Experimental validation of CFD mass transfer simulations in flat channels with non-woven net spacers
Li, F.; Meindersma, G.W.; de Haan, A.B.; Reith, T.
2004-01-01
The objective of the present paper is to validate experimentally the mass transfer simulations presented in a previous paper by the same authors [J. Membr. Sci. 208 (2002) 289]. In the present study, mass transfer coefficients were obtained by the limiting current method. The results from CFD
A net-jet flow system for mass transfer and microsensor studies of sinking aggregates
DEFF Research Database (Denmark)
Ploug, H.; Jørgensen, BB
1999-01-01
A flow system was developed which enables studies of hydrodynamics and mass transfer in freely sinking aggregates. The aggregates stabilized their positions in the water phase at an upward flow Velocity which balanced and opposed the sinking velocity of the individual aggregate. The flow field...
Vrentas, James S
2013-01-01
The book first covers the five elements necessary to formulate and solve mass transfer problems, that is, conservation laws and field equations, boundary conditions, constitutive equations, parameters in constitutive equations, and mathematical methods that can be used to solve the partial differential equations commonly encountered in mass transfer problems. Jump balances, Green’s function solution methods, and the free-volume theory for the prediction of self-diffusion coefficients for polymer–solvent systems are among the topics covered. The authors then use those elements to analyze a wide variety of mass transfer problems, including bubble dissolution, polymer sorption and desorption, dispersion, impurity migration in plastic containers, and utilization of polymers in drug delivery. The text offers detailed solutions, along with some theoretical aspects, for numerous processes including viscoelastic diffusion, moving boundary problems, diffusion and reaction, membrane transport, wave behavior, sedime...
Baehr, Hans Dieter
2011-01-01
This comprehensive textbook provides a solid foundation of knowledge on the principles of heat and mass transfer and shows how to solve problems by applying modern methods. The basic theory is developed systematically, exploring in detail the solution methods to all important problems. The thoroughly revised 3rd edition includes an introduction to the numerical solution of Finite Elements. A new section on heat and mass transfer in porous media has also been added. The book will be useful not only to upper-level and graduate students, but also to practicing scientists and engineers, offering a firm understanding of the principles of heat and mass transfer, and showing how to solve problems by applying modern methods. Many completed examples and numerous exercises with solutions facilitate learning and understanding, and an appendix includes data on key properties of important substances.
Karwa, Rajendra
2017-01-01
This textbook presents the classical treatment of the problems of heat transfer in an exhaustive manner with due emphasis on understanding of the physics of the problems. This emphasis is especially visible in the chapters on convective heat transfer. Emphasis is laid on the solution of steady and unsteady two-dimensional heat conduction problems. Another special feature of the book is a chapter on introduction to design of heat exchangers and their illustrative design problems. A simple and understandable treatment of gaseous radiation has been presented. A special chapter on flat plate solar air heater has been incorporated that covers thermo-hydraulic modeling and simulation. The chapter on mass transfer has been written looking specifically at the needs of the students of mechanical engineering. The book includes a large number and variety of solved problems with supporting line diagrams. The author has avoided duplicating similar problems, while incorporating more application-based examples. All the end-...
Mass Transfer with Chemical Reaction.
DeCoursey, W. J.
1987-01-01
Describes the organization of a graduate course dealing with mass transfer, particularly as it relates to chemical reactions. Discusses the course outline, including mathematics models of mass transfer, enhancement of mass transfer rates by homogeneous chemical reaction, and gas-liquid systems with chemical reaction. (TW)
Mass Transfer Method and Apparatus
DEFF Research Database (Denmark)
1995-01-01
.g. polytetrafluoroethylene (PTFE, Teflon $m(3)) membranes, in the form of hollow fibres having gas-containing pores and contacting the second fluid with the inner surface of the membranes. Useful membranes are characterized in that they e.g. have a porosity ($g(e)) of at least 0.50, a mass transfer coefficient of e...
Mass transfer between binary stars
Modisette, J. L.; Kondo, Y.
1980-01-01
The transfer of mass from one component of a binary system to another by mass ejection is analyzed through a stellar wind mechanism, using a model which integrates the equations of motion, including the energy equation, with an initial static atmosphere and various temperature fluctuations imposed at the base of the star's corona. The model is applied to several situations and the energy flow is calculated along the line of centers between the two binary components, in the rotating frame of the system, thereby incorporating the centrifugal force. It is shown that relatively small disturbances in the lower chromosphere or photosphere can produce mass loss through a stellar wind mechanism, due to the amplification of the disturbance propagating into the thinner atmosphere. Since there are many possible sources of the disturbance, the model can be used to explain many mass ejection phenomena.
Zero-Net Mass-Flux Actuator Cavity Vortex
Krieg, Michael; Mohseni, Kamran
2013-11-01
Zero-Net Mass-Flux (ZNMT) devices are used commonly as synthetic jet actuators for flow control in various applications. The authors have recently proposed using larger ZNMF jet actuators for underwater propulsion; similar to squid and jellyfish. Generally the external flow generated by these devices is characterized according to momentum and energy transfer rates, and little attention is paid to the dynamics of flow inside the cavity. In fact the flow inside the cavity, especially during the refilling phase is not only highly dynamic but greatly influences the pressure distribution at the opening as well as the external flow during the following jetting phase. A completely transparent axisymmetric ZNMF cavity was constructed in order to investigate the internal vortex dynamics. The flow is seeded with reflective particles and illumined with a laser sheet bisecting the axis of symmetry. Standard 2D DPIV techniques are used to recover the velocity field in this cross section. During filling it is observed that a starting jet extending from the opening to the inside of the cavity rolls into a vortex ring much like the jetting phase. However, the effect of the cavity walls becomes apparent almost immediately. In this talk we characterize how the circulation within the cavity decays as a function of both cavity/orifice geometry and the mass flux program. In addition a load cell measures the total thrust acting on the device which is used to validate pressure calculations performed on the moving surface inside the cavity, showing excellent agreement. This work is supported by a grant from the Office of Naval Research.
HEAT-MASS TRANSFER IN MOVING MELT
Directory of Open Access Journals (Sweden)
R. I. Yesman
2005-01-01
Full Text Available The paper gives mathematical formation and solution of the heat-mass transfer problem when liquid metals are flowing in the channels of complicated geometry. The problem is solved with the help of numerical methods. A method of control volume is used for finite-difference approximation of transfer equations. The research results can be applied for execution of a numerical experiment while investigating heat-mass transfer in liquid-metal heat-transfer and reological media.
Dynamical mass transfer in cataclysmic binaries
Melia, Fulvio; Lamb, D. Q.
1987-01-01
When a binary comes into contact and mass transfer begins, orbital angular momentum is stored in the accretion disk until the disk couples tidally to the binary system. Taam and McDermott (1987) have suggested that this leads to unstable dynamical mass transfer in many cataclysmic variables in which mass transfer would otherwise be stable, and that it explains the gap between 2 and 3 h in the orbital period distribution of these systems. Here the consequences of this hypothesis for the evolution of cataclysmic binaries are explored. It is found that systems coming into contact longward of the period gap undergo one or more episodes of dynamical mass transfer.
A Simple Experiment for Mass Transfer.
Rodriguez, Jesus M.; Henriquez, Vicente; Macias-Machin, Agustin
1998-01-01
Presents an experiment in which students use laboratory data to calculate the interphase mass transfer coefficient for a fluid passed over a sphere and obtain correlations for solid-gas mass transfer. Students develop a realistic mathematical model to describe the sublimation process. (DDR)
How We Make Mass Transfer Seem Difficult.
Cussler, E. L.
1984-01-01
Indicates that teaching of mass transfer can be improved by: (1) using a single, simple definition of mass transfer coefficients; (2) altering use of analogies; and (3) repeatedly stressing differences between mathematical models used for chemical reactions and the actual chemistry of these reactions. Examples for undergraduate/graduate courses…
Modeling ozone mass transfer in reclaimed wastewater.
Jiang, Pan; Chen, Hsiao-Ting; Babcock, Roger W; Stenstrom, Michael K
2009-01-01
Ozone mass transfer in reclaimed water was evaluated at pilot scale to determine mass-transfer characteristics and reaction kinetics and to assess the use of oxygen as a surrogate to measure this process. Tests were conducted in a 40-L/min pilot plant over a 3-year period. Nonsteady-state mass-transfer analyses for both oxygen and ozone were performed for superficial gas flow rates ranging from 0.13m/min to 0.40m/min. The psi factor, which is the ratio of volumetric mass-transfer coefficients of ozone to oxygen, was determined. The decrease in oxygen transfer rate caused by contaminants in reclaimed water was only 10 to 15% compared to tap water. A simple mathematical model was developed to describe transfer rate and steady state ozone concentration. Ozone decay was modeled accurately as a pseudo first-order reaction between ozone and ozone-demanding materials.
Binary stars: Mass transfer and chemical composition
Lambert, D. L.
1982-01-01
It is noted that mass exchange (and mass loss) within a binary system should produce observable changes in the surface chemical composition of both the mass losing and mass gaining stars as a stellar interior exposed to nucleosyntheses is uncovered. Three topics relating mass exchange and/or mass loss to nucleosynthesis are sketched: the chemical composition of Algol systems; the accretion disk of a cataclysmic variable fed by mass from a dwarf secondary star; and the hypothesis that classical Ba II giants result from mass transfer from a more evolved companion now present as a white dwarf.
Heat and mass transfer in particulate suspensions
Michaelides, Efstathios E (Stathis)
2013-01-01
Heat and Mass Transfer in Particulate Suspensions is a critical review of the subject of heat and mass transfer related to particulate Suspensions, which include both fluid-particles and fluid-droplet Suspensions. Fundamentals, recent advances and industrial applications are examined. The subject of particulate heat and mass transfer is currently driven by two significant applications: energy transformations –primarily combustion – and heat transfer equipment. The first includes particle and droplet combustion processes in engineering Suspensions as diverse as the Fluidized Bed Reactors (FBR’s) and Internal Combustion Engines (ICE’s). On the heat transfer side, cooling with nanofluids, which include nanoparticles, has attracted a great deal of attention in the last decade both from the fundamental and the applied side and has produced several scientific publications. A monograph that combines the fundamentals of heat transfer with particulates as well as the modern applications of the subject would be...
2010-04-01
... section 482 and net section 482 transfer price adjustments. 1.6662-6 Section 1.6662-6 Internal Revenue... described in section 482 and net section 482 transfer price adjustments. (a) In general—(1) Purpose and... (the transactional penalty) or a net section 482 transfer price adjustment (the net adjustment penalty...
Irradiation and mass transfer in low-mass compact binaries
Ritter, H.; Kolb, U.; Zhang, Z. -Y.
2000-01-01
We study the reaction of low-mass stars to anisotropic irradiation and its importance for the long-term evolution of compact binaries binaries. We show by means of a simple homology model that if the energy outflow through the surface layers of a low-mass main sequence star is blocked over a fraction s_eff < 1 of its surface it will inflate only modestly and that the maximum contribution to mass transfer is s_eff times what one obtains in the isotropic case. The duration of this mass transfer...
Mass Transfer Operations for the Practicing Engineer
Theodore, Louis
2011-01-01
Part of the Essential Engineering Calculations Series, this book presents step-by-step solutions of the basic principles of mass transfer operations, including sample problems and solutions and their applications, such as distillation, absorption, and stripping. Presenting the subject from a strictly pragmatic point of view, providing both the principles of mass transfer operations and their applications, with clear instructions on how to carry out the basic calculations needed, the book also covers topics useful for readers taking their professional exams.
Gas mass transfer for stratified flows
Energy Technology Data Exchange (ETDEWEB)
Duffey, R.B. [Brookhaven National Lab., Upton, NY (United States); Hughes, E.D. [CSA, Inc., Idaho Falls, ID (United States)
1995-06-01
We analyzed gas absorption and release in water bodies using existing surface renewal theory. We show a new relation between turbulent momentum and mass transfer from gas to water, including the effects of waves and wave roughness, by evaluating the equilibrium integral turbulent dissipation due to energy transfer to the water from the wind. Using Kolmogoroff turbulence arguments the gas transfer velocity, or mass transfer coefficient, is then naturally and straightforwardly obtained as a non-linear function of the wind speed drag coefficient and the square root of the molecular diffusion coefficient. In dimensionless form, the theory predicts the turbulent Sherwood number to be Sh{sub t} = (2/{radical}{pi})Sc{sup 1/2}, where Sh{sub t} is based on an integral dissipation length scale in the air. The theory confirms the observed nonlinear variation of the mass transfer coefficient as a function of the wind speed; gives the correct transition with turbulence-centered models for smooth surfaces at low speeds; and predicts experimental data from both laboratory and environmental measurements within the data scatter. The differences between the available laboratory and field data measurements are due to the large differences in the drag coefficient between wind tunnels and oceans. The results also imply that the effect of direct aeration due to bubble entrainment at wave breaking is no more than a 20% increase in the mass transfer for the highest speeds. The theory has importance to mass transfer in both the geo-physical and chemical engineering literature.
Gas mass transfer for stratified flows
Energy Technology Data Exchange (ETDEWEB)
Duffey, R.B. [Brookhaven National Lab., Upton, NY (United States); Hughes, E.D. [CSA Inc., Idaho Falls, ID (United States)
1995-07-01
We analyzed gas absorption and release in water bodies using existing surface renewal theory. We show a new relation between turbulent momentum and mass transfer from gas to water, including the effects of waves and wave roughness, by evaluating the equilibrum integral turbulent dissipation due to energy transfer to the water from the wind. Using Kolmogoroff turbulence arguments the gas transfer velocity, or mass transfer coefficient, is then naturally and straightforwardly obtained as a non-linear function of the wind speed drag coefficient and the square root of the molecular diffusion coefficient. In dimensionless form, the theory predicts the turbulent Sherwood number to be Sh{sub t} = (2/{radical}{pi}) Sc{sup 1/2}, where Sh{sub t} is based on an integral dissipation length scale in the air. The theory confirms the observed nonlinear variation of the mass transfer coefficient as a function of the wind speed; gives the correct transition with turbulence-centered models for smooth surfaces at low speeds; and predicts experimental data from both laboratory and environmental measurements within the data scatter. The differences between the available laboratory and field data measurements are due to the large differences in the drag coefficient between wind tunnels and oceans. The results also imply that the effect of direct aeration due to bubble entrainment at wave breaking is no more than a 20% increase in the mass transfer for the highest speeds. The theory has importance to mass transfer in both the geophysical and chemical engineering literature.
Mills, A F
1999-01-01
The Second Edition offers complete coverage of heat transfer with broad up-to-date coverage that includes an emphasis on engineering relevance and on problem solving. Integrates software to assist the reader in efficiently calculations. Carefully orders material to make book more reader-friendly and accessible. Offers an extensive introduction to heat exchange design to enhance the engineering and design content of course to satisfy ABET requirements. For professionals in engineering fields.
Mass transfer cycles in cataclysmic variables
King, A. R.; Frank, J.; Kolb, U.; Ritter, H.
1995-01-01
It is well known that in cataclysmic variables the mass transfer rate must fluctuate about the evolutionary mean on timescales too long to be directly observable. We show that limit-cycle behavior can occur if the radius change of the secondary star is sensitive to the instantaneous mass transfer rate. The only reasonable way in which such a dependence can arise is through irradiation of this star by the accreting component. The system oscillates between high states, in which irradiation causes slow expansion of the secondary and drives an elevated transfer rate, and low states, in which this star contracts.
Conjugate heat and mass transfer in heat mass exchanger ducts
Zhang, Li-Zhi
2013-01-01
Conjugate Heat and Mass Transfer in Heat Mass Exchanger Ducts bridges the gap between fundamentals and recent discoveries, making it a valuable tool for anyone looking to expand their knowledge of heat exchangers. The first book on the market to cover conjugate heat and mass transfer in heat exchangers, author Li-Zhi Zhang goes beyond the basics to cover recent advancements in equipment for energy use and environmental control (such as heat and moisture recovery ventilators, hollow fiber membrane modules for humidification/dehumidification, membrane modules for air purification, desi
Mass Transfer Enhancement in Moving Biofilm Structures
Taherzadeh, Danial; Picioreanu, Cristian; Horn, Harald
2012-01-01
Biofilms are layers of microbial cells growing on an interface and they can form highly complex structures adapted to a wide variety of environmental conditions. Biofilm streamers have a small immobile base attached to the support and a flexible tail elongated in the flow direction, which can vibrate in fast flows. Herein we report numerical results for the role of the periodical movement of biofilm streamers on the nutrient uptake and in general on the solute mass transfer enhancement due to flow-induced oscillations. We developed what to our knowledge is a novel two-dimensional fluid-structure interaction model coupled to unsteady solute mass transport and solved the model using the finite element method with a moving mesh. Results demonstrate that the oscillatory movement of the biofilm tail significantly increases the substrate uptake. The mass transfer coefficient is the highest in regions close to the streamer tip. The reason for substrate transfer enhancement is the increase in speed of tip movement relative to the surrounding liquid, thereby reducing the thickness of the mass transfer boundary layer. In addition, we show that the relative mass transfer enhancement in unsteady conditions compared with the rigid static structure is larger at higher flow velocities, and this relative increase favors a more flexible structure. PMID:22500748
Convective mass transfer around a dissolving bubble
Duplat, Jerome; Grandemange, Mathieu; Poulain, Cedric
2017-11-01
Heat or mass transfer around an evaporating drop or condensing vapor bubble is a complex issue due to the interplay between the substrate properties, diffusion- and convection-driven mass transfer, and Marangoni effects, to mention but a few. In order to disentangle these mechanisms, we focus here mainly on the convective mass transfer contribution in an isothermal mass transfer problem. For this, we study the case of a millimetric carbon dioxide bubble which is suspended under a substrate and dissolved into pure liquid water. The high solubility of CO2 in water makes the liquid denser and promotes a buoyant-driven flow at a high (solutal) Rayleigh number (Ra˜104 ). The alteration of p H allows the concentration field in the liquid to be imaged by laser fluorescence enabling us to measure both the global mass flux (bubble volume, contact angle) and local mass flux around the bubble along time. After a short period of mass diffusion, where the boundary layer thickens like the square root of time, convection starts and the CO2 is carried by a plume falling at constant velocity. The boundary layer thickness then reaches a plateau which depends on the bubble cross section. Meanwhile the plume velocity scales like (dV /d t )1 /2 with V being the volume of the bubble. As for the rate of volume loss, we recover a constant mass flux in the diffusion-driven regime followed by a decrease in the volume V like V2 /3 after convection has started. We present a model which agrees well with the bubble dynamics and discuss our results in the context of droplet evaporation, as well as high Rayleigh convection.
An Entrance Region Mass Transfer Experiment.
Youngquist, G. R.
1979-01-01
This paper describes an experiment designed to reveal the consequences of the development of a concentration boundary layer. The rate of a mass transfer limited electrochemical reaction is measured and used to obtain the dependence of average Sherwood number on Reynolds number and entrance length. (Author/BB)
Selective mass transfer in a membrane absorber
Okunev, A. Yu.; Laguntsov, N. I.
2006-09-01
A theoretical study of selective mass transfer in a plane-frame membrane absorber (contactor) has been made. A mathematical model of the process has been developed and the process of purification of a gas mixture depending on the flow parameters, the membrane, and the feeding-mixture composition has been studied with its help.
Electronic Equipment Cooling by Simultaneous Heat and Mass Transfer,
ELECTRONIC EQUIPMENT, COOLING, HEAT TRANSFER, SUPERSONIC AIRCRAFT, HIGH ALTITUDE, DENSITY, THERMAL STRESSES, AIR, COOLING AND VENTILATING EQUIPMENT, FLUIDS, COOLANTS, HEAT EXCHANGERS, WATER, MASS TRANSFER .
Heat and mass transfer in materials processing
Tanasawa, Ichiro; Lior, Noam
Various papers on heat and mass transfer in materials processing are presented. The topics addressed include: heat transfer in plasma spraying, structure of ultrashort pulse plasma for CVD processing, heat flow and thermal contraction during plasma spray deposition, metal melting process by laser heating, improved electron beam weld design and control with beam current profile measurements, transport phenomena in laser materials processing, perspectives on integrated modeling of transport processes in semiconductor crystal growth, numerical simulation of natural convection in crystal growth in space and on the earth, conjugate heat transfer in crystal growth, effects of convection on the solidification of binary mixtures. Also discussed are: heat transfer in in-rotating-liquid-spinning process, thermal oscillations in materials processing, modeling and simulation of manufacturing processes of advanced composite materials, reaction engineering principles of combustion synthesis of advanced materials, numerical evaluation of the physical properties of magnetic fluids suitable for heat transfer control, and measurement techniques of thermophysical properties of high temperature melts. (For individual items see A93-10827 to A93-10843)
Eze, Ikenna C; Kramer, Karen; Msengwa, Amina; Mandike, Renata; Lengeler, Christian
2014-05-27
To protect the most vulnerable groups from malaria (pregnant women and infants) the Tanzanian Government introduced a subsidy (voucher) scheme in 2004, on the basis of a public-private partnership. These vouchers are provided to pregnant women at their first antenatal care visit and mothers of infants at first vaccination. The vouchers are redeemed at registered retailers for a long-lasting insecticidal net against the payment of a modest top-up price. The present work analysed a large body of data from the Tanzanian National Voucher Scheme, focusing on interactions with concurrent mass distribution campaigns of free nets. In an ecologic study involving all regions of Tanzania, voucher redemption data for the period 2007-2011, as well as data on potential determinants of voucher redemption were analysed. The four outcome variables were: pregnant woman and infant voucher redemption rates, use of treated bed nets by all household members and by under- five children. Each of the outcomes was regressed with selected determinants, using a generalized estimating equation model and accounting for regional data clustering. There was a consistent improvement in voucher redemption rates over the selected time period, with rates >80% in 2011. The major determinants of redemption rates were the top-up price paid by the voucher beneficiary, the retailer- clinic ratio, and socio-economic status. Improved redemption rates after 2009 were most likely due to reduced top-up prices (following a change in policy). Redemption rates were not affected by two major free net distribution campaigns. During this period, there was a consistent improvement in net use across all the regions, with rates of up to 75% in 2011. The key components of the National Treated Nets Programme (NATNETS) seem to work harmoniously, leading to a high level of net use in the entire population. This calls for the continuation of this effort in Tanzania and for emulation by other countries with endemic malaria.
NUMERICAL ANALYSIS OF INTER-PHASE MASS TRANSFER ...
African Journals Online (AJOL)
NUMERICAL ANALYSIS OF INTER-PHASE MASS TRANSFER WITH. CHEMICAL REACTION. Nigus Gabbiye, Nurelegne Tefera and Daggupati Venkata Narasaiah. Department of Chemical Engineering. Addis Ababa University. ABSTRACT. The numerical analysis in' the present study simulates interphase mass transfer ...
Mixing and Mass Transfer in Industrial Bioreactors
DEFF Research Database (Denmark)
Villadsen, John
2015-01-01
Design of a real reactor for a real process in industrial scale requires much more than the design of the "ideal" reactors. This insight is formulated in empirical relations between key process parameters, such as mass and heat transfer coefficients, and the power input to the process. Mixing...... formulas are not in any way quantitatively correct, but based on dimensional analysis one is able to extrapolate from small-to large-scale operation. It is shown that linear scale-up may not give the smallest power input for a given mixing objective. The introduction presented is the basis...
MASS-TRANSFER IN GAS-LIQUID SLURRY REACTORS
BEENACKERS, AACM; VANSWAAIJ, WPM
A critical review is presented on the mass transfer characteristics of gas-liquid slurry reactors. The recent findings on the influence of the presence of solid particles on the following mass transfer parameters in slurry reactors are discussed: volumetric gas-liquid mass transfer coefficients
Mass transfer in gas-liquid slurry reactors
Beenackers, A.A.C.M.; van Swaaij, Willibrordus Petrus Maria
1993-01-01
A critical review is presented on the mass transfer characteristics of gas¿liquid slurry reactors. The recent findings on the influence of the presence of solid particles on the following mass transfer parameters in slurry reactors are discussed: volumetric gas¿liquid mass transfer coefficients
Review of mass transfer aspects for biological gas treatment
Kraakman, N.J.R.; Rocha-Rios, J.; Van Loosdrecht, M.C.M.
2011-01-01
This contribution reviews the mass transfer aspects of biotechnological processes for gas treatment, with an emphasis on the underlying principles and technical feasible methods for mass transfer enhancements. Understanding of the mass transfer behavior in bioreactors for gas treatment will result
Mass transfer mechanism in hydrophilic interaction chromatography.
Gritti, Fabrice; Guiochon, Georges
2013-08-09
The mass transfer mechanism in HILIC was investigated in depth. The reduced heights equivalent to a theoretical plate (HETP) of five low molecular weigh compounds with retention factors of -0.05 (slight exclusion from the surface due to the presence of a water-rich layer in which naphthalene is insoluble) to 3.64 were measured at room temperature for a 4.6mm×100mm column packed with 3.5μm 140Å XBridge HILIC particles in a wide range of flow velocities. The mobile phase was a buffered acetonitrile-water mixture (92.5/7.5, v/v). Using a physically reliable model of effective diffusion in binary composite media (Torquato's model), the longitudinal diffusion and solid-liquid mass transfer resistance reduced HETP terms were measured. The reduced short-range eddy dispersion HETP was taken from the literature data. The long-range reduced HETP was directly measured from the subtraction of these HETP terms to the overall HETP measured from moment analysis. In contrast to RPLC, the plots of the reduced HETP versus the reduced velocity depend weakly on the retention factor, due to the constant, low intra-particle diffusivity observed in HILIC. So, the reduced longitudinal diffusion HETP is smaller and the reduced solid-liquid mass transfer resistance HETP is larger in HILIC than in RPLC. Whereas border effects can be concealed in RPLC for retained analytes due to fast radial equilibration across the column diameter, a residual long-range eddy dispersion term persists in 4.6mm I.D. HILIC columns, even at very slow flow rates. Experiments show that the minor differences in the long-range eddy dispersion term between analytes having different retention factors is directly correlated to the reciprocal of their bulk diffusion coefficient. The performance of HILIC columns packed with fine particles is then more sensitive to the inlet sample distribution and to the outlet sample collection than RPLC columns due to the relatively poor radial mixing controlled by lateral diffusion
Heat and mass transfer in flames
Faeth, G. M.
1986-01-01
Heat- and mass-transfer processes in turbulent diffusion flames are discussed, considering turbulent mixing and the structure of single-phase flames, drop processes in spray flames, and nonluminous and luminous flame radiation. Interactions between turbulence and other phenomena are emphasized, concentrating on past work of the author and his associates. The conserved-scalar formalism, along with the laminar-flamelet approximation, is shown to provide reasonable estimates of the structure of gas flames, with modest levels of empiricism. Extending this approach to spray flames has highlighted the importance of drop/turbulence interactions; e.g., turbulent dispersion of drops, modification of turbulence by drops, etc. Stochastic methods being developed to treat these phenomena are yielding encouraging results.
Experimental and modeling studies of mass transfer in ...
African Journals Online (AJOL)
Gaining a better understanding of mass transfer problems in encapsulated cell systems and in tissue engineering requires both experimental investigations and mathematical modelling. Specific mass transfer studies are reviewed including oxygen transfer in immobilised animal cell culture systems, modelling of ...
Mass Transfer and Tidal Dynamics in White Dwarf Binary Systems
Gerber, Jeffrey; Fuller, J.
2014-01-01
Compact white dwarf (WD) binary systems (with orbital periods ranging from minutes to hours) can produce a variety of interesting astrophysical objects (e.g., type Ia supernovae, AM CVn systems, R Cor Bor stars, sdB stars) upon the onset of mass transfer. These systems are driven toward Roche lobe overflow by the emission of gravitational radiation, but it is not known whether the mass transfer will be stable (forming an Am CVn system) or become unstable (resulting in a merger). We analyze how the combined effects of mass transfer and tidal torques affect the evolution of these systems by creating numerical models with the MESA stellar evolution program. Using new calculations of the tidal torque in rotating WDs, we predict the outcome of mass transfer in these systems as a function of the masses of the WD components. We find that the stability of mass transfer depends primarily on the peak mass transfer rate near the period minimum, which is highly dependent on the WD masses and on the strength of the tidal torques. Except for low WD accretor masses, the tidal torques are insufficient to significantly increase the stability of mass transfer. We find that mass transfer is generally unstable for WD donor masses greater than about 0.25 solar masses, and that the 12 minute system SDSS J0615 will end its inspiral in a WD merger, likely producing an R Cor Bor star.
ChemNet: A Transferable and Generalizable Deep Neural Network for Small-Molecule Property Prediction
Energy Technology Data Exchange (ETDEWEB)
Goh, Garrett B.; Siegel, Charles M.; Vishnu, Abhinav; Hodas, Nathan O.
2017-12-08
With access to large datasets, deep neural networks through representation learning have been able to identify patterns from raw data, achieving human-level accuracy in image and speech recognition tasks. However, in chemistry, availability of large standardized and labelled datasets is scarce, and with a multitude of chemical properties of interest, chemical data is inherently small and fragmented. In this work, we explore transfer learning techniques in conjunction with the existing Chemception CNN model, to create a transferable and generalizable deep neural network for small-molecule property prediction. Our latest model, ChemNet learns in a semi-supervised manner from inexpensive labels computed from the ChEMBL database. When fine-tuned to the Tox21, HIV and FreeSolv dataset, which are 3 separate chemical tasks that ChemNet was not originally trained on, we demonstrate that ChemNet exceeds the performance of existing Chemception models, contemporary MLP models that trains on molecular fingerprints, and it matches the performance of the ConvGraph algorithm, the current state-of-the-art. Furthermore, as ChemNet has been pre-trained on a large diverse chemical database, it can be used as a universal “plug-and-play” deep neural network, which accelerates the deployment of deep neural networks for the prediction of novel small-molecule chemical properties.
Numerical Computation of Net Radiative Heat Transfer within a Non Absorbing Furnace Enclosure
Directory of Open Access Journals (Sweden)
Shuaibu Ndache MOHAMMED
2006-07-01
Full Text Available The numerical evaluation of the net radiative heat transfer rate in a single zone, non absorbing furnace enclosure is reported. In this analysis, simplified mathematical furnace model namely, the long furnace model is used to determine furnace performance. The formulation assumes some known temperature values. Thus, heat transfer equations were set up and solved numerically. A FORTRAN computer program was developed and debugged. Results obtained from this study compare favourably well with the results from the traditional graphical method. Also, the computer program developed can handle variations in furnace operating conditions, temperatures, thermal properties and dimensions.
Second Law Analysis in Convective Heat and Mass Transfer
Directory of Open Access Journals (Sweden)
A. Ben Brahim
2006-02-01
Full Text Available This paper reports the numerical determination of the entropy generation due to heat transfer, mass transfer and fluid friction in steady state for laminar double diffusive convection, in an inclined enclosure with heat and mass diffusive walls, by solving numerically the mass, momentum, species conservation and energy balance equations, using a Control Volume Finite-Element Method. The influences of the inclination angle, the thermal Grashof number and the buoyancy ratio on total entropy generation were investigated. The irreversibilities localization due to heat transfer, mass transfer and fluid friction is discussed for three inclination angles at a fixed thermal Grashof number.
Estimates of Regional Equilibrium Line Altitudes and Net Mass Balance from MODIS Imagery
Shea, J. M.; Menounos, B.; Moore, R. D.
2011-12-01
Glacier mass balance is a key variable used to assess the health of glaciers and ice sheets. Estimates of glacier mass balance are required to model the dynamic response of glaciers and ice sheets to climate change, estimate sea-level contribution from surface melt, and document the response of glaciers to climate forcing. Annually resolved estimates of regional mass balance for mountain ranges is often inferred from a sparse network of ground-based measurements of mass balance for individual glaciers. Given that net mass balance is highly correlated with the annual equilibrium line altitude (ELA), we develop an automated approach to estimate the ELA, and by inference net mass balance, on large glaciers and icefields using MODIS 250 m imagery (MOD02QKM). We discriminate areas of bare ice and snow/firn using the product of MODIS' red (0.620 - 0.670 μ m) and near infrared (0.841 - 0.876 μ m) bands. To assess the skill in estimating glacier ELAs, we compare ELAs derived from (1) manual delineation and (2) unsupervised classification of the band product to ground-based observations of ELA and net mass balance at seven long term mass-balance monitoring sites in western North America (Gulkana, Wolverine, Lemon Creek, Taku, Place, Peyto, and South Cascade). Spatial and temporal variations in MODIS-derived ELAs provide an opportunity to validate regional mass-balance models, estimate surface melt contributions to sea-level rise, and examine the cryospheric response to climate change.
Mass transfer in white dwarf-neutron star binaries
Bobrick, Alexey; Davies, Melvyn B.; Church, Ross P.
2017-05-01
We perform hydrodynamic simulations of mass transfer in binaries that contain a white dwarf and a neutron star (WD-NS binaries), and measure the specific angular momentum of material lost from the binary in disc winds. By incorporating our results within a long-term evolution model, we measure the long-term stability of mass transfer in these binaries. We find that only binaries containing helium white dwarfs (WDs) with masses less than a critical mass of MWD, crit = 0.2 M⊙ undergo stable mass transfer and evolve into ultracompact X-ray binaries. Systems with higher mass WDs experience unstable mass transfer, which leads to tidal disruption of the WD. Our low critical mass compared to the standard jet-only model of mass-loss arises from the efficient removal of angular momentum in the mechanical disc winds, which develop at highly super-Eddington mass-transfer rates. We find that the eccentricities expected for WD-NS binaries when they come into contact do not affect the loss of angular momentum, and can only affect the long-term evolution if they change on shorter time-scales than the mass-transfer rate. Our results are broadly consistent with the observed numbers of both ultracompact X-ray binaries and radio pulsars with WD companions. The observed calcium-rich gap transients are consistent with the merger rate of unstable systems with higher mass WDs.
THE ELECTRONIC COURSE OF HEAT AND MASS TRANSFER
Directory of Open Access Journals (Sweden)
Alexander P. Solodov
2013-01-01
Full Text Available The Electronic course of heat and mass transfer in power engineering is presented containing the full Electronic book as the structured hypertext document, the full set of Mathcad-documents with the whole set of educative computer models of heat and mass transfer, the computer labs, and selected educational presentations.
Novel spacers for mass transfer enhancement in membrane separations
Li, F.; Meindersma, G.W.; de Haan, A.B.; Reith, T.
2005-01-01
The optimal flow pattern for mass transfer enhancement in spacer-filled channels is characterized by the coexistence of transversal and longitudinal vortices in the flow close to the channel walls and minimal cross-flow power consumption in the middle of the channel. The mass transfer enhancement of
Limits of mass-transfer in parallel plate dialyzers
Kolev, S.D.; Kolev, Spas D.; van der Linden, W.E.
1992-01-01
The absolute limits of mass transfer across the membrane in a parallel-plate dialyser set by the flow pattern in both channels were determined on the basis of a mathematical model assuming axially dispersed plug flow. The lower limit corresponds to the case of mass transfer under laminar flow
Overall mass-transfer coefficients in non-linear chromatography
DEFF Research Database (Denmark)
Mollerup, Jørgen; Hansen, Ernst
1998-01-01
In case of mass transfer where concentration differences in both phases must be taken into account, one may define an over-all mass-transfer coefficient basd on the apparent over-all concentration difference. If the equilibrium relationship is linear, i.e. in cases where a Henry´s law relationshi...
Hydrodynamics and mass transfer in a tubular airlift photobioreactor
Babcock Jr., R.W.; Malda, J.; Radway, J.C.
2002-01-01
In photobioreactors, which are usually operated under light limitation, sufficient dissolved inorganic carbon must be provided to avoid carbon limitation. Efficient mass transfer of CO2 into the culture medium is desirable since undissolved CO2 is lost by outgassing. Mass transfer of O2 out of the
Energy Technology Data Exchange (ETDEWEB)
Tafreshi, H. Vahedi; Ercan, E.; Pourdeyhimi, B. [North Carolina State University, Nonwovens Cooperative Research Center, Raleigh, NC (United States)
2006-07-15
In this note, the evaporation rate from a vertical wet fabric sheet is calculated using a free convection heat transfer correlation. Chilton-Colburn analogy is used to derive a mass transfer correlation from a heat transfer correlation proposed by Churchill and Chu for free convection from a vertical isothermal plate. The mass transfer rate obtained from this expression has shown excellent agreement with experimental data. (orig.)
Introduction to computational mass transfer with applications to chemical engineering
Yu, Kuo-Tsung
2017-01-01
This book offers an easy-to-understand introduction to the computational mass transfer (CMT) method. On the basis of the contents of the first edition, this new edition is characterized by the following additional materials. It describes the successful application of this method to the simulation of the mass transfer process in a fluidized bed, as well as recent investigations and computing methods for predictions for the multi-component mass transfer process. It also demonstrates the general issues concerning computational methods for simulating the mass transfer of the rising bubble process. This new edition has been reorganized by moving the preparatory materials for Computational Fluid Dynamics (CFD) and Computational Heat Transfer into appendices, additions of new chapters, and including three new appendices on, respectively, generalized representation of the two-equation model for the CMT, derivation of the equilibrium distribution function in the lattice-Boltzmann method, and derivation of the Navier-S...
Sarsimbayeva, S. M.; Kospanova, K. K.
2015-11-01
The article provides the discussion of matters associated with the problems of transferring of object-oriented Windows applications from C++ programming language to .Net platform using C# programming language. C++ has always been considered to be the best language for the software development, but the implicit mistakes that come along with the tool may lead to infinite memory leaks and other errors. The platform .Net and the C#, made by Microsoft, are the solutions to the issues mentioned above. The world economy and production are highly demanding applications developed by C++, but the new language with its stability and transferability to .Net will bring many advantages. An example can be presented using the applications that imitate the work of queuing systems. Authors solved the problem of transferring of an application, imitating seaport works, from C++ to the platform .Net using C# in the scope of Visual Studio.
Formulation of Generalized Mass Transfer Correlations for Blood Oxygenator Design.
Low, Kenny W Q; Van Loon, Raoul; Rolland, Samuel A; Sienz, Johann
2017-03-01
This paper numerically investigates non-Newtonian blood flow with oxygen and carbon dioxide transport across and along an array of uniformly square and staggered arranged fibers at various porosity (ε) levels, focussing on a low Reynolds number regime (Re mass transfer correlations, expressed in the form of Sherwood number (Sh = f(ε, Re, Sc)), that identifies the link from local mass transfer investigations to full-device analyses. The development of a concentration field is initially investigated and expressions are established covering the range from a typical deoxygenated condition up to a full oxygenated condition. An important step is identified where a cut-off point in those expressions is required to avoid any under- or over-estimation on the Sherwood number. Geometrical features of a typical commercial blood oxygenator is adopted and results in general show that a balance in pressure drop, shear stress, and mass transfer is required to avoid potential blood trauma or clotting formation. Different definitions of mass transfer correlations are found for oxygen/carbon dioxide, parallel/transverse flow, and square/staggered configurations, respectively. From this set of correlations, it is found that transverse flow has better gas transfer than parallel flow which is consistent with reported literature. The mass transfer dependency on fiber configuration is observed to be pronounced at low porosity. This approach provides an initial platform when one is looking to improve the mass transfer performance in a blood oxygenator without the need to conduct any numerical simulations or experiments.
Directory of Open Access Journals (Sweden)
Abass Ali K
2010-06-01
Full Text Available Abstract Background Insecticide-treated nets (ITN and long-lasting insecticidal treated nets (LLIN are important means of malaria prevention. Although there is consensus regarding their importance, there is uncertainty as to which delivery strategies are optimal for dispensing these life saving interventions. A targeted mass distribution of free LLINs to children under five and pregnant women was implemented in Zanzibar between August 2005 and January 2006. The outcomes of this distribution among children under five were evaluated, four to nine months after implementation. Methods Two cross-sectional surveys were conducted in May 2006 in two districts of Zanzibar: Micheweni (MI on Pemba Island and North A (NA on Unguja Island. Household interviews were conducted with 509 caretakers of under-five children, who were surveyed for socio-economic status, the net distribution process, perceptions and use of bed nets. Each step in the distribution process was assessed in all children one to five years of age for unconditional and conditional proportion of success. System effectiveness (the accumulated proportion of success and equity effectiveness were calculated, and predictors for LLIN use were identified. Results The overall proportion of children under five sleeping under any type of treated net was 83.7% (318/380 in MI and 91.8% (357/389 in NA. The LLIN usage was 56.8% (216/380 in MI and 86.9% (338/389 in NA. Overall system effectiveness was 49% in MI and 87% in NA, and equity was found in the distribution scale-up in NA. In both districts, the predicting factor of a child sleeping under an LLIN was caretakers thinking that LLINs are better than conventional nets (OR = 2.8, p = 0.005 in MI and 2.5, p = 0.041 in NA, in addition to receiving an LLIN (OR = 4.9, p Conclusions Targeted free mass distribution of LLINs can result in high and equitable bed net coverage among children under five. However, in order to sustain high effective coverage, there
Beer, Netta; Ali, Abdullah S; de Savigny, Don; Al-Mafazy, Abdul-Wahiyd H; Ramsan, Mahdi; Abass, Ali K; Omari, Rahila S; Björkman, Anders; Källander, Karin
2010-06-18
Insecticide-treated nets (ITN) and long-lasting insecticidal treated nets (LLIN) are important means of malaria prevention. Although there is consensus regarding their importance, there is uncertainty as to which delivery strategies are optimal for dispensing these life saving interventions. A targeted mass distribution of free LLINs to children under five and pregnant women was implemented in Zanzibar between August 2005 and January 2006. The outcomes of this distribution among children under five were evaluated, four to nine months after implementation. Two cross-sectional surveys were conducted in May 2006 in two districts of Zanzibar: Micheweni (MI) on Pemba Island and North A (NA) on Unguja Island. Household interviews were conducted with 509 caretakers of under-five children, who were surveyed for socio-economic status, the net distribution process, perceptions and use of bed nets. Each step in the distribution process was assessed in all children one to five years of age for unconditional and conditional proportion of success. System effectiveness (the accumulated proportion of success) and equity effectiveness were calculated, and predictors for LLIN use were identified. The overall proportion of children under five sleeping under any type of treated net was 83.7% (318/380) in MI and 91.8% (357/389) in NA. The LLIN usage was 56.8% (216/380) in MI and 86.9% (338/389) in NA. Overall system effectiveness was 49% in MI and 87% in NA, and equity was found in the distribution scale-up in NA. In both districts, the predicting factor of a child sleeping under an LLIN was caretakers thinking that LLINs are better than conventional nets (OR = 2.8, p = 0.005 in MI and 2.5, p = 0.041 in NA), in addition to receiving an LLIN (OR = 4.9, p < 0.001 in MI and in OR = 30.1, p = 0.001 in NA). Targeted free mass distribution of LLINs can result in high and equitable bed net coverage among children under five. However, in order to sustain high effective coverage, there is need
Heat and mass transfer in frozen porous media
Loon, van W.
1991-01-01
In this thesis processes and parameters associated with heat and mass transfer in frozen porous media both on a theoretical and empirical basis are studied. To obtain the required measurements some existing measuring methods needed to be
Heat and Mass Transfer in an L Shaped Porous Medium
Salman Ahmed, N. J.; Azeem; Yunus Khan, T. M.
2017-08-01
This article is an extension to the heat transfer in L-shaped porous medium by including the mass diffusion. The heat and mass transfer in the porous domain is represented by three coupled partial differential equations representing the fluid movement, energy transport and mass transport. The equations are converted into algebraic form of equations by the application of finite element method that can be conveniently solved by matrix method. An iterative approach is adopted to solve the coupled equations by setting suitable convergence criterion. The results are discussed in terms of heat transfer characteristics influenced by physical parameters such as buoyancy ratio, Lewis number, Rayleigh number etc. It is found that these physical parameters have significant effect on heat and mass transfer behavior of L-shaped porous medium.
Convective heat and mass transfer in rotating disk systems
Shevchuk, Igor V
2009-01-01
The book describes results of investigations of a series of convective heat and mass transfer problems in rotating-disk systems. Methodology used included integral methods, self-similar and approximate analytical solutions, as well as CFD.
Correlation of liquid-film cooling mass transfer data.
Gater, R. A.; L'Ecuyer, M. R.
1972-01-01
An empirical correlation proposed by Gater and Ecuyer (1970) for liquid-film cooling mass transfer, accounting for film roughness and entrainment effects, is extended to include liquid films of arbitrary length. A favorable comparison between the predicted results and the experimental data of Kinney et al. (1952) and Emmons and Warner (1964) shows the utility of the mass transfer correlation for predictions over a wide range of experimental parameters.
HEAT AND MASS TRANSFER. VOLUME 2, 1968 (COLLECTION OF ARTICLES),
are quite thoroughly investigated. Also treated are such problems as internal heat and mass transfer during filtration of gases through a porous...boundary layer of a multi-component gas, critical heat fluxes during the boiling of organic heat carriers, the intensification of heat and mass ... transfer , entropy during the melting of polymers, the thermodynamics of plasma flows, process of sublimation by various methods of energy supply, and others
Imaging Heat and Mass Transfer Processes Visualization and Analysis
Panigrahi, Pradipta Kumar
2013-01-01
Imaging Heat and Mass Transfer Processes: Visualization and Analysis applies Schlieren and shadowgraph techniques to complex heat and mass transfer processes. Several applications are considered where thermal and concentration fields play a central role. These include vortex shedding and suppression from stationary and oscillating bluff bodies such as cylinders, convection around crystals growing from solution, and buoyant jets. Many of these processes are unsteady and three dimensional. The interpretation and analysis of images recorded are discussed in the text.
Heat and mass transfer in building services design
Moss, Keith
1998-01-01
Building design is increasingly geared towards low energy consumption. Understanding the fundamentals of heat transfer and the behaviour of air and water movements is more important than ever before. Heat and Mass Transfer in Building Services Design provides an essential underpinning knowledge for the technology subjects of space heating, water services, ventilation and air conditioning. This new text: *provides core understanding of heat transfer and fluid flow from a building services perspective *complements a range of courses in building services engineering *
Principles of heat and mass transfer
Incropera, Frank P; Bergman, Theodore L; Lavine, Adrienne S
2013-01-01
Completely updated, the seventh edition provides engineers with an in-depth look at the key concepts in the field. It incorporates new discussions on emerging areas of heat transfer, discussing technologies that are related to nanotechnology, biomedical engineering and alternative energy. The example problems are also updated to better show how to apply the material. And as engineers follow the rigorous and systematic problem-solving methodology, they'll gain an appreciation for the richness and beauty of the discipline.
Mass transfer during ice particle collisions in planetary rings
Mcdonald, J. S. B.; Hatzes, A.; Bridges, F.; Lin, D. N. C.
1989-01-01
Experimental results are presented from laboratory environment simulations of the ice particle collisional properties defining the structure and dynamical evolution of planetary rings. It is inferred from these data that there is a dependence of the interacting volume on the impact velocity. Although the volume fraction exchanged during a collision is small, the net amount of material transferred can be substantially smaller. Attention is given to the implications of these determinations for planetary ring structure and evolution.
Influence of pluronic F68 on oxygen mass transfer.
Sieblist, Christian; Jenzsch, Marco; Pohlscheidt, Michael
2013-01-01
Pluronic F68 is one of the most used shear protecting additives in cell culture cultivations. It is well known from literature that such surface-active surfactants lower the surface tension at the gas-liquid interface, which influences the mass transfer. In this study, the effect of Pluronic F68 on oxygen mass transfer in aqueous solutions was examined. Therefore, the gassing in/gassing out method and bubble size measurements were used. At low concentrations of 0.02 g/L, a 50% reduction on mass transfer was observed for all tested spargers and working conditions. An explanation of the observed effects by means of Higbie's penetration or Dankwerts surface renewal theory was applied. It could be demonstrated that the suppressed movement of the bubble surface layer is the main cause for the significant drop down of the kL a-values. For Pluronic F68 concentrations above 0.1 g/L, it was observed that it comes to changes in bubble appearance and bubble size strongly dependent on the sparger type. By using the bubble size measurement data, it could be shown that only small changes in mass transfer coefficient (kL ) take place above the critical micelle concentration. Further changes on overall mass transfer at higher Pluronic F68 concentrations are mainly based on increasing of gas holdup and, more importantly, by increasing of the surface area available for mass transfer. © 2013 American Institute of Chemical Engineers.
Mass transfer kinetics, band broadening and column efficiency.
Gritti, Fabrice; Guiochon, Georges
2012-01-20
Important progress was recently made in our understanding of the physico-chemical aspects of mass transfer kinetics in chromatographic columns, in methods used for accurate determination of the different contributions to the height equivalent to a theoretical plate (HETP), and in the application of these advances to the elucidation of mass transfer mechanisms in columns packed with recent chromatographic supports (sub-2 μm fully porous particles, sub-3 μm core-shell particles, and monoliths). The independent contributions to the HETP are longitudinal diffusion, eddy dispersion, liquid-solid mass transfer (including trans-particle or trans-skeleton mass transfer and external film mass transfer), and the contributions caused by the thermal heterogeneity of the column. The origin and importance of these contributions are investigated in depth. This work underlines the areas in which improvements are needed, an understanding of the contribution of the external film mass transfer term, a better design of HPLC instruments providing a decrease of the extra-column band broadening contributions to the apparent HETP, the development of better packing procedures giving more radially homogeneous column beds, and new packing materials having a higher thermal conductivity to eliminate the nefarious impact of heat effects in very high pressure liquid chromatography (vHPLC) and supercritical fluid chromatography (SFC). Copyright © 2011 Elsevier B.V. All rights reserved.
The new automotive 42V PowerNet. Preparing for mass production
Energy Technology Data Exchange (ETDEWEB)
Graf, A. (ed.)
2001-07-01
A number of international auto makers have set themselves the target of getting an automobile with a dual 12V/42V PowerNet into mass production by the year 2005. Reports on practical experience of current projects at leading international auto makers and suppliers allow the reader to get a picture of the status of introduction of the 42V PowerNet and of the problems associated with translating development work into mass production, providing them with an idea of the opportunities for structuring their own company or organizing company activities. The book gives an overview of the problems of introducing the 42V PowerNet into automotive engineering. The basic question here is not 'Why 42V?' but rather 'How can a 42V system be introduced into mass production alongside an existing 12V system?''. It provides information from the standpoint of the engineer and the businessman on: The problems of introduction as seen by the auto maker - Proposed solutions to detailed problems such as short circuits and sparking-System reviews, such as Intelligent Power Management - Suggestions for individual components, such as individual semiconductors - Suggested solutions involving new materials - Solution variants and verification by simulation. (orig.)
Mass transfer relations for transpiration evaporation experiments
Limpt, J.A.C. van; Beerkens, R.G.C.; Lankhorst, A.M.; Habraken, A.
2005-01-01
Transpiration evaporation experiments are often used to study evaporation kinetics from liquids or melts. The mass transport of volatile species in a transpiration experiment depends among others on the flow conditions of the carrier gas in the tube and on the geometrical configuration. For a
Mass transfer in asymptotic-giant-branch binary systems
Chen, Zhuo; Frank, Adam; Blackman, Eric G.; Nordhaus, Jason; Carroll-Nellenback, Jonathan
2017-10-01
Binary stars can interact via mass transfer when one member (the primary) ascends onto a giant branch. The amount of gas ejected by the binary and the amount of gas accreted by the secondary over the lifetime of the primary influence the subsequent binary phenomenology. Some of the gas ejected by the binary will remain gravitationally bound and its distribution will be closely related to the formation of planetary nebulae. We investigate the nature of mass transfer in binary systems containing an AGB star by adding radiative transfer to the AstroBEAR AMR Hydro/MHD code.
Geoelectrical Measurement of Multi-Scale Mass Transfer Parameters
Energy Technology Data Exchange (ETDEWEB)
Day-Lewis, Frederick David [US Geological Survey, Storrs, CT (United States); Singha, Kamini [Colorado School of Mines, Golden, CO (United States); Johnson, Timothy C. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Haggerty, Roy [Oregon State Univ., Corvallis, OR (United States); Binley, Andrew [Lancaster Univ. (United Kingdom); Lane, John W. [US Geological Survey, Storrs, CT (United States)
2014-11-25
Mass transfer affects contaminant transport and is thought to control the efficiency of aquifer remediation at a number of sites within the Department of Energy (DOE) complex. An improved understanding of mass transfer is critical to meeting the enormous scientific and engineering challenges currently facing DOE. Informed design of site remedies and long-term stewardship of radionuclide-contaminated sites will require new cost-effective laboratory and field techniques to measure the parameters controlling mass transfer spatially and across a range of scales. In this project, we sought to capitalize on the geophysical signatures of mass transfer. Previous numerical modeling and pilot-scale field experiments suggested that mass transfer produces a geoelectrical signature—a hysteretic relation between sampled (mobile-domain) fluid conductivity and bulk (mobile + immobile) conductivity—over a range of scales relevant to aquifer remediation. In this work, we investigated the geoelectrical signature of mass transfer during tracer transport in a series of controlled experiments to determine the operation of controlling parameters, and also investigated the use of complex-resistivity (CR) as a means of quantifying mass transfer parameters in situ without tracer experiments. In an add-on component to our grant, we additionally considered nuclear magnetic resonance (NMR) to help parse mobile from immobile porosities. Including the NMR component, our revised study objectives were to: 1. Develop and demonstrate geophysical approaches to measure mass-transfer parameters spatially and over a range of scales, including the combination of electrical resistivity monitoring, tracer tests, complex resistivity, nuclear magnetic resonance, and materials characterization; and 2. Provide mass-transfer estimates for improved understanding of contaminant fate and transport at DOE sites, such as uranium transport at the Hanford 300 Area. To achieve our objectives, we implemented a 3
Heat and mass transfer over slippery, superhydrophobic surfaces
Haase, A. Sander; Lammertink, Rob G.H.
2016-01-01
The classical Graetz-Nusselt problem is extended to describe heat and mass transfer over heterogeneously slippery, superhydrophobic surfaces. The cylindrical wall consists of segments with a constant temperature/concentration and areas that are insulating/impermeable. Only in the case of mass
Mass transfer between debris discs during close stellar encounters
Jílková, Lucie; Hamers, Adrian S.; Hammer, Michael; Portegies Zwart, Simon
2016-04-01
We study mass transfers between debris discs during stellar encounters. We carried out numerical simulations of close flybys of two stars, one of which has a disc of planetesimals represented by test particles. We explored the parameter space of the encounters, varying the mass ratio of the two stars, their pericentre and eccentricity of the encounter, and its geometry. We find that particles are transferred to the other star from a restricted radial range in the disc and the limiting radii of this transfer region depend on the parameters of the encounter. We derive an approximate analytic description of the inner radius of the region. The efficiency of the mass transfer generally decreases with increasing encounter pericentre and increasing mass of the star initially possessing the disc. Depending on the parameters of the encounter, the transfer particles have a specific distribution in the space of orbital elements (semimajor axis, eccentricity, inclination, and argument of pericentre) around their new host star. The population of the transferred particles can be used to constrain the encounter through which it was delivered. We expect that many stars experienced transfer among their debris discs and planetary systems in their birth environment. This mechanism presents a formation channel for objects on wide orbits of arbitrary inclinations, typically having high eccentricity but possibly also close to circular (eccentricities of about 0.1). Depending on the geometry, such orbital elements can be distinct from those of the objects formed around the star.
A mass transfer in heterogeneous systems by the adsorption method (
Directory of Open Access Journals (Sweden)
N. Bošković-Vragolović
2009-01-01
Full Text Available A mass transfer coefficient between: a liquid and single sphere and a liquid and column wall in packed and fluidized beds of a spherical inert particle have been studied experimentally using the adsorption method. The experiments were conducted in a column 40 mm in diameter for packed and fluidized beds, and in a two-dimensional column 140 mm×10 mm for the flow past single sphere. In all runs, the mass transfer rates were determined in the presence of spherical glass particles, 3 mm in diameter, for packed and fluidized beds. The mass transfer data were obtained by studying transfer for flow past single sphere, 20 mm in diameter. This paper discusses the possibilities of application of the adsorption method for fluid flow visualization. Local and average mass transfer coefficients were determined from the color intensity of the surface of the foils of silica gel. Correlations, Sh = f(Re and jD = f(Re, were derived using the mass transfer coefficient data.
An experimental investigation of flows from zero-net mass-flux actuators
Holman, Ryan Jay
Zero-net mass-flux (ZNMF) devices consist of an oscillating driver, a cavity, and a small opening such as a rectangular slot or a circular orifice. The driver produces a series of vortex pairs (or rings) at the slot/orifice which add momentum and circulation to the flow. ZNMF devices are useful tools for flow control applications such as heat transfer, mixing enhancement, and boundary layer separation control. To date much research has been done to qualify and quantify the effects of ZNMF devices in many applications, both experimental and computational. However, a number of issues still remain. First, there is no universally accepted dimensionless parameter space, which makes device characterization and comparison between studies difficult. Second, most experimental studies do not sufficiently quantify the nearfield behavior, which hinders the fundamental understanding of the underlying flow physics. Of particular interest are the regimes of jet formation, and transition from laminar to turbulent-like flow, which are not well understood. Finally, the accuracy of experimental measurements are seldom reported in the literature. This study unifies the experimental and numerical data presented in the literature for ZNMF flowfields exhausting into a quiescent medium. A quantitative experimental database is also generated to completely characterize the topological regions of ZNMF flows over a useful range of the dimensionless parameter space. The database is derived chiefly from two-dimensional velocity field measurements using particle image velocimetry and laser Doppler anemometry. Vorticity, circulation, Reynolds stress, and turbulent kinetic energy is acquired to characterize the resulting flowfield. Significant insight into the behavior of voice coil driven ZNMF devices is uncovered. Design improvements are made by implementing a sinusoidal controller for piston motion and eliminating the need for a sealing membrane in the cavity. It is shown that the proper
Studies on mass transfer in electrochemical systems
Energy Technology Data Exchange (ETDEWEB)
Sundstroem, L.G.
