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Sample records for mpa

  1. Protein: MPA1 [TP Atlas

    Lifescience Database Archive (English)

    Full Text Available MPA1 TLR signaling molecules Rsad2 Vig1 Radical S-adenosyl methionine domain-containing pr...otein 2 Viperin, Virus inhibitory protein, endoplasmic reticulum-associated, interferon-inducible 10090 Mus musculus 58185 Q8CBB9 21435586 ...

  2. Protein: MPA1 [TP Atlas

    Lifescience Database Archive (English)

    Full Text Available MPA1 TLR signaling molecules MAVS IPS1, KIAA1271, VISA VISA_(gene) Mitochondrial antiviral-signaling pr...otein CARD adapter inducing interferon beta, Interferon beta promoter stimulator protein... 1, Putative NF-kappa-B-activating protein 031N, Virus-induced-signaling adapter 9606 Homo sapiens Q7Z434 57506 2VGQ 57506 ...

  3. MPA Materials Matter July 2016

    Energy Technology Data Exchange (ETDEWEB)

    Kippen, Karen Elizabeth [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-07-21

    This is the newsletter of the Materials Physics and Applications Division of Los Alamos National Laboratory for July 2016. Researcher Nathan Mara is highlighted, the MPA Deputy Division Leader gives a summary of progress within the division, and two different LANL-published studies are detailed.

  4. 34. MPA seminar 2008. Proceedings; 34. MPA Seminar 2008. Vortraege

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-12-17

    The proceedings include two introductory lectures: The renaissance of nuclear power - causes and challenges; on the way to the coal fired power plant with 50% efficiency. The other contributions concern the following topics: MPA-IfW-NIMS-Workshop: microstructural evolution (7 contributions), advanced materials (6 contributions), material and damage behaviour (6 contributions), integrity of nuclear plants and components (13 contributions), monitoring and inspection (6 contributions), creep and lifetime analysis (4 contributions), applications to HT components (4 contributions), fracture mechanics (7 components).

  5. 33. MPA seminar 2007. Proceedings; 33. MPA Seminar 2007. Vortraege

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    In a single PDF file, the CD-ROM contains all papers presented at the 33. MPA Seminar in Stuttgart. Subjects: Life management of nuclear facilities: Materials, integrity analysis, fracture mechanics; Behaviour of welds; Material development and qualification for power plants with enhanced steam parameters; monitoring concepts (e.g. state monitoring of components, test concepts); Design of pipelines with flanged joints; Assembly and joining technology for flanged joints; Non-destructive testing in plant engineering; Materials for new nuclear reactors. Many of the papers are available as separate items in this database. [German] In einer einzigen PDF-Datei sind auf der CD-ROM alle Vortraege enthalten, die auf dem 33. MPA-Seminar in Stuttgart gehalten wurden. Die Themenschwerpunkte sind: Lebensdauermanagement kerntechnischer Anlagen - Werkstoffverhalten, Integritaetsanalyse, Bruchmechanik; Verhalten von Schweissverbindungen; Werkstoffentwicklung und -qualifizierung fuer Kraftwerke mit erhoehten Dampfparametern; Ueberwachungskonzepte (z.B. Zustandsueberwachung von Komponenten, Pruefkonzepte); Auslegung von Rohrleitungen mit Flanschverbindungen; Montage- und Dichtungstechnik fuer Flanschverbindungen; Zerstoerungsfreie Pruefung in der Anlagentechnik; Werkstoffe fuer neue Kernreaktoren. Ein grosser Teil der Vortraege wurde separat aufgenommen.

  6. Visit to MPA Stuttgart - Universitaet Stuttgart

    International Nuclear Information System (INIS)

    1980-01-01

    The booklet contains the introduction lectures to the following demonstration tests of the MPA Stuttgart: - Large scale specimen tensile testing; - full size vessel; - high speed tensile machine; - explosion high speed tensile machine; - heat affected zone simulation. (RW)

  7. Lessons from Philippines MPA Management: Social Ecological Interactions, Participation, and MPA Performance

    Science.gov (United States)

    Twichell, Julia; Pollnac, Richard; Christie, Patrick

    2018-06-01

    International interest in increasing marine protected area (MPA) coverage reflects broad recognition of the MPA as a key tool for marine ecosystems and fisheries management. Nevertheless, effective management remains a significant challenge. The present study contributes to enriching an understanding of best practices for MPA management through analysis of archived community survey data collected in the Philippines by the Learning Project (LP), a collaboration with United States Coral Triangle Initiative (USCTI), United States Agency for International Development (USAID), and partners. We evaluate stakeholder participation and social ecological interactions among resource users in MPA programs in the Palawan, Occidental Mindoro, and Batangas provinces in the Philippines. Analysis indicates that a complex suite of social ecological factors, including demographics, conservation beliefs, and scientifically correct knowledge influence participation, which in turn is related to perceived MPA performance. Findings indicate positive feedbacks within the system that have potential to strengthen perceptions of MPA success. The results of this evaluation provide empirical reinforcement to current inquiries concerning the role of participation in influencing MPA performance.

  8. Lessons from Philippines MPA Management: Social Ecological Interactions, Participation, and MPA Performance.

    Science.gov (United States)

    Twichell, Julia; Pollnac, Richard; Christie, Patrick

    2018-06-01

    International interest in increasing marine protected area (MPA) coverage reflects broad recognition of the MPA as a key tool for marine ecosystems and fisheries management. Nevertheless, effective management remains a significant challenge. The present study contributes to enriching an understanding of best practices for MPA management through analysis of archived community survey data collected in the Philippines by the Learning Project (LP), a collaboration with United States Coral Triangle Initiative (USCTI), United States Agency for International Development (USAID), and partners. We evaluate stakeholder participation and social ecological interactions among resource users in MPA programs in the Palawan, Occidental Mindoro, and Batangas provinces in the Philippines. Analysis indicates that a complex suite of social ecological factors, including demographics, conservation beliefs, and scientifically correct knowledge influence participation, which in turn is related to perceived MPA performance. Findings indicate positive feedbacks within the system that have potential to strengthen perceptions of MPA success. The results of this evaluation provide empirical reinforcement to current inquiries concerning the role of participation in influencing MPA performance.

  9. Microstructural Effects on Hydrogen Delayed Fracture of 600 MPa and 800 MPa grade Deposited Weld Metal

    International Nuclear Information System (INIS)

    Kang, Hee Jae; Lee, Tae Woo; Cho, Kyung Mox; Kang, Namhyun; Yoon, Byung Hyun; Park, Seo Jeong; Chang, Woong Seong

    2012-01-01

    Hydrogen-delayed fracture (HDF) was analyzed from the deposited weld metals of 600-MPa and 800-MPa flux-cored arc (FCA) welding wires, and then from the diffusible hydrogen behavior of the weld zone. Two types of deposited weld metal, that is, rutile weld metal and alkali weld metal, were used for each strength level. Constant loading test (CLT) and thermal desorption spectrometry (TDS) analysis were conducted on the hydrogen pre-charged specimens electrochemically for 72 h. The effects of microstructures such as acicular ferrite, grain-boundary ferrite, and low-temperature-transformation phase on the time-to failure and amount of diffusible hydrogen were analyzed. The fracture time for hydrogen-purged specimens in the constant loading tests decreased as the grain size of acicular ferrite decreased. The major trapping site for diffusible hydrogen was the grain boundary, as determined by calculating the activation energies for hydrogen detrapping. As the strength was increased and alkali weld metal was used, the resistance to HDF decreased.

  10. U.S. Marine Protected Areas Boundaries: MPA Inventory

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The MPA Inventory is a comprehensive catalog that provides detailed information for existing marine protected areas in the United States. The inventory provides...

  11. HHP treatment of liquid egg at 200-350 MPa

    Science.gov (United States)

    Tóth, A.; Németh, Cs; Palotás, P.; Surányi, J.; Zeke, I.; Csehi, B.; Castillo, L. A.; Friedrich, L.; Balla, Cs

    2017-10-01

    High hydrostatic pressure (HHP) treatment of egg proteins partially limits their sensitivity to pressure. According to the literature, at the 450 MPa level, denaturation of some proteins sets in to the extent that sensory and functional characteristics are impacted. This study involved treating liquid egg (egg white, yolk, and melange) at less than the above-mentioned value, after which the microbiological effect was examined. For the study, pressure pouches were filled with 100ml of raw liquid egg per pouch. Then the samples were treated at 200, 250, 300 and 350 MPa. In each case, the level was reached by increasing pressure at a rate of 100 MPa/min. Measurements were taken at the Corvinus University of Budapest, Faculty of Food Science, Dept. of Refrigeration and Livestock Products Technology RESATO FPU 100-2000 equipment. Denaturation was determined with calorimetric (DSC) tests. From our results, it appears that even at 250 MPa pressure treatment, the viable cell count decreases. Further, it can be said that microbe count went down in the egg white samples at 300-350 MPa, below the impact level. Significant denaturation was not detected during our examinations. In summary, we state that the most HHP-sensitive liquid egg type, egg white, can be pressure treated to reduce microbe count at a level less than that which causes denaturation. Microbe reduction was smaller in yolk and melange, so higher pressure values are appropriate for these products.

  12. An Empirical Investigation of MPA Student Performance and Admissions Criteria

    Science.gov (United States)

    Ragothaman, Srinivasan; Carpenter, Jon; Davies, Thomas

    2009-01-01

    The quality of a Master of Professional Accountancy (MPA) program, similar to other undergraduate and graduate programs in business and other disciplines, is typically directly related to the quality of its students. While there is a considerable published scholarly work on MBA student performance, there is very little research to predict student…

  13. Matrix phased array (MPA) imaging technology for resistance spot welds

    Science.gov (United States)

    Na, Jeong K.; Gleeson, Sean T.

    2014-02-01

    A three-dimensional MPA probe has been incorporated with a high speed phased array electronic board to visualize nugget images of resistance spot welds. The primary application area of this battery operated portable MPA ultrasonic imaging system is in the automotive industry which a conventional destructive testing process is commonly adopted to check the quality of resistance spot welds in auto bodies. Considering an average of five-thousand spot welds in a medium size passenger vehicle, the amount of time and effort given to popping the welds and measuring nugget size are immeasurable in addition to the millions of dollars' worth of scrap metals recycled per plant per year. This wasteful labor intensive destructive testing process has become less reliable as auto body sheet metal has transitioned from thick and heavy mild steels to thin and light high strength steels. Consequently, the necessity of developing a non-destructive inspection methodology has become inevitable. In this paper, the fundamental aspects of the current 3-D probe design, data acquisition algorithms, and weld nugget imaging process are discussed.

  14. Matrix phased array (MPA) imaging technology for resistance spot welds

    International Nuclear Information System (INIS)

    Na, Jeong K.; Gleeson, Sean T.

    2014-01-01

    A three-dimensional MPA probe has been incorporated with a high speed phased array electronic board to visualize nugget images of resistance spot welds. The primary application area of this battery operated portable MPA ultrasonic imaging system is in the automotive industry which a conventional destructive testing process is commonly adopted to check the quality of resistance spot welds in auto bodies. Considering an average of five-thousand spot welds in a medium size passenger vehicle, the amount of time and effort given to popping the welds and measuring nugget size are immeasurable in addition to the millions of dollars' worth of scrap metals recycled per plant per year. This wasteful labor intensive destructive testing process has become less reliable as auto body sheet metal has transitioned from thick and heavy mild steels to thin and light high strength steels. Consequently, the necessity of developing a non-destructive inspection methodology has become inevitable. In this paper, the fundamental aspects of the current 3-D probe design, data acquisition algorithms, and weld nugget imaging process are discussed

  15. Matrix phased array (MPA) imaging technology for resistance spot welds

    Energy Technology Data Exchange (ETDEWEB)

    Na, Jeong K.; Gleeson, Sean T. [Edison Welding Institute, 1250 Arthur E. Adams Drive, Columbus, OH 43221 (United States)

    2014-02-18

    A three-dimensional MPA probe has been incorporated with a high speed phased array electronic board to visualize nugget images of resistance spot welds. The primary application area of this battery operated portable MPA ultrasonic imaging system is in the automotive industry which a conventional destructive testing process is commonly adopted to check the quality of resistance spot welds in auto bodies. Considering an average of five-thousand spot welds in a medium size passenger vehicle, the amount of time and effort given to popping the welds and measuring nugget size are immeasurable in addition to the millions of dollars' worth of scrap metals recycled per plant per year. This wasteful labor intensive destructive testing process has become less reliable as auto body sheet metal has transitioned from thick and heavy mild steels to thin and light high strength steels. Consequently, the necessity of developing a non-destructive inspection methodology has become inevitable. In this paper, the fundamental aspects of the current 3-D probe design, data acquisition algorithms, and weld nugget imaging process are discussed.

  16. Temperature control for high pressure processes up to 1400 MPa

    International Nuclear Information System (INIS)

    Reineke, K; Mathys, A; Knorr, D; Heinz, V

    2008-01-01

    Pressure- assisted sterilisation is an emerging technology. Hydrostatic high pressure can reduce the thermal load of the product and this allows quality retention in food products. To guarantee the safety of the sterilisation process it is necessary to investigate inactivation kinetics especially of bacterial spores. A significant roll during the inactivation of microorganisms under high pressure has the thermodynamic effect of the adiabatic heating. To analyse the individual effect of pressure and temperature on microorganism inactivation an exact temperature control of the sample to reach ideal adiabatic conditions and isothermal dwell times is necessary. Hence a heating/cooling block for a high pressure unit (Stansted Mini-Food-lab; high pressure capillary with 300 μL sample volume) was constructed. Without temperature control the sample would be cooled down during pressure built up, because of the non-adiabatic heating of the steel made vessel. The heating/cooling block allows an ideal adiabatic heat up and cooling of the pressure vessel during compression and decompression. The high pressure unit has a pressure build-up rate up to 250 MPa s -1 and a maximum pressure of 1400 MPa. Sebacate acid was chosen as pressure transmitting medium because it had no phase shift over the investigate pressure and temperature range. To eliminate the temperature difference between sample and vessel during compression and decompression phase, the mathematical model of the adiabatic heating/cooling of water and sebacate acid was implemented into a computational routine, written in Test Point. The calculated temperature is the setpoint of the PID controller for the heating/cooling block. This software allows an online measurement of the pressure and temperature in the vessel and the temperature at the outer wall of the vessel. The accurate temperature control, including the model of the adiabatic heating opens up the possibility to realise an ideal adiabatic heating and cooling

  17. Argon Diffusion Measured in Rhyolite Melt at 100 MPa

    Science.gov (United States)

    Weldon, N.; Edwards, P. M.; Watkins, J. M.; Lesher, C. E.

    2016-12-01

    Argon diffusivity (D_{Ar} ) controls the rate and length scale of argon exchange between melt and gas phases and is used as a parameter to model noble gas fractionation during magma degassing. D_{Ar} may also be useful in geochronology to estimate the distribution of excess (non-radiogenic) atmospheric argon in lavas. Our measurements of D_{Ar} in molten anhydrous rhyolite near 1000 °C and 100 MPa add to the existing dataset. Using a rapid-quench cold seal pressure apparatus we exposed cylindrical charges drilled from a Miocene rhyolite flow near Buck Mtn., CA to a pure argon atmosphere resulting in a gradually lengthening argon concentration gradient between the saturated surface and the argon poor interior. Argon concentration was measured by electron microprobe along radial transects from the center to the surface of bisected samples. D_{Ar} was calculated for each transect by fitting relative argon concentration (as a function of distance from the surface) to Green's function (given each experiment's specific temperature, pressure and runtime). Variability (σ = 1.202{μm }^{2} /s) was smaller than in previous studies, but still greater than what is likely due to analytical or experimental uncertainty. We observed a symmetric geometric bias in the distribution of argon in our samples, possibly related to advective redistribution of argon accompanying the deformation of cylindrical charges into spheroids driven by surface tension. Average diffusivity, D_{Ar} = 4.791{μm }^{2} /s, is close to the predicted value, D_{Ar} = {μm }^{2} /s ( σ_{ \\bar{x} } = 1.576 {μm }^{2} /s), suggesting that Behrens and Zhang's (2001) empirical model is valid for anhydrous rhyolite melts to relatively higher temperatures and lower pressures. Behrens, H. and Y. Zhang (2001). "Ar diffusion in hydrous silicic melts: implications for volatile diffusion mechanisms and fractionation." Earth and Planetary Science Letters 192: 363-376.

  18. Nonprofit Management Education in MPA Programs: Lessons for Successful Track Building

    Science.gov (United States)

    Gerlach, John David

    2016-01-01

    As the American nonprofit sector continues to grow, so does interest in nonprofit management graduate education. MPA programs play a significant role in preparing students for work in the nonprofit field. This article examines nonprofit management as an area of graduate study, paying particular attention to how NASPAA-accredited MPA programs…

  19. Integrity of power plant components. Research performed by Professor K. Kussmaul at MPA Stuttgart

    International Nuclear Information System (INIS)

    Roos, E.; Maile, K.

    1998-01-01

    The history of the Staatliche Materialpruefungsanstalt - the State Material Testing Institute - (MPA) Stuttgart is characterized by the scientific qualifications of its directors. During the 40 years of work at the MPA, Professor Karl Kussmaul has come up to the expectations of this tradition and has with his works firmly established the renowned 'Stuttgarter Schule' - the School of Stuttgart - founded by Bach. (orig.) [de

  20. PENGENDALIAN KEBAKARAN HUTAN OLEH MASYARAKAT PEDULI API (MPA DI TAMAN NASIONAL GUNUNG CIREMAI

    Directory of Open Access Journals (Sweden)

    Nurul Fadillah

    2017-05-01

    Full Text Available Mount Ciremai National Park (TNGC is a National Park (TN which has enormous ecological functions, especially as a water catchment area. Forest fires in TNGC occur every year and fluctuated from year to year. Forst fires destroy ecosystems and interfere the function of TNGC. Anti Fire Community (MPA is a partnership which consist of local communities involved in forest fire control. Community partnership will never succeess without the MPA’s participation. The research objectives are to describe the perception and participation of MPA on the forest fires control in TNGC and the implementation of MPA policies. This research method is done by questionnaires, observation and interviews. The results showed that MPA positively perceive that dry season as supporting factors and community activities that involve a fire as direct factors of forest fires. The public perception is not always in line with the participation. A strong perception does not guarantee a high participation, it might be the opposit (low participation. The highest MPA’s participation in forest fires control is in forest fighting activities. Affecting factors on MPA's participation in forest fire control activities are economic factors ie wage, logistics dan goods. Occuring gap between the ideal conditions and real conditions is 80,95 percent. Perceptions which is not in line with the participation and the emerge gap is suspected to cause unoptimized of forest fire control conducted by MPA in TNGC. Keywords: forest fire control, gap, MPA, particiation, perception

  1. Interfacial (Fiber-matrix) Properties of High-strength Mortar (150 MPa) from Fiber Pullout

    DEFF Research Database (Denmark)

    Shannag, M.J.; Brincker, Rune; Hansen, Will

    1996-01-01

     The steel fiber-matrix properties of high-strength mortar (150 MPa), such as DSP (densified small particle), are obtained and compared to an ordinary strength mortar (40 MPa) using a specially designed fiber pullout apparatus. A new method for estimating the debonding energy of the interfacial z......-strength DSP mortar has significantly improved interfacial properties compared to ordinary strength mortar. These results are important in the understanding of the role of steel fibers in improving the tensile properties of high-strength, brittle, cement-matrix composites....... The steel fiber-matrix properties of high-strength mortar (150 MPa), such as DSP (densified small particle), are obtained and compared to an ordinary strength mortar (40 MPa) using a specially designed fiber pullout apparatus. A new method for estimating the debonding energy of the interfacial...

  2. Research activities of MPA, Stuttgart University, for enhanced safety and reliability of components under complex load

    International Nuclear Information System (INIS)

    Herter, K.H.; Roos, E.; Schuler, X.; Maile, K.

    2004-01-01

    MPA research activities focus on fracture prevention and on the development of a generally applicable method of component integrity testing which, independent of the safety relevance of the components involved, is also part of ageing management. (orig.) [de

  3. Neurons in the brain of the male cynomolgus monkey accumulate 3H-medroxyprogesterone acetate (MPA)

    International Nuclear Information System (INIS)

    Michael, R.P.; Bonsall, R.W.; Rees, H.D.

    1986-01-01

    MPA is a synthetic progestin with androgen-depleting activity. It is used clinically to reduce sexual motivation and aggression in male sex offenders. The mechanisms for its behavioral effects are not known. The authors used steroid autoradiography to help identify sites where MPA may act in the brain of male primates. Twenty-four hours after castration, two adult male cynomolgus macaques, weighing 4.9 and 6.6 kg, were administered 5 mCi 3 H-MPA (NEN, 47.7 Ci/mmol) i.v., and were killed 1 h later. Left sides of the brains and samples of pituitary glands were frozen and 4-micron sections were cut and processed for thaw-mount autoradiography. Radioactivity was concentrated in the nuclei of many neutrons in the ventromedial hypothalamic nucleus (n.), arcuate n., medial preoptic n., and anterior hypothalamic area. Virtually no labeled cells were seen in the bed n. of stria terminalis, lateral septal n., amygdala, or pituitary gland. Right sides of the brains were analyzed by HPLC which demonstrated that 98% of the radioactivity in cell nuclei from the hypothalamus was in the form of unmetabolized 3 H-MPA. The distribution of labelling in the brain following 3 H-MPA administration resembled that previously seen following 3 H-ORG 2058 in female cynomolgus monkeys. These data indicate that MPA has a circumscribed localization in the brain

  4. Movement patterns of Mediterranean moray and European conger in a coastal MPA

    Directory of Open Access Journals (Sweden)

    Ana Filipa Silva

    2015-11-01

    Full Text Available The Pessegueiro Island Marine Protected Area (MPA, SW coast of Portugal, was implemented in 2011 with the purpose of protect biodiversity and prevent over-exploitation of commercially important fish species. Amongst those species are the Mediterranean moray (Muraena helena and the European conger (Conger conger. In this context, the aim of this study was to assess the importance of this MPA as a refuge/feeding area for these species and to evaluate its location and size adequacy. The study was carried out during the summer of 2013 and a total of 19 morays and 6 congers were tagged with acoustic transmitters. An array of 19 automatic receivers was deployed with a sampling design that spatially covered the entire MPA. The data from the receivers was analysed through multivariate statistics (PERMANOVA, Kernel Density Estimation (KDE and Network Analysis. Results showed that the Pessegueiro Island MPA is an important zone for both species since the tagged morays and congers spent 48% of the time within the area (average residency index. Also, KDE and Network Analysis showed that both species displayed relatively reduced home ranges, 20 ha in average for morays and 30 ha for congers, and the movements performed were limited to adjacent areas. Activity was more intense during night time for both species. Regarding morays, lunar cycle and sea conditions also seemed to influence their movement patterns. The data collected in this study highlight the importance of this MPA for the target species.

  5. Tensile Properties of Under-Matched Weld Joints for 950 MPa Steel.

    Science.gov (United States)

    Yamamoto, Kouji; Arakawa, Toshiaki; Akazawa, Nobuki; Yamamoto, Kousei; Matsuo, Hiroki; Nakagara, Kiyoyuki; Suita, Yoshikazu

    In welding of 950 MPa-class high tensile strength steel, preheating is crucial in order to avoid cold cracks, which, however, eventually increases welding deformations. One way to decrease welding deformations is lowering preheating temperature by using under-matched weld metal. Toyota and others clarify that although breaking elongation can decrease due to plastic constraint effect under certain conditions, static tensile of under-matched weld joints is comparable to that of base metal. However, there has still been no report about joint static tensile of under-matched weld joints applied to 950 MPa-class high tensile strength steel. In this study, we aim to research tensile strength and fatigue strength of under-matched weld joints applied to 950 MPa-class high tensile steel.

  6. The MPA Capstone Course: Multifaceted Uses and Potentialities in Program Assessment

    Science.gov (United States)

    Ahmed, Shamima

    2015-01-01

    In the United States, Master of Public Administration Program (MPA) accreditations come through fulfilling the Network of Schools of Public Policy, Affairs, and administration (NASPAA) accreditation standards. In 2009, NASPAA made some significant revisions to its accreditation standards. One of the major revisions is the requirement for programs…

  7. MammaPrint Pre-screen Algorithm (MPA) reduces chemotherapy in ...

    African Journals Online (AJOL)

    MammaPrint Pre-screen Algorithm (MPA) reduces chemotherapy in patients with early-stage breast cancer. ... An implementation study was designed to take advantage of the fact that the 70-gene profile excludes analysis of hormone receptor and human epidermal growth factor receptor 2 (HER2) status, which form part of ...

  8. Activities of the MPA Stuttgart in connection with QA of nuclear power plants

    International Nuclear Information System (INIS)

    Maier, H.J.

    1980-01-01

    The MPA Stuttgart (Institute of Testing of Materials, University of Stuttgart) is concerned with quality assurance of german nuclear power plants, additional to the technical inspection organizations and the plant owners. The orders are given by state authorities, federal authorities and the RSK (reactor security commission). There are shown some examples of this work, concerning with materials and testing of materials. (orig./RW)

  9. Microstructure and properties of 700 MPa grade HSLA steel during high temperature deformation

    International Nuclear Information System (INIS)

    Chen, Xizhang; Huang, Yuming; Lei, Yucheng

    2015-01-01

    Highlights: • Hot deformation behavior of 700 MPa HSLA steel above 1200 °C in was detailed studied. • Uniform and granular bainite is formed when the deformation amount is 40%. • Deformation resistance value under steady-equilibrium state is about 56 MPa. - Abstract: A high temperature deformation experiment was conducted on a high strength low alloy (HSLA) steel Q690 using Thermecmastor-Z thermal/physical simulator. During the experiment, the specimens were heated from room temperature to 1200 °C with the heating rate of 10 °C/s and 50 °C/s, respectively. The deformation temperature was 1200 °C and the deformation amounts were 0%, 10% and 40%, respectively. The microstructures, stress–strain diagram and hardness were obtained. The results revealed that the microstructure transformation of deformed austenite was quite different from that of the normal situation. With the increasing of deformation amount, more lath-shaped microstructure and less granulous microstructure were observed. The compressive deformation effectively prevented the precipitation of carbides. Larger deformation amount or lower heating rate was conducive to the atomic diffusion, which led to the microstructure uniformity and hardness decreasing. The maximum stress was 68.4 MPa and the steady stress was about 56 MPa

  10. Science summary in support of Manatee Protection Area (MPA) design in Puerto Rico

    Science.gov (United States)

    Drew, C. Ashton; Alexander-Vaughn, Louise B.; Collazo, Jaime A.

    2012-01-01

    The Antillean manatee (Trichechus manatus manatus), a subspecies of the West Indian manatee, is listed as endangered by the US Department of Interior. In accordance with its listing, the U.S. Fish and Wildlife Service’s Caribbean Field Office (USFWS) is mandated to create one or more Manatee Protection Areas (MPAs) for Puerto Rico. Designation of these areas must comply with the legal definition of an MPA’s purpose: to prevent or reduce take of manatees (CFR 50: 44 FR 60964, Oct. 22, 1979). To meet this goal, we pursued two objectives: 1) identify areas which include the specific ecological attributes necessary to support manatee populations, and 2) identify areas where take can be reduced through approved MPA regulatory frameworks. We achieved these objectives through literature review, expert elicitation, and geospatial modeling. This report delivers to USFWS a set of nine potential MPA regions. These regions represent the spatial realization of experts’ hypotheses regarding manatee requirements and threats, and the potential to implement MPA strategies (e.g. watercraft access, speed regulations, signage and boater education). The nine regions are compared based on a number of factors, including their potential to reduce take, quality of the habitat encompassed, and total area. These maps and statistics serve as suitable starting points to select one or more MPA sites, but we recommend that the mapped attributes and threats (i.e., boating activity) of MPAs be ground-truthed to visually confirm the local presence of resources, threats, and manatees before any area is selected. Once established, the effectiveness of MPAs can be monitored and updated through processes of adaptive monitoring and management. Aerial surveys, radio tracking studies, and public surveys are all valuable tools to assess the success of an MPA. Establishing MPAs is a management action that, integrated within the species Recovery Plan, should enhance the conservation of manatees.

