj, Mamoun; Lee, Soo Yeol; Pelton, Arthur D.

2016-01-01

Highlights: • All phase diagram and thermodynamic data critically assessed for the (Ce + Mg + Zn) system. • All phases described by optimized thermodynamic models. • In-situ neutron diffraction performed to identify phases and transition temperatures. • Assessments of other (RE + Mg + Zn) systems have been carried out simultaneously. • The final product is a thermodynamic database for multicomponent (Mg + RE + Zn) systems. - Abstract: All available phase diagram data for the (Ce + Mg + Zn) system were critically assessed. In-situ neutron diffraction (ND) experiments were performed on selected samples to identify phases and transition temperatures. A critical thermodynamic evaluation and optimization of the (Ce + Mg + Zn) system were carried out and model parameters for the thermodynamic properties of all phases were obtained. The phase transformation behaviour of selected samples was well resolved from the ND experiments and experimental data were used to refine the thermodynamic model parameters.

Neutron diffraction for studying the influence of the relative humidity on the carbonation process of cement pastes

International Nuclear Information System (INIS)

Galan, I; Andrade, C; Castellote, M; Rebolledo, N; Sanchez, J; Toro, L; Puente, I; Campo, J; Fabelo, O

2011-01-01

The effect of humidity on hydrated cement carbonation has been studied by means of in-situ neutron diffraction measurements. The evolution of the main crystalline phases in the bulk of the sample, portlandite and calcite, has been monitored during the process. Data obtained from neutron diffraction allow the quantification of the phases involved. The results highlight the great influence of humidity on carbonation. At very low humidity there are almost no changes. Between 53 and 75% relative humidity, portlandite decrease and calcite increase data can be fitted to exponential decay functions. At very high humidity portlandite remains nearly constant while calcite increases slightly with time, almost linearly.

Neutron diffraction from the vortex lattice in the heavy-fermion superconductor UPt3

DEFF Research Database (Denmark)

Kleiman, R.N.; Broholm, C.; Aeppli, G.

1992-01-01

We have used neutron diffraction to observe the vortex lattice of UPt3. This is the first such measurement in a heavy-fermion system, a superconductor below 1 K, or in a system with such a long magnetic penetration depth (6000 +/- 75 angstrom). It also provides the first value for the pair...

The structure of molten CuCl, CuI and their mixtures as investigated by using neutron diffraction

International Nuclear Information System (INIS)

Drewitt, James W E; Salmon, Philip S; Takeda, Shin'ichi; Kawakita, Yukinobu

2009-01-01

The structure of molten CuCl, CuI and their mixtures (CuCl) x (CuI) 1-x with x = 0.294, 0.576, 0.801 was studied by using neutron diffraction. The results are discussed by reference to the information that is available on the structure of CuCl and CuI from experiment, theory and computer simulation. The comparison points to a need for more realistic models for the CuCl-CuI system which should take into account the presence of chemical bonds that have been found in CuI by the application of ab initio molecular dynamics methods.

Real Structure and Resudal Stresses in Advanced Welds Determined by X-ray and Neutron Diffraction

Czech Academy of Sciences Publication Activity Database

Trojan, K.; Hervoches, Charles; Ganev, N.; Mikula, Pavol; Čapek, J.

2017-01-01

Roč. 9, SEP (2017), s. 32-38 E-ISSN 2336-5382 R&D Projects: GA MŠk LM2015056; GA ČR GB14-36566G Institutional support: RVO:61389005 Keywords : laser and MAG welding * residual stresses * X-ray diffraction * neutron diffraction Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) https://ojs.cvut.cz/ojs/index.php/APP/article/view/4401/4298

Fluid bilayer structure determination: Joint refinement in composition space using X-ray and neutron diffraction data

Energy Technology Data Exchange (ETDEWEB)

White, S.H. [Univ. of California, Irvine, CA (United States); Wiener, M.C. [Univ. of California, San Francisco, CA (United States)

1994-12-31

Experimentally-determined structural models of fluid lipid bilayers are essential for verifying molecular dynamics simulations of bilayers and for understanding the structural consequences of peptide interactions. The extreme thermal motion of bilayers precludes the possibility of atomic-level structural models. Defining {open_quote}the structure{close_quote} of a bilayer as the time-averaged transbilayer distribution of the water and the principal lipid structural groups such as the carbonyls and double-bonds (quasimolecular fragments), one can represent the bilayer structure as a sum of Gaussian functions referred to collectively as the quasimolecular structure. One method of determining the structure is by neutron diffraction combined with exhaustive specific deuteration. This method is impractical because of the expense of the chemical syntheses and the limited amount of neutron beam time currently available. We have therefore developed the composition space refinement method for combining X-ray and minimal neutron diffraction data to arrive at remarkably detailed and accurate structures of fluid bilayers. The composition space representation of the bilayer describes the probability of occupancy per unit length across the width of the bilayer of each quasimolecular component and permits the joint refinement of X-ray and neutron lamellar diffraction data by means of a single quasimolecular structure that is fitted simultaneously to both data sets. Scaling of each component by the appropriate neutron or X-ray scattering length maps the composition-space profile to the appropriate scattering length space for comparison to experimental data. The difficulty with the method is that fluid bilayer structures are generally only marginally determined by the experimental data. This means that the space of possible solutions must be extensively explored in conjunction with a thorough analysis of errors.

Fluid bilayer structure determination: Joint refinement in composition space using X-ray and neutron diffraction data

International Nuclear Information System (INIS)

White, S.H.; Wiener, M.C.

1994-01-01

Experimentally-determined structural models of fluid lipid bilayers are essential for verifying molecular dynamics simulations of bilayers and for understanding the structural consequences of peptide interactions. The extreme thermal motion of bilayers precludes the possibility of atomic-level structural models. Defining open-quote the structure close-quote of a bilayer as the time-averaged transbilayer distribution of the water and the principal lipid structural groups such as the carbonyls and double-bonds (quasimolecular fragments), one can represent the bilayer structure as a sum of Gaussian functions referred to collectively as the quasimolecular structure. One method of determining the structure is by neutron diffraction combined with exhaustive specific deuteration. This method is impractical because of the expense of the chemical syntheses and the limited amount of neutron beam time currently available. We have therefore developed the composition space refinement method for combining X-ray and minimal neutron diffraction data to arrive at remarkably detailed and accurate structures of fluid bilayers. The composition space representation of the bilayer describes the probability of occupancy per unit length across the width of the bilayer of each quasimolecular component and permits the joint refinement of X-ray and neutron lamellar diffraction data by means of a single quasimolecular structure that is fitted simultaneously to both data sets. Scaling of each component by the appropriate neutron or X-ray scattering length maps the composition-space profile to the appropriate scattering length space for comparison to experimental data. The difficulty with the method is that fluid bilayer structures are generally only marginally determined by the experimental data. This means that the space of possible solutions must be extensively explored in conjunction with a thorough analysis of errors

Measurement of residual stress in textured Al alloy by neutron diffraction method

International Nuclear Information System (INIS)

Okido, S.; Hayashi, M.; Tanaka, K.; Akiniwa, Y.; Minakawa, N.; Morii, Y.

1999-01-01

Residual stress generated in a shrunken aluminum alloy specimen, which was prepared for the round robin test conducted by VAMAS (Versailles Project on Advanced Materials and Standards) TWA-20 organized for the purpose of standardizing residual stress measurement methods, was evaluated by a neutron diffraction method. The main purpose of the round robin test was to assess the reproducibility of data obtained with the measurement facilities of the participants. The general standard of the Residual Stress Analyzer (RESA) constructed in the Japan Atomic Energy Research Institute was verified from the measured residual strains, which were equivalent to the values calculated by FEM and values measured by the research facilities in North America. Residual stress was calculated from residual strain in three perpendicular directions. The diffraction intensities were dependent on measurement directions since the prepared specimen possessed texture. Diffraction profiles in directions having a weak diffraction intensity caused an inaccurate evaluation of the residual stress. To solve this problem, a new method for evaluating residual stress with respect to diffraction plane dependency of the elastic constant was applied. The diffraction plane giving the highest intensity among 110, 200, and 220 diffraction was used to evaluate the residual strain in each of three directions. The residual strain obtained on the used diffraction plane was converted to the equivalent strain for the defined diffraction plane using the ratio of elastic constants of these two planes. The developed evaluation method achieved highly accurate measurement and remarkable efficiency in the measurement process. (author)

Methane storage mechanism in the metal-organic framework Cu3(btc)2: An in situ neutron diffraction study

NARCIS (Netherlands)

Getzschmann, J.; Senkovska, I.; Wallacher, D.; Tovar, M.; Fairen-Jimenez, D.; Düren, T.; van Baten, J.M.; Krishna, R.; Kaskel, S.

2010-01-01

The adsorption of deutero-methane (CD4) in Cu3(btc)2 (HKUST-1) was investigated at 77 K using high-resolution neutron powder diffraction. Rietveld refinement of the neutron data revealed a sequential filling of the rigid framework at distinct preferred adsorption sites, and showed the importance of

Structural studies of liquid alcohols by neutron diffraction

International Nuclear Information System (INIS)

Montague, D.G.; Cummings, S.

1984-01-01

Neutron diffraction measurements have been made on methyl alcohol at room temperature for an incident wavelength of 0.94 A. Cross sections have been obtained for CD 3 OD, CD 3 OH, and mixtures of these compounds. These data are subtracted to obtain the separated structure factors for intermolecular H 0 H 0 , the hydroxyl components, and the non-hydroxyl components. The Fourier transformations of the structure factors show components of both intra- and intermolecular distribution functions. Width parameters obtained from model fits are too large for thermal vibrations and are interpreted as geometrical broadening due to the stretching of bonds, variations in bond angles, and rotation of the methyl group. Differences in the real space distribution function between hydrogen and deuterium are noted. (author)

Single-crystal neutron diffraction study of ammonium nitrate phase III

International Nuclear Information System (INIS)

Choi, C.S.; Prask, H.J.

1982-01-01

The crystal structure of ammonium nitrate phase III has been studied at room temperature by neutron diffraction using a single crystal containing 5% KNO 3 in solid-solution form. The space group is Pnma, with a = 7.6772 (4), b = 5.8208 (4), c = 7.1396 (5) A, Z = 4. The final residual after full-matrix least-squares refinement was R = 0.042 for 348 observed reflections. The ammonium ions are thermally disordered into two orientations, displaced by an angle of approximately 42 0 about an axis parallel to the c axis. (Auth.)

Electrostatic levitation facility optimized for neutron diffraction studies of high temperature liquids at a spallation neutron source

Energy Technology Data Exchange (ETDEWEB)

Mauro, N. A., E-mail: namauro@noctrl.edu [Department of Physics, North Central College, Naperville, Illinois 60540 (United States); Vogt, A. J. [Instrument and Source Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Derendorf, K. S. [Mechanical Engineering and Materials Science, Washington University, St. Louis, Missouri 63130 (United States); Johnson, M. L.; Kelton, K. F. [Department of Physics and Institute of Materials Science and Engineering, Washington University, 1 Brookings Drive, St. Louis, Missouri 63130 (United States); Rustan, G. E.; Quirinale, D. G.; Goldman, A. I. [Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States); Kreyssig, A. [Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States); Division of Materials Sciences and Engineering, Ames Laboratory, Ames, Iowa 50011 (United States); Lokshin, K. A. [Department of Materials Science and Engineering, University of Tennessee, Knoxville, Tennessee 37996 (United States); Quantum Condensed Matter Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Neuefeind, J. C.; An, Ke [Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Wang, Xun-Li [Department of Physics and Materials Science, City University of Hong Kong, 83 Tat Chee Ave., Kowloon (Hong Kong); Egami, T. [Department of Materials Science and Engineering, University of Tennessee, Knoxville, Tennessee 37996 (United States); Department of Physics and Astronomy, Joint Institute for Neutron Sciences, University of Tennessee, Knoxville, Tennessee 37996 (United States)

2016-01-15

Neutron diffraction studies of metallic liquids provide valuable information about inherent topological and chemical ordering on multiple length scales as well as insight into dynamical processes at the level of a few atoms. However, there exist very few facilities in the world that allow such studies to be made of reactive metallic liquids in a containerless environment, and these are designed for use at reactor-based neutron sources. We present an electrostatic levitation facility, NESL (for Neutron ElectroStatic Levitator), which takes advantage of the enhanced capabilities and increased neutron flux available at spallation neutron sources (SNSs). NESL enables high quality elastic and inelastic neutron scattering experiments to be made of reactive metallic and other liquids in the equilibrium and supercooled temperature regime. The apparatus is comprised of a high vacuum chamber, external and internal neutron collimation optics, and a sample exchange mechanism that allows up to 30 samples to be processed between chamber openings. Two heating lasers allow excellent sample temperature homogeneity, even for samples approaching 500 mg, and an automated temperature control system allows isothermal measurements to be conducted for times approaching 2 h in the liquid state, with variations in the average sample temperature of less than 0.5%. To demonstrate the capabilities of the facility for elastic scattering studies of liquids, a high quality total structure factor for Zr{sub 64}Ni{sub 36} measured slightly above the liquidus temperature is presented from experiments conducted on the nanoscale-ordered materials diffractometer (NOMAD) beam line at the SNS after only 30 min of acquisition time for a small sample (∼100 mg)

Determination of the Magnetic Structure of Complex anti-Perovskite Fluorides by Neutron Diffraction

Science.gov (United States)

Felder, Justin; Yeon, Jeongho; Zur Loye, Hans-Conrad

An unusual family of anti-perovskite fluorides consisting of complex ions as the A, B, and X building units has been synthesized as single crystals. This family of anti-perovskites provides a unique framework to probe the magnetic properties of transition metals. Presented here is the Fe endmember of the family: [Cu(H2O)4]3[FeF6]2. The iron member exhibits complex magnetic behavior at low temperatures, which has been probed by magnetometry and neutron diffraction experiments. Presented here are the results from the anisotropic magnetometry study as well as the magnetic spin structure as determined by neutron diffraction experiments. The materials presented here represent an interesting class of perovskites that are as-yet unexplored. Given the wide range of properties possible in perovskites and related structures, it is reasonable to expect that further exploration of these materials will reveal many interesting attributes; both chemical and physical. United States Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering, Award DE-SC0008664.

Study of the α and β phases of quartz by neutron multiple diffraction

International Nuclear Information System (INIS)

Mazzocchi, V.L.

1984-01-01

Crystal structures of α and β phases of quartz are studied, employing neutron multiple diffraction as a method of analysis. Theoretical multiple diffraction patterns in a many-beam case were determined by a computer program which calculates intensities of beams as sums of Taylor's series expansions, retaining terms up to a order n. Experimental 'umweg' and transmitted beam patterns were obtained for the 00.1 primary reflection of α and β phases of quartz. To calculate α - quartz multiple diffraction intensities it was necessary to determine the Dauphine twinning fraction for the crystal after having passed by the β-phase. For the two models of β-quartz a better agreement between experimental and calculated integrated intensities was found for the disordered structure model based on split-half-oxigen positions. (Author) [pt

Perdeuteration, purification, crystallization and preliminary neutron diffraction of an ocean pout type III antifreeze protein

International Nuclear Information System (INIS)

Petit-Haertlein, Isabelle; Blakeley, Matthew P.; Howard, Eduardo; Hazemann, Isabelle; Mitschler, Andre; Haertlein, Michael; Podjarny, Alberto

2009-01-01

Perdeuterated type III antifreeze protein has been expressed, purified and crystallized. Preliminary neutron data collection showed diffraction to 1.85 Å resolution from a 0.13 mm 3 crystal. The highly homologous type III antifreeze protein (AFP) subfamily share the capability to inhibit ice growth at subzero temperatures. Extensive studies by X-ray crystallography have been conducted, mostly on AFPs from polar fishes. Although interactions between a defined flat ice-binding surface and a particular lattice plane of an ice crystal have now been identified, the fine structural features underlying the antifreeze mechanism still remain unclear owing to the intrinsic difficulty in identifying H atoms using X-ray diffraction data alone. Here, successful perdeuteration (i.e. complete deuteration) for neutron crystallographic studies of the North Atlantic ocean pout (Macrozoarces americanus) AFP in Escherichia coli high-density cell cultures is reported. The perdeuterated protein (AFP D) was expressed in inclusion bodies, refolded in deuterated buffer and purified by cation-exchange chromatography. Well shaped perdeuterated AFP D crystals have been grown in D 2 O by the sitting-drop method. Preliminary neutron Laue diffraction at 293 K using LADI-III at ILL showed that with a few exposures of 24 h a very low background and clear small spots up to a resolution of 1.85 Å were obtained using a ‘radically small’ perdeuterated AFP D crystal of dimensions 0.70 × 0.55 × 0.35 mm, corresponding to a volume of 0.13 mm 3

A comparison of dilatometry and in-situ neutron diffraction in tracking bulk phase transformations in a martensitic stainless steel

Energy Technology Data Exchange (ETDEWEB)

Christien, F., E-mail: frederic.christien@univ-nantes.fr [Institut des Matériaux Jean Rouxel (IMN), Université de Nantes, CNRS, Rue Christian Pauc, BP 50609, 44306 Nantes Cedex 3 (France); Telling, M.T.F. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, OX11 0QX (United Kingdom); Department of Materials, University of Oxford, Parks Road, Oxford (United Kingdom); Knight, K.S. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, OX11 0QX (United Kingdom); Department of Earth Sciences, The Natural History Museum, Cromwell Road, London (United Kingdom)

2013-08-15

Phase transformations in the 17-4PH martensitic stainless steel have been studied using different in-situ techniques, including dilatometry and high resolution neutron diffraction. Neutron diffraction patterns were quantitatively processed using the Rietveld refinement method, allowing the determination of the temperature-dependence of martensite (α′, bcc) and austenite (γ, fcc) phase fractions and lattice parameters on heating to 1000 °C and then cooling to room temperature. It is demonstrated in this work that dilatometry doesn't permit an accurate determination of the end temperature (Ac3) of the α′ → γ transformation which occurs upon heating to high temperature. The analysis of neutron diffraction data has shown that the respective volumes of the two phases become very close to each other at high temperature, thus making the dilatometric technique almost insensitive in that temperature range. However, there is a very good agreement between neutron diffraction and dilatometry at lower temperature. The martensitic transformation occurring upon cooling has been analysed using the Koistinen–Marburger equation. The thermal expansion coefficients of the two phases have been determined in addition. A comparison of the results obtained in this work with data from literature is presented. - Highlights: • Martensite is still present at very high temperature (> 930 °C) upon heating. • The end of austenitisation cannot be accurately monitored by dilatometry. • The martensite and austenite volumes become similar at high temperature (> ∼ 850 °C)

Neutron diffraction studies on lattice strain evolution around a crack-tip during tensile loading and unloading cycles

Energy Technology Data Exchange (ETDEWEB)

Sun Yinan [Department of Materials Science and Engineering, University of Tennessee, Knoxville, TN 37996 (United States)]. E-mail: ysun1@utk.edu; Choo, Hahn [Department of Materials Science and Engineering, University of Tennessee, Knoxville, TN 37996 (United States); Metals and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Liaw, Peter K. [Department of Materials Science and Engineering, University of Tennessee, Knoxville, TN 37996 (United States); Lu Yulin [Department of Materials Science and Engineering, University of Tennessee, Knoxville, TN 37996 (United States); Yang Bing [Department of Materials Science and Engineering, University of Tennessee, Knoxville, TN 37996 (United States); Brown, Donald W. [Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Bourke, Mark A.M. [Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

2005-10-15

Elastic lattice-strain profiles ahead of a fatigue-crack-tip were measured during tensile loading and unloading cycles using neutron diffraction. The crack-closure phenomenon after an overload was observed. Furthermore, the plastic-zone size in front of the crack-tip was estimated from the diffraction-peak broadening, which showed good agreement with the calculated result.

Development of a sample environment for neutron diffraction at low temperature

International Nuclear Information System (INIS)

Lee, Jeong Soo; Lee, Chang Hee; Choi, Yong Nam

2000-06-01

This report contains the development of low temperature sample environment for the neutron diffraction and its utilization techniques. With this research, a low temperature experimental facility of T=10-300 K was developed. We measured magnetic peak of La 1 .4Sr 1 .6Mn 2 O 7 due to low temperature phase transition successfully by this unit installed at the sample table of HRPD. Therefore, the research capability for various materials under the low temperature was expanded

Neutron powder diffraction studies of Hydrogen and Denterium in Palladium Phosphides

International Nuclear Information System (INIS)

Andersson, Y.

1986-01-01

The use of the Rietveld-type profile refinements on neutron powder diffraction intensity data for determining crystallographic positions of hydrogen and deuterium in metal hydrides is illustrated by results obtained on some hydrogenated and deuterated palladium phosphides. The structural features of the solid solutions of hydrogen and deuterium in Pd/sb15/P/sb2/ Pd/sb6/P and Pd/sb3/P/sb1-u/ (0< u<0.28) are briefly presented and discussed

The analysis of powder diffraction data

International Nuclear Information System (INIS)

David, W.I.F.; Harrison, W.T.A.

1986-01-01

The paper reviews neutron powder diffraction data analysis, with emphasis on the structural aspects of powder diffraction and the future possibilities afforded by the latest generation of very high resolution neutron and x-ray powder diffractometers. Traditional x-ray powder diffraction techniques are outlined. Structural studies by powder diffraction are discussed with respect to the Rietveld method, and a case study in the Rietveld refinement method and developments of the Rietveld method are described. Finally studies using high resolution powder diffraction at the Spallation Neutron Source, ISIS at the Rutherford Appleton Laboratory are summarized. (U.K.)

Preferred orientation of a naturally and experimentally deformed pyrrhotite ore by X-ray and neutron diffraction texture analysis

International Nuclear Information System (INIS)

Niederschlag, E.; Brokmeier, H.G.; Siemes, H.

1994-01-01

Two samples of polycrystalline naturally deformed hexagonal Pyrrhotite were deformed experimentally in axial compression tests with different temperatures and strain. The texture of the naturally deformed ore was investigated both by X-ray and neutron texture analyses. Texture measurements on the experimentally deformed ore were carried out by neutron diffraction. (orig.)

Residual stresses in cold-coiled helical compression springs for automotive suspensions measured by neutron diffraction

Czech Academy of Sciences Publication Activity Database

Matějíček, Jiří; Brand, P. C.; Drews, A. R.; Krause, A.; Lowe-Ma, C.

2004-01-01

Roč. 367, 1-2 (2004), s. 306-311 ISSN 0921-5093 Institutional research plan: CEZ:AV0Z2043910 Keywords : residual stress, automotive springs, neutron diffraction Subject RIV: JB - Sensors, Measurment, Regulation Impact factor: 1.445, year: 2004

Stresses in plasma-sprayed Cr2O3 coatings measured by neutron diffraction

Czech Academy of Sciences Publication Activity Database

Dubský, Jiří; Prask, H. J.; Matějíček, Jiří; Gnäupel-Herold, T.

