Sample records for lithium hydrides

Sample records 1 - 1 shown.


Diastereosseletividade na redução de enonas bicíclicas com hidretos volumosos/ Diastereoselectivity in the reduction of bicyclic enones with hindered hydrides

Camozzato, Andreza C.; Tenius, Beatriz S. M.; Oliveira, Eduardo R. de; Viegas Jr., Cláudio; Victor, Maurício M.; Silveira, Leandro G. da

Resumo em inglês Reduction of five substituted octalones employing lithium tri-sec-butylborohydride (L-selectride®) in THF and ethyl ether led to allylic alcohols with moderate diastereoselectivity. The stereoselectivity of addition of bulky hydrides showed to be different from most examples in the literature and was strongly influenced by substitution on the octalone ring.

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