  11. Influence of superplasticizer on microstructure of a 40 MPa strength concrete; Influencia do aditivo superplastificante na microestrutura de um concreto de resistencia mecanica de 40 MPa

    Energy Technology Data Exchange (ETDEWEB)

    Teixeira, Sandra M.F.; Menezes, Raquel Maria R.O.; Figueiredo, Roberto B.; Aguilar, Maria Teresa P. [Universidade Federal de Minas Gerais (UFMG), MG (Brazil); Franca, Fabricio Carlos [LafargeHolcim, Rio de Janeiro, RJ (Brazil); Bezerra, Augusto Cesar da S. [Centro Federal de Educacao Tecnologica de Minas Gerais (CEFET-MG), MG (Brazil)

    2016-07-01

    The self compacting concrete has high fluidity and deformability. Studies analyze its performance through compressive strength, mortar content and / or water cement factor, which does not allow the evaluation of superplasticante influence the microstructure of these concretes. In this work, we evaluated the influence of superplasticizer comparing the phases present in a self-compacting concrete 40 MPa and at a same conventional compressive strength, same water / cement and mortar content. Therefore, scanning techniques were employed by electron microscope low vacuum using backscattered electrons and thermal analysis. The observed results show no significant differences in the microstructure of the two composites, ie the superplasticizer does not alter the microstructure of the self-compacting concrete. However, thermal analysis indicates that the present self-compacting concrete greater calcium hydroxide content which may suggest a lower content of such dry cement concrete. (author)

  12. PERFORMANCE ANALYSIS OF RECTANGULAR MPA USING DIFFERENT SUBSTRATE MATERIALS FOR WLAN APPLICATION

    Directory of Open Access Journals (Sweden)

    E Aravindraj

    2017-03-01

    Full Text Available In this paper, a rectangular microstrip patch antenna (MPA is designed using different substrate materials for analyzing the performance of the MPA. Alumina (Al2O3, Bakelite, Beryllium oxide (BeO, Gallium Arsenide (GaAs, RT-Duroid and Flame Retardant 4 (FR-4 are the six different substrate used in the design. The size of the rectangular microstrip patch antenna varies according to the dielectric constant of substrate materials used. The operating frequency taken for this analysis is 5.8 GHz. The proposed design provides the study on the performance of rectangular microstrip patch antenna for different substrate materials using the same frequency. This study conveys that which substrate material provides better performance. Moreover, this comparative study conveys that which substrate material provides better performance. The simulation parameters are investigated using HFSS.

  13. Applicability of newly developed 610MPa class heavy thickness high strength steel to boiler pressure vessel

    Energy Technology Data Exchange (ETDEWEB)

    Katayama, Norihiko; Kaihara, Shoichiro; Ishii, Jun [Ishikawajima-Harima Heavy Industries Corp., Yokohama (Japan); Kajigaya, Ichiro [Ishikawajima-Harima Heavy Industries Corp., Tokyo (Japan); Totsuka, Takehiro; Miyazaki, Takashi [Ishikawajima-Harima Heavy Industries Corp., Aioi (Japan)

    1995-11-01

    Construction of a 350 MW Class PFBC (Pressurized Fluidized Bed Combustion) boiler plant is under planning in Japan. Design temperature and pressure of the vessel are maximum 350 C and 1.69 MPa, respectively. As the plate thickness of the vessel exceeds over 100 mm, high strength steel plate of good weldability and less susceptible to reheat cracking was required and developed. The steel was aimed to satisfy the tensile strength over 610 MPa at 350 C after postweld heat treatment (PWHT), with good notch toughness. The authors investigated the welding performances of the newly developed steel by using 150 mm-thick plate welded by pulsed-MAG and SAW methods. It was confirmed that the newly developed steel and its welds possess sufficient strength and toughness after PWHT, and applicable to the actual pressure vessel.

  14. Mental training, relaxation techniques and pedagogical instructions to reduce Music Performance Anxiety (MPA) in flute students

    OpenAIRE

    Carmen Viejo Llaneza; Ana Laucirica Larrinaga

    2016-01-01

    Music Performance Anxiety (MPA) is, frequently, one of the problems faced by a musical performer in his or her career. This study observes way in which stage fright affects in musicians, which is a possible factor that may later lead to anxiety in public performances and, furthermore, how we can intervene to mitigate or reduce its effects. An initial interview was conducted with four upper division students of transverse flute. This was followed by some training techniques - relaxation techni...

  15. The effect of intramuscular administration of medroxy progesterone acetate (MPA on electrocardiographic alterations of female dogs

    Directory of Open Access Journals (Sweden)

    M Neshat Gharamaleky

    2010-11-01

    Full Text Available Progestins are useful for hormonal prevention of pregnancy in humans and animals. Progestrone and medroxy progestrone acetate are used for treatment of premenopausal syndrome and decreasing complications of estrogen therapy after menopause. Prescription of progesterone in dogs is usually done to control or delay estrus. If this drug is used at anestrous it will inhibit the gonadotropin excretion beyond the basic level and it will prevent cycle from happening again in proestrus or at the beginning of estrus progesterone will prevent ovulation. Use of progesterone is not totally safe in bitches. It can cause several problems such as cystic endometrial hyperplasia and pyrometera. In this study the effects of medroxy progestrone acetat (MPA on electrocardiographic changes are evaluated. After nutritional and environmental uniformity and other evaluations, the animals were divided into two groups with six bitches in each group. MPA was used at 10 mg/kg for the first group and 20 mg/kg for the second group. An ECG was recorded from the first group in time zero. MPA was injected intramuscularly and immediately after ECG recording and the time of injection was noted. Another ECG was recorded 0.5 and 2 hours after injection. The same process was repeated for the second group. It was observed that MPA at 20 mg/kg increased the heart rate and consequently PR interval and RR interval were decreased significantly in normal range. Also administration of drug at 10 mg/kg decreased the heart rate and increased PR interval, QT interval and RR interval significantly in normal range. It is probable that these observations are the result of MPAs dose dependent vasodilatory nature that induces the heart to exhibit compensative reactions such as increasing heart rate.

  16. Thermal properties of Permian Basin evaporites to 493 K temperature and 30 MPa confining pressure

    International Nuclear Information System (INIS)

    Durham, W.B.; Heard, H.C.; Boro, C.O.; Keller, K.T.; Ralph, W.E.; Trimmer, D.A.

    1987-03-01

    Laboratory measurements of the thermal conductivity and diffusivity of four rock salts, two anhydrites, and two dolomites bordering Cycle 4 and Cycle 5 bedded salt formations in the Permian Basin in Deaf Smith County, Texas, were made in conditions ranging from 303 to 473 K in temperature and 0.1 to 31.0 MPa in hydrostatic confining pressure. Within the +-5% measurement resolution neither conductivity nor diffusivity showed a dependence upon pressure in any of the rocks. Conductivity and diffusivity in all rocks had a negative temperature dependence. For the Cycle 4 salt samples, conductivity fell from 5.5 to 3.75 W/m . K, and diffusivity fell from about 2.7 to 1.7 x 10 -6 m 2 /s. One Cycle 5 salt was a single crystal with anomalous results, but the other had a low conductivity with very weak temperature dependence and a high diffusivity. In the nonsalts, conductivity and diffusivity decreased 10 to 20% over the temperature range explored. In measurements of the coefficient of thermal linear expansion for Cycle 5 salt and nonsalts, the coefficient typically varied from about 12 x 10 -6 K -1 at P = 3.0 MPa to 4 x 10 -6 K -1 at P = 30 MPa for both nonsalt rocks. In anhydrite, it decreased with increasing temperature. In dolomite, the coefficient increased at roughly the same rate. Expansion of the salt ranged from 33 to 38 x 10 -6 K -1 and was independent of pressure and temperature

  17. Hydrogen embrittlement property of a 1700-MPa-class ultrahigh-strength tempered martensitic steel

    Energy Technology Data Exchange (ETDEWEB)

    Li Songjie; Zhang Boping [School of Materials Science and Engineering, University of Science and Technology Beijing, No. 30 Xueyuan Road, Hidian Zone, Beijing 100083 (China); Akiyama, Eiji; Yuuji, Kimura; Tsuzaki, Kaneaki [Structural Metals Center, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Uno, Nobuyoshi, E-mail: AKIYAMA.Eiji@nims.go.j [Nippon Steel and Sumikin Metal Products Co, Ltd, SA Bldg., 17-12 Kiba 2-chome, Koto-ku, Tokyo (Japan)

    2010-04-15

    The hydrogen embrittlement property of a prototype 1700-MPa-class ultrahigh-strength steel (NIMS17) containing hydrogen traps was evaluated using a slow strain rate test (SSRT) after cathodic hydrogen precharging, cyclic corrosion test (CCT) and atmospheric exposure. The hydrogen content in a fractured specimen was measured after SSRT by thermal desorption spectroscopy (TDS). The relationship between fracture stress and hydrogen content for the hydrogen-precharged specimens showed that the fracture stress of NIMS17 steel was higher, at a given hydrogen content, than that of conventional AISI 4135 steels with tensile strengths of 1300 and 1500 MPa. This suggests better resistance of NIMS17 steel to hydrogen embrittlement. However, hydrogen uptake to NIMS17 steel under CCT and atmospheric exposure decreased the fracture stress. This is because of the stronger hydrogen uptake to the steel containing hydrogen traps than to the AISI 4135 steels. Although NIMS17 steel has a higher strength level than AISI 4135 steel with a tensile strength of 1500 MPa, the decrease in fracture stress is similar between these steels.

  18. Hydrogen embrittlement property of a 1700-MPa-class ultrahigh-strength tempered martensitic steel

    Directory of Open Access Journals (Sweden)

    Songjie Li, Eiji Akiyama, Kimura Yuuji, Kaneaki Tsuzaki, Nobuyoshi Uno and Boping Zhang

    2010-01-01

    Full Text Available The hydrogen embrittlement property of a prototype 1700-MPa-class ultrahigh-strength steel (NIMS17 containing hydrogen traps was evaluated using a slow strain rate test (SSRT after cathodic hydrogen precharging, cyclic corrosion test (CCT and atmospheric exposure. The hydrogen content in a fractured specimen was measured after SSRT by thermal desorption spectroscopy (TDS. The relationship between fracture stress and hydrogen content for the hydrogen-precharged specimens showed that the fracture stress of NIMS17 steel was higher, at a given hydrogen content, than that of conventional AISI 4135 steels with tensile strengths of 1300 and 1500 MPa. This suggests better resistance of NIMS17 steel to hydrogen embrittlement. However, hydrogen uptake to NIMS17 steel under CCT and atmospheric exposure decreased the fracture stress. This is because of the stronger hydrogen uptake to the steel containing hydrogen traps than to the AISI 4135 steels. Although NIMS17 steel has a higher strength level than AISI 4135 steel with a tensile strength of 1500 MPa, the decrease in fracture stress is similar between these steels.

  19. Hydrogen embrittlement property of a 1700-MPa-class ultrahigh-strength tempered martensitic steel

    International Nuclear Information System (INIS)

    Li Songjie; Zhang Boping; Akiyama, Eiji; Yuuji, Kimura; Tsuzaki, Kaneaki; Uno, Nobuyoshi

    2010-01-01

    The hydrogen embrittlement property of a prototype 1700-MPa-class ultrahigh-strength steel (NIMS17) containing hydrogen traps was evaluated using a slow strain rate test (SSRT) after cathodic hydrogen precharging, cyclic corrosion test (CCT) and atmospheric exposure. The hydrogen content in a fractured specimen was measured after SSRT by thermal desorption spectroscopy (TDS). The relationship between fracture stress and hydrogen content for the hydrogen-precharged specimens showed that the fracture stress of NIMS17 steel was higher, at a given hydrogen content, than that of conventional AISI 4135 steels with tensile strengths of 1300 and 1500 MPa. This suggests better resistance of NIMS17 steel to hydrogen embrittlement. However, hydrogen uptake to NIMS17 steel under CCT and atmospheric exposure decreased the fracture stress. This is because of the stronger hydrogen uptake to the steel containing hydrogen traps than to the AISI 4135 steels. Although NIMS17 steel has a higher strength level than AISI 4135 steel with a tensile strength of 1500 MPa, the decrease in fracture stress is similar between these steels.

  20. The Support of MPA (Marine Protected Area) in Coral Triangle Area: Evidence from Kei Islands, Indonesia

    Science.gov (United States)

    Hamid, Syahibul K.; Teniwut, Wellem A.; Teniwut, Roberto M. K.; Rahantoknam, Meyske A.; Hasyim, Cawalinya L.; Hungan, Marselus

    2017-10-01

    Kei Islands located inside the coral triangle. Therefore, the biodiversity level on the sea in this area is considered high. United nation has proposed for water that included in the coral triangle has to apply marine protected area (MPA) to preserve the area. The main problem is most of the community especially in Kei Islands have depended on the sea as their sources of the economy even fisheries commodity like fish play a large part on the inflation rate and other prosperity indicators likes school and housing. Also, Kei Islands practice on form local wisdom for owning areal of the sea which calls “petuanan laut” by certain of villages or group of villages in one area. This study aimed to map the cluster of catching fisheries area based on the quantity of fish supply on a local market in Kei Islands and measure each cluster on their support and perspective on Marine Protected Area (MPA). We conducted a focus group discussion and collecting additional data by questionnaires with descriptive and quantitative analysis with logistic regression. The implication of this study can provide a clear view of coastal communities view on MPA program also to identify an area that has marine resources, human resources, and equipment to provide government an empirical view on catching fisheries in Kei Islands to issued better policy to develop fishing industry in Kei Islands.

  1. Thermal properties of Permian Basin evaporites to 493 K and 30 MPa confining pressure

    International Nuclear Information System (INIS)

    Durham, W.B.; Heard, H.C.; Boro, C.O.; Keller, K.T.; Ralph, W.E.; Trimmer, D.A.

    1987-01-01

    Laboratory measurements have been made of the thermal conductivity and diffusivity of four rock salts, two anhydrites, and two dolomites bordering the Cycle 4 and Cycle 5 bedded salt formations in the Permian Basin in Deaf Smith County, Texas. Measurement conditions ranged from 303 to 473 K in temperature, and 0.1 to 31.0 MPa in hydrostatic confining pressure. Within the +-5% measurement resolution neither conductivity nor diffusivity showed a dependence upon pressure in any of the rocks. Conductivity and diffusivity in all rocks had a negative temperature dependence. For the two Cycle 4 salt samples, conductivity over the temperature range explored fell from 5.5 to 3.75 W/m.K, and diffusivity fell from about 2.7 to 1.7 x 10 -6 m 2 /s. One of the Cycle 5 salts was a single crystal which had anomalous results, but the other had a low conductivity, about 3.4 W/m.K, with very weak temperature dependence, and a high diffusivity, 3.8 to 2.5 x 10 -6 m 2 /s over the temperature range. In the nonsalts, conductivity and diffusivity decreased 10 to 20% over the temperature range explored, which was 308 -6 m 2 /s for the anhydrites and 1.4 x 10 -6 m 2 /s for both the dolomites. The coefficient of thermal linear expansion was measured for the Cycle 5 salt and nonsalts over 308 -6 K -1 at P = 3.0 MPa to 4 x 10 -6 K -1 at P = 30 MPa for both nonsalt rocks. In anhydrite, it decreased with increasing temperature at a rate of roughly 5 x 10 -8 K -2 at all pressures. In dolomite, the coefficient increased at roughly the same rate. Expansion of the salt ranged from 33 to 38 x 10 -6 K -1 and was independent of pressure and temperature

  2. Variations of microstructure and properties of 690 MPa grade low carbon bainitic steel after tempering

    Energy Technology Data Exchange (ETDEWEB)

    Feng, Rui [Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, Shandong University, Jinan Shandong 250061 (China); School of Materials Science and Engineering, Shandong University, Jinan Shandong 250061 (China); Li, Shengli, E-mail: lishengli@sdu.edu.cn [Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, Shandong University, Jinan Shandong 250061 (China); School of Materials Science and Engineering, Shandong University, Jinan Shandong 250061 (China); Li, Zhenshun; Tian, Lei [Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, Shandong University, Jinan Shandong 250061 (China); School of Materials Science and Engineering, Shandong University, Jinan Shandong 250061 (China)

    2012-12-15

    The variations of microstructure, mechanical properties and electrical resistivity of 690 MPa grade low carbon bainitic steel tempered at different temperatures were investigated with Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM) and double-arm Bridge. The results show that the appearance of granular bainite, decomposition of retained austenite, variations of dislocation density and solid solution of microalloying elements are the main reasons for variations of mechanical properties and electrical resistivity. Electrical resistivity reflects the solution content of microalloying elements and variations of dislocation density, which can be used as a fast and effective way to analyze the microstructure of materials.

  3. Modifications to a Laboratory-Scale Confined Laser Ignition Chamber for Pressure Measurements to 70 MPa

    Science.gov (United States)

    2017-09-01

    Include area code ) (410) 306-0760 Standard Form 298 (Rev. 8/98) Prescribed by ANSI Std. Z39.18 Approved for public release; distribution is...achieved was 61.8 MPa ............................................... 10 Fig. 12 Lead window seat punched from 1.6-mm-thick lead sheet (left), and...1.6-mm-thick lead sheet . Figure 12 shows 2 of these seats, unused and used. A center hole to clear the laser port is first made using a 7-mm punch

  4. Mifepristone inhibits MPA-and FGF2-induced mammary tumor growth but not FGF2-induced mammary hyperplasia

    Directory of Open Access Journals (Sweden)

    Juan P. Cerliani

    2010-12-01

    Full Text Available We have previously demonstrated a crosstalk between fibroblast growth factor 2 (FGF2 and progestins inducing experimental breast cancer growth. The aim of the present study was to compare the effects of FGF2 and of medroxyprogesterone acetate (MPA on the mouse mammary glands and to investigate whether the antiprogestin RU486 was able to reverse the MPA- or FGF2-induced effects on both, mammary gland and tumor growth. We demonstrate that FGF2 administered locally induced an intraductal hyperplasia that was not reverted by RU486, suggesting that FGF2-induced effects are progesterone receptor (PR-independent. However, MPA-induced paraductal hyperplasia was reverted by RU486 and a partial agonistic effect was observed in RU486-treated glands. Using C4-HD tumors which only grow in the presence of MPA, we showed that FGF2 administered intratumorally was able to stimulate tumor growth as MPA. The histology of FGF2-treated tumors showed different degrees of gland differentiation. RU486 inhibited both, MPA or FGF2 induced tumor growth. However, only complete regression was observed in MPA-treated tumors. Our results support the hypothesis that stromal FGF2 activates PR inducing hormone independent tumor growth.

  5. Thermal properties of Avery Island salt to 5730K and 50-MPa confining pressure

    International Nuclear Information System (INIS)

    Durham, W.B.; Abey, A.E.

    1981-01-01

    Thermal conductivity, thermal diffusivity, and thermal linear expansion were measured on two samples of Avery Island rock salt up to simultaneous temperatures and pressures of 573 0 K and 50 MPa. Thermal conductivity at room temperature measured 6.3 +- 0.6 W/mK and decreased monotonically to 3.3 +- 0.4 W/mK at 573 0 K. Thermal diffusivity decreased from 3.0 +- 0.8 x 10 -6 m 2 /s at room temperature to 1.4 +- 0.5 x 10 -6 m 2 /s at 573 0 K. Thermal linear expansivity increased from 4.8 +- 0.3 x 10 -5 K -1 at room temperature to 5.6 +- 0.3 x 10 -5 K -1 at 573 0 K. The thermal properties showed no measurable (+-5%) dependence on confining pressure from 0 to 50 MPa for any temperature tested. The thermal conductivity values were not distinguishable (+-5%) from intrinsic (single crystal) values measured by others. Diffusivity fell about 20% below intrinsic values, and linear expansivity about 20% above intrinsic values. Thermal conductivity values for Avery Island salt measured recently by Morgan are as much as 50% lower than values measured here and were probably strongly affected by sample handling prior to measurement. The pressure independence of the thermal properties measured in our study suggests that thermally-induced microfracturing is nearly nonexistent. This lack of thermal cracking is consistent with the high (cubic) symmetry of halite

  6. Thermal properties of rock salt and quartz monzonite to 5730K and 50-MPa confining pressure

    International Nuclear Information System (INIS)

    Durham, W.B.; Abey, A.E.

    1981-01-01

    Measurements of thermal conductivity, thermal diffusivity, and thermal linear expansion have been made on two rock types, a rock salt and a quartz monzonite, at temperatures from 300 to 573 0 K and confining pressures from 10 to 50 MPa. The samples were taken from deep rock formations under consideration as possible sites for a nuclear waste repository - the rock salt from a domal salt formation at Avery Island, Louisiana, and the quartz monzonite from the Climax Stock, Nevada Test Site, Nevada. The testing temperature and pressures are meant to bracket conditions expected in the repository. In both rock types, the thermal properties show a strong dependence upon temperature and a weak or non-dependence upon confining pressure. Thermal conductivity and diffusivity both decrease with increasing temperature in approximately linear fashion for samples which have not been previously heated. At 50 MPa in both rocks this decrease closely matches the measured or expected intrinsic (crack-free) behavior of the material. Preliminary indications from the quartz monzonite suggest that conductivity and diffusivity at low pressure and temperature may decrease as a result of heat treatment above 400 0 K

  7. Immunosuppressant MPA Modulates Tight Junction through Epigenetic Activation of MLCK/MLC-2 Pathway via p38MAPK

    Directory of Open Access Journals (Sweden)

    Niamat Khan

    2015-12-01

    Full Text Available Background: Mycophenolic acid (MPA is an important immunosuppressive drug (ISD prescribed to prevent graft rejection in the organ transplanted patients, however, its use is also associated with adverse side effects like sporadic gastrointestinal (GI disturbances. Recently, we reported the MPA induced tight junctions (TJs deregulation which involves MLCK/MLC-2 pathway. Here, we investigated the global histone acetylation as well as gene-specific chromatin signature of several genes associated with TJs regulation in Caco-2 cells after MPA treatment.Results: The epigenetic analysis shows that MPA treatment increases the global histone acetylation levels as well as the enrichment for transcriptional active histone modification mark (H3K4me3 at promoter regions of p38MAPK, ATF-2, MLCK, and MLC-2. In contrast, the promoter region of occludin was enriched for transcriptional repressive histone modification mark (H3K27me3 after MPA treatment. In line with the chromatin status, MPA treatment increased the expression of p38MAPK, ATF-2, MLCK, and MLC-2 both at transcriptional and translational level, while occludin expression was negatively influenced. Interestingly, the MPA induced gene expression changes and functional properties of Caco-2 cells could be blocked by the inhibition of p38MAPK using a chemical inhibitor (SB203580.Conclusions: Collectively, our results highlight that MPA disrupts the structure of TJs via p38MAPK-dependent activation of MLCK/MLC-2 pathway that results in decreased integrity of Caco-2 monolayer. These results led us to suggest that p38MAPK-mediated lose integrity of epithelial monolayer could be the possible cause of GI disturbance (barrier dysfunction in the intestine, leading to leaky style diarrhea observed in the organ-transplanted patients treated with MPA.

  8. Influence of superplasticizer on microstructure of a 40 MPa strength concrete

    International Nuclear Information System (INIS)

    Teixeira, Sandra M.F.; Menezes, Raquel Maria R.O.; Figueiredo, Roberto B.; Aguilar, Maria Teresa P.; Franca, Fabricio Carlos; Bezerra, Augusto Cesar da S.

    2016-01-01

    The self compacting concrete has high fluidity and deformability. Studies analyze its performance through compressive strength, mortar content and / or water cement factor, which does not allow the evaluation of superplasticante influence the microstructure of these concretes. In this work, we evaluated the influence of superplasticizer comparing the phases present in a self-compacting concrete 40 MPa and at a same conventional compressive strength, same water / cement and mortar content. Therefore, scanning techniques were employed by electron microscope low vacuum using backscattered electrons and thermal analysis. The observed results show no significant differences in the microstructure of the two composites, ie the superplasticizer does not alter the microstructure of the self-compacting concrete. However, thermal analysis indicates that the present self-compacting concrete greater calcium hydroxide content which may suggest a lower content of such dry cement concrete. (author)

  9. Validation for a new apparatus measuring water vapour enhancement factors up to 6 MPa

    International Nuclear Information System (INIS)

    Sairanen, H; Heinonen, M

    2014-01-01

    High accuracy dew-point measurements require a water vapour enhancement factor to correct the effects of pressure drop in a sampling line. The enhancement factor is also needed when a humidity quantity value is converted to another. In this paper a new apparatus for traceable measurements of the enhancement factor is presented along with the results of validation measurements with air and methane. The apparatus is designed for dew-point temperatures from −50 to +15 °C and the pressure range from atmospheric pressure up to 6 MPa. The performance of the apparatus was investigated by comparing measurement results to the literature data for air and the data calculated from published thermodynamic measurement results for methane. It is shown that the experimental results agree with the reference data within the estimated uncertainties. (paper)

  10. Granite - water interactions at 100 deg C, 50 MPa: an experimental study

    International Nuclear Information System (INIS)

    Savage, D.

    1984-01-01

    A monzogranite was reacted with water in hydrothermal solution equipment at 100 deg C, 50 MPa for 203 days, during which time six fluid samples were extracted at run temperature and pressure for chemical analysis. Fluid samples were analysed using ICP, INAA and standard wet chemical techniques and data are presented for 18 chemical species. Solids were examined using XRD and SEM. The high temperature speciation of the fluid phase chemistry was investigated using the geochemical software package EQ3/6. The evolution of the fluid phase chemistry is discussed in terms of mineral-fluid equilibria and the kinetics of mineral dissolution and precipitation reactions. The implications of these results to the modelling of the near-field geochemical environment of a high-level radioactive waste repository in granitic rock are discussed. (author)

  11. Density and Compressibility of Multicomponent n-Alkane Mixtures up to 463 K and 140 MPa

    DEFF Research Database (Denmark)

    Regueira, Teresa; Glykioti, Maria-Lito; Stenby, Erling Halfdan

    2017-01-01

    Density measurements of two ternary alkane mixtures (methane/n-butane/n-decane and methane/n-butane/n-dodecane) and two multicomponent mixtures composed of methane/n-butane/n-octane/n-dodecane/n-hexadecane/n-eicosane were performed in the temperature range from (278.15 to 463.15) K and pressures ......–Redlich–Kwong (SRK), Peng–Robinson (PR), Perturbed Chain Statistical Associating Fluid Theory (PC-SAFT), and Soave-Benedict-Webb-Rubin (Soave-BWR) were used for predicting the experimental density values as well as the excess volumes....... to 140 MPa. The isothermal compressibility values of these mixtures were obtained by differentiation from a Tait-type fitting of experimental densities as a function of temperature and pressure. Excess volume of the studied mixtures was also determined. Four different equations of state, that is, Soave...

  12. Equations of state for enriched uranium and uranium alloy to 3500 MPa

    International Nuclear Information System (INIS)

    Bai Chaomao; Hai Yuying; Liu Jenlong; Li Zhenrong

    1990-04-01

    The volume compressions of 6 kinds of cast materials including enriched uranium, poor uranium, U-0.57 wt% Ti, U-0.33 wt% Nb, U-2.85 wt% Nb and U-7.5 wt% Nb-3.3 wt% Zr have been determined by monitoring piston displacements in a piston cylinder apparatus with double strengthening rings to 3500 MPa at room temperature. The dilation of the cylinder vessel and the press deformation were corrected by some experiments. The calculational data free from using the standard sample closed with used standard sample. The volume compressions of enriched uranium and poor uranium are nearly coincident. Pure uranium is more compressible than uranium alloys. These values of enriched uranium are in close agreement with values of Bridgman's pure uranium. The fitting coefficients of Bridgman's polynomial and Anderson's equation of state and isothermal bulk modules for the above materials are given

  13. Photoinduced interaction between MPA capped CdTe QDs and certain anthraquinone dyes

    Energy Technology Data Exchange (ETDEWEB)

    Jagadeeswari, S.; Asha Jhonsi, M.; Kathiravan, A. [School of Chemistry, Bharathidasan University, Tiruchirappalli 620 024, Tamil Nadu (India); Renganathan, R., E-mail: rrengas@gmail.co [School of Chemistry, Bharathidasan University, Tiruchirappalli 620 024, Tamil Nadu (India)

    2011-04-15

    Photoinduced interaction of mercapto propionic acid (MPA) capped CdTe quantum dots (QDs) with certain anthraquinone dyes namely alizarin, alizarin red S, acid blue 129 and uniblue has been studied by steady state and time resolved fluorescence measurements. Addition of anthraquinone dyes to CdTe QDs results in the reduction of electron hole recombination has been observed (i.e., fluorescence quenching). The Stern-Volmer constant (K{sub SV}), quenching rate constant (k{sub q}) and association constants (K) were obtained from fluorescence quenching data. The interaction of anthraquinone dyes with QDs occurs through static quenching was confirmed by unaltered fluorescence lifetime. The occurrence of electron transfer quenching mechanism has been proved by the negative free energy change ({Delta}G{sub et}) obtained as per the Rehm-Weller equation.