2002-01-01

Roč. 75, - (2002), s. 1-3 ISSN 0947-8396. [International Conference on Neutron Scattreing. Munich, 09.08.2001-13.08.2002] R&D Projects: GA ČR GA106/01/0094 Institutional research plan: CEZ:AV0Z2043910 Keywords : plasma sprayed, diffraction Subject RIV: JK - Corrosion ; Surface Treatment of Materials Impact factor: 2.231, year: 2002

Study of ethanol-lysozyme interactions using neutron diffraction

International Nuclear Information System (INIS)

Lehmann, M.S.; Mason, S.A.; McIntyre, G.J.

1985-01-01

Single-crystal neutron diffraction has been used to observe the interactions between deuterated ethanol (CD3CD2OH) and lysozyme in triclinic crystals of hen egg white lysozyme soaked in 25% (v/v) ethanol solutions. A total of 6047 observed reflections to a resolution of 2 A were used, and 13 possible ethanol sites were identified. The three highest occupied sites are close to locations for bromoethanol found in an earlier study by Yonath et al. [Yonath, A., Podjarny, A., Honig, B., Traub, W., Sielecki, A., Herzberg, O., and Moult, J. (1978) Biophys. Struct. Mech. 4, 27-36]. Structure refinements including a model for the flat solvent lead to a final crystallographic agreement factor of 0.097. Comparison with earlier neutron studies on triclinic lysozyme showed that neither the molecular structure nor the thermal motions were affected significantly by the ethanol. A detailed analysis of the ethanol-lysozyme contacts showed 61% of these to be with hydrophobic sites, in agreement with the dominant hydrophobic nature of ethanol. This, together with the fact that the molecular structure of lysozyme is not perturbed, suggests a model for denaturation of lysozyme by alcohol, which proceeds via a dehydration of the protein at high alcohol concentration

Studying magnetic structure of Bi doped Co2MnO4 cubic spinel by neutron diffraction

International Nuclear Information System (INIS)

Rajeevan, N.E.; Kaushik, S.D.; Kumar, Ravi

2016-01-01

In present work, we studied effect of Bi doped spinel Bi x Co 2-x MnO 4 (x = 0, 0.05, 0.10, 0.15 and 0.20) samples on their crystal as well as magnetic structure by employing neutron diffraction of wavelength 1.48 A using focusing crystal diffractometer of UGC-DAECSR Mumbai Centre at Dhruva, Trombay, Mumbai, India. The analysis of the neutron diffraction using Fullprof program reveals that crystal structure due to Bi doping remains intact and all the samples have been formed in the cubic spinel structure with Fd3m (space group no. 227). The lattice parameter shows the positive thermal expansion upon Bi doping across the temperature range. In order to understand the implication on the spin structure and magnetism in the detail, temperature dependent neutron diffraction study is carried out on some of the samples (x = 0, 0.1) in the series. The ND pattern of x = 0.1 at 2.9K is shown. The experimental finding in terms of modified magnetic structure upon Bi doping are discussed which are understood in terms of variation in the ferroelectric properties, bond lengths and their effect on the CoO 6 polyhedra. Furthermore, Bi substitution in Co 2 MnO 4 spinel brings in the balance of structural distortion, which affects both ferrimagnetism and ferroelectricity

A comparison of texture results obtained using precession electron diffraction and neutron diffraction methods at diminishing length scales in ordered bimetallic nanolamellar composites

International Nuclear Information System (INIS)

Carpenter, J.S.; Liu, X.; Darbal, A.; Nuhfer, N.T.; McCabe, R.J.; Vogel, S.C.; LeDonne, J.E.; Rollett, A.D.; Barmak, K.; Beyerlein, I.J.; Mara, N.A.

2012-01-01

Precession electron diffraction (PED) is used to acquire orientation information in Cu–Nb nanolamellar composites fabricated by accumulative roll bonding (ARB). The resulting maps quantify the grain size, shape, orientation distributions and interface planes in the vicinity of nanometer-thick deformation twins. The PED-based texture results compare favorably with bulk textures provided by neutron diffraction measurements, indicating uniformity in the ARB Cu–Nb texture. Additionally, {1 1 2} Cu ||{1 1 2} Nb interfaces are present, suggesting that ARB techniques can lead to stable interfaces with a special crystallography.

Mapping residual and internal stress in materials by neutron diffraction

International Nuclear Information System (INIS)

Withers, Ph.J.

2007-01-01

Neutron diffraction provides one of the few means of mapping residual stresses deep within the bulk of materials and components. This article reviews the basic scientific methodology by which internal strains and stresses are inferred from recorded diffraction peaks. Both conventional angular scans and time-of-flight measurements are reviewed and compared. Their complementarity with analogous synchrotron X-ray methods is also highlighted. For measurements to be exploited in structural integrity calculations underpinning the safe operation of engineering components, measurement standards have been defined and the major findings are summarised. Examples are used to highlight the unique capabilities of the method showing how it can provide insights ranging from the basic physics of slip mechanisms in hexagonal polycrystalline materials, through the materials optimisation of stress induced transformations in smart nano-materials, to the industrial introduction of novel friction welding processes exploiting stress residual measurements transferred from prototype sub-scale tests to the joining of full-scale aero-engine assemblies. (author)

Real time neutron diffraction and NMR of the Empress II glass-ceramic system.

Science.gov (United States)

O'Donnell, M D; Hill, R G; Karpukhina, N; Law, R V

2011-10-01

This study reports real time neutron diffraction on the Empress II glass-ceramic system. The commercial glass-ceramics was characterized by real time neutron diffraction, ³¹P and ²⁹Si solid-state MAS-NMR, DSC and XRD. On heating, the as-received glass ceramic contained lithium disilicate (Li₂Si₂O₅), which melted with increasing temperature. This was revealed by neutron diffraction which showed the Bragg peaks for this phase had disappeared by 958°C in agreement with thermal analysis. On cooling lithium metasilicate (Li₂SiO₃) started to form at around 916°C and a minor phase of cristobalite at around 852°C. The unit cell volume of both Li-silicate phases increased linearly with temperature at a rate of +17×10⁻³ ų.°C⁻¹. Room temperature powder X-ray diffraction (XRD) of the material after cooling confirms presence of the lithium metasilicate and cristobalite as the main phases and shows, in addition, small amount of lithium disilicate and orthophosphate. ³¹P MAS-NMR reveals presence of the lithiorthophosphate (Li₃PO₄) before and after heat treatment. The melting of lithium disilicate on heating and crystallisation of lithium metasilicate on cooling agree with endothermic and exotermic features respectively observed by DSC. ²⁹Si MAS-NMR shows presence of lithium disilicate phase in the as-received glass-ceramic, though not in the major proportion, and lithium metasilicate in the material after heat treatment. Both phases have significantly long T₁ relaxation time, especially the lithium metasilicate, therefore, a quantitative analysis of the ²⁹Si MAS-NMR spectra was not attempted. Significance. The findings of the present work demonstrate importance of the commercially designed processing parameters in order to preserve desired characteristics of the material. Processing the Empress II at a rate slower than recommended 60°C min⁻¹ or long isothermal hold at the maximal processing temperature 920°C can cause

High-resolution inelastic neutron scattering and neutron powder diffraction study of the adsorption of dihydrogen by the Cu(II) metal–organic framework material HKUST-1

Energy Technology Data Exchange (ETDEWEB)

Callear, Samantha K.; Ramirez-Cuesta, Anibal J.; David, William I.F. [ISIS Facility, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, OX11 0QX (United Kingdom); Millange, Franck [Institut Lavoisier Versailles (CNRS UMR 8180), Université de Versailles, 78035 Versailles (France); Walton, Richard I., E-mail: r.i.walton@warwick.ac.uk [Department of Chemistry, University of Warwick, CV4 7AL, Coventry (United Kingdom)

2013-12-12

Highlights: • Binding sites for dihydrogen in a metal–organic framework have been identified. • The combination of diffraction and spectroscopy shows competitive filling of various adsorption sites. • Inelastic neutron scattering over wide-momentum transfer reveals new models for hydrogen-framework interactions. - Abstract: We present new high-resolution inelastic neutron scattering (INS) spectra (measured using the TOSCA and MARI instruments at ISIS) and powder neutron diffraction data (measured on the diffractometer WISH at ISIS) from the interaction of the prototypical metal–organic framework HKUST-1 with various dosages of dihydrogen gas. The INS spectra show direct evidence for the sequential occupation of various distinct sites for dihydrogen in the metal–organic framework, whose population is adjusted during increasing loading of the guest. The superior resolution of TOSCA reveals subtle features in the spectra, not previously reported, including evidence for split signals, while complementary spectra recorded on MARI present full information in energy and momentum transfer. The analysis of the powder neutron patterns using the Rietveld method shows a consistent picture, allowing the crystallographic indenisation of binding sites for dihydrogen, thus building a comprehensive picture of the interaction of the guest with the nanoporous host.

High-resolution inelastic neutron scattering and neutron powder diffraction study of the adsorption of dihydrogen by the Cu(II) metal–organic framework material HKUST-1

International Nuclear Information System (INIS)

Callear, Samantha K.; Ramirez-Cuesta, Anibal J.; David, William I.F.; Millange, Franck; Walton, Richard I.

2013-01-01

Highlights: • Binding sites for dihydrogen in a metal–organic framework have been identified. • The combination of diffraction and spectroscopy shows competitive filling of various adsorption sites. • Inelastic neutron scattering over wide-momentum transfer reveals new models for hydrogen-framework interactions. - Abstract: We present new high-resolution inelastic neutron scattering (INS) spectra (measured using the TOSCA and MARI instruments at ISIS) and powder neutron diffraction data (measured on the diffractometer WISH at ISIS) from the interaction of the prototypical metal–organic framework HKUST-1 with various dosages of dihydrogen gas. The INS spectra show direct evidence for the sequential occupation of various distinct sites for dihydrogen in the metal–organic framework, whose population is adjusted during increasing loading of the guest. The superior resolution of TOSCA reveals subtle features in the spectra, not previously reported, including evidence for split signals, while complementary spectra recorded on MARI present full information in energy and momentum transfer. The analysis of the powder neutron patterns using the Rietveld method shows a consistent picture, allowing the crystallographic indenisation of binding sites for dihydrogen, thus building a comprehensive picture of the interaction of the guest with the nanoporous host

Structural studies of WO3-TeO2 glasses by high-Q-neutron diffraction and Raman spectroscopy

International Nuclear Information System (INIS)

Khanna, A.; Kaur, A.; Krishna, P.S.R.; Shinde, A.B.

2013-01-01

Glasses from the system: xWO 3 -(100-x)TeO 2 (x=15, 20 and 25 mol %) were prepared by melt quenching technique and characterized by density, UV-visible absorption spectroscopy, Differential Scanning Calorimetry (DSC), Raman spectroscopy and high-Q neutron diffraction measurements. Glass density and glass transition temperature increased with increase in WO 3 concentration, Raman spectroscopy indicated the conversion of TeO 4 units into TeO 3 units with increase in WO 3 content. The increase in glass transition temperature with the incorporation of WO 3 was attributed to the increase in average bond strength of the glass network since the bond dissociation energy of W-O bonds (672 kJ/mol) is significantly higher than that of Te-O bonds (376 kJ/mol). UV-visible studies found a very strong optical absorption band due to W 6+ ions, just below the absorption edge. High-Q neutron diffraction measurements were performed on glasses and radial distribution function analyses revealed changes in W-O and Te-O correlations in the glass network. The findings about changes in glass structure from neutron diffraction studies were consistent with structural information obtained from Raman spectroscopy and structure-property correlations were made. (author)

The neutron diffraction of molten TlCl, TlBr, and TlI

International Nuclear Information System (INIS)

Satow, T.; Uemura, O.; Hoshino, K.; Watanabe, T.

1984-01-01

Structure factors S(K) for liquid TlCl, TlBr, and TlI are determined by neutron diffraction measurements. Atomic radial distribution functions (RDF) derived from S(K) are presented. All RDF values are slightly smaller than those of their solid state counter parts. Results show that TlX has a tendency not to retain cesium-chloride type local order, but to take sodium-chloride type order when melting

The determination of the crystal structures of some uranium compounds by means of x-ray and neutron diffraction

International Nuclear Information System (INIS)

Adrian, H.W.W.

1977-10-01

In industrial uranium processing or reprocessing procedures, aqueous uranyl nitrate solutions are an intermediate product. The compounds, whose structures are reported, might prove valuable as alternative crystallization products to existing methods of extracting the uranium from solution. The compounds are obtained by the addition of hydroxylammonium to the uranyl nitrate solution and are of the general formula UO 2 (NH 2 0) 2 .xH 2 0, where x can take the values zero, two, three and four. In addition a compound of the formula UO 2 (NH 2 0) 2 .2(NH 2 CH).2H 2 0 was obtained. The UO 2 (NH 2 0) compound crystallized in a monoclinic crystal form. Crystals large enough for neutron diffraction were not obtained. The structure of the UO 2 (NH 2 0) 2 .2H 2 0 could not be solved because only disordered crystalline material was available. The structure of UO 2 (NH 2 0) 2 .3H 2 0 was solved by means of room- and low-temperature neutron diffraction. The unit cell is orthorhombic. The structure of α-UO 2 (NH 2 0) 2 .4H 2 0 was investigated by means of room-temperature x-ray and room- and low-temperature neutron diffraction. The unit cell is triclinic. This compound strongly resembles the trihydrate. The UO 2 (NH 2 0) 2 .2(NH 2 0H).2H 2 0 compound gave crystals large enough for single crystal x-ray but not neutron diffraction. The unit cell is orthorhombic. The characteristic powder patterns (indexed except for the dihydrate compound) of the above compounds are reported [af

Development and applications of the reverse neutron time-of-flight method with Fourier-type beam chopper

International Nuclear Information System (INIS)

Antson, O.

1991-09-01

The neutron powder diffraction method has been applied to the crystal structure analysis of high-temperature superconductors such as La 0 .8Sr 0 .2CuO 4 - y , YBa 2 Cu 3 O 7 - y and Bi 2 Sr 2 CaCu 2 O 8 + y optically active yttriumformate Y(HCOO) 3 , and β phase of deuterated acetonitrile, CD 3 CN. The structural information, containing symmetry, positional and thermal parameters, occupation factors and the order parameter, was obtained by measuring the coherent elastic scattering cross-section. The Rietveld profile refinement method was used for the extraction of structural parameters from experimental data. The diffraction spectra were obtained by measuring the time-of-flight distribution of neutrons with a Fourier-type beam chopper. The neutron diffraction spectrum is created by the on-line synthesis of the cross-correlation function between the beam modulation function and the detector intensity. Such an operational mode, called the reverse time-of-flight method, has many unique properties. The possibility of filtering out a low-frequency part of a diffraction spectrum, eg. incoherent background, by a properly selected band-pass filter has been studied. One of the practical applications of the reverse time-of-flight method, the Mini-Sfinks facility, is described with technical details, and its operational characteristics are compared with other high-resolution instruments

Type I and type II residual stress in iron meteorites determined by neutron diffraction measurements

Science.gov (United States)

Caporali, Stefano; Pratesi, Giovanni; Kabra, Saurabh; Grazzi, Francesco

2018-04-01

In this work we present a preliminary investigation by means of neutron diffraction experiment to determine the residual stress state in three different iron meteorites (Chinga, Sikhote Alin and Nantan). Because of the very peculiar microstructural characteristic of this class of samples, all the systematic effects related to the measuring procedure - such as crystallite size and composition - were taken into account and a clear differentiation in the statistical distribution of residual stress in coarse and fine grained meteorites were highlighted. Moreover, the residual stress state was statistically analysed in three orthogonal directions finding evidence of the existence of both type I and type II residual stress components. Finally, the application of von Mises approach allowed to determine the distribution of type II stress.

Anomalous spin distribution in the superconducting ferromagnet UCoGe studied by polarized neutron diffraction

NARCIS (Netherlands)

Prokeš, K.; de Visser, A.; Huang, Y.K.; Fåk, B.; Ressouche, E.

2010-01-01

We report a polarized neutron-diffraction study conducted to reveal the nature of the weak ferromagnetic moment in the superconducting ferromagnet UCoGe. We find that the ordered moment in the normal phase in low magnetic fields (B∥c) is predominantly located at the U atom and has a magnitude of

Neutron diffraction study of stress-induced martensitic transformation and variant change in Fe-Pd shape memory alloy

International Nuclear Information System (INIS)

Oliver, E.C.; Mori, T.; Daymond, M.R.; Withers, P.J.

2003-01-01

Neutron diffraction spectra were recorded during tensile testing of Fe-30.5 at.% Pd shape memory alloy at temperatures above M s and below M f . Peak intensity changes indicate that the application of tensile stress to initially fully austenitic material results in the preferential martensitic transformation of grains oriented with austenite parallel to the tensile axis. Tensile stress applied to initially fully martensitic material causes the greatest extent of reorientation in those variants oriented with martensite lying parallel to the tensile axis. These results are interpreted using a simple elasticity-based theory. Additionally, diffraction peak shifts provide information on the development of lattice strain in differently oriented grain families during loading. This indicates that above M s the alloy exhibits high single crystal elastic anisotropy. Below M f the apparent stiffnesses of different grain families suggest that axially compressive internal stresses develop in those grain families in which most variant reorientation occurs. These stresses act to reverse the variant changes upon subsequent unloading

Laue 2007: international workshop on advanced Laue diffraction in frontier science

International Nuclear Information System (INIS)

Adachi, S.I.; Akgul, G.; Aksoy, F.; Andersen, K.; Andersson, M.; Anfinrud, Ph.; Baruchel, J.; Bastie, P.; Bau, R.; Blakeley, M.; Bourgeois, D.; Brau, D.; Bravin, A.; Cammarata, M.; Christensen, M.; Cole, J.; Courtois, P.; Cousson, A.; Eggonopoulos-Papadopoulos, B.; Daoud-Aladine, M.A.; Dera, P.; Feng, R.; Fiedler, St.; Fischer, H.; Fisher, St.; Folami, S.; Fosu, M.A.; Fuente, F.; Fullagar, W.; Fulla Marsa, D.; Ghosh, R.; Giles, C.; Goossens, D.; Goujon, A.; Gutmann, M.; Heger, G.; Henry, E.; Hewat, A.; Hossmann, Ch.; Ivanov, A.; Jauch, W.; Jorgensen, R.; Katona, G.; Keen, D.; Kong, Q.; Koshihara, Sh.Y.; Lauss, B.; Laue, M.V.; Lecomte, C.; Legrand, V.; Lemee-Cailleau, M.H.; Marmeggi, J.C.; Martinez-Criado, G.; Mason, S.; McIntyre, G.; Mailleur, F.; Micha, J.S.; Moffat, K.; Mohammed Mustapha, A.; Ouladdiaf, B.; Pahl, R.; Parise, J.; Pearson, A.; Pecaut, J.; Popov, A.; Prokleska, J.; Raitman, E.; Ren, Z.; Rodriguez-Carvajal, J.; Sasaki, J.; Schmidt, M.; Schotte, F.; Stirling, W.; Suominen Fuller, M.; Tanaka, I.; Timmins, P.; Tomking, P.; Turner, M.; Van Thor, J.; Vettier, Ch.; Wildes, A.; Wilson, Ch.; Wohri, A.; Wulf, M.; Zhao, Y.

2007-01-01

Laue diffraction is currently undergoing a lively renaissance due to new instrumental developments at both synchrotron X-ray and neutron sources. The aim of the workshop Laue-2007 is to offer state-of-the-art experimental methods and hands-on experience of data analysis for exploration, using single-crystal Laue diffraction, of the crystalline structure of complex materials in extreme cases. The oral sessions cover the following topics: -) history and renaissance of Laue diffraction, -) modern X-ray techniques, -) modern neutron techniques, -) applications, -) analysis and software demonstrations including hands-on experience, and -) future directions. This document gathers the abstracts of the presentations and of the posters

Laue 2007: international workshop on advanced Laue diffraction in frontier science

Energy Technology Data Exchange (ETDEWEB)

Adachi, S I; Akgul, G; Aksoy, F; Andersen, K; Andersson, M; Anfinrud, Ph; Baruchel, J; Bastie, P; Bau, R; Blakeley, M; Bourgeois, D; Brau, D; Bravin, A; Cammarata, M; Christensen, M; Cole, J; Courtois, P; Cousson, A; Eggonopoulos-Papadopoulos, B; Daoud-Aladine, M A; Dera, P; Feng, R; Fiedler, St; Fischer, H; Fisher, St; Folami, S; Fosu, M A; Fuente, F; Fullagar, W; Fulla Marsa, D; Ghosh, R; Giles, C; Goossens, D; Goujon, A; Gutmann, M; Heger, G; Henry, E; Hewat, A; Hossmann, Ch; Ivanov, A; Jauch, W; Jorgensen, R; Katona, G; Keen, D; Kong, Q; Koshihara, Sh Y; Lauss, B; Laue, M V; Lecomte, C; Legrand, V; Lemee-Cailleau, M H; Marmeggi, J C; Martinez-Criado, G; Mason, S; McIntyre, G; Mailleur, F; Micha, J S; Moffat, K; Mohammed Mustapha, A; Ouladdiaf, B; Pahl, R; Parise, J; Pearson, A; Pecaut, J; Popov, A; Prokleska, J; Raitman, E; Ren, Z; Rodriguez-Carvajal, J; Sasaki, J; Schmidt, M; Schotte, F; Stirling, W; Suominen Fuller, M; Tanaka, I; Timmins, P; Tomking, P; Turner, M; Van Thor, J; Vettier, Ch; Wildes, A; Wilson, Ch; Wohri, A; Wulf, M; Zhao, Y

2007-07-01

Laue diffraction is currently undergoing a lively renaissance due to new instrumental developments at both synchrotron X-ray and neutron sources. The aim of the workshop Laue-2007 is to offer state-of-the-art experimental methods and hands-on experience of data analysis for exploration, using single-crystal Laue diffraction, of the crystalline structure of complex materials in extreme cases. The oral sessions cover the following topics: -) history and renaissance of Laue diffraction, -) modern X-ray techniques, -) modern neutron techniques, -) applications, -) analysis and software demonstrations including hands-on experience, and -) future directions. This document gathers the abstracts of the presentations and of the posters.

Thermal expansion study of simulated DUPIC fuel using neutron diffraction

International Nuclear Information System (INIS)

Kang, Kweon Ho; Ryu, H. J.; Bae, J. H.; Kim, H. S.; Song, K. C.; Yang, M. S.; Choi, Y. N.; Han, Y. S.; Oh, H. S.

2001-07-01

The lattice parameters of simulated DUPIC fuel and UO2 were measured from room temperature to 1273 K using neutron diffraction to investigate the thermal expansion and density variation with temperature. The lattice parameter of simulated DUPIC fuel is lower than that of UO2 and the linear thermal expansion of simulated DUPIC fuel is higher than that of UO2. For the temperature range from 298 to 1273 K, the average linear thermal expansion coefficients for UO2 and simulated DUPIC fuel are 10.471 ''10-6 and 10.751 ''10-6 K-1, respectively

An in situ neutron diffraction study of shape setting shape memory NiTi

International Nuclear Information System (INIS)

Benafan, O.; Padula, S.A.; Noebe, R.D.; Brown, D.W.; Clausen, B.; Vaidyanathan, R.

