WorldWideScience

Sample records for network study ions

  1. IOOC Organizational Network (ION) Project

    Science.gov (United States)

    Dean, H.

    2013-12-01

    In order to meet the growing need for ocean information, research communities at the national and international levels have responded most recently by developing organizational frameworks that can help to integrate information across systems of existing networks and standardize methods of data gathering, management, and processing that facilitate integration. To address recommendations and identified challenges related to the need for a better understanding of ocean observing networks, members of the U.S. Interagency Ocean Observation Committee (IOOC) supported pursuing a project that came to be titled the IOOC Organizational Network (ION). The ION tool employs network mapping approaches which mirror approaches developed in academic literature aimed at understanding political networks. Researchers gathered data on the list of global ocean observing organizations included in the Framework for Ocean Observing (FOO), developed in 2012 by the international Task Team for an Integrated Framework for Sustained Ocean Observing. At the international scale, researchers reviewed organizational research plans and documents, websites, and formal international agreement documents. At the U.S. national scale, researchers analyzed legislation, formal inter-agency agreements, work plans, charters, and policy documents. Researchers based analysis of relationships among global organizations and national federal organizations on four broad relationship categories: Communications, Data, Infrastructure, and Human Resources. In addition to the four broad relationship categories, researchers also gathered data on relationship instrument types, strength of relationships, and (at the global level) ocean observing variables. Using network visualization software, researchers then developed a series of dynamic webpages. Researchers used the tool to address questions identified by the ocean observing community, including identifying gaps in global relationships and the types of tools used to

  2. Ion aggregation in high salt solutions. II. Spectral graph analysis of water hydrogen-bonding network and ion aggregate structures

    Science.gov (United States)

    Choi, Jun-Ho; Cho, Minhaeng

    2014-10-01

    Graph theory in mathematics and computer science is the study of graphs that are structures with pairwise connections between any objects. Here, the spectral graph theory and molecular dynamics simulation method are used to describe both morphological variation of ion aggregates in high salt solutions and ion effects on water hydrogen-bonding network structure. From the characteristic value analysis of the adjacency matrices that are graph theoretical representations of ion clusters, ion networks, and water H-bond structures, we obtained the ensemble average eigenvalue spectra revealing intricate connectivity and topology of ion aggregate structure that can be classified as either ion cluster or ion network. We further show that there is an isospectral relationship between the eigenvalue spectra of ion networks in high KSCN solutions and those of water H-bonding networks. This reveals the isomorphic relationship between water H-bond structure and ion-ion network structure in KSCN solution. On the other hand, the ion clusters formed in high NaCl solutions are shown to be graph-theoretically and morphologically different from the ion network structures in KSCN solutions. These observations support the bifurcation hypothesis on large ion aggregate growth mechanism via either ion cluster or ion network formation. We thus anticipate that the present spectral graph analyses of ion aggregate structures and their effects on water H-bonding network structures in high salt solutions can provide important information on the specific ion effects on water structures and possibly protein stability resulting from protein-water interactions.

  3. Ion aggregation in high salt solutions. II. Spectral graph analysis of water hydrogen-bonding network and ion aggregate structures.

    Science.gov (United States)

    Choi, Jun-Ho; Cho, Minhaeng

    2014-10-21

    Graph theory in mathematics and computer science is the study of graphs that are structures with pairwise connections between any objects. Here, the spectral graph theory and molecular dynamics simulation method are used to describe both morphological variation of ion aggregates in high salt solutions and ion effects on water hydrogen-bonding network structure. From the characteristic value analysis of the adjacency matrices that are graph theoretical representations of ion clusters, ion networks, and water H-bond structures, we obtained the ensemble average eigenvalue spectra revealing intricate connectivity and topology of ion aggregate structure that can be classified as either ion cluster or ion network. We further show that there is an isospectral relationship between the eigenvalue spectra of ion networks in high KSCN solutions and those of water H-bonding networks. This reveals the isomorphic relationship between water H-bond structure and ion-ion network structure in KSCN solution. On the other hand, the ion clusters formed in high NaCl solutions are shown to be graph-theoretically and morphologically different from the ion network structures in KSCN solutions. These observations support the bifurcation hypothesis on large ion aggregate growth mechanism via either ion cluster or ion network formation. We thus anticipate that the present spectral graph analyses of ion aggregate structures and their effects on water H-bonding network structures in high salt solutions can provide important information on the specific ion effects on water structures and possibly protein stability resulting from protein-water interactions.

  4. Magnetostatics and dynamics of ion irradiatied NiFe/Ta multilayer films studied by vector network analyzer ferromagnetic resonance

    Energy Technology Data Exchange (ETDEWEB)

    Marko, Daniel

    2010-11-25

    In the present work, the implications of ion irradiation on the magnetostatic and dynamic properties of soft magnetic Py/Ta (Py=Permalloy: Ni{sub 80}Fe{sub 20}) single and multilayer films have been investigated with the main objective of finding a way to determine their saturation magnetization. Both polar magneto-optical Kerr effect (MOKE) and vector network analyzer ferromagnetic resonance (VNA-FMR) measurements have proven to be suitable methods to determine {mu}{sub 0}M{sub S}, circumventing the problem of the unknown effective magnetic volume that causes conventional techniques such as SQUID or VSM to fail. Provided there is no perpendicular anisotropy contribution in the samples, the saturation magnetization can be determined even in the case of strong interfacial mixing due to an inherently high number of Py/Ta interfaces and/or ion irradiation with high fluences. Another integral part of this work has been to construct a VNA-FMR spectrometer capable of performing both azimuthal and polar angle-dependent measurements using a magnet strong enough to saturate samples containing iron. Starting from scratch, this comprised numerous steps such as developing a suitable coplanar waveguide design, and writing the control, evaluation, and fitting software. With both increasing ion fluence and number of Py/Ta interfaces, a decrease of saturation magnetization has been observed. In the case of the 10 x Py samples, an immediate decrease of {mu}{sub 0}M{sub S} already sets in at small ion fluences. However, for the 1 x Py and 5 x Py samples, the saturation magnetization remains constant up to a certain ion fluence, but then starts to rapidly decrease. Ne ion irradiation causes a mixing and broadening of the interfaces. Thus, the Py/Ta stacks undergo a transition from being polycrystalline to amorphous at a critical fluence depending on the number of interfaces. The saturation magnetization is found to vanish at a Ta concentration of about 10-15 at.% in the Py layers

  5. Ion aggregation in high salt solutions. V. Graph entropy analyses of ion aggregate structure and water hydrogen bonding network

    Science.gov (United States)

    Choi, Jun-Ho; Cho, Minhaeng

    2016-05-01

    Dissolved ions in water tend to form polydisperse ion aggregates such as ion pairs, relatively compact ion clusters, and even spatially extended ion networks with increasing salt concentration. Combining molecular dynamics simulation and graph theoretical analysis methods, we recently studied morphological structures of ion aggregates with distinctively different characteristics. They can be distinguished from each other by calculating various spectral graph theoretical properties such as eigenvalues and eigenvectors of adjacency matrices of ion aggregates and water hydrogen-bonding networks, minimum path lengths, clustering coefficients, and degree distributions. Here, we focus on percolation and graph entropic properties of ion aggregates and water hydrogen-bonding networks in high salt solutions. Ion network-forming K+ and SCN- ions at high concentrations show a percolating behavior in their aqueous solutions, but ion cluster-forming ions in NaCl solutions do not show such a transition from isolated ion aggregates to percolating ion-water mixture morphology. Despite that the ion aggregate structures are strikingly different for either cluster- or network-forming ions in high salt solutions, it is interesting that the water structures remain insensitive to the electrostatic properties, such as charge densities and polydentate properties, of dissolved ions, and morphological structures of water H-bonding networks appear to be highly robust regardless of the nature and concentration of salt. We anticipate that the present graph entropy analysis results would be of use in understanding a variety of anomalous behaviors of interfacial water around biomolecules as well as electric conductivities of high electrolyte solutions.

  6. Ion aggregation in high salt solutions. V. Graph entropy analyses of ion aggregate structure and water hydrogen bonding network.

    Science.gov (United States)

    Choi, Jun-Ho; Cho, Minhaeng

    2016-05-28

    Dissolved ions in water tend to form polydisperse ion aggregates such as ion pairs, relatively compact ion clusters, and even spatially extended ion networks with increasing salt concentration. Combining molecular dynamics simulation and graph theoretical analysis methods, we recently studied morphological structures of ion aggregates with distinctively different characteristics. They can be distinguished from each other by calculating various spectral graph theoretical properties such as eigenvalues and eigenvectors of adjacency matrices of ion aggregates and water hydrogen-bonding networks, minimum path lengths, clustering coefficients, and degree distributions. Here, we focus on percolation and graph entropic properties of ion aggregates and water hydrogen-bonding networks in high salt solutions. Ion network-forming K(+) and SCN(-) ions at high concentrations show a percolating behavior in their aqueous solutions, but ion cluster-forming ions in NaCl solutions do not show such a transition from isolated ion aggregates to percolating ion-water mixture morphology. Despite that the ion aggregate structures are strikingly different for either cluster- or network-forming ions in high salt solutions, it is interesting that the water structures remain insensitive to the electrostatic properties, such as charge densities and polydentate properties, of dissolved ions, and morphological structures of water H-bonding networks appear to be highly robust regardless of the nature and concentration of salt. We anticipate that the present graph entropy analysis results would be of use in understanding a variety of anomalous behaviors of interfacial water around biomolecules as well as electric conductivities of high electrolyte solutions.

  7. Near Edge X-ray Absorption Fine Structure Studies of Cu Ion-Containing PAMAMOS Dendrimer Networks

    Science.gov (United States)

    Bubeck, Robert; Dvornic, Petar; Fischer, Daniel

    2012-02-01

    There is continuing interest in the development of nanocomposites containing metal ions based on the use of dendrimers as the host matrix. One may utilize functionalized dendrimer interiors to complex the added constituent and serve as a template for the organization of the resulting nanoscale structures. Potential applications of include: catalysts, biotechnology, functional membranes, molecular sensors, etc. We report on recent results obtained using near edge X-ray absorption fine structure (NEXAFS) to characterize Cu(2+) covalent interactions in three-dimensionally cross linked dendrimer networks. These networks were made from radially-layered poly(amidoamine-organosilicon), PAMAMOS, dendrimers having generation 4 (G4) polyamidoamine (PAMAM) interiors surrounded by one layer of organosilicon, OS, exterior branch cells. Lower generation homologues (i.e., G1 through G3) were also examined on a more limited basis. The nitrogen and carbonyl moieties contained in the PAMAM dendrimer interior were shown to be highly interactive with metallic cations, in large measure because of the dendrimer geometry. Similar measurements on chemically similar but much less physically constraining hyperbranched polymers indicated very limited interaction with the amine and carbonyl moieties.

  8. Ion-induced modification of the sucrose network and its impact on melting of freeze-dried liposomes. DSC and molecular dynamics study.

    Science.gov (United States)

    Bakarić, Danijela; Petrov, Dražen; Mouvenchery, Yamuna Kunhi; Heiβler, Stefan; Oostenbrink, Chris; Schaumann, Gabriele E

    2017-11-24

    Disaccharides play an important role in survival of anhydrobiotic organisms during extreme environmental conditions. A key protection feature is their capability to form the hydrogen bond (HB) network in a similar fashion as the one made by water. Since various ions also affect the HB network in completely hydrated systems, it is of a great interest to understand how they impact preservation when incorporated in a disaccharide network. To address this, we employ a combination of experimental and modeling techniques to study behavior of multilamellar 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) liposomes freeze-dried with sucrose in presence of NaCl or NaH2PO4·H2O at various concentrations (0.01-1M). Differential scanning calorimetry (DSC) was employed in order to determine the cooperative unit size (CUS), the number of lipid molecules that constitute a domain of cooperative motion in the liposome, and the melting temperature (Tm). In the absence of salt CUS was estimated to be 122±12, whereas in the presence of NaCl CUS increases more (347±34 for c=1M) than for NaH2PO4·H2O (193±26 for 1M). When it comes to Tm, the situation is reversed; NaCl induces increase by about 1K, while NaH2PO4·H2O by about 10K. These findings clearly demonstrate how different interaction forces-hydrogen bonding, charge pairing, and van der Waals interactions between acyl chains-affect CUS and Tm. Their interplay and contribution of particular interaction was further analyzed with molecular dynamics (MD) simulations. This analysis demonstrated that the HB network of DMPC and sucrose is partially disrupted in the presence of NaCl ions, and even to a greater extent in the case of NaH2PO4·H2O ions. Notably, H2PO4- ions outcompete and replace the sucrose molecules at the DMPC surface, which in turn alters the nature of the DMPC-surrounding interactions, from a weaker HB-dominated to a stronger CP-dominated interaction network. Copyright © 2017 Elsevier B.V. All rights reserved.

  9. Tropospheric ozone surface depletion (spring) and pollution (summer) in 2008 from the ARCTAS Intensive Ozonesonde Network Study (ARC-IONS) soundings

    Science.gov (United States)

    Thompson, A. M.; Luzik, A. M.; Doughty, D. C.; Gallagher, S. D.; Miller, S. K.; Oltmans, S. J.; Tarasick, D. W.; Witte, J. C.; Bryan, A. M.; Walker, T.; Osterman, G. B.; Worden, J.

    2008-12-01

    During NASA's ARCTAS (Arctic Research of the Composition of the Troposphere with Aircraft and Satellites; http://espo.nasa.gov/arctas) spring and summer 2008 campaigns, an ozonesonde network, ARC- IONS (ARCTAS Intensive Ozonesonde Network Study), launched ozonesonde-radiosonde packages each day (1-20 April, 26 June-12 July) during the A-Train satellite constellation overpass, ~1300 local. Seventeen ARC-IONS stations were located across the northern tier of North America, over both Alaska and Canada, with one site in Greenland and two in the western US; map at (http://croc.gsfc.nasa.gov/arcions). In addition to satellite validation, the soundings provided a coherent, well-distributed set of ozone profiles for: (1) comparison with and interpretation of airborne measurements; (2) complementarity to ARCTAS and IPY (International Polar Year) ground bases at Greenland, Barrow, Eureka, Yellowknife; (3) model evaluation; (4) investigations of processes affecting day-to-day ozone variability. Two aspects of tropospheric ozone variability are described here. First, ozone depletion likely associated with rapid halogen reactions, is prominent in spring at Barrow (71N, 157W) and Resolute (75N, 95W). Second, during summer, relationships among long-range transport of Asian pollution (industrial and fires), California and Canadian fires and daily ozone budgets are established with trajectories, satellite smoke/fire data and laminar identification, the latter method developed in Thompson et al. (2007) and Yorks et al. (2008). Canadian maritime stations display eastern seaboard pollution and stratospheric influences as in IONS-04 (INTEX Ozonesonde Network Study).

  10. Tropospheric ozone sources and wave activity over Mexico City and Houston during MILAGRO/Intercontinental Transport Experiment (INTEX-B Ozonesonde Network Study, 2006 (IONS-06

    Directory of Open Access Journals (Sweden)

    L. Ladino

    2008-09-01

    Full Text Available During the INTEX-B (Intercontinental Chemical Transport Experiment/ MILAGRO (Megacities Initiative: Local and Global Research Observations experiments in March 2006 and the associated IONS-06 (INTEX Ozonesonde Network Study; ions06.html" target="_blank">http://croc.gsfc.nasa.gov/intexb/ions06.html, regular ozonesonde launches were made over 15 North American sites. The soundings were strategically positioned to study inter-regional flows and meteorological interactions with a mixture of tropospheric O3 sources: local pollution; O3 associated with convection and lightning; stratosphere-troposphere exchange. The variability of tropospheric O3 over the Mexico City Basin (MCB; 19° N, 99° W and Houston (30° N, 95° W is reported here. MCB and Houston profiles displayed a double tropopause in most soundings and a subtropical tropopause layer with frequent wave disturbances, identified through O3 laminae as gravity-wave induced. Ozonesondes launched over both cities in August and September 2006 (IONS-06, Phase 3 displayed a thicker tropospheric column O3 (~7 DU or 15–20% than in March 2006; nearly all of the increase was in the free troposphere. In spring and summer, O3 laminar structure manifested mixed influences from the stratosphere, convective redistribution of O3 and precursors, and O3 from lightning NO. Stratospheric O3 origins were present in 39% (MCB and 60% (Houston of the summer sondes. Comparison of summer 2006 O3 structure with summer 2004 sondes (IONS-04 over Houston showed 7% less tropospheric O3 in 2006. This may reflect a sampling contrast, August to mid-September 2006 instead of July-mid August 2004.

  11. Tropospheric ozone sources and wave activity over Mexico City and Houston during MILAGRO/Intercontinental Transport Experiment (INTEX-B) Ozonesonde Network Study, 2006 (IONS-06)

    Science.gov (United States)

    Thompson, A. M.; Yorks, J. E.; Miller, S. K.; Witte, J. C.; Dougherty, K. M.; Morris, G. A.; Baumgardner, D.; Ladino, L.; Rappenglück, B.

    2008-09-01

    During the INTEX-B (Intercontinental Chemical Transport Experiment)/ MILAGRO (Megacities Initiative: Local and Global Research Observations) experiments in March 2006 and the associated IONS-06 (INTEX Ozonesonde Network Study; http://croc.gsfc.nasa.gov/intexb/ions06.html), regular ozonesonde launches were made over 15 North American sites. The soundings were strategically positioned to study inter-regional flows and meteorological interactions with a mixture of tropospheric O3 sources: local pollution; O3 associated with convection and lightning; stratosphere-troposphere exchange. The variability of tropospheric O3 over the Mexico City Basin (MCB; 19° N, 99° W) and Houston (30° N, 95° W) is reported here. MCB and Houston profiles displayed a double tropopause in most soundings and a subtropical tropopause layer with frequent wave disturbances, identified through O3 laminae as gravity-wave induced. Ozonesondes launched over both cities in August and September 2006 (IONS-06, Phase 3) displayed a thicker tropospheric column O3 (~7 DU or 15 20%) than in March 2006; nearly all of the increase was in the free troposphere. In spring and summer, O3 laminar structure manifested mixed influences from the stratosphere, convective redistribution of O3 and precursors, and O3 from lightning NO. Stratospheric O3 origins were present in 39% (MCB) and 60% (Houston) of the summer sondes. Comparison of summer 2006 O3 structure with summer 2004 sondes (IONS-04) over Houston showed 7% less tropospheric O3 in 2006. This may reflect a sampling contrast, August to mid-September 2006 instead of July-mid August 2004.

  12. Anomalous ion diffusion within skeletal muscle transverse tubule networks

    Directory of Open Access Journals (Sweden)

    Soboleva Tanya K

    2007-05-01

    Full Text Available Abstract Background Skeletal muscle fibres contain transverse tubular (t-tubule networks that allow electrical signals to rapidly propagate into the fibre. These electrical signals are generated by the transport of ions across the t-tubule membranes and this can result in significant changes in ion concentrations within the t-tubules during muscle excitation. During periods of repeated high-frequency activation of skeletal muscle the t-tubule K+ concentration is believed to increase significantly and diffusive K+ transport from the t-tubules into the interstitial space provides a mechanism for alleviating muscle membrane depolarization. However, the tortuous nature of the highly branched space-filling t-tubule network impedes the diffusion of material through the network. The effective diffusion coefficient for ions in the t-tubules has been measured to be approximately five times lower than in free solution, which is significantly different from existing theoretical values of the effective diffusion coefficient that range from 2–3 times lower than in free solution. To resolve this discrepancy, in this paper we study the process of diffusion within electron microscope scanned sections of the skeletal muscle t-tubule network using mathematical modelling and computer simulation techniques. Our model includes t-tubule geometry, tautness, hydrodynamic and non-planar network factors. Results Using our model we found that the t-tubule network geometry reduced the K+ diffusion coefficient to 19–27% of its value in free solution, which is consistent with the experimentally observed value of 21% and is significantly smaller than existing theoretical values that range from 32–50%. We also found that diffusion in the t-tubules is anomalous for skeletal muscle fibres with a diameter of less than approximately 10–20 μm as a result of obstructed diffusion. We also observed that the [K+] within the interior of the t-tubule network during high

  13. Molecular Dynamics Study of Twister Ribozyme: Role of Mg(2+) Ions and the Hydrogen-Bonding Network in the Active Site.

    Science.gov (United States)

    Ucisik, Melek N; Bevilacqua, Philip C; Hammes-Schiffer, Sharon

    2016-07-12

    The recently discovered twister ribozyme is thought to utilize general acid-base catalysis in its self-cleavage mechanism, but the roles of nucleobases and metal ions in the mechanism are unclear. Herein, molecular dynamics simulations of the env22 twister ribozyme are performed to elucidate the structural and equilibrium dynamical properties, as well as to examine the role of Mg(2+) ions and possible candidates for the general base and acid in the self-cleavage mechanism. The active site region and the ends of the pseudoknots were found to be less mobile than other regions of the ribozyme, most likely providing structural stability and possibly facilitating catalysis. A purported catalytic Mg(2+) ion and the closest neighboring Mg(2+) ion remained chelated and relatively immobile throughout the microsecond trajectories, although removal of these Mg(2+) ions did not lead to any significant changes in the structure or equilibrium motions of the ribozyme on the microsecond time scale. In addition, a third metal ion, a Na(+) ion remained close to A1(O5'), the leaving group atom, during the majority of the microsecond trajectories, suggesting that it might stabilize the negative charge on A1(O5') during self-cleavage. The locations of these cations and their interactions with key nucleotides in the active site suggest that they may be catalytically relevant. The P1 stem is partially melted at its top and bottom in the crystal structure and further unwinds in the trajectories. The simulations also revealed an interconnected network comprised of hydrogen-bonding and π-stacking interactions that create a relatively rigid network around the self-cleavage site. The nucleotides involved in this network are among the highly conserved nucleotides in twister ribozymes, suggesting that this interaction network may be important to structure and function.

  14. Helium ion microscopy for high-resolution visualization of the articular cartilage collagen network.

    Science.gov (United States)

    Vanden Berg-Foels, W S; Scipioni, L; Huynh, C; Wen, X

    2012-05-01

    The articular cartilage collagen network is an important research focus because network disruption results in cartilage degeneration and patient disability. The recently introduced helium ion microscope (HIM), with its smaller probe size, longer depth of field and charge neutralization, has the potential to overcome the inherent limitations of electron microscopy for visualization of collagen network features, particularly at the nanoscale. In this study, we evaluated the capabilities of the helium ion microscope for high-resolution visualization of the articular cartilage collagen network. Images of rabbit knee cartilage were acquired with a helium ion microscope; comparison images were acquired with a field emission scanning electron microscope (FE-SEM) and a transmission electron microscope (TEM). Sharpness of example high-resolution helium ion microscope and field emission scanning electron microscope images was quantified using the 25-75% rise distance metric. The helium ion microscope was able to acquire high-resolution images with unprecedented clarity, with greater sharpness and three-dimensional-like detail of nanoscale fibril morphologies and fibril connections, in samples without conductive coatings. These nanoscale features could not be resolved by field emission scanning electron microscopy, and three-dimensional network structure could not be visualized with transmission electron microscopy. The nanoscale three-dimensional-like visualization capabilities of the helium ion microscope will enable new avenues of investigation in cartilage collagen network research. © 2012 The Authors Journal of Microscopy © 2012 Royal Microscopical Society.

  15. Multispecies Trapped-Ion Node for Quantum Networking

    Science.gov (United States)

    Inlek, I. V.; Crocker, C.; Lichtman, M.; Sosnova, K.; Monroe, C.

    2017-06-01

    Trapped atomic ions are a leading platform for quantum information networks, with long-lived identical qubit memories that can be locally entangled through their Coulomb interaction and remotely entangled through photonic channels. However, performing both local and remote operations in a single node of a quantum network requires extreme isolation between spectator qubit memories and qubits associated with the photonic interface. We achieve this isolation by cotrapping 171Yb+ and 138Ba+ qubits. We further demonstrate the ingredients of a scalable ion trap network node with two distinct experiments that consist of entangling the mixed species qubit pair through their collective motion and entangling a 138Ba+ qubit with an emitted visible photon.

  16. Ion aggregation in high salt solutions. IV. Graph-theoretical analyses of ion aggregate structure and water hydrogen bonding network

    Science.gov (United States)

    Choi, Jun-Ho; Cho, Minhaeng

    2015-09-01

    Ions in high salt solutions form a variety of ion aggregates, from ion pairs to clusters and networks. Their influences on water hydrogen bonding (H-bonding) network structures have long been of great interest. Recently, we have shown that the morphological structures of ion aggregates can be analyzed by using a spectral graph analysis theory, where each ion cluster or ion network is represented by a properly defined graph with edges and vertices. Here, to further examine the network properties of ion aggregates and water H-bonding networks in high salt solutions, we consider a few representative graph-theoretical descriptors: clustering coefficient, minimum path length, global efficiency, and degree distribution of ion aggregates. From the molecular dynamics trajectories, these graph theoretical properties of ion aggregates and water structures in NaCl and kosmotropic solutions are calculated and shown to be strongly dependent on the two types of ion aggregate structures, i.e., ion cluster and ion network. Ion clusters in high NaCl solutions exhibit typical behaviors of scale free network. The corresponding graph theoretical properties of ion networks in high KSCN solutions are notably different from those of NaCl ion clusters and furthermore they are very similar to those of water hydrogen-bonding network. The present graph-theoretical analysis results indicate that the high solubility limits of KSCN and other ion-network-forming salts might originate from their ability to form a large scale morphological network that can be intertwined with co-existing water H-bonding network. Furthermore, it is shown that the graph-theoretical properties of water H-bonding network structures do not strongly depend on the nature of dissolved ions nor on the morphological structures of ion aggregates, indicating that water's H-bonding interaction and network-forming capability are highly robust. We anticipate that the present graph-theoretical analysis results of high salt

  17. Ion aggregation in high salt solutions. IV. Graph-theoretical analyses of ion aggregate structure and water hydrogen bonding network.

    Science.gov (United States)

    Choi, Jun-Ho; Cho, Minhaeng

    2015-09-14

    Ions in high salt solutions form a variety of ion aggregates, from ion pairs to clusters and networks. Their influences on water hydrogen bonding (H-bonding) network structures have long been of great interest. Recently, we have shown that the morphological structures of ion aggregates can be analyzed by using a spectral graph analysis theory, where each ion cluster or ion network is represented by a properly defined graph with edges and vertices. Here, to further examine the network properties of ion aggregates and water H-bonding networks in high salt solutions, we consider a few representative graph-theoretical descriptors: clustering coefficient, minimum path length, global efficiency, and degree distribution of ion aggregates. From the molecular dynamics trajectories, these graph theoretical properties of ion aggregates and water structures in NaCl and kosmotropic solutions are calculated and shown to be strongly dependent on the two types of ion aggregate structures, i.e., ion cluster and ion network. Ion clusters in high NaCl solutions exhibit typical behaviors of scale free network. The corresponding graph theoretical properties of ion networks in high KSCN solutions are notably different from those of NaCl ion clusters and furthermore they are very similar to those of water hydrogen-bonding network. The present graph-theoretical analysis results indicate that the high solubility limits of KSCN and other ion-network-forming salts might originate from their ability to form a large scale morphological network that can be intertwined with co-existing water H-bonding network. Furthermore, it is shown that the graph-theoretical properties of water H-bonding network structures do not strongly depend on the nature of dissolved ions nor on the morphological structures of ion aggregates, indicating that water's H-bonding interaction and network-forming capability are highly robust. We anticipate that the present graph-theoretical analysis results of high salt

  18. ENLIGHT: The European Network for Light Ion Hadron Therapy.

    Science.gov (United States)

    Dosanjh, Manjit; Cirilli, Manuela; Greco, Virginia; Meijer, Annelie E

    2012-11-01

    The European Network for Light Ion Hadron Therapy (ENLIGHT) was established in 2002 to coordinate European efforts on hadron therapy (radiotherapy performed with protons and light ions instead of high-energy photons). The ENLIGHT network is formed by the European Hadron Therapy Community, with more than 300 participants from 20 different countries. A major success of ENLIGHT has been uniting traditionally separate communities so that clinicians, physicists, biologists, and engineers with experience and interest in particle therapy work together. ENLIGHT has been a successful initiative in forming a common European platform and bringing together people from diverse disciplines. ENLIGHT demonstrates the advantages of regular and organized exchanges of data, information, and best practices, as well as determining and following strategies for future needs in research and technological development in the hadron therapy field.

  19. Networked Microgrids Scoping Study

    Energy Technology Data Exchange (ETDEWEB)

    Backhaus, Scott N. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dobriansky, Larisa [General MicroGrids, San Diego, CA (United States); Glover, Steve [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Liu, Chen-Ching [Washington State Univ., Pullman, WA (United States); Looney, Patrick [Brookhaven National Lab. (BNL), Upton, NY (United States); Mashayekh, Salman [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Pratt, Annabelle [National Renewable Energy Lab. (NREL), Golden, CO (United States); Schneider, Kevin [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Stadler, Michael [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Starke, Michael [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Wang, Jianhui [Argonne National Lab. (ANL), Argonne, IL (United States); Yue, Meng [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2016-12-05

    Much like individual microgrids, the range of opportunities and potential architectures of networked microgrids is very diverse. The goals of this scoping study are to provide an early assessment of research and development needs by examining the benefits of, risks created by, and risks to networked microgrids. At this time there are very few, if any, examples of deployed microgrid networks. In addition, there are very few tools to simulate or otherwise analyze the behavior of networked microgrids. In this setting, it is very difficult to evaluate networked microgrids systematically or quantitatively. At this early stage, this study is relying on inputs, estimations, and literature reviews by subject matter experts who are engaged in individual microgrid research and development projects, i.e., the authors of this study The initial step of the study gathered input about the potential opportunities provided by networked microgrids from these subject matter experts. These opportunities were divided between the subject matter experts for further review. Part 2 of this study is comprised of these reviews. Part 1 of this study is a summary of the benefits and risks identified in the reviews in Part 2 and synthesis of the research needs required to enable networked microgrids.

  20. Studies of the hydroxyborohydride and triborohydride ions

    Energy Technology Data Exchange (ETDEWEB)

    Reed, J.

    1977-10-01

    Results of the following studies are reported: chemical synthesis of hydroxytrihydroborate and peroxynitrite; the reduction of organic compounds with the hydroxyborohydride ion; and a kinetic study of the hydrolysis of the octahydrotriborate ions. (LK)

  1. Ion aggregation in high salt solutions. VII. The effect of cations on the structures of ion aggregates and water hydrogen-bonding network

    Science.gov (United States)

    Choi, Jun-Ho; Choi, Hyung Ran; Jeon, Jonggu; Cho, Minhaeng

    2017-10-01

    Ions in high salt solutions have a strong propensity to form polydisperse ion aggregates with broad size and shape distributions. In a series of previous comparative investigations using femtosecond IR pump-probe spectroscopy, molecular dynamics simulation, and graph theoretical analysis, we have shown that there exists a morphological difference in the structures of ion aggregates formed in various salt solutions. As salt concentration increases, the ions in high salt solutions form either cluster-like structures excluding water molecules or network-like structures entwined with water hydrogen-bonding networks. Interestingly, such morphological characteristics of the ion aggregates have been found to be in correlation with the solubility limits of salts. An important question that still remains unexplored is why certain salts with different cations have notably different solubility limits in water. Here, carrying out a series of molecular dynamics simulations of aqueous salt solutions and analyzing the distributions and connectivity patterns of ion aggregates with a spectral graph analysis method, we establish the relationship between the salt solubility and the ion aggregate morphology with a special emphasis on the cationic effects on water structures and ion aggregation. We anticipate that the understanding of large scale ion aggregate structures revealed in this study will be critical for elucidating the specific ion effects on the solubility and conformational stability of co-solute molecules such as proteins in water.

  2. Ion heat transport studies in JET

    DEFF Research Database (Denmark)

    Mantica, P; Angioni, C; Baiocchi, B

    2011-01-01

    Detailed experimental studies of ion heat transport have been carried out in JET exploiting the upgrade of active charge exchange spectroscopy and the availability of multi-frequency ion cyclotron resonance heating with 3He minority. The determination of ion temperature gradient (ITG) threshold a...

  3. Optimization of artificial neural networks used for retention modelling in ion chromatography.

    Science.gov (United States)

    Srecnik, Goran; Debeljak, Zeljko; Cerjan-Stefanović, Stefica; Novic, Milko; Bolancab, Tomislav

    2002-10-11

    The aim of this work is the development of an artificial neural network model, which can be generalized and used in a variety of applications for retention modelling in ion chromatography. Influences of eluent flow-rate and concentration of eluent anion (OH-) on separation of seven inorganic anions (fluoride, chloride, nitrite, sulfate, bromide, nitrate, and phosphate) were investigated. Parallel prediction of retention times of seven inorganic anions by using one artificial neural network was applied. MATLAB Neural Networks ToolBox was not adequate for application to retention modelling in this particular case. Therefore the authors adopted it for retention modelling by programming in MATLAB metalanguage. The following routines were written; the division of experimental data set on training and test set; selection of data for training and test set; Dixon's outlier test; retraining procedure routine; calculations of relative error. A three-layer feed forward neural network trained with a Levenberg-Marquardt batch error back propagation algorithm has been used to model ion chromatographic retention mechanisms. The advantage of applied batch training methodology is the significant increase in speed of calculation of algorithms in comparison with delta rule training methodology. The technique of experimental data selection for training set was used allowing improvement of artificial neural network prediction power. Experimental design space was divided into 8-32 subspaces depending on number of experimental data points used for training set. The number of hidden layer nodes, the number of iteration steps and the number of experimental data points used for training set were optimized. This study presents the very fast (300 iteration steps) and very accurate (relative error of 0.88%) retention model, obtained by using a small amount of experimental data (16 experimental data points in training set). This indicates that the method of choice for retention modelling in ion

  4. Selective removal of heavy metal ions by disulfide linked polymer networks

    Energy Technology Data Exchange (ETDEWEB)

    Ko, Dongah [Department of Environmental Engineering, Technical University of Denmark, Miljøvej 113, 2800 Kgs. Lyngby (Denmark); Lee, Joo Sung [Graduate School of EEWS, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141 (Korea, Republic of); Patel, Hasmukh A. [Department of Chemistry, Northwestern University, Evanston, IL 60208 (United States); Jakobsen, Mogens H. [Department of Micro and Nano technology, Technical University of Denmark, Ørsteds Plads, 345B, 2800 Kgs. Lyngby (Denmark); Hwang, Yuhoon [Department of Environmental Engineering, Seoul National University of Science and Technology, 232 Gongreung-ro, Nowon-gu, Seoul 01811 (Korea, Republic of); Yavuz, Cafer T. [Graduate School of EEWS, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141 (Korea, Republic of); Hansen, Hans Chr. Bruun [Department of Plant and Environmental Sciences, University of Copenhagen, Frederiksberg, Thorvaldsensvej 40, 1871 Frederiksberg C (Denmark); Andersen, Henrik R., E-mail: henrik@ndersen.net [Department of Environmental Engineering, Technical University of Denmark, Miljøvej 113, 2800 Kgs. Lyngby (Denmark)

    2017-06-15

    Highlights: • Disulfide/thiol polymer networks are promising as sorbent for heavy metals. • Rapid sorption and high Langmuir affinity constant (a{sub L}) for stormwater treatment. • Selective sorption for copper, cadmium, and zinc in the presence of calcium. • Reusability likely due to structure stability of disulfide linked polymer networks. - Abstract: Heavy metal contaminated surface water is one of the oldest pollution problems, which is critical to ecosystems and human health. We devised disulfide linked polymer networks and employed as a sorbent for removing heavy metal ions from contaminated water. Although the polymer network material has a moderate surface area, it demonstrated cadmium removal efficiency equivalent to highly porous activated carbon while it showed 16 times faster sorption kinetics compared to activated carbon, owing to the high affinity of cadmium towards disulfide and thiol functionality in the polymer network. The metal sorption mechanism on polymer network was studied by sorption kinetics, effect of pH, and metal complexation. We observed that the metal ions–copper, cadmium, and zinc showed high binding affinity in polymer network, even in the presence of competing cations like calcium in water.

  5. INFRARED AND RAMAN SPECTROSCOPIC STUDY OF ION ...

    African Journals Online (AJOL)

    Infrared and Raman spectroscopy techniques have been used to study the ionic interactions of strontium(II) and barium(II) with thiocyanate ion in liquid ammonia. A number of bands were observed in both n (CN) and n (CS) regions of infrared and Raman spectra and these were assigned to 1:1 contact ion pair, ...

  6. To Break or to Brake Neuronal Network Accelerated by Ammonium Ions?

    Directory of Open Access Journals (Sweden)

    Vladimir V Dynnik

    Full Text Available The aim of present study was to investigate the effects of ammonium ions on in vitro neuronal network activity and to search alternative methods of acute ammonia neurotoxicity prevention.Rat hippocampal neuronal and astrocytes co-cultures in vitro, fluorescent microscopy and perforated patch clamp were used to monitor the changes in intracellular Ca2+- and membrane potential produced by ammonium ions and various modulators in the cells implicated in neural networks.Low concentrations of NH4Cl (0.1-4 mM produce short temporal effects on network activity. Application of 5-8 mM NH4Cl: invariably transforms diverse network firing regimen to identical burst patterns, characterized by substantial neuronal membrane depolarization at plateau phase of potential and high-amplitude Ca2+-oscillations; raises frequency and average for period of oscillations Ca2+-level in all cells implicated in network; results in the appearance of group of «run out» cells with high intracellular Ca2+ and steadily diminished amplitudes of oscillations; increases astrocyte Ca2+-signalling, characterized by the appearance of groups of cells with increased intracellular Ca2+-level and/or chaotic Ca2+-oscillations. Accelerated network activity may be suppressed by the blockade of NMDA or AMPA/kainate-receptors or by overactivation of AMPA/kainite-receptors. Ammonia still activate neuronal firing in the presence of GABA(A receptors antagonist bicuculline, indicating that «disinhibition phenomenon» is not implicated in the mechanisms of networks acceleration. Network activity may also be slowed down by glycine, agonists of metabotropic inhibitory receptors, betaine, L-carnitine, L-arginine, etc.Obtained results demonstrate that ammonium ions accelerate neuronal networks firing, implicating ionotropic glutamate receptors, having preserved the activities of group of inhibitory ionotropic and metabotropic receptors. This may mean, that ammonia neurotoxicity might be prevented by

  7. To Break or to Brake Neuronal Network Accelerated by Ammonium Ions?

    Science.gov (United States)

    Dynnik, Vladimir V.; Kononov, Alexey V.; Sergeev, Alexander I.; Teplov, Iliya Y.; Tankanag, Arina V.; Zinchenko, Valery P.

    2015-01-01

    Purpose The aim of present study was to investigate the effects of ammonium ions on in vitro neuronal network activity and to search alternative methods of acute ammonia neurotoxicity prevention. Methods Rat hippocampal neuronal and astrocytes co-cultures in vitro, fluorescent microscopy and perforated patch clamp were used to monitor the changes in intracellular Ca2+- and membrane potential produced by ammonium ions and various modulators in the cells implicated in neural networks. Results Low concentrations of NH4Cl (0.1–4 mM) produce short temporal effects on network activity. Application of 5–8 mM NH4Cl: invariably transforms diverse network firing regimen to identical burst patterns, characterized by substantial neuronal membrane depolarization at plateau phase of potential and high-amplitude Ca2+-oscillations; raises frequency and average for period of oscillations Ca2+-level in all cells implicated in network; results in the appearance of group of «run out» cells with high intracellular Ca2+ and steadily diminished amplitudes of oscillations; increases astrocyte Ca2+-signalling, characterized by the appearance of groups of cells with increased intracellular Ca2+-level and/or chaotic Ca2+-oscillations. Accelerated network activity may be suppressed by the blockade of NMDA or AMPA/kainate-receptors or by overactivation of AMPA/kainite-receptors. Ammonia still activate neuronal firing in the presence of GABA(A) receptors antagonist bicuculline, indicating that «disinhibition phenomenon» is not implicated in the mechanisms of networks acceleration. Network activity may also be slowed down by glycine, agonists of metabotropic inhibitory receptors, betaine, L-carnitine, L-arginine, etc. Conclusions Obtained results demonstrate that ammonium ions accelerate neuronal networks firing, implicating ionotropic glutamate receptors, having preserved the activities of group of inhibitory ionotropic and metabotropic receptors. This may mean, that ammonia

  8. Study on Coulomb explosions of ion mixtures

    CERN Document Server

    Boella, E; D'Angola, A; Coppa, G; Silva, L O

    2015-01-01

    The paper presents a theoretical work on the dynamics of Coulomb explosion for spherical nanoplasmas composed by two different ion species. Particular attention has been dedicated to study the energy spectra of the ions with the larger charge-to-mass ratio. The connection between the formation of shock shells and the energy spread of the ions has been the object of a detailed analysis, showing that under particular conditions the width of the asymptotic energy spectrum tends to become very narrow, which leads to a multi-valued ion phase-space. The conditions to generate a quasi mono-energetic ion spectrum have been rigorously demonstrated and verifed by numerical simulations, using a technique that, exploiting the spherical symmetry of the problem, allows one to obtain very accurate and precise results.

  9. Dynamic State Transitions in the Nervous System: From Ion Channels to Neurons to Networks

    Science.gov (United States)

    Århem, Peter; Braun, Hans A.; Huber, Martin T.; Liljenström, Hans

    The following sections are included: * Introduction * Ion channels: The microscopic scale * The variety of ion channels * Channel kinetics * Neurons: The mesoscopic scale * The feedback loops between membrane potential and ion currents * Neuron models: Concepts and examples * Impulse pattern modulation by ion channel densities * Oscillatory patterns * Irregular patterns * Impulse pattern modulation by subthreshold oscillations * The cold receptor model * Deterministic patterns and noise induced state-transitions on temperature scaling * Neuronal networks: The oscopic scale * Random channel events cause network state transitions * A hippocampal neural network model * Simulating noise-induced state transitions * Functional significance of oscopic neurodynamics * Conclusions * Appendix A: Computation of the neuron models * Hippocampal neuron model * The cold receptor model * Appendix B: Neural network model * References

  10. Processing of signals from an ion-elective electrode array by a neural network

    NARCIS (Netherlands)

    Bos, M.; Bos, A.; van der Linden, W.E.

    1990-01-01

    Neural network software is described for processing the signals of arrays of ion-selective electrodes. The performance of the software was tested in the simultaneous determination of calcium and copper(II) ions in binary mixtures of copper(II) nitrate and calcium chloride and the simultaneous

  11. A model for phosphate glass topology considering the modifying ion sub-network

    DEFF Research Database (Denmark)

    Hermansen, Christian; Mauro, J.C.; Yue, Yuanzheng

    2014-01-01

    In the present paper we establish a temperature dependent constraint model of alkali phosphate glasses considering the structural and topological role of the modifying ion sub-network constituted by alkali ions and their non-bonding oxygen coordination spheres. The model is consistent with availa...

  12. Studying Dynamics in Business Networks

    DEFF Research Database (Denmark)

    Andersen, Poul Houman; Anderson, Helen; Havila, Virpi

    1998-01-01

    This paper develops a theory on network dynamics using the concepts of role and position from sociological theory. Moreover, the theory is further tested using case studies from Denmark and Finland......This paper develops a theory on network dynamics using the concepts of role and position from sociological theory. Moreover, the theory is further tested using case studies from Denmark and Finland...

  13. How Mg(2+) ion and water network affect the stability and structure of non-Watson-Crick base pairs in E. coli loop E of 5S rRNA: a molecular dynamics and reference interaction site model (RISM) study.

    Science.gov (United States)

    Shanker, Sudhanshu; Bandyopadhyay, Pradipta

    2017-08-01

    The non-Watson-Crick (non-WC) base pairs of Escherichia coli loop E of 5S rRNA are stabilized by Mg(2+) ions through water-mediated interaction. It is important to know the synergic role of Mg(2+) and the water network surrounding Mg(2+) in stabilizing the non-WC base pairs of RNA. For this purpose, free energy change of the system is calculated using molecular dynamics (MD) simulation as Mg(2+) is pulled from RNA, which causes disturbance of the water network. It was found that Mg(2+) remains hexahydrated unless it is close to or far from RNA. In the pentahydrated form, Mg(2+) interacts directly with RNA. Water network has been identified by two complimentary methods; MD followed by a density-based clustering algorithm and three-dimensional-reference interaction site model. These two methods gave similar results. Identification of water network around Mg(2+) and non-WC base pairs gives a clue to the strong effect of water network on the stability of this RNA. Based on sequence analysis of all Eubacteria 5s rRNA, we propose that hexahydrated Mg(2+) is an integral part of this RNA and geometry of base pairs surrounding it adjust to accommodate the [Formula: see text]. Overall the findings from this work can help in understanding the basis of the complex structure and stability of RNA with non-WC base pairs.

  14. Campus network security model study

    Science.gov (United States)

    Zhang, Yong-ku; Song, Li-ren

    2011-12-01

    Campus network security is growing importance, Design a very effective defense hacker attacks, viruses, data theft, and internal defense system, is the focus of the study in this paper. This paper compared the firewall; IDS based on the integrated, then design of a campus network security model, and detail the specific implementation principle.

  15. Networked Microgrids Scoping Study

    Energy Technology Data Exchange (ETDEWEB)

    Starke, Michael R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2016-10-01

    While the utilization of a microgrid for local power reliability during grid outage and emergencies is a well-known benefit, the integration of microgrids with the broader electrical distribution system will allow for seamless interaction with distribution system operations, contributing to resource and economic optimization, enhanced reliability and resiliency, and improved power quality. By virtue of integration with the distribution system, multiple microgrids should be networked and collectively known as networked microgrids. As a follow-up to the work conducted by Oak Ridge National Laboratory on a microgrid controller [the Complete System-level Efficient and Interoperable Solution for Microgrid Integrated Controls (CSEISMIC)], the main goal of this work is to identify the next steps for bringing microgrid research to the utility industry, particularly as a resource for enhancing efficiency, reliability, and resilience. Various R&D needs for the integration of microgrids into the distribution system have been proposed, including interconnection types, communications, control architectures, quantification of benefits, functional requirements, and various operational issues.

  16. Ion Suppression Study for Tetracyclines in Feed

    NARCIS (Netherlands)

    Chico, J.; Holthoon, van F.L.; Zuidema, T.

    2012-01-01

    Ion suppression in analysis of tetracyclines in feed was studied. The conventional analysis consists of a liquid extraction followed by a clean-up step using solid phase extraction (SPE) technique and analysis of the tetracyclines by liquid chromatography and mass spectrometric detection. Various

  17. Study of Light Ion Collisions

    CERN Multimedia

    2002-01-01

    Inelastic and elastic pd, dd, p@a and @a@a interactions are studied at a nucleon-nucleon cm energy @]s^n^n = 31~GeV using the Split-Field-Magnet detector. The two forward telescopes have been upgraded by two calorimeters to tag spectator neutrons and by two MWPCs for improved detection of charged nuclear fragments. Several selective triggers are planned in addition to the minimum-bias trigger: 1) high p^t single hadron at 10|0, 20|0 and 45|0; 2) central particle production together with unfragmented projectiles; 3) nuclear break-up without particle production; 4) elastic interactions. This experiment is an extension of the @a-run in 1980; the new one will benefit from the direct comparisons of @a@a, dd, @ap and dp interactions; from expected higher integrated luminosity for @a@a interactions; the upgrading of the spectator tagging capability and the new high p^t triggers installed by R41

  18. Structure simulation into a lamellar supramolecular network and calculation of the metal ions/ligands ratio

    Directory of Open Access Journals (Sweden)

    Visa Aurelia

    2012-08-01

    Full Text Available Abstract Background Research interest in phosphonates metal organic frameworks (MOF has increased extremely in the last two decades, because of theirs fascinating and complex topology and structural flexibility. In this paper we present a mathematical model for ligand/metal ion ratio of an octahedral (Oh network of cobalt vinylphosphonate (Co(vP·H2O. Results A recurrent relationship of the ratio between the number of ligands and the number of metal ions in a lamellar octahedral (Oh network Co(vP·H2O, has been deducted by building the 3D network step by step using HyperChem 7.52 package. The mathematical relationship has been validated using X ray analysis, experimental thermogravimetric and elemental analysis data. Conclusions Based on deducted recurrence relationship, we can conclude prior to perform X ray analysis, that in the case of a thermogravimetric analysis pointing a ratio between the number of metal ions and ligands number around 1, the 3D network will have a central metal ion that corresponds to a single ligand. This relation is valid for every type of supramolecular network with divalent metal central ion Oh coordinated and bring valuable information with low effort and cost.

  19. Network type sp3 boron-based single-ion conducting polymer electrolytes for lithium ion batteries

    Science.gov (United States)

    Deng, Kuirong; Wang, Shuanjin; Ren, Shan; Han, Dongmei; Xiao, Min; Meng, Yuezhong

    2017-08-01

    Electrolytes play a vital role in modulating lithium ion battery performance. An outstanding electrolyte should possess both high ionic conductivity and unity lithium ion transference number. Here, we present a facile method to fabricate a network type sp3 boron-based single-ion conducting polymer electrolyte (SIPE) with high ionic conductivity and lithium ion transference number approaching unity. The SIPE was synthesized by coupling of lithium bis(allylmalonato)borate (LiBAMB) and pentaerythritol tetrakis(2-mercaptoacetate) (PETMP) via one-step photoinitiated in situ thiol-ene click reaction in plasticizers. Influence of kinds and content of plasticizers was investigated and the optimized electrolytes show both outstanding ionic conductivity (1.47 × 10-3 S cm-1 at 25 °C) and high lithium transference number of 0.89. This ionic conductivity is among the highest ionic conductivity exhibited by SIPEs reported to date. Its electrochemical stability window is up to 5.2 V. More importantly, Li/LiFePO4 cells with the prepared single-ion conducting electrolytes as the electrolyte as well as the separator display highly reversible capacity and excellent rate capacity under room temperature. It also demonstrates excellent long-term stability and reliability as it maintains capacity of 124 mA h g-1 at 1 C rate even after 500 cycles without obvious decay.

  20. Topological Origin of the Network Dilation Anomaly in Ion-Exchanged Glasses

    Science.gov (United States)

    Wang, Mengyi; Smedskjaer, Morten M.; Mauro, John C.; Sant, Gaurav; Bauchy, Mathieu

    2017-11-01

    Ion exchange is commonly used to strengthen oxide glasses. However, the resulting stuffed glasses usually do not reach the molar volume of as-melted glasses of similar composition—a phenomenon known as the network dilation anomaly. This behavior seriously limits the potential for the chemical strengthening of glasses and its origin remains one of the mysteries of glass science. Here, based on molecular dynamics simulations of sodium silicate glasses coupled with topological constraint theory, we show that the topology of the atomic network controls the extent of ion-exchange-induced dilation. We demonstrate that isostatic glasses do not show any network dilation anomaly. This is found to arise from the combined absence of floppy modes of deformation and internal eigenstress in isostatic atomic networks.

  1. Ion pair reinforced semi-interpenetrating polymer network for direct methanol fuel cell applications.

    Science.gov (United States)

    Fang, Chunliu; Julius, David; Tay, Siok Wei; Hong, Liang; Lee, Jim Yang

    2012-06-07

    This paper describes the synthesis of ion-pair-reinforced semi-interpenetrating polymer networks (SIPNs) as proton exchange membranes (PEMs) for the direct methanol fuel cells (DMFCs). Specifically, sulfonated poly(2,6-dimethyl-1,4-phenylene oxide) (SPPO), a linear polymer proton source, was immobilized in a brominated PPO (BPPO) network covalently cross-linked by ethylenediamine (EDA). The immobilization of SPPO in the SIPN network was accomplished not only by the usual means of mechanical interlocking but also by ion pair formation between the sulfonic acid groups of SPPO and the amine moieties formed during the cross-linking reaction of BPPO with EDA. Through the ion pair interactions, the immobilization of SPPO polymer in the BPPO network was made more effective, resulting in a greater uniformity of sulfonic acid cluster distribution in the membrane. The hydrophilic amine-containing cross-links also compensated for some of the decrease in proton conductivity caused by ion pair formation. The SIPN membranes prepared as such showed good proton conductivity, low methanol permeability, good mechanical properties, and dimensional stability. Consequently, the PPO based SIPN membranes were able to deliver a higher maximum power density than Nafion, demonstrating the potential of the SIPN structure for PEM designs.

  2. An ion gun and detector system for ion drift surface studies on toroidal devices

    Science.gov (United States)

    Sasser, G. E.; Knowlton, S. F.; Gandy, R. F.; Lin, H.; Thomas, E. E.; Owens, M. A.

    1995-01-01

    An ion gun and detector system have been designed and tested to study energetic ion trajectories and single-particle confinement in the vacuum field and low-density plasma of the Compact Auburn Torsatron (CAT). Thermionic Li+ and Mg+ sources are used. The gun positioning is capable of two degrees of freedom, allowing selection of the pitch angle and initial flux surface. The injection energy of the ions is variable from 5 to 100 eV, allowing investigation of the orbits of particles with large Larmor radii. The ion currents of typical magnitude I=10 nA are detected with a movable paddle probe making use of a boxcar-averaging technique. The detected ion trajectories are compared with the predicted trajectories from a guiding center code that makes use of a detailed model of the CAT magnetic configuration. The ion gun and detector system will be used to study the effect of magnetic islands on energetic ion trajectories.

  3. Studies of defects on ion irradiated diamond

    Energy Technology Data Exchange (ETDEWEB)

    Lai, P.F.; Prawer, S.; Spargo, A.E.C.; Bursill, L.A. [Melbourne Univ., Parkville, VIC (Australia). School of Physics

    1996-12-31

    It is known that diamond is amorphized or graphitized when irradiated above a critical dose. Above this critical dose, D{sub c}, the resistance R is found to drop very rapidly due to the formation of graphite regions which overlap at D{sub c} to form a semi-continuous electrically conducting pathway through the sample. One particularly interesting method of studying this transformation is electron energy-loss spectroscopy (EELS). Using EELS, the different phases of carbon can be identified and distinguished from each other using the extended energy-loss fine structure (EXELFS) of the core-loss part of the spectrum. EELS is a sensitive method for determining the electronic structure of small areas of a sample. In this paper, transmission electron microscopy (TEM) and EELS measurements of the ion irradiated diamond were combined in an attempt to correlate the microstructural nature of the ion-beam induced damage to the changes in the electrical and other properties. 7 refs., 1 tab., 2 figs.

  4. OGO 6 ion concentration irregularity studies

    Science.gov (United States)

    Mcclure, J. P.

    1973-01-01

    Research is reported concerning the ionospheric F-region irregularities. The results are based on in-situ OGO-6 measurements of the total ion concentration N sub i. A proposed mechanism for the generation of equatorial F-region irregularities and the morphological results, and the occurrence of Fe(+) ions in the equatorial F-region are discussed. Related research papers are included.

  5. Evaluation of Pore Networks in Caprocks at Geologic Storage Sites: A Combined Study using High Temperature and Pressure Reaction Experiments, Small Angle Neutron Scattering, and Focused Ion Beam-Scanning Electron Microscopy

    Science.gov (United States)

    Mouzakis, K. M.; Sitchler, A.; Wang, X.; McCray, J. E.; Kaszuba, J. P.; Rother, G.; Dewers, T. A.; Heath, J. E.

    2011-12-01

    Low permeability rock units, often shales or mudstones, that overlie geologic formations under consideration for CO2 sequestration will help contain injected CO2. CO2 that does flow through these rocks will dissolve into the porewaters, creating carbonic acid lowering the pH. This perturbation of the system may result in mineral dissolution or precipitation, which can change the pore structure and impact the flow properties of the caprocks. In order to investigate the impacts that reaction can have on caprock pore structure, we performed a combination of high pressure high temperature reaction experiments, small angle neutron scattering (SANS) experiments and high resolution focused ion beam-scanning electron microscope (FIB-SEM) imaging on samples from the Gothic shale and Marine Tuscaloosa Group. Small angle neutron scattering was performed on unreacted and reacted caprocks at the High Flux Isotope Reactor at Oak Ridge National Laboratory. New precipitates and pores are observed in high-resolution images of the reacted samples. The precipitates have been preliminarily identified as gypsum or anhydrite, and sulfide minerals. Results from small angle neutron scattering, a technique that provides information about pores and pore/mineral interfaces at scales ~ 5 to 300 nm, show an increased porosity and specific surface area after reaction with brine and CO2. However, there appear to be differences in how the pore networks change between the two samples that are related to sample mineralogy and original pore network structure. Changes to pores and formation of new pores may lead to different capillary sealing behavior and permeability. This combination of controlled laboratory experiments, neutron scattering and high-resolution imaging provides detailed information about the geochemical processes that occur at the pore scale as CO2 reacts with rocks underground. Such information is integral to the evaluation of large-scale CO2 sequestration as a feasible technology

  6. Neutralized ion beam modification of cellulose membranes for study of ion charge effect on ion-beam-induced DNA transfer

    Energy Technology Data Exchange (ETDEWEB)

    Prakrajang, K., E-mail: k.prakrajang@gmail.com [Plasma and Beam Physics Research Facility, Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Sangwijit, K.; Anuntalabhochai, S. [Molecular Biology Laboratory, Department of Biology, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Wanichapichart, P. [Membrane Science and Technology Research Center, Department of Physics, Faculty of Science, Prince of Songkla University, Hat Yai, Songkla 90110 (Thailand); Thailand Center of Excellence in Physics, Commission on Higher Education, 328 Si Ayutthaya Road, Bangkok 10400 (Thailand); Yu, L.D., E-mail: yuld@fnrf.science.cmu.ac.th [Plasma and Beam Physics Research Facility, Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand); Thailand Center of Excellence in Physics, Commission on Higher Education, 328 Si Ayutthaya Road, Bangkok 10400 (Thailand)

    2012-02-01

    Low-energy ion beam biotechnology (IBBT) has recently been rapidly developed worldwide. Ion-beam-induced DNA transfer is one of the important applications of IBBT. However, mechanisms involved in this application are not yet well understood. In this study plasma-neutralized ion beam was applied to investigate ion charge effect on induction of DNA transfer. Argon ion beam at 7.5 keV was neutralized by RF-driven plasma in the beam path and then bombarded cellulose membranes which were used as the mimetic plant cell envelope. Electrical properties such as impedance and capacitance of the membranes were measured after the bombardment. An in vitro experiment on plasmid DNA transfer through the cellulose membrane was followed up. The results showed that the ion charge input played an important role in the impedance and capacitance changes which would affect DNA transfer. Generally speaking, neutral particle beam bombardment of biologic cells was more effective in inducing DNA transfer than charged ion beam bombardment.

  7. Semi-Interpenetrating Polymer Networks with Predefined Architecture for Metal Ion Fluorescence Monitoring

    Directory of Open Access Journals (Sweden)

    Kyriakos Christodoulou

    2016-11-01

    Full Text Available The development of new synthetic approaches for the preparation of efficient 3D luminescent chemosensors for transition metal ions receives considerable attention nowadays, owing to the key role of the latter as elements in biological systems and their harmful environmental effects when present in aquatic media. In this work, we describe an easy and versatile synthetic methodology that leads to the generation of nonconjugated 3D luminescent semi-interpenetrating amphiphilic networks (semi-IPN with structure-defined characteristics. More precisely, the synthesis involves the encapsulation of well-defined poly(9-anthrylmethyl methacrylate (pAnMMA (hydrophobic, luminescent linear polymer chains within a covalent poly(2-(dimethylaminoethyl methacrylate (pDMAEMA hydrophilic polymer network, derived via the 1,2-bis-(2-iodoethoxyethane (BIEE-induced crosslinking process of well-defined pDMAEMA linear chains. Characterization of their fluorescence properties demonstrated that these materials act as strong blue emitters when exposed to UV irradiation. This, combined with the presence of the metal-binding tertiary amino functionalities of the pDMAEMA segments, allowed for their applicability as sorbents and fluorescence chemosensors for transition metal ions (Fe3+, Cu2+ in solution via a chelation-enhanced fluorescence-quenching effect promoted within the semi-IPN network architecture. Ethylenediaminetetraacetic acid (EDTA-induced metal ion desorption and thus material recyclability has been also demonstrated.

  8. Dilepton Production In Ion-Ion Collisions Studied Using HADES

    Science.gov (United States)

    Kugler, A.; Agakichiev, H.; Agodi, C.; Alvarez-Pol, H.; Balanda, A.; Bellia, G.; Bertini, D.; Bielcik, J.; Böhmer, M.; Bokemeyer, H.; Boyard, J. L.; Braun-Munzinger, P.; Cabanelas, P.; Chernenko, S.; Christ, T.; Coniglione, R.; Cosentino, L.; Diaz, J.; Dohrmann, F.; Duran, I.; Eberl, Th.; Enghardt, W.; Fabbietti, L.; Fateev, O.; Fernandez, C.; Finocchiaro, P.; Friese, J.; Fröhlich, I.; Fuentes, B.; Garabatos, C.; Garzon, J. A.; Gernhäuser, R.; Gilardi, C.; Golubeva, M.; Gonzales-Diaz, D.; Grosse, E.; Guber, F.; Hennino, Th.; Hlavac, S.; Holzmann, R.; Homolka, J.; Ierusalimov, A.; Iori, I.; Ivashkin, A.; Jaskula, M.; Jurkovic, M.; Kagarlis, M.; Kajetanowicz, M.; Kämpfer, B.; Kanaki, K.; Karavicheva, T.; Kastenmüller, A.; Kidon, L.; Kienle, P.; Koenig, I.; Koenig, W.; Körner, H.-J.; Kolb, B. W.; Kotte, R.; Krizek, F.; Krücken, R.; Kühn, W.; Kulessa, R.; Kurepin, A.; Lang, S.; Lange, S.; Lehnert, J.; Lins, E.; Magestro, D.; Maiolino, C.; Malarz, A.; Markert, J.; Metag, V.; Mousa, J.; Münch, M.; Müntz, C.; Naumann, L.; Nekhaev, A.; Novotny, R.; Otwinowski, J.; Pachmayer, Y. C.; Pechenov, V.; Perez, T.; Piattelli, P.; Pietraszko, J.; Pleskac, R.; Ploskon, M.; Pospisil, V.; Prokopowicz, W.; Przygoda, W.; Ramstein, B.; Reshetin, A.; Ritman, J.; Roy-Stephan, M.; Rustamov, A.; Sadovski, A.; Sailer, B.; Salabura, P.; Sanchez, M.; Sapienza, P.; Schmah, A.; Schön, H.; Schroeder, C.; Schwab, E.; Simon, R.; Smoliankin, V.; Smykov, L.; Spataro, S.; Spruck, B.; Ströbele, H.; Stroth, J.; Sturm, C.; Sudol, M.; Taranenko, A.; Tlusty, P.; Toia, A.; Traxler, M.; Tsertos, H.; Turzo, I.; Vassiliev, D.; Vazquez, A.; Wagner, V.; Walus, W.; Wiśniowski, M.; Wojcik, T.; Wüstenfeld, J.; Zanevsky, Yu.; Zeitelhack, K.; Zovinec, D.; Zumbruch, P.

    2007-10-01

    The High-Acceptance Di-Electron Spectrometer installed at GSI Darmstadt is a second generation experiment to study production of dielectron pairs from proton, pion and nucleus induced reactions at the SIS/BEVALAC energy regime. During period 2002-4 medium-resolution data have been taken with HADES on the light C+C system at 1 and 2 AGeV. The data analysis confirms former finding of the DLS collaboration. First physics run on slightly heavier system Ar+KCl was carried out will almost full HADES setup at 2005.

  9. Enhanced electron/fuel-ion equilibration through impurity ions: Studies applicable to NIF and Omega

    Science.gov (United States)

    Petrasso, R. D.; Sio, H.; Kabadi, N.; Lahmann, B.; Simpson, R.; Parker, C.; Frenje, J.; Gatu Johnson, M.; Li, C. K.; Seguin, F. H.; Rinderknecht, H.; Casey, D.; Grabowski, P.; Graziani, F.; Taitano, W.; Le, A.; Chacon, L.; Hoffman, N.; Kagan, G.; Simakov, A.; Zylstra, A.; Rosenberg, M.; Betti, R.; Srinivasan, B.; Mancini, R.

    2017-10-01

    In shock-driven exploding-pushers, a platform used extensively to study multi-species and kinetic effects, electrons and fuel ions are far out of equilibrium, as reflected by very different temperatures. However, impurity ions, even in small quantities, can couple effectively to the electrons, because of a Z2 dependence, and in turn, impurity ions can then strongly couple to the fuel ions. Through this mechanism, electrons and fuel-ions can equilibrate much faster than they otherwise would. This is a quantitative issue, depending upon the amount and Z of the impurity. For NIF and Omega, we consider the role of this process. Coupled non-linear equations, reflecting the temperatures of the three species, are solved for a range of conditions. Consideration is also given to ablatively driven implosions, since impurities can similarly affect the equilibration. This work was supported in part by DOE/NNSA DE-NA0002949 and DE-NA0002726.

  10. Network management systems for active distribution networks. A feasibility study

    Energy Technology Data Exchange (ETDEWEB)

    Roberts, D.A.

    2004-07-01

    A technical feasibility study on network management systems for active distribution networks is reported. The study investigated the potential for modifying a Distribution Network Operator (DNO) Supervisory Control and Data Acquisition System (SCADA) to give some degree of active management. Government incentives have encouraged more and more embedded generation being connected to the UK distribution networks and further acceleration of the process should support the 2010 target for a reduction in emissions of carbon dioxide. The report lists the objectives of the study and summarises what has been achieved; it also discusses limitations, reliability and resilience of existing SCADA. Safety and operational communications are discussed under staff safety and operational safety. Recommendations that could facilitate active management through SCADA are listed, together with suggestions for further study. The work was carried out as part of the DTI New and Renewable Energy Programme managed by Future Energy Solutions.

  11. Fluoride ions vs removal technologies: A study

    Directory of Open Access Journals (Sweden)

    Jagvir Singh

    2016-11-01

    Full Text Available Literature reported that drinking water is a precious and scarce resource and it has to be protected and kept free from any kind of contamination. Further, it has to be used carefully without wasting. Literature also reported that fluoride bearing rocks are abundant in India, as a result, fluoride leaches out and contaminates the adjacent water and soil resources. A high concentration of fluoride ions in ground water increases up to more than 30 mg/L. This high concentration of fluoride ions causes many harmful and dangerous effects on our datum. Fluoride ions in larger quantities i.e. 20–80 mg/day taken over a period of 10–20 years result in crippling and skeletal fluorosis, severely damaging the bone. In the present scenario, there is a continuously increasing worldwide concern for the development of fluoride treatment technologies. Possibilities of reducing the high fluorine content in groundwater are by defluorination process/dilution with the surface water which is a very simple technique but the addition of Ca2+ ions to a solution in contact with fluorite when experimented in distilled water caused an appreciable decrease in fluoride concentration. In this review article, we emphasized the relationship between high concentrations of fluoride ions and their compounds and their health impact.

  12. Ion beam analysis techniques applied to large scale pollution studies

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, D.D.; Bailey, G.; Martin, J.; Garton, D.; Noorman, H.; Stelcer, E.; Johnson, P. [Australian Nuclear Science and Technology Organisation, Lucas Heights, NSW (Australia)

    1993-12-31

    Ion Beam Analysis (IBA) techniques are ideally suited to analyse the thousands of filter papers a year that may originate from a large scale aerosol sampling network. They are fast multi-elemental and, for the most part, non-destructive so other analytical methods such as neutron activation and ion chromatography can be performed afterwards. ANSTO in collaboration with the NSW EPA, Pacific Power and the Universities of NSW and Macquarie has established a large area fine aerosol sampling network covering nearly 80,000 square kilometres of NSW with 25 fine particle samplers. This network known as ASP was funded by the Energy Research and Development Corporation (ERDC) and commenced sampling on 1 July 1991. The cyclone sampler at each site has a 2.5 {mu}m particle diameter cut off and runs for 24 hours every Sunday and Wednesday using one Gillman 25mm diameter stretched Teflon filter for each day. These filters are ideal targets for ion beam analysis work. Currently ANSTO receives 300 filters per month from this network for analysis using its accelerator based ion beam techniques on the 3 MV Van de Graaff accelerator. One week a month of accelerator time is dedicated to this analysis. Four simultaneous accelerator based IBA techniques are used at ANSTO, to analyse for the following 24 elements: H, C, N, O, F, Na, Al, Si, P, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Cu, Ni, Co, Zn, Br and Pb. The IBA techniques were proved invaluable in identifying sources of fine particles and their spatial and seasonal variations accross the large area sampled by the ASP network. 3 figs.

  13. Study on space charge compensation in negative hydrogen ion beam

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, A. L.; Chen, J. E. [University of Chinese Academy of Sciences, Beijing 100049 (China); State Key Laboratory of Nuclear Physics and Technology, Institute of Heavy Ion Physics, School of Physics, Peking University, Beijing 100871 (China); Peng, S. X., E-mail: sxpeng@pku.edu.cn; Ren, H. T.; Zhang, T.; Zhang, J. F.; Xu, Y.; Guo, Z. Y. [State Key Laboratory of Nuclear Physics and Technology, Institute of Heavy Ion Physics, School of Physics, Peking University, Beijing 100871 (China)

    2016-02-15

    Negative hydrogen ion beam can be compensated by the trapping of ions into the beam potential. When the beam propagates through a neutral gas, these ions arise due to gas ionization by the beam ions. However, the high neutral gas pressure may cause serious negative hydrogen ion beam loss, while low neutral gas pressure may lead to ion-ion instability and decompensation. To better understand the space charge compensation processes within a negative hydrogen beam, experimental study and numerical simulation were carried out at Peking University (PKU). The simulation code for negative hydrogen ion beam is improved from a 2D particle-in-cell-Monte Carlo collision code which has been successfully applied to H{sup +} beam compensated with Ar gas. Impacts among ions, electrons, and neutral gases in negative hydrogen beam compensation processes are carefully treated. The results of the beam simulations were compared with current and emittance measurements of an H{sup −} beam from a 2.45 GHz microwave driven H{sup −} ion source in PKU. Compensation gas was injected directly into the beam transport region to modify the space charge compensation degree. The experimental results were in good agreement with the simulation results.