1997-10-01
The first part is of an introductory nature. It contains a description of the methods used, a discussion of the physics of electrochemical cells with a liquid electrolyte, and a summary of the different studies made, including both those which have been reported in papers, and those which have not. Contributions with novel aspects include (* a derivation of the electro-neutrality condition from Maxwell`s equations of electrodynamics, and **) an argument in favour of the use of mass-averaged velocity in ion transport expressions. The second part focuses on specific cases. It consists of seven research papers which give a more detailed presentation of the main studies 40 refs, 6 figs
Unsteady Mass transfer Across the Sediment-Water Interface
McCluskey, Alexander; Grant, Stanley; Stewardson, Michael
2017-04-01
Fluxes across the sediment-water interface (SWI) are of high ecological significance, as they promote biogeochemical processes that support benthic ecosystems within the hyporheic zone. The SWI marks a boundary between the turbulent water column (typically modelled by Navier Stokes equations) and the interstitial pore fluids in the sediment column, which are typically laminar (and modelled by Darcy's law). Although models of these two flow regimes are generally not coupled, flow in the turbulent boundary layer is affected by the sediment permeability and a slip velocity at the SWI, which decays exponentially into the streambed across a characteristic mixing length. Momentum is transferred across this region (known as the Brinkman layer) through the penetration of coherent structures and turbulent mixing, however, these turbulent structures also promote turbulent mass transfer. Mass transfer within the hyporheic zone can be conceptualised in terms of: (1) the downwelling of solutes from the stream; (2) retention of solutes in the sediment; and (3) the upwelling of solutes back into the stream. Recent work by the authors has shown that a mass transfer coefficient can be defined where a downwelling-upwelling unit cell exists across a concentration gradient. Such unit cells are generated at the SWI by pressure variation from: (1) steady-state influences, such as stream geometry and velocity variation; and (2) unsteady pressure waves produced by coherent turbulent structures. With this definition, mass transfer coefficients can be defined for: steady exchange, by adopting the Elliott and Brooks [1997] advective pumping model; and unsteady exchange, induced by streamwise propagation of upwelling-downwelling unit cells migrating downstream with a characteristic celerity associated with turbulent eddies. We hypothesize that beneath the Brinkman layer (where Laplace equation applies) these mass transfer coefficients can be summed to yield the total mass flux. Although, it
The Role of Mass Transfer in Membrane Systems
Directory of Open Access Journals (Sweden)
Levent Gürel
2015-12-01
Full Text Available Membranes are situated in the foreground among the considerably popular treatment systems in the last years. The use of membranes was become widespread in many fields such as drinking water treatment, wastewater treatment and obtaining drinking water from sea water. The predominance of membranes against the classical systems regarding the wastewater treatment, and the decreasing cost of membrane materials each day provided these systems to enter among the preferable options. There are considerably different types of membranes. Microfiltration (MF, ultrafiltration (UF, nanofiltration (NF and reverse osmosis (RO are the processes drawing most attention. One of the most important considerations in membrane processes is the amount of constituents passing from the membrane and rejecting by the membrane. Mass transfer concept arises in this place. Mass transfer is a critically important case used in the design of treatment systems and the estimation of efficiency. In addition to the points mentioned above, investigation of mass transfer occurring in membranes is important in comparing of different membrane types. In this review article, general information about the membranes, membrane types, uses of membranes and module designs are given, concept of mass transfer is viewed and the mass transfer processes realizing in these treatment systems are assessed.
Crystal growth: an anisotropic mass transfer process at the interface.
Sun, Congting; Xue, Dongfeng
2017-05-17
Crystal growth is a dynamic physicochemical process, which depends on the multi-parameter synergetic control and directly determines the crystal features such as geometry and size. In this study, both thermodynamic and kinetic factors that determine inorganic single crystal growth are integrated by focusing on the mass transfer process at an interface. For the specific growth system, the integrated parameter is then classified to extract the critical control factors in anisotropic growth. The driving force of mass transfer essentially depends on the anisotropic chemical bonding architectures, leading to different concentration gradients along various [uvw] directions. Exquisitely controlling the chemical bonding architecture can therefore be used to regulate the mass transfer process of a compound in a straightforward manner, encompassing the origin of anisotropic growth as well as a variety of geometries in the formation of a multicomponent crystal.
Mass transfer apparatus and method for separation of gases
Blount, Gerald C.
2015-10-13
A process and apparatus for separating components of a source gas is provided in which more soluble components of the source gas are dissolved in an aqueous solvent at high pressure. The system can utilize hydrostatic pressure to increase solubility of the components of the source gas. The apparatus includes gas recycle throughout multiple mass transfer stages to improve mass transfer of the targeted components from the liquid to gas phase. Separated components can be recovered for use in a value added application or can be processed for long-term storage, for instance in an underwater reservoir.
RESEARCH OF THE MASS TRANSFER AT MEMBRANE CLEANING OF BIOGAZ
Directory of Open Access Journals (Sweden)
Marat SATAYEV
2015-04-01
Full Text Available Everyone has long known the benefits and effectiveness of biogas. Particularly, getting biogas from the agricultural waste is very promising. But, the question is if we can use such a useful and effective biogas at 100%. Today, we use only a half of the benefit, because to get the biogas we spend more energy than we get. In this regard, the work on the study of the biogas development is extremely important. The study of the biogas formation requires numerous experiments. This article analyzes the biogas mass transfer with the membrane purification and identification of the of mass transfer mechanisms through the membrane pores.
Mass transfer apparatus and method for separation of gases
Energy Technology Data Exchange (ETDEWEB)
Blount, Gerald C.; Gorensek, Maximilian Boris; Hamm, Luther L.
2018-01-16
A process and apparatus for separating components of a source gas is provided in which more soluble components of the source gas are dissolved in an aqueous solvent at high pressure. The system can utilize hydrostatic pressure to increase solubility of the components of the source gas. The apparatus includes gas recycle throughout multiple mass transfer stages to improve mass transfer of the targeted components from the liquid to gas phase. Separated components can be recovered for use in a value added application or can be processed for long-term storage, for instance in an underwater reservoir.
Flow-dependent mass transfer may trigger endothelial signaling cascades.
Vandrangi, Prashanthi; Sosa, Martha; Shyy, John Y-J; Rodgers, Victor G J
2012-01-01
It is well known that fluid mechanical forces directly impact endothelial signaling pathways. But while this general observation is clear, less apparent are the underlying mechanisms that initiate these critical signaling processes. This is because fluid mechanical forces can offer a direct mechanical input to possible mechanotransducers as well as alter critical mass transport characteristics (i.e., concentration gradients) of a host of chemical stimuli present in the blood stream. However, it has recently been accepted that mechanotransduction (direct mechanical force input), and not mass transfer, is the fundamental mechanism for many hemodynamic force-modulated endothelial signaling pathways and their downstream gene products. This conclusion has been largely based, indirectly, on accepted criteria that correlate signaling behavior and shear rate and shear stress, relative to changes in viscosity. However, in this work, we investigate the negative control for these criteria. Here we computationally and experimentally subject mass-transfer limited systems, independent of mechanotransduction, to the purported criteria. The results showed that the negative control (mass-transfer limited system) produced the same trends that have been used to identify mechanotransduction-dominant systems. Thus, the widely used viscosity-related shear stress and shear rate criteria are insufficient in determining mechanotransduction-dominant systems. Thus, research should continue to consider the importance of mass transfer in triggering signaling cascades.
Geoelectrical Measurement of Multi-Scale Mass Transfer Parameters
Energy Technology Data Exchange (ETDEWEB)
Day-Lewis, Frederick; Singha, Kamini; Haggerty, Roy; Johnson, Tim; Binley, Andrew; Lane, John
2014-01-16
Mass transfer affects contaminant transport and is thought to control the efficiency of aquifer remediation at a number of sites within the Department of Energy (DOE) complex. An improved understanding of mass transfer is critical to meeting the enormous scientific and engineering challenges currently facing DOE. Informed design of site remedies and long-term stewardship of radionuclide-contaminated sites will require new cost-effective laboratory and field techniques to measure the parameters controlling mass transfer spatially and across a range of scales. In this project, we sought to capitalize on the geophysical signatures of mass transfer. Previous numerical modeling and pilot-scale field experiments suggested that mass transfer produces a geoelectrical signature—a hysteretic relation between sampled (mobile-domain) fluid conductivity and bulk (mobile + immobile) conductivity—over a range of scales relevant to aquifer remediation. In this work, we investigated the geoelectrical signature of mass transfer during tracer transport in a series of controlled experiments to determine the operation of controlling parameters, and also investigated the use of complex-resistivity (CR) as a means of quantifying mass transfer parameters in situ without tracer experiments. In an add-on component to our grant, we additionally considered nuclear magnetic resonance (NMR) to help parse mobile from immobile porosities. Including the NMR component, our revised study objectives were to: 1. Develop and demonstrate geophysical approaches to measure mass-transfer parameters spatially and over a range of scales, including the combination of electrical resistivity monitoring, tracer tests, complex resistivity, nuclear magnetic resonance, and materials characterization; and 2. Provide mass-transfer estimates for improved understanding of contaminant fate and transport at DOE sites, such as uranium transport at the Hanford 300 Area. To achieve our objectives, we implemented a 3
Dissociation and Mass Transfer Coefficients for Ammonia Volatilization Models
Process-based models are being used to predict ammonia emissions from manure sources, but their accuracy has not been fully evaluated for cattle manure. Laboratory trials were conducted to measure the dissociation and mass transfer coefficients for ammonia volatilization from media of buffered ammon...
Transient natural convection heat and mass transfer in crystal growth
Han, Samuel S.
1990-01-01
A numerical analysis of transient combined heat and mass transfer across a rectangular cavity is performed. The physical parameters are selected to represent a range of possible crystal growth in solutions. Good agreements with measurement data are observed. It is found that the thermal and solute fields become highly oscillatory when the thermal and solute Grashof numbers are large.
A Course in Advanced Topics in Heat and Mass Transfer.
Shaeiwitz, Joseph A.
1983-01-01
A three or four semester-hour graduate course was designed to provide basic instruction in heat/mass transfer topics relevant to chemical engineering problems and to train students to develop mathematical descriptions for new situations encountered in problem-solving. Course outline and list of references used in the course are provided. (JM)
MASS TRANSFER KINETICS AND EFFECTIVE DIFFUSIVITIES DURING COCOA ROASTING
Directory of Open Access Journals (Sweden)
Y. M. BAGHDADI
2017-01-01
Full Text Available The current studies investigated the effects of temperature and moisture addition on the mass transfer kinetics of cocoa nibs during roasting. Experiments were carried out by roasting 500 gm of cocoa nibs inside an air ventilated oven at three temperature levels (120°C, 140°C and 160°C under medium air flowrate for one hour. Two types of samples were prepared namely the raw and soaked nib samples. The soaked nib samples were prepared by soaking the raw nibs in 200 ml of water at room temperature for 5 and 10 hours. Mathematical modelling was carried out to model the mass transfer process using semi-empirical models. Modelling showed that both Page and two-term models were able to give close fitting between the experimental and predicted values. Effective diffusivity values were estimated in the order of magnitude of 10-5 m2/s for the mass transfer process. Results obtained from these studies fill the current knowledge gap on the mass transfer kinetics of cocoa roasting.
Mass transfer analysis for terephthalic acid biodegradation by ...
African Journals Online (AJOL)
Biodegradation of terephthalic acid (TA) by polyvinyl alcohol (PVA)-alginate immobilized Pseudomonas sp. was carried out in a packed-bed reactor. The effect of inlet TA concentration on biodegradation was investigated at 30°C, pH 7 and flow rate of 20 ml/min. The effects of flow rate on mass transfer and biodegradation ...
Mass transfer coefficients determination from linear gradient elution experiments.
Pfister, David; Morbidelli, Massimo
2015-01-02
A procedure to estimate mass transfer coefficients in linear gradient elution chromatography is presented and validated by comparison with experimental data. Mass transfer coefficients are traditionally estimated experimentally through the van Deemter plot, which represents the HETP as a function of the fluid velocity. Up to now, the HETP was obtained under isocratic elution conditions. Unfortunately, isocratic elution experiments are often not suitable for large biomolecules which suffer from severe mass transfer hindrances. Yamamoto et al. were the first to propose a semi-empirical equation to relate HETPs measured from linear gradient elution experiments to those obtained under isocratic conditions [7]. Based on his pioneering work, the approach presented in this work aims at providing an experimental procedure supported by simple equations to estimate reliable mass transfer parameters from linear gradient elution chromatographic experiments. From the resolution of the transport model, we derived a rigorous analytical expression for the HETP in linear gradient elution chromatography. Copyright © 2014 Elsevier B.V. All rights reserved.
Saponification reaction system: a detailed mass transfer coefficient determination.
Pečar, Darja; Goršek, Andreja
2015-01-01
The saponification of an aromatic ester with an aqueous sodium hydroxide was studied within a heterogeneous reaction medium in order to determine the overall kinetics of the selected system. The extended thermo-kinetic model was developed compared to the previously used simple one. The reaction rate within a heterogeneous liquid-liquid system incorporates a chemical kinetics term as well as mass transfer between both phases. Chemical rate constant was obtained from experiments within a homogeneous medium, whilst the mass-transfer coefficient was determined separately. The measured thermal profiles were then the bases for determining the overall reaction-rate. This study presents the development of an extended kinetic model for considering mass transfer regarding the saponification of ethyl benzoate with sodium hydroxide within a heterogeneous reaction medium. The time-dependences are presented for the mass transfer coefficient and the interfacial areas at different heterogeneous stages and temperatures. The results indicated an important role of reliable kinetic model, as significant difference in k(L)a product was obtained with extended and simple approach.
On some group properties of heat and mass transfer equations
Stepanova, I. V.
2017-10-01
Heat and mass transfer equations with variable transport coefficients are under study. The forms of unknown thermal conductivity, diffusion and Dufour coefficients are found by means of Lie group theory. It is shown that arbitrary elements have the power-law, logarithmic and exponential dependencies on temperature and concentration.
Mass transfer in rolling rotary kilns: a novel approach
Heydenrych, M.D.; Greeff, P.; Heesink, Albertus B.M.; Versteeg, Geert
2002-01-01
A novel approach to modeling mass transfer in rotary kilns or rotating cylinders is explored. The movement of gas in the interparticle voids in the bed of the kiln is considered, where particles move concentrically with the geometry of the kiln and gas is entrained by these particles. The approach
NUMERICAL SIMULATION OF MASS TRANSFER IN CENTRIFUGAL EVAPORATOR
Directory of Open Access Journals (Sweden)
E. N. Kalinin
2017-01-01
Full Text Available Subject of Research. The paper deals with the problem of an adequate mathematical model of mass transfer process occurring during evaporation and concentration of spent process solution in a centrifugal evaporator with variable geometric parameters. The model provides a science-based forecast of the process parameters. Methods. Definition of the film flow parameters on a rotating conical surface of the centrifugal evaporator rotor is carried out on the basis of the solution of Navier-Stokes equations. Solution of the system of differential equations describing the mass transfer process in the studied dynamic system is performed by numerical methods. With this aim in view, we realized semi-implicit finite difference scheme for the SIMPLE pressure. Main Results. We have developed an algorithm and performed numerical solution of differential equations describing the mass transfer process occurring during concentration of the working solution in the centrifugal type evaporator. On the basis of the obtained numerical solution we have created a computer model of the given process. With the aid of the model we have defined basic hydrodynamic and operating parameters of the evaporator, as well as dependencies between them. Practical Relevance. Developed computer model of the mass transfer process enables to define the parameters of the solution moving along the conical surface of the centrifugal evaporator rotor: speed, pressure and the thickness of the flowing-down film. The results can be applied in real industrial process management and during personnel training.
Modelling toluene oxidation : Incorporation of mass transfer phenomena
Hoorn, J.A.A.; van Soolingen, J.; Versteeg, G. F.
The kinetics of the oxidation of toluene have been studied in close interaction with the gas-liquid mass transfer occurring in the reactor. Kinetic parameters for a simple model have been estimated on basis of experimental observations performed under industrial conditions. The conclusions for the
Gas-liquid mass transfer coefficient in stirred tank reactors
Yawalkar, Archis A.; Heesink, Albertus B.M.; Versteeg, Geert; Pangarkar, Vishwas G.
2003-01-01
Volumetric gas—liquid mass transfer coefficient (kLa) data available in the literature for larger tanks (T = 0.39 m to 2.7 m) have been analyzed on the basis of relative dispersion parameter, N/Ncd. It was observed that at a given superficial gas velocity (VG), kLa values were approximately the same
Gas–Liquid Mass Transfer Coefficient in Stirred Tank Reactors
Yawalkar, Archis A.; Heesink, Albertus B.M.; Versteeg, Geert F.; Pangarkar, Vishwas G.
2002-01-01
Volumetric gas–liquid mass transfer coefficient (kLa) data available in the literature for larger tanks (T = 0.39 m to 2.7 m) have been analyzed on the basis of relative dispersion parameter, N/Ncd. It was observed that at a given superficial gas velocity (VG), kLa values were approximately the same
Estimation of convection heat and mass transfer coefficients for ...
African Journals Online (AJOL)
Estimation of convection heat and mass transfer coefficients for constant-rate drying period during tape casting. Y T Puyate. Abstract. No Abstract. Global Journal of Engineering Research Vol. 6 (1) 2007: pp. 75-77. Full Text: EMAIL FULL TEXT EMAIL FULL TEXT · DOWNLOAD FULL TEXT DOWNLOAD FULL TEXT.
Minimal mass transfer across dolomitic granular fault cores
Billi, Andrea; Primavera, Paolo; Soligo, Michele; Tuccimei, Paola
2008-01-01
The role of chemical changes and mass transfer in the formation of granular fault cores across carbonate strata is still unclear. Thirteen granular fault cores across strata of dolostone from Sperlonga, central Italy, are analyzed by chemical and physical methods. The analyzed faults are reverse or transpressional, up to about 1 m thick, and flanked by a host rock affected by a widely developed solution cleavage. Grain size distributions of fault core rocks are determined by a sieving procedure for grains larger than 63 μm. Mechanisms of grain comminution are inferred by microscopic analyses on a set of thin sections obtained from epoxy-impregnated fault rock samples. Concentrations of calcium and magnesium in the fault cores and in the adjacent host rock are determined by titrimetry. Results show that both the breccia and the gouge forming the fault cores show little evidence for mass transfer, regardless of the fault type and grain size distribution of fault rocks. We interpret these results as chiefly the effect, within the fault core, of a strongly reduced permeability, which impeded significant mass transfer processes through solute transport. It follows that grain comminution occurred mostly by brittle processes such as crushing and abrasive wear. Previous work suggests that these results are rather generalizable; some exceptions, however, compel further research on the role of circulating fluids and mass transfer in the formation of carbonate fault rocks.
Atmospheric composition affects heat- and mass-transfer processes
Blakely, R. L.; Nelson, W. G.
1970-01-01
For environmental control system functions sensitive to atmospheric composition, components are test-operated in helium-oxygen and nitrogen-oxygen mixtures, pure oxygen, and air. Transient heat- and mass-transfer tests are conducted for carbon dioxide adsorption on molecular sieve and for water vapor adsorption on silica gel.
Heat and mass transfer during baking: product quality aspects
Asselman, A.; Straten, van G.; Hadiyanto, H.; Boom, R.M.; Esveld, D.C.; Boxtel, van A.J.B.
2005-01-01
Abstract Most food product qualities are developed during heating processes. Therefore the internal heating and mass transfer of water are important aspects in food processing. Heating of food products is mostly induced by convection heating. However, the number applications of convective heating in
Modelling of heat and mass transfer processes in neonatology
Energy Technology Data Exchange (ETDEWEB)
Ginalski, Maciej K [FLUENT Europe, Sheffield Business Park, Europa Link, Sheffield S9 1XU (United Kingdom); Nowak, Andrzej J [Institute of Thermal Technology, Silesian University of Technology, Konarskiego 22, 44-100 Gliwice (Poland); Wrobel, Luiz C [School of Engineering and Design, Brunel University, Uxbridge UB8 3PH (United Kingdom)], E-mail: maciej.ginalski@ansys.com, E-mail: Andrzej.J.Nowak@polsl.pl, E-mail: luiz.wrobel@brunel.ac.uk
2008-09-01
This paper reviews some of our recent applications of computational fluid dynamics (CFD) to model heat and mass transfer problems in neonatology and investigates the major heat and mass transfer mechanisms taking place in medical devices such as incubators and oxygen hoods. This includes novel mathematical developments giving rise to a supplementary model, entitled infant heat balance module, which has been fully integrated with the CFD solver and its graphical interface. The numerical simulations are validated through comparison tests with experimental results from the medical literature. It is shown that CFD simulations are very flexible tools that can take into account all modes of heat transfer in assisting neonatal care and the improved design of medical devices.
Heat and Mass Transfer Model in Freeze-Dried Medium
Alfat, Sayahdin; Purqon, Acep
2017-07-01
There are big problems in agriculture sector every year. One of the major problems is abundance of agricultural product during the peak of harvest season that is not matched by an increase in demand of agricultural product by consumers, this causes a wasted agricultural products. Alternative way was food preservation by freeze dried method. This method was already using heat transfer through conduction and convection to reduce water quality in the food. The main objective of this research was to design a model heat and mass transfer in freeze-dried medium. We had two steps in this research, the first step was design of medium as the heat injection site and the second was simulate heat and mass transfer of the product. During simulation process, we use physical property of some agriculture product. The result will show how temperature and moisture distribution every second. The method of research use finite element method (FEM) and will be illustrated in three dimensional.
Bibliography on augmentation of convective heat and mass transfer
Energy Technology Data Exchange (ETDEWEB)
Bergles, A.E.; Webb, R.L.; Junkhan, G.H.; Jensen, M.K.
1979-05-01
Heat transfer augmentation has developed into a major specialty area in heat transfer research and development. A bibliography of world literature on augmentation is presented. The literature is classified into passive augmentation techniques, which require no external power, and active techniques, which do require external power. The fourteen techniques are grouped in terms of their application to the various modes of heat transfer. Mass transfer is included for completeness. Key words are included with each citation for technique/mode identification. The total number of publications cited is 1,967, including 75 surveys of various techniques and 42 papers on performance evaluation of passive techniques. Patents are not included as they will be the subject of a future topical report.
Application of Lattice Boltzmann Methods in Complex Mass Transfer Systems
Sun, Ning
Lattice Boltzmann Method (LBM) is a novel computational fluid dynamics method that can easily handle complex and dynamic boundaries, couple local or interfacial interactions/reactions, and be easily parallelized allowing for simulation of large systems. While most of the current studies in LBM mainly focus on fluid dynamics, however, the inherent power of this method makes it an ideal candidate for the study of mass transfer systems involving complex/dynamic microstructures and local reactions. In this thesis, LBM is introduced to be an alternative computational method for the study of electrochemical energy storage systems (Li-ion batteries (LIBs) and electric double layer capacitors (EDLCs)) and transdermal drug design on mesoscopic scale. Based on traditional LBM, the following in-depth studies have been carried out: (1) For EDLCs, the simulation of diffuse charge dynamics is carried out for both the charge and the discharge processes on 2D systems of complex random electrode geometries (pure random, random spheres and random fibers). Steric effect of concentrated solutions is considered by using modified Poisson-Nernst-Plank (MPNP) equations and compared with regular Poisson-Nernst-Plank (PNP) systems. The effects of electrode microstructures (electrode density, electrode filler morphology, filler size, etc.) on the net charge distribution and charge/discharge time are studied in detail. The influence of applied potential during discharging process is also discussed. (2) For the study of dendrite formation on the anode of LIBs, it is shown that the Lattice Boltzmann model can capture all the experimentally observed features of microstructure evolution at the anode, from smooth to mossy to dendritic. The mechanism of dendrite formation process in mesoscopic scale is discussed in detail and compared with the traditional Sand's time theories. It shows that dendrite formation is closely related to the inhomogeneous reactively at the electrode-electrolyte interface
Heat and mass transfer effects in a direct methanol fuel cell: A 1D model
Energy Technology Data Exchange (ETDEWEB)
Oliveira, V.B.; Falcao, D.S.; Pinto, A.M.F.R. [Centro de Estudos de Fenomenos de Transporte, Departamento de Eng. Quimica, Faculdade de Engenharia da Universidade do Porto, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal); Rangel, C.M. [INETI - Unidade de Electroquimica e Materiais, Paco do Lumiar, 22,1649-038 (Portugal)
2008-07-15
Models are a fundamental tool for the design process of fuel cells and fuel cell systems. In this work, a steady-state, one-dimensional model accounting for coupled heat and mass transfer, along with the electrochemical reactions occurring in the DMFC, is presented. The model output is the temperature profile through the cell and the water balance and methanol crossover between the anode and the cathode. The model predicts the correct trends for the influence of current density and methanol feed concentration on both methanol and water crossover. The model estimates the net water transfer coefficient through the membrane, {alpha}, a very important parameter to describe water management in the DMFC. Suitable operating ranges can be set up for different MEA structures maintaining the crossover of methanol and water within acceptable levels. The model is rapidly implemented and is therefore suitable for inclusion in real-time system level DMFC calculations. (author)
Griffioen, J.
1998-01-01
The concept of first-order mass transfer between mobile and immobile regions, which mathematically simplifies the concept of Fickian diffusion in stagnant areas, has often been used to describe physical nonequilibrium transport of solutes into natural porous media. This study compares the two
Study of molecular iodine-epoxy paint mass transfer
Energy Technology Data Exchange (ETDEWEB)
Belval-Haltier, E. [Inst. de Protection et Surete Nucleaire, IPSN, CEN Cadarache, St. Paul-lez-Durance (France)
1996-12-01
The mass transfer phenomena may have a significant influence on the quantity of I{sub 2} which could be released following a severe accident of a nuclear power plant and specially the mass transfer of iodine onto containment surfaces. So, the objective of the present work was to evaluate which phase limited the adsorption process of iodine onto gaseous epoxy paint under a range of conditions which may be relevant to a severe reactor accident. In this aim, a series of experiments was conducted in which the sorption kinetics of molecular iodine, labelled with {sup 131}I, was measured by monitoring continuously the accumulation of this species on the epoxy surface. For each test condition, the initial deposition velocity was determined and the corresponding gas phase mass transfer, kg, was estimated by using the heat transfer analogy for a laminar flow passing over a flat plate. Then, the surface reaction rate, Kr, was deduced from these two values. Experiments performed indicated that iodine adsorption onto epoxy paint is highly dependent on temperature, relative humidity of the carrier gas and moisture content of the painted coupon. In dry air flow conditions, the adsorption of iodine onto paint was found to increase with temperature and to be limited by the surface reaction rate, Kr. The I{sub 2} adsorption rate was found to increase with the humidity of carrier gas and in some studied conditions, the initial deposition velocity appeared to be controlled by gas phase mass transfer rather than surface interaction. The same phenomenon has been observed with an increase of the initial water content of the painted coupon. (author) 6 figs., 1 tab., 8 refs.
Rates of mass, momentum, and energy transfer at the magnetopause
Hill, T. W.
1979-01-01
Empirical estimates of the global rates of transfer of solar wind mass, tangential momentum, and energy at the Earth's magnetopause are presented for comparison against model estimates based on the four principal mechanisms that have been proposed to explain such transfer. The comparisons, although not quite conclusive, strongly favor a model that incorporates some combination of direct magnetic connection and anomalous cross field diffusion. An additional global constraint, the rate at which magnetic flux is cycled through the magnetospheric convection system, strongly suggests that direct magnetic connection plays a significant if not dominant role in the solar wind/magnetosphere interaction.
Heat and mass transfer in porous cavity: Assisting flow
Energy Technology Data Exchange (ETDEWEB)
Badruddin, Irfan Anjum [Dept. of Mechanical Engineering, University of Malaya, Kuala Lumpur, 50603 (Malaysia); Quadir, G. A. [School of Mechatronic Engineering, University Malaysia Perlis, Pauh Putra, 02600 Arau, Perlis (Malaysia)
2016-06-08
In this paper, investigation of heat and mass transfer in a porous cavity is carried out. The governing partial differential equations are non-dimensionalised and solved using finite element method. The left vertical surface of the cavity is maintained at constant temperature and concentration which are higher than the ambient temperature and concentration applied at right vertical surface. The top and bottom walls of the cavity are adiabatic. Heat transfer is assumed to take place by natural convection and radiation. The investigation is carried out for assisting flow when buoyancy and gravity force act in same direction.
Geoelectrical inference of mass transfer parameters using temporal moments
Day-Lewis, Frederick D.; Singha, Kamini
2008-01-01
We present an approach to infer mass transfer parameters based on (1) an analytical model that relates the temporal moments of mobile and bulk concentration and (2) a bicontinuum modification to Archie's law. Whereas conventional geochemical measurements preferentially sample from the mobile domain, electrical resistivity tomography (ERT) is sensitive to bulk electrical conductivity and, thus, electrolytic solute in both the mobile and immobile domains. We demonstrate the new approach, in which temporal moments of collocated mobile domain conductivity (i.e., conventional sampling) and ERT-estimated bulk conductivity are used to calculate heterogeneous mass transfer rate and immobile porosity fractions in a series of numerical column experiments. Copyright 2008 by the American Geophysical Union.
Heat and mass transfer in the melting of frost
Mohs, William F
2015-01-01
This Brief is aimed at engineers and researchers involved in the refrigeration industry: specifically, those interested in energy utilization and system efficiency. The book presents what the authors believe is the first comprehensive frost melting study involving all aspects of heat and mass transfer. The volume’s description of in-plane and normal digital images of frost growth and melting is also unique in the field, and the digital analysis technique offers an advantage over invasive measurement methods. The scope of book’s coverage includes modeling and experimentation for the frost formation and melting processes. The key sub-specialties to which the book are aimed include refrigeration system analysis and design, coupled heat and mass transfer, and phase-change processes.
Study of heat and mass transfer in evaporative coolers
Perez-Blanco, H.; Bird, W. A.
1982-06-01
Evaporative coolers are generally considered efficient and economical devices for rejecting waste heat. In these coolers, a hot fluid circulates inside tubes, rejecting heat to a mixture of air and water. Water is sprayed on the tubes and flows downward while air circulates upward; thus, latent and sensible heat is transferred from the water to the air. Commercially available coolers are of the horizonal tube type; a vertical tube evaporative cooler is studied because it is possible to enhance condensing heat transfer coefficients by using vertical fluted tubes. A mathematical model describing the performance of a single tube is formulated which can predict performance for varied inlet conditions, thereby eliminating the need for extensive testing. The validity of the model rests on the accuracy of the controlling heat and mass transfer coefficients used, so these coefficients are measured experimentally in a single tube cooler and found to agree with existing empirical correlations.
Esrael, D; Kacem, M; Benadda, B
2017-07-01
We investigate how the simulation of the venting/soil vapour extraction (SVE) process is affected by the mass transfer coefficient, using a model comprising five partial differential equations describing gas flow and mass conservation of phases and including an expression accounting for soil saturation conditions. In doing so, we test five previously reported quations for estimating the non-aqueous phase liquid (NAPL)/gas initial mass transfer coefficient and evaluate an expression that uses a reference NAPL saturation. Four venting/SVE experiments utilizing a sand column are performed with dry and non-saturated sand at low and high flow rates, and the obtained experimental results are subsequently simulated, revealing that hydrodynamic dispersion cannot be neglected in the estimation of the mass transfer coefficient, particularly in the case of low velocities. Among the tested models, only the analytical solution of a convection-dispersion equation and the equation proposed herein are suitable for correctly modelling the experimental results, with the developed model representing the best choice for correctly simulating the experimental results and the tailing part of the extracted gas concentration curve. Copyright © 2017 Elsevier B.V. All rights reserved.
Esrael, D.; Kacem, M.; Benadda, B.
2017-07-01
We investigate how the simulation of the venting/soil vapour extraction (SVE) process is affected by the mass transfer coefficient, using a model comprising five partial differential equations describing gas flow and mass conservation of phases and including an expression accounting for soil saturation conditions. In doing so, we test five previously reported quations for estimating the non-aqueous phase liquid (NAPL)/gas initial mass transfer coefficient and evaluate an expression that uses a reference NAPL saturation. Four venting/SVE experiments utilizing a sand column are performed with dry and non-saturated sand at low and high flow rates, and the obtained experimental results are subsequently simulated, revealing that hydrodynamic dispersion cannot be neglected in the estimation of the mass transfer coefficient, particularly in the case of low velocities. Among the tested models, only the analytical solution of a convection-dispersion equation and the equation proposed herein are suitable for correctly modelling the experimental results, with the developed model representing the best choice for correctly simulating the experimental results and the tailing part of the extracted gas concentration curve.
Bubble Coalescence and Breakup Modeling for Computing Mass Transfer Coefficient
Mawson, Ryan A.
2012-01-01
There exist several different numerical models for predicting bubble coalescence and breakup using computational fluid dynamics (CFD). Various combinations of these models will be employed to model a bioreactor process in a stirred reactor tank. A mass transfer coefficient, Kla, has been calculated and compared to those found experimentally by Thermo-Fisher Scientific, to validate the accuracy of currently available mathematical models for population balance equations. These include various c...
Mass transfer ways of ultraviolet printing ink ingredients into foodstuffs.
Jung, T; Simat, T J; Altkofer, W
2010-07-01
The case of isopropylthioxanthone (ITX) showed conclusively that the ingredients of ultraviolet printing inks may migrate into packaged foodstuffs. For multilayered materials like beverage cartons, the only way that mass transfer can occur is by the so-called set-off effect. In contrast, in the case of rigid plastics like yoghurt cups, two other methods of mass transfer, permeation and gas phase, have to be considered. In cooperation with producers of ink, plastic cups and yoghurt, a project was conducted in order to elucidate the mass transfer of ink ingredients. In addition, the influence of storage time and the age of ultraviolet lamps on the migration level was examined. The suitability of 50% ethanol as a simulant for yoghurt was also tested. ITX was chosen as a model migrant, as it is easily detectable. Furthermore, the migration of two other substances, the photo-initiator 2-methyl-4'-(methylthio)-2-morpholinopropiophenone (MTMP) and the amine synergist ethyl-4-(dimethylamino)benzoate (EDAB), which may be used in combination with ITX, was studied. Before being filled with yoghurt or 50% ethanol, the printed cups were stored under different contact conditions, with and without contact between the inner layer and the printed surfaces, in order to distinguish between the possible mass transfer ways. All analyses were performed by means of high performance liquid chromatography with diode array and fluorescence detection (HPLC-DAD/FLD). It was shown that contamination with ITX and EDAB occurs via set-off and that the degree of migration increases with lamp age and storage time of the unfilled cups. Migration of MTMP was not detectable. The results show that besides the careful selection of the appropriate raw materials for printing ink, a close monitoring of the process also plays a major role in migration control. In addition, the results proved that 50% ethanol is a suitable simulant for yoghurt.
Influence of impeller type on mass transfer in fermentation vessels
Energy Technology Data Exchange (ETDEWEB)
Junker, B.H.; Stanik, M.; Salmon, P.; Buckland, B.C. [Merck Sharp and Dohme Research Labs., Rahway, NJ (United States); Barna, C. [Merck Manufacturing Div., West Point, PA (United States)
1998-12-01
Radial flow Rushton impellers were compared qualitatively with axial flow hydrofoil impellers (Maxflo T and A315) at the pilot scale. Six types of impellers were compared for qualitative differences in mass transfer. Measurements were conducted using three model systems: water, glycerol and Melojel (soluble starch). Power measurements were obtained using watt transducers, which although limited in accuracy and prone to interferences, were able to provide useful qualitative monitoring results. While there was little effect of impeller type on mass transfer as measured by the rapid pressure increase technique, significant qualitative differences were observed using the rapid temperature increase technique specifically for the Melojel and glycerol model systems. The Miller correlation, relating gassed-to-ungassed power, was used effectively to qualitatively evaluate the power drop upon gassing for both the model systems and a Streptomyces fermentation for the various impeller types.A high oxygen demand Streptomcyes fermentation then was conducted in fermenters possessing each type of impeller. Performance was not adequate with the A315 impellers pumping upwards and the small diameter Maxflo T impellers. Peak titers and profiles of the estimated apparent broth viscosity varied depending upon the impeller type. Mass transfer rates generally declined with higher viscosities when other fermentation operating conditions where held constant. Overall, values for OUR, k{sub L}a, P{sub g}/V{sub L} and other calculated mass transfer and power input quantities for the A315 pumping upwards and undersized Maxflo T (D{sub T}/D{sub I} = 2.3) impellers were at the lower end of the range obtained for the larger Maxflo T (D{sub T}/D{sub I} = 1.8-2.0) and A315 impellers pumping downwards. Rushton impellers generally behaved qualitatively similar to hydrofoil impellers based on these calculated quantities. (orig.) With 7 figs., 10 tabs.
Combined heat and mass transfer device for improving separation process
Tran, Thanh Nhon
1999-01-01
A two-phase small channel heat exchange matrix simultaneously provides for heat transfer and mass transfer between the liquid and vapor phases of a multi-component mixture at a single, predetermined location within a separation column, significantly improving the thermodynamic efficiency of the separation process. The small channel heat exchange matrix is composed of a series of channels having a hydraulic diameter no greater than 5.0 millimeters for conducting a two-phase coolant. In operation, the matrix provides the liquid-vapor contacting surfaces within the separation column, such that heat and mass are transferred simultaneously between the liquid and vapor phases. The two-phase coolant allows for a uniform heat transfer coefficient to be maintained along the length of the channels and across the surface of the matrix. Preferably, a perforated, concave sheet connects each channel to an adjacent channel to facilitate the flow of the liquid and vapor phases within the column and to increase the liquid-vapor contacting surface area.
Liquid-gas mass transfer at drop structures.
Matias, Natércia; Nielsen, Asbjørn Haaning; Vollertsen, Jes; Ferreira, Filipa; Matos, José Saldanha
2017-05-01
Over the last decades, considerable progress has been made in the understanding of the sulfur cycle in sewer systems. In spite of a wealth of experimental and field studies that have addressed the release of hydrogen sulfide from free surface flows in gravity sewers and the corresponding air-water mass transfer, little is known about hydrogen sulfide emission under highly turbulent conditions (e.g., drop structures, hydraulic jumps). In this study, experimental work was carried out to analyze the influence of characteristics of drops on reaeration. Physical models were built, mimicking typical sewer drop structures and allowing different types of drops, drop heights, tailwater depths and flow rates. In total, 125 tests were performed. Based on their results, empirical expressions translating the relationship between the mass transfer of oxygen and physical parameters of drop structures were established. Then, by applying the two-film theory with two-reference substances, the relation to hydrogen sulfide release was defined. The experiments confirmed that the choice of the type of drop structure is critical to determine the uptake/emission rates. By quantifying the air-water mass transfer rates between free-fall and backdrop types of drop, the latter resulted in considerably lower oxygen uptake rates.
MASS TRANSFER IN PORE STRUCTURES OF SUPPORTED CATALYSTS
Directory of Open Access Journals (Sweden)
F.R.C. Silva
1997-09-01
Full Text Available The effects of gas-solid interaction and mass transfer in fixed-bed systems of supported catalysts were analyzed for g -Al2O3 (support and Cu/g -Al2O3 (catalyst systems. Evaluations of the mass transfer coefficients in the macropores and of the diffusivity in the micropores, as formed by the crystallite agglomerates of the metallic phases, were obtained. Dynamic experiments with gaseous tracers permitted the quantification of the parameters based on models for these two pore structures. With a flow in a range of 18 cm3 s-1 to 39.98 cm3 s-1 at 45oC, 65oC and 100oC, mass transfer coefficients km =4.33x10-4 m s-1 to 7.38x10-4 m s-1 for macropore structures and diffusivities Dm =1.29x10-11 m2 s-1 to 5.35x10-11 m2 s-1 for micropore structures were estimated
Heat and mass transfer analysis of a desiccant dehumidifier matrix
Energy Technology Data Exchange (ETDEWEB)
Pesaran, A.A.
1986-07-01
This report documents the SERI Single-Blow Test Facility's design, fabrication, and testing for characterizing desiccant dehumidifiers for solar cooling applications. The first test article, a silica-gel parallel-plate dehumidifier with highly uniform passages, was designed and fabricated. Transient heat and mass transfer data and pressure drop data across the dehumidifier were obtained. Available heat and mass transfer models were extended to the parallel-place geometry, and the experimental data were compared with model predictions. Pressure drop measurements were also compared with model predictions of the fully developed laminar flow theory. The comparisons between the lumped-capacitance model and the experimental data were satisfactory. The pressure drop data compared satisfactorily with the theory (within 15%). A solid-side resistance model that is more detailed and does not assume symmetrical diffusion in particles was recommended for performance. This study has increased our understanding of the heat and mass transfer in silica gel parallel-plate dehumidifiers.
Proton Transfer Time-of-Flight Mass Spectrometer
Energy Technology Data Exchange (ETDEWEB)
Watson, Thomas B. [Brookhaven National Lab. (BNL), Upton, NY (United States)
2016-03-01
The Proton Transfer Reaction Mass Spectrometer (PTRMS) measures gas-phase compounds in ambient air and headspace samples before using chemical ionization to produce positively charged molecules, which are detected with a time-of-flight (TOF) mass spectrometer. This ionization method uses a gentle proton transfer reaction method between the molecule of interest and protonated water, or hydronium ion (H_{3}O^{+}), to produce limited fragmentation of the parent molecule. The ions produced are primarily positively charged with the mass of the parent ion, plus an additional proton. Ion concentration is determined by adding the number of ions counted at the molecular ion’s mass-to-charge ratio to the number of air molecules in the reaction chamber, which can be identified according to the pressure levels in the reaction chamber. The PTRMS allows many volatile organic compounds in ambient air to be detected at levels from 10–100 parts per trillion by volume (pptv). The response time is 1 to 10 seconds.
Dullaart, R. P. F.; de Vries, R.; Dallinga-Thie, G. M.; van Tol, A.; Sluiter, W. J.
Adipose tissue contributes to plasma levels of lipid transfer proteins and is also the major source of plasma adipokines. We hypothesized that plasma cholesteryl ester transfer protein (CETP) mass, phospholipid transfer protein (PLTP) activity and cholesteryl ester transfer (CET, a measure of CETP
Mass Transfer in a closed stirred gas/liquid contactor: Part 1: The mass transfer rate kLS
Koetsier, W.T.; Thoenes, D.; Frankena, J.F.
1973-01-01
Liquid phase mass transfer rates kLS for the absorption of oxygen in tap water and in aqueous ionic solutions have been determined in two closed stirred tank contactors for a power input between 3 and 70 W/kg and (impeller diameter)f(tank diameter) ratios DifT of 0.3, 0.35 and 0.4. The contactors
Mass Transfer Model of Desulfurization in the Electroslag Remelting Process
Hou, Dong; Jiang, Zhou-Hua; Dong, Yan-Wu; Li, Yang; Gong, Wei; Liu, Fu-Bin
2017-06-01
Experimental and theoretical studies have been carried out to investigate the effects of the slag on desulfurization during the electroslag remelting (ESR) process with a focus of developing a mass transfer model to understand the mechanism of desulfurization. Stainless steel 1Cr21Ni5Ti was used as the electrode and remelted with two different kinds of slags using a 50-kg ESR furnace. The contents of sulfur along the axial direction of product ingots were analyzed. It was found that the sulfur content of 350 ppm in the electrode is reduced to 71 to 95 ppm in the ingot by remelting with the slag containing 5 wt pct of CaO, and lowered more to 47 to 59 ppm with another slag having 20 wt pct CaO. On the basis of the penetration and film theories, the theoretical model developed in this work well elucidates the kinetics of desulfurization revealing the mechanism of sulfur transfer during the ESR process. The calculation results obtained from the model agree well with the experimental results. The model indicates that when sulfur content in electrode is given, there is a corresponding minimum value of sulfur content in the ingot due to the kinetics limit. This lowest sulfur content cannot be further reduced even with increasing L S (sulfur distribution coefficient between metal and slag phases) or decreasing sulfur content in the slag. Constant addition of extra amount of CaO to the molten slag with the increase of sulfur content in the slag during the remelting process can improve the macrosegregation of sulfur distributed along the axial direction of ESR ingots. Since the rate-determining steps of the sulfur mass transfer lie in the metal phase, adding calcium as deoxidizer can change mass transfer of sulfur and thus promote desulfurization further during the ESR process.
Heat and mass transfer and hydrodynamics in swirling flows (review)
Leont'ev, A. I.; Kuzma-Kichta, Yu. A.; Popov, I. A.
2017-02-01
Research results of Russian and foreign scientists of heat and mass transfer in whirling flows, swirling effect, superficial vortex generators, thermodynamics and hydrodynamics at micro- and nanoscales, burning at swirl of the flow, and technologies and apparatuses with the use of whirling currents for industry and power generation were presented and discussed at the "Heat and Mass Transfer in Whirling Currents" 5th International Conference. The choice of rational forms of the equipment flow parts when using whirling and swirling flows to increase efficiency of the heat-power equipment and of flow regimes and burning on the basis of deep study of the flow and heat transfer local parameters was set as the main research prospect. In this regard, there is noticeable progress in research methods of whirling and swirling flows. The number of computational treatments of swirling flows' local parameters has been increased. Development and advancement of the up to date computing models and national productivity software are very important for this process. All experimental works are carried out with up to date research methods of the local thermoshydraulic parameters, which enable one to reveal physical mechanisms of processes: PIV and LIV visualization techniques, high-speed and infrared photography, high speed registration of parameters of high-speed processes, etc. There is a problem of improvement of researchers' professional skills in the field of fluid mechanics to set adequately mathematics and physics problems of aerohydrodynamics for whirling and swirling flows and numerical and pilot investigations. It has been pointed out that issues of improvement of the cooling system and thermal protection effectiveness of heat-power and heat-transfer equipment units are still actual. It can be solved successfully using whirling and swirling flows as simple low power consumption exposing on the flow method and heat transfer augmentation.
Mathematical model of mass transfer at electron beam treatment
Konovalov, Sergey V.; Sarychev, Vladimir D.; Nevskii, Sergey A.; Kobzareva, Tatyana Yu.; Gromov, Victor E.; Semin, Alexander P.
2017-01-01
The paper proposes a model of convective mass transfer at electron beam treatment with beams in titanium alloys subjected to electro-explosion alloying by titanium diboride powder. The proposed model is based on the concept that treatment with concentrated flows of energy results in the initiation of vortices in the melted layer. The formation mechanism of these vortices rooted in the idea that the availability of temperature drop leads to the initiation of the thermo-capillary convection. For the melted layer of metal the equations of the convective heat transfer and boundary conditions in terms of the evaporated material are written. The finite element solution of these equations showed that electron-beam treatment results in the formation of multi-vortex structure that in developing captures all new areas of material. It leads to the fact that the strengthening particles are observed at the depth increasing many times the depth of their penetration according to the diffusion mechanism. The distribution of micro-hardness at depth and the thickness of strengthening zone determined from these data supported the view that proposed model of the convective mass transfer describes adequately the processes going on in the treatment with low-energy high-current electron beam.
Heat and mass transfers in the jets; Transferts de chaleur et de masse dans les jets
Energy Technology Data Exchange (ETDEWEB)
NONE
2001-07-01
This day on the heat and mass transfers in the jets, was organized by the SFT (French Society of Thermic) to present the state of the art in the domain. Fifteen presentations allowed the participants to discuss about turbulent flows, simulation of fluid flow and jets impacts. (A.L.B.)
Transferring Mass between Circumstellar Disks during Stellar Flybys
Hammer, Michael; Jílková, Lucie; Portegies Zwart, Simon
2015-01-01
Early in its life, a star that still lives in its birth cluster has the chance to encounter - or 'fly by' - other stars depending on the density of the cluster. These stellar interactions can significantly alter a star's disk if the flyby is close enough. While previous studies have analyzed what happens to the part of the disk that is able to survive an encounter, we focus on studying the lost disk particles that transfer from one star to the other by simulating the flybys using a hybrid N-body method derived from integrators in the AMUSE package. (1) We conduct a parameter study to simulate a variety of flyby conditions - including [i] the mass ratio of the two stars, [ii] the distance of closest approach of the flyby, and [iii] the eccentricity of the flyby orbit. (2) Quantitatively, we find the furthest flyby distance across the parameter study that can induce disk particles to transfer and find a fit for the percentage of transferred disk particles. We also investigate what types of orbits those transferred particles develop. (3) Lastly, we consider implications for potential stellar flybys in the history of our solar system.
Mass transfers through electromagnetically stirred interfaces - nuclear wastes application
Energy Technology Data Exchange (ETDEWEB)
Courtessole, C.; Etay, J. [CNRS-SIMAP-EPM ENSEEG BP75 38402 St Martin d' Heres Cedex (France); SAADI, B.; Allibert, M. [23 Av. Marcellin Berthelot 38100 Grenoble (France)
2009-06-15
Molten salts are good heat conductors. They are identified for future applications such as the implementation of a GEN IV nuclear reactor, heat transportation between 650 deg. and 850 deg. C for the hydrogen generation purpose, and electrolysis of aluminum between 850 deg. and 950 deg. C. Generally speaking, these salts are aggressive for materials that maintain them such as transportation, mixing and chemical composition. That is why we want to study and implement induction devices to replace the functions of these materials by electromagnetic forces. This will allow a dual benefit: improving the longevity and reduce secondary wastes. In the present work, we use a specific electromagnetic device for accelerating mass transfers through liquid / liquid interface. To reduce barriers to transfer, the interface is shacked at a frequency near of one of its natural frequencies. To achieve this, we use an adapted dual-frequency electromagnetic field. A pyrometallurgy pre-industrial graded facility, based on cold crucible technique, is used to carry out numerous experiments on the extraction of actinides and other elements from a fluorinated salt into a liquid metal phase containing a reducing agent such as magnesium, aluminium or lithium. At time t = 0, the metallic alloy is poured under the molten salt. Metallic samples are taken from the bulk at known time intervals. Later, the samples are analysed using optical ICP. Transfer rate and kinetics are deduced from obtained experimental data. Compare to other treatment, the present one is found to lead faster to a higher rate of transfer. (authors)
Saha, Dipendu
2009-02-01
The feasibility of drastically reducing the contactor size in mass transfer processes utilizing centrifugal field has generated a lot of interest in rotating packed bed (Higee). Various investigators have proposed correlations to predict mass transfer coefficients in Higee, but, none of the correlations was more than 20-30% accurate. In this work, artificial neural network (ANN) is employed for predicting mass transfer coefficient data. Results show that ANN provides better estimation of mass transfer coefficient with accuracy 5-15%.
Characterizing Mass Transfer at the Hanford 300 Area
Hall, L. H.
2012-12-01
Aquifer remediation efforts in the Hanford 300 Area in Washington have presented substantial challenges for the Department of Energy. Since the early 1940s, this site has been a receptacle for radiological and chemical wastes from nuclear weapons production, including high concentrations of uranium. Employing techniques to estimate and measure mass transfer in-situ will improve understanding of contaminant fate and transport at this site, and perhaps others. A field experiment was conducted with a combination of electrical resistivity tomography (ERT) and ionic tracer tests through a double-ring infiltrometer to quantify multirate mass-transfer and other transport parameters in the 300 Area. The tests included a series of injections into an infiltrating column of water. After saturating the column with fresh water at a constant head, bromide tracer solution with initial known concentration was injected for a specified amount of hours. This was followed by a continual fresh water injection during which time fluid samples were taken at varying depths along the probe to observe the tailing of the breakthrough curve during this purge. Throughout the experiment, ERT data collected along the column as well as along a transect perpendicular to the vertical sampling ports. These experiments will result in a model of the local vadose zone which will be calibrated using field data and modeled using HYDRUS 2D and its sequential inverse modeling feature. This program numerically solves the Richards equation for variably saturated water flow and advection-dispersion (AD) type equations for solute transport. It also considers dual-porosity type flow in the mobile and immobile domain. Additionally, mass transfer parameters will be modeled using a code which utilizes the AD equation and numerically solves for concentrations using Laplace Transforms. Analysis on governing processes and calibration of this code using field data will be used for additional verification on
Direct geoelectrical evidence of mass transfer at the laboratory scale
Swanson, Ryan D.; Singha, Kamini; Day-Lewis, Frederick D.; Binley, Andrew; Keating, Kristina; Haggerty, Roy
2012-01-01
Previous field-scale experimental data and numerical modeling suggest that the dual-domain mass transfer (DDMT) of electrolytic tracers has an observable geoelectrical signature. Here we present controlled laboratory experiments confirming the electrical signature of DDMT and demonstrate the use of time-lapse electrical measurements in conjunction with concentration measurements to estimate the parameters controlling DDMT, i.e., the mobile and immobile porosity and rate at which solute exchanges between mobile and immobile domains. We conducted column tracer tests on unconsolidated quartz sand and a material with a high secondary porosity: the zeolite clinoptilolite. During NaCl tracer tests we collected nearly colocated bulk direct-current electrical conductivity (σb) and fluid conductivity (σf) measurements. Our results for the zeolite show (1) extensive tailing and (2) a hysteretic relation between σf and σb, thus providing evidence of mass transfer not observed within the quartz sand. To identify best-fit parameters and evaluate parameter sensitivity, we performed over 2700 simulations of σf, varying the immobile and mobile domain and mass transfer rate. We emphasized the fit to late-time tailing by minimizing the Box-Cox power transformed root-mean square error between the observed and simulated σf. Low-field proton nuclear magnetic resonance (NMR) measurements provide an independent quantification of the volumes of the mobile and immobile domains. The best-fit parameters based on σf match the NMR measurements of the immobile and mobile domain porosities and provide the first direct electrical evidence for DDMT. Our results underscore the potential of using electrical measurements for DDMT parameter inference.
Transient mass transfer at the rotating disk electrode.
Nanis, L.; Klein, I.
1972-01-01
Transient mass transfer at the rotating disk has been investigated theoretically and experimentally for cathodic reduction of ferricyanide in the redox system ferricyanide-ferrocyanide with potassium hydroxide supporting electrolyte. It has been shown that overpotential-time predictions for the rotating disk are fitted very well for decay (current interruption) but poorly for build-up following switching on of constant current. As an explanation for this behavior, attention is directed to the inadequacy of the assumption that a radially independent concentration profile exists at the disk surface just at the start of galvanostatic current passage.
Schlieren and Shadowgraph Methods in Heat and Mass Transfer
Panigrahi, Pradipta Kumar
2012-01-01
Schlieren and Shadowgraph Methods in Heat and Mass Transfer lays out the fundamentals of refractive index based imaging techniques, optical configurations, image analysis, and three dimensional reconstructions. The present monograph aims at temperature and concentration measurements in transparent media using ray bending effects in a variable refractive index field. Data analysis procedure for three-dimensional reconstruction of temperature and concentration field using images at different view angles is presented. Test cases illustrating the validation of the quantitative analysis procedure are presented.
Mass Transfer From Fundamentals to Modern Industrial Applications
Asano, Koichi
2006-01-01
This didactic approach to the principles and modeling of mass transfer as it is needed in modern industrial processes is unique in combining a step-by-step introduction to all important fundamentals with the most recent applications. Based upon the renowned author's successful new modeling method as used for the O-18 process, the exemplary exercises included in the text are fact-proven, taken directly from existing chemical plants. Fascinating reading for chemists, graduate students, chemical and process engineers, as well as thermodynamics physicists.
Gas stream in Algol. [mass transfer in binary star systems
Cugier, H.; Chen, K.-Y.
1977-01-01
Additional absorption features in the red wings of the Mg II resonance lines near 2800 A are found in observations of Algol made from the Copernicus satellite. The absorption features were clearly seen only during a part of the primary eclipse, in the phase interval 0.90-0.03. The observations are interpreted as being produced by a stream of matter flowing from Algol B in the direction of Algol A. The measured Doppler shifts of the features give the value of 150 km/s as the characteristic velocity of matter in the stream. The mass transfer connected with the stream is estimated to be of the order of 10 to the -13th power solar mass per year.
Mass transfer in porous media with heterogeneous chemical reaction
Directory of Open Access Journals (Sweden)
Souza S.M.A.G.Ulson de
2003-01-01
Full Text Available In this paper, the modeling of the mass transfer process in packed-bed reactors is presented and takes into account dispersion in the main fluid phase, internal diffusion of the reactant in the pores of the catalyst, and surface reaction inside the catalyst. The method of volume averaging is applied to obtain the governing equation for use on a small scale. The local mass equilibrium is assumed for obtaining the one-equation model for use on a large scale. The closure problems are developed subject to the length-scale constraints and the model of a spatially periodic porous medium. The expressions for effective diffusivity, hydrodynamic dispersion, total dispersion and the Darcy's law permeability tensors are presented. Solution of the set of final equations permits the variations of velocity and concentration of the chemical species along the packed-bed reactors to be obtained.
Acoustic Streaming and Heat and Mass Transfer Enhancement
Trinh, E. H.; Gopinath, A.
1996-01-01
A second order effect associated with high intensity sound field, acoustic streaming has been historically investigated to gain a fundamental understanding of its controlling mechanisms and to apply it to practical aspects of heat and mass transfer enhancement. The objectives of this new research project are to utilize a unique experimental technique implementing ultrasonic standing waves in closed cavities to study the details of the generation of the steady-state convective streaming flows and of their interaction with the boundary of ultrasonically levitated near-spherical solid objects. The goals are to further extend the existing theoretical studies of streaming flows and sample interactions to higher streaming Reynolds number values, for larger sample size relative to the wavelength, and for a Prandtl and Nusselt numbers parameter range characteristic of both gaseous and liquid host media. Experimental studies will be conducted in support to the theoretical developments, and the crucial impact of microgravity will be to allow the neglect of natural thermal buoyancy. The direct application to heat and mass transfer in the absence of gravity will be emphasized in order to investigate a space-based experiment, but both existing and novel ground-based scientific and technological relevance will also be pursued.
