Investigation on water content in fresco mock-ups in the microwave and near-IR spectral regions

International Nuclear Information System (INIS)

Magrini, Donata; Riminesi, Cristiano; Cucci, Costanza; Olmi, Roberto; Picollo, Marcello

2017-01-01

Water diffusion inside masonry is responsible for the majority of the decay phenomena observed in wall paintings and frescos. Thus, the diagnostics of moisture and water content and their monitoring represent a key issue. In order to preserve the integrity of surfaces of artistic interest, investigations by means of non-destructive techniques (NDT) are preferred over others. The aim of this research is to determine methodologies to quantify the moisture content (MC) of frescos by means of the integrated use of two non-invasive techniques, namely fiber optic reflectance spectroscopy (FORS) in the near-IR region and evanescent field dielectrometry (EFD) in the microwave range. The FORS technique has been employed in order to assess the amount of water adsorbed from the surface by means of an analysis of the reflectance spectra in the Vis–NIR (350-2200 nm) range. This technique investigates the electronic and vibrational transitions that are characteristic of each compound and enables their identification. The water content is evaluated on the basis of the 1920 nm and 1450 nm absorption bands. The EFD system consists of a resonant probe connected to a network analyzer. The resonance frequency of the cavity under different moisture-content conditions of frescos is in the 1.0–1.5 GHz range. The device makes it possible to compute, in real time, the MC from a measurement of the transmission coefficient (amplitude versus frequency) through the probe. Fresco mock-ups have been prepared in collaboration with the Opificio delle Pietre Dure in order to recreate most of the possible chromatic shades obtained by mixing iron oxides and hydroxide-based pigments. Measurements were performed by employing both techniques on fresco models after wet-dry cycles obtained by means of poultices with a known water content. The results obtained with these two techniques were compared, and cross relationships between the EFD and FORS data were defined. (paper)

UV, visible, and near-IR reflectivity data for magnetic soils/rocks from Brazil

Science.gov (United States)

Vempati, R. K.; Morris, R. V.; Lauer, H. V., Jr.; Coey, J. M. D.

1991-01-01

The objective is to obtain UV, visible, and near-IR reflectivity spectra for several magnetic Brazilian soils/rocks and compare them to corresponding data for Mars to see if these materials satisfy both magnetic and spectral constraints for Mars. Selected physical properties of the magnetic Brazilian soils/rocks are presented. In general, the spectral features resulting from ferric crystal-field transitions are much better defined in the spectra of the magnetic Brazilian soils/rocks than in Martian spectral data. Presumably, this results from a relatively higher proportion of crystalline ferric oxides for the former. The apparent masking of the spectral signature of maghemite by hematite or goethite for the Brazilian samples implies the magnetic and spectral constraints for Mars can be decoupled. That is, maghemite may be present in magnetically-significant but optically-insignificant amounts compared to crystalline hematite.

Near-IR imaging of cracks in teeth

Science.gov (United States)

Fried, William A.; Simon, Jacob C.; Lucas, Seth; Chan, Kenneth H.; Darling, Cynthia L.; Staninec, Michal; Fried, Daniel

2014-02-01

Dental enamel is highly transparent at near-IR wavelengths and several studies have shown that these wavelengths are well suited for optical transillumination for the detection and imaging of tooth decay. We hypothesize that these wavelengths are also well suited for imaging cracks in teeth. Extracted teeth with suspected cracks were imaged at several wavelengths in the near-IR from 1300-1700-nm. Extracted teeth were also examined with optical coherence tomography to confirm the existence of suspected cracks. Several teeth of volunteers were also imaged in vivo at 1300-nm to demonstrate clinical potential. In addition we induced cracks in teeth using a carbon dioxide laser and imaged crack formation and propagation in real time using near-IR transillumination. Cracks were clearly visible using near-IR imaging at 1300-nm in both in vitro and in vivo images. Cracks and fractures also interfered with light propagation in the tooth aiding in crack identification and assessment of depth and severity.

IR spectral analysis for the diagnostics of crust earthquake precursors

Science.gov (United States)

Umarkhodgaev, R. M.; Liperovsky, V. A.; Mikhailin, V. V.; Meister, C.-V.; Naumov, D. Ju

2012-04-01

In regions of future earthquakes, a few days before the seismic shock, the emanation of radon and hydrogen is being observed, which causes clouds of increased ionisation in the atmosphere. In the present work the possible diagnostics of these clouds using infrared (IR) spectroscopy is considered, which may be important and useful for the general geophysical system of earthquake prediction and the observation of industrial emissions of radioactive materials into the atmosphere. Some possible physical processes are analysed, which cause, under the condition of additional ionisation in a pre-breakdown electrical field, emissions in the IR interval. In doing so, the transparency region of the IR spectrum at wavelengths of 7-15 μm is taken into account. This transparency region corresponds to spectral lines of small atmospheric constituents like CH4, CO2, N2O, NO2, NO, and O3. The possible intensities of the IR emissions observable in laboratories and in nature are estimated. The acceleration process of the electrons in the pre-breakdown electrical field before its adhesion to the molecules is analysed. The laboratory equipment for the investigation of the IR absorption spectrum is constructed for the cases of normal and decreased atmospheric pressures. The syntheses of ozone and nitrous oxides are performed in the barrier discharge. It is studied if the products of the syntheses may be used to model atmospheric processes where these components take part. Spectra of products of the syntheses in the wavelength region of 2-10 μm are observed and analysed. A device is created for the syntheses and accumulation of nitrous oxides. Experiments to observe the IR-spectra of ozone and nitrous oxides during the syntheses and during the further evolution of these molecules are performed. For the earthquake prediction, practically, the investigation of emission spectra is most important, but during the laboratory experiments, the radiation of the excited molecules is shifted by a

Mid-IR laser system for advanced neurosurgery

Science.gov (United States)

Klosner, M.; Wu, C.; Heller, D. F.

2014-03-01

We present work on a laser system operating in the near- and mid-IR spectral regions, having output characteristics designed to be optimal for cutting various tissue types. We provide a brief overview of laser-tissue interactions and the importance of controlling certain properties of the light beam. We describe the principle of operation of the laser system, which is generally based on a wavelength-tunable alexandrite laser oscillator/amplifier, and multiple Raman conversion stages. This configuration provides robust access to the mid-IR spectral region at wavelengths, pulse energies, pulse durations, and repetition rates that are attractive for neurosurgical applications. We summarize results for ultra-precise selective cutting of nerve sheaths and retinas with little collateral damage; this has applications in procedures such as optic-nerve-sheath fenestration and possible spinal repair. We also report results for cutting cornea, and dermal tissues.

Composite multilobe descriptors for cross-spectral recognition of full and partial face

Science.gov (United States)

Cao, Zhicheng; Schmid, Natalia A.; Bourlai, Thirimachos

2016-08-01

Cross-spectral image matching is a challenging research problem motivated by various applications, including surveillance, security, and identity management in general. An example of this problem includes cross-spectral matching of active infrared (IR) or thermal IR face images against a dataset of visible light images. A summary of recent developments in the field of cross-spectral face recognition by the authors is presented. In particular, it describes the original form and two variants of a local operator named composite multilobe descriptor (CMLD) for facial feature extraction with the purpose of cross-spectral matching of near-IR, short-wave IR, mid-wave IR, and long-wave IR to a gallery of visible light images. The experiments demonstrate that the variants of CMLD outperform the original CMLD and other recently developed composite operators used for comparison. In addition to different IR spectra, various standoff distances from close-up (1.5 m) to intermediate (50 m) and long (106 m) are also investigated. Performance of CMLD I to III is evaluated for each of the three cases of distances. The newly developed operators, CMLD I to III, are further utilized to conduct a study on cross-spectral partial face recognition where different facial regions are compared in terms of the amount of useful information they contain for the purpose of conducting cross-spectral face recognition. The experimental results show that among three facial regions considered in the experiments the eye region is the most informative for all IR spectra at all standoff distances.

Near-IR laser-based spectrophotometer for comparative analysis of isotope content of CO2 in exhale air samples

International Nuclear Information System (INIS)

Stepanov, E V; Glushko, A N; Kasoev, S G; Koval', A V; Lapshin, D A

2011-01-01

We present a laser spectrophotometer aimed at high-accuracy comparative analysis of content of 12 CO 2 and 13 CO 2 isotope modifications in the exhale air samples and based on a tunable near-IR diode laser (2.05 μm). The two-channel optical scheme of the spectrophotometer and the special digital system for its control are described. An algorithm of spectral data processing aimed at determining the difference in the isotope composition of gas mixtures is proposed. A few spectral regions (near 4880 cm -1 ) are determined to be optimal for analysis of relative content of 12 CO 2 and 13 CO 2 in the exhale air. The use of the proposed spectrophotometer scheme and the developed algorithm makes the results of the analysis less susceptible to the influence of the interference in optical elements, to the absorption in the open atmosphere, to the slow drift of the laser pulse envelope, and to the offset of optical channels. The sensitivity of the comparative analysis of the isotope content of CO 2 in exhale air samples, achieved using the proposed scheme, is estimated to be nearly 0.1‰.

Multi-pollutants sensors based on near-IR telecom lasers and mid-IR difference frequency generation: development and applications; Instruments de mesure multi-polluants par spectroscopie infrarouge bases sur des lasers fibres et par generation de difference de frequences: developpement et applications

Energy Technology Data Exchange (ETDEWEB)

Cousin, J

2006-12-15

At present the detection of VOC and other anthropic trace pollutants is an important challenge in the measurement of air quality. Infrared spectroscopy, allowing spectral regions rich in molecular absorption to be probed, is a suitable technique for in-situ monitoring of the air pollution. Thus the aim of this work was to develop instruments capable of detecting multiple pollutants for in-situ monitoring by IR spectroscopy. A first project benefited from the availability of the telecommunications lasers emitting in near-IR. This instrument was based on an external cavity diode laser (1500 - 1640 nm) in conjunction with a multipass cell (100 m). The detection sensitivity was optimised by employing a balanced detection and a sweep integration procedure. The instrument developed is deployable for in-situ measurements with a sensitivity of < 10{sup -8} cm{sup -1} Hz{sup -1/2} and allowed the quantification of chemical species such as CO{sub 2}, CO, C{sub 2}H{sub 2}, CH{sub 4} and the determination of the isotopic ratio {sup 13}CO{sub 2}/{sup 12}CO{sub 2} in combustion environment The second project consisted in mixing two near-IR fiber lasers in a non-linear crystal (PPLN) in order to produce a laser radiation by difference frequency generation in the middle-IR (3.15 - 3.43 {mu}m), where the absorption bands of the molecules are the most intense. The first studies with this source were carried out on detection of ethylene (C{sub 2}H{sub 4}) and benzene (C{sub 6}H{sub 6}). Developments, characterizations and applications of these instruments in the near and middle IR are detailed and the advantages of the 2 spectral ranges is highlighted. (author)

THE SPECTACULAR RADIO-NEAR-IR-X-RAY JET OF 3C 111: THE X-RAY EMISSION MECHANISM AND JET KINEMATICS

Energy Technology Data Exchange (ETDEWEB)

Clautice, Devon; Perlman, Eric S. [Department of Physics and Space Sciences, Florida Institute of Technology, 150 W. University Boulevard, Melbourne, FL 32901 (United States); Georganopoulos, Markos [Department of Physics, University of Maryland—Baltimore County, 1000 Hilltop Circle, Baltimore, MD 21250 (United States); Lister, Matthew L.; Hogan, Brandon [Department of Physics and Astronomy, Purdue University, 525 Northwestern Avenue, West Lafayette, IN 47907 (United States); Tombesi, Francesco [Department of Astronomy, University of Maryland, College Park, MD 20742-2421 (United States); Cara, Mihai [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Marshall, Herman L. [Kavli Institute for Astrophysics and Space Research, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Kazanas, Demos [NASA’s Goddard Space Flight Center, Astrophysics Science Division, Code 663, Greenbelt, MD 20771 (United States)

2016-08-01

Relativistic jets are the most energetic manifestation of the active galactic nucleus (AGN) phenomenon. AGN jets are observed from the radio through gamma-rays and carry copious amounts of matter and energy from the sub-parsec central regions out to the kiloparsec and often megaparsec scale galaxy and cluster environs. While most spatially resolved jets are seen in the radio, an increasing number have been discovered to emit in the optical/near-IR and/or X-ray bands. Here we discuss a spectacular example of this class, the 3C 111 jet, housed in one of the nearest, double-lobed FR II radio galaxies known. We discuss new, deep Chandra and Hubble Space Telescope ( HST ) observations that reveal both near-IR and X-ray emission from several components of the 3C 111 jet, as well as both the northern and southern hotspots. Important differences are seen between the morphologies in the radio, X-ray, and near-IR bands. The long (over 100 kpc on each side), straight nature of this jet makes it an excellent prototype for future, deep observations, as it is one of the longest such features seen in the radio, near-IR/optical, and X-ray bands. Several independent lines of evidence, including the X-ray and broadband spectral shape as well as the implied velocity of the approaching hotspot, lead us to strongly disfavor the EC/CMB model and instead favor a two-component synchrotron model to explain the observed X-ray emission for several jet components. Future observations with NuSTAR , HST , and Chandra will allow us to further constrain the emission mechanisms.

NEAR-INFRARED IMAGING AND SPECTROSCOPIC SURVEY OF THE SOUTHERN REGION OF THE YOUNG OPEN CLUSTER NGC 2264

Energy Technology Data Exchange (ETDEWEB)

Marinas, Naibi; Lada, Elizabeth A. [Astronomy Department, University of Florida, Gainesville, FL 32611 (United States); Teixiera, Paula S. [Department of Astrophysics, University of Vienna, Tuerkenschanzstrasse 17, A-1180 Vienna (Austria); Lada, Charles J. [Harvard-Smithsonian CFA, Cambridge, MA (United States)

2013-08-01

We have obtained JHK near-IR images and JH band low-resolution spectra of candidate members of the southern region of the young open cluster NGC 2264. We have determined spectral types from H-band spectra for 54 sources, 25 of which are classified for the first time. The stars in our sample cover a large range of spectral types (A8-M8). Using a cluster distance of 780 pc, we determined a median age of 1 Myr for this region of NGC 2264, with 90% of the stars being 5 Myr or younger. To improve the statistical significance of our sample, we included 66 additional cluster members within our field of view with optical spectral classification in the literature. We derived infrared excesses using stellar properties to model the photospheric emission for each source and the extinction to correct FLAMINGOS near-IR and Spitzer mid-IR photometry, and obtained a disk fraction of 51% {+-} 5% for the region. Binning the stars by stellar mass, we find a disk fraction of 38% {+-} 9% for the 0.1-0.3 solar mass group, 55% {+-} 6% for 0.3-1 solar masses, and 58% {+-} 10% for the higher than 1 solar mass group. The lower disk fraction for the lower mass stars is similar to the results found in non-cluster regions like Taurus and Chamaeleon, but differs from the older 3 Myr cluster IC 348 in which the disk fraction is lower for the higher mass stars. This mass-dependent disk fraction is accentuated in the sample with isochrone ages younger than 2 Myr. Here, we find that 45% {+-} 11% of the 0.1-0.3 solar mass stars have disks, 60% {+-} 7% of the 0.3-1 solar mass stars have disks, and all 1-3 solar mass stars have disks. Stellar masses might be an important factor in the ability of a system to form or retain a disk early on. However, regardless of the stellar mass, the large infrared excesses expected from optically thick disks disappear within the first 2 Myr for all stars in our study and small excesses from optically thin disks are found mostly in sources younger than 4 Myr.

Composite films prepared by plasma ion-assisted deposition (IAD) for design and fabrication of antireflection coatings in visible and near-infrared spectral regions

Science.gov (United States)

Tsai, Rung-Ywan; Ho, Fang C.

1994-11-01

Ion-assisted deposition (IAD) processes configured with a well-controlled plasma source at the center base of a vacuum chamber, which accommodates two independent e-gun sources, is used to deposition TiO2MgF2 and TiO2-SiO2 composite films of selected component ratios. Films prepared by this technology are found durable, uniform, and nonabsorbing in visible and near-IR regions. Single- and multilayer antireflection coatings with refractive index from 1.38 to 2.36 at (lambda) equals 550 nm are presented. Methods of enhancement in optical performance of these coatings are studied. The advantages of AR coatings formed by TiO2-MgF2 composite films over those similar systems consisting of TiO2-SiO2 composite films in both visible and near-IR regions are also presented.

Structure and linear spectroscopic properties of near IR polymethine dyes

International Nuclear Information System (INIS)

Webster, Scott; Padilha, Lazaro A.; Hu Honghua; Przhonska, Olga V.; Hagan, David J.; Van Stryland, Eric W.; Bondar, Mikhail V.; Davydenko, Iryna G.; Slominsky, Yuriy L.; Kachkovski, Alexei D.

2008-01-01

We performed a detailed experimental investigation and quantum-chemical analysis of a new series of near IR polymethine dyes with 5-butyl-7,8-dihydrobenzo[cd]furo[2,3-f]indolium terminal groups. We also synthesized and studied two neutral dyes, squaraine and tetraone, with the same terminal groups and performed a comparison of the spectroscopic properties of this set of 'near IR' dyes (polymethine, squaraine, and tetraone) with an analogous set of 'visible' dyes with simpler benzo[e]indolium terminal groups. From these measurements, we find that the dyes with dihydrobenzo[cd]furo[2,3-f]indolium terminal groups are characterized by a remarkably large shift ∼300 nm (∼200 nm for tetraone) of their absorption bands towards the red region. We discuss the difference in electronic structure for these molecules and show that the 'near IR' dyes are characterized by an additional weak fluorescence band from the higher lying excited states connected with the terminal groups. Absorption spectra for the longest polymethines are solvent-dependent and are characterized by a broadening of the main band in polar solvents, which is explained by ground state symmetry breaking and reduced charge delocalization within the polymethine chromophore. The results of these experiments combined with the agreement of quantum chemical calculations moves us closer to a predictive capability for structure-property relations in cyanine-like molecules

Constraining Cometary Crystal Shapes from IR Spectral Features

Science.gov (United States)

Wooden, D. H.; Lindsay, S.; Harker, D. E.; Kelley, M. S.; Woodward, C. E.; Murphy, J. R.

2013-12-01

A major challenge in deriving the silicate mineralogy of comets is ascertaining how the anisotropic nature of forsterite crystals affects the spectral features' wavelength, relative intensity, and asymmetry. Forsterite features are identified in cometary comae near 10, 11.05-11.2, 16, 19, 23.5, 27.5 and 33 μm [1-10], so accurate models for forsterite's absorption efficiency (Qabs) are a primary requirement to compute IR spectral energy distributions (SEDs, λFλ vs. λ) and constrain the silicate mineralogy of comets. Forsterite is an anisotropic crystal, with three crystallographic axes with distinct indices of refraction for the a-, b-, and c-axis. The shape of a forsterite crystal significantly affects its spectral features [13-16]. We need models that account for crystal shape. The IR absorption efficiencies of forsterite are computed using the discrete dipole approximation (DDA) code DDSCAT [11,12]. Starting from a fiducial crystal shape of a cube, we systematically elongate/reduce one of the crystallographic axes. Also, we elongate/reduce one axis while the lengths of the other two axes are slightly asymmetric (0.8:1.2). The most significant grain shape characteristic that affects the crystalline spectral features is the relative lengths of the crystallographic axes. The second significant grain shape characteristic is breaking the symmetry of all three axes [17]. Synthetic spectral energy distributions using seven crystal shape classes [17] are fit to the observed SED of comet C/1995 O1 (Hale-Bopp). The Hale-Bopp crystalline residual better matches equant, b-platelets, c-platelets, and b-columns spectral shape classes, while a-platelets, a-columns and c-columns worsen the spectral fits. Forsterite condensation and partial evaporation experiments demonstrate that environmental temperature and grain shape are connected [18-20]. Thus, grain shape is a potential probe for protoplanetary disk temperatures where the cometary crystalline forsterite formed. The

Large-format platinum silicide microwave kinetic inductance detectors for optical to near-IR astronomy.

Science.gov (United States)

Szypryt, P; Meeker, S R; Coiffard, G; Fruitwala, N; Bumble, B; Ulbricht, G; Walter, A B; Daal, M; Bockstiegel, C; Collura, G; Zobrist, N; Lipartito, I; Mazin, B A

2017-10-16

We have fabricated and characterized 10,000 and 20,440 pixel Microwave Kinetic Inductance Detector (MKID) arrays for the Dark-speckle Near-IR Energy-resolved Superconducting Spectrophotometer (DARKNESS) and the MKID Exoplanet Camera (MEC). These instruments are designed to sit behind adaptive optics systems with the goal of directly imaging exoplanets in a 800-1400 nm band. Previous large optical and near-IR MKID arrays were fabricated using substoichiometric titanium nitride (TiN) on a silicon substrate. These arrays, however, suffered from severe non-uniformities in the TiN critical temperature, causing resonances to shift away from their designed values and lowering usable detector yield. We have begun fabricating DARKNESS and MEC arrays using platinum silicide (PtSi) on sapphire instead of TiN. Not only do these arrays have much higher uniformity than the TiN arrays, resulting in higher pixel yields, they have demonstrated better spectral resolution than TiN MKIDs of similar design. PtSi MKIDs also do not display the hot pixel effects seen when illuminating TiN on silicon MKIDs with photons with wavelengths shorter than 1 µm.

On the gain properties of “thin” elastically strained InGaAs/InGaAlAs quantum wells emitting in the near-infrared spectral region near 1550 nm

Energy Technology Data Exchange (ETDEWEB)

Novikov, I. I.; Karachinsky, L. Ya. [Connector Optics LLC (Russian Federation); Kolodeznyi, E. S.; Bougrov, V. E. [National Research University of Information Technologies, Mechanics and Optics (Russian Federation); Kurochkin, A. S.; Gladyshev, A. G.; Babichev, A. V. [Connector Optics LLC (Russian Federation); Gadzhiev, I. M.; Buyalo, M. S. [National Research University of Information Technologies, Mechanics and Optics (Russian Federation); Zadiranov, Yu. M.; Usikova, A. A., E-mail: anton@beam.ioffe.ru; Shernyakov, Yu. M. [Russian Academy of Sciences, Ioffe Physical–Technical Institute (Russian Federation); Savelyev, A. V.; Nyapshaev, I. A. [National Research University of Information Technologies, Mechanics and Optics (Russian Federation); Egorov, A. Yu. [Connector Optics LLC (Russian Federation)

2016-10-15

The results of experimental studies of the gain properties of “thin” (3.2 nm thick) elastically strained InGaAs/InGaAlAs quantum wells emitting in the near-infrared spectral region near 1550 nm are presented. The results of studying the threshold and gain characteristics of stripe laser diodes with active regions based on “thin” quantum wells with a lattice–substrate mismatch of +1.0% show that the quantum wells under study exhibit a high modal gain of 11 cm{sup –1} and a low transparency current density of 46 A/cm{sup 2} per quantum well.

The X-Shooter spectral library

NARCIS (Netherlands)

Chen, Y. P.; Trager, S. C.; Peletier, R. F.; Lançon, A.; Prugniel, Ph.; Koleva, M.

2012-01-01

We are building a new spectral library with the X-Shooter instrument on ESO's VLT: XSL, the X-Shooter Spectral Library. We present our progress in building XSL, which covers the wavelength range from the near-UV to the near-IR with a resolution of R˜10000. As of now we have collected spectra for

Optical properties of reduced graphene oxide and CuFe2O4 composites in the IR region

Science.gov (United States)

Ma, De-yue; Li, Xiao-xia; Guo, Yu-xiang; Zeng, Yu-run

2018-01-01

The complex refractive index of reduced graphene oxide and CuFe2O4 composites prepared by hydrothermal method was calculated using infrared Micro-reflective spectra and K-K relation, and the calculation errors were analyzed according to its IR transmission and spectral reflectivity calculated by Fresnel formula. And then normal emissivity of the composite in IR atmospheric window was calculated by means of Fresnel formula and modified refraction angle formula. The calculation accuracy was verified by comparing measured normal total emissivity with the calculated one. The results show that complex refractive index and normal emissivity calculated by the formulas have a high accuracy. It has been found that the composite has a good absorption and radiation characteristics in IR atmospheric window and a strong scattering ability in middle IR region by analyzing its extinction, absorption and radiation properties in IR region. Therefore, it may be used as IR absorption, extinction and radiation materials in some special fields.

Fluorenyl benzothiadiazole and benzoselenadiazole near-IR fluorescent probes for two-photon fluorescence imaging (Conference Presentation)

Science.gov (United States)

Belfield, Kevin D.; Yao, Sheng; Kim, Bosung; Yue, Xiling

2016-03-01

Imaging biological samples with two-photon fluorescence (2PF) microscopy has the unique advantage of resulting high contrast 3D resolution subcellular image that can reach up to several millimeters depth. 2PF probes that absorb and emit at near IR region need to be developed. Two-photon excitation (2PE) wavelengths are less concerned as 2PE uses wavelengths doubles the absorption wavelength of the probe, which means 2PE wavelengths for probes even with absorption at visible wavelength will fall into NIR region. Therefore, probes that fluoresce at near IR region with high quantum yields are needed. A series of dyes based on 5-thienyl-2, 1, 3-benzothiadiazole and 5-thienyl-2, 1, 3-benzoselenadiazole core were synthesized as near infrared two-photon fluorophores. Fluorescence maxima wavelengths as long as 714 nm and fluorescence quantum yields as high as 0.67 were achieved. The fluorescence quantum yields of the dyes were nearly constant, regardless of solvents polarity. These diazoles exhibited large Stokes shift (GM), and high two-photon fluorescence figure of merit (FM , 1.04×10-2 GM). Cells incubated on a 3D scaffold with one of the new probes (encapsulated in Pluronic micelles) exhibited bright fluorescence, enabling 3D two-photon fluorescence imaging to a depth of 100 µm.

A Sensitivity Study on the Effects of Particle Chemistry, Asphericity and Size on the Mass Extinction Efficiency of Mineral Dust in the Earth's Atmosphere: From the Near to Thermal IR

Science.gov (United States)

Hansell, R. A., Jr.; Reid, J. S.; Tsay, S. C.; Roush, T. L.; Kalashnikova, O. V.

2011-01-01

To determine a plausible range of mass extinction efficiencies (MEE) of terrestrial atmospheric dust from the near to thermal IR, sensitivity analyses are performed over an extended range of dust microphysical and chemistry perturbations. The IR values are subsequently compared to those in the near-IR, to evaluate spectral relationships in their optical properties. Synthesized size distributions consistent with measurements, model particle size, while composition is defined by the refractive indices of minerals routinely observed in dust, including the widely used OPAC/Hess parameterization. Single-scattering properties of representative dust particle shapes are calculated using the T-matrix, Discrete Dipole Approximation and Lorenz-Mie light-scattering codes. For the parameterizations examined, MEE ranges from nearly zero to 1.2 square meters per gram, with the higher values associated with non-spheres composed of quartz and gypsum. At near-IR wavelengths, MEE for non-spheres generally exceeds those for spheres, while in the thermal IR, shape-induced changes in MEE strongly depend on volume median diameter (VMD) and wavelength, particularly for MEE evaluated at the mineral resonant frequencies. MEE spectral distributions appear to follow particle geometry and are evidence for shape dependency in the optical properties. It is also shown that non-spheres best reproduce the positions of prominent absorption peaks found in silicates. Generally, angular particles exhibit wider and more symmetric MEE spectral distribution patterns from 8-10 micrometers than those with smooth surfaces, likely due to their edge-effects. Lastly, MEE ratios allow for inferring dust optical properties across the visible-IR spectrum. We conclude the MEE of dust aerosol are significant for the parameter space investigated, and are a key component for remote sensing applications and the study of direct aerosol radiative effects.

LENS MODELS OF HERSCHEL-SELECTED GALAXIES FROM HIGH-RESOLUTION NEAR-IR OBSERVATIONS

Energy Technology Data Exchange (ETDEWEB)

Calanog, J. A.; Cooray, A.; Ma, B.; Casey, C. M. [Department of Physics and Astronomy, University of California, Irvine, CA 92697 (United States); Fu, Hai [Department of Physics and Astronomy, University of Iowa, Van Allen Hall, Iowa City, IA 52242 (United States); Wardlow, J. [Dark Cosmology Centre, Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, DK-2100 Copenhagen (Denmark); Amber, S. [Department of Physical Sciences, The Open University, Milton Keynes MK7 6AA (United Kingdom); Baker, A. J. [Department of Physics and Astronomy, Rutgers, The State University of New Jersey, 136 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Baes, M. [1 Sterrenkundig Observatorium, Universiteit Gent, Krijgslaan 281, B-9000 Gent (Belgium); Bock, J. [California Institute of Technology, 1200 E. California Blvd., Pasadena, CA 91125 (United States); Bourne, N.; Dye, S. [School of Physics and Astronomy, University of Nottingham, NG7 2RD (United Kingdom); Bussmann, R. S. [Department of Astronomy, Space Science Building, Cornell University, Ithaca, NY 14853-6801 (United States); Chapman, S. C. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 0HA (United Kingdom); Clements, D. L. [Astrophysics Group, Imperial College London, Blackett Laboratory, Prince Consort Road, London SW7 2AZ (United Kingdom); Conley, A. [Center for Astrophysics and Space Astronomy 389-UCB, University of Colorado, Boulder, CO 80309 (United States); Dannerbauer, H. [Laboratoire AIM-Paris-Saclay, CEA/DSM/Irfu-CNRS-Université Paris Diderot, CE-Saclay, pt courrier 131, F-91191 Gif-sur-Yvette (France); De Zotti, G. [INAF-Osservatorio Astronomico di Padova, Vicolo dell' Osservatorio 5, I-35122 Padova (Italy); Dunne, L.; Eales, S. [School of Physics and Astronomy, Cardiff University, Queens Buildings, The Parade, Cardiff CF24 3AA (United Kingdom); and others

2014-12-20

We present Keck-Adaptive Optics and Hubble Space Telescope high resolution near-infrared (IR) imaging for 500 μm bright candidate lensing systems identified by the Herschel Multi-tiered Extragalactic Survey and Herschel Astrophysical Terahertz Large Area Survey. Out of 87 candidates with near-IR imaging, 15 (∼17%) display clear near-IR lensing morphologies. We present near-IR lens models to reconstruct and recover basic rest-frame optical morphological properties of the background galaxies from 12 new systems. Sources with the largest near-IR magnification factors also tend to be the most compact, consistent with the size bias predicted from simulations and previous lensing models for submillimeter galaxies (SMGs). For four new sources that also have high-resolution submillimeter maps, we test for differential lensing between the stellar and dust components and find that the 880 μm magnification factor (μ{sub 880}) is ∼1.5 times higher than the near-IR magnification factor (μ{sub NIR}), on average. We also find that the stellar emission is ∼2 times more extended in size than dust. The rest-frame optical properties of our sample of Herschel-selected lensed SMGs are consistent with those of unlensed SMGs, which suggests that the two populations are similar.

BOOTES-IR: near IR follow-up GRB observations by a robotic system

International Nuclear Information System (INIS)

Castro-Tirado, A.J.; Postrigo, A. de Ugarte; Jelinek, M.

2005-01-01

BOOTES-IR is the extension of the BOOTES experiment, which operates in Southern Spain since 1998, to the near IR (NIR). The goal is to follow up the early stage of the gamma ray burst (GRB) afterglow emission in the NIR, alike BOOTES does already at optical wavelengths. The scientific case that drives the BOOTES-IR performance is the study of GRBs with the support of spacecraft like INTEGRAL, SWIFT and GLAST. Given that the afterglow emission in both, the NIR and the optical, in the instances immediately following a GRB, is extremely bright (reached V = 8.9 in one case), it should be possible to detect this prompt emission at NIR wavelengths too. The combined observations by BOOTES-IR and BOOTES-1 and BOOTES-2 will allow for real time identification of trustworthy candidates to have a high redshift (z > 5). It is expected that, few minutes after a GRB, the IR magnitudes be H ∼ 7-10, hence very high quality spectra can be obtained for objects as far as z = 10 by larger instruments

Laboratory oscillator strengths of Sc i in the near-infrared region for astrophysical applications

Science.gov (United States)

Pehlivan, A.; Nilsson, H.; Hartman, H.

2015-10-01

Context. Atomic data is crucial for astrophysical investigations. To understand the formation and evolution of stars, we need to analyse their observed spectra. Analysing a spectrum of a star requires information about the properties of atomic lines, such as wavelengths and oscillator strengths. However, atomic data of some elements are scarce, particularly in the infrared region, and this paper is part of an effort to improve the situation on near-IR atomic data. Aims: This paper investigates the spectrum of neutral scandium, Sc I, from laboratory measurements and improves the atomic data of Sc I lines in the infrared region covering lines in R, I, J, and K bands. Especially, we focus on measuring oscillator strengths for Sc I lines connecting the levels with 4p and 4s configurations. Methods: We combined experimental branching fractions with radiative lifetimes from the literature to derive oscillator strengths (f-values). Intensity-calibrated spectra with high spectral resolution were recorded with Fourier transform spectrometer from a hollow cathode discharge lamp. The spectra were used to derive accurate oscillator strengths and wavelengths for Sc I lines, with emphasis on the infrared region. Results: This project provides the first set of experimental Sc I lines in the near-infrared region for accurate spectral analysis of astronomical objects. We derived 63 log(gf) values for the lines between 5300 Å and 24 300 Å. The uncertainties in the f-values vary from 5% to 20%. The small uncertainties in our values allow for an increased accuracy in astrophysical abundance determinations.

Calibration with near-continuous spectral measurements

DEFF Research Database (Denmark)

Nielsen, Henrik Aalborg; Rasmussen, Michael; Madsen, Henrik

2001-01-01

In chemometrics traditional calibration in case of spectral measurements express a quantity of interest (e.g. a concentration) as a linear combination of the spectral measurements at a number of wavelengths. Often the spectral measurements are performed at a large number of wavelengths and in thi...... by an example in which the octane number of gasoline is related to near infrared spectral measurements. The performance is found to be much better that for the traditional calibration methods....

Metallicity and the spectral energy distribution and spectral types of dwarf O-stars

NARCIS (Netherlands)

Mokiem, MR; Martin-Hernandez, NL; Lenorzer, A; de Koter, A; Tielens, AGGA

We present a systematic study of the effect of metallicity on the stellar spectral energy distribution (SED) of 0 main sequence (dwarf) stars, focussing on the hydrogen and helium ionizing continua, and on the optical and near-IR lines used for spectral classification. The spectra are based on

Metallicity and the spectral energy distribution and spectral types of dwarf O-stars

NARCIS (Netherlands)

Mokiem, M.R.; Martín-Hernández, N.L.; Lenorzer, A.; de Koter, A.; Tielens, A.G.G.M.

2004-01-01

We present a systematic study of the effect of metallicity on the stellar spectral energy distribution (SED) of O main sequence (dwarf) stars, focussing on the hydrogen and helium ionizing continua, and on the optical and near-IR lines used for spectral classification. The spectra are based on

Third-generation intelligent IR focal plane arrays

Science.gov (United States)

Caulfield, H. John; Jack, Michael D.; Pettijohn, Kevin L.; Schlesselmann, John D.; Norworth, Joe

1998-03-01

SBRC is at the forefront of industry in developing IR focal plane arrays including multi-spectral technology and '3rd generation' functions that mimic the human eye. 3rd generation devices conduct advanced processing on or near the FPA that serve to reduce bandwidth while performing needed functions such as automatic target recognition, uniformity correction and dynamic range enhancement. These devices represent a solution for processing the exorbitantly high bandwidth coming off large area FPAs without sacrificing systems sensitivity. SBRC's two-color approach leverages the company's HgCdTe technology to provide simultaneous multiband coverage, from short through long wave IR, with near theoretical performance. IR systems that are sensitive to different spectral bands achieve enhanced capabilities for target identification and advanced discrimination. This paper will provide a summary of the issues, the technology and the benefits of SBRC's third generation smart and two-color FPAs.

Monolayers of gold nanostars with two Near-IR LSPR capable of additive photothermal response

KAUST Repository

Pallavicini, Piersandro

2015-07-06

Monolayers of photothermally responsive gold nanostars on PEI-coated surfaces display two Localized Surface Plasmon Resonances (LSPR) in the near-IR region that can be laser-irradiated either separately, obtaining two different T jumps, or simultaneously, obtaining a T jump equal to the sum of what obtained with separate irradiations

Monolayers of gold nanostars with two Near-IR LSPR capable of additive photothermal response

KAUST Repository

Pallavicini, Piersandro; Basile, Simone; Chirico, Giuseppe; Dacarro, Giacomo; D'Alfonso, Laura; Donà , Alice; Patrini, Maddalena; Falqui, Andrea; Sironi, Laura; Taglietti, Angelo

2015-01-01

Monolayers of photothermally responsive gold nanostars on PEI-coated surfaces display two Localized Surface Plasmon Resonances (LSPR) in the near-IR region that can be laser-irradiated either separately, obtaining two different T jumps, or simultaneously, obtaining a T jump equal to the sum of what obtained with separate irradiations

Near IR spectra of symbiotic stars

International Nuclear Information System (INIS)

Andrillat, Y.

1982-01-01

The author reports on recent observations from the near IR spectra of symbiotic stars. The helium and oxygen lines useful for the construction of theoretical models are identified. Observations for cool stars and novae (nebular phase) are outlined and the spectra of specific symbiotic stars between lambdalambda 8000-11000 are presented and discussed. (Auth./C.F.)

Study on IR Properties of Reduced Graphene Oxide

Science.gov (United States)

Ma, Deyue; Li, Xiaoxia; Guo, Yuxiang; Zeng, Yurun

2018-01-01

Firstly, the reduced graphene oxide was prepared by modified hummer method and characterized. Then, the complex refractive index of reduced graphene oxide in IR band was tested and its IR absorption and radiation properties were researched by correlated calculation. The results show that reduced graphene oxide prepared by hummer method are multilayered graphene with defects and functional groups on its surface. Its absorption in near and far IR bands is strong, but it’s weaker in middle IR band. At the IR atmosphere Window, its normal spectral emissivity decreases with wavelength increasing, and its total normal spectral emissivity in 3 ∼ 5μm and 8 ∼ 14μm are 0.75 and 0.625, respectively. Therefore, reduced graphene oxide can be used as IR absorption and coating materials and have a great potential in microwave and infrared compatible materials.

Outflows in the star-formation region near R CrA

Science.gov (United States)

Hartigan, Patrick; Graham, J. A.

1987-01-01

Photographs, spectra, and velocities are presented for the Herbig-Haro objects and visible stars associated with the star-formation region near R CrA. The new data are used to discuss the gas outflows in the area. At least two flows are present; one is linked with the bright variable star R CrA, and the second with the IR source near HH 100. Special attention is given to HH 101. The velocity and spatial structures HH 101 are complex, but are consistent with condensations inside an expanding shell of material ejected from HH 100IR.

Near-IR period-luminosity relations for pulsating stars in ω Centauri (NGC 5139)

Science.gov (United States)

Navarrete, C.; Catelan, M.; Contreras Ramos, R.; Alonso-García, J.; Gran, F.; Dékány, I.; Minniti, D.

2017-08-01

Aims: The globular cluster ω Centauri (NGC 5139) hosts hundreds of pulsating variable stars of different types, thus representing a treasure trove for studies of their corresponding period-luminosity (PL) relations. Our goal in this study is to obtain the PL relations for RR Lyrae and SX Phoenicis stars in the field of the cluster, based on high-quality, well-sampled light curves in the near-infrared (IR). Methods: Observations were carried out using the VISTA InfraRed CAMera (VIRCAM) mounted on the Visible and Infrared Survey Telescope for Astronomy (VISTA). A total of 42 epochs in J and 100 epochs in KS were obtained, spanning 352 days. Point-spread function photometry was performed using DoPhot and DAOPHOT crowded-field photometry packages in the outer and inner regions of the cluster, respectively. Results: Based on the comprehensive catalog of near-IR light curves thus secured, PL relations were obtained for the different types of pulsators in the cluster, both in the J and KS bands. This includes the first PL relations in the near-IR for fundamental-mode SX Phoenicis stars. The near-IR magnitudes and periods of Type II Cepheids and RR Lyrae stars were used to derive an updated true distance modulus to the cluster, with a resulting value of (m - M)0 = 13.708 ± 0.035 ± 0.10 mag, where the error bars correspond to the adopted statistical and systematic errors, respectively. Adding the errors in quadrature, this is equivalent to a heliocentric distance of 5.52 ± 0.27 kpc. Based on observations collected at the European Organisation for Astronomical Research in the Southern Hemisphere, Chile, with the VISTA telescope (project ID 087.D-0472, PI R. Angeloni).

Near-Infrared Spectroscopic Study of Chlorite Minerals

OpenAIRE

Min Yang; Meifang Ye; Haihui Han; Guangli Ren; Ling Han; Zhuan Zhang

2018-01-01

The mineral chemistry of twenty chlorite samples from the United States Geological Survey (USGS) spectral library and two other regions, having a wide range of Fe and Mg contents and relatively constant Al and Si contents, was studied via infrared (IR) spectroscopy, near-infrared (NIR) spectroscopy, and X-ray fluorescence (XRF) analysis. Five absorption features of the twenty samples near 4525, 4440, 4361, 4270, and 4182 cm−1 were observed, and two diagnostic features at 4440 and 4280 cm−1 we...

Innovative monolithic detector for tri-spectral (THz, IR, Vis) imaging

Science.gov (United States)

Pocas, S.; Perenzoni, M.; Massari, N.; Simoens, F.; Meilhan, J.; Rabaud, W.; Martin, S.; Delplanque, B.; Imperinetti, P.; Goudon, V.; Vialle, C.; Arnaud, A.

2012-10-01

Fusion of multispectral images has been explored for many years for security and used in a number of commercial products. CEA-Leti and FBK have developed an innovative sensor technology that gathers monolithically on a unique focal plane arrays, pixels sensitive to radiation in three spectral ranges that are terahertz (THz), infrared (IR) and visible. This technology benefits of many assets for volume market: compactness, full CMOS compatibility on 200mm wafers, advanced functions of the CMOS read-out integrated circuit (ROIC), and operation at room temperature. The ROIC houses visible APS diodes while IR and THz detections are carried out by microbolometers collectively processed above the CMOS substrate. Standard IR bolometric microbridges (160x160 pixels) are surrounding antenna-coupled bolometers (32X32 pixels) built on a resonant cavity customized to THz sensing. This paper presents the different technological challenges achieved in this development and first electrical and sensitivity experimental tests.

Enhanced spectral emissivity of CeO2 coating with cauliflower-like microstructure

International Nuclear Information System (INIS)

Huang Jianping; Li Yibin; He Xiaodong; Song Guangping; Fan Chenglei; Sun Yue; Fei Weidong; Du Shanyi

2012-01-01

Highlights: ► Cauliflower-like microstructured CeO 2 coating is prepared on Ni based substrate. ► The infrared emissive property at high temperature is investigated. ► Rough CeO 2 coating shows high emissivity, that is, 0.9 at 873 K and 0.87 at 1073 K. ► The emissivity enhancement mechanisms for the rough CeO 2 coating are discussed. - Abstract: Cerium dioxide is a transparent oxide with high refractive index (from 1.6 to 2.5 at 633 nm) in the visible and near-IR spectral regions. However, little attention has been paid to its optical property in mid-IR (2.5–25 μm). Here we report that the cauliflower-like microstructured CeO 2 coating deposited by electron beam physical vapor deposition technique shows high emissivity up to 0.9 at 873 K in the mid-IR spectral region. The high emissivity is attributed to the coupling between free propagating waves and space-variant polarizations caused by the cauliflower-like microstructure. This high emissivity coating shows a potential application in high temperature components.

Identification of mineral compositions in some renal calculi by FT Raman and IR spectral analysis

Science.gov (United States)

Tonannavar, J.; Deshpande, Gouri; Yenagi, Jayashree; Patil, Siddanagouda B.; Patil, Nikhil A.; Mulimani, B. G.

2016-02-01

We present in this paper accurate and reliable Raman and IR spectral identification of mineral constituents in nine samples of renal calculi (kidney stones) removed from patients suffering from nephrolithiasis. The identified mineral components include Calcium Oxalate Monohydrate (COM, whewellite), Calcium Oxalate Dihydrate (COD, weddellite), Magnesium Ammonium Phosphate Hexahydrate (MAPH, struvite), Calcium Hydrogen Phosphate Dihydrate (CHPD, brushite), Pentacalcium Hydroxy Triphosphate (PCHT, hydroxyapatite) and Uric Acid (UA). The identification is based on a satisfactory assignment of all the observed IR and Raman bands (3500-400 cm- 1) to chemical functional groups of mineral components in the samples, aided by spectral analysis of pure materials of COM, MAPH, CHPD and UA. It is found that the eight samples are composed of COM as the common component, the other mineral species as common components are: MAPH in five samples, PCHT in three samples, COD in three samples, UA in three samples and CHPD in two samples. One sample is wholly composed of UA as a single component; this inference is supported by the good agreement between ab initio density functional theoretical spectra and experimental spectral measurements of both sample and pure material. A combined application of Raman and IR techniques has shown that, where the IR is ambiguous, the Raman analysis can differentiate COD from COM and PCHT from MAPH.

Identification of mineral compositions in some renal calculi by FT Raman and IR spectral analysis.

Science.gov (United States)

Tonannavar, J; Deshpande, Gouri; Yenagi, Jayashree; Patil, Siddanagouda B; Patil, Nikhil A; Mulimani, B G

2016-02-05

We present in this paper accurate and reliable Raman and IR spectral identification of mineral constituents in nine samples of renal calculi (kidney stones) removed from patients suffering from nephrolithiasis. The identified mineral components include Calcium Oxalate Monohydrate (COM, whewellite), Calcium Oxalate Dihydrate (COD, weddellite), Magnesium Ammonium Phosphate Hexahydrate (MAPH, struvite), Calcium Hydrogen Phosphate Dihydrate (CHPD, brushite), Pentacalcium Hydroxy Triphosphate (PCHT, hydroxyapatite) and Uric Acid (UA). The identification is based on a satisfactory assignment of all the observed IR and Raman bands (3500-400c m(-1)) to chemical functional groups of mineral components in the samples, aided by spectral analysis of pure materials of COM, MAPH, CHPD and UA. It is found that the eight samples are composed of COM as the common component, the other mineral species as common components are: MAPH in five samples, PCHT in three samples, COD in three samples, UA in three samples and CHPD in two samples. One sample is wholly composed of UA as a single component; this inference is supported by the good agreement between ab initio density functional theoretical spectra and experimental spectral measurements of both sample and pure material. A combined application of Raman and IR techniques has shown that, where the IR is ambiguous, the Raman analysis can differentiate COD from COM and PCHT from MAPH. Copyright © 2015 Elsevier B.V. All rights reserved.

Quantitative gas analysis with FT-IR

DEFF Research Database (Denmark)

Bak, J.; Larsen, A.

1995-01-01

Calibration spectra of CO in the 2.38-5100 ppm concentration range (22 spectra) have been measured with a spectral resolution of 4 cm(-1), in the mid-IR (2186-2001 cm(-1)) region, with a Fourier transform infrared (FT-IR) instrument. The multivariate calibration method partial least-squares (PLS1...

Simulation and analysis of Au-MgF2 structure in plasmonic sensor in near infrared spectral region

Science.gov (United States)

Sharma, Anuj K.

2018-05-01

Plasmonic sensor based on metal-dielectric combination of gold and MgF2 layers is studied in near infrared (NIR) spectral region. An emphasis is given on the effect of variable thickness of MgF2 layer in combination with operating wavelength and gold layer thickness on the sensor's performance in NIR. It is established that the variation in MgF2 thickness in connection with plasmon penetration depth leads to significant variation in sensor's performance. The analysis leads to a conclusion that taking smaller values of MgF2 layer thickness and operating at longer NIR wavelength leads to enhanced sensing performance. Also, fluoride glass can provide better sensing performance than chalcogenide glass and silicon substrate.

Bulk mineralogy of the NE Syrtis and Jezero crater regions of Mars derived through thermal infrared spectral analyses

Science.gov (United States)

Salvatore, M. R.; Goudge, T. A.; Bramble, M. S.; Edwards, C. S.; Bandfield, J. L.; Amador, E. S.; Mustard, J. F.; Christensen, P. R.

2018-02-01

We investigated the area to the northwest of the Isidis impact basin (hereby referred to as "NW Isidis") using thermal infrared emission datasets to characterize and quantify bulk surface mineralogy throughout this region. This area is home to Jezero crater and the watershed associated with its two deltaic deposits in addition to NE Syrtis and the strong and diverse visible/near-infrared spectral signatures observed in well-exposed stratigraphic sections. The spectral signatures throughout this region show a diversity of primary and secondary surface mineralogies, including olivine, pyroxene, smectite clays, sulfates, and carbonates. While previous thermal infrared investigations have sought to characterize individual mineral groups within this region, none have systematically assessed bulk surface mineralogy and related these observations to visible/near-infrared studies. We utilize an iterative spectral unmixing method to statistically evaluate our linear thermal infrared spectral unmixing models to derive surface mineralogy. All relevant primary and secondary phases identified in visible/near-infrared studies are included in the unmixing models and their modeled spectral contributions are discussed in detail. While the stratigraphy and compositional diversity observed in visible/near-infrared spectra are much better exposed and more diverse than most other regions of Mars, our thermal infrared analyses suggest the dominance of basaltic compositions with less observed variability in the amount and diversity of alteration phases. These results help to constrain the mineralogical context of these previously reported visible/near-infrared spectral identifications. The results are also discussed in the context of future in situ investigations, as the NW Isidis region has long been promoted as a region of paleoenvironmental interest on Mars.

Wide-band IR imaging in the NIR-MIR-FIR regions for in situ analysis of frescoes

Science.gov (United States)

Daffara, C.; Pezzati, L.; Ambrosini, D.; Paoletti, D.; Di Biase, R.; Mariotti, P. I.; Frosinini, C.

2011-06-01

Imaging methods offer several advantages in the field of conservation allowing to perform non-invasive inspection of works of art. In particular, non-invasive techniques based on imaging in different infrared (IR) regions are widely used for the investigation of paintings. Using radiation beyond the visible range, different characteristics of the inspected artwork may be revealed according to the bandwidth acquired. In this paper we present the recent results of a joint project among the two research institutes DIMEG and CNR-INO, and the restoration facility Opificio delle Pietre Dure, concerning the wide-band integration of IR imaging techniques, in the spectral ranges NIR 0.8-2.5 μm, MIR 3-5 μm, and FIR 8-12 μm, for in situ analysis of artworks. A joint, multi-mode use of reflection and thermal bands is proposed for the diagnostics of mural paintings, and it is demonstrated to be an effective tool in inspecting the layered structure. High resolution IR reflectography and, to a greater extent, IR imaging in the 3-5 μm band, are effectively used to characterize the superficial layer of the fresco and to analyze the stratigraphy of different pictorial layers. IR thermography in the 8-12 μm band is used to characterize the support deep structure. The integration of all the data provides a multi- layered and multi-spectral representation of the fresco that yields a comprehensive analysis.

Comparative Evaluation of Spectral Transmittance of Some Welding Glasses with ANSI Z87.1

Directory of Open Access Journals (Sweden)

saeed Rahmani

2016-04-01

Full Text Available Background: Welding emits harmful rays to the eyes. We evaluate and compare the UV, blue light and IR transmittance characteristics of some currently available welding safety protectors with ANSI Z87.1 criteria.Materials and Methods: Three type of welding safety protectors (three of each type have been evaluated for spectral transmittance. One-sample T-test was performed to establish is there a statistically significant difference between the standard criteria and UV, blue and IR regions for the welding protectors (α=0.05.Results: In ultraviolet (UV (far and near region, two types of the tested protectors (P1, P2 transmitted lower than the maximum allowable value specified in the standard (P<0.001. In infrared (IR spectrum only one type (P3 transmitted lower than the maximum allowable value specified in the standard (P<0.001. In blue light region, all of the tested protectors transmitted lower than the maximum allowable value specified in the standard (P<0.001.Conclusion: Although all of the tested glasses could meet some parts of the criteria, but none of them could meet the complete spectral transmittance requirements of ANSI Z87.1.

A calibration method for the measurement of IR detector spectral responses using a FTIR spectrometer equipped with a DTGS reference cell

Science.gov (United States)

Gravrand, Olivier; Wlassow, J.; Bonnefond, L.

2014-07-01

Various high performance IR detectors are today available on the market from QWIPs to narrow gap semiconductor photodiodes, which exhibit various spectral features. In the astrophysics community, the knowledge of the detector spectral shape is of first importance. This quantity (spectral QE or response) is usually measured by means of a monochromator followed by an integrating sphere and compared to a calibrated reference detector. This approach is usually very efficient in the visible range, where all optical elements are very well known, particularly the reference detector. This setup is also widely used in the near IR (up to 3μm) but as the wavelength increases, it becomes less efficient. For instance, the internal emittance of integrating spheres in the IR, and the bad knowledge of reference detectors for longer wavelengths tend to degrade the measurement reliability. Another approach may therefore be considered, using a Fourier transform IR spectrometer (FTIR). In this case, as opposed to the monochromator, the tested detector is not in low flux condition, the incident light containing a mix of different wavelengths. Therefore, the reference detector has to be to be sensitive (and known) in the whole spectral band of interest, because it will sense all those wavelengths at the same time. A popular detector used in this case is a Deuterated Triglycine Sulfate thermal detector (DTGS). Being a pyro detetector, the spectral response of such a detector is very flat, mainly limited by its window. However, the response of such a detector is very slow, highly depending on the temporal frequency of the input signal. Moreover, being a differential detector, it doesn't work in DC. In commercial FTIR spectrometers, the source luminance is usually continuously modulated by the moving interferometer, and the result is that the interferogram mixes optical spectral information (optical path difference) and temporal variations (temporal frequency) so that the temporal

Multiplexing of spatial modes in the mid-IR region

Science.gov (United States)

Gailele, Lucas; Maweza, Loyiso; Dudley, Angela; Ndagano, Bienvenu; Rosales-Guzman, Carmelo; Forbes, Andrew

2017-02-01

Traditional optical communication systems optimize multiplexing in polarization and wavelength both trans- mitted in fiber and free-space to attain high bandwidth data communication. Yet despite these technologies, we are expected to reach a bandwidth ceiling in the near future. Communications using orbital angular momentum (OAM) carrying modes offers infinite dimensional states, providing means to increase link capacity by multiplexing spatially overlapping modes in both the azimuthal and radial degrees of freedom. OAM modes are multiplexed and de-multiplexed by the use of spatial light modulators (SLM). Implementation of complex amplitude modulation is employed on laser beams phase and amplitude to generate Laguerre-Gaussian (LG) modes. Modal decomposition is employed to detect these modes due to their orthogonality as they propagate in space. We demonstrate data transfer by sending images as a proof-of concept in a lab-based scheme. We demonstrate the creation and detection of OAM modes in the mid-IR region as a precursor to a mid-IR free-space communication link.

The impact of grid and spectral nudging on the variance of the near-surface wind speed

DEFF Research Database (Denmark)

Vincent, Claire Louise; Hahmann, Andrea N.

2015-01-01

Grid and spectral nudging are effective ways of preventing drift from large scale weather patterns in regional climate models. However, the effect of nudging on the wind-speed variance is unclear. In this study, the impact of grid and spectral nudging on near-surface and upper boundary layer wind...... nudging at and above 1150 m above ground level (AGL). Nested 5 km simulations are not nudged directly, but inherit boundary conditions from the 15 km experiments. Spatial and temporal spectra show that grid nudging causes smoothing of the wind in the 15 km domain at all wavenumbers, both at 1150 m AGL...... and near the surface where nudging is not applied directly, while spectral nudging mainly affects longer wavenumbers. Maps of mesoscale variance show spatial smoothing for both grid and spectral nudging, although the effect is less pronounced for spectral nudging. On the inner, 5 km domain, an indirect...

Enhanced spectral emissivity of CeO{sub 2} coating with cauliflower-like microstructure

Energy Technology Data Exchange (ETDEWEB)

Huang Jianping [Center for Composite Materials and Structures, Harbin Institute of Technology, 150080 Harbin (China); Li Yibin, E-mail: liyibin@hit.edu.cn [Center for Composite Materials and Structures, Harbin Institute of Technology, 150080 Harbin (China); He Xiaodong; Song Guangping [Center for Composite Materials and Structures, Harbin Institute of Technology, 150080 Harbin (China); Fan Chenglei [Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, 150001 Harbin (China); Sun Yue [Center for Composite Materials and Structures, Harbin Institute of Technology, 150080 Harbin (China); Fei Weidong [School of Materials Science and Engineering, Harbin Institute of Technology, 150001 Harbin (China); Du Shanyi [Center for Composite Materials and Structures, Harbin Institute of Technology, 150080 Harbin (China)

2012-10-15

Highlights: Black-Right-Pointing-Pointer Cauliflower-like microstructured CeO{sub 2} coating is prepared on Ni based substrate. Black-Right-Pointing-Pointer The infrared emissive property at high temperature is investigated. Black-Right-Pointing-Pointer Rough CeO{sub 2} coating shows high emissivity, that is, 0.9 at 873 K and 0.87 at 1073 K. Black-Right-Pointing-Pointer The emissivity enhancement mechanisms for the rough CeO{sub 2} coating are discussed. - Abstract: Cerium dioxide is a transparent oxide with high refractive index (from 1.6 to 2.5 at 633 nm) in the visible and near-IR spectral regions. However, little attention has been paid to its optical property in mid-IR (2.5-25 {mu}m). Here we report that the cauliflower-like microstructured CeO{sub 2} coating deposited by electron beam physical vapor deposition technique shows high emissivity up to 0.9 at 873 K in the mid-IR spectral region. The high emissivity is attributed to the coupling between free propagating waves and space-variant polarizations caused by the cauliflower-like microstructure. This high emissivity coating shows a potential application in high temperature components.

Optical design for a breadboard high-resolution spectrometer for SIRTF/IRS

Science.gov (United States)

Brown, Robert J.; Houck, James R.; van Cleve, Jeffrey E.

1996-11-01

The optical design of a breadboard high resolution infrared spectrometer for the IRS instrument on the SIRTF mission is discussed. The spectrometer uses a crossed echelle grating configuration to cover the spectral region from 10 to 20 micrometer with a resolving power of approximately equals 600. The all reflective spectrometer forms a nearly diffraction limited image of the two dimensional spectrum on a 128 multiplied by 128 arsenic doped silicon area array with 75 micrometer pixels. The design aspects discussed include, grating numerology, image quality, packaging and alignment philosophy.

The Formation of Massive Stars: from Herschel to Near-Infrared

Directory of Open Access Journals (Sweden)

Paolo Persi

2014-12-01

Full Text Available We have studied a number of selected high mass star forming regions, including high resolution near-infrared broad- and narrow-band imaging, Herschel (70, 160, 250, 350 and 500 μm and Spitzer (3.6, 4.5, 5.8 and 8.0 m images. The preliminary results of one of this region, IRAS 19388+2357(MOL110 are discussed. In this region a dense core has been detected in the far-infrared, and a young stellar cluster has been found around this core. Combining near-IR data with Spitzer and Herschel photometry we have derived the spectral energy distribution of Mol110. Finally comparing our H2 and Kc narrow-band images, we have found an H2 jet in this region.

Spectral properties of common intraocular lens (IOL) types

Science.gov (United States)

Milne, Peter J.; Chapon, Pascal F.; Hamaoui, Marie; Parel, Jean-Marie A.; Clayman, H.; Rol, Pascal O.

1999-06-01

Currently over 50 kinds of intraocular lenses (IOLs) are approved for patient use in the treatment of cataracts and ametropia. These lenses are manufactured from at least 2 kinds of silicones as well as several kinds of acrylic polymers including polyHEMA, Poly HOXEMA, a range of polymethacrylate and polyacrylate formulations. We sought to measure spectral transmission curves of a range of IOLS in the UV-visible and near IR spectral regions in order to better characterize their optical properties and to provide a baseline from which to assess their alteration following implantation over time. Consideration of how this may best be achieved are discussed. The variable ability of both explained IOLs and some samples from a range of manufacturers to block UV wavelengths is commented upon.

An unbiased spectral line survey toward R CrA IRS7B in the 345 GHz window with ASTE

DEFF Research Database (Denmark)

Watanabe, Yoshimasa; Sakai, Nami; Lindberg, Johan

2012-01-01

We have conducted a spectral line survey in the 332-364 GHz region with the Atacama Submillimeter Telescope Experiment 10 m telescope toward R CrA IRS7B, a low-mass protostar in the Class 0 or Class 0/I transitional stage. We have also performed some supplementary observations in the 450 GHz band...... corino. These results suggest a weak hot corino activity in R CrA IRS7B. On the other hand, the carbon-chain related molecules, CCH and c-C3H2, are found to be abundant. However, this source cannot be classified as a WCCC source, since long carbon-chain molecules are not detected. If WCCC and hot corino...... chemistry represent the two extremes in chemical compositions of low-mass Class 0 sources, R CrA IRS7B would be a source with a mixture of these two chemical characteristics. The UV radiation from the nearby Herbig Ae star R CrA may also affect the chemical composition. The present line survey demonstrates...

The first photometric analysis of the near contact binary IR Cas

International Nuclear Information System (INIS)

Li, Kai; Hu, S.-M.; Guo, D.-F.; Jiang, Y.-G.; Gao, D.-Y.; Chen, X.

2014-01-01

The first photometric analysis of IR Cas was carried out based on the new observed BVRI light curves. The symmetric light curves and nearly flat secondary minimum indicate that very precise photometric results can be determined. We found that IR Cas is a near contact binary with the primary component filling its Roche lobe. An analysis of the O – C diagram based on all available times of minimum light reveals evidence for a periodic change with a semi-amplitude of 0.0153 days and a period of 39.7 yr superimposed on a secular decrease at a rate of dp/dt = –1.28(± 0.09) × 10 –7 days yr –1 . The most reasonable explanation for the periodic change is the light time-travel effect due to a third body. The period decrease may be caused by mass transfer from the primary component to the secondary. With the decreasing period, IR Cas would eventually evolve into a contact system.

Meteorite Source Regions as Revealed by the Near-Earth Object Population

Science.gov (United States)

Binzel, Richard P.; DeMeo, Francesca E.; Burt, Brian J.; Polishook, David; Burbine, Thomas H.; Bus, Schelte J.; Tokunaga, Alan; Birlan, Mirel

2014-11-01

Spectroscopic and taxonomic information is now available for 1000 near-Earth objects, having been obtained through both targeted surveys (e.g. [1], [2], [3]) or resulting from all-sky surveys (e.g. [4]). We determine their taxonomic types in the Bus-DeMeo system [5] [6] and subsequently examine meteorite correlations based on spectral analysis (e.g. [7],[8]). We correlate our spectral findings with the source region probabilities calculated using the methods of Bottke et al. [9]. In terms of taxonomy, very clear sources are indicated: Q-, Sq-, and S-types most strongly associated with ordinary chondrite meteorites show clear source signatures through the inner main-belt. V-types are relatively equally balanced between nu6 and 3:1 resonance sources, consistent with the orbital dispersion of the Vesta family. B- and C-types show distinct source region preferences for the outer belt and for Jupiter family comets. A Jupiter family comet source predominates for the D-type near-Earth objects, implying these "asteroidal" bodies may be extinct or dormant comets [10]. Similarly, near-Earth objects falling in the spectrally featureless "X-type" category also show a strong outer belt and Jupiter family comet source region preference. Finally the Xe-class near-Earth objects, which most closely match the spectral properties of enstatite achondrite (aubrite) meteorites seen in the Hungaria region[11], show a source region preference consistent with a Hungaria origin by entering near-Earth space through the Mars crossing and nu6 resonance pathways. This work supported by the National Science Foundation Grant 0907766 and NASA Grant NNX10AG27G.[1] Lazzarin, M. et al. (2004), Mem. S. A. It. Suppl. 5, 21. [2] Thomas, C. A. et al. (2014), Icarus 228, 217. [3] Tokunaga, A. et al. (2006) BAAS 38, 59.07. [4] Hasselmann, P. H., Carvano, J. M., Lazzaro, D. (2011) NASA PDS, EAR-A-I0035-5-SDSSTAX-V1.0. [5] Bus, S.J., Binzel, R.P. (2002). Icarus 158, 146. [6] DeMeo, F.E. et al. (2009), Icarus

Composite multi-lobe descriptor for cross spectral face recognition: matching active IR to visible light images

Science.gov (United States)

Cao, Zhicheng; Schmid, Natalia A.

2015-05-01

Matching facial images across electromagnetic spectrum presents a challenging problem in the field of biometrics and identity management. An example of this problem includes cross spectral matching of active infrared (IR) face images or thermal IR face images against a dataset of visible light images. This paper describes a new operator named Composite Multi-Lobe Descriptor (CMLD) for facial feature extraction in cross spectral matching of near-infrared (NIR) or short-wave infrared (SWIR) against visible light images. The new operator is inspired by the design of ordinal measures. The operator combines Gaussian-based multi-lobe kernel functions, Local Binary Pattern (LBP), generalized LBP (GLBP) and Weber Local Descriptor (WLD) and modifies them into multi-lobe functions with smoothed neighborhoods. The new operator encodes both the magnitude and phase responses of Gabor filters. The combining of LBP and WLD utilizes both the orientation and intensity information of edges. Introduction of multi-lobe functions with smoothed neighborhoods further makes the proposed operator robust against noise and poor image quality. Output templates are transformed into histograms and then compared by means of a symmetric Kullback-Leibler metric resulting in a matching score. The performance of the multi-lobe descriptor is compared with that of other operators such as LBP, Histogram of Oriented Gradients (HOG), ordinal measures, and their combinations. The experimental results show that in many cases the proposed method, CMLD, outperforms the other operators and their combinations. In addition to different infrared spectra, various standoff distances from close-up (1.5 m) to intermediate (50 m) and long (106 m) are also investigated in this paper. Performance of CMLD is evaluated for of each of the three cases of distances.

A study of the region of massive star formation L379IRS1 in radio lines of methanol and other molecules

Science.gov (United States)

Kalenskii, S. V.; Shchurov, M. A.