  14. Experimental Study on Effect of Electrode Location on Ion Current

    Directory of Open Access Journals (Sweden)

    Xu Hanqing

    2017-01-01

    Full Text Available In an attempt to use ion current method on a suction flame holder for combustion diagnosis, the position of the detection electrode that has the significant effect on ion current, should be investigated. The objective of this study was to experimentally investigate the ion current distribution in different combustion zones by changing the electrode length and streamwise location. An ion current acquisition system was built on basis of the principle of Langmuir probe, and experiments were conducted under different fuel-air ratios ranging from 0.008~0.022. The results suggest that the ion current distribution obeys the same regulation at different fuel-air ratios. With the electrode length increasing, the ion current increases first, then decreases, and finally presents a unimodal curve. As the electrode streamwise location increases, the ion current demonstrates a linear decrease rule. The maximum ion current is obtained in the case that the electrode length and streamwise location equals 60mm and 0.75. Since the larger ion current provides the wider range for setting the misfire threshold, the position where the maximum ion current occurs can be a better choice for arranging the electrode.

  15. Study on actinoid isolation by antimonide ion exchanger

    Energy Technology Data Exchange (ETDEWEB)

    Tsuji, Masamichi [Tokyo Inst. of Tech. (Japan). Faculty of Science; Kubota, Masumitsu; Yamagishi, Isao

    1996-01-01

    To establish a containment of long-life nuclides and an effective reduction of waste volume is important to reduce the loadings on the natural environment. Chemical isolation of radioactive nuclides from wastes was attempted by using inorganic ion exchanger with high specificity and thermal stability. In this study, titanium antimonide was used as an ion exchanger to investigate the adsorption of trivalent metallic ions according to Kielland plot curves. When the ionic equivalent fraction (X-bar{sub M}) was around 0.005, Kielland plot curve of either of 3-valent metallic ions was bent, suggesting the exchanger had two different adsorption sites. The slope of the curve became smaller as an elevation of temperature. These results show that the ion radius was decreased resulting from partial elimination of the hydrated water of ion and thus, the steric conditions around the exchange site might be improved. (M.N.)

  16. Ion beam production and study of radioactive isotopes with the laser ion source at ISOLDE

    Science.gov (United States)

    Fedosseev, Valentin; Chrysalidis, Katerina; Day Goodacre, Thomas; Marsh, Bruce; Rothe, Sebastian; Seiffert, Christoph; Wendt, Klaus

    2017-08-01

    At ISOLDE the majority of radioactive ion beams are produced using the resonance ionization laser ion source (RILIS). This ion source is based on resonant excitation of atomic transitions by wavelength tunable laser radiation. Since its installation at the ISOLDE facility in 1994, the RILIS laser setup has been developed into a versatile remotely operated laser system comprising state-of-the-art solid state and dye lasers capable of generating multiple high quality laser beams at any wavelength in the range of 210-950 nm. A continuous programme of atomic ionization scheme development at CERN and at other laboratories has gradually increased the number of RILIS-ionized elements. At present, isotopes of 40 different elements have been selectively laser-ionized by the ISOLDE RILIS. Studies related to the optimization of the laser-atom interaction environment have yielded new laser ion source types: the laser ion source and trap and the versatile arc discharge and laser ion source. Depending on the specific experimental requirements for beam purity or versatility to switch between different ionization mechanisms, these may offer a favourable alternative to the standard hot metal cavity configuration. In addition to its main purpose of ion beam production, the RILIS is used for laser spectroscopy of radioisotopes. In an ongoing experimental campaign the isotope shifts and hyperfine structure of long isotopic chains have been measured by the extremely sensitive in-source laser spectroscopy method. The studies performed in the lead region were focused on nuclear deformation and shape coexistence effects around the closed proton shell Z = 82. The paper describes the functional principles of the RILIS, the current status of the laser system and demonstrated capabilities for the production of different ion beams including the high-resolution studies of short-lived isotopes and other applications of RILIS lasers for ISOLDE experiments. This article belongs to the Focus on

  17. Studying mechanosensitive ion channels with an automated patch clamp

    NARCIS (Netherlands)

    Barthmes, Maria; Jose, Mac Donald F; Birkner, Jan Peter; Brüggemann, Andrea; Wahl-Schott, Christian; Kocer, Armagan

    Patch clamp electrophysiology is the main technique to study mechanosensitive ion channels (MSCs), however, conventional patch clamping is laborious and success and output depends on the skills of the operator. Even though automated patch systems solve these problems for other ion channels, they

  18. Synthesis, characterization and ion recognition studies of lower rim ...

    Indian Academy of Sciences (India)

    An amido-linked rhodamine conjugate of calix[4]arene, L has been synthesized and characterized. Metal ion recognition properties of L have been studied by emission and absorption techniques with 14 different metal ions including the transition ones. Results show that, L exhibits ratiometric emission intensity towards ...

  19. Advanced applications of ion channeling for the study of imperfections in crystals

    Energy Technology Data Exchange (ETDEWEB)

    Swanson, M.L. [North Carolina Univ., Chapel Hill, NC (United States)

    1997-03-01

    A review will be given of the applications of medium energy ion channeling for the studies of imperfections in the near-surface regions of crystals. The following topics will be discussed: (1.) epitaxial layers, including elemental depositions of a few monolayers, strained-layer superlattices, and compound layers; (2.) lattice defects, including ion damage in diamond, dislocation networks in Si, and anomalous lattice vibrations in high temperature superconductors; (3.) lattice sites of solute atoms, including substitutional sites in compounds (LiNbO{sub 3} and GaP), and interstitial sites produced by association with point defects. (author)

  20. A Study of Single Pass Ion Effects at the ALS

    Energy Technology Data Exchange (ETDEWEB)

    Byrd, J.M.; Thomson, J.; /LBL, Berkeley; Chao, A.W.; Heifets, S.; Minty, M.G.; Seeman, J.T.; Stupakov, G.V.; Zimmermann, F.; /SLAC; Raubenheimer, T.O.; /CERN

    2011-09-13

    We report the results of experiments on a 'fast beam-ion instability' at the Advanced Light Source (ALS). This ion instability, which can arise even when the ions are not trapped over multiple beam passages, will likely be important for many future accelerators. In our experiments, we filled the ALS storage ring with helium gas, raising the pressure approximately two orders of magnitude above the nominal pressure. With gaps in the bunch train large enough to avoid conventional (multi-turn) ion trapping, we observed a factor of 2-3 increase in the vertical beam size along with coherent beam oscillations which increased along the bunch train. Ion trapping has long been recognized as a potential limitation in electron storage rings. The ions, generated by beam-gas collisions, become trapped in the negative potential of the beam and accumulate over multiple beam passages. The trapped ions are then observed to cause a number of deleterious effects such as an increasing beam phase space, a broadening and shifting of the beam transverse oscillation frequencies (tunes), collective beam instabilities, and beam lifetime reductions. All of these effects are of concern for the next generation of accelerators, such as the B-factories or damping rings for future linear colliders, which will store high beam currents with closely spaced bunches and ultra-low beam emittances. One of the standard solutions used to prevent ion trapping is to include a gap in the bunch train which is long compared to the bunch spacing. In this case, the ions are first strongly-focused by the passing electron bunches and then over-focused in the gap. With a sufficiently large gap, the ions can be driven to large amplitudes where they form a diffuse halo and do not affect the beam. In this paper, we describe experiments that study a new regime of transient ion instabilities predicted to arise in future electron storage rings, and linacs with bunch trains. These future rings and linacs, which

  1. Effects of autapse and ion channel block on the collective firing activity of Newman-Watts small-world neuronal networks

    Science.gov (United States)

    Uzun, Rukiye; Yilmaz, Ergin; Ozer, Mahmut

    2017-11-01

    An autapse is a special kind of synapse established between the axon and dendrites of the same neuron. In the present study, we have investigated the cooperative effects of autapse and ion channel block on the collective firing regularity of Newman-Watts small-world networks of stochastic Hodgkin-Huxley neurons. We obtain autaptic time delay induced multi-coherence resonance (MCR) phenomenon in the absence of ion channel block. When the ion channel block is considered, we find that this autaptic delay induced MCR phenomenon enhances with the increasing of potassium channel block, whereas it weakens with the increasing of sodium channel block at weak and intermediate autaptic conductance regimes. However, at strong autaptic conductance regime neither sodium nor potassium channel block have a significant effect on the collective firing regularity of the network. Besides, we investigate the effects of the coupling strength, the network randomness and the cell size on the regularity. We obtain an optimal coupling strength value and an optimal cell size leading to a more prominent MCR effect. We also show that the MCR phenomenon increases with the increasing of network randomness in potassium channel block, but it needs to a minimum network randomness for its appearing in case of sodium channel block.

  2. Study of the negative ion extraction mechanism from a double-ion plasma in negative ion sources

    Energy Technology Data Exchange (ETDEWEB)

    Goto, I.; Nishioka, S.; Hatayama, A. [Graduate school of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522 (Japan); Miyamoto, K. [Naruto University of Education, 748 Nakashima, Takashima, Naruto-cho, Naruto-shi, Tokushima 772-8502 (Japan)

    2015-04-08

    We have developed a 2D3V-PIC model of the extraction region, aiming to clarify the basic extraction mechanism of H{sup −} ions from the double-ion plasma in H{sup −} negative ion sources. The result shows the same tendency of the H{sup −} ion density n{sub H{sup −}} as that observed in the experiments, i.e.,n{sub H{sup −}} in the upstream region away from the plasma meniscus (H{sup −} emitting surface) has been reduced by applying the extraction voltage. At the same time, relatively slow temporal oscillation of the electric potential compared with the electron plasma frequency has been observed in the extraction region. Results of the systematic study using a 1D3V-PIC model with the uniform magnetic field confirm the result that the electrostatic oscillation is identified to be lower hybrid wave. The effect of this oscillation on the H{sup −} transport will be studied in the future.

  3. Arthur L. Schawlow Prize in Laser Science Talk: Trapped Ion Quantum Networks with Light

    Science.gov (United States)

    Monroe, Christopher

    2015-05-01

    Laser-cooled atomic ions are standards for quantum information science, acting as qubit memories with unsurpassed levels of quantum coherence while also allowing near-perfect measurement. When qubit state-dependent optical dipole forces are applied to a collection of trapped ions, their Coulomb interaction is modulated in a way that allows the entanglement of the qubits through quantum gates that can form the basis of a quantum computer. Similar optical forces allow the simulation of quantum many-body physics, where recent experiments are approaching a level of complexity that cannot be modelled with conventional computers. Scaling to much larger numbers of qubits can be accomplished by coupling trapped ion qubits through optical photons, where entanglement over remote distances can be used for quantum communication and large-scale distributed quantum computers. Laser sources and quantum optical techniques are the workhorse for such quantum networks, and will continue to lead the way as future quantum hardware is developed. This work is supported by the ARO with funding from the IARPA MQCO program, the DARPA Quiness Program, the ARO MURI on Hybrid Quantum Circuits, the AFOSR MURIs on Quantum Transduction and Quantum Verification, and the NSF Physics Frontier Center at JQI.

  4. Computer Networks and African Studies Centers.

    Science.gov (United States)

    Kuntz, Patricia S.

    The use of electronic communication in the 12 Title VI African Studies Centers is discussed, and the networks available for their use are reviewed. It is argued that the African Studies Centers should be on the cutting edge of contemporary electronic communication and that computer networks should be a fundamental aspect of their programs. An…

  5. Polarization Studies in Fast-Ion Beam Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Trabert, E

    2001-12-20

    In a historical review, the observations and the insight gained from polarization studies of fast ions interacting with solid targets are presented. These began with J. Macek's recognition of zero-field quantum beats in beam-foil spectroscopy as indicating alignment, and D.G. Ellis' density operator analysis that suggested the observability of orientation when using tilted foils. Lastly H. Winter's studies of the ion-beam surface interaction at grazing incidence yielded the means to produce a high degree of nuclear orientation in ion beams.

  6. Kinetic study of heavy metal ions removal by ion exchange in batch conical air spouted bed

    Directory of Open Access Journals (Sweden)

    T.M. Zewail

    2015-03-01

    Full Text Available Spouted bed contactor is a hybrid of fixed and fluidized bed contactors, which retains the advantages of each with good hydrodynamic conditions. The aim of the present study is to investigate the performance of a batch conical air spouted vessel for heavy metal removal by strong cation exchange resins (AMBERJET 1200 Na. The effect of various parameters such as type of heavy metal ions (Ni+2 and Pb+2, contact time, superficial air velocity and initial heavy metal ion concentration on % heavy metal ion removal has been investigated. It has been found that under optimum conditions 98% and 99% removal of Ni+2 and Pb+2 were achieved respectively. Several kinetic models were used to test the experimental data and to examine the controlling mechanism of the sorption process. The present results of Ni+2 and Pb+2 well fit pseudo second order kinetic model with a high correlation coefficient. Both film diffusion and intra-particle diffusion contribute to the ion exchange process. The present study revealed that spouted bed vessel may provide an effective alternative for conducting ion exchange reactions.

  7. Ion transport studies in lithium phospho-molybdate glasses containing Cl{sup −} ion

    Energy Technology Data Exchange (ETDEWEB)

    Gowda, V.C. Veeranna [Department of Physics, Government College for Women, Chintamani (India); Chethana, B.K. [Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore (India); Reddy, C. Narayana, E-mail: nivetejareddy@gmail.com [Department of Physics, Maharani' s Science College for Women, Bangalore (India)

    2013-07-01

    Highlights: • Addition of LiCl creates more conducting channels for Li{sup +} ion movement. • The decrease in E{sub dc} with increasing LiCl concentration could be due to Li{sup +} ions present in the columbic wells surrounded by Cl{sup −} ions are expected to be shallow. • Examined the power law fits using both two term and three term equation with fixed and floated parameters. -- Abstract: Ion conducting glasses in xLiCl–20Li{sub 2}O–(80−x) [0.80P{sub 2}O{sub 5}–0.20MoO{sub 3}] glass system have been prepared over a wide range of composition (X = 5, 10, 15, 20 and 25 mol%). The electrical conductivity and dielectric relaxation of these glasses were analyzed using impedance spectroscopy in the frequency range of 10 Hz–10 MHz and in the temperature range of 313–353 K. D.c. activation energies extracted from Arrhenius plots using regression analysis, decreases with increasing LiCl mol%. A.c. conductivity data has been fitted to both single and double power law equation with both fixed and variable parameters. The increased conductivity in the present glass system has been correlated with the volume increasing effect and the coordination changes that occur due to structural modification resulting in the creation of non-bridging oxygens (NBO's) of the type O-Mo-O{sup −} bonds in the glass network. Dielectric relaxation mechanism in these glasses is analyzed using Kohlrausch–Williams–Watts (KWW) stretched exponential function and stretched exponent (β) is found to be insensitive to temperature.

  8. Dynamics of Bottlebrush Networks: A Computational Study

    Science.gov (United States)

    Dobrynin, Andrey; Cao, Zhen; Sheiko, Sergei

    We study dynamics of deformation of bottlebrush networks using molecular dynamics simulations and theoretical calculations. Analysis of our simulation results show that the dynamics of bottlebrush network deformation can be described by a Rouse model for polydisperse networks with effective Rouse time of the bottlebrush network strand, τR =τ0Ns2 (Nsc + 1) where, Ns is the number-average degree of polymerization of the bottlebrush backbone strands between crosslinks, Nsc is the degree of polymerization of the side chains and τ0is a characteristic monomeric relaxation time. At time scales t smaller than the Rouse time, t crosslinks, the network response is pure elastic with shear modulus G (t) =G0 , where G0 is the equilibrium shear modulus at small deformation. The stress evolution in the bottlebrush networks can be described by a universal function of t /τR . NSF DMR-1409710.

  9. CCNA Cisco Certified Network Associate Study Guide

    CERN Document Server

    Lammle, Todd

    2011-01-01

    Learn from the Best - Cisco Networking Authority Todd LammleWritten by Cisco networking authority Todd Lammle, this comprehensive guide has been completely updated to reflect the latest CCNA 640-802 exam. Todd's straightforward style provides lively examples, hands on and written labs, easy-to-understand analogies, and real-world scenarios that will not only help you prepare for the exam, but also give you a solid foundation as a Cisco networking professional.This Study Guide teaches you how toDescribe how a network worksConfigure, verify and troubleshoot a switch with VLANs and interswitch co

  10. Ion Mobility Studies on the Negative Ion-Molecule Chemistry of Isoflurane and Enflurane

    Science.gov (United States)

    González-Méndez, Ramón; Watts, Peter; Howse, David C.; Procino, Immacolata; McIntyre, Henry; Mayhew, Chris A.

    2017-05-01

    In the present work we present an investigation of the negative ion-molecule chemistry of the anaesthetics isoflurane, ISOF, and enflurane, ENF, in an ion mobility spectrometry/mass spectrometry (IMS/MS), in both air and nitrogen. Hexachloroethane (HCE) was introduced in both air and nitrogen to produce Cl- as a reactant ion. This study was undertaken owing to uncertainties in the chemical processes, which lead to the cluster ions reported in other work (Eiceman et al. Anal. Chem. 61, 1093-1099, 1). In particular for ISOF the product ion observed was ISOF.Cl-, and it was suggested that the Cl- was formed by dissociative electron attachment (DEA) although there was mention of a chlorine containing contaminant. We show in this study that ISOF and ENF do not produce Cl- in an IMS system either by capture of free electrons or reaction with O2 -. This demonstrates that the Cl- containing ions, reported in the earlier study, must have been the result of a chlorine containing contaminant as suggested. The failure of ISOF and ENF to undergo DEA was initially surprising given the high calculated electron affinities, but further calculations showed that this was a result of the large positive vertical attachment energies (VAEs). This experimental work has been supported by electronic structure calculations at the B3LYP level, and is consistent with those obtained in a crossed electron-molecular beam two sector field mass spectrometer. An unusual observation is that the monomer complexes of ISOF and ENF with O2 - are relatively unstable compared with the dimer complexes.

  11. A study on dry decontamination using ion exchange polymer

    Energy Technology Data Exchange (ETDEWEB)

    Jung, Ki Jung; Ahn, Byung Gil

    1997-12-01

    Through the project of {sup A} study on dry decontamination using ion exchange polymer{sup ,} the followings were investigated. 1. Highly probable decontamination technologies for the decontamination were investigated. 2. Development of gel type decontamination agent using ion-exchange resin powder (mixed type) as an ion exchanger. 3. Manufacturing of contaminated specimens (5 kinds) with Cs-137 solution and dust / Cs-137 solution. 4. Decontamination performance evaluation of the manufactured agent. 5. Analysis of composition (XRF) and the structure of surface of specimens (optic micrography). (author). 20 refs., 11 figs.

  12. Atomic Scale Picture of the Ion Conduction Mechanism in Tetrahedral Network of Lanthanum Barium Gallate

    Energy Technology Data Exchange (ETDEWEB)

    Jalarvo, Niina H [ORNL; Gourdon, Olivier [ORNL; Bi, Zhonghe [ORNL; Gout, Delphine J [ORNL; Ohl, Michael E [ORNL; Paranthaman, Mariappan Parans [ORNL

    2013-01-01

    Combined experimental study of impedance spectroscopy, neutron powder diffraction and quasielastic neutron scattering was performed to shed light into the atomic scale ion migration processes in proton and oxide ion conductor; La0.8Ba1.2GaO3.9 . This material consist of tetrahedral GaO4 units, which are rather flexible and rocking motion of these units promotes the ionic migration process. The oxide ion (vacancy) conduction takes place on channels along c axis, involving a single elementary step, which occurs between adjacent tetrahedron (inter-tetrahedron jump). The proton conduction mechanism consists of intra-tetrahedron and inter-tetrahedron elementary processes. The intra-tetrahedron proton transport is the rate-limiting process, with activation energy of 0.44 eV. The rocking motion of the GaO4 tetrahedron aids the inter-tetrahedral proton transport, which has the activation energy of 0.068 eV.

  13. Selective removal of heavy metal ions by disulfide linked polymer networks

    DEFF Research Database (Denmark)

    Ko, Dongah; Sung Lee, Joo; Patel, Hasmukh A.

    2017-01-01

    a moderate surface area, it demonstrated cadmium removal efficiency equivalent to highly porous activated carbon while it showed 16 times faster sorption kinetics compared to activated carbon, owing to the high affinity of cadmium towards disulfide and thiol functionality in the polymer network. The metal...... sorption mechanism on polymer network was studied by sorption kinetics, effect of pH, and metal complexation. We observed that the metal ions―copper, cadmium, and zinc showed high binding affinity in polymer network, even in the presence of competing cations like calcium in water....

  14. Ionization efficiency studies for xenon ions with thesuperconducting ECR ion source VENUS

    Energy Technology Data Exchange (ETDEWEB)

    Leitner, Daniela; Lyneis, Claude M.; Todd, DamonS.; Tarvainen,Olli

    2007-06-05

    Ionization efficiency studies for high charge state xenon ions using a calibrated gas leak are presented. A 75% enriched {sup 129}Xe gas leak with a gas flow equivalent to 5.11p{mu}A was used in all the measurements. The experiments were performed at the VENUS (Versatile ECR ion source for Nuclear Science) ion source for 18 GHz, 28 GHz and double frequency operation. Overall, total ionization efficiencies close to 100% and ionization efficiencies into a single charge state up to 22% were measured. The influence of the biased disk on the ionization efficiency was studied and the results were somewhat surprising. When the biased disk was removed from the plasma chamber, the ionization efficiency was dramatically reduced for single frequency operation. However, using double frequency heating the ionization efficiencies achieved without the biased disk almost matched the ionization efficiencies achieved with the biased probe. In addition, we have studied the influence of the support gas on the charge state distribution of the xenon ions. Either pure oxygen or a mixture of oxygen and helium were used as support gases. The addition of a small amount of helium can increase the ionization efficiency into a single charge state by narrowing the charge state distribution. Furthermore by varying the helium flow the most efficient charge state can be shifted over a wide range without compromising the ionization efficiency. This is not possible using only oxygen as support gas. Results from these studies are presented and discussed.

  15. Photorecombination studies of highly charged tungsten ions at Shanghai EBIT

    Science.gov (United States)

    Tu, B.; Xiao, J.; Yao, K.; Wang, X.; Shen, Y.; Yang, Y.; Lu, D.; Huang, L.; Zhen, C.; Fu, Y.; Wei, B.; Hutton, R.; Zou, Y.

    2017-11-01

    In this paper, we report studies on photorecombination (PR) processes for highly charged W ions. The experiment was performed at Shanghai electron beam ion trap by employing a fast electron beam-energy scanning technique. The KLL dielectronic recombination (DR) resonance strengths for He- up to O-like W ions were determined. The strong interference effect between DR and radiative recombination (RR) was observed and the Fano factor, which measures the interference degree, was determined for the main resonances of ground state He-, Be-, B-, C-, N-, and O-like W ions. In addition, we show experimentally that an autoionizing state can have both Fano and Lorentzian behavior naturally, depending on the processes involved. A fully relativistic configuration interaction method implemented in the flexible atomic code was employed to calculate DR, RR processes and also the inference effect.

  16. Earth Regime Network Evolution Study (ERNESt)

    Science.gov (United States)

    Menrad, Bob

    2016-01-01

    Speaker and Presenter at the Lincoln Laboratory Communications Workshop on April 5, 2016 at the Massachusetts Institute of Technology Lincoln Laboratory in Lexington, MA. A visual presentation titled Earth Regimes Network Evolution Study (ERNESt).

  17. A large ion beam device for laboratory solar wind studies

    Science.gov (United States)

    Ulibarri, Zach; Han, Jia; Horányi, Mihály; Munsat, Tobin; Wang, Xu; Whittall-Scherfee, Guy; Yeo, Li Hsia

    2017-11-01

    The Colorado Solar Wind Experiment is a new device constructed at the Institute for Modeling Plasma, Atmospheres, and Cosmic Dust at the University of Colorado. A large cross-sectional Kaufman ion source is used to create steady state plasma flow to model the solar wind in an experimental vacuum chamber. The plasma beam has a diameter of 12 cm at the source, ion energies of up to 1 keV, and ion flows of up to 0.1 mA/cm2. Chamber pressure can be reduced to 4 × 10-5 Torr under operating conditions to suppress ion-neutral collisions and create a monoenergetic ion beam. The beam profile has been characterized by a Langmuir probe and an ion energy analyzer mounted on a two-dimensional translation stage. The beam profile meets the requirements for planned experiments that will study solar wind interaction with lunar magnetic anomalies, the charging and dynamics of dust in the solar wind, plasma wakes and refilling, and the wakes of topographic features such as craters or boulders. This article describes the technical details of the device, initial operation and beam characterization, and the planned experiments.

  18. Prospects of real-time ion temperature and rotation profiles based on neural-network charge exchange analysis

    Energy Technology Data Exchange (ETDEWEB)

    Koenig, R.W.T.; Von Hellermann, M. [Commission of the European Communities, Abingdon (United Kingdom). JET Joint Undertaking; Svensson, J. [Royal Inst. of Tech., Stockholm (Sweden)

    1994-07-01

    A back-propagation neural network technique is used at JET to extract plasma parameters like ion temperature, rotation velocities or spectral line intensities from charge exchange (CX) spectra. It is shown that in the case of the C VI CX spectra, neural networks can give a good estimation (better than +-20% accuracy) for the main plasma parameters (Ti, V{sub rot}). Since the neural network approach involves no iterations or initial guesses the speed with which a spectrum is processed is so high (0.2 ms/spectrum) that real time analysis will be achieved in the near future. 4 refs., 8 figs.

  19. Heavy ion linear accelerator for radiation damage studies of materials

    Energy Technology Data Exchange (ETDEWEB)

    Kutsaev, Sergey V.; Mustapha, Brahim; Ostroumov, Peter N.; Nolen, Jerry; Barcikowski, Albert; Pellin, Michael; Yacout, Abdellatif

    2017-03-01

    A new eXtreme MATerial (XMAT) research facility is being proposed at Argonne National Laboratory to enable rapid in situ mesoscale bulk analysis of ion radiation damage in advanced materials and nuclear fuels. This facility combines a new heavy-ion accelerator with the existing high-energy X-ray analysis capability of the Argonne Advanced Photon Source. The heavy-ion accelerator and target complex will enable experimenters to emulate the environment of a nuclear reactor making possible the study of fission fragment damage in materials. Material scientists will be able to use the measured material parameters to validate computer simulation codes and extrapolate the response of the material in a nuclear reactor environment. Utilizing a new heavy-ion accelerator will provide the appropriate energies and intensities to study these effects with beam intensities which allow experiments to run over hours or days instead of years. The XMAT facility will use a CW heavy-ion accelerator capable of providing beams of any stable isotope with adjustable energy up to 1.2 MeV/u for U-238(50+) and 1.7 MeV for protons. This energy is crucial to the design since it well mimics fission fragments that provide the major portion of the damage in nuclear fuels. The energy also allows damage to be created far from the surface of the material allowing bulk radiation damage effects to be investigated. The XMAT ion linac includes an electron cyclotron resonance ion source, a normal-conducting radio-frequency quadrupole and four normal-conducting multi-gap quarter-wave resonators operating at 60.625 MHz. This paper presents the 3D multi-physics design and analysis of the accelerating structures and beam dynamics studies of the linac.

  20. Heavy ion linear accelerator for radiation damage studies of materials

    Science.gov (United States)

    Kutsaev, Sergey V.; Mustapha, Brahim; Ostroumov, Peter N.; Nolen, Jerry; Barcikowski, Albert; Pellin, Michael; Yacout, Abdellatif

    2017-03-01

    A new eXtreme MATerial (XMAT) research facility is being proposed at Argonne National Laboratory to enable rapid in situ mesoscale bulk analysis of ion radiation damage in advanced materials and nuclear fuels. This facility combines a new heavy-ion accelerator with the existing high-energy X-ray analysis capability of the Argonne Advanced Photon Source. The heavy-ion accelerator and target complex will enable experimenters to emulate the environment of a nuclear reactor making possible the study of fission fragment damage in materials. Material scientists will be able to use the measured material parameters to validate computer simulation codes and extrapolate the response of the material in a nuclear reactor environment. Utilizing a new heavy-ion accelerator will provide the appropriate energies and intensities to study these effects with beam intensities which allow experiments to run over hours or days instead of years. The XMAT facility will use a CW heavy-ion accelerator capable of providing beams of any stable isotope with adjustable energy up to 1.2 MeV/u for 238U50+ and 1.7 MeV for protons. This energy is crucial to the design since it well mimics fission fragments that provide the major portion of the damage in nuclear fuels. The energy also allows damage to be created far from the surface of the material allowing bulk radiation damage effects to be investigated. The XMAT ion linac includes an electron cyclotron resonance ion source, a normal-conducting radio-frequency quadrupole and four normal-conducting multi-gap quarter-wave resonators operating at 60.625 MHz. This paper presents the 3D multi-physics design and analysis of the accelerating structures and beam dynamics studies of the linac.

  1. In-Situ Ion Analysis of Fresh Waters via an ISE Multiprobe and Artificial Neural Networks

    Science.gov (United States)

    Mueller, A. V.; Hemond, H.

    2010-12-01

    The ecological and geochemical sciences stand to substantially gain from capability for comprehensive, real-time, in-situ characterization of the chemical constituents of natural waters, e.g. by facilitating rapid high-resolution adaptive sampling campaigns and avoiding the potential errors and high costs related to traditional grab sample collection, transportation and in-lab analysis. In-situ chemical instrumentation also promotes the goals of large-scale monitoring networks, such as CUASHI and WATERS, by reducing the financial and human resources overhead required for traditional sampling at this scale. Problems of environmental remediation and monitoring of industrial waste waters would additionally benefit from such instrumental capacity. We have pursued in-situ measurement of all major ions contributing to the charge makeup (>99%) of oxic natural fresh waters via an instrument combining an array of ion-selective electrode (ISE) hardware with an appropriate multivariate signal processing architecture. Commercially available electrochemical sensors promote low cost and a fast development schedule, as well as easy maintenance and reproduction. Data processing techniques are adapted from artificial intelligence and chemometrics to extract accurate information from the corresponding in-situ data matrix. This architecture takes into account temperature, conductivity, and non-linearity effects, as well as taking advantage of sensor cross-selectivities traditionally considered as interferences. Chemical and mathematical constraints, e.g. charge balance and total ionic strength, provide further system-level information. Maximizing data recovery from the sensor array allows use of the instrument without the standard additions or ionic strength adjustment traditionally-required with use of ISEs. Initial work demonstrates the effectiveness of this methodology at predicting inorganic cations (sodium, potassium, calcium, and ammonium ) and hydrogen ion in a simplified

  2. The impact of functionalized CNT in the network of sodium alginate-based nanocomposite beads on the removal of Co(II) ions from aqueous solutions

    Energy Technology Data Exchange (ETDEWEB)

    Karkeh-abadi, Fatemeh [Department of Chemistry, University of Kashan, Kashan (Iran, Islamic Republic of); Saber-Samandari, Samaneh, E-mail: samaneh.saber@gmail.com [Department of Chemistry, Eastern Mediterranean University, Gazimagusa, TRNC via Mersin 10 (Turkey); Saber-Samandari, Saeed, E-mail: saeedss@aut.ac.ir [New Technologies Research Center, Amirkabir University of Technology, Tehran (Iran, Islamic Republic of)

    2016-07-15

    Highlights: • The sodium alginate-hydroxyapatite-CNT nanocomposite beads were prepared. • Amide functionalized CNT imprinted in the network of sodium alginate containing HAp. • The prepared beads were used as adsorbents of cobalt ions from an aqueous solution. • The adsorption was fit with the Freundlich isotherm and second-order kinetic models. • The endothermic adsorption process is spontaneous and thermodynamically favorable. - Abstract: Significant efforts have been made to develop highly efficient adsorbents to remove radioactive Co(II) ion pollutants from medical and industrial wastewaters. In this study, amide group functionalized multi-walled carbon nanotube (CNT-CONH{sub 2}) imprinted in the network of sodium alginate containing hydroxyapatite, and new nanocomposite beads were synthesized. Then, they were characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction analysis (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS). The prepared nanocomposite beads were used as an adsorbent of Co(II) ions from an aqueous solution. The presence and distribution of Co(II) ions in the surface of the nanocomposite beads was confirmed using FESEM, EDS and metal mapping analysis. The effect of various experimental conditions such as time, pH, and initial concentration of the adsorbate solution and temperature on the adsorption capacity of the nanocomposite beads were explored. The maximum Co(II) ions adsorption capacity of the prepared nanocomposite beads with the largest surface area of 163.4 m{sup 2} g{sup −1} was 347.8 mg g{sup −1} in the optimized condition. The adsorption mechanism followed a pseudo-second-order kinetic model. Furthermore, the Freundlich appears to produce better fit than the Langmuir adsorption isotherm. Finally, thermodynamic studies suggest that endothermic adsorption process of Co(II) ions is spontaneous and

  3. Social network analysis of study environment

    Directory of Open Access Journals (Sweden)

    Blaženka Divjak

    2010-06-01

    Full Text Available Student working environment influences student learning and achievement level. In this respect social aspects of students’ formal and non-formal learning play special role in learning environment. The main research problem of this paper is to find out if students' academic performance influences their position in different students' social networks. Further, there is a need to identify other predictors of this position. In the process of problem solving we use the Social Network Analysis (SNA that is based on the data we collected from the students at the Faculty of Organization and Informatics, University of Zagreb. There are two data samples: in the basic sample N=27 and in the extended sample N=52. We collected data on social-demographic position, academic performance, learning and motivation styles, student status (full-time/part-time, attitudes towards individual and teamwork as well as informal cooperation. Afterwards five different networks (exchange of learning materials, teamwork, informal communication, basic and aggregated social network were constructed. These networks were analyzed with different metrics and the most important were betweenness, closeness and degree centrality. The main result is, firstly, that the position in a social network cannot be forecast only by academic success and, secondly, that part-time students tend to form separate groups that are poorly connected with full-time students. In general, position of a student in social networks in study environment can influence student learning as well as her/his future employability and therefore it is worthwhile to be investigated.

  4. The network modifier and former role of the bismuth ions in the bismuth-lead-germanate glasses.

    Science.gov (United States)

    Rada, M; Rus, L; Rada, S; Culea, E; Rusu, T

    2014-11-11

    The present work is focused on the enhancement of network former environment in lead-germanate glasses by bismuth ions doping. A series of bismuth-lead-germanate glasses with the xBi2O3·(100-x)[7GeO2·3PbO] composition glass where 0≤x≤30 mol% Bi2O3 were synthesized by melt-quenching method. The FTIR, UV-VIS spectroscopy and cyclic voltammetry were conducted on these samples to evaluate the doping effect of structure of the host matrix network. Our results indicate that direct incorporation of Bi2O3 into the lead-germanate network modifies the lead-germanate network and the internal structure of glass network is rearranged. The structural flexibility of the lead-germanate network is possible due to its incapacity to accommodate with the excess of oxygen atoms and the creation of bridging oxygen ions. Optical gap energy and refractive index were obtained as a function of Bi2O3 content. Gap energy values decrease as Bi2O3 content increased from 0 to 10 mol%. Further increase of Bi2O3 concentration beyond 10 mol% increased the gap energy values. These behaviors of the glass system can be explained by two mechanisms: (i) for x≤10 mol% Bi2O3--increase of degree of disorder of the host matrix because Bi2O3 is network modifier and (ii) for x>10 mol%--Bi2O3 acts as a network former. Cyclic voltammetry measurements using the glass system with 10Bi2O3·90[7GeO2·3PbO] composition as working electrode show the mobility of the lead ions, in agreement with UV-VIS data. Copyright © 2014 Elsevier B.V. All rights reserved.

  5. Recent developments of ion sources for life-science studies at the Heavy Ion Medical Accelerator in Chiba (invited).

    Science.gov (United States)

    Kitagawa, A; Drentje, A G; Fujita, T; Muramatsu, M; Fukushima, K; Shiraishi, N; Suzuki, T; Takahashi, K; Takasugi, W; Biri, S; Rácz, R; Kato, Y; Uchida, T; Yoshida, Y

    2016-02-01

    With about 1000-h of relativistic high-energy ion beams provided by Heavy Ion Medical Accelerator in Chiba, about 70 users are performing various biology experiments every year. A rich variety of ion species from hydrogen to xenon ions with a dose rate of several Gy/min is available. Carbon, iron, silicon, helium, neon, argon, hydrogen, and oxygen ions were utilized between 2012 and 2014. Presently, three electron cyclotron resonance ion sources (ECRISs) and one Penning ion source are available. Especially, the two frequency heating techniques have improved the performance of an 18 GHz ECRIS. The results have satisfied most requirements for life-science studies. In addition, this improved performance has realized a feasible solution for similar biology experiments with a hospital-specified accelerator complex.

  6. Ion extraction system study. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Hyman, J. Jr.; Williamson, W.S.

    1977-05-01

    Results of an 8-month study of plasma-extraction processes for laser isotope separation of uranium are reported. A simulation technology was developed, using mercury instead of uranium, and analytical and experimental studies of plasma-extraction processes were performed in the context of mercury simulation. (LK)

  7. Experiments Studying Desorbed Gas and Electron Clouds in Ion Accelerators

    CERN Document Server

    Molvik, Arthur; Barnard, John J; Bieniosek, Frank; Celata, C M; Cohen, Ronald; Covo, Michel K; Friedman, Alex; Lund, Steven M; Seidl, Peter; Vay, Jean-Luc; Vujic, J L; Waldron, William

    2005-01-01

    Electron clouds and gas pressure rise limit the performance of many major accelerator rings. We are studying these issues experimentally with ~1 MeV heavy-ion beams, coordinated with significant efforts in self-consistent simulation and theory.* The experiments use multiple diagnostics, within and between quadrupole magnets, to measure the sources and accumulation of electrons and gas. In support of these studies, we have measured gas desorption and electron emission coefficients for potassium ions impinging on stainless steel targets at angles near grazing incidence.** Our goal is to measure the electron particle balance for each source - ionization of gas, emission from beam tubes, and emission from an end wall - determine the electron effects on the ion beam and apply the increased understanding to mitigation.

  8. Study of ion-irradiated tungsten in deuterium plasma

    Energy Technology Data Exchange (ETDEWEB)

    Khripunov, B.I., E-mail: boris@nfi.kiae.ru [National Research Center Kurchatov Institute, Kurchatov Sq. 1, Moscow 123182 (Russian Federation); Gureev, V.M.; Koidan, V.S.; Kornienko, S.N.; Latushkin, S.T.; Petrov, V.B.; Ryazanov, A.I.; Semenov, E.V.; Stolyarova, V.G.; Danelyan, L.S. [National Research Center Kurchatov Institute, Kurchatov Sq. 1, Moscow 123182 (Russian Federation); Kulikauskas, V.S.; Zatekin, V.V. [Institute of Nuclear Physics, Lomonosov University, Moscow 119991 (Russian Federation); Unezhev, V.N. [National Research Center Kurchatov Institute, Kurchatov Sq. 1, Moscow 123182 (Russian Federation)

    2013-07-15

    Experimental study aimed at investigation of neutron induced damage influence on fusion reactor plasma facing materials is reported. Displacement damage was produced in tungsten by high-energy helium and carbon ions at 3–10 MeV. The reached level of displacement damage ranged from several dpa to 600 dpa. The properties of the irradiated tungsten were studied in steady-state deuterium plasma on the LENTA linear divertor simulator. Plasma exposures were made at 250 eV of ion energy to fluence 10{sup 21}–10{sup 22} ion/cm{sup 2}. Erosion dynamics of the damaged layer and deuterium retention were observed. Surface microstructure modifications and important damage of the 5 μm layer shown. Deuterium retention in helium-damaged tungsten (ERD) showed its complex behavior (increase or decrease) depending on implanted helium quantity and the structure of the surface layer.

  9. The impact of functionalized CNT in the network of sodium alginate-based nanocomposite beads on the removal of Co(II) ions from aqueous solutions.

    Science.gov (United States)

    Karkeh-Abadi, Fatemeh; Saber-Samandari, Samaneh; Saber-Samandari, Saeed

    2016-07-15

    Significant efforts have been made to develop highly efficient adsorbents to remove radioactive Co(II) ion pollutants from medical and industrial wastewaters. In this study, amide group functionalized multi-walled carbon nanotube (CNT-CONH2) imprinted in the network of sodium alginate containing hydroxyapatite, and new nanocomposite beads were synthesized. Then, they were characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction analysis (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS). The prepared nanocomposite beads were used as an adsorbent of Co(II) ions from an aqueous solution. The presence and distribution of Co(II) ions in the surface of the nanocomposite beads was confirmed using FESEM, EDS and metal mapping analysis. The effect of various experimental conditions such as time, pH, and initial concentration of the adsorbate solution and temperature on the adsorption capacity of the nanocomposite beads were explored. The maximum Co(II) ions adsorption capacity of the prepared nanocomposite beads with the largest surface area of 163.4m(2)g(-1) was 347.8mgg(-1) in the optimized condition. The adsorption mechanism followed a pseudo-second-order kinetic model. Furthermore, the Freundlich appears to produce better fit than the Langmuir adsorption isotherm. Finally, thermodynamic studies suggest that endothermic adsorption process of Co(II) ions is spontaneous and thermodynamically favorable. Copyright © 2016 Elsevier B.V. All rights reserved.

  10. Electron cloud studies for heavy-ion and proton machines

    CERN Document Server

    Petrov, F; Weiland, Th

    2013-01-01

    Electron cloud effects are a known problem in various accelerator facilities around the world. Electron clouds cause instabilities and emittance growth in positron and proton beams as well as in heavy ion beams. Most of the hadron machines experience the build-up of EC due to the multipacting. In LHC and in positron machines production of electrons due to the synchrotron radiation becomes as important as the build-up due to the secondary emission. The main source of seed electrons in heavy ion machines is the residual gas ionization. FAIR facility in Darmstadt will operate with heavy-ion and proton beams. However, the beam parameters are such that the multipacting will start to play a role only for the unconditioned wall with the secondary emission yieldmore than 1.8. In this paperwe study the electron cloud build-up and its effect on the beam stability for FAIR heavy-ion coasting beams. These beams will be used during slow extraction. Electron scattering on the beam ions and its effect on the final neutraliz...

  11. Simulation study of secondary electron images in scanning ion microscopy

    CERN Document Server

    Ohya, K

    2003-01-01

    The target atomic number, Z sub 2 , dependence of secondary electron yield is simulated by applying a Monte Carlo code for 17 species of metals bombarded by Ga ions and electrons in order to study the contrast difference between scanning ion microscopes (SIM) and scanning electron microscopes (SEM). In addition to the remarkable reversal of the Z sub 2 dependence between the Ga ion and electron bombardment, a fine structure, which is correlated to the density of the conduction band electrons in the metal, is calculated for both. The brightness changes of the secondary electron images in SIM and SEM are simulated using Au and Al surfaces adjacent to each other. The results indicate that the image contrast in SIM is much more sensitive to the material species and is clearer than that for SEM. The origin of the difference between SIM and SEM comes from the difference in the lateral distribution of secondary electrons excited within the escape depth.

  12. Diagnostic studies of ion beam formation in inductively coupled plasma

    Energy Technology Data Exchange (ETDEWEB)

    Jacobs, Jenee L. [Iowa State Univ., Ames, IA (United States)

    2015-01-01

    This dissertation describes a variety of studies focused on the plasma and the ion beam in inductively coupled plasma mass spectrometry (ICP-MS). The ability to use ICP-MS for measurements of trace elements in samples requires the analytes to be efficiently ionized. Updated ionization efficiency tables are discussed for ionization temperatures of 6500 K and 7000 K with an electron density of 1 x 1015 cm-3. These values are reflective of the current operating parameters of ICP-MS instruments. Calculations are also discussed for doubly charged (M2+) ion formation, neutral metal oxide (MO) ionization, and metal oxide (MO+) ion dissociation for similar plasma temperature values. Ionization efficiency results for neutral MO molecules in the ICP have not been reported previously.

  13. Surface and Interface Studies with Radioactive Ions

    CERN Multimedia

    Weber, A

    2002-01-01

    Investigations on the atomic scale of magnetic surfaces and magnetic multilayers were performed by Perturbed Angular Correlation (PAC) spectroscopy. The unique combination of the Booster ISOLDE facility equipped with a UHV beamline and the UHV chamber ASPIC (Apparatus for Surface Physics and Interfaces at CERN) is ideally suited for such microscopic studies. Main advantages are the choice of problem-oriented radioactive probes and the purity of mass-separated beams. The following results were obtained: $\\,$i) Magnetic hyperfine fields (B$_{hf}$) of Se on Fe, Co, Ni surfaces were determined. The results prompted a theoretical study on the B$_{hf}$ values of the 4sp-elements in adatom position on Ni and Fe, confirming our results and predicting unexpected behaviour for the other elements. $\\,$ii) Exemplarily we have determined B$_{hf}$ values of $^{111}$Cd at many different adsorption sites on Ni surfaces. We found a strong dependence on the coordination number of the probes. With decreasing coordination nu...

  14. Luminescence study of lanthanide(III) ions in non-aqueous solutions containing azide ions

    Energy Technology Data Exchange (ETDEWEB)

    Lis, S.; Kimura, T.; Yoshida, Z.; But, S

    2004-10-20

    Luminescence lifetime and intensity measurements of lanthanide(III) ions, Ln{sup 3+} (Eu, Gd and Tb), in non-aqueous solutions containing azide ions (N{sub 3}{sup -}) have been performed to study the quenching effect of N{sub 3}{sup -} using time-resolved laser-induced luminescence spectroscopy and conventional luminescence spectroscopy. The luminescence Stern-Volmer quenching constants K{sub sv}{sup P}HI and azide non-radiative decay constants k{sub N{sub 3}} of the excited Eu(III) ion in the presence of N{sub 3}{sup -} were measured in N,N-dimethylformamide (DMF), dimethyl sulfoxide (DMSO), N-methylformamide (NMF), formamide (FA) and methanol (MeOH). The obtained quenching effect of the Ln{sup 3+} luminescence by azide in the non-aqueous solvents shows the order: Gd>Eu>Tb, which does not obey the energy gap law, {delta}E, between the emitting and the ground state of the Ln{sup 3+} ion (Gd>Tb>Eu). The anomaly in the quenching pattern observed in the case of Eu{sup 3+} can be attributed to its partial reduction to Eu{sup 2+}, additionally to the energy transfer from excited state of Eu{sup 3+} to N{sub 3}{sup -}. The values of quenching rate constants k{sub N{sub 3}} measured for Eu{sup 3+} in various solutions depend on the acceptor number (AN) of the solvents used.

  15. Photoluminescence and Raman studies in swift heavy ion irradiated ...

    Indian Academy of Sciences (India)

    Photoluminescence and Raman studies in swift heavy ion irradiated polycrystalline aluminum oxide ... Polymers Volume 32 Issue 5 October 2009 pp 515-519 ... A broad photoluminescence (PL) emission with peak at ∼447 nm and two sharp emissions with peak at ∼ 679 and ∼ 695 nm are observed in pristine when ...

  16. Recent studies in heavy ion induced fission reactions

    Indian Academy of Sciences (India)

    channel spins. Recently studies have been carried out on the spin distributions of fission fragments through the gamma ray multiplicity measurements. ... Heavy ion fission; angular distributions; fragment spin; mass; energy. ... neutrons and protons (magic numbers), and also resulting in deformed ground state shapes.

  17. Equilibrium and kinetics studies of metal ion adsorption on dyed ...

    African Journals Online (AJOL)

    GREGO

    2007-04-02

    diffusion control- led, even though these two different mechanisms cannot be sharply demarcated (Okieimen et al., 1987). In this study the rate of adsorption of Cu(II) and Zn(II) ions onto dyed coconut pollens was investigated at pH of.

  18. Equilibrium and kinetics studies of metal ion adsorption on dyed ...

    African Journals Online (AJOL)

    Batch equilibration studies were conducted to determine the nature of adsorption of Zn (II) and Cu (II) onto dyed coconut pollens. The nature of adsorption of metal ions was explained using the Langmuir equation. The calculated values of equilibrium parameter indicated favourable adsorption by the adsorbents. Also the ...

  19. Adsorption studies of phosphate ions on alginate-calcium carbonate ...

    African Journals Online (AJOL)

    Alginate-calcium carbonate composite beads was prepared by the sol-gel method and characterized by Fourier transform infra-red spectroscopy (FT-IR) and scanning electron microscope (SEM) instruments. Adsorption potential of phosphate ions have been studied on laboratory scale. The effects of contact time, adsorbent ...

  20. Design and Beam Dynamics Studies of a Multi-Ion Linac Injector for the JLEIC Ion Complex

    Energy Technology Data Exchange (ETDEWEB)

    Ostroumov, P. N.; Plastun, A. S.; Mustapha, B.; Conway, Z. A.

    2016-01-01

    The electron-ion collider (JLEIC) being proposed at JLab requires a new ion accelerator complex which includes a linac capable of delivering any ion beam from hydrogen to lead to the booster. We are currently developing a linac which consists of several ion sources, a normal conducting (NC) front end, up to 5 MeV/u, and a SC section for energies > 5 MeV/u. This design work is focused on the beam dynamics and electrodynamics studies performed to design efficient and cost-effective accelerating structures for both the NC and SC sections of the linac. Currently, we are considering two separate RFQs for the heavy-ion and light-ion beams including polarized beams, and different types of NC accelerating structures downstream of the RFQ. Quarter-wave and half-wave resonators can be effectively used in the SC section.

  1. Silicon-Encapsulated Hollow Carbon Nanofiber Networks as Binder-Free Anodes for Lithium Ion Battery

    Directory of Open Access Journals (Sweden)

    Ding Nan

    2014-01-01

    Full Text Available Silicon-encapsulated hollow carbon nanofiber networks with ample space around the Si nanoparticles (hollow Si/C composites were successfully synthesized by dip-coating phenolic resin onto the surface of electrospun Si/PVA nanofibers along with the subsequent solidification and carbonization. More importantly, the structure and Si content of hollow Si/C composite nanofibers can be effectively tuned by merely varying the concentration of dip solution. As-synthesized hollow Si/C composites show excellent electrochemical performance when they are used as binder-free anodes for Li-ion batteries (LIBs. In particular, when the concentration of resol/ethanol solution is 3.0%, the product exhibits a large capacity of 841 mAh g−1 in the first cycle, prominent cycling stability, and good rate capability. The discharge capacity retention of it was ~90%, with 745 mAh g−1 after 50 cycles. The results demonstrate that the hollow Si/C composites are very promising as alternative anode candidates for high-performance LIBs.

  2. Antimony nanoparticles anchored in three-dimensional carbon network as promising sodium-ion battery anode

    Science.gov (United States)

    Luo, Wen; Zhang, Pengfei; Wang, Xuanpeng; Li, Qidong; Dong, Yifan; Hua, Jingchen; Zhou, Liang; Mai, Liqiang

    2016-02-01

    A novel composite with antimony (Sb) nanoparticles anchored in three-dimensional carbon network (denoted as SbNPs@3D-C) is successfully synthesized via a NaCl template-assisted self-assembly strategy, followed by freeze-drying and one-step in-situ carbonization. The three-dimensional interconnected macroporous carbon framework can not only stabilize the architecture and buffer the volume expansion for Sb nanoparticles, but also provide high electrical conductivity for the whole electrode. Consequently, as a sodium-ion battery anode, the SbNPs@3D-C delivers a high reversible capacity (456 mAh g-1 at 100 mA g-1), stable cycling performance (94.3% capacity retention after 500 cycles at 100 mA g-1) as well as superior rate capability (270 mAh g-1 at 2000 mA g-1). When compared with commercial Sb particles, the SbNPs@3D-C exhibits dramatically enhanced electrochemical performance. Free from expensive template sources and complex manipulation, this work might shed some light on the synthesis of low-cost and high-performance materials for the next ;beyond lithium; battery generation.

  3. Networking and Information Technology Workforce Study: Final Report

    Data.gov (United States)

    Networking and Information Technology Research and Development, Executive Office of the President — This report presents the results of a study of the global Networking and Information Technology NIT workforce undertaken for the Networking and Information...

  4. Studies on a network of complex neurons

    Science.gov (United States)

    Chakravarthy, Srinivasa V.; Ghosh, Joydeep

    1993-09-01

    In the last decade, much effort has been directed towards understanding the role of chaos in the brain. Work with rabbits reveals that in the resting state the electrical activity on the surface of the olfactory bulb is chaotic. But, when the animal is involved in a recognition task, the activity shifts to a specific pattern corresponding to the odor that is being recognized. Unstable, quasiperiodic behavior can be found in a class of conservative, deterministic physical systems called the Hamiltonian systems. In this paper, we formulate a complex version of Hopfield's network of real parameters and show that a variation on this model is a conservative system. Conditions under which the complex network can be used as a Content Addressable memory are studied. We also examine the effect of singularities of the complex sigmoid function on the network dynamics. The network exhibits unpredictable behavior at the singularities due to the failure of a uniqueness condition for the solution of the dynamic equations. On incorporating a weight adaptation rule, the structure of the resulting complex network equations is shown to have an interesting similarity with Kosko's Adaptive Bidirectional Associative Memory.

  5. An empirical study of Chinese language networks

    Science.gov (United States)

    Zhou, Shuigeng; Hu, Guobiao; Zhang, Zhongzhi; Guan, Jihong

    2008-05-01

    Chinese is spoken by the largest number of people in the world, and it is regarded as one of the most important languages. In this paper, we explore the statistical properties of Chinese language networks (CLNs) within the framework of complex network theory. Based on one of the largest Chinese corpora, i.e. People’s Daily Corpus, we construct two networks (CLN1 and CLN2) from two different respects, with Chinese words as nodes. In CLN1, a link between two nodes exists if they appear next to each other in at least one sentence; in CLN2, a link represents that two nodes appear simultaneously in a sentence. We show that both networks exhibit small-world effect, scale-free structure, hierarchical organization and disassortative mixing. These results indicate that in many topological aspects Chinese language shapes complex networks with organizing principles similar to other previously studied language systems, which shows that different languages may have some common characteristics in their evolution processes. We believe that our research may shed some new light into the Chinese language and find some potentially significant implications.

  6. Case studies of attacks on communication networks

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Sin Bok; Han, Eon Suk [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    1996-06-15

    Recently, as the computer hardware and communications are developed, the data exchange through inter-networking has been highlighted and the data is being recognized as a great asset. Most of the organizations, businesses and enterprises are open to the external world-computer communication networks, attention must be focused on the securities of the information infrastructure. A government organization has been developing 'Circuits Analyzers', and 'Hacker-Tracking Program' and is struggling to track down sneakers. In this report, we analyze the contents of the cases where the communication network has been invaded, from the past up until now in Korea. This report also contains the result of a study on E-mail security, for the protection of KAERI Integrated Management Information System under which utilizes the CALS concepts and web services. (Author)

  7. Studying Ion Beam Mixing of Te/In Bilayer System .

    CERN Document Server

    Abdullah, A; Saleh, N

    2002-01-01

    Ion beam mixing at room temperature of Te/In bialayer system induced by 400 keV Ar sup + Ions from Jordan Van De Graff Accelerator (JOVAC) with fluences ranging from 1.11*10 sup 1 sup 4 to 7*10 sup 1 sup 5 ions is studied means of AC electrical resistivity measurements and 2 MeV sup 4 He sup + back scattering spectrometry. Changes in electrical resistivity (rho) were correlated with the growth of an intermixed layer at interface. Data is explained in terms of Riviere et al. Model showing that mixing is due to collisional cascade processes. It was found that primary collisions and collisional cascade mechanism contribute to ion mixing. Demixing is noticed which is attributed to the mechanism of primary collisions with the target atoms . FORTRAN (77) was written to calculate the thickness of upper and lower layers of the Te/In system before and after irradiation and the thickness and composition of intermixed layer at interface with the aid of (RBS) data. Also, a solid solution In sub 6 sub 7 Te sub 3 sub 3 was...

  8. Study of resonant reactions with radioactive ion beams

    CERN Document Server

    Galindo-Uribarri, A; Chavez, E; Gomez-Del Campo, J; Gross, C J; Huerta, A; Liang, J F; Ortiz, M E; Padilla, E; Pascual, S; Paul, S D; Shapira, D; Stracener, D W; Varner, R L

    2000-01-01

    A fast and efficient method to study (p,p) and (p,alpha) resonances with radioactive beams in inverse kinematics is described. It is based on the use of thick targets and large area double-sided silicon strip detectors (DSSDs) to detect the recoiling light-charged particles and to determine precisely their scattering angle. The first nuclear physics experiments with the technique have been performed recently at the Holifield Radioactive Ion Beam Facility (HRIBF) at Oak Ridge with stable beams of sup 1 sup 7 O and radioactive beams of sup 1 sup 7 F. The high-quality resonance measurements obtained demonstrate the capabilities of the technique. Pure sup 1 sup 7 F beams from HRIBF were produced by fully stripping the ions and separating the interfering and more abundant sup 1 sup 7 O ions by the beam transport system. The removal of interfering isobars is one of the various common challenges to both accelerator mass spectrometry (AMS) and radioactive ion beam (RIB) production. Experiments done with RIBs will ben...

  9. Proton-Ion Medical Machine Study (PIMMS), 2

    CERN Document Server

    Bryant, P J; Benedikt, Michael; Crescenti, M; Holy, P; Maier, A T; Pullia, M; Reimoser, S; Rossi, S; Borri, G; Knaus, P; Gramatica, F; Pavlovic, M; Weisser, L

    2000-01-01

    The Proton-Ion Medical Machine Study (PIMMS) group was formed following an agreement between the Med-AUSTRON (Austria) and the TERA Foundation (Italy) to combine their efforts in the design of a cancer therapy synchrotron capable of accelerating either light ions or protons. CERN agreed to support and host this study in its PS Division. A close collaboration was also set up with GSI (Germany). The study group was later joined by Onkologie-2000 (Czech Republic). Effort was first focused on the theoretical understanding of slow extraction and the techniques required to produce a smooth beam spill for the conformal treatment of complex-shaped tumours with a sub-millimetre accuracy by active scanning with proton and carbon ion beams. Considerations for passive beam spreading were also included for protons. The study has been written in two parts. The more general and theoretical aspects are recorded in Part I and the specific technical design considerations are presented in the present volume, Part II. An accompa...

  10. Taste masking of ciprofloxacin by ion-exchange resin and sustain release at gastric-intestinal through interpenetrating polymer network

    Directory of Open Access Journals (Sweden)

    A. Michael Rajesh

    2015-07-01

    Full Text Available The aim of the study was to taste mask ciprofloxacin (CP by using ion-exchange resins (IERs followed by sustain release of CP by forming interpenetrating polymer network (IPN. IERs based on the copolymerization of acrylic acid with different cross linking agents were synthesised. Drug-resin complexes (DRCs with three different ratios of drug to IERs (1:1, 1:2, 1:4 were prepared & evaluated for taste masking by following in vivo and in vitro methods. Human volunteers graded ADC 1:4, acrylic acid-divinyl benzene (ADC-3 resin as tasteless. Characterization studies such as FTIR, SEM, DSC, P-XRD differentiated ADC 1:4, from physical mixture (PM 1:4 and confirmed the formation of complex. In vitro drug release of ADC 1:4 showed complete release of CP within 60 min at simulated gastric fluid (SGF i.e. pH 1.2. IPN beads were prepared with ADC 1:4 by using sodium alginate (AL and sodium alginate-chitosan (AL-CS for sustain release of CP at SGF pH and followed by simulated intestinal fluid (SIF i.e. pH 7.4. FTIR spectra confirmed the formation of IPN beads. The release of CP was sustain at SGF pH (75%. The kinetic model of IPN beads showed the release of CP was non-Fickian diffusion type.

  11. Porous polymer networks and ion-exchange media and metal-polymer composites made therefrom

    Science.gov (United States)

    Kanatzidis, Mercouri G.; Katsoulidis, Alexandros

    2016-10-18

    Porous polymeric networks and composite materials comprising metal nanoparticles distributed in the polymeric networks are provided. Also provided are methods for using the polymeric networks and the composite materials in liquid- and vapor-phase waste remediation applications. The porous polymeric networks, are highly porous, three-dimensional structures characterized by high surface areas. The polymeric networks comprise polymers polymerized from aldehydes and phenolic molecules.

  12. Ion irradiation induced surface modification studies of polymers using Spmb

    Energy Technology Data Exchange (ETDEWEB)

    Tripathi, A. [Nuclear Science Centre, P.O. Box 10502, Aruna Asaf Ali Marg, New Delhi 110067 (India)]. E-mail: ambuj@nsc.res.in; Kumar, Amit [Nuclear Science Centre, P.O. Box 10502, Aruna Asaf Ali Marg, New Delhi 110067 (India); Singh, F. [Nuclear Science Centre, P.O. Box 10502, Aruna Asaf Ali Marg, New Delhi 110067 (India); Kabiraj, D. [Nuclear Science Centre, P.O. Box 10502, Aruna Asaf Ali Marg, New Delhi 110067 (India); Avasthi, D.K. [Nuclear Science Centre, P.O. Box 10502, Aruna Asaf Ali Marg, New Delhi 110067 (India); Pivin, J.C. [CSNSM, IN2 P3-CNRS, Batiment 108, F-91405 Orsay Campus (France)

    2005-07-01

    Various types of scanning probe microscopy (SPM) techniques: atomic force microscopy (AFM) (contact and tapping in height and amplitude mode), scanning tunnelling microscopy (STM) and conducting atomic force microscopy (C-AFM) are used for studying ion beam induced surface modifications, nanostructure/cluster formation and disintegration in polymers and similar soft carbon based materials. In the present study, the results of studies on four materials, namely (A) methyltriethoxysilane/phenyltriethoxysilane (MTES/PTES) based gel, (B) triethoxisilane (TH) based gel, (C) highly oriented pyrolytic graphite (HOPG) bulk and (D) fullerene (C{sub 60}) thin films are discussed. In the case of Si based gels prepared from pre-cursors containing organic groups (MTES/PTES), hillocks are observed at the surface and their size decreases from 70 to 25 nm with increasing fluence, whereas, in the case of a gel with a stoichiometry SiO{sub 1.25}H{sub 1}, prepared from TH, an increases in the size of hillocks is observed. Hillocks are also formed at the surface of HOPG irradiated with 120 MeV Au beam at a low fluence, whereas, formation of craters and a re-organisation of surface features is observed at a higher fluence. In the case of C{sub 60} films, 120 MeV Au ion irradiation induces the formation of conducting ion tracks, which is attributed to the transformation from insulating C{sub 60} to conducting graphite like carbon.

  13. Improved lithium-ion battery anode capacity with a network of easily fabricated spindle-like carbon nanofibers.

    Science.gov (United States)

    Liu, Mengting; Xie, Wenhe; Gu, Lili; Qin, Tianfeng; Hou, Xiaoyi; He, Deyan

    2016-01-01

    A novel network of spindle-like carbon nanofibers was fabricated via a simplified synthesis involving electrospinning followed by preoxidation in air and postcarbonization in Ar. Not only was the as-obtained carbon network comprised of beads of spindle-like nanofibers but the cubic MnO phase and N elements were successfully anchored into the amorphous carbon matrix. When directly used as a binder-free anode for lithium-ion batteries, the network showed excellent electrochemical performance with high capacity, good rate capacity and reliable cycling stability. Under a current density of 0.2 A g-1, it delivered a high reversible capacity of 875.5 mAh g-1 after 200 cycles and 1005.5 mAh g-1 after 250 cycles with a significant coulombic efficiency of 99.5%.

  14. Social networks and cooperation: a bibliometric study

    Directory of Open Access Journals (Sweden)

    Ana Paula Lopes

    2013-05-01

    Full Text Available The social network analysis involves social and behavioral science. The decentralization of productive activities, such as the formation of "network organizations" as a result of downsizing of large corporate structures of the past, marked by outsoucing and formation of alliances, shows the importance of this theme. The main objective of this paper is to analyze the theory of cooperation and social networks over a period of 24 years. For this, was performed a bibliometric study with content analysis. The database chosen for the initial sample search was ISI Web of Science. The search topics were “social network” and “cooperation”. Were analyzed 97 articles and their references, through networks of citations. The main identified research groups dealing with issues related to trust, strategic alliances, natural cooperation, game theory, social capital, intensity of interaction, reciprocity and innovation. It was found that the publications occurred in a large number of journals, which indicates that the theme is multidisciplinary, and only five journals published at least three articles. Although the first publication has occurred in 1987, was from 2006 that the publications effectively increased. The areas most related to the theme of the research were performance, evolution, management, graphics, model and game theory.

  15. Ion beam technology applications study. [ion impact, implantation, and surface finishing

    Science.gov (United States)

    Sellen, J. M., Jr.; Zafran, S.; Komatsu, G. K.

    1978-01-01

    Specific perceptions and possible ion beam technology applications were obtained as a result of a literature search and contact interviews with various institutions and individuals which took place over a 5-month period. The use of broad beam electron bombardment ion sources is assessed for materials deposition, removal, and alteration. Special techniques examined include: (1) cleaning, cutting, and texturing for surface treatment; (2) crosslinking of polymers, stress relief in deposited layers, and the creation of defect states in crystalline material by ion impact; and (3) ion implantation during epitaxial growth and the deposition of neutral materials sputtered by the ion beam. The aspects, advantages, and disadvantages of ion beam technology and the competitive role of alternative technologies are discussed.

  16. Ion trap architectures and new directions

    Science.gov (United States)

    Siverns, James D.; Quraishi, Qudsia

    2017-12-01

    Trapped ion technology has seen advances in performance, robustness and versatility over the last decade. With increasing numbers of trapped ion groups worldwide, a myriad of trap architectures are currently in use. Applications of trapped ions include: quantum simulation, computing and networking, time standards and fundamental studies in quantum dynamics. Design of such traps is driven by these various research aims, but some universally desirable properties have lead to the development of ion trap foundries. Additionally, the excellent control achievable with trapped ions and the ability to do photonic readout has allowed progress on quantum networking using entanglement between remotely situated ion-based nodes. Here, we present a selection of trap architectures currently in use by the community and present their most salient characteristics, identifying features particularly suited for quantum networking. We also discuss our own in-house research efforts aimed at long-distance trapped ion networking.

  17. Rutherford Backscattering Spectrometry studies of 100 keV nitrogen ion implanted polypropylene polymer

    Science.gov (United States)

    Chawla, Mahak; Aggarwal, Sanjeev; Sharma, Annu

    2017-09-01

    The effect of nitrogen ion implantation on the structure and composition in polypropylene (PP) polymer has been studied. Implantation was carried out using 100 keV N+ ions at different fluences of 1 × 1015, 1 × 1016 and 1 × 1017 ions cm-2 with beam current density of ∼0.65 μA cm-2. Surface morphological changes in the pre- and post-implanted PP specimens have been studied using Rutherford Backscattering Spectrometry (RBS) and UV-Visible Spectroscopy. The spatial distribution of implantation induced modification in the form of carbonization and dehydrogenation in the near surface region of PP matrix, the projected range, retained dose of implanted nitrogen, the various elements present in the implanted layers and their differential cross-sections have been analyzed using RBS spectra. RUMP simulation yielded an increase in the concentration of carbon near the surface from 33 at.% (virgin) to 42 at.% at fluence of 1 × 1017 N+ cm-2. Further, optical absorption has been found to increase with a shift in the absorption edge from UV towards visible region with increasing fluence. UV-Vis absorption spectra also indicate a drastic decrease in optical energy gap from 4.12 eV (virgin) to 0.25 eV (1 × 1017 N+ cm-2) indicating towards the formation of carbonaceous network in the implanted region. All these changes observed using UV-Visible have been further correlated with the outcomes of the RBS characterization.

  18. Design and construction of a imaging instrument for studying ion emission from pure ion emitters

    Energy Technology Data Exchange (ETDEWEB)

    Olson, John E. [Idaho State Univ., Pocatello, ID (United States)

    1993-09-01

    The development of new ion sources is important in the area of surface analysis to make it easier to perform more sensitive and accurate analyses. In surface analysis a primary ion beam composed of a single species can help when predicting and interpreting the results. Therefore, much interest and effort has been focused on producing pure ion emitters. An instrument has been designed and constructed to view the current densities of the ions being emitted from pure ion emitters. The instrument electrostatically accelerates and focuses the ion beam onto a microchannel plate detector equipped with a phosphor screen for viewing the images. These images are used to identify areas of enhanced ion emission. Once these areas are identified, the investigator can use other instruments to analyze them, and hopefully develop a better understanding of the chemistry and physics involved in the ion emission process. A computer based control system has been integrated into the system to simplify the operation of the instrument and provide safety features to protect the hardware from damage. A closed-circuit video camera system is used to allow the images to be remotely viewed during imaging procedures. Experiments show that the instrument has a lower detection limit of 7.45 x 103 ions/sec/mm2 and a spatial resolution of approximately 3 - 4 μm. Results from imaging cesium zeolite and perrhenate ion sources indicate that the ions are primarily being emitted from the surface of the sources and not from the interfacial region between the substrate and the emitter material.