  14. Thermodynamic functions of hydration of hydrocarbons at 298.15 K and 0.1 MPa

    Science.gov (United States)

    Plyasunov, Andrey V.; Shock, Everett L.

    2000-02-01

    An extensive compilation of experimental data yielding the infinite dilution partial molar Gibbs energy of hydration Δ hGO, enthalpy of hydration Δ hHO, heat capacity of hydration Δ hCpO, and volume V2O, at the reference temperature and pressure, 298.15 K and 0.1 MPa, is presented for hydrocarbons (excluding polyaromatic compounds) and monohydric alcohols. These results are used in a least-squares procedure to determine the numerical values of the corresponding properties of the selected functional groups. The simple first order group contribution method, which in general ignores nearest-neighbors and steric hindrance effects, was chosen to represent the compiled data. Following the precedent established by Cabani et al. (1981), the following groups are considered: CH 3, CH 2, CH, C for saturated hydrocarbons; c-CH 2, c-CH, c-C for cyclic saturated hydrocarbons; CH ar, C ar for aromatic hydrocarbons (containing the benzene ring); C=C, C≡C for double and triple bonds in linear hydrocarbons, respectively; c-C=C for the double bond in cyclic hydrocarbons; H for a hydrogen atom attached to the double bond (both in linear and cyclic hydrocarbons) or triple bond; and OH for the hydroxyl functional group. In addition it was found necessary to include the "pseudo"-group I(C-C) to account for the specific interactions of the neighboring hydrocarbon groups attached to the benzene or cyclic ring (in the latter case only for cis-isomers). Results of this study, the numerical values of the group contributions, will allow in most cases reasonably accurate estimations of Δ hGO, Δ hHO, Δ hCpO, and V2O at 298.15 K, 0.1 MPa for many hydrocarbons involved in geochemical and environmental processes.

  15. Validation of a dew-point generator for pressures up to 6 MPa using nitrogen and air

    Science.gov (United States)

    Bosma, R.; Mutter, D.; Peruzzi, A.

    2012-08-01

    A new primary humidity standard was developed at VSL that, in addition to ordinary operation with air and nitrogen at atmospheric pressure, can be operated with other carrier gases such as natural gas at pressures up to 6 MPa and SF6 at pressures up to 1 MPa. The temperature range of the standard is from -80 °C to +20 °C. In this paper, we report the validation of the new primary dew-point generator in the temperature range -41 °C to +5 °C and the pressure range 0.1 MPa to 6 MPa using nitrogen and air. For the validation the flow through the dew-point generator was varied up to 10 l min-1 (at 23 °C and 1013 hPa) and the dew point of the gas entering the generator was varied up to 15 °C above the dew point exiting the generator. The validation results showed that the new generator, over the tested temperature and pressure range, can be used with a standard uncertainty of 0.02 °C frost/dew point. The measurements used for the validation at -41 °C and -20 °C with nitrogen and at +5 °C with air were also used to calculate the enhancement factor at pressures up to 6 MPa. For +5 °C the differences between the measured and literature values were compatible with the respective uncertainties. For -41 °C and -20 °C they were compatible only up to 3 MPa. At 6 MPa a discrepancy was observed.

  16. Selected Peer-Reviewed Articles from The International Meeting on Developments in Materials, Processes and Applications of Nanotechnology (MPA 2008), UK

    NARCIS (Netherlands)

    Ali, Nasar; De Hosson, Jeff. Th. M.; Ahmed, W.

    The International Meeting on Developments in Materials, Processes and Applications of Nanotechnology (MPA 2008) held at Robinson College, University of Cambridge, UK was the second event of the MPA conference series. The first MPA-2007, held at the University of Ulster, UK officially launched the

  17. Effects of Ar and He on Microstructures and Properties of Laser Welded 800MPa TRIP Steel

    Directory of Open Access Journals (Sweden)

    Wang Wen-Quan

    2018-01-01

    Full Text Available Fiber laser welding of cold rolled TRIP steel (transformation Induced Plasticity steel sheet with tensile strength of 820MPa and thickness of 1.4mm was carried out using shielding gases Ar and He, respectively. For the same laser power and welding speed, the effects of different shielding gases on penetration and bead section morphologies were investigated. The microstructures and properties of the TRIP steel joints were also studied. The investigation showed that higher penetration and lower porosity could be obtained under shielding gas He using the same laser power and welding speed. The microstructures of the TRIP joint mainly included martensite and retained austenite. But the joint microhardness and tensile strength were higher under the shielding gas He. The tensile strength of the welded joint perpendicular to the weld line was equal to that of the base metal. But the tensile strength of the joint parallel with the weld line was higher than that of the base metal. The plasticity and formability of the welded joint were impaired due to the formation of martensite in the weld metal.

  18. Acquisition and evaluation of thermodynamic data for bieberite-moorhouseite equilibria at 0.1 MPa

    Science.gov (United States)

    Chou, I.-Ming; Seal, R.R.

    2005-01-01

    Published estimates for the equilibrium relative humidity (RH) at 25 deg;C for the reaction: bieberite (CoSO4??7H2O) = moorhouseite (CoSO4??6H2O) + H2O, range from 69.8 to 74.5%. To evaluate these data, the humidity-buffer technique was used to determine equilibrium constants for this reaction between 14 and 43 ??C at 0.1 MPa. Reversals along five humidity-buffer curves yield In K = 18.03-6509.43/T, where K is the equilibrium constant, and T is temperature in K. The derived standard Gibbs free energy of reaction is 9.43 kJ/mol, which agrees well with several previously reported values based on vapor-pressure measurements. It also agrees well with values calculated from the data derived mostly from calorimetric measurements. Previous studies indicated that the temperature of the invariant point for the assemblage bieberite-moorhouseite-aqueous solution-vapor is near 44.7 ??C, and our extrapolated data predict 91.1% RH at this temperature; the predicted position for the invariant point is in excellent agreement with those reported previously.

  19. Acquisition and evaluation of thermodynamic data for morenosite-retgersite equilibria at 0.1 MPa

    Science.gov (United States)

    Chou, I.-Ming; Seal, R.R.

    2003-01-01

    Metal-sulfate salts in mine drainage environments commonly occur as solid solutions containing Fe, Cu, Mg, Zn, Al, Mn, Ni, Co, Cd, and other elements. Thermodynamic data for some of the end-member salts containing Fe, Cu, Zn, and Mg have been collected and evaluated previously, and the present study extends to the system containing Ni. Morenosite (NiSO4-7H2O)-retgersite (NiSO4-6H2O) equilibria were determined along five humidity buffer curves at 0.1 MPa and between 5 and 22??C. Reversals along these humidity-buffer curves yield In K = 17.58-6303.35/T, where K is the equilibrium constant, and T is temperature in K. The derived standard Gibbs free energy of reaction is 8.84 kJ/mol, which agrees very well with the values of 8.90, 8.83, and 8.85 kJ/mol based on the vapor pressure measurements of Schumb (1923), Bonnell and Burridge (1935), and Stout et al. (1966). respectively. This value also agrees reasonably well with the values of 8.65 and 9.56 kJ/mol calculated from the data compiled by Wagman et al. (1982) and DeKock (1982), respectively. The temperature-humidity relationships defined by this study for dehydration equilibria between morenosite and retgersite explain the more common occurrence of retgersite relative to morenosite in nature.

  20. A Calibration Facility for Dew Point in Air up to 1 MPa

    Science.gov (United States)

    Carroll, P. A.; Bell, S. A.; Stevens, M.

    2015-12-01

    The provision of primary dew-point standards for humidified air and nitrogen at atmospheric pressure is well established, and measurement traceability to these standards provides confidence in a vast number of air humidity measurements. However, hygrometers are used industrially at a wide range of pressures. Both the performance of hygrometers and the properties of humid gases are known to vary with gas pressure. The pressure-dependence of gas non-ideality for air-water mixtures (water-vapor enhancement factor) is well enough known at moderate pressures, but there remains a need to characterize hygrometers at the pressure of use. To address this, a humidity calibration capability of wider scope is under development at the UK National Physical Laboratory (NPL). As an initial stage in the development of this capability, a humidity standard generating air or nitrogen in the dew-point range from -60° C to +10° C, at pressures up to 1 MPa (10 bar) has been validated for the calibration of hygrometers. The expanded uncertainty of the dew-point generator in this range with a coverage factor k= 2 is ± 0.07° C.

  1. Research activities of MPA, Stuttgart University, for enhanced safety and reliability of components under complex load; Forschungsaktivitaeten der MPA Universitaet Stuttgart zu Erhoehung der Sicherheit und Zuverlaessigkeit komplex beanspruchter Bauteile

    Energy Technology Data Exchange (ETDEWEB)

    Herter, K.H.; Roos, E.; Schuler, X.; Maile, K. [Materialpruefungsanstalt (MPA), Univ. Stuttgart, Stuttgart (Germany)

    2004-07-01

    MPA research activities focus on fracture prevention and on the development of a generally applicable method of component integrity testing which, independent of the safety relevance of the components involved, is also part of ageing management. (orig.) [German] Die Forschungsaktivitaeten an der MPA im Hinblick auf die Erhoehung der Sicherheit und Zuverlaessigkeit komplex beanspruchter Bauteile orientieren sich an den Grundgedanken des Basissicherheitskonzepts (Prinzip des Bruchausschlusses). Zielsetzung war dabei die Entwicklung eines allgemein anwendbaren Nachweisverfahrens zur Komponentenintegritaet, das, abhaengig von der sicherheitstechnischen Relevanz der zu betrachtenden Komponenten, auch Bestandteil des Alterungsmanagements ist. (orig.)

  2. Spectroscopic and thermodynamic properties of molecular hydrogen dissolved in water at pressures up to 200 MPa

    Science.gov (United States)

    Borysow, Jacek; del Rosso, Leonardo; Celli, Milva; Moraldi, Massimo; Ulivi, Lorenzo

    2014-04-01

    We have measured the Raman Q-branch of hydrogen in a solution with water at a temperature of about 280 K and at pressures from 20 to 200 MPa. From a least-mean-square fitting analysis of the broad Raman Q-branch, we isolated the contributions from the four lowest individual roto-vibrational lines. The vibrational lines were narrower than the pure rotational Raman lines of hydrogen dissolved in water measured previously, but significantly larger than in the gas. The separations between these lines were found to be significantly smaller than in gaseous hydrogen and their widths were slightly increasing with pressure. The lines were narrowing with increasing rotational quantum number. The Raman frequencies of all roto-vibrational lines were approaching the values of gas phase hydrogen with increasing pressure. Additionally, from the comparison of the integrated intensity signal of Q-branch of hydrogen to the integrated Raman signal of the water bending mode, we have obtained the concentration of hydrogen in a solution with water along the 280 K isotherm. Hydrogen solubility increases slowly with pressure, and no deviation from a smooth behaviour was observed, even reaching thermodynamic conditions very close to the transition to the stable hydrogen hydrate. The analysis of the relative hydrogen concentration in solution on the basis of a simple thermodynamic model has allowed us to obtain the molar volume for the hydrogen gas/water solution. Interestingly, the volume relative to one hydrogen molecule in solution does not decrease with pressure and, at high pressure, is larger than the volume pertinent to one molecule of water. This is in favour of the theory of hydrophobic solvation, for which a larger and more stable structure of the water molecules is expected around a solute molecule.

  3. Determination of Coefficient of Thermal Expansion (CTE) of 20MPa Mass Concrete Using Granite Aggregate

    Science.gov (United States)

    Chee Siang, GO

    2017-07-01

    Experimental test was carried out to determine the coefficient of thermal expansion (CTE) value of 20MPa mass concrete using granite aggregate. The CTE value was established using procedure proposed by Kada et al. 2002 in determining the magnitude of early-ages CTE through laboratory test which is a rather accurate way by eliminating any possible superimposed effect of others early-age thermal deformation shrinkages such as autogenous, carbonation, plastic and drying shrinkage. This was done by submitting granite concrete block samples instrumented with ST4 vibrating wire extensometers to thermal shocks. The response of the concrete samples to this shock results in a nearly instantaneous deformation, which are measured by the sensor. These deformations, as well as the temperature signal, are used to calculate the CTE. By repeating heat cycles, the variation in the early-ages of concrete CTE over time was monitored and assessed for a period of upto 7 days. The developed CTE value facilitating the verification and validation of actual maximum permissible critical temperature differential limit (rather than arbitrarily follow published value) of cracking potential. For thick sections, internal restraint is dominant and this is governed by differentials mainly. Of the required physical properties for thermal modelling, CTE is of paramount importance that with given appropriate internal restraint factor the condition of cracking due to internal restraint is governs by equation, ΔTmax= 3.663ɛctu / αc. Thus, it can be appreciated that an increase in CTE will lower the maximum allowable differential for cracking avoidance in mass concrete while an increase of tensile strain capacity will increase the maximum allowable temperature differential.

  4. 27. MPA-Seminar - Safety and reliability in energy technology. Vol. 2: Papers 27-45; 27. MPA-Seminar - Sicherheit und Verfuegbarkeit in der Energietechnik. Bd. 2: Vortraege 27-45

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    The proceedings of the 27th MPA Seminar on 'Safety and Reliability in Energy Technology' were issued in two volumes. The main topics of the second volume are: 1. Material behaviour in the creep regime; 2. Fracture machanics; 3. Reliability analysis and 4. Failure analysis.

  5. Challenges of the Administrative Consultation Wiki Research Project as a Learning and Competences Development Method for MPA Students

    Science.gov (United States)

    Kovac, Polonca; Stare, Janez

    2015-01-01

    Administrative Consultation Wiki (ACW) is a project run under the auspices of the Faculty of Administration and the Ministry of Public Administration in Slovenia since 2009. A crucial component thereof is the involvement of students of Master of Public Administration (MPA) degree programs to offer them an opportunity to develop competences in…

  6. Measurement and calculation of gas compressibility factor for condensate gas and natural gas under pressure up to 116 MPa

    International Nuclear Information System (INIS)

    Yan, Ke-Le; Liu, Huang; Sun, Chang-Yu; Ma, Qing-Lan; Chen, Guang-Jin; Shen, De-Ji; Xiao, Xiang-Jiao; Wang, Hai-Ying

    2013-01-01

    Highlights: • Volumetric properties of two reservoir fluid samples were measured with pressure up to 116 MPa. • Dew point pressures at four temperatures for condensate gas sample are obtained. • Correlations and thermodynamic model for describing gas compressibility factor under high pressure were compared. • The thermodynamic model recommended is most suitable for fluids produced from reservoirs with a wide pressure range. -- Abstract: The volumetric properties of two reservoir fluid samples collected from one condensate gas well and one natural gas well were measured under four groups of temperatures, respectively, with pressure up to 116 MPa. For the two samples examined, the experimental results show that the gas compressibility factor increases with the increase of pressure. But the influence of the temperature is related to the range of the experimental pressure. It approximately decreases with the increase of temperature when the pressure is larger than (45 to 50) MPa, while there is the opposite trend when the pressure is lower than (45 to 50) MPa. The dew point pressure was also determined for the condensate gas sample, which decreases with the increase of temperature. The capabilities of four empirical correlations and a thermodynamic model based on equation of state for describing gas compressibility factor of reservoir fluids under high pressure were investigated. The comparison results show that the thermodynamic model recommended is the most suitable for fluids whatever produced from high-pressure reservoirs or conventional mild-pressure reservoirs

  7. Preservation of rat hearts in subfreezing temperature isochoric conditions to - 8 °C and 78 MPa.

    Science.gov (United States)

    Wan, Lili; Powell-Palm, Matthew J; Lee, Charles; Gupta, Anshal; Weegman, Bradley P; Clemens, Mark G; Rubinsky, Boris

    2018-02-12

    Isochoric (constant volume) preservation at subfreezing temperatures is being investigated as a novel method for preserving cells and organs. This study is a first initial effort to evaluate the efficacy of this method for heart preservation, and to provide a preliminary outline of appropriate preservation parameters. To establish a baseline for further studies, rat hearts were preserved in a University of Wisconsin (UW) intracellular solution for one hour under isochoric conditions at: 0 °C (atmospheric pressure - 0.1 MPa), - 4 °C (41 MPa), - 6 °C (60 MPa) and - 8 °C (78 MPa). The viability of the heart was evaluated using Langendorff perfusion and histological examination. The physiological performance of hearts preserved at - 4 °C (41 MPa) was comparable to that of a heart preserved on ice at atmospheric pressure, with no statistically significant difference in histological injury score. However, hearts preserved at -4 °C displayed substantially reduced interstitial edema compared to hearts preserved by conventional hypothermic preservation in UW on ice at atmospheric pressure, suggesting significant protection from increased vascular permeability following preservation. Hearts preserved at - 6 °C (60 MPa) suffered injury from cellular swelling and extensive edema, and at - 8 °C (78 MPa) hearts experienced significant morphological disruption. To the best of our knowledge, this is the first publication showing that a mammalian organ can survive low subfreezing temperatures without the use of a cryoprotective additive. Lowering the preservation temperature reduces metabolism and improves preservation quality, and these results suggest that improvements in preservation are possible at subzero temperatures with low to moderate pressures observed at -4 °C. Notably, tissue damage was observed at lower temperatures (-6 °C or below) accompanying further elevation of pressure associated with isochoric preservation that may

  8. Development of a Dew-Point Generator for Gases Other than Air and Nitrogen and Pressures up to 6 MPa

    Science.gov (United States)

    Bosma, R.; Peruzzi, A.

    2012-09-01

    A new primary humidity standard is currently being developed at VSL that, in addition to ordinary operation with air and nitrogen at atmospheric pressure, can be operated also with special carrier gases such as natural gas and SF6 and at pressures up to 6 MPa. In this paper, the design and construction of this new primary dew-point generator and the preliminary tests performed on the generator are reported. The results of the first efficiency tests, performed for the dew-point temperature range from -50 °C to 20°C, for pressures up to 0.7MPa and for carrier gas flow rates up to 4L· min-1, showed satisfactory generator performance when used in the single-pass mode, i.e., with no recirculation of the carrier gas.

  9. Optimizing the use of natural gravel Brantas river as normal concrete mixed with quality fc = 19.3 Mpa

    Science.gov (United States)

    Limantara, A. D.; Widodo, A.; Winarto, S.; Krisnawati, L. D.; Mudjanarko, S. W.

    2018-04-01

    The use of natural gravel (rivers) as concrete mixtures is rarely encountered after days of demands for a higher strength of concrete. Moreover, today people have found High-Performance Concrete which, when viewed from the rough aggregate consisted mostly of broken stone, although the fine grain material still used natural sand. Is it possible that a mixture of concrete using natural gravel as a coarse aggregate is capable of producing concrete with compressive strength equivalent to a concrete mixture using crushed stone? To obtain information on this, a series of tests on concrete mixes with crude aggregates of Kalitelu Crusher, Gondang, Tulungagung and natural stone (river gravel) from the Brantas River, Ngujang, Tulungagung in the Materials Testing Laboratory Tugu Dam Construction Project, Kab. Trenggalek. From concrete strength test results using coarse material obtained value 19.47 Mpa, while the compressive strength of concrete with a mixture of crushed stone obtained the value of 21.12 Mpa.

  10. Microbial oil-degradation under mild hydrostatic pressure (10 MPa): which pathways are impacted in piezosensitive hydrocarbonoclastic bacteria?

    Science.gov (United States)

    Scoma, Alberto; Barbato, Marta; Hernandez-Sanabria, Emma; Mapelli, Francesca; Daffonchio, Daniele; Borin, Sara; Boon, Nico

    2016-01-01

    Oil spills represent an overwhelming carbon input to the marine environment that immediately impacts the sea surface ecosystem. Microbial communities degrading the oil fraction that eventually sinks to the seafloor must also deal with hydrostatic pressure, which linearly increases with depth. Piezosensitive hydrocarbonoclastic bacteria are ideal candidates to elucidate impaired pathways following oil spills at low depth. In the present paper, we tested two strains of the ubiquitous Alcanivorax genus, namely A. jadensis KS_339 and A. dieselolei KS_293, which is known to rapidly grow after oil spills. Strains were subjected to atmospheric and mild pressure (0.1, 5 and 10 MPa, corresponding to a depth of 0, 500 and 1000 m, respectively) providing n-dodecane as sole carbon source. Pressures equal to 5 and 10 MPa significantly lowered growth yields of both strains. However, in strain KS_293 grown at 10 MPa CO2 production per cell was not affected, cell integrity was preserved and PO43− uptake increased. Analysis of its transcriptome revealed that 95% of its genes were downregulated. Increased transcription involved protein synthesis, energy generation and respiration pathways. Interplay between these factors may play a key role in shaping the structure of microbial communities developed after oil spills at low depth and limit their bioremediation potential. PMID:27020120

  11. Microbial oil-degradation under mild hydrostatic pressure (10 MPa): which pathways are impacted in piezosensitive hydrocarbonoclastic bacteria?

    KAUST Repository

    Scoma, Alberto

    2016-03-29

    Oil spills represent an overwhelming carbon input to the marine environment that immediately impacts the sea surface ecosystem. Microbial communities degrading the oil fraction that eventually sinks to the seafloor must also deal with hydrostatic pressure, which linearly increases with depth. Piezosensitive hydrocarbonoclastic bacteria are ideal candidates to elucidate impaired pathways following oil spills at low depth. In the present paper, we tested two strains of the ubiquitous Alcanivorax genus, namely A. jadensis KS_339 and A. dieselolei KS_293, which is known to rapidly grow after oil spills. Strains were subjected to atmospheric and mild pressure (0.1, 5 and 10 MPa, corresponding to a depth of 0, 500 and 1000 m, respectively) providing n-dodecane as sole carbon source. Pressures equal to 5 and 10 MPa significantly lowered growth yields of both strains. However, in strain KS_293 grown at 10 MPa CO2 production per cell was not affected, cell integrity was preserved and PO43− uptake increased. Analysis of its transcriptome revealed that 95% of its genes were downregulated. Increased transcription involved protein synthesis, energy generation and respiration pathways. Interplay between these factors may play a key role in shaping the structure of microbial communities developed after oil spills at low depth and limit their bioremediation potential.

  12. Vapour pressures of selected organic compounds down to 1 mPa, using mass-loss Knudsen effusion method

    International Nuclear Information System (INIS)

    Fonseca, José M.S.; Gushterov, Nikola; Dohrn, Ralf

    2014-01-01

    Graphical abstract: - Highlights: • A recently described mass-loss Knudsen apparatus was used for measurements of vapour pressures down to around 1 mPa. • Complementary calorimetric studies were performed in a Calvet-type calorimeter. • New vapour pressures are given for benzoic acid and benzanthrone, in ranges in which no consistent data existed. • Vapour pressures for solid n-octadecane are presented, correcting existing values from literature. - Abstract: A recently developed Knudsen effusion apparatus was improved and used for measurements of vapour pressures of selected organic compounds. Calorimetric studies were conducted using a Calvet-type calorimeter, complementing the information obtained for the vapour pressures and facilitating the modelling and analysis of the data. Vapour pressures of benzoic acid, a reference substance, were determined at temperatures between 269 K and 317 K, corresponding to a pressure range from 2 mPa to 1 Pa, extending the range of results available in the literature to lower pressures. Benzanthrone was studied between temperatures 360 K and 410 K (5 mPa–1 Pa) in order to test the apparatus at higher temperatures. Values presented in the literature for the vapour pressure of solid n-octadecane, one of the most promising compounds to be used as “phase change material” for textile applications, were found inconsistent with the triple point of the substance. Sublimation pressures were measured for this compound between T = 286 K and 298 K (2–20 mPa) allowing the correction of the existing values. Finally, vapour pressures of diphenyl carbonate, a compound of high industrial relevance for its use in the production of polycarbonates, were determined from T = 302 K to 332 K (0.02–1 Pa)

  13. Elastic moduli, thermal expansion, and inferred permeability of Climax quartz monzonite and Sudbury gabbro to 5000C and 55 MPa

    International Nuclear Information System (INIS)

    Page, L.; Heard, H.C.

    1981-01-01

    Young's modulus (E), bulk modulus (K), and the coefficient of thermal linear expansion (α) have been determined for Climax quartz monzonite to 500 0 C and pressures (P) to 55 MPa and for Sudbury gabbro to 300 0 C and 55 MPa. For each rock, both E and K decreased with T and increased with P in a nonlinear manner. In the monzonite, E and K decreased by up to 60% as P decreased from 55.2 to 6.9 MPa isothermally, while the gabbro indicated a decrease up to 70% over the same pressure range. As T increased isobarically, E and K for the monzonite decreased by up to a factor of approx. 80% from 19 to 500 0 C. The moduli of the gabbro decreased by as much as 70% from 19 to 300 0 C. α for the monzonite increased with T and decreased with P in a nonmonotonic fashion, with most measured values for α greater than values calculated for the crack-free aggregate. Depending on P, α in the monzonite increased from 8 to 11.10 -6 0 C -1 at 40 0 C to 22 to 25.10 -6 C -1 at 475 0 C. For the gabbro, α also generally decreased with increasing P. Values ranged from 6 to 11.10 -6 0 C -1 , showing a nonlinear trend and very little net increas over the T range from 19 to 300 0 C. Calculated permeability of these rocks based on the α determinations indicated that permeabilities may increase by up to a factor of 3 over the temperature interval 19 to 300 0 C, and the permeability of the monzonite is inferred to increase by up to a factor of 8 by 500 0 C. In both rocks, most measurements are consistent with microcracks controlling the thermoelastic response by opening with T and closing with sigma and P

  14. Molar volume, thermal expansivity and isothermal compressibility of trans-decahydronaphthalene up to 200MPa and 446K

    Institute of Scientific and Technical Information of China (English)

    Zhu Hu-Gang; Liu Zhi-Hua; Tian Yi-Ling; Xue Yuan; Yin Liang

    2005-01-01

    The molar volume isotherms of trans-decahydronaphthalene (C10H18) between 293 and 446 K and at pressures from 10 to 200 MPa have been determined. A modified Tait equation of state is used to fit each experimental molar volume isotherm with a maximum average deviation of 0.029%. The thermal expansivity (cubic expansion coefficient) α and isothermal compressibility κ were determined by fitting the slopes of the isobaric curves and isotherms, respectively.The coefficients in the equation Vm = C1 + C2T + C3T2 - C4p - C5pT have been fitted with an average deviation of 1.03%.

  15. Viscosity Measurements and Correlations for 1,1,1,2-tetrafluoroethane (HFC-134a) up to 140 MPa

    DEFF Research Database (Denmark)

    Comuñas, M.J.P.; Baylaucq, A.; Cisneros, Sergio

    2003-01-01

    In spite of being one of the most studied refrigerants, large discrepancies in the experimental determination of the dynamic viscosity of 1, 1, 1,2-tetrafluoroethane (HFC-134a) prevail. Additionally, there is a need for supplementary high-pressure measurements that can help to derive sound general...... correlations for the viscosity of this compound. Hence, in this work new dynamic viscosity measurements for HFC-134a using a falling-body viscometer in the temperature range of 293.15-373.15 K and pressures up to 140 MPa are presented. This work high-pressure data in combination with already published data...

  16. Comparing the Structure and Mechanical Properties of Welds on Ductile Cast Iron (700 MPa under Different Heat Treatment Conditions

    Directory of Open Access Journals (Sweden)

    Ronny M. Gouveia

    2018-01-01

    Full Text Available The weldability of ductile iron, as widely known, is relatively poor, essentially due to its typical carbon equivalent value. The present study was developed surrounding the heat treatability of welded joints made with a high strength ductile cast iron detaining an ultimate tensile strength of 700 MPa, and aims to determine which heat treatment procedures promote the best results, in terms of microstructure and mechanical properties. These types of alloys are suitable for the automotive industry, as they allow engineers to reduce the thickness of parts while maintaining mechanical strength, decreasing the global weight of vehicles and providing a path for more sustainable development. The results allow us to conclude that heat treatment methodology has a large impact on the mechanical properties of welded joints created from the study material. However, the thermal cycles suffered during welding promote the formation of ledeburite areas near the weld joint. This situation could possibly be dealt through the implementation of post-welding heat treatments (PWHT with specific parameters. In contrast to a ductile cast iron tested in a previous work, the bull-eye ductile cast iron with 700 MPa ultimate tensile strength presented better results during the post-welding heat treatment than during preheating.