2016-04-01

The results of spectral observations of the region of massive star formation L379IRS1 (IRAS18265-1517) are presented. The observations were carried out with the 30-m Pico Veleta radio telescope (Spain) at seven frequencies in the 1-mm, 2-mm, and 3-mm wavelength bands. Lines of 24 molecules were detected, from simple diatomic or triatomic species to complex eight- or nine-atom compounds such as CH3OCHO or CH3OCH3. Rotation diagrams constructed from methanol andmethyl cyanide lines were used to determine the temperature of the quiescent gas in this region, which is about 40-50 K. In addition to this warm gas, there is a hot component that is revealed through high-energy lines of methanol and methyl cyanide, molecular lines arising in hot regions, and the presence of H2O masers and Class II methanol masers at 6.7 GHz, which are also related to hot gas. One of the hot regions is probably a compact hot core, which is located near the southern submillimeter peak and is related to a group of methanol masers at 6.7 GHz. High-excitation lines at other positions may be associated with other hot cores or hot post-shock gas in the lobes of bipolar outflows. The rotation diagrams can be use to determine the column densities and abundances of methanol (10-9) and methyl cyanide (about 10-11) in the quiescent gas. The column densities of A- and E-methanol in L379IRS1 are essentually the same. The column densities of other observedmolecules were calculated assuming that the ratios of the molecular level abundances correspond to a temperature of 40 K. The molecular composition of the quiescent gas is close to that in another region of massive star formation, DR21(OH). The only appreciable difference is that the column density of SO2 in L379IRS1 is at least a factor of 20 lower than the value in DR21(OH). The SO2/CS and SO2/OCS abundance ratios, which can be used as chemical clocks, are lower in L379IRS1 than in DR21(OH), suggesting that L379IRS1 is probably younger than DR21(OH).

A Resolved and Asymmetric Ring of PAHs within the Young Circumstellar Disk of IRS 48

Energy Technology Data Exchange (ETDEWEB)

Schworer, Guillaume; Lacour, Sylvestre; Du Foresto, Vincent Coudé [LESIA, Observatoire de Paris, PSL Research University, CNRS, Sorbonne Universits, UPMC Univ. Paris 06, Univ. Paris Diderot, Sorbonne Paris Cité (France); Huélamo, Nuria [Dpto. Astrofísica, Centro de Astrobiología (INTA-CSIC), ESAC Campus, P.O. Box 78, E-28691, Villanueva de la Cañada (Spain); Pinte, Christophe; Chauvin, Gaël [Univ. Grenoble Alpes, IPAG, F-38000 Grenoble, France CNRS, IPAG, F-38000 Grenoble (France); Ehrenreich, David [Observatoire de l’Université de Genève, 51 chemin des Maillettes, 1290 Versoix (Switzerland); Girard, Julien [European Southern Observatory, Alonso de Cordova 3107, Casilla 19001 Vitacura, Santiago 19 (Chile); Tuthill, Peter [Sydney Institute for Astronomy, School of Physics, The University of Sydney, NSW 2006 (Australia)

2017-06-20

For one decade, the spectral type and age of the ρ Oph object IRS-48 were subject to debate and mystery. Modeling its disk with mid-infrared to millimeter observations led to various explanations to account for the complex intricacy of dust holes and gas-depleted regions. We present multi-epoch high-angular-resolution interferometric near-infrared data of spatially resolved emissions in the first 15 au of IRS-48, known to have very strong polycyclic aromatic hydrocarbon (PAH) emissions within this dust-depleted region. We make use of new Sparse-Aperture-Masking data to instruct a revised radiative-transfer model, where spectral energy distribution fluxes and interferometry are jointly fitted. Neutral and ionized PAH, very small grains (VSG), and classical silicates are incorporated into the model; new stellar parameters and extinction laws are explored. A bright (42 L {sub ⊙}) and hence large (2.5 R {sub ⊙}) central star with A {sub v} = 12.5 mag and R {sub v} = 6.5 requires less near-infrared excess: the inner-most disk at ≈1 au is incompatible with the interferometric data. The revised stellar parameters place this system on a 4 Myr evolutionary track, four times younger than the previous estimations, which is in better agreement with the surrounding ρ Oph region and disk-lifetime observations. The disk-structure solution converges to a classical-grain outer disk from 55 au combined with an unsettled and fully resolved VSG and PAH ring, between 11 and 26 au. We find two overluminosities in the PAH ring at color-temperatures consistent with the radiative transfer simulations; one follows a Keplerian circular orbit at 14 au. We show a depletion of a factor of ≈5 of classical dust grains up to 0.3 mm compared to very small particles: the IRS-48 disk is nearly void of dust grains in the first 55 au. A 3.5 M {sub Jup} planet on a 40 au orbit can qualitatively explain the new disk structure.

Visible to near-IR fluorescence from single-digit detonation nanodiamonds: excitation wavelength and pH dependence.

Science.gov (United States)

Reineck, Philipp; Lau, Desmond W M; Wilson, Emma R; Nunn, Nicholas; Shenderova, Olga A; Gibson, Brant C

2018-02-06

Detonation nanodiamonds are of vital significance to many areas of science and technology. However, their fluorescence properties have rarely been explored for applications and remain poorly understood. We demonstrate significant fluorescence from the visible to near-infrared spectral regions from deaggregated, single-digit detonation nanodiamonds dispersed in water produced via post-synthesis oxidation. The excitation wavelength dependence of this fluorescence is analyzed in the spectral region from 400 nm to 700 nm as well as the particles' absorption characteristics. We report a strong pH dependence of the fluorescence and compare our results to the pH dependent fluorescence of aromatic hydrocarbons. Our results significantly contribute to the current understanding of the fluorescence of carbon-based nanomaterials in general and detonation nanodiamonds in particular.

The influence of spectral nudging on typhoon formation in regional climate models

Science.gov (United States)

Feser, Frauke; Barcikowska, Monika

2012-03-01

Regional climate models can successfully simulate tropical cyclones and typhoons. This has been shown and was evaluated for hindcast studies of the past few decades. But often global and regional weather phenomena are not simulated at the observed location, or occur too often or seldom even though the regional model is driven by global reanalysis data which constitute a near-realistic state of the global atmosphere. Therefore, several techniques have been developed in order to make the regional model follow the global state more closely. One is spectral nudging, which is applied for horizontal wind components with increasing strength for higher model levels in this study. The aim of this study is to show the influence that this method has on the formation of tropical cyclones (TC) in regional climate models. Two ensemble simulations (each with five simulations) were computed for Southeast Asia and the Northwestern Pacific for the typhoon season 2004, one with spectral nudging and one without. First of all, spectral nudging reduced the overall TC number by about a factor of 2. But the number of tracks which are similar to observed best track data (BTD) was greatly increased. Also, spatial track density patterns were found to be more similar when using spectral nudging. The tracks merge after a short time for the spectral nudging simulations and then follow the BTD closely; for the no nudge cases the similarity is greatly reduced. A comparison of seasonal precipitation, geopotential height, and temperature fields at several height levels with observations and reanalysis data showed overall a smaller ensemble spread, higher pattern correlations and reduced root mean square errors and biases for the spectral nudged simulations. Vertical temperature profiles for selected TCs indicate that spectral nudging is not inhibiting TC development at higher levels. Both the Madden-Julian Oscillation and monsoonal precipitation are reproduced realistically by the regional model

The influence of spectral nudging on typhoon formation in regional climate models

International Nuclear Information System (INIS)

Feser, Frauke; Barcikowska, Monika

2012-01-01

Regional climate models can successfully simulate tropical cyclones and typhoons. This has been shown and was evaluated for hindcast studies of the past few decades. But often global and regional weather phenomena are not simulated at the observed location, or occur too often or seldom even though the regional model is driven by global reanalysis data which constitute a near-realistic state of the global atmosphere. Therefore, several techniques have been developed in order to make the regional model follow the global state more closely. One is spectral nudging, which is applied for horizontal wind components with increasing strength for higher model levels in this study. The aim of this study is to show the influence that this method has on the formation of tropical cyclones (TC) in regional climate models. Two ensemble simulations (each with five simulations) were computed for Southeast Asia and the Northwestern Pacific for the typhoon season 2004, one with spectral nudging and one without. First of all, spectral nudging reduced the overall TC number by about a factor of 2. But the number of tracks which are similar to observed best track data (BTD) was greatly increased. Also, spatial track density patterns were found to be more similar when using spectral nudging. The tracks merge after a short time for the spectral nudging simulations and then follow the BTD closely; for the no nudge cases the similarity is greatly reduced. A comparison of seasonal precipitation, geopotential height, and temperature fields at several height levels with observations and reanalysis data showed overall a smaller ensemble spread, higher pattern correlations and reduced root mean square errors and biases for the spectral nudged simulations. Vertical temperature profiles for selected TCs indicate that spectral nudging is not inhibiting TC development at higher levels. Both the Madden–Julian Oscillation and monsoonal precipitation are reproduced realistically by the regional model

Near infrared photometry of violent star formation regions

International Nuclear Information System (INIS)

Melnick, J.; Terlevich, R.; Moles, M.

1985-01-01

Near infrared broad band photometry and CO indices for a significant number of Violent Star Formation Regions are presented. The existence of a narrow correlation between W (Hβ) and IR colour is confirmed. The interpretation of this relation as an age sequence implies a correlation between CO index and W(Hβ) which is not found. It is argued however that this failure is most likely a consequence of using narrow band filters to determine CO indices in objects with strong emission-line spectra. (author)

A NEAR-INFRARED SPECTROSCOPIC STUDY OF YOUNG FIELD ULTRACOOL DWARFS

Energy Technology Data Exchange (ETDEWEB)

Allers, K. N. [Department of Physics and Astronomy, Bucknell University, Lewisburg, PA 17837 (United States); Liu, Michael C., E-mail: k.allers@bucknell.edu [Institute for Astronomy, University of Hawaii, 2680 Woodlawn Drive, Honolulu, HI 96822 (United States)

2013-08-01

We present a near-infrared (0.9-2.4 {mu}m) spectroscopic study of 73 field ultracool dwarfs having spectroscopic and/or kinematic evidence of youth ( Almost-Equal-To 10-300 Myr). Our sample is composed of 48 low-resolution (R Almost-Equal-To 100) spectra and 41 moderate-resolution spectra (R {approx}> 750-2000). First, we establish a method for spectral typing M5-L7 dwarfs at near-IR wavelengths that is independent of gravity. We find that both visual and index-based classification in the near-IR provides consistent spectral types with optical spectral types, though with a small systematic offset in the case of visual classification at J and K band. Second, we examine features in the spectra of {approx}10 Myr ultracool dwarfs to define a set of gravity-sensitive indices based on FeH, VO, K I, Na I, and H-band continuum shape. We then create an index-based method for classifying the gravities of M6-L5 dwarfs that provides consistent results with gravity classifications from optical spectroscopy. Our index-based classification can distinguish between young and dusty objects. Guided by the resulting classifications, we propose a set of low-gravity spectral standards for the near-IR. Finally, we estimate the ages corresponding to our gravity classifications.

Influence of temperature on water and aqueous glucose absorption spectra in the near- and mid-infrared regions at physiologically relevant temperatures

DEFF Research Database (Denmark)

Jensen, P.S.; Bak, J.; Andersson-Engels, S.

2003-01-01

transmission cell controlled within 0.02 degreesC. Pathlengths of 50 mum and 0.4 mm were used in the mid- and near-infrared spectral region, respectively. Difference spectra were used to determine the effect of temperature on the water spectra quantitatively. These spectra were obtained by subtracting the 37...... degreesC water spectrum from the spectra measured at other temperatures. The difference spectra reveal that the effect of temperature is highest in the vicinity of the strong absorption bands, with a number of isosbestic points with no temperature dependence and relatively flat plateaus in between......Near- and mid-infrared absorption spectra of pure water and aqueous 1.0 g/dL glucose solutions in the wavenumber range 8000-950 cm(-1) were measured in the temperature range 30-42 C in steps of 2 degreesC. Measurements were carried out with an FT-IR spectrometer and a variable pathlength...

Spectrally resolved confocal microscopy using lanthanide centred near-IR emission

DEFF Research Database (Denmark)

Liao, Zhiyu; Tropiano, Manuel; Mantulnikovs, Konstantins

2015-01-01

The narrow, near infrared (NIR) emission from lanthanide ions has attracted great interest, particularly with regard to developing tools for bioimaging, where the long lifetimes of lanthanide excited states can be exploited to address problems arising from autofluorescence and sample transparency...

[Study of near infrared spectral preprocessing and wavelength selection methods for endometrial cancer tissue].

Science.gov (United States)

Zhao, Li-Ting; Xiang, Yu-Hong; Dai, Yin-Mei; Zhang, Zhuo-Yong

2010-04-01

Near infrared spectroscopy was applied to measure the tissue slice of endometrial tissues for collecting the spectra. A total of 154 spectra were obtained from 154 samples. The number of normal, hyperplasia, and malignant samples was 36, 60, and 58, respectively. Original near infrared spectra are composed of many variables, for example, interference information including instrument errors and physical effects such as particle size and light scatter. In order to reduce these influences, original spectra data should be performed with different spectral preprocessing methods to compress variables and extract useful information. So the methods of spectral preprocessing and wavelength selection have played an important role in near infrared spectroscopy technique. In the present paper the raw spectra were processed using various preprocessing methods including first derivative, multiplication scatter correction, Savitzky-Golay first derivative algorithm, standard normal variate, smoothing, and moving-window median. Standard deviation was used to select the optimal spectral region of 4 000-6 000 cm(-1). Then principal component analysis was used for classification. Principal component analysis results showed that three types of samples could be discriminated completely and the accuracy almost achieved 100%. This study demonstrated that near infrared spectroscopy technology and chemometrics method could be a fast, efficient, and novel means to diagnose cancer. The proposed methods would be a promising and significant diagnosis technique of early stage cancer.

Hyper-Spectral Imager in visible and near-infrared band for lunar ...

Indian Academy of Sciences (India)

India's first lunar mission, Chandrayaan-1, will have a Hyper-Spectral Imager in the visible and near-infrared spectral ... mapping of the Moon's crust in a large number of spectral channels. The planned .... In-flight verification may be done.

Photo-redox activated drug delivery systems operating under two photon excitation in the near-IR.

Science.gov (United States)

Guardado-Alvarez, Tania M; Devi, Lekshmi Sudha; Vabre, Jean-Marie; Pecorelli, Travis A; Schwartz, Benjamin J; Durand, Jean-Olivier; Mongin, Olivier; Blanchard-Desce, Mireille; Zink, Jeffrey I

2014-05-07

We report the design and synthesis of a nano-container consisting of mesoporous silica nanoparticles with the pore openings covered by "snap-top" caps that are opened by near-IR light. A photo transducer molecule that is a reducing agent in an excited electronic state is covalently attached to the system. Near IR two-photon excitation causes inter-molecular electron transfer that reduces a disulfide bond holding the cap in place, thus allowing the cargo molecules to escape. We describe the operation of the "snap-top" release mechanism by both one- and two-photon activation. This system presents a proof of concept of a near-IR photoredox-induced nanoparticle delivery system that may lead to a new type of photodynamic drug release therapy.

Rydberg excitation of neutral nitric oxide molecules in strong UV and near-IR laser fields

International Nuclear Information System (INIS)

Lv Hang; Zhang Jun-Feng; Zuo Wan-Long; Xu Hai-Feng; Jin Ming-Xing; Ding Da-Jun

2015-01-01

Rydberg state excitations of neutral nitric oxide molecules are studied in strong ultraviolet (UV) and near-infra-red (IR) laser fields using a linear time-of-flight (TOF) mass spectrometer with the pulsed electronic field ionization method. The yield of Rydberg molecules is measured as a function of laser intensity and ellipticity, and the results in UV laser fields are compared with those in near-IR laser fields. The present study provides the first experimental evidence of neutral Rydberg molecules surviving in a strong laser field. The results indicate that a rescattering-after-tunneling process is the main contribution to the formation of Rydberg molecules in strong near-IR laser fields, while multi-photon excitation may play an important role in the strong UV laser fields. (paper)

Third-harmonic generation in silicon and photonic crystals of macroporous silicon in the spectral intermediate-IR range; Erzeugung der Dritten Harmonischen in Silizium und Photonischen Kristallen aus makroporoesem Silizium im spektralen mittleren IR-Bereich

Energy Technology Data Exchange (ETDEWEB)

Mitzschke, Kerstin

2007-11-01

Nonlinear optical spectroscopy is a powerful method to study surface or bulk properties of condensed matter. In centrosymmetric materials like silicon even order nonlinear optical processes are forbidden. Besides self-focussing or self phase modulation third-harmonic-generation (THG) is the simplest process that can be studied. This work demonstrates that THG is a adapted non-contact and non-invasive optical method to get information about bulk structures of silicon and Photonic crystals (PC), consisting of silicon. Until now most studies are done in the visible spectral range being limited by the linear absorption losses. So the extension of THG to the IR spectral range is extremely useful. This will allow the investigation of Photonic Crystals, where frequencies near a photonic bandgap are of special interest. 2D- photonic structures under investigation were fabricated via photoelectrochemical etching of the Si (100) wafer (thickness 500 {mu}m) receiving square and hexagonal arranged pores. The typical periodicity of the structures used is 2 {mu}m and the length of the pores reached to 400 {mu}m. Because of stability the photonic structures were superimposed on silicon substrate. The experimental set-up used for the THG experiments generates tuneable picosecond IR pulses (tuning range 1500-4000 cm{sup -1}). The IR-pulse hit the sample either perpendicular to the sample surface or under an angle {theta}. The sample can be rotated (f) around the surface normal. The generated third harmonic is analysed by a polarizer, spectrally filtered by a polychromator and registered by a CCD camera. The setup can be used either in transmission or in reflection mode. Optical transmission and reflection spectra of the Si bulk correspond well with the theoretical description, a 4-fold and a 8-fold dependencies of the azimuth angle resulting in the structure of the x{sup (3)}-tensor of (100)-Si. The situation changes dramatically if the PC with hexagonal structure is investigated

Low loss mid-IR transmission bands using silica hollow-core anisotropic anti-resonant fibers

DEFF Research Database (Denmark)

Habib, Selim; Bang, Ole; Bache, Morten

2016-01-01

In this paper, a node-free anisotropic hollow-core anti-resonant fiber has been proposed to give low transmission loss in the near-IR to mid-IR spectral regime. The proposed silica-based fiber design shows transmission loss below 10 dB/km at 2.94 μm with multiple low loss transmission bands. Tran...

Radioluminescence dating: the IR emission of feldspar

International Nuclear Information System (INIS)

Schilles, Thomas.; Habermann, Jan

2000-01-01

A new luminescence reader for radioluminescence (RL) measurements is presented. The system allows detection of RL emissions in the near infrared region (IR). Basic bleaching properties of the IR-RL emission of feldspars are investigated. Sunlight-bleaching experiments as a test for sensitivity changes are presented. IR-bleaching experiments were carried out to obtain information about the underlying physical processes of the IR-RL emission

Visible and Near-IR Reflectance Spectra for Smectite, Sulfate And Perchlorate under Dry Conditions for Interpretation of Martian Surface Mineralogy

Science.gov (United States)

Morris, R.V.; Ming, W.; Golden, D.C.; Arvidson, R.E.; Wiseman, S.M.; Lichtenberg, K.A.; Cull, S.; Graff, T.G.

2009-01-01

Visible and near-IR (VNIR) spectral data for the martian surface obtained from orbit by the MRO-CRISM and OMEGA instruments are interpreted as having spectral signatures of H2O/OH-bearing phases, including smectites and other phyllosilicates, sulfates, and high-SiO2 phases [e.g., 1-4]. Interpretations of martian spectral signatures are based on and constrained by spectra that are obtained in the laboratory on samples with known mineralogical compositions and other physicochemical characteristics under, as appropriate, Mars-like environmental conditions (e.g., temperature, pressure, and humidity). With respect to environmental conditions, differences in the absolute concentration of atmospheric H2O can effect the hydration state and therefore the spectra signatures of smectite phyllosilicates (solvation H2O) and certain sulfates (hydration H2O) [e.g., 5-7]. We report VNIR spectral data acquired under humid (laboratory air) and dry (dry N2 gas) environments for two natural smectites (nontronite API-33A and saponite SapCa-1) to characterize the effect of solvation H2O on spectral properties. We also report spectral data for the thermal dehydration products of (1) melanterite (FeSO4.7H2O) in both air and dry N2 gas and (2) Mg-perchlorate (Mg(ClO4)2.6H2O) in dry N2 environments. Spectral measurements for samples dehydrated in dry N2 were made without exposing them to humid laboratory air.

Nonlinear upconversion based infrared spectroscopy on ZSM-5 zeolite

DEFF Research Database (Denmark)

Kehlet, Louis Martinus; Beato, Pablo; Tidemand-Lichtenberg, Peter

2017-01-01

We present a spectroscopic measurement of zeolite ZSM-5 in the mid-IR following the methanol attachment to active sites at 200 °C. The spectra are measured using nonlinear frequency upconversion to the near-IR spectral region.......We present a spectroscopic measurement of zeolite ZSM-5 in the mid-IR following the methanol attachment to active sites at 200 °C. The spectra are measured using nonlinear frequency upconversion to the near-IR spectral region....

Spectral Confirmation of New Galactic LBV and WN Stars Associated With Mid-IR Nebulae

Science.gov (United States)

Stringfellow, Guy; Gvaramadze, Vasilii V.

2014-08-01

Luminous Blue Variable (LBV) stars represent an extremely rare class and short-lived phase in the lives of very luminous massive stars with high mass loss rates. Extragalactic LBVs are responsible for producing false supernovae (SN), the SN Impostors, and have been directly linked with the progenitors of actual SN, indicating the LBV phase can be a final endpoint for massive star evolution. Yet only a few confirmed LBVs have been identified in the Galaxy. Their stellar evolution is poorly constrained by observations, and the physical reason for their unstable nature, both in terms of moderate spectral and photometric variability of a few magnitudes and the giant eruptions a la η Car that rival SN explosions, remains a mystery. Newly discovered mid-IR shells act as signposts, pointing to the central massive stars (LBV and Wolf-Rayet [WR] stars) that produced them. We have undertaken a spectroscopic survey of possible progenitor stars within these shells and are discovering that many are LBVs and WN-type WR transitional stars. We propose to extend this IR spectral survey to the south to search for new progenitor stars associated with dozens of newly identified shells. This survey should result in a substantial increase of new WRs and candidate LBVs for continued future study. Spectral analysis will yield new insights into the winds and physical properties of these rare and important objects, and lead to a better understanding of the physics driving giant eruptions.

AXION DECAY AND ANISOTROPY OF NEAR-IR EXTRAGALACTIC BACKGROUND LIGHT

Energy Technology Data Exchange (ETDEWEB)

Gong, Yan; Chen, Xuelei [National Astronomical Observatories, Chinese Academy of Sciences, Beijing, 100012 (China); Cooray, Asantha; Mitchell-Wynne, Ketron [Department of Physics and Astronomy, University of California, Irvine, CA 92697 (United States); Zemcov, Michael [Center for Detectors, School of Physics and Astronomy, Rochester Institute of Technology, Rochester, NY 14623 (United States); Smidt, Joseph [Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

2016-07-10

The extragalactic background light (EBL) is composed of the cumulative radiation from all galaxies and active galactic nuclei over cosmic history. In addition to point sources, the EBL also contains information from diffuse sources of radiation. The angular power spectra of the near-infrared intensities could contain additional signals, and a complete understanding of the nature of the infrared (IR) background is still lacking in the literature. Here we explore the constraints that can be placed on particle decays, especially candidate dark matter (DM) models involving axions that trace DM halos of galaxies. Axions with a mass around a few electronvolts will decay via two photons with wavelengths in the near-IR band and will leave a signature in the IR background intensity power spectrum. Using recent power spectra measurements from the Hubble Space Telescope and the Cosmic Infrared Background Experiment, we find that the 0.6–1.6 μ m power spectra can be explained by axions with masses around 4 eV. The total axion abundance Ω{sub a} ≃ 0.05, and it is comparable to the baryon density of the universe. The suggested mean axion mass and abundance are not ruled out by existing cosmological observations. Interestingly, the axion model with a mass distribution is preferred by the data, which cannot be explained by the standard quantum chromodynamics theory and needs further discussion.

Similarity maps and hierarchical clustering for annotating FT-IR spectral images.

Science.gov (United States)

Zhong, Qiaoyong; Yang, Chen; Großerüschkamp, Frederik; Kallenbach-Thieltges, Angela; Serocka, Peter; Gerwert, Klaus; Mosig, Axel

2013-11-20

Unsupervised segmentation of multi-spectral images plays an important role in annotating infrared microscopic images and is an essential step in label-free spectral histopathology. In this context, diverse clustering approaches have been utilized and evaluated in order to achieve segmentations of Fourier Transform Infrared (FT-IR) microscopic images that agree with histopathological characterization. We introduce so-called interactive similarity maps as an alternative annotation strategy for annotating infrared microscopic images. We demonstrate that segmentations obtained from interactive similarity maps lead to similarly accurate segmentations as segmentations obtained from conventionally used hierarchical clustering approaches. In order to perform this comparison on quantitative grounds, we provide a scheme that allows to identify non-horizontal cuts in dendrograms. This yields a validation scheme for hierarchical clustering approaches commonly used in infrared microscopy. We demonstrate that interactive similarity maps may identify more accurate segmentations than hierarchical clustering based approaches, and thus are a viable and due to their interactive nature attractive alternative to hierarchical clustering. Our validation scheme furthermore shows that performance of hierarchical two-means is comparable to the traditionally used Ward's clustering. As the former is much more efficient in time and memory, our results suggest another less resource demanding alternative for annotating large spectral images.

Detection and classification of salmonella serotypes using spectral signatures collected by fourier transform infrared (FT-IR) spectroscopy

Science.gov (United States)

Spectral signatures of Salmonella serotypes namely Salmonella Typhimurium, Salmonella Enteritidis, Salmonella Infantis, Salmonella Heidelberg and Salmonella Kentucky were collected using Fourier transform infrared spectroscopy (FT-IR). About 5-10 µL of Salmonella suspensions with concentrations of 1...

FT-IR Microspectroscopy of Rat Ear Cartilage.

Directory of Open Access Journals (Sweden)

Benedicto de Campos Vidal

Full Text Available Rat ear cartilage was studied using Fourier transform-infrared (FT-IR microspectroscopy to expand the current knowledge which has been established for relatively more complex cartilage types. Comparison of the FT-IR spectra of the ear cartilage extracellular matrix (ECM with published data on articular cartilage, collagen II and 4-chondroitin-sulfate standards, as well as of collagen type I-containing dermal collagen bundles (CBs with collagen type II, was performed. Ear cartilage ECM glycosaminoglycans (GAGs were revealed histochemically and as a reduction in ECM FT-IR spectral band heights (1140-820 cm-1 after testicular hyaluronidase digestion. Although ear cartilage is less complex than articular cartilage, it contains ECM components with a macromolecular orientation as revealed using polarization microscopy. Collagen type II and GAGs, which play a structural role in the stereo-arrangement of the ear cartilage, contribute to its FT-IR spectrum. Similar to articular cartilage, ear cartilage showed that proteoglycans add a contribution to the collagen amide I spectral region, a finding that does not recommend this region for collagen type II quantification purposes. In contrast to articular cartilage, the symmetric stretching vibration of -SO3- groups at 1064 cm-1 appeared under-represented in the FT-IR spectral profile of ear cartilage. Because the band corresponding to the asymmetric stretching vibration of -SO3- groups (1236-1225 cm-1 overlapped with that of amide III bands, it is not recommended for evaluation of the -SO3- contribution to the FT-IR spectrum of the ear cartilage ECM. Instead, a peak (or shoulder at 1027-1016 cm-1 could be better considered for this intent. Amide I/amide II ratios as calculated here and data from the literature suggest that protein complexes of the ear cartilage ECM are arranged with a lower helical conformation compared to pure collagen II. The present results could motivate further studies on this tissue

Spectral reflectance relationships to leaf water stress

Science.gov (United States)

Ripple, William J.

1986-01-01

Spectral reflectance data were collected from detached snapbean leaves in the laboratory with a multiband radiometer. Four experiments were designed to study the spectral response resulting from changes in leaf cover, relative water content of leaves, and leaf water potential. Spectral regions included in the analysis were red (630-690 nm), NIR (760-900 nm), and mid-IR (2.08-2.35 microns). The red and mid-IR bands showed sensitivity to changes in both leaf cover and relative water content of leaves. The NIR was only highly sensitive to changes in leaf cover. Results provided evidence that mid-IR reflectance was governed primarily by leaf moisture content, although soil reflectance was an important factor when leaf cover was less than 100 percent. High correlations between leaf water potentials and reflectance were attributed to covariances with relative water content of leaves and leaf cover.

Moving the Plasmon of LaB₆ from IR to Near-IR via Eu-Doping.

Science.gov (United States)

Mattox, Tracy M; Coffman, D Keith; Roh, Inwhan; Sims, Christopher; Urban, Jeffrey J

2018-02-01

Lanthanum hexaboride (LaB₆) has become a material of intense interest in recent years due to its low work function, thermal stability and intriguing optical properties. LaB₆ is also a semiconductor plasmonic material with the ability to support strong plasmon modes. Some of these modes uniquely stretch into the infrared, allowing the material to absorb around 1000 nm, which is of great interest to the window industry. It is well known that the plasmon of LaB₆ can be tuned by controlling particle size and shape. In this work, we explore the options available to further tune the optical properties by describing how metal vacancies and Eu doping concentrations are additional knobs for tuning the absorbance from the near-IR to far-IR in La 1-x Eu x B₆ (x = 0, 0.2, 0.5, 0.8, and 1.0). We also report that there is a direct correlation between Eu concentration and metal vacancies within the Eu 1-x La x B₆.

Photochemistry of Fe:H2O Adducts in Argon Matrixes: A Combined Experimental and Theoretical Study in the Mid-IR and UV-Visible Regions.

Science.gov (United States)

Deguin, Vincent; Mascetti, Joëlle; Simon, Aude; Ben Amor, Nadia; Aupetit, Christian; Latournerie, Sandra; Noble, Jennifer A

2018-01-18

The photochemistry of Fe:H 2 O adducts is of interest in fields as diverse as catalysis and astrochemistry. Industrially, iron can be used as a catalyst to convert H 2 O to H 2 , whereas in the interstellar medium it may be an important component of dust grains, influencing the chemistry on their icy surfaces. This study consisted of the deposition and spectral characterization of binary systems of atomic iron with H 2 O in cryogenic argon matrixes. In this way, we were able to obtain information about the interaction of the two species; we observed the formation of adducts of iron monomers and dimers with water molecules in the mid-IR and UV-visible spectral domains. Upon irradiation with a UV radiation source, the iron species were inserted into the water molecules to form HFeOH and HFe 2 OH, leading in some cases to the formation of FeO possibly accompanied by the production of H 2 . DFT and correlated multireference wave function calculations confirmed our attributions. This combination of IR and UV-visible spectroscopy with theoretical calculations allowed us to determine, for the first time, the spectral characteristics of iron adducts and their photoproducts in the UV-visible and in the OH stretching region of the mid-IR domain.

Tidal Distortion of the Envelope of an AGB Star IRS 3 near Sgr A{sup *}

Energy Technology Data Exchange (ETDEWEB)

Yusef-Zadeh, F.; Royster, M. J.; Roberts, D. A. [Department of Physics and Astronomy, Northwestern University, Evanston, IL 60208 (United States); Wardle, M. [Department of Physics and Astronomy and Research Center for Astronomy, Astrophysics and Astrophotonics, Macquarie University, Sydney NSW 2109 (Australia); Cotton, W.; Kunneriath, D. [National Radio Astronomy Observatory, Charlottesville, VA 22903 (United States); Schödel, R. [Instituto de Astfisica de Andalucia (CSIC), Glorieta de la Astronomia S/N, E-18008 Granada (Spain)

2017-03-01

We present radio and millimeter continuum observations of the Galactic center taken with the Very Large Array (VLA) and ALMA at 44 and 226 GHz, respectively. We detect radio and millimeter emission from IRS 3, lying ∼4.″5 NW of Sgr A*, with a spectrum that is consistent with the photospheric emission from an AGB star at the Galactic center. Millimeter images reveal that the envelope of IRS 3, the brightest and most extended 3.8 μ m Galactic center stellar source, consists of two semicircular dust shells facing the direction of Sgr A*. The outer circumstellar shell, at a distance of 1.6 × 10{sup 4} au, appears to break up into “fingers” of dust directed toward Sgr A*. These features coincide with molecular CS (5–4) emission and a near-IR extinction cloud distributed between IRS 3 and Sgr A*. The NE–SW asymmetric shapes of the IRS 3 shells seen at 3.8 μ m and radio are interpreted as structures that are tidally distorted by Sgr A*. Using the kinematics of CS emission and the proper motion of IRS 3, the tidally distorted outflowing material from the envelope after 5000 yr constrains the distance of IRS 3 to ∼0.7 pc in front of or ∼0.5 pc behind Sgr A*. This suggests that the mass loss by stars near Sgr A* can supply a reservoir of molecular material near Sgr A*. We also present dark features in radio continuum images coincident with the envelope of IRS 3. These dusty stars provide examples in which high-resolution radio continuum images can identify dust-enshrouded stellar sources embedded in an ionized medium.

Interpretation of the Near-IR Spectra of the Kuiper Belt Object

Science.gov (United States)

Eluszkiewicz, Janusz; Cady-Pereira, Karen; Brown, Michael E.; Stansberry, John A.

2007-01-01

Visible and near-IR observations of the Kuiper Belt Object (136472) 2005 FY(9) have indicated the presence of unusually long (1 cm or more) optical path lengths in a layer of methane ice. Using microphysical and radiative transfer modeling, we show that even at the frigid temperatures in the outer reaches of the solar system, a slab of low porosity methane ice can indeed form by pressureless sintering of micron-sized grains, and it can qualitatively reproduce the salient features of the measured spectra. A good semiquantitative match with the near-IR spectra can be obtained with a realistic slab model, provided the spectra are scaled to a visible albedo of 0.6, at the low end of the values currently estimated from Spitzer thermal measurements. Consistent with previous modeling studies, matching spectra scaled to higher albedos requires the incorporation of strong backscattering effects. The albedo may become better constrained through an iterative application of the slab model to the analysis of the thermal measurements from Spitzer and the visible/near-IR reflectance spectra. The slab interpretation offers two falsifiable predictions (1) Absence of an opposition surge, which is commonly attributed to the fluffiness of the optical surface. This prediction is best testable with a spacecraft, as Earth-based observations at true opposition will not be possible until early next century. (2) Unlikelihood of the simultaneous occurrence of very long spectroscopic path lengths in both methane and nitrogen ice on the surface of any Kuiper Belt Object, as the more volatile nitrogen would hinder densification in methane ice.

Properties of magnetic photonic crystals in the visible spectral region and their performance limitations

Science.gov (United States)

Kotov, V. A.; Shavrov, V. G.; Vasiliev, M.; Alameh, K.; Nur-E-Alam, M.; Balabanov, D. E.

2018-02-01

We report on the results of computer modelling and performance analysis of the optical and magneto-optical (MO) characteristics of one-dimensional magnetic photonic crystals (MPC) of several classic design types (having either a single structure defect, or a number of these), designed for applications in the visible spectral region. The calculations are performed accounting for the real levels of optical absorption achievable in existing MO materials which currently demonstrate the best MO quality (bismuth-substituted ferrite garnets). We consider Bi2Dy1Fe4Ga1O12 as the base material for use within quarter-wave thick MO layers of MPC; silica is used for the non-magnetic transparent quarter-wave layers. The achieved results can be used to clarify the nature of the differences that exist between the expected practical potential of MPCs in integrated photonics, and the actual attained experimental results. Our results show that in MPCs optimized for light intensity modulation applications, in the red spectral region (near 650 nm), the achievable levels of optical transmission are limited to about 30%. This coincides spectrally with the peaks of Faraday rotation reaching their maxima at about 25°, with further transmission increases possible in the near-infrared region. Larger Faraday rotation angles are only achievable currently in structures or single film layers with reduced transmission.

Visible/Near-Infrared Spectral Properties of MUSES C Target Asteroid 25143 Itokawa

Science.gov (United States)

Jarvis, K. S.; Vilas, F.; Kelley, M. S.; Abell, P. A.

2004-01-01

The Japanese MUSES C mission launched the Hayabusa spacecraft last May 15, 2003, to encounter and study the near-Earth asteroid 25143 Itokawa. The spacecraft will obtain visible images through broadband filters similar to the ECAS filters, and near-infrared spectra from 0.85 - 2.1 microns. In preparation for this encounter, opportunities to study the asteroid with Earth-based telescopes have been fully leveraged. Visible and near-infrared spectral observations were made of asteroid 25143 Itokawa during several nights of March, 2001, around the last apparition. We report here on the results of extensive spectral observations made to address the questions of compositional variations across the surface of the asteroid (as determined by the rotational period and shape model); variations in phase angle (Sun-Itokawa-Earth angle) on spectral characteristics; and predictions of Itokawa observations by Hayabusa based on the spectral resolution and responsivity of the NIRS and AMICA instruments.

AN UNBIASED SPECTRAL LINE SURVEY TOWARD R CrA IRS7B IN THE 345 GHz WINDOW WITH ASTE

International Nuclear Information System (INIS)

Watanabe, Yoshimasa; Sakai, Nami; Yamamoto, Satoshi; Lindberg, Johan E.; Bisschop, Suzanne E.; Jørgensen, Jes K.

2012-01-01

We have conducted a spectral line survey in the 332-364 GHz region with the Atacama Submillimeter Telescope Experiment 10 m telescope toward R CrA IRS7B, a low-mass protostar in the Class 0 or Class 0/I transitional stage. We have also performed some supplementary observations in the 450 GHz band. In total, 16 molecular species are identified in the 332-364 GHz region. Strong emission lines of CN and CCH are observed, whereas complex organic molecules and long carbon-chain molecules, which are characteristics of hot corino and warm carbon-chain chemistry (WCCC) source, respectively, are not detected. The rotation temperature of CH 3 OH is evaluated to be 31 K, which is significantly lower than that reported for the prototypical hot corino IRAS 16293-2422 (∼85 K). The deuterium fractionation ratios for CCH and H 2 CO are obtained to be 0.038 and 0.050, respectively, which are much lower than those in the hot corino. These results suggest a weak hot corino activity in R CrA IRS7B. On the other hand, the carbon-chain related molecules, CCH and c-C 3 H 2 , are found to be abundant. However, this source cannot be classified as a WCCC source, since long carbon-chain molecules are not detected. If WCCC and hot corino chemistry represent the two extremes in chemical compositions of low-mass Class 0 sources, R CrA IRS7B would be a source with a mixture of these two chemical characteristics. The UV radiation from the nearby Herbig Ae star R CrA may also affect the chemical composition. The present line survey demonstrates further chemical diversity in low-mass star-forming regions.

Spectral properties of eight near-Earth asteroids

Science.gov (United States)

Popescu, M.; Birlan, M.; Binzel, R.; Vernazza, P.; Barucci, A.; Nedelcu, D. A.; DeMeo, F.; Fulchignoni, M.

2011-11-01

Context. Near-Earth objects are among the most accessible bodies in the solar system in terms of the spacecraft propulsion requirements to reach them. The choice of targets and the planning of space missions are based on high quality ground-based science. Aims: The knowledge of the ensemble of physical parameters for these objects, including their composition, is a critical point in defining any mission scientific objectives. Determining the physical properties of near-Earth asteroids (NEAs) is also possible from the ground by analyzing spectroscopy at both visible and infrared wavelengths. Methods: We present spectra of eight NEAs (1917, 8567, 16960, 164400, 188452, 2001 SG286, and 2010 TD54) obtained using the NASA telescope IRTF equipped with the spectro-imager SpeX. The observations were performed in the 0.8-2.5 μm spectral region using the low resolution mode of the spectrograph. We completed the taxonomic classification using the Bus-DeMeo taxonomy. We analyzed the spectra by comparing them to meteorite spectra from the Relab database using a χ2 approach. For the S-type asteroids of our sample, the band centers and BAR were calculated. We also attempted to interpret our data using a space-weathering model. Results: The taxonomic classification of five objects was reviewed and we assigned a corresponding type to the other three asteroids that were not classified before. We found that (1917) Cuyo, (8567) 1996 HW1, (16960) 1998 QS52, (188452) 2004 HE62, and 2010 TD54 are in the S-complex. We achieved a good matching of our S-type asteroids with the spectra of ordinary chondrites meteorites. The asteroid (5620) Jasonwheeler was found to have a NIR spectrum similar to carbonaceous chondrite meteorites. Thus, our results confirm its primitive properties obtained in several other spectral intervals. Appendices A and B are available in electronic form at http://www.aanda.org

Characterizing CDOM Spectral Variability Across Diverse Regions and Spectral Ranges

Science.gov (United States)

Grunert, Brice K.; Mouw, Colleen B.; Ciochetto, Audrey B.

2018-01-01

Satellite remote sensing of colored dissolved organic matter (CDOM) has focused on CDOM absorption (aCDOM) at a reference wavelength, as its magnitude provides insight into the underwater light field and large-scale biogeochemical processes. CDOM spectral slope, SCDOM, has been treated as a constant or semiconstant parameter in satellite retrievals of aCDOM despite significant regional and temporal variabilities. SCDOM and other optical metrics provide insights into CDOM composition, processing, food web dynamics, and carbon cycling. To date, much of this work relies on fluorescence techniques or aCDOM in spectral ranges unavailable to current and planned satellite sensors (e.g., global variability in SCDOM and fit deviations in the aCDOM spectra using the recently proposed Gaussian decomposition method. From this, we investigate if global variability in retrieved SCDOM and Gaussian components is significant and regionally distinct. We iteratively decreased the spectral range considered and analyzed the number, location, and magnitude of fitted Gaussian components to understand if a reduced spectral range impacts information obtained within a common spectral window. We compared the fitted slope from the Gaussian decomposition method to absorption-based indices that indicate CDOM composition to determine the ability of satellite-derived slope to inform the analysis and modeling of large-scale biogeochemical processes. Finally, we present implications of the observed variability for remote sensing of CDOM characteristics via SCDOM.

Upconversion imager measures single mid-IR photons

DEFF Research Database (Denmark)

Dam, Jeppe Seidelin; Tidemand-Lichtenberg, Peter; Pedersen, Christian

2013-01-01

the performance of today's state of the art IR detectors for the visible/near-IR region shows a striking contrast, as the latter can have dark currents in the range of 0.001 electrons per second. Demonstrated performance of waveguide upconversion techniques still show considerable dark noise, even when working...

Infrared (IR) photon-sensitive spectromicroscopy in a cryogenic environment

Science.gov (United States)

Pereverzev, Sergey

2016-06-14

A system designed to suppress thermal radiation background and to allow IR single-photon sensitive spectromicroscopy of small samples by using both absorption, reflection, and emission/luminescence measurements. The system in one embodiment includes: a light source; a plurality of cold mirrors configured to direct light along a beam path; a cold or warm sample holder in the beam path; windows of sample holder (or whole sample holder) are transparent in a spectral region of interest, so they do not emit thermal radiation in the same spectral region of interest; a cold monochromator or other cold spectral device configured to direct a selected fraction of light onto a cold detector; a system of cold apertures and shields positioned along the beam path to prevent unwanted thermal radiation from arriving at the cold monochromator and/or the detector; a plurality of optical, IR and microwave filters positioned along the beam path and configured to adjust a spectral composition of light incident upon the sample under investigation and/or on the detector; a refrigerator configured to maintain the detector at a temperature below 1.0K; and an enclosure configured to: thermally insulate the light source, the plurality of mirrors, the sample holder, the cold monochromator and the refrigerator.

Raman and Mid-IR Spectral Analysis of the Atacamite-Structure Hydroxyl/Deuteroxyl Nickel Chlorides Ni2(OH/D)3Cl

Institute of Scientific and Technical Information of China (English)

LIU Xiao-Dong; Hagihala Masato; ZHENG Xu-Guang; MENG Dong-Doug; GUO Qi-Xin

2011-01-01

@@ Vibrational spectra(Raman 4000-95cm-1 and mid-IR 4000-400cm-1) of the atacamite-structure Ni2(OH)3Cl,including a rarely reported kind of asymmetric trimetric hydrogen bond, as a member of the geometrically frustrated material series and its deuteride Ni2(OD)3Cl are, to the best of our knowledge, reported for the first time and analyzed at room temperature.Through a comparative study of four spectra according to their crystal structural parameters, we assign OH stretching modes v(OH) in a functional group region(3700-3400 cm-1) and their deformation modes δ(NiOH/D) in the correlation peak region(900-600 cm-1)with the corresponding mode frequency ratios ωv(OD)/ωv(OH)≈73% and ωδ(NiOD)/ωδ(NiOH)≈75%, and further self-consistently suggest NiO and Ni-Cl related modes in the fingerprint region(500-200cm-1 and 200-Ocm-1, respectively) by use of the unified six-ligand NiO5Cl and NiO4Cl2 frames.This report may contribute to the spectral analysis of other hydroxyl transition-metal halides and to the understanding of the fundamental physics of their exotic magnetic geometrical frustration property from the spectral changes around the corresponding low transition temperatures.

Radical protection by differently composed creams in the UV/VIS and IR spectral ranges.

Science.gov (United States)

Meinke, Martina C; Syring, Felicia; Schanzer, Sabine; Haag, Stefan F; Graf, Rüdiger; Loch, Manuela; Gersonde, Ingo; Groth, Norbert; Pflücker, Frank; Lademann, Jürgen

2013-01-01

Modern sunscreens are well suited to provide sufficient protection in the UV range because the filter substances absorb or scatter UV radiation. Although up to 50% of radicals are formed in the visible and infrared spectral range during solar radiation protection strategies are not provided in this range. Previous investigations of commercially available products have shown that in addition to physical filters, antioxidants (AO) are necessary to provide protective effects in the infrared range by neutralizing already formed radicals. In this study, the efficacy of filter substances and AO to reduce radical formation in both spectral ranges was investigated after UV/VIS or IR irradiation. Optical properties and radical protection were determined for the investigated creams. It was found that organic UV filters lower radical formation in the UV/VIS range to 35% compared to untreated skin, independent of the presence of AO. Further reduction to 14% was reached by addition of 2% physical filters, whereas physical filters alone were ineffective in the UV/VIS range due to the low concentration. In contrast, this filter type reduced radical formation in the IR range significantly to 65%; similar effects were aroused after application of AO. Sunscreens which contain organic UV filters, physical filters and AO ensure protection in the complete solar spectrum. © 2013 The American Society of Photobiology.

Spectral properties of near-Earth asteroids on cometary orbits

Science.gov (United States)

Popescu, M.; Vaduvescu, O.; de Leon, J.; Boaca, I. L.; Gherase, R. M.; Nedelcu, D. A.; INT students, I. N. G.

2017-09-01

We studied the spectral distributions of near-Earth asteroids on cometary orbits (NEACOs) in order to identify potential dormant or extinct comets among these objects. We present the spectral observations for 19 NEACOs obtained with Isaac Newton Telescope and Infrared Telescope Facility (IRTF). Although initially classified as asteroid, one of our targets - 2007 VA85 was confirmed to be active comet 333P/LINEAR on its 2016 appearance. We found that the NEACOs population is a mixing of different compositional classes.

AgCl-doped CdSe quantum dots with near-IR photoluminescence.

Science.gov (United States)

Kotin, Pavel Aleksandrovich; Bubenov, Sergey Sergeevich; Mordvinova, Natalia Evgenievna; Dorofeev, Sergey Gennadievich

2017-01-01

We report the synthesis of colloidal CdSe quantum dots doped with a novel Ag precursor: AgCl. The addition of AgCl causes dramatic changes in the morphology of synthesized nanocrystals from spherical nanoparticles to tetrapods and finally to large ellipsoidal nanoparticles. Ellipsoidal nanoparticles possess an intensive near-IR photoluminescence ranging up to 0.9 eV (ca. 1400 nm). In this article, we explain the reasons for the formation of the ellipsoidal nanoparticles as well as the peculiarities of the process. The structure, Ag content, and optical properties of quantum dots are also investigated. The optimal conditions for maximizing both the reaction yield and IR photoluminescence quantum yield are found.

EPR and IR spectral investigations on some leafy vegetables of Indian origin

Science.gov (United States)

Prasuna, C. P. Lakshmi; Chakradhar, R. P. S.; Rao, J. L.; Gopal, N. O.

2009-09-01

EPR spectral investigations have been carried out on four edible leafy vegetables of India, which are used as dietary component in day to day life. In Rumex vesicarius leaf sample, EPR spectral investigations at different temperatures indicate the presence of anti-ferromagnetically coupled Mn(IV)-Mn(IV) complexes. EPR spectra of Trigonella foenum graecum show the presence of Mn ions in multivalent state and Fe 3+ ions in rhombic symmetry. EPR spectra of Basella rubra indicate the presence of Mn(IV)-O-Mn(IV) type complexes. The EPR spectra of Basella rubra have been studied at different temperatures. It is found that the spin population for the resonance signal at g = 2.06 obeys the Boltzmann distribution law. The EPR spectra of Moringa oliefera leaves show the presence of Mn 2+ ions. Radiation induced changes in free radical of this sample have also been studied. The FT-IR spectra of Basella rubra and Moringa oliefera leaves show the evidences for the protein matrix bands and those corresponding to carboxylic C dbnd O bonds.

DISCOVERY OF THE VERY RED NEAR-INFRARED AND OPTICAL AFTERGLOW OF THE SHORT-DURATION GRB 070724A

International Nuclear Information System (INIS)

Berger, E.; Cenko, S. B.; Fox, D. B.; Cucchiara, A.

2009-01-01

We report the discovery of the near-infrared and optical afterglow of the short-duration gamma-ray burst GRB 070724A. The afterglow is detected in iJHK s observations starting 2.3 hr after the burst with K s = 19.59 ± 0.16 mag and i = 23.79 ± 0.07 mag, but is absent in images obtained 1.3 yr later. Fading is also detected in the K s band between 2.8 and 3.7 hr at a 4σ significance level. The optical/near-IR spectral index, β O,NIR ∼ -2, is much redder than expected in the standard afterglow model, pointing to either significant dust extinction, A host V ∼ 2 mag, or a non-afterglow origin for the near-IR emission. The case for extinction is supported by a shallow optical to X-ray spectral index, consistent with the definition for 'dark bursts', and a normal near-IR to X-ray spectral index. Moreover, a comparison to the optical discovery magnitudes of all short GRBs with optical afterglows indicates that the near-IR counterpart of GRB 070724A is one of the brightest to date, while its observed optical emission is one of the faintest. In the context of a non-afterglow origin, the near-IR emission may be dominated by a mini-supernova (mini-SN), leading to an estimated ejected mass of M ∼ 10 -4 M sun and a radioactive energy release efficiency of f ∼ 5 x 10 -3 (for v ∼ 0.3c). However, the mini-SN model predicts a spectral peak in the UV rather than near-IR, suggesting that this is either not the correct interpretation or that the mini-SN models need to be revised. Finally, the afterglow coincides with a star-forming galaxy at z = 0.457, previously identified as the host based on its coincidence with the X-ray afterglow position (∼2'' radius). Our discovery of the optical/near-IR afterglow makes this association secure, and furthermore localizes the burst to the outskirts of the galaxy, with an offset of 4.8 ± 0.1 kpc relative to the host center. At such a large offset, the possible large extinction points to a dusty environment local to the burst and

Investigation of conspicuous infrared star cluster and star-forming region RCW 38 IR Cluster

International Nuclear Information System (INIS)

Gyulbudaghian, A.L.; May, J.

2008-01-01

An infrared star cluster RCW 38 IR Cluster, which is also a massive star-forming region, is investigated. The results of observations with SEST (Cerro is Silla, Chile) telescope on 2.6-mm 12 CO spectral line and with SIMBA on 1.2-mm continuum are given. The 12 CO observations revealed the existence of several molecular clouds, two of which (clouds I and 2) are connected with the object RCW 38 IR Cluster. Cloud 1 is a massive cloud, which has a depression in which the investigated object is embedded. It is not excluded that the depression was formed by the wind and/or emission from the young bright stars belonging to the star cluster. Rotation of cloud 2, around the axis having SE-NW direction, with an angular velocity ω 4.6 · 10 -14 s -1 is also found. A red-shifted outflow with velocity ∼+5.6 km/s, in the SE direction and perpendicular to the elongation of cloud 2 has been also found. The investigated cluster is associated with an IR point source IRAS 08573-4718, which has IR colours typical for a, non-evolved embedded (in the cloud) stellar object. The cluster is also connected with a water maser. The SIMBA image shoves the existence of a central bright condensation, coinciding with the cluster itself, and two extensions. One of these extensions (the one with SW-NE direction) coincides, both in place and shape, with cloud 2, so that it is not excluded the possibility that this extension might be also rotating like cloud 2. In the vicinity of these extensions there are condensations resembling HH objects

Moving the Plasmon of LaB6 from IR to Near-IR via Eu-Doping

Directory of Open Access Journals (Sweden)

Tracy M. Mattox

2018-02-01

Full Text Available Lanthanum hexaboride (LaB6 has become a material of intense interest in recent years due to its low work function, thermal stability and intriguing optical properties. LaB6 is also a semiconductor plasmonic material with the ability to support strong plasmon modes. Some of these modes uniquely stretch into the infrared, allowing the material to absorb around 1000 nm, which is of great interest to the window industry. It is well known that the plasmon of LaB6 can be tuned by controlling particle size and shape. In this work, we explore the options available to further tune the optical properties by describing how metal vacancies and Eu doping concentrations are additional knobs for tuning the absorbance from the near-IR to far-IR in La1−xEuxB6 (x = 0, 0.2, 0.5, 0.8, and 1.0. We also report that there is a direct correlation between Eu concentration and metal vacancies within the Eu1−xLaxB6.

Validation of Correction Algorithms for Near-IR Analysis of Human Milk in an Independent Sample Set-Effect of Pasteurization.

Science.gov (United States)

Kotrri, Gynter; Fusch, Gerhard; Kwan, Celia; Choi, Dasol; Choi, Arum; Al Kafi, Nisreen; Rochow, Niels; Fusch, Christoph

2016-02-26

Commercial infrared (IR) milk analyzers are being increasingly used in research settings for the macronutrient measurement of breast milk (BM) prior to its target fortification. These devices, however, may not provide reliable measurement if not properly calibrated. In the current study, we tested a correction algorithm for a Near-IR milk analyzer (Unity SpectraStar, Brookfield, CT, USA) for fat and protein measurements, and examined the effect of pasteurization on the IR matrix and the stability of fat, protein, and lactose. Measurement values generated through Near-IR analysis were compared against those obtained through chemical reference methods to test the correction algorithm for the Near-IR milk analyzer. Macronutrient levels were compared between unpasteurized and pasteurized milk samples to determine the effect of pasteurization on macronutrient stability. The correction algorithm generated for our device was found to be valid for unpasteurized and pasteurized BM. Pasteurization had no effect on the macronutrient levels and the IR matrix of BM. These results show that fat and protein content can be accurately measured and monitored for unpasteurized and pasteurized BM. Of additional importance is the implication that donated human milk, generally low in protein content, has the potential to be target fortified.

Spectral Imaging by Upconversion

DEFF Research Database (Denmark)

Dam, Jeppe Seidelin; Pedersen, Christian; Tidemand-Lichtenberg, Peter

2011-01-01

We present a method to obtain spectrally resolved images using upconversion. By this method an image is spectrally shifted from one spectral region to another wavelength. Since the process is spectrally sensitive it allows for a tailored spectral response. We believe this will allow standard...... silicon based cameras designed for visible/near infrared radiation to be used for spectral images in the mid infrared. This can lead to much lower costs for such imaging devices, and a better performance....

Spectral energy distributions of T Tauri stars - disk flaring and limits on accretion

International Nuclear Information System (INIS)

Kenyon, S.J.; Hartmann, L.

1987-01-01

The Adams et al. (1987) conclusion that much of the IR excess emission in the spectral energy distribution of T Tauri stars arises from reprocessing of stellar radiation by a dusty circumstellar disk is presently supported by analyses conducted in light of various models of these stars' spectra. A low mass reprocessing disk can, however, produce these spectra as well as a massive accretion disk. The detection of possible boundary layer radiation in the optical and near-UV regions poses the strongest limits on accretion rates. Disk accretion in the T Tauri phase does not significantly modify stellar evolution. 85 references

Infrared polarimetry of the reflection nebula near L 1551 IRS 5

Energy Technology Data Exchange (ETDEWEB)

Nagata, Tetsuya; Yamashita, Takuya; Sato, Shuji; Suzuki, Hiro; Hough, J H; Garden, R; Gatley, I

1986-11-01

The K-band polarization has been measured in the region extending 30 arcsec to the SW of L 1551 IRS5. The degree of polarization is exceptionally high, reaching approx. 67 per cent. The large polarizations and the azimuthal pattern of the position angles are attributed to scattering of infrared radiation from IRS5 by dust grains. The infrared brightness distribution resembles that of the optical nebulosity. It is proposed that infrared scattering occurs at the 'walls' of a cavity formed by the interaction of stellar winds with the ambient cloud.

Water vapor retrieval from near-IR measurements of polarized scanning atmospheric corrector

Science.gov (United States)

Qie, Lili; Ning, Yuanming; Zhang, Yang; Chen, Xingfeng; Ma, Yan; Li, Zhengqiang; Cui, Wenyu

2018-02-01

Water vapor and aerosol are two key atmospheric factors effecting the remote sensing image quality. As water vapor is responsible for most of the solar radiation absorption occurring in the cloudless atmosphere, accurate measurement of water content is important to not only atmospheric correction of remote sensing images, but also many other applications such as the study of energy balance and global climate change, land surface temperature retrieval in thermal remote sensing. A multi-spectral, single-angular, polarized radiometer called Polarized Scanning Atmospheric Corrector (PSAC) were developed in China, which are designed to mount on the same satellite platform with the principle payload and provide essential parameters for principle payload image atmospheric correction. PSAC detect water vapor content via measuring atmosphere reflectance at water vapor absorbing channels (i.e. 0.91 μm) and nearby atmospheric window channel (i.e. 0.865μm). A near-IR channel ratio method was implemented to retrieve column water vapor (CWV) amount from PSAC measurements. Field experiments were performed at Yantai, in Shandong province of China, PSAC aircraft observations were acquired. The comparison between PSAC retrievals and ground-based Sun-sky radiometer measurements of CWV during the experimental flights illustrates that this method retrieves CWV with relative deviations ranging from 4% 13%. This method retrieve CWV more accurate over land than over ocean, as the water reflectance is low.

Nonlocal Coulomb correlations in pure and electron-doped Sr2IrO4 : Spectral functions, Fermi surface, and pseudo-gap-like spectral weight distributions from oriented cluster dynamical mean-field theory

Science.gov (United States)

Martins, Cyril; Lenz, Benjamin; Perfetti, Luca; Brouet, Veronique; Bertran, François; Biermann, Silke

2018-03-01

We address the role of nonlocal Coulomb correlations and short-range magnetic fluctuations in the high-temperature phase of Sr2IrO4 within state-of-the-art spectroscopic and first-principles theoretical methods. Introducing an "oriented-cluster dynamical mean-field scheme", we compute momentum-resolved spectral functions, which we find to be in excellent agreement with angle-resolved photoemission spectra. We show that while short-range antiferromagnetic fluctuations are crucial to accounting for the electronic properties of Sr2IrO4 even in the high-temperature paramagnetic phase, long-range magnetic order is not a necessary ingredient of the insulating state. Upon doping, an exotic metallic state is generated, exhibiting cuprate-like pseudo-gap spectral properties, for which we propose a surprisingly simple theoretical mechanism.

ETA CARINAE ACROSS THE 2003.5 MINIMUM: ANALYSIS IN THE VISIBLE AND NEAR-INFRARED SPECTRAL REGION

International Nuclear Information System (INIS)

Nielsen, K. E.; Kober, G. Vieira; Weis, K.; Bomans, D. J.; Gull, T. R.; Stahl, O.

2009-01-01

We present an analysis of the visible through near-infrared spectrum of Eta Carinae (η Car) and its ejecta obtained during the 'η Car Campaign with the Ultraviolet and Visual Echelle Spectrograph (UVES) at the ESO Very Large Telescope (VLT)'. This is a part of larger effort to present a complete η Car spectrum, and extends the previously presented analyses with the Hubble Space Telescope/Space Telescope Imaging Spectrograph (HST/STIS) in the UV (1240-3159 A) to 10,430 A. The spectrum in the mid- and near-UV is characterized by the ejecta absorption. At longer wavelengths, stellar wind features from the central source and narrow-emission lines from the Weigelt condensations dominate the spectrum. However, narrow absorption lines from the circumstellar shells are present. This paper provides a description of the spectrum between 3060 and 10,430 A, including line identifications of the ejecta absorption spectrum, the emission spectrum from the Weigelt condensations and the P Cygni stellar wind features. The high spectral resolving power of VLT/UVES enables equivalent width measurements of atomic and molecular absorption lines for elements with no transitions at the shorter wavelengths. However, the ground-based seeing and contributions of nebular-scattered radiation prevent direct comparison of measured equivalent widths in the VLT/UVES and HST/STIS spectra. Fortunately, HST/STIS and VLT/UVES have a small overlap in wavelength coverage which allows us to compare and adjust for the difference in scattered radiation entering the instruments' apertures. This paper provides a complete online VLT/UVES spectrum with line identifications and a spectral comparison between HST/STIS and VLT/UVES between 3060 and 3160 A.

Mord studies in IR region by new dispersion relation

International Nuclear Information System (INIS)

Murthy, V.R.; Kumar, R. Jeevan

1994-01-01

This is the continuation of the series reporting MORD studies to typical problem in Chemistry and Polymer Science. In our earlier papers the MORDsup1.2 studied only in visible region. In this present investigation we extended the application of the New Dispersion Relation in IR region to determine the MORD and tested to some simple systems

The design and application of a multi-band IR imager

Science.gov (United States)

Li, Lijuan

2018-02-01

Multi-band IR imaging system has many applications in security, national defense, petroleum and gas industry, etc. So the relevant technologies are getting more and more attention in rent years. As we know, when used in missile warning and missile seeker systems, multi-band IR imaging technology has the advantage of high target recognition capability and low false alarm rate if suitable spectral bands are selected. Compared with traditional single band IR imager, multi-band IR imager can make use of spectral features in addition to space and time domain features to discriminate target from background clutters and decoys. So, one of the key work is to select the right spectral bands in which the feature difference between target and false target is evident and is well utilized. Multi-band IR imager is a useful instrument to collect multi-band IR images of target, backgrounds and decoys for spectral band selection study at low cost and with adjustable parameters and property compared with commercial imaging spectrometer. In this paper, a multi-band IR imaging system is developed which is suitable to collect 4 spectral band images of various scenes at every turn and can be expanded to other short-wave and mid-wave IR spectral bands combination by changing filter groups. The multi-band IR imaging system consists of a broad band optical system, a cryogenic InSb large array detector, a spinning filter wheel and electronic processing system. The multi-band IR imaging system's performance is tested in real data collection experiments.

EVIDENCE FOR NON-STELLAR REST-FRAME NEAR-IR EMISSION ASSOCIATED WITH INCREASED STAR FORMATION IN GALAXIES AT z ∼ 1

International Nuclear Information System (INIS)

Lange, Johannes U.; Van Dokkum, Pieter G.; Momcheva, Ivelina G.; Nelson, Erica J.; Leja, Joel; Brammer, Gabriel; Whitaker, Katherine E.; Franx, Marijn

2016-01-01

We explore the presence of non-stellar rest-frame near-IR (2–5 μm) emission in galaxies at z ∼ 1. Previous studies identified this excess in relatively small samples and suggested that such non-stellar emission, which could be linked to the 3.3 μm polycyclic aromatic hydrocarbons feature or hot dust emission, is associated with an increased star formation rate (SFR). In this Letter, we confirm and quantify the presence of an IR excess in a significant fraction of galaxies in the 3D-HST GOODS catalogs. By constructing a matched sample of galaxies with and without strong non-stellar near-IR emission, we find that galaxies with such emission are predominantly star-forming galaxies. Moreover, star-forming galaxies with an excess show increased mid- and far-IR and Hα emission compared to other star-forming galaxies without. While galaxies with a near-IR excess show a larger fraction of individually detected X-ray active galactic nuclei (AGNs), an X-ray stacking analysis, together with the IR-colors and Hα profiles, shows that AGNs are unlikely to be the dominant source of excess in the majority of galaxies. Our results suggest that non-stellar near-IR emission is linked to increased SFRs and is ubiquitous among star-forming galaxies. As such, the near-IR emission might be a powerful tool to measure SFRs in the era of the James Webb Space Telescope

Near Infrared Cavity Ring-Down Spectroscopy for Isotopic Analyses of CH4 on Future Martian Surface Missions

Science.gov (United States)

Chen, Y.; Mahaffy P.; Holmes, V.; Burris, J.; Morey, P.; Lehmann, K.K.; Lollar, B. Sherwood; Lacrampe-Couloume, G.; Onstott, T.C.

2014-01-01

A compact Near Infrared Continuous Wave Cavity Ring-Down Spectrometer (near-IR-cw-CRDS) was developed as a candidate for future planetary surface missions. The optical cavity was made of titanium with rugged quartz windows to protect the delicate super cavity from the harsh environmental changes that it would experience during space flight and a Martian surface mission. This design assured the long-term stability of the system. The system applied three distributed feedback laser diodes (DFB-LD), two of which were tuned to the absorption line peaks of (sup 12)CH4 and (sup 13)CH4 at 6046.954 inverse centimeters and 6049.121 inverse centimeters, respectively. The third laser was tuned to a spectral-lines-free region for measuring the baseline cavity loss. The multiple laser design compensated for typical baseline drift of a CRDS system and, thus, improved the overall precision. A semiconductor optical amplifier (SOA) was used instead of an Acousto-Optic Module (AOM) to initiate the cavity ring-down events. It maintained high acquisition rates such as AOM, but consumed less power. High data acquisition rates combined with improved long-term stability yielded precise isotopic measurements in this near-IR region even though the strongest CH4 absorption line in this region is 140 times weaker than that of the strongest mid-IR absorption band. The current system has a detection limit of 1.4 times 10( sup –12) inverse centimeters for (sup 13)CH4. This limit corresponds to approximately 7 parts per trillion volume of CH4 at 100 Torrs. With no further improvements the detection limit of our current near IR-cw-CRDS at an ambient Martian pressure of approximately 6 Torrs (8 millibars) would be 0.25 parts per billion volume for one 3.3 minute long analysis.