  19. Scintillating screens study for LEIR/LHC heavy ion beams

    CERN Document Server

    Bal, C; Lefèvre, T; Scrivens, R; Taborelli, M

    2005-01-01

    It has been observed on different machines that scintillating ceramic screens (like chromium doped alumina) are quickly damaged by low energy ion beams. These particles are completely stopped on the surface of the screens, inducing both a high local temperature increase and the electrical charging of the material. A study has been initiated to understand the limiting factors and the damage mechanisms. Several materials, ZrO2, BN and Al2O3, have been tested at CERN on LINAC3 with 4.2MeV/u lead ions. Alumina (Al2O3) is used as the reference material as it is extensively used in beam imaging systems. Boron nitride (BN) has better thermal properties than Alumina and Zirconium oxide (ZrO2). BN has in fact the advantage of increasing its electrical conductivity when heated. This contribution presents the results of the beam tests, including the post-mortem analysis of the screens and the outlook for further measurements. The strategy for the choice of the screens for the Low Energy Ion Ring (LEIR), currently under ...

  20. TARGET EXCITATION IN BARE ION XE/AR COLLISIONS STUDIED BY ELECTRON TARGET ION COINCIDENCES

    NARCIS (Netherlands)

    DENIJS, G; HOEKSTRA, R; MORGENSTERN, R

    We present electron spectra resulting from collisions of bare ions N-15(7+) and C-13(6+) on Ar and the charge state distribution of target ions resulting from C-13(6+)-Xe collisions. From both type of experiments we find evidence that electron capture accompanied by target excitation is an important

  1. Molecular dynamics study of radiation damage and microstructure evolution of zigzag single-walled carbon nanotubes under carbon ion incidence

    Energy Technology Data Exchange (ETDEWEB)

    Li, Huan [Department of Nuclear Science & Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing (China); Tang, Xiaobin, E-mail: tangxiaobin@nuaa.edu.cn [Department of Nuclear Science & Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing (China); Jiangsu Key Laboratory of Nuclear Energy Equipment Materials Engineering, Nanjing (China); Chen, Feida; Huang, Hai; Liu, Jian [Department of Nuclear Science & Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing (China); Chen, Da [Department of Nuclear Science & Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing (China); Jiangsu Key Laboratory of Nuclear Energy Equipment Materials Engineering, Nanjing (China)

    2016-07-01

    Highlights: • Various incident sites of CNTs are classified into three types for the first time. • Different ion energies and fluences are considered to study the radiation damage. • CNTs have ability to heal the radiation-induced damage at higher temperature. • Stability of a large-diameter tube excels in a slim one under the same conditions. - Abstract: The radiation damage and microstructure evolution of different zigzag single-walled carbon nanotubes (SWCNTs) were investigated under incident carbon ion by molecular dynamics (MD) simulations. The radiation damage of SWCNTs under incident carbon ion with energy ranging from 25 eV to 1 keV at 300 K showed many differences at different incident sites, and the defect production increased to the maximum value with the increase in incident ion energy, and slightly decreased but stayed fairly stable within the majority of the energy range. The maximum damage of SWCNTs appeared when the incident ion energy reached 200 eV and the level of damage was directly proportional to incident ion fluence. The radiation damage was also studied at 100 K and 700 K and the defect production decreased distinctly with rising temperature because radiation-induced defects would anneal and recombine by saturating dangling bonds and reconstructing carbon network at the higher temperature. Furthermore, the stability of a large-diameter tube surpassed that of a thin one under the same radiation environments.

  2. Ion Dynamics Study of Potato Starch + Sodium Salts Electrolyte System

    Directory of Open Access Journals (Sweden)

    Tuhina Tiwari

    2013-01-01

    Full Text Available The effect of different anions, namely, SCN−, I−, and ClO4−, on the electrical properties of starch-based polymer electrolytes has been studied. Anion size and conductivity are having an inverse trend indicating systems to be predominantly anionic conductor. Impact of anion size and multiplet forming tendency is reflected in number of charge carriers and mobility, respectively. Ion dynamics study reveals the presence of different mechanisms in different frequency ranges. Interestingly, superlinear power law (SLPL is found to be present at <5 MHz frequency, which is further confirmed by dielectric data.

  3. Study of ion beam transport from the SECRAL electron cyclotron resonance ion source at the Institute of Modern Physics.

    Science.gov (United States)

    Cao, Y; Lu, W; Zhang, W H; Sha, S; Yang, Y; Ma, B H; Wang, H; Zhu, Y H; Guo, J W; Fang, X; Lin, S H; Li, X X; Feng, Y C; Li, J Y; Zhao, H Y; Ma, H Y; Zhang, X Z; Guo, X H; Wu, Q; Sun, L T; Zhao, H W; Xie, D Z

    2012-02-01

    Ion beam transport from the Superconducting Electron Cyclotron Resonance ion source with Advanced design in Lanzhou (SECRAL) electron cyclotron resonance ion source was studied at the Institute of Modern Physics during 2010. Particle-in-cell simulations and experimental results have shown that both space charge and magnetic aberrations lead to a larger beam envelope and emittance growth. In the existing SECRAL extraction beam line, it has been shown that raising the solenoid lens magnetic field reduces aberrations in the subsequent dipole and results in lower emittance. Detailed beam emittance measurements are presented in this paper.

  4. Probing the selective separation of potassium ion from sodium ion with cyclopentadienyl anion as receptor: a computational study.

    Science.gov (United States)

    Desai, Mittal L; Si, Mrinal Kanti; Lo, Rabindranath; Ganguly, Bishwajit

    2015-08-01

    A systematic computational study has been carried out using post-Hartree-Fock and density functional theory methods on half sandwich (M-Cp), sandwich (Cp-M-Cp), inversed sandwich (M-Cp-M), and multi-decker chain complexes of alkali metal ions (Na(+), and K(+)). The binding affinity of cyclopentadienyl anion (Cp) with K(+) and Na(+) ions has been studied in half sandwich, sandwich, inversed sandwich, and multi-decker chain complexes. These complexes have been examined in the aqueous phase. The calculated results show that Cp anion can preferentially bind with Na(+) ion over K(+) ion in aqueous phase. The results obtained from DFT calculations have been compared with the crystal structures of Cp-Na and Cp-K complexes. The Bader's atoms in molecule (AIM) analysis were performed to characterize the non-covalent cation-π interactions in the Cp-M complexes. The calculated electron density at cage critical point indicates the strength of the Cp-M complexes. Energy decomposition analysis (EDA) has also been performed to investigate the origins of these interactions. The electrostatic interaction contributes significantly to the total interaction energy in Cp-M complexes. The relative stability difference of cyclopentadienyl anion (Cp) with K(+) and Na(+) ions in aqueous phase can be exploited for the separations from mixture such as sea bittern. The lower stability of K-Cp complex can induce to precipitate the K(+) ions more easily than the corresponding Na(+) ions. Graphical Abstract Potassium ion from sodium ion with cyclopentadienyl anion as receptor.

  5. Studies of transition states and radicals by negative ion photodetachment

    Energy Technology Data Exchange (ETDEWEB)

    Metz, Ricardo Baer [Univ. of California, Berkeley, CA (United States)

    1991-12-01

    Negative ion photodetachment is a versatile tool for the production and study of transient neutral species such as reaction intermediates and free radicals. Photodetachment of the stable XHY- anion provides a direct spectroscopic probe of the transition state region of the potential energy surface for the neutral hydrogen transfer reaction X + HY → XH + Y, where X and Y are halogen atoms. The technique is especially sensitive to resonances, which occur at a specific energy, but the spectra also show features due to direct scattering. We have used collinear adiabatic simulations of the photoelectron spectra to evaluate trail potential energy surfaces for the biomolecular reactions and have extended the adiabatic approach to three dimensions and used it to evaluate empirical potential energy surfaces for the I + Hl and Br + HI reactions. In addition, we have derived an empirical, collinear potential energy surface for the Br + HBr reaction that reproduces our experimental results and have extended this surface to three dimensions. Photodetachment of a negative ion can be also used to study neutral free radicals. We have studied the vibrational and electronic spectroscopy of CH2NO2 by photoelectron spectroscopy of CH2NO2-, determining the electron affinity of CH2NO2, gaining insight on the bonding of the 2B1 ground state and observing the 2A2 excited state for the first time. Negative ion photodetachment also provides a novel and versatile source of mass-selected, jet-cooled free radicals. We have studied the photodissociation of CH2NO2 at 270, 235, and 208 nm, obtaining information on the dissociation products by measuring the kinetic energy release in the photodissociation.

  6. Studies of transition states and radicals by negative ion photodetachment

    Energy Technology Data Exchange (ETDEWEB)

    Metz, R.B.

    1991-12-01

    Negative ion photodetachment is a versatile tool for the production and study of transient neutral species such as reaction intermediates and free radicals. Photodetachment of the stable XHY{sup {minus}} anion provides a direct spectroscopic probe of the transition state region of the potential energy surface for the neutral hydrogen transfer reaction X + HY {yields} XH + Y, where X and Y are halogen atoms. The technique is especially sensitive to resonances, which occur at a specific energy, but the spectra also show features due to direct scattering. We have used collinear adiabatic simulations of the photoelectron spectra to evaluate trail potential energy surfaces for the biomolecular reactions and have extended the adiabatic approach to three dimensions and used it to evaluate empirical potential energy surfaces for the I + Hl and Br + HI reactions. In addition, we have derived an empirical, collinear potential energy surface for the Br + HBr reaction that reproduces our experimental results and have extended this surface to three dimensions. Photodetachment of a negative ion can be also used to study neutral free radicals. We have studied the vibrational and electronic spectroscopy of CH{sub 2}NO{sub 2} by photoelectron spectroscopy of CH{sub 2}NO{sub 2}{sup {minus}}, determining the electron affinity of CH{sub 2}NO{sub 2}, gaining insight on the bonding of the {sup 2}B{sub 1} ground state and observing the {sup 2}A{sub 2} excited state for the first time. Negative ion photodetachment also provides a novel and versatile source of mass-selected, jet-cooled free radicals. We have studied the photodissociation of CH{sub 2}NO{sub 2} at 270, 235, and 208 nm, obtaining information on the dissociation products by measuring the kinetic energy release in the photodissociation.

  7. Flexible, solid-state, ion-conducting membrane with 3D garnet nanofiber networks for lithium batteries

    Science.gov (United States)

    Fu, Kun (Kelvin); Gong, Yunhui; Dai, Jiaqi; Gong, Amy; Han, Xiaogang; Yao, Yonggang; Wang, Chengwei; Wang, Yibo; Chen, Yanan; Yan, Chaoyi; Li, Yiju; Wachsman, Eric D.; Hu, Liangbing

    2016-01-01

    Beyond state-of-the-art lithium-ion battery (LIB) technology with metallic lithium anodes to replace conventional ion intercalation anode materials is highly desirable because of lithium’s highest specific capacity (3,860 mA/g) and lowest negative electrochemical potential (∼3.040 V vs. the standard hydrogen electrode). In this work, we report for the first time, to our knowledge, a 3D lithium-ion–conducting ceramic network based on garnet-type Li6.4La3Zr2Al0.2O12 (LLZO) lithium-ion conductor to provide continuous Li+ transfer channels in a polyethylene oxide (PEO)-based composite. This composite structure further provides structural reinforcement to enhance the mechanical properties of the polymer matrix. The flexible solid-state electrolyte composite membrane exhibited an ionic conductivity of 2.5 × 10−4 S/cm at room temperature. The membrane can effectively block dendrites in a symmetric Li | electrolyte | Li cell during repeated lithium stripping/plating at room temperature, with a current density of 0.2 mA/cm2 for around 500 h and a current density of 0.5 mA/cm2 for over 300 h. These results provide an all solid ion-conducting membrane that can be applied to flexible LIBs and other electrochemical energy storage systems, such as lithium–sulfur batteries. PMID:27307440

  8. Artificial neural network applications in ionospheric studies

    Directory of Open Access Journals (Sweden)

    L. R. Cander

    1998-06-01

    Full Text Available The ionosphere of Earth exhibits considerable spatial changes and has large temporal variability of various timescales related to the mechanisms of creation, decay and transport of space ionospheric plasma. Many techniques for modelling electron density profiles through entire ionosphere have been developed in order to solve the "age-old problem" of ionospheric physics which has not yet been fully solved. A new way to address this problem is by applying artificial intelligence methodologies to current large amounts of solar-terrestrial and ionospheric data. It is the aim of this paper to show by the most recent examples that modern development of numerical models for ionospheric monthly median long-term prediction and daily hourly short-term forecasting may proceed successfully applying the artificial neural networks. The performance of these techniques is illustrated with different artificial neural networks developed to model and predict the temporal and spatial variations of ionospheric critical frequency, f0F2 and Total Electron Content (TEC. Comparisons between results obtained by the proposed approaches and measured f0F2 and TEC data provide prospects for future applications of the artificial neural networks in ionospheric studies.

  9. Mobile-ip Aeronautical Network Simulation Study

    Science.gov (United States)

    Ivancic, William D.; Tran, Diepchi T.

    2001-01-01

    NASA is interested in applying mobile Internet protocol (mobile-ip) technologies to its space and aeronautics programs. In particular, mobile-ip will play a major role in the Advanced Aeronautic Transportation Technology (AATT), the Weather Information Communication (WINCOMM), and the Small Aircraft Transportation System (SATS) aeronautics programs. This report presents the results of a simulation study of mobile-ip for an aeronautical network. The study was performed to determine the performance of the transmission control protocol (TCP) in a mobile-ip environment and to gain an understanding of how long delays, handoffs, and noisy channels affect mobile-ip performance.

  10. Synthesis of polyacrylate/polyethylene glycol interpenetrating network hydrogel and its sorption of heavy-metal ions

    Directory of Open Access Journals (Sweden)

    Qunwei Tang, Xiaoming Sun, Qinghua Li, Jihuai Wu and Jianming Lin

    2009-01-01

    Full Text Available A simple two-step aqueous polymerization method was introduced to synthesize a polyacrylate/polyethylene glycol (PAC/PEG interpenetrating network (IPN hydrogel. On the basis of the effects of the ratio of PAC to PEG, neutralization degree, heavy-metal ion concentration, and temperature on the adsorption behavior of PAC/PEG IPN hydrogel toward Ni2 +, Cr3 + and Cd2 +, the preparation conditions were optimized. In our system, the greatest amount of Ni2 +, Cr3 + and Cd2 + adsorbed were 102.34, 49.38 and 33.41 mg g- 1, respectively. The adsorption abilities of a dried PAC/PEG composite and a swollen PAC/PEG IPN hydrogel were compared. It was found that the efficiency of removing metal ions using the swollen hydrogel was greater than that using the dried composite. The adsorption mechanism and model are also discussed.

  11. Proton-Ion Medical Machine Study (PIMMS), 1

    CERN Document Server

    Badano, L; Benedikt, Michael; Bryant, P J; Crescenti, M; Holy, P; Maier, A T; Pullia, M; Rossi, S; Knaus, P

    2000-01-01

    The Proton-Ion Medical Machine Study (PIMMS) group was formed following an agreement between the Med-AUSTRON (Austria) and the TERA Foundation (Italy) to combine their efforts in the design of a cancer therapy synchrotron. CERN agreed to host this study in its PS Division and a close collaboration was set up with GSI (Germany). The study group was later joined by Onkologie-2000 (Czech Republic). Effort was first focused on the theoretical understanding of slow extraction and the techniques required to produce a smooth beam spill for the conformal treatment of complex-shaped tumours with a sub-millimetre accuracy by active scanning with proton and carbon ion beams. Considerations for passive scanning were also included. The more general and theoretical aspects of the study are recorded in Part I and the more specific technical design considerations are presented in a second volume Part II. The PIMMS team started their work in January 1996 in the PS Division and continued for a period of three years.

  12. Dedicated medical ion accelerator design study. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1977-12-01

    Results and conclusions are reported from a design study for a dedicated medical accelerator. Basing efforts on the current consensus regarding medical requirements, the resulting demands on accelerator and beam delivery systems were analyzed, and existing accelerator technology was reviewed to evaluate the feasibility of meeting these demands. This general analysis was augmented and verified by preparing detailed preliminary designs for sources of therapeutic beams of neutrons, protons and heavy ions. The study indicates that circular accelerators are the most desirable and economical solutions for such sources. Synchrotrons are clearly superior for beams of helium and heavier ions, while synchrotrons and cyclotrons seem equally well suited for protons although they have different strengths and weaknesses. Advanced techniques of beam delivery are of utmost importance in fully utilizing the advantages of particle beams. Several issues are invloved here. First, multi-treatment room arrangements are essential for making optimal use of the high dose rate capabilities of ion accelerators. The design of corresponding beam switching systems, the principles of which are already developed for physics experimental areas, pose no problems. Second, isocentric beam delivery substantially enhances flexibility of dose delivery. After several designs for such devices were completed, it was concluded that high field magnets are necessary to keep size, bulk and cost acceptable. Third, and most important, is the generation of large, homogeneous radiation fields. This is presently accomplished with the aid of scattering foils, occluding rings, collimators, ridge filters, and boluses. A novel approach, three-dimensional beam scanning, was developed here, and the most demanding components of such a system (fast-scanning magnet and power supply) were built and tested.

  13. Study of Tools for Network Discovery and Network Mapping

    Science.gov (United States)

    2003-11-01

    DISCOVERY OptiView Console supports central and distributed architectures. OptiView Console consists of the Viewer and the Service Manager that...OptiView console. Service Manager is the engine that performs network discovery, data management, data analysis, and provides notification services...The Service Manager gives you status information and configuration control of the services that are part of the OptiView Console application. These

  14. Electrochemical and thermal studies of lithium ion batteries

    Science.gov (United States)

    Lu, Wenquan

    The structural, electrochemical, and thermal characteristics of carbonaceous anodes and LiNi0.8Co0.2O2 cathode in Li-ion cells were investigated using various electrochemical and calorimetric techniques. The electrode-electrolyte interface was investigated for various carbonaceous materials such as graphite with different shapes, surface modified graphite with copper, and novel carbon material derived from sepiolite template. The structural and morphological properties were determined using XRD, TGA, SEM, BET techniques. The electrochemical characteristics were studied using conventional electrochemical techniques such as galvanostatic charge/discharge cycling, cyclic voltammetry, and impedance (AC and DC) methods. It was observed that the electrochemical active surface area instead of the BET area plays a critical role in the irreversible capacity loss associated with the carbonaceous anodes. It was also found that the exfoliation of carbon anodes especially in PC based electrolyte could be significantly reduced by protective copper coating of the natural graphite. LiNi0.8Co0.2O2 cathode material was found to possess high energy density and excellent cycling characteristics. The structural and electrochemical properties of LiNi0.8Co 0.2O2 synthesized by sol-gel and solid-state methods were studied. Results of the AC impedance spectroscopy carried out on LiNi 0.8Co0.2O2 cathodes revealed that the charge transfer resistance is a function of the state of charge. The solid state Li + diffusion was calculated to be around 10-13 cm2/s in the oxide particle by Warburg impedance method. In addition, the cell fabricated with LiNi0.8Co0.2O 2 cathode showed excellent energy and power performance under static and dynamic load conditions that prevail in Electric and Hybrid Vehicles. Thermal properties of the LiNi0.8Co0.2O2 cathode, carbonaceous anodes, and Li-ion cells fabricated with these electrodes were also investigated using isothermal microcalorimetry (IMC), differential

  15. Entrepreneurs Network of Networks: studying entrepreneurs social netwerk using smart-phone data

    NARCIS (Netherlands)

    Song, Y.; Vinig, T.

    2010-01-01

    Entrepreneurs are embedded in multiple networks, from which they seek opportunities and resources to start-up businesses. Adopting a network perspective to study entrepreneurship may contribute to our understanding of why some entrepreneurs succeed while others fail. However, as most social network

  16. Studying Fin Whales with Seafloor Seismic Networks

    Science.gov (United States)

    Wilcock, W. S.; Soule, D. C.; Weirathmueller, M.; Thomson, R.

    2011-12-01

    Baleen whales are found throughout the world's oceans and their welfare captivates the general public. Depending on the species, baleen whales vocalize at frequencies ranging from ~10 Hz to several kilohertz. Passive acoustic studies of whale calls are used to investigate behavior and habitat usage, monitor the recovery of populations from whaling and assess the impacts of anthropogenic sounds. Since airguns are a significant source of sound in the oceans, the research goals of academic seismologists can lead to conflicts with those who advocate for whale conservation while being unwilling to consider the societal benefits of marine geophysical studies. In contrast, studies that monitor earthquakes with ocean bottom seismometers (OBSs) provide an opportunity to enhance studies of baleen whales and improve relationships with environmental advocates. The bandwidth of the typical high-frequency or intermediate-band ocean bottom seismometer overlaps the call frequency of the two largest baleen whale species; blue whales generate sequences of 10- to 20-s-long calls centered at ~16 Hz and fin whales produce long sequences of downswept 1-s-long chirps centered at ~20 Hz. Several studies have demonstrated the potential of OBS networks to monitor calling patterns and determine tracks for fin and blue whales. We will summarize the results from a study to track fin whales near the Endeavour hydrothermal vent fields on the Juan de Fuca Ridge and investigate a potential correlation between the density of whales and enhanced zooplankton found throughout the water column overlying the vent fields. From 2003-2006 an 8-station local seismic network that was designed to monitor hydrothermal earthquakes also recorded ~300,000 fin whale vocalizations, mostly in the fall and winter. Automatic picking and localization techniques that are analogous to those used to analyze earthquakes are employed to determine whale tracks. The tracks are then used to interpret calling patterns in the

  17. Do governance choices matter in health care networks?: an exploratory configuration study of health care networks

    Science.gov (United States)

    2013-01-01

    Background Health care networks are widely used and accepted as an organizational form that enables integrated care as well as dealing with complex matters in health care. However, research on the governance of health care networks lags behind. The research aim of our study is to explore the type and importance of governance structure and governance mechanisms for network effectiveness. Methods The study has a multiple case study design and covers 22 health care networks. Using a configuration view, combinations of network governance and other network characteristics were studied on the level of the network. Based on interview and questionnaire data, network characteristics were identified and patterns in the data looked for. Results Neither a dominant (or optimal) governance structure or mechanism nor a perfect fit among governance and other characteristics were revealed, but a number of characteristics that need further study might be related to effective networks such as the role of governmental agencies, legitimacy, and relational, hierarchical, and contractual governance mechanisms as complementary factors. Conclusions Although the results emphasize the situational character of network governance and effectiveness, they give practitioners in the health care sector indications of which factors might be more or less crucial for network effectiveness. PMID:23800334

  18. Do governance choices matter in health care networks?: an exploratory configuration study of health care networks.

    Science.gov (United States)

    Willem, Annick; Gemmel, Paul

    2013-06-24

    Health care networks are widely used and accepted as an organizational form that enables integrated care as well as dealing with complex matters in health care. However, research on the governance of health care networks lags behind. The research aim of our study is to explore the type and importance of governance structure and governance mechanisms for network effectiveness. The study has a multiple case study design and covers 22 health care networks. Using a configuration view, combinations of network governance and other network characteristics were studied on the level of the network. Based on interview and questionnaire data, network characteristics were identified and patterns in the data looked for. Neither a dominant (or optimal) governance structure or mechanism nor a perfect fit among governance and other characteristics were revealed, but a number of characteristics that need further study might be related to effective networks such as the role of governmental agencies, legitimacy, and relational, hierarchical, and contractual governance mechanisms as complementary factors. Although the results emphasize the situational character of network governance and effectiveness, they give practitioners in the health care sector indications of which factors might be more or less crucial for network effectiveness.

  19. Langmuir probe studies on a RF ion source for NBI

    Energy Technology Data Exchange (ETDEWEB)

    McNeely, P. E-mail: p.mcneely@ipp.mpg.de; Heineman, B.; Kraus, W.; Riedl, R.; Speth, E.; Vollmer, O

    2001-10-01

    IPP Garching has been developing a RF ion source for H{sup -} production. In order to improve the data quality a new scanning probe system with passive RF compensation has been installed on the Type VI ion source on the BATMAN test stand. Using this probe, measurements have been carried out to study changes to the plasma parameters (electron density, electron temperature, and plasma potential) due to variation in the source operating conditions. The data were collected at a source pressure of 0.5 Pa and with 60{+-}5 kW applied RF power. Presented are some of the results of these measurements, focusing on the effect of: argon seeding, addition of Cs to the source, and the newly added Faraday screen. The electron density behaves in a fashion that agrees with the theory of ambipolar diffusion. Typically there is little change to the average electron energy observed regardless of which effect is considered. The plasma potential shows the most significant changes with external source conditions, both in value for all cases and shape when the Faraday screen was added.

  20. Solution synthesis of lead seeded germanium nanowires and branched nanowire networks and their application as Li-ion battery anodes

    Science.gov (United States)

    Flynn, Grace; Palaniappan, Kumaranand; Sheehan, Martin; Kennedy, Tadhg; Ryan, Kevin M.

    2017-06-01

    Herein, we report the high density growth of lead seeded germanium nanowires (NWs) and their development into branched nanowire networks suitable for application as lithium ion battery anodes. The synthesis of the NWs from lead seeds occurs simultaneously in both the liquid zone (solution-liquid-solid (SLS) growth) and solvent rich vapor zone (vapor-liquid-solid (VLS) growth) of a high boiling point solvent growth system. The reaction is sufficiently versatile to allow for the growth of NWs directly from either an evaporated catalyst layer or from pre-defined nanoparticle seeds and can be extended to allowing extensive branched nanowire formation in a secondary reaction where these seeds are coated onto existing wires. The NWs are characterized using TEM, SEM, XRD and DF-STEM. Electrochemical analysis was carried out on both the single crystal Pb-Ge NWs and the branched Pb-Ge NWs to assess their suitability for use as anodes in a Li-ion battery. Differential capacity plots show both the germanium wires and the lead seeds cycle lithium and contribute to the specific capacity that is approximately 900 mAh g-1 for the single crystal wires, rising to approximately 1100 mAh g-1 for the branched nanowire networks.

  1. Modelling third harmonic ion cyclotron acceleration of deuterium beams for JET fusion product studies experiments

    DEFF Research Database (Denmark)

    Schneider, M.; Johnson, T.; Dumont, R.

    2016-01-01

    Recent JET experiments have been dedicated to the studies of fusion reactions between deuterium (D) and Helium-3 (3He) ions using neutral beam injection (NBI) in synergy with third harmonic ion cyclotron radio-frequency heating (ICRH) of the beam. This scenario generates a fast ion deuterium tail...

  2. Multifunctional semi-interpenetrating polymer network-nanoencapsulated cathode materials for high-performance lithium-ion batteries.

    Science.gov (United States)

    Kim, Ju-Myung; Park, Jang-Hoon; Lee, Chang Kee; Lee, Sang-Young

    2014-04-08

    As a promising power source to boost up advent of next-generation ubiquitous era, high-energy density lithium-ion batteries with reliable electrochemical properties are urgently requested. Development of the advanced lithium ion-batteries, however, is staggering with thorny problems of performance deterioration and safety failures. This formidable challenge is highly concerned with electrochemical/thermal instability at electrode material-liquid electrolyte interface, in addition to structural/chemical deficiency of major cell components. Herein, as a new concept of surface engineering to address the abovementioned interfacial issue, multifunctional conformal nanoencapsulating layer based on semi-interpenetrating polymer network (semi-IPN) is presented. This unusual semi-IPN nanoencapsulating layer is composed of thermally-cured polyimide (PI) and polyvinyl pyrrolidone (PVP) bearing Lewis basic site. Owing to the combined effects of morphological uniqueness and chemical functionality (scavenging hydrofluoric acid that poses as a critical threat to trigger unwanted side reactions), the PI/PVP semi-IPN nanoencapsulated-cathode materials enable significant improvement in electrochemical performance and thermal stability of lithium-ion batteries.

  3. Adaptive prognosis of lithium-ion batteries based on the combination of particle filters and radial basis function neural networks

    Science.gov (United States)

    Sbarufatti, Claudio; Corbetta, Matteo; Giglio, Marco; Cadini, Francesco

    2017-03-01

    Lithium-Ion rechargeable batteries are widespread power sources with applications to consumer electronics, electrical vehicles, unmanned aerial and spatial vehicles, etc. The failure to supply the required power levels may lead to severe safety and economical consequences. Thus, in view of the implementation of adequate maintenance strategies, the development of diagnostic and prognostic tools for monitoring the state of health of the batteries and predicting their remaining useful life is becoming a crucial task. Here, we propose a method for predicting the end of discharge of Li-Ion batteries, which stems from the combination of particle filters with radial basis function neural networks. The major innovation lies in the fact that the radial basis function model is adaptively trained on-line, i.e., its parameters are identified in real time by the particle filter as new observations of the battery terminal voltage become available. By doing so, the prognostic algorithm achieves the flexibility needed to provide sound end-of-discharge time predictions as the charge-discharge cycles progress, even in presence of anomalous behaviors due to failures or unforeseen operating conditions. The method is demonstrated with reference to actual Li-Ion battery discharge data contained in the prognostics data repository of the NASA Ames Research Center database.

  4. A study of light ion accelerators for cancer treatment

    Energy Technology Data Exchange (ETDEWEB)

    Prelec, K.

    1997-07-01

    This review addresses several issues, such as possible advantages of light ion therapy compared to protons and conventional radiation, the complexity of such a system and its possible adaptation to a hospital environment, and the question of cost-effectiveness compared to other modalities for cancer treatment or to other life saving procedures. Characteristics and effects of different types of radiation on cells and organisms will be briefly described; this will include conventional radiation, protons and light ions. The status of proton and light ion cancer therapy will then be described, with more emphasis on the latter; on the basis of existing experience the criteria for the use of light ions will be listed and areas of possible medical applications suggested. Requirements and parameters of ion beams for cancer treatment will then be defined, including ion species, energy and intensity, as well as parameters of the beam when delivered to the target (scanning, time structure, energy spread). Possible accelerator designs for light ions will be considered, including linear accelerators, cyclotrons and synchrotrons and their basic features given; this will be followed by a review of existing and planned facilities for light ions. On the basis of these considerations a tentative design for a dedicated light ion facility will be suggested, a facility that would be hospital based, satisfying the clinical requirements, simple to operate and reliable, concluding with its cost-effectiveness in comparison with other modalities for treatment of cancer.

  5. Heavy-ion physics studies for the Future Circular Collider

    CERN Document Server

    Armesto, Nestor; d'Enterria, David; Masciocchi, Silvia; Roland, Christof; Salgado, Carlos; van Leeuwen, Marco; Wiedemann, Urs

    2014-01-01

    The Future Circular Collider (FCC) design study is aimed at assessing the physics potential and the technical feasibility of a new collider with centre-of-mass energies, in the hadron-hadron collision mode including proton and nucleus beams, more than seven-times larger than the nominal LHC energies. An electron-positron collider in the same tunnel is also considered as an intermediate step, which would provide the electron-hadron option in the long term. First ideas on the physics opportunities with heavy ions at the FCC are presented, covering the physics of Quark-Gluon Plasma, gluon saturation, photon-induced collisions, as well as connections with ultra-high-energy cosmic rays.

  6. Heavy-ion physics studies for the Future Circular Collider

    Energy Technology Data Exchange (ETDEWEB)

    Armesto, N. [Departamento de Física de Partículas and IGFAE, Universidade de Santiago de Compostela, 15706 Santiago de Compostela, Galicia (Spain); Dainese, A., E-mail: andrea.dainese@pd.infn.it [INFN — Sezione di Padova, 35131 Padova (Italy); D' Enterria, D. [Physics Department, CERN, CH-1211 Genéve 23 (Switzerland); Masciocchi, S. [EMMI and GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, Darmstadt (Germany); Roland, C. [Massachusetts Institute of Technology, Cambridge, MA 02139-4307 (United States); Salgado, C.A. [Departamento de Física de Partículas and IGFAE, Universidade de Santiago de Compostela, 15706 Santiago de Compostela, Galicia (Spain); Leeuwen, M. van [Nikhef, National Institute for Subatomic Physics and Institute for Subatomic Physics of Utrecht University, Utrecht (Netherlands); Wiedemann, U.A. [Physics Department, CERN, CH-1211 Genéve 23 (Switzerland)

    2014-11-15

    The Future Circular Collider (FCC) design study is aimed at assessing the physics potential and the technical feasibility of a new collider with centre-of-mass energies, in the hadron–hadron collision mode including proton and nucleus beams, more than seven times larger than the nominal LHC energies. An electron–positron collider in the same tunnel is also considered as an intermediate step, which in the long term would allow for electron–hadron collisions. First ideas on the physics opportunities with heavy ions at the FCC are presented, covering the physics of quark–gluon plasma, gluon saturation, photon-induced collisions, as well as connections with the physics of ultra-high-energy cosmic rays.

  7. Studies on the radio frequency power supply system for the ITER NB injector ion source

    Energy Technology Data Exchange (ETDEWEB)

    Gaio, E. [Consorzio RFX-Associazione EURATOM-ENEA sulla Fusione, C.so Stati Uniti 4, 35127 Padova (Italy)], E-mail: elena.gaio@igi.cnr.it; Kraus, W.; Martens, C. [Max-Planck-Institut fuer Plasmaphysik, Postfach 1533, D-85740 Garching (Germany); Piovan, R. [Consorzio RFX-Associazione EURATOM-ENEA sulla Fusione, C.so Stati Uniti 4, 35127 Padova (Italy); Speth, E. [Max-Planck-Institut fuer Plasmaphysik, Postfach 1533, D-85740 Garching (Germany); Toigo, V. [Consorzio RFX-Associazione EURATOM-ENEA sulla Fusione, C.so Stati Uniti 4, 35127 Padova (Italy)

    2007-10-15

    In the framework of the European activities on the ITER neutral beam (NB) injector, the design of a 1 MHz, 1 MW power supply (PS) system for the radio frequency (RF) driven ion source, has been developed in cooperation between IPP and RFX laboratories. This paper describes the studies performed with particular emphasis on the system design, the definition of the best modularity level to be adopted and the integration of the RF PS in the overall power supply system of the NB injector. Dedicated analyses were addressed to the RF matching network optimization which led to an improved and simplified solution without both matching transformers and remotely controlled variable capacitors in the source.

  8. An Adaptive Recurrent Neural Network for Remaining Useful Life Prediction of Lithium-ion Batteries

    Science.gov (United States)

    2010-10-01

    application for RUL prediction. We compare its performance with the classical recurrent neural network (RNN) and the recurrent neural fuzzy system ...Jang (1993). ANFIS: adaptive-network-based fuzzy inference system , IEEE Transactions on Systems , Man, and Cybernetics-Part B: Cybernetics, vol. 23...pp. 665-685, 1993. J. Jang, C. T. Sun, and E. Mizutani (1997). Neuro - Fuzzy and Soft Computing: A computational approach to learning and machine

  9. Dividing to unveil protein microheterogeneities: traveling wave ion mobility study.

    Science.gov (United States)

    Halgand, F; Habchi, Johnny; Cravello, Laetitia; Martinho, Marlène; Guigliarelli, Bruno; Longhi, Sonia

    2011-10-01

    Overexpression of a protein in a foreign host is often the only route toward an exhaustive characterization, especially when purification from the natural source(s) is hardly achievable. The key issue in these studies relies on quality control of the purified recombinant protein to precisely determining its identity as well as any undesirable microheterogeneities. While standard proteomics approaches preclude unbiased search for modifications, the optional technique of top-down tandem mass spectrometry (MSMS) requires the use of highly accurate and highly resolved experiments to reveal subtle sequence modifications. In the present study, the top-down MSMS approach combined with traveling wave ion mobility (TWIM) separation was evaluated for its ability to achieve high sequence coverage and to reveal subtle microheterogeneities that were hitherto only accessible with Fourier-transform ion cyclotron resonance-MS instruments. The power of this approach is herein illustrated in an in-depth analysis of both the wild type and K496C variant of the recombinant X domain (XD; aa's 459-507) of the measles virus phosphoprotein expressed in Escherichia coli . Using top-down MSMS combined with TWIM, we show that XD samples occasionally exhibit a microheterogeneity that could not be anticipated from the nucleotide sequence of the encoding constructs and that likely reflects a genetic drift, neutral or not, occurring during expression. In addition, a 1-oxyl-2,2,5,5-tetramethyl-δ3-pyrroline-3-methyl methanethiosulfonate nitroxide probe that was grafted onto the K496C XD variant was shown to undergo oxidation and/or protonation in the electrospray ionization source, leading to artifactual mass increases.

  10. Signaling Network of Environmental Sensing and Adaptation in Plants:. Key Roles of Calcium Ion

    Science.gov (United States)

    Kurusu, Takamitsu; Kuchitsu, Kazuyuki

    2011-01-01

    Considering the important issues concerning food, environment, and energy that humans are facing in the 21st century, humans mostly depend on plants. Unlike animals which move from an inappropriate environment, plants do not move, but rapidly sense diverse environmental changes or invasion by other organisms such as pathogens and insects in the place they root, and adapt themselves by changing their own bodies, through which they developed adaptability. Whole genetic information corresponding to the blueprints of many biological systems has recently been analyzed, and comparative genomic studies facilitated tracing strategies of each organism in their evolutional processes. Comparison of factors involved in intracellular signal transduction between animals and plants indicated diversification of different gene sets. Reversible binding of Ca2+ to sensor proteins play key roles as a molecular switch both in animals and plants. Molecular mechanisms for signaling network of environmental sensing and adaptation in plants will be discussed with special reference to Ca2+ as a key element in information processing.

  11. Study of Ion Acoustic Wave Damping through Green's Functions

    DEFF Research Database (Denmark)

    Hsuan, H.C.S.; Jensen, Vagn Orla

    1973-01-01

    Green's function analyses of ion acoustic waves in streaming plasmas show that, in general, the waves damp algebraically rather than exponentially with distance from exciter.......Green's function analyses of ion acoustic waves in streaming plasmas show that, in general, the waves damp algebraically rather than exponentially with distance from exciter....

  12. Photoluminescence and Raman studies in swift heavy ion irradiated ...

    Indian Academy of Sciences (India)

    Administrator

    Swift heavy ions (SHI) cause intense electronic excita- tions along the ion trajectory when they pass through material that may result in defect production or amorphiza- tion or phase transformation on nanometer scale (Bolse et al 2004; Wang et al 2004). Thus, it is interesting to know the effect of strong electronic excitation ...

  13. Metal Ion Selectivity of Kojate Complexes: A Theoretical Study

    Directory of Open Access Journals (Sweden)

    Sarita Singh

    2013-01-01

    Full Text Available Density functional calculations have been performed on four-coordinate kojate complexes of selected divalent metal ions in order to determine the affinity of the metal ions for the kojate ion. The complexation reactions are characterized by high energies, showing that they are highly exothermic. It is found that Ni(II exhibits the highest affinity for the kojate ion, and this is attributed to the largest amount of charge transfer from the ligand to the metal ion. The Ni(II complex has distorted square planar structure. The HOMOs and LUMOs of the complexes are also discussed. All complexes display a strong band at ~1500 cm−1 corresponding to the stretching frequency of the weakened carbonyl bond. Comparison of the complexation energies for the two steps shows that most of the complexation energy is realized in the first step. The energy released in the second step is about one-third that of the first step.

  14. Reverse Engineering of Gene Regulatory Networks: A Comparative Study

    Directory of Open Access Journals (Sweden)

    Hache Hendrik

    2009-01-01

    Full Text Available Reverse engineering of gene regulatory networks has been an intensively studied topic in bioinformatics since it constitutes an intermediate step from explorative to causative gene expression analysis. Many methods have been proposed through recent years leading to a wide range of mathematical approaches. In practice, different mathematical approaches will generate different resulting network structures, thus, it is very important for users to assess the performance of these algorithms. We have conducted a comparative study with six different reverse engineering methods, including relevance networks, neural networks, and Bayesian networks. Our approach consists of the generation of defined benchmark data, the analysis of these data with the different methods, and the assessment of algorithmic performances by statistical analyses. Performance was judged by network size and noise levels. The results of the comparative study highlight the neural network approach as best performing method among those under study.

  15. Study of nonlinear ion- and electron-acoustic waves in multi-component space plasmas

    Directory of Open Access Journals (Sweden)

    G. S. Lakhina

    2008-11-01

    Full Text Available Large amplitude ion-acoustic and electron-acoustic waves in an unmagnetized multi-component plasma system consisting of cold background electrons and ions, a hot electron beam and a hot ion beam are studied using Sagdeev pseudo-potential technique. Three types of solitary waves, namely, slow ion-acoustic, ion-acoustic and electron-acoustic solitons are found provided the Mach numbers exceed the critical values. The slow ion-acoustic solitons have the smallest critical Mach numbers, whereas the electron-acoustic solitons have the largest critical Mach numbers. For the plasma parameters considered here, both type of ion-acoustic solitons have positive potential whereas the electron-acoustic solitons can have either positive or negative potential depending on the fractional number density of the cold electrons relative to that of the ions (or total electrons number density. For a fixed Mach number, increases in the beam speeds of either hot electrons or hot ions can lead to reduction in the amplitudes of the ion-and electron-acoustic solitons. However, the presence of hot electron and hot ion beams have no effect on the amplitudes of slow ion-acoustic modes. Possible application of this model to the electrostatic solitary waves (ESWs observed in the plasma sheet boundary layer is discussed.

  16. Modelling third harmonic ion cyclotron acceleration of deuterium beams for JET fusion product studies experiments

    DEFF Research Database (Denmark)

    Schneider, M.; Johnson, T.; Dumont, R.

    2016-01-01

    Recent JET experiments have been dedicated to the studies of fusion reactions between deuterium (D) and Helium-3 (3He) ions using neutral beam injection (NBI) in synergy with third harmonic ion cyclotron radio-frequency heating (ICRH) of the beam. This scenario generates a fast ion deuterium tail...... ion diagnostics, showing an overall good agreement. Finally, a sawtooth activity for these experiments has been observed and interpreted using SPOT/RFOF simulations in the framework of Porcelli’s theoretical model, where NBI+ICRH accelerated ions are found to have a strong stabilizing effect, leading...

  17. Study of chromatographic characteristics of inorganic analytes in biopartitioning micellar chromatography with ion-pair additives.

    Science.gov (United States)

    Rukhadze, Marina; Lominadze, Nino; Akhalkatsi, Levan; Gvaramia, Manuchar

    2010-12-01

    The chromatographic behavior of model ions of biomedical and environmental significance was investigated by using nonionic micellar mobile phases modified with ion-pair additives. The influence of concentrations of polyoxyethylene (23) lauryl ether and ornithine hydrochloride in the mobile phase on the retention factors of chromium (III), chromium (VI), iodide and bromide ions was studied. The possible mechanisms of retention of the mentioned ions in biopartitioning micellar chromatography with zwitter ion-pair additives were proposed. Copyright © 2010 John Wiley & Sons, Ltd.

  18. A simple model for studying interacting networks

    Science.gov (United States)

    Liu, Wenjia; Jolad, Shivakumar; Schmittmann, Beate; Zia, R. K. P.

    2011-03-01

    Many specific physical networks (e.g., internet, power grid, interstates), have been characterized in considerable detail, but in isolation from each other. Yet, each of these networks supports the functions of the others, and so far, little is known about how their interactions affect their structure and functionality. To address this issue, we consider two coupled model networks. Each network is relatively simple, with a fixed set of nodes, but dynamically generated set of links which has a preferred degree, κ . In the stationary state, the degree distribution has exponential tails (far from κ), an attribute which we can explain. Next, we consider two such networks with different κ 's, reminiscent of two social groups, e.g., extroverts and introverts. Finally, we let these networks interact by establishing a controllable fraction of cross links. The resulting distribution of links, both within and across the two model networks, is investigated and discussed, along with some potential consequences for real networks. Supported in part by NSF-DMR-0705152 and 1005417.

  19. NMR methods for studying ion and molecular transport in polymer electrolytes

    Science.gov (United States)

    Volkov, V. I.; Marinin, A. A.

    2013-03-01

    Data demonstrating the potential of NMR methods in studying the formation of transport channels, the mechanisms of ion-polymer matrix interaction, the mobility and diffusion of ions and molecules in polymer electrolytes are analyzed and generalized. Ion-exchange membranes with polymer matrices of various chemical types are considered. The translational mobilities of ions measured by pulsed field gradient NMR are compared with the data on ionic conductivity acquired by impedance spectroscopy methods. Attention is focused on the possibilities of NMR methods in studying the state of ions and molecules in electrolytes and also their diffusional mobility on different spatial scales. Based on the NMR data, the mechanisms of ion transport in ion-exchange perfluorinated membranes are proposed. The bibliography includes 182 references.

  20. Optical band gap and spectroscopic study of lithium alumino silicate glass containing Y3+ ions.

    Science.gov (United States)

    Shakeri, M S; Rezvani, M

    2011-09-01

    The effect of different amounts of Y2O3 dopant on lithium alumino silicate (LAS) glass has been studied in this work. Glasses having 14.8Li2O-20Al2O3-65.2SiO2 (wt%) composition accompanied with Y2O3 dopant were prepared by normal melting process. In order to calculate the absorption coefficient of samples, transmittance and reflectance spectra of polished samples were measured in the room temperature. Optical properties i.e. Fermi energy level, direct and indirect optical band gaps and Urbach energy were calculated using functionality of extinction coefficient from Fermi-Dirac distribution function, Tauc's plot and the exponential part of absorption coefficient diagram, respectively. It has been clarified that variation in mentioned optical parameters is associated with the changes in physical properties of samples i.e. density or molar mass. On the other hand, increasing of Y3+ ions in the glassy microstructure of samples provides a semiconducting character to LAS glass by reducing the direct and indirect optical band gaps of glass samples from 1.97 to 1.67 and 3.46 to 2.1 (eV), respectively. These changes could be attributed to the role of Y3+ ions as the network former in the track of SiO4 tetrahedrals. Copyright © 2011 Elsevier B.V. All rights reserved.

  1. Si nanoparticle-decorated Si nanowire networks for Li-ion battery anodes

    KAUST Repository

    Hu, Liangbing

    2011-01-01

    We designed and fabricated binder-free, 3D porous silicon nanostructures for Li-ion battery anodes, where Si nanoparticles electrically contact current collectors via vertically grown silicon nanowires. When compared with a Si nanowire anode, the areal capacity was increased by a factor of 4 without having to use long, high temperature steps under vacuum that vapour-liquid-solid Si nanowire growth entails. © 2011 The Royal Society of Chemistry.

  2. Spatial Studies of Ion Beams in an Expanding Plasma

    Science.gov (United States)

    Aguirre, Evan; Good, Timothy; Scime, Earl; Thompson, Derek

    2017-10-01

    We report spatially resolved perpendicular and parallel ion velocity distribution function (IVDF) measurements in an expanding argon helicon plasma. The parallel IVDFs, obtained through laser induced fluorescence (LIF), show an ion beam with v 8 km/s flowing downstream that is confined to the center of the discharge. The ion beam is confined to within a few centimeters radially and is measurable for tens of centimeters axially before the LIF signal fades, likely a result of metastable quenching of the beam ions. The axial ion beam velocity slows in agreement with collisional processes. The perpendicular IVDFs show an ion population with a radially outward flow that increases with radial location. The DC electric field, electron temperature, and the plasma density in the double layer plume are all consistent with magnetic field aligned structures. The upstream and downstream electric field measurements show clear evidence of an ion hole that maps along the magnetic field at the edge of the plasma. Current theories and simulations of double layers, which are one-dimensional, completely miss these critically important two-dimensional features.

  3. Study on actinoids in boundary ion transfer from an aspect of solution chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Kihara, Sorin; Shirai, Makoto; Matsui, Masakazu [Kyoto Univ., Uji (Japan). Inst. for Chemical Research; Yoshida, Zenko; Aoyagi, Hisao; Kitatsuji, Yoshihiro

    1996-01-01

    This study aimed to elucidate the fundamental properties of boundary ion transfer between water (W) and organic solvent (O) and to apply the results to the study on actinoid ions. First, dissolved states of ion in W and O in relation to boundary transfer were investigated and the transfer stimulation effects by an addition of some agents which can induce their complex formation were examined. Then, a theoretical equation which expresses a relationship between ion-pair extraction reaction and {Delta}Gtr was proposed and proved with {Delta}Gtr of single ion obtained by the use of VITIES, which is an apparatus for voltammetric determination of boundary ion transfer developed by the authors. Single ion transfer in W/O was estimated from the voltammogram based on I-{Delta}V curve (I; electric current which corresponds to the amount of ion transfer and {Delta}V; phase boundary voltage). In addition, determination of actinoid ion transfer in W/O boundary was made by VITIES to clarify the ion transfer energy, velocity and transferred molecular species. Thus, developments of a new isolation method and a trial sensor for actinoid ions were undertaken based on these results. (M.N.)

  4. Fifth high-energy heavy-ion study

    Energy Technology Data Exchange (ETDEWEB)

    1981-10-01

    This was the fifth of a continuing series of summer studies held at LBL to discuss high energy heavy ion collisions. Recently, a similar meeting has been held on alternate years at GSI (Darmstadt); and, in 1979, we held a meeting at LBL exclusively devoted to ultra-relativistic nuclear collisions. Two new features distinguish this study from earlier meetings in the series. First, the energy range for discussion was broadened by including collisions from about 20 MeV/nucleon to the highest available in the cosmic radiation. The lower range, particularly below 100 MeV/nucleon, will be under intense study in the near future with machines such as the upgraded Bevalac, Michigan State University Superconducting Cyclotron, GANIL in France, and the SC at CERN. Recently, the high energy collision regime has been expanded by the successful operation of the CERN ISR with alpha particles. Second, in addition to an extensive program of invited talks, we decided for the first time to actively solicit contributions. Forty-seven individual items from the conference were prepared separately for the data base. (GHT)

  5. Deep Space Network information system architecture study

    Science.gov (United States)

    Beswick, C. A.; Markley, R. W. (Editor); Atkinson, D. J.; Cooper, L. P.; Tausworthe, R. C.; Masline, R. C.; Jenkins, J. S.; Crowe, R. A.; Thomas, J. L.; Stoloff, M. J.

    1992-01-01

    The purpose of this article is to describe an architecture for the DSN information system in the years 2000-2010 and to provide guidelines for its evolution during the 1990's. The study scope is defined to be from the front-end areas at the antennas to the end users (spacecraft teams, principal investigators, archival storage systems, and non-NASA partners). The architectural vision provides guidance for major DSN implementation efforts during the next decade. A strong motivation for the study is an expected dramatic improvement in information-systems technologies--i.e., computer processing, automation technology (including knowledge-based systems), networking and data transport, software and hardware engineering, and human-interface technology. The proposed Ground Information System has the following major features: unified architecture from the front-end area to the end user; open-systems standards to achieve interoperability; DSN production of level 0 data; delivery of level 0 data from the Deep Space Communications Complex, if desired; dedicated telemetry processors for each receiver; security against unauthorized access and errors; and highly automated monitor and control.

  6. A rotary nano ion pump: a molecular dynamics study.

    Science.gov (United States)

    Lohrasebi, A; Feshanjerdi, M

    2012-09-01

    The dynamics of a rotary nano ion pump, inspired by the F (0) part of the F(0)F(1)-ATP synthase biomolecular motor, were investigated. This nanopump is composed of a rotor, which is constructed of two carbon nanotubes with benzene rings, and a stator, which is made of six graphene sheets. The molecular dynamics (MD) method was used to simulate the dynamics of the ion nanopump. When the rotor of the nanopump rotates mechanically, an ion gradient will be generated between the two sides of the nanopump. It is shown that the ion gradient generated by the nanopump is dependant on parameters such as the rotary frequency of the rotor, temperature and the amounts and locations of the positive and negative charges of the stator part of the nanopump. Also, an electrical potential difference is generated between the two sides of the pump as a result of its operation.

  7. Social network analysis and network connectedness analysis for industrial symbiotic systems: model development and case study

    Science.gov (United States)

    Zhang, Yan; Zheng, Hongmei; Chen, Bin; Yang, Naijin

    2013-06-01

    An important and practical pattern of industrial symbiosis is rapidly developing: eco-industrial parks. In this study, we used social network analysis to study the network connectedness (i.e., the proportion of the theoretical number of connections that had been achieved) and related attributes of these hybrid ecological and industrial symbiotic systems. This approach provided insights into details of the network's interior and analyzed the overall degree of connectedness and the relationships among the nodes within the network. We then characterized the structural attributes of the network and subnetwork nodes at two levels (core and periphery), thereby providing insights into the operational problems within each eco-industrial park. We chose ten typical ecoindustrial parks in China and around the world and compared the degree of network connectedness of these systems that resulted from exchanges of products, byproducts, and wastes. By analyzing the density and nodal degree, we determined the relative power and status of the nodes in these networks, as well as other structural attributes such as the core-periphery structure and the degree of sub-network connectedness. The results reveal the operational problems created by the structure of the industrial networks and provide a basis for improving the degree of completeness, thereby increasing their potential for sustainable development and enriching the methods available for the study of industrial symbiosis.

  8. Electromigration study of focused ion beam modified metal lines

    Energy Technology Data Exchange (ETDEWEB)

    Lee, J.L.; Yao, D.H. [IBM Microelectronics Div., Essex Junction, VT (United States)

    1995-12-31

    Focus ion beam (FIB) technology is a commonly used tool for integrated circuit device modification, failure analysis, and a variety of other applications. However, limited reliability data of FIB altered circuit is available. This study describes the electromigration mechanism of FIB-altered Al(Cu-Si)/Ti-layered metal lines. The electromigration failures encountered resulted in Al voids at the anode end of FIB-deposited W and Al{sub 2}Cu precipitates at the cathode end. A higher frequency of Al extrusions was also observed on samples stressed at higher temperatures. These observations indicated that FIB-W was an effective blocking boundary for Al and Cu, and confirmed that Cu does electromigrate before Al. The electromigration mechanism of the FIB-altered line closely resembles the published results from two-level Al/W-line/stud interconnect studies. An activation energy of 0.66 eV, with a current exponent of 1.9 and a lognormal sigma of 0.55, was determined from the kinetic analysis of the FIB-altered metal line.

  9. Study of structural and spectroscopic behavior of Sm3+ ions in lead-zinc borate glasses containing alkali metal ions

    Science.gov (United States)

    Sasi Kumar, M. V.; Babu, S.; Rajeswara Reddy, B.; Ratnakaram, Y. C.

    2017-06-01

    High luminescence behavior of rare earth inorganic glasses have a variety of uses in the industry. In the past few decades, rare earth ions with characteristic photonics applications are being hosted by heavy metal oxide glasses. Among the rare earth ions Sm3+ ion has features which make it apt for high density optical storage. The authors of the paper have experimented to synthesize Sm3+ doped glasses. In this regard a new series of borate glasses doped with 1 mol% Sm3+ ion are developed by using melt-quenching technique. XRD, FTIR, optical absorption, luminescence techniques are used to study the various characteristics of Sm3+ ion in the present glass matrices. The XRD spectra confirms the amorphous nature of glasses. Further, the researchers have used differential thermal analysis to study the glass transition temperature. The structural groups in the prepared glasses are studied using Fourier transform infrared spectra. From the measurement of its optical absorption, three phenomenological Judd-Ofelt intensity parameters (Ω2, Ω4 and Ω6) have been computed. Based on these Judd-Ofelt intensity parameters, radiative properties such as radiative probabilities (Arad), branching ratios (β), and radiative life time (τR) are calculated. The excitation spectra of Sm3+ doped lithium heavy metal borate glass matrix is recorded under the emission wavelength of 600 nm. The emission spectra are recorded under 404 nm excitation wavelength. From various emission transitions, 4G5/2 → 6H7/2 and 4G5/2 → 6H9/2 bands could be of interest for various applications. The decay profiles of 4G5/2 level exhibit single exponential nature in all the prepared glass matrices. The potassium glass matrix exhibits higher quantum efficiency than the other glass matrices. Finally, by going through these several spectroscopic characterizations, it is concluded that the prepared Sm3+ doped lead-zinc borate glasses might be useful for visible light applications.

  10. Inter-organizational network studies – a literature review

    DEFF Research Database (Denmark)

    Bergenholtz, Carsten; Waldstrøm, Christian

    2011-01-01

    network analysis. However, this has not been without serious theoretical and ethodological issues. Most notably, a number of the concepts, methods and theories used within the field of inter-organizational networks originate from research in interpersonal and intra-organizational networks where some...... of the methodological issues (e.g. unit of analysis and boundary specification) are more easily addressed. In order to map the different methodological approaches in the field of inter-organizational networks, this paper presents a large-scale systematic literature review of the last 12 years’ research on inter......-organizational networks, with a focus on the methodological features. Some of the main variables relate to the unit of analysis, whether social network analysis is applied and what concept of a network is involved. The main findings of this paper are that few of the previous studies have used the full methodological (and...

  11. Photoconductivity studies of the ferrocyanide ion under high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Finston, M. I.

    1979-01-01

    The photoaquation of the ferrocyanide ion was studied using a high-pressure photoconductivity apparatus and a steady-state high-pressure mercury lamp. The first-order photocurrent rise-time could be related to the relative quantum efficiency of the photoaquation process, while the dark decay of the photocurrent yielded a relative value of the bimolecular rate-constant for the reverse reaction. Kinetic measurements were carried out on dilute solutions of potassium ferrocyanide in pure water, and in 20% ethanol. The photocurrent yield in aqueous solution was dependent upon secondary chemical equilibria which were sensitive to pressure in a predictable way. In ethanolic solution, the dependence of photocurrent yield on pressure followed the variation of the reciprocal solvent vicosity. In both aqueous and alcoholic solution, the photoaquation quantum efficiency decreased exponentially with pressure, as did the biomolecular rate-constant for the dark reaction in aqueous solution. The pressure dependence of the bimolecular rate-constant in the alcoholic solution indicated a diffusion-limited process. The pressure dependence of the photoaquation quantum yield, and of the bimolecular rate-constant in aqueous solution, was interpreted in terms of an activation volume model. The photoaquation data for both the aqueous and the alcoholic solutions agreed with a hypothetical mechanism whereby ligand-to-metal bond-breaking, and solvent-to-metal bond-formation, are effectively simultaneous. The results for the aqueous dark reaction strongly indicated breaking of the solvent-to-metal bond as the rate-limiting step.

  12. SAXS study of molybdenum irradiated with helium ions

    Science.gov (United States)

    Osamura, Kozo; Suzuki, Hideo

    1983-01-01

    Defects produced by helium ion irradiation have been investigated by means of small-angle X-ray scattering (SAXS) measurements, transmission electron microscope (TEM) and scanning electron microscope (SEM) observations. He + ions with projectile energy of 2 MeV were implanted in thin high-purity molybdenum foils with dose rates of 7-56 μA cm -2 up to total doses of 0.43-3.46 × 10 18 ions cm -2. The critical fluence producing blisters and the blister skin thickness were measured to be about 0.5 × 10 18 ions cm t-2 and 2.8 ± 0.4 μm, respectively, from SEM observations. Two types of bubbles were observed by TEM. The angular dependence of SAXS intensity was explained by the superposition of three Gaussian-shaped scattering curves, suggesting three different types of irradiation defects. Type II, which had a dimension of 4-7 nm, was identified with polygonal bubbles observed by TEM. This type appeared beyond the critical dose of 0.6 × 10 18 ions cm -2. Type III, which had a dimension of 0.6-2.7 nm, was identified with finer bubbles observed by TEM and distinguishable from type II. The SAXS results have been applied to evaluate quantitatively the kinetics of formation of these bubbles.

  13. High temperature annealing studies of strontium ion implanted glassy carbon

    Energy Technology Data Exchange (ETDEWEB)

    Odutemowo, O.S., E-mail: u12052613@tuks.co.za [Department of Physics, University of Pretoria, Pretoria 0002 (South Africa); Malherbe, J.B.; Prinsloo, L.; Langa, D.F. [Department of Physics, University of Pretoria, Pretoria 0002 (South Africa); Wendler, E. [Institut für Festkörperphysik, Friedrich-Schiller University, Jena (Germany)

    2016-03-15

    Glassy carbon samples were implanted with 200 keV strontium ions to a fluence of 2 × 10{sup 16} ions/cm{sup 2} at room temperature. Analysis with Raman spectroscopy showed that ion bombardment amorphises the glassy carbon structure. Partial recovery of the glassy carbon structure was achieved after the implanted sample was vacuum annealed at 900 °C for 1 h. Annealing the strontium ion bombarded sample at 2000 °C for 5 h resulted in recovery of the glassy carbon substrate with the intensity of the D peak becoming lower than that of the pristine glassy carbon. Rutherford backscattering spectroscopy (RBS) showed that the implanted strontium diffused towards the surface of the glassy carbon after annealing the sample at 900 °C. This diffusion was also accompanied by loss of the implanted strontium. Comparison between the as-implanted and 900 °C depth profiles showed that less than 30% of the strontium was retained in the glassy carbon after heat treatment at 900 °C. The RBS profile after annealing at 2000 °C indicated that no strontium ions were retained after heat treatment at this temperature.

  14. Study of multiple scattering effects in heavy ion RBS

    Energy Technology Data Exchange (ETDEWEB)

    Fang, Z.; O`Connor, D.J. [Newcastle Univ., NSW (Australia). Dept. of Physics

    1996-12-31

    Multiple scattering effect is normally neglected in conventional Rutherford Backscattering (RBS) analysis. The backscattered particle yield normally agrees well with the theory based on the single scattering model. However, when heavy incident ions are used such as in heavy ion Rutherford backscattering (HIRBS), or the incident ion energy is reduced, multiple scattering effect starts to play a role in the analysis. In this paper, the experimental data of 6MeV C ions backscattered from a Au target are presented. In measured time of flight spectrum a small step in front of the Au high energy edge is observed. The high energy edge of the step is about 3.4 ns ahead of the Au signal which corresponds to an energy {approx} 300 keV higher than the 135 degree single scattering energy. This value coincides with the double scattering energy of C ion undergoes two consecutive 67.5 degree scattering. Efforts made to investigate the origin of the high energy step observed lead to an Monte Carlo simulation aimed to reproduce the experimental spectrum on computer. As a large angle scattering event is a rare event, two consecutive large angle scattering is extremely hard to reproduce in a random simulation process. Thus, the simulation has not found a particle scattering into 130-140 deg with an energy higher than the single scattering energy. Obviously faster algorithms and a better physical model are necessary for a successful simulation. 16 refs., 3 figs.

  15. Symmetry Properties of Proton Velocity Distributions: a Vlasov Simulation Study of the Ion Cyclotron Instability

    Science.gov (United States)

    Araneda, J. A.; López, R. A.; Vinas, A. F.

    2014-12-01

    The ion cyclotron instability is driven by a sufficiently large proton temperature anisotropy, generating a spectrum of counterpropagating field-aligned ion cyclotron fluctuations. In this work, we use low-noise one-dimensional electromagnetic Vlasov simulations in a magnetized and collisionless plasma of fluid electrons and one ion species to study the evolution of proton velocity distributions during the thermal relaxation process. Special attention is given to deviations from initial bi-Maxwellian shapes.

  16. Transport Network Technologies – Study and Testing

    DEFF Research Database (Denmark)

    Bozorgebrahimi, K.; Channegowda, M.; Colmenero, A.

    Following on from the theoretical research into Carrier Class Transport Network Technologies (CCTNTs) documented in DJ1.1.1, this report describes the extensive testing performed by JRA1 Task 1. The tests covered EoMPLS, Ethernet OAM, Synchronous Ethernet, PBB-TE, MPLS-TP, OTN and GMPLS, and the ......Following on from the theoretical research into Carrier Class Transport Network Technologies (CCTNTs) documented in DJ1.1.1, this report describes the extensive testing performed by JRA1 Task 1. The tests covered EoMPLS, Ethernet OAM, Synchronous Ethernet, PBB-TE, MPLS-TP, OTN and GMPLS...

  17. Study of fluid mechanical helium argon ion laser

    Science.gov (United States)

    1972-01-01

    An approach to an argon ion laser based on gasdynamic techniques is presented. Improvement in efficiency and power output are achieved by eliminating high heat rejection problems and plasma confinement of the seal-off conventional lasers. The process of producing population inversion between the same energy levels, as in the conventional argon ion laser, has been divided into two phases by separating each other from the processes of ionization and subsequent excitation. Line drawings and graphs are included to amplify the theoretical presentation.

  18. A multi-satellite study of accelerated ionospheric ion beams above the polar cap

    Directory of Open Access Journals (Sweden)

    R. Maggiolo

    2006-07-01

    Full Text Available This paper presents a study of nearly field-aligned outflowing ion beams observed on the Cluster satellites over the polar cap. Data are taken at geocentric radial distances of the order of 5–9 RE. The distinction is made between ion beams originating from the polar cusp/cleft and beams accelerated almost along the magnetic field line passing by the spacecraft. Polar cusp beams are characterized by nearly field-aligned proton and oxygen ions with an energy ratio EO+ / EH+, of the order of 3 to 4, due to the ion energy repartition inside the source and to the latitudinal extension of the source. Rapid variations in the outflowing ion energy are linked with pulses/modifications of the convection electric field. Cluster data allow one to show that these perturbations of the convection velocity and the associated ion structures propagate at the convection velocity. In contrast, polar cap local ion beams are characterized by field-aligned proton and oxygen ions with similar energies. These beams show the typical inverted V structures usually observed in the auroral zone and are associated with a quasi-static converging electric field indicative of a field-aligned electric field. The field-aligned potential drop fits well the ion energy profile. The simultaneous observation of precipitating electrons and upflowing ions of similar energies at the Cluster orbit indicates that the spacecraft are crossing the mid-altitude part of the acceleration region. In the polar cap, the parallel electric field can thus extend to altitudes higher than 5 Earth radii. A detailed analysis of the distribution functions shows that the ions are heated during their parallel acceleration and that energy is exchanged between H+ and O+. Furthermore, intense electrostatic waves are observed simultaneously. These observations could be due to an ion-ion two-stream instability.

  19. Kinetic and equilibrium study for the sorption of Pb(II) ions from ...

    African Journals Online (AJOL)

    This paper reports the kinetic and equilibrium studies of Eichhornia crassipes root biomass as a biosorbent for Pb(II) ions from aqueous system. Batch adsorption studies were carried out to examine the influence of various parameters such as the pH, contact time, adsorbent dose, initial metal ion concentration, temperature ...

  20. Studies of Heavy-Ion Reactions and Transuranic Nuclei

    Energy Technology Data Exchange (ETDEWEB)

    Schroeder, W. Udo [Univ. of Rochester, NY (United States). Dept. of Chemistry. Dept. of Physics

    2016-07-28

    Studies of heavy-ion reactions and transuranic nuclei performed by the University of Rochester Nuclear Science Research Group have been successful in furthering experimental systematics and theoretical understanding of the behavior of nuclear systems excited to their limits of stability. The theoretical results explain specifically the “boiling” and “vaporization” of atomic nuclei, but are more generally applicable to isolated, quantal many-particle systems which, under thermal or mechanical stresses, all disintegrate by evaporation, via surface cluster emission, or via fission-like processes. Accompanying experimental investigations by the group have demonstrated several new types of dynamical instability of nuclei: In central, “head-on” collisions, target nuclei exhibit limited ability to stop energetic projectile nuclei and to dissipate the imparted linear momentum. Substantial matter overlap (“neck”) between projectile and target nuclei, which is observed at elevated collision energies, can be stretched considerably and break at several places simultaneously. These results provide new testing grounds for microscopic theory of the cohesion of nuclear matter. This property has remained elusive, even though the elementary nucleon-nucleon forces are well known since some time. Technical R&D has resulted in a detailed characterization of a novel plastic material, which can now be used in the design of sensitive diagnostic systems for various types of radio-activity. Innovative application of powerful laser systems has produced intense, controllable sources of exotic particle radioactivity for nuclear investigations. Several students have received their Ph.D. degree in experimental nuclear science for their work on basic nuclear research or R&D projects.

  1. Studies on a Q/A selector for the SECRAL electron cyclotron resonance ion source.

    Science.gov (United States)

    Yang, Y; Sun, L T; Feng, Y C; Fang, X; Lu, W; Zhang, W H; Cao, Y; Zhang, X Z; Zhao, H W

    2014-08-01

    Electron cyclotron resonance ion sources are widely used in heavy ion accelerators in the world because they are capable of producing high current beams of highly charged ions. However, the design of the Q/A selector system for these devices is challenging, because it must have a sufficient ion resolution while controlling the beam emittance growth. Moreover, this system has to be matched for a wide range of ion beam species with different intensities. In this paper, research on the Q/A selector system at the SECRAL (Superconducting Electron Cyclotron Resonance ion source with Advanced design in Lanzhou) platform both in experiment and simulation is presented. Based on this study, a new Q/A selector system has been designed for SECRAL II. The features of the new design including beam simulations are also presented.

  2. Prediction study on the degeneration of lithium-ion battery based on fuzzy inference system

    Science.gov (United States)

    Shi, Jian Ping

    2017-07-01

    The degradation degree prediction of lithium-ion battery has been studied through experimental data. Characterization parameters on the degradation degree of lithium-ion battery were deduced under consideration of the internal and external factors. The analysis of discrete degree was proposed to depict the degradation degree for lithium-ion battery. Furthermore, based on fuzzy inference system (FIS), the predicted model of the degradation degree for lithium-ion battery was built and its output was defined as the degenerate coefficient β, β ∈ [0, 1]. Finally, by learning, training and simulating, the FIS model has been validated to be reliable and applicable in prediction on the degradation degree of lithium-ion battery. The simulation results show that the degradation degree of lithium-ion battery is more serious when β is closer to 1, and the degradation degree is lighter when β is closer to 0.

