WorldWideScience

Sample records for negative heat capacity

  1. Quantum Confinement and Negative Heat Capacity

    OpenAIRE

    Serra, Pablo; Carignano, Marcelo; Alharbi, Fahhad; Kais, Sabre

    2013-01-01

    Thermodynamics dictates that the specific heat of a system is strictly non-negative. However, in finite classical systems there are well known theoretical and experimental cases where this rule is violated, in particular finite atomic clusters. Here, we show for the first time that negative heat capacity can also occur in finite quantum systems. The physical scenario on which this effect might be experimentally observed is discussed. Observing such an effect might lead to the design of new li...

  2. Negative heat capacity of sodium clusters

    CERN Document Server

    Reyes-Nava, J A; Michaelian, K; Reyes-Nava, Juan A.; Garzon, Ignacio L.; Michaelian, Karo

    2003-01-01

    Heat capacities of Na_N, N = 13, 20, 55, 135, 142, and 147, clusters have been investigated using a many-body Gupta potential and microcanonical molecular dynamics simulations. Negative heat capacities around the cluster melting-like transition have been obtained for N = 135, 142, and 147, but the smaller clusters (N = 13, 20, and 55) do not show this peculiarity. By performing a survey of the cluster potential energy landscape (PEL), it is found that the width of the distribution function of the kinetic energy and the spread of the distribution of potential energy minima (isomers), are useful features to determine the different behavior of the heat capacity as a function of the cluster size. The effect of the range of the interatomic forces is studied by comparing the heat capacities of the Na_55 and Cd_55 clusters. It is shown that by decreasing the range of the many-body interaction, the distribution of isomers characterizing the PEL is modified appropriately to generate a negative heat capacity in the Cd_...

  3. Negative thermal expansion and anomalies of heat capacity of LuB50 at low temperatures.

    Science.gov (United States)

    Novikov, V V; Zhemoedov, N A; Matovnikov, A V; Mitroshenkov, N V; Kuznetsov, S V; Bud'ko, S L

    2015-09-28

    Heat capacity and thermal expansion of LuB50 boride were experimentally studied in the 2-300 K temperature range. The data reveal an anomalous contribution to the heat capacity at low temperatures. The value of this contribution is proportional to the first degree of temperature. It was identified that this anomaly in heat capacity is caused by the effect of disorder in the LuB50 crystalline structure and it can be described in the soft atomic potential model (SAP). The parameters of the approximation were determined. The temperature dependence of LuB50 heat capacity in the whole temperature range was approximated by the sum of SAP contribution, Debye and two Einstein components. The parameters of SAP contribution for LuB50 were compared to the corresponding values for LuB66, which was studied earlier. Negative thermal expansion at low temperatures was experimentally observed for LuB50. The analysis of the experimental temperature dependence for the Gruneisen parameter of LuB50 suggested that the low-frequency oscillations, described in SAP mode, are responsible for the negative thermal expansion. Thus, the glasslike character of the behavior of LuB50 thermal characteristics at low temperatures was confirmed.

  4. Liquid heat capacity lasers

    Science.gov (United States)

    Comaskey, Brian J.; Scheibner, Karl F.; Ault, Earl R.

    2007-05-01

    The heat capacity laser concept is extended to systems in which the heat capacity lasing media is a liquid. The laser active liquid is circulated from a reservoir (where the bulk of the media and hence waste heat resides) through a channel so configured for both optical pumping of the media for gain and for light amplification from the resulting gain.

  5. Heat Capacity in Proteins

    Science.gov (United States)

    Prabhu, Ninad V.; Sharp, Kim A.

    2005-05-01

    Heat capacity (Cp) is one of several major thermodynamic quantities commonly measured in proteins. With more than half a dozen definitions, it is the hardest of these quantities to understand in physical terms, but the richest in insight. There are many ramifications of observed Cp changes: The sign distinguishes apolar from polar solvation. It imparts a temperature (T) dependence to entropy and enthalpy that may change their signs and which of them dominate. Protein unfolding usually has a positive ΔCp, producing a maximum in stability and sometimes cold denaturation. There are two heat capacity contributions, from hydration and protein-protein interactions; which dominates in folding and binding is an open question. Theoretical work to date has dealt mostly with the hydration term and can account, at least semiquantitatively, for the major Cp-related features: the positive and negative Cp of hydration for apolar and polar groups, respectively; the convergence of apolar group hydration entropy at T ≈ 112°C; the decrease in apolar hydration Cp with increasing T; and the T-maximum in protein stability and cold denaturation.

  6. Direct experimental evidence for a negative heat capacity in the liquid-to-gas like phase transition in hydrogen cluster ions backbending of the caloric curve

    CERN Document Server

    Gobet, F; Carré, M; Farizon, B; Farizon, M; Gaillard, M J; Maerk, T D; Scheier, P

    2002-01-01

    By (i) selecting specific decay reactions in high energy collisions (60 keV/amu) of hydrogen cluster ions with a helium target (utilizing event-by-event data of a recently developed multi-coincidence experiment) and by (ii) deriving corresponding temperatures for these microcanonical cluster ensembles (analyzing the respective fragment distributions) we are able to construct caloric curves for ii sub 3 sup + (ii sub 2) sub m cluster ions (6 <= m <= 14). All individual curves and the mean of these curves show a backbending in the plateau region thus constituting direct evidence for a negative microcanonical heat capacity in the liquid-to-gas like transition of these finite systems.

  7. Frequency-dependent heat capacity

    DEFF Research Database (Denmark)

    Behrens, Claus Flensted

    and as a thermometer. The aim of the work is to improve and understand this planar heater experiment. I find: • Carbon has advantages as heater material over the traditionally used metal (nickel) heaters. • The thermal coupling to the surrounding temperature bath should not be made through the liquid but through......The frequency–dependent heat capacity of super-cooled glycerol near the glass transition is measured using the 3w detection technique. An electrical conducting thin film with a temperature–dependent electrical resistance is deposited on a substrate. The thin film is used simultaneously as a heater...... the substrate. • Edge effects, as a result of the finite size of the heater, play an important role. The traditionally way of dealing with these effects are not entirely correct. • The Cole–Davidson function with bCD...

  8. Heat Capacity of 1D Molecular Chains

    Science.gov (United States)

    Bagatskii, M. I.; Barabashko, M. S.; Sumarokov, V. V.; Jeżowski, A.; Stachowiak, P.

    2017-04-01

    The heat capacity of 1D chains of nitrogen and methane molecules (adsorbed in the outer grooves of bundles of closed-cap single-walled carbon nanotubes) has been studied in the temperature ranges 2-40 and 2-60 K, respectively. The temperature dependence of the heat capacity of 1D chains of nitrogen molecules below 3 K is close to a linear. It was found that the rotational heat capacity of methane molecules is a significant part of the total heat capacity of the chains throughout the whole investigated temperature range, whereas in the case of nitrogen, the librations are significant only above 15 K. The dependence of the heat capacity for methane below 10 K indicates the presence of a Schottky anomaly caused by the tunneling between the lowest energy levels of the CH4 molecule rotational spectra. Characteristic features observed in the temperature dependence of the heat capacity of 1D methane crystals are also discussed.

  9. The Heat Capacity of Ideal Gases

    Science.gov (United States)

    Scott, Robert L.

    2006-01-01

    The heat capacity of an ideal gas has been shown to be calculable directly by statistical mechanics if the energies of the quantum states are known. However, unless one makes careful calculations, it is not easy for a student to understand the qualitative results. Why there are maxima (and occasionally minima) in heat capacity-temperature curves…

  10. Heat Capacity Mapping Mission: 1978-1980

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — NASA's Heat Capacity Mapping Mission (HCMM) project collected Earth data in the visible and thermal bands between April 1978 and September 1980. This was an...

  11. Heat Capacity Mapping Mission: 1978-1980

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — NASA's Heat Capacity Mapping Mission (HCMM) project collected Earth data in the visible and thermal bands between April 1978 and September 1980. This was an...

  12. Heat Capacity of Hydrous Silicate Melts

    Science.gov (United States)

    Robert, G.; Whittington, A. G.; Stechern, A.; Behrens, H.

    2015-12-01

    We determined the heat capacities of four series of glasses and liquids of basaltic and basaltic andesite compositions including two natural remelts from Fuego volcano, Guatemala, and two Fe-free analogs. The samples are low-alkali, Ca- and Mg-rich aluminosilicates with non-bridging oxygen to tetrahedrally-coordinated cation ratios (NBO/T) ranging between 0.33 and 0.67. Differential scanning calorimetry measurements were performed at atmospheric pressure between room temperature and ≈100 K above the glass transition for hydrous samples and up to ≈1800 K for dry samples. The water contents investigated range up to 5.34 wt.% (16.4 mol%). Water does not measurably affect the heat capacity of glasses (T heat capacity, which generally gets larger with increasing water content and with decreasing polymerization. The onset of the glass transition in hydrous samples also occurs below the Dulong-Petit limit of 3R/g atom. We see little change in liquid heat capacity with increasing water content; hydrous liquid heat capacities are within 3-6% of the dry liquid, at low temperatures just above the glass transition. However, dry liquids show a decrease in heat capacity with increasing temperature above the glass transition, from supercooled to superliquidus temperatures. Liquid heat capacity values just above the glass transition range between 95-100 J/mol K, whereas liquid heat capacity values at superliquidus temperatures are between 85-91 J/mol K. Comparison with other studies of the heat capacity of hydrous glasses and liquids shows that the liquid heat capacity of strongly depolymerized samples (NBO/T ≥ 0.8) increases with increasing water content, whereas depolymerized samples (0.4 ≤ NBO/T ≤ 0.8) or polymerized samples (NBO/T ≤ 0.4) generally show little change or a moderate decrease in liquid heat capacity with increasing water content.

  13. The heat capacity of solid antimony selenide

    Science.gov (United States)

    Pashinkin, A. S.; Malkova, A. S.; Mikhailova, M. S.

    2008-06-01

    The literature data on the heat capacity of solid antimony selenide over the temperature range 53 K- T m were analyzed. The heat capacity of Sb2Se3 was measured from 350 to 600 K on a DSM-2M calorimeter. The experimental data were used to calculate the dependence C p = a + bT + cT -2 and the thermodynamic functions of solid Sb2Se3 over the temperature range 298.15 700 K.

  14. MEASUREMENT OF SPECIFIC HEAT CAPACITY OF SALTSTONE

    Energy Technology Data Exchange (ETDEWEB)

    Harbour, J; Vickie Williams, V

    2008-09-29

    One of the goals of the Saltstone variability study is to identify (and quantify the impact of) the operational and compositional variables that control or influence the important processing and performance properties of Saltstone grout mixtures. The heat capacity of the Saltstone waste form is one of the important properties of Saltstone mixes that was last measured at SRNL in 1997. It is therefore important to develop a core competency for rapid and accurate analysis of the specific heat capacity of the Saltstone mixes in order to quantify the impact of compositional and operational variations on this property as part of the variability study. The heat capacity, coupled with the heat of hydration data obtained from isothermal calorimetry for a given Saltstone mix, can be used to predict the maximum temperature increase in the cells within the vaults of the Saltstone Disposal Facility (SDF). The temperature increase controls the processing rate and the pour schedule. The maximum temperature is also important to the performance properties of the Saltstone. For example, in mass pours of concrete or grout of which Saltstone is an example, the maximum temperature increase and the maximum temperature difference (between the surface and the hottest location) are controlled to ensure durability of the product and prevent or limit the cracking caused by the thermal gradients produced during curing. This report details the development and implementation of a method for the measurement of the heat capacities of Saltstone mixes as well as the heat capacities of the cementitious materials of the premix and the simulated salt solutions used to batch the mixes. The developed method utilizes the TAM Air isothermal calorimeter and takes advantage of the sophisticated heat flow measurement capabilities of the instrument. Standards and reference materials were identified and used to validate the procedure and ensure accuracy of testing. Heat capacities of Saltstone mixes were

  15. Residential Variable-Capacity Heat Pumps Sized to Heating Loads

    Energy Technology Data Exchange (ETDEWEB)

    Munk, Jeffrey D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jackson, Roderick K. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Odukomaiya, Adewale [Georgia Inst. of Technology, Atlanta, GA (United States); Gehl, Anthony C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2014-01-01

    Variable capacity heat pumps are an emerging technology offering significant energy savings potential and improved efficiency. With conventional single-speed systems, it is important to appropriately size heat pumps for the cooling load as over-sizing would result in cycling and insufficient latent capacity required for humidity control. These appropriately sized systems are often under-sized for the heating load and require inefficient supplemental electric resistance heat to meet the heating demand. Variable capacity heat pumps address these shortcomings by providing an opportunity to intentionally size systems for the dominant heating season load without adverse effects of cycling or insufficient dehumidification in the cooling season. This intentionally-sized system could result in significant energy savings in the heating season, as the need for inefficient supplemental electric resistance heat is drastically reduced. This is a continuation of a study evaluating the energy consumption of variable capacity heat pumps installed in two unoccupied research homes in Farragut, a suburb of Knoxville, Tennessee. In this particular study, space conditioning systems are intentionally sized for the heating season loads to provide an opportunity to understand and evaluate the impact this would have on electric resistance heat use and dehumidification. The results and conclusions drawn through this research are valid and specific for portions of the Southeastern and Midwestern United States falling in the mixed-humid climate zone. While other regions in the U.S. do not experience this type of climate, this work provides a basis for, and can help understand the implications of other climate zones on residential space conditioning energy consumption. The data presented here will provide a framework for fine tuning residential building EnergyPlus models that are being developed.

  16. Residential Variable-Capacity Heat Pumps Sized to Heating Loads

    Energy Technology Data Exchange (ETDEWEB)

    Munk, Jeffrey D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jackson, Roderick K. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Odukomaiya, Adewale [Georgia Inst. of Technology, Atlanta, GA (United States); Gehl, Anthony C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2014-01-01

    Variable capacity heat pumps are an emerging technology offering significant energy savings potential and improved efficiency. With conventional single-speed systems, it is important to appropriately size heat pumps for the cooling load as over-sizing would result in cycling and insufficient latent capacity required for humidity control. These appropriately sized systems are often under-sized for the heating load and require inefficient supplemental electric resistance heat to meet the heating demand. Variable capacity heat pumps address these shortcomings by providing an opportunity to intentionally size systems for the dominant heating season load without adverse effects of cycling or insufficient dehumidification in the cooling season. This intentionally-sized system could result in significant energy savings in the heating season, as the need for inefficient supplemental electric resistance heat is drastically reduced. This is a continuation of a study evaluating the energy consumption of variable capacity heat pumps installed in two unoccupied research homes in Farragut, a suburb of Knoxville, Tennessee. In this particular study, space conditioning systems are intentionally sized for the heating season loads to provide an opportunity to understand and evaluate the impact this would have on electric resistance heat use and dehumidification. The results and conclusions drawn through this research are valid and specific for portions of the Southeastern and Midwestern United States falling in the mixed-humid climate zone. While other regions in the U.S. do not experience this type of climate, this work provides a basis for, and can help understand the implications of other climate zones on residential space conditioning energy consumption. The data presented here will provide a framework for fine tuning residential building EnergyPlus models that are being developed.

  17. Finite heat-capacity effects in regenerators

    Science.gov (United States)

    de Waele, A. T. A. M.

    2012-01-01

    This paper deals with the influence the finite heat capacity of the matrix of regenerators on the performance of cryocoolers. The dynamics of the various parameters is treated in the harmonic approximation focussing on the finite heat-capacity effects, real-gas effects, and heat conduction. It is assumed that the flow resistance is zero, that the heat contact between the gas and the matrix is perfect, and that there is no mass storage in the matrix. Based on an energy-flow analysis, the limiting temperature, temperature profiles in the regenerator, and cooling powers are calculated. The discussion refers to pulse-tube refrigerators, but it is equally relevant for Stirling coolers and GM-coolers.

  18. Heat capacities of the mixtures of ionic liquids with acetonitrile

    Energy Technology Data Exchange (ETDEWEB)

    Waliszewski, Dariusz, E-mail: waliszew@uni.lodz.p [Department of Physical Chemistry, University of Lodz, Pomorska 165, PL-90 236 Lodz (Poland); Piekarski, Henryk [Department of Physical Chemistry, University of Lodz, Pomorska 165, PL-90 236 Lodz (Poland)

    2010-02-15

    Isobaric specific heat capacities were measured for left brace1-hexyl-3-methylimidazolium tetrafluoroborate (HMIMBF{sub 4}) + acetonitrile (MeCN)right brace and left brace1-methyl-3-octylimidazolium tetrafluoroborate (OMIMBF{sub 4}) + acetonitrileright brace within the whole range of composition and temperatures from (283.15 to 323.15) K. The excess molar heat capacities were calculated from the experimental results and satisfactorily fitted to Redlich-Kister type polynomials for several selected temperatures. Negative deviations from the additivity of molar heat capacities were observed within the whole composition range of (HMIBMF{sub 4} + MeCN) and (OMIMBF{sub 4} + MeCN). The results obtained have been interpreted in terms of interactions between ionic liquids and acetonitrile.

  19. Phonon dispersion and heat capacity in polyfuran

    Science.gov (United States)

    Ali, Parvej; Srivastava, Seema; Ali Khan, Irfan; Gupta, V. D.; Ansari, Saif-ul-Islam

    A study of the normal modes of vibration and their dispersion in polyfuran (Pfu) based on the Urey-Bradley force field is reported. It provides a detailed interpretation of IR and Raman spectra. Characteristic features of dispersion curves such as regions of high density-of-states, repulsion and character mixing of dispersive modes are discussed. Predictive values of heat capacity as a function of temperature are calculated.

  20. Method of Measurement Isobaric Heat Capacity of the Organic Liquid

    Directory of Open Access Journals (Sweden)

    Yu.A. Neruchev

    2013-12-01

    Full Text Available A technique for measuring the heat capacity of liquids on modernized authors the installation of IT-Cp-400 is considered. The results of measurements the isobaric heat capacity of some bromosubstituted n-alkanes is presented.

  1. Chemical thermodynamics of nuclear materials. 8. The high-temperature heat capacity of unalloyed plutonium metal

    Energy Technology Data Exchange (ETDEWEB)

    Oetting, F.L.; Adams, R.O. (Rockwell International Corp., Golden, CO (USA). Energy Systems Group)

    1983-06-01

    The heat capacity of pure plutonium metal has been determined from 330 to 700 K by adiabatic calorimetry. This includes measurements on the ..cap alpha..-, ..beta..-, ..gamma..-, and delta-phases. A large contribution to the heat capacity, especially in the delta-phase, is due to the electronic heat capacity. A negative anharmonic heat capacity is found for the ..cap alpha..-phase. The enthalpies and temperatures of the transitions between these phases were also determined. With the use of thermodynamic quantities on the delta'-, epsilon-, and (1)-phases available from the literature, the thermal functions for pure plutonium metal were calculated to 1000 K.

  2. Capacity recovery after storage negatively precharged nickel hydrogen cells

    Science.gov (United States)

    Lowery, John E.

    1993-01-01

    Tests were conducted to investigate the recovery of capacity lost during open circuit storage of negatively precharged nickel hydrogen batteries. Four Eagle Picher RNH-90-3 cells were used in the tests. Recovery procedures and test results are presented in outline and graphic form.

  3. Negative Knudsen force on heated microbeams

    KAUST Repository

    Zhu, Taishan

    2011-11-18

    Knudsen force acting on a heated microbeam adjacent to a cold substrate in a rarefied gas is a mechanical force created by unbalanced thermal gradients. The measured force has its direction pointing towards the side with a lower thermal gradient and its magnitude vanishes in both continuum and free-molecule limits. In our previous study, negative Knudsen forces were discovered at the high Knudsen regime before diminishing in the free-molecule limit. Such a phenomenon was, however, neither observed in experiment [A. Passian et al., Phys. Rev. Lett. 90, 124503 (2003)], nor captured in the latest numerical study [J. Nabeth et al., Phys. Rev. E 83, 066306 (2011)]. In this paper, the existence of such a negative Knudsen force is further confirmed using both numerical simulation and theoretical analysis. The asymptotic order of the Knudsen force near the collisionless limit is analyzed and the analytical expression of its leading term is provided, from which approaches for the enhancement of negative Knudsen forces are proposed. The discovered phenomenon could find its applications in novel mechanisms for pressure sensing and actuation.

  4. Temperature dependence of electronic heat capacity in Holstein model

    CERN Document Server

    Fialko, N S; Lakhno, V D

    2015-01-01

    The dynamics of charge migration was modeled to calculate temperature dependencies of its thermodynamic equilibrium values such as energy and electronic heat capacity in homogeneous adenine fragments. The energy varies from nearly polaron one at T~0 to midpoint of the conductivity band at high temperatures. The peak on the graph of electronic heat capacity is observed at the polaron decay temperature.

  5. Heat capacity prediction of complex molecules by mass connectivity index

    Directory of Open Access Journals (Sweden)

    Koutchoukali O.

    2013-07-01

    Full Text Available Heat capacity prediction and estimation methods of solid organic compounds in terms of temperature are limited, particularly concerning complex molecules with functional groups such as active principles and intermediaries used in pharmaceutical field. Recently a correlation between heat capacity at constant pressure (Cp, temperature and a new concept named mass connectivity index (MCI, for ionic liquids, was published [1-3]. In this predictive method, heat capacity can be calculated at different temperatures, if standard heat capacity at 298.15 K is known. The effect of molecular structure on heat capacity is accounted for in this model by the mass connectivity index, a molecular descriptor, which differentiates between compounds. The Valderrama generalized correlation admits, in addition, two universal coefficients, which are obtained from experimental data regression. In the present work, a similar approach is used to predict solid state heat capacity of organics and pharmaceutical products. In order to find model parameters, a database was grouped comprising (104 different compounds and a set of more than 5,791 experimental values of solid state Cps obtained from literature. These collected data were used in multiple linear regression to find model parameters. It was found that the values of predicted heat capacities of compounds non-included in the database were good; they are quite close to the ones presented in the literature. Moreover, this method is simple to use, since only molecular structure of the component and its solid state heat capacity at 298.15 K should be known.

  6. Solvation thermodynamics and heat capacity of polar and charged solutes in water.

    Science.gov (United States)

    Sedlmeier, Felix; Netz, Roland R

    2013-03-21

    The solvation thermodynamics and in particular the solvation heat capacity of polar and charged solutes in water is studied using atomistic molecular dynamics simulations. As ionic solutes we consider a F(-) and a Na(+) ion, as an example for a polar molecule with vanishing net charge we take a SPC/E water molecule. The partial charges of all three solutes are varied in a wide range by a scaling factor. Using a recently introduced method for the accurate determination of the solvation free energy of polar solutes, we determine the free energy, entropy, enthalpy, and heat capacity of the three different solutes as a function of temperature and partial solute charge. We find that the sum of the solvation heat capacities of the Na(+) and F(-) ions is negative, in agreement with experimental observations, but our results uncover a pronounced difference in the heat capacity between positively and negatively charged groups. While the solvation heat capacity ΔC(p) stays positive and even increases slightly upon charging the Na(+) ion, it decreases upon charging the F(-) ion and becomes negative beyond an ion charge of q = -0.3e. On the other hand, the heat capacity of the overall charge-neutral polar solute derived from a SPC/E water molecule is positive for all charge scaling factors considered by us. This means that the heat capacity of a wide class of polar solutes with vanishing net charge is positive. The common ascription of negative heat capacities to polar chemical groups might arise from the neglect of non-additive interaction effects between polar and apolar groups. The reason behind this non-additivity is suggested to be related to the second solvation shell that significantly affects the solvation thermodynamics and due to its large spatial extent induces quite long-ranged interactions between solvated molecular parts and groups.

  7. Heat capacities of ionic liquids and their heats of solution in molecular liquids

    Energy Technology Data Exchange (ETDEWEB)

    Waliszewski, D. [Department of Physical Chemistry, Univesity of Lodz, PL-90 236 Lodz (Poland); Stepniak, I. [Faculty of Chemical Technology, Poznan University of Technology, PL-60 965 Poznan (Poland); Piekarski, H. [Department of Physical Chemistry, Univesity of Lodz, PL-90 236 Lodz (Poland); Lewandowski, A. [Faculty of Chemical Technology, Poznan University of Technology, PL-60 965 Poznan (Poland)]. E-mail: andrzej.lewandowski@put.poznan.pl

    2005-08-01

    Heat capacities of ionic liquids (IL): 1-ethyl-3-methylimidazolium tetrafluoroborate (EMImBF{sub 4}), 1-ethyl-3-methyl imidazolium bis((trifluoromethyl)sulfonyl) imide (EMImN(CF{sub 3}SO{sub 2}){sub 2}), 1-bytyl-3-methylimidazolium tetrafluoroborate (BMImBF{sub 4}) and N,N-methyl, propyl pyrrolidinium bis((trifluoromethyl)sulfonyl) imide (MPPyN(CF{sub 3}SO{sub 2}){sub 2}) were measured from 283.15 to 358.15 K. Room temperature heat capacities have also been estimated by an additive group contribution method, based on the assumption that the heat capacity of a molecular compound equals the sum of individual atomic-group contributions. The C {sub p} {sup 293.15K} estimated values are about 12% higher than experimental values. The estimates suggest that heat capacities of ionic liquids do not differ considerably from those typical for molecular liquids (ML). The heats of solution, {delta}{sub sol} H, of ionic liquids EMImBF{sub 4}, BMImBF{sub 4} EMImN(CF{sub 3}SO{sub 2}){sub 2} and MPPyN(CF{sub 3}SO{sub 2}){sub 2} were measured in water, acetonitrile (AN) and methanol, as a function of ionic liquid concentration c {sub m}. The measured {delta}{sub sol} H values decrease with decreasing c {sub m}. Enthalpies of ionic liquid transfer, {delta}{sub t} H deg., from water to methanol and acetonitrile were calculated from measured solution enthalpies. Values of {delta}{sub t} H deg. for the transfer from water to methanol are positive and those for the transfer to acetonitrile are negative.

  8. Least dissipation principle of heat transport potential capacity and its application in heat conduction optimization

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    In the viewpoint of heat transfer, heat transport potential capacity and its dissipation are defined based on the essence of heat transport phenomenon. Respectively, their physical meanings are the overall heat transfer capabilityand the dissipation rate of the heat transfer capacity. Then the least dissipation principle of heat transport potential capacity is presented to enhance the heat conduction efficiency in the heat conduction optimization. The principle is,for a conduction process with the constant integral of the thermal conductivityover the region, the optimal distribution of thermal conductivity, which corresponds to the highest heat conduction efficiency, is characterized by the least dissipation of heat transport potential capacity. Finally the principle is applied to some cases in heat conduction optimization.

  9. Heat-capacity measurements on small samples: The hybrid method

    NARCIS (Netherlands)

    Klaasse, J.C.P.; Brück, E.H.

    2008-01-01

    A newly developed method is presented for measuring heat capacities on small samples, particularly where thermal isolation is not sufficient for the use of the traditional semiadiabatic heat-pulse technique. This "hybrid technique" is a modification of this heat-pulse method in case the temperature

  10. Heat-capacity measurements on small samples: The hybrid method

    NARCIS (Netherlands)

    Klaasse, J.C.P.; Brück, E.H.

    2008-01-01

    A newly developed method is presented for measuring heat capacities on small samples, particularly where thermal isolation is not sufficient for the use of the traditional semiadiabatic heat-pulse technique. This "hybrid technique" is a modification of this heat-pulse method in case the temperature

  11. The heat capacity of hydrous cordierite above 295 K

    Science.gov (United States)

    Carey, J. William

    1993-04-01

    The heat capacity of synthetic hydrous cordierite (Mg2Al4Si5O18·nH2O) has been determined by differential scanning calorimetry (DSC) from 295 to 425 K as a function of H2O content. Six samples with H2O contents ranging from 0 to 0.82 per formula unit were examined. The partial molar heat capacity of H2O in cordierite over the measured temperature interval is independent of composition and temperature within experimental uncertainty and is equal to 43.3 ±0.8 J/mol/ K. This value exceeds the molar heat capacity of gaseous H2O by 9.7 J/mol/K, but is significantly smaller than the heat capacity of H2O in several zeolites and liquid H2O. A statistical-mechanical model of the heat capacity of adsorbed gas species (Barrer 1978) is used to extrapolate the heat capacity of hydrous cordierite to temperatures greater than 425 K. In this model, the heat capacity of hydrous cordierite (Crd·nH2O) is represented as follows: Cp(Crd · nH2O) = Cp(Crd)+ n{Cp(H2O, gas)+ R(gas constant)} (1) An examination of calorimetric data for hydrous beryl, analcime, mordenite, and clinoptilolite (Hemingway et al. 1986; Johnson et al. 1982, 1991, 1992) demonstrates the general applicability of the statistical-mechanical model for the extrapolation of heat capacity data of zeolitic minerals. The heat capacity data for cordierite are combined with the data of Carey and Navrotsky (1992) to obtain the molar enthalpy of formation and enthalpy of hydration of hydrous cordierite as a function of temperature.

  12. Phonon heat capacity of graphene nanofilms and nanotubes

    Science.gov (United States)

    Gospodarev, I. A.; Grishaev, V. I.; Manzhelii, E. V.; Syrkin, E. S.; Feodosyev, S. B.; Minakova, K. A.

    2017-02-01

    Based on calculations conducted on a microscopic level, the phonon heat capacity of ultrathin graphene nanofilms such as bigraphene and trigraphene, and single-wall graphene nanotubes, is quantitatively described. The nature of the flexural stiffness of graphene monolayers is analyzed, and the temperature intervals at which the shape of the temperature dependence of heat capacity is determined by contributions made by flexural vibrations are identified. The contribution to the phonon heat capacity derived from graphene nanotube flexural waves that propagate along the surface thereof is analyzed, as are the bending vibrations of the tube as a whole one-dimensional object, and the contribution from torsional vibrations.

  13. Low Temperature Heat Capacity of a Severely Deformed Metallic Glass

    Science.gov (United States)

    Bünz, Jonas; Brink, Tobias; Tsuchiya, Koichi; Meng, Fanqiang; Wilde, Gerhard; Albe, Karsten

    2014-04-01

    The low temperature heat capacity of amorphous materials reveals a low-frequency enhancement (boson peak) of the vibrational density of states, as compared with the Debye law. By measuring the low-temperature heat capacity of a Zr-based bulk metallic glass relative to a crystalline reference state, we show that the heat capacity of the glass is strongly enhanced after severe plastic deformation by high-pressure torsion, while subsequent thermal annealing at elevated temperatures leads to a significant reduction. The detailed analysis of corresponding molecular dynamics simulations of an amorphous Zr-Cu glass shows that the change in heat capacity is primarily due to enhanced low-frequency modes within the shear band region.

  14. Heat capacity and thermal expansion of water and helium

    Science.gov (United States)

    Putintsev, N. M.; Putintsev, D. N.

    2017-04-01

    Original expressions for heat capacity CV and its components, vibrational and configurational components of thermal expansion coefficient were established. The values of CV, Cvib, Cconf, αvib and αconf for water and helium 4He were calculated.

  15. Heat Capacity Mapping Mission Digital Source: 1978-1980

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — NASA's Heat Capacity Mapping Mission (HCMM) project collected Earth data in the visible and thermal bands between April 1978 and September 1980. This was an...

  16. The revision on heat capacity of Einstein's solid model

    Institute of Scientific and Technical Information of China (English)

    WANG Ai-kun; ZHOU Guo-xiang; LI Guo-chang; XUE Jian-hua

    2005-01-01

    This paper is based on Einstein's supposition about crystal lattice vibration, which states that when Einstein's temperature ( )E is not less than the crystal temperature T but less than 2T, the expression of crystal molar heat capacity changes to the Dulong-Petit equation Cv = 3R. Thereby this equation can explain why crystal molar heat capacity equals about 3R not only at low temperatures but also at normal temperatures for many kinds of metals. It can be calculated that the nonlinear interaction among atoms contributes to the molar heat capacity using the coefficient of expansionβ and the Grüneisen constant γ. The result is that the relative error between the theoretical and the experimental value of the molar heat capacity is reduced greatly for many kinds of metals, especially for metals of IA. The relative error can be cut by about 17%.

  17. The sensitivity of magnetic calorimeters with large heat capacity

    Energy Technology Data Exchange (ETDEWEB)

    Fleischmann, A. E-mail: e62@urz.uni-heidelberg.de; Enss, C.; Schoenefeld, J.; Sollner, J.; Horst, K.; Adams, J.S.; Kim, Y.H.; Seidel, G.M.; Bandler, S.R

    2000-04-07

    Magnetic sensors, based on the measurement of the magnetization of paramagnetic spins, possess characteristics that make them suitable for use with low-temperature calorimeters having large heat capacities. When the properties of the sensor, which can be calculated, are optimized for a given heat capacity, the energy resolution depends on heat capacity roughly as C{sup 1/3}. We have obtained an energy resolution of 135 eV at 6 keV with a calorimeter having a heat capacity of 4x10{sup -9} J/K. No deviations from a linear response with respect to energy were observed in the detector up to 136 keV. Prospects for the improvement of the performance of large calorimeters are discussed.

  18. Heat Capacity Mapping Mission Digital Source: 1978-1980

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — NASA's Heat Capacity Mapping Mission (HCMM) project collected Earth data in the visible and thermal bands between April 1978 and September 1980. This was an...

  19. Accurate Measurement of Heat Capacity by Differential Scanning Calorimetry

    Science.gov (United States)

    1984-01-01

    Experience with high quality heat capacity measurement by differential scanning calorimetry is summarized and illustrated, pointing out three major causes of error: (1) incompatible thermal histories of the sample, reference and blank runs; (2) unstable initial and final isotherms; (3) incompatible differences between initial and final isotherm amplitudes for sample, reference and blank runs. Considering these problems, it is shown for the case of polyoxymethylene that accuracies in heat capacity of 0.1 percent may be possible.

  20. Accurate Measurement of Heat Capacity by Differential Scanning Calorimetry

    Science.gov (United States)

    1984-01-01

    Experience with high quality heat capacity measurement by differential scanning calorimetry is summarized and illustrated, pointing out three major causes of error: (1) incompatible thermal histories of the sample, reference and blank runs; (2) unstable initial and final isotherms; (3) incompatible differences between initial and final isotherm amplitudes for sample, reference and blank runs. Considering these problems, it is shown for the case of polyoxymethylene that accuracies in heat capacity of 0.1 percent may be possible.

  1. Global negative emissions capacity of ocean macronutrient fertilization

    Science.gov (United States)

    Harrison, Daniel P.

    2017-03-01

    In order to meet the goal of limiting global average temperature increase to less than 2 °C, it is increasingly apparent that negative emissions technologies of up to 10 Pg C yr‑1 will be needed before the end of the century. Recent research indicates that fertilization of the ocean with the macronutrients nitrogen and phosphorus where they limit primary production, may have sequestration advantages over fertilizing iron limited regions. Utilizing global datasets of oceanographic field measurements, and output from a high resolution global circulation model, the current study provides the first comprehensive assessment of the global potential for carbon sequestration from ocean macronutrient fertilization (OMF). Sufficient excess phosphate exists outside the iron limited surface ocean to support once-off sequestration of up to 3.6 Pg C by fertilization with nitrogen. Ongoing maximum capacity of nitrogen only fertilization is estimated at 0.7 ± 0.4 Pg C yr‑1. Sequestration capacity is expected to decrease from the upper toward the lower bound over time under continued intense fertilization. If N and P were used in combination the capacity is ultimately limited by societies willingness to utilize phosphate resources. Doubling current phosphate production would allow an additional 0.9 Pg C yr‑1 and consume 0.07% yr‑1 of known global resources. Therefore offsetting up to around 15% (1.5 Pg C yr‑1) of annual global CO2 emissions is assessed as being technically plausible. Environmental risks which to date have received little quantitative evaluation, could also limit the scale of implementation. These results reinforce the need to consider a multi-faceted approach to greenhouse gasses, including a reduction in emissions coupled with further research into negative emissions technologies.

  2. Heat capacity of helium in cylindrical environments

    Science.gov (United States)

    Gatica, S. M.; Hernández, E. S.; Szybisz, L.

    2003-10-01

    We perform a systematic investigation of the structure, elementary, and phonon excitations of quantum fluid 4He adsorbed in the interior of carbon nanotubes. We show that the helium fluid inside the cylinder behaves exactly as in planar films on a graphite substrate, presenting the same kind of layering transition. This tendency is confirmed by the behavior of a single 3He impurity diluted into adsorbed 4He. We also present a simple description of the lowest excitation modes of the adsorbed fluid and compute the low-temperature contribution of the phonon spectrum to the specific heat, which displays the dimensionality characteristics reported in previous works.

  3. Heat capacity measurements on high T sub c superconductors

    CERN Document Server

    Oezcan, S

    1998-01-01

    temperature interval. The phase transition jump increases with the increasing of oxygen amount in the CuO sub 2 layers. The hight of the jump is varying from 1.5% to 3.5% of the total specific heat which is the nature of the bulk superconductivity. The small coherence length increases fluctuation effects and also causes the dependence of superconducting properties on structural defects. The fluctuation effects on the heat capacity of YBCO is investigated on the sample that shows clear superconducting properties. In this work, a heat capacity measurement system which has high sensitivity and reproducibility designed and constructed. The investigation of the effect of oxygen stoichiometry on the superconducting properties of high T sub c superconductors was aimed. For this purpose electrical resistivity, magnetic susceptibility and heat capacity experiment were performed. The constructed system is a computerized adiabatic calorimeter which has temperature resolution of about 0.1 mk and operates in the temperatu...

  4. On the Heat Capacity of Cu2Se

    Science.gov (United States)

    Bulat, L. P.; Pshenay-Severin, D. A.; Ivanov, A. A.; Osvenskii, V. B.; Parkhomenko, Yu. N.

    2017-05-01

    Copper selenide is a promising thermoelectric material. One of the reasons for its high efficiency is its low thermal conductivity that can be connected with the decrease of heat capacity with temperature. The possibility of the decrease of heat capacity with the increase of temperature in this material can be connected with the liquid-like behavior of copper ions. In order to reveal the influence of this factor, measurements of constant pressure heat capacity c p and calculations of constant volume heat capacity c V were performed for cubic β-Cu2Se at temperatures T = 450-1000 K. Both calculations and measurements made in the present work demonstrate only a small decrease of heat capacity with temperature. The temperature dependence of c p reasonably correlates with the literature data. But, c V values showed a similar trend only up to 770 K; at higher temperatures, the values obtained previously by other authors are considerably smaller. As the diffusion of copper atoms was taken into account in our calculations, the comparison suggests that small c V values obtained at T > 770 K previously are connected mainly with large thermal expansion of Cu2Se in this temperature range.

  5. Heat Capacity of Spider Silk-like Block Copolymers.

    Science.gov (United States)

    Huang, Wenwen; Krishnaji, Sreevidhya; Hu, Xiao; Kaplan, David; Cebe, Peggy

    2011-07-12

    We synthesized and characterized a new family of di-block copolymers based on the amino acid sequences of Nephila clavipes major ampulate dragline spider silk, having the form HABn and HBAn (n=1-3), comprising an alanine-rich hydrophobic block, A, a glycine-rich hydrophilic block, B, and a histidine tag, H. The reversing heat capacities, Cp(T), for temperatures below and above the glass transition, Tg, were measured by temperature modulated differential scanning calorimetry. For the solid state, we then calculated the heat capacities of our novel block copolymers based on the vibrational motions of the constituent poly(amino acid)s, whose heat capacities are known or can be estimated from the ATHAS Data Bank. For the liquid state, the heat capacity was estimated by using the rotational and translational motions in the polymer chain. Excellent agreement was found between the measured and calculated values of the heat capacity, showing that this method can serve as a standard by which to assess the Cp for other biologically inspired block copolymers. The fraction of beta sheet crystallinity of spider silk block copolymers was also determined by using the predicted Cp, and was verified by wide angle X-ray diffraction and Fourier transform infrared spectroscopy. The glass transition temperatures of spider silk block copolymer were fitted by Kwei's equation and the results indicate that attractive interaction exists between the A-block and B-block.

  6. Reductions in labour capacity from heat stress under climate warming

    Science.gov (United States)

    Dunne, John P.; Stouffer, Ronald J.; John, Jasmin G.

    2013-06-01

    A fundamental aspect of greenhouse-gas-induced warming is a global-scale increase in absolute humidity. Under continued warming, this response has been shown to pose increasingly severe limitations on human activity in tropical and mid-latitudes during peak months of heat stress. One heat-stress metric with broad occupational health applications is wet-bulb globe temperature. We combine wet-bulb globe temperatures from global climate historical reanalysis and Earth System Model (ESM2M) projections with industrial and military guidelines for an acclimated individual's occupational capacity to safely perform sustained labour under environmental heat stress (labour capacity)--here defined as a global population-weighted metric temporally fixed at the 2010 distribution. We estimate that environmental heat stress has reduced labour capacity to 90% in peak months over the past few decades. ESM2M projects labour capacity reduction to 80% in peak months by 2050. Under the highest scenario considered (Representative Concentration Pathway 8.5), ESM2M projects labour capacity reduction to less than 40% by 2200 in peak months, with most tropical and mid-latitudes experiencing extreme climatological heat stress. Uncertainties and caveats associated with these projections include climate sensitivity, climate warming patterns, CO2 emissions, future population distributions, and technological and societal change.

  7. On the Heat Capacity of Cu2Se

    Science.gov (United States)

    Bulat, L. P.; Pshenay-Severin, D. A.; Ivanov, A. A.; Osvenskii, V. B.; Parkhomenko, Yu. N.

    2016-10-01

    Copper selenide is a promising thermoelectric material. One of the reasons for its high efficiency is its low thermal conductivity that can be connected with the decrease of heat capacity with temperature. The possibility of the decrease of heat capacity with the increase of temperature in this material can be connected with the liquid-like behavior of copper ions. In order to reveal the influence of this factor, measurements of constant pressure heat capacity c p and calculations of constant volume heat capacity c V were performed for cubic β-Cu2Se at temperatures T = 450-1000 K. Both calculations and measurements made in the present work demonstrate only a small decrease of heat capacity with temperature. The temperature dependence of c p reasonably correlates with the literature data. But, c V values showed a similar trend only up to 770 K; at higher temperatures, the values obtained previously by other authors are considerably smaller. As the diffusion of copper atoms was taken into account in our calculations, the comparison suggests that small c V values obtained at T > 770 K previously are connected mainly with large thermal expansion of Cu2Se in this temperature range.

  8. Heat Capacities of Natural Antlerite and Brochantite at Low Temperature.

    Science.gov (United States)

    Bissengaliyeva, Mira R; Bekturganov, Nuraly S; Gogol, Daniil B; Taimassova, Shynar T; Koketai, Temirgaly A; Bespyatov, Michael A

    2013-11-14

    The investigation of a magnetic component of the heat capacity of natural samples of copper sulfates antlerite Cu3SO4(OH)4 in the temperature range below 40 K and brochantite Cu4SO4(OH)6 below 55 K has been carried out. A regular component of the heat capacity has been calculated from experimental data of adiabatic calorimetry. In the low-temperature area of (0 to 55) K two peaks of magnetic heat capacity for brochantite have been registered. The contributions of anomalous component ΔStr into entropy of the minerals are (11 ± 3) J·mol(-1)·K(-1) for antlerite and (5.3 ± 1.5) J·mol(-1)·K(-1) for brochantite.

  9. Maximum Power Point Characteristics of Generalized Heat Engines with Finite Time and Finite Heat Capacities

    Directory of Open Access Journals (Sweden)

    Abhishek Khanna

    2012-01-01

    Full Text Available We revisit the problem of optimal power extraction in four-step cycles (two adiabatic and two heat-transfer branches when the finite-rate heat transfer obeys a linear law and the heat reservoirs have finite heat capacities. The heat-transfer branch follows a polytropic process in which the heat capacity of the working fluid stays constant. For the case of ideal gas as working fluid and a given switching time, it is shown that maximum work is obtained at Curzon-Ahlborn efficiency. Our expressions clearly show the dependence on the relative magnitudes of heat capacities of the fluid and the reservoirs. Many previous formulae, including infinite reservoirs, infinite-time cycles, and Carnot-like and non-Carnot-like cycles, are recovered as special cases of our model.

  10. Magic Numbers for Classical Lennard-Jones Cluster Heat Capacities

    CERN Document Server

    Frantz, D D

    1994-01-01

    Heat capacity curves as functions of temperature for classical atomic clusters bound by pairwise Lennard-Jones potentials were calculated for aggregate sizes from 4 to 24 using Monte Carlo methods. J-walking (or jump-walking) was used to overcome convergence difficulties due to quasi-ergodicity in the solid-liquid transition region. The heat capacity curves were found to differ markedly and nonmonotonically as functions of cluster size. Curves for N = 4, 5 and 8 consisted of a smooth, featureless, monotonic increase throughout the transition region, while curves for N = 7 and 15-17 showed a distinct shoulder in this region; the remaining clusters had distinguishable transition heat capacity peaks. The size and location of these peaks exhibited "magic number" behavior, with the most pronounced peaks occurring for magic number sizes of N = 13, 19 and 23. A comparison of the heat capacities with other cluster properties in the solid-liquid transition region that have been reported in the literature indicates par...

  11. Heat capacities of lanthanide and actinide monazite-type ceramics

    Science.gov (United States)

    Kowalski, Piotr M.; Beridze, George; Vinograd, Victor L.; Bosbach, Dirk

    2015-09-01

    (Ln, An)xPO4 monazite-type ceramics are considered as potential matrices for the disposal of nuclear waste. In this study we computed the heat capacities and the standard entropies of these compounds using density functional perturbation theory. The calculations of lanthanide monazites agree well with the existing experimental data and provide information on the variation of the standard heat capacities and entropies along the lanthanide series. The results for AnPO4 monazites are similar to those obtained for the isoelectronic lanthanide compounds. This suggests that the missing thermodynamic data on actinide monazites could be similarly computed or assessed based on the properties of their lanthanide analogs. However, the computed heat capacity of PuPO4 appear to be significantly lower than the measured data. We argue that this discrepancy might indicate potential problems with the existing experimental data or with their interpretation. This shows a need for further experimental studies of the heat capacities of actinide-bearing, monazite-type ceramics.

  12. Measurement of the specific heat capacity of graphite

    Energy Technology Data Exchange (ETDEWEB)

    Picard, S.; Burns, D.T.; Roger, P

    2006-01-15

    With the objective of implementing graphite calorimetry at the BIPM to measure absorbed dose, an experimental assembly has recently been constructed to measure the specific heat capacity of graphite. A status description of the apparatus and results from the first measurements are given. The outcome is discussed and the experimental uncertainty is reviewed. (authors)

  13. Improved Method for Determining the Heat Capacity of Metals

    Science.gov (United States)

    Barth, Roger; Moran, Michael J.

    2014-01-01

    An improved procedure for laboratory determination of the heat capacities of metals is described. The temperature of cold water is continuously recorded with a computer-interfaced temperature probe and the room temperature metal is added. The method is more accurate and faster than previous methods. It allows students to get accurate measurements…

  14. Space qualification of high capacity grooved heat pipes

    Energy Technology Data Exchange (ETDEWEB)

    Dubois, M.; Mullender, B.; Druart, J. [SABCA, Societe Anomyme Belgel de Construction Aeronautique (Belgium); Supper, W.; Beddows, A. [ESTEC-The (Netherlands)

    1996-12-31

    Based on the thermal requirements of the future telecommunication satellites, the development of a High Capacity Grooved Heat Pipe (HPG), was contracted by ESA to SABCA leading to an aluminium extruded heat pipe (outer diameter of 25 mm) based on a multi re-entrant grooves design. After an intensive acceptance test campaign whose results showed a good confidence in the design and the fulfillment of the required specifications of heat transport and on tilt capability (experimental maximum heat transport capability of 1500 Watt metres for a vapour temperature of 20 deg C), similar heat pipes have been developed with various outer diameters (11 mm, 15 mm and 20 mm) and with various shapes (circular outer shapes, integrated saddles). Several of these heat pipes were tested during two parabolic flight campaigns, by varying the heat loads during the micro-gravity periods. This HGP heat pipe family is now being submitted to a space qualification program according to ESA standards (ESA PSS-49), both in straight and bent configuration. Within this qualification, the heat pipes are submitted to an extended test campaign including environmental (random/sinus vibration, constant acceleration) and thermal tests (thermal performance, thermal cycle, thermal soak, ageing). (authors) 9 refs.

  15. Sorption heat engines: simple inanimate negative entropy generators

    OpenAIRE

    Muller, Anthonie W. J.; Schulze-Makuch, Dirk

    2005-01-01

    The name 'sorption heat engines' is proposed for simple negative entropy generators that are driven by thermal cycling and work on alternating adsorption and desorption. These generators are in general not explicitly recognized as heat engines. Their mechanism is applicable to the fields of engineering, physics, chemistry, geology, and biology, in particular the origin of life. Four kinds of sorption heat engines are distinguished depending on the occurrence of changes in the adsorbent or ads...

  16. On the specific heat capacity enhancement in nanofluids.

    Science.gov (United States)

    Hentschke, Reinhard

    2016-12-01

    Molten salts are used as heat transfer fluids and for short-term heat energy storage in solar power plants. Experiments show that the specific heat capacity of the base salt may be significantly enhanced by adding small amounts of certain nanoparticles. This effect, which is technically interesting and economically important, is not yet understood. This paper presents a critical discussion of the existing attendant experimental literature and the phenomenological models put forward thus far. A common assumption, the existence of nanolayers surrounding the nanoparticles, which are thought to be the source of, in some cases, the large increase of a nanofluid's specific heat capacity is criticized and a different model is proposed. The model assumes that the influence of the nanoparticles in the surrounding liquid is of long range. The attendant long-range interfacial layers may interact with each other upon increase of nanoparticle concentration. This can explain the specific heat maximum observed by different groups, for which no other theoretical explanation appears to exist.

  17. Poly(3-methylpyrrole): Vibrational dynamics, phonon dispersion and heat capacity

    Science.gov (United States)

    Ali, Parvej; Srivastava, Seema; Ansari, Saif-ul-Islam; Gupta, V. D.

    2013-07-01

    Normal modes of vibration and their dispersions in poly(3-methylpyrrole) (P3MPy) based on the Urey-Bradley force field are reported. It provides a detailed interpretation of previously reported I.R. spectra. Characteristic features of dispersion curves, such as regions of high density-of-states, repulsion, and character mixing of dispersive modes are discussed. Predictive values of heat capacity as a function of temperature are calculated from dispersion curves via density-of-states.

  18. Experimental Temperature and Heat Capacity in Rare Earth Nuclei

    Science.gov (United States)

    Melby, E.; Bergholt, L.; Guttormsen, M.; Hjorth-Jensen, M.; Ingebretsen, F.; Messelt, S.; Rekstad, J.; Schiller, A.; Siem, S.; Ødegård, S. W.

    Temperature and heat capacity for the rare earth nuclei 162Dy, 166Er and 172Yb have been extracted from experimental data at the Oslo Cyclotron Laboratory (OCL). The starting point to determine thermodynamical quantities is the density of levels as a function of excitation energy. The density of accessible levels in the (3He,α γ)-reaction has been extracted from measured γ-spectra.

  19. Negative specific heat in a thermodynamic model of multifragmentation

    CERN Document Server

    Das, C B; Mekjian, A Z

    2003-01-01

    We consider a soluble model of multifragmentation which is similar in spirit to many models which have been used to fit intermediate energy heavy ion collision data. In this model $c_v$ is always positive but for finite nuclei $c_p$ can be negative for some temperatures and pressures. Furthermore, negative values of $c_p$ can be obtained in canonical treatment. One does not need to use the microcanonical ensemble. Negative values for $c_p$ can persist for systems as large as 200 paticles but this depends upon parameters used in the model calculation. As expected, negative specific heats are absent in the thermodynamic limit.

  20. Heat Capacity and Enthalpy of Fusion of Fenoxycarb

    Institute of Scientific and Technical Information of China (English)

    SUN Xiao-Hong; LIU Yuan-Fa; TAN Zhi-Cheng; JIA Ying-Qi; YANG Jian-Wu; WANG Mei-Han

    2005-01-01

    Fenoxycarb was synthesized and its heat capacities were precisely measured with an automated adiabatic calorimeter over the temperature range from 79 to 360 K. The sample was observed to melt at (326.31±0.14) K. The molar enthalpy and entropy of fusion as well as the chemical purity of the compound were determined to be (26.98±0.04) kJ·mol-1, (82.69±0.09) J·K-1·mol-1 and 99.53% ±0.01%, respectively. The thermodynamic functions relative to the reference temperature (298.15 K) were calculated based on the heat capacity measurements in the temperature range between 80 and 360 K. The extrapolated melting temperature for the absolutely pure compound obtained from fractional melting experiments was (326.62 ± 0.06) K. Further research on the melting process of this compound was carried out by means of differential scanning calorimetry technique. The result was in agreement with that obtained from the measurements of heat capacities.

  1. Indoor temperatures for calculating room heat loss and heating capacity of radiant heating systems combined with mechanical ventilation systems

    DEFF Research Database (Denmark)

    Wu, Xiaozhou; Olesen, Bjarne W.; Fang, Lei;

    2016-01-01

    system were determined according to the principle of heat transfer. A model to predict indoor temperatures in the room was proposed, and it was determined that the predicted indoor temperatures agreed well with the measured data. Qualitative analyses of the effects of heated surface temperature and air...... change rates on the indoor temperatures were performed using the proposed model. When heated surface temperatures and air change rates were from 21.0 to 29.0 degrees C and from 0.5 to 4.0 h-1, the indoor temperatures for calculating the transmission heat loss and ventilation heat loss were between 20.......8% for calculating the transmission heat loss and ventilation heat loss, respectively, and between 16.0% and 17.4% for calculating the heating capacity of the hybrid system. Due to large relative calculation errors, it is necessary to consider the effect of heated surface and cool supply air on indoor temperatures...

  2. Molar heat capacity and molar excess enthalpy measurements in aqueous amine solutions

    Science.gov (United States)

    Poozesh, Saeed

    Experimental measurements of molar heat capacity and molar excess enthalpy for 1, 4-dimethyl piperazine (1, 4-DMPZ), 1-(2-hydroxyethyl) piperazine (1, 2-HEPZ), I-methyl piperazine (1-MPZ), 3-morpholinopropyl amine (3-MOPA), and 4-(2-hydroxy ethyl) morpholine (4, 2-HEMO) aqueous solutions were carried out in a C80 heat flow calorimeter over a range of temperatures from (298.15 to 353.15) K and for the entire range of the mole fractions. The estimated uncertainty in the measured values of the molar heat capacity and molar excess enthalpy was found to be +/- 2%. Among the five amines studied, 3-MOPA had the highest values of the molar heat capacity and 1-MPZ the lowest. Values of molar heat capacities of amines were dominated by --CH 2, --N, --OH, --O, --NH2 groups and increased with increasing temperature, and contributions of --NH and --CH 3 groups decreased with increasing temperature for these cyclic amines. Molar excess heat capacities were calculated from the measured molar heat capacities and were correlated as a function of the mole fractions employing the Redlich-Kister equation. The molar excess enthalpy values were also correlated as a function of the mole fractions employing the Redlich-Kister equation. Molar enthalpies at infinite dilution were derived. Molar excess enthalpy values were modeled using the solution theory models: NRTL (Non Random Two Liquid) and UNIQUAC (UNIversal QUAsi Chemical) and the modified UNIFAC (UNIversal quasi chemical Functional group Activity Coefficients - Dortmund). The modified UNIFAC was found to be the most accurate and reliable model for the representation and prediction of the molar excess enthalpy values. Among the five amines, the 1-MPZ + water system exhibited the highest values of molar excess enthalpy on the negative side. This study confirmed the conclusion made by Maham et al. (71) that -CH3 group contributed to higher molar excess enthalpies. The negative excess enthalpies were reduced due to the contribution of

  3. Laws of Large Numbers of Negatively Correlated Random Variables for Capacities

    Institute of Scientific and Technical Information of China (English)

    Wen-juan LI; Zeng-jing CHEN

    2011-01-01

    Our aim is to present some limit theorems for capacities.We consider a sequence of pairwise negatively correlated random variables.We obtain laws of large numbers for upper probabilities and 2-aiternating capacities,using some results in the classical probability theory and a non-additive version of Chebyshev's inequality and Borai-Contelli lemma for capacities.

  4. Determination of the heat capacities of Lithium/BCX (bromide chloride in thionyl chloride) batteries

    Science.gov (United States)

    Kubow, Stephen A.; Takeuchi, Kenneth J.; Takeuchi, Esther S.

    1989-12-01

    Heat capacities of twelve different Lithium/BCX (BrCl in thionyl chloride) batteries in sizes AA, C, D, and DD were determined. Procedures and measurement results are reported. The procedure allowed simple, reproducible, and precise determinations of heat capacities of industrially important Lithium/BCX cells, without interfering with performance of the cells. Use of aluminum standards allowed the accuracy of the measurements to be maintained. The measured heat capacities were within 5 percent of calculated heat capacity values.

  5. On the Einstein-Stern model of rotational heat capacities

    DEFF Research Database (Denmark)

    Dahl, Jens Peder

    1998-01-01

    The Einstein-Stern model for the rotational contribution to the heat capacity of a diatomic gas has recently been resuscitated. In this communication, we show that the apparent success of the model is illusory, because it is based on what has turned out to be an unfortunate comparison with experi...... with experiment. We also take exception to the possibility of assigning any meaning to the rotational zero-point energy introduced by the model. (C) 1998 American Institute of Physics. [S0021-9606(98)02448-9]....

  6. Heat capacity of paramagnetic nickelocene: Comparison with diamagnetic ferrocene

    Science.gov (United States)

    Sorai, Michio; Kaneko, Yuki; Hashiguchi, Takao

    2014-05-01

    Nickelocene [bis(η5-cyclopentadienyl)nickel: Ni(C5H5)2, electron spin S=1, the ground state configuration 3A2g] is paramagnetic and belongs to a typical molecule-based magnet. Heat capacities of nickelocene have been measured at temperatures in the 3-320 K range by adiabatic calorimetry. By comparing with those of diamagnetic ferrocene crystal, a small heat capacity peak centered at around 15 K and a sluggish hump centered at around 135 K were successfully separated. The low-temperature peak at 15 K caused by the spin is well reproduced by the Schottky anomaly due to the uniaxial zero-field splitting of the spin S=1 with the uniaxial zero-field splitting parameter D/k=45 K (k: the Boltzmann constant). The magnetic entropy 9.7 J K-1mol-1 is substantially the same as the contribution from the spin-manifold R ln 3=9.13 J K-1mol-1 (R: the gas constant). The sluggish hump centered at around 135 K arises from rotational disordering of the cyclopentadienyl rings of nickelocene molecule. The enthalpy and entropy gains due to this anomaly are 890 J mol-1 and 6.9 J K-1mol-1, respectively. As the hump spreads over a wide temperature region, separation of the hump from the observed heat capacity curve involves a little bit ambiguity. Therefore, these values should be regarded as being reasonable but tentative. The present entropy gain is comparable with 5.5 J K-1mol-1 for the sharp phase transition at 163.9 K of ferrocene crystal. This fact implies that although the disordering of the rings likewise takes place in both nickelocene and ferrocene, it proceeds gradually in nickelocene and by way of a cooperative phase transition in ferrocene. A reason for this originates in loose molecular packing in nickelocene crystal. Molar heat capacity and the standard molar entropy of nickelocene are larger than those of ferrocene beyond the mass effect over the whole temperature region investigated. This fact provides with definite evidences for the loose molecular packing in nickelocene

  7. Low-temperature heat capacity of magnetic fluids

    Science.gov (United States)

    Lebedev, A. V.

    2008-12-01

    This paper continues the previous investigation into a recently discovered phenomenon of magnetic fluid solidification at temperatures essentially exceeding the freezing point of the base fluid. Physically, this phenomenon is related to the fact that at decreasing temperatures the magnetic fluid loses fluidity (with its viscosity tending to infinity) at a temperature higher than the freezing point of the base fluid. The main factor determining the freezing point is the type of the surface-active substance covering the particles. A group of different surfactants is examined with the aim of finding the lowest possible solidification temperature. The best result is obtained for linoleic acid (-100°C). In order to gain a deeper insight into the mechanisms of fluid solidification, a series of thermophysical measurements has been done. Heat capacity measurements made for an isooctane-based magnetic fluid stabilized by oleic acid at a temperature ranging from -130°C to 0 did not reveal any noticeable heat capacity anomalies in the vicinity of the solidification temperature. This suggests that the solidification of the magnetic fluid proceeds without phase transition. The highest peak of the heat flux is observed at the freezing point of isooctane. The position of the maximum slightly changes with the concentration of magnetic particles. With an increase of the concentration the temperature of the heat flux maximum decreases. In the presence of free oleic acid in isooctane a low peak is observed at a temperature of about -15°C. The peak position is independent of the oleic acid concentration. Tables 1, Figs 7, Refs 1.

  8. Anomalous dependence of the heat capacity of supercooled water on pressure and temperature

    Directory of Open Access Journals (Sweden)

    I.A. Stepanov

    2014-01-01

    Full Text Available In some papers, dependences of the isobaric heat capacity of water versus pressure and temperature were obtained. It is shown that these dependences contradict both the dependence of heat capacity on temperature for supercooled water, and an important thermodynamic equation for the dependence of heat capacity on pressure. A possible explanation for this contradiction is proposed.

  9. Effect of Heat Leak and Finite Thermal Capacity on the Optimal Configuration of a Two-Heat-Reservoir Heat Engine for Another Linear Heat Transfer Law

    Directory of Open Access Journals (Sweden)

    Chih Wu

    2003-12-01

    Full Text Available Abstract: Based on a model of a two-heat-reservoir heat engine with a finite high-temperature source and bypass heat leak, the optimal configuration of the cycle is found for the fixed cycle period with another linear heat transfer law . The finite thermal capacity source without heat leak makes the configuration of the cycle to a class of generalized Carnot cycle. The configuration of the cycle with heat leak and finite thermal capacity source is different from others.

  10. Experimental investigation and modelling of heat capacity, heat of fusion and melting interval of rocks

    Energy Technology Data Exchange (ETDEWEB)

    Leth-Miller, R.; Jensen, A.D.; Glarborg, P.; Jensen, L.M.; Hansen, P.B.; Joergensen, S.B

    2003-11-28

    The heat capacity and heat of fusion were measured for a number of minerals using differential scanning calorimetry (DSC). The DSC measurements showed that the heat of fusion for the minerals is very low compared to the heat of fusion for pure crystalline phases reported elsewhere. A model for the melting behaviour of mineral materials in terms of melting interval, heat capacities and heat of fusion has been developed. The only model input is the chemical composition of the mineral material. The model was developed to be implemented in a detailed model of a cupola furnace, thus the focus for the development was not only precision but also to obtain a model that was continuous and differentiable. The model is based on several different submodels that each covers a part of the heating and melting of rocks. Each submodel is based on large amounts of empirical data. Comparison of the model and the DSC measurements showed reasonable agreement for the model to be used when a fast estimate is needed and experimental data is not available.

  11. Prediction of heat capacities and heats of vaporization of organic liquids by group contribution methods

    DEFF Research Database (Denmark)

    Ceriani, Roberta; Gani, Rafiqul; Meirelles, A.J.A.

    2009-01-01

    In the present work a group contribution method is proposed for the estimation of the heat capacity of organic liquids as a function of temperature for fatty compounds found in edible oil and biofuels industries. The data bank used for regression of the group contribution parameters (1395 values...

  12. Heat capacities and glass transitions of ion gels.

    Science.gov (United States)

    Yamamuro, Osamu; Someya, Takenori; Kofu, Maiko; Ueki, Takeshi; Ueno, Kazuhide; Watanabe, Masayoshi

    2012-09-06

    We have investigated thermodynamic properties of ion gels consisting of a PMMA [poly(methyl methacrylate)] network and EMITFSI [1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide] ionic liquid by means of an adiabatic calorimeter. The heat capacity data were measured in the temperature range between 5 and 375 K for 7 samples with x = 0 (pure PMMA), 0.10, 0.18, 0.27, 0.48, 0.65, and 1.0 (pure ionic liquid) where x is a mole fraction of EMITFSI. These data revealed that two broad but distinct glass transitions appeared in the low x region. The upper glass transition is mainly due to the freezing of the PMMA motion, while the lower one is due to the ionic liquid. The upper glass transition temperature T(g) drastically decreased with increasing x, reflecting a large plasticization effect observed in mechanical experiments. The x dependence of the T(g)s and the excess heat capacities gave new physical insight to the interaction between polymer and ionic liquid in ion gels.

  13. Negative Joule Heating in Ion-Exchange Membranes

    CERN Document Server

    Biesheuvel, P M; Hamelers, H V M

    2014-01-01

    In ion-exchange membrane processes, ions and water flow under the influence of gradients in hydrostatic pressure, ion chemical potential, and electrical potential (voltage), leading to solvent flow, ionic fluxes and ionic current. At the outer surfaces of the membranes, electrical double layers (EDLs) are formed (Donnan layers). When a current flows through the membrane, we argue that besides the positive Joule heating in the bulk of the membrane and in the electrolyte outside the membrane, there is also negative Joule heating in one of the EDLs. We define Joule heating as the inner product of the two vectors current and field strength. Also when fluid flows through a charged membrane, at one side of the membrane there is pressure-related cooling, due to the osmotic and hydrostatic pressure differences across the EDLs.

  14. Heat capacity and magnetocaloric effect in polycrystalline Gd1-xSmxMn2Si2

    OpenAIRE

    2006-01-01

    We report the magnetocaloric effect in terms of isothermal magnetic entropy change as well as adiabatic temperature change, calculated using the heat capacity data. Using the zero field heat capacity data, the magnetic contribution to the heat capacity has been estimated. The variations in the magnetocaloric behavior have been explained on the basis of the magnetic structure of these compounds. The refrigerant capacities have also been calculated for these compounds.

  15. On the heat capacity of liquids at high temperatures

    CERN Document Server

    Stishov, S M

    2016-01-01

    Making use of a simple approximation for the evolution of the radial distribution function, we calculate the temperature dependence of the heat capacity $C_v$ of Ar at constant density. $C_v$ decreases with temperature roughly according to the law $\\sim T^{-1/4}$, slowly approaching the hard sphere asymptotic value $C_v=\\frac{3}{2}R$. However, the asymptotic value of $C_v$ is not reachable at reasonable temperatures , but stays close to 1.7--1.8 $R$ over a wide range of temperatures after passing a " magic " $2R$ value at about 2000 K. Nevertheless these values has nothing to do with loss of vibrational degrees of freedom, but arises as a result of a temperature variation of the collision diameter $\\sigma$. \\end{abstract}

  16. Recent Applications of Heat Capacity Measurement in Physicochemical Investigations

    Science.gov (United States)

    Lakshmikumar, S. T.; Gopal, E. S. R.

    This review discusses the recent experimental heat capacity measurements which have been very useful in physicochemical investigations. Areas reviewed include critical point phenomena in systems such as fluids, magnetic systems, liquid crystals, co-operative Jahn-Teller transitions, etc. The uses of Cp measurements in the study of discrete energy levels in solids, in glasses at very low temperatures, in thin films and at high pressures are discussed. Calorimetric investigations in A-15 and other superconducting materials and applications of Cp measurements for evaluation of thermodynamic parameters in several new classes of materials are then briefly described. Finally, examples of applications of calorimetry in areas of biophysics, biological sciences and clinical medicine are cited. Two hundred and seventy references are cited and 25 figures are used for illustration.

  17. Thermodynamics of micellization from heat-capacity measurements.

    Science.gov (United States)

    Šarac, Bojan; Bešter-Rogač, Marija; Lah, Jurij

    2014-06-23

    Differential scanning calorimetry (DSC), the most important technique for studying the thermodynamics of structural transitions of biological macromolecules, is seldom used in quantitative thermodynamic studies of surfactant micellization/demicellization. The reason for this could be ascribed to an insufficient understanding of the temperature dependence of the heat capacity of surfactant solutions (DSC data) in terms of thermodynamics, which leads to problems with the design of experiments and interpretation of the output signals. We address these issues by careful design of DSC experiments performed with solutions of ionic and nonionic surfactants at various surfactant concentrations, and individual and global mass-action model analysis of the obtained DSC data. Our approach leads to reliable thermodynamic parameters of micellization for all types of surfactants, comparable with those obtained by using isothermal titration calorimetry (ITC). In summary, we demonstrate that DSC can be successfully used as an independent method to obtain temperature-dependent thermodynamic parameters for micellization.

  18. SPECIFIC HEAT CAPACITY AND THERMAL CONDUCTIVITY OF HEAT STORAGE MATERIALS BASED ON PARAFFIN, BROWN-COAL WAX AND POLYETHYLENE WAX

    Directory of Open Access Journals (Sweden)

    Snezhkin Yu.

    2014-08-01

    Full Text Available The present paper overviews heat storage materials (HSM with phase change based on organic compounds. They consist of paraffin, brown-coal wax and polyethylene wax. These materials are produced on an industrial scale for the foundry work. It is shown that heat capacity of HSM in the solid and liquid states can be used for heat storage in addition to the heat of phase change. The results of investigations of phase change during heating and cooling HSM are presented. The studies are carried out by differential scanning calorimetry (DSC. The measurement techniques of the specific heat capacity and the coefficient of thermal conductivity are shown. Temperature dependences of the specific heat capacity of HSM in the solid and liquid states are researched by DSC. Values of the coefficient of thermal conductivity are determined by contact stationary technique of the flat plate over the entire temperature range of the operation of heat storage system.

  19. Molecular dynamics simulations on specific heat capacity and glass transition tempera-ture of liquid silver

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The embedded-atom method is adopted to simulate the specific heat capacity of liquid silver. The relationship between the specific heat capacity and the temperature above and below melting point is derived. The results show that there exists an anormaly of the specific heat capacity of liquid silver near 950 K. Simulated pair distribution functions show that the liquid-to-glass transition takes place at this temperature.

  20. Heat capacity for systems with excited-state quantum phase transitions

    Science.gov (United States)

    Cejnar, Pavel; Stránský, Pavel

    2017-03-01

    Heat capacities of model systems with finite numbers of effective degrees of freedom are evaluated using canonical and microcanonical thermodynamics. Discrepancies between both approaches, which are observed even in the infinite-size limit, are particularly large in systems that exhibit an excited-state quantum phase transition. The corresponding irregularity of the spectrum generates a singularity in the microcanonical heat capacity and affects smoothly the canonical heat capacity.

  1. The heat capacity of small metallic grains studied by the random matrices theory

    Institute of Scientific and Technical Information of China (English)

    Chen Zhi-Qian; Cheng Nan-Pu; Shi Zhen-Gang

    2004-01-01

    The random matrices theory is applied to a study of the heat capacity of small metallic grains. The numerical calculations indicate that the level distribution and the difference between the particles respectively with an even and an odd numbers of electrons are important for the heat capacity of the small metallic grains at a low temperature and the level correlation mainly affects the heat capacity at a high temperature.