Validation of Correction Algorithms for Near-IR Analysis of Human Milk in an Independent Sample Set—Effect of Pasteurization

Science.gov (United States)

Kotrri, Gynter; Fusch, Gerhard; Kwan, Celia; Choi, Dasol; Choi, Arum; Al Kafi, Nisreen; Rochow, Niels; Fusch, Christoph

2016-01-01

Commercial infrared (IR) milk analyzers are being increasingly used in research settings for the macronutrient measurement of breast milk (BM) prior to its target fortification. These devices, however, may not provide reliable measurement if not properly calibrated. In the current study, we tested a correction algorithm for a Near-IR milk analyzer (Unity SpectraStar, Brookfield, CT, USA) for fat and protein measurements, and examined the effect of pasteurization on the IR matrix and the stability of fat, protein, and lactose. Measurement values generated through Near-IR analysis were compared against those obtained through chemical reference methods to test the correction algorithm for the Near-IR milk analyzer. Macronutrient levels were compared between unpasteurized and pasteurized milk samples to determine the effect of pasteurization on macronutrient stability. The correction algorithm generated for our device was found to be valid for unpasteurized and pasteurized BM. Pasteurization had no effect on the macronutrient levels and the IR matrix of BM. These results show that fat and protein content can be accurately measured and monitored for unpasteurized and pasteurized BM. Of additional importance is the implication that donated human milk, generally low in protein content, has the potential to be target fortified. PMID:26927169

Surface Compositional Units on Mercury from Spectral Reflectance at Ultraviolet to Near-infrared Wavelengths

Science.gov (United States)

Izenberg, N. R.; Holsclaw, G. M.; Domingue, D. L.; McClintock, W. E.; Klima, R. L.; Blewett, D. T.; Helbert, J.; Head, J. W.; Sprague, A. L.; Vilas, F.; Solomon, S. C.

2012-12-01

The Mercury Atmospheric and Surface Composition Spectrometer (MASCS) on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft has been acquiring reflectance spectra of Mercury's surface for over 16 months. The Visible and Infrared Spectrograph (VIRS) component of MASCS has accumulated a global data set of more than 2 million spectra over the wavelength range 300-1450 nm. We have derived a set of VIRS spectral units (VSUs) from the following spectral parameters: visible brightness (R575: reflectance at 575 nm); visible/near-infrared reflectance ratio (VISr: reflectance at 415 nm to that at 750 nm); and ultraviolet reflectance ratio (UVr: reflectance at 310 nm to that at 390 nm). Five broad, slightly overlapping VSUs may be distinguished from these parameters. "Average VSU" areas have spectral parameters close to mean global values. "Dark blue VSU" areas have spectra with low R575 and high UVr. "Red VSU" areas have spectra with low UVr and higher VISr and R575 than average. "Intermediate VSU" areas have spectra with higher VISr than VSU red, generally higher R575, and a wide range of UVr. "Bright VSU" areas have high R575 and VISr and intermediate UVr. Several units defined by morphological or multispectral criteria correspond to specific VSUs, including low-reflectance material (dark blue VSU), pyroclastic deposits (red VSU), and hollows (intermediate VSU), but these VSUs generally include other types of areas as well. VSU definitions are complementary to those obtained by unsupervised clustering analysis. The global distribution of VIRS spectral units provides new information on Mercury's geological evolution. Much of Mercury's northern volcanic plains show spectral properties ranging from those of average VSU to those of red VSU, as does a large region in the southern hemisphere centered near 50°S, 245°E. Dark blue VSU material is widely distributed, with concentrations south of the northern plains, around the Rembrandt and

Group velocity measurement using spectral interference in near-field scanning optical microscopy

International Nuclear Information System (INIS)

Mills, John D.; Chaipiboonwong, Tipsuda; Brocklesby, William S.; Charlton, Martin D. B.; Netti, Caterina; Zoorob, Majd E.; Baumberg, Jeremy J.

2006-01-01

Near-field scanning optical microscopy provides a tool for studying the behavior of optical fields inside waveguides. In this experiment the authors measure directly the variation of group velocity between different modes of a planar slab waveguide as the modes propagate along the guide. The measurement is made using the spectral interference between pulses propagating inside the waveguide with different group velocities, collected using a near-field scanning optical microscope at different points down the guide and spectrally resolved. The results are compared to models of group velocities in simple guides

Spectral Identification of New Galactic cLBV and WR Stars

Science.gov (United States)

Stringfellow, G. S.; Gvaramadze, V. V.; Beletsky, Y.; Kniazev, A. Y.

2012-12-01

We have undertaken a near-IR spectral survey of stars associated with compact nebulae recently revealed by the Spitzer and WISE imaging surveys. These circumstellar nebulae, produced by massive evolved stars, display a variety of symmetries and shapes and are often only evident at mid-IR wavelengths. Stars associated with ˜50 of these nebulae have been observed. We also obtained recent spectra of previously confirmed (known) luminous blue variables (LBVs) and candidate LBVs (cLBVs). The spectral similarity of the stars observed when compared directly to known LBVs and Wolf-Rayet (WR) stars indicate many are newly identified cLBVs, with a few being newly discovered WR stars, mostly of WN8-9h spectral type. These results suggest that a large population of previously unidentified cLBVs and related transitional stars reside in the Galaxy and confirm that circumstellar nebulae are inherent to most (c)LBVs.

FT-IR spectroscopy of lipoproteins—A comparative study

Science.gov (United States)

Krilov, Dubravka; Balarin, Maja; Kosović, Marin; Gamulin, Ozren; Brnjas-Kraljević, Jasminka

2009-08-01

FT-IR spectra, in the frequency region 4000-600 cm -1, of four major lipoprotein classes: very low density lipoprotein (VLDL), low density lipoprotein (LDL) and two subclasses of high density lipoproteins (HDL 2 and HDL 3) were analyzed to obtain their detailed spectral characterization. Information about the protein domain of particle was obtained from the analysis of amide I band. The procedure of decomposition and curve fitting of this band confirms the data already known about the secondary structure of two different apolipoproteins: apo A-I in HDL 2 and HDL 3 and apo B-100 in LDL and VLDL. For information about the lipid composition and packing of the particular lipoprotein the well expressed lipid bands in the spectra were analyzed. Characterization of spectral details in the FT-IR spectrum of natural lipoprotein is necessary to study the influence of external compounds on its structure.

Near-infrared spectral imaging Michelson interferometer for astronomical applications

Science.gov (United States)

Wells, C. W.; Potter, A. E.; Morgan, T. H.

1980-01-01

The design and operation of an imaging Michelson interferometer-spectrometer used for near-infrared (0.8 micron to 2.5 microns) spectral imaging are reported. The system employs a rapid scan interferometer modified for stable low resolution (250/cm) performance and a 42 element PbS linear detector array. A microcomputer system is described which provides data acquisition, coadding, and Fourier transformation for near real-time presentation of the spectra of all 42 scene elements. The electronic and mechanical designs are discussed and telescope performance data presented.

Investigation of hybrid molecular material prepared by ionic liquid ...

Indian Academy of Sciences (India)

Wintec

Near IR spectral region (1000–2500 nm) shows the elimination of water in the compound which ... 1-Butyl 3-methyl imidazolium bromide; molecular material; phosphotungstic acid; near IR. ..... attributable to the first overtone of hydroxyl groups,.

SOLAR VARIABILITY FROM 240 TO 1750 nm IN TERMS OF FACULAE BRIGHTENING AND SUNSPOT DARKENING FROM SCIAMACHY

International Nuclear Information System (INIS)

Pagaran, J.; Weber, M.; Burrows, J.

2009-01-01

The change of spectral decomposition of the total radiative output on various timescales of solar magnetic activity is of large interest to terrestrial and solar-stellar atmosphere studies. Starting in 2002, SCIAMACHY was the first satellite instrument to observe daily solar spectral irradiance (SSI) continuously from 230 nm (UV) to 1750 nm (near-infrared; near-IR). In order to address the question of how much UV, visible (vis), and IR spectral regions change on 27 day and 11 year timescales, we parameterize short-term SSI variations in terms of faculae brightening (Mg II index) and sunspot darkening (photometric sunspot index) proxies. Although spectral variations above 300 nm are below 1% and, therefore, well below the accuracy of absolute radiometric calibration, relative accuracy for short-term changes is shown to be in the per mill range. This enables us to derive short-term spectral irradiance variations from the UV to the near-IR. During Halloween solar storm in 2003 with a record high sunspot area, we observe a reduction of 0.3% in the near-IR to 0.5% in the vis and near-UV. This is consistent with a 0.4% reduction in total solar irradiance (TSI). Over an entire 11 year solar cycle, SSI variability covering simultaneously the UV, vis, and IR spectral regions have not been directly observed so far. Using variations of solar proxies over solar cycle 23, solar cycle spectral variations have been estimated using scaling factors that best matched short-term variations of SCIAMACHY. In the 300-400 nm region, which strongly contributes to TSI solar cycle change, a contribution of 34% is derived from SCIAMACHY observations, which is lower than the reported values from SUSIM satellite data and the empirical SATIRE model. The total UV contribution (below 400 nm) to TSI solar cycle variations is estimated to be 55%.

Extending laser plasma accelerators into the mid-IR spectral domain with a next-generation ultra-fast CO2 laser

Science.gov (United States)

Pogorelsky, I. V.; Babzien, M.; Ben-Zvi, I.; Polyanskiy, M. N.; Skaritka, J.; Tresca, O.; Dover, N. P.; Najmudin, Z.; Lu, W.; Cook, N.; Ting, A.; Chen, Y.-H.

2016-03-01

Expanding the scope of relativistic plasma research to wavelengths longer than the λ/≈   0.8-1.1 μm range covered by conventional mode-locked solid-state lasers would offer attractive opportunities due to the quadratic scaling of the ponderomotive electron energy and critical plasma density with λ. Answering this quest, a next-generation mid-IR laser project is being advanced at the BNL ATF as a part of the user facility upgrade. We discuss the technical approach to this conceptually new 100 TW, 100 fs, λ  =   9-11 μm CO2 laser BESTIA (Brookhaven Experimental Supra-Terawatt Infrared at ATF) that encompasses several innovations applied for the first time to molecular gas lasers. BESTIA will enable new regimes of laser plasma accelerators. One example is shock-wave ion acceleration (SWA) from gas jets. We review ongoing efforts to achieve stable, monoenergetic proton acceleration by dynamically shaping the plasma density profile from a hydrogen gas target with laser-produced blast waves. At its full power, 100 TW BESTIA promises to achieve proton beams at an energy exceeding 200 MeV. In addition to ion acceleration in over-critical plasma, the ultra-intense mid-IR BESTIA will open up new opportunities in driving wakefields in tenuous plasmas, expanding the landscape of laser wakefield accelerator (LWFA) studies into the unexplored long-wavelength spectral domain. Simple wavelength scaling suggests that a 100 TW CO2 laser beam will be capable of efficiently generating plasma ‘bubbles’ a thousand times greater in volume compared with a near-IR solid state laser of an equivalent power. Combined with a femtosecond electron linac available at the ATF, this wavelength scaling will facilitate the study of external seeding and staging of LWFAs.

High Resolution Near Infrared Spectrometer to Study the Zodiacal Light Spectrum

Science.gov (United States)

Kutyrev, Alexander; Arendt, R.; Dwek, E.; Moseley, S. H.; Silverberg, R.; Rapchun, D.

2007-12-01

We are developing a near infrared spectrometer for measuring solar absorption lines in the zodiacal light in the near infrared region. R. Reynolds at el. (2004, ApJ 612, 1206) demonstrated that observing single Fraunhofer line can be a powerful tool for extracting zodiacal light parameters based on their measurements of the profile of the Mg I line at 5184 A. We are extending this technique to the near infrared with the primary goal of measuring the absolute intensity of the zodiacal light. This measurement will provide the crucial information needed to accurately subtract zodiacal emission from the DIRBE measurements to get a much higher quality measurement of the extragalactic IR background. The instrument design is based on a dual Fabry-Perot interferometer with a narrow band filter. Its double etalon design allows to achieve high spectral contrast to reject the bright out of band telluric OH emission. High spectral contrast is absolutely necessary to achieve detection limits needed to accurately measure the intensity of the absorption line. We present the design, estimated performance of the instrument with the expected results of the observing program. The project is supported by NASA ROSES-APRA grant.

2.5 TW, two-cycle IR laser pulses via frequency domain optical parametric amplification.

Science.gov (United States)

Gruson, V; Ernotte, G; Lassonde, P; Laramée, A; Bionta, M R; Chaker, M; Di Mauro, L; Corkum, P B; Ibrahim, H; Schmidt, B E; Legaré, F

2017-10-30

Broadband optical parametric amplification in the IR region has reached a new milestone through the use of a non-collinear Frequency domain Optical Parametric Amplification system. We report a laser source delivering 11.6 fs pulses with 30 mJ of energy at a central wavelength of 1.8 μm at 10 Hz repetition rate corresponding to a peak power of 2.5 TW. The peak power scaling is accompanied by a pulse shortening of about 20% upon amplification due to the spectral reshaping with higher gain in the spectral wings. This source paves the way for high flux soft X-ray pulses and IR-driven laser wakefield acceleration.

Near-IR laser-triggered target cell collection using a carbon nanotube-based cell-cultured substrate.

Science.gov (United States)

Sada, Takao; Fujigaya, Tsuyohiko; Niidome, Yasuro; Nakazawa, Kohji; Nakashima, Naotoshi

2011-06-28

Unique near-IR optical properties of single-walled carbon nanotube (SWNTs) are of interest in many biological applications. Here we describe the selective cell detachment and collection from an SWNT-coated cell-culture dish triggered by near-IR pulse laser irradiation. First, HeLa cells were cultured on an SWNT-coated dish prepared by a spraying of an aqueous SWNT dispersion on a glass dish. The SWNT-coated dish was found to show a good cell adhesion behavior as well as a cellular proliferation rate similar to a conventional glass dish. We discovered, by near-IR pulse laser irradiation (at the laser power over 25 mW) to the cell under optical microscopic observation, a quick single-cell detachment from the SWNT-coated surface. Shockwave generation from the irradiated SWNTs is expected to play an important role for the cell detachment. Moreover, we have succeeded in catapulting the target single cell from the cultured medium when the depth of the medium was below 150 μm and the laser power was stronger than 40 mW. The captured cell maintained its original shape. The retention of the genetic information of the cell was confirmed by the polymerase chain reaction (PCR) technique. A target single-cell collection from a culture medium under optical microscopic observation is significant in wide fields of single-cell studies in biological areas.

Near-Infrared Spectroscopic Study of Chlorite Minerals

Directory of Open Access Journals (Sweden)

Min Yang

2018-01-01

Full Text Available The mineral chemistry of twenty chlorite samples from the United States Geological Survey (USGS spectral library and two other regions, having a wide range of Fe and Mg contents and relatively constant Al and Si contents, was studied via infrared (IR spectroscopy, near-infrared (NIR spectroscopy, and X-ray fluorescence (XRF analysis. Five absorption features of the twenty samples near 4525, 4440, 4361, 4270, and 4182 cm−1 were observed, and two diagnostic features at 4440 and 4280 cm−1 were recognized. Assignments of the two diagnostic features were made for two combination bands (ν+δAlAlO−OH and ν+δSiAlO−OH by regression with IR fundamental absorptions. Furthermore, the determinant factors of the NIR band position were found by comparing the band positions with relative components. The results showed that Fe/(Fe + Mg values are negatively correlated with the two NIR combination bands. The findings provide an interpretation of the NIR band formation and demonstrate a simple way to use NIR spectroscopy to discriminate between chlorites with different components. More importantly, spectroscopic detection of mineral chemical variations in chlorites provides geologists with a tool with which to collect information on hydrothermal alteration zones from hyperspectral-resolution remote sensing data.

Optical Remote Sensing for Fence-Line Monitoring using Open-Path Quantum Cascade Laser (QCL) mono-static system for multiple target compounds in the Mid IR 7-13um (Fingerprint) region.

Science.gov (United States)

Zemek, P. G.

2017-12-01

Quantum Cascade Lasers (QCLs) are quickly replacing Tunable Diode Lasers (TDL) for multi-target species identification and quantification in both extractive and open-path (OP) Optical Remote Sensing (ORS) fence-line instrumentation. As was seen with TDL incorporation and pricing drops as the adoption by the telecommunications industry and its current scaling has improved robustness and pricing, the QCL is also, albiet more slowly, becoming a mature market. There are several advantages of QCLs over conventional TDLs such as improved brightness and beam density, high resolution, as well as the incorporation of external etalons or internal gratings to scan over wide spectral areas. QCLs typically operate in the Mid infra-red (MIR) as opposed to the Near-Infrared (NIR) region used with TDL. The MidIR is a target rich absorption band area where compounds have high absorbtivity coefficients resulting in better detection limits as compared to TDL instruments. The use of novel chemometrics and more sensitive non-cryo-cooled detectors has allowed some of the first QCL open-path instruments in both active and passive operation. Data and field studies of one of the newest QCL OP systems is presented that allows one system to measure multiple target compounds. Multiple QCL spectral regions may be stitched together to increase the capability of QCLs over TDL OP systems. A comparison of several ORS type systems will be presented.

Spectral tuning of near-field radiative heat transfer by graphene-covered metasurfaces

Science.gov (United States)

Zheng, Zhiheng; Wang, Ao; Xuan, Yimin

2018-03-01

When two gratings are respectively covered by a layer of graphene sheet, the near-field radiative heat transfer between two parallel gratings made of silica (SiO2) could be greatly improved. As the material properties of doped silicon (n-type doping concentration is 1020 cm-3, marked as Si-20) and SiO2 differ greatly, we theoretically investigate the near-field radiative heat transfer between two parallel graphene-covered gratings made of Si-20 to explore some different phenomena, especially for modulating the spectral properties. The radiative heat flux between two parallel bulks made of Si-20 can be enhanced by using gratings instead of bulks. When the two gratings are respectively covered by a layer of graphene sheet, the radiative heat flux between two gratings made of Si-20 can be further enhanced. By tuning graphene chemical potential μ and grating filling factor f, due to the interaction between surface plasmon polaritons (SPPs) of graphene sheets and grating structures, the spectral properties of the radiative heat flux between two parallel graphene-covered gratings can be effectively regulated. This work will develop and supplement the effects of materials on the near-field radiative heat transfer for this kind of system configuration, paving a way to modulate the spectral properties of near-field radiative heat transfer.

Spectral properties near the Mott transition in the two-dimensional Hubbard model

Science.gov (United States)

Kohno, Masanori

2013-03-01

Single-particle excitations near the Mott transition in the two-dimensional (2D) Hubbard model are investigated by using cluster perturbation theory. The Mott transition is characterized by the loss of the spectral weight from the dispersing mode that leads continuously to the spin-wave excitation of the Mott insulator. The origins of the dominant modes of the 2D Hubbard model near the Mott transition can be traced back to those of the one-dimensional Hubbard model. Various anomalous spectral features observed in cuprate high-temperature superconductors, such as the pseudogap, Fermi arc, flat band, doping-induced states, hole pockets, and spinon-like and holon-like branches, as well as giant kink and waterfall in the dispersion relation, are explained in a unified manner as properties near the Mott transition in a 2D system.

Chapter 1.1 Crystallinity of Nanocellulose Materials by Near-IR FT-Raman Spectroscopy

Science.gov (United States)

Umesh P. Agarwal; Richard S. Reiner; Sally A. Ralph

2013-01-01

Considering that crystallinity is one of the important properties that influence the end use of cellulose nanomaterials, it is important that the former be measured accurately. Recently, a new method based on near-IR FTRaman spectroscopy was proposed to determine cellulose I crystallinity. It was reported that in the Raman spectrum of cellulose materials, the...

Measurement of the refractive index dispersion of As2Se3 bulk glass and thin films prior to and after laser irradiation and annealing using prism coupling in the near- and mid-infrared spectral range

International Nuclear Information System (INIS)

Carlie, N.; Petit, L.; Musgraves, J. D.; Richardson, K.; Anheier, N. C. Jr.; Qiao, H. A.; Bernacki, B.; Phillips, M. C.

2011-01-01

The prism coupling technique has been utilized to measure the refractive index in the near- and mid-IR spectral region of chalcogenide glasses in bulk and thin film form. A commercial system (Metricon model 2010) has been modified with additional laser sources, detectors, and a new GaP prism to allow the measurement of refractive index dispersion over the 1.5-10.6 μm range. The instrumental error was found to be ±0.001 refractive index units across the entire wavelength region examined. Measurements on thermally evaporated AMTIR2 thin films confirmed that (i) the film deposition process provides thin films with reduced index compared to that of the bulk glass used as a target, (ii) annealing of the films increases the refractive index of the film to the level of the bulk glass used as a target to create it, and (iii) it is possible to locally increase the refractive index of the chalcogenide glass using laser exposure at 632.8 nm.

Recent Characterization of the Night-Sky Irradiance in the Visible/Near-Infrared Spectral Band

Science.gov (United States)

Moore, Carolynn; Wood, Michael; Bender, Edward; Hart, Steve

2018-01-01

The U.S. Army RDECOM CERDEC NVESD has made numerous characterizations of the night sky over the past 45 years. Up until the last four years, the measurement devices were highly detector-limited, which led to low spectral resolution, marginal sensitivity in no-moon conditions, and the need for inferential analysis of the resulting data. In 2014, however, the PhotoResearch Model PR-745 spectro-radiometer established a new state of the art for measurement of the integrated night-sky irradiance over the Visible-to-Near-Infrared (VNIR) spectral band (400-1050nm). This has enabled characterization of no-moon night-sky irradiance with a spectral bandwidth less than 15 nanometers, even when this irradiance is attenuated by heavy clouds or forest canopy. Since 2014, we have conducted a series of night-sky data collections at remote sites across the United States. The resulting data has provided new insights into natural radiance variations, cultural lighting impacts, and the spectrally-varying attenuation caused by cloud cover and forest canopy. Several new metrics have also been developed to provide insight into these newly-found components and temporal variations. The observations, findings and conclusions of the above efforts will be presented, including planned near-term efforts to further characterize the night-sky irradiance in the Visible/Near-Infrared spectral band.

Spectral scattering characteristics of space target in near-UV to visible bands.

Science.gov (United States)

Bai, Lu; Wu, Zhensen; Cao, Yunhua; Huang, Xun

2014-04-07

In this study, the spectral scattering characteristics of a space target are calculated in the near-UV to visible bands on the basis of measured data of spectral hemispheric reflectivity in the upper half space. Further, the bidirectional reflection distribution function (BRDF) model proposed by Davies is modified to describe the light scattering properties of a target surface. This modification aims to improve the characteristics identifying ability for different space targets. By using this modified Davies spectrum BRDF model, the spectral scattering characteristics of each subsurface can be obtained. A mathematical model of spectral scattering properties of the space target is built by summing all the contributing surface grid reflection scattering components, considering the impact of surface shadow effect.Moreover, the spectral scattering characteristics of the space target calculated with both the traditional and modified Davies BRDF models are compared. The results show that in the fixed and modified cases, the hemispheric reflectivity significantly affects the spectral scattering irradiance of the target.

Application of FT-IR spectroscopy on breast cancer serum analysis

Science.gov (United States)

Elmi, Fatemeh; Movaghar, Afshin Fayyaz; Elmi, Maryam Mitra; Alinezhad, Heshmatollah; Nikbakhsh, Novin

2017-12-01

Breast cancer is regarded as the most malignant tumor among women throughout the world. Therefore, early detection and proper diagnostic methods have been known to help save women's lives. Fourier Transform Infrared (FT-IR) spectroscopy, coupled with PCA-LDA analysis, is a new technique to investigate the characteristics of serum in breast cancer. In this study, 43 breast cancer and 43 healthy serum samples were collected, and the FT-IR spectra were recorded for each one. Then, PCA analysis and linear discriminant analysis (LDA) were used to analyze the spectral data. The results showed that there were differences between the spectra of the two groups. Discriminating wavenumbers were associated with several spectral differences over the 950-1200 cm- 1(sugar), 1190-1350 cm- 1 (collagen), 1475-1710 cm- 1 (protein), 1710-1760 cm- 1 (ester), 2800-3000 cm- 1 (stretching motions of -CH2 & -CH3), and 3090-3700 cm- 1 (NH stretching) regions. PCA-LDA performance on serum IR could recognize changes between the control and the breast cancer cases. The diagnostic accuracy, sensitivity, and specificity of PCA-LDA analysis for 3000-3600 cm- 1 (NH stretching) were found to be 83%, 84%, 74% for the control and 80%, 76%, 72% for the breast cancer cases, respectively. The results showed that the major spectral differences between the two groups were related to the differences in protein conformation in serum samples. It can be concluded that FT-IR spectroscopy, together with multivariate data analysis, is able to discriminate between breast cancer and healthy serum samples.

Euclid Near Infrared Spectrometer and Photometer instrument concept and first test results obtained for different breadboards models at the end of phase C

DEFF Research Database (Denmark)

Maciaszek, Thierry; Ealet, Anne; Jahnke, Knud

2016-01-01

program with its launch planned for 2020 (ref [1]). The NISP (Near Infrared Spectrometer and Photometer) is one of the two Euclid instruments and is operating in the near-IR spectral region (900- 2000nm) as a photometer and spectrometer. The instrument is composed of: - a cold (135K) optomechanical...... subsystem consisting of a Silicon carbide structure, an optical assembly (corrector and camera lens), a filter wheel mechanism, a grism wheel mechanism, a calibration unit and a thermal control system - a detection subsystem based on a mosaic of 16 HAWAII2RG cooled to 95K with their front-end readout...

N-annulated perylene fused porphyrins with enhanced near-IR absorption and emission

KAUST Repository

Jiao, Chongjun

2010-09-17

N-Annulated perylene fused porphyrins 1 and 2 were synthesized by oxidative dehydrogenation using a Sc(OTf)3/DDQ system. These newly synthesized hybrid molecules are highly soluble in organic solvents and exhibit remarkably intense near-IR absorption, as well as detectable photoluminescence quantum yields, all of which are comparable to or even exceed those of either meso-β doubly linked porphyrin dimer/trimer or bis/tri-N-annulated rylenes. © 2010 American Chemical Society.

Spectral classification of medium-scale high-latitude F region plasma density irregularities

International Nuclear Information System (INIS)

Singh, M.; Rodriguez, P.; Szuszczewicz, E.P.; Sachs Freeman Associates, Bowie, MD)

1985-01-01

The high-latitude ionosphere represents a highly structured plasma. Rodriguez and Szuszczewicz (1984) reported a wide range of plasma density irregularities (150 km to 75 m) at high latitudes near 200 km. They have shown that the small-scale irregularities (7.5 km to 75 m) populated the dayside oval more often than the other phenomenological regions. It was suggested that in the lower F region the chemical recombination is fast enough to remove small-scale irregularities before convection can transport them large distances, leaving structured particle precipitation as the dominant source term for irregularities. The present paper provides the results of spectral analyses of pulsed plasma probe data collected in situ aboard the STP/S3-4 satellite during the period March-September 1978. A quantitative description of irregularity spectra in the high-latitude lower F region plasma density is given. 22 references

Salinity and spectral reflectance of soils

Science.gov (United States)

Szilagyi, A.; Baumgardner, M. F.

1991-01-01

The basic spectral response related to the salt content of soils in the visible and reflective IR wavelengths is analyzed in order to explore remote sensing applications for monitoring processes of the earth system. The bidirectional reflectance factor (BRF) was determined at 10 nm of increments over the 520-2320-nm spectral range. The effect of salts on reflectance was analyzed on the basis of 162 spectral measurements. MSS and TM bands were simulated within the measured spectral region. A strong relationship was found in variations of reflectance and soil characteristics pertaining to salinization and desalinization. Although the individual MSS bands had high R-squared values and 75-79 percent of soil/treatment combinations were separable, there was a large number of soil/treatment combinations not distinguished by any of the four highly correlated MSS bands under consideration.

Spectral dependence of the main parameters of ITE silicon avalanche photodiodes

Science.gov (United States)

Wegrzecka, Iwona; Grynglas, Maria; Wegrzecki, Maciej

2001-08-01

New applications for avalanche photodiodes (APDs) as in systems using visible radiation, have prompted the need for the evaluation of detection properties of ITE APDs in the 400 divided by 700 nm spectral range. The paper presents the method and result of studies on the spectral dependence of the gain, dark and noise currents, sensitivity and excess noise factor of ITE APDs. The studies have shown that ITE APDs optimized for the near IR radiation can be effectively applied in the detection of radiation above the 500 nm wavelength.

MicrOmega IR: a new infrared hyperspectral imaging microscope or in situ analysis

Science.gov (United States)

Vaitua, Leroi; Bibring, Jean-Pierre; Berthé, Michel

2017-11-01

MicrOmega IR is an ultra miniaturized Near Infrared hyperspectral microscope for in situ analysis of samples. It is designed to be implemented on board space planetary vehicles (lander and/or rovers). It acquires images of samples typically some 5 mm in width with a spatial sampling of 20 μm. On each pixel, MicrOmega acquires the spectrum in the spectral range 0.9 - 2.6 μm, with a possibility to extend the sensibility up to 4 μm. The spectrum will be measured in up to 300 contiguous spectral channels (600 in the extended range): given the diagnostic spectral features present in this domain, it provides the composition of each spatially resolved constituent. MicrOmega has thus the potential to identify: minerals, such as pyroxene and olivine, ferric oxides, hydrated phases such as phyllosilicates, sulfates and carbonates, ices and organics. The composition of the various phases within a given sample is a critical record of its formation and evolution. Coupled to the mapping information, it provides unique clues to describe the history of the parent body. In particular, the capability to identify hydrated grains and to characterize their adjacent phases has a huge potential in the search for potential bio-relics in Martian samples. This purely non destructive characterization enables further analyses (e.g. through mass spectrometry) to be performed, and/or to contribute to sample selection to return to Earth. MicrOmega IR is coupled to a visible microscope: MicrOmega VIS. Thus, the MicrOmega instrument is developed by an international consortium: IAS (Orsay, France), LESIA (Meudon, France), CBM (Orléans, France), University Of Bern (Bern, Switzerland), IKI (Moscow, Russia). This instrument (MicrOmega IR, MicrOmega VIS and the electronics) is selected for the ESA Exomars mission (launch scheduled for 2013). MicrOmega IR will be used in a reduced spectral range (0.9 - 2.6 μm), due to power, mass and thermal constraints: however, most minerals and other

Mars atmosphere studies with the SPICAM IR emission phase function observations

Science.gov (United States)

Trokhimovskiy, Alexander; Fedorova, Anna; Montmessin, Franck; Korablev, Oleg; Bertaux, Jean-Loup

Emission Phase Function (EPF) observations is a powerful tool for characterization of atmosphere and surface. EPF sequence provides the extensive coverage of scattering angles above the targeted surface location which allow to separate the surface and aerosol scattering, study a vertical distribution of minor species and aerosol properties. SPICAM IR instrument on Mars Express mission provides continuous atmospheric observations in near IR (1-1.7 mu) in nadir and limb starting from 2004. For the first years of SPICAM operation only a very limited number of EPFs was performed. But from the mid 2013 (Ls=225, MY31) SPICAM EPF observations become rather regular. Based on the multiple-scattering radiative transfer model SHDOM, we analyze equivalent depths of carbon dioxide (1,43 mu) and water vapour (1,38 mu) absorption bands and their dependence on airmass during observation sequence to get aerosol optical depths and properties. The derived seasonal dust opacities from near IR can be used to retrieve the size distribution from comparison with simultaneous results of other instruments in different spectral ranges. Moreover, the EPF observations of water vapour band allow to access poorly known H2O vertical distribution for different season and locations.

Real-time near-IR imaging of laser-ablation crater evolution in dental enamel

Science.gov (United States)

Darling, Cynthia L.; Fried, Daniel

2007-02-01

We have shown that the enamel of the tooth is almost completely transparent near 1310-nm in the near-infrared and that near-IR (NIR) imaging has considerable potential for the optical discrimination of sound and demineralized tissue and for observing defects in the interior of the tooth. Lasers are now routinely used for many applications in dentistry including the ablation of dental caries. The objective of this study was to test the hypothesis that real-time NIR imaging can be used to monitor laser-ablation under varying conditions to assess peripheral thermal and transient-stress induced damage and to measure the rate and efficiency of ablation. Moreover, NIR imaging may have considerable potential for monitoring the removal of demineralized areas of the tooth during cavity preparations. Sound human tooth sections of approximately 3-mm thickness were irradiated by a CO II laser under varying conditions with and without a water spray. The incision area in the interior of each sample was imaged using a tungsten-halogen lamp with band-pass filter centered at 131--nm combined with an InGaAs focal plane array with a NIR zoom microscope in transillumination. Due to the high transparency of enamel at 1310-nm, laser-incisions were clearly visible to the dentin-enamel junction and crack formation, dehydration and irreversible thermal changes were observed during ablation. This study showed that there is great potential for near-IR imaging to monitor laser-ablation events in real-time to: assess safe laser operating parameters by imaging thermal and stress-induced damage, elaborate the mechanisms involved in ablation such as dehydration, and monitor the removal of demineralized enamel.

Limewashed mural paintings as seen by VIS-IR reflectography

Science.gov (United States)

Fontana, R.; Striova, J.; Barucci, M.; Pampaloni, E.; Raffaelli, M.; Pezzati, L.; Mariotti, P.

2015-06-01

Near-Infrared (NIR) reflectography is a well-established technique for painting diagnostics, offering a fundamental contribution to the conservation of paintings. Since the '80s it has been routinely applied to study the execution technique of the author, as well as the presence of pentimenti, retouches, integrations or underdrawing. In the last decades IR reflectography has been extended to the visible (VIS) spectral range, providing information about the pigment composition. Up to now the multispectral analysis is still applied at an experimental level, as the processing of the image set is not straightforward. Rarely multispectral VIS-IR application has been applied to frescos, probably due to the lack, in most cases, of a scattering background. In this work we present the results provided by a multispectral scanning device based on single sensor acquisition, working in the 380-2500 nm spectral range, that is a laboratory prototype specifically built for research-grade imaging. The technique have been applied on a mock up simulating a mural painting substrate where an underdrawing, made of either carbon or iron-gall ink, was covered by different surface layers of limewash, the so-called scialbo.

Euler deconvolution and spectral analysis of regional aeromagnetic ...

African Journals Online (AJOL)

Existing regional aeromagnetic data from the south-central Zimbabwe craton has been analysed using 3D Euler deconvolution and spectral analysis to obtain quantitative information on the geological units and structures for depth constraints on the geotectonic interpretation of the region. The Euler solution maps confirm ...

Attenuated total reflection design for in situ FT-IR spectroelectrochemical studies

International Nuclear Information System (INIS)

Visser, Hendrik; Curtright, Aimee E.; McCusker, James K.; Sauer, Kenneth

2000-01-01

A versatile spectroelectrochemical apparatus is introduced to study the changes in IR spectra of organic and inorganic compounds upon oxidation or reduction. The design is based on an attenuated total reflection (ATR) device, which permits the study of a wide spectral range of 16,700 cm-1 (600 nm) - 250 cm-1 with a small opaque region of 2250 - 1900 cm-1. In addition, an IR data collection protocol is introduced to deal with electrochemically non-reversible background signals. This method is tested with ferrocene in acetonitrile, producing results that agree with those in the literature

Optical changes of dentin in the near-IR as a function of mineral content

Science.gov (United States)

Berg, Rhett A.; Simon, Jacob C.; Fried, Daniel; Darling, Cynthia L.

2017-02-01

The optical properties of human dentin can change markedly due to aging, friction from opposing teeth, and acute trauma, resulting in the formation of transparent or sclerotic dentin with increased mineral density. The objective of this study was to determine the optical attenuation coefficient of human dentin tissues with different mineral densities in the near-infrared (NIR) spectral regions from 1300-2200 nm using NIR transillumination and optical coherence tomography (OCT). N=50 dentin samples of varying opacities were obtained by sectioning whole extracted teeth into 150 μm transverse sections at the cemento-enamel junction or the apical root. Transillumination images were acquired with a NIR camera and attenuation measurements were acquired at various NIR wavelengths using a NIR sensitive photodiode. Samples were imaged with transverse microradiography (gold standard) in order to determine the mineral density of each sample.

NEAR-IR PHOTOMETRIC PROPERTIES OF HB, MSTO, AND SGB FOR METAL POOR GALACTIC GLOBULAR CLUSTERS

Directory of Open Access Journals (Sweden)

J.-W. Kim

2007-03-01

Full Text Available We report photometric features of the HB, MSTO, and SGB for a set of metal-poor Galactic globular clusters on the near-IR CMDs. The magnitude and color of the MSTO and SGB are measured on the fiducial normal points of the CMDs by applying a polynomial fit. The near-IR luminosity functions of horizontal branch stars in the classical second parameter pair M3 and M13 indicate that HB stars in M13 are dominated by hot stars that are rotatively faint in the infrared, whereas HB stars in M3 are brighter than those in M13. The luminosity functions of HB stars in the observed bulge clusters, except for NGC 6717, show a trend that the fainter hot HB stars are dominated in the relatively metal-poor clusters while the relatively metal-rich clusters contain the brighter HB stars. It is suggestive that NGC 6717 would be an extreme example of the second-parameter phenomenon for the bulge globular clusters.

Properties of poly(vinyl alcohol)–borax gel doped with neodymium ...

Indian Academy of Sciences (India)

visible region then leads to luminescent emission in the near infra-red region. The spectral qualities of the ... molecular hydrogen bonding between the hydroxyl groups on poly(vinyl ..... mately results in near IR emissions. The maximum of the.

Hungaria Asteroid Region Telescopic Spectral Survey (HARTSS): Stony Asteroids Abundant in the Background and Family Populations

Science.gov (United States)

Lucas, Michael P.; Emery, Joshua P.; Pinilla-Alonso, Noemi; Lindsay, Sean S.; Lorenzi, Vania

2016-10-01

The Hungaria region represents a "purgatory" for the closest, preserved samples of the material from which the terrestrial planets accreted. The Hungaria region harbors a collisional family of Xe-type asteroids, which are situated among a background of predominantly S-complex asteroids. Deciphering their surface composition may provide constraints on the nature of the primordial building blocks of the terrestrial planets. We hypothesize that planetesimals in the inner part of the primordial asteroid belt experienced partial- to full-melting and differentiation, the Hungaria region should retain any petrologically-evolved material that formed there.We have undertaken an observational campaign entitled the Hungaria Asteroid Region Telescopic Spectral Survey (HARTSS) to record near-infrared (NIR) spectra to characterize taxonomy, surface mineralogy, and potential meteorite analogs. We used NIR instruments at two ground-based facilities (NASA IRTF; TNG). Our data set includes spectra of 82 Hungaria asteroids (61 background; 21 family), 65 were observed during HARTSS. We compare S-complex background asteroids to calibrations developed via laboratory analyses of ordinary chondrites, and to our analyses (EPMA, XRD, VIS+NIR spectra) of 11 primitive achondrite (acapulcoite-lodranite clan) meteorites.We find that stony S-complex asteroids dominate the Hungaria background population (~80%). Background objects exhibit considerable spectral diversity, when quantified by spectral band parameter measurements, translates to a variety of surface compositions. Two main meteorite groups are represented within the Hungaria background: unmelted, nebular L chondrites (and/or L chondrites), and partially-melted primitive achondrites. H-chondrite mineralogies appear to be absent from the Hungaria background. Xe-type Hungaria family members exhibit spectral homogeneity, consistent with the hypothesis that the family was derived from the disruption of a parent body analogous to an enstatite

Visible, Very Near IR and Short Wave IR Hyperspectral Drone Imaging System for Agriculture and Natural Water Applications

Science.gov (United States)

Saari, H.; Akujärvi, A.; Holmlund, C.; Ojanen, H.; Kaivosoja, J.; Nissinen, A.; Niemeläinen, O.

2017-10-01

The accurate determination of the quality parameters of crops requires a spectral range from 400 nm to 2500 nm (Kawamura et al., 2010, Thenkabail et al., 2002). Presently the hyperspectral imaging systems that cover this wavelength range consist of several separate hyperspectral imagers and the system weight is from 5 to 15 kg. In addition the cost of the Short Wave Infrared (SWIR) cameras is high (  50 k€). VTT has previously developed compact hyperspectral imagers for drones and Cubesats for Visible and Very near Infrared (VNIR) spectral ranges (Saari et al., 2013, Mannila et al., 2013, Näsilä et al., 2016). Recently VTT has started to develop a hyperspectral imaging system that will enable imaging simultaneously in the Visible, VNIR, and SWIR spectral bands. The system can be operated from a drone, on a camera stand, or attached to a tractor. The targeted main applications of the DroneKnowledge hyperspectral system are grass, peas, and cereals. In this paper the characteristics of the built system are shortly described. The system was used for spectral measurements of wheat, several grass species and pea plants fixed to the camera mount in the test fields in Southern Finland and in the green house. The wheat, grass and pea field measurements were also carried out using the system mounted on the tractor. The work is part of the Finnish nationally funded DroneKnowledge - Towards knowledge based export of small UAS remote sensing technology project.

THE ULTRAVIOLET-TO-MID-INFRARED SPECTRAL ENERGY DISTRIBUTION OF WEAK EMISSION LINE QUASARS

International Nuclear Information System (INIS)

Lane, Ryan A.; Shemmer, Ohad; Diamond-Stanic, Aleksandar M.; Fan Xiaohui; Anderson, Scott F.; Brandt, W. N.; Schneider, Donald P.; Plotkin, Richard M.; Richards, Gordon T.; Strauss, Michael A.

2011-01-01

We present Spitzer Space Telescope photometry of 18 Sloan Digital Sky Survey (SDSS) quasars at 2.7 ≤ z ≤ 5.9 which have weak or undetectable high-ionization emission lines in their rest-frame ultraviolet (UV) spectra (hereafter weak-lined quasars, or WLQs). The Spitzer data are combined with SDSS spectra and ground-based, near-infrared (IR) photometry of these sources to produce a large inventory of spectral energy distributions (SEDs) of WLQs across the rest-frame ∼0.1-5 μm spectral band. The SEDs of our sources are inconsistent with those of BL Lacertae objects which are dominated by synchrotron emission due to a jet aligned close to our line of sight, but are consistent with the SED of ordinary quasars with similar luminosities and redshifts that exhibit a near-to-mid-IR 'bump', characteristic of hot dust emission. This indicates that broad emission lines in WLQs are intrinsically weak, rather than suffering continuum dilution from a jet, and that such sources cannot be selected efficiently from traditional photometric surveys.

THE ULTRAVIOLET-TO-MID-INFRARED SPECTRAL ENERGY DISTRIBUTION OF WEAK EMISSION LINE QUASARS

Energy Technology Data Exchange (ETDEWEB)

Lane, Ryan A.; Shemmer, Ohad [Department of Physics, University of North Texas, Denton, TX 76203 (United States); Diamond-Stanic, Aleksandar M. [Center for Astrophysics and Space Sciences, University of California, San Diego, La Jolla, CA 92093 (United States); Fan Xiaohui [Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States); Anderson, Scott F. [Department of Astronomy, University of Washington, Box 351580, Seattle, WA 98195 (United States); Brandt, W. N.; Schneider, Donald P. [Department of Astronomy and Astrophysics, The Pennsylvania State University, University Park, PA 16802 (United States); Plotkin, Richard M. [Astronomical Institute ' Anton Pannekoek' , University of Amsterdam, Science Park 904, NL-1098 XH Amsterdam (Netherlands); Richards, Gordon T. [Department of Physics, Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104 (United States); Strauss, Michael A., E-mail: RyanLane@my.unt.edu, E-mail: ohad@unt.edu [Princeton University Observatory, Peyton Hall, Princeton, NJ 08544 (United States)

2011-12-20

We present Spitzer Space Telescope photometry of 18 Sloan Digital Sky Survey (SDSS) quasars at 2.7 {<=} z {<=} 5.9 which have weak or undetectable high-ionization emission lines in their rest-frame ultraviolet (UV) spectra (hereafter weak-lined quasars, or WLQs). The Spitzer data are combined with SDSS spectra and ground-based, near-infrared (IR) photometry of these sources to produce a large inventory of spectral energy distributions (SEDs) of WLQs across the rest-frame {approx}0.1-5 {mu}m spectral band. The SEDs of our sources are inconsistent with those of BL Lacertae objects which are dominated by synchrotron emission due to a jet aligned close to our line of sight, but are consistent with the SED of ordinary quasars with similar luminosities and redshifts that exhibit a near-to-mid-IR 'bump', characteristic of hot dust emission. This indicates that broad emission lines in WLQs are intrinsically weak, rather than suffering continuum dilution from a jet, and that such sources cannot be selected efficiently from traditional photometric surveys.

The near-infrared radius-luminosity relationship for active galactic nuclei

Science.gov (United States)

Landt, Hermine; Bentz, Misty C.; Peterson, Bradley M.; Elvis, Martin; Ward, Martin J.; Korista, Kirk T.; Karovska, Margarita

2011-05-01

Black hole masses for samples of active galactic nuclei (AGNs) are currently estimated from single-epoch optical spectra. In particular, the size of the broad-line emitting region needed to compute the black hole mass is derived from the optical or ultraviolet continuum luminosity. Here we consider the relationship between the broad-line region size, R, and the near-infrared (near-IR) AGN continuum luminosity, L, as the near-IR continuum suffers less dust extinction than at shorter wavelengths and the prospects for separating the AGN continuum from host-galaxy starlight are better in the near-IR than in the optical. For a relationship of the form R∝Lα, we obtain for a sample of 14 reverberation-mapped AGN a best-fitting slope of α= 0.5 ± 0.1, which is consistent with the slope of the relationship in the optical band and with the value of 0.5 naïvely expected from photoionization theory. Black hole masses can then be estimated from the near-IR virial product, which is calculated using the strong and unblended Paschen broad emission lines (Paα or Paβ).

Near-Field Spectral Effects due to Electromagnetic Surface Excitations

OpenAIRE

Shchegrov , Andrei ,; Joulain , Karl; Carminati , Rémi; Greffet , Jean-Jacques

2000-01-01

International audience; We demonstrate theoretically that the spectra of electromagnetic emission of surface systems can display remarkable differences in the near and the far zones. The spectral changes occur due to the loss of evanescent modes and are especially pronounced for systems which support surface waves. PACS numbers: 78.20. – e, 05.40. – a, 44.40. + a, 87.64.Xx Spectroscopy of electromagnetic radiation is perhaps the most powerful exploration tool employed in natural sciences: ast...

NEAR: Low-mass Planets in α Cen with VISIR

Science.gov (United States)

Kasper, M.; Arsenault, R.; Käufl, H.-U.; Jakob, G.; Fuenteseca, E.; Riquelme, M.; Siebenmorgen, R.; Sterzik, M.; Zins, G.; Ageorges, N.; Gutruf, S.; Reutlinger, A.; Kampf, D.; Absil, O.; Carlomagno, B.; Guyon, O.; Klupar, P.; Mawet, D.; Ruane, G.; Karlsson, M.; Pantin, E.; Dohlen, K.

2017-09-01

ESO, in collaboration with the Breakthrough Initiatives, is working to modify the Very Large Telescope mid-IR imager (VISIR) to greatly enhance its ability to search for potentially habitable planets around both components of the binary Alpha Centauri, part of the closest stellar system to the Earth. Much of the funding for the NEAR (New Earths in the Alpha Cen Region) project is provided by the Breakthrough Initiatives, and ESO mostly provides staff and observing time. The concept combines adaptive optics using the deformable secondary mirror at Unit Telescope 4, a new annular groove phase mask (AGPM) coronagraph optimised for the most sensitive spectral bandpass in the N-band, and a novel internal chopper system for noise filtering based on a concept for longer wavelengths invented by the microwave pioneer Robert Dicke. The NEAR experiment is relevant to the mid-infrared METIS instrument on the Extremely Large Telescope, as the knowledge gained and proof of concept will be transferable.

Mineralogy and Thermal Properties of V-Type Asteroid 956 Elisa: Evidence for Diogenitic Material from the Spitzer IRS (5-35 Micrometers) Spectrum

Science.gov (United States)

Lim, Lucy F.; Emery, Joshua P.; Moskovitz, Nicholas A.

2010-01-01

We present the thermal infrared (5-35 micrometer) spectrum of 956 Elisa as measured by the Spitzer Infrared Spectrograph ("IRS"; Houck,1.R. et .11. [20041. Astrophys, 1. SuppL 154, 18-24) together with new ground-based lightcurve data and near-IR spectra. From the visible lightcurve photometry, we determine a rotation period of 16.494 +/- 0.001 h, identify the rotational phase of the Spitzer observations, and estimate the visible absolute magnitude (Hv) at that rotational phase to be 12.58 +/- 0.04. From radiometric analysis of the thermal flux spectrum, we find that at the time of observation 956 Elisa had a projected radius of 5.3 +/- 0.4 km with a visible albedo pv = 0.142+/- 0.022, significantly lower than that of the prototype V-type asteroid, 4 Vesta. (This corresponds to a radius of 5.2 +/- 0.4 km at lightcurve mean.) Analysis with the standard thermal model (STM) results in a sub-solar temperature of 292.3 +/- 2.8 K and beaming parameter eta = 1.16 +/- 0.05. Thermophysical modeling places a lower limit of 20 J m(exp -2)K(exp -1)s(exp -1/2) on the thermal inertia of the asteroid's surface layer (if the surface is very smooth) but more likely values fall between 30 and 150 J m(exp -2)K(exp -1)s(exp -1/2) depending on the sense of rotation. The emissivity spectrum, calculated by dividing the measured thermal flux spectrum by the modeled thermal continuum, exhibits mineralogically interpretable spectral features within the 9-12 micrometer reststrahlen band, the 15-16.5 micrometer Si-O-Si stretching region, and the 16-25 micrometer reststrahlen region that are consistent with pyroxene of diogenitic composition: extant diogenitic pyroxenes fall within the narrow compositional range W0(sub 2+/-1)En(sub 74+/-2)Fs(sub 24+/-1). Spectral deconvolution of the 9-12 micrometer reststrahlen features indicates that up to approximately 20% olivine may also be present, suggesting an olivine-diogenite-like mineralogy. The mid-IR spectrum is inconsistent with non

Near-fault earthquake ground motion prediction by a high-performance spectral element numerical code

International Nuclear Information System (INIS)

Paolucci, Roberto; Stupazzini, Marco

2008-01-01

Near-fault effects have been widely recognised to produce specific features of earthquake ground motion, that cannot be reliably predicted by 1D seismic wave propagation modelling, used as a standard in engineering applications. These features may have a relevant impact on the structural response, especially in the nonlinear range, that is hard to predict and to be put in a design format, due to the scarcity of significant earthquake records and of reliable numerical simulations. In this contribution a pilot study is presented for the evaluation of seismic ground-motions in the near-fault region, based on a high-performance numerical code for 3D seismic wave propagation analyses, including the seismic fault, the wave propagation path and the near-surface geological or topographical irregularity. For this purpose, the software package GeoELSE is adopted, based on the spectral element method. The set-up of the numerical benchmark of 3D ground motion simulation in the valley of Grenoble (French Alps) is chosen to study the effect of the complex interaction between basin geometry and radiation mechanism on the variability of earthquake ground motion

Polarized BRDF measurement of steel E235B in the near-infrared region: Based on a self-designed instrument with absolute measuring method

Science.gov (United States)

Liu, Yanlei; Yu, Kun; Liu, Zilong; Zhao, Yuejin; Liu, Yufang

2018-06-01

The spectral bidirectional reflectance distribution (BRDF) offers a complete description of the optical properties of the opaque material. Numerous studies on BRDF have been conducted for its important role in scientific research and industrial production. However, most of these studies focus on the visible region and unpolarized BRDF, and the spectral polarized BRDF in the near-infrared region is rarely reported. In this letter, we propose an absolute method to measure the spectral BRDF in the near-infrared region, and the detailed derivation is presented. A self-designed instrument is set up for the absolute measurement of BRDF. The reliability of this method is verified by comparing the experimental data of the three metal (aluminum, silver and gold) mirrors with the reference data. The in-plane polarized BRDF of steel E235B are measured, and the influence of incident angle and roughness on the BRDF are discussed. The degree of linear polarization (DOLP) are determined based on the polarized BRDF. The results indicate that both the roughness and incident angle have distinct influence on the BRDF and DOLP.

The W40 region in the gould belt: An embedded cluster and H II region at the junction of filaments

Energy Technology Data Exchange (ETDEWEB)

Mallick, K. K.; Ojha, D. K. [Department of Astronomy and Astrophysics, Tata Institute of Fundamental Research, Homi Bhabha Road, Colaba, Mumbai 400005 (India); Kumar, M. S. N. [Centro de Astrofísica da Universidade do Porto, Rua das Estrelas, 4150-762 s/n Porto (Portugal); Bachiller, Rafael [Observatorio Astronómico Nacional (IGN), Alfonso XII 3, E-28014 Madrid (Spain); Samal, M. R. [Aix Marseille Université, CNRS, LAM (Laboratoire d' Astrophysique de Marseille), UMR 7326, F-13388 Marseille (France); Pirogov, L., E-mail: kshitiz@tifr.res.in [Institute of Applied Physics, Russian Academy of Sciences, 46 Uljanov str., Nizhny Novgorod 603950 (Russian Federation)

2013-12-20

We present a multiwavelength study of the W40 star-forming region using infrared (IR) observations in the UKIRT JHK bands, Spitzer Infrared Array Camera bands, and Herschel PACS bands, 2.12 μm H{sub 2} narrowband imaging, and radio continuum observations from GMRT (610 and 1280 MHz), in a field of view (FoV) of ∼34' × 40'. Archival Spitzer observations in conjunction with near-IR observations are used to identify 1162 Class II/III and 40 Class I sources in the FoV. The nearest-neighbor stellar surface density analysis shows that the majority of these young stellar objects (YSOs) constitute the embedded cluster centered on the high-mass source IRS 1A South. Some YSOs, predominantly the younger population, are distributed along and trace the filamentary structures at lower stellar surface density. The cluster radius is measured to be 0.44 pc—matching well with the extent of radio emission—with a peak density of 650 pc{sup –2}. The JHK data are used to map the extinction in the region, which is subsequently used to compute the cloud mass—126 M {sub ☉} and 71 M {sub ☉} for the central cluster and the northern IRS 5 region, respectively. H{sub 2} narrowband imaging shows significant emission, which prominently resembles fluorescent emission arising at the borders of dense regions. Radio continuum analysis shows that this region has a blister morphology, with the radio peak coinciding with a protostellar source. Free-free emission spectral energy distribution analysis is used to obtain physical parameters of the overall photoionized region and the IRS 5 sub-region. This multiwavelength scenario is suggestive of star formation having resulted from the merging of multiple filaments to form a hub. Star formation seems to have taken place in two successive epochs, with the first epoch traced by the central cluster and the high-mass star(s)—followed by a second epoch that is spreading into the filaments as uncovered by the Class I sources and even

F region electron density irregularity spectra near Auroral acceleration and shear regions

International Nuclear Information System (INIS)

Basu, S.; Basu, S.; MacKenzie, E.; Coley, W.R.; Hanson, W.B.; Lin, C.S.

1984-01-01

Spectral characteristics of auroral F region irregularities were studied by the use of high-resolution (approx.35 m) density measurements made by the retarding potential analyzer (RPA) on board the Atmosphere Explorer D (AE-D) satellite during two orbits when the satellite was traversing the high-latitude ionosphere in the evening sector. Coordinated DMSP passes provided synoptic coverage of auroral activity. The auroral energy input was estimated by intergrating the low-energy electron (LEE) data on AE-D. It was found that the one-dimensional in situ spectral index (p 1 ) of the irregularities at scale lengths of 1 values of approx.-3. This is interpreted as resulting from the effects of E region conductivity on the F region irregularity structure. The regions in between the precipitation structures, where presumably the E region conductivity was small, were generally associated with large shears in the horizontal E-W drifts and large velocities, as measured by the ion drift meter on board AE-D. The maximum drifts measured were approx.2 km s -1 , corresponding to an electric field of 100 mV m -1 . The large-velocity regions were also associated with substantial ion heating and electron density depletions. The largest shear magnitudes observed were approx.80 m s -1 km -1 , and the shear gradient scale lengths were approx.10 km, which was approximately the resolution of the ion drift meter data set used. The spectral characteristics of irregularities in the large, variable flow regions were very different, with p 1 being approx.-1

Study of Shortwave Spectra in Fully 3D Environment: Synergy Between Scanning Radars and Spectral Radiation Measurements

Science.gov (United States)

Wiscombe, Warren J.

2012-01-01

The main theme for our research is the understanding and closure of the surface spectral shortwave radiation problem in fully 3D cloud situations by combining the new ARM scanning radars, shortwave spectrometers, and microwave radiometers with the arsenal of radiative transfer tools developed by our group. In particular, we define first a large number of cloudy test cases spanning all 3D possibilities not just the customary uniform-overcast ones. Second, for each case, we define a "Best Estimate of Clouds That Affect Shortwave Radiation" using all relevant ARM instruments, notably the new scanning radars, and contribute this to the ARM Archive. Third, we test the ASR-signature radiative transfer model RRTMG_SW for those cases, focusing on the near-IR because of long-standing problems in this spectral region, and work with the developers to improve RRTMG_SW in order to increase its penetration into the modeling community.

A TALE OF TWO NARROW-LINE REGIONS: IONIZATION, KINEMATICS, AND SPECTRAL ENERGY DISTRIBUTIONS FOR A LOCAL PAIR OF MERGING OBSCURED ACTIVE GALAXIES

Energy Technology Data Exchange (ETDEWEB)

Hainline, Kevin N.; Hickox, Ryan C.; Chen, Chien-Ting; Carroll, Christopher M.; Jones, Mackenzie L.; Zervos, Alexandros S. [Department of Physics and Astronomy, Dartmouth College, Hanover, NH 03755 (United States); Goulding, Andrew D. [Department Astrophysical Sciences, Princeton University, Princeton, NJ 08544 (United States)

2016-05-20

We explore the gas ionization and kinematics, as well as the optical-IR spectral energy distributions for UGC 11185, a nearby pair of merging galaxies hosting obscured active galactic nuclei (AGNs), also known as SDSS J181611.72+423941.6 and J181609.37+423923.0 (J1816NE and J1816SW, z ≈ 0.04). Due to the wide separation between these interacting galaxies (∼23 kpc), observations of these objects provide a rare glimpse of the concurrent growth of supermassive black holes at an early merger stage. We use BPT line diagnostics to show that the full extent of the narrow-line emission in both galaxies is photoionized by an AGN, and confirm the existence of a 10 kpc-scale ionization cone in J1816NE, while in J1816SW the AGN narrow-line region is much more compact (1–2 kpc) and relatively undisturbed. Our observations also reveal the presence of ionized gas that nearly spans the entire distance between the galaxies, which is likely in a merger-induced tidal stream. In addition, we carry out a spectral analysis of the X-ray emission using data from XMM-Newton . These galaxies represent a useful pair to explore how the [O iii] luminosity of an AGN is dependent on the size of the region used to explore the extended emission. Given the growing evidence for AGN “flickering” over short timescales, we speculate that the appearances and impacts of these AGNs may change multiple times over the course of the galaxy merger, which is especially important given that these objects are likely the progenitors of the types of systems commonly classified as “dual AGNs.”.

Retrieval of Surface Lambert Albedos and Aerosols Optical Depths Using OMEGA Near-IR EPF Observations of Mars

Science.gov (United States)

Vincendon, M.; Langevin, Y.; Poulet, F.; Bibring, J.-P.; Gondet, B.

2007-03-01

We have analyzed five EPF sequences acquired by OMEGA/Mars Express in the near-IR over ice-free and ice-covered surfaces to retrieve simultaneously the Lambert albedo of the surface and the optical depth of aerosols.

The early phases of galaxy clusters formation in IR: coupling hydrodynamical simulations with GRASIL-3D

Science.gov (United States)

Granato, Gian Luigi; Ragone-Figueroa, Cinthia; Domínguez-Tenreiro, Rosa; Obreja, Aura; Borgani, Stefano; De Lucia, Gabriella; Murante, Giuseppe

2015-06-01

We compute and study the infrared and sub-mm properties of high-redshift (z ≳ 1) simulated clusters and protoclusters. The results of a large set of hydrodynamical zoom-in simulations including active galactic nuclei (AGN) feedback, have been treated with the recently developed radiative transfer code GRASIL-3D, which accounts for the effect of dust reprocessing in an arbitrary geometry. Here, we have slightly generalized the code to adapt it to the present purpose. Then we have post-processed boxes of physical size 2 Mpc encompassing each of the 24 most massive clusters identified at z = 0, at several redshifts between 0.5 and 3, producing IR and sub-mm mock images of these regions and spectral energy distributions (SEDs) of the radiation coming out from them. While this field is in its infancy from the observational point of view, rapid development is expected in the near future thanks to observations performed in the far-IR and sub-mm bands. Notably, we find that in this spectral regime our prediction are little affected by the assumption required by this post-processing, and the emission is mostly powered by star formation (SF) rather than accretion on to super massive black hole (SMBH). The comparison with the little observational information currently available, highlights that the simulated cluster regions never attain the impressive star formation rates suggested by these observations. This problem becomes more intriguing taking into account that the brightest cluster galaxies (BCGs) in the same simulations turn out to be too massive. It seems that the interplay between the feedback schemes and the star formation model should be revised, possibly incorporating a positive feedback mode.

Spectral classification by the near infrared photometric parameters

International Nuclear Information System (INIS)

Tignanelli, H.L.; Feinstein, A.

1985-01-01

From the analysis of the measurements of KM-type stars done in the near infrared (1 to 3.5 microns: the JHKL bands of Johnsons's system), with an 83 cm reflector and a PbS detector at La Plata Observatory, we try to establish a new photometric classification system that discriminates luminosity class by means of certain parameters defined by infrared colours and infrared magnitudes. Data compiled and homogenized by J.Koornneef of southern bright stars in those bands were also included. The results give us information about the spectral types and reddening of those stars. We also indicate how to calculate the radiation excess that those stars could have. (author)

Effect of H+ implantation on the optical properties of semi-insulating GaAs crystals in the IR spectral region

International Nuclear Information System (INIS)

Klyui, N. I.; Lozinskii, V. B.; Liptuga, A. I.; Dikusha, V. N.; Oksanych, A. P.; Kogdas’, M. G.; Perekhrest, A. L.; Pritchin, S. E.

2017-01-01

The optical properties of semi-insulating GaAs crystals subjected to multienergy hydrogen-ion implantation and treatment in a high-frequency electromagnetic field are studied in the infrared spectral region. It is established that such combined treatment provides a means for substantially increasing the transmittance of GaAs crystals to values characteristic of crystals of high optical quality. On the basis of analysis of the infrared transmittance and reflectance data, Raman spectroscopy data, and atomic-force microscopy data on the surface morphology of the crystals, a physical model is proposed to interpret the effects experimentally observed in the crystals. The model takes into account the interaction of radiation defects with the initial structural defects in the crystals as well as the effect of compensation of defect centers by hydrogen during high-frequency treatment.

Near-infrared metallicities, radial velocities, and spectral types for 447 nearby M dwarfs

Energy Technology Data Exchange (ETDEWEB)

Newton, Elisabeth R.; Charbonneau, David; Irwin, Jonathan; Berta-Thompson, Zachory K. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Rojas-Ayala, Barbara [Centro de Astrofsica, Universidade do Porto, Rua das Estrelas, 4150-762 Porto (Portugal); Covey, Kevin [Lowell Observatory, 1400 West Mars Hill Road, Flagstaff, AZ 86001 (United States); Lloyd, James P., E-mail: enewton@cfa.harvard.edu [Department of Astronomy, Cornell University, 226 Space Sciences Building, Ithaca, NY 14853 (United States)

2014-01-01

We present metallicities, radial velocities, and near-infrared (NIR) spectral types for 447 M dwarfs determined from moderate resolution (R ≈ 2000) NIR spectra obtained with the NASA Infrared Telescope Facility (IRTF)/SpeX. These M dwarfs are primarily targets of the MEarth Survey, a transiting planet survey searching for super Earths around mid-to-late M dwarfs within 33 pc. We present NIR spectral types for each star and new spectral templates for the IRTF in the Y, J, H, and K-bands, created using M dwarfs with near-solar metallicities. We developed two spectroscopic distance calibrations that use NIR spectral type or an index based on the curvature of the K-band continuum. Our distance calibration has a scatter of 14%. We searched 27 NIR spectral lines and 10 spectral indices for metallicity sensitive features, taking into account correlated noise in our estimates of the errors on these parameters. We calibrated our relation using 36 M dwarfs in common proper pairs with an F-, G-, or K-type star of known metallicity. We validated the physical association of these pairs using proper motions, radial velocities, and spectroscopic distance estimates. Our resulting metallicity calibration uses the sodium doublet at 2.2 μm as the sole indicator for metallicity. It has an accuracy of 0.12 dex inferred from the scatter between the metallicities of the primaries and the estimated metallicities of the secondaries. Our relation is valid for NIR spectral types from M1V to M5V and for –1.0 dex < [Fe/H] < +0.35 dex. We present a new color-color metallicity relation using J – H and J – K colors that directly relates two observables: the distance from the M dwarf main sequence and equivalent width of the sodium line at 2.2 μm. We used radial velocities of M dwarf binaries, observations at different epochs, and comparison between our measurements and precisely measured radial velocities to demonstrate a 4 km s{sup –1} accuracy.

Upconversion applied for mid-IR hyperspectral image acquisition

DEFF Research Database (Denmark)

Tidemand-Lichtenberg, Peter; Kehlet, Louis Martinus; Sanders, Nicolai Højer

2015-01-01

Different schemes for upconversion mid-IR hyperspectral imaging is implemented and compared in terms of spectral coverage, spectral resolution, speed and noise. Phasematch scanning and scanning of the object within the field of view is considered....