Mass transfer effects in hygroscopic measurements of aerosol particles
Directory of Open Access Journals (Sweden)
M. N. Chan
2005-01-01
Full Text Available The tandem differential mobility analyzer (TDMA has been widely utilized to measure the hygroscopicity of laboratory-generated and atmospheric submicrometer particles. An important concern in investigating the hygroscopicity of the particles is if the particles have attained equilibrium state in the measurements. We present a literature survey to investigate the mass transfer effects in hygroscopicity measurements. In most TDMA studies, a residence time in the order of seconds is used for humidification (or dehumidification. NaCl and (NH42SO4 particles are usually used to verify the equilibrium measurements during this residence time, which is presumed to be sufficient for other particles. There have been observations that not all types of submicrometer particles, including atmospheric particles, attain their equilibrium sizes within this time scale. We recommend that experimentation with different residence times be conducted and that the residence time should be explicitly stated in future TDMA measurements. Mass transfer effects may also exist in the measurements of other properties related to the water uptake of atmospheric particles such as relative humidity dependent light scattering coefficients and cloud condensation nuclei activity.
Hornblendite delineates zones of mass transfer through the lower crust
Daczko, Nathan R.; Piazolo, Sandra; Meek, Uvana; Stuart, Catherine A.; Elliott, Victoria
2016-08-01
Geochemical signatures throughout the layered Earth require significant mass transfer through the lower crust, yet geological pathways are under-recognized. Elongate bodies of basic to ultrabasic rocks are ubiquitous in exposures of the lower crust. Ultrabasic hornblendite bodies hosted within granulite facies gabbroic gneiss of the Pembroke Valley, Fiordland, New Zealand, are typical occurrences usually reported as igneous cumulate hornblendite. Their igneous features contrast with the metamorphic character of their host gabbroic gneiss. Both rock types have a common parent; field relationships are consistent with modification of host gabbroic gneiss into hornblendite. This precludes any interpretation involving cumulate processes in forming the hornblendite; these bodies are imposter cumulates. Instead, replacement of the host gabbroic gneiss formed hornblendite as a result of channeled high melt flux through the lower crust. High melt/rock ratios and disequilibrium between the migrating magma (granodiorite) and its host gabbroic gneiss induced dissolution (grain-scale magmatic assimilation) of gneiss and crystallization of mainly hornblende from the migrating magma. The extent of this reaction-replacement mechanism indicates that such hornblendite bodies delineate significant melt conduits. Accordingly, many of the ubiquitous basic to ultrabasic elongate bodies of the lower crust likely map the ‘missing’ mass transfer zones.
Mass transfer and transport in a geologic environment
Energy Technology Data Exchange (ETDEWEB)
Chambre, P.L.; Pigford, T.H.; Lee, W.W.L.; Ahn, J.; Kajiwara, S.; Kim, C.L.; Kimura, H.; Lung, H.; Williams, W.J.; Zavoshy, S.J.
1985-04-01
This report is in a continuing series of reports that present analytic solutions for the dissolution and hydrogeologic transport of radionuclides from geologic repositories of nuclear waste. Previous reports have dealt mainly with radionuclide transport in the far-field, away from the effects of the repository. In the present report, the emphasis is on near-field processes, the transfer and transport of radionuclides in the vicinity of the waste packages. The primary tool used in these analyses is mass transfer theory from chemical engineering. The thrust of our work is to develop methods for predicting the performance of geologic repositories. The subjects treated in the present report are: radionuclide transport from a spherical-equivalent waste form through a backfill; analysis of radionuclide transport through a backfill using a non-linear sorption isotherm; radionuclide transport from a prolate spheroid-equivalent waste form with a backfill; radionuclide transport from a spherical-equivalent waste form through a backfill, where the solubility, diffusivity and retardation coefficients are temperature dependent; a coupled near-field, far-field analysis where dissolution and migration rates are temperature dependent; transport of radionuclides from a point source in a three-dimensional flow field; and a general solution for the transport of radioactive chains in geologic media. There are several important results from the numerical evaluations. First, radioactive decay, higher sorption in the rock and the backfill steepens the gradient for mass transfer, and lead to higher dissolution rates. This is contrary to what was expected by some other workers, but is shown clearly in the analytical solutions. Second, the backfill serves to provide sorption sites so that there is a delay in the arrival of radionuclides in the rock, although this effect is not so important for the steady-state transport of long-lived radionuclides.
Lee, Jung Gil
2017-11-03
In order to improve water production of membrane distillation (MD), the development of high performance membrane having better mass transfer and enhancement of convection heat transfer in MD module have been continuously investigated. This paper presents the relationship between the heat and mass transfer resistance across the membrane and the performance improvement. Various ranges of mass transfer coefficient (MTC) from normal (0.3×10−6 to 2.1×10−6kg/m2sPa: currently available membranes) to high (>2.1×10−6kg/m2sPa: membranes under development) were simulated using an experimentally validated model at different ranges of convection heat transfer by varying the inlet flow rates and spacer enhancement factor. The effect of mass transfer and convection heat transfer on the MD performance parameters including temperature polarization coefficient (TPC), mean permeate flux, and specific energy consumption were investigated in a direct contact MD (DCMD) configuration. Results showed that improving the MTC at the low ranges is more important than that at the high ranges where the heat transfer resistance becomes dominant and hence the convection heat transfer coefficient must be increased. Therefore, an effort on designing MD modules using feed and permeate spacers and controlling the membrane surface roughness to increase the convection heat transfer and TPC in the channel aiming to enhance the flux is required because the currently developed mass transfer has almost reached the critical point.
Analysis of the suction effect on the mass transfer when using the heat and mass transfer analogy
Energy Technology Data Exchange (ETDEWEB)
Rosa, J.C. de la [Department of PRA and Fluid Systems, Initec-Westinghouse Technology Services, S.A., Nuclear Services Business, Central Nuclear de Vandellos II, Aptdo. de correos no 48, 43890 L' Hospitalet de L' Infant, Tarragona (Spain)], E-mail: jcrosa@anacnv.com; Herranz, L.E. [Unit of Nuclear Safety Research CIEMAT, Avda. Complutense 22, 28040 Madrid (Spain); Munoz-Cobo, J.L. [Department of Chemical and Nuclear Engineering, Polytechnic University of Valencia Camino de Vera S/N, 46022 Valencia (Spain)
2009-10-15
The transport phenomenon between a fluid in movement and a wall is strongly affected by the permeability of the wall. The application of a correction factor standing for the transpiration effect will be required whenever a heat transfer model is based either on the use of heat, mass or momentum analogies or on the use of empirical correlations for the computation of the heat transfer coefficient. The suction factor commonly used when solving as a function of either mass or molar fractions is called the Bird suction factor. The validity of this factor rests on the hypothesis of the film theory or Couette flow. This paper reviews the Bird suction factor in laminar regime, extending the analysis to turbulent flow conditions and finding thereby that Bird's equation can overestimate the suction factor under turbulent condensation conditions in the gas phase. Finally, an alternative formulation for the suction factor under turbulent condensation conditions has been proposed and compared with Bird's original formulation. In doing this, both data and models developed by other authors and the UW-Madison test facility database have been used. The results show the suitability of the alternative formulation when calculating the condensation rate in turbulent natural circulation scenarios, whereas Bird's formulation seems to be more appropriate for laminar regimes.
COOLING, *POROUS MATERIALS), (*HEAT TRANSFER, *COMBUSTION), (* MASS TRANSFER , COMBUSTION), CONVECTION(HEAT TRANSFER), GAS FLOW, INJECTION, CHEMICAL REACTIONS, LAMINAR BOUNDARY LAYER, TURBULENT BOUNDARY LAYER, THERMAL INSULATION, USSR
Mass transfer in binary X-ray systems
Mccray, R.; Hatchett, S.
1975-01-01
The influence of X-ray heating on gas flows in binary X-ray systems is examined. A simple estimate is obtained for the evaporative wind flux from a stellar atmosphere due to X-ray heating which agrees with numerical calculations by Alme and Wilson (1974) but disagrees with calculations by Arons (1973) and by Basko and Sunyaev (1974) for the Her X-1/HZ Her system. The wind flux is sensitive to the soft X-ray spectrum. The self-excited wind mechanism does not work. Mass transfer in the Hercules system probably occurs by flow of the atmosphere of HZ Her through the gravitational saddle point of the system. The accretion gas stream is probably opaque with atomic density of not less than 10 to the 15th power per cu cm and is confined to a small fraction of 4(pi) steradians. Other binary X-ray systems are briefly discussed.
Mass transfer inside oblate spheroidal solids: modelling and simulation
Directory of Open Access Journals (Sweden)
J. E. F. Carmo
2008-03-01
Full Text Available A numerical solution of the unsteady diffusion equation describing mass transfer inside oblate spheroids, considering a constant diffusion coefficient and the convective boundary condition, is presented. The diffusion equation written in the oblate spheroidal coordinate system was used for a two-dimensional case. The finite-volume method was employed to discretize the basic equation. The linear equation set was solved iteratively using the Gauss-Seidel method. As applications, the effects of the Fourier number, the Biot number and the aspect ratio of the body on the drying rate and moisture content during the process are presented. To validate the methodology, results obtained in this work are compared with analytical results of the moisture content encountered in the literature and good agreement was obtained. The results show that the model is consistent and it may be used to solve cases such as those that include disks and spheres and/or those with variable properties with small modifications.
Combined heat and mass transfer for drying ceramic (shell body
Directory of Open Access Journals (Sweden)
Zawati Harun
2008-03-01
Full Text Available In the present work, a two-dimensional numerical model of heat and mass transfer for the convective drying of ceramic porous system was developed. The governing system of fully coupled non-linear partial differential equations describing the process was derived from a mechanistic approach. A formulation including hygrothermal and moisture transport in soil was adopted as the basis for further development in this work. The calculation results for drying of a ceramic brick showed that the model presented is in good agreement with other studies that have been reported previously in the drying of porous material. Further investigation on the shell drying agrees well with the most drying mechanism of ceramic porous body. The influence of material parameter on the drying profile is taken into consideration by carrying out some investigation on the material sensitivity study.
Modelling of convective heat and mass transfer in rotating flows
Shevchuk, Igor V
2016-01-01
This monograph presents results of the analytical and numerical modeling of convective heat and mass transfer in different rotating flows caused by (i) system rotation, (ii) swirl flows due to swirl generators, and (iii) surface curvature in turns and bends. Volume forces (i.e. centrifugal and Coriolis forces), which influence the flow pattern, emerge in all of these rotating flows. The main part of this work deals with rotating flows caused by system rotation, which includes several rotating-disk configurations and straight pipes rotating about a parallel axis. Swirl flows are studied in some of the configurations mentioned above. Curvilinear flows are investigated in different geometries of two-pass ribbed and smooth channels with 180° bends. The author demonstrates that the complex phenomena of fluid flow and convective heat transfer in rotating flows can be successfully simulated using not only the universal CFD methodology, but in certain cases by means of the integral methods, self-similar and analyt...
Devices with extended area structures for mass transfer processing of fluids
TeGrotenhuis, Ward E.; Wegeng, Robert S.; Whyatt, Greg A.; King, David L.; Brooks, Kriston P.; Stenkamp, Victoria S.
2009-04-21
A microchannel device includes several mass transfer microchannels to receive a fluid media for processing at least one heat transfer microchannel in fluid communication with a heat transfer fluid defined by a thermally conductive wall, and at several thermally conductive fins each connected to the wall and extending therefrom to separate the mass transfer microchannels from one another. In one form, the device may optionally include another heat transfer microchannel and corresponding wall that is positioned opposite the first wall and has the fins and the mass transfer microchannels extending therebetween.
Impact of Porous Media and NAPL Spatial Variability at the Pore Scale on Interphase Mass Transfer
Copty, N. K.; Agaoglu, B.; Scheytt, T.
2015-12-01
Sherwood number expressions are often used to model NAPL dissolution in porous media. Such expressions are generally derived from meso-scale experiments and expressed in terms of fluid and porous medium properties averaged over some representative volume. In this work a pore network model is used to examine the influence of porous media and NAPL pore scale variability on interphase mass transfer. The focus was on assessing the impact of (i) NAPL saturation, (ii) interfacial area (iii) NAPL spatial distribution at the pore scale, (iv) grain size heterogeneity and (v) REV or domain size on the apparent interphase mass transfer. Variability of both the mass transfer coefficient that explicitly accounts for the interfacial area and the mass transfer coefficient that lumps the interfacial area was examined. It was shown that pore scale NAPL distribution and its orientation relative to the flow direction have significant impact on flow bypassing and the interphase mass transfer coefficient. This results in a complex non-linear relationship between interfacial area and the REV-based interphase mass transfer rate. In other words, explicitly accounting for the interfacial area does not eliminate the variability of the mass transfer coefficient. Moreover, grain size heterogeneity can also lead to a decrease in the interphase mass transfer. It was also shown that, even for explicitly defined flow patterns, changing the domain size over which the mass transfer process is average influences the extent of NAPL bypassing and dilution and, consequently, the interphase mass transfer.
Two-phase flow with mass transfer in bubble columns
Energy Technology Data Exchange (ETDEWEB)
Mewes, D.; Wiemann, D. [Institute of Process Engineering, University of Hannover, D-30167 Hannover (Germany)
2003-08-06
Bubble columns are widely used in the chemical and biochemical industries. In these reactors a gaseous phase is dispersed into a continuous liquid phase thus the rising bubble swarm induces a circulating flow field. For the dimension of these reactors the local interfacial area and the residence time of the liquid and the gaseous phase are key parameters. In this paper an Euler-Euler approach is used to calculate the flow field in bubble columns numerically. Therefore a transport equation for the mean bubble volume based on a population balance equation approach is coupled with the balance equations for mass and momentum. The calculations are performed for three-dimensional, instationary flow fields in cylindrical bubble columns considering the homogeneous and the heterogeneous flow regime. For the interphase mass transfer the physical absorption of the gaseous phase into the liquid is assumed. The back mixing in the gaseous and liquid phase is calculated from the local and time dependent concentration of a tracer. (Abstract Copyright [2003], Wiley Periodicals, Inc.)
Energy Technology Data Exchange (ETDEWEB)
Siddiqui, O.; Fung, A.; Tse, H.; Zhang, D. [Ryerson Polytechnic Univ., Toronto, ON (Canada). Dept. of Mechanical and Industrial Engineering
2008-07-01
Since buildings in Canada account for 30 per cent of the country's total energy consumption, it has become necessary to find ways to reduce the overall energy use in buildings. Heating and cooling loads in buildings can be effectively reduced by using the thermal mass incorporated into the building envelope, particularly in climates where a large daily temperature fluctuations exist. Thermal mass is defined as any building material that has a high heat storage capacity that can be integrated into the structural fabric of the building to use the passive solar energy for heating or cooling purposes. Concrete slabs, bricks and ceramic blocks are some of the commonly used materials. This study analyzed the impact of using thermal mass with a highly insulated building envelope such as that used in Low Energy or Net Zero housing. In particular, TRNSYS was used to simulate a Net Zero Energy Town House located in Toronto, in which a ground source heat pump was integrated with an infloor radiant heating system. The simulation revealed that for colder climates such as in Canada, thermal mass can replace some of the insulation while still providing excellent results in terms of the reductions in daily indoor temperature fluctuations. The impact of thermal mass during the winter was more significant when compared with summer, possibly because of the unique construction and orientation of the Net Zero Energy House. The optimum thickness of the concrete slab was determined to be 6 inches for the winter season and 4 inches for summer. The optimum location for the thermal mass was found to be right next to the gypsum wallboard that forms the interior part of the wall. 12 refs., 1 tab., 11 figs.
Directory of Open Access Journals (Sweden)
A. Ankomah
2014-01-01
Full Text Available Background. Malaria during pregnancy is a major public health problem in Nigeria especially in malaria-endemic areas. It increases the risk of low birth weight and child/maternal morbidity/mortality. This paper addresses the impact of radio campaigns on the use of insecticide-treated bed nets among pregnant women in Nigeria. Methods. A total of 2,348 pregnant women were interviewed during the survey across 21 of Nigeria’s 36 states. Respondents were selected through a multistage sampling technique. Analysis was based on multivariate logistic regression. Results. Respondents who knew that sleeping under ITN prevents malaria were 3.2 times more likely to sleep under net (OR: 3.15; 95% CI: 2.28 to 4.33; P<0.0001. Those who listened to radio are also about 1.6 times more likely to use ITN (OR: 1.56; 95% CI: 1.07 to 2.28; P=0.020, while respondents who had heard of a specific sponsored radio campaign on ITN are 1.53 times more likely to use a bed net (P=0.019. Conclusion. Pregnant women who listened to mass media campaigns were more likely to adopt strategies to protect themselves from malaria. Therefore, behavior change communication messages that are aimed at promoting net use and antenatal attendance are necessary in combating malaria.
Incremental Identification of Reaction and Mass-Transfer Kinetics Using the Concept of Extents
Bhatt, Nirav; Amrhein, Michael; Bonvin, Dominique
2011-01-01
This paper proposes a variation of the incremental approach to identify reaction and mass-transfer kinetics (rate expressions and the corresponding rate parameters) from concentration measurements for both homogeneous and gas-liquid reaction systems. This incremental approach proceeds in two steps: (i) computation of the extents of reaction and mass transfer from concentration measurements without explicit knowledge of the reaction and mass-transfer rate expressions, and (ii) estimation of ...
THE EFFECT OF THE STARTING LENGTH ON MASS TRANSFER FROM A CONE IN SUPERSONIC FLOW.
The purpose of this investigation was to see what effect, if any, the starting length had on mass transfer from a cone. A blowdown supersonic wind...tunnel was utilized to bring about a flow regime of approximately Mach 3.15. The experimental results of mass transfer from cones in supersonic flow...are presented and a comparison to theoretical values is made. The cones used in the mass transfer tests were made of copper coated with p
A review is presented of the heat (and or component mass transfer boundary layer concept. The review included the following: Basic Equations, Partial...Methods, Series Methods for Wedge Flows, and Spalding’s Methods; Extension of Nickel’s Estimation Method to Heat and Mass Transfer , Estimation Theorem...for Heat and Mass Transfer , Application of Nickel’s Estimation Theorem, Discussion on Bracketing Unknown Exact Solutions with Lower and Upper Bounds
Heat and mass transfer in a vertical flue ring furnace
Energy Technology Data Exchange (ETDEWEB)
Jacobsen, Mona
1997-12-31
The main emphasis of this thesis was the design of a mathematical simulation model for studying details in the baking of anodes in the Hydro Aluminium anode baking furnace. The change of thermal conductivity, density, porosity and permeability during heat treatment was investigated. The Transient Plane Source technique for measuring thermal conductivity of solids was used on green carbon materials during the baking process in the temperature range 20-600 {sup o}C. Next, change of mass, density, porosity and permeability of anode samples were measured after being baked to temperatures between 300 and 1200 {sup o}C. The experimental data were used for parameter estimation and verification of property models for use in the anode baking models. Two distinct mathematical models have been modified to study the anode baking. A transient one-dimensional model for studying temperature, pressure and gas evolution in porous anodes during baking was developed. This was extended to a two-dimensional model incorporating the flue gas flow. The mathematical model which included porous heat and mass transfer, pitch pyrolysis, combustion of volatiles, radiation and turbulent channel flow, was developed by source code modification of the Computational Fluid Dynamics code FLUENT. The two-dimensional geometry of a flue gas channel adjacent to a porous flue gas wall, packing coke and anode was used for studying the effect of different firing strategies, raw materials properties and packing coke thickness. The model proved useful for studying the effects of heating rate, geometry and anode properties. 152 refs., 73 figs, 11 tabs.
Micro-scale mass-transfer variations during electrodeposition
Energy Technology Data Exchange (ETDEWEB)
Sutija, D.P.
1991-08-01
Results of two studies on micro-scale mass-transfer enhancement are reported: (1) Profiled cross-sections of striated zinc surfaces deposited in laminar channel flow were analyzed with fast-fourier transforms (FFT) to determine preferred striation wavelengths. Striation frequency increases with current density until a minimum separation between striae of 150 {mu}m is reached. Beyond this point, independent of substrate used, striae meld together and form a relatively smooth, nodular deposit. Substrates equipped with artificial micron-sized protrusions result in significantly different macro-morphology in zinc deposits. Micro-patterned electrodes (MPE) with hemispherical protrusions 5 {mu}m in diameter yield thin zinc striae at current densities that ordinarily produce random nodular deposits. MPEs with artificial hemi-cylinders, 2.5 {mu}m in height and spaced 250 {mu}m apart, form striae with a period which matches the spacing of micron-sized ridges. (2) A novel, corrosion-resistant micromosaic electrode was fabricated on a silicon wafer. Measurements of mass-transport enhancement to a vertical micromosaic electrode caused by parallel bubble streams rising inside of the diffusion boundary-layer demonstrated the presence of two co-temporal enhancement mechanisms: surface-renewal increases the limiting current within five bubble diameters of the rising column, while bubble-induced laminar flows cause weaker enhancement over a much broader swath. The enhancement caused by bubble curtains is predicted accurately by linear superposition of single-column enhancements. Two columns of smaller H{sub 2} bubbles generated at the same volumetric rate as a single column of larger bubbles cause higher peak and far-field enhancements. 168 refs., 96 figs., 6 tabs.
DEFF Research Database (Denmark)
Nielsen, Anders Michael; Nielsen, Lars Peter; Feilberg, Anders
2009-01-01
A membrane inlet mass spectrometer (MIMS) was used in combination with a developed computer model to study and improve management of a biofilter (BF) treating malodorous ventilation air from a meat rendering facility. The MIMS was used to determine percentage removal efficiencies (REs) of selected...... sulfur gases and to provide toluene retention profiles for the model to determine the air velocity and overall mass-transfer coefficient of toluene. The mass-transfer coefficient of toluene was used as a reference for determining the mass transfer of sulfur gases. By presenting the model to scenarios...... of a filter bed with a consortium of effective sulfur oxidizers, the most likely mechanism for incomplete removal of sulfur compounds from the exhaust air was elucidated. This was found to be insufficient mass transfer and not inadequate bacterial activity as anticipated by the manager of the BF. Thus...
Clack, Herek L
2006-06-01
Electrostatic precipitation is the dominant method of particulate control used for coal combustion, and varying degrees of mercury capture and transformation have been reported across ESPs. Nevertheless, the fate of gas-phase mercury within an ESP remains poorly understood. The present analysis focuses on the gas-particle mass transfer that occurs within a charged aerosol in an ESP. As a necessary step in gas-phase mercury adsorption or transformation, gas-particle mass transfer-particularly in configurations other than fixed beds-has received far less attention than studies of adsorption kinetics. Our previous analysis showed that only a small fraction of gas-phase mercury entering an ESP is likelyto be adsorbed by collected particulate matter on the plate electrodes. The present simplified analysis provides insight into gas-particle mass transfer within an ESP under two limiting conditions: laminar and turbulent fluid flows. The analysis reveals that during the process of particulate collection, gas-particle mass transfer can be quite high, easily exceeding the mass transfer to ESP plate electrodes in most cases. Decreasing particle size, increasing particle mass loading, and increasing temperature all result in increased gas-particle mass transfer. The analysis predicts significantly greater gas-particle mass transfer in the laminar limitthan in the turbulent limit; however, the differences become negligible under conditions where other factors, such as total mass of suspended particulates, are the controlling mass transfer parameters. Results are compared to selected pilot- and full-scale sorbent injection data.
Mass transfer kinetics during osmotic dehydration of pomegranate arils.
Mundada, Manoj; Hathan, Bahadur Singh; Maske, Swati
2011-01-01
The mass transfer kinetics during osmotic dehydration of pomegranate arils in osmotic solution of sucrose was studied to increase palatability and shelf life of arils. The freezing of the whole pomegranate at -18 °C was carried out prior to osmotic dehydration to increase the permeability of the outer cellular layer of the arils. The osmotic solution concentrations used were 40, 50, 60°Bx, osmotic solution temperatures were 35, 45, 55 °C. The fruit to solution ratio was kept 1:4 (w/w) during all the experiments and the process duration varied from 0 to 240 min. Azuara model and Peleg model were the best fitted as compared to other models for water loss and solute gain of pomegranate arils, respectively. Generalized Exponential Model had an excellent fit for water loss ratio and solute gain ratio of pomegranate arils. Effective moisture diffusivity of water as well as solute was estimated using the analytical solution of Fick's law of diffusion. For above conditions of osmotic dehydration, average effective diffusivity of water loss and solute gain varied from 2.718 × 10(-10) to 5.124 × 10(-10) m(2)/s and 1.471 × 10(-10) to 5.147 × 10(-10) m(2)/s, respectively. The final product was successfully utilized in some nutritional formulations such as ice cream and bakery products.
Heat and mass transfer in unsaturated porous media. Final report
Energy Technology Data Exchange (ETDEWEB)
Childs, S.W.; Malstaff, G.
1982-02-01
A preliminary study of heat and water transport in unsaturated porous media is reported. The project provides background information regarding the feasibility of seasonal thermal energy storage in unconfined aquifers. A parametric analysis of the factors of importance, and an annotated bibliography of research findings pertinent to unconfined aquifer thermal energy storage (ATES) are presented. This analysis shows that heat and mass transfer of water vapor assume dominant importance in unsaturated porous media at elevated temperature. Although water vapor fluxes are seldom as large as saturated medium liquid water fluxes, they are important under unsaturated conditions. The major heat transport mechanism for unsaturated porous media at temperatures from 50 to 90/sup 0/C is latent heat flux. The mechanism is nonexistent under saturated conditions but may well control design of unconfined aquifer storage systems. The parametric analysis treats detailed physical phenomena which occur in the flow systems study and demonstrates the temperature and moisture dependence of the transport coefficients of importance. The question of design of an unconfined ATES site is also addressed by considering the effects of aquifer temperature, depth to water table, porous medium flow properties, and surface boundary conditions. Recommendations are made for continuation of this project in its second phase. Both scientific and engineering goals are considered and alternatives are presented.
Biological conversion of synthesis gas. Mass transfer/kinetic studies
Energy Technology Data Exchange (ETDEWEB)
Klasson, K.T.; Basu, R.; Johnson, E.R.; Clausen, E.C.; Gaddy, J.L.
1992-03-01
Mass transfer and kinetic studies were carried out for the Rhodospirillum rubrum and Chlorobium thiosulfatophilum bacterial systems. R. rubrum is a photosynthetic anaerobic bacterium which catalyzes the biological water gas shift reaction: CO + H{sub 2}0 {yields} CO{sub 2} + H{sub 2}. C. thiosulfatophilum is also a H{sub 2}S and COS to elemental sulfur. The growth of R. rubrum may be satisfactorily carried out at 25{degree} and 30{degree}C, while CO uptake and thus the conversion of CO best occurs at temperatures of either 30{degree}, 32{degree} or 34{degree}C. The rate of conversion of COs and H{sub 2}O to CO{sub 2} and H{sub 2}S may be modeled by a first order rate expression. The rate constant at 30{degree}C was found to be 0.243 h{sup {minus}1}. The growth of C. thiosulfatophilum may be modeled in terms of incoming light intensity using a Monod equation: {mu} = {sub 351} + I{sub o}/{sup 0.152}I{sub o}. Comparisons of the growth of R. rubrum and C. thiosulfatophilum shows that the specific growth rate of C. thiosulfatophilum is much higher at a given light intensity.
Particle size distribution effects on gas-particle mass transfer within electrostatic precipitators.
Clack, Herek L
2006-06-15
Varying degrees of mercury capture and transformation have been reported across electrostatic precipitators (ESPs). Previous analyses have shown that the dominant mass transfer mechanism responsible for mercury capture within ESPs is gas-particle mass transfer during particulate collection. Whereas previous analyses assumed dispersions of uniform size, the present analysis reveals the effects of polydispersity on both gas-particle mass transfer and particle collection within an ESP. The analysis reveals that the idealized monodisperse particle size distribution provides the highest gas-particle mass transfer but results in the lowest particle collection efficiency (% mass). As the particle size distribution broadens, gas-particle mass transfer decreases and particle collection efficiency increases. The results suggest that more than just reporting mean particle diameter provided by the sorbent manufacturer, pilot- and field-tests of sorbent injection for mercury emissions control need to experimentally measure the particle size distribution of the sorbent as it is injected in order to facilitate interpretation of their results.
Directory of Open Access Journals (Sweden)
Abel Eigege
Full Text Available In central Nigeria Anopheles mosquitoes transmit malaria and lymphatic filariasis (LF. The strategy used for interrupting LF transmission in this area is annual mass drug administration (MDA with albendazole and ivermectin, but after 8 years of MDA, entomological evaluations in sentinel villages showed continued low-grade mosquito infection rates of 0.32%. After long-lasting insecticidal net (LLIN distribution by the national malaria program in late 2010, however, we were no longer able to detect infected vectors over a 24-month period. This is evidence that LLINs are synergistic with MDA in interrupting LF transmission.
Pinto, Diego D D; Emonds, Rob; Versteeg, Geert F.
2016-01-01
The absorption process is strongly influenced by the effective contact area. In absorber columns, this is related to the type of the internals used in the columns. Therefore, a good representation of the effective mass-transfer area and mass-transfer coefficients (kL or kg) is also essential for
J. A. Mardini; A. S. Lavine; V. K.. Dhir
1996-01-01
Abstract--An experimental and analytical study of heat and mass transfer in wooden dowels during a simulated fire is presented in this paper. The goal of this study is to understand the processes of heat and mass transfer in wood during wildland fires. A mathematical model is developed to describe the processes of heating, drying and pyrolysis of wood until ignition...
Absorption and desorption mass transfer rates in non-reactive systems
Hamborg, Espen S.; Kersten, Sascha R. A.; Versteeg, Geert F.
2010-01-01
Liquid phase mass transfer coefficients have been measured in a controlled environment during gas absorption into a liquid and gas desorption from a liquid in a batch operated stirred tank reactor over a wide range of operating conditions. At identical operating conditions, the mass transfer
Heat-And-Mass Transfer Relationship to Determine Shear Stress in Tubular Membrane Systems
DEFF Research Database (Denmark)
Ratkovich, Nicolas Rios; Nopens, Ingmar
2012-01-01
to remove particulates due to the high shear rates and high mass transfer between the membrane surface and the bulk region. However, to calculate the mass transfer coefficient in an efficient and accurate way is not straightforward. Indeed, for accurate determination, numerous complex experimental...
Estimating kinetic mass transfer by resting-period measurements in flow-interruption tracer tests.
Gong, R; Lu, C; Wu, W-M; Cheng, H; Gu, B; Watson, D B; Criddle, C S; Kitanidis, P K; Brooks, S C; Jardine, P M; Luo, J
2010-09-20
Flow-interruption tracer test is an effective approach to identify kinetic mass transfer processes for solute transport in subsurface media. By switching well pumping and resting, one may alter the dominant transport mechanism and generate special concentration patterns for identifying kinetic mass transfer processes. In the present research, we conducted three-phase (i.e., pumping, resting, and pumping) field-scale flow-interruption tracer tests using a conservative tracer bromide in a multiple-well system installed at the US Department of Energy Site, Oak Ridge, TN. A novel modeling approach based on the resting-period measurements was developed to estimate the mass transfer parameters. This approach completely relied on the measured breakthrough curves without requiring detailed aquifer characterization and solving transport equations in nonuniform, transient flow fields. Additional measurements, including hydraulic heads and tracer concentrations in large pumping wells, were taken to justify the assumption that mass transfer processes dominated concentration change during resting periods. The developed approach can be conveniently applied to any linear mass transfer model. Both first-order and multirate mass transfer models were applied to analyze the breakthrough curves at various monitoring wells. The multirate mass transfer model was capable of jointly fitting breakthrough curve behavior, showing the effectiveness and flexibility for incorporating aquifer heterogeneity and scale effects in upscaling effective mass transfer models. Copyright (c) 2010 Elsevier B.V. All rights reserved.
Analysis of combined heat and mass transfer of water-vapor in a ...
African Journals Online (AJOL)
Jn this paper, the combined heat and mass transfer of water-vapor into a cylindrical zeolite adsorber has been numerically simulated The twodimensional heat and mass transfer equations are numerically solved using gPROMS program - a general Process Modeling System [J] program, inserting the proper initial and ...
Analysis of combined heat and mass transfer of water- Vapor in a ...
African Journals Online (AJOL)
In this paper, the combined heat and mass transfer of water-vapor into a cylindrical zeolite adsorber has been numerically simulated The twodimensional heat and mass transfer equations are numerically solved using gPROMS program - a general Process Modeling System {lJ program, inserting the proper initial and ...
CO2 Mass transfer model for carbonic anhydrase-enhanced aqueous MDEA solutions
DEFF Research Database (Denmark)
Gladis, Arne Berthold; Deslauriers, Maria Gundersen; Neerup, Randi
2018-01-01
In this study a CO2 mass transfer model was developed for carbonic anhydrase-enhanced MDEA solutions based on a mechanistic kinetic enzyme model. Four different enzyme models were compared in their ability to predict the liquid side mass transfer coefficient at temperatures in the range of 298...
Racz, I.G.; Groot Wassink, J.; Klaassen, R.
1986-01-01
Concentration polarisation, decreasing the efficiency in membrane separation processes, can be reduced by increasing mass transfer between membrane surface and bulk of the feed stream. Analogous to techniques used in plate heat exchangers efforts have been made to enhance mass transfer in a plate
Fuhrmann, Eckart; Dreyer, Michael E.
2014-06-01
In this paper, we analyzed the heat and mass transfer at a free surface under microgravity conditions. The SOURCE-II (Sounding Rocket COMPERE Experiment) experiment was performed on a suborbital flight in February 2012 from Esrange in North Sweden. It provided representative data with respect to solid, liquid, and vapor temperatures as well as the visible surface position. The objectives were to quantify the deformation of the free liquid surface and to correlate the apparent contact angle to a characteristic temperature difference between subcooled liquid and superheated wall. Furthermore, the influence of evaporation and condensation at the liquid/vapor interface and at the superheated wall must be taken into account to analyze heat and mass fluxes due to a characteristic temperature difference. In the following, we show evidently that the magnitude of the apparent contact angle depends on the exerted specific pressurizations of the vapor phase during the experiment and hence on the change in the saturation temperature at the free surface. The characteristic temperature difference is defined with respect to the wall temperature in the vicinity of the contact line and the saturation temperature. Therefore, apparent contact angle and temperature difference can be correlated and indicate a specific characteristic. Concerning the heat and mass transfer at the free liquid surface and the contact line, two different methods are presented to evaluate the net mass due to phase change within a certain time interval. In the first approach, the mass flow rate is calculated by means of the ideal gas law and its derivatives with respect to temperature and pressure. The second approach calculates the heat flux as well as the mass flux at the wall and in the region of the free liquid surface. In these cases, a specific heat transfer coefficient and a thermal boundary layer thickness are used.
Mass transfer and adsorption equilibrium for low volatility alkanes in BPL activated carbon.
Wang, Yu; Mahle, John J; Furtado, Amanda M B; Glover, T Grant; Buchanan, James H; Peterson, Gregory W; LeVan, M Douglas
2013-03-05
The structure of a molecule and its concentration can strongly influence diffusional properties for transport in nanoporous materials. We study mass transfer of alkanes in BPL activated carbon using the concentration-swing frequency response method, which can easily discriminate among mass transfer mechanisms. We measure concentration-dependent diffusion rates for n-hexane, n-octane, n-decane, 2,7-dimethyloctane, and cyclodecane, which have different carbon numbers and geometries: straight chain, branched chain, and cyclic. Micropore diffusion is determined to be the controlling mass transfer resistance except at low relative saturation for n-decane, where an external mass transfer resistance also becomes important, showing that the controlling mass transfer mechanism can change with system concentration. Micropore diffusion coefficients are found to be strongly concentration dependent. Adsorption isotherm slopes obtained from measured isotherms, the concentration-swing frequency response method, and a predictive method show reasonably good agreement.
A generic model-based methodology for quantification of mass transfer limitations in microreactors
DEFF Research Database (Denmark)
Van Daele, Timothy; Fernandes del Pozo, David; Van Hauwermeiren, Daan
2016-01-01
Microreactors are becoming more popular in the biocatalytic field to speed up reactions and thus achieve process intensification. However, even these small-scale reactors can suffer from mass transfer limitations. Traditionally, dimensionless numbers such as the second Damköhler number are used...... to determine whether the reaction is either kinetically or mass transfer limited. However, these dimensionless numbers only give a qualitative measure of the extent of the mass transfer limitation, and are only applicable to simple reactor configurations. In practice, this makes it difficult to rapidly...... quantify the importance of such mass transfer limitations and compare different reactor configurations. This paper presents a novel generic methodology to quantify mass transfer limitations. It was applied to two microreactor configurations: a microreactor with immobilised enzyme at the wall and a Y...
Evaluation of mixing and mass transfer in a stirred pilot scale bioreactor utilizing CFD
DEFF Research Database (Denmark)
Bach, Christian; Yang, Jifeng; Larsson, Hilde Kristina
2017-01-01
and mass transfer performance of a high power agitated pilot scale bioreactor has been characterized using a novel combination of computational fluid dynamics (CFD) and experimental investigations. The effect of turbulence inside the vessel was predicted using a standard RANS k-ε model. Mixing time......Knowledge and prediction of mixing and mass transfer in agitated bioreactors is fundamental for process development and scale up. In particular key process parameters such as mixing time and volumetric mass transfer coefficient are essential for bioprocess development. In this work the mixing...... transfer coefficients were determined from six Trichoderma reesei fermentations at different well-defined process conditions. Similarly the mass transfer was predicted by Higbie’s penetration model from two-phase CFD simulations using a correlation of bubble size and power input, and the overall mass...
A CFD model for determining mixing and mass transfer in a high power agitated bioreactor
DEFF Research Database (Denmark)
Bach, Christian; Albæk, Mads O.; Stocks, Stuart M.
simulations, and the overall mass transfer coefficient was found to be in accordance with experimental data. This work illustrates the possibility of predicting the hydrodynamic performance of an agitated bioreactor using validated CFD models. These models can be applied in the testing of new bioreactor...... good agreement with the experimental data. The mass transfer coefficient was determined during three fed batch Trichoderma reesei fermentations at different process conditions previously described in [2]. Similarly the mass transfer was predicted by Higbie’s penetration model [3] from two-phase CFD......Prediction of mixing and mass transfer in agitated systems is a vital tool for process development and scale up in industrial biotechnology. In particular key process parameters such as mixing time and kLa are essential for bioprocess development [1]. In this work the mixing and mass transfer...
Development and validation of mass transfer models for the design of agitated gas-liquid reactors
Laakkonen, Marko
2006-01-01
Mechanical agitation is used commonly in gas-liquid reactors to improve the homogeneity of dispersion and to enhance the transfer of reacting compounds between gas and liquid. The design and scaleup of gas-liquid reactors is problematic due to non-ideal mixing, heat and mass transfer limitations. In this work, phenomenological models were developed and validated against experiments to investigate local gas-liquid mass transfer in agitated tanks. The aim was to develop more generalized and rel...
Shamu, Shepherd; Rusakaniko, Simbarashe; Hongoro, Charles
2016-01-01
Health-care technologies (HCTs) play an important role in any country's health-care system. Zimbabwe's health-care system uses a lot of HCTs developed in other countries. However, a number of local factors have affected the absorption and use of these technologies. We therefore set out to test the hypothesis that the net benefit regression framework (NBRF) could be a helpful benefit testing model that enables assessment of intra-national variables in HCT transfer. We used an NBRF model to assess the benefits of transferring cost-effective technologies to different jurisdictions. We used the country's 57 administrative districts to proxy different jurisdictions. For the dependent variable, we combined the cost and effectiveness ratios with the districts' per capita health expenditure. The cost and effectiveness ratios were obtained from HIV/AIDS and malaria randomized controlled trials, which did either a prospective or retrospective cost-effectiveness analysis. The independent variables were district demographic and socioeconomic determinants of health. The study showed that intra-national variation resulted in different net benefits of the same health technology intervention if implemented in different districts in Zimbabwe. The study showed that population data, health data, infrastructure, demographic and health-seeking behavior had significant effects on the net margin benefit for the different districts. The net benefits also differed in terms of magnitude as a result of the local factors. Net benefit testing using local data is a very useful tool for assessing the transferability and further adoption of HCTs developed elsewhere. However, adopting interventions with a positive net benefit should also not be an end in itself. Information on positive or negative net benefit could also be used to ascertain either the level of future savings that a technology can realize or the level of investment needed for the particular technology to become beneficial.
Turbulent heat/mass transfer at oceanic interfaces
Energy Technology Data Exchange (ETDEWEB)
Enstad, Lars Inge
2005-07-01
The thesis studies heat/mass transfer and uses various simulation techniques. A numerical method has been developed. 4 papers which describes the work, are included. In the first paper we look at such flow configuration where the flow is driven by a constant pressure gradient and the interface is cooled from above. Papers 2 and 3. 2: The effect of stable density stratification on turbulent vortical structures near an atmosphere-ocean interface driven by low wind shear. 3: Low shear turbulence structures beneath a gas-liquid interface under neutral and stable stratified conditions. A well known feature of the upper layer of the ocean is the presence of counter-rotating streamwise vorticity, so called Langmuir circulation. Earlier numerical investigations show that similar vortex structures appear on small scale induced by shear instability only. Short wave solar radiation may create a stable situation which affects the turbulence near the interface. In these papers we investigate such a flow situation by employing a uniform and constant shear stress at the interface together with a similar heat flux into the interface. In both articles we also use a two-point correlation to give a statistical representation of the streamwise vorticity. The spatial extent and intensity are decreased by stable stratification. In addition, in article 3, we find that the Reynolds stress is damped by stable stratification. This leads to an increased mean velocity since decreased Reynolds stress is compensated by a larger mean velocity gradient. The cospectra of the Reynolds stress in the spanwise direction show that the production of Reynolds stress is decreased at lower wave numbers and thus shifted to higher wave numbers in the presence of stable stratification. The streak structure created by the streamwise vorticity is disorganized by stable stratification. Article 4: A numerical study of a density interface using the General Ocean Turbulence Model (GOTM) coupled with a Navier Stokes
Brusseau, Mark L.; Guo, Zhilin
2018-01-01
It is evident based on historical data that groundwater contaminant plumes persist at many sites, requiring costly long-term management. High-resolution site-characterization methods are needed to support accurate risk assessments and to select, design, and operate effective remediation operations. Most subsurface characterization methods are generally limited in their ability to provide unambiguous, real-time delineation of specific processes affecting mass-transfer, transformation, and mass removal, and accurate estimation of associated rates. An integrated contaminant elution and tracer test toolkit, comprising a set of local-scale groundwater extraction-and injection tests, was developed to ameliorate the primary limitations associated with standard characterization methods. The test employs extended groundwater extraction to stress the system and induce hydraulic and concentration gradients. Clean water can be injected, which removes the resident aqueous contaminant mass present in the higher-permeability zones and isolates the test zone from the surrounding plume. This ensures that the concentrations and fluxes measured within the isolated area are directly and predominantly influenced by the local mass-transfer and transformation processes controlling mass removal. A suite of standard and novel tracers can be used to delineate specific mass-transfer and attenuation processes that are active at a given site, and to quantify the associated mass-transfer and transformation rates. The conceptual basis for the test is first presented, followed by an illustrative application based on simulations produced with a 3-D mathematical model and a brief case study application.
Proton transfer reaction-mass spectrometry applications in medical research.
Herbig, Jens; Amann, Anton
2009-06-01
Gathering information about a subject's physiological and pathophysiological condition from the `smell' of breath is an idea that dates back to antiquity. This intriguing concept of non-invasive diagnosis has been revitalized by `exhaled breath analysis' in recent decades. A main driving force was the development of sensitive and versatile gas-chromatographic and mass-spectrometric instruments for trace gas analysis. Ironically, only non-smelling constituents of breath, such as O(2), CO(2), H(2), and NO have so far been included in routine clinical breath analysis. The `smell' of human breath, on the other hand, arises through a combination of volatile organic compounds (VOCs) of which several hundred have been identified to date. Most of these volatiles are systemic and are released in the gas-exchange between blood and air in the alveoli. The concentration of these compounds in the alveolar breath is related to the respective concentrations in blood. Measuring VOCs in exhaled breath allows for screening of disease markers, studying the uptake and effect of medication (pharmacokinetics), or monitoring physiological processes. There is a range of requirements for instruments for the analysis of a complex matrix, such as human breath. Mass-spectrometric techniques are particularly well suited for this task since they offer the possibility of detecting a large variety of interesting compounds. A further requirement is the ability to measure accurately in the concentration range of breath VOCs, i.e. between parts-per-trillion (pptv) and parts-per-million (ppmv) range. In the mid 1990's proton transfer reaction-mass spectrometry (PTR-MS) was developed as a powerful and promising tool for the analysis of VOCs in gaseous media. Soon thereafter these instruments became commercially available to a still growing user community and have now become standard equipment in many fields including environmental research, food and flavour science, as well as life sciences. Their
Mass transfer in a 1370 C (2500 F) lithium thermal convection loop
Scheuermann, C. M.
1974-01-01
Experimental results from a test to evaluate interstitial element mass transfer effects on T-111, ASTAR 811C, and ASTAR 1211C after 5000 hours in flowing lithium at 1370 C (2500 F) are presented. No gross corrosion effects were observed. However, hafnium and nitrogen transfer to cooler regions within the loop were noted. Oxygen was in general removed from test specimens, but there was no evidence to indicate that it was a major factor in the mass transfer process. Carbon and hydrogen transfer were not detected.
Numerical calculations of mass transfer flow in semi-detached binary systems. [of stars
Edwards, D. A.; Pringle, J. E.
1987-01-01
The details of the mass transfer flow near the inner Lagrangian point in a semidetached binary system are numerically calculated. A polytropic equation of state with n = 3/2 is used. The dependence of the mass transfer rate on the degree to which the star overfills its Roche lobe is calculated, and good agreement with previous analytic estimates is found. The variation of mass transfer rate which occurs if the binary system has a small eccentricity is calculated and is used to cast doubt on the model for superhumps in dwarf novae proposed by Papaloizou and Pringle (1979).
The mass transfer approach to multivariate discrete first order stochastic dominance
DEFF Research Database (Denmark)
Østerdal, Lars Peter Raahave
2010-01-01
of times. This paper provides a new and elementary proof of that result by showing that starting with an arbitrary system of mass transfers, whenever the resulting distribution is first order dominated one can gradually rearrange transfers, according to a certain decentralized procedure, and obtain...... a system of transfers all shifting mass to outcomes that are worse.......A fundamental result in the theory of stochastic dominance tells that first order dominance between two finite multivariate distributions is equivalent to the property that the one can be obtained from the other by shifting probability mass from one outcome to another that is worse a finite number...
Energy Technology Data Exchange (ETDEWEB)
Choi, M. S.; Yeo, D. J.; Byun, J. H.; Suh, J. J.; Yang, J. K. [Chonnam National University, Yeosu (Korea, Republic of)
2009-02-15
The authors developed the transfer mass coefficient method (TMCM) in order to compute effectively the dynamic response of a beam structure. In this paper, the algorithm for the dynamic response analysis of a three-dimensional beam structure is formulated. Through the computation results of numerical models, which are plane and space beam structures, obtained by the transfer mass coefficient method and the direct integration method, we verify that the transfer mass coefficient method can remarkably decrease the computation time of the direct integration method without the loss of accuracy in spite of using small computer storage
Study of coupled heat and mass transfer during absorption of ...
Indian Academy of Sciences (India)
Abstract. A two-dimensional numerical analysis of coupled heat and mass trans- fer processes in a cylindrical metal hydride reactor containing MmNi4·6Al0·4 is presented. To understand the hydrogen absorption mechanism the governing equa- tions for energy, momentum and mass conservation and reaction kinetic ...
Effect of operating temperature on styrene mass transfer characteristics in a biotrickling filter.
Parnian, Parham; Zamir, Seyed Morteza; Shojaosadati, Seyed Abbas
2017-05-01
To study the effect of operating temperature on styrene mass transfer from gas to liquid phase in biotrickling filters (BTFs), overall mass transfer coefficient (KL a) was calculated through fitting test data to a general mass balance model under abiotic conditions. Styrene was used as the volatile organic compound and the BTF was packed with a mixture of pall rings and pumice. Operating temperature was set at 30°C and 50°C for mesophilic and thermophilic conditions, respectively. KL a values increased from 54 to 70 h-1 at 30°C and from 60 to 90 h-1 at 50°C, respectively, depending on the countercurrent gas to liquid flow ratio that varied in the range of 7.5-32. Evaluation of styrene mass transfer capacity (MTC) showed that liquid-phase mass transfer resistance decreased as the flow ratio increased at constant temperature. MTC also decreased with an increase in operating temperature. Both gas-liquid partition coefficient and KL a increased with increasing temperature; however the effect on gas-liquid partition coefficient was more significant and served to increase mass transfer limitations. Thermophilic biofiltration on the one hand increases mass transfer limitations, but on the other hand may enhance the biodegradation rate in favor of enhancing BTFs' performance.
Study of coupled heat and mass transfer during absorption of ...
Indian Academy of Sciences (India)
Performance studies on MmNi4·6Al0·4 based hydrogen storage device are carried out by varying the hydrogen supply pressure, absorption (cooling ﬂuid) temperature, overall heat transfer coefﬁcient and hydride bed thickness. Effect of convection terms in the energy equation on hydrogen storage performance is found to ...
Langmuir approach in the study of interface mass transfer
Remorov, R. G.; Bardwell, M. W.
2005-07-01
A study of the mass transport of non-reactive species through an infinite planar interface of a gas-liquid phase is presented. On the basis of the Hertz-Knudsen equation and "cluster" approaches formulated by Davidovits et al. [Journal of Physical Chemistry 95 (1991) 6337], an analytical formulation of the mass-accommodation coefficient is considered. According to the work reported herein, for the case of an interfacial equilibrium, the mass-accommodation coefficient is inversely proportional to the "cluster" factor and directly proportional to the exponential factor of the difference between free energies in the bulk and interface regions. The "cluster" factor is determined as a function of the cluster sizes in the bulk and interface. Estimation of the mass-accommodation coefficient for a series of non-reactive compounds gives a good agreement with experimental data.
Heat and mass transfer intensification and shape optimization a multi-scale approach
2013-01-01
Is the heat and mass transfer intensification defined as a new paradigm of process engineering, or is it just a common and old idea, renamed and given the current taste? Where might intensification occur? How to achieve intensification? How the shape optimization of thermal and fluidic devices leads to intensified heat and mass transfers? To answer these questions, Heat & Mass Transfer Intensification and Shape Optimization: A Multi-scale Approach clarifies the definition of the intensification by highlighting the potential role of the multi-scale structures, the specific interfacial area, the distribution of driving force, the modes of energy supply and the temporal aspects of processes. A reflection on the methods of process intensification or heat and mass transfer enhancement in multi-scale structures is provided, including porous media, heat exchangers, fluid distributors, mixers and reactors. A multi-scale approach to achieve intensification and shape optimization is developed and clearly expla...
Spanwise mass transfer variations on a cylinder in 'nominally' uniform crossflow
Mayle, R. E.; Marziale, M.
1982-01-01
Mass transfer experiments on a circular cylinder in a 'nominally' uniform crossflow are described. Experiments were conducted at the tunnel's turbulence level and with a woven-wire turbulence screen. In both cases spanwise and circumferential mass transfer measurements were made. Without the turbulence screen, the results were found to be spanwise independent and agreed quite well with both theory and the result of others. In addition to the mass transfer measurements, spanwise traverse measurements of the mean velocity and turbulence quantities in the incident flow were made and showed that the screen produced a small-amplitude spanwise periodic perturbation in the incident flow. Although this perturbation was only one quarter of a percent in the mean velocity and buried in the stream's turbulence, disproportionately large spanwise variations of 15 percent were found in the mass transfer rate.
Energy Technology Data Exchange (ETDEWEB)
Tabares Velasco, P. C.
2011-04-01
This presentation discusses estimating heat and mass transfer processes in green roof systems: current modeling capabilities and limitations. Green roofs are 'specialized roofing systems that support vegetation growth on rooftops.'
Ventosa, Edgar; Paulitsch, Bianca; Marzak, Philipp; Yun, Jeongsik; Schiegg, Florian; Quast, Thomas; Bandarenka, Aliaksandr S
2016-12-01
Intercalation of alkali metal cations, like Li+ or Na+, follows the same three-stage mechanism of the interfacial charge and mass transfer irrespective of the nature of the electrolyte, electrolyte composition or electrode material.
Mass Transfer Studies on Adsorption of Phenol from Wastewater Using Lantana camara, Forest Waste
Directory of Open Access Journals (Sweden)
C. R. Girish
2016-01-01
Full Text Available Adsorption is one of the important treatment methods for the removal of pollutants from wastewater. The determination of rate controlling step in the process is important in the design of the process. Therefore, in the present work, mass transfer studies were done to evaluate the rate-limiting step in the adsorption of phenol from aqueous solution onto Lantana camara. Different mass transfer models were used to find the rate-limiting step and also to find the values of external mass transfer coefficient and diffusion coefficient. The Biot number was found to investigate the importance of external mass transfer to intraparticle diffusion. From the various models studied and the Biot numbers obtained, it was found that the adsorption on Lantana camara was controlled by film diffusion. The sensitivity analysis was performed to study the significance of the model parameters on the adsorption process.
A mass transfer origin for blue stragglers in NGC 188 as revealed by half-solar-mass companions.
Geller, Aaron M; Mathieu, Robert D
2011-10-19
In open star clusters, where all members formed at about the same time, blue straggler stars are typically observed to be brighter and bluer than hydrogen-burning main-sequence stars, and therefore should already have evolved into giant stars and stellar remnants. Correlations between blue straggler frequency and cluster binary star fraction, core mass and radial position suggest that mass transfer or mergers in binary stars dominates the production of blue stragglers in open clusters. Analytic models, detailed observations and sophisticated N-body simulations, however, argue in favour of stellar collisions. Here we report that the blue stragglers in long-period binaries in the old (7 × 10(9)-year) open cluster NGC 188 have companions with masses of about half a solar mass, with a surprisingly narrow mass distribution. This conclusively rules out a collisional origin, as the collision hypothesis predicts a companion mass distribution with significantly higher masses. Mergers in hierarchical triple stars are marginally permitted by the data, but the observations do not favour this hypothesis. The data are highly consistent with a mass transfer origin for the long-period blue straggler binaries in NGC 188, in which the companions would be white dwarfs of about half a solar mass.
Oxygen mass transfer studies on batch cultivation of P. aeruginosa in a biocalorimeter
Sivaprakasam,Senthilkumar; Mahadevan,Surianarayanan; Gopalaraman,Swaminathan
2008-01-01
In the present work volumetric mass transfer coefficient (kLa) was investigated during batch cultivations of Pseudomonas aeruginosa on a nutrient media. The effects of process variables (viz. impeller speed, oxygen flow and geometry of impeller) on the volumetric mass transfer coefficient of oxygen, kLa, in a biocalorimeter (Bio-RC1) was investigated and reported in this research work. The experimental data have been analyzed employing MATLAB to obtain the influences of the process parameters...
Modelling gas-liquid flow and local mass transfer in stirred tanks
Moilanen, Pasi
2009-01-01
This doctorial thesis offers a guideline for modelling gas-liquid flow in stirred tanks with computational fluid dynamics (CFD). Particularly the effect of varying physical properties and industrial operating conditions is highlighted. The most important thing in modelling mass transfer in stirred vessels is the accurate prediction of local bubble size. Population balances for bubbles are needed for accurate description of the local mass transfer rate. There are many pitfalls in gas-liquid mo...
Mixing and mass transfer in a pilot scale U-loop bioreactor
DEFF Research Database (Denmark)
Petersen, Leander Adrian Haaning; Villadsen, John; Jørgensen, Sten Bay
2017-01-01
A system capable of handling a large volumetric gas fraction while providing a high gas to liquid mass transfer is a necessity if the metanotrophic bacterium Methylococcus capsulatus is to be used in single cell protein (SCP) production. In this study mixing time and mass transfer coefficients we...... equipped with static mixers at modest volumetric liquid and gas flow rates. This article is protected by copyright. All rights reserved...
A CFD model for determining mixing and mass transfer in a high power agitated bioreactor
Bach, Christian; Albæk, Mads O.; Stocks, Stuart M.; Krühne, Ulrich; Gernaey, Krist V.
2016-01-01
Prediction of mixing and mass transfer in agitated systems is a vital tool for process development and scale up in industrial biotechnology. In particular key process parameters such as mixing time and kLa are essential for bioprocess development [1]. In this work the mixing and mass transfer performance of a high power agitated pilot scale bioreactor has been characterized using a novel combination of computational fluid dynamics (CFD) and experimental investigations. The effect of turbulenc...
Influence of rotating magnetic field on gas-liquid volumetric mass transfer coefficient
Directory of Open Access Journals (Sweden)
Rakoczy Rafał
2017-09-01
Full Text Available The main objective of these experiments was to study the oxygen mass transfer rate through the volumetric mass transfer coefficient (kLa for an experimental set-up equipped with a rotating magnetic field (RMF generator and various liquids. The experimental results indicated that kLa increased along the magnetic strength and the superficial gas velocity. Mathematical correlations defining the influence of the considered factors on kLa were proposed.
Ultrasound in gas–liquid systems: Effects on solubility and mass transfer
Laugier, Frédéric; Andriantsiferana, Caroline; Wilhelm, Anne-Marie; Delmas, Henri
2008-01-01
The effect of ultrasound on the pseudo-solubility of nitrogen in water and on gas–liquid mass transfer kinetics has been investigated in an autoclave reactor equipped with a gas induced impeller. In order to use organic liquids and to investigate the effect of pressure, gas–liquid mass transfer coefficient was calculated from the evolution of autoclave pressure during gas absorption to avoid any side-effects of ultrasound on the concentrations measurements. Ultrasound effect on the apparent s...
