Mono- and Bis-Ortho-Chelated Lithium and Sodium Phenolates. Molecular Structures of the First Lithium Phenolate with a Stable, Trinuclear Structure and of a Tetranuclear Sodium Analog, [MOC~6H~2(CH~2NMe~2)~2-2,6-Me-4)~x (M = Li, x = 3; M = Na, x = 4)
Organoamido- and aryloxo-lanthanoids. V. Preparations of low-coordinate lanthanoid(II) phenolates, Ln(OC~6H~2Bu^t~2-2,6-X-4)~2(thf)~n (Ln = Yb or Eu; X = H, Me or Bu^t; n = 2 or 3) and the X-ray crystal structure of five-coordinate [Yb(OC~6H~2Bu^t~3-2,4,6)~2(thf)~3].thf.
Macrocyclic complexes derived from the cyclocondensation of sodium 2,6-diformyl-4-substituted phenolates with N,N-bis(2-aminoethyl)-2-hydroxybenzylamine and in situ transmetallation. An anticipated dinuclear Cd(II) pendant-arm macrocyclic complex and an unexpected mononuclear Fe(III) macrocyclic complex
Synthesis and Reactivity of Tantalum Complexes Supported by Bidentate X~2 and Tridentate LX~2 Ligands with Two Phenolates Linked to Pyridine, Thiophene, Furan, and Benzene Connectors: Mechanistic Studies of the Formation of a Tantalum Benzylidene and Insertion Chemistry for Tantalum-Carbon Bonds