Visible and Near-IR Reflectance Spectra of Smectite Acquired Under Dry Conditions for Interpretation of Martian Surface Mineralogy

Science.gov (United States)

Morris, Richard V.; Achilles, Cherie N; Archer, Paul D.; Graff, Trevor G.; Agresti, David G.; Ming, Douglas W; Golden, Dadi C.; Mertzman, Stanley A.

2011-01-01

Visible and near-IR (VNIR) spectra from the MEx OMEGA and the MRO CRISM hyper-spectral imaging instruments have spectral features associated with the H2O molecule and M OH functional groups (M = Mg, Fe, Al, and Si). Mineralogical assignments of martian spectral features are made on the basis of laboratory VNIR spectra, which were often acquired under ambient (humid) conditions. Smectites like nontronite, saponite, and montmorillionite have interlayer H2O that is exchangeable with their environment, and we have acquired smectite reflectance spectra under dry environmental conditions for interpretation of martian surface mineralogy. We also obtained chemical, Moessbauer (MB), powder X-ray diffraction (XRD), and thermogravimetric (TG) data to understand variations in spectral properties. VNIR spectra were recorded in humid lab air at 25-35C, in a dynamic dry N2 atmosphere (50-150 ppmv H2O) after exposing the smectite samples (5 nontronites, 3 montmorillionites, and 1 saponite) to that atmosphere for up to approximately l000 hr each at 25-35C, approximately 105C, and approximately 215C, and after re-exposure to humid lab air. Heating at 105C and 215C for approximately 1000 hr is taken as a surrogate for geologic time scales at lower temperatures. Upon exposure to dry N2, the position and intensity of spectral features associated with M-OH were relatively insensitive to the dry environment, and the spectral features associated with H2O (e.g., approximately 1.90 micrometers) decreased in intensity and are sometimes not detectable by the end of the 215C heating step. The position and intensity of H2O spectral features recovered upon re-exposure to lab air. XRD data show interlayer collapse for the nontronites and Namontmorillionites, with the interlayer remaining collapsed for the latter after re-exposure to lab air. The interlayer did not collapse for the saponite and Ca-montmorillionite. TG data show that the concentration of H2O derived from structural OH was invariant

THE RADIO-2 mm SPECTRAL INDEX OF THE CRAB NEBULA MEASURED WITH GISMO

International Nuclear Information System (INIS)

Arendt, R. G.; George, J. V.; Staguhn, J. G.; Benford, D. J.; Fixsen, D. J.; Maher, S. F.; Moseley, S. H.; Sharp, E.; Wollack, E. J.; Devlin, M. J.; Dicker, S. R.; Korngut, P. M.; Irwin, K. D.; Jhabvala, C. A.; Miller, T. M.; Kovacs, A.; Mason, B. S.; Navarro, S.; Sievers, A.; Sievers, J. L.

2011-01-01

We present results of 2 mm observations of the Crab Nebula, obtained using the Goddard-IRAM Superconducting 2 Millimeter Observer (GISMO) bolometer camera on the IRAM 30 m telescope. Additional 3.3 mm observations with the MUSTANG bolometer array on the Green Bank Telescope are also presented. The integrated 2 mm flux density of the Crab Nebula provides no evidence for the emergence of a second synchrotron component that has been proposed. It is consistent with the radio power-law spectrum, extrapolated up to a break frequency of log (ν b [GHz]) = 2.84 ± 0.29 or ν b = 695 +651 -336 GHz. The Crab Nebula is well resolved by the ∼16.''7 beam (FWHM) of GISMO. Comparison to radio data at comparable spatial resolution enables us to confirm significant spatial variation of the spectral index between 21 cm and 2 mm. The main effect is a spectral flattening in the inner region of the Crab Nebula, correlated with the toroidal structure at the center of the nebula that is prominent in the near-IR through X-ray regime.

Spectral relationships for atmospheric correction. I. Validation of red and near infra-red marine reflectance relationships.

Science.gov (United States)

Goyens, C; Jamet, C; Ruddick, K G

2013-09-09

The present study provides an extensive overview of red and near infra-red (NIR) spectral relationships found in the literature and used to constrain red or NIR-modeling schemes in current atmospheric correction (AC) algorithms with the aim to improve water-leaving reflectance retrievals, ρw(λ), in turbid waters. However, most of these spectral relationships have been developed with restricted datasets and, subsequently, may not be globally valid, explaining the need of an accurate validation exercise. Spectral relationships are validated here with turbid in situ data for ρw(λ). Functions estimating ρw(λ) in the red were only valid for moderately turbid waters (ρw(λNIR) turbidity ranges presented in the in situ dataset. In the NIR region of the spectrum, the constant NIR reflectance ratio suggested by Ruddick et al. (2006) (Limnol. Oceanogr. 51, 1167-1179), was valid for moderately to very turbid waters (ρw(λNIR) turbid waters (ρw(λNIR) > 10(-2)). The results of this study suggest to use the red bounding equations and the polynomial NIR function to constrain red or NIR-modeling schemes in AC processes with the aim to improve ρw(λ) retrievals where current AC algorithms fail.

Parametric Explosion Spectral Model

Energy Technology Data Exchange (ETDEWEB)

Ford, S R; Walter, W R

2012-01-19

Small underground nuclear explosions need to be confidently detected, identified, and characterized in regions of the world where they have never before occurred. We develop a parametric model of the nuclear explosion seismic source spectrum derived from regional phases that is compatible with earthquake-based geometrical spreading and attenuation. Earthquake spectra are fit with a generalized version of the Brune spectrum, which is a three-parameter model that describes the long-period level, corner-frequency, and spectral slope at high-frequencies. Explosion spectra can be fit with similar spectral models whose parameters are then correlated with near-source geology and containment conditions. We observe a correlation of high gas-porosity (low-strength) with increased spectral slope. The relationship between the parametric equations and the geologic and containment conditions will assist in our physical understanding of the nuclear explosion source.

Fiber optic lasers with emission to the region 2-3 μm of IR medium

International Nuclear Information System (INIS)

Anzuelo Sanchez, G.; Osuna Galan, I.; Camas Anzueto, J.; Martinez Rios, A.; Selvas Aguilar, R.

2009-01-01

We present recent advances in laser emission in the 2-2-5 μm mid-IR, using a chalcogenide fiber with low loss and a high Raman gain in the region 2-10 μm. We present a review of fiber lasers operating in 2-3 μm of the mid IR. (Author)

THE FAST DECLINING TYPE Ia SUPERNOVA 2003gs, AND EVIDENCE FOR A SIGNIFICANT DISPERSION IN NEAR-INFRARED ABSOLUTE MAGNITUDES OF FAST DECLINERS AT MAXIMUM LIGHT

International Nuclear Information System (INIS)

Krisciunas, Kevin; Marion, G. H.; Suntzeff, Nicholas B.

2009-01-01

We obtained optical photometry of SN 2003gs on 49 nights, from 2 to 494 days after T(B max ). We also obtained near-IR photometry on 21 nights. SN 2003gs was the first fast declining Type Ia SN that has been well observed since SN 1999by. While it was subluminous in optical bands compared to more slowly declining Type Ia SNe, it was not subluminous at maximum light in the near-IR bands. There appears to be a bimodal distribution in the near-IR absolute magnitudes of Type Ia SNe at maximum light. Those that peak in the near-IR after T(B max ) are subluminous in the all bands. Those that peak in the near-IR prior to T(B max ), such as SN 2003gs, have effectively the same near-IR absolute magnitudes at maximum light regardless of the decline rate Δm 15 (B). Near-IR spectral evidence suggests that opacities in the outer layers of SN 2003gs are reduced much earlier than for normal Type Ia SNe. That may allow γ rays that power the luminosity to escape more rapidly and accelerate the decline rate. This conclusion is consistent with the photometric behavior of SN 2003gs in the IR, which indicates a faster than normal decline from approximately normal peak brightness.

A near-UV-converted LiMgBO3:Dy3+ nanophosphor: Surface and spectral investigations

International Nuclear Information System (INIS)

Bedyal, A.K.; Kumar, Vinay; Prakash, Ram; Ntwaeaborwa, O.M.; Swart, H.C.

2015-01-01

Graphical abstract: - Highlights: • Combustion method was employed to synthesize LiMgBO 3 :Dy 3+ nanophosphors. • The phosphor can be efficiently excited by near-UV chips. • XPS was done to investigate the chemical constitution and chemical bonding state of elements in the LiMgBO 3 : Dy 3+ nanophosphor. • The calculated CIE coordinates (0.45, 0.46) were found to be in the white spectrum region. - Abstract: A near-ultra violet (UV) converted LiMgBO 3 :Dy 3+ nanophosphors have been synthesized by the combustion method. The structural, spectral and optical properties were examined by powder X-ray diffraction, fluorescent spectrophotometry and UV–vis spectroscopy. The excitation spectra of the phosphors contain sharp peaks at 294, 323, 348 and 385 nm due to the 4f–4f transition of the Dy 3+ ion. The phosphor is efficiently excited by near-UV chips. Upon near-UV excitation the phosphor emits intense blue and yellow with a weak red band centered at 484, 573 and 669 nm respectively, ascribed to the transition of Dy 3+ ion from 4 F 9/2 → 6 H 15/2 , 6 H 13/2 , 6 H 11/2 . The diffuse reflectance spectra of the phosphors were consistent with the excitation spectra and were used to calculate the band gap of the material, approximated to be 5.4 eV. The calculated CIE coordinates (0.45, 0.46) under 348 nm excitation were found to be in the white spectrum region. For surface investigation, X-ray photoelectron spectroscopy was used which confirms the presence of all the elements on the surface of the material

Near infrared spectral imaging of explosives using a tunable laser source

Energy Technology Data Exchange (ETDEWEB)

Klunder, G L; Margalith, E; Nguyen, L K

2010-03-26

Diffuse reflectance near infrared hyperspectral imaging is an important analytical tool for a wide variety of industries, including agriculture consumer products, chemical and pharmaceutical development and production. Using this technique as a method for the standoff detection of explosive particles is presented and discussed. The detection of the particles is based on the diffuse reflectance of light from the particle in the near infrared wavelength range where CH, NH, OH vibrational overtones and combination bands are prominent. The imaging system is a NIR focal plane array camera with a tunable OPO/laser system as the illumination source. The OPO is programmed to scan over a wide spectral range in the NIR and the camera is synchronized to record the light reflected from the target for each wavelength. The spectral resolution of this system is significantly higher than that of hyperspectral systems that incorporate filters or dispersive elements. The data acquisition is very fast and the entire hyperspectral cube can be collected in seconds. A comparison of data collected with the OPO system to data obtained with a broadband light source with LCTF filters is presented.

Spectral Signature of Radiative Forcing by East Asian Dust-Soot Mixture

Science.gov (United States)

Zhu, A.; Ramanathan, V.

2007-12-01

The Pacific Dust Experiment (PACDEX) provides the first detailed sampling of dust-soot mixtures from the western Pacific to the eastern Pacific Ocean. The data includes down and up spectral irradiance, mixing state of dust and soot, and other aerosol properties. This study attempts to simulate the radiative forcing by dust-soot mixtures during the experimental period. The MODTRAN band model was employed to investigate the spectral signatures of solar irradiance change induced by aerosols at moderate spectral resolutions. For the short wave band (300-1100nm) used in this study, the reduction of downward irradiance at surface by aerosols greatly enhances with increasing wavelength in the UV band (300-400nm), reaches a maximum in the blue band, then gradually decreases toward the red band. In the near-IR band (700-1100nm), irradiance reduction by aerosols shows great fluctuations in the band with center wavelength at around 940nm, 820nm, 720nm, 760nm, 690nm, where the aerosol effect is overwhelmed by the water vapor and O2 absorptions. The spectral pattern of irradiance reduction varies for different aerosol species. The maximum reduction lies at around 450nm for soot, and shifting to about 490nm for East Asian mineral dust. It's worth noting that although soot aerosols reduce more irradiance than East Asian dust in the UV and blue band, the impact of dust to the irradiance exceeds that by soot at the longer wavelength band (i.e. around 550nm). The reduction of irradiance by East Asian dust (soot) in the UV band, visible band, and near-IR accounts for about 6% (10%), 56% (64%), and 38% (26%) of total irradiance reduction. As large amount of soot aerosols are involved during the long range transport of East Asian dust, the optical properties of dust aerosols are modified with different mixing state with soot, the spectral pattern of the irradiance reduction will be changed. The study of aerosol forcing at moderate spectral resolutions has the potential application for

Doubly and triply linked porphyrin-perylene monoimides as near IR dyes with large dipole moments and high photostability

KAUST Repository

Jiao, Chongjun; Huang, Kuo-Wei; Chi, Chunyan; Wu, Jishan

2011-01-01

Doubly and triply linked porphyrin-perylene monoimides 3 and 4, with extraordinary stability, large dipole moments, and strong near IR absorption, were prepared by means of one-pot oxidative cyclodehydrogenation promoted by FeCl 3. © 2010 American

Red-Shift Effects in Surface Enhanced Raman Spectroscopy: Spectral or Intensity Dependence of the Near-Field?

KAUST Repository

Colas, Florent; Cottat, Maximilien; Gillibert, Raymond; Guillot, Nicolas; Djaker, Nadia; Lidgi-Guigui, Nathalie; Toury, Timothé e; Barchiesi, Dominique; Toma, Andrea; Di Fabrizio, Enzo M.; Gucciardi, Pietro Giuseppe; de la Chapelle, Marc Lamy

2016-01-01

Optimum amplification in Surface Enhanced Raman Scattering (SERS) from individual nanoantennas is expected when the excitation is slightly blue-shifted with respect to the Localized Surface Plasmon Resonance (LSPR), so that the LSPR peak falls in the middle between the laser and the Stokes Raman emission. Recent experiments have shown when moving the excitation from the visible to the near-infrared that this rule of thumb is no more valid. The excitation has to be red-shifted with respect to the LSPR peak, up to 80nm, to obtain highest SERS. Such discrepancy is usually attributed to a Near-Field (NF) to Far-Field (FF) spectral shift. Here we critically discuss this hypothesis for the case of gold nanocylinders. By combining multi-wavelength excitation SERS experiments with numerical calculations, we show that the red-shift of the excitation energy does not originate from a spectral shift between the extinction (FF) and the near-field distribution (NF), which is found to be not larger than 10nm. Rather, it can be accounted for by looking at the peculiar spectral dependence of the near-field intensity on the cylinders diameter, characterized by an initial increase, up to 180nm diameter, followed by a decrease and a pronounced skewness.

Red-Shift Effects in Surface Enhanced Raman Spectroscopy: Spectral or Intensity Dependence of the Near-Field?

KAUST Repository

Colas, Florent

2016-06-06

Optimum amplification in Surface Enhanced Raman Scattering (SERS) from individual nanoantennas is expected when the excitation is slightly blue-shifted with respect to the Localized Surface Plasmon Resonance (LSPR), so that the LSPR peak falls in the middle between the laser and the Stokes Raman emission. Recent experiments have shown when moving the excitation from the visible to the near-infrared that this rule of thumb is no more valid. The excitation has to be red-shifted with respect to the LSPR peak, up to 80nm, to obtain highest SERS. Such discrepancy is usually attributed to a Near-Field (NF) to Far-Field (FF) spectral shift. Here we critically discuss this hypothesis for the case of gold nanocylinders. By combining multi-wavelength excitation SERS experiments with numerical calculations, we show that the red-shift of the excitation energy does not originate from a spectral shift between the extinction (FF) and the near-field distribution (NF), which is found to be not larger than 10nm. Rather, it can be accounted for by looking at the peculiar spectral dependence of the near-field intensity on the cylinders diameter, characterized by an initial increase, up to 180nm diameter, followed by a decrease and a pronounced skewness.

Transparency of Semi-Insulating, n-Type, and p-Type Ammonothermal GaN Substrates in the Near-Infrared, Mid-Infrared, and THz Spectral Range

Directory of Open Access Journals (Sweden)

Robert Kucharski

2017-06-01

Full Text Available GaN substrates grown by the ammonothermal method are analyzed by Fast Fourier Transformation Spectroscopy in order to study the impact of doping (both n- and p-type on their transparency in the near-infrared, mid-infrared, and terahertz spectral range. It is shown that the introduction of dopants causes a decrease in transparency of GaN substrates in a broad spectral range which is attributed to absorption on free carriers (n-type samples or dopant ionization (p-type samples. In the mid-infrared the transparency cut-off, which for a semi-insulating GaN is at ~7 µm due to an absorption on a second harmonic of optical phonons, shifts towards shorter wavelengths due to an absorption on free carriers up to ~1 µm at n ~ 1020 cm−3 doping level. Moreover, a semi-insulating GaN crystal shows good transparency in the 1–10 THz range, while for n-and p-type crystal, the transparency in this spectral region is significantly quenched below 1%. In addition, it is shown that in the visible spectral region n-type GaN substrates with a carrier concentration below 1018 cm−3 are highly transparent with the absorption coefficient below 3 cm−1 at 450 nm, a satisfactory condition for light emitting diodes and laser diodes operating in this spectral range.

Measurement of spectral sea ice albedo at Qaanaaq fjord in northwest Greenland

Science.gov (United States)

Tanikawa, T.

2017-12-01

The spectral albedos of sea ice were measured at Qaanaaq fjord in northwest Greenland. Spectral measurements were conducted for sea ice covered with snow and sea ice without snow where snow was artificially removed around measurement point. Thickness of the sea ice was approximately 1.3 m with 5 cm of snow over the sea ice. The measurements show that the spectral albedos of the sea ice with snow were lower than those of natural pure snow especially in the visible regions though the spectral shapes were similar to each other. This is because the spectral albedos in the visible region have information of not only the snow but also the sea ice under the snow. The spectral albedos of the sea ice without the snow were approximately 0.4 - 0.5 in the visible region, 0.05-0.25 in the near-infrared region and almost constant of approximately 0.05 in the region of 1500 - 2500 nm. In the visible region, it would be due to multiple scattering by an air bubble within the sea ice. In contrast, in the near-infrared and shortwave infrared wavelengths, surface reflection at the sea ice surface would be dominant. Since a light absorption by the ice in these regions is relatively strong comparing to the visible region, the light could not be penetrated deeply within the sea ice, resulting that surface reflection based on Fresnel reflection would be dominant. In this presentation we also show the results of comparison between the radiative transfer calculation and spectral measurement data.

Doubly and triply linked porphyrin-perylene monoimides as near IR dyes with large dipole moments and high photostability

KAUST Repository

Jiao, Chongjun

2011-01-21

Doubly and triply linked porphyrin-perylene monoimides 3 and 4, with extraordinary stability, large dipole moments, and strong near IR absorption, were prepared by means of one-pot oxidative cyclodehydrogenation promoted by FeCl 3. © 2010 American Chemical Society.

IGRINS NEAR-IR HIGH-RESOLUTION SPECTROSCOPY OF MULTIPLE JETS AROUND LkHα 234

Energy Technology Data Exchange (ETDEWEB)

Oh, Heeyoung; Yuk, In-Soo; Park, Byeong-Gon; Park, Chan; Chun, Moo-Young; Kim, Kang-Min; Oh, Jae Sok; Jeong, Ueejeong; Yu, Young Sam; Lee, Jae-Joon; Kim, Hwihyun; Hwang, Narae; Lee, Sungho [Korea Astronomy and Space Science Institute, 776 Daedeok-daero, Yuseong-gu, Daejeon 305-348 (Korea, Republic of); Pyo, Tae-Soo [Subaru Telescope, National Astronomical Observatory of Japan, 650 North A’ohoku Place, Hilo, HI 96720 (United States); Pak, Soojong; Lee, Hye-In; Le, Huynh Anh Nguyen [School of Space Research and Institute of Natural Sciences, Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin-si, Gyeonggi-do 17104 (Korea, Republic of); Kaplan, Kyle; Pavel, Michael; Mace, Gregory, E-mail: hyoh@kasi.re.kr [Department of Astronomy, University of Texas at Austin, Austin, TX (United States); and others

2016-02-01

We present the results of high-resolution near-IR spectroscopy toward the multiple outflows around the Herbig Be star LkHα 234 using the Immersion Grating Infrared Spectrograph. Previous studies indicate that the region around LkHα 234 is complex, with several embedded young stellar objects and the outflows associated with them. In simultaneous H- and K-band spectra from HH 167, we detected 5 [Fe ii] and 14 H{sub 2} emission lines. We revealed a new [Fe ii] jet driven by radio continuum source VLA 3B. Position–velocity diagrams of the H{sub 2} 1−0 S(1) λ2.122 μm line show multiple velocity peaks. The kinematics may be explained by a geometrical bow shock model. We detected a component of H{sub 2} emission at the systemic velocity (V{sub LSR} = −10.2 km s{sup −1}) along the whole slit in all slit positions, which may arise from the ambient photodissociation region. Low-velocity gas dominates the molecular hydrogen emission from knots A and B in HH 167, which is close to the systemic velocity; [Fe ii] emission lines are detected farther from the systemic velocity, at V{sub LSR} = −100–−130 km s{sup −1}. We infer that the H{sub 2} emission arises from shocked gas entrained by a high-velocity outflow. Population diagrams of H{sub 2} lines imply that the gas is thermalized at a temperature of 2500–3000 K and the emission results from shock excitation.

CORRELATION ANALYSIS OF IR, 1 H- AND 13 C-NMR SPECTRAL DATA OF N-ALKYL AND N-CYCLOALKYL CYANOACETAMIDES

Directory of Open Access Journals (Sweden)

Aleksandar D. Marinković

2011-09-01

Full Text Available Linear free energy relationships (LFER were applied to the IR, 1H- and 13C--NMR spectral data in N-alkyl and N-cycloalkyl cyanoacetamides. N-alkyl and N-cycloalkyl cyanocetamides were synthesized from corresponding amine and ethyl cyanoacetate. A number of substituents were employed for alkyl substitution, and fairly good correlations were obtained, using simple Hammett equation. In N-alkyl and N-cycloalkyl cyanoacetamides substituent cause SCS of N-H hydrogen primarily by steric interaction, polar subtituent effect influences SCS shift of C=O carbon, while steric effect of N-alkyl substituent causes IR stretching frequencies of N-H, C=O and CN group. The conformations of investigated compounds have been studied by the use of semiempirical PM6 method, and together with LFER analysis, give a better insight into the influence of such a structure on the transmission of electronic substituent effects. Negative ρ values for several correlations (reverse substituent effect were found.

Thermal Infrared and Visible to Near-Infrared Spectral Analysis of Chert and Amorphous Silica

Science.gov (United States)

McDowell, M. L.; Hamilton, V. E.; Cady, S. L.; Knauth, P.

2009-03-01

We look in detail at the thermal infrared and visible to near-infrared spectra of various forms of chert and amorphous silica and compare the spectral variations between samples with variations in physical and chemical characteristics.

Determine the optimum spectral reflectance of juniper and pistachio in arid and semi-arid region

Science.gov (United States)

Fadaei, Hadi; Suzuki, Rikie

2012-11-01

Arid and semi-arid areas of northeast Iran cover about 3.4 million ha are populated by two main tree species, the broadleaf Pistacia vera. L (pistachio) and the conifer Juniperus excelsa ssp. polycarpos (Persian juniper). Natural stands of pistachio in Iran are not only environmentally important but genetically essential as seed sources for pistachio production in orchards. In this study, we estimated the optimum spectral reflectance of juniper forests and natural pistachio stands using remote sensing to help in the sustainable management and production of pistachio in Iran. In this research spectral reflectance are able to specify of multispectral from Advanced Land Observing Satellite (ALOS) that provided by JAXA. These data included PRISM is a panchromatic radiometer with a 2.5 m spatial resolution at nadir, has one band with a wavelength of 0.52-0.77 μm and AVNIR-2 is a visible and near infrared radiometer for observing land and coastal zones with a 10 m spatial resolution at nadir, has four multispectral bands: blue (0.42-0.50 μm), green (0.52-0.60 μm), red (0.61-0.69 μm), and near infrared (0.76-0.89 μm). Total ratio vegetation index (TRVI) of optimum spectral reflectance of juniper and pistachio have been evaluated. The result of TRVI for Pistachio and juniper were (R2= 0.71 and 0.55). I hope this research can provide decision of managers to helping sustainable management for arid and semi-arid regions in Iran.

White light spectral interferometer for measuring dispersion in the visible-near infrared

Science.gov (United States)

Arosa, Yago; Rodríguez Fernández, Carlos Damian; Algnamat, Bilal S.; López-Lago, Elena; de la Fuente, Raul

2017-08-01

We have designed a spectrally resolved interferometer to measure the refractive index of transparent samples over a wide spectral band from 400 to 1550 nm. The measuring device consists of a Michelson interferometer whose output is analyzed by means of three fiber spectrometers. The first one is a homemade prism spectrometer, which obtains the interferogram produced by the sample over 400 to 1050 nm; the second one is a homemade transmission grating spectrometer thought to measure the interferogram in the near infrared spectral band from 950 to 1550 nm; the last one is a commercial Czerny-Turner spectrometer used to make high precision measurements of the displacement between the Michelson mirrors also using white light interferometry. The whole system is illuminated by a white light source with an emission spectrum similar to black body. We have tested the instrument with solid and liquids samples achieving accuracy to the fourth decimal on the refractive index after fitting it to a Cauchy formula

Pepper seed variety identification based on visible/near-infrared spectral technology

Science.gov (United States)

Li, Cuiling; Wang, Xiu; Meng, Zhijun; Fan, Pengfei; Cai, Jichen

2016-11-01

Pepper is a kind of important fruit vegetable, with the expansion of pepper hybrid planting area, detection of pepper seed purity is especially important. This research used visible/near infrared (VIS/NIR) spectral technology to detect the variety of single pepper seed, and chose hybrid pepper seeds "Zhuo Jiao NO.3", "Zhuo Jiao NO.4" and "Zhuo Jiao NO.5" as research sample. VIS/NIR spectral data of 80 "Zhuo Jiao NO.3", 80 "Zhuo Jiao NO.4" and 80 "Zhuo Jiao NO.5" pepper seeds were collected, and the original spectral data was pretreated with standard normal variable (SNV) transform, first derivative (FD), and Savitzky-Golay (SG) convolution smoothing methods. Principal component analysis (PCA) method was adopted to reduce the dimension of the spectral data and extract principal components, according to the distribution of the first principal component (PC1) along with the second principal component(PC2) in the twodimensional plane, similarly, the distribution of PC1 coupled with the third principal component(PC3), and the distribution of PC2 combined with PC3, distribution areas of three varieties of pepper seeds were divided in each twodimensional plane, and the discriminant accuracy of PCA was tested through observing the distribution area of samples' principal components in validation set. This study combined PCA and linear discriminant analysis (LDA) to identify single pepper seed varieties, results showed that with the FD preprocessing method, the discriminant accuracy of pepper seed varieties was 98% for validation set, it concludes that using VIS/NIR spectral technology is feasible for identification of single pepper seed varieties.

Effect of H{sup +} implantation on the optical properties of semi-insulating GaAs crystals in the IR spectral region

Energy Technology Data Exchange (ETDEWEB)

Klyui, N. I.; Lozinskii, V. B., E-mail: lvb@isp.kiev.ua [Jilin University, College of Physics (China); Liptuga, A. I.; Dikusha, V. N. [National Academy of Sciences of Ukraine, Lashkaryov Institute of Semiconductor Physics (Ukraine); Oksanych, A. P.; Kogdas’, M. G.; Perekhrest, A. L.; Pritchin, S. E. [Kremenchug National University (Ukraine)

2017-03-15

The optical properties of semi-insulating GaAs crystals subjected to multienergy hydrogen-ion implantation and treatment in a high-frequency electromagnetic field are studied in the infrared spectral region. It is established that such combined treatment provides a means for substantially increasing the transmittance of GaAs crystals to values characteristic of crystals of high optical quality. On the basis of analysis of the infrared transmittance and reflectance data, Raman spectroscopy data, and atomic-force microscopy data on the surface morphology of the crystals, a physical model is proposed to interpret the effects experimentally observed in the crystals. The model takes into account the interaction of radiation defects with the initial structural defects in the crystals as well as the effect of compensation of defect centers by hydrogen during high-frequency treatment.

Optimization of silicon waveguides for gas detection application at mid-IR wavelengths

Science.gov (United States)

Butt, M. A.; Kozlova, E. S.

2018-04-01

There are several trace gases such as N2O, CO, CO2, NO, H2O, NO2, NH3, CH4 etc. which have their absorption peaks in Mid-IR spectrum These gases strongly absorb in the mid-IR > 2.5 μm spectral region due to their fundamental rotational and vibrational transitions. In this work, we modelled and optimized three different kinds of waveguides such as rib, strip and slot based on silicon platform to obtain maximum evanescent field ratio. These waveguides are designed at 3.39 μm and 4.67 μm which correspond to the absorption line of methane (CH4) and carbon monoxide (CO) respectively.

Selective suppression of high-order harmonics within phase-matched spectral regions.

Science.gov (United States)

Lerner, Gavriel; Diskin, Tzvi; Neufeld, Ofer; Kfir, Ofer; Cohen, Oren

2017-04-01

Phase matching in high-harmonic generation leads to enhancement of multiple harmonics. It is sometimes desired to control the spectral structure within the phase-matched spectral region. We propose a scheme for selective suppression of high-order harmonics within the phase-matched spectral region while weakly influencing the other harmonics. The method is based on addition of phase-mismatched segments within a phase-matched medium. We demonstrate the method numerically in two examples. First, we show that one phase-mismatched segment can significantly suppress harmonic orders 9, 15, and 21. Second, we show that two phase-mismatched segments can efficiently suppress circularly polarized harmonics with one helicity over the other when driven by a bi-circular field. The new method may be useful for various applications, including the generation of highly helical bright attosecond pulses.

Hungaria asteroid region telescopic spectral survey (HARTSS) I: Stony asteroids abundant in the Hungaria background population

Science.gov (United States)

Lucas, Michael P.; Emery, Joshua P.; Pinilla-Alonso, Noemi; Lindsay, Sean S.; Lorenzi, Vania

2017-07-01

The Hungaria asteroids remain as survivors of late giant planet migration that destabilized a now extinct inner portion of the primordial asteroid belt and left in its wake the current resonance structure of the Main Belt. In this scenario, the Hungaria region represents a ;purgatory; for the closest, preserved samples of the asteroidal material from which the terrestrial planets accreted. Deciphering the surface composition of these unique samples may provide constraints on the nature of the primordial building blocks of the terrestrial planets. We have undertaken an observational campaign entitled the Hungaria Asteroid Region Telescopic Spectral Survey (HARTSS) to record near-infrared (NIR) reflectance spectra in order to characterize their taxonomy, surface mineralogy, and potential meteorite analogs. The overall objective of HARTSS is to evaluate the compositional diversity of asteroids located throughout the Hungaria region. This region harbors a collisional family of Xe-type asteroids, which are situated among a background (i.e., non-family) of predominantly S-complex asteroids. In order to assess the compositional diversity of the Hungaria region, we have targeted background objects during Phase I of HARTSS. Collisional family members likely reflect the composition of one original homogeneous parent body, so we have largely avoided them in this phase. We have employed NIR instruments at two ground-based telescope facilities: the NASA Infrared Telescope Facility (IRTF), and the Telescopio Nazionale Galileo (TNG). Our data set includes the NIR spectra of 42 Hungaria asteroids (36 background; 6 family). We find that stony S-complex asteroids dominate the Hungaria background population (29/36 objects; ∼80%). C-complex asteroids are uncommon (2/42; ∼5%) within the Hungaria region. Background S-complex objects exhibit considerable spectral diversity as band parameter measurements of diagnostic absorption features near 1- and 2-μm indicate that several

Regional Spectral Model simulations of the summertime regional climate over Taiwan and adjacent areas

Science.gov (United States)

Ching-Teng Lee; Ming-Chin Wu; Shyh-Chin Chen

2005-01-01

The National Centers for Environmental Prediction (NCEP) regional spectral model (RSM) version 97 was used to investigate the regional summertime climate over Taiwan and adjacent areas for June-July-August of 1990 through 2000. The simulated sea-level-pressure and wind fields of RSM1 with 50-km grid space are similar to the reanalysis, but the strength of the...

Methods for deconvoluting and interpreting complex gamma- and x-ray spectral regions

International Nuclear Information System (INIS)

Gunnink, R.

1983-06-01

Germanium and silicon detectors are now widely used for the detection and measurement of x and gamma radiation. However, some analysis situations and spectral regions have heretofore been too complex to deconvolute and interpret by techniques in general use. One example is the L x-ray spectrum of an element taken with a Ge or Si detector. This paper describes some new tools and methods that were developed to analyze complex spectral regions; they are illustrated with examples

[Near ultraviolet absorption spectral properties of chromophoric dissolved organic matter in the north area of Yellow Sea].

Science.gov (United States)

Wang, Lin; Zhao, Dong-Zhi; Yang, Jian-Hong; Chen, Yan-Long

2010-12-01

Chromophoric dissolved organic matter (CDOM) near ultraviolet absorption spectra contains CDOM molecular structure, composition and other important physical and chemical information. Based on the measured data of CDOM absorption coefficient in March 2009 in the north area of Yellow Sea, the present paper analyzed near ultraviolet absorption spectral properties of CDOM. The results showed that due to the impact of near-shore terrigenous input, the composition of CDOM is quite different in the north area of Yellow Sea, and this area is a typical case II water; fitted slope with specific range of spectral band and absorption coefficient at specific band can indicate the relative size of CDOM molecular weight, correlation between spectral slope of the Sg,275-300), Sg,300-350, Sg,350-400 and Sg,250-275 and the relative size of CDOM molecular weight indicative parameter M increases in turn and the highest is up to 0.95. Correlation between a(g)(lambda) and M value increases gradually with the increase in wavelength, and the highest is up to 0.92 at 400 nm; being correlated or not between spectral slope and absorption coefficient is decided by the fitting-band wavelength range for the spectra slope and the wavelength for absorption coefficient. Correlation between Sg,275-300 and a(g)(400) is the largest, up to 0.87.

Analysis of dust and marine aerosol optical depth spectral-curvature information in the UV to SWIR (Short Wave Infrared) wavelength regions.

Science.gov (United States)

O'Neill, N. T.; Smirnov, A.; Eck, T. F.; Sakerin, S.; Kabanov, D.

2005-12-01

Traditional sunphotometry in the UV, visible and very NIR (Near Infrared) spectral regions is weighted, in terms of spectral information content, towards sub-micron (fine mode) particles. Sunphotometry in the NIR and SWIR increases the diversity and information content of spectral aerosol optical depth (AOD) measurements for supermicron (coarse mode) particles. Two data sets representing dust aerosols from the UAE (United Arab Emirates) region and marine aerosols from the northern, tropical and southern Atlantic Ocean were analyzed in terms of their spectral curvature diversity and information content. The former data set was acquired using NIR-enhanced CIMEL sunphotometers (340, 340, 380, 440, 500, 670, 870, 1020, 1640 nm) as part of the August to October, 2004 UAE2 field campaign while the latter data set was acquired using an automated Russian UV to SWIR SP-5 sunphotometer (339, 423, 438, 484, 552, 633, 677, 777, 869, 1241, 1560, 2148, 4000 nm) as part of a October/December 2004 cruise campaign in the northern, tropical and south Atlantic Ocean. A Microtops hand-held sunphotometer was also employed to acquire VIS to NIR AOD spectra during the latter field campaign. Results will be presented in terms of robust micro-physical and spectral curvature parameters which characterize super-micron aerosols and, in a more general sense, in terms of what universal/fundamental optical inferences can be drawn from the two disperse data sets.

Optical design of a versatile FIRST high-resolution near-IR spectrograph

Science.gov (United States)

Zhao, Bo; Ge, Jian

2012-09-01

We report the update optical design of a versatile FIRST high resolution near IR spectrograph, which is called Florida IR Silicon immersion grating spectromeTer (FIRST). This spectrograph uses cross-dispersed echelle design with white pupils and also takes advantage of the image slicing to increase the spectra resolution, while maintaining the instrument throughput. It is an extremely high dispersion R1.4 (blazed angle of 54.74°) silicon immersion grating with a 49 mm diameter pupil is used as the main disperser at 1.4μm -1.8μm to produce R=72,000 while an R4 echelle with the same pupil diameter produces R=60,000 at 0.8μm -1.35μm. Two cryogenic Volume Phase Holographic (VPH) gratings are used as cross-dispersers to allow simultaneous wavelength coverage of 0.8μm -1.8μm. The butterfly mirrors and dichroic beamsplitters make a compact folding system to record these two wavelength bands with a 2kx2k H2RG array in a single exposure. By inserting a mirror before the grating disperser (the SIG and the echelle), this spectrograph becomes a very efficient integral field 3-D imaging spectrograph with R=2,000-4,000 at 0.8μm-1.8μm by coupling a 10x10 telescope fiber bundle with the spectrograph. Details about the optical design and performance are reported.

Near IR observations of Quiet Chromosphere

Science.gov (United States)

Prasad Choudhary, Debi; Deng, N.; Tejamoortula, U.; Penn, M. J.

2009-05-01

We have carried out the observations of quiet solar limb during April 29 to May 1, 2008, March 9-13, 2009 using the vertical spectrograph at the focal plane of McMath-Pierce telescope at Kitt Peak National Observatory. The solar limb was mostly featureless during the observations. The New Infrared Array (NAC) at the exit port of the spectrograph has been used to record the limb spectrum at HeI 1083.0 nm, Hydrogen Paschen beta at 1281.8 nm and Brackett gamma 2165.5 nm wavelength regions. The NAC is a 1024 x 1024 InSb Alladin III Detector operating over 1-5 micron range with high density sampling at 0.018 arc second/pixel. The all-reflective optical train minimizes number of surfaces and eliminates ghosts leading to low scatter, ghost-free optics. The close-cycle cryogenic provides a stable cooling environment over six hour period with an accuracy of about 0.01K leading to low dark current. The low read out noise combined with low scattered light and dark current makes NAC an ideal detector for making high quality infrared spectral observations of solar limb. In this presentation, we shall compare the line parameters of these lines around the solar disk. Acknowledgements: This work is supported by NSF under grant ATM 05-48952 and by NASA under grant NNX08AQ32G.

Broadly tunable picosecond ir source

International Nuclear Information System (INIS)

Campillo, A.J.; Hyer, R.C.; Shapiro, S.L.

1979-01-01

A completely grating tuned (1.9 to 2.4 μm) picosecond traveling wave IR generator capable of controlled spectral bandwidth operation down to the Fourier Transform limit is reported. Subsequent down conversion in CdSe extends tuning to 10 to 20 μm

Synthesis and characterization of near IR fluorescent albumin nanoparticles for optical detection of colon cancer

International Nuclear Information System (INIS)

Cohen, Sarit; Pellach, Michal; Kam, Yossi; Grinberg, Igor; Corem-Salkmon, Enav; Rubinstein, Abraham; Margel, Shlomo

2013-01-01

Near IR (NIR) fluorescent human serum albumin (HSA) nanoparticles hold great promise as contrast agents for tumor diagnosis. HSA nanoparticles are considered to be biocompatible, non-toxic and non-immunogenic. In addition, NIR fluorescence properties of these nanoparticles are important for in vivo tumor diagnostics, with low autofluorescence and relatively deep penetration of NIR irradiation due to low absorption of biomatrices. The present study describes the synthesis of new NIR fluorescent HSA nanoparticles, by entrapment of a NIR fluorescent dye within the HSA nanoparticles, which also significantly increases the photostability of the dye. Tumor-targeting ligands such as peanut agglutinin (PNA) and anti-carcinoembryonic antigen antibodies (anti-CEA) were covalently conjugated to the NIR fluorescent albumin nanoparticles, increasing the potential fluorescent signal in tumors with upregulated corresponding receptors. Specific colon tumor detection by the NIR fluorescent HSA nanoparticles was demonstrated in a chicken embryo model and a rat model. In future work we also plan to encapsulate cancer drugs such as doxorubicin within the NIR fluorescent HSA nanoparticles for both colon cancer imaging and therapy. - Highlights: ► Near IR human serum albumin nanoparticles were synthesized and characterized. ► Nanoparticles were shown to be physically and chemically stable and photostable. ► Tumor-targeting ligands were covalently conjugated to the nanoparticles. ► Specific colon cancer tumor detection was demonstrated in chicken-embryo and rat models.

A classification of spectral populations observed in HF radar backscatter from the E region auroral electrojets

Directory of Open Access Journals (Sweden)

S. E. Milan

2001-02-01

Full Text Available Observations of HF radar backscatter from the auroral electrojet E region indicate the presence of five major spectral populations, as opposed to the two predominant spectral populations, types I and II, observed in the VHF regime. The Doppler shift, spectral width, backscatter power, and flow angle dependencies of these five populations are investigated and described. Two of these populations are identified with type I and type II spectral classes, and hence, are thought to be generated by the two-stream and gradient drift instabilities, respectively. The remaining three populations occur over a range of velocities which can greatly exceed the ion acoustic speed, the usual limiting velocity in VHF radar observations of the E region. The generation of these spectral populations is discussed in terms of electron density gradients in the electrojet region and recent non-linear theories of E region irregularity generation.Key words. Ionosphere (ionospheric irregularities

Investigation of spectral characteristics of tunnel photodiodes based on DLC nanofilms

Science.gov (United States)

Akchurin, Garif G.; Aban'shin, Nickolay P.; Avetisyan, Yuri A.; Akchurin, Georgy G.; Kochubey, Vyacheslav I.; Yakunin, Alexander N.

2018-04-01

The tunneling photo effect has been studied in a microdiode with an electrostatic field localized at an emitter based on a nanosized DLC structure. It is established the photocurrent, when the carbon nanoemitter is exposed by laser and tunable low-coherent radiation in the spectral range from UV to near IR with photons of low energy (below work function). A linear dependence of the photocurrent on the level of optical power in the range of micro- and milliwatt power is established. The effect of saturation of the current-voltage characteristics of the tunnel photocurrent associated with a finite concentration of non-equilibrium photoelectrons is observed. The observed spectral Watt-Amper characteristics can be adequately interpreted using a modified Fowler-Nordheim equation for non-equilibrium photoelectrons.

Optical Cherenkov radiation by cascaded nonlinear interaction: an efficient source of few-cycle energetic near- to mid-IR pulses

DEFF Research Database (Denmark)

Bache, Morten; Bang, Ole; Zhou, Binbin

2011-01-01

When ultrafast noncritical cascaded second-harmonic generation of energetic femtosecond pulses occur in a bulk lithium niobate crystal optical Cherenkov waves are formed in the near- to mid-IR. Numerical simulations show that the few-cycle solitons radiate Cherenkov (dispersive) waves in the λ = 2...

Spectral filter for splitting a beam with electromagnetic radiation having wavelengths in the extreme ultraviolet (EUV) or soft X-Ray (Soft X) and the infrared (IR) wavelength range

NARCIS (Netherlands)

van Goor, F.A.; Bijkerk, Frederik; van den Boogaard, Toine; van den Boogaard, A.J.R.; van der Meer, R.

2012-01-01

Spectral filter for splitting the primary radiation from a generated beam with primary electromagnetic radiation having a wavelength in the extreme ultraviolet (EUV radiation) or soft X-ray (soft X) wavelength range and parasitic radiation having a wavelength in the infrared wavelength range (IR

Toward single-mode UV to near-IR guidance using hollow-core anti-resonant silica fiber

DEFF Research Database (Denmark)

Habib, Md Selim; Antonio-Lopez, Jose Enrique; Van Newkirk, Amy

2017-01-01

Hollow-core anti-resonant (HC-AR) fibers with a “negative-curvature” of the core-cladding boundary have been extensively studied over the past few years owing to their low loss and wide transmission bandwidths. The key unique feature of the HC-AR fiber is that the coupling between the core and cl...... a silica HC-AR fiber having a single ring of 7 non-touching capillaries, designed to have effectively single-mode operation and low loss from UV to near-IR....

HOM [higher order mode] losses at the IR [interaction region] of the B-factory

International Nuclear Information System (INIS)

Heifets, S.

1990-08-01

Masking at the interaction region (IR) will presumably reduce the synchrotron radiation background in the detector. One possible layout of the IR for B-factory shows a rather complicated system of masks. A bunch passing each mask will generate RF waves. These waves (called usually higher order modes, HOM-s) will be absorbed in the beam pipe wall producing additional heating and, interacting with the beam, kicking particles in the radial and azimuthal directions. This may change the bunch motion and its emittance. These effects are estimated in the present note

Subarcsecond observations of NGC 7538 IRS 1: Continuum distribution and dynamics of molecular gas

Energy Technology Data Exchange (ETDEWEB)

Zhu, Lei; Shi, Hui [National Astronomical Observatories, Chinese Academy of Sciences, A20 Datun Road, Chaoyang District, Beijing 100012 (China); Zhao, Jun-Hui [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Wright, M. C. H. [Department of Astronomy, University of California, Berkeley, Berkeley, CA 94720 (United States); Sandell, Göran [SOFIA-USRA, NASA Ames Research Center, MS 232-12, Building N232, Rm. 146, P.O. Box 1, Moffett Field, CA 94035-0001 (United States); Wu, Yue-Fang [Department of Astronomy, Peking University, Beijing 100871 (China); Brogan, Crystal; Corder, Stuartt, E-mail: lzhu@nao.cas.cn [NRAO, 520 Edgemont Road, Charlottesville, VA 22903 (United States)

2013-12-10

We report new results based on the analysis of the Submillimeter Array (SMA) and Combined Array for Research in Millimeter-wave Astronomy (CARMA) observations of NGC 7538 IRS 1 at 1.3 and 3.4 mm with subarcsecond resolutions. With angular resolutions ∼0.''7, the SMA and CARMA observations show that the continuum emission at 1.3 and 3.4 mm from the hyper-compact H II region IRS 1 is dominated by a compact source with a tail-like extended structure to the southwest of IRS 1. With a CARMA B-array image at 1.3 mm convolved to 0.''1, we resolve the hyper-compact H II region into two components: an unresolved hyper-compact core, and a north-south extension with linear sizes of <270 AU and ∼2000 AU, respectively. The fine structure observed with CARMA is in good agreement with the previous Very Large Array results at centimeter wavelengths, suggesting that the hyper-compact H II region at the center of IRS 1 is associated with an ionized bipolar outflow. We image the molecular lines OCS(19-18) and CH{sub 3}CN(12-11) as well as {sup 13}CO(2-1) surrounding IRS 1, showing a velocity gradient along the southwest-northeast direction. The spectral line profiles in {sup 13}CO(2-1), CO(2-1), and HCN(1-0) observed toward IRS 1 show broad redshifted absorption, providing evidence for gas infall with rates in the range of 3-10 × 10{sup –3} M {sub ☉} yr{sup –1} inferred from our observations.

A classification of spectral populations observed in HF radar backscatter from the E region auroral electrojets

Directory of Open Access Journals (Sweden)

S. E. Milan

Full Text Available Observations of HF radar backscatter from the auroral electrojet E region indicate the presence of five major spectral populations, as opposed to the two predominant spectral populations, types I and II, observed in the VHF regime. The Doppler shift, spectral width, backscatter power, and flow angle dependencies of these five populations are investigated and described. Two of these populations are identified with type I and type II spectral classes, and hence, are thought to be generated by the two-stream and gradient drift instabilities, respectively. The remaining three populations occur over a range of velocities which can greatly exceed the ion acoustic speed, the usual limiting velocity in VHF radar observations of the E region. The generation of these spectral populations is discussed in terms of electron density gradients in the electrojet region and recent non-linear theories of E region irregularity generation.

Key words. Ionosphere (ionospheric irregularities

Semiconductor lasers with a continuous tuning range above 100 nm in the nearest IR spectral region

Energy Technology Data Exchange (ETDEWEB)

Kostin, Yu O; Lobintsov, A A; Shramenko, M V [OOO ' Opton' , Moscow (Russian Federation); Ladugin, M A; Marmalyuk, A A [Open Joint-Stock Company M.F. Stel' makh Polyus Research Institute, Moscow (Russian Federation); Chamorovsky, A Yu [Superlum Ltd., Unit B3, Fota Point Enterprise Park, Carrigtwohill, Co Cork (Ireland); Yakubovich, S D [Moscow State Institute of Radio-Engineering, Electronics and Automation (Technical University), Moscow (Russian Federation)

2015-08-31

We have developed two new types of lasers based on quantum-confined semiconductor optical amplifiers with an acousto-optic tunable filter in an external fibre ring cavity. The lasers offer continuous wavelength tuning ranges from 780 to 885 and from 880 to 1010 nm, 20 mW of cw output power, and a tuning rate up to 10{sup 4} nm s{sup -1} at an instantaneous spectral linewidth less than 0.1 nm. (lasers)

Selection/extraction of spectral regions for autofluorescence spectra measured in the oral cavity

NARCIS (Netherlands)

Skurichina, M; Paclik, P; Duin, RPW; de Veld, D; Sterenborg, HJCM; Witjes, MJH; Roodenburg, JLN; Fred, A; Caelli, T; Duin, RPW; Campilho, A; DeRidder, D

2004-01-01

Recently a number of successful algorithms to select/extract discriminative spectral regions was introduced. These methods may be more beneficial than the standard feature selection/extraction methods for spectral classification. In this paper, on the example of autofluorescence spectra measured in

THE HST EXTREME DEEP FIELD (XDF): COMBINING ALL ACS AND WFC3/IR DATA ON THE HUDF REGION INTO THE DEEPEST FIELD EVER

International Nuclear Information System (INIS)

Illingworth, G. D.; Magee, D.; Oesch, P. A.; Bouwens, R. J.; Labbé, I.; Franx, M.; Stiavelli, M.; Van Dokkum, P. G.; Trenti, M.; Carollo, C. M.; Gonzalez, V.

2013-01-01

The eXtreme Deep Field (XDF) combines data from 10 years of observations with the Hubble Space Telescope Advanced Camera for Surveys (ACS) and the Wide-Field Camera 3 Infra-Red (WFC3/IR) into the deepest image of the sky ever in the optical/near-IR. Since the initial observations of the Hubble Ultra-Deep Field (HUDF) in 2003, numerous surveys and programs, including supernovae follow-up, HUDF09, CANDELS, and HUDF12, have contributed additional imaging data across this region. However, these images have never been combined and made available as one complete ultra-deep image dataset. We combine them now with the XDF program. Our new and improved processing techniques provide higher quality reductions of the total dataset. All WFC3/IR and optical ACS data sets have been fully combined and accurately matched, resulting in the deepest imaging ever taken at these wavelengths, ranging from 29.1 to 30.3 AB mag (5σ in a 0.''35 diameter aperture) in 9 filters. The combined image therefore reaches to 31.2 AB mag 5σ (32.9 at 1σ) for a flat f ν source. The gains in the optical for the four filters done in the original ACS HUDF correspond to a typical improvement of 0.15 mag, with gains of 0.25 mag in the deepest areas. Such gains are equivalent to adding ∼130 to ∼240 orbits of ACS data to the HUDF. Improved processing alone results in a typical gain of ∼0.1 mag. Our 5σ (optical+near-IR) SExtractor catalogs reveal about 14,140 sources in the full field and about 7121 galaxies in the deepest part of the XDF

Gasoline classification using near infrared (NIR) spectroscopy data: Comparison of multivariate techniques

Energy Technology Data Exchange (ETDEWEB)

Balabin, Roman M., E-mail: balabin@org.chem.ethz.ch [Department of Chemistry and Applied Biosciences, ETH Zurich, 8093 Zurich (Switzerland); Safieva, Ravilya Z. [Gubkin Russian State University of Oil and Gas, 119991 Moscow (Russian Federation); Lomakina, Ekaterina I. [Faculty of Computational Mathematics and Cybernetics, Lomonosov Moscow State University, 119992 Moscow (Russian Federation)

2010-06-25

Near infrared (NIR) spectroscopy is a non-destructive (vibrational spectroscopy based) measurement technique for many multicomponent chemical systems, including products of petroleum (crude oil) refining and petrochemicals, food products (tea, fruits, e.g., apples, milk, wine, spirits, meat, bread, cheese, etc.), pharmaceuticals (drugs, tablets, bioreactor monitoring, etc.), and combustion products. In this paper we have compared the abilities of nine different multivariate classification methods: linear discriminant analysis (LDA), quadratic discriminant analysis (QDA), regularized discriminant analysis (RDA), soft independent modeling of class analogy (SIMCA), partial least squares (PLS) classification, K-nearest neighbor (KNN), support vector machines (SVM), probabilistic neural network (PNN), and multilayer perceptron (ANN-MLP) - for gasoline classification. Three sets of near infrared (NIR) spectra (450, 415, and 345 spectra) were used for classification of gasolines into 3, 6, and 3 classes, respectively, according to their source (refinery or process) and type. The 14,000-8000 cm{sup -1} NIR spectral region was chosen. In all cases NIR spectroscopy was found to be effective for gasoline classification purposes, when compared with nuclear magnetic resonance (NMR) spectroscopy or gas chromatography (GC). KNN, SVM, and PNN techniques for classification were found to be among the most effective ones. Artificial neural network (ANN-MLP) approach based on principal component analysis (PCA), which was believed to be efficient, has shown much worse results. We hope that the results obtained in this study will help both further chemometric (multivariate data analysis) investigations and investigations in the sphere of applied vibrational (infrared/IR, near-IR, and Raman) spectroscopy of sophisticated multicomponent systems.

Gasoline classification using near infrared (NIR) spectroscopy data: Comparison of multivariate techniques

International Nuclear Information System (INIS)

Balabin, Roman M.; Safieva, Ravilya Z.; Lomakina, Ekaterina I.

2010-01-01

Near infrared (NIR) spectroscopy is a non-destructive (vibrational spectroscopy based) measurement technique for many multicomponent chemical systems, including products of petroleum (crude oil) refining and petrochemicals, food products (tea, fruits, e.g., apples, milk, wine, spirits, meat, bread, cheese, etc.), pharmaceuticals (drugs, tablets, bioreactor monitoring, etc.), and combustion products. In this paper we have compared the abilities of nine different multivariate classification methods: linear discriminant analysis (LDA), quadratic discriminant analysis (QDA), regularized discriminant analysis (RDA), soft independent modeling of class analogy (SIMCA), partial least squares (PLS) classification, K-nearest neighbor (KNN), support vector machines (SVM), probabilistic neural network (PNN), and multilayer perceptron (ANN-MLP) - for gasoline classification. Three sets of near infrared (NIR) spectra (450, 415, and 345 spectra) were used for classification of gasolines into 3, 6, and 3 classes, respectively, according to their source (refinery or process) and type. The 14,000-8000 cm -1 NIR spectral region was chosen. In all cases NIR spectroscopy was found to be effective for gasoline classification purposes, when compared with nuclear magnetic resonance (NMR) spectroscopy or gas chromatography (GC). KNN, SVM, and PNN techniques for classification were found to be among the most effective ones. Artificial neural network (ANN-MLP) approach based on principal component analysis (PCA), which was believed to be efficient, has shown much worse results. We hope that the results obtained in this study will help both further chemometric (multivariate data analysis) investigations and investigations in the sphere of applied vibrational (infrared/IR, near-IR, and Raman) spectroscopy of sophisticated multicomponent systems.

Living Matter Observations with a Novel Hyperspectral Supercontinuum Confocal Microscope for VIS to Near-IR Reflectance Spectroscopy

Directory of Open Access Journals (Sweden)

Francesca R. Bertani

2013-10-01

Full Text Available A broad range hyper-spectroscopic microscope fed by a supercontinuum laser source and equipped with an almost achromatic optical layout is illustrated with detailed explanations of the design, implementation and data. The real novelty of this instrument, a confocal spectroscopic microscope capable of recording high resolution reflectance data in the VIS-IR spectral range from about 500 nm to 2.5 μm wavelengths, is the possibility of acquiring spectral data at every physical point as defined by lateral coordinates, X and Y, as well as at a depth coordinate, Z, as obtained by the confocal optical sectioning advantage. With this apparatus we collect each single scanning point as a whole spectrum by combining two linear spectral detector arrays, one CCD for the visible range, and one InGaAs infrared array, simultaneously available at the sensor output channel of the home made instrument. This microscope has been developed for biomedical analysis of human skin and other similar applications. Results are shown illustrating the technical performances of the instrument and the capability in extracting information about the composition and the structure of different parts or compartments in biological samples as well as in solid statematter. A complete spectroscopic fingerprinting of samples at microscopic level is shown possible by using statistical analysis on raw data or analytical reflectance models based on Abelés matrix transfer methods.

Robustness of the charge-ordered phases in IrTe2 against photoexcitation

Science.gov (United States)

Monney, C.; Schuler, A.; Jaouen, T.; Mottas, M.-L.; Wolf, Th.; Merz, M.; Muntwiler, M.; Castiglioni, L.; Aebi, P.; Weber, F.; Hengsberger, M.

2018-02-01

We present a time-resolved angle-resolved photoelectron spectroscopy study of IrTe2, which undergoes two first-order structural and charge-ordered phase transitions on cooling below 270 K and below 180 K. The possibility of inducing a phase transition by photoexcitation with near-infrared femtosecond pulses is investigated in the charge-ordered phases. We observe changes of the spectral function occurring within a few hundreds of femtoseconds and persisting up to several picoseconds, which we interpret as a partial photoinduced phase transition (PIPT). The necessary time for photoinducing these spectral changes increases with increasing photoexcitation density and reaches time scales longer than the rise time of the transient electronic temperature. We conclude that the PIPT is driven by a transient increase of the lattice temperature following the energy transfer from the electrons. However, the photoinduced changes of the spectral function are small, which indicates that the low-temperature phase is particularly robust against photoexcitation. We suggest that the system might be trapped in an out-of-equilibrium state, for which only a partial structural transition is achieved.

High-resolution IR absorption spectroscopy of polycyclic aromatic hydrocarbons in the 3 μm region: role of hydrogenation and alkylation

Science.gov (United States)

Maltseva, Elena; Mackie, Cameron J.; Candian, Alessandra; Petrignani, Annemieke; Huang, Xinchuan; Lee, Timothy J.; Tielens, Alexander G. G. M.; Oomens, Jos; Buma, Wybren Jan

2018-03-01

Aim. We aim to elucidate the spectral changes in the 3 μm region that result from chemical changes in the molecular periphery of polycyclic aromatic hydrocarbons (PAHs) with extra hydrogens (H-PAHs) and methyl groups (Me-PAHs). Methods: Advanced laser spectroscopic techniques combined with mass spectrometry were applied on supersonically cooled 1,2,3,4-tetrahydronaphthalene, 9,10-dihydroanthracene, 9,10-dihydrophenanthrene, 1,2,3,6,7,8-hexahydropyrene, 9-methylanthracene, and 9,10-dimethylanthracene, allowing us to record mass-selective and conformationally selective absorption spectra of the aromatic, aliphatic, and alkyl CH-stretches in the 3.175 - 3.636 µm region with laser-limited resolution. We compared the experimental absorption spectra with standard harmonic calculations and with second-order vibrational perturbation theory anharmonic calculations that use the SPECTRO program for treating resonances. Results: We show that anharmonicity plays an important if not dominant role, affecting not only aromatic, but also aliphatic and alkyl CH-stretch vibrations. The experimental high-resolution data lead to the conclusion that the variation in Me- and H-PAHs composition might well account for the observed variations in the 3 μm emission spectra of carbon-rich and star-forming regions. Our laboratory studies also suggest that heavily hydrogenated PAHs form a significant fraction of the carriers of IR emission in regions in which an anomalously strong 3 μm plateau is observed.

On the Search for Mid-IR and Pure Rotational H3+ Emission in Jupiter's Northern Aurora

Science.gov (United States)

Trafton, Laurence M.; Miller, Steve; Lacy, John H.; Greathouse, Thomas K.

2017-06-01

The first identification of astronomical spectral emission from the H3+ ion was made in Jupiter’s southern auroral region in the first overtone band near 2 μm (Drossart et al. 1989; Nature 340, 539). Trafton et al. (1989; ApJ 343, L73) also detected H3+ emission from this band near each of Jupiter’s auroral poles, but without identifying it. Shortly thereafter, Maillard et al (1990; ApJ 363, L37) detected the fundamental band emission near 4 μm. In order to determine the non-LTE column abundance of H3+, which is Jupiter’s primary ionospheric coolant, we searched in 2001-2002, initially above 10 μm, for emission lines from the H3+ pure rotational and ν1 -> ν2 difference band. This was done near the northern auroral “hot spot” at System III longitude 180 deg based on predicted theoretical frequencies. The results were reported by Trafton et al. (2009; Icarus 203, 189). No pure rotational lines were detected but there were marginal detections of two metastable difference band lines. The IR-inactive ν1 levels are populated in thermal equilibrium so these difference band lines are proxies for the pure rotational lines in establishing the total H3+ column. These marginal results are consistent with a vibrational relaxation of the ν2 level by a factor of ~6, consistent with the non-LTE calculation of Melin et al. (2005; Icarus 178, 97).We report here results from subsequent observations of Jupiter’s H3+ hot spot spectrum below 10 μm, where better detectivity was expected from the lower thermal background. However, this was offset by the reduced availability of emission from known hydrocarbons, leading to acquisition and guiding difficulty, which was resolved by offsetting from a Galilean satellite. The observations were made with the TEXES high-resolution mid-IR spectrograph at the IRTF telescope on Oct 1, 6, and 8 of 2012. Of the 18 lines predicted for this wavelength regime, half avoided blending with lines apparent in Jupiter’s auroral spectrum or

Near-IR search for lensed supernovae behind galaxy clusters. II. First detection and future prospects

OpenAIRE

Goobar, A.; Paech, K.; Stanishev, V.; Amanullah, R.; Dahlén, T.; Jönsson, J.; Kneib, J. P.; Lidman, C.; Limousin, M.; Mörtsell, E.; Nobili, S.; Richard, J.; Riehm, T.; von Strauss, M.

2009-01-01

Aims. Powerful gravitational telescopes in the form of massive galaxy clusters can be used to enhance the light collecting power over a limited field of view by about an order of magnitude in flux. This effect is exploited here to increase the depth of a survey for lensed supernovae at near-IR wavelengths. Methods. We present a pilot supernova search programme conducted with the ISAAC camera at VLT. Lensed galaxies behind the massive clusters A1689, A1835, and AC114 were observed for a tot...

On global and regional spectral evaluation of global geopotential models

International Nuclear Information System (INIS)

Ustun, A; Abbak, R A

2010-01-01

Spectral evaluation of global geopotential models (GGMs) is necessary to recognize the behaviour of gravity signal and its error recorded in spherical harmonic coefficients and associated standard deviations. Results put forward in this wise explain the whole contribution of gravity data in different kinds that represent various sections of the gravity spectrum. This method is more informative than accuracy assessment methods, which use external data such as GPS-levelling. Comparative spectral evaluation for more than one model can be performed both in global and local sense using many spectral tools. The number of GGMs has grown with the increasing number of data collected by the dedicated satellite gravity missions, CHAMP, GRACE and GOCE. This fact makes it necessary to measure the differences between models and to monitor the improvements in the gravity field recovery. In this paper, some of the satellite-only and combined models are examined in different scales, globally and regionally, in order to observe the advances in the modelling of GGMs and their strengths at various expansion degrees for geodetic and geophysical applications. The validation of the published errors of model coefficients is a part of this evaluation. All spectral tools explicitly reveal the superiority of the GRACE-based models when compared against the models that comprise the conventional satellite tracking data. The disagreement between models is large in local/regional areas if data sets are different, as seen from the example of the Turkish territory

The FUR to near-IR morphologies of luminous infrared galaxies in the goals sample

International Nuclear Information System (INIS)

Petty, S. M.; Armus, L.; Díaz-Santos, T.; Howell, J. H.; Surace, J. A.; Charmandaris, V.; Psychogyios, A.; Evans, A. S.; Stierwalt, S.; Floc’h, E. Le; Bridge, C.; Inami, H.

2014-01-01

We compare the morphologies of a sample of 20 luminous infrared galaxies (LIRGs) from the Great Observatories All-sky LIRG Survey (GOALS) in the FUV, B, I, and H bands, using the Gini (G) and M 20 parameters to quantitatively estimate the distribution and concentration of flux as a function of wavelength. Hubble Space Telescope (HST) images provide an average spatial resolution of ∼80 pc. While our LIRGs can be reliably classified as mergers across the entire range of wavelengths studied here, there is a clear shift toward more negative M 20 (more bulge-dominated) and a less significant decrease in G values at longer wavelengths. We find no correlation between the derived FUV G-M 20 parameters and the global measures of the IR to FUV flux ratio (IRX). Given the fine resolution in our HST data, this suggests either that the UV morphology and IRX are correlated on very small scales, or that the regions emitting the bulk of the IR emission emit almost no FUV light. We use our multi-wavelength data to simulate how merging LIRGs would appear from z∼0.5–3 in deep optical and near-infrared images such as the Hubble Ultra-Deep Field, and use these simulations to measure the G-M 20 at these redshifts. Our simulations indicate a noticeable decrease in G, which flattens at z⩾2 by as much as 40%, resulting in mis-classifying our LIRGs as disk-like, even in the rest-frame FUV. The higher redshift values of M 20 for the GOALS sources do not appear to change more than about 10% from the values at z∼0. The change in G-M 20 is caused by the surface brightness dimming of extended tidal features and asymmetries, and also the decreased spatial resolution which reduced the number of individual clumps identified. This effect, seen as early as z∼0.5, could easily lead to an underestimate of the number of merging galaxies at high-redshift in the rest-frame FUV.

The FUV to Near-IR Morphologies of Luminous Infrared Galaxies in the Goals Sample

Science.gov (United States)

Petty, S. M.; Armus, L.; Charmandaris, V.; Evans, A. S.; Le Floc'h, E.; Bridge, C.; Díaz-Santos, T.; Howell, J. H.; Inami, H.; Psychogyios, A.; Stierwalt, S.; Surace, J. A.