2013-01-01

A bulk polycrystalline Ni 49.9 Ti 50.1 (at.%) shape memory alloy specimen was shape set while neutron diffraction spectra were simultaneously acquired. The objective was to correlate internal stress, phase volume fraction, and texture measurements (from neutron diffraction spectra) with the macroscopic stress and shape changes (from load cell and extensometry measurements) during the shape setting procedure and subsequent shape recovery. Experimental results showed the evolution of the martensitic transformation (lattice strains, phase fractions and texture) against external constraints during both heating and cooling. Constrained heating resulted in a build-up of stresses during the martensite to austenite transformation, followed by stress relaxation due to thermal expansion, final conversion of retained martensite, and recovery processes. Constrained cooling also resulted in stress build-up arising from thermal contraction and early formation of martensite, followed by relaxation as the austenite fully transformed to martensite. Comparisons were also made between specimens pre-shape set and post-shape set with and without external constraints. The specimens displayed similar shape memory behavior consistent with the microstructure of the shape set sample, which was mostly unchanged by the shape setting process and similar to that of the as-received material

Modulation Spectrometry Of Neutrons With Diffractometry Applications

International Nuclear Information System (INIS)

Hiismaki, P.

1997-01-01

Modulation spectrometry of neutrons refers to a measuring principle, characterized by classification of neutron histories in a probabilistic way, not the usual deterministic way. In order to accomplish this, neutron beams entering the sample are modulated by high-transmission, white-beam selectors of the multislit type, such as Fourier or statistical choppers or high-frequency-modulated spin-flippers. In this scheme it is impossible to decide in a unique way through which particular slit any single neutron passed, but the distribution of histories for a large population of neutrons can nevertheless be correctly obtained, by classifying each conceivable history either as a high-probability or as a low-probability event,based on the actual observed state of the neutron selector. So far the principle has been successfully applied to powder diffraction, but it seems to offer extra degrees of freedom if applied to measuring dispersion curves of coherent excitations, such as phonons in single crystals

Neutron diffraction studies of Ho1-xYxNi2B2C compounds

DEFF Research Database (Denmark)

Chang, L.J.; Tomy, C.V.; Paul, D.M.K.

1996-01-01

Neutron diffraction measurements have been carried out to investigate the nature of magnetic ordering in Ho(1-x)Y(x)Ni(2)B(2)C (x = 0, 0.1 and 0.2) compounds. HoNi(2)B(2)C shows a complex type of magnetic ordering below the superconducting transition, with a commensurate antiferromagnetic ordering...

Neutron diffraction study of carbontetrachloride, siliciumtetrachloride, titaniumtetrachloride, and tintetrachloride in the liquid state at 295 K

International Nuclear Information System (INIS)

Tricht, J.B. van

1977-01-01

Neutron diffraction data on the molecular liquids CCl 4 , SiCl 4 , TiCl 4 , and sSnCl 4 have been collected in an interval of the scattering parameter, kappa = 4πsintheta/lambda, extending from 0.4 A -1 to 13.3 A -1 . The neutron wavelength was 0.878 A. The statistical accuracy of the data was better than 0.25 percent, and for titanium and tin tetrachloride a factor of two better. The intermolecular contributions to the diffracted intensity is dealt with in two ways: first a comparison in kappa- and in r-space between the experimental scattering and the corresponding distribution calculated from a model of randomly oriented molecules consisting of hard spheres. Furthermore, the regions in kappa- and in r-space can be identified where positional and where orientational correlations are predominent

High frequency time modulation of neutrons by LiNbO3 crystals with surface acoustic waves excited under the diffraction condition

International Nuclear Information System (INIS)

Takahashi, Toshio; Granzer, E.; Kikuta, Seishi; Tomimitsu, Hiroshi; Doi, Kenji.

1985-01-01

High frequency time modulation of neutrons was investigated by using Y-cut LiNbO 3 crystals with surface acoustic waves excited. A double crystal arrangement of (+, -) parallel setting was used for 030 symmetric Bragg-case reflections. Synchronized standing waves with a resonance frequency of 14.26 MHz were excited on the both crystals. Variation of the diffracted intensity with phase difference between two standing waves was studied. The result showed an intensity change of diffracted neutrons with twice the resonance frequency. (author)

Applications of polarized neutrons

International Nuclear Information System (INIS)

Mezei, F.

1993-01-01

The additional spin degree of freedom of the neutron can be made use of in neutron scattering work in two fundamental ways: (a) directly for the identification of magnetic scattering effects and (b) indirectly as a spectroscopic tool for modulating and analysing beams. Although strong magnetic scattering contributions can often be studied by unpolarized neutrons, a fully unambiguous separation of nuclear and magnetic phenomena can only be achieved by the additional information provided by polarized neutrons, especially if one of the two kinds of contributions is weak compared to the other. In the most general case a sample with both magnetic and nuclear features can be characterized by as many as 16 independent dynamic correlation functions instead of the single well known S(q, ω) for non-magnetic nuclear scattering only. Polarization analysis in principle allows one to determine all these 16 functions. The indirect applications of polarized neutrons are also steadily gaining importance. The most widely used method of this kind, the application of Larmor precessions for high resolution energy analysis in Neutron Spin Echo spectroscopy opened up a whole new domain in inelastic neutron scattering which was not accessible to any other spectroscopic method with or without neutrons before. (author)

A high-resolution neutron powder diffraction study of neodymium doping in barium cerate

DEFF Research Database (Denmark)

Knight, K.S.; Bonanos, N.

1995-01-01

High-resolution neutron powder diffraction data have been collected on 6 perovskites of composition BaCe1-xNdxO3-x/(2), with 0 less than or equal to x less than or equal to 0.2, in which structural phase transitions Pmcn-->P4/mbm at x=0.05, and P4/mbm-->Pm3m at x=0.1, were inferred from a recent ...

A time-of-flight spectrometer for neutron diffraction under high pressure or at high temperature

International Nuclear Information System (INIS)

Roult, G.; Buevoz, J.L.

1975-01-01

For high pressure neutron diffraction studies (40 kilobars) the sample is placed in a very thick cell. In order to allow the neutron beam to go through the cell loosing as little intensity as possible, the inner part is kept solid while the external part has some windows facing the incident and reflected beam. The window dimensions are small (a few millimeters wide and a few centimeters long). There are two alternatives: to have the window either in a perpendicular plane or in a plane parallel to the axis. In the first case a fixed wavelength spectrometer can be used but the sample is small and the contribution of the cell to the diffraction pattern is relatively great. In the second case samples can be something like ten times greater and the cell contribution can be eliminated but a fixed wavelength spectrometer cannot be used. Thus the time-of-flight method is very convenient. The second alternative was chosen

Fundamentals and applications of neutron imaging. Application part 9. Application of neutron imaging to biological research

International Nuclear Information System (INIS)

Kawabata, Yuji

2007-01-01

For radiography, the use of neutrons as a complement to X-rays is especially suitable for biological research such as plant, wood, and medical application due to the enhanced sensitivity to light elements such as hydrogen, carbon, and nitrogen. The present paper introduces applications of neutron CT to the humidity (water) distribution and its variation in the flowering plant as cut carnation, observation of water movement in refrigerated chrysanthemum leaves using very cold neutron and in cut leaves using deuterium oxide and ordinary water, measurement of water movement in sprouting cone and soy bean and growing ginseng in the soil, and other applications as to archaeological wood immersed in a restoration solution and to medical purposes. (S. Ohno)

An in situ thermo-mechanical rig for lattice strain measurement during creep using neutron diffraction

Science.gov (United States)

Wang, Y. Q.; Kabra, S.; Zhang, S. Y.; Truman, C. E.; Smith, D. J.

2018-05-01

A long-term high-temperature testing stress rig has been designed and fabricated for performing in situ neutron diffraction tests at the ENGIN-X beamline, ISIS facility in the UK. It is capable of subjecting metals to high temperatures up to 800 °C and uniaxial loading under different boundary conditions including constant load, constant strain, and elastic follow-up, each with minimum of external control. Samples are held horizontally between grips and connected to a rigid rig frame, a soft aluminium bar, and a stepper motor with forces up to 20 kN. A new three zone split electrical resistance furnace which generates a stable and uniform heat atmosphere over 200 mm length was used to heat the samples. An 8 mm diameter port at 45° to the centre of the furnace was made in order to allow the neutron beam through the furnace to illuminate the sample. The entire instrument is mounted on the positioner at ENGIN-X and has the potential ability to operate continuously while being moved in and out of the neutron diffraction beam. The performance of the rig has been demonstrated by tracking the evolution of lattice strains in type 316H stainless steel under elastic follow-up control at 550 °C.

Principles of the measurement of residual stress by neutron diffraction

Energy Technology Data Exchange (ETDEWEB)

Webster, G A; Ezeilo, A N [Imperial Coll. of Science and Technology, London (United Kingdom). Dept. of Mechanical Engineering

1996-11-01

The presence of residual stresses in engineering components can significantly affect their load carrying capacity and resistance to fracture. In order to quantify their effect it is necessary to know their magnitude and distribution. Neutron diffraction is the most suitable method of obtaining these stresses non-destructively in the interior of components. In this paper the principles of the technique are described. A monochromatic beam of neutrons, or time of flight measurements, can be employed. In each case, components of strain are determined directly from changes in the lattice spacings between crystals. Residual stresses can then be calculated from these strains. The experimental procedures for making the measurements are described and precautions for achieving reliable results discussed. These include choice of crystal planes on which to make measurements, extent of masking needed to identify a suitable sampling volume, type of detector and alignment procedure. Methods of achieving a stress free reference are also considered. A selection of practical examples is included to demonstrate the success of the technique. (author) 14 figs., 1 tab., 18 refs.

Principles of the measurement of residual stress by neutron diffraction

International Nuclear Information System (INIS)

Webster, G.A.; Ezeilo, A.N.

1996-01-01

The presence of residual stresses in engineering components can significantly affect their load carrying capacity and resistance to fracture. In order to quantify their effect it is necessary to know their magnitude and distribution. Neutron diffraction is the most suitable method of obtaining these stresses non-destructively in the interior of components. In this paper the principles of the technique are described. A monochromatic beam of neutrons, or time of flight measurements, can be employed. In each case, components of strain are determined directly from changes in the lattice spacings between crystals. Residual stresses can then be calculated from these strains. The experimental procedures for making the measurements are described and precautions for achieving reliable results discussed. These include choice of crystal planes on which to make measurements, extent of masking needed to identify a suitable sampling volume, type of detector and alignment procedure. Methods of achieving a stress free reference are also considered. A selection of practical examples is included to demonstrate the success of the technique. (author) 14 figs., 1 tab., 18 refs

Data analysis of a polycrystalline nickel sample obtained with neutron diffraction

International Nuclear Information System (INIS)

Parente, C.B.R.; Mazzochi, V.L.; Araujo Kaschny, J.R. de; Costa, M.S. da; Rizzo, P.; Campos, W.M.S.

1990-01-01

A simple analysis of the nickel structure was made. Neutron diffraction data were used, obtained with polycrystalline nickel placed in a cylindrical sample-holder with dimensions of 1,5cm of diameter and 5cm of height. The theoretical intensities were calculated of 3 forms: 1. without considering the temperature and obsorption effects, 2. considering only the temperature effect and 3. considering both the temperature and absorption effects. The disagreement factors found in this 3 cases were, respectively, R 1 = 13.4%, R 2 = 7,7% e R 3 = 7,5%. (L.C.)

Application of neutrons in biology

International Nuclear Information System (INIS)

Cser, L.

1982-01-01

Applications of neutron scattering to determine the structure of biological macromolecules are reviewed. A theoretical and experimental introduction to neutron scattering and its mathematical description is given. The analysis of crystal structure using neutron scattering and the problem of Fourier reconstruction of structure are discussed. Some special problems concerning biological materials are described. The isotope effect of neutron scattering is applied to determine and identify the hydrogen atoms in biological macromolecules. Some examples illustrating the structure determination of amino acids and proteins are given. Mathematical methods of evaluation of small angle neutron scattering experiments and applications to investigate E. coli ribosome are described. New developments and new research trends are also reviewed. (D.Gy.)

Residual stress measurement in socket welded joints by neutron diffraction

International Nuclear Information System (INIS)

Hayashi, Makoto; Ishiwata, Masayuki; Minakawa, Noriaki; Funahashi, Satoru.

1995-01-01

Neutron diffraction measurements of lattice spacings provide the spatial map of residual stress near welds in ferritic steel socket joints. The high tensile stress greater than 200 MPa was found in the fusion and heat-affected zones in the hoop direction. However, the highest tensile stress in the axial direction at the weld root was about 110 MPa relatively lower than the expected value from the fatigue test results. The balancing compressive stress was found near the surface of the socket weld fusion zone. Heat treatment at 625degC for 2 hours was sufficient for the relief of residual stress in socket welds. (author)

Powder neutron diffraction study on Pb2Sr2YCu3O8+δ(δ = 0.0 and 1.67)

International Nuclear Information System (INIS)

Fujishita, Hideshi; Sato, Masatoshi; Morii, Yukio; Funahashi, Satoru.

1993-01-01

Powder neutron diffraction patterns of Pb 2 Sr 2 YCu 3 O 8+δ (δ = 0.0 and 1.67) were analyzed by Rietveld method. For δ = 0, it had been indicated, by powder X-ray diffraction, that the structure was a monoclinic one. The R factors of the present analysis for the monoclinic structure were about 3/4 of those for the previous orthorhombic ones. The structure was almost the same as the previous X-ray result except z (02). For the annealed phase, the tetragonal and the orthorhombic structures had been presented by X-ray diffraction and by neutron diffraction, respectively. The R factors of the present analysis for the orthorhombic structure were about 5/6 of those for the tetragonal structure. The distance between the Pb plane and the oxygen deficient Cu plane was found to become larger in proportion to δ, though there occurs a phase separation in low δ region. (author)

Effect of loading mode on lattice strain measurements via neutron diffraction

International Nuclear Information System (INIS)

Skippon, T.; Clausen, B.; Daymond, M.R.

2013-01-01

The study of lattice strain evolution during uniaxial deformation via in situ neutron diffraction is a well established technique for characterizing the deformation behavior of metals. However, the relatively low flux of neutron facilities results in count times on the order of several minutes, requiring experimenters to choose between either applying a very slow strain rate, or loading the sample incrementally rather than continuously. Here we investigate the effects on lattice strain data obtained by using stress, strain, and position controlled incremental loading, as well as continuous loading, on samples of Zircaloy-2 under uniaxial compression. It was found that both qualitative and quantitative differences arise in the lattice strain behavior of certain grain families, particularly {101 ¯ 0} and {112 ¯ 0}, while other grain families show no discernible effect. The differences in lattice strain evolution brought on by the variation in loading modes are believed to be the result of thermally activated dislocation motion

X-Ray and Neutron Diffraction Measurements of Dislocation Density and Subgrain Size in a Friction-Stir-Welded Aluminum Alloy

International Nuclear Information System (INIS)

Woo, Wan Chuck; Ungar, Tomas; Feng, Zhili; Kenik, Edward A.; Clausen, B.

2009-01-01

The dislocation density and subgrain size were determined in the base material and friction-stir welds of 6061-T6 aluminum alloy. High-resolution X-ray diffraction measurement was performed in the base material. The result of the line profile analysis of the X-ray diffraction peak shows that the dislocation density is about 4.5 x 10 14 m -2 and the subgrain size is about 200 nm. Meanwhile, neutron diffraction measurements have been performed to observe the diffraction peaks during friction-stir welding (FSW). The deep penetration capability of the neutron enables us to measure the peaks from the midplane of the Al plate underneath the tool shoulder of the friction-stir welds. The peak broadening analysis result using the Williamson-Hall method shows the dislocation density of about 3.2 x 10 15 m -2 and subgrain size of about 160 nm. The significant increase of the dislocation density is likely due to the severe plastic deformation during FSW. This study provides an insight into understanding the transient behavior of the microstructure under severe thermomechanical deformation

Neutron diffraction search for the charge density waves in early rare earth metal deuterides RD/sub 3/ (R = La, Ce)

Energy Technology Data Exchange (ETDEWEB)

Alikhanov, R A; Buzin, V I; Kulikov, N I [AN SSSR, Moscow. Inst. Fiziki Vysokikh Davlenij; Kost, M E [Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow (USSR); Sikora, W [Joint Inst. for Nuclear Research, Dubna (USSR); Smirnov, L S [Institute of Theoretical and Experimental Physics, Moscow (USSR)

1984-08-01

The results of neutron diffraction measurements performed on CeDsub(x) near the trihydride composition MeD/sub 3/ at room temperature and on LaDsub(2.9) at liquid nitrogen and room temperatures are presented. Superstructure reflections have been found. The system of additional reflections in lanthanum deuteride is different from that in cerium deuteride. The concentration and temperature boundaries for the transformed phases are reported. The experimental results are discussed on the basis of Kulikov's excitonic dielectric model for metal-to-semiconductor phase transitions. The determination of crystal structures from experimental neutron diffraction patterns is discussed.

A Neutron-Diffraction Study of the Solid Layers at the Liquid Solid Boundary in 4He-Films Adsorbed on Graphite

DEFF Research Database (Denmark)

da Costa Carneiro, Kim; Passell, L.; Thomlinson, W.

1981-01-01

A neutron scattering study of the structure of 4He films adsorbed on graphite is reported. Diffraction from helium monolayers at a temperature of 1.2K shows the formation of an incommensurate, triangular-lattice solid of high density. As the coverage is increased above two layers, the diffraction...

Determination of crystalline texture in aluminium - uranium alloys by neutron diffraction

International Nuclear Information System (INIS)

Azevedo, A.M.V. de.

1978-01-01

Textures of hot-rolled aluminum-uranium alloys and of aluminum were determined by neutron diffraction. Sheets of alloys containing 8.0, 21.5 and 23.7 wt pct U, as well as pure aluminum, were obtained in a stepped rolling process, 15% reduction each step, 75% total reduction. During the rolling the temperature was 600 0 C. Alloys with low uranium contents are two phase systems in which an intermetallic compound UAl 4 , orthorhombic, is dispersed in a pure aluminum matrix. The addition of a few percent of Si in such alloys leads to the formation of UAl 3 , simple cubic, instead of UAl 4 . The Al -- 23.7 wt pct U alloy was prepared with 2,2 wt pct of Si. The results indicate that the texture of the matrix is more dependent on the uranium concentration than on the texture of the intermetallic phases. An improvement in the technique applied to texture measurements by using a sample fully bathed in the neutron beam is also presented. The method takes advantage of the low neutron absorption of the studied materials as well as of the neglibible variation in the multiple scattering which occurs in a conveniently shaped sample having a weakly developed texture. (Author) [pt

Crystal structure of barium hydride, determined by neutron diffraction experiments on BaD2

International Nuclear Information System (INIS)

Bronger, W.; Scha Chi-Chien; Mueller, P.

1987-01-01

A reinvestigation of the structure of BaH 2 and BaD 2 was performed on powdered samples by X-ray- and neutron diffraction experiments. It is shown, that the hydrogen positions correspond with those found in calcium deuteride and not with those proposed in the literature. The classification of barium hydride in the PbCl 2 structure type is discussed. (author)

High-pressure cells for study of condensed matter by diffraction and inelastic neutron scattering at low temperatures and in strong magnetic fields

Science.gov (United States)

Sadykov, R. A.; Strassle, Th; Podlesnyak, A.; Keller, L.; Fak, B.; Mesot, J.

2017-12-01

We have developed and implemented series of new original clamp high-pressure cells for neutron diffraction and inelastic neutron scattering at low temperatures. The cells design allows one to place them in the standard cryostats or cryomagnets used on neutron sources. Some results obtained for ZnCr2Se4 are demonstrated as an example.

Residual stresses determination by neutron diffraction in a 100Cr6 chromium steel bearing ring

Czech Academy of Sciences Publication Activity Database

Rogante, M.; Martinat, G.; Mikula, Pavol; Vrána, Miroslav

2013-01-01

Roč. 51, č. 5 (2013), s. 275-281 ISSN 0023-432X R&D Projects: GA MŠk(XE) LM2011019 Institutional support: RVO:61389005 Keywords : 100Cr6 steel * rings * martensitic hardening * tempering * residual stress es * neutron diffraction Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 0.546, year: 2013

Kinetic studies of methane-ethane mixed gas hydrates by neutron diffraction and Raman spectroscopy.

Science.gov (United States)

Murshed, M Mangir; Kuhs, Werner F

2009-04-16

In situ formations of CH(4)-C(2)H(6) mixed gas hydrates were made using high flux neutron diffraction at 270 K and 5 MPa. For this purpose, a feed gas composition of CH(4) and C(2)H(6) (95 mol% CH(4)) was employed. The rates of transformation of spherical grains of deuterated ice Ih into hydrates were measured by time-resolved neutron powder diffraction on D20 at ILL, Grenoble. Phase fractions of the crystalline constituents were obtained from Rietveld refinements. A concomitant formation of structure type I (sI) and structure type II (sII) hydrates were observed soon after the gas pressure was applied. The initial fast formation of sII hydrate reached its maximum volume and started declining very slowly. The formation of sI hydrate followed a sigmoid growth kinetics that slowed down due to diffusion limitation. This observation has been interpreted in terms of a kinetically favored nucleation of the sII hydrate along with a slow transformation into sI. Both powder diffraction and Raman spectroscopic results suggest that a C(2)H(6)-rich sII hydrate was formed at the early part of the clathration, which slowly decreased to approximately 3% after a reaction of 158 days as confirmed by synchrotron XRD. The final persistence of a small portion of sII hydrate points to a miscibility gap between CH(4)-rich sI and C(2)H(6)-rich sII hydrates.

In-situ neutron diffraction during biaxial deformation

International Nuclear Information System (INIS)

Van Petegem, S.; Wagner, J.; Panzner, T.; Upadhyay, M.V.; Trang, T.T.T.; Van Swygenhoven, H.

2016-01-01

A change in strain path may have a significant effect on the mechanical response of metals. In order to understand or even predict the macroscopic behaviour under such conditions a detailed knowledge on the microstructural evolution is crucial. Yet relatively little work has been done to quantify and understand how the inter- and intragranular strains are affected during a change in strain path. In this work we present a new multiaxial deformation rig that allows performing in situ proportional and non-proportional loading under neutron diffraction. We demonstrate the capabilities of this new setup for the case of a 316 L stainless steel. We show that the nature and magnitude of intergranular strain strongly depends on the applied stress state and demonstrate that micro yielding and internal strain recovery are responsible for the observed transient softening during a 90° strain path change. We anticipate that this new characterization method will provide previously inaccessible microstructural data that can serve as input for benchmarking current state-of-the-art crystal plasticity models.