  3. Measuring the dissimilarity of multiplex networks: An empirical study of international trade networks

    Science.gov (United States)

    Zhang, Xiaohang; Cui, Huiyuan; Zhu, Ji; Du, Yu; Wang, Qi; Shi, Wenhua

    2017-02-01

    In recent years, multiplex networks are becoming a research focus in the domain of complex networks. Discovering significant correlations between layers in multiplex networks can provide an insight to their structures. In this study, we propose some methods to measure the dissimilarities of different layers in directed and weighted multiplex networks. The dissimilarity is defined on two levels: node level and layer level. The node dissimilarity is computed based on the distance of the probability distribution of its link weights vectors in different layers; and the layer-level dissimilarity is the weighted sum of the nodes' dissimilarities. Furthermore, the dissimilarity is disintegrated into the connection-based dissimilarity and the weight-based dissimilarity, which represent the topological structure changes and the link weight changes, respectively. The proposed methods are applied to international trade networks.

  4. Physicochemical studies on ion-pair amphiphiles: Solution and ...

    Indian Academy of Sciences (India)

    Administrator

    cation potentials in the field of membrane mimick- ing systems, drug delivery, nanoparticle synthesis, etc. 4–10 ... The phase diagrams consist- ing of a micellar solution phase, and a liquid crystal- line phase (at higher ... madzu, Japan) using a matched pair of quartz cells of path length 1cm. The ion-pairs produced appre-.

  5. Equilibrium and kinetics studies of metal ion adsorption on dyed ...

    African Journals Online (AJOL)

    GREGO

    2007-04-02

    Apr 2, 2007 ... diffusion rate constant, Ka show that adsorption of metal ions is particle diffusion controlled. The adsorbent produced from coconut fibre can be used to remove heavy metals from aqueous solution with high efficiency. Key words: Adsorption dynamics, fractional attianment of equilibrium, intraparticle ...

  6. Absolute and Convective Ion Beam Instability Studied through Green's Function

    DEFF Research Database (Denmark)

    Jensen, Vagn Orla; Michelsen, Poul; Hsuan, H. C. S.

    1974-01-01

    A Vlasov plasma with a double‐humped, unstable ion velocity distribution function is considered. A δ function in space is assumed as the initial perturbation and the plasma response to this perturbation is calculated, i.e., the Green's function for the problem is found. The response can be divided...

  7. Upconversion studies in rare earth ions-doped lanthanide materials

    Indian Academy of Sciences (India)

    2014-02-08

    Feb 8, 2014 ... for direct vision applications. There are many applications of rare earth-doped materials. [1,2]. Er3+ ion has low photon absorption coefficient at around 976 nm. The 976 nm laser excitation wavelength is cheaply available and absorption of this wavelength in water is also low. Therefore, many researchers ...

  8. Thermodynamic studies on adsorption of lead (II) Ion from aqueous ...

    African Journals Online (AJOL)

    The instrumental techniques used for characterizing the adsorbents include Fourier Transform Infrared (FTIR), X –ray Fluorescence (XRF) and Scanning Electron Microscopy coupled with energy dispersive X-ray (SEM-EDX). The comparative adsorption of Pb (II) ion from aqueous solution onto different adsorbents was ...

  9. Ionophores in polymeric membranes for selective ion recognition; impedance studies

    Energy Technology Data Exchange (ETDEWEB)

    Lisowska-Oleksiak, A. [Department of Chemical Technology, Gdansk University of Technology, ul. Narutowicza 11/12, 80-952 Gdansk (Poland)]. E-mail: alo@chem.pg.gda.pl; Lesinska, U. [Department of Chemical Technology, Gdansk University of Technology, ul. Narutowicza 11/12, 80-952 Gdansk (Poland); Nowak, A.P. [Department of Chemical Technology, Gdansk University of Technology, ul. Narutowicza 11/12, 80-952 Gdansk (Poland); Bochenska, M. [Department of Chemical Technology, Gdansk University of Technology, ul. Narutowicza 11/12, 80-952 Gdansk (Poland)]. E-mail: marboch@chem.pg.gda.pl

    2006-02-15

    Synthetic calix[4]arene-crown ionophores for selective Na{sup +} (ionophore L1) and Cs{sup +}-ions (ionophore L2) recognition find application in ion-selective membrane electrodes (ISE) for analytical purpose. Selectivity coefficients for the electrodes with compounds L1 and L2 are logK{sub Na,Cs}{sup pot}=-2.6 and logK{sub Cs,Na}{sup pot}=-2.4, respectively. Electrodes of two different construction: all-solid-state (ASS) (with conducting polymer layer on glassy carbon or platinum as ion-to-electron transducer) and conventional ion-selective electrode (ISE) (with liquid electrolyte and Ag/AgCl) are presented and their properties and lifetime are being compared. Resistance of PVC membrane with ionophores L1 and L2 were within the range 0.15-1.4M{omega} depending on the type of the outer electrolyte and its concentration. Conductivity of the membranes was in the range 0.7x10{sup -8} to 6x10{sup -8}{omega}{sup -1}cm{sup -1}. Warburg coefficients {sigma} were within 0.16x10{sup 4} to 12.7x10{sup 4}{omega}s{sup -1/2}, dielectric constant values {epsilon} were in a range 28-60 depending mainly on the type of plasticizer.

  10. Glass-Fiber Networks as an Orbit for Ions: Fabrication of Excellent Antistatic PP/GF Composites with Extremely Low Organic Salt Loadings.

    Science.gov (United States)

    Gu, Senlin; Zhu, Leon; Mercier, Claude; Li, Yongjin

    2017-05-31

    Polypropylene (PP)/glass fiber (GF) composites showing excellent antistatic performance were prepared by a simple melt process blending PP with GF and a small amount of organic salts (OSs). Two types of OSs, tribuyl(octyl)phosphonium bis(trifloromethanesulfonyl)imide (TBOP-TFSI) and lithium bis(trifloromethanesulfonyl)imide (Li-TFSI), with equivalent anions were used as antistatic agents for the composites. It was found that the GF and OSs exhibited significant synergistic effects on the antistatic performance as well as the mechanical properties of the composites. On the one hand, the incorporation of GF significantly enhanced the electric conductivity of the composites at a constant OS loading. On the other hand, the two types of OSs improved the interfacial adhesion between the GF and the PP matrix, which led to an enhancement of the mechanical properties. This study showed that OSs had specific interactions with GFs and were absorbed exclusively on the GF surface. The GF network in the PP matrix provided perfect orbits for the movement of ions, inducing the excellent antistatic performance exhibited by the PP/GF composites at an OS loading of as low as 0.25 wt % when the GF formed a network in the PP matrix.

  11. Earth Regimes Network Evolution Study (ERNESt): Introducing the Space Mobile Network

    Science.gov (United States)

    Menrad, Bob

    2016-01-01

    Speaker and Presenter at the Lincoln Laboratory Communications Workshop on April 5, 2016 at the Massachusetts Institute of Technology Lincoln Laboratory in Lexington, MA. A visual presentation titled Earth Regimes Network Evolution Study (ERNESt).

  12. Studying Equilibrium in the Chemical Reaction between Ferric and Iodide Ions in Solution Using a Simple and Inexpensive Approach

    Science.gov (United States)

    Nikolaychuk, Pavel Anatolyevich; Kuvaeva, Alyona Olegovna

    2016-01-01

    A laboratory experiment on the study of the chemical equilibrium based on the reaction between ferric and iodide ions in solution with the formation of ferrous ions, free iodine, and triiodide ions is developed. The total concentration of iodide and triiodide ions in the reaction mixture during the reaction is determined by the argentometric…

  13. The complexity of crime network data: a case study of its consequences for crime control and the study of networks.

    Directory of Open Access Journals (Sweden)

    Amir Rostami

    Full Text Available The field of social network analysis has received increasing attention during the past decades and has been used to tackle a variety of research questions, from prevention of sexually transmitted diseases to humanitarian relief operations. In particular, social network analyses are becoming an important component in studies of criminal networks and in criminal intelligence analysis. At the same time, intelligence analyses and assessments have become a vital component of modern approaches in policing, with policy implications for crime prevention, especially in the fight against organized crime. In this study, we have a unique opportunity to examine one specific Swedish street gang with three different datasets. These datasets are the most common information sources in studies of criminal networks: intelligence, surveillance and co-offending data. We use the data sources to build networks, and compare them by computing distance, centrality, and clustering measures. This study shows the complexity factor by which different data sources about the same object of study have a fundamental impact on the results. The same individuals have different importance ranking depending on the dataset and measure. Consequently, the data source plays a vital role in grasping the complexity of the phenomenon under study. Researchers, policy makers, and practitioners should therefore pay greater attention to the biases affecting the sources of the analysis, and be cautious when drawing conclusions based on intelligence assessments and limited network data. This study contributes to strengthening social network analysis as a reliable tool for understanding and analyzing criminality and criminal networks.

  14. The complexity of crime network data: a case study of its consequences for crime control and the study of networks.

    Science.gov (United States)

    Rostami, Amir; Mondani, Hernan

    2015-01-01

    The field of social network analysis has received increasing attention during the past decades and has been used to tackle a variety of research questions, from prevention of sexually transmitted diseases to humanitarian relief operations. In particular, social network analyses are becoming an important component in studies of criminal networks and in criminal intelligence analysis. At the same time, intelligence analyses and assessments have become a vital component of modern approaches in policing, with policy implications for crime prevention, especially in the fight against organized crime. In this study, we have a unique opportunity to examine one specific Swedish street gang with three different datasets. These datasets are the most common information sources in studies of criminal networks: intelligence, surveillance and co-offending data. We use the data sources to build networks, and compare them by computing distance, centrality, and clustering measures. This study shows the complexity factor by which different data sources about the same object of study have a fundamental impact on the results. The same individuals have different importance ranking depending on the dataset and measure. Consequently, the data source plays a vital role in grasping the complexity of the phenomenon under study. Researchers, policy makers, and practitioners should therefore pay greater attention to the biases affecting the sources of the analysis, and be cautious when drawing conclusions based on intelligence assessments and limited network data. This study contributes to strengthening social network analysis as a reliable tool for understanding and analyzing criminality and criminal networks.

  15. Statistical methods for studying the evolution of networks and behavior

    NARCIS (Netherlands)

    Schweinberger, Michael

    2007-01-01

    Studying longitudinal network and behavior data is important for understanding social processes, because human beings are interrelated, and the relationships among human beings (human networks) on one hand and human behavior on the other hand are not independent. The complex nature of longitudinal

  16. A Bayesian Approach to Measurement Bias in Networking Studies

    NARCIS (Netherlands)

    Zhu, Ling; Robinson, Scott E.; Torenvlied, René

    2014-01-01

    The study of managerial networking has been growing in the field of public administration; a field that analyzes how managers in open system organizations interact with different external actors and organizations. Coincident with this interest in managerial networking is the use of self-reported

  17. Electrochemical studies on Li/K ion exchange behaviour in K 4 Fe ...

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Chemical Sciences; Volume 127; Issue 1. Electrochemical studies on Li+/K+ ion exchange behaviour in K4Fe(CN)6 cathode material for Li, K-ion battery. Bikash Mandal I Basumallick Susanta Ghosha. Regular Articles Volume 127 Issue 1 January 2015 pp 141-148 ...

  18. Study of transient current induced by heavy-ion microbeams in Si and GaAs

    Energy Technology Data Exchange (ETDEWEB)

    Hirao, Toshio; Nashiyama, Isamu; Kamiya, Tomihiro; Suda, Tamotu [Japan Atomic Energy Research Inst., Takasaki, Gunma (Japan). Takasaki Radiation Chemistry Research Establishment

    1997-03-01

    Heavy-ion microbeams were applied to the study of mechanism of single event upset (SEU). Transient current induced in p{sup +}n junction diodes by strike of heavy ion microbeam were measured by using a high-speed digitizing sampling system. (author)

  19. Infrared and Raman spectroscopic study of ion pairing of strontium(II ...

    African Journals Online (AJOL)

    ABSTRACT. Infrared and Raman spectroscopy techniques have been used to study the ionic interactions of strontium(II) and barium(II) with thiocyanate ion in liquid ammonia. A number of bands were observed in both ν(CN) and ν(CS) regions of infrared and Raman spectra and these were assigned to 1:1 contact ion pair, ...

  20. Spectroscopic and transport studies of Cu ion doped in (40 – x)Li2O ...

    Indian Academy of Sciences (India)

    Unknown

    BiO3] ... Preparation; (40 – x)Li2O–xLiF–60Bi2O3 glasses; spectroscopic and transport studies. 1. Introduction. The need to develop efficient ..... probe ion, it may be responsible for the change in local environment of the probe ion (Cu2+). The IR ...

  1. Jet studies in heavy ion collisions with the ATLAS detector

    CERN Document Server

    Slovak, Radim; The ATLAS collaboration

    2016-01-01

    In relativistic heavy ion collisions, a hot medium with a high density of unscreened color charges is produced. Jets are produced at the early stages of this collision and are known to become attenuated as they propagate through the hot matter. One manifestation of this energy loss is a lower yield of jets emerging from the medium than expected in the absence of medium effects. ATLAS has provided a quantification of this jet suppression by the jet Raa measurement in run 1 of LHC. A factor of two suppression was seen in central heavy ion collisions with respect to pp collisions. The Raa exhibited only a week, if any, rapidity dependence, and a slow rise with increasing jet momentum. This talk summarizes the run 1 results on the inclusive jet production and the new results on dijet measurements.

  2. Studying heavy-ion collisions with FAUST-QTS

    Directory of Open Access Journals (Sweden)

    Cammarata P.

    2015-01-01

    Full Text Available Heavy-ion collisions at lower energies provide a rich environment for investigating reaction dynamics. Recent theory has suggested a sensitivity to the symmetry energy and the equation of state via deformations of the reaction system and ternary breaking of the deformed reaction partners into three heavy fragments. A new detection system has been commissioned at Texas A&M University in an attempt to investigate some of the observables sensitive to the nuclear equation of state.

  3. Studies of an inductively coupled negative hydrogen ion radio frequency source through simulations and experiments

    Energy Technology Data Exchange (ETDEWEB)

    Bandyopadhyay, M.

    2004-08-24

    In the frame work of a development project for ITER neutral beam injection system a radio frequency (RF) driven negative hydrogen (H-/D-) ion source, (BATMAN ion source) is developed which is designed to produce several 10s of ampere of H-/D- beam current. This PhD work has been carried out to understand and optimize BATMAN ion source. The study has been done with the help of computer simulations, modeling and experiments. The complete three dimensional Monte-Carlo computer simulation codes have been developed under the scope of this PhD work. A comprehensive description about the volume production and the surface production of H- ions is presented in the thesis along with the study results obtained from the simulations, modeling and the experiments. One of the simulations is based on the volume production of H- ions, where it calculates the density profile of the vibrationally excited H2 molecules, the density profile of H- ions and the transport probability of those H- ions along the source axis towards the grid. The other simulation studies the transport of those H- ions which are produced on the surface of the plasma grid. It is expected that if there is a plasma flow in the source, the transport of plasma components (molecules and ions) would be influenced. Experimentally it is observed that there is a convective plasma flow exists in the ion source. A transverse magnetic filter field which is present near the grid inside the ion source reduces the flow velocity. Negative ions and electrons have the same sign of charge; therefore the electrons are co-extracted with the negative ions through the grid system, which is not desirable. It is observed that a magnetic field near the grid, magnetized the electrons and therefore reduce the co-extracted electron current. It is also observed experimentally that if the plasma grid is biased positively with respect to the source body, the electron density near the plasma grid is reduced and therefore the co

  4. Spectro-microscopic study of the formation of supramolecular networks

    Science.gov (United States)

    Sadowski, Jerzy T.

    2015-03-01

    Metal-organic frameworks (MOFs) are emerging as a new class of materials for CO2 capture. There are many fundamental questions, including the optimum pore size and arrangement of the molecules in the structure to achieve highest CO2 uptake. As only the surface is of interest for potential applications such as heterogeneous catalysis, nano-templating, and sensing, 2D analogs of MOFs can serve as good model systems. Utilizing capabilities of LEEM/PEEM for non-destructive interrogation of the real-time molecular self-assembly, we investigated supramolecular systems based on carboxylic acid-metal complexes, such as trimesic and mellitic acid, doped with transition metals. Such 2D networks act as host systems for transition-metal phthalocyanines (MPc; M = Fe, Ti, Sc) and the electrostatic interactions of CO2 molecules with transition metal ions, can be tuned by controlling the type of TM ion and the size of the pore in the host network. The understanding of directed self-assembly by controlling the molecule-substrate interaction can enable us to engineer the pore size and density, and thus tune the host's chemical activity. Research carried out at the Center for Functional Nanomaterials and National Synchrotron Light Source, Brookhaven National Laboratory, which are supported by the U.S. Department of Energy, Office of Basic Energy Sciences, under Contract No. DE-AC02-98CH10.

  5. Study on Dissemination Patterns in Location-Aware Gossiping Networks

    Science.gov (United States)

    Kami, Nobuharu; Baba, Teruyuki; Yoshikawa, Takashi; Morikawa, Hiroyuki

    We study the properties of information dissemination over location-aware gossiping networks leveraging location-based real-time communication applications. Gossiping is a promising method for quickly disseminating messages in a large-scale system, but in its application to information dissemination for location-aware applications, it is important to consider the network topology and patterns of spatial dissemination over the network in order to achieve effective delivery of messages to potentially interested users. To this end, we propose a continuous-space network model extended from Kleinberg's small-world model applicable to actual location-based applications. Analytical and simulation-based study shows that the proposed network achieves high dissemination efficiency resulting from geographically neutral dissemination patterns as well as selective dissemination to proximate users. We have designed a highly scalable location management method capable of promptly updating the network topology in response to node movement and have implemented a distributed simulator to perform dynamic target pursuit experiments as one example of applications that are the most sensitive to message forwarding delay. The experimental results show that the proposed network surpasses other types of networks in pursuit efficiency and achieves the desirable dissemination patterns.

  6. New approaches to model and study social networks

    Science.gov (United States)

    Lind, P. G.; Herrmann, H. J.

    2007-07-01

    We describe and develop three recent novelties in network research which are particularly useful for studying social systems. The first one concerns the discovery of some basic dynamical laws that enable the emergence of the fundamental features observed in social networks, namely the nontrivial clustering properties, the existence of positive degree correlations and the subdivision into communities. To reproduce all these features, we describe a simple model of mobile colliding agents, whose collisions define the connections between the agents which are the nodes in the underlying network, and develop some analytical considerations. The second point addresses the particular feature of clustering and its relationship with global network measures, namely with the distribution of the size of cycles in the network. Since in social bipartite networks it is not possible to measure the clustering from standard procedures, we propose an alternative clustering coefficient that can be used to extract an improved normalized cycle distribution in any network. Finally, the third point addresses dynamical processes occurring on networks, namely when studying the propagation of information in them. In particular, we focus on the particular features of gossip propagation which impose some restrictions in the propagation rules. To this end we introduce a quantity, the spread factor, which measures the average maximal fraction of nearest neighbours which get in contact with the gossip, and find the striking result that there is an optimal non-trivial number of friends for which the spread factor is minimized, decreasing the danger of being gossiped about.

  7. Analytical study of effects of positron density and temperature anisotropy on electrostatic ion cyclotron instability

    Science.gov (United States)

    Barati Moqadam Niyat, M.; Khorashadizadeh, S. M.; Niknam, A. R.

    2017-03-01

    The effects of the positron concentration and ion temperature anisotropy on the electrostatic ion cyclotron instability are studied analytically, in a magnetized electron-positron-ion plasma with temperature anisotropy, using the linear kinetic theory. Positrons and electrons are supposed to drift either in the same direction or in opposite directions relative to singly ionized stationary ions and parallel to the magnetic field. The dispersion relation of the electrostatic ion cyclotron waves is derived, and then the conditions for exciting the instability of the waves are investigated. Moreover, the condition for the marginally stable state is also studied. It is found that as the positron concentration and perpendicular ion temperature increase, the growth rate of the electrostatic ion cyclotron instability decreases, whereas the critical drift velocity increases. It is also found that for the chosen set of parameters, with electrons and positrons drifting in the same direction, the instability in the plasma is stronger than when the electrons and positrons drift in opposite directions. In addition, a comparison is made to the normal electron-ion plasma.

  8. Studies in High Energy Heavy Ion Nuclear Physics

    Energy Technology Data Exchange (ETDEWEB)

    Hoffmann, Gerald W. [Univ. of Texas, Austin, TX (United States); Markert, Christina [Univ. of Texas, Austin, TX (United States)

    2016-09-01

    This close-out report covers the period 1994 - 2015 for DOE grant DE-FG02-94ER40845 with the University of Texas at Austin. The research was concerned with studies of the strong nuclear force and properties of nuclear matter under extreme conditions of temperature and density which far exceed that in atomic nuclei. Such extreme conditions are briefly created (for about 10 trillionths of a trillionth of a second) during head-on collisions of large atomic nuclei (e.g. gold) colliding at speeds very close to the speed-of-light. The collisions produce thousands of subatomic particles, many of which are detected in our experiment called STAR at the Relativistic Heavy-Ion Collider at the Brookhaven National Lab in New York. The goal of our research is to learn how the strong nuclear force and its fundamental particles (quarks and gluons) behave in extreme conditions similar to that of the early Universe when it was about 1 micro-second old, and in the cores of very dense neutron stars. To learn anything new about the matter which exists for such a very short amount of time requires carefully designed probes. In our research we focused on two such probes, one being short-lived resonance particles and the other using correlations between pairs of the detected particles. Resonances are short-lived particles created in the collision, which interact with the surrounding matter, and which break apart, or "decay" into more stable particles which survive long enough to be seen in our detectors. The dependence of resonance properties on the conditions in the collision system permit tests of theoretical models and improve our understanding. Dynamical interactions in the matter also leave imprints on the final, outgoing particle distributions measured in the experiment. In particular, angular correlations between pairs of particles can be related to the fundamental strong force as it behaves in the hot, dense matter. Studying correlations as a function of experimentally controlled

  9. Minerva neural network based surrogate model for real time inference of ion temperature profiles at Wendelstein 7-X

    Science.gov (United States)

    Pavone, Andrea; Svensson, Jakob; Langenberg, Andreas; Pablant, Novimir; Wolf, Robert C.

    2017-10-01

    Artificial neural networks (ANNs) can reduce the computation time required for the application of Bayesian inference on large amounts of data by several orders of magnitude, making real-time analysis possible and, at the same time, providing a reliable alternative to more conventional inversion routines. The large scale fusion experiment Wendelstein 7-X (W7-X) requires tens of diagnostics for plasma parameter measurements and is using the Minerva Bayesian modelling framework as its main inference engine, which can handle joint inference in complex systems made of several physics models. Conventional inversion routines are applied to measured data to infer the posterior distribution of the free parameters of the models implemented in the framework. We have trained ANNs on a training set made of samples from the prior distribution of the free parameters and the corresponding data calculated with the forward model, so that the trained ANNs constitute a surrogate model of the physics model. The ANNs have been then applied to 2D images measured by an X-ray spectrometer, representing the spectral emission from plasma impurities measured along a fan of lines of sight covering a major fraction of the plasma cross-section, for the inference of ion temperature profiles and then compared with the conventional inversion routines, showing that they constitute a robust and reliable alternative for real time plasma parameter inference.

  10. Negative- and positive-ion fragmentation of core-excited formic-acid molecules studied with three- and four-ion coincidence spectroscopy

    Science.gov (United States)

    Strâhlman, Christian; Kivimäki, Antti; Richter, Robert; Sankari, Rami

    2017-08-01

    The negative-ion fragmentation of formic acid (HCOOH) is studied with negative- and positive-ion coincidence spectroscopy. We report four-body ionic fragmentation where up to three positive ions are collected in coincidence with one negative ion. We report yields for 21 three-body channels and five four-body channels. More than 80% of all negative-ion fragmentation involves production of O-, and it is dominated by complete dissociation of all molecular bonds. Negative-ion creation is most abundant at high-Rydberg resonances and just above the molecule's core-ionization potentials. The existence of four-body fragmentation channels evidences a strong charge redistribution in the molecule.

  11. Alternative solutions to caesium in negative-ion sources: a study of negative-ion surface production on diamond in H2/D2 plasmas

    Science.gov (United States)

    Cartry, Gilles; Kogut, Dmitry; Achkasov, Kostiantyn; Layet, Jean-Marc; Farley, Thomas; Gicquel, Alix; Achard, Jocelyn; Brinza, Ovidiu; Bieber, Thomas; Khemliche, Hocine; Roncin, Philippe; Simonin, Alain

    2017-02-01

    This paper deals with a study of H-/D- negative ion surface production on diamond in low pressure H2/D2 plasmas. A sample placed in the plasma is negatively biased with respect to plasma potential. Upon positive ion impacts on the sample, some negative ions are formed and detected according to their mass and energy by a mass spectrometer placed in front of the sample. The experimental methods developed to study negative ion surface production and obtain negative ion energy and angle distribution functions are first presented. Different diamond materials ranging from nanocrystalline to single crystal layers, either doped with boron or intrinsic, are then investigated and compared with graphite. The negative ion yields obtained are presented as a function of different experimental parameters such as the exposure time, the sample bias which determines the positive ion impact energy and the sample surface temperature. It is concluded from these experiments that the electronic properties of diamond materials, among them the negative electron affinity, seem to be favourable for negative-ion surface production. However, the negative ion yield decreases with the plasma induced defect density.

  12. Dosimetry in radiobiological studies with the heavy ion beam of the Warsaw cyclotron

    Energy Technology Data Exchange (ETDEWEB)

    Kaźmierczak, U. [Heavy Ion Laboratory, University of Warsaw, ul. Pasteura 5A, 02-093 Warsaw (Poland); Faculty of Physics, University of Warsaw, ul. Pasteura 5, 02-093 Warsaw (Poland); Banaś, D.; Braziewicz, J. [Institute of Physics, Jan Kochanowski University, ul. Świętokrzyska 15, 25-406 Kielce (Poland); Holycross Cancer Center, ul. Artwińskiego 3, 25-734 Kielce (Poland); Czub, J. [Institute of Physics, Jan Kochanowski University, ul. Świętokrzyska 15, 25-406 Kielce (Poland); Jaskóła, M.; Korman, A. [National Centre for Nuclear Research, ul. Andrzeja Sołtana 7, 05-400 Otwock (Poland); Kruszewski, M. [Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warsaw (Poland); Institute of Rural Health, ul. Jaczewskiego 2, 20-090 Lublin (Poland); Lankoff, A. [Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warsaw (Poland); Institute of Biology, Jan Kochanowski University, ul. Świętokrzyska 15, 25-406 Kielce (Poland); Lisowska, H. [Institute of Biology, Jan Kochanowski University, ul. Świętokrzyska 15, 25-406 Kielce (Poland); Malinowska, A. [National Centre for Nuclear Research, ul. Andrzeja Sołtana 7, 05-400 Otwock (Poland); Stępkowski, T. [Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warsaw (Poland); Szefliński, Z. [Heavy Ion Laboratory, University of Warsaw, ul. Pasteura 5A, 02-093 Warsaw (Poland); and others

    2015-12-15

    The aim of this study was to verify various dosimetry methods in the irradiation of biological materials with a {sup 12}C ion beam at the Heavy Ion Laboratory of the University of Warsaw. To this end the number of ions hitting the cell nucleus, calculated on the basis of the Si-detector system used in the set-up, was compared with the number of ion tracks counted in irradiated Solid State Nuclear Track Detectors and with the number of ion tracks detected in irradiated Chinese Hamster Ovary cells processed for the γ-H2AX assay. Tests results were self-consistent and confirmed that the system serves its dosimetric purpose.

  13. Gamma-resonance study of the reaction of iron ions with synthetic L-dopa melanin

    Energy Technology Data Exchange (ETDEWEB)

    Bagirov, R.M.; Stukan, R.A.; Lapina, V.A.; Dontsov, A.E.; Ostrovskii, M.A.

    1986-07-01

    The reaction of Fe/sup 3 +/ and Fe/sup 2 +/ ions with synthetic L-dopa melanin, which is a model compound of natural melanin (the melanoprotein granules in the pigment epithelial cells in vertebrate and human eyes), has been studied by gamma-resonance spectroscopy. The investigations showed that L-dopa melanin is capable of effectively binding iron ions and that it displays oxidative or reducing properties with respect to Fe, depending on the composition of the subsystem of the Fe ions and the ambient pH. Trivalent Fe/sup 3 +/ ions form stronger complexes with L-dopa melanin than do Fe/sup 2 +/ ions. The coordination takes place mainly with the carboxyl groups and the amino and imino groups of the polymer. The conformational state of the polymer apparently changes as the pH is varied.

  14. Studies on stochastic cooling of heavy ions in the LHC

    CERN Document Server

    Schaumann, M; Salvant, B; Wendt, M; Blaskiewicz, M; Verdú-Andrés, S

    2014-01-01

    Future high luminosity heavy-ion operation of the LHC will be dominated by very rapid luminosity decay due to the large collision cross-section and, to a lesser extent, emittance growth from intra-beam scattering (IBS) due to the high bunch intensities. A stochastic cooling system could reduce the emittance far below its initial value and reduce the losses from debunching during collisions, allowing more of the initial beam intensity to be converted into integrated luminosity before the beams are dumped. We review the status of this proposal, system and hardware properties and potential locations for the equipment in the tunnel.

  15. In Situ Studies of Energy Deposition by Ion Beams.

    Science.gov (United States)

    1985-06-14

    M. Choi , J. Groeger, F. A. Otter, Y. Bruynseraede and M. Clapp. 1984. Modifications in the unit cell geometry of sputtered niobium films caused by...Budnick, M. Choi , J. Groeger, F. A. Otter, Y. Bruynseraede and M. Clapp. 1984. Modifications in the unit cell geometry of sputtered niobium films caused by...helw.V beam off 3. Experimental Results b Z 18 L iNhO 0 4C Exposure of the LiNbO 3 to an Ar+ ion beam of pairticle energy 100 key and current density

  16. Network interventions on physical activity in an afterschool program: an agent-based social network study.

    Science.gov (United States)

    Zhang, Jun; Shoham, David A; Tesdahl, Eric; Gesell, Sabina B

    2015-04-01

    We studied simulated interventions that leveraged social networks to increase physical activity in children. We studied a real-world social network of 81 children (average age = 7.96 years) who lived in low socioeconomic status neighborhoods, and attended public schools and 1 of 2 structured afterschool programs. The sample was ethnically diverse, and 44% were overweight or obese. We used social network analysis and agent-based modeling simulations to test whether implementing a network intervention would increase children's physical activity. We tested 3 intervention strategies. The intervention that targeted opinion leaders was effective in increasing the average level of physical activity across the entire network. However, the intervention that targeted the most sedentary children was the best at increasing their physical activity levels. Which network intervention to implement depends on whether the goal is to shift the entire distribution of physical activity or to influence those most adversely affected by low physical activity. Agent-based modeling could be an important complement to traditional project planning tools, analogous to sample size and power analyses, to help researchers design more effective interventions for increasing children's physical activity.

  17. Exposure to Air Ions in Indoor Environments: Experimental Study with Healthy Adults

    Directory of Open Access Journals (Sweden)

    Peter Wallner

    2015-11-01

    Full Text Available Since the beginning of the 20th century there has been a scientific debate about the potential effects of air ions on biological tissues, wellbeing and health. Effects on the cardiovascular and respiratory system as well as on mental health have been described. In recent years, there has been a renewed interest in this topic. In an experimental indoor setting we conducted a double-blind cross-over trial to determine if higher levels of air ions, generated by a special wall paint, affect cognitive performance, wellbeing, lung function, and cardiovascular function. Twenty healthy non-smoking volunteers (10 female, 10 male participated in the study. Levels of air ions, volatile organic compounds and indoor climate factors were determined by standardized measurement procedures. Air ions affected the autonomous nervous system (in terms of an increase of sympathetic activity accompanied by a small decrease of vagal efferent activity: In the test room with higher levels of air ions (2194/cm3 vs. 1038/cm3 a significantly higher low to high frequency ratio of the electrocardiography (ECG beat-to-beat interval spectrogram was found. Furthermore, six of nine subtests of a cognitive performance test were solved better, three of them statistically significant (verbal factor, reasoning, and perceptual speed, in the room with higher ion concentration. There was no influence of air ions on lung function and on wellbeing. Our results indicate slightly activating and cognitive performance enhancing effects of a short-term exposure to higher indoor air ion concentrations.

  18. The study towards high intensity high charge state laser ion sources.

    Science.gov (United States)

    Zhao, H Y; Jin, Q Y; Sha, S; Zhang, J J; Li, Z M; Liu, W; Sun, L T; Zhang, X Z; Zhao, H W

    2014-02-01

    As one of the candidate ion sources for a planned project, the High Intensity heavy-ion Accelerator Facility, a laser ion source has been being intensively studied at the Institute of Modern Physics in the past two years. The charge state distributions of ions produced by irradiating a pulsed 3 J/8 ns Nd:YAG laser on solid targets of a wide range of elements (C, Al, Ti, Ni, Ag, Ta, and Pb) were measured with an electrostatic ion analyzer spectrometer, which indicates that highly charged ions could be generated from low-to-medium mass elements with the present laser system, while the charge state distributions for high mass elements were relatively low. The shot-to-shot stability of ion pulses was monitored with a Faraday cup for carbon target. The fluctuations within ±2.5% for the peak current and total charge and ±6% for pulse duration were demonstrated with the present setup of the laser ion source, the suppression of which is still possible.

  19. Performance Study of Graphite Anode Slurry in Lithium-ion Flow Battery by Ball Milling

    Directory of Open Access Journals (Sweden)

    FENG Cai-mei

    2018-02-01

    Full Text Available Graphite anode slurry of lithium-ion flow battery was prepared by the method of ball milling. The morphology, conductivity, specific capacity and cycle performance of graphite anode slurry were studied. Results show that the addition of conductive carbon material can improve the suspension stability of the electrode slurry; the ball milling process can not only improve the suspension stability but also reduce the resistivity of the mixed powders of graphite and conductive carbon materials, the ball milling effect is satisfactory when the mass ratio of the balls and the solid particles is 5:1, but too high ratio of the milling ball and the solid materials can destroy the layer structure of the graphite and affect the stability of the slurry. Increasing the fraction of the graphite and conductive carbon materials can form stable electrical network structure in the slurry and improve the reversible capacity; at the premise of keeping the flowability of the electrode slurry, the reversible specific capacity can be more than 40mAh/g. The capacity loss of graphite anode slurry mainly occurs in the first charging-discharging process, as the increase of the cycles, the capacity loss rate decreases, the capacity goes stable after 5 cycles.

  20. Kinetic studies of clavulanic acid recovery by ion exchange chromatography.

    Science.gov (United States)

    Barboza, M; Almeida, R M; Hokka, C O

    2001-01-01

    Clavulanic acid (CA) is a beta-lactamase inhibitor produced by strains of Streptomyces clavuligerus. Nowadays, the combination of CA with amoxycillin is the most successful example of the use of a beta-lactam antibiotic sensitive to beta-lactamases together with an inhibitor of these enzymes. Clavulanic acid is purified from fermentation broth by a series of steps consisting mainly of two-phase separation processes such as liquid-liquid extraction, adsorption or ion-exchange chromatography, among others. Amberlite IRA 400, a strong anion-exchange resin, has a very high adsorption capacity for CA (Mayer et al. 1997). This resin can be pre-treated with NaCl (chloride cycle), to remove selectively only those anions, which are able to displace chloride from the resin or with NaOH (hydroxyl cycle), to remove all species of anions. In order to decide the best operating conditions for CA recovery by ion-exchange resins and then to construct a model of this separation process, batch experiments were conducted using Amberlite IRA 400 in the chloride cycle. These runs were carried out in a 200 ml stirred tank, at two different initial solution pH, 6.2 and 4.0; the temperature was maintained at 10 degrees C and 20 degrees C during adsorption and 30 degrees C during the desorption step. It was possible, on the basis of these batch results, to model the separation process, including the adsorption kinetics, equilibrium data and mass transfer limitations.

  1. Radiochemical study of the reactions of heavy ions with gold

    Energy Technology Data Exchange (ETDEWEB)

    Binder, I.

    1977-07-01

    Thick gold foils have been bombarded with heavy-ion projectiles at energies above the Coulomb barrier. The radioactive products were identified and their yields measured using gamma-ray spectrometry and an extensive series of computer programs developed for the data analysis. The total mass-yield distribution was extracted from the data using charge-dispersion curves inferred from the experimental results. One observes a change in the mass-yield distributions corresponding to primarily fusion-fission tractions occurring with the lighter projectiles Ne-20 and Ar-40 and deep-inelastic transfer reactions predominating with heavier Kr-84, Kr-86, and Xe-136 projectiles. For the deep-inelastic transfer reaction, more mass transfer is seen to occur for a higher incident projectile energy, and the Gaussian distribution of products shows exponential tailing. The preferred direction for mass transfer is from gold to the projectile nucleus. Sequential fission is a likely fate for nucludes beyond the lead shell closure. The ''gold finger'' is explained as a combination of mass transfer, nucleon evaporation and sequential fission. The yields of gold nuclides indicate a superposition of two reaction mechanisms, quasi-elastic and deep-inelastic. The angular momentum involved with each mechanism determines which of two isomeric states is the end product of the nuclear reaction. Suggestions are offered regarding the possibility of synthesizing super-heavy elements by use of heavy-ion nuclear reactions.

  2. Implementation of a neural network for digital pulse shape analysis on a FPGA for on-line identification of heavy ions

    Energy Technology Data Exchange (ETDEWEB)

    Jimenez, R., E-mail: naharro@uhu.es [Departamento de Ingenieria Eletronica, Sistemas Informaticos y Automatica, Universidad de Huelva, 21071 Huelva (Spain); Sanchez-Raya, M.; Gomez-Galan, J.A. [Departamento de Ingenieria Eletronica, Sistemas Informaticos y Automatica, Universidad de Huelva, 21071 Huelva (Spain); Flores, J.L. [Departamento Ingenieria Electrica y Termica, Universidad de Huelva, 21071 Huelva (Spain); Duenas, J.A.; Martel, I. [Departamento de Fisica Aplicada, Universidad de Huelva, 21071 Huelva (Spain)

    2012-05-11

    Pulse shape analysis techniques for the identification of heavy ions produced in nuclear reactions have been recently proposed as an alternative to energy loss and time of flight methods. However this technique requires a large amount of memory for storing the shapes of charge and current signals. We have implemented a hardware solution for fast on-line processing of the signals producing the relevant information needed for particle identification. Since the pulse shape analysis can be formulated in terms of a pattern recognition problem, a neural network has been implemented in a FPGA device. The design concept has been tested using {sup 12,13}C ions produced in heavy ion reactions. The actual latency of the system is about 20 {mu}s when using a clock frequency of 50 MHz.

  3. 3D Networked Tin Oxide/Graphene Aerogel with a Hierarchically Porous Architecture for High-Rate Performance Sodium-Ion Batteries.

    Science.gov (United States)

    Xie, Xiuqiang; Chen, Shuangqiang; Sun, Bing; Wang, Chengyin; Wang, Guoxiu

    2015-09-07

    Low-cost and sustainable sodium-ion batteries are regarded as a promising technology for large-scale energy storage and conversion. The development of high-rate anode materials is highly desirable for sodium-ion batteries. The optimization of mass transport and electron transfer is crucial in the discovery of electrode materials with good high-rate performances. Herein, we report the synthesis of 3 D interconnected SnO2 /graphene aerogels with a hierarchically porous structure as anode materials for sodium-ion batteries. The unique 3 D architecture was prepared by a facile in situ process, during which cross-linked 3 D conductive graphene networks with macro-/meso-sized hierarchical pores were formed and SnO2 nanoparticles were dispersed uniformly on the graphene surface simultaneously. Such a 3 D functional architecture not only facilitates the electrode-electrolyte interaction but also provides an efficient electron pathway within the graphene networks. When applied as anode materials in sodium-ion batteries, the as-prepared SnO2 /graphene aerogel exhibited high reversible capacity, improved cycling performance compared to SnO2 , and promising high-rate capability. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Studies at the border between nuclear and atomic physics: Weak decays of highly charged ions

    Science.gov (United States)

    Atanasov, D.; Blaum, K.; Bosch, F.; Brandau, C.; Bühler, P.; Cakirli, R. B.; Chen, X. C.; Dillmann, I.; Faestermann, T.; Gao, B. S.; Geissel, H.; Gernhäuser, R.; Glorius, J.; Grisenti, R.; Gumberidze, A.; Hagmann, S.; Hillenbrand, P.-M.; Kienle, P.; Kozhuharov, C.; Lane, G.; Langer, C.; Lederer-Woods, C.; Lestinsky, M.; Litvinov, S. A.; Litvinov, Yu A.; Ma, X. W.; Najafi, M. A.; Nolden, F.; Ohtsubo, T.; Ozawa, A.; Ozturk, F. C.; Patyk, Z.; Pavicevic, M. K.; Petridis, N.; Reifarth, R.; Sanchez, R.; Sanjari, M. S.; Schneider, D.; Shevelko, V.; Spillmann, U.; Steck, M.; Stöhlker, T.; Sun, B. H.; Suzaki, F.; Suzuki, T.; Torilov, S. Yu; Trageser, C.; Trassinelli, M.; Tu, X. L.; Uesaka, T.; Walker, P. M.; Wang, M.; Weick, H.; Winckler, N.; Woods, P. J.; Xu, H. S.; Yamaguchi, T.; Yamaguchi, Y.; Yan, X. L.; Zhang, Y. H.; Zhou, X. H.; ">ILIMA, studies of weak decays of highly charged ions is presented. The paper closely follows the progress-report presentation given at the conference. Due to the limited space an emphasis is given to an exhaustive bibliography.

  5. Study of a High Voltage Ion Engine Power Supply

    Science.gov (United States)

    Stuart, Thomas A.; King, Roger J.; Mayer, Eric

    1996-01-01

    A complete laboratory breadboard version of a ion engine power converter was built and tested. This prototype operated on a line voltage of 80-120 Vdc, and provided output ratings of 1100 V at 1.8 kW, and 250 V at 20 mA. The high-voltage (HV) output voltage rating was revised from the original value of 1350 V at the beginning of the project. The LV output was designed to hold up during a 1-A surge current lasting up to 1 second. The prototype power converter included a internal housekeeping power supply which also operated from the line input. The power consumed in housekeeping was included in the overall energy budget presented for the ion engine converter. HV and LV output voltage setpoints were commanded through potentiometers. The HV converter itself reached its highest power efficiency of slightly over 93% at low line and maximum output. This would dip below 90% at high line. The no-load (rated output voltages, zero load current) power consumption of the entire system was less than 13 W. A careful loss breakdown shows that converter losses are predominately Metal-Oxide-Semiconductor Field Effect Transistor (MOSFET) conduction losses and HV rectifier snubbing losses, with the rectifier snubbing losses becoming predominant at high line. This suggests that further improvements in power efficiency could best be obtained by either developing a rectifier that was adequately protected against voltage overshoot with less snubbing, or by developing a pre-regulator to reduced the range of line voltage on the converter. The transient testing showed the converter to be fully protected against load faults, including a direct short-circuit from the HV output to the LV output terminals. Two currents sensors were used: one to directly detect any core ratcheting on the output transformer and re-initiate a soft start, and the other to directly detect a load fault and quickly shut down the converter for load protection. The finished converter has been extensively fault tested

  6. Making junctions between carbon nanotubes using an ion beam

    CERN Document Server

    Krasheninnikov, A V; Keinonen, J; Banhart, F

    2003-01-01

    Making use of empirical potential molecular dynamics, we study ion bombardment of crossed single-walled carbon nanotubes as a tool to join the nanotubes. We demonstrate that ion irradiation should result in welding of crossed nanotubes, both suspended and deposited on substrates. We further predict optimum ion doses and energies for ion-mediated nanotube welding which may potentially be used for developing complicated networks of joined nanotubes.

  7. Light ion production for a future radiobiological facility at CERN: preliminary studies.

    Science.gov (United States)

    Stafford-Haworth, Joshua; Bellodi, Giulia; Küchler, Detlef; Lombardi, Alessandra; Röhrich, Jörg; Scrivens, Richard

    2014-02-01

    Recent medical applications of ions such as carbon and helium have proved extremely effective for the treatment of human patients. However, before now a comprehensive study of the effects of different light ions on organic targets has not been completed. There is a strong desire for a dedicated facility which can produce ions in the range of protons to neon in order to perform this study. This paper will present the proposal and preliminary investigations into the production of light ions, and the development of a radiobiological research facility at CERN. The aims of this project will be presented along with the modifications required to the existing linear accelerator (Linac3), and the foreseen facility, including the requirements for an ion source in terms of some of the specification parameters and the flexibility of operation for different ion types. Preliminary results from beam transport simulations will be presented, in addition to some planned tests required to produce some of the required light ions (lithium, boron) to be conducted in collaboration with the Helmholtz-Zentrum für Materialien und Energie, Berlin.

  8. Experimental studies of the Negative Ion of Hydrogen. Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Bryant, Howard C.

    1999-06-30

    This document presents an overview of the results of the DOE'S support of experimental research into the structure and interactions of the negative ion of hydrogen conducted by the Department of Physics and Astronomy of the University of New Mexico at the Los Alamos National Laboratory. The work involves many collaborations with scientists from both institutions, as well as others. Although official DOE support for this work began in 1977, the experiment that led to it was done in 1971, near the time the 800 MeV linear accelerator at Los Alamos (LAMPF) first came on line. Until the mid nineties, the work was performed using the relativistic beam at LAMFF. The most recent results were obtained using the 35 keV injector beam for the Ground Test Accelerator at Los Alamos. A list of all published results from this work is presented.

  9. Hydration of magnesia cubes: a helium ion microscopy study

    Directory of Open Access Journals (Sweden)

    Ruth Schwaiger

    2016-02-01

    Full Text Available Physisorbed water originating from exposure to the ambient can have a strong impact on the structure and chemistry of oxide nanomaterials. The effect can be particularly pronounced when these oxides are in physical contact with a solid substrate such as the ones used for immobilization to perform electron or ion microscopy imaging. We used helium ion microscopy (HIM and investigated morphological changes of vapor-phase-grown MgO cubes after vacuum annealing and pressing into foils of soft and high purity indium. The indium foils were either used as obtained or, for reference, subjected to vacuum drying. After four days of storage in the vacuum chamber of the microscope and at a base pressure of p −7 mbar, we observed on these cubic particles the attack of residual physisorbed water molecules from the indium substrate. As a result, thin magnesium hydroxide layers spontaneously grew, giving rise to characteristic volume expansion effects, which depended on the size of the particles. Rounding of the originally sharp cube edges leads to a significant loss of the morphological definition specific to the MgO cubes. Comparison of different regions within one sample before and after exposure to liquid water reveals different transformation processes, such as the formation of Mg(OH2 shells that act as diffusion barriers for MgO dissolution or the evolution of brucite nanosheets organized in characteristic flower-like microstructures. The findings underline the significant metastability of nanomaterials under both ambient and high-vacuum conditions and show the dramatic effect of ubiquitous water films during storage and characterization of oxide nanomaterials.

  10. Socialising Health Burden Through Different Network Topologies: A Simulation Study.

    Science.gov (United States)

    Peacock, Adrian; Cheung, Anthony; Kim, Peter; Poon, Simon K

    2017-01-01

    An aging population and the expectation of premium quality health services combined with the increasing economic burden of the healthcare system requires a paradigm shift toward patient oriented healthcare. The guardian angel theory described by Szolovits [1] explores the notion of enlisting patients as primary providers of information and motivation to patients with similar clinical history through social connections. In this study, an agent based model was developed to simulate to explore how individuals are affected through their levels of intrinsic positivity. Ring, point-to-point (paired buddy), and random networks were modelled, with individuals able to send messages to each other given their levels of variables positivity and motivation. Of the 3 modelled networks it is apparent that the ring network provides the most equal, collective improvement in positivity and motivation for all users. Further study into other network topologies should be undertaken in the future.

  11. Religious networking organizations and social justice: an ethnographic case study.

    Science.gov (United States)

    Todd, Nathan R

    2012-09-01

    The current study provides an innovative examination of how and why religious networking organizations work for social justice in their local community. Similar to a coalition or community coordinating council, religious networking organizations are formal organizations comprised of individuals from multiple religious congregations who consistently meet to organize around a common goal. Based on over a year and a half of ethnographic participation in two separate religious networking organizations focused on community betterment and social justice, this study reports on the purpose and structure of these organizations, how each used networking to create social capital, and how religion was integrated into the organizations' social justice work. Findings contribute to the growing literature on social capital, empowering community settings, and the unique role of religious settings in promoting social justice. Implications for future research and practice also are discussed.

  12. Comparative study on the topological structure of China Education Network

    Science.gov (United States)

    Yu, Ming-Min; Zhang, Ning; Mao, Guo-Yong

    2017-07-01

    China Education Network (CEN) of year 2014 was studied as a complex network object. By searching the domain of “.edu.cn” and filtering some unexpected results, we finally get a network with 14,100,628 pages and 213,513,401 links. The topology of this network was studied to get the features such as out-degree distribution, in-degree distribution and average shortest path length. These features were compared with that of year 2007 and 2004 to observe the evolution mechanisms of CEN. According to the statistical results, it is found that some topology features of CEN such as out-degree distribution, in-degree distribution and average shortest path have changed a lot and the related reasons for these changes are given in this paper.

  13. Ecosystem Studies within the German network TERENO

    Science.gov (United States)

    Rebmann, Corinna; Cuntz, Matthias; Drüe, Clemens; Graf, Alexander; Mauder, Matthias; Schmidt, Marius; Schmid, Hans Peter; Sachs, Torsten; Steinbrecher, Rainer

    2013-04-01

    Many future environmental changes will be caused by global climate change. To find solutions which help to deal with alterations in climate, ecosystem productivity, and water resources, an interdisciplinary and long-term research programme involving six Helmholtz Association Centers, was established in Germany. TERENO (Terrestrial Environmental Observatories) spans an Earth observation network that extends from the North German lowlands to the Bavarian Alps. This large-scale project aims to catalogue the longterm ecological, social and economic impact of global change at regional level. In this contribution we mainly describe the infrastructure which is used to determine the atmosphere-biosphere exchange of trace gases and energy in four German regions with different land use and climatic and edaphic conditions. A strong focus will be on the terrestrial water budgets, such as variability of precipitation and soil moisture, but also on the partitioning of evapotranspiration with the help of intensive sap flow measurements. Some of the TERENO sites do also contribute to the ICOS infrastructure where the main focus is the quantification of greenhouse gases with standardized measurement techniques. The TERENO sites involved are located in the Northeastern German Lowland (GFZ), Central Germany Lowland / Harz (UFZ), the Lower Rhine Valley / Eifel (FZJ) and in the Bavarian Prealps (KIT).

  14. Numerical study on the perception-based network formation model

    CERN Document Server

    Jo, Hang-Hyun

    2015-01-01

    In order to understand the evolution of social networks in terms of perception-based strategic link formation, we numerically study a perception-based network formation model. Here each individual is assumed to have his/her own perception of the actual network, and use it to decide whether to create a link to other individual. An individual with the least perception accuracy can benefit from updating his/her perception using that of the most accurate individual via a new link. This benefit is compared to the cost of linking in decision making. Once a new link is created, it affects the accuracies of other individuals' perceptions, leading to a further evolution of the actual network. The initial actual network and initial perceptions are modeled by Erd\\H{o}s-R\\'enyi random networks but with different linking probabilities. Then the stable link density of the actual network is found to show discontinuous transitions or jumps according to the cost of linking. The effect of initial conditions on the complexity o...

  15. Studies on calcium phosphate precipitation: effects of metal ions used in dental materials.

    Science.gov (United States)

    Okamoto, Y; Hidaka, S

    1994-12-01

    The effects of 26 metal ions, of which 23 are used in dental materials, on the conversion of amorphous calcium phosphate (ACP) to hydroxyapatite (HAP) in vitro were studied. From the effects on both the rate of HAP transformation and induction time, effects of metal ions were classified into three types; inhibitory (in the order: nickel, tin, cobalt, manganese, copper, zinc, gallium, thallium, molybdenum, cadmium, antimony, magnesium, and mercury); ineffective (cesium, titanium, chromium, iron [ferrous], iridium, palladium, platinum, silver, gold, aluminum, and lead); and stimulatory (iron [ferric] and indium). These results suggest that metal ions used in dental materials may modify the precipitation of oral calcium phosphate.

  16. Rational design of carbon network cross-linked Si-SiC hollow nanosphere as anode of lithium-ion batteries.

    Science.gov (United States)

    Wen, Zhenhai; Lu, Ganhua; Cui, Shumao; Kim, Haejune; Ci, Suqin; Jiang, Junwei; Hurley, Patrick T; Chen, Junhong

    2014-01-07

    This study aims to realize controllable synthesis of Si-based nanostructures from common and easily accessible silica nanoparticles and to study their component/structure-dependent electrochemical performance as an anode of lithium-ion batteries (LIBs). To this end, a controllable route based on deliberate design has been developed to prepare hollow Si-based nanospheres with tunable composition and crystal structure at the nanoscale. The synthesis process started with coating silica nanoparticles with a carbonaceous polymer with a controllable thickness followed by magnesiothermic reduction. An Si-SiC-C composite was finally produced with a unique hollow sphere structure featuring Si-SiC nanoparticles encapsulated by a cross-linked carbon film network. In addition to the scalability of the synthetic route, the resulting composite exhibits a number of advantageous properties, including excellent electrical conductivity, highly accessible surfaces, structural coherence, and a favorable structure for the formation of a stable solid-electrolyte interphase, which makes it attractive and promising for advanced anode materials of LIBs.

  17. COMPARATIVE STUDY ON METAL IONS ADSORPTION ON A LOW COST CARBONACEOUS ADSORBENT KINETIC EQUILIBRIUM AND MECHANISTIC STUDIES

    Directory of Open Access Journals (Sweden)

    S. Arivoli, M. Hema, C. Barathiraja

    2008-01-01

    Full Text Available A carbonaceous adsorbent prepared from an indigenous waste and treated by acid was tested for its efficiency in removing metal ions of Fe(II, Co(II and Ni(II. The process parameters studied included agitation time, initial metal ion concentration, carbon dosage, pH, other ions and temperature. The kinetics of adsorption followed first order reaction equation and the rate was mainly controlled by intraparticle diffusion. Freundlich and Langmuir isotherm models were applied to the equilibrium data. The adsorption capacity obtained from the Langmuir isotherm plots was found around 28mg/g for all selected metal ions at an initial pH of 6. The temperature variation study showed that the metal ions adsorption is endothermic and spontaneous with increased randomness at the solid solution interface. Significant effect on adsorption was observed on varying pH of the metal ion solutions. The type I and II isotherms obtained, positive H0 values, pH dependent results and desorption of metal ions in mineral acid suggests that the adsorption of metal ions on this type of adsorbent involves both chemisorption and physical adsorption mechanisms.

  18. A multi-satellite study of accelerated ionospheric ion beams above the polar cap

    Directory of Open Access Journals (Sweden)

    R. Maggiolo

    2006-07-01

    Full Text Available This paper presents a study of nearly field-aligned outflowing ion beams observed on the Cluster satellites over the polar cap. Data are taken at geocentric radial distances of the order of 5–9 RE. The distinction is made between ion beams originating from the polar cusp/cleft and beams accelerated almost along the magnetic field line passing by the spacecraft. Polar cusp beams are characterized by nearly field-aligned proton and oxygen ions with an energy ratio EO+ / EH+, of the order of 3 to 4, due to the ion energy repartition inside the source and to the latitudinal extension of the source. Rapid variations in the outflowing ion energy are linked with pulses/modifications of the convection electric field. Cluster data allow one to show that these perturbations of the convection velocity and the associated ion structures propagate at the convection velocity.

    In contrast, polar cap local ion beams are characterized by field-aligned proton and oxygen ions with similar energies. These beams show the typical inverted V structures usually observed in the auroral zone and are associated with a quasi-static converging electric field indicative of a field-aligned electric field. The field-aligned potential drop fits well the ion energy profile. The simultaneous observation of precipitating electrons and upflowing ions of similar energies at the Cluster orbit indicates that the spacecraft are crossing the mid-altitude part of the acceleration region. In the polar cap, the parallel electric field can thus extend to altitudes higher than 5 Earth radii. A detailed analysis of the distribution functions shows that the ions are heated during their parallel acceleration and that energy is exchanged between H+ and O+. Furthermore, intense electrostatic waves are observed simultaneously. These observations could be due to an ion-ion two-stream instability.

  19. VO2+ ions in zinc lead borate glasses studied by EPR and optical absorption techniques.

    Science.gov (United States)

    Prakash, P Giri; Rao, J Lakshmana

    2005-09-01

    Electron paramagnetic resonance (EPR) and optical absorption spectra of vanadyl ions in zinc lead borate (ZnO-PbO-B2O3) glass system have been studied. EPR spectra of all the glass samples exhibit resonance signals characteristic of VO2+ ions. The values of spin-Hamiltonian parameters indicate that the VO2+ ions in zinc lead borate glasses were present in octahedral sites with tetragonal compression and belong to C4V symmetry. The spin-Hamiltonian parameters g and A are found to be independent of V2O5 content and temperature but changing with ZnO content. The decrease in Deltag( parallel)/Deltag( perpendicular) value with increase in ZnO content indicates that the symmetry around VO2+ ions is more octahedral. The decrease in intensity of EPR signal above 10 mol% of V2O5 is attributed to a fall in the ratio of the number of V4+ ions (N4) to the number of V5+ ions (N5). The number of spins (N) participating in resonance was calculated as a function of temperature for VO2+ doped zinc lead borate glass sample and the activation energy was calculated. From the EPR data, the paramagnetic susceptibility was calculated at various temperatures and the Curie constant was evaluated from the 1/chi-T graph. The optical absorption spectra show single absorption band due to VO2+ ions in tetragonally distorted octahedral sites.

  20. The Study of Two-Ion Flow in The Plasma Presheath

    Science.gov (United States)

    Wang, Xu; Ko, Eunsuk; Hershkowitz, Noah

    2004-11-01

    The ion flow created in the presheath of a weakly ionized He-Ar plasma is studied experimentally. Mobility limited flow was used to predict ion drift velocities of each species and found to be in agreement with previous LIF measurements [1] for Ar ions 2.0cm from the boundary. The phase velocity of ion acoustic wave was measured by launching a continuous sinusoidal wave, detecting the wave from electron saturation current with a cylindrical probe and time sampling with a boxcar averager. The relationship between Ar^+ and He^+ drift velocities was established by the wave dispersion relation. He^+ drift velocities were determined for given Ar^+ drift velocities and compared to the mobility limited flow predictions. Ion-ion electrostatic two stream instabilities were observed in the presheath for different positions, partial and total pressures to determine if this instability alters ion drift velocities near the sheath-presheath boundary. The instabilities predicted by fluid and kinetic dispersion relations are compared to the data. [1] G. D. Severn, Xu Wang, Eunsuk Ko and N. Hershkowitz, Phys. Rev. Lett. 90, 145001 (2003).

  1. Hot-cavity studies for the Resonance Ionization Laser Ion Source

    Energy Technology Data Exchange (ETDEWEB)

    Henares, J.L., E-mail: henares@ganil.fr [GANIL, BP 55027, 14076 Caen Cedex 5 (France); Lecesne, N.; Hijazi, L.; Bastin, B. [GANIL, BP 55027, 14076 Caen Cedex 5 (France); Kron, T. [Johannes Gutenberg-Universität Mainz, Staudinger Weg 7, 55099 Mainz (Germany); Lassen, J. [TRIUMF, 4004 Wesbrook Mall, Vancouver, BC, Canada V6T 2A3 (Canada); Le Blanc, F. [IPN Orsay, BP 1-91406 Orsay (France); Leroy, R.; Osmond, B. [GANIL, BP 55027, 14076 Caen Cedex 5 (France); Raeder, S. [Johannes Gutenberg-Universität Mainz, Staudinger Weg 7, 55099 Mainz (Germany); KU Leuven, Oude Markt 13, 3000 Leuven (Belgium); Schneider, F.; Wendt, K. [Johannes Gutenberg-Universität Mainz, Staudinger Weg 7, 55099 Mainz (Germany)

    2016-09-11

    The Resonance Ionization Laser Ion Source (RILIS) has emerged as an important technique in many Radioactive Ion Beam (RIB) facilities for its reliability, and ability to ionize target elements efficiently and element selectively. GISELE is an off-line RILIS test bench to study the implementation of an on-line laser ion source at the GANIL separator facility. The aim of this project is to determine the best technical solution which combines high selectivity and ionization efficiency with small ion beam emittance and stable long term operation. The ion source geometry was tested in several configurations in order to find a solution with optimal ionization efficiency and beam emittance. Furthermore, a low work function material was tested to reduce the contaminants and molecular sidebands generated inside the ion source. First results with ZrC ionizer tubes will be presented. Furthermore, a method to measure the energy distribution of the ion beam as a function of the time of flight will be discussed.

  2. Review of Heavy-ion Induced Desorption Studies for Particle Accelerators

    CERN Document Server

    Mahner, E

    2008-01-01

    During high-intensity heavy-ion operation of several particle accelerators worldwide, large dynamic pressure rises of orders of magnitude were caused by lost beam ions that impacted under grazing angle onto the vacuum chamber walls. This ion-induced desorption, observed, for example, at CERN, GSI, and BNL, can seriously limit the ion intensity, luminosity, and beam lifetime of the accelerator. For the heavyion program at CERN's Large Hadron Collider collisions between beams of fully stripped lead (208Pb82+) ions with a beam energy of 2.76 TeV/u and a nominal luminosity of 10**27 cm**-2 s**-1 are foreseen. The GSI future project FAIR (Facility for Antiproton and Ion Research) aims at a beam intensity of 10**12 uranium (238U28+) ions per second to be extracted from the synchrotron SIS18. Over the past years an experimental effort has been made to study the observed dynamic vacuum degradations, which are important to understand and overcome for present and future particle accelerators. The paper reviews the resu...

  3. Beam optics study of a negative ion source for neutral beam injection application at ASIPP

    Energy Technology Data Exchange (ETDEWEB)

    Wei, Jiang-Long; Liang, Li-Zhen [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); Jiang, Cai-Chao [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); Graduate school, University of Science and Technology of China, Hefei 230026 (China); Xie, Ya-Hong, E-mail: xieyh@ipp.ac.cn [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); Hu, Chun-Dong; Li, Jun; Gu, Yu-Ming; Chen, Yu-Qian [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); Li, Jing-Yong; Wu, Ming-Shan [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); Graduate school, University of Science and Technology of China, Hefei 230026 (China)

    2017-04-15

    In order to study the generation and extraction of negative ions for neutral beam injection application, a negative ion source is being designed and constructed at Institute of Plasma Physics, Chinese Academy of Sciences (ASIPP). Through a four electrode grids system inside the accelerator, a negative ion beam will be extracted and accelerated up to −60 kV on a reduced scale extraction area of 12 × 50 cm{sup 2} (the area of PG apertures is 185 cm{sup 2}). The beam optics is a key issue for the accelerator design, and greatly determine the source experimental performance in term of beam current, heat load on the grid, beam divergence, and so on. In this paper, the trajectories of electrons and negative ions were simulated in the electrode grids of the negative ion source. The filter capability of electron deflection magnet on the co-extracted electrons is evaluated and confirmed. The negative ion beam optics was designed according to the calculated results of beam divergence and beam radius along the beamlet in different acceleration voltages. The deflection effect of the electron deflection magnet on the negative ion beam was investigated in the single beamlet case and multi-beamlets case.

  4. Numerical studies of acceleration of thorium ions by a laser pulse of ultra-relativistic intensity

    Science.gov (United States)

    Domanski, Jaroslaw; Badziak, Jan

    2018-01-01

    One of the key scientific projects of ELI-Nuclear Physics is to study the production of extremely neutron-rich nuclides by a new reaction mechanism called fission-fusion using laser-accelerated thorium (232Th) ions. This research is of crucial importance for understanding the nature of the creation of heavy elements in the Universe; however, they require Th ion beams of very high beam fluencies and intensities which are inaccessible in conventional accelerators. This contribution is a first attempt to investigate the possibility of the generation of intense Th ion beams by a fs laser pulse of ultra-relativistic intensity. The investigation was performed with the use of fully electromagnetic relativistic particle-in-cell code. A sub-μm thorium target was irradiated by a circularly polarized 20-fs laser pulse of intensity up to 1023 W/cm2, predicted to be attainable at ELI-NP. At the laser intensity 1023 W/cm2 and an optimum target thickness, the maximum energies of Th ions approach 9.3 GeV, the ion beam intensity is > 1020 W/cm2 and the total ion fluence reaches values 1019 ions/cm2. The last two values are much higher than attainable in conventional accelerators and are fairly promising for the planned ELI-NP experiment.

  5. Kinetic study of sulfite ion inhibition during alcoholic fermentation of beet molasses

    Energy Technology Data Exchange (ETDEWEB)

    Glacet, A.; Letourneau, F.; Leveque, P.; Villa, P. (UER des Sciences Exactes et Naturelles, 80 - Amiens (France))

    Alcoholic fermentation cycle has been studied on beet molasses exempt from sulfite ions, and containing added amounts of these ions from 1000 to 3000 ppm. Experimental results show that fermentation duration increasing sulfite concentration in the medium from 8% to 40% if SO/sub 3//sup - -/ added varies from 1000 to 3000 ppm. A detailed kinetic study reveals that this increase occurs only during latency period. Moreover the biomass and the ethanol generation curves drawn after latency period appear to be quite linear, their slopes being independent of initial sulfite concentration. Sulfite evolution during fermentation cycle of artificial wort, under identical experimental conditions to those of wort molasses, indicates that more than 80% of these ions disappear during latency period. We have proved that this phenomenon is due to yeast action and not to any chemical reactions between sulfites ions and wort components.

  6. Erratum to: Study on Chloride Ion Penetration Resistance of Rubberized Concrete Under Steady State Condition

    Directory of Open Access Journals (Sweden)

    Md Noor Nurazuwa

    2016-01-01

    In this paper, the effect of crumb rubber, CR as fine aggregate in the concrete to enhance concrete durability against chloride ion diffusion was studied. Chloride ion diffusion in rubberized concrete was tested by migration test under steady state condition. Concrete specimen with water-to-cement ratio of 0.50 was prepared to study the CR effectiveness in comparison with lower water-to-cement ratio. In addition, 10% silica fume, SF was added to provide denser concrete and to understand its effectiveness against chloride ion diffusion. Results showed that chloride transport characteristics were improved by the increasing amount of CR in all mixed due to the fact that CR has the ability to repel water. Meanwhile, rubberized concrete with w/c = 0.35 gave better resistance against chloride ion penetration compared to w/c = 0.50. This was much improved with combination of CR and SF.

  7. Metabolic robustness and network modularity: a model study.

    Science.gov (United States)

    Holme, Petter

    2011-02-02

    Several studies have mentioned network modularity-that a network can easily be decomposed into subgraphs that are densely connected within and weakly connected between each other-as a factor affecting metabolic robustness. In this paper we measure the relation between network modularity and several aspects of robustness directly in a model system of metabolism. By using a model for generating chemical reaction systems where one can tune the network modularity, we find that robustness increases with modularity for changes in the concentrations of metabolites, whereas it decreases with changes in the expression of enzymes. The same modularity scaling is true for the speed of relaxation after the perturbations. Modularity is not a general principle for making metabolism either more or less robust; this question needs to be addressed specifically for different types of perturbations of the system.

  8. Polyampholyte Ionomer Networks

    Science.gov (United States)

    Cavicchi, Kevin; Deng, Guodong

    Novel materials that can reversibly adapt to their environment are important as functional materials. In polymer networks, dynamic bonding of the crosslinks, which can break and reform under an external stimuli (e.g. heat or mechanical stress) are of interest for functional material properties (e.g. self-healing or shape memory) and enhanced mechanical properties (e.g. toughness, strength). One general route to introduce dynamic bonds is through non-covalent interactions. In this work, poly(butyl acrylate) networks crosslinked by vinyl benzyl tri-n-octyl ammonium/phosphonium styrene sulfonate ion pairs were prepared as model system to study the thermo-mechanical properties of polyampholyte networks as a function of the network parameters, including ion-pair chemistry and crosslink density. Results of rheological behavior, mechanical and thermal properties of these materials will be presented and compared to other ionic systems, such as ionomers with pendant counter ions.

  9. Fragmentation studies of 158 A GeV Pb ions using CR39 nuclear track detectors

    CERN Document Server

    Dekhissi, H; Giorgini, M; Mandrioli, G; Manzoor, S; Patrizii, L; Popa, V; Serra, P; Togo, V

    2000-01-01

    Six stacks of CR39 nuclear track detectors with different targets were exposed to a lead ion beam of 158 A GeV at the CERN-SPS, at normal incidence, in order to study the fragmentation properties of ultra-relativistic lead nuclei. Measurements of the total, break-up and pick-up charge-changing cross sections of 158 A GeV Pb ions have been made for the first time.

  10. Studi Operasi Resin Penukar Ion Dalam Sistem Purifikasi Air Primer Pwr

    OpenAIRE

    Biyantoro, Dwi; Basuki, Kris Tri; Subagiono, Subagiono

    2006-01-01

    STUDI OPERASI RESIN PENUKAR ION DALAM SISTEM PURIFIKASI AIR PRIMER PWR. Telah dilakukan studioperasi resin penukar ion dalam sistem purifikasi air primer PWR. Air pendingin reaktor yang pada awalnya sesuaidengan persyaratan setelah pengoperasian reaktor sering kualitasnya berubah, sehingga harus dimurnikan. Unsurunsurpengotor dalam air primer PWR diidentifikasi sebagai penyebab pengotor seperti korosi, pelepasan produk fisi(Cs137, Sr90, Co60,C14, Tc99), dan pelepasan kembali unsur oleh resin ...