Numerical modelling of combined heat and mass transfer in film absorption
Directory of Open Access Journals (Sweden)
Bartashevich Maria V.
2017-01-01
Full Text Available Heat and mass transfer during absorption on a film of lithium bromide water solution flowing by a cooled wall in the steam atmosphere is numerically investigated in this paper. The self-similar solutions are using as the initial conditions for solving the problem beyond the entrance region. The key criteria characterizing heat and mass transfer in the film absorption with uniform velocity profile and with a constant thickness have been determined.
Li, Chunyan
2015-01-01
The evolution of biofilm structure on the carriers used in moving bed biofilm reactor was investigated by means of optical coherence tomography and biofilm image analysis. A method was developed by combining biofilm imaging and mathematical modeling to study the mass transfer characteristics in the vicinity of biofilm surface. The method was further used to examine the effect of the deposition of organic particle at biofilm surface on the mass transfer from bulk liquid into biofilms.
Determination of the gas-to-membrane mass transfer coefficient in a catalytic membrane reactor
Veldsink, J.W.; Versteeg, G.F.; Swaaij, W.P.M. van
1995-01-01
A novel method to determine the external mass transfer coefficient in catalytic membrane reactors (Sloot et al., 1992a, b) was presented in this study. In a catalytically active membrane reactor, in which a very fast reaction occurs, the external transfer coefficient can conveniently be measured by
Directory of Open Access Journals (Sweden)
Daniel Jandačka
2013-09-01
Full Text Available OBJECTIVE: To determine the reliability of the measurement of net joint power during repeated gait measurements within one day and between two different measurement days. METHODS: Thirty able-bodied men who underwent repeated gait measurements within a day and between days participated in this research. An acceptable trial was one in which the participant complied with the range of walking speed 1.45 m/s ± 5%. Three-dimensional angles, angular velocities, net moments of force and net power for the ankle, knee and hip joints were determined using external passive reflective markers, an 8-camera motion analysis system and two force plates. RESULTS: This study presents the patterns of the net power in the fundamental joints of the lower limbs in young healthy men at standard gait velocity. Intraclass correlation coefficients for net joint power measure reached values in the range of .70 to .89 on the first day, from .69 to .86 on the second day, and from .67 to .83 in total. CONCLUSION: The reliability of the measurement of the peak net joint power within one day and between the two measurement days was evaluated as satisfactory. The study provides the value of minimal detectable change for the peak net power of the lower limb in the sagittal plane during gait. The net joint power appears to be a reliable measure and could be used in practice.
Interfacial mass transfer to a cylinder endwall during spin-up/spin-down
Larrousse, Mark F.; Wilcox, William R.
1990-01-01
The local rate of mass transfer to the bottom endwall of a large aspect ratio cylinder was measured during spin-up/spin-down. The local mass transfer rate was a strong function radial position along the endwall. At the center during spin-up from rest, the maximum enhancement in mass transfer occurred after the Ekman time scale and before the viscous time scale. At the center during spin-down to rest, a stagnation vortex formed, causing the mass transfer rate to decay and then increase back to the original value of the order of the viscous time scale. Away from the center a much more complicated pattern was observed, but spin-up and spin-down were similar. Two peaks in mass transfer rate occurred for an Ekman number over 0.0074. Alternating spin-up and spin-down with a short period caused the center of the endwall to experience a nearly sinusoidal variation in mass transfer with the frequency equal to the forcing frequency. Near the edge the frequency was twice the forcing frequency.
Cvetkovic, Vladimir; Fiori, Aldo; Dagan, Gedeon
2016-04-01
The driving mechanism of contaminant transport in aquifers is groundwater flow, which is controlled by boundary conditions and heterogeneity of hydraulic properties. In this work we show how hydrodynamics and mass transfer can be combined in a general analytical manner to derive a physically-based (or process-based) residence time distribution for a given integral scale of the hydraulic conductivity; the result can be applied for a broad class of linear mass transfer processes. The derived tracer residence time distribution is a transfer function with parameters to be inferred from combined field and laboratory measurements. It is scalable relative to the correlation length and applicable for an arbitrary statistical distribution of the hydraulic conductivity. Based on the derived residence time distribution, the coefficient of variation and skewness of contaminant residence time are illustrated assuming a log-normal hydraulic conductivity distribution and first-order mass transfer. We show that for a low Damkohler number the coefficient of variation is more strongly influenced by mass transfer than by heterogeneity, whereas skewness is more strongly influenced by heterogeneity. The derived physically-based residence time distribution for solute transport in heterogeneous aquifers is particularly useful for studying natural attenuation of contaminants. We illustrate the relative impacts of high heterogeneity and a generalised (non-Fickian) multi-rate mass transfer on natural attenuation defined as contaminant mass loss from injection to a downstream compliance boundary.
Zhang, Yong; Li, Kuiling; Wang, Jun; Hou, Deyin; Liu, Huijuan
2017-09-01
To understand the mass transfer behaviors in hollow fiber membrane contactors, ozone fluxes affected by various conditions and membranes were investigated. For physical absorption, mass transfer rate increased with liquid velocity and the ozone concentration in the gas. Gas flow rate was little affected when the velocity was larger than the critical value, which was 6.1 × 10-3m/s in this study. For chemical absorption, the flux was determined by the reaction rate between ozone and the absorbent. Therefore, concentration, species, and pH affected the mass transfer process markedly. For different absorbents, the order of mass transfer rate was the same as the reaction rate constant, which was phenol, sodium nitrite, hydrogen peroxide, and oxalate. Five hydrophobic membranes with various properties were employed and the mass transfer behavior can be described by the Graetz-Lévèque equation for the physical absorption process. The results showed the process was controlled by liquid film and the gas phase conditions, and membrane properties did not affect the ozone flux. For the chemical absorption, gas film, membrane and liquid film affected the mass transfer together, and none of them were negligible.
Energy Technology Data Exchange (ETDEWEB)
He, Zhixia; Zhang, Liang; Saha, Kaushik; Som, Sibendu; Duan, Lian; Wang, Qian
2017-12-01
The super high fuel injection pressure and micro size of nozzle orifice has been an important development trend for the fuel injection system. Accordingly, cavitation transient process, fuel compressibility, amount of noncondensable gas in the fuel and cavitation erosion have attracted more attention. Based on the fact of cavitation in itself is a kind of thermodynamic phase change process, this paper takes the perspective of the cavitation phase change mass transfer process to analyze above mentioned phenomenon. The two-phase cavitating turbulent flow simulations with VOF approach coupled with HRM cavitation model and U-RANS of standard k-ε turbulence model were performed for investigations of cavitation phase change mass transfer process. It is concluded the mass transfer time scale coefficient in the Homogenous Relaxation Model (HRM) representing mass transfer rate should tend to be as small as possible in a condition that ensured the solver stable. At very fast mass transfer rate, the phase change occurs at very thin interface between liquid and vapor phase and condensation occurs more focused and then will contribute predictably to a more serious cavitation erosion. Both the initial non-condensable gas in fuel and the fuel compressibility can accelerate the cavitation mass transfer process.
Modeling the mass transfer of semi-volatile organics in combustion aerosols
Energy Technology Data Exchange (ETDEWEB)
Odum, J.R.; Kamens, R.M. [Univ. of North Carolina, Chapel Hill, NC (United States). Dept. of Environmental Sciences and Engineering
1994-12-31
The atmospheric transport and fate of airborne organic compounds are highly dependent upon which phase or phases (i.e., gas or particle or gas/particle) the compound exists. Recently Rounds and Pankow developed a radial pore-diffusion model to simulate the mass transfer of semi-volatile organics in and out of combustion aerosols. Preliminary results from their model and other recent discoveries suggest that many types of combustion aerosols may be coated with a liquid organic layer and that diffusion of semi-volatile organics through this layer impedes rapid mass transfer of these compounds. Therefore a radial diffusion model was developed to describe the mass transfer of semi-volatile organics into and out of combustion aerosols. The model combustion aerosol consists of a solid carbon core that is surrounded by a viscous, liquid-like, organic layer. Diffusion takes place only within the organic layer and is controlled by mass transfer at the particle surface. Modeling of semi-volatiles requires the tuning of two separate parameters: a diffusion coefficient and a surface mass transfer coefficient. Preliminary testing of the model on the uptake of deuterated pyrene by diesel exhaust aerosol at 25 C suggests that diffusion coefficients for PAH are on the order of 10{sup {minus}15} cm{sup 2}/sec and that surface mass transfer coefficients for pyrene are on the order of 10{sup {minus}9} cm/sec.
Turbulent heat and mass transfers across a thermally stratified air-water interface
Papadimitrakis, Y. A.; Hsu, Y.-H. L.; Wu, J.
1986-01-01
Rates of heat and mass transfer across an air-water interface were measured in a wind-wave research facility, under various wind and thermal stability conditions (unless otherwise noted, mass refers to water vapor). Heat fluxes were obtained from both the eddy correlation and the profile method, under unstable, neutral, and stable conditions. Mass fluxes were obtained only under unstable stratification from the profile and global method. Under unstable conditions the turbulent Prandtl and Schmidt numbers remain fairly constant and equal to 0.74, whereas the rate of mass transfer varies linearly with bulk Richardson number. Under stable conditions the turbulent Prandtl number rises steadily to a value of 1.4 for a bulk Richardson number of about 0.016. Results of heat and mass transfer, expressed in the form of bulk aerodynamic coefficients with friction velocity as a parameter, are also compared with field data.
Tube-side mass transfer for hollow fibre membrane contactors operated in the low Graetz range.
Wang, C Y; Mercer, E; Kamranvand, F; Williams, L; Kolios, A; Parker, A; Tyrrel, S; Cartmell, E; McAdam, E J
2017-02-01
Transformation of the tube-side mass transfer coefficient derived in hollow fibre membrane contactors (HFMC) of different characteristic length scales (equivalent diameter and fibre length) has been studied when operated in the low Graetz range (Gzmass transfer is generally described by the Graetz problem (Sh=3.67) which assumes that the concentration profile comprises a constant shape over the fibre radius. In this study, it is experimentally evidenced that this assumption over predicts mass transfer within the low Graetz range. Furthermore, within the low Gz range (below 2), a proportional relationship between the experimentally determined mass transfer coefficient (Kov ) and the Graetz number has been identified. For Gz numbers below 2, the experimental Sh number approached unity, which suggests that mass transfer is strongly dependent upon diffusion. However, within this diffusion controlled region of mass transfer, tube-side fluid velocity remained important. For Gz numbers above 2, Sh could be satisfactorily described by extension to the Lévêque solution, which can be ascribed to the constrained growth of the concentration boundary layer adjacent to the fibre wall. Importantly this study demonstrates that whilst mass transfer in the low Graetz range does not explicitly conform to either the Graetz problem or classical Lévêque solution, it is possible to transform the experimentally derived overall mass transfer coefficient (Kov ) between characteristic length scales (dh and L). T h is was corroborated by comparison of the empirical relationship determined in this study (Sh=0.36Gz) with previously published studies operated in the low Gz range. This analysis provides important insight for process design when slow tube-side flows, or low Schmidt numbers (coincident with gases) constrain operation of hollow fibre membrane contactors to the low Gz range.
Thermal diffusion effects on free convection and mass transfer flow for an infinite vertical plate
Abdel-Khalek, M M
2003-01-01
A theoretical study is performed to examine the effects of thermal diffusion on free convection and mass transfer flow for an infinite vertical plate. The governing equations for the fluid flow and the heat transfer are solved subject to the relevant boundary conditions. A perturbation technique is used to obtain expressions for the velocity field and skin friction. An analysis of the effects of the parameters on the concentration, velocity and temperature profiles as well as skin friction and the rate of mass and heat transfer is done with the aid of graphs.
Final Report: Geoelectrical Measurement of Multi-Scale Mass Transfer Parameters
Energy Technology Data Exchange (ETDEWEB)
Haggerty, Roy [Oregon State Univ., Corvallis, OR (United States); Day-Lewis, Fred [U.S. Geological Survey, Storrs, CT (United States); Singha, Kamini [Colorado School of Mines, Golden, CO (United States); Johnson, Timothy [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Binley, Andrew [Lancaster Univ. (United Kingdom); Lane, John [U.S. Geological Survey, Storrs, CT (United States)
2014-03-20
Mass transfer affects contaminant transport and is thought to control the efficiency of aquifer remediation at a number of sites within the Department of Energy (DOE) complex. An improved understanding of mass transfer is critical to meeting the enormous scientific and engineering challenges currently facing DOE. Informed design of site remedies and long-term stewardship of radionuclide-contaminated sites will require new cost-effective laboratory and field techniques to measure the parameters controlling mass transfer spatially and across a range of scales. In this project, we sought to capitalize on the geophysical signatures of mass transfer. Previous numerical modeling and pilot-scale field experiments suggested that mass transfer produces a geoelectrical signature—a hysteretic relation between sampled (mobile-domain) fluid conductivity and bulk (mobile + immobile) conductivity—over a range of scales relevant to aquifer remediation. In this work, we investigated the geoelectrical signature of mass transfer during tracer transport in a series of controlled experiments to determine the operation of controlling parameters, and also investigated the use of complex-resistivity (CR) as a means of quantifying mass transfer parameters in situ without tracer experiments. In an add-on component to our grant, we additionally considered nuclear magnetic resonance (NMR) to help parse mobile from immobile porosities. Including the NMR component, our revised study objectives were to: 1. Develop and demonstrate geophysical approaches to measure mass-transfer parameters spatially and over a range of scales, including the combination of electrical resistivity monitoring, tracer tests, complex resistivity, nuclear magnetic resonance, and materials characterization; and 2. Provide mass-transfer estimates for improved understanding of contaminant fate and transport at DOE sites, such as uranium transport at the Hanford 300 Area. To achieve our objectives, we implemented a 3
Intensification of mass transfer in wet textile processes by power ultrasound
Moholkar, V.S.; Nierstrasz, Vincent; Warmoeskerken, Marinus
2003-01-01
In industrial textile pre-treatment and finishing processes, mass transfer and mass transport are often rate-limiting. As a result, these processes require a relatively long residence time, large amounts of water and chemicals, and are also energy-consuming. In most of these processes, diffusion and
An Experiment to Introduce Mass Transfer Concepts Using a Commercial Hollow Fiber Blood Oxygenator
McIver, Keith; Merrill, Thomas; Farrell, Stephanie
2017-01-01
A commercial hollow fiber blood oxygenation laboratory experiment was used to introduce lower level engineering students to mass balances in a two-phase system. Using measured values of concentration and flow rate, students calculated the rate of mass transfer from the gas phase and into the liquid phase, and compared the two values to determine…
Mass Transfer Limited Enhanced Bioremediation at Dnapl Source Zones: a Numerical Study
Kokkinaki, A.; Sleep, B. E.
2011-12-01
The success of enhanced bioremediation of dense non-aqueous phase liquids (DNAPLs) relies on accelerating contaminant mass transfer from the organic to the aqueous phase, thus enhancing the depletion of DNAPL source zones compared to natural dissolution. This is achieved by promoting biological activity that reduces the contaminant's aqueous phase concentration. Although laboratory studies have demonstrated that high reaction rates are attainable by specialized microbial cultures in DNAPL source zones, field applications of the technology report lower reaction rates and prolonged remediation times. One possible explanation for this phenomenon is that the reaction rates are limited by the rate at which the contaminant partitions from the DNAPL to the aqueous phase. In such cases, slow mass transfer to the aqueous phase reduces the bioavailability of the contaminant and consequently decreases the potential source zone depletion enhancement. In this work, the effect of rate limited mass transfer on bio-enhanced dissolution of DNAPL chlorinated ethenes is investigated through a numerical study. A multi-phase, multi-component groundwater transport model is employed to simulate DNAPL mass depletion for a range of source zone scenarios. Rate limited mass transfer is modeled by a linear driving force model, employing a thermodynamic approach for the calculation of the DNAPL - water interfacial area. Metabolic reductive dechlorination is modeled by Monod kinetics, considering microbial growth and self-inhibition. The model was utilized to identify conditions in which mass transfer, rather than reaction, is the limiting process, as indicated by the bioavailability number. In such cases, reaction is slower than expected, and further increase in the reaction rate does not enhance mass depletion. Mass transfer rate limitations were shown to affect both dechlorination and microbial growth kinetics. The complex dynamics between mass transfer, DNAPL transport and distribution, and
Stability of coaxial jets confined in a tube with heat and mass transfer
Mohanta, Lokanath; Cheung, Fan-Bill; Bajorek, Stephen M.
2016-02-01
A linear temporal stability of coaxial confined jets in a vertical tube involving heat and mass transfer at the interface is presented in this paper. A potential flow analysis that includes the effect of viscosity at the interface is performed in analyzing the stability of the system. Film boiling in a vertical tube gives rise to the flow configuration explored in this work. The effects of various non-dimensional parameters on the growth rate and the neutral curve are discussed. The heat transfer at the interface has been characterized by introducing a heat flux ratio between the conduction heat flux and the evaporation heat flux. Viscous forces and the heat and mass transfer at the interface are found to stabilize the flow both in the capillary instability region and Kelvin-Helmholtz instability region. Increasing heat and mass transfer at the interface stabilizes the flow to small as well as very large wave numbers.
Optimal design of a bar with an attached mass for maximizing the heat transfer
Directory of Open Access Journals (Sweden)
Boris P. Belinskiy
2012-10-01
Full Text Available We maximize, with respect to the cross sectional area, the rate of heat transfer through a bar of given mass. The bar serves as an extended surface to enhance the heat transfer surface of a larger heated known mass to which the bar is attached. In this paper we neglect heat transfer from the sides of the bar and consider only conduction through its length. The rate of cooling is defined by the first eigenvalue of the corresponding Sturm-Liouville problem. We establish existence of an optimal design via rearrangement techniques. The necessary conditions of optimality admit a unique optimal design. We compare the rate of heat transfer for that bar with the rate for the bar of the same mass but of a constant cross-section area.
DEFF Research Database (Denmark)
Nie, Jinzhe; Fang, Lei
2014-01-01
recovery unit with polymer membrane foils was used as refeering unit in this study. The experiments were conducted with different outdoor thermal climates e.g. warm-humid and cold-dry climates; isothermal and non isothermal as well as equal humidity and non equal humidity with indoor climate. Three......Laboratory experimental studies were conducted to investigate the mass transfer of contaminants through a total heat recovery unit with polymer membranes foils. The studies were conducted in twin climate chambers which simulated outdoor and indoor thermal climates. One manufacturd total heat...... could transfer from exhaust air to supply air through the enthalpy recovery unit. The mass transfer efficiency of contaminants was independent of the hygro-thermal differences between indoor and outdoor climate conditions. The mass transfer ratio of the chemical contaminants in the total heat recovery...
Gas-liquid mass transfer in filamentous slurries in airlift bioreactors
Energy Technology Data Exchange (ETDEWEB)
Chisti, M.Y.; Moo-Young, M. (Waterloo Univ., ON (Canada))
1988-01-01
Biotechnology production processes are often critically dependent on oxygen transfer in gas-liquid-solid multiphase systems. Some of these biofluid slurries are composed of fibrous or filamentous, mycelial, solids suspended in a water-like medium. Examples are the broths of Aspergilli, Penicillia, Neurospora and Streptomyces, all of which are of commercial importance. This paper reports of the gas-liquid mass transfer behaviour of aqueous slurries of cellulose fibre solids (1-3 wt./vol. % solids in 0.15 kmol m/sup -3/ NaCl) which simulate the filamentous fermentation broths of interest. Fundamental investigations into the relationship between the mass transfer coefficient (k/sub L/) and bubble diameter (d/sub B/) are undertaken. The observations can be usefully employed for scale-up of bioreactors for gas-liquid mass transfer as demonstrated in the paper.
Heat and mass transfer of submerged helium injection in liquid oxygen vessel
Jung, Youngsuk; Cho, Namkyung; Baek, Seungwhan; Jeong, Sangkwon
2014-11-01
The submerged helium injection process results in the heat and mass transfer between the helium bubble and the cryogenic liquid. The objective of this paper is to analyze the dynamics of the heat and mass transfer process. It is observed that during the helium injection process the dynamics of mass transfer is dominant and the transient heat transfer is negligible. The helium bubble shape and rising patterns are observed with a visualization device that helps to discern the dominant process between heat transfer and mass transfer. The clustering patterns such as coalescence of helium bubbles are observed with the visualization device. The visualization results indicate that, it is very difficult to determine the representative size of bubbles due to the irregular shape of the helium bubbles. The shape and size of the helium bubbles are important parameters for evaluating the overall mass transfer coefficient (kGA) which is the essential parameter for calculating the evaporation rate of the bulk liquid into the helium bubbles. In this paper, the simplified lumped model is considered to fairly approximate the evaporation rate of the cryogenic liquid into the bubbles and the cooling rate of helium injection. The empirical correlation for the average concentration (C‾A) of evaporated cryogenic liquid into the helium bubbles is presented and the overall mass transfer coefficients (kGA) are calculated as the result of the lumped model. The proposed model and empirical correlations are compared with the experimental results, and the comparison result shows good agreement with differences that are less than ±0.4 K.
Self-consistent liquid-to-gas mass transfer calculations.
Smith, Simon A; Stöckle, Claudio O
2010-12-01
This work develops an alternative gas transfer calculation method to the two methods currently used in anaerobic digestion modelling. The current calculation methods are problematic because one is computationally stiff, while the other introduces an artificial overpressure. The new approach began by noting that the gas partial pressures are the same as the partial flows at the liquid/gas interface, and then used the self-consistency requirement to develop gas pressure equations which were used by a search algorithm. The new approach took about three iterations to achieve a flow precision better than 2x10(-7) mol h(-1) l(-1), and was self-consistent and stable even when working with eight gases. 2010 Elsevier Ltd. All rights reserved.
Mass transfer in back-to-back elbows arranged in an out of plane configuration
Energy Technology Data Exchange (ETDEWEB)
Le, T.; Ewing, D. [Department of Mechanical Engineering, McMaster University, Hamilton, ON, L8S 4L7 Canada (Canada); Schefski, C. [Atomic Energy of Canada Ltd., Chalk River, ON, K0J 1J0 Canada (Canada); Ching, C.Y., E-mail: chingcy@mcmaster.ca [Department of Mechanical Engineering, McMaster University, Hamilton, ON, L8S 4L7 Canada (Canada)
2014-04-01
Highlights: • Mass transfer in back-to-back elbows in an out of plane configuration was measured. • The Reynolds number was 70,000 and Schmidt number was 1280. • Maximum mass transfer was on the downstream elbow. • The maximum decreased as the separation distance between the elbows increased. • Relative roughness on the second elbow was higher than that in the upstream pipe. - Abstract: Flow-Accelerated Corrosion (FAC) is a major degradation mechanism affecting carbon steel piping systems in nuclear power plants (NPPs). Flow and mass transfer conditions determine the local distribution of wall thinning, even though chemistry and materials determine the overall potential for FAC. Different localized thinning rates in back-to-back elbow configurations between the first and second elbows have been noted at NPPs, and this difference depends on the distance between elbows, flow conditions, and the configuration of the back-to-back elbows (S-, C-, or out of plane). This paper will focus on mass transfer measurements for back-to-back elbows arranged in an out of plane configuration for different elbow separation distances under single-phase flow conditions. The mass transfer measurements were performed using a mass dissolution technique of gypsum test sections in water. The experiments were performed at a Reynolds number of 70,000 and a resulting Schmidt number of 1280, which is similar to that for the diffusion of the iron magnetite layer of carbon steel piping in water, providing a mass transfer environment analogous to that in NPPs. Experiments were performed with 0, 1, 2 and 5 pipe diameters in length between the elbows. The mass transfer results show regions of higher mass transfer in the second elbow in comparison to the first elbow. The maximum mass transfer enhancement factor decreased from 2.7 to 2.1 as the separation distance increased from 0 to 5 pipe diameters. Flow streaks on the second elbow surface indicated swirling flow and its strength
Fuel cell collector plates with improved mass transfer channels
Gurau, Vladimir; Barbir, Frano; Neutzler, Jay K.
2003-04-22
A fuel cell collector plate can be provided with one or more various channel constructions for the transport of reactants to the gas diffusion layer and the removal of water therefrom. The outlet channel can be arranged to have a reduced volume compared to the inlet channel, in both interdigitated and discontinuous spiral applications. The land width between an inlet channel and outlet channel can be reduced to improved mass flow rate in regions of deleted reactant concentrations. Additionally or alternatively, the depth of the inlet channel can be reduced in the direction of flow to reduce the diffusion path as the concentration of reactant is reduced.
Deissler, Robert G
1955-01-01
The expression for eddy diffusivity from a previous analysis was modified in order to account for the effect of kinematic viscosity on the turbulence in the region close to a wall. By using the modified expression, good agreement was obtained between predicted and experimental results for heat and mass transfer at Prandtl and Schmidt numbers between 0.5 and 3000. The effects of length-to-diameter ratio and of variable viscosity were also investigated for a wide range of Prandtl numbers.
Quantification of the Mass Transfer at Fluid Interfaces in Microfluidic Channels
Wismeth, Carina; Manhart, Michael; Niessner, Reinhard; Baumann, Thomas
2017-04-01
Mass transfer rates at interfaces in a complex porous media are relevant in many environmental applications and control the functions of natural filter systems in subsurface environments. The mass transfer at fluid interfaces is associated with interface convection caused by local inhomogeneities in interface tension and hydrodynamic instabilities at the interface. If there is a surface tension gradient along the surface a shear stress jump is generated that results in fluid motion along the surface that is called Marangoni effect. These spontaneous convection currents can lead to an increased mass transfer of the transition component at the phase boundary and to an increased mixing of the phases. Therefore compensatory currents at the interface can have a significant influence on the subsurface transport of contaminants in the groundwater area, especially in the vadose zone. Using microfluidic channels and advanced experimental techniques it is possible to measure the fluid flow and mass transfer rates directly and to quantify the effect of the Marangoni convection on the mass transfer at interfaces between a non-aqueous liquid and water with high temporal and spatial resolution. The use of fluorescent particles as well as the recording and analysis of their trajectories is intended to visualize interfacial processes and to quantify the mass transfer at fluid phase boundaries. Concentration gradients at the interface are analysed by spectroscopic methods and allow an assessment of the enrichment and depletion at the phase boundaries. Extensive test series provide the experimental basis for quantifying and analysing the impact of the Marangoni effect on the mass transfer rates at interfaces in porous media in subsurface aquatic environments. Within this research project we concentrate on the effect of Marangoni convection on the mass transfer near an 1-octanol-water interface, which serves as a well defined proxy for non-aqueous phase liquids in porous media
Heat and mass transfer with condensation in capillary porous bodies.
Larbi, Salah
2014-01-01
The purpose of this present work is related to wetting process analysis caused by condensation phenomena in capillary porous material by using a numerical simulation. Special emphasis is given to the study of the mechanism involved and the evaluation of classical theoretical models used as a predictive tool. A further discussion will be given for the distribution of the liquid phase for both its pendular and its funicular state and its consequence on diffusion coefficients of the mathematical model used. Beyond the complexity of the interaction effects between vaporisation-condensation processes on the gas-liquid interfaces, the comparison between experimental and numerical simulations permits to identify the specific contribution and the relative part of mass and energy transport parameters. This analysis allows us to understand the contribution of each part of the mathematical model used and to simplify the study.
Heat and Mass Transfer with Condensation in Capillary Porous Bodies
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Salah Larbi
2014-01-01
Full Text Available The purpose of this present work is related to wetting process analysis caused by condensation phenomena in capillary porous material by using a numerical simulation. Special emphasis is given to the study of the mechanism involved and the evaluation of classical theoretical models used as a predictive tool. A further discussion will be given for the distribution of the liquid phase for both its pendular and its funicular state and its consequence on diffusion coefficients of the mathematical model used. Beyond the complexity of the interaction effects between vaporisation-condensation processes on the gas-liquid interfaces, the comparison between experimental and numerical simulations permits to identify the specific contribution and the relative part of mass and energy transport parameters. This analysis allows us to understand the contribution of each part of the mathematical model used and to simplify the study.
Numerical Study on Mass Transfer of a Vapor Bubble Rising in Very High Viscous Fluid
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T. Kunugi
2014-09-01
Full Text Available This study focused on a bubble rising behavior in a molten glass because it is important to improve the efficiency of removal of bubbles from the molten glass. On the other hand, it is expected that some gas species which exists in a bubble are transferred into the molten glass through the bubble interface, i.e., the mass transfer, subsequently, it may cause a bubble contraction in the molten glass. In this paper, in order to understand the bubble rising behavior with its contraction caused by the mass transfer through the bubble interface in the very high viscous fluid such as the molten glass, a bubble contraction model has been developed. The direct numerical simulations based on the MARS (Multi-interface Advection and Reconstruction Solver coupled with the mass transfer equation and the bubble contraction model regarding the mass transfer from the rising bubble in very high viscous fluid have been performed. Here, the working fluids were water vapor as the gas species and the molten glass as the very high viscous fluid. Also, the jump conditions at the bubble interface for the mass transfer were examined. Furthermore, the influence of the bubble contraction for the bubble rising compared to that in the water as a normal viscous fluid was investigated. From the result of the numerical simulations, it was found that the bubble rising behavior was strongly affected not only by the viscosity of the working fluid but also by the bubble contraction due to the mass transfer through the bubble interface.
Influence of relative air/water flow velocity on oxygen mass transfer in gravity sewers.
Carrera, Lucie; Springer, Fanny; Lipeme-Kouyi, Gislain; Buffiere, Pierre
2017-04-01
Problems related to hydrogen sulfide may be serious for both network stakeholders and the public in terms of health, sustainability of the sewer structure and urban comfort. H2S emission models are generally theoretical and simplified in terms of environmental conditions. Although air transport characteristics in sewers must play a role in the fate of hydrogen sulfide, only a limited number of studies have investigated this issue. The aim of this study was to better understand H2S liquid to gas transfer by highlighting the link between the mass transfer coefficient and the turbulence in the air flow and the water flow. For experimental safety reasons, O2 was taken as a model compound. The oxygen mass transfer coefficients were obtained using a mass balance in plug flow. The mass transfer coefficient was not impacted by the range of the interface air-flow velocity values tested (0.55-2.28 m·s-1) or the water velocity values (0.06-0.55 m·s-1). Using the ratio between kL,O2 to kL,H2S, the H2S mass transfer behavior in a gravity pipe in the same hydraulic conditions can be predicted.
Kiss, Ibolya; Bacskay, Ivett; Kilár, Ferenc; Felinger, Attila
2010-06-01
The characterization of mass-transfer processes in a chromatographic column during a separation process is essential, since the influence of the mass-transfer kinetics on the shape of the chromatographic band profiles and on the efficiency of the separation is crucial. Several sources of mass transfer in a chromatographic bed have been identified and studied: the axial dispersion in the stream of mobile phase, the external mass-transfer resistance, intraparticle diffusion, and the kinetics of adsorption-desorption. We measured and compared the characteristics and performance of a new brand of shell particles and those of a conventional brand of totally porous silica particles. The shell stationary phase was made of 2.7-microm superficially porous particles (a 1.7-microm solid core is covered with a 0.5-microm-thick shell of porous silica). The other material consisted of totally porous particles of conventional 3.5-microm commercial silica. We measured the first and second central moments of the peaks of human insulin over a wide range of mobile phase velocities (from 0.02 to 1.3 mL/min) at 20 degrees C. The plate height equations were constructed and the axial dispersion, external mass transfer, as well as the intraparticle diffusion coefficients were calculated for the two stationary phases.
Energy Technology Data Exchange (ETDEWEB)
Lemouari, M. [Department of Processes Engineering, Faculty of Sciences and Engineering, University of Bejaia (Algeria); Boumaza, M. [Department of Chemical Engineering, College of Engineering - King Saud University, P.O. Box 800, Riyadh (Saudi Arabia); Kaabi, A. [Department of Genie Climatique, Faculty of Engineering, University of Constantine, Constantine (Algeria)
2009-06-15
This paper deals with an experimental analysis of simultaneous heat and mass transfer phenomena between water and air by direct contact in a packed cooling tower. The tower is filled with a ''VGA.'' (Vertical Grid Apparatus) type packing. The packing is 0.42 m high and consists of four (04) galvanised sheets having a zigzag form, between which are disposed three (03) metallic vertical grids in parallel with a cross-sectional test area of 0.15 m x 0.148 m. This study investigates the effect of the air and water flow rates on the global heat and mass transfer coefficient as well as the evaporation rate of water into the air stream, for different inlet water temperatures. Two operating regimes were observed during the air/water contact inside the tower, a Pellicular Regime (PR) and a Bubble and Dispersion Regime (BDR). These two regimes can determine the best way to promote the heat and mass transfer phenomena in such device. The BDR regime seems to be more efficient than the Pellicular Regime, as it enables to achieve relatively higher values of the global heat and mass transfer coefficient and larger water evaporation rates. The comparison between the obtained results and some of those available in the literature for other types of packing indicates that this type possesses good heat and mass transfer characteristics. (author)
Thermophoretically augmented mass transfer rates to solid walls across laminar boundary layers
Gokoglu, S. A.; Rosner, D. E.
1986-01-01
Predictions of mass transfer (heavy vapor and small particle deposition) rates to solid walls, including the effects of thermal (Soret) diffusion ('thermophoresis' for small particles), are made by numerically solving the two-dimensional self-similar forced convection laminar boundary-layer equations with variable properties, covering the particle size range from vapor molecules up to the size threshold for inertial (dynamical nonequilibrium) effects. The effect of thermophoresis is predicted to be particularly important for submicron particle deposition on highly cooled solid surfaces, with corresponding enhancement factors at atmospheric conditions being over a thousand-fold at T(w)/T(e) equal to about 0.6. As a consequence of this mass transfer mechanism, the particle size dependence of the mass transfer coefficient to a cooled wall will be much weaker than for the corresponding case of isothermal capture by Brownian-convective diffusion.
Effects of mass transfer on damping mechanisms of vapor bubbles oscillating in liquids.
Zhang, Yuning; Gao, Yuhang; Guo, Zhongyu; Du, Xiaoze
2018-01-01
The damping mechanisms play an important role in the behavior of vapor bubbles. In the present paper, effects of mass transfer on the damping mechanisms of oscillating vapor bubbles in liquids are investigated within a wide range of parameter zone (e.g. in terms of frequency and bubble Péclet number). Results of the vapor bubbles are also compared with those of the gas bubbles. Our findings reveal that the damping mechanisms of vapor bubbles are significantly affected by the mass transfer especially in the regions with small and medium bubble Péclet number. Comparing with the gas bubbles, the contributions of the mass-transfer damping mechanism for the vapor bubble case are quite significant, being the dominant damping mechanism in a wide region. Copyright © 2017 Elsevier B.V. All rights reserved.
A Novel Model for the Mass Transfer of Articular Cartilage: Rolling Depression Load Device
Fan, Zhenmin; Zhang, Chunqiu; Liu, Haiying; Xu, Baoshan; Li, Jiang; Gao, Lilan
The mass transfer is one of important aspects to maintain the physiological activity proper of tissue, specially, cartilage cannot run without mechanical environment. The mechanical condition drives nutrition in and waste out in the cartilage tissue, the change of this process plays a key role for biological activity. Researchers used to adopt compression to study the mass transfer in cartilage, here we firstly establish a new rolling depression load (RDL) device, and also put this device into practice. The device divided into rolling control system and the compression adjusting mechanism. The rolling control system makes sure the pure rolling and uniform speed of roller applying towards cultured tissue. The compression adjusting mechanism can realize different compressive magnitudes and uniform compression. Preliminary test showed that rolling depression load indeed enhances the process of mass transfer articular cartilage.
Hristopulos, D. T.; Leonidakis, L.; Tsetsekou, A.
2006-03-01
The evolution of grain structures in materials is a complex and multiscale process that determines the material's final properties [1]. Understanding the dynamics of grain growth is a key factor for controlling this process. We propose a phenomenological approach, based on a nonlinear, discrete mass transfer equation for the evolution of an arbitrary initial grain size distribution. Transition rates for mass transfer across grains are assumed to follow the Arrhenius law, but the activation energy depends on the degree of amorphization of each grain. We argue that the magnitude of the activation energy controls the final (sintered) grain size distribution, and we verify this prediction by numerical simulation of mass transfer in a one-dimensional grain aggregate.
Stagnation point flow and mass transfer with chemical reaction past a stretching/shrinking cylinder.
Najib, Najwa; Bachok, Norfifah; Arifin, Norihan Md; Ishak, Anuar
2014-02-26
This paper is about the stagnation point flow and mass transfer with chemical reaction past a stretching/shrinking cylinder. The governing partial differential equations in cylindrical form are transformed into ordinary differential equations by a similarity transformation. The transformed equations are solved numerically using a shooting method. Results for the skin friction coefficient, Schmidt number, velocity profiles as well as concentration profiles are presented for different values of the governing parameters. Effects of the curvature parameter, stretching/shrinking parameter and Schmidt number on the flow and mass transfer characteristics are examined. The study indicates that dual solutions exist for the shrinking cylinder but for the stretching cylinder, the solution is unique. It is observed that the surface shear stress and the mass transfer rate at the surface increase as the curvature parameter increases.
Extraction of chlorophyll from pandan leaves using ethanol and mass transfer study
Directory of Open Access Journals (Sweden)
Putra Meilana Dharma
2017-01-01
Full Text Available Green pigments are used in many industrial branches including food, drinks, soap and cosmetics. Chlorophyll can substitute synthetic dyes which may affect health. Chlorophyll can be extracted from pandan leaves; the pandan crop grows in many tropical areas. The effects of temperature, 30–70°C and agitation speed, 100–400 rpm on chlorophyll extraction from pandan leaves, using ethanol and the evaluation of mass transfer coefficient, using dimensionless analysis were investigated. The optimal conditions of extraction was obtained at 60°C and 300 rpm; the chlorophyll concentration was 107.1 mg L-1. The volumetric mass transfer coefficient increased with the temperature and agitation speed. Determination of volumetric mass transfer coefficient and dimensionless correlations are useful for further process development or industrial applications.
Robust Modelling of Heat and Mass Transfer in Processing of Solid Foods
DEFF Research Database (Denmark)
Feyissa, Aberham Hailu
The study is focused on combined heat and mass transfer during processing of solid foods such as baking and frying processes. Modelling of heat and mass transfer during baking and frying is a significant scientific challenge. During baking and frying, the food undergoes several changes...... in microstructure and other physical properties of the food matrix. The heat and water transport inside the food is coupled in a complex way, which for some food systems it is not yet fully understood. A typical example of the latter is roasting of meat in convection oven, where the mechanism of water transport...... is unclear. Establishing the robust mathematical models describing the main mechanisms reliably is of great concern. A quantitative description of the heat and mass transfer during the solid food processing, in the form of mathematical equations, implementation of the solution techniques, and the value...
Effect of Reynolds number on flow and mass transfer characteristics of a 90 degree elbow
Fujisawa, Nobuyuki; Ikarashi, Yuya; Yamagata, Takayuki; Taguchi, Syoichi
2016-11-01
The flow and mass transfer characteristics of a 90 degree elbow was studied experimentally by using the mass transfer measurement by plaster dissolution method, the surface flow visualization by oil film method and stereo PIV measurement. The experiments are carried out in a water tunnel of a circular pipe of 56mm in diameter with a working fluid of water. The Reynolds number was varied from 30000 to 200000. The experimental result indicated the change of the mass transfer coefficient distribution in the elbow with increasing the Reynolds number. This phenomenon is further examined by the surface flow visualization and measurement of secondary flow pattern in the elbow, and the results showed the suggested change of the secondary flow pattern in the elbow with increasing the Reynolds numbers.
Stagnation Point Flow and Mass Transfer with Chemical Reaction past a Stretching/Shrinking Cylinder
Najib, Najwa; Bachok, Norfifah; Arifin, Norihan Md.; Ishak, Anuar
2014-02-01
This paper is about the stagnation point flow and mass transfer with chemical reaction past a stretching/shrinking cylinder. The governing partial differential equations in cylindrical form are transformed into ordinary differential equations by a similarity transformation. The transformed equations are solved numerically using a shooting method. Results for the skin friction coefficient, Schmidt number, velocity profiles as well as concentration profiles are presented for different values of the governing parameters. Effects of the curvature parameter, stretching/shrinking parameter and Schmidt number on the flow and mass transfer characteristics are examined. The study indicates that dual solutions exist for the shrinking cylinder but for the stretching cylinder, the solution is unique. It is observed that the surface shear stress and the mass transfer rate at the surface increase as the curvature parameter increases.
Nedredal, Geir I.; Amiot, Bruce P.; Nyberg, Peter; Luebke-Wheeler, Jennifer; Lillegard, Joseph B.; McKenzie, Travis J.; Nyberg, Scott L.
2010-01-01
This study was designed to determine optimal operating conditions of a bioartificial liver (BAL) based on mass transfer of representative hepatotoxins and mediators of immune damage. A microprocessor-controlled BAL was used to study mass transfer between patient and cell compartments separated by a hollow fiber membrane. Membrane permeability (70, 150, or 400 kDa molecular weight cut-off—MWCO), membrane convection (high: 50 mL/min; medium: 25 mL/min; low: 10 mL/min; diffusion: 0 mL/min), and albumin concentration in the cell compartment (0.5 or 5 g%) were considered for a total of 24 test conditions. Initially, the patient compartment contained pig plasma supplemented with ammonia (0.017 kDa), unconjugated bilirubin (0.585 kDa), conjugated bilirubin (0.760 kDa), TNF-α (17 kDa), pig albumin (67 kDa), pig IgG (147 kDa), and pig IgM (900 kDa). Mass transfer of each substance was determined by its rate of appearance in the cell compartment. Membrane fouling was assessed by dextran polymer technique. Of the three tested variables (membrane pore size, convection, and albumin concentration), membrane permeability had the greatest impact on mass transfer (P Mass transfer of all toxins was greatest under high convection with a 400 kDa membrane. Transfer of IgG and IgM was insignificant under all conditions. Bilirubin transfer was increased under high albumin conditions (P = 0.055). Fouling of membranes ranged from 7% (400 kDa), 24% (150 kDa) to 62% (70 kDa) during a 2-h test interval. In conclusion, optimal toxin removal was achieved under high convection with a 400-kDa membrane, a condition which should provide adequate immunoprotection of hepatocytes in the BAL. PMID:19557829
Directory of Open Access Journals (Sweden)
Kyu Hmwe Hmwe
2013-01-01
Full Text Available Abstract Background Nigeria carries the greatest malaria burden among countries in the world. As part of the National Malaria Control Strategic Plan, free long-lasting insecticidal nets (LLINs were distributed in 14 states of Nigeria through mass campaigns led by different organizations (the World Bank, UNICEF, or the Global Fund between May 2009 and August 2010. The objective of this study was to evaluate the association between LLIN distribution campaigns and child malaria in Nigeria. Methods Data were from the Nigeria Malaria Indicator Survey which was carried out from October to December 2010 on a nationally representative sample of households. Participants were women aged 15–49 years and their children aged less than five years (N = 4082. The main outcome measure was the presence or absence of malaria parasites in blood samples of children (6–59 months. Results Compared with children living in communities with no campaigns, those in the campaign areas were less likely to test positive for malaria after adjusting for geographic locations, community- and individual-level characteristics including child-level use of insecticide-treated nets (ITNs. The protective effects were statistically significant for the World Bank Booster Project areas (OR = 0.18, 95% CI = 0.04-0.73 but did not reach statistical significance for other campaign areas. Results also showed that community-level wealth (OR = 0.51, 95% CI = 0.34-0.76, community-level maternal knowledge regarding malaria prevention (OR = 0.70, 95% CI = 0.50-0.97, and child-level use of ITNs (OR = 0.79, 95% CI = 0.63-0.99 were negatively associated with child malaria. Conclusions The observed protective effects on child malaria of these campaigns (statistically significant in the World Bank Booster Project areas and non-significant in the other areas need to be corroborated by future effectiveness studies. Results also show that improving community
Sulfide emissions in sewer networks: focus on liquid to gas mass transfer coefficient.
Carrera, Lucie; Springer, Fanny; Lipeme-Kouyi, Gislain; Buffiere, Pierre
2017-04-01
H2S emission dynamics in sewers are conditioned by the mass transfer coefficient at the interface. This work aims at measuring the variation of the mass transfer coefficient with the hydraulic characteristics, with the objective of estimating H2S emission in gravity pipes, and collecting data to establish models independent of the system geometry. The ratio between the H2S and O2 mass transfer coefficient was assessed in an 8 L mixed reactor under different experimental conditions. Then, oxygen mass transfer measurements were performed in a 10 m long gravity pipe. The following ranges of experimental conditions were investigated: velocity flow [0-0.61 m.s-1], Reynolds number [0-23,333]. The hydrodynamic parameters at the liquid/gas interface were calculated by computational fluid dynamics (CFD). In the laboratory-scale reactor, the O2 mass transfer coefficient was found to depend on the stirring rate (rph) as follows: KL,O2 = 0.016 + 0.025 N3.85. A KL,H2S/KL,O2 ratio of 0.64 ± 0.24 was found, in accordance with previously published data. CFD results helped in refining this correlation: the mass transfer coefficient depends on the local interface velocity ui (m.h-1): KL,O2 = 0.016 + 1.02 × 10-5 ui3.85 In the gravity pipe device, KL,O2 also exponentially increased with the mean flow velocity. These trends were found to be consistent with the increasing level of turbulence.
Mansour, M A; El-Kabeir, S M
2000-01-01
Steady laminar boundary layer analysis of heat and mass transfer characteristics in magnetohydrodynamic (MHD) flow of a micropolar fluid on a circular cylinder maintained at uniform heat and mass flux has been conducted. The solution of the energy equation inside the boundary layer is obtained as a power series of the distance measured along the surface from the front stagnation point of the cylinder. The results of dimensionless temperature, Nusselt number, wall shear stress, wall couple stress and Sherwood number have been presented graphically for various values of the material parameters. The results indicate that the micropolar fluids display a reduction in drag as well as heat transfer rate when compared with Newtonian fluids.
Directory of Open Access Journals (Sweden)
C. Rasmussen
2013-09-01
Full Text Available Recent work suggests that a coupled effective energy and mass transfer (EEMT term, which includes the energy associated with effective precipitation and primary production, may serve as a robust prediction parameter of critical zone structure and function. However, the models used to estimate EEMT have been solely based on long-term climatological data with little validation using direct empirical measures of energy, water, and carbon balances. Here we compare catchment-scale EEMT estimates generated using two distinct approaches: (1 EEMT modeled using the established methodology based on estimates of monthly effective precipitation and net primary production derived from climatological data, and (2 empirical catchment-scale EEMT estimated using data from 86 catchments of the Model Parameter Estimation Experiment (MOPEX and MOD17A3 annual net primary production (NPP product derived from Moderate Resolution Imaging Spectroradiometer (MODIS. Results indicated positive and significant linear correspondence (R2 = 0.75; P −2 yr−1. Modeled EEMT values were consistently greater than empirical measures of EEMT. Empirical catchment estimates of the energy associated with effective precipitation (EPPT were calculated using a mass balance approach that accounts for water losses to quick surface runoff not accounted for in the climatologically modeled EPPT. Similarly, local controls on primary production such as solar radiation and nutrient limitation were not explicitly included in the climatologically based estimates of energy associated with primary production (EBIO, whereas these were captured in the remotely sensed MODIS NPP data. These differences likely explain the greater estimate of modeled EEMT relative to the empirical measures. There was significant positive correlation between catchment aridity and the fraction of EEMT partitioned into EBIO (FBIO, with an increase in FBIO as a fraction of the total as aridity increases and percentage of
Gondrexon, N; Cheze, L; Jin, Y; Legay, M; Tissot, Q; Hengl, N; Baup, S; Boldo, P; Pignon, F; Talansier, E
2015-07-01
This paper aims to illustrate the interest of ultrasound technology as an efficient technique for both heat and mass transfer intensification. It is demonstrated that the use of ultrasound results in an increase of heat exchanger performances and in a possible fouling monitoring in heat exchangers. Mass transfer intensification was observed in the case of cross-flow ultrafiltration. It is shown that the enhancement of the membrane separation process strongly depends on the physico-chemical properties of the filtered suspensions. Copyright © 2014 Elsevier B.V. All rights reserved.
Heat and mass transfer and friction resistance of forced superheated vapor flow in tubes
Energy Technology Data Exchange (ETDEWEB)
Grebennikov, V.N.
This paper describes a procedure used for calculating the heat/mass transfer and friction resistance of a forced superheated vapor flow in tubes of separators-vapor superheaters and direct-flow vapor generators under equilibrium conditions and also under conditions where the flow is in a thermodynamic nonequilibrium state. Using the Reynolds analogy-based concept, an analysis of the process is carried out. Recommendations for calculating the heat/mass transfer and the hydraulic characteristics of vapor- superheating sections in separators-vapor superheaters and direct-flow vapor generators are made.
New method for mass transfer across the surface of non-spherical particles in turbulence
Oehmke, T.; Variano, E. A.
2016-12-01
We present a method for making model particles that allow for the interfacial mass transfer rate to be measured. This is similar to traditional use of gypsum plaster used to measure erosion rates on the timescale of weeks to years. Our new method is useful for measuring erosion rates on the timescale of minutes. We use this to measure the manner in which particle shape affects its rate of dissolution in turbulent flow. The related questions are relevant to mass transfer in turbulence, e.g. in cases of marine biology and pollution by microplastics.
Rosner, D. E.
1985-01-01
The effects of Soret diffusion (for vapors) and thermophoresis (for particles) are illustrated using recent optical experiments and boundary layer computations. Mass transfer rate augmentations of up to a factor of 1000 were observed and predicted for submicron-particle capture by cooled solid surfaces, while mass transfer suppressions of more than 10 to the -10th-fold were predicted for 'overheated' surfaces. It is noted that the results obtained are of interest in connection with such technological applications as fly-ash capture in power generation equipment and glass droplet deposition in optical-waveguide manufacture.
Studies on oxygen mass transfer in stirred bioreactors 2: Suspensions of bacteria, yeasts and fungis
Directory of Open Access Journals (Sweden)
Galaction Anca-Irina
2003-01-01
Full Text Available The aim of these experiments is to study the oxygen mass transfer rate by means of the mass transfer coefficient, for a stirred bioreactor and different fermentation broths, using a large domain of operating variables. For quantifying the effects of the considered factors (concentration and morphology of the biomass, specific power input, superficial air velocity surface aeration on ka, the experiments were carried out for non-respirating biomass suspensions of Propionibacterium shermanii Saccharomyces cerevisiae and Penicillium chrysogenum, mycelial aggregates (pellets and free mycelia morphological structures.
Thermodynamic analysis of human heat and mass transfer and their impact on thermal comfort
Prek, Matjaž
2015-01-01
In this paper a thermodynamic analysis of human heat and mass transfer based on the 2nd law of thermodynamics in presented. For modelling purposes the two-node human thermal model was used. This model was improved in order to establish the exergy consumption within the human body as a consequence of heat and mass transfer and/or conversion. It is shown that the human body's exergy consumption in relation to selected human parameters exhibit a minimal value at certain combinations of environme...
Kinetics of diffusive decomposition in the case of several mass transfer mechanisms
Alexandrov, D. V.
2017-01-01
An analytical description of the final stage of diffusive decomposition leaning upon the Slezov theory is developed for several mass transfer mechanisms. The process of formation and relaxation of the crystal size distribution function from the initial ripening stage to its final state corresponding to the universal distribution is studied. The boundary points of a transition region responsible for the tails of the distribution functions on the right of the relevant stopping points are found analytically. The explicit time-dependent analytical expressions for the distribution function and particle growth rates are derived with allowance for the plausible mechanisms of mass transfer.
Mass transfer in wetted-wall columns: correlations at high Reynolds numbers
DEFF Research Database (Denmark)
Nielsen, Christian H.E.; Kiil, Søren; Thomsen, Henrik W.
1998-01-01
The rate of gas-and liquid-phase mass transport in a pilot-scale wetted-wall column with an inner diameter of 3.26 cm and a length of 5 m was investigated. Empirical correlations for the physical liquid-phase mass transfer coefficient (k(L)(O)) and the gas-phase mass transfer coefficient (k...... of the obtained correlations. Our data showed that Sh(L) and Sh(G) both depend on Re-G and Re-L due to changes in the interfacial area at the high Reynolds numbers employed. The presence of inert particles in the liquid-phase may influence the rate of mass transport, and experimental work was initiated to study...
On the multi-physics of mass-transfer across fluid interfaces
Bothe, Dieter
2015-01-01
Mass transfer of gaseous components from rising bubbles to the ambient liquid can be described based on continuum mechanical sharp-interface balances of mass, momentum and species mass. In this context, the standard model consists of the two-phase Navier-Stokes equations for incompressible fluids with constant surface tension, complemented by reaction-advection-diffusion equations for all constituents, employing Fick's law. This standard model is inconsistent with the continuity equation, the momentum balance and the second law of thermodynamics. The present paper reports on the details of these severe shortcomings and provides thermodynamically consistent model extensions which are required to capture various phenomena which occur due to the multi-physics of interfacial mass transfer. In particular, we provide a simple derivation of the interface Maxwell-Stefan equations which does not require a time scale separation, while the main contribution is to show how interface concentrations and interface chemical ...
Evidence of a non-conservative mass transfer for XTE J0929-314
Marino, A.; Di Salvo, T.; Gambino, A. F.; Iaria, R.; Burderi, L.; Matranga, M.; Sanna, A.; Riggio, A.
2017-07-01
Context. In 1998 the first accreting millisecond pulsar, SAX J1808.4-3658, was discovered and to date 18 systems showing coherent, high frequency (>100 Hz) pulsations in low-mass X-ray binaries are known. Since their discovery, this class of sources has shown interesting and sometimes puzzling behaviours. In particular, apart from a few exceptions, they are all transient with very long X-ray quiescent periods implying a quite low averaged mass accretion rate onto the neutron star. Among these sources, XTE J0929-314 has been detected in outburst just once in about 15 years of continuous monitoring of the X-ray sky. Aims: We aim to demonstrate that a conservative mass transfer in this system will result in an X-ray luminosity that is higher than the observed, long-term averaged X-ray luminosity. Methods: Under the hypothesis of a conservative mass transfer driven by gravitational radiation, as expected for this system given the short orbital period of about 43.6 min and the low-mass of the companion implied by the mass function derived from timing techniques, we calculate the expected mass transfer rate in this system and predict the long-term averaged X-ray luminosity. This is compared with the averaged, over 15 years, X-ray flux observed from the system, and a lower limit of the distance to the source is inferred. Results: This distance is shown to be >7.4 kpc in the direction of the Galactic anticentre, implying a large height, >1.8 kpc, of the source with respect to the Galactic plane, placing the source in an empty region of the Galaxy. We suggest that the inferred value of the distance is unlikely. Conclusions: This problem can be solved if we hypothesize that the source is undergoing a non-conservative mass transfer, in which most of the mass transferred from the companion star is ejected from the system, probably because of the (rotating magnetic dipole) radiation pressure of the pulsar. If confirmed by future observations, this may be another piece of
On the stream-accretion disk interaction - Response to increased mass transfer rate
Dgani, Ruth; Livio, Mario; Soker, Noam
1989-01-01
The time-dependent interaction between the stream of mass from the inner Lagrangian point and the accretion disk, resulting from an increasing mass transfer rate is calculated. The calculation is fully three-dimensional, using a pseudoparticle description of the hydrodynamics. It is demonstrated that the results of such calculations, when combined with specific observations, have the potential of both determining essential parameters, such as the viscosity parameter alpha, and can distinguish between different models of dwarf nova eruptions.
Curry, D. M.; Cox, J. E.
1972-01-01
Coupled nonlinear partial differential equations describing heat and mass transfer in a porous matrix are solved in finite difference form with the aid of a new iterative technique (the strongly implicit procedure). Example numerical results demonstrate the characteristics of heat and mass transport in a porous matrix such as a charring ablator. It is emphasized that multidimensional flow must be considered when predicting the thermal response of a porous material subjected to nonuniform boundary conditions.
Jiao, Anjun; Zhang, Yuwen; Ma, Hongbin; Critser, John
2010-01-01
Heat and mass transfer in a circular tube subject to the boundary condition of the third kind is investigated. The closed form of temperature and concentration distributions, the local Nusselt number based on the total external heat transfer and convective heat transfer inside the tube, as well as the Sherwood number were obtained. The effects of Lewis number and Biot number on heat and mass transfer were investigated. PMID:20862211
Ma, Qiang; Chen, Zhenqian; Liu, Hao
2017-07-01
In this paper, to predict the dynamics behaviors of flow and mass transfer with adsorption phenomena in porous media at the representative elementary volume (REV) scale, a multiple-relaxation-time (MRT) lattice Boltzmann (LB) model for the convection-diffusion equation is developed to solve the transfer problem with an unsteady source term in porous media. Utilizing the Chapman-Enskog analysis, the modified MRT-LB model can recover the macroscopic governing equations at the REV scale. The coupled MRT-LB model for momentum and mass transfer is validated by comparing with the finite-difference method and the analytical solution. Moreover, using the MRT-LB method coupled with the linear driving force model, the fluid transfer and adsorption behaviors of the carbon dioxide in a porous fixed bed are explored. The breakthrough curve of adsorption from MRT-LB simulation is compared with the experimental data and the finite-element solution, and the transient concentration distributions of the carbon dioxide along the porous fixed bed are elaborated upon in detail. In addition, the MRT-LB simulation results show that the appearance time of the breakthrough point in the breakthrough curve is advanced as the mass transfer resistance in the linear driving force model increases; however, the saturation point is prolonged inversely.
Dissociation and ammonia mass transfer from ammonium solution and dairy cattle manure
Process-based models are being used to predict ammonia (NH**3) emissions from manure sources, but their accuracy has not been fully evaluated for cattle manure. Laboratory trials were conducted to measure the dissociation and mass transfer coefficient for NH**3 volatilization from media of buffered ...