  17. Liquid density of HFE-7200 and HFE-7500 from T = (283 to 363) K at pressures up to 100 MPa

    International Nuclear Information System (INIS)

    Fang, Dan; Li, Ying; Meng, Xianyang; Wu, Jiangtao

    2014-01-01

    Highlights: • Liquid densities are reported for HFE-7200 and HFE-7500 at temperatures from (283 to 363) K, pressures up to 100 MPa. • The expanded uncertainty (k = 2) of density measurement for HFE-7200 and HFE-7500 were 0.04% and 0.03%, respectively. • Modified Tait equations were correlated with the experimental data. • The isobaric thermal expansivity and isothermal compressibility of HFE-7200 and HFE-7500 were calculated. -- Abstract: The liquid densities of HFE-7200 (1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane, CAS Registry Number: 163702-05-4) and HFE-7500 (3-ethoxyperfluoro(2-methylhexane), CAS Registry Number: 297730-93-9) have been measured over the temperature range from (283 to 363) K and pressures up to 100 MPa by using a high pressure vibrating-tube densimeter. R134a has been used as a reference fluid to validate the densimeter. The uncertainty of each obtained datum was estimated, and the maximum expanded uncertainty with a level of confidence of 0.95 (k = 2) of density measurement for HFE-7200 and HFE-7500 were 0.04% and 0.03%, respectively. The measured liquid densities were correlated with the modified Tait equation and the maximum deviation is less than 0.03%. The isothermal compressibility and isobaric thermal expansivity were also calculated

  18. Stakeholder opinions on the assessment of MPA effectiveness and their interests to participate at Pacific Rim National Park Reserve, Canada.

    Science.gov (United States)

    Heck, Nadine; Dearden, Philip; McDonald, Adrian; Carver, Steve

    2011-04-01

    As the number of marine protected areas (MPAs) is globally increasing, information is needed on the effectiveness of existing sites. Many protected area agencies however have limited resources and are unable to evaluate MPA effectiveness. An evaluation conducted entirely by the managing agency may also lack credibility. Long-term monitoring and evaluation programs should ideally offer opportunities for participation of diverse groups in the selection of evaluation indicators and their assessment. A participatory approach has the potential to enhance evaluation capacity, to increase credibility and acceptance of results, to strengthen relationships between managers and local stakeholders, and to address more locally relevant information. Using a case study approach, this paper investigates diverse stakeholder groups' opinions on the design of an evaluation and their interest to participate in an assessment. Respondents were most interested in the assessment of MPA achievements and outcome indicators. Most groups identified a range of government agencies and stakeholders that should participate in an assessment but only half of all respondents were interested to participate in monitoring activities. Most frequently mentioned limitations for more participation were a lack of time and money, but also governance shortcomings such as limited participation possibilities and not paying enough credit to stakeholders' input. Participation interest was also influenced by occupation, place of residency, and familiarity with the marine environment. Differences exist among stakeholders about suitable evaluators and preferred monitoring partners, which could affect the credibility of evaluation results and affect monitoring activities.

  19. Mechanically, the shoot apical meristem of Arabidopsis behaves like a shell inflated by a pressure of about 1 MPa

    Directory of Open Access Journals (Sweden)

    Léna eBeauzamy

    2015-11-01

    Full Text Available In plants, the shoot apical meristem contains the stem cells and is responsible for the generation of all aerial organs. Mechanistically, organogenesis is associated with an auxin-dependent local softening of the epidermis. This has been proposed to be sufficient to trigger outgrowth, because the epidermis is thought to be under tension and stiffer than internal tissues in all the aerial part of the plant. However, this has not been directly demonstrated in the shoot apical meristem. Here we tested this hypothesis in Arabidopsis using indentation methods and modeling. We considered two possible scenarios: either the epidermis does not have unique properties and the meristem behaves as a homogeneous linearly-elastic tissue, or the epidermis is under tension and the meristem exhibits the response of a shell under pressure. Large indentation depths measurements with a large tip (~size of the meristem were consistent with a shell-like behavior. This also allowed us to deduce a value of turgor pressure, estimated at 0.82 ± 0.16 MPa. Indentation with atomic force microscopy provided local measurements of pressure in the epidermis, further confirming the values obtained from large deformations. Altogether, our data demonstrate that the Arabidopsis shoot apical meristem behaves like a shell under a MPa range pressure and support a key role for the epidermis in shaping the shoot apex.

  20. (p, {rho}, T, x) properties for CO{sub 2}/isobutane binary mixtures at T = (280 to 440) K and (3 to 200) MPa

    Energy Technology Data Exchange (ETDEWEB)

    Sugiyama, T. [Master' s Programs of Mechanical Systems Engineering, Toyama Prefectural University (Japan); Orita, S. [Department of Mechanical Systems Engineering, Toyama Prefectural University (Japan); Miyamoto, H., E-mail: miyamoto@pu-toyama.ac.jp [Department of Mechanical Systems Engineering, Toyama Prefectural University (Japan)

    2011-12-15

    Highlights: > The p{rho}Tx properties for CO{sub 2}/isobutane were measured in the compressed liquid phase. > A total of 283 points data were obtained from T = (280 to 440) K and (3 to 200) MPa. > The data were compared with the available equation of state. > The excess molar volumes were calculated and plotted as a function of T and P. - Abstract: The (p, {rho}, T, x) properties for binary mixtures of CO{sub 2} (volume fraction purity 0.99999) and isobutane (mole fraction purity 0.99988) {l_brace}x{sub 1} CO{sub 2} + x{sub 2} isobutane (x{sub 1} = 0.2482, 0.4718, and 0.7506){r_brace} were measured in the compressed liquid phase using a metal-bellows variable volumometer. Measurements were conducted from T = (280 to 440) K and (3 to 200) MPa. The expanded uncertainties (k = 2) were estimated to be: temperature, <3 mK; pressure, 1.5 kPa (p {<=} 7 MPa), 0.06% (7 MPa < p {<=} 50 MPa), 0.1% (50 MPa < p {<=} 150 MPa), 0.2% (p > 150 MPa); density, 0.10%; and composition, 4.4 . 10{sup -4}. At >100 MPa and T = (280 or 440) K, the uncertainties in the density measurements increased to 0.14% and 0.22%, respectively. The data are compared with the available equation of state. The excess molar volumes, v{sub m}{sup E}, of the mixtures were calculated and plotted as a function of temperature and pressure.

  1. Vapour pressures and vapour-liquid equilibria of propyl acetate and isobutyl acetate with ethanol or 2-propanol at 0.15 MPa. Binary systems

    Directory of Open Access Journals (Sweden)

    Susial Pedro

    2012-01-01

    Full Text Available Vapour pressures of propyl acetate, isobutyl acetate and 2-propanol from 0.004 to 1.6 MPa absolute pressure and VLE data for the binary systems propyl acetate+ethanol, propyl acetate+2-propanol, isobutyl acetate+ethanol and isobutyl acetate+2-propanol at 0.15 MPa have been determined. The experimental VLE data were verified with the test of van Ness and the Fredenslund criterion. The propyl acetate+ethanol or +2-propanol binary systems have an azeotropic point at 0.15 MPa. The different versions of the UNIFAC and ASOG group contribution models were applied.

  2. The effect of transverse loads up to 300 MPa on the critical currents of Nb3Sn cables

    International Nuclear Information System (INIS)

    Boschman, H.; Verweij, A.P.; Wessel, S.; ten Kate, H.H.J.; van de Klundert, L.J.M.

    1991-01-01

    In the framework of the development of an experimental 10 T Nb 3 Sn dipole coil for the LHC at CERN the effects of transverse stress on Rutherford type of Nb 3 Sn cables have been investigated. For this purpose a special facility was designed and taken into operation in which the voltage-current behavior of short pieces of Nb 3 Sn cables can be investigated in a background field up to 11 T and an applied stress of 300 MPa. The repulsive Lorentz force of 250 kN, generated by a set of superconducting coils, is used to impress the cable over an area of 20 x 42 mm 2 maximum, in presence of a transport current up to 40 kA. In this paper the testing equipment is described and the first results of the observed critical current degradation of two Nb 3 Sn cables are discussed

  3. Effect of Weld Bead Shape on the Fatigue Behavior of GMAW Lap Fillet Joint in GA 590 MPa Steel Sheets

    Directory of Open Access Journals (Sweden)

    Insung Hwang

    2017-09-01

    Full Text Available In this study, the effect of weld bead shape on the fatigue strength of lap fillet joints using the gas metal arc welding (GMAW process was investigated. The base material used in the experiment was 590 MPa grade galvanealed steel sheet with 2.3 mm and 2.6 mm thickness. In order to make the four types of weld beads with different shapes by factors such as length, angle, and area, the welding process, wire feeding speed, and joint shape were changed. The stress-number of cycles to failure (S–N curve and fatigue strength were obtained from the fatigue test for four types of weld bead, and the cause of the fatigue strength difference was clarified through the analysis of the geometrical factors, such as length, angle, and area of the weld bead. In addition, the relationship between weld bead shape and fatigue strength was discussed.

  4. Macrostructural and microstructural features of 1 000 MPa grade TRIP steel joint by CO2 laser welding

    Institute of Scientific and Technical Information of China (English)

    Wang Wenquan; Sun Daqian; Kang Chungyun

    2008-01-01

    Bead-on-plate CO2 laser welding of 1 000 MPa grade transformation induced plasticity (TRIP) steel was conducted under different welding powers, welding speeds and shield gases. The macrostructural and microstructural features of the welded joint were investigated. The increase of welding speed reduced the width of the weld bead and the porosities in the weld bead resulting from the different flow mode of melted metal in weld pool. The decrease of welding power or use of shield gas of helium also contributed to the reduction of porosity in the weld bead due to the alleviation of induced plasma formation, thus stabilizing the keyhole. The porosity formation intimately correlated with the evaporation of alloy element Mn in the base metal. The laser welded metal had same martensite microstructure as that of water-quenched base metal. The welding parameters which increased cooling rate all led to fine microstructures of the weld bead.

  5. Foulant analysis of hollow fine fiber (HFF) membranes in Red Sea SWRO plants using membrane punch autopsy (MPA)

    KAUST Repository

    Green, Troy N.

    2017-06-12

    Membrane punch autopsy (MPA) is a procedure for quantitative foulant analysis of hollow fine fiber (HFF) permeators. In the past, quantitative autopsies of membranes were restricted to spiral wound. This procedure was developed at SWCC laboratories and tested on permeators of two commercial Red Sea reverse osmosis plants. For membrane autopsies, stainless steel hollow bore picks were penetrated to membrane cores and fibers extracted for foulant analysis. Quantitative analysis of extracted materials contained inorganic and organic foulants including bacteria. Fourier transform infrared spectroscopy analysis confirmed the presence of organic fouling functional groups and scanning electron microscopy with energy dispersive X-ray spectroscopy in the presence of diatoms and silica most likely not from particulate sand. API analysis revealed the presence of Shewanella and two Vibrio microbial species confirmed by 16S rDNA sequence library. It was observed that fouling content of HFF cellulose triacetate (CTA) membranes were more than 800 times than polyamide spiral wound membranes.

  6. A comparative approach for the characterization of a pneumatic piston gauge up to 8 MPa using finite element calculations

    International Nuclear Information System (INIS)

    Dogra, Sugandha; Singh, Jasveer; Lodh, Abhishek; Sharma, Nita Dilawar; Bandyopadhyay, A K

    2011-01-01

    This paper reports the behavior of a well-characterized pneumatic piston gauge in the pressure range up to 8 MPa through simulation using finite element method (FEM). Experimentally, the effective area of this piston gauge has been estimated by cross-floating to obtain A 0 and λ. The FEM technique addresses this problem through simulation and optimization with standard commercial software (ANSYS) where the material properties of the piston and cylinder, dimensional measurements, etc are used as the input parameters. The simulation provides the effective area A p as a function of pressure in the free deformation mode. From these data, one can estimate A p versus pressure and thereby A o and λ. Further, we have carried out a similar theoretical calculation of A p using the conventional method involving the Dadson's as well as Johnson–Newhall equations. A comparison of these results with the experimental results has been carried out

  7. Density measurements of liquid 2-propanol at temperatures between (280 and 393) K and at pressures up to 10 MPa

    International Nuclear Information System (INIS)

    Stringari, Paolo; Scalabrin, Giancarlo; Valtz, A.; Richon, D.

    2009-01-01

    Liquid densities for 2-propanol have been measured at T = (280, 300, 325, 350, 375, and 393) K from about atmospheric pressure up to 10 MPa using a vibrating tube densimeter. The period of vibration has been converted into density using the Forced Path Mechanical Calibration method. The R134a has been used as reference fluid for T ≤ 350 K and water for T > 350 K. The uncertainty of the measurements is lower than ±0.05%. The measured liquid densities have been correlated with a Starling BWR equation with an overall AAD of 0.025%. The same BWR equation agrees within an AAD lower than 0.2% with the experimental values available in the literature over the same temperature and pressure range

  8. Small GSH-Capped CuInS2 Quantum Dots: MPA-Assisted Aqueous Phase Transfer and Bioimaging Applications.

    Science.gov (United States)

    Zhao, Chuanzhen; Bai, Zelong; Liu, Xiangyou; Zhang, Yijia; Zou, Bingsuo; Zhong, Haizheng

    2015-08-19

    An efficient ligand exchange strategy for aqueous phase transfer of hydrophobic CuInS2/ZnS quantum dots was developed by employing glutathione (GSH) and mercaptopropionic acid (MPA) as the ligands. The whole process takes less than 20 min and can be scaled up to gram amount. The material characterizations show that the final aqueous soluble samples are solely capped with GSH on the surface. Importantly, these GSH-capped CuInS2/ZnS quantum dots have small size (hydrodynamic diameter quantum dots, for instance, CuInSe2 and CdSe/ZnS quantum dots. We further demonstrated that GSH-capped quantum dots could be suitable fluorescence markers to penetrate cell membrane and image the cells. In addition, the GSH-capped CuInS2 quantum dots also have potential use in other fields such as photocatalysis and quantum dots sensitized solar cells.

  9. A comparative approach for the characterization of a pneumatic piston gauge up to 8 MPa using finite element calculations

    Science.gov (United States)

    Dogra, Sugandha; Singh, Jasveer; Lodh, Abhishek; Dilawar Sharma, Nita; Bandyopadhyay, A. K.

    2011-02-01

    This paper reports the behavior of a well-characterized pneumatic piston gauge in the pressure range up to 8 MPa through simulation using finite element method (FEM). Experimentally, the effective area of this piston gauge has been estimated by cross-floating to obtain A0 and λ. The FEM technique addresses this problem through simulation and optimization with standard commercial software (ANSYS) where the material properties of the piston and cylinder, dimensional measurements, etc are used as the input parameters. The simulation provides the effective area Ap as a function of pressure in the free deformation mode. From these data, one can estimate Ap versus pressure and thereby Ao and λ. Further, we have carried out a similar theoretical calculation of Ap using the conventional method involving the Dadson's as well as Johnson-Newhall equations. A comparison of these results with the experimental results has been carried out.

  10. High pressure apparatus for hydrogen isotopes to pressures of 345 MPa (50,000 psi) and temperatures of 12000C

    International Nuclear Information System (INIS)

    Lakner, J.F.

    1977-01-01

    A functional new high pressure, high temperature apparatus for hydrogen isotopes uses an internally heated pressure vessel within a larger pressure vessel. The pressure capability is 345 MPa (50 K psi) at 1200 0 C. The gas pressure inside the internal vessel is balanced with gas pressure in the external vessel. The internal vessel is attached to a closure and is also the sample container. Our design allows thin-walled internal vessel construction and keeps the sample from ''seeing'' the furnace or other extraneous environment. The sample container together with the closure can easily be removed and loaded under argon using standard glove-box procedures. The small volume of the inner vessel permits small volumes of gas to be used, thus increasing the sensitivity during pressure-volume-temperature (PVT) work

  11. Experimental determination of the phase boundary between kornelite and pentahydrated ferric sulfate at 0.1MPa

    Science.gov (United States)

    Kong, W.G.; Wang, A.; Chou, I.-Ming

    2011-01-01

    Recent findings of various ferric sulfates on Mars emphasize the importance of understanding the fundamental properties of ferric sulfates at temperatures relevant to that of Martian surface. In this study, the phase boundary between kornelite (Fe2(SO4)3.7H2O) and pentahydrated ferric sulfate (Fe2(SO4)3.5H2O) was experimentally determined using the humidity-buffer technique together with gravimetric measurements and Raman spectroscopy at 0.1MPa in the 36-56??C temperature range. Through the thermodynamic analysis of our experimental data, the enthalpy change (-290.8??0.3kJ/mol) and the Gibbs free energy change (-238.82??0.02kJ/mol) for each water molecule of crystallization in the rehydration of pentahydrated ferric sulfate to kornelite were obtained. ?? 2011 Elsevier B.V.

  12. Examining the microtexture evolution in a hole-edge punched into 780 MPa grade hot-rolled steel

    Energy Technology Data Exchange (ETDEWEB)

    Shin, J.H.; Kim, M.S. [Department of Printed Electronics Engineering, Sunchon National University, 315 Maegok, Sunchon, Jeonnam 540-950 (Korea, Republic of); Kim, S.I.; Seo, S.J. [POSCO Technical Research Laboratories, Gwangyang 545-090 (Korea, Republic of); Choi, S.-H., E-mail: shihoon@sunchon.ac.kr [Department of Printed Electronics Engineering, Sunchon National University, 315 Maegok, Sunchon, Jeonnam 540-950 (Korea, Republic of)

    2016-08-15

    The deformation behavior in the hole-edge of 780 MPa grade hot-rolled steel during the punching process was investigated via microstructure characterization and computational simulation. Microstructure characterization was conducted to observe the edges of punched holes through the thickness direction, and electron back-scattered diffraction (EBSD) was used to analyze the heterogeneity of the deformation. Finite element analysis (FEA) that could account for a ductile fracture criterion was conducted to simulate the deformation and fracture behaviors of 780 MPa grade hot-rolled steel during the punching process. Calculation of rotation rate fields at the edges of the punched holes during the punching process revealed that metastable orientations in Euler space were confined to specific orientation groups. Rotation-rate fields effectively explained the stability of the initial texture components in the hole-edge region during the punching process. A visco-plastic self-consistent (VPSC) polycrystal model was used to calculate the microtexture evolution in the hole-edge region during the punching process. FEA revealed that the heterogeneous effective strain was closely related to the heterogeneity of the Kernel average misorientation (KAM) distribution in the hole-edge region. A simulation of the deformation microtexture evolution in the hole-edge region using a VPSC model was in good agreement with the experimental results. - Highlights: •We analyzed the microstructure in a hole-edge punched in HR 780HB steel. •Rotation rate fields revealed the stability of the initial texture components. •Heterogeneous effective stain was closely related to the KAM distribution. •VPSC model successfully simulated the deformation microtexture evolution.

  13. Measurement of the ( p, , T) Properties for Pure Hydrocarbons at Temperatures up to 600 K and Pressures up to 200 MPa

    Science.gov (United States)

    Ito, T.; Nagata, Y.; Miyamoto, H.

    2014-10-01

    The data available for the thermodynamic properties of propane, -butane, and isobutane at temperatures above 440 K are outdated and show significant discrepancies with each other. The ambiguity associated with these data could be limiting to the development of any understanding related to the effects of mixing of these substances with other materials such as , ammonia, and non-flammable or lower-flammable HFC refrigerants. In this study, the ( p, , T) properties of propane, -butane, and isobutane were measured at temperatures ranging from (360 to 600) K and pressures ranging from (50 to 200) MPa. Precise measurements were carried out using a metal-bellows variable volumometer with a thermostatted air bath. The expanded uncertainties in the temperature, pressure, and density measurements were estimated to be 5 mK, 0.02 MPa, and 0.88 kg m ( K, MPa), 0.76 kg ( K, MPa), 0.76 kg ( K, MPa), and 2.94 kg ( K, MPa), respectively. The data obtained throughout this study were systematically compared with the calculated values derived from the available equations of state. These models agree well with the measured data at higher temperatures up to 600 K, demonstrating their suitability for an effective and precise examination of the mixing effects of potential alternative mixtures.

  14. Effects of high pressure application (400 and 900 MPa) and refrigerated storage time on the oxidative stability of sliced skin vacuum packed dry-cured ham.

    Science.gov (United States)

    Clariana, Maria; Guerrero, Luis; Sárraga, Carmen; Garcia-Regueiro, José A

    2012-02-01

    The effect of high pressure processing at 400 MPa and 900 MPa on the oxidative stability of sliced and vacuum packaged commercial dry-cured ham was determined by analyzing the antioxidant enzyme activities, TBARS levels (thiobarbituric acid reactive substances), vitamin E content and physicochemical characteristics during refrigerated storage for 50 days in different light conditions. In dry-cured ham pressurized at 400 MPa color changes and sensory analyses were also assessed. The high pressure process at 900 MPa produced a decrease in superoxide dismutase (SOD) and glutathione peroxidase (GSHPx) activities and increased vitamin E content. In contrast, pressurization at 400 MPa, increased SOD activity, and showed no effect on vitamin E content and GSHPx activity. In general the physicochemical parameters determined (fat, moisture and collagen) were unaffected by pressurization. Treatment at 400 MPa increased the instrumental color measurement of lightness (L* values, CIELAB). This level of pressure also modified the hardness, chewiness, saltiness and color intensity. These changes of the sensory attributes in dry-cured ham were significant, but small. Copyright © 2011 Elsevier Ltd. All rights reserved.

  15. Northeast MPA Valuation

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The design of marine protected areas (MPAs) generates much discussion among marine scientists. Ecological studies have suggested that protecting 10 to 40% of...

  16. Development of a model for the anodic behavior of T60 titanium in chlorinated and oxygenated aqueous media. Application to the specific conditions of hydrothermal oxidation (1 MPaMPa, 20 deg. C

    International Nuclear Information System (INIS)

    Frayret, C.; Jaszay, Th.; Lestienne, B.; Delville, M.H.

    2003-01-01

    This work evaluates the anodic electrochemical behavior of titanium metal in hydrothermal oxidation conditions (up to 400 deg. C and 28 MPa) in chlorinated media in order to estimate the supercritical water oxidation reactors reliability for the treatment of less than 10% organic-waste waters. The titanium room temperature dissolution mechanism in chlorinated acidic medium (pH 2 oxide formation with a very limited tetravalent dissolution). In hydrothermal oxidation (pH>1), only the second branch is effective. The titanium protection is directly related to the oxide stability in high pH systems. The mechanism model is expressed in terms of 'current-potential' laws, which provide kinetic parameters using optimization calculations. The different elementary steps reaction rates were estimated as well as the evolution of the reaction intermediates coverage ratios with the potential. The quantification of each elementary step was performed to understand and/or orient the materials behavior according to different factors (pH, chloride ions contents, potentials...)

  17. (p, ρ, T) Properties for n-butane in the temperature range from 280 K to 380 K at pressures up to 200 MPa

    International Nuclear Information System (INIS)

    Miyamoto, H.; Uematsu, M.

    2007-01-01

    The (p, ρ, T) properties for n-butane in the compressed liquid phase were measured by means of a metal-bellows variable volumometer in the temperature range from 280 K to 380 K at pressures up to 200 MPa. The mole fraction purity of the n-butane used in the measurements was 0.9997. The expanded uncertainties (k = 2) in temperature, pressure, and density measurements have been estimated to be less than ±3 mK; 1.4 kPa (p ≤ 7 MPa), 0.06% (7 MPa 150 MPa); and 0.09%, respectively. In the region above100 MPa at T = 280 K and T = 440 K, the uncertainty in density measurements increases from 0.09% to 0.13% and 0.22%, respectively. Eight (p, ρ, T) measurements at the same temperatures and pressures as the literature values have been conducted for comparisons. In addition, comparisons of the available equations of state with the present measurements are reported

  18. Measurements of (p, ρ, T) properties for isobutane in the temperature range from 280 K to 440 K at pressures up to 200 MPa

    International Nuclear Information System (INIS)

    Miyamoto, H.; Uematsu, M.

    2006-01-01

    Measurements of (p, ρ, T) properties for isobutane in the compressed liquid phase have been obtained by means of a metal-bellows variable volumometer in the temperature range from 280 K to 440 K at pressures up to 200 MPa. The volume-fraction purity of isobutane used was 0.9999. The expanded uncertainties (k = 2) of temperature, pressure, and density measurements have been estimated to be less than 3 mK, 1.5 kPa (p ≤ 7 MPa), 0.06% (7 MPa 150 MPa), and 0.11%, respectively. In region more than 100 MPa at 280 K and 440 K, the uncertainty in density measurements rise up to 0.15% and 0.23%, respectively. The differences of the present density values at the same temperature between two series of measurements, in which the sample fillings are different, are within the maximum deviation of 0.09% in density, which is enough lower than the expanded uncertainty in density. Eight (p, ρ, T) measurements at the same temperatures and pressures as the literature values have been conducted for comparison. In addition, vapour pressures were measured at T = (280, 300) K. Moreover, the comparisons of the available equations of state with the present measurements are reported

  19. Properties of Normal and Recycled Brick Aggregates for Production of Medium Range (25–30 MPa Structural Strength Concrete

    Directory of Open Access Journals (Sweden)

    Suvash Chandra Paul

    2018-05-01

    Full Text Available This study compares the properties of normal and recycled brick aggregates to produce a medium range (25–30 MPa compressive strength of structural grade concrete. Up to date, brick aggregates are commonly used in structural concrete in some South Asian and African countries. Many concrete structures which were built in the last century are made from brick aggregates and some of them are already in a position of ending of their service life. At the same time, population and economic growth is forcing the demolition of many old structures. Therefore, there is a huge flow of construction and demolition waste and thereby it is necessary to recycle the waste to overcome the problem of occupying the landfill sites. For this study, recycled brick aggregates were collected from the various demolished building sites and their physical and mechanical performance were then compared with the concrete made from normal brick aggregates. It is found that the mechanical properties of recycled brick concrete are comparable to that of normal brick aggregate at medium strength level. The production cost of recycled brick concrete is also found to be 10–12% lower than normal brick aggregates.

  20. The effect of microstructure on the sheared edge quality and hole expansion ratio of hot-rolled 700 MPa steel

    Science.gov (United States)

    Kaijalainen, A.; Kesti, V.; Vierelä, R.; Ylitolva, M.; Porter, D.; Kömi, J.

    2017-09-01

    The effects of microstructure on the cutting and hole expansion properties of three thermomechanically rolled steels have been investigated. The yield strength of the studied 3 mm thick strip steels was approximately 700 MPa. Detailed microstructural studies using laser scanning confocal microscopy (LCSM), FESEM and FESEM-EBSD revealed that the three investigated materials consist of 1) single-phase polygonal ferrite, 2) polygonal ferrite with precipitates and 3) granular bainite. The quality of mechanically sheared edges were evaluated using visual inspection and LSCM, while hole expansion properties were characterised according to the methods described in ISO 16630. Roughness values (Ra and Rz) of the sheet edge with different cutting clearances varied between 12 µm to 21 µm and 133 µm to 225 µm, respectively. Mean hole expansion ratios varied from 28.4% to 40.5%. It was shown that granular bainite produced the finest cutting edge, but the hole expansion ratio remained at the same level as in the steel comprising single-phase ferrite. This indicates that a single-phase ferritic matrix enhances hole expansion properties even with low quality edges. A brief discussion of the microstructural features controlling the cutting quality and hole expansion properties is given.

  1. Fluorescence enhancement of CdTe MPA-capped quantum dots by glutathione for hydrogen peroxide determination.

    Science.gov (United States)

    Rodrigues, S Sofia M; Ribeiro, David S M; Molina-Garcia, L; Ruiz Medina, A; Prior, João A V; Santos, João L M

    2014-05-01

    The manipulation of the surface chemistry of semiconductor nanocrystals has been exploited to implement distinct sensing strategies in many analytical applications. In this work, reduced glutathione (GSH) was added at reaction time, as an electron-donor ligand, to markedly increase the quantum yield and the emission efficiency of MPA-capped CdTe quantum dots. The developed approach was employed in the implementation of an automated flow methodology for hydrogen peroxide determination, as this can oxidize GSH preventing its surface passivating effect and producing a manifest fluorescence quenching. After optimization, linear working calibration curve for hydrogen peroxide concentrations between 0.0025% and 0.040% were obtained (n=6), with a correlation coefficient of 0.9975. The detection limit was approximately 0.0012%. The developed approach was employed in the determination of H₂O₂ in contact lens preservation solutions and the obtained results complied with those furnished by the reference method, with relative deviations comprised between -1.18 and 4.81%. Copyright © 2014 Elsevier B.V. All rights reserved.