  11. State selective electron capture studies with slow state prepared ion beams

    CERN Document Server

    McCullough, R W

    1999-01-01

    Double translational energy spectroscopy has been successfully used to study state selective electron capture processes in atomic and molecular targets involving slow ( nu <1 au) C/sup 2+/, N/sup 2+/ and O/sup 2+/ primary ions in prepared ground or metastable states. The results show that previous TES and total one electron capture measurements involving primary ions beams containing unknown fractions of metastable states require cautious interpretation. (22 refs).

  12. Assessment of potential advantages of relevant ions for particle therapy: A model based study

    Energy Technology Data Exchange (ETDEWEB)

    Grün, Rebecca, E-mail: r.gruen@gsi.de [Department of Biophysics, GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt 64291 (Germany); Institute of Medical Physics and Radiation Protection, University of Applied Sciences Gießen, Gießen 35390 (Germany); Medical Faculty of Philipps-University Marburg, Marburg 35032 (Germany); Friedrich, Thomas; Krämer, Michael; Scholz, Michael [Department of Biophysics, GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt 64291 (Germany); Zink, Klemens [Institute of Medical Physics and Radiation Protection, University of Applied Sciences Gießen, Gießen 35390, Germany and Department of Radiotherapy and Radiation Oncology, University Medical Center Giessen and Marburg, Marburg 35043 (Germany); Durante, Marco [Department of Biophysics, GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt 64291, Germany and Department of Condensed Matter Physics, Darmstadt University of Technology, Darmstadt 64289 (Germany); Engenhart-Cabillic, Rita [Medical Faculty of Philipps-University Marburg, Marburg 35032, Germany and Department of Radiotherapy and Radiation Oncology, University Medical Center Giessen and Marburg, Marburg 35043 (Germany)

    2015-02-15

    Purpose: Different ion types offer different physical and biological advantages for therapeutic applications. The purpose of this work is to assess the advantages of the most commonly used ions in particle therapy, i.e., carbon ({sup 12}C), helium ({sup 4}He), and protons ({sup 1}H) for different treatment scenarios. Methods: A treatment planning analysis based on idealized target geometries was performed using the treatment planning software TRiP98. For the prediction of the relative biological effectiveness (RBE) that is required for biological optimization in treatment planning the local effect model (LEM IV) was used. To compare the three ion types, the peak-to-entrance ratio (PER) was determined for the physical dose (PER{sub PHY} {sub S}), the RBE (PER{sub RBE}), and the RBE-weighted dose (PER{sub BIO}) resulting for different dose-levels, field configurations, and tissue types. Further, the dose contribution to artificial organs at risk (OAR) was assessed and a comparison of the dose distribution for the different ion types was performed for a patient with chordoma of the skull base. Results: The study showed that the advantages of the ions depend on the physical and biological properties and the interplay of both. In the case of protons, the consideration of a variable RBE instead of the clinically applied generic RBE of 1.1 indicates an advantage in terms of an increased PER{sub RBE} for the analyzed configurations. Due to the fact that protons show a somewhat better PER{sub PHY} {sub S} compared to helium and carbon ions whereas helium shows a higher PER{sub RBE} compared to protons, both protons and helium ions show a similar RBE-weighted dose distribution. Carbon ions show the largest variation of the PER{sub RBE} with tissue type and a benefit for radioresistant tumor types due to their higher LET. Furthermore, in the case of a two-field irradiation, an additional gain in terms of PER{sub BIO} is observed when using an orthogonal field configuration

  13. Assessment of potential advantages of relevant ions for particle therapy: a model based study.

    Science.gov (United States)

    Grün, Rebecca; Friedrich, Thomas; Krämer, Michael; Zink, Klemens; Durante, Marco; Engenhart-Cabillic, Rita; Scholz, Michael

    2015-02-01

    Different ion types offer different physical and biological advantages for therapeutic applications. The purpose of this work is to assess the advantages of the most commonly used ions in particle therapy, i.e., carbon ((12)C), helium ((4)He), and protons ((1)H) for different treatment scenarios. A treatment planning analysis based on idealized target geometries was performed using the treatment planning software TRiP98. For the prediction of the relative biological effectiveness (RBE) that is required for biological optimization in treatment planning the local effect model (LEM IV) was used. To compare the three ion types, the peak-to-entrance ratio (PER) was determined for the physical dose (PERPHY S), the RBE (PERRBE), and the RBE-weighted dose (PERBIO) resulting for different dose-levels, field configurations, and tissue types. Further, the dose contribution to artificial organs at risk (OAR) was assessed and a comparison of the dose distribution for the different ion types was performed for a patient with chordoma of the skull base. The study showed that the advantages of the ions depend on the physical and biological properties and the interplay of both. In the case of protons, the consideration of a variable RBE instead of the clinically applied generic RBE of 1.1 indicates an advantage in terms of an increased PERRBE for the analyzed configurations. Due to the fact that protons show a somewhat better PERPHY S compared to helium and carbon ions whereas helium shows a higher PERRBE compared to protons, both protons and helium ions show a similar RBE-weighted dose distribution. Carbon ions show the largest variation of the PERRBE with tissue type and a benefit for radioresistant tumor types due to their higher LET. Furthermore, in the case of a two-field irradiation, an additional gain in terms of PERBIO is observed when using an orthogonal field configuration for carbon ions as compared to opposing fields. In contrast, for protons, the PERBIO is almost

  14. An ICR study of ion-molecule reactions of PH(n)+ ions. [of importance to interstellar chemistry, using ion cyclotron resonance techniques

    Science.gov (United States)

    Thorne, L. R.; Anicich, V. G.; Huntress, W. T.

    1983-01-01

    The reactions of PH(n)+ ions (n = 0-3) were examined with a number of neutrals using ion-cyclotron-resonance techniques. The reactions examined have significance for the distribution of phosphorus in interstellar molecules. The results indicate that interstellar molecules containing the P-O bond are likely to be more abundant than those containing the P-H bond.

  15. Theoretical study on photorecombination of C V ion

    Science.gov (United States)

    Ma, Kun; Xie, Lu-You; Zhang, Deng-Hong; Dong, Chen-Zhong

    2015-07-01

    The partial and total photorecombination cross sections of the ground-state C V ion in the KLL and KLM resonant energy regions were calculated in detail by using the Dirac atomic R-matrix code based on a fully relativistic R-matrix method. Meanwhile, the principal resonant lines in each photorecombination channel have been classified according to the calculated transition energies and probabilities from the KLL and KLM resonant states to the 1s2nl (n = 2, 3 and l = s,p,d) final states. The validity of these calculations is assessed by comparison with previously published experimental and theoretical data. The good agreement between the present calculated results and those obtained using different approaches confirms the accuracy of the present results. In addition, it is found that the damping effect can be neglected for the KLL resonant, but not for the KLM resonant. Project supported by the National Natural Science Foundation of China (Grant Nos. 11274254, U1332206, and U1331122) and the International Scientific and Technological Cooperative Project of Gansu Province, China (Grant No. 1104WCGA186).

  16. Computational Studies of Marine Toxins Targeting Ion Channels

    Directory of Open Access Journals (Sweden)

    Serdar Kuyucak

    2013-03-01

    Full Text Available Toxins from marine animals offer novel drug leads for treatment of diseases involving ion channels. Computational methods could be very helpful in this endeavour in several ways, e.g., (i constructing accurate models of the channel-toxin complexes using docking and molecular dynamics (MD simulations; (ii determining the binding free energies of toxins from umbrella sampling MD simulations; (iii predicting the effect of mutations from free energy MD simulations. Using these methods, one can design new analogs of toxins with improved affinity and selectivity properties. Here we present a review of the computational methods and discuss their applications to marine toxins targeting potassium and sodium channels. Detailed examples from the potassium channel toxins—ShK from sea anemone and κ-conotoxin PVIIA—are provided to demonstrate capabilities of the computational methods to give accurate descriptions of the channel-toxin complexes and the energetics of their binding. An example is also given from sodium channel toxins (μ-conotoxin GIIIA to illustrate the differences between the toxin binding modes in potassium and sodium channels.

  17. Thin Coating of Microporous Organic Network Makes a Big Difference: Sustainability Issue of Ni Electrodes on the PET Textile for Flexible Lithium-Ion Batteries.

    Science.gov (United States)

    Kang, Chang Wan; Choi, Jaewon; Ko, Yoon-Joo; Lee, Sang Moon; Kim, Hae Jin; Kim, Jong Pil; Son, Seung Uk

    2017-10-25

    Poly(ethylene terephthalate) fibers (PET-Fs) were coated with microporous organic networks (MONs) by the Sonogashira coupling of tetra(4-ethynylphenyl)methane with 1,4-diiodobenzene. Ni was deposited on the PET-F@MON via electroless deposition. Interestingly, although Ni on the PET-F showed a sharp decrease in conductivity in repeated bending tests, the PET-F@MON@Ni showed excellent retention of conductivity. We suggest that thin MON layers play roles of an efficient binder for Ni attachment to fibers and a structural buffer for the relaxation of bending strain. The positive effect of MON was supported by scanning electron microscopy studies of the PET-F@Ni or PET-F@MON@Ni retrieved after 2000 bending numbers. Although Ni on the PET-F showed severe detachment after bending tests, PET-F@MON@Ni retained the original morphologies. The pouch cells of lithium-ion batteries fabricated using PET-F@MON@Ni as the current collectors showed excellent performance against bending.

  18. Turbulent energization of ions in warm collisionless plasmas - hybrid simulation study

    Science.gov (United States)

    Maneva, Yana; Vinas, Adolfo; Poedts, Stefaan

    2016-04-01

    Turbulent waves and structures are ubiquitous and indispensable part of the solar wind throughout the Heliosphere and have crucial contribution to the energization of particles in the warm collisionless plasma near the Earth, especially in regions where strong wave activity is observed. Wave-based turbulent energization of protons and minor ions in the undisturbed solar wind can occur through resonant and non-resonant wave-particle interactions and related wave absorption, particle scattering and diffusion in phase space. The efficiency of the ion heating depends on the characteristics of the waves carrying energy at the ion scales, such as polarization, direction of propagation and spectral properties of the fluctuations. The observed solar wind turbulence includes different types of waves at all scales, starting from the large-scale fluid regime and reaching towards the small electron scales, where the magnetic fluctuations are ultimately dissipated. Although the spatial and temporal scales of these fluctuation are separated by few orders of magnitudes, they can still exchange energy due to large and small-scales turbulent cascades. Trying to model part of the solar wind turbulence at the ion scales we assume a superposition of non-resonant Alfvén waves, which follow Kolmogorov-type spectral slope by construction. Such waves are frequently observed in situ in the solar wind, and yet their specific role for the energization of minor ions remains unclear. We perform 2.5D hybrid simulations with fluid electrons, kinetic ions and minor ions to study the effects of turbulent energization of minor ions by initial broad-band spectra, consisting of parallel and oblique forward propagating Alfvén waves. The numerical model is driven by observations of the solar wind plasma parameters at 1AU and takes into account the differential streaming between the protons and the minor ions. For the chosen spectral range of the external initial wave spectra we observe preferential

  19. Study of negative hydrogen ion beam optics using the 3D3V PIC model

    Energy Technology Data Exchange (ETDEWEB)

    Miyamoto, K., E-mail: kmiyamot@naruto-u.ac.jp [Naruto University of Education, 748 Nakashima, Takashima, Naruto-cho, Naruto-shi, Tokushima, 772-8502 (Japan); Nishioka, S.; Goto, I.; Hatayama, A. [Faculty of Science and Technology, Keio University, 3-14-1, Hiyoshi, Kohoku-ku, Yokohama, 223-8522 (Japan); Hanada, M.; Kojima, A. [Japan Atomic Energy Agency, 801-1,Mukoyama, Naka, 319-0913 (Japan)

    2015-04-08

    The mechanism of negative ion extraction under real conditions with the complex magnetic field is studied by using the 3D PIC simulation code. The extraction region of the negative ion source for the negative ion based neutral beam injection system in fusion reactors is modelled. It is shown that the E x B drift of electrons is caused by the magnetic filter and the electron suppression magnetic field, and the resultant asymmetry of the plasma meniscus. Furthermore, it is indicated that that the asymmetry of the plasma meniscus results in the asymmetry of negative ion beam profile including the beam halo. It could be demonstrated theoretically that the E x B drift is not significantly weakened by the elastic collisions of the electrons with neutral particles.

  20. Semi-aerobic stabilized landfill leachate treatment by ion exchange resin: isotherm and kinetic study

    Science.gov (United States)

    Zamri, Mohd Faiz Muaz Ahmad; Kamaruddin, Mohamad Anuar; Yusoff, Mohd Suffian; Aziz, Hamidi Abdul; Foo, Keng Yuen

    2017-05-01

    This study was carried out to investigate the treatability of ion exchange resin (Indion MB 6 SR) for the removal of chromium (VI), aluminium (III), zinc (II), copper (II), iron (II), and phosphate (PO4)3-, chemical oxygen demand (COD), ammonia nitrogen (NH3-N) and colour from semi-aerobic stabilized leachate by batch test. A range of ion exchange resin dosage was tested towards the removal efficiency of leachate parameters. It was observed that equilibrium data were best represented by the Langmuir model for metal ions and Freundlich was ideally fit for COD, NH3-N and colour. Intra particle diffusion model, pseudo first-order and pseudo second-order isotherm models were found ideally fit with correlation of the experimental data. The findings revealed that the models could describe the ion exchange kinetic behaviour efficiently, which further suggests comprehensive outlook for the future research in this field.

  1. Accelerator and Ion Beam Tradeoffs for Studies of Warm Dense Matter

    CERN Document Server

    Barnard, John J; Callahan, Debra; Davidson, Ronald C; Friedman, Alex; Grant-Logan, B; Grisham, Larry; Lee, Edward; Lee, Richard; Olson, Craig; Rose, David; Santhanam, Parthiban; Sessler, Andrew M; Staples, John W; Tabak, Max; Welch, Dale; Wurtele, Jonathan; Yu, Simon

    2005-01-01

    One approach to heat a target to "Warm Dense Matter" conditions (similar, for example, to the interiors of giant planets or certain stages in Inertial Confinement Fusion targets), is to use intense ion beams as the heating source. By consideration of ion beam phase space constraints, both at the injector, and at the final focus, and consideration of simple equations of state, approximate conditions at a target foil may be calculated. Thus target temperature and pressure may be calculated as a function of ion mass, ion energy, pulse duration, velocity tilt, and other accelerator parameters. We examine the variation in target performance as a function of various beam and accelerator parameters, in the context of several different accelerator concepts, recently proposed for WDM studies.

  2. Inter-organizational network studies - a literature review

    DEFF Research Database (Denmark)

    Bergenholtz, Carsten; Waldstrøm, Christian

    The vast body of studies on inter-organizational networks suffers from a number of conceptual and methodological gaps which render some of the studies incompatible and hinder a greater understanding and coherence of the field. Part of the problem is that quite a number of the concepts, methods...... literature review of the last 12 years' research on inter-organizational networks, with a focus on the methodological aspects. The findings of this paper is that few of the previous studies have used the full methodological (and thus theoretical) scope of the available data and that the most cited papers...

  3. Recurrence networks to study dynamical transitions in a turbulent combustor

    Science.gov (United States)

    Godavarthi, V.; Unni, V. R.; Gopalakrishnan, E. A.; Sujith, R. I.

    2017-06-01

    Thermoacoustic instability and lean blowout are the major challenges faced when a gas turbine combustor is operated under fuel lean conditions. The dynamics of thermoacoustic system is the result of complex nonlinear interactions between the subsystems—turbulent reactive flow and the acoustic field of the combustor. In order to study the transitions between the dynamical regimes in such a complex system, the time series corresponding to one of the dynamic variables is transformed to an ɛ-recurrence network. The topology of the recurrence network resembles the structure of the attractor representing the dynamics of the system. The transitions in the thermoacoustic system are then captured as the variation in the topological characteristics of the network. We show the presence of power law degree distribution in the recurrence networks constructed from time series acquired during the occurrence of combustion noise and during the low amplitude aperiodic oscillations prior to lean blowout. We also show the absence of power law degree distribution in the recurrence networks constructed from time series acquired during the occurrence of thermoacoustic instability and during the occurrence of intermittency. We demonstrate that the measures derived from recurrence network can be used as tools to capture the transitions in the turbulent combustor and also as early warning measures for predicting impending thermoacoustic instability and blowout.

  4. Adsorption of Chromium Ions by Acid Activated Low Cost Carbon-Kinetic,Thermodynamic and Equilibrium Studies

    Directory of Open Access Journals (Sweden)

    B. R. Venkatraman

    2009-01-01

    Full Text Available A carbonaceous adsorbent prepared from an indigenous waste, by acid treatment was tested for its efficiency in removing metal ions. The process parameters studied include agitation time, initial metal ions concentration, carbon dose, pH and temperature. The adsorption followed first order reaction equation and the rate is mainly controlled by intra-particle diffusion. Freundlich and Langmuir isotherm models were applied to the equilibrium data. The adsorption capacity (Qm obtained from the Langmuir isotherm plot were found to around 30 mg/g at an initial pH of 7.0. The temperature variation study showed that the metal ions adsorption is endothermic and spontaneous with increased randomness at the solid solution interface. Significant effect on adsorption was observed on varying the pH of the metal ion solutions. The Langmuir and Freundlich adsorption isotherms obtained, positive ΔH0 value, pH dependent results and desorption of metal ions in mineral acid suggest that the adsorption of metal ions on BBC involves chemisorption as well as physisorption mechanism.

  5. Adsorption of Nickel Ion by Low Cost Carbon-Kinetic, Thermodynamic and Equilibrium Studies

    Directory of Open Access Journals (Sweden)

    V. Vijayakumaran

    2009-01-01

    Full Text Available A carbonaceous adsorbent prepared from an indigenous waste, by acid treatment was tested for its efficiency in removing nickel ion. The process parameters studied include agitation time, initial metal ion concentration, carbon dose, pH and temperature. The adsorption followed first order reaction equation and the rate is mainly controlled by intraparticle diffusion. Freundlich and Langmuir isotherm models were applied to the equilibrium data. The adsorption capacity (Qm obtained from the Langmuir isotherm plot were found to around 43 mg/g at an initial pH of 7.0. The temperature variation study showed that the nickel ions adsorption is endothermic and spontaneous with increased randomness at the solid solution interface. Significant effect on adsorption was observed on varying the pH of the nickel ion solutions. The Langmuir and Freundlich adsorption isotherms obtained, positive ΔH0 value, pH dependent results and desorption of metal ions in mineral acid suggest that the adsorption of nickel ion on MCC involves chemisorption as well as physisorption mechanism.

  6. Study of co-authorship network of papers in the Journal of Research in Medical Sciences using social network analysis

    Directory of Open Access Journals (Sweden)

    Firoozeh Zare-Farashbandi

    2014-01-01

    Full Text Available Background: Co-authorship is one of the most tangible forms of research collaboration. A co-authorship network is a social network in which the authors through participation in one or more publication through an indirect path have linked to each other. The present research using the social network analysis studied co-authorship network of 681 articles published in Journal of Research in Medical Sciences (JRMS during 2008-2012. Materials and Methods: The study was carried out with the scientometrics approach and using co-authorship network analysis of authors. The topology of the co-authorship network of 681 published articles in JRMS between 2008 and 2012 was analyzed using macro-level metrics indicators of network analysis such as density, clustering coefficient, components and mean distance. In addition, in order to evaluate the performance of each authors and countries in the network, the micro-level indicators such as degree centrality, closeness centrality and betweenness centrality as well as productivity index were used. The UCINET and NetDraw softwares were used to draw and analyze the co-authorship network of the papers. Results: The assessment of the authors productivity in this journal showed that the first ranks were belonged to only five authors, respectively. Furthermore, analysis of the co-authorship of the authors in the network demonstrated that in the betweenness centrality index, three authors of them had the good position in the network. They can be considered as the network leaders able to control the flow of information in the network compared with the other members based on the shortest paths. On the other hand, the key role of the network according to the productivity and centrality indexes was belonged to Iran, Malaysia and United States of America. Conclusion: Co-authorship network of JRMS has the characteristics of a small world network. In addition, the theory of 6° separation is valid in this network was also true.

  7. Synthesis and Characterization of Network Single Ion Conductors(NSIC) Based On Comb-Branched Polyepoxide Ethers and LithiumBis(allylmalonato)borate

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Xiao-Guang; Kerr, John B.

    2004-07-11

    Network single ion conductors (NSICs) based on comb-branch polyepoxide ethers and lithium bis(allylmalonato) borate have been synthesized and thoroughly characterized by means of ionic conductivity measurements, electrochemical impedance and by dynamic mechanical analysis (DMA). The materials have been tested as battery electrolytes by cycling in symmetrical Li/Li half cells and in Li/V{sub 6}O{sub 13} full cells in which the NSIC was used as both binder and electrolyte in the cathode electrode and as the electrolyte separator membrane,. The substitution of the trimethylene oxide (TMO) unit into the side chains in place of ethylene oxide (EO) units increased the polymerion mobility (lower glass transition temperature). However, the ionic conductivity was nearly one and half orders of magnitude lower than the corresponding pure EO based single ion conductor at the same salt concentration. This effect may be ascribed to the lower dielectric constant of the TMO side chains that result in a lower concentration of free conducting lithium cations. For a highly cross-linked system (EO/Li=20), only 47 wt% plasticizing solvent (ethylene carbonate (EC)/ethyl methyl carbonate (EMC), 1/1 by wt) could be taken up and the ionic conductivity was only increased by one order of magnitude over the dry polyelectrolyte while for a less densely crosslinked system (EO/Li=80), up to 75 wt% plasticizer could be taken up and the ionic conductivity was increased by nearly two orders of magnitude. A Li/Li symmetric cell that was cycled at 85 C at a current density of 25{micro}Acm{sup -2} showed no concentration polarization or diffusional relaxation, consistent with a lithium ion transference number of one. However, both the bulk and interfacial impedances increased after 20 cycles, apparently due to continued cross-linking reactions within the membrane and on the surface of the lithium electrodes. A Li/V{sub 6}O{sub 13} full cell constructed using a single ion conductor gel (propylene

  8. Studying the Adsorption Behavior of Copper Ions in Industrial Wastewater, Using Modified Electrospun Polymeric Nano Fiber

    Directory of Open Access Journals (Sweden)

    Davood Kaviani

    2016-09-01

    Full Text Available Background & Aims of the Study:  Soil and water pollution to heavy metals is a serious threat for environment and human health. Finding an effective way for refining water from these metals is very important. The aim of this study was modifying electrospun polymeric nano fibers and studying its efficiency for copper ion omission in water solutions. Materials & Methods: In this study, nano fiber was produced by solution electrospun polystyrene in DMF/THF solvent and produced nano fiber was used for copper pre-concentration in waste water sample. In this study, an investigation of primary PH of solution, adsorption particle size, cleaning solvent volume, salt supply, contact time duration of adsorption material on copper ion adsorption supply was done, using modified nano fiber. Results: According to this study, copper adsorption process with correlation coefficient of (R2 in scope of 0.986 by Langmuir and Freundlich are describable. Findings show that, pH optimized amount for isolating copper ion on absorbent level is 7, absorbent particle size is 0.006 g/l, salt 1.3, potassium nitrate and the contact time of absorbent material on copper ion adsorption is 10 minutes. Copper ion adsorbate was cleaned, using 0.7 ml methanol. Most of obtrusive ions didn't have any inconvenience for copper ion isolation and measuring. The mean of the method was 2.7 µg/l and standard deviation was lower than %4. Conclusions: this method was done on actual samples which findings show that, this method has the ability of cooper adsorption and can use this method for measuring heavy metals like copper in different tissues. This method because of having the privilege for isolating and pre concentrating different kind of mineral and organic is used successfully in different samples.

  9. A Study of Rank Defect and Network Effect in Processing the CMONOC Network on Bernese

    Directory of Open Access Journals (Sweden)

    Weiwei Wu

    2018-02-01

    Full Text Available High-precision GPS data processing on Bernese has been employed to routinely resolve daily position solutions of GPS stations in the Crustal Movement Observation Network of China (CMONOC. The rank-deficient problems of the normal equation (NEQ system and the network effect on the frame alignment of NEQs in the processing of CMONOC data on Bernese still present difficulties. In this study, we diagnose the rank-deficient problems of the original NEQ, review the efficiency of the controlled datum removal (CDR method in filtering out the three frame-origin-related datum contents, investigate the reliabilities of the inherited frame orientation and scale information from the fixation of the GPS satellite orbits and the Earth rotation parameters in establishing the NEQ of the CMONOC network on Bernese, and analyze the impact of the network effect on the position time series of GPS stations. Our results confirm the nonsingularity of the original NEQ and the efficiency of the CDR filtering in resolving the rank-deficient problems; show that the frame origin parameters are weakly defined and should be stripped off, while the frame orientation and scale parameters should be retained due to their insufficient redefinition from the minimal constraint (MC implementation through inhomogeneous and asymmetrical fiducial networks; and reveal the superiority of a globally distributed fiducial network for frame alignment of the reconstructed NEQs via No-Net-Translation (NNT MC conditions. Finally, we attribute the two apparent discontinuities in the position time series to the terrestrial reference frame (TRF conversions of the GPS satellite orbits, and identify it as the orbit TRF effect.

  10. Ion mobility studies of carbohydrates as group I adducts: isomer specific collisional cross section dependence on metal ion radius.

    Science.gov (United States)

    Huang, Yuting; Dodds, Eric D

    2013-10-15

    Carbohydrates play numerous critical roles in biological systems. Characterization of oligosaccharide structures is essential to a complete understanding of their functions in biological processes; nevertheless, their structural determination remains challenging in part due to isomerism. Ion mobility spectrometry provides the means to resolve gas phase ions on the basis of their shape-to-charge ratios, thus providing significant potential for separation and differentiation of carbohydrate isomers. Here, we report on the determination of collisional cross sections for four groups of isomeric carbohydrates (including five isomeric disaccharides, four isomeric trisaccharides, two isomeric pentasaccharides, and two isomeric hexasaccharides) as their group I metal ion adducts (i.e., [M + Li](+), [M + Na](+), [M + K](+), [M + Rb](+), and [M + Cs](+)). In all, 65 collisional cross sections were measured, the great majority of which have not been previously reported. As anticipated, the collisional cross sections of the carbohydrate metal ion adducts generally increase with increasing metal ion radius; however, the collisional cross sections were found to scale with the group I cation size in isomer specific manners. Such measurements are of substantial analytical value, as they illustrate how the selection of charge carrier influences carbohydrate ion mobility determinations. For example, certain pairs of isomeric carbohydrates assume unique collisional cross sections upon binding one metal ion, but not another. On the whole, these data suggest a role for the charge carrier as a probe of carbohydrate structure and thus have significant implications for the continued development and application of ion mobility spectrometry for the distinction and resolution of isomeric carbohydrates.

  11. Studies of Ion Acceleration from Thin Solid-Density Targets on High-Intensity Lasers

    Science.gov (United States)

    Willis, Christopher R.

    Over the past two decades, a number of experiments have been performed demonstrating the acceleration of ions from the interaction of an intense laser pulse with a thin, solid density target. These ions are accelerated by quasi-static electric fields generated by energetic electrons produced at the front of the target, resulting in ion energies up to tens of MeV. These ions have been widely studied for a variety of potential applications ranging from treatment of cancer to the production of neutrons for advanced radiography techniques. However, realization of these applications will require further optimization of the maximum energy, spectrum, or species of the accelerated ions, which has been a primary focus of research to date. This thesis presents two experiments designed to optimize several characteristics of the accelerated ion beam. The first of these experiments took place on the GHOST laser system at the University of Texas at Austin, and was designed to demonstrate reliable acceleration of deuterium ions, as needed for the most efficient methods of neutron generation from accelerated ions. This experiment leveraged cryogenically cooled targets coated in D2 O ice to suppress the protons which typically dominate the accelerated ions, producing as many as 2 x 1010 deuterium ions per 1 J laser shot, exceeding the proton yield by an average ratio of 5:1. The second major experiment in this work was performed on the Scarlet laser system at The Ohio State University, and studied the accelerated ion energy, yield, and spatial distribution as a function of the target thickness. In principle, the peak energy increases with decreasing target thickness, with the thinnest targets accessing additional acceleration mechanisms which provide favorable scaling with the laser intensity. However, laser prepulse characteristics provide a lower bound for the target thickness, yielding an optimum target thickness for ion acceleration which is dependent on the laser system. This

  12. A computational study of routing algorithms for realistic transportation networks

    Energy Technology Data Exchange (ETDEWEB)

    Jacob, R.; Marathe, M.V.; Nagel, K.

    1998-12-01

    The authors carry out an experimental analysis of a number of shortest path (routing) algorithms investigated in the context of the TRANSIMS (Transportation Analysis and Simulation System) project. The main focus of the paper is to study how various heuristic and exact solutions, associated data structures affected the computational performance of the software developed especially for realistic transportation networks. For this purpose the authors have used Dallas Fort-Worth road network with very high degree of resolution. The following general results are obtained: (1) they discuss and experimentally analyze various one-one shortest path algorithms, which include classical exact algorithms studied in the literature as well as heuristic solutions that are designed to take into account the geometric structure of the input instances; (2) they describe a number of extensions to the basic shortest path algorithm. These extensions were primarily motivated by practical problems arising in TRANSIMS and ITS (Intelligent Transportation Systems) related technologies. Extensions discussed include--(i) time dependent networks, (ii) multi-modal networks, (iii) networks with public transportation and associated schedules. Computational results are provided to empirically compare the efficiency of various algorithms. The studies indicate that a modified Dijkstra`s algorithm is computationally fast and an excellent candidate for use in various transportation planning applications as well as ITS related technologies.

  13. Exploiting sensitivity analysis in Bayesian networks for consumer satisfaction study

    NARCIS (Netherlands)

    Jaronski, W.; Bloemer, J.M.M.; Vanhoof, K.; Wets, G.

    2004-01-01

    The paper presents an application of Bayesian network technology in a empirical customer satisfaction study. The findings of the study should provide insight as to the importance of product/service dimensions in terms of the strength of their influence on overall satisfaction. To this end we apply a

  14. Comparative Study of Elastic Network Model and Protein Contact Network for Protein Complexes: The Hemoglobin Case

    Directory of Open Access Journals (Sweden)

    Guang Hu

    2017-01-01

    Full Text Available The overall topology and interfacial interactions play key roles in understanding structural and functional principles of protein complexes. Elastic Network Model (ENM and Protein Contact Network (PCN are two widely used methods for high throughput investigation of structures and interactions within protein complexes. In this work, the comparative analysis of ENM and PCN relative to hemoglobin (Hb was taken as case study. We examine four types of structural and dynamical paradigms, namely, conformational change between different states of Hbs, modular analysis, allosteric mechanisms studies, and interface characterization of an Hb. The comparative study shows that ENM has an advantage in studying dynamical properties and protein-protein interfaces, while PCN is better for describing protein structures quantitatively both from local and from global levels. We suggest that the integration of ENM and PCN would give a potential but powerful tool in structural systems biology.

  15. Ion release from orthodontic brackets in 3 mouthwashes: an in-vitro study.

    Science.gov (United States)

    Danaei, Shahla Momeni; Safavi, Afsaneh; Roeinpeikar, S M Mehdi; Oshagh, Morteza; Iranpour, Shiva; Omidkhoda, Maryam; Omidekhoda, Maryam

    2011-06-01

    Stainless steel orthodontic brackets can release metal ions into the saliva. Fluoridated mouthwashes are often recommended to orthodontic patients to reduce the risk of white-spot lesions around their brackets. However, little information is available regarding the effect of different mouthwashes in ion release of orthodontic brackets. The purpose of this study was to measure the amount of metal ion release from orthodontic brackets when kept in different mouthwashes. One hundred sixty stainless steel brackets (0.022-in, 3M Unitek, Monrovia, Calif) were divided randomly into 4 equal groups and immersed in Oral B (Procter & Gamble, Weybridge, United Kingdom), chlorhexidine (Shahdaru Labratories, Tehran, Iran), and Persica (Poursina Pharmaceutical Laboratories, Tehran, Iran) mouthwashes and distilled deionized water and incubated at 37°C for 45 days. Nickel, chromium, iron, copper, and manganese released from the orthodontic brackets were measured with an inductively coupled plasma spectrometer. For statistical analysis, 1-way analysis of variance (ANOVA) and the Duncan multiple-range tests were used. The results showed that ion release in deionized water was significantly (P 0.05) in nickel, chromium, iron, and copper ion release in the Oral B and Persica mouthwashes. The level of manganese release was significantly different in all 4 groups. If ion release is a concern, Oral B and Persica mouthwashes might be better options than chlorhexidine for orthodontic patients with stainless steel brackets. Copyright © 2011 American Association of Orthodontists. Published by Mosby, Inc. All rights reserved.

  16. A comparative study of silicon detector degradation under irradiation by heavy ions and relativistic protons

    Science.gov (United States)

    Eremin, V.; Mitina, D.; Fomichev, A.; Kiselev, O.; Egorov, N.; Eremin, I.; Shepelev, A.; Verbitskaya, E.

    2018-01-01

    Silicon detectors irradiated by 40Ar ions with the energy of 1.62 GeV were studied with the goal to find the parameters of radiation damage induced by ions. The measurements of the I–V characteristics, temperature dependences of the detector bulk current, deep level spectra and current pulse response were carried out for detectors irradiated within the fluence range 5×1010–2.3×1013 ion/cm2 and the obtained results were compared with the corresponding data for detectors irradiated by 23 GeV protons. It is shown that the processes of defect introduction by ions and overall radiation damage are similar to those induced by 23 GeV protons, while the introduction rates of radiation defects and current generation centers are about ten times higher for irradiation by 40Ar ions. The fact that these processes have much in common gives grounds to use the physical models and characteristic parametrization such as those developed earlier for detectors irradiated by protons and neutrons to build the long-term scenario of Si detector operation in the Time-Of-Flight diagnostic system of Super FRagment Separator designed at GSI for the future Facility for Antiproton and Ion Research, FAIR.

  17. High Resolution Studies of the Origins of Polyatomic Ions in Inductively Coupled Plasma-Mass Spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Ferguson, Jill Wisnewski [Iowa State Univ., Ames, IA (United States)

    2006-01-01

    The inductively coupled plasma (ICP) is an atmospheric pressure ionization source. Traditionally, the plasma is sampled via a sampler cone. A supersonic jet develops behind the sampler, and this region is pumped down to a pressure of approximately one Torr. A skimmer cone is located inside this zone of silence to transmit ions into the mass spectrometer. The position of the sampler and skimmer cones relative to the initial radiation and normal analytical zones of the plasma is key to optimizing the useful analytical signal [1]. The ICP both atomizes and ionizes the sample. Polyatomic ions form through ion-molecule interactions either in the ICP or during ion extraction [l]. Common polyatomic ions that inhibit analysis include metal oxides (MO+), adducts with argon, the gas most commonly used to make up the plasma, and hydride species. While high resolution devices can separate many analytes from common interferences, this is done at great cost in ion transmission efficiency--a loss of 99% when using high versus low resolution on the same instrument [2]. Simple quadrupole devices, which make up the bulk of ICP-MS instruments in existence, do not present this option. Therefore, if the source of polyatomic interferences can be determined and then manipulated, this could potentially improve the figures of merit on all ICP-MS devices, not just the high resolution devices often utilized to study polyatomic interferences.

  18. Global Malaysian Studies Network: A Proposal to Australian National University

    OpenAIRE

    Ahmad Rizal Mohd Yusof; Zarina Othman; Shamsul, A.B.; Mohamed Abu Bakar Kassim

    2014-01-01

    Problem statement: Global Malaysian Studies Network (GMSN) is an idea proposed to Australian National University (ANU) in setting up its Malaysian Studies. Currently, there are a number of academic institutions which have established its Malaysian Studies. However, there have been problems and restraints where some research institutes have failed to effectively deliver such studies and in turn drives institute to shift to the other studies which promise good students and research funds. With ...

  19. Conversion Reaction Mechanisms in Lithium Ion Batteries: Study of the Binary Metal Fluoride Electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Feng; Robert, Rosa; Chernova, Natasha A.; Pereira, Nathalie; Omenya, Fredrick; Badway, Fadwa; Hua, Xiao; Ruotolo, Michael; Zhang, Ruigang; Wu, Lijun; Volkov, Vyacheslav; Su, Dong; Key, Baris; Whittingham, M. Stanley; Grey, Clare P.; Amatucci, Glenn G.; Zhu, Yimei; Graetz, Jason (Binghamton); (Rutgers); (BNL); (Cambridge); (SBU)

    2015-10-15

    Materials that undergo a conversion reaction with lithium (e.g., metal fluorides MF{sub 2}: M = Fe, Cu, ...) often accommodate more than one Li atom per transition-metal cation, and are promising candidates for high-capacity cathodes for lithium ion batteries. However, little is known about the mechanisms involved in the conversion process, the origins of the large polarization during electrochemical cycling, and why some materials are reversible (e.g., FeF{sub 2}) while others are not (e.g., CuF{sub 2}). In this study, we investigated the conversion reaction of binary metal fluorides, FeF{sub 2} and CuF{sub 2}, using a series of local and bulk probes to better understand the mechanisms underlying their contrasting electrochemical behavior. X-ray pair-distribution-function and magnetization measurements were used to determine changes in short-range ordering, particle size and microstructure, while high-resolution transmission electron microscopy (TEM) and electron energy-loss spectroscopy (EELS) were used to measure the atomic-level structure of individual particles and map the phase distribution in the initial and fully lithiated electrodes. Both FeF{sub 2} and CuF{sub 2} react with lithium via a direct conversion process with no intercalation step, but there are differences in the conversion process and final phase distribution. During the reaction of Li{sup +} with FeF{sub 2}, small metallic iron nanoparticles (<5 nm in diameter) nucleate in close proximity to the converted LiF phase, as a result of the low diffusivity of iron. The iron nanoparticles are interconnected and form a bicontinuous network, which provides a pathway for local electron transport through the insulating LiF phase. In addition, the massive interface formed between nanoscale solid phases provides a pathway for ionic transport during the conversion process. These results offer the first experimental evidence explaining the origins of the high lithium reversibility in FeF{sub 2}. In contrast

  20. Value Assessment of Distribution Network Reconfiguration: A Danish Case Study

    DEFF Research Database (Denmark)

    Vaskantiras, Georgios; You, Shi

    2016-01-01

    Distribution network reconfiguration is a mechanism that can improve the distribution system performance from multiple perspectives. In the context of smart grid wherein the degrees of automation and intelligence are high, the potential value of network reconfiguration can be significant....... This paper presents a case study-based analysis to explore the potential value of reconfiguration in detail. The study is performed using a 10kV distribution grid of Denmark, while reconfiguration is applied to minimize the energy losses under both normal and post-fault conditions. The results show...... that although the reconfiguration is performed to achieve a single objective, the overall network performance is improved. In addition, the value achieved by reconfiguration can be very sensitive to the reconfiguration frequency and the associated cost....

  1. Soft- to network hard-material for constructing both ion- and electron-conductive hierarchical porous structure to significantly boost energy density of a supercapacitor.

    Science.gov (United States)

    Yang, Pingping; Xie, Jiale; Guo, Chunxian; Li, Chang Ming

    2017-01-01

    Soft-material PEDOT is used to network hard Co3O4 nanowires for constructing both ion- and electron-conductive hierarchical porous structure Co3O4/PEDOT to greatly boost the capacitor energy density than sum of that of plain Co3O4 nanowires and PEDOT film. Specifically, the networked hierarchical porous structure of Co3O4/PEDOT is synthesized and tailored through hydrothermal method and post-electrochemical polymerization method for the PEDOT coating onto Co3O4 nanowires. Typically, Co3O4/PEDOT supercapacitor gets a highest areal capacitance of 160mFcm-2 at a current density of 0.2mAcm-2, which is about 2.2 times larger than the sum of that of plain Co3O4 NWs (0.92mFcm-2) and PEDOT film (69.88mFcm-2). Besides, if only PEDOT as active mass is counted, Co3O4/PEDOT cell can achieve a highest capacitance of 567.21Fg-1, this is the highest capacitance value obtained by PEDOT-based supercapacitors. Furthermore, this soft-hard network porous structure also achieves a high cycling stability of 93% capacitance retention after the 20,000th cycle. This work demonstrates a new approach to constructing both ion and electron conductive hierarchical porous structure to significantly boost energy density of a supercapacitor. Copyright © 2016 Elsevier Inc. All rights reserved.

  2. Sanad and Ulama Network of the Quranic Studies in Nusantara

    Directory of Open Access Journals (Sweden)

    Zainul Milal Bizawie

    2015-07-01

    Full Text Available In several studies related to the development of Qur'anic studies, especially in the field of interpretation, implicit questions remain unanswered on current connectivity and the authority of science in the Qur'anic studies as well as the capability of a person in compiling commentary or interpretation of the Qur’an that has an effect on Islamic society in Indonesia. Interpretations of al Quran today seems to be affected by various sources leading to polemics. According to scholars in Nusantara, it can be understood that there is a connection with the network of scholars based in the Middle East making the thoughts unseparated from the cleric network. Therefore, to uncover a network of sciences and chain of transmission lines (sanad in Qur'anic studies is very important, particualrly in understanding the intersection between Huffaz clerics and tarekats in the dissemination of teaching the Qur'an.The study highlights that there is continuity and correlation between Huffaz and tarekat scholars network in Nusantara. However, at this time, the development of interpretation studies in Nusantara seems to be increasingly departed and separated by the guards of Qur’an, tarekat and the Islam community.

  3. Studies of Limits on Uncontrolled Heavy Ion Beam Losses for Allowing Hands-On Maintenance

    Energy Technology Data Exchange (ETDEWEB)

    Reginald M. Ronningen; Igor Remec

    2010-09-11

    Dose rates from accelerator components activated by 1 W/m beam losses are obtained semiempirically for a 1 GeV proton beam and by use of Monte Carlo transport codes for the proton beam and for 777 MeV/u 3He, 500 MeV/u 48Ca, 86Kr, 136Xe, and 400 MeV/u 238U ions. The dose rate obtained by the semi-empirical method, 0.99 mSv/h (99 mrem/h) at 30 cm, 4 h after 100 d irradiation by a 1-GeV proton beam, is consistent with studies at several accelerator facilities and with adopted hands-on maintenance dose rate limits. Monte Carlo simulations verify this result for protons and extend studies to heavy ion beam losses in drift-tube linac and superconducting linac accelerating structures. The studies indicate that the 1 W/m limit imposed on uncontrolled beam losses for high-energy proton beams might be relaxed for heavy ion beams. These studies further suggest that using the ratio of neutrons produced by a heavy ion beam to neutrons produced by a proton beam along with the dose rate from the proton beam (for thin-target scenarios) should allow an estimate of the dose rates expected from heavy ion beam losses.

  4. Lithium ion adsorption and diffusion on black phosphorene nanotube: A first-principles study

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Jin; Shi, Jing, E-mail: sjd865@jxnu.edu.cn; Hu, Yinquan; Wu, Musheng; Ouyang, Chuying; Xu, Bo

    2017-01-15

    Highlights: • Li ion storage performance of the single-walled black phosphorene nanotube was studied. • Li ion adsorption and diffusion on inside/outside wall of SWPNT was studied. • In-PNT system has higher adsorption energy and lower diffusion energy barrier. • 1-D tubular phosphorene improve Li storage performances as an anode material of LIBs. - Abstract: Li ion storage performance of the single-walled black phosphorene nanotube (PNT), which is considered as potential anode materials for high-performance Li-ion batteries (LIBs), is studied from first-principles calculations. The Li ion adsorption, diffusion and structural evolution of the one-dimensional armchair type PNT (aPNT) upon Li intercalation on the inside (in-PNT) and outside (out-PNT) surfaces were explored, comparing with that of the two-dimensional phosphorene (Psheet). A maximum Li storage capacity (at the intercalated state of Li{sub 22}P{sub 44}) is evaluated to be 432 mAh/g. It is also shown that the in-PNT system has higher adsorption energy and lower Li diffusion energy barrier compared with that of the Psheet and the out-PNT systems. The reason on why the better Li storage performance of the in-PNT is also studied from charge distribution and transfer analysis. These results suggest that PNT can be served as potential anode material for LIBs.

  5. Radiation defect dynamics in Si at room temperature studied by pulsed ion beams

    Energy Technology Data Exchange (ETDEWEB)

    Wallace, J. B.; Charnvanichborikarn, S.; Bayu Aji, L. B.; Myers, M. T.; Shao, L.; Kucheyev, S. O.

    2015-10-07

    The evolution of radiation defects after the thermalization of collision cascades often plays the dominant role in the formation of stable radiation disorder in crystalline solids of interest to electronics and nuclear materials applications. Here, we explore a pulsed-ion-beam method to study defect interaction dynamics in Si crystals bombarded at room temperature with 500 keV Ne, Ar, Kr, and Xe ions. The effective time constant of defect interaction is measured directly by studying the dependence of lattice disorder, monitored by ion channeling, on the passive part of the beam duty cycle. The effective defect diffusion length is revealed by the dependence of damage on the active part of the beam duty cycle. Results show that the defect relaxation behavior obeys a second order kinetic process for all the cases studied, with a time constant in the range of ~4–13 ms and a diffusion length of ~15–50 nm. Both radiation dynamics parameters (the time constant and diffusion length) are essentially independent of the maximum instantaneous dose rate, total ion dose, and dopant concentration within the ranges studied. However, both the time constant and diffusion length increase with increasing ion mass. This demonstrates that the density of collision cascades influences not only defect production and annealing efficiencies but also the defect interaction dynamics.

  6. Studying Heavy Ion Collisions Using Methods From Cosmic Microwave Background (CMB Analysis

    Directory of Open Access Journals (Sweden)

    Gaardhøje J. J.

    2014-04-01

    Full Text Available We present and discuss a framework for studying the morphology of high-multiplicity events from relativistic heavy ion collisions using methods commonly employed in the analysis of the photons from the Cosmic Microwave Background (CMB. The analysis is based on the decomposition of the distribution of the number density of (charged particles expressed in polar and azimuthal coordinates into a sum of spherical harmonic functions. We present an application of the method exploting relevant symmetries to the study of azimuthal correlations arizing from collective flow among charged particles produced in relativistic heavy ion collisions. We discuss perspectives for event-by- event analyses, which with increasing collision energy will eventually open entirely new dimensions in the study of ultrarelaticistic heavy ion reactions.

  7. Adsorption studies of cadmium ions on alginate-calcium carbonate composite beads

    Science.gov (United States)

    Mahmood, Zahid; Amin, Athar; Zafar, Uzma; Raza, Muhammad Amir; Hafeez, Irfan; Akram, Adnan

    2017-05-01

    Alginate-calcium carbonate composite material was prepared in the form of beads and characterized using Fourier transform infra red (FT-IR) spectroscopy and scanning electron microscope (SEM) techniques. The adsorption of Cd2+ ions was studied through batch experiments. The adsorption parameters such as contact time (120 min), adsorbent dose (1.5 g), initial metal ion concentration(10 mg/L), pH (6) and agitation speed (150 rpm) were optimized at room temperature. Langmuir and Freundlich isotherms were applied to the data and it was noted that the adsorption of Cd2+ ions is better explained by Freundlich model. The kinetic studies showed that the adsorption of Cd2+ ions followed pseudo-first order kinetics. Thermodynamic parameters like ∆ G 0, ∆ H 0 and ∆ S 0 were calculated and on the basis of these values it was established that the adsorption process is feasible and endothermic in nature. It was concluded from the study that the composite material of alginate and calcium carbonate can effectively be used to recover Cd2+ ions from wastewater.

  8. Quantitative studies of subdiffusion in living cells and actin networks

    DEFF Research Database (Denmark)

    Munteanu, Emilia-Laura; Olsen, Anja Lea; Tolic-Nørrelykke, Iva Marija

    2006-01-01

    of optical tweezers data, primarily baed on the power spectra of time series of postions for trapped spherical objects. The majority of precise studies in the literature are performed on in vitro systems, whereas in the present work, an example of an in vivo system is presented for which precise power...... spectral analysis is both useful and necessary. The biological system is the cytoplasm of fission yeast, S. pombe, in which we observe subdiffusion of lipid granuli. in a search for the cause of subdiffusion, we chemically disrupt the actin network in the cytoplasm and further consider in vitro networks...

  9. Ion aggregation in high salt solutions. VI. Spectral graph analysis of chaotropic ion aggregates

    Science.gov (United States)

    Choi, Jun-Ho; Cho, Minhaeng

    2016-11-01

    Carrying out molecular dynamics simulations and graph theoretical analyses of high salt solutions, and comparing numerically calculated vibrational spectroscopic properties of water with femtosecond IR pump-probe experimental data, we have recently found that ions in high salt solutions can form two morphologically different ion aggregate structures. In the cases of NaCl solutions, Na+ and Cl- tend to form compact cluster-like ion aggregate in high NaCl solutions. In contrast, K+ and SCN- form spatially extended network-like ion aggregates that also exhibit a percolating network behavior. Interestingly, a variety of graph theoretical properties of ion network in high KSCN solutions were found to be very similar to those of water H-bonding network. It was shown that spatially extended ion networks in high KSCN solutions are completely intertwined with water H-bonding networks, which might be the key to understand the high solubility of thiocyanate salts in water. Here, we further consider two salts that have been extensively studied experimentally by using femtosecond IR pump-probe technique, which are NaClO4 and NaBF4. Note that ClO4 - and BF4 - are well-known chaotropic ions that have been believed to behave as water structure breaker. To understand how such chaotropic ions affect water H-bonding structure, we carried out spectral graph analyses of molecular dynamics simulation data of these aqueous solutions. Graph spectra and degree distribution of ion aggregates formed in high NaBF4 and NaClO4 solutions show that these chaotropic anions also have a strong propensity to form ion networks. The fact that salts containing chaotropic ions like SCN-, BF4 - , and ClO4 - have very high solubility limits in water could then be related to our observation that these chaotropic anions with counter cations in high salt solutions are capable of forming intricate ion networks intertwined with water H-bonding networks. We anticipate that the present graph theoretical analysis

  10. Holistic Thinking Aproach: Case Study of Post Network in Slovenia

    Directory of Open Access Journals (Sweden)

    Andrej Lisec

    2008-03-01

    Full Text Available Modern complexity of management is associated with importantdecision making, confronting a great number of uselessinformation. Selection of information- the choice of only qualityones, i. e. essential ones, is a big problem in management decision-making. Implementation of systemic approach i. e. dialectical-network thinking (DNT can help to deal with it. Thepaper presents a holistic thinking approach in a case study forthe Slovenian parcel postal problem. The volume of parcelflows at the Post of Slovenia between Posts is increasing rapidlyand it requires a new design of the postal network. This paperpresents a reorganization of parcel services between Postal LogisticsCenters and Posts by adding Regional Parcel Centersand Parcel Posts to the network. A case for the area covered byLjubljana Postal Logistics Center is given, which takes intoconsideration the sorting out and the retaining of parcels in thePosts, Parcel Posts and Regional Parcel Centers within their individualareas.

  11. Communication: Nanoscale ion fluctuations in Nafion polymer electrolyte

    Energy Technology Data Exchange (ETDEWEB)

    Rumberger, Brant; Bennett, Mackenzie; Zhang, Jingyun; Israeloff, N. E. [Department of Physics, Northeastern University, Boston, Massachusetts 02115 (United States); Dura, J. A. [National Institute of Standards and Technology, Center for Neutron Research, Gaithersburg, Maryland 20899 (United States)

    2014-08-21

    Ion conduction mechanisms and the nanostructure of ion conduction networks remain poorly understood in polymer electrolytes which are used as proton-exchange-membranes (PEM) in fuel cell applications. Here we study nanoscale surface-potential fluctuations produced by Brownian ion dynamics in thin films of low-hydration Nafion™, the prototype PEM. Images and power spectra of the fluctuations are used to derive the local conductivity-relaxation spectrum, in order to compare with bulk behavior and hopping-conductivity models. Conductivity relaxation-times ranged from hours to milliseconds, depending on hydration and temperature, demonstrating that the observed fluctuations are produced by water-facilitated hydrogen-ion hopping within the ion-channel network. Due to the small number of ions probed, non-Gaussian statistics of the fluctuations can be used to constrain ion conduction parameters and mechanisms.

  12. Communication: nanoscale ion fluctuations in Nafion polymer electrolyte.

    Science.gov (United States)

    Rumberger, Brant; Bennett, Mackenzie; Zhang, Jingyun; Dura, J A; Israeloff, N E

    2014-08-21

    Ion conduction mechanisms and the nanostructure of ion conduction networks remain poorly understood in polymer electrolytes which are used as proton-exchange-membranes (PEM) in fuel cell applications. Here we study nanoscale surface-potential fluctuations produced by Brownian ion dynamics in thin films of low-hydration Nafion™, the prototype PEM. Images and power spectra of the fluctuations are used to derive the local conductivity-relaxation spectrum, in order to compare with bulk behavior and hopping-conductivity models. Conductivity relaxation-times ranged from hours to milliseconds, depending on hydration and temperature, demonstrating that the observed fluctuations are produced by water-facilitated hydrogen-ion hopping within the ion-channel network. Due to the small number of ions probed, non-Gaussian statistics of the fluctuations can be used to constrain ion conduction parameters and mechanisms.

  13. Collective Study On Security Threats In VOIP Networks

    Directory of Open Access Journals (Sweden)

    Muhammad Zulkifl Hasan

    2017-01-01

    Full Text Available The Collective study will critically evaluate the voice over internet protocol VOIP Security threats issues amp challenges in the communication over the network the solution provided by different vendors. Authors will be discussing all security issues different protocols but main focus will be on SIP protocol its implementation and vendors VOIP security system.

  14. International Students' Networks: A Case Study in a UK University

    Science.gov (United States)

    Taha, Nashrawan; Cox, Andrew

    2016-01-01

    The great influx of international students into UK universities has led to internationalisation becoming an important issue. Previous studies have focused on the integration of home and international students, illustrating a lack of intercultural interaction. Yet there has been a lack of research investigating international students' networks and…

  15. Social Networks and Health: A Systematic Review of Sociocentric Network Studies in Low- and Middle-Income Countries

    Science.gov (United States)

    Perkins, Jessica M; Subramanian, S V; Christakis, Nicholas A

    2015-01-01

    In low- and middle-income countries (LMICs), naturally occurring social networks may be particularly vital to health outcomes as extended webs of social ties often are the principal source of various resources. Understanding how social network structure, and influential individuals within the network, may amplify the effects of interventions in LMICs, by creating, for example, cascade effects to non-targeted participants, presents an opportunity to improve the efficiency and effectiveness of public health interventions in such settings. We conducted a systematic review of PubMed, Econlit, Sociological Abstracts, and PsycINFO to identify a sample of 17 sociocentric network papers (arising from 10 studies) that specifically examined health issues in LMICs. We also separately selected to review 19 sociocentric network papers (arising from 10 other studies) on development topics related to wellbeing in LMICs. First, to provide a methodological resource, we discuss the sociocentric network study designs employed in the selected papers, and then provide a catalog of 105 name generator questions used to measure social ties across all the LMIC network papers (including both ego- and sociocentric network papers) cited in this review. Second, we show that network composition, individual network centrality, and network structure are associated with important health behaviors and health and development outcomes in different contexts across multiple levels of analysis and across distinct network types. Lastly, we highlight the opportunities for health researchers and practitioners in LMICs to 1) design effective studies and interventions in LMICs that account for the sociocentric network positions of certain individuals and overall network structure, 2) measure the spread of outcomes or intervention externalities, and 3) enhance the effectiveness and efficiency of aid based on knowledge of social structure. In summary, human health and wellbeing are connected through complex

  16. Social networks and health: a systematic review of sociocentric network studies in low- and middle-income countries.

    Science.gov (United States)

    Perkins, Jessica M; Subramanian, S V; Christakis, Nicholas A

    2015-01-01

    In low- and middle-income countries (LMICs), naturally occurring social networks may be particularly vital to health outcomes as extended webs of social ties often are the principal source of various resources. Understanding how social network structure, and influential individuals within the network, may amplify the effects of interventions in LMICs, by creating, for example, cascade effects to non-targeted participants, presents an opportunity to improve the efficiency and effectiveness of public health interventions in such settings. We conducted a systematic review of PubMed, Econlit, Sociological Abstracts, and PsycINFO to identify a sample of 17 sociocentric network papers (arising from 10 studies) that specifically examined health issues in LMICs. We also separately selected to review 19 sociocentric network papers (arising from 10 other studies) on development topics related to wellbeing in LMICs. First, to provide a methodological resource, we discuss the sociocentric network study designs employed in the selected papers, and then provide a catalog of 105 name generator questions used to measure social ties across all the LMIC network papers (including both ego- and sociocentric network papers) cited in this review. Second, we show that network composition, individual network centrality, and network structure are associated with important health behaviors and health and development outcomes in different contexts across multiple levels of analysis and across distinct network types. Lastly, we highlight the opportunities for health researchers and practitioners in LMICs to 1) design effective studies and interventions in LMICs that account for the sociocentric network positions of certain individuals and overall network structure, 2) measure the spread of outcomes or intervention externalities, and 3) enhance the effectiveness and efficiency of aid based on knowledge of social structure. In summary, human health and wellbeing are connected through complex

  17. Study of the degradation process of polyimide induced by high energetic ion irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Severin, Daniel

    2008-09-19

    The dissertation focuses on the radiation hardness of Kapton under extreme radiation environment conditions. To study ion-beam induced modifications, Kapton foils were irradiated at the GSI linear accelerator UNILAC using several projectiles (e.g. Ti, Mo, Au, and U) within a large fluence regime (1 x 10{sup 10}-5 x 10{sup 12} ions/cm{sup 2}). The irradiated Kapton foils were analysed by means of infrared and UV/Vis spectroscopy, tensile strength measurement, mass loss analysis, and dielectric relaxation spectroscopy. For testing the radiation stability of Kapton at the cryogenic operation temperature (5-10 K) of the superconducting magnets, additional irradiation experiments were performed at the Grand Accelerateur National d' Ions Lourds (GANIL, France) focusing on the online analysis of the outgassing process of small volatile degradation fragments. The investigations of the electrical properties analysed by dielectric relaxation spectroscopy exhibit a different trend: high fluence irradiations with light ions (e.g. Ti) lead to a slight increase of the conductivity, whereas heavy ions (e.g. Sm, Au) cause a drastic change already in the fluence regime of nonoverlapping tracks (5 x 10{sup 10} ions/cm{sup 2}). Online analysis of the outgassing process during irradiation at cryogenic temperatures shows the release of a variety of small gaseous molecules (e.g. CO, CO{sub 2}, and short hydro carbons). Also a small amount of large polymer fragments is identified. The results allow the following conclusions which are of special interest for the application of Kapton as insulating material in a high-energetic particle radiation environment. a) The material degradation measured with the optical spectroscopy and tensile strength tests are scalable with the dose deposited by the ions. The high correlation of the results allows the prediction of the mechanical degradation with the simple and non-destructive infrared spectroscopy. The degradation curve points to a

  18. 3D network single-phase Ni0.9Zn0.1O as anode materials for lithium-ion batteries

    DEFF Research Database (Denmark)

    Huang, Guoyong; Guo, Xueyi; Cao, Xiao

    2016-01-01

    two-step Li-ion storage mechanism in the 3D network single−phase Ni0.9Zn0.1O has been discovered and verified to be: a reversible conversion reaction between Ni0.9Zn0.1O and Ni-Zn alloy (Ni0.9Zn0.1), and a reversible Li-alloying reaction between Ni-Zn alloy and Ni0.9Zn0.1Li. More remarkably, due...

  19. Femtosecond photodissociation dynamics of I studied by ion imaging

    DEFF Research Database (Denmark)

    Larsen, J.J.; Bjerre, N.; Mørkbak, N.J.

    1998-01-01

    on imaging is employed to analyze the fragments from timed Coulomb explosion studies of femtosecond (fs) molecular dynamics. The technique provides high detection efficiency and direct recording of the two-dimensional velocity of all ionized fragments. We illustrate the approach by studying...

  20. Software for Brain Network Simulations: A Comparative Study

    Science.gov (United States)

    Tikidji-Hamburyan, Ruben A.; Narayana, Vikram; Bozkus, Zeki; El-Ghazawi, Tarek A.

    2017-01-01

    Numerical simulations of brain networks are a critical part of our efforts in understanding brain functions under pathological and normal conditions. For several decades, the community has developed many software packages and simulators to accelerate research in computational neuroscience. In this article, we select the three most popular simulators, as determined by the number of models in the ModelDB database, such as NEURON, GENESIS, and BRIAN, and perform an independent evaluation of these simulators. In addition, we study NEST, one of the lead simulators of the Human Brain Project. First, we study them based on one of the most important characteristics, the range of supported models. Our investigation reveals that brain network simulators may be biased toward supporting a specific set of models. However, all simulators tend to expand the supported range of models by providing a universal environment for the computational study of individual neurons and brain networks. Next, our investigations on the characteristics of computational architecture and efficiency indicate that all simulators compile the most computationally intensive procedures into binary code, with the aim of maximizing their computational performance. However, not all simulators provide the simplest method for module development and/or guarantee efficient binary code. Third, a study of their amenability for high-performance computing reveals that NEST can almost transparently map an existing model on a cluster or multicore computer, while NEURON requires code modification if the model developed for a single computer has to be mapped on a computational cluster. Interestingly, parallelization is the weakest characteristic of BRIAN, which provides no support for cluster computations and limited support for multicore computers. Fourth, we identify the level of user support and frequency of usage for all simulators. Finally, we carry out an evaluation using two case studies: a large network with

  1. Methyl tert-butyl ether (MTBE) degradation by ferrous ion-activated persulfate oxidation: feasibility and kinetics studies.

    Science.gov (United States)

    Chen, K F; Kao, C M; Wu, L C; Surampalli, R Y; Liang, S H

    2009-07-01

    The objective of this study was to evaluate the feasibility of using ferrous ion-activated persulfate oxidation to remediate groundwater contaminated with methyl tert-butyl ether (MTBE). In this study, batch experiments were conducted to evaluate the effects of various factors on the efficiency of MTBE degradation including persulfate concentrations, ferrous ion concentrations, and persulfate coupled with hydrogen peroxide. Results show that ferrous ion-activated persulfate oxidation was capable of degrading MTBE efficiently. Persulfate and ferrous ion concentrations correlated with MTBE degradation rates. However, excess addition of ferrous ion resulted in decreased MTBE degrading rates most likely because of competition for sulfate free radicals between ferrous ion and MTBE. Two main byproducts of MTBE degradation, tert-butyl formate and tert-butyl alcohol, were detected in the experiments; both were, however, subsequently degraded. Results of sulfate analysis show that proper addition of ferrous ion could prevent unnecessary persulfate decomposition.

  2. APPLICATION OF PRINCIPAL COMPONENTS ANALYSIS IN THE STUDY OF ADSORPTIVE VOLTAMMETRY OF METALICS IONS

    Directory of Open Access Journals (Sweden)

    Leandra de Oliveira Cruz da Silva

    2010-01-01

    Full Text Available The adsorptive stripping voltammetry with differential pulse cathodic through the use of a mixture of complexing agents dimethylglyoxime and oxine was used for an exploratory study simultaneously of ions cadmium, cobalt, copper, nickel, lead and zinc. Were obtained voltammograms of the 64 individual solutions used in planning and current data were submitted to principal component analysis (PCA, allowing to characterize the trends of the solutions of metal ions studied. The system can be described in eight principal components that explained 98.32% of variance. Since the first three principal components accumulated approximately 85.46% of the total variance.

  3. Transport and emittance study for 18 GHz superconducting-ECR ion source at RCNP.

    Science.gov (United States)

    Yorita, T; Hatanaka, K; Fukuda, M; Ueda, H; Kibayashi, M; Morinobu, S; Tamii, A

    2012-02-01

    As the upgrade program of the azimuthally varying field (AVF) cyclotron is at the cyclotron facility of the RCNP, Osaka University for the improvement of the quality, stability, and intensity of accelerated beams, an 18 GHz superconducting (SC) ECR ion source has been installed to increase beam currents and to extend the variety of ions, especially for highly charged heavy ions which can be accelerated by RCNP AVF cyclotron. The production development of several ions such as B, O, N, Ne, Ar, Ni, Kr, and Xe has been performed by Yorita et al. [Rev. Sci. Instrum. 79, 02A311(2008); 81, 02A332 (2010)]. Further studies for the beam transport have been done in order to improve the beam current more for injection of cyclotron. The effect of field leakage of AVF main coil is not negligible and additional steering magnet has been installed and then beam transmission has been improved. The emittance monitor has also been developed for the purpose of investigating correlation between emittance of beam from ECR ion sources and injection efficiency. The monitor consists with BPM82 with rotating wire for fast measurement for efficient study.

  4. and Cr(VI) ions by chitosan: kinetics and equilibrium studies

    African Journals Online (AJOL)

    The ability of chitosan as an adsorbent for Cu (II) and Cr (VI) ions in aqueous solution was studied. The experiments were done as batch processes. Equilibrium studies were done on both cross-linked and non-cross-linked chitosan for both metals. Cr (VI) adsorption behaviour could be described using the Langmuir ...

  5. Study of back streaming ion using a slot-type grounded grid in hydrogen negative-ion source

    Science.gov (United States)

    Ikeda, K.; Kisaki, M.; Nakano, H.; Nagaoka, K.; Osakabe, M.; Kamio, S.; Tsumori, K.; Geng, S.; Takeiri, Y.

    2017-08-01

    The properties of cesium (Cs) recycling due to back-streaming ions have been investigated using an optical emission spec-troscopy in the hydrogen negative ion (H-) source with a slot-type grounded grid (GG). The slot-type GG performed well to enhance the beam performance, and to reduce the thermal loading on GG by high transparency. We clearly observed increase of Cs optical emission intensity during beam extraction owing to the increase of the Cs ions sputtered from the back plate of the source due to the back-streaming positive hydrogen ions. Increase of Cs is closely related with the extracted H- current, but it does not depend on the beam energy. Recycling Cs from the back plate is deeply relevant to the perveance condition of the H- beam, and is minimized at the optimum perveance. Strong Cs recycling from the back plate owing to the back-streaming ions is promoted in the high perveance condition with large divergence, which is consistent with the numerical calculation for the distribution of back streaming ions. This high Cs recycling condition, however, is not suitable for safety beam operation with high energy beam. The output of beam power is saturated by the space charge limitation, and divergent beam is trapped in the grounded grid (GG), which may cause damage on the slot-type GG surface by high thermal loading as large as in the aperture-type GG.

  6. A study on the design of hexapole in an 18-GHz ECR ion source for heavy ion accelerators

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Zhan; Wei, Shaoqing; Lee, Sang Jin [Uiduk University, Gyeongju (Korea, Republic of); Choi, Suk Jin [Rare Isotope Science Project, Institute for Basic Science, Daejeon (Korea, Republic of)

    2016-06-15

    High charge state electron cyclotron resonance (ECR) ion source is important on the performance of heavy ion accelerators. In this paper, a low temperature superconductor (LTS) was used to make a hexapole coil for an 18-GHz ECR ion source. Several hexapole structures, including racetrack, graded racetrack, and saddle were implemented and analyzed for the hexapole-in-solenoid ECR ion source system. Under the appropriate radial confinement field, the smaller outer radius of hexapole can be better for the solenoid design. Saddle hexapole was selected by comparing the wire length, maximum outer radius of the hexapole, the Lorentz force at the end part of the hexapole and the maximum magnetic field in the coil. Based on saddle hexapole, a new design for hexapoles, the snake hexapole, was developed in this paper. By comparative analysis of the Lorentz force at the end part of the saddle and snake hexapoles, the snake hexapole is much better in the ECR ion source system. The suggested design for the ECR ion source with the snake hexapole is presented in this paper.

  7. Ion distributions at charged aqueous surfaces: Synchrotron X-ray scattering studies

    Energy Technology Data Exchange (ETDEWEB)

    Bu, Wei [Iowa State Univ., Ames, IA (United States)

    2009-01-01

    Surface sensitive synchrotron X-ray scattering studies were performed to obtain the distribution of monovalent ions next to a highly charged interface at room temperature. To control surface charge density, lipids, dihexadecyl hydrogen-phosphate (DHDP) and dimysteroyl phosphatidic acid (DMPA), were spread as monolayer materials at the air/water interface, containing CsI at various concentrations. Five decades in bulk concentrations (CsI) are investigated, demonstrating that the interfacial distribution is strongly dependent on bulk concentration. We show that this is due to the strong binding constant of hydronium H3O+ to the phosphate group, leading to proton-transfer back to the phosphate group and to a reduced surface charge. Using anomalous reflectivity off and at the L3 Cs+ resonance, we provide spatial counterion (Cs+) distributions next to the negatively charged interfaces. The experimental ion distributions are in excellent agreement with a renormalized surface charge Poisson-Boltzmann theory for monovalent ions without fitting parameters or additional assumptions. Energy Scans at four fixed momentum transfers under specular reflectivity conditions near the Cs+ L3 resonance were conducted on 10-3 M CsI with DHDP monolayer materials on the surface. The energy scans exhibit a periodic dependence on photon momentum transfer. The ion distributions obtained from the analysis are in excellent agreement with those obtained from anomalous reflectivity measurements, providing further confirmation to the validity of the renormalized surface charge Poisson-Boltzmann theory for monovalent ions. Moreover, the dispersion corrections f0 and f00 for Cs+ around L3 resonance, revealing the local environment of a Cs+ ion in the solution at the interface, were extracted simultaneously with output of ion distributions.