Evaluation of residual stresses in composite materials by using neutron diffraction; study of elasto-plasticity; Etude des composites a matrice metallique par la technique de la diffraction de neutrons: analyse du comportement elastoplastique et evaluation des contraintes residuelles

Energy Technology Data Exchange (ETDEWEB)

Levy-Tubiana, R

1999-11-05

This work deals with the study of Metal Matrix Composites (MMC) using neutrons diffraction method and the analysis of the elastoplastic behavior in such materials. First, we evaluated macro-stresses in aluminium MMC reinforced with 17%vol. of SiC particles. One of the analyzed sample has been 4 point bending deformed, measurements have been performed after relaxation. The difference between the coefficients of thermal expansion constrains the matrix to be in tensile state and the particles in compressive state in the sample which has not be deformed. In the sample deformed, the MMC response is predicted by the science of Resistance Materials applied to a bent bar. We assume that macro-stresses are the sum of stresses with different origins (elastic, plastic, thermal mismatch): elastic mismatch is evaluated by Eshelby model and we determined micro-stresses in the unbent bar: they are equivalent and constant along width direction. For the bent bar, we observe relaxation of thermal stresses in the surface region. Theses results are confirmed by measurements of tensile/compressive sample using neutrons diffraction method. We also observed the influence of mechanical and thermal treatment on such MMC: the shear stress (established by the auto-coherent model) depends only on the way of cooling. Finally, a study was performed on titanium MMC for SNECMA on rotor beings used in the gas turbine engine industry. Evolution of stresses between felloe and boring is confirmed by a finite elements modeling and they are the first experimental results in this application. (author)

Neutron and X-ray diffraction from modulated structures

International Nuclear Information System (INIS)

Harris, P.

1994-07-01

This thesis describes X-ray and neutron scattering experiments performed on two examples of modulated structures. After an introduction to the subject of modulated structures, the thesis is divided in three parts. A single crystal elastic neutron scattering experiment between 4.2 and 115 Κ has been performed and four-circle X-ray data have been collected at 8 Κ for the monoclinic low-temperature phase of the layered perovskite PAMC. The results from the neutron scattering experiment indicate that magnetoelastic effects influence the ordering of the crystal. The X-ray experiments have made it possible to determine the crystal structure in the low-temperature phase. The superspace group is P2 1 /b(β-30)Os, with β = 1/3. A small-angle neutron scattering experiment has been performed on the magnetic structure of manganese silicide. When a magnetic field is applied, the modulation vectors turn towards the field direction, showing domain growth and diverging peak widths as they approach the field direction. Phase 'A' is established to have the modulation vectors directed perpendicular to the field direction. Cooling in zero field shows increasing peak widths at low temperatures, indicating a lock-in transition below the lowest reached temperature. To be able to analyse the data of the magnetic order in MnSi, and analytical calculation of the three dimensional resolution function for a small-angle neutron scattering spectrometer has been performed. The calculation is done by application of a combination of phase space analysis and Gaussian approximations for the neutron distribution as well as for the transmission functions of the different apertures. A finite mosaic spread of the crystal and finite correlation widths of the Bragg reflections have been included in the cross section. (au) (3 tabs., 48 ills., 100 refs.)

Stress distribution in mechanically surface treated Ti-2.5Cu determined by combining energy-dispersive synchrotron and neutron diffraction

International Nuclear Information System (INIS)

Maawad, E.; Brokmeier, H.-G.; Hofmann, M.; Genzel, Ch.; Wagner, L.

2010-01-01

Mechanical surface treatments such as shot peening (SP) or ball-burnishing (BB) induce plastic deformation close to the surface resulting in work-hardening and compressive residual stresses. It enhances the fatigue performance by retarding or even suppressing micro-crack growth from the surface into the interior. SP and BB were carried out on a solution heat treated (SHT) Ti-2.5Cu. The investigations of compressive and balancing tensile residual stresses need a combination of energy-dispersive synchrotron (ED) and neutron diffraction. Essential for the stress distribution is the stress state before surface treatments which was determined by neutron diffraction. Results show that the maximum compressive stress and its depth play an important role to improve the fatigue performance.

Study of the earth's deep interior and crystallography. X-ray and neutron diffraction experiments under high pressures

International Nuclear Information System (INIS)

Yagi, Takehiko

2014-01-01

History of the study of the Earth's deep interior was reviewed. In order to understand Earth's deep interior from the view point of materials science, X-ray diffraction under high pressure and high temperature played very important role. Use of synchrotron radiation dramatically advanced this experimental technique and it is now possible to make precise X-ray study under the P-T conditions corresponding even to the center of the Earth. In order to clarify the behavior of light elements such as hydrogen, however, studies using neutron diffraction are also required. A new neutron beam line dedicated for high-pressure science is constructed at J-PARC and is now ready for use. (author)

Secondary extinction in cylindrical and spherical crystals for X-ray and neutron diffraction

International Nuclear Information System (INIS)

Hu Huachen; Li Zhaohuan; Yang Bin; Shen Caiwan

2001-01-01

The distribution of the reflection power ratio for a neutron or x-ray diffracted from a cylindrical crystal immersed in an homogenous incident beam is obtained by the numerical solution of the transfer equations for the first time. The profile well reflects all the physical properties of the absorption and extinction behaviour in the crystals. A systematic investigation of the secondary extinction for cylindrical and spherical crystals was carried out based on these results

Neutron-Diffraction Study of the Phase Transition in Stannous Chloride Dihydrate

DEFF Research Database (Denmark)

Youngblood, R.; Kjems, Jørgen

1979-01-01

of the system does not change. We present neutron-diffraction results which show that the temperature dependence of the hydrogen-site occupancies is also highly symmetric around the phase-transition temperature. These results are discussed in terms of a lattice statistical model which was proposed and solved......The order-disorder phase transition in two-dimensional hydrogen-bonded layers of water molecules in SnCl2·2D2O is remarkable in several respects. It has been shown that the peak in the specific heat is highly symmetric around the phase-transition temperature, and that the crystallographic symmetry...

Neutron diffraction study of a nitrogen martensitic steel 0Kh16N4AB under load

Czech Academy of Sciences Publication Activity Database

Sumin, V. V.; Papushkin, I.V.; Bannykh, O.A.; Blinov, V.M.; Lukáš, Petr

2008-01-01

Roč. 105, č. 1 (2008), s. 88-91 ISSN 0031-918X Institutional research plan: CEZ:AV0Z10480505 Keywords : steel 0Kh16N4AB * neutron diffraction * FSD Subject RIV: BG - Nuclear, Atomic and Molecular Physics , Colliders Impact factor: 0.412, year: 2008

Neutron diffraction studies on Ca1− xBaxZr4P6O24 solid solutions

Indian Academy of Sciences (India)

P6O24 compositions from combined Rietveld refinements of powder X-ray and neutron diffraction data. All the studied compositions crystallize in rhombohedral lattice (space group R-3 No. 148). A continuous solid solution is concluded from ...

Twinning processes in Cu-Al-Ni martensite single crystals investigated by neutron single crystal diffraction method

International Nuclear Information System (INIS)

Molnar, P.; Sittner, P.; Novak, V.; Lukas, P.

2008-01-01

A neutron single crystal diffraction method for inspecting the quality of martensite single crystals is introduced. True interface-free martensite single crystals are indispensable for, e.g. measurement of elastic constants of phases by ultrasonic techniques. The neutron diffraction method was used to detect and distinguish the presence of individual lattice correspondence variants of the 2H orthorhombic martensite phase in Cu-Al-Ni as well as to follow the activity of twinning processes during the deformation test on the martensite variant single crystals. When preparing the martensite single variant prism-shaped crystals by compression deformation method, typically a small fraction of second unwanted martensitic variant (compound twin) remains in the prism samples. Due to the very low stress (∼1 MPa) for the compound twinning in many shape memory alloys, it is quite difficult not only to deplete the martensite prisms of all internal interfaces but mainly to keep them in the martensite single variant state for a long time needed for further investigations

Diffraction limit of refractive compound lens

International Nuclear Information System (INIS)

Kolchevsky, N.N.; Petrov, P.V.

2015-01-01

A compound X-ray and neutron lenses is an array of lenses with a common axis. The resolution limited by aberration and by diffraction. Diffraction limit comes from theory based on absorption aperture of the compound refractive lenses. Beam passing through transparent lenses form Airy pattern. Results of calculation of diffraction resolution limit for non-transparent X-ray and neutron lenses are discussed. (authors)

Neutron diffraction studies and magnetism in Ti doped SrFeO3−δ systems

International Nuclear Information System (INIS)

Sendil Kumar, A.; Srinath, S.; Babu, P. D.

2014-01-01

The magnetic ground state of single phase tetragonal crystal structure with I4/mmm space group SrFe 1−x Ti x O 3−δ (x = 0.2 and 0.3) is investigated from 2 K to 300 K. Strong irreversibility is observed in zero-field-cooled (ZFC) and field-cooled DC magnetization curves. Arrott plots show the absence of spontaneous magnetization (M S ) down to 2 K, ruling out the possibility of long range ferromagnetic order. Neutron diffraction measurements carried out at H = 0, 7 T (field cooled) at several temperatures above and below the T* (temperature at which M ZFC (T) is maximum) do not show any additional peaks and also no difference in intensity rules out, both the long range antiferromagnetic and ferromagnetic orders. Hence, the combined study of dc magnetization and neutron diffraction results reveals cluster spin glass behavior in SrFe 1−x Ti x O 3−δ (x = 0.2 and 0.3)

In situ neutron diffraction studies of martensitic transformations in NiTi polycrystals under tension and compression stress

Czech Academy of Sciences Publication Activity Database

Šittner, Petr; Lukáš, Petr; Novák, Václav; Daymond, M. R.; Swallowe, G. M.

2004-01-01

Roč. 378, - (2004), s. 97-104 ISSN 0921-5093 Institutional research plan: CEZ:AV0Z1010914 Keywords : martensitic transformation * shape memory alloy * neutron diffraction * NiTi Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.445, year: 2004

Investigation of phase transformations by in-situ neutron diffraction in a Co-Re-based high temperature alloy

Czech Academy of Sciences Publication Activity Database

Mukherji, D.; Strunz, Pavel; Gilles, R.; Hofmann, M.; Schmitz, F.; Rösler, J.

2010-01-01

Roč. 64, č. 23 (2010), s. 2608-2611 ISSN 0167-577X Institutional research plan: CEZ:AV0Z10480505 Keywords : Superalloy * Carbide * Neutron diffraction Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 2.120, year: 2010

Deformation behavior of Mg-alloy-based composites at different temperatures studied by neutron diffraction

Czech Academy of Sciences Publication Activity Database

Farkas, Gergely; Máthis, K.; Pilch, Jan; Minárik, P.; Lukáš, Petr; Vinogradov, A.

2017-01-01

Roč. 685, FEB (2017), s. 284-293 ISSN 0921-5093 R&D Projects: GA ČR GB14-36566G; GA MŠk LM2015056 Institutional support: RVO:61389005 Keywords : magnesium alloy matrix composite s * neutron diffraction * deformation * twinning Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) Impact factor: 3.094, year: 2016

Complex investigation of deformation twinning in gamma-TiAl by TEM and neutron diffraction

Czech Academy of Sciences Publication Activity Database

Beran, Přemysl; Heczko, Milan; Kruml, Tomáš; Panzner, T.; van Petegem, S.

2016-01-01

Roč. 95, OCT (2016), s. 647-662 ISSN 0022-5096 R&D Projects: GA ČR(CZ) GAP107/11/0704; GA MŠk(CZ) ED1.1.00/02.0068 Institutional support: RVO:68081723 ; RVO:61389005 Keywords : dislocations * twinning * polycrystalline material * neutron diffraction * electron microscopy Subject RIV: BM - Solid Matter Physics ; Magnetism; JL - Materials Fatigue, Friction Mechanics (UFM-A) Impact factor: 4.255, year: 2016

Assessment of Shape Memory Alloys - From Atoms To Actuators - Via In Situ Neutron Diffraction

Science.gov (United States)

Benafan, Othmane

2014-01-01

As shape memory alloys (SMAs) become an established actuator technology, it is important to identify the fundamental mechanisms responsible for their performance by understanding microstructure performance relationships from processing to final form. Yet, microstructural examination of SMAs at stress and temperature is often a challenge since structural changes occur with stress and temperature and microstructures cannot be preserved through quenching or after stress removal, as would be the case for conventional materials. One solution to this dilemma is in situ neutron diffraction, which has been applied to the investigation of SMAs and has offered a unique approach to reveal the fundamental micromechanics and microstructural aspects of bulk SMAs in a non-destructive setting. Through this technique, it is possible to directly correlate the micromechanical responses (e.g., internal residual stresses, lattice strains), microstructural evolutions (e.g., texture, defects) and phase transformation properties (e.g., phase fractions, kinetics) to the macroscopic actuator behavior. In this work, in situ neutron diffraction was systematically employed to evaluate the deformation and transformation behavior of SMAs under typical actuator conditions. Austenite and martensite phases, yield behavior, variant selection and transformation temperatures were characterized for a polycrystalline NiTi (49.9 at. Ni). As the alloy transforms under thermomechanical loading, the measured textures and lattice plane-level variations were directly related to the cyclic actuation-strain characteristics and the dimensional instability (strain ratcheting) commonly observed in this alloy. The effect of training on the shape memory characteristics of the alloy and the development of two-way shape memory effect (TWSME) were also assessed. The final conversion from a material to a useful actuator, typically termed shape setting, was also investigated in situ during constrained heatingcooling and

Kinetics of methane-ethane gas replacement in clathrate-hydrates studied by time-resolved neutron diffraction and Raman spectroscopy.

Science.gov (United States)

Murshed, M Mangir; Schmidt, Burkhard C; Kuhs, Werner F

2010-01-14

The kinetics of CH(4)-C(2)H(6) replacement in gas hydrates has been studied by in situ neutron diffraction and Raman spectroscopy. Deuterated ethane structure type I (C(2)H(6) sI) hydrates were transformed in a closed volume into methane-ethane mixed structure type II (CH(4)-C(2)H(6) sII) hydrates at 5 MPa and various temperatures in the vicinity of 0 degrees C while followed by time-resolved neutron powder diffraction on D20 at ILL, Grenoble. The role of available surface area of the sI starting material on the formation kinetics of sII hydrates was studied. Ex situ Raman spectroscopic investigations were carried out to crosscheck the gas composition and the distribution of the gas species over the cages as a function of structure type and compared to the in situ neutron results. Raman micromapping on single hydrate grains showed compositional and structural gradients between the surface and core of the transformed hydrates. Moreover, the observed methane-ethane ratio is very far from the one expected for a formation from a constantly equilibrated gas phase. The results also prove that gas replacement in CH(4)-C(2)H(6) hydrates is a regrowth process involving the nucleation of new crystallites commencing at the surface of the parent C(2)H(6) sI hydrate with a progressively shrinking core of unreacted material. The time-resolved neutron diffraction results clearly indicate an increasing diffusion limitation of the exchange process. This diffusion limitation leads to a progressive slowing down of the exchange reaction and is likely to be responsible for the incomplete exchange of the gases.

Dynamic processes of domain switching in lead zirconate titanate under cyclic mechanical loading by in situ neutron diffraction

International Nuclear Information System (INIS)

Pojprapai, Soodkhet; Luo, Zhenhua; Clausen, Bjorn; Vogel, Sven C.; Brown, Donald W.; Russel, Jennifer; Hoffman, Mark

2010-01-01

The performance of ferroelectric ceramics is governed by the ability of domains to switch. A decrease in the switching ability can lead to degradation of the materials and failure of ferroelectric devices. In this work the dynamic properties of domain reorientation are studied. In situ time-of-flight neutron diffraction is used to probe the evolution of ferroelastic domain texture under mechanical cyclic loading in bulk lead zirconate titanate ceramics. The high sensitivity of neutron diffraction to lattice strain is exploited to precisely analyze the change of domain texture and strain through a full-pattern Rietveld method. These results are then used to construct a viscoelastic model, which explains the correlation between macroscopic phenomena (i.e. creep and recovered deformation) and microscopic dynamic behavior (i.e. ferroelastic switching, lattice strain).

Low-temperature neutron diffraction study of La 0.95 Nd 0.05 CrO 3

Indian Academy of Sciences (India)

We have synthesized polycrystalline La0.95Nd0.05CrO3 sample by doping the La-site of LaCrO3 with Nd and its magnetic properties have been studied using DC magnetization and neutron diffraction techniques. DC magnetization study shows a paramagnetic to a weak ferromagnetic-like transition at ∼295 K followed by ...

Design of a new lithium ion battery test cell for in-situ neutron diffraction measurements

Czech Academy of Sciences Publication Activity Database

Roberts, M.; Biendicho, J. J.; Hull, S.; Beran, Přemysl; Gustafsson, T.; Svensson, G.; Edstrom, K.

2013-01-01

Roč. 226, MAR 15 (2013), s. 249-255 ISSN 0378-7753 R&D Projects: GA MŠk(XE) LM2011019 Institutional support: RVO:61389005 Keywords : neutron * Lithium * LiFePO4 * diffraction * in situ Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 5.211, year: 2013 http://www.sciencedirect.com/science/article/pii/S0378775312016515

Neutron diffraction investigation of hysteresis reduction and increase in linearity in the stress-strain response of superelastic NiTi

International Nuclear Information System (INIS)

Rathod, C.R.; Clausen, B.; Bourke, M.A.M.; Vaidyanathan, R.

2006-01-01

In situ neutron diffraction measurements during loading have been performed on plastically deformed superelastic NiTi samples. The measurements observed retained B19 ' phase in the unloaded state as a result of the plastic deformation in otherwise completely B2 phase samples. A reversible stress-induced B2-B19 ' transformation on application and removal of stress occurred in the presence of this retained B19 ' phase. The amount and orientation of this retained B19 ' phase changed with cycling. Such direct atomic scale observations in the bulk are used here for the first time to qualitatively elucidate the macroscopic stress-strain response in plastically deformed superelastic NiTi

Neutron applications in materials for energy

CERN Document Server

Kearley, Gordon J

2015-01-01

Neutron Applications in Materials for Energy collects results and conclusions of recent neutron-based investigations of materials that are important in the development of sustainable energy. Chapters are authored by leading scientists with hands-on experience in the field, providing overviews, recent highlights, and case-studies to illustrate the applicability of one or more neutron-based techniques of analysis. The theme follows energy production, storage, and use, but each chapter, or section, can also be read independently, with basic theory and instrumentation for neutron scattering being

Magnetic structure of the swedenborgite CaBa (Co3Fe ) O7 derived by unpolarized neutron diffraction and spherical neutron polarimetry

Science.gov (United States)

Qureshi, N.; Díaz, M. T. Fernández; Chapon, L. C.; Senyshyn, A.; Schweika, W.; Valldor, M.

2018-02-01

We present a study that combines polarized and unpolarized neutrons to derive the magnetic structure of the swedenborgite compound CaBa (Co3Fe ) O7. Integrated intensities from a standard neutron diffraction experiment and polarization matrices from spherical neutron polarimetry have been simultaneously analyzed revealing a complex order, which differs from the usual spin configurations on a kagome lattice. We find that the magnetic structure is well described by a combination of two one-dimensional representations corresponding to the magnetic superspace symmetry P 21' , and it consists of spins rotating around an axis close to the [110] direction. Due to the propagation vector q =(1/3 00 ) , this modulation has cycloidal and helicoidal character rendering this system a potential multiferroic. The resulting spin configuration can be mapped onto the classical √{3 }×√{3 } structure of a kagome lattice, and it indicates an important interplay between the kagome and the triangular layers of the crystal structure.

Diffraction analysis of the microstructure of materials

CERN Document Server

Scardi, Paolo

2004-01-01

Diffraction Analysis of the Microstructure of Materials provides an overview of diffraction methods applied to the analysis of the microstructure of materials. Since crystallite size and the presence of lattice defects have a decisive influence on the properties of many engineering materials, information about this microstructure is of vital importance in developing and assessing materials for practical applications. The most powerful and usually non-destructive evaluation techniques available are X-ray and neutron diffraction. The book details, among other things, diffraction-line broadening methods for determining crystallite size and atomic-scale strain due, e.g. to dislocations, and methods for the analysis of residual (macroscale) stress. The book assumes only a basic knowledge of solid-state physics and supplies readers sufficient information to apply the methods themselves.

Neutron diffraction on CeMnAlD{sub x} (0{<=}x{<=}2.5)

Energy Technology Data Exchange (ETDEWEB)

Spatz, P.; Gross, K.; Schlapbach, L. [Fribourg Univ. (Switzerland); Fischer, P.; Fauth, F. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

1997-09-01

CeMnAl was found to absorb considerable amounts of hydrogen. Part of the totally stored hydrogen is absorbed at low pressures (< 10 mbar). Additional hydrogen can be absorbed and desorbed reversible in a wide pressure range (10 mbar to 10 bar) at room temperature. In order to a better understanding of this new metal-hydride system, we performed neutron diffraction on deuterated CeMnAl samples with different D-concentrations. (author) 1 fig., 2 refs.

Residual Stress Measurement of SiC tile/Al7075 Hybrid Composites by Neutron Diffraction

Energy Technology Data Exchange (ETDEWEB)

Park, Jong Bok; Lee, Jun Ho; Hong, Soon Hyung; Ryu, Ho Jin [KAIST, Daejeon (Korea, Republic of); Lee, Sang Bok; Lee, Sang Kwan [Korea Institute of Materials Science, Changwon (Korea, Republic of); Muslihd, M. Rifai [Center for Advanced Materials Science and Technology, Tangerang (India)

2016-05-15

In this research, SiC which has low density, high compressive strength, and high elastic modulus was used to fabricate the armor plate. In addition, Al which has low density and high toughness was used for a metal matrix of the composites. If two materials are combined, the composite can be effective materials for light weight armor applications. However, the existence of a large difference in coefficients of thermal expansion (CTE) between SiC and Al matrix, SiC/Al composites can have residual stresses while cooled in the fabrication process. Previous research reported that residual stresses in the composites or microstructures have an effect on the fatigue life and their mechanical properties. Some researchers reported about the residual stresses in the SiCp/Al metal matrix composites by numerical simulation systems, X-ray diffraction, and destructive methods. In order to analyze the residual stress of SiC/Al composites, the neutron diffraction as the non-destructive method was performed in this research. The 50 vol.% SiC{sub p}/Al7075 composites and SiC tile inserted 50 vol.% SiC{sub p}/Al7075 hybrid composites were measured to analyze the residual stress of Al (111) and SiC (111). Both samples had the tensile residual stresses in the Al (111) and the compressive residual stresses in the SiC (111) due to the difference in CTE.

Neutron diffraction studies of a double-crystal ( plus n,-m) setting containing a fully asymmetric diffraction geometry (FAD) of a bent perfect crystal (BPC)

Czech Academy of Sciences Publication Activity Database

Mikula, Pavol; Vrána, Miroslav; Šaroun, Jan; Em, V.

2017-01-01

Roč. 32, Supl-1 (2017), s. 13-18 ISSN 0885-7156 R&D Projects: GA ČR GC16-08803J; GA MŠk LM2015048 Institutional support: RVO:61389005 Keywords : neutron diffraction * monochromator * bent perfect crystal Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) Impact factor: 0.674, year: 2016

Scope of neutron interferometry

International Nuclear Information System (INIS)

Rauch, H.