  2. Excess molar enthalpies and heat capacities of dimethyl sulfoxide + seven normal alkanols at 303.15 K and atmospheric pressure

    Energy Technology Data Exchange (ETDEWEB)

    Rubini, Katia [Dipartimento di Chimica ' G. Ciamician' , Universita deg.li Studi, via Selmi 2, I-40126 Bologna (Italy); Francesconi, Romolo [Dipartimento di Chimica ' G. Ciamician' , Universita deg.li Studi, via Selmi 2, I-40126 Bologna (Italy); Bigi, Adriana [Dipartimento di Chimica ' G. Ciamician' , Universita deg.li Studi, via Selmi 2, I-40126 Bologna (Italy); Comelli, Fabio [Istituto per la Sintesi Organica e la Fotoreattivita (ISOF)-CNR, via Gobetti 101, I-40129 Bologna (Italy)]. E-mail: comelli@isof.cnr.it

    2007-01-15

    Excess molar enthalpies and heat capacities of binary mixtures containing dimethyl sulfoxide (DMSO) + seven normal alkanols, namely methanol, ethanol, propan-1-ol, butan-1-ol, hexan-1-ol, octan-1-ol, and decan-1-ol, have been determined at 303.15 K and atmospheric pressure. With the exception of the DMSO-methanol system, which shows negative values, all mixtures show positive values of excess molar enthalpies over the whole range of mole fraction, increasing as the number of carbon atoms increases. Heat capacities of pure components have been determined in the range 288.15 < T (K) < 325.15. Molar heat capacities of the mixtures are always positive and decrease as the number of carbon atoms decreases. The results were fitted to the Redlich-Kister polynomial equation. Molecular interactions in the mixtures are interpreted on the basis of the results obtained.

  3. Reassembling and testing of a high-precision heat capacity drop calorimeter. Heat capacity of some polyphenyls at T = 298.15 K

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Luis M.N.B.F., E-mail: lbsantos@fc.up.pt [Centro de Investigacao em Quimica, Departamento de Quimica e Bioquimica, Faculdade de Ciencias, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Rocha, Marisa A.A.; Rodrigues, Ana S.M.C. [Centro de Investigacao em Quimica, Departamento de Quimica e Bioquimica, Faculdade de Ciencias, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Stejfa, Vojtech; Fulem, Michal [Department of Physical Chemistry, Institute of Chemical Technology, Technicka 5, CZ-166 28 Prague 6 (Czech Republic); Bastos, Margarida [Centro de Investigacao em Quimica, Departamento de Quimica e Bioquimica, Faculdade de Ciencias, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal)

    2011-12-15

    Graphical abstract: Highlights: > We present the reassembling, improvement and testing of a high-precision C{sub p} drop calorimeter. > The apparatus was tested, using benzoic acid and hexafluorobenzene. > The high sensitivity of the apparatus is comparable to the one obtained in adiabatic calorimetry. > Heat capacities at T = 298.15 K of some polyphenyls were measured. > Subtle heat capacity differences among position isomers (ortho, meta, para) were detected. - Abstract: The description of the reassembling and testing of a twin heat conduction, high-precision, drop microcalorimeter for the measurement of heat capacities of small samples are presented. The apparatus, originally developed and used at the Thermochemistry Laboratory, Lund, Sweden, has now been reassembled and modernized, with changes being made as regarding temperature sensors, electronics and data acquisition system. The apparatus was thereafter thoroughly tested, using benzoic acid and hexafluorobenzene as test substances. The accuracy of the C{sub p,m}{sup 0} (298.15 K) data obtained with this apparatus is comparable to that achieved by high-precision adiabatic calorimetry. Here we also present the results of heat capacity measurements on of some polyphenyls (1,2,3-triphenylbenzene, 1,3,5-triphenylbenzene, p-terphenyl, m-terphenyl, o-terphenyl, p-quaterphenyl) at T = 298.15 K, measured with the renewed high precision heat capacity drop calorimeter system. The high resolution and accuracy of the obtained heat capacity data enabled differentiation among the ortho-, meta-, and para-phenyl isomers.

  4. Evaluation of Heat Capacity and Resistance to Cyclic Oxidation of Nickel Superalloys

    Directory of Open Access Journals (Sweden)

    Przeliorz R.

    2014-08-01

    Full Text Available Paper presents the results of evaluation of heat resistance and specific heat capacity of MAR-M-200, MAR-M-247 and Rene 80 nickel superalloys. Heat resistance was evaluated using cyclic method. Every cycle included heating in 1100°C for 23 hours and cooling for 1 hour in air. Microstructure of the scale was observed using electron microscope. Specific heat capacity was measured using DSC calorimeter. It was found that under conditions of cyclically changing temperature alloy MAR-M-247 exhibits highest heat resistance. Formed oxide scale is heterophasic mixture of alloying elements, under which an internal oxidation zone was present. MAR-M-200 alloy has higher specific heat capacity compared to MAR-M-247. For tested alloys in the temperature range from 550°C to 800°C precipitation processes (γ′, γ″ are probably occurring, resulting in a sudden increase in the observed heat capacity.

  5. Temperature fluctuation and heat capacity in relativistic heavy-ion collisions

    CERN Document Server

    Ma, Guo Liang; Chen Jin Gen; He Ze-Jun; Long Jia-Li; Lu Zhao-Hui; Ma Yu-Gang; Sá Ben-Hao; Shen Wen-Qing; Wang Kun; Wei Yi-Bin; Zhang Hu-Yong; Zhong Chen

    2004-01-01

    We used LUCIAE3.0 model to simulate the Pb+Pb and C+C in SPS energy. The heat capacity was then extracted from event-by-event temperature fluctuation. It is found that the heat capacity per hadron multiplicity decreases with the increasing of beam energy and impact parameter for a given reaction system. While the hadron mass increases, the heat capacity per hadron multiplicity rises. In addition, we found that, for a given hadron, the heat capacity per hadron multiplicity is almost the same regardless of the reaction system. Some discussions were also given.

  6. Optimal temperature range for determining magnetocaloric magnitudes from heat capacity

    Science.gov (United States)

    Moreno-Ramírez, L. M.; Blázquez, J. S.; Law, J. Y.; Franco, V.; Conde, A.

    2016-12-01

    The determination of the magnetocaloric magnitudes (specific magnetic entropy change, Δs M, and adiabatic temperature change, ΔT ad) from heat capacity (c H) measurements requires measurements performed at very low temperatures (~0 K) or data extrapolation when the low temperature range is unavailable. In this work we analyze the influence on the calculated Δs M and ΔT ad of the usually employed linear extrapolation of c H from the initial measured temperature down to 0 K. Numerical simulations have been performed using the Brillouin equation of state, the Debye model and the Fermi electron statistics to reproduce the magnetic, lattice and electronic subsystems, respectively. It is demonstrated that it is not necessary to reach experimentally temperatures very close to 0 K due to the existence of certain starting temperatures of the experiments, the same for Δs M and ΔT ad, that minimize the error of the results. A procedure is proposed to obtain the experimental magnitudes of Δs M and ΔT ad with a minimum error from c H data limited in temperature. It has been successfully applied to a GdZn alloy and results are compared to those derived from magnetization measurements.

  7. Enthalpy and Heat Capacity Data for 1,2-Cyclohexanediol

    Institute of Scientific and Technical Information of China (English)

    周彩荣; 章亚东; 蒋登高

    2003-01-01

    The thermodynamic properties of different geometric structures of 1,2-cyclohexanediol which were rarely reported in literature, such as combustion enthalpy, formation enthalpy, melting enthalpy and heat capacities, were determined by NETZSCH DSC 204 Scanning Calorimeter. The relationship between the melting point and the composition for the mixture system of cis-l,2-cyclohexanediol and trans-l,2-cyclohexanediol was investigated and corresponding phase diagram was obtained. "The melting enthalpies of both cis-l,2-cyclohexanediol and trans-l,2-cyclohexanediol are 20.265 kJ·mo1-1 and 16.368 kJ·mo1-1 respectively. The standard combustion enthalpies of cis- and trans-l,2-cyclohexaneddiol were determined by calorimeter. They are respectively -3507.043kJ·mo1-1 and -3497.8kJ·mo1-1 at 298.15 K.The standard formation enthalpies are respectively 568.997kJ·mol-1 and 578.240kJ·mol-1 for cis- and trans-1,2-cyclohexaneddiol.

  8. Preliminary Analysis on Heat Removal Capacity of Passive Air-Water Combined Cooling Heat Exchanger Using MARS

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Seung-Sin; Jeon, Seong-Su; Hong, Soon-Joon [FNC Tech, Yongin (Korea, Republic of); Bae, Sung-Won; Kwon, Tae-Soon [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-10-15

    Current design requirement for working time of PAFS heat exchanger is about 8 hours. Thus, it is not satisfied with the required cooling capability for the long term SBO(Station Black-Out) situation that is required to over 72 hours cooling. Therefore PAFS is needed to change of design for 72 hours cooling. In order to acquirement of long terms cooling using PAFS, heat exchanger tube has to be submerged in water tank for long time. However, water in the tank is evaporated by transferred heat from heat exchanger tubes, so water level is gradually lowered as time goes on. The heat removal capacity of air cooling heat exchanger is core parameter that is used for decision of applicability on passive air-water combined cooling system using PAFS in long term cooling. In this study, the development of MARS input model and plant accident analysis are performed for the prediction of the heat removal capacity of air cooling heat exchanger. From analysis result, it is known that inflow air velocity is the decisive factor of the heat removal capacity and predicted air velocity is lower than required air velocity. But present heat transfer model and predicted air velocity have uncertainty. So, if changed design of PAFS that has over 4.6 kW heat removal capacity in each tube, this type heat exchanger can be applied to long term cooling of the nuclear power plant.

  9. Parametric Study on the Dynamic Heat Storage Capacity of Building Elements

    DEFF Research Database (Denmark)

    Artmann, Nikolai; Manz, H.; Heiselberg, Per

    2007-01-01

    as their interrelation. The potential of increasing thermal mass by using phase change materials (PCM) was estimated assuming increased thermal capacity. The results show a significant impact of the heat transfer coefficient on heat storage capacity, especially for thick, thermally heavy elements. The storage capacity...... of a 100 mm thick concrete slab was found to increase with increasing heat transfer coefficients as high as 30 W/m2K. In contrast the heat storage capacity of a thin gypsum plaster board was found to be constant when the heat transfer coefficient exceeded 3 W/m2K. Additionally, the optimal thickness...... potential. However, because heat gains and night ventilation periods do not coincide in time, a sufficient amount of thermal mass is needed in the building to store the heat. Assuming a 24 h-period harmonic oscillation of the indoor air temperature within a range of thermal comfort, the analytical solution...

  10. Heat capacity and monogamy relations in the mixed-three-spin XXX Heisenberg model at low temperatures

    Science.gov (United States)

    Zad, Hamid Arian; Movahhedian, Hossein

    2016-08-01

    Heat capacity of a mixed-three-spin (1/2,1,1/2) antiferromagnetic XXX Heisenberg chain is precisely investigated by use of the partition function of the system for which, spins (1,1/2) have coupling constant J1 and spins (1/2,1/2) have coupling constant J2. We verify tripartite entanglement for the model by means of the convex roof extended negativity (CREN) and concurrence as functions of temperature T, homogeneous magnetic field B and the coupling constants J1 and J2. As shown in our previous work, [H. A. Zad, Chin. Phys. B 25 (2016) 030303.] the temperature, the magnetic field and the coupling constants dependences of the heat capacity for such spin system have different behaviors for the entangled and separable states, hence, we did some useful comparisons between this quantity and negativities of its organized bipartite (sub)systems at entangled and separable states. Here, we compare the heat capacity of the mixed-three-spin (1/2,1,1/2) system with the CREN and the tripartite concurrence (as measures of the tripartite entanglement) at low temperature. Ground state phase transitions, and also, transition from ground state to some excited states are explained in detail for this system at zero temperature. Finally, we investigate the heat capacity behavior around those critical points in which these quantum phase transitions occur.

  11. Specific Heat Capacity of Physically Confined Ethylene glycol in Nano Pores

    Science.gov (United States)

    Amanuel, Samuel; Linthicum, Will

    2013-03-01

    Sensible heat is a cheap and effective means of storing solar energy where energy storage density can be improved by enhancing the specific heat capacity of the heat transfer materials. Formulating composite materials of heat transfer fluids is a mechanism by which the bulk specific heat capacity can be altered and preferably increased. Traditionally, the specific heat capacity of composite material is evaluated from the weighed average of the individual specific heat capacities of the constituents. This, however, does not take into account the effect of interfacial atoms and molecules. The effect of interfacial atoms and molecules becomes increasingly significant when one of the constituents has dimensions in nano meters. In this study, we evaluate the role of interfacial molecules on the specific heat capacity of composite systems. In order to systematically control the interfacial molecules, we have measured the specific heat capacity of ethylene glycol when it is physically confined in nano pores. This work has been supported financially by Union College Faculty Research Fund, NSF-EEC 0939322 and New York State NASA space grant for financial support.

  12. Measurement and Model Validation of Nanofluid Specific Heat Capacity with Differential Scanning Calorimetry

    Directory of Open Access Journals (Sweden)

    Harry O'Hanley

    2012-01-01

    Full Text Available Nanofluids are being considered for heat transfer applications; therefore it is important to know their thermophysical properties accurately. In this paper we focused on nanofluid specific heat capacity. Currently, there exist two models to predict a nanofluid specific heat capacity as a function of nanoparticle concentration and material. Model I is a straight volume-weighted average; Model II is based on the assumption of thermal equilibrium between the particles and the surrounding fluid. These two models give significantly different predictions for a given system. Using differential scanning calorimetry (DSC, a robust experimental methodology for measuring the heat capacity of fluids, the specific heat capacities of water-based silica, alumina, and copper oxide nanofluids were measured. Nanoparticle concentrations were varied between 5 wt% and 50 wt%. Test results were found to be in excellent agreement with Model II, while the predictions of Model I deviated very significantly from the data. Therefore, Model II is recommended for nanofluids.

  13. Investigation of a Microcalorimeter for Thin-Film Heat Capacity Measurement

    Institute of Scientific and Technical Information of China (English)

    YU Jun; TANG Zhen-An; ZHANG Feng-Tian; WEI Guang-Fen; WANG Li-Ding

    2005-01-01

    @@ A microcalorimeter is studied for testing heat capacity of thin films. The microcalorimeter is a suspended membrane supported by six microbridges, which is fabricated by the front-side surface micromachining. Compared to the bulk miCro-machined one, the microcalorimeter has excellent mechanical strength and precisely controlled pattern size as well as good thermal characteristics that are essential to a microcalorimeter. The heating rate of the microcalorimeter is up to 2 × 105 K/s with 4.5mW heating power in vacuum, and the heat capacity of the corresponding empty microcalorimeter is about 23.4nJ/K at 300K. By a pulse calorimetry, the heat capacity of Al thin films with thickness of 40-1150nm are measured in the temperature range from 300K to 420K in vacuum. The mass of each sample is evaluated and the specific heat capacity is calculated. The results show that specific heat capacity of the 1150-nm Al film agrees well with the data of bulk Al reported in the literature. For the thinner films, enhanced heat capacity is observed.

  14. Heat Capacity Changes for Transition-State Analogue Binding and Catalysis with Human 5'-Methylthioadenosine Phosphorylase.

    Science.gov (United States)

    Firestone, Ross S; Cameron, Scott A; Karp, Jerome M; Arcus, Vickery L; Schramm, Vern L

    2017-02-17

    Human 5'-methylthioadenosine phosphorylase (MTAP) catalyzes the phosphorolysis of 5'-methylthioadenosine (MTA). Its action regulates cellular MTA and links polyamine synthesis to S-adenosylmethionine (AdoMet) salvage. Transition state analogues with picomolar dissociation constants bind to MTAP in an entropically driven process at physiological temperatures, suggesting increased hydrophobic character or dynamic structure for the complexes. Inhibitor binding exhibits a negative heat capacity change (-ΔCp), and thus the changes in enthalpy and entropy upon binding are strongly temperature-dependent. The ΔCp of inhibitor binding by isothermal titration calorimetry does not follow conventional trends and is contrary to that expected from the hydrophobic effect. Thus, ligands of increasing hydrophobicity bind with increasing values of ΔCp. Crystal structures of MTAP complexed to transition-state analogues MT-DADMe-ImmA, BT-DADMe-ImmA, PrT-ImmA, and a substrate analogue, MT-tubercidin, reveal similar active site contacts and overall protein structural parameters, despite large differences in ΔCp for binding. In addition, ΔCp values are not correlated with Kd values. Temperature dependence of presteady state kinetics revealed the chemical step for the MTAP reaction to have a negative heat capacity for transition state formation (-ΔCp(‡)). A comparison of the ΔCp(‡) for MTAP presteady state chemistry and ΔCp for inhibitor binding revealed those transition-state analogues most structurally and thermodynamically similar to the transition state. Molecular dynamics simulations of MTAP apoenzyme and complexes with MT-DADMe-ImmA and MT-tubercidin show small, but increased dynamic motion in the inhibited complexes. Variable temperature CD spectroscopy studies for MTAP-inhibitor complexes indicate remarkable protein thermal stability (to Tm = 99 °C) in complexes with transition-state analogues.

  15. Predictive model for the heat capacity of ionic liquids using the mass connectivity index

    Energy Technology Data Exchange (ETDEWEB)

    Valderrama, Jose O., E-mail: jvalderr@userena.cl [Univ. of La Serena, Fac. of Engineering, Dept. of Mech. Eng., Casilla 554, La Serena (Chile); Center for Technological Information (CIT), Casilla 724, La Serena (Chile); Martinez, Gwendolyn [Center for Technological Information (CIT), Casilla 724, La Serena (Chile); Univ. Nacional Pedro Ruiz Gallo, Fac. of Chemical Engineering, Lambayeque (Peru); Rojas, Roberto E. [Univ. of La Serena, Fac. of Sciences, Dept. of Chemistry, Casilla 554, La Serena (Chile)

    2011-01-20

    A simple and accurate model to predict the heat capacity of ionic liquids is presented. The proposed model considers variables readily available for ionic liquids and that have important effect on heat capacity, according to the literature information. Additionally a recently defined structural parameter known as mass connectivity index is incorporated into the model. A set of 602 heat capacity data for 146 ionic liquids have been used in the study. The results were compared with experimental data and with values reported by other available estimation methods. Results show that the new simple correlation gives low deviations and can be used with confidence in thermodynamic and engineering calculations.

  16. Low temperature anomaly of heat capacity of CD4 rotors in solid CD4-Kr solution

    OpenAIRE

    Bagatskii, M.I.; Dudkin, V. V.; Manzhelii, V. G.; Mashchenko, D. A.; Feodosiev, S. B.

    2004-01-01

    The heat capacity of the solid Kr-CD4 (13% CD4) solution has been investigated. It is shown that the temperature dependence of the heat capacity Crot of the rotational subsystem in this solution is radically different from the corresponding dependences in the previously studied Kr-CD4 (1%, 5% CD4) and Kr-CH4 (5-60%) solutions. A model is proposed to explain the observed dependence Crot(T). The experimental results can be described taking into account the contribution to the heat capacity from...

  17. Determination of the thermal conductivity and specific heat capacity of neem seeds by inverse problem method

    Directory of Open Access Journals (Sweden)

    S.N. Nnamchi

    2010-01-01

    Full Text Available Determination of the thermal conductivity and the specific heat capacity of neem seeds (Azadirachta indica A. Juss usingthe inverse method is the main subject of this work. One-dimensional formulation of heat conduction problem in a spherewas used. Finite difference method was adopted for the solution of the heat conduction problem. The thermal conductivityand the specific heat capacity were determined by least square method in conjunction with Levenberg-Marquardt algorithm.The results obtained compare favourably with those obtained experimentally. These results are useful in the analysis ofneem seeds drying and leaching processes.

  18. Mechanism of negative hydrogen ion emission from heated saline hydrides

    Energy Technology Data Exchange (ETDEWEB)

    Kawano, Hiroyuki; Serizawa, Naoshi; Takeda, Makiko; Hasegawa, Seiji [Ehime Univ., Matsuyama (Japan). Faculty of Science

    1997-02-01

    To find a clue to the mechanism of negative hydrogen ion emission from a heated sample ({approx}10 mg) of powdery saline hydride (LiH or CaH{sub 2}) deposited on a molybdenum ribbon ({approx}0.1 cm{sup 2}), both the ionic and electronic emission currents were measured as a function of sample temperature ({approx}700 - 800 K), thereby yielding {approx}10{sup -15} - 10{sup -12} A of H{sup -} after mass analysis and {approx}10{sup -7} - 10{sup -5} A of thermal electron. Thermophysical analysis of these data indicates that the desorption energy (E{sup -}) of H{sup -} and work function ({phi}) of the emitting sample surface are 5.1 {+-} 0.3 and 3.1 {+-} 0.2 eV for LiH, respectively, while E{sup -} is 7.7 {+-} 0.3 eV and {phi} is 5.0 {+-} 0.2 eV for CaH{sub 2}. Thermochemical analysis based on our simple model on the emissions indicates that the values of E{sup -} - {phi} are 2.35 and 2.31 eV for LiH and CaH{sub 2}, respectively, which are in fair agreement with the respective values (2.1 {+-} 0.3 and 2.6 {+-} 0.3 eV) determined experimentally. This agreement indicates that the emission of H{sup -} is reasonably explained by our model from the viewpoint of reaction energy. (author)

  19. Mitochondrial Spare Respiratory Capacity Is Negatively Correlated with Nuclear Reprogramming Efficiency

    DEFF Research Database (Denmark)

    Yan, Zhou; Al-Saaidi, Rasha Abdelkadhem; Fernandez Guerra, Paula;

    2017-01-01

    extracellular energy flux analyzer, we measured oxygen consumption rate (OCR) profiles of the cells, along with their nuclear reprogramming efficiency into iPSCs. Our results showed that fibroblasts with the lowest mitochondrial spare respiratory capacity (SRC) had the highest nuclear reprogramming efficiency...... of the modified fibroblasts and impaired reprogramming efficiency. Our findings indicate a negative correlation between high mitochondrial SRC in somatic cells and low reprogramming efficiencies. This type of analysis potentially allows screening and predicting reprogramming efficiency before reprogramming...

  20. Chemical thermodynamics of nuclear materials. Pt. 9. The high temperature heat capacity of plutonium-3. 2 at. % gallium alloy

    Energy Technology Data Exchange (ETDEWEB)

    Adams, R.O.; Oetting, F.L. (Rockwell International Corp., Golden, CO (USA). Energy Systems Group)

    The heat capacity of delta-stabilized plutonium (Pu-3.2 at.% Ga) has been determined from 330 to 700 K using an adiabatic calorimeter. It was found that a large portion of the total heat capacity in this temperature range is due to some combination of the electronic heat capacity and the anharmonic heat capacity. By including certain data from the literature, the thermal functions for this plutonium-gallium alloy were calculated in the temperature range 298 to 700 K.

  1. Prediction of heat capacities of solid inorganic salts from group contributions

    Energy Technology Data Exchange (ETDEWEB)

    Mostafa, A.T.M.G.; Eakman, J.M. [New Mexico State Univ., Las Cruces, NM (United States). Dept. of Chemical Engineering; Yarbro, S.L. [Los Alamos National Lab., NM (United States)

    1997-01-01

    A group contribution technique is proposed to predict the coefficients in the heat capacity correlation, C{sub p} = a + bT + c/T{sup 2} + dT{sup 2}, for solid inorganic salts. The results from this work are compared with fits to experimental data from the literature. It is shown to give good predictions for both simple and complex solid inorganic salts. Literature heat capacities for a large number (664) of solid inorganic salts covering a broad range of cations (129), anions (17) and ligands (2) have been used in regressions to obtain group contributions for the parameters in the heat capacity temperature function. A mean error of 3.18% is found when predicted values are compared with literature values for heat capacity at 298{degrees} K. Estimates of the error standard deviation from the regression for each additivity constant are also determined.

  2. High temperature heat capacity of PuPO{sub 4} monazite-analogue

    Energy Technology Data Exchange (ETDEWEB)

    Benes, Ondrej, E-mail: ondrej.benes@ec.europa.eu [European Commission, Joint Research Centre, Institute for Transuranium Elements, P.O. Box 2340, 76125 Karlsruhe (Germany); Popa, Karin [' Al.I. Cuza' University, Department of Chemistry, 11-Carol I Blvd., 700506 Iasi (Romania); Reuscher, Vivien [European Commission, Joint Research Centre, Institute for Transuranium Elements, P.O. Box 2340, 76125 Karlsruhe (Germany); Physikalisch-Chemisches Institut, Ruprecht-Karls-Universitaet Heidelberg, Im Neuenheimer Feld 253, 69120 Heidelberg (Germany); Zappia, Alessandro; Staicu, Dragos; Konings, Rudy J.M. [European Commission, Joint Research Centre, Institute for Transuranium Elements, P.O. Box 2340, 76125 Karlsruhe (Germany)

    2011-11-15

    Highlights: > The heat capacity of PuPO{sub 4} has been measured up to 1400 K. > Good agreement between the DSC and the drop technique has been found. > It was demonstrated that drop calorimetry is precise enough to measure relatively small samples. - Abstract: The enthalpy increments of PuPO{sub 4} have been measured using drop calorimetry in the temperature range from 530 K to 1386 K. The heat capacity was derived from the obtained data and compared with heat capacity data obtained directly from differential scanning calorimeter measured in this study from 400 K to 1400 K. The recommended heat capacity of PuPO{sub 4} was determined based on both techniques as: C{sub p}{sup 0}(JK{sup -1}mol{sup -1})=126.600+32.999x10{sup -3}(T/K)-1.9503x10{sup 6}(T/K){sup -2}.

  3. Experimental Study of the Thermal Diffusivity and Heat Capacity Concerning Some Duplex Stainless Steel

    Directory of Open Access Journals (Sweden)

    Riad Harwill Abdul Abas

    2015-06-01

    Full Text Available In the present work, thermal diffusivity and heat capacity measurements have been investigated in temperature range between RT and 1473 K for different duplex stainless steel supplied by Outokumpu Stainless AB, Sweden. The purpose of this study is to get a reliable thermophysical data of these alloys and to study the effect of microstructure on the thermal diffusivity and heat capacity value. Results show the ferrite content in the duplex stainless steel increased with temperature at equilibrium state. On the other hand, ferrite content increased with increasing Cr/Ni ratio and there is no significant effect of ferrite content on the thermal diffusivity value at room temperature. Furthermore, the heat capacity of all samples increases with temperature from room temperature to 473 K, while it decreases with increasing temperature until 1073 K. Then it increases with temperature at higher temperature. Curie temperature and sigma phase formation temperature can be detected by heat capacity-temperature curves.

  4. The heat capacity of solid antimony telluride Sb2Te3

    Science.gov (United States)

    Pashinkin, A. S.; Malkova, A. S.; Mikhailova, M. S.

    2008-05-01

    The literature data on the heat capacity of solid antimony telluride over the range 53 895 K were analyzed. The heat capacity of Sb2Te3 was measured over the range 350 700 K on a DSM-2M calorimeter. The equation for the temperature dependence was suggested. The thermodynamic functions of Sb2Te3 were calculated over the range 298.15 700 K.

  5. On the speed of sound and heat capacity of liquid neon in the subcritical region

    CERN Document Server

    Goncharov, A L; Postnikov, E B

    2016-01-01

    The data (the speed of sound, the isobaric and isochoric heat capacities as well as the heat capacity ratio) for liquid neon presented in NIST Chemistry WebBook are analyzed. It has been shown, basing on the representation of the inverse reduced volume fluctuations, that they consist of sufficient discrepancies in the subcritical region. The correction of data in this region of the coexistence curve is evaluated using the fluctuation approach and the theory of thermodynamic similarity.

  6. Calculation of heat capacities of light and heavy water by path-integral molecular dynamics

    Science.gov (United States)

    Shiga, Motoyuki; Shinoda, Wataru

    2005-10-01

    As an application of atomistic simulation methods to heat capacities, path-integral molecular dynamics has been used to calculate the constant-volume heat capacities of light and heavy water in the gas, liquid, and solid phases. While the classical simulation based on conventional molecular dynamics has estimated the heat capacities too high, the quantum simulation based on path-integral molecular dynamics has given reasonable results based on the simple point-charge/flexible potential model. The calculated heat capacities (divided by the Boltzmann constant) in the quantum simulation are 3.1 in the vapor H2O at 300 K, 6.9 in the liquid H2O at 300 K, and 4.1 in the ice IhH2O at 250 K, respectively, which are comparable to the experimental data of 3.04, 8.9, and 4.1, respectively. The quantum simulation also reproduces the isotope effect. The heat capacity in the liquid D2O has been calculated to be 10% higher than that of H2O, while it is 13% higher in the experiment. The results demonstrate that the path-integral simulation is a promising approach to quantitatively evaluate the heat capacities for molecular systems, taking account of quantum-mechanical vibrations as well as strongly anharmonic motions.

  7. Synthesis of Flexible Heat Exchanger Networks with Stream Splits Based on Rangers of Stream Supply Temperatures and Heat Capacity Flowrates

    Institute of Scientific and Technical Information of China (English)

    李志红; 罗行; 华贵; W.Roetzel

    2004-01-01

    A new superstructure model of heat exchanger networks (HEN) with stream splits based on rangers of streams supply temperatures and heat capacity flow rates is presented. The simultaneous optimal mathematical model of flexible HEN synthesis is established too. Firstly, the streams with rangers of supply temperatures and/or the streams with the rangers of heat capacity flow rates are pretreated; Secondly, several rules are proposed to establish the superstructure model of HEN with splits and the simultaneous optimal mathematical model of flexible HEN; Thirdly, the improving genetic algorithm is applied to solve the mathematical model established at the second step effectively, and the original optimal structure of HEN based on the maximum operation limiting condition can be obtained easily; Finally, the rules of heat exchange unit merged and the heat load of heat exchanger relaxed are presented, the flexible configuration of HEN satisfied the operation condition between the upper and down bounds of supply temperature and heat capacity flow rates can be obtained based on the original optimal structure of HEN by means of these rules. A case study demonstrates the method presented in this paper is effective

  8. Plastic and evolutionary responses to heat stress in a temperate dung fly: negative correlation between basal and induced heat tolerance?

    Science.gov (United States)

    Esperk, T; Kjaersgaard, A; Walters, R J; Berger, D; Blanckenhorn, W U

    2016-05-01

    Extreme weather events such as heat waves are becoming more frequent and intense. Populations can cope with elevated heat stress by evolving higher basal heat tolerance (evolutionary response) and/or stronger induced heat tolerance (plastic response). However, there is ongoing debate about whether basal and induced heat tolerance are negatively correlated and whether adaptive potential in heat tolerance is sufficient under ongoing climate warming. To evaluate the evolutionary potential of basal and induced heat tolerance, we performed experimental evolution on a temperate source population of the dung fly Sepsis punctum. Offspring of flies adapted to three thermal selection regimes (Hot, Cold and Reference) were subjected to acute heat stress after having been exposed to either a hot-acclimation or non-acclimation pretreatment. As different traits may respond differently to temperature stress, several physiological and life history traits were assessed. Condition dependence of the response was evaluated by exposing juveniles to different levels of developmental (food restriction/rearing density) stress. Heat knockdown times were highest, whereas acclimation effects were lowest in the Hot selection regime, indicating a negative association between basal and induced heat tolerance. However, survival, adult longevity, fecundity and fertility did not show such a pattern. Acclimation had positive effects in heat-shocked flies, but in the absence of heat stress hot-acclimated flies had reduced life spans relative to non-acclimated ones, thereby revealing a potential cost of acclimation. Moreover, body size positively affected heat tolerance and unstressed individuals were less prone to heat stress than stressed flies, offering support for energetic costs associated with heat tolerance. Overall, our results indicate that heat tolerance of temperate insects can evolve under rising temperatures, but this response could be limited by a negative relationship between basal and

  9. Heat Capacity of PbS: Isotope Effects

    OpenAIRE

    Cardona, M.; Kremer, R. K.; Lauck, R.; Siegle, G.; Serrano, J.; Romero, A. H.

    2007-01-01

    In recent years, the availability of highly pure stable isotopes has made possible the investigation of the dependence of the physical properties of crystals, in particular semiconductors, on their isotopic composition. Following the investigation of the specific heat ($C_p$, $C_v$) of monatomic crystals such as diamond, silicon, and germanium, similar investigations have been undertaken for the tetrahedral diatomic systems ZnO and GaN (wurtzite structure), for which the effect of the mass of...

  10. Analysis of the Storage Capacity in an Aggregated Heat Pump Portfolio

    DEFF Research Database (Denmark)

    Nielsen, Kirsten Mølgaard; Andersen, Palle; Pedersen, Tom Søndergård

    2015-01-01

    Energy storages connected to the power grid will be of great importance in the near future. A pilot project has investigated more than 100 single family houses with heat pumps all connected to the internet. The houses have large heat capacities and it is possible to move energy consumption...

  11. Heat transfer coefficient of wheel rim of large capacity steam turbines

    Institute of Scientific and Technical Information of China (English)

    Jinyuan SHI; Zhicheng DENG; Yu YANG; Ganwen JUN

    2008-01-01

    A way of calculating the overall equivalent heat transfer coefficient of wheel rims of large capacity steam turbines is presented. The method and formula to calculate the mean forced convection heat-transfer coefficient of the surface of the blade and for the bottom wall of the blade passage, are introduced. The heat transmission from the blade to the rim was simplified by analogy to heat transmission in the fins. A fin heat transfer model was then used to calculate the equivalent heat transfer coefficient of the blade passage. The overall equivalent heat transfer coefficient of the wheel rim was then calculated using a cylindrical surface model. A practical calculation example was presented. The pro-posed method helps determine the heat transfer bound-ary conditions in finite element analyses of temperature and thermal stress fields of steam turbine rotors.

  12. CHIP Knockdown Reduced Heat Shock Response and Protein Quality Control Capacity in Lens Epithelial Cells.

    Science.gov (United States)

    Zhang, W; Liu, Z; Bao, X; Qin, Y; Taylor, A; Shang, F; Wu, M

    2015-01-01

    Protein quality control (PQC) systems, including molecular chaperones and ubiquitin-proteasome pathway (UPP), plays an important role in maintaining intracellular protein homeostasis. Carboxyl terminus of Hsc70- interacting protein (CHIP) links the chaperone and UPPs, thus contributing to the repair or removal of damaged proteins. Over-expression of CHIP had previously been used to protect cells from environmental stress. In order to gain a more physiologic mechanism of the advantage conferred by CHIP, we induced a CHIP knockdown and monitored the ability of cells to cope with environmental stress. To knockdown CHIP, the human lens epithelial cell line HLE B3 was transfected with lentiviral particles that encode a CHIP short hairpin RNA (shRNA) or negative control lentiviral particles. Stable CHIP-knock down cells (KD) and negative control cells (NC) were selected with puromycin. After exposure to heat shock stress, there was no change observed in the expression of Hsp90. In contrast, Hsp70 levels increased significantly in NC cells but less so in KD cells. Hsp27 levels also increased after heat shock, but only in NC cells. Protein ubiquitination was reduced when CHIP was knocked down. CHIP knockdown reduced the ability to clear aggregation proteins. When same levels of aggregation-prone RFP-mutant crystallin fusion protein, RFP/V76D-γD, was expressed, there was ~9- fold more aggregates in KD cells as compared to that observed in NC cells. Furthermore, KD cells were more sensitive to toxicity of amino acid analog canavanine as compared to NC cells. Together, these data indicate that CHIP is required for PQC and that CHIP knockdown diminished cellular PQC capacity in lens cells.

  13. Ultrafast demagnetization of FePt:Cu thin films and the role of magnetic heat capacity

    Science.gov (United States)

    Kimling, Johannes; Kimling, Judith; Wilson, R. B.; Hebler, Birgit; Albrecht, Manfred; Cahill, David G.

    2014-12-01

    The phenomenon of different time scales of ultrafast demagnetization has attracted much attention. This so-called diversity of ultrafast demagnetization has been explained by the microscopic three temperature model (M3TM) and by the Landau-Lifshitz-Bloch model (LLBM). Here, we revisit the basic three temperature model (3TM) and provide a general criterion for explaining the different time scales observed. We focus on the role of magnetic heat capacity, which we find mainly determines the slowing down of the demagnetization time with increasing ambient temperature and laser fluence. In this context, we clarify the role of magnetic heat capacity in the M3TM and compare the 3TM with the LLBM. To illustrate the role of magnetic heat capacity, we present a simulation of ultrafast demagnetization of Ni. Furthermore, we present time-resolved magneto-optic Kerr effect measurements of ultrafast demagnetization and specific heat of Fe46Cu6Pt48 from 300 K to close to its Curie temperature. While most of the prior experimental research used high-fluence laser pulses causing sizable temperature excursions of the sample, our experiments involve small temperature excursions, which are crucial for studying the role of magnetic heat capacity in ultrafast demagnetization. Our experimental results corroborate that the slowing down of ultrafast demagnetization is dominated by the increase of the magnetic heat capacity near the Curie temperature.

  14. Measurements of thermal diffusivity, specific heat capacity and thermal conductivity with LFA 447 apparatus

    DEFF Research Database (Denmark)

    Zajas, Jan Jakub; Heiselberg, Per

    The LFA 447 can be successfully used for measurements of thermal diffusivity, specific heat and thermal conductivity of various samples. It is especially useful when determining the properties of materials on a very small scale. The matrix measurement mode allows for determining the local...... properties with a fine resolution, down to 1 millimeter. Special attention needs to be taken when determining the specific heat capacity in the comparative method. First of all, the test and reference sample should be of nearly identical thickness. Secondly, their heat diffusion time should be comparable, so...... that the heat losses from both samples during the measurement are similar. Finally, the leveling of the samples is very important. Very small discrepancies can cause a massive error in the derivation of specific heat capacity and, as a result, thermal conductivity....

  15. A heat capacity model of T(3/2) dependence for quantum dots.

    Science.gov (United States)

    Roslee, Amirul Edham; Muzakir, Saifful Kamaluddin; Ismail, Jamil; Yusoff, Mashitah M; Jose, Rajan

    2016-12-21

    This article addresses the heat capacity of quantum dots (QDs) using density functional theory (DFT). By analyzing the evolution of phonon density of states and heat capacity as CdSe clusters grow from a molecular cluster into larger quantum confined solids, we have shown that their heat capacity does not fit very well with the Debye T(3) model. We observed that the number of phonon modes, which is discrete, increases as the particles grow, and the dispersion relation shows a quadratic behavior in contrast to the bulk solids whose dispersion relation is linear and equal to the sound velocity. The phonon density of states showed a square root variation with respect to frequency whereas that of the bulk is a quadratic variation of frequency. From the observed variation in the phonon density of states and holding the fact that the atomic vibrations in solids are elastically coupled, we have re-derived the expression for total energy of the QDs and arrive at a T(3/2) model of heat capacity, which fits very well to the observed heat capacity data. These results give promising directions in the understanding of the evolution of the thermophysical properties of solids.

  16. Heat capacity and entropy of a GaAs quantum dot with Gaussian confinement.

    Science.gov (United States)

    Boyacioglu, B; Chatterjee, A

    2012-10-15

    The heat capacity and entropy effects in a GaAs quantum dot with Gaussian confinement are calculated in the presence of a magnetic field and its interaction with the electron spin using the canonical ensemble approach. It is shown that the heat capacity shows a Schottky-like anomaly at a low temperature, while it approaches a saturation value 2k(B) as the temperature increases. As a function of the magnetic field, the heat capacity shows a maximum and then reduces to zero. Also the width of the maximum becomes wider with temperature. It is also shown that the heat capacity remains constant up to a certain value of the confinement length beyond which it displays a monotonic increase. However as a function of the confinement strength, though the heat capacity initially shows a significant drop, it remains constant thereafter. At low temperatures like T = 10 and 20 K, the entropy is found to decrease with increasing magnetic field, but at higher temperatures, it remains almost independent of the magnetic field. At high temperatures, entropy shows a monotonic increase with temperature, but at a sufficiently low temperature as the magnetic field decreases, the entropy is found to develop a shoulder which becomes more and more pronounced with decreasing magnetic field.

  17. A Study of Specific Heat Capacity Functions of Polyvinyl Alcohol- Cassava Starch Blends

    Science.gov (United States)

    Sin, Lee Tin; Rahman, W. A. W. A.; Rahmat, A. R.; Morad, N. A.; Salleh, M. S. N.

    2010-03-01

    The specific heat capacity ( C sp) of polyvinyl alcohol (PVOH) blends with cassava starch (CSS) was studied by the differential scanning calorimetry method. Specimens of PVOH-CSS blends: PPV37 (70 mass% CSS) and PPV46 (60 mass% CSS) were prepared by a melt blending method with glycerol added as a plasticizer. The results showed that the specific heat capacity of PPV37 and PPV46 at temperatures from 330 K to 530 K increased from (2.963 to 14.995) J· g-1 · K-1 and (2.517 to 14.727) J · g-1· K-1, respectively. The specific heat capacity of PVOH-CSS depends on the amount of starch. The specific heat capacity of the specimens can be approximated by polynomial equations with a curve fitting regression > 0.992. For instance, the specific heat capacity (in J · g-1 · K-1) of PPV37 can be expressed by C sp = -17.824 + 0.063 T and PPV46 by C sp = -18.047 + 0.061 T, where T is the temperature (in K).

  18. Cooling and Heating Season Impacts of Right-Sizing of Fixed- and Variable-Capacity Heat Pumps With Attic and Indoor Ductwork

    Energy Technology Data Exchange (ETDEWEB)

    Cummings, James [Building America Partnership for Improved Residential Construction, Cocoa, FL (United States); Withers, Charles [Building America Partnership for Improved Residential Construction, Cocoa, FL (United States); Kono, Jamie [Building America Partnership for Improved Residential Construction, Cocoa, FL (United States)

    2015-06-01

    A new generation of central, ducted variable-capacity heat pump systems has come on the market, promising very high cooling and heating efficiency. They are controlled differently than standard fixed-capacity systems. Instead of cycling on at full capacity and then cycling off when the thermostat is satisfied, they vary their cooling and heating output over a wide range (approximately 40% - 118% of nominal full capacity), thus staying 'on' for 60% - 100% more hours per day compared to fixed -capacity systems. Experiments in this research examined the performance of 2-ton and 3-ton fixed- and variable-capacity systems and the impacts of system oversizing.

  19. Technical-and-Economic Efficiency of Draft Enriched with Oxygen in Small-Capacity Heating Boilers

    Directory of Open Access Journals (Sweden)

    P. Ratnikov

    2013-01-01

    Full Text Available Data on complex experimental and theoretical investigations pertaining to efficiency of oxygen-enriched draft in the small-capacity heating boilers as exemplified by the plant HEIZA (HW-S-10/K have been presented in the paper. The paper provides a calculation model of heating processes in heat generator burner (as exemplified by HEIZA plant. Simulation of heating processes in the operational zone has been executed in paper. The experimental data have proved model adequacy. The calculation scheme of the plant will be used in future for determination of power and ecological efficiency of draft enrichment with oxygen.

  20. Negative Joule Heating in Ion-Exchange Membranes

    OpenAIRE

    Biesheuvel, P. M.; D. Brogioli; Hamelers, H. V. M.

    2014-01-01

    In ion-exchange membrane processes, ions and water flow under the influence of gradients in hydrostatic pressure, ion chemical potential, and electrical potential (voltage), leading to solvent flow, ionic fluxes and ionic current. At the outer surfaces of the membranes, electrical double layers (EDLs) are formed (Donnan layers). When a current flows through the membrane, we argue that besides the positive Joule heating in the bulk of the membrane and in the electrolyte outside the membrane, t...

  1. Debye temperature, thermal expansion, and heat capacity of TcC up to 100 GPa

    Energy Technology Data Exchange (ETDEWEB)

    Song, T., E-mail: songting@mail.lzjtu.cn [School of Mathematics and Physics, Lanzhou Jiaotong University, Lanzhou 730070 (China); School of Material Science and Engineering, Lanzhou University of Technology, Lanzhou 730050 (China); Ma, Q. [School of Material Science and Engineering, Lanzhou University of Technology, Lanzhou 730050 (China); Tian, J.H. [School of Mathematics and Physics, Lanzhou Jiaotong University, Lanzhou 730070 (China); Liu, X.B. [School of Physics and Information Science, Tianshui Normal University, Tianshui 741000 (China); Ouyang, Y.H.; Zhang, C.L.; Su, W.F. [School of Mathematics and Physics, Lanzhou Jiaotong University, Lanzhou 730070 (China)

    2015-01-15

    Highlights: • A number of thermodynamic properties of rocksalt TcC are investigated for the first time. • The quasi-harmonic Debye model is applied to take into account the thermal effect. • The pressure and temperature up to about 100 GPa and 3000 K, respectively. - Abstract: Debye temperature, thermal expansion coefficient, and heat capacity of ideal stoichiometric TcC in the rocksalt structure have been studied systematically by using ab initio plane-wave pseudopotential density functional theory method within the generalized gradient approximation. Through the quasi-harmonic Debye model, in which the phononic effects are considered, the dependences of Debye temperature, thermal expansion coefficient, constant-volume heat capacity, and constant-pressure heat capacity on pressure and temperature are successfully predicted. All the thermodynamic properties of TcC with rocksalt phase have been predicted in the entire temperature range from 300 to 3000 K and pressure up to 100 GPa.

  2. Origin of the low temperature excess heat capacity of isotopically substituted acetylsalicylic acid

    Science.gov (United States)

    Schröder, F.; Winkler, B.; Bauer, J. D.; Haussühl, E.; Rivera Escoto, B.; Tristan López, F.; Avalos Borja, M.; Richter, C.; Ferner, J.

    2011-09-01

    The low temperature heat capacities of single crystals of fully protonated acetylsalicylic acid, measured between 2 K < T < 80 K, have been compared to samples in which the methyl-group was replaced by CD3, CH2D and 13CH3. For the partially methyl-deuterated crystal (CH2D) a significant excess heat capacity was found below T < 40 K with a broad maximum around T ≈ 14 K. The thermodynamic data are explained on the basis of a Schottky model using results obtained in earlier NMR and neutron spectroscopic experiments. In contrast, the excess heat capacity of the fully deuterated compound can be explained by a change of the phonon density of states.

  3. Correlation dependence of the volumetric thermal expansion coefficient of metallic aluminum on its heat capacity

    Science.gov (United States)

    Bodryakov, V. Yu.; Bykov, A. A.

    2016-05-01

    The correlation between the volumetric thermal expansion coefficient β( T) and the heat capacity C( T) of aluminum is considered in detail. It is shown that a clear correlation is observed in a significantly wider temperature range, up to the melting temperature of the metal, along with the low-temperature range where it is linear. The significant deviation of dependence β( C) from the low-temperature linear behavior is observed up to the point where the heat capacity achieves the classical Dulong-Petit limit of 3 R ( R is the universal gas constant).

  4. Investigations of temperature dependences of electrical resistivity and specific heat capacity of metals

    Energy Technology Data Exchange (ETDEWEB)

    Eser, Erhan, E-mail: eserphy@gmail.com [Department of Physics, Polatlı Faculty of Arts and Sciences, Gazi University, Polatlı, Ankara (Turkey); Koç, Hüseyin [Department of Electrical and Electronics Engineering, Faculty of Engineering, Muş Alparslan University, Muş (Turkey)

    2016-07-01

    In this study, we calculated the electrical resistivity and heat capacities of some ideal metals (Cu, Pt, and Pd) using a method that it employs the statistical model and Debye functions. The method is used to provide a simple and reliable analytical procedure for wide temperature range. The results obtained for the electrical resistivity and heat capacity have been compared with the results in literature. The results obtained at low temperature are in excellent agreement with experimental and theoretical results. Finally the used approximation and analytical method are a useful approach to calculate thermophysical properties of metals.

  5. Investigation of laser diode face-pumped high average power heat capacity laser

    Institute of Scientific and Technical Information of China (English)

    Shenjin Zhang; Shouhuan Zhou; Xiaojun Tang; Guojiang Bi; Huachang LV

    2006-01-01

    The three-dimensional (3D) pump intensity distribution in medium of the laser diode (LD) pumped highaverage power heat capacity laser is simulated by the ray tracing method, and the divergence characteristicsof fast axis and slow axis of LD are simultaneously considered. The transient 3D temperature and stressdistributions are also simulated by the finite element method (FEM) with considering the uneven heatsource distribution in medium. A LD face-pumped Nd:GGG heat capacity laser is designed. The averageoutput power is 1.49 kW with an optical-optical efficiency of 24.1%.

  6. Negative plates for dry-charged lead storage batteries. [higher charging capacity when impregnated with tannin solution

    Energy Technology Data Exchange (ETDEWEB)

    Fiedler, V.; Malikova, V.; Weber, H.

    1970-09-15

    Impregnation of negative plates with acid solutions of sulfomethylated tannins was found to improve the charging properties at low temperatures. Methods for synthesizing tannins are described. Charging capacity at 0/sup 0/ was 7.3A. (RWR)

  7. The dependence of isobaric thermal heat capacity of gas condensates in liquid phase on their temperature

    Directory of Open Access Journals (Sweden)

    Bukhovich Y. V.

    2015-09-01

    Full Text Available The study of the thermo-physical properties of liquids gives an opportunity of qualitative and quantitative evaluation of condensed matter theory, phase transitions and critical phenomena. To forecast the thermo-dynamic properties of liquid natural hydrocarbons one must know the basic heat-physical characteristics in a wide range of condition parameters. We have researched specific isobaric thermal heat capacity of gas condensates of Oposhnyanskoye, Solokhovskoye, Bukharskoye, Rybalskoye, Stavropolskoye, Schebelinskoye and Yubileinoye deposits theoretically and experimentally. These substances were in liquid phase on pseudo-critical isobar in the range of temperatures from minus 40 till 100 °C. In the article the findings of the investigation are presented. The mean relative experimental error doesn’t exceed ± 1.5 %, with reliability 0.95. The universal equation expressing specific isobaric thermal heat capacity as the function of temperature and molar mass has been obtained. It describes specific isobaric thermal heat capacity on pseudo-critical isobar for investigated natural hydrocarbons with the mean relative error, which does not exceed ± 1.65 %. The use of the equation for the calculation of specific isobaric thermal heat capacity of the substances of other deposits is recommended

  8. Heat capacities and thermal diffusivities of n-alkane acid ethyl esters—biodiesel fuel components

    Science.gov (United States)

    Bogatishcheva, N. S.; Faizullin, M. Z.; Nikitin, E. D.

    2017-09-01

    The heat capacities and thermal diffusivities of ethyl esters of liquid n-alkane acids C n H2 n-1O2C2H5 with the number of carbon atoms in the parent acid n = 10, 11, 12, 14, and 16 are measured. The heat capacities are measured using a DSC 204 F1 Phoenix heat flux differential scanning calorimeter (Netzsch, Germany) in the temperature range of 305-375 K. Thermal diffusivities are measured by means of laser flash method on an LFA-457 instrument (Netzsch, Germany) at temperatures of 305-400 K. An equation is derived for the dependence of the molar heat capacities of the investigated esters on temperature. It is shown that the dependence of molar heat capacity C p,m (298.15 K) on n ( n = 1-6) is close to linear. The dependence of thermal diffusivity on temperature in the investigated temperature range is described by a first-degree polynomial, but thermal diffusivity a (298.15 K) as a function of n has a minimum at n = 5.

  9. Research on the Specific Heat Capacity of PBX Formulations Based on RDX

    Directory of Open Access Journals (Sweden)

    Flávio Rodrigues Chaves

    2016-07-01

    Full Text Available The experimental results of specific heat capacity of 2 plastic bonded explosives formulations based on 1,3,5-trinitroperhydro-1,3,5-triazine, using differential scanning calorimetry thermal analysis, and the theoretical ones calculated with the specific heat capacity and mass fraction of individual compounds are compared for a temperature range between 340 and 410 K. Apart the filler, the plastic bonded explosives composition includes the binder based on hydroxyl-terminated polybutadiene, the plasticizer bis (2-ethylhexyl sebacate and the curing agent isophorone diisocyanate. The experimental and theoretical results showed a better approach when no curing agent is added. Without curing agent, the specific heat capacity of plastic bonded explosives increases linearly with temperature. When plastic bonded explosive is cured, the specific heat capacity is nearly constant until 380 K and decreases linearly for higher temperature values. These results suggest that phase change requires adjusting parameters to different heating rates in order to describe adequately the experimental data.

  10. Heat Capacity Uncertainty Calculation for the Eutectic Mixture of Biphenyl/Diphenyl Ether Used as Heat Transfer Fluid: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Gomez, J. C.; Glatzmaier, G. C.; Mehos, M.

    2012-09-01

    The main objective of this study was to calculate the uncertainty at 95% confidence for the experimental values of heat capacity of the eutectic mixture of biphenyl/diphenyl ether (Therminol VP-1) determined from 300 to 370 degrees C. Twenty-five samples were evaluated using differential scanning calorimetry (DSC) to obtain the sample heat flow as a function of temperature. The ASTM E-1269-05 standard was used to determine the heat capacity using DSC evaluations. High-pressure crucibles were employed to contain the sample in the liquid state without vaporizing. Sample handling has a significant impact on the random uncertainty. It was determined that the fluid is difficult to handle, and a high variability of the data was produced. The heat capacity of Therminol VP-1 between 300 and 370 degrees C was measured to be equal to 0.0025T+0.8672 with an uncertainty of +/- 0.074 J/g.K (3.09%) at 95% confidence with T (temperature) in Kelvin.

  11. Continuum-atomistic simulation of picosecond laser heating of copper with electron heat capacity from ab initio calculation

    Science.gov (United States)

    Ji, Pengfei; Zhang, Yuwen

    2016-03-01

    On the basis of ab initio quantum mechanics (QM) calculation, the obtained electron heat capacity is implemented into energy equation of electron subsystem in two temperature model (TTM). Upon laser irradiation on the copper film, energy transfer from the electron subsystem to the lattice subsystem is modeled by including the electron-phonon coupling factor in molecular dynamics (MD) and TTM coupled simulation. The results show temperature and thermal melting difference between the QM-MD-TTM integrated simulation and pure MD-TTM coupled simulation. The successful construction of the QM-MD-TTM integrated simulation provides a general way that is accessible to other metals in laser heating.

  12. Continuum-atomistic simulation of picosecond laser heating of copper with electron heat capacity from ab initio calculation

    CERN Document Server

    Ji, Pengfei

    2016-01-01

    On the basis of ab initio quantum mechanics (QM) calculation, the obtained electron heat capacity is implemented into energy equation of electron subsystem in two temperature model (TTM). Upon laser irradiation on the copper film, energy transfer from the electron subsystem to the lattice subsystem is modeled by including the electron-phonon coupling factor in molecular dynamics (MD) and TTM coupled simulation. The results show temperature and thermal melting difference between the QM-MD-TTM integrated simulation and pure MD-TTM coupled simulation. The successful construction of the QM-MD-TTM integrated simulation provide a general way that is accessible to other metals in laser heating.

  13. Building America Case Study: Impact of Improved Duct Insulation on Fixed-Capacity (SEER 13) and Variable-Capacity (SEER 22) Heat Pumps, Cocoa, Florida

    Energy Technology Data Exchange (ETDEWEB)

    C. Withers, J. Cummings, B. Nigusse, E. Martin

    2017-04-01

    A new generation of central, ducted variable-capacity heat pump systems has come on the market, promising very high cooling and heating efficiency. Instead of cycling on at full capacity and then cycling off when the thermostat is satisfied, they vary their cooling and heating output over a wide range (approximately 40 to 118% of nominal full capacity); thus, staying 'on' for 60% to 100% more hours per day compared to fixed-capacity systems. Current Phase 4 experiments in an instrumented lab home with simulated occupancy evaluate the impact of duct R-value enhancement on the overall operating efficiency of the variable-capacity system compared to the fixed-capacity system.

  14. Heat capacity and transition behavior of sucrose by standard, fast scanning and temperature-modulated calorimetry

    Energy Technology Data Exchange (ETDEWEB)

    Magoń, A. [Department of Chemistry, University of Technology, 35-959 Rzeszów (Poland); Wurm, A.; Schick, C. [Department of Physics, University of Rostock, 18057 Rostock (Germany); Pangloli, Ph.; Zivanovic, S. [Department of Food Science and Technology, University of Tennessee, Knoxville, TN 37996 (United States); Skotnicki, M. [Department of Pharmaceutical Technology, Poznan University of Medical Sciences, 60-780 Poznań (Poland); Pyda, M., E-mail: mpyda@utk.edu [Department of Chemistry, University of Technology, 35-959 Rzeszów (Poland)

    2014-08-10

    Highlights: • Experimental, apparent heat capacity of sucrose was investigated by advanced thermal analysis. • Vibrational heat capacity of solid state was linked with a low temperature experimental heat capacity of sucrose. • Equilibrium melting parameters of sucrose were determined. • Decomposition, superheating of crystalline sucrose during melting process were presented. • TGA, DSC, TMDSC, and FSC are useful tools for characterization of sucrose. - Abstract: The heat capacity (C{sub p}) of crystalline and amorphous sucrose was determined using standard and quasi-isothermal temperature modulated differential scanning calorimetry. The results were combined with the published data determined by adiabatic calorimetry, and the C{sub p} values are now reported for the wide 5–600 K range. The experimental C{sub p} of solid sucrose at 5–300 K was used to calculate the vibrational, solid C{sub p} based on the vibrational molecular motions. The calculated solid and liquid C{sub p} together with the transition parameters for equilibrium conditions were used as references for detailed quantitative thermal analysis of crystalline and amorphous sucrose. Melting temperature (T{sub m}) of the crystalline sucrose was identified in a broad 442–465 K range with a heat of fusion of 40–46 J/mol determined at heating rates 0.5–20 K/min, respectively. The equilibrium T{sub m} and heat of fusion of crystalline sucrose were estimated at zero heating rate as T{sup o}{sub m} = 424.4 K and ΔH{sup o}{sub f} = 32 kJ/mol, respectively. The glass transition temperature (T{sub g}) of amorphous sucrose was at 331 K with a change in C{sub p} of 267 J/(mol K) as it was estimated from reversing heat capacity by quasi-isothermal TMDSC on cooling. At heating rates less than 30 K/min, thermal decomposition occurred during melting, while at extreme rate of 1000 K/s, degradation was not observed. Data obtained by fast scanning calorimetry (FSC) at 1000 K/s, showed that T{sub m} was

  15. Liquid heat capacity of the solvent system (piperazine + 2-amino-2-methyl-l-propanol + water)

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Y.-R. [R and D Center for Membrane Technology and Department of Chemical Engineering, Chung Yuan Christian University, Chung Li 32023, Taiwan (China); Caparanga, Alvin R.; Soriano, Allan N. [R and D Center for Membrane Technology and Department of Chemical Engineering, Chung Yuan Christian University, Chung Li 32023, Taiwan (China); School of Chemical Engineering and Chemistry, Mapua Institute of Technology, Intramuros, Manila 1002 (Philippines); Li, M.-H., E-mail: mhli@cycu.edu.t [R and D Center for Membrane Technology and Department of Chemical Engineering, Chung Yuan Christian University, Chung Li 32023, Taiwan (China)

    2010-04-15

    This report presents a new set of heat capacity data for the system piperazine left brace(PZ) + 2-amino-2-methyl-1-propanol (AMP) + water (H{sub 2}O)right brace, measured using the differential scanning calorimetry technique, over the temperature range 303.2 K to 353.2 K and at fourteen (14) different concentrations in which the water mole fractions, x{sub 3}'s, were fixed at 0.60, 0.70, 0.80, and 0.90. Heat capacity for the binary system left bracePZ (1) + AMP (2)right brace at x{sub 1} = 0.05, 0.10, 0.15, and 0.20 were, likewise, measured to generate parameters necessary in the Redlich-Kister-type model, which was used to estimate excess molar heat capacities. Such estimates were then used to predict the values of the molar heat capacity at the corresponding sets of temperature and concentration. The predicted values were subsequently compared against the measured values and the results are satisfactory.

  16. Low-temperature heat capacity and thermodynamic functions of vitamin B{sub 12}

    Energy Technology Data Exchange (ETDEWEB)

    Knyazev, A.V., E-mail: knyazevav@gmail.com; Smirnova, N.N.; Plesovskikh, A.S.; Shushunov, A.N.; Knyazeva, S.S.

    2014-04-01

    Graphical abstract: - Highlights: • Temperature dependence of heat capacity of vitamin B{sub 12} has been measured by precision adiabatic vacuum calorimetry. • The thermodynamic functions of the vitamin B{sub 12} have been determined for the range from T → 0 to 343 K. • The character of heterodynamics of structure was detected. • The thermal stability of cyanocobalamin was studied by differential scanning calorimetry. - Abstract: In the present work temperature dependence of heat capacity of vitamin B{sub 12} (cyanocobalamin) has been measured for the first time in the range from 6 to 343 K by precision adiabatic vacuum calorimetry. Based on the experimental data, the thermodynamic functions of the vitamin B{sub 12}, namely, the heat capacity, enthalpy H°(T) − H°(0), entropy S°(T) − S°(0) and Gibbs function G°(T) − H°(0) have been determined for the range from T → 0 to 343 K. The value of the fractal dimension D in the function of multifractal generalization of Debye's theory of the heat capacity of solids was estimated and the character of heterodynamics of structure was detected. The thermal stability of cyanocobalamin was also studied by differential scanning calorimetry.

  17. Heat capacity singularity of binary liquid mixtures at the liquid-liquid critical point.

    Science.gov (United States)

    Méndez-Castro, Pablo; Troncoso, Jacobo; Peleteiro, José; Romaní, Luis

    2013-10-01

    The critical anomaly of the isobaric molar heat capacity for the liquid-liquid phase transition in binary nonionic mixtures is explained through a theory based on the general assumption that their partition function can be exactly mapped into that of the Ising three-dimensional model. Under this approximation, it is found that the heat capacity singularity is directly linked to molar excess enthalpy. In order to check this prediction and complete the available data for such systems, isobaric molar heat capacity and molar excess enthalpy near the liquid-liquid critical point were experimentally determined for a large set of binary liquid mixtures. Agreement between theory and experimental results-both from literature and from present work-is good for most cases. This fact opens a way for explaining and predicting the heat capacity divergence at the liquid-liquid critical point through basically the same microscopic arguments as for molar excess enthalpy, widely used in the frame of solution thermodynamics.

  18. Modeling the Heat Capacity of Spider Silk Inspired Di-block Copolymers

    Science.gov (United States)

    Huang, W.; Krishnaji, S.; Kaplan, D.; Cebe, P.

    2011-03-01

    We synthesized and characterized a new family of di-block copolymers based on the amino acid sequences of Nephila clavipes major ampulate dragline spider silk, having the form HABn and HBAn (n=1-6), comprising an alanine-rich hydrophobic block, A, a glycine-rich hydrophilic block, B, and a histidine tag, H. Using temperature modulated differential scanning calorimetry (TMDSC), we captured the effect of bound water acting as a plasticizer for copolymer films which had been cast from water solution and dried. We determined the water content by thermogravimetry and used the weight loss vs. temperature to correct the mass in TMDSC experiments. Our result shows that non-freezing bound water has a strong plasticization effect which lowers the onset of the glass transition by about 10circ; C. The reversing heat capacities, Cp(T), for temperatures below and above the glass transition were also characterized by TMDSC. We then calculated the solid state heat capacities of our novel block copolymers below the glass transition (Tg) based on the vibrational motions of the constituent poly(amino acid)s, whose heat capacities are known from the ATHAS Data Bank. Excellent agreement was found between the measured and calculated values of the heat capacity, showing that this model can serve as a standard method to predict the solid state Cp for other biologically inspired block copolymers. Support was provided from the NSF CBET-0828028 and the MRI Program under DMR-0520655 for thermal analysis instrumentation.

  19. THE HEAT CAPACITY OF FLUORINATED PROPANE AND BUTANE DERIVATIVES BY DIFFERENTIAL SCANNING CALORIMETRY

    Science.gov (United States)

    The paper gives results of the measurement (to 3% accuracy) of the constant-pressure liquid-phase heat capacities of 21 hydrogen-containing fluorinated propane and butane derivatives and one fluorinated ether (CF3OCF2H) with boiling points ranging from -34.6 to 76.7 C, using diff...

  20. THE HEAT CAPACITY OF FLUORINATED PROPANE AND BUTANE DERIVATIVES BY DIFFERENTIAL SCANNING CALORIMETRY

    Science.gov (United States)

    The paper gives results of the measurement (to 3% accuracy) of the constant-pressure liquid-phase heat capacities of 21 hydrogen-containing fluorinated propane and butane derivatives and one fluorinated ether (CF3OCF2H) with boiling points ranging from -34.6 to 76.7 C, using diff...

  1. The Determination of Heat Capacity Ratios in a Simple Open System

    Science.gov (United States)

    Holden, Glen L.

    2007-01-01

    A virtually closed system is treated as open and compared to known results. The classic experiment of Clement and Desormes provides the conceptual framework for this open system approach in determining the molar heat capacity ratios, lambda. This alternate view, extends the theoretical treatment beyond the first law of thermodynamics for closed…

  2. First-principles calculations of heat capacities of ultrafast laser-excited electrons in metals

    Science.gov (United States)

    Bévillon, E.; Colombier, J. P.; Recoules, V.; Stoian, R.

    2015-05-01

    Ultrafast laser excitation can induce fast increases of the electronic subsystem temperature. The subsequent electronic evolutions in terms of band structure and energy distribution can determine the change of several thermodynamic properties, including one essential for energy deposition; the electronic heat capacity. Using density functional calculations performed at finite electronic temperatures, the electronic heat capacities dependent on electronic temperatures are obtained for a series of metals, including free electron like, transition and noble metals. The effect of exchange and correlation functionals and the presence of semicore electrons on electronic heat capacities are first evaluated and found to be negligible in most cases. Then, we tested the validity of the free electron approaches, varying the number of free electrons per atom. This shows that only simple metals can be correctly fitted with these approaches. For transition metals, the presence of localized d electrons produces a strong deviation toward high energies of the electronic heat capacities, implying that more energy is needed to thermally excite them, compared to free sp electrons. This is attributed to collective excitation effects strengthened by a change of the electronic screening at high temperature.

  3. Evaluation of a large capacity heat pump concept for active cooling of hypersonic aircraft structure

    Science.gov (United States)

    Pagel, L. L.; Herring, R. L.

    1978-01-01

    Results of engineering analyses assessing the conceptual feasibility of a large capacity heat pump for enhancing active cooling of hypersonic aircraft structure are presented. A unique heat pump arrangement which permits cooling the structure of a Mach 6 transport to aluminum temperatures without the aid of thermal shielding is described. The selected concept is compatible with the use of conventional refrigerants, with Freon R-11 selected as the preferred refrigerant. Condenser temperatures were limited to levels compatible with the use of conventional refrigerants by incorporating a unique multipass condenser design, which extracts mechanical energy from the hydrogen fuel, prior to each subsequent pass through the condenser. Results show that it is technically feasible to use a large capacity heat pump in lieu of external shielding. Additional analyses are required to optimally apply this concept.

  4. Enhancing heat capacity of colloidal suspension using nanoscale encapsulated phase-change materials for heat transfer.

    Science.gov (United States)

    Hong, Yan; Ding, Shujiang; Wu, Wei; Hu, Jianjun; Voevodin, Andrey A; Gschwender, Lois; Snyder, Ed; Chow, Louis; Su, Ming

    2010-06-01

    This paper describes a new method to enhance the heat-transfer property of a single-phase liquid by adding encapsulated phase-change nanoparticles (nano-PCMs), which absorb thermal energy during solid-liquid phase changes. Silica-encapsulated indium nanoparticles and polymer-encapsulated paraffin (wax) nanoparticles have been made using colloid method, and suspended into poly-alpha-olefin (PAO) and water for potential high- and low-temperature applications, respectively. The shells prevent leakage and agglomeration of molten phase-change materials, and enhance the dielectric properties of indium nanoparticles. The heat-transfer coefficients of PAO containing indium nanoparticles (30% by mass) and water containing paraffin nanoparticles (10% by mass) are 1.6 and 1.75 times higher than those of corresponding single-phase fluids. The structural integrity of encapsulation allows repeated use of such nanoparticles for many cycles in high heat generating devices.

  5. Final Report: Cooling Seasonal Energy and Peak Demand Impacts of Improved Duct Insulation on Fixed-Capacity (SEER 13) and Variable-Capacity (SEER 22) Heat Pumps

    Energy Technology Data Exchange (ETDEWEB)

    Withers, C. [Building America Partnership for Improved Residential Construction, Cocoa, FL (United States); Florida Solar Energy Center, Cocoa, FL (United States); Cummings, J. [Building America Partnership for Improved Residential Construction, Cocoa, FL (United States); Florida Solar Energy Center, Cocoa, FL (United States); Nigusse, B. [Building America Partnership for Improved Residential Construction, Cocoa, FL (United States); Florida Solar Energy Center, Cocoa, FL (United States)

    2016-09-08

    A new generation of full variable-capacity, central, ducted air-conditioning (AC) and heat pump units has come on the market, and they promise to deliver increased cooling (and heating) efficiency. They are controlled differently than standard single-capacity (fixed-capacity) systems. Instead of cycling on at full capacity and then cycling off when the thermostat is satisfied, they can vary their capacity over a wide range (approximately 40% to 118% of nominal full capacity), thus staying “on” for up to twice as many hours per day compared to fixed-capacity systems of the same nominal capacity. The heating and cooling capacity is varied by adjusting the indoor fan air flow rate, compressor, and refrigerant flow rate as well as the outdoor unit fan air flow rate. Note that two-stage AC or heat pump systems were not evaluated in this research effort. The term dwell is used to refer to the amount of time distributed air spends inside ductwork during space-conditioning cycles. Longer run times mean greater dwell time and therefore greater exposure to conductive gains and losses.

  6. Final Report: Cooling Seasonal Energy and Peak Demand Impacts of Improved Duct Insulation on Fixed-Capacity (SEER 13) and Variable-Capacity (SEER 22) Heat Pumps

    Energy Technology Data Exchange (ETDEWEB)

    Withers, C. [Building America Partnership for Improved Residential Construction, Cocoa, FL (United States); Florida Solar Energy Center (FSEC), Cocoa, FL (United States); Cummings, J. [Building America Partnership for Improved Residential Construction, Cocoa, FL (United States); Florida Solar Energy Center (FSEC), Cocoa, FL (United States); Nigusse, B. [Building America Partnership for Improved Residential Construction, Cocoa, FL (United States); Florida Solar Energy Center (FSEC), Cocoa, FL (United States)

    2016-09-01

    A new generation of full variable-capacity, central, ducted air-conditioning (AC) and heat pump units has come on the market, and they promise to deliver increased cooling (and heating) efficiency. They are controlled differently than standard single-capacity (fixed-capacity) systems. Instead of cycling on at full capacity and then cycling off when the thermostat is satisfied, they can vary their capacity over a wide range (approximately 40% to 118% of nominal full capacity), thus staying “on” for up to twice as many hours per day compared to fixed-capacity systems of the same nominal capacity. The heating and cooling capacity is varied by adjusting the indoor fan air flow rate, compressor, and refrigerant flow rate as well as the outdoor unit fan air flow rate. Note that two-stage AC or heat pump systems were not evaluated in this research effort. The term dwell is used to refer to the amount of time distributed air spends inside ductwork during space-conditioning cycles. Longer run times mean greater dwell time and therefore greater exposure to conductive gains and losses.