  2. Experimental study of the polyamorphism of water. I. The isobaric transitions from amorphous ices to LDA at 4 MPa

    Science.gov (United States)

    Handle, Philip H.; Loerting, Thomas

    2018-03-01

    The existence of more than one solid amorphous state of water is an extraordinary feature. Since polyamorphism might be connected to the liquid-liquid critical point hypothesis, it is particularly important to study the relations amongst the different amorphous ices. Here we study the polyamorphic transformations of several high pressure amorphous ices to low-density amorphous ice (LDA) at 4 MPa by isobaric heating utilising in situ volumetry and ex situ X-ray diffraction. We find that very-high density amorphous ice (VHDA) and unannealed high density amorphous ice (HDA) show significant relaxation before transforming to LDA, whereby VHDA is seen to relax toward HDA. By contrast, expanded HDA shows almost no relaxation prior to the transformation. The transition to LDA itself obeys criteria for a first-order-like transition in all cases. In the case of VHDA, even macroscopic phase separation is observed. These findings suggest that HDA and LDA are two clearly distinct polyamorphs. We further present evidence that HDA reaches the metastable equilibrium at 140 K and 0.1 GPa but only comes close to that at 140 K and 0.2 GPa. The most important is the path independence of the amorphous phase reached at 140 K and 0.1 GPa.

  3. Investigation of hydrogen isotope exchange reaction rate in mixed gas (H2 and D2) at pressure up to 200 MPa using Raman spectroscopy

    International Nuclear Information System (INIS)

    Tikhonov, V.V.; Yukhimchuk, A.A.; Musyayev, R.K.; Gurkin, A.I.

    2015-01-01

    Raman spectroscopy is a relevant method for obtaining objective data on isotopic exchange rate in a gaseous mix of hydrogen isotopes, since it allows one to determine a gaseous mix composition in real time without sampling. We have developed a high-pressure fiber-optic probe to be used for obtaining protium Raman spectra under pressures up to 400 MPa and we have recorded spectral line broadening induced by molecule collisions starting from ∼ 40 MPa. Using this fiber-optic probe we have performed experiments to study isotopic exchange kinetics in a gaseous mix of hydrogen isotopes (protium-deuterium) at pressures up to 200 MPa. Preliminary results show that the dependence of the average isotopic exchange rate related to pressure take unexpected values at the very beginning of the time evolution. More work is required to understand this inconsistency

  4. Investigation of hydrogen isotope exchange reaction rate in mixed gas (H{sub 2} and D{sub 2}) at pressure up to 200 MPa using Raman spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Tikhonov, V.V.; Yukhimchuk, A.A.; Musyayev, R.K.; Gurkin, A.I. [Russian Federal Nuclear Center, All-Russian Research Institute of Experimental Physics, Sarov (Russian Federation)

    2015-03-15

    Raman spectroscopy is a relevant method for obtaining objective data on isotopic exchange rate in a gaseous mix of hydrogen isotopes, since it allows one to determine a gaseous mix composition in real time without sampling. We have developed a high-pressure fiber-optic probe to be used for obtaining protium Raman spectra under pressures up to 400 MPa and we have recorded spectral line broadening induced by molecule collisions starting from ∼ 40 MPa. Using this fiber-optic probe we have performed experiments to study isotopic exchange kinetics in a gaseous mix of hydrogen isotopes (protium-deuterium) at pressures up to 200 MPa. Preliminary results show that the dependence of the average isotopic exchange rate related to pressure take unexpected values at the very beginning of the time evolution. More work is required to understand this inconsistency.

  5. Development and Technology of Large Thickness TMCP Steel Plate with 390MPA Grade Used for Engineering Machinery

    Science.gov (United States)

    Wang, Xiaoshu; Zhang, Zhijun; Zhang, Peng

    Recently, with the rapid upgrading of the equipment in the steel Corp, the rolling technology of TMCP has been rapidly developed and widely applied. A large amount of steel plate has been produced by using the TMCP technology. The TMCP processes have been used more and more widely and replaced the heat treatment technology of normalizing, quenching and tempering heat process. In this paper, low financial input is considered in steel plate production and the composition of the steel has been designed with low C component, a limited alloy element of the Nb, and certain amounts of Mn element. During the continuous casting process, the size of the continuous casting slab section is 300 mm × 2400 mm. The rolling technology of TMCP is controlled at a lower rolling and red temperature to control the transformation of the microstructure. Four different rolling treatments are chosen to test its effects on the 390MPa grade low carbon steel of bainitic microstructure and properties. This test manages to produce a proper steel plate fulfilling the standard mechanical properties. Specifically, low carbon bainite is observed in the microstructure of the steel plate and the maximum thickness of steel plate under this TMCP technology is up to 80mm. The mechanical property of the steel plate is excellent and the KV2 at -40 °C performs more than 200 J. Moreover, the production costs are greatly reduced when the steel plate is produced by this TMCP technology when replacing the current production process of quenching and tempering. The low cost steel plate could well meet the requirements of producing engineering machinery in the steel market.

  6. Heat capacity and Joule-Thomson coefficient of selected n-alkanes at 0.1 and 10 MPa in broad temperature ranges

    DEFF Research Database (Denmark)

    Regueira Muñiz, Teresa; Varzandeh, Farhad; Stenby, Erling Halfdan

    2017-01-01

    Isobaric heat capacity of six n-alkanes, i.e. n-hexane, n-octane, n-decane, n-dodecane, n-tetradecane and n-hexadecane, was determined with a Calvet type differential heat-flux calorimeter at 0.1 and 10 MPa in a broad temperature range. The measured isobaric heat capacity data were combined...

  7. Phase Equilibrium Measurements and Modeling of 1-Propanethiol+1-Butanethiol + CH4 in Methane Ternary System at 303, 336, and 368 K and Pressure Up to 9 MPa

    DEFF Research Database (Denmark)

    Awan, Javeed A.; Coquelet, Christophe; Tsivintzelis, Ioannis

    2016-01-01

    New vapor-liquid equilibrium (VLE) data for 1-propanethiol + 1-butanethiol + CH4 ternary system is reported. Measurements were performed at three different temperatures (303, 336, and 368 K), and the pressure ranged from 1 to 9 MPa. The total system pressure was maintained by CH4. The inlet mole...

  8. Determination of isobaric thermal expansivity of organic compounds from 0.1 to 30 MPa at 30 degrees C with an isothermal pressure scanning microcalorimeter

    DEFF Research Database (Denmark)

    Verdier, Sylvain Charles Roland; Andersen, Simon Ivar

    2003-01-01

    This paper describes a simple high-pressure mercury-free microcalorimetric technique that enables the compression of a fluid from 0.1 to 30 MPa. Thermal expansivities of several compounds were calculated (n-hexane, cyclohexane, heptane, and toluene) with the pressure. scanning transitiometry method...

  9. Stretch rate effects and flame surface densities in premixed turbulent combustion up to 1.25 MPa

    KAUST Repository

    Bagdanavicius, Audrius

    2015-11-01

    Independent research at two centres using a burner and an explosion bomb has revealed important aspects of turbulent premixed flame structure. Measurements at pressures and temperatures up to 1.25MPa and 673K in the two rigs were aimed at quantifying the influences of flame stretch rate and strain rate Markstein number, Masr , on both turbulent burning velocity and flame surface density. That on burning velocity is expressed through the stretch rate factor, Io , or probability of burning, Pb 0.5. These depend on Masr , but they grow in importance as the Karlovitz stretch factor, K, increases, and are evaluated from the associated burning velocity data. Planar laser tomography was employed to identify contours of reaction progress variable in both rigs. These enabled both an appropriate flame front for the measurement of the turbulent burning velocity to be identified, and flame surface densities, with the associated factors, to be evaluated. In the explosion measurements, these parameters were derived also from the flame surface area, the derived Pb 0.5 factor and the measured turbulent burning velocities. In the burner measurement they were calculated directly from the flame surface density, which was derived from the flame contours.A new overall correlation is derived for the Pb 0.5 factor, in terms of Masr at different K and this is discussed in the light of previous theoretical studies. The wrinkled flame surface area normalised by the area associated with the turbulent burning velocity measurement, and the ratio of turbulent to laminar burning velocity, ut /ul , are also evaluated. The higher the value of Pb0.5, the more effective is an increased flame wrinkling in increasing ut /ul A correlation of the product of k and the laminar flame thickness with Karlovitz stretch factor and Markstein number is explored using the present data and those of other workers. Some generality is revealed, enabling the wave length associated with the spatial change in mean

  10. Stretch rate effects and flame surface densities in premixed turbulent combustion up to 1.25 MPa

    KAUST Repository

    Bagdanavicius, Audrius; Bowen, Phil J.; Bradley, Derek; Lawes, Malcolm; Mansour, Morkous S.

    2015-01-01

    Independent research at two centres using a burner and an explosion bomb has revealed important aspects of turbulent premixed flame structure. Measurements at pressures and temperatures up to 1.25MPa and 673K in the two rigs were aimed at quantifying the influences of flame stretch rate and strain rate Markstein number, Masr , on both turbulent burning velocity and flame surface density. That on burning velocity is expressed through the stretch rate factor, Io , or probability of burning, Pb 0.5. These depend on Masr , but they grow in importance as the Karlovitz stretch factor, K, increases, and are evaluated from the associated burning velocity data. Planar laser tomography was employed to identify contours of reaction progress variable in both rigs. These enabled both an appropriate flame front for the measurement of the turbulent burning velocity to be identified, and flame surface densities, with the associated factors, to be evaluated. In the explosion measurements, these parameters were derived also from the flame surface area, the derived Pb 0.5 factor and the measured turbulent burning velocities. In the burner measurement they were calculated directly from the flame surface density, which was derived from the flame contours.A new overall correlation is derived for the Pb 0.5 factor, in terms of Masr at different K and this is discussed in the light of previous theoretical studies. The wrinkled flame surface area normalised by the area associated with the turbulent burning velocity measurement, and the ratio of turbulent to laminar burning velocity, ut /ul , are also evaluated. The higher the value of Pb0.5, the more effective is an increased flame wrinkling in increasing ut /ul A correlation of the product of k and the laminar flame thickness with Karlovitz stretch factor and Markstein number is explored using the present data and those of other workers. Some generality is revealed, enabling the wave length associated with the spatial change in mean

  11. Solubility of methane and carbon dioxide in ethylene glycol at pressures up to 14 MPa and temperatures ranging from (303 to 423) K

    International Nuclear Information System (INIS)

    Galvao, A.C.; Francesconi, A.Z.

    2010-01-01

    This work reports solubility data of methane and carbon dioxide in ethylene glycol and the Henry's law constant of each solute in the studied solvent at saturation pressure. The measurements were performed at (303, 323, 373, 398, and 423.15) K and pressures up to 6.3 MPa for mixtures containing carbon dioxide and pressures up to 13.7 MPa for mixtures containing methane. The experiments were performed in an autoclave type phase equilibrium apparatus using the total pressure method (synthetic method). All investigated systems show an increase of gas solubility with the increase of pressure. A decrease of carbon dioxide solubility with the increase of temperature and an increase of methane solubility with the increase of temperature was observed. From the variation of solubility with temperature, the partial molar enthalpy, and entropy change are calculated.

  12. Fast response, 2.5K psi (17.24 MPa) transducer for measurement of gas pressure in PWR fuel rods

    International Nuclear Information System (INIS)

    Piper, T.C.

    1976-09-01

    A strain gage pressure transducer of 2,500 psi (17.24 MPa) range for operation in a 650 0 F environment is described. Specific design parameters are given along with the calibration results obtained from typical transducers. Appendices delineate the bridge output to be expected and the actual open circuit value of a strain gage calculated from measurements taken with the bridge completed

  13. Effect of hot-dip galvanizing processes on the microstructure and mechanical properties of 600-MPa hot-dip galvanized dual-phase steel

    Science.gov (United States)

    Kuang, Chun-fu; Zheng, Zhi-wang; Wang, Min-li; Xu, Quan; Zhang, Shen-gen

    2017-12-01

    A C-Mn dual-phase steel was soaked at 800°C for 90 s and then either rapidly cooled to 450°C and held for 30 s (process A) or rapidly cooled to 350°C and then reheated to 450°C (process B) to simulate the hot-dip galvanizing process. The influence of the hot-dip galvanizing process on the microstructure and mechanical properties of 600-MPa hot-dip galvanized dual-phase steel (DP600) was investigated using optical microscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and tensile tests. The results showed that, in the case of process A, the microstructure of DP600 was composed of ferrite, martensite, and a small amount of bainite. The granular bainite was formed in the hot-dip galvanizing stage, and martensite islands were formed in the final cooling stage after hot-dip galvanizing. By contrast, in the case of process B, the microstructure of the DP600 was composed of ferrite, martensite, bainite, and cementite. In addition, compared with the yield strength (YS) of the DP600 annealed by process A, that for the DP600 annealed by process B increased by approximately 50 MPa because of the tempering of the martensite formed during rapid cooling. The work-hardening coefficient ( n value) of the DP600 steel annealed by process B clearly decreased because the increase of the YS affected the computation result for the n value. However, the ultimate tensile strength (UTS) and elongation ( A 80) of the DP600 annealed by process B exhibited less variation compared with those of the DP600 annealed by process A. Therefore, DP600 with excellent comprehensive mechanical properties (YS = 362 MPa, UTS = 638 MPa, A 80 = 24.3%, n = 0.17) was obtained via process A.

  14. The concept of an information analytical system monitoring of radiation situation and social-hygienic life conditions for residents in the areas influenced by Mayak production association (MPA)

    International Nuclear Information System (INIS)

    Kravtsova, E.M.; Kravtsova, O.S.

    1996-01-01

    The development of computerized informational-analytical system is started with the purpose to organize monitoring and to estimate radiation effect on population residing in the zone affected by MPA (1992). The data base includes a special information block containing social-economic characteristics. A specific feature of the method used to create the data base is the focus on the family connections. Currently the block meant for registration of environmental monitoring, in residential areas around Mayak plants has been developed most completely

  15. 30. MPA-Seminar 'Safety and reliability in energy technology' in conjunction with the 9th German-Japanese seminar. Vol. 2 (Papers 27-53)

    International Nuclear Information System (INIS)

    Roos, E.

    2004-01-01

    he 30th MPA-seminar on ''Safety and Availability in Energy Engineering'' was held in conjuction with the 9th German-Japanese Seminar. The 52 contributions were published in two volumes. Volume 1 contains the contributions to the following sessions: fracture mechanics, fatigue, welding, environmental impact and European research projects. Volume 2 contains contributions of sessions 6-9: high-temperature application, modelling-simulation, ageing management and non-destructive testing. (uke)

  16. 30. MPA-Seminar 'Safety and reliability in energy technology' in conjunction with the 9th German-Japanese seminar. Vol. 1 (Papers 1-26)

    International Nuclear Information System (INIS)

    Roos, E.

    2004-01-01

    The 30th MPA-seminar on ''Safety and Availability in Energy Engineering'' was held in conjuction with the 9th German-Japanese Seminar. The 52 contributions were published in two volumes. Volume 1 contains the contributions to the following sessions: fracture mechanics, fatigue, welding, environmental impact and European research projects. Volume 2 contains contributions of sessions 6-9: high-temperature application, modelling-simulation, ageing management and non-destructive testing. (uke)

  17. INTER-RATER RELIABILITY FOR MOVEMENT PATTERN ANALYSIS (MPA: MEASURING PATTERNING OF BEHAVIORS VERSUS DISCRETE BEHAVIOR COUNTS AS INDICATORS OF DECISION-MAKING STYLE

    Directory of Open Access Journals (Sweden)

    Brenda L Connors

    2014-06-01

    Full Text Available The unique yield of collecting observational data on human movement has received increasing attention in a number of domains, including the study of decision-making style. As such, interest has grown in the nuances of core methodological issues, including the best ways of assessing inter-rater reliability. In this paper we focus on one key topic – the distinction between establishing reliability for the patterning of behaviors as opposed to the computation of raw counts – and suggest that reliability for each be compared empirically rather than determined a priori. We illustrate by assessing inter-rater reliability for key outcome measures derived from Movement Pattern Analysis (MPA, an observational methodology that records body movements as indicators of decision-making style with demonstrated predictive validity. While reliability ranged from moderate to good for raw counts of behaviors reflecting each of two Overall Factors generated within MPA (Assertion and Perspective, inter-rater reliability for patterning (proportional indicators of each factor was significantly higher and excellent (ICC = .89. Furthermore, patterning, as compared to raw counts, provided better prediction of observable decision-making process assessed in the laboratory. These analyses support the utility of using an empirical approach to inform the consideration of measuring discrete behavioral counts versus patterning of behaviors when determining inter-rater reliability of observable behavior. They also speak to the substantial reliability that may be achieved via application of theoretically grounded observational systems such as MPA that reveal thinking and action motivations via visible movement patterns.

  18. Thermodynamic properties and equation of state of liquid di-isodecyl phthalate at temperature between (273 and 423) K and at pressures up to 140 MPa

    Energy Technology Data Exchange (ETDEWEB)

    Peleties, F. [Department of Chemical Engineering, Imperial College London, South Kensington Campus, London SW7 2AZ (United Kingdom); Segovia, J.J. [Grupo de Termodinamica y Calibracion (TERMOCAL), Dpto. Ingenieria Energetica y Fluidomecanica, E.T.S. de Ingenieros Industriales, Universidad de Valladolid, E-47011 Valladolid (Spain); Trusler, J.P.M., E-mail: m.trusler@imperial.ac.u [Department of Chemical Engineering, Imperial College London, South Kensington Campus, London SW7 2AZ (United Kingdom); Vega-Maza, D. [Grupo de Termodinamica y Calibracion (TERMOCAL), Dpto. Ingenieria Energetica y Fluidomecanica, E.T.S. de Ingenieros Industriales, Universidad de Valladolid, E-47011 Valladolid (Spain)

    2010-05-15

    We report measurements of the thermodynamic properties of liquid di-isodecyl phthalate (DIDP) and an equation of state determined therefrom. The speed of sound in DIDP was measured at temperatures between (293.15 and 413.15) K and a pressures between (0.1 and 140) MPa with a relative uncertainty of 0.1%. In addition, the isobaric specific heat capacity was measured at temperatures between (293.15 and 423.15) K at a pressure of 0.1 MPa with a relative uncertainty of 1%, and the density was measured at temperatures between (273.15 and 413.15) K at a pressure of 0.1 MPa with a relative uncertainty of 0.015%. The thermodynamic properties of DIDP were obtained from the measured speeds of sound by thermodynamic integration starting from the initial values of density and isobaric specific heat capacity obtained experimentally. The results have been represented by a new equation of state containing nine parameters with an uncertainty in density not worse than 0.025%. Comparisons with literature data are made.

  19. Calcium Sensitive Fluorescent Dyes Fluo-4 and Fura Red under Pressure: Behaviour of Fluorescence and Buffer Properties under Hydrostatic Pressures up to 200 MPa.

    Science.gov (United States)

    Schneidereit, D; Vass, H; Reischl, B; Allen, R J; Friedrich, O

    2016-01-01

    The fluorescent Ca2+ sensitive dyes Fura Red (ratiometric) and Fluo-4 (non-ratiometric) are widely utilized for the optical assessment of Ca2+ fluctuations in vitro as well as in situ. The fluorescent behavior of these dyes is strongly depends on temperature, pH, ionic strength and pressure. It is crucial to understand the response of these dyes to pressure when applying calcium imaging technologies in the field of high pressure bioscience. Therefore, we use an optically accessible pressure vessel to pressurize physiological Ca2+-buffered solutions at different fixed concentrations of free Ca2+ (1 nM to 25.6 μM) and a specified dye concentration (12 μM) to pressures of 200 MPa, and record dye fluorescence intensity. Our results show that Fluo-4 fluorescence intensity is reduced by 31% per 100 MPa, the intensity of Fura Red is reduced by 10% per 100 MPa. The mean reaction volume for the dissociation of calcium from the dye molecules [Formula: see text] is determined to -17.8 ml mol-1 for Fluo-4 and -21.3 ml mol-1 for Fura Red. Additionally, a model is presented that is used to correct for pressure-dependent changes in pH and binding affinity of Ca2+ to EGTA, as well as to determine the influence of these changes on dye fluorescence.

  20. Thermodynamic properties and equation of state of liquid di-isodecyl phthalate at temperature between (273 and 423) K and at pressures up to 140 MPa

    International Nuclear Information System (INIS)

    Peleties, F.; Segovia, J.J.; Trusler, J.P.M.; Vega-Maza, D.

    2010-01-01

    We report measurements of the thermodynamic properties of liquid di-isodecyl phthalate (DIDP) and an equation of state determined therefrom. The speed of sound in DIDP was measured at temperatures between (293.15 and 413.15) K and a pressures between (0.1 and 140) MPa with a relative uncertainty of 0.1%. In addition, the isobaric specific heat capacity was measured at temperatures between (293.15 and 423.15) K at a pressure of 0.1 MPa with a relative uncertainty of 1%, and the density was measured at temperatures between (273.15 and 413.15) K at a pressure of 0.1 MPa with a relative uncertainty of 0.015%. The thermodynamic properties of DIDP were obtained from the measured speeds of sound by thermodynamic integration starting from the initial values of density and isobaric specific heat capacity obtained experimentally. The results have been represented by a new equation of state containing nine parameters with an uncertainty in density not worse than 0.025%. Comparisons with literature data are made.

  1. Calcium Sensitive Fluorescent Dyes Fluo-4 and Fura Red under Pressure: Behaviour of Fluorescence and Buffer Properties under Hydrostatic Pressures up to 200 MPa

    Science.gov (United States)

    Vass, H.; Reischl, B.; Allen, R. J.; Friedrich, O.

    2016-01-01

    The fluorescent Ca2+ sensitive dyes Fura Red (ratiometric) and Fluo-4 (non-ratiometric) are widely utilized for the optical assessment of Ca2+ fluctuations in vitro as well as in situ. The fluorescent behavior of these dyes is strongly depends on temperature, pH, ionic strength and pressure. It is crucial to understand the response of these dyes to pressure when applying calcium imaging technologies in the field of high pressure bioscience. Therefore, we use an optically accessible pressure vessel to pressurize physiological Ca2+-buffered solutions at different fixed concentrations of free Ca2+ (1 nM to 25.6 μM) and a specified dye concentration (12 μM) to pressures of 200 MPa, and record dye fluorescence intensity. Our results show that Fluo-4 fluorescence intensity is reduced by 31% per 100 MPa, the intensity of Fura Red is reduced by 10% per 100 MPa. The mean reaction volume for the dissociation of calcium from the dye molecules Δdv¯ is determined to -17.8 ml mol-1 for Fluo-4 and -21.3 ml mol-1 for Fura Red. Additionally, a model is presented that is used to correct for pressure-dependent changes in pH and binding affinity of Ca2+ to EGTA, as well as to determine the influence of these changes on dye fluorescence. PMID:27764134

  2. Liquid density of biofuel mixtures: (Dibutyl ether + 1-butanol) system at pressures up to 140 MPa and temperatures from (293.15 to 393.15) K

    International Nuclear Information System (INIS)

    Alaoui, Fatima E.M.; Montero, Eduardo A.; Bazile, Jean-Patrick; Aguilar, Fernando; Boned, Christian

    2011-01-01

    Highlights: → New density data for binary mixtures of (dibutyl ether + 1-butanol) are reported. → The pressure and temperature intervals are 0.1 to 140 MPa and 293.15 to 393.15 K. → 445 Data points measured at five compositions were fitted to a Tait-like equation. → Excess volumes have been calculated from the experimental data. → The isobaric expansivity and the isothermal compressibility have been derived. - Abstract: This work reports new experimental density data (445 points) for binary mixtures of (dibutyl ether + 1-butanol) over the composition range (five compositions; 0.15 ≤ dibutyl ether mole fraction x ≤ 0.85), from (293.15 to 393.15) K (every 20 K), and for 15 pressures from (0.1 to 140) MPa (every 10 MPa). An Anton Paar vibrating tube densimeter, calibrated with an uncertainty of ±0.5 kg . m -3 was used to perform these measurements. The experimental density data were fitted with a Tait-like equation with low standard deviations. Excess volumes have been calculated from the experimental data and fitted by the Redlich-Kister equation. In addition, the isobaric thermal expansivity and the isothermal compressibility have been derived from the Tait-like equation.

  3. Liquid density of biofuel mixtures: (Dibutyl ether + 1-butanol) system at pressures up to 140 MPa and temperatures from (293.15 to 393.15) K

    Energy Technology Data Exchange (ETDEWEB)

    Alaoui, Fatima E.M. [Laboratoire des Fluides Complexes, Faculte des Sciences et Techniques, UMR CNRS 5150, Universite de Pau, BP 1155, 64013 Pau Cedex (France); Departamento de Ingenieria Electromecanica, Escuela Politecnica Superior, Universidad de Burgos, E-09006 Burgos (Spain); Montero, Eduardo A., E-mail: emontero@ubu.es [Departamento de Ingenieria Electromecanica, Escuela Politecnica Superior, Universidad de Burgos, E-09006 Burgos (Spain); Bazile, Jean-Patrick [Laboratoire des Fluides Complexes, Faculte des Sciences et Techniques, UMR CNRS 5150, Universite de Pau, BP 1155, 64013 Pau Cedex (France); Aguilar, Fernando [Departamento de Ingenieria Electromecanica, Escuela Politecnica Superior, Universidad de Burgos, E-09006 Burgos (Spain); Boned, Christian [Laboratoire des Fluides Complexes, Faculte des Sciences et Techniques, UMR CNRS 5150, Universite de Pau, BP 1155, 64013 Pau Cedex (France)

    2011-11-15

    Highlights: > New density data for binary mixtures of (dibutyl ether + 1-butanol) are reported. > The pressure and temperature intervals are 0.1 to 140 MPa and 293.15 to 393.15 K. > 445 Data points measured at five compositions were fitted to a Tait-like equation. > Excess volumes have been calculated from the experimental data. > The isobaric expansivity and the isothermal compressibility have been derived. - Abstract: This work reports new experimental density data (445 points) for binary mixtures of (dibutyl ether + 1-butanol) over the composition range (five compositions; 0.15 {<=} dibutyl ether mole fraction x {<=} 0.85), from (293.15 to 393.15) K (every 20 K), and for 15 pressures from (0.1 to 140) MPa (every 10 MPa). An Anton Paar vibrating tube densimeter, calibrated with an uncertainty of {+-}0.5 kg . m{sup -3} was used to perform these measurements. The experimental density data were fitted with a Tait-like equation with low standard deviations. Excess volumes have been calculated from the experimental data and fitted by the Redlich-Kister equation. In addition, the isobaric thermal expansivity and the isothermal compressibility have been derived from the Tait-like equation.

  4. Accurate (p, ρ, T) data for two new (carbon dioxide + nitrogen) mixtures from (250 to 400) K at pressures up to 20 MPa

    International Nuclear Information System (INIS)

    Mondéjar, M.E.; Villamañán, R.M.; Span, R.; Chamorro, C.R.

    2012-01-01

    Highlights: ► New (p, ρ, T) data of two mixtures of nitrogen and carbon dioxide are reported. ► Experimental data show a disagreement with the equation of state at low temperatures and high pressures. ► Relative deviations in density increase with the carbon dioxide molar fraction of the mixture. ► Only relative deviations at pressures below 10 MPa are within a 0.1% band. - Abstract: Recently our group published a set of (p, ρ, T) data for two (carbon dioxide + nitrogen) mixtures with a low carbon dioxide content (x CO 2 =0.10,0.15). These data showed larger relative deviations from the GERG-2008 equation of state than expected, specially at low temperatures, high pressures, and for the mixture with higher carbon dioxide content (x CO 2 =0.15). In order to analyze whether the mentioned deviations from the equation of state increase with the carbon dioxide content, it was decided to measure the (p, ρ, T) behavior of two additional mixtures with higher carbon dioxide molar fractions (x CO 2 =0.20,0.50). The new experimental data show again an appreciable disagreement with the GERG-2008 equation of state at low temperatures and high pressures. Relative deviations, which depend on temperature, arise to 0.4% at 250 K and 20 MPa and to 0.24% at 275 K and 20 MPa for the x CO 2 =0.20 and x CO 2 =0.50 mixture, respectively. Second virial coefficients are calculated for the two new mixtures presented in this work and also for those presented in our previous paper.

  5. Phase equilibrium measurements of (methane + benzene) and (methane + methylbenzene) at temperatures from (188 to 348) K and pressures to 13 MPa

    International Nuclear Information System (INIS)

    Hughes, Thomas J.; Kandil, Mohamed E.; Graham, Brendan F.; Marsh, Kenneth N.; Huang, Stanley H.; May, Eric F.