1978-01-01

This paper deals with the interferometry of well separated coherent beams, where the phase of the beams can be manipulated individually. The basic equation of the dynamical neutron diffraction theory are recalled. The various contributions to the interaction of as low neutron with its surroundings are discussed: the various terms denote the nuclear, magnetic, electromagnetic, intrinsic, gravitational, and weak interaction respectively. Applications to nuclear physics, fundamental physics and solid state physics are successively envisaged

In Situ Neutron Diffraction of Rare-Earth Phosphate Proton Conductors Sr/Ca-doped LaPO4 at Elevated Temperatures

Science.gov (United States)

Al-Wahish, Amal; Al-Binni, Usama; Bridges, C. A.; Huq, A.; Bi, Z.; Paranthaman, M. P.; Tang, S.; Kaiser, H.; Mandrus, D.

Acceptor-doped lanthanum orthophosphates are potential candidate electrolytes for proton ceramic fuel cells. We combined neutron powder diffraction (NPD) at elevated temperatures up to 800° C , X-ray powder diffraction (XRD) and scanning electron microscopy (SEM) to investigate the crystal structure, defect structure, thermal stability and surface topography. NPD shows an average bond length distortion in the hydrated samples. We employed Quasi-Elastic Neutron Scattering (QENS) and electrochemical impedance spectroscopy (EIS) to study the proton dynamics of the rare-earth phosphate proton conductors 4.2% Sr/Ca-doped LaPO4. We determined the bulk diffusion and the self-diffusion coefficients. Our results show that QENS and EIS are probing fundamentally different proton diffusion processes. Supported by the U.S. Department of Energy.

Neutron diffraction study of history dependence in MnFeP0.6Si0.4

International Nuclear Information System (INIS)

Zhang, L.; Moze, O.; Prokes, K.; Tegus, O.; Brueck, E.

2005-01-01

In the MnFe(P,As) compounds which are promising magnetorefrigerant materials, we have studied the effect of Si substitution and successfully replaced As by Si. Surprisingly besides all the other changes, a peculiar history dependence of the magnetic phase transition was disclosed. The as-prepared sample shows a significantly lower transition temperature (namely a virgin T C ) than the sample that has experienced thermal cycling. The neutron diffraction patterns recorded during the first cooling manifest the first-order and magnetic-field-induced characters of the virgin phase transition. However, the refinement of the diffraction patterns does not provide evidence for atomic-position swapping, which might account for this history dependence

Neutron diffraction as a precise and reliable method for obtaining structural properties of bulk quantities of graphene

Czech Academy of Sciences Publication Activity Database

Sofer, Z.; Šimek, P.; Jankovský, O.; Sedmidubský, D.; Beran, Přemysl; Pumera, M.

2014-01-01

Roč. 6, č. 21 (2014), s. 13082-13089 ISSN 2040-3364 R&D Projects: GA MŠk(XE) LM2011019 Institutional support: RVO:61389005 Keywords : graphen * graphit oxide * neutron diffraction Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 7.394, year: 2014

Structures of high and low density amorphous ice by neutron diffraction

International Nuclear Information System (INIS)

Finney, J.L.; Hallbrucker, A.; Kohl, I.; Soper, A.K.; Bowron, D.T.

2002-01-01

Neutron diffraction with isotope substitution is used to determine the structures of high (HDA) and low (LDA) density amorphous ice. Both 'phases' are fully hydrogen bonded, tetrahedral networks, with local order similarities between LDA and ice Ih, and HDA and liquid water. Moving from HDA, through liquid water and LDA to ice Ih, the second shell radial order increases at the expense of spatial order. This is linked to a fifth first neighbor 'interstitial' that restricts the orientations of first shell waters. This 'lynch pin' molecule which keeps the HDA structure intact has implications for the nature of the HDA-LDA transition that bear on the current metastable water debate

Twinning processes in Cu-Al-Ni martensite single crystals investigated by neutron single crystal diffraction method

Czech Academy of Sciences Publication Activity Database

Molnar, P.; Šittner, P.; Novák, V.; Lukáš, Petr

2008-01-01

Roč. 481, Sp.Iss.SI (2008), s. 513-517 ISSN 0921-5093 R&D Projects: GA AV ČR IAA100480704 Institutional research plan: CEZ:AV0Z10480505 Keywords : Cu-Al-Ni * single crystals * neutron diffraction Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 1.806, year: 2008

14 MeV neutrons physics and applications

CERN Document Server

Valkovic, Vladivoj

2015-01-01

Despite the often difficult and time-consuming effort of performing experiments with fast (14 MeV) neutrons, these neutrons can offer special insight into nucleus and other materials because of the absence of charge. 14 MeV Neutrons: Physics and Applications explores fast neutrons in basic science and applications to problems in medicine, the environment, and security.Drawing on his more than 50 years of experience working with 14 MeV neutrons, the author focuses on:Sources of 14 MeV neutrons, including laboratory size accelerators, small and sealed tube generators, well logging sealed tube ac

Neutron diffraction study of the formation of ordered antiphase domains in cubic titanium carbide TiC0.60

International Nuclear Information System (INIS)

Khidirov, I.; Parpiev, A. S.

2013-01-01

A series of superstructural reflections (described within the sp. gr. Fd3m) are found to be split into three symmetric parts in the neutron powder diffraction pattern of titanium carbide TiC 0.60 annealed at a temperature of 600°C. No splitting of superstructural reflections is observed in the neutron diffraction pattern of TiC 0.60 annealed at relatively high temperatures (780°C). This phenomenon can be explained by that fact that the ordering of carbon atoms at relatively high temperatures (780°C) is accompanied by the formation of randomly oriented rather large antiphase domains (APDs) (450 Å). At relatively low temperatures (600°C), stacking faults arise in the arrangement of partially ordered carbon atoms. In this case, relatively small ordered APDs (290 Å) are formed, along with disordered ones.

Neutron diffraction and low temperature magnetization study of Tb0.8Y0.2MnO3

International Nuclear Information System (INIS)

Chakraborty, Keka R.; Mukadam, M.; Yusuf, S.M.; Shukla, R.; Tyagi, A.K.; Kaushik, S.D.; Siruguri, V.

2012-01-01

Multiferroic materials possess mutually correlated magnetic and electric order parameters which are suitable for device applications but scarcity of such materials and the separation of magnetic and electric ordering temperatures are a major hindrance in technological applications. TbMnO 3 is one of the material which is reported to have higher magnetoelectric coupling. Structurally, TbMnO 3 crystallizes in orthorhombically distorted perovskite structure (space group Pbnm). For TbMnO 3 , several reports are available in the literature which further modify the magnetoelectric coupling by selective doping or reducing the particle size to nano dimensions, or preparing thin films. Here, we study the effect of Y doping at Tb site in nanoparticle form in terms of crystal structure and magnetic properties. Nanoparticles of Tb 0.8 Y 0.2 MnO 3 were synthesized using the gel combustion technique. Crystal structure of this sample is studied at 300 K using neutron diffraction

Fundamentals and applications of neutron imaging. Applications part 5. Application of neutron imaging to fluid engineering-1

International Nuclear Information System (INIS)

Takenaka, Nobuyuki; Asano, Hitoshi; Umekawa, Hisashi; Matsubayashi, Masahito

2007-01-01

Characteristics of the neutron beam attenuation vary with elements constituting the object and it attenuates with hydrogen and a specific element greatly and penetrates most metal well. Normal liquid such as water, oil, the organic liquid includes a lot of hydrogen, and a neutron beam attenuates, but attenuation characteristics of the metal well used industrially such as iron, copper, aluminum are smaller than normal liquid. Because most machines are made of metal, and liquid behavior of the machine inside can be seen through neutron radiography, it is possible to be used as the X-rays of the machine. As an application of neutron radiography to the fluid engineering, fluid behavior in the metal pipe and container, especially two phase flow mingled with each phase of gas/liquid/solid, has been visible and measurable which is difficult to be performed by other methods, and in late years the industry use of neutron radiography attracts attention particularly. This serial course describes overviews of two-phase flow visualization and measurement and freezing/cooling machinery as the first example of recent application to the machinery. (T. Tanaka)

Fundamentals and applications of neutron imaging. Application part 3. Application of neutron imaging in aircraft, space rocket, car and gunpowder industries

International Nuclear Information System (INIS)

Ikeda, Yasushi

2007-01-01

Neutron imaging is applied to nondestructive test. Four neutron imaging facilities are used in Japan. The application examples of industries are listed in the table: space rocket, aircraft, car, liquid metal, and works of art. Neutron imaging of transportation equipments are illustrated as an application to industry. X-ray radiography testing (XRT) image and neutron radiography testing (NRT) image of turbine blade of aircraft engine, honeycomb structure of aircraft, helicopter rotor blade, trigger tube, separation nut of space rocket, carburetor of car, BMW engine, fireworks and ammunitions are illustrated. (S.Y.)

Integrated intensities and flipping ratios in neutron diffraction by perfect magnetic crystals

International Nuclear Information System (INIS)

Guigay, J.P.; Schlenker, M.

1979-01-01

A theoretical study of neutron diffraction by perfect magnetic crystals is presented which shows that when the magnetization is perpendicular to the diffraction vector (β- π/2), the dispersion surface is made up of two hyperbolic surfaces corresponding to simple polarization states and the results of the two-beam dynamical theory for non-magnetic crystals can be directly applied. The asymptotic properties of the dispersion surface are of the dispersion surface are also discussed in the more general case (β is not equal to π/2) and an analytical treatment of the kinematical limit is presented. Integrated intensities and flipping ratios outside this limit can only be calculated numerically. It is shown that the wave fields defined by the different points of the dispersion surface are polarized in the (g, B 0 ) plane; this is a generalization of the fact that they are (+-) states with respect to B 0 in the simple case (β=π/2). (UK)

Neutron radiography, techniques and applications

International Nuclear Information System (INIS)

Domanus, J.C.

1987-10-01

After describing the principles of the ''in pool'' and ''dry'' installations, techniques used in neutron radiography are reviewed. Use of converter foils with silver halide films for the direct and transfer methods is described. Advantages of the use of nitrocellulose film for radiographying radioactive objects are discussed. Dynamic imaging is shortly reviewed. Standardization in the field of neutron radiography (ASTM and Euratom Neutron Radiography Working Group) is described. The paper reviews main fields of use of neutron radiography. Possibilities of use of neutron radiography at research reactors in various scientific, industrial and other fields are mentioned. Examples are given of application of neutron radiography in industry and the nuclear field. (author)

An investigation of the structure of disordered materials by using neutron diffraction

International Nuclear Information System (INIS)

Petri, I.

1999-01-01

The structure of several semiconducting, metallic and ionic disordered materials was investigated using neutron diffraction and the results were compared with those obtained from recent ab initio molecular dynamics methods. The method of isotopic substitution was applied to measure the full set of partial structure factors, S αβ (Q), for the liquid semiconductor GeSe and the covalent network glass GeSe 2 . Their short range ordering and for GeSe 2 also the intermediate range ordering were identified and a substantial number of 'defects' such as homopolar bonds were detected in both systems. Further, the structure of liquid GeSe 2 with increasing temperature was studied at the total structure factor level. Also, changes in the topology of Ge x Se 1-x glasses in the range 0 ≤ x ≤ 0.4 were observed and investigated by measuring the total structure factors. As far as possible our results were compared with those from molecular dynamics studies. The Ge-Se system was found to serve as a sensitive test-system for these studies, giving an insight into the strengths and limitations of them. For instance, problems are found in the region of the homopolar bonds for g GeGe (r) and for the first sharp diffraction peak in the Bhatia-Thornton concentration-concentration structure factor that could not be reproduced. The structure of liquid lithium was measured and particular attention was paid to the inelasticity and resolution function corrections. The ion-ion and ion-valence electron partial structure factors were obtained and found to be in good agreement with ab initio molecular dynamics studies. The method of first order difference functions in neutron diffraction in combination with H/D substitution was applied to 2 molal solutions of Cu(ClO 4 ) 2 in perchloric acid to measure the Cu-H and, to a first order approximation, the Cu-O partial structure factor. A (4 + 1) distortion of the hydration shell around the Cu 2+ ion was measured. (author)

Residual stress characterization of steel TIG welds by neutron diffraction and by residual magnetic stray field mappings

Energy Technology Data Exchange (ETDEWEB)

Stegemann, Robert, E-mail: Robert.Stegemann@bam.de [Bundesanstalt für Materialforschung und -prüfung (BAM), Unter den Eichen 87, 12200 Berlin (Germany); Cabeza, Sandra; Lyamkin, Viktor; Bruno, Giovanni; Pittner, Andreas [Bundesanstalt für Materialforschung und -prüfung (BAM), Unter den Eichen 87, 12200 Berlin (Germany); Wimpory, Robert; Boin, Mirko [HZB Helmholtz-Zentrum Berlin, Hahn-Meitner-Platz 1, 14109 Berlin (Germany); Kreutzbruck, Marc [Bundesanstalt für Materialforschung und -prüfung (BAM), Unter den Eichen 87, 12200 Berlin (Germany); IKT, University of Stuttgart, Pfaffenwaldring 32, 70569 Stuttgart (Germany)

2017-03-15

The residual stress distribution of tungsten inert gas welded S235JRC+C plates was determined by means of neutron diffraction (ND). Large longitudinal residual stresses with maxima around 600 MPa were found. With these results as reference, the evaluation of residual stress with high spatial resolution GMR (giant magneto resistance) sensors was discussed. The experiments performed indicate a correlation between changes in residual stresses (ND) and the normal component of local residual magnetic stray fields (GMR). Spatial variations in the magnetic field strength perpendicular to the welds are in the order of the magnetic field of the earth. - Highlights: • Comparison of magnetic microstructure with neutron diffraction stress analysis. • High spatial resolution magnetic stray field images of hypereutectoid TIG welds. • Spatial variations of the stray fields are below the magnetic field of the earth. • GMR spin valve gradiometer arrays adapted for the evaluation of magnetic microstructures. • Magnetic stray fields are closely linked to microstructure of the material.

Analysis of neutron diffraction spectra acquired in situ during stress-induced transformations in superelastic NiTi

International Nuclear Information System (INIS)

Vaidyanathan, R.; Bourke, M.A.; Dunand, D.C.

1999-01-01

Neutron diffraction spectra were obtained during various stages of a reversible stress-induced austenite to martensite phase transformation in superelastic NiTi. This was accomplished by neutron diffraction measurements on bulk polycrystalline NiTi samples simultaneously subjected to mechanical loading. Analysis of the data was carried out using individual lattice plane (hkl) reflections as well as by Rietveld refinement. In the Rietveld procedure, strains in austenite were described in terms of an isotropic (hkl independent) and an anisotropic (hkl dependent) component. At higher stresses, austenite lattice plane reflections exhibited nonlinear and dissimilar elastic responses which may be attributed to the transformation. The texture evolution is significant in both austenite and martensite phases during the transformation and two approaches were used to describe this evolving texture, i.e., an ellipsoidal model due to March - Dollase and a generalized spherical-harmonic approach. The respective predictions of the phase fraction evolution as a function of applied stress were compared. A methodology is thus established to quantify the discrete phase strains, phase volume fractions, and texture during such transformations. copyright 1999 American Institute of Physics

Determination of Coherency and Rigidity Temperatures in Al-Cu Alloys Using In Situ Neutron Diffraction During Casting

Science.gov (United States)

Drezet, Jean-Marie; Mireux, Bastien; Szaraz, Zoltan; Pirling, Thilo

2014-08-01

The rigidity temperature of a solidifying alloy is the temperature at which the solid phase is sufficiently coalesced to transmit tensile stress. It is a major input parameter in numerical modeling of solidification processes as it defines the point at which thermally induced deformations start to generate internal stresses in a casting. This temperature has been determined for an Al-13 wt.% Cu alloy using in situ neutron diffraction during casting in a dog-bone-shaped mold. This setup allows the sample to build up internal stress naturally as its contraction is not possible. The cooling on both sides of the mold induces a hot spot at the middle of the sample that is irradiated by neutrons. Diffraction patterns are recorded every 11 s using a large detector, and the very first change of diffraction angles allows for the determination of the rigidity temperature. We measured rigidity temperatures equal to 557°C and 548°C depending on the cooling rate for grain refined Al-13 wt.% Cu alloys. At a high cooling rate, rigidity is reached during the formation of the eutectic phase. In this case, the solid phase is not sufficiently coalesced to sustain tensile load and thus cannot avoid hot tear formation.

FEM Analysis and Measurement of Residual Stress by Neutron Diffraction on the Dissimilar Overlay Weld Pipe

International Nuclear Information System (INIS)

Kim, Kang Soo; Lee, Ho Jin; Woo, Wan Chuck; Seong, Baek Seok; Byeon, Jin Gwi; Park, Kwang Soo; Jung, In Chul

2010-01-01

Much research has been done to estimate the residual stress on a dissimilar metal weld. There are many methods to estimate the weld residual stress and FEM (Finite Element Method) is generally used due to the advantage of the parametric study. And the X-ray method and a Hole Drilling technique for an experimental method are also usually used. The aim of this paper is to develop the appropriate FEM model to estimate the residual stresses of the dissimilar overlay weld pipe. For this, firstly, the specimen of the dissimilar overlay weld pipe was manufactured. The SA 508 Gr3 nozzle, the SA 182 safe end and SA376 pipe were welded by the Alloy 182. And the overlay weld by the Alloy 52M was performed. The residual stress of this specimen was measured by using the Neutron Diffraction device in the HANARO (High-flux Advanced Neutron Application ReactOr) research reactor, KAERI (Korea Atomic Energy Research Institute). Secondly, FEM Model on the dissimilar overlay weld pipe was made and analyzed by the ABAQUS Code (ABAQUS, 2004). Thermal analysis and stress analysis were performed, and the residual stress was calculated. Thirdly, the results of the FEM analysis were compared with those of the experimental methods

Disorder and transport properties of In3SbTe2 - an X-ray, neutron and electron diffraction study

International Nuclear Information System (INIS)

Schroeder, Thorsten; Rosenthal, Tobias; Grott, Sebastian; Stiewe, Christian; Boor, Johannes de; Oeckler, Oliver

2013-01-01

Quenched metastable In 3 SbTe 2 was investigated by X-ray and neutron powder diffraction as well as by single-crystal X-ray diffraction. The average structure corresponds to the rocksalt type, the anion position being occupied by antimony and tellurium. Neutron data indicate no antisite disorder of indium and antimony. The compound is a high-temperature phase that can be quenched to yield a metastable compound at ambient temperature which, upon heating, decomposes at ca. 320 C into InSb and InTe. Diffuse scattering in reconstructed X-ray and selected area electron diffraction patterns indicates local distortions of the crystal structure due to static atom displacement along <100> from the average positions, caused by the different size of the anions, but no superstructure. The electrical conductivity of In 3 SbTe 2 is 3.2 x 10 4 S.cm -1 at 25 C, the temperature characteristics correspond to metallic behavior. Consequently, the thermal conductivity is also rather high. The decomposition into InSb and InTe reduces the electrical conductivity by a factor of 3 in heterogeneous microstructures. (Copyright copyright 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Structure and Thermal Expansion of YSZ and La2Zr2O7 Above 1500°C from Neutron Diffraction on Levitated Samples

International Nuclear Information System (INIS)

Ushakov, Sergey V.; Neuefeind, Joerg C.

2015-01-01

High-temperature time-of-flight neutron diffraction experiments were performed in this paper on cubic yttria-stabilized zirconia (YSZ, 10 mol% YO 1.5 ) and lanthanum zirconate (LZ) prepared by laser melting. Three spheroids of each composition were aerodynamically levitated and rotated in argon flow and heated with a CO 2 laser. Unit cell, positional and atomic displacement parameters were obtained by Rietveld analysis. Below ~1650°C the mean thermal expansion coefficient (TEC) for YSZ is higher than for LZ (13 ± 1 vs. 10.3 ± 0.6) × 10 -6 /K. From ~1650°C to the onset of melting of LZ at ~2250°C, TEC for YSZ and LZ are similar and within (7 ± 2) × 10 -6 /K. LZ retains the pyrochlore structure up to the melting temperature with Zr coordination becoming closer to perfectly octahedral. Congruently melting LZ is La deficient. The occurrence of thermal disordering of oxygen sublattice (Bredig transition) in defect fluorite structure was deduced from the rise in YSZ TEC to ~25 × 10 -6 /K at 2350°C–2550°C with oxygen displacement parameters (U iso ) reaching 0.1 Å 2 , similar to behavior observed in UO 2 . Acquisition of powder-like high-temperature neutron diffraction data from solid-levitated samples is feasible and possible improvements are outlined. Finally, this methodology should be applicable to a wide range of materials for high-temperature applications.

Selection method and characterization of neutron monochromator natural crystals

International Nuclear Information System (INIS)

Stasiulevicius, R.; Kastner, G.F.

2000-01-01

Thermal neutrons are important analytical tools for microscopic material probe. These neutrons can be selected by diffraction technique using monocrystal, usually artificial. A crystal selection process was implemented and the characteristics of natural specimens were studied by activation analysis-k 0 method. The representative 120 samples, of which 21 best types, were irradiated in IPR-R1 and measured with a neutron diffractometer at IEA-R1m Brazilian reactors. These results are useful for database build up and ease the choice of appropriate natural crystal, with some advantage options: highest intensity diffracted, enlarging the energy operational interval and optimal performance in special applications. (author)

Lattice-preferred orientations of late-Variscan granitoids derived from neutron diffraction data: implications for magma emplacement mechanisms

Czech Academy of Sciences Publication Activity Database

Müller, A.; Leiss, B.; Ullemeyer, K.; Breiter, Karel

2011-01-01

Roč. 100, č. 7 (2011), s. 1515-1532 ISSN 1437-3254 Institutional research plan: CEZ:AV0Z30130516 Keywords : neutron diffraction * lattice-preferred orientation * shape-preferred orientation * magma tic flow * Podlesí granite * Meissen massif Subject RIV: DB - Geology ; Mineralogy Impact factor: 2.342, year: 2011

Neutron diffraction study of the stress distribution in steel matrix around active NiTi inserts

Czech Academy of Sciences Publication Activity Database

Davydov, Vadim; Lukáš, Petr; Vrána, Miroslav; Malard, B.; Pilch, Jan; Maximov, V.; Šittner, Petr

2010-01-01

Roč. 527, č. 15 (2010), s. 3310-3316 ISSN 0921-5093 R&D Projects: GA ČR GAP107/10/0824; GA AV ČR(CZ) IAA200100627 Institutional research plan: CEZ:AV0Z10480505; CEZ:AV0Z10100520 Keywords : In-situ neutron diffraction * Shape memory alloys * Residual stresses Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 2.090, year: 2010

Residual Stress Measurement of Coarse Crystal Grain in Aluminium Casting Alloy by Neutron Diffraction

International Nuclear Information System (INIS)

Nishida, Masayuki; Watanabe, Yoshitaka; Hanabusa, Takao

2009-01-01

Full text: Neutron stress measurement can detect strain and stress information in deep region because of large penetration ability of neutron beams. The present paper describes procedure and results in the residual stress measurement of aluminium casting alloy by neutron diffraction. Usually, the aluminium casting alloy includes the large crystal grains. The existence of large crystal grains makes it difficult to estimate the residual stresses in highly accuracy. In this study, the modified three axial method using Hook's equation was employed for neutron stress measurement. These stress measurements were performed under the two kinds of new techniques. One is a rocking curve method to calculate the principal strains in three directions. The peak profiles which appear discretely on rocking curves were translated to principle stresses by the Bragg law and the basic elastic theory. Another is the consideration of measurement positions and the edge effect in the neutron irradiated area (volume gage). The edge effect generates the errors of 2θ-peak position in the neutron stress measurement. In this study, the edge effect was investigated in detail by a small bit of copper single crystal. The copper bit was moved and scanned on three dimensionally within the gage volume. Furthermore, the average strains of symmetrical positions are measure by the sample turning at 180 degrees, because the error distributions of the 2θ-peak position followed to positions inside the gage volume. Form these results of this study, the residual stresses in aluminium casting alloy which includes the large crystal grains were possible to estimate by neutron stress measurement with the rocking curve method and the correction of the edge effect. (author)

Comparison of neutron and synchrotron diffraction measurements of residual stress in bead-on-plate weldments

International Nuclear Information System (INIS)

Paradowska, A.M.; Price, J.W.; Finlayson, T.R.; Lienert, U.; Ibrahim, R.