  7. The effective heat capacity of the building envelope; Bygningsdeles effektive varmekapacitet

    Energy Technology Data Exchange (ETDEWEB)

    Rose, J.

    2000-12-01

    This report presents an evaluation of the methods described in the European standards, EN 832 and prEN ISO 13786, concerning the calculation of the heating demand for buildings, taking into account the effect of the effective heat capacity of the building envelope. The evaluation is carried out by comparing results obtained using the European standards with results from the building simulation program tsbi3. In addition the report shows the influence of the heat capacity on the heat demand for a typical 1-family residential building. The report heads of with a short description of the background for and purpose of the report, followed by a short description of the approach that is taken for the analysis. After this a description of the method given in the European standards is presented. The description is a more or less direct translation of the standards, however a few explanatory comments are added in order to explain better the background of the method. The project describes the method for calculating the heat demand, taking into account the effective heat capacity (EN 832) and how the effective heat capacity of a building component is calculated (prEN ISO 13786). Three test houses used for the comparison are described. The three test houses are modelled with different building components, varying from light constructions to heavy constructions. The transmission coefficients for the building components are the same from house to house, and therefore the only difference is the total thermal mass of the houses. The calculation of the heat demand for each of the three test houses, using both calculation methods, is described. First the calculations are carried out using EN 832 and then by using tsbi3. Calculations show that EN 832 expects a larger influence of the thermal mass of the buildings than tsbi3 does. Therefore a number of parametric variations for the tsbi3 calculation is performed in an attempt to explain the differences. The analysis shows that it is

  8. Heat capacity and latent heat measurements of CoMnSi using a microcalorimeter.

    Science.gov (United States)

    Miyoshi, Y; Morrison, K; Moore, J D; Caplin, A D; Cohen, L F

    2008-07-01

    A new method of utilizing a commercial silicon nitride membrane calorimeter to measure the latent heat at a first order phase transition is presented. The method is a direct measurement of the thermoelectric voltage jump induced by the latent heat, in a thermally isolated system ideally suited for single crystal and small microgram samples. We show that when combined with the ac calorimetry technique previously developed, the resultant thermal measurement capabilities are extremely powerful. We demonstrate the applicability of the combined method with measurements on a 100 microm size fragment of CoMnSi exhibiting a sizable magnetocaloric effect near room temperature, and obtain good agreement with previously reported values on bulk samples.

  9. Electron cyclotron resonance heating by magnetic filter field in a negative hydrogen ion source

    Energy Technology Data Exchange (ETDEWEB)

    Kim, June Young, E-mail: beacoolguy@snu.ac.kr; Cho, Won-Hwi; Dang, Jeong-Jeung; Chung, Kyoung-Jae, E-mail: jkjlsh1@snu.ac.kr; Hwang, Y. S. [Department of Nuclear Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of)

    2016-02-15

    The influence of magnetic filter field on plasma properties in the heating region has been investigated in a planar-type inductively coupled radio-frequency (RF) H{sup −} ion source. Besides filtering high energy electrons near the extraction region, the magnetic filter field is clearly observed to increase the electron temperature in the heating region at low pressure discharge. With increasing the operating pressure, enhancement of electron temperature in the heating region is reduced. The possibility of electron cyclotron resonance (ECR) heating in the heating region due to stray magnetic field generated by a filter magnet located at the extraction region is examined. It is found that ECR heating by RF wave field in the discharge region, where the strength of an axial magnetic field is approximately ∼4.8 G, can effectively heat low energy electrons. Depletion of low energy electrons in the electron energy distribution function measured at the heating region supports the occurrence of ECR heating. The present study suggests that addition of axial magnetic field as small as several G by an external electromagnet or permanent magnets can greatly increase the generation of highly ro-vibrationally excited hydrogen molecules in the heating region, thus improving the performance of H{sup −} ion generation in volume-produced negative hydrogen ion sources.

  10. Low-temperature heat capacity and localized vibrational modes in natural and synthetic tetrahedrites

    Science.gov (United States)

    Lara-Curzio, E.; May, A. F.; Delaire, O.; McGuire, M. A.; Lu, X.; Liu, Cheng-Yun; Case, E. D.; Morelli, D. T.

    2014-05-01

    The heat capacity of natural (Cu12-x (Fe, Zn, Ag)x(Sb, As)4S13) and synthetic (Cu12-xZnxSb4S13 with x = 0, 1, 2) tetrahedrite compounds was measured between 2 K and 380 K. It was found that the temperature dependence of the heat capacity can be described using a Debye term and three Einstein oscillators with characteristic temperatures that correspond to energies of ˜1.0 meV, ˜2.8 meV, and ˜8.4 meV. The existence of localized vibrational modes, which are assigned to the displacements of the trigonally coordinated Cu atoms in the structure, is discussed in the context of anharmonicity and its effect on the low lattice thermal conductivity exhibited by these compounds.

  11. Influence of heat treatment on antioxidant capacity and (poly)phenolic compounds of selected vegetables.

    Science.gov (United States)

    Juániz, Isabel; Ludwig, Iziar A; Huarte, Estibaliz; Pereira-Caro, Gema; Moreno-Rojas, Jose Manuel; Cid, Concepción; De Peña, María-Paz

    2016-04-15

    The impact of cooking heat treatments (frying in olive oil, frying in sunflower oil and griddled) on the antioxidant capacity and (poly)phenolic compounds of onion, green pepper and cardoon, was evaluated. The main compounds were quercetin and isorhamnetin derivates in onion, quercetin and luteolin derivates in green pepper samples, and chlorogenic acids in cardoon. All heat treatments tended to increase the concentration of phenolic compounds in vegetables suggesting a thermal destruction of cell walls and sub cellular compartments during the cooking process that favor the release of these compounds. This increase, specially that observed for chlorogenic acids, was significantly correlated with an increase in the antioxidant capacity measured by DPPH (r=0.70). Griddled vegetables, because of the higher temperature applied during treatment in comparison with frying processes, showed the highest amounts of phenolic compounds with increments of 57.35%, 25.55% and 203.06% compared to raw onion, pepper and cardoon, respectively.

  12. AC measurement of heat capacity and magnetocaloric effect for pulsed magnetic fields.

    Science.gov (United States)

    Kohama, Yoshimitsu; Marcenat, Christophe; Klein, Thierry; Jaime, Marcelo

    2010-10-01

    A new calorimeter for measurements of the heat capacity and magnetocaloric effect of small samples in pulsed magnetic fields is discussed for the exploration of thermal and thermodynamic properties at temperatures down to 2 K. We tested the method up to μ(0)H=50 T, but it could be extended to higher fields. For these measurements we used carefully calibrated bare-chip Cernox(®) and RuO(2) thermometers, and we present a comparison of their performances. The monotonic temperature and magnetic field dependences of the magnetoresistance of RuO(2) allow thermometry with a precision as good as ±4 mK at T=2 K. To test the performance of our calorimeter, heat capacity and magnetocaloric effect for the spin-dimer compound Sr(3)Cr(2)O(8) and the triangular lattice antiferromagnet RbFe(MoO(4))(2) are presented.

  13. Changes in molar volume and heat capacity of actin upon polymerization.

    Science.gov (United States)

    Quirion, F; Gicquaud, C

    1993-11-01

    We have used densimetry and microcalorimetry to measure the changes in molar volume and heat capacity of the actin molecule during Mg(2+)-induced polymerization. Molar volume is decreased by 720 ml/mol. This result is in contradiction with previous measurements by Ikkai and Ooi [(1966) Science 152, 1756-1757], and by Swezey and Somero [(1985) Biochemistry 24, 852-860]: both of these groups reported increases in actin volume during polymerization, of 391 ml/mol and 63 ml/mol respectively. We also observed a decrease in heat capacity of about 69.5 kJ.K-1.mol-1 during polymerization. This is in agreement with the concept of conformational fluctuation of proteins proposed by Lumry and Gregory [(1989) J.Mol. Liq. 42, 113-144]whereby either ligand binding by a protein or monomer-monomer interaction decreases the protein's conformational flexibility.

  14. Isobaric heat capacity, isothermal compressibility and fluctuational properties of 1-bromoalkanes

    CERN Document Server

    Korotkovskii, V I; Neruchev, Yu A; Goncharov, A L; Postnikov, E B

    2016-01-01

    We present results of the experimental measurements of the isobaric heat capacity for 1-bromohexane, 1-bromoheptane, 1-bromooctane, 1-bromononane, 1-bromodecane, 1-bromoundecane, 1-bromododecane and 1-bromo-tetradecane at normal pressure and the speed of sound and the density for 1-bromotetradecane within the temperature range 298.15--423.15~K. These data on the isobaric heat capacity and the literature-based reference data for the density and the speed of sound were used to calculate the isothermal compressibility and the inverse reduced fluctuations. Based on the comparison of the results for pure n-alkanes and $\\alpha,\\omega$-dibromoalkanes, we discuss the influence of bromine atom on the volume fluctuations.

  15. Magnetic susceptibility and heat capacity of graphene in two-band Harrison model

    Science.gov (United States)

    Mousavi, Hamze; Bagheri, Mehran; Khodadadi, Jabbar

    2015-11-01

    Using a two-band tight-binding Harrison model and Green's function technique, the influences of both localized σ and delocalized π electrons on the density of states, the Pauli paramagnetic susceptibility, and the heat capacity of a graphene sheet are investigated. We witness an extension in the bandwidth and an increase in the number of Van-Hove singularities as well. As a notable point, besides the magnetic nature which includes diamagnetism in graphene-based nanosystems, a paramagnetic behavior associated with the itinerant π electrons could be occurred. Further, we report a Schottky anomaly in the heat capacity. This study asserts that the contribution of both σ and π electrons play dominant roles in the mentioned physical quantities.

  16. Dynamic heat capacity of the east model and of a bead-spring polymer model.

    Energy Technology Data Exchange (ETDEWEB)

    McCoy, John Dwane (New Mexico Institute of Mining and Technology, Socorro, NM); Brown, Jonathan R. (New Mexico Institute of Mining and Technology, Socorro, NM); Adolf, Douglas Brian

    2011-10-01

    In this report we have presented a brief review of the glass transition and one means of characterizing glassy materials: linear and nonlinear thermodynamic oscillatory experiments to extract the dynamic heat capacity. We have applied these methods to the east model (a variation of the Ising model for glass forming systems) and a simple polymeric system via molecular dynamics simulation, and our results match what is seen in experiment. For the east model, since the dynamics are so simple, a mathematical model is developed that matches the simulated dynamics. For the polymeric system, since the system is a simulation, we can instantaneously 'quench' the system - removing all vibrational energy - to separate the vibrational dynamics from dynamics associated with particle rearrangements. This shows that the long-time glassy dynamics are due entirely to the particle rearrangements, i.e. basin jumping on the potential energy landscape. Finally, we present an extension of linear dynamic heat capacity to the nonlinear regime.

  17. Structure and heat capacity of the NaCeF4 compound

    Institute of Scientific and Technical Information of China (English)

    Virgil Constantin; Ana-Maria Popescu

    2013-01-01

    This work continued our general research program on obtaining metallic cerium by electrodeposition from NaCeF4 dis-solved in different molten fluorides. The structure of NaCeF4 (cubic or hexagonal depending on the way of preparation) was estab-lished by DTA analysis, IR spectra and X-ray diffraction. The heat capacity (Cp) of NaCeF4 was measured by differential scanning calorimetry in the temperature range of 300-1093 K using the“step-method”. The Cp was fitted by an equation with a satisfactory re-sult. Heat capacity was compared with that calculated from the Neumann-Kopp rule (NKR) and the deviations observed were consis-tent with the stability of the NaCeF4 compound.

  18. Thermal behavior, specific heat capacity and adiabatic time-to-explosion of G(FOX-7).

    Science.gov (United States)

    Xu, Kangzhen; Song, Jirong; Zhao, Fengqi; Ma, Haixia; Gao, Hongxu; Chang, Chunran; Ren, Yinghui; Hu, Rongzu

    2008-10-30

    [H(2)N=C(NH(2))(2)](+)(FOX-7)(-)-G(FOX-7) was prepared by mixing FOX-7 and guanidinium chloride solution in potassium hydroxide solution. Its thermal decomposition was studied under the non-isothermal conditions with DSC and TG/DTG methods. The apparent activation energy (E) and pre-exponential constant (A) of the two exothermic decomposition stages were obtained by Kissinger's method and Ozawa's method, respectively. The critical temperature of thermal explosion (T(b)) was obtained as 201.72 degrees C. The specific heat capacity of G(FOX-7) was determined with Micro-DSC method and theoretical calculation method and the standard molar specific heat capacity is 282.025 J mol(-1) K(-1) at 298.15 K. Adiabatic time-to-explosion of G(FOX-7) was also calculated to be a certain value between 13.95 and 15.66 s.

  19. Low-Temperature Heat Capacity of 4 He Films on Graphite

    Science.gov (United States)

    Morishita, Masashi

    2017-02-01

    Heat capacities of 4 He films have been measured at rather low temperatures between 2 and 80 mK and at areal densities between 2 and 24 nm^{-2} . These areal densities correspond to a monolayer fluid and third-layer fluid. For monolayer films, the results do not contradict previous measurements carried out at high temperatures. On the other hand, at some areal densities, small and broad but definite bumps, whose origin has not yet been understood, have been observed around 15 mK. Between 13 and 24 nm^{-2} , the measured heat capacities above 40 mK are proportional to T2 and hardly change with areal density. These behaviors suggest that the second atomic layer does not solidify before the third-layer promotion, at least not into a commensurate solid, such as the so-called 4/7 phase.

  20. Dependence on molecular parameters of the heat capacity critical behaviour for nitroalkane + alcohol binary systems

    Science.gov (United States)

    Souto-Caride, M.; Troncoso, J.; Losada-Pérez, P.; Peleteiro, J.; Carballo, E.; Romani, L.

    2009-04-01

    Heat capacities per unit volume for a set of nitroalkane + alcohol critical mixtures near their upper consolute point are presented. The selected nitroalkanes were nitromethane and nitroethane whereas the 1-alcohol series from 1-propanol to 1-decanol was studied. The critical anomaly of nitroalkane + non-primary alcohols was also investigated; 2-propanol, 2-pentanol, 3-pentanol and 5-nonanol were chosen to this end. The heat capacity data are obtained at atmospheric pressure as a function of temperature in the homogeneous and heterogeneous regions by means of a differential scanning calorimeter. The exponent and amplitudes that characterises the observed critical anomaly are determined from experimental data, being their values coherent with previous results. In addition, the critical amplitude of the correlation length was calculated using the universality of the two-scale factor. Finally, the changes in the critical parameters as a function of the molecular structure of both nitroalkane and alcohol are analysed.

  1. Cooling and Heating Season Impacts of Right-Sizing of Fixed- and Variable-Capacity Heat Pumps With Attic and Indoor Ductwork

    Energy Technology Data Exchange (ETDEWEB)

    Cummings, James [Building America Partnership for Improved Residential Construction, Cocoa, FL (United States); Withers, Charles [Building America Partnership for Improved Residential Construction, Cocoa, FL (United States); Kono, Jamie [Building America Partnership for Improved Residential Construction, Cocoa, FL (United States)

    2015-06-24

    A new generation of full variable-capacity air-conditioning (A/C) and heat pump units has come on the market that promises to deliver very high cooling and heating efficiency. The units are controlled differently than standard single-capacity (fixed-capacity) systems. Instead of cycling on at full capacity and cycling off when the thermostat is satisfied, the new units can vary their capacity over a wide range (approximately 40%–118% of nominal full capacity) and stay on for 60%–100% more hours per day than the fixed-capacity systems depending on load-to-capacity ratios. Two-stage systems were not evaluated in this research effort.

  2. Magic number behavior for heat capacities of medium sized classical Lennard-Jones clusters

    CERN Document Server

    Frantz, D D

    2001-01-01

    Monte Carlo methods were used to calculate heat capacities as functions of temperature for classical atomic clusters of aggregate sizes $25 \\leq N \\leq 60$ that were bound by pairwise Lennard-Jones potentials. The parallel tempering method was used to overcome convergence difficulties due to quasiergodicity in the solid-liquid phase-change regions. All of the clusters studied had pronounced peaks in their heat capacity curves, most of which corresponded to their solid-liquid phase-change regions. The heat capacity peak height and location exhibited two general trends as functions of cluster size: for $N = 25$ to 36, the peak temperature slowly increased, while the peak height slowly decreased, disappearing by $N = 37$; for $N = 30$, a very small secondary peak at very low temperature emerged and quickly increased in size and temperature as $N$ increased, becoming the dominant peak by $N = 36$. Superimposed on these general trends were smaller fluctuations in the peak heights that corresponded to ``magic numbe...

  3. The heat capacity of lipid membranes in finite reservoirs and the relation to the frequency dependence

    CERN Document Server

    Mosgaard, Lars D; Heimburg, Thomas

    2013-01-01

    Membranes are two-dimensional structures embedded in a three-dimensional heat reservoir. At constant temperature, the heat capacity is proportional to the enthalpy fluctuations. However, when the membrane is embedded in a finite aqueous reservoir, the enthalpy and temperature fluctuations of the reservoir are intimately coupled to the enthalpy fluctuations of the membrane. Employing Monte Carlo simulations, we show that membranes embedded in water reservoirs of various sizes display different enthalpy fluctuations and fluctuation time scales. In particular, larger water reservoirs result in a larger enthalpy fluctuations of the membrane and in slower fluctuation time scales (relaxation times). In periodic processes such as sound propagation in membranes, the membrane has only a finite time available to exchange heat with the medium. A larger frequency therefore reduces the accessible volume of the reservoir. We discuss the relevance of these considerations for the frequency dependence of the compressibility a...

  4. Negative specific heat of black-holes from Fluid-Gravity Correspondence

    OpenAIRE

    Bhattacharya, Swastik; Shankaranarayanan, S.

    2017-01-01

    Black-holes in asymptotically flat space-times have negative specific heat --- they get hotter as they loose energy. A clear statistical mechanical understanding of this has remained a challenge. In this work, we address this issue using fluid-gravity correspondence which aims to associate fluid degrees of freedom to the horizon. Using linear response theory and the teleological nature of event horizon, we show explicitly that the fluctuations of the horizon-fluid lead to negative specific he...

  5. Heat evolution of micelle formation, dependence of enthalpy, and heat capacity on the surfactant chain length and head group.

    Science.gov (United States)

    Opatowski, Ella; Kozlov, Michael M; Pinchuk, Ilya; Lichtenberg, Dov

    2002-02-15

    Micelle formation by many surfactants is endothermic at low temperatures but exothermic at high temperatures. In this respect, dissociation of micelles (demicellization) is similar to dissolving hydrocarbons in water. However, a remarkable difference between the two processes is that dissolving hydrocarbons is isocaloric at about 25 degrees C, almost independently of the hydrocarbon chain length, whereas the temperature (T*) at which demicellization of different surfactants is athermal varies over a relatively large range. We have investigated the temperature dependence of the heat of demicellization of three alkylglucosides with hydrocarbon chains of 7, 8, and 9 carbon atoms. At about 25 degrees C, the heat of demicellization of the three studied alkylglucosides varied within a relatively small range (DeltaH=-7.8+/-0.4 kJ/mol). The temperature dependence of DeltaH(demic) indicates that within the studied temperature range the heat capacity of demicellization (DeltaC(P,demic)) is about constant. The value of DeltaC(P,demic) exhibited an apparently linear dependence on the surfactant's chain length (DeltaC(P,demic)/n(CH(2))=47+/-7 kJ/mol K). Our interpretation of these results is that (i) the transfer of the head groups from micelles to water is exothermic and (ii) the temperature dependence of the heat associated with water-hydrocarbon interactions is only slightly affected by the head group. This implies that the deviation of the value of T* from 25 degrees C results from the contribution of the polar head to the overall heat of demicellization. Calorimetric studies of other series of amphiphiles will have to be conducted to test whether the latter conclusion is general.

  6. Yeast probiotic supplementation mitigates some of the negative effects of heat stress in feedlot heifers

    Science.gov (United States)

    Heat stress (HS) in feedlot cattle can be detrimental to performance, health and profitability; however, utilization of feed additives has the potential to mitigate some of these negative effects. Therefore, this study was designed to determine if supplementation of a combination live yeast and ye...

  7. Design and Fabricate a Metallic Hydride Heat Pump with a Cooling Capacity of 9000 BTU/H

    Science.gov (United States)

    1989-02-07

    I ERGENICS, INC. N 681 Lawl Ins Road Wyckoff. NJ 07481 DESIGN AND FABRICATE A METALLIC HYDRIDE HEAT PUMP WITH A COOLING CAPACITY OF 9000 BTU/H...air conditioning unit employing a metal hydride heat pump and a silicone heat transfer fluid. The contract was subsequently modified on 29 September 3...for thermally driven ECE systems. Metal hydride heat pumps were proposed as for this application.. However, only laboratory bench experiments have

  8. A new experimental method to determine specific heat capacity of inhomogeneous concrete material with incorporated microencapsulated-PCM

    DEFF Research Database (Denmark)

    Pomianowski, Michal Zbigniew; Heiselberg, Per; Jensen, Rasmus Lund

    2014-01-01

    PCM. This paper describes the development of the new material and the experimental set-up to determine the specific heat capacity of the PCM concrete material. Moreover, various methods are proposed and compared to calculate the specific heat capacity of the PCM concrete. Finally, it is hoped......The study presented in this paper focuses on an experimental investigation of the specific heat capacity as a function of the temperature Cp (T) of concrete mixed with various amounts of phase change material (PCM). The tested specimens are prepared by directly mixing concrete and microencapsulated...

  9. Heat capacities of polycrystalline {sup n}LiH and {sup n}LiD by differential scanning calorimetric method

    Energy Technology Data Exchange (ETDEWEB)

    Jat, Ram Avtar [Product Development Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India); Parida, S.C., E-mail: sureshp@barc.gov.i [Product Development Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India); Krishnan, K. [Fuel Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India); Anand, N.S.; Sawant, S.G.; Agarwal, Renu; Singh, Ziley [Product Development Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India); Aggarwal, S.K. [Fuel Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India); Venugopal, V. [RC and I Group, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India)

    2010-08-27

    The heat capacities of polycrystalline {sup n}LiH and {sup n}LiD were measured by differential scanning calorimeter in the temperature range from 125 to 800 K. The smoothed values of heat capacities were used to calculate various thermodynamic functions for {sup n}LiH and {sup n}LiD from 0 to 800 K. Isotopic effect on heat capacity of {sup n}LiH and {sup n}LiD is predominant at higher temperatures (>80 K) whereas below 80 K the isotopic effect is negligible.

  10. Effect of Heat Treatment and Digestive Enzymes on Cereal Water-Retention Capacity

    Directory of Open Access Journals (Sweden)

    Rodica Caprita

    2015-10-01

    Full Text Available Thermal treatment of cereal grains affects carbohydrate and micronutrient content and bioavailability. Water-retention capacity (WRC is an important index for the effects of fiber in the diet and the metabolic activity of fiber along the gut. This study evaluated the effect of thermal treatment and digestive enzymes on wheat and barley WRC. Ground wheat and barley samples were heated for different time periods at 150ºC before in vitro gastric and intestinal digestion. WRC values in heat treated wheat and barley are at higher levels as compared to the values of untreated cereals. WRC in barley ranged from 1.026 g water/g DM (untreated to 1.36 g water/g DM (heated at 150ºC for 15 minute. The increase was much lower in heat treated wheat, from 0.973 g water/g DM up to 1.03 g water/g DM at 5 minutes heating time.

  11. Phase transitions in mixed-valence potassium manganese hexacyanoferrate Prussian blue analogue: Heat capacity calorimetric study

    Energy Technology Data Exchange (ETDEWEB)

    Bhattacharjee, A. [Department of Physics, Visva-Bharati, Santiniketan 731235 (India)]. E-mail: ashis@vbphysics.net.in; Saha, S. [Department of Chemistry, Jadavpur University, Kolkata 700032 (India); Koner, S. [Department of Chemistry, Jadavpur University, Kolkata 700032 (India); Miyazaki, Y. [Research Center for Molecular Thermodynamics, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan)]. E-mail: miyazaki@chem.sci.osaka-u.ac.jp

    2007-05-15

    Phase transitions in K{sub 0.2}Mn{sub 0.66}{sup II}Mn{sub 1.44}{sup III}[Fe{sub 0.2}{sup II}Fe{sub 0.8}{sup III}(CN){sub 6}]O{sub 0.6}= {sub 6}(CH{sub 3}COO){sub 1.32}].7.6H{sub 2}O-a mixed valence PB analogue have been investigated with the help of heat capacity calorimetry under 0-90kOe magnetic fields in the 1.8-300K temperature range. Two heat capacity anomalies at 2.1 and 7.5K have been detected, which correspond to ferromagnetic and ferrimagnetic transitions, respectively. The magnitudes as well as the position of these thermal anomalies have varied with changing magnetic field. The estimated zero-field magnetic entropy amounted to 29.2JK{sup -1}mol{sup -1}, which is close to the expected value (33.7JK{sup -1}mol{sup -1}). The uniaxial zero-field splitting parameter is estimated to be D/k{sub B}=14.7K. A comparatively stronger antiferromagnetic interaction seems to lead to the magnetic transition around 7.3K, whereas a weaker ferromagnetic interaction gives rise to the thermal anomaly at 2.1K. The present results on magnetic phase transitions are in complete agreement with the earlier observations made through magnetic studies. Additionally, a glass transition at 194K has been observed in the heat capacity study presumably due to freezing of the orientational motion of the H{sub 2}O molecules present in the material. This phenomenon is reflected into the temperature dependence of the estimated Fe{sup III} and Fe{sup II} concentrations in the present material obtained earlier through Mossbauer spectroscopy.

  12. Heat capacity and density of potassium iodide solutions in mixed N-methylpyrrolidone-water solvent at 298.15 K

    Science.gov (United States)

    Novikov, A. N.

    2014-10-01

    The heat capacity and density of potassium iodide solutions in a mixed N-methylpyrrolidone (MP)-water solvent with a low content of the organic component are measured via calorimetry and densimetry at 298.15 K. Standard partial molal heat capacities and volumes of potassium iodide in MP-water mixtures are calculated. Standard heat capacities and volumes of potassium and iodide ions are determined. The character of the changes in heat capacity and volume are discussed on the basis of calculating additivity coefficients δ c and δ v upon the mixing of isomolal binary solutions KI-MP and KI-water, depending on the composition of the MP-H2O mixture and the concentration of the electrolyte.

  13. Chemical thermodynamics of nuclear materials. IX. High temperature heat capacity of plutonium-3. 2 at. % gallium alloy

    Energy Technology Data Exchange (ETDEWEB)

    Adams, R.O.; Oetting, F.L.

    1982-01-01

    The heat capacity of delta-stabilized plutonium (Pu - 3.2 at. % Ga) has been determined from 330 to 700/sup 0/K by an adiabatic calorimeter. The heat capacity for this alloy may be expressed by: Cp (Pu-3.2 at. % Ga)/(J K/sup -1/ mol/sup -1/) = 39.249 - 0.0264 (T/K) + 3.595 x 10/sup 5/ (T/K)/sup 2/ - 2.506 x 10/sup 5/ (K/T)/sup 2/. It was found that a large contribution to the heat capacity is due to the electronic heat capacity. The thermal functions for this plutonium-gallium alloy are calculated to 700/sup 0/K.

  14. Heat capacities of xenotime-type ceramics: An accurate ab initio prediction

    Science.gov (United States)

    Ji, Yaqi; Beridze, George; Bosbach, Dirk; Kowalski, Piotr M.

    2017-10-01

    Because of ability to incorporate actinides into their structure, the lanthanide phosphate ceramics (LnPO4) are considered as potential matrices for the disposal of nuclear waste. Here we present highly reliable ab initio prediction of the variation of heat capacities and the standard entropies of these compounds in zircon structure along lanthanide series (Ln = Dy, …,Lu) and validate them against the existing experimental data. These data are helpful for assessment of thermodynamic parameters of these materials in the context of using them as matrices for immobilization of radionuclides for the purpose of nuclear waste management.

  15. AC measurement of heat capacity and magnetocaloric effect for pulsed magnetic fields

    OpenAIRE

    2010-01-01

    International audience; A new calorimeter for measurements of the heat capacity and magnetocaloric effect of small samples in pulsed magnetic fields is discussed for the exploration of thermal and thermodynamic properties at temperatures down to 2 K. We tested the method up to 0H=50 T, but it could be extended to higher fields. For these measurements we used carefully calibrated bare-chip Cernox® and RuO2 thermometers, and we present a comparison of their performances. The monotonic temperatu...

  16. Low-tmperature Heat Capacities and Standard Molar Enthalpy of Formation of 4-Nitrobenzyl Alcohol

    Institute of Scientific and Technical Information of China (English)

    MENG, Qingfen; TAN, Zhicheng; WANG, Xiaohuan; DONG, Yaping; LI, Wu; SHI, Quan

    2009-01-01

    Low-temperature heat capacities of 4-nitrobenzyl alcohol (4-NBA) have been measured by a high precision automated adiabatic calorimeter over the temperature range from 78 to 396 K. The melting temperature, the molar calculated in the range from 80 to 400 K at the interval of 5 K. The constant-volume energy and standard molar en- at T=298.15 K. The standard molar enthalpy of formation has been derived, ΔfHom(C7H7NO3, s)=-(206.49± namic quantities through a Hess thermochemical cycle.

  17. High-temperature heat capacity of orthovanadates Ce1- x Bi x VO4

    Science.gov (United States)

    Denisova, L. T.; Chumilina, L. G.; Belousova, N. V.; Denisov, V. M.

    2016-09-01

    Orthovanadates Ce1- x Bi x VO4 (1 ≥ x ≥ 0) have been produced by solid-phase synthesis from initial oxides CeO2, Bi2O3, and V2O5 upon step-by-step burning. The high-temperature heat capacity of Ce1- x Bi x VO4 has been measured by differential scanning calorimetry. The experimental data on C p = f(T) were used to calculate the thermodynamic properties (the enthalpy changes, the entropy changes, and the Gibbs energy).

  18. On the Interpretation of Near-Critical Gas-Liquid Heat Capacities

    Science.gov (United States)

    Woodcock, Leslie V.

    2017-09-01

    This comment is in response to a comment by Sengers and Anisimov on the article "Gibbs density surface of fluid argon" that contradicts prevailing theory. It has not "been established experimentally that the thermodynamic properties of fluids satisfy scaling laws with universal critical exponents asymptotically close to a single critical point of the vapor-liquid phase transition." Here we explain why an apparent divergence of Cv, in historical experimental "evidence," is based upon a misinterpretation of near-critical gas-liquid heat capacity measurements in the two-phase coexistence region. The conclusion that there is no "singular critical point" on Gibbs density surface still stands.

  19. The heat capacity and enthalpy of condensed UO 2: Critical review and assessment

    Science.gov (United States)

    Hyland, G. J.; Ohse, R. W.

    1986-09-01

    Having established the role of the heat capacity, Cp( T), of condensed UO 2 in various FBR accident scenarios, e.g. HCDA and PAHR, and having noted the unsatisfactory state of present knowledge concerning this basic thermophysical property of the fuel, all existing enthalpy and heat capacity data are collated and assessed, and certain recommendations made. The conventional method of obtaining Cp( T) by analytical differentiation of some adopted fit to this enthalpy data is then critically examined. The attendant problems are illustrated both for solid UO 2, where the contribution to Cp( T) from the weak, sigmoidal, enthalpy structure (which is just discernible in the data of Hein and Flagella) is missed and for molten UO 2, where not even the direction of the trend of Cp( T) with T can be definitively established, resulting, upon extrapolation to 5000 K, in Cp values which can differ by as much as 60 J mol -1K -1. Some recent progress towards a more acceptable, "model-independent" approach, known as quasi-local linear regression (QLLR), is then reviewed and applied to enthalpy data of UO 2 on both sides of its melting point, Tm. In the case of solid UO 2, a pronounced heat capacity peak, extending over about 100 K and centred on 2610 K., is revealed, whose magnitude and location is very similar to that found in other fluorite structured materials near 0.8 Tm wherein it indicates a (Bredig) transition to a state characterised by giant ionic conductivities. Whilst it is impossible to establish any definite T-dependence for the Cp(QLLR) values in molten UO 2, the tendency to slightly decrease appears to marginally outweigh the converse, in qualitative accord with the dependence advocated by Hoch and Vernardakis. In the post-transitional region Tt< T< Tm the opposite holds, as is necessary for consistency between the independently established T-dependences of the thermal conductivity and diffusivity, which requires that Cp( T) increases with T faster than the density

  20. Anomalies in thermal expansion and heat capacity of TmB50 at low temperatures: magnetic phase transition and crystal electric field effect.

    Science.gov (United States)

    Novikov, V V; Zhemoedov, N A; Mitroshenkov, N V; Matovnikov, A V

    2016-11-01

    We experimentally study the heat capacity and thermal expansion of thulium boride (TmB50) at temperatures of 2-300 K. The wide temperature range (2-180 K) of boride negative expansion was revealed. We found the anomalies in C(T) heat capacity temperature dependence, attributed to the Schottky contribution (i.e. the influence of the crystal electric field: CEF), as well as the magnetic phase transition. CEF-splitting of the f-levels of the Tm(3+) ion was described by the Schottky function of heat capacity with a quasi-quartet in the ground state. Excited multiplets are separated from the ground state by energy gaps δ1 = 100 K, and δ2 ≈ 350 K. The heat capacity maximum at Tmax ≈ 2.4 K may be attributed to the possible magnetic transition in TmB50. Other possible causes of the low-temperature maximum of C(T) dependence are the nonspherical surroundings of rare earth atoms due to the boron atoms in the crystal lattice of the boride and the emergence of two-level systems, as well as the splitting of the ground multiplet due to local magnetic fields of the neighboring ions of thulium. Anomalies in heat capacity are mapped with the thermal expansion features of boride. It is found that the TmB50 thermal expansion characteristic features are due to the influence of the CEF, as well as the asymmetry of the spatial arrangement of boron atoms around the rare earth atoms in the crystal lattice of RB50. The Grüneisen parameters, corresponding to the excitation of different multiplets of CEF-splitting, were determined. A satisfactory accordance between the experimental and estimated temperature dependencies of the boride thermal expansion coefficient was achieved.

  1. Elementary School-Age Children's Capacity To Choose Positive Diagnostic and Negative Diagnostic Tests.

    Science.gov (United States)

    Samuels, Mark C.; McDonald, John

    2002-01-01

    Two experiments compared 10-year-olds' and adults' ability to choose positive and negative diagnostic tests over positive and negative nondiagnostic tests. Findings indicated that both age groups were more likely to prefer positive diagnostic tests over positive nondiagnostic tests, although only adults showed a significant preference for negative…

  2. Non-negative Matrix Factorization as a Method for Studying Coronal Heating

    Science.gov (United States)

    Barnes, Will; Bradshaw, Stephen

    2015-04-01

    Many theoretical efforts have been made to model the response of coronal loops to nanoflare heating, but the theory has long suffered from a lack of direct observations. Nanoflares, originally proposed by Parker (1988), heat the corona through short, impulsive bursts of energy. Because of their short duration and comparatively low amplitude, emission signatures from nanoflare heating events are often difficult to detect. Past algorithms (e.g. Ugarte-Urra and Warren, 2014) for measuring the frequency of transient brightenings in active region cores have provided only a lower bound for such measurements. We present the use of non-negative matrix factorization (NMF) to analyze spectral data in active region cores in order to provide more accurate determinations of nanoflare heating properties. NMF, a matrix deconvolution technique, has a variety of applications , ranging from Raman spectroscopy to face recognition, but, to our knowledge, has not been applied in the field of solar physics. The strength of NMF lies in its ability to estimate sources (heating events) from measurements (observed spectral emission) without any knowledge of the mixing process (Cichocki et al., 2009). We apply our NMF algorithm to forward-modeled emission representative of that produced by nanoflare heating events in an active region core. The heating events are modeled using a state-of-the-art hydrodynamics code (Bradshaw and Cargill, 2013) and the emission and active regions are synthesized using advanced forward modeling and visualization software (Bradshaw and Klimchuk, 2011; Reep et al., 2013). From these active region visualizations, our NMF algorithm is then able to predict the heating event frequency and amplitudes. Improved methods of nanoflare detection will help to answer fundamental questions regarding the frequency of energy release in the solar corona and how the corona responds to such impulsive heating. Additionally, development of reliable, automated nanoflare detection

  3. Investigation on molar heat capacity, standard molar enthalpy of combustion for guaiacol and acetyl guaiacol ester

    Institute of Scientific and Technical Information of China (English)

    Changshuai Shen; Wenli Li; Cairong Zhou

    2016-01-01

    The molar heat capacities (Cp) of guaiacol (CAS 90-50-1) and acetyl guaiacol ester (AGE, CAS 613-70-7) were determinated from 290 K to 350 K by differential scanning calorimetry (DSC), and expressed as a function of tem-perature. Two kinds of group contribution models were used to estimate the molar heat capacities of both guaiacol and AGE, the average relative deviation is less than 10%. The standard molar enthalpies of combustion of guaiacol and AGE were−3590.0 kJ·mol−1 and−4522.1 kJ·mol−1 by a precise thermal isolation Oxygen Bomb Calorimeter. The standard molar enthalpies of formation of guaiacol and AGE in a liquid state at 298.15 K were calculated to be−307.95 kJ·mol−1 and−448.72 kJ·mol−1, respectively, based on the standard molar enthalpies of combustion. The thermodynamic properties are useful for exploiting the new synthesis method, engineering design and industry production of AGE using guaiacol as a raw material.

  4. Phonon Density of States and Heat Capacity of La$_{3-x}$Te$_4$

    Energy Technology Data Exchange (ETDEWEB)

    Delaire, Olivier A [ORNL; May, Andrew F. [California Institute of Technology, Pasadena; McGuire, Michael A [ORNL; Porter, Wallace D [ORNL; Lucas, [ORNL; Stone, Matthew B [ORNL; Abernathy, Douglas L [ORNL; Snyder, G. J. [California Institute of Technology, Pasadena

    2009-01-01

    The phonon density of states (DOS) of La$_{3-x}$Te$_4$ compounds ($x=0.0, 0.18, 0.32$) was measured at 300, 520, and 780$\\,$K, using inelastic neutron scattering. A significant stiffening of the phonon DOS, and a large broadening of features were observed upon introduction of vacancies on La sites (increasing $x$). Heat capacity measurements were performed at temperatures $~1.85 \\leqslant T \\leqslant 1200 \\,$K, and were analyzed to quantify the contributions of phonons and electrons. The Debye temperature and the electronic coefficient of heat capacity determined from these measurements are consistent with the neutron scattering results, and with previously reported first-principles calculations. Our results indicate that La vacancies in La$_{3-x}$Te$_4$ strongly scatter phonons, and this source of scattering appears to be independent of temperature. The stiffening of the phonon DOS induced by the introduction of vacancies is explained in terms of the electronic structure and the change in bonding. The temperature dependence of the phonon DOS is captured satisfactorily by the quasiharmonic approximation.

  5. Thermal Behavior, Specific Heat Capacity and Adiabatic Time-to-explosion of GDN

    Institute of Scientific and Technical Information of China (English)

    YANG Xing-kun; XU Kang-zhen; ZHAO Feng-qi; YANG Xin; WANG Han; SONG Ji-rong; WANG Yao-yu

    2009-01-01

    A new compound, [(NH2)2C=NH2]+N(NO2)2-(GDN), was prepared by mixing ammonium dinitramide (ADN) and guanidine hydrochloride in water. The thermal behavior of GDN was studied under the non-isothermal conditions with DSC and TG/DTG methods. The apparent activation energy(E) and pre-exponential constant(A) of the exothermic decomposition stage of GDN were 118.75 kJ/mol and 1010.86 s-1, respectively. The critical temperature of the thermal explosion(Tb) of GDN was 164.09 ℃. The specific heat capacity of GDN was determined with the Micro-DSC method and the theoretical calculation method, and the standard molar specific heat capacity was 234.76J·mol-1·K-1 at 298.15K.The adiabatic time-to-explosion of GDN was also calculated to be a certain value between 404.80 and 454.95 s.

  6. Phonon spectrum, thermal expansion and heat capacity of UO{sub 2} from first-principles

    Energy Technology Data Exchange (ETDEWEB)

    Yun, Younsuk, E-mail: younsuk.yun@psi.ch [Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden); Laboratory of Reactor Physics and Systems Behaviour, Paul Scherrer Institut, CH-5232 Villigen PSI (Switzerland); Legut, Dominik [Nanotechnology Centre, VSB-Technical University of Ostrava, 17. listopadu 15, CZ-708 33 Ostrava (Czech Republic); Atomistic Modeling and Design of Materials, University of Leoben, Leoben (Austria); Oppeneer, Peter M. [Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden)

    2012-07-15

    We report first-principles calculations of the phonon dispersion spectrum, thermal expansion, and heat capacity of uranium dioxide. The so-called direct method, based on the quasiharmonic approximation, is used to calculate the phonon frequencies within a density functional framework for the electronic structure. The phonon dispersions calculated at the theoretical equilibrium volume agree well with experimental dispersions. The computed phonon density of states (DOSs) compare reasonably well with measured data, as do also the calculated frequencies of the Raman and infrared active modes including the LO/TO splitting. To study the pressure dependence of the phonon frequencies we calculate phonon dispersions for several lattice constants. Our computed phonon spectra demonstrate the opening of a gap between the optical and acoustic modes induced by pressure. Taking into account the phonon contribution to the total free energy of UO{sub 2} its thermal expansion coefficient and heat capacity have been computed from first-principles. Both quantities are in good agreement with available experimental data for temperatures up to about 500 K.

  7. Heat capacity measurements of atoms and molecules adsorbed on evaporated metal films

    Energy Technology Data Exchange (ETDEWEB)

    Kenny, T.W.

    1989-05-01

    Investigations of the properties of absorbed monolayers have received great experimental and theoretical attention recently, both because of the importance of surface processes in practical applications such as catalysis, and the importance of such systems to the understanding of the fundamentals of thermodynamics in two dimensions. We have adapted the composite bolometer technology to the construction of microcalorimeters. For these calorimeters, the adsorption substrate is an evaporated film deposited on one surface of an optically polished sapphire wafer. This approach has allowed us to make the first measurements of the heat capacity of submonolayer films of /sup 4/He adsorbed on metallic films. In contrast to measurements of /sup 4/He adsorbed on all other insulating substrates, we have shown that /sup 4/He on silver films occupies a two-dimensional gas phase over a broad range of coverages and temperatures. Our apparatus has been used to study the heat capacity of Indium flakes. CO multilayers, /sup 4/He adsorbed on sapphire and on Ag films and H/sub 2/ adsorbed on Ag films. The results are compared with appropriate theories. 68 refs., 19 figs.

  8. Above room temperature heat capacity and phase transition of lithium tetrahydroborate

    Energy Technology Data Exchange (ETDEWEB)

    El Kharbachi, A., E-mail: a.elkharbachi@simap.grenoble-inp.fr [Laboratoire de Science et Ingenierie des Materiaux et Procedes (SIMaP), CNRS-UMR 5266, Universite de Grenoble, 1130 rue de la Piscine, Domaine Universitaire, BP 75, 38402 Saint Martin d' Heres (France); Nuta, I.; Hodaj, F. [Laboratoire de Science et Ingenierie des Materiaux et Procedes (SIMaP), CNRS-UMR 5266, Universite de Grenoble, 1130 rue de la Piscine, Domaine Universitaire, BP 75, 38402 Saint Martin d' Heres (France); Baricco, M. [Dipartimento di Chimica I.F.M and NIS, Universita di Torino, via P. Giuria 9, 10125 Torino (Italy)

    2011-06-10

    Highlights: {yields} LiBH{sub 4} as hydrogen storage material. {yields} Thermodynamic properties of this compound are lacking in literature. Molar heat capacity, C{sub p,m}, of the different phases (ortho-phase, hexa-phase and liquid phase) needs to be determined. {yields} C{sub p,m} 'anomaly' is observed to be independent of the main phase transition. - Abstract: New calorimetric determinations of molar heat capacity C{sub p,m} of lithium tetrahydroborate (LiBH{sub 4}) were performed in order to analyze the origin of the previously observed 'anomaly' before the polymorphous transition at 386 K. The above room temperature dependence of LiBH{sub 4}C{sub p,m} was measured until approaching the melting point of the compound at 553 K and the abnormal behaviour was attributed to lattice defects independent of the main crystalline phase transition. As a result, lower entropy of the transition {Delta}{sub trs}S = 13.11 {+-} 0.23 J K{sup -1} mol{sup -1} than that proposed in literature was obtained, which is in agreement with the observed anisotropy and crystal density decrease before the transition from recent X-ray diffraction indexing. An estimate of the liquid C{sub p,m} of LiBH{sub 4} 'molten salt' is proposed.

  9. An Experimental Study of Waveguide Coupled Microwave Heating with Conventional Multicusp Negative Ion Source

    CERN Document Server

    Komppula, J; Koivisto, H; Laulainen, J; Tarvainen, O

    2015-01-01

    Negative ion production with conventional multicusp plasma chambers utilizing 2.45 GHz microwave heating is demonstrated. The experimental results were obtained with the multicusp plasma chambers and extraction systems of the RFdriven RADIS ion source and the filament driven arc discharge ion source LIISA. A waveguide microwave coupling system, which is almost similar to the one used with the SILHI ion source, was used. The results demonstrate that at least one third of negative ion beam obtained with inductive RF-coupling (RADIS) or arc discharge (LIISA) can be achieved with 1 kW of 2.45 GHz microwave power in CW mode without any modification of the plasma chamber. The co-extracted electron to H^- ratio and the optimum pressure range were observed to be similar for both heating methods. The behaviour of the plasma implies that the energy transfer from the microwaves to the plasma electrons is mainly an off-resonance process.

  10. An experimental study of waveguide coupled microwave heating with conventional multicusp negative ion sources

    Science.gov (United States)

    Komppula, J.; Kalvas, T.; Koivisto, H.; Laulainen, J.; Tarvainen, O.

    2015-04-01

    Negative ion production with conventional multicusp plasma chambers utilizing 2.45 GHz microwave heating is demonstrated. The experimental results were obtained with the multicusp plasma chambers and extraction systems of the RF-driven RADIS ion source and the filament driven arc discharge ion source LIISA. A waveguide microwave coupling system, which is almost similar to the one used with the SILHI ion source, was used. The results demonstrate that at least one third of negative ion beam obtained with inductive RF-coupling (RADIS) or arc discharge (LIISA) can be achieved with 1 kW of 2.45 GHz microwave power in CW mode without any modification of the plasma chamber. The co-extracted electron to H- ratio and the optimum pressure range were observed to be similar for both heating methods. The behaviour of the plasma implies that the energy transfer from the microwaves to the plasma electrons is mainly an off-resonance process.

  11. Negative specific heat of black-holes from fluid-gravity correspondence

    Science.gov (United States)

    Bhattacharya, Swastik; Shankaranarayanan, S.

    2017-04-01

    Black holes in asymptotically flat space-times have negative specific heat—they get hotter as they loose energy. A clear statistical mechanical understanding of this has remained a challenge. In this work, we address this issue using fluid-gravity correspondence which aims to associate fluid degrees of freedom to the horizon. Using linear response theory and the teleological nature of event horizon, we show explicitly that the fluctuations of the horizon-fluid lead to negative specific heat for a Schwarzschild black Hole. We also point out how the specific heat can be positive for Kerr–Newman or AdS black holes. Our approach constitutes an important advance as it allows us to apply the canonical ensemble approach to study thermodynamics of asymptotically flat black hole space-times.

  12. Zero-field and magnetic-field low-temperature heat capacity of solid-state electrotransport-purified erbium

    Energy Technology Data Exchange (ETDEWEB)

    Pecharsky, V.K.; Gschneidner, K.A. Jr. (Ames Laboratory and Department of Materials Science and Engineering, Iowa State University, Ames, Iowa 50011 (United States)); Fort, D. (School of Metallurgy and Materials, University of Birmingham, P.O. Box 363, Birmingham B15 2TT (United Kingdom))

    1993-03-01

    Zero-field (1.5--80 K) and high-magnetic-field (1.5--20 K) low-temperature heat-capacity measurements have been carried out on 99.97 at. % (99.996 wt %) pure polycrystalline erbium. The electronic specific-heat coefficient (in zero field) was found to be 8.7[plus minus]0.1 mJ/mol K[sup 2] and the Debye temperature to be 176.9[plus minus]0.4 K. The ferromagnetic'' transition of erbium around 19 K exhibits a tremendously large and sharp heat-capacity maximum of 169 J/mol K. Five other heat-capacity anomalies at 25.1, 27.5, 42, 48.9, and 51.4 K were observed. The 51.4-K peak is associated with antiferromagnetic ordering in the basal plane, and the other four anomalies are associated with spin-slip transitions between two different commensurate antiferromagnetic structures. An external magnetic field shifts the ferromagnetic heat-capacity peak toward higher temperatures with a remarkable suppression and broadening of the maximum, and reduces the total heat capacity below the magnetic ordering maximum for temperatures down to about 5 K. At lower temperatures, the high-magnetic field ([ital H][gt]5 T) increases the sample heat capacity due to an increase in both the [sup 167]Er hyperfine coupling and electronic contributions. The effective magnetic field at the nucleus increases from 7.2 MOe at [ital H]=0 to 10.3 MOe at [ital H]=9.85 T. The electronic specific constant (density of state at the Fermi level) exhibits a 15% increase at [ital H][similar to]2 T due to a spin reorientation of the basal plane moments. This change is also evident in the magnetic contribution to the heat capacity.

  13. New design of a microcalorimeter for measuring absolute heat capacity from 300 to 550 K

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Woong-Jhae; Kim, Hyung Joon; Kim, Jae Wook; Nam, Dong Hak; Choi, Ki-Young [Center for Novel States of Complex Materials Research, Department of Physics and Astronomy, Seoul National University, Seoul 151-747 (Korea, Republic of); Kim, Kee Hoon, E-mail: khkim@phya.snu.ac.kr [Center for Novel States of Complex Materials Research, Department of Physics and Astronomy, Seoul National University, Seoul 151-747 (Korea, Republic of); Institute of Applied Physics, Seoul National University, Seoul 151-747 (Korea, Republic of)

    2015-03-10

    Highlights: • A microcalorimeter (C{sub add} ∼ 6 μJ K{sup −1}) having a Si:N/SiO{sub 2} membrane was designed. • Concentric heater and sensor leads are useful for achieving better heat confinement. • Fabrication in one side of the membrane makes the process easy and cost-effective. • The lumped-τ{sub 2} model incorporating radiation effects was used to measure accurate C{sub p}. • Measurement errors were confirmed to be less than 3% from 300 to 550 K. - Abstract: We report development of a new type of a microcalorimeter based on an amorphous membrane composed of Si:N and SiO{sub 2} layers, which holds an isothermal Au film of a disc shape and concentric Pt leads as a heater and a thermal sensor. Two-dimensional thermal simulation was used to confirm that the layout of the isothermal platform and metallic leads result in nearly perfect isothermal conditions at temperatures from 20 to 600 K. Moreover, by placing the insulating SiO{sub 2} layer between the isothermal film and metallic leads, we could locate all electrical and thermal components in the top side of the membrane, allowing the micro-fabrication easy and cost-effective. The micro-fabrication method produces a total of 49 devices in a four inch Si wafer and can be also applied in a larger wafer size. Heat capacity value of the isothermal platform was found to be as small as ∼6 μJ K{sup −1} at room temperature. Upon applying the lumped-τ{sub 2} model in the measurement scheme, we found that specific heat of an Al{sub 2}O{sub 3} single crystal (NIST standard, ∼0.2 mg) was consistent with the literature value within ∼3% at temperatures between 300 and 550 K. Our results show that the circular layout of the isothermal platform with better heat confinement is useful for increasing the accuracy of measured heat capacity if the other parameters such as thickness and thermal conductivity of each layer in the membrane are fixed.

  14. Effect of Heat Treatment of Wild Cherry Wood on Abrasion Resistance and Withdrawal Capacity of Screws

    Directory of Open Access Journals (Sweden)

    Ayhan Aytin

    2016-01-01

    Full Text Available In its wise use, many properties of wood are important. Among these properties, wood abrasion resistance (AR and withdrawal capacity of screws (WCS are deemed to be relatively signifi cant. It is well know that heat treatment changes the resistance features of wooden materials by changing the structural characteristics of wood. Within the scope of this study, the effects were investigated of the temperature and duration of heat treatment of Wild Cherry (Cerasus avium (L. Monench on its AR and its WCS in the radial direction and tangential direction. The test results indicated that weight loss (WL and thickness reduction (TR remained almost the same in the radial direction specimen, but there was significant TR in the tangential direction specimen. As a result of these changes, the abrasion effect of the S-42 abrader diminished based on the increase in the number of cycles. However, in both the radial and tangential direction, the WCS decreased to a significantly greater extent in the heat-treated specimens than in the control specimens.

  15. Analysis of the fragility of the Zr77Ni23 metallic glass based on low-temperature heat capacity measurements

    Science.gov (United States)

    Salčinović Fetić, Amra; Remenyi, Georgy; Starešinić, Damir; Kuršumović, Ahmed; Babić, Emil; Sulejmanović, Suada; Biljaković, Katica

    2017-08-01

    We present an experimental investigation of the fragility and heat capacity of metallic glass Zr77Ni23 . The ribbon sample was produced by melt-spinning technique. Glass transition temperature Tg obtained by differential scanning calorimetry with various heating rates was used to estimate fragility parameter m . Heat capacity measurements were performed in a wide temperature interval, ranging from 1.8 K up to room temperature, for as-cast and relaxed samples in different magnetic field strengths. Our results do not show any excess of vibrational density of states over the Debye contribution corresponding to the boson peak. Relaxation of the sample causes a slight decrease of Debye contribution consistent with the measured increase of Young modulus. The fact that no boson peak is observed in heat capacity, together with the obtained intermediate fragility of m =53 , positions Zr77Ni23 well outside established correlations between fragility, boson peak strength, and glass forming ability.

  16. New equations for density, entropy, heat capacity, and potential temperature of a saline thermal fluid

    Science.gov (United States)

    Sun, Hongbing; Feistel, Rainer; Koch, Manfred; Markoe, Andrew

    2008-10-01

    A set of fitted polynomial equations for calculating the physical variables density, entropy, heat capacity and potential temperature of a thermal saline fluid for a temperature range of 0-374 °C, pressure range of 0.1-100 MPa and absolute salinity range of 0-40 g/kg is established. The freshwater components of the equations are extracted from the recently released tabulated data of freshwater properties of Wagner and Pruß [2002. The IAPWS formulation 1995 for the thermodynamic properties of ordinary water substance for general and scientific use. Journal of Physical and Chemical Reference Data 31, 387-535]. The salt water component of the equation is based on the near-linear relationship between density, salinity and specific heat capacity and is extracted from the data sets of Feistel [2003. A new extended Gibbs thermodynamic potential of seawater. Progress in Oceanography 58, 43-114], Bromley et al. [1970. Heat capacities and enthalpies of sea salt solutions to 200 °C. Journal of Chemical and Engineering Data 15, 246-253] and Grunberg [1970. Properties of sea water concentrates. In: Third International Symposium on Fresh Water from the Sea, vol. 1, pp. 31-39] in a temperature range 0-200 °C, practical salinity range 0-40, and varying pressure and is also calibrated by the data set of Millero et al. [1981. Summary of data treatment for the international high pressure equation of state for seawater. UNESCO Technical Papers in Marine Science 38, 99-192]. The freshwater and salt water components are combined to establish a workable multi-polynomial equation, whose coefficients were computed through standard linear regression analysis. The results obtained in this way for density, entropy and potential temperature are comparable with those of existing models, except that our new equations cover a wider temperature—(0-374 °C) than the traditional (0-40 °C) temperature range. One can apply these newly established equations to the calculation of in-situ or

  17. Analysis of heat capacity and Mössbauer data for LuZnSn2 compound

    Directory of Open Access Journals (Sweden)

    Łątka Kazimierz

    2015-03-01

    Full Text Available New analysis of heat capacity data is presented for LuZnSn2 compound that takes into account anharmonic effects together with the existence of Einstein modes. 119mSn Mössbauer spectroscopy was used to monitor the hyperfine parameters at the two crystallographically inequivalent Sn sites in the studied compound. The problem of non-unique mathematical resonance spectrum description and the problem how to choose physically meaningful set of hyperfine parameters will be thoroughly discussed. Measured quadrupole interaction constants by 119mSn Mössbauer spectroscopy give estimations for Vzz component of electric field gradient tensor at both Sn sites in LuZnSn2.

  18. Dynamics of Efficiency Change by Temperature in Diode Pumped Nd:YAG Heat Capacity Laser

    Institute of Scientific and Technical Information of China (English)

    WANG Xiao-Jun; TANG Bing; SHU Xiao-Jian

    2007-01-01

    We investigate the influence of temperature on the efficiency of diode pumped Nd:YAG heat capacity laser is studied. It is shown that the efficiency of such a laser system is greatly reduced at higher temperature. This bad behaviour is mainly caused by the doped-ion redistribution among various Stark levels of the ground state, and by a thermal equilibrium between the upper laser level and the pump level. Meanwhile, the thermal excitations from the ground state to the lower laser level also play a role. We derive a model to describe those effects, with the considerations of emission spectrum of laser diodes, the subtle Stark structures and the linewidth of absorption and of simulated-emission.

  19. Determination of the magnetic anisotropy constant of nanoparticles using measurements of the low-temperature heat capacity

    Energy Technology Data Exchange (ETDEWEB)

    Ugulava, A. [Department of Physics, I.Javakhishvili Tbilisi State University, I.Chavchavadze av. 3, 0179 Tbilisi, Georgia (United States); Chkhaidze, S., E-mail: simon.chkhaidze@tsu.ge [Department of Physics, I.Javakhishvili Tbilisi State University, I.Chavchavadze av. 3, 0179 Tbilisi, Georgia (United States); Kekutia, Sh. [B. Chavchanidze Institute of Cybernetics, at the Technical State University, S. Euli str. 5, 0186, Tbilisi, Georgia (United States); Verulashvili, M. [Department of Physics, A. Tsereteli Kutaisi State University, Queen Tamar str. 59, 0179 Kutaisi, Georgia (United States)

    2014-12-01

    At low temperatures, the anisotropy energy can significantly affect heat capacity of a superparamagnetic “ideal gas”. At sufficiently low temperatures, when the anisotropy energy of uniaxial magnetic nanoparticles exceeds the energy of thermal fluctuations, the anisotropy energy can be expressed as a sum of the energies of two thermodynamic subsystems (two potential wells). One of these subsystems is composed of magnetic nanoparticles oriented predominantly along the axis of anisotropy, and the other – of particles of opposite orientation. There is a similarity between the considered anisotropy energy and the two-level quantum system. Therefore, the temperature dependence of the magnetic part of the heat capacity (similar to Schottky anomaly) will have a sharp peak. At low temperatures, on the curve of the temperature dependence of the heat capacity, besides a usual T{sup 3} background, a portion with a pronounced maximum is monitored. The relation between the maximum heat capacity and the magnetic anisotropy constant is derived. Using this relation and measuring the maximum heat capacity at a given temperature, the numerical value of the magnetic anisotropy constant can be obtained.

  20. High capacity hydrogen storage alloy negative electrodes for use in nickel–metal hydride batteries

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, Hiroshi, E-mail: inoue-h@chem.osakafu-u.ac.jp; Kotani, Norihiro; Chiku, Masanobu; Higuchi, Eiji

    2015-10-05

    Highlights: • Rare earth-free TiV{sub 2.1−x}Cr{sub x}Ni{sub 0.3} (x = 0.4–1.0) alloys were prepared by arc-melting. • All alloys were composed of two phases, bcc phase and TiNi-based phase. • The higher Cr content, the lower discharge capacity, the higher cycle durability. • The lower charge-transfer resistance led to the higher HRD. • The TiV{sub 1.6}Cr{sub 0.5}Ni{sub 0.3} alloy electrode had the highest HRD. - Abstract: Rare earth-free V-based TiV{sub 2.1−x}Cr{sub x}Ni{sub 0.3} (x = 0.4–1.0) alloys were prepared by arc-melting. All alloys were composed of two phases, the primary phase in which the V and Cr constituents were mainly distributed and the secondary phase in which the Ti and Ni constituents were mainly distributed. When the Cr content was increased, the maximum discharge capacity was decreased, but charge–discharge cycle durability was improved. The lower the charge-transfer resistance and the higher the specific discharge current at which the positive shift of potential at degree of discharge of 50% stagnates, the higher the HRD. In the present study, the TiV{sub 1.6}Cr{sub 0.5}Ni{sub 0.3} alloy electrode had the highest HRD.

  1. Pressure perturbation calorimetry, heat capacity and the role of water in protein stability and interactions.

    Science.gov (United States)

    Cooper, A; Cameron, D; Jakus, J; Pettigrew, G W

    2007-12-01

    It is widely acknowledged, and usually self-evident, that solvent water plays a crucial role in the overall thermodynamics of protein stabilization and biomolecular interactions. Yet we lack experimental techniques that can probe unambiguously the nature of protein-water or ligand-water interactions and how they might change during protein folding or ligand binding. PPC (pressure perturbation calorimetry) is a relatively new technique based on detection of the heat effects arising from application of relatively small pressure perturbations (+/-5 atm; 1 atm=101.325 kPa) to dilute aqueous solutions of proteins or other biomolecules. We show here how this can be related to changes in solvation/hydration during protein-protein and protein-ligand interactions. Measurements of 'anomalous' heat capacity effects in a wide variety of biomolecular interactions can also be related to solvation effects as part of a quite fundamental principle that is emerging, showing how the apparently unusual thermodynamics of interactions in water can be rationalized as an inevitable consequence of processes involving the co-operative interaction of multiple weak interactions. This leads to a generic picture of the thermodynamics of protein folding stabilization in which hydrogen-bonding plays a much more prominent role than has been hitherto supposed.

  2. Defining the `negative emission' capacity of global agriculture deployed for enhanced rock weathering

    Science.gov (United States)

    Beerling, D. J.; Taylor, L.; Banwart, S. A.; Kantzas, E. P.; Lomas, M.; Mueller, C.; Ridgwell, A.; Quegan, S.

    2016-12-01

    Enhanced rock weathering involves application of crushed silicates (e.g. basalt) to the landscape to accelerate their chemical breakdown to release base cations and form bicarbonate that ultimate sequester CO2 in the oceans. Global croplands cover an area of 12 million km2 and might be deployed for long-term removal of anthropogenic CO2 through enhanced rock weathering with a number of co-benefits for food security. This presentation assesses the potential of this strategy to contribute to `negative emissions' as defined by a suite of simulations coupling a detailed model of rock grain weathering by crop root-microbial processes with a managed land dynamic global vegetation model driven by the `business as usual' future climate change scenarios. We calculate potential atmospheric CO2 drawdown over the next century by introducing a strengthened C-sink term into the global carbon cycle model within an intermediate complexity Earth system model. Our simulations indicate agricultural lands deployed in this way constitute a `low tech' biological negative emissions strategy. As part of a wider portfolio of options, this strategy might contribute to limiting future warming to 2oC, subject to economic costs and energy requirements.

  3. Heat capacity and Joule-Thomson coefficient of selected n-alkanes at 0.1 and 10 MPa in broad temperature ranges

    DEFF Research Database (Denmark)

    Regueira Muñiz, Teresa; Varzandeh, Farhad; Stenby, Erling Halfdan

    2017-01-01

    Isobaric heat capacity of six n-alkanes, i.e. n-hexane, n-octane, n-decane, n-dodecane, n-tetradecane and n-hexadecane, was determined with a Calvet type differential heat-flux calorimeter at 0.1 and 10 MPa in a broad temperature range. The measured isobaric heat capacity data were combined with ...

  4. EXPERIENCE OF UTILIZATION OF CAPACITY BANKS AND SCHEMES OF FREQUENCY REGULATION IN MUNICIPAL CENTRALIZED HEATING SYSTEM OF CHISINAU

    Directory of Open Access Journals (Sweden)

    CHERNEI M

    2013-04-01

    Full Text Available The current paper provides a brief summary of the district heating system of the municipality Chisinau, including heat power sources, heat distribution network, production and consumption development over the past two decades and other data. Also, the priority investment projects realized by JSC "Termocom" are being presented. The company had implemented an automated monitoring system for the heat power production, transportation and distribution. For many years, the company used bellows pipes with polyurethane insulation, ball valves and plate heat exchangers. 14 out of 21 district heating boiler stations were upgraded 10 were completely automated having as a result no further need in full-time duty personnel there. The experience gained in the implementation of capacity banks and frequency inverters, summarizing the benefits and achieved results, is also presented in the current paper. It is to be underlined that in 2011 the company achieved decrease in electricity consumption by about 30% in comparison with 2005.

  5. Applying a dual process model of self-regulation: The association between executive working memory capacity, negative urgency, and negative mood induction on pre-potent response inhibition.

    Science.gov (United States)

    Gunn, Rachel L; Finn, Peter R

    2015-03-01

    This study tested a dual-process model of self-control where the combination of high impulsivity (negative urgency - NU), weak reflective / control processes (low executive working memory capacity - E-WMC), and a cognitive load is associated with increased failures to inhibit pre-potent responses on a cued go/no-go task. Using a within-subjects design, a cognitive load with and without negative emotional load was implemented to consider situational factors. Results suggested that: (1) high NU was associated with low E-WMC; (2) low E-WMC significantly predicted more inhibitory control failures across tasks; and (3) there was a significant interaction of E-WMC and NU, revealing those with low E-WMC and high NU had the highest rates of inhibitory control failures on all conditions of the task. In conclusion, results suggest that while E-WMC is a strong independent predictor of inhibitory control, NU provides additional information for vulnerability to problems associated with self-regulation.

  6. Dynamic Heat Storage and Cooling Capacity of a Concrete Deck with PCM and Thermally Activated Building System

    DEFF Research Database (Denmark)

    Pomianowski, Michal Zbigniew; Heiselberg, Per; Jensen, Rasmus Lund

    2012-01-01

    the performance of the new deck with PCM concrete is the thermal properties of such a new material, as the PCM concrete is yet to be well defined. The results presented in the paper include models in which the PCM concrete material properties, such as thermal conductivity, and specific heat capacity were first......This paper presents a heat storage and cooling concept that utilizes a phase change material (PCM) and a thermally activated building system (TABS) implemented in a hollow core concrete deck. Numerical calculations of the dynamic heat storage capacity of the hollow core concrete deck element...... with and without microencapsulated PCM are presented. The new concrete deck with microencapsulated PCM is the standard deck on which an additional layer of the PCM concrete was added and, at the same time, the latent heat storage was introduced to the construction. The challenge of numerically simulating...

  7. High-temperature heat capacity of oxides of the CuO-V2O5 system

    Science.gov (United States)

    Denisova, L. T.; Belousova, N. V.; Denisov, V. M.; Galiakhmetova, N. A.

    2017-06-01

    CuV2O6 and Cu2V2O7 compounds have been produced from initial components CuO and V2O5 by solid-phase synthesis. The high-temperature heat capacity of the oxide compounds has been measured using differential scanning calorimetry. The thermodynamic properties (the enthalpy change, the entropy change, and the reduced Gibbs energy) have been calculated using experimental dependences C P = f( T). It is found that there is a correlation between the specific heat capacity and the composition of oxides of the CuO-V2O5 system.

  8. Zero-Thermal Expansion and Heat Capacity of Zirconium Pyrovanadate Doped with Zirconia and Vanadium (V) Oxide

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The dominant phase ZrV2O7 material, doped with zirconia and vanadium (V) oxide, was synthesized by solid state reaction and sol-gel methods. X-ray power diffraction patterns show that it is cubic structure. Thermal mechanic analysis measurements exhibit a zero-thermal expansion of this material above 150 ℃. Meanwhile, the heat capacity dependent on temperature, determined by differential scanning calorimetry, keeps in constant almost in the same temperature range. The relationship between unusual thermal expansion and abnormal heat capacity is discussed with Gr€黱eisen parameter.

  9. Experimental campaign and modeling of a low capacity waste heat recovery system based on a single screw expander

    OpenAIRE

    2014-01-01

    In recent years, due to the increasing concern over energy shortage and global warming, the interest in low grade heat recovery from industrial processes has grown dramatically. Several studies have underlined the potential of small-capacity Organic Rankine Cycle (ORC) power plants for Waste Heat Recovery (WHR) applications. For such systems, accurate models based on actual experimental data represent an important tool, in particular when control issues are considered. This paper presents an ...

  10. Effects of Carbon Structure and Mixing Sequence in an Expander on the Capacity of Negative Electrodes in a Traction Battery

    Science.gov (United States)

    Meenakorn, Somsak; Termsuksawad, Preecha; Phiboonkulsumrit, Sorraya

    2015-01-01

    Expanders were prepared by mixing barium sulfate, sodium lignosulfonate, and carbon materials by a high speed mixer. Effects of type of carbon materials and mixing sequence on electrochemical property of electrode were studied. Three different carbon materials: medium structure carbon black, high structure carbon black, and multi-wall carbon nanotube, were employed. The amount of charge and charge transfer resistance of electrode using different expanders were investigated by cyclic voltammetry and electrochemical impedance spectroscopy, respectively. Prepared expanders were characterized by a transmission electron microscope and a field emission scanning electron microscope. The capacity of the battery was tested by the high discharge rate test. Negative active materials were characterized by a field emission scanning electron microscope. The results showed that the type of carbon material and mixing sequence influenced the structure of carbon network in an expander and resulted in the change of the amount of charge and charge transfer resistance. All prepared expanders exhibited higher amount of charge and lower charge transfer resistance than those of a commercial expander. The highest amount of charge was obtained when the expander was prepared by mixing medium structure carbon black for 90 s before adding high structure carbon black. The high discharge test shows that the capacity of a battery using NAM prepared by this expander is approximately 10% higher than that using a commercial expander. The higher capacity is due to an increase of the surface area of NAM.

  11. An experimental study of waveguide coupled microwave heating with conventional multicusp negative ion sources

    Energy Technology Data Exchange (ETDEWEB)

    Komppula, J.; Kalvas, T.; Koivisto, H.; Laulainen, J.; Tarvainen, O.