A Laboratory Experiment for Measuring Solid-Liquid Mass Transfer Parameters
Dapia, Sonia; Vila, Carlos; Dominguez, Herminia; Parajo, Juan Carlos
2004-01-01
The lab experiment described starts from the principles developed by Sensel and Myers, but the experimental procedure are modified to provide a more reliable experiment assessment. The mass transfer equation is solved and all the involved parameters are calculated by a simple, numerical method.
A mass transfer model of ethanol emission from thin layers of corn silage
A mass transfer model of ethanol emission from thin layers of corn silage was developed and validated. The model was developed based on data from wind tunnel experiments conducted at different temperatures and air velocities. Multiple regression analysis was used to derive an equation that related t...
Mass-transfer properties of insulin on core-shell and fully porous stationary phases.
Lambert, Nándor; Kiss, Ibolya; Felinger, Attila
2014-10-31
The mass-transfer properties of three superficially-porous packing materials, with 2.6 and 3.6μm particle and 1.9, 2.6, and 3.2μm inner core diameter, respectively, were investigated and compared with those of fully porous packings with similar particle properties. Several sources of band spreading in the chromatographic bed have been identified and studied according to the general rate model of chromatography. Besides the axial dispersion in the stream of the mobile phase, and the external mass transfer resistance, the intraparticle diffusion was studied in depth. The first absolute and the second central moments of the peaks of human insulin, over a wide range of mobile phase velocities were measured and used for the calculation of the mass-transfer coefficients. The experimental data were also analyzed using the stochastic or molecular dynamic model of Giddings and Eyring. The dissimilarities of the mass-transfer observed in the different columns were identified and evaluated. Copyright © 2014 Elsevier B.V. All rights reserved.
T. W. Appelboom; G. M. Chescheir; R. W. Skaggs; J. W. Gilliam; Devendra M. Amatya
2006-01-01
Watershed modeling has become an important tool for researchers with the high costs of water quality monitoring. When modeling nitrate transport within drainage networks, denitrification within the sediments needs to be accounted for. Birgand et. al. developed an equation using a term called a mass transfer coefficient to mathematically describe sediment...
T.W. Appelboom; G.M. Chescheir; F. Birgand; R.W. Skaggs; J.W. Gilliam; D. Amatya
2010-01-01
Watershed modeling has become an important tool for researchers. Modeling nitrate transport within drainage networks requires quantifying the denitrification within the sediments in canals and streams. In a previous study, several of the authors developed an equation using a term called a mass transfer coefficient to mathematically describe sediment denitrification....
Mass transfer coefficient in ginger oil extraction by microwave hydrotropic solution
Handayani, Dwi; Ikhsan, Diyono; Yulianto, Mohamad Endy; Dwisukma, Mandy Ayulia
2015-12-01
This research aims to obtain mass transfer coefficient data on the extraction of ginger oil using microwave hydrotropic solvent as an alternative to increase zingiberene. The innovation of this study is extraction with microwave heater and hydrotropic solvent,which able to shift the phase equilibrium, and the increasing rate of the extraction process and to improve the content of ginger oil zingiberene. The experiment was conducted at the Laboratory of Separation Techniques at Chemical Engineering Department of Diponegoro University. The research activities carried out in two stages, namely experimental and modeling work. Preparation of the model postulated, then lowered to obtain equations that were tested and validated using data obtained from experimental. Measurement of experimental data was performed using microwave power (300 W), extraction temperature of 90 ° C and the independent variable, i.e.: type of hydrotropic, the volume of solvent and concentration in order, to obtain zingiberen levels as a function of time. Measured data was used as a tool to validate the postulation, in order to obtain validation of models and empirical equations. The results showed that the mass transfer coefficient (Kla) on zingiberene mass transfer models ginger oil extraction at various hydrotropic solution attained more 14 ± 2 Kla value than its reported on the extraction with electric heating. The larger value of Kla, the faster rate of mass transfer on the extraction process. To obtain the same yields, the microwave-assisted extraction required one twelfth time shorter.
Modeling of mass transfer in combination with a homogeneously catalyzed reaction
Hoorn, J.A.A.; Versteeg, G. F.
The mass transfer rates of a gaseous reactant into a liquid where the reactions are catalyzed by homogeneous catalysts have been evaluated by the numerical solution of the diffusion-reaction equations according to Higbie's penetration theory. The concentration profiles as well as enhancement factors
Dumitrescu, Ioana; Crooks, Richard M.
2012-01-01
Here we report on the effect of the mass transfer rate (kt) on the oxygen reduction reaction (ORR) catalyzed by Pt dendrimer-encapsulated nanoparticles (DENs) comprised of 147 and 55 atoms (Pt147 and Pt55). The experiments were carried out using a dual-electrode microelectrochemical device, which enables the study of the ORR under high kt conditions with simultaneous detection of H2O2. At low kt (0.02 to 0.12 cm s-1) the effective number of electrons involved in ORR, neff, is 3.7 for Pt147 and 3.4 for Pt55. As kt is increased, the mass-transfer-limited current for the ORR becomes significantly lower than the value predicted by the Levich equation for a 4-electron process regardless of catalyst size. However, the percentage of H2O2 detected remains constant, such that neff barely changes over the entire kt range explored (0.02 cm s-1). This suggests that mass transfer does not affect neff, which has implications for the mechanism of the ORR on Pt nanoparticles. Interestingly, there is a significant difference in neff for the two sizes of Pt DENs (neff = 3.7 and 3.5 for Pt147 and Pt55, respectively) that cannot be assigned to mass transfer effects and that we therefore attribute to a particle size effect. PMID:22665772
Energetic efficiency of mass transfer accompanied by chemical reactions in liquid-liquid systems
Directory of Open Access Journals (Sweden)
Jasińska Magdalena
2017-09-01
Full Text Available Energetic efficiency depicting the fraction of energy dissipation rate used to perform processes of drop breakup and mass transfer in two-phase, liquid-liquid systems is considered. Results of experiments carried out earlier in two types of high-shear mixers: an in-line rotor-stator mixer and a batch rotor-stator mixer, have been applied to identify and compare the efficiency of drop breakage and mass transfer in both types of mixers. The applied method is based on experimental determination of both: the product distribution of chemical test reactions and the drop size distributions. Experimental data are interpreted using a multifractal model of turbulence for drop breakage and the model by Favelukis and Lavrenteva for mass transfer. Results show that the energetic efficiency of the in-line mixer is higher than that of the batch mixer; two stator geometries were considered in the case of the batch mixer and the energetic efficiency of the device equipped with a standard emulsor screen (SES was higher than the efficiency of the mixer equipped with a general purpose disintegrating head (GPDH for drop breakup but smaller for mass transfer.
Mixing and mass transfer in a pilot scale U-loop bioreactor.
Petersen, Leander A H; Villadsen, John; Jørgensen, Sten B; Gernaey, Krist V
2017-02-01
A system capable of handling a large volumetric gas fraction while providing a high gas to liquid mass transfer is a necessity if the metanotrophic bacterium Methylococcus capsulatus is to be used in single cell protein (SCP) production. In this study, mixing time and mass transfer coefficients were determined in a 0.15 m 3 forced flow U-loop fermenter of a novel construction. The effect on the impeller drawn power when a gas was introduced into the system was also studied. Mixing time decreased and mass transfer increased with increasing volumetric liquid flow rate and specific power input. This happened also for a large volume fraction of the gas, which was shown to have only minor effect on the power drawn from the pump impeller. Very large mass transfer coefficients, considerably higher than those obtainable in an STR and previous tubular loop reactors, could be achieved in the U-loop fermenter equipped with static mixers at modest volumetric liquid and gas flow rates. Biotechnol. Bioeng. 2017;114: 344-354. © 2016 Wiley Periodicals, Inc. © 2016 Wiley Periodicals, Inc.
Scale analysis and integral approximation applied to heat and mass transfer in packed beds
Sman, van der R.G.M.
2008-01-01
In this paper, we apply two mathematical tools for the analysis of models describing heat and mass transfer in dispersed systems, namely scale analysis and integral approximation. The particular model investigated is a 1-D model describing the cooling of packed beds of fresh agricultural produce
On computations for thermal radiation in MHD channel flow with heat and mass transfer.
Hayat, T; Awais, M; Alsaedi, A; Safdar, Ambreen
2014-01-01
This study examines the simultaneous effects of heat and mass transfer on the three-dimensional boundary layer flow of viscous fluid between two infinite parallel plates. Magnetohydrodynamic (MHD) and thermal radiation effects are present. The governing problems are first modeled and then solved by homotopy analysis method (HAM). Influence of several embedded parameters on the velocity, concentration and temperature fields are described.
Resistances for heat and mass transfer through a liquid–vapor interface in a binary mixture
Glavatskiy, K.S.; Bedeaux, D.
2010-01-01
In this paper we calculate the interfacial resistances to heat and mass transfer through a liquid–vapor interface in a binary mixture. We use two methods, the direct calculation from the actual nonequilibrium solution and integral relations, derived earlier. We verify, that integral relations, being
Mass Transfer Study of Chlorine Dioxide Gas Through Polymeric Packaging Materials
A continuous system for measuring the mass transfer of gaseous chlorine dioxide (ClO2), a strong oxidizing agent and used in food and pharmaceutical packaging, through 10 different types of polymeric packaging material was developed utilizing electrochemical sensor as a detector. Permeability, diff...
Directory of Open Access Journals (Sweden)
Eric Monflier
2012-11-01
Full Text Available The replacement of hazardous solvents and the utilization of catalytic processes are two key points of the green chemistry movement, so aqueous organometallic catalytic processes are of great interest in this context. Nevertheless, these processes require not only the use of water-soluble ligands such as phosphanes to solubilise the transition metals in water, but also the use of mass transfer agents to increase the solubility of organic substrates in water. In this context, phosphanes based on a cyclodextrin skeleton are an interesting alternative since these compounds can simultaneously act as mass transfer agents and as coordinating species towards transition metals. For twenty years, various cyclodextrin-functionalized phosphanes have been described in the literature. Nevertheless, while their coordinating properties towards transition metals and their catalytic properties were fully detailed, their mass transfer agent properties were much less discussed. As these mass transfer agent properties are directly linked to the availability of the cyclodextrin cavity, the aim of this review is to demonstrate that the nature of the reaction solvent and the nature of the linker between cyclodextrin and phosphorous moieties can deeply influence the recognition properties. In addition, the impact on the catalytic activity will be also discussed.
Energy Technology Data Exchange (ETDEWEB)
Maximuk, E.P. [Institute of Applied Pysics, Kishinev (Russian Federation); Vogelpohl, A. [Mass Transfer Lab., Clausthal Univ. of Technology, Clausthal-Zellerfeld (Germany)
2002-05-01
A physicomathematical model for electrohydrodynamic spraying (EHDS) of a conductive liquid and the mass transfer in a parallel plate electrode system of an EHDS distillation column is presented. The influence of the electric field on the formation and general characteristics of the finely dispersed aerosol flow of the conductive liquid in EHDS distillation columns has been determined from the model. (orig.)
Clack, Herek L
2006-06-01
Varying degrees of mercury (Hg) capture have been reported within the electrostatic precipitators (ESPs) of coal-fired electric utility boilers. There has been some speculation that the adsorption takes place on the particulate-covered plate electrodes. This convective mass transfer analysis of laminar and turbulent channel flows provides the maximum potential for Hg adsorption by the plate electrodes within an ESP under those conditions. Mass transfer calculations, neglecting electrohydrodynamic (EHD) effects, reveal 65% removal of elemental Hg for a laminar flow within a 15-m-long channel of 0.2-m spacing and 42% removal for turbulent flow within a similar configuration. Both configurations represent specific collection areas (SCAs) that are significantly larger than conventional ESPs in use. Results reflecting more representative SCA values generally returned removal efficiencies of <20%. EHD effects, although potentially substantial at low Reynolds numbers, diminish rapidly with increasing Reynolds number and become negligible at typical ESP operating conditions. The present results indicate maximum Hg removal efficiencies for ESPs that are much less than those observed in practice for comparable ESP operating conditions. Considering Hg adsorption kinetics and finite sorbent capacity in addition to the present mass transfer analyses would yield even lower adsorption efficiencies than the present results. In a subsequent paper, the author addresses the mass transfer potential presented by the charged, suspended particulates during their collection within an ESP and the role they potentially play in Hg capture within ESPs.
Luo, Benyi; Lu, Yigang
2008-10-01
Based on several hypotheses about the process of supercritical carbon dioxide extraction, the onflow around the solute granule is figured out by the Navier-Stocks equation. In combination with the Higbie’s solute infiltration model, the link between the mass-transfer coefficient and the velocity of flow is found. The mass-transfer coefficient with the ultrasonical effect is compared with that without the ultrasonical effect, and then a new parameter named the ultrasonic-enhanced factor of mass-transfer coefficient is brought forward, which describes the mathematical model of the supercritical carbon dioxide extraction process enhanced by ultrasonic. The model gives out the relationships among the ultrasonical power, the ultrasonical frequency, the radius of solute granule and the ultrasonic-enhanced factor of mass-transfer coefficient. The results calculated by this model fit well with the experimental data, including the extraction of Coix Lacryma-jobi Seed Oil (CLSO) and Coix Lacryma-jobi Seed Ester (CLSE) from coix seeds and the extraction of Eicosapentaenoic Acid (EPA) and Docosahexaenoic Acid (DHA) from the alga by means of the ultrasonic-enhanced supercritical carbon dioxide extraction (USFE) and the supercritical carbon dioxide extraction (SFE) respectively. This proves the rationality of the ultrasonic-enhanced factor model. The model provides a theoretical basis for the application of ultrasonic-enhanced supercritical fluid extraction technique.
Impact of Heat and Mass Transfer on MHD Oscillatory Flow of Jeffery ...
African Journals Online (AJOL)
The objective of this paper is to study Dufour, Soret and thermal conductivity on unsteady heat and mass transfer of magneto hydrodynamic (MHD) oscillatory flow of Jeffery fluid through a porous medium in a channel. The partial differential equations governing the flow have been solved numerically using semi-implicit ...
Analysis of coupled mass transfer and sol-gel reaction in a two-phase system
Castelijns, H.J.; Huinink, H.P.; Pel, L.; Zitha, P.L.J.
2006-01-01
The coupled mass transfer and chemical reactions of a gel-forming compound in a two-phase system were studied in detail. Tetra-methyl-ortho-silicate (TMOS) is often used as a precursor in sol-gel chemistry to produce silica gels in aqueous systems. TMOS can also be mixed with many hydrocarbons
Unsteady free convection and mass transfer flow of a non-newtonian ...
African Journals Online (AJOL)
We study the unsteady free convection and mass transfer of a non-Newtonian fluid past an infinite vertical plate in the presence of thermal diffusion. Closed form analytical solutions are obtained for the concentration and the temperature distributions by means of the Laplace transform technique on the assumption that the ...
HYDRODYNAMICS AND LOCAL MASS-TRANSFER CHARACTERISTICS OF GAS-LIQUID EJECTORS
CRAMERS, PHMR; SMIT, L; LEUTERITZ, GM; VANDIERENDONCK, LL; BEENACKERS, AACM
1993-01-01
The hydrodynamics and mass transfer characteristics of a straight tube ejector have been investigated. From the experiments it can be concluded that two different hydrodynamic zones exist in the ejector. In the first zone, the ''mixing shock'' region, extremely high k(L)a values are obtained. In the
Mass Transfer Testing of a 12.5-cm Rotor Centrifugal Contactor
Energy Technology Data Exchange (ETDEWEB)
D. H. Meikrantz; T. G. Garn; J. D. Law; N. R. Mann; T. A. Todd
2008-09-01
TRUEX mass transfer tests were performed using a single stage commercially available 12.5 cm centrifugal contactor and stable cerium (Ce) and europium (Eu). Test conditions included throughputs ranging from 2.5 to 15 Lpm and rotor speeds of 1750 and 2250 rpm. Ce and Eu extraction forward distribution coefficients ranged from 13 to 19. The first and second stage strip back distributions were 0.5 to 1.4 and .002 to .004, respectively, throughout the dynamic test conditions studied. Visual carryover of aqueous entrainment in all organic phase samples was estimated at < 0.1 % and organic carryover into all aqueous phase samples was about ten times less. Mass transfer efficiencies of = 98 % for both Ce and Eu in the extraction section were obtained over the entire range of test conditions. The first strip stage mass transfer efficiencies ranged from 75 to 93% trending higher with increasing throughput. Second stage mass transfer was greater than 99% in all cases. Increasing the rotor speed from 1750 to 2250 rpm had no significant effect on efficiency for all throughputs tested.
Development of a model to determine mass transfer coefficient and oxygen solubility in bioreactors
Directory of Open Access Journals (Sweden)
Johnny Lee
2017-02-01
where T is in degree Kelvin, and the subscripts refer to degree Celsius; E, ρ, σ are properties of water. Furthermore, using data from published data on oxygen solubility in water, it was found that solubility bears a linear and inverse relationship with the mass transfer coefficient.
Numerical Problems and Agent-Based Models for a Mass Transfer Course
Murthi, Manohar; Shea, Lonnie D.; Snurr, Randall Q.
2009-01-01
Problems requiring numerical solutions of differential equations or the use of agent-based modeling are presented for use in a course on mass transfer. These problems were solved using the popular technical computing language MATLABTM. Students were introduced to MATLAB via a problem with an analytical solution. A more complex problem to which no…
Bai, Ge; Armenante, Piero M
2009-04-01
Tablets undergoing dissolution in the USP Dissolution Testing Apparatus II are often found at locations on the vessel bottom that are off-center with respect to the dissolution vessel and impeller. A previously validated CFD approach and a novel experimental method were used here to examine the effect of tablet location on strain rates and dissolution rates. Dissolution tests were conducted with non-disintegrating tablets (salicylic acid) and disintegrating tablets (Prednisone) immobilized at different locations along the vessel bottom. CFD was used to predict the velocity profiles and strain rates when the tablets were placed at such locations. A CFD-based model was derived to predict the mass transfer coefficient and dissolution curves, which were then compared to the experimental results. Both non-disintegrating and disintegrating off-center tablets experimentally produced higher dissolution rates than centered tablets. The CFD-predicted strain rate distribution along the bottom was highly not uniform and the predicted strain rates correlated well with the experimental mass transfer coefficients. The proposed CFD-based model predicts mass transfer rates that correlate well with the experimental ones. The exact tablet location has a significant impact on the dissolution profile. The proposed model can satisfactorily predict the mass transfer coefficients and dissolution profiles for non-disintegrating tablets.
Demonstrating the Effect of Interphase Mass Transfer in a Transparent Fluidized Bed Reactor
Saayman, Jean; Nicol, Willie
2011-01-01
A demonstration experiment is described that employs the ozone decomposition reaction at ambient conditions on Fe2O3 impregnated Fluidized Catalytic Cracking (FCC) catalyst. Using a two-dimensional see-through column the importance of interphase mass transfer is clearly illustrated by the significant difference in ozone conversion between the…
Analytical solution of mass transfer effects on unsteady flow past an ...
African Journals Online (AJOL)
This paper discussed the analytical solution of unsteady free convection and mass transfer flow past an accelerated infinite vertical porous flat plate with suction, heat generation and chemical species when the plate accelerates in its own plane. The governing equations are solved analytically using perturbation technique.
Oxygen mass transfer and scale-up studies in baffled roller bioreactors.
Nikakhtari, H; Song, W; Nemati, M; Hill, G A
2014-02-01
Oxygen mass transfer was studied in conventional, bead mill and baffled roller bioreactors. Using central composite rotational design, impacts of size, rotation speed and working volume on the oxygen mass transfer were evaluated. Baffled roller bioreactor outperformed its conventional and bead mill counterparts, with the highest k(L)a obtained in these configurations being 0.58, 0.19, 0.41 min(-1), respectively. Performances of the bead mill and baffled roller bioreactor were only comparable when a high bead loading (40%) was applied. Regardless of configuration increase in rotation speed and decrease in working volume improved the oxygen mass transfer rate. Increase in size led to enhanced mass transfer and higher k(L)a in baffled roller bioreactor (0.49 min(-1) for 2.2 L and 1.31 min(-1) for 55 L bioreactors). Finally, the experimentally determined k(L)a in the baffled roller bioreactors of different sizes fit reasonably well to an empirical correlation describing the k(L)a in terms of dimensionless numbers.
Effect of mass transfer on concentration wave propagation during anaerobic digestion of solid waste.
Vavilin, Vasily A; Shchelkanov, Micael Yu; Rytov, Sergey V
2002-05-01
A distributed model of anaerobic digestion of solid waste was developed to study effects of mass transfer on the rate of propagation of initiation methanogenic area. The diffusion and advection of volatile fatty acids (VFA) and methanogenic biomass were taken into account in the model of a one-dimensional (ID) reactor. It was considered that VFA inhibits both polymer hydrolysis and acetoclastic methanogenesis. This approach allows to view the bioreactor as an active medium that provokes concentration waves from some area of methanogenic initiation (local VFA depression) to the total reactor volume. The model shows that mass transfer-based acceleration of methane production in the reactor is possible when the intensity of VFA utilization in the methanogenic area is sufficient for a complete digestion of the incoming VFA. Otherwise, initiation methanogenic area will be suppressed by increasing concentration of VFA. The obtained results emphasize the importance of considering spatial heterogeneity of the reaction for the analysis of solid anaerobic digestion in bioreactors and landfills. The digestion of solid waste can be optimized by setting the low rate of mass transfer (mixing or leachate recirculation) during lag-phase of the reaction with subsequent increase in the mass transfer rate in parallel with the propagation of methanogenic population. In this case, the rate of concentration waves substantially increases.
Directory of Open Access Journals (Sweden)
D.K. Tiwari
2015-09-01
Full Text Available A linear analysis of capillary instability of a cylindrical interface in the presence of axial magnetic field has been carried out when there is heat and mass transfer across the interface. Both fluids are taken as incompressible, viscous and magnetic with different kinematic viscosities and different magnetic permeabilities. Viscous potential flow theory is used for the investigation and a dispersion relation that accounts for the growth of axisymmetric waves is derived. Stability criterion is given by critical value of applied magnetic field as well as critical wave number and stability is discussed theoretically as well as numerically. Various graphs are drawn showing the effect of various physical parameters such as magnetic field strength, heat transfer capillary number, and permeability ratio, on the stability of the system. It has been observed that the axial magnetic field and heat and mass transfer both have stabilizing effect on the stability of the system.
Directory of Open Access Journals (Sweden)
E. R. Gouveia
2000-12-01
Full Text Available In the present work rheological characteristics and volumetric oxygen transfer coefficient (kLa were investigated during batch cultivations of Streptomyces clavuligerus NRRL 3585 for production of clavulanic acid. The experimental rheological data could be adequately described in terms of the power law model and logistic equation. Significant changes in the rheological parameters consistency index (K and flow behavior index (n were observed with the fermentation evolution. Interesting correlations between the consistency index (K/biomass concentration (C X and the flow behavior index (n/biomass concentration were proposed. Volumetric oxygen mass transfer coefficient (kLa was determined by the gas balance method. Classical correlation relating the volumetric oxygen mass transfer coefficient to the operating conditions, physical and to transport properties, including apparent viscosity (muap, could be applied to the experimental results.
DEFF Research Database (Denmark)
Grathwohl, Peter; Haberer, Cristina; Ye, Yu
and the dispersion coefficients are the same as below the water table. Water table fluctuations cause temporarily increased fluxes of oxygen into groundwater during draining conditions and entrapped air after water table rise. High-permeability inclusions in the capillary fringe enhance mass transfer of oxygen......Diffusive–dispersive mass transfer in the capillary fringe is important for many groundwater quality issues such as transfer of volatile compounds into (and out of) the groundwater, the supply of oxygen for aerobic degradation of hydrocarbons as well as for precipitation of minerals (e.g. iron...... to the underlying anoxic groundwater by increased dispersion due to flow focusing and by significant air trapping in the coarse material inclusions....
2-D and 3-D Radiation Transfer Models of High-Mass Star Formation
Whitney, Barbara A.; Robitaille, Thomas P.; Indebetouw, Remy; Wood, Kenneth; Bjorkman, J. E.; Denzmore, Pia
2005-01-01
2-D and 3-D radiation transfer models of forming stars generally produce bluer 1-10 micron colors than 1-D models of the same evolutionary state and envelope mass. Therefore, 1-D models of the shortwave radiation will generally estimate a lower envelope mass and later evolutionary state than multidimensional models. 1-D models are probably reasonable for very young sources, or longwave analysis (wavelengths > 100 microns). In our 3-D models of high-mass stars in clumpy molecular clouds, we fi...
Ahn, Sungwoo; Werner, David; Luthy, Richard G
2008-06-01
A three-compartment kinetic partitioning model was employed to assess contaminant mass transfer and intraparticle diffusion in systems comprising dense slurries of polluted soil or aquifer sediment with or without sorbent amendments to sequester polycyclic aromatic hydrocarbons (PAHs). The model was applied to simulate temporal changes in aqueous and particle-bound PAH concentrations comparing different pollution sources (heavy oil or tar sludge) and various sorbent amendments (polyoxymethylene (POM), coke breeze, and activated carbon). For the model evaluation, all the parameters needed were directly measured from a series of experiments, allowing full calibration and verification of model predictions without parameter fitting. The numerical model reproduced two separate laboratory-scale experiments reasonably: PAH uptake in POM beads and PAH uptake by semipermeable membrane devices. PAH mass transfer was then simulated for various scenarios, considering different sorbent doses and mass transfer rates as well as biodegradation. Such model predictions provide a quick assessment tool for identifying mass transfer limitations during washing, stabilization, or bioslurry treatments of polluted soil or sediment in mixed systems. It appears that PAHs would be readily released from materials contaminated by small oil droplets, but not tar decanter sludge. Released PAHs would be sequestered rapidly by activated carbon amendment but to a much lesser extent by coke breeze. If sorbing black carbon is present in the slurries, POM pellets would not be effective as a sequestration amendment. High first-order biodegradation rates in the free aqueous phase, e.g., in the order of 0.001 s(-1) for phenanthrene, would be required to compete effectively with adsorption and mass transfer for strong sorbents.
Energy Technology Data Exchange (ETDEWEB)
Ahn, S.; Werner, D.; Luthy, R.G. [Stanford University, Stanford, CA (United States). Dept. for Civil & Environmental Engineering
2008-06-15
A three-compartment kinetic partitioning model was employed to assess contaminant mass transfer and intraparticle diffusion in systems comprising dense slurries of polluted soil or aquifer sediment with or without sorbent amendments to sequester polycyclic aromatic hydrocarbons (PAHs). The model was applied to simulate temporal changes in aqueous and particle-bound PAH concentrations comparing different pollution sources (heavy oil or tar sludge) and various sorbent amendments (polyoxymethylene (POM), coke breeze, and activated carbon). For the model evaluation, all the parameters needed were directly measured from a series of experiments, allowing full calibration and verification of model predictions without parameter fitting. The numerical model reproduced two separate laboratory-scale experiments reasonably: PAH uptake in POM beads and PAH uptake by semipermeable membrane devices. PAH mass transfer was then simulated for various scenarios, considering different sorbent doses and mass transfer rates as well as biodegradation. Such model predictions provide a quick assessment tool for identifying mass transfer limitations during washing, stabilization, or bioslurry treatments of polluted soil or sediment in mixed systems. It appears that PAHs would be readily released from materials contaminated by small oil droplets, but not tar decanter sludge. Released PAHs would be sequestered rapidly by activated carbon amendment but to a much lesser extent by coke breeze. If sorbing black carbon is present in the slurries, POM pellets would not be effective as a sequestration amendment. High first-order biodegradation rates in the free aqueous phase, e.g., in the order of 0.001 s{sup -1} for phenanthrene, would be required to compete effectively with adsorption and mass transfer for strong sorbents.
Opitz, Armin W; Czymmek, Kirk J; Wickstrom, Eric; Wagner, Norman J
2013-02-01
Targeted delivery of imaging agents to cells can be optimized with the understanding of uptake and efflux rates. Cellular uptake of macromolecules is studied frequently with fluorescent probes. We hypothesized that the internalization and efflux of fluorescently labeled macromolecules into and out of mammalian cells could be quantified by confocal microscopy to determine the rate of uptake and efflux, from which the mass transfer coefficient is calculated. The cellular influx and efflux of a third generation poly(amido amine) (PAMAM) dendrimer labeled with an Alexa Fluor 555 dye was measured in Capan-1 pancreatic cancer cells using confocal fluorescence microscopy. The Capan-1 cells were also labeled with 5-chloromethylfluorescein diacetate (CMFDA) green cell tracker dye to delineate cellular boundaries. A dilution curve of the fluorescently labeled PAMAM dendrimer enabled quantification of the concentration of dendrimer in the cell. A simple mass transfer model described the uptake and efflux behavior of the PAMAM dendrimer. The effective mass transfer coefficient was found to be 0.054±0.043μm/min, which corresponds to a rate constant of 0.035±0.023min(-1) for uptake of the PAMAM dendrimer into the Capan-1 cells. The effective mass transfer coefficient was shown to predict the efflux behavior of the PAMAM dendrimer from the cell if the fraction of labeled dendrimer undergoing non-specific binding is accounted for. This work introduces a novel method to quantify the mass transfer behavior of fluorescently labeled macromolecules into mammalian cells. Copyright © 2012 Elsevier B.V. All rights reserved.
Analysis of mass transfer characteristics in a tubular membrane using CFD modeling.
Yang, Jixiang; Vedantam, Sreepriya; Spanjers, Henri; Nopens, Ingmar; van Lier, Jules B
2012-10-01
In contrast to the large amount of research into aerobic membrane bioreactors, little work has been reported on anaerobic membrane bioreactors (AMBRs). As to the application of membrane bioreactors, membrane fouling is a key issue. Membrane fouling generally occurs more seriously in AMBRs than in aerobic membrane bioreactors. However, membrane fouling could be managed through the application of suitable shear stress that can be introduced by the application of a two-phase flow. When the two-phase flow is applied in AMBRs, little is known about the mass transfer characteristics, which is of particular importance, in tubular membranes of AMBRs. In our present work, we have employed fluid dynamic modeling to analyze the mass transfer characteristics in the tubular membrane of a side stream AMBR in which, gas-lift two-phase flow was applied. The modeling indicated that the mass transfer capacity at the membrane surface at the noses of gas bubbles was higher than the mass transfer capacity at the tails of the bubbles, which is in contrast to the results when water instead of sludge is applied. At the given mass transfer rate, the filterability of the sludge was found to have a strong influence on the transmembrane pressure at a steady flux. In addition, the model also showed that the shear stress in the internal space of the tubular membrane was mainly around 20 Pa but could be as high as about 40 Pa due to gas bubble movements. Nonetheless, at these shear stresses a stable particle size distribution was found for sludge particles. Copyright © 2012 Elsevier Ltd. All rights reserved.
Liquid-liquid Slug Flow in a Microchannel Reactor and its Mass Transfer Properties - A Review
Directory of Open Access Journals (Sweden)
Rahul Antony
2014-10-01
Full Text Available Mass transfer is a basic phenomenon behind many processes like reaction, absorption, extraction etc. Mass transfer plays a significant role in microfluidic systems where the chemical / biological process systems are shrinkened down to a micro scale. Micro reactor system, with its high compatibility and performance, gains a wide interest among the researchers in the recent years. Micro structured reac-tors holds advantages over the conventional types in chemical processes. The significance of micro re-actor not limited to its scalability but to energy efficiency, on-site / on-demand production, reliability, safety, highly controlled outputs, etc. Liquid-liquid two phase reaction in a microreactor system is highly demandable when both reactants are liquids or when air medium cannot be suitable. This arti-cle overviews various liquid-liquid flow regimes in a microchannel. Discussions on the hydrodynamics of flow in micro scale are made. Considering the importance of mass transfer in liquid-liquid systems and the advantage of slug regime over other regimes, the article focuses especially on the mass trans-fer between two liquid phases in slug flow and the details of experimental studies carried out in this area. The advantages of slug flow over other flow regimes in micro structured reactor applications are showcased. © 2014 BCREC UNDIP. All rights reservedReceived: 31st May 2014; Revised: 6th August 2014; Accepted: 14th August 2014How to Cite: Antony, R., Giri Nandagopal, M.S., Sreekumar, N., Rangabhashiyam, S., Selvaraju, N. (2014. Liquid-liquid Slug Flow in a Microchannel Reactor and its Mass Transfer Properties - A Review. Bulletin of Chemical Reaction Engineering & Catalysis,9(3: 207-223. (doi:10.9767/bcrec.9.3.6977.207-223Permalink/DOI: http://dx.doi.org/10.9767/bcrec.9.3.6977.207-223
Mass transfer during sulfuric acid concentration by evaporation into the air flow
Directory of Open Access Journals (Sweden)
V. K. Lukashov
2016-12-01
Full Text Available This article shows the results of the study of mass transfer under periodic concentration of sulfuric acid by evaporation inthe gas flow, neutral with respect to the components of acid.Used mathematical model for mass transferbases on the proposed simplified physical representations.This model has allowed to construct an algorithm for calculation the coefficient of mass transfer from the liquid phase into the gas flow. The algorithm uses the experimental data of change the amount of acid and concentration of the water taken from the laboratory tests. Time-based Nusselt diffusion criterion represent the results of the study at different modes of the evaporation process.It has been found that the character of the influence of temperature and initial acid concentration on Nusselt diffusion criterion depends on the variation range of the mass fraction of water in the acid.It is shown that these dependences are well approximated by an exponential function from the dimensionless parameters of the process. This allows usingthem for calculation the mass transfer coefficient into the gas phase in a batch process of concentrating in the range of investigated modes.
Bibliography on augmentation of convective heat and mass transfer-II
Energy Technology Data Exchange (ETDEWEB)
Bergles, A.E.; Nirmalan, V.; Junkhan, G.H.; Webb, R.L.
1983-12-01
Heat transfer augmentation has developed into a major specialty area in heat transfer research and development. This report presents and updated bibliography of world literature on augmentation. The literature is classified into passive augmentation techniques, which require no external power, and active techniques, which do require external power. The fifteen techniques are grouped in terms of their applications to the various modes of heat transfer. Mass transfer is included for completeness. Key words are included with each citation for technique/mode identification. The total number of publications cited is 3045, including 135 surveys of various techniques and 86 papers on performance evaluation of passive techniques. Patents are not included, as they are the subject of a separate bibliographic report.
Netcher, Andrea C; Duranceau, Steven J
2016-03-01
In surface water treatment, ultrafiltration (UF) membranes are widely used because of their ability to supply safe drinking water. Although UF membranes produce high-quality water, their efficiency is limited by fouling. Improving UF filtrate productivity is economically desirable and has been attempted by incorporating sustainable biofiltration processes as pretreatment to UF with varying success. The availability of models that can be applied to describe the effectiveness of biofiltration on membrane mass transfer are lacking. In this work, UF water productivity was empirically modeled as a function of biofilter feed water quality using either a quadratic or Gaussian relationship. UF membrane mass transfer variability was found to be governed by the dimensionless mass ratio between the alkalinity (ALK) and dissolved organic carbon (DOC). UF membrane productivity was optimized when the biofilter feed water ALK to DOC ratio fell between 10 and 14. Copyright © 2015 Elsevier Ltd. All rights reserved.
Directory of Open Access Journals (Sweden)
Younsi Ramdane
2015-01-01
Full Text Available In the present paper, three-dimensional equations for coupled heat and mass conservation equations for wood are solved to study the transient heat and mass transfer during high thermal treatment of wood. The model is based on Luikov’s approach, including pressure. The model equations are solved numerically by the commercial package FEMLfor the temperature and moisture content histories under different treatment conditions. The simulation of the proposed conjugate problem allows the assessment of the effect of the heat and mass transfer within wood. A parametric study was also carried out to determine the effects of several parameters such as initial moisture content and the sample thickness on the temperature, pressure and moisture content distributions within the samples during heat treatment.
Heat and mass transfer correlations for liquid droplet of a pure fuel in combustion
Energy Technology Data Exchange (ETDEWEB)
Dgheim, J.; Chesneau, X.; Pietri, L.; Zeghmati, B. [Groupe de Mecanique Acoustique et Instrumentation, Centre d' Etudes Fondamentales UPRES EA 2986, Universite de Perpignan (France)
2002-08-01
The authors report a numerical analysis of heat and mass transfers, which govern the combustion of a fuel droplet assimilated to a sphere. The results are presented in the form of temperature, mass-fraction, Nusselt and Sherwood number profiles. The following heat and mass transfers correlations are developed: Nu =1.31.Gr {sub T}{sup 0.26}.Pr{sup 0.33}; Sh=1.484.Gr{sub M}{sup 0.25}.Sc{sup 0.155}, which account for the effects of natural convection and the physical properties of the gas phase. These correlations agree with the results of detailed numerical analysis as well as the experimental data involving a single droplet. (orig.)
The influence of surface treatment on mass transfer between air and building material
DEFF Research Database (Denmark)
Kwiatkowski, Jerzy; Rode, Carsten; Hansen, Kurt Kielsgaard
2008-01-01
The processes of mass transfer between air and building structure and in the material influence not only the conditions within the material but also inside the connected air spaces. The material which absorbs and desorbs water vapour can be used to moderate the amplitude of indoor relative humidity...... and therefore to participate in the improvement of the indoor air quality and energy saving. Many parameters influence water vapour exchange between indoor air and building material. The aim of this work is to present the change of mass transfer under different climatic and material conditions. The measurements...... for the experiments: gypsum board and calcium silicate. The wallpaper and paint were used as finishing materials. Impact of the following parameters for changes of RH was studied: coating, temperature and air movement. The measurements showed that acryl paint (diffusion open) can significantly decrease mass uptake...
Briët, Olivier J T; Penny, Melissa A; Hardy, Diggory; Awolola, Taiwo S; Van Bortel, Wim; Corbel, Vincent; Dabiré, Roch K; Etang, Josiane; Koudou, Benjamin G; Tungu, Patrick K; Chitnis, Nakul
2013-02-25
The effectiveness of insecticide-treated nets in preventing malaria is threatened by developing resistance against pyrethroids. Little is known about how strongly this affects the effectiveness of vector control programmes. Data from experimental hut studies on the effects of long-lasting, insecticidal nets (LLINs) on nine anopheline mosquito populations, with varying levels of mortality in World Health Organization susceptibility tests, were used to parameterize malaria models. Both simple static models predicting population-level insecticidal effectiveness and protection against blood feeding, and complex dynamic epidemiological models, where LLINs decayed over time, were used. The epidemiological models, implemented in OpenMalaria, were employed to study the impact of a single mass distribution of LLINs on malaria, both in terms of episodes prevented during the effective lifetime of the batch of LLINs, and in terms of net health benefits (NHB) expressed in disability-adjusted life years (DALYs) averted during that period, depending on net type (standard pyrethroid-only LLIN or pyrethroid-piperonyl butoxide combination LLIN), resistance status, coverage and pre-intervention transmission level. There were strong positive correlations between insecticide susceptibility status and predicted population level insecticidal effectiveness of and protection against blood feeding by LLIN intervention programmes. With the most resistant mosquito population, the LLIN mass distribution averted up to about 40% fewer episodes and DALYs during the effective lifetime of the batch than with fully susceptible populations. However, cost effectiveness of LLINs was more sensitive to the pre-intervention transmission level and coverage than to susceptibility status. For four out of the six Anopheles gambiae sensu lato populations where direct comparisons between standard LLINs and combination LLINs were possible, combination nets were more cost effective, despite being more expensive
Jiao, Qingbin; Bayanheshig; Tan, Xin; Zhu, Jiwei
2014-03-01
Mass transfer coefficient is an important parameter in the process of mass transfer. It can reflect the degree of enhancement of mass transfer process in liquid-solid reaction and in non-reactive systems like dissolution and leaching, and further verify the issues by experiments in the reaction process. In the present paper, a new computational model quantitatively solving ultrasonic enhancement on mass transfer coefficient in liquid-solid reaction is established, and the mass transfer coefficient on silicon surface with a transducer at frequencies of 40 kHz, 60 kHz, 80 kHz and 100 kHz has been numerically simulated. The simulation results indicate that mass transfer coefficient increases with the increasing of ultrasound power, and the maximum value of mass transfer coefficient is 1.467 × 10(-4) m/s at 60 kHz and the minimum is 1.310 × 10(-4) m/s at 80 kHz in the condition when ultrasound power is 50 W (the mass transfer coefficient is 2.384 × 10(-5) m/s without ultrasound). The extrinsic factors such as temperature and transducer diameter and distance between reactor and ultrasound source also influence the mass transfer coefficient on silicon surface. Mass transfer coefficient increases with the increasing temperature, with the decreasing distance between silicon and central position, with the decreasing of transducer diameter, and with the decreasing of distance between reactor and ultrasound source at the same ultrasonic power and frequency. The simulation results indicate that the computational model can quantitatively solve the ultrasonic enhancement on mass transfer coefficient. Copyright © 2013 Elsevier B.V. All rights reserved.
Briët, Olivier JT; Chitnis, Nakul
2013-01-01
Background The effectiveness of long-lasting, insecticidal nets (LLINs) in preventing malaria is threatened by the changing biting behaviour of mosquitoes, from nocturnal and endophagic to crepuscular and exophagic, and by their increasing resistance to insecticides. Methods Using epidemiological stochastic simulation models, we studied the impact of a mass LLIN distribution on Plasmodium falciparum malaria. Specifically, we looked at impact in terms of episodes prevented during the effective...
Energy Technology Data Exchange (ETDEWEB)
Önder, Asim; Meyers, Johan, E-mail: johan.meyers@mech.kuleuven.be [Department of Mechanical Engineering, KU Leuven, Celestijnenlaan 300A, B3001 Leuven (Belgium)
2014-07-15
We study the near field of a zero-net-mass-flux (ZNMF) actuated round jet using direct numerical simulations. The Reynolds number of the jet Re{sub D} = 2000 and three ZNMF actuators are used, evenly distributed over a circle, and directed towards the main jet. The actuators are triggered in phase, and have a relatively low momentum coefficient of C{sub μ} = 0.0049 each. We study four different control frequencies with Strouhal numbers ranging from St{sub D} = 0.165 to St{sub D} = 1.32; next to that, also two uncontrolled baseline cases are included in the study. We find that this type of ZNMF actuation leads to strong deformations of the near-field jet region that are very similar to those observed for non-circular jets. At the end of the jet's potential core (x/D = 5), the jet-column cross section is deformed into a hexagram-like geometry that results from strong modifications of the vortex structures. Two mechanisms lead to these modifications, i.e., (i) self-deformation of the jet's primary vortex rings started by distortions in their azimuthal curvature by the actuation, and (ii) production of side jets by the development and subsequent detachment of secondary streamwise vortex pairs. Further downstream (x/D = 10), the jet transforms into a triangular pattern, as the sharp corner regions of the hexagram entrain fluid and spread. We further investigate the global characteristics of the actuated jets. In particular when using the jet preferred frequency, i.e., St{sub D} = 0.33, parameters such as entrainment, centerline decay rate, and mean turbulent kinetic energy are significantly increased. Furthermore, high frequency actuation, i.e., St{sub D} = 1.32, is found to suppress the mechanisms leading to large scale structure growth and turbulent kinetic energy production. The simulations further include a passive scalar equation, and passive scalar mixing is also quantified and visualized.
de Godos, I; Mendoza, J L; Acién, F G; Molina, E; Banks, C J; Heaven, S; Rogalla, F
2014-02-01
Mass transfer of CO2 from flue gas was quantified in a 100m(2) raceway. The carbonation sump was operated with and without a baffle at different liquid/gas ratios, with the latter having the greatest influence on CO2 recovery from the flue gas. A rate of mass transfer sufficient to meet the demands of an actively growing algal culture was best achieved by maintaining pH at ∼8. Full optimisation of the process required both pH control and selection of the best liquid/gas flow ratio. A carbon transfer rate of 10gCmin(-1) supporting an algal productivity of 17gm(-2)day(-1) was achieved with only 4% direct loss of CO2 in the sump. 66% of the carbon was incorporated into biomass, while 6% was lost by outgassing and the remainder as dissolved carbon in the liquid phase. Use of a sump baffle required additional power without significantly improving carbon mass transfer. Copyright © 2013 Elsevier Ltd. All rights reserved.
2013-01-01
In this study, a miniature stirred tank bioreactor was designed for treatment of waste gas containing benzene, toluene and xylene. Oxygen mass transfer characteristics for various twin and single-impeller systems were investigated for 6 configurations in a vessel with 10 cm of inner diameter and working volume of 1.77L. Three types of impellers, namely, Rushton turbine, Pitched 4blades and Pitched 2blades impellers with downward pumping have been used. Deionized water was used as a liquid phase. With respect to other independent variables such as agitation speed, aeration rate, type of sparger, number of impellers, the relative performance of these impellers was assessed by comparing the values of (KLa) as a key parameter. Based on the experimental data, empirical correlations as a function of the operational conditions have been proposed, to study the oxygen transfer rates from air bubbles generated in the bioreactor. It was shown that twin Rushton turbine configuration demonstrates superior performance (23% to 77% enhancement in KLa) compared with other impeller compositions and that sparger type has negligible effect on oxygen mass transfer rate. Agitation speeds of 400 to 800 rpm were the most efficient speeds for oxygen mass transfer in the stirred bioreactor. PMID:23369581
Directory of Open Access Journals (Sweden)
Ali Karimi
2013-01-01
Full Text Available In this study, a miniature stirred tank bioreactor was designed for treatment of waste gas containing benzene, toluene and xylene. Oxygen mass transfer characteristics for various twin and single-impeller systems were investigated for 6 configurations in a vessel with 10 cm of inner diameter and working volume of 1.77L. Three types of impellers, namely, Rushton turbine, Pitched 4blades and Pitched 2blades impellers with downward pumping have been used. Deionized water was used as a liquid phase. With respect to other independent variables such as agitation speed, aeration rate, type of sparger, number of impellers, the relative performance of these impellers was assessed by comparing the values of (KLa as a key parameter. Based on the experimental data, empirical correlations as a function of the operational conditions have been proposed, to study the oxygen transfer rates from air bubbles generated in the bioreactor. It was shown that twin Rushton turbine configuration demonstrates superior performance (23% to 77% enhancement in KLa compared with other impeller compositions and that sparger type has negligible effect on oxygen mass transfer rate. Agitation speeds of 400 to 800 rpm were the most efficient speeds for oxygen mass transfer in the stirred bioreactor.
Kato, Hideki
2014-07-01
Photon mass energy transfer coefficient is an essential factor when converting photon energy fluence into kinetic energy released per unit mass (kerma). Although mass attenuation coefficient and mass energy absorption coefficients can be looked up in databases, the mass energy transfer coefficient values are still controversial. In this paper, the photon mass energy transfer coefficients for elements Z=1-92 were calculated based on cross-sectional data for each photon interaction type. Mass energy transfer coefficients for 48 compounds and/or mixtures of dosimetric interest were calculated from coefficient data for elements using Bragg's additivity rule. We additionally developed software that can search these coefficient data for any element or substance of dosimetric interest. The database and software created in this paper should prove useful for radiation measurements and/or dose calculations.
Mass transfer in cataclysmic variables - Clues from the dwarf nova period distribution
Shafter, A. W.; Wheeler, J. C.; Cannizzo, J. K.
1986-01-01
Evidence is presented in support of the hypothesis that the mean mass-transfer rate at a given orbital period is not continuous across the 2-3 hr gap in the orbital period distribution for cataclysmic variables. It is pointed out that although dwarf novae comprise nearly half (48 percent) of all disk systems with orbital periods less than 10 hr, only three systems out of the 22 with periods between 3 and 4 hr appear to be dwarf novae. The overall orbital period distribution for dwarf novae in conjunction with the predictions from current theories of dwarf nova eruptions are used to argue that mass-transfer rates must be generally higher for systems with orbital periods greater than 3 hr relative to systems with periods less than 2 hr. It is further argued that the mean mass-transfer rate at a given orbital period cannot increase more steeply than P exp 1.7 unless the white dwarf mass is positively correlated with orbital period.
Interferometric study on the mass transfer in cryogenic distillation under magnetic field
Bao, S. R.; Zhang, R. P.; Y Rong, Y.; Zhi, X. Q.; Qiu, L. M.
2017-12-01
Cryogenic distillation has long been used for the mass production of industrial gases because of its features of high efficiency, high purity, and capability to produce noble gases. It is of great theoretical and practical significance to explore methods to improve the mass transfer efficiency in cryogenic distillation. The negative correlation between the susceptibility of paramagnetic oxygen and temperature provides a new possibility of comprehensive utilization of boiling point and susceptibility differences in cryogenic distillation. Starting from this concept, we proposed a novel distillation intensifying method by using gradient magnetic field, in which the magnetic forces enhance the transport of the oxygen molecules to the liquid phase in the distillation. In this study, a cryogenic testbed was designed and fabricated to study the diffusion between oxygen and nitrogen under magnetic field. A Mach-Zehnder interferometer was used to visualize the concentration distribution during the diffusion process. The mass transfer characteristics with and without magnetic field, in the chamber filled with the magnetized medium, were systematically studied. The concentration redistribution of oxygen was observed, and the stable stratified diffusion between liquid oxygen and nitrogen was prolonged by the non-uniform magnetic field. The experimental results show that the magnetic field can efficiently influence the mass transfer in cryogenic distillation, which can provide a new mechanism for the optimization of air separation process.
Mass transfer in electromembrane extraction--The link between theory and experiments.
Huang, Chuixiu; Jensen, Henrik; Seip, Knut Fredrik; Gjelstad, Astrid; Pedersen-Bjergaard, Stig
2016-01-01
Electromembrane extraction was introduced in 2006 as a totally new sample preparation concept for the extraction of charged analytes present in aqueous samples. Electromembrane extraction is based on electrokinetic migration of the analytes through a supported liquid membrane and into a μL-volume of acceptor solution under the influence of an external electrical field. To date, electromembrane extraction has mostly been used for the extraction of drug substances, amino acids, and peptides from biological fluids, and for organic micropollutants from environmental samples. Electromembrane extraction has typically been combined with chromatography, mass spectrometry, and electrophoresis for analyte separation and detection. At the moment, close to 125 research papers have been published with focus on electromembrane extraction. Electromembrane extraction is a hybrid technique between electrophoresis and liquid-liquid extraction, and the fundamental principles for mass transfer have only partly been investigated. Thus, although there is great interest in electromembrane extraction, the fundamental principle for mass transfer has to be described in more detail for the scientific acceptance of the concept. This review summarizes recent efforts to describe the fundamentals of mass transfer in electromembrane extraction, and aim to give an up-to-date understanding of the processes involved. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Numerical study of heat and mass transfer during evaporation of a thin liquid film
Directory of Open Access Journals (Sweden)
Oubella M’hand
2015-01-01
Full Text Available A numerical study of mixed convection heat and mass transfer with film evaporation in a vertical channel is developed. The emphasis is focused on the effects of vaporization of three different liquid films having widely different properties, along the isothermal and wetted walls on the heat and mass transfer rates in the channel. The induced laminar downward flow is a mixture of blowing dry air and vapour of water, methanol or acetone, assumed as ideal gases. A two-dimensional steady state and elliptical flow model, connected with variable thermo-physical properties, is used and the phase change problem is based on thin liquid film assumptions. The governing equations of the model are solved by a finite volume method and the velocity-pressure fields are linked by SIMPLE algorithm. The numerical results, including the velocity, temperature and concentration profiles, as well as axial variations of Nusselt numbers, Sherwood number and dimensionless film evaporation rate are presented for two values of inlet temperature and Reynolds number. It was found that lower the inlet temperature and Re, the higher the induced flows cooling with respect of most volatile film. The better mass transfer rates related with film evaporation are found for a system with low mass diffusion coefficient.
Mass Transfer Coefficientin Stirred Tank for p-Cresol Extraction Process from Coal Tar
Fardhyanti, D. S.; Tyaningsih, D. S.; Afifah, S. N.
2017-04-01
Indonesia is a country that has a lot of coal resources. The Indonesian coal has a low caloric value. Pyrolysis is one of the process to increase the caloric value. One of the by-product of the pyrolysis process is coal tar. It contains a lot of aliphatic or aromatic compounds such asp-cresol (11% v/v). It is widely used as a disinfectant. Extractionof p-Cresol increases the economic value of waste of coal. The aim of this research isto study about mass tranfer coefficient in the baffled stirred tank for p-Cresolextraction from coal tar. Mass transfer coefficient is useful for design and scale up of industrial equipment. Extraction is conducted inthe baffled stirred tank equipped with a four-bladed axial impeller placed vertically in the vessel. Sample for each time processing (5, 10, 15, 20, 25 and 30minutes) was poured into a separating funnel, settled for an hour and separated into two phases. Then the two phases were weighed. The extract phases and raffinate phases were analyzed by Spectronic UV-Vis. The result showed that mixing speed of p-Cresol extraction increasesthe yield of p-Cresol and the mass transfer coefficient. The highest yield of p-Cresol is 49.32% and the highest mass transfer coefficient is 4.757 x 10-6kg/m2s.
Pressure drop and mass transfer in two-pass ribbed channels
Chandra, P. R.; Han, J. C.
1989-01-01
The combined effects of the sharp 180-deg turn and of the rib configuration on the pressure drop and mass transfer characteristics in a two-pass square channel with a pair of opposite rib-roughened walls (to simulate turbine airfoil cooling passages) were determined for a Reynolds number range of 10,000-60,000. Heat transfer enhancements were compared for the first pass and for the two-pass channel with the sharp 180-deg turn. Correlations for the fully-developed friction factors and loss coefficients were obtained.
DEFF Research Database (Denmark)
Feyissa, Aberham Hailu; Gernaey, Krist; Adler-Nissen, Jens
2012-01-01
Similar to other processes, the modelling of heat and mass transfer during food processing involves uncertainty in the values of input parameters (heat and mass transfer coefficients, evaporation rate parameters, thermo-physical properties, initial and boundary conditions) which leads to uncertai...
DEFF Research Database (Denmark)
Gilbert, Dorthea; Jakobsen, Hans H.; Winding, Anne
2014-01-01
as sink and source for polycyclic aromatic hydrocarbons (PAHs). This resulted in stable concentration gradients in water (>24 h). Adding the model organism Tetrahymena pyriformis to the experimental system enhanced PAH mass transfer up to hundred-fold (benzo[a]pyrene). Increasing mass transfer enhancement...
Mass transfer equation for proteins in very high-pressure liquid chromatography.
Gritti, Fabrice; Guiochon, Georges
2009-04-01
The mass transfer kinetics of human insulin was investigated on a 50 mm x 2.1 mm column packed with 1.7 microm BEH-C(18) particles, eluted with a water/acetonitrile/trifluoroacetic acid (TFA) (68/32/0.1, v/v/v) solution. The different contributions to the mass transfer kinetics, e.g., those of longitudinal diffusion, eddy dispersion, the film mass transfer resistance, cross-particle diffusivity, adsorption-desorption kinetics, and transcolumn differential sorption, were incorporated into a general mass transfer equation designed to account for the mass transfer kinetics of proteins under high pressure. More specifically, this equation includes the effects of pore size exclusion, pressure, and temperature on the band broadening of a protein. The flow rate was first increased from 0.001 to 0.250 mL/min, the pressure drop increasing from 2 to 298 bar, and the column being placed in stagnant air at 296.5 K, in order to determine the effective diffusivity of insulin through the porous particles, the mass transfer rate constants, and the adsorption equilibrium constant in the low-pressure range. Then, the column inlet pressure was increased by using capillary flow restrictors downstream the column, at the constant flow rate of 0.03 mL/min. The column temperature was kept uniform by immersing the column in a circulating water bath thermostatted at 298.7 and 323.15 K, successively. The results showed that the surface diffusion coefficient of insulin decreases faster than its bulk diffusion coefficient with increasing average column pressure. This is consistent with the adsorption energy of insulin onto the BEH-C(18) surface increasing strongly with increasing pressure. In contrast, given the precision of the height equivalent to a theoretical plate (HETP) measurement (+/-12%), the adsorption kinetics of insulin appears to be rather independent of the pressure. On average, the adsorption rate constant of insulin is doubled from about 40 to 80 s(-1) when the temperature
Directory of Open Access Journals (Sweden)
Zhixian Huang
Full Text Available Abstract To investigate the mass transfer behavior of a liquid-liquid system with high density difference (∆ρ≈500 kg/m3, single drop experiments were performed by using the ternary chloroform-ethanol-water system. The mass transfer direction was from the dispersed phase to the continuous phase, while the aqueous phase was dispersed in chloroform to generate drops. The influences of drop diameter, initial solute concentration and temperature on the mass transfer were investigated. The effects of the drop diameter and initial solute concentration on interfacial instability of droplets hanging in the continuous phase were also observed. For the purpose of correlation, a mass transfer enhancement factor F was introduced and then correlated as a function of dimensionless variables. The modified correlation from the mass transfer coefficient model was found to fit well with the experimental values.
Takano, Tsuyoshi; Yamagata, Takayuki; Ito, Akihiro; Fujisawa, Nobuyuki
A pipe-wall thinning phenomenon behind an orifice in a circular pipe is studied by measuring the mass transfer using the naphthalene sublimation method. An attention is placed on an asymmetric increase of local mass transfer behind the orifice, which is combined with the influence of swirling flow and the orifice bias. The present results indicate that the mass transfer is generally increased with an increase in swirl intensity. However, it becomes asymmetric by the combined effect of the orifice bias for the bias larger than 0.4% of the pipe diameter and the swirl intensity larger than approximately 0.2. The enhanced mass transfer is found on the shorter orifice side behind a biased orifice, and the maximum mass transfer is increased 40% in comparison with the case without swirl and orifice bias.