    2015-01-01

    Highlights: • VLE data for (CH 4 (1) + C 6 H 6 (2)) and (CH 4 (1) + C 6 H 5 CH 3 (3)) were measured. • LLE was observed at T = 198.15 K, a T higher than expected, for (CH 4 + C 6 H 5 CH 3 ) . • Inconsistences in the literature data were identified and assessed. • More data at x 1 > 0.3 for both systems are needed to investigate discrepancies. - Abstract: New isothermal pTxy data are reported for (methane + benzene) and (methane + methylbenzene (toluene)) at pressures up to 13 MPa over the temperature range (188 to 313) K using a custom-built (vapor + liquid) equilibrium (VLE) apparatus. The aim of this work was to investigate literature data inconsistencies and to extend the measurements to lower temperatures. For (methane (1) + benzene (2)), measurements were made along six isotherms from (233 to 348) K at pressures to 9.6 MPa. At temperatures below 279 K there was evidence of a solid phase, and thus only vapor phase samples were analyzed at these temperatures. For the (methane (1) + methylbenzene (3)) system, measurements were made along seven isotherms from T = (188 to 313) K at pressures up to 13 MPa. Along the 198 K isotherm, a significant change in the data’s p,x slope was observed indicating (liquid + liquid) equilibria at higher pressures. The data were compared with literature data and with calculations made using the Peng–Robinson (PR) equation of state (EOS). For both binary systems our data agree with much of the literature data that also deviate from the EOS in a similar manner. However, the data of Elbishlawi and Spencer (1951) for both binary systems, which appear to have received an equal weighting to other data in the EOS development, are inconsistent with the results of our measurements and data from other literature sources

  6. Determination of Temperature Rise and Temperature Differentials of CEMII/B-V Cement for 20MPa Mass Concrete using Adiabatic Temperature Rise Data

    Science.gov (United States)

    Chee Siang, GO

    2017-07-01

    Experimental test was carried out to determine the temperature rise characteristics of Portland-Fly-Ash Cement (CEM II/B-V, 42.5N) of Blaine fineness 418.6m2/kg and 444.6m2/kg respectively for 20MPa mass concrete under adiabatic condition. The estimation on adiabatic temperature rise by way of CIRIA C660 method (Construction Industry Research & Information Information) was adopted to verify and validate the hot-box test results by simulating the heat generation curve of the concrete under semi-adiabatic condition. Test result found that Portland fly-ash cement has exhibited decrease in the peak value of temperature rise and maximum temperature rise rate. The result showed that the temperature development and distribution profile, which is directly contributed from the heat of hydration of cement with time, is affected by the insulation, initial placing temperature, geometry and size of concrete mass. The mock up data showing the measured temperature differential is significantly lower than the technical specifications 20°C temperature differential requirement and the 27.7°C limiting temperature differential for granite aggregate concrete as stipulated in BS8110-2: 1985. The concrete strength test result revealed that the 28 days cubes compressive strength was above the stipulated 20MPa characteristic strength at 90 days. The test demonstrated that with proper concrete mix design, the use of Portland flyash cement, combination of chilled water and flake ice, and good insulation is effective in reducing peak temperature rise, temperature differential, and lower adiabatic temperature rise for mass concrete pours. As far as the determined adiabatic temperature rise result was concern, the established result could be inferred for in-situ thermal properties of 20MPa mass concrete application, as the result could be repeatable on account of similar type of constituent materials and concrete mix design adopted for permanent works at project site.

  7. Experimental study on spray break-up and atomization processes from GDI injector using high injection pressure up to 30 MPa

    International Nuclear Information System (INIS)

    Lee, Sanghoon; Park, Sungwook

    2014-01-01

    Highlights: • We obtain distribution of droplet velocity and diameter using PDPA system. • Transition of a jet break-up processes is visualized using Nd:Yag sheet laser system. • Elevated injection pressure can activate a jet break-up processes. • A limit in injection pressure to enhance droplet atomization is observed. -- Abstract: This paper focuses on the influence of injection pressures up to 30 MPa on single liquid jet break-up and atomization processes. For this purpose, a single jet from a multi-hole GDI injector has been characterized performing visualization and PDPA (phase Doppler particle analyzer) experiments. Using a thin sheet of light generated by a Nd:Yag laser and capturing a sequence of jet development images with a CCD camera, the internal structure was visualized. In order to quantify the droplet diameter and velocity, a 2-D PDPA system were carried out in addition to the spray visualization. Analyzing the images of the internal structure of jet and the result of PDPA, including droplet diameter and velocity distribution with increasing injection pressure up to 30 MPa, the elevated injection pressure on a jet break-up and atomization was characterized. Our experimental results show the existence of a leading edge of the jet observed at the initial stage of injection. This phenomenon revealed relatively large droplets ahead of the main jet then disappeared quickly as lose the droplets momentum. Furthermore, for all injection pressures, unique ‘branch-like structure’ was observed when the jet was fully developed. This structure had many counter rotating branches related to the effect of air-entrainment and rapidly broken down into droplet clusters and droplets. Especially, as increased injection pressure, the time to exhibit the structure and distance between two branches were decreased. In addition, based on the results of droplet diameter and velocity distribution at various injection pressures, we confirmed that the injection

  8. Measurements of the viscosity of carbon dioxide at temperatures from (253.15 to 473.15) K with pressures up to 1.2 MPa

    International Nuclear Information System (INIS)

    Schäfer, Michael; Richter, Markus; Span, Roland

    2015-01-01

    Highlights: • A new rotating-body viscometer for the low-pressure region was presented. • A viscosity dependent offset was compensated by calibrating the viscometer. • The viscosity of carbon dioxide was measured at low pressures. • Measurements were carried out from T = (253.15 to 473.15) K with p ≤ 1.2 MPa. • The relative expanded combined uncertainty (k = 2) was U r,c (η) = (0.20 to 0.41)%. - Abstract: The viscosity of carbon dioxide was measured over the temperature range T = (253.15 to 473.15) K with pressures up to 1.2 MPa utilizing a new rotating-body viscometer. The relative expanded combined uncertainty (k = 2) in viscosity (including uncertainties of temperature and pressure) was (0.20 to 0.41)%. The instrument was specifically designed for measurements at low gas densities and enables measurements of the dynamic viscosity at temperatures between T = 253.15 K and T = 473.15 K with pressures up to 2 MPa. For carbon dioxide, the fluid specific measuring range with regard to pressure was limited to 1.2 MPa due to the formation of disturbing vortices inside the measuring cell at higher pressures. The model function for the viscosity measurement was extended in such a way that the dynamic viscosity was measured relative to helium. Therefore, the influence of the geometry of the concentric cylindrical system inside the measuring cell became almost negligible. Moreover, a systematic offset resulting from a small but inevitable eccentricity of the cylindrical system was compensated for. The residual damping, usually measured in vacuum, was calibrated in the entire temperature range using viscosity values of helium, neon and argon calculated ab initio; at T = 298.15 K recommended reference values were used. A viscosity dependent offset of the measured viscosities, which was observed in previously published data, did not occur when using the calibrated residual damping. The new carbon dioxide results were compared to other experimental literature data

  9. Ternary Vapor–Liquid Equilibrium Measurements and Modeling of Ethylene Glycol (1) + Water (2) + Methane (3) Systems at 6 and 12.5 MPa

    DEFF Research Database (Denmark)

    Kruger, Francois J.; Danielsen, Marie V.; Kontogeorgis, Georgios M.

    2018-01-01

    Novel technologies in the field of subsea gasprocessing include the development of natural gas dehydration facilities, which may operate at high pressure due to their proximity to reservoirs. For the qualification and design of these processing units, ternary vapor−liquid equilibrium data...... are required to validate the thermodynamic models used in the design process. For this purpose, 16 new ternary data points were measured for ethylene glycol (1) + water (2) + methane (3) at 6.0 and 12.5 MPa with temperatures ranging from 288to 323 K and glycol content above 90 wt %. Glycol in gas (y1),water...

  10. Neutron sample cell suitable for the diffraction of aligned biomaterials and capable of exerting up to 370 MPa of hydrostatic pressure

    International Nuclear Information System (INIS)

    Watson, M.J.; Nieh, M.-P.; Harroun, T.A.; Katsaras, J.

    2003-01-01

    We describe a temperature controlled sample cell suitable for the study of biomimetic materials (e.g., lipid bilayers) using neutron diffraction, and capable of exerting hydrostatic pressures of up to 370 MPa. The advantage of this sample cell, compared to previous high-pressure cells of its type, is that it allows for the use of samples aligned on a solid support which, compared to 'powder' or so-called liposomal preparations, requires only small amounts of sample and allows for the clear differentiation between in-plane and out-of-plane structure

  11. WSC-2: a subchannel dryout correlation for water-cooled clusters over the pressure range 3.4-15.9 MPA (500-2300 PSIA)

    International Nuclear Information System (INIS)

    Bowring, R.W.

    1979-05-01

    WSC-2 is a subchannel dryout correlation for use with subchannel analysis computer codes such as HAMBO. It was optimised from 1074 experimental data points from 54 clusters simulating Pressure Tube Reactor, BWR and PWR geometries and covering the pressure range 3.4-15.9 MPa. The correlation errors were(a) PWR - type data: RMS 8.8%, Mean 0.2%,(b) all classes of data: RMS 7.2%, Mean - 0.3%. This represents a significant improvement over the other correlations used for reactor assessment with which it has been compared. (author)

  12. Microstructure Evolution and Mechanical Properties of Underwater Dry and Local Dry Cavity Welded Joints of 690 MPa Grade High Strength Steel.

    Science.gov (United States)

    Shi, Yonghua; Sun, Kun; Cui, Shuwan; Zeng, Min; Yi, Jianglong; Shen, Xiaoqin; Yi, Yaoyong

    2018-01-22

    Q690E high strength low alloy (HSLA) steel plays an important role in offshore structures. In addition, underwater local cavity welding (ULCW) technique was widely used to repair important offshore constructions. However, the high cooling rate of ULCW joints results in bad welding quality compared with underwater dry welding (UDW) joints. Q690E high strength low alloy steels were welded by multi-pass UDW and ULCW techniques, to study the microstructural evolution and mechanical properties of underwater welded joints. The microstructure and fracture morphology of welded joints were observed by scanning electron microscope and optical microscope. The elemental distribution in the microstructure was determined with an Electron Probe Microanalyzer. The results indicated that the microstructure of both two welded joints was similar. However, martensite and martensite-austenite components were significantly different with different underwater welding methods such that the micro-hardness of the HAZ and FZ in the ULCW specimen was higher than that of the corresponding regions in UDW joint. The yield strength and ultimate tensile strength of the ULCW specimen are 109 MPa lower and 77 MPa lower, respectively, than those of the UDW joint. The impact toughness of the UDW joint was superior to those of the ULCW joint.

  13. Densities and derived thermodynamic properties of 1-heptanol and 2-heptanol at temperatures from 313 K to 363 K and pressures up to 22 MPa

    Energy Technology Data Exchange (ETDEWEB)

    Zuniga-Moreno, Abel [Laboratorio de Termodinamica, ESIQIE, Instituto Politecnico Nacional, Edif. Z, Secc. 6, 1er piso, UPALM Zacatenco, 07738 Lindavista, Mexico, D.F. (Mexico); Galicia-Luna, Luis A. [Laboratorio de Termodinamica, ESIQIE, Instituto Politecnico Nacional, Edif. Z, Secc. 6, 1er piso, UPALM Zacatenco, 07738 Lindavista, Mexico, D.F. (Mexico)], E-mail: lgalicial@ipn.mx; Betancourt-Cardenas, Felix F. [Laboratorio de Termodinamica, ESIQIE, Instituto Politecnico Nacional, Edif. Z, Secc. 6, 1er piso, UPALM Zacatenco, 07738 Lindavista, Mexico, D.F. (Mexico)

    2008-01-15

    Experimental densities were determined in liquid phase for 1-heptanol and 2-heptanol at temperatures from 313 K to 363 K and pressures up to 22 MPa using a vibrating tube densimeter. Water and nitrogen were used as reference fluids for the calibration of the vibrating tube densimeter. The uncertainties of the experimental measurements in the whole range of reported data are estimated to be {+-}0.03 K for temperature, {+-}0.008 MPa for pressure, and {+-}0.20 kg . m{sup -3} for density. The experimental data are correlated using a short empirical equation of six parameters and the 11-parameter Benedict-Webb-Rubin-Starling equation of state (BWRS EoS) using a least square optimization. Statistical values to evaluate the different correlations are reported. Published density data of 1-heptanol are compared with values calculated with the 6-parameter equation using the parameters obtained in this work. The experimental data determined here are also compared with an available correlation for 1-heptanol. Densities of 2-heptanol at high pressure were not found in the literature and the data reported here represent the first set of data reported in the literature. Isothermal compressibilities and isobaric thermal expansivity are calculated using the 6-parameter equation for both alcohols within uncertainties estimated to be {+-}0.025 Gpa{sup -1} and {+-}4 x 10{sup -7} K{sup -1}, respectively.

  14. Partial molar volumes of organic solutes in water. XXVIII. Three aliphatic poly(ethylene glycols) at temperatures T = 298 K–573 K and pressures up to 30 MPa

    International Nuclear Information System (INIS)

    Cibulka, Ivan

    2017-01-01

    Highlights: • Standard molar volumes of three poly(ethylene glycols) in water are presented. • Data were obtained in the range T from (298 to 573) K and p up to 30 MPa. • Data are analyzed and compared with those of similar solutes. - Abstract: Densities of dilute aqueous solutions of three poly(ethylene glycols): 3-oxapentane-1,5-diol (diethylene glycol), 3,6-dioxaoctane-1,8-diol (triethylene glycol), and 3,5,9-trioxaundecane-1,11-diol (tetraethylene glycol) measured in the temperature range from (298 to 573) K and at pressures up to 30 MPa using an automated flow vibrating-tube densimeter are reported. Standard molar volumes were evaluated from the measured data. Present data complement both the previous measurements performed at atmospheric pressure in the temperature range from (278 to 343) K and the data already available for the first member of the homologous series (ethylene glycol). A comparison with data previously measured for the homologous series of linear aliphatic polyethers (poly(ethylene glycol) dimethyl ethers, glymes), diethylene glycol monomethyl ether (3,6-dioxaheptan-1-ol), and selected alkane-α,ω-diols is presented.

  15. Densities and derived thermodynamic properties of 1-heptanol and 2-heptanol at temperatures from 313 K to 363 K and pressures up to 22 MPa

    International Nuclear Information System (INIS)

    Zuniga-Moreno, Abel; Galicia-Luna, Luis A.; Betancourt-Cardenas, Felix F.

    2008-01-01

    Experimental densities were determined in liquid phase for 1-heptanol and 2-heptanol at temperatures from 313 K to 363 K and pressures up to 22 MPa using a vibrating tube densimeter. Water and nitrogen were used as reference fluids for the calibration of the vibrating tube densimeter. The uncertainties of the experimental measurements in the whole range of reported data are estimated to be ±0.03 K for temperature, ±0.008 MPa for pressure, and ±0.20 kg . m -3 for density. The experimental data are correlated using a short empirical equation of six parameters and the 11-parameter Benedict-Webb-Rubin-Starling equation of state (BWRS EoS) using a least square optimization. Statistical values to evaluate the different correlations are reported. Published density data of 1-heptanol are compared with values calculated with the 6-parameter equation using the parameters obtained in this work. The experimental data determined here are also compared with an available correlation for 1-heptanol. Densities of 2-heptanol at high pressure were not found in the literature and the data reported here represent the first set of data reported in the literature. Isothermal compressibilities and isobaric thermal expansivity are calculated using the 6-parameter equation for both alcohols within uncertainties estimated to be ±0.025 Gpa -1 and ±4 x 10 -7 K -1 , respectively

  16. Partial molar volumes of organic solutes in water. XXIII. Cyclic ketones at T = (298 to 573) K and pressures up to 30 MPa

    International Nuclear Information System (INIS)

    Cibulka, Ivan; Simurka, Lukas; Hnedkovsky, Lubomir; Bolotov, Alexander

    2011-01-01

    Research highlights: → In this study we examine standard molar volumes of aqueous cyclic ketones. → State parameters of measurements were (298 to 573) K and pressures up to 30 MPa. → Differences in behavior of monoketones and cyclohexane-1,4-dione were observed. → Group contribution method was designed and examined. - Abstract: Density data for dilute aqueous solutions of four cyclic ketones (cyclopentanone, cyclohexanone, cycloheptanone, and cyclohexane-1,4-dione) are presented together with standard molar volumes (partial molar volumes at infinite dilution) calculated from the experimental data. The measurements were performed at temperatures from T = 298 K up to T = 573 K. Experimental pressures were close to the saturated vapor pressure of water, and (15 and 30) MPa. The data were obtained using a high-temperature high-pressure flow vibrating-tube densimeter. Experimental standard molar volumes were correlated as a function of temperature and pressure using an empirical polynomial function. Contributions of the molecular structural segments (methylene and carbonyl groups) to the standard molar volume were also evaluated and analyzed.

  17. Partial molar volumes of organic solutes in water. XXVII. Two aliphatic polyethers (triglyme, tetraglyme) at temperatures T = 298–573 K and pressures up to 30 MPa

    International Nuclear Information System (INIS)

    Cibulka, Ivan

    2016-01-01

    Highlights: • Standard molar volumes of two linear aliphatic polyethers in water are presented. • Data were obtained in the range T from (298 to 573) K and p up to 30 MPa. • Data combined with those obtained previously are analyzed and compared with standard molar volumes of cyclic ethers. - Abstract: Densities of dilute aqueous solutions of two linear aliphatic polyethers: 2,5,8,11-tetraoxadodecane (triethylene glycol dimethyl ether, triglyme) and 2,5,8,11,14-pentaoxapentadecane (tetraethylene glycol dimethyl ether, tetraglyme), measured in the temperature range from (298 to 573) K and at pressures up to 30 MPa using an automated flow vibrating-tube densimeter are reported. Standard molar volumes were evaluated from the measured data. The present values complement previous measurements performed for the title polyethers at atmospheric pressure in the temperature range from (278 to 343) K and extend the knowledge to temperature and pressure ranges in which the data on standard molar volumes for lower members of the homologous series (monoglyme, diglyme) are already available.

  18. Microstructure Evolution and Mechanical Properties of Underwater Dry and Local Dry Cavity Welded Joints of 690 MPa Grade High Strength Steel

    Science.gov (United States)

    Sun, Kun; Cui, Shuwan; Zeng, Min; Yi, Jianglong; Shen, Xiaoqin; Yi, Yaoyong

    2018-01-01

    Q690E high strength low alloy (HSLA) steel plays an important role in offshore structures. In addition, underwater local cavity welding (ULCW) technique was widely used to repair important offshore constructions. However, the high cooling rate of ULCW joints results in bad welding quality compared with underwater dry welding (UDW) joints. Q690E high strength low alloy steels were welded by multi-pass UDW and ULCW techniques, to study the microstructural evolution and mechanical properties of underwater welded joints. The microstructure and fracture morphology of welded joints were observed by scanning electron microscope and optical microscope. The elemental distribution in the microstructure was determined with an Electron Probe Microanalyzer. The results indicated that the microstructure of both two welded joints was similar. However, martensite and martensite-austenite components were significantly different with different underwater welding methods such that the micro-hardness of the HAZ and FZ in the ULCW specimen was higher than that of the corresponding regions in UDW joint. The yield strength and ultimate tensile strength of the ULCW specimen are 109 MPa lower and 77 MPa lower, respectively, than those of the UDW joint. The impact toughness of the UDW joint was superior to those of the ULCW joint. PMID:29361743

  19. Macro Pixel ASIC (MPA): The readout ASIC for the pixel-strip (PS) module of the CMS outer tracker at HL-LHC

    CERN Document Server

    Ceresa, Davide; Kloukinas, Konstantinos; Jan Kaplon; Bialas, Wojciech; Re, Valerio; Traversi, Gianluca; Gaioni, Luigi; Ratti, Lodovico

    2014-01-01

    The CMS tracker at HL-LHC is required to provide prompt information on particles with high transverse momentum to the central Level\\,1 trigger. For this purpose, the innermost part of the outer tracker is based on a combination of a pixelated sensor with a short strip sensor, the so-called Pixel-Strip module (PS). The readout of these sensors is carried out by distinct ASICs, the Strip Sensor ASIC (SSA), for the strip layer, and the Macro Pixel ASIC (MPA) for the pixel layer. The processing of the data directly on the front-end module represents a design challenge due to the large data volume (30720\\,pixels and 1920\\,strips per module) and the limited power budget. This is the reason why several studies have been carried out to find the best compromise between ASICs performance and power consumption. This paper describes the current status of the MPA ASIC development where the logic for generating prompt information on particles with high transverse momentum is implemented. An overview of the readout method i...

  20. Time-resolved interaction of seawater with gabbro: An experimental study of rare-earth element behavior up to 475 °C, 100 MPa

    Science.gov (United States)

    Beermann, Oliver; Garbe-Schönberg, Dieter; Bach, Wolfgang; Holzheid, Astrid

    2017-01-01

    High metal and rare-earth element (REE) concentrations with unusual ('atypical') normalized REE patterns are documented in fluids from active hydrothermal vent fields on the Mid-Atlantic Ridge, 5°S and the East Scotia Ridge. Those fluids show relative enrichment of middle heavy REEs and almost no Eu anomalies in chondrite-normalized patterns. To understand the processes that produce such atypical REE patterns we ran a series of experiments, in which natural bottom seawater or aqueous solutions (NaCl, NaCl-MgCl2, or NaCl-CaCl2) were reacted with gabbro and gabbro mineral assemblages from 300 to 475 °C and 40 and 100 MPa. These P-T conditions are representative for water-rock interactions in hydrothermal root and discharge zones. Fluid flux variability and kinetics were addressed in the experiments by varying the water-to-rock mass ratio (w/r) from 0.5-10 and using different run durations from 3-720 h. Only seawater and synthetic MgCl2-bearing fluid mobilized significant amounts of REEs, Si, Ca, Fe, and Mn from gabbro, from clinopyroxene, and from plagioclase. At 425 °C and 40 MPa, fluids were initially acidic with pH (25 °C) of ∼2 increasing to values between ∼4 and 7 upon progressing reactions. Rare earth element and Fe contents peaked within 3-6 h after interaction with gabbroic mineral grains (125-500 μm) at w/r of 5 (REEs) and 2-5 (Fe) but decreased with continuing reaction without strong REE fractionation. Most of the REEs that were leached from primary minerals and dissolved in the fluids early became redeposited into solid reaction products after 720 h. Contents of dissolved SiO2 were pressure-dependent, being about twofold higher at 100 MPa than at 40 MPa (425 °C) and were below quartz saturation with gabbro and clinopyroxene as solid starting material and close to quartz saturation with plagioclase reactant. However, Si in fluids from the rock-dominated experiments at 100 MPa with gabbro (w/r 0.5-1) dropped to very low contents. A concomitant

  1. 30. MPA-Seminar 'Safety and reliability in energy technology' in conjunction with the 9th German-Japanese seminar. Vol. 1 (Papers 1-26); 30. MPA-Seminar 'Sicherheit und Verfuegbarkeit in der Energietechnik' in Verbindung mit dem 9. Deutsch-Japanischen Seminar. Bd. 1 (Vortraege 1-26)

    Energy Technology Data Exchange (ETDEWEB)

    Roos, E. (comp.)

    2004-07-01

    The 30th MPA-seminar on ''Safety and Availability in Energy Engineering'' was held in conjuction with the 9th German-Japanese Seminar. The 52 contributions were published in two volumes. Volume 1 contains the contributions to the following sessions: fracture mechanics, fatigue, welding, environmental impact and European research projects. Volume 2 contains contributions of sessions 6-9: high-temperature application, modelling-simulation, ageing management and non-destructive testing. (uke)

  2. 30. MPA-Seminar 'Safety and reliability in energy technology' in conjunction with the 9th German-Japanese seminar. Vol. 2 (Papers 27-53); 30. MPA-Seminar 'Sicherheit und Verfuegbarkeit in der Energietechnik' in Verbindung mit dem 9. Deutsch-Japanischen Seminar. Bd. 2 (Vortraege 27-53)

    Energy Technology Data Exchange (ETDEWEB)

    Roos, E. (comp.)

    2004-07-01

    he 30th MPA-seminar on ''Safety and Availability in Energy Engineering'' was held in conjuction with the 9th German-Japanese Seminar. The 52 contributions were published in two volumes. Volume 1 contains the contributions to the following sessions: fracture mechanics, fatigue, welding, environmental impact and European research projects. Volume 2 contains contributions of sessions 6-9: high-temperature application, modelling-simulation, ageing management and non-destructive testing. (uke)

  3. 32. MPA seminar 2006. Lectures; 32. MPA Seminar 2006. Vortraege

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    This conference CD contains the full text of 47 papers on the following subjects: 1. Ageing management; 2. Integrity analysis; 3. Materials engineering; 4. State monitoring; 5. Pressure equipment status monitoring; 6. Quality assurance; 7. Non-destructive testing; 8. Fracture-mechanical analysis of components. [German] Diese Tagungs-CD enthaelt den Text von 47 Vortraegen mit folgenden Themenschwerpunkten: 1. Alterungsmanagement; 2. Integritaetsanalyse; 3. Werkstofftechnik; 4. Zustandsueberwachung; 5. Beschaffenheit Druckgeraete; 6. Qualitaetssicherung; 7. Zerstoerungsfreie Pruefung; und 8. Bruchmechanische Bauteilanalyse.

  4. Effect of Welding Heat Input on the Microstructure and Toughness in Simulated CGHAZ of 800 MPa-Grade Steel for Hydropower Penstocks

    Directory of Open Access Journals (Sweden)

    Qingfeng Ding

    2017-03-01

    Full Text Available To determine the appropriate welding heat input for simulated coarse grained heat affected zone (CGHAZ of 800 MPa-grade steel used in hydropower penstocks, the microstructural evolution, hardness, and 50% fraction appearance transition temperature (50% FATT were investigated. The results indicated that when the cooling rate (heat input is reduced (increased, the impact toughness at −20 °C and hardness of the simulated CGHAZ decreased. When the heat input increased from 18 to 81 kJ/cm, the 50% FATT increased from −80 °C to −11 °C. At 18 kJ/cm, the microstructures consisted of lath bainite and granular bainite, but lath bainite decreased with increasing heat input. The increase in the 50% FATT was attributed mainly to an increase in the austenite grain size and effective grain size, and a decrease in lath bainite and the fraction of HAGBs (misorientation: ≥15°.

  5. Isobaric specific heat capacity of water and aqueous cesium chloride solutions for temperatures between 298 K and 370 K at p = 0.1 MPa

    International Nuclear Information System (INIS)

    Lourenco, M.J.V.; Santos, F.J.V.; Ramires, M.L.V.; Nieto de Castro, C.A.

    2006-01-01

    There has been some controversy regarding the uncertainty of measurements of thermal properties using differential scanning calorimeters, namely heat capacity of liquids. A differential scanning calorimeter calibrated in enthalpy and temperature was used to measure the isobaric specific heat capacity of water and aqueous solutions of cesium chloride, in the temperature range 298 K to 370 K, for molalities up 3.2 mol . kg -1 , at p = 0.1 MPa, with an estimated uncertainty (ISO definition) better than 1.1%, at a 95% confidence level. The measurements are completely traceable to SI units of energy and temperature. The results obtained were correlated as a function of temperature and molality and compared with other authors, obtained by different methods and permit to conclude that a DSC calibrated by Joule effect is capable of very accurate measurements of the isobaric heat capacity of liquids, traceable to SI units of measurement

  6. A simple and facile synthesis of MPA capped CdSe and CdSe/CdS core/shell nanoparticles

    Science.gov (United States)

    Sukanya, D.; Sagayaraj, P.

    2015-06-01

    II-VI semiconductor nanostructures, in particular, CdSe quantum dots have drawn a lot of attention because of their promising potential applications in biological tagging, photovoltaic, display devices etc. due to their excellent optical properties, high emission quantum yield, size dependent emission wavelength and high photostability. In this paper, we describe the synthesis and properties of mercaptopropionic acid capped CdSe and CdSe/CdS nanoparticles through a simple and efficient co-precipitation method followed by hydrothermal treatment. The growth process, characterization and the optical absorption as a function of wavelength for the synthesized MPA capped CdSe and CdSe/CdS nanoparticles have been determined using X-ray diffraction study (XRD), Ultraviolet-Visible spectroscopy (UV-Vis), Fourier transform infrared spectroscopy (FT-IR) and High Resolution Transmission Electron Microscopy (HRTEM).