2014-12-01

We compare the morphologies of a sample of 20 luminous infrared galaxies (LIRGs) from the Great Observatories All-sky LIRG Survey (GOALS) in the FUV, B, I, and H bands, using the Gini (G) and M20 parameters to quantitatively estimate the distribution and concentration of flux as a function of wavelength. Hubble Space Telescope (HST) images provide an average spatial resolution of ˜ 80 pc. While our LIRGs can be reliably classified as mergers across the entire range of wavelengths studied here, there is a clear shift toward more negative M20 (more bulge-dominated) and a less significant decrease in G values at longer wavelengths. We find no correlation between the derived FUV G-M20 parameters and the global measures of the IR to FUV flux ratio (IRX). Given the fine resolution in our HST data, this suggests either that the UV morphology and IRX are correlated on very small scales, or that the regions emitting the bulk of the IR emission emit almost no FUV light. We use our multi-wavelength data to simulate how merging LIRGs would appear from z˜ 0.5-3 in deep optical and near-infrared images such as the Hubble Ultra-Deep Field, and use these simulations to measure the G-M20 at these redshifts. Our simulations indicate a noticeable decrease in G, which flattens at z≥slant 2 by as much as 40%, resulting in mis-classifying our LIRGs as disk-like, even in the rest-frame FUV. The higher redshift values of M20 for the GOALS sources do not appear to change more than about 10% from the values at z˜ 0. The change in G-M20 is caused by the surface brightness dimming of extended tidal features and asymmetries, and also the decreased spatial resolution which reduced the number of individual clumps identified. This effect, seen as early as z˜ 0.5, could easily lead to an underestimate of the number of merging galaxies at high-redshift in the rest-frame FUV.

The FALCON Concept: Multi-Object Spectroscopy Combined with MCAO in Near-IR

Science.gov (United States)

Hammer, François; Sayède, Frédéric; Gendron, Eric; Fusco, Thierry; Burgarella, Denis; Cayatte, Véronique; Conan, Jean-Marc; Courbin, Frédéric; Flores, Hector; Guinouard, Isabelle; Jocou, Laurent; Lançon, Ariane; Monnet, Guy; Mouhcine, Mustapha; Rigaud, François; Rouan, Daniel; Rousset, Gérard; Buat, Véronique; Zamkotsian, Frédéric

A large fraction of the present-day stellar mass was formed between z=0.5 and z˜ 3 and our understanding of the formation mechanisms at work at these epochs requires both high spatial and high spectral resolution: one shall simultaneously obtain images of objects with typical sizes as small as 1-2 kpc (˜ 0".1), while achieving 20-50 km/s (R≥ 5000) spectral resolution. In addition, the redshift range to be considered implies that most important spectral features are redshifted in the near-infrared. The obvious instrumental solution to adopt in order to tackle the science goal is therefore a combination of multi-object 3D spectrograph with multi-conjugate adaptive optics in large fields. A very promising way to achieve such a technically challenging goal is to relax the conditions of the traditional full adaptive optics correction. A partial, but still competitive correction shall be prefered, over a much wider field of view. This can be done by estimating the turbulent volume from sets of natural guide stars, by optimizing the correction to several and discrete small areas of few arcsec 2 selected in a large field (Nasmyth field of 25 arcmin) and by correcting up to the 6th, and eventually, up to the 60 th Zernike modes. Simulations on real extragalactic fields, show that for most sources (> 80%), the recovered resolution could reach 0".15-0".25 in the J and H bands. Detection of point-like objects is improved by factors from 3 to ≥10, when compared with an instrument without adaptive correction. The proposed instrument concept, FALCON, is equipped with deployable mini-integral field units (IFUs), achieving spectral resolutions between R=5000 and 20000. Its multiplex capability, combined with high spatial and spectral resolution characteristics, is a natural ground based complement to the next generation of space telescopes. Galaxy formation in the early Universe is certainly a main science driver. We describe here how FALCON shall allow to answer puzzling

Near-IR Two-Photon Fluorescent Sensor for K(+) Imaging in Live Cells.

Science.gov (United States)

Sui, Binglin; Yue, Xiling; Kim, Bosung; Belfield, Kevin D

2015-08-19

A new two-photon excited fluorescent K(+) sensor is reported. The sensor comprises three moieties, a highly selective K(+) chelator as the K(+) recognition unit, a boron-dipyrromethene (BODIPY) derivative modified with phenylethynyl groups as the fluorophore, and two polyethylene glycol chains to afford water solubility. The sensor displays very high selectivity (>52-fold) in detecting K(+) over other physiological metal cations. Upon binding K(+), the sensor switches from nonfluorescent to highly fluorescent, emitting red to near-IR (NIR) fluorescence. The sensor exhibited a good two-photon absorption cross section, 500 GM at 940 nm. Moreover, it is not sensitive to pH in the physiological pH range. Time-dependent cell imaging studies via both one- and two-photon fluorescence microscopy demonstrate that the sensor is suitable for dynamic K(+) sensing in living cells.

Spectral density of electron concentration fluctuations in ionospheric D region

International Nuclear Information System (INIS)

Martynenko, S.I.

1989-01-01

Expression for spectral density of electron concentration fluctuations in D-region with regard to the effect of ionization-recombination proceses and negative ions is obtained in terms of atmospheric turbulence model which obeys Kolmogorov-Obukhov 2/3 law

NEAR-INFRARED IMAGING OF THE STAR-FORMING REGIONS SH2-157 AND SH2-152

International Nuclear Information System (INIS)

Chen Yafeng; Yang Ji; Zeng Qin; Yao Yongqiang; Sato, Shuji

2009-01-01

Near-infrared JHK' and H 2 v = 1-0 S (1) imaging observations of the star-forming regions Sh2-157 and Sh2-152 are presented. The data reveal a cluster of young stars associated with H 2 line emission in each region. Additionally, many IR point sources are found in the dense core of each molecular cloud. Most of these sources exhibit infrared color excesses typical of T Tauri stars, Herbig Ae/Be stars, and protostars. Several display the characteristics of massive stars. We calculate histograms of the K'-magnitude and [H - K'] color for all sources, as well as two-color and color-magnitude diagrams. The stellar populations inside and outside the clusters are similar, suggesting that these systems are rather evolved. Shock-driven H 2 emission knots are also detected, which may be related to evident subclusters in an earlier evolutionary stage.

Mid-IR Spectra of Refractory Minerals Relevant to Comets

Science.gov (United States)

Jauhari, Shekeab

2008-09-01

On 4 July 2005 the Spitzer Space Telescope obtained mid-IR ( 5-40 µm) spectra of the ejecta from the hypervelocity impact of the Deep Impact projectile with comet 9P/Tempel 1. Spectral modeling demonstrates that there are abundant minerals present in the ejecta including Ca/Fe/Mg-rich silicates, carbonates, phyllosilicates, water ice, amorphous carbon, and sulfides [1]. However, precise mineralogical identifications are hampered by the lack of comprehensive 5 - 40 µm spectral measurements of the emissivity for a broad compositional range of these materials. Here, we present our initial results for 2 - 50 µm transmission spectra and absorption constants for materials relevant to comets, including pyrrhotite, pyrite, and several phyllosilicate (clay) minerals. Measuring the transmission of materials over the full spectral range sensitive by Spitzer requires grinding the minerals into submicron powders and then mixing them with KBr (for the 1-25 um region) and polyethylene (16-50 um region) to form pellets. Transmission measurements of sub-micron sulfides are particularly difficult to obtain because the minerals oxidize rapidly upon grinding and subsequent handling unless special care is taken. A detailed description of our sample preparation and measurement technique will be provided to assist other researchers in their attempts to acquire similar spectra. References: [1] Lisse, C.M. et al., Science 313, 635 - 640 (2006)

Synthesis and characterization of near IR fluorescent albumin nanoparticles for optical detection of colon cancer

Energy Technology Data Exchange (ETDEWEB)

Cohen, Sarit; Pellach, Michal [Department of Chemistry, Bar-Ilan Institute of Nanotechnology and Advanced Materials, Bar-Ilan University, Ramat-Gan 52900 (Israel); Kam, Yossi [Institute for Drug Research, School of Pharmacy, Faculty of Medicine, The Hebrew University of Jerusalem, P.O. Box 12065, Jerusalem 91120 (Israel); Grinberg, Igor; Corem-Salkmon, Enav [Department of Chemistry, Bar-Ilan Institute of Nanotechnology and Advanced Materials, Bar-Ilan University, Ramat-Gan 52900 (Israel); Rubinstein, Abraham [Institute for Drug Research, School of Pharmacy, Faculty of Medicine, The Hebrew University of Jerusalem, P.O. Box 12065, Jerusalem 91120 (Israel); Margel, Shlomo, E-mail: shlomo.margel@mail.biu.ac.il [Department of Chemistry, Bar-Ilan Institute of Nanotechnology and Advanced Materials, Bar-Ilan University, Ramat-Gan 52900 (Israel)

2013-03-01

Near IR (NIR) fluorescent human serum albumin (HSA) nanoparticles hold great promise as contrast agents for tumor diagnosis. HSA nanoparticles are considered to be biocompatible, non-toxic and non-immunogenic. In addition, NIR fluorescence properties of these nanoparticles are important for in vivo tumor diagnostics, with low autofluorescence and relatively deep penetration of NIR irradiation due to low absorption of biomatrices. The present study describes the synthesis of new NIR fluorescent HSA nanoparticles, by entrapment of a NIR fluorescent dye within the HSA nanoparticles, which also significantly increases the photostability of the dye. Tumor-targeting ligands such as peanut agglutinin (PNA) and anti-carcinoembryonic antigen antibodies (anti-CEA) were covalently conjugated to the NIR fluorescent albumin nanoparticles, increasing the potential fluorescent signal in tumors with upregulated corresponding receptors. Specific colon tumor detection by the NIR fluorescent HSA nanoparticles was demonstrated in a chicken embryo model and a rat model. In future work we also plan to encapsulate cancer drugs such as doxorubicin within the NIR fluorescent HSA nanoparticles for both colon cancer imaging and therapy. - Highlights: Black-Right-Pointing-Pointer Near IR human serum albumin nanoparticles were synthesized and characterized. Black-Right-Pointing-Pointer Nanoparticles were shown to be physically and chemically stable and photostable. Black-Right-Pointing-Pointer Tumor-targeting ligands were covalently conjugated to the nanoparticles. Black-Right-Pointing-Pointer Specific colon cancer tumor detection was demonstrated in chicken-embryo and rat models.

Building up a database of spectro-photometric standard stars from the UV to the near-IR: A status report

NARCIS (Netherlands)

Vernet, J.; Kerber, F.; Saitta, F.; Mainieri, V.; D'Odorico, S.; Lidman, C.; Mason, E.; Bohlin, R.C.; Rauch, T.; Ivanov, V.D.; Smette, A.; Walsh, J.R.; Fosbury, R.A.E.; Goldoni, P.; Groot, P.; Hammer, F.; Horrobin, M.; Kaper, L.; Kjaergaard-Rasmussen, P.; Pallavicini, R.; Royer, F.

2008-01-01

We present a project aimed at establishing a set of 12 spectro-photometric standards over a wide wavelength range from 320 to 2500 nm. Currently no such set of standard stars covering the near-IR is available. Our strategy is to extend the useful range of existing well-established optical flux

Synchronous photoelectrical observations of flare stars in the visible and near infrared ranges

International Nuclear Information System (INIS)

Bruevich, V.V.; Kilyachkov, N.N.; Shevchenko, V.S.; Burnashov, V.I.; Grinin, V.P.; Koryshev, V.V.; Shakhovskaya, N.I.

1980-01-01

The results of synchronous photoelectrical observations of the AD Leo and EV Lac flare stars made in 1975 in the Crimea in B-filter and in the near infrared region (i-band, lambdasub(ef) approximately 0.85 μm) and the observations of the UV Cet and EV Lac stars made in 1976 in the Astronomical Institute Uzbek SSR in three passbands: U, isub(TiO)(lambdasub(ef)=0.71 μ) and isub(C)(lambdasub(ef)=0.80μm) are given. Practically all strong flares in the visible spectral range were followed by the IR-flares. In about 70% of the cases the predicted infrared negative preflares were observed. The amplitudes (in erg/s) of the negative flares are comparable with the amplitude of the optical flares. The analysis of the observed data shows that: a) the amplitudes and the energies of the positive IR flares are in average the larger the stronger is the optical flare; b) the amplitudes of the negative IR preflares are on the contrary the smaller the stronger is the optical flare; c) there are infrared flares the main energy out of which takes place in the infrared range of wavelengths; d) The U-i color shows a positive correlation with the amplitude of the flare in U: the stronger is the flare the bluer is its radiation

SPECTRAL TYPING OF LATE-TYPE STELLAR COMPANIONS TO YOUNG STARS FROM LOW-DISPERSION NEAR-INFRARED INTEGRAL FIELD UNIT DATA

Energy Technology Data Exchange (ETDEWEB)

Roberts, Lewis C.; Beichman, Charles A.; Burruss, Rick; Ligon, E. Robert; Lockhart, Thomas G.; Roberts, Jennifer E.; Shao, Michael [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Rice, Emily L.; Brenner, Douglas; Oppenheimer, Ben R. [American Museum of Natural History, Central Park West at 79th Street, New York, NY 10024 (United States); Crepp, Justin R.; Dekany, Richard G.; Hillenbrand, Lynne A.; Hinkley, Sasha [California Institute of Technology, 1200 East California Boulevard, Pasadena, CA 91125 (United States); King, David; Parry, Ian R. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 OHA (United Kingdom); Metchev, Stanimir [Department of Physics and Astronomy, State University of New York, Stony Brook, NY 11794-3800 (United States); Pueyo, Laurent; Sivaramakrishnan, Anand; Soummer, Remi, E-mail: lewis.c.roberts@jpl.nasa.gov [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); and others

2012-07-15

We used the Project 1640 near-infrared coronagraph and integral field spectrograph to observe 19 young solar-type stars. Five of these stars are known binary stars and we detected the late-type secondaries and were able to measure their JH spectra with a resolution of R {approx} 30. The reduced, extracted, and calibrated spectra were compared to template spectra from the IRTF spectral library. With this comparison, we test the accuracy and consistency of spectral-type determination with the low-resolution near-infrared spectra from P1640. Additionally, we determine effective temperature and surface gravity of the companions by fitting synthetic spectra calculated with the PHOENIX model atmosphere code. We also present several new epochs of astrometry of each of the systems. Together, these data increase our knowledge and understanding of the stellar make up of these systems. In addition to the astronomical results, the analysis presented helps validate the Project 1640 data reduction and spectral extraction processes and the utility of low-resolution, near-infrared spectra for characterizing late-type companions in multiple systems.

FT-IR spectroscopic studies of protein secondary structures for breast cancer diagnosis

International Nuclear Information System (INIS)

Karamancheva, I; Simonova, D.; Milev, A.

2013-01-01

Full text: Roughly 14 million new cancer cases and 8 million cancer deaths have occurred worldwide in 2012. At least 30 % of all cancer cases and 40 % of the cancer deaths should be avoided by improving the early detection. Fourier transform infrared (FT-IR) spectroscopy has shown many advantages as a tool for the detection of cancer over the traditional methods such as histopathological analysis, X-ray transmission, ultrasonic and computer tomography techniques. With the aim to establish the FT-IR spectroscopy as an alternative method for the diagnosis of human cancers, we have made several studies to examine in details the spectroscopic properties of normal and carcinomatous tissues. Human breast tissues were obtained immediately after surgical breast resection with the informed patient's consent. In our studies we made extensive use of Fourier self-deconvolution, second-order derivatization, difference spectra, curve-fitting procedures and quantitative determinations according to Beer's law. Cancer is a multi-step process. Characteristic differences in both the frequencies and the intensity ratios of several bands have been revealed. Considerable differences have been found in the spectral patterns. The most important and informative region in the mid-IR for determination of protein secondary structure is the amide I and amide II region. The bands between 1730 and 1600 cm -1 are highly sensitive to conformational changes. Considerable changes were observed in the A1735/A1652 absorbance ratio, which provides a measure for the content of a- helix and P-sheet domains. Our investigations have shown that the major biomarker peaks are in the amide I and amide II regions. In the so called 'fingerprint region' many molecular constituents such as lipids, phospholipids, proteins, DNA and RNA, carbohydrates and metabolites may overlap and the quantitative interpretation is impossible. The spectrum may therefore reflect only the average biochemical composition.; key words

The Effect of Epidermal Structures on Leaf Spectral Signatures of Ice Plants (Aizoaceae

Directory of Open Access Journals (Sweden)

René Hans-Jürgen Heim

2015-12-01

Full Text Available Epidermal structures (ES of leaves are known to affect the functional properties and spectral responses. Spectral studies focused mostly on the effect of hairs or wax layers only. We studied a wider range of different ES and their impact on spectral properties. Additionally, we identified spectral regions that allow distinguishing different ES. We used a field spectrometer to measure ex situ leaf spectral responses from 350 nm–2500 nm. A spectral library for 25 species of the succulent family Aizoaceae was assembled. Five functional types were defined based on ES: flat epidermal cell surface, convex to papillary epidermal cell surface, bladder cells, hairs and wax cover. We tested the separability of ES using partial least squares discriminant analysis (PLS-DA based on the spectral data. Subsequently, variable importance (VIP was calculated to identify spectral regions relevant for discriminating our functional types (classes. Classification performance was high, with a kappa value of 0.9 indicating well-separable spectral classes. VIP calculations identified six spectral regions of increased importance for the classification. We confirmed and extended previous findings regarding the visible-near-infrared spectral region. Our experiments also confirmed that epidermal leaf traits can be classified due to clearly distinguishable spectral signatures across species and genera within the Aizoaceae.

Magnetorefractive effect in manganites with a colossal magnetoresistance in the visible spectral region

International Nuclear Information System (INIS)

Sukhorukov, Yu. P.; Telegin, A. V.; Granovsky, A. B.; Gan’shina, E. A.; Zhukov, A.; Gonzalez, J.; Herranz, G.; Caicedo, J. M.; Yurasov, A. N.; Bessonov, V. D.; Kaul’, A. R.; Gorbenko, O. Yu.; Korsakov, I. E.

2012-01-01

The magnetotransmission, magnetoreflection, and magnetoresistance of the La 0.7 Ca 0.3 MnO 3 and La 0.9 Ag 0.1 MnO 3 epitaxial films have been investigated. It has been found that the films exhibit a significant magnetorefractive effect in the case of reflection and transmission of light in the fundamental absorption region both in the vicinity of the Curie temperature and at low temperatures. It has been shown that the magnetorefractive effect in the infrared spectral region of the manganites is determined by a high-frequency response to magnetoresistance, whereas the magnetorefractive effect in the visible spectral region of these materials is associated with a change in the electronic structure in response to a magnetic field, which, in turn, leads to a change in the electron density of states, the probability of interband optical transitions, and the shift of light absorption bands. The obtained values of the magnetotransmittance and magnetoreflectance in the visible spectral region are less than those observed in the infrared region of the spectrum, but they are several times greater than the linear magneto-optical effects. As a result, the magnetorefractive effect, which is a nongyrotropic phenomenon, makes it possible to avoid the use of light analyzers and polarizers in optical circuits.

Influence of the core-hole effect on optical properties of magnesium oxide (MgO) near the Mg L-edge region.

Science.gov (United States)

Sinha, Mangalika; Modi, Mohammed H; Ghosh, Haranath; Yadav, P K; Gupta, R K

2018-05-01

The influence of the core-hole effect on optical properties of magnesium oxide (MgO) is established through experimental determination of optical constants and first-principles density functional theory studies. Optical constants (δ and β) of MgO thin film are measured in the spectral region 40-300 eV using reflectance spectroscopy techniques at the Indus-1 synchrotron radiation source. The obtained optical constants show strong core exciton features near the Mg L-edge region, causing significant mismatch with Henke's tabulated values. On comparing the experimentally obtained optical constants with Henke's tabulated values, an edge shift of ∼3.0 eV is also observed. Distinct evidence of effects of core exciton on optical constants (δ and β) in the near Mg L-edge absorption spectra are confirmed through first-principles simulations.

Spectral analysis and compositing techniques for the Near Earth Asteroid Rendezvous (NEAR Shoemaker), X-ray and Gamma-Ray Spectrometers (XGRS)

CERN Document Server

McClanahan, T P; Nittler, L R; Boynton, W V; Bruckner, J; Squyres, S W; Evans, L G; Bhangoo, J S; Clark, P E; Floyd, S R; McCartney, E; Mikheeva, I; Starr, R D

2001-01-01

An X-ray and Gamma-Ray Spectrometer (XGRS) is on board the Near Earth Asteroid Rendezvous (NEAR) spacecraft to determine the elemental composition of the surface of the asteroid 433 Eros. The Eros asteroid is highly oblate and irregular in shape. As a result, analysis methodologies are in many ways a divergence from comparable techniques. Complex temporal, spatial and instrument performance relationships must be accounted for during the analysis process. Field of view and asteroid surface geometry measurements must be modeled and then combined with real measurements of solar, spectral and instrument calibration information to derive scientific results. NEAR is currently orbiting 433 Eros and is in the initial phases of its primary data integration and mapping phases. Initial results have been obtained and bulk chemistry assessments have been obtained through specialized background assessment and data reduction techniques.

A variable-tune spatial heterodyne spectrometer for broadband spectral line studies in the visible and near-UV

Science.gov (United States)

Dawson, Olivia R.; Harris, Walter M.

2017-11-01

Reflective Spatial Heterodyne Spectroscopy (SHS) is an interferometric technique that combines high resolving power and a large input acceptance angle in a format that is compact enough for use at small telescope focal planes and in spacecraft observations of targets in the visible to far ultra-violet (FUV) spectral range. SHS instruments are well suited to the study of faint, extended emission line sources, particularly in the UV where stellar background continuum becomes weak. Their primary limitation comes from the limited spatial sampling of the output interference pattern generated by the incoming spectral source, which limits their use to narrow bandpass near the central tuning wavelength. We describe a the first light results from a broadband SHS that can be used to scan the tuning wavelength across a bandpass extending from 300 to 700 nm. The limitations on the bandpass are arbitrary and can easily be extended into the UV or near infrared. We discuss the results of these validation program and the potential improvements that could be used to expand and/or improve the broadband spectral response of the instrument.

Spectral variation of the solar radiation during an eclipse

Directory of Open Access Journals (Sweden)

Peter Koepke

2001-05-01

Full Text Available The time dependent variation of the spectral extraterrestrial solar flux is modelled for the conditions during a total eclipse. These data are used to calculate irradiance and actinic flux at the Earth’s surface for atmospheric conditions of August 11, 1999 at Weihenstephan. These results are compared with measurements. It is shown, that the spectral composition of solar radiation varies during the eclipse, since solar limb darkening has a spectral dependence. The solar radiation differs from that of a hypothetical sun without limb darkening by up to 30% in the near IR at 1500 nm and 60% in the UV-B at 310 nm. As shown by a comparison of modelling and measurements, this spectral variation has to be taken into account for modelling of UV radiative quantities in the atmosphere and resulting photochemical processes. The effect of broken cloudiness on irradiance and actinic flux and its dependency on wavelength and receiver geometry is explained. Der Verlauf der spektralen extraterrestrischen solaren Strahlung wÄhrend einer Sonnenfinsternis wurde berechnet. Basierend auf diesen Daten, unter BerÜcksichtigung der atmosphÄrischen Bedingungen am 11. August 1999 in Weihenstephan, wurden Globalstrahlung und Aktinischer Fluss am Boden modelliert und mit Messwerten verglichen. Die spektrale Zusammensetzung der Strahlung Ändert sich wÄhrend einer Sonnenfinsternis, bedingt durch die wellenlÄngenabhÄngige Randverdunklung der Sonne. Im Vergleich zu einer hypothetischen Sonne ohne Randverdunklung ist die solare Strahlung im nahen IR um bis zu 30% gemindert und im UVB bei 310 nm um bis zu 60%. Diese spektralen Änderungen sollten bei der Modellierung von Strahlung, z.B. fÜr photochemische Prozesse berÜcksichtigt werden. Dies wurde durch Messung und Modellierung gezeigt. Der Einfluss von Wolken auf gemessene Werte von Globalstrahlung und Aktinischem Fluss wurde untersucht und erklÄrt.

Impact of spectral nudging on regional climate simulation over CORDEX East Asia using WRF

Science.gov (United States)

Tang, Jianping; Wang, Shuyu; Niu, Xiaorui; Hui, Pinhong; Zong, Peishu; Wang, Xueyuan

2017-04-01

In this study, the impact of the spectral nudging method on regional climate simulation over the Coordinated Regional Climate Downscaling Experiment East Asia (CORDEX-EA) region is investigated using the Weather Research and Forecasting model (WRF). Driven by the ERA-Interim reanalysis, five continuous simulations covering 1989-2007 are conducted by the WRF model, in which four runs adopt the interior spectral nudging with different wavenumbers, nudging variables and nudging coefficients. Model validation shows that WRF has the ability to simulate spatial distributions and temporal variations of the surface climate (air temperature and precipitation) over CORDEX-EA domain. Comparably the spectral nudging technique is effective in improving the model's skill in the following aspects: (1), the simulated biases and root mean square errors of annual mean temperature and precipitation are obviously reduced. The SN3-UVT (spectral nudging with wavenumber 3 in both zonal and meridional directions applied to U, V and T) and SN6 (spectral nudging with wavenumber 6 in both zonal and meridional directions applied to U and V) experiments give the best simulations for temperature and precipitation respectively. The inter-annual and seasonal variances produced by the SN experiments are also closer to the ERA-Interim observation. (2), the application of spectral nudging in WRF is helpful for simulating the extreme temperature and precipitation, and the SN3-UVT simulation shows a clear advantage over the other simulations in depicting both the spatial distributions and inter-annual variances of temperature and precipitation extremes. With the spectral nudging, WRF is able to preserve the variability in the large scale climate information, and therefore adjust the temperature and precipitation variabilities toward the observation.

Laboratory Thermal Infrared and Visible to Near-Infrared Spectral Analysis of Chert

Science.gov (United States)

McDowell, M. L.; Hamilton, V. E.

2007-12-01

Though basaltic materials dominate the composition of the Martian surface, a material with a relatively high silica component in an area of Eos Chasma was reported by [1] from thermal infrared (TIR) data. The spectrum of the silica phase resembles quartz or chert, but with the existing information it is difficult to tell which phase best fits the observations. Though quartz, chert, and amorphous silica are chemically identical (SiO2), their physical differences (e.g., microstructures) result in different TIR spectral characteristics. Previous studies have analyzed a limited number of chert samples using emission infrared spectroscopy [2] and transmission infrared spectroscopy [3]. We continue these preliminary studies with an investigation aiming to more completely understand and document the variation in spectral character of cherts. This knowledge may help to identify the silica phase in Eos Chasma and any future discoveries. Our study includes a more extensive sampling of geologic chert in hand sample (>15 samples) with various sources, methods of formation, surface textures, and crystallinities. We analyzed their visible to near-infrared (VNIR) reflectance spectra, as well as spectral features in TIR emission spectra. We measured multiple locations on each sample to determine spectral homogeneity across the sample and between various orientations. Where possible, natural, cut, and recently fractured surfaces were measured. We compared the collected TIR spectra for similarities and differences in shape and spectral contrast within each sample and between samples that may relate to variations in the samples' structure (e.g. crystallinity, and surface texture). VNIR measurements show features indicative of non-silica phases and water that may be present in the cherts. [1] Hamilton, V.E. (2005) Eos Trans. AGU, Fall Meeting Suppl., Abstract P24A-08. [2] Michalski, J.R. (2005) PhD Diss., ASU, Tempe. [3] Long, D. G. et al. (2001) Canadian Archaeological Assoc., 33rd

Gaseous effluent monitoring and identification using an imaging Fourier transform spectrometer

Energy Technology Data Exchange (ETDEWEB)

Carter, M.R.; Bennett, C.L.; Fields, D.J.; Hernandez, J.

1993-10-01

We are developing an imaging Fourier transform spectrometer for chemical effluent monitoring. The system consists of a 2-D infrared imaging array in the focal plane of a Michelson interferometer. Individual images are coordinated with the positioning of a moving mirror in the Michelson interferometer. A three dimensional data cube with two spatial dimensions and one interferogram dimension is then Fourier transformed to produce a hyperspectral data cube with one spectral dimension and two spatial dimensions. The spectral range of the instrument is determined by the choice of optical components and the spectral range of the focal plane array. Measurements in the near UV, visible, near IR, and mid-IR ranges are possible with the existing instrument. Gaseous effluent monitoring and identification measurements will be primarily in the ``fingerprint`` region of the spectrum, ({lambda} = 8 to 12 {mu}m). Initial measurements of effluent using this imaging interferometer in the mid-IR will be presented.

Faecal near-IR spectroscopy to determine the nutritional value of diets consumed by beef cattle in east Mediterranean rangelands.

Science.gov (United States)

Landau, S Y; Dvash, L; Roudman, M; Muklada, H; Barkai, D; Yehuda, Y; Ungar, E D

2016-02-01

Rapid assessment of the nutritional quality of diets ingested by grazing animals is pivotal for successful cow-calf management in east Mediterranean rangelands, which receive unpredictable rainfall and are subject to hot-spells. Clipped vegetation samples are seldom representative of diets consumed, as cows locate and graze selectively. In contrast, faeces are easily sampled and their near-IR spectra contain information about nutrients and their utilization. However, a pre-requisite for successful faecal near-infrared reflectance spectroscopy (FNIRS) is that the calibration database encompass the spectral variability of samples to be analyzed. Using confined beef cows in Northern and Southern Israel, we calibrated prediction equations based on individual pairs of known dietary attributes and the NIR spectra of associated faeces (n=125). Diets were composed of fresh-cut green fodder of monocots (wheat and barley), dicots (safflower and garden pea) and natural pasture collected at various phenological states over 2 consecutive years, and, optionally, supplements of barley grain and dried poultry litter. A total of 48 additional pairs of faeces and diets sourced from cows fed six complete mixed rations covering a wide range of energy and CP concentrations. Precision (linearity of calibration, R2cal, and of cross-validation, R2cv) and accuracy (standard error of cross-validation, SEcv) were criteria for calibration quality. The calibrations for dietary ash, CP, NDF and in vitro dry matter digestibility yielded R2cal values >0.87, R2cv of 0.81 to 0.89 and SEcv values of 16, 13, 39 and 31 g/kg dry matter, respectively. Equations for nutrient intake were of low quality, with the exception of CP. Evaluation of FNIRS predictions was carried out with grazing animals supplemented or not with poultry litter, and implementation of the method in one herd over 2 years is presented. The potential usefulness of equations was also established by calculating the Mahalanobis (H

Fundamental observations concerning hysteresis in the deformation of intact and jointed rock with applications to nonlinear attenuation in the near source region

International Nuclear Information System (INIS)

Boitnott, G.N.

1993-01-01

In order to estimate yields of large underground explosions, it is important that we have a clear understanding of the near source phenomena and their effects on regional and teleseismic signals. While it is generally accepted that a considerable amount of attenuation and resultant waveform distortion occurs due to nonlinear deformation near the source, an area that has received little attention is the broad enveloping region where moderate stress perturbations occur. In this region, where strain perturbation amplitudes range from microstrains to a few millistrains, the resulting deformation of rock is inelastic and nonlinear but little to no permanent deformation results. Owing to its great extent, the moderate strain regime has the potential to influence the entire frequency band of the regional and teleseismic signals and thus may be central to the problem of inferring source characteristics from far field signals. Detailed rheological descriptions are required in order to understand the effects of the nonlinearities on the spectral content of regional and teleseismic signals

Suppression of superconductivity in Nb by IrMn in IrMn/Nb bilayers

KAUST Repository

Wu, B. L.

2013-10-10

Effect of antiferromagnet on superconductivity has been investigated in IrMn/Nb bilayers. Significant suppression of both transition temperature (Tc) and lower critical field (Hc1) of Nb is found in IrMn/Nb bilayers as compared to a single layer Nb of same thickness; the suppression effect is even stronger than that of a ferromagnet in NiFe/Nb bilayers. The addition of an insulating MgO layer at the IrMn-Nb interface nearly restores Tc to that of the single layer Nb, but Hc1 still remains suppressed. These results suggest that, in addition to proximity effect and magnetic impurity scattering, magnetostatic interaction also plays a role in suppressing superconductivity of Nb in IrMn/Nb bilayers. In addition to reduced Tc and Hc1, the IrMn layer also induces broadening in the transition temperature of Nb, which can be accounted for by a finite distribution of stray field from IrMn.

Ngc7538 Irs1 - A Highly Collimated Ionized Wind Source Powered By Accretion

Science.gov (United States)

Sandell, Goran H. L.; Wright, M.; Goss, W.; Corder, S.

2009-01-01

Recent images show that NGC7538 IRS1 is not a conventional Ultracompact or Hypercompact HII region, but is completely wind-excited (other broad recombination line hypercompact HII regions may be similar to IRS1). NGC 7538 IRS1 is a well studied young high-mass star (L 2 10^5 L_Sun).VLA images at 6 and 2 cm (Cambell 1984; ApJ, 282, L27) showed a compact bipolar core (lobe separation 0.2") with more extended faint lobes. Recombination line observations (Gaume et al. 1995, ApJ, 438, 776) show extremely wide line profiles indicating substantial mass motion of the ionized gas. We re-analyzed high angular resolution VLA archive data from 6 cm to 7 mm, and measured the flux from the compact core and the extended (1.5 - 2") bipolar lobes. We find that the compact core has a spectral index, alpha 0.6, which could be explained by an optically thick hypercompact core with a density gradient. However, the size of the core shrinks with increasing frequency; from 0.24" at 6 cm to 0.1" at 7 mm, consistent with that expected for a collimated jet (Reynolds 1986, ApJ, 304, 713). If we do a crude size correction so that we compare emission from the optically thick inner part of the jet for a set of 2 cm and 7 mm observations we get alpha 1.6, i.e. close to the optically thick value. BIMA and CARMA continuum observations at 3 mm show some dust excess, while. HCO+ J=1-0 observations combined with FCRAO single dish data show a clear inverse P Cygni profile towards IRS1. These observations confirm that IRS1 is heavily accreting with an accretion rate 2 10^-4 M_Sun/year, sufficient to quench the formation of an HII region.

On the Spatially Resolved Star Formation History in M51. I. Hybrid UV+IR Star Formation Laws and IR Emission from Dust Heated by Old Stars

Science.gov (United States)

Eufrasio, R. T.; Lehmer, B. D.; Zezas, A.; Dwek, E.; Arendt, R. G.; Basu-Zych, A.; Wiklind, T.; Yukita, M.; Fragos, T.; Hornschemeier, A. E.; Markwardt, L.; Ptak, A.; Tzanavaris, P.

2017-12-01

We present LIGHTNING, a new spectral energy distribution fitting procedure, capable of quickly and reliably recovering star formation history (SFH) and extinction parameters. The SFH is modeled as discrete steps in time. In this work, we assumed lookback times of 0-10 Myr, 10-100 Myr, 0.1-1 Gyr, 1-5 Gyr, and 5-13.6 Gyr. LIGHTNING consists of a fully vectorized inversion algorithm to determine SFH step intensities and combines this with a grid-based approach to determine three extinction parameters. We apply our procedure to the extensive far-UV-to-far-IR photometric data of M51, convolved to a common spatial resolution and pixel scale, and make the resulting maps publicly available. We recover, for M51a, a peak star formation rate (SFR) between 0.1 and 5 Gyr ago, with much lower star formation activity over the past 100 Myr. For M51b, we find a declining SFR toward the present day. In the outskirt regions of M51a, which includes regions between M51a and M51b, we recover an SFR peak between 0.1 and 1 Gyr ago, which corresponds to the effects of the interaction between M51a and M51b. We utilize our results to (1) illustrate how UV+IR hybrid SFR laws vary across M51 and (2) provide first-order estimates for how the IR luminosity per unit stellar mass varies as a function of the stellar age. From the latter result, we find that IR emission from dust heated by stars is not always associated with young stars and that the IR emission from M51b is primarily powered by stars older than 5 Gyr.

The near-infrared broad emission line region of active galactic nuclei - II. The 1-μm continuum

Science.gov (United States)

Landt, Hermine; Elvis, Martin; Ward, Martin J.; Bentz, Misty C.; Korista, Kirk T.; Karovska, Margarita

2011-06-01

We use quasi-simultaneous near-infrared (near-IR) and optical spectroscopy from four observing runs to study the continuum around 1 μm in 23 well-known broad emission line active galactic nuclei (AGN). We show that, after correcting the optical spectra for host galaxy light, the AGN continuum around this wavelength can be approximated by the sum of mainly two emission components, a hot dust blackbody and an accretion disc. The accretion disc spectrum appears to dominate the flux at ˜ 1 μm, which allows us to derive a relation for estimating AGN black hole masses based on the near-IR virial product. This result also means that a near-IR reverberation programme can determine the AGN state independent of simultaneous optical spectroscopy. On average we derive hot dust blackbody temperatures of ˜1400 K, a value close to the sublimation temperature of silicate dust grains, and relatively low hot dust covering factors of ˜7 per cent. Our preliminary variability studies indicate that in most sources, the hot dust emission responds to changes in the accretion disc flux with the expected time lag; however, a few sources show a behaviour that can be attributed to dust destruction.

Near-Infrared Spectrophotometry of Phobos and Deimos

Science.gov (United States)

Rivkin, A. S.; Brown, R. H.; Trilling, D. E.; Bell, J. F., III; Plassmann, J. H.

2002-01-01

We have observed the leading and trailing hemispheres of Phobos from 1.65 to 3.5 microns and Deimos from 1.65 to 3.12 microns near opposition. We find the trailing hemisphere of Phobos to be brighter than its leading hemisphere by 0.24 +/- 0.06 magnitude at 1.65 microns and brighter than Deimos by 0.98 +/- 0.07 magnitude at 1.65 microns. We see no difference larger than observational uncertainties in spectral slope between the leading and trailing hemispheres when the spectra are normalized to 1.65 microns. We find no 3-microns absorption feature due to hydrated minerals on either hemisphere to a level of approx. 5 - 10% on Phobos and approx. 20% on Deimos. When the infrared data are joined to visible and near-IR data obtained by previous workers, our data suggest the leading (Stickney-dominated) side of Phobos is best matched by T-class asteroids. The spectral slope of the trailing side of Phobos and leading side of Deimos are bracketed by the D-class asteroids. The best laboratory spectral matches to these parts of Phobos are mature lunar soils and heated carbonaceous chondrites. The lack of 3-microns absorption features on either side of Phobos argues against the presence of a large interior reservoir of water ice according to current models of Phobos' interior.

Green's function asymptotics near the internal edges of spectra of periodic elliptic operators. Spectral edge case

KAUST Repository

Kuchment, Peter

2012-06-21

Precise asymptotics known for the Green\\'s function of the Laplace operator have found their analogs for periodic elliptic operators of the second order at and below the bottom of the spectrum. Due to the band-gap structure of the spectra of such operators, the question arises whether similar results can be obtained near or at the edges of spectral gaps. As the result of this work shows, this is possible at a spectral edge when the dimension d ≥ 3. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Green's function asymptotics near the internal edges of spectra of periodic elliptic operators. Spectral edge case

KAUST Repository

Kuchment, Peter; Raich, Andrew

2012-01-01

Precise asymptotics known for the Green's function of the Laplace operator have found their analogs for periodic elliptic operators of the second order at and below the bottom of the spectrum. Due to the band-gap structure of the spectra of such operators, the question arises whether similar results can be obtained near or at the edges of spectral gaps. As the result of this work shows, this is possible at a spectral edge when the dimension d ≥ 3. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Spectral composition of shortwave radiation reflected and deep penetrating into snow near the Barentsburg settlement (Svalbard

Directory of Open Access Journals (Sweden)

P. N. Svyashchennikov

2015-01-01

Full Text Available Data on spectral composition of shortwave radiation that is reflected from snow and penetrates deep into the snow cover obtained near the Barentsburg settlement (Svalbard are discussed in the paper. Measurements were made by the use of the spectral radiometer TriOS Ramses within the wavelength range of 280–950 nm. The results will allow more proper taking account of the anthropogenic pollution effects on the radiative properties of snow cover under conditions of industrial activity related to the coal extraction and burning in Barentsburg.

High spatial and spectral resolution measurements of Jupiter's auroral regions using Gemini-North-TEXES

Science.gov (United States)

Sinclair, J. A.; Orton, G. S.; Greathouse, T. K.; Lacy, J.; Giles, R.; Fletcher, L. N.; Vogt, M.; Irwin, P. G.

2017-12-01

Jupiter exhibits auroral emission at a multitude of wavelengths. Auroral emission at X-ray, ultraviolet and near-infrared wavelengths demonstrate the precipitation of ion and electrons in Jupiter's upper atmosphere, at altitudes exceeding 250 km above the 1-bar level. Enhanced mid-infrared emission of CH4, C2H2, C2H4 and further hydrocarbons is also observed coincident with Jupiter's auroral regions. Retrieval analyses of infrared spectra from IRTF-TEXES (Texas Echelon Cross Echelle Spectrograph on NASA's Infrared Telescope Facility) indicate strong heating at the 1-mbar level and evidence of ion-neutral chemistry, which enriches the abundances of unsaturated hydrocarbons (Sinclair et al., 2017b, doi:10.1002/2017GL073529, Sinclair et al., 2017c (under review)). The extent to which these phenomena in the stratosphere are correlated and coupled physically with the shorter-wavelength auroral emission originating from higher altitudes has been a challenge due to the limited spatial resolution available on the IRTF. Smaller-scale features observed in the near-infrared and ultraviolet emission, such as the main `oval', transient `swirls' and dusk-active regions within the main oval (e.g. Stallard et al., 2014, doi:10.1016/j/Icarus.2015.12.044, Nichols et al., 2017, doi: 10.1002/2017GL073029) are potentially being blurred in the mid-infrared by the diffraction-limited resolution (0.7") of IRTF's 3-metre primary aperture. However, on March 17-19th 2017, we obtained spectral measurements of H2 S(1), CH4, C2H2, C2H4 and C2H6 emission of Jupiter's high latitudes using TEXES on Gemini-North, which has a 8-metre primary aperture. This rare opportunity combines the superior spectral resolving power of TEXES and the high spatial resolution provided by Gemini-North's 8-metre aperture. We will perform a retrieval analyses to determine the 3D distributions of temperature, C2H2, C2H4 and C2H6. The morphology will be compared with near-contemporaneous measurements of H3+ emission from

Communication: Enhanced oxygen reduction reaction and its underlying mechanism in Pd-Ir-Co trimetallic alloys

Energy Technology Data Exchange (ETDEWEB)

Ham, Hyung Chul; Hwang, Gyeong S., E-mail: gshwang@che.utexas.edu [Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712 (United States); Manogaran, Dhivya [Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, Texas 78712 (United States); Lee, Kang Hee; Jin, Seon-ah; You, Dae Jong; Pak, Chanho [Energy Lab, Samsung Advanced Institute of Technology, Samsung Electronics Co., Ltd., Suwon (Korea, Republic of); Kwon, Kyungjung [Department of Energy and Mineral Resources Engineering, Sejong University, Seoul 143-747 (Korea, Republic of)

2013-11-28

Based on a combined density functional theory and experimental study, we present that the electrochemical activity of Pd{sub 3}Co alloy catalysts toward oxygen reduction reaction (ORR) can be enhanced by adding a small amount of Ir. While Ir tends to favorably exist in the subsurface layers, the underlying Ir atoms are found to cause a substantial modification in the surface electronic structure. As a consequence, we find that the activation barriers of O/OH hydrogenation reactions are noticeably lowered, which would be mainly responsible for the enhanced ORR activity. Furthermore, our study suggests that the presence of Ir in the near-surface region can suppress Co out-diffusion from the Pd{sub 3}Co substrate, thereby improving the durability of Pd-Ir-Co catalysts. We also discuss the relative roles played by Ir and Co in enhancing the ORR activity relative to monometallic Pd catalysts.

Communication: Enhanced oxygen reduction reaction and its underlying mechanism in Pd-Ir-Co trimetallic alloys

International Nuclear Information System (INIS)

Ham, Hyung Chul; Hwang, Gyeong S.; Manogaran, Dhivya; Lee, Kang Hee; Jin, Seon-ah; You, Dae Jong; Pak, Chanho; Kwon, Kyungjung

2013-01-01

Based on a combined density functional theory and experimental study, we present that the electrochemical activity of Pd 3 Co alloy catalysts toward oxygen reduction reaction (ORR) can be enhanced by adding a small amount of Ir. While Ir tends to favorably exist in the subsurface layers, the underlying Ir atoms are found to cause a substantial modification in the surface electronic structure. As a consequence, we find that the activation barriers of O/OH hydrogenation reactions are noticeably lowered, which would be mainly responsible for the enhanced ORR activity. Furthermore, our study suggests that the presence of Ir in the near-surface region can suppress Co out-diffusion from the Pd 3 Co substrate, thereby improving the durability of Pd-Ir-Co catalysts. We also discuss the relative roles played by Ir and Co in enhancing the ORR activity relative to monometallic Pd catalysts

Magnetorefractive effect in manganites with a colossal magnetoresistance in the visible spectral region

Energy Technology Data Exchange (ETDEWEB)

Sukhorukov, Yu. P., E-mail: suhorukov@imp.uran.ru; Telegin, A. V. [Russian Academy of Sciences, Institute of Metal Physics, Ural Branch (Russian Federation); Granovsky, A. B., E-mail: granov@magn.ru; Gan' shina, E. A. [Moscow State University, Faculty of Physics (Russian Federation); Zhukov, A.; Gonzalez, J. [Universidad del Pais Vasco (UPV)/Euskal Herriko Unibertsitatea (EHU), Departamento de Fisica de Materiales, Facultad de Quimica (Spain); Herranz, G. [Institut de Ciencia de Materials de Barcelona (ICMAB)-CSIC (Spain); Caicedo, J. M. [Universidad del Pais Vasco (UPV)/Euskal Herriko Unibertsitatea (EHU), Departamento de Fisica de Materiales, Facultad de Quimica (Spain); Yurasov, A. N. [Moscow State Institute of Radio-Engineering, Electronics, and Automation (Technical University) (Russian Federation); Bessonov, V. D. [Russian Academy of Sciences, Institute of Metal Physics, Ural Branch (Russian Federation); Kaul' , A. R.; Gorbenko, O. Yu.; Korsakov, I. E. [Moscow State University, Faculty of Physics (Russian Federation)

2012-01-15

The magnetotransmission, magnetoreflection, and magnetoresistance of the La{sub 0.7}Ca{sub 0.3}MnO{sub 3} and La{sub 0.9}Ag{sub 0.1}MnO{sub 3} epitaxial films have been investigated. It has been found that the films exhibit a significant magnetorefractive effect in the case of reflection and transmission of light in the fundamental absorption region both in the vicinity of the Curie temperature and at low temperatures. It has been shown that the magnetorefractive effect in the infrared spectral region of the manganites is determined by a high-frequency response to magnetoresistance, whereas the magnetorefractive effect in the visible spectral region of these materials is associated with a change in the electronic structure in response to a magnetic field, which, in turn, leads to a change in the electron density of states, the probability of interband optical transitions, and the shift of light absorption bands. The obtained values of the magnetotransmittance and magnetoreflectance in the visible spectral region are less than those observed in the infrared region of the spectrum, but they are several times greater than the linear magneto-optical effects. As a result, the magnetorefractive effect, which is a nongyrotropic phenomenon, makes it possible to avoid the use of light analyzers and polarizers in optical circuits.

Effects of Heavy Ions on ULF Wave Resonances Near the Equatorial Region

International Nuclear Information System (INIS)

Lee, D.-H.; Johnson, J.R.; Kim, K.; Kim, K.-S.

2008-01-01

Pc1-2 ULF waves are strongly associated with the presence of various ions in the magnetosphere. We investigate the role of heavy ion resonances in nonuniform plasmas near the equatorial region. By adopting the invariant imbedding method, the coupled plasma wave equations are solved in an exact manner to calculate the resonant absorption at the ion-ion hybrid resonance. Our results show that irreversible mode conversion occurs at the resonance, which absorbs the fast wave energy. It is found that waves near the resonances appear with linear polarization, and their amplitude and frequency are sensitive to the properties of the heavy ion plasma composition. We examine how these resonances occur for various H+ - He+ populations in detail by performing an accurate calculation of the mode conversion efficiency. Because the multi-ion hybrid resonance locations in cold plasmas are determined by simple parameters such as the fraction of the ion number density of each species and the magnetic field, we suggest that it is possible to monitor heavy ion composition by examining the peak frequencies of linearly polarized wave events in either electric field or magnetic field spectral data

Effects of Heavy Ions on ULF Wave Resonances Near the Equatorial Region

Energy Technology Data Exchange (ETDEWEB)

D.-H.Lee, J.R. Johnson, K. Kim and K.-S.Kim

2008-11-20

Pc1-2 ULF waves are strongly associated with the presence of various ions in the magnetosphere. We investigate the role of heavy ion resonances in nonuniform plasmas near the equatorial region. By adopting the invariant imbedding method, the coupled plasma wave equations are solved in an exact manner to calculate the resonant absorption at the ion-ion hybrid resonance. Our results show that irreversible mode conversion occurs at the resonance, which absorbs the fast wave energy. It is found that waves near the resonances appear with linear polarization, and their amplitude and frequency are sensitive to the properties of the heavy ion plasma composition. We examine how these resonances occur for various H+ - He+ populations in detail by performing an accurate calculation of the mode conversion effciency. Because the multi-ion hybrid resonance locations in cold plasmas are determined by simple parameters such as the fraction of the ion number density of each species and the magnetic field, we suggest that it is possible to monitor heavy ion composition by examining the peak frequencies of linearly polarized wave events in either electric field or magnetic field spectral data.

Data fusion of Landsat TM and IRS images in forest classification

Science.gov (United States)

Guangxing Wang; Markus Holopainen; Eero Lukkarinen

2000-01-01

Data fusion of Landsat TM images and Indian Remote Sensing satellite panchromatic image (IRS-1C PAN) was studied and compared to the use of TM or IRS image only. The aim was to combine the high spatial resolution of IRS-1C PAN to the high spectral resolution of Landsat TM images using a data fusion algorithm. The ground truth of the study was based on a sample of 1,020...

Improved mid infrared detector for high spectral or spatial resolution and synchrotron radiation use

Energy Technology Data Exchange (ETDEWEB)

Faye, Mbaye; Bordessoule, Michel; Kanouté, Brahim; Brubach, Jean-Blaise; Roy, Pascale [Synchrotron SOLEIL, L’Orme des Merisiers, F-91192 Gif-sur-Yvette (France); Manceron, Laurent [Synchrotron SOLEIL, L’Orme des Merisiers, F-91192 Gif-sur-Yvette (France); Laboratoire MONARIS, CNRS-Université Pierre et Marie Curie, UMR 8233, 4 Place Jussieu, F-75252 Paris Cedex (France)

2016-06-15

When using bright, small effective size sources, such as synchrotron radiation light beam, for broadband spectroscopy at spectral or spatial high resolution for mid-IR FTIR measurements, a marked detectivity improvement can be achieved by setting up a device matching the detector optical étendue to that of the source. Further improvement can be achieved by reducing the background unmodulated flux and other intrinsic noise sources using a lower temperature cryogen, such as liquid helium. By the combined use of cooled apertures, cold reimaging optics, filters and adapted detector polarization, and preamplification electronics, the sensitivity of a HgCdTe photoconductive IR detector can be improved by a significant factor with respect to standard commercial devices (more than one order of magnitude on average over 6–20 μm region) and the usable spectral range extended to longer wavelengths. The performances of such an optimized detector developed on the AILES Beamline at SOLEIL are presented here.

Beam alignment based on two-dimensional power spectral density of a near-field image.

Science.gov (United States)

Wang, Shenzhen; Yuan, Qiang; Zeng, Fa; Zhang, Xin; Zhao, Junpu; Li, Kehong; Zhang, Xiaolu; Xue, Qiao; Yang, Ying; Dai, Wanjun; Zhou, Wei; Wang, Yuanchen; Zheng, Kuixing; Su, Jingqin; Hu, Dongxia; Zhu, Qihua

2017-10-30

Beam alignment is crucial to high-power laser facilities and is used to adjust the laser beams quickly and accurately to meet stringent requirements of pointing and centering. In this paper, a novel alignment method is presented, which employs data processing of the two-dimensional power spectral density (2D-PSD) for a near-field image and resolves the beam pointing error relative to the spatial filter pinhole directly. Combining this with a near-field fiducial mark, the operation of beam alignment is achieved. It is experimentally demonstrated that this scheme realizes a far-field alignment precision of approximately 3% of the pinhole size. This scheme adopts only one near-field camera to construct the alignment system, which provides a simple, efficient, and low-cost way to align lasers.

Real-time near IR (1310 nm) imaging of CO2 laser ablation of enamel.

Science.gov (United States)

Darling, Cynthia L; Fried, Daniel

2008-02-18

The high-transparency of dental enamel in the near-IR (NIR) can be exploited for real-time imaging of ablation crater formation during drilling with lasers. NIR images were acquired with an InGaAs focal plane array and a NIR zoom microscope during drilling incisions in human enamel samples with a lambda=9.3-microm CO(2) laser operating at repetition rates of 50-300-Hz with and without a water spray. Crack formation, dehydration and thermal changes were observed during ablation. These initial images demonstrate the potential of NIR imaging to monitor laser-ablation events in real-time to provide information about the mechanism of ablation and to evaluate the potential for peripheral thermal and mechanical damage.

Climate Prediction Center IR 4km Dataset

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — CPC IR 4km dataset was created from all available individual geostationary satellite data which have been merged to form nearly seamless global (60N-60S) IR...

Fabrication of Large Area Fishnet Optical Metamaterial Structures Operational at Near-IR Wavelengths

Directory of Open Access Journals (Sweden)

Dennis W. Prather

2010-12-01

Full Text Available In this paper, we demonstrate a fabrication process for large area (2 mm × 2 mm fishnet metamaterial structures for near IR wavelengths. This process involves: (a defining a sacrificial Si template structure onto a quartz wafer using deep-UV lithography and a dry etching process (b deposition of a stack of Au-SiO2-Au layers and (c a ‘lift-off’ process which removes the sacrificial template structure to yield the fishnet structure. The fabrication steps in this process are compatible with today’s CMOS technology making it eminently well suited for batch fabrication. Also, depending on area of the exposure mask available for patterning the template structure, this fabrication process can potentially lead to optical metamaterials spanning across wafer-size areas.

Near Infrared Spectral Linearisation in Quantifying Soluble Solids Content of Intact Carambola

Directory of Open Access Journals (Sweden)

Mohd Zubir MatJafri

2013-04-01

Full Text Available This study presents a novel application of near infrared (NIR spectral linearisation for measuring the soluble solids content (SSC of carambola fruits. NIR spectra were measured using reflectance and interactance methods. In this study, only the interactance measurement technique successfully generated a reliable measurement result with a coefficient of determination of (R2 = 0.724 and a root mean square error of prediction for (RMSEP = 0.461° Brix. The results from this technique produced a highly accurate and stable prediction model compared with multiple linear regression techniques.

Near infrared spectral linearisation in quantifying soluble solids content of intact carambola.

Science.gov (United States)

Omar, Ahmad Fairuz; MatJafri, Mohd Zubir

2013-04-12

This study presents a novel application of near infrared (NIR) spectral linearisation for measuring the soluble solids content (SSC) of carambola fruits. NIR spectra were measured using reflectance and interactance methods. In this study, only the interactance measurement technique successfully generated a reliable measurement result with a coefficient of determination of (R2) = 0.724 and a root mean square error of prediction for (RMSEP) = 0.461° Brix. The results from this technique produced a highly accurate and stable prediction model compared with multiple linear regression techniques.

Far-IR transparency and dynamic infrared signature control with novel conducting polymer systems

Science.gov (United States)

Chandrasekhar, Prasanna; Dooley, T. J.

1995-09-01

Materials which possess transparency, coupled with active controllability of this transparency in the infrared (IR), are today an increasingly important requirement, for varied applications. These applications include windows for IR sensors, IR-region flat panel displays used in camouflage as well as in communication and sight through night-vision goggles, coatings with dynamically controllable IR-emissivity, and thermal conservation coatings. Among stringent requirements for these applications are large dynamic ranges (color contrast), 'multi-color' or broad-band characteristics, extended cyclability, long memory retention, matrix addressability, small area fabricability, low power consumption, and environmental stability. Among materials possessing the requirements for variation of IR signature, conducting polymers (CPs) appear to be the only materials with dynamic, actively controllable signature and acceptable dynamic range. Conventional CPs such as poly(alkyl thiophene), poly(pyrrole) or poly(aniline) show very limited dynamic range, especially in the far-IR, while also showing poor transparency. We have developed a number of novel CP systems ('system' implying the CP, the selected dopant, the synthesis method, and the electrolyte) with very wide dynamic range (up to 90% in both important IR regions, 3 - 5 (mu) and 8 - 12 (mu) ), high cyclability (to 105 cycles with less than 10% optical degradation), nearly indefinite optical memory retention, matrix addressability of multi-pixel displays, very wide operating temperature and excellent environmental stability, low charge capacity, and processability into areas from less than 1 mm2 to more than 100 cm2. The criteria used to design and arrive at these CP systems, together with representative IR signature data, are presented in this paper.

Using Fourier transform IR spectroscopy to analyze biological materials

Science.gov (United States)

Baker, Matthew J; Trevisan, Júlio; Bassan, Paul; Bhargava, Rohit; Butler, Holly J; Dorling, Konrad M; Fielden, Peter R; Fogarty, Simon W; Fullwood, Nigel J; Heys, Kelly A; Hughes, Caryn; Lasch, Peter; Martin-Hirsch, Pierre L; Obinaju, Blessing; Sockalingum, Ganesh D; Sulé-Suso, Josep; Strong, Rebecca J; Walsh, Michael J; Wood, Bayden R; Gardner, Peter; Martin, Francis L

2015-01-01

IR spectroscopy is an excellent method for biological analyses. It enables the nonperturbative, label-free extraction of biochemical information and images toward diagnosis and the assessment of cell functionality. Although not strictly microscopy in the conventional sense, it allows the construction of images of tissue or cell architecture by the passing of spectral data through a variety of computational algorithms. Because such images are constructed from fingerprint spectra, the notion is that they can be an objective reflection of the underlying health status of the analyzed sample. One of the major difficulties in the field has been determining a consensus on spectral pre-processing and data analysis. This manuscript brings together as coauthors some of the leaders in this field to allow the standardization of methods and procedures for adapting a multistage approach to a methodology that can be applied to a variety of cell biological questions or used within a clinical setting for disease screening or diagnosis. We describe a protocol for collecting IR spectra and images from biological samples (e.g., fixed cytology and tissue sections, live cells or biofluids) that assesses the instrumental options available, appropriate sample preparation, different sampling modes as well as important advances in spectral data acquisition. After acquisition, data processing consists of a sequence of steps including quality control, spectral pre-processing, feature extraction and classification of the supervised or unsupervised type. A typical experiment can be completed and analyzed within hours. Example results are presented on the use of IR spectra combined with multivariate data processing. PMID:24992094

Signal-to-noise ratio of FT-IR CO gas spectra

DEFF Research Database (Denmark)

Bak, J.; Clausen, Sønnik

1999-01-01

in emission and transmission spectrometry, an investigation of the SNR in CO gas spectra as a function of spectral resolution has been carried out. We present a method to (1) determine experimentally the SNR at constant throughput, (2) determine the SNR on the basis of measured noise levels and Hitran......The minimum amount of a gaseous compound which can be detected and quantified with Fourier transform infrared (FT-IR) spectrometers depends on the signal-to-noise ratio (SNR) of the measured gas spectra. In order to use low-resolution FT-IR spectrometers to measure combustion gases like CO and CO2...... simulated signals, and (3) determine the SNR of CO from high to low spectral resolutions related to the molecular linewidth and vibrational-rotational lines spacing. In addition, SNR values representing different spectral resolutions but scaled to equal measurement times were compared. It was found...

VARIABILITY AT THE EDGE: OPTICAL NEAR/IR RAPID-CADENCE MONITORING OF NEWLY OUTBURSTING FU ORIONIS OBJECT HBC 722

International Nuclear Information System (INIS)

Green, Joel D.; Robertson, Paul; Pak, Soojong; Meschiari, Stefano; Baek, Giseon; Lee, Jeong-Eun; Pooley, David; Im, Myungshin; Jeon, Yiseul; Choi, Changsu

2013-01-01

We present the detection of day-timescale periodic variability in the r-band lightcurve of newly outbursting FU Orionis-type object HBC 722, taken from >42 nights of observation with the CQUEAN instrument on the McDonald Observatory 2.1 m telescope. The optical/near-IR lightcurve of HBC 722 shows a complex array of periodic variability, clustering around 5.8-day (0.044 mag amplitude) and 1.28-day (0.016 mag amplitude) periods, after removal of overall baseline variation. We attribute the unusual number of comparable strength signals to a phenomenon related to the temporary increase in accretion rate associated with FUors. We consider semi-random 'flickering', magnetic braking/field compression and rotational asymmetries in the disk instability region as potential sources of variability. Assuming that the 5.8-day period is due to stellar rotation and the 1.28-day period is indicative of Keplerian rotation at the inner radius of the accretion disk (at 2 R * ), we derive a B-field strength of 2.2-2.7 kG, slightly larger than typical T Tauri stars. If instead the 5.8-day signal is from a disk asymmetry, the instability region has an outer radius of 5.4 R * , consistent with models of FUor disks. Further exploration of the time domain in this complicated source and related objects will be key to understanding accretion processes.

Linearly Polarized IR Spectroscopy Theory and Applications for Structural Analysis

CERN Document Server

Kolev, Tsonko

2011-01-01

A technique that is useful in the study of pharmaceutical products and biological molecules, polarization IR spectroscopy has undergone continuous development since it first emerged almost 100 years ago. Capturing the state of the science as it exists today, "Linearly Polarized IR Spectroscopy: Theory and Applications for Structural Analysis" demonstrates how the technique can be properly utilized to obtain important information about the structure and spectral properties of oriented compounds. The book starts with the theoretical basis of linear-dichroic infrared (IR-LD) spectroscop

Sugar and acid content of Citrus prediction modeling using FT-IR fingerprinting in combination with multivariate statistical analysis.

Science.gov (United States)

Song, Seung Yeob; Lee, Young Koung; Kim, In-Jung

2016-01-01

A high-throughput screening system for Citrus lines were established with higher sugar and acid contents using Fourier transform infrared (FT-IR) spectroscopy in combination with multivariate analysis. FT-IR spectra confirmed typical spectral differences between the frequency regions of 950-1100 cm(-1), 1300-1500 cm(-1), and 1500-1700 cm(-1). Principal component analysis (PCA) and subsequent partial least square-discriminant analysis (PLS-DA) were able to discriminate five Citrus lines into three separate clusters corresponding to their taxonomic relationships. The quantitative predictive modeling of sugar and acid contents from Citrus fruits was established using partial least square regression algorithms from FT-IR spectra. The regression coefficients (R(2)) between predicted values and estimated sugar and acid content values were 0.99. These results demonstrate that by using FT-IR spectra and applying quantitative prediction modeling to Citrus sugar and acid contents, excellent Citrus lines can be early detected with greater accuracy. Copyright © 2015 Elsevier Ltd. All rights reserved.

Properties of the fullerene C_6_0-containing PN Lin49 in the SMC; Explanations of strong near-IR excess

International Nuclear Information System (INIS)

Otsuka, Masaaki; Kemper, Francisca; Leal-Ferreira, Marcelo L.; Aleman, Isabel; Ochsendorf, Bram; Bernard-Salas, Jeronimo; Cami, Jan; Peeters, Els

2016-01-01

We performed a detailed spectroscopic analysis of the fullerene C_6o-containing planetary nebula (PN) Lin49 in the Small Magellanic Cloud (SMC). Lin49 is a C-rich and metal- deficient PN (Z∼⃒0.0006) and its nebular abundances are in agreement with the AGB model for the initially 1.25M_☉ stars with the metallicity Z = 0.001 of Fishlock et al. (2014, [1]). By stellar absorption fitting with TLUSTY, we derived stellar abundances, effective temperature, and surface gravity. We constructed the photo-ionization model with CLOUDY in order to investigate physical conditions of Lin49. The model with the 0.005-0.1 μm radius graphite and a constant hydrogen density shell could not fit the ∼⃒1-5 μm SED owing to the strong near-IR excess. We propose that the near-IR excess indicates (1) the presence of extremely small carbon molecules or (2) the presence of high-density structure surrounding the central star. (paper)

Broadband dye-sensitized upconverting nanocrystals enabled near-infrared planar perovskite solar cells

Science.gov (United States)

Lai, Xuesen; Li, Xitao; Lv, Xinding; Zheng, Yan-Zhen; Meng, Fanli; Tao, Xia

2017-12-01

Extending the spectral absorption of perovskite solar cells (PSCs) from visible into near-infrared (NIR) range is a promising strategy to minimize non-absorption loss of solar photons and enhance the cell photovoltaic performance. Herein, we report on for the first time a viable strategy of incorporating IR806 dye-sensitized upconversion nanocrystals (IR806-UCNCs) into planar PSC for broadband upconversion of NIR light (800-1000 nm) into perovskite absorber-responsive visible emissions. A smart trick is firstly adopted to prepare hydrophilic IR806-UCNCs via a NOBF4 assisted two-step ligand-exchange that allows incorporating with perovskite precursor for in-situ growth of upconverting planar perovskite film. Unlike typically reported upconverting nanoparticles with narrow NIR absorption, the as-prepared IR806-UCNCs are able to harvest NIR light broadly and then transfer the captured energy to the UCNCs for an efficient visible upconversion. The IR806-UCNCs-incorporated cell exhibits a power conversion efficiency of 17.49%, corresponding to 29% increment from that of the pristine cell (13.52%). This strategy provides a feasible way to enable the most efficient harvesting of NIR sunlight for solar cells and other optoelectric devices.