DEFF Research Database (Denmark)
Rong, Li; Nielsen, Peter V.; Zhang, Guoqiang
2010-01-01
to investigate the surface concentration distribution and mass transfer coefficient at different temperatures and velocities for which the Reynolds number is from 1.36 × 104 to 5.43 × 104 (based on wind tunnel length). The surface concentration increases as velocity decreases and varies...... greatly along the airflow direction on the emission surface. The average mass transfer coefficient increases with higher velocity and turbulence intensity. However, the mass transfer coefficient estimated by CFD simulation is consistently larger than the calculated one by the method using dissociation...... constant and Henry's constant models. In addition, the results show that the liquid-air temperature difference has little impact on the simulated mass transfer coefficient by CFD modeling, whereas the mass transfer coefficient increases with higher liquid temperature using the other method under...
Rong, Li; Nielsen, Peter V; Zhang, Guoqiang
2010-04-01
This paper reports the results of an investigation, based on fundamental fluid dynamics and mass transfer theory, carried out to obtain a general understanding of ammonia mass transfer from an emission surface. The effects of airflow and aqueous ammonium solution temperature on ammonia mass transfer are investigated by using computational fluid dynamics (CFD) modeling and by a mechanism modeling using dissociation constant and Henry's constant models based on the parameters measured in the experiments performed in a wind tunnel. The validated CFD model by experimental data is used to investigate the surface concentration distribution and mass transfer coefficient at different temperatures and velocities for which the Reynolds number is from 1.36 x 10(4) to 5.43 x 10(4) (based on wind tunnel length). The surface concentration increases as velocity decreases and varies greatly along the airflow direction on the emission surface. The average mass transfer coefficient increases with higher velocity and turbulence intensity. However, the mass transfer coefficient estimated by CFD simulation is consistently larger than the calculated one by the method using dissociation constant and Henry's constant models. In addition, the results show that the liquid-air temperature difference has little impact on the simulated mass transfer coefficient by CFD modeling, whereas the mass transfer coefficient increases with higher liquid temperature using the other method under the conditions that the liquid temperature is lower than the air temperature. Although there are differences of mass transfer coefficients between these two methods, the mass transfer coefficients determined by these two methods are significantly related.
Mass transfer from a sphere in an oscillating flow with zero mean velocity
Drummond, Colin K.; Lyman, Frederic A.
1990-01-01
A pseudospectral numerical method is used for the solution of the Navier-Stokes and mass transport equations for a sphere in a sinusoidally oscillating flow with zero mean velocity. The flow is assumed laminar and axisymmetric about the sphere's polar axis. Oscillating flow results were obtained for Reynolds numbers (based on the free-stream oscillatory flow amplitude) between 1 and 150, and Strouhal numbers between 1 and 1000. Sherwood numbers were computed and their dependency on the flow frequency and amplitude discussed. An assessment of the validity of the quasi-steady assumption for mass transfer is based on these results.
Kharkov, N. S.
2017-11-01
Results of numerical modeling of the coupled nonstationary heat and mass transfer problem under conditions of a convective flow in facade system of a three-layer concrete panel for two different constructions (with ventilation channels and without) are presented. The positive effect of ventilation channels on the energy and humidity regime over a period of 12 months is shown. Used new method of replacement a solid zone (requiring specification of porosity and material structure, what complicates process of convergence of the solution) on quasi-solid in form of a multicomponent mixture (with restrictions on convection and mass fractions).
Heat Transfer and Mass Diffusion in Nanofluids over a Moving Permeable Convective Surface
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Muhammad Qasim
2013-01-01
Full Text Available Heat transfer and mass diffusion in nanofluid over a permeable moving surface are investigated. The surface exhibits convective boundary conditions and constant mass diffusion. Effects of Brownian motion and thermophoresis are considered. The resulting partial differential equations are reduced into coupled nonlinear ordinary differential equations using suitable transformations. Shooting technique is implemented for the numerical solution. Velocity, temperature, and concentration profiles are analyzed for different key parameters entering into the problem. Performed comparative study shows an excellent agreement with the previous analysis.
Simultaneous heat and mass transfer in packed bed brying of seeds having a mucilage coating
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M. M. Prado
2008-03-01
Full Text Available The simultaneous heat and mass transfer between fluid phase and seeds having a mucilaginous coating was studied during packed bed drying. To describe the process, a two-phase model approach was employed, in which the effects of bed shrinkage and nonconstant physical properties were considered. The model took into account bed contraction by employing moving coordinates. Equations relating shrinkage and structural parameters of the packed bed with moisture content, required in the drying model, were developed from experimental results in thick-layer bed drying. The model verification was based on a comparison between experimental and predicted data on moisture content and temperature along the bed. Parametric studies showed that the application of correlations capable of incorporating changes in bed properties gives better data simulation. By experimental-theoretical analysis, the importance of shrinkage for a more accurate interpretation of heat and mass transfer phenomena in the drying of porous media composed of mucilaginous seeds is corroborated.
Analysis of Heat-and-Mass Transfer Conjugated Problem Solution while Forming Thin-Wall Castings
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R. I. Еsman
2009-01-01
Full Text Available The paper contains an analysis of heat-and-mass transfer conjugated problem in case of moving of liquid melts in channels of metallic forms (moulds, dies, crystallizers etc.. Investigations of velocity profiles at various flow sections, current lines in the calculated area, pressure and viscosity fields in non-stationary state have been carried out in the paper.The paper reveals that current is of parabolic shape in the annular channel at rather large distance from a projection up and down the flow and pressure along channel section is practically unchangeable.The executed investigations of heat-and-mass transfer in the moving melt make it possible to create a data base of control parameters for development of prospective technologies of special casting methods.
Noreen, S.; Hayat, T.; Alsaedi, A.; Qasim, M.
2013-09-01
A mathematical model is constructed to investigate the mixed convective heat and mass transfer effects on peristaltic flow of magnetohydrodynamic pseudoplastic fluid in a symmetric channel. An analysis has been carried out to examine the impact of an inclined magnetic field and chemical reaction in presence of heat sink/source. Mechanics of flow and heat/mass transfer described in terms of continuity, linear momentum, energy and concentration equations are predicted by using long wavelength and low Reynolds number. Expressions for stream function, temperature, concentration and pressure gradient are derived. Numerical simulation is performed for the rise in pressure per wave length. Effects of several physical parameters on the flow quantities are analyzed.
The mass transfer rate in X1916-053 - It is driven by gravitational radiation?
Swank, J. H.; Taam, R. E.; White, N. E.
1985-01-01
A 50-minute period for a binary system harboring an X-ray burster would allow several alternatives for the mass-giving secondary, including an H-shell burning-plus-He degenerate core composite model. The burst properties of X1916-053 are presently used to argue against the He degenerate as well as the He main sequence solutions and to estimate whether, for any of the other solutions, the mass transfer rate could be consistent with that expected from gravitational radiation (GR). Within an uncertainty of a factor of 2, the transfer rate for the composite model solution is consistent with gravitational radiation, but enhancement by other mechanisms should be investigated.
Enzyme mass-transfer coefficient in aqueous two-phase systems using static mixer extraction column.
Rostami, K; Alamshahi, M
2002-09-01
Recent technical advances in aqueous two-phase systems (ATPS) have made this a sound technique for the extraction of biomacromolecules. The extraction of alpha-amylase was investigated using aqueous two-phase systems formed by sodium sulphate-polyethylene glycol (PEG) in water in a 47-mm inner diameter spray column packed with three types of static mixers. The effects of dispersed-phase flow rate, phase composition, column height and diameter were studied. The extraction column was operated in a semi-batch manner. It was found that the hold-up and volumetric mass transfer coefficients increased with an increase in dispersed (PEG-rich) phase velocity and decreased with increasing phase composition. Empirical correlations were developed for fractional dispersed-phase hold-up and volumetric mass transfer coefficients.
SOLAR ABSORBING COOLING SYSTEMS BASED ON MULTISTAGE HEAT-MASS-TRANSFER DEVICES
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Doroshenko A.V.
2014-08-01
Full Text Available The article presents the worked out schematics for the alternative refrigeration systems and of air-conditioning systems, based on the use of absorbing cycle and of the sunny energy for the regeneration (renewals of absorbent solution. We use here the cascade principle of construction of all heat-mass-transfer apparatus with variation of both the temperature level and the growth of absorbent concentration on the cascade stages. The heat-mass-transfer equipment as a part of the drying and cooling units is standardized and is executed by means of multistage monoblock compositions from poly-meric materials. The preliminary analysis of possibilities of the sunny systems in application to the tasks of cooling of environment and air-conditioning systems is carried out.
Dong, Zhengya; Yao, Chaoqun; Zhang, Xiaoli; Xu, Jie; Chen, Guangwen; Zhao, Yuchao; Yuan, Quan
2015-02-21
The combination of ultrasound and microreactor is an emerging and promising area, but the report of designing high-power ultrasonic microreactor (USMR) is still limited. This work presents a robust, high-power and highly efficient USMR by directly coupling a microreactor plate with a Langevin-type transducer. The USMR is designed as a longitudinal half wavelength resonator, for which the antinode plane of the highest sound intensity is located at the microreactor. According to one dimension design theory, numerical simulation and impedance analysis, a USMR with a maximum power of 100 W and a resonance frequency of 20 kHz was built. The strong and uniform sound field in the USMR was then applied to intensify gas-liquid mass transfer of slug flow in a microfluidic channel. Non-inertial cavitation with multiple surface wave oscillation was excited on the slug bubbles, enhancing the overall mass transfer coefficient by 3.3-5.7 times.
Energy Technology Data Exchange (ETDEWEB)
Jeon, Seung Won; Lee, Kyn Jung; Cho, Yeon Hwa [Korea Univ., Seoul (Korea, Republic of); Moon, Dong Ju [Korea Institute of Science and Technology, Seoul (Korea, Republic of)
2012-09-15
A numerical study of a microchannel steam methane reforming reactor has been performed to understand the characteristics of heat and mass transfer. The integration of Rh catalyzed steam methane reforming and Pt catalyzed methane combustion has been simulated. The reaction rates for chemical reactions have been incorporated into the simulation. This study investigated the effect of contact time, flow pattern (parallel of counter), and channel size on the reforming performance and temperature distribution. The parallel and counter flow have opposite temperature distribution, and they show a different type of reaction rate and species mole fraction. As the contact time decreases and channel size increases, mass transfer between the catalyst layer and the flow is limited, and the reforming performance is decreased.
Analysis of heat and mass transfer during microwave drying of food products
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A. K. Haghi
2008-09-01
Full Text Available Microwave (MW drying is a rapid dehydration technique that can be applied to specific foods. Increasing concerns over product quality and production costs have motivated the researchers to investigate and the industry to adopt microwave drying technology. The advantages of microwave drying include the following: shorter drying time, improved product quality, and flexibility in producing a wide variety of dried products. Drying is influenced by heat and mass transfer between drying airflow and product, as well as the complex moisture transport processes which take place in the product.. This paper presents an analytical approach for the drying of potato. The laws of moisture content change in the food product as a function of mass transfer are used for the theoretical approach. The study gives a brief description of efforts made to obtain basic drying parameters under different microwave drying conditions. This computational method can be used as a tool for microwave drying of potato slabs more efficiency.
Mass transfer and microbiological profile of pork meat dehydrated in two different osmotic solutions
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Plavšić Dragana V.
2012-01-01
Full Text Available The effects of osmotic dehydration on mass transfer properties and microbiological profile were investigated in order to determine the usefulness of this technique as pre-treatment for further treatment of meat. Process was studied in two solutions (sugar beet molasses, and aqueous solution of sodium chloride and sucrose, at two temperatures (4 and 22°C at atmospheric pressure. The most significant parameters of mass transfer were determined after 300 minutes of the dehydration. The water activity (aw values of the processed meat were determined, as well as the change of the microbiological profile between the fresh and dehydrated meat. At the temperature of 22°C the sugar beet molasses proved to be most suitable as an osmotic solution, despite the greater viscosity.
Mass transfer and power characteristics of stirred tank with Rushton and curved blade impeller
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Thiyam Tamphasana Devi
2017-04-01
Full Text Available Present work compares the mass transfer coefficient (kLa and power draw capability of stirred tank employed with Rushton and curved blade impeller using computational fluid dynamics (CFD techniques in single and double impeller cases. Comparative analysis for different boundary conditions and mass transfer model has been done to assess their suitability. The predicted local kLa has been found higher in curved blade impeller than the Rushton impeller, whereas stirred tank with double impeller does not show variation due to low superficial gas velocity. The global kLa predicted has been found higher in curved blade impeller than the Rushton impeller in double and single cases. Curved blade impeller also exhibits higher power draw capability than the Rushton impeller. Overall, stirred tank with curved blade impeller gives higher efficiency in both single and double cases than the Rushton turbine
Investigation of CO2 dissolution via mass transfer inside a porous medium
Patmonoaji, Anindityo; Suekane, Tetsuya
2017-12-01
The dissolution of trapped carbon dioxide (CO2) gas under various water flow rate inside a porous medium was experimentally studied using X-ray microtomography. Image processing techniques were used to determine the morphologies, CO2 fractions, and interfacial areas of the trapped bubbles. Based on fractal dimension analysis, the bubble morphology was classified into single-pore bubbles and multi-pore bubbles. Different dissolution phenomena with liquid-liquid systems were observed. First, the calculated mass transfer coefficient was lower than one order of magnitude. Second, two consecutive dissolution fronts appeared. These two fronts were not triggered by a difference in solute concentration because they occurred at CO2 concentrations far from saturated conditions. However, velocity-dependent mass transfer indicated a power function with a power value similar with liquid-liquid system dissolution experiment.
A general real-time formulation for multi-rate mass transfer problems
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O. Silva
2009-08-01
Full Text Available Many flow and transport phenomena, ranging from delayed storage in pumping tests to tailing in river or aquifer tracer breakthrough curves or slow kinetics in reactive transport, display non-equilibrium (NE behavior. These phenomena are usually modeled by non-local in time formulations, such as multi-porosity, multiple processes non equilibrium, continuous time random walk, memory functions, integro-differential equations, fractional derivatives or multi-rate mass transfer (MRMT, among others. We present a MRMT formulation that can be used to represent all these models of non equilibrium. The formulation can be extended to non-linear phenomena. Here, we develop an algorithm for linear mass transfer, which is accurate, computationally inexpensive and easy to implement in existing groundwater or river flow and transport codes. We illustrate this approach by application to published data involving NE groundwater flow and solute transport in rivers and aquifers.
Unit operations for gas-liquid mass transfer in reduced gravity environments
Pettit, Donald R.; Allen, David T.
1992-01-01
Basic scaling rules are derived for converting Earth-based designs of mass transfer equipment into designs for a reduced gravity environment. Three types of gas-liquid mass transfer operations are considered: bubble columns, spray towers, and packed columns. Application of the scaling rules reveals that the height of a bubble column in lunar- and Mars-based operations would be lower than terrestrial designs by factors of 0.64 and 0.79 respectively. The reduced gravity columns would have greater cross-sectional areas, however, by factors of 2.4 and 1.6 for lunar and Martian settings. Similar results were obtained for spray towers. In contract, packed column height was found to be nearly independent of gravity.
Gas-liquid mass transfer coefficient of methane in bubble column reactor
Energy Technology Data Exchange (ETDEWEB)
Lee, Jaewon; Ha, Kyoung-Su; Lee, Jinwon; Kim, Choongik [Sogang University, Seoul (Korea, Republic of); Yasin, Muhammad; Park, Shinyoung; Chang, In Seop [Gwangju Institute of Science and Technology (GIST), Gwangju (Korea, Republic of); Lee, Eun Yeol [Kyung Hee University, Yongin (Korea, Republic of)
2015-06-15
Biological conversion of methane gas has been attracting considerable recent interest. However, methanotropic bioreactor is limited by low solubility of methane gas in aqueous solution. Although a large mass transfer coefficient of methane in water could possibly overcome this limitation, no dissolved methane probe in aqueous environment is commercially available. We have developed a reactor enabling the measurement of aqueous phase methane concentration and mass transfer coefficient (k{sub L}a). The feasibility of the new reactor was demonstrated by measuring k{sub L}a values as a function of spinning rate of impeller and flow rate of methane gas. Especially, at spinning rate of 300 rpm and flow rate of 3.0 L/min, a large k{sub L}a value of 102.9 h{sup -1} was obtained.
Heat and Mass Transfer in a Falling Film Evaporator with Aqueous Lithium Bromide Solution
Olbricht, M.; Addy, J.; Luke, A.
2016-09-01
Horizontal tube bundles are often used as falling film evaporators in absorption chillers, especially for systems working at low pressure as H2O/LiBr. Experimental investigations are carried out in a falling film evaporator consisting of a horizontal tube bundle with eighty horizontal tubes installed in an absorption chiller because of a lack of consistent data for heat and mass transfer in the literature. The heat and mass transfer mechanisms and the flow pattern in the falling film are analysed and compared with correlations from literature. The deviations of the experimental data from those of the correlations are within a tolerance of 30%. These deviations may be explained by a change of the flow pattern at a lower Reynolds number than compared to the literature.
In situ global method for measurement of oxygen demand and mass transfer
Energy Technology Data Exchange (ETDEWEB)
Klasson, K.T. [Oak Ridge National Lab., TN (United States). Chemical Technology Div.; Lundbaeck, K.M.O.; Clausen, E.C.; Gaddy, J.L. [Univ. of Arkansas, Fayetteville, AR (United States). Dept. of Chemical Engineering
1997-05-01
Two aerobic microorganisms, Saccharomycopsis lipolytica and Brevibacterium lactofermentum, have been used in a study of mass transfer and oxygen uptake from a global perspective using a closed gas system. Oxygen concentrations in the gas and liquid were followed using oxygen electrodes, and the results allowed for easy calculation of in situ oxygen transport. The cell yields on oxygen for S. lipolytica and B. lactofermentum were 1.01 and 1.53 g/g respectively. The mass transfer coefficient was estimated as 10 h{sup {minus}1} at 500 rpm for both fermentations. The advantages with this method are noticeable since the use of model systems may be avoided, and the in situ measurements of oxygen demand assure reliable data for scale-up.
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C.S.K. Raju
2016-03-01
Full Text Available In this study we analyzed the flow, heat and mass transfer behavior of Casson fluid past an exponentially permeable stretching surface in presence of thermal radiation, magneticfield, viscous dissipation, heat source and chemical reaction. We presented dual solutions by comparing the results of the Casson fluid with the Newtonian fluid. The governing partial nonlinear differential equations of the flow, heat and mass transfer are transformed into ordinary differential equations by using similarity transformation and solved numerically by using Matlab bvp4c package. The effects of various non-dimensional governing parameters on velocity, temperature and concentration profiles are discussed and presented graphically. Also, the friction factor, Nusselt and Sherwood numbers are analyzed and presented in tabular form for both Casson and Newtonian fluids separately. Under some special conditions the results of the present study have an excellent agreement with existing studies for both Casson and Newtonian fluid cases.
Mass transfer of Disperse Red 153 and its crude dye in supercritical CO2 fluid
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Zheng Huan-Da
2017-01-01
Full Text Available In this paper, polyester fibers were dyed with Disperse Red 153 and its crude dye in supercritical CO2. The effect of dyeing temperature, dyeing time, dyeing pressure, as well as auxiliaries in the commercialized Disperse Red 153 on the dyeing performance of polyester fibers was investigated. The obtained results showed that the dyeing effect of crude dye for polyester was better than that of Disperse Red 153 in the same dyeing condition. The color strength values of the dyed polyester samples were increased gradually with the increase of temperature and pressure since mass transfer of dye was improved. In addition, the mass transfer model of Disperse Red 153 in supercritical CO2 was also proposed.
A simplified kinetic and mass transfer modelling of the thermal hydrolysis of vegetable oils
DEFF Research Database (Denmark)
Forero-Hernandez, Hector Alexander; Jones, Mark Nicholas; Sarup, Bent
2017-01-01
This work presents a combined modelling approach to investigate the kinetics and masstransfer effects on the hydrolysis of vegetable oils under subcritical conditions. The primary purpose of this simplified model is to interpret experimental data collected from typical batch tests and to estimate...... parameters for the proposed model. Due to its heterogeneous nature, the hydrolysis reaction is affected not only by the chemical kinetics but also by the rate of mass transfer between the oil and water as well as their specific contact area in this two phase emulsion. Considering these properties, a model...... was developed and evaluated by comparing the results with experimental data from literature. The model included among others the mass transfer coefficient as a function of operation and process variables, e.g. agitation speed, temperature, pressure, density and viscosity. Thereafter, uncertainty analysis...
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Rosinski Stefan
2003-01-01
Full Text Available On the long way to clinical transplantable hybrid systems, comprising of cells, acting as immuno-protected bioreactors microencapsulated in a polymeric matrix and delivering desired factors (proteins, hormones, enzymes etc to the patient's body, an important step is the optimization of the microcapsule. This topic includes the selection of a proper coating membrane which could fulfil, first of all, the mass transfer as well as biocompatibility, stability and durability requirements. Three different membranes from polymerised aminoacids, formed around exactly identical alginate gel cores, were considered, concerning their mass transport properties, as potential candidates in this task. The results of the evaluation of the mass ingress and mass transfer coefficient h for the selected low molecular mass marker, vitamin B12, in poly-L-lysine (HPLL poly-L-ornithine (HPLO and poly-methylene-co-guanidine hydrochloride (HPMCG membrane alginate microcapsules demonstrate the advantage of using the mass transfer approach to a preliminary screening of various microcapsule formulations. Applying a single marker and evaluating mass transfer coefficients can help to quickly rank the investigated membranes and microcapsules according to their permeability. It has been demonstrated that HPLL, HPLO and HPMCG microcapsules differ from each other by a factor of two concerning the rate of low molecular mass marker transport. Interesting differences in mass transfer through the membrane in both directions in-out was also found, which could possibly be related to the membrane asymmetry.
Study on Electrohydrodynamic Rayleigh-Taylor Instability with Heat and Mass Transfer
Awasthi, Mukesh Kumar; Srivastava, Vineet K.
2014-01-01
The linear analysis of Rayleigh-Taylor instability of the interface between two viscous and dielectric fluids in the presence of a tangential electric field has been carried out when there is heat and mass transfer across the interface. In our earlier work, the viscous potential flow analysis of Rayleigh-Taylor instability in presence of tangential electric field was studied. Here, we use another irrotational theory in which the discontinuities in the irrotational tangential velocity and shear stress are eliminated in the global energy balance. Stability criterion is given by critical value of applied electric field as well as critical wave number. Various graphs have been drawn to show the effect of various physical parameters such as electric field, heat transfer coefficient, and vapour fraction on the stability of the system. It has been observed that heat transfer and electric field both have stabilizing effect on the stability of the system. PMID:24526897
Study on Electrohydrodynamic Rayleigh-Taylor Instability with Heat and Mass Transfer
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Mukesh Kumar Awasthi
2014-01-01
Full Text Available The linear analysis of Rayleigh-Taylor instability of the interface between two viscous and dielectric fluids in the presence of a tangential electric field has been carried out when there is heat and mass transfer across the interface. In our earlier work, the viscous potential flow analysis of Rayleigh-Taylor instability in presence of tangential electric field was studied. Here, we use another irrotational theory in which the discontinuities in the irrotational tangential velocity and shear stress are eliminated in the global energy balance. Stability criterion is given by critical value of applied electric field as well as critical wave number. Various graphs have been drawn to show the effect of various physical parameters such as electric field, heat transfer coefficient, and vapour fraction on the stability of the system. It has been observed that heat transfer and electric field both have stabilizing effect on the stability of the system.
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Torres, R. [Escuela de Ingenieria de Antioquia Calle 25 Sur No. 42-73, Envigado (Colombia); Jimenez, Y.; Arnau, A. [Departamento Ingenieria Electronica, ETSI de Telecomunicacion, Universidad Politecnica de Valencia, Camino de Vera s/n, C.P. 46022, Valencia (Spain); Gabrielli, C.; Joiret, S. [CNRS, UPR 15 du CNRS, Laboratoire Interfaces et Systemes Electrochimiques-LISE, 4, place Jussieu, 75005 Paris (France)] [UPMC, Universite Pierre et Marie Curie-Paris 6, Laboratoire Interfaces et Systemes Electrochimiques-LISE, 4, place Jussieu, 75005 Paris (France); Perrot, H., E-mail: hubert.perrot@upmc.f [CNRS, UPR 15 du CNRS, Laboratoire Interfaces et Systemes Electrochimiques-LISE, 4, place Jussieu, 75005 Paris (France)] [UPMC, Universite Pierre et Marie Curie-Paris 6, Laboratoire Interfaces et Systemes Electrochimiques-LISE, 4, place Jussieu, 75005 Paris (France); To, T.K.L.; Wang, X. [CNRS, UPR 15 du CNRS, Laboratoire Interfaces et Systemes Electrochimiques-LISE, 4, place Jussieu, 75005 Paris (France)] [UPMC, Universite Pierre et Marie Curie-Paris 6, Laboratoire Interfaces et Systemes Electrochimiques-LISE, 4, place Jussieu, 75005 Paris (France)
2010-08-30
For many years, polyaniline films have appeared to be one of the most studied conducting polymers. At the same time, ac-electrogravimetry has been used as a powerful technique for different polymer films but in general for slow perturbation rates. Two reasons for that: on the one hand, high frequency mass transfer responses are not expected and on the other hand, the electronic interfaces dedicated for ac-electrogravimetry are not prepared to follow, without distortion, high rate frequency shifts, faster than a few hertz. This paper shows that high ionic transfer responses can be detected by using a new ac-electrogravimetry concept. The experiments conducted with PANI tried to verify whether high frequency responses in conducting polymers are possible or not. The main interest of the new device is to reach the high frequency values directly and to demonstrate an ionic transfer contribution at 1 kHz which was not predicted with old systems.
Torki-Harchegani, Mehdi; Ghanbarian, Davoud; Sadeghi, Morteza
2015-08-01
To design new dryers or improve existing drying equipments, accurate values of mass transfer parameters is of great importance. In this study, an experimental and theoretical investigation of drying whole lemons was carried out. The whole lemons were dried in a convective hot air dryer at different air temperatures (50, 60 and 75 °C) and a constant air velocity (1 m s-1). In theoretical consideration, three moisture transfer models including Dincer and Dost model, Bi- G correlation approach and conventional solution of Fick's second law of diffusion were used to determine moisture transfer parameters and predict dimensionless moisture content curves. The predicted results were then compared with the experimental data and the higher degree of prediction accuracy was achieved by the Dincer and Dost model.
Modulated mass-transfer model for superhumps in SU Ursae Majoris stars
Mineshige, Shin
1988-01-01
The response of a circular accretion disk to rapid modulation of the mass-transfer rate into the disk is explored in order to model superhumps in SU UMa stars. It is proposed that periodically enhanced flow may disrupt or heat up the outer disk and produce the dips noted just before the superhump peaks. The elliptical accretion-disk model with extended vertical disk structure can account for the observed characteristics of superhumps in these stars.
Microscale Enhancement of Heat and Mass Transfer for Hydrogen Energy Storage
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Drost, Kevin [Oregon State Univ., Corvallis, OR (United States); Jovanovic, Goran [Oregon State Univ., Corvallis, OR (United States); Paul, Brian [Oregon State Univ., Corvallis, OR (United States)
2015-09-30
The document summarized the technical progress associated with OSU’s involvement in the Hydrogen Storage Engineering Center of Excellence. OSU focused on the development of microscale enhancement technologies for improving heat and mass transfer in automotive hydrogen storage systems. OSU’s key contributions included the development of an extremely compact microchannel combustion system for discharging hydrogen storage systems and a thermal management system for adsorption based hydrogen storage using microchannel cooling (the Modular Adsorption Tank Insert or MATI).
Identification of mass-transfer coefficient in spatial problem of filtration
Bomba, A. Ya.; Safonyk, A. P.
2014-01-01
A modeling problem of the process of liquid multi component decontamination by a spatial filter is considered, it takes into account the reverse influence of decisive factors (contamination concentrations of liquid and sediment) on characteristics (coefficient of porosity, diffusion) of the medium and gives us the possibility to determine small mass transfer coefficient under the conditions of prevailing of convective constituents over diffusive ones. An algorithm of the solution of the corre...
Wang, Yu-Fu; Levene, Howard B; Gu, Weiyong; Huang, C -Y Charles
2017-06-13
Insufficient nutrient supply has been suggested to be one of the etiologies for intervertebral disc (IVD) degeneration. We are investigating nutrient transport into the IVD as a potential treatment strategy for disc degeneration. Most cellular activities in the IVD (e.g., cell proliferation and extracellular matrix production) are mainly driven by adenosine-5'-triphosphate (ATP) which is the main energy currency. The objective of this study was to investigate the effect of increased mass transfer on ATP production in the IVD by the implantation of polyurethane (PU) mass transfer devices. In this study, the porcine functional spine units were used and divided into intact, device and surgical groups. For the device and surgical groups, two puncture holes were created bilaterally at the dorsal side of the annulus fibrosus (AF) region and the PU mass transfer devices were only implanted into the holes in the device group. Surgical groups were observed for the effects of placing the holes through the AF only. After 7 days of culture, the surgical group exhibited a significant reduction in the compressive stiffness and disc height compared to the intact and device groups, whereas no significant differences were found in compressive stiffness, disc height and cell viability between the intact and device groups. ATP, lactate and the proteoglycan contents in the device group were significantly higher than the intact group. These results indicated that the implantation of the PU mass transfer device can promote the nutrient transport and enhance energy production without compromising mechanical and cellular functions in the disc. These results also suggested that compromise to the AF has a negative impact on the IVD and must be addressed when treatment strategies are considered. The results of this study will help guide the development of potential strategies for disc degeneration.
Enhancing natural product extraction and mass transfer using selective microwave heating
Lee, Chai Siah; Binner, Eleanor; Winkworth-Smith, Charles; John, Rebecca; Gomes, R.L.; Robinson, John
2016-01-01
This study uses a combination of empirical observations and an analysis of mass transfer behaviour to yield new insights into the mechanism of microwave assisted extraction. Enhancements in extraction rate and yield were observed experimentally compared with conventional extraction at temperatures in excess of 50°C, however at lower temperatures there was no observable difference between the two processes. A step-change in extract yield between microwave and conventional processes was shown t...
Experimental study of convective coefficient of mass transfer of avocado (Persia americana Mill.)
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Alves, Suerda Bezerra; Luiz, Marcia Ramos; Amorim, Joselma Araujo de; Gusmao, Rennam Pereira de; Gurgel, Jose Mauricio [Universidade Federal da Paraiba (LES/UFPB), Joao Pessoa, PB (Brazil). Lab. de Energia Solar
2010-07-01
Most of all energy consumed worldwide comes from fossil fuels derived from petroleum. With the petroleum crisis in the 70 were sought new energy sources, among them renewable. One such source is biodiesel energy, organic matter originated from animal and/or vegetable. Among the various plant species is the avocado (Persia americana Mill.) showing great potential in the production of petroleum extracted from the pulp and the alcohol removed from the seed. The main obstacle for obtaining the petroleum is the high humidity found in the pulp, being necessary to the drying process, which involves the transfer of heat and mass. The aim of this study was to use the mathematical model represented by Newton's Law of Cooling to simulate the mass transfer on the surface of the avocado pulp during the drying process. The equation of the mathematical model was solved numerically and the method of least squares was identified convective coefficient of Mass Transfer. The dryer used in the experimental process was operated with air flow in the vertical, air flow average fixed 3m/s and temperatures of 50, 60 and 70 deg C. The scheme of the dryer used in the research is composed of the following equipment: centrifugal fan, which drives the air-drying; valve, which allows control of airflow; electrical resistance, used for heating air; the drying chamber, where enables measurement of temperature and relative humidity; support for smaller trays; trays smaller, where the samples of the pulp of the avocado are placed; exit of the air of drying for the environment. The result presented shows the ratio of moisture content as a function of temperature over time, where it is possible to also observe that how much bigger the temperature of drying, greater will be the convective coefficient of mass transfer of the avocado. (author)
Leithner Reinhard; Askarova Aliya; Bolegenova Saltanat; Bolegenova Symbat; Maximov Valeriy; Ospanova Shinar; Ergalieva Aigul; Nugymanova Aizhan; Beketayeva Meruyert
2016-01-01
In this paper the results obtained by the method of numerical modelling of Ekibastuz coal burning in furnace of Kazakhstan Power Plant. Numerical experiment was carried out on the basis of three-dimensional equations of convective heat and mass transfer, taking into account the heat propagation, heat radiation, chemical reactions and multiphase structure of the medium to predict the influence of different water content in coal on overall furnace operation and formation of combustion products.
Directory of Open Access Journals (Sweden)
Leithner Reinhard
2016-01-01
Full Text Available In this paper the results obtained by the method of numerical modelling of Ekibastuz coal burning in furnace of Kazakhstan Power Plant. Numerical experiment was carried out on the basis of three-dimensional equations of convective heat and mass transfer, taking into account the heat propagation, heat radiation, chemical reactions and multiphase structure of the medium to predict the influence of different water content in coal on overall furnace operation and formation of combustion products.
Simulating gas-liquid mass transfer in a spin filter bioreactor
Niño López, Lilibeth Caridad; Gelves Zambrano, Germán Ricardo
2015-01-01
Computational fluid dynamics (CFD) and population balance model (PBM) model have been used to simulate hydrodynamics and mass transfer in a 0.014 m3 Spin Filter Bioreactor. The operating conditions chosen were defined by typical settings used for culturing plant cells. Turbulence, rotating flow, bubbles breakage and coalescence were simulated by using the k-e, MRF (Multiple Reference Frame) and PBM approaches, respectively. The numerical results from different operational conditions are compa...
Page 1 Phase coefficients for heat and mass transfer 33 The type of ...
Indian Academy of Sciences (India)
(Nu), – 0.000123 (Re);” (Pr)?”, (11) . (Sh), - 0.0001.23 (Re);” (Sc)?”. (12). The combined data showed an average deviation of +12.77% with a maximum deviation of 26.51%. It is also to be noted that the sample mass transfer data of. Handlos & Baron (1957), Garner & Hale (1955) and Coulson & Skinner (1952) when. Pro.
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M. B. Akgül
2012-01-01
Full Text Available Hydromagnetic flow and mass transfer of a viscous incompressible fluid over a microcantilever sensor surface are studied in the presence of slip flow. In addition, chemical reaction at the sensor surface is taken into account. The governing equations for the flow are reduced to a local nonsimilarity form. Resulting equations are solved numerically for various values of flow parameters. Effects of physical quantities on the velocity and concentration profiles are discussed in detail.
Galaction, Anca-Irina; Cascaval, Dan; Turnea, Marius; Folescu, Elena
2005-07-01
The previous works on simulated broths are continued and developed for Propionibacterium shermanii broths. The obtained results indicated the considerable increase of kLa in presence of n-dodecane as oxygen-vector and the existence of a certain value of hydrocarbon concentration that corresponds to the maximum mass transfer rate of oxygen. The magnitude of the positive effect of the oxygen-vector strongly depends on operational conditions of the bioreactor, on broth characteristics and on P. shermanii concentration.
Investigation of the Mass Transfer Parameters of Caffeine Extraction in a Packed Column
Mehmet BİLGİN; HASDEMİR, İ. Metin; Aydin, Ahmet; Umur DRAMUR
1998-01-01
In this study, the mass transfer parameters were investigated in the liquid extraction process, which is the main step of producing caffeine from tea residue, in a packed brosilicate glass column, 5.86 cm in diameter, 132 cm in height, filled by 10x10 mm glass Raschig rings. Because chloroform was used as a solvent in the extraction process, the equilibrium distribution of the water-caffeine-chloroform ternary system were determined at room temperature. By using various solvent/raffi...
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Kristi Christensen; Veronica Rutledge; Troy Garn
2011-09-01
In support of the Nuclear Energy Advanced Modeling Simulation Safeguards and Separations (NEAMS SafeSep) program, the Idaho National Laboratory (INL) worked in collaboration with Los Alamos National Laboratory (LANL) to further a modeling effort designed to predict mass transfer behavior for selected metal species between individual dispersed drops and a continuous phase in a two phase liquid-liquid extraction (LLE) system. The purpose of the model is to understand the fundamental processes of mass transfer that occur at the drop interface. This fundamental understanding can be extended to support modeling of larger LLE equipment such as mixer settlers, pulse columns, and centrifugal contactors. The work performed at the INL involved gathering the necessary experimental data to support the modeling effort. A custom experimental apparatus was designed and built for performing drop contact experiments to measure mass transfer coefficients as a function of contact time. A high speed digital camera was used in conjunction with the apparatus to measure size, shape, and velocity of the drops. In addition to drop data, the physical properties of the experimental fluids were measured to be used as input data for the model. Physical properties measurements included density, viscosity, surface tension and interfacial tension. Additionally, self diffusion coefficients for the selected metal species in each experimental solution were measured, and the distribution coefficient for the metal partitioning between phases was determined. At the completion of this work, the INL has determined the mass transfer coefficient and a velocity profile for drops rising by buoyancy through a continuous medium under a specific set of experimental conditions. Additionally, a complete set of experimentally determined fluid properties has been obtained. All data will be provided to LANL to support the modeling effort.
Effect of partial wetting on liquid/solid mass transfer in trickle bed reactors
Baussaron, Loïc; Julcour-Lebigue, Carine; Boyer, Christophe; Wilhelm, Anne-Marie; Delmas, Henri
2007-01-01
The wetting efficiency of liquid trickle flow over a fixed bed reactor has been measured for a wide range of parameters including operating conditions, bed structure and physico-chemistry of liquid/solid phases. This data bank has been used to develop a new correlation for averaged wetting efficiency based on five different non-dimensional numbers. Finally liquid/solid mass transfer has been determined in partial wetting conditions to analyse what are the respective effects of wetting and ...
Mass transfer from a circular cylinder: Effects of flow unsteadiness and slight nonuniformities
Marziale, M. L.; Mayle, R. E.
1984-01-01
Experiments were performed to determine the effect of periodic variations in the angle of the flow incident to a turbine blade on its leading edge heat load. To model this situation, measurements were made on a circular cylinder oscillating rotationally in a uniform steady flow. A naphthalene mass transfer technique was developed and used in the experiments and heat transfer rates are inferred from the results. The investigation consisted of two parts. In the first, a stationary cylinder was used and the transfer rate was measured for Re = 75,000 to 110,000 and turbulence levels from .34 percent to 4.9 percent. Comparisons with both theory and the results of others demonstrate that the accuracy and repeatability of the developed mass transfer technique is about + or - 2 percent, a large improvement over similar methods. In the second part identical flow conditions were used but the cylinder was oscillated. A Strouhal number range from .0071 to .1406 was covered. Comparisons of the unsteady and steady results indicate that the magnitude of the effect of oscillation is small and dependent on the incident turbulence conditions.
Heat and Mass Transfer Remote Control in Bioreactors of Technological Lines
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Viktorija M. Mel’nick
2017-10-01
Full Text Available Background. The main problems that arise when using equipment for cultivation are to ensure the heat and mass transfer processes in devices, presence of turbulent and stagnant zones, high-energy consumption, low heat transfer coefficients when working with viscous fluids. Objective. The aim of the paper is the experimental determination of the remote control heat transfer advantages in production line bioreactors using ultrasonic beam compared to contact methods. Methods. An experimental study of the heat and mass transfer process in a bioreactor on the stand with UZP-6-1 immersion unit of the ultrasonic radiator with radiation frequency 42 kHz is carried out. Results. Sound waves emitted into a liquid form a concentration zone of passable sound energy in the confocal vessel form of a cylindrical surface and force the liquid to move along the inner surface of the glass along the ascending cylindrical spiral, forming a motive flow throughout the volume, causing peripheral layers of liquid and bottom layers to move in a horizontal and vertical planes, without leaving stagnant zones. The closer to the coincidence angle is the directed ultrasonic beam the greater is the effectiveness of the driving flow. Conclusions. The use of sound waves allows obtaining a high-quality product in technological lines based on bioreactors with minimal risk for the technological process. Radiation parameters and working volume physic-mechanical properties change allow fully using the properties of resonant manifestations of the sound wave influence on the working liquid with minimal costs.
Method and system for simulating heat and mass transfer in cooling towers
Bharathan, Desikan; Hassani, A. Vahab
1997-01-01
The present invention is a system and method for simulating the performance of a cooling tower. More precisely, the simulator of the present invention predicts values related to the heat and mass transfer from a liquid (e.g., water) to a gas (e.g., air) when provided with input data related to a cooling tower design. In particular, the simulator accepts input data regarding: (a) cooling tower site environmental characteristics; (b) cooling tower operational characteristics; and (c) geometric characteristics of the packing used to increase the surface area within the cooling tower upon which the heat and mass transfer interactions occur. In providing such performance predictions, the simulator performs computations related to the physics of heat and mass transfer within the packing. Thus, instead of relying solely on trial and error wherein various packing geometries are tested during construction of the cooling tower, the packing geometries for a proposed cooling tower can be simulated for use in selecting a desired packing geometry for the cooling tower.
Model of Mass and Heat Transfer during Vacuum Freeze-Drying for Cornea
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Zou Huifen
2012-01-01
Full Text Available Cornea is the important apparatus of organism, which has complex cell structure. Heat and mass transfer and thermal parameters during vacuum freeze-drying of keeping corneal activity are studied. The freeze-drying cornea experiments were operated in the homemade vacuum freeze dryer. Pressure of the freeze-drying box was about 50 Pa and temperature was about −10°C by controlled, and operating like this could guarantee survival ratio of the corneal endothelium over the grafting normal. Theory analyzing of corneal freeze-drying, mathematical model of describing heat and mass transfer during vacuum freeze-drying of cornea was established. The analogy computation for the freeze-drying of cornea was made by using finite-element computational software. When pressure of the freeze-drying box was about 50 Pa and temperature was about −10°C, time of double-side drying was 170 min. In this paper, a moving-grid finite-element method was used. The sublimation interface was tracked continuously. The finite-element mesh is moved continuously such that the interface position always coincides with an element node. Computational precision was guaranteed. The computational results were agreed with the experimental results. It proved that the mathematical model was reasonable. The finite-element software is adapted for calculating the heat and mass transfer of corneal freeze-drying.
Li, Chunqing; Tie, Xiaobo; Liang, Kai; Ji, Chanjuan
2016-01-01
After conducting the intensive research on the distribution of fluid's velocity and biochemical reactions in the membrane bioreactor (MBR), this paper introduces the use of the mass-transfer differential equation to simulate the distribution of the chemical oxygen demand (COD) concentration in MBR membrane pool. The solutions are as follows: first, use computational fluid dynamics to establish a flow control equation model of the fluid in MBR membrane pool; second, calculate this model by adopting direct numerical simulation to get the velocity field of the fluid in membrane pool; third, combine the data of velocity field to establish mass-transfer differential equation model for the concentration field in MBR membrane pool, and use Seidel iteration method to solve the equation model; last but not least, substitute the real factory data into the velocity and concentration field model to calculate simulation results, and use visualization software Tecplot to display the results. Finally by analyzing the nephogram of COD concentration distribution, it can be found that the simulation result conforms the distribution rule of the COD's concentration in real membrane pool, and the mass-transfer phenomenon can be affected by the velocity field of the fluid in membrane pool. The simulation results of this paper have certain reference value for the design optimization of the real MBR system.
Distribution and mass transfer of dissolved oxygen in a multi-habitat membrane bioreactor.
Tang, Bing; Qiu, Bing; Huang, Shaosong; Yang, Kanghua; Bin, Liying; Fu, Fenglian; Yang, Huiwen
2015-04-01
This work investigated the DO distribution and the factors influencing the mass transfer of DO in a multi-habitat membrane bioreactor. Through the continuous measurements of an on-line automatic system, the timely DO values at different zones in the bioreactor were obtained, which gave a detailed description to the distribution of oxygen within the bioreactor. The results indicated that the growth of biomass had an important influence on the distribution of oxygen. As the extension of operational time, the volumetric oxygen mass transfer coefficient (kLa) was generally decreased. With the difference in DO values, a complex environment combining anoxic and oxic state was produced within a single bioreactor, which provided a fundamental guarantee for the total removal of TN. Aeration rate, the concentration and apparent viscosity of MLSS have different influences on kLa, but adjusting the viscosity is a feasible method to improve the mass transfer of oxygen in the bioreactor. Copyright © 2015 Elsevier Ltd. All rights reserved.
Simultaneous heat and mass transfer in absorption of gases in laminar liquid films
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Grossman, G
1982-09-01
A theoretical analysis of the combined heat and mass transfer process taking place in the absorption of a gas or vapor into a laminar liquid film is described. This type of process, which occurs in many gas-liquid systems, often releases only a small amount of heat, making the process almost isothermal. In some cases, however, the heat of absorption is significant and temperature variations cannot be ignored. One example, from which the present study originated, is in absorption heat pumps where mass transfer is produced specifically to generate a temperature change. The model analyzed describes a liquid film that flows over an inclined plane and has its free surface in contact with stagnant vapor. The absorption process at the surface creates nonuniform temperature and concentration profiles in the film, which develop until equilibrium between the liquid and vapor is achieved. The energy and diffusion equations are solved simultaneously to give the temperature and concentration variations at the interface and the wall. Two cases of interest are considered: constant-temperature and adiabatic walls. The Nusselt and Sherwood numbers are expressed in terms of the operating parameters, from which heat and mass transfer coefficients can be determined. The Nusselt and Sherwood numbers are found to depend on the Peclet and Lewis numbers as well as on the equilibrium characteristics of the working materials.
Ultrasound in gas-liquid systems: effects on solubility and mass transfer.
Laugier, F; Andriantsiferana, C; Wilhelm, A M; Delmas, H
2008-09-01
The effect of ultrasound on the pseudo-solubility of nitrogen in water and on gas-liquid mass transfer kinetics has been investigated in an autoclave reactor equipped with a gas induced impeller. In order to use organic liquids and to investigate the effect of pressure, gas-liquid mass transfer coefficient was calculated from the evolution of autoclave pressure during gas absorption to avoid any side-effects of ultrasound on the concentrations measurements. Ultrasound effect on the apparent solubility is very low (below 12%). Conversely ultrasound greatly improves gas-liquid mass transfer, especially below gas induction speed, this improvement being boosted by pressure. In typical conditions of organic synthesis: 323 K, 1100 rpm, 10 bar, k(L).a is multiplied by 11 with ultrasound (20 kHz/62.6 W). The impact of sonication is much higher on gassing out than on gassing in. In the same conditions, this enhancement is at least five times higher for degassing.
Numerical simulation of coupled heat and mass transfer in wood dried at high temperature
Zhu, Zhenggang; Kaliske, Michael
2011-03-01
The mutual effect between heat and mass transfer is investigated for wood dried at high temperature. A numerical model of coupled heat and mass transfer under the effect of the pressure gradient is presented. Based on the macroscopic viewpoint of continuum mechanics, the mathematical model with three independent variables (temperature, moisture content and gas pressure) is constructed. Mass transfer in the pores involves a diffusional flow driven by the gradient of moisture content, convectional flow of gaseous mixture governed by the gradient of gas pressure, the Soret effect and phase change of water. Energy gain or loss due to phase change of water is taken as the heat source. Numerical methods, the finite element method and the finite difference method are used to discretize the spatial and time dimension, respectively. A direct iteration method to solve the nonlinear problem without direct evaluation of the tangential matrix is introduced. The local convergence condition based on the contraction-mapping principle is discussed. The mathematical model is applied to a 3-D wood board dried at high temperature with the Neumann boundary conditions for both temperature and moisture content, and the Dirichlet boundary conditions for gas pressure.
Theoretical approach for enhanced mass transfer effects in-duct flue gas desulfurization processes
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Jozewicz, W. (Acurex Corp., Research Triangle Park, NC (United States). Environmental Systems Div.); Rochelle, G.T. (Texas Univ., Austin, TX (United States). Dept. of Chemical Engineering)
1992-01-29
Removal of sulfur dioxide (SO{sub 2}) from the flue gas of coal- burning power plants can be achieved by duct spray drying using calcium hydroxide (Ca(OH){sub 2}) slurries. A primary objective of this research was to discover the aspects of mass transfer into Ca(OH){sub 2} slurries which limit SO{sub 2} absorption. A bench- scale stirred tank reactor with a flat gas/liquid interface was used to simulate SO{sub 2} absorption in a slurry droplet. The absorption rate of SO{sub 2} from gas concentrations of 500 to 5000 ppm was measured at 55{degrees}C in clear solutions and slurries of Ca(OH){sub 2} up to 1.0 M (7 wt percent). Results are reported in terms of the enhancement factor, {O}. This research will allow prediction of conditions where the absorption of SO{sub 2} in Ca(OH){sub 2} slurries can be enhanced by changes to liquid phase constituents (under which SO{sub 2} absorption is controlled by liquid film mass transfer). Experiments in the stirred tank have shown that SO{sub 2} absorption in a 1.0 M Ca(OH){sub 2} slurry was completely dominated by gas film mass transfer with a large excess of Ca(OH){sub 2} but becomes controlled by liquid film resistance at greater than 50 percent Ca(OH){sub 2} utilization. (VC)
Directory of Open Access Journals (Sweden)
Lulu Wang
2016-01-01
Full Text Available A two-dimensional, single-phase, isothermal, multicomponent, transient model is built to investigate the transport phenomena in unitized regenerative fuel cells (URFCs under the condition of switching from the fuel cell (FC mode to the water electrolysis (WE mode. The model is coupled with an electrochemical reaction. The proton exchange membrane (PEM is selected as the solid electrolyte of the URFC. The work is motivated by the need to elucidate the complex mass transfer and electrochemical process under operation mode switching in order to improve the performance of PEM URFC. A set of governing equations, including conservation of mass, momentum, species, and charge, are considered. These equations are solved by the finite element method. The simulation results indicate the distributions of hydrogen, oxygen, water mass fraction, and electrolyte potential response to the transient phenomena via saltation under operation mode switching. The hydrogen mass fraction gradients are smaller than the oxygen mass fraction gradients. The average mass fractions of the reactants (oxygen and hydrogen and product (water exhibit evident differences between each layer in the steady state of the FC mode. By contrast, the average mass fractions of the reactant (water and products (oxygen and hydrogen exhibit only slight differences between each layer in the steady state of the WE mode. Under either the FC mode or the WE mode, the duration of the transient state is only approximately 0.2 s.
Shah, Nita H.; Shah, Digeshkumar B.; Patel, Dushyantkumar G.
2015-07-01
This study aims at formulating an integrated supplier-buyer inventory model when market demand is variable price-sensitive trapezoidal and the supplier offers a choice between discount in unit price and permissible delay period for settling the accounts due against the purchases made. This type of trade credit is termed as 'net credit'. In this policy, if the buyer pays within offered time M1, then the buyer is entitled for a cash discount; otherwise the full account must be settled by the time M2; where M2 > M1 ⩾ 0. The goal is to determine the optimal selling price, procurement quantity, number of transfers from the supplier to the buyer and payment time to maximise the joint profit per unit time. An algorithm is worked out to obtain the optimal solution. A numerical example is given to validate the proposed model. The managerial insights based on sensitivity analysis are deduced.
U-loop reactor modelling for optimization. Part 2: Mass transfer
Energy Technology Data Exchange (ETDEWEB)
Roende Andersen, B.; Bagterp Joergensen, J.; Bay Joergensen, S.
2005-09-01
The present report is a continuation of Andersen et al. [2005] where the heat loss from the U-loop reactor pilot plant Gas estimated for operation without fermentation. The proposed model described the dependency on circulation velocity, air flow rate and reactor temperature. The model could not describe variations in heat exchanger flow rate. Since the heat exchanger flow rate is actuator for the reactor temperature control during cooling, this dependency is important. The most likely explanation of the mismatch between the model and the experimental values are inadequate calibration of the flow and temperature sensors. The energy balance for the reactor cannot be included in the present model before these sensors have been calibrated. This calibration still awaits. Initially separate mass transfer experiments were planned and a master project is devoted to mass transfer in autumn 2005. Until these experiments are performed, the mass transfer is attempted estimated from a fermentation experiment, but the experiment is not designed for estimating mass transfer. The fermentation experiment studied in this report was delayed till July 2005, consequently only a crude model has been set up. The most reasonable description of the U-loop reactor is obtained by partial differential equations due to the distributed nature of the reactor. However given the limited time that only allowed a crude model to be formulated with a number of well mixed tanks in series. Furthermore the significant pressure variations through the reactor have been ignored. This means that only a rough average value of the mass transfer coefficient can be estimated. This value can be compared at different operating conditions for this U-loop reactor but the value cannot be sensibly compared to other reactor types. Anyway, the crude model does indicate some of the process limitations. The experiment was planned to run under methanol limitation with excess of oxygen and nitrogen. The results from the
Tauris; van Den Heuvel EP; Savonije
2000-02-20
We have performed detailed numerical calculations of the nonconservative evolution of close X-ray binary systems with intermediate-mass (2.0-6.0 M middle dot in circle) donor stars and a 1.3 M middle dot in circle accreting neutron star. We calculated the thermal response of the donor star to mass loss in order to determine its stability and follow the evolution of the mass transfer. Under the assumption of the "isotropic reemission model," we demonstrate that in many cases it is possible for the binary to prevent a spiral-in and survive a highly super-Eddington mass transfer phase (1millisecond pulsars with heavy CO white dwarfs and relatively short orbital periods (3-50 days). However, we conclude that to produce a binary pulsar with a O-Ne-Mg white dwarf or Porb approximately 1 day (e.g., PSR B0655+64) the above scenario does not work, and a spiral-in phase is still considered the most plausible scenario for the formation of such a system.
FEHMN 1.0: Finite element heat and mass transfer code; Revision 1
Energy Technology Data Exchange (ETDEWEB)
Zyvoloski, G.; Dash, Z.; Kelkar, S.
1992-05-01
A computer code is described which can simulate non-isothermal multi-phase multicomponent flow in porous media. It is applicable to natural-state studies of geothermal systems and groundwater flow. The equations of heat and mass transfer for multiphase flow in porous and permeable media are solved sing the finite element method. The permeability and porosity of the medium are allowed to depend on pressure and temperature. The code also has provisions for movable air and water phases and noncoupled tracers; that is, tracer solutions that do not affect the heat and mass transfer solutions. The tracers can be passive or reactive. The code can simulate two-dimensional, two-dimensional radial, or three-dimensional geometries. A summary of the equations in the model and the numerical solution procedure are provided in this report. A user`s guide and sample problems are also included. The FEHMN (Finite Element Heat and Mass Nuclear) code, described in this report, is a version of FEHM (Finite Element Heat and Mass, Zyvoloski et al., 1988) developed for the Yucca Mountain Site Characterization Project (YMP). The main use of FEHMN will be to assist in the understanding of flow fields in the saturated zone below the potential Yucca Mountain repository.
Evaluation of magnetization transfer ratio in ascites and pelvic cystic masses
Energy Technology Data Exchange (ETDEWEB)
Okada, Susumu [Nippon Medical School, Inba, Chiba (Japan). Chiba-Hokuso Hospital; Kato, Tomoyasu; Yamashita, Takashi [and others
1997-12-01
To investigate the feasibility of magnetization transfer contrast (MTC) in characterization of pelvic cystic masses and ascites, in vitro studies were performed. Cystic fluids were taken from operative specimens of ten ovarian cystic masses (five mucinous cystadenomas, one cystadenocarcinoma, two serous cystadenocarcinomas, two clear cell carcinomas) and three non-ovarian pelvic cysts (one paraovarian cyst, one pseudomyxoma peritonei, one pelvic abscess). Samples of ascitic flied were drawn by peritoneal puncture in twenty patients (thirteen with peritonitis carcinomatosa, five with liver dysfunction, two with renal dysfunction). Total protein content in ascitic fluids was measured. Magnetization transfer ratio (MTR) was calculated by the signal intensities under the gradient echo sequence with and without the application of off-resonance pulses. The relative signal intensities (RSI) relative to water in T{sub 1} and T{sub 2} weighted images were obtained using spin echo sequence. There was no correlation between histological type of pelvic mass and MTR and RSI. Good correlation (R{sup 2}=0.761) was obtained between MTR and protein content in ascitic fluids, whereas no correlation was noted between RSI and protein content in ascitic fluids. These results suggest that MTC is not useful in the characterization of pelvic masses but is applicable in the differentiation between exudative ascites and transudative ascites. (author)
Marin, Pricila; Borba, Carlos Eduardo; Módenes, Aparecido Nivaldo; Espinoza-Quiñones, Fernando R; de Oliveira, Silvia Priscila Dias; Kroumov, Alexander Dimitrov
2014-01-01
Reactive blue 5G dye removal in a fixed-bed column packed with Dowex Optipore SD-2 adsorbent was modelled. Three mathematical models were tested in order to determine the limiting step of the mass transfer of the dye adsorption process onto the adsorbent. The mass transfer resistance was considered to be a criterion for the determination of the difference between models. The models contained information about the external, internal, or surface adsorption limiting step. In the model development procedure, two hypotheses were applied to describe the internal mass transfer resistance. First, the mass transfer coefficient constant was considered. Second, the mass transfer coefficient was considered as a function of the dye concentration in the adsorbent. The experimental breakthrough curves were obtained for different particle diameters of the adsorbent, flow rates, and feed dye concentrations in order to evaluate the predictive power of the models. The values of the mass transfer parameters of the mathematical models were estimated by using the downhill simplex optimization method. The results showed that the model that considered internal resistance with a variable mass transfer coefficient was more flexible than the other ones and this model described the dynamics of the adsorption process of the dye in the fixed-bed column better. Hence, this model can be used for optimization and column design purposes for the investigated systems and similar ones.