  7. A simple and facile synthesis of MPA capped CdSe and CdSe/CdS core/shell nanoparticles

    International Nuclear Information System (INIS)

    Sukanya, D.; Sagayaraj, P.

    2015-01-01

    II-VI semiconductor nanostructures, in particular, CdSe quantum dots have drawn a lot of attention because of their promising potential applications in biological tagging, photovoltaic, display devices etc. due to their excellent optical properties, high emission quantum yield, size dependent emission wavelength and high photostability. In this paper, we describe the synthesis and properties of mercaptopropionic acid capped CdSe and CdSe/CdS nanoparticles through a simple and efficient co-precipitation method followed by hydrothermal treatment. The growth process, characterization and the optical absorption as a function of wavelength for the synthesized MPA capped CdSe and CdSe/CdS nanoparticles have been determined using X-ray diffraction study (XRD), Ultraviolet-Visible spectroscopy (UV-Vis), Fourier transform infrared spectroscopy (FT-IR) and High Resolution Transmission Electron Microscopy (HRTEM)

  8. New generation of full composite vessels for 70 MPa gaseous hydrogen storage : results and achievements of the French HyBou project

    Energy Technology Data Exchange (ETDEWEB)

    Nony, F. [CEA Materials, Monts (France); Weber, M. [Air Liquide, Paris (France); Tcharkhtchi, A. [Ecole Nationale Superieure d' Arts et Metiers, Paris (France); Lafarie-Frenot, M.C. [Ecole Nationale Superique De Mecanique et d' Aerotechnique, Poitiers (France); Perrier, O. [Raigi, Arbouville (France)

    2009-07-01

    The French collaborative Project known as HyBou explores hydrogen storage as a key enabling technology for the extensive use of hydrogen as an energy carrier. HyBou aims to develop robust, safe and efficient compressed gaseous hydrogen (CGH2) storage systems and validate innovative materials and processes suitable for storage vessel manufacturing with improved performance at low cost. The development of a new generation of type-4 70 MPa vessel was described along with a newly developed liner based on polyurethane materials. The new liner presents increased thermal stability, hydrogen barrier properties and cost effectiveness. The project also aims to evaluate the potential of new high resistance fibers and develop an improved thermosetting resin for composite winding with enhanced mechanical resistance and durability. A specific apparatus was therefore designed to characterize and evaluate coupled thermal and mechanical fatigue resistance in representative conditions.

  9. Compressed liquid densities of 1-butanol and 2-butanol at temperatures from 313 K to 363 K and pressures up to 25 MPa

    Energy Technology Data Exchange (ETDEWEB)

    Zuniga-Moreno, Abel [Laboratorio de Termodinamica, ESIQIE, Instituto Politecnico Nacional, Edif. Z, Secc. 6, 1ER Piso, UPALM, C.P. 07738, Mexico, D.F. (Mexico); Galicia-Luna, Luis A. [Laboratorio de Termodinamica, ESIQIE, Instituto Politecnico Nacional, Edif. Z, Secc. 6, 1ER Piso, UPALM, C.P. 07738, Mexico, D.F. (Mexico)]. E-mail: lgalicial@ipn.mx; Camacho-Camacho, Luis E. [Laboratorio de Termodinamica, ESIQIE, Instituto Politecnico Nacional, Edif. Z, Secc. 6, 1ER Piso, UPALM, C.P. 07738, Mexico, D.F. (Mexico)

    2007-02-15

    (p, {rho}, T) properties were determined in liquid phase for 1-butanol and 2-butanol at temperatures from 313 K to 363 K and pressures up to 25 MPa using a vibrating tube densimeter. The uncertainty is estimated to be lower than {+-}0.2 kg . m{sup -3} for the experimental densities. Nitrogen and water were used as reference fluids for the calibration of the vibrating tube densimeter. Experimental densities of 1-butanol and 2-butanol were correlated with a short empirical equation and the 11-parameter Benedict-Webb-Rubin-Starling equation of state (BWRS EoS) using a least square optimization. Statistical values to evaluate the different correlations were reported. Published densities of 1-butanol and 2-butanol are compared with values calculated with the BWRS EoS using the parameters obtained in this work. The experimental data determined here are also compared with available correlations for 1-butanol and 2-butanol.

  10. (Vapor + liquid) equilibrium data for (carbon dioxide + 1,1-difluoroethane) system at temperatures from (258 to 343) K and pressures up to about 8 MPa

    International Nuclear Information System (INIS)

    Madani, Hakim; Valtz, Alain; Coquelet, Christophe; Meniai, Abdeslam Hassen; Richon, Dominique

    2008-01-01

    Accurate thermo-physical data are of utmost interest for the development of new efficient refrigeration systems. Carbon dioxide (R744) and 1,1-difluoroethane (R152a) are addressed here. Isothermal (vapor + liquid) equilibrium data are reported herein for (R744 + R152a) binary system in the (258-343) K temperature range and in the (0.14 to 7.65) MPa pressure range. A reliable 'static-analytic' method taking advantage of two online ROLSI TM micro capillary samplers is used for all thermodynamic measurements. The data are correlated using our in-house ThermoSoft thermodynamic model using the Peng-Robinson equation of state, the Mathias-Copeman alpha function, the Wong-Sandler mixing rules, and the NRTL model

  11. Compressed liquid densities of 1-butanol and 2-butanol at temperatures from 313 K to 363 K and pressures up to 25 MPa

    International Nuclear Information System (INIS)

    Zuniga-Moreno, Abel; Galicia-Luna, Luis A.; Camacho-Camacho, Luis E.

    2007-01-01

    (p, ρ, T) properties were determined in liquid phase for 1-butanol and 2-butanol at temperatures from 313 K to 363 K and pressures up to 25 MPa using a vibrating tube densimeter. The uncertainty is estimated to be lower than ±0.2 kg . m -3 for the experimental densities. Nitrogen and water were used as reference fluids for the calibration of the vibrating tube densimeter. Experimental densities of 1-butanol and 2-butanol were correlated with a short empirical equation and the 11-parameter Benedict-Webb-Rubin-Starling equation of state (BWRS EoS) using a least square optimization. Statistical values to evaluate the different correlations were reported. Published densities of 1-butanol and 2-butanol are compared with values calculated with the BWRS EoS using the parameters obtained in this work. The experimental data determined here are also compared with available correlations for 1-butanol and 2-butanol

  12. Effects of Nb on microstructure and continuous cooling transformation of coarse grain heat-affected zone in 610 MPa class high-strength low-alloy structural steels

    International Nuclear Information System (INIS)

    Zhang, Y.Q.; Zhang, H.Q.; Liu, W.M.; Hou, H.

    2009-01-01

    Continuous cooling transformation diagrams of the coarse grain heat-affected zone and microstructure after continuous cooling were investigated for 610 MPa class high-strength low-alloy (HSLA) structural steels with and without niobium. For the steel without Nb, grain boundary ferrite, degenerate pearlite and acicular ferrite are produced at slower cooling rates. Bainite phase is formed at faster cooling rates. However, for the steel with Nb, granular bainite is dominant at a large range of cooling rates. At cooling rates 32 K/s, Nb addition has no obvious influence on transformation start temperature, but it influences microstructure transformation significantly. Martensite is observed in steel with Nb at faster cooling rates, but not produced in steel without Nb

  13. (Pressure + volume + temperature) properties for binary oligomeric solutions of poly(ethylene glycol mono-4-octylphenyl ether) with 1-octanol or acetophenone at pressures up to 50 MPa

    International Nuclear Information System (INIS)

    Lee, M.-J.; Ku, T.-J.; Lin Homu

    2009-01-01

    Densities were measured with a high-pressure densitometer for two binary oligomeric systems of poly(ethylene glycol mono-4-octylphenyl ether) (PEGOPE) with 1-octanol or acetophenone at temperatures from 298.15 K to 348.15 K and pressures up to 50 MPa. While the excess volumes are negative in (acetophenone + PEGOPE) over the entire composition range, those are found to change from positive to negative with increasing mole fraction of the solvent in (1-octanol + PEGOPE). The pressure-effect on the liquid densities can be represented accurately by the Tait equation. Moreover, an empirical equation with two characteristic parameters correlates well the PVT data over the entire experimental conditions for each binary system. The experimental specific volumes were also correlated with the Flory-Orwoll-Vrij (FOV) and the Schotte equations of state to within the experimental uncertainty.

  14. Micro-Raman spectroscopy studies of changes in lipid composition in breast and prostate cancer cells treated with MPA and R1881 hormones

    Science.gov (United States)

    Potcoava, Mariana C.; Futia, Gregory L.; Aughenbaugh, Jessica; Schlaepfer, Isabel; Gibson, Emily A.

    2014-03-01

    Increasing interest in the role of lipids in cancer cell proliferation or resistance to drug therapies has motivated the need to develop better tools for cellular lipid analysis. Quantification of lipids in cells is typically done by destructive chromatography protocols that do not provide spatial information on lipid distribution and prevent dynamic live cell studies. Methods that allow the analysis of lipid content in live cells is therefore of great importance for research. Using Raman micro-spectroscopy we investigated whether the female hormone medroxyprogesterone acetate (MPA) and the synthetic androgen R1881 affect the lipid expression in breast (T47D) and prostate (LNCaP) cancer cells. Differences were noted in the spectral regions at 830-1800 cm-1 and 2800-3000 cm-1 when comparing different drug treatments. Significant changes were noticed for saturated (1063 - 1125 cm-1, 1295 cm-1 and 1439 cm-1), unsaturated (1262 cm-1 and 1656 cm-1, and 1720 - 1748 cm-1) chemical bonds, suggesting that the composition of the lipid droplets was changed by the hormone treatments. Also, significant differences were observed in the high frequency regions of lipids and proteins at 2851 cm-1 and around 2890 cm-1. Principal component analysis with Linear Discriminant Analysis (PCA-LDA) of the Raman spectra was able to differentiate between cancer cells that were treated with MPA, R1881 or vehicle (P < 0.05). Future work includes analysis to determine exact lipid composition and concentrations as well as development of clinical techniques to characterize differences in patient tumor lipid profiles to determine response to drug treatment and prognosis.

  15. Main: MPA5 [TP Atlas

    Lifescience Database Archive (English)

    Full Text Available ion people suffer from African trypanosomiasis, sleeping sickness, caused by Tryp...rasitic protozoan trypanosomes. A half million people suffer from African trypanosomiasis, sleep

  16. Main: MPA1 [TP Atlas

    Lifescience Database Archive (English)

    Full Text Available Nucleic acids (DNA and RNA) are found to induce the innate immunity - We will elucidate detailed molecular m...Rapid advances in our understanding of innate immune systems, which provide immediate defense agai...sistance effects in mice. We would like to elucidate detailed molecular mechanism

  17. Main: MPA4 [TP Atlas

    Lifescience Database Archive (English)

    Full Text Available t for Alzheimer's disease Alzheimer's disease: γ-secretase Taisuke Tomita Graduate School of Pharmaceutical ...ing both the entire γ-secretase complex and the ectodomain of nicastrin - We have identified novel compounds

  18. MPA Materials Matter October 2015

    Energy Technology Data Exchange (ETDEWEB)

    Kippen, Karen Elizabeth [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-10-20

    In support of the U.S. Department of Energy’s (DOE) Technology-to-Market activities in the Office of Energy Efficiency and Renewable Energy, Fuel Cell Technology Office, Los Alamos researchers hosted the hands-on short course on fuel cells. The DOE’s Technology-to-Market activities efforts place emphasis on national laboratories increasing their industrial contacts, engaging more companies, and developing technology skills.

  19. 32. MPA seminar 2006. Lectures

    International Nuclear Information System (INIS)

    2006-01-01

    This conference CD contains the full text of 47 papers on the following subjects: 1. Ageing management; 2. Integrity analysis; 3. Materials engineering; 4. State monitoring; 5. Pressure equipment status monitoring; 6. Quality assurance; 7. Non-destructive testing; 8. Fracture-mechanical analysis of components [de

  20. Saturated phase densities of (CO_2 + H_2O) at temperatures from (293 to 450) K and pressures up to 64 MPa

    International Nuclear Information System (INIS)

    Efika, Emmanuel C.; Hoballah, Rayane; Li, Xuesong; May, Eric F.; Nania, Manuela; Sanchez-Vicente, Yolanda; Martin Trusler, J.P.

    2016-01-01

    Highlights: • Saturated phase densities of CO_2 + H_2O were measured with a 1.5 kg · m"−"3 uncertainty. • Aqueous phase densities can be predicted within 3 kg · m"−"3 using empirical models. • The CO_2-rich phase density was within 8 kg · m"−"3 of pure CO_2 at the same (p, T). • The cubic EOS of Spycher and Pruess deviates from the data by up to about 8 kg · m"−"3. - Abstract: An apparatus consisting of an equilibrium cell connected to two vibrating tube densimeters and two syringe pumps was used to measure the saturated phase densities of (CO_2 + H_2O) at temperatures from (293 to 450) K and pressures up to 64 MPa, with estimated average standard uncertainties of 1.5 kg · m"−"3 for the CO_2-rich phase and 1.0 kg · m"−"3 for the aqueous phase. The densimeters were housed in the same thermostat as the equilibrium cell and were calibrated in situ using pure water, CO_2 and helium. Following mixing, samples of each saturated phase were displaced sequentially at constant pressure from the equilibrium cell into the vibrating tube densimeters connected to the top (CO_2-rich phase) and bottom (aqueous phase) of the cell. The aqueous phase densities are predicted to within 3 kg · m"−"3 using empirical models for the phase compositions and partial molar volumes of each component. However, a recently developed multi-parameter equation of state (EOS) for this binary mixture, Gernert and Span [32], was found to under predict the measured aqueous phase density by up to 13 kg · m"−"3. The density of the CO_2-rich phase was always within about 8 kg · m"−"3 of the density for pure CO_2 at the same pressure and temperature; the differences were most positive near the critical density, and became negative at temperatures above about 373 K and pressures below about 10 MPa. For this phase, the multi-parameter EOS of Gernert and Span describes the measured densities to within 5 kg · m"−"3, whereas the computationally-efficient cubic EOS model of

  1. In Situ Raman Spectral Characteristics of Carbon Dioxide in a Deep-Sea Simulator of Extreme Environments Reaching 300 ℃ and 30 MPa.

    Science.gov (United States)

    Li, Lianfu; Du, Zengfeng; Zhang, Xin; Xi, Shichuan; Wang, Bing; Luan, Zhendong; Lian, Chao; Yan, Jun

    2018-01-01

    Deep-sea carbon dioxide (CO 2 ) plays a significant role in the global carbon cycle and directly affects the living environment of marine organisms. In situ Raman detection technology is an effective approach to study the behavior of deep-sea CO 2 . However, the Raman spectral characteristics of CO 2 can be affected by the environment, thus restricting the phase identification and quantitative analysis of CO 2 . In order to study the Raman spectral characteristics of CO 2 in extreme environments (up to 300 ℃ and 30 MPa), which cover most regions of hydrothermal vents and cold seeps around the world, a deep-sea extreme environment simulator was developed. The Raman spectra of CO 2 in different phases were obtained with Raman insertion probe (RiP) system, which was also used in in situ Raman detection in the deep sea carried by remotely operated vehicle (ROV) "Faxian". The Raman frequency shifts and bandwidths of gaseous, liquid, solid, and supercritical CO 2 and the CO 2 -H 2 O system were determined with the simulator. In our experiments (0-300 ℃ and 0-30 MPa), the peak positions of the symmetric stretching modes of gaseous CO 2, liquid CO 2 , and supercritical CO 2 shift approximately 0.6 cm -1 (1387.8-1388.4 cm -1 ), 0.7 cm -1 (1385.5-1386.2 cm -1 ), and 2.5 cm -1 (1385.7-1388.2 cm -1 ), and those of the bending modes shift about 1.0 cm -1 (1284.7-1285.7 cm -1 ), 1.9 cm -1 (1280.1-1282.0 cm -1 ), and 4.4 cm -1 (1281.0-1285.4 cm -1 ), respectively. The Raman spectral characteristics of the CO 2 -H 2 O system were also studied under the same conditions. The peak positions of dissolved CO 2 varied approximately 4.5 cm -1 (1282.5-1287.0 cm -1 ) and 2.4 cm -1 (1274.4-1276.8 cm -1 ) for each peak. In comparison with our experiment results, the phases of CO 2 in extreme conditions (0-3000 m and 0-300 ℃) can be identified with the Raman spectra collected in situ. This qualitative research on CO 2 can also support the

  2. The structure of liquid water up to 360 MPa from x-ray diffraction measurements using a high Q-range and from molecular simulation

    Energy Technology Data Exchange (ETDEWEB)

    Skinner, L. B. [X-Ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Mineral Physics Institute, Stony Brook University, Stony Brook, New York, New York 11794-2100 (United States); Galib, M.; Fulton, J. L., E-mail: John.Fulton@pnnl.gov, E-mail: benmore@anl.gov; Mundy, C. J.; Schenter, G. K. [Physical and Computational Sciences Division, Pacific Northwest National Laboratory, Richland, Washington 99354 (United States); Parise, J. B. [Mineral Physics Institute, Stony Brook University, Stony Brook, New York, New York 11794-2100 (United States); Department of Geosciences, Stony Brook University, Stony Brook, New York, New York 11794-2100 (United States); Photon Sciences Division, Brookhaven National Laboratory, Upton, New York 11973 (United States); Pham, V.-T. [Synchrotron SOLEIL, L’Orme des Merisiers, Saint-Aubin, BP48, 91192 Gif-sur-Yvette (France); Center for Quantum Electronics, Institute of Physics, Vietnam Academy of Science and Technology, P.O. Box 429, Boho, Hanoi 10000 (Viet Nam); Benmore, C. J., E-mail: John.Fulton@pnnl.gov, E-mail: benmore@anl.gov [X-Ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)

    2016-04-07

    X-ray diffraction measurements of liquid water are reported at pressures up to 360 MPa corresponding to a density of 0.0373 molecules per Å{sup 3}. The measurements were conducted at a spatial resolution corresponding to Q{sub max} = 16 Å{sup −1}. The method of data analysis and measurement in this study follows the earlier benchmark results reported for water under ambient conditions having a density of 0.0333 molecules per Å{sup 3} and Q{sub max} = 20 Å{sup −1} [J. Chem. Phys. 138, 074506 (2013)] and at 70 °C having a density of 0.0327 molecules per Å{sup 3} and Q{sub max} = 20 Å{sup −1} [J. Chem. Phys. 141, 214507 (2014)]. The structure of water is very different at these three different T and P state points and thus they provide the basis for evaluating the fidelity of molecular simulation. Measurements show that at 360 MPa, the 4 waters residing in the region between 2.3 and 3 Å are nearly unchanged: the peak position, shape, and coordination number are nearly identical to their values under ambient conditions. However, in the region above 3 Å, large structural changes occur with the collapse of the well-defined 2nd shell and shifting of higher shells to shorter distances. The measured structure is compared to simulated structure using intermolecular potentials described by both first-principles methods (revPBE-D3) and classical potentials (TIP4P/2005, MB-pol, and mW). The DFT-based, revPBE-D3, method and the many-body empirical potential model, MB-pol, provide the best overall representation of the ambient, high-temperature, and high-pressure data. The revPBE-D3, MB-pol, and the TIP4P/2005 models capture the densification mechanism, whereby the non-bonded 5th nearest neighbor molecule, which partially encroaches the 1st shell at ambient pressure, is pushed further into the local tetrahedral arrangement at higher pressures by the more distant molecules filling the void space in the network between the 1st and 2nd shells.

  3. Viscosity of n-hexadecane, n-octadecane and n-eicosane at pressures up to 243 MPa and temperatures up to 534 K

    International Nuclear Information System (INIS)

    Baled, Hseen O.; Xing, Dazun; Katz, Harrison; Tapriyal, Deepak; Gamwo, Isaac K.; Soong, Yee; Bamgbade, Babatunde A.; Wu, Yue; Liu, Kun; McHugh, Mark A.; Enick, Robert M.

    2014-01-01

    Highlights: • A novel windowed Inconel rolling-ball viscometer is designed and used by our team. • Viscosity data are reported for n-hexadecane, n-octadecane, and n-eicosane at high temperatures and pressures. • The viscosity results are compared with the available literature data. • The viscosity results are modeled with the free volume theory model. - Abstract: Viscosity data are reported for n-hexadecane (C16), n-octadecane (C18), and n-eicosane (C20) at pressures between (3 and 243) MPa and temperatures between (304 and 534) K. These extreme conditions are representative of those encountered in ultra-deep petroleum formations beneath the deepwaters of the Gulf of Mexico. The measurements are taken with a novel windowed Inconel rolling-ball viscometer designed by our team that is calibrated with n-decane. A comparison of the reported viscosity values with the available literature data that cover limited pressure and temperature ranges, shows that the mean absolute percentage deviation, δ, ranges between 1.1% and 4.8%. The reported data extend the database of viscosity to the high-temperature, high-pressure region where most gaps occur in the literature data for n-hexadecane and n-octadecane. To the best of our knowledge, the results for n-eicosane are the first reported viscosity values at pressures above 2 MPa over the entire temperature range. The viscosity results are modeled with the free volume theory model in conjunction with density values obtained using the Peng–Robinson equation of state (EoS) and the PC-SAFT EoS. The δ values obtained with this model range from 2.0% to 3.5%. The data are also correlated by a non-linear surface fit as a simultaneous function of temperature and pressure that yields δ values of 0.40%, 0.43%, and 0.38% for C16, C18, and C20, respectively

  4. In vivo positron emission tomography studies on the novel nicotinic receptor agonist [11C]MPA compared with [11C]ABT-418 and (S)(-)[11C]nicotine in Rhesus monkeys

    International Nuclear Information System (INIS)

    Sihver, Wiebke; Fasth, Karl-Johan; Oegren, Matthias; Lundqvist, Hans; Bergstroem, Mats; Watanabe, Yasuyoshi; Laangstroem, Bengt; Nordberg, Agneta

    1999-01-01

    The novel 11 C-labeled nicotinic agonist (R,S)-1-[ 11 C]methyl-2(3-pyridyl)azetidine ([ 11 C]MPA) was evaluated as a positron emission tomography (PET) ligand for in vivo characterization of nicotinic acetylcholine receptors in the brain of Rhesus monkeys in comparison with the nicotinic ligands (S)-3-methyl-5-(1-[ 11 C]methyl-2-pyrrolidinyl)isoxazol ([ 11 C]ABT-418) and (S)(-)[ 11 C]nicotine. The nicotinic receptor agonist [ 11 C]MPA demonstrated rapid uptake into the brain to a similar extent as (S)(-) [ 11 C]nicotine and [ 11 C]ABT-418. When unlabeled (S)(-)nicotine (0.02 mg/kg) was administered 5 min before the radioactive tracers, the uptake of [ 11 C]MPA was decreased by 25% in the thalamus, 19% in the temporal cortex, and 11% in the cerebellum, whereas an increase was found for the uptake of (S)(-)[ 11 C]nicotine and [ 11 C]ABT-418. This finding indicates specific binding of [ 11 C]MPA to nicotinic receptors in the brain in a simple classical displacement study. [ 11 C]MPA seems to be a more promising radiotracer than (S)(-)[ 11 C]nicotine or [ 11 C]ABT-418 for PET studies to characterize nicotinic receptors in the brain

  5. Compressed liquid densities and excess molar volumes for (CO2 + 1-pentanol) binary system at temperatures from 313 to 363 K and pressures up to 25 MPa

    International Nuclear Information System (INIS)

    Zuniga-Moreno, Abel; Galicia-Luna, Luis A.; Sandler, Stanley I.

    2008-01-01

    Measurements of compressed liquid densities for 1-pentanol and for {CO 2 (1) + 1-pentanol (2)} system were carried out at temperatures from 313 K to 363 K and pressures up to 25 MPa. Densities were measured for binary mixtures at 10 different compositions, x 1 = 0.0816, 0.1347, 0.3624, 0.4651, 0.6054, 0.7274, 0.8067, 0.8573, 0.9216, and 0.9757. A vibrating tube densimeter was used to perform density measurements using two reference calibration fluids. The uncertainty is estimated to be better than ±0.2 kg . m -3 for the experimental density measurements. For each mixture and for 1-pentanol, the experimental densities were correlated using an explicit volume equation of six parameters and an 11-parameter equation of state (EoS). Excess molar volumes were determined for the (CO 2 + 1-pentanol) system using 1-pentanol densities calculated from the 11-parameter EoS and CO 2 densities calculated from a multiparameter reference EoS

  6. A comparative study of the microstructure and properties of 800 MPa microalloyed C-Mn steel welded joints by laser and gas metal arc welding

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Qian [The State Key Laboratory of Rolling and Automation of Northeastern University, Shenyang 110819 (China); Di, Hong-Shuang, E-mail: hongshuangdi_ral@126.com [The State Key Laboratory of Rolling and Automation of Northeastern University, Shenyang 110819 (China); Li, Jun-Chen [The State Key Laboratory of Rolling and Automation of Northeastern University, Shenyang 110819 (China); Wu, Bao-Qiang [National Key Laboratory for Precision Hot Processing of Metals, Harbin Institute of Technology, Harbin 150001 (China); Misra, R.D.K. [Laboratory for Excellence in Advanced Steel Research, Department of Metallurgical, Material and Biomedical Engineering, University of Texas at El Paso, TX 79968 (United States)

    2016-07-04

    The differences in microstructure and mechanical properties of laser beam welded (LBW) and gas metal arc welded (GMAW) joints of 800 MPa grade Nb-Ti-Mo microalloyed C-Mn steel of 5 mm thickness were studied. The study suggested that the microstructure in welded seam (WS) of GMAW was acicular ferrite and fine grained ferrite, whereas lath martensite (LM) was obtained in WS of LBW, where inclusions were finer and did not act as nucleation sites for acicular ferrite. The microstructure of coarse-grained HAZ (CGHAZ) obtained using the two welding methods was LM and granular bainite (GB), respectively. The original austenite grain size in CGHAZ of LBW was 1/3 of GMAW. The microstructure of fine-grained HAZ and mixed-grained HAZ using the two welding methods was ferrite and M-A constituents, while that of LBW was significantly fine. The hardness of LBW welded joints was higher than the base metal (BM), which was the initiation site for tensile fracture. The tensile fracture location of GMAW welded joints was in WS. The impact toughness of LBW welded joints was excellent and the impact absorption energy was similar to BM.

  7. Application results of a prototype ultrasonic liquid film sensor to a 7 MPa steam-water two-phase flow experiment

    International Nuclear Information System (INIS)

    Aoyama, Goro; Fujimoto, Kiyoshi; Katono, Kenichi; Nagayoshi, Takuji; Baba, Atsushi; Yasuda, Kenichi

    2016-01-01

    A prototype ultrasonic liquid film sensor was applied to a high-temperature steam-water two-phase flow experiment. The liquid film sensor was vertically installed in a loop which was connected to HUSTLE, a multi-purpose steam source test facility. The hydraulic diameter of the measurement section was 9.4 mm. The output waveforms of the sensor were acquired with a digital oscilloscope. The fluid temperature and system pressure were kept at 288°C and 7.2 MPa, respectively, during the experiment. The pulse-echo method was used to calculate the liquid film thickness. The cross-correlation calculation was utilized to determine the time difference between the pulse reflected at the sensor surface and the pulse reflected at the liquid film surface. The time-averaged liquid film thicknesses were less than 0.055 mm in the annular flow condition. The increase of the time-averaged thickness was small with the change of the gas momentum flux. The film thicknesses measured with the sensor were compared with the past experimental results; the former were smaller than one-fourth of the thickness estimated as the mean film thickness. The comparison results suggested that the continuous liquid sublayer thickness was measured with the liquid film sensor. (author)

  8. Experimental determination of heat transfer coefficients in roll bite and air cooling for computer simulations of 1100 MPa carbon steel rolling

    Science.gov (United States)

    Leinonen, Olli; Ilmola, Joonas; Seppälä, Oskari; Pohjonen, Aarne; Paavola, Jussi; Koskenniska, Sami; Larkiola, Jari

    2018-05-01

    In modeling of hot rolling pass schedules the heat transfer phenomena have to be known. Radiation to ambient, between rolls and a steel slab as well as heat transfer in contacts must be considered to achieve accurate temperature distribution and thereby accurate material behavior in simulations. Additional heat is generated by friction between the slab and the work roll and by plastic deformation. These phenomena must be taken into account when the effective heat transfer coefficient is determined from experimental data. In this paper we determine the effective heat transfer coefficient at the contact interface and emissivity factor of slab surface for 1100MPa strength carbon steel for hot rolling simulations. Experimental pilot rolling test were carried out and slab temperatures gathered right below the interface and at the mid thickness of the slab. Emissivity factor tests were carried out in the same manner but without rolling. Experimental data is utilized to derive contact heat transfer coefficient at the interface and emissivity factor of slab surface. Pilot rolling test is reproduced in FE-analysis to further refine the heat transfer coefficient and emissivity factor. Material mechanical properties at rolling temperatures were determined by Gleeble™ thermo-mechanical simulator and IDS thermodynamic-kinetic-empirical software.