Magnetic feature and near-infrared absorption of a [Pt(mnt)2]-based H-bond supramolecular crystal

International Nuclear Information System (INIS)

Li, Cui-Ping; Nie, Li; Pei, Wen-Bo; Li, Li; Tian, Zheng-Fang; Liu, Jian-Lan; Gao, Xu-Sheng; Ren, Xiao-Ming

2016-01-01

A new salt [H 2 DABCO][Pt(mnt) 2 ] 2 (1) (mnt 2- =maleonitriledithiolate and H 2 DABCO 2+ is diprotonated 1,4-diazabicyclo[2.2.2]octane) has been synthesized; its crystal structure, magnetic and near-IR absorption properties have been investigated. Two different [Pt(mnt) 2 ] - anions form the strong π-dimers, labeled as Pt(1)-dimer and Pt(2)-dimer, with quite shorter Pt…Pt and S…S distances and molecular plane-to-plane distance (<3.5 Å) within a dimer. The [Pt(mnt) 2 ] 2 2- π-dimers are connected through the cations in the strong H-bond manner to form three-dimensional H-bond supramolecular crystal. The salt shows weak paramagnetism in 1.99–300 K and this is due to the existence of strong antiferromagnetic coupling within a π-dimer. In addition, a small thermal hysteresis loop is observed at ca. 120 K, indicating that a phase transition probably occurs that is further confirmed by variable-temperature IR spectra. Another fascinating functionality of 1 is the intense near-IR absorption in the region of 750–2500 nm, and this near-IR absorption feature makes it to be a promising optical material. - Graphical abstract: A H-bond supramolecular crystal of [H 2 DABCO][Pt(mnt) 2 ] 2 shows a magnetic phase transition at ca. 120 K with sizable thermal hysteresis loop and intense near-IR absorption in the region of 750–2500 nm.

Near-IR spectroscopic monitoring of CLASS I protostars: Variability of accretion and wind indicators

Energy Technology Data Exchange (ETDEWEB)

Connelley, Michael S. [Institute for Astronomy, University of Hawaii, 640 N. Aohoku Place, Hilo, HI 96720 (United States); Greene, Thomas P. [NASA Ames Research Center, M.S. 245-6, Moffett Field, CA 94035 (United States)

2014-06-01

We present the results of a program that monitored the near-IR spectroscopic variability of a sample of 19 embedded protostars. Spectra were taken on time intervals from 2 days to 3 yr, over a wavelength range from 0.85 μm to 2.45 μm, for 4-9 epochs of observations per target. We found that the spectra of all targets are variable and that every emission feature observed is also variable (although not for all targets). With one exception, there were no drastic changes in the continua of the spectra, nor did any line completely disappear, nor did any line appear that was not previously apparent. This analysis focuses on understanding the connection between accretion (traced by H Br γ and CO) and the wind (traced by He I, [Fe II], and sometimes H{sub 2}). For both accretion and wind tracers, the median variability was constant versus the time interval between observations; however, the maximum variability that we observed increased with the time interval between observations. Extinction is observed to vary within the minimum sampling time of 2 days, suggesting extinguishing material within a few stellar radii at high disk latitudes. The variability of [Fe II] and H{sub 2} were correlated for most (but not all) of the 7 young stellar objects showing both features, and the amplitude of the variability depends on the veiling. Although the occurrence of CO and Br γ emission are connected, their variability is uncorrelated, suggesting that these emissions originate in separate regions near the protostar (e.g., disk and wind). The variability of Br γ and wind tracers were found to be positively correlated, negatively correlated, or uncorrelated, depending on the target. The variability of Br γ, [Fe II], and H{sub 2} always lies on a plane, although the orientation of the plane in three dimensions depends on the target. While we do not understand all interactions behind the variability that we observed, we have shown that spectroscopic variability is a powerful tool

Application of partial least squares near-infrared spectral classification in diabetic identification

Science.gov (United States)

Yan, Wen-juan; Yang, Ming; He, Guo-quan; Qin, Lin; Li, Gang

2014-11-01

In order to identify the diabetic patients by using tongue near-infrared (NIR) spectrum - a spectral classification model of the NIR reflectivity of the tongue tip is proposed, based on the partial least square (PLS) method. 39sample data of tongue tip's NIR spectra are harvested from healthy people and diabetic patients , respectively. After pretreatment of the reflectivity, the spectral data are set as the independent variable matrix, and information of classification as the dependent variables matrix, Samples were divided into two groups - i.e. 53 samples as calibration set and 25 as prediction set - then the PLS is used to build the classification model The constructed modelfrom the 53 samples has the correlation of 0.9614 and the root mean square error of cross-validation (RMSECV) of 0.1387.The predictions for the 25 samples have the correlation of 0.9146 and the RMSECV of 0.2122.The experimental result shows that the PLS method can achieve good classification on features of healthy people and diabetic patients.

Gaz Phase IR and UV Spectroscopy of Neutral Contact Ion Pairs

Science.gov (United States)

Habka, Sana; Brenner, Valerie; Mons, Michel; Gloaguen, Eric

2016-06-01

Cations and anions, in solution, tend to pair up forming ion pairs. They play a crucial role in many fundamental processes in ion-concentrated solutions and living organisms. Despite their importance and vast applications in physics, chemistry and biochemistry, they remain difficult to characterize namely because of the coexistence of several types of pairing in solution. However, an interesting alternative consists in applying highly selective gas phase spectroscopy which can offer new insights on these neutral ion pairs. Our study consists in characterizing contact ion pairs (CIPs) in isolated model systems (M+, Ph-(CH2)n-COO- with M=Li, Na, K, Rb, Cs, and n=1-3), to determine their spectral signatures and compare them to ion pairs in solution. We have used laser desorption to vaporize a solid tablet containing the desired salt. Structural information for each system was obtained by mass-selective, UV and IR laser spectroscopy combined with high level quantum chemistry calculations1. Evidence of the presence of neutral CIPs was found by scanning the π-π* transition of the phenyl ring using resonant two-photon ionization (R2PI). Then, conformational selective IR/UV double resonance spectra were recorded in the CO2- stretch region for each conformation detected. The good agreement between theoretical data obtained at the BSSE-corrected-fullCCSD(T)/dhf-TZVPP//B97-D3/dhf-TZVPP level and experimental IR spectra led us to assign the 3D structure for each ion pair formed. Spectral signatures of (M+, Ph-CH2-COO-) pairs, were assigned to a bidentate CIPs between the alkali cation and the carboxylate group. In the case of (Li+, Ph-(CH2)3-COO-) pairs, the presence of a flexible side chain promotes a cation-π interaction leading to a tridentate O-O-π structure with its unique IR and UV signatures. IR spectra obtained on isolated CIPs were found very much alike the ones published on lithium and sodium acetate in solution2. However, in the case of sodium acetate, solution

Characterization and identification of microorganisms by FT-IR microspectrometry

Science.gov (United States)

Ngo-Thi, N. A.; Kirschner, C.; Naumann, D.

2003-12-01

We report on a novel FT-IR approach for microbial characterization/identification based on a light microscope coupled to an infrared spectrometer which offers the possibility to acquire IR-spectra of microcolonies containing only few hundred cells. Microcolony samples suitable for FT-IR microspectroscopic measurements were obtained by a replica technique with a stamping device that transfers spatially accurate cells of microcolonies growing on solid culture plates to a special, IR-transparent or reflecting stamping plate. High quality spectra could be recorded either by applying the transmission/absorbance or the reflectance/absorbance mode of the infrared microscope. Signal to noise ratios higher than 1000 were obtained for microcolonies as small as 40 μm in diameter. Reproducibility levels were established that allowed species and strain identification. The differentiation and classification capacity of the FT-IR microscopic technique was tested for different selected microorganisms. Cluster and factor analysis methods were used to evaluate the complex spectral data. Excellent discrimination between bacteria and yeasts, and at the same time Gram-negative and Gram-positive bacterial strains was obtained. Twenty-two selected strains of different species within the genus Staphylococcus were repetitively measured and could be grouped into correct species cluster. Moreover, the results indicated that the method allows also identifications at the subspecies level. Additionally, the new approach allowed spectral mapping analysis of single colonies which provided spatially resolved characterization of growth heterogeneity within complex microbial populations such as colonies.

Dust-deficient Palomar-Green Quasars and the Diversity of AGN Intrinsic IR Emission

Energy Technology Data Exchange (ETDEWEB)

Lyu, Jianwei; Rieke, G. H. [Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States); Shi, Yong, E-mail: jianwei@email.arizona.edu [School of Astronomy and Space Science, Nanjing University, Nanjing 210093 (China)

2017-02-01

To elucidate the intrinsic broadband infrared (IR) emission properties of active galactic nuclei (AGNs), we analyze the spectral energy distributions (SEDs) of 87 z ≲ 0.5 Palomar-Green (PG) quasars. While the Elvis AGN template with a moderate far-IR correction can reasonably match the SEDs of the AGN components in ∼60% of the sample (and is superior to alternatives such as that by Assef), it fails on two quasar populations: (1) hot-dust-deficient (HDD) quasars that show very weak emission thoroughly from the near-IR to the far-IR, and (2) warm-dust-deficient (WDD) quasars that have similar hot dust emission as normal quasars but are relatively faint in the mid- and far-IR. After building composite AGN templates for these dust-deficient quasars, we successfully fit the 0.3–500 μm SEDs of the PG sample with the appropriate AGN template, an infrared template of a star-forming galaxy, and a host galaxy stellar template. 20 HDD and 12 WDD quasars are identified from the SED decomposition, including seven ambiguous cases. Compared with normal quasars, the HDD quasars have AGNs with relatively low Eddington ratios and the fraction of WDD quasars increases with AGN luminosity. Moreover, both the HDD and WDD quasar populations show relatively stronger mid-IR silicate emission. Virtually identical SED properties are also found in some quasars from z = 0.5 to 6. We propose a conceptual model to demonstrate that the observed dust deficiency of quasars can result from a change of structures of the circumnuclear tori that can occur at any cosmic epoch.

Optical polarimetric and near-infrared photometric study of the RCW95 Galactic H II region

Science.gov (United States)

Vargas-González, J.; Roman-Lopes, A.; Santos, F. P.; Franco, G. A. P.; Santos, J. F. C.; Maia, F. F. S.; Sanmartim, D.

2018-02-01

We carried out an optical polarimetric study in the direction of the RCW 95 star-forming region in order to probe the sky-projected magnetic field structure by using the distribution of linear polarization segments which seem to be well aligned with the more extended cloud component. A mean polarization angle of θ = 49.8° ± 7.7°7 was derived. Through the spectral dependence analysis of polarization it was possible to obtain the total-to-selective extinction ratio (RV) by fitting the Serkowski function, resulting in a mean value of RV = 2.93 ± 0.47. The foreground polarization component was estimated and is in agreement with previous studies in this direction of the Galaxy. Further, near-infrared (NIR) images from Vista Variables in the Via Láctea (VVV) survey were collected to improve the study of the stellar population associated with the H II region. The Automated Stellar Cluster Analysis algorithm was employed to derive structural parameters for two clusters in the region, and a set of PAdova and TRieste Stellar Evolution Code (PARSEC) isochrones was superimposed on the decontaminated colour-magnitude diagrams to estimate an age of about 3 Myr for both clusters. Finally, from the NIR photometry study combined with spectra obtained with the Ohio State Infrared Imager and Spectrometer mounted at the Southern Astrophysics Research Telescope we derived the spectral classification of the main ionizing sources in the clusters associated with IRAS 15408-5356 and IRAS 15412-5359, both objects classified as O4V stars.

Liver Status Assessment by Spectrally and Time Resolved IR Detection of Drug Induced Breath Gas Changes

Directory of Open Access Journals (Sweden)

Tom Rubin

2016-05-01

Full Text Available The actual metabolic capacity of the liver is crucial for disease identification, liver therapy, and liver tumor resection. By combining induced drug metabolism and high sensitivity IR spectroscopy of exhaled air, we provide a method for quantitative liver assessment at bedside within 20 to 60 min. Fast administration of 13C-labelled methacetin induces a fast response of liver metabolism and is tracked in real-time by the increase of 13CO2 in exhaled air. The 13CO2 concentration increase in exhaled air allows the determination of the metabolic liver capacity (LiMAx-test. Fluctuations in CO2 concentration, pressure and temperature are minimized by special gas handling, and tracking of several spectrally resolved CO2 absorption bands with a quantum cascade laser. Absorption measurement of different 12CO2 and 13CO2 rotation-vibration transitions in the same time window allows for multiple referencing and reduction of systematic errors. This FLIP (Fast liver investigation package setup is being successfully used to plan operations and determine the liver status of patients.

Identification of Spectral Regions for Quantification of Red Wine Tannins with Fourier Transform Mid-Infrared Spectroscopy

DEFF Research Database (Denmark)

Jensen, Jacob Skibsted; Egebo, Max; Meyer, Anne S.

2008-01-01

Accomplishment of fast tannin measurements is receiving increased interest as tannins are important for the mouthfeel and color properties of red wines. Fourier transform mid-infrared spectroscopy allows fast measurement of different wine components, but quantification of tannins is difficult due...... to interferences from spectral responses of other wine components. Four different variable selection tools were investigated for the identification of the most important spectral regions which would allow quantification of tannins from the spectra using partial least-squares regression. The study included...... to be particularly important for tannin quantification. The spectral regions identified from the variable selection methods were used to develop calibration models. All four variable selection methods identified regions that allowed an improved quantitative prediction of tannins (RMSEP = 69−79 mg of CE/L; r = 0...

Spatially resolved star formation and dust attenuation in Mrk 848: Comparison of the integral field spectra and the UV-to-IR SED

Science.gov (United States)

Yuan, Fang-Ting; Argudo-Fernández, María; Shen, Shiyin; Hao, Lei; Jiang, Chunyan; Yin, Jun; Boquien, Médéric; Lin, Lihwai

2018-05-01

We investigate the star formation history and the dust attenuation in the galaxy merger Mrk 848. Thanks to the multiwavelength photometry from the ultraviolet (UV) to the infrared (IR), and MaNGA's integral field spectroscopy, we are able to study this merger in a detailed way. We divide the whole merger into the core and tail regions, and fit both the optical spectrum and the multi-band spectral energy distribution (SED) to models to obtain the star formation properties for each region respectively. We find that the color excess of stars in the galaxy E(B-V)sSED measured with the multi-band SED fitting is consistent with that estimated both from the infrared excess (the ratio of IR to UV flux) and from the slope of the UV continuum. Furthermore, the reliability of the E(B-V)sSED is examined with a set of mock SEDs, showing that the dust attenuation of the stars can be well constrained by the UV-to-IR broadband SED fitting. The dust attenuation obtained from optical continuum E(B-V)sspec is only about half of E(B-V)sSED. The ratio of the E(B-V)sspec to the E(B-V)g obtained from the Balmer decrement is consistent with the local value (around 0.5). The difference between the results from the UV-to-IR data and the optical data is consistent with the picture that younger stellar populations are attenuated by an extra dust component from the birth clouds compared to older stellar populations which are only attenuated by the diffuse dust. Both with the UV-to-IR SED fitting and the spectral fitting, we find that there is a starburst younger than 100 Myr in one of the two core regions, consistent with the scenario that the interaction-induced gas inflow can enhance the star formation in the center of galaxies.

Novel Cavities in Vertical External Cavity Surface Emitting Lasers for Emission in Broad Spectral Region by Means of Nonlinear Frequency Conversion

Science.gov (United States)

Lukowski, Michal L.

second harmonic generation in a V- cavity is presented. Tens of watts of output power for both blue and green wavelengths prove the viability for VECSELs to replace the other types of lasers currently used for applications in laser light shows, for Ti:Sapphire pumping, and for medical applications such as laser skin resurfacing. The novel, recently patented, two-chip T-cavity configuration allowing for spatial overlap of two, separate VECSEL cavities is described in detail. This type of setup is further used to demonstrate type II sum frequency generation to green with multi-watt output, and the full potential of the T-cavity is utilized by achieving type II difference frequency generation to the mid-IR spectral region. The tunable output around 5.4 microm with over 10 mW power is showcased. In the same manner the first attempts to generate THz radiation are discussed. Finally, a slightly modified T-cavity VECSEL is used to reach the UV spectral regions thanks to type I fourth harmonic generation. Over 100 mW at around 265 nm is obtained in a setup which utilizes no stabilization techniques. The dissertation demonstrates the flexibility of the VECSEL in achieving broad spectral coverage and thus its potential for a wide range of applications.

Near-surface wind variability over the broader Adriatic region: insights from an ensemble of regional climate models

Science.gov (United States)

Belušić, Andreina; Prtenjak, Maja Telišman; Güttler, Ivan; Ban, Nikolina; Leutwyler, David; Schär, Christoph

2018-06-01

Over the past few decades the horizontal resolution of regional climate models (RCMs) has steadily increased, leading to a better representation of small-scale topographic features and more details in simulating dynamical aspects, especially in coastal regions and over complex terrain. Due to its complex terrain, the broader Adriatic region represents a major challenge to state-of-the-art RCMs in simulating local wind systems realistically. The objective of this study is to identify the added value in near-surface wind due to the refined grid spacing of RCMs. For this purpose, we use a multi-model ensemble composed of CORDEX regional climate simulations at 0.11° and 0.44° grid spacing, forced by the ERA-Interim reanalysis, a COSMO convection-parameterizing simulation at 0.11° and a COSMO convection-resolving simulation at 0.02° grid spacing. Surface station observations from this region and satellite QuikSCAT data over the Adriatic Sea have been compared against daily output obtained from the available simulations. Both day-to-day wind and its frequency distribution are examined. The results indicate that the 0.44° RCMs rarely outperform ERA-Interim reanalysis, while the performance of the high-resolution simulations surpasses that of ERA-Interim. We also disclose that refining the grid spacing to a few km is needed to properly capture the small-scale wind systems. Finally, we show that the simulations frequently yield the accurate angle of local wind regimes, such as for the Bora flow, but overestimate the associated wind magnitude. Finally, spectral analysis shows good agreement between measurements and simulations, indicating the correct temporal variability of the wind speed.

A car-borne highly sensitive near-IR diode-laser methane detector

International Nuclear Information System (INIS)

Berezin, A G; Ershov, Oleg V; Shapovalov, Yu P

2003-01-01

A highly sensitive automated car-borne detector for measuring methane concentration in real time is designed, developed and tested under laboratory and field conditions. Measurements were made with the help of an uncooled tunable near-IR 1.65-μm laser diode. The detector consists of a multipass optical cell with a 45-m long optical path and a base length of 0.5 m. The car-borne detector is intended for monitoring the methane concentration in air from the moving car to reveal the leakage of domestic gas. The sensitivity limit (standard deviation) under field conditions is 1 ppm (20 ppb under laboratory conditions) for a measuring time of 0.4 s. The measuring technique based on the detection of a single methane line ensured a high selectivity of methane detector relative to other gases. The methane detector can be easily modified for measuring other simple-molecule gases (e.g., CO, CO 2 , HF, NO 2 , H 2 O) by replacing the diode laser and varying the parameters of the control program. (special issue devoted to the memory of academician a m prokhorov)

Exploration of Integrated Visible to Near-, Shortwave-, and Longwave-Infrared (Full-Range) Spectral Analysis

Science.gov (United States)

2014-09-01

wavelength region .................................... 67 Table 7. Description of comparison locations...concentration and characteristics of the silicate bonds. Sulfates, phosphates, oxides, and hydroxides also exhibit strong features in the LWIR. Because...authors suggested that full spectral coverage would provide complementary information about the mineralogical and mineral chemistry patterns. The

Cap integration in spectral gravity forward modelling: near- and far-zone gravity effects via Molodensky's truncation coefficients

Science.gov (United States)

Bucha, Blažej; Hirt, Christian; Kuhn, Michael

2018-04-01

Spectral gravity forward modelling is a technique that converts a band-limited topography into its implied gravitational field. This conversion implicitly relies on global integration of topographic masses. In this paper, a modification of the spectral technique is presented that provides gravity effects induced only by the masses located inside or outside a spherical cap centred at the evaluation point. This is achieved by altitude-dependent Molodensky's truncation coefficients, for which we provide infinite series expansions and recurrence relations with a fixed number of terms. Both representations are generalized for an arbitrary integer power of the topography and arbitrary radial derivative. Because of the altitude-dependency of the truncation coefficients, a straightforward synthesis of the near- and far-zone gravity effects at dense grids on irregular surfaces (e.g. the Earth's topography) is computationally extremely demanding. However, we show that this task can be efficiently performed using an analytical continuation based on the gradient approach, provided that formulae for radial derivatives of the truncation coefficients are available. To demonstrate the new cap-modified spectral technique, we forward model the Earth's degree-360 topography, obtaining near- and far-zone effects on gravity disturbances expanded up to degree 3600. The computation is carried out on the Earth's surface and the results are validated against an independent spatial-domain Newtonian integration (1 μGal RMS agreement). The new technique is expected to assist in mitigating the spectral filter problem of residual terrain modelling and in the efficient construction of full-scale global gravity maps of highest spatial resolution.

IR technology for enhanced force protection by AIM

Science.gov (United States)

Breiter, R.; Ihle, T.; Rode, W.; Wendler, J.; Rühlich, I.; Haiml, M.; Ziegler, J.

2008-04-01

In all recent missions our forces are faced with various types of asymmetric threads like snipers, IEDs, RPGs or MANPADS. 2 nd and 3 rd Gen IR technology is a backbone of modern force protection by providing situational awareness and accurate target engagement at day/night. 3 rd Gen sensors are developed for thread warning capabilities by use of spectral or spatial information. The progress on a dual-color IR module is discussed in a separate paper [1]. A 1024x256 SWIR array with flexure bearing compressor and pulse tube cold finger provides > 50,000h lifetime for space or airborne hyperspectral imaging in pushbroom geometry with 256 spectral channels for improved change detection and remote sensing of IEDs or chemical agents. Similar concepts are pursued in the LWIR with either spectroscopic imaging or a system of LWIR FPA combined with a cooled tunable Laser to do spectroscopy with stimulated absorption of specific wavelengths. AIM introduced the RangIR sight to match the requirements of sniper teams, AGLs and weapon stations, extending the outstanding optronic performance of the fielded HuntIR with position data of a target by a laser range finder (LRF), a 3 axis digital magnetic compass (DMC) and a ballistic computer for accurate engagement of remote targets. A version with flexure bearing cooler with >30,000h life time is being developed for continuous operation in e.g. gunfire detection systems. This paper gives an overview of AIM's technologies for enhanced force protection.

Silicon spectral response extension through single wall carbon nanotubes in hybrid solar cells

KAUST Repository

Del Gobbo, Silvano; Castrucci, P.; Fedele, S.; Riele, L.; Convertino, A.; Morbidoni, M.; De Nicola, F.; Scarselli, M.; Camilli, L.; De Crescenzi, M.

2013-01-01

Photovoltaic devices based on single wall carbon nanotubes (SWCNTs) and n-silicon multiple heterojunctions have been fabricated by a SWCNT film transferring process. We report on the ability of the carbon nanotubes to extend the Si spectral range towards the near ultraviolet (UV) and the near infrared regions. Semiconducting and about metallic SWCNT networks have been studied as a function of the film sheet resistance, Rsh. Optical absorbance and Raman spectroscopy have been used to assign nanotube chirality and electronic character. This gave us hints of evidence of the participation of the metal nanotubes in the photocurrent generation. Moreover, we provide evidence that the external quantum efficiency spectral range can be modulated as a function of the SWCNT network sheet resistance in a hybrid SWCNT/Si solar cell. This result will be very useful to further design/optimize devices with improved performance in spectral regions generally not covered by conventional Si p-n devices. © 2013 The Royal Society of Chemistry.

WATER ABSORPTION FROM GAS VERY NEAR THE MASSIVE PROTOSTAR AFGL 2136 IRS 1

International Nuclear Information System (INIS)

Indriolo, Nick; Neufeld, D. A.; Seifahrt, A.; Richter, M. J.

2013-01-01

We present ground-based observations of the ν 1 and ν 3 fundamental bands of H 2 O toward the massive protostar AFGL 2136 IRS 1, identifying absorption features due to 47 different ro-vibrational transitions between 2.468 μm and 2.561 μm. Analysis of these features indicates the absorption arises in warm (T = 506 ± 25 K), very dense (n(H 2 ) > 5 × 10 9 cm –3 ) gas, suggesting an origin close to the central protostar. The total column density of warm water is estimated to be N(H 2 O) = (1.02 ± 0.02) × 10 19 cm –2 , giving a relative abundance of N(H 2 O)/N(H 2 ) ≈ 10 –4 . Our study represents the first extensive use of water vapor absorption lines in the near infrared, and demonstrates the utility of such observations in deriving physical parameters

Power scaling of ultrafast mid-IR source enabled by high-power fiber laser technology

Energy Technology Data Exchange (ETDEWEB)

Zhou, Gengji

2017-11-15

Ultrafast laser sources with high repetition-rate (>10 MHz) and tunable in the mid-infrared (IR) wavelength range of 7-18 μm hold promise for many important spectroscopy applications. Currently, these ultrafast mid- to longwavelength-IR sources can most easily be achieved via difference-frequency generation (DFG) between a pump beam and a signal beam. However, current ultrafast mid- to longwavelength-IR sources feature a low average power, which limits their applications. In this thesis, we propose and demonstrate a novel approach to power scaling of DFG-based ultrafast mid-IR laser sources. The essence of this novel approach is the generation of a high-energy signal beam. Both the pump beam and the signal beam are derived from a home-built Yb-fiber laser system that emits 165-fs pulses centered at 1035 nm with 30-MHz repetition rate and 14.5-W average power (corresponding to 483-nJ pulse energy). We employ fiber-optic self-phase modulation (SPM) to broaden the laser spectrum and generate isolated spectral lobes. Filtering the rightmost spectral lobe leads to femtosecond pulses with >10 nJ pulse energy. Tunable between 1.1-1.2 μm, this SPM-enabled ultrafast source exhibits ∝100 times higher pulse energy than can be obtained from Raman soliton sources in this wavelength range. We use this SPM-enabled source as the signal beam and part of the Yb-fiber laser output as the pump beam. By performing DFG in GaSe crystals, we demonstrate that power scaling of a DFG-based mid-IR source can be efficiently achieved by increasing the signal energy. The resulting mid-IR source is tunable from 7.4 μm to 16.8 μm. Up to 5.04-mW mid-IR pulses centered at 11 μm are achieved. The corresponding pulse energy is 167 pJ, representing nearly one order of magnitude improvement compared with other reported DFG-based mid-IR sources at this wavelength. Despite of low pulse energy, Raman soliton sources have become a popular choice as the signal source. We carry out a detailed study on

Power scaling of ultrafast mid-IR source enabled by high-power fiber laser technology

International Nuclear Information System (INIS)

Zhou, Gengji

2017-11-01

Ultrafast laser sources with high repetition-rate (>10 MHz) and tunable in the mid-infrared (IR) wavelength range of 7-18 μm hold promise for many important spectroscopy applications. Currently, these ultrafast mid- to longwavelength-IR sources can most easily be achieved via difference-frequency generation (DFG) between a pump beam and a signal beam. However, current ultrafast mid- to longwavelength-IR sources feature a low average power, which limits their applications. In this thesis, we propose and demonstrate a novel approach to power scaling of DFG-based ultrafast mid-IR laser sources. The essence of this novel approach is the generation of a high-energy signal beam. Both the pump beam and the signal beam are derived from a home-built Yb-fiber laser system that emits 165-fs pulses centered at 1035 nm with 30-MHz repetition rate and 14.5-W average power (corresponding to 483-nJ pulse energy). We employ fiber-optic self-phase modulation (SPM) to broaden the laser spectrum and generate isolated spectral lobes. Filtering the rightmost spectral lobe leads to femtosecond pulses with >10 nJ pulse energy. Tunable between 1.1-1.2 μm, this SPM-enabled ultrafast source exhibits ∝100 times higher pulse energy than can be obtained from Raman soliton sources in this wavelength range. We use this SPM-enabled source as the signal beam and part of the Yb-fiber laser output as the pump beam. By performing DFG in GaSe crystals, we demonstrate that power scaling of a DFG-based mid-IR source can be efficiently achieved by increasing the signal energy. The resulting mid-IR source is tunable from 7.4 μm to 16.8 μm. Up to 5.04-mW mid-IR pulses centered at 11 μm are achieved. The corresponding pulse energy is 167 pJ, representing nearly one order of magnitude improvement compared with other reported DFG-based mid-IR sources at this wavelength. Despite of low pulse energy, Raman soliton sources have become a popular choice as the signal source. We carry out a detailed study on

Imaging of lipids in atherosclerotic lesion in aorta from ApoE/LDLR-/- mice by FT-IR spectroscopy and Hierarchical Cluster Analysis.

Science.gov (United States)

P Wrobel, Tomasz; Mateuszuk, Lukasz; Chlopicki, Stefan; Malek, Kamilla; Baranska, Malgorzata

2011-12-21

Spectroscopy-based approaches can provide an insight into the biochemical composition of a tissue sample. In the present work Fourier transform infrared (FT-IR) spectroscopy was used to develop a reliable methodology to study the content of free fatty acids, triglycerides, cholesteryl esters as well as cholesterol in aorta from mice with atherosclerosis (ApoE/LDLR(-/-) mice). In particular, distribution and concentration of palmitic, oleic and linoleic acid derivatives were analyzed. Spectral analysis of pure compounds allowed for clear discrimination between free fatty acids and other similar moieties based on the carbonyl band position (1699-1710 cm(-1) range). In order to distinguish cholesteryl esters from triglycerides a ratio of carbonyl band to signal at 1010 cm(-1) was used. Imaging of lipids in atherosclerotic aortic lesions in ApoE/LDLR(-/-) mice was followed by Hierarchical Cluster Analysis (HCA). The aorta from C57Bl/6J control mice (fed with chow diet) was used for comparison. The measurements were completed with an FT-IR spectrometer equipped with a 128 × 128 FPA detector. In cross-section of aorta from ApoE/LDLR(-/-) mice a region of atherosclerotic plaque was clearly identified by HCA, which was later divided into 2 sub-regions, one characterized by the higher content of cholesterol, while the other by higher contents of cholesteryl esters. HCA of tissues deposited on normal microscopic glass, hence limited to the 2200-3800 cm(-1) spectral range, also identified a region of atherosclerotic plaque. Importantly, this region correlates with the area stained by standard histological staining for atherosclerotic plaque (Oil Red O). In conclusion, the use of FT-IR and HCA may provide a novel tool for qualitative and quantitative analysis of contents and distribution of lipids in atherosclerotic plaque.

Mid-IR Reflectance (DRIFT) Spectral Variations in Basaltic Mineralogy with Direction of Impact at Lonar Crater, India

Science.gov (United States)

Basavaiah, N.; Chavan, R. S.; Arif, M.

2012-12-01

Identification of spectral changes with the direction of impact has important implications for understanding the impact cratering phenomenon occurring on both terrestrial and extraterrestrial planets and also for geology of the crater. Fortuitously, Lonar Impact Crater (India) is the only well-preserved terrestrial simple crater excavated on Deccan basalts and serves as an excellent analogue to craters on Mars and Moon. An ~570 ka old Lonar crater was suggested to be formed by an oblique impact of a chondritic impactor that struck the pre-impact target from the east into a sequence of six basaltic Deccan flows and created a 1.88 km diameter crater with two layers of ejecta blanket. Here we report preliminary laboratory studies of spectral results on fine-grained rock powers (IR (4000-400 cm-1) Diffuse Reflectance Infrared Fourier Transform (DRIFT) spectroscopy. The basalts were collected from two profiles in the east and south sections of the crater wall and the upper most crater rim, which later subdivided into sector-wise samples to carry out a systematic study of spectral properties of Lonar basalts, together with impact related samples of breccias and impact melts. For the first time, data of the shock metamorphism of Lonar basalt is examined using DRIFT spectroscopy. Infrared spectra of rock powders of relatively unshocked and shocked basalts are obtained to document the mineralogical variations and the distribution of primary (e.g. Plagioclase Feldspar, Pyroxene), and secondary Phyllosilicate minerals (e.g. Illite, Smectite, Montmorillonite, Saponite, Serpentine) with direction of impact. The spectral data between pre-impact unshocked and post-impact shocked basalts are interpreted to reflect the effect of shock pressure and alteration that rock have undergone. On western crater rim sector, typical silicate spectral features in 900-1200 cm-1 which attributed to Si-O stretching, are observed to change slightly in the width and shift in position as a result of

Identification of spectral regions for the quantification of red wine tannins with fourier transform mid-infrared spectroscopy.

Science.gov (United States)

Jensen, Jacob S; Egebo, Max; Meyer, Anne S

2008-05-28

Accomplishment of fast tannin measurements is receiving increased interest as tannins are important for the mouthfeel and color properties of red wines. Fourier transform mid-infrared spectroscopy allows fast measurement of different wine components, but quantification of tannins is difficult due to interferences from spectral responses of other wine components. Four different variable selection tools were investigated for the identification of the most important spectral regions which would allow quantification of tannins from the spectra using partial least-squares regression. The study included the development of a new variable selection tool, iterative backward elimination of changeable size intervals PLS. The spectral regions identified by the different variable selection methods were not identical, but all included two regions (1485-1425 and 1060-995 cm(-1)), which therefore were concluded to be particularly important for tannin quantification. The spectral regions identified from the variable selection methods were used to develop calibration models. All four variable selection methods identified regions that allowed an improved quantitative prediction of tannins (RMSEP = 69-79 mg of CE/L; r = 0.93-0.94) as compared to a calibration model developed using all variables (RMSEP = 115 mg of CE/L; r = 0.87). Only minor differences in the performance of the variable selection methods were observed.

Tokamak residual zonal flow level in near-separatrix region

International Nuclear Information System (INIS)

Bing-Ren, Shi

2010-01-01

Residual zonal flow level is calculated for tokamak plasmas in the near-separatrix region of a diverted tokamak. A recently developed method is used to construct an analytic divertor tokamak configuration. It is shown that the residual zonal flow level becomes smaller but still keeps finite near the separatrix because the neoclassical polarisation mostly due to the trapped particles goes larger in this region. (fluids, plasmas and electric discharges)

Continuous-wave near-photon counting spectral imaging detector in the mid-infrared by upconversion

DEFF Research Database (Denmark)

Dam, Jeppe Seidelin; Tidemand-Lichtenberg, Peter; Pedersen, Christian

2013-01-01

is usually measured in number of electrons. The second noise source is usually referred to as dark noise, which is the background signal generated over time. Dark noise is usually measured in electrons per pixel per second. For silicon cameras certain models like EM-CCD have close to zero read noise, whereas...... high-end IR cameras have read noise of hundreds of electrons. The dark noise for infrared cameras based on semiconductor materials is also substantially higher than for silicon cameras, typical values being millions of electrons per pixel per second for cryogenically cooled cameras whereas peltier...... cooled CCD cameras have dark noise measured in fractions of electrons per pixel per second. An ideal solution thus suggest the combination of an efficient low noise image wavelength conversion system combined with low noise silicon based cameras for low noise imaging in the IR region. We discuss image...

A UV to mid-IR study of AGN selection

Energy Technology Data Exchange (ETDEWEB)

Chung, Sun Mi; Kochanek, Christopher S. [Department of Astronomy, The Ohio State University, 140 West 18th Avenue, Columbus, OH 43210 (United States); Assef, Roberto [Núcleo de Astronomía de la Facultad de Ingeniería, Universidad Diego Portales, Av. Ejército Libertador 441, Santiago (Chile); Brown, Michael J. I. [School of Physics, Monash University, Clayton, Vic 3800 (Australia); Stern, Daniel [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Mail Stop 169-221, Pasadena, CA 91109 (United States); Jannuzi, Buell T. [Department of Astronomy and Steward Observatory, University of Arizona, Tucson, AZ 85721 (United States); Gonzalez, Anthony H. [Department of Astronomy, University of Florida, Gainesville, FL 32611 (United States); Hickox, Ryan C. [Department of Physics and Astronomy, Dartmouth College, 6127 Wilder Laboratory, Hanover, NH 03755 (United States); Moustakas, John [Department of Physics and Astronomy, Siena College, 515 Loudon Road, Loudonville, NY 12211 (United States)

2014-07-20

We classify the spectral energy distributions (SEDs) of 431,038 sources in the 9 deg{sup 2} Boötes field of the NOAO Deep Wide-Field Survey (NDWFS). There are up to 17 bands of data available per source, including ultraviolet (GALEX), optical (NDWFS), near-IR (NEWFIRM), and mid-infrared (IRAC and MIPS) data, as well as spectroscopic redshifts for ∼20,000 objects, primarily from the AGN and Galaxy Evolution Survey. We fit galaxy, active galactic nucleus (AGN), stellar, and brown dwarf templates to the observed SEDs, which yield spectral classes for the Galactic sources and photometric redshifts and galaxy/AGN luminosities for the extragalactic sources. The photometric redshift precision of the galaxy and AGN samples are σ/(1 + z) = 0.040 and σ/(1 + z) = 0.169, respectively, with the worst 5% outliers excluded. On the basis of the χ{sub ν}{sup 2} of the SED fit for each SED model, we are able to distinguish between Galactic and extragalactic sources for sources brighter than I = 23.5 mag. We compare the SED fits for a galaxy-only model and a galaxy-AGN model. Using known X-ray and spectroscopic AGN samples, we confirm that SED fitting can be successfully used as a method to identify large populations of AGNs, including spatially resolved AGNs with significant contributions from the host galaxy and objects with the emission line ratios of 'composite' spectra. We also use our results to compare with the X-ray, mid-IR, optical color, and emission line ratio selection techniques. For an F-ratio threshold of F > 10, we find 16,266 AGN candidates brighter than I = 23.5 mag and a surface density of ∼1900 AGN deg{sup –2}.

Near infrared spectral polarization imaging of prostate cancer tissues using Cybesin: a receptor-targeted contrast agent

Science.gov (United States)

Pu, Yang; Wang, W. B.; Tang, G. C.; Liang, Kexian; Achilefu, S.; Alfano, R. R.

2013-03-01

Cybesin, a smart contrast agent to target cancer cells, was investigated using a near infrared (NIR) spectral polarization imaging technique for prostate cancer detection. The approach relies on applying a contrast agent that can target cancer cells. Cybesin, as a small ICG-derivative dye-peptide, emit fluorescence between 750 nm and 900 nm, which is in the "tissue optical window". Cybesin was reported targeting the over-expressed bombesin receptors in cancer cells in animal model and the human prostate cancers over-expressing bombesin receptors. The NIR spectral polarization imaging study reported here demonstrated that Cybesin can be used as a smart optical biomarker and as a prostate cancer receptor targeted contrast agent.

High-resolution TNG spectra of T Tauri stars. Near-IR GIANO observations of the young variables XZ Tauri and DR Tauri

Science.gov (United States)

Antoniucci, S.; Nisini, B.; Biazzo, K.; Giannini, T.; Lorenzetti, D.; Sanna, N.; Harutyunyan, A.; Origlia, L.; Oliva, E.

2017-10-01

Aims: We aim to characterise the star-disk interaction region in T Tauri stars that show photometric and spectroscopic variability. Methods: We used the GIANO instrument at the Telescopio Nazionale Galileo to obtain near-infrared high-resolution spectra (R 50 000) of XZ Tau and DR Tau, which are two actively accreting T Tauri stars classified as EXors. Equivalent widths and profiles of the observed features are used to derive information on the properties of the inner disk, the accretion columns, and the winds. Results: Both sources display composite H I line profiles, where contributions from both accreting gas and high-velocity winds can be recognised. These lines are progressively more symmetric and narrower with increasing upper energy which may be interpreted in terms of two components with different decrements or imputed to self-absorption effects. XZ Tau is observed in a relatively high state of activity with respect to literature observations. The variation of the He I 1.08 μm line blue-shifted absorption, in particular, suggests that the inner wind has undergone a dramatic change in its velocity structure, connected with a recent accretion event. DR Tau has a more stable wind as its He I 1.08 μm absorption does not show variations with time in spite of strong variability of the emission component. The IR veiling in the two sources can be interpreted as due to blackbody emission at temperatures of 1600 K and 2300 K for XZ Tau and DR Tau, respectively, with emitting areas 30 times larger than the central star. While for XZ Tau these conditions are consistent with emission from the inner rim of the dusty disk, the fairly high temperature inferred for DR Tau might suggest that its veiling originates from a thick gaseous disk located within the dust sublimation radius. Strong and broad metallic lines, mainly from C I and Fe I, are detected in XZ Tau, similar to those observed in other EXor sources during burst phases. At variance, DR Tau shows weaker and

Characterization by Fourier transform infrared spectroscopy (FT-IR) and 2D IR correlation spectroscopy of a carbosilane dendrimer with peripheral ammonium groups

Energy Technology Data Exchange (ETDEWEB)

Popescu, Maria-Cristina, E-mail: cpopescu@icmpp.ro [' Petru Poni' Institute of Macromolecular Chemistry (Romania); Gomez, Rafael; Mata, Fco Javier de la; Rasines, Beatriz [Universidad de Alcala, Departamento de Quimica Inorganica (Spain); Simionescu, Bogdan C. [' Petru Poni' Institute of Macromolecular Chemistry (Romania)

2013-06-15

Fourier transform infrared spectroscopy and 2D correlation spectroscopy were used to study the microstructural changes occurring on heating of a new carbosilane dendrimer with peripheral ammonium groups. Temperature-dependent spectral variations in the 3,010-2,710, 1,530-1,170, and 1,170-625 cm{sup -1} regions were monitored during the heating process. The dependence, on temperature, of integral absorptions and position of spectral bands was established and the spectral modifications associated with molecular conformation rearrangements, allowing molecular shape changes, were found. Before 180 Degree-Sign C, the studied carbosilane dendrimer proved to be stable, while at higher temperatures it oxidizes and Si-O groups appear. 2D IR correlation spectroscopy gives new information about the effect of temperature on the structure and dynamics of the system. Synchronous and asynchronous spectra indicate that, at low temperature, conformational changes of CH{sub 3} and CH{sub 3}-N{sup +} groups take place first. With increasing temperature, the intensity variation of the CH{sub 2}, C-N, Si-C and C-C groups from the dendritic core is faster than that of the terminal units. This indicates that, with increasing temperature, the segments of the dendritic core obtain enough energy to change their conformation more easily as compared to the terminal units, due to their internal flexibility.

Characterization by Fourier transform infrared spectroscopy (FT-IR) and 2D IR correlation spectroscopy of a carbosilane dendrimer with peripheral ammonium groups

International Nuclear Information System (INIS)

Popescu, Maria-Cristina; Gómez, Rafael; Mata, Fco Javier de la; Rasines, Beatriz; Simionescu, Bogdan C.

2013-01-01

Fourier transform infrared spectroscopy and 2D correlation spectroscopy were used to study the microstructural changes occurring on heating of a new carbosilane dendrimer with peripheral ammonium groups. Temperature-dependent spectral variations in the 3,010–2,710, 1,530–1,170, and 1,170–625 cm −1 regions were monitored during the heating process. The dependence, on temperature, of integral absorptions and position of spectral bands was established and the spectral modifications associated with molecular conformation rearrangements, allowing molecular shape changes, were found. Before 180 °C, the studied carbosilane dendrimer proved to be stable, while at higher temperatures it oxidizes and Si–O groups appear. 2D IR correlation spectroscopy gives new information about the effect of temperature on the structure and dynamics of the system. Synchronous and asynchronous spectra indicate that, at low temperature, conformational changes of CH 3 and CH 3 –N + groups take place first. With increasing temperature, the intensity variation of the CH 2 , C–N, Si–C and C–C groups from the dendritic core is faster than that of the terminal units. This indicates that, with increasing temperature, the segments of the dendritic core obtain enough energy to change their conformation more easily as compared to the terminal units, due to their internal flexibility.

Chemical profiling and adulteration screening of Aquilariae Lignum Resinatum by Fourier transform infrared (FT-IR) spectroscopy and two-dimensional correlation infrared (2D-IR) spectroscopy

Science.gov (United States)

Qu, Lei; Chen, Jian-bo; Zhang, Gui-Jun; Sun, Su-qin; Zheng, Jing

2017-03-01

As a kind of expensive perfume and valuable herb, Aquilariae Lignum Resinatum (ALR) is often adulterated for economic motivations. In this research, Fourier transform infrared (FT-IR) spectroscopy is employed to establish a simple and quick method for the adulteration screening of ALR. First, the principal chemical constituents of ALR are characterized by FT-IR spectroscopy at room temperature and two-dimensional correlation infrared (2D-IR) spectroscopy with thermal perturbation. Besides the common cellulose and lignin compounds, a certain amount of resin is the characteristic constituent of ALR. Synchronous and asynchronous 2D-IR spectra indicate that the resin (an unstable secondary metabolite) is more sensitive than cellulose and lignin (stable structural constituents) to the thermal perturbation. Using a certified ALR sample as the reference, the infrared spectral correlation threshold is determined by 30 authentic samples and 6 adulterated samples. The spectral correlation coefficient of an authentic ALR sample to the standard reference should be not less than 0.9886 (p = 0.01). Three commercial adulterated ALR samples are identified by the correlation threshold. Further interpretation of the infrared spectra of the adulterated samples indicates the common adulterating methods - counterfeiting with other kind of wood, adding ingredient such as sand to increase the weight, and adding the cheap resin such as rosin to increase the content of resin compounds. Results of this research prove that FT-IR spectroscopy can be used as a simple and accurate quality control method of ALR.

Airborne differential absorption lidar for water vapour measurements in the upper troposphere and lower stratosphere in the spectral region around 940 nm

Energy Technology Data Exchange (ETDEWEB)

Poberaj, G.

2000-07-01

Two all-solid-state laser systems were developed and studied in detail to optimise their performance for an airborne water vapour differential absorption lidar (DIAL). Their special features are high average output powers and excellent spectral properties in the 940-nm spectral region relevant for monitoring very low water vapour contents in the upper troposphere and lower stratosphere. One system is an injection-seeded pulsed Ti:sapphire ring laser with a spectral bandwidth of 105 MHz and an average power of 1.1 W. The other system is an injection-seeded optical parametric oscillator (OPO) in a ring configuration. Using KTP as nonlinear crystal, a signal output with a spectral bandwidth of 140 MHz and an average power of 1.2 W was achieved. Both systems, the Ti:sapphire ring laser and the KTP OPO, possess spectral purity values higher than 99%. The pump source for these systems is a frequency doubled diode-pumped Nd:YAG laser operating at a repetition rate of 100 Hz. The KTP OPO system has been used as a transmitter in a new airborne water vapour DIAL instrument. For the first time, measurements of two-dimensional water vapour distributions with a high vertical (500 m) and horizontal (20 km) resolution across several potential vorticity streamers were performed. Very low water vapour mixing ratios (10-50 ppmv) and strong gradients were observed in the tropopause region. The sensitivity of the DIAL instrument in the centre of a stratospheric intrusion ranges from 3% in the near field to 12% in the far field (4 km). The first comparison experiments with in situ measuring instruments show a good agreement. Considerable differences are found between DIAL measurements and data obtained from the ECMWF operational analyses and a mesoscale numerical model. (orig.)

Spectral reflectance study of the Hadley-Appenine (Apollo 15) region

International Nuclear Information System (INIS)

Lucey, P.G.; Hawke, B.R.

1985-01-01

Twenty three near infrared spectra were obtained from the Mauna Kea Observatory 2.2 m telescope. Results of an analysis of near infrared spectra obtained for surface units in the Hadley-Apennine region were presented. Compositional trends from the interior to exterior of the Imbrium are discussed

The Infrared Telescope Facility (IRTF) Spectral Library: Cool Stars

Science.gov (United States)

Rayner, John T.; Cushing, Michael C.; Vacca, William D.

2009-12-01

We present a 0.8-5 μm spectral library of 210 cool stars observed at a resolving power of R ≡ λ/Δλ ~ 2000 with the medium-resolution infrared spectrograph, SpeX, at the 3.0 m NASA Infrared Telescope Facility (IRTF) on Mauna Kea, Hawaii. The stars have well-established MK spectral classifications and are mostly restricted to near-solar metallicities. The sample not only contains the F, G, K, and M spectral types with luminosity classes between I and V, but also includes some AGB, carbon, and S stars. In contrast to some other spectral libraries, the continuum shape of the spectra is measured and preserved in the data reduction process. The spectra are absolutely flux calibrated using the Two Micron All Sky Survey photometry. Potential uses of the library include studying the physics of cool stars, classifying and studying embedded young clusters and optically obscured regions of the Galaxy, evolutionary population synthesis to study unresolved stellar populations in optically obscured regions of galaxies and synthetic photometry. The library is available in digital form from the IRTF Web site.

Using ATR-FT/IR to detect carbohydrate-related molecular structure features of carinata meal and their in situ residues of ruminal fermentation in comparison with canola meal

Science.gov (United States)

Xin, Hangshu; Yu, Peiqiang

2013-10-01

There is no information on the co-products from carinata bio-fuel and bio-oil processing (carinata meal) in molecular structural profiles mainly related to carbohydrate biopolymers in relation to ruminant nutrition. Molecular analyses with Fourier transform infrared spectroscopy (FT/IR) technique with attenuated total reflectance (ATR) and chemometrics enable to detect structural features on a molecular basis. The objectives of this study were to: (1) determine carbohydrate conformation spectral features in original carinata meal, co-products from bio-fuel/bio-oil processing; and (2) investigate differences in carbohydrate molecular composition and functional group spectral intensities after in situ ruminal fermentation at 0, 12, 24 and 48 h compared to canola meal as a reference. The molecular spectroscopic parameters of carbohydrate profiles detected were structural carbohydrates (STCHO, mainly associated with hemi-cellulosic and cellulosic compounds; region and baseline ca. 1483-1184 cm-1), cellulosic compounds (CELC, region and baseline ca. 1304-1184 cm-1), total carbohydrates (CHO, region and baseline ca. 1193-889 cm-1) as well as the spectral ratios calculated based on respective spectral intensity data. The results showed that the spectral profiles of carinata meal were significantly different from that of canola meal in CHO 2nd peak area (center at ca. 1091 cm-1, region: 1102-1083 cm-1) and functional group peak intensity ratios such as STCHO 1st peak (ca. 1415 cm-1) to 2nd peak (ca. 1374 cm-1) height ratio, CHO 1st peak (ca. 1149 cm-1) to 3rd peak (ca. 1032 cm-1) height ratio, CELC to total CHO area ratio and STCHO to CELC area ratio, indicating that carinata meal may not in full accord with canola meal in carbohydrate utilization and availability in ruminants. Carbohydrate conformation and spectral features were changed by significant interaction of meal type and incubation time and almost all the spectral parameters were significantly decreased (P

Non-invasive, MRI-compatible fibreoptic device for functional near-IR reflectometry of human brain

International Nuclear Information System (INIS)

Sorvoja, H.S.S.; Myllylae, T S; Myllylae, Risto A; Kirillin, M Yu; Sergeeva, Ekaterina A; Elseoud, A A; Nikkinen, J; Tervonen, O; Kiviniemi, V

2011-01-01

A non-invasive device for measuring blood oxygen variations in human brain is designed, implemented, and tested for MRI compatibility. The device is based on principles of near-IR reflectometry; power LEDs serve as sources of probing radiation delivered to patient skin surface through optical fibres. Numerical Monte Carlo simulations of probing radiation propagation in a multilayer brain model are performed to evaluate signal levels at different source - detector separations at three operation wavelengths and an additional wavelength of 915 nm. It is shown that the device can be applied for brain activity studies using power LEDs operating at 830 and 915 nm, while employment of wavelength of 660 nm requires an increased probing power. Employment of the wavelength of 592 nm in the current configuration is unreasonable. (application of lasers and laser-optical methods in life sciences)

Model and measurements of linear mixing in thermal IR ground leaving radiance spectra

Science.gov (United States)

Balick, Lee; Clodius, William; Jeffery, Christopher; Theiler, James; McCabe, Matthew; Gillespie, Alan; Mushkin, Amit; Danilina, Iryna

2007-10-01

Hyperspectral thermal IR remote sensing is an effective tool for the detection and identification of gas plumes and solid materials. Virtually all remotely sensed thermal IR pixels are mixtures of different materials and temperatures. As sensors improve and hyperspectral thermal IR remote sensing becomes more quantitative, the concept of homogeneous pixels becomes inadequate. The contributions of the constituents to the pixel spectral ground leaving radiance are weighted by their spectral emissivities and their temperature, or more correctly, temperature distributions, because real pixels are rarely thermally homogeneous. Planck's Law defines a relationship between temperature and radiance that is strongly wavelength dependent, even for blackbodies. Spectral ground leaving radiance (GLR) from mixed pixels is temperature and wavelength dependent and the relationship between observed radiance spectra from mixed pixels and library emissivity spectra of mixtures of 'pure' materials is indirect. A simple model of linear mixing of subpixel radiance as a function of material type, the temperature distribution of each material and the abundance of the material within a pixel is presented. The model indicates that, qualitatively and given normal environmental temperature variability, spectral features remain observable in mixtures as long as the material occupies more than roughly 10% of the pixel. Field measurements of known targets made on the ground and by an airborne sensor are presented here and serve as a reality check on the model. Target spectral GLR from mixtures as a function of temperature distribution and abundance within the pixel at day and night are presented and compare well qualitatively with model output.

Toward optimal spatial and spectral quality in widefield infrared spectromicroscopy of IR labelled single cells.

Science.gov (United States)

Mattson, Eric C; Unger, Miriam; Clède, Sylvain; Lambert, François; Policar, Clotilde; Imtiaz, Asher; D'Souza, Roshan; Hirschmugl, Carol J

2013-10-07

Advancements in widefield infrared spectromicroscopy have recently been demonstrated following the commissioning of IRENI (InfraRed ENvironmental Imaging), a Fourier Transform infrared (FTIR) chemical imaging beamline at the Synchrotron Radiation Center. The present study demonstrates the effects of magnification, spatial oversampling, spectral pre-processing and deconvolution, focusing on the intracellular detection and distribution of an exogenous metal tris-carbonyl derivative 1 in a single MDA-MB-231 breast cancer cell. We demonstrate here that spatial oversampling for synchrotron-based infrared imaging is critical to obtain accurate diffraction-limited images at all wavelengths simultaneously. Resolution criteria and results from raw and deconvoluted images for two Schwarzschild objectives (36×, NA 0.5 and 74×, NA 0.65) are compared to each other and to prior reports for raster-scanned, confocal microscopes. The resolution of the imaging data can be improved by deconvolving the instrumental broadening that is determined with the measured PSFs, which is implemented with GPU programming architecture for fast hyperspectral processing. High definition, rapidly acquired, FTIR chemical images of respective spectral signatures of the cell 1 and shows that 1 is localized next to the phosphate- and Amide-rich regions, in agreement with previous infrared and luminescence studies. The infrared image contrast, localization and definition are improved after applying proven spectral pre-processing (principal component analysis based noise reduction and RMie scattering correction algorithms) to individual pixel spectra in the hyperspectral cube.

Generalized radiative transfer theory for scattering by particles in an absorbing gas: Addressing both spatial and spectral integration in multi-angle remote sensing of optically thin aerosol layers

Science.gov (United States)

Davis, Anthony B.; Xu, Feng; Diner, David J.

2018-01-01

We demonstrate the computational advantage gained by introducing non-exponential transmission laws into radiative transfer theory for two specific situations. One is the problem of spatial integration over a large domain where the scattering particles cluster randomly in a medium uniformly filled with an absorbing gas, and only a probabilistic description of the variability is available. The increasingly important application here is passive atmospheric profiling using oxygen absorption in the visible/near-IR spectrum. The other scenario is spectral integration over a region where the absorption cross-section of a spatially uniform gas varies rapidly and widely and, moreover, there are scattering particles embedded in the gas that are distributed uniformly, or not. This comes up in many applications, O2 A-band profiling being just one instance. We bring a common framework to solve these problems both efficiently and accurately that is grounded in the recently developed theory of Generalized Radiative Transfer (GRT). In GRT, the classic exponential law of transmission is replaced by one with a slower power-law decay that accounts for the unresolved spectral or spatial variability. Analytical results are derived in the single-scattering limit that applies to optically thin aerosol layers. In spectral integration, a modest gain in accuracy is obtained. As for spatial integration of near-monochromatic radiance, we find that, although both continuum and in-band radiances are affected by moderate levels of sub-pixel variability, only extreme variability will affect in-band/continuum ratios.

Bedload transport from spectral analysis of seismic noise near rivers

Science.gov (United States)

Hsu, L.; Finnegan, N. J.; Brodsky, E. E.

2010-12-01

Channel change in rivers is driven by bedload sediment transport. However, the nonlinear nature of sediment transport combined with the difficulty of making direct observations in rivers at flood hinder prediction of the timing and magnitude of bedload movement. Recent studies have shown that spectral analysis of seismic noise from seismometers near rivers illustrate a correlation between the relative amplitude of high frequency (>1 Hz) seismic noise and conditions for bedload transport, presumably from the energy transferred from clast collisions with the channel. However, a previous study in the Himalayas did not contain extensive bedload transport or discharge measurements, and the correspondence of seismic noise with proxy variables such as regional hydrologic and meteorologic data was not exact. A more complete understanding of the relationship between bedload transport and seismic noise would be valuable for extending the spatial and temporal extent of bedload data. To explore the direct relationship between bedload transport and seismic noise, we examine data from several seismic stations near the Trinity River in California, where the fluvial morphodynamics and bedload rating curves have been studied extensively. We compare the relative amplitude of the ambient seismic noise with records of water discharge and sediment transport. We also examine the noise at hourly, daily, and seasonal timescales to determine other possible sources of noise. We report the influence of variables such as local river slope, adjacent geology, anthropogenic noise, and distance from the river. The results illustrate the feasibility of using existing seismic arrays to sense radiated energy from processes of bedload transport. In addition, the results can be used to design future seismic array campaigns to optimize information about bedload transport. This technique provides great spatial and temporal coverage, and can be performed where direct bedload measurements are difficult or

Near-infrared light absorption by brown carbon in the ambient atmosphere

Science.gov (United States)

Chung, C.; Hoffer, A.; Beres, N. D.; Moosmüller, H.; Liu, C.; Green, M.; Kim, S. W.; Engelbrecht, J. P.; Gelencser, A.

2017-12-01

Organic aerosols have been assumed to have little-to-no absorption in the red and near-infrared spectral regions of solar radiation, even though a class of organic aerosols were shown to absorb significantly in these spectral regions. Here, we show that ambient atmospheric data from commonly-used 7-wavelength aethalometers contain evidence of abundant near-infrared light absorption by organic aerosol. This evidence comes from the absorption Ångström exponent over 880 950 nm, which often exceeds values explainable by fresh or coated black carbon, or mineral dust. This evidence is not due to an artifact from the instrument random errors or biases, either. The best explanation for these large 880/950 nm absorption Ångström exponent values in the aethalometer data is near-infrared light absorption by tar balls. Tar balls are among common particles from forest fire.

Airborne pipeline leak detection: UV or IR?

Science.gov (United States)

Babin, François; Gravel, Jean-François; Allard, Martin

2016-05-01

This paper presents a study of different approaches to the measurement of the above ground vapor plume created by the spill caused by a small 0.1 l/min (or less) leak in an underground liquid petroleum pipeline. The scenarios are those for the measurement from an airborne platform. The usual approach is that of IR absorption, but in the case of liquid petroleum products, there are drawbacks that will be discussed, especially when using alkanes to detect a leak. The optical measurements studied include UV enhanced Raman lidar, UV fluorescence lidar and IR absorption path integrated lidars. The breadboards used for testing the different approaches will be described along with the set-ups for leak simulation. Although IR absorption would intuitively be the most sensitive, it is shown that UV-Raman could be an alternative. When using the very broad alkane signature in the IR, the varying ground spectral reflectance are a problem. It is also determined that integrated path measurements are preferred, the UV enhanced Raman measurements showing that the vapor plume stays very close to the ground.

Assessing mine drainage pH from the color and spectral reflectance of chemical precipitates

Science.gov (United States)

Williams, D.J.; Bigham, J.M.; Cravotta, C.A.; Traina, S.J.; Anderson, J.E.; Lyon, J.G.

2002-01-01

The pH of mine impacted waters was estimated from the spectral reflectance of resident sediments composed mostly of chemical precipitates. Mine drainage sediments were collected from sites in the Anthracite Region of eastern Pennsylvania, representing acid to near neutral pH. Sediments occurring in acidic waters contained primarily schwertmannite and goethite while near neutral waters produced ferrihydrite. The minerals comprising the sediments occurring at each pH mode were spectrally separable. Spectral angle difference mapping was used to correlate sediment color with stream water pH (r2=0.76). Band-center and band-depth analysis of spectral absorption features were also used to discriminate ferrihydrite and goethite and/or schwertmannite by analyzing the 4T1??? 6A1 crystal field transition (900-1000 nm). The presence of these minerals accurately predicted stream water pH (r2=0.87) and provided a qualitative estimate of dissolved SO4 concentrations. Spectral analysis results were used to analyze airborne digital multispectral video (DMSV) imagery for several sites in the region. The high spatial resolution of the DMSV sensor allowed for precise mapping of the mine drainage sediments. The results from this study indicate that airborne and space-borne imaging spectrometers may be used to accurately classify streams impacted by acid vs. neutral-to-alkaline mine drainage after appropriate spectral libraries are developed.

Infrared spectral imaging as a novel approach for histopathological recognition in colon cancer diagnosis

Science.gov (United States)

Nallala, Jayakrupakar; Gobinet, Cyril; Diebold, Marie-Danièle; Untereiner, Valérie; Bouché, Olivier; Manfait, Michel; Sockalingum, Ganesh Dhruvananda; Piot, Olivier

2012-11-01

Innovative diagnostic methods are the need of the hour that could complement conventional histopathology for cancer diagnosis. In this perspective, we propose a new concept based on spectral histopathology, using IR spectral micro-imaging, directly applied to paraffinized colon tissue array stabilized in an agarose matrix without any chemical pre-treatment. In order to correct spectral interferences from paraffin and agarose, a mathematical procedure is implemented. The corrected spectral images are then processed by a multivariate clustering method to automatically recover, on the basis of their intrinsic molecular composition, the main histological classes of the normal and the tumoral colon tissue. The spectral signatures from different histological classes of the colonic tissues are analyzed using statistical methods (Kruskal-Wallis test and principal component analysis) to identify the most discriminant IR features. These features allow characterizing some of the biomolecular alterations associated with malignancy. Thus, via a single analysis, in a label-free and nondestructive manner, main changes associated with nucleotide, carbohydrates, and collagen features can be identified simultaneously between the compared normal and the cancerous tissues. The present study demonstrates the potential of IR spectral imaging as a complementary modern tool, to conventional histopathology, for an objective cancer diagnosis directly from paraffin-embedded tissue arrays.

Water vapor absorption coefficients in the 8-13-micron spectral region - A critical review

Science.gov (United States)

Grant, William B.

1990-01-01

Measurements of water vapor absorption coefficients in the thermal IR atmospheric window (8-13 microns) during the past 20 years obtained by a variety of techniques are reviewed for consistency and compared with computed values based on the AFGL spectral data tapes. The methods of data collection considered were atmospheric long path absorption with a CO2 laser or a broadband source and filters, a White cell and a CO2 laser or a broadband source and a spectrometer, and a spectrophone with a CO2 laser. Advantages and disadvantages of each measurement approach are given as a guide to further research. Continuum absorption has apparently been measured accurately to about the 5-10 percent level in five of the measurements reported.

DUST IN THE POLAR REGION AS A MAJOR CONTRIBUTOR TO THE INFRARED EMISSION OF ACTIVE GALACTIC NUCLEI

Energy Technology Data Exchange (ETDEWEB)

Hoenig, S. F.; Antonucci, R. [Department of Physics, University of California in Santa Barbara, Broida Hall, Santa Barbara, CA 93109 (United States); Kishimoto, M.; Tristram, K. R. W.; Asmus, D.; Weigelt, G. [Max-Planck-Institut fuer Radioastronomie, Auf dem Huegel 69, D-53121 Bonn (Germany); Prieto, M. A. [Instituto de Astrofisica de Canarias, E-38200 La Laguna, Tenerife (Spain); Gandhi, P. [Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency, 3-1-1 Yoshinodai, chuo-ku, Sagamihara, Kanagawa 252-5210 (Japan); Burtscher, L. [Max-Planck-Institut fuer extraterrestrische Physik, Giessenbachstrae, D-85748 Garching (Germany); Duschl, W. J., E-mail: shoenig@physics.ucsb.edu [Institut fuer Theoretische Physik und Astrophysik, Christian-Albrechts-Universitaet zu Kiel, Leibnizstr. 15, D-24098, Kiel (Germany)

2013-07-10

Dust around active galactic nuclei (AGNs) is distributed over a wide range of spatial scales and can be observed in the infrared (IR). It is generally assumed that the distribution on parsec scales forms a geometrically and optically thick entity in the equatorial plane around the accretion disk and broad-line region-dubbed {sup d}ust torus{sup -}that emits the bulk of the subarcsecond-scale IR emission and gives rise to orientation-dependent obscuration. However, recent IR interferometry studies with unprecedented position angle (P.A.) and baseline coverage on these small scales in two obscured (type 2) AGNs have revealed that the majority of the mid-IR emission in these objects is elongated in the polar direction. These observations are difficult to reconcile with the standard interpretation that most of the parsec-scale mid-IR emission in AGNs originate from the torus and challenges the justification of using simple torus models to model the broadband IR emission. Here, we report detailed interferometry observations of the unobscured (type 1) AGN in NGC 3783 that allow us to constrain the size, elongation, and direction of the mid-IR emission with high accuracy. The mid-IR emission is characterized by a strong elongation toward position angle P.A. -52 Degree-Sign , closely aligned with the polar axis (P.A. -45 Degree-Sign ). We determine half-light radii along the major and minor axes at 12.5 {mu}m of (20.0 {+-} 3.0) mas Multiplication-Sign (6.7 {+-} 1.0) mas or (4.23 {+-} 0.63) pc Multiplication-Sign (1.42 {+-} 0.21) pc, which corresponds to intrinsically scaled sizes of (69.4 {+-} 10.8) r{sub in} Multiplication-Sign (23.3 {+-} 3.5) r{sub in} for the inner dust radius of r{sub in} = 0.061 pc as inferred from near-IR reverberation mapping. This implies an axis ratio of 3:1, with about 60%-90% of the 8-13 {mu}m emission associated with the polar-elongated component. It is quite likely that the hot-dust emission as recently resolved by near-IR interferometry is

FAST VARIABILITY AND MILLIMETER/IR FLARES IN GRMHD MODELS OF Sgr A* FROM STRONG-FIELD GRAVITATIONAL LENSING

Energy Technology Data Exchange (ETDEWEB)

Chan, Chi-kwan; Psaltis, Dimitrios; Özel, Feryal; Marrone, Daniel [Steward Observatory and Department of Astronomy, University of Arizona, 933 N. Cherry Avenue, Tucson, AZ 85721 (United States); Medeiros, Lia [Department of Physics, Broida Hall, University of California, Santa Barbara, Santa Barbara, CA 93106 (United States); Sadowski, Aleksander [MIT Kavli Institute for Astrophysics and Space Research, 77 Massachusetts Avenue, Cambridge, MA 02139 (United States); Narayan, Ramesh, E-mail: chanc@email.arizona.edu [Institute for Theory and Computation, Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)

2015-10-20

We explore the variability properties of long, high-cadence general relativistic magnetohydrodynamic (GRMHD) simulations across the electromagnetic spectrum using an efficient, GPU-based radiative transfer algorithm. We focus on both standard and normal evolution (SANE) and magnetically arrested disk (MAD) simulations with parameters that successfully reproduce the time-averaged spectral properties of Sgr A* and the size of its image at 1.3 mm. We find that the SANE models produce short-timescale variability with amplitudes and power spectra that closely resemble those inferred observationally. In contrast, MAD models generate only slow variability at lower flux levels. Neither set of models shows any X-ray flares, which most likely indicates that additional physics, such as particle acceleration mechanisms, need to be incorporated into the GRMHD simulations to account for them. The SANE models show strong, short-lived millimeter/infrared (IR) flares, with short (≲1 hr) time lags between the millimeter and IR wavelengths, that arise from the combination of short-lived magnetic flux tubes and strong-field gravitational lensing near the horizon. Such events provide a natural explanation for the observed IR flares with no X-ray counterparts.