Study on heat and mass transfer characteristics of humid air-flow in a fin bundle
Energy Technology Data Exchange (ETDEWEB)
Kim, Dong-Hwi [Air-Conditioner Research Laboratory, LG Electronics, Seoul 153-082 (Korea); Koyama, Shigeru; Kuwahara, Ken [Department of Energy and Environmental Engineering, Kyushu University, Kasuga, Fukuoka 816-8580 (Japan); Kwon, Jeong-Tae [Department of Mechanical Engineering, Hoseo University, Asan, Chungnam 336-795 (Korea); Park, Byung-Duck [School of Mechanical and Automotive Engineering, Kyungpook National University, Sangju, Gyeongbuk 742-711 (Korea)
2010-11-15
This paper deals with the heat and mass transfer characteristics of humid air-flow under frosting conditions. A slit fin bundle was used for the simulation of fins of a heat exchanger. The effects of the cooling block temperature, air humidity and air velocity on the frosting characteristics were experimentally investigated. The frosted mass was affected considerably by the cooling block temperature and air humidity. However, the effect of air velocity on it was not so large. The pressure drop was affected remarkably by all experimental parameters in this study. Local heat flux distribution and frost thickness distribution on each fin were predicted from the measured fin temperatures and the mass and energy conservation equations on the frost surface and inside the frost layer. (author)
What is the role of wind mass transfer in the progenitor evolution of Type Ia supernovae?
Abate, Carlo
Type Ia supernovae (SNe Ia) are thermonuclear explosions of carbon-oxygen white dwarfs (WDs) that accrete mass from a binary companion, which can be either a non-degenerate star (a main-sequence star or a giant) or an other WD in a binary merger (single- and double-degenerate scenario, respectively). In population-synthesis studies of SNe Ia the contribution of asymptotic giant branch (AGB) stars to either scenario is marginal. However, most of these studies adopt simplified assumptions to compute the effects of wind mass loss and accretion in binary systems. This work investigates the impact of wind mass transfer on a population of binary stars and discusses the role of AGB stars as progenitors of SNe Ia.
Samala, Ravi K; Chan, Heang-Ping; Hadjiiski, Lubomir; Helvie, Mark A; Wei, Jun; Cha, Kenny
2016-12-01
Develop a computer-aided detection (CAD) system for masses in digital breast tomosynthesis (DBT) volume using a deep convolutional neural network (DCNN) with transfer learning from mammograms. A data set containing 2282 digitized film and digital mammograms and 324 DBT volumes were collected with IRB approval. The mass of interest on the images was marked by an experienced breast radiologist as reference standard. The data set was partitioned into a training set (2282 mammograms with 2461 masses and 230 DBT views with 228 masses) and an independent test set (94 DBT views with 89 masses). For DCNN training, the region of interest (ROI) containing the mass (true positive) was extracted from each image. False positive (FP) ROIs were identified at prescreening by their previously developed CAD systems. After data augmentation, a total of 45 072 mammographic ROIs and 37 450 DBT ROIs were obtained. Data normalization and reduction of non-uniformity in the ROIs across heterogeneous data was achieved using a background correction method applied to each ROI. A DCNN with four convolutional layers and three fully connected (FC) layers was first trained on the mammography data. Jittering and dropout techniques were used to reduce overfitting. After training with the mammographic ROIs, all weights in the first three convolutional layers were frozen, and only the last convolution layer and the FC layers were randomly initialized again and trained using the DBT training ROIs. The authors compared the performances of two CAD systems for mass detection in DBT: one used the DCNN-based approach and the other used their previously developed feature-based approach for FP reduction. The prescreening stage was identical in both systems, passing the same set of mass candidates to the FP reduction stage. For the feature-based CAD system, 3D clustering and active contour method was used for segmentation; morphological, gray level, and texture features were extracted and merged with a
Conjugate heat and mass transfer in the lattice Boltzmann equation method.
Li, Like; Chen, Chen; Mei, Renwei; Klausner, James F
2014-04-01
An interface treatment for conjugate heat and mass transfer in the lattice Boltzmann equation method is proposed based on our previously proposed second-order accurate Dirichlet and Neumann boundary schemes. The continuity of temperature (concentration) and its flux at the interface for heat (mass) transfer is intrinsically satisfied without iterative computations, and the interfacial temperature (concentration) and their fluxes are conveniently obtained from the microscopic distribution functions without finite-difference calculations. The present treatment takes into account the local geometry of the interface so that it can be directly applied to curved interface problems such as conjugate heat and mass transfer in porous media. For straight interfaces or curved interfaces with no tangential gradient, the coupling between the interfacial fluxes along the discrete lattice velocity directions is eliminated and thus the proposed interface schemes can be greatly simplified. Several numerical tests are conducted to verify the applicability and accuracy of the proposed conjugate interface treatment, including (i) steady convection-diffusion in a channel containing two different fluids, (ii) unsteady convection-diffusion in the channel, (iii) steady heat conduction inside a circular domain with two different solid materials, and (iv) unsteady mass transfer from a spherical droplet in an extensional creeping flow. The accuracy and order of convergence of the simulated interior temperature (concentration) field, the interfacial temperature (concentration), and heat (mass) flux are examined in detail and compared with those obtained from the "half-lattice division" treatment in the literature. The present analysis and numerical results show that the half-lattice division scheme is second-order accurate only when the interface is fixed at the center of the lattice links, while the present treatment preserves second-order accuracy for arbitrary link fractions. For curved
Heat and mass transfer from the mantle: heat flow and He-isotope constraints
Directory of Open Access Journals (Sweden)
B. G. Polyak
2005-06-01
Full Text Available Terrestrial heat flow density, q, is inversely correlated with the age, t, of tectono-magmatic activity in the Earth's crust (Polyak and Smirnov, 1966; etc.. «Heat flow-age dependence» indicates unknown temporal heat sources in the interior considered a priori as the mantle-derived diapirs. The validity of this hypothesis is demonstrated by studying the helium isotope ratio, 3He/4He = R, in subsurface fluids. This study discovered the positive correlation between the regionally averaged (background estimations of R- and q-values (Polyak et al., 1979a. Such a correlation manifests itself in both pan-regional scales (Norhtern Eurasia and separate regions, e.g., Japan (Sano et al., 1982, Eger Graben (Polyak et al., 1985 Eastern China rifts (Du, 1992, Southern Italy (Italiano et al., 2000, and elsewhere. The R-q relation indicates a coupled heat and mass transfer from the mantle into the crust. From considerations of heat-mass budget this transfer can be provided by the flux consisting of silicate matter rather than He or other volatiles. This conclusion is confirmed by the correlation between 3He/ 4He and 87Sr/86Sr ratios in the products of the volcanic and hydrothermal activity in Italy (Polyak et al., 1979b; Parello et al., 2000 and other places. Migration of any substance through geotemperature field transports thermal energy accumulated within this substance, i.e. represents heat and mass transfer. Therefore, only the coupled analysis of both material and energy aspects of this transfer makes it possible to characterise the process adequately and to decipher an origin of terrestrial heat flow observed in upper parts of the earth crust. An attempt of such kind is made in this paper.
Sajjadi, Baharak; Asgharzadehahmadi, Seyedali; Asaithambi, Perumal; Raman, Abdul Aziz Abdul; Parthasarathy, Rajarathinam
2017-01-01
This paper aims at investigating the influence of acoustic streaming induced by low-frequency (24kHz) ultrasound irradiation on mass transfer in a two-phase system. The main objective is to discuss the possible mass transfer improvements under ultrasound irradiation. Three analyses were conducted: i) experimental analysis of mass transfer under ultrasound irradiation; ii) comparative analysis between the results of the ultrasound assisted mass transfer with that obtained from mechanically stirring; and iii) computational analysis of the systems using 3D CFD simulation. In the experimental part, the interactive effects of liquid rheological properties, ultrasound power and superficial gas velocity on mass transfer were investigated in two different sonicators. The results were then compared with that of mechanical stirring. In the computational part, the results were illustrated as a function of acoustic streaming behaviour, fluid flow pattern, gas/liquid volume fraction and turbulence in the two-phase system and finally the mass transfer coefficient was specified. It was found that additional turbulence created by ultrasound played the most important role on intensifying the mass transfer phenomena compared to that in stirred vessel. Furthermore, long residence time which depends on geometrical parameters is another key for mass transfer. The results obtained in the present study would help researchers understand the role of ultrasound as an energy source and acoustic streaming as one of the most important of ultrasound waves on intensifying gas-liquid mass transfer in a two-phase system and can be a breakthrough in the design procedure as no similar studies were found in the existing literature. Copyright © 2016. Published by Elsevier B.V.
DEFF Research Database (Denmark)
Zhang, Ge; He, Wenna; Fang, Lei
2013-01-01
The transfer mechanism of volatile organic compounds (VOCs) being trapped inside the various types of adsorbents is usually regarded as mere diffusion. This paper investigated the contribution of convective mass transfer inside the adsorbents used for VOC air-cleaning. The adsorbents are typically...... and cavity would form, approximately, a consecutive parabola. The convective mass transfer inside the adsorbents would have little impact on the axial VOC transfer but could affect the average adsorption rate significantly at high porosities. The Peclet number Pe which is based on the inlet velocity...... error of average adsorption rate of less than 10% as found by this study....
The influence of pH on gas-liquid mass transfer in non-Newtonian fluids
Li Shaobai; Fan Jungeng; Xu Shuang; Li Rundong; Luan Jingde
2017-01-01
In this study, the effect of pH on the mass transfer of oxygen bubble swarms in non-Newtonian fluids was experimentally studied. The volumetric liquid side mass transfer coefficient (kLa), liquid side mass transfer coefficient (kL), and specific interfacial area (a) were investigated. The pH was regulated by the addition of hydrochloric acid and sodium hydroxide (NaOH). It was found that the kLa increased with the gas flow rate increasing and decreased with the apparent viscosity of the liqui...
An inverse gas chromatographic methodology for studying gas-liquid mass transfer.
Paloglou, A; Martakidis, K; Gavril, D
2017-01-13
A novel methodology of reversed flow inverse gas chromatography (RF-IGC) is presented. It permits the simultaneous determination of mass transfer coefficients across the gas liquid interface as well as the respective solubility parameters and thermodynamic functions of dissolution of gases into liquids. The standard deviation of the experimentally determined parameters is estimated for first time, which combined with the successful comparison of the values of the present parameters with other literature ones ascertain the reliability of the methodology. Another novelty of the present work is that the chromatographic sampling of the physicochemical phenomena is done without performing the usual flow reversals procedure. Vinyl chloride monomer's (VCM) interaction with various composition liquid foods: orange juice, milk and olive oil was used as model system. The present transfer rates are controlled by the gas film at lower temperatures, but at higher temperatures the resistances in both films tend to become equal. The found liquid diffusivity values express the total mass transfer from the gas phase into the liquid's bulk and they decrease with rising temperature, as the solubilities of gases in liquids do. Solubility, expressed by Henry's law constant and the mean values of interfacial thickness are of the same order of magnitude to literature ones. From the thermodynamic point of view, VCM dissolution in all liquids is accompanied by significant heat release and it is a slightly non-spontaneous process, near equilibrium, while the entropy change values are negative. Copyright © 2016 Elsevier B.V. All rights reserved.
Ultrasound as an Alternative to Conventional Marination: Acceptability and Mass Transfer
Directory of Open Access Journals (Sweden)
Leopolda González-González
2017-01-01
Full Text Available In this study, the effects of ultrasound- (US- assisted beef marination on consumer perception and the homogeneity of the solute and mass transfer were evaluated. Marinated and US-treated meat samples (40 kHz, 11 W/cm2 for 20, 40, and 60 min, and storing at 4°C for 7 d were evaluated by a group of consumers using a structured 9-point hedonic scale of satisfaction. The preferences were analyzed with XLSTAT-Sensory® software. The analysis was performed in conjunction with an energy-dispersive X-ray spectroscopic study to evaluate the sodium transference. The perception analysis indicated that the use of US-assisted marination did not increase the beef acceptability. The sonicated samples showed a more homogeneous distribution of sodium. However, traditional marination (TM stored for 7 d resulted in greater mass transfer than the US-assisted marination without storage.
Directory of Open Access Journals (Sweden)
P. Otero
2013-05-01
Full Text Available The estimation of sea–air CO2 fluxes is largely dependent on wind speed through the gas transfer velocity parameterization. In this paper, we quantify uncertainties in the estimation of the CO2 uptake in the Bay of Biscay resulting from the use of different sources of wind speed such as three different global reanalysis meteorological models (NCEP/NCAR 1, NCEP/DOE 2 and ERA-Interim, one high-resolution regional forecast model (HIRLAM-AEMet, winds derived under the Cross-Calibrated Multi-Platform (CCMP project, and QuikSCAT winds in combination with some of the most widely used gas transfer velocity parameterizations. Results show that net CO2 flux estimations during an entire seasonal cycle (September 2002–September 2003 may vary by a factor of ~ 3 depending on the selected wind speed product and the gas exchange parameterization, with the highest impact due to the last one. The comparison of satellite- and model-derived winds with observations at buoys advises against the systematic overestimation of NCEP-2 and the underestimation of NCEP-1. In the coastal region, the presence of land and the time resolution are the main constraints of QuikSCAT, which turns CCMP and ERA-Interim in the preferred options.
Energy and momentum analysis of the deployment dynamics of nets in space
Botta, Eleonora M.; Sharf, Inna; Misra, Arun K.
2017-11-01
In this paper, the deployment dynamics of nets in space is investigated through a combination of analysis and numerical simulations. The considered net is deployed by ejecting several corner masses and thanks to momentum and energy transfer from those to the innermost threads of the net. In this study, the net is modeled with a lumped-parameter approach, and assumed to be symmetrical, subject to symmetrical initial conditions, and initially slack. The work-energy and momentum conservation principles are employed to carry out centroidal analysis of the net, by conceptually partitioning the net into a system of corner masses and the net proper and applying the aforementioned principles to the corresponding centers of mass. The analysis provides bounds on the values that the velocity of the center of mass of the corner masses and the velocity of the center of mass of the net proper can individually attain, as well as relationships between these and different energy contributions. The analytical results allow to identify key parameters characterizing the deployment dynamics of nets in space, which include the ratio between the mass of the corner masses and the total mass, the initial linear momentum, and the direction of the initial velocity vectors. Numerical tools are employed to validate and interpret further the analytical observations. Comparison of deployment results with and without initial velocity of the net proper suggests that more complete and lasting deployment can be achieved if the corner masses alone are ejected. A sensitivity study is performed for the key parameters identified from the energy/momentum analysis, and the outcome establishes that more lasting deployment and safer capture (i.e., characterized by higher traveled distance) can be achieved by employing reasonably lightweight corner masses, moderate shooting angles, and low shooting velocities. A comparison with current literature on tether-nets for space debris capture confirms overall
Hydrodynamics, mass transfer, and yeast culture performance of a column bioreactor with ejector.
Prokop, A; Janík, P; Sobotka, M; Krumphanzl, V
1983-04-01
A bubble column fitted with an ejector has been tested for its physical and biological performance. The axial diffusion coefficient of the liquid phase in the presence of electrolytes and ethanol was measured by a stimulus-response technique with subsequent evaluation by means of a diffusion model. In contrast to ordinary bubble columns, the coefficient of axial mixing is inversely dependent on the superficial air velocity. The liquid velocity acts in an opposite direction to the backmixing flow in the column. The measurement of volumetric oxygen transfer coefficient in the presence of electrolytes and ethanol was performed using a dynamic gassing-in method adapted for a column. The data were correlated with the superficial air and liquid velocities, total power input, and power for aeration and mixing; the economy coefficient of oxygen transfer was used for finding an optimum ratio of power for aeration and pumping. Growth experiments with Candida utilis on ethanol confirmed some of the above results. Biomass productivity of 2.5 g L(-1) h(-1) testifies about a good transfer capability of the column. Columns fitted with pneumatic and/or hydraulic energy input may be promising for aerobic fermentations considering their mass transfer and mixing characteristics.
nTiO2 mass transfer and deposition behavior in an aquatic environment
Wei, Xiuzhen; He, Junhui; Wang, Meng; Fang, Jinfeng; Chen, Jinyuan; Lv, Bosheng
2016-12-01
Nano-TiO2 (nTiO2) is widely used in industry, and some of it is inevitably released into natural aquatic environments. nTiO2 can be deposited on the streambed or transported along the stream and streambed, and it can also undergo exchange-transfer processes in these systems. The behavior of nTiO2 in rivers includes deposition-transfer processes in the stream and exchange-transfer processes between the stream and streambed. In this work, the deposition, mass transfer, exchange, and aggregation behavior of nTiO2 in a simulated river were studied as a function of the solution pH, stream velocity, and anionic, cationic, and neutral surfactant concentrations. In these experiments, a recirculating flume was used to simulate a natural stream. The nTiO2 deposition and aggregation phenomena in the river and streambed were characterized. Of the three surfactants studied, the anionic surfactant enhanced the nTiO2 stability in the river and limited its aggregation most effectively, resulting in slow nTiO2 deposition and nTiO2 transport over long distances. This study provides information about nanoparticle transport phenomena in simulated natural aquatic systems.
Ruth, van S.M.; Floris, V.; Fayoux, S.
2006-01-01
The volatile profiles of 13 infant formulas were evaluated by proton transfer reaction-mass spectrometry (PTR-MS) and gas chromatography¿mass spectrometry (GC¿MS). The infant formulas varied in brand (Aptamil, Cow & Gate, SMA), type (for different infant target groups) and physical form
3D modelling of coupled mass and heat transfer of a convection-oven roasting process.
Feyissa, Aberham Hailu; Gernaey, Krist V; Adler-Nissen, Jens
2013-04-01
A 3D mathematical model of coupled heat and mass transfer describing oven roasting of meat has been developed from first principles. The proposed mechanism for the mass transfer of water is modified and based on a critical literature review of the effect of heat on meat. The model equations are based on a conservation of mass and energy, coupled through Darcy's equations of porous media - the water flow is mainly pressure-driven. The developed model together with theoretical and experimental assessments were used to explain the heat and water transport and the effect of the change in microstructure (permeability, water binding capacity and elastic modulus) that occur during the meat roasting process. The developed coupled partial differential equations were solved by using COMSOL Multiphysics®3.5 and state variables are predicted as functions of both position and time. The proposed mechanism was partially validated by experiments in a convection oven where temperatures were measured online. Copyright © 2012 Elsevier Ltd. All rights reserved.
Scherr, Thomas F; Markwalter, Christine F; Bauer, Westley S; Gasperino, David; Wright, David W; Haselton, Frederick R
2017-08-01
In many diagnostic assays, specific biomarker extraction and purification from a patient sample is performed in microcentrifuge tubes using surface-functionalized magnetic beads. Although assay binding times are known to be highly dependent on sample viscosity, sample volume, capture reagent, and fluid mixing, the theoretical mass transport framework that has been developed and validated in engineering has yet to be applied in this context. In this work, we adapt this existing framework for simultaneous mass transfer and surface reaction and apply it to the binding of biomarkers in clinical samples to surface-functionalized magnetic beads. We discuss the fundamental fluid dynamics of vortex mixing within microcentrifuge tubes as well as describe how particles and biomolecules interact with the fluid. The model is solved over a wide range of parameters, and we present scenarios when a simplified analytical expression would be most accurate. Next, we review of some relevant techniques for model parameter estimation. Finally, we apply the mass transfer theory to practical use-case scenarios of immediate use to clinicians and assay developers. Throughout, we highlight where further characterization is necessary to bridge the gap between theory and practical application. Copyright © 2017. Published by Elsevier B.V.
Numerical study of heat and mass transfer of ammonia-water in falling film evaporator
Bu, Xianbiao; Ma, Weibin; Huang, Yuanfeng
2012-05-01
To investigate the performance of the heat and mass transfer of ammonia water during the process of falling film evaporation in vertical tube evaporator, a mathematical model of evaporation process was developed and solved based on stream function. Then an experimental study of falling film evaporation was carried out in order to validate the mathematical model. A series of parameters, such as velocity, film thickness and concentration, etc., were obtained from the mathematical model. The calculated results show that the average velocity and the film thickness change sharp at the entrance region when x 100 mm. The film thickness depends largely on the flow rate of solution. It is observed that the heating power and mass flow of solution significantly affect the concentration difference between the inlet and outlet of evaporation tube. The calculated results reveal that the tube length has a significant impact on the amounts of ammonia vapor evaporated. It is suggested that the roll-worked enhanced tube should be used in order to decrease the concentration gradient in the film thickness direction and enhance the heat and mass transfer rate. Furthermore, the experimental and calculated results indicate that the inlet solution concentration has a great influence on the heat exchange capacity, the amounts of ammonia vapor evaporated and the evaporation pressure.
Laminar mixed convection heat and mass transfer in an isothermally cooled channel
Energy Technology Data Exchange (ETDEWEB)
Oulaid, O. [Laboratoire de Mecanique des Fluides et d Energetique, Marrakech (Morocco). Dept. of Physics; Sherbrooke Univ., PQ (Canada). Dept. of Mechanical Engineering; Benhamou, B. [Laboratoire de Mecanique des Fluides et d Energetique, Marrakech (Morocco). Dept. of Physics; Galanis, N. [Sherbrooke Univ., PQ (Canada). Dept. of Mechanical Engineering
2009-07-01
Many studies have been performed to investigate the combined effects of thermal and mass buoyancy forces in channel convection. This paper presented a numerical study of a laminar mixed convection associated with phase change in an isothermally cooled vertical parallel-plate channel. The plates were wetted by a thin liquid water film and maintained at a constant temperature lower than that of the air entering the channel. The paper discussed the use of an elliptical model, including axial diffusion of momentum, heat and mass transfer. The paper also presented the solution of the governing equations using the finite volume method with the simpler algorithm for handling the velocity-pressure coupling. Cases of film evaporation and vapor condensation were also considered. In order to to bring out the effects of buoyancy forces, results from mixed convection case and forced convection were compared. A comparative evaluation showed that these forces, mostly of thermal origin, decelerate the flow near the walls and induce flow reversal for high temperatures, thus reducing heat and mass transfer. 17 refs., 1 tab., 6 figs.
Hollow fiber apparatus and use thereof for fluids separations and heat and mass transfers
Bikson, Benjamin; Etter, Stephen; Ching, Nathaniel
2014-06-10
A hollow fiber device includes a hollow fiber bundle, comprising a plurality of hollow fibers, a first tubesheet and a second tubesheet encapsulating respective distal ends of the hollow fiber bundle. The tubesheets have boreholes in fluid communication with bores of the hollow fibers. In at least one of the tubesheets, the boreholes are formed radially. The hollow fiber device can be utilized in heat exchange, in gas/gas, liquid/liquid and gas/liquid heat transfer, in combined heat and mass transfer and in fluid separation assemblies and processes. The design disclosed herein is light weight and compact and is particularly advantageous when the pressure of a first fluid introduced into the bores of hollow fibers is higher than the pressure on the shell side of the device.
Modeling of Heat and Mass Transfer in a TEC-Driven Lyophilizer
Yuan, Zeng-Guang; Hegde, Uday; Litwiller, Eric; Flynn, Michael; Fisher, John
2006-01-01
Dewatering of wet waste during space exploration missions is important for crew safety as it stabilizes the waste. It may also be used to recover water and serve as a preconditioning step for waste compaction. A thermoelectric cooler (TEC)-driven lyophilizer is under development at NASA Ames Research Center for this purpose. It has three major components: (i) an evaporator section where water vapor sublimes from the frozen waste, (ii) a condenser section where this water vapor deposits as ice, and (iii) a TEC section which serves as a heat pump to transfer heat from the condenser to the evaporator. This paper analyses the heat and mass transfer processes in the lyophilizer in an effort to understand the ice formation behavior in the condenser. The analysis is supported by experimental observations of ice formation patterns in two different condenser units.
Directory of Open Access Journals (Sweden)
Kalidas Das
2016-10-01
Full Text Available The present work is concerned with heat and mass transfer of an electrically conducting second grade MHD fluid past a semi-infinite stretching sheet with convective surface heat flux. The analysis accounts for thermophoresis and thermal radiation. A similarity transformations is used to reduce the governing equations into a dimensionless form. The local similarity equations are derived and solved using Nachtsheim-Swigert shooting iteration technique together with Runge–Kutta sixth order integration scheme. Results for various flow characteristics are presented through graphs and tables delineating the effect of various parameters characterizing the flow. Our analysis explores that the rate of heat transfer enhances with increasing the values of the surface convection parameter. Also the fluid velocity and temperature in the boundary layer region rise significantly for increasing the values of thermal radiation parameter.
DEFF Research Database (Denmark)
Larsson, Hilde Kristina
the velocity and pressure distributions in a fluid. CFD also enables the modelling of several fluids simultaneously, e.g. gas bubbles in a liquid, as well as the presence of turbulence and dissolved chemicals in a fluid, and many other phenomena. This makes CFD an appreciated tool for studying flow structures......, mixing, and other mass transfer phenomena in chemical and biochemical reactor systems. In this project, four selected case studies are investigated in order to explore the capabilities of CFD. The selected cases are a 1 ml stirred microbioreactor, an 8 ml magnetically stirred reactor, a Rushton impeller...... stirred pilot plant reactor, and a rotating bed reactor filled with catalytic porous material. A selection of the simulated phenomena includes the velocities and turbulent quantities in the reactors, as well as the distribution of the gas and liquid phases in them. Mixing times, oxygen transfer rates...
Mass transfer in rectification of a binary mixture containing an inert component
Energy Technology Data Exchange (ETDEWEB)
Rudov, G.Ya.; Trifonov, S.A.
1988-08-20
Rectification sometimes involves separating a mixture containing an inert component, which enters the column with the raw material or is added deliberately to replace part of the vapor phase in the column, or else to reduce the temperature to save energy. There is a restricted number of methods available for calculating such processes, most of which are based on assuming equimolar mass transfer. However, various factors cause the transfer to deviate considerably from equimolar, including heat losses, input of recycled material below its boiling point, raw material input, differences in the molar heats of evaporation between components, and inert components in the vapor phase. They consider a system consisting of a vapor phase, in which three components diffuse, one of which is an inert component, and a liquid phase, which contains two components. The mixtures were propanol-water, isopropanol-water, propanol-water-air, and isopropanol-water-air.
Simulation of the heat and mass transfer processes during the vacuum frying of potato chips
Directory of Open Access Journals (Sweden)
Ram Yamsaengsung
2008-01-01
Full Text Available A fundamental two-dimensional model to predict the heat and mass transfer that occur during the vacuum frying of potato chips was solved using the Finite Element toolbox in MATLAB 6.1. The simulation of the heat transfer process included the convection of heat from the surface to the product, the conduction of heat into the product, and a loss of heat using the heat source term representing evaporation. The mass transfer process was divided into two periods: (1 water loss and (2 oil absorption. The first scenario included a diffusion term and a source term. The source term represented the convection and evaporation of water from the product. For the second period, the diffusion term represented the gradual absorption of oil through capillary diffusion.From the simulation, a good agreement between the experimental data and the predicted values was obtained. From the heat transfer model, the rapid increase in temperature of the product toward the boiling point of water (at the associated pressure followed by its steady increase toward the temperature of the oil was validated. Furthermore, by separating the rate of moisture loss into two parts to represent the constant rate and falling rate period of drying, the model was able to predict an initial period of rapid moisture loss followed by a decreasing rate of moisture loss. The simulation also demonstrated the formation of the crust and the gradual movement of the crust inward. Finally, using two sets of diffusion coefficients that correlated to the two schemes of moisture loss, the model predicted the rapid flux of oil into the product during the constant drying stage, followed by a small amount of oil absorption into its interior once the crust had been established.
Energy Technology Data Exchange (ETDEWEB)
Waesche, S.; Hempel, D.C. [Technische Univ. Braunschweig (Germany). Inst. fuer Bioverfahrenstechnik; Horn, H. [Fachhochschule Magdeburg (Germany). Hydro- und Abfallchemie
1999-07-01
Substance transfer in the boundary layer bulk/biofilm can be only inadequately described by conventional model concepts. In such cases where the surface structure of a biofilm adapts to given hydraulic conditions, the substance transfer phenomena need to be studied in depth. In addition, the entire biofilm structure is much influenced both by substrate conditions and by hydrodynamic conditions during growth. With a view to quantifying these factors, biofilms were cultured under various substrate and hydrodynamic conditions in tube reactors with a diameter of 2.6 cm. For characterizing the cultured biofilms, biofilm density and substrate turnover measured as maximum mass transfer density were determined in each test series. Biofilm density (dry biomass/biofilm volume) was determined by gravimetry. Maximum mass transfer densities in biofilm were established in batch experiments with excess substrate. By means of oxygen microelectrodes, oxygen profiles in the biofilm were measured directly in the reactor. These measurements concerned biofilms of thicknesses ranging from 400 to 2000 {mu}m, where the biofilms did not yet exhibit erosion. (orig.) [German] Der Stoffuebergang in der Grenzschicht Bulk/Biofilm ist mit herkoemmlichen Modellvorstellungen nur ungenuegend beschreibbar. Eine sich an die aktuellen hydraulischen Bedingungen anpassende Oberflaechenstruktur des Biofilms erfordert eine intensive Untersuchung der Stoffuebergangsphaenomene in derartigen Systemen. Darueber hinaus wird die gesamte Biofilmstruktur sowohl von den Substratbedingungen als auch von den hydrodynamischen Bedingungen waehrend des Wachstums stark beeinflusst. Um diese Faktoren quantifizieren zu koennen, wurden Biofilme bei verschiedenen Substrat- und hydrodynamischen Bedingungen in Rohrreaktoren mit einem Durchmesser von 2,6 cm kultiviert. Zur Charakterisierung der kultivierten Biofilme wurde die Biofilmdichte und der Substratumsatz, gemessen als maximale Massestromdichte, bei jeder Versuchsreihe
QUALITY, PERFORMANCE ANALYSIS, MASS TRANSFER PARAMETERS AND MODELING OF DRYING KINETICS OF SOYBEAN
Directory of Open Access Journals (Sweden)
H. Darvishi
Full Text Available Abstract Different aspects of soybean drying such as energy and exergy analyses, quality, mass transfer parameters, and modeling of drying kinetics were investigated in a microwave dryer. Results showed that energy and exergy efficiency increased with increasing microwave power, while values of energy efficiency (33.70 to 66.0% were higher than exergy efficiency (23.38 - 48.30%. Specific energy consumption and energy loss varied 4.93 to 9.11 MJ/kg water and 5.04 to 8.89 MJ/kg water, respectively. Approximately 8.94 to 20.07% of the total energy input is consumed by increasing of the product temperature. The values of improvement potential changed between 1.31- 5.35 MJ/kg water. Bulk density, degree of shrinkage and rehydration ratio varied from 726.6 to 762.8 kg/m3, 0.888 to 0.910, and 0.618 - 0.799, respectively. Parameters total color change (14.68 - 19. 89 and hue angle (88.07 to 91.73º increased with increasing microwave power. Effective diffusivity and mass transfer coefficient varied from 1.99×10−9 to 12.25×10−9 m2/s and 2.71×10−6 to 19.98×10−6 m/s, respectively. The activation energy was found to be 4.98 W/g for a diffusion model and 5.33 W/g for a mass transfer model. Among the models, the Page model was found to best describe the drying behavior of soybean.
Gas diffusion electrodes improve hydrogen gas mass transfer for a hydrogen oxidizing bioanode.
Rodenas, Pau; Zhu, Fangqi; Ter Heijne, Annemiek; Sleutels, Tom; Saakes, Michel; Buisman, Cees
2017-12-01
Bioelectrochemical systems (BESs) are capable of recovery of metals at a cathode through oxidation of organic substrate at an anode. Recently, also hydrogen gas was used as an electron donor for recovery of copper in BESs. Oxidation of hydrogen gas produced a current density of 0.8 A m-2 and combined with Cu2+ reduction at the cathode, produced 0.25 W m-2. The main factor limiting current production was the mass transfer of hydrogen to the biofilm due to the low solubility of hydrogen in the anolyte. Here, the mass transfer of hydrogen gas to the bioanode was improved by use of a gas diffusion electrode (GDE). With the GDE, hydrogen was oxidized to produce a current density of 2.9 A m-2 at an anode potential of -0.2 V. Addition of bicarbonate to the influent led to production of acetate, in addition to current. At a bicarbonate concentration of 50 mmol L-1, current density increased to 10.7 A m-2 at an anode potential of -0.2 V. This increase in current density could be due to oxidation of formed acetate in addition to oxidation of hydrogen, or enhanced growth of hydrogen oxidizing bacteria due to the availability of acetate as carbon source. The effect of mass transfer was further assessed through enhanced mixing and in combination with the addition of bicarbonate (50 mmol L-1) current density increased further to 17.1 A m-2. Hydrogen gas may offer opportunities as electron donor for bioanodes, with acetate as potential intermediate, at locations where excess hydrogen and no organics are available. © 2017 The Authors. Journal of Chemical Technology & Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.
Energy Technology Data Exchange (ETDEWEB)
Park, Sang Kyoo; Yang, Hei Cheon [Chonnam Nat’l Univ., Gwangju (Korea, Republic of)
2017-06-15
As stricter environmental regulation have led to an increase in the water treatment cost, it is necessary to quantitatively study the input power of the aeration process to improve the energy efficiency of the water treatment processes. The objective of this study is to propose the empirical correlations for the mass transfer coefficient with the gas hold-up and input power in order to investigate the mass transfer characteristics of the aeration process. It was found that as the input power increases, the mass transfer coefficient increases because of the decrease of gas hold-up and increase of Reynolds number, the penetration length, and dispersion of mixed flow. The correlations for the volumetric mass transfer coefficients with gas hold-up and input power were consistent with the experimental data, with the maximum deviation less than approximately ±10.0%.
Zhang, Xin; Duan, Xili; Gao, Zhengming
2017-10-01
In this paper, the three-phase (gas-liquid-solid) system in a stirred tank is experimentally studied. The response surface methodology (RSM) is used to analyze the three phase mass transfer coefficient under different conditions, i.e., rotation speeds (8, 10, and 12 s-1), volumetric solid content fractions (0, 6 and 12%), gas flow rates (6, 8, and 10 m3 h-1) and temperatures (40, 54, and 68 °C). With the RSM, it was found that all of these four operational parameters are significant in affecting the mass transfer coefficient, with the rotation speed being the most significant one. A new correlation is developed with a quadratic term for solid content fraction, indicating that there is a minimum value of mass transfer coefficient at a certain solid content fraction. Compared with traditional experimental design and correlation methods, the RSM in this study reduces experiment time and provides a better correlation to predict the mass transfer coefficient.
Khan, Kashif Ali; Butt, Asma Rashid; Raza, Nauman
2018-03-01
In this study, an endeavor is to observe the unsteady two-dimensional boundary layer flow with heat and mass transfer behavior of Casson fluid past a stretching sheet in presence of wall mass transfer by ignoring the effects of viscous dissipation. Chemical reaction of linear order is also invoked here. Similarity transformation have been applied to reduce the governing equations of momentum, energy and mass into non-linear ordinary differential equations; then Homotopy analysis method (HAM) is applied to solve these equations. Numerical work is done carefully with a well-known software MATHEMATICA for the examination of non-dimensional velocity, temperature, and concentration profiles, and then results are presented graphically. The skin friction (viscous drag), local Nusselt number (rate of heat transfer) and Sherwood number (rate of mass transfer) are discussed and presented in tabular form for several factors which are monitoring the flow model.
DEFF Research Database (Denmark)
Ratkovich, Nicolas Rios; Berube, P.R.; Nopens, I.
2011-01-01
higher shear stresses near the membrane surface, which generate high mass transfer coefficients from the surface to the bulk region. However, measuring the mass transfer coefficient is difficult in complex heterogeneous mixtures like activated sludge and existing techniques (e.g. electrochemical methods......) cannot be applied directly. As an alternative, in this work, a multidisciplinary approach was selected, by exploiting dimensionless analysis using the Sherwood number. Mass transfer coefficients were measured at various superficial velocities of gas and liquid flow in a tubular system. Due......). A semi-empirical relationship based on the Lévêque relationship for the Sherwood number (mass transfer coefficient) was formulated for the laminar regime. A test case comparison between water and activated sludge was performed based on full-scale airlift MBR operational conditions. It was found...
Directory of Open Access Journals (Sweden)
S. Heinrich
2005-06-01
Full Text Available A model was developed taking into consideration the heat and mass transfer processes in liquid-sprayed fluidized beds. Such fluidized beds (FB are used for granulation, coating and agglomeration. Conclusions are drawn on the relevance of particle dispersion, spraying and drying to temperature and concentrations distributions. In extension, the model was coupled with a population balance model to describe the particle size distribution and the seeds formation for continuous external FBSG (fluidized bed spray granulation with non-classifying product discharge and a screening and milling unit in the seeds recycle. The effects of seeds formation on the stability of the process is discussed.
PROCESSES OF HEAT-MASS-TRANSFER IN APPARATUS OF SOLAR ABSORBING REFRIGERATION SYSTEMS
Directory of Open Access Journals (Sweden)
Doroshenko A.V.
2014-12-01
Full Text Available Ideology of development of the solar refrigeration systems and systems of air-conditioning, based on the use of absorbing cycle and solar energy for the regeneration of absorbent solution, is presented in the article. The processes of joint heat-mass-transfer are considered in the direct and indirect types of evaporated coolers taking into account the phenomenon of re-condensation of aquatic steams at the low temperature evaporated cooling of environments. The pre-liminary analysis of possibilities of the solar systems is executed as it applies in relation to the tasks of cooling of envi-ronments and air-conditioning systems.
DEFF Research Database (Denmark)
Smets, Barth F.; Lardon, Laurent
2009-01-01
Predicting the fate of horizontally transmissible elements in extant microbial communities might be facilitated by the availability of suitable mathematical models. Since the mid-1970s, mass action models have been introduced to describe the transfer of conjugal and mobilizable genetic elements...... of the outcomes to the various plasmid dynamic parameters. For our analysis, we developed a set of user-friendly MatLab® routines, which are deposited in the public domain. We hope that the availability of these routines will encourage the computationally untrained microbiologist to make use of these mathematical...
Solutions for a mass transfer process governed by fractional diffusion equations with reaction terms
Lenzi, E. K.; dos Santos, M. A. F.; Lenzi, M. K.; Menechini Neto, R.
2017-07-01
We investigate the behavior of a mass transfer process governed by a set of fractional diffusion equations coupled by appropriate reaction terms. The presence of memory effects in the diffusive term is also considered. For this set of equations, we obtain solutions and analyze the influence of the reaction terms on the spreading of these solutions. Particularly, we observe that for reversible reaction processes the reaction terms play an important role for intermediate times and for long times the processes are essentially governed by the bulk equations. These results show a rich class of behaviors which can be connected to sub- or superdiffusive regime.
MHD mass transfer flow of an Eyring-Powell fluid over a stretching sheet
Babu, D. Harish; Sudheer Babu, M.; Narayana, P. V. Satya
2017-11-01
This study investigates the mass transfer flow of Powell-Eyring fluid due to the porous stretching sheet with magnetic field. A second-order approximation of the Eyring-Powell fluid model is used to obtain the flow equations. Using usual similarity transformations, the governing equations have been transformed into non-linear ordinary differential equations and solved by a powerful technique known as shooting method along with R-K fourth order scheme. Graphical results displaying the influence of pertinent physical parameters on the velocity, concentration profile, skin-friction coefficient and Sherwood number are given.
DEFF Research Database (Denmark)
Molina, Henrik; Horn, David M; Tang, Ning
2007-01-01
Electron transfer dissociation (ETD) is a recently introduced mass spectrometric technique that provides a more comprehensive coverage of peptide sequences and posttranslational modifications. Here, we evaluated the use of ETD for a global phosphoproteome analysis. In all, we identified a total...... of 1,435 phosphorylation sites from human embryonic kidney 293T cells, of which 1,141 ( approximately 80%) were not previously described. A detailed comparison of ETD and collision-induced dissociation (CID) modes showed that ETD identified 60% more phosphopeptides than CID, with an average of 40% more...
Mass transfer kinetics during deep fat frying of wheat starch and gluten based snacks
Sobukola, O. P.; Bouchon, P.
2014-06-01
Mass transfer (moisture loss and oil uptake) kinetics during deep fat frying of wheat starch and gluten based snacks was investigated. Both followed a modified first order reaction. Activation energies, z-value, and highest values of D and k for moisture loss and oil uptake were 28.608 kJ/mol, 129.88 °C, 490 and 0.0080 s-1; and 60.398 kJ/mol, 61.79 °C, 1,354.71 and 0.0052 s-1, respectively.
Pore-scale Analysis of Equilibrium and Non-equilibrium DNAPL Mass Transfer
Roberts, K. L.; Willson, C. S.; Thompson, K. E.; Moe, W. M.
2008-12-01
A large number of groundwater aquifers are contaminated by dense nonaqueous phase liquids (DNAPL) comprised of chlorinated hydrocarbons. While there have been a large number of experimental and modeling studies investigating NAPL dissolution at various length scales, rate-limiting processes involved in DNAPL dissolution remain poorly understood. Appropriate mathematical models for describing localized phenomena in a manner conducive to continuum scale modeling are not yet fully developed or have not been robustly tested in comparison to experimental data. Here, high-resolution (i.e., ~10 micron) synchrotron X-ray tomography was used to non-destructively obtain three-dimensional images of the internal structure of a series of unconsolidated porous media (40/50 Accusand) systems at various stages of tetrachloroethene (PCE) dissolution during equilibrium and non-equilibrium mass transfer conditions. Algorithms developed by our group were used to: (1) quantify the granular packing characteristics (e.g., grain sizes, shapes, coordination number); (2) pore network structure (e.g., individual pore body geometry and connectivity); and (3) DNAPL blob characteristics (e.g., blobs sizes, interfacial areas); and (4) correlations between the blob characteristics and pore network structure. Generation of the detailed pore network structure allowed pore network modeling to be performed on the actual void space geometry and topology. A unique aspect of this approach is that it directly incorporated pore-scale preferential flow paths that formed due to pore-level heterogeneities and NAPL blob location and geometry. Analysis of the granular packing and pore network structure properties indicate that the column preparation technique resulted in uniform packing among the different systems. This allowed us to assess the impact of flowrates and local pore-level properties on mass transfer and dissolution of individual DNAPL blobs. Experimental results from columns subjected to low flow
Effects of mass transfer on MHD flow of casson fluid with chemical reaction and suction
Directory of Open Access Journals (Sweden)
S. A. Shehzad
2013-03-01
Full Text Available Effect of mass transfer in the magnetohydrodynamic flow of a Casson fluid over a porous stretching sheet is addressed in the presence of a chemical reaction. A series solution for the resulting nonlinear flow is computed. The skin friction coefficient and local Sherwood number are analyzed through numerical values for various parameters of interest. The velocity and concentration fields are illustrated for several pertinent flow parameters. We observed that the Casson parameter and Hartman number have similar effects on the velocity in a qualitative sense. We further analyzed that the concentration profile decreases rapidly in comparison to the fluid velocity when we increased the values of the suction parameter.
Mass Transfer and Kinetics Study of Heterogeneous Semi-Batch Precipitation of Magnesium Carbonate
DEFF Research Database (Denmark)
Han, B.; Qu, H. Y.; Niemi, H.
2014-01-01
Precipitation kinetics and mass transfer of magnesium carbonate (MgCO3) hydrates from a reaction of magnesium hydroxide (Mg(OH)(2)) and CO2 were analyzed. The effect of CO2 flow rate and mixing intensity on precipitation was investigated under ambient temperature and atmospheric pressure. Raman...... spectroscopy was used to determine the composition of the solids during semi-batch crystallization. The obtained spectra revealed the dissolution of Mg(OH)(2) and the formation of MgCO3. The precipitation rate increased with higher gas flow rate. The rotation speed of the stirrer had a significant effect...
Directory of Open Access Journals (Sweden)
R. Muthuraj
2016-03-01
Full Text Available The influence of elasticity of flexible walls on peristaltic transport of a dusty fluid with heat and mass transfer in a horizontal channel in the presence of chemical reaction has been investigated under long wavelength approximation. Expressions have been constructed for stream function, temperature and concentration by using perturbation technique. The effects of various parameters on heat and mass transfer characteristics of the flow are discussed through graphs.
Yun, Xiao; Quarini, Giuseppe L
2017-03-13
We demonstrate a method for the study of the heat and mass transfer and of the freezing phenomena in a subcooled brine environment. Our experiment showed that, under the proper conditions, ice can be produced when water is introduced to a bath of cold brine. To make ice form, in addition to having the brine and water mix, the rate of heat transfer must bypass that of mass transfer. When water is introduced in the form of tiny droplets to the brine surface, the mode of heat and mass transfer is by diffusion. The buoyancy stops water from mixing with the brine underneath, but as the ice grows thicker, it slows down the rate of heat transfer, making ice more difficult to grow as a result. When water is introduced inside the brine in the form of a flow, a number of factors are found to influence how much ice can form. Brine temperature and concentration, which are the driving forces of heat and mass transfer, respectively, can affect the water-to-ice conversion ratio; lower bath temperatures and brine concentrations encourage more ice to form. The flow rheology, which can directly affect both the heat and mass transfer coefficients, is also a key factor. In addition, the flow rheology changes the area of contact of the flow with the bulk fluid.
Mass driver reaction engine characteristics and performance in earth orbital transfer missions
Snow, W. R.; Dunbar, R. S.
1982-01-01
Configurations of a typical mass driver reaction engine (MDRE) are presented and its use for delivery of payloads to geosynchronous orbit (GEO) from low earth orbit (LEO) is discussed. Basic rocket equations are developed for LEO to GEO round-trip missions using a single exhaust velocity. It is shown that exhaust velocities in the 5-10 km/sec range (specific impulse of 500-1000 sec) are well suited for mass drivers, minimizing the overall cost of missions. Payload delivery rate fractions show that there is little to be gained by stretching out LEO to GEO transfer times from 90 to 180 days. It therefore pays to use the shorter trip time, approximately doubling the amount of delivered payload during any fixed time of use of the MDRE.
Wall mass transfer and pressure gradient effects on turbulent skin friction
Watson, R. D.; Balasubramanian, R.
1984-01-01
The effects of mass injection and pressure gradients on the drag of surfaces were studied theoretically with the aid of boundary-layer and Navier-Stokes codes. The present investigation is concerned with the effects of spatially varying the injection in the case of flat-plate drag. Effects of suction and injection on wavy wall surfaces are also explored. Calculations were performed for 1.2 m long surfaces, one flat and the other sinusoidal with a wavelength of 30.5 cm. Attention is given to the study of the effect of various spatial blowing variations on flat-plate skin friction reduction, local skin friction coefficient calculated by finite difference boundary-layer code and Navier-Stokes code, and the effect of phase-shifting sinusoidal mass transfer on the drag of a sinusoidal surface.
Guo, Xin; Yao, Lishan; Huang, Qingshan
2015-08-01
Effects of superficial gas velocity and top clearance on gas holdup, liquid circulation velocity, mixing time, and mass transfer coefficient are investigated in a new airlift loop photobioreactor (PBR), and empirical models for its rational control and scale-up are proposed. In addition, the impact of top clearance on hydrodynamics, especially on the gas holdup in the internal airlift loop reactor, is clarified; a novel volume expansion technique is developed to determine the low gas holdup in the PBR. Moreover, a model strain of Chlorella vulgaris is cultivated in the PBR and the volumetric power is analyzed with a classic model, and then the aeration is optimized. It shows that the designed PBR, a cost-effective reactor, is promising for the mass cultivation of microalgae. Copyright © 2015 Elsevier Ltd. All rights reserved.
Energy Technology Data Exchange (ETDEWEB)
Zhu, Hongying; Huang, Guangming, E-mail: gmhuang@ustc.edu.cn
2015-03-31
Graphical abstract: Direct and humidity independent mass spectrometry analysis of gas phase chemicals could be achieved via ambient proton transfer ionization, ion intensity was found to be stable with humidity ranged from ∼10% to ∼100%. - Highlights: • A humidity independent mass spectrometric method for gas phase samples analysis. • A universal and good sensitivity method. • The method can real time identify plant released raw chemicals. - Abstract: In this work, a humidity independent mass spectrometric method was developed for rapid analysis of gas phase chemicals. This method is based upon ambient proton transfer reaction between gas phase chemicals and charged water droplets, in a reaction chamber with nearly saturate humidity under atmospheric pressure. The humidity independent nature enables direct and rapid analysis of raw gas phase samples, avoiding time- and sample-consuming sample pretreatments in conventional mass spectrometry methods to control sample humidity. Acetone, benzene, toluene, ethylbenzene and meta-xylene were used to evaluate the analytical performance of present method. The limits of detection for benzene, toluene, ethylbenzene and meta-xylene are in the range of ∼0.1 to ∼0.3 ppbV; that of benzene is well below the present European Union permissible exposure limit for benzene vapor (5 μg m{sup −3}, ∼1.44 ppbV), with linear ranges of approximately two orders of magnitude. The majority of the homemade device contains a stainless steel tube as reaction chamber and an ultrasonic humidifier as the source of charged water droplets, which makes this cheap device easy to assemble and facile to operate. In addition, potential application of this method was illustrated by the real time identification of raw gas phase chemicals released from plants at different physiological stages.
Wall-to-bed mass transfer in three phase fluidized beds in the presence of angled disc promoter
Rohini Kumar, P.; Ashok Kumar, K.; Murty, M. S. N.; Ramesh, K. V.
2017-10-01
Mass transfer coefficient data were computed from measured limiting current values obtained at point electrodes fixed flush with the inner wall of an outer cylinder of three phase fluidized bed electrochemical reactor in the presence of an angled disc internal. Nitrogen was used as gas phase. Glass balls of different diameters were used as solid phase. The liquid phase was an electrolyte that belonged to the ferricyanide-ferrocyanide redox system. Enhancement in mass transfer coefficient obtained in the case of three-phase fluidized bed in the presence of angled disc internal was upto 14 fold in comparison with the homogeneous flow of electrolyte in plain pipe. The mass transfer coefficient data thus obtained were found to increase with increasing gas velocity, pitch and disc diameter. An increase in disc angle resulted in a decrease in the mass transfer coefficient. The influence of liquid velocity, promoter rod diameter and particle diameter on mass transfer coefficient was found to be insignificant. The entire mass transfer coefficient data obtained in the present study were subjected to regression analysis and useful correlation equation was obtained.
Thorslund, Josefin; Jarsjö, Jerker; Chalov, Sergey; Belozerova, Ekaterina
2013-04-01
The flux, transfer and accumulation of heavy metals in aquatic systems pose a potential danger to the ecosystem at various scales, due to their toxicity and non-destroyable nature. Mining and ore excavation can cause heavy metal pollution of both local and downstream water systems, including groundwater sources. The Zaamar Goldfield, located in the upper Lake Baikal Basin (Mongolia), is an example of an extensive gold mining site, which significantly contributes to downstream increases in riverine concentrations of heavy metals, both in dissolved and suspended phases. However, the placer mining area is large and the pollution is diffuse by nature. Due to lack of detailed monitoring, it is unclear how the pollution is transported from the mine tailings to the river. There are several potentially important pathways, such as mobilization of bank sediments, in-stream dissolution from metal-rich suspended/bottom sediments, and through polluted groundwater. We here aim at estimating diffuse mass flows from the source zone to the river, in addition to riverine mass flows. Additionally, the behaviour of heavy metals under varying geochemical conditions (such as pH) is investigated, to be able to understand the solubility of various heavy metals and their partitioning between particulate and dissolved phase. We base our analysis on on-site hydrogeochemical field campaigns. These include concentration measurements in different media (groundwater, waste ponds, ditches, river water, suspended sediments, and bottom sediments). Runoff estimations from the site as well as solubility calculations are also main analytical methods. Results show a net increase in both dissolved and suspended riverine mass flows over the Zaamar site. Concentrations in the deep groundwater system are generally in the same order of magnitude as river concentrations, which suggest important inputs of dissolved heavy metals to the river through groundwater flows. The input of dissolved concentrations are
Kleinman, Leonid S.; Red, X. B., Jr.
1995-01-01
An algorithm has been developed for time-dependent forced convective diffusion-reaction having convection by a recirculating flow field within the drop that is hydrodynamically coupled at the interface with a convective external flow field that at infinity becomes a uniform free-streaming flow. The concentration field inside the droplet is likewise coupled with that outside by boundary conditions at the interface. A chemical reaction can take place either inside or outside the droplet, or reactions can take place in both phases. The algorithm has been implemented, and for comparison results are shown here for the case of no reaction in either phase and for the case of an external first order reaction, both for unsteady behavior. For pure interphase mass transfer, concentration isocontours, local and average Sherwood numbers, and average droplet concentrations have been obtained as a function of the physical properties and external flow field. For mass transfer enhanced by an external reaction, in addition to the above forms of results, we present the enhancement factor, with the results now also depending upon the (dimensionless) rate of reaction.
Bugbee, B.; Monje, O.; Tanner, B.
1996-01-01
Here we report on the in situ performance of inexpensive, miniature sensors that have increased our ability to measure mass and energy fluxes from plant canopies in controlled environments: 1. Surface temperature. Canopy temperature measurements indicate changes in stomatal aperture and thus latent and sensible heat fluxes. Infrared transducers from two manufacturers (Exergen Corporation, Newton, MA; and Everest Interscience, Tucson, AZ, USA) have recently become available. Transducer accuracy matched that of a more expensive hand-held infrared thermometer. 2. Air velocity varies above and within plant canopies and is an important component in mass and energy transfer models. We tested commercially-available needle, heat-transfer anemometers (1 x 50 mm cylinder) that consist of a fine-wire thermocouple and a heater inside a hypodermic needle. The needle is heated and wind speed determined from the temperature rise above ambient. These sensors are particularly useful in measuring the low wind speeds found within plant canopies. 3. Accurate measurements of air temperature adjacent to plant leaves facilitates transport phenomena modeling. We quantified the effect of radiation and air velocity on temperature rise in thermocouples from 10 to 500 micrometers. At high radiation loads and low wind speeds, temperature errors were as large as 7 degrees C above air temperature.
On Entropy Generation and the Effect of Heat and Mass Transfer Coupling in a Distillation Process
Burgos-Madrigal, Paulina; Mendoza, Diego F.; López de Haro, Mariano
2018-01-01
The entropy production rates as obtained from the exergy analysis, entropy balance and the nonequilibrium thermodynamics approach are compared for two distillation columns. The first case is a depropanizer column involving a mixture of ethane, propane, n-butane and n-pentane. The other is a weighed sample of Mexican crude oil distilled with a pilot scale fractionating column. The composition, temperature and flow profiles, for a given duty and operating conditions in each column, are obtained with the Aspen Plus V8.4 software by using the RateFrac model with a rate-based nonequilibrium column. For the depropanizer column the highest entropy production rate is found in the central trays where most of the mass transfer occurs, while in the second column the highest values correspond to the first three stages (where the vapor mixture is in contact with the cold liquid reflux), and to the last three stages (where the highest temperatures take place). The importance of the explicit inclusion of thermal diffusion in these processes is evaluated. In the depropanizer column, the effect of the coupling between heat and mass transfer is found to be negligible, while for the fractionating column it becomes appreciable.
Measuring Nitrous Oxide Mass Transfer into Non-Aqueous CO2BOL CO2 Capture Solvents
Energy Technology Data Exchange (ETDEWEB)
Whyatt, Greg A.; Freeman, Charles J.; Zwoster, Andy; Heldebrant, David J.
2016-03-28
This paper investigates CO2 absorption behavior in CO2BOL solvents by decoupling the physical and chemical effects using N2O as a non-reactive mimic. Absorption measurements were performed using a wetted-wall contactor. Testing was performed using a “first generation” CO2 binding organic liquid (CO2BOL), comprised of an independent base and alcohol. Measurements were made with N2O at a lean (0.06 mol CO2/mol BOL) and rich (0.26 mol CO2/mol BOL) loading, each at three temperatures (35, 45 and 55 °C). Liquid-film mass transfer coefficients (kg') were calculated by subtracting the gas film resistance – determined from a correlation from literature – from the overall mass transfer measurement. The resulting kg' values for N2O in CO2BOLs were found to be higher than that of 5 M aqueous MEA under comparable conditions, which is supported by published measurements of Henry’s coefficients for N2O in various solvents. These results suggest that the physical solubility contribution for CO2 absorption in CO2BOLs is greater than that of aqueous amines, an effect that may pertain to other non-aqueous solvents.
An overview of challenges in modeling heat and mass transfer for living on Mars.
Yamashita, Masamichi; Ishikawa, Yoji; Kitaya, Yoshiaki; Goto, Eiji; Arai, Mayumi; Hashimoto, Hirofumi; Tomita-Yokotani, Kaori; Hirafuji, Masayuki; Omori, Katsunori; Shiraishi, Atsushi; Tani, Akira; Toki, Kyoichiro; Yokota, Hiroki; Fujita, Osamu
2006-09-01
Engineering a life-support system for living on Mars requires the modeling of heat and mass transfer. This report describes the analysis of heat and mass transfer phenomena in a greenhouse dome, which is being designed as a pressurized life-support system for agricultural production on Mars. In this Martian greenhouse, solar energy will be converted into chemical energy in plant biomass. Agricultural products will be harvested for food and plant cultivation, and waste materials will be processed in a composting microbial ecosystem. Transpired water from plants will be condensed and recycled. In our thermal design and analysis for the Martian greenhouse, we addressed the question of whether temperature and pressure would be maintained in the appropriate range for humans as well as plants. Energy flow and material circulation should be controlled to provide an artificial ecological system on Mars. In our analysis, we assumed that the greenhouse would be maintained at a subatmospheric pressure under 1/3-G gravitational force with 1/2 solar light intensity on Earth. Convection of atmospheric gases will be induced inside the greenhouse, primarily by heating from sunlight. Microclimate (thermal and gas species structure) could be generated locally around plant bodies, which would affect gas transport. Potential effects of those environmental factors are discussed on the phenomena including plant growth and plant physiology and focusing on transport processes. Fire safety is a crucial issue and we evaluate its impact on the total gas pressure in the greenhouse dome.