    2015-04-08

    Negative ion production with conventional multicusp plasma chambers utilizing 2.45 GHz microwave heating is demonstrated. The experimental results were obtained with the multicusp plasma chambers and extraction systems of the RF-driven RADIS ion source and the filament driven arc discharge ion source LIISA. A waveguide microwave coupling system, which is almost similar to the one used with the SILHI ion source, was used. The results demonstrate that at least one third of negative ion beam obtained with inductive RF-coupling (RADIS) or arc discharge (LIISA) can be achieved with 1 kW of 2.45 GHz microwave power in CW mode without any modification of the plasma chamber. The co-extracted electron to H{sup −} ratio and the optimum pressure range were observed to be similar for both heating methods. The behaviour of the plasma implies that the energy transfer from the microwaves to the plasma electrons is mainly an off-resonance process.

  12. Heat buffers improve capacity and exploitation degree of geothermal energy sources

    NARCIS (Netherlands)

    Ooster, van 't A.; Wit, de J.; Janssen, E.G.O.N.; Ruigrok, J.

    2008-01-01

    This research focuses on the role of heat buffers to support optimal use of combinations of traditional and renewable heat sources like geothermal heat for greenhouse heating. The objective was to determine the contribution of heat buffers to effective new combinations of resources that satisfy gree

  13. Reprint of “Heat capacity and transition behavior of sucrose by standard, fast scanning and temperature-modulated calorimetry”

    Energy Technology Data Exchange (ETDEWEB)

    Magoń, A. [Department of Chemistry, University of Technology, 35-959 Rzeszów (Poland); Wurm, A.; Schick, C. [Department of Physics, University of Rostock, 18057 Rostock (Germany); Pangloli, Ph.; Zivanovic, S. [Department of Food Science and Technology, University of Tennessee, Knoxville, TN 37996 (United States); Skotnicki, M. [Department of Pharmaceutical Technology, Poznan University of Medical Sciences, 60-780 Poznań (Poland); Pyda, M., E-mail: mpyda@utk.edu [Department of Chemistry, University of Technology, 35-959 Rzeszów (Poland)

    2015-03-10

    Highlights: • Experimental, apparent heat capacity of sucrose was investigated by advanced thermal analysis. • Vibrational heat capacity of solid state was linked with a low temperature experimental heat capacity of sucrose. • Equilibrium melting parameters of sucrose were determined. • Decomposition, superheating of crystalline sucrose during melting process were presented. • TGA, DSC, TMDSC, and FSC are useful tools for characterization of sucrose. - Abstract: The heat capacity (C{sub p}) of crystalline and amorphous sucrose was determined using standard and quasi-isothermal temperature modulated differential scanning calorimetry. The results were combined with the published data determined by adiabatic calorimetry, and the C{sub p} values are now reported for the wide 5–600 K range. The experimental C{sub p} of solid sucrose at 5–300 K was used to calculate the vibrational, solid C{sub p} based on the vibrational molecular motions. The calculated solid and liquid C{sub p} together with the transition parameters for equilibrium conditions were used as references for detailed quantitative thermal analysis of crystalline and amorphous sucrose. Melting temperature (T{sub m}) of the crystalline sucrose was identified in a broad 442–465 K range with a heat of fusion of 40–46 J/mol determined at heating rates 0.5–20 K/min, respectively. The equilibrium T{sub m} and heat of fusion of crystalline sucrose were estimated at zero heating rate as T{sup o}{sub m} = 424.4 K and ΔH{sup o}{sub f} = 32 kJ/mol, respectively. The glass transition temperature (T{sub g}) of amorphous sucrose was at 331 K with a change in C{sub p} of 267 J/(mol K) as it was estimated from reversing heat capacity by quasi-isothermal TMDSC on cooling. At heating rates less than 30 K/min, thermal decomposition occurred during melting, while at extreme rate of 1000 K/s, degradation was not observed. Data obtained by fast scanning calorimetry (FSC) at 1000 K/s, showed that T{sub m} was

  14. Low-temperature heat capacity of room-temperature ionic liquid, 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide.

    Science.gov (United States)

    Shimizu, Yoshitaka; Ohte, Yoko; Yamamura, Yasuhisa; Saito, Kazuya; Atake, Tooru

    2006-07-20

    Heat capacities of liquid, stable crystal, and liquid-quenched glass of a room-temperature ionic liquid (RTIL), 1-hexyl-3-methylimidazolium bis(trifluromethylsulfonyl)imide were measured between 5 and 310 K by adiabatic calorimetry. Heat capacity of the liquid at 298.15 K was determined for an IUPAC project as (631.6 +/- 0.5) J K(-1) mol(-1). Fusion was observed at T(fus) = 272.10 K for the stable crystalline phase, with enthalpy and entropy of fusion of 28.34 kJ mol(-1) and 104.2 J K(-1) mol(-1), respectively. The purity of the sample was estimated as 99.83 mol % by the fractional melting method. The liquid could be supercooled easily and the glass transition was observed around T(g) approximately 183 K, which was in agreement with the empirical relation, T(g) approximately ((2)/(3)) T(fus). The heat capacity of the liquid-quenched glass was larger than that of the crystal as a whole. In the lowest temperature region, however, the difference between the two showed a maximum around 6 K and a minimum around 15 K, at which the heat capacity of the glass was a little smaller than that of crystal.

  15. Heat capacity of Tb2Cu2O5 in the temperature range 379-924 K

    Science.gov (United States)

    Denisova, L. T.; Denisov, V. M.; Chumilina, L. G.; Kirik, S. D.; Istomin, S. A.

    2013-12-01

    The heat capacity of Tb2Cu2O5 in the temperature range 379-924 K has been measured using differential scanning calorimetry. It has been shown that the obtained dependence C p = f( T) can be described by a combination of the Debye and Einstein functions.

  16. Sporulation environment of emetic toxin-producing Bacillus cereus strains determines spore size, heat resistance and germination capacity

    NARCIS (Netherlands)

    Voort, van der M.; Abee, T.

    2013-01-01

    Aim Heat resistance, germination and outgrowth capacity of Bacillus cereus spores in processed foods are major factors in causing the emetic type of gastrointestinal disease. In this study, we aim to identify the impact of different sporulation conditions on spore properties of emetic toxin-producin

  17. Sporulation environment of emetic toxin-producing Bacillus cereus strains determines spore size, heat resistance and germination capacity

    NARCIS (Netherlands)

    Voort, van der M.; Abee, T.

    2013-01-01

    Aim Heat resistance, germination and outgrowth capacity of Bacillus cereus spores in processed foods are major factors in causing the emetic type of gastrointestinal disease. In this study, we aim to identify the impact of different sporulation conditions on spore properties of emetic

  18. Low Temperature heat capacity of Uranium-Plutonium MOX single crystals

    Science.gov (United States)

    Griveau, Jean-Christophe; Colineau, Eric; Eloirdi, Rachel; Caciuffo, Roberto

    2015-03-01

    The establishment of the basic properties of actinides based materials is crucial for the understanding of conventional and advanced nuclear fuels. Accessing ground state properties at very low temperature for these systems gives a direct overview of their fundamental features. Moreover, when these materials can be produced as single crystals, side effects due to the presence of grains and impurities phases are drastically reduced, giving a very powerful add-in for theoretical and industrial oriented studies. This clearly ensures the reliability of the parameters determined while existing models of these strategic materials can be probed especially in the purpose of applications/developments and safety concerns. Here we report on heat capacity measurements performed on U-Pu MOX in single crystal form. Tiny crystals with mass of 2 to 15 mg have been produced by solid-solid chemical vapour transport technique with several different compositions ranging from pure UO2 to PuO2. Compositions close to UO2 (U rich) present a persistent signature similarly to the magnetic transition reported for the pure phase TN ~ 31 K while plutonium rich concentrations do not show any hint of the magnetic transition down to the minimum temperature achieved.

  19. Determination of heat capacity of ionic liquid based nanofluids using group method of data handling technique

    Science.gov (United States)

    Sadi, Maryam

    2017-07-01

    In this study a group method of data handling model has been successfully developed to predict heat capacity of ionic liquid based nanofluids by considering reduced temperature, acentric factor and molecular weight of ionic liquids, and nanoparticle concentration as input parameters. In order to accomplish modeling, 528 experimental data points extracted from the literature have been divided into training and testing subsets. The training set has been used to predict model coefficients and the testing set has been applied for model validation. The ability and accuracy of developed model, has been evaluated by comparison of model predictions with experimental values using different statistical parameters such as coefficient of determination, mean square error and mean absolute percentage error. The mean absolute percentage error of developed model for training and testing sets are 1.38% and 1.66%, respectively, which indicate excellent agreement between model predictions and experimental data. Also, the results estimated by the developed GMDH model exhibit a higher accuracy when compared to the available theoretical correlations.

  20. Heat Capacities and Thermodynamic Properties of 3-(2,2-Dichloroethenyl ) -2,2-dimethylcyclopropanecarboxylic Acid

    Institute of Scientific and Technical Information of China (English)

    XUE Bin; WANG Jian-ya; TAN Zhi-cheng; WU Tong-hao

    2007-01-01

    The heat capacities of 3 - (2,2-dichloroethenyl) -2,2-dimethylcyclopropanecarboxylic acid ( a racemic mixture,molar ratio of cis-/trans-structure is 35/65) in a temperature range from 78 to 389 K were measured with a precise automatic adiabatic calorimeter. The sample was prepared with a purity of 98.75% ( molar fraction). A solid-liquid fusion phase transition was observed in the experimental temperature range. The melting point, Tm, enthalpy and entropy of fusion, △fusHm, △fusSm, of the acid were determined to be ( 331.48 ± 0.03 ) K, ( 16. 321 ± 0.031 ) kJ/mol,and (49.24 ± 0.19) J/( K·mol), respectively. The thermodynamic functions of the sample, HT - H298.15, ST -S298.15 and GT - G298.15, were reported at a temperature intervals of 5 K. The thermal decomposition of the sample was studied using thermogravimetric (TG) analytic technique, the thermal decomposition starts at ca. 418 K and ends at ca. 544 K, the maximum decomposition rate was obtained at 510 K. The order of reaction, preexponential factor and activation energy are n =0.23, A =7. 3 × 107 min -1, E =70.64 KJ/mol, respectively.

  1. Analytical insight into the lattice thermal conductivity and heat capacity of monolayer MoS2

    Science.gov (United States)

    Saha, Dipankar; Mahapatra, Santanu

    2016-09-01

    We report, a detailed theoretical study on the lattice thermal conductivity of a suspended monolayer MoS2, far beyond its ballistic limit. The analytical approach adopted in this work mainly relies on the use of Boltzmann transport equation (BTE) within the relaxation time approximation (RTA), along with the first-principles calculations. Considering the relative contributions from the various in-plane and out-of-plane acoustic modes, we derive the closed-form expressions of the mode specific heat capacities, which we later use to obtain the phonon thermal conductivities of the monolayer MoS2. Besides finding the intrinsic thermal conductivity, we also analyse the effect of the phonon-boundary scattering, for different dimensions and edge roughness conditions. The viability of the semi-analytic solution of lattice thermal conductivity reported in this work ranges from a low temperature (T∼30 K) to a significantly high temperature (T∼550 K), and the room temperature (RT) thermal conductivity value has been obtained as 34.06 Wm-1K-1 which is in good agreement with the experimental result.

  2. Large heat capacity anomaly near the consolute point of the binary mixture nitromethane and 3-pentanol

    Science.gov (United States)

    Losada-Pérez, Patricia; Tripathi, Chandra Shekhar Pati; Leys, Jan; Glorieux, Christ; Thoen, Jan

    2011-01-01

    The large critical anomaly in the isobaric heat capacity C_{p,x}(T) of the binary mixture nitromethane + 3-pentanol is measured using high-resolution adiabatic scanning calorimetry. The unique features of this technique provided an alternative approach to the study of the critical behavior of C_{p,x}(T), providing further C_{p,x}(T) related quantities from which valuable information could be extracted. Our data are in full agreement with the predictions of the Modern Theory of Critical Phenomena; specifically, 3D-Ising model values for the critical exponent α and the universal amplitude ratio values of the leading critical amplitudes, as well as for the first correction-to-scaling ones, provide the optimum fits to represent the experimental data. Evidence for the need of higher-order terms, i.e., first correction-to-scaling term, is given. The large value of the coefficient E for the linear temperature dependence of the background obtained is ascribed to a possible contribution of the regular linear background term, of a higher-order asymmetry term, and of the second correction-to-scaling term. Internal consistency of C_{p,x}(T) and its related quantities is successfully checked.

  3. OVEREXPRESSION OF DOMINANT-NEGATIVE IRE1 ENZYME IN H1299-shE6AP CELLS INCREASES HEAT SHOCK ELEMENT-DEPENDENT TRANSCRIPTION

    Directory of Open Access Journals (Sweden)

    D. O.

    2015-12-01

    Full Text Available To investigate IRE1-dependent branch of endoplasmic reticulum stress pathway in various cancer cells we created cDNA-constructs for expression of dominant-negative inositol-requiring enzyme – 1 IRE1 and cytosolic domain of IRE1 fused on a C-terminus with c-Myc and 6xHis tags. The non-small-cell lung carcinoma cells H1299-shE6AP were transfected with these constructs. Using anti-c-Myc antibodies we demonstrated effective, dose-dependent expression of dominant-negative and cytosolic IRE1 proteins. In order to investigate IRE1-mediated, heat shock element-dependent transcription, the cells were further transfected with a reporter construct containing heat shock element. We observed that overexpression of dnIRE1 in H1299-shE6AP cells led to significant induction of heat shock element-dependent transcription. This observation may reflect the induction of heat shock genes, which contribute to cellular adaptation to inhibition of native IRE1, a key sensory-signaling enzyme of endoplasmic reticulum stress pathway, which suppresses cancer cell proliferative capacities and alternates the expression of numerous genes, including many transcription factors.

  4. Limits to sustained energy intake. XXIII. Does heat dissipation capacity limit the energy budget of lactating bank voles?

    Science.gov (United States)

    Sadowska, Edyta T; Król, Elżbieta; Chrzascik, Katarzyna M; Rudolf, Agata M; Speakman, John R; Koteja, Paweł

    2016-03-01

    Understanding factors limiting sustained metabolic rate (SusMR) is a central issue in ecological physiology. According to the heat dissipation limit (HDL) theory, the SusMR at peak lactation is constrained by the maternal capacity to dissipate body heat. To test that theory, we shaved lactating bank voles (Myodes glareolus) to experimentally elevate their capacity for heat dissipation. The voles were sampled from lines selected for high aerobic exercise metabolism (A; characterized also by increased basal metabolic rate) and unselected control lines (C). Fur removal significantly increased the peak-lactation food intake (mass-adjusted least square means ± s.e.; shaved: 16.3 ± 0.3 g day(-1), unshaved: 14.4 ± 0.2 g day(-1); Plines. Thus, the experimental evolution model did not reveal a difference in the limiting mechanism between animals with inherently different metabolic rates.

  5. Current-Controlled Negative Differential Resistance Due to Joule Heating In Tio2

    Science.gov (United States)

    Bratkovsky, A. M.; Alexandrov, A. S.; Savel'Ev, S. E.; Strukov, D. B.; Williams, R. S.

    2012-02-01

    We show that Joule heating causes current-controlled negative differential resistance (CC-NDR) in TiO2 memristive systems by constructing an analytical model of the current-voltage characteristics based on polaronic transport for Ohm's law and Newton's law of cooling and fitting this model to experimental data. This threshold switching is he ``soft breakdown'' observed during electroforming in TiO2 and other transition-metal oxide based memristors, as well as a precursor to ``ON'' or ``SET'' switching of unipolar memristors from their high to their low resistance states. The shape of the V-I curves is a sensitive indicator of the nature of the polaronic conduction, which apparently follows an adiabatic regime [1]. [4pt] [1] A.S. Alexandrov, A.M.Bratkovsky, B.Bridle, S.E.Savel'ev, D. Strukov, and R.S.Williams, Appl. Phys. Lett. 99, xxx (2011).

  6. Excess Molar Volume,Viscosity and Heat Capacity for the Mixture of 1,2—Propanediol—Water at Different Temperatures

    Institute of Scientific and Technical Information of China (English)

    杨长生; 马沛生; 唐多强; 靳凤民

    2003-01-01

    Experimental densities,viscosities and heat capacities at different emperatures were presented over the entire mole fraction range for the binary mixture of 1,2-propanediol and water,Density values were used in the determination of excess molar volumes,VE,At the same time,the excess viscosity was in vestigated,The values of VE and ηE were fitted to the Redlich-kister equation.Good agreement was observed,The excess volumes are negative over the entire range of composition.They show an U-shaped-concentration dependence and decrease in abolute values with increase of temperature,Values of ηE are negative over the entire range of the composition,and has a trend very similar to that of VE ,The analysis shows that at any temperature the specific heat of mixture is a linear function of the composition as x1>20%,All the extended lines intersect at one point.An empirical equation is obtained to calculate the specific heat to mixture at any composition and temperature in the experimental range.

  7. Current instabilities under HF electron gas heating in semiconductors with negative differential conductivity

    Energy Technology Data Exchange (ETDEWEB)

    Gurevich, Yu. G.; Logvinov, G. N. [Instituto Politecnico Nacional, Mexico, D.F. (Mexico); Laricheva, N. [Datmouth College, New Hampshire (United States); Mashkevich, O. L. [Kharkov University, Kharkov (Ukraine)

    2001-10-01

    A nonlinear temperature dependence of the kinetic coefficients of semiconductor plasma can result in the appearance of regions of negative differential conductivity (NDC) in both the high-frequency (HF) and static current-voltage characteristics (CVC). In the present paper the formation of the static NDC under simultaneous electron gas heating by HF and static electric field is studied. As is shown below, in this case the heating electromagnetic wave has a pronounced effect on the appearance of NDC caused by the overheating mechanisms and the type of the static CVC as a whole. [Spanish] Una dependencia no lineal de la temperatura de los coeficientes cineticos del plasma del semiconductor puede llevar a la aparicion de regiones con conductividad diferencial negativa (CDN) en las caracteristicas corriente voltaje (CCV) de alta frecuencia (AF) y estatica. En este articulo se estudia la formacion de la CDN estatica bajo la accion simultanea del calentamiento del gas de electrones por AF y el campo electrico estatico. Como se muestra mas adelante, en este caso la onda electromagnetica que calienta a los electrones ejerce un fuerte efecto en la aparicion de la CDN; que se obtiene por mecanismos de sobrecalentamiento, y en el tipo de CCV estatica.

  8. Acute oral administration of a tyrosine and phenylalanine-free amino acid mixture reduces exercise capacity in the heat.

    Science.gov (United States)

    Tumilty, Les; Davison, Glen; Beckmann, Manfred; Thatcher, Rhys

    2013-06-01

    Acute tyrosine administration is associated with increased exercise capacity in the heat. To explore whether reduced plasma tyrosine and phenylalanine (tyrosine precursor) is associated with impaired exercise capacity in the heat, eight healthy, moderately trained male volunteers, unacclimated to exercise in the heat, performed two tests in a crossover design separated by at least 7 days. In a randomised, double-blind fashion, subjects ingested 500 mL flavoured, sugar-free water containing amino acids [(TYR-free; isoleucine 15 g, leucine 22.5 g, valine 17.5 g, lysine 17.5 g, methionine 5 g, threonine 10 g, tryptophan 2.5 g)] to lower the ratio of plasma tyrosine plus phenylalanine:amino acids competing for blood-brain barrier uptake (CAA), a key determinant of brain uptake, or a balanced mixture (BAL; TYR-free plus 12.5 g tyrosine and 12.5 g phenylalanine). One hour later, subjects cycled to exhaustion at 63 ± 5 % [Formula: see text]O2peak in 30 °C and 60 % relative humidity. Pre-exercise ratio of plasma tyrosine plus phenylalanine:ΣCAA declined 75 ± 5 % from rest in TYR-free (P 0.05) and thermal sensation (P > 0.05) were similar at exhaustion in both trials. These data indicate that acutely depleting plasma catecholamine precursors:ΣCAA is associated with reduced submaximal exercise capacity in the heat.

  9. Thermodynamic properties of biofuels: Heat capacities of binary mixtures containing ethanol and hydrocarbons up to 20 MPa and the pure compounds using a new flow calorimeter

    Energy Technology Data Exchange (ETDEWEB)

    Vega-Maza, David [Research Group TERMOCAL, Thermodynamics and Calibration, Department of Energy, University of Valladolid, Paseo del Cauce 59, E-47011 Valladolid (Spain); Segovia, Jose J., E-mail: josseg@eis.uva.es [Research Group TERMOCAL, Thermodynamics and Calibration, Department of Energy, University of Valladolid, Paseo del Cauce 59, E-47011 Valladolid (Spain); Carmen Martin, M.; Villamanan, Rosa M.; Villamanan, Miguel A. [Research Group TERMOCAL, Thermodynamics and Calibration, Department of Energy, University of Valladolid, Paseo del Cauce 59, E-47011 Valladolid (Spain)

    2011-12-15

    Highlights: > Isobaric heat capacities for heptane, ethanol, and the mixtures of ethanol with heptane and toluene are reported. > They have been measured at 5 pressures over the range (0 to 20) MPa. > An automated flow calorimeter has been developed for the measurements. > The experimental data are fitted to Redlich-Kister equations. > Excess isobaric heat capacities are calculated. - Abstract: Heat capacities are of great significance in the design of new processes and the improvement of existing ones in R and D in production plants as well as the adaptation of new products, in this case, biofuels to their use in a variety of engines and technical devices. An automated flow calorimeter has been developed for the accurate measurement of isobaric heat capacities for pure compounds and mixtures over the range (250 to 400) K and (0 to 20) MPa. In this paper, isobaric heat capacities for heptane, ethanol and the binary mixtures of ethanol with heptane and toluene are reported.

  10. A method for determination of heat storage capacity of the mold materials using a differential thermal analysis

    Science.gov (United States)

    Ol'khovik, E.

    2016-04-01

    The article proposes a method for determining of the heat storage capacity of the mould materials. Modern materials for mouldsare made using a variety of technologies, and the manufacturers of binders and additives ensure thermal properties of certain materials only when using a certain recipe. In practice, for management of the casting solidification process (creation of the volume or directed mode) it is favorable to apply various technological methods, including modification of one of the important properties of the casting mould, which is heat storage capacity. A rather simple technique based on the application of the differential thermal analysis was developed for its experimental definition. The obtained data showed a possibility of industrial application of the method.

  11. Bias induced modulation of electrical and thermal conductivity and heat capacity of BN and BN/graphene bilayers

    Science.gov (United States)

    Chegel, Raad

    2017-04-01

    By using the tight binding approximation and Green function method, the electronic structure, density of state, electrical conductivity, heat capacity of BN and BN/graphene bilayers are investigated. The AA-, AB1- and AB2- BN/graphene bilayers have small gap unlike to BN bilayers which are wide band gap semiconductors. Unlike to BN bilayer, the energy gap of graphene/BN bilayers increases with external field. The magnitude of the change in the band gap of BN bilayers is much higher than the graphene/BN bilayers. Near absolute zero, the σ(T) is zero for BN bilayers and it increases with temperature until reaches maximum value then decreases. The BN/graphene bilayers have larger electrical conductivity larger than BN bilayers. For both bilayers, the specific heat capacity has a Schottky anomaly.

  12. Bias induced modulation of electrical and thermal conductivity and heat capacity of BN and BN/graphene bilayers

    Energy Technology Data Exchange (ETDEWEB)

    Chegel, Raad, E-mail: Raad.chegel@gmail.com

    2017-04-15

    By using the tight binding approximation and Green function method, the electronic structure, density of state, electrical conductivity, heat capacity of BN and BN/graphene bilayers are investigated. The AA-, AB{sub 1}- and AB{sub 2}- BN/graphene bilayers have small gap unlike to BN bilayers which are wide band gap semiconductors. Unlike to BN bilayer, the energy gap of graphene/BN bilayers increases with external field. The magnitude of the change in the band gap of BN bilayers is much higher than the graphene/BN bilayers. Near absolute zero, the σ(T) is zero for BN bilayers and it increases with temperature until reaches maximum value then decreases. The BN/graphene bilayers have larger electrical conductivity larger than BN bilayers. For both bilayers, the specific heat capacity has a Schottky anomaly.

  13. Unprecedented Integral-Free Debye Temperature Formulas: Sample Applications to Heat Capacities of ZnSe and ZnTe

    Directory of Open Access Journals (Sweden)

    R. Pässler

    2017-01-01

    Full Text Available Detailed analytical and numerical analyses are performed for combinations of several complementary sets of measured heat capacities, for ZnSe and ZnTe, from the liquid-helium region up to 600 K. The isochoric (harmonic parts of heat capacities, CVh(T, are described within the frame of a properly devised four-oscillator hybrid model. Additional anharmonicity-related terms are included for comprehensive numerical fittings of the isobaric heat capacities, Cp(T. The contributions of Debye and non-Debye type due to the low-energy acoustical phonon sections are represented here for the first time by unprecedented, integral-free formulas. Indications for weak electronic contributions to the cryogenic heat capacities are found for both materials. A novel analytical framework has been constructed for high-accuracy evaluations of Debye function integrals via a couple of integral-free formulas, consisting of Debye’s conventional low-temperature series expansion in combination with an unprecedented high-temperature series representation for reciprocal values of the Debye function. The zero-temperature limits of Debye temperatures have been detected from published low-temperature Cp(T data sets to be significantly lower than previously estimated, namely, 270 (±3 K for ZnSe and 220 (±2 K for ZnTe. The high-temperature limits of the “true” (harmonic lattice Debye temperatures are found to be 317 K for ZnSe and 262 K for ZnTe.

  14. Effect of hydrolysis on heat capacity, thermodynamic functions, and the relaxation transition of crab chitin and chitosan

    Science.gov (United States)

    Kashtanov, E. A.; Uryash, V. F.; Kokurina, N. Yu.; Larina, V. N.

    2014-02-01

    The heat capacity of crab chitin and chitosan is measured in a vacuum adiabatic calorimeter at 10-330 K. The thermodynamic characteristics (enthalpy, entropy, and Gibbs function) are calculated at T → 0 K to 330 K. Differential thermal analysis is used to calculate the relaxation transitions and thermal degradation of chitin and chitosan at 80-600 K. Acid hydrolysis is performed and its effect on the physicochemical properties and thermodynamic functions of chitin and chitosan is studied.

  15. Laser Measurement of the Speed of Sound in Gases: A Novel Approach to Determining Heat Capacity Ratios and Gas Composition

    Science.gov (United States)

    Baum, J. Clayton; Compton, R. N.; Feigerle, Charles S.

    2008-01-01

    The speed of sound is measured in several gases using a pulsed laser to create a micro-spark on a carbon rod and a microphone connected to a digital oscilloscope to measure the time-of-flight of the resulting shockwave over a known distance. These data are used to calculate the heat capacity ratios (C[subscript p]/C[subscript V]) of the gases and…

  16. Simultaneous measurement of thermal conductivity and heat capacity of bulk and thin film materials using frequency-dependent transient thermoreflectance method.

    Science.gov (United States)

    Liu, Jun; Zhu, Jie; Tian, Miao; Gu, Xiaokun; Schmidt, Aaron; Yang, Ronggui

    2013-03-01

    The increasing interest in the extraordinary thermal properties of nanostructures has led to the development of various measurement techniques. Transient thermoreflectance method has emerged as a reliable measurement technique for thermal conductivity of thin films. In this method, the determination of thermal conductivity usually relies much on the accuracy of heat capacity input. For new nanoscale materials with unknown or less-understood thermal properties, it is either questionable to assume bulk heat capacity for nanostructures or difficult to obtain the bulk form of those materials for a conventional heat capacity measurement. In this paper, we describe a technique for simultaneous measurement of thermal conductivity κ and volumetric heat capacity C of both bulk and thin film materials using frequency-dependent time-domain thermoreflectance (TDTR) signals. The heat transfer model is analyzed first to find how different combinations of κ and C determine the frequency-dependent TDTR signals. Simultaneous measurement of thermal conductivity and volumetric heat capacity is then demonstrated with bulk Si and thin film SiO2 samples using frequency-dependent TDTR measurement. This method is further testified by measuring both thermal conductivity and volumetric heat capacity of novel hybrid organic-inorganic thin films fabricated using the atomic∕molecular layer deposition. Simultaneous measurement of thermal conductivity and heat capacity can significantly shorten the development∕discovery cycle of novel materials.

  17. A study on specific heat capacities of Li-ion cell components and their influence on thermal management

    Science.gov (United States)

    Loges, André; Herberger, Sabrina; Seegert, Philipp; Wetzel, Thomas

    2016-12-01

    Thermal models of Li-ion cells on various geometrical scales and with various complexity have been developed in the past to account for the temperature dependent behaviour of Li-ion cells. These models require accurate data on thermal material properties to offer reliable validation and interpretation of the results. In this context a thorough study on the specific heat capacities of Li-ion cells starting from raw materials and electrode coatings to representative unit cells of jelly rolls/electrode stacks with lumped values was conducted. The specific heat capacity is reported as a function of temperature and state of charge (SOC). Seven Li-ion cells from different manufactures with different cell chemistry, application and design were considered and generally applicable correlations were developed. A 2D thermal model of an automotive Li-ion cell for plug-in hybrid electric vehicle (PHEV) application illustrates the influence of specific heat capacity on the effectivity of cooling concepts and the temperature development of Li-ion cells.

  18. Novel Synthesis of β-FeOOH Nanofluid and Determination of Its Heat Capacity by an Adiabatic Calorimeter

    Institute of Scientific and Technical Information of China (English)

    NAN, Zhaodong; ZHANG, Pingping; YU, Aijun; WEI, Chengzhen; SHI, Quan; TAN, Zhicheng

    2009-01-01

    A novel and facile method for preparation of stable nanofluid is introduced, in which FeCl3·6H2O and urea were used as reactants without any surfactants. The obtained solid sample was proved to be β-FeOOH by XRD technol- ogy and spindle-shaped by TEM technology. The coexisting NH3 molecules may be the main reason for the stable nanofluid. The weak bonding between nitrogen and iron atoms would be formed. The investigation on the excess heat capacity of the obtained nanofluid sustains this opinion. The heat capacities of the obtained β-FeOOH particles and the nanofluid were determined by an adiabatic calorimeter. And these obtained results will help the applications of β-FeOOH and the nanofluid to industry, and the establishment of the model of thermal conductivity of nanofluid. The thermodynamic properties of the obtained β-FeOOH particles and the nanofluid were calculated based on the obtained functions of heat capacity with respective to thermodynamic temperature and the relationships between the thermodynamic properties.

  19. The determination of values of the specific heat capacity of the selected thermal insulation materials used in track bed structure

    Directory of Open Access Journals (Sweden)

    Dobeš Peter

    2017-01-01

    Full Text Available The report concentrates on the determination of the specific heat capacity of the selected thermal insulation materials (liapor, styrodur, foam concrete. The aim of the report is to gain the necessary input parameters for the numerical modelling of the temperature changes of various track bed structures of the railway line where a part or, if appropriate, the whole protective layer is replaced by the material with better thermal insulation properties. There are described the methods for stating the specific heat capacity as well as the calibration of the calorimeter for stating of the calorimetric constant in the introduction of the report. The parameters needed for calculation of the specific heat capacity of the selected thermal insulation materials are characterized in the second part of the report. There are also introduced the laboratory stated values of the parameter in question. The comparison of the values stated by the laboratory measurements with the values introduced in the technical data sheets from their producers (or if appropriate gained from the foreign sources is made in the conclusion of the report.

  20. Practical approach for measuring heat capacity of pharmaceutical crystals/glasses by modulated-temperature differential scanning calorimetry.

    Science.gov (United States)

    Harada, Takuji; Kawakami, Kohsaku; Yoshihashi, Yasuo; Yonemochi, Etsuo; Terada, Katsuhide; Moriyama, Hiroshi

    2013-01-01

    A practical protocol to obtain accurate heat capacity values of pharmaceutical compounds using modulated-temperature differential scanning calorimetry was established. Three pharmaceutical compounds, acetaminophen, indomethacin, and tri-O-methyl-β-cyclodextrin were used as model compounds. Powder samples did not produce reproducible results, presumably due to inclusion of gas in gap of powders that influenced the measured heat capacity and thermal homogeneity in the sample. Thus, the amorphous characteristics were evaluated using quench-cooled samples. Crystalline samples were obtained by partially melting the sample to allow recrystallization using the residual crystal as a template. Optimum sample mass was about 10 mg. Use of too small sample size resulted in poor reproducibility due to localization of the sample in the pan, while too large size resulted in low heat capacity values probably because of heterogeneity of the sample temperature. The optimum modulation period was in the range of 60 s and 90 s, to which the ramp rates of 2°C/min and 1°C/min, respectively, were applied. The ramp amplitude was less significant in the evaluation. This information should help in comprehending basic characteristics of pharmaceutical compounds.

  1. Evaluation on the heat removal capacity of the first wall for water cooled breeder blanket of CFETR

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, Kecheng, E-mail: jiangkecheng@ipp.ac.cn; Cheng, Xiaoman; Chen, Lei; Huang, Kai; Ma, Xuebin; Liu, Songlin

    2016-02-15

    Highlights: • Heat removal capacity of the FW is evaluated under BWR, PWR and He coolant inlet conditions. • Heat transfer property of the gas–liquid two phase and the two boiling crises are analyzed. • Heat removal capacity of water is larger than helium coolant. - Abstract: The water cooled ceramic breeder blanket (WCCB) is being researched for Chinese Fusion Engineering Test Reactor (CFETR). As an important component of the blanket, the FW should satisfy with the thermal requirements in any case. In this paper, three parameters including the heat removal capacity, coolant pressure drop as well as the temperature rise of the FW were investigated under different coolant velocity and heat flux from the plasma. Using the same first wall structure, two main water cooled schemes including Boiling Water Reactor (BWR, 7 MPa pressure and 265 °C temperature inlet) and Pressurized Water Reactor (PWR, 15 MPa pressure and 285 °C temperature inlet) conditions are discussed in the thermal hydraulic calculation. For further research, the thermal hydraulic characteristics of using helium as coolant (8 MPa pressure, 300 °C temperature inlet) are also explored to provide CFETR blanket design with more useful data supports. Without regard to the outlet coolant condition requirements of the blanket, the results indicate that the ultimate heat flux that the FW can resist is 2.2 MW/m{sup 2} at velocity of 5 m/s for BWR, 2.0 MW/m{sup 2} at velocity of 5 m/s for PWR and 0.87 MW/m{sup 2} for helium at velocity 100 m/s under the chosen operation condition. The detrimental departure from nucleate boiling (DNB) crisis would occur at the velocity of 1 m/s under the heat flux of 3 MW/m{sup 2} and dry out crisis appears at the velocity of less than 0.2 m/s with the heat flux of more than 1 MW/m{sup 2} for BWR. The further blanket/FW optimization design is provided with more useful data references according to the abundant calculation results.

  2. Multiple pulse-heating experiments with different current to determine total emissivity, heat capacity, and electrical resistivity of electrically conductive materials at high temperatures.

    Science.gov (United States)

    Watanabe, Hiromichi; Yamashita, Yuichiro

    2012-01-01

    A modified pulse-heating method is proposed to improve the accuracy of measurement of the hemispherical total emissivity, specific heat capacity, and electrical resistivity of electrically conductive materials at high temperatures. The proposed method is based on the analysis of a series of rapid resistive self-heating experiments on a sample heated at different temperature rates. The method is used to measure the three properties of the IG-110 grade of isotropic graphite at temperatures from 850 to 1800 K. The problem of the extrinsic heating-rate effect, which reduces the accuracy of the measurements, is successfully mitigated by compensating for the generally neglected experimental error associated with the electrical measurands (current and voltage). The results obtained by the proposed method can be validated by the linearity of measured quantities used in the property determinations. The results are in reasonably good agreement with previously published data, which demonstrate the suitability of the proposed method, in particular, to the resistivity and total emissivity measurements. An interesting result is the existence of a minimum in the emissivity of the isotropic graphite at around 1120 K, consistent with the electrical resistivity results.

  3. Low-temperature heat capacities of crystalline Ho(Gly)_3Cl_3·3H_2O from 78 to 348 K

    Institute of Scientific and Technical Information of China (English)

    张景楠; 王辉; 谭志诚; 刘北平; 史全; 童波

    2009-01-01

    Heat capacities of the rare-earth complex with glycine [Ho(Gly)3Cl3·3H2O] were measured with a high-precision automatic adiabatic calorimeter over the temperature range from 78 to 348 K.In the experimental temperature range,the heat capacities increased in a smooth and continuous manner and no phase transition or thermal anomaly occurred.Therefore,the sample was stable in the above temperature range.The values of experimental heat capacities were fitted to a polynomial equation with least square method and ...

  4. Heat capacities of the mixtures of ionic liquids with methanol at temperatures from 283.15 K to 323.15 K

    Energy Technology Data Exchange (ETDEWEB)

    Waliszewski, Dariusz [Department of Physical Chemistry, University of Lodz, PL-90 236 Lodz (Poland)], E-mail: waliszew@uni.lodz.pl

    2008-02-15

    The molar isobaric heat capacities of (methanol + 1-hexyl-3-methylimidazolium tetrafluoroborate) and (methanol + 1-methyl-3-octylimidazolium tetrafluoroborate) mixtures have been determined over the temperature range from 283.15 K to 323.15 K within the whole composition range. The excess molar heat capacities of investigated mixtures have been fitted to the Redlich-Kister equation at several selected temperatures. Positive deviations from the additivity of molar heat capacities have been observed in both examined systems. The results obtained have been discussed in terms of molecular interactions in binary mixtures.

  5. Energy savings in one-pipe steam heating systems fitted with high-capacity air vents. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1994-09-01

    Multifamily buildings heated by one-pipe steam systems experience significant temperature gradients from apartment to apartment, often reaching 15{degrees}F. As a result, many tenants are to cold, or if the heating system output is increased so as to heat the coldest apartment adequately, too hot. While both are undesirable, the second is particularly so because it wastes energy. It was thought that insufficient air venting of the steam pipes contributed to the gradient. Theoretically, if steam mains and risers are quickly vented, steam will reach each radiator at approximately the same time and balance apartment temperatures. The project`s objective was to determine if the installation of large-capacity air vents at the ends of steam mains and risers would economically reduce the temperature gradient between apartments and reduce the amount of space heating energy required. The test was conducted by enabling and disabling air vents biweekly in 10 multifamily buildings in New York City between December 1992 to May 1993. The temperatures of selected apartments and total space heating energy were compared during each venting regime. There was no difference in energy consumption between ``vents on`` and ``vents off`` periods (see Tables 2 and 5); however, there was a reduction in the maximum spread of apartment temperatures.

  6. Measurement of heat load density profile on acceleration grid in MeV-class negative ion accelerator

    Energy Technology Data Exchange (ETDEWEB)

    Hiratsuka, Junichi, E-mail: hiratsuka.junichi@jaea.go.jp; Hanada, Masaya; Kojima, Atsushi; Umeda, Naotaka; Kashiwagi, Mieko; Yoshida, Masafumi; Nishikiori, Ryo; Ichikawa, Masahiro; Watanabe, Kazuhiro; Tobari, Hiroyuki [Japan Atomic Energy Agency, 801-1 Mukoyama, Naka 311-0193 (Japan); Miyamoto, Kenji [Naruto University of Education, 748 Nakashima, Takashima, Naruto-cho, Naruto-shi, Tokushima 772-8502 (Japan)

    2016-02-15

    To understand the physics of the negative ion extraction/acceleration, the heat load density profile on the acceleration grid has been firstly measured in the ITER prototype accelerator where the negative ions are accelerated to 1 MeV with five acceleration stages. In order to clarify the profile, the peripheries around the apertures on the acceleration grid were separated into thermally insulated 34 blocks with thermocouples. The spatial resolution is as low as 3 mm and small enough to measure the tail of the beam profile with a beam diameter of ∼16 mm. It was found that there were two peaks of heat load density around the aperture. These two peaks were also clarified to be caused by the intercepted negative ions and secondary electrons from detailed investigation by changing the beam optics and gas density profile. This is the first experimental result, which is useful to understand the trajectories of these particles.

  7. Investigation of heat transfer in high-capacity power transformers having modifications preventing explosions

    Science.gov (United States)

    Aksenov, A. A.; Zhluktov, S. V.; Kudimov, N. F.; Son, E. E.; Savitskii, D. V.; Tretiyakova, O. N.; Shishaeva, A. S.

    2014-12-01

    Results of numerical simulation of complex conjugate heat transfer in a high power electric transformer are presented. Simulation of the flow and heat transfer inside a transformer with static blast protection was carried out. Analysis of test calculations performed in the FlowVision software suit was carried out. Comparison of the performance of created numerical model against the real experimental data from the thermal tests of the transformer was made.

  8. Ice ingestion with a long rest interval increases the endurance exercise capacity and reduces the core temperature in the heat.

    Science.gov (United States)

    Naito, Takashi; Iribe, Yuka; Ogaki, Tetsuro

    2017-01-05

    The timing in which ice before exercise should be ingested plays an important role in optimizing its success. However, the effects of differences in the timing of ice ingestion before exercise on cycling capacity, and thermoregulation has not been studied. The aim of the present study was to assess the effect of length of time after ice ingestion on endurance exercise capacity in the heat. Seven males ingested 1.25 g kg body mass(-1) of ice (0.5 °C) or cold water (4 °C) every 5 min, six times. Under three separate conditions after ice or water ingestion ([1] taking 20 min rest after ice ingestion, [2] taking 5 min rest after ice ingestion, and [3] taking 5 min rest after cold water ingestion), seven physically active male cyclists exercised at 65% of their maximal oxygen uptake to exhaustion in the heat (35 °C, 30% relative humidity). Participants cycled significantly longer following both ice ingestion with a long rest interval (46.0 ± 7.7 min) and that with a short rest interval (38.7 ± 5.7 min) than cold water ingestion (32.3 ± 3.2 min; both p Heat storage under condition of ice ingestion with a long rest interval during the pre-exercise period was significantly lower than that observed with a short rest interval (-4.98 ± 2.50 W m(-2); p heat, which is suggested to be driven by a reduced rectal temperature and heat storage before the start of exercise.

  9. Heat-treated Escherichia coli as a high-capacity biosorbent for tungsten anions.

    Science.gov (United States)

    Ogi, Takashi; Makino, Takahiko; Iskandar, Ferry; Tanabe, Eishi; Okuyama, Kikuo

    2016-10-01

    Adsorption performance in the biosorption of tungsten using Escherichia coli cells can be significantly improved by using cell suspensions that have been heat-treated at ⩽100°C. In the case of E. coli cells suspension heated at 100°C, the aqueous tungsten ions concentration rapidly decreased from 0.8mmol/L to practically zero within 1h. This biosorption time is much shorter than that of non-heat treated E. coli cells (7h). Furthermore, the adsorption saturation amount for cells heat-treated at 100°C was significantly increased up to 1.62mmol-W/g-E. coli compared to the unheated E. coli cells case (0.62mmol-W/g-E. coli). Determination of the surface potential and surface structure along with quantitative analyses of free amino acids of heat-treated E. coli cells were also carried out and revealed that heated cells have a high zeta potential and express a higher concentration of amino acids on the cell surface.

  10. Dimensionless Model of a Thermoelectric Cooling Device Operating at Real Heat Transfer Conditions: Maximum Cooling Capacity Mode

    Science.gov (United States)

    Melnikov, A. A.; Kostishin, V. G.; Alenkov, V. V.

    2016-09-01

    Real operating conditions of a thermoelectric cooling device are in the presence of thermal resistances between thermoelectric material and a heat medium or cooling object. They limit performance of a device and should be considered when modeling. Here we propose a dimensionless mathematical steady state model, which takes them into account. Analytical equations for dimensionless cooling capacity, voltage, and coefficient of performance (COP) depending on dimensionless current are given. For improved accuracy a device can be modeled with use of numerical or combined analytical-numerical methods. The results of modeling are in acceptable accordance with experimental results. The case of zero temperature difference between hot and cold heat mediums at which the maximum cooling capacity mode appears is considered in detail. Optimal device parameters for maximal cooling capacity, such as fraction of thermal conductance on the cold side y, fraction of current relative to maximal j' are estimated in range of 0.38-0.44 and 0.48-0.95, respectively, for dimensionless conductance K' = 5-100. Also, a method for determination of thermal resistances of a thermoelectric cooling system is proposed.

  11. Calculation of thermal conductivity, thermal diffusivity and specific heat capacity of sedimentary rocks using petrophysical well logs

    Science.gov (United States)

    Fuchs, Sven; Balling, Niels; Förster, Andrea

    2015-12-01

    In this study, equations are developed that predict for synthetic sedimentary rocks (clastics, carbonates and evapourates) thermal properties comprising thermal conductivity, specific heat capacity and thermal diffusivity. The rock groups are composed of mineral assemblages with variable contents of 15 major rock-forming minerals and porosities of 0-30 per cent. Petrophysical properties and their well-logging-tool-characteristic readings were assigned to these rock-forming minerals and to pore-filling fluids. Relationships are explored between each thermal property and other petrophysical properties (density, sonic interval transit time, hydrogen index, volume fraction of shale and photoelectric absorption index) using multivariate statistics. The application of these relations allows computing continuous borehole profiles for each rock thermal property. The uncertainties in the prediction of each property vary depending on the selected well-log combination. Best prediction is in the range of 2-8 per cent for the specific heat capacity, of 5-10 per cent for the thermal conductivity, and of 8-15 for the thermal diffusivity, respectively. Well-log derived thermal conductivity is validated by laboratory data measured on cores from deep boreholes of the Danish Basin, the North German Basin, and the Molasse Basin. Additional validation of thermal conductivity was performed by comparing predicted and measured temperature logs. The maximum deviation between these logs is effect on the subsurface temperature field can be observed in the North German Basin. This effect reduces the surface heat-flow density by 25 mW m-2.

  12. Effects of caffeine on endurance capacity and psychological state in young females and males exercising in the heat.

    Science.gov (United States)

    Suvi, Silva; Timpmann, Saima; Tamm, Maria; Aedma, Martin; Kreegipuu, Kairi; Ööpik, Vahur

    2017-01-01

    Acute caffeine ingestion is considered effective in improving endurance capacity and psychological state. However, current knowledge is based on the findings of studies that have been conducted on male subjects mainly in temperate environmental conditions, but some physiological and psychological effects of caffeine differ between the sexes. The purpose of this study was to compare the physical performance and psychological effects of caffeine in young women and men exercising in the heat. Thirteen male and 10 female students completed 2 constant-load walks (60% of thermoneutral peak oxygen consumption on a treadmill until volitional exhaustion) in a hot-dry environment (air temperature, 42 °C; relative humidity, 20%) after caffeine (6 mg·kg(-1)) and placebo (wheat flour) ingestion in a double-blind, randomly assigned, crossover manner. Caffeine, compared with placebo, induced greater increases (p Caffeine decreased (p caffeine was associated with a shorter time to exhaustion. In conclusion, acute caffeine ingestion increases HR and blood lactate levels during exercise in the heat, but it has no impact on thermoregulation or endurance capacity in either gender. Under exercise-heat stress, caffeine reduces ratings of perceived exertion and fatigue in males but not in females.

  13. Thermoeconomic Evaluation of Modular Organic Rankine Cycles for Waste Heat Recovery over a Broad Range of Heat Source Temperatures and Capacities

    Directory of Open Access Journals (Sweden)

    Markus Preißinger

    2017-02-01

    Full Text Available Industrial waste heat recovery by means of an Organic Rankine Cycle (ORC can contribute to the reduction of CO2 emissions from industries. Before market penetration, high efficiency modular concepts have to be developed to achieve appropriate economic value for industrial decision makers. This paper aims to investigate modularly designed ORC systems from a thermoeconomic point of view. The main goal is a recommendation for a suitable chemical class of working fluids, preferable ORC design and a range of heat source temperatures and thermal capacities in which modular ORCs can be economically feasible. For this purpose, a thermoeconomic model has been developed which is based on size and complexity parameters of the ORC components. Special emphasis has been laid on the turbine model. The paper reveals that alkylbenzenes lead to higher exergetic efficiencies compared to alkanes and siloxanes. However, based on the thermoeconomic model, the payback periods of the chemical classes are almost identical. With the ORC design, the developed model and the boundary conditions of this study, hexamethyldisiloxane is a suitable working fluid and leads to a payback period of less than 5 years for a heat source temperature of 400 to 600 °C and a mass flow rate of the gaseous waste heat stream of more than 4 kg/s.

  14. The Expression of Carnosine and Its Effect on the Antioxidant Capacity of Muscle in Finishing Pigs Exposed to Constant Heat Stress

    Directory of Open Access Journals (Sweden)

    Peige Yang

    2014-12-01

    Full Text Available The objective of this study was to assess the effects of constant high ambient temperatures on meat quality, antioxidant capacity, and carnosine expression in longissimus dorsi muscle of finishing pigs. Castrated 24 male DLY (crossbreeds between Landrace×Yorkshire sows and Duroc boars pigs were allocated to one of three treatments: constant ambient temperature at 22°C and ad libitum feeding (CON, n = 8; constant high ambient temperature at 30°C and ad libitum feeding (H30, n = 8; and constant ambient temperature at 22°C and pair-fed with H30 (PF, n = 8. Meat quality, malondialdehyde (MDA content, antioxidant capacity, carnosine content, and carnosine synthetase (CARNS1 mRNA expression in longissimus dorsi muscle were measured after three weeks. The results revealed that H30 had lower pH24 h, redness at 45 min, and yellowness at 24 h post-mortem (p<0.05, and higher drip loss at 48 h and lightness at 24 h post-mortem (p<0.01. Constant heat stress disrupted the pro-oxidant/antioxidant balance in longissimus dorsi muscle with higher MDA content (p<0.01 and lower antioxidant capacity (p<0.01. Carnosine content and CARNS1 mRNA expression in longissimus dorsi muscle of H30 pigs were significantly decreased (p<0.01 after three weeks at 30°C. In conclusion, constant high ambient temperatures affect meat quality and antioxidant capacity negatively, and the reduction of muscle carnosine content is one of the probable reasons.

  15. Heat capacity of associated systems. Experimental data and application of a two-state model to pure liquids and mixtures.

    Science.gov (United States)

    Cerdeiriña, Claudio A; Troncoso, Jacobo; Gonzalez-Salgado, Diego; García-Miaja, Gonzalo; Hernandez-Segura, Gerardo O; Bessières, David; Medeiros, Milton; Romaní, Luis; Costas, Miguel

    2007-02-08

    The predictions from a recently reported (J. Chem. Phys. 2004, 120, 6648) two-state association model (TSAM) have been tested against experimental data. The temperature, T, and pressure, p, dependence of the isobaric heat capacity, C(p), for three pure alcohols and the temperature dependence at atmospheric pressure of the excess heat capacity, C(p)(E), for four alcohol + ester mixtures have been measured. The branched alcohols were 3-pentanol, 3-methyl-3-pentanol, and 3-ethyl-3-pentanol, and the mixtures were 1-butanol and 3-methyl-3-pentanol mixed with propyl acetate and with butyl formate. These data, together with literature data for alcohol + n-alkane and alcohol + toluene mixtures, have been analyzed using the TSAM. The model, originally formulated for the C(p) of pure liquids, has been extended here to account for the C(p)(E) of mixtures. To evaluate its performance, quantum mechanical ab initio calculations for the H-bond energy, which is one of the model parameters, were performed. The effect of pressure on C(p) for pure liquids was elucidated, and the variety of C(p)(E)(T) behaviors was rationalized. Furthermore, from the C(p) data at various pressures, the behavior of the volume temperature derivative, (deltaV/deltaT)(p), was inferred, with the existence of a (deltaV/deltaT)(p) versus T maximum for pure associated liquids such as the branched alcohols being predicted. It is concluded that the TSAM captures the essential elements determining the behavior of the heat capacity for pure liquids and mixtures, providing insight into the macroscopic manifestation of the association phenomena occurring at the molecular level.

  16. Low-temperature Heat Capacities and Thermodynamic Properties of Hydrated Sodium Cupric Arsenate [ NaCuAsO4·1.5H2O(s)

    Institute of Scientific and Technical Information of China (English)

    CHEN Jing-tao; DI You-ying; TAN Zhi-cheng; SUN Li-xian

    2007-01-01

    Low-temperature heat capacities of the solid compound NaCuAsO4 · 1.5H2O(s) were measured using a precision automated adiabatic calorimeter over a temperature range of T = 78 K to T = 390 K. A dehydration process occurred in the temperature range of T = 368-374 K. The peak temperature of the dehydration was observed to be TD = (371.828±0.146) K by means of the heat-capacity measurement. The molar enthalpy and entropy of the dehyperimental values of heat capacities for the solid(Ⅰ) and the solid-liquid mixture(Ⅱ) were respectively fitted to two polynomial equations by the least square method. The smoothed values of the molar heat capacities and the fundamental thermodynamic functions of the sample relative to the standard reference temperature 298.15 K were tabulated at an interval of 5 K.

  17. Analysis and experimental study of the temperature and stress distribution in the slab of a solid-state heat capacity laser

    Science.gov (United States)

    Yang, Jiankun; Wan, Xuebin; Xu, Xiaojun; Lu, Qisheng

    2008-03-01

    In conventional cooling operation, thermal effects and stress distribution in slabs of solid-state laser are presented by many workers, it is different with that in the solid state heat capacity laser. In this paper, the transient temperature and stress distribution in Xeon flash lamps pumped slabs for single-shot and repetitively pulsed operations will be produced in the heat capacity operation. A high speed CCD camera was used to set up an experiment system to measure the interference fringes, from these fringes' changes, the extension of the slab due to the stress and thermal expansion can be obtained. Since dielectric materials are inherently several factors stronger in compression than in tension, this temperature reversal in heat capacity operation increases the inherent fracture limit of the system and allows a heat capacity operated laser to be pumped much harder than a conventionally operated slab laser.

  18. Compressibility, thermal expansion coefficient and heat capacity of CH4 and CO2 hydrate mixtures using molecular dynamics simulations.

    Science.gov (United States)

    Ning, F L; Glavatskiy, K; Ji, Z; Kjelstrup, S; H Vlugt, T J

    2015-01-28

    Understanding the thermal and mechanical properties of CH4 and CO2 hydrates is essential for the replacement of CH4 with CO2 in natural hydrate deposits as well as for CO2 sequestration and storage. In this work, we present isothermal compressibility, isobaric thermal expansion coefficient and specific heat capacity of fully occupied single-crystal sI-CH4 hydrates, CO2 hydrates and hydrates of their mixture using molecular dynamics simulations. Eight rigid/nonpolarisable water interaction models and three CH4 and CO2 interaction potentials were selected to examine the atomic interactions in the sI hydrate structure. The TIP4P/2005 water model combined with the DACNIS united-atom CH4 potential and TraPPE CO2 rigid potential were found to be suitable molecular interaction models. Using these molecular models, the results indicate that both the lattice parameters and the compressibility of the sI hydrates agree with those from experimental measurements. The calculated bulk modulus for any mixture ratio of CH4 and CO2 hydrates varies between 8.5 GPa and 10.4 GPa at 271.15 K between 10 and 100 MPa. The calculated thermal expansion and specific heat capacities of CH4 hydrates are also comparable with experimental values above approximately 260 K. The compressibility and expansion coefficient of guest gas mixture hydrates increase with an increasing ratio of CO2-to-CH4, while the bulk modulus and specific heat capacity exhibit the opposite trend. The presented results for the specific heat capacities of 2220-2699.0 J kg(-1) K(-1) for any mixture ratio of CH4 and CO2 hydrates are the first reported so far. These computational results provide a useful database for practical natural gas recovery from CH4 hydrates in deep oceans where CO2 is considered to replace CH4, as well as for phase equilibrium and mechanical stability of gas hydrate-bearing sediments. The computational schemes also provide an appropriate balance between computational accuracy and cost for predicting

  19. Thermal sensitivity analysis data utilizing Q10 scanning, Boltzmann slope factor and the change of molar heat capacity.

    Science.gov (United States)

    Kang, KyeongJin

    2016-03-01

    As a further elaboration of the recently devised Q10 scanning analysis ("Exceptionally high thermal sensitivity of rattlesnake TRPA1 correlates with peak current amplitude" [1]), the interval between current data points at two temperatures was shortened and the resulting parameters representing thermal sensitivities such as peak Q10s and temperature points of major thermosensitivity events are presented for two TRPA1 orthologues from rattlesnakes and boas. In addition, the slope factors from Boltzmann fitting and the change of molar heat capacity of temperature-evoked currents were evaluated and compared as alternative ways of thermal sensitivity appraisal of TRPA1 orthologues.

  20. Heat Capacity and Enthalpy of Fusion of Crystalline Pyrimethanil Decylate (C22 H33 N3 O2)

    Institute of Scientific and Technical Information of China (English)

    SUN Xiao-hong; LIU Yuan-fa; TAN Zhi-cheng; WANG Mei-han; JIA Ying-qi

    2005-01-01

    Low-temperature heat capacities of pyrimethanil decylate (C22 H33 N3 O2) were precisely measured with an automated adiabatic calorimeter over the temperature range from 78 to 373 K. The sample was observed to melt at(311.04 ±0.06) K. The molar enthalpy and entropy of fusion as well as the chemical purity of the compound were determined The extrapolated melting temperature for the absolutely pure compound obtained from fractional melting experiments is (311.204±0.035) K.

  1. Heat capacity of the frustrated magnetic pyrochlores Gd2Zr2O7 and Gd2Hf2O7

    Science.gov (United States)

    Durand, Alice M.; Klavins, Peter; Corruccini, L. R.

    2008-06-01

    The heat capacities of Gd2Zr2O7 and Gd2Hf2O7 both show sharp peaks in the vicinity of 0.77 K, consistent with the existence of long range magnetic order. They are superimposed in both cases on broader maxima centered at approximately 1 K, presumably due to short range spin correlations. Both compounds exhibit antiferromagnetic interactions, with Weiss constants of approximately -7 K. Comparisons are made to earlier results for the isomorphic compounds Gd2Ti2O7 and Gd2Sn2O7.

  2. IMP improves water-holding capacity, physical and sensory properties of heat-induced gels from porcine meat.

    Science.gov (United States)

    Nakamura, Yukinobu; Migita, Koshiro; Okitani, Akihiro; Matsuishi, Masanori

    2014-05-01

    Water-holding capacity (WHC) of heat-induced pork gels was examined. The heat-induced gels were obtained from meat homogenates prepared by adding nine volumes of 0.3-0.5 mol/L NaCl solutions containing 9-36 mmol/L disodium inosine-5'-monophosphate (IMP) or 9 mmol/L tetrapotassium pyrophosphate (KPP) to minced pork. IMP at 36 mmol/L enhanced the WHC to the same level as attained by KPP. Physical and sensory properties of heat-induced gels were also examined. The heat-induced gels were prepared from porcine meat homogenates containing 0.3 mol/L NaCl and 9-36 mmol/L IMP or 9 mmol/L KPP. IMP at 36 mmol/L enhanced the values of hardness, cohesiveness, gumminess and springiness, measured with a Tensipresser, and several organoleptic scores to the same level as the score attained by KPP. Thus, it is concluded that IMP is expected to be a practical substitute for pyrophosphates to improve the quality of sausages.

  3. Calculation of difference in heat capacities at constant pressure and constant volume with the aid of the empirical Nernst and Lindemann equation

    Science.gov (United States)

    Leontev, K. L.

    1981-07-01

    An expression is obtained for heat capacity differences of materials at a constant pressure and volume, on the basis of the rigorous thermodynamic equation (Kittel, 1976), and by using the Grueneisen law (Kikoin and Kikoin, 1976) of constancy of the ratio of the cubic expansion coefficient to the molar heat capacity. Conditions are determined, where the empirical Nernst and Lindemann (Filippov, 1967) equation is regarded as rigorous.

  4. Using heat demand prediction to optimise Virtual Power Plant production capacity

    NARCIS (Netherlands)

    Bakker, Vincent; Molderink, Albert; Hurink, Johann L.; Smit, Gerardus Johannes Maria

    2008-01-01

    In the coming decade a strong trend towards distributed electricity generation (microgeneration) is expected. Micro-generators are small appliances that generate electricity (and heat) at the kilowatt level, which allows them to be installed in households. By combining a group of micro-generators, a

  5. Prediction of capacity of heat exchanger by thermal network method. Prediction of a capacity of a condenser with effective specific heat model; Netsukairomoho ni yoru kuki chowayo netsukokanki seino no yosoku. Yukohi netsu model wo mochiita gyosukukuki seino no o yosoku

    Energy Technology Data Exchange (ETDEWEB)

    Kaga, K.; Yamada, K.; Koto, S.; Ogushi, T. [Mitsubishi Electric Corp. Tokyo (Japan)

    2000-07-25

    In this paper, thermal network method using effective specific heat model of refrigerant with phase change is proposed for predicting the capacity of a plate fin and tube type heat exchanger. Effective specific heat model suits for obtaining an accurate result of a heat exchanging capacity of a condenser with small number of elements. By comparing calculated results with experiment, it is clarified that an error of calculated capacity of condenser is less than 1% in case that the range of sub-cool degree is from 15K to 22K at outlet of refrigerant flow. (author)

  6. The heat capacity of Li{sub 2}MoO{sub 4} in the temperature range 6–310 K

    Energy Technology Data Exchange (ETDEWEB)

    Musikhin, A.E., E-mail: musikhin@niic.nsc.ru; Naumov, V.N.; Bespyatov, M.A.; Ivannikova, N.V.

    2015-08-05

    Highlights: • The low temperature heat capacity of Li{sub 2}MoO{sub 4} single crystal was measured. • Integral thermodynamic functions at 298.15 K were calculated. • An equation for extrapolation of heat capacity to 0 K was proposed. • The result of the analysis indicates to the possible existence of the bosonic peak. - Abstract: The heat capacity of a single crystal of lithium molybdate Li{sub 2}MoO{sub 4} in the range 6–310 K was measured by the adiabatic method. No anomalous behavior of the heat capacity was found. Based on the obtained data, thermodynamic functions (entropy, enthalpy, and reduced Gibbs energy) under standard conditions were calculated. An equation for extrapolation of low-temperature heat capacity to 0 K was proposed, which has a wider temperature range of applicability as compared to the scope of validity of the Debye law (C ∼ T{sup 3}). Analysis of heat capacity behavior points to the presence of a low-frequency peak in the density of phonon states for Li{sub 2}MoO{sub 4}.

  7. Effect of high energy electron beam (10MeV) on specific heat capacity of low-density polyethylene/hydroxyapatite nano-composite.

    Science.gov (United States)

    Soltani, Z; Ziaie, F; Ghaffari, M; Beigzadeh, A M

    2017-02-01

    In the present work, thermal properties of low density polyethylene (LDPE) and its nano composites are investigated. For this purpose LDPE reinforced with different weight percents of hydroxyapatite (HAP) powder which was synthesized via hydrolysis method are produced. The samples were irradiated with 10MeV electron beam at doses of 75 to 250kGy. Specific heat capacity measurement have been carried out at different temperatures, i.e. 25, 50, 75 and 100°C using modulated temperature differential scanning calorimetry (MTDSC) apparatus and the effect of three parameters include of temperature, irradiation dose and the amount of HAP nano particles as additives on the specific heat capacity of PE/HAP have been investigated precisely. The MTDSC results indicate that the specific heat capacity have decreased by addition of nano sized HAP as reinforcement for LDPE. On the other hand, the effect of radiation dose is reduction in the specific heat capacity in all materials including LDPE and its nano composites. The HAP nano particles along with cross-link junctions due to radiation restrain the movement of the polymer chains in the vicinity of each particle and improve the immobility of polymer chains and consequently lead to reduction in specific heat capacity. Also, the obtained results confirm that the radiation effect on the specific heat capacity is more efficient than the reinforcing effect of nano-sized hydroxyapatite.

  8. Study on Optimizing Thermal Energy Storage Capacity for Heat Supply System

    Institute of Scientific and Technical Information of China (English)

    曹家枞

    2001-01-01

    Thermal energy storage (TES) can increase the energetic efficiencies and, in many cases, the exergetic efficiencies of thermal energy systems. Steam boiler plant with a violently fluctuating load is a typical example when a steam accumulator is added to it. While the conparatively big first cost constitutes a barrier to the wide use of TES, the cost will notably be reduced through minimizing the necessary thermal capacity of it JThe structure and illustrations are given for the computer program designed for performing the optimization. This'program was applied to an existing boiler plant equipped with a steam accumulator. The results show that there would have been a big reduction in the necessary capacity, if the design of this steam accumulator had been optimized. Four conclusions have been reached.

  9. Small heat-shock proteins and leaf cooling capacity account for the unusual heat tolerance of the central spike leaves in Agave tequilana var. Weber.

    Science.gov (United States)

    Luján, Rosario; Lledías, Fernando; Martínez, Luz María; Barreto, Rita; Cassab, Gladys I; Nieto-Sotelo, Jorge

    2009-12-01

    Agaves are perennial crassulacean acid metabolism (CAM) plants distributed in tropical and subtropical arid environments, features that are attractive for studying the heat-shock response. In agaves, the stress response can be analysed easily during leaf development, as they form a spirally shaped rosette, having the meristem surrounded by folded leaves in the centre (spike) and the unfolded and more mature leaves in the periphery. Here, we report that the spike of Agave tequilana is the most thermotolerant part of the rosette withstanding shocks of up to 55 degrees C. This finding was inconsistent with the patterns of heat-shock protein (Hsp) gene expression, as maximal accumulation of Hsp transcripts was at 44 degrees C in all sectors (spike, inner, middle and outer). However, levels of small HSP (sHSP)-CI and sHSP-CII proteins were conspicuously higher in spike leaves at all temperatures correlating with their thermotolerance. In addition, spike leaves showed a higher stomatal density and abated more efficiently their temperature several degrees below that of air. We propose that the greater capacity for leaf cooling during the day in response to heat stress, and the elevated levels of sHSPs, constitute part of a set of strategies that protect the SAM and folded leaves of A. tequilana from high temperatures.

  10. Thermodynamic study of simple molecular glasses: universal features in their heat capacity and the size of the cooperatively rearranging regions.

    Science.gov (United States)

    Tatsumi, Soichi; Aso, Shintaro; Yamamuro, Osamu

    2012-07-27

    We have obtained some universal thermodynamic properties on glass transitions of molecular liquids. The heat capacity C(p) of glassy propene, which was vitrified by using a vapor-deposition technique, was measured with a newly developed adiabatic calorimeter. Propene has the lowest glass transition temperature (T(g)=56 K), the largest C(p) jump at T(g) (C(p)(lq)/C(p)(gl)~2.5), and the lowest residual entropy (S(res)~Rln2) compared with glass-forming molecules measured before. We have analyzed the present data with other hydrocarbon molecules vitrified by liquid quenching and obtained the following results: (1) The excess heat capacities are scaled well by using a Kauzmann temperature T(K), (2) The size of the cooperative rearrangement region (CRR) frozen at T(g) increases with decreasing the temperature difference between T(g) and T(K) (Kauzmann temperature), and (3) The simpler the molecule is, the larger the frozen CRR becomes. These are all supporting the validity of the Adam-Gibbs theory.

  11. Discontinuity in heat capacity of Fe0.5Co0.5(110) alloy thin films

    Science.gov (United States)

    Ramírez-Dámaso, G.; Castillo-Alvarado, F.-L.; Cruz-Torres, A.; Rójas-Hernández, E.

    2016-07-01

    In this work we calculate heat capacity of alloy thin films of FeCo on the surface of the plane (110), using three parameters, the concentration x(i), the lattice long range order parameter t(i) and the magnetic order parameter σ(i), being i the number of layers of the thin film. The formulations reported by Hill [1] in the context of small particles and Valenta's model [2] can be applied to the film structure when we treat a thin film as a system divided into subsystems equivalent to two-dimensional parallel layers. The FeCo bulk alloy is completely homogeneous while a thin film have spatial discontinuities in their surfaces. We consider three ferromagnetic thin films formed by 11, 15 and 19 layers in the Helmholtz's free energy, which is minimized applying their first partial derivatives with respect to chemical composition, long range order parameter and magnetic order parameter. We calculate internal energy and heat capacity as a function of temperature and we verify that have two jumps as are reported in literature for the bulk; there are many results of bulk or surface effects of FeCo, but no enough results about ferromagnetic FeCo thin films and this fact does this work interesting.

  12. Preparation, non-isothermal decomposition kinetics, heat capacity and adiabatic time-to-explosion of NTOxDNAZ.

    Science.gov (United States)

    Ma, Haixia; Yan, Biao; Li, Zhaona; Guan, Yulei; Song, Jirong; Xu, Kangzhen; Hu, Rongzu

    2009-09-30

    NTOxDNAZ was prepared by mixing 3,3-dinitroazetidine (DNAZ) and 3-nitro-1,2,4-triazol-5-one (NTO) in ethanol solution. The thermal behavior of the title compound was studied under a non-isothermal condition by DSC and TG/DTG methods. The kinetic parameters were obtained from analysis of the DSC and TG/DTG curves by Kissinger method, Ozawa method, the differential method and the integral method. The main exothermic decomposition reaction mechanism of NTOxDNAZ is classified as chemical reaction, and the kinetic parameters of the reaction are E(a)=149.68 kJ mol(-1) and A=10(15.81)s(-1). The specific heat capacity of the title compound was determined with continuous C(p) mode of microcalorimeter. The standard mole specific heat capacity of NTOxDNAZ was 352.56 J mol(-1)K(-1) in 298.15K. Using the relationship between C(p) and T and the thermal decomposition parameters, the time of the thermal decomposition from initialization to thermal explosion (adiabatic time-to-explosion) was obtained.

  13. Molecular simulation of caloric properties of fluids modelled by force fields with intramolecular contributions: Application to heat capacities

    Science.gov (United States)

    Smith, William R.; Jirsák, Jan; Nezbeda, Ivo; Qi, Weikai

    2017-07-01

    The calculation of caloric properties such as heat capacity, Joule-Thomson coefficients, and the speed of sound by classical force-field-based molecular simulation methodology has received scant attention in the literature, particularly for systems composed of complex molecules whose force fields (FFs) are characterized by a combination of intramolecular and intermolecular terms. The calculation of a thermodynamic property for a system whose molecules are described by such a FF involves the calculation of the residual property prior to its addition to the corresponding ideal-gas property, the latter of which is separately calculated, either using thermochemical compilations or nowadays accurate quantum mechanical calculations. Although the simulation of a volumetric residual property proceeds by simply replacing the intermolecular FF in the rigid molecule case by the total (intramolecular plus intermolecular) FF, this is not the case for a caloric property. We describe the correct methodology required to perform such calculations and illustrate it in this paper for the case of the internal energy and the enthalpy and their corresponding molar heat capacities. We provide numerical results for cP, one of the most important caloric properties. We also consider approximations to the correct calculation procedure previously used in the literature and illustrate their consequences for the examples of the relatively simple molecule 2-propanol, CH3CH(OH)CH3, and for the more complex molecule monoethanolamine, HO(CH2)2NH2, an important fluid used in carbon capture.

  14. Low Temperature Heat Capacity of Layered Superconductors SrNi2Ge2 and SrPd2Ge2

    Science.gov (United States)

    Hung, T. L.; Chen, I. A.; Huang, C. H.; Lin, C. Y.; Chen, C. W.; You, Y. B.; Jian, S. T.; Yang, M. C.; Hsu, Y. Y.; Ho, J. C.; Chen, Y. Y.; Ku, H. C.