  8. A coupled thermal and electrochemical study of lithium-ion battery cooled by paraffin/porous-graphite-matrix composite

    Science.gov (United States)

    Greco, Angelo; Jiang, Xi

    2016-05-01

    Lithium-ion (Li-ion) battery cooling using a phase change material (PCM)/compressed expanded natural graphite (CENG) composite is investigated, for a cylindrical battery cell and for a battery module scale. An electrochemistry model (average model) is coupled to the thermal model, with the addition of a one-dimensional model for the solution and solid diffusion using the nodal network method. The analysis of the temperature distribution of the battery module scale has shown that a two-dimensional model is sufficient to describe the transient temperature rise. In consequence, a two-dimensional cell-centred finite volume code for unstructured meshes is developed with additions of the electrochemistry and phase change. This two-dimensional thermal model is used to investigate a new and usual battery module configurations cooled by PCM/CENG at different discharge rates. The comparison of both configurations with a constant source term and heat generation based on the electrochemistry model showed the superiority of the new design. In this study, comparisons between the predictions from different analytical and computational tools as well as open-source packages were carried out, and close agreements have been observed.

  9. The role of glutamate in neuronal ion homeostasis: A case study of spreading depolarization.

    Directory of Open Access Journals (Sweden)

    Niklas Hübel

    2017-10-01

    Full Text Available Simultaneous changes in ion concentrations, glutamate, and cell volume together with exchange of matter between cell network and vasculature are ubiquitous in numerous brain pathologies. A complete understanding of pathological conditions as well as normal brain function, therefore, hinges on elucidating the molecular and cellular pathways involved in these mostly interdependent variations. In this paper, we develop the first computational framework that combines the Hodgkin-Huxley type spiking dynamics, dynamic ion concentrations and glutamate homeostasis, neuronal and astroglial volume changes, and ion exchange with vasculature into a comprehensive model to elucidate the role of glutamate uptake in the dynamics of spreading depolarization (SD-the electrophysiological event underlying numerous pathologies including migraine, ischemic stroke, aneurysmal subarachnoid hemorrhage, intracerebral hematoma, and trauma. We are particularly interested in investigating the role of glutamate in the duration and termination of SD caused by K+ perfusion and oxygen-glucose deprivation. Our results demonstrate that glutamate signaling plays a key role in the dynamics of SD, and that impaired glutamate uptake leads to recovery failure of neurons from SD. We confirm predictions from our model experimentally by showing that inhibiting astrocytic glutamate uptake using TFB-TBOA nearly quadruples the duration of SD in layers 2-3 of visual cortical slices from juvenile rats. The model equations are either derived purely from first physical principles of electroneutrality, osmosis, and conservation of particles or a combination of these principles and known physiological facts. Accordingly, we claim that our approach can be used as a future guide to investigate the role of glutamate, ion concentrations, and dynamics cell volume in other brain pathologies and normal brain function.

  10. Study of clusters using negative ion photodetachment spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Yuexing [Univ. of California, Berkeley, CA (United States)

    1995-12-01

    The weak van der Waals interaction between an open-shell halogen atom and a closed-shell atom or molecule has been investigated using zero electron kinetic energy (ZEKE) spectroscopy. This technique is also applied to study the low-lying electronic states in GaAs and GaAs-. In addition, the spectroscopy and electron detachment dynamics of several small carbon cluster anions are studied using resonant multiphoton detachment spectroscopy.

  11. A novel Schiff base: Synthesis, structural characterisation and comparative sensor studies for metal ion detections.

    Science.gov (United States)

    Köse, Muhammet; Purtas, Savas; Güngör, Seyit Ali; Ceyhan, Gökhan; Akgün, Eyup; McKee, Vickie

    2015-02-05

    A novel Schiff base ligand was synthesized by the condensation reaction of 2,6-diformylpyridine and 4-aminoantipyrine in MeOH and characterised by its melting point, elemental analysis, FT-IR, (1)H, (13)C NMR and mass spectroscopic studies. Molecular structure of the ligand was determined by single crystal X-ray diffraction technique. The electrochemical properties of the Schiff base ligand were studied in different solvents at various scan rates. Sensor ability of the Schiff base ligand was investigated by colorimetric and fluorometric methods. Visual colour change of the ligand was investigated in MeOH solvent in presence of various metal ions Na(+), Mg(2+), Al(3+), K(+), Cr(3+), Mn(2+), Fe(3+), Co(2+), Ni(2+), Cu(2+), Zn(2+), Cd(2+), Hg(2+) and Pb(2+). Upon addition of Al(3+) ion into a MeOH solution of the ligand, an orange colour developed which is detectable by naked eye. Fluorescence emission studies showed that the ligand showed single emission band at 630-665nm upon excitation at 560nm. Addition of metal ions Na(+), Mg(2+), K(+), Cr(3+), Mn(2+), Fe(3+), Co(2+), Ni(2+), Cu(2+), Zn(2+), Cd(2+), Hg(2+) and Pb(2+) (1:1M ratio) cause fluorescence quenching, however addition of Al(+3) resulted in an increase in fluorescence intensity. No significant variation was observed in the fluorescence intensity caused by Al(3+) in presence of other metal ions. Therefore, the Schiff base ligand can be used for selective detection of Al(3+) ions in the presence of the other metal ions studied. Copyright © 2014 Elsevier B.V. All rights reserved.

  12. Simultaneous Counter-Ion Co-Deposition a Technique Enabling Matrix Isolation Spectroscopy Studies Using Low-Energy Beams of Mass-Selected Ions

    Science.gov (United States)

    Ludwig, Ryan M.; Moore, David T.

    2014-06-01

    Matrix isolation spectroscopy was first developed in Pimentel's group during the 1950's to facilitate spectroscopic studies of transient species. Cryogenic matrices of condensed rare gases provide an inert chemical environment with facile energy dissipation and are transparent at all wavelengths longer than vacuum UV, making them ideal for studying labile and reactive species such as radicals, weakly bound complexes, and ions. Since frozen rare gases are poor electrolytes, studies of ions require near-equal populations of anions and cations in order to stabilize the number densities required for spectroscopic experiments. Many techniques for generation of ions for using in matrix isolation studies satisfy this criterion intrinsically, however when ion beams generated in external sources are deposited, the counter-ions typically arise via secondary processes that are at best loosely controlled. It has long been recognized that it would be desirable to stabilize deposition of mass-selected ions generated in an external source using simultaneous co-deposition of a beam of counter-ions, however previous attempts to achieve this have been reported as unsuccessful. The Moore group at Lehigh has demonstrated successful experiments of this type, using mass-selected anions generated from a metal cluster source, co-deposited with a balanced current of cations generated in a separate electron ionization source. This talk will focus on the details of the technique, and present some results from proof-of-concept studies on anionic copper carbonyl complexes formed in argon matrices following co-deposition of Cu- with Ar+ or Kr+. Funding support from NSF CAREER Award CHE-0955637 is gratefully acknowledged. Whittle et al., J. Chem. Phys. 22, p.1943 (1954); Becker et al., J. Chem. Phys. 25, p.224 (1956). Godbout et al., J. Chem. Phys. 96, p.2892 (1996). Sabo et al., Appl. Spectrosc. 45, p. 535 (1991).

  13. A fundamental study on materials for Li-ion batteries

    NARCIS (Netherlands)

    Verhoeven, V.W.J.

    2001-01-01

    In April 1997 the program "Decentralized Production and Storage for Large-Scale Application of Renewable Energy" of the Delft Interfaculty Research Centre (DIOC) was launched. In this program various groups from several Faculties of the Delft University of Technology studied the feasibility of large

  14. Study of the Influence Between Barium Ions and Calcium Ions on Morphology and Size of Coprecipitation in Microemulsion

    Science.gov (United States)

    Wang, Nong; Meng, Qing Luo

    2015-03-01

    In this paper, we systematically drew a series of inverse-microemulsion quasi-ternary system phase diagrams of OP-10+C8H17OH+C6H12+brine (CaCl2/BaCl2) by adjusting the ratio of CaCl2 and BaCl2. On this basis, microemulsions have been prepared with seven different molar ratios of Ca2+/Ba2+, and calcium carbonate and barium carbonate coprecipitation products were obtained by reaction with an equimolar amount of sodium carbonate. The influence of barium ion to morphology and composition of nanometer calcium carbonate were studied. These samples were characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The SEM photographs indicated that when the content of Ca2+ was higher, some incomplete large cube of coprecipitation particles were formed in solution, but with the content of Ba2+ increased gradually, they formed a large number of small spherical particles, with the further increase of Ba2+ concentration, the particles mainly had structures of irregular polyhedron eventually. The measurement results of FTIR and XRD indicated that CaCO3 coprecipitation products gradually changed from calcite to the vaterite, eventually turned into being aragonite with the further increase of Ba2+ concentration.

  15. In Situ Study of Strain-Dependent Ion Conductivity of Stretchable Polyethylene Oxide Electrolyte

    Science.gov (United States)

    Kelly, Taylor; Ghadi, Bahar Moradi; Berg, Sean; Ardebili, Haleh

    2016-02-01

    There is a strong need in developing stretchable batteries that can accommodate stretchable or irregularly shaped applications including medical implants, wearable devices and stretchable electronics. Stretchable solid polymer electrolytes are ideal candidates for creating fully stretchable lithium ion batteries mainly due to their mechanical and electrochemical stability, thin-film manufacturability and enhanced safety. However, the characteristics of ion conductivity of polymer electrolytes during tensile deformation are not well understood. Here, we investigate the effects of tensile strain on the ion conductivity of thin-film polyethylene oxide (PEO) through an in situ study. The results of this investigation demonstrate that both in-plane and through-plane ion conductivities of PEO undergo steady and linear growths with respect to the tensile strain. The coefficients of strain-dependent ion conductivity enhancement (CSDICE) for in-plane and through-plane conduction were found to be 28.5 and 27.2, respectively. Tensile stress-strain curves and polarization light microscopy (PLM) of the polymer electrolyte film reveal critical insights on the microstructural transformation of stretched PEO and the potential consequences on ionic conductivity.

  16. [Preliminary study of atomic emission spectrometry of Ti (H) plasma produced by vacuum arc ion source].

    Science.gov (United States)

    Deng, Chun-Feng; Wu, Chun-Lei; Wang, Yi-Fu; Lu, Biao; Wen, Zhong-Wei

    2014-03-01

    In order to study the discharge process of vacuum arc ion source, make a detail description of the discharge plasma, and lay the foundation for further research on ion source, atomic emission spectrometry was used to diagnose the parameters of plasma produced by vaccum arc ion source. In the present paper, two kinds of analysis method for the emission spectra data collected by a spectrometer were developed. Those were based in the stark broadening of spectral lines and Saba-Boltzmann equation. Using those two methods, the electron temperature, electron number density and the ion temperature of the plasma can be determined. The emission spectroscopy data used in this paper was collected from the plasma produced by a vacuum are ion source whose cathode was made by Ti material (which adsorbed hydrogen during storage procedure). Both of the two methods were used to diagnose the plasma parameters and judge the thermal motion state of the plasma. Otherwise, the validity of the diagnostic results by the two methods were analyzed and compared. In addition, the affection from laboratory background radiation during the spectral acquisition process was discussed.

  17. History-dependent dynamics in a generic model of ion channels - an analytic study

    Directory of Open Access Journals (Sweden)

    Daniel Soudry

    2010-04-01

    Full Text Available Recent experiments have demonstrated that the timescale of adaptation of single neurons and ion channel populations to stimuli slows down as the length of stimulation increases; in fact, no upper bound on temporal time-scales seems to exist in such systems. Furthermore, patch clamp experiments on single ion channels have hinted at the existence of large, mostly unobservable, inactivation state spaces within a single ion channel. This raises the question of the relation between this multitude of inactivation states and the observed behavior. In this work we propose a minimal model for ion channel dynamics which does not assume any specific structure of the inactivation state space. The model is simple enough to render an analytical study possible. This leads to a clear and concise explanation of the experimentally observed exponential history-dependent relaxation in sodium channels in a voltage clamp setting, and shows that their recovery rate from slow inactivation must be voltage dependent. Furthermore, we predict that history-dependent relaxation cannot be created by overly sparse spiking activity. While the model was created with ion channel populations in mind, its simplicity and genericalness render it a good starting point for modeling similar effects in other systems, and for scaling up to higher levels such as single neurons which are also known to exhibit multiple time scales.

  18. Spectrophotometric evaluation of calcium ion release from different calcium hydroxide preparations: An in-vitro study.

    Directory of Open Access Journals (Sweden)

    Atul Jain

    2017-03-01

    Full Text Available Pulp tissue conditions such as infections have long been treated with calcium hydroxide (CaOH. In the last decade, use of mineral trioxide aggregate (MTA has gained ground. This study was carried out to comparatively evaluate the Ca release from CaOH powder with different vehicles and different types of MTA. Materials and Methods: 40 single rooted mandibular premolars were selected, decoronated and biomechanically prepared. They were randomly divided into four groups, consisting of 10 samples each. Root canals were packed with different preparations of CaOH and MTA. Calcium ion release was evaluated with an UV-spectrophotometer. Result: Amongst the CaOH preparations, using propylene glycol as a vehicle produced extended release of calcium ions (7.34±0.01 for a period of 14 days. Whereas, amongst MTA based products, MTA angelus produced the maximum release of calcium ions (2.42±0.010. A statistically significant difference was present between the four groups (p<0.05. Conclusion: Propylene glycol mixed with CaOH powder, produces a higher and extended release of calcium ions compared to distilled water. MTA angelus produces consistent calcium ion release.

  19. Study on Pressure drop for Ion Exchanger in Jordan Research and Training Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Park, Ki-jung; Choi, Jungwoon; Kim, Seong-Hoon; Chi, Dae-Young; Park, Cheol [KAERI, Daejeon (Korea, Republic of)

    2016-05-15

    The Jordan Research and Training Reactor (JRTR) is currently being constructed and commissioned in the JUST (Jordan University of Science and Technology) site. The main fluid systems relevant to the JRTR have been proceeding at the Korea Atomic Energy Research Institute. In order to achieve the purpose of the pool water purification, two filters and two ion exchangers which can be to remove suspended solids and ionic impurities in the in-taken pool water have been designed. For the reliable design of this system pump, it is important to predict the pressure drop of the system equipment including the ion exchanger. In this study, the pressure drop in the ion exchanger of PWMS is predicted by using the well-known model and the results provided from manufacturing company. And, the calculated results are compared to the actual data which is measured from the ion exchanger during the PWMS commissioning. The predicted pressure drop is dominated by the resin bed as a portion of about 85% for total pressure drop. The predicted pressure drop is compared to the measured pressure drop of the ion exchanger which is installed in the JRTR, the data above 5 kg/s agree within 5% in the entire range.

  20. DFT study on the interaction between hydrogen sulfide ions and cerussite (110) surface

    Science.gov (United States)

    Feng, Qicheng; Wen, Shuming; Deng, Jiushuai; Zhao, Wenjuan

    2017-02-01

    The interaction between hydrogen sulfide ions (HS-) and the cerussite surface was simulated using density functional theory (DFT) calculations. The calculated results show that Pb atoms are the dominating active sites for the subsequent reaction on the cerussite (110) surface. The S atom in HS- ions can readily interact with the Pb atoms at the cerussite surface layers with the interaction energy of -5.19 eV, resulting in the formation of lead sulfide species. An obvious difference occurs when HS- ions interact with the various Pb atoms on the cerussite surface. The density of state analysis reveals that the Pb 6p orbital at the mineral surface layers and S 3p orbital from HS- ions are overlapped between -1.5 and 0.5 eV near the Fermi level, indicating a stable chemical adsorption. The Mulliken population result suggests that the electron transfer exists between the bonding atoms and the oxidation of the HS- ions is involved in the adsorption process. This study provides an insight into the sulfidization mechanism at an atomic level, and further confirms the experimental phenomenon proposed in our previous work.

  1. Studies of infrasound propagation using the USArray seismic network (Invited)

    Science.gov (United States)

    Hedlin, M. A.; Degroot-Hedlin, C. D.; Walker, K. T.

    2010-12-01

    Although there are currently ~ 100 infrasound arrays worldwide, more than ever before, the station density is still insufficient to provide validation for detailed propagation modeling. Much structure in the atmosphere is short-lived and occurs at spatial scales much smaller than the average distance between infrasound stations. Relatively large infrasound signals can be observed on seismic channels due to coupling at the Earth's surface. Recent research, using data from the 70-km spaced 400-station USArray and other seismic network deployments, has shown the value of dense seismic network data for filling in the gaps between infrasound arrays. The dense sampling of the infrasound wavefield has allowed us to observe complete travel-time branches of infrasound signals and shed more light on the nature of infrasound propagation. We present early results from our studies of impulsive atmospheric sources, such as series of UTTR rocket motor detonations in Utah. The Utah blasts have been well recorded by USArray seismic stations and infrasound arrays in Nevada and Washington State. Recordings of seismic signals from a series of six events in 2007 are used to pinpoint the shot times to anticipate studying dense acoustic network recordings as the USArray is currently being upgraded with infrasound microphones. These new sensors will allow us to make semi-continental scale network recordings of infrasound signals free of concerns about how the signals observed on seismic channels were modified when being coupled to seismic.

  2. Analysis of bone minerals by time-of-flight secondary ion mass spectrometry: a comparative study using monoatomic and cluster ions sources.

    Science.gov (United States)

    Malmberg, Per; Bexell, Ulf; Eriksson, Cecilia; Nygren, Håkan; Richter, Katrin

    2007-01-01

    Time-of-flight secondary ion mass spectrometry (TOF-SIMS) is an important tool for the analysis of bone minerals at implant surfaces. Most studies have been performed with monoatomic primary ion sources such as Ga(+) with poor secondary molecular ion production efficiency and only elemental distributions and minor fragments of bone minerals have been reported. By using cluster ion sources, such as Au(1-3) (+) and Bi(1-3) (+), identification of larger hydroxyapatite species at m/z 485, 541, 597 and 653, identified as Ca(5)P(3)O(12), Ca(6)P(3)O(13), Ca(7)P(3)O(14) and Ca(8)P(3)O(15), respectively, became possible. The ions appear to be fragments of the hydroxyapatite unit cell Ca(10)(PO(4))(6)(OH)(2). Each ion in the series is separated by 55.9 m/z units, corresponding to CaO, and this separation might reflect the columnar nature of the unit cell. Copyright (c) 2007 John Wiley & Sons, Ltd.

  3. Sustaining a Global Social Network: a quasi-experimental study.

    Science.gov (United States)

    Benton, D C; Ferguson, S L

    2017-03-01

    To examine the longer term impact on the social network of participating nurses in the Global Nursing Leadership Institute (GNLI2013) through using differing frequencies of follow-up to assess impact on maintenance of network cohesion. Social network analysis is increasingly been used by nurse researchers, however, studies tend to use single point-in-time descriptive methods. This study utilizes a repeated measures, block group, control-intervention, quasi-experimental design. Twenty-eight nurse leaders, competitively selected through a double-blind peer review process, were allocated to five action learning-based learning groups. Network architecture, measures of cohesion and node degree frequency were all used to assess programme impact. The programme initiated and sustained connections between nurse leaders drawn from a geographically dispersed heterogeneous group. Modest inputs of two to three e-mails over a 6-month period seem sufficient to maintain connectivity as indicated by measures of network density, diameter and path length. Due to the teaching methodology used, the study sample was relatively small and the follow-up data collection took place after a relatively short time. Replication and further cohort data collection would be advantageous. In an era where many policy solutions are being debated and initiated at the global level, action learning leadership development that utilizes new technology follow-up appears to show significant impact and is worthy of wider application. The approach warrants further inquiry and testing as to its longer term effects on nursing's influence on policy formulation and implementation. © 2016 International Council of Nurses.

  4. International operations networks

    CERN Document Server

    Farooq, Sami; Cheng, Yang

    2014-01-01

    Although the area of International Manufacturing Network (IMN) and International Operations Network (ION) has received considerable attention in the literature, most of studies appear multifaceted and interdisciplinary, and thereby require thorough investigation from both academic and practical perspectives, in order to deepen our related understanding. The book seeks advanced contributions that will combine theoretical insights and empirical experience by offering a detailed examination of IMN and, further, ION from various perspectives. This book can be used as a reference material for scholarpractitioners, business executives, and university researchers who need to deepen their understanding on the importance and influence of IMN and ION as well as their development. The book is important because there are few reference/resource materials available related to IMN and ION.

  5. Physicochemical studies on Ciclopirox olamine complexes with divalent metal ions.

    Science.gov (United States)

    Tarawneh, Ruba T; Hamdan, Imad I; Bani-Jaber, Ahmad; Darwish, Rula M

    2005-01-31

    Ciclopirox olamine (CPO) metal complexes have been prepared and characterized using elemental analysis, infra red (IR), melting point and differential scanning calorimetry (DSC). Spectroscopic titration using molar ratio method indicated the occurrence of 1:1 complexes for CPO with almost all the examined metals. Physicochemical properties were also studied including aqueous solubility and apparent partition coefficient. Results showed that generally complex formation dramatically decreased the solubility and increased apparent partition coefficient. However, some metal complexes exhibited opposite effect. It could be concluded that complex formation can modify the solubility and apparent partition coefficient, which may suggest the use of complexes to manipulate the physicochemical properties of the drug.

  6. EPR and optical absorption studies on manganese ion doped in mixed alkali cadmium phosphate glasses

    Science.gov (United States)

    Giridhar, G.; Rangacharyulu, M.; Ravikumar, R. V. S. S. N.; Sambasiva Rao, P.

    2009-07-01

    Electron paramagnetic resonance (EPR) spectra of Mn(II) ions in cadmium phosphate glasses are presented with mixed alkali variation as xLi2O + (20 - x) Na2O + 20 CdO + 59.5 P2O5 + 0.5 MnO glass system with 5 EPR spectra of Mn(II) ions doped samples exhibit a sextet centered at g = 2·0. The optical absorption spectrum at room temperature shows three bands for Mn(II) ions in octahedral symmetry. The crystal field (Dq) and Racah parameters (B and C) are evaluated. From EPR and optical spectral studies reveals the nature of the bonding is dominantly ionic and its site symmetry is octahedral. At equal composition of alkali content, i.e. for x = 10 the glass system shows the mixed alkali effect.

  7. Electrophoretic studies of polygalacturonate oligomers and their interactions with metal ions.

    Science.gov (United States)

    Wiedmer, S K; Cassely, A; Hong, M; Novotny, M V; Riekkola, M L

    2000-09-01

    Polygalacturonic acid, a linear homopolysaccharide, was investigated by capillary electrophoresis (CE) using linear polyacrylamide-coated capillaries and laser-induced fluorescence (LIF) detection. A successful separation of its fluorescently labeled oligomers was achieved through sieving in polyacrylamide entangled matrices. The reaction conditions for the derivatization of polygalacturonic acid were optimized. In studying the interactions between polygalacturonic acid and various metal ions, the end-label, free-solution electrophoretic (ELFSE) technique, developed earlier in our laboratory (Sudor, J., Novotny, M. V., Anal. Chem. 1995, 67, 4205-4209) was found preferable to the sieving method. ELFSE is fast and convenient in that no polymer solutions are needed for the separation. The investigation showed that for the moderately large oligomers, the strongest binding occurred with calcium and cadmium ions, while the smallest interaction was observed with magnesium ions.

  8. Ion beam experiments for the study of plasma-surface interactions

    Science.gov (United States)

    Karahashi, Kazuhiro; Hamaguchi, Satoshi

    2014-06-01

    Experimental studies based on mass-selected ion beams are reviewed as a means to examine plasma-surface interactions for industrial plasma processing. Plasma etching and deposition processes widely used in the microelectronics industry exploit surface chemical reactions induced by plasmas. Such reactions typically result from a conglomeration of complex interactions of the surface material with incident free radicals and ions. While it is in general difficult to analyse individual surface reactions separately in a plasma system, ion and/or charge-neutral beam experiments allow one to analyse specific surface reactions involving only selected gaseous species. In this review, experiments on beam-surface interactions are discussed in detail and beam reaction data for silicon surfaces are presented as sample data.

  9. Study of Effect of Ion Source Energy Spread on RFQ Beam Dynamics at REX-ISOLDE

    CERN Document Server

    Fraser, M A

    2013-01-01

    With an upgrade to the Electron Beam Ion Source (EBIS) at REX under consideration a study was launched in order to understand the effect of an increased energy spread from the ion source on the beam dynamics of the RFQ. Due to the increased electron beam potential needed to achieve the upgrade’s charge breeding specification it is expected that the energy spread of the beam will increase from today’s estimated value of approximately +-0.1%. It is shown through beam dynamics simulations that the energy spread can be increased to +-1% without significant degradation of the beam quality output by the RFQ.

  10. Evolution of MBE HgCdTe defect structure studied with ion milling method

    Directory of Open Access Journals (Sweden)

    Pociask-Bialy Malgorzata

    2017-01-01

    Full Text Available In this paper, is shown how ion milling can assist in assessing the defect structure of MCT by revealing the residual doping, and establishing the minimum level of donor concentration Nmd, which is needed for obtaining n-regions with a reproducible n value. For this purpose, a study of the electrical properties of ion-milled LWIR n-type MCT films, un-doped and doped with indium with the concentration NIn = 5 × 1014–1017 cm−3 is proposed.

  11. Surgery of fast, highly charged ions studied by zero-degree Auger spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Stolterfoht, N.; Miller, P.D.; Krause, H.F.; Yamazaki, Y.; Swenson, J.K.; Bruch, R.; Dittner, P.F.; Pepmiller, P.L.; Datz, S.

    1986-01-01

    Zero-degree Auger spectra were measured in collisions of oxygen and carbon on He with incident charge states of q = 2 to 5 and for energies from 5 to 30 MeV. Since the light target particle He acts selectively on the projectile ion, we refer to the present method as ion surgery. Apart from the one-electron processes single excitation and single loss, two-electron processes such as transfer excitation and transfer loss are studied. 17 refs., 4 figs., 1 tab.

  12. A Comprehensive Study on the Degradation of Lithium-Ion Batteries during Calendar Ageing

    DEFF Research Database (Denmark)

    Stroe, Daniel Loan; Swierczynski, Maciej Jozef; Kær, Søren Knudsen

    2016-01-01

    their capacity and internal resistance. This paper investigates, based on extended laboratory calendar ageing tests, the degradation of the internal resistance of a Lithium-ion battery. The dependence of the internal resistance increase on the temperature and state-of-charge level have been extensive studied...... and quantified. Based on the obtained laboratory results, an accurate semi-empirical lifetime model, which is able to predict with high accuracy the internal resistance increase of the Lithium-ion battery over a wide temperature range and for all state-of-charge levels was proposed and validated....

  13. The Rare Cancer Network: ongoing studies and future strategy

    Directory of Open Access Journals (Sweden)

    Mahmut Ozsahin

    2014-08-01

    Full Text Available The Rare Cancer Network (RCN was formed in the early 1990’s to create a global network that could pool knowledge and resources in the studies of rare malignancies whose infrequency prevented both their study with prospective clinical trials. To date, the RCN has initiated 74 studies resulting in 46 peer reviewed publications. The First International Symposium of the Rare Cancer Network took place in Nice in March of 2014. Status updates and proposals for new studies were heard for fifteen topics. Ongoing studies continue for cardiac sarcomas, thyroid cancers, glomus tumors, and adult medulloblastomas. New proposals were presented at the symposium for primary hepatic lymphoma, solitary fibrous tumors, Rosai-Dorfman disease, tumors of the ampulla of Vater, salivary gland tumors, anorectal melanoma, midline nuclear protein in testes carcinoma, pulmonary lymphoepithelioma-like carcinoma, adenoid cystic carcinoma of the trachea, osteosarcomas of the mandible, and extra-cranial hemangiopericytoma. This manuscript presents the abstracts of those proposals and updates on ongoing studies, as well a brief summary of the vision and future of the RCN.

  14. Transverse studies with ions at SPS flat bottom

    CERN Document Server

    Antoniou, F; Saa Hernandez, A; Huschauer, A

    2017-01-01

    The LHC injectors upgrade project (LIU) aims at con-solidating and upgrading the existing accelerator chain atCERN in view of the increased beam performance requiredfor the High Luminosity LHC (HL-LHC) project. For theion chain, the losses and emittance growth in the SPS imposepresently the main performance limitation. The significantbeam degradation encountered on the long injection plateauhas been studied during the 2016 MD runs with Pb82+. Inthis report we present the systematic measurements of emit-tance, bunch length and transmission performed along theinjection plateau for different bunch intensities. We present,as well, static and dynamic tune scans for the optimizationof the working point and measurement of the loss rate atcloseby resonances.

  15. Studies of copper(II) sulphide ion-selective electrodes.

    Science.gov (United States)

    Johansson, G; Edström, K

    1972-12-01

    Changes in liquid junction potentials in copper(II) solutions were measured when different reference electrodes were used. The slope and intercept of a calibration curve for a copper-selective electrode will depend on the selection of reference electrode. The condition of the electrode surface of an Orion copper-selective electrode was studied microscopically and the influence of redox potential on stability of the electrode against corrosion is discussed. Oxidizing solutions will produce pits at dislocations in the material and there will be a mixed electrode potential. The slope, stability, and speed of response are much lower when the surface contains pits. Diamond-polishing was shown to improve the electrode significantly.

  16. Novel computational approach for studying ph effects, excluded volume and ion-ion correlations in electrical double layers around polyelectrolytes and nanoparticles

    Science.gov (United States)

    Ovanesyan, Zaven

    , which are important details for proper description of EDL properties. In this thesis, we implement an efficient and accurate classical solvation density functional theory (CDSFT) for EDLs of spherical macroions and cylindrical polyelectrolytes embedded in aqueous electrolytes. This approach extends the capabilities of mean field approximations by taking into account electrostatic ion-ion correlations, size asymmetry and excluded volume effects without compromising the computational cost. We apply the computational tool to study the structural and thermodynamic properties of the ionic atmosphere around B-DNA and spherical nanoparticles. We demonstrate that the presence of solvent molecules at experimental concentration and size values has a significant impact on the layering of ions. This layering directly influences the integrated charge and mean electrostatic potential in the diffuse region of the spherical electrical double layer (SEDL) and have a noticeable impact on the behavior of zeta potential (ZP). Recently, we have extended the aforementioned CSDFT to account for the charge-regulated mechanisms of the macroion surface on the structural and thermodynamic properties of spherical EDLs. In the approach, the CSDFT is combined with a surface complexation model to account for ion correlation and excluded volume effects on the surface titration of spherical macroions. We apply the proposed computational approach to describe the role that the ion size and solvent excluded volume play on the surface titration properties of silica nanoparticles. We analyze the effects of the nanoparticle size, pH and salt concentration of the aqueous solution on the nanoparticle's surface charge and zeta potential. The results reveal that surface charge density and zeta potential significantly depend on excluded volume and ion-ion correlation effects as well as on pH for monovalent ion species at high salt concentrations. Overall, our results are in good agreement with Monte Carlo

  17. Studying Policy Transfer through the Lens of Social Network Analysis

    DEFF Research Database (Denmark)

    Staunæs, Dorthe; Brøgger, Katja; Steiner-Khamsi, Gita

    Studying Policy Transfer through the Lens of Social Network Analysis The panelists present the findings of a joint empirical research project carried out at Aarhus University (DPU/Copenhagen) and at Teachers College, Columbia University (New York). The research project succeeded to identify...... or collaborating with each other, respectively. Against the backdrop of globalization studies in comparative education, the research project attempted to identify borrowers, translators, and brokers of educational reform drawing on a complementary set of expertise from social network analysis methodology (Oren...... Pizmony-Levy Drezner), research on the 2014 Danish school reform (Dorthe Staunæs), policy borrowing theory and methodology (Katja Brøgger Jensen), and comparative policy studies (Gita Steiner-Khamsi). Papers The Relevance of the Research Project Understanding the Context/Case Policy Borrowing Research...

  18. Supertetrahedral networks and lithium-ion mobility in Li{sub 2}SiP{sub 2} and LiSi{sub 2}P{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Haffner, Arthur; Braeuniger, Thomas; Johrendt, Dirk [Department Chemie, Ludwig-Maximilians-Universitaet Muenchen (Germany)

    2016-10-17

    The new phosphidosilicates Li{sub 2}SiP{sub 2} and LiSi{sub 2}P{sub 3} were synthesized by heating the elements at 1123 K and characterized by single-crystal X-ray diffraction. Li{sub 2}SiP{sub 2} (I4{sub 1}/acd, Z=32, a=12.111(1) Aa, c=18.658(2) Aa) contains two interpenetrating diamond-like tetrahedral networks consisting of corner-sharing T2 supertetrahedra [(SiP{sub 4/2}){sub 4}]. Sphalerite-like interpenetrating networks of uniquely bridged T4 and T5 supertetrahedra make up the complex structure of LiSi{sub 2}P{sub 3} (I4{sub 1}/a, Z=100, a=18.4757(3) Aa, c=35.0982(6) Aa). The lithium ions are located in the open spaces between the supertetrahedra and coordinated by four to six phosphorus atoms. Temperature-dependent {sup 7}Li solid-state MAS NMR spectroscopic data indicate high mobility of the Li{sup +} ions with low activation energies of 0.10 eV in Li{sub 2}SiP{sub 2} and 0.07 eV in LiSi{sub 2}P{sub 3}. (copyright 2016 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim)

  19. Data science and complex networks real case studies with Python

    CERN Document Server

    Caldarelli, Guido

    2016-01-01

    This book provides a comprehensive yet short description of the basic concepts of complex network theory and the code to implement this theory. Differently from other books, we present these concepts starting from real cases of study. The application topics span from food webs, to the Internet, the World Wide Web, and social networks, passing through the international trade web and financial time series. The final part is devoted to definition and implementation of the most important network models. We provide information on the structure of the data and on the quality of available datasets. Furthermore, we provide a series of codes to implement instantly what is described theoretically in the book. People knowing the basis of network theory could learn the art of coding in Python by checking our codes and using the online material. In particular, the interactive Python notebook format is used so that the reader can immediately experiment by themselves with the codes present in the manuscript. To this purpose...

  20. Wind Speed Forecasting by Wavelet Neural Networks: A Comparative Study

    Directory of Open Access Journals (Sweden)

    Chuanan Yao

    2013-01-01

    Full Text Available Due to the environmental degradation and depletion of conventional energy, much attention has been devoted to wind energy in many countries. The intermittent nature of wind power has had a great impact on power grid security. Accurate forecasting of wind speed plays a vital role in power system stability. This paper presents a comparison of three wavelet neural networks for short-term forecasting of wind speed. The first two combined models are two types of basic combinations of wavelet transform and neural network, namely, compact wavelet neural network (CWNN and loose wavelet neural network (LWNN in this study, and the third model is a new hybrid method based on the CWNN and LWNN models. The efficiency of the combined models has been evaluated by using actual wind speed from two test stations in North China. The results show that the forecasting performances of the CWNN and LWNN models are unstable and are affected by the test stations selected; the third model is far more accurate than the other forecasting models in spite of the drawback of lower computational efficiency.

  1. A study on equilibrium and kinetics of ion exchange of alkaline earth ...

    Indian Academy of Sciences (India)

    A study on equilibrium and kinetics of ion exchange of alkaline earth metals using an inorganic cation exchanger - zirconium titanium phosphate ... Further, various kinetic parameters like self-diffusion coefficient (0), energy of activation () and entropy of activation (*) have been evaluated under conditions favouring a ...

  2. Kinetic and equilibrium studies on the adsorption of Cu and Zn ions ...

    African Journals Online (AJOL)

    STORAGESEVER

    2009-07-20

    Jul 20, 2009 ... Quite a number of biomaterials have been inves-. *Corresponding author. ... is imperative that more biomaterials be studied for their potential ... Data analysis. The mean metal ion adsorbed by the biomass was determined using a mass balance equation by Chu and Hashin (2001);. (. )t. O t. C. C m. V q. −. =.

  3. Studies of Compound States of Atomic Negative Ions Using Laser Beams

    Science.gov (United States)

    1984-07-01

    of experimental state. The results agree closely with the experimental and theoretical studies of the He- ion. value of 0.076 eV obtained by Oparin ...420 10 V. A. Oparin , R. N. Ilin, i. T. Serenkov and N. V. Fedorenko, (1968). Zh. Eksp. Teor. Fiz. Pis’ma Red. 12, 237 (1970) [JETP Lett. 25G. N. Estberg

  4. Real-time scanning tunneling microscopy studies of thin film deposition and ion erosion

    NARCIS (Netherlands)

    Fokkema, Vincent

    2011-01-01

    In this thesis I present my research on the physics of some important processes in the production of thin films. I studied physical vapour deposition (PVD) and thin film modification through ion bombardment using a newly developed, high-speed scanning tunneling microscope (STM). The instrument has

  5. Field ionization kinetic and electron impact studies of gas phase transition states - The cyclic bromonium ion

    Science.gov (United States)

    Green, M. M.; Giguere, R. J.; Falick, A. M.; Aberth, W.; Burlingame, A. L.

    1978-01-01

    Cis- and trans-isomers of 4-t-butylcyclohexyl bromide were studied to determine the mechanism of cyclic bromonium ion formation. The field ionization kinetic and electron impact data indicate that the formation of the cyclic structure occurs simultaneously with loss of the neutral fragment. The data also show that little or no gas-phase cis-trans isomerization occurs.

  6. Adsorption studies for the removal of Cr(VI) ion from aqueous solution

    African Journals Online (AJOL)

    The adsorption characteristics of Cr(VI) in the form of Cr2O7(-2) ion from aqueous solution onto synthetic exchanger Amberlite IRA 400(Cl) resin was studied from UV – visible spectrphotometric measurement using DPC at 580nm. The efficiency of the adsorbent was judged from the variation of the % adsorption with (i) ...

  7. Adsorption of ions on hematite (α-Fe2O3) : a colloid-chemical study

    NARCIS (Netherlands)

    Breeuwsma, A.

    1973-01-01

    This study is primarily intended to provide a better understanding of the adsorption of ions on hematite (α-Fe 2 O 3 ). In addition, due attention is given to the relation between the ionic adsorption and the colloidal stability of hematite sols.

    Chapter 1. is concerned

  8. Structural Behavioral Study on the General Aviation Network Based on Complex Network

    Science.gov (United States)

    Zhang, Liang; Lu, Na

    2017-12-01

    The general aviation system is an open and dissipative system with complex structures and behavioral features. This paper has established the system model and network model for general aviation. We have analyzed integral attributes and individual attributes by applying the complex network theory and concluded that the general aviation network has influential enterprise factors and node relations. We have checked whether the network has small world effect, scale-free property and network centrality property which a complex network should have by applying degree distribution of functions and proved that the general aviation network system is a complex network. Therefore, we propose to achieve the evolution process of the general aviation industrial chain to collaborative innovation cluster of advanced-form industries by strengthening network multiplication effect, stimulating innovation performance and spanning the structural hole path.

  9. Computational study of noise in a large signal transduction network

    Directory of Open Access Journals (Sweden)

    Ruohonen Keijo

    2011-06-01

    Full Text Available Abstract Background Biochemical systems are inherently noisy due to the discrete reaction events that occur in a random manner. Although noise is often perceived as a disturbing factor, the system might actually benefit from it. In order to understand the role of noise better, its quality must be studied in a quantitative manner. Computational analysis and modeling play an essential role in this demanding endeavor. Results We implemented a large nonlinear signal transduction network combining protein kinase C, mitogen-activated protein kinase, phospholipase A2, and β isoform of phospholipase C networks. We simulated the network in 300 different cellular volumes using the exact Gillespie stochastic simulation algorithm and analyzed the results in both the time and frequency domain. In order to perform simulations in a reasonable time, we used modern parallel computing techniques. The analysis revealed that time and frequency domain characteristics depend on the system volume. The simulation results also indicated that there are several kinds of noise processes in the network, all of them representing different kinds of low-frequency fluctuations. In the simulations, the power of noise decreased on all frequencies when the system volume was increased. Conclusions We concluded that basic frequency domain techniques can be applied to the analysis of simulation results produced by the Gillespie stochastic simulation algorithm. This approach is suited not only to the study of fluctuations but also to the study of pure noise processes. Noise seems to have an important role in biochemical systems and its properties can be numerically studied by simulating the reacting system in different cellular volumes. Parallel computing techniques make it possible to run massive simulations in hundreds of volumes and, as a result, accurate statistics can be obtained from computational studies.

  10. Conceptual study of in-tank cesium removal using an inorganic ion exchange material

    Energy Technology Data Exchange (ETDEWEB)

    Goheen, R.S.; Kurath, D.E.

    1996-04-01

    Presently, the Hanford Site contains approximately 230,000 m{sup 3} of mixed waste stored in 177 underground tanks. Approximately 55,000 m{sup 3} of this waste is sludge, 90,000 m{sup 3} is salt cake, and 80,000 m{sup 3} is supernate. Although the pretreatment and final disposal requirements for the waste have not been entirely defined, it is likely that some supernatant pretreatment will be required to remove {sup 137}Cs and possibly {sup 90}Sr and the transuranic components. The objective of this study was to estimate the number of HLW glass canisters resulting from the use of inorganic ion exchanger materials as in-tank pretreatment technology. The variables in the study were: number of contacts between waste and ion exchange material; ion exchange material; and decontamination requirement. This conceptual study investigates a generic in-tank Cs removal flowsheet using crystalline silico-titanates and IE-96 zeolites, and the impact of each ion exchanger on the number of glass canisters produced. In determining glass formulation, data based on current reference technology was used. Sample calculations from the worksheets and summaries of final calculated results are included at the end of this report.

  11. Educational Designs Supporting Student Engagement Through Network Project Studies

    DEFF Research Database (Denmark)

    Nielsen, Jørgen Lerche

    2016-01-01

    , developed from the traditions of organizing university studies through student-driven project work and problem-driven learning approaches, which have been developed at the Danish universities of Roskilde and Aalborg as early as from the beginning of the 1970s. Specific educational designs integrating...... digital media are discussed, especially focusing on student engagement and the implications of organizing the pedagogical practice as networked project work. The discussions are based on the author’s experiences during 16 years of teaching and supervising at the Danish Master’s Program of ICT and Learning...... (MIL), where students conduct blended learning study in groups within a networked learning structure. In problem-oriented learning and teaching, teachers act as well as teachers and as supervisors of students’ projects. This challenges the traditional teacher role, and it is crucial for a teacher...

  12. Bayesian neural networks for detecting epistasis in genetic association studies.

    Science.gov (United States)

    Beam, Andrew L; Motsinger-Reif, Alison; Doyle, Jon

    2014-11-21

    Discovering causal genetic variants from large genetic association studies poses many difficult challenges. Assessing which genetic markers are involved in determining trait status is a computationally demanding task, especially in the presence of gene-gene interactions. A non-parametric Bayesian approach in the form of a Bayesian neural network is proposed for use in analyzing genetic association studies. Demonstrations on synthetic and real data reveal they are able to efficiently and accurately determine which variants are involved in determining case-control status. By using graphics processing units (GPUs) the time needed to build these models is decreased by several orders of magnitude. In comparison with commonly used approaches for detecting interactions, Bayesian neural networks perform very well across a broad spectrum of possible genetic relationships. The proposed framework is shown to be a powerful method for detecting causal SNPs while being computationally efficient enough to handle large datasets.

  13. Heterogeneous fuzzy logic networks: fundamentals and development studies.

    Science.gov (United States)

    Pedrycz, Witold

    2004-11-01

    The recent trend in the development of neurofuzzy systems has profoundly emphasized the importance of synergy between the fundamentals of fuzzy sets and neural networks. The resulting frameworks of the neurofuzzy systems took advantage of an array of learning mechanisms primarily originating within the theory of neurocomputing and the use of fuzzy models (predominantly rule-based systems) being well established in the realm of fuzzy sets. Ideally, one can anticipate that neurofuzzy systems should fully exploit the linkages between these two technologies while strongly preserving their evident identities (plasticity or learning abilities to be shared by the transparency and full interpretability of the resulting neurofuzzy constructs). Interestingly, this synergy still becomes a target yet to be satisfied. This study is an attempt to address the fundamental interpretability challenge of neurofuzzy systems. Our underlying conjecture is that the transparency of any neurofuzzy system links directly with the logic fabric of the system so the logic fundamentals of the underlying architecture become of primordial relevance. Having this in mind the development of neurofuzzy models hinges on a collection of logic driven processing units named here fuzzy (logic) neurons. These are conceptually simple logic-oriented elements that come with a well-defined semantics and plasticity. Owing to their diversity, such neurons form essential building blocks of the networks. The study revisits the existing categories of logic neurons, provides with their taxonomy, helps understand their functional features and sheds light on their behavior when being treated as computational components of any neurofuzzy architecture. The two main categories of aggregative and reference neurons are deeply rooted in the fundamental operations encountered in the technology of fuzzy sets (including logic operations, linguistic modifiers, and logic reference operations). The developed heterogeneous networks

  14. The study of individual large ions using fourier transform ion cyclotron resonance: An approach for increasing mass range and sensitivity

    Energy Technology Data Exchange (ETDEWEB)

    Smith, R.D.; Bruce, J.E.; Cheng, Xueheng; Hofstadler, S.A.; Anderson, G.A.; Wu, Qinyuan; Chen, Ruidan; Van Orden, S.L.; Rockwood, A.L.; Mitchell, D.W. [Pacific National Lab., Richland, WA (United States)

    1994-12-31

    ESI-FTICR offers the benefits of mass spectrometry combined with nondestructive detection. Because detection is nondestructive, ions can be remeasured many times. In this work, the feasibility of detecting a single molecule with multiple charges is considered. Polyethylene glycol (PEG) was used a test molecule.

  15. Study of the magnets used for a mobile isocenter carbon ion gantry.

    Science.gov (United States)

    Moreno, Jhonnatan Osorio; Pullia, Marco G; Priano, Cristiana; Lante, Valeria; Necchi, Monica M; Savazzi, Simone

    2013-07-01

    A conceptual design of a mobile isocenter carbon ion gantry was carried out in the framework of the Particle Training Network for European Radiotherapy (PARTNER) and Union of Light Ion Centres in Europe (ULICE) projects. To validate the magnets used in this gantry, Finite Element Method (FEM) simulations were performed with COMSOL multiphysics; the purpose was to evaluate the magnetic field quality and the influence of additional support structures for correctors, 90° bending dipole and quadrupoles, both in dynamic and static regimes. Due to the low ramp rates, the dynamic effects do not disturb the homogeneity and the magnetic field level. The differences between the stationary field and the corresponding dynamic field after the end of the ramps are in the order of 10(-4); it implies that the magnets can be operated without significant field lag at the nominal ramp rate. However, even in static regime the magnetic length of corrector magnet decreases by 5% when the rotator mechanical structure is considered. The simulations suggest an optimization phase of the correctors in the rotator.

  16. A Study on Network Configuration of Distributed Flexible Network PV System

    Science.gov (United States)

    Dakkak, Mohamed; Hatori, Kenji; Miura, Yushi; Ise, Toshifumi

    The introduction of Distributed Flexible Network Photovoltaic (DFNPV) system is going towards solving the shortcomings of stand-alone systems in remote areas. Three types of configurations of DFNPV system are studied: star, loop, and mesh. Each configuration has many subsystems, which are assumed to have the similar characteristics and location, and consist of PV panel, DC/DC converter, and dc load. Comparative study had been carried out from the viewpoint of power losses in wires, wire length, and initial cost. First of all for estimating the size of DFNPV system within acceptable voltage drop, relations between wire length, power loss, wire cost, and cable types are discussed. The problem in DFNPV System is to find the best location of the battery bank from a many viewpoints, minimum extension cost and minimum losses in wires. This paper describes how to optimize the best location of the common battery bank from the viewpoints of the cost of power losses and the extension cost. The results of optimizing configurations show that a star configuration for initial installations is most effective, in future expansion; loop network is more cost effective. In addition, the economic study shows the final cost advantage of DFNPV system, for three types of configurations over stand-alone ones.

  17. Ion Exchange Study of Some New Copolymer Resins Derived from 8-Hydroxyquinoline-5-sulphonic Acid, Biuret and Formaldehyde

    Directory of Open Access Journals (Sweden)

    P. A. Dhakite

    2011-01-01

    Full Text Available Copolymer resins (8-HQSABF were synthesized by the condensation of 8-hydroxyquinoline-5-sulphonic acid and biuret with formaldehyde in the presence of hydrochloric acid as catalyst, proved to be selective chelation ion exchange copolymer resins for certain metals. Chelation ion exchange properties to these polymers were studied for Cu2+, Cd2+, Co2+ and Zn2+ ions. A batch equilibrium method was employed in the study of the selectivity of the distribution of a given metal ions between the polymer sample and a solution containing the metal ion. The study was carried out over a wide pH range and in a media of various ions strengths. The polymer showed a higher selectivity for Cu2+ ions than for Cd2+, Co2+ and Zn2+ ions. Hence on the basis of above studies these copolymer may be used as semiconductors, surface coating, ion-exchangers, materials for rechargeable battery cell in various electronic industries, plastic materials, elastomers and in boiler plants

  18. Developing Educational designs supporting student engagement through networked project studies

    DEFF Research Database (Denmark)

    Nielsen, Jørgen Lerche; Birch Andreasen, Lars

    2013-01-01

    within a networked learning structure are studying in groups combining on-site seminars with independent and challenging virtually organized project periods, implementing new educational technology, which require teachers who are flexible and aware of the different challenges in the networked environment...... in the online dialogues. Thus in contrast to the traditional understanding of the teacher as the sole designer of the learning environment, here the students were involved as active co-designers. Our understanding of problem-based learning is characterized by collaborative project work in groups, where students...... and interconnected learners, and discuss cases of developing student engagement through educational designs that facilitates group organized project work and learners’ participation in dialogically organized online seminars. Here we will focus on how the dimensions of participation and reification are played out....

  19. Impact of green technologies in optical networks case study: green wireless optical broadband access network

    Science.gov (United States)

    Puche, William S.; Sierra, Javier E.

    2014-09-01

    This article analyzes the current state of green technologies in optical telecommunications networks, analyzing in detail the basic structure of a hybrid network (Optical-Wireless), taking into account energy consumption by proposing a mathematical model is presented to establish the optimum number of ONUs in a network.

  20. MetaNetwork : A computational protocol for the genetic study of metabolic networks

    NARCIS (Netherlands)

    Fu, Jingyuan; Swertz, Morris A.; Keurentjes, Joost J. B.; Jansen, Ritsert C.

    2007-01-01

    We here describe the MetaNetwork protocol to reconstruct metabolic networks using metabolite abundance data from segregating populations. MetaNetwork maps metabolite quantitative trait loci (mQTLs) underlying variation in metabolite abundance in individuals of a segregating population using a

  1. MetaNetwork: a computational protocol for the genetic study of metabolic networks

    NARCIS (Netherlands)

    Fu, J.; Swertz, M.A.; Keurentjes, J.J.B.; Jansen, R.C.

    2007-01-01

    We here describe the MetaNetwork protocol to reconstruct metabolic networks using metabolite abundance data from segregating populations. MetaNetwork maps metabolite quantitative trait loci (mQTLs) underlying variation in metabolite abundance in individuals of a segregating population using a

  2. A study of structural properties of gene network graphs for mathematical modeling of integrated mosaic gene networks.

    Science.gov (United States)

    Petrovskaya, Olga V; Petrovskiy, Evgeny D; Lavrik, Inna N; Ivanisenko, Vladimir A

    2017-04-01

    Gene network modeling is one of the widely used approaches in systems biology. It allows for the study of complex genetic systems function, including so-called mosaic gene networks, which consist of functionally interacting subnetworks. We conducted a study of a mosaic gene networks modeling method based on integration of models of gene subnetworks by linear control functionals. An automatic modeling of 10,000 synthetic mosaic gene regulatory networks was carried out using computer experiments on gene knockdowns/knockouts. Structural analysis of graphs of generated mosaic gene regulatory networks has revealed that the most important factor for building accurate integrated mathematical models, among those analyzed in the study, is data on expression of genes corresponding to the vertices with high properties of centrality.

  3. Computational and experimental studies on stabilities, reactions and reaction rates of cations and ion-dipole complexes

    NARCIS (Netherlands)

    Ervasti, H.K.

    2008-01-01

    In this thesis, ion stability, ion-molecule reactions and reaction rates are studied using mass spectrometry and molecular modelling. In Chapter 2 the effect of functional group substitution on neutral and ionised ketene are studied. Electron-donating substituents show a stabilising positive

  4. Study of electron transport across the magnetic filter of NIO1 negative ion source

    Science.gov (United States)

    Veltri, P.; Sartori, E.; Cavenago, M.; Serianni, G.; Barbisan, M.; Zaniol, B.

    2017-08-01

    In the framework of the accompanying activities in support to the ITER NBI test facility, a relatively compact radiofrequency (RF) ion source, named NIO1 (Negative Ion Optimization, phase 1) was developed in Padua, Italy, in collaboration between Consorzio RFX and INFN. Negative hydrogen ions are formed in a cold, inductively coupled plasma with a 2MHz, 2.5 kW external antenna. A low electron energy is necessary to increase the survival probability of negative ions in the proximity of the extraction area. This goal is accomplished by means of a transversal magnetic field, confining the high energy electrons better than the colder electrons. In NIO1, this filter field can cover different topologies, exploiting different set of magnets and high current paths. In this contribution we study the property of the plasma in the vicinity of the extraction region for two different B field configurations. For this experiment the source was operated in pure volume conditions, in hydrogen and oxygen plasmas. The experimental data, measured by spectroscopic means, is interpreted also with the support of finite element analyses simulations of the magnetic field and a dedicated particle in cell (PIC) numerical model for the electron transport across it, including Coulomb and gas collisions.

  5. Characteristics of ion distribution functions in dipolarizing flux bundles: Event studies

    Science.gov (United States)

    Runov, A.; Angelopoulos, V.; Artemyev, A.; Birn, J.; Pritchett, P. L.; Zhou, X.-Z.

    2017-06-01

    Taking advantage of multipoint observations from a repeating configuration of the five Time History of Events and Macroscale Interactions during Substorms (THEMIS) probes separated by 1 to 2 Earth radii (RE) along X, Y, and Z in the geocentric solar magnetospheric system (GSM), we study ion distribution functions collected by the probes during three dipolarizing flux bundle (DFB) events observed at geocentric distances 9 GSM directions and |Bx| levels, which characterize the distance from the neutral sheet. We found that the characteristics of the ion distribution functions strongly depended on the |Bx| level, whereas changes with respect to X and Y were minor. In all three events, ion distribution functions f(v) observed inside DFBs were organized by magnetic and electric fields. The probes near the magnetic equator observed perpendicular anisotropy of the phase space density in the range between thermal energy and twice the thermal energy, although the distribution in the ambient plasma sheet was isotropic. The anisotropic ion distribution in DFBs injected toward the inner magnetosphere may provide the free energy for waves and instabilities, which are important elements of particle energization.

  6. Complexation Enhancement Drives Water-to-Oil Ion Transport: A Simulation Study

    Energy Technology Data Exchange (ETDEWEB)

    Qiao, Baofu [Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne Illinois 60439 USA; Ferru, Geoffroy [Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne Illinois 60439 USA; Ellis, Ross J. [Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne Illinois 60439 USA; Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge Tennessee 37831 USA

    2016-11-23

    We address the structures and energetics of ion solvation in aqueous and organic solutions to understand liquid-liquid ion transport. Atomistic molecular dynamics (MD) simulations with polarizable force field are performed to study the coordination transformations driving lanthanide (Ln(III)) and nitrate ion transport between aqueous and an alkylamide-oil solution. An enhancement of the coordination behavior in the organic phase is achieved in contrast with the aqueous solution. In particular, the coordination number of Ce3+ increases from 8.9 in the aqueous to 9.9 in the organic solutions (from 8 in the aqueous to 8.8 in the organic systems for Yb3+). Moreover, the local coordination environ ment changes dramatically. Potential of mean force calculations show that the Ln(III)-ligand coordination interaction strengths follow the order of Ln(III-)nitrate> Ln(III)-water>Ln(III)-DMDBTDMA. They increase 2-fold in the lipophilic environment in comparison to the aqueous phase, and we attribute this to the shedding of the outer solvation shell. Our findings highlight the importance of outer sphere interactions on the competitive solvation energetics that cause ions to migrate between immiscible phases; an essential ingredient for advancing important applications such as rare earth metal separations. Some open questions in simulating the coordination behavior of heavy metals are also addressed.

  7. Identification of specific sensory neuron populations for study of expressed ion channels.

    Science.gov (United States)

    Ramachandra, Renuka; McGrew, Stephanie; Elmslie, Keith

    2013-12-24

    Sensory neurons transmit signals from various parts of the body to the central nervous system. The soma for these neurons are located in the dorsal root ganglia that line the spinal column. Understanding the receptors and channels expressed by these sensory afferent neurons could lead to novel therapies for disease. The initial step is to identify the specific subset of sensory neurons of interest. Here we describe a method to identify afferent neurons innervating the muscles by retrograde labeling using a fluorescent dye DiI (1,1'-dioctadecyl-3,3,3',3'-tetramethylindocarbocyanine perchlorate). Understanding the contribution of ion channels to excitation of muscle afferents could help to better control excessive excitability induced by certain disease states such as peripheral vascular disease or heart failure. We used two approaches to identify the voltage dependent ion channels expressed by these neurons, patch clamp electrophysiology and immunocytochemistry. While electrophysiology plus pharmacological blockers can identify functional ion channel types, we used immunocytochemistry to identify channels for which specific blockers were unavailable and to better understand the ion channel distribution pattern in the cell population. These techniques can be applied to other areas of the nervous system to study specific neuronal groups.

  8. Simulation study of a rectifying bipolar ion channel: Detailed model versus reduced model

    Directory of Open Access Journals (Sweden)

    Z. Ható

    2016-02-01

    Full Text Available We study a rectifying mutant of the OmpF porin ion channel using both all-atom and reduced models. The mutant was created by Miedema et al. [Nano Lett., 2007, 7, 2886] on the basis of the NP semiconductor diode, in which an NP junction is formed. The mutant contains a pore region with positive amino acids on the left-hand side and negative amino acids on the right-hand side. Experiments show that this mutant rectifies. Although we do not know the structure of this mutant, we can build an all-atom model for it on the basis of the structure of the wild type channel. Interestingly, molecular dynamics simulations for this all-atom model do not produce rectification. A reduced model that contains only the important degrees of freedom (the positive and negative amino acids and free ions in an implicit solvent, on the other hand, exhibits rectification. Our calculations for the reduced model (using the Nernst-Planck equation coupled to Local Equilibrium Monte Carlo simulations reveal a rectification mechanism that is different from that seen for semiconductor diodes. The basic reason is that the ions are different in nature from electrons and holes (they do not recombine. We provide explanations for the failure of the all-atom model including the effect of all the other atoms in the system as a noise that inhibits the response of ions (that would be necessary for rectification to the polarizing external field.

  9. Monte Carlo studies of the interaction of relativistic ions with nuclear emulsion

    Energy Technology Data Exchange (ETDEWEB)

    Hashemi-Nezhad, S.R., E-mail: reza@physics.usyd.edu.au [School of Physics, A28, University of Sydney, NSW 2006 (Australia); Brandt, R. [Kernchemie, Fachbereich Chemie, Philipps-Universität, 35043 Marburg (Germany); Ditlov, V.A. [Alikhanov Institute of Theoretical and Experimental Physics, Moscow (Russian Federation); Firu, E. [Bucharest Institute of Space Sciences, Bucharest (Romania); Ganssauge, E. [Fachbereich Physik, Philipps-Universität, Marburg (Germany); Haiduc, M.; Neagu, A.T. [Bucharest Institute of Space Sciences, Bucharest (Romania); Westmeier, W. [Kernchemie, Fachbereich Chemie, Philipps-Universität, 35043 Marburg (Germany); Dr. Westmeier GmbH, 35085 Ebsdorfergrund (Germany)

    2017-01-01

    Interaction of high energy heavy ions with nuclear emulsion simulated using MCNPX 2.7 and its associated Monte Carlo codes. The simulations were performed for interactions of 4.1 AGeV/c {sup 22}Ne ions with nuclear emulsion event by event via batch files written for this purpose. It is shown that MCNPX correctly simulates the spallation as well as “complete destruction” interactions using the same physics principles and models. Cross-sections for interaction of 4.1 AGeV/c {sup 22}Ne ions with emulsion, Ag and Br in emulsion and rest of the nuclei in the emulsion were determined. Good agreements between calculations and experimental results were obtained. - Highlights: • Interaction of 4.1 A GeV/c {sup 22}Ne ions with Ilford G5 nuclear emulsion studies using MCNPX 2.7 Monte Carlo code. • Procedures for simulations of the intaractions event by event have been described. • Spallation and “total destruction” events in the emulsion were investigated. • MC predictions are in good agreement with experimental findings.

  10. Sustained release of antibiotic complexed by multivalent ion: in vitro and in vivo study for the treatment of peritonitis.

    Science.gov (United States)

    Na, Seung Yeon; Oh, Se Heang; Kim, Tae Ho; Yoon, Jin A; Lee, In Soo; Lee, Jin Ho

    2014-12-10

    The main aims of this study are (i) the development of an antibiotic complexed with multivalent ion, which can allow sustained release of the antibiotic without any additional matrix or difficult process and (ii) the feasibility study of the ion-complexed antibiotic as a therapeutic technique for peritonitis treatment. An ion-complexed antibiotic is prepared by simple mixing of two aqueous solutions containing an ionized (water-soluble) drug (tetracycline) and a multivalent counter ionic compound. The ion-complexed antibiotic shows a continuous release of the antibiotic up to 21 days, and thus prolonged anti-bacterial effect by gradual ionic exchange between the multivalent ions in the complex and same-charged monovalent ions in surrounding medium. From the in vivo animal study using a cecum perforated peritonitis mouse model, the ion-complexed antibiotic group shows sufficient anti-bacterial effect and thus effectively treat the peritonitis because of the extermination of the contaminated enteric bacteria in the peritoneum during wound healing of injury cecum (by the sustained release of antibiotic from the ion complex). These results suggest that the ion-complexed antibiotic system may be promising for the effective treatment of the peritonitis caused by frequent gastrointestinal defect in clinical fields. Copyright © 2014 Elsevier B.V. All rights reserved.

  11. DFT study of the interaction between DOTA chelator and competitive alkali metal ions.

    Science.gov (United States)

    Frimpong, E; Skelton, A A; Honarparvar, B

    2017-09-01

    1, 4, 7, 10-tetraazacyclododecane-1, 4, 7, 10-tetracetic acid (DOTA) is an important chelator for radiolabeling of pharmaceuticals. The ability of alkali metals found in the body to complex with DOTA and compete with radio metal ions can alter the radiolabeling process. Non-covalent interactions between DOTA complexed with alkali metals Li + , Na + , K + and Rb + , are investigated with density functional theory using B3LYP and ωB97XD functionals. Conformational possibilities of DOTA were explored with a varying number of carboxylic pendant arms of DOTA in close proximity to the ions. It is found that the case in which four arms of DOTA are interacting with ions is more stable than other conformations. The objective of this study is to explore the electronic structure properties upon complexation of alkali metals Li + Na + , K + and Rb + with a DOTA chelator. Interaction energies, relaxation energies, entropies, Gibbs free energies and enthalpies show that the stability of DOTA, complexed with alkali metals decreases down the group of the periodic table. Implicit water solvation affects the complexation of DOTA-ions leading to decreases in the stability of the complexes. NBO analysis through the natural population charges and the second order perturbation theory, revealed a charge transfer between DOTA and alkali metals. Conceptual DFT-based properties such as HOMO/LUMO energies, ΔE HOMO-LUMO and chemical hardness and softness indicated a decrease in the chemical stability of DOTA-alkali metal complexes down the alkali metal series. This study serves as a guide to researchers in the field of organometallic chelators, particularly, radiopharmaceuticals in finding the efficient optimal match between chelators and various metal ions. Copyright © 2017 Elsevier Inc. All rights reserved.

  12. Interaction of different metal ions with carboxylic acid group: a quantitative study.

    Science.gov (United States)

    Bala, Tanushree; Prasad, B L V; Sastry, Murali; Kahaly, Mousumi Upadhyay; Waghmare, Umesh V

    2007-07-19

    The binding strength of the carboxylic acid group (-COOH) with different divalent metal ions displays considerable variation in arachidic acid (AA) thin films. It is considered that in AA thin films the metal ions straddle the hydrophilic regions of the stacked bilayers of AA molecules via formation of carboxylates. In this study first the uptake of different divalent cations in films of AA is estimated by atomic absorption spectroscopy (AAS). Through the amount of cation uptake, it is found that the strength of binding of different cations varies as Ca2+>Co2+>Pb2+>Cd2+. Variation in the binding strength of different ions is also manifested in experiments where AA thin films are exposed to metal ion mixtures. The higher binding strength of AA with certain metal ions when exposed individually, as well as the preference over the other metal ions when exposed to mixtures, reveal some interesting deviation from the expected behavior based on considerations of ionic radii. For example, Pb2+ is always found to bind to AA much more strongly than Cd2+ even though the latter has smaller ionic radius, indicating that other factors also play an important role in governing the binding strength trends apart from the effects of ionic radii. Then, to get a more meaningful knowledge regarding the binding capability, first-principles calculations based on density functional theory have been applied to study the interaction of different cations with the simplest carboxylic acid, acetic acid, that can result in formation of metal diacetates. Their electronic and molecular structures, cohesive energies, and stiffness of the local potential energy well at the cation (M) site are determined and attempts are made to understand the diversity in geometry and the properties of binding of different metal ions with -COOH group. We find that the calculated M-O bond energies depend sensitively on the chemistry of M atom and follow the experimentally observed trends quite accurately. The trends

  13. [Study on effect of seed vigor and agronomic characters of Cassia seeds implanted with low energy nitrogen ion beans].

    Science.gov (United States)

    Song, Mei; Wang, Xiang-Yang

    2012-07-01

    To study the effect of low energy nitrogen ion implantation on seed germination and agronomic characters. Different doses of low energy nitrogen ion implantation were implanted into fresh Cassia seed embryos. Seed germination, seedling growth and field agronomic characters were observed. The seeds after ion implantation showed significant reduction in germination energy, germination percentage and germination index, besides the significant decreasement in root length, fresh weight and vigor index of seedling. Plant height decreased despite the increase in grain size and grain weight. The low energy nitrogen ion implantation have significant effect on Cassia seeds, and being of great significance on Cassia artificial cultivation.

  14. Portable test bench for the studies concerning ion sources and ion beam extraction and focusing systems; Banco de pruebas portatil para el estudio de fuentes de iones y de la extraccion y enfoque del haz de iones

    Energy Technology Data Exchange (ETDEWEB)

    Cordero Lopez, F.

    1961-07-01

    A portable test bench is described, which was designed to check ion sources, ion beam extraction and focusing systems before its use in a 600 KeV Cockcroft-Walton accelerator. The vacuum possibilities of the system are specially analyzed in connection with its particular use. The whole can be considered as a portable accelerator of low energy (50 keV). (Author)

  15. Enhancing ion yields in time-of-flight-secondary ion mass spectrometry: a comparative study of argon and water cluster primary beams.

    Science.gov (United States)

    Sheraz née Rabbani, Sadia; Razo, Irma Berrueta; Kohn, Taylor; Lockyer, Nicholas P; Vickerman, John C

    2015-02-17

    Following from our previous Letter on this topic, this Article reports a detailed study of time-of-flight-secondary ion mass spectrometry (TOF-SIMS) positive ion spectra generated from a set of model biocompounds (arginine, trehalose, DPPC, and angiotensin II) by water cluster primary ion beams in comparison to argon cluster beams over a range of cluster sizes and energies. Sputter yield studies using argon and water beams on arginine and Irganox 1010 have confirmed that the sputter yields using water cluster beams lie on the same universal sputtering curve derived by Seah for argon cluster beams. Thus, increased ion yield using water cluster beams must arise from increased ionization. The spectra and positive ion signals observed using cluster beams in the size range from 1,000 to 10,000 and the energy range 5-20 keV are reported. It is confirmed that water cluster beams enhance proton related ionization over against argon beams to a significant degree such that enhanced detection sensitivities from 1 μm(2) in the region of 100 to 1,000 times relative to static SIMS analysis with Ar2000 cluster beams appear to be accessible. These new studies show that there is an unexpected complexity in the ionization enhancement phenomenon. Whereas optimum ion yields under argon cluster bombardment occur in the region of E/n ≥ 10 eV (where E is the beam energy and n the number of argon atoms in the cluster) and fall rapidly when E/n beams, ion yields increase significantly in this E/n regime (where n is the number of water molecules in the cluster) and peak for 20 keV beams at a cluster size of 7,000 or E/n ∼3 eV. This important result is explored further using D2O cluster beams that confirm that in this low E/n regime protonation does originate to a large extent from the water molecules. The results, encouraging in themselves, suggest that for both argon and water cluster beams, higher energy beams, e.g., 40 and 80 keV, would enable larger cluster sizes to be exploited

  16. A simple mechanical system for studying adaptive oscillatory neural networks

    DEFF Research Database (Denmark)

    Jouffroy, Guillaume; Jouffroy, Jerome

    model, etc.) might be too complex to study. In this paper, we use a comparatively simple mechanical system, the nonholonomic vehicle referred to as the Roller-Racer, as a means towards testing different learning strategies for an Recurrent Neural Network-based (RNN) controller/guidance system. After...... a brief description of the Roller-Racer, we present as a preliminary study an RNN-based feed-forward controller whose parameters are obtained through the well-known teacher forcing learning algorithm, extended to learn signals with a continuous component....