2010-01-01

This paper explores the use of neutron and synchrotron diffractions for the evaluation of residual stresses in welded components. It has been shown that it is possible to achieve very good agreement between the two independent diffraction techniques. This study shows the significance of the weld start and end sites on the residual strain/stress distribution. Quantitative evaluation of the residual stress development process for multibead weldments has been presented. Some measurements were also taken before and after postweld stress relieving to establish the reduction and redistribution of the residual stress. The detailed measurements of residual stress around the weld achieved in this work significantly improve the knowledge and understanding of residual stress in welded components.

Compact neutron generator development and applications

International Nuclear Information System (INIS)

Leung, Ka-Ngo; Reijonen, Jani; Gicquel, Frederic; Hahto, Sami; Lou, Tak-Pui

2004-01-01

The Plasma and Ion Source Technology Group at the Lawrence Berkeley National Laboratory has been engaging in the development of high yield compact neutron generators for the last ten years. Because neutrons in these generators are formed by using either D-D, T-T or D-T fusion reaction, one can produce either mono-energetic (2.4 MeV or 14 MeV) or white neutrons. All the neutron generators being developed by our group utilize 13.5 MHz RF induction discharge to produce a pure deuterium or a mixture of deuterium-tritium plasma. As a result, ion beams with high current density and almost pure atomic ions can be extracted from the plasma source. The ion beams are accelerated to ∼100 keV and neutrons are produced when the beams impinge on a titanium target. Neutron generators with different configurations and sizes have been designed and tested at LBNL. Their applications include neutron activation analysis, oil-well logging, boron neutron capture therapy, brachytherapy, cargo and luggage screening. A novel small point neutron source has recently been developed for radiography application. The source size can be 2 mm or less, making it possible to examine objects with sharper images. The performance of these neutron generators will be described in this paper

Neutron diffraction studies of amphipathic helices in phospholipid bilayers

Energy Technology Data Exchange (ETDEWEB)

Bradshaw, J.P.; Gilchrist, P.J. [Univ. of Edinburgh (United Kingdom); Duff, K.C. [Univ. of Edinburgh Medical School (United Kingdom); Saxena, A.M. [Brookhaven National Laboratory, Upton, NY (United States)

1994-12-31

The structural feature which is thought to facilitate the interaction of many peptides with phospholipid bilayers is the ability to fold into an amphipathic helix. In most cases the exact location and orientation of this helix with respect to the membrane is not known, and may vary with factors such as pH and phospholipid content of the bilayer. The growing interest in this area is stimulated by indications that similar interactions can contribute to the binding of certain hormones to their cell-surface receptors. We have been using the techniques of neutron diffraction from stacked phospholipid bilayers in an attempt to investigate this phenomenon with a number of membrane-active peptides. Here we report some of our findings with three of these: the bee venom melittin; the hormone calcitonin; and a synthetic peptide representing the ion channel fragment of influenza A M2 protein.

Neutron diffraction studies of amphipathic helices in phospholipid bilayers

International Nuclear Information System (INIS)

Bradshaw, J.P.; Gilchrist, P.J.; Duff, K.C.; Saxena, A.M.

1994-01-01

The structural feature which is thought to facilitate the interaction of many peptides with phospholipid bilayers is the ability to fold into an amphipathic helix. In most cases the exact location and orientation of this helix with respect to the membrane is not known, and may vary with factors such as pH and phospholipid content of the bilayer. The growing interest in this area is stimulated by indications that similar interactions can contribute to the binding of certain hormones to their cell-surface receptors. We have been using the techniques of neutron diffraction from stacked phospholipid bilayers in an attempt to investigate this phenomenon with a number of membrane-active peptides. Here we report some of our findings with three of these: the bee venom melittin; the hormone calcitonin; and a synthetic peptide representing the ion channel fragment of influenza A M2 protein

Discussion on accuracy of weld residual stress measurement by neutron diffraction. Influence of strain free reference

International Nuclear Information System (INIS)

Suzuki, Hiroshi; Akita, Koichi

2012-01-01

It is required to evaluate a strain-free reference, α 0 , to perform accurate stress measurement using neutron diffraction. In this study, accuracy of neutron stress measurement was quantitatively discussed from α 0 evaluations on a dissimilar metal butt-weld between a type 304 austenitic stainless steel and an A533B low alloy ferritic steel. A strain-free standard specimen and a sliced specimen with 10 mm thickness taken from the dissimilar metal butt-weld were utilized. In the lattice constant evaluation using the standard specimen, average lattice constant derived from multiple hkl reflections was evaluated as the stress-free reference with cancelling out an intergranular strain. Comparing lattice constant distributions in each reflection with average lattice constant distribution in the standard specimen, αFe211 and γFe311 reflections were judged as a suitable reflection for neutron strain measurement to reduce intergranular strain effects. Residual stress distribution in the sliced specimen evaluated using α 0 measured here exhibited higher accuracy than that measured using strain gauges. On the other hand, α 0 distributions were evaluated using the sliced specimen under the plane-stress condition. Existence of slight longitudinal residual stresses near the weld center decreased accuracy of the α 0 evaluations, which means that it is required to optimize the thickness of the sliced specimen for accurate α 0 evaluation under plane strain condition. As a conclusion of this study, it was confirmed that procedures of accurate α 0 evaluation, optimization of the measurement condition, and multiple evaluations on the results play an important role to improve accuracy of the residual stress measurement using neutron diffraction. (author)

Extra spots in the electron diffraction patterns of neutron irradiated zirconium and its alloys

International Nuclear Information System (INIS)

Madden, P.K.

1977-01-01

Specimens of neutron irradiated zirconium and its alloys were examined in the transmission electron microscope. Groups of extra spots, often exhibiting four-fold symmetry, were observed in thin foil electron diffraction patterns of these specimens. The 'extra-spot' structure, like the expected black-dot/small scale dislocation loop neutron irradiated damage, is approximately 100 A in size. Its nature is uncertain. It may be related to irradiation damage or to some artefact introduced during specimen preparation. If it is the latter, then published irradiation damage defect size distributions and determined irradiation growth strains of other investigators, may require modification. The present inconclusive results indicate that extra-spot structure is likely to consist of oxide particles, but may correspond to hydride precipitation or decoration effects, or even, to electron beam effects. (author)

Measurement of residual strain in composites by means of time-of- flight neutron diffraction

International Nuclear Information System (INIS)

Kupperman, D.S.; Majumdar, S.; Richardson, J.; Saigal, A.

1993-01-01

Neutron diffraction time-of-flight measurements using the Intense Pulsed Neutron Source at Argonne National Laboratory have been employed to study strain in various metal- and ceramic-matrix composites. For example, measurements carried out to 900 C on a composite composed of a titanium alloy matrix and silicon carbide fibers have been used to validate theoretical assumptions in the prediction of fabrication-induced residual stress. Sapphire reinforced nickel aluminide composites have also been studied. Studies of a high-temperature ceramic superconducting composite consisting of yttrium barium copper oxide and silver with various volume fractions of silver have also been carried out. The results of these studies have provided information on the effect of Ag content on interface bonding. In addition, ceramic-matrix composites with randomly dispersed ceramic whiskers with varying fiber content have been investigated

Neutron- and X-ray diffraction investigations for the metallic glasses Ni81B19 and Co80P20

International Nuclear Information System (INIS)

Sperl, W.

1982-01-01

By means of isotope substitution for three chemically and technically identical amorphous Ni 81 B 19 samples neutron diffraction experiments are performed and the partial structure factors and the partial pair correlation functions are determined. (BHO)

High-level expression and deuteration of sperm whale myoglobin: A study of its solvent structure by X-ray and neutron diffraction methods

Energy Technology Data Exchange (ETDEWEB)

Shu, F. [State Univ. of New York, Stony Brook, NY (United States); Ramakrishnan, V. [Brookhaven National Laboratory, Upton, NY (United States); Schoenborn, B.P. [Los Alamos National Laboratory, NM (United States)

1994-12-31

Neutron diffraction has become one of the best ways to study light atoms, such as hydrogens. Hydrogen however has a negative coherent scattering factor, and a large incoherent scattering factor, while deuterium has virtually no incoherent scattering, but a large positive coherent scattering factor. Beside causing high background due to its incoherent scattering, the negative coherent scattering of hydrogen tends to cancel out the positive contribution from other atoms in a neutron density map. Therefore a fully deuterated sample will yield better diffraction data with stronger density in the hydrogen position. On this basis, a sperm whale myoglobin gene modified to include part of the A cII protein gene has been cloned into the T7 expression system. Milligram amounts of fully deuterated holo-myoglobin have been obtained and used for crystallization. The synthetic sperm whale myoglobin crystallized in P2{sub 1} space group isomorphous with the native protein crystal. A complete X-ray diffraction dataset at 1.5{Angstrom} has been collected. This X-ray dataset, and a neutron data set collected previously on a protonated carbon-monoxymyoglobin crystal have been used for solvent structure studies. Both X-ray and neutron data have shown that there are ordered hydration layers around the protein surface. Solvent shell analysis on the neutron data further has shown that the first hydration layer behaves differently around polar and apolar regions of the protein surface. Finally, the structure of per-deuterated myoglobin has been refined using all reflections to a R factor of 17%.

High-level expression and deuteration of sperm whale myoglobin: A study of its solvent structure by X-ray and neutron diffraction methods

International Nuclear Information System (INIS)

Shu, F.; Ramakrishnan, V.; Schoenborn, B.P.

1994-01-01

Neutron diffraction has become one of the best ways to study light atoms, such as hydrogens. Hydrogen however has a negative coherent scattering factor, and a large incoherent scattering factor, while deuterium has virtually no incoherent scattering, but a large positive coherent scattering factor. Beside causing high background due to its incoherent scattering, the negative coherent scattering of hydrogen tends to cancel out the positive contribution from other atoms in a neutron density map. Therefore a fully deuterated sample will yield better diffraction data with stronger density in the hydrogen position. On this basis, a sperm whale myoglobin gene modified to include part of the A cII protein gene has been cloned into the T7 expression system. Milligram amounts of fully deuterated holo-myoglobin have been obtained and used for crystallization. The synthetic sperm whale myoglobin crystallized in P2 1 space group isomorphous with the native protein crystal. A complete X-ray diffraction dataset at 1.5 Angstrom has been collected. This X-ray dataset, and a neutron data set collected previously on a protonated carbon-monoxymyoglobin crystal have been used for solvent structure studies. Both X-ray and neutron data have shown that there are ordered hydration layers around the protein surface. Solvent shell analysis on the neutron data further has shown that the first hydration layer behaves differently around polar and apolar regions of the protein surface. Finally, the structure of per-deuterated myoglobin has been refined using all reflections to a R factor of 17%

Non-invasive neutron diffraction analysis of marbles from the 'Edificio con Tre Esedre' in Villa Adriana

International Nuclear Information System (INIS)

Filabozzi, A.; Andreani, C.; Pietropaolo, A.; De Pascale, M.P.; Gorini, G.; Kockelmann, W.; Chapon, L.C.

2006-01-01

Roman marble fragments from the Villa Adriana at Tivoli (Rome) have been characterised by neutron diffraction. This study aimed at distinguishing between different marble types on the basis of the mineral phase compositions and the crystallographic textures. It is demonstrated that on a multi-detector time-offlight neutron diffractometer a quantitative bulk texture analysis can be performed on a stationary marble sample in a matter of minutes. This potentially allows investigating large sample series or bulky, intact marble objects in a completely nondestructive manner. The texture information, along with other structure details, can be used as characterising feature to address questions of attribution and restoration of archaeological marble objects

Refinement of the ferri and paramagnetic phases of magnetite measured by neutron multiple diffraction

International Nuclear Information System (INIS)

Mazzochi, V.L.; Parente, C.B.R.

1989-10-01

Structural parameters of the ferri and paramagnetic phases of magnetite have been refined from neutron multiple diffraction data. Experimental patterns were obtained by measuring the III primary reflection of a natural single crystal of this compound, at room temperature for the ferrimagnetic phase and 703 0 C for the paramagnetic phase. Theoretical multiple diffraction patterns for both phases have been calculated by the program MULTI which uses the iterative method. In this method intensities are caluclated as Taylor series expansions summed up to a order sufficient for a good approximation. A step by step process has been used in the refinements similarly to the parameter-shift method. Final values for the discrepancy factor found for the ferri and paramagnetic phases were R = 3.96% and R = 3.46%, respectively. (author) [pt

Analytical applications for delayed neutrons

International Nuclear Information System (INIS)

Eccleston, G.W.

1983-01-01

Analytical formulations that describe the time dependence of neutron populations in nuclear materials contain delayed-neutron dependent terms. These terms are important because the delayed neutrons, even though their yields in fission are small, permit control of the fission chain reaction process. Analytical applications that use delayed neutrons range from simple problems that can be solved with the point reactor kinetics equations to complex problems that can only be solved with large codes that couple fluid calculations with the neutron dynamics. Reactor safety codes, such as SIMMER, model transients of the entire reactor core using coupled space-time neutronics and comprehensive thermal-fluid dynamics. Nondestructive delayed-neutron assay instruments are designed and modeled using a three-dimensional continuous-energy Monte Carlo code. Calculations on high-burnup spent fuels and other materials that contain a mix of uranium and plutonium isotopes require accurate and complete information on the delayed-neutron periods, yields, and energy spectra. A continuing need exists for delayed-neutron parameters for all the fissioning isotopes

Residual stresses in a composite steel tube measured by neutron diffraction

International Nuclear Information System (INIS)

Taran, Yu.V.; Balagurov, A.M.; Zlokazov, V.B.; Schreiber, J.; Stuhr, U.; Kockelmann, H.

2006-01-01

The triaxial residual stresses in a composite tube from an austenitic stainless steel with a welded ferritic steel cladding were measured by the time-of-flight neutron diffraction method on the POLDI instrument at the PSI SINQ facility. The POLDI results are compared to the results obtained by the destructive turning out method and theoretical predictions of calculations by the finite element method. Only for the tangential component of the stress tensor the semiquantitative agreement of all used methods was observed. There is a clear discrepancy between the results of the different methods in the axial component. For the radial component all methods reveal quite small stresses, however, with some distinct differences in their distributions

New generation non-stationary portable neutron generators for biophysical applications of Neutron Activation Analysis.

Science.gov (United States)

Marchese, N; Cannuli, A; Caccamo, M T; Pace, C

2017-01-01

Neutron sources are increasingly employed in a wide range of research fields. For some specific purposes an alternative to existing large-scale neutron scattering facilities, can be offered by the new generation of portable neutron devices. This review reports an overview for such recently available neutron generators mainly addressed to biophysics applications with specific reference to portable non-stationary neutron generators applied in Neutron Activation Analysis (NAA). The review reports a description of a typical portable neutron generator set-up addressed to biophysics applications. New generation portable neutron devices, for some specific applications, can constitute an alternative to existing large-scale neutron scattering facilities. Deuterium-Deuterium pulsed neutron sources able to generate 2.5MeV neutrons, with a neutron yield of 1.0×10 6 n/s, a pulse rate of 250Hz to 20kHz and a duty factor varying from 5% to 100%, when combined with solid-state photon detectors, show that this kind of compact devices allow rapid and user-friendly elemental analysis. "This article is part of a Special Issue entitled "Science for Life" Guest Editor: Dr. Austen Angell, Dr. Salvatore Magazù and Dr. Federica Migliardo". Copyright © 2016 Elsevier B.V. All rights reserved.

Magnetic properties of the ternary carbide DyCoC2 studied by magnetization measurements, neutron diffraction and 161Dy Moessbauer spectroscopy

International Nuclear Information System (INIS)

Amanai, H.; Onodera, H.; Ohashi, M.; Matsuo, S.; Yamauchi, H.

1995-01-01

The magnetic properties of DyCoC 2 have been investigated by means of magnetization measurements, powder neutron diffraction and 161 Dy Moessbauer spectroscopy. The magnetization versus temperature curves of a single-crystalline sample reveal that the magnetic structure of DyCoC 2 is a simple collinear ferromagnetic one below T C =10.0 K. At 4.2 K, the magnitude of the Dy moment is 8.7(1)μ B , whose direction is defined by an angle of 38.0(5) from the a-axis toward the c-axis. The magnetic structure and the magnitude of the moment are also confirmed by the results of powder neutron diffraction experiments and 161 Dy Moessbauer spectroscopy, respectively. ((orig.))

Eighth International Conference on Neutron Scattering ICNS2005. Final Programme and Abstract Book

International Nuclear Information System (INIS)

2005-01-01

Full text: This conference encompassed a very wide range of neutron-related research. Topics addressed ranged from almost all applications of neutron scattering and diffraction like discovering magnetic ordering, magnetic properties and structural analysis, negative thermal expansion, spin states, proton dynamics, crystal structure, phase transitions and phase morphology, neutron spin echo to neutron powder diffraction studies and new generation neutron analysis methods as well as x-ray reflectivity versus neutron reflectivity, neutron resonance, cold and thermal neutron studies and spectrometers. Areas of research covered bacteria, DNA, drugs targeting, enzyme arrangement, structure of cholesterol, lung surfactant action, nanocapsules, disease, muscles, lipids, liquids, crystals, industrial gauges, metals, rare earths, shielding and geopolymers. Not all abstracts are included in this input; there exists an emphasis on Australian contributions and those from ANSTO

Development of neutron science and technology

International Nuclear Information System (INIS)

Lee, Ki Hong; Seong, Baik Seok; Lee, Jeong Soo

2012-04-01

Using various neutron scattering, imaging, and activation analysis instruments and irradiation facility and capsules, the short-term industrial application and mid and long-term basic science with neutrons was carried out. In this regard, we proposed the utilization of the neutron scattering and diffraction techniques to the study of physical, mechanical material properties in industrial components. The nano magnetic thin film structure study using neutron reflectometry, spin structure and dynamics study using neutron scattering, hydrogen combination structure study using single crystal diffraction were carried out. The triple-axis spectrometer has been installed. Also, a new growth facility of single crystal has been developed to supply crystals for the neutron scattering experiment. We have contributed to the performance enhancement of hydrogen fuel cell by the development of quantitative neutron radiography technology and developed the differential phase imaging technology using silicon grating. To perform precise neutron activation analysis, a Compton suppressed gamma-ray spectroscopy system was installed. Through the analysis of actual samples as well as geological and biological reference materials, performance test was carried out. We built up analytical data base and develope integrated analytical program for INAA/PGAA. The analysis and evaluation technology of the irradiation capsule test in HANARO for the commercial and future nuclear reactor systems was improved

Neutrons and Nuclear Engineering

International Nuclear Information System (INIS)

Ekkebus, Allen E.

2007-01-01

Oak Ridge National Laboratory hosted two workshops in April 2007 relevant to nuclear engineering education. In the Neutron Stress, Texture, and Phase Transformation for Industry workshop (http://neutrons.ornl.gov/workshops/nst2/), several invited speakers gave examples of neutron stress mapping for nuclear engineering applications. These included John Root of National Research Council of Canada, Mike Fitzpatrick of the UK's Open University, and Yan Gao of GE Global Research on their experiences with industrial and academic uses of neutron diffraction. Xun-Li Wang and Camden Hubbard described the new instruments at ORNL that can be used for such studies. This was preceded by the Neutrons for Materials Science and Engineering educational symposium (http://neutrons.ornl.gov/workshops/edsym2007). It was directed to the broad materials science and engineering community based in universities, industry and laboratories who wish to learn what the neutron sources in the US can provide for enhancing the understanding of materials behavior, processing and joining. Of particular interest was the presentation of Donald Brown of Los Alamos about using 'Neutron diffraction measurements of strain and texture to study mechanical behavior of structural materials.' At both workshops, the ORNL neutron scattering instruments relevant to nuclear engineering studies were described. The Neutron Residual Stress Mapping Facility (NRSF2) is currently in operation at the High Flux Isotope Reactor; the VULCAN Engineering Materials Diffractometer will begin commissioning in 2008 at the Spallation Neutron Source. For characteristics of these instruments, as well as details of other workshops, meetings, capabilities, and research proposal submissions, please visit http://neutrons.ornl.gov. To submit user proposals for time on NRSF2 contact Hubbard at hubbardcratornl.gov

Neutrons and synchrotron radiation in engineering materials science. From fundamentals to applications. 2. ed.

Energy Technology Data Exchange (ETDEWEB)

Staron, Peter [Helmholtz-Zentrum Geesthacht, Zentrum fuer Material- und Kuestenforschung GmbH, Geesthacht (Germany). Inst. of Materials Research; Schreyer, Andreas [European Spallation Source ERIC, Lund (Sweden); Clemens, Helmut; Mayer, Svea (eds.) [Montanuniv. Leoben (Austria). Dept. of Physical Metallurgy and Materials Testing

2017-07-01

This book provides a systematic overview of the increasingly important field of characterization of engineering materials with the help of neutrons and synchrotron radiation. The first part introduces readers to the fundamentals of structure-property relationships in materials and the radiation sources suitable for materials characterization. The second part then focuses on such characterization techniques as diffraction and scattering methods, as well as direct imaging and tomography. The third part presents new and emerging methods of materials characterization in the field of 3D characterization techniques like three-dimensional X-ray diffraction microscopy. The fourth and final part is a collection of examples that demonstrate the application of the methods introduced in the first parts to problems in materials science.

On the atomic structure of liquid Ni-Si alloys: a neutron diffraction study

Science.gov (United States)

Gruner, S.; Marczinke, J.; Hennet, L.; Hoyer, W.; Cuello, G. J.

2009-09-01

The atomic structure of the liquid NiSi and NiSi2 alloys is investigated by means of neutron diffraction experiments with isotopic substitution. From experimental data-sets obtained using four Ni isotopes, partial structure factors and pair correlation functions are obtained by applying a reverse Monte Carlo modelling approach. Both alloys were found to exhibit a strong tendency to hetero-coordination within the first coordination shell. In particular, covalent Si-Si bonds with somewhat greater distances seem to influence the structure of the liquid NiSi alloy.