A comparison of telescopic and Phobos-2 ISM spectra of Mars in the short-wave near-infrared (0.76-1.02 microns)

Science.gov (United States)

Bell, James F., III; Mustard, John F.

1993-01-01

Recent analyses of near-IR (0.76-3.16 microns) Mars surface reflectance spectra obtained by the Phobos-2 ISM instrument during early 1989 have revealed the presence of substantial variability in surface spectral properties. Strong absorption features seen in the 0.85-1.05 micron region are up to 10-15 percent deep relative to the local continuum and have been interpreted as evidence of Fe(2+) and Fe(3+) bearing minerals (pyroxenes and iron oxides, respectively). Though these observed band depths are comparable to those seen in laboratory reflectance spectra, they are up to three times larger than most previously reported band depths for Mars spectra at these wavelengths. Six regions of variable albedo and geologic setting were identified where ISM and 1988 opposition telescopic coverage either overlapped physically or sampled the same surface geologic unit. The areal sizes and positions of the regions measured telescopically were compiled by Bell et al. ISM pixels falling within these spots were averaged to produce a spatially convolved spectrum that simulates what would have been seen telescopically. To facilitate comparisons of absorption band positions and relative strengths, the convolved ISM data and the 1988 telescopic spectra were scaled to unity at 0.81 microns and are presented. The data have also been convolved to equivalent band pass normalized reflectances in the region of spectral overlap. A scatter diagram of telescopic vs. ISM reflectances is shown. The results from the investigation are discussed.

Chemical profiling and adulteration screening of Aquilariae Lignum Resinatum by Fourier transform infrared (FT-IR) spectroscopy and two-dimensional correlation infrared (2D-IR) spectroscopy.

Science.gov (United States)

Qu, Lei; Chen, Jian-Bo; Zhang, Gui-Jun; Sun, Su-Qin; Zheng, Jing

2017-03-05

As a kind of expensive perfume and valuable herb, Aquilariae Lignum Resinatum (ALR) is often adulterated for economic motivations. In this research, Fourier transform infrared (FT-IR) spectroscopy is employed to establish a simple and quick method for the adulteration screening of ALR. First, the principal chemical constituents of ALR are characterized by FT-IR spectroscopy at room temperature and two-dimensional correlation infrared (2D-IR) spectroscopy with thermal perturbation. Besides the common cellulose and lignin compounds, a certain amount of resin is the characteristic constituent of ALR. Synchronous and asynchronous 2D-IR spectra indicate that the resin (an unstable secondary metabolite) is more sensitive than cellulose and lignin (stable structural constituents) to the thermal perturbation. Using a certified ALR sample as the reference, the infrared spectral correlation threshold is determined by 30 authentic samples and 6 adulterated samples. The spectral correlation coefficient of an authentic ALR sample to the standard reference should be not less than 0.9886 (p=0.01). Three commercial adulterated ALR samples are identified by the correlation threshold. Further interpretation of the infrared spectra of the adulterated samples indicates the common adulterating methods - counterfeiting with other kind of wood, adding ingredient such as sand to increase the weight, and adding the cheap resin such as rosin to increase the content of resin compounds. Results of this research prove that FT-IR spectroscopy can be used as a simple and accurate quality control method of ALR. Copyright © 2016 Elsevier B.V. All rights reserved.

Ir Spectroscopic Studies on Microsolvation of HCl by Water

Science.gov (United States)

Mani, Devendra; Schwan, Raffael; Fischer, Theo; Dey, Arghya; Kaufmann, Matin; Redlich, Britta; van der Meer, Lex; Schwaab, Gerhard; Havenith, Martina

2016-06-01

Acid dissociation reactions are at the heart of chemistry. These reactions are well understood at the macroscopic level. However, a microscopic level understanding is still in the early stages of development. Questions such as 'how many H_2O molecules are needed to dissociate one HCl molecule?' have been posed and explored both theoretically and experimentally.1-5 Most of the theoretical calculations predict that four H_2O molecules are sufficient to dissociate one HCl molecule, resulting in the formation of a solvent separated H_3O+(H_2O)3Cl- cluster.1-3 IR spectroscopy in helium nanodroplets has earlier been used to study this dissociation process.3-5 However, these studies were carried out in the region of O-H and H-Cl stretch, which is dominated by the spectral features of undissociated (HCl)m-(H_2O)n clusters. This contributed to the ambiguity in assigning the spectral features arising from the dissociated cluster.4,5 Recent predictions from Bowman's group, suggest the presence of a broad spectral feature (1300-1360 wn) for the H_3O+(H_2O)3Cl- cluster, corresponding to the umbrella motion of H_3O+ moiety.6 This region is expected to be free from the spectral features due to the undissociated clusters. In conjunction with the FELIX laboratory, we have performed experiments on the (HCl)m(H_2O)n (m=1-2, n≥4) clusters, aggregated in helium nanodroplets, in the 900-1700 wn region. Mass selective measurements on these clusters revealed the presence of a weak-broad feature which spans between 1000-1450 wn and depends on both HCl as well as H_2O concentration. Measurements are in progress for the different deuterated species. The details will be presented in the talk. References: 1) C.T. Lee et al., J. Chem. Phys., 104, 7081 (1996). 2) H. Forbert et al., J. Am. Chem. Soc., 133, 4062 (2011). 3) A. Gutberlet et al., Science, 324, 1545 (2009). 4) S. D. Flynn et al., J. Phys. Chem. Lett., 1, 2233 (2010). 5) M. Letzner et al., J. Chem. Phys., 139, 154304 (2013). 6) J. M

Spectroscopic studies of ozone in cryosolutions: FT-IR spectra of 16O3 in liquid nitrogen, oxygen, argon and krypton

Science.gov (United States)

Bulanin, Kirill M.; Bulanin, Michael O.; Rudakova, Aida V.; Kolomijtsova, Tatiana D.; Shchepkin, Dmitrij N.

2018-03-01

We have measured and interpreted the IR spectra of ozone dissolved in liquid nitrogen, oxygen, argon, and krypton in the 650-4700 cm-1 spectral region at 79-117 K. Frequency shifts, band intensities and bandshapes of 22 spectral features of soluted ozone were analyzed. The bands of the A1 symmetry have a complex contour and possess an excess intensity with respect to the value of the purely vibrational transition moment. It was found that this effect is related to the manifestation of the Coriolis interaction. The bandshape distortion manifests itself as an additional intensity from the side of the B1 symmetry band being an intensity source in the case of the Coriolis interaction.

Spectral Slope as an Indicator of Pasture Quality

Directory of Open Access Journals (Sweden)

Rachel Lugassi

2014-12-01

Full Text Available In this study, we develop a spectral method for assessment of pasture quality based only on the spectral information obtained with a small number of wavelengths. First, differences in spectral behavior were identified across the near infrared–shortwave infrared spectral range that were indicative of changes in chemical properties. Then, slopes across different spectral ranges were calculated and correlated with the changes in crude protein (CP, neutral detergent fiber (NDF and metabolic energy concentration (MEC. Finally, partial least squares (PLS regression analysis was applied to identify the optimal spectral ranges for accurate assessment of CP, NDF and MEC. Six spectral domains and a set of slope criteria for real-time evaluation of pasture quality were suggested. The evaluation of three level categories (low, medium, high for these three parameters showed a success rate of: 73%–96% for CP, 72%–87% for NDF and 60%–85% for MEC. Moreover, only one spectral range, 1748–1764 nm, was needed to provide a good estimation of CP, NDF and MEC. Importantly, five of the six selected spectral regions were not affected by water absorbance. With some modifications, this rationale can be applied to further analyses of pasture quality from airborne sensors.

A SURVEY FOR NEW MEMBERS OF THE TAURUS STAR-FORMING REGION WITH THE SLOAN DIGITAL SKY SURVEY

International Nuclear Information System (INIS)

Luhman, K. L.; Mamajek, E. E.; Shukla, S. J.; Loutrel, N. P.

2017-01-01

Previous studies have found that ∼1 deg 2 fields surrounding the stellar aggregates in the Taurus star-forming region exhibit a surplus of solar-mass stars relative to denser clusters like IC 348 and the Orion Nebula Cluster. To test whether this difference reflects mass segregation in Taurus or a variation in the initial mass function, we have performed a survey for members of Taurus across a large field (∼40 deg 2 ) that was imaged by the Sloan Digital Sky Survey (SDSS). We obtained optical and near-infrared spectra of candidate members identified with those images and the Two Micron All Sky Survey, as well as miscellaneous candidates that were selected with several other diagnostics of membership. We have classified 22 of the candidates as new members of Taurus, which includes one of the coolest known members (M9.75). Our updated census of members within the SDSS field shows a surplus of solar-mass stars relative to clusters, although it is less pronounced than in the smaller fields toward the stellar aggregates that were surveyed for previously measured mass functions in Taurus. In addition to spectra of our new members, we include in our study near-IR spectra of roughly half of the known members of Taurus, which are used to refine their spectral types and extinctions. We also present an updated set of near-IR standard spectra for classifying young stars and brown dwarfs at M and L types.

A SURVEY FOR NEW MEMBERS OF THE TAURUS STAR-FORMING REGION WITH THE SLOAN DIGITAL SKY SURVEY

Energy Technology Data Exchange (ETDEWEB)

Luhman, K. L. [Department of Astronomy and Astrophysics, The Pennsylvania State University, University Park, PA 16802 (United States); Mamajek, E. E. [Department of Physics and Astronomy, The University of Rochester, Rochester, NY 14627 (United States); Shukla, S. J. [Institute of Astronomy, Madingley Road, Cambridge CB3 0HA (United Kingdom); Loutrel, N. P., E-mail: kluhman@astro.psu.edu [eXtreme Gravity Institute, Department of Physics, Montana State University, Bozeman, MT 59715 (United States)

2017-01-01

Previous studies have found that ∼1 deg{sup 2} fields surrounding the stellar aggregates in the Taurus star-forming region exhibit a surplus of solar-mass stars relative to denser clusters like IC 348 and the Orion Nebula Cluster. To test whether this difference reflects mass segregation in Taurus or a variation in the initial mass function, we have performed a survey for members of Taurus across a large field (∼40 deg{sup 2}) that was imaged by the Sloan Digital Sky Survey (SDSS). We obtained optical and near-infrared spectra of candidate members identified with those images and the Two Micron All Sky Survey, as well as miscellaneous candidates that were selected with several other diagnostics of membership. We have classified 22 of the candidates as new members of Taurus, which includes one of the coolest known members (M9.75). Our updated census of members within the SDSS field shows a surplus of solar-mass stars relative to clusters, although it is less pronounced than in the smaller fields toward the stellar aggregates that were surveyed for previously measured mass functions in Taurus. In addition to spectra of our new members, we include in our study near-IR spectra of roughly half of the known members of Taurus, which are used to refine their spectral types and extinctions. We also present an updated set of near-IR standard spectra for classifying young stars and brown dwarfs at M and L types.

THE ROLE OF THE ACCRETION DISK, DUST, AND JETS IN THE IR EMISSION OF LOW-LUMINOSITY ACTIVE GALACTIC NUCLEI

Energy Technology Data Exchange (ETDEWEB)

Mason, R. E. [Gemini Observatory, Northern Operations Center, 670 N. A' ohoku Place, Hilo, HI 96720 (United States); Ramos Almeida, C. [Instituto de Astrofísica de Canarias, C/Vía Láctea, s/n, E-38205 La Laguna, Tenerife (Spain); Levenson, N. A. [Gemini Observatory, Southern Operations Center, c/o AURA, Casilla 603, La Serena (Chile); Nemmen, R. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Alonso-Herrero, A., E-mail: rmason@gemini.edu [Instituto de Física de Cantabria, CSIC-UC, Avenida de los Castros s/n, E-39005 Santander (Spain)

2013-11-10

We use recent high-resolution infrared (IR; 1-20 μm) photometry to examine the origin of the IR emission in low-luminosity active galactic nuclei (LLAGN). The data are compared with published model fits that describe the spectral energy distribution (SED) of LLAGN in terms of an advection-dominated accretion flow, truncated thin accretion disk, and jet. The truncated disk in these models is usually not luminous enough to explain the observed IR emission, and in all cases its spectral shape is much narrower than the broad IR peaks in the data. Synchrotron radiation from the jet appears to be important in very radio-loud nuclei, but the detection of strong silicate emission features in many objects indicates that dust must also contribute. We investigate this point by fitting the IR SED of NGC 3998 using dusty torus and optically thin (τ{sub mid-IR} ∼ 1) dust shell models. While more detailed modeling is necessary, these initial results suggest that dust may account for the nuclear mid-IR emission of many LLAGN.

IR Spectroscopy. An introduction

International Nuclear Information System (INIS)

Guenzler, H.; Gremlich, H.U.

2002-01-01

The following topics are dealt with: absorption and molecular design, spectrometers, sample preparation, qualitative spectral interpretation and assertions, near-infrared and far-infrared spectroscopy, reference spectra and expert systems

Rapid identification of soil cadmium pollution risk at regional scale based on visible and near-infrared spectroscopy

International Nuclear Information System (INIS)

Chen, Tao; Chang, Qingrui; Clevers, J.G.P.W.; Kooistra, L.

2015-01-01

Soil heavy metal pollution due to long-term sewage irrigation is a serious environmental problem in many irrigation areas in northern China. Quickly identifying its pollution status is an important basis for remediation. Visible-near-infrared reflectance spectroscopy (VNIRS) provides a useful tool. In a case study, 76 soil samples were collected and their reflectance spectra were used to estimate cadmium (Cd) concentration by partial least squares regression (PLSR) and back propagation neural network (BPNN). To reduce noise, six pre-treatments were compared, in which orthogonal signal correction (OSC) was first used in soil Cd estimation. Spectral analysis and geostatistics were combined to identify Cd pollution hotspots. Results showed that Cd was accumulated in topsoil at the study area. OSC can effectively remove irrelevant information to improve prediction accuracy. More accurate estimation was achieved by applying a BPNN. Soil Cd pollution hotspots could be identified by interpolating the predicted values obtained from spectral estimates. - Highlights: • Soil reflectance spectroscopy provides a promising tool for detecting soil contaminants. • Orthogonal signal correction efficiently extracted information from noisy spectra. • Back propagation neural network achieved a more accurate estimation for soil Cd. • Soil Cd pollution hotspots could be identified by interpolating the predicted Cd. - Combining spectral analysis and geostatistics can provide a rapid method for identifying the pollution hotspot of soil heavy metal at regional scale.

Dielectric properties of semi-insulating Fe-doped InP in the terahertz spectral region.

Science.gov (United States)

Alyabyeva, L N; Zhukova, E S; Belkin, M A; Gorshunov, B P

2017-08-04

We report the values and the spectral dependence of the real and imaginary parts of the dielectric permittivity of semi-insulating Fe-doped InP crystalline wafers in the 2-700 cm -1 (0.06-21 THz) spectral region at room temperature. The data shows a number of absorption bands that are assigned to one- and two-phonon and impurity-related absorption processes. Unlike the previous studies of undoped or low-doped InP material, our data unveil the dielectric properties of InP that are not screened by strong free-carrier absorption and will be useful for designing a wide variety of InP-based electronic and photonic devices operating in the terahertz spectral range.

Spectral Comparison and Stability of Red Regions on Jupiter

Science.gov (United States)

Simon, A. A.; Carlson, R. W.; Sanchez-Lavega, A.

2013-01-01

A study of absolute color on Jupiter from Hubble Space Telescope imaging data shows that the Great Red Spot (GRS) is not the reddest region of the planet. Rather, a transient red cyclone visible in 1995 and the North Equatorial Belt both show redder spectra than the GRS (i.e., more absorption at blue and green wavelengths). This cyclone is unique among vortices in that it is intensely colored yet low altitude, unlike the GRS. Temporal analysis shows that the darkest regions of the NEB are relative constant in color from 1995 to 2008, while the slope of the GRS core may vary slightly. Principal component analysis shows several spectral components are needed, in agreement with past work, and further highlights the differences between regions. These color differences may be indicative of the same chromophore(s) under different conditions, such as mixing with white clouds, longer UV irradiation at higher altitude, and thermal processing, or may indicate abundance variations in colored compounds. A single compound does not fit the spectrum of any region well and mixes of multiple compounds including NH4SH, photolyzed NH3, hydrocarbons, and possibly P4, are likely needed to fully match each spectrum.

Isolated Gramicidin Peptides Probed by IR Spectroscopy

NARCIS (Netherlands)

Rijs, A. M.; Kabelac, M.; Abo-Riziq, A.; Hobza, P.; de Vries, M. S.

2011-01-01

We report double-resonant IR/UV ion-dip spectroscopy of neutral gramicidin peptides in the gas phase. The IR spectra of gramicidin A and C, recorded in both the 1000 cm(-1) to 1800 cm(-1) and the 2700 to 3750 cm(-1) region, allow structural analysis. By studying this broad IR range, various local

Oxadiazole-carbazole polymer (POC)-Ir(ppy)3 tunable emitting composites

Science.gov (United States)

Bruno, Annalisa; Borriello, Carmela; Di Luccio, Tiziana; Sessa, Lucia; Concilio, Simona; Haque, Saif A.; Minarini, Carla

2017-04-01

POC polymer is an oxadiazole-carbazole copolymer we have previously synthetized and established as light emitting material in Organic Light Emitting Devices (OLEDs), although POC quantum yield emission efficiency and color purity still need to be enhanced. On the other hand, tris[2-phenylpyridinato-C2,N]iridium(III) (Ir(ppy)3) complexes, namely Ir(ppy)3 are among the brightest luminophores employed in green light emitting devices. Our aim, in this work, is to take advantage of Ir(ppy)3 bright emission by combining the Ir complex with blue emitting POC to obtain tunable light emitting composites over a wide range of the visible spectrum. Here we have investigated the optical proprieties POC based nanocomposites with different concentrations of Ir(ppy)3, ranging from 1 to 10 wt%. Both spectral and time resolved fluorescence measurements show an efficient energy transfer from the polymer to the dopants, resulting in white-emitting composites. The most intense and stable emission has been found when POC was doped with about 5 wt% concentration of Ir(ppy)3.

High-z X-ray Obscured Quasars in Galaxies with Extreme Mid-IR/Optical Colors

Science.gov (United States)

Piconcelli, E.; Lanzuisi, G.; Fiore, F.; Feruglio, C.; Vignali, C.; Salvato, M.; Grappioni, C.

2009-05-01

Extreme Optical/Mid-IR color cuts have been used to uncover a population of dust-enshrouded, mid-IR luminous galaxies at high redshifts. Several lines of evidence point towards the presence of an heavily absorbed, possibly Compton-thick quasar at the heart of these systems. Nonetheless, the X-ray spectral properties of these intriguing sources still remain largely unexplored. Here we present an X-ray spectroscopic study of a large sample of 44 extreme dust-obscured galaxies (EDOGs) with F24 μm/FR>2000 and F24 μm>1.3 mJy selected from a 6 deg2 region in the SWIRE fields. The application of our selection criteria to a wide area survey has been capable of unveiling a population of X-ray luminous, absorbed z>1 quasars which is mostly missed in the traditional optical/X-ray surveys performed so far. Advances in the understanding of the X-ray properties of these recently-discovered sources by Simbol-X observations will be also discussed.

An optical-near-IR study of a triplet of super star clusters in the starburst core of M82

Energy Technology Data Exchange (ETDEWEB)

Westmoquette, M. S. [European Southern Observatory, Karl-Schwarzschild-Str. 2, D-85748 Garching bei München (Germany); Bastian, N. [Excellence Cluster Universe, Boltzmannstrasse 2, D-85748 Garching bei München (Germany); Smith, L. J. [Space Telescope Science Institute and European Space Agency, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Seth, A. C. [University of Utah, Salt Lake City, UT 84112 (United States); Gallagher III, J. S.; Ryon, J. E. [Department of Astronomy, University of Wisconsin-Madison, 5534 Sterling, 475 North Charter Street, Madison, WI 53706 (United States); O' Connell, R. W. [Department of Astronomy, University of Virginia, P.O. Box 3818, Charlottesville, VA 22903 (United States); Silich, S.; Mayya, Y. D.; González, D. Rosa [Instituto Nacional de Astrofísica, Optica y Electronica, Luis Enrique Erro 1, Tonantzintla, C.P. 72840, Puebla (Mexico); Muñoz-Tuñón, C., E-mail: westmoquette@gmail.com [Instituto de Astrofísica de Canarias, C/vía Láctea s/n, E-38200 La Laguna, Tenerife (Spain)

2014-07-10

We present HST/STIS optical and Gemini/NIFS near-IR IFU spectroscopy and archival Hubble Space Telescope (HST) imaging of the triplet of super star clusters (A1, A2, and A3) in the core of the M82 starburst. Using model fits to the Space Telescope Imaging Spectrograph (STIS) spectra and the weakness of red supergiant CO absorption features (appearing at ∼6 Myr) in the NIFS H-band spectra, the ages of A2 and A3 are 4.5 ± 1.0 Myr. A1 has strong CO bands, consistent with our previously determined age of 6.4 ± 0.5 Myr. The photometric masses of the three clusters are 4-7 × 10{sup 5} M{sub ☉}, and their sizes are R{sub eff} = 159, 104, 59 mas (∼2.8, 1.8, 1.0 pc) for A1, A2, and A3. The STIS spectra yielded radial velocities of 320 ± 2, 330 ± 6, and 336 ± 5 km s{sup –1} for A1, A2, and A3, placing them at the eastern end of the x{sub 2} orbits of M82's bar. Clusters A2 and A3 are in high-density (800-1000 cm{sup –3}) environments, and like A1, are surrounded by compact H II regions. We suggest the winds from A2 and A3 have stalled, as in A1, due to the high ISM ambient pressure. We propose that the three clusters were formed in situ on the outer x{sub 2} orbits in regions of dense molecular gas subsequently ionized by the rapidly evolving starburst. The similar radial velocities of the three clusters and their small projected separation of ∼25 pc suggest that they may merge in the near future unless this is prevented by velocity shearing.

A System for Compressive Spectral and Polarization Imaging at Short Wave Infrared (SWIR) Wavelengths

Science.gov (United States)

2017-10-18

UV -­‐ VIS -­‐IR   60mm   Apo   Macro  lens   Jenoptik-­‐Inc   $5,817.36   IR... VIS /NIR Compressive Spectral Imager”, Proceedings of IEEE International Conference on Image Processing (ICIP ’15), Quebec City, Canada, (September...imaging   system   will   lead   to   a   wide-­‐band   VIS -­‐NIR-­‐SWIR   compressive  spectral  and  polarimetric

THE MID-INFRARED AND NEAR-ULTRAVIOLET EXCESS EMISSIONS OF QUIESCENT GALAXIES ON THE RED SEQUENCE

International Nuclear Information System (INIS)

Ko, Jongwan; Lee, Jong Chul; Hwang, Ho Seong; Sohn, Young-Jong

2013-01-01

We study the mid-infrared (IR) and near-ultraviolet (UV) excess emissions of spectroscopically selected quiescent galaxies on the optical red sequence. We use the Wide-field Infrared Survey Explorer mid-IR and Galaxy Evolution Explorer near-UV data for a spectroscopic sample of galaxies in the Sloan Digital Sky Survey Data Release 7 to study the possible connection between quiescent red-sequence galaxies with and without mid-IR/near-UV excess. Among 648 12 μm detected quiescent red-sequence galaxies without Hα emission, 26% and 55% show near-UV and mid-IR excess emissions, respectively. When we consider only bright (M r n 4000 than those without mid-IR and near-UV excess emissions. We also find that mid-IR weighted mean stellar ages of quiescent red-sequence galaxies with mid-IR excess are larger than those with near-UV excess, and smaller than those without mid-IR and near-UV excess. The environmental dependence of the fraction of quiescent red-sequence galaxies with mid-IR and near-UV excess seems strong even though the trends of quiescent red-sequence galaxies with near-UV excess differ from those with mid-IR excess. These results indicate that the recent star formation traced by near-UV (∼< 1 Gyr) and mid-IR (∼< 2 Gyr) excess is not negligible among nearby, quiescent, red, early-type galaxies. We suggest a possible evolutionary scenario of quiescent red-sequence galaxies from quiescent red-sequence galaxies with near-UV excess to those with mid-IR excess to those without near-UV and mid-IR excess.

Regional Spectral Model Workshop in memory of John Roads and Masao Kanamitsu

Science.gov (United States)

Hann-Ming Henry Juang; Shyh-Chin Chen; Songyou Hong; Hideki Kanamaru; Thomas Reichler; Takeshi Enomoto; Dian Putrasahan; Bruce T. Anderson; Sasha Gershunov; Haiqin Li; Kei Yoshimura; Nikolaus Buenning; Diane Boomer

2014-01-01

The committee for the 12th International Regional Spectral Model (RSM) Workshop drew its members from the National Centers for Environmental Prediction (NCEP), the U.S. Forest Service, Yonsei University, the Cooperative Institute for Climate and Satellites, the University of Tokyo, the Food and Agriculture Organization of the United Nations (FAO), Hokkaido University,...

Wolf-Rayet stars in the central region of the Milky Way

Science.gov (United States)

Hamann, Wolf-Rainer; Graefener, Goetz; Oskinova, Lidia; Zinnecker, Hans

2004-09-01

We propose to take mid-IR spectra of two Wolf-Rayet stars in the inner part of our Galaxy, within 30pc projected distance from the central Black Hole. Massive stars dominate the central galactic region by their mass-loss and ionizing radiation. A quantitative analysis of this stellar inventory is essential for understanding the energy, momentum and mass budget, for instance with respect to the feeding of the central black hole. Our group developed a highly advanced model code for the expanding atmospheres of WR stars. Recently we extended the spectrum synthesis to IR wavelengths. These models will be applied for the analysis of the Spitzer IRS data. The proposed mid-IR observations will provide a wide spectral range with many lines which are needed to determine the stellar parameters, such as stellar luminosity, effective temperature, mass-loss rate and chemical composition. Near-IR spectra of the program stars are available and will augment the analysis. The capability of our code to reproduce the observed mid-IR spectrum of a WN star has been demonstrated. The two targets we selected are sufficiently isolated, while the Galactic center cluster is too crowded for the size of Spitzer's spectrograph slit. As estimated from the K-band spectra, one of the stars (WR102ka) is of very late subtype (WN9), while the other star (WR102c) has the early subtype WN6. Hence they represent different stages in the evolutionary sequence of massive stars, the late-WN just having entered the Wolf-Rayet phase and the early WN being further evolved. We expect that the parameters of massive stars in the inner galaxy differ from the usual Galactic population. One reason is that higher metallicity should lead to stronger mass-loss, which affects the stellar evolution. The Spitzer IRS, with its high sensitivity, provides a unique opportunity to study representative members of the stellar population in the vicinity of the Galactic center.

THE SPECTRAL ENERGY DISTRIBUTIONS AND INFRARED LUMINOSITIES OF z ≈ 2 DUST-OBSCURED GALAXIES FROM Herschel AND Spitzer

International Nuclear Information System (INIS)

Melbourne, J.; Soifer, B. T.; Desai, Vandana; Armus, Lee; Pope, Alexandra; Alberts, Stacey; Dey, Arjun; Jannuzi, B. T.; Bussmann, R. S.

2012-01-01

Dust-obscured galaxies (DOGs) are a subset of high-redshift (z ≈ 2) optically-faint ultra-luminous infrared galaxies (ULIRGs, e.g., L IR > 10 12 L ☉ ). We present new far-infrared photometry, at 250, 350, and 500 μm (observed-frame), from the Herschel Space Telescope for a large sample of 113 DOGs with spectroscopically measured redshifts. Approximately 60% of the sample are detected in the far-IR. The Herschel photometry allows the first robust determinations of the total infrared luminosities of a large sample of DOGs, confirming their high IR luminosities, which range from 10 11.6 L ☉ IR (8-1000 μm) 13.6 L ☉ . 90% of the Herschel-detected DOGs in this sample are ULIRGs and 30% have L IR > 10 13 L ☉ . The rest-frame near-IR (1-3 μm) spectral energy distributions (SEDs) of the Herschel-detected DOGs are predictors of their SEDs at longer wavelengths. DOGs with 'power-law' SEDs in the rest-frame near-IR show observed-frame 250/24 μm flux density ratios similar to the QSO-like local ULIRG, Mrk 231. DOGs with a stellar 'bump' in their rest-frame near-IR show observed-frame 250/24 μm flux density ratios similar to local star-bursting ULIRGs like NGC 6240. None show 250/24 μm flux density ratios similar to extreme local ULIRG, Arp 220; though three show 350/24 μm flux density ratios similar to Arp 220. For the Herschel-detected DOGs, accurate estimates (within ∼25%) of total IR luminosity can be predicted from their rest-frame mid-IR data alone (e.g., from Spitzer observed-frame 24 μm luminosities). Herschel-detected DOGs tend to have a high ratio of infrared luminosity to rest-frame 8 μm luminosity (the IR8 = L IR (8-1000 μm)/νL ν (8 μm) parameter of Elbaz et al.). Instead of lying on the z = 1-2 'infrared main sequence' of star-forming galaxies (like typical LIRGs and ULIRGs at those epochs) the DOGs, especially large fractions of the bump sources, tend to lie in the starburst sequence. While, Herschel-detected DOGs are similar to scaled up

THE INFRARED TELESCOPE FACILITY (IRTF) SPECTRAL LIBRARY: COOL STARS

International Nuclear Information System (INIS)

Rayner, John T.; Cushing, Michael C.; Vacca, William D.

2009-01-01

We present a 0.8-5 μm spectral library of 210 cool stars observed at a resolving power of R ≡ λ/Δλ ∼ 2000 with the medium-resolution infrared spectrograph, SpeX, at the 3.0 m NASA Infrared Telescope Facility (IRTF) on Mauna Kea, Hawaii. The stars have well-established MK spectral classifications and are mostly restricted to near-solar metallicities. The sample not only contains the F, G, K, and M spectral types with luminosity classes between I and V, but also includes some AGB, carbon, and S stars. In contrast to some other spectral libraries, the continuum shape of the spectra is measured and preserved in the data reduction process. The spectra are absolutely flux calibrated using the Two Micron All Sky Survey photometry. Potential uses of the library include studying the physics of cool stars, classifying and studying embedded young clusters and optically obscured regions of the Galaxy, evolutionary population synthesis to study unresolved stellar populations in optically obscured regions of galaxies and synthetic photometry. The library is available in digital form from the IRTF Web site.

Compressibility of Ir-Os alloys under high pressure

International Nuclear Information System (INIS)

Yusenko, Kirill V.; Bykova, Elena; Bykov, Maxim; Gromilov, Sergey A.; Kurnosov, Alexander V.; Prescher, Clemens; Prakapenka, Vitali B.; Hanfland, Michael; Smaalen, Sander van; Margadonna, Serena; Dubrovinsky, Leonid S.

2015-01-01

Highlights: • fcc- and hcp-Ir-Os alloys were prepared from single-source precursors. • Their atomic volumes measured at ambient conditions using powder X-ray diffraction follow nearly linear dependence. • Compressibility of alloys have been studied up to 30 GPa at room temperature in diamond anvil cells. • Their bulk moduli increase with increasing osmium content. - Abstract: Several fcc- and hcp-structured Ir-Os alloys were prepared from single-source precursors in hydrogen atmosphere at 873 K. Their atomic volumes measured at ambient conditions using powder X-ray diffraction follow nearly linear dependence as a function of composition. Alloys have been studied up to 30 GPa at room temperature by means of synchrotron-based X-ray powder diffraction in diamond anvil cells. Their bulk moduli increase with increasing osmium content and show a deviation from linearity. Bulk modulus of hcp-Ir 0.20 Os 0.80 is identical to that of pure Os (411 GPa) within experimental errors. Peculiarities on fcc-Ir 0.80 Os 0.20 compressibility curve indicate possible changes of its electronic properties at ∼20 GPa

A Statistical study of the Doppler spectral width of high-latitude ionospheric F-region echoes recorded with SuperDARN coherent HF radars

Directory of Open Access Journals (Sweden)

J.-P. Villain

2002-11-01

Full Text Available The HF radars of the Super Dual Auroral Radar Network (SuperDARN provide measurements of the E × B drift of ionospheric plasma over extended regions of the high-latitude ionosphere. We have conducted a statistical study of the associated Doppler spectral width of ionospheric F-region echoes. The study has been conducted with all available radars from the Northern Hemisphere for 2 specific periods of time. Period 1 corresponds to the winter months of 1994, while period 2 covers October 1996 to March 1997. The distributions of data points and average spectral width are presented as a function of Magnetic Latitude and Magnetic Local Time. The databases are very consistent and exhibit the same features. The most stringent features are: a region of very high spectral width, collocated with the ionospheric LLBL/cusp/mantle region; an oval shaped region of high spectral width, whose equator-ward boundary matches the poleward limit of the Holzworth and Meng auroral oval. A simulation has been conducted to evaluate the geometrical and instrumental effects on the spectral width. It shows that these effects cannot account for the observed spectral features. It is then concluded that these specific spectral width characteristics are the signature of ionospheric/magnetospheric coupling phenomena.Key words. Ionosphere (auroral ionosphere; ionosphere-magnetosphere interactions; ionospheric irregularities

A Statistical study of the Doppler spectral width of high-latitude ionospheric F-region echoes recorded with SuperDARN coherent HF radars

Directory of Open Access Journals (Sweden)

J.-P. Villain

Full Text Available The HF radars of the Super Dual Auroral Radar Network (SuperDARN provide measurements of the E × B drift of ionospheric plasma over extended regions of the high-latitude ionosphere. We have conducted a statistical study of the associated Doppler spectral width of ionospheric F-region echoes. The study has been conducted with all available radars from the Northern Hemisphere for 2 specific periods of time. Period 1 corresponds to the winter months of 1994, while period 2 covers October 1996 to March 1997. The distributions of data points and average spectral width are presented as a function of Magnetic Latitude and Magnetic Local Time. The databases are very consistent and exhibit the same features. The most stringent features are: a region of very high spectral width, collocated with the ionospheric LLBL/cusp/mantle region; an oval shaped region of high spectral width, whose equator-ward boundary matches the poleward limit of the Holzworth and Meng auroral oval. A simulation has been conducted to evaluate the geometrical and instrumental effects on the spectral width. It shows that these effects cannot account for the observed spectral features. It is then concluded that these specific spectral width characteristics are the signature of ionospheric/magnetospheric coupling phenomena.

Key words. Ionosphere (auroral ionosphere; ionosphere-magnetosphere interactions; ionospheric irregularities

Drift and transmission FT-IR spectroscopy of forest soils: an approach to determine decomposition processes of forest litter

International Nuclear Information System (INIS)

Haberhauer, G.; Gerzabek, M.H.

1999-06-01

A method is described to characterize organic soil layers using Fourier transformed infrared spectroscopy. The applicability of FT-IR, either dispersive or transmission, to investigate decomposition processes of spruce litter in soil originating from three different forest sites in two climatic regions was studied. Spectral information of transmission and diffuse reflection FT-IR spectra was analyzed and compared. For data evaluation Kubelka Munk (KM) transformation was applied to the DRIFT spectra. Sample preparation for DRIFT is simpler and less time consuming in comparison to transmission FT-IR, which uses KBr pellets. A variety of bands characteristics of molecular structures and functional groups has been identified for these complex samples. Analysis of both transmission FT-IR and DRIFT, showed that the intensity of distinct bands is a measure of the decomposition of forest litter. Interferences due to water adsorption spectra were reduced by DRIFT measurement in comparison to transmission FT-IR spectroscopy. However, data analysis revealed that intensity changes of several bands of DRIFT and transmission FT-IR were significantly correlated with soil horizons. The application of regression models enables identification and differentiation of organic forest soil horizons and allows to determine the decomposition status of soil organic matter in distinct layers. On the basis of the data presented in this study, it may be concluded that FT-IR spectroscopy is a powerful tool for the investigation of decomposition dynamics in forest soils. (author)

Soil classification basing on the spectral characteristics of topsoil samples

Science.gov (United States)

Liu, Huanjun; Zhang, Xiaokang; Zhang, Xinle

2016-04-01

Soil taxonomy plays an important role in soil utility and management, but China has only course soil map created based on 1980s data. New technology, e.g. spectroscopy, could simplify soil classification. The study try to classify soils basing on the spectral characteristics of topsoil samples. 148 topsoil samples of typical soils, including Black soil, Chernozem, Blown soil and Meadow soil, were collected from Songnen plain, Northeast China, and the room spectral reflectance in the visible and near infrared region (400-2500 nm) were processed with weighted moving average, resampling technique, and continuum removal. Spectral indices were extracted from soil spectral characteristics, including the second absorption positions of spectral curve, the first absorption vale's area, and slope of spectral curve at 500-600 nm and 1340-1360 nm. Then K-means clustering and decision tree were used respectively to build soil classification model. The results indicated that 1) the second absorption positions of Black soil and Chernozem were located at 610 nm and 650 nm respectively; 2) the spectral curve of the meadow is similar to its adjacent soil, which could be due to soil erosion; 3) decision tree model showed higher classification accuracy, and accuracy of Black soil, Chernozem, Blown soil and Meadow are 100%, 88%, 97%, 50% respectively, and the accuracy of Blown soil could be increased to 100% by adding one more spectral index (the first two vole's area) to the model, which showed that the model could be used for soil classification and soil map in near future.

Engineering of near IR fluorescent albumin nanoparticles for in vivo detection of colon cancer

Directory of Open Access Journals (Sweden)

Cohen Sarit

2012-08-01

Full Text Available Abstract Background The use of near-infrared (NIR fluorescence imaging techniques has gained great interest for early detection of cancer because water and other intrinsic biomolecules display negligible absorption or autofluorescence in this region. Novel fluorescent nanoparticles with potential to improve neoplasm detection sensitivity may prove to be a valuable tool in early detection of colon tumors. Methods The present study describes the synthesis and use of NIR fluorescent albumin nanoparticles as a diagnostic tool for detection of colon cancer. These fluorescent nanoparticles were prepared by a precipitation process of human serum albumin (HSA in aqueous solution in the presence of a carboxylic acid derivative of the NIR dye IR-783 (CANIR. Tumor-targeting ligands such as peanut agglutinin (PNA, anti-carcinoembryonic antigen antibodies (anti-CEA and tumor associated glycoprotein-72 monoclonal antibodies (anti-TAG-72 were covalently conjugated to the albumin nanoparticles via the surface carboxylate groups by using the carbodiimide activation method. Results and discussion Leakage of the encapsulated dye into PBS containing 4% HSA or human bowel juice was not detected. This study also demonstrates that the encapsulation of the NIR fluorescent dye within the HSA nanoparticles reduces the photobleaching of the dye significantly. Specific colon tumor detection in a mouse model was demonstrated for PNA, anti-CEA and anti-TAG-72 conjugated NIR fluorescent HSA nanoparticles. These bioactive NIR fluorescent albumin nanoparticles also detected invisible tumors that were revealed as pathological only subsequent to histological analysis. Conclusions These results may suggest a significant advantage of NIR fluorescence imaging using NIR fluorescent nanoparticles over regular colonoscopy. In future work we plan to broaden this study by encapsulating cancer drugs, such as paclitaxel and doxorubicin, within these biodegradable NIR fluorescent HSA

Engineering of near IR fluorescent albumin nanoparticles for in vivo detection of colon cancer.

Science.gov (United States)

Cohen, Sarit; Margel, Shlomo

2012-08-14

The use of near-infrared (NIR) fluorescence imaging techniques has gained great interest for early detection of cancer because water and other intrinsic biomolecules display negligible absorption or autofluorescence in this region. Novel fluorescent nanoparticles with potential to improve neoplasm detection sensitivity may prove to be a valuable tool in early detection of colon tumors. The present study describes the synthesis and use of NIR fluorescent albumin nanoparticles as a diagnostic tool for detection of colon cancer. These fluorescent nanoparticles were prepared by a precipitation process of human serum albumin (HSA) in aqueous solution in the presence of a carboxylic acid derivative of the NIR dye IR-783 (CANIR). Tumor-targeting ligands such as peanut agglutinin (PNA), anti-carcinoembryonic antigen antibodies (anti-CEA) and tumor associated glycoprotein-72 monoclonal antibodies (anti-TAG-72) were covalently conjugated to the albumin nanoparticles via the surface carboxylate groups by using the carbodiimide activation method. Leakage of the encapsulated dye into PBS containing 4% HSA or human bowel juice was not detected. This study also demonstrates that the encapsulation of the NIR fluorescent dye within the HSA nanoparticles reduces the photobleaching of the dye significantly. Specific colon tumor detection in a mouse model was demonstrated for PNA, anti-CEA and anti-TAG-72 conjugated NIR fluorescent HSA nanoparticles. These bioactive NIR fluorescent albumin nanoparticles also detected invisible tumors that were revealed as pathological only subsequent to histological analysis. These results may suggest a significant advantage of NIR fluorescence imaging using NIR fluorescent nanoparticles over regular colonoscopy. In future work we plan to broaden this study by encapsulating cancer drugs, such as paclitaxel and doxorubicin, within these biodegradable NIR fluorescent HSA nanoparticles, in order to use them for both detection as well as therapy of colon

Study of the spectral and energy characteristics of lasing in the green spectral region by lithium fluoride with radiation color centers

Energy Technology Data Exchange (ETDEWEB)

Voitovich, A.P.; Kalinov, V.S.; Mikhnov, S.A.; Ovseichuk, S.I.

1987-06-01

The spectral and energy characteristics of lasers utilizing lithium fluoride with F2 and F3(+) color centers in transverse and longitudinal pumping schemes are studied. The feasibility of obtaining stable narrow-band radiation in the 510-570 nm range using a selective resonator is demonstrated. Consideration is given to the effect of lithium-fluoride crystal processing by excimer laser radiation at a wavelength of 308 nm on the spectroscopic and lasing characteristics of the F3(+) color center. After this processing, the laser efficiency in the green spectral region increases by more than a factor of two (reaching an efficiency of 14 percent). 7 references.

Measurement of the Shape of the Optical-IR Spectrum of Prompt Emission from Gamma-Ray Bursts

Science.gov (United States)

Grossan, Bruce; Kistaubayev, M.; Smoot, G.; Scherr, L.

2017-06-01

While the afterglow phase of gamma-ray bursts (GRBs) has been extensively measured, detections of prompt emission (i.e. during bright X-gamma emission) are more limited. Some prompt optical measurements are regularly made, but these are typically in a single wide band, with limited time resolution, and no measurement of spectral shape. Some models predict a synchrotron self-absorption spectral break somewhere in the IR-optical region. Measurement of the absorption frequency would give extensive information on each burst, including the electron Lorentz factor, the radius of emission, and more (Shen & Zhang 2008). Thus far the best prompt observations have been explained invoking a variety of models, but often with a non-unique interpretation. To understand this apparently heterogeneous behavior, and to reduce the number of possible models, it is critical to add data on the optical - IR spectral shape.Long GRB prompt X-gamma emission typically lasts ~40-80 s. The Swift BAT instrument rapidly measures GRB positions to within a few arc minutes and communicates them via the internet within a few seconds. We have measured the time for a fast-moving D=700 mm telescope to point and settle to be less than 9 s anywhere on the observable sky. Therefore, the majority of prompt optical-IR emission can be measured responding to BAT positions with this telescope. In this presentation, we describe our observing and science programs, and give our design for the Burst Simultaneous Three-channel Instrument (BSTI), which uses dichroics to send eparate bands to 3 cameras. Two EMCCD cameras, give high-time resolution in B and V; a third camera with a HgCdTe sensor covers H band, allowing us to study extinguished bursts. For a total exposure time of 10 s, we find a 5 sigma sensitivity of 21.3 and 20.3 mag in B and R for 1" seeing and Kitt Peak sky brightness, much fainter than typical previous prompt detections. We estimate 5 sigma H-band sensitivity for an IR optimized telescope to be

Far-IR measurements at Cerro Toco, Chile: FIRST, REFIR, and AERI

Science.gov (United States)

Cageao, Richard P.; Alford, J. Ashley; Johnson, David G.; Kratz, David P.; Mlynczak, Martin G.

2010-09-01

In mid-2009, the Radiative Heating in the Underexplored Bands Campaign II (RHUBC-II) was conducted from Cerro Toco, Chile, a high, dry, remote mountain plateau, 23°S , 67.8°W at 5.4km, in the Atacama Desert of Northern Chile. From this site, dominant IR water vapor absorption bands and continuum, saturated when viewed from the surface at lower altitudes, or in less dry locales, were investigated in detail, elucidating infrared (IR) absorption and emission in the atmosphere. Three Fourier Transform InfraRed (FTIR) instruments were at the site, the Far-Infrared Spectroscopy of the Troposphere (FIRST), the Radiation Explorer in the Far Infrared (REFIR), and the Atmospheric Emitted Radiance Interferometer (AERI). In a side-by-side comparison, these measured atmospheric downwelling radiation, with overlapping spectral coverage from 5 to 100μm (2000 to 100cm-1), and instrument spectral resolutions from 0.5 to 0.643cm-1, unapodized. In addition to the FTIR and other ground-based IR and microwave instrumentation, pressure/temperature/relative humidity measuring sondes, for atmospheric profiles to 18km, were launched from the site several times a day. The derived water vapor profiles, determined at times matching the FTIR measurement times, were used to model atmospheric radiative transfer. Comparison of instrument data, all at the same spectral resolution, and model calculations, are presented along with a technique for determining adjustments to line-by-line calculation continuum models. This was a major objective of the campaign.

From spectral holeburning memory to spatial-spectral microwave signal processing

International Nuclear Information System (INIS)

Babbitt, Wm Randall; Barber, Zeb W; Harrington, Calvin; Mohan, R Krishna; Sharpe, Tia; Bekker, Scott H; Chase, Michael D; Merkel, Kristian D; Stiffler, Colton R; Traxinger, Aaron S; Woidtke, Alex J

2014-01-01

Many storage and processing systems based on spectral holeburning have been proposed that access the broad bandwidth and high dynamic range of spatial-spectral materials, but only recently have practical systems been developed that exceed the performance and functional capabilities of electronic devices. This paper reviews the history of the proposed applications of spectral holeburning and spatial-spectral materials, from frequency domain optical memory to microwave photonic signal processing systems. The recent results of a 20 GHz bandwidth high performance spectrum monitoring system with the additional capability of broadband direction finding demonstrates the potential for spatial-spectral systems to be the practical choice for solving demanding signal processing problems in the near future. (paper)

[Cotton identification and extraction using near infrared sensor and object-oriented spectral segmentation technique].

Science.gov (United States)

Deng, Jin-Song; Shi, Yuan-Yuan; Chen, Li-Su; Wang, Ke; Zhu, Jin-Xia

2009-07-01

The real-time, effective and reliable method of identifying crop is the foundation of scientific management for crop in the precision agriculture. It is also one of the key techniques for the precision agriculture. However, this expectation cannot be fulfilled by the traditional pixel-based information extraction method with respect to complicated image processing and accurate objective identification. In the present study, visible-near infrared image of cotton was acquired using high-resolution sensor. Object-oriented segmentation technique was performed on the image to produce image objects and spatial/spectral features of cotton. Afterwards, nearest neighbor classifier integrated the spectral, shape and topologic information of image objects to precisely identify cotton according to various features. Finally, 300 random samples and an error matrix were applied to undertake the accuracy assessment of identification. Although errors and confusion exist, this method shows satisfying results with an overall accuracy of 96.33% and a KAPPA coefficient of 0.926 7, which can meet the demand of automatic management and decision-making in precision agriculture.

An Atomically Precise Au10 Ag2 Nanocluster with Red-Near-IR Dual Emission.

Science.gov (United States)

Lei, Zhen; Guan, Zong-Jie; Pei, Xiao-Li; Yuan, Shang-Fu; Wan, Xian-Kai; Zhang, Jin-Yuan; Wang, Quan-Ming

2016-08-01

A red-near-IR dual-emissive nanocluster with the composition [Au10 Ag2 (2-py-C≡C)3 (dppy)6 ](BF4 )5 (1; 2-py-C≡C is 2-pyridylethynyl, dppy=2-pyridyldiphenylphosphine) has been synthesized. Single-crystal X-ray structural analysis reveals that 1 has a trigonal bipyramidal Au10 Ag2 core that contains a planar Au4 (2-py-C≡C)3 unit sandwiched by two Au3 Ag(dppy)3 motifs. Cluster 1 shows intense red-NIR dual emission in solution. The visible emission originates from metal-to-ligand charge transfer (MLCT) from silver atoms to phosphine ligands in the Au3 Ag(dppy)3 motifs, and the intense NIR emission is associated with the participation of 2-pyridylethynyl in the frontier orbitals of the cluster, which is confirmed by a time-dependent density functional theory (TD-DFT) calculation. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

UV TO FAR-IR CATALOG OF A GALAXY SAMPLE IN NEARBY CLUSTERS: SPECTRAL ENERGY DISTRIBUTIONS AND ENVIRONMENTAL TRENDS

Energy Technology Data Exchange (ETDEWEB)

Hernandez-Fernandez, Jonathan D.; Iglesias-Paramo, J.; Vilchez, J. M., E-mail: jonatan@iaa.es [Instituto de Astrofisica de Andalucia, Glorieta de la Astronomia s/n, 18008 Granada (Spain)

2012-03-01

In this paper, we present a sample of cluster galaxies devoted to study the environmental influence on the star formation activity. This sample of galaxies inhabits in clusters showing a rich variety in their characteristics and have been observed by the SDSS-DR6 down to M{sub B} {approx} -18, and by the Galaxy Evolution Explorer AIS throughout sky regions corresponding to several megaparsecs. We assign the broadband and emission-line fluxes from ultraviolet to far-infrared to each galaxy performing an accurate spectral energy distribution for spectral fitting analysis. The clusters follow the general X-ray luminosity versus velocity dispersion trend of L{sub X} {proportional_to} {sigma}{sup 4.4}{sub c}. The analysis of the distributions of galaxy density counting up to the 5th nearest neighbor {Sigma}{sub 5} shows: (1) the virial regions and the cluster outskirts share a common range in the high density part of the distribution. This can be attributed to the presence of massive galaxy structures in the surroundings of virial regions. (2) The virial regions of massive clusters ({sigma}{sub c} > 550 km s{sup -1}) present a {Sigma}{sub 5} distribution statistically distinguishable ({approx}96%) from the corresponding distribution of low-mass clusters ({sigma}{sub c} < 550 km s{sup -1}). Both massive and low-mass clusters follow a similar density-radius trend, but the low-mass clusters avoid the high density extreme. We illustrate, with ABELL 1185, the environmental trends of galaxy populations. Maps of sky projected galaxy density show how low-luminosity star-forming galaxies appear distributed along more spread structures than their giant counterparts, whereas low-luminosity passive galaxies avoid the low-density environment. Giant passive and star-forming galaxies share rather similar sky regions with passive galaxies exhibiting more concentrated distributions.

Atmospheric-water absorption features near 2.2 micrometers and their importance in high spectral resolution remote sensing

Science.gov (United States)

Kruse, F. A.; Clark, R. N.

1986-01-01

Selective absorption of electromagnetic radiation by atmospheric gases and water vapor is an accepted fact in terrestrial remote sensing. Until recently, only a general knowledge of atmospheric effects was required for analysis of remote sensing data; however, with the advent of high spectral resolution imaging devices, detailed knowledge of atmospheric absorption bands has become increasingly important for accurate analysis. Detailed study of high spectral resolution aircraft data at the U.S. Geological Survey has disclosed narrow absorption features centered at approximately 2.17 and 2.20 micrometers not caused by surface mineralogy. Published atmospheric transmission spectra and atmospheric spectra derived using the LOWTRAN-5 computer model indicate that these absorption features are probably water vapor. Spectral modeling indicates that the effects of atmospheric absorption in this region are most pronounced in spectrally flat materials with only weak absorption bands. Without correction and detailed knowledge of the atmospheric effects, accurate mapping of surface mineralogy (particularly at low mineral concentrations) is not possible.

Temperature fluctuation spectral analysis of turbulent flow in circular sections with internal roughness

International Nuclear Information System (INIS)

Blanco, Rosa L.D.; Moeller, Sergio V.

1995-01-01

The experimental study of the temperature fluctuation in a circular section pipe with artificial roughness is presented. Micro thermocouples are applied for the measurements of the temperature and its fluctuations. Auto spectral density functions as well as autocorrelation functions were obtained by means of a Fourier Analyzer. Results compared to measurements performed in a smooth pipe, show that the turbulent scales for the temperature fluctuations increase in the regions near the walls, without significant changes in the regions near the center of the pipe. (author). 15 refs, 10 figs

Spectral Collection of Polyethylene Pellets at nearly Cryogenic Temperature to Improve Selectivity of Raman Measurement

International Nuclear Information System (INIS)

Kim, Saetbyeol; Lee, Sanguk; Hwang, Jinyoung; Chung, Hoeil

2010-01-01

Raman spectroscopy has been extensively used for analysis of diverse polymer samples. Normally, Raman spectral collection of samples is routinely performed at room temperature for convenience. However, the feasibility of improving spectral selectivity and the resulting quantitative accuracy, when samples are measured at nearly cryogenic temperature, has not been investigated. For this purpose, we attempted to measure the density of polyethylene (PE) pellets at cryogenic temperatures and the resulting accuracies were compared with that from room temperature measurement. Initially, each of 25 PE sample was allowed to cool down to cryogenic temperature and the corresponding Raman spectra were continuously collected while the temperature of sample increased. When the temperature of sample was at cryogenic temperature, the resulting band widths were narrower compared to those at room temperature, thereby improving the accuracy of density measurement. In overall, the proposed Raman scheme is simple and efficient; therefore, it could be further applied for analysis of other polymers.

NEOCAM: Near Earth Object Chemical Analysis Mission: Bridging the Gulf between Telescopic Observations and the Chemical and Mineralogical Compositions of Asteroids or Diogenes A: Diagnostic Observation of the Geology of Near Earth Spectrally-Classified Asteroids

Science.gov (United States)

Nuth, Joseph A.

2009-01-01

Studies of meteorites have yielded a wealth of scientific information based on highly detailed chemical and isotopic studies possible only in sophisticated terrestrial laboratories. Telescopic studies have revealed an enormous (greater than 10(exp 5)) number of physical objects ranging in size from a few tens of meters to several hundred kilometers, orbiting not only in the traditional asteroid belt between Mars and Jupiter but also throughout the inner solar system. Many of the largest asteroids are classed into taxonomic groups based on their observed spectral properties and are designated as C, D. X, S or V types (as well as a wide range in sub-types). These objects are certainly the sources far the meteorites in our laboratories, but which asteroids are the sources for which meteorites? Spectral classes are nominally correlated to the chemical composition and physical characteristics of the asteroid itself based on studies of the spectral changes induced in meteorites due to exposure to a simulated space environment. While laboratory studies have produced some notable successes (e.g. the identification of the asteroid Vesta as the source of the H, E and D meteorite classes), it is unlikely that we have samples of each asteroidal spectral type in our meteorite collection. The correlation of spectral type and composition for many objects will therefore remain uncertain until we can return samples of specific asteroid types to Earth for analyses. The best candidates for sample return are asteroids that already come close to the Earth. Asteroids in orbit near 1 A.U. have been classified into three groups (Aten, Apollo & Amor) based on their orbital characteristics. These Near Earth Objects (NEOs) contain representatives of virtually all spectral types and sub-types of the asteroid population identified to date. Because of their close proximity to Earth, NEOs are prime targets for asteroid missions such as the NEAR-Shoemaker NASA Discovery Mission to Eros and the

Imaging breast adipose and fibroglandular tissue molecular signatures by using hybrid MRI-guided near-infrared spectral tomography

Science.gov (United States)

Brooksby, Ben; Pogue, Brian W.; Jiang, Shudong; Dehghani, Hamid; Srinivasan, Subhadra; Kogel, Christine; Tosteson, Tor D.; Weaver, John; Poplack, Steven P.; Paulsen, Keith D.

2006-06-01

Magnetic resonance (MR)-guided near-infrared spectral tomography was developed and used to image adipose and fibroglandular breast tissue of 11 normal female subjects, recruited under an institutional review board-approved protocol. Images of hemoglobin, oxygen saturation, water fraction, and subcellular scattering were reconstructed and show that fibroglandular fractions of both blood and water are higher than in adipose tissue. Variation in adipose and fibroglandular tissue composition between individuals was not significantly different across the scattered and dense breast categories. Combined MR and near-infrared tomography provides fundamental molecular information about these tissue types with resolution governed by MR T1 images. hemoglobin | magnetic resonance imaging | water | fat | oxygen saturation

Identification of Serine Conformers by Matrix-Isolation IR Spectroscopy Aided by Near-Infrared Laser-Induced Conformational Change, 2D Correlation Analysis, and Quantum Mechanical Anharmonic Computations.

Science.gov (United States)

Najbauer, Eszter E; Bazsó, Gábor; Apóstolo, Rui; Fausto, Rui; Biczysko, Malgorzata; Barone, Vincenzo; Tarczay, György

2015-08-20

The conformers of α-serine were investigated by matrix-isolation IR spectroscopy combined with NIR laser irradiation. This method, aided by 2D correlation analysis, enabled unambiguously grouping the spectral lines to individual conformers. On the basis of comparison of at least nine experimentally observed vibrational transitions of each conformer with empirically scaled (SQM) and anharmonic (GVPT2) computed IR spectra, six conformers were identified. In addition, the presence of at least one more conformer in Ar matrix was proved, and a short-lived conformer with a half-life of (3.7 ± 0.5) × 10(3) s in N2 matrix was generated by NIR irradiation. The analysis of the NIR laser-induced conversions revealed that the excitation of the stretching overtone of both the side chain and the carboxylic OH groups can effectively promote conformational changes, but remarkably different paths were observed for the two kinds of excitations.

Monitoring combat wound healing by IR hyperspectral imaging

Science.gov (United States)

Howle, Chris R.; Spear, Abigail M.; Gazi, Ehsan; Crane, Nicole J.

2016-03-01

In recent conflicts, battlefield injuries consist largely of extensive soft injuries from blasts and high energy projectiles, including gunshot wounds. Repair of these large, traumatic wounds requires aggressive surgical treatment, including multiple surgical debridements to remove devitalised tissue and to reduce bacterial load. Identifying those patients with wound complications, such as infection and impaired healing, could greatly assist health care teams in providing the most appropriate and personalised care for combat casualties. Candidate technologies to enable this benefit include the fusion of imaging and optical spectroscopy to enable rapid identification of key markers. Hence, a novel system based on IR negative contrast imaging (NCI) is presented that employs an optical parametric oscillator (OPO) source comprising a periodically-poled LiNbO3 (PPLN) crystal. The crystal operates in the shortwave and midwave IR spectral regions (ca. 1.5 - 1.9 μm and 2.4 - 3.8 μm, respectively). Wavelength tuning is achieved by translating the crystal within the pump beam. System size and complexity are minimised by the use of single element detectors and the intracavity OPO design. Images are composed by raster scanning the monochromatic beam over the scene of interest; the reflection and/or absorption of the incident radiation by target materials and their surrounding environment provide a method for spatial location. Initial results using the NCI system to characterise wound biopsies are presented here.

Differentiation between probiotic and wild-type Bacillus cereus isolates by antibiotic susceptibility test and Fourier transform infrared spectroscopy (FT-IR).

Science.gov (United States)

Mietke, Henriette; Beer, W; Schleif, Julia; Schabert, G; Reissbrodt, R

2010-05-30

Animal feed often contains probiotic Bacillus strains used as feed additives. Spores of the non-pathogenic B. cereus var. toyoi (product name Toyocerin) are used. Distinguishing between toxic wild-type Bacillus cereus strains and this probiotic strain is essential for evaluating the quality and risk of feed. Bacillus cereus CIP 5832 (product name Paciflor was used as probiotic strain until 2001. The properties of the two probiotic strains are quite similar. Differentiating between probiotic strains and wild-type B. cereus strains is not easy. ss-lactam antibiotics such as penicillin and cefamandole exhibit an inhibition zone in the agar diffusion test of probiotic B. cereus strains which are not seen for wild-type strains. Therefore, performing the agar diffusion test first may make sense before FT-IR testing. When randomly checking these strains by Fourier transform infrared spectroscopy (FT-IR), the probiotic B. cereus strains were separated from wild-type B. cereus/B. thuringiensis/B. mycoides/B. weihenstephanensis strains by means of hierarchical cluster analysis. The discriminatory information was contained in the spectral windows 3000-2800 cm(-1) ("fatty acid region"), 1200-900 cm(-1) ("carbohydrate region") and 900-700 cm(-1) ("fingerprint region"). It is concluded that FT-IR spectroscopy can be used for the rapid quality control and risk analysis of animal feed containing probiotic B. cereus strains. (c) 2010 Elsevier B.V. All rights reserved.

Micro and Nano Electromechanical Systems for Near-Zero Power Infrared Detection

Science.gov (United States)

Qian, Zhenyun

Light is one of the most important tools for human beings to probe and sense the physical world. Infrared (IR) radiation located in longer wavelengths than those of visible light carries rich information of an environment as it reveals the temperature distribution and chemical composition of objects. In addition, it has been utilized for communication and distance measurement owing to the atmospheric window and insensitiveness of human eyes to the IR radiation. As a result, IR detectors nowadays can be found in a wide variety of applications, including thermal imaging, automotive night vision, standoff chemical detection, remote control and laser ranging, just to mention a few. On the other hand, due to the recent fast development of the Internet of Things (IoT), there is a growing demand for miniaturized and power efficient unattended sensors that can be widely distributed in large volumes to form a wireless sensor networks capable of monitoring the environment with high accuracy and long lifetime. In this context, micro and nano electromechanical systems (MEMS/NEMS) may provide a huge impact, since they can be used for the implementation of miniaturized, low power, high-performance sensors and wireless communication devices fully compatible with standard integrated circuitry. This dissertation presents the design and the experimental verification of high performance uncooled IR detectors based on Aluminum Nitride (AlN) nano electromechanical resonators, and a first-of-its-kind near-zero power IR digitizer based on plasmonically-enhanced micromechanical photoswitches. The unique advantages of the piezoelectric AlN thin film in terms of scaling in thickness and transduction efficiency are exploited by the first experimental demonstration of ultra-fast (thermal time constant, tau ˜ 80 mus) and high resolution (noise equivalent power, NEP ˜ 656 pW/Hz1/2) AlN NEMS resonant IR detectors with reduced pixel size comparable to the state-of-the-art microbolometers

Optical properties of graphene nanoribbons encapsulated in single-walled carbon nanotubes.

Science.gov (United States)

Chernov, Alexander I; Fedotov, Pavel V; Talyzin, Alexandr V; Suarez Lopez, Inma; Anoshkin, Ilya V; Nasibulin, Albert G; Kauppinen, Esko I; Obraztsova, Elena D

2013-07-23

We report the photoluminescence (PL) from graphene nanoribbons (GNRs) encapsulated in single-walled carbon nanotubes (SWCNTs). New PL spectral features originating from GNRs have been detected in the visible spectral range. PL peaks from GNRs have resonant character, and their positions depend on the ribbon geometrical structure in accordance with the theoretical predictions. GNRs were synthesized using confined polymerization and fusion of coronene molecules. GNR@SWCNTs material demonstrates a bright photoluminescence both in infrared (IR) and visible regions. The photoluminescence excitation mapping in the near-IR spectral range has revealed the geometry-dependent shifts of the SWCNT peaks (up to 11 meV in excitation and emission) after the process of polymerization of coronene molecules inside the nanotubes. This behavior has been attributed to the strain of SWCNTs induced by insertion of the coronene molecules.

Multichannel Dynamic Fourier-Transform IR Spectrometer

Science.gov (United States)

Balashov, A. A.; Vaguine, V. A.; Golyak, Il. S.; Morozov, A. N.; Khorokhorin, A. I.

2017-09-01

A design of a multichannel continuous scan Fourier-transform IR spectrometer for simultaneous recording and analysis of the spectral characteristics of several objects is proposed. For implementing the design, a multi-probe fiber is used, constructed from several optical fibers connected into a single optical connector and attached at the output of the interferometer. The Fourier-transform spectrometer is used as a signal modulator. Each fiber is individually mated with an investigated sample and a dedicated radiation detector. For the developed system, the radiation intensity of the spectrometer is calculated from the condition of the minimum spectral resolution and parameters of the optical fibers. Using the proposed design, emission spectra of a gas-discharge neon lamp have been recorded using a single fiber 1 mm in diameter with a numerical aperture NA = 0.22.

Generation of spectral clusters in a mixture of noble and Raman-active gases.

Science.gov (United States)

Hosseini, Pooria; Abdolvand, Amir; St J Russell, Philip

2016-12-01

We report a novel scheme for the generation of dense clusters of Raman sidebands. The scheme uses a broadband-guiding hollow-core photonic crystal fiber (HC-PCF) filled with a mixture of H2, D2, and Xe for efficient interaction between the gas mixture and a green laser pump pulse (532 nm, 1 ns) of only 5 μJ of energy. This results in the generation from noise of more than 135 rovibrational Raman sidebands covering the visible spectral region with an average spacing of only 2.2 THz. Such a spectrally dense and compact fiber-based source is ideal for applications where closely spaced narrow-band laser lines with high spectral power density are required, such as in spectroscopy and sensing. When the HC-PCF is filled with a H2-D2 mixture, the Raman comb spans the spectral region from the deep UV (280 nm) to the near infrared (1000 nm).