    2013-04-01

    Low-temperature heat capacity C( T) of the weakly electron-correlated SrNi2Ge2 122-layer compound undergoes a superconducting transition with onset at 1.4 K and a bulk T c =0.75 K, where heat-capacity jump ratio ΔC( T c )/ γT c =0.88-1.05. A small average superconducting energy gap E g (ave)=2.21 kT c =0.14 meV is derived for this multi-gap superconductor. Similar results for isostructural SrPd2Ge2 include T c (onset)=3.5 K, bulk T c of 2.92 K, ΔC( T c )/ γT c =0.70 and E g (ave)=2.54 kT c =0.64 meV. The higher T c onset could be associated with stoichiometric 1:2:2 grains in the polycrystalline samples. In addition, deviations of E g / kT c from the BCS ratio of 3.5 suggest that, just like their iron-based counterpart, these 122-layer germanides may also exhibit an unconventional, fully-opened multi-gap s-wave superconductivity.

  15. A comprehensive assessment of geographic variation in heat tolerance and hardening capacity in populations of Drosophila melanogaster from eastern Australia

    DEFF Research Database (Denmark)

    Sgrò, C M; Overgaard, J; Kristensen, T N;

    2010-01-01

    We examined latitudinal variation in adult and larval heat tolerance in Drosophila melanogaster from eastern Australia. Adults were assessed using static and ramping assays. Basal and hardened static heat knockdown time showed significant linear clines; heat tolerance increased towards the tropics...... knockdown temperature increased towards temperate latitudes, probably reflecting a greater capacity of temperate flies to withstand sudden temperature increases during summer in temperate Australia. Larval viability showed a quadratic association with latitude under heat stress. Thus, patterns of heat...... resistance depend on assay methods. Genetic correlations in thermotolerance across life stages and evolutionary potential for critical thermal limits should be the focus of future studies....

  16. Effects of Heat Treatment on Flavonoids Content and Antioxidant Capacity of Buckwheat (Fagopyrum tataricum Gaert) Flour Ethanolic Extracts

    Institute of Scientific and Technical Information of China (English)

    ZHONG Geng; Romeo T Toledo; CHEN Zong-dao

    2003-01-01

    The chemical composition, total flavonoids and antioxidant capacity of 50% ethanolic extracts from raw and cooked buckwheat flour from southwest of China were determined. The heat treatment used to gelatinize the flour starch significantly reduced the total flavonoids in the extract from 83.52 to 67.36 mg 100 g-1 of dry matter in the raw and cooked flour, respectively. The antioxidant capacity of the extracts was evaluated using autooxidation in a β-carotene-linoleate model system (AA or AAC), DPPH radical scavenging assay (IP) and oxygen radical absorbance capacity (ORAC) assay. Values for raw buckwheat flour extract were 97.84, 874.31, 76.45 and 94.92% for AA, AAC, ORAC and IP, respectively, while values in cooked buckwheat flour were 86.14, 842.88, 63.93 and 94.74% for AA, AAC, ORAC and IP, respectively. Values before cooked and raw buckwheat flour extracts were significantly different (P<0.05) for AA, AAC, and ORAC.

  17. Heat capacity measurements on YbGd2–Zr2O7 ( = 0, 1, 2) ceramics by differential scanning calorimetry

    Indian Academy of Sciences (India)

    Zhan-Guo Liu; Jia-Hu Ouyang; Yu Zhou

    2009-12-01

    YbGd2–Zr2O7 ( = 0, 1, 2) ceramics were pressureless-sintered using ceramic powders acquired by chemical-coprecipitation and calcination methods. Heat capacities of YbGd2–Zr2O7 were measured with a heat flux-type differential scanning calorimetry in the temperature range of 298–1200 K. At 298 K, the heat capacities of Gd2Zr2O7, YbGdZr2O7 and Yb2Zr2O7 were 214, 221 and 230 J.K-1 mol-1, respectively.

  18. Modular compact house substations for district heating with capacities of up to 1 MW. Modulare Fernwaermekompakthausstation bis 1 MW Leistung

    Energy Technology Data Exchange (ETDEWEB)

    Schmitt, F. (Mannheimer Versorgungs- und Verkehrsgesellschaft mbH (MVV), Mannheim (Germany)); Dausch, H.J. (Mannheimer Versorgungs- und Verkehrsgesellschaft mbH (MVV), Mannheim (Germany))

    1994-03-01

    The ever-increasing competition on the heating market has forced us - within the framework of overall optimization of district-heating service - to continue improving our house substantions as the main link between distribution lines and consumer installations. The aim is to develop a modern, high-tech 'product', capable of supplying any demand regardless of the technical parameters involved. Furthermore, it should integrate the best of the respective economic, functional, operational, and aesthetic attributes of this technology. These objectives provide us with very precisely definable demands on the various elements of our hourse substantions. The following considerations form the main focus of optimization: Compactness, the right concept to meet each individual case, coverage of a capacity range of up to 1 MW, managing the large variety of alternatives with the aid of a modular system, incorporating thermostats oriented to outside temperatures, resolving questions on integration of water-heating systems for domestic use into the substantion concepts, and designing system piping and instrumentation. However, investments as well as operating and maintenance costs should always be maintained well within the lowest possible parameters. This article presents the most important basic thinking on these points. It also provides information on some additional aims of optimization, references, and projects already completed. (orig.)

  19. Molecular cloning and expression of a hexameric Drosophila heat shock factor subject to negative regulation.

    Science.gov (United States)

    Clos, J; Westwood, J T; Becker, P B; Wilson, S; Lambert, K; Wu, C

    1990-11-30

    We report the cloning of the transcriptional activator of heat shock genes, HSF, from Drosophila. The predicted sequence of Drosophila HSF protein is surprisingly divergent from that of yeast HSF, except in regions important for DNA binding and oligomerization. A segment of the DNA binding domain of HSF bears an intriguing similarity to the putative DNA recognition helix of bacterial sigma factors, while the oligomerization domain contains an unusual arrangement of conserved hydrophobic heptad repeats. Drosophila HSF produced in E. coli under nonshock conditions forms a hexamer that binds specifically to DNA with high affinity and activates transcription from a heat shock promoter in vitro. In contrast, when HSF is expressed in Xenopus oocytes, maximal DNA binding affinity is observed only after heat shock induction. These results suggest that Drosophila HSF has an intrinsic affinity for DNA, which is repressed under nonshock conditions in vivo.

  20. Development of a molecular-dynamics-based cluster-heat-capacity model for study of homogeneous condensation in supersonic water-vapor expansions.

    Science.gov (United States)

    Borner, Arnaud; Li, Zheng; Levin, Deborah A

    2013-02-14

    Supersonic expansions to vacuum produce clusters of sufficiently small size that properties such as heat capacities and latent heat of evaporation cannot be described by bulk vapor thermodynamic values. In this work the Monte-Carlo Canonical-Ensemble (MCCE) method was used to provide potential energies and constant-volume heat capacities for small water clusters. The cluster structures obtained using the well-known simple point charge model were found to agree well with earlier simulations using more rigorous potentials. The MCCE results were used as the starting point for molecular dynamics simulations of the evaporation rate as a function of cluster temperature and size which were found to agree with unimolecular dissociation theory and classical nucleation theory. The heat capacities and latent heat obtained from the MCCE simulations were used in direct-simulation Monte-Carlo of two experiments that measured Rayleigh scattering and terminal dimer mole fraction of supersonic water-jet expansions. Water-cluster temperature and size were found to be influenced by the use of kinetic rather than thermodynamic heat-capacity and latent-heat values as well as the nucleation model.

  1. Exposure to positively- and negatively-charged plasma cluster ions impairs IgE-binding capacity of indoor cat and fungal allergens

    OpenAIRE

    NISHIKAWA, Kazuo; Fujimura, Takashi; Ota, Yasuhiro; Abe, Takuya; ElRamlawy, Kareem Gamal; Nakano, Miyako; Takado, Tomoaki; Uenishi, Akira; Kawazoe, Hidechika; Sekoguchi, Yoshinori; Tanaka, Akihiko; Ono, Kazuhisa; Kawamoto, Seiji

    2016-01-01

    Background Environmental control to reduce the amount of allergens in a living place is thought to be important to avoid sensitization to airborne allergens. However, efficacy of environmental control on inactivation of airborne allergens is not fully investigated. We have previously reported that positively- and negatively-charged plasma cluster ions (PC-ions) reduce the IgE-binding capacity of crude allergens from Japanese cedar pollen as important seasonal airborne allergens. Cat (Felis do...

  2. Body temperature null distributions in reptiles with nonzero heat capacity: seasonal thermoregulation in the American alligator (Alligator mississippiensis).

    Science.gov (United States)

    Seebacher, Frank; Elsey, Ruth M; Trosclair, Phillip L

    2003-01-01

    Regulation of body temperature may increase fitness of animals by ensuring that biochemical and physiological processes proceed at an optimal rate. The validity of current methods of testing whether or not thermoregulation in reptiles occurs is often limited to very small species that have near zero heat capacity. The aim of this study was to develop a method that allows estimation of body temperature null distributions of large reptiles and to investigate seasonal thermoregulation in the American alligator (Alligator mississippiensis). Continuous body temperature records of wild alligators were obtained from implanted dataloggers in winter (n=7, mass range: 1.6-53.6 kg) and summer (n=7, mass range: 1.9-54.5 kg). Body temperature null distributions were calculated by randomising behavioural postures, thereby randomly altering relative animal surface areas exposed to different avenues of heat transfer. Core body temperatures were predicted by calculations of transient heat transfer by conduction and blood flow. Alligator body temperatures follow regular oscillations during the day. Occasionally, body temperature steadied during the day to fall within a relatively narrow range. Rather than indicating shuttling thermoregulation, however, this pattern could be predicted from random movements. Average daily body temperature increases with body mass in winter but not in summer. Daily amplitudes of body temperature decrease with increasing body mass in summer but not in winter. These patterns result from differential exposure to heat transfer mechanisms at different seasons. In summer, alligators are significantly cooler than predictions for a randomly moving animal, and the reverse is the case in winter. Theoretical predictions show, however, that alligators can be warmer in winter if they maximised their sun exposure. We concluded that alligators may not rely exclusively on regulation of body temperature but that they may also acclimatise biochemically to seasonally

  3. Determination of heat capacity of unfolding for marginally stable proteins from a single temperature induced protein unfolding profile

    Energy Technology Data Exchange (ETDEWEB)

    Saini, Komal; Ahluwalia, Unnati [Department of Chemistry, Indian Institute of Technology, Delhi 110016 (India); Deep, Shashank, E-mail: sdeep@chemistry.iitd.ac.in [Department of Chemistry, Indian Institute of Technology, Delhi 110016 (India)

    2010-07-10

    A reliable estimation of heat capacity of denaturation ({Delta}C{sub p}) is necessary to calculate the free energy of unfolding of proteins. For marginally stable proteins, such as mutants of a protein or proteins at low pH or under denaturating conditions, the pre-transition region is not fully populated by the native state. Analysis of differential scanning calorimeter (DSC) data under such conditions may not yield a reliable value of {Delta}C{sub p} and other associated thermodynamic parameters of unfolding. Analysis of denaturation profiles of (a) cytochrome c at pH 2.5, 3 and 8 and (b) myoglobin at pH 4, show that an accurate value of {Delta}C{sub p} can be extracted from a single unfolding profile obtained spectroscopically by including low temperature data.

  4. Toward the physical basis of thermophilic proteins: linking of enriched polar interactions and reduced heat capacity of unfolding.

    Science.gov (United States)

    Zhou, Huan-Xiang

    2002-01-01

    The enrichment of salt bridges and hydrogen bonding in thermophilic proteins has long been recognized. Another tendency, featuring lower heat capacity of unfolding (DeltaC(p)) than found in mesophilic proteins, is emerging from the recent literature. Here we present a simple electrostatic model to illustrate that formation of a salt-bridge or hydrogen-bonding network around an ionized group in the folded state leads to increased folding stability and decreased DeltaC(p). We thus suggest that the reduced DeltaC(p) of thermophilic proteins could partly be attributed to enriched polar interactions. A reduced DeltaC(p) might serve as an indicator for the contribution of polar interactions to folding stability. PMID:12496083

  5. Calculation of thermal conductivity, thermal diffusivity and specific heat capacity of sedimentary rocks using petrophysical well logs

    DEFF Research Database (Denmark)

    Fuchs, Sven; Balling, Niels; Förster, Andrea

    2015-01-01

    of 15 major rock-forming minerals and porosities of 0–30 per cent. Petrophysical properties and their well-logging-tool-characteristic readings were assigned to these rock-forming minerals and to pore-filling fluids. Relationships are explored between each thermal property and other petrophysical...... of each property vary depending on the selected well-log combination. Best prediction is in the range of 2–8 per cent for the specific heat capacity, of 5–10 per cent for the thermal conductivity, and of 8–15 for the thermal diffusivity, respectively. Well-log derived thermal conductivity is validated...... by laboratory data measured on cores from deep boreholes of the Danish Basin, the North German Basin, and the Molasse Basin. Additional validation of thermal conductivity was performed by comparing predicted and measured temperature logs. The maximum deviation between these logs is

  6. Heat capacity jumps induced by magnetic field in the Er{sub 2}HoAl{sub 5}O{sub 12} garnet

    Energy Technology Data Exchange (ETDEWEB)

    Shevchenko, E.V. [Centre for Diagnostics of Functional Materials for Medicine, Pharmacology and Nanoelectronics, St. Petersburg State University, St. Petersburg, 198504 (Russian Federation); Charnaya, E.V., E-mail: charnaya@live.com [Physics Department, St. Petersburg State University, St. Petersburg, 198504 (Russian Federation); Lee, M.K. [Department of Physics, National Cheng Kung University, Tainan, 70101 Taiwan (China); NSC Instrument Center at NCKU, Tainan, 70101 Taiwan (China); Chang, L.J. [Department of Physics, National Cheng Kung University, Tainan, 70101 Taiwan (China); Khazanov, E.N.; Taranov, A.V. [Kotel' nikov Institute of Radio Engineering and Electronics RAS, 125009 (Russian Federation); Bugaev, A.S. [Moscow Institute of Physics and Technology, Moscow, 141700 (Russian Federation)

    2017-01-30

    Measurements of the heat capacity were carried out for the mixed Er{sub 2}HoAl{sub 5}O{sub 12} garnet at magnetic fields up to 15 T. The heat capacity variations at low temperatures were dominated by the Schottky anomalies. In addition, anomalous sharp steps in the heat capacity were observed in magnetic fields stronger than 8 T upon cooling as well as upon warming. The temperatures of the steps increased with increasing magnetic field. Jumps found upon cooling and warming were shifted relative to each other showing the thermal hysteresis. The sharp decrease in the heat capacity at low temperatures suggested the blocking of magnetic flips induced by strong enough magnetic fields. - Highlights: • Anomalous steps of the heat capacity were observed in the Er{sub 2}HoAl{sub 5}O{sub 12} garnet. • The steps are induced by magnetic field at low temperatures. • The temperatures of the steps increased with increasing magnetic field. • The steps show a pronounced thermal hysteresis. • The findings suggest the blocking of the magnetic moment flips at field.

  7. Low-temperature heat capacities and standard molar enthalpy of formation of N-methylnorephedrine C211H17NO(s)

    Institute of Scientific and Technical Information of China (English)

    Di You-Ying; Wang Da-Qi; Shi Quan; Tan Zhi-Cheng

    2008-01-01

    This paper reports that low-temperature heat capacities of N-methylnorephedrine C11H17NO(s) have been mea- sured by a precision automated adiabatic calorimeter over the temperature range from T=78 K to T=400 K. A solid to liquid phase transition of the compound was found in the heat capacity curve in the temperature range of T=342- 364 K. The peak temperature, molar enthalpy and entropy of fusion of the substance were determined. The experimental values of the molar heat capacities in the temperature regions of T=78-342 K and T=364-400 K were fitted to two poly- nomial equations of heat capacities with the reduced temperatures by least squares method. The smoothed molar heat capacities and thermodynamic functions of N-methylnorephedrine C11H17NO(s) relative to the standard refer- ence temperature 298.15 K were calculated based on the fitted polynomials and tabulated with an interval of 5 K. The constant-volume energy of combustion of the compound at T=298.15 K was measured by means of an isoperibol preci- sion oxygen-bomb combustion calorimeter. The standard molar enthalpy of combustion of the sample was calculated. The standard molar enthalpy of formation of the compound was determined from the combustion enthalpy and other auxiliary thermodynamic data through a Hess thermochemical cycle.

  8. Group additive values for the gas-phase standard enthalpy of formation, entropy and heat capacity of oxygenates.

    Science.gov (United States)

    Paraskevas, Paschalis D; Sabbe, Maarten K; Reyniers, Marie-Françoise; Papayannakos, Nikos; Marin, Guy B

    2013-11-25

    A complete and consistent set of 60 Benson group additive values (GAVs) for oxygenate molecules and 97 GAVs for oxygenate radicals is provided, which allow to describe their standard enthalpies of formation, entropies and heat capacities. Approximately half of the GAVs for oxygenate molecules and the majority of the GAVs for oxygenate radicals have not been reported before. The values are derived from an extensive and accurate database of thermochemical data obtained by ab initio calculations at the CBS-QB3 level of theory for 202 molecules and 248 radicals. These compounds include saturated and unsaturated, α- and β-branched, mono- and bifunctional oxygenates. Internal rotations were accounted for by using one-dimensional hindered rotor corrections. The accuracy of the database was further improved by adding bond additive corrections to the CBS-QB3 standard enthalpies of formation. Furthermore, 14 corrections for non-nearest-neighbor interactions (NNI) were introduced for molecules and 12 for radicals. The validity of the constructed group additive model was established by comparing the predicted values with both ab initio calculated values and experimental data for oxygenates and oxygenate radicals. The group additive method predicts standard enthalpies of formation, entropies, and heat capacities with chemical accuracy, respectively, within 4 kJ mol(-1) and 4 J mol(-1) K(-1) for both ab initio calculated and experimental values. As an alternative, the hydrogen bond increment (HBI) method developed by Lay et al. (T. H. Lay, J. W. Bozzelli, A. M. Dean, E. R. Ritter, J. Phys. Chem.- 1995, 99, 14514) was used to introduce 77 new HBI structures and to calculate their thermodynamic parameters (Δ(f)H°, S°, C(p)°). The GAVs reported in this work can be reliably used for the prediction of thermochemical data for large oxygenate compounds, combining rapid prediction with wide-ranging application.

  9. Thermodynamics of liquids: standard molar entropies and heat capacities of common solvents from 2PT molecular dynamics.

    Science.gov (United States)

    Pascal, Tod A; Lin, Shiang-Tai; Goddard, William A

    2011-01-07

    We validate here the Two-Phase Thermodynamics (2PT) method for calculating the standard molar entropies and heat capacities of common liquids. In 2PT, the thermodynamics of the system is related to the total density of states (DoS), obtained from the Fourier Transform of the velocity autocorrelation function. For liquids this DoS is partitioned into a diffusional component modeled as diffusion of a hard sphere gas plus a solid component for which the DoS(υ) → 0 as υ→ 0 as for a Debye solid. Thermodynamic observables are obtained by integrating the DoS with the appropriate weighting functions. In the 2PT method, two parameters are extracted from the DoS self-consistently to describe diffusional contributions: the fraction of diffusional modes, f, and DoS(0). This allows 2PT to be applied consistently and without re-parameterization to simulations of arbitrary liquids. We find that the absolute entropy of the liquid can be determined accurately from a single short MD trajectory (20 ps) after the system is equilibrated, making it orders of magnitude more efficient than commonly used perturbation and umbrella sampling methods. Here, we present the predicted standard molar entropies for fifteen common solvents evaluated from molecular dynamics simulations using the AMBER, GAFF, OPLS AA/L and Dreiding II forcefields. Overall, we find that all forcefields lead to good agreement with experimental and previous theoretical values for the entropy and very good agreement in the heat capacities. These results validate 2PT as a robust and efficient method for evaluating the thermodynamics of liquid phase systems. Indeed 2PT might provide a practical scheme to improve the intermolecular terms in forcefields by comparing directly to thermodynamic properties.

  10. Experimental Study of the Isochoric Heat Capacity of Diethyl Ether (DEE) in the Critical and Supercritical Regions

    Science.gov (United States)

    Polikhronidi, N. G.; Abdulagatov, I. M.; Batyrova, R. G.; Stepanov, G. V.; Wu, J. T.; Ustuzhanin, E. E.

    2012-02-01

    Two- and one-phase liquid and vapor isochoric heat capacities ( C V ρ T relationship) of diethyl ether (DEE) in the critical and supercritical regions have been measured with a high-temperature and high-pressure nearly constant-volume adiabatic calorimeter. The measurements were carried out in the temperature range from 347 K to 575 K for 12 liquid and 5 vapor densities from 212.6 kg·m-3 to 534.6 kg·m-3. The expanded uncertainties (coverage factor k = 2, two-standard deviation estimate) for values of the heat capacity were 2% to 3% in the near-critical region, 1.0% to 1.5% for the liquid isochores, and 3% to 4% for the vapor isochores. The uncertainties of density ( ρ) and temperature ( T) measurements were 0.02% and 15 mK, respectively. The values of the internal energy, U( T, V), and second temperature derivative of pressure, (∂2 P/∂ T 2) ρ , were derived using the measured C V data near the critical point. The critical anomaly of the measured C V and derived values of U( T, V) and (∂2 P/∂ T 2) ρ in the critical and supercritical regions were interpreted in terms of the scaling theory of critical phenomena. The asymptotic critical amplitudes {({A_0^+} and {A_0^- )}} of the scaling power laws along the critical isochore for one- and two-phase C V were calculated from the measured values of C V . Experimentally derived values of the critical amplitude ratio for {CV left({A_0^+ /A_0^- = 0.521}right)} are in good agreement with the values predicted by scaling theory. The measured C V data for DEE were analyzed to study the behavior of loci of isothermal and isochoric C V maxima and minima in the critical and supercritical regions.

  11. Zeolite Y adsorbents with high vapor uptake capacity and robust cycling stability for potential applications in advanced adsorption heat pumps

    Energy Technology Data Exchange (ETDEWEB)

    Li, XS; Narayanan, S; Michaelis, VK; Ong, TC; Keeler, EG; Kim, H; Mckay, IS; Griffin, RG; Wang, EN

    2015-01-01

    Modular and compact adsorption heat pumps (AHPs) promise an energy-efficient alternative to conventional vapor compression based heating, ventilation and air conditioning systems. A key element in the advancement of AHPs is the development of adsorbents with high uptake capacity, fast intracrystalline diffusivity and durable hydrothermal stability. Herein, the ion exchange of NaY zeolites with ingoing Mg2+ ions is systematically studied to maximize the ion exchange degree (IED) for improved sorption performance. It is found that beyond an ion exchange threshold of 64.1%, deeper ion exchange does not benefit water uptake capacity or characteristic adsorption energy, but does enhance the vapor diffusivity. In addition to using water as an adsorbate, the uptake properties of Mg, Na-Y zeolites were investigated using 20 wt.% MeOH aqueous solution as a novel anti-freeze adsorbate, revealing that the MeOH additive has an insignificant influence on the overall sorption performance. We also demonstrated that the lab-scale synthetic scalability is robust, and that the tailored zeolites scarcely suffer from hydrothermal stability even after successive 108-fold adsorption/desorption cycles. The samples were analyzed using N-2 sorption, Al-27/Si-29 MAS NMR spectroscopy, ICP-AES, dynamic vapor sorption, SEM, Fick's 2nd law and D-R equation regressions. Among these, close examination of sorption isotherms for H2O and N-2 adsorbates allows us to decouple and extract some insightful information underlying the complex water uptake phenomena. This work shows the promising performance of our modified zeolites that can be integrated into various AHP designs for buildings, electronics, and transportation applications. (C) 2014 Elsevier Inc. All rights reserved.

  12. Zeolite Y Adsorbents with High Vapor Uptake Capacity and Robust Cycling Stability for Potential Applications in Advanced Adsorption Heat Pumps.

    Science.gov (United States)

    Li, Xiansen; Narayanan, Shankar; Michaelis, Vladimir K; Ong, Ta-Chung; Keeler, Eric G; Kim, Hyunho; McKay, Ian S; Griffin, Robert G; Wang, Evelyn N

    2015-01-01

    Modular and compact adsorption heat pumps (AHPs) promise an energy-efficient alternative to conventional vapor compression based heating, ventilation and air conditioning systems. A key element in the advancement of AHPs is the development of adsorbents with high uptake capacity, fast intracrystalline diffusivity and durable hydrothermal stability. Herein, the ion exchange of NaY zeolites with ingoing Mg(2+) ions is systematically studied to maximize the ion exchange degree (IED) for improved sorption performance. It is found that beyond an ion exchange threshold of 64.1%, deeper ion exchange does not benefit water uptake capacity or characteristic adsorption energy, but does enhance the vapor diffusivity. In addition to using water as an adsorbate, the uptake properties of Mg,Na-Y zeolites were investigated using 20 wt.% MeOH aqueous solution as a novel anti-freeze adsorbate, revealing that the MeOH additive has an insignificant influence on the overall sorption performance. We also demonstrated that the labscale synthetic scalability is robust, and that the tailored zeolites scarcely suffer from hydrothermal stability even after successive 108-fold adsorption/desorption cycles. The samples were analyzed using N2 sorption, (27)Al/(29)Si MAS NMR spectroscopy, ICP-AES, dynamic vapor sorption, SEM, Fick's 2(nd) law and D-R equation regressions. Among these, close examination of sorption isotherms for H2O and N2 adsorbates allows us to decouple and extract some insightful information underlying the complex water uptake phenomena. This work shows the promising performance of our modified zeolites that can be integrated into various AHP designs for buildings, electronics, and transportation applications.

  13. Heat capacity studies of single-crystalline CePt{sub 4}In

    Energy Technology Data Exchange (ETDEWEB)

    Pikul, A.P. [Polish Academy of Sciences, Institute of Low Temperature and Structure Research, P Nr 1410, 50-950 Wroclaw 2 (Poland); Max Planck Institute for Chemical Physics of Solids, Noethnitzer Str. 40, 01187 Dresden (Germany)], E-mail: A.Pikul@int.pan.wroc.pl; Kaczorowski, D.; Bukowski, Z. [Polish Academy of Sciences, Institute of Low Temperature and Structure Research, P Nr 1410, 50-950 Wroclaw 2 (Poland); Steglich, F. [Max Planck Institute for Chemical Physics of Solids, Noethnitzer Str. 40, 01187 Dresden (Germany)

    2008-04-01

    Single crystals of CePt{sub 4}In have been studied by means of specific heat measurements performed at low temperatures (down to 60 mK) and in high magnetic fields (up to 9 T). In zero magnetic field the {delta}C/T ratio strongly increases with decreasing temperature down to about 250 mK, where a broad maximum ({approx}1.75Jmol{sup -1}K{sup -2}) occurs. At lower temperatures {delta}C/T slightly diminishes and finally saturates at a value of about 1.7Jmol{sup -1}K{sup -2}. Upon applying magnetic field the maximum in {delta}C/T(T) disappears (it is not visible already in 0.5 T) and the magnitude of {delta}C/T becomes significantly lower. We argue that the observed anomaly in {delta}C(T)/T is due to some magnetic ordering of the cerium magnetic moments, in line with our previous statement on the localized character of the 4f-electrons in this compound.

  14. Assessment of Potential Capacity Increases at Combined Heat and Power Facilities Based on Available Corn Stover and Forest Logging Residues

    Directory of Open Access Journals (Sweden)

    Donald L. Grebner

    2013-08-01

    Full Text Available Combined Heat and Power (CHP production using renewable energy sources is gaining importance because of its flexibility and high-energy efficiency. Biomass materials, such as corn stover and forestry residues, are potential sources for renewable energy for CHP production. In Mississippi, approximately 4.0 MT dry tons of woody biomass is available annually for energy production. In this study, we collected and analyzed 10 years of corn stover data (2001–2010 and three years of forest logging residue data (1995, 1999, and 2002 in each county in Mississippi to determine the potential of these feed stocks for sustainable CHP energy production. We identified six counties, namely Amite, Copiah, Clarke, Wayne, Wilkinson and Rankin, that have forest logging residue feedstocks to sustain a CHP facility with a range of capacity between 8.0 and 9.8 MW. Using corn stover alone, Yazoo and Washington counties can produce 13.4 MW and 13.5 MW of energy, respectively. Considering both feedstocks and based on a conservative amount of 30% available forest logging residue and 33% corn stover, we found that 20 counties have adequate supply for a CHP facility with a capacity of 8.3 MW to 19.6 MW.

  15. Heat capacity of quantum adsorbates: Hydrogen and helium on evaporated gold films

    Energy Technology Data Exchange (ETDEWEB)

    Birmingham, J.T. [Univ. of California, Berkeley, CA (United States). Dept. of Physics]|[Lawrence Berkeley National Lab., CA (United States). Materials Sciences Div.

    1996-06-01

    The author has constructed an apparatus to make specific heat measurements of quantum gases adsorbed on metallic films at temperatures between 0.3 and 4 K. He has used this apparatus to study quench-condensed hydrogen films between 4 and 923 layers thick with J = 1 concentrations between 0.28 and 0.75 deposited on an evaporated gold surface. He has observed that the orientational ordering of the J = 1 molecules depends on the substrate temperature during deposition of the hydrogen film. He has inferred that the density of the films condensed at the lowest temperatures is 25% higher than in bulk H{sub 2} crystals and have observed that the structure of those films is affected by annealing at 3.4 K. The author has measured the J = 1 to J = 0 conversion rate to be comparable to that of the bulk for thick films; however, he found evidence that the gold surface catalyzes conversion in the first two to four layers. He has also used this apparatus to study films of {sup 4}He less than one layer thick adsorbed on an evaporated gold surface. He shows that the phase diagram of the system is similar to that for {sup 4}He/graphite although not as rich in structure, and the phase boundaries occur at different coverages and temperatures. At coverages below about half a layer and at sufficiently high temperatures, the {sup 4}He behaves like a two-dimensional noninteracting Bose gas. At lower temperatures and higher coverages, liquidlike and solidlike behavior is observed. The Appendix shows measurements of the far-infrared absorptivity of the high-{Tc} superconductor La{sub 1.87}Sr{sub 0.13}CuO{sub 4}.

  16. Heat capacities and volumetric changes in the glass transition range: a constitutive approach based on the standard linear solid

    Science.gov (United States)

    Lion, Alexander; Mittermeier, Christoph; Johlitz, Michael

    2017-09-01

    A novel approach to represent the glass transition is proposed. It is based on a physically motivated extension of the linear viscoelastic Poynting-Thomson model. In addition to a temperature-dependent damping element and two linear springs, two thermal strain elements are introduced. In order to take the process dependence of the specific heat into account and to model its characteristic behaviour below and above the glass transition, the Helmholtz free energy contains an additional contribution which depends on the temperature history and on the current temperature. The model describes the process-dependent volumetric and caloric behaviour of glass-forming materials, and defines a functional relationship between pressure, volumetric strain, and temperature. If a model for the isochoric part of the material behaviour is already available, for example a model of finite viscoelasticity, the caloric and volumetric behaviour can be represented with the current approach. The proposed model allows computing the isobaric and isochoric heat capacities in closed form. The difference c_p -c_v is process-dependent and tends towards the classical expression in the glassy and equilibrium ranges. Simulations and theoretical studies demonstrate the physical significance of the model.

  17. Avian thermoregulation in the heat: evaporative cooling capacity in an archetypal desert specialist, Burchell's sandgrouse (Pterocles burchelli).

    Science.gov (United States)

    McKechnie, Andrew E; Smit, Ben; Whitfield, Maxine C; Noakes, Matthew J; Talbot, William A; Garcia, Mateo; Gerson, Alexander R; Wolf, Blair O

    2016-07-15

    Sandgrouse (Pterocliformes) are quintessential examples of avian adaptation to desert environments, but relatively little is known about the limits to their heat tolerance and evaporative cooling capacity. We predicted that evaporative cooling in Burchell's sandgrouse (Pterocles burchelli) is highly efficient and provides the basis for tolerance of very high air temperature (Ta). We measured body temperature (Tb), resting metabolic rate (RMR) and evaporative water loss (EWL) at Ta between 25°C and ∼58°C in birds exposed to successive increments in Ta Normothermic Tb averaged 39.0°C, lower than typical avian values. At Ta>34.5°C, Tb increased linearly to a maximum of 43.6°C at Ta=56°C. The upper critical limit of thermoneutrality (Tuc) was Ta=43.8°C, closely coinciding with the onset of panting and gular flutter. Above the Tuc, RMR increased 2.5-fold to 2.89 W at Ta=56°C, a fractional increase far exceeding that of many other species under comparable conditions. Rates of EWL increased rapidly at Ta>42.9°C to 7.84±0.90 g h(-1) at Ta=56°C, an 11-fold increase above minimal levels. Maximum evaporative cooling efficiency (ratio of evaporative heat loss to metabolic heat production) was 2.03, but could be as high as 2.70 if our assumption that the birds were metabolising lipids is incorrect. Thermoregulation at very high Ta in P. burchelli was characterised by large increases in RMR and EWL, and is much less efficient than in taxa such as columbids and caprimulgids.

  18. Carbohydrate ingestion and pre-cooling improves exercise capacity following soccer-specific intermittent exercise performed in the heat.

    Science.gov (United States)

    Clarke, N D; Maclaren, D P M; Reilly, T; Drust, B

    2011-07-01

    Ingestion of carbohydrate and reducing core body temperature pre-exercise, either separately or combined, may have ergogenic effects during prolonged intermittent exercise in hot conditions. The aim of this investigation was to examine the effect of carbohydrate ingestion and pre-cooling on the physiological responses to soccer-specific intermittent exercise and the impact on subsequent high-intensity exercise performance in the heat. Twelve male soccer players performed a soccer-specific intermittent protocol for 90 min in the heat (30.5°C and 42.2% r.h.) on four occasions. On two occasions, the participants underwent a pre-cooling manoeuvre. During these sessions either a carbohydrate-electrolyte solution (CHOc) or a placebo was consumed at (PLAc). During the remaining sessions either the carbohydrate-electrolyte solution (CHO) or placebo (PLA) was consumed. At 15-min intervals throughout the protocol participants performed a mental concentration test. Following the soccer-specific protocol participants performed a self-chosen pace test and a test of high-intensity exercise capacity. The period of pre-cooling significantly reduced core temperature, muscle temperature and thermal sensation (P < 0.05). Self-chosen pace was greater with CHOc (12.5 ± 0.5 km h(-1)) compared with CHO (11.3 ± 0.4 km h(-1)), PLA (11.3 ± 0.4 km h(-1)) and PLAc (11.6 ± 0.5 km h(-1)) (P < 0.05). High-intensity exercise capacity was improved with CHOc and CHO when compared with PLA (CHOc; 79.8 ± 7 s, CHO; 72.1 ± 5 s, PLAc; 70.1 ± 8 s, PLA; 57.1 ± 5 s; P < 0.05). Mental concentration during the protocol was also enhanced during CHOc compared with PLA (P < 0.05). These results suggest pre-cooling in conjunction with the ingestion of carbohydrate during exercise enhances exercise capacity and helps maintain mental performance during intermittent exercise in hot conditions.

  19. Comparison of the heavy metal biosorption capacity of active, heat-inactivated and NaOH-treated Phanerochaete chrysosporium biosorbents

    Energy Technology Data Exchange (ETDEWEB)

    Guerisik, E.; Bektas, S.; Genc, Oe. [Hacettepe University, Department of Chemistry, 06532 Beytepe, Ankara (Turkey); Arica, M.Y. [Kirikkale University, Department of Biology, Yahsihan, Kirikkale (Turkey)

    2004-02-05

    Three different kinds of Phanerochaete chrysosporium (NaOH-treated, heat-inactivated and active) biosorbent were used for the removal of Cd(II) and Hg(II) ions from aquatic systems. The biosorption of Cd(II) and Hg(II) ions on three different forms of Phanerochaete chrysosporium was studied in aqueous solutions in the concentration range of 50-700 mg/L. Maximum biosorption capacities of NaOH-treated, heat-inactivated and active Phanerochaete chrysosporium biomass were found to be 148.37 mg/g, 78.68 mg/g and 68.56 mg/g for Cd(II) as well as 224.67 mg/g, 122.37 mg/g and 88.26 mg/g for Hg(II), respectively. For Cd(II) and Hg(II) ions, the order of affinity of the biosorbents was arranged as NaOH-treated > heat-inactivated > active. The order of the amount of metal ions adsorbed was established as Hg(II) > Cd(II) on a weight basis, and as Cd(II) > Hg(II) on a molar basis. Biosorption equilibriums were established in about 60 min. The effect of the pH was also investigated, and maximum rates of biosorption of metal ions on the three different forms of Phanerochaete chrysosporium were observed at pH 6.0. The reusability experiments and synthetic wastewater studies were carried out with the most effective form, i.e., the NaOH-treated Phanerochaete chrysosporium biomass. It was observed that the biosorbent could be regenerated using 10 mM HCl solution, with a recovery of up to 98%, and it could be reused in five biosorption-desorption cycles without any considerable loss in biosorption capacity. The alkali-treated Phanerochaete chrysosporium removed 73% of Cd(II) and 81% of Hg(II) ions from synthetic wastewater. (Abstract Copyright [2004], Wiley Periodicals, Inc.)

  20. The ⋋ Structure of the Heat Capacity of an Ideal Gas in the Critical Region of Bose-Einstein Condensation for Various Mesoscopic Traps

    Science.gov (United States)

    Tarasov, S. V.

    2016-11-01

    The features of the ⋋ structure of the heat capacity of an ideal gas of Bose atoms, which is confined in arbitrarily shaped and sized mesoscopic traps, are considered on the basis of a general exact description of the Bose-Einstein condensation. The main attention is paid to the boundarycondition role in the critical region, in which the heat capacity is described by a self-similar function that is sensitive to perturbations of the confining potential and the boundary-condition variation. Various traps, which allow one to experimentally study the influence of the boundary conditions on the shape of the ⋋ structure of the heat capacity and observe variations in other thermodynamic parameters due to the corresponding rearrangement of the self-similar structure of the critical region, are considered.

  1. Schottky contribution to the heat capacity of monazite type (La, Pr)PO4 from low temperature calorimetry and fluorescence measurements

    Science.gov (United States)

    Bauer, J. D.; Hirsch, A.; Bayarjargal, L.; Peters, L.; Roth, G.; Winkler, B.

    2016-06-01

    We show that the combination of fluorescence spectroscopy and low temperature heat capacity measurements of Pr-containing samples in the (La, Pr)PO4 solid solution series can be employed to strongly constrain the Stark energy levels of Pr3+ in monazite type structures. The resulting set of Stark energy levels for the 3H4 ground state of Pr3+ reproduces the low temperature Schottky anomaly of the heat capacity much more accurately than theoretical models published earlier. We also show that there is no excess heat capacity along the binary solid solution with respect to an interpolation between the two end members LaPO4 and PrPO4.

  2. Low-temperature heat capacities and standard molar enthalpy of formation of 4-(2-aminoethyl)-phenol(C8H11NO)

    Institute of Scientific and Technical Information of China (English)

    Di You-Ying; Kong Yu-Xia; Yang Wei-Wei; Tan Zhi-Cheng

    2008-01-01

    This paper reports that low-temperature heat capacities of 4-(2-aminoethyl)-phenol(C8H11NO)are measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 400 K.A polynomial equation of heat capacities as a function of the temperature was fitted by the least square method.Based on the fitted polynomial,the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15 K were calculated and tabulated at the interval of 5 K.The energy equivalent,gcalor,of the oxygen-bomb The constant-volume energy of combustion of the compound at T=298.15 K was measured by a precision oxygen-bomb combustion and other thermodynamic principles.Finally,the standard molar enthalpy of formation of the compound

  3. Negatively charged residues of the segment linking the enzyme and cytolysin moieties restrict the membrane-permeabilizing capacity of adenylate cyclase toxin

    Science.gov (United States)

    Masin, Jiri; Osickova, Adriana; Sukova, Anna; Fiser, Radovan; Halada, Petr; Bumba, Ladislav; Linhartova, Irena; Osicka, Radim; Sebo, Peter

    2016-01-01

    The whooping cough agent, Bordetella pertussis, secretes an adenylate cyclase toxin-hemolysin (CyaA) that plays a crucial role in host respiratory tract colonization. CyaA targets CR3-expressing cells and disrupts their bactericidal functions by delivering into their cytosol an adenylate cyclase enzyme that converts intracellular ATP to cAMP. In parallel, the hydrophobic domain of CyaA forms cation-selective pores that permeabilize cell membrane. The invasive AC and pore-forming domains of CyaA are linked by a segment that is unique in the RTX cytolysin family. We used mass spectrometry and circular dichroism to show that the linker segment forms α-helical structures that penetrate into lipid bilayer. Replacement of the positively charged arginine residues, proposed to be involved in target membrane destabilization by the linker segment, reduced the capacity of the toxin to translocate the AC domain across cell membrane. Substitutions of negatively charged residues then revealed that two clusters of negative charges within the linker segment control the size and the propensity of CyaA pore formation, thereby restricting the cell-permeabilizing capacity of CyaA. The ‘AC to Hly-linking segment’ thus appears to account for the smaller size and modest cell-permeabilizing capacity of CyaA pores, as compared to typical RTX hemolysins. PMID:27581058

  4. TLR4-mediated podosome loss discriminates gram-negative from gram-positive bacteria in their capacity to induce dendritic cell migration and maturation.

    Science.gov (United States)

    van Helden, Suzanne F G; van den Dries, Koen; Oud, Machteld M; Raymakers, Reinier A P; Netea, Mihai G; van Leeuwen, Frank N; Figdor, Carl G

    2010-02-01

    Chronic infections are caused by microorganisms that display effective immune evasion mechanisms. Dendritic cell (DC)-dependent T cell-mediated adaptive immunity is one of the mechanisms that have evolved to prevent the occurrence of chronic bacterial infections. In turn, bacterial pathogens have developed strategies to evade immune recognition. In this study, we show that gram-negative and gram-positive bacteria differ in their ability to activate DCs and that gram-negative bacteria are far more effective inducers of DC maturation. Moreover, we observed that only gram-negative bacteria can induce loss of adhesive podosome structures in DCs, a response necessary for the induction of effective DC migration. We demonstrate that the ability of gram-negative bacteria to trigger podosome turnover and induce DC migration reflects their capacity to selectively activate TLR4. Examining mice defective in TLR4 signaling, we show that this DC maturation and migration are mainly Toll/IL-1 receptor domain-containing adaptor-inducing IFNbeta-dependent. Furthermore, we show that these processes depend on the production of PGs by these DCs, suggesting a direct link between TLR4-mediated signaling and arachidonic metabolism. These findings demonstrate that gram-positive and gram-negative bacteria profoundly differ in their capacity to activate DCs. We propose that this inability of gram-positive bacteria to induce DC maturation and migration is part of the armamentarium necessary for avoiding the induction of an effective cellular immune response and may explain the frequent involvement of these pathogens in chronic infections.

  5. Recent progress of high-power negative ion beam development for fusion plasma heating

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, Kazuhiro; Akino, Noboru; Aoyagi, Tetsuo [Japan Atomic Energy Research Inst., Naka, Ibaraki (Japan). Naka Fusion Research Establishment] [and others

    1997-03-01

    A negative-ion-based neutral beam injector (N-NBI) has been constructed for JT-60U. The N-NBI is designed to inject 500 keV, 10 MW neutral beams using two ion sources, each producing a 500 keV, 22 A D{sup -} ion beam. Beam acceleration test started in July, 1995 using one ion source. In the preliminary experiment, D{sup -} ion beam of 13.5 A has been successfully accelerated with an energy of 400 keV (5.4 MW) for 0.12 s at an operating pressure of 0.22 Pa. This is the highest D{sup -} beam current and power in the world. Co-extracted electron current was effectively suppressed to the ratio of Ie/I{sub D}- <1. The highest energy beam of 460 keV, 2.4 A, 0.44 s has also been obtained. Neutral beam injection starts in March, 1996 using two ion sources. To realize 1 MeV class NBI system for ITER (International Thermonuclear Experimental Reactor), demonstration of ampere class negative ion beam acceleration up to 1 MeV is an important mile stone. To achieve the mile stone, a high energy test facility called MeV Test Facility (MTF) was constructed. The system consists of a 1 MV, 1 A acceleration power supply and a 100 kW power supply system for negative ion production. Up to now, an H{sup -} ion beam was accelerated up to the energy of 805 keV with an acceleration drain current of 150 mA for 1 s in a five stage electrostatic multi-aperture accelerator. (author)

  6. Dietary antioxidants at supranutritional doses improve oxidative status and reduce the negative effects of heat stress in sheep.

    Science.gov (United States)

    Chauhan, S S; Celi, P; Leury, B J; Clarke, I J; Dunshea, F R

    2014-08-01

    The present study was undertaken to investigate the impact of heat (thermal) stress and dietary antioxidant supplementation on the oxidative and physiological status of sheep. Twenty-four Merino × Poll Dorset crossbred ewes were housed in 1 of 2 climatic chambers (thermoneutral or heat stress) and offered either a control (10 IU vitamin E/kg DM and 0.24 mg Se/kg DM) or high antioxidant (100 IU vitamin E/kg DM and 1.20 mg Se/kg DM) diet. The sheep were exposed to 2 thermal (temperature) treatments (thermoneutral [TN]: 18-21°C and 26-30% relative humidity; and heat stress [HS]: 28-40°C and 40-50% relative humidity) for 2 wk in a single reversal design. After 1 wk of dietary treatment, animals in 1 chamber were subjected to HS for 1 wk, with the temperature being increased to 40°C between 0900 and 1700 h and then maintained at 28°C overnight. Those sheep in the TN group were maintained at 18 to 21°C. Physiological parameters were recorded 4 times a day (0900, 1300, 1700, and 2100 h) and blood samples were collected on d 1 and 7 of heat treatment. Plasma samples and red blood cell lysates were assayed for oxidative stress biomarkers. The thermal treatments were then reversed and the above measures repeated. All measured physiological parameters were elevated (P antioxidants as indicated by a diet × temperature × time interaction (P = 0.010). There was 13% decline (P = 0.014) in feed intake of the unsupplemented animals during HS whereas the same was maintained in sheep supplemented with high doses of antioxidants. Plasma reactive oxygen metabolites concentrations were reduced (114 vs. 85 units/dL; P antioxidant potential tended to be increased (3,688 vs. 3,985 μmol/L; P = 0.070) in heat stressed sheep supplemented with antioxidants. The oxidative stress index was 30% lower (P antioxidant supplemented heat stressed sheep as compared to their unsupplemented counterparts. It was concluded that heat stress negatively affects the oxidative status of sheep along

  7. Ozone generation by negative corona discharge: the effect of Joule heating

    Science.gov (United States)

    Yanallah, K.; Pontiga, F.; Fernández-Rueda, A.; Castellanos, A.; Belasri, A.

    2008-10-01

    Ozone generation in pure oxygen using a wire-to-cylinder corona discharge reactor is experimentally and numerically investigated. Ozone concentration is determined by means of direct UV spectroscopy and the effects of Joule heating and ozone decomposition on the electrodes are analysed for different discharge gaps. The numerical model combines the physical processes in the corona discharge with the chemistry of ozone formation and destruction. The chemical kinetics model and the electrical model are coupled through Poisson's equation, and the current-voltage (CV) characteristic measured in experiments is used as input data to the numerical simulation. The numerical model is able to predict the radial distributions of electrons, ions, atoms and molecules for each applied voltage of the CV characteristic. In particular, the evolution of ozone density inside the discharge cell has been investigated as a function of current intensity and applied voltage.

  8. Ozone generation by negative corona discharge: the effect of Joule heating

    Energy Technology Data Exchange (ETDEWEB)

    Yanallah, K; Castellanos, A [Departamento de Electronica y Electromagnetismo, Universidad de Sevilla (Spain); Pontiga, F; Fernandez-Rueda, A [Departamento de Fisica Aplicada II, Universidad de Sevilla (Spain); Belasri, A [Laboratoire de Physique des Plasmas, des Materiaux Conducteur et Leurs Applications, Universite d' Oran (Algeria)

    2008-10-07

    Ozone generation in pure oxygen using a wire-to-cylinder corona discharge reactor is experimentally and numerically investigated. Ozone concentration is determined by means of direct UV spectroscopy and the effects of Joule heating and ozone decomposition on the electrodes are analysed for different discharge gaps. The numerical model combines the physical processes in the corona discharge with the chemistry of ozone formation and destruction. The chemical kinetics model and the electrical model are coupled through Poisson's equation, and the current-voltage (CV) characteristic measured in experiments is used as input data to the numerical simulation. The numerical model is able to predict the radial distributions of electrons, ions, atoms and molecules for each applied voltage of the CV characteristic. In particular, the evolution of ozone density inside the discharge cell has been investigated as a function of current intensity and applied voltage.

  9. Extending the hydrophobic cavity of β-cyclodextrin results in more negative heat capacity changes but reduced binding affinities

    DEFF Research Database (Denmark)

    Schönbeck, Christian; Holm, René; Westh, Peter;

    2014-01-01

    . Calorimetric titrations in a broad temperature range and molecular dynamics simulations confirm previous speculations that the HP-chains cause an increase in dehydrated nonpolar surface area upon formation of the complexes. This additional burial of nonpolar surface area, 12–16 Å2 per HP-chain according...... CD (but depend on the type of bile salt). Interestingly, these convergence temperatures are close to what is observed for unfolding of proteins and may be a common feature of hydrophobic dehydration....

  10. Heat stress evaluation of two-layer chemical demilitarization ensembles with a full face negative pressure respirator.

    Science.gov (United States)

    Fletcher, Oclla Michele; Guerrina, Ryan; Ashley, Candi D; Bernard, Thomas E

    2014-01-01

    The purpose of this study was to examine the heat stress effects of three protective clothing ensembles: (1) protective apron over cloth coveralls including full face negative pressure respirator (APRON); (2) the apron over cloth coveralls with respirator plus protective pants (APRON+PANTS); and (3) protective coveralls over cloth coveralls with respirator (PROTECTIVE COVERALLS). In addition, there was a no-respirator ensemble (PROTECTIVE COVERALLS-noR), and WORK CLOTHES as a reference ensemble. Four acclimatized male participants completed a full set of five trials, and two of the participants repeated the full set. The progressive heat stress protocol was used to find the critical WBGT (WBGTcrit) and apparent total evaporative resistance (Re,T,a) at the upper limit of thermal equilibrium. The results (WBGTcrit [°C-WBGT] and Re,T,a [kPa m(2) W(-1)]) were WORK CLOTHES (35.5, 0.0115), APRON (31.6, 0.0179), APRON+PANTS (27.7, 0.0244), PROTECTIVE COVERALLS (25.9, 0.0290), and PROTECTIVE COVERALLS-noR (26.2, 0.0296). There were significant differences among the ensembles. Supporting previous studies, there was little evidence to suggest that the respirator contributed to heat stress.

  11. Temperature Increase Negatively Affects the Fatty Acid Bioconversion Capacity of Rainbow Trout (Oncorhynchus mykiss) Fed a Linseed Oil-Based Diet.

    Science.gov (United States)

    Mellery, Julie; Geay, Florian; Tocher, Douglas R; Kestemont, Patrick; Debier, Cathy; Rollin, Xavier; Larondelle, Yvan

    2016-01-01

    Aquaculture is meant to provide fish rich in omega-3 long chain polyunsaturated fatty acids (n-3 LC-PUFA). This objective must be reached despite (1) the necessity to replace the finite and limited fish oil in feed production and (2) the increased temperature of the supply water induced by the global warming. The objective of the present paper was to determine to what extent increased water temperature influences the fatty acid bioconversion capacity of rainbow trout (Oncorhynchus mykiss) fed a plant-derived diet. Fish were fed two diets formulated with fish oil (FO) or linseed oil (LO) as only added lipid source at the optimal water temperature of 15°C or at the increased water temperature of 19°C for 60 days. We observed that a temperature increase close to the upper limit of the species temperature tolerance range negatively affected the feed efficiency of rainbow trout fed LO despite a higher feed intake. The negative impact of increased water temperature on fatty acid bioconversion capacity appeared also to be quite clear considering the reduced expression of fatty acid desaturase 2 in liver and intestine and the reduced Δ6 desaturase enzymatic activity in intestinal microsomes. The present results also highlighted a negative impact of increased temperature on the apparent in vivo enzymatic activity of Δ5 and Δ6 desaturases of fish fed LO. Interestingly, this last parameter appeared less affected than those mentioned above. This study highlights that the increased temperature that rainbow trout may face due to global warming could reduce their fatty acid bioconversion capacity. The unavoidable replacement of finite fish oil by more sustainable, readily available and economically viable alternative lipid sources in aquaculture feeds should take this undeniable environmental issue on aquaculture productivity into account.

  12. Imbalance between oxygen photoreduction and antioxidant capacities in Symbiodinium cells exposed to combined heat and high light stress

    Science.gov (United States)

    Roberty, S.; Fransolet, D.; Cardol, P.; Plumier, J.-C.; Franck, F.

    2015-12-01

    During the last decades, coral reefs have been affected by several large-scale bleaching events, and such phenomena are expected to increase in frequency and severity in the future, thus compromising their survival. High sea surface temperature accompanied by high levels of solar irradiance has been found to be responsible for the induction of oxidative stress ultimately ending with the disruption of the symbiosis between cnidarians and Symbiodinium. For two decades, many studies have pointed to the water-water cycle (WWC) as being one of the primary mediators of this phenomenon, but the impacts of environmental stress on the O2 reduction by PSI and the associated reactive oxygen species (ROS)-detoxifying enzymes remain to be determined. In this study, we analyzed the impacts of acute thermal and light stress on the WWC in the model Symbiodinium strain A1. We observed that the high light treatment at 26 °C resulted in the up-regulation of superoxide dismutase, ascorbate peroxidase, and glutathione reductase activities and an increased production of ROS with no significant change in O2-dependent electron transport. Under high light and at 33 °C, O2-dependent electron transport was significantly increased relative to total electron transport. This increase was concomitant with a twofold increase in ROS generation compared with the treatment at 26 °C, while enzymes involved in the WWC were largely inactivated. These data show for the first time that combined heat and light stress inactivate antioxidant capacities of the WWC and suggests that its photoprotective functions are overwhelmed under these conditions. This study also indicates that cnidarians may be more prone to bleach if they harbor Symbiodinium cells having a highly active Mehler-type electron transport, unless they are able to quickly up-regulate their antioxidant capacities.

  13. Low-Temperature Heat Capacities and Thermodynamic Properties of Octahydrated Barium Dihydroxide,Ba(OH)2·8H2O(s)

    Institute of Scientific and Technical Information of China (English)

    DI,You-Ying; TAN,Zhi-Cheng; SUN,Li-Xian

    2007-01-01

    Low-temperature heat capacities of octahydrated barium dihydroxide, Ba(OH)2·8H2O(s), were measured by a precision automated adiabatic calorimeter in the temperature range from T=78 to 370 K. An obvious endothermic process took place in the temperature range of 345-356 K. The peak in the heat capacity curve was correspondent to the sum of both the fusion and the first thermal decomposition or dehydration. The experimental molar heat capacities in the temperature ranges of 78-345 K and 356-369 K were fitted to two polynomials. The peak temperature, molar enthalpy and entropy of the phase change have been determined to be (355.007±0.076) K,(73.506±0.011) kJ·mol-1 and (207.140±0.074) J·K-1·mol-1, respectively, by three series of repeated heat capacity measurements in the temperature region of 298-370 K. The thermodynamic functions, (HT-H298.15 K)and (ST-S298.15 K), of the compound have been calculated by the numerical integral of the two heat-capacity polynomials. In addition, DSC and TG-DTG techniques were used for the further study of thermal behavior of the compound. The latent heat of the phase change became into a value larger than that of the normal compound because the melting process of the compound must be accompanied by the thermal decomposition or dehydration of 7H2O.

  14. Low Temperature Heat Capacities and Thermodynamic Properties of Zinc L-Threonate Zn(C4H7O5)2(s)by Adiabatic Calorimetry

    Institute of Scientific and Technical Information of China (English)

    CHEN Jing-tao; DI You-ying; TAN Zhi-cheng; CHEN San-ping; GAO Sheng-li

    2008-01-01

    Low-temperature heat capacities of the solid compound Zn(C4H7O5)2(s) were measured in a temperature range from 78 to 374 K,with an automated adiabatic calorimeter.A solid-to-solid phase transition occurred in the temperature range of 295-322 K.The peak temperature,the enthalpy,and entropy of the phase transition were experimental values of the molar heat capacities in the temperature regions of 78-295 K and 322-374 K were fitted to two polynomial equations of heat capacities(Cp,m) with reduced temperatures(X) and [X=f(T)],with the help of the least squares method,respectively.The smoothed molar heat capacities and thermodynamic functions of the compound,relative to that of the standard reference temperature 293.15 K,were calculated on the basis of the fitted polynomials and tabulated with an interval of 5 K.In addition,the possible mechanism of thermal decomposition of the compound was inferred by the result of TG-DTG analysis.

  15. Isobaric Heat Capacities of Micelle Formation by 1-Methyl-4-n-dodecylpyridinium Iodide in Aqueous Solution; Effects of Added Urea

    NARCIS (Netherlands)

    Posthumus, Willem; Engberts, Jan B.F.N.; Bijma, Koos; Blandamer, Michael J.

    1997-01-01

    Over the temperature range from 303 to 333 K, the enthalpy of micelle formation by 1-methyl-4-n-dodecylpyridinium iodide in aqueous solution is exothermic, characterised by an isobaric heat capacity of micelle formation equal to -439 ± 10 J K-1 mol-1. At 303 K, the critical micellar concentration (2

  16. Molar heat capacities of La2Mo2O9 and La1.9Sr0.1MO2O9-δ

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The molar heat capacities of La2Mo2O9 and La1.9Sr0.1Mo2O9-δ were obtained using the differential scanning calorimetry (DSC) technique in a temperature range from 298 to 1473 K. The DSC curve of La2Mo2O9 showed an endothermal peak around 834 K corresponding to a first-order monoclinic-cubic phase transition, and the enthalpy change accompanying this phase transition is 5.99 kJ/mol. No evident endothermal peak existed in the DSC curve of La1.9Sr0.1Mo2O94, but a broad thermal anomaly existed in its heat capacity curve at around 832 K. In addition, the heat capacity values of La2Mo2O9 and La1.9Sr0.1Mo2O9-δ began to decrease at 1196 and 1330 K, respectively. The non-transitional heat capacity values of La2Mo2O9 and La1.9Sr0.1Mo2O9-δ were formulated using multiple regression analysis in two temperature ranges.

  17. Excess heat capacity of the (Li1−xCax)F1+x liquid solution determined by differential scanning calorimetry and drop calorimetry

    NARCIS (Netherlands)

    Capelli, E.; Benes, O.; Konings, R.J.M.

    2014-01-01

    The work presents the measured heat capacity of the (Li1−xCax)F1+x liquid solution. Four samples with different compositions have been prepared and measured using a Differential Scanning Calorimeter. Since this technique was newly adopted for measuring encapsulated fluoride samples, some

  18. Introduction of Differential Scanning Calorimetry in a General Chemistry Laboratory Course: Determination of Heat Capacity of Metals and Demonstration of Law of Dulong and Petit

    Science.gov (United States)

    D'Amelia, Ronald P.; Stracuzzi, Vincent; Nirode, William F.

    2008-01-01

    Today's general chemistry students are introduced to many of the principles and concepts of thermodynamics. In first-year general chemistry undergraduate courses, thermodynamic properties such as heat capacity are frequently discussed. Classical calorimetric methods of analysis and thermal equilibrium experiments are used to determine heat…

  19. Introduction of Differential Scanning Calorimetry in a General Chemistry Laboratory Course: Determination of Heat Capacity of Metals and Demonstration of Law of Dulong and Petit

    Science.gov (United States)

    D'Amelia, Ronald P.; Stracuzzi, Vincent; Nirode, William F.

    2008-01-01

    Today's general chemistry students are introduced to many of the principles and concepts of thermodynamics. In first-year general chemistry undergraduate courses, thermodynamic properties such as heat capacity are frequently discussed. Classical calorimetric methods of analysis and thermal equilibrium experiments are used to determine heat…

  20. High-temperature heat capacity of YBiGeO5 and GdBiGeO5 in the range 373-1000 K

    Science.gov (United States)

    Denisova, L. T.; Belousova, N. V.; Galiakhmetova, N. A.; Denisov, V. M.

    2017-05-01

    The oxide YBiGeO5 and GdBiGeO5 compounds have been synthesized by solid-phase synthesis. The high-temperature heat capacity has been measured using differential scanning calorimetry in the range 373-1000 K. The results were used to calculate the thermodynamic properties (the change in the enthalpy and entropy).

  1. Determining the Optimal Capacities of Renewable-Energy-Based Energy Conversion Systems for Meeting the Demands of Low-Energy District Heating, Electricity, and District Cooling

    DEFF Research Database (Denmark)

    Tol, Hakan; Svendsen, Svend; Dincer, Ibrahim

    2015-01-01

    This chapter presents a method for determining the optimal capacity of a renewable-energy-based energy conversion system for meeting the energy requirements of a given district as considered on a monthly basis, with use of a low-energy district heating system operating at a low temperature, as lo...

  2. Temperature dependence of the heat capacities in the solid state of 18 mono-, di-, and poly-saccharides

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez-Segura, Gerardo O. [Laboratorio de Biofisicoquimica, Departamento de Fisicoquimica, Facultad de Quimica, Universidad Nacional Autonoma de Mexico, Mexico D.F. 04510 (Mexico); Campos, Myriam [Departamento de Quimica, Centro de Investigacion y Estudios Avanzados del I.P.N., Apdo. Postal 14-740, Mexico D.F. 07000 (Mexico); Costas, Miguel [Laboratorio de Biofisicoquimica, Departamento de Fisicoquimica, Facultad de Quimica, Universidad Nacional Autonoma de Mexico, Mexico D.F. 04510 (Mexico)], E-mail: costasmi@servidor.unam.mx; Torres, Luis A. [Departamento de Quimica, Centro de Investigacion y Estudios Avanzados del I.P.N., Apdo. Postal 14-740, Mexico D.F. 07000 (Mexico)], E-mail: ltorres@cinvestav.mx

    2009-01-15

    The temperature dependence of the heat capacities in solid state C{sub p}(T) of 18 mono-, di-, and poly-saccharides has been determined using a power-compensation differential scanning calorimeter. The saccharides were {alpha}-D-xylose, D-ribose, 2-deoxy-D-ribose, methyl-{beta}-D-ribose, {alpha}-D-glucose, 2-deoxy-D-glucose, {alpha}-D-mannose, {beta}-D-fructose, {alpha}-D-galactose, methyl-{alpha}-D-glucose, sucrose, maltose monohydrate, {alpha}-lactose monohydrate, cellobiose, maltotriose, N-acetyl-D-glucosamine, {alpha}-cyclodextrin, and {beta}-cyclodextrin. The measurements were carried out at atmospheric pressure and from T = (288.15 to 358.15) K for 15 saccharides and from T = (288.15 to 328.15) K for D-ribose, 2-deoxy-D-ribose, and methyl-{beta}-D-ribose. The present results are compared against literature values both at single temperatures, where most of the data are available, and throughout a range of temperatures, i.e., for C{sub p}(T). The predictions of a recently published correlation for organic solids are briefly discussed. By grouping saccharides in subsets, our present results can be used to compare amongst saccharide isomers and to assess the effect of different chemical groups and molecular size.

  3. Anomalous influence of spin fluctuations on the heat capacity and entropy in a strongly correlated helical ferromagnet MnSi

    Science.gov (United States)

    Povzner, A. A.; Volkov, A. G.; Nogovitsyna, T. A.

    2017-02-01

    The influence of spin fluctuations on the thermodynamic properties of a helical ferromagnet MnSi has been investigated in the framework of the Hubbard model with the electronic spectrum determined from the first-principles LDA + U + SO calculation, which is extended taking into account the Hund coupling and the Dzyaloshinskii-Moriya antisymmetric exchange. It has been shown that the ground state of the magnetic material is characterized by large zero-point fluctuations, which disappear at the temperature T* (< T c is the temperature of the magnetic phase transition). In this case, the entropy abruptly increases, and a lambdashaped anomaly appears in the temperature dependence of the heat capacity at constant volume ( C V ( T)). In the temperature range T* < T < T c , thermal fluctuations lead to the disappearance of the inhomogeneous magnetization. The competition between the increase in the entropy due to paramagnon excitations and its decrease as a result of the reduction in the amplitude of local magnetic moments, under the conditions of strong Hund exchange, is responsible for in the appearance of a "shoulder" in the dependence C V ( T)).

  4. Combined Heat and Power (CHP Allocation and Capacity Determination According to Fuzzy Bus Thermal Coefficient and Nodal Pricing Method using Cooperative Game Theory

    Directory of Open Access Journals (Sweden)

    Mohamad Hasan Moradi

    2014-12-01

    Full Text Available In this paper a hybrid and practical method is presented to allocate and determine combined heat and power capacity (CHP generator at a bus. This method consists of two stages. First, the suitable buses for CHP installation will be found by the bus thermal coefficient . This coefficient indicates the possibility of the heat selling around each bus and will be calculated by using the Fuzzy method. Next, for each of the appropriate buses, considering the obtained heat capacity and electrical power ratio to the heat of the CHPs in the market, several CHPs are recommended. Second, on the one hand, the improvement of the technical criteria after the CHPs installation is derived by using the nodal pricing methods as the financial benefits of the distribution companies and on the other hand, the investors’ financial benefits from the sold heat output of the CHPs is determined. Finally, using the Game Theory and considering the distribution companies and investors as the players, the suitable location and capacity for CHP installation based on the set Game strategy is obtained. The proposed method is implemented to a sample distribution feeder in the Hamadan city and the results are shown.

  5. The Effect of Moisture Content and Temperature on the Specific Heat Capacity of Nut and Kernel of Two Iranian Pistachio Varieties

    Directory of Open Access Journals (Sweden)

    A.R Salari Kia

    2014-04-01

    Full Text Available Pistachio has a special ranking among Iranian agricultural products. Iran is known as the largest producer and exporter of pistachio in the world. Agricultural products are imposed under different thermal treatments during storage and processing. Designing all these processes requires thermal parameters of the products such as specific heat capacity. Regarding the importance of pistachio processing as an exportable product, in this study the specific heat capacity of nut and kernel of two varieties of Iranian pistachio (Kalle-Ghochi and Badami were investigated at four levels of moisture content (initial moisture content (5%, 15%, 25% and 40% w.b. and three levels of temperature (40, 50 and 60°C. In both varieties, the differences between the data were significant at the 1% of probability; however, the effect of moisture content was greater than that of temperature. The results indicated that the specific heat capacity of both nuts and kernels increase logarithmically with increase of moisture content and also increase linearly with increase of temperature. This parameter has altered for nut and kernel of Kalle-Ghochi and Badami varieties within the range of 1.039-2.936 kJ kg-1 K-1, 1.236-3.320 kJ kg-1 K-1, 0.887-2.773 kJ kg-1 K-1 and 0.811-2.914 kJ kg-1 K-1, respectively. Moreover, for any given level of temperature, the specific heat capacity of kernels was higher than that of nuts. Finally, regression models with high R2 values were developed to predict the specific heat capacity of pistachio varieties as a function of moisture content and temperature

  6. Mechanochemical effect in the iron(III) spin crossover complex [Fe(3-MeO-salenEt2]PF6 as studied by heat capacity calorimetry.

    Science.gov (United States)

    Sorai, Michio; Burriel, Ramón; Westrum, Edgar F; Hendrickson, David N

    2008-04-10

    Magnetic and thermal properties of the iron(III) spin crossover complex [Fe(3MeO-salenEt)(2)]PF(6) are very sensitive to mechanochemical perturbations. Heat capacities for unperturbed and differently perturbed samples were precisely determined by adiabatic calorimetry at temperatures in the 10-300 K range. The unperturbed compound shows a cooperative spin crossover transition at 162.31 K, presenting a hysteresis of 2.8 K. The anomalous enthalpy and entropy contents of the transition were evaluated to be Delta(trs)H = 5.94 kJ mol(-1) and Delta(trs)S = 36.7 J K(-1) mol(-1), respectively. By mechanochemical treatments, (1) the phase transition temperature was lowered by 1.14 K, (2) the enthalpy and entropy gains at the phase transition due to the spin crossover phenomenon were diminished to Delta(trs)H = 4.94 kJ mol(-1) and Delta(trs)S = 31.1 J K(-1) mol(-1), and (3) the lattice heat capacities were larger than those of the unperturbed sample over the whole temperature range. In spite of different mechanical perturbations (grinding with a mortar and pestle and grinding in a ball-mill), two sets of heat capacity measurements provided basically the same results. The mechanochemical perturbation exerts its effect more strongly on the low-spin state than on the high-spin state. It shows a substantial increase of the number of iron(III) ions in the high-spin state below the transition temperature. The heat capacities of the diamagnetic cobalt(III) analogue [Co(3MeO-salenEt)(2)]PF(6) also were measured. The lattice heat capacity of the iron compounds has been estimated from either the measurements on the cobalt complex using a corresponding states law or the effective frequency distribution method. These estimations have been used for the evaluation of the transition anomaly.

  7. 温度对发射药比热容影响规律研究%Temperature Dependence of the Specific Heat Capacity of Propellant

    Institute of Scientific and Technical Information of China (English)

    胡哲; 江劲勇; 路桂娥; 葛强; 王韶光; 贾昊楠

    2015-01-01

    目的 确定发射药比热容参数.方法 选用发射药9/7单基药、SF-3和GATo推进剂为研究对象,利用热重分析仪研究发射药的热分解特性,确定实验温度区间.利用差示扫描量热仪采用动态温度调制法对温度区间内发射药比热容进行测量,对发射药比热容变化规律进行分析,并计算热力学函数.结果 发射药的比热容随温度升高而逐渐变大.结论 在进行发射药热模拟计算时,从安全角度出发,应该使用常温下发射药比热容.%Objective To determine the specific heat capacity parameter of propellant. Methods 9/7 single-base propellant,SF-3 and GATo were selected as the research objects. The thermal decomposition characteristics of propellant were studied using thermogravimetric analyzer, and the experimental temperature zone of propellant was determined. The specific heat capacity of propellant in the temperature range was measured by the method of dynamic temperature modulation using DSC, and the changing law was analyzed for the specific heat capacity of propellant. Thermodynamic functions of propellant were calculated. Results The results showed that the specific heat capacity gradually increased with the rising temperature. Conclusion In the process of thermal simulation of propellant, from the safety point of view, the specific heat capacity of propellant at room temperature should be used.