On the atomic structure of liquid Ni-Si alloys: a neutron diffraction study

Energy Technology Data Exchange (ETDEWEB)

Gruner, S; Marczinke, J; Hoyer, W [Institute of Physics, Chemnitz University of Technology, D-09107 Chemnitz (Germany); Hennet, L [CNRS-CEMHTI, University of Orleans, F-45071 Orleans (France); Cuello, G J, E-mail: sascha.gruner@physik.tu-chemnitz.d [Institute Laue-Langevin, PO Box 156, F-38042 Grenoble (France)

2009-09-23

The atomic structure of the liquid NiSi and NiSi{sub 2} alloys is investigated by means of neutron diffraction experiments with isotopic substitution. From experimental data-sets obtained using four Ni isotopes, partial structure factors and pair correlation functions are obtained by applying a reverse Monte Carlo modelling approach. Both alloys were found to exhibit a strong tendency to hetero-coordination within the first coordination shell. In particular, covalent Si-Si bonds with somewhat greater distances seem to influence the structure of the liquid NiSi alloy.

Neutron diffraction instruments at the BR2 reactor and their use in the study of crystal and magnetic structures

International Nuclear Information System (INIS)

Legrand, E.

1977-01-01

The study of structural properties of condensed matted is frequently performed by means of methods based on X-ray, electron or neutron scattering. In many particular cases, the latter technique offers definite advantages which are mainly based on the following characteristics of neutron-matter interaction: The large penetration depth for neutrons in matter (with the exception of a few elements), which allow the study of large samples and the use of wavelengths from 0.5 to 5A, and even to 10 A; the absence of an atomic form factor; the irregular dependence of the scattering length for the different elements as a function of their atomic number; the large cross section for magnetic scattering; the energy of thermal neutrons which allows the direct measuremtment of the enrgy exchange between the neutrons and the scatterer. Three of the four neutron diffraction instruments for solid state research, installed at the BR2 reactor, are described in detail. (author)

In-situ neutron diffraction study of magnetic field induced reorientation in Ni-Mn-Ga under constant stress

Czech Academy of Sciences Publication Activity Database

Molnár, Peter; Šittner, Petr; Novák, Václav; Prokleška, J.; Sechovsky, V.; Ouladdiaf, B.; Hanulla, S.P.; Heczko, O.

2008-01-01

Roč. 20, č. 10 (2008), 104224/1-104224/7 ISSN 0953-8984 R&D Projects: GA AV ČR(CZ) IAA200100627 Institutional research plan: CEZ:AV0Z10100520 Keywords : shape memory alloys * NiMnGa * neutron diffraction Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.900, year: 2008

New neutron imaging techniques to close the gap to scattering applications

International Nuclear Information System (INIS)

Lehmann, Eberhard H.; Peetermans, S.; Trtik, P.; Betz, B.; Grünzweig, C.

2017-01-01

Neutron scattering and neutron imaging are activities at the strong neutron sources which have been developed rather independently. However, there are similarities and overlaps in the research topics to which both methods can contribute and thus useful synergies can be found. In particular, the spatial resolution of neutron imaging has improved recently, which - together with the enhancement of the efficiency in data acquisition- can be exploited to narrow the energy band and to implement more sophisticated methods like neutron grating interferometry. This paper provides a report about the current options in neutron imaging and describes how the gap to neutron scattering data can be closed in the future, e.g. by diffractive imaging, the use of polarized neutrons and the dark-field imagining of relevant materials. This overview is focused onto the interaction between neutron imaging and neutron scattering with the aim of synergy. It reflects mainly the authors’ experiences at their PSI facilities without ignoring the activities at the different other labs world-wide. (paper)

New neutron imaging techniques to close the gap to scattering applications

Science.gov (United States)

Lehmann, Eberhard H.; Peetermans, S.; Trtik, P.; Betz, B.; Grünzweig, C.

2017-01-01

Neutron scattering and neutron imaging are activities at the strong neutron sources which have been developed rather independently. However, there are similarities and overlaps in the research topics to which both methods can contribute and thus useful synergies can be found. In particular, the spatial resolution of neutron imaging has improved recently, which - together with the enhancement of the efficiency in data acquisition- can be exploited to narrow the energy band and to implement more sophisticated methods like neutron grating interferometry. This paper provides a report about the current options in neutron imaging and describes how the gap to neutron scattering data can be closed in the future, e.g. by diffractive imaging, the use of polarized neutrons and the dark-field imagining of relevant materials. This overview is focused onto the interaction between neutron imaging and neutron scattering with the aim of synergy. It reflects mainly the authors’ experiences at their PSI facilities without ignoring the activities at the different other labs world-wide.

In Situ Study of Microstructure Evolution in Solidification of Hypereutectic Al-Si Alloys with Application of Thermal Analysis and Neutron Diffraction

Science.gov (United States)

Sediako, Dimitry G.; Kasprzak, Wojciech

2015-09-01

Understanding of the kinetics of solid-phase evolution in solidification of hypereutectic aluminum alloys is a key to control their as-cast microstructure and resultant mechanical properties, and in turn, to enhance the service characteristics of actual components. This study was performed to evaluate the solidification kinetics for three P-modified hypereutectic Al-19 pct Si alloys: namely, Al-Si binary alloy and with the subsequent addition of 2.8 pct Cu and 2.8 pct Cu + 0.7 pct Mg. Metallurgical evaluation included thermodynamic calculations of the solidification process using the FactSage™ 6.2 software package, as well as experimental thermal analysis, and in situ neutron diffraction. The study revealed kinetics of solid α-Al, solid Si, Al2Cu, and Mg2Si evolution, as well as the individual effects of Cu and Mg alloying additions on the solidification path of the Al-Si system. Various techniques applied in this study resulted in some discrepancies in the results. For example, the FactSage computations, in general, resulted in 281 K to 286 K (8 °C to 13 °C) higher Al-Si eutectic temperatures than the ones recorded in the thermal analysis, which are also ~278 K (~5 °C) higher than those observed in the in situ neutron diffraction. None of the techniques can provide a definite value for the solidus temperature, as this is affected by the chosen calculation path [283 K to 303 K (10 °C to 30 °C) higher for equilibrium solidification vs non-equilibrium] for the FactSage analysis; and further complicated by evolution of secondary Al-Cu and Mg-Si phases that commenced at the end of solidification. An explanation of the discrepancies observed and complications associated with every technique applied is offered in the paper.

X-ray and neutron diffraction and molecular dynamics simulation of molten lithium and rubidium nitrates

International Nuclear Information System (INIS)

Yamaguchi, Toshio; Okada, Isao; Ohtaki, Hitoshi; Mikami, Masuhiro; Kawamura, Kazutaka

1986-01-01

Molecular dynamics simulations have been performed for lithium and rubidium nitrate melts at 550 and 600K, respectively, together with X-ray and neutron diffraction experiments. Simple Coulomb pair potentials with Born-type repulsions have been adopted in the simulations with a rigid body model for the nitrate ion. Structure functions derived from the X-ray and neutron experiments are well reproduced by the simulations, from which the three-dimensional cation distribution around the nitrate ion has been revealed. The self-diffusion coefficients, the velocity autocorrelation functions and the self-exchange velocities of lithium, rubidium and nitrate ions have been calculated. Anisotropic motion of nitrate ions has been found and is discussed on the basis of the structure of the melts. (author)

Dynamically polarized samples for neutron protein crystallography at the Spallation Neutron Source

International Nuclear Information System (INIS)

Zhao, Jinkui; Pierce, Josh; Robertson, J. L.; Herwig, Kenneth W.; Myles, Dean; Cuneo, Matt; Li, Le; Meilleur, Flora; Standaert, Bob

2016-01-01

To prepare for the next generation neutron scattering instruments for the planned second target station at the Spallation Neutron Source (SNS) and to broaden the scientific impact of neutron protein crystallography at the Oak Ridge National Laboratory, we have recently ramped up our efforts to develop a dynamically polarized target for neutron protein crystallography at the SNS. Proteins contain a large amount of hydrogen which contributes to incoherent diffraction background and limits the sensitivity of neutron protein crystallography. This incoherent background can be suppressed by using polarized neutron diffraction, which in the same time also improves the coherent diffraction signal. Our plan is to develop a custom Dynamic Nuclear Polarization (DNP) setup tailored to neutron protein diffraction instruments. Protein crystals will be polarized at a magnetic field of 5 T and temperatures of below 1 K. After the dynamic polarization process, the sample will be brought to a frozen-spin mode in a 0.5 T holding field and at temperatures below 100 mK. In a parallel effort, we are also investigating various ways of incorporating polarization agents needed for DNP, such as site specific spin labels, into protein crystals. (paper)

Structure, magnetic properties, polarized neutron diffraction, and theoretical study of a copper(II) cubane.

Science.gov (United States)

Aronica, Christophe; Chumakov, Yurii; Jeanneau, Erwann; Luneau, Dominique; Neugebauer, Petr; Barra, Anne-Laure; Gillon, Béatrice; Goujon, Antoine; Cousson, Alain; Tercero, Javier; Ruiz, Eliseo

2008-01-01

The paper reports the synthesis, X-ray and neutron diffraction crystal structures, magnetic properties, high field-high frequency EPR (HF-EPR), spin density and theoretical description of the tetranuclear CuII complex [Cu4L4] with cubane-like structure (LH2=1,1,1-trifluoro-7-hydroxy-4-methyl-5-aza-hept-3-en-2-one). The simulation of the magnetic behavior gives a predominant ferromagnetic interaction J1 (+30.5 cm(-1)) and a weak antiferromagnetic interaction J2 (-5.5 cm(-1)), which correspond to short and long Cu-Cu distances, respectively, as evidence from the crystal structure [see formulate in text]. It is in agreement with DFT calculations and with the saturation magnetization value of an S=2 ground spin state. HF-EPR measurements at low temperatures (5 to 30 K) provide evidence for a negative axial zero-field splitting parameter D (-0.25+/-0.01 cm(-1)) plus a small rhombic term E (0.025+/-0.001 cm(-1), E/D = 0.1). The experimental spin distribution from polarized neutron diffraction is mainly located in the basal plane of the CuII ion with a distortion of yz-type for one CuII ion. Delocalization on the ligand (L) is observed but to a smaller extent than expected from DFT calculations.

Examples of neutron diffraction texture analysis on one and the same chalcopyrite sample before and after experimental deformation

International Nuclear Information System (INIS)

Jansen, E.M.; Brokmeier, H.G.; Siemes, H.

1994-01-01

Natural chalcopyrite specimens from Mt. Isa, Australia were investigated by neutron diffraction texture analysis. The preferred orientation of the specimens consists of 3 main orientation components. After axial shortening at a temperature of 25 C the initial orientation components became weaker, a new component was detected. (orig.)

On the determination of double diffraction dissociation cross section at HERA

International Nuclear Information System (INIS)

Holtmann, H.; Nikolaev, N.N.; Speth, J.; Zakharov, B.G.

1996-01-01

The excitation of the proton into undetected multiparticle states (double diffraction dissociation) is an important background to single diffractive deep-inelastic processes ep→e'p'ρ 0 , e'p'J/Ψ, e'p'X at HERA. We present estimates of the admixture of the double diffraction dissociation events in all diffractive events. We find that in the J/Ψ photoproduction, electroproduction of the ρ 0 at large Q 2 and diffraction dissociation of real and virtual photons into high mass states X the contamination of the double diffraction dissociation can be as large as ∼30%, thus affecting substantially the experimental tests of the pomeron exchange in deep inelastic scattering at HERA. We discuss a possibility of tagging the double diffraction dissociation by neutrons observed in the forward neutron calorimeter. We present evaluations of the spectra of neutrons and efficiency of neutron tagging based on the experimental data for diffractive processes in the proton-proton collisions. (orig.)

Application of neutron radiography in Japan

International Nuclear Information System (INIS)

Kobayashi, M.; Wada, N.; Sekita, J.; Sanno-cho, Ota-ku, Tokyo, Japan)

1983-01-01

The history and the present state of neutron radiography in Japan are reviewed. Three types of neutron sources, namely nuclear reactors, accelerators and radioisotopes are now used. The interests on the application on neutron radiography become greater and greater in the industries, such as atomic energy, aeronautics and space etc. (Auth.)

Time-of-flight pulsed neutron diffraction of molten salts

Energy Technology Data Exchange (ETDEWEB)

Fukushima, Y; Misawa, M; Suzuki, K [Tohoku Univ., Sendai (Japan). Research Inst. for Iron, Steel and Other Metals

1975-06-01

In this work, the pulsed neutron diffraction of molten alkali metal nitrate and bismuth trihalide was measured by the time-of-flight method. An electron linear accelerator was used as the pulsed neutron source. All the measurements were carried out with the T-O-F neutron diffractometer installed on the 300 MeV electron lineac. Molten NaNO/sub 3/ and RbNO/sub 3/ were adopted as the samples for alkali metal nitrate. The measurement is in progress for KNO/sub 3/ and LiNO/sub 3/. As the first step of the study on bismuth-bismuth trihalide system, the temperature dependence of structure factors was observed for BiCl/sub 3/, BiBr/sub 3/ and BiI/sub 3/ in the liquid state. The structure factors Sm(Q) for molten NaNO/sub 3/ at 340/sup 0/C and RbNO/sub 3/ at 350/sup 0/C were obtained, and the form factor F/sub 1/(Q) for single NO/sub 3//sup -/ radical with equilateral triangle structure was calculated. In case of molten NaNO/sub 3/, the first peak of Sm(Q) is simply smooth and a small hump can be observed in the neighbourhood of the first minimum Q position. The first peak of Sm(Q) for molten RbNO/sub 3/ is divided into two peaks, whereas a hump at the first minimum becomes big, and shifts to the low Q side of the second peak. The size of the NO/sub 3//sup -/ radical in molten NaNO/sub 3/ is a little smaller than that in molten RbNO/sub 3/. The values of the bond length in the NO/sub 3//sup -/ radical are summarized for crystal state and liquid state. The temperature dependence of the structure factor S(Q) was observed for BiCl/sub 3/, BiBr/sub 3/ and BiI/sub 3/, and shown in a figure.

Hemoglobin redux: combining neutron and X-ray diffraction with mass spectrometry to analyse the quaternary state of oxidized hemoglobins

Energy Technology Data Exchange (ETDEWEB)

Mueser, Timothy C., E-mail: timothy.mueser@utoledo.edu; Griffith, Wendell P. [Department of Chemistry, University of Toledo, Toledo, OH 43606 (United States); Kovalevsky, Andrey Y. [Bioscience Division, MS M888, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Guo, Jingshu; Seaver, Sean [Department of Chemistry, University of Toledo, Toledo, OH 43606 (United States); Langan, Paul [Department of Chemistry, University of Toledo, Toledo, OH 43606 (United States); Bioscience Division, MS M888, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Hanson, B. Leif [Department of Chemistry, University of Toledo, Toledo, OH 43606 (United States)

2010-11-01

X-ray and neutron diffraction studies of cyanomethemoglobin are being used to evaluate the structural waters within the dimer–dimer interface involved in quaternary-state transitions. Improvements in neutron diffraction instrumentation are affording the opportunity to re-examine the structures of vertebrate hemoglobins and to interrogate proton and solvent position changes between the different quaternary states of the protein. For hemoglobins of unknown primary sequence, structural studies of cyanomethemoglobin (CNmetHb) are being used to help to resolve sequence ambiguity in the mass spectra. These studies have also provided additional structural evidence for the involvement of oxidized hemoglobin in the process of erythrocyte senescence. X-ray crystal studies of Tibetan snow leopard CNmetHb have shown that this protein crystallizes in the B state, a structure with a more open dyad, which possibly has relevance to RBC band 3 protein binding and erythrocyte senescence. R-state equine CNmetHb crystal studies elaborate the solvent differences in the switch and hinge region compared with a human deoxyhemoglobin T-state neutron structure. Lastly, comparison of histidine protonation between the T and R state should enumerate the Bohr-effect protons.

In-situ neutron diffraction study of Zircaloy 4 subjected to biaxial tension

Energy Technology Data Exchange (ETDEWEB)

Gharghouri, M.A. [Canadian Neutron Beam Centre, Chalk River Laboratories, Chalk River, ON (Canada); McDonald, D.; Xiao, L. [Atomic Energy of Canada Limited, Chalk River, ON (Canada)

2014-07-01

Zircaloy-4 is widely used as fuel element cladding in nuclear reactors. Pellet-clad interaction (PCI) failure is a concern for many water reactor fuel designs. Extensive work on the mechanism of PCI failure has led to the conclusion that stress corrosion cracking (SCC) induced by iodine vapour in the temperature range relevant to fuel operation is the most probable cause of PCI failure in zirconium alloy fuel element cladding. In-situ neutron diffraction measurements performed on tubular Zircaloy-4 specimens simultaneously pulled in tension and pressurized internally will provide information on the effects of stress biaxiality on the distribution of stresses at the crystal level during loading. (author)

Neutron diffraction study of dense-Kondo compound CeNi2Al5

International Nuclear Information System (INIS)

Munoz, A.; Givord, F.; Boucherie, J.X.; Flouquet, J.; Isikawa, Y.; Mizushima, T.; Sakurai, J.; Mori, K.; Oliveira, I.S.

1993-01-01

Intermetallic CeNi 2 Al 5 is a dense-Kondo compound with a magnetic transition temperature at 2.6 K. We have carried out a neutron diffraction measurement to study a magnetic structure of CeNi 2 Al 5 using a powder sample and a single crystalline sample. It is found that the magnetic structure is an incommensurate sinusoidal one with a propagation vector k = (0.5, 0.405, 0.083) and that the amplitude of magnetic moment is 1.54 μ Β and the direction of magnetic moment is declined 8 deg. from the b-axis toward the a-axis. (authors). 3 refs., 2 figs

In situ Neutron Diffraction during Casting: Determination of Rigidity Point in Grain Refined Al-Cu Alloys.

Science.gov (United States)

Drezet, Jean-Marie; Mireux, Bastien; Szaraz, Zoltan; Pirling, Thilo

2014-02-12

The rigidity temperature of a solidifying alloy is the temperature at which the solid plus liquid phases are sufficiently coalesced to transmit long range tensile strains and stresses. It determines the point at which thermally induced deformations start to generate internal stresses in a casting. As such, it is a key parameter in numerical modelling of solidification processes and in studying casting defects such as solidification cracking. This temperature has been determined in Al-Cu alloys using in situ neutron diffraction during casting in a dog bone shaped mould. In such a setup, the thermal contraction of the solidifying material is constrained and stresses develop at a hot spot that is irradiated by neutrons. Diffraction peaks are recorded every 11 s using a large detector, and their evolution allows for the determination of the rigidity temperatures. We measured rigidity temperatures equal to 557 °C and 548 °C, depending on cooling rate, for a grain refined Al-13 wt% Cu alloy. At high cooling rate, rigidity is reached during the formation of the eutectic phase and the solid phase is not sufficiently coalesced, i.e. , strong enough, to avoid hot tear formation.

In situ Neutron Diffraction during Casting: Determination of Rigidity Point in Grain Refined Al-Cu Alloys

Directory of Open Access Journals (Sweden)

Jean-Marie Drezet

2014-02-01

Full Text Available The rigidity temperature of a solidifying alloy is the temperature at which the solid plus liquid phases are sufficiently coalesced to transmit long range tensile strains and stresses. It determines the point at which thermally induced deformations start to generate internal stresses in a casting. As such, it is a key parameter in numerical modelling of solidification processes and in studying casting defects such as solidification cracking. This temperature has been determined in Al-Cu alloys using in situ neutron diffraction during casting in a dog bone shaped mould. In such a setup, the thermal contraction of the solidifying material is constrained and stresses develop at a hot spot that is irradiated by neutrons. Diffraction peaks are recorded every 11 s using a large detector, and their evolution allows for the determination of the rigidity temperatures. We measured rigidity temperatures equal to 557 °C and 548 °C, depending on cooling rate, for a grain refined Al-13 wt% Cu alloy. At high cooling rate, rigidity is reached during the formation of the eutectic phase and the solid phase is not sufficiently coalesced, i.e., strong enough, to avoid hot tear formation.

Six-six (6-6) cell used in X-ray and neutron diffraction experiments under high pressure

International Nuclear Information System (INIS)

Nishiyama, Norimasa; Yamada, Akihiro

2015-01-01

At synchrotron radiation facilities and neutron experimental facilities, X-ray diffraction experiments and neutron diffraction experiments under high-pressure for large-capacity of samples are conducted using DIA type device and 6-axis pressure device that add pressure on cubic space. As the anvil assembly capable of mounting on the above two devices, MA6-6 cell has come to be used. This paper introduces the advantages of using MA6-6 cell, pressure region where experiment is possible with MA6-6 cell, and large-capacity high-pressure press beamline P61.2 that simulates MA-6-6 cell. At MA6-6 cell, 6 pieces of the first-stage anvils of DIA type device or 6-axis pressure device pressurize 6 pieces of the second-stage anvils. These second-stage anvils are included in MA6-6 anvil assembly. The greatest feature of MA6-6 cell is the adoption of the frame for taking alignment of the second stage anvils. By combining MA6-6 cell with DIA-type device or 6-axis pressure device, the degree of freedom of experiment increases, which can simplify the experimental setup. (A.O.)

Generation of laser-induced fast neutron and its application

International Nuclear Information System (INIS)

Cha, Hyung Ki; Kwon, D. H.; Nam, S. M.

2010-04-01

The supply of high-efficiency neutron source is still problematic even though a fast neutron source is being accepted increasingly for industrial applications. Radioisotopes and a neutron tube are typically being used, but their neutron flux, lifetime, and price are the limiting factors for more diverse applications. As ultra high power, short pulse laser technologies have been developed, a neutron source generated via laser induced nuclear reaction comes to the fore. The laser induced neutron source has a high peak flux in comparison to the traditional neutron source and is like a point source with its diameter less than 1 mm. These properties can be utilized effectively for the analysis of pulsed fast neutron activation or the studies of a fast neutron material damage and/or recover. The purpose of R and D here is to develop a robust neutron source with a yield of 10 7 neutrons/s, and to carry out a preliminary research for application study in the next research stage

Anisotropic thermal expansion of MgSiN2 from 10 to 300 K as measured by neutron diffraction

NARCIS (Netherlands)

Bruls, R.J.; Hintzen, H.T.J.M.; Metselaar, R.; Loong, C.K.

2000-01-01

The lattice parameters of orthorhombic MgSiN2 as a function of the temperature have been determined from time-of-flight neutron powder diffraction. The results indicate that MgSiN2, just like several other adamantine-type crystals, exhibits a relatively small thermal expansion coefficient at low

A re-analysis of neutron diffraction data from UO2

International Nuclear Information System (INIS)

Cooper, M.J.; Sakata, M.