  17. Silkworm eggs: An ideal model for studying the biological effects of low energy Ar{sup +} ion interaction in animals

    Energy Technology Data Exchange (ETDEWEB)

    Ling Lin; Liu Xuelan [School of Life Sciences, Anhui Agricultural University, Hefei 230031 (China); Xu Jiaping, E-mail: jiapingxu@163.com [School of Life Sciences, Anhui Agricultural University, Hefei 230031 (China); You Zhengying; Zhou Jingbo [School of Life Sciences, Anhui Agricultural University, Hefei 230031 (China)

    2011-09-15

    Highlights: {yields} Low energy Ar{sup +} ion beam interactions with silkworm eggs. {yields} Ion beam bombardment as a novel method for gene transfer in silkworm. {yields} Provide evidence for studying the mechanisms of ion beam interaction in animals. - Abstract: The object of the current work was to study low energy Ar{sup +} ion beam interactions with silkworm eggs and thus provide further understanding of the mechanisms involved in ion bombardment-induced direct gene transfer into silkworm eggs. In this paper, using low-energy Ar{sup +} ion beam bombardment combined with piggyBac transposon, we developed a novel method to induce gene transfer in silkworm. Using bombardment conditions optimized for egg-incubation (25 keV with ion fluences of 800 x 2.6 x 10{sup 15} ions/cm{sup 2} in dry state under vacuum), vector pBac{l_brace}3 x P3-EGFPaf{r_brace} and helper plasmid pHA3pig were successfully transferred into the silkworm eggs. Our results obtained from by PCR assay and genomic Southern blotting analysis of the G1 generations provide evidence that low-energy ion beam can generate some craters that play a role in acting as pathways of exogenous DNA molecules into silkworm eggs.

  18. [Study of scintillating luminescence spectra of lead tungstate scintillation crystal doped with ions].

    Science.gov (United States)

    Wan, You-bao; Wu, Yu-rong; Zhang, Jian-xin; Yang, Pei-zhi; Xiao, Lin-rong; Yang, Hui

    2009-09-01

    The light yield of the as-grown PbWO4, annealed PbWO4 and BaF2:PbWO4 crystals were raised by utilizing our improved crystal growth instrument and technique. Their scintillating properties including transmittance, decay time and light yield were studied. Results reveal that the scintillating performances of the crystals were improved evidently by using the crystal annealing technique and the ions doping technique, especially the negative ions doping technique. The influence results of the two techniques are different. The ions doping technique raises their transmittance intensity in the whole measuring wavelength range. But the influence of annealing PbWO4 crystal on their transmittance is complicated. It improves its transmittance intensity at the wavelength above 360 nm, but weakens the transmittance intensity of the annealed PbWO4 crystal in the wavelength range from 320 to 360 nm. These phenomena should be related to the crystal defects which have absorption peaks in this wavelength range, especially for V(Pb)3+ defect which has characterized absorption peaks in this wavelength range. Also, the absorption of the defects influences the character of the decay time of these crystals. The big defect concentration relates to the short decay time. It should be mentioned that the ions doping technique reduces the defect content in the crystal, which is beneficial to the high transmittance intensity but induces slightly longer decay time than that of as-grown crystal and well annealed PbWO4 crystal. Also, the ions doping technique of the F- ion doped crystal leads to high light yield. The annealing technique and ions doping technique improve the light yield of crystals. The light yield of BaF2:PbWO4 reaches 65 p.e./MeV, which is near to the requirement of PET. The good result is related to the degeneration of the [WO4]2- tetrahedron induced by the F- occupying the O2- site in the crystal cell.

  19. Compositional and structural studies of ion-beam modified AlN/TiN multilayers

    Science.gov (United States)

    Amati, M.; Gregoratti, L.; Sezen, H.; Grce, A.; Milosavljević, M.; Homewood, K. P.

    2017-07-01

    This paper reports on compositional and structural modifications induced in coated AlN/TiN multilayers by argon ion irradiation. The initial structure consisting of totally 30 alternate AlN (8 nm thick) and TiN (9.3 nm thick) layers was deposited on Si (100) wafers, by reactive sputtering. Irradiation was done with 180 keV Ar+ to a high dose of 8 × 1016 ions/cm2, which introduces up to ∼10 at.% of argon species, and generates a maximum displacement per atom of 92 for AlN and 127 for TiN, around the projected ion range (109 ± 34 nm). Characterizations were performed by Rutherford backscattering spectrometry, spatially resolved x-ray photoelectron spectroscopy, and transmission electron microscopy. The obtained results reveal that this highly immiscible and thermally stable system suffered a severe modification upon the applied ion irradiation, although it was performed at room temperature. They illustrate a thorough inter-layer mixing, atomic redistribution, structural change and phase transformation within the affected depth. The original TiN layers appear to grow in thickness, consuming the adjacent AlN layers, while retaining the fcc crystalline structure. In the mostly affected region, the interaction proceeds until all of the original AlN layers are consumed. Compositional studies with photoemission spectroscopy show that due to the ion irradiation treatment the TiN and AlN layers are transformed into Ti0.75Al0.25N and Ti0.65Al0.35N ternary compounds characterized by a better homogenized chemical form compared to non-irradiated layers. The results can be interesting towards further development of radiation tolerant materials based on immiscible ceramic nanocomposites.

  20. CompTIA Network+ Certification Study Guide, Exam N10-004

    CERN Document Server

    Shimonski, Robert

    2009-01-01

    CompTIA's Network+ certification is a globally-recognized, vendor neutral exam that has helped over 235,000 IT professionals reach further and higher in their careers. The 2009 Network+ exam (N10-004) is a major update with more focus on security and wireless aspects of networking. Our new study guide has been updated accordingly with focus on network, systems, and WAN security and complete coverage of today's wireless networking standards. As always this companion covers the core Network+ material including basic design principles, management and operation of a network infrastructure, and tes

  1. Functional alignment of regulatory networks: a study of temperate phages.

    Directory of Open Access Journals (Sweden)

    Ala Trusina

    2005-12-01

    Full Text Available The relationship between the design and functionality of molecular networks is now a key issue in biology. Comparison of regulatory networks performing similar tasks can provide insights into how network architecture is constrained by the functions it directs. Here, we discuss methods of network comparison based on network architecture and signaling logic. Introducing local and global signaling scores for the difference between two networks, we quantify similarities between evolutionarily closely and distantly related bacteriophages. Despite the large evolutionary separation between phage lambda and 186, their networks are found to be similar when difference is measured in terms of global signaling. We finally discuss how network alignment can be used to pinpoint protein similarities viewed from the network perspective.

  2. Study of Vivaldi Algorithm in Energy Constraint Networks

    Directory of Open Access Journals (Sweden)

    Tomas Handl

    2011-01-01

    Full Text Available The presented paper discusses a viability of Vivaldi localization algorithm and synthetic coordinate system in general to be used for localization purposes in energy constraint networks. Synthetic coordinate systems achieve good results in IP based networks and thus, it could be a perspective way of node localization in other types of networks. However, transfer of Vivaldi algorithm into a different kind of network is a difficult task because the different basic characteristic of the network and network nodes. In this paper we focus on the different aspects of IP based networks and networks of wireless sensors which suffer from strict energy limitation. During our work we proposed a modified version of two dimensional Vivaldi localization algorithm with height system and developed a simulator tool for initial investigation of its function in ad-hoc energy constraint networks.

  3. Beam dynamics design studies of a superconducting radioactive ion beam postaccelerator

    CERN Document Server

    Fraser, M A; Jones, R M

    2011-01-01

    The HIE-ISOLDE project at CERN proposes a superconducting upgrade to increase the energy range and quality of the radioactive ion beams produced at ISOLDE, which are currently postaccelerated by the normal conducting radioactive ion beam experiment linac. The specification and design choices for the HIE-ISOLDE linac are outlined along with a comprehensive beam dynamics study undertaken to understand and mitigate the sources of beam emittance dilution. The dominant cause of transverse emittance growth was attributed to the coupling between the transverse and longitudinal motions through the phase dependence of the rf defocusing force in the accelerating cavities. A parametric resonance induced by the coupling was observed and its excitation surveyed as a function of transverse phase advance using numerical simulations and analytic models to understand and avoid the regions of transverse beam instability. Other sources of emittance growth were studied and where necessary ameliorated, including the beam steering...

  4. BEAM DYNAMICS STUDIES FOR A COMPACT CARBON ION LINAC FOR THERAPY

    Energy Technology Data Exchange (ETDEWEB)

    Plastun, A.; Mustapha, B.; Nassiri, A.; Ostroumov, P.

    2016-05-01

    Feasibility of an Advanced Compact Carbon Ion Linac (ACCIL) for hadron therapy is being studied at Argonne National Laboratory in collaboration with RadiaBeam Technologies. The 45-meter long linac is designed to deliver 109 carbon ions per second with variable energy from 45 MeV/u to 450 MeV/u. S-band structure provides the acceleration in this range. The carbon beam energy can be adjusted from pulse to pulse, making 3D tumor scanning straightforward and fast. Front end accelerating structures such as RFQ, DTL and coupled DTL are designed to operate at lower frequencies. The design of the linac was accompanied with extensive end-to-end beam dynamics studies which are presented in this paper.

  5. LOCAL AREA NETWORK MANAGEMENT (Case Study at Assessment and Development Information Technology Units Brawijaya University Malang)

    OpenAIRE

    Hadiwijaya, Mohammad Firman

    2015-01-01

    The purpose of this study was to know the management local area network at Assessment and Development Information Technology units, furthermore this study focusing on network management functions that applied by Assessment and Development Information Technology Units. This study will explain about the implementation of network management functions in the local area network management. The research method employ in this research is by using descriptive qualitative method by study case approach...

  6. Page 1 i Studies on ionic transport properties of a new Ag" ion ...

    Indian Academy of Sciences (India)

    Studies on ionic transport properties of a new Ag" ion conductor 577. 2. O. Blocking Reversing. Battery elºgues key l. 5. 1. 2. Records f. Temperature ~300 K. O 0.2 0.4 0.6 0.8 1 5 15 25 35 i;5. Time (sec) —”. Figure 4. Transient ionic current vs time plot for ionic mobility measurement of the optimum conducting composition ...

  7. Studies of the QCD Phase Diagram with Heavy-Ion Collisions at J-PARC

    Science.gov (United States)

    Sako, Hiroyuki

    To clarify phase structures in the QCD phase diagram is an ultimate goal of heavy-ion collision experiments. Studies of internal structures of neutron stars are also one of the most important topics of nuclear physics since the discovery of neutron stars with two-solar mass. For these physics goals, J-PARC heavy-ion project (J-PARC-HI) has been proposed, where extremely dense matter with 5-10 times the normal nuclear density will be created. Heavy-ion beams up to Uranium will be accelerated to 1-19 AGeV/c, with the designed world's highest beam rate of 1011 Hz. The acceleration of such high-rate beams can be realized by a new heavy-ion linac and a new booster ring, in addition to the existing 3-GeV and 50-GeV proton synchrotrons. To study the above physics goals, following physics observables will be measured in extremely high statistics expected in J-PARC-HI. To search for the critical point, high-order event-by-event fluctuations of conserved charges such as a net-baryon number, an electric charge number, and a strangeness number will be measured. To study the chiral symmetry restoration, dilepton spectra from light vector meson decays will be measured. Also, collective flows, particle correlations will be measured to study the equation of state and hyperon-hyperon and hyperon-nucleon interactions related to neutron stars. Strange quark matter (strangelet) and multi-strangeness hypernuclei will be searched for which may be related directly to the matter constituting the neutron star core. In this work, the physics goals, the experimental design, and expected physics results of J-PARC-HI will be discussed.

  8. Cellulose Aerogel Membranes with a Tunable Nanoporous Network as a Matrix of Gel Polymer Electrolytes for Safer Lithium-Ion Batteries.

    Science.gov (United States)

    Wan, Jiqiang; Zhang, Jinming; Yu, Jian; Zhang, Jun

    2017-07-26

    Cellulose aerogel membranes (CAMs) are proposed as a matrix for gel polymer electrolyte to the fabrication of lithium-ion batteries (LIBs) with superior thermal stability. The CAMs are obtained from a cellulose-ionic liquid solution via a dissolution-regeneration-supercritical drying route. The presence of high porosity, the nanoporous network structure, and numerous polar hydroxyl groups benefits the quick absorption of liquid electrolytes for gelation of the CAMs and improves the ionic conductivity of the gelled CAMs. LIBs assembled with the gelled CAMs display excellent electrochemical performance at room temperature, and more importantly, the intrinsic thermal resistance of cellulose allows the LIBs to run stably for at least 30 min at working temperatures as high as 120 °C. The CAMs, with their excellent thermal stability, are promising for the development of highly safe, cost-effective, and high-performance LIBs.

  9. Studies on the Effect pH on the Sorption of Pb(II) and Cu(II) ions from ...

    African Journals Online (AJOL)

    The effect of pH on the sorption of Pb2+ and Cu2+ ion onto Nypa fruticans Wurmb biomass was investigated. Initial pH value of 2, 5, 7, 9, and 12 were used for this study with varying initial concentrations of metal ions. The experimental results were analyzed in terms of Langmuir, Freundlich and Flory-Huggins isotherms.

  10. Qualitative and quantitative study on drainage networks at laboratory scale

    Science.gov (United States)

    Oliveto, G.; Palma, D.; di Domenico, A.

    2009-04-01

    Although simulated drainage networks at the laboratory scale would represent highly-simplified models of natural drainages, they would provide a significant contribute to the comprehension of the complex dynamics governing the fluvial systems. Laboratory experiments also give the advantage to detect transient growth phases shedding some light on the knowledge of temporal and spatial landform evolution. Perhaps, pioneering laboratory experiments on drainage network evolution were carried out in 1977 at REF (Rainfall Erosion Facility) of Colorado State University by Schumm and co-workers. This study deals with an analysis of physical experiments simulating the evolution and the development of drainage networks. To this purpose, some experiments were carried out at University of Basilicata by using a 1.5 m by 1.5 m box-basin-simulator with an outlet incised in the middle of the downslope-end side. The experimental landscape was made of a weakly cohesive soil mainly constituted by clay and silt. A system of microsprinklers generated an almost uniform artificial precipitation. Simulations were performed at a constant rainfall rate with intensity of 100 mm/h. In total four experiments were carried out. Three of those were conducted by ensuring consistent initial conditions except for the initial landscape planar slope of 9%, 5%, and 0.6%, respectively. The remaining experiment was performed with a landscape slope of 9% again, but with the (surface) base-level coinciding with the base of the outlet (i.e. streams could not erode below the base-level). Despite the central outlet constraint, the generated stream system for the 9% plane exhibited trellis-like drainage patterns with many short tributaries joining the main stream at nearly right angles. For the 5% experiment still sub-parallel drainage patterns were formed but mainly in the centre of the watershed. Channels were clearly shallower than those of the 9% experiment. For the gentler slope of 0.6% dendritic drainage

  11. Brain Networks Responsible for Sense of Agency: An EEG Study.

    Directory of Open Access Journals (Sweden)

    Suk Yun Kang

    Full Text Available Self-agency (SA is a person's feeling that his action was generated by himself. The neural substrates of SA have been investigated in many neuroimaging studies, but the functional connectivity of identified regions has rarely been investigated. The goal of this study is to investigate the neural network related to SA.SA of hand movements was modulated with virtual reality. We examined the cortical network relating to SA modulation with electroencephalography (EEG power spectrum and phase coherence of alpha, beta, and gamma frequency bands in 16 right-handed, healthy volunteers.In the alpha band, significant relative power changes and phase coherence of alpha band were associated with SA modulation. The relative power decrease over the central, bilateral parietal, and right temporal regions (C4, Pz, P3, P4, T6 became larger as participants more effectively controlled the virtual hand movements. The phase coherence of the alpha band within frontal areas (F7-FP2, F7-Fz was directly related to changes in SA. The functional connectivity was lower as the participants felt that they could control their virtual hand. In the other frequency bands, significant phase coherences were observed in the frontal (or central to parietal, temporal, and occipital regions during SA modulation (Fz-O1, F3-O1, Cz-O1, C3-T4L in beta band; FP1-T6, FP1-O2, F7-T4L, F8-Cz in gamma band.Our study suggests that alpha band activity may be the main neural oscillation of SA, which suggests that the neural network within the anterior frontal area may be important in the generation of SA.

  12. Brain Networks Responsible for Sense of Agency: An EEG Study.

    Science.gov (United States)

    Kang, Suk Yun; Im, Chang-Hwan; Shim, Miseon; Nahab, Fatta B; Park, Jihye; Kim, Do-Won; Kakareka, John; Miletta, Nathanial; Hallett, Mark

    2015-01-01

    Self-agency (SA) is a person's feeling that his action was generated by himself. The neural substrates of SA have been investigated in many neuroimaging studies, but the functional connectivity of identified regions has rarely been investigated. The goal of this study is to investigate the neural network related to SA. SA of hand movements was modulated with virtual reality. We examined the cortical network relating to SA modulation with electroencephalography (EEG) power spectrum and phase coherence of alpha, beta, and gamma frequency bands in 16 right-handed, healthy volunteers. In the alpha band, significant relative power changes and phase coherence of alpha band were associated with SA modulation. The relative power decrease over the central, bilateral parietal, and right temporal regions (C4, Pz, P3, P4, T6) became larger as participants more effectively controlled the virtual hand movements. The phase coherence of the alpha band within frontal areas (F7-FP2, F7-Fz) was directly related to changes in SA. The functional connectivity was lower as the participants felt that they could control their virtual hand. In the other frequency bands, significant phase coherences were observed in the frontal (or central) to parietal, temporal, and occipital regions during SA modulation (Fz-O1, F3-O1, Cz-O1, C3-T4L in beta band; FP1-T6, FP1-O2, F7-T4L, F8-Cz in gamma band). Our study suggests that alpha band activity may be the main neural oscillation of SA, which suggests that the neural network within the anterior frontal area may be important in the generation of SA.

  13. Electrokinetic migration studies on removal of chromium and uranyl ions from 904-A trench soil

    Energy Technology Data Exchange (ETDEWEB)

    Bibler, J.P.; Meaker, T.F.; O`Steen, A.B.

    1992-09-30

    This report describes a laboratory-scale study, in which electrokinetic migration technology was used to remove chromium and uranium, as well as other ions, from soil taken from a bore hole adjacent to the 904-A trench at the Savannah River Technology Center. Imposition of an electric current on humid (not saturated) soil successfully caused cations to migrate through the pore water of the soil to the cathode, where they were captured in an ISOLOCKTm polymer matrix and in a cation exchange resin incorporated in the polymer. Chemicals circulated through the anode/polymer and cathode/polymer were able to control pH excursions in the electrokinetic-cells by reacting with the H{sup +} and OH{sup {minus}} generated at the anode and cathode, respectively. The study indicates that ions adsorbed on the surface of the soil as well as those in the pores of soil particles can be caused to migrate through the soil to an appropriate electrode. After 10 days of operation at 20--25 V and 2 mA, approximately 65% of the chromium was removed from two 3.5 kg soil samples. A 57% removal of uranium was achieved. The study shows that electrokinetic migration, using the ISOLOCK{trademark} polymer will be effective as an in situ treatment method for the removal of metal ion contaminants in soil adjacent to the 904-A trench.

  14. Li-Ion Pouch Cells for Vehicle Applications — Studies of Water Transmission and Packing Materials

    Directory of Open Access Journals (Sweden)

    Göran Flodberg

    2013-01-01

    Full Text Available This study includes analysis of encapsulation materials from lithium-ion pouch cells and water vapour transmission rate (WVTR measurements. WVTR measurements are performed on both fresh and environmentally stressed lithium-ion pouch cells. Capacity measurements are performed on both the fresh and the environmentally stressed battery cells to identify possible influences on electrochemical performance. Preparation of the battery cells prior to WVTR measurements includes opening of battery cells and extraction of electrode material, followed by resealing the encapsulations and adhesively mounting of gas couplings. A model describing the water diffusion through the thermal welds of the encapsulation are set up based on material analysis of the encapsulation material. Two WVTR equipments with different type of detectors are evaluated in this study. The results from the WVTR measurements show how important it is to perform this type of studies in dry environment and apply a rigorous precondition sequence before testing. Results from modelling confirm that the WVTR method has potential to be used for measurements of water diffusion into lithium-ion pouch cells. Consequently, WVTR measurements should be possible to use as a complement or alternative method to for example Karl Fisher titration.

  15. Networking Course Syllabus in Accredited Library and Information Science Programs: A Comparative Analysis Study

    Science.gov (United States)

    Abouserie, Hossam Eldin Mohamed Refaat

    2009-01-01

    The study investigated networking courses offered in accredited Library and Information Science schools in the United States in 2009. The study analyzed and compared network syllabi according to Course Syllabus Evaluation Rubric to obtain in-depth understanding of basic features and characteristics of networking courses taught. The study embraced…

  16. Studies of extraction and transport system for highly charged ion beam of 18 GHz superconducting electron cyclotron resonance ion source at Research Center for Nuclear Physics.

    Science.gov (United States)

    Yorita, T; Hatanaka, K; Fukuda, M; Ueda, H; Yasuda, Y; Morinobu, S; Tamii, A; Kamakura, K

    2014-02-01

    An 18 GHz superconducting electron cyclotron resonance ion source is installed to increase beam currents and to extend the variety of ions especially for highly charged heavy ions which can be accelerated by cyclotrons of Research Center for Nuclear Physics (RCNP), Osaka University. The beam production developments of several ions from B to Xe have been already done [T. Yorita, K. Hatanaka, M. Fukuda, M. Kibayashi, S. Morinobu, H.Okamura, and A. Tamii, Rev. Sci. Instrum. 79, 02A311 (2008) and T. Yorita, K. Hatanaka, M. Fukuda, M. Kibayashi, S. Morinobu, H.Okamura, and A. Tamii, Rev. Sci. Instrum. 81, 02A332 (2010)] and the further studies for those beam extraction and its transport have been done in order to increase the beam current more. The plasma electrode, extraction electrode, and einzel lens are modified. Especially extraction electrode can be applied minus voltage for the beam extraction and it works well to improve the extracted beam current. The extraction voltage dependences of transmission and emittance also have been studied for beam current improvement which is injected into azimuthally varying field cyclotron at RCNP.

  17. Compositional and structural studies of ion-beam modified AlN/TiN multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Amati, M., E-mail: matteo.amati@elettra.eu [Elettra – Sincrotrone Trieste SCpA,Area Science Park, 34149, Trieste (Italy); Gregoratti, L.; Sezen, H. [Elettra – Sincrotrone Trieste SCpA,Area Science Park, 34149, Trieste (Italy); Grce, A.; Milosavljević, M. [VINČA Institute of Nuclear Sciences, Belgrade University, P.O. Box 522, 11001, Belgrade (Serbia); Homewood, K.P. [Materials Research Institute and School of Physics and Astronomy, Queen Mary University of London, Mile End Road, E1 4NS, London (United Kingdom)

    2017-07-31

    Highlights: • Inter-layer mixing, atomic redistribution, structural change, and phase transformation on AlN/TiN multilayers via argon ion irradiation. • Severe modifications are observed with TEM studies on highly immiscible alternating layers without any side effects such as beam heating. • The original TiN layers appear to grow in thickness by consuming the adjacent AlN layers, while obtaining a better TiAlN fcc crystalline structure. • Photoemission spectroscopy/microscopy indicates a transformation into Al deficient ternary and highly homogeneous compounds on both layers. • These results can be interesting towards further development of radiation tolerant materials based on immiscible ceramic nanocomposites. - Abstract: This paper reports on compositional and structural modifications induced in coated AlN/TiN multilayers by argon ion irradiation. The initial structure consisting of totally 30 alternate AlN (8 nm thick) and TiN (9.3 nm thick) layers was deposited on Si (100) wafers, by reactive sputtering. Irradiation was done with 180 keV Ar{sup +} to a high dose of 8 × 10{sup 16} ions/cm{sup 2}, which introduces up to ∼10 at.% of argon species, and generates a maximum displacement per atom of 92 for AlN and 127 for TiN, around the projected ion range (109 ± 34 nm). Characterizations were performed by Rutherford backscattering spectrometry, spatially resolved x-ray photoelectron spectroscopy, and transmission electron microscopy. The obtained results reveal that this highly immiscible and thermally stable system suffered a severe modification upon the applied ion irradiation, although it was performed at room temperature. They illustrate a thorough inter-layer mixing, atomic redistribution, structural change and phase transformation within the affected depth. The original TiN layers appear to grow in thickness, consuming the adjacent AlN layers, while retaining the fcc crystalline structure. In the mostly affected region, the interaction proceeds

  18. Study of Robustness in Functionally Identical Coupled Networks against Cascading Failures.

    Directory of Open Access Journals (Sweden)

    Xingyuan Wang

    Full Text Available Based on coupled networks, taking node load, capacity and load redistribution between two networks into consideration, we propose functionally identical coupled networks, which consist of two networks connected by interlinks. Functionally identical coupled networks are derived from the power grid of the United States, which consists of many independent grids. Many power transmission lines are planned to interconnect those grids and, therefore, the study of the robustness of functionally identical coupled networks becomes important. In this paper, we find that functionally identical coupled networks are more robust than single networks under random attack. By studying the effect of the broadness and average degree of the degree distribution on the robustness of the network, we find that a broader degree distribution and a higher average degree increase the robustness of functionally identical coupled networks under random failure. And SF-SF (two coupled scale-free networks is more robust than ER-ER (two coupled random networks or SF-ER (coupled random network and scale-free network. This research is useful to construct robust functionally identical coupled networks such as two cooperative power grids.

  19. Study of Robustness in Functionally Identical Coupled Networks against Cascading Failures

    Science.gov (United States)

    Wang, Xingyuan; Cao, Jianye; Qin, Xiaomeng

    2016-01-01

    Based on coupled networks, taking node load, capacity and load redistribution between two networks into consideration, we propose functionally identical coupled networks, which consist of two networks connected by interlinks. Functionally identical coupled networks are derived from the power grid of the United States, which consists of many independent grids. Many power transmission lines are planned to interconnect those grids and, therefore, the study of the robustness of functionally identical coupled networks becomes important. In this paper, we find that functionally identical coupled networks are more robust than single networks under random attack. By studying the effect of the broadness and average degree of the degree distribution on the robustness of the network, we find that a broader degree distribution and a higher average degree increase the robustness of functionally identical coupled networks under random failure. And SF-SF (two coupled scale-free networks) is more robust than ER-ER (two coupled random networks) or SF-ER (coupled random network and scale-free network). This research is useful to construct robust functionally identical coupled networks such as two cooperative power grids. PMID:27494715

  20. Prediction of Thorough QT study results using action potential simulations based on ion channel screens.

    Science.gov (United States)

    Mirams, Gary R; Davies, Mark R; Brough, Stephen J; Bridgland-Taylor, Matthew H; Cui, Yi; Gavaghan, David J; Abi-Gerges, Najah

    2014-01-01

    Detection of drug-induced pro-arrhythmic risk is a primary concern for pharmaceutical companies and regulators. Increased risk is linked to prolongation of the QT interval on the body surface ECG. Recent studies have shown that multiple ion channel interactions can be required to predict changes in ventricular repolarisation and therefore QT intervals. In this study we attempt to predict the result of the human clinical Thorough QT (TQT) study, using multiple ion channel screening which is available early in drug development. Ion current reduction was measured, in the presence of marketed drugs which have had a TQT study, for channels encoded by hERG, CaV1.2, NaV1.5, KCNQ1/MinK, and Kv4.3/KChIP2.2. The screen was performed on two platforms - IonWorks Quattro (all 5 channels, 34 compounds), and IonWorks Barracuda (hERG & CaV1.2, 26 compounds). Concentration-effect curves were fitted to the resulting data, and used to calculate a percentage reduction in each current at a given concentration. Action potential simulations were then performed using the ten Tusscher and Panfilov (2006), Grandi et al. (2010) and O'Hara et al. (2011) human ventricular action potential models, pacing at 1Hz and running to steady state, for a range of concentrations. We compared simulated action potential duration predictions with the QT prolongation observed in the TQT studies. At the estimated concentrations, simulations tended to underestimate any observed QT prolongation. When considering a wider range of concentrations, and conventional patch clamp rather than screening data for hERG, prolongation of ≥5ms was predicted with up to 79% sensitivity and 100% specificity. This study provides a proof-of-principle for the prediction of human TQT study results using data available early in drug development. We highlight a number of areas that need refinement to improve the method's predictive power, but the results suggest that such approaches will provide a useful tool in cardiac safety

  1. On the study of ion-acoustic solitary waves and double-layers in a ...

    Indian Academy of Sciences (India)

    Using the pseudopotential method, theoretical investigation has been made on the first-order Korteweg-deVries ion-acoustic solitons in a multicomponent plasma consisting of warm positive ions, negative ions and isothermal electrons. The effects of electron-inertia and drift motion of the ions on the amplitudes and widths of ...

  2. On the study of ion-acoustic solitary waves and double-layers in a ...

    Indian Academy of Sciences (India)

    Abstract. Using the pseudopotential method, theoretical investigation has been made on the first- order Korteweg-deVries ion-acoustic solitons in a multicomponent plasma consisting of warm pos- itive ions, negative ions and isothermal electrons. The effects of electron-inertia and drift motion of the ions on the amplitudes ...

  3. How Hot are Your Ions Really? A Threshold Collision-Induced Dissociation Study of Substituted Benzylpyridinium "Thermometer" Ions

    Science.gov (United States)

    Carpenter, John E.; McNary, Christopher P.; Furin, April; Sweeney, Andrew F.; Armentrout, P. B.

    2017-09-01

    The first absolute experimental bond dissociation energies (BDEs) for the main heterolytic bond cleavages of four benzylpyridinium "thermometer" ions are measured using threshold collision-induced dissociation in a guided ion beam tandem mass spectrometer. In this experiment, substituted benzylpyridinium ions are introduced into the apparatus using an electrospray ionization source, thermalized, and collided with Xe at varied kinetic energies to determine absolute cross-sections for these reactions. Various effects are accounted for, including kinetic shifts, multiple collisions, and internal and kinetic energy distributions. These experimentally measured 0 K BDEs are compared with computationally predicted values at the B3LYP-GD3BJ, M06-GD3, and MP2(full) levels of theory with a 6-311+G(2d,2p) basis set using vibrational frequencies and geometries determined at the B3LYP/6-311+G(d,p) level. Additional dissociation pathways are observed for nitrobenzylpyridinium experimentally and investigated using these same levels of theory. Experimental BDEs are also compared against values in the literature at the AM1, HF, B3LYP, B3P86, and CCSD(T) levels of theory. Of the calculated values obtained in this work, the MP2(full) level of theory with counterpoise corrections best reproduces the experimental results, as do the similar literature CCSD(T) values. Lastly, the survival yield method is used to determine the characteristic temperature (Tchar) of the electrospray source prior to the thermalization region and to confirm efficient thermalization. [Figure not available: see fulltext.

  4. Studies of endothelial monolayer formation on irradiated poly-L-lactide acid with ions of different stopping power and velocity

    Energy Technology Data Exchange (ETDEWEB)

    Arbeitman, Claudia R. [CONICET – Consejo Nacional de Investigaciones Científicas y Técnicas (Argentina); Gerencia de Investigación y Aplicaciones, TANDAR-CNEA (Argentina); UNQ – IMBICE – CCT – CONICET – LA PLATA (Argentina); Grosso, Mariela F. del [CONICET – Consejo Nacional de Investigaciones Científicas y Técnicas (Argentina); Gerencia de Investigación y Aplicaciones, TANDAR-CNEA (Argentina); Ibañez, Irene L. [CONICET – Consejo Nacional de Investigaciones Científicas y Técnicas (Argentina); Behar, Moni [Instituto de Física, UFRGS, Porto Alegre, RS (Brazil); Grasselli, Mariano [UNQ – IMBICE – CCT – CONICET – LA PLATA (Argentina); Bermúdez, Gerardo García [Gerencia de Investigación y Aplicaciones, TANDAR-CNEA (Argentina)

    2015-12-15

    In this work we study cell viability, proliferation and morphology of bovine aortic endothelial cells (BAEC) cultured on poly-L-lactide acid (PLLA) modified by heavy ion irradiation. In a previous study comparing ions beams with the same stopping power we observed an increase in cell density and a better cell morphology at higher ion velocities. In the present work we continued this study using heavy ions beam with different stopping power and ion velocities. To this end thin films of 50 μm thickness were irradiated with 2 MeV/u and 0.10 MeV/u ion beams provided the Tandar (Buenos Aires, Argentina) and Tandetron (Porto Alegre, Brazil) accelerators, respectively. The results suggest that a more dense and elongated cell shapes, similar to the BAEC cells on the internal surface of bovine aorta, was obtained for stopping power of 18.2–22.1 MeV cm{sup 2} mg{sup −1} and ion velocity of 2 MeV/u. On the other hand, for low ion velocity 0.10 MeV/u the cells present a more globular shapes.

  5. Kinetics and thermodynamics studies of silver ions adsorption onto coconut shell activated carbon.

    Science.gov (United States)

    Silva-Medeiros, Flávia V; Consolin-Filho, Nelson; Xavier de Lima, Mateus; Bazzo, Fernando Previato; Barros, Maria Angélica S D; Bergamasco, Rosângela; Tavares, Célia R G

    2016-12-01

    The presence of silver in the natural water environment has been of great concern because of its toxicity, especially when it is in the free ion form (Ag(+)). This paper aims to study the adsorption kinetics of silver ions from an aqueous solution onto coconut shell activated carbon using batch methods. Batch kinetic data were fitted to the first-order model and the pseudo-second-order model, and this last equation fits correctly the experimental data. Equilibrium experiments were carried out at 30°C, 40°C, and 50°C. The adsorption isotherms were reasonably fit using Langmuir model, and the adsorption process was slightly influenced by changes in temperature. Thermodynamic parameters (ΔH°, ΔG°, and ΔS°) were determined. The adsorption process seems to be non-favorable, exothermic, and have an increase in the orderness.

  6. Nanolesions induced by heavy ions in human tissues: Experimental and theoretical studies

    Directory of Open Access Journals (Sweden)

    Marcus Bleicher

    2012-07-01

    Full Text Available The biological effects of energetic heavy ions are attracting increasing interest for their applications in cancer therapy and protection against space radiation. The cascade of events leading to cell death or late effects starts from stochastic energy deposition on the nanometer scale and the corresponding lesions in biological molecules, primarily DNA. We have developed experimental techniques to visualize DNA nanolesions induced by heavy ions. Nanolesions appear in cells as “streaks” which can be visualized by using different DNA repair markers. We have studied the kinetics of repair of these “streaks” also with respect to the chromatin conformation. Initial steps in the modeling of the energy deposition patterns at the micrometer and nanometer scale were made with MCHIT and TRAX models, respectively.

  7. A kinematic coincidence technique for the study of low-energy heavy-ion reactions

    Energy Technology Data Exchange (ETDEWEB)

    Corradi, L.; Montagnoli, G.; Napoli, D.R.; Spolaore, P.; Stefanini, A.M.; Xu Jincheng (Istituto Nazionale di Fisica Nucleare, Padua (Italy). Lab. di Legnaro); Beghini, S.; Scarlassara, F.; Segato, G.F.; Soramel, F. (Padua Univ. (Italy). Dipt. di Fisica Istituto Nazionale di Fisica Nucleare, Padua (Italy)); Signorini, C. (Salerno Univ. (Italy). Dipt. di Fisica Istituto Nazionale di Fisica Nucleare, Padua (Italy))

    1990-12-10

    A setup for kinematic coincidences has been developed for the study of low-energy binary heavy-ion reactions. It consists of a position-sensitive silicon detector, and a counter telescope with microchannel plates detectors and a conventional {Delta}E-E ionization chamber. The solid angle is around 0.6 msr. By measuring the time of flight of one of the ions, and both correlated scattering angles, we achieve mass and Q-value resolutions of {Delta}A/A{approx equal}1/120 FWHM and {Delta}Q{approx equal}900 keV, respectively, for the elastic scattering of {sup 58}Ni+{sup 64}Ni near the barrier. (orig.).

  8. Imaging and structural studies of DNA–protein complexes and membrane ion channels

    KAUST Repository

    Marini, Monica

    2017-01-17

    In bio-imaging by electron microscopy, damage of the sample and limited contrast are the two main hurdles for reaching high image quality. We extend a new preparation method based on nanofabrication and super-hydrophobicity to the imaging and structural studies of nucleic acids, nucleic acid-protein complexes (DNA/Rad51 repair protein complex) and neuronal ion channels (gap-junction, K+ and GABA(A) channels) as paradigms of biological significance and increasing complexity. The preparation method is based on the liquid phase and is compatible with physiological conditions. Only in the very last stage, samples are dried for TEM analysis. Conventional TEM and high-resolution TEM (HRTEM) were used to achieve a resolution of 3.3 and 1.5 angstrom, respectively. The EM dataset quality allows the determination of relevant structural and metrological information on the DNA structure, DNA-protein interactions and ion channels, allowing the identification of specific macromolecules and their structure.

  9. ESR and spectral studies of Er{sup 3+} ions in soda-lime silicate glass

    Energy Technology Data Exchange (ETDEWEB)

    Kaewwiset, W., E-mail: opticslaser@yahoo.com [Department of Physics, Faculty of Science, King Mongkut' s University of Technology, Thonburi, Bangkok 10140 (Thailand); Thamaphat, K. [Department of Physics, Faculty of Science, King Mongkut' s University of Technology, Thonburi, Bangkok 10140 (Thailand); Kaewkhao, J. [Center of Excellence in Glass Technology and Materials Science (CEGM), Faculty of Science and Technology, Nakhon Pathom Rajabhat University, Nakhon Pathom 73000 (Thailand); Thailand Center of Excellence in Physics, CHE, Ministry of Education, Bangkok 10400 (Thailand); Limsuwan, P. [Department of Physics, Faculty of Science, King Mongkut' s University of Technology, Thonburi, Bangkok 10140 (Thailand); Thailand Center of Excellence in Physics, CHE, Ministry of Education, Bangkok 10400 (Thailand)

    2013-01-15

    Electron spin resonance (ESR), optical absorption spectra and photoluminescence spectra of Er{sup 3+} ions in soda-lime silicate glasses doped with different concentrations of Er{sub 2}O{sub 3} have been studied. The glasses of the composition (in mol%) (65-x)SiO{sub 2}:25Na{sub 2}O:10CaO:xEr{sub 2}O{sub 3} (where x=0.02, 0.05, 0.1, 0.3, 0.5, 1, 2, 3, 4 and 5) were prepared by the melt quenching method. ESR measurements were carried out at room temperature down to 1.62 K. Absorption spectra were investigated in the UV-VIS-NIR region from 300 to 1800 nm. Photoluminescence spectra were observed in the spectral range 500-800 nm under 514.5 nm argon-ion laser line excitation.

  10. In operando PXRD study P2-NaxTMO2 cycled in a sodium ion battery

    DEFF Research Database (Denmark)

    Birgisson, Steinar; Shen, Yanbin; Christiansen, Troels Lindahl

    Sodium ion batteries (SIB) are being considered as a cheaper and more environmentally friendly alternative to lithium ion batteries (LIB). Application of SIB is especially important in large scale electricity storage from renewable energy sources [1]. A mayor hindrance of the development of SIB...... for practical applications is that so far there are no known electrode materials with sufficiently good rate and cycling capability. Studying structural changes of electrode materials while the battery is being charged and discharged is important to gain a deeper understanding of processes affecting...... the electrode materials. This understanding can be used to optimize battery performance and understand decay mechanisms, which in turn will facilitate the development of electrode materials fit for practical application in SIB. Our research group has developed an in operando battery cell capable of following...

  11. Structural and photocatalytic studies on pure and Sn ion doped ZnO-graphene nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Beura, Rosalin; Thangadurai, P., E-mail: thangaduraip.nst@pondiuni.edu.in [Centre for Nanoscience and Technology, Pondicherry University, R V Nagar, Kalapet, Puducherry - 605 014 (India)

    2016-05-23

    Graphene based metal oxide nanocomposites have been widely used as a photocatalyst for the treatment of water pollutants. This work demonstrates the synthesis of graphene composite with pure and Sn ion doped-ZnO and their photocatalytic properties are reported. Structural studies were carried out by X-ray diffraction and Raman spectroscopy to confirm the formation of the nanocomposites. Microstructure was characterized by scanning electron microscopy showing rod shaped ZnO and the layer structured graphene in the ZnO-graphene composite. In comparison with the undoped ZnO-graphene composite, the Sn ion doped ZnO-graphene composite have shown better degradation of methyl orange dye that is about 99% of degradation. Band gap of the composite materials was calculated to be 3.36 eV from the UV-Vis result.

  12. SAXS study of ion tracks in San Carlos olivine and Durango apatite

    Energy Technology Data Exchange (ETDEWEB)

    Afra, B., E-mail: baf109@physics.anu.edu.au [Department of Electronic Materials Engineering, Research School of Physics and Engineering, Australian National University, Canberra, ACT 0200 (Australia); Rodriguez, M.D. [Department of Electronic Materials Engineering, Research School of Physics and Engineering, Australian National University, Canberra, ACT 0200 (Australia); Lang, M.; Ewing, R.C. [Department of Geological Sciences, University of Michigan, Ann Arbor, MI 48109-1005 (United States); Kirby, N. [Australian Synchrotron, 800 Blackburn Road, Clayton, VIC 3168 (Australia); Trautmann, C. [GSI Helmholtz Centre for Heavy Ion Research, Planckstrasse 1, Darmstadt D-64291 (Germany); Kluth, P. [Department of Electronic Materials Engineering, Research School of Physics and Engineering, Australian National University, Canberra, ACT 0200 (Australia)

    2012-09-01

    Ion tracks were generated in crystalline San Carlos olivine (Mg,Fe){sub 2}SiO{sub 4} and Durango apatite Ca{sub 10}(PO{sub 4}){sub 6}F{sub 2} using different heavy ions ({sup 58}Ni, {sup 101}Ru, {sup 129}Xe, {sup 197}Au, and {sup 238}U) with energies ranging between 185 MeV and 2.6 GeV. The tracks and their annealing behavior were studied by means of synchrotron based small angle X-ray scattering in combination with in situ annealing. Track radii vary as a function of electronic energy loss but are very similar in both minerals. Furthermore, the annealing behavior of the track radii has been investigated and preliminary results reveal a lower recovery rate of the damaged area in olivine compared with apatite.

  13. Satellite studies of N/D-2/ emission and ion chemistry in aurorae

    Science.gov (United States)

    Rusch, D. W.; Gerard, J.-C.

    1980-01-01

    The incident particle flux ion and neutral composition data taken on the AE-D satellite have been used to investigate the quantal emission of N2(plus) at 4278 A, N(D-2) at 5200 A, and the ion chemistry in aurorae. The results of a time dependent auroral model have been compared to the data. The calculated 4278 A emission of N2(plus), the 5200 A emission of N(D-2), the densities of O2(plus), NO(plus), N2(plus), O(plus), and the electron density are generally in agreement with the measured values. These results are consistent with the branching ratios and quenching rates deduced from previous studies of the N(D-2) densities in the day-time, mid-latitude ionosphere. It is found that in an auroral arc, the measured atomic oxygen density is lower than predicted by the MSIS model.

  14. Use of Ion-Channel Modulating Agents to Study Cyanobacterial Na+ - K+ Fluxes

    Directory of Open Access Journals (Sweden)

    Pomati Francesco

    2004-01-01

    Full Text Available Here we describe an experimental design aimed to investigate changes in total cellular levels of Na+ and K+ ions in cultures of freshwater filamentous cyanobacteria. Ion concentrations were measured in whole cells by flame photometry. Cellular Na+ levels increased exponentially with rising alkalinity, with K+ levels being maximal for optimal growth pH (~8. At standardized pH conditions, the increase in cellular Na+, as induced by NaCl at 10 mM, was coupled by the two sodium channel-modulating agents lidocaine hydrochloride at 1 &mgr;M and veratridine at 100 &mgr;M. Both the channel-blockers amiloride (1 mM and saxitoxin (1 &mgr;M, decreased cell-bound Na+ and K+ levels. Results presented demonstrate the robustness of well-defined channel blockers and channel-activators in the study of cyanobacterial Na+- K+ fluxes.

  15. Studies for the ion cyclotron range of frequency heating in a tokamak fusion experimental device

    Energy Technology Data Exchange (ETDEWEB)

    Saigusa, Mikio [Japan Atomic Energy Research Inst., Naka, Ibaraki (Japan). Naka Fusion Research Establishment

    1996-02-01

    Ion cyclotron range of frequency heating has been investigated as an efficient additional plasma heating and non-inductive current driving methods in a tokamak type fusion experimental device. At first, an ICRF antenna coupling code was developed for the estimation of the coupling properties of phased antenna array, so that the ICRF antennas were designed for JT-60 and JT-60U ICRF heating systems using the coupling codes. The ICRF heating experiments had been performed in JT-60 and JT-60U. The coupling properties of ICRF antenna, the physics of peripheral plasma and energy confinement by ICRF heating in various heating regimes have been investigated. Next, the Toroidicity induced Alfven Eigen (TAE) mode have been studied using minority ICRF heating for producing energetic ions which can excite TAE mode. The TAE mode could be suppressed by current profile control using current ramp operation and lower hybrid current drive. (author) 74 refs.

  16. [Effect of octadecyl amine (ODA) on the complex titration of magnesium and calcium ions studied with UV-visible spectrophotometry].

    Science.gov (United States)

    Qing, Bin-Ju; Liu, Hai-Ning; Ye, Xiu-Shen; Li, Quan; Guo, Min; Liu, Teng-Yun; Wu, Zhi-Jian

    2009-10-01

    The effect of flotation agent octadecyl amine (ODA) on the complex titration of both magnesium and calcium ions was studied with two groups of comparative experiments: (1) Before titration, the suspension was not filtered. In this case, ODA had a great effect on the complex titration of both magnesium and calcium ions. The titration end-point of magnesium ions was difficult to be determined. Although the titration end-point of calcium ions could be determined, there was an obvious experimental error compared with the blank solution without ODA. These results were confirmed by the UV-Visible spectrum analyses of the related solutions. (2) Before titration, the suspension was filtered. In this case, the influence of ODA on the complex titration of both magnesium and calcium ions could be removed. UV-Visible spectrum studies showed that, in this case, both the spectra and time scanning curves of the tested solutions were similar to those of the blank solutions.

  17. Studies of the beam extraction system of the GTS-LHC electron cyclotron resonance ion source at CERN.

    Science.gov (United States)

    Toivanen, V; Küchler, D

    2016-02-01

    The 14.5 GHz GTS-LHC Electron Cyclotron Resonance Ion Source (ECRIS) provides multiply charged heavy ion beams for the CERN experimental program. The GTS-LHC beam formation has been studied extensively with lead, argon, and xenon beams with varied beam extraction conditions using the ion optical code IBSimu. The simulation model predicts self-consistently the formation of triangular and hollow beam structures which are often associated with ECRIS ion beams, as well as beam loss patterns which match the observed beam induced markings in the extraction region. These studies provide a better understanding of the properties of the extracted beams and a way to diagnose the extraction system performance and limitations, which is otherwise challenging due to the lack of direct diagnostics in this region and the limited availability of the ion source for development work.

  18. Optimizing neural network models: motivation and case studies

    OpenAIRE

    Harp, S A; T. Samad

    2012-01-01

    Practical successes have been achieved  with neural network models in a variety of domains, including energy-related industry. The large, complex design space presented by neural networks is only minimally explored in current practice. The satisfactory results that nevertheless have been obtained testify that neural networks are a robust modeling technology; at the same time, however, the lack of a systematic design approach implies that the best neural network models generally  rem...

  19. Determination of metal ion content of beverages and estimation of target hazard quotients: a comparative study

    Directory of Open Access Journals (Sweden)

    Barker James

    2008-06-01

    Full Text Available Abstract Background Considerable research has been directed towards the roles of metal ions in nutrition with metal ion toxicity attracting particular attention. The aim of this study is to measure the levels of metal ions found in selected beverages (red wine, stout and apple juice and to determine their potential detrimental effects via calculation of the Target Hazard Quotients (THQ for 250 mL daily consumption. Results The levels (mean ± SEM and diversity of metals determined by ICP-MS were highest for red wine samples (30 metals totalling 5620.54 ± 123.86 ppb followed by apple juice (15 metals totalling 1339.87 ± 10.84 ppb and stout (14 metals totalling 464.85 ± 46.74 ppb. The combined THQ values were determined based upon levels of V, Cr, Mn, Ni, Cu, Zn and Pb which gave red wine samples the highest value (5100.96 ± 118.93 ppb followed by apple juice (666.44 ± 7.67 ppb and stout (328.41 ± 42.36 ppb. The THQ values were as follows: apple juice (male 3.11, female 3.87, stout (male 1.84, female 2.19, red wine (male 126.52, female 157.22 and ultra-filtered red wine (male 110.48, female 137.29. Conclusion This study reports relatively high levels of metal ions in red wine, which give a very high THQ value suggesting potential hazardous exposure over a lifetime for those who consume at least 250 mL daily. In addition to the known hazardous metals (e.g. Pb, many metals (e.g. Rb have not had their biological effects systematically investigated and hence the impact of sustained ingestion is not known.

  20. Social Context and network formation : an experimental study

    NARCIS (Netherlands)

    Burger, Martijn J.; Buskens, Vincent

    2009-01-01

    Recently, there has been increasing interest in determining which social network structures emerge as a consequence of the conscious actions of actors.Motivated by the belief that “networks matter” in reaching personal objectives, it is a natural assumption that actors try to optimize their network

  1. Positron annihilation lifetime and Doppler broadening study in 50 MeV Li{sup 3+} ion irradiated polystyrene films

    Energy Technology Data Exchange (ETDEWEB)

    Asad Ali, S., E-mail: asadapd@yahoo.co [Department of Applied Physics, Faculty of Engineering and Technology, Aligarh Muslim University, Aligarh 202002 (India); Kumar, Rajesh [Department of Physics, University School of Basic and Applied Sciences, G.G.S.I.P University, New Delhi 110403 (India); Nambissan, P.M.G. [Saha Institute of Nuclear Physics, 1/AF, Bidhan Nagar, Kolkata 700064 (India); Singh, F. [Inter-University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi 110067 (India); Prasad, Rajendra [Department of Applied Physics, Faculty of Engineering and Technology, Aligarh Muslim University, Aligarh 202002 (India); Vivekananda College of Technology and Management, Aligarh 202002 (India)

    2010-06-15

    Swift heavy ion (SHI) irradiation of polymeric materials results in the change of their free volume properties which have strong correlation with their macroscopic properties. The modification depends on the polymer and ion beam parameters, namely ion energy, fluence and ion species. Polystyrene films were irradiated with Li{sup 3+} ions of energy 50 MeV from 15 UD Pelletron accelerators at Inter University Accelerator Centre (IUAC), New Delhi, India to the fluences of 10{sup 11}, 10{sup 12} and 10{sup 13} ions/cm{sup 2}. Nanosized free volume parameters in the polymer have been studied by positron annihilation lifetime spectroscopy (PALS) and Doppler broadening spectroscopy (DBS). From o-Ps lifetime {tau}{sub 3,} free volume hole radius, mean free volume of microvoids and fractional free volume are computed and modification in free volume with the fluence is studied. Free volume parameters change slowly with ion fluence with a decrease at the highest fluence of 10{sup 13} ions/cm{sup 2}. The decrease in {tau}{sub 3} and I{sub 3} (reflecting the number of free volume holes) may be interpreted on the process of cross-linking. S parameter obtained from DBS measurements showed a minor decrease with increasing fluence.

  2. An Empirical Rate Constant Based Model to Study Capacity Fading in Lithium Ion Batteries

    Directory of Open Access Journals (Sweden)

    Srivatsan Ramesh

    2015-01-01

    Full Text Available A one-dimensional model based on solvent diffusion and kinetics to study the formation of the SEI (solid electrolyte interphase layer and its impact on the capacity of a lithium ion battery is developed. The model uses the earlier work on silicon oxidation but studies the kinetic limitations of the SEI growth process. The rate constant of the SEI formation reaction at the anode is seen to play a major role in film formation. The kinetics of the reactions for capacity fading for various battery systems are studied and the rate constants are evaluated. The model is used to fit the capacity fade in different battery systems.

  3. Statistical process control using optimized neural networks: a case study.

    Science.gov (United States)

    Addeh, Jalil; Ebrahimzadeh, Ata; Azarbad, Milad; Ranaee, Vahid

    2014-09-01

    The most common statistical process control (SPC) tools employed for monitoring process changes are control charts. A control chart demonstrates that the process has altered by generating an out-of-control signal. This study investigates the design of an accurate system for the control chart patterns (CCPs) recognition in two aspects. First, an efficient system is introduced that includes two main modules: feature extraction module and classifier module. In the feature extraction module, a proper set of shape features and statistical feature are proposed as the efficient characteristics of the patterns. In the classifier module, several neural networks, such as multilayer perceptron, probabilistic neural network and radial basis function are investigated. Based on an experimental study, the best classifier is chosen in order to recognize the CCPs. Second, a hybrid heuristic recognition system is introduced based on cuckoo optimization algorithm (COA) algorithm to improve the generalization performance of the classifier. The simulation results show that the proposed algorithm has high recognition accuracy. Copyright © 2013 ISA. Published by Elsevier Ltd. All rights reserved.

  4. Defending Tor from Network Adversaries: A Case Study of Network Path Prediction

    Directory of Open Access Journals (Sweden)

    Juen Joshua

    2015-06-01

    Full Text Available The Tor anonymity network has been shown vulnerable to traffic analysis attacks by autonomous systems (ASes and Internet exchanges (IXes, which can observe different overlay hops belonging to the same circuit. We evaluate whether network path prediction techniques provide an accurate picture of the threat from such adversaries, and whether they can be used to avoid this threat. We perform a measurement study by collecting 17.2 million traceroutes from Tor relays to destinations around the Internet. We compare the collected traceroute paths to predicted paths using state-of-the-art path inference techniques. We find that traceroutes present a very different picture, with the set of ASes seen in the traceroute path differing from the predicted path 80% of the time. We also consider the impact that prediction errors have on Tor security. Using a simulator to choose paths over a week, our traceroutes indicate a user has nearly a 100% chance of at least one compromise in a week with 11% of total paths containing an AS compromise and less than 1% containing an IX compromise when using default Tor selection. We find modifying the path selection to choose paths predicted to be safe lowers total paths with an AS compromise to 0.14% but still presents a 5–11% chance of at least one compromise in a week while making 5% of paths fail, with 96% of failures due to false positives in path inferences. Our results demonstrate more measurement and better path prediction is necessary to mitigate the risk of AS and IX adversaries to Tor.

  5. A descriptive study of fracture networks in rocks using complex network metrics

    Science.gov (United States)

    Santiago, Elizabeth; Velasco-Hernández, Jorge X.; Romero-Salcedo, Manuel

    2016-03-01

    In this paper we describe the static topological fracture structure of five rock samples from three regions in Eastern Mexico by the application of centrality and communicability measures used in the area of complex networks. The information obtained from fracture images is used to characterize the fracture networks. The analysis is divided into two groups of characteristics. The first provides a general summary of the fracture network through the description of the number of nodes, edges, diameter, radius, lengths and clustering coefficients. A second group of features centers on the description of communicability in the network by means of three indexes recently proposed. In addition, we apply centrality measures (betweenness, closeness, eigenvector and eccentricity) for quantifying the importance of nodes in the entire network. Finally, we identify a topology for fracture networks using a classification based on the degree of communicability. The most important results obtained in this work are focused in the topological characteristic patterns found in fracture networks applying the approach of complex networks that in general provide local and global parameters of connectivity and communicability.

  6. Paraconsistent artificial neural networks and Alzheimer disease: A preliminary study

    Directory of Open Access Journals (Sweden)

    Jair Minoro Abe

    Full Text Available Abstract EEG visual analysis has proved useful in aiding AD diagnosis, being indicated in some clinical protocols. However, such analysis is subject to the inherent imprecision of equipment, patient movements, electric registers, and individual variability of physician visual analysis. Objectives: To employ the Paraconsistent Artificial Neural Network to ascertain how to determine the degree of certainty of probable dementia diagnosis. Methods: Ten EEG records from patients with probable Alzheimer disease and ten controls were obtained during the awake state at rest. An EEG background between 8 Hz and 12 Hz was considered the normal pattern for patients, allowing a variance of 0.5 Hz. Results: The PANN was capable of accurately recognizing waves belonging to Alpha band with favorable evidence of 0.30 and contrary evidence of 0.19, while for waves not belonging to the Alpha pattern, an average favorable evidence of 0.19 and contrary evidence of 0.32 was obtained, indicating that PANN was efficient in recognizing Alpha waves in 80% of the cases evaluated in this study. Artificial Neural Networks - ANN - are well suited to tackle problems such as prediction and pattern recognition. The aim of this work was to recognize predetermined EEG patterns by using a new class of ANN, namely the Paraconsistent Artificial Neural Network - PANN, which is capable of handling uncertain, inconsistent and paracomplete information. An architecture is presented to serve as an auxiliary method in diagnosing Alzheimer disease. Conclusions: We believe the results show PANN to be a promising tool to handle EEG analysis, bearing in mind two considerations: the growing interest of experts in visual analysis of EEG, and the ability of PANN to deal directly with imprecise, inconsistent, and paracomplete data, thereby providing a valuable quantitative analysis.

  7. Theoretical study of the dielectronic recombination process of Li-like Xe51+ ions

    Science.gov (United States)

    Dou, Lijun; Xie, Luyou; Zhang, Denghong; Dong, Chenzhong; Wen, Weiqiang; Huang, Zhongkui; Ma, Xinwen

    2017-05-01

    The dielectronic recombination of Li-like Xe51+ (2s) ions was studied using the flexible atomic code based on the relativistic configuration interaction method. The resonance energies, radiative and autoionization rates, and resonance strengths were calculated systematically for the doubly excited states (2p1/2nlj)J(n = 18-32) and (2p3/2n'lj)J(n' = 9-27) of Be-like Xe50+ ions. For the higher Rydberg resonance states with n ≥ 33 and n' ≥ 28, the resonance energies and strengths were obtained by extrapolation based on quantum defect theory. The theoretical rate coefficients, covering the center-of-mass energy range 0-505 eV, are in a better agreement with the experimental results measured at the heavy-ion storage ring ESR than the Multi-Configuration Dirac-Fock calculations, especially at the resonance energy range close to the series limits. Contribution to the Topical Issue: "Atomic and Molecular Data and their Applications", edited by Gordon W.F. Drake, Jung-Sik Yoon, Daiji Kato, Grzegorz Karwasz.

  8. Calorimetric study on complexation of copper(II) ion with some amide solvents in acetonitrile

    Energy Technology Data Exchange (ETDEWEB)

    Fujii, Kenta [Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan); Endoh, Toshihiko [Department of Chemistry, Faculty of Science, Shinshu University, Asahi, Matsumoto 390-8621 (Japan); Yokoi, Masatoki [Department of Chemistry, Faculty of Science, Shinshu University, Asahi, Matsumoto 390-8621 (Japan); Umebayashi, Yasuhiro [Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan); Ishiguro, Shin-Ichi [Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan)]. E-mail: analsscc@mbox.nc.kyushu-u.ac.jp

    2005-06-15

    Complexation of copper(II) ion with some amide solvents such as N-methylformamide (NMF), formamide (FA), N,N-dimethylacetamide (DMA) and N-methylacetamide (NMA) has been studied by titration calorimetry in acetonitrile containing 0.1 mol dm{sup -3} (C{sub 2}H{sub 5}){sub 4}ClO{sub 4} as an ionic medium at 298 K. These amides coordinate to the metal ion to form a series of mononuclear complexes, and their formation constants, enthalpies and entropies have been obtained. Thermodynamic parameters of formation of Cu(NMF){sup 2+} and Cu(FA){sup 2+} are not significantly different from those of Cu(DMF){sup 2+} (DMF: N,N-dimethylformamide), implying that a strong hydrogen-bonded structure of liquid NMF and FA are practically ruptured in the acetonitrile solution examined. The formation of Cu(DMA){sup 2+} and Cu(NMA){sup 2+} are appreciably less exothermic than the respective formation of Cu(DMF){sup 2+} and Cu(NMF){sup 2+} complexes, implying that the presence of the acetyl group causes steric hindrance upon its coordination to the metal ion.

  9. Helium behaviour in UO{sub 2} through low fluence ion implantation studies

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, P., E-mail: philippe.garcia@cea.fr [CEA – DEN/DEC, Bât. 352, 13108 Saint-Paul-Lez-Durance Cedex (France); Gilabert, E. [Centre d’Et' udes Nucleáires de Bordeaux-Gradignan, Le Haut Vigneau, 33175 Gradignan (France); Martin, G.; Carlot, G.; Sabathier, C. [CEA – DEN/DEC, Bât. 352, 13108 Saint-Paul-Lez-Durance Cedex (France); Sauvage, T.; Desgardin, P.; Barthe, M.-F. [CNRS-CEMHTI, UPR3079, 45071 Orleáns (France)

    2014-05-01

    In this work we focus on experiments involving implantation of 500 keV {sup 3}He ions in sintered polycrystalline material. Samples are implanted at low fluences (∼2 ×10{sup 13} ions/cm{sup 2}) and subsequently isothermally annealed in a highly sensitive thermal desorption spectrometry (TDS) device PIAGARA (Plateforme Interdisciplinaire pour l’Analyse des GAz Rares en Aquitaine). The helium fluencies studied are two to three orders of magnitude lower than previous Nuclear Reaction Analysis (NRA) experiments carried out on identical samples implanted at identical energies. The fractional release of helium obtained in the TDS experiments is interpreted using a three-dimensional axisymmetric diffusion model which enables results to be quantitatively compared to previous NRA data. The analysis shows that helium behaviour is qualitatively independent of ion fluency over three orders of magnitude: helium diffusion appears to be strongly inhibited below 1273 K within the centre of the grains presumably as a result of helium bubble precipitation. The scenario involving diffusion at grain boundaries and in regions adjacent to them observed at higher fluencies is quantitatively confirmed at much lower doses. The main difference lies in the average width of the region in which uninhibited diffusion occurs.

  10. An Auger Sputter Profiling Study of Nitrogen and Oxygen Ion Implantations in Two Titanium Alloys

    Energy Technology Data Exchange (ETDEWEB)

    Barton, B. D., Pope, L. E., Wittberg, T. N.

    1989-07-31

    Samples of two titanium alloys, Ti-6A1-4V and Ti-15V-3Cr-3Sn-3A1, were ion implanted with a combination of nitrogen (N+) and oxygen (O+). For each alloy, implantation parameters were chosen to give implanted nitrogen concentrations of approximately 10 or 50 atomic percent, from a depth of 100 nanometers to a depth of 400 nanometers. In all but one case, dual energy (200 keV and 90 keV) implantations of nitrogen were used to give a relatively uniform nitrogen concentration to a depth of 300 nanometers. In each case, oxygen was implanted at 35 keV, following the nitrogen implantation, to give an oxygen-enriched region near the surface. The implanted samples were then examined by Auger electron spectroscopy (AES) combined with argon ion sputtering. In order to determine the stoichiometry of the nitrogen implanted regions, it was necessary to determine the N (KVV) contribution to the overlapping N (KVV) and Ti (LMM) Auger transitions. It was also necessary to correct for the ion-bombardment-induced compositional changes which have been described in an earlier study of titanium nitride thin films. The corrected AES depth profiles were in good agreement with theoretical predictions.

  11. Wave packet study of the secondary emission of negatively charged, monoatomic ions from sputtered metals

    Energy Technology Data Exchange (ETDEWEB)

    Sindona, A. [Dipartimento di Fisica, Universita della Calabria, Via P. Bucci 31C, 87036 Rende (Italy) and Istituto Nazionale di Fisica Nucleare (INFN), Gruppo collegato di Cosenza, Via P. Bucci 31C, 87036 Rende (Italy)]. E-mail: sindona@fis.unical.it; Riccardi, P. [Dipartimento di Fisica, Universita della Calabria, Via P. Bucci 31C, 87036 Rende (Italy); Istituto Nazionale di Fisica Nucleare (INFN), Gruppo collegato di Cosenza, Via P. Bucci 31C, 87036 Rende (Italy); Maletta, S. [Dipartimento di Fisica, Universita della Calabria, Via P. Bucci 31C, 87036 Rende (Italy); Rudi, S.A. [Dipartimento di Fisica, Universita della Calabria, Via P. Bucci 31C, 87036 Rende (Italy); Istituto Nazionale di Fisica Nucleare (INFN), Gruppo collegato di Cosenza, Via P. Bucci 31C, 87036 Rende (Italy); Falcone, G. [Dipartimento di Fisica, Universita della Calabria, Via P. Bucci 31C, 87036 Rende (Italy); Istituto Nazionale di Fisica Nucleare (INFN), Gruppo collegato di Cosenza, Via P. Bucci 31C, 87036 Rende (Italy)

    2007-05-15

    Secondary emission of Ag{sup -} and Au{sup -} particles, following the sputtering of clean Ag(1 0 0) and Au(1 0 0) targets, respectively, is studied with a Crank-Nicholson wave-packet propagation method. A one-electron pseudo-potential is used to describe the plane metal surface, with a projected band gap, the ejected ion, whose charge state is investigated, and its nearest-neighbor substrate ion, put in motion by the collision cascade generated by the primary ion beam. Time-dependent Schroedinger equation is solved backwards in time to determine the evolution of the affinity orbital of the negative particles from an instant when they are unperturbed, at distances of the order of {approx}10{sup 2} a.u. from the surface, to the instant of ejection. The probability that a band electron will be eventually detected in affinity state of the ejected particle is, thus, calculated and compared with the result of another method based on the spectral decomposition of the one-electron Hamiltonian.

  12. EPR study of complex formation between copper (II) ions and sympathomimetic amines in aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Preoteasa, E.A. [Inst. of Atomic Physics, IFIN, Bucharest (Romania); Duliu, O.G.; Grecu, V.V. [Bucharest, Univ. (Romania). Dept. of Atomic and Nuclear Physics

    1997-07-01

    The complex formation between sympathomimetic amines (SA): adrenaline (AD), noradrenaline (NA), dopamine (DA), ephedrine (ED) and p-tyramine (pTA), and Cu(II) ion in aqueous solution has been studied by X-band EPR at room temperature. Excepting pTA, all investigated SA yielded two types of complexes in different pH domains. All complexes consistent with a ligand fields having a distorted octahedral symmetry, i.e., hexacoordination of Cu(II). The covalence coefficient calculated from the isotropic g and A values has shown strong ionic sigma-type ligand bonds. A structural model with the Cu(II) ion bound by four catecholic O(hydroxy) atoms for the low pH complexes of AD, NA and DA is proposed. For the high pH complexes of the former compounds as well as for both Ed complexes, the authors suppose Cu(II) bound by two N (amino) and two O (hydroxy) atoms. The spectra are consistent to water binding on the longitudinal octahedron axis in all compounds excepting the high pH complex of Ed, where OH2- ions are bound. Possible implications for the SA-cell receptors interactions are discussed.

  13. Spectroscopic and Structural Study of Proton and Halide Ion Cooperative Binding to GFP

    Science.gov (United States)

    Arosio, Daniele; Garau, Gianpiero; Ricci, Fernanda; Marchetti, Laura; Bizzarri, Ranieri; Nifosì, Riccardo; Beltram, Fabio

    2007-01-01

    This study reports the influence of halogens on fluorescence properties of the Aequorea victoria Green Fluorescent Protein variant S65T/T203Y (E2GFP). Halide binding forms a specific nonfluorescent complex generating a substantial drop of the fluorescence via static quenching. Spectroscopic analysis under different solution conditions reveals high halogen affinity, which is strongly dependent on the pH. This evidences the presence in E2GFP of interacting binding sites for halide ions and for protons. Thermodynamic link and cooperative interaction are assessed demonstrating that binding of one halide ion is associated with the binding of one proton in a cooperative fashion with the formation, in the pH range 4.5–10, of a single fully protonated E2GFP·halogen complex. To resolve the structural determinants of E2GFP sensitivity to halogens, high-resolution crystallographic structures were obtained for the halide-free and I−, Br−, and Cl− bound E2GFP. Remarkably the first high-resolution (1.4 Å) crystallographic structure of a chloride-bound GFP is reported. The chloride ion occupies a specific and unique binding pocket in direct contact (3.4 Å) with the chromophore imidazolidinone aromatic ring. Unanticipated flexibility, strongly modulated by halide ion interactions, is observed in the region surrounding the chromophore. Furthermore molecular dynamics simulations identified E222 residue (along with the chromophore Y66 residue) being in the protonated state when E2GFP·halogen complex is formed. The impact of these results on high-sensitivity biosensor design will be discussed. PMID:17434942

  14. Comparative studies of ONNO-based ligands as ionophores for palladium ion-selective membrane sensors.

    Science.gov (United States)

    Gupta, Vinod K; Goyal, Rajendra N; Sharma, Ram A

    2009-04-30

    Palladium sensors based on two neutral ionophores, N,N'-bis(acetylacetone) cyclohexanediamine (L(1)) and N,N'-bis(o-hydroxyacetophenone)-1,2-cyclohexanediamine (L(2)) for quantification of palladium ions are described. Effect of various plasticizers (o-NPOE, DBP, DEP, DOP, TBP, and CN) and anion excluder, sodium tetra phenyl borate (NaTPB) has been studied. The best performance is obtained with a membrane composition of PVC:o-NPOE:ionophore (L(1)):NaTPB of 150:300:5:5 (%, w/w). The sensor exhibits significantly enhanced selectivity towards palladium ion over the concentration range 1.0 x 10(-8) to 1.0 x 10(-1)M with a lower detection limit of 4.0 x 10(-9)M and a Nernstian compliance (29.1+/-0.3 mV decade(-1) of activity) within pH range 2.0-6.0 and fast response time of 10s. Influence of the membrane composition and possible interfering ions has also been investigated on the response properties of the electrode. Fast and stable response, good reproducibility and long-term stability of the sensor are demonstrated. The sensor has been found to work satisfactorily in partially non-aqueous media up to 20% (v/v) content of methanol, ethanol and acetonitrile and could be used for a period of 4 months. Selectivity coefficients determined with fixed interference method (FIM) indicate high selectivity for palladium. The proposed electrode shows fairly good discrimination of palladium from other cations. The application of prepared sensor has been demonstrated in determination of palladium ions in spiked water sample.