  8. 热解过程中生物质半焦比热容的测定%Determination of specific heat capacity of biomass char during pyrolysis

    Institute of Scientific and Technical Information of China (English)

    陈群; 庞任重; 陈熙; 杨锐明; 禚玉群; 陈昌和

    2014-01-01

    The specific heat capacities of chars during primary pyrolysis of biomass with different conversion and the heat capacities of virgin biomass were determined.The ratio method was employed to measure the specific heat capacities of two biomass samples and their pyrolyzed chars through thermogravimetry and differential scanning calorimetry ( TG-DSC).A mathematical model was developed to calculate values of specific heat of chars.The results show that the specific heat capacitei s of the two biomass samples and their derived chars increase linearly within 60~200℃.The values oft he specific heat capacity fo the chars are lower than those fo the virgin biomass samples.The specific heat of chars decreases as the extent of pyrolysis increases.The calculated specific heat capacities from the developed mathematical model are quite close to those me asured by TG-DSC analyses eb twe n 150~200℃.%采用热重-差示量热扫描法( TG-DSC)测量了生物质和一次热解焦炭及不同转化率下半焦的比热容,建立了计算半焦比热容的数学模型并与实验测量结果进行了对比。结果表明,生物质样品和热解焦炭的比热容在60~200℃随温度升高而线性增大。生物质焦炭的比热容低于生物质样品的比热容,从60℃时的1.2 J/(g· K)增大到200℃附近的1.8~2.0 J/(g· K)。生物质半焦比热容随热解转化率的提高而降低。由半焦比热容数学模型计算得到的结果在接近150~200℃时与实验测定的半焦比热容数值基本一致。

  9. Pre-anthesis high temperature acclimation alleviates the negative effects of post-anthesis heat stress on stem stored carbohydrates remobilization and grain starch accumulation in wheat

    DEFF Research Database (Denmark)

    Wang, Xiao; Cai, Jian; Liu, Fulai

    2012-01-01

    The potential role of pre-anthesis high temperature acclimation in alleviating the negative effects of post-anthesis heat stress on stem stored carbohydrate remobilization and grain starch accumulation in wheat was investigated. The treatments included no heat-stress (CC), heat stress at pre......-anthesis only (HC), heat at post-anthesis only (CH), and heat stress at both stages (HH). Post-anthesis heat stress decreased grain starch content, reduced the content of fructans and depressed activities of related synthesis enzymes of sucrose:sucrose fructosyltransferase and fructan......:fructan fructosyltransferase. Interestingly, HH plants had significantly higher grain yield than the CH plants. In addition, post-anthesis high temperature lowered grain starch content and increased percentages of volume, number and surface area of B-type starch granules in CH and HH than in CC treatment. However, HH plants...

  10. Comprehensive assessment of geographic variation in heat tolerance and hardening capacity in populations of Drosophila melanogaster from eastern Australia

    DEFF Research Database (Denmark)

    Sgro, Carla M.; Overgaard, Johannes; Kristensen, Torsten Nygård

    2010-01-01

    We examined latitudinal variation in adult and larval heat tolerance in Drosophila melanogaster from eastern Australia. Adults were assessed using static and ramping assays. Basal and hardened static heat knockdown time showed significant linear clines; heat tolerance increased towards the tropics...

  11. Effect of pH Changes on Antioxidant Capacity and the Content of Betalain Pigments During the Heating of a Solution of Red Beet Betalains

    Directory of Open Access Journals (Sweden)

    Mikołajczyk-Bator Katarzyna

    2017-06-01

    Full Text Available Red beets and their products are mainly consumed after processing. In this study, the effect of pH on changes in antioxidant capacity (AC and the content of betalain pigments were analysed during the heating of a betalain preparation solution. With pH ranging from 4 to 9 during the heat-treatment, the content of red pigments decreased depending on the pH level of the sample. The losses of red pigments in the investigated betalain preparation solution increased along with rising pH levels of the heated solution. The greatest losses were recorded at pH of 9.0. An opposite correlation was observed for yellow pigments. The content of yellow pigments in the heated betalain preparation solution was increasing along with increasing pH. The most pronounced increase in the content of yellow pigments was found at pH of 6.5 and 7.0. At the same time, the heated betalain preparation solution was shown to exhibit a higher antioxidant capacity at pH of 6.0 (14.9 μmol Trolox/mL than at pH of 4.0 (12.6 μmol Trolox/mL. It was observed that the increase in the antioxidant capacity in heated betalain preparation solutions with pH in the 6.0–6.5 range occurred as a result of increased concentrations of neobetanin, assessed by HPLC, within the pH range from 5.0 to 6.5.

  12. Non-isothermal Decomposition Kinetics,Specific Heat Capacity and Adiabatic Time-to-explosion of 1-Amino-1-hydrazino-2,2-dinitroethylene (AHDNE)

    Institute of Scientific and Technical Information of China (English)

    XU,Kangzhen; ZHAO,Fengqi; SONG,Jirong; CHANG,Chunran; LI,Meng; WANG,Yaoyu; HU,Rongzu

    2009-01-01

    The thermal behavior and non-isothermal kinetics of the exothermic decomposition reaction of 1-amino-1-hydrazino-2,2-dinitroethylene (AHDNE) were studied with DSC and TG/DTG methods.The kinetic equation obtained is dα/dT=1019.29(1-α)exp(-1.88×104/T)/β.The critical temperature of thermal explosion is 98.16 ℃.The specific heat capacity of AHDNE was determined,and the standard molar specific heat capacity is 211.86 J·mol-1·K-1 at 298.15 K.The adiabatic time-to-explosion of AHDNE was also calculated to be 59.21 s.AHDNE is unstable and has much lower thermostability than 1,1-diamino-2,2-dinitroethylene (FOX-7).

  13. Thermal expansion, heat capacity and Grüneisen parameter of iridium phosphide Ir2P from quasi-harmonic Debye model

    Science.gov (United States)

    Liu, Z. J.; Song, T.; Sun, X. W.; Ma, Q.; Wang, T.; Guo, Y.

    2017-03-01

    Thermal expansion coefficient, heat capacity, and Grüneisen parameter of iridium phosphide Ir2P are reported by means of quasi-harmonic Debye model for the first time in the current study. This model combines with first-principles calculations within generalized gradient approximation using pseudopotentials and a plane-wave basis in the framework of density functional theory, and it takes into account the phononic effects within the quasi-harmonic approximation. The Debye temperature as a function of volume, the Grüneisen parameter, thermal expansion coefficient, constant-volume and constant-pressure heat capacities, and entropy on the temperature T are also successfully obtained. All the thermodynamic properties of Ir2P in the whole pressure range from 0 to 100 GPa and temperature range from 0 to 3000 K are summarized and discussed in detail.

  14. Temperature dependent electron-phonon coupling and heat capacity in thin slabs of topological insulator Bi2Te3 as pertinent to the thermal spike model

    Science.gov (United States)

    Patra, Paramita; Srivastava, S. K.

    2016-07-01

    Electron-phonon coupling strength and electronic heat capacity are essential ingredients of the widely accepted thermal spike model of swift heavy ion matter interaction. The concept, although applicable very well in metals, loses its validity in materials with a band gap, wherein it is customary to take the two quantities merely as adjustable parameters to fit the experimental results. Topological insulators, like Bi2Te3, are quite interesting in this regard because they are also metallic albeit near the surface. In this work, we compute by first-principles the electron density of states of ∼16 Å thick Bi2Te3 slabs of different orientations and demonstrate an unusually high metallicity for the [0 0 1] slab. The density of states is then used to calculate the electron-phonon coupling strength and electronic heat capacity as a function of electron temperature. Strongly electron temperature dependent but weak electron-phonon coupling has been observed, along with systematic deviations of the electronic heat capacity from the linear free-electron metal values.

  15. Cu/Nb-Ti MRI wires with improved stability by incorporating filaments of large heat capacity substance PrB6

    Science.gov (United States)

    Keilin, V. E.; Kovalev, I. A.; Kruglov, S. L.; Sсherbakov, V. I.; Shutova, D. I.; Vorobjeva, A. E.; Salunin, N. I.; Potanina, L. V.

    2015-03-01

    In this paper we report our recent research on thermal stabilization of low-temperature superconducting magnets by means of large heat capacity substances (LHCS). Two samples (lengths ˜100 m) of NbTi composite wires with additional internal filaments made from intermetallic compound PrB6 (5.9-7.3 vol.%) were produced and tested. The design of the wires was similar to that of the conventional MRI sc wires, except for their smaller diameter (0.835 mm instead of 1.345 mm). Our final goal was the investigation of the possibility to minimize (or even eliminate completely) the necessity of MRI magnets training before their commissioning. The comparative stability measurements showed a twofold increase of the minimum quench energies (MQEs) of the doped wires against short heat disturbances. The magnetic field corresponding to the first flux jump increased by 50%. In MQE tests, the PrB6 heat capacity was fully utilized over the course of a 1 ms heat pulse. In the thermomagnetic stability measurements, the efficiency of LHCS doping was about 75% due to the fast evolution of the flux jumps.

  16. Thermodynamic Properties at Saturation Derived from Experimental Two-Phase Isochoric Heat Capacity of 1-Hexyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide

    Science.gov (United States)

    Polikhronidi, Nikolai G.; Batyrova, Rabiyat G.; Abdulagatov, Ilmutdin M.; Magee, Joseph W.; Wu, Jiangtao

    2016-11-01

    New measurements are reported for the isochoric heat capacity of the ionic liquid substance 1-hexyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([C6mim][NTf2]). These measurements extend the ranges of our earlier study (Polikhronidi et al. in Phys Chem Liq 52:657, 2014) by 5 % of the compressed liquid density and by 75 K. An adiabatic calorimeter was used to measure one-phase (C_{V1}) liquid and two-phase (C_{V2}) liquid + vapor isochoric heat capacities, densities (ρ _s), and phase-transition temperatures (T_s) of the ionic liquid (IL) substance. The combined expanded uncertainty of the density ρ and isochoric heat capacity C_V measurements at the 95 % confidence level with a coverage factor of k = 2 is estimated to be 0.15 % and 3 %, respectively. Measurements are concentrated in the immediate vicinity of the liquid + vapor phase-transition curve, in order to closely observe phase transitions. The present measurements and those of our earlier study are analyzed together and are presented in terms of thermodynamic properties (T_s, ρ _s, C_{V1} and C_{V2}) evaluated at saturation and in terms of key-derived thermodynamic properties C_P, C_S, W_S^' }}, K_{TS}^' }}, ( {partial P/partial T} ) V^' }, and ( {partial V/partial T} ) _{P}^' }) on the liquid + vapor phase-transition curve. A thermodynamic relation by Yang and Yang is used to confirm the internal consistency of measured two-phase heat capacities C_{V2} , which are observed to fall perfectly on a line as a function of specific volume at a constant temperature. The observed linear behavior is exploited to evaluate contributions to the quantity C_{V2} = f(V, T) from chemical potential C_{{Vμ}} =-Td^{{2}}μ /dT2 and from vapor pressure C_{VP} =VTd2PS /dT2. The physical nature and specific details of the temperature and specific volume dependence of the two-phase isochoric heat capacity and some features of the other derived thermodynamic properties of IL at liquid saturation curve are considered

  17. Enthalpy and heat capacity changes for formation of an oligomeric DNA duplex: interpretation in terms of coupled processes of formation and association of single-stranded helices.

    Science.gov (United States)

    Holbrook, J A; Capp, M W; Saecker, R M; Record, M T

    1999-06-29

    The thermodynamics of self-assembly of a 14 base pair DNA double helix from complementary strands have been investigated by titration (ITC) and differential scanning (DSC) calorimetry, in conjunction with van't Hoff analysis of UV thermal scans of individual strands. These studies demonstrate that thermodynamic characterization of the temperature-dependent contributions of coupled conformational equilibria in the individual "denatured" strands and in the duplex is essential to understand the origins of duplex stability and to derive stability prediction schemes of general applicability. ITC studies of strand association at 293 K and 120 mM Na+ yield an enthalpy change of -73 +/- 2 kcal (mol of duplex)-1. ITC studies between 282 and 312 K at 20, 50, and 120 mM Na+ show that the enthalpy of duplex formation is only weakly salt concentration-dependent but is very strongly temperature-dependent, decreasing approximately linearly with increasing temperature with a heat capacity change (282-312 K) of -1.3 +/- 0.1 kcal K-1 (mol of duplex)-1. From DSC denaturation studies in 120 mM Na+, we obtain an enthalpy of duplex formation of -120 +/- 5 kcal (mol of duplex)-1 and an estimate of the corresponding heat capacity change of -0.8 +/- 0.4 kcal K-1 (mol of duplex)-1 at the Tm of 339 K. van't Hoff analysis of UV thermal scans on the individual strands indicates that single helix formation is noncooperative with a temperature-independent enthalpy change of -5.5 +/- 0.5 kcal at 120 mM Na+. From these observed enthalpy and heat capacity changes, we obtain the corresponding thermodynamic quantities for two fundamental processes: (i) formation of single helices from disordered strands, involving only intrastrand (vertical) interactions between neighboring bases; and (ii) formation of double helices by association (docking) of single helical strands, involving interstrand (horizontal and vertical) interactions. At 293 K and 120 mM Na+, we calculate that the enthalpy change for

  18. Data use investigations for applications Explorer Mission A (Heat Capacity Mapping Mission): HCMM's role in studies of the urban heat island, Great Lakes thermal phenomena and radiometric calibration of satellite data. [Buffalo, Syracuse, and Rochester New York and Lake Ontario

    Science.gov (United States)

    Schott, J. R. (Principal Investigator); Schimminger, E. W.

    1981-01-01

    The utility of data from NASA'a heat capacity mapping mission satellite for studies of the urban heat island, thermal phenomena in large lakes and radiometric calibration of satellite sensors was assessed. The data were found to be of significant value in all cases. Using HCMM data, the existence and microstructure of the heat island can be observed and associated with land cover within the urban complex. The formation and development of the thermal bar in the Great Lakes can be observed and quantitatively mapped using HCMM data. In addition, the thermal patterns observed can be associated with water quality variations observed both from other remote sensing platforms and in situ. The imaging radiometer on-board the HCMM satellite is shown to be calibratible to within about 1.1 C of actual surface temperatures. These findings, as well as the analytical procedures used in studying the HCMM data, are included.

  19. Heat capacity, entropy of Ln2(MoO4)3 (Ln = La, Sm, and Gd), and the high-temperature enthalpy of Ln2(MoO4)3 (Ln = Eu, Dy, and Ho)

    Science.gov (United States)

    Lazarev, V. M.; Suponitskiy, Y. L.; Liashenko, S. E.

    2016-05-01

    The low-temperature heat capacity of Ln2(MoO4)3 (Ln = La, Sm, and Gd) is investigated by means of adiabatic calorimetry within the range of 60-300 K. The temperature dependences of the heat capacity are found and the values of the standard entropy are calculated, based on extrapolations to 0 K. Characteristic temperatures for molybdates are determined from the results of IR spectroscopic studies. The high-temperature enthalpy of Ln2(MoO4)3 (Ln = Eu, Dy, and Ho) is measured via high-temperature microcalorimetry, and the temperature dependence of heat capacity is calculated in the range of 298-1000 K. Since samarium and gadolinium molybdates are of the same structural type as terbium molybdate, we can estimate the anomaly of the heat capacity in the low-temperature region using the data for terbium molybdate and find the entropy of samarium and gadolinium molybdates.

  20. Looking for footprint of bulk metallic glass in electronic and phonon heat capacities of Cu55Hf45-xTix alloys

    Science.gov (United States)

    Remenyi, G.; Biljaković, K.; Starešinić, D.; Dominko, D.; Ristić, R.; Babić, E.; Figueroa, I. A.; Davies, H. A.

    2014-04-01

    We report on the heat capacity investigation of Cu55Hf45-xTix metallic glasses. The most appropriate procedure to estimate low temperature electronic and phonon contributions has been determined. Both contributions exhibit monotonous Ti concentration dependence, demonstrating that there is no relation of either the electron density of states at the Fermi level or the Debye temperature to the increased glass forming ability in the Ti concentration range x = 15-30. The thermodynamic parameters (e.g., reduced glass temperature) remain better indicators in assessing the best composition for bulk metallic glass formation.

  1. Thermolysis, nonisothermal decomposition kinetics, specific heat capacity and adiabatic time-to-explosion of [Cu(NH3)4](DNANT)2 (DNANT= dinitroacetonitrile).

    Science.gov (United States)

    Zhang, Yu; Wu, Hao; Xu, Kangzhen; Zhang, Wantao; Ren, Zhaoyu; Song, Jirong; Zhao, Fengqi

    2014-02-20

    A new energetic copper complex of dinitroacetonitrile (DNANT), [Cu(NH3)4](DNANT)2, was first synthesized through an unexpected reaction. The thermal decomposition of [Cu(NH3)4](DNANT)2 was studied with DSC and TG/DTG methods. The gas products were analyzed through a TG-FTIR-MS method. The nonisothermal kinetic equation of the exothermic process is dα/dT = 10(10.92)/β4(1 - α)[-ln(1 - α)](3/4) exp(-1.298 × 10(5)/RT). The self-accelerating decomposition temperature and critical temperature of thermal explosion are 217.9 and 221.0 °C. The specific heat capacity of [Cu(NH3)4](DNANT)2 was determined with a micro-DSC method, and the molar heat capacity is 512.6 J mol(-1) K(-1) at 25 °C. Adiabatic time-to-explosion of Cu(NH3)4(DNANT)2 was also calculated to be about 137 s.

  2. Heat capacity and magnetic properties of fluoride CsFe{sup 2+}Fe{sup 3+}F{sub 6} with defect pyrochlore structure

    Energy Technology Data Exchange (ETDEWEB)

    Gorev, M.V., E-mail: gorev@iph.krasn.ru [Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, 660036 Krasnoyarsk (Russian Federation); Institute of Engineering Physics and Radio Electronics, Siberian State University, 660074 Krasnoyarsk (Russian Federation); Flerov, I.N. [Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, 660036 Krasnoyarsk (Russian Federation); Institute of Engineering Physics and Radio Electronics, Siberian State University, 660074 Krasnoyarsk (Russian Federation); Tressaud, A. [Institut de Chimie de la Matière Condensée, ICMCB-CNRS, Université Bordeaux, 33608 Pessac Cedex (France); Bogdanov, E.V. [Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, 660036 Krasnoyarsk (Russian Federation); Astafijev Krasnoyarsk State Pedagogical University, 660049 Krasnoyarsk (Russian Federation); Kartashev, A.V. [Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, 660036 Krasnoyarsk (Russian Federation); Krasnoyarsk State Agrarian University, 660049 Krasnoyarsk (Russian Federation); Bayukov, O.A. [Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, 660036 Krasnoyarsk (Russian Federation); Eremin, E.V. [Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, 660036 Krasnoyarsk (Russian Federation); Institute of Engineering Physics and Radio Electronics, Siberian State University, 660074 Krasnoyarsk (Russian Federation); Krylov, A.S. [Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, 660036 Krasnoyarsk (Russian Federation)

    2016-05-15

    Heat capacity, Mössbauer and Raman spectra as well as magnetic properties of fluoride CsFe{sub 2}F{sub 6} with defect pyrochlore structure were studied. In addition to recently found above room temperature three successive structural transformations Pnma-Imma-I4{sub 1}amd-Fd-3m, phase transition of antiferromagnetic nature with the 13.7 K Neel temperature and a broad heat capacity anomaly with a maximum at about 30 K were observed. The room temperature symmetry Pnma is unchanged at least down to 7 K. Simple model of indirect bond used to estimate the exchange interactions and to propose a magnetic structure model. - Graphical abstract: The ordered arrangement of Fe{sup 2+} and Fe{sup 3+} ions in high-spin states as well as antiferromagnetic phase transition followed by significant magnetic frustrations were found in pyrocholore-related CsFe{sup 2+}Fe{sup 3+}F{sub 6}. A magnetic structure was proposed using a simple model of indirect bonds. - Highlights: • The Pnma structure in pyrocholore CsFe{sub 2}F{sub 6} is stable down to helium temperature. • Mössbauer spectra confirmed the ordering of Fe{sup 2+} and Fe{sup 3+} ions. • Antiferromagnetic transformation and significant magnetic frustrations are found. • Experimental magnetic entropy agrees with entropy for Fe ions in high-spin state. • Superexchange interactions were calculated and a magnetic structure was proposed.

  3. Temperature-dependent determination of electron heat capacity and electron-phonon coupling factor for Fe0.72Cr0.18Ni0.1

    Science.gov (United States)

    Winter, Jan; Sotrop, Jürgen; Borek, Stephan; Huber, Heinz P.; Minár, Jan

    2016-04-01

    A theoretical approach using ab initio calculations was applied to study the interaction of an ultrashort laser pulse with the metal alloy Fe0.72Cr0.18Ni0.1 (AISI 304). The electronic structure was simulated by taking into account the chemical and magnetic disorder of the alloy by the coherent potential approximation implemented in a fully relativistic Korringa-Kohn-Rostoker formalism in the framework of spin density functional theory. A self-consistent calculation of the electronic structure using the Matsubara technique in the paramagnetic state of Fe0.72Cr0.18Ni0.1 for finite temperatures was applied. Utilizing these predictions we determined the electron heat capacity and the electron-phonon coupling factor of Fe0.72Cr0.18Ni0.1 in dependence on the electron temperature for two-temperature model applications. Compared with pure Fe a maximum deviation of 5% for the electron heat capacity and 25% for the electron-phonon coupling factor was found.

  4. Heat capacity measurement and EXAFS study of (U{sub 0.85}Mg{sub 0.15})O{sub 2{minus}x} for x = 0 and 0.1

    Energy Technology Data Exchange (ETDEWEB)

    Atita, Y; Matsui, T. [Nagoya Univ. (Japan); Ohno, H. [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Office of Synchrotron Radiation Facility Project; Kobayashi, K. [National Lab. for High Energy Physics, Tsukuba, Ibaraki (Japan). Photon Factory

    1997-03-01

    Heat capacities and electrical conductivities of (U{sub 0.85}Mg{sub 0.15})O{sub 2{minus}x} (x = 0 and 0.1) were measured simultaneously by means of a direct heating pulse calorimeter (DHPC) in the temperature range from 300 to 1500 K. Anomalous increases in the heat capacity curves of (U{sub 0.85}Mg{sub 0.15})O{sub 2{minus}x} (x = 0 and 0.1) were observed above about 800 and 1150 K, respectively. The values for the enthalpy of oxygen Frenkel defect formation were calculated from the excess heat capacity and were found to be similar to those for UO{sub 2} doped with rare earth elements. On the other hand, no anomaly was seen in the electrical conductivity curve around the onset temperature of the anomalous increase in the heat capacity. It was, therefore, concluded that the excess heat capacity originates from the predominant contribution of the formation of Frenkel pair-like defects of oxygen. An extended X-ray absorption fine structure (EXAFS) experiment shows a different environment of oxygen around uranium and magnesium, and this should be a cause of the onset temperature difference.

  5. Numerical study of plasma generation process and internal antenna heat loadings in J-PARC RF negative ion source

    Energy Technology Data Exchange (ETDEWEB)

    Shibata, T., E-mail: shibat@post.j-parc.jp; Ueno, A.; Oguri, H.; Ohkoshi, K.; Ikegami, K.; Takagi, A.; Asano, H.; Naito, F. [J-PARC Center, Tokai-mura, Naka-gun, Ibaraki-ken 319-1195 (Japan); Nishida, K.; Mochizuki, S.; Hatayama, A. [Keio University, Hiyoshi, Kohoku-ku, Yokohama-shi, Kanagawa-ken 223-8522 (Japan); Mattei, S.; Lettry, J. [European Organization for Nuclear Research (CERN), 1211 Geneva 23 (Switzerland)

    2016-02-15

    A numerical model of plasma transport and electromagnetic field in the J-PARC (Japan Proton Accelerator Research Complex) radio frequency ion source has been developed to understand the relation between antenna coil heat loadings and plasma production/transport processes. From the calculation, the local plasma density increase is observed in the region close to the antenna coil. Electrons are magnetized by the magnetic field line with absolute magnetic flux density 30–120 Gauss which leads to high local ionization rate. The results suggest that modification of magnetic configuration can be made to reduce plasma heat flux onto the antenna.

  6. submitter Numerical study of plasma generation process and internal antenna heat loadings in J-PARC RF negative ion source

    CERN Document Server

    Shibata, T; Mochizuki, S; Mattei, S; Lettry, J; Hatayama, A; Ueno, A; Oguri, H; Ohkoshi, K; Ikegami, K; Takagi, A; Asano, H; Naito, F

    2016-01-01

    A numerical model of plasma transport and electromagnetic field in the J-PARC (Japan Proton Accelerator Research Complex) radio frequency ion source has been developed to understand the relation between antenna coil heat loadings and plasma production/transport processes. From the calculation, the local plasma density increase is observed in the region close to the antenna coil. Electrons are magnetized by the magnetic field line with absolute magnetic flux density 30-120 Gauss which leads to high local ionization rate. The results suggest that modification of magnetic configuration can be made to reduce plasma heat flux onto the antenna.

  7. Performance of cooling capacity adjustment in gas engine-driven heat pump%燃气机热泵容量调节制冷性能试验

    Institute of Scientific and Technical Information of China (English)

    王明涛; 刘焕卫; 张百浩

    2015-01-01

    Gas engine driven heat pump (GEHP), which mainly consists of a gas engine, an evaporator, a condenser and an expansion valve, can make full use of the waste heat from cylinder jacket and exhaust gas and achieve a higher primary energy ratio (PER) than other forms of heating/cooling systems, and therefore has been considered as a preferable choice in the air-conditioning scheme. Compared with the electric-driven heat pump (EHP), the GEHP has two distinguished advantages: 1) the ability to recover the gas engine waste heat from cylinder jacket and exhaust gas; 2) easy modulation of gas engine speed to meet the cooling loads. In the present article, a novel GEHP which could independently provide heating, cooling and hot water for the buildings was presented. The capacity adjustment and stable operation of GEHP could be achieved by controlling engine rotary speed. The goals of engine rotary speed control were to match the rotary speed and cooling/heating capacity, and keep robust to disturbance. In order to control engine rotary speed effectively, the engine rotary speed expert proportion-integration-differentiation (PID) controller was designed according to the engine rotary speed control knowledge base and the controlling rules in this study. Meanwhile, the energy analysis of GEHP was presented as well as the GEHP operating parameters (such as ambient air temperature, evaporator water flow and engine rotary speed). The engine rotary expert PID controller was applied to the engine rotary speed control in a GEHP system experimentally under different conditions (modulation on cooling loads and anti-disturbance), and the cooling performance characteristics of GEHP were investigated experimentally over a wide range of engine rotary speed (1 400-2 200 r/min). The performance of GEHP was characterized by cooling capacity, waste heat amount recovered, coefficient of performance (COP) and PER. The relationships between engine rotary speed and cooling capacity, waste heat

  8. Determination of heat-set gelation capacity of a quinoa protein isolate (Chenopodium quinoa) by dynamic oscillatory rheological analysis.

    Science.gov (United States)

    Kaspchak, Elaine; Oliveira, Marco Aurelio Schüler de; Simas, Fernanda Fogagnoli; Franco, Célia Regina Cavicchiolo; Silveira, Joana Léa Meira; Mafra, Marcos Rogério; Igarashi-Mafra, Luciana

    2017-10-01

    This work aimed to study the influence of pH (3.5 and 7.0) and CaCl2 and MgCl2 addition on heat-set gelation of a quinoa protein isolate at 10% and 15% (w/w). The protein isolate obtained was composed mainly of 11S globulin as was observed by electrophoresis and mass spectrometry analysis. Heat-set gelation occurred at both pH values studied. Nevertheless, the gels formed at pH 3.5 were more viscoelastic and denser than those formed at pH 7.0, that was coarser and presented syneresis. The CaCl2 and MgCl2 addition increased the gel strength during rheological analysis at pH 3.5, possibly due to the formation of fiber-like connections in the gel network. At pH 7.0, the divalent salts resulted in weaker gels formed by agglomerates, suggesting a neutralization of the protein surface charges. The differences in quinoa protein gelation were attributed to solubility, and the flexibility of proteins secondary structure at the pH studied. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Low-Temperature Heat Capacity and Thermal Decomposition of Crystalline[Ho(Thr)(H2O)5]Cl3

    Institute of Scientific and Technical Information of China (English)

    蓝孝征; 谭志诚; 刘北平; 南照东; 孙立贤; 徐芬

    2003-01-01

    Rare earth elements have been widely used in many areas. Rare earth complex bearing an amino acid was synthesized to study the influence and the long-term effect of rare earth elements on environment and human beings,because amino acid is the basic unit of the living things. Previous work on these kinds of comidex is focused on synthesis and characterization of them. But thermodynamic data have seldom been reported. Here we present the thermod~nRmle study of [ Ho (Thr)(H20 )5]Cl3. The heat capecity of Holmium complex with threonine,[Ho(Thr)(H2O)5]Cl3,was measured with an automatic adiabatic calorimeter in the temperature range from 79K to 330K and no thermal anomaly was found in this range,Thermodynamic functions relative to standard state 298.15K were derived from the heat capactiy data.Thermal decomposition behavior of the complex in nitrogen atmosphere in the range from 300K to 900K was studied by thermogravimetric(TG) technique and a possible decompostion mechanism was proposed according to the TG-DTG results.

  10. 开式湖水源热泵系统的水体热承载能力计算方法%CALCULATION MEETHOD OF THE HEAT CARRING CAPACITY OF WATER IN LAKE-WATER SOURCE HEAT PUMP SYSTEMS

    Institute of Scientific and Technical Information of China (English)

    王勇; 韩传璞

    2012-01-01

    在流体运动基本方程N-S方程的基础上,利用水温、质量和能量方程,建立了湖水源热泵系统利用水体水温变化的二维数学模型,并耦合求解得到水体水温的数值解.以夏季取水温度限值为依据,求解出在供冷期间不同负荷特征以及不同初始水温下水体能够承受的最大排热量.通过回归方法,得到水体热承载能力的检验方程.根据工程案例测试数据分析,该计算方法下的理论结果和实际测试结果较吻合,能够应用于湖水源热泵系统的可行性研究.%Based on N-S equations, dynamic two-dimensional model of lake water used for lake-water source heat pump system was built using temperature equation mass equation and energy equation. And arithmetic solution of wate temperature was attained by coupled solution. Based on limit temperature of water abstraction in summer, the largest quantity of heat the water can carried was obtained in different load and different start water temperature in heating period. Through regression, heat carrying capacity of water was obtained. Based on test data analysis, engineering project, theoretical result and test result in this computational method were coincide well,and this computational method can be used in feasibility study for lake-water source heat pump system.

  11. Specific features of low-frequency vibrational dynamics and low-temperature heat capacity of double-walled carbon nanotubes

    Science.gov (United States)

    Avramenko, M. V.; Roshal, S. B.

    2016-05-01

    A continuous model has been constructed for low-frequency dynamics of a double-walled carbon nanotube. The formation of the low-frequency part of the phonon spectrum of a double-walled nanotube from phonon spectra of its constituent single-walled nanotubes has been considered in the framework of the proposed approach. The influence of the environment on the phonon spectrum of a single double-walled carbon nanotube has been analyzed. A combined method has been proposed for estimating the coefficients of the van der Waals interaction between the walls of the nanotube from the spectroscopic data and the known values of the elastic moduli of graphite. The low-temperature specific heat has been calculated for doublewalled carbon nanotubes, which in the field of applicability of the model ( T nanotubes forming it.

  12. Effect of nanoparticles on heat capacity of nanofluids based on molten salts as PCM for thermal energy storage.

    Science.gov (United States)

    Chieruzzi, Manila; Cerritelli, Gian F; Miliozzi, Adio; Kenny, José M

    2013-10-29

    In this study, different nanofluids with phase change behavior were developed by mixing a molten salt base fluid (selected as phase change material) with nanoparticles using the direct-synthesis method. The thermal properties of the nanofluids obtained were investigated. These nanofluids can be used in concentrating solar plants with a reduction of storage material if an improvement in the specific heat is achieved. The base salt mixture was a NaNO3-KNO3 (60:40 ratio) binary salt. The nanoparticles used were silica (SiO2), alumina (Al2O3), titania (TiO2), and a mix of silica-alumina (SiO2-Al2O3). Three weight fractions were evaluated: 0.5, 1.0, and 1.5 wt.%. Each nanofluid was prepared in water solution, sonicated, and evaporated. Measurements on thermophysical properties were performed by differential scanning calorimetry analysis and the dispersion of the nanoparticles was analyzed by scanning electron microscopy (SEM). The results obtained show that the addition of 1.0 wt.% of nanoparticles to the base salt increases the specific heat of 15% to 57% in the solid phase and of 1% to 22% in the liquid phase. In particular, this research shows that the addition of silica-alumina nanoparticles has a significant potential for enhancing the thermal storage characteristics of the NaNO3-KNO3 binary salt. These results deviated from the predictions of the theoretical model used. SEM suggests a greater interaction between these nanoparticles and the salt.

  13. Effect of nanoparticles on heat capacity of nanofluids based on molten salts as PCM for thermal energy storage

    Science.gov (United States)

    Chieruzzi, Manila; Cerritelli, Gian F.; Miliozzi, Adio; Kenny, José M.

    2013-10-01

    In this study, different nanofluids with phase change behavior were developed by mixing a molten salt base fluid (selected as phase change material) with nanoparticles using the direct-synthesis method. The thermal properties of the nanofluids obtained were investigated. These nanofluids can be used in concentrating solar plants with a reduction of storage material if an improvement in the specific heat is achieved. The base salt mixture was a NaNO3-KNO3 (60:40 ratio) binary salt. The nanoparticles used were silica (SiO2), alumina (Al2O3), titania (TiO2), and a mix of silica-alumina (SiO2-Al2O3). Three weight fractions were evaluated: 0.5, 1.0, and 1.5 wt.%. Each nanofluid was prepared in water solution, sonicated, and evaporated. Measurements on thermophysical properties were performed by differential scanning calorimetry analysis and the dispersion of the nanoparticles was analyzed by scanning electron microscopy (SEM). The results obtained show that the addition of 1.0 wt.% of nanoparticles to the base salt increases the specific heat of 15% to 57% in the solid phase and of 1% to 22% in the liquid phase. In particular, this research shows that the addition of silica-alumina nanoparticles has a significant potential for enhancing the thermal storage characteristics of the NaNO3-KNO3 binary salt. These results deviated from the predictions of the theoretical model used. SEM suggests a greater interaction between these nanoparticles and the salt.

  14. 碳酸镁和碳酸锌的比热容及分解吸热效应研究%On the specific heat capacity and decomposition heat of the basic magnesium carbonate and zinc carbonate hydroxide

    Institute of Scientific and Technical Information of China (English)

    高云升; 杜志明; 王春迎

    2013-01-01

    This paper aims to bring about our experimental results on the study of the specific heat capacity and decomposition heat of the basic magnesium carbonate and zinc carbonate hydroxide. As is known, most of carbonates are prone to decompose by absorbing heat, which accounts for their being used as a coolant. Basic magnesium carbonate and zinc carbonate hydroxide have good environmental performance and chemical stability, which accounts for their popular use in the condensed aerosol fire extinguishing device as a coolant for high-temperature gases. Thermal analysis experiments tell us that the specific heat capacities of basic magnesium carbonate and zinc carbonate hydroxide are 1.249 - 2.099 J/(g·℃) and 1.022 - 1.420 J/(g·℃) respectively in the range of 45 - 150℃ . We have also found the relation curve about the specific heat capacity and the temperature of the two compounds. And, next, we have worked out the decomposition reaction of heat absorption capacities of basic magnesium carbonate and zinc carbonate hydroxide to the differential scanning calorimetry curve s peak area by means of the integral method. The experimental facts state that the basic magnesium carbonate has two endothermic peaks: one is near the 250 ℃ , whose decomposition caloric receptivity is about 266.91 J/g, whereas the other is near the 400 ℃ , whose decomposition caloric receptivity is about 1 512.27 J/g. However, zinc carbonate hydroxide has only one endothermic peak, which is bound to be reached near the 250℃ . Its decomposition caloric receptivity is about 283.91 J/g. Hence, the cooling effect of the basic magnesium carbonate has been found preliminary through testing and measurement, which accounts for its application as a coolant in the condensed aerosol fire extinguishing device. The above results prove that basic magnesium carbonate can serve as an excellent chemical coolant suitable for such a device.%碱式碳酸镁和碱式碳酸锌常用作热气溶胶灭火装置

  15. Ion beam transport: modelling and experimental measurements on a large negative ion source in view of the ITER heating neutral beam

    Science.gov (United States)

    Veltri, P.; Sartori, E.; Agostinetti, P.; Aprile, D.; Brombin, M.; Chitarin, G.; Fonnesu, N.; Ikeda, K.; Kisaki, M.; Nakano, H.; Pimazzoni, A.; Tsumori, K.; Serianni, G.

    2017-01-01

    Neutral beam injectors are among the most important methods of plasma heating in magnetic confinement fusion devices. The propagation of the negative ions, prior to their conversion into neutrals, is of fundamental importance in determining the properties of the beam, such as its aiming and focusing at long-distances, so as to deposit the beam power in the proper position inside the confined plasma, as well as to avoid interaction with the material surfaces along the beam path. The final design of the ITER Heating Neutral Beam prototype has been completed at Consorzio RFX (Padova, Italy), in the framework of a close collaboration with European, Japanese and Indian fusion research institutes. The physical and technical rationales on which the design is based were essentially driven by numerical modelling of the relevant physical processes, and the same models and codes will be useful to design the DEMO neutral beam injector in the near future. This contribution presents a benchmark study of the codes used for this purpose, by comparing their results against the measures performed in an existing large-power device, hosted at the National Institute for Fusion Science, Japan. In particular, the negative ion formation and acceleration are investigated. A satisfactory agreement was found between codes and experiments, leading to an improved understanding of beam transport dynamics. The interpretation of the discrepancies identified in previous works, possibly related to the non-uniformity of the extracted negative ion current, is also presented.

  16. Supine Treadmill Exercise in Lower Body Negative Pressure Combined with Resistive Exercise Counteracts Bone Loss, Reduced Aerobic Upright Exercise Capacity and Reduced Muscle Strength

    Science.gov (United States)

    Meuche, Sabine; Schneider, S. M.; Lee, S. M. C.; Macias, B. R.; Smith, S. M.; Watenpaugh, D. E.; Hargens, A. R.

    2006-01-01

    Long-term exposure to weightlessness leads to cardiovascular and musculoskeletal deconditioning. In this report, the effectiveness of combined supine treadmill exercise in a lower body negative pressure chamber (LBNPex) and flywheel resistive exercise (Rex) countermeasures was determined to prevent bone loss, reduced aerobic upright exercise capacity and reduced muscle strength. We hypothesized that exercise subjects would show less decrease in bone mineral density (BMD), peak oxygen consumption (VO2pk) and knee extensor strength (KES) than control subjects. Sixteen healthy female subjects participated in a 60-d 6(sup 0) head-down tilt bed rest (BR) study after providing written informed consent. Subjects were assigned to one of two groups: a non-exercising control group CON or an exercise group EX performing LBNPex 2-4 d/wk and Rex every 3rd-d. VO2pk was measured with a maximal, graded, upright treadmill test performed pre-BR and on 3-d after BR. BMD was assessed before and 3-d after BR. Isokinetic KES was measured before and 5-d after BR. Two-way repeated measures ANOVA were performed. Statistical significance was set at p less than 0.05. CON experienced a significant decrease in BMD in the trochanter (PRE: 0.670 plus or minus 0.045; POST: 0.646 plus or minus 0.352 g (raised dot) per square centimeter) and in the whole hip (PRE=0.894 plus or minus 0.059; POST: 0.858 plus or minus 0.057 g (raised dot) per square centimeter). BMD also decreased significantly in EX in the trochanter (PRE: 0.753 plus or minus 0.0617; POST: 0.741 plus or minus 0.061 g (raised dot) per square centimeter) and whole hip (PRE: 0.954 plus or minus 0.067; POST: 0.935 plus or minus 0.069 g (raised dot) per square centimeter). BMD losses were significantly less in EX than in CON subjects. VO2pk was significantly decreased in the CON after BR (PRE: 38.0 plus or minus 4.8; POST: 29.9 plus or minus 4.2 ml (raised dot) per kilogram per minute), but not in the EX (PRE: 39.0 plus or minus 2.0; POST

  17. The electronic properties, electronic heat capacity and magnetic susceptibility of monolayer boron nitride graphene-like structure in the presence of electron-phonon coupling

    Science.gov (United States)

    Yarmohammadi, Mohsen

    2017-03-01

    In this work, we have studied the influences of electron-phonon (e-ph) coupling and chemical potential on the boron nitride graphene-like sheet. In particular, by starting the Green's function technique and Holstein model, the electronic density of states (DOS), electronic heat capacity (EHC) and magnetic susceptibility (MS) of this system have been investigated in the context of self-consistent second order perturbation theory which has been implemented to find the electronic self-energy. Our findings show that the band gap size decreases (increases) with e-ph coupling (chemical potential) parameters. The Schottky anomaly (crossover) decreases in EHC (MS) as soon as e-ph coupling increases. Also, the corresponding temperature with Schottky anomaly is considerably affected by e-ph coupling.

  18. DSC、MDSC测定物质比热容的比较%Comparison of differential scanning calorimetry and modulated differential scanning calorimetry in measurement of specific heat capacities

    Institute of Scientific and Technical Information of China (English)

    鲁红; 冯大春; 杨继佑

    2011-01-01

    实验用TA公司具有DSC、MDSC两种模式、具备先进Tzero技术的热流型DSCQ200热分析仪测定物质的比热容.对如何运用传统方法及调制方法测定物质的比热容进行了详细阐述;以氯化钾、苯甲酸、去离子水为测试样,对两种方法所得实验结果进行了分析比较.%The specific heat capacities of potassium choride, benzoic acid and deionized water samples were measured by DSCQ 200 tbermal analyzer in two different method (differential scanning calorimetry. DSC, and modulated differential scanning calorimetry. MDSC), The results obtained by two methods are compared.The questions in the application of DSC and MDSC are discussed in detail.

  19. Simultaneous correlation of the excess enthalpy and W-shaped excess heat capacity of 1,4-dioxane+n-alkane systems by PRSV-HVOS CEOS

    Directory of Open Access Journals (Sweden)

    SLOBODAN P. SERBANOVIC

    2003-01-01

    Full Text Available In this work the Peng-Robinson-Stryjek-Vera (PRSV equation of state coupled with the Huron-Vidal-Orbey-Sandler (HVOS rule was tested for the correlation of the excess enthalpy (HE and the excess heat capacity (cpE alone and simultaneously. The HVOS mixing rule incorporates the NRTL equation as the GE model. All calculations were performed using the linear and reciprocal forms of the temperature dependent parameters of the models. For all the evaluations the 1,4-dioxane+n-alkane systems were chosen having in mind the unusually W-shaped concentration dependence of cpE for these systems. The correlation of the HE and cpE data alone for all the investigated systems using four coefficients and for the simultaneous correlation of HE+cpE data using six coefficients of the temperature dependent parameters of the PRSV-HVOS models could be considered as being very satisfactory.

  20. Effect of heat capacity and conductivity of NbTi normal matrix of a composite superconductor on the stability to magnetic flux jumps

    Science.gov (United States)

    Kruglov, S. L.; Shutova, D. I.; Shcherbakov, V. I.

    2017-02-01

    The stability against magnetic flux jumps has experimentally been studied in the external magnetic field for three samples from NbTi composite superconductors, one monofilamentary and two multifilamentary. A comparison between the experiment and theory of thermomagnetic stability of composite superconductors has been carried out. We have determined threshold values of the rates of the external magnetic fields, starting from which heat capacity and conductivity of the normal composite matrix become determining stabilizing factors. For the first time, the increasing dependence of field of first magnetic flux jump on the rate of the rise in the external magnetic field has been experimentally registered in the superconducting wire for MRI. The reason for this effect is the shunting effect of a high pure copper matrix and the low volume fraction of a superconductor in the composite ( 10%).

  1. Heat capacities, magnetic properties, and resistivities of ternary RPdBi alloys where R = La, Nd, Gd, Dy, Er, and Lu

    Energy Technology Data Exchange (ETDEWEB)

    Riedemann, T.M.

    1996-05-01

    Over the past four and a half decades research on the rare earths, their compounds, and their alloys has yielded significant insights into the nature of materials. The rare earths can be used to systematically study a series of alloys or compounds. Magnetic ordering, crystalline fields, spin fluctuations, the magnetocaloric effect, and magnetostriction are a small sample of phenomena studied that are exhibited by the rare earth family. A significant portion of research has been conducted on the abundant RM{sub 2} and RM phases, where R is the rare earth and M is a transition metal. The natural progression of science has led to the study of related RMX ternary phases, where X is either another transition metal or semimetal. There are now over 1,000 known RMX phases. The focus of this study is on RPdBi where R = La, Nd, Gd, Dy, Er, and Lu. Their heat capacities, magnetic properties, and resistivities are studied.

  2. Heat capacity and thermodynamic functions of 2-methylbiphenyl and 3,3'-dimethylbiphenyl in the range of 6 to 372 K

    Science.gov (United States)

    Tkachenko, E. S.; Druzhinina, A. I.; Varushchenko, R. M.; Tarazanov, S. V.; Nesterova, T. N.; Reshetova, M. D.; Polyakova, O. V.

    2013-05-01

    The heat capacities of 2-methylbiphenyl and 3,3'-dimethylbiphenyl are measured by means of low-temperature adiabatic calorimetry in the temperature range of 6 to 372 K. The thermodynamic characteristics of fusion and the glass transition of the investigated compounds are determined. The saturation vapor pressure and enthalpy of vaporization of 3,3'-dimethylbiphenyl are determined according to the dynamic method based on the transfer of a substance vapor in a helium flow. The absolute entropies and changes in Gibbs energies of biphenyl derivatives are calculated from the data obtained in the condensed and ideal gas states. The contribution of the Cb-(Cb) group is determined using the Benson additive method for calculating the absolute entropies of biphenyl derivatives in the liquid state (where Cb is the carbon atom in a benzene ring).

  3. Low-Temperature Heat Capacities and Thermodynamic Properties of Hydrated Nickel L-Threonate Ni(C4H7O5)2·2H2O(s)

    Institute of Scientific and Technical Information of China (English)

    DI You-Ying; TAN Zhi-Cheng; GAO Sheng-Li; CHEN San-Ping; SUN Li-Xian

    2007-01-01

    Low-temperature heat capacities of the compound Ni(C4H7O5)2·2H2O(s) have been measured with an automated adiabatic calorimeter. A thermal decomposition or dehydration occurred in 350-369 K. The temperature,enthalpy and entropy of the dehydration were determined to be (368.141+-0.095)K,(18.809+-0.088)kJ·mol-1 and (51.093+-0.239)J·K-1·mol-1 respertively.The exterimental values of the molar heat capacities in the temperature regions of 78-350 and 368-390 K were fitted to two polynomial equations of heat capacities (Cp,m)with the reduced temperatures (X), [X=f(T)], by a least squares method, respectively. The smoothed molar heat capacities and thermodynamic functions of the compound were calculated on the basis of the fitted polynomials. The smoothed values of the molar heat capacities and fundamental thermodynamic functions of the sample relative to the standard reference temperature 298.15 K were tabulated with an interval of 5 K.

  4. vdW气体比热容比与音速关系的理论研究%A Theoretical Study on Relation between Specific Heat Capacity Ratio of VDW Gas and Sonic Speed

    Institute of Scientific and Technical Information of China (English)

    陈漓

    2012-01-01

    The relation between specific heat capacity ratio of vdW gas and sonic speed is analyzed and derived by thermodynamics relation and is compared, analyzed with the value from experimental determination and specific heat capacity ratio of ideal gas. The relation curve between specific heat capacity ratio and temperature is developed by using simulation technique of Matlab and the reasons why the coincident degree between specific heat capacity ratio of vdW gas and real gas is better than the specific heat capacity ratio of ideal gas are provided in the paper.%通过热力学关系分析和导出vdW气体的比热容比与音速的关系式,将它与实验测定的数值以及理想气体比热容比进行对比分析,并运用Matlab仿真技术绘制出比热容比与温度的关系曲线,进而说明vdW气体比热容比与实际气体比热容比吻合的程度好于理想气体的比热容比.

  5. 纳米晶体铁的低温热容和热稳定性%LOW TEMPERATURE HEAT CAPACITY AND THERMAL STABILITY OF NANOCRYSTALLINE IRON

    Institute of Scientific and Technical Information of China (English)

    王岚; 谭志诚; 孟霜鹤; 梁东白; 高东升; 孙志忠; 刘振田

    2002-01-01

    用等离子体法制备的纳米晶体铁由XRD和SEM等方法测定其晶粒尺寸的平均值为87nm.用绝热量热方法在79~371K温区精确测定了其低温热容,测量结果比大晶粒Fe的热容值有明显的增强.在80~300 K温区之间增强热容为8%~14%.差示扫描量热(DSC)在高温区的研究结果则表明,纳米晶体Fe在400~700 K温区有一个宽的放热峰,对应于非平衡晶格缺陷所引起的焓释放850 K观察到一个放热峰.是纳米晶体铁从α相向α+γ相转变所引起的%The sample of nanocrystalline iron with the average grain size of 87nm was prepared by thermal plasma technique, and characterized by XRD and SEM. Measurement of low temperature heat capacity of the nano-Fe has been performed in the temperature range of 79~371K with an automated adiabatic calorimeter. Enhanced heat capacities varying from 8% to 14% were observed.The differential scanning calorimetric measurement showed one broad exothermic regime from 400K to700K corresponding to the enthalpy releasing, due to the contribution of nonequibrium lattice defects.An endothermic peak at 850K due to a γ→α + γ phase transition of nc-Fe was observed.

  6. Alternating current calorimeter for specific heat capacity measurements at temperatures below 10 K and pressures up to 10 GPa.

    Science.gov (United States)

    Umeo, Kazunori

    2016-06-01

    A developed alternating current calorimeter for measuring the absolute value of specific heat C of a very small sample under a pressure up to 10 GPa and low temperature below 10 K is described. A Bridgman anvil cell made of tungsten carbide with a top diameter of 3 mm is used. A hollow at the top prevents expansion of the sample space over the anvil top. Two chip resistors, which act as a thermometer and a heater, are mounted on the outer part of a copper-beryllium gasket with a frying pan-like shape. Thus, the thermometer is not pressurized. In order to isolate the gasket from the anvil thermally, diamond powder with a grain size of 0.25 μm is placed on the anvil top. Two jumps of C at the superconducting transitions of Pb (3.3 mg) and In (5.0 mg) are observed under various pressures up to 9 GPa, as clearly as those at the ambient pressure.

  7. Transition Helmholtz free energy, entropy, and heat capacity of free-standing smectic films in water: A mean-field treatment

    Energy Technology Data Exchange (ETDEWEB)

    Śliwa, Izabela, E-mail: izasliwa@ifmpan.poznan.pl [Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznaǹ (Poland); Zakharov, A. V., E-mail: alexandre.zakharov@yahoo.ca [Saint Petersburg Institute for Machine Sciences, The Russian Academy of Sciences, Saint Petersburg 199178 (Russian Federation)

    2014-11-21

    Using the extended McMillan's mean field approach with anisotropic forces a study of both the structural and thermodynamic properties of free-standing smectic film (FSSF) in water on heating to the isotropic temperature is carried out numerically. By solving the self-consistent nonlinear equations for the order parameters, we obtained that the smectic-A-isotropic (AI) transition occurs through the series of layer-thinning transitions causing the films to thin in the stepwise manner as the temperature is increased above the bulk smectic-A-isotropic temperature T{sub AI}(bulk). With enhanced pair interactions in the bounding layers, the smectic-isotropic transition corresponds to smectic melting of the central layers. The effects of surface “enhanced” pair interactions in the bounding layers and of film thickness on the orientational and translational order parameters, the Helmholtz free energy and entropy, as well as the temperature dependence of the heat capacity of FSSFs, have also been investigated. Reasonable agreement between the theoretically predicted and the experimentally obtained – by means of optical microscopy and ellipsometry techniques – data of the temperature when the thin decylcyanobiphenyl smectic film immersing in water ruptures has been obtained.

  8. Transition Helmholtz free energy, entropy, and heat capacity of free-standing smectic films in water: a mean-field treatment.

    Science.gov (United States)

    Śliwa, Izabela; Zakharov, A V

    2014-11-21

    Using the extended McMillan's mean field approach with anisotropic forces a study of both the structural and thermodynamic properties of free-standing smectic film (FSSF) in water on heating to the isotropic temperature is carried out numerically. By solving the self-consistent nonlinear equations for the order parameters, we obtained that the smectic-A-isotropic (AI) transition occurs through the series of layer-thinning transitions causing the films to thin in the stepwise manner as the temperature is increased above the bulk smectic-A-isotropic temperature TAI(bulk). With enhanced pair interactions in the bounding layers, the smectic-isotropic transition corresponds to smectic melting of the central layers. The effects of surface "enhanced" pair interactions in the bounding layers and of film thickness on the orientational and translational order parameters, the Helmholtz free energy and entropy, as well as the temperature dependence of the heat capacity of FSSFs, have also been investigated. Reasonable agreement between the theoretically predicted and the experimentally obtained - by means of optical microscopy and ellipsometry techniques - data of the temperature when the thin decylcyanobiphenyl smectic film immersing in water ruptures has been obtained.

  9. Low temperature heat capacities and thermodynamic properties of rare earth triisothiocyanate hydrates——Pr(NCS)3· 7H2O and Nd(NCS)3· 7H2O

    Institute of Scientific and Technical Information of China (English)

    谭志诚; Matsuo Takasuke; Suga Hiroshi; 张志英; 尹敬执; 蒋本杲; 孙同山

    1996-01-01

    Heat capacities of Pr(NCS)3·7H2O and Nd(NCS)3· 7H2O haw been measured from 13 to 300 K by using a fully automated adiabatic calorimeter. Schottky anomaly was observed for Pr(NCS)3·7H2O below 50 K. The polynomial equations for calculating the heat capacity values of the two compounds in the range of 13-300 K were obtained by the least-squares fitting based on the experimental Cp data. The Cp values below 13 K were estimated by using the Debye-Einstein and Schottky heat capacity functions. The standard molar thermodynamic functions were computed from 0 to 300 K. The standard entropies and Gibbs energies of formation of the two compounds were also calculated.

  10. Astaxanthin present in the maturation medium reduces negative effects of heat shock on the developmental competence of porcine oocytes.

    Science.gov (United States)

    Do, Lanh Thi Kim; Luu, Vien Viet; Morita, Yasuhiro; Taniguchi, Masayasu; Nii, Masahiro; Peter, Augustine T; Otoi, Takeshige

    2015-06-01

    Astaxanthin, one of the most common carotenoids, elicits antioxidant effects on cellular viability and embryonic development. This study was conducted to investigate the effects of astaxanthin on maturation, fertilization and development of porcine oocytes matured in vitro under heat stress conditions, and then fertilized and cultured under standard conditions. Porcine oocytes were cultured in maturation medium supplemented with different concentrations of astaxanthin (0, 0.25, 0.5 or 1 ppm) for 46 h at either 38.5 or 41 °C. In comparison to oocytes cultured at 38.5 °C, the exposure of porcine oocytes to 41.0 °C during in vitro maturation (IVM) significantly inhibited maturation and development of fertilized oocytes to the blastocyst stage. Supplementation of maturation medium with astaxanthin (0.5 ppm) significantly improved oocyte maturation, fertilization and development to the blastocysts stage in both oocyte groups. However, the total cell number and apoptosis index of blastocysts did not differ among groups. Moreover, astaxanthin (0.5 ppm) significantly increased the rate of oocytes that reached metaphase II and decreased proportion of apoptotic oocytes exposed to H2O2 (1.0mM) during IVM. In summary, we demonstrated that supplementation of maturation medium with astaxanthin (0.5 ppm) exerted antioxidative effects and improved the ability of maturation, fertilization, and development of porcine oocytes exposed to heat stress.

  11. Negative effect of heat shock on feline calicivirus release from infected cells is associated with the control of apoptosis.

    Science.gov (United States)

    Alvarez-Sanchez, Cristal; Cancio-Lonches, Clotilde; Mora-Heredia, José Eduardo; Santos-Valencia, Juan Carlos; Barrera-Vázquez, Oscar Salvador; Yocupicio-Monroy, Martha; Gutiérrez-Escolano, Ana Lorena

    2015-02-16

    FCV infection causes rapid cytopathic effects, and its replication results in the induction of apoptosis changes in cultured cells. It is well established that the survival of apoptotic cells can be enhanced by the expression of heat-shock proteins (Hsp) to prevent damage or facilitate recovery. Hsps can act as molecular chaperones, but they can also have anti-apoptotic roles by binding to apoptotic proteins and inhibiting the activation of caspases, the primary mediators of apoptosis. Because apoptosis occurs during FCV infection and heat shock (HS) treatment has a cytoprotective role due to the expression of Hsps, we studied the effect of the HS response to hyperthermia during FCV infection in cultured cells. We found that FCV infection does not inhibit the expression of Hsp70 induced by HS and that non-structural and structural protein synthesis was not modified during HS treatment. However, HS caused a delay in the appearance of a cytopathic effect in infected cells, as well as a reduction in the extracellular but not in the cell-associated viral yield. This antiviral effect of HS correlates with the inhibition of caspase-3 activation. Thus, the HS-induced reduction in virus production appeared to be associated with the control of apoptosis, supporting previous data that indicate that apoptosis is necessary for FCV release. Copyright © 2015 Elsevier B.V. All rights reserved.

  12. Behavior of the heat capacity at second-order phase transitions in the [Zn2(C8H4O4)2 · C6H12N2] metal-organic framework compound

    Science.gov (United States)

    Kozlova, S. G.

    2016-08-01

    The temperature dependence of the heat capacity at second-order phase transitions that were previously detected in the [Zn2(C8H4O4)2 · C6H12N2] metal-organic framework compound has been analyzed. The critical exponents have been obtained. It has been shown that the behavior of the heat capacity below the critical temperature of 60 K, which is attributed to the violation of the mirror symmetry of C2H12N6 molecules, is exponential.

  13. The low temperature heat capacity of LaPO{sub 4} and GdPO{sub 4}, the thermodynamic functions of the monazite-type LnPO{sub 4} series

    Energy Technology Data Exchange (ETDEWEB)

    Thiriet, C. [European Commission, Joint Research Centre, Institute for Transuranium Elements, P.O. Box 2340, 76125 Karlsruhe (Germany)]. E-mail: catherine.thiriet@itu.fzk.de; Konings, R.J.M. [European Commission, Joint Research Centre, Institute for Transuranium Elements, P.O. Box 2340, 76125 Karlsruhe (Germany)]. E-mail: konings@itu.fzk.de; Javorsky, P. [European Commission, Joint Research Centre, Institute for Transuranium Elements, P.O. Box 2340, 76125 Karlsruhe (Germany)]. E-mail: javor@met.mff.cuni.cz; Magnani, N. [I.N.F.M. and University of Parma, Parco Area delle Scienze 7/A, I-43100 Parma (Italy)]. E-mail: magnani@fis.unipr.it; Wastin, F. [European Commission, Joint Research Centre, Institute for Transuranium Elements, P.O. Box 2340, 76125 Karlsruhe (Germany)]. E-mail: wastin@itu.fzk.de

    2005-02-01

    The heat capacity of lanthanum and gadolinium orthophosphate (LaPO{sub 4} and GdPO{sub 4}) with monazite-like structure (i.e., monoclinic) was measured by hybrid adiabatic relaxation calorimetry in the temperature ranges (2 to 380) K and (0.5 to 301) K respectively. A semi-empirical method has been used to describe the total specific heat as the sum of a lattice and an excess component. An excess contribution due to magnetic effects was observed for GdPO{sub 4} below T = 12 K and it was found that GdPO{sub 4} orders magnetically below 0.8 K. Combining the results obtained for both compounds, the excess heat capacity for CePO{sub 4} was deduced and compared to the excess heat capacity derived from the crystal-field energies. A good agreement has been found between the experimental heat capacity and the calculated one. The thermodynamic functions of the monazite-type LnPO{sub 4} series were determined.

  14. The Gibbs-Thomson effect and intergranular melting in ice emulsions: Interpreting the anomalous heat capacity and volume of supercooled water

    Science.gov (United States)

    Johari, G. P.

    1997-12-01

    Calculations for the Gibbs-Thomson effect and the intergranular melting of the ice droplets in (water) emulsions at temperatures below 273.16 K show that water and ice coexist at thermodynamic equilibrium in an apparently frozen emulsion. The fraction of water at this equilibrium increases on heating, which alters further the thermodynamic properties of the emulsion. As some of the ice in the emulsion has already melted, the increase in the enthalpy, H, and heat capacity, Cp, and the decrease in the volume measured on the normal melting at 273.16 K, are less than the values anticipated. The ratio of this increase in H, or Cp, on melting of the emulsion to the corresponding value for pure ice, underestimates the emulsion's water content which, when used for scaling the difference between the Cp of the unfrozen and frozen emulsion at lower temperatures, as in earlier studies, leads to a larger Cp of supercooled water than the actual value. Similar scaling of the corresponding difference between the volume leads to higher volume, or lower density, than the actual value. A formalism for this premelting effect is given for both the adiabatic and differential scanning calorimetry (DSC), and its magnitude is calculated. New experiments show that the rise in the DSC signal, or equivalently in the apparent Cp observed on heating the frozen emulsion, occurs over a temperature range much wider than the Gibbs-Thomson effect and intergranular melting predict, for which reasons are given. It is shown that Cp of the dispersant phase is also affected by the melting of ice droplets. There are four consequences of the premelting effects for all finely dispersed materials, for frozen water emulsions below 273.16 K: (i) water and ice coexist in the emulsion, (ii) its apparent Cp will increase with increase in the heat input used to measure it, (iii) the apparent Cp will increase with decrease in the average size of the droplets, and (iv) the apparent Cp will decrease on annealing the

  15. Thermal effusivity measurement based on analysis of 3D heat flow by modulated spot heating using a phase lag matrix with a combination of thermal effusivity and volumetric heat capacity

    Science.gov (United States)

    Ohta, Hiromichi; Hatori, Kimihito; Matsui, Genzou; Yagi, Takashi; Miyake, Shugo; Okamura, Takeo; Endoh, Ryo; Okada, Ryo; Morishita, Keisuke; Yokoyama, Shinichiro; Taguchi, Kohei; Kato, Hideyuki

    2016-11-01

    The study goal was to establish a standard industrial procedure for the measurement of thermal effusivity by a thermal microscope (TM), using a periodic heating method with a thermoreflectance (TR) technique. To accomplish this goal, a working group was organized that included four research institutes. Each institute followed the same procedure: a molybdenum (Mo) film was sputtered on the surface of Pyrex, yttria-stabilized zirconia (YSZ), alumina (Al2O3), Germanium (Ge), and silicon (Si) samples, and then the phase lag of the laser intensity modulation was measured by the resultant surface temperature. A procedure was proposed to calibrate the effect of 3D heat flow, based on the analytical solution of the heat conduction equation, and thermal effusivity was measured. The derived values show good agreement with literature values. As a result, the TM calibration procedure can be recommended for practical use in measuring the thermal effusivity in a small region of the materials.

  16. Excess Molar Volume, Viscosity and Heat Capacity for the Binary Mixture of p-Xylene and Acetic Acid at Different Temperatures%对二甲苯和醋酸二元液体混合物在不同温度下的超额摩尔体积、粘度和热容

    Institute of Scientific and Technical Information of China (English)

    杨长生; 马沛生; 唐多强; 尹秋响; 赵长伟

    2002-01-01

    Experimental densities, viscosities and heat capacities at different temperatures were presented overthe entire range of mole fraction for the binary mixture of p-xylene and acetic acid. Density values were used in thedetermination of excess molar volumes, VE. At the same time, the excess viscosity and excess molar heat capacitieswere calculated. The values of VE, ηE and cpE were fitted to the Redlich-Kister equation. Good agreements wereobserved. The excess molar volumes are positive with a large maximum value located in the central concentrationrange. The excess viscosity has an opposite trend to the excess molar volume VE. ηE values are negative over theentire range of the mixture. The cure of dependence of cEp on concentration has a special shape. The molecularinteraction between p-xylene and acetic acid is discussed.

  17. Research of Macroscopic Regularities of Heat and Mass Transfer at the Ignition Condition of a Liquid High-Energy Material by an Immersed Source with a Limited Energy Capacity

    Directory of Open Access Journals (Sweden)

    Dmitrii O. Glushkov

    2014-04-01

    Full Text Available We carried out a numerical and experimental investigation of heat and mass transfer at the ignition condition of a liquid high-energy material by a typical immersed source with a limited energy capacity, being a small, intensely heated metallic particle. The numerical research is made on the basis of a model taking into account a group of interrelated physicochemical processes (thermal conductivity, diffusion, convection, mixing, and radiative heat transfer with phase transitions (evaporation of the liquid and crystallization of the particle's material. We established such terminal conditions for the immersion energy source that prevent inflammation of the high-energy material.

  18. Extended least-squares analysis of heat capacities incorporating the effect of phase transitions and its application to the deuteration-induced phase transition in Rb{sub 3}D(SO{sub 4}){sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Matsuo, Takasuke; Tanaka, Nobuki; Fukai, Mari; Yamamuro, Osamu; Inaba, Akira; Ichikawa, Mizuhiko

    2003-06-26

    A non-linear least-squares method of analysis has been developed for the heat capacities of solids undergoing phase transitions. It utilizes harmonic heat capacity functions corrected for thermal expansion. The unique feature of the method is that it incorporates the effect of a gradual phase transition in the fitting function for the low temperature phase. Compact expressions approximating the Debye function and the Ising model heat capacity function have been derived and presented in practical forms for use in the Kaleidagraph software. The method has been tested on the heat capacity of sodium chloride (which lacks a phase transition) and tri-rubidium deuterium disulfate (Rb{sub 3}D(SO{sub 4}){sub 2}, TRDS) which undergoes a phase transition at 78.5 K in the deuterated form but not in the normal hydrogenous form. The excess entropy based on the fitting was 5.27 J K{sup -1} mol{sup -1}, close enough to R ln 2=5.76 J K{sup -1} mol{sup -1} to suggest an order-disorder mechanism for the phase transition.

  19. Heat capacity and thermodynamical properties of the crystal of [RE2(Glu)2(H2O)8](ClO4)4·H2O (RE=Nd,Eu,Dy)

    Institute of Scientific and Technical Information of China (English)

    WU XinMin; LI Wei; TAN ZhiCheng; QU SongSheng

    2009-01-01

    Thermodynamical data of rare earth complexes with amino acid are important for engineering chemistry and fundamental chemistry.However,they have rarely been reported.In this work,a series of crystalline complexes of rare earth perchlorate coordinated with glutamic acid have been synthesized in water medium,and their thermodynamical data,including the heat capacity in low temperature range and the standard enthalpy of formation,were determined.These complexes were identified to be [RE2(Glu)2(H2O)8](ClO4)4.H2O (RE=Nd,Eu,Dy) by using thermogravimetric analysis (TG),differential thermal analysis (DTA),and chemical and elementary analyses.Their purity has been determined.No melting points were observed for all the three complexes.The heat capacity of the complexes was measured by an adiabatic calorimeter from 79 to 370 K.Abnormal heat capacity values were detected for two of the complexes and the decomposition range of one complex was found.The temperature,enthalpy change and entropy change of the decomposition processes of the three complexes were calculated.The polynomial equations of heat capacity in the experimental temperature range have been obtained by least squares fitting.The standard enthalpy of formation was determined by an isoperibol reaction calorimeter at 298.15 K.

  20. Heat capacity and thermodynamical properties of the crystal of [RE2(Glu)2(H2O)8](ClO4)4·H2O (RE = Nd, Eu, Dy)

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Thermodynamical data of rare earth complexes with amino acid are important for engineering chemistry and fundamental chemistry. However, they have rarely been reported. In this work, a series of crystalline complexes of rare earth perchlorate coordinated with glutamic acid have been synthesized in water medium, and their thermodynamical data, including the heat capacity in low temperature range and the standard enthalpy of formation, were determined. These complexes were identified to be [RE2(Glu)2(H2O)8](ClO4)4·H2O (RE = Nd, Eu, Dy) by using thermogravimetric analysis (TG), differential thermal analysis (DTA), and chemical and elementary analyses. Their purity has been determined. No melting points were observed for all the three complexes. The heat capacity of the complexes was measured by an adiabatic calorimeter from 79 to 370 K. Abnormal heat capacity values were detected for two of the complexes and the decomposition range of one complex was found. The temperature, enthalpy change and entropy change of the decomposition processes of the three complexes were calculated. The polynomial equations of heat capacity in the experimental temperature range have been obtained by least squares fitting. The standard enthalpy of formation was determined by an isoperibol reaction calorimeter at 298.15 K.

  1. Role of the heat capacity change in understanding and modeling melting thermodynamics of complementary duplexes containing standard and nucleobase-modified LNA.

    Science.gov (United States)

    Hughesman, Curtis B; Turner, Robin F B; Haynes, Charles A

    2011-06-14

    Melting thermodynamic data obtained by differential scanning calorimetry (DSC) are reported for 43 duplexed oligonucleotides containing one or more locked nucleic acid (LNA) substitutions. The measured heat capacity change (ΔC(p)) for the helix-to-coil transition is used to compute the changes in enthalpy and entropy for melting of an LNA-bearing duplex at the T(m) of its corresponding isosequential unmodified DNA duplex to allow rigorous thermodynamic analysis of the stability enhancements provided by LNA substitutions. Contrary to previous studies, our analysis shows that the origin of the improved stability is almost exclusively a net reduction (ΔΔS° thermodynamics and the increased melting temperature (ΔT(m)) of heteroduplexes formed between an unmodified DNA strand and a complementary strand containing any number and configuration of standard LNA nucleotides A, T, C, and G. This single-base thermodynamic (SBT) model requires only four entropy-related parameters in addition to ΔC(p). Finally, DSC data for 20 duplexes containing the nucleobase-modified LNAs 2-aminoadenine (D) and 2-thiothymine (H) are reported and used to determine SBT model parameters for D and H. The data and model suggest that along with the greater stability enhancement provided by D and H bases relative to their corresponding A and T analogues, the unique pseudocomplementary properties of D-H base pairs may make their use appealing for in vitro and in vivo applications.

  2. Heat Capacity and Thermal Conductance Measurements of a Superconducting-Normal Mixed State by Detection of Single 3 eV Photons in a Magnetic Penetration Thermometer

    Science.gov (United States)

    Stevenson, T. R.; Balvin, M. A.; Bandler, S. R.; Denis, K. L.; Lee, S.-J.; Nagler, P. C.; Smith, S. J.