1979-04-01

The results of a re-analysis of recent single crystal and powder neutron diffraction data from UO2 are presented and discussed. It is shown that apparent inconsistencies in the results of previous analyses of these data arose from differences between the values assumed for some of the parameters and that the various sets of data are in fact extremely consistent. These data also provide a more accurate value for the ratio of the scattering amplitudes, i.e. bU/bO = 1.451(2), which gives a value for bU = 0.842(2) x 10(-12) cm on the assumption of a value for b0 = 0.5805(11) x 10(-12) cm. The temperature factors for the atoms at room temperature are determined to be BU = 0.23(1)Angstrom and BO = 0.44(1)Angstrom(2). (author)

Structure of Se-Te glasses studied using neutron, X-ray diffraction and reverse Monte Carlo modelling

Energy Technology Data Exchange (ETDEWEB)

Itoh, Keiji, E-mail: itoh@okayama-u.ac.jp [Graduate School of Education, Okayama University, Tsushima-naka, Okayama 700-8530 (Japan); Research Reactor Institute, Kyoto University, Kumatori, Osaka 590-0494 (Japan)

2017-02-15

Pulsed neutron diffraction and synchrotron X-ray diffraction measurements were performed on Se{sub 100-x}Te{sub x} bulk glasses with x=10, 20, 30 and 40. The coordination numbers obtained from the diffraction results demonstrate that Se and Te atoms are twofold coordinated and the glass structure is formed by the chain network. The three-dimensional structure model for Se{sub 60}Te{sub 40} glass obtained by using reverse Monte Carlo modelling shows that the alternating arrangements of Se and Te atoms compose the major part of the chain clusters but several other fragments such as Se{sub n} chains and Te-Te dimers are also present in large numbers. The chain clusters have geometrically disordered forms and the interchain atomic order is different from those in the crystal structures of trigonal Se and trigonal Te. - Graphical abstract: Coordination environment in Se{sub 60}Te{sub 40} glass.

Neutrons and synchrotron radiation in engineering materials science from fundamentals to applications

CERN Document Server

Schreyer, Andreas; Clemens, Helmut; Mayer, Svea

2017-01-01

Retaining its proven concept, the second edition of this ready reference specifically addresses the need of materials engineers for reliable, detailed information on modern material characterization methods. As such, it provides a systematic overview of the increasingly important field of characterization of engineering materials with the help of neutrons and synchrotron radiation. The first part introduces readers to the fundamentals of structure-property relationships in materials and the radiation sources suitable for materials characterization. The second part then focuses on such characterization techniques as diffraction and scattering methods, as well as direct imaging and tomography. The third part presents new and emerging methods of materials characterization in the field of 3D characterization techniques like three-dimensional X-ray diffraction microscopy. The fourth and final part is a collection of examples that demonstrate the application of the methods introduced in the first parts to probl...

Automation of angular movement of the arm neutron diffractometer; Automatizacion del movimiento angular del brazo del difractometro de neutrones

Energy Technology Data Exchange (ETDEWEB)

Aguilar H, F.; Herrera A, E.; Quintana C, G. [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico); Torres R, C. E.; Reyes V, M., E-mail: fortunato.aguilar@inin.gob.mx [Instituto Tecnologico de Toluca, Av. Tecnologico s/n, Ex-Rancho La Virgen, Metepec, Estado de Mexico (Mexico)

2015-09-15

A technique to determine the crystal structure of some materials is the neutron diffraction. This technique consists on placing the material in question in a monoenergetic neutron beam obtained by neutron diffraction in a monochromator crystal. The neutron energy depends of the diffraction angle. The Instituto Nacional de Investigaciones Nucleares has a neutron diffractometer and monochromator crystals of pyrolytic graphite. This crystal can be selecting the neutron energy depending on the angle of diffraction in the glass. The radiation source for the neutron diffractometer is the TRIGA Mark III reactor of the Nuclear Center Dr. Nabor Carrillo Flores. During their operation are also obtained besides neutrons, β and γ radiation. The interest is to have thermal neutrons, so fast neutrons and γ rays are removed using appropriate shielding. The average neutron fluxes of the radial port RE2 of neutron diffractometer at power 1 MW are: heat flow 2,466 x 10{sup 8} n cm{sup -2} sec{sup -1} and fast flow 1,239 x 10{sup 8} n cm{sup -2} sec{sup -1}. The neutron detector is housed in a shield mounted on a mechanical linkage with which the diffraction angle is selected, and therefore the energy of the neutrons. The movement of this joint was performed by the equipment operator manually, so that accuracy to select the diffraction angle was not good and the process rather slow. Therefore a mechanical system was designed, automated by means of a motor as an actuator, a system of force transmission and an electronic control in order that the operator will schedule the diffraction angles and allow the count in the neutrons detection system in a simple manner. (Author)

Discussions in symposium 'neutron dosimetry in neutron fields - from detection techniques to medical applications'

International Nuclear Information System (INIS)

Tanimura, Y.; Sato, T.; Kumada, H.; Terunuma, T.; Sakae, T.; Harano, H.; Matsumoto, T.; Suzuki, T.; Matsufuji, N.

2008-01-01

Recently the traceability system (JCSS) of neutron standard based on the Japanese law 'Measurement Act' has been instituted. In addition, importance of the neutron dose evaluation has been increasing in not only the neutron capture medical treatment but also the proton or heavy particle therapy. Against such a background, a symposium 'Neutron dosimetry in neutron fields - From detection techniques to medical applications-' was held on March 29, 2008 and recent topics on the measuring instruments and their calibration, the traceability system, the simulation technique and the medical applications were introduced. This article summarizes the key points in the discussion at the symposium. (author)

On the use of a composite moderator at the IBR-2 reactor: Advantages for the neutron-diffraction texture analysis of rocks

Czech Academy of Sciences Publication Activity Database

Bulavin, M. V.; Vasin, R.N.; Kulikov, S.A.; Lokajíček, Tomáš; Levin, D.M.

2016-01-01

Roč. 10, č. 4 (2016), s. 677-686 ISSN 1027-4510 Institutional support: RVO:67985831 Keywords : cold moderator * neutron-diffraction texture analysis * phase analysis * Rietveld method Subject RIV: DB - Geology ; Mineralogy

Stress-induced martensite variant reorientation in magnetic shape memory Ni–Mn–Ga single crystal studied by neutron diffraction

Czech Academy of Sciences Publication Activity Database

Molnár, Peter; Šittner, Petr; Lukáš, Petr; Hannula, S.-P.; Heczko, Oleg

2008-01-01

Roč. 17, č. 3 (2008), 035014/1-035014/4 ISSN 0964-1726 Institutional research plan: CEZ:AV0Z10100520; CEZ:AV0Z10480505 Keywords : NiMnGa single crystal * neutron diffraction * stress induced martensite reorientation Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.743, year: 2008

Influence of Al on the magnetic properties of TmCo{sub 4}Al compound, a magnetic and neutron diffraction study

Energy Technology Data Exchange (ETDEWEB)

Laslo, A. [CNRS, Inst. Néel, F-38042 Grenoble (France); Univ. Grenoble Alpes, Inst. Néel, F-38042 Grenoble (France); Babes-Bolyai University, Faculty of Physics, 400084 Cluj-Napoca (Romania); Pop, V. [Babes-Bolyai University, Faculty of Physics, 400084 Cluj-Napoca (Romania); Isnard, O. [CNRS, Inst. Néel, F-38042 Grenoble (France); Univ. Grenoble Alpes, Inst. Néel, F-38042 Grenoble (France)

2015-03-25

Highlights: • The existence of a compensation temperature is found for TmCo{sub 4}Al. • The crystal structure and its thermal evolution are analysed by X-ray and neutron diffraction. • The ferrimagnetic magnetic structure of TmCo{sub 4}Al is established. • Magnetic properties are determined. • Significant coercivity is reported for TmCo{sub 4}Al. - Abstract: The structural and magnetic properties of the TmCo{sub 4}Al compound are presented as deduced from magnetic measurements, X-ray and neutron powder diffraction. The crystal structure is obtained in the light of Rietveld refinement of the neutron powder diffraction pattern. The symmetry of the CaCu{sub 5} structure is preserved and the Al atom is found to substitute the Co one exclusively on the 3g atomic position. Thermal expansion of the crystal lattice is reported, the temperature variation occurring mostly along the basal hexagonal plane. This compound exhibits a ferrimagnetic structure, the Tm and Co magnetic moments being coupled antiparallel. An ordering temperature of 511 K is found. The thermal dependence of the Tm magnetic moment is obtained down to 4 K. A compensation of the two sublattice magnetization is found at 75 K, a feature induced by the Al for Co substitution and not observed in the corresponding TmCo{sub 5} compound. Magnetization curves reveal large coercivity values at low temperature such as 2.48 T at 2 K.

Application of imaging plate neutron detector to neutron radiography

CERN Document Server

Fujine, S; Kamata, M; Etoh, M

1999-01-01

As an imaging plate neutron detector (IP-ND) has been available for thermal neutron radiography (TNR) which has high resolution, high sensitivity and wide range, some basic characteristics of the IP-ND system were measured at the E-2 facility of the KUR. After basic performances of the IP were studied, images with high quality were obtained at a neutron fluence of 2 to 7x10 sup 8 n cm sup - sup 2. It was found that the IP-ND system with Gd sub 2 O sub 3 as a neutron converter material has a higher sensitivity to gamma-ray than that of a conventional film method. As a successful example, clear radiographs of the flat view for the fuel side plates with boron burnable poison were obtained. An application of the IP-ND system to neutron radiography (NR) is presented in this paper.

Neutron diffraction study of internal stresses in brazed CFC/Mo divertor structures for NET/ITER

Energy Technology Data Exchange (ETDEWEB)

Ceretti, M [Laboratoire Leon-Brillouin, CEA/CE Saclay, F-91191, Gif-sur-Yvette (France); Coppola, R [ENEA/Casaccia, INN-FIS, C.P. 2400, I-00100 Rome (Italy); Di Pietro, E [ENEA/Frascati, Dip. FUS, C.P. 2400, I-00100 Rome (Italy); Lodini, A [Laboratoire Leon-Brillouin, CEA/CE Saclay, F-91191, Gif-sur-Yvette (France) Universite de Champagne-Ardennes, Reims (France); Perrin, M [Laboratoire Leon-Brillouin, CEA/CE Saclay, F-91191, Gif-sur-Yvette (France); Piant, A [Laboratoire Leon-Brillouin, CEA/CE Saclay, F-91191, Gif-sur-Yvette (France); Rustichelli, F [Istituto di Scienze Fisiche, Universita di Ancona (Italy)

1994-09-01

This contribution presents the first results of a study, performed by neutron diffraction, on the internal stresses remaining after brazing at 860 C in graphite/molybdenum samples developed for NET/ITER. Samples of polycrystalline graphite and a carbon-fiber composite are considered. The deformation field is characterized close to the brazing interface, within a linear spatial resolution of approximately 2 mm. The results are discussed with reference to those obtainable by other methods and to theoretical considerations. ((orig.))

Neutron beam applications - Development of operational techniques for neutron four-circle diffractometer and structure determination of C{sub 16}H{sub 15}NO{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Kim, Moon Jib [Soonchunhyang University, Asan (Korea); Suh, Il Hwan [Chungnam National University, Taejon (Korea)

1999-06-01

We have been studied to find out the experimental methods and procedures for neutron diffraction method for neutron diffractometer in HANARO -the atomic research reactor in KAERI. We have studied experimental process for the neutron diffraction data analysis, using computer soft-wares such as SHELXS for the calculation the initial phase of crystal structure, SHELXL for refinement of atomic coordinate using least-squares method, ORTEP for the display of the calculated positions of molecule, and PATSEE for the calculation of the phase from the expected structure. In these studies, we analyzed the structure of test sample using these programs, and prepare the user's manual for these soft-wares. We have also studied on bending effect of monochromator in order to increase the intensity of neutron beam, and designed HRPD - High Resolution Powder Diffractometers. 7 refs., 6 figs. (Author)

The role of iron in tetrahedrite and tennantite determined by Rietveld refinement of neutron powder diffraction data

DEFF Research Database (Denmark)

Andreasen, Jens Wenzel; Makovicky, Emil; Lebech, Bente

2008-01-01

Rietveld refinement of neutron powder diffraction data on four samples of synthetic, iron-bearing tetrahedrite (Cu12-xFexSb4S13) with x = 0.28, 0.69, 0.91, 2.19 and four samples of synthetic tennantite (Cu12-xFexAs4S13) with x = 0.33, 0.38, 0.86, 1.5 indicate unambiguously that iron is incorporated...

Novel applications of fast neutron interrogation methods

International Nuclear Information System (INIS)

Gozani, Tsahi

1994-01-01

The development of non-intrusive inspection methods for contraband consisting primarily of carbon, nitrogen, oxygen, and hydrogen requires the use of fast neutrons. While most elements can be sufficiently well detected by the thermal neutron capture process, some important ones, e.g., carbon and in particular oxygen, cannot be detected by this process. Fortunately, fast neutrons, with energies above the threshold for inelastic scattering, stimulate relatively strong and specific gamma ray lines from these elements. The main lines are: 6.13 for O, 4.43 for C, and 5.11, 2.31 and 1.64 MeV for N. Accelerator-generated neutrons in the energy range of 7 to 15 MeV are being considered as interrogating radiations in a variety of non-intrusive inspection systems for contraband, from explosives to drugs and from coal to smuggled, dutiable goods. In some applications, mostly for inspection of small items such as luggage, the decision process involves a rudimentary imaging, akin to emission tomography, to obtain the localized concentration of various elements. This technique is called FNA - Fast Neutron Analysis. While this approach offers improvements over the TNA (Thermal Neutron Analysis), it is not applicable to large objects such as shipping containers and trucks. For these challenging applications, a collimated beam of neutrons is rastered along the height of the moving object. In addition, the neutrons are generated in very narrow nanosecond pulses. The point of their interaction inside the object is determined by the time of flight (TOF) method, that is measuring the time elapsed from the neutron generation to the time of detection of the stimulated gamma rays. This technique, called PFNA (Pulsed Fast Neutron Analysis), thus directly provides the elemental, and by inference, the chemical composition of the material at every volume element (voxel) of the object. The various neutron-based techniques are briefly described below. ((orig.))

High-resolution inelastic neutron scattering and neutron powder diffraction study of the adsorption of dihydrogen by the Cu(II) metal-organic framework material HKUST-1

Science.gov (United States)

Callear, Samantha K.; Ramirez-Cuesta, Anibal J.; David, William I. F.; Millange, Franck; Walton, Richard I.

2013-12-01

We present new high-resolution inelastic neutron scattering (INS) spectra (measured using the TOSCA and MARI instruments at ISIS) and powder neutron diffraction data (measured on the diffractometer WISH at ISIS) from the interaction of the prototypical metal-organic framework HKUST-1 with various dosages of dihydrogen gas. The INS spectra show direct evidence for the sequential occupation of various distinct sites for dihydrogen in the metal-organic framework, whose population is adjusted during increasing loading of the guest. The superior resolution of TOSCA reveals subtle features in the spectra, not previously reported, including evidence for split signals, while complementary spectra recorded on MARI present full information in energy and momentum transfer. The analysis of the powder neutron patterns using the Rietveld method shows a consistent picture, allowing the crystallographic indenisation of binding sites for dihydrogen, thus building a comprehensive picture of the interaction of the guest with the nanoporous host.

Neutron diffraction study of magnetic structures in TbNiAl

International Nuclear Information System (INIS)

Javorsky, P.; Burlet, P.; Andreev, A.V.; Svoboda, P.

1997-01-01

A single crystal of TbNiAl has been studied by neutron diffraction and magnetization measurements. Terbium magnetic moments are aligned along the c-axis over the whole temperature range below T N =44.6 K. A change of the propagation and magnitude of one-third of the moments occurs at T 1 =23.5 K. Below T 1 , moments at (x,0,1/2) and (x,x,1/2) propagate with k=(1/2,0,1/2), while moments at (0,x,1/2) propagate with k'=(0,1/2,1/2) or k '' =(-1/2,1/2,1/2). All moments have the same magnitude. Between T 1 and T N , all moments propagate with the same propagation vector k, but moments at (0,x,1/2) are significantly reduced. A metamagnetic transition occurs in a field of 0.4 T applied along the c-axis. (orig.)

Development of MnBi permanent magnet: Neutron diffraction of MnBi powder

Energy Technology Data Exchange (ETDEWEB)

Cui, J., E-mail: jun.cui@pnnl.gov; Choi, J. P.; Li, G.; Polikarpov, E.; Darsell, J. [Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99354 (United States); Kramer, M. J.; Zarkevich, N. A.; Wang, L. L.; Johnson, D. D. [Materials Sciences and Engineering Division, Ames Laboratory, Ames, Iowa 50011 (United States); Marinescu, M. [Electron Energy Corporation, Landisville, Pennsylvania 17538 (United States); Huang, Q. Z.; Wu, H. [NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899-6102 (United States); Vuong, N. V.; Liu, J. P. [Department of Physics, University of Texas at Arlington, Arlington, Texas 76019 (United States)

2014-05-07

MnBi attracts great attention in recent years for its great potential as permanent magnet materials. MnBi phase is difficult to obtain because of the rather drastic peritectic reaction between Mn and Bi. In this paper, we report our effort on synthesizing high purity MnBi compound using conventional powder metallurgical approaches. Neutron diffraction was carried out to investigate the crystal and nuclear structure of the obtained powder. The result shows that the purity of the obtained powder is about 91 wt. % at 300 K, and the magnetic moment of the Mn atom in MnBi lattice is 4.424 and 4.013 μ{sub B} at 50 K and 300 K, respectively.

Deformation behaviors of aluminum alloys for automobile parts studied by neutron diffraction

International Nuclear Information System (INIS)

Katayanagi, Kazue; Morita, Kensuke; Tomota, Yo; Kamiyama, Takashi; Terakado, Katsuyoshi

2008-01-01

In situ time of flight neutron diffraction measurements during tension test were performed for three Al-Si alloys with different microstructures including hot-forged (AHS 2), T 6 heat-treated (AHS 2-T 6) and die-cast (ACD 12) specimens. Strength and work-hardening behaviors of these specimens are investigated by evaluating phase stresses, i.e., stress partitioning between Si and the Al matrix as well as intergranular stresses of [hkl] oriented family grains in the component phases. It is revealed that Si particles embedded in the Al matrix play a role of the hard second phase. The size and shape of the Si particles affect work hardening and fracture of the alloys. (author)

Development of MnBi permanent magnet: Neutron diffraction of MnBi powder

Energy Technology Data Exchange (ETDEWEB)

Cui, J; Choi, JP; Li, G; Polikarpov, E; Darsell, J; Kramer, MJ; Zarkevich, NA; Wang, LL; Johnson, DD; Marinescu, M; Huang, QZ; Wu, H; Vuong, NV; Liu, JP

2014-05-07

MnBi attracts great attention in recent years for its great potential as permanent magnet materials. MnBi phase is difficult to obtain because of the rather drastic peritectic reaction between Mn and Bi. In this paper, we report our effort on synthesizing high purity MnBi compound using conventional powder metallurgical approaches. Neutron diffraction was carried out to investigate the crystal and nuclear structure of the obtained powder. The result shows that the purity of the obtained powder is about 91 wt. % at 300 K, and the magnetic moment of the Mn atom in MnBi lattice is 4.424 and 4.013 mu(B) at 50 K and 300 K, respectively. (C) 2014 AIP Publishing LLC.

Measurement of residual stress in materials using neutrons. Proceedings of a technical meeting

International Nuclear Information System (INIS)

2005-06-01

One of the objectives of the IAEA's project on effective utilization of research reactors is to promote the use of the existing research reactors based on their capabilities and is implemented through workshops and technical meetings. Measurement of residual stress is one of the techniques that find wide applications in materials development and testing. The Technical Meeting on Measurement of Residual Stress Using Neutrons was organized to meet this objective. This publication is the outcome of the deliberations during the meeting and the presentations by the participants and is addressed to the research reactor managers, users and designers of facilities for reactor utilization. It will especially benefit those seeking to develop new facilities or upgrade the existing ones to enhance the utilization of their research reactors. Experts with a long experience in developing and using neutron beam instruments in high flux and medium flux research reactors participated in this technical meeting. They presented the design, development and utilization of the facilities at their respective centres and reviewed the current status of the residual stress measurements using neutron beams from research reactors. The sessions included brainstorming on the methodology and data analysis, characterization and standardization of the equipment and identifying the scope for further development. This publication refers to the determination of residual and/or applied stresses in polycrystalline materials using neutron diffraction technique. Stress is developed during the synthesis and use of materials such as alloys and compounds. Measurement of residual stress is essential to improve the quality of synthesized materials and diagnosis of failure and/or reliability of fabricated components. Neutron scattering has played an important role in studying structure and dynamics of condensed matter. Neutron scattering is a non-destructive technique and is useful for testing large samples. The

Use of neutron beams for fundamental research, applications and human capacity building: From national to regional perspectives

International Nuclear Information System (INIS)

Nothnagel, S.G.

2010-01-01

The SAFARI-1 research reactor at NECSA South Africa is currently one of the best utilized research reactors in the world. Apart from being used for materials irradiation and isotope production, there is a history of innovative utilization of neutron beam line techniques, such as neutron diffraction (strain scanning, powder and single crystal), neutron radiography/tomography, prompt gamma-ray neutron activation analysis and small angle neutron scattering both for NECSA research programs and external users. Through these applications neutron beam line diagnostics have been shown to make important contributions to a number of key research areas in South Africa. As a result these techniques are now being viewed as 'standard and essential' for an increasing number of researchers who came to appreciate the extra dimension of knowledge provided by neutron techniques. In addition neutron beam line facilities provide excellent training platforms for human capacity building in nuc lear and material related science and technology. Because of these reasons neutron beam line facilities at research reactors offer unique opportunities to build productive cross-cutting research collaborations, at national and regional levels. Some information on the role that nuclear beams can play, in the capacities mentioned, will be shared by virtue of some examples and the national, international and regional net-working potential of research reactor based neutron facilities shall be discussed.

Compact D-D/D-T neutron generators and their applications

International Nuclear Information System (INIS)

Lou, Tak Pui

2003-01-01

Neutron generators based on the 2 H(d,n) 3 He and 3 H(d,n) 4 He fusion reactions are the most commonly available neutron sources. The applications of current commercial neutron generators are often limited by their low neutron yield and their short operational lifetime. A new generation of D-D/D-T fusion-based neutron generators has been designed at Lawrence Berkeley National Laboratory (LBNL) by using high current ion beams hitting on a self-loading target that has a large surface area to dissipate the heat load. This thesis describes the rationale behind the new designs and their potential applications. A survey of other neutron sources is presented to show their advantages and disadvantages compared to the fusion-based neutron generator. A prototype neutron facility was built at LBNL to test these neutron generators. High current ion beams were extracted from an RF-driven ion source to produce neutrons. With an average deuteron beam current of 24 mA and an energy of 100 keV, a neutron yield of >10 9 n/s has been obtained with a D-D coaxial neutron source. Several potential applications were investigated by using computer simulations. The computer code used for simulations and the variance reduction techniques employed were discussed. A study was carried out to determine the neutron flux and resolution of a D-T neutron source in thermal neutron scattering applications for condensed matter experiments. An error analysis was performed to validate the scheme used to predict the resolution. With a D-T neutron yield of 10 14 n/s, the thermal neutron flux at the sample was predicted to be 7.3 x 10 5 n/cm 2 s. It was found that the resolution of cold neutrons was better than that of thermal neutrons when the duty factor is high. This neutron generator could be efficiently used for research and educational purposes at universities. Additional applications studied were positron production and Boron Neutron Capture Therapy (BNCT). The neutron flux required for positron