Tirunehe, Gossaye; Norddahl, B
2016-04-01
Gas sparging performances of a flat sheet and tubular polymeric membranes were investigated in 3.1 m bubble column bioreactor operated in a semi batch mode. Air-water and air-CMC (Carboxymethyl cellulose) solutions of 0.5, 0.75 and 1.0 % w/w were used as interacting gas-liquid mediums. CMC solutions were employed in the study to simulate rheological properties of bioreactor broth. Gas holdup, bubble size distribution, interfacial area and gas-liquid mass transfer were studied in the homogeneous bubbly flow hydrodynamic regime with superficial gas velocity (U(G)) range of 0.0004-0.0025 m/s. The study indicated that the tubular membrane sparger produced the highest gas holdup and densely populated fine bubbles with narrow size distribution. An increase in liquid viscosity promoted a shift in bubble size distribution to large stable bubbles and smaller specific interfacial area. The tubular membrane sparger achieved greater interfacial area and an enhanced overall mass transfer coefficient (K(L)a) by a factor of 1.2-1.9 compared to the flat sheet membrane.
The role of crystal diversity in understanding mass transfer in nanoporous materials
Remi, Julien Cousin Saint; Lauerer, Alexander; Chmelik, Christian; Vandendael, Isabelle; Terryn, Herman; Baron, Gino V.; Denayer, Joeri F. M.; Kärger, Jörg
2016-04-01
Nanoporous materials find widespread applications in our society: from drug delivery to environmentally friendly catalysis and separation technologies. The efficient design of these processes depends crucially on understanding the mass transfer mechanism. This is conventionally determined by uptake or release experiments, carried out with assemblages of nanoporous crystals, assuming all crystals to be identical. Using micro-imaging techniques, we now show that even apparently identical crystals (that is, crystals of similar size and shape) from the same batch may exhibit very different uptake rates. The relative contribution of the surface resistance to the overall transport resistance varied with both the crystal and the guest molecule. As a consequence of this crystal diversity, the conventional approach may not distinguish correctly between the different mass transfer mechanisms. Detection of this diversity adds an important new piece of evidence in the search for the origin of the surface barrier phenomenon. Our investigations were carried out with the zeolite SAPO-34, a key material in the methanol-to-olefins (MTO) process, propane-propene separation and adsorptive heat transformation.
Mass Transfer From Nonaqueous Phase Organic Liquids in Water-Saturated Porous Media
Geller, J. T.; Hunt, J. R.
2010-01-01
Results of dissolution experiments with trapped nonaqueous phase liquids (NAPLs) are modeled by a mass transfer analysis. The model represents the NAPL as isolated spheres that shrink with dissolution and uses a mass transfer coefficient correlation reported in the literature for dissolving spherical solids. The model accounts for the reduced permeability of a region of residual NAPL relative to the permeability of the surrounding clean media that causes the flowing water to partially bypass the residual NAPL. The dissolution experiments with toluene alone and a benzene-toluene mixture were conducted in a water-saturated column of homogeneous glass beads over a range of Darcy velocities from 0.5 to 10 m d−1. The model could represent the observed effluent concentrations as the NAPL underwent complete dissolution. The changing pressure drop across the column was predicted following an initial period of NAPL reconfiguration. The fitted NAPL sphere diameters of 0.15 to 0.40 cm are consistent with the size of NAPL ganglia observed by others and are the smallest at the largest flow velocity. PMID:20336189
Belháčová-Minaříková, Michaela; Rusina, Tatsiana; Smedes, Foppe; Vrana, Branislav
2017-10-02
The freely dissolved concentration of persistent organic pollutants (POPs) is one of the most important parameters for risk assessment in aquatic environments, due to its proportionality to the chemical activity. Chemical activity difference represents the driving force for a spontaneous contaminant transport, such as water-aquatic biota or water-sediment. Freely dissolved concentrations in sediment pore water can be estimated from the concentrations in a partition-based passive sampler equilibrated in suspensions of contaminated sediment. Equilibration in the sediment/passive sampler system is slow, since concentrations of most POPs in the water phase, which is the main route for mass transfer, are very low. Adding methanol to sediment in suspension increases the POPs' solubility and, consequently, the permeability in the water phase. The resulting higher aqueous concentrations enhance POPs mass transfer up to three times for investigated POPs (polycyclic aromatic hydrocarbons, polychlorinated biphenyls, organochlorine pesticides) and shorten equilibrium attainment to less than 6 weeks. The addition of methanol to the aqueous phase up to a molar fraction of 0.2 changed the POPs equilibrium distribution ratio between sediment and passive sampler by less than a factor of two. As a result, the pore water concentrations of POPs, calculated from their amounts accumulated in a passive sampler, are affected by methanol addition not more than by the same factor.
Heat and Mass Transfer of Droplet Vacuum Freezing Process Based on Dynamic Mesh
Directory of Open Access Journals (Sweden)
Lili Zhao
2014-01-01
Full Text Available A numerical simulation using dynamic mesh method by COMSOL has been developed to model heat and mass transfer during vacuum freezing by evaporation of a single droplet. The initial droplet diameter, initial droplet temperature, and vacuum chamber pressure effect are studied. The surface and center temperature curve was predicted to show the effect. The mass transfer rate and radius displacement were also calculated. The results show the dynamic mesh shows well the freezing process with the radius reduction of droplet. The initial droplet diameter, initial droplet temperature, and vacuum pressure have obvious effect on freezing process. The total freezing time is about 200 s, 300 s, and 400 s for droplet diameter 7.5 mm, 10.5 mm, and 12.5 mm, respectively. The vacuum pressure less than 200 Pa is enough for the less time to freezing the droplet, that is, the key point in freezing time. The initial droplet temperature has obvious effect on freezing but little effect on freezing temperature.
Tip-enhanced laser ablation sample transfer for biomolecule mass spectrometry.
Ghorai, Suman; Seneviratne, Chinthaka A; Murray, Kermit K
2015-01-01
Atomic force microscope (AFM) tip-enhanced laser ablation was used to transfer molecules from thin films to a suspended silver wire for off-line mass spectrometry using laser desorption ionization (LDI) and matrix-assisted laser desorption ionization (MALDI). An AFM with a 30 nm radius gold-coated silicon tip was used to image the sample and to hold the tip 15 nm from the surface for material removal using a 355 nm Nd:YAG laser. The ablated material was captured on a silver wire that was held 300 μm vertically and 100 μm horizontally from the tip. For the small molecules anthracene and rhodamine 6G, the wire was cut and affixed to a metal target using double-sided conductive tape and analyzed by LDI using a commercial laser desorption time-of-flight mass spectrometer. Approximately 100 fg of material was ablated from each of the 1 μm ablation spots and transferred with approximately 3% efficiency. For larger polypeptide molecules angiotensin II and bovine insulin, the captured material was dissolved in saturated matrix solution and deposited on a target for MALDI analysis.
Numerical simulation of annular two-phase flow considering the four involved mass transfers
Baniamerian, Z.; Mehdipour, R.
2013-05-01
In the present study, a numerical model is developed for simulation of annular two-phase flow considering bubbly flow regime in the liquid film along with the four involved mechanisms of mass transfer those are evaporation, entrainment, deposition and condensation. In the numerical approach, liquid film accompanied by fine nucleated bubbles are simulated with innovative model named suction model, the whole domain containing liquid film and the vapor core is simulated by volume of fluid model. While the vapor and the entrained droplets are treated as homogeneous flow. The interface between the liquid and the vapor is traced by level set formulation. The model is then validated by experimental models of Lee & Lee and Stevanovic et al. and shows a good precision such that it predicts the experimental results of Stevanivic et al. Better than their own numerical model. This issue is due to the least possible simplifying assumptions along with considering the effect of boiling in liquid film and all mechanisms of mass transfer in the fluid flow.
Impact of gamma-irradiation on some mass transfer driven operations in food processing
Energy Technology Data Exchange (ETDEWEB)
Rastogi, N.K. [Department of Food Engineering, Central Food Technological Research Institute, Mysore 570 020 (India)]. E-mail: nkrastogi@cftri.com
2005-08-01
The effect of gamma-irradiation pretreatment on some mass transfer driven operations such as dehydration, osmotic dehydration and rehydration, commonly used in food processing, was studied. Applied irradiation up to 12.0 kGy resulted in decrease in hardness of the samples, as indicated by texture analysis. The effective diffusion coefficients of water and solute determined for dehydration, osmotic dehydration as well as for rehydration using a Fickian diffusion model. The effective diffusion coefficients for water (in case of osmotic dehydration and dehydration) and solid diffusion (in case of osmotic dehydration) were found to increase exponentially with doses of gamma-irradiation (G) according to an equation of the form D=A exp(-B/G), where A and B are constants. Microstructures of irradiated-carrot samples revealed that the exposure of carrot to gamma irradiation resulted in the breakage of cell wall structure, thereby causing softening of irradiated samples and facilitating mass transfer during dehydration and osmotic dehydration. The rehydration characteristics showed that gamma-irradiated sample did not absorb as much water as control, probably due to loss of cell integrity.
Impact of gamma-irradiation on some mass transfer driven operations in food processing
Rastogi, N. K.
2005-08-01
The effect of gamma-irradiation pretreatment on some mass transfer driven operations such as dehydration, osmotic dehydration and rehydration, commonly used in food processing, was studied. Applied irradiation up to 12.0 kGy resulted in decrease in hardness of the samples, as indicated by texture analysis. The effective diffusion coefficients of water and solute determined for dehydration, osmotic dehydration as well as for rehydration using a Fickian diffusion model. The effective diffusion coefficients for water (in case of osmotic dehydration and dehydration) and solid diffusion (in case of osmotic dehydration) were found to increase exponentially with doses of gamma-irradiation ( G) according to an equation of the form D= A exp(- B/ G), where A and B are constants. Microstructures of irradiated-carrot samples revealed that the exposure of carrot to gamma irradiation resulted in the breakage of cell wall structure, thereby causing softening of irradiated samples and facilitating mass transfer during dehydration and osmotic dehydration. The rehydration characteristics showed that gamma-irradiated sample did not absorb as much water as control, probably due to loss of cell integrity.
Energy Technology Data Exchange (ETDEWEB)
Ramazanova, E.E.; Nurmamedova, Z.A. [Azerbaijan State Oil Academy, Baku (Azerbaijan). Geotechnological Research Inst. of Oil, Gas, and Chemistry
1997-06-01
The results of research on hydrocarbon mixture sorption in porous medium showed that adsorbent activity with regard to separate components of a gas mixture changes in partial dependence on pressure. The alteration of vented gas content will take place not only in gas condensate fields, when this effect is conditioned by the losses of condensate in the stratum, but also in gas fields, by methods connected with desorption processes. At the same time, gas composition is the basis for different process calculations, such as separation, gas transport, gas filtration in porous medium, and others. Thus the determination of characteristic alterations of gas mixture composition in thermodynamically nonequilibrium hydrocarbon systems mass transfer process becomes important. The binary (methane + pentane) and tricomponent (methane + butane + pentane) systems composed of individual gases of high purity have been researched. Then with help of mathematical methods of experimental data processing the moment of the more characteristic changes of the mass transfer process was discovered. Processing of experimental data for tricomponent system by statistical differentiation allowed the discovery of a pressure below of which lightening of the vented gas was observed.
The role of oxygen mass transfer in the erosion-corrosion of slurry pipelines
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Postlethwaite, J.; Dobbin, M.H.; Bergevin, K.
1986-09-01
The erosion-corrosion of vertical 38-mm diameter pipes carrying aerated slurry (20 vol% -30 + 50 mesh silica sand) in 3.13% NaCl solution at 2 to 6 m/s has been measured by weight loss measurements over periods of 100 h. Electrochemical methods have been applied to clarify the mechanism of the process and to determine the corrosion component of the metal. Total wear rates in the range of 6 to 25 mm/y were related to the slurry velocity (v) by wear rate = const v/sup n/. The value of n was in agreement with oxygen mass transfer controlled corrosion being the dominant mode of metal loss, with n approx. = 1. The absolute values of the wear rate were sufficiently close to those measured by electrochemical methods and those calculated form a mass transfer correlation determined for this system, Sh = 0.031 Re/sup 0.83/Sc/sup 0.33/, to conclude that the dominant mode of metal loss is corrosion. The role of erosive action in the erosion-corrosion process is to prevent the formation of a complete rust film that normally stifles corrosion and reduces the rate to <1 mm/y, not to yield high erosion rates of the corrosion-roughened surfaces, as previously proposed.
Calibration transfer for solving the signal instability in quantitative headspace-mass spectrometry.
Pérez Pavón, José Luis; del Nogal Sánchez, Miguel; García Pinto, Carmelo; Fernández Laespada, M Esther; Moreno Cordero, Bernardo
2003-11-15
It is reported that calibration transfer is able to compensate the variations in sensitivity in direct coupling of a headspace sampler to a mass spectrometer when used for quantification purposes using multivariate calibration techniques. This strategy of signal stability compensation allows the use of models constructed from large calibration standard sets without having to repeat their measurement even though variations occur in sensitivity, which may or may not be constant along the mass range. This technique offers advantages over the use of internal standards in this methodology and only requires the measurement of a small number of transfer samples with each set of unknown samples. The results obtained in the determination of six volatile organic compounds-benzene, toluene, ethylbenzene, and m-xylene (BTEX), methyl tert-butyl ether (MTBE), and mesitylene-are reported. To obtain an appropriate calibration set, a Plackett-Burman design with five levels of concentration for each component was employed. A PLS multivariate calibration model was constructed with a group of 25 samples. For selection of the optimum number of principal components, an external validation set (5 samples) was used and the prediction capacity of this set was checked with an additional group of samples that had not been used either in the construction or in the validation of the model. The results obtained can be considered highly satisfactory, and the methodology was successfully tested with natural matrixes (river and tap water).
Heat and Mass Transfer Measurements for Tray-Fermented Fungal Products
Jou, R.-Y.; Lo, C.-T.
2011-01-01
In this study, heat and mass transfer in static tray fermentation, which is widely used in solid-state fermentation (SSF) to produce fungal products, such as enzymes or koji, is investigated. Specifically, kinetic models of transport phenomena in the whole-tray chamber are emphasized. The effects of temperature, moisture, and humidity on microbial growth in large-scale static tray fermentation are essential to scale-up SSF and achieve uniform fermentation. In addition, heat and mass transfer of static tray fermentation of Trichoderma fungi with two tray setups—traditional linen coverings and stacks in a temperature-humidity chamber is examined. In both these setups, the following factors of fermentation were measured: air velocity, air temperature, illumination, pH, carbon dioxide (CO2) concentration, and substrate temperature, and the effects of bed height, moisture of substrate, and relative humidity of air are studied. A thin (1 cm) bed at 28 °C and 95 % relative humidity is found to be optimum. Furthermore, mixing was essential for achieving uniform fermentation of Trichoderma fungi. This study has important applications in large-scale static tray fermentation of fungi.
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Saadi, B
2006-04-15
Most metallurgical processes, such as steel refining or nuclear waste processing; the interfaces between two liquid phases are the regions of mass transfer. These transfers require the implementation of a means of stirring to accelerate the kinetics of the pollutants transfer between both phases. This thesis deals with the use of the electromagnetic forces to stir, without any material contact, the bath core and the interface in order to control or even increase the kinetic transfers. To achieve this, two complementary experimental installations were used. The first experiment allows the measurement of the Indium transfer, initially dissolved in mercury towards a covering electrolyte layer and the velocity field in mercury. The performed experiments, determine the topology of the fields flows speeds in the mercury bath, moreover the behaviour of the transfer kinetics versus the intensity of the magnetic field are established. This evolution is correlated with the dynamic behaviour of the mercury surface. The second installation allows the characterization of an element transfer (Pb, Zr or Ce) initially contained in a fluorinated salt towards an antimony matrix containing lithium. It appears that all transfers kinetics are very fast. The proposed experimental set-up is particularly efficient for Cerium transfer (limited by the interface) but does not present any action for Zirconium transfer. (author)
Heat and mass transfer parameters in the drying of cocoyam slice
Directory of Open Access Journals (Sweden)
Macmanus C. Ndukwu
2017-03-01
Full Text Available The paper investigates some heat and mass transfer parameters (HMTPs of three varieties of cocoyam slice and their vitamin B retention level in convective drying. The varieties include Colocasia esculenta (COE and xanthosoma sagittiffolium (white flesh – NX01, red flesh – NX02. The objective is to generate HMTPs for process model development, applied in dryer design. The oven and sun drying procedures were employed where temperatures were maintained between 50 and 70 °C (oven drying and sun drying, the readings were observed at every one hour. The results obtained show that the mass transfer coefficient for the three varieties lies between 1.01044×10−6 and 3.44876×10−6 m/s while the heat transfer coefficient ranged from 1.17973 to 3.58284 W/m2 K. The specific energy consumption for drying was estimated at 14.15, 25.16 and 35.07 kWh/kg for NX02, NX01, and COE respectively, at drying temperature (DT of 60 °C. However, at DT range between 50 and 70 °C the moisture extraction rate was varied from 0.047 to 0.185 kg/kWh, for NX02, 0.070–0.258 kg/kWh for NX01 and 0.099–1.42 kg/kWh for COE, with vitamin B retention level ranging from 70.13% to 100% at all DTs for the varieties.
A frequency quantum interpretation of the surface renewal model of mass transfer.
Mondal, Chanchal; Chatterjee, Siddharth G
2017-07-01
The surface of a turbulent liquid is visualized as consisting of a large number of chaotic eddies or liquid elements. Assuming that surface elements of a particular age have renewal frequencies that are integral multiples of a fundamental frequency quantum, and further assuming that the renewal frequency distribution is of the Boltzmann type, performing a population balance for these elements leads to the Danckwerts surface age distribution. The basic quantum is what has been traditionally called the rate of surface renewal. The Higbie surface age distribution follows if the renewal frequency distribution of such elements is assumed to be continuous. Four age distributions, which reflect different start-up conditions of the absorption process, are then used to analyse transient physical gas absorption into a large volume of liquid, assuming negligible gas-side mass-transfer resistance. The first two are different versions of the Danckwerts model, the third one is based on the uniform and Higbie distributions, while the fourth one is a mixed distribution. For the four cases, theoretical expressions are derived for the rates of gas absorption and dissolved-gas transfer to the bulk liquid. Under transient conditions, these two rates are not equal and have an inverse relationship. However, with the progress of absorption towards steady state, they approach one another. Assuming steady-state conditions, the conventional one-parameter Danckwerts age distribution is generalized to a two-parameter age distribution. Like the two-parameter logarithmic normal distribution, this distribution can also capture the bell-shaped nature of the distribution of the ages of surface elements observed experimentally in air-sea gas and heat exchange. Estimates of the liquid-side mass-transfer coefficient made using these two distributions for the absorption of hydrogen and oxygen in water are very close to one another and are comparable to experimental values reported in the literature.
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Van Berkel, G.J.; Zhou, F. (Oak Ridge National Lab., TN (United States))
1994-10-15
Cyclic voltammetry (CV), UV/visible absorption spectroscopy, and electrospray mass spectrometry (ES-MS) are used in conjunction to study the mono- and /or dications produced in solution from the reaction of three model compounds ([beta]-carotene, cobalt(II) octaethylporphyrin (Co[sup II]OEP), nickel(II) octaethylporphyrin (Ni[sup II]OEP), in three different solvent/electron-transfer reagent systems (methylene chloride/0.1% trifluoroacetic acid (TFA) (v/v), methylene chloride/0.1% TFA/2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) v/v/200 [mu]M), methylene chloride/0.1% TFA/0.1% antimony pentafluoride (SbF[sub 5]) (v/v/v)). The reactions were carried out on-line with ES-MS by means of flow injection. Correlation of the CV data for these analytes with the ionic species determined to be in the solution on the basis of UV/visible absorption spectra and/or on the basis of the ionic species observed in the gas phase by ES-MS, along with our previously published data on these solvent/reagent systems, allowed an effective oxidation potential range, E, to be assigned to these solvent/reagent systems: methylene chloride/0.1% TFA (v/v), 0.6V [le] E[sub TFA] < 0.7 V; methylene chloride/0.1% TFA/DDQ (v/v/200 [mu]M), 0.8 [le] E[sub TFA/DDQ] < 1.0 V; methylene chloride/0.1% TFA/0.1% SbF[sub 5] (v/v/v), 1.3 [le] E[sub TFA/SbF(5)] < 1.5. 40 refs., 7 figs.
Weert, de J.P.A.; Streminska, M.A.; Hua, D.; Grotenhuis, J.T.C.; Langenhoff, A.A.M.; Rijnaarts, H.H.M.
2010-01-01
Sediments can function as secondary source for water pollution of aerobically biodegradable non-halogenated organic compounds, which are persistent in anaerobic sediments. The mass transfer of compounds from sediment to bulk water depends on hydraulic conditions. In this study, desorption, mass
Jimenez, Mélanie; Dietrich, Nicolas; Grace, John R; Hébrard, Gilles
2014-07-01
Powerful techniques, based on the Planar Laser Induced Fluorescence (PLIF) technique, are deployed to locally visualize and quantify the impact of surfactants in wastewaters on hydrodynamics and oxygen mass transfer. Bubble diameter, aspect ratio, rise velocity, contamination angle, as well as flux, flux density, liquid side mass transfer and diffusion coefficients of transferred oxygen are determined based on these techniques applied in the wake of rising bubbles of diameter 1 mm and through planar gas/liquid interfaces. The initial experiments were performed in demineralized water containing small amounts of surfactant. Different concentrations of surfactant were added to finally reach the Critical Micelle Concentration (CMC). Bubbles have classically been found to be more spherical with a reduced rise velocity in the presence of surfactants up to the CMC. Above the CMC, these hydrodynamic characteristics were found to be almost constant, although the oxygen mass transfer decreased due to the presence of surfactants. Experimental results were markedly lower than predicted by the well-known Frössling equation with rigid surfaces. This is believed to be caused by a barrier of surfactants hindering the oxygen mass transfer at the interface. Similar hindrance of oxygen mass transfer applies to waters from sewage plants (filtered raw water and treated water), making accurate design of aeration tanks difficult. Copyright © 2014 Elsevier Ltd. All rights reserved.
Energy Technology Data Exchange (ETDEWEB)
Woods, Jason D [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Kozubal, Eric J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)
2018-02-06
Liquid desiccant heat and mass exchangers are a promising technology for efficient humidity control in buildings. Many researchers have investigated these exchangers, often using numerical models to predict their performance. However, there is a lack of information in the literature on the magnitude of the heat and mass transfer resistances, both for the dehumidifier (which absorbs moisture from the air) and the regenerator (which heats the liquid desiccant to re-concentrate it). This article focuses on internally-cooled, 3-fluid exchangers in a parallel plate geometry. Water heats or cools a desiccant across a plate, and the desiccant absorbs or releases water into an airstream through a membrane. A sensitivity analysis was used to estimate the importance of each of the heat and mass transfer resistances (air, membrane, desiccant, plate, water), and how it changes with different design geometries. The results show that, for most designs, the latent and sensible heat transfer of the dehumidifier is dominated by the air mass transfer resistance and air heat transfer resistance, respectively. The air mass transfer resistance is also important for the regenerator, but much less so; the change in the desiccant equilibrium humidity ratio due to a change in either temperature or desiccant mass fraction is much higher at the regenerator's higher temperatures. This increases the importance of (1) getting heat from the water to the desiccant/membrane interface, and (2) diffusing salt ions quickly away from the desiccant/membrane interface. The membrane heat transfer and water heat transfer resistances were found to be the least important. These results can help inform decisions about what simplifying assumptions to make in numerical models, and can also help in designing these exchangers by understanding which resistances are most important.
Energy Technology Data Exchange (ETDEWEB)
Day-Lewis, Frederick; Singha, Kamini; Haggerty, Roy; Johnson, Timothy; Binley, Andrew; Lane, John
2014-03-10
. In this project, we sought to capitalize on the geophysical signatures of mass transfer. Previous numerical modeling and pilot-scale field experiments suggested that mass transfer produces a geoelectrical signature—a hysteretic relation between sampled (mobile-domain) fluid conductivity and bulk (mobile + immobile) conductivity—over a range of scales relevant to aquifer remediation. In this work, we investigated the geoelectrical signature of mass transfer during tracer transport in a series of controlled experiments to determine the operation of controlling parameters, and also investigated the use of complex-resistivity (CR) as a means of quantifying mass transfer parameters in situ without tracer experiments. In an add-on component to our grant, we additionally considered nuclear magnetic resonance (NMR) to help parse mobile from immobile porosities. Our study objectives were to: 1. Develop and demonstrate geophysical approaches to measure mass-transfer parameters spatially and over a range of scales, including the combination of electrical resistivity monitoring, tracer tests, complex resistivity, nuclear magnetic resonance, and materials characterization; and 2. Provide mass-transfer estimates for improved understanding of contaminant fate and transport at DOE sites, such as uranium transport at the Hanford 300 Area. To achieve our objectives, we implemented a 3-part research plan involving (1) development of computer codes and techniques to estimate mass-transfer parameters from time-lapse electrical data; (2) bench-scale experiments on synthetic materials and materials from cores from the Hanford 300 Area; and (3) field demonstration experiments at the DOE’s Hanford 300 Area.
Flow Boiling Heat Transfer in Two-Phase Micro Channel Heat Sink at Low Water Mass Flux
Kuznetsov, Vladimir V.; Shamirzaev, Alisher S.
2009-08-01
Boiling heat transfer at water flow with low mass flux in heat sink which contained rectangular microchannels was studied. The stainless steel heat sink contained ten parallel microchannels with a size of 640 × 2050 μm in cross-section with typical wall roughness of 10-15 μm. The local flow boiling heat transfer coefficients were measured at mass velocity of 17 and 51 kg/m2s, heat flux on 30 to 150 kW/m2 and vapor quality of up to 0.8 at pressure in the channels closed to atmospheric one. It was observed that Kandlikar nucleate boiling correlation is in good agreement with the experimental data at mass flow velocity of 85 kg/m2s. At smaller mass flux the Kandlikar model and Zhang, Hibiki and Mishima model demonstrate incorrect trend of heat transfer coefficients variation with vapor quality.
Energy Technology Data Exchange (ETDEWEB)
Keyhani, M; Miller, W A
1999-11-14
Absorption chillers are gaining global acceptance as quality comfort cooling systems. These machines are the central chilling plants and the supply for cotnfort cooling for many large commercial buildings. Virtually all absorption chillers use lithium bromide (LiBr) and water as the absorption fluids. Water is the refrigerant. Research has shown LiBr to he one of the best absorption working fluids because it has a high affinity for water, releases water vapor at relatively low temperatures, and has a boiling point much higher than that of water. The heart of the chiller is the absorber, where a process of simultaneous heat and mass transfer occurs as the refrigerant water vapor is absorbed into a falling film of aqueous LiBr. The more water vapor absorbed into the falling film, the larger the chiller's capacity for supporting comfort cooling. Improving the performance of the absorber leads directly to efficiency gains for the chiller. The design of an absorber is very empirical and requires experimental data. Yet design data and correlations are sparse in the open literature. The experimental data available to date have been derived at LiBr concentrations ranging from 0.30 to 0.60 mass fraction. No literature data are readily available for the design operating conditions of 0.62 and 0.64 mass fraction of LiBr and absorber pressures of 0.7 and 1.0 kPa.
Biasioli, F; Aprea, E; Gasperi, F; Märk, T D
2009-01-01
PTR-MS (Proton Transfer Reaction-Mass Spectrometry) is an innovative technique that allows the rapid detection of most volatile organic compounds (VOCs) with high sensitivity (sub-ppb) and by direct injection. We describe here the possible use of PTR-MS in waste managements and composting plants both for the real time monitoring of volatile emissions and, after calibration with olfactometric assessments, for the instrumental determination of odour concentration. Beside a short description of the technique, we will report on the calibration of PTR-MS data with olfactometric assessment of odour concentration showing the possibility of a relatively good estimation of odour concentration by instrumental data. We will also show how the rapid PTR-MS fingerprint can be used to visualise the overall effect of a biofilter on the VOCs concentration and to calculate the reduction of the concentration of single masses and, finally, we will provide examples of the performances of a new implementation of this technique based on a time of flight (TOF) analyser. Instead of the usual quadrupole mass filter, the TOF provides an increase of analytical information and the possibility to separate important compounds that in the quadrupole version were not or only indirectly quantifiable. In conclusion we suggest that PTR-MS analysis can be a valuable tool for the rapid and on site monitoring of odour emission and plant operation.
Mass transfer of a neutral solute in porous microchannel under streaming potential.
Mondal, Sourav; De, Sirshendu
2014-03-01
The mass transport of a neutral solute in a porous wall, under the influence of streaming field, has been analyzed in this study. The effect of the induced streaming field on the electroviscous effect of the fluid for different flow geometries has been suitably quantified. The overall electroosmotic velocity profile and expression for streaming field have been obtained analytically using the Debye-Huckel approximation, and subsequently used in the analysis for the mass transport. The analysis shows that as the solution Debye length increases, the strength of the streaming field and, consequently, the electroviscous effect diminishes. The species transport equation has been coupled with Darcy's law for quantification of the permeation rate across the porous wall. The concentration profile inside the mass transfer boundary layer has been solved using the similarity transformation, and the Sherwood number has been calculated from the definition. In this study, the variation of the permeation rate and solute permeate concentration has been with the surface potential, wall retention factor and osmotic pressure coefficient has been demonstrated for both the circular as well as rectangular channel cross-section. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Pore-scale supercritical CO_{2} dissolution and mass transfer under drainage conditions
Energy Technology Data Exchange (ETDEWEB)
Chang, Chun; Zhou, Quanlin; Oostrom, Mart; Kneafsey, Timothy J.; Mehta, Hardeep
2017-02-01
Abstract: Recently, both core- and pore-scale imbibition experiments have shown non-equilibrium dissolution of supercritical CO_{2} (scCO_{2}) and a prolonged depletion of residual scCO_{2}. In this study, pore-scale scCO_{2} dissolution and mass transfer under drainage conditions were investigated using a two-dimensional heterogeneous micromodel and a novel fluorescent water dye with a sensitive pH range between 3.7 and 6.5. Drainage experiments were conducted at 9 MPa and 40 °C by injecting scCO_{2} into the sandstone-analogue pore network initially saturated by water without dissolved CO_{2} (dsCO_{2}). During the experiments, time-lapse images of dye intensity, reflecting water pH, were obtained. These images show non-uniform pH in individual pores and pore clusters, with average pH levels gradually decreasing with time. Further analysis on selected pores and pore clusters shows that (1) rate-limited mass transfer prevails with slowly decreasing pH over time when the scCO_{2}-water interface area is low with respect to the volume of water-filled pores and pore clusters, (2) fast scCO_{2} dissolution and phase equilibrium occurs when scCO_{2} bubbles invade into water-filled pores, significantly enhancing the area-to-volume ratio, and (3) a transition from rate-limited to diffusion-limited mass transfer occurs in a single pore when a medium area-to-volume ratio is prevalent. The analysis also shows that two fundamental processes – scCO_{2} dissolution at phase interfaces and diffusion of dsCO_{2} at the pore scale (10-100 µm) observed after scCO_{2} bubble invasion into water-filled pores without pore throat constraints – are relatively fast. The overall slow dissolution of scCO_{2} in the millimeter-scale micromodel can be attributed to the small area-to-volume ratios that represent pore-throat configurations and characteristics of phase
Quantification of colloidal and aqueous element transfer in soils: The dual-phase mass balance model
Bern, Carleton R.; Thompson, Aaron; Chadwick, Oliver A.
2015-01-01
Mass balance models have become standard tools for characterizing element gains and losses and volumetric change during weathering and soil development. However, they rely on the assumption of complete immobility for an index element such as Ti or Zr. Here we describe a dual-phase mass balance model that eliminates the need for an assumption of immobility and in the process quantifies the contribution of aqueous versus colloidal element transfer. In the model, the high field strength elements Ti and Zr are assumed to be mobile only as suspended solids (colloids) and can therefore be used to distinguish elemental redistribution via colloids from redistribution via dissolved aqueous solutes. Calculations are based upon element concentrations in soil, parent material, and colloids dispersed from soil in the laboratory. We illustrate the utility of this model using a catena in South Africa. Traditional mass balance models systematically distort elemental gains and losses and changes in soil volume in this catena due to significant redistribution of Zr-bearing colloids. Applying the dual-phase model accounts for this colloidal redistribution and we find that the process accounts for a substantial portion of the major element (e.g., Al, Fe and Si) loss from eluvial soil. In addition, we find that in illuvial soils along this catena, gains of colloidal material significantly offset aqueous elemental loss. In other settings, processes such as accumulation of exogenous dust can mimic the geochemical effects of colloid redistribution and we suggest strategies for distinguishing between the two. The movement of clays and colloidal material is a major process in weathering and pedogenesis; the mass balance model presented here is a tool for quantifying effects of that process over time scales of soil development.
Leach, Franklin E.; Riley, Nicholas M.; Westphall, Michael S.; Coon, Joshua J.; Amster, I. Jonathan
2017-09-01
The structural characterization of sulfated glycosaminoglycan (GAG) carbohydrates remains an important target for analytical chemists attributable to challenges introduced by the natural complexity of these mixtures and the defined need for molecular-level details to elucidate biological structure-function relationships. Tandem mass spectrometry has proven to be the most powerful technique for this purpose. Previously, electron detachment dissociation (EDD), in comparison to other methods of ion activation, has been shown to provide the largest number of useful cleavages for de novo sequencing of GAG oligosaccharides, but such experiments are restricted to Fourier transform ion cyclotron resonance mass spectrometers (FTICR-MS). Negative electron transfer dissociation (NETD) provides similar fragmentation results, and can be achieved on any mass spectrometry platform that is designed to accommodate ion-ion reactions. Here, we examine for the first time the effectiveness of NETD-Orbitrap mass spectrometry for the structural analysis of GAG oligosaccharides. Compounds ranging in size from tetrasaccharides to decasaccharides were dissociated by NETD, producing both glycosidic and cross-ring cleavages that enabled the location of sulfate modifications. The highly-sulfated, heparin-like synthetic GAG, ArixtraTM, was also successfully sequenced by NETD. In comparison to other efforts to sequence GAG chains without fully ionized sulfate constituents, the occurrence of sulfate loss peaks is minimized by judicious precursor ion selection. The results compare quite favorably to prior results with electron detachment dissociation (EDD). Significantly, the duty cycle of the NETD experiment is sufficiently short to make it an effective tool for on-line separations, presenting a straightforward path for selective, high-throughput analysis of GAG mixtures. [Figure not available: see fulltext.
Chen, Xuwei; Yang, Xu; Zeng, Wanying; Wang, Jianhua
2015-08-04
Protein transfer from aqueous medium into ionic liquid is an important approach for the isolation of proteins of interest from complex biological samples. We hereby report a solid-cladding/liquid-core/liquid-cladding sandwich optical waveguide system for the purpose of monitoring the dynamic mass-transfer behaviors of hemoglobin (Hb) at the aqueous/ionic liquid interface. The optical waveguide system is fabricated by using a hydrophobic IL (1,3-dibutylimidazolium hexafluorophosphate, BBimPF6) as the core, and protein solution as one of the cladding layer. UV-vis spectra are recorded with a CCD spectrophotometer via optical fibers. The recorded spectra suggest that the mass transfer of Hb molecules between the aqueous and ionic liquid media involve accumulation of Hb on the aqueous/IL interface followed by dynamic extraction/transfer of Hb into the ionic liquid phase. A part of Hb molecules remain at the interface even after the accomplishment of the extraction/transfer process. Further investigations indicate that the mass transfer of Hb from aqueous medium into the ionic liquid phase is mainly driven by the coordination interaction between heme group of Hb and the cationic moiety of ionic liquid, for example, imidazolium cation in this particular case. In addition, hydrophobic interactions also contribute to the transfer of Hb.
Methods to control phase inversions and enhance mass transfer in liquid-liquid dispersions
Tsouris, Constantinos; Dong, Junhang
2002-01-01
The present invention is directed to the effects of applied electric fields on liquid-liquid dispersions. In general, the present invention is directed to the control of phase inversions in liquid-liquid dispersions. Because of polarization and deformation effects, coalescence of aqueous drops is facilitated by the application of electric fields. As a result, with an increase in the applied voltage, the ambivalence region is narrowed and shifted toward higher volume fractions of the dispersed phase. This permits the invention to be used to ensure that the aqueous phase remains continuous, even at a high volume fraction of the organic phase. Additionally, the volume fraction of the organic phase may be increased without causing phase inversion, and may be used to correct a phase inversion which has already occurred. Finally, the invention may be used to enhance mass transfer rates from one phase to another through the use of phase inversions.
Heat pipe and surface mass transfer cooling of hypersonic vehicle structures
Colwell, Gene T.; Modlin, James M.
1992-01-01
The problem of determining the feasibility of cooling hypersonic vehicle leading-edge structures exposed to severe aerodynamic surface heating using heat pipe and mass transfer cooling techniques is addressed. A description is presented of a numerical finite-difference-based hypersonic leading-edge cooling model incorporating poststartup liquid metal heat pipe cooling with surface transpiration and film cooling to predict the transient structural temperature distributions and maximum surface temperatures of hypersonic vehicle leading edge. An application of this model to the transient cooling of a typical aerospace plane wing leading-edge section. The results of this application indicated that liquid metal heat pipe cooling alone is insufficient to maintain surface temperatures below an assumed maximum level of 1800 K for about one-third of a typical aerospace plane ascent trajectory through the earth's atmosphere.
Dispersed bubble reactor for enhanced gas-liquid-solids contact and mass transfer
Vimalchand, Pannalal; Liu, Guohai; Peng, WanWang; Bonsu, Alexander
2016-01-26
An apparatus to promote gas-liquid contact and facilitate enhanced mass transfer. The dispersed bubble reactor (DBR) operates in the dispersed bubble flow regime to selectively absorb gas phase constituents into the liquid phase. The dispersion is achieved by shearing the large inlet gas bubbles into fine bubbles with circulating liquid and additional pumped liquid solvent when necessary. The DBR is capable of handling precipitates that may form during absorption or fine catalysts that may be necessary to promote liquid phase reactions. The DBR can be configured with multistage counter current flow sections by inserting concentric cylindrical sections into the riser to facilitate annular flow. While the DBR can absorb CO.sub.2 in liquid solvents that may lead to precipitates at high loadings, it is equally capable of handling many different types of chemical processes involving solids (precipitates/catalysts) along with gas and liquid phases.
Analytical solutions for transport processes fluid mechanics, heat and mass transfer
Brenn, Günter
2017-01-01
This book provides analytical solutions to a number of classical problems in transport processes, i.e. in fluid mechanics, heat and mass transfer. Expanding computing power and more efficient numerical methods have increased the importance of computational tools. However, the interpretation of these results is often difficult and the computational results need to be tested against the analytical results, making analytical solutions a valuable commodity. Furthermore, analytical solutions for transport processes provide a much deeper understanding of the physical phenomena involved in a given process than do corresponding numerical solutions. Though this book primarily addresses the needs of researchers and practitioners, it may also be beneficial for graduate students just entering the field. .
An analysis of a charring ablator with thermal nonequilibrium, chemical kinetics, and mass transfer
Clark, R. K.
1973-01-01
The differential equations governing the transient response of a one-dimensional ablative thermal protection system are presented for thermal nonequilibrium between the pyrolysis gases and the char layer and with finite rate chemical reactions occurring. The system consists of three layers (the char layer, the uncharred layer, and an optical insulation layer) with concentrated heat sinks at the back surface and between the second and third layers. The equations are solved numerically by using a modified implicit finite difference scheme to obtain solutions for the thickness of the charred and uncharred layers, surface recession and pyrolysis rates, solid temperatures, porosity profiles, and profiles of pyrolysis-gas temperature, pressure, composition, and flow rate. Good agreement is obtained between numerical results and exact solutions for a number of simplified cases. The complete numerical analysis is used to obtain solutions for an ablative system subjected to a constant heating environment. Effects of thermal, chemical, and mass transfer processes are shown.
Electrochemical model of polyaniline-based memristor with mass transfer step
Energy Technology Data Exchange (ETDEWEB)
Demin, V.A. [National Research Centre ' Kurchatov Institute' , 123182, Moscow (Russian Federation); Moscow Institute of Physics and Technology (State University), 141700, Dolgoprudny, Moscow Region (Russian Federation); Erokhin, V.V. [CNR-IMEM (National Research Council, Institute of Materials for Electronics and Magnetism) and University of Parma, Viale Usberti 7A, 42124, Parma (Italy); Kashkarov, P.K.; Kovalchuk, M.V. [National Research Centre ' Kurchatov Institute' , 123182, Moscow (Russian Federation); Moscow Institute of Physics and Technology (State University), 141700, Dolgoprudny, Moscow Region (Russian Federation); Lomonosov Moscow State University, GSP-1, Leninskie Gory, 119991, Moscow (Russian Federation)
2015-03-10
The electrochemical organic memristor with polyaniline active layer is a stand-alone device designed and realized for reproduction of some synapse properties in the innovative electronic circuits, such as the new field-programmable gate arrays or the neuromorphic networks capable for learning. In this work a new theoretical model of the polyaniline memristor is presented. The developed model of organic memristor functioning was based on the detailed consideration of possible electrochemical processes occuring in the active zone of this device including the mass transfer step of ionic reactants. Results of the calculation have demonstrated not only the qualitative explanation of the characteristics observed in the experiment, but also quantitative similarities of the resultant current values. This model can establish a basis for the design and prediction of properties of more complicated circuits and systems (including stochastic ones) based on the organic memristive devices.
Methods to increase the rate of mass transfer during osmotic dehydration of foods.
Chwastek, Anna
2014-01-01
Traditional methods of food preservation such as freezing, freeze drying (lyophilization), vacuum drying, convection drying are often supplemented by new technologies that enable obtaining of high quality products. Osmotic dehydration is more and more often used during processing of fruits and vegetables. This method allows maintaining good organoleptic and functional properties in the finished product. Obtaining the desired degree of dehydration or saturation of the material with an osmoactive substance often requires elongation of time or use of high temperatures. In recent years much attention was devoted to techniques aimed at increasing the mass transfer between the dehydrated material and the hypertonic solution. The work reviews the literature focused on methods of streamlining the process of osmotic dehydration which include the use of: ultrasound, high hydrostatic pressure, vacuum osmotic dehydration and pulsed electric field.
Mass transfer and oxidation kinetics in an in situ ozone generator.
Mathews, A P; Panda, K K; Ananthi, S; Padmanabhan, K
2004-01-01
An in situ ozone generator design based on a novel type of corona discharge tube construction was tested to examine enhancements in mass transfer and ozonation efficiency over conventional systems. In this design, the discharge gap is kept juxtaposed to the tubular pathway through which the treatment fluid is passed. A porous inner electrode tube is employed in the discharge tube, and the generated ozone diffuses through this porous tube and dissolves and reacts with the contaminants in the fluid that is being treated. The inner porous ceramic tube is grounded while the outer glass electrode is positively charged for corona discharge. Oxidation studies conducted on Reactive Blue 19 dye indicate that the time required for 90% color removal is about half that of a conventional ozone generation and bubble diffusion system at the same ozone dosage.
Mass transfer and sorptive properties of geological samples from the Drigg site
Energy Technology Data Exchange (ETDEWEB)
Berry, J.A.; Brownsword, M.; Gilling, D.; Jefferies, N.L.; Lineham, T.R.; Linsell, I.M.
1990-02-01
This report presents the results of an experimental programme to determine the mass transfer and sorptive properties of selected glacial sand and clays from the Drigg Disposal Site operated by British Nuclear Fuels plc. The hydraulic conductivity of both the sand and clay has been determined and the sensitivity of this parameter to changing water chemistry investigated. The hydrodynamic dispersion properties of the glacial sand were measured in order to aid the interpretation of column sorption experiments. The sorption of strontium and uranium from groundwater onto clay and sand samples has been studied using through-diffusion, column and batch techniques. Employing the batch technique, the effect of a series of humic acid concentrations on distribution ratios for uranium and plutonium has also been investigated. Groundwater and trench leachate were used with both clay and sand. (author).
Heat, Mass and Aerosol Transfers in Spray Conditions for Containment Application
Porcheron, Emmanuel; Lemaitre, Pascal; Nuboer, Amandine; Vendel, Jacques
TOSQAN is an experimental program undertaken by the Institut de Radioprotection et de Surété Nucleaire (IRSN) in order to perform thermal hydraulic containment studies. The TOSQAN facility is a large enclosure devoted to simulating typical accidental thermal hydraulic flow conditions in nuclear Pressurized Water Reactor (PWR) containment. The TOSQAN facility, which is highly instrumented with non-intrusive optical diagnostics, is particularly adapted to nuclear safety CFD code validation. The present work is devoted to studying the interaction of a water spray injection used as a mitigation means in order to reduce the gas pressure and temperature in the containment, to produce gases mixing and washout of fission products. In order to have a better understanding of heat and mass transfers between spray droplets and the gas mixture, and to analyze mixing effects due to spray activation, we performed detailed characterization of the two-phase flow.
Directory of Open Access Journals (Sweden)
A. Vlasenko
2010-08-01
Full Text Available Formaldehyde measurements can provide useful information about photochemical activity in ambient air, given that HCHO is formed via numerous oxidation processes. Proton transfer reaction mass spectrometry (PTR-MS is an online technique that allows measurement of VOCs at the sub-ppbv level with good time resolution. PTR-MS quantification of HCHO is hampered by the humidity dependence of the instrument sensitivity, with higher humidity leading to loss of PTR-MS signal. In this study we present an analytical, first principles approach to correct the PTR-MS HCHO signal according to the concentration of water vapor in sampled air. The results of the correction are validated by comparison of the PTR-MS results to those from a Hantzsch fluorescence monitor which does not have the same humidity dependence. Results are presented for an intercomparison made during a field campaign in rural Ontario at Environment Canada's Centre for Atmospheric Research Experiments.
Dynamic model of heat and mass transfer in rectangular adsorber of a solar adsorption machine
Chekirou, W.; Boukheit, N.; Karaali, A.
2016-10-01
This paper presents the study of a rectangular adsorber of solar adsorption cooling machine. The modeling and the analysis of the adsorber are the key point of such studies; because of the complex coupled heat and mass transfer phenomena that occur during the working cycle. The adsorber is heated by solar energy and contains a porous medium constituted of activated carbon AC-35 reacting by adsorption with methanol. To study the solar collector type effect on system's performances, the used model takes into account the variation of ambient temperature and solar intensity along a simulated day, corresponding to a total daily insolation of 26.12 MJ/m2 with ambient temperature average of 27.7 °C, which is useful to know the daily thermal behavior of the rectangular adsorber.
Heat or mass transfer from a sphere in Stokes flow at low Péclet number
Bell, Christopher G.
2013-04-01
We consider the low Péclet number, Pe≪1, asymptotic solution for steady-state heat or mass transfer from a sphere immersed in Stokes flow with a Robin boundary condition on its surface, representing Newton cooling or a first-order chemical reaction. The application of Van Dyke\\'s rule up to terms of O(Pe3) shows that the O(Pe3logPe) terms in the expression for the average Nusselt/Sherwood number are twice those previously derived in the literature. Inclusion of the O(Pe3) terms is shown to increase the range of validity of the expansion. © 2012 Elsevier Ltd. All rights reserved.
Processes of heat and mass transfer in straw bales using flue gasses as a drying medium
Directory of Open Access Journals (Sweden)
Goryl Wojciech
2016-01-01
Full Text Available Moisture content is a main problem of using straw in form of bales for energy production. The paper presents possibility of straw drying in dedicated, innovative and patented in Poland straw dryers which using flue gasses as a drying medium. Paper presents an improved way of drying which proved to be very sufficient. Temperature and humidity of straw during the process of drying were measured. The measurements helped understand and perform numerical model of heat and mass transfer inside the straw bale. By using CFD codes it was possible to perform analysis of phenomenon occurring inside the dried straw bale. Based on the CFD model, proposals of the optimization and improvement process of drying have been discussed. Experimental and computational data have been compared in terms of convergence. A satisfying degree of agreement has been achieved. Applying improved drying method, homogenous field of moisture content and temperature in the straw bale is achieved in a very cost effective way.
Processes of heat and mass transfer in straw bales using flue gasses as a drying medium
Goryl, Wojciech; Szubel, Mateusz; Filipowicz, Mariusz
2016-03-01
Moisture content is a main problem of using straw in form of bales for energy production. The paper presents possibility of straw drying in dedicated, innovative and patented in Poland straw dryers which using flue gasses as a drying medium. Paper presents an improved way of drying which proved to be very sufficient. Temperature and humidity of straw during the process of drying were measured. The measurements helped understand and perform numerical model of heat and mass transfer inside the straw bale. By using CFD codes it was possible to perform analysis of phenomenon occurring inside the dried straw bale. Based on the CFD model, proposals of the optimization and improvement process of drying have been discussed. Experimental and computational data have been compared in terms of convergence. A satisfying degree of agreement has been achieved. Applying improved drying method, homogenous field of moisture content and temperature in the straw bale is achieved in a very cost effective way.
On the theory of Ostwald ripening in the presence of different mass transfer mechanisms
Alexandrov, D. V.
2016-04-01
A theoretical description of the concluding stage of Ostwald ripening based on the Slezov theory (Slezov, 1978) and recently developed approach (Alexandrov, 2015) is formulated. The present analysis focuses on the formation and relaxation of the particle size distribution function from the intermediate stage of ripening process to its final state, which is described by the universal distribution. The boundaries of the transition layer in the vicinity of a blocking point are found. The time-dependent corrections to the growth rates of crystals and the distribution functions are determined for different mass transfer mechanisms. The obtained analytical distributions are in good agreement with experimental data. All analytical results are presented in a form directly suitable for their use in applications.
Fulazzaky, Mohamad Ali; Nuid, Maria; Aris, Azmi; Muda, Khalida
2017-07-13
Understanding of mass transfer kinetics is important for biosorption of nitrogen compounds from palm oil mill effluent (POME) to gain a mechanistic insight into future biological processes for the treatment of high organic loading wastewater. In this study, the rates of global and sequential mass transfer were determined using the modified mass transfer factor equations for the experiments to remove nitrogen by aerobic granular sludge accumulation in a sequencing batch reactor (SBR). The maximum efficiencies as high as 97% for the experiment run at [kL a]g value of 1421.8 h-1 and 96% for the experiment run at [kL a]g value of 9.6 × 1037 h-1 were verified before and after the addition of Serratia marcescens SA30, respectively. The resistance of mass transfer could be dependent on external mass transfer that controls the transport of nitrogen molecule along the experimental period of 256 days. The increase in [kL a]g value leading to increased performance of the SBR was verified to contribute to the future applications of the SBR because this phenomenon provides new insight into the dynamic response of biological processes to treat POME.
Fukuda, Makoto; Yoshimura, Kengo; Namekawa, Koki; Sakai, Kiyotaka
2017-06-01
The objective of the present study is to evaluate the effect of filtration coefficient and internal filtration on dialysis fluid flow and mass transfer coefficient in dialyzers using dimensionless mass transfer correlation equations. Aqueous solution of vitamin B12 clearances were obtained for REXEED-15L as a low flux dialyzer, and APS-15EA and APS-15UA as high flux dialyzers. All the other design specifications were identical for these dialyzers except for filtration coefficient. The overall mass transfer coefficient was calculated, moreover, the exponents of Reynolds number (Re) and film mass transfer coefficient of the dialysis-side fluid (k D) for each flow rate were derived from the Wilson plot and dimensionless correlation equation. The exponents of Re were 0.4 for the low flux dialyzer whereas 0.5 for the high flux dialyzers. Dialysis fluid of the low flux dialyzer was close to laminar flow because of its low filtration coefficient. On the other hand, dialysis fluid of the high flux dialyzers was assumed to be orthogonal flow. Higher filtration coefficient was associated with higher k D influenced by mass transfer rate through diffusion and internal filtration. Higher filtration coefficient of dialyzers and internal filtration affect orthogonal flow of dialysis fluid.
Orgill, James J; Atiyeh, Hasan K; Devarapalli, Mamatha; Phillips, John R; Lewis, Randy S; Huhnke, Raymond L
2013-04-01
Trickle-bed reactor (TBR), hollow fiber membrane reactor (HFR) and stirred tank reactor (STR) can be used in fermentation of sparingly soluble gasses such as CO and H2 to produce biofuels and bio-based chemicals. Gas fermenting reactors must provide high mass transfer capabilities that match the kinetic requirements of the microorganisms used. The present study compared the volumetric mass transfer coefficient (K(tot)A/V(L)) of three reactor types; the TBR with 3 mm and 6 mm beads, five different modules of HFRs, and the STR. The analysis was performed using O2 as the gaseous mass transfer agent. The non-porous polydimethylsiloxane (PDMS) HFR provided the highest K(tot)A/V(L) (1062 h(-1)), followed by the TBR with 6mm beads (421 h(-1)), and then the STR (114 h(-1)). The mass transfer characteristics in each reactor were affected by agitation speed, and gas and liquid flow rates. Furthermore, issues regarding the comparison of mass transfer coefficients are discussed. Copyright © 2013 Elsevier Ltd. All rights reserved.
Ahmadi, Hamid; Bolinius, Damien Johann; Jahnke, Annika; MacLeod, Matthew
2016-12-01
Plant leaves play an important role in the fate of hydrophobic organic contaminants (HOCs) in the environment. Yet much remains unknown about the permeability of leaves by HOCs. In this pilot study we measured (i) the kinetics of mass transfer of three polycyclic aromatic hydrocarbons (PAHs) and six polychlorinated biphenyls between a spiked and an unspiked sheet of polydimethylsiloxane (PDMS) in direct contact with each other for 24 h and (ii) kinetics of mass transfer of two PAHs through leaves and low-density polyethylene (LDPE) in a passive dosing experiment by inserting these matrices between the two sheets of PDMS for 48 h. The kinetics of mass transfer of fluoranthene between PDMS sheets in direct contact were a factor of 12 slower than those reported in the literature. The kinetics of mass transfer of fluorene and phenanthrene through leaves were within the range of those previously reported for 2,4-dichlorophenoxyacetic acid through isolated cuticles. Our results provide a proof-of-concept demonstration that the passive dosing method applied in this study can be used to measure the mass transfer coefficients of organic chemicals through leaves. Key recommendations for future experiments are to load the PDMS at the highest feasible concentrations to avoid working at analyte levels close to the limit of detection, to keep the leaves moist and to minimize potential pathways for contamination of the PDMS sheets by exposure to laboratory air. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.
Shi, Zhi-Jian; Guo, Qiong; Xu, Yi-Qun; Wu, Dan; Liao, Si-Mo; Zhang, Fu-Yue; Zhang, Zheng-Zhe; Jin, Ren-Cun
2017-11-01
In this study, the mass transfer, rheological behavior and fractal dimension of anaerobic ammonium oxidation (anammox) granules in upflow anaerobic sludge blanket reactors at various temperatures (8.5-34.5°C) and upflow velocities (0.06, 0.18mh-1) were investigated. The results demonstrated that a lower temperature increased the external mass transfer coefficient and apparent viscosity and impaired the performance of anammox granules. The external mass transfer coefficient was decreased, but efficient nitrogen removal of up to 96% was achieved under high upflow velocity, which also decreased the apparent viscosity. Furthermore, a fractal dimension of up to 2.93 achieved at low temperature was higher than the previously reported values for mesophilic anammox granules. A higher upflow velocity was associated with the lower fractal dimension. Because of the disturbance in granule flaking, the effectiveness factor was less suitable than the external mass transfer coefficient for characterization of mass transfer resistance. Copyright © 2017 Elsevier Ltd. All rights reserved.
Yao, Kangning; Chi, Yong; Wang, Fei; Yan, Jianhua; Ni, Mingjiang; Cen, Kefa
2016-01-01
A commonly used aeration device at present has the disadvantages of low mass transfer rate because the generated bubbles are several millimeters in diameter which are much bigger than microbubbles. Therefore, the effect of a microbubble on gas-liquid mass transfer and wastewater treatment process was investigated. To evaluate the effect of each bubble type, the volumetric mass transfer coefficients for microbubbles and conventional bubbles were determined. The volumetric mass transfer coefficient was 0.02905 s(-1) and 0.02191 s(-1) at a gas flow rate of 0.67 L min(-1) in tap water for microbubbles and conventional bubbles, respectively. The degradation rate of simulated municipal wastewater was also investigated, using aerobic activated sludge and ozone. Compared with the conventional bubble generator, the chemical oxygen demand (COD) removal rate was 2.04, 5.9, 3.26 times higher than those of the conventional bubble contactor at the same initial COD concentration of COD 200 mg L(-1), 400 mg L(-1), and 600 mg L(-1), while aerobic activated sludge was used. For the ozonation process, the rate of COD removal using microbubble generator was 2.38, 2.51, 2.89 times of those of the conventional bubble generator. Based on the results, the effect of initial COD concentration on the specific COD degradation rate were discussed in different systems. Thus, the results revealed that microbubbles could enhance mass transfer in wastewater treatment and be an effective method to improve the degradation of wastewater.
Directory of Open Access Journals (Sweden)
Khamidun Mohd Hairul
2017-01-01
Full Text Available The understanding resistance of mass transfer for adsorption of phosphate (PO43- onto industrial waste such as clay brick and ceramic as an adsorbent is important to verify. This study presented the removal of (PO43- from a synthetic solution by adsorbing onto the clay brick and ceramic wastes in a plug flow column (PFC. The experimental results showed that increasing the flow rate was decreases the breakthrough time. The mass transfer factor (MTF models were used to study the behaviours of breakthrough curve and to determine the resistance of mass transfer. The MTF models verified that the resistance of mass transfer could be dependent on porous diffusion until the percentage of outflow reaches 72% for clay brick waste and 86% for ceramic waste, even though film mass transfer can play a minor role in controlling the movement of (PO43- from the bulk water to film zone. The results of MTF models coefficient could be indicated to increase the capacity of clay brick and ceramic wastes to adsorb (PO43- from synthetic solution, it needs to develop the porosity of these adsorbents by either physical or chemical modification.