    2015-01-01

    We report on measurements of the detected signal pulses in a molybdenum-gold Magnetic Penetration Thermometer (MPT) in response to absorption of one or more 3 eV photons. We designed and used this MPT sensor for x-ray microcalorimetry. In this device, the diamagnetic response of a superconducting MoAu bilayer is used to sense temperature changes in response to absorbed photons, and responsivity is enhanced by a Meissner transition in which the magnetic flux penetrating the sensor changes rapidly to minimize free energy in a mixed superconducting normal state. We have previously reported on use of our MPT to study a thermal phonon energy loss to the substrate when absorbing x-rays. We now describe results of extracting heat capacity C and thermal conductance G values from pulse height and decay time of MPT pulses generated by 3 eV photons. The variation in C and G at temperatures near the Meissner transition temperature (set by an internal magnetic bias field) allow us to probe the behavior in superconducting normal mixed state of the condensation energy and the electron cooling power resulting from quasi-particle recombination and phonon emission. The information gained on electron cooling power is also relevant to the operation of other superconducting detectors, such as Microwave Kinetic Inductance Detectors.

  3. Spin heat capacity of monolayer and AB-stacked bilayer MoS2 in the presence of exchange magnetic field

    Science.gov (United States)

    Hoi, Bui Dinh; Yarmohammadi, Mohsen; Mirabbaszadeh, Kavoos

    2017-04-01

    Dirac theory and Green's function technique are carried out to compute the spin dependent band structures and corresponding electronic heat capacity (EHC) of monolayer (ML) and AB-stacked bilayer (BL) molybdenum disulfide (MoS2) two-dimensional (2D) crystals. We report the influence of induced exchange magnetic field (EMF) by magnetic insulator substrates on these quantities for both structures. The spin-up (down) subband gaps are shifted with EMF from conduction (valence) band to valence (conduction) band at both Dirac points in the ML because of the spin-orbit coupling (SOC) which leads to a critical EMF in the K point and EHC returns to its initial states for both spins. In the BL case, EMF results split states and the decrease (increase) behavior of spin-up (down) subband gaps has been observed at both K and K‧ valleys which is due to the combined effect of SOC and interlayer coupling. For low and high EMFs, EHC of BL MoS2 does not change for spin-up subbands while increases for spin-down subbands.

  4. 1,2-环己二醇的焓和热容数据研究%Enthalpy and Heat Capacity Data for 1,2-Cyclohexanediol

    Institute of Scientific and Technical Information of China (English)

    周彩荣; 章亚东; 蒋登高

    2003-01-01

    The thermodynamic properties of different geometric structures of 1,2-cyclohexanediol which were rarely reported in literature, such as combustion enthalpy, formation enthalpy, melting enthalpy and heat capacities, were determined by NETZSCH DSC 204 Scanning Calorimeter. The relationship between the melting point and the composition for the mixture system of cis-1,2-cyclohexanediol and trans-1,2-cyclohexanediol was investigated and corresponding phase diagram was obtained. The melting enthMpies of both cis-1,2-cyclohexanediol and trans-1,2-cyclohexanediol are 20.265 kJ·mol-1 and 16.368 kJ·mol-1 respectively. The standard combustion enthalpies of cis- and trans-1,2-cyclohexaneddiol were determined by calorimeter. They are respectively -3507.043 kJ·mol-1 and -3497.8 k J·mol-1 at 298.15 K.The standard formation enthalpies are respectively 568.997kJ·mol-1and 578.240kJ·mol-1 for cis- and trans-1,2-cyclohexaneddiol.

  5. A small sample-size automated adiabatic calorimeter from 70 to 580 K——Molar heat capacities of α-Al2O3

    Institute of Scientific and Technical Information of China (English)

    谭志诚; 张际标; 孟霜鹤; 李莉

    1999-01-01

    An automatic adiabatic calorimeter for measuring heat capacities in the temperature range 70—580 K, equipped with a small sample cell of 7.4 cm~3 in the internal volume has been developed. In order to obtain a good adiabatic condition of the calorimeter at high temperature, the calorimeter was surrounded in sequence by two adiabatic shields, three radiation shields and an auxiliary temperature-controlled sheath. The main body of the cell made of copper and the lid made of brass are silver-soldered and the cell is sealed with a copper screw cap. A sealing gasket made of Pb-Sn alloy is put between the cap and the lid to ensure a high vacuum sealing of the cell in the whole experimental temperature range. All the leads are insulated and fixed with W30-11 varnish, thus a good electric insulation is obtained at high temperature. All the experimental data, including those for energy and temperature are collected and processed automatically with a personal computer using a predetermined program. To verify the

  6. Magneto-heat capacity study on Kondo lattice system Ce(Ni$_{1−x}$Cu$_x$)$_2$Al$_3$

    Indian Academy of Sciences (India)

    SANKARARAO YADAM; DURGESH SINGH; D VENKATESHWARLU; MOHAN KUMAR GANGRADE; S SHANMUKHA RAO SAMATHAM; V GANESAN

    2016-04-01

    Heat capacity studies on the Kondo lattice system Ce(Ni$_{1−x}$Cu$_x$)$_2$Al$_3$, in the presence of magnetic fields, were reported for $x = 0.0−0.4$. The physical properties of the intermediate compositions like $x = 0.3$ and 0.4 were known for their enhanced thermoelectric power and hence have been analysed with an extra interest. It was also shown from the X-ray diffraction that these systems with $x = 0.3$ and 0.4 were in single phase in terms of sample purity and it stabilized the phases easily with the increase in the Cu doping in the system. The low temperature risein $C_p/T$ below 10 K under the influence of high magnetic fields was analysed using a multi-level Schottky effect. A gradual decrease of the total angular momentum (J) with the increase of applied magnetic fields indicated ascenario of screening of Ce$^{3+}$ magnetic moment while simultaneously the system settled for the Fermi liquid state. The screening thus seen was in line with the expectations of electrical conductivity measurements on these samples.

  7. Spin- and valley-dependent electronic band structure and electronic heat capacity of ferromagnetic silicene in the presence of strain, exchange field and Rashba spin-orbit coupling

    Science.gov (United States)

    Hoi, Bui Dinh; Yarmohammadi, Mohsen; Kazzaz, Houshang Araghi

    2017-10-01

    We studied how the strain, induced exchange field and extrinsic Rashba spin-orbit coupling (RSOC) enhance the electronic band structure (EBS) and electronic heat capacity (EHC) of ferromagnetic silicene in presence of external electric field (EF) by using the Kane-Mele Hamiltonian, Dirac cone approximation and the Green's function approach. Particular attention is paid to investigate the EHC of spin-up and spin-down bands at Dirac K and K‧ points. We have varied the EF, strain, exchange field and RSOC to tune the energy of inter-band transitions and consequently EHC, leading to very promising features for future applications. Evaluation of EF exhibits three phases: Topological insulator (TI), valley-spin polarized metal (VSPM) and band insulator (BI) at given aforementioned parameters. As a new finding, we have found a quantum anomalous Hall phase in BI regime at strong RSOCs. Interestingly, the effective mass of carriers changes with strain, resulting in EHC behaviors. Here, exchange field has the same behavior with EF. Finally, we have confirmed the reported and expected symmetry results for both Dirac points and spins with the study of valley-dependent EHC.

  8. 非能动余热排出换热器换热能力数值分析%Numerical Analysis on Heat Removal Capacity of Passive Residual Heat Removal Heat Exchanger

    Institute of Scientific and Technical Information of China (English)

    张文文; 丛腾龙; 田文喜; 秋穗正; 苏光辉; 谢永诚; 蒋兴

    2015-01-01

    Thermal‐hydraulics characteristics of AP1000 passive residual heat removal heat exchanger (PRHR‐HX) at initial operating stage were analyzed based on the por‐ous media model .The data obtained from RELAP5 under the condition of the station blackout was employed as the inlet flow rate and temperature boundary of CFD calcula‐tion .The distribution resistances were added into the C‐type tube bundle region which was treated as porous zone .Three‐dimensional distributions of velocity and temperature in the in‐containment refueling water storage tank (IRWST ) were calculated by the commercial CFD code FLUENT .The heat transfer between the primary loop side and the IRWST side was calculated by user self‐defined function UDF .The results show that the heat transfer capability decreases with the increase of water temperature and a thermal stratification phenomenon in the tank occurs .The present results indicate that the method containing coupled heat transfer from the primary loop side fluid to IRWST side fluid and porous media model is a suitable approach to study the transient thermal‐hydraulics of PRHR/IRWST system .%基于多孔介质模型,对AP1000非能动余热排出换热器(PRHR‐HX)运行初始阶段进行了数值模拟。一回路的入口温度及流量采用RELAP5的计算结果,并以此作为CFD计算的边界条件。采用多孔介质模型处理C型管束区,添加管束区分布阻力。通过商业CFD软件FLUENT 计算得到安全壳内置换料水箱(IRWST )侧冷却剂的三维温度及速度分布,通过用户自定义函数 UDF 完成一回路侧与IRWST侧的耦合换热计算,获得一回路温度分布及换热量。计算结果表明,随着IRWST 内冷却剂温度升高,换热器热负荷降低,并出现明显的热分层现象,同时证明采用多孔介质模型与耦合换热计算是分析PRHR/IRWST系统瞬态热工水力特性的有效方法。

  9. Environmental Heat Capacity of River Received the Tail Water of Surface Water Resource Heat Pump%基于地表水源热泵尾水排放的江河热环境容量研究

    Institute of Scientific and Technical Information of China (English)

    黄晓武; 刘杰; 孔淑琼; 洪念; 顾晨; 李恺

    2012-01-01

    运用FLUENT软件对重庆市洪崖洞水源热泵系统尾水排入受纳水域的过程进行二维数值模拟,选取FLUENT中非耦合、隐式求解器对模型内的定常流动进行求解,得出受纳水域受水源热泵系统温排水影响后的温度梯度和温升面积.在温排水流量为4 500 m3/h、温差为6℃的条件下,得出受纳水域温升值超过1℃的水域面积约为1 600m2,为模拟江河水域面积的2.0%.选取1℃温升值作为温升带边界控制值,在热泵系统最大负荷工况下,计算得出受纳水域的热环境容量为312.5 (m3·℃)/s,剩余热环境容量为306.25 (m3·℃)/s.根据地表水环境质量标准,该工程温排水量小于受纳水域的热承载力,不会对受纳水域生态环境造成热污染.%Public hydrodynamic FLUENT software was used to make two dimensional numerical simulation on the process of tail water discharged into the received water of water resource heat pump of Hongya Hole in Chongqing, the steady flow process in the model by using uncoupled implicit solvers was studied, and the temperature rising area and temperature grads of the influencing source were obtained. As the flow of thermal discharge was 4 500 m3/h and temperature difference was 6 ℃, it showed that water area was 1 600 m2 if temperature of water rose 1 t, which was 2.0% of simulation river acreage area. Boundary value control of temperature rising area with one degree was intercalated, in the condition of mostly polluted, environment heat capacity was 312.5 (m3·℃)/s, furthermore the residual environmental heat capacity was 306.25 (m3·℃)/s. According to water environment quality standard, capacity of thermal discharge was under the received water, and there was no thermal pollution to ecological environment of the received water.

  10. Excess Molar Volume, Viscosity and Heat Capacity for the Mixture of 1,2-Propanediol-Water at Different Temperatures%1,2-丙二醇水溶液在不同温度下的超额摩尔体积黏度和热容

    Institute of Scientific and Technical Information of China (English)

    杨长生; 马沛生; 唐多强; 靳凤民

    2003-01-01

    Experimental densities, viscosities and heat capacities at different temperatures were presented over the entire mole fraction range for the binary mixture of 1,2-propanediol and water. Density values were used in the determination of excess molar volumes, VE. At the same time, the excess viscosity was investigated. The values of VE and ηE were fitted to the Redlich-Kister equation. Good agreement was observed. The excess volumes are negative over the entire range of composition. They show an U-shaped-concentration dependence and decrease in absolute values with increase of temperature. Values of ηE are negative over the entire range of the composition, and has a trend very similar to that of VE . The analysis shows that at any temperature the specific heat of mixture is a linear function of the composition as x1>20%. All the extended lines intersect at one point. An empirical equation is obtained to calculate the specific heat to mixture at any composition and temperature in the experimental range.

  11. 基于温度和热容流率同时变化的有分流换热网络弹性设计的研究%Synthesis of Flexible Heat Exchanger Networks with Stream Splits Based on Rangers of Stream Supply Temperatures and Heat Capacity Flowrates

    Institute of Scientific and Technical Information of China (English)

    李志红; 罗行; 华贲; W.Roetzel

    2004-01-01

    A new superstructure model of heat exchanger networks (HEN) with stream splits based on rangers of streams supply temperatures and heat capacity flow rates is presented. The simultaneous optimal mathematical model of flexible HEN synthesis is established too. Firstly, the streams with rangers of supply temperatures and/or the streams with the rangers of heat capacity flow rates are pretreated; Secondly, several rules are proposed to establish the superstructure model of HEN with splits and the simultaneous optimal mathematical model of flexible HEN; Thirdly, the improving genetic algorithm is applied to solve the mathematical model established at the second step effectively, and the original optimal structure of HEN based on the maximum operation limiting condition can be obtained easily; Finally, the rules of heat exchange unit merged and the heat load of heat exchanger relaxed are presented, the flexible configuration of HEN satisfied the operation condition between the upper and down bounds of supply temperature and heat capacity flow rates can be obtained based on the original optimal structure of HEN by means of these rules. A case study demonstrates the method presented in this paper is effective

  12. Measurements of Enthalpy Change of Reaction of Formation, Molar Heat Capacity and Constant-Volume Combustion Energy of Solid Complex Yb(Et2dtc)3(phen)

    Institute of Scientific and Technical Information of China (English)

    Song Weiming; Hu Qilin; Chang Xuan; Chen Sanping; Xie Gang; Gao Shengli

    2006-01-01

    A ternary solid complex Yb(Et2dtc)3(phen) was obtained from the reaction of hydrous ytterbium chloride with sodium diethyldithiocarbamate (NaEt2dtc), and 1, 10-phenanthroline (o-phen·H2O) in absolute ethanol.The bonding characteristics of the complex were characterized by IR.The result shows Yb3+ bands with two sulfur atoms in the Na(Et2dtc)3 and two nitrogen atoms in the o-phen.The enthalpy change of liquid-phase reaction of formation of the complex ΔrHθm (l), was determined as being (-24.838±0.114) kJ·mol-1 at 298.15 K, by an RD-496 Ⅲ type heat conduction microcalormeter.The enthalpy change of the solid-phase reaction of formation of the complex ΔrHθm (s), was calculated as being (108.015±0.479) kJ·mol-1 on the basis of an appropriate thermochemistry cycle.The thermodynamics of liquid-phase reaction of formation of the complex was investigated by changing the temperature during the liquid-phase reaction.Fundamental parameters, the activation enthalpy, ΔHθ≠, the activation entropy, ΔSθ≠, the activation free energy, ΔGθ≠, the apparent reaction rate constant k, the apparent activation energy E, the pre-exponential constant A, and the reaction order n, were obtained by a combination of the reaction thermodynamic and kinetic equations with the data from the thermokinetic experiments.At the same time, the molar heat capacity of the complex cm, p, was determined to be (86.34±1.74) J·mol-1·K-1 by the same microcalormeter.The constant-volume combustion energy of the complex, ΔcU, was determined to be (-17954.08±8.11) kJ·mol-1 by an RBC-Ⅱ type rotating-bomb calorimeter at 298.15 K.Its standard enthalpy of combustion, ΔcHθm, and standard enthalpy of formation, ΔfHθm, were calculated to be (-17973.29±8.11) kJ·mol-1 and (-770.36±9.02) kJ·mol-1, respectively.

  13. Thermodynamic properties (enthalpy, bond energy, entropy, and heat capacity) and internal rotor potentials of vinyl alcohol, methyl vinyl ether, and their corresponding radicals.

    Science.gov (United States)

    da Silva, Gabriel; Kim, Chol-Han; Bozzelli, Joseph W

    2006-06-29

    Vinyl alcohols (enols) have been discovered as important intermediates and products in the oxidation and combustion of hydrocarbons, while methyl vinyl ethers are also thought to occur as important combustion intermediates. Vinyl alcohol has been detected in interstellar media, while poly(vinyl alcohol) and poly(methyl vinyl ether) are common polymers. The thermochemical property data on these vinyl alcohols and methyl vinyl ethers is important for understanding their stability, reaction paths, and kinetics in atmospheric and thermal hydrocarbon-oxygen systems. Enthalpies , entropies , and heat capacities (C(p)()(T)) are determined for CH(2)=CHOH, C(*)H=CHOH, CH(2)=C(*)OH, CH(2)=CHOCH(3), C(*)H=CHOCH(3), CH(2)=C(*)OCH(3), and CH(2)=CHOC(*)H(2). Molecular structures, vibrational frequencies, , and C(p)(T) are calculated at the B3LYP/6-31G(d,p) density functional calculation level. Enthalpies are also determined using the composite CBS-Q, CBS-APNO, and G3 methods using isodesmic work reactions to minimize calculation errors. Potential barriers for internal rotors are calculated at the B3LYP/6-31G(d,p) level and used to determine the hindered internal rotational contributions to entropy and heat capacity. The recommended ideal gas phase values calculated in this study are the following (in kcal mol(-1)): -30.0, -28.9 (syn, anti) for CH(2)=CHOH; -25.6, -23.9 for CH(2)=CHOCH(3); 31.3, 33.5 for C(*)H=CHOH; 27.1 for anti-CH(2)=C(*)OH; 35.6, 39.3 for C(*)H=CHOCH(3); 33.5, 32.2 for CH(2)=C(*)OCH(3); 21.3, 22.0 for CH(2)=CHOC(*)H(2). Bond dissociation energies (BDEs) and group additivity contributions are also determined. The BDEs reveal that the O-H, O-CH(3), C-OH, and C-OCH(3) bonds in vinyl alcohol and methyl vinyl ether are similar in energy to those in the aromatic molecules phenol and methyl phenyl ether, being on average around 3 kcal mol(-1) weaker in the vinyl systems. The keto-enol tautomerization enthalpy for the interconversion of vinyl alcohol to acetaldehyde is

  14. Improved methods for Feynman path integral calculations and their application to calculate converged vibrational–rotational partition functions, free energies, enthalpies, entropies, and heat capacities for methane

    Energy Technology Data Exchange (ETDEWEB)

    Mielke, Steven L., E-mail: slmielke@gmail.com, E-mail: truhlar@umn.edu; Truhlar, Donald G., E-mail: slmielke@gmail.com, E-mail: truhlar@umn.edu [Department of Chemistry, Chemical Theory Center, and Supercomputing Institute, University of Minnesota, 207 Pleasant St. S.E., Minneapolis, Minnesota 55455-0431 (United States)

    2015-01-28

    We present an improved version of our “path-by-path” enhanced same path extrapolation scheme for Feynman path integral (FPI) calculations that permits rapid convergence with discretization errors ranging from O(P{sup −6}) to O(P{sup −12}), where P is the number of path discretization points. We also present two extensions of our importance sampling and stratified sampling schemes for calculating vibrational–rotational partition functions by the FPI method. The first is the use of importance functions for dihedral angles between sets of generalized Jacobi coordinate vectors. The second is an extension of our stratification scheme to allow some strata to be defined based only on coordinate information while other strata are defined based on both the geometry and the energy of the centroid of the Feynman path. These enhanced methods are applied to calculate converged partition functions by FPI methods, and these results are compared to ones obtained earlier by vibrational configuration interaction (VCI) calculations, both calculations being for the Jordan–Gilbert potential energy surface. The earlier VCI calculations are found to agree well (within ∼1.5%) with the new benchmarks. The FPI partition functions presented here are estimated to be converged to within a 2σ statistical uncertainty of between 0.04% and 0.07% for the given potential energy surface for temperatures in the range 300–3000 K and are the most accurately converged partition functions for a given potential energy surface for any molecule with five or more atoms. We also tabulate free energies, enthalpies, entropies, and heat capacities.

  15. Improved methods for Feynman path integral calculations and their application to calculate converged vibrational-rotational partition functions, free energies, enthalpies, entropies, and heat capacities for methane.

    Science.gov (United States)

    Mielke, Steven L; Truhlar, Donald G

    2015-01-28

    We present an improved version of our "path-by-path" enhanced same path extrapolation scheme for Feynman path integral (FPI) calculations that permits rapid convergence with discretization errors ranging from O(P(-6)) to O(P(-12)), where P is the number of path discretization points. We also present two extensions of our importance sampling and stratified sampling schemes for calculating vibrational-rotational partition functions by the FPI method. The first is the use of importance functions for dihedral angles between sets of generalized Jacobi coordinate vectors. The second is an extension of our stratification scheme to allow some strata to be defined based only on coordinate information while other strata are defined based on both the geometry and the energy of the centroid of the Feynman path. These enhanced methods are applied to calculate converged partition functions by FPI methods, and these results are compared to ones obtained earlier by vibrational configuration interaction (VCI) calculations, both calculations being for the Jordan-Gilbert potential energy surface. The earlier VCI calculations are found to agree well (within ∼1.5%) with the new benchmarks. The FPI partition functions presented here are estimated to be converged to within a 2σ statistical uncertainty of between 0.04% and 0.07% for the given potential energy surface for temperatures in the range 300-3000 K and are the most accurately converged partition functions for a given potential energy surface for any molecule with five or more atoms. We also tabulate free energies, enthalpies, entropies, and heat capacities.

  16. Heat pump air conditioning system for pure electric vehicle at ultra-low temperature

    Directory of Open Access Journals (Sweden)

    Li Hai-Jun

    2014-01-01

    Full Text Available When the ordinary heat pump air conditioning system of a pure electric vehicle runs at ultra-low temperature, the discharge temperature of compressor will be too high and the heating capacity of the system will decay seriously, it will lead to inactivity of the heating system. In order to solve this problem, a modification is put forward, and an experiment is also designed. The experimental results show that in the same conditions, this new heating system increases more than 20% of the heating capacity; when the outside environment temperature is negative 20 degrees, the discharge temperature of compressor is below 60 degrees.

  17. On Heat Properties of AdS Black Holes in Higher Dimensions

    CERN Document Server

    Belhaj, A; Moumni, H EL; Masmar, K; Sedra, B; Segui, A

    2015-01-01

    We investigate the heat properties of AdS Black Holes in higher dimensions. We consider the study of the corresponding thermodynamical properties including the heat capacity explored in the determination of the black hole stability. In particular, we compute the heat latent. To overcome the instability problem, the Maxwell construction, in the (T,S)-plane, is elaborated. This method is used to modify the the Hawking-Page phase structure by removing the negative heat capacity regions. Then, we discuss the thermodynamic cycle and the heat engines using the way based on the extraction of the work from a black hole solution.

  18. Thermophysical properties of ilvaite CaFe22+Fe3+Si2O7O (OH); heat capacity from 7 to 920 K and thermal expansion between 298 and 856 K

    Science.gov (United States)

    Robie, R.A.; Evans, H.T.; Hemingway, B.S.

    1988-01-01

    The heat capacity of ilvaite from Seriphos, Greece was measured by adiabatic shield calorimetry (6.4 to 380.7 K) and by differential scanning calorimetry (340 to 950 K). The thermal expansion of ilvaite was also investigated, by X-ray methods, between 308 and 853 K. At 298.15 K the standard molar heat capacity and entropy for ilvaite are 298.9??0.6 and 292.3??0.6 J/(mol. K) respectively. Between 333 and 343 K ilvaite changes from monoclinic to orthorhombic. The antiferromagnetic transition is shown by a hump in Cp0with a Ne??el temperature of 121.9??0.5 K. A rounded hump in Cp0between 330 and 400 K may possibily arise from the thermally activated electron delocalization (hopping) known to take place in this temperature region. ?? 1988 Springer-Verlag.

  19. Ultimate negative bending-moment capacity of outer-plated steel-concrete continuous composite beams%外包钢-混凝土连续组合梁的负弯矩极限承载力

    Institute of Scientific and Technical Information of China (English)

    陈丽华; 李爱群; 娄宇; 李培彬

    2009-01-01

    Static load tests and bearing capacity analyses are cardeA out for two outer-plated steel-concrete continuous composite beams.The load-deflection curve and the loat-strain culve of specimens are obtained and analyzed.The test results indicate that effective cooperation can be achieved by the shear-resistant connection between the reinforcement in the negative moment area and the outer-plated steel beam,and the overall working performance of the composite beams is favorable.At the load-bearing limiting state,the plastic strain on the maximum negative and positive moment section becomes fully developed so as to form relatively ideal plastic hinges.With the increase in the reinforcement ratio,the moment-carrying capacity of the composite beams improves significantly,but the ductility of the beams and the rotation ability of the plastic hinges decrease.The formulae for calculating the limit bending capacity in the negative moment area of outer-plated steel-concrete composite beams are proposed based on the test data.The calculated results agree well with the test results.%对2根外包钢-混凝土连续梁试件进行了静力加载实验研究与承栽力分析.测量并分析了试件的荷栽-挠度及荷载-应变关系曲线.结果表明:外包钢-混凝土组合梁负弯矩区钢筋和外包钢梁通过抗剪连接措施能有效地共同工作,整体工作性能良好.在承栽能力极限状态,负弯矩和正弯矩最大截面的塑性应变均充分发展,并形成比较理想的塑性铰.随着配筋率的提高,组合梁受弯承栽力明显提高,而延性和转动能力相应降低.在试验数据基础上,给出了外包钢-混凝土组合梁在负弯矩区极限受弯承载力的计算公式,计算结果与实验结果吻合良好.

  20. Comparison of cardiovascular response to sinusoidal and constant lower body negative pressure with reference to very mild whole-body heating

    Directory of Open Access Journals (Sweden)

    Ishibashi Keita

    2012-11-01

    Full Text Available Abstract Background The purpose of the present study was to compare sinusoidal versus constant lower body negative pressure (LBNP with reference to very mild whole-body heating. Sinusoidal LBNP has a periodic load component (PLC and a constant load component (CLC of orthostatic stress, whereas constant LBNP has only a CLC. We tested two sinusoidal patterns (30-s and 180-s periods with 25 mmHg amplitude of LBNP and a constant LBNP with −25 mmHg in 12 adult male subjects. Results Although the CLC of all three LBNP conditions were configured with −25 mmHg, the mean arterial pressure (MAP results showed a significantly large decrease from baseline in the 30-s period condition (P 0, total peripheral resistance (TPR, the natural logarithmic of the HF component (lnHF, and LF/HF (ln(LF/HF of heart rate variability (HRV showed relatively small variations from baseline in the 30-s period condition (P Conclusion These results revealed that the effect of the CLC of LBNP on cardiovascular adjustability was attenuated by the addition of the PLC to LBNP. Based on the results of suppressed HRV response from baseline in the 30-s period condition, we suggest that the attenuation may be caused by the suppression of the vagal responsiveness to LBNP.

  1. Low-temperature heat capacities of CaAl2SiO6 glass and pyroxene and thermal expansion of CaAl2SiO6 pyroxene.

    Science.gov (United States)

    Haselton, H.T.; Hemingway, B.S.; Robie, R.A.

    1984-01-01

    Low-T heat capacities (5-380 K) have been measured by adiabatic calorimetry for synthetic CaAl2SiO6 glass and pyroxene. High-T unit cell parameters were measured for CaAl2SiO6 pyroxene by means of a Nonius Guinier-Lenne powder camera in order to determine the mean coefficient of thermal expansion in the T range 25-1200oC. -J.A.Z.

  2. 固态热容激光器3维瞬态热畸变模拟分析%Simulation analysis of 3D dynamic thermo-optic effect of solid state heat capacity laser

    Institute of Scientific and Technical Information of China (English)

    杨火木; 张凯; 唐淳; 冯国英

    2011-01-01

    According to dynamic working characteristics of solid state heat capacity laser, the three dimensional(3D) temperature and thermal stress distribution of cylinder disk heat capacity laser varying with working time is simulated and analyzed using finite difference method.Dynamic variation of thermal distortions and depolarization losses of heat capacity laser is also analyzed.The simulation results are compared with those of continued water-cooled rod laser.Deformation is found to be the main factor of phase distortion for cylinder disk heat capacity laser.Moreover, the depolarization loss increases nonlinearly with the pumping time and pump power.%根据固态热容激光器的动态工作特性,考虑热力学参数与温度的关系,采用3维有限差分方法模拟分析了薄片热容激光器的3维温度和热应力分布随时间的变化关系.计算了热容激光器的热畸变和退偏损耗随时间的动态变化规律,并与采用连续水冷却方式工作的圆棒激光器的热畸变特性做了比较.模拟结果显示,形变是引起波前相位畸变的主要因素,退偏损耗随泵浦时间增加和泵浦功率增大而非线性增大.

  3. Heat capacity and magnetic phase transition of two-dimensional metal-assembled complex, K[{l_brace}Mn{sup III}(3-MeOsalen){r_brace}{sub 2}Fe{sup III}(China){sub 6}

    Energy Technology Data Exchange (ETDEWEB)

    Miyazaki, Yuji [Research Center for Molecular Thermodynamics, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan)]. E-mail: miyazaki@chem.sci.osaka-u.ac.jp; Wang, Qi [Research Center for Molecular Thermodynamics, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan); Department of Chemistry, Zhejiang University, Hangzhou 310027 (China); Yu, Qing-sen [Research Center for Molecular Thermodynamics, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan); Department of Chemistry, Zhejiang University, Hangzhou 310027 (China); Matsumoto, Tetsuya [Research Center for Molecular Thermodynamics, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan); Miyasaka, Hitoshi [Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Minami-ohsawa 1-1, Hachioji, Tokyo 192-0397 (Japan); Matsumoto, Naohide [Department of Chemistry, Faculty of Science, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555 (Japan); Sorai, Michio [Research Center for Molecular Thermodynamics, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan)

    2005-06-15

    Heat capacities of the two-dimensional metal-assembled complex, K[{l_brace}Mn{sup III}(3-MeOsalen){r_brace}{sub 2}Fe{sup III}(China){sub 6}] [3-MeOsalen N,N'-ethylenebis(3-methoxysalicylideneaminato) dianion], were measured at the temperatures from 0.5 to 300 K by adiabatic calorimetry. An antiferromagnetic phase transition was observed at T {sub N} = 8.29 K. Above T {sub N}, a heat capacity tail arising from the short-range-order effect of the spins was found, which is characteristic of two-dimensional magnets. The magnetic enthalpy and entropy were evaluated to be {delta}H = 373 J mol{sup -1} and {delta}S = 31.3 J K{sup -1} mol{sup -1}, respectively. The experimental magnetic entropy is in good agreement with {delta}S = R ln (5 x 5 x 2) (=32.5 J K{sup -1} mol{sup -1}; R being the gas constant), which is expected for the metal complex with two Mn(III) ions in high spin state (spin quantum number S = 2) and one Fe(III) ion in low spin state (S = 1/2). The spin wave analysis suggests that the complex shows three-dimensional antiferromagnetic order below T {sub N}. The heat capacity tail above T {sub N} was decreased by grinding and pressurizing the crystal. This mechanochemical effect would originate in the increase of lattice defects and imperfections in the crystal lattice, leading to decrease of the magnetic heat capacity and hence the magnetic enthalpy and entropy.

  4. Heat capacities and entropies from 8 to 1000 K of langbeinite (K2Mg2(SO4)3), anhydrite (CaSO4) and of gypsum (CaSO4·2H2O)

    Science.gov (United States)

    Robie, Richard A.; Russell-Robinson, Susan; Hemingway, Bruce S.

    1989-01-01

    Heat capacities of K2Mg2(SO4)3 (langbeinite) and CaSO4 (anhydrite) were measured from approximately 8 to 1000 K by combined adiabatic shield calorimetry (8-365 K) and differential scanning calorimetry (350-1000 K). Heat capacities were also measured on natural crystals of gypsum (CaSO4 · 2H2O) between 8.1 and 323.5 K. The molar entropies at 298.15 K, Smo(298.15 K), are 378.8 ± 0.6, 107.4 ± 0.2 and 193.8 ± 0.3 J K−1 mol−1 for langbeinite, anhydrite and gypsum, respectively. The heat capacity in J K−1 mol−1 of langbeinite can be represented by the equation Cp,mo(K2Mg2(SO4)3T) = 535.9 + 0.11011T-1.0200 × 106/T2-4.909 × 10−5T2 -4040.2/T0.5 between 300 and 1000 K with an average deviation of ± 0.4%. For anhydrite the heat capacity between 300 and 1000 K is given by Cp,mo(CaSO4,T) = 372.8 - 0.1574 T +1.695 × 106/T2 + 7.993 × 10−5T2 - 4330.8/T0.5 with an average deviation of ±0.4%.

  5. Calculating in situ density and heat capacity of rocks with GMIN: new type of input data for thermomechanical modeling of subduction zones

    Science.gov (United States)

    Burchard, M.; Gerya, T.

    2003-04-01

    The technique of minimizing the Gibbs free energy of specified rock compositions by varying the amounts and compositions of coexisting phases has provided new insights and possibilities for petrological investigations. For thermomechanical modeling of subduction zone processes density, isobaric heat capacity, thermal expansion and compressibility can then be extracted as a function of the amounts and compositions of coexisting phases [1]. At present two programs offer the possibility of calculating phase diagrams with this technique, Holland and Powell's Thermocalc [2] and De Capitani's Theriac/Domino [3] package. The first one is a command line program producing a text output which can be converted to graphics with a user-written MathematicaTM program. It uses the Holland and Powell data base [2]. De Capitani's program is distributed as a Fortran 77 source code and uses the Berman database. Neither of these programs offers interfaces for use with geodynamic modeling programs. We have therefore enhanced our new Gibbs minimization program GMin [4] with an interface able to transfer density, entahalpy and volume values into databases or other programs. The minimization algorithm of our program is based on the de Capitani method [3], modified and adapted for the Holland and Powell database [2]. To achieve rapid convergence and stability of minimization we have optimized the computing strategy for models of solid solutions used in [2]. The standard program is divided in two parts, a front end and a calculation program controlled by the front end program. This construction opens the possibility of starting up several calculations in parallel on different computers and different operating systems. In this way large numbers of calculations can be performed on normal PC-networks (servers and clients) controlled by only one front end program. The front end is able to create pressure and temperature ordered databases containing density, enthalpy, volume and composition which

  6. Single-crystal growth, crystallography, magnetic susceptibility, heat capacity, and thermal expansion of the antiferromagnetic S=1 chain compound CaV[subscript 2]O[subscript 4

    Energy Technology Data Exchange (ETDEWEB)

    Niazi, A.; Bud' ko, S.L.; Schlagel, D.L.; Yan, J.Q.; Lograsso, T.A.; Kreyssig, A.; Das, S.; Nandi, S.; Goldman, A.I.; Honecker, A.; McCallum, R.W.; Reehuis, M.; Pieper, O.; Lake, B.; Johnston, D.C.; (Ames; Gö); (tingen); (HMI); (MXPL-F)

    2009-05-01

    The compound CaV{sub 2}O{sub 4} contains V{sup +3} cations with spin S=1 and has an orthorhombic structure at room temperature containing zigzag chains of V atoms running along the c axis. We have grown single crystals of CaV{sub 2}O{sub 4} and report crystallography, static magnetization, magnetic susceptibility x, ac magnetic susceptibility, heat capacity C{sub p}, and thermal expansion measurements in the temperature T range of 1.8--350 K on the single crystals and on polycrystalline samples. An orthorhombic-to-monoclinic structural distortion and a long-range antiferromagnetic (AF) transition were found at sample-dependent temperatures T{sub S}{approx}108--145 K and T{sub N}{approx}51--76 K, respectively. In two annealed single crystals, another transition was found at {approx}200 K. In one of the crystals, this transition is mostly due to V{sub 2}O{sub 3} impurity phase that grows coherently in the crystals during annealing. However, in the other crystal the origin of this transition at 200 K is unknown. The x(T) shows a broad maximum at {approx}300 K associated with short-range AF ordering and the anisotropy of x above T{sub N} is small. The anisotropic x(T{yields}0) data below T{sub N} show that the (average) easy axis of the AF magnetic structure is the b axis. The C{sub p}(T) data indicate strong short-range AF ordering above T{sub N}, consistent with the x(T) data. We fitted our x data by a J{sub 1}-J{sub 2} S=1 Heisenberg chain model, where J{sub 1}(J{sub 2}) is the (next)-nearest-neighbor exchange interaction. We find J{sub 1}{approx}230 K and surprisingly, J{sub 2}/J{sub 1}{approx}0 (or J{sub 1}/J{sub 2}{approx}0). The interaction J{sub {perpendicular}} between these S=1 chains leading to long-range AF ordering at T{sub N} is estimated to be J{sub {perpendicular}}/J{sub 1}{approx_equal}0.04.

  7. 乙基甲基咪唑磷酸二乙酯+水/乙醇/甲醇二元溶液混合热及比热容的测量与关联%Measurement and correlation of mixing heat and specific heat capacity for binary solution: 1-ehtyl-3-methylimidazolium diethylphosphate +H2O/C2H5OH/ CH3OH

    Institute of Scientific and Technical Information of China (English)

    赵健华; 晏双华; 赵宗昌

    2011-01-01

    离子液体是一类新型绿色溶剂,具有蒸汽压极低,不挥发,不易燃,宽液程和良好的热稳定性,对许多有机物和无机物有良好的溶解性.前期的研究发现,离子液体乙基甲基咪唑磷酸二乙酯[EMIM][DEP]与H2O、C2H5OH和CH3OH有良好的溶解性,所构成的二元溶液表现出对拉乌尔定律显著的负偏差,这些性质使得离子液体[EMIM][DEP]有可能成为吸收制冷/热泵循环的新型吸收剂.二元工质溶液[EMIM] [DEP]+H2O/C2H5OH/CH3OH的混合热以及比热容是分析吸收制冷/热泵性能重要的热力学基础数据之一.本文采用绝热量热法对[EMIM][DEP]分别与水,乙醇和甲醇所构成的3个二元溶液体系,在25℃以及不同浓度下的混合热进行了测量,并采用Redlich-Kister方程对数据进行了关联.实验结果表明,[EMIM][DEP]与水,乙醇和甲醇的混合过程均为放热过程,混合热大小次序是H2O> CH3OH> C2H5OH.对3个二元溶液体系在不同温度和浓度下的比热容进行了测量,并采用浓度的多项式函数对其进行关联.结果发现,离子液体溶液的比热容随温度的增加而线性增加,随离子液体的含量增加而降低.%Ionic liquid is a new kind of green solvent. It has many advantages, such as negligible vapor pressure, non-flammability, wide liquid state range, thermal stability and good solubility to many kinds of organic or inorganic solvent. Ionic liquids, l-ehtyl-3-methylimidazolium diethylphosphate ([EMIM][DEP]) has good solubility to water, ethanol or methanol and corresponding binary solutions, [EMIM][DEP]+ H2O /C2H5OH/ CH3OH displayed a considerable negative deviation from Raoult's law in our previous study, which indicated that [EMIM][DEP] had the potential to be a new absorbent for absorption refrigeration or absorption heat pump. The mixing heat and specific heat capacity of [EMIM][DEP] with H2O/C2H5OH/ CH3OH are one of important basic physical properties for simulating thermodynamic

  8. Quantitative Relationship between NTU and Fluid Temperature and Ratio of Heat Capacity vs.Flow Rate%NTU与流体温度及热容流率比间的定量关系研究

    Institute of Scientific and Technical Information of China (English)

    张洪流; 赵权; 陈明功

    2011-01-01

    The calculation of operation model of heat exchanger usually needs repetitious trial and error or look up e - NTU figure, which is complex and has some error. In order to avoid these problems, the quantitative relationship between the number of heat - transfer units ( NTU) and fluid temperature and the ratio of heat capacity vs. Flow rate for one -way no phase changed heat exchanger was studied. By this way, a formula was obtained. Then the formula and the chart were verified and analyzed by an practical example. The results showed that by u-sing the formula to calculate the fluid temperature and consumption of media can avoid repetitious trial and error or look up e - NTU figure. The method is simpler and more precocious. Ratio of heat capacity vs. Flow rate has a critical value. In order to get economical heat transfer process, the ratio of heat capacity vs. Flow rate should be kept below its critical value in process of heat exchanger design and selection.%换热器操作型问题计算往往需反复试差或查取算图,计算繁复或有误差.为回避试差或查算图,对单程无相变换热器传热单元数与流体温度及热容流率比间的定量关系进行研究,导出了计算公式,对导出公式及获得的计算图表通过实例检验和分析.研究结果表明:用导出公式确定流体温度及介质消耗量可避免试差或查算图,方法简便、精度高;热客流率比存在临界值,在换热器设计及应用过程中需控制在临界值以下,以确保换热过程的经济性.

  9. Realistic Heat Capacity Effects in Two Phase Aluminum Dust Detonations%真实比热模型中铝粉尘两相爆轰波的数值研究

    Institute of Scientific and Technical Information of China (English)

    滕宏辉; 杨旸; 姜宗林

    2013-01-01

    采用多流体模型对铝粉尘两相爆轰波进行数值模拟,研究颗粒能量计算方法对起爆和传播过程的影响.以前的固相颗粒能量的计算一般采用固定比热方法,本文采用随温度变化的真实比热.由于铝颗粒及其产物氧化铝的比热变化很大,模拟得到的爆轰波的速度、压力和波后参数变化和采用固定比热存在较大的差异.变比热计算得到的爆轰波压力、传播速度和实验结果更加接近,而固定比热的计算方法会对这些参数造成高估.对爆轰波的形成进行研究,发现起爆距离主要受起爆能量影响,但是相对于固定比热模型,采用变比热模型得到的起爆距离较短.%Two phase detonations of aluminum dust are simulated in a multi-fluid model to study particle energy calculation methods. In previous studies heat capacities of solid particles are constants, while realistic heat capacities change with temperature. In this simulation, effects of realistic heat capacities are studied. Numerical results show that detonation parameters are influenced significantly. The results with realistic capacities are close to experiments, while the results with fixed capacities overestimate pressure and detonation velocity. In detonation initiation, run-up distance is mainly decide by ignition energy, while realistic effect makes the distance shorter than that in the fixed heat capacity case.

  10. 沼气池散热量与内部温度场的数值模拟研究%Numerical Simulation of Heat Dissipating Capacity and Internal Temperature Field for Biogas Digester

    Institute of Scientific and Technical Information of China (English)

    张富强; 孟祥睿; 魏新利

    2012-01-01

    The heat dissipating capacity of insulation layer with different materials and different thicknesses and the internal temperature field of biogas digester were numerically simulated by using the Fluent software based on the climatic conditions in Zhengzhou. The results showed that when the others conditions were the same, the heat dissipating capacity of concrete biogas digester was about 4.66 times of that of heat dissipation of foaming cement biogas digester, so the material with small coefficient of thermal conductivity can be chosen as the insulation layer; the thickness of the insulation layer had few influence on the heat dissipating capacity of biogas digester, so the thickness of insulation layer should be chosen according to actual conditions; the temperature field in the biogas digester distributed unevenly and can not reach the set temperature for biogas fermentation, so the digester needed to add the mixer to achieve the purpose of uniform mixing.%以郑州地区的气象条件为参数,使用Fluent软件对沼气池不同材料、不同厚度的保温层及沼气池内部温度场的数值进行了模拟研究.结果表明:其他条件一定时,混凝土沼气池的散热量约为发泡水泥沼气池的4.66倍,可选择导热系数小的材料作为保温层;保温层的厚度对沼气池的散热量影响不大,根据实际条件选择厚度;池内温度场的分布不均匀,没有达到沼气发酵设定的温度,因此需要增加搅拌器以达到混合均匀的目的.

  11. Heat capacities and thermodynamic functions for beryl, Be3Al2Si6O18, phenakite, Be2SiO4, euclase, BeAlSiO4(OH), bertrandite, Be4Si2O7(OH)2, and chrysoberyl, BeAl2O4.

    Science.gov (United States)

    Hemingway, B.S.; Barton, M.D.; Robie, R.A.; Haselton, H.T.

    1986-01-01

    The heat capacities of beryl, phenakite, euclase and bertrandite have been measured between approx 5 and 800 K by combined quasi-adiabatic cryogenic calorimetry and differential scanning calorimetry. The heat capacities of chrysoberyl have been measured from 340 to 800 K. The resulting data have been combined with solution and phase-equilibrium experimental data and simultaneously adjusted using the programme PHAS20 to provide an internally consistent set of thermodynamic properties for several important beryllium phases. The experimental heat capacities and tables of derived thermodynamic properties are presented.-J.A.Z.

  12. Station Capacity

    DEFF Research Database (Denmark)

    Landex, Alex

    2011-01-01

    Stations are often limiting the capacity of railway networks. This is due to extra need of tracks when trains stand still, trains turning around, and conflicting train routes. Although stations are often the capacity bottlenecks, most capacity analysis methods focus on open line capacity. Therefore......, this paper presents methods to analyze station capacity. Four methods to analyze station capacity are developed. The first method is an adapted UIC 406 capacity method that can be used to analyze switch zones and platform tracks at stations that are not too complex. The second method examines the need...... the probability of conflicts and the minimum headway times into account. The last method analyzes how optimal platform tracks are used by examining the arrival and departure pattern of the trains. The developed methods can either be used separately to analyze specific characteristics of the capacity of a station...

  13. Dielectric and magnetic properties of NiFe{sub 2}O{sub 4} at 2.45 GHz and heating capacity for potential uses under microwaves

    Energy Technology Data Exchange (ETDEWEB)

    Polaert, Isabelle, E-mail: isabelle.polaert@insa-rouen.fr [LSPC (Laboratoire de Sécurité des Procédés Chimiques). Institut National des Sciences Appliquées INSA Rouen (France); Bastien, Samuel [Département de génie chimique et de génie biotechnologique, Université de Sherbrooke, Sherbrooke, Québec, Canada J1K 2R1 (Canada); Legras, Benoit [LSPC (Laboratoire de Sécurité des Procédés Chimiques). Institut National des Sciences Appliquées INSA Rouen (France); Département de génie chimique et de génie biotechnologique, Université de Sherbrooke, Sherbrooke, Québec, Canada J1K 2R1 (Canada); Estel, Lionel [LSPC (Laboratoire de Sécurité des Procédés Chimiques). Institut National des Sciences Appliquées INSA Rouen (France); Braidy, Nadi [Département de génie chimique et de génie biotechnologique, Université de Sherbrooke, Sherbrooke, Québec, Canada J1K 2R1 (Canada)

    2015-01-15

    This paper presents the dielectric and magnetic properties, measured at 2.45 GHz, of a new nickel ferrite, NiFe{sub 2}O{sub 4}, synthetized by plasma technology. These properties were measured by the small perturbation method in a resonant cavity, from 293 to 513 K. Using these values, the adiabatic heating of nanoparticles of NiFe{sub 2}O{sub 4} under microwave irradiation was also modeled. The wave propagation equation (Maxwell's equation) coupled to the heat transfer in the solid was numerically solved. The influence of parameters such as the bed volume, its porosity, the microwave incident power or the microwave system geometry is discussed. This study demonstrates that NiFe{sub 2}O{sub 4} nanoparticles can be rapidly heated up to at least 513 K under microwaves and can probably achieve higher temperatures according to the thermal insulation. The magnetic contribution to heating overcomes the dielectric one in the explored temperature range. Very efficient energy yield (>90%) can then be achieved when the magnetic field position is centered over the bed. - Highlights: • A new nickel ferrite, NiFe{sub 2}O{sub 4}, was synthetized by plasma technology. • Its dielectric and magnetic properties were measured at 2.45 GHz. • The adiabatic heating of nanoparticles of NiFe{sub 2}O{sub 4} under microwave was modeled. • NiFe{sub 2}O{sub 4} nanoparticles can be rapidly heated up to at least 513 K. • The magnetic contribution to heating overcomes the dielectric one from 293 K to 513 K.

  14. Station Capacity

    DEFF Research Database (Denmark)

    Landex, Alex

    2011-01-01

    Stations are often limiting the capacity of railway networks. This is due to extra need of tracks when trains stand still, trains turning around, and conflicting train routes. Although stations are often the capacity bottlenecks, most capacity analysis methods focus on open line capacity. Therefore......, this paper presents methods to analyze station capacity. Four methods to analyze station capacity are developed. The first method is an adapted UIC 406 capacity method that can be used to analyze switch zones and platform tracks at stations that are not too complex. The second method examines the need...... for platform tracks and the probability that arriving trains will not get a platform track immediately at arrival. The third method is a scalable method that analyzes the conflicts in the switch zone(s). In its simplest stage, the method just analyzes the track layout while the more advanced stages also take...

  15. The temperature response of CO2 assimilation, photochemical activities and Rubisco activation in Camelina sativa, a potential bioenergy crop with limited capacity for acclimation to heat stress.

    Science.gov (United States)

    Carmo-Silva, A Elizabete; Salvucci, Michael E

    2012-11-01

    The temperature optimum of photosynthesis coincides with the average daytime temperature in a species' native environment. Moderate heat stress occurs when temperatures exceed the optimum, inhibiting photosynthesis and decreasing productivity. In the present study, the temperature response of photosynthesis and the potential for heat acclimation was evaluated for Camelina sativa, a bioenergy crop. The temperature optimum of net CO(2) assimilation rate (A) under atmospheric conditions was 30-32 °C and was only slightly higher under non-photorespiratory conditions. The activation state of Rubisco was closely correlated with A at supra-optimal temperatures, exhibiting a parallel decrease with increasing leaf temperature. At both control and elevated temperatures, the modeled response of A to intercellular CO(2) concentration was consistent with Rubisco limiting A at ambient CO(2). Rubisco activation and photochemical activities were affected by moderate heat stress at lower temperatures in camelina than in the warm-adapted species cotton and tobacco. Growth under conditions that imposed a daily interval of moderate heat stress caused a 63 % reduction in camelina seed yield. Levels of cpn60 protein were elevated under the higher growth temperature, but acclimation of photosynthesis was minimal. Inactivation of Rubisco in camelina at temperatures above 35 °C was consistent with the temperature response of Rubisco activase activity and indicated that Rubisco activase was a prime target of inhibition by moderate heat stress in camelina. That photosynthesis exhibited no acclimation to moderate heat stress will likely impact the development of camelina and other cool season Brassicaceae as sources of bioenergy in a warmer world.

  16. Effect of variable thermal conductivity and specific heat capacity on the calculation of the critical metal hydride thickness for Ti1.1CrMn

    DEFF Research Database (Denmark)

    Mazzucco, Andrea; Rokni, Masoud

    2014-01-01

    High pressure metal hydrides have been recently considered as one of the most promising hydrogen solid storage options for on - board applications. Unfortunately the high purchasing costs related to these materials and the complexity related to building a scaled high pressure tank system...... model is applied to the metal hydride system, with Ti 1.1 CrMn as the absorbing alloy, to predict the weight fraction of absorbed hydrogen and solid bed temperat ure . Dependencies of thermal conductivity and specific heat capacity upon pressure and hydrogen content respectively , are accounted for...

  17. Inhibition of Sonic Hedgehog Signaling Pathway by Thiazole Antibiotic Thiostrepton Attenuates the CD44+/CD24-Stem-Like Population and Sphere-Forming Capacity in Triple-Negative Breast Cancer

    Directory of Open Access Journals (Sweden)

    Na Yang

    2016-03-01

    Full Text Available Background/Aim: Triple-negative breast cancer (TNBC represents a particular clinical challenge because these cancers do not respond to endocrine therapy or other available targeted agents. The lack of effective agents and obvious targets are major challenges in treating TNBC. In this study we explored the cytostatic effect of thiazole ring containing antibiotic drug thiostrepton on TNBC cell lines and investigated the molecular mechanism. Methods: Cell viability was measured by MTT assay. Cell surface marker was monitored by FCM. Western blot was applied to assess the protein expression levels of target genes. Results: We found that thiostrepton remarkably suppressed the CD44+/CD24- stem-like population and sphere forming capacity of TNBC cell lines. Notably, we showed for the first time that thiostrepton exerted its pharmacological action by targeting sonic hedgehog (SHH signaling pathway. Thiostrepton repressed SHH ligand expression and reduced Gli-1 nuclear localization in TNBC cell line. Furthermore, the downstream target of SHH signaling undergone dose-dependent, rapid, and sustained loss of mRNA transcript level after thiostrepton treatment. Finally, we showed that SHH ligand was essential for maintaining CD44+/CD24- stem-like population in TNBC cell line. Conclusion: We conclude that thiostrepton suppresses the CD44+/CD24- stem-like population through inhibition of SHH signaling pathway. Our results give a new insight into the mechanism of thiostrepton anti-tumor activity and suggest thiostrepton as a promising agent that targets hedgehog signaling pathway in TNBC.

  18. Na 2 Ti 3 O 7 Nanoplatelets and Nanosheets Derived from a Modified Exfoliation Process for Use as a High-Capacity Sodium-Ion Negative Electrode

    Energy Technology Data Exchange (ETDEWEB)

    Ko, Jesse S.; Doan-Nguyen, Vicky V. T.; Kim, Hyung-Seok; Muller, Guillaume A.; Serino, Andrew C.; Weiss, Paul S.; Dunn, Bruce S.

    2017-01-18

    The increasing interest in Na-ion batteries (NIBs) can be traced to sodium abundance, its low cost compared to lithium, and its intercalation chemistry being similar to that of lithium. We report that the electrochemical properties of a promising negative electrode material, Na2Ti3O7, are improved by exfoliating its layered structure and forming 2D nanoscale morphologies, nanoplatelets, and nanosheets. Exfoliation of Na2Ti3O7 was carried out by controlling the amount of proton exchange for Na+ and then proceeding with the intercalation of larger cations such as methylammonium and propylammonium. An optimized mixture of nanoplatelets and nanosheets exhibited the best electrochemical performance in terms of high capacities in the range of 100–150 mA h g–1 at high rates with stable cycling over several hundred cycles. These properties far exceed those of the corresponding bulk material, which is characterized by slow charge-storage kinetics and poor long-term stability. The results reported in this study demonstrate that charge-storage processes directed at 2D morphologies of surfaces and few layers of sheets are an exciting direction for improving the energy and power density of electrode materials for NIBs.

  19. Cryogenic heat transfer

    CERN Document Server

    Barron, Randall F

    2016-01-01

    Cryogenic Heat Transfer, Second Edition continues to address specific heat transfer problems that occur in the cryogenic temperature range where there are distinct differences from conventional heat transfer problems. This updated version examines the use of computer-aided design in cryogenic engineering and emphasizes commonly used computer programs to address modern cryogenic heat transfer problems. It introduces additional topics in cryogenic heat transfer that include latent heat expressions; lumped-capacity transient heat transfer; thermal stresses; Laplace transform solutions; oscillating flow heat transfer, and computer-aided heat exchanger design. It also includes new examples and homework problems throughout the book, and provides ample references for further study.

  20. Heat capacities and thermodynamic functions of new nanosized ferro-chromo-manganites LaM0.5 IIFeCrMnO6.5 (MII-Mg, Ca, Sr, Ba)

    Science.gov (United States)

    Kasenov, B. K.; Kasenova, Sh. B.; Sagintaeva, Zh. I.; Turtubaeva, M. O.; Kakenov, K. S.; Esenbaeva, G. A.

    2017-03-01

    The heat capacities of nanosized ferro-chromo-manganites LaM0.5 IIFeCrMnO6.5 (MII-Mg, Ca, Sr, Ba) are measured via dynamic calorimetry in the temperature range of 298.15-673 K using an IT-S-400 instrument. It is established that the C°p f( T) function of LaM0.5 IIFeCrMnO6.5 (MII-Mg, Ca, Sr, Ba) has λ-type effects, due probably to phase transitions of the second order. Considering the temperatures of the phase transitions, equations of the heat capacity of ferro-chromo-manganites LaM0.5 IIFeCrMnO6.5 (MII-Mg, Ca, Sr, Ba) as a function of temperature are derived on the basis of experimental data. Thermodynamic functions H°( T)- H°(298.15), S°( T), and V xx( T) are calculated in the temperature range of 298.15-675 K.

  1. Carrying Capacity

    DEFF Research Database (Denmark)

    Schroll, Henning; Andersen, Jan; Kjærgård, Bente

    2012-01-01

    A spatial planning act was introduced inIndonesia 1992 and renewed in 2008. It emphasised the planning role of decentralised authorities. The spatial planning act covers both spatial and environmental issues. It defines the concept of carrying capacity and includes definitions of supportive...... carrying capacity (SCC) and assimilative carrying capacity (ACC). The act mandates that the latter two aspects must be taken into consideration in the local spatial plans. The present study aimed at developing a background for a national guideline for carrying capacity in Indonesian provinces and districts...... standard or governmental political objective exists. In most cases it was possible to select a set of indicators, including thresholds that are workable in a carrying capacity planning at the local administrative levels. Not all relevant sectors at the decentralized level were included. Indicators of SCC...

  2. Review of heat capacities of magnetic regenerator materials at 4K and the relevant applications%4K磁性蓄冷材料比热及应用综述

    Institute of Scientific and Technical Information of China (English)

    程远; 张鹏; 夏再忠

    2012-01-01

    蓄冷材料常应用于超导磁体、低温制冷机等低温装置.因其低温下的高比热特性,单位体积可储存较大冷量.文中针对4K温度范围的磁性蓄冷材料的比热及其应用进行了综述,讨论的磁性蓄冷材料主要包括稀土金属元素构成的金属间化合物.简要介绍了低温比热理论,给出了相关磁性蓄冷材料的德拜温度、相变温度、晶格结构.针对不同材料应用于4K制冷机的情况进行了总结分析.最后,概括了近年来磁性蓄冷材料在超导领域的应用.%Owing to phase transition at Curie point or Neel point, magnetic regenerator materials are often employed in cryogenic applications (like superconducting magnets and cryocoolers) for large cold energy storage capacity. These materials being discussed mainly include intermetallics of rare earth metal compounds. Heat capacity theory at low temperatures and Debye temperature, phase - transition temperature and lattice structure of magnetic regenerator materials were introduced briefly. The performance of 4K cryocoolers with magnetic regenerator materials and the utilization of large heat capacity materials for improving transient stability of superconducting magnets were summarized.

  3. 不同浓度配比硼酸溶液比定压热容的实验测量%Experimental measurement of isobaric heat capacity of boric acid solution

    Institute of Scientific and Technical Information of China (English)

    宋星佑; 苏超; 刘向阳; 何茂刚

    2015-01-01

    采用高精度的流动型量热法测量了温度在303~396 K、压力在0.1~0.5 MPa时,质量摩尔浓度分别为0.648、3.700(无杂质)和3.700(含杂质)mol/kg 三种配比硼酸溶液的比定压热容。实验系统的温度、压力、比定压热容的测量不确定度分别小于0.05 K、18 kPa、0.28%。为了验证实验系统的测量精度和可靠性,测量了温度为296~396 K、压力为0.1~6.0 MPa内纯水的比定压热容,与 NIST 值相比的相对偏差绝对平均值为0.41%。%Isobaric heat capacities of boric acid solution at the concentrations of 0.648,3.700 (no impurities)and 3.700 mol/kg (containing impurities) were measured using high accuracy flow calorimeter at temperatures of 303-396 K and pressures of 0.1-0.5 MPa.The uncertainties of temperature,pressure,and isobaric haet capacity were less than ±0.05 K,±18 kPa and ±0.28 %, respectively.In order to evaluate the reliability of the experimental system,isobaric heat capacities of pure water at temperatures of 296-396 K and pressures from atmosphere to 6.0 MPa were measured, and the measured average relative deviation from the NIST literature values is within 0.41%.

  4. Serotonin transporter binding in the hypothalamus correlates negatively with tonic heat pain ratings in healthy subjects: A [11C]DASB PET study

    DEFF Research Database (Denmark)

    Kupers, Ron; Frokjaer, Vibe G.; Erritzoe, David

    2010-01-01

    analysis revealed a positive correlation between pain tolerance and SERT binding in the hypothalamus (r = 0.53; p = 0.02) although this was not seen in the parametric analysis. These data extend our earlier observation that cortical 5-HT receptors co-determine responses to tonic but not to phasic pain......There is a large body of evidence that the serotonergic system plays an important role in the transmission and regulation of pain. Here we used positron emission tomography (PET) with the serotonin transporter (SERT) tracer [11C]DASB to study the relationship between SERT binding in the brain...... and responses to noxious heat stimulation in a group of 21 young healthy volunteers. Responses to noxious heat stimuli were assessed in a separate psychophysical experiment and included measurements of pain threshold, pain tolerance, and responses to phasic noxious heat stimuli and to a long lasting (7-minute...

  5. High Capacity, Superior Cyclic Performances in All-Solid-State Lithium-Ion Batteries Based on 78Li2S-22P2S5 Glass-Ceramic Electrolytes Prepared via Simple Heat Treatment.

    Science.gov (United States)

    Zhang, Yibo; Chen, Rujun; Liu, Ting; Shen, Yang; Lin, Yuanhua; Nan, Ce-Wen

    2017-08-30

    Highly Li-ion conductive 78Li2S-22P2S5 glass-ceramic electrolytes were prepared by simple heat treatment of the glass phase obtained via mechanical ball milling. A high ionic conductivity of ∼1.78 × 10(-3) S cm(-1) is achieved at room temperature and is attributed to the formation of a crystalline phase of high lithium-ion conduction. All-solid-state lithium-ion batteries based on these glass-ceramic electrolytes are assembled by using Li2S nanoparticles or low-cost commercially available FeS2 as active cathode materials and Li-In alloys as anode. A high discharge capacity of 535 mAh g(-1) is achieved after at least 50 cycles for the all-solid-state cells with Li2S as cathode materials, suggesting a rather high capacity retention of 97.4%. Even for the cells using low-cost FeS2 as cathode materials, same high discharge capacity of 560 mAh g(-1) is also achieved after at least 50 cycles. Moreover, the Coulombic efficiency remain at ∼99% for these all-solid-state cells during the charge-discharge cycles.

  6. 压水堆余热排出换热器性能研究%Numerical Investigation of Residual Heat Removal Heat Exchange Capacity in Pressurized Water Reactor Plants

    Institute of Scientific and Technical Information of China (English)

    丘锦萌; 李军; 王晓江; 王志刚

    2013-01-01

    以压水堆余热排出系统为对象,建立管壳式换热器的数学模型.与换热器设计软件HTRI的计算结果进行对比,结果表明该模型可以准确预测管壳式换热器的管壳侧出口温度.总传热系数敏感性计算表明,该参数随管壳侧流量变化而变化,在换热器性能预测时不能当作常数处理,应与工况进行耦合计算.当管壳侧体积流量小于1000 m3/h时,总传热系数对流量较为敏感;当体积流量大于1000m3/h时,流量的影响则相对较弱.该模型为预测换热器其他工况的换热性能提供基础,为换热设备调试提供指导,为核电厂设计验证及高效安全运行提供可靠依据.%Mathematical model is established for shell and tube heat exchanger of PWR residual heat removal system. Comparison with the calculated results from the design software HTRI for the heat exchanger is conducted, and the results show that outlet temperatures of shell and tube side are precisely predicted. The calculation of overall heat exchanger coefficient sensibility shows that this parameter varies with the flow rates of tube and shell side and it is not advisable to keep it as constant value in the simulation. The overall heat exchanger coefficient shall be coupled with the heat exchanger flow and heat exchanging conditions during calculation. The overall coefficient is extremely dependent on the flowrates which is less than 1000 m3/h while it seems to be independent with the higher flowrates. The model can be easily employed to predict other system conditions elsewhere and provide the convenient way for the plant test, design verification and high efficient operation of nuclear power plants.

  7. 氢腐蚀分层对换热器筒体承载能力的影响%Influence of bearing capacity of heat exchanger shell caused by hydrogen corrosion delaminating crack

    Institute of Scientific and Technical Information of China (English)

    何家胜; 李超; 朱晓明; 陈伟; 路远明; 杨峰

    2013-01-01

    To explore the influence of hydrogen corrosion delaminating crack on the mechanical properties and bearing capacity in operation of the layered heat exchanger shell, the material capability of layered heat exchanger shell was analyzed by using chemical constituents analysis, hardness test, tensile tests, Charpy V-notch pendulum impact test. The finite element method was used to calculate the stress distribution of heat exchanger shell and to discuss the stress intensity factors of crack tip. The results show that the Mn element is lower in the chemical constituents, other elements accord with the National Standards; the material hardness meets the requirements, but the toughness declines obviously. The material of heat layered exchanger shell is deteriorated by the hydrogen corrosion, which destroys the continuity and uniformity of the material, decreases the ultimate strength, but increases the yield-strength ratio. The film stress state is destroyed, and material resistance to crack growth decreases. The hydrogen corrosion delaminating crack causes biggish partial stress and makes bearing capacity of the heat exchanger shell decrease.%为了解换热器筒体发生氢腐蚀分层后,其简体局部材料的性能发生的变化及对换热器运行中的承载能力带来的影响,采用化学成分分析、硬度测试、拉伸试验、夏比V口冲击韧性试验等方法对换热器筒体材料的性能进行了分析;运用有限元分析方法计算了简体分层处的应力分布,并探讨了裂纹尖端应力强度因子的变化情况.研究结果表明:材料化学成分中除Mn元素的含量偏低外,其它元素含量符合国家标准;材料的硬度符合要求,材料的强度极限降低,屈强比上升,韧性明显降低.氢腐蚀分层使换热器筒体材料局部劣化,破坏了材料的均匀性和连续性,破坏了简体的薄膜应力状态,产生了较大的局部应力,使换热器筒体承载能力下降.

  8. Heat training increases exercise capacity in hot but not in temperate conditions: a mechanistic counter-balanced cross-over study.

    Science.gov (United States)

    Keiser, Stefanie; Flück, Daniela; Hüppin, Fabienne; Stravs, Alexander; Hilty, Matthias P; Lundby, Carsten

    2015-09-01

    The aim was to determine the mechanisms facilitating exercise performance in hot conditions following heat training. In a counter-balanced order, seven males (V̇o2max 61.2 ± 4.4 ml·min(-1)·kg(-1)) were assigned to either 10 days of 90-min exercise training in 18 or 38°C ambient temperature (30% relative humidity) applying a cross-over design. Participants were tested for V̇o2max and 30-min time trial performance in 18 (T18) and 38°C (T38) before and after training. Blood volume parameters, sweat output, cardiac output (Q̇), cerebral perfusion (i.e., middle cerebral artery velocity [MCAvmean]), and other variables were determined. Before one set of exercise tests in T38, blood volume was acutely expanded by 538 ± 16 ml with an albumin solution (T38A) to determine the role of acclimatization induced hypervolemia on exercise performance. We furthermore hypothesized that heat training would restore MCAvmean and thereby limit centrally mediated fatigue. V̇o2max and time trial performance were equally reduced in T38 and T38A (7.2 ± 1.6 and 9.3 ± 2.5% for V̇o2max; 12.8 ± 2.8 and 12.9 ± 2.8% for time trial). Following heat training both were increased in T38 (9.6 ± 2.1 and 10.4 ± 3.1%, respectively), whereas both V̇o2max and time trial performance remained unchanged in T18. As expected, heat training augmented plasma volume (6 ± 2%) and mean sweat output (26 ± 6%), whereas sweat [Na(+)] became reduced by 19 ± 7%. In T38 Q̇max remained unchanged before (21.3 ± 0.6 l/min) to after (21.7 ± 0.5 l/min) training, whereas MCAvmean was increased by 13 ± 10%. However, none of the observed adaptations correlated with the concomitant observed changes in exercise performance. Copyright © 2015 the American Physiological Society.

  9. Heat capacity and magnetic phase diagram of the low-dimensional antiferromagnet Y{sub 2}BaCuO{sub 5}

    Energy Technology Data Exchange (ETDEWEB)

    Knafo, W; Meingast, C; Wolf, Th; Loehneysen, H v [Forschungszentrum Karlsruhe, Institut fuer Festkoerperphysik, D-76021 Karlsruhe (Germany); Inaba, A [Research Center for Molecular Thermodynamics, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan)

    2008-08-20

    A study by specific heat of a polycrystalline sample of the low-dimensional magnetic system Y{sub 2}BaCuO{sub 5} is presented. Magnetic fields up to 14 T are applied and permit us to extract the (T,H) phase diagram. Below {mu}{sub 0}H* approx. = 2 T, the Neel temperature, associated with a three-dimensional antiferromagnetic long-range ordering, is constant and equals T{sub N} = 15.6 K. Above H*, T{sub N} increases linearly with H and a field-induced increase of the entropy at T{sub N} is related to the presence of an isosbestic point at T{sub X} approx. = 20 K, where all the specific-heat curves cross. A comparison is made between Y{sub 2}BaCuO{sub 5} and the quasi-two-dimensional magnetic systems BaNi{sub 2}V{sub 2}O{sub 8}, Sr{sub 2}CuO{sub 2}Cl{sub 2} and Pr{sub 2}CuO{sub 4}, for which very similar phase diagrams have been reported. An effective field-induced magnetic anisotropy is proposed to explain these phase diagrams.

  10. Carrying Capacity

    DEFF Research Database (Denmark)

    Schroll, Henning; Andersen, Jan; Kjærgård, Bente

    2012-01-01

    A spatial planning act was introduced inIndonesia 1992 and renewed in 2008. It emphasised the planning role of decentralised authorities. The spatial planning act covers both spatial and environmental issues. It defines the concept of carrying capacity and includes definitions of supportive...... and ACC may increase the political focus on resources and environmental issues and may help to move local authorities towards a more holistic spatial planning approach. A carrying capacity approach could be an inspiration for local spatial planning in developing countries. A spatial planning act...... was introduced inIndonesia 1992 and renewed in 2008. It emphasised the planning role of decentralised authorities. The spatial planning act covers both spatial and environmental issues. It defines the concept of carrying capacity and includes definitions of supportive carrying capacity (SCC) and assimilative...

  11. Non-Debye heat capacity formula refined and applied to GaP, GaAs, GaSb, InP, InAs, and InSb

    Directory of Open Access Journals (Sweden)

    R. Pässler

    2013-08-01

    Full Text Available Characteristic non-Debye behaviors of low-temperature heat capacities of GaP, GaAs, GaSb, InP, InAs, and InSb, which are manifested above all in form of non-monotonic behaviors (local maxima of the respective Cp(T/T3 curves in the cryogenic region, are described by means of a refined version of a recently proposed low-to-high-temperature interpolation formula of non-Debye type. Least-mean-square fittings of representative Cp(T data sets available for these materials from several sources show excellent agreements, from the liquid-helium region up to room temperature. The results of detailed calculations of the respective material-specific Debye temperature curves, ΘD(T, are represented in graphical form. The strong, non-monotonic variations of ΘD(T values confirm that it is impossible to provide reasonable numerical simulations of measured Cp(T dependences in terms of fixed Debye temperatures. We show that it is possible to describe in good approximation the complete Debye temperature curves, from the cryogenic region up to their definitive disappearance (dropping to 0 in the high temperature region, by a couple of unprecedented algebraic formulas. The task of constructing physically adequate prolongations of the low-temperature Cp(T curves up to melting points was strongly impeded by partly rather large differences (up to an order of 10 J/(K·mol between the high-temperature data sets presented in different research papers and/or data reviews. Physically plausible criteria are invoked, which enabled an a priori rejection of a series of obviously unrealistic high-temperature data sets. Residual uncertainties for GaAs and InAs could be overcome by re-evaluations of former enthalpy data on the basis of a novel set of properly specified four-parameter polynomial expressions applying to large regions, from moderately low temperatures up to melting points. Detailed analytical and numerical descriptions are given for the anharmonicity

  12. Dual capacity reciprocating compressor

    Science.gov (United States)

    Wolfe, Robert W.