Spectral nudging in regional climate modelling: How strongly should we nudge?

OpenAIRE

Omrani , Hiba; Drobinski , Philippe; Dubos , Thomas

2012-01-01

International audience; Spectral nudging is a technique consisting in driving regional climate models (RCMs) on selected spatial scales corresponding to those produced by the driving global circulation model (GCM). This technique prevents large and unrealistic departures between the GCM driving fields and the RCM fields at the GCM spatial scales. Theoretically, the relaxation of the RCM towards the GCM should be infinitely strong provided thre are perfect large-scale fields. In practice, the ...

Near-nucleus optical observations of P/Halley

International Nuclear Information System (INIS)

Larson, S.M.

1987-01-01

The Near-Nucleus Studies Net of the International Halley Watch has obtained an extensive series of high resolution optical images of P/Halley during its most active phases in 1985-86 which may be useful in interpreting radio observations of Comet Halley. They often show coma structure resulting from anisotropic emission of dust and gas from the inhomogeneous nucleus. Images were obtained in broadband spectral regions to study dust coma morphology, and in medium to narrow spectral bands to isolate the principal emissions of CN, C 3 , C 2 , CO + and H 2 O + . The goals and methods of near-nucleus studies are discussed and recent studies of 1910 images are briefly reviewed. The role of dust jets and cometary activity in P/Halley is discussed and several examples of anisotropic emission of dust during the current apparition are shown. 12 references

Near-opposition martian limb-darkening: Quantification and implication for visible-near-infrared bidirectional reflectance studies.

Science.gov (United States)

de Grenier, Muriel; Pinet, Patrick C.

1995-06-01

A nearly global coverage of the martian eastern hemisphere, acquired under small phase angles and varying observational geometries conditions, has been produced from 1988 opposition by spectral (0.5-1 μm) imaging data obtained at the Pic du Midi Observatory in France. From this data set, the methodology presented here permits a systematic analysis of martian photometric behavior at a regional scale of 100-300 km in the visible and near-infrared. The quantification of limb-darkening as a function of wavelength and surface albedo gives access in martian regional properties as a function of wavelength and surface albedo and results in the production of visible and near-infrared geometric albedo maps. A linear relation between the limb darkening parameter k and geometric albedo exists in the near infrared. Based on laboratory studies, it suggests a spectral response of particulate type for the martian soil. Conversely, in the visible, the value of k parameter is 0.6 independent of albedo and is consistent with a single scattering photometric behavior in the surface layer. However, the observed change in the martian photometry from single to multiple scattering may be partially due to a large contribution of atmospheric scattering above 0.7 μm. In the absence of a multitemporal dataset analysis, it must be emphasized that the present results are a priori only pertinent to the atmospheric and surface conditions existing on Mars at the time of observation. However, this analysis may contribute to characterize some physical properties, such as surface roughness. In the near-infrared, for bright terrains, k tends to 0.8 and agrees with the presence of very fine particulate materials. Photometry of dark areas is more irregular (0.48 duricrust. Finally, we evaluate the influence of reflectance geometrical effects on the multispectral and spectroscopic data of the martian surface.

Impacts of using spectral nudging on regional climate model RCA4 simulations of the Arctic

Directory of Open Access Journals (Sweden)

P. Berg

2013-06-01

Full Text Available The performance of the Rossby Centre regional climate model RCA4 is investigated for the Arctic CORDEX (COordinated Regional climate Downscaling EXperiment region, with an emphasis on its suitability to be coupled to a regional ocean and sea ice model. Large biases in mean sea level pressure (MSLP are identified, with pronounced too-high pressure centred over the North Pole in summer of over 5 hPa, and too-low pressure in winter of a similar magnitude. These lead to biases in the surface winds, which will potentially lead to strong sea ice biases in a future coupled system. The large-scale circulation is believed to be the major reason for the biases, and an implementation of spectral nudging is applied to remedy the problems by constraining the large-scale components of the driving fields within the interior domain. It is found that the spectral nudging generally corrects for the MSLP and wind biases, while not significantly affecting other variables, such as surface radiative components, two-metre temperature and precipitation.

Analysis of Irradiation Holes of In-Core Region

Energy Technology Data Exchange (ETDEWEB)

In, Won-ho; Lee, Yong-sub; Kim, Tae-hwan; Lim, Kyoung-hwan; Ahn, Hyung-jin [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2015-05-15

Test fuels and materials are irradiated in the in-core region in side of the chimney. The inner chimney is composed of In-Core and Out-Core regions. The In-Core region has 23 hexagonal vertical irradiation holes named from R01 to R20, CT, IR1 and IR2 and 8 cylindrical irradiation holes named from CAR1 to CAR4 and SOR1 to SOR4. The Out-Core region is composed of 8 cylindrical irradiation holes named from OR1 to OR8 which are installed near the inner shell of the reflector tank. HANARO is the multi-purpose research reactor which utilizes in-core irradiation holes, which is being used in various field. Over the past 7 years we have used CT 8 times, IR once, IR2 and OR3 twice, OR4 three times and OR5 ten times. These irradiation holes are used to perform an evaluation of the neutron irradiation properties and the tests were all completed and done successfully. HANARO has been used successfully, and it still will be used continuously in various fields such as nuclear in-pile tests, the production of radioisotopes, neutron transmutation doping, neutron activation analysis, neutron beam research, radiography, environmental science.

Global Source Parameters from Regional Spectral Ratios for Yield Transportability Studies

Science.gov (United States)

Phillips, W. S.; Fisk, M. D.; Stead, R. J.; Begnaud, M. L.; Rowe, C. A.

2016-12-01

We use source parameters such as moment, corner frequency and high frequency rolloff as constraints in amplitude tomography, ensuring that spectra of well-studied earthquakes are recovered using the ensuing attenuation and site term model. We correct explosion data for path and site effects using such models, which allows us to test transportability of yield estimation techniques based on our best source spectral estimates. To develop a background set of source parameters, we applied spectral ratio techniques to envelopes of a global set of regional distance recordings from over 180,000 crustal events. Corner frequencies and moment ratios were determined via inversion using all event pairs within predetermined clusters, shifting to absolute levels using independently determined regional and teleseismic moments. The moment and corner frequency results can be expressed as stress drop, which has considerable scatter, yet shows dramatic regional patterns. We observe high stress in subduction zones along S. America, S. Mexico, the Banda Sea, and associated with the Yakutat Block in Alaska. We also observe high stress at the Himalayan syntaxes, the Pamirs, eastern Iran, the Caspian, the Altai-Sayan, and the central African rift. Low stress is observed along mid ocean spreading centers, the Afar rift, patches of convergence zones such as Nicaragua, the Zagros, Tibet, and the Tien Shan, among others. Mine blasts appear as low stress events due to their low corners and steep rolloffs. Many of these anomalies have been noted by previous studies, and we plan to compare results directly. As mentioned, these results will be used to constrain tomographic imaging, but can also be used in model validation procedures similar to the use of ground truth in location problems, and, perhaps most importantly, figure heavily in quality control of local and regional distance amplitude measurements.

High spectral resolution infrared observations of V1057 Cygni

International Nuclear Information System (INIS)

Hartmann, L.; Kenyon, S.J.

1987-01-01

High-resolution near-infrared spectra of V1057 Cygni obtained in 1986 with the KPNO 4-m Fourier transform spectrometer provide support for a previously proposed accretion disk model. The model predicts that the observed rotational broadening of spectral lines should be smaller in the infrared than in the optical. The present observations show that V1057 Cyg rotates more slowly at 2.3 microns than at 6000 A by an amount quantitatively consistent with the simple disk models. The absence of any radial velocity variations in either the infrared or optical spectral regions supports the suggestion that the accreted material arises from a remnant disk of protostellar material. 19 references

A spectral study of the elementary step of proton transfer in heterogeneous acid catalysis

Energy Technology Data Exchange (ETDEWEB)

Kazanskii, V B

1977-09-01

A spectral study of the elementary step of proton transfer in heterogeneous acid catalysis involved a determination of the potential curves of the OH bond in surface hydroxyl groups (e.g., those on silica, NaHY zeolite, or glass) of differing acidity from IR stretching frequency data in the overtone region; a calculation of the activation energies for proton transfer during acid catalysis from the changes in the curve forms after adsorption of various molecules (e.g., water, ammonia, benzene, toluene, xylenes, acetone, and cyclohexane); and a comparison of the IR predictions with quantum-chemical calculations of the potential curves. The results appear to furnish a new criterion for the coordinate of reactions involving Broensted sites: if the activation energy measured during actual catalysis is close to that calculated from the IR stretching data, the reaction proceeds by the stepwise mechanism of acid catalysis; but if these values differ greatly, the reaction involves a concerted mechanism (i.e., activation of the adsorbed molecule without involvement of OH groups). Tables, graphs, and 15 references.

Visualizing Infrared (IR) Spectroscopy with Computer Animation

Science.gov (United States)

Abrams, Charles B.; Fine, Leonard W.

1996-01-01

IR Tutor, an interactive, animated infrared (IR) spectroscopy tutorial has been developed for Macintosh and IBM-compatible computers. Using unique color animation, complicated vibrational modes can be introduced to beginning students. Rules governing the appearance of IR absorption bands become obvious because the vibrational modes can be visualized. Each peak in the IR spectrum is highlighted, and the animation of the corresponding normal mode can be shown. Students can study each spectrum stepwise, or click on any individual peak to see its assignment. Important regions of each spectrum can be expanded and spectra can be overlaid for comparison. An introduction to the theory of IR spectroscopy is included, making the program a complete instructional package. Our own success in using this software for teaching and research in both academic and industrial environments will be described. IR Tutor consists of three sections: (1) The 'Introduction' is a review of basic principles of spectroscopy. (2) 'Theory' begins with the classical model of a simple diatomic molecule and is expanded to include larger molecules by introducing normal modes and group frequencies. (3) 'Interpretation' is the heart of the tutorial. Thirteen IR spectra are analyzed in detail, covering the most important functional groups. This section features color animation of each normal mode, full interactivity, overlay of related spectra, and expansion of important regions. This section can also be used as a reference.

Pixelated coatings and advanced IR coatings

Science.gov (United States)

Pradal, Fabien; Portier, Benjamin; Oussalah, Meihdi; Leplan, Hervé

2017-09-01

Reosc developed pixelated infrared coatings on detector. Reosc manufactured thick pixelated multilayer stacks on IR-focal plane arrays for bi-spectral imaging systems, demonstrating high filter performance, low crosstalk, and no deterioration of the device sensitivities. More recently, a 5-pixel filter matrix was designed and fabricated. Recent developments in pixelated coatings, shows that high performance infrared filters can be coated directly on detector for multispectral imaging. Next generation space instrument can benefit from this technology to reduce their weight and consumptions.

Automated classification and visualization of healthy and pathological dental tissues based on near-infrared hyper-spectral imaging

Science.gov (United States)

Usenik, Peter; Bürmen, Miran; Vrtovec, Tomaž; Fidler, Aleš; Pernuš, Franjo; Likar, Boštjan

2011-03-01

Despite major improvements in dental healthcare and technology, dental caries remains one of the most prevalent chronic diseases of modern society. The initial stages of dental caries are characterized by demineralization of enamel crystals, commonly known as white spots which are difficult to diagnose. If detected early enough, such demineralization can be arrested and reversed by non-surgical means through well established dental treatments (fluoride therapy, anti-bacterial therapy, low intensity laser irradiation). Near-infrared (NIR) hyper-spectral imaging is a new promising technique for early detection of demineralization based on distinct spectral features of healthy and pathological dental tissues. In this study, we apply NIR hyper-spectral imaging to classify and visualize healthy and pathological dental tissues including enamel, dentin, calculus, dentin caries, enamel caries and demineralized areas. For this purpose, a standardized teeth database was constructed consisting of 12 extracted human teeth with different degrees of natural dental lesions imaged by NIR hyper-spectral system, X-ray and digital color camera. The color and X-ray images of teeth were presented to a clinical expert for localization and classification of the dental tissues, thereby obtaining the gold standard. Principal component analysis was used for multivariate local modeling of healthy and pathological dental tissues. Finally, the dental tissues were classified by employing multiple discriminant analysis. High agreement was observed between the resulting classification and the gold standard with the classification sensitivity and specificity exceeding 85 % and 97 %, respectively. This study demonstrates that NIR hyper-spectral imaging has considerable diagnostic potential for imaging hard dental tissues.

High-resolution mid-IR spectrometer based on frequency upconversion

DEFF Research Database (Denmark)

Hu, Qi; Dam, Jeppe Seidelin; Pedersen, Christian

2012-01-01

We demonstrate a novel approach for high-resolution spectroscopy based on frequency upconversion and postfiltering by means of a scanning Fabryx2013;Perot interferometer. The system is based on sum-frequency mixing, shifting the spectral content from the mid-infrared to the near-visible region al......-frequency 1064xA0;nm laser. We investigate water vapor emission lines from a butane burner and compare the measured results to model data. The presented method we suggest to be used for real-time monitoring of specific gas lines and reference signals....

Photometric and Spectral Study of the Saturnian Satellites

Science.gov (United States)

Newman, Sarah F.

2005-01-01

Photometric and spectra analysis of data from the Cassini Visual and Infrared Mapping Spectrometer (VIMS) has yielded intriguing findings regarding the surface properties of several of the icy Saturnian satellites. Spectral cubes were obtained of these satellites with a wavelength distribution in the IR far more extensive than from any previous observations. Disk-integrated solar phase curves were constructed in several key IR wavelengths that are indicative of key properties of the surface of the body, such as macroscopic roughness, fluffiness (or the porosity of the surface), global albedo and scattering properties of surface particles. Polynomial fits to these phase curves indicate a linear albedo trend of the curvature of the phase functions. Rotational phase functions from Enceladus were found to exhibit a double-peaked sinusoidal curve, which shows larger amplitudes for bands corresponding to water ice and a linear amplitude-albedo trend. These functions indicate regions on the surface of the satellite of more recent geologic activity. In addition, recent images of Enceladus show tectonic features and an absence of impact craters on Southern latitudes which could be indicative of a younger surface. Investigations into the properties of these features using VIMS are underway.

A near-infrared spectroscopic study of the starburst core of M82

International Nuclear Information System (INIS)

Lester, D.F.; Gaffney, N.; Carr, J.S.; Joy, M.

1990-01-01

Near-IR spectroscopy of the M82 starburst core is presented, including complete J, H, and K band spectra with a resolution of 0.0035-micron for the inner 60 pc of the galaxy. Also, spatial profiles along the starburst ridge are presented for Br-gamma, molecular hydrogen, and forbidden Fe II line fluxes. Emission from shocked molecular hydrogen is detected from the core of M82. The distribution of features across the starburst disk are mapped to study the relationships between spectral diagnostics. The observations are used to test the appropriateness of single-beam, aggregate models for studying the physical conditions in starbursts. 68 refs

A near-infrared spectroscopic study of the starburst core of M82

Science.gov (United States)

Lester, D. F.; Gaffney, N.; Carr, J. S.; Joy, M.

1990-01-01

Near-IR spectroscopy of the M82 starburst core is presented, including complete J, H, and K band spectra with a resolution of 0.0035-micron for the inner 60 pc of the galaxy. Also, spatial profiles along the starburst ridge are presented for Br-gamma, molecular hydrogen, and forbidden Fe II line fluxes. Emission from shocked molecular hydrogen is detected from the core of M82. The distribution of features across the starburst disk are mapped to study the relationships between spectral diagnostics. The observations are used to test the appropriateness of single-beam, aggregate models for studying the physical conditions in starbursts.

Identification of Serine Conformers by Matrix-Isolation IR Spectroscopy Aided by Near-Infrared Laser Induced Conformational Change, 2D Correlation Analysis, and Quantum Mechanical Anharmonic Computations

Science.gov (United States)

Najbauer, Eszter E.; Bazsó, Gábor; Apóstolo, Rui; Fausto, Rui; Biczysko, Malgorzata; Barone, Vincenzo; Tarczay, György

2018-01-01

The conformers of α-serine were investigated by matrix-isolation IR spectroscopy combined with NIR laser irradiation. This method, aided by 2D correlation analysis, enabled unambiguously grouping the spectral lines to individual conformers. On the basis of comparison of at least nine experimentally observed vibrational transitions of each conformer with empirically scaled (SQM) and anharmonic (GVPT2) computed IR spectra, 6 conformers were identified. In addition, the presence of at least one more conformer in Ar matrix was proved, and a short-lived conformer with a half-live of (3.7±0.5)·103 s in N2 matrix was generated by NIR irradiation. The analysis of the NIR laser induced conversions revealed that the excitation of the stretching overtone of both the side-chain and the carboxylic OH groups can effectively promote conformational changes, but remarkably different paths were observed for the two kinds of excitations. PMID:26201050

Breath Analysis Using Laser Spectroscopic Techniques: Breath Biomarkers, Spectral Fingerprints, and Detection Limits

Directory of Open Access Journals (Sweden)

Peeyush Sahay

2009-10-01

Full Text Available Breath analysis, a promising new field of medicine and medical instrumentation, potentially offers noninvasive, real-time, and point-of-care (POC disease diagnostics and metabolic status monitoring. Numerous breath biomarkers have been detected and quantified so far by using the GC-MS technique. Recent advances in laser spectroscopic techniques and laser sources have driven breath analysis to new heights, moving from laboratory research to commercial reality. Laser spectroscopic detection techniques not only have high-sensitivity and high-selectivity, as equivalently offered by the MS-based techniques, but also have the advantageous features of near real-time response, low instrument costs, and POC function. Of the approximately 35 established breath biomarkers, such as acetone, ammonia, carbon dioxide, ethane, methane, and nitric oxide, 14 species in exhaled human breath have been analyzed by high-sensitivity laser spectroscopic techniques, namely, tunable diode laser absorption spectroscopy (TDLAS, cavity ringdown spectroscopy (CRDS, integrated cavity output spectroscopy (ICOS, cavity enhanced absorption spectroscopy (CEAS, cavity leak-out spectroscopy (CALOS, photoacoustic spectroscopy (PAS, quartz-enhanced photoacoustic spectroscopy (QEPAS, and optical frequency comb cavity-enhanced absorption spectroscopy (OFC-CEAS. Spectral fingerprints of the measured biomarkers span from the UV to the mid-IR spectral regions and the detection limits achieved by the laser techniques range from parts per million to parts per billion levels. Sensors using the laser spectroscopic techniques for a few breath biomarkers, e.g., carbon dioxide, nitric oxide, etc. are commercially available. This review presents an update on the latest developments in laser-based breath analysis.

Toward an Empirically-based Parametric Explosion Spectral Model

Science.gov (United States)

Ford, S. R.; Walter, W. R.; Ruppert, S.; Matzel, E.; Hauk, T. F.; Gok, R.

2010-12-01

Small underground nuclear explosions need to be confidently detected, identified, and characterized in regions of the world where they have never occurred. We develop a parametric model of the nuclear explosion seismic source spectrum derived from regional phases (Pn, Pg, and Lg) that is compatible with earthquake-based geometrical spreading and attenuation. Earthquake spectra are fit with a generalized version of the Brune spectrum, which is a three-parameter model that describes the long-period level, corner-frequency, and spectral slope at high-frequencies. These parameters are then correlated with near-source geology and containment conditions. There is a correlation of high gas-porosity (low strength) with increased spectral slope. However, there are trade-offs between the slope and corner-frequency, which we try to independently constrain using Mueller-Murphy relations and coda-ratio techniques. The relationship between the parametric equation and the geologic and containment conditions will assist in our physical understanding of the nuclear explosion source, and aid in the prediction of observed local and regional distance seismic amplitudes for event identification and yield determination in regions with incomplete or no prior history of underground nuclear testing.

Measurements and estimation of the columnar optical depth of tropospheric aerosols in the UV spectral region

Directory of Open Access Journals (Sweden)

V. E. Cachorro

2002-04-01

Full Text Available We report values of the columnar tropospheric aerosol optical depth at UV wavelengths based on experimental measurements of the direct spectral irradiances carried out by a commercial spectroradiometer (Li1800 of Licor company covering the range from 300–1100 nm at two stations with different climate characteristics in Spain. The first station is located in a rural site in north central Spain with continental climate. The data extend from March to the end of October of 1995. The other station is a coastal site in the Gulf of Cádiz (southwest Spain of maritime climate type. This study is mainly focused on the capability of estimating aerosol optical depth values in the UV region based on the extracted information in the visible and near infrared ranges. A first method has been used based on the Ångström turbidity parameters. However, since this method requires detailed spectral information, a second method has also been used, based on the correlation between wavelengths. A correlation has been established between the experimental aerosol optical depth values at 350 nm and 500 nm wavelengths. Although the type of aerosol seems to be the key factor that determines the quality of these estimations, the evaluation of the associated error is necessary to know the behaviour of these estimations in each area of study.Key words. Atmospheric composition and structure (aerosols and particles; transmission and scattering of radiation; troposphere – composition and chemistry

Measurements and estimation of the columnar optical depth of tropospheric aerosols in the UV spectral region

Directory of Open Access Journals (Sweden)

V. E. Cachorro

Full Text Available We report values of the columnar tropospheric aerosol optical depth at UV wavelengths based on experimental measurements of the direct spectral irradiances carried out by a commercial spectroradiometer (Li1800 of Licor company covering the range from 300–1100 nm at two stations with different climate characteristics in Spain. The first station is located in a rural site in north central Spain with continental climate. The data extend from March to the end of October of 1995. The other station is a coastal site in the Gulf of Cádiz (southwest Spain of maritime climate type. This study is mainly focused on the capability of estimating aerosol optical depth values in the UV region based on the extracted information in the visible and near infrared ranges. A first method has been used based on the Ångström turbidity parameters. However, since this method requires detailed spectral information, a second method has also been used, based on the correlation between wavelengths. A correlation has been established between the experimental aerosol optical depth values at 350 nm and 500 nm wavelengths. Although the type of aerosol seems to be the key factor that determines the quality of these estimations, the evaluation of the associated error is necessary to know the behaviour of these estimations in each area of study.

Key words. Atmospheric composition and structure (aerosols and particles; transmission and scattering of radiation; troposphere – composition and chemistry

NEAR-IR TWO PHOTON MICROSCOPY IMAGING OF SILICA NANOPARTICLES FUNCTIONALIZED WITH ISOLATED SENSITIZED Yb(III) CENTERS

Energy Technology Data Exchange (ETDEWEB)

Lapadula, Giuseppe; Bourdolle, Adrien; Allouche, Florian; Conley, Matthew P.; Maron, Laurent; Lukens, Wayne W.; Guyot, Yannick; Andraud, Chantal; Brasselet, Sophie; Copé; ret, Christophe; Maury, Olivier; Andersen, Richard A.

2013-01-12

Bright nano objects emitting in the near infrared with a maximal cross section of 41.4 x 103 GM (Goppert Mayer), were prepared by implanting ca. 180 4,4 diethylaminostyryl 2,2 bipyridine (DEAS) Yb(III) complexes on the surface of 12 nm silica nanoparticles. The surface complexes ([DEAS Ln SiO2], Ln =Y,Yb) were characterized using IR, solid state NMR, UV Vis, EXAFS spectroscopies in combination with the preparation and characterization of similar molecular analogues by analytical techniques (IR, solution NMR, UV Vis, X ray crystallography) as well as DFT calculations. Starting from the partial dehydroxylation of the silica at 700 C on high vacuum having 0.8 OH.nm 2, the grafting of Ln(N(SiMe3)2)3 generate ≤SiO Ln(N(SiMe3)2)2, which upon thermal step and coordination of the DEAS chromophore yields (≤SiO)3Ln(DEAS). Surface and molecular analogues display similar properties, in terms of DEAS binding constants absorption maxima and luminescence properties (intense emission band assigned to a ligand centered CT fluorescence and life time) in the solid state, consistent with the molecular nature of the surface species. The densely functionalized nanoparticles can be dispersed via ultra-sonication in small ca. 15-20 nm aggregates (1 to 6 elementary particles) that were detected using two photon microscopy imaging at 720 nm excitation, making them promising nano objects for bio imaging.

Luminosity and Redshift dependence of quasar spectral properties

Energy Technology Data Exchange (ETDEWEB)

Daniel E. Vanden Berk et al.

2004-03-09

Using a large sample of quasar spectra from the SDSS, we examine the composite spectral trends of quasars as functions of both redshift and luminosity, independently of one another. Aside from the well known Baldwin effect (BE)--the decrease of line equivalent width with luminosity--the average spectral properties are remarkably similar. Host galaxy contamination and the BE are the primary causes for apparent changes in the average spectral slope of the quasars. The BE is detected for most emission lines, including the Balmer lines, but with several exceptions including NV1240A. Emission line shifts of several lines are associated with the BE. The BE is mainly a function of luminosity, but also partly a function of redshift in that line equivalent widths become stronger with redshift. Some of the complex iron features change with redshift, particularly near the small blue bump region.

Quantitative infrared and near-infrared gas-phase spectra for pyridine: Absolute intensities and vibrational assignments

Energy Technology Data Exchange (ETDEWEB)

Johnson, T. J.; Aker, P. M.; Scharko, N. K.; Williams, S. D.

2018-02-01

Using vetted methods for generating quantitative absorption reference data, broadband infrared and near-infrared spectra (total range 11,000 – 600 cm-1) of pyridine vapor were recorded at 0.1 cm-1 spectral resolution, with the analyte thermostatted at 298 K and pressure-broadened to 1 atmosphere using N2 ballast gas. The quantitative spectrum is reported for the first time, and we have re-assigned some of the 27 fundamental modes. Fundamental assignments were confirmed by IR vapor phase band shapes, FT-Raman measurements and comparison with previous analyses. For the 760-Torr vapor-phase IR data several bands show resolved peaks (Q-branches). We have also assigned for the first time hundreds of combination and overtone bands in the mid- and near-IR. All assignments were made via comparison to theoretically calculated frequencies and intensities: The frequencies were computed with Gaussian03 with the anharmonic option, using MP2 and the ccpvtz basis set. The intensities were taken from a VSCF calculation in GAMESS using Hartree-Fock (for overtones and combination bands) or from the harmonic MP2 for fundamentals. Overtone and combination band harmonic and anharmonic frequencies, as well as intensities were also calculated using the CFOUR program. It is seen in the NIR spectrum near 6000 cm-1 that the very strong bands arise from the C-H first overtones, whereas only much weaker bands are observed for combination bands of C-H stretching modes. Certain features are discussed for their potential utility for atmospheric monitoring.

Ground based mid-IR heterodyne spectrometer concept for planetary atmospheres observations

Science.gov (United States)

Garamov, V.; Benderov, O.; Semenov, V.; Spiridonov, M.; Rodin, A.; Stepanov, B.

2017-09-01

We present a heterodyne spectrometer concept based on distributed feedback (DFB) quantum cascade lasers (QCL) operated in midle infrared region (MIR). The instrument is assumed to be mount on the Russian infrared observatories. The core features of the concept are compact design, utilizing a novel mid-IR fiber optical components and dynamic local oscillator frequency locking using reference molecule absorption line. The instrument characteristics are similar to modern heterodyne devices THIS (Cologne University, Germany) and MILAHI (Tohoku University, Japan) in terms of fundamental parameters, including spectral resolution, spectral coverage in a single observation. At present moment we created laboratory setup including all necessary elements of MIR heterodyne spectrometer. We have studied different components of noises of our system and found optimal value of LO power. The measured signal to noise ratio (SNR) with MCT PD was about 10 times greater than LO's shot noise (theoretical limit of heterodyne technique SNR) and limited by QCL relative intensity noise (RIN). However, applying additional filtering it is possible to reduce this value better than 5 shot noise level, which is typical to TEC cooled MCT PD. Also we demonstrate heterodyne signal measurements using laboratory black body with temperature of 400 oC.

Physical Characterization of Warm Spitzer-observed Near-Earth Objects

Science.gov (United States)

Thomas, Cristina A.; Emery, Joshua P.; Trilling, David E.; Delbo, Marco; Hora, Joseph L.; Mueller, Michael

2014-01-01

Near-infrared spectroscopy of Near-Earth Objects (NEOs) connects diagnostic spectral features to specific surface mineralogies. The combination of spectroscopy with albedos and diameters derived from thermal infrared observations can increase the scientific return beyond that of the individual datasets. For instance, some taxonomic classes can be separated into distinct compositional groupings with albedo and different mineralogies with similar albedos can be distinguished with spectroscopy. To that end, we have completed a spectroscopic observing campaign to complement the ExploreNEOs Warm Spitzer program that obtained albedos and diameters of nearly 600 NEOs (Trilling et al., 2010). The spectroscopy campaign included visible and near-infrared observations of ExploreNEOs targets from various observatories. Here we present the results of observations using the low-resolution prism mode (approx. 0.7-2.5 microns) of the SpeX instrument on the NASA Infrared Telescope Facility (IRTF). We also include near-infrared observations of Explore-NEOs targets from the MIT-UH-IRTF Joint Campaign for Spectral Reconnaissance. Our dataset includes near-infrared spectra of 187 ExploreNEOs targets (125 observations of 92 objects from our survey and 213 observations of 154 objects from the MIT survey). We identify a taxonomic class for each spectrum and use band parameter analysis to investigate the mineralogies for the S-, Q-, and V-complex objects. Our analysis suggests that for spectra that contain near-infrared data but lack the visible wavelength region, the Bus-DeMeo system misidentifies some S-types as Q-types. We find no correlation between spectral band parameters and ExploreNEOs albedos and diameters. We investigate the correlations of phase angle with band area ratio and near-infrared spectral slope. We find slightly negative Band Area Ratio (BAR) correlations with phase angle for Eros and Ivar, but a positive BAR correlation with phase angle for Ganymed.The results of our

Performance analysis of near-field thermophotovoltaic devices considering absorption distribution

International Nuclear Information System (INIS)

Park, K.; Basu, S.; King, W.P.; Zhang, Z.M.

2008-01-01

This paper elucidates the energy transfer and conversion processes in near-field thermophotovoltaic (TPV) systems, considering local radiation absorption and photocurrent generation in the TPV cell. Radiation heat transfer in a multilayered structure is modeled using the fluctuation-dissipation theorem, and the electric current generation is evaluated based on the photogeneration and recombination of electron-hole pairs in different regions of the TPV cell. The effects of near-field radiation on the photon penetration depth, photocurrent generation, and quantum efficiency are examined in the spectral region of interest. The detailed analysis performed in the present work demonstrates that, while the near-field operation can enhance the power throughput, the conversion efficiency is not much improved and may even be reduced. Subsequently, a modified design of near-field TPV systems is proposed to improve the efficiency

Tunable dye laser research at U. N. E

Energy Technology Data Exchange (ETDEWEB)

Haydon, S C

1976-10-01

Attempts to extend present tunable radiation sources into the wavelength region from 140 to 330 nm are presented in the following areas: frequency doubling and parametric upconversion methods, frequency mixing techniques in metal vapors, the pulsed N/sub 2/ laser, tunable dye lasers for the near uv to ir spectral range, heat pipe ovens, and preliminary experiments. (MHR)

The spectral changes of deforestation in the Brazilian tropical savanna.

Science.gov (United States)

Trancoso, Ralph; Sano, Edson E; Meneses, Paulo R

2015-01-01

The Cerrado is a biome in Brazil that is experiencing the most rapid loss in natural vegetation. The objective of this study was to analyze the changes in the spectral response in the red, near infrared (NIR), middle infrared (MIR), and normalized difference vegetation index (NDVI) when native vegetation in the Cerrado is deforested. The test sites were regions of the Cerrado located in the states of Bahia, Minas Gerais, and Mato Grosso. For each region, a pair of Landsat Thematic Mapper (TM) scenes from 2008 (before deforestation) and 2009 (after deforestation) was compared. A set of 1,380 samples of deforested polygons and an equal number of samples of native vegetation have their spectral properties statistically analyzed. The accuracy of deforestation detections was also evaluated using high spatial resolution imagery. Results showed that the spectral data of deforested areas and their corresponding native vegetation were statistically different. The red band showed the highest difference between the reflectance data from deforested areas and native vegetation, while the NIR band showed the lowest difference. A consistent pattern of spectral change when native vegetation in the Cerrado is deforested was identified regardless of the location in the biome. The overall accuracy of deforestation detections was 97.75%. Considering both the marked pattern of spectral changes and the high deforestation detection accuracy, this study suggests that deforestation in Cerrado can be accurately monitored, but a strong seasonal and spatial variability of spectral changes might be expected.

Visible/near-infrared spectral diversity from in situ observations of the Bagnold Dune Field sands in Gale Crater, Mars

Science.gov (United States)

Johnson, Jeffrey R.; Achilles, Cherie; Bell, James F.; Bender, Steve; Cloutis, Edward; Ehlmann, Bethany; Fraeman, Abigail; Gasnault, Olivier; Hamilton, Victoria E.; Le Mouélic, Stéphane; Maurice, Sylvestre; Pinet, Patrick; Thompson, Lucy; Wellington, Danika; Wiens, Roger C.

2017-12-01

As part of the Bagnold Dune campaign conducted by Mars Science Laboratory rover Curiosity, visible/near-infrared reflectance spectra of dune sands were acquired using Mast Camera (Mastcam) multispectral imaging (445-1013 nm) and Chemistry and Camera (ChemCam) passive point spectroscopy (400-840 nm). By comparing spectra from pristine and rover-disturbed ripple crests and troughs within the dune field, and through analysis of sieved grain size fractions, constraints on mineral segregation from grain sorting could be determined. In general, the dune areas exhibited low relative reflectance, a weak 530 nm absorption band, an absorption band near 620 nm, and a spectral downturn after 685 nm consistent with olivine-bearing sands. The finest grain size fractions occurred within ripple troughs and in the subsurface and typically exhibited the strongest 530 nm bands, highest relative reflectances, and weakest red/near-infrared ratios, consistent with a combination of crystalline and amorphous ferric materials. Coarser-grained samples were the darkest and bluest and exhibited weaker 530 nm bands, lower relative reflectances, and stronger downturns in the near-infrared, consistent with greater proportions of mafic minerals such as olivine and pyroxene. These grains were typically segregated along ripple crests and among the upper surfaces of grain flows in disturbed sands. Sieved dune sands exhibited progressive decreases in reflectance with increasing grain size, as observed in laboratory spectra of olivine size separates. The continuum of spectral features observed between the coarse- and fine-grained dune sands suggests that mafic grains, ferric materials, and air fall dust mix in variable proportions depending on aeolian activity and grain sorting.

MIRIS observation of near-infrared diffuse Galactic light

Science.gov (United States)

Onishi, Yosuke; Sano, Kei; Matsuura, Shuji; Jeong, Woong-Seob; Pyo, Jeonghyun; Kim, Il-Jong; Seo, Hyun Jong; Han, Wonyong; Lee, DaeHee; Moon, Bongkon; Park, Wonkee; Park, Younsik; Kim, MinGyu; Matsumoto, Toshio; Matsuhara, Hideo; Nakagawa, Takao; Tsumura, Kohji; Shirahata, Mai; Arai, Toshiaki; Ienaka, Nobuyuki

2018-06-01

We report near-infrared (IR) observations of high Galactic latitude clouds to investigate diffuse Galactic light (DGL), which is starlight scattered by interstellar dust grains. The observations were performed at 1.1 and 1.6 μm with a wide-field camera instrument, the Multi-purpose Infra-Red Imaging System (MIRIS) onboard the Korean satellite STSAT-3. The DGL brightness is measured by correlating the near-IR images with a far-IR 100 μm map of interstellar dust thermal emission. The wide-field observation of DGL provides the most accurate DGL measurement achieved to-date. We also find a linear correlation between optical and near-IR DGL in the MBM32 field. To study interstellar dust properties in MBM32, we adopt recent dust models with and without μm-sized very large grains and predict the DGL spectra, taking into account the reddening effect of the interstellar radiation field. The result shows that the observed color of the near-IR DGL is closer to the model spectra without very large grains. This may imply that dust growth in the observed MBM32 field is not active owing to the low density of its interstellar medium.

Crystal growth and characterization of Ir-Te compounds

Energy Technology Data Exchange (ETDEWEB)

Kurzhals, Philipp; Weber, Frank; Zocco, Diego; Adelmann, Peter; Merz, Michael; Wolf, Thomas; Kuntz, Sebastian; Grube, Kai [Karlsruhe Institute of Technology, Institute for Solid State Physics, Karlsruhe (Germany)

2016-07-01

IrTe{sub 2} is distinguished by a structural phase transition whose origin is not understood up to the present day. We grew crystals using the self-flux method starting from the reagents iridium and tellurium and got specimen with varying amounts of IrTe{sub 2} and Ir{sub 3}Te{sub 8}, analyzed by x-ray powder diffraction. We studied the transition near T = 280 K in magnetization measurements down to T = 1.8 K probing also for superconductivity, which was reported for intercalated samples. Results indicate that the structural transition happens over an extended range in temperature and superconductivity is absent in our samples. Ir{sub 3}Te{sub 8} is not studied to such an extent as IrTe{sub 2}. In previous publications a structural phase transition is reported. We characterized the transition by performing magnetization measurements and X-ray diffraction.

Multiple Scattering Principal Component-based Radiative Transfer Model (PCRTM) from Far IR to UV-Vis

Science.gov (United States)

Liu, X.; Wu, W.; Yang, Q.

2017-12-01

Modern satellite hyperspectral satellite remote sensors such as AIRS, CrIS, IASI, CLARREO all require accurate and fast radiative transfer models that can deal with multiple scattering of clouds and aerosols to explore the information contents. However, performing full radiative transfer calculations using multiple stream methods such as discrete ordinate (DISORT), doubling and adding (AD), successive order of scattering order of scattering (SOS) are very time consuming. We have developed a principal component-based radiative transfer model (PCRTM) to reduce the computational burden by orders of magnitudes while maintain high accuracy. By exploring spectral correlations, the PCRTM reduce the number of radiative transfer calculations in frequency domain. It further uses a hybrid stream method to decrease the number of calls to the computational expensive multiple scattering calculations with high stream numbers. Other fast parameterizations have been used in the infrared spectral region reduce the computational time to milliseconds for an AIRS forward simulation (2378 spectral channels). The PCRTM has been development to cover spectral range from far IR to UV-Vis. The PCRTM model have been be used for satellite data inversions, proxy data generation, inter-satellite calibrations, spectral fingerprinting, and climate OSSE. We will show examples of applying the PCRTM to single field of view cloudy retrievals of atmospheric temperature, moisture, traces gases, clouds, and surface parameters. We will also show how the PCRTM are used for the NASA CLARREO project.

Change detection by the IR-MAD and kernel MAF methods in Landsat TM data covering a Swedish forest region

DEFF Research Database (Denmark)

Nielsen, Allan Aasbjerg; Olsson, Håkan

2010-01-01

Change over time between two 512 by 512 (25 m by 25 m pixels) multispectral Landsat Thematic Mapper images dated 6 June 1986 and 27 June 1988 respectively covering a forested region in northern Sweden, is here detected by means of the iteratively reweighted multivariate alteration detection (IR-M...

A Q-switched Ho:YAG laser assisted nanosecond time-resolved T-jump transient mid-IR absorbance spectroscopy with high sensitivity

Energy Technology Data Exchange (ETDEWEB)

Li, Deyong; Li, Yunliang; Li, Hao; Weng, Yuxiang, E-mail: yxweng@iphy.ac.cn [Key Laboratory of Soft Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Wu, Xianyou [Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031 (China); Yu, Qingxu [School of Physics and Optoelectronic Technology, Dalian University of Technology, No. 2, Linggong Road, Dalian 116023 (China)

2015-05-15

Knowledge of dynamical structure of protein is an important clue to understand its biological function in vivo. Temperature-jump (T-jump) time-resolved transient mid-IR absorbance spectroscopy is a powerful tool in elucidating the protein dynamical structures and the folding/unfolding kinetics of proteins in solution. A home-built setup of T-jump time-resolved transient mid-IR absorbance spectroscopy with high sensitivity is developed, which is composed of a Q-switched Cr, Tm, Ho:YAG laser with an output wavelength at 2.09 μm as the T-jump heating source, and a continuous working CO laser tunable from 1580 to 1980 cm{sup −1} as the IR probe. The results demonstrate that this system has a sensitivity of 1 × 10{sup −4} ΔOD for a single wavelength detection, and 2 × 10{sup −4} ΔOD for spectral detection in amide I′ region, as well as a temporal resolution of 20 ns. Moreover, the data quality coming from the CO laser is comparable to the one using the commercial quantum cascade laser.

Impact of spectral nudging on the downscaling of tropical cyclones in regional climate simulations

Science.gov (United States)

Choi, Suk-Jin; Lee, Dong-Kyou

2016-06-01

This study investigated the simulations of three months of seasonal tropical cyclone (TC) activity over the western North Pacific using the Advanced Research WRF Model. In the control experiment (CTL), the TC frequency was considerably overestimated. Additionally, the tracks of some TCs tended to have larger radii of curvature and were shifted eastward. The large-scale environments of westerly monsoon flows and subtropical Pacific highs were unreasonably simulated. The overestimated frequency of TC formation was attributed to a strengthened westerly wind field in the southern quadrants of the TC center. In comparison with the experiment with the spectral nudging method, the strengthened wind speed was mainly modulated by large-scale flow that was greater than approximately 1000 km in the model domain. The spurious formation and undesirable tracks of TCs in the CTL were considerably improved by reproducing realistic large-scale atmospheric monsoon circulation with substantial adjustment between large-scale flow in the model domain and large-scale boundary forcing modified by the spectral nudging method. The realistic monsoon circulation took a vital role in simulating realistic TCs. It revealed that, in the downscaling from large-scale fields for regional climate simulations, scale interaction between model-generated regional features and forced large-scale fields should be considered, and spectral nudging is a desirable method in the downscaling method.

Rotation and Noise Invariant Near-Infrared Face Recognition by means of Zernike Moments and Spectral Regression Discriminant Analysis

Czech Academy of Sciences Publication Activity Database

Farokhi, S.; Shamsuddin, S. M.; Flusser, Jan; Sheikh, U. U.; Khansari, M.; Jafari-Khouzani, K.

2013-01-01

Roč. 22, č. 1 (2013), s. 1-11 ISSN 1017-9909 R&D Projects: GA ČR GAP103/11/1552 Keywords : face recognition * infrared imaging * image moments Subject RIV: JD - Computer Applications, Robotics Impact factor: 0.850, year: 2013 http://library.utia.cas.cz/separaty/2013/ZOI/flusser-rotation and noise invariant near-infrared face recognition by means of zernike moments and spectral regression discriminant analysis.pdf

Spitzer SAGE-Spec: Near infrared spectroscopy, dust shells, and cool envelopes in extreme Large Magellanic Cloud asymptotic giant branch stars

Energy Technology Data Exchange (ETDEWEB)

Blum, R. D. [NOAO, 950 North Cherry Avenue, Tucson, AZ 85719 (United States); Srinivasan, S.; Kemper, F.; Ling, B. [Academia Sinica, Institute of Astronomy and Astrophysics, 11F of Astronomy-Mathematics Building, NTU/AS, No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan (China); Volk, K. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States)

2014-11-01

K-band spectra are presented for a sample of 39 Spitzer Infrared Spectrograph (IRS) SAGE-Spec sources in the Large Magellanic Cloud. The spectra exhibit characteristics in very good agreement with their positions in the near-infrared—Spitzer color-magnitude diagrams and their properties as deduced from the Spitzer IRS spectra. Specifically, the near-infrared spectra show strong atomic and molecular features representative of oxygen-rich and carbon-rich asymptotic giant branch stars, respectively. A small subset of stars was chosen from the luminous and red extreme ''tip'' of the color-magnitude diagram. These objects have properties consistent with dusty envelopes but also cool, carbon-rich ''stellar'' cores. Modest amounts of dust mass loss combine with the stellar spectral energy distribution to make these objects appear extreme in their near-infrared and mid-infrared colors. One object in our sample, HV 915, a known post-asymptotic giant branch star of the RV Tau type, exhibits CO 2.3 μm band head emission consistent with previous work that demonstrates that the object has a circumstellar disk.

Spitzer SAGE-Spec: Near infrared spectroscopy, dust shells, and cool envelopes in extreme Large Magellanic Cloud asymptotic giant branch stars

International Nuclear Information System (INIS)

Blum, R. D.; Srinivasan, S.; Kemper, F.; Ling, B.; Volk, K.

2014-01-01

K-band spectra are presented for a sample of 39 Spitzer Infrared Spectrograph (IRS) SAGE-Spec sources in the Large Magellanic Cloud. The spectra exhibit characteristics in very good agreement with their positions in the near-infrared—Spitzer color-magnitude diagrams and their properties as deduced from the Spitzer IRS spectra. Specifically, the near-infrared spectra show strong atomic and molecular features representative of oxygen-rich and carbon-rich asymptotic giant branch stars, respectively. A small subset of stars was chosen from the luminous and red extreme ''tip'' of the color-magnitude diagram. These objects have properties consistent with dusty envelopes but also cool, carbon-rich ''stellar'' cores. Modest amounts of dust mass loss combine with the stellar spectral energy distribution to make these objects appear extreme in their near-infrared and mid-infrared colors. One object in our sample, HV 915, a known post-asymptotic giant branch star of the RV Tau type, exhibits CO 2.3 μm band head emission consistent with previous work that demonstrates that the object has a circumstellar disk.

Changes in spectral signatures of red lettuce regards to Zinc uptake

Science.gov (United States)

Shin, J.; Yu, J.; Koh, S. M.; Park, G.; Kim, S.

2017-12-01

Heavy metal contaminations caused by human activities such as mining and industrial activities caused serious soil contamination. Soil contaminations causes secondary impact on vegetation by uptake processes. Intakes of vegetables harvested from heavy metal contaminated soil may cause serious health problems. It would be very effective if screening tool could be developed before the vegetables are distributed over the market. This study investigated spectral response of red lettuce regards to Zn uptake from the treated soil in a laboratory condition. Zn solutions at different levels of concentration are injected to potted lettuce. The chemical composition and spectral characteristics of the leaves are analyzed every 2 days and the correlation between the Zn concentration and spectral reflectance is investigated. The experiment reveals that Zn uptake of red lettuce is significantly higher for the leaves from treated pot compared to untreated pot showing highly contaminated concentrations beyond the standard Zn concentrations for food. The spectral response regards to Zn is manifested at certain level of concentration threshold. Below the threshold, reflectance at NIR regions increases regards to increase in Zn concentration. On the other hand, above the threshold, IR reflectance decreases and slope of NIR shoulder increases regards to higher Zn concentration. We think this result may contribute for development of screening tools for heavy metal contaminations in vegetables.

[Spectral characteristics of decomposition of incorporated straw in compound polluted arid loess].

Science.gov (United States)

Fan, Chun-Hui; Zhang, Ying-Chao; Xu, Ji-Ting; Wang, Jia-Hong

2014-04-01

The original loess from western China was used as soil sample, the spectral methods of scanning electron microscope-energy dispersive X-ray spectroscopy (SEM-EDS), elemental analysis, Fourier transform infrared spectroscopy (FT-IR) and 13C nuclear magnetic resonance (13C NMR) were used to investigate the characteristics of decomposed straw and formed humic acids in compound polluted arid loess. The SEM micrographs show the variation from dense to decomposed surface, and finally to damaged structure, and the EDS data reveal the phenomenon of element transfer. The newly-formed humic acids are of low aromaticity, helpful for increasing the activity of organic matters in loess. The FTIR spectra in the whole process are similar, indicating the complexity of transformation dynamics of humic acids. The molecular structure of humic acids becomes simpler, shown from 13C NMR spectra. The spectral methods are useful for humic acids identification in loess region in straw incorporation process.

DISK EVOLUTION IN THE THREE NEARBY STAR-FORMING REGIONS OF TAURUS, CHAMAELEON, AND OPHIUCHUS

International Nuclear Information System (INIS)

Furlan, E.; Watson, Dan M.; McClure, M. K.

2009-01-01

We analyze samples of Spitzer Infrared Spectrograph spectra of T Tauri stars in the Ophiuchus, Taurus, and Chamaeleon I star-forming regions, whose median ages lie in the <1-2 Myr range. The median mid-infrared spectra of objects in these three regions are similar in shape, suggesting, on average, similar disk structures. When normalized to the same stellar luminosity, the medians follow each other closely, implying comparable mid-infrared excess emission from the circumstellar disks. We use the spectral index between 13 and 31 μm and the equivalent width of the 10 μm silicate emission feature to identify objects whose disk configuration departs from that of a continuous, optically thick accretion disk. Transitional disks, whose steep 13-31 μm spectral slope and near-IR flux deficit reveal inner disk clearing, occur with about the same frequency of a few percent in all three regions. Objects with unusually large 10 μm equivalent widths are more common (20%-30%); they could reveal the presence of disk gaps filled with optically thin dust. Based on their medians and fraction of evolved disks, T Tauri stars in Taurus and Chamaeleon I are very alike. Disk evolution sets in early, since already the youngest region, the Ophiuchus core (L1688), has more settled disks with larger grains. Our results indicate that protoplanetary disks show clear signs of dust evolution at an age of a few Myr, even as early as ∼1 Myr, but age is not the only factor determining the degree of evolution during the first few million years of a disk's lifetime.

Circumnuclear Regions In Barred Spiral Galaxies. 1; Near-Infrared Imaging

Science.gov (United States)

Perez-Ramirez, D.; Knapen, J. H.; Peletier, R. F.; Laine, S.; Doyon, R.; Nadeau, D.

2000-01-01

We present sub-arcsecond resolution ground-based near-infrared images of the central regions of a sample of twelve barred galaxies with circumnuclear star formation activity, which is organized in ring-like regions typically one kiloparsec in diameter. We also present Hubble Space Telescope near-infrared images of ten of our sample galaxies, and compare them with our ground-based data. Although our sample galaxies were selected for the presence of circumnuclear star formation activity, our broad-band near-infrared images are heterogeneous, showing a substantial amount of small-scale structure in some galaxies, and practically none in others. We argue that, where it exists, this structure is caused by young stars, which also cause the characteristic bumps or changes in slope in the radial profiles of ellipticity, major axis position angle, surface brightness and colour at the radius of the circumnuclear ring in most of our sample galaxies. In 7 out of 10 HST images, star formation in the nuclear ring is clearly visible as a large number of small emitting regions, organised into spiral arm fragments, which are accompanied by dust lanes. NIR colour index maps show much more clearly the location of dust lanes and, in certain cases, regions of star formation than single broad-band images. Circumnuclear spiral structure thus outlined appears to be common in barred spiral galaxies with circumnuclear star formation.

Diagnostics of Coronal Magnetic Fields through the Hanle Effect in UV and IR Lines

Energy Technology Data Exchange (ETDEWEB)

Raouafi, Nour E. [The John Hopkins University Applied Physics Laboratory, Laurel, MD (United States); Riley, Pete [Predictive Science Inc., San Diego, CA (United States); Gibson, Sarah [High Altitude Observatory, National Center for Atmospheric Research, Boulder, CO (United States); Fineschi, Silvano [The Astrophysical Observatory of Turin, National Institute for Astrophysics, Turin (Italy); Solanki, Sami K., E-mail: noureddine.raouafi@jhuapl.edu [Max-Planck-Institut für Sonnensystemforschung, Göttingen (Germany); School of Space Research, Kyung Hee University, Yongin, South (Korea, Republic of)

2016-06-22

The plasma thermodynamics in the solar upper atmosphere, particularly in the corona, are dominated by the magnetic field, which controls the flow and dissipation of energy. The relative lack of knowledge of the coronal vector magnetic field is a major handicap for progress in coronal physics. This makes the development of measurement methods of coronal magnetic fields a high priority in solar physics. The Hanle effect in the UV and IR spectral lines is a largely unexplored diagnostic. We use magnetohydrodynamic (MHD) simulations to study the magnitude of the signal to be expected for typical coronal magnetic fields for selected spectral lines in the UV and IR wavelength ranges, namely the H i Ly-α and the He i 10,830 Å lines. We show that the selected lines are useful for reliable diagnosis of coronal magnetic fields. The results show that the combination of polarization measurements of spectral lines with different sensitivities to the Hanle effect may be most appropriate for deducing coronal magnetic properties from future observations.

Portable compact multifunction IR calibrator

International Nuclear Information System (INIS)

Wyatt, C.L.; Jacobsen, L.; Steed, A.

1988-01-01

A compact portable multifunction calibrator designed for future sensor systems is described which enables a linearity calibration for all detectors simultaneously using a near small-area source, a high-resolution mapping of the focal plane with 10 microrad setability and with a blur of less than 100 microrad, system spectral response calibration (radiometer) using a Michelson interferometer source, relative spectral response (spectrometer) using high-temperature external commercial blackbody simulators, and an absolute calibration using an internal low-temperature extended-area source. 5 references

Spectral characterization and crystal structure of 2-amino-N′-[(1Z-1-(4-chlorophenylethylidene]-benzohydrazide

Directory of Open Access Journals (Sweden)

Mohammad Arfan

2016-01-01

Full Text Available The crystal structure of 2-amino-N′-[(1Z-1-(4-chlorophenylethylidene]benzohydrazide (I is determined by X-ray diffraction at room temperature. The structure of I also was characterized by elemental analysis, mass, FT-IR and NMR spectroscopic techniques. The compound crystallizes in triclinic system, and space group is P1¯. Unit-cell dimensions are the following: a = 7.05380(10 Å, b = 7.65490(10 Å, c = 13.7094(4 Å, V = 694.01(2 Å3, Z = 2. The title compound is nearly planar and has intermolecular N–H⋯O hydrogen bonding. According to the spectral data, I exhibits an amide-iminol tautomerism.

Impact of Humidity on Quartz-Enhanced Photoacoustic Spectroscopy Based CO Detection Using a Near-IR Telecommunication Diode Laser

Directory of Open Access Journals (Sweden)

Xukun Yin

2016-01-01

Full Text Available A near-IR CO trace gas sensor based on quartz-enhanced photoacoustic spectroscopy (QEPAS is evaluated using humidified nitrogen samples. Relaxation processes in the CO-N2-H2O system are investigated. A simple kinetic model is used to predict the sensor performance at different gas pressures. The results show that CO has a ~3 and ~5 times slower relaxation time constant than CH4 and HCN, respectively, under dry conditions. However, with the presence of water, its relaxation time constant can be improved by three orders of magnitude. The experimentally determined normalized detection sensitivity for CO in humid gas is 1.556 × 10 − 8   W ⋅ cm − 1 / Hz 1 / 2 .

Evaluation of Turmeric Powder Adulterated with Metanil Yellow Using FT-Raman and FT-IR Spectroscopy

Directory of Open Access Journals (Sweden)

Sagar Dhakal

2016-05-01

Full Text Available Turmeric powder (Curcuma longa L. is valued both for its medicinal properties and for its popular culinary use, such as being a component in curry powder. Due to its high demand in international trade, turmeric powder has been subject to economically driven, hazardous chemical adulteration. This study utilized Fourier Transform-Raman (FT-Raman and Fourier Transform-Infra Red (FT-IR spectroscopy as separate but complementary methods for detecting metanil yellow adulteration of turmeric powder. Sample mixtures of turmeric powder and metanil yellow were prepared at concentrations of 30%, 25%, 20%, 15%, 10%, 5%, 1%, and 0.01% (w/w. FT-Raman and FT-IR spectra were acquired for these mixture samples as well as for pure samples of turmeric powder and metanil yellow. Spectral analysis showed that the FT-IR method in this study could detect the metanil yellow at the 5% concentration, while the FT-Raman method appeared to be more sensitive and could detect the metanil yellow at the 1% concentration. Relationships between metanil yellow spectral peak intensities and metanil yellow concentration were established using representative peaks at FT-Raman 1406 cm−1 and FT-IR 1140 cm−1 with correlation coefficients of 0.93 and 0.95, respectively.

RESOLVING THE ACTIVE GALACTIC NUCLEUS AND HOST EMISSION IN THE MID-INFRARED USING A MODEL-INDEPENDENT SPECTRAL DECOMPOSITION

Energy Technology Data Exchange (ETDEWEB)

Hernán-Caballero, Antonio; Alonso-Herrero, Almudena [Instituto de Física de Cantabria, CSIC-UC, Avenida de los Castros s/n, E-39005, Santander (Spain); Hatziminaoglou, Evanthia [European Southern Observatory, Karl-Schwarzschild-Strasse 2, D-85748 Garching bei München (Germany); Spoon, Henrik W. W. [Cornell University, CRSR, Space Sciences Building, Ithaca, NY 14853 (United States); Almeida, Cristina Ramos [Instituto de Astrofísica de Canarias, Vía Láctea s/n, E-38205 La Laguna, Tenerife (Spain); Santos, Tanio Díaz [Núcleo de Astronomía de la Facultad de Ingeniería, Universidad Diego Portales, Av. Ejército Libertador 441, Santiago (Chile); Hönig, Sebastian F. [School of Physics and Astronomy, University of Southampton, Southampton SO18 1BJ (United Kingdom); González-Martín, Omaira [Centro de Radioastronomía y Astrofísica (CRyA-UNAM), 3-72 (Xangari), 8701, Morelia (Mexico); Esquej, Pilar, E-mail: ahernan@ifca.unican.es [Departamento de Astrofísica, Facultad de CC. Físicas, Universidad Complutense de Madrid, E-28040 Madrid (Spain)

2015-04-20

We present results on the spectral decomposition of 118 Spitzer Infrared Spectrograph (IRS) spectra from local active galactic nuclei (AGNs) using a large set of Spitzer/IRS spectra as templates. The templates are themselves IRS spectra from extreme cases where a single physical component (stellar, interstellar, or AGN) completely dominates the integrated mid-infrared emission. We show that a linear combination of one template for each physical component reproduces the observed IRS spectra of AGN hosts with unprecedented fidelity for a template fitting method with no need to model extinction separately. We use full probability distribution functions to estimate expectation values and uncertainties for observables, and find that the decomposition results are robust against degeneracies. Furthermore, we compare the AGN spectra derived from the spectral decomposition with sub-arcsecond resolution nuclear photometry and spectroscopy from ground-based observations. We find that the AGN component derived from the decomposition closely matches the nuclear spectrum with a 1σ dispersion of 0.12 dex in luminosity and typical uncertainties of ∼0.19 in the spectral index and ∼0.1 in the silicate strength. We conclude that the emission from the host galaxy can be reliably removed from the IRS spectra of AGNs. This allows for unbiased studies of the AGN emission in intermediate- and high-redshift galaxies—currently inaccesible to ground-based observations—with archival Spitzer/IRS data and in the future with the Mid-InfraRed Instrument of the James Webb Space Telescope. The decomposition code and templates are available at http://denebola.org/ahc/deblendIRS.

Ratioing methods for in-flight response calibration of space-based spectro-radiometers, operating in the solar spectral region

Science.gov (United States)

Lobb, Dan

2017-11-01

One of the most significant problems for space-based spectro-radiometer systems, observing Earth from space in the solar spectral band (UV through short-wave IR), is in achievement of the required absolute radiometric accuracy. Classical methods, for example using one or more sun-illuminated diffusers as reflectance standards, do not generally provide methods for monitoring degradation of the in-flight reference after pre-flight characterisation. Ratioing methods have been proposed that provide monitoring of degradation of solar attenuators in flight, thus in principle allowing much higher confidence in absolute response calibration. Two example methods are described. It is shown that systems can be designed for relatively low size and without significant additions to the complexity of flight hardware.

Design and Development of a Spectral Library for Different Vegetation and Landcover Types for Arctic, Antarctic and Chihuahua Desert Ecosystem

Science.gov (United States)

Matharasi, K.; Goswami, S.; Gamon, J.; Vargas, S.; Marin, R.; Lin, D.; Tweedie, C. E.

2008-12-01

All objects on the Earth's surface absorb and reflect portions of the electromagnetic spectrum. Depending on the composition of the material, every material has its characteristic spectral profile. The characteristic spectral profile for vegetation is often used to study how vegetation patterns at large spatial scales affect ecosystem structure and function. Analysis of spectroscopic data from the laboratory, and from various other platforms like aircraft or spacecraft, requires a knowledge base that consists of different characteristic spectral profiles for known different materials. This study reports on establishment of an online and searchable spectral library for a range of plant species and landcover types in the Arctic, Anatarctic and Chihuahuan desert ecosystems. Field data were collected from Arctic Alaska, the Antarctic Peninsula and the Chihuahuan desert in the visible to near infrared (IR) range using a handheld portable spectrometer. The data have been archived in a database created using postgre sql with have been made publicly available on a plone web-interface. This poster describes the data collected in more detail and offers instruction to users who wish to make use of this free online resource.

Compact near-IR and mid-IR cavity ring down spectroscopy device

Science.gov (United States)

Miller, J. Houston (Inventor)

2011-01-01

This invention relates to a compact cavity ring down spectrometer for detection and measurement of trace species in a sample gas using a tunable solid-state continuous-wave mid-infrared PPLN OPO laser or a tunable low-power solid-state continuous wave near-infrared diode laser with an algorithm for reducing the periodic noise in the voltage decay signal which subjects the data to cluster analysis or by averaging of the interquartile range of the data.

Impaired Insulin Signaling is Associated with Hepatic Mitochondrial Dysfunction in IR+/−-IRS-1+/− Double Heterozygous (IR-IRS1dh Mice

Directory of Open Access Journals (Sweden)

Andras Franko

2017-05-01

Full Text Available Mitochondria play a pivotal role in energy metabolism, but whether insulin signaling per se could regulate mitochondrial function has not been identified yet. To investigate whether mitochondrial function is regulated by insulin signaling, we analyzed muscle and liver of insulin receptor (IR+/−-insulin receptor substrate-1 (IRS-1+/− double heterozygous (IR-IRS1dh mice, a well described model for insulin resistance. IR-IRS1dh mice were studied at the age of 6 and 12 months and glucose metabolism was determined by glucose and insulin tolerance tests. Mitochondrial enzyme activities, oxygen consumption, and membrane potential were assessed using spectrophotometric, respirometric, and proton motive force analysis, respectively. IR-IRS1dh mice showed elevated serum insulin levels. Hepatic mitochondrial oxygen consumption was reduced in IR-IRS1dh animals at 12 months of age. Furthermore, 6-month-old IR-IRS1dh mice demonstrated enhanced mitochondrial respiration in skeletal muscle, but a tendency of impaired glucose tolerance. On the other hand, 12-month-old IR-IRS1dh mice showed improved glucose tolerance, but normal muscle mitochondrial function. Our data revealed that deficiency in IR/IRS-1 resulted in normal or even elevated skeletal muscle, but impaired hepatic mitochondrial function, suggesting a direct cross-talk between insulin signaling and mitochondria in the liver.

New infrared observations of IRS 1, IRS 3, and the adjacent nebula in the OMC-2 cluster

International Nuclear Information System (INIS)

Pendelton, Y.; Werner, M.; Dinerstein, H.

1984-01-01

Recent reports show that near infrared reflection nebulae are often observed around embedded protostellar objects. New observations are here reported of the infrared cluster of low luminosity protostars in Orion Molecular Cloud 2 (OMC2). It has been determined that the asymmetric distribution of the extended emission seen about IRS1 is in fact another infrared reflection nebula. Observations of near infrared polarimetry, photometry, and spectrophotometry were carried out at the NASA Infrared Telescope Facility October 1982 and January 1983. (author)

Transfer standard for the spectral density of relative intensity noise of optical fiber sources near 1550 nm

International Nuclear Information System (INIS)

Obarski, Gregory E.; Splett, Jolene D.

2001-01-01

We have developed a transfer standard for the spectral density of relative intensity noise (RIN) of optical fiber sources near 1550 nm. Amplified spontaneous emission (ASE) from an erbium-doped fiber amplifier (EDFA), when it is optically filtered over a narrow band (<5 nm), yields a stable RIN spectrum that is practically constant to several tens of gigahertz. The RIN is calculated from the power spectral density as measured with a calibrated optical spectrum analyzer. For a typical device it is -110 dB/Hz, with uncertainty ≤0.12 dB/Hz. The invariance of the RIN under attenuation yields a considerable dynamic range with respect to rf noise levels. Results are compared with those from a second method that uses a distributed-feedback laser (DFB) that has a Poisson-limited RIN. Application of each method to the same RIN measurement system yields frequency-dependent calibration functions that, when they are averaged, differ by ≤0.2 dB. [copyright] 2001 Optical Society of America

Transparency of Semi-Insulating, n-Type, and p-Type Ammonothermal GaN Substrates in the Near-Infrared, Mid-Infrared, and THz Spectral Range

OpenAIRE

Robert Kucharski; Łukasz Janicki; Marcin Zajac; Monika Welna; Marcin Motyka; Czesław Skierbiszewski; Robert Kudrawiec

2017-01-01

GaN substrates grown by the ammonothermal method are analyzed by Fast Fourier Transformation Spectroscopy in order to study the impact of doping (both n- and p-type) on their transparency in the near-infrared, mid-infrared, and terahertz spectral range. It is shown that the introduction of dopants causes a decrease in transparency of GaN substrates in a broad spectral range which is attributed to absorption on free carriers (n-type samples) or dopant ionization (p-type samples). In the mid-in...

Diode Laser Detection of Greenhouse Gases in the Near-Infrared Region by Wavelength Modulation Spectroscopy: Pressure Dependence of the Detection Sensitivity

Directory of Open Access Journals (Sweden)

Takashi Asakawa

2010-05-01

Full Text Available We have investigated the pressure dependence of the detection sensitivity of CO2, N2O and CH4 using wavelength modulation spectroscopy (WMS with distributed feed-back diode lasers in the near infrared region. The spectral line shapes and the background noise of the second harmonics (2f detection of the WMS were analyzed theoretically. We determined the optimum pressure conditions in the detection of CO2, N2O and CH4, by taking into consideration the background noise in the WMS. At the optimum total pressure for the detection of CO2, N2O and CH4, the limits of detection in the present system were determined.

The Type IIP SN 2005ay: An Extensive Study From UltraViolet To Near-IR

Science.gov (United States)