  15. Atomic spectroscopy on fusion relevant ions and studies of light impurities in the JET tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Tunklev, M

    1999-03-01

    The spectrum and energy levels of C IV and the 3l-4l system of the Mg-like ions in the iron group elements have been investigated. This has led to several hundred identified transitions, many of them previously unknown. Using the Charge Exchange Diagnostic system at JET, ion temperatures, rotation velocities and densities have been derived from visible spectroscopic measurements on fully ionised light impurities, such as He, C, N and Ne. The existence of plume contribution from beam produced hydrogen-like ions has been proven beyond any doubt to affect the deduction of the active charge exchange signal of He II. In the case of C VI the plume signal was estimated to be at least a factor of five lower than the active charge exchange signal. Line integrated passive charge exchange emission between neutral background atoms and fully stripped impurity ions has been investigated and modelled. When the synthetic spectrum is fitted into the experimentally detected spectra the neutral background density can be deduced. The importance of including background atoms (H, D and T) as charge exchange donors, not only in state 2s, but also in state 1s, has shown to be crucial in high temperature shots. Transport of light impurities has been studied with gas puff injections into steady state H-mode plasmas. The results suggest that light impurities are transported as described by the neo-classical Pfirsch-Schlueter regime at the edge, whilst in the centre, sawtoothing, preferably to Banana transport, is mixing the plasma and increases the measured values on the diffusion. For the peaking of impurities in a steady state plasma an anomalous treatment was more in agreement with the experimental data. Certain confinement information, previously predicted theoretically as a part of the peaking equation, has been experimentally verified

  16. Preliminary Design Study for a National Digital Seismograph Network

    Science.gov (United States)

    Peterson, Jon; Hutt, Charles R.

    1981-01-01

    Introduction Recently, the National Research Council published a report by the Panel on National, Regional, and Local Seismograph Networks of the Committee on Seismology in which the principal recommendation was for the establishment of a national digital seismograph network (NDSN). The Panel Report (Bolt, 1980) addresses both the need and the scientific requirements for the new national network. The purpose of this study has been to translate the scientific requirements into an instrumentation concept for the NSDS. There are literally hundreds, perhaps thousands, of seismographs in operation within the United States. Each serves an important purpose, but most have limited objectives in time, in region, or in the types of data that are being recorded. The concept of a national network, funded and operated by the Federal Government, is based on broader objectives that include continuity of time, uniform coverage, standardization of data format and instruments, and widespread use of the data for a variety of research purposes. A national digital seismograph network will be an important data resource for many years to come; hence, its design is likely to be of interest to most seismologists. Seismologists have traditionally been involved in the development and field operation of seismic systems and thus have been familiar with both the potential value and the limitations of the data. However, in recent years of increasing technological sophistication, the development of data sstems has fallen more to system engineers, and this trend is likely to continue. One danger in this is that the engineers may misinterpret scientific objectives or subordinate them to purely technological considerations. Another risk is that the data users may misuse or misinterpret the data because they are not aware of the limitations of the data system. Perhaps the most important purpose of a design study such as this is to stimulate a dialogue between system engineers and potential data users

  17. Cointegration-based financial networks study in Chinese stock market

    Science.gov (United States)

    Tu, Chengyi

    2014-05-01

    We propose a method based on cointegration instead of correlation to construct financial complex network in Chinese stock market. The network is obtained starting from the matrix of p-value calculated by Engle-Granger cointegration test between all pairs of stocks. Then some tools for filtering information in complex network are implemented to prune the complete graph described by the above matrix, such as setting a level of statistical significance as a threshold and Planar Maximally Filtered Graph. We also calculate Partial Correlation Planar Graph of these stocks to compare the above networks. Last, we analyze these directed, weighted and non-symmetric networks by using standard methods of network analysis, including degree centrality, PageRank, HITS, local clustering coefficient, K-shell and strongly and weakly connected components. The results shed a new light on the underlying mechanisms and driving forces in a financial market and deepen our understanding of financial complex network.

  18. Production networks in Asia: A case study from the hard disk drive industry

    OpenAIRE

    Hiratsuka, Daisuke

    2011-01-01

    Production networks have been extensively developed in East Asia. Previous studies on production networks used international trade data or input–output tables, but such aggregate data cannot explain how the networks actually operate. With the aim of understanding the features and characteristics of East Asian production networks, this paper examines the procurement system of a HDD assembler operating in Thailand. This micro-level case study found that this particular production networ...

  19. How do German veterinarians use social networks? A study, using the example of the 'NOVICE' veterinary medicine network.

    Science.gov (United States)

    Schaper, Elisabeth; Forrest, Neil D; Tipold, Andrea; Ehlers, Jan P

    2013-01-01

    NOVICE (Network Of Veterinary ICT in Education, http://www.noviceproject.eu/), is a professional online social network for veterinarians, lecturers and students of veterinary medicine as well as for e-Learning advisers and others working in establishments that teach veterinary medicine. This study sets out to investigate to what extent German veterinarians, lecturers, students of veterinary medicine and e-Learning representatives would accept a specialist network, what requirements would have to be met by an online social network, how to use web 2.0 tools [21], [30] and what advantages a specialist network could offer. The investigation was carried out by analysing data from the Elgg platform database as well as using Google Analytics. Annual focus group surveys and individual interviews were carried out in order to perform an analysis of acceptance among network users. 1961 users from 73 different countries registered on the NOVICE site between 1 September 2010 and 21 March 2012. Germany represents the biggest user group, with 565 users (28.81%). During this period, most individual hits on the website came from Germany too. In total, 24.83% of all members are active, while 19.22% of German members participate actively. In terms of gender, there are significantly more female members than male members, both in the NOVICE network as a whole as well as in Germany. The most used web 2.0 tools are chat and email messaging services as well as writing wikis and contributing to forum discussions. The focus group surveys showed that respondents generally make use of other online communities too. Active members generally use more web 2.0 tools than in other networks, while passive members are generally more reluctant in all networks. All participants of the survey welcomed the idea of having a network specifically set up for the profession and believe that it could be very useful for veterinary medicine. The network and its membership figures developed very positively during

  20. Ion pair structures in aqueous KSCN solution: Classical and quantum mechanical/molecular mechanical molecular dynamic simulation study

    Energy Technology Data Exchange (ETDEWEB)

    Ghosh, Manik Kumer; Choi, Cheol Ho [Dept. of Chemistry and Green-Nano Materials Research Center, College of Natural Sciences, Kyungpook National University, Daegu (Korea, Republic of); Choi, Jun Ho; Cho, Min Haeng [Dept. of Chemistry, Korea University, Seoul (Korea, Republic of)

    2015-03-15

    Ion pair formation and dissociation are fundamental processes in electrolyte solutions so that understanding thermodynamic stabilities and dynamic aspects of ion pairs is of great importance. The structures of various ion pair states are here studied by carrying out classical and quantum mechanical/molecular mechanical (QM/MM) molecular dynamics (MD) simulations of aqueous KSCN solutions. A few different solvent potential models are considered and the resulting ion pair structures are directly compared. In particular, when KSCN is treated quantum mechanically and effective fragment potential (EFP) model for water is used, we found two stable forms of ion pairs that can be considered as contact ion pair (CIP) and solvent separated ion pair (SSIP), where the interionic distances between K{sup +} and SCN {sup −} are found to be 4.0 and 5.5 Å, respectively. QM/EFP-MD further indicates that the nitrogen side of SCN {sup −} is preferentially interacting with K{sup +} in CIP. However, the corresponding CIP appears at 3.0 Å interionic distance in fully classical MD simulation at a higher KSCN concentration. Nonetheless, both QM/EFP and classical MD simulation results show that the CIP state appears to be more stable than SSIP. From the site-site radial distribution functions (RDF) calculated from the QM/MM and classical MD trajectories, detailed ion pair structures and surrounding solvent configurations are further elucidated.

  1. Network Distributed Data Acquisition, Storage, and Graphical Live Display Software for a Laser Ion Source at CERN

    CERN Document Server

    Rossel, Ralf Erik; Rothe, Sebastian

    2014-01-01

    This project documentation outlines the requirements and implementation details for the measurement data recording software currently in development for the Resonance Ionisation Laser Ion Source (RILIS) at CERN. The software is capable of acquiring data from multiple laser parameter monitoring devices and associating the gathered values to represent qualitative and quantitative measurements. The measurement data is displayed graphically within the program and recorded to files for later analysis. The main application of the software is the acquisition coordination and recording of measurement data during spectroscopy experiments performed by RILIS and collaborating experiments. This document describes the design concept and detailed program implementation status at the end of July 2014 and provides an outlook to future developments in RILIS spectroscopy data acquisition.

  2. Ku-band signal design study. [space shuttle orbiter data processing network

    Science.gov (United States)

    Rubin, I.

    1978-01-01

    Analytical tools, methods and techniques for assessing the design and performance of the space shuttle orbiter data processing system (DPS) are provided. The computer data processing network is evaluated in the key areas of queueing behavior synchronization and network reliability. The structure of the data processing network is described as well as the system operation principles and the network configuration. The characteristics of the computer systems are indicated. System reliability measures are defined and studied. System and network invulnerability measures are computed. Communication path and network failure analysis techniques are included.

  3. FTIR study of carbon monoxide adsorption on ion-exchanged X, Y and mordenite type zeolites

    Directory of Open Access Journals (Sweden)

    R. HERCIGONJA

    2003-05-01

    Full Text Available In this work Fourier transform infrared (FTIR study has been applied to study the adsorption of carbon monoxide on transition metal (Mn+, Co2+, Ni2+ ion-exchanged zeolites type Y, X and mordenites. The adsorption of CO at room temperature produces overlapping IR absorption bands in the 2120–2200 cm-1 region. The frequency of the band around 2200 cm-1 is found to be dependent not only on the charge-balancing transition metal cation, but also on the framework composition. The frequencies of the band near 1600 cm-1 was found to be dependent on the Si/Al ratio of the investigated zeolites.

  4. Bundle Security Protocol for ION

    Science.gov (United States)

    Burleigh, Scott C.; Birrane, Edward J.; Krupiarz, Christopher

    2011-01-01

    This software implements bundle authentication, conforming to the Delay-Tolerant Networking (DTN) Internet Draft on Bundle Security Protocol (BSP), for the Interplanetary Overlay Network (ION) implementation of DTN. This is the only implementation of BSP that is integrated with ION.

  5. Near-threshold photoionization of hydrogenlike uranium studied in ion-atom collisions via the time-reversed process.

    Science.gov (United States)

    Stöhlker, T; Ma, X; Ludziejewski, T; Beyer, H F; Bosch, F; Brinzanescu, O; Dunford, R W; Eichler, J; Hagmann, S; Ichihara, A; Kozhuharov, C; Krämer, A; Liesen, D; Mokler, P H; Stachura, Z; Swiat, P; Warczak, A

    2001-02-05

    Radiative electron capture, the time-reversed photoionization process occurring in ion-atom collisions, provides presently the only access to photoionization studies for very highly charged ions. By applying the deceleration mode of the ESR storage ring, we studied this process in low-energy collisions of bare uranium ions with low- Z target atoms. This technique allows us to extend the current information about photoionization to much lower energies than those accessible for neutral heavy elements in the direct reaction channel. The results prove that for high- Z systems, higher-order multipole contributions and magnetic corrections persist even at energies close to the threshold.

  6. Tumor tracking based on correlation models in scanned ion beam therapy: an experimental study

    Science.gov (United States)

    Seregni, M.; Kaderka, R.; Fattori, G.; Riboldi, M.; Pella, A.; Constantinescu, A.; Saito, N.; Durante, M.; Cerveri, P.; Bert, C.; Baroni, G.

    2013-07-01

    Accurate dose delivery to extra-cranial lesions requires tumor motion compensation. An effective compensation can be achieved by real-time tracking of the target position, either measured in fluoroscopy or estimated through correlation models as a function of external surrogate motion. In this work, we integrated two internal/external correlation models (a state space model and an artificial neural network-based model) into a custom infra-red optical tracking system (OTS). Dedicated experiments were designed and conducted at GSI (Helmholtzzentrum für Schwerionenforschung). A robotic breathing phantom was used to reproduce regular and irregular internal target motion as well as external thorax motion. The position of a set of markers placed on the phantom thorax was measured with the OTS and used by the correlation models to infer the internal target position in real-time. Finally, the estimated target position was provided as input for the dynamic steering of a carbon ion beam. Geometric results showed that the correlation models transversal (2D) targeting error was always lower than 1.3 mm (root mean square). A significant decrease of the dosimetric error with respect to the uncompensated irradiation was achieved in four out of six experiments, demonstrating that phase shifts are the most critical irregularity for external/internal correlation models.

  7. Spatial fractionation of the dose using neon and heavier ions: A Monte Carlo study.

    Science.gov (United States)

    Peucelle, C; Martínez-Rovira, I; Prezado, Y

    2015-10-01

    This work explores a new radiation therapy approach which might trigger a renewed use of neon and heavier ions to treat cancers. These ions were shown to be extremely efficient in radioresistant tumor killing. Unfortunately, the efficient region also extends into the normal tissue in front of the tumor. The strategy the authors propose is to profit from the well-established sparing effect of thin spatially fractionated beams, so that the impact on normal tissues might be minimized while a high tumor control is achieved. The main goal of this work is to provide a proof of concept of this new approach. With that aim, a dosimetric study was carried out as a first step to evaluate the interest of further explorations of this avenue. The gate/geant4 v.6.1 Monte Carlo simulation platform was employed to simulate arrays of rectangular minibeams (700 μm × 2 cm) of four ions (Ne, Si, Ar, and Fe). The irradiations were performed with a 2 cm-long spread-out Bragg peak centered at 7 cm-depth. Dose distributions in a water phantom were scored considering two minibeams center-to-center distances: 1400 and 3500 μm. Peak and valley doses, peak-to-valley dose ratios (PVDRs), beam penumbras, and relative contribution of nuclear fragments and electromagnetic processes were assessed as figures of merit. In addition, the type and proportion of the secondary nuclear fragments were evaluated in both peak and valley regions. Extremely high PVDR values (>100) and low valley doses were obtained. The higher the atomic number (Z) of the primary ion is, the lower the valleys and the narrower the penumbras. Although the yield of secondary nuclear products increases with Z, the actual dose being deposited by the secondary nuclear fragments in the valleys starts to be the dominant contribution at deeper points, helping in the sparing of proximal normal tissues. Additionally, a wider center-to-center distance leads to a minimized contribution of heavier secondary fragments in valleys. The

  8. Chain Migration through Social Networks: Case Study of Vietnamese Migrants in Thailand

    Directory of Open Access Journals (Sweden)

    Anh Tuan NGUYEN

    2016-11-01

    Full Text Available The paper aims to investigate the relationship between the recent increasingly pattern of Vietnamese migrants in Thailand and migration networks. By surveying 50 Vietnamese migrants in Bangkok, Thailand, the study confirms that migration networks have played a critical role in facilitating migration flows, especially irregular flows from Vietnam to Thailand over the years. It can be reflected by reducing the cost of migration, coping with new working environment and risks during working in Thailand and ensuring the return process for Vietnamese migrants. Moreover, forms of social networks includes personal networks (kinship and friendship networks, and community network (ngườidẫnđường’s network, social media has been also discussed. The study also implies that the người dẫn đường’s networks might contribute to recently emerging issues such as human trafficking and smugglings, which require further research.

  9. A study of knowledge supernetworks and network robustness in different business incubators

    Science.gov (United States)

    Zhang, Haihong; Wu, Wenqing; Zhao, Liming

    2016-04-01

    As the most important intangible resource of the new generation of business incubators, knowledge has been studied extensively, particularly with respect to how it spreads among incubating firms through knowledge networks. However, these homogeneous networks do not adequately describe the heterogeneity of incubating firms in different types of business incubators. To solve the problem of heterogeneity, the notion of a knowledge supernetwork has been used both to construct a knowledge interaction model among incubating firms and to distinguish social network relationships from knowledge network relationships. The process of knowledge interaction and network evolution can then be simulated with a few rules for incubating firms regarding knowledge innovation/absorption, social network connection, and entry and exit, among other aspects. Knowledge and networks have been used as performance indicators to evaluate the evolution of knowledge supernetworks. Moreover, we study the robustness of incubating firms' social networks by employing four types of attack strategies. Based on our simulation results, we conclude that there have been significant knowledge interaction and network evolution among incubating firms on a periodic basis and that both specialized and diversified business incubators have every advantage necessary in terms of both knowledge and networks to cultivate start-up companies. As far as network robustness is concerned, there is no obvious difference between the two types of business incubators with respect to the stability of their network structures, but specialized business incubators have stronger network communication abilities than diversified business incubators.

  10. Robustness analysis metrics for worldwide airport network: A comprehensive study

    Directory of Open Access Journals (Sweden)

    Xiaoqian Sun

    2017-04-01

    Full Text Available Robustness of transportation networks is one of the major challenges of the 21st century. This paper investigates the resilience of global air transportation from a complex network point of view, with focus on attacking strategies in the airport network, i.e., to remove airports from the system and see what could affect the air traffic system from a passenger’s perspective. Specifically, we identify commonalities and differences between several robustness measures and attacking strategies, proposing a novel notion of functional robustness: unaffected passengers with rerouting. We apply twelve attacking strategies to the worldwide airport network with three weights, and evaluate three robustness measures. We find that degree and Bonacich based attacks harm passenger weighted network most. Our evaluation is geared toward a unified view on air transportation network attack and serves as a foundation on how to develop effective mitigation strategies.

  11. Applied Graph-Mining Algorithms to Study Biomolecular Interaction Networks

    Science.gov (United States)

    2014-01-01

    Protein-protein interaction (PPI) networks carry vital information on the organization of molecular interactions in cellular systems. The identification of functionally relevant modules in PPI networks is one of the most important applications of biological network analysis. Computational analysis is becoming an indispensable tool to understand large-scale biomolecular interaction networks. Several types of computational methods have been developed and employed for the analysis of PPI networks. Of these computational methods, graph comparison and module detection are the two most commonly used strategies. This review summarizes current literature on graph kernel and graph alignment methods for graph comparison strategies, as well as module detection approaches including seed-and-extend, hierarchical clustering, optimization-based, probabilistic, and frequent subgraph methods. Herein, we provide a comprehensive review of the major algorithms employed under each theme, including our recently published frequent subgraph method, for detecting functional modules commonly shared across multiple cancer PPI networks. PMID:24800226

  12. Study of Li atom diffusion in amorphous Li3PO4 with neural network potential

    Science.gov (United States)

    Li, Wenwen; Ando, Yasunobu; Minamitani, Emi; Watanabe, Satoshi

    2017-12-01

    To clarify atomic diffusion in amorphous materials, which is important in novel information and energy devices, theoretical methods having both reliability and computational speed are eagerly anticipated. In the present study, we applied neural network (NN) potentials, a recently developed machine learning technique, to the study of atom diffusion in amorphous materials, using Li3PO4 as a benchmark material. The NN potential was used together with the nudged elastic band, kinetic Monte Carlo, and molecular dynamics methods to characterize Li vacancy diffusion behavior in the amorphous Li3PO4 model. By comparing these results with corresponding DFT calculations, we found that the average error of the NN potential is 0.048 eV in calculating energy barriers of diffusion paths, and 0.041 eV in diffusion activation energy. Moreover, the diffusion coefficients obtained from molecular dynamics are always consistent with those from ab initio molecular dynamics simulation, while the computation speed of the NN potential is 3-4 orders of magnitude faster than DFT. Lastly, the structure of amorphous Li3PO4 and the ion transport properties in it were studied with the NN potential using a large supercell model containing more than 1000 atoms. The formation of P2O7 units was observed, which is consistent with the experimental characterization. The Li diffusion activation energy was estimated to be 0.55 eV, which agrees well with the experimental measurements.

  13. [Cost estimation of an epidemiological surveillance network for animal diseases in Central Africa: a case study of the Chad network].

    Science.gov (United States)

    Ouagal, M; Berkvens, D; Hendrikx, P; Fecher-Bourgeois, F; Saegerman, C

    2012-12-01

    In sub-Saharan Africa, most epidemiological surveillance networks for animal diseases were temporarily funded by foreign aid. It should be possible for national public funds to ensure the sustainability of such decision support tools. Taking the epidemiological surveillance network for animal diseases in Chad (REPIMAT) as an example, this study aims to estimate the network's cost by identifying the various costs and expenditures for each level of intervention. The network cost was estimated on the basis of an analysis of the operational organisation of REPIMAT, additional data collected in surveys and interviews with network field workers and a market price listing for Chad. These costs were then compared with those of other epidemiological surveillance networks in West Africa. The study results indicate that REPIMAT costs account for 3% of the State budget allocated to the Ministry of Livestock. In Chad in general, as in other West African countries, fixed costs outweigh variable costs at every level of intervention. The cost of surveillance principally depends on what is needed for surveillance at the local level (monitoring stations) and at the intermediate level (official livestock sectors and regional livestock delegations) and on the cost of the necessary equipment. In African countries, the cost of surveillance per square kilometre depends on livestock density.

  14. Using actor-network theory to study an educational situation: an ...

    African Journals Online (AJOL)

    Actor-network theory allows a researcher to analyse a complex social setting involving both human and non-human actors. An actor network can be used to model a dynamic and complex set of relationships between these actors. This article describes actor-network theory and shows how it was applied to study and model ...

  15. Social Networking Tools and Teacher Education Learning Communities: A Case Study

    Science.gov (United States)

    Poulin, Michael T.

    2014-01-01

    Social networking tools have become an integral part of a pre-service teacher's educational experience. As a result, the educational value of social networking tools in teacher preparation programs must be examined. The specific problem addressed in this study is that the role of social networking tools in teacher education learning communities…

  16. The Embeddedness of Teachers' Social Networks: Evidence from a Study of Mathematics Reform

    Science.gov (United States)

    Coburn, Cynthia E.; Mata, Willow S.; Choi, Linda

    2013-01-01

    Teachers' social networks can play an important role in teacher learning and organizational change. But what influences teachers' networks? Why do some teachers have networks that are likely to support individual and organizational change, while others do not? This study is a first step in answering this question. We focus on how district policy…

  17. A Study of Gaps in Network Knowledge Synthesis

    Science.gov (United States)

    2016-10-14

    report: • Attack detection: activities primarily focused on detection of malicious activities (covered in the “Attack Analysis” report [27]) • Social ...network research: analysis or measurements related to social network websites, e.g., Facebook, Twitter, etc. (low priority) • Mobile ad-hoc networks...computers with identical (or similar) hardware and software configurations. (Memory dumps are obtained using one of four methods: (1) software

  18. Method for studying a sample of material using a heavy ion induced mass spectrometer source

    Science.gov (United States)

    Fries, David P.; Browning, James F.

    1999-01-01

    A heavy ion generator is used with a plasma desorption mass spectrometer to provide an appropriate neutron flux in the direction of a fissionable material in order to desorb and ionize large molecules from the material for mass analysis. The heavy ion generator comprises a fissionable material having a high n,f reaction cross section. The heavy ion generator also comprises a pulsed neutron generator that is used to bombard the fissionable material with pulses of neutrons, thereby causing heavy ions to be emitted from the fissionable material. These heavy ions impinge on a material, thereby causing ions to desorb off that material. The ions desorbed off the material pass through a time-of-flight mass analyzer, wherein ions can be measured with masses greater than 25,000 amu.

  19. System for studying a sample of material using a heavy ion induced mass spectrometer source

    Science.gov (United States)

    Fries, David P.; Browning, James F.

    1998-01-01

    A heavy ion generator is used with a plasma desorption mass spectrometer to provide an appropriate neutron flux in the direction of a fissionable material in order to desorb and ionize large molecules from the material for mass analysis. The heavy ion generator comprises a fissionable material having a high n,f reaction cross section. The heavy ion generator also comprises a pulsed neutron generator that is used to bombard the fissionable material with pulses of neutrons, thereby causing heavy ions to be emitted from the fissionable material. These heavy ions impinge on a material, thereby causing ions to desorb off that material. The ions desorbed off the material pass through a time-of-flight mass analyzer, wherein ions can be measured with masses greater than 25,000 amu.

  20. Vinylimidazole-Based Asymmetric Ion Pair Comonomers: Synthesis, Polymerization Studies and Formation of Ionically Crosslinked PMMA

    NARCIS (Netherlands)

    Jana, S.; Vasantha, V.A.; Stubbs, L.P.; Parthiban, A.; Vancso, Gyula J.

    2013-01-01

    Vinylimidazole-based asymmetric ion pair comonomers (IPCs) which are free from nonpolymerizable counter ions have been synthesized, characterized and polymerized by free radical polymerization (FRP), atom transfer radical polymerization (ATRP), and reversible addition-fragmentation chain transfer

  1. iPTMnet: Integrative Bioinformatics for Studying PTM Networks.

    Science.gov (United States)

    Ross, Karen E; Huang, Hongzhan; Ren, Jia; Arighi, Cecilia N; Li, Gang; Tudor, Catalina O; Lv, Mengxi; Lee, Jung-Youn; Chen, Sheng-Chih; Vijay-Shanker, K; Wu, Cathy H

    2017-01-01

    Protein post-translational modification (PTM) is an essential cellular regulatory mechanism, and disruptions in PTM have been implicated in disease. PTMs are an active area of study in many fields, leading to a wealth of PTM information in the scientific literature. There is a need for user-friendly bioinformatics resources that capture PTM information from the literature and support analyses of PTMs and their functional consequences. This chapter describes the use of iPTMnet ( http://proteininformationresource.org/iPTMnet/ ), a resource that integrates PTM information from text mining, curated databases, and ontologies and provides visualization tools for exploring PTM networks, PTM crosstalk, and PTM conservation across species. We present several PTM-related queries and demonstrate how they can be addressed using iPTMnet.

  2. Permeation of ammonia across bilayer lipid membranes studied by ammonium ion selective microelectrodes.

    Science.gov (United States)

    Antonenko, Y N; Pohl, P; Denisov, G A

    1997-01-01

    Ammonium ion and proton concentration profiles near the surface of a planar bilayer lipid membrane (BLM) generated by an ammonium ion gradient across the BLM are studied by means of microelectrodes. If the concentration of the weak base is small compared with the buffer capacity of the medium, the experimental results are well described by the standard physiological model in which the transmembrane transport is assumed to be limited by diffusion across unstirred layers (USLs) adjacent to the membrane at basic pH values (pH > pKa) and by the permeation across the membrane itself at acidic pH values. In a poorly buffered medium, however, these predictions are not fulfilled. A pH gradient that develops within the USL must be taken into account under these conditions. From the concentration distribution of ammonium ions recorded at both sides of the BLM, the membrane permeability for ammonia is determined for BLMs of different lipid composition (48 x 10(-3) cm/s in the case of diphytanoyl phosphatidylcholine). A theoretical model of weak electrolyte transport that is based on the knowledge of reaction and diffusion rates is found to describe well the experimental profiles under any conditions. The microelectrode technique can be applied for the study of the membrane permeability of other weak acids or bases, even if no microsensor for the substance under study is available, because with the help of the theoretical model the membrane permeability values can be estimated from pH profiles alone. The accuracy of such measurements is limited, however, because small changes in the equilibrium constants, diffusion coefficients, or concentrations used for computations create a systematic error. PMID:9129821

  3. Study of Nuclear Reactions with 11C and 15O Radioactive Ion Beams

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Dongwon [Univ. of California, Berkeley, CA (United States)

    2007-05-14

    Nuclear reaction study with radioactive ion beams is one of the most exciting research topics in modern nuclear physics. The development of radioactive ion beams has allowed nuclear scientists and engineers to explore many unknown exotic nuclei far from the valley of nuclear stability, and to further our understanding of the evolution of the universe. The recently developed radioactive ion beam facility at the Lawrence Berkeley National Laboratory's 88-inch cyclotron is denoted as BEARS and provides 11C, 14O and 15O radioactive ion beams of high quality. These moderate to high intensity, proton-rich radioactive ion beams have been used to explore the properties of unstable nuclei such as 12N and 15F. In this work, the proton capture reaction on 11C has been evaluated via the indirect d(11C, 12N)n transfer reaction using the inverse kinematics method coupled with the Asymptotic Normalization Coefficient (ANC) theoretical approach. The total effective 12N → 11C+p ANC is found to be (C eff12N = 1.83 ± 0.27 fm-1. With the high 11C beam intensity available, our experiment showed excellent agreement with theoretical predictions and previous experimental studies. This study also indirectly confirmed that the 11C(p,γ) reaction is a key step in producing CNO nuclei in supermassive low-metallicity stars, bypassing the slow triple alpha process. The newly developed 15O radioactive ion beam at BEARS was used to study the poorly known level widths of 16F via the p(15O,15O)p reaction. Among the nuclei in the A=16, T=1 isobaric triad, many states in 16N and 16O have been well established, but less has been reported on 16F. Four states of 16F below 1 MeV have been identified experimentally: 0-, 1

  4. Comparative Study between Robust Control of Robotic Manipulators by Static and Dynamic Neural Networks

    OpenAIRE

    Ghrab, Nadya; Kallel, Hichem

    2013-01-01

    A comparative study between static and dynamic neural networks for robotic systems control is considered. So, two approaches of neural robot control were selected, exposed, and compared. One uses a static neural network; the other uses a dynamic neural network. Both compensate the nonlinear modeling and uncertainties of robotic systems. The first approach is direct; it approximates the nonlinearities and uncertainties by a static neural network. The second approach is indirect; it uses a dyna...

  5. Formal Food-related Networks in Ireland: A Case Study Analysis

    Directory of Open Access Journals (Sweden)

    Maeve Henchion

    2012-03-01

    Full Text Available  Strategic networking is of crucial importance for innovation in small and medium sized enterprises (SMEs as it enables these companies access external resources and overcome internal constraints. However, SMEs often lack the skills and competencies to engage in and benefit from networks. Consequently SMEs often fail in establishing strategic and efficient networks. To date, there is limited guidance available on the optimal design of such networks. Furthermore, limited guidance is available on the number of networks, and level of engagement therein, that companies should be involved with. Using case studies across a range of formal networks within the food sector in Ireland, insights into the success factors and barriers to network learning are presented, which provide a foundation for such guidelines. Three case studies were selected for analysis in Ireland. Up to ten in-depth interviews were scheduled with the network managers and key informants from the triple helix (i.e. policy, research and industry sectors within each formal network. Initially, interviewees were identified as a result of a review of secondary sources and personal knowledge of the authors. The snowball sampling technique was then employed to identify additional interviewees within each network. The findings from this study revealed that some formal networks had a strong institutional influence, including significant financial inputs, whilst others had bottom-up origins. Many networks had strong levels of interaction prior to formalisation, which provided solid trust-based foundations. Innovation and/or learning were not the expressed objectives of all networks at the outset. However, interviewees across all three networks felt that positive impacts had been achieved in these areas. Whilst being involved in a broad network can provide access to a wider range of ideas, these case studies suggest that being involved in a smaller, dense network, with high levels of IP

  6. Development and testing of a pulsed helium ion source for probing materials and warm dense matter studies

    Energy Technology Data Exchange (ETDEWEB)

    Ji, Q., E-mail: qji@lbl.gov; Seidl, P. A.; Waldron, W. L.; Takakuwa, J. H.; Persaud, A.; Schenkel, T. [Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Friedman, A.; Grote, D. P.; Barnard, J. J. [Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)

    2016-02-15

    The neutralized drift compression experiment was designed and commissioned as a pulsed, linear induction accelerator to drive thin targets to warm dense matter (WDM) states with peak temperatures of ∼1 eV using intense, short pulses (∼1 ns) of 1.2 MeV lithium ions. At that kinetic energy, heating a thin target foil near the Bragg peak energy using He{sup +} ions leads to more uniform energy deposition of the target material than Li{sup +} ions. Experiments show that a higher current density of helium ions can be delivered from a plasma source compared to Li{sup +} ions from a hot plate type ion source. He{sup +} beam pulses as high as 200 mA at the peak and 4 μs long were measured from a multi-aperture 7-cm-diameter emission area. Within ±5% variation, the uniform beam area is approximately 6 cm across. The accelerated and compressed pulsed ion beams can be used for materials studies and isochoric heating of target materials for high energy density physics experiments and WDM studies.

  7. ESR studies of high-energy phosphorus-ion implanted synthetic diamond crystals

    Energy Technology Data Exchange (ETDEWEB)

    Isoya, J. [University of Library and Information Science, Tsukuba, Ibaraki (Japan); Kanda, H.; Morita, Y.; Ohshima, T.

    1997-03-01

    Phosphorus is among potential n-type dopants in diamond. High pressure synthetic diamond crystals of type IIa implanted with high energy (9-18 MeV) phosphorus ions have been studied by using electron spin resonance (ESR) technique. The intensity and the linewidth of the ESR signal attributed to the dangling bond of the amorphous phase varied with the implantation dose, suggesting the nature of the amorphization varies with the dose. The ESR signals of point defects have been observed in the low dose as-implanted crystals and in the high dose crystals annealed at high temperature and at high pressure. (author)

  8. Study of beryllium redeposition under bombardment by high intensity -low energy- hydrogen ion beams

    Energy Technology Data Exchange (ETDEWEB)

    Gureev, V.M.; Guseva, M.I.; Danelyan, L.S. [Russian Research Centre Kurchatov Inst., Moscow (Russian Federation)] [and others

    1998-01-01

    The results of studying the erosion of beryllium under an effect of intense ion fluxes with the energy of 250 eV, at the fluences {approx}10{sup 2}1 cm{sup -2}, at the MAGRAS-stand are given. The operating conditions under which a practically-complete redeposition of the sputtered beryllium upon the target surface were experimentally-realized. A change in the microstructure of a beryllium target under sputtering and redeposition is analyzed. Some technological applications are considered. (author)

  9. Studying the applicability of densities mixture unfolding for heavy ion jet spectra in the ALICE experiment

    CERN Document Server

    Hackstock, Philip

    2016-01-01

    The results of a three months summer project from July 4th 2016 to September 23rd are presented in this summer student report.\\\\ The method presented in the paper\\footnote{\\url{http://www.sciencedirect.com/science/article/pii/S0168900215000406}} on densities mixture unfolding by Nikolay Gagunashvili and its software implementation were studied. A mind map flowchart, plotting macros and documentation were produced and while an 18 fold performance boost trough parallelization could be achieved, the verdict on the applicability of this method for heavy ion jet spectra in the ALICE experiment remains inconclusive. This is mainly due to a lack of time and complexity of the method and its implementation.

  10. SAXS study on the morphology of etched and un-etched ion tracks in apatite

    Directory of Open Access Journals (Sweden)

    Nadzri A.

    2015-01-01

    Full Text Available Natural apatite samples were irradiated with 185 MeV Au and 2.3 GeV Bi ions to simulate fission tracks. The resulting track morphology was investigated using synchrotron small angle x-ray scattering (SAXS measurements before and after chemical etching. We present preliminary results from the SAXS measurement showing the etching process is highly anisotropic yielding faceted etch pits with a 6-fold symmetry. The measurements are a first step in gaining new insights into the correlation between etched and unetched fission tracks and the use of SAXS as a tool for studying etched tracks.

  11. A Study of the Ion Hose Instability in the DARHT-II Downstream Transport Region

    Energy Technology Data Exchange (ETDEWEB)

    McCarrick, J F

    2004-11-11

    is created and accelerated up to 18.4 MeV over a distance of about fifty meters. Then the true downstream transport begins: the beam drifts through a matching section in preparation for the kicker, over some ten meters; the long-pulse beam then travels about four more meters from the kicker to the main dump. In the accelerator, the beam energy is obviously not constant; the transport is emittance-dominated and done through nearly continuous solenoidal focusing. In the downstream section, there are only two discrete solenoids over the entire fourteen meters and the transport is largely ballistic. Since ion hose has been studied in the accelerator [3] and since the lack of continuous focusing is considered a concern with respect to ion hose in the downstream section, the focus of this study is only from the exit of the accelerator to the main dump. A more in-depth description of the baseline (ion-free) DARHT-II downstream transport, including description of the actual transport elements and their use, will not be presented in this document; such details can be found in the documents cited in the References. The study of these effects will be done in stages. In the next section, the nature of the residual gas in the vacuum system will be considered, along with the various assumptions made in characterizing the creation of ions. Then the ion hose instability will be described in its simplest form. In the fourth section, additional features of ion hose will then be presented which attempt to capture some of the key behavior. Then a much more complete model using particle-in-cell (PIC) numerical techniques will be described, followed by details of the specific implementation used here. In section seven, the code will be benchmarked against results published in the literature. Section eight has the most relevant material: the actual study of the effects of ion hose and background gas focusing in the DARHT-II downstream transport region. In section nine, a simple experiment

  12. NMR Study of Ion Dynamics and Charge Storage in Ionic Liquid Supercapacitors

    Science.gov (United States)

    2015-01-01

    Ionic liquids are emerging as promising new electrolytes for supercapacitors. While their higher operating voltages allow the storage of more energy than organic electrolytes, they cannot currently compete in terms of power performance. More fundamental studies of the mechanism and dynamics of charge storage are required to facilitate the development and application of these materials. Here we demonstrate the application of nuclear magnetic resonance spectroscopy to study the structure and dynamics of ionic liquids confined in porous carbon electrodes. The measurements reveal that ionic liquids spontaneously wet the carbon micropores in the absence of any applied potential and that on application of a potential supercapacitor charging takes place by adsorption of counterions and desorption of co-ions from the pores. We find that adsorption and desorption of anions surprisingly plays a more dominant role than that of the cations. Having elucidated the charging mechanism, we go on to study the factors that affect the rate of ionic diffusion in the carbon micropores in an effort to understand supercapacitor charging dynamics. We show that the line shape of the resonance arising from adsorbed ions is a sensitive probe of their effective diffusion rate, which is found to depend on the ionic liquid studied, as well as the presence of any solvent additives. Taken as whole, our NMR measurements allow us to rationalize the power performances of different electrolytes in supercapacitors. PMID:25973552

  13. NMR Study of Ion Dynamics and Charge Storage in Ionic Liquid Supercapacitors.

    Science.gov (United States)

    Forse, Alexander C; Griffin, John M; Merlet, Céline; Bayley, Paul M; Wang, Hao; Simon, Patrice; Grey, Clare P

    2015-06-10

    Ionic liquids are emerging as promising new electrolytes for supercapacitors. While their higher operating voltages allow the storage of more energy than organic electrolytes, they cannot currently compete in terms of power performance. More fundamental studies of the mechanism and dynamics of charge storage are required to facilitate the development and application of these materials. Here we demonstrate the application of nuclear magnetic resonance spectroscopy to study the structure and dynamics of ionic liquids confined in porous carbon electrodes. The measurements reveal that ionic liquids spontaneously wet the carbon micropores in the absence of any applied potential and that on application of a potential supercapacitor charging takes place by adsorption of counterions and desorption of co-ions from the pores. We find that adsorption and desorption of anions surprisingly plays a more dominant role than that of the cations. Having elucidated the charging mechanism, we go on to study the factors that affect the rate of ionic diffusion in the carbon micropores in an effort to understand supercapacitor charging dynamics. We show that the line shape of the resonance arising from adsorbed ions is a sensitive probe of their effective diffusion rate, which is found to depend on the ionic liquid studied, as well as the presence of any solvent additives. Taken as whole, our NMR measurements allow us to rationalize the power performances of different electrolytes in supercapacitors.

  14. Measurement of storage time, estimation of ion number and study of ...

    Indian Academy of Sciences (India)

    destructive method. Storage time of Eu+ ions achieved in vacuum was improved by orders of magnitude employing buffer gas cooling. The experimentally detected signal was fitted to the ion response signal and the total number of ions trapped was ...

  15. Natural products as tools for studies of ligand-gated ion channels

    DEFF Research Database (Denmark)

    Strømgaard, Kristian

    2005-01-01

    Ligand-gated ion channels, or ionotropic receptors, constitute a group of membrane-bound proteins that regulate the flux of ions across the cell membrane. In the brain, ligand-gated ion channels mediate fast neurotransmission. They are crucial for normal brain function and involved in many diseas...

  16. Interpenetrated Networks between Graphitic Carbon Infilling and Ultrafine TiO2 Nanocrystals with Patterned Macroporous Structure for High-Performance Lithium Ion Batteries.

    Science.gov (United States)

    Zheng, Wenji; Yan, Zhijun; Dai, Yan; Du, Naixu; Jiang, Xiaobin; Dai, Hailing; Li, Xiangcun; He, Gaohong

    2017-06-21

    Interpenetrated networks between graphitic carbon infilling and ultrafine TiO2 nanocrystals with patterned macropores (100-200 nm) were successfully synthesized. Polypyrrole layer was conformably coated on the primary TiO2 nanoparticles (∼8 nm) by a photosensitive reaction and was then transformed into carbon infilling in the interparticle mesopores of the TiO2 nanoparticles. Compared to the carbon/graphene supported TiO2 nanoparticles or carbon coated TiO2 nanostructures, the carbon infilling would provide a conductive medium and buffer layer for volume expansion of the encapsulated TiO2 nanoparticles, thus enhancing conductivity and cycle stability of the C-TiO2 anode materials for lithium ion batteries (LIBs). In addition, the macropores with diameters of 100-200 nm in the C-TiO2 anode and the mesopores in carbon infilling could improve electrolyte transportation in the electrodes and shorten the lithium ion diffusion length. The C-TiO2 electrode can provide a large capacity of 192.8 mA h g-1 after 100 cycles at 200 mA g-1, which is higher than those of the pure macroporous TiO2 electrode (144.8 mA h g-1), C-TiO2 composite electrode without macroporous structure (128 mA h g-1), and most of the TiO2 based electrodes in the literature. Importantly, the C-TiO2 electrode exhibits a high rate performance and still delivers a high capacity of ∼140 mA h g-1 after 1000 cycles at 1000 mA g-1 (∼5.88 C), suggesting good lithium storage properties of the macroporous C-TiO2 composites with high capacity, cycle stability, and rate capability. This work would be instructive for designing hierarchical porous TiO2 based anodes for high-performance LIBs.

  17. Ion Channel ElectroPhysiology Ontology (ICEPO) - a case study of text mining assisted ontology development.

    Science.gov (United States)

    Elayavilli, Ravikumar Komandur; Liu, Hongfang

    2016-01-01

    Computational modeling of biological cascades is of great interest to quantitative biologists. Biomedical text has been a rich source for quantitative information. Gathering quantitative parameters and values from biomedical text is one significant challenge in the early steps of computational modeling as it involves huge manual effort. While automatically extracting such quantitative information from bio-medical text may offer some relief, lack of ontological representation for a subdomain serves as impedance in normalizing textual extractions to a standard representation. This may render textual extractions less meaningful to the domain experts. In this work, we propose a rule-based approach to automatically extract relations involving quantitative data from biomedical text describing ion channel electrophysiology. We further translated the quantitative assertions extracted through text mining to a formal representation that may help in constructing ontology for ion channel events using a rule based approach. We have developed Ion Channel ElectroPhysiology Ontology (ICEPO) by integrating the information represented in closely related ontologies such as, Cell Physiology Ontology (CPO), and Cardiac Electro Physiology Ontology (CPEO) and the knowledge provided by domain experts. The rule-based system achieved an overall F-measure of 68.93% in extracting the quantitative data assertions system on an independently annotated blind data set. We further made an initial attempt in formalizing the quantitative data assertions extracted from the biomedical text into a formal representation that offers potential to facilitate the integration of text mining into ontological workflow, a novel aspect of this study. This work is a case study where we created a platform that provides formal interaction between ontology development and text mining. We have achieved partial success in extracting quantitative assertions from the biomedical text and formalizing them in ontological

  18. Analysing Health Professionals' Learning Interactions in an Online Social Network: A Longitudinal Study.

    Science.gov (United States)

    Li, Xin; Verspoor, Karin; Gray, Kathleen; Barnett, Stephen

    2016-01-01

    This paper summarises a longitudinal analysis of learning interactions occurring over three years among health professionals in an online social network. The study employs the techniques of Social Network Analysis (SNA) and statistical modeling to identify the changes in patterns of interaction over time and test associated structural network effects. SNA results indicate overall low participation in the network, although some participants became active over time and even led discussions. In particular, the analysis has shown that a change of lead contributor results in a change in learning interaction and network structure. The analysis of structural network effects demonstrates that the interaction dynamics slow down over time, indicating that interactions in the network are more stable. The health professionals may be reluctant to share knowledge and collaborate in groups but were interested in building personal learning networks or simply seeking information.

  19. Study on characteristic frequencies of ELF emissions and estimation of ion constituents in the vicinity of magnetic equator

    Science.gov (United States)

    Matsuda, S.; Kasahara, Y.; Goto, Y.

    2012-12-01

    The AKEBONO satellite has been operated continuously over 2 cycles of solar activity. Long-term observation data obtained by the AKEBONO satellite is very valuable to clarify plasma dynamics in the magnetosphere. Recently, the mechanism of wave-particle interaction around the radiation belt has attracted considerable attention. The ELF receiver, which is a sub-system of the VLF instruments onboard AKEBONO, measures waveforms below 50Hz for one component of electric field and three components of magnetic field, or waveforms below 100Hz for one component of electric and magnetic field, respectively. It was reported that ion cyclotron waves were observed near magnetic equator by the receiver [1] . It is well known that ion cyclotron wave generally propagates with a left-handed circularly polarization, but there exists right-handed polarized ion cyclotron wave below a characteristic frequency called 'crossover' in the presence of two or more kinds of ions such as oxygen and helium ions besides proton. As the crossover frequency can be derived theoretically from relative constituents of ions in plasma, it is possible to estimate the ion constituents by identifying the crossover frequency observationally. In this study, we analyze polarization of the ion cyclotron waves observed around the magnetic equator by the ELF receiver onboard AKEBONO, and report an example of ion cyclotron wave whose polarization changes from left-handed to right-handed at crossover frequency. As a next step, we estimate the ion constituents according to the polarization analysis. Furthermore, these phenomena sometimes have characteristic lower cut-off frequencies changing along the trajectories of Akebono. According to our work, it was found that the cutoff frequency is frequently in agreement with 1/n of proton's cyclotron frequency, where "n" is integer. The lower cut-off of ion cyclotron wave can be theoretically derived considering certain ion constituents of the background cold plasma

  20. CompTIA Network+ Study Guide Exam N10-005

    CERN Document Server

    Lammle, Todd

    2012-01-01

    Todd Lammle's latest CompTIA Network+ Study Guide, now updated for the new exam! CompTIA's Network+ certification tells the world you have the skills to install, configure, and troubleshoot today's basic networking hardware peripherals and protocols. But first, you have to pass the exam! This detailed CompTIA Authorized study guide by networking guru Todd Lammle has everything you need to prepare for the CompTIA's new Network+Exam N10-005. All exam objectives are covered. He thoroughly explains key topics, offers plenty of practical examples, and draws upon his own invaluable 25+ years of netw

  1. Multi-Dielectric Brownian Dynamics and Design-Space-Exploration Studies of Permeation in Ion Channels.

    Science.gov (United States)

    Siksik, May; Krishnamurthy, Vikram

    2017-09-01

    This paper proposes a multi-dielectric Brownian dynamics simulation framework for design-space-exploration (DSE) studies of ion-channel permeation. The goal of such DSE studies is to estimate the channel modeling-parameters that minimize the mean-squared error between the simulated and expected "permeation characteristics." To address this computational challenge, we use a methodology based on statistical inference that utilizes the knowledge of channel structure to prune the design space. We demonstrate the proposed framework and DSE methodology using a case study based on the KcsA ion channel, in which the design space is successfully reduced from a 6-D space to a 2-D space. Our results show that the channel dielectric map computed using the framework matches with that computed directly using molecular dynamics with an error of 7%. Finally, the scalability and resolution of the model used are explored, and it is shown that the memory requirements needed for DSE remain constant as the number of parameters (degree of heterogeneity) increases.

  2. Social Networking Sites in The Netherlands; an Explorative Study

    NARCIS (Netherlands)

    Constantinides, Efthymios; Lorenzo-Romero, C.; Alarcon-del-Amo, Maria-del-Carmen

    2011-01-01

    The rampant growth of social networking has become an issue of attention and interest by commercial organizations. Based on a national sample this paper investigates the demographics, profiles and behavior of participants of Social Networking sites in The Netherlands. The paper provides a typology

  3. Neural Networks for Language Identification: A Comparative Study.

    Science.gov (United States)

    MacNamara, Shane; Cunningham, Padraig; Byrne, John

    1998-01-01

    Analyzes a neural network for its ability to perform a task involving identification of the language entries in a 19th-century library catalog containing entries in 14 different languages. Compares the neural network's performance with that of trigrams and a suffix/morphology analysis; the trigrams prove to be superior. (AEF)

  4. Error Propagation in Geodetic Networks Studied by FEMLAB

    DEFF Research Database (Denmark)

    Borre, Kai

    2009-01-01

    Geodetic networks can be described by discrete models. The observations may be height differences, distances, and directions. Geodesists always make more observations than necessary and estimate the solution by using the principle of least squares. Contemporary networks often contain several thou...

  5. Study on Countermeasures on Moral Education through School Network

    Science.gov (United States)

    Wang, Zhi-guo

    2009-01-01

    Nowadays, the society witnesses the rapid development of internet information. Network has not only brought active and positive convenience to students, but also the passive and negative impact, so network moral education can not be ignored. The present paper attempts to combine the traditional moral education with online interactivity education,…

  6. Molecular dynamics simulation study of the "stay or leave" problem for two magnesium ions in gene transcription.

    Science.gov (United States)

    Wu, Shaogui

    2017-06-01

    Two magnesium ions play important roles in nucleotide addition cycle (NAC) of gene transcription. However, at the end of each NAC, why does one ion stay in the active site while the other ion leaves with product pyrophosphate (PPi )? This problem still remains obscure. In this work, we studied the problem using all-atom molecular dynamics simulation combined with steered molecular dynamics and umbrella sampling simulation methods. Our simulations reveal that although both ions are located in the active site after chemistry, their detailed positions are not symmetrical, leading to their different forces from surrounding groups. One ion makes weaker contacts with PPi than the whole protein. Hence, PPi release is less likely to take it away. The other one forms tighter contacts with PPi relative to the protein. The formed (Mg2+ -PPi )2- complex is found to break the contacts with surrounding protein residues one by one so as to dissociate from the active site. This effectively avoids the coexistence of two ions in the active site after PPi release and guarantees a reasonable Mg2+ ion number in the active site for the next NAC. The observations from this work can provide valuable information for comprehensively understanding the molecular mechanism of transcription. Proteins 2017; 85:1002-1007. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

  7. Phase-Controlled Iron Oxide Nanobox Deposited on Hierarchically Structured Graphene Networks for Lithium Ion Storage and Photocatalysis

    Science.gov (United States)

    Yun, Sol; Lee, Young-Chul; Park, Ho Seok

    2016-01-01

    The phase control, hierarchical architecturing and hybridization of iron oxide is important for achieving multifunctional capability for many practical applications. Herein, hierarchically structured reduced graphene oxide (hrGO)/α-Fe2O3 and γ-Fe3O4 nanobox hybrids (hrGO/α-Fe and hrGO/γ-Fe NBhs) are synthesized via a one-pot, hydrothermal process and their functionality controlled by the crystalline phases is adapted for energy storage and photocatalysis. The three-dimensionally (3D) macroporous structure of hrGO/α-Fe NBhs is constructed, while α-Fe2O3 nanoboxes (NBs) in a proximate contact with the hrGO surface are simultaneously grown during a hydrothermal treatment. The discrete α-Fe2O3 NBs are uniformly distributed on the surface of the hrGO/α-Fe and confined in the 3D architecture, thereby inhibiting the restacking of rGO. After the subsequent phase transition into γ-Fe3O4, the hierarchical structure and the uniform distribution of NBs are preserved. Despite lower initial capacity, the hrGO/α-Fe NBhs show better rate and cyclic performances than those of commercial rGO/α-Fe due to the uniform distribution of discrete α-Fe2O3 NBs and electronic conductivity, macroporosity, and buffering effect of the hrGO for lithium ion battery anodes. Moreover, the catalytic activity and kinetics of hrGO/γ-Fe NBhs are enhanced for photo-Fenton reaction because of the uniform distribution of discrete γ-Fe3O4 NBs on the 3D hierarchical architecture.

  8. Absorption and fluorescence studies of Sm{sup 3+} ions in lead containing sodium fluoroborate glasses

    Energy Technology Data Exchange (ETDEWEB)

    Madhukar Reddy, C.; Dillip, G.R.; Mallikarjuna, K.; Zulifiqar Ali Ahamed, Sd. [Department of Physics, Sri Venkateswara University, Tirupati 517502 (India); Sudhakar Reddy, B. [Department of Physics, Sri Venkateswara Degree College, Kadapa 516003 (India); Deva Prasad Raju, B., E-mail: drdevaprasadraju@gmail.co [Department of Future Studies, Sri Venkateswara University, Tirupati 517 502 (India)

    2011-07-15

    Lead containing calcium zinc sodium fluoroborate glasses (LCZSFB) with molar composition of 20PbO+5CaO+5ZnO+10NaF+(60-x) B{sub 2}O{sub 3}+x Sm{sub 2}O{sub 3}, (x=0.1, 0.25, 0.5, 1.0 and 2.0 mol%) were prepared and investigated by the XRD, FTIR, optical absorption, photoluminescence and decay curve analysis. Judd-Ofelt theory was applied to the experimental oscillator strengths to evaluate the phenomenological J-O intensity parameters {Omega}{sub {lambda}} ({lambda}=2, 4 and 6). Using the J-O intensity parameters as well as from the emission and decay measurements, various radiative parameters such as transition probabilities (A{sub R}), radiative lifetimes ({tau}{sub R}), measured lifetimes ({tau}{sub m}), calculated branching ratios ({beta}{sub R}), measured branching ratios ({beta}{sub m}), effective bandwidth ({Delta}{lambda}{sub eff}) and stimulated emission cross sections {sigma}({lambda}{sub p}) have been calculated for the excited {sup 4}G{sub 5/2} luminescent level. The nature of decay curves of {sup 4}G{sub 5/2} level for different Sm{sup 3+} ion concentrations in all LCZSFB glasses has been analyzed and the lifetimes are noticed to decrease with increase of concentration. The concentration quenching has been attributed to the energy transfer through the cross-relaxation between Sm{sup 3+} ions. Based on these results, the utility of Sm{sup 3+} ions doped lead containing fluoroborate glasses as laser active materials in the visible region is discussed. - Highlights: {yields} In this study, we prepared LCZSFB glasses for different concentrations of Sm{sup 3+} ions. {yields} We characterize the prepared glasses with XRD, FTIR, absorption, emission and decay curve analysis. {yields} We used Judd-Ofelt theory to calculate oscillator strengths, J-O intensity parameters and different radiative properties. {yields} In this study, we conclude that Sm{sup 3+}-doped LCZSFB glasses are useful for the development of lasers and photonic devices in the visible region.

  9. INNOVATION NETWORKS AND MARKETING MIX: AN EXPLORATORY STUDY ON PRODUCT'S DEVELOPMENT

    Directory of Open Access Journals (Sweden)

    Thel Augusto Monteiro

    2013-12-01

    Full Text Available The purpose of this paper is to present how innovation networks can be used to develop a new product or service, using the marketing compound. The study methodology consists of an exploratory research from literature review on this subject. After an initial discussion of the characteristics of innovation networks and marketing functions, the study presents proposals that allow adequately addressing the main difficulties in the management of marketing in innovation networks. Through this study it can be stated that these networks have been identified as an attractive alternative for the development of new products, when using the marketing mix, given the dynamics of the contemporary market. Innovation networks bring a lot of benefits to companies that embrace the relationship between these networks and marketing. The discussion reveals that the structure in the form of innovation networks can bring effective results in the organization which adopt it, providing competitiveness and adaptability in the face of its target market.

  10. Noninvasive microelectrode ion flux estimation technique (MIFE) for the study of the regulation of root membrane transport by cyclic nucleotides

    KAUST Repository

    Ordoñez, Natalia Maria

    2013-09-03

    Changes in ion permeability and subsequently intracellular ion concentrations play a crucial role in intracellular and intercellular communication and, as such, confer a broad array of developmental and adaptive responses in plants. These changes are mediated by the activity of plasma-membrane based transport proteins many of which are controlled by cyclic nucleotides and/or other signaling molecules. The MIFE technique for noninvasive microelectrode ion flux measuring allows concurrent quantification of net fluxes of several ions with high spatial (μm range) and temporal (ca. 5 s) resolution, making it a powerful tool to study various aspects of downstream signaling events in plant cells. This chapter details basic protocols enabling the application of the MIFE technique to study regulation of root membrane transport in general and cyclic nucleotide mediated transport in particular. © Springer Science+Business Media New York 2013.

  11. Temperature dependence of ion pairing of a potassium salt in nonaqueous liquid and polymer electrolytes: X-ray absorption studies

    Energy Technology Data Exchange (ETDEWEB)

    Yang, X.Q.; Lee, H.S.; McBreen, J. (Brookhaven National Laboratory, Upton, New York 11973 (United States)); Xu, Z.S.; Skotheim, T.A. (Moltech Corporation, Stony Brook, New York 11794-2275 (United States)); Okamoto, Y. (Polytechnic University, Brooklyn, New York 11201 (United States)); Lu, F. (CFFLS, University of Kentucky, Lexington, Kentucky 40506 (United States))

    1994-08-15

    Near-edge x-ray absorption fine structure spectroscopy was used to study the effect of temperature on ion pairing of a potassium salt in a modified carbonate (MC3) solution and in a poly(ethylene oxide)-potassium salt complex that used MC3 as a plasticizer. The modified carbonate was made by attaching three ethylene oxide units to the four position of ethylene carbonate. Spectra were obtained, at the [ital K] edge of potassium, over the temperature range of 25--110 [degree]C. Studies of reference systems showed a correlation between ion pairing and white line splitting in the near-edge region of the spectra. The degree of white line splitting was used as a qualitative indicator of the degree of ion pairing as a function of temperature. The results indicate that, in both systems, the number of ion pairs increases with increasing temperature.

  12. Kinetic and equilibrium study for the sorption of Pb(II ions from aqueous phase by water hyacinth (Eichhornia crassipes

    Directory of Open Access Journals (Sweden)

    Gerald. K. Muthakia

    2012-08-01

    Full Text Available This paper reports the kinetic and equilibrium studies of Eichhornia crassipes root biomass as a biosorbent for Pb(II ions from aqueous system. Batch adsorption studies were carried out to examine the influence of various parameters such as the pH, contact time, adsorbent dose, initial metal ion concentration, temperature and agitation speed on the metal ion uptake. Uptake of Pb(II ions on the E. crassipes roots showed a pH-dependent profile. The maximum metal uptake values were 164 μg/mL. Langmuir model fitted the experimental sorption equilibrium data with a good fit (R2 › 0.99. The biosorption kinetics was described by the pseudo-second-order model (R2 › 0.99.DOI: http://dx.doi.org/10.4314/bcse.v26i2.3

  13. Studies of the Dynamics of Ion Molecule Collisions Using Cross Beam Technique.

    Science.gov (United States)

    Abbas, Isam Ahmed

    Available from UMI in association with The British Library. Requires signed TDF. The work presented in this thesis involved assembling and testing an apparatus designed to observe photon-scattered ion coincidences in crossed beam arrangement. The crossed beams technique has been used to study the scattering of a fast atomic ion of helium (He^+) by argon gas atoms. The results are reported for collision energies between 100-900eV. The data of reduced cross sections show a pure elastic process at energies 100eV and 200eV. At higher energies there is a region of pure elastic process at small angles but at large angles there is a small inelastic component. The reduced cross section at 600eV is in good agreement with the data extracted from Barat et al (1970) (62) especially in the region of pure elastic scattering (small angles). The deflection function and repulsive potential show reasonable agreement with the deflection function and repulsive potential obtained by processing the data of Barat et al (1970) in the same way that our data were processed. The coincidence measurement was one of the main objectives of designing this apparatus. Crossed beams of He^{+} on N _2 were set up and the time correlation between the scattered ions of He^{+} at angle 2.1^circ and photons of wavelength 337.1nm emitted from transition of C ^3pi_{rm u} to B^3pi_{rm u} was recorded. The feasibility calculation and the result obtained at a single scattering angle proves that the required result is not far from reach.

  14. Thermal Emission of Alkali Metal Ions from Al30-Pillared Montmorillonite Studied by Mass Spectrometric Method.

    Science.gov (United States)

    Motalov, V B; Karasev, N S; Ovchinnikov, N L; Butman, M F

    2017-01-01

    The thermal emission of alkali metal ions from Al 30 -pillared montmorillonite in comparison with its natural form was studied by mass spectrometry in the temperature range 770-930 K. The measurements were carried out on a magnetic mass spectrometer MI-1201. For natural montmorillonite, the densities of the emission currents ( j ) decrease in the mass spectrum in the following sequence (T = 805 K, A/cm 2 ): K + (4.55 · 10 -14 ), Cs + (9.72 · 10 -15 ), Rb + (1.13 · 10 -15 ), Na + (1.75 · 10 -16 ), Li + (3.37 · 10 -17 ). For Al 30 -pillared montmorillonite, thermionic emission undergoes temperature-time changes. In the low-temperature section of the investigated range (770-805 K), the value of j increases substantially for all ions in comparison with natural montmorillonite (T = 805 K, A/cm 2 ): Cs + (6.47 · 10 -13 ), K + (9.44 · 10 -14 ), Na + (3.34 · 10 -15 ), Rb + (1.77 · 10 -15 ), and Li + (4.59 · 10 -16 ). A reversible anomaly is observed in the temperature range 805-832 K: with increasing temperature, the value of j of alkaline ions falls abruptly. This effect increases with increasing ionic radius of M + . After a long heating-up period, this anomaly disappears and the ln j - 1/ T dependence acquires a classical linear form. The results are interpreted from the point of view of the dependence of the efficiency of thermionic emission on the phase transformations of pillars.

  15. Study of lithium ion exchange by two synthetic zeolites: Kinetics and equilibrium.

    Science.gov (United States)

    Navarrete-Casas, R; Navarrete-Guijosa, A; Valenzuela-Calahorro, C; López-González, J D; García-Rodríguez, A

    2007-02-15

    We examined the exchange of univalent cations (Na+ and H+) retained on two commercially available synthetic zeolites with Li+ ions present in aqueous solutions in contact with the solids with a view to preparing effective controlled-release pharmaceutical forms. The studied zeolites were manufactured by Merck and featured channel diameters of 0.5 (Zeolite 5A, Ref. 1.05705.250, designated Z-05 in this work) and 1.0 nm (Zeolite 13X, Ref. 1.05703.250, designated Z-10 here). The XRD technique revealed that Z-05 possesses an LTA structure derived from that of sodalite and Z-10 a faujasite-type structure. Their exchange capacities were found to be 2.72 and 3.54 meq/g. The Z-Na + Li(+) / Z-Li + Na(+) and Z-H + Li(+) / Z-Li + H(+) ion-exchange processes were found to be reversible and their kinetic laws to obey the equation (-dC/dt) = k(a) x C(n) x (1-theta) - (k(d) x theta), with n = 1 for Z-10 and n = 2 for Z-05. Based on the equilibrium results, the overall processes involve one (with Z-05) or two single ion-exchange processes (with Z-10). In both cases, the equations that govern equilibrium are direct results of the kinetic laws. Thus, the first process-the one with only Z-05-involves the retention of Li+ cations at anionic sites on the outer surface of the solid and their access to the larger pores; the second process-which occurs with Z-10 only-involves the retention of lithium(I) cations within the zeolite channels. In both systems, the exchange with Li+ (from the aqueous solution) is easier than that with H+; this is consistent with our kinetic, equilibrium, and thermodynamic results.

  16. ion with phenolate ions

    Indian Academy of Sciences (India)

    Administrator

    Photoinduced electron transfer (PET) reaction of homoleptic tris-chelated polypyridine ruthenium(II) complexes with phenolate ions is sensitive to the structure of the ligand of the Ru(II) complex as well as of the phenolate ions 1. In recent years 2 the photophysical and photochemical properties of Ru(II) complexes based on ...

  17. Spectroscopic study of energetic helium-ion irradiation effects on nuclear graphite tiles

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Do Wan; Lee, K.W. [Department of Physics, Korea University, Seoul 136-713 (Korea, Republic of); Choi, D.M.; Noh, S.J.; Kim, H.S. [Department of Applied Physics, Dankook University, Yongin 448-701 (Korea, Republic of); Lee, Cheol Eui, E-mail: rscel@korea.ac.kr [Department of Physics, Korea University, Seoul 136-713 (Korea, Republic of)

    2016-02-01

    Highlights: • Energetic helium-ion irradiation on nuclear graphite tiles studied for plasma facing components. • XPS reveals recrystallization at low dose irradiation and DLC sites at higher doses. • Raman spectroscopy reveals increasing diamond-like defects and structural deformation. • Average inter-defect distance obtained as a function of irradiation dose from Raman intensities. - Abstract: Helium ion-irradiation effects on the nuclear graphite tiles were studied in order to understand the structural modifications and damages that can be produced by fusion reaction in tokamaks. The surface morphological changes due to increasing dose of the irradiation were examined by the field-effect scanning electron microscopy, and X-ray photoelectron spectroscopy elucidated the changes in the shallow surface bonding configurations caused by the energetic irradiation. Raman spectroscopy revealed the structural defects and diamond-like carbon sites that increased with increasing irradiation dose, and the average inter-defect distance was found from the Raman peak intensities as a function of the irradiation dose.

  18. Mass measurements of exotic ions in the heavy mass region for nuclear structure studies at ISOLTRAP

    Energy Technology Data Exchange (ETDEWEB)

    Borgmann, Christopher

    2012-11-07

    The mass is a unique fingerprint of each nucleus as it reflects the sum of all interactions within it. Comparing experimental mass values with theoretical calculations provides an important benchmark of how well the role of these interactions is already understood. By investigating differences of experimental binding energies, such as two-neutron separation energies (S{sub 2n}), valuable indications for nuclear-structure studies are provided. The present thesis contributes to these studies providing new high-precision mass measurements especially in the heavy-mass region. Here, nuclear theory is heavily challenged due to the large number of nucleons. The data have been obtained at the Penning-trap mass spectrometer ISOLTRAP located at the radioactive-ion-beam facility Isolde at CERN. For the determination of the masses, the time-of-flight ion-cyclotron-resonance technique has been applied. While the new mass data for {sup 122-124}Ag continue existing trends in the S{sub 2n} energies, the new mass values for {sup 207,208}Fr render them more precisely. In the case of the mass values for {sup 184,186,190,193-195}Tl a new interesting odd-even effect has been revealed. The comparison of the measured mass values with theoretical models furthermore demonstrates significant problems in reproducing the strength of the pairing correctly. This is of special interest for the discussion about shape coexistence in the region around the doubly-magic {sup 208}Pb.

  19. Study of resonance production as a probe of heavy-ion collisions with the ALICE detector

    CERN Multimedia

    CERN. Geneva

    2017-01-01

    Hadronic resonances provide a rich set of measurements that can be used to study the properties of ultra-relativistic heavy-ion collisions. Measurements of resonances and long-lived particles provide information about the properties of the late hadronic phase due to the presence of scattering effects that can modify resonance yields. Resonances can also be used along with long-lived hadrons to study the various mechanisms that shape particle pT spectra, including in-medium energy loss, radial flow, and recombination. Measurements of resonances in pp and p-Pb collisions serve as baselines for measurements in heavy-ion collisions, provide input for tuning QCD-inspired event generators, and aid searches for collective behavior in small systems. I will present measurements of a wide variety of hadronic resonances, including some of the most recent results presented at the Quark Matter conference. By comparing measurements of resonances with different masses, lifetimes, and quark contents in pp, p-Pb, and Pb-Pb co...

  20. Electrical and electrochemical studies on sodium ion-based gel polymer electrolytes

    Science.gov (United States)

    Isa, K. B. Md; Othman, L.; Hambali, D.; Osman, Z.

    2017-09-01

    Gel polymer electrolytes (GPEs) have captured great attention because of their unique properties such as good mechanical stability, high flexibility and high conductivity approachable to that of the liquid electrolytes. In this work, we have prepared sodium ion conducting gel polymer electrolyte (GPE) films consisting of polyvinylidenefluoride-co-hexafluoropropylene (PVdF-HFP) as a polymer host using the solution casting technique. Sodium trifluoromethane- sulfonate (NaCF3SO3) was used as an ionic salt and the mixture of ethylene carbonate (EC) and propylene carbonate (PC) as a plasticizing solvent. Impedance spectroscopy measurements were carried out to determine the ionic conductivity of the GPE films. The sample containing 20 wt.% of NaCF3SO3 salt exhibits the highest room temperature ionic conductivity of 2.50 × 10-3 S cm-1. The conductivity of the GPE films was found to depend on the salt concentration that added to the films. The ionic and cationic transference numbers of GPE films were estimated by DC polarization and the combination of AC and DC polarization method, respectively. The results had shown that both ionic and cationic transference numbers are consistent with the conductivity studies. The electrochemical stability of the GPE films was tested using linear sweep voltammetry (LSV) and the value of working voltage range appears to be high enough to be used as an electrolyte in sodium batteries. The cyclic voltammetry (CV) studies confirmed the sodium ion conduction in the GPE films.