    1984-01-01

    A multi-cylinder compressor 10 particularly useful in connection with northern climate heat pumps and in which different capacities are available in accordance with reversing motor 16 rotation is provided with an eccentric cam 38 on a crank pin 34 under a fraction of the connecting rods, and arranged for rotation upon the crank pin between opposite positions 180.degree. apart so that with cam rotation on the crank pin such that the crank throw is at its normal maximum value all pistons pump at full capacity, and with rotation of the crank shaft in the opposite direction the cam moves to a circumferential position on the crank pin such that the overall crank throw is zero. Pistons 24 whose connecting rods 30 ride on a crank pin 36 without a cam pump their normal rate with either crank rotational direction. Thus a small clearance volume is provided for any piston that moves when in either capacity mode of operation.

  13. Superconducting gap function in the organic superconductor (TMTSF)2ClO4 with anion ordering; First-principles calculations and quasiclassical analysis for angle-resolved heat capacity

    Science.gov (United States)

    Nagai, Yuki; Nakamura, Hiroki; Machida, Masahiko

    2011-03-01

    We calculate angle-dependent heat capacity in a low magnetic field range on the basis of the Kramer-Pesch approximation together with an electronic structure obtained by first-principles calculations to determine a superconducting gap function of (TMTSF)2ClO4 through its comparisons with experiments. The present comparative studies reveal that a nodal d-wave gap function consistently explains the experimental results for (TMTSF)2ClO4. It is especially emphasized that the observed unusual axis asymmetry of the angle dependence eliminates the possibility of s-wave and nodeless d-wave functions. It is also found that the directional ordering of ClO4 anions does not have any significant effects on the Fermi surface structure contrary to the previous modelings since the two Fermi surfaces obtained by the band calculations almost cross within the present full accuracy in first-principles calculations.

  14. 纳米氢氧化铜的均匀沉淀法制备及低温热容%Preparation of Cu (OH)2 nanometric powders by homogeneous precipitation and their low temperature heat capacity

    Institute of Scientific and Technical Information of China (English)

    吴新明; 易求实; 吴金平; 谭志诚; 屈松生

    2001-01-01

    使用氨水溶解硫酸铜,加入氢氧化钡沉淀分离硫酸根,所得铜氨清液加热蒸氨得氢氧化铜超细沉淀.沉淀分别用氨水和无水乙醇洗涤,60℃干燥,放置干燥器中至恒重.XRD、TEM、IcP测定表明,其平均粒径尺寸为45 nm,粒度分布范围窄,纯度高.用高精密全自动量热仪在78~370 K温区测定了热容,拟合出热容随温度变化的多项式方程,并对此氨浸新工艺--均匀沉淀法和有关的热力学性质进行了讨论.%The Cu(OH) 2 nanometric powders were prepared by a new method of homogeneous precipitation.The CuSO4 was dissolved in ammonia and the SO42- was removed by adding Ba(OH)2. The filtrate was heatedto remove ammonia and the Cu(OH) 2 was homogeneously deposited. The deposition was washed by ammoniaand ethanol, and the product was dried at 60 ℃, and then put in a desiccator to keep constant weight. Thegained powders were examined by XRD, TEM and ICP techniques and the results show that the grain size ofCu(OH) 2 nanometric powders is 45 nm in average within a narrow distribution range, and the powders arehighly purified. The heat capacity of the powders was measured in the temperature range of 78 ~ 370 K, andthe polynomial equations expressing the change of heat capacity with temperature was fitted. The ammonialeach techniques and thermodynamic properties were discussed.

  15. The Urban Heat Island Effect and the Role of Vegetation to Address the Negative Impacts of Local Climate Changes in a Small Brazilian City

    Directory of Open Access Journals (Sweden)

    Elis Dener Lima Alves

    2017-02-01

    Full Text Available This study analyzes the influence of urban-geographical variables on determining heat islands and proposes a model to estimate and spatialize the maximum intensity of urban heat islands (UHI. Simulations of the UHI based on the increase of normalized difference vegetation index (NDVI, using multiple linear regression, in Iporá (Brazil are also presented. The results showed that the UHI intensity of this small city tended to be lower than that of bigger cities. Urban geometry and vegetation (UI and NDVI were the variables that contributed the most to explain the variability of the maximum UHI intensity. It was observed that areas located in valleys had lower thermal values, suggesting a cool island effect. With the increase in NDVI in the central area of a maximum UHI, there was a significant decrease in its intensity and size (a 45% area reduction. It is noteworthy that it was possible to spatialize the UHI to the whole urban area by using multiple linear regression, providing an analysis of the urban set from urban-geographical variables and thus performing prognostic simulations that can be adapted to other small tropical cities.

  16. Heat pumps in district heating networks

    DEFF Research Database (Denmark)

    Ommen, Torben Schmidt; Markussen, Wiebke Brix; Elmegaard, Brian

    constraints limit the power plants. Efficient heat pumps can be used to decouple the constraints of electricity and heat production, while maintaining the high energy efficiency needed to match the politically agreed carbon emission goals. The requirements in terms of COP, location, capacity and economy...... are calculated using an energy system model which includes power plants, heat pumps and district heating consumption profiles. The model is developed with focus on accurate representation of the performance of the units in different locations and operating modes. The model can assist in investment decisions...... and strategic planning in the energy sector. The paper presents a case study of optimal implementation of heat pumps in the present energy system of the Copenhagen area. By introduction of the correct capacity of heat pumps, a 1,6 % reduction in fuel consumption for electricity and heat production can...

  17. Long-pulse operation of an intense negative ion source

    Energy Technology Data Exchange (ETDEWEB)

    Takeiri, Yasuhiko; Osakabe, Masaki; Tsumori, Katsuyoshi; Kaneko, Osamu; Oka, Yoshihide; Asano, Eiji; Kawamoto, Toshikazu; Akiyama, Ryuichi; Kuroda, Tsutomu [National Inst. for Fusion Science, Nagoya (Japan)

    1997-02-01

    In the National Institute for Fusion Science, as the heating system for the Large Helical Device (LHD), the negative ion NBI system of 20 MW incident power has been planned, and the development of a large current, large size negative ion source has been advanced. Based on the results obtained so far, the design of the LHD-NBI system was reconsidered, and the specification of the actual negative ion source was decided as 180 KeV-40A. This time, the grounding electrode with heightened heat removal capacity was made, and the long pulse operation was attempted, therefore, its results are reported. The structure of the external magnetic filter type large negative ion source used for the long pulse experiment is explained. In order to form the negative ion beam of long pulses, it is necessary to form stable are discharge plasma for long time, and variable resistors were attached to the output side of arc power sources of respective filament systems. By adjusting the resistors, uniform are discharge was able to be caused for longer than 10 s stably. The results of the long pulse experiment are reported. The dependence of the characteristics of negative ion beam on plasma electrode temperature was small, and the change of the characteristics of negative ion beam due to beam pulse width was not observed. (K.I.)

  18. Weather and road capacity

    DEFF Research Database (Denmark)

    Jensen, Thomas Christian

    2014-01-01

    The paper presents estimations of the effect of bad weather on the observed speed on a Danish highway section; Køge Bugt Motorvejen. The paper concludes that weather, primarily precipitation and snow, has a clear negative effect on speed when the road is not in hypercongestion mode. Furthermore......, the capacity of the highway seems to be reduced in bad weather and there are indications that travel time variability is also increased, at least in free-flow conditions. Heavy precipitation reduces speed and capacity by around 5-8%, whereas snow primarily reduces capacity. Other weather variables......-parametrically against traffic density and in step 2 the residuals from step 1 are regressed linearly against the weather variables. The choice of a non-parametric method is made to avoid constricting ties from a parametric specification and because the focus here is not on the relationship between traffic flow...

  19. Low-temperature heat capacities and thermodynamic properties of rare-earth triisothiocyanate hydrates (Ⅲ)——Sm(NCS)3·6H2O,Gd(NCS)3·6H2O,Yb(NCS)3·6H2O and Y(NCS)3·6H2O

    Institute of Scientific and Technical Information of China (English)

    谭志诚; Matsuo Takasuke; Suga Hiroshi; 张志英; 尹敬执; 蒋本杲; 孙同山

    1997-01-01

    The heat capacities of four RE isothiocyanate hydrates,Sm( NCS)3 6H2O,Gd( NCS)3 6H2O,Yb(NCS)3 6H2O and Y( NCS)3 6H2O,have been measured from 13 to 300 K with a fully-automated adiabatic calorimeter No obvious thermal anomaly was observed for the above-mentioned compounds in the experimental tem-peiatnre ranges.The polynomial equations for calculating the heat capacities of the four compounds in the range of 13-300K were obtained by the least-squares fitting based on the experimental Cp data.The Cp values below 13 K were estimated by using the Debye-Einstem heat capacity functions.The standard molar thermodynamic functions were calculated from 0 to 300 K.Gibbs energies of formation were also calculated.

  20. Thermal expansion, thermal conductivity, and heat capacity measurements for boreholes UE25 NRG-4, UE25 NRG-5, USW NRG-6, and USW NRG-7/7A

    Energy Technology Data Exchange (ETDEWEB)

    Brodsky, N.S.; Riggins, M. [Sandia National Labs., Albuquerque, NM (United States); Connolly, J. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Geology and Inst. of Meteoritics; Ricci, P. [Holometrix, Inc., Bedford, MA (United States)

    1997-09-01

    Specimens were tested from four thermal-mechanical units, namely Tiva Canyon (TCw), Paintbrush Tuff (PTn), and two Topopah Spring units (TSw1 and TSw2), and from two lithologies, i.e., welded devitrified (TCw, TSw1, TSw2) and nonwelded vitric tuff (PTn). Thermal conductivities in W(mk){sup {minus}1} averaged over all boreholes, ranged (depending upon temperature and saturation state) from 1.2 to 1.9 for TCw, from 0.4 to 0.9 for PTn, from 1.0 to 1.7 for TSw1, and from 1.5 to 2.3 for TSw2. Mean coefficients of thermal expansion were highly temperature dependent and values, averaged over all boreholes, ranged (depending upon temperature and saturation state) from 6.6 {times} 10{sup {minus}6} to 49 {times} 10{sup {minus}6} C{sup {minus}1} for TCw, from the negative range to 16 {times} 10{sup {minus}6} {center_dot} {degree}C{sup {minus}1} for PTn, from 6.3 {times} 10{sup {minus}6} to 44 {times} 10{sup {minus}6} C{sup {minus}1} for TSw1, and from 6.7 {times} 10{sup {minus}6} to 37 {times} 10{sup {minus}6} {center_dot} {degree}C{sup {minus}1} for TSw2. Mean values of thermal capacitance in J/cm{sup 3}K (averaged overall specimens) ranged from 1.6 J to 2.1 for TSw1 and from 1.8 to 2.5 for TSw2. In general, the lithostratigraphic classifications of rock assigned by the USGS are consistent with the mineralogical data presented in this report.

  1. Thermal load capacity analysis on small lakes utilized as heat source-sink of surface water heat pump systems%小型湖泊应用于地表水源热泵时的热承载能力分析

    Institute of Scientific and Technical Information of China (English)

    陈晓; 林汉柱; 林宣军; 李明

    2011-01-01

    Two thermal load capacity calculation methods including the water surface temperature method and the uniform mixing method for small lakes utilized as heat source-sink of surface water heat pump systems were introduced. The calculation results of the Hangzhou City indicate that the water surface temperature method is more convincing because it objectively reflects the process of discharge-mixing and water temperature recovering. Thermal load capacity calculations of small lakes in seven representative cities were performed. The results show that the thermal load capacity in summer varies from 23,4W/m2 to 29.5W/m2, and that in winter varies from 31.6W/m2 to 45.7W/m2. The key issue for the design of such surface water heat pump systems is to satisfy the constraint of thermal load capacity in summer.%分析了小型湖泊应用于地表水源热泵时的两种热承载能力计算方法——水面温度法和均匀混合法,并采用其计算了杭州小型湖泊应用于地表水源热泵时的热承载能力。计算结果表明:水面温度法较客观地反映了实际的排水混合及水温恢复过程,可信度更高。用水面温度法对7个代表性城市小型湖泊热承载能力进行分析的结果表明:夏季热承载能力在23-4—29.5W/m2之间,冬季热承载能力在31.6~45.7W/m2之间;设计这类系统的关键在于满足夏季热承载能力的约束。

  2. Identification of coagulase-negative Staphylococcus saprophyticus by polymerase chain reaction based on the heat-shock repressor encoding hrcA gene.

    Science.gov (United States)

    Paiva-Santos, Weslley de; Barros, Elaine M; Sousa, Viviane Santos de; Laport, Marinella Silva; Giambiagi-deMarval, Marcia

    2016-11-01

    Staphylococcus saprophyticus is an uropathogen belonging to the human microbiota and is responsible for community-acquired infections of the urinary tract. Identification of Staphylococcus species by biochemical tests is laborious and costly when compared to routine laboratory tests. Because of their high sensitivity and specificity, molecular methods are better suited for accurate identification of Staphylococcusspp. Therefore, the goal of this work was to standardize a polymerase chain reaction (PCR) protocol using species-specific primers, based on the heat-shock repressor coding hrcA gene, for the identification of S.saprophyticus. A total of 142 S. saprophyticus strains were obtained from different sources, including clinical, environmental, and foodborne strains. We also included 98 strains of Staphylococcus spp. to further validate the proposed method. Reliable results for the detection of S. saprophyticus isolates were obtained for 100% of the strains evaluated. The results were in accordance with matrix-assisted laser desorption ionization-time of flight mass spectrometry identification, thus highlighting the applicability of species-specific PCR for the molecular identification of S. saprophyticus.

  3. 链状分子状态方程的推导及热容的推算%New Perturbation Theory Model for Chain like Molecule Fluid and the Predicted Heat Capacity

    Institute of Scientific and Technical Information of China (English)

    梁世强; 张秉坚; 路映红; 胡文暄; 金之钧

    2001-01-01

    A model for the freely jointed square well chain fluid is developed based on the thermodynamic perturbation theory of Barker Henderson,Zhang and Wertheim.The analytic representations of square well monomer by Zhang are extended to obtain a series of representations for thermodynamic properties of square well chain fluids using the incorporating structural information for square well monomer of Wertheim's TPT1 model.The same work has been done using incorporating structural information for the diatomic square well fluid of TPT D model.The calculated results of compressibility factor,residual internal energy and constant volume heat capacity of 4 mer,8 mer and 16 mer chain fluids are tested against the MC results and a careful comparison between the model from TPT1 and that from TPT D has been made.The former agree with MC results much better than the later,especially for internal energy.To obtain the constant volume heat capacity,NVT MC simulations have been performed.%在 Barker Henderson, Zhang以及 Wertheim 等微扰理论的基础上 ,以方阱势硬球流体为参考体系 ,将 Zhang的解析表达方法与 Wertheim 的链成键自由能的处理方法结合起来 ,推导出自由链接的链状分子流体的 Helmholtz自由能的解析表达式 ,并得到了压缩因子、内能、恒容热容等热力学性质的计算式 .计算结果与 MC(Monte Carlo)模拟结果吻合良好 .对 Zhang的解析表达式与“ TPT D” (二阶 Wertheim微扰理论 )的结合也作了推导和计算 .

  4. VTX HyHeat Project

    Data.gov (United States)

    National Aeronautics and Space Administration — In this project Orbital Technologies Corporation (ORBITEC) will utilize its unique vortex propulsion technology to develop a high-capacity heating system to heat...

  5. Numerical study of heat pipe application in heat recovery systems

    Energy Technology Data Exchange (ETDEWEB)

    Song Lin; Broadbent, John; McGlen, Ryan [Thermacore Europe, Ashington (United Kingdom)

    2005-01-01

    Heat pipes are two-phase heat transfer devices with extremely high effective thermal conductivity. They can be cylindrical or planar in structure. Heat pipes can be embedded in a metal cooling plate, which is attached to the heat source, and can also be assembled with a fin stack for fluid heat transfer. Due to the high heat transport capacity, heat exchangers with heat pipes have become much smaller than traditional heat exchangers in handling high heat fluxes. With the working fluid in a heat pipe, heat can be absorbed on the evaporator region and transported to the condenser region where the vapour condenses releasing the heat to the cooling media. Heat pipe technology has found increasing applications in enhancing the thermal performance of heat exchangers in microelectronics, energy and other industrial sectors. Utilisation of a heat pipe fin stack in the drying cycle of domestic appliances for heat recovery may lead to a significant energy saving in the domestic sector. However, the design of the heat pipe heat exchanger will meet a number of challenges. This paper presents a design method by using CFD simulation of the dehumidification process with heat pipe heat exchangers. The strategies of simulating the process with heat pipes are presented. The calculated results show that the method can be further used to optimise the design of the heat pipe fin stack. The study suggests that CFD modelling is able to predict thermal performance of the dehumidification solution with heat pipe heat exchangers. (Author)

  6. Capacity and Capacity Utilization in Fishing Industries

    OpenAIRE

    Kirkley, James E; Squires, Dale

    1999-01-01

    Excess capacity of fishing fleets is one of the most pressing problems facing the world's fisheries and the sustainable harvesting of resource stocks. Considerable confusion persists over the definition and measurement of capacity and capacity utilization in fishing. Fishing capacity and capacity utilization, rather than capital (or effort) utilization, provide the appropriate framework. This paper provides both technological-economic and economic definitions of capacity and excess capacity i...

  7. 用于复杂有机化合物热容预测的一个新的拓扑指数%ESTIMATION OF HEAT CAPACITY OF COMPLEX ORGANIC COMPOUNDS BY A NOVEL TOPOLOGICAL INDEX

    Institute of Scientific and Technical Information of China (English)

    任碧野; 陈国斌; 许友

    1999-01-01

    A colored hydrogen-depleted graph was proposed to replace molecular graph so as to obtain good discrimination of the complex organic compounds by dyeing both the edges and the vertices. Furthermore, the topological index Xu based on the adjacency matrix A and distance matrix D was derived and further adapted to multiple bonds, heteroatom-containing compounds by using the related ratio of bond length to C—C bond in place of the adjacent topological distance and the valence δi in place of the degree of vertex vi in this paper. The index was highly correlated with the heat capacity of alkanes, olefins, aromatics,sulfur-containing and oxygen-containing compounds,etc.The calculated values were in good agreement with experimental data. The absolute average deviations of CLp for 79 compounds and CGp for 70 compounds were 1.57% and 2.24%, respectively. The proposed Xu index promised to be a useful parameter in QSPR/ QSAR research.

  8. Heat Capacity and the Equipartition Theorem

    Science.gov (United States)

    Dence, Joseph B.

    1972-01-01

    Limitations of classical mechanics in understanding molecular properties are discussed. Modifications introduced by quantum mechanics enable the instructor to include and integrate important concepts from thermodynamics, quantum mechanics, spectroscopy, and statistics. (DF)

  9. Simulation of capacity fade in lithium-ion batteries

    Science.gov (United States)

    Spotnitz, R.

    The technical literature, including datasheets from battery manufacturers, is reviewed to identify the major characteristics of capacity fade: impedance growth and capacity loss. Impedance growth is significant at both the positive and negative electrodes, though capacity fade loss due to SEI growth is usually attributed to the negative. Techniques for accelerated life testing are summarized. Simple models are used to describe mechanisms for capacity loss at the negative. Finally, numerical simulations are used to explore the effect of porous electrodes on fade behavior.

  10. Solar Heating System with Building-Integrated Heat Storage

    DEFF Research Database (Denmark)

    Heller, Alfred

    1996-01-01

    Traditional solar heating systems cover between 5 and 10% of the heat demand fordomestic hot water and comfort heating. By applying storage capacity this share can beincreased much. The Danish producer of solar heating systems, Aidt-Miljø, markets such a system including storage of dry sand heated...... by PP-pipe heat exchanger. Heat demand is reduced due to direct solar heating, and due to storage. Heat demand is reduced due to direct solar heating, due to storage and due to lower heat losses through the ground. In theory, by running the system flow backwards through the sand storage, active heating...... can be achieved.The objective of the report is to present results from measured system evaluation andcalculations and to give guidelines for the design of such solar heating systems with building integrated sand storage. The report is aimed to non-technicians. In another report R-006 the main results...

  11. Negative learning

    Energy Technology Data Exchange (ETDEWEB)

    Oppenheimer, M. [Woodrow Wilson School of Public and International Affairs, Department of Geosciences, Princeton University, Princeton, NJ (United States); O' Neill, B.C. [International Institute for Applied Systems Analysis, Laxenburg (Austria)]|[Institute for the Study of Society and Environment, National Center for Atmospheric Research, Boulder, CO (United States); Webster M. [MIT Joint Program on the Science and Policy of Global Change, Massachusetts Institute of Technology, Cambridge, MA (United States)

    2008-07-15

    New technical information may lead to scientific beliefs that diverge over time from the a posteriori right answer. We call this phenomenon, which is particularly problematic in the global change arena, negative learning. Negative learning may have affected policy in important cases, including stratospheric ozone depletion, dynamics of the West Antarctic ice sheet, and population and energy projections. We simulate negative learning in the context of climate change with a formal model that embeds the concept within the Bayesian framework, illustrating that it may lead to errant decisions and large welfare losses to society. Based on these cases, we suggest approaches to scientific assessment and decision making that could mitigate the problem. Application of the tools of science history to the study of learning in global change, including critical examination of the assessment process to understand how judgments are made, could provide important insights on how to improve the flow of information to policy makers.

  12. Water activities of NaClO4, Ca(ClO4)2, and Mg(ClO4)2 brines from experimental heat capacities: Water activity >0.6 below 200 K

    Science.gov (United States)

    Toner, J. D.; Catling, D. C.

    2016-05-01

    Perchlorate salts found on Mars are extremely hygroscopic and form low eutectic temperature aqueous solutions, which could allow liquid water to exist on Mars despite cold and dry conditions. The formation, dynamics, and potential habitability of perchlorate salt solutions can be broadly understood in terms of water activity. Water activity controls condensation and evaporation of water vapor in brines, deliquescence and efflorescence of crystalline salts, and ice formation during freezing. Furthermore, water activity is a basic parameter defining the habitability of aqueous solutions. Despite the importance of water activity, its value in perchlorate solutions has only been measured at 298.15 K and at the freezing point of water. To address this lack of data, we have determined water activities in NaClO4, Ca(ClO4)2, and Mg(ClO4)2 solutions using experimental heat capacities measured by Differential Scanning Calorimetry. Our results include concentrations up to near-saturation and temperatures ranging from 298.15 to 178 K. We find that water activities in NaClO4 solutions increase with decreasing temperature, by as much as 0.25 aw from 298.15 to 178 K. Consequently, aw reaches ∼0.6-0.7 even for concentrations up to 15 molal NaClO4 below 200 K. In contrast, water activities in Ca(ClO4)2 and Mg(ClO4)2 solutions generally decrease with decreasing temperature. The temperature dependence of water activity indicates that low-temperature NaClO4 solutions will evaporate and deliquesce at higher relative humidity, crystallize ice at higher temperature, and potentially be more habitable for life (at least in terms of water activity) compared to solutions at 298.15 K. The opposite effects occur in Ca(ClO4)2 and Mg(ClO4)2 solutions.

  13. LT-IIb(T13I, a non-toxic type II heat-labile enterotoxin, augments the capacity of a ricin toxin subunit vaccine to evoke neutralizing antibodies and protective immunity.

    Directory of Open Access Journals (Sweden)

    Christopher J Greene

    Full Text Available Currently, there is a shortage of adjuvants that can be employed with protein subunit vaccines to enhance protection against biological threats. LT-IIb(T13I is an engineered nontoxic derivative of LT-IIb, a member of the type II subfamily of heat labile enterotoxins expressed by Escherichia coli, that possesses potent mucosal adjuvant properties. In this study we evaluated the capacity of LT-IIb(T13I to augment the potency of RiVax, a recombinant ricin toxin A subunit vaccine, when co-administered to mice via the intradermal (i.d. and intranasal (i.n. routes. We report that co-administration of RiVax with LT-IIb(T13I by the i.d. route enhanced the levels of RiVax-specific serum IgG antibodies (Ab and elevated the ratio of ricin-neutralizing to non-neutralizing Ab, as compared to RiVax alone. Protection against a lethal ricin challenge was also augmented by LT-IIb(T13I. While local inflammatory responses elicited by LT-IIb(T13I were comparable to those elicited by aluminum salts (Imject®, LT-IIb(T13I was more effective than aluminum salts at augmenting production of RiVax-specific serum IgG. Finally, i.n. administration of RiVax with LT-IIb(T13I also increased levels of RiVax-specific serum and mucosal Ab and enhanced protection against ricin challenge. Collectively, these data highlight the potential of LT-IIb(T13I as an effective next-generation i.d., or possibly i.n. adjuvant for enhancing the immunogenicity of subunit vaccines for biodefense.

  14. Riemann solvers for multi-component gas mixtures with temperature dependent heat capacities; Solveurs de riemann pour des melanges de gaz parfaits avec capacites calorifiques dependant de la temperature

    Energy Technology Data Exchange (ETDEWEB)

    Beccantini, A

    2001-07-01

    This thesis represents a contribution to the development of upwind splitting schemes for the Euler equations for ideal gaseous mixtures and their investigation in computing multidimensional flows in irregular geometries. In the preliminary part we develop and investigate the parameterization of the shock and rarefaction curves in the phase space. Then, we apply them to perform some field-by-field decompositions of the Riemann problem: the entropy-respecting one, the one which supposes that genuinely-non-linear (GNL) waves are both shocks (shock-shock one) and the one which supposes that GNL waves are both rarefactions (rarefaction-rarefaction one). We emphasize that their analysis is fundamental in Riemann solvers developing: the simpler the field-by-field decomposition, the simpler the Riemann solver based on it. As the specific heat capacities of the gases depend on the temperature, the shock-shock field-by-field decomposition is the easiest to perform. Then, in the second part of the thesis, we develop an upwind splitting scheme based on such decomposition. Afterwards, we investigate its robustness, precision and CPU-time consumption, with respect to some of the most popular upwind splitting schemes for polytropic/non-polytropic ideal gases. 1-D test-cases show that this scheme is both precise (exact capturing of stationary shock and stationary contact) and robust in dealing with strong shock and rarefaction waves. Multidimensional test-cases show that it suffers from some of the typical deficiencies which affect the upwind splitting schemes capable of exact capturing stationary contact discontinuities i.e the developing of non-physical instabilities in computing strong shock waves. In the final part, we use the high-order multidimensional solver here developed to compute fully-developed detonation flows. (author)

  15. Computation of methodology-independent single-ion solvation properties from molecular simulations. III. Correction terms for the solvation free energies, enthalpies, entropies, heat capacities, volumes, compressibilities, and expansivities of solvated ions.

    Science.gov (United States)

    Reif, Maria M; Hünenberger, Philippe H

    2011-04-14

    The raw single-ion solvation free energies computed from atomistic (explicit-solvent) simulations are extremely sensitive to the boundary conditions (finite or periodic system, system or box size) and treatment of electrostatic interactions (Coulombic, lattice-sum, or cutoff-based) used during these simulations. However, as shown by Kastenholz and Hünenberger [J. Chem. Phys. 124, 224501 (2006)], correction terms can be derived for the effects of: (A) an incorrect solvent polarization around the ion and an incomplete or/and inexact interaction of the ion with the polarized solvent due to the use of an approximate (not strictly Coulombic) electrostatic scheme; (B) the finite-size or artificial periodicity of the simulated system; (C) an improper summation scheme to evaluate the potential at the ion site, and the possible presence of a polarized air-liquid interface or of a constraint of vanishing average electrostatic potential in the simulated system; and (D) an inaccurate dielectric permittivity of the employed solvent model. Comparison with standard experimental data also requires the inclusion of appropriate cavity-formation and standard-state correction terms. In the present study, this correction scheme is extended by: (i) providing simple approximate analytical expressions (empirically-fitted) for the correction terms that were evaluated numerically in the above scheme (continuum-electrostatics calculations); (ii) providing correction terms for derivative thermodynamic single-ion solvation properties (and corresponding partial molar variables in solution), namely, the enthalpy, entropy, isobaric heat capacity, volume, isothermal compressibility, and isobaric expansivity (including appropriate standard-state correction terms). The ability of the correction scheme to produce methodology-independent single-ion solvation free energies based on atomistic simulations is tested in the case of Na(+) hydration, and the nature and magnitude of the correction terms for

  16. Geothermal properties of Swiss Molasse Basin (depth range 0-500 m) - 2006 upgrade of the thermal conductivity, heat capacity, rock density and porosity data base; Geothermische Eigenschaften der Schweizer Molasse (Tiefenbereich 0-500 m). Datenbank fuer Waermeleitfaehigkeit, spezifische Waermekapazitaet, Gesteinsdichte und Porositaet. Ueberarbeitung 2006

    Energy Technology Data Exchange (ETDEWEB)

    Leu, W. [Geoform AG, Minusio (Switzerland); Megel, T. [Geowatt, Zuerich (Switzerland); Schaerli, U. [Geologie und Geophysik, Zuerich (Switzerland)

    2006-07-01

    The main aim of this project is the preparation of a specific data base of geothermal properties for typical rocks of the Swiss Molasse Basin (depth interval 0-500 m). The project includes the development of a new laboratory tool for efficient heat capacity measurements on rock samples, numerous new measurements of geothermal rock properties in the laboratory and calculation of such data from geophysical borehole logs. In the geographical area under review, 282 rock samples, mainly from deep boreholes, were analyzed with the successfully calibrated new heat capacity device and conventional thermal conductivity measuring techniques (cuttings and cores). Based on sonic and density log data from exploration wells, 374 additional data points were generated. This new data base characterizes in detail the six main lithological rock types in the three Molasse groups OSM, OMM and USM within the Swiss Plateau Molasse. The statistical evaluation of all data illustrates the regional variation of the petrophysical and geothermal parameters. For most data groups bulk rock density and thermal conductivity increase, whereas heat capacity decreases in the direction towards the Alpine front. Thermal conductivity shows a distinct increase with depth. Based on this new information and with the aid of the evaluation software tool SwEWS, the costs of planned geothermal installations can be optimized thanks to more precise heat extraction simulations with existing software packages like COSOND, TRNSYS, EWS or WPcalc. (author)

  17. The Heat Is on: An Inquiry-Based Investigation for Specific Heat

    Science.gov (United States)

    Herrington, Deborah G.

    2011-01-01

    A substantial number of upper-level science students and practicing physical science teachers demonstrate confusion about thermal equilibrium, heat transfer, heat capacity, and specific heat capacity. The traditional method of instruction, which involves learning the related definitions and equations, using equations to solve heat transfer…

  18. The Heat Is on: An Inquiry-Based Investigation for Specific Heat

    Science.gov (United States)

    Herrington, Deborah G.

    2011-01-01

    A substantial number of upper-level science students and practicing physical science teachers demonstrate confusion about thermal equilibrium, heat transfer, heat capacity, and specific heat capacity. The traditional method of instruction, which involves learning the related definitions and equations, using equations to solve heat transfer…

  19. 四氯合镉酸正十一烷铵的合成、晶体结构及低温热容%Synthesis, Crystal Structure and Low-temperature Heat Capacities of Bis(n-undecylammonium)tetrachlorocadmiumate

    Institute of Scientific and Technical Information of China (English)

    卢冬飞; 邸友莹; 窦建民

    2012-01-01

    The crystalline bis(n-undecylammonium)tetrachlorocadmiumate (CllH23NH3)2CdCI4(s) [abbre- viated as CllCd(s)] was synthesized. The crystal structure and composition of the complex were determined by single crystal X-ray diffraction, chemical analysis and elementary analysis. The lattice potential energy was calculated to be UpoT= 908.18 kJ·mo1^-1 from crystallographic data. Low-temperature heat capacities of the complex were measured by a precision automatic adiabatic calorimeter over the temperature range from 78 to 395 K. The experimental results show that there are two continuous phase changes appearing in the temperature region. The peak temperatures, molar enthalpies and entropies of two phase transitions for the complex were determined to be: Ttrs,l=(321.88±0.07) K,△trsHm, l=-(37.59±0.17) kJ·mol^-1 and △trsSm,l= (117.24±0.12) J·K^-l·mol^-1 for the first peak; Ttrs,2=(323.81±0.30) K, △trsHm,2 = (12.42± 0.02) kJ·mol^-1 and △trsSm,2=-(38.36±0.09) J·K^-l·mol^-1 for the second peak. Two polynomial equations of the heat capacities as a function of the temperature were fitted by least square method. The smoothed heat capacities and thermodynamic functions relative to 298.15 based on the fitted polynomials. K of the complex were calculated with an interval of 5 K%合成了四氯合镉酸正十一烷铵配合物(C11H23NH3)2CdCl4(s)[简写:C11Cd(s)].用X射线单晶衍射技术、化学分析和元素分析确定其晶体结构和化学组成.利用其晶体学数据计算出晶格能为:UpoT=908.18 kJ·mol^-1.利用精密自动绝热热量计测定了它在78-395K温区的低温热容,结果表明,该配合物在此温区出现两次连续的固-固相转变,计算出两次相变的峰温、摩尔焓及摩尔熵分别为:Ttrs.1=(321.88±0.07)K,△trsHm.1=(37.59±0.17)kJ·mol^-1,△trsSm.1=(117.24±0.12)J·K^-1·mol^-1,Ttrs.2=(323.8l±0.30

  20. Negative Certainty

    Science.gov (United States)

    Ariso, José María

    2017-01-01

    The definitions of "negative knowledge" and the studies in this regard published to date have not considered the categorial distinction Wittgenstein established between knowledge and certainty. Hence, the important role that certainty, despite its omission, should have in these definitions and studies has not yet been shown. In this…

  1. Negative Numbers

    Science.gov (United States)

    Galbraith, Mary J.

    1974-01-01

    Examination of models for representing integers demonstrates that formal operational thought is required for establishing the operations on integers. Advocated is the use of many models for introducing negative numbers but, apart from addition, it is recommended that operations on integers be delayed until the formal operations stage. (JP)

  2. Negative Certainty

    Science.gov (United States)

    Ariso, José María

    2017-01-01

    The definitions of "negative knowledge" and the studies in this regard published to date have not considered the categorial distinction Wittgenstein established between knowledge and certainty. Hence, the important role that certainty, despite its omission, should have in these definitions and studies has not yet been shown. In this…

  3. Heat Roadmap Europe

    DEFF Research Database (Denmark)

    David, Andrei; Mathiesen, Brian Vad; Averfalk, Helge

    2017-01-01

    The Heat Roadmap Europe (HRE) studies estimated a potential increase of the district heating (DH) share to 50% of the entire heat demand by 2050, with approximately 25–30% of it being supplied using large-scale electric heat pumps. This study builds on this potential and aims to document...... capacity of electric large-scale heat pumps with more than 1 MW thermal output, operating in European DH systems. The survey is the first database of its kind containing the technical characteristics of these heat pumps, and provides the basis for the analysis of this paper. By quantifying the heat sources...... that such developments can begin now with technologies currently available. We present a database and the status of the technology and its ability of expansion to other European locations by reviewing experiences aimed at further research or application in the heating industry. This is based on a survey of the existing...

  4. Visualising dual downregulation of insulin-like growth factor receptor-1 and vascular endothelial growth factor-A by heat shock protein 90 inhibition effect in triple negative breast cancer.

    Science.gov (United States)

    Terwisscha van Scheltinga, Anton G T; Berghuis, Paul; Nienhuis, Hilde H; Timmer-Bosscha, Hetty; Pot, Linda; Gaykema, Sietske B M; Lub-de Hooge, Marjolijn N; Kosterink, Jos G W; de Vries, Elisabeth G E; Schröder, Carolien P

    2014-09-01

    Triple negative breast cancer (TNBC) is biologically characterised by heterogeneous presence of molecular pathways underlying it. Insulin-like growth factor receptor-1 (IGF-1R) expression and vascular endothelial growth factor-A (VEGF-A) have been identified as key factors in these pathways in TNBC. In this study, we aimed at in vivo PET imaging the effect of heat shock protein (Hsp) 90 inhibition by means of NVP-AUY922 on these pathways, with zirconium-89 ((89)Zr) labelled antibodies targeting IGF-1R and VEGF-A. In vitro NVP-AUY922 effects on cellular IGF-1R expression and VEGF-A secretion were determined in MCF-7 and MDA-MB-231 cell lines. Moreover human TNBC bearing MDA-MB-231 mice received 50mg/kg NVP-AUY922 or vehicle q3d intraperitoneally for 21days. PET scans with (89)Zr-MAB391 and (89)Zr-bevacizumab for visualisation of IGF-1R and VEGF-A were performed before and during treatment. Ex vivo biodistribution and correlative tissue analyses were performed. NVP-AUY922 treatment reduced IGF-1R expression and VEGF-A excretion in both cell lines. Hsp90 inhibition lowered tumour uptake on (89)Zr-MAB391-PET by 37.3% (Ptherapy in TNBC. Copyright © 2014 Elsevier Ltd. All rights reserved.

  5. Measurement of Specific Heat Capacity of Insulating Brick at High Temperatures by a Half-Open Dynamic Method Based on Hybrid Principle%采用基于混合原理的动态半开放方法测量保温砖的高温比热容

    Institute of Scientific and Technical Information of China (English)

    龙海敏; 卢元; 康进武; 聂刚; 马斌; 付龙

    2011-01-01

    保温砖是铸造中的常用材料,比热容是材料重要的热物性参数,也是铸件凝固过程数值模拟所需参数.保温砖为多孔材料,其高温比热容测量困难.针对这种情况,提出了基于混合原理的动态半开放比热容测量方法,并研制了相应的比热容测量仪.采用已知比热容的蓝宝石试样进行标定,试验值和理论值误差在6.3%以内.采用此方法测得了进口和国产两种保温砖在30~760℃的比热容曲线.%Insulating brick is widely used in casting production. Its specific heat capacity is one of the important thermal properties and crucial for numerical simulation of solidification process. Because of its porous characteristic, it is hard to measure the specific heat capacity at high temperatures. In this paper, a half-open dynamic measurement method based on hybrid principle was presented and a measurement device was established. Sapphire with given standard value of specific heat capacity is used to calibrate the system; the error is less than 6.3%. Specific heat capacity of two different kinds of insulating bricks were measured in the temperature range from 30 °C to760°Co

  6. Temperature drops in heat pipes

    Energy Technology Data Exchange (ETDEWEB)

    Saatci, A.M.; Khalifa, A.M.A.; Akyurt, M.

    1986-01-01

    The role of entrainment in limiting heat pipe power handling capacity is discussed. The effect of entrainment on the measured temperature field in the integral heat pipe of a split system solar cooker is analyzed. An experimental set-up depicting a heat loop is presented, along with test results.

  7. Heat capacity and neutron diffraction studies on the frustrated magnetic Co{sub 2}(OH)(PO{sub 4}){sub 1-x}(AsO{sub 4}){sub x} [0{<=}x{<=}1] solid solution

    Energy Technology Data Exchange (ETDEWEB)

    Pedro, I. de, E-mail: depedrovm@unican.es [CITIMAC, Facultad de Ciencias, Universidad de Cantabria, 39005 Santander (Spain); Departamento de Quimica Inorganica, Facultad de Ciencia y Tecnologia, Universidad del Pais Vasco, 48080 Bilbao (Spain); Rojo, J.M. [Departamento de Quimica Inorganica, Facultad de Ciencia y Tecnologia, Universidad del Pais Vasco, 48080 Bilbao (Spain); Rodriguez Fernandez, J.; Sanchez Marcos, J. [CITIMAC, Facultad de Ciencias, Universidad de Cantabria, 39005 Santander (Spain); Fernandez-Diaz, M.T. [Institut Laue-Langevin, BP 156X, F-38042 Grenoble Cedex (France); Rojo, T. [Departamento de Quimica Inorganica, Facultad de Ciencia y Tecnologia, Universidad del Pais Vasco, 48080 Bilbao (Spain)

    2012-04-15

    The Co{sub 2}(OH)(PO{sub 4}){sub 1-x}(AsO{sub 4}){sub x} [0{<=}x{<=}1] solid solution exhibits a complex magnetic behaviour due to the bond-frustration in its magnetic structure. Heat capacity measurements of the (x=0.1-0.5) phases show a three-dimensional magnetic ordering ({lambda} anomaly) that shifts to lower temperatures and becomes broader as the AsO{sub 4}{sup 3-} content increases. For x=0.75, no significant feature was observed whereas for higher arsenate ion content, x=0.9 and 1, a small maximum was detected. The magnetic structures of solid solution are consistent with the existence of predominant antiferromagnetic superexchange interactions through the |OH| and |XO{sub 4}| (X=P and As) groups between the Co{sup +2} ions. The substitution of PO{sub 4}{sup 3-} by AsO{sub 4}{sup 3-} anions by more than 90% substantially modifies the magnetic exchange pathways in the solid solution, leading to an incommensurate antiferromagnetic structure in Co{sub 2}(OH)(PO{sub 4}){sub 1-x}(AsO{sub 4}){sub x} [x=0.9 and 1] phases. - Graphical abstract: Magnetic structures of Co{sub 2}(OH)(PO{sub 4}){sub 1-x}(AsO{sub 4}){sub x} [0{<=}x{<=}1]. The ordering of the magnetic moments of Co{sup 2+} is in c direction for the two crystallographic positions (dimers and chains) in all compounds. The unit cell is surrounded by a red line. Highlights: Black-Right-Pointing-Pointer Synthesis of a new adamite-type compounds, Co{sub 2}(OH)(PO{sub 4}){sub 1-x}(AsO{sub 4}){sub x} (0.1, 0.25, 0.5, 0.75, 0.9) phases. Black-Right-Pointing-Pointer Co{sub 2}(OH)(PO{sub 4}){sub 1-x}(AsO{sub 4}){sub x} (0-1) solid solution; magnetic frustrated system. Black-Right-Pointing-Pointer High resolution neutron powder diffraction to determine the crystal structures. Black-Right-Pointing-Pointer Incommensurate magnetic structures at low temperature. Black-Right-Pointing-Pointer Magnetostructural correlations in cobalt-based Co{sub 2}(OH)XO{sub 4} (X=P and As) insulation compounds.

  8. The decrease in the IgG-binding capacity of intensively dry heated whey proteins is associatead with intense Maillard reaction, structural changes of the proteins and formation of RAGE-ligands

    NARCIS (Netherlands)

    Liu, F.; Teodorowicz, M.; Boekel, van M.A.J.S.; Wichers, H.J.; Hettinga, K.A.

    2016-01-01

    Heat treatment is the most common way of milk processing, inducing structural changes as well as chemical modifications in milk proteins. These modifications influence the immune-reactivity and allergenicity of milk proteins. This study shows the influence of dry heating on the solubility, particle

  9. Capacity fade of Sony 18650 cells cycled at elevated temperatures. Part II. Capacity fade analysis

    Science.gov (United States)

    Ramadass, P.; Haran, Bala; White, Ralph; Popov, Branko N.

    A complete capacity fade analysis was carried out for Sony 18650 cells cycled at elevated temperatures. The major causes of capacity loss were identified and a complete capacity fade balance was carried out to account for the total capacity loss of Li-ion battery as a function of cycle number and temperature. The three most significant parameters that cause capacity loss were loss of secondary active material (LiCoO 2/carbon) and primary active material (Li +) and the rate capability losses. Intrinsic capacity measurements for both positive and negative electrode has been used to estimate the capacity loss due to secondary active material and a charge balance gives the capacity lost due to primary active material (Li +). Capacity fade has been quantified with secondary active material loss dominating the other losses.

  10. Photovoltaics effective capacity: Interim final report 2

    Energy Technology Data Exchange (ETDEWEB)

    Perez, R.; Seals, R. [State Univ. of New York, Albany, NY (United States). Atmospheric Sciences Research Center

    1997-11-01

    The authors provide solid evidence, based on more than 8 million data points, that regional photovoltaic (PV) effective capacity is largely unrelated to the region`s solar resource. They confirm, however, that effective capacity is strongly related to load-shape characteristics. The load-shape effective-capacity relationship appears to be valid for end-use loads as small as 100 kW, except possibly in the case of electrically heated buildings. This relationship was used as a tool to produce a US map of PV`s effective capacity. The regions of highest effective capacities include (1) the central US from the northern Great Plains to the metropolitan areas of Chicago and Detroit, down to the lower Mississippi Valley, (2) California and western Arizona, and (3) the northeast metropolitan corridor. The features of this map are considerably different from the traditional solar resource maps. They tend to reflect the socio-economic and climatic factors that indirectly drive PV`s effective capacity: e.g., commercial air-conditioning, little use of electric heat, and strong summer heat waves. The map provides a new and significant insight to a comprehensive valuation of the PV resource. The authors assembled preliminary evidence showing that end-use load type may be related to PV`s effective capacity. Highest effective capacities were found for (nonelectrically heated) office buildings, followed by hospitals. Lowest capacities were found for airports and residences. Many more data points are needed, however, to ascertain and characterize these preliminary findings.

  11. Photovoltaics effective capacity: Interim final report 2

    Energy Technology Data Exchange (ETDEWEB)

    Perez, R.; Seals, R. [State Univ. of New York, Albany, NY (United States). Atmospheric Sciences Research Center

    1997-11-01

    The authors provide solid evidence, based on more than 8 million data points, that regional photovoltaic (PV) effective capacity is largely unrelated to the region`s solar resource. They confirm, however, that effective capacity is strongly related to load-shape characteristics. The load-shape effective-capacity relationship appears to be valid for end-use loads as small as 100 kW, except possibly in the case of electrically heated buildings. This relationship was used as a tool to produce a US map of PV`s effective capacity. The regions of highest effective capacities include (1) the central US from the northern Great Plains to the metropolitan areas of Chicago and Detroit, down to the lower Mississippi Valley, (2) California and western Arizona, and (3) the northeast metropolitan corridor. The features of this map are considerably different from the traditional solar resource maps. They tend to reflect the socio-economic and climatic factors that indirectly drive PV`s effective capacity: e.g., commercial air-conditioning, little use of electric heat, and strong summer heat waves. The map provides a new and significant insight to a comprehensive valuation of the PV resource. The authors assembled preliminary evidence showing that end-use load type may be related to PV`s effective capacity. Highest effective capacities were found for (nonelectrically heated) office buildings, followed by hospitals. Lowest capacities were found for airports and residences. Many more data points are needed, however, to ascertain and characterize these preliminary findings.

  12. Heat Transfer Characteristics of SiC-coated Heat Pipe for Passive Decay Heat Removal

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Kyung Mo; Kim, In Guk; Jeong, Yeong Shin; Bang, In Cheol [Ulsan National Institute of Science and Technology, Ulsan (Korea, Republic of)

    2014-10-15

    The main concern with the Fukushima accident was the failure of active and passive core cooling systems. The main function of existing passive decay heat removal systems is feeding additional coolant to the reactor core. Thus, an established emergency core cooling system (ECCS) cannot operate properly because of impossible depressurization under the station blackout (SBO) condition. Therefore, a new concept for passive decay heat removal system is required. In this study, an innovative hybrid control rod concept is considered for passive in-core decay heat removal that differs from the existing direct vessel injection core cooling system and passive auxiliary feedwater system (PAFS). The heat transfer between the evaporator and condenser sections occurs by phase change of the working fluid and capillary action induced by wick structures installed on the inner wall of the heat pipe. In this study, a hybrid control rod is developed to take the roles of both neutron absorption and heat removal by combining the functions of a heat pipe and control rod. Previous studies on enhancing the heat removal capacity of heat pipes used nanofluids, self-rewetting fluids, various wick structures and condensers. Many studies have examined the thermal performances of heat pipes using various nanofluids. They concluded that the enhanced thermal performance of the heat pipe using nanofluids is due to nanoparticle deposition on the wick structures. Thus, the wick structure of heat pipes has been modified by nanoparticle deposition to enhance the heat removal capacity. However, previous studies used relatively small heat pipes and narrow ranges of heat loads. The environment of a nuclear reactor is very specific, and the decay heat produced by fission products after shutdown is relatively large. Thus, this study tested a large-scale heat pipe over a wide range of power. The concept of a hybrid heat pipe for an advanced in-core decay heat removal system was introduced for complete

  13. Capacity Statement for Railways

    DEFF Research Database (Denmark)

    Landex, Alex

    2007-01-01

    The subject “Railway capacity” is a combination of the capacity consumption and how the capacity is utilized. The capacity utilization of railways can be divided into 4 core elements: The number of trains; the average speed; the heterogeneity of the operation; and the stability. This article...... describes how the capacity consumption for railways can be worked out and analytical measurements of how the capacity is utilized. Furthermore, the article describes how it is possible to state and visualize railway capacity. Having unused railway capacity is not always equal to be able to operate more...

  14. Measures of Financial Capacity: A Review.

    Science.gov (United States)

    Ghesquiere, Angela R; McAfee, Caitlin; Burnett, Jason

    2017-05-23

    Capacity to manage finances and make financial decisions can affect risk for financial exploitation and is often the basis for legal determinations of conservatorship/guardianship. Several structured assessments of financial capacity have been developed, but have not been compared regarding their focus, validity, or reliability. Therefore, we conducted a review of financial capacity measures to examine these factors. We searched electronic databases, reference lists in identified articles, conference proceedings and other grey literature for measures of financial capacity. We then extracted data on the length and domains of each measure, the population for which they were intended, and their validity and reliability. We identified 10 structured measures of financial capacity. Most measures could be completed in 25-30 min, and were designed to be administered to older adults with some level of cognitive impairment. Reliability and validity were high for most. Measurement of financial capacity is complex and multidimensional. When selecting a measure of financial capacity, consideration should be made of the population of focus and the domains of capacity to be assessed. More work is needed on the cultural sensitivity of financial capacity measures, their acceptability, and their use in clinical work. Better understanding of when, and to whom, to administer different financial capacity measures could enhance the ability to accurately detect those suffering from impaired financial capacity, and prevent related negative outcomes like financial exploitation.

  15. Heat Waves

    Science.gov (United States)

    Heat Waves Dangers we face during periods of very high temperatures include: Heat cramps: These are muscular pains and ... having trouble with the heat. If a heat wave is predicted or happening… - Slow down. Avoid strenuous ...

  16. Heat Islands

    Science.gov (United States)

    EPA's Heat Island Effect Site provides information on heat islands, their impacts, mitigation strategies, related research, a directory of heat island reduction initiatives in U.S. communities, and EPA's Heat Island Reduction Program.

  17. Measurement and estimation of heat capacity of dicationic ionic liquid [C3 ( MIM)2][PF6]2%双阳离子型离子液体[C3(MIM)2][PF6]2的热容测定及估算

    Institute of Scientific and Technical Information of China (English)

    杨许召; 王军; 孙新科

    2011-01-01

    利用差示扫描热量计(DSC)测定了双阳离子型离子液体1,1′-(丙烷-1,3-二基)-双(3-甲基-1H-咪唑鎓-1-基)双六氟磷酸盐([C3(MIM)2][PF6]2)在293.15-543.15 K温区内的摩尔热容.实验结果表明:在293.15-403.15 K和433.15-543.15 K温区内,该化合物无相变及其他热异常现象发生,将实验数据拟合得到了该化合物热容随温度变化的多项式方程.其熔化温度、熔化焓及熔化熵分别为416.83 K,38.256 kJ/mol和91.778 J/(K·mol).由热容数据计算出其在固相区和液相区相对于标准参考温度298.15 K的热力学函数值.采用基团贡献法对433.15-543.15 K温区的热容进行了估算,为该离子液体的工业应用提供了热力学基础数据.%The molar heat capacity of dicationic ionic liquid 1, 1'-( propane-1, 3-diyl)-bis (3-methyl-1Himidazolium-1-yl) dihexafluorophosphate ( [C3 ( MIM )2][PF6]2 ) was measured with differential scanning calorimeter(DSC) at 293.15-543.15 K.The results show that no phase transition or other thermal anomaly is observed in the range of 293.15-403.15 K and 433.15-543.15 K, in which the molar heat capacities are fitted to polynomials.The fusing temperature, molar enthalpy and entropy of fusion are 416.83 K, 38.256 kJ/mol and 91.778 J/(K· mol), respectively.The thermodynamic functions relative to the standard reference temperature 298.15 K were derived based on the heat capacity data.A group contribution method was used to calculate its molar heat capacity from 433.15 to 543.15 K.The basic data are helpful for its industrial application.

  18. High capacity carbon dioxide sorbent

    Energy Technology Data Exchange (ETDEWEB)

    Dietz, Steven Dean; Alptekin, Gokhan; Jayaraman, Ambalavanan

    2015-09-01

    The present invention provides a sorbent for the removal of carbon dioxide from gas streams, comprising: a CO.sub.2 capacity of at least 9 weight percent when measured at 22.degree. C. and 1 atmosphere; an H.sub.2O capacity of at most 15 weight percent when measured at 25.degree. C. and 1 atmosphere; and an isosteric heat of adsorption of from 5 to 8.5 kilocalories per mole of CO.sub.2. The invention also provides a carbon sorbent in a powder, a granular or a pellet form for the removal of carbon dioxide from gas streams, comprising: a carbon content of at least 90 weight percent; a nitrogen content of at least 1 weight percent; an oxygen content of at most 3 weight percent; a BET surface area from 50 to 2600 m.sup.2/g; and a DFT micropore volume from 0.04 to 0.8 cc/g.

  19. Discontinuous symplectic capacities

    NARCIS (Netherlands)

    Zehmisch, K.; Ziltener, F.J.

    2014-01-01

    We show that the spherical capacity is discontinuous on a smooth family of ellipsoidal shells. Moreover, we prove that the shell capacity is discontinuous on a family of open sets with smooth connected boundaries.

  20. Responsibility and Capacities

    DEFF Research Database (Denmark)

    Ryberg, Jesper

    2014-01-01

    That responsible moral agency presupposes certain mental capacities, constitutes a widely accepted view among theorists. Moreover, it is often assumed that degrees in the development of the relevant capacities co-vary with degrees of responsibility. In this article it is argued that, the move from...... the view that responsibility requires certain mental capacities to the position that degrees of responsibility co-vary with degrees of the development of the mental capacities, is premature....

  1. CDMA systems capacity engineering

    CERN Document Server

    Kim, Kiseon

    2004-01-01

    This new hands-on resource tackles capacity planning and engineering issues that are crucial to optimizing wireless communication systems performance. Going beyond the system physical level and investigating CDMA system capacity at the service level, this volume is the single-source for engineering and analyzing systems capacity and resources.

  2. 分子热力学前沿基础研究领域中的新理论12:论气体定压比热的理论计算法%New theory of the leading basic research of molecular thermodynamics 12: argon model and theoretic equation for calculation of gaseous heat capacity

    Institute of Scientific and Technical Information of China (English)

    张克武; 张宇英

    2006-01-01

    提出气体不平衡状态方程后,将其移植应用于气体平衡性质的研究,建立气体定压比热理论方程和两个定理;经用各种结构类型的538种气体纯质2398个实验数据检验,平均误差0.38%,显著优于文献中各式,尤其突出的是物理意义明晰,有一定的理论意义与实际应用价值,在基础理论研究中取得重要进展.%According to differential equation of Argon model the author has proposed a theoretical equation for the nonequilibrium state of gases (TENSG), that is extended here to the theoretical calculation of gaseous heat capacity. Thus an equation of the heat capacity of gases at constant pressure is derived. This equation applies to both polar and nonpolar gases, the average error from 2398 experimental values being 0. 38% based on 538 compounds. The method is far better than the other published methods. These results show that this work makes a great progress in basic research.

  3. Apparent molar volumes and apparent molar heat capacities of aqueous adonitol, dulcitol, glycerol, meso-erythritol, myo-inositol, D-sorbitol, and xylitol at temperatures from (278.15 to 368.15) K and at the pressure 0.35 MPa

    Energy Technology Data Exchange (ETDEWEB)

    Blodgett, M.B. [Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT, 84602-5700 (United States); Ziemer, S.P. [Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT, 84602-5700 (United States); Brown, B.R. [Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT, 84602-5700 (United States); Niederhauser, T.L. [Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT, 84602-5700 (United States); Woolley, E.M. [Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT, 84602-5700 (United States)]. E-mail: earl_woolley@byu.edu

    2007-04-15

    Apparent molar volumes V {sub {phi}} were determined for aqueous adonitol, dulcitol, glycerol, meso-erythritol, myo-inositol, D-sorbitol, and xylitol at temperatures from (278.15 to 368.15) K and at the pressure 0.35 MPa, and apparent molar heat capacities C {sub p,{phi}} of the same solutions were determined at temperatures from (278.15 to 363.15) K at the same pressure. Molalities m/(mol . kg{sup -1}) of the solutions were in the range (0.02 {<=} m {<=} 3.2) for adonitol, (0.02 {<=} m {<=} 0.15) for dulcitol, (0.02 {<=} m {<=} 5.0) for glycerol, (0.02 {<=} m {<=} 3.0) for meso-erythritol, (0.02 {<=} m {<=} 0.5) for myo-inositol, (0.02 {<=} m {<=} 2.0) for D-sorbitol, and (0.02 {<=} m {<=} 2.7) for xylitol. A vibrating tube densimeter was used to obtain solution densities and a fixed-cell temperature scanning calorimeter was used to obtain heat capacities. Values of V {sub {phi}} and C {sub p,{phi}} for these sugar alcohols are discussed relative to one another and compared to values from the literature, where available.

  4. Experimental determination of the specific heat capacity c sub p and the differential Joule-Thomson effect. mu. of FFC R227 (C sub 3 HF sub 7 ). Experimentelle Bestimmung der spezifischen Waermekapazitaet c sub p und des differentiellen Joule-Thomson-Effektes. mu. des chlorfreien Arbeitsstoffes R227 (C sub 3 HF sub 7 )

    Energy Technology Data Exchange (ETDEWEB)

    Wirbser, H.; Ernst, G.; Braeuning, G. (Karlsruhe Univ. (T.H.) (Germany, F.R.). Inst. fuer Technische Thermodynamik)

    1990-01-01

    To prove the suitability of R227 (C{sub 3}HF{sub 7}) as a substitute for chlorinated hydrocarbons, exact measurements of its c{sub p} and {mu} were performed at temperatures between -20deg C and 150deg C and at pressures up to 15.0 MPa at Institut fuer Technische Thermodynamik (University of Karlsruhe). Measurements to determine the ideal share of the specific heat capacity c{sub p}{sup 0} were performed using low-pressure equipment. All other measurements were performed using high-pressure and high-temperature systems. Using the high-pressure system, the specific heat capacity c{sub p} of R227 in the liquid and supercritical phases was measured at 117 points, and the differential Joule-Thomson effect {mu} in the liquid and supercritical phases was measured at 66 points. These selectively chosen phase points allowed an easy calculation of the enthalpy function h(p, T). (orig./HW).

  5. 46 CFR 154.178 - Contiguous hull structure: Heating system.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Contiguous hull structure: Heating system. 154.178... Equipment Hull Structure § 154.178 Contiguous hull structure: Heating system. The heating system for... the heating capacity to meet § 154.174(b)(2) or § 154.176(b)(2); (b) Have stand-by heating to...

  6. Transience and capacity of minimal submanifolds

    DEFF Research Database (Denmark)

    Markvorsen, Steen; Palmer, V.

    2003-01-01

    We prove explicit lower bounds for the capacity of annular domains of minimal submanifolds P-m in ambient Riemannian spaces N-n with sectional curvatures bounded from above. We characterize the situations in which the lower bounds for the capacity are actually attained. Furthermore we apply...... these bounds to prove that Brownian motion defined on a complete minimal submanifold is transient when the ambient space is a negatively curved Hadamard-Cartan manifold. The proof stems directly from the capacity bounds and also covers the case of minimal submanifolds of dimension m > 2 in Euclidean spaces....

  7. Heat Stress

    Science.gov (United States)

    ... Publications and Products Programs Contact NIOSH NIOSH HEAT STRESS Recommend on Facebook Tweet Share Compartir NEW OSHA- ... hot environments may be at risk of heat stress. Exposure to extreme heat can result in occupational ...

  8. Heating automation

    OpenAIRE

    Tomažič, Tomaž

    2013-01-01

    This degree paper presents usage and operation of peripheral devices with microcontroller for heating automation. The main goal is to make a quality system control for heating three house floors and with that, increase efficiency of heating devices and lower heating expenses. Heat pump, furnace, boiler pump, two floor-heating pumps and two radiator pumps need to be controlled by this system. For work, we have chosen a development kit stm32f4 - discovery with five temperature sensors, LCD disp...

  9. Passive Vaporizing Heat Sink

    Science.gov (United States)

    Knowles, TImothy R.; Ashford, Victor A.; Carpenter, Michael G.; Bier, Thomas M.

    2011-01-01

    A passive vaporizing heat sink has been developed as a relatively lightweight, compact alternative to related prior heat sinks based, variously, on evaporation of sprayed liquids or on sublimation of solids. This heat sink is designed for short-term dissipation of a large amount of heat and was originally intended for use in regulating the temperature of spacecraft equipment during launch or re-entry. It could also be useful in a terrestrial setting in which there is a requirement for a lightweight, compact means of short-term cooling. This heat sink includes a hermetic package closed with a pressure-relief valve and containing an expendable and rechargeable coolant liquid (e.g., water) and a conductive carbon-fiber wick. The vapor of the liquid escapes when the temperature exceeds the boiling point corresponding to the vapor pressure determined by the setting of the pressure-relief valve. The great advantage of this heat sink over a melting-paraffin or similar phase-change heat sink of equal capacity is that by virtue of the =10x greater latent heat of vaporization, a coolant-liquid volume equal to =1/10 of the paraffin volume can suffice.

  10. Measurement of negative ion density in a pulsed multicusp negative ion source

    Energy Technology Data Exchange (ETDEWEB)

    Coonan, B.; Mellon, K.N.; Hopkins, M.B. (Dublin City University, Dublin (Ireland))

    1992-10-05

    The production of negative ion beams for use in neutral beam injection heating has become an important area of research in recent years. This paper discusses the negative ion densities measured in a pulsed multicusp volume ion source using photodetachment diagnostic technique. A pulse modulated negative ion source is being used as an alternative to the tandem source and an increase in negative ion extracted current has previously been observed by Hopkins and Mellon. Work with photodetachment quoted in this paper shows an increase in negative ion density during the post discharge similar to previous results obtained using an accelerator to extract the negative ions.

  11. Negation and negative concord in romance

    NARCIS (Netherlands)

    Swart, Henriëtte de; Sag, I.A.

    This paper addresses the two interpretations a combination of negative indefinites can get in concord languages like French, namely a concord reading which amounts to a single negation, or a double negation reading. We develop an analysis in a polyadic framework, in which a sequence of

  12. Capacity at Railway Stations

    DEFF Research Database (Denmark)

    Landex, Alex

    2011-01-01

    Stations do have other challenges regarding capacity than open lines as it is here the traffic is dispatched. The UIC 406 capacity method that can be used to analyse the capacity consumption can be exposed in different ways at stations which may lead to different results. Therefore, stations need...... special focus when conducting UIC 406 capacity analyses.This paper describes how the UIC 406 capacity method can be expounded for stations. Commonly for the analyses of the stations it is recommended to include the entire station including the switch zone(s) and all station tracks. By including the switch...... is changed, this paper recommends that the railway lines are not always be divided. In case trains turn around on open (single track) line, the capacity consumption may be too low if a railway line is divided. The same can be the case if only few trains are overtaken at an overtaking station. For dead end...

  13. Evaluation of railway capacity

    DEFF Research Database (Denmark)

    Landex, Alex; Kaas, Anders H.; Schittenhelm, Bernd

    2006-01-01

    This paper describes the relatively new UIC 406 method for calculating capacity consumption on railway lines. The UIC 406 method is an easy and effective way of calculating the capacity consumption, but it is possible to expound the UIC 406 method in different ways which can lead to different...... capacity consumptions. This paper describes the UIC 406 method and how it is expounded in Denmark. The paper describes the importance of choosing the right length of the line sections examined and how line sections with multiple track sections are examined. Furthermore, the possibility of using idle...... capacity to run more trains is examined. The paper presents a method to examine the expected capacity utilization of future timetables. The method is based on the plan of operation instead of the exact (known) timetable. At the end of the paper it is described how it is possible to make capacity statements...

  14. Capacity Building in Vietnam

    OpenAIRE

    Adam McCarty

    2001-01-01

    This report is the outcome of a study commissioned to examine the capacity building needs in Vietnam, and is a supplementary document to the Asian Development Bank's Country Operational Strategy for Vietnam. Vietnam's needs in terms of capacity building are particularly important given that is it a transitional economy and also one with little institutional experience in dealing with the international donor community. This paper examines the international awareness of capacity building and ca...

  15. Heat pumps in combined heat and power systems

    DEFF Research Database (Denmark)

    Ommen, Torben Schmidt; Markussen, Wiebke Brix; Elmegaard, Brian

    2014-01-01

    of the considered cases. When considering a case where the heat pump is located at a CHP (combined heat and power) plant, a configuration that increases the DH return temperature proposes the lowest operation cost, as low as 12 EUR MWh-1 for a 90 °C e 40 °C DH network. Considering the volumetric heating capacity......Heat pumps have previously been proposed as a way to integrate higher amounts of renewable energy in DH (district heating) networks by integrating, e.g., wind power. The paper identifies and compares five generic configurations of heat pumps in DH systems. The operational performance......, a third configuration is superior in all cases. Finally, the three most promising heat pump configurations are integrated in a modified PQ-diagram of the CHP plant. Each show individual advantages, and for two, also disadvantages in order to achieve flexible operation....

  16. Solar-powered Rankine heat pump for heating and cooling

    Science.gov (United States)

    Rousseau, J.

    1978-01-01

    The design, operation and performance of a familyy of solar heating and cooling systems are discussed. The systems feature a reversible heat pump operating with R-11 as the working fluid and using a motor-driven centrifugal compressor. In the cooling mode, solar energy provides the heat source for a Rankine power loop. The system is operational with heat source temperatures ranging from 155 to 220 F; the estimated coefficient of performance is 0.7. In the heating mode, the vapor-cycle heat pump processes solar energy collected at low temperatures (40 to 80 F). The speed of the compressor can be adjusted so that the heat pump capacity matches the load, allowing a seasonal coefficient of performance of about 8 to be attained.

  17. 变容量家庭能源中心单独制热水模式的实验研究%Experimental study on water heating mode of domestic energy system with variable capacity compressor

    Institute of Scientific and Technical Information of China (English)

    鲁双; 吴静怡

    2014-01-01

    提出了可全年供应空调和热水需要的变容量家庭能源中心系统,并提出单独制热水模式下的性能系数计算方法。通过对该模式瞬时动态特性的研究,指出变容量压缩机可以有效地保证机组的安全可靠运行。实验研究了单独制热水模式在不同环境温度、不同压缩机负荷条件下的性能。结果表明,在同一压缩机负荷条件下,热水性能系数均随环境温度的升高而升高,与传统热泵热水器的变化趋势相同。而压缩机负荷变化对机组热水性能系数的影响在不同的环境温度下呈现不同的规律,因此,可根据不同的环境温度优化控制压缩机负荷,以提高制热水效率,节约能源。%A domestic energy system was introduced,which can realize the supply of space heating, cooling and domestic hot water throughout the year.The authors proposed a new system performance indicator to describe energy efficiency of the water heating mode.A serial of experiments were conducted under variable conditions.The transient performance shows that the compressor control is more effective than the outdoor fan speed control for safe and reliable operation.When the compressor load is fixed,the mode has similar performance trend to the traditional heat pump water heater under different outdoor temperature conditions. However, the influence of compressor load varies significantly with ambient temperature.The system efficiency of 100% compressor load is not the highest,especially when ambient temperature is relatively high.Optimized compressor load control can help to improve energy efficiency.

  18. First-principles study of the phonon sp ectrum and heat capacity of TATB crystal%TATB晶体声子谱及比热容的第一性原理研究∗

    Institute of Scientific and Technical Information of China (English)

    蒋文灿; 陈华; 张伟斌

    2016-01-01

    The widely used energetic material 1, 3, 5-triamino-2, 4, 6-trinitrobenzene (TATB) is an extremely powerful explosive and known for its extraordinary insensitivity to external stimuli (i.e., shock, friction, impact). TATB crystal exhibits graphitic-like sheets with significant inter- and intra-molecular hydrogen bondings within each layer and weak van der Waals (vdW) interactions between layers. Although TATB has been extensively studied both theoretically and experimentally, a fully understanding of its unique detonation phenomenon at a microscopic level is still lacking. Before establishing the exact pathway through which the initial energy is transferred, a fundamental knowledge of both the lattice vibrations (phonons) and molecule internal vibrations must be gained at the first step. Recently, it has been demonstrated that density functional theory (DFT) is inadequate in treating conventional energetic materials, within which dispersion interactions appear to be major contributors to the binding forces. In the present work, phonon spectrum and specific heat of TATB crystal are calculated in the framework of DFT with vdW-DF2 correction, which has been validated in our previous studies of the equation of state, structure and vibration property of TATB crystal under pressures in a range of 0–8.5 GPa. Structure optimization is preformed at zero-pressure, followed by calculating the equation of state, crystal density and lattice energy. The computed results are found to fit well with the experimental and other theoretical values. Frozen phonon method is used to calculate the phonon spectrum and phonon density of states. We find that the phonon density of states reaches its maximum at a vibration frequency of 2.3 THz, which is in good agreement with the strong absorption peak at 2.22 THz observed by THz spectroscopy. The assignment of several Raman active vibrations of TATB above 7.5 THz is given, and a comparison with other published results is also made in this

  19. Visualising dual downregulation of insulin-like growth factor receptor-1 and vascular endothelial growth factor-A by heat shock protein 90 inhibition effect in triple negative breast cancer

    NARCIS (Netherlands)

    Terwisscha Van Scheltinga, Anton G. T.; Berghuis, Paul; Nienhuis, Hilde H.; Timmer-Bosscha, Hetty; Pot, Linda; Gaykema, Sietske B. M.; Lub-de Hooge, Marjolijn N.; Kosterink, Jos G. W.; de Vries, Elisabeth G. E.; Schroder, Carolien P.

    Purpose: Triple negative breast cancer (TNBC) is biologically characterised by heterogeneous presence of molecular pathways underlying it. Insulin-like growth factor receptor-1 (IGF-1R) expression and vascular endothelial growth factor-A (VEGF-A) have been identified as key factors in these pathways

  20. Heat pumps

    CERN Document Server

    Macmichael, DBA

    1988-01-01

    A fully revised and extended account of the design, manufacture and use of heat pumps in both industrial and domestic applications. Topics covered include a detailed description of the various heat pump cycles, the components of a heat pump system - drive, compressor, heat exchangers etc., and the more practical considerations to be taken into account in their selection.