  9. Structure–property relationship in a 960 MPa grade ultrahigh strength low carbon niobium–vanadium microalloyed steel: The significance of high frequency induction tempering

    International Nuclear Information System (INIS)

    Xie, Z.J.; Fang, Y.P.; Han, G.; Guo, H.; Misra, R.D.K.; Shang, C.J.

    2014-01-01

    The present study describes the microstructure and precipitation behavior in an ultra-high strength low carbon niobium–vanadium microalloyed steel that was processed by quenching and high frequency induction tempering. Ultrahigh yield strength of ∼1000 MPa with high elongation of ∼15% and high low temperature toughness of 55 J (half thickness) at −40 °C was obtained after quenching from austenitization at 900 °C for 30 min, and tempering at 600 °C for 15 min by induction reheating with a reheating rate of ∼50 °C/s. While the yield strength increase on tempering was similar for both induction reheating and conventional reheating (electrical resistance reheating), there was ∼100% increase in low temperature toughness in induction reheated steel compared to the conventional reheating process. The underlying reason for the increase in toughness was attributed to the transformation of cementite film observed in conventional reheating and tempering to nanoscale cementite in induction reheating and tempering. The precipitation of nanoscale carbides is believed to significantly contribute to ultra-high strength, good ductility, and high toughness in the high frequency induction reheating and tempering process

  10. History and practice of material research on the examples of Material Testing and Materialpruefungsanstalt (MPA) Stuttgart, liquid crystals and screen technology as well as superconductivity. An interdisciplinary teaching project of the University of Stuttgart; Geschichte und Praxis der Materialforschung an den Beispielen Materialpruefung und Materialpruefungsanstalt (MPA) Stuttgart, Fluessigkristalle und Bildschirmtechnik sowie Supraleitung. Ein interdisziplinaeres Lehrprojekt der Universitaet Stuttgart

    Energy Technology Data Exchange (ETDEWEB)

    Hentschel, Klaus; Webel, Josef (eds.)

    2016-07-01

    The knowledge of material research and its history is not very common among scientists and engineers alike. Within the scope of an interdisciplinary teaching project carried out for the first time in the summer semester 2014 and ever since then every summer semester at the University of Stuttgart, an attempt is made to approach material research both from a scientific, technical and historical perspective. The Material Testing and Materials Testing Institute in Stuttgart (MPA), the liquid crystals and the screen technology as well as the superconductivity were selected as topics, which have a long tradition in research and teaching in Stuttgart. In this anthology the materials of the teaching project are summarized. [German] Das Wissen um die Materialforschung und ihre Geschichte ist selbst unter Naturwissenschaftlern und Ingenieuren wenig verbreitet. Im Rahmen eines erstmals im Sommersemester 2014 und seither dann jedes Sommersemester an der Universitaet Stuttgart durchgefuehrten interdisziplinaeren Lehrprojektes wird deshalb der Versuch unternommen, sich der Materialforschung sowohl aus naturwissenschaftlicher und technischer als auch aus historischer Perspektive anzunaehern. Als Themenbereiche wurden dafuer die Materialpruefung und Materialpruefungsanstalt (MPA) Stuttgart, die Fluessigkristalle und die Bildschirmtechnik sowie die Supraleitung ausgewaehlt, die in Stuttgart auf eine lange Tradition in Forschung und Lehre zurueckblicken. Im vorliegenden Sammelband sind die Materialien des Lehrprojektes zusammengefasst.

  11. Adaptation of a Freon-12 CHF correlation to apply for water in uniformly heated vertical tubes. Part 2: Based on CHF data for water at pressures in the range 6-20 MPa

    International Nuclear Information System (INIS)

    Green, W.J.

    1982-03-01

    An examination of more than 5000 sets of experimental data for critical heat flux (CHF) in uniformly heated vertical tubes internally cooled by high pressure water has shown that the CHF correlation proposed in Part 1 of this work is accurate for water at pressures up to approximately 17 MPa, provided that minor modifications are made to the Prandtl number index, and the saturation boiling length function. For pressures greater than 17 MPa, CHF values calculated from the correlation are increasingly lower than the experimental data, particularly at low saturation boiling length ratios ( -1 m -2 or thermal equilibrium exit qualities are less than 0.1

  12. Evaluation at 290 degrees Celsius and 8 MPa of the anticorrosion properties of hydrothermal ceramic nano deposits on preoxidized 304l Ss

    Energy Technology Data Exchange (ETDEWEB)

    Lopez G, N.; Marin A, M.; Medina A, A. L. [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico); Galicia A, G., E-mail: natali_log@hotmail.com [Universidad Veracruzana, Instituto de Ingenieria, Av. Juan Pablo II s/n, Fracc. Costa Verde, 94294 Boca del Rio, Veracruz (Mexico)

    2017-09-15

    In the present paper, we present the electrochemical evaluation carried out under reductive conditions (molar ratio H{sub 2}:O{sub 2} >5), at 290 degrees Celsius and 8 MPa, of preoxidized 304l Ss with hydrothermal deposits of nanoparticles of TiO{sub 2} and ZrO{sub 2}. The anticorrosion properties of the deposits were studied by Electrochemical Impedance Spectroscopy (EIS) and Linear Polarization Resistance (LPR). After electrochemical tests, the samples were characterized by X-Ray Diffraction (XRD) and Scanning Electron Microscopy (Sem). It was found by EIS that both, ZrO{sub 2} and TiO{sub 2} produce an increase in the charge transfer resistance (R{sub CT}) of preoxidized 304l Ss. At the same time, by LPR we observed that the studied ceramic nano deposits decrease the corrosion rate (Cr) and corrosion current density (i{sub corr}), however, in most of the cases the Electrochemical Corrosion Potential (Ecp) is slightly higher in the presence of the ceramic nano deposits that the one of preoxidized 304l Ss. After holding time at 290 degrees Celsius, when the impedance (Z) increases, the capacitance increases also, which is attributed to a surface increase due to the roughness of the oxide formed at this temperature under a reductive environment. The observed electrochemical behavior has a dependence on the homogeneity and thickness of the deposits, as has been corroborated by Sem and XRD. The best electrochemical results are obtained when two conditions are fulfilled: The bigger the effective coated area and the lower the deposit thickness. (Author)

  13. Diffusion coefficients for Tl, Pb, Cd, In, Zn, Bi, As, Mo and Sb in hydrous rhyolite at 100-200 MPa

    Science.gov (United States)

    Berlo, Kim; Brooker, Richard; Wilke, Max

    2014-05-01

    A series of experiments have been conducted to determine the diffusivities of Tl, Pb, Cd, In, Zn, Bi, As, Mo and Sb in hydrous rhyolitic melt. Diffusion experiments used two adjoining glass cylinder of the same hydrous composition, one doped with the elements of interest at ~ 100 ppm. These couples were rapidly heated to 850, 1000 and 1150°C at 100-200 MPa for a few hours. After quenching the sectioned charges were analyzed by both synchrotron XRF (The Diamond Light Source) and LA-ICP-MS (University of Oxford). The data shows excellent correlation between these two techniques. The diffusion profiles were fitted to a 1-D diffusion couple equation to determine the diffusivities and fitting to the different temperature runs defined the Arrhenius parameters. We find that for 850°C the diffusion coefficients follow the trend Tl>Pb>Cd>Zn>In>Bi>As>Sb>Mo. Additional experiments were performed with either S or Cl added (to both sides of the diffusion couple). In general S increases the diffusion rate of all metals except Mo and Sb, which diffuse slower in the presence of S. Chlorine also speeds up the diffusion of metals with the exception of In, Mo and Sb. The systematic change in diffusivities of these metals and their different behaviour in the presence of the ligands that are also observed to be significant in volcanic gases, are important in determining the distribution of these metals during degassing (e.g. MacKenzie and Canil, 2008). This is particularly important in a dynamic environment such as a volcanic conduit. There are also implications for economic exploration and well as hazard mitigation.

  14. New (p, {rho}, T) data for carbon dioxide - Nitrogen mixtures from (250 to 400) K at pressures up to 20 MPa

    Energy Technology Data Exchange (ETDEWEB)

    Mondejar, M.E.; Martin, M.C. [Grupo de Termodinamica y Calibracion (TERMOCAL), Dpto. Ingenieria Energetica y Fluidomecanica, Escuela de Ingenierias Industriales, Universidad de Valladolid, Paseo del Cauce, 59, E-47011 Valladolid (Spain); Span, R. [Lehrstuhl fuer Thermodynamik, Fakultaet fuer Maschinenbau Gebaeude IB, Ebene 5, Ruhr-Universitaet Bochum, Universitaetsstr. 150, 44780 Bochum (Germany); Chamorro, C.R., E-mail: cescha@eis.uva.es [Grupo de Termodinamica y Calibracion (TERMOCAL), Dpto. Ingenieria Energetica y Fluidomecanica, Escuela de Ingenierias Industriales, Universidad de Valladolid, Paseo del Cauce, 59, E-47011 Valladolid (Spain)

    2011-12-15

    Highlights: > Densities of two mixtures of nitrogen and carbon dioxide are reported. > Experimental data are compared with calculated densities from the equation of state. > Experimental data agree with the equation of state for low pressures above 300 K. > The equation of state shows higher deviations than expected at high pressures. - Abstract: Comprehensive (p, {rho}, T) measurements on two binary mixtures (0.10 CO{sub 2} + 0.90 N{sub 2} and 0.15 CO{sub 2} + 0.85 N{sub 2}) were carried out in the gas phase at seven isotherms between (250 and 400) K and pressures up to 20 MPa using a single sinker densimeter with magnetic suspension coupling. A total of 69 (p, {rho}, T) data for the first mixture and 69 (p, {rho}, T) data for the second are presented in this article. The uncertainty in density was estimated to be (0.02 to 0.15)%, while the uncertainty in temperature was 3.9 mK and the uncertainty in pressure was less than 0.015% (coverage factor k = 2). Experimental results were compared with densities calculated from the GERG equation of state and with data reported by other authors for similar mixtures. Results yielded that, while deviations between experimental data and values calculated from the GERG equation were lower than 0.05% in density for low pressures, the relative error at high pressures and low temperatures increased to about (0.2 to 0.3)%. The main aim of this work was to contribute to an accurate density data base for CO{sub 2}/N{sub 2} mixtures and to check or improve equations of state existing for these binary mixtures.

  15. Densities and apparent molar volumes of aqueous LiI solutions at temperatures from (296 to 600) K and at pressures up to 30 MPa

    International Nuclear Information System (INIS)

    Abdulagatov, I.M.; Azizov, N.D.

    2004-01-01

    Densities of five aqueous LiI solutions (0.0906, 0.2832, 0.6621, 1.6046, and 3.0886) mol . kg -1 H 2 O were measured in the liquid phase with a constant-volume piezometer immersed in a precision liquid thermostat. Measurements were made along various isotherms between (296.95 and 600.25) K. The range of pressure was (0.1 to 30) MPa. The total uncertainty of density, pressure, temperature, and concentration measurements was estimated to be less than 0.06%, 0.05%, 15 mK, and 0.014%, respectively. To check and confirm the accuracy of the measurements, (p,V m ,T,x) data were taken for pure water at selected temperatures and pressures. Experimental and calculated (IAPWS formulation) densities for pure water show excellent agreement within their experimental uncertainties (average absolute deviation is 0.02%). Values of saturated densities were determined by extrapolating experimental p - ρ data to the vapour pressure at fixed temperature and composition using a linear interpolating equation. Apparent molar volumes were derived using measured values of density for solutions and pure water. The apparent molar volumes were extrapolated to zero concentration (m → 0) to yield partial molar volumes of electrolyte (LiI) at infinite dilution. The temperature, pressure, and concentration dependence of apparent and partial molar volumes was studied. The measured values of density, apparent and partial molar volume were compared with data reported in the literature by other authors. A polynomial type of equation of state for specific volume was obtained as a function of temperature, pressure, and composition by a least-squares method using the experimental data. The average absolute deviation (AAD) between measured and calculated values from this polynomial equation for density was 0.065%

  16. Standard molar volumes and heat capacities of aqueous solutions of sodium trifluoromethanesulfonate at temperatures up to 573 K and pressures to 28 MPa

    International Nuclear Information System (INIS)

    Pourtier, Emilie; Ballerat-Busserolles, Karine; Majer, Vladimir; Šedlbauer, Josef

    2013-01-01

    Highlights: ► Original HT/HP data for NaTr(aq) obtained using non-commercial instruments. ► First heat capacity data for NaTr(aq) at conditions remote from ambient. ► Correction for association when calculating stand. therm. properties of Tr(aq) anion. - Abstract: Densities and heat capacities of aqueous solutions of sodium trifluoromethanesulfonate (sodium triflate) of concentrations from 0.025 to 0.3 mol · kg −1 were measured with high temperature, high pressure custom-made instruments at temperatures up to 573 K and at pressures up to 28 MPa. Standard molar volumes and standard molar heat capacities were obtained via extrapolation of the apparent molar properties to infinite dilution. The results for volumetric properties are consistent with earlier literature data, but no previous measurements exist for heat capacities of sodium triflate at superambient conditions. The new data were used for calculating the standard molar volumes and heat capacities for the triflate anion and compared with the results for triflic acid that should be essentially identical within the expected error margins. At temperatures above 473 K an effort was made to refine the processing of literature data for HCl(aq), taking into account its partial association, and subsequently to modify the value for Na + ion calculated from the standard thermodynamic values of NaCl(aq) where its ion pairing was already considered. This approach yields reasonable agreement at high temperatures between the values for triflate ion calculated from its salt and those for triflic acid.

  17. New (p, ρ, T) data for carbon dioxide - Nitrogen mixtures from (250 to 400) K at pressures up to 20 MPa

    International Nuclear Information System (INIS)

    Mondejar, M.E.; Martin, M.C.; Span, R.; Chamorro, C.R.

    2011-01-01

    Highlights: → Densities of two mixtures of nitrogen and carbon dioxide are reported. → Experimental data are compared with calculated densities from the equation of state. → Experimental data agree with the equation of state for low pressures above 300 K. → The equation of state shows higher deviations than expected at high pressures. - Abstract: Comprehensive (p, ρ, T) measurements on two binary mixtures (0.10 CO 2 + 0.90 N 2 and 0.15 CO 2 + 0.85 N 2 ) were carried out in the gas phase at seven isotherms between (250 and 400) K and pressures up to 20 MPa using a single sinker densimeter with magnetic suspension coupling. A total of 69 (p, ρ, T) data for the first mixture and 69 (p, ρ, T) data for the second are presented in this article. The uncertainty in density was estimated to be (0.02 to 0.15)%, while the uncertainty in temperature was 3.9 mK and the uncertainty in pressure was less than 0.015% (coverage factor k = 2). Experimental results were compared with densities calculated from the GERG equation of state and with data reported by other authors for similar mixtures. Results yielded that, while deviations between experimental data and values calculated from the GERG equation were lower than 0.05% in density for low pressures, the relative error at high pressures and low temperatures increased to about (0.2 to 0.3)%. The main aim of this work was to contribute to an accurate density data base for CO 2 /N 2 mixtures and to check or improve equations of state existing for these binary mixtures.

  18. Solubility of perfumery and fragrance raw materials based on cyclohexane in 1-octanol under ambient and high pressures up to 900 MPa

    International Nuclear Information System (INIS)

    Domanska, Urszula; Morawski, Piotr; Piekarska, Maria

    2008-01-01

    The (solid + liquid) phase equilibria (SLE) of binary mixtures containing 1-octanol and fragrance raw materials based on cyclohexane were investigated. The systems {1-octanol (1) + cyclohexyl carboxylic acid (CCA), or cyclohexyl acetic acid (CAA), or cyclohexyl acetate (CA), or 2-cyclohexyl ethyl acetate (2CEA), or 2-cyclohexyl ethanol (2CE)(2)} have been measured by a dynamic method in wide range of temperatures from (220 to 320) K and ambient pressure. For all systems SLE diagrams were detected as eutectic mixtures with complete miscibility in the liquid phase. The experimental data were correlated by means of the Wilson and NRTL equations, utilizing parameters derived from the (solid + liquid) equilibrium. The root-mean-square deviations of the solubility temperatures for all calculated data are dependent upon the particular system and the particular equation used. Additionally, the SLE in binary mixture that contain {1-octanol (1) + CCA (2)} has been measured under very high pressures up to about 900 MPa at the temperature range from T = (303.15 to 353.15) K. The thermostatted apparatus for the measurements of transition pressures from the (liquid + solid) state was used. The freezing and melting temperatures at a constant composition increase monotonously with pressure. The high pressure experimental results obtained at isothermal conditions (p-x) were interpolated to more convenient T-x diagram. Data of the (pressure + temperature) composition relation at the high pressure (solid + liquid) phase equilibria was correlated by the polynomial based on the Yang model. The basic thermodynamic properties of pure substances viz. the melting point, enthalpy of fusion, enthalpy of solid-solid phase transition, and glass transition, have been determined by the differential scanning calorimetry (DSC)

  19. (Liquid + liquid) equilibria measurements for ternary systems (sulfolane + a carboxylic acid + n-heptane) at T = 303.15 K and at 0.1 MPa

    International Nuclear Information System (INIS)

    Cele, N.P.; Bahadur, I.; Redhi, G.G.; Ebenso, E.E.

    2016-01-01

    Highlights: • The (liquid + liquid) equilibrium for (sulfolane + a carboxylic acid + heptane) was measured. • Selectivity values for solvent separation efficiency were calculated. • Separation of carboxylic acids from heptane is feasible by extraction. • Three parameter equations have been fitted to the binodal curve data. • The NRTL and UNIQUAC models were used to correlate the experimental data. - Abstract: In the present work, new (liquid + liquid) equilibrium (LLE) values are reported for ternary systems {sulfolane(1) + acetic acid, or propanoic acid, or butanoic acid, or 2-methylpropanoic acid, or pentanoic acid, or 3-methylbutanoic acid (2) + n-heptane (3)} at T = 303.15 K and at p = 0.1 MPa. The mutual solubility of carboxylic acid in sulfolane is dependent on the length and structure of the alkyl chain of the carboxylic acid; it progressively increases with an increase in the alkyl chain of the carboxylic acid. The single phase homogenous region increases as the alkyl chain of the carboxylic acid increases. The n-heptane is most soluble in the carboxylic acid mixtures with long alkyl chain, that is, (3-methylbutanoic acid + sulfolane) and (pentanoic acid + sulfolane) systems and least soluble in the carboxylic acid with short alkyl chain (acetic acid + sulfolane) system. Carboxylic acid together with many other oxygenates and hydrocarbons are produced by SASOL Company in South Africa using the Fischer–Tropsch process. The details about this process are given in introduction section. The NRTL and UNIQUAC models were used to correlate the experimental tie-lines and to calculate the phase compositions of the ternary systems. It was found that the NRTL model fits the experimental values significantly better than the UNIQUAC model.

  20. Patterns of variation of intertidal species of commercial interest in the Parque Litoral Norte (north Portugal) MPA: comparison with three reference shores.

    Science.gov (United States)

    Bertocci, Iacopo; Dominguez, Rula; Freitas, Cristiano; Sousa-Pinto, Isabel

    2012-06-01

    Marine Protected Areas (MPAs) are world-wide established with the aim of conserving biodiversity and preventing overexploitation of marine organisms. Evaluating the effectiveness of MPAs is needed in order to support and implement their management, but it is complicated by the large natural variability in space and time of distribution and abundance of natural populations. Here, we tested the hypothesis that patterns of total abundance and size-frequency distribution of two intensively harvested intertidal species (the sea urchin Paracentrotus lividus and the mussel Mytilus galloprovincialis) differed between a protected and three reference shores along the rocky coast of north Portugal. Response variables were in terms of mean values and measures of variance at different spatial scales (from centimetres to metres) and over time (along a period of about 12 months). A further comparison involved the estimation of the reproductive potential of sea urchins, quantified as variations of Gonad Index (GI = gonad dry weight/body dry weight × 100) at the scale of shore. Results did not generally support a predictable direct effect of protection, as the total abundance and the abundance of larger individuals of both species and GI did not differ between the MPA and reference shores. However, a considerable temporal and spatial variability at smaller scales was detected for several response variables. Such findings have implications for management of MPAs, highlighting the need for sampling designs properly replicated in space and time, in order to examine their effectiveness, and for considering spatial and temporal heterogeneity of target populations and driving processes as a criterion for their implementation and design. Copyright © 2012 Elsevier Ltd. All rights reserved.

  1. Solubility of perfumery and fragrance raw materials based on cyclohexane in 1-octanol under ambient and high pressures up to 900 MPa

    Energy Technology Data Exchange (ETDEWEB)

    Domanska, Urszula [Physical Chemistry Division, Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw (Poland)], E-mail: ula@ch.pw.edu.pl; Morawski, Piotr; Piekarska, Maria [Physical Chemistry Division, Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw (Poland)

    2008-04-15

    The (solid + liquid) phase equilibria (SLE) of binary mixtures containing 1-octanol and fragrance raw materials based on cyclohexane were investigated. The systems {l_brace}1-octanol (1) + cyclohexyl carboxylic acid (CCA), or cyclohexyl acetic acid (CAA), or cyclohexyl acetate (CA), or 2-cyclohexyl ethyl acetate (2CEA), or 2-cyclohexyl ethanol (2CE)(2){r_brace} have been measured by a dynamic method in wide range of temperatures from (220 to 320) K and ambient pressure. For all systems SLE diagrams were detected as eutectic mixtures with complete miscibility in the liquid phase. The experimental data were correlated by means of the Wilson and NRTL equations, utilizing parameters derived from the (solid + liquid) equilibrium. The root-mean-square deviations of the solubility temperatures for all calculated data are dependent upon the particular system and the particular equation used. Additionally, the SLE in binary mixture that contain {l_brace}1-octanol (1) + CCA (2){r_brace} has been measured under very high pressures up to about 900 MPa at the temperature range from T = (303.15 to 353.15) K. The thermostatted apparatus for the measurements of transition pressures from the (liquid + solid) state was used. The freezing and melting temperatures at a constant composition increase monotonously with pressure. The high pressure experimental results obtained at isothermal conditions (p-x) were interpolated to more convenient T-x diagram. Data of the (pressure + temperature) composition relation at the high pressure (solid + liquid) phase equilibria was correlated by the polynomial based on the Yang model. The basic thermodynamic properties of pure substances viz. the melting point, enthalpy of fusion, enthalpy of solid-solid phase transition, and glass transition, have been determined by the differential scanning calorimetry (DSC)

  2. Analysing and modelling the growth behaviour of Listeria monocytogenes on RTE cooked meat products after a high pressure treatment at 400 MPa.

    Science.gov (United States)

    Hereu, A; Dalgaard, P; Garriga, M; Aymerich, T; Bover-Cid, S

    2014-09-01

    Various predictive models are available for high pressure inactivation of Listeria monocytogenes in food, but currently available models do not consider the growth kinetics of surviving cells during the subsequent storage of products. Therefore, we characterised the growth of L. monocytogenes in sliced cooked meat products after a pressurization treatment. Two inoculum levels (10(7) or 10(4) CFU/g) and two physiological states before pressurization (freeze-stressed or cold-adapted) were evaluated. Samples of cooked ham and mortadella were inoculated, high pressure processed (400 MPa, 5 min) and subsequently stored at 4, 8 and 12 °C. The Logistic model with delay was used to estimate lag phase (λ) and maximum specific growth rate (μmax) values from the obtained growth curves. The effect of storage temperature on μmax and λ was modelled using the Ratkowsky square root model and the relative lag time (RLT) concept. Compared with cold-adapted cells the freeze-stressed cells were more pressure-resistant and showed a much longer lag phase during growth after the pressure treatment. Interestingly, for high-pressure inactivation and subsequent growth, the time to achieve a concentration of L. monocytogenes 100-fold (2-log) higher than the cell concentration prior to the pressure treatment was similar for the two studied physiological states of the inoculum. Two secondary models were necessary to describe the different growth behaviour of L. monocytogenes on ready-to-eat cooked ham (lean product) and mortadella (fatty product). This supported the need of a product-oriented approach to assess growth after high pressure processing. The performance of the developed predictive models for the growth of L. monocytogenes in high-pressure processed cooked ham and mortadella was evaluated by comparison with available data from the literature and by using the Acceptable Simulation Zone approach. Overall, 91% of the relative errors fell into the Acceptable Simulation Zone

  3. 25. MPA-seminar: safety and reliability of plant technology with special emphasis on safety and reliability - integrity proofs, qualification of components, damage prevention. Vol. 1. Papers 1-29

    International Nuclear Information System (INIS)

    1999-01-01

    The proceedings of the 25th MPA Seminar on 'Safety and Reliability of Plant Technology' were issued in two volumes. The main topics of the first volume are: 1. Structural and safety analysis, 2. Reliability analysis, 3. Fracture mechanics, and 4. Nondestructive Testing. s

  4. H2moves.eu Scandinavia. ''Experience from operating a 70 MPa hydrogen refuelling station in Oslo''. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Sloth, M.

    2013-02-15

    As part of the H2MOVES Scandinavia project H2 Logic were to construct a large scale hydrogen refuelling station (HRS) in Oslo providing hydrogen for FCEV's from Daimler and Hyundai in the project. The effort has provided extensive results and lessons learned across the entire process from site selection, HRS design and manufacturing to the final installation and operation. An extensive site screening of more than 30 sites in Oslo was firstly conducted to identify the most optimal location for the HRS. A suitable site was identified at the research organisation SINTEF in Gaustad in the western part of Oslo. The location was strategically well located with regards to the other HRS's in the city ensuring good refuelling coverage in Oslo. The HRS was manufactured, installed and operated by H2 Logic based on the company's H2Station technology. The HRS provides 70MPa refuelling in accordance with the SAE J2601, and operation results have confirmed refuelling times consistently below four minutes for a full tank. The HRS includes onsite electrolysis production providing a 20kg/day base load supply, with potentially additional trucking-in of hydrogen up to a total capacity of 200kg/day. The installation of the HRS took in total 10 days, from arrival at site, until first refuelling was conducted. This included local inspection by third parties and authorities as well as several days of hydrogen production and compression to reach the necessary refuelling pressure. Before opening a refuelling recommendation process was successfully conducted by Daimler. The HRS opened on 21st November 2011 and has been operated for 13,5 months during the remainder project period (ending December 2012). The HRS is expected to continue operation beyond the project. Below are shown the major operation results from the HRS during the project: 1) 701 kg dispensed; 2) 313 refueling's conducted; 3) Average availability of 97% during first half of 2012; 4) 53% of all down

  5. Stability of Zircon and Its Isotopic Ratios in High-Temperature Fluids: Long-Term (4 months Isotope Exchange Experiment at 850°C and 50 MPa

    Directory of Open Access Journals (Sweden)

    Ilya N. Bindeman

    2018-05-01

    Full Text Available Stability of zircon in hydrothermal fluids and vanishingly slow rates of diffusion identify zircon as a reliable recorder of its formation conditions in recent and ancient rocks. Debate, however, persists on how rapidly oxygen and key trace elements (e.g., Li, B, Pb diffuse when zircon is exposed to silicate melt or hot aqueous fluids. Here, we report results of a nano- to micrometer-scale investigation of isotopic exchange using natural zircon from Mesa Falls Tuff (Yellowstone treated with quartz-saturated, isotopically (18O, D, 7Li, and 11B labeled water with a nominal δ18O value of +450%0 over 4 months at 850°C and 50 MPa. Frontside (crystal rim inwards δ18O depth profiling of zircon by magnetic sector SIMS shows initially high but decreasing 18O/16O over a ~130 nm non-Fickian profile, with a decay length comparable to the signal from surficial Au coating deposited onto zircon. In contrast, backside (crystal interior outwards depth profiling on a 2-3 μm thick wafer cut and thinned from treated zircon by focused ion beam (FIB milling lacks any significant increase in 18O/16O during penetration of the original surface layer. Near-surface time-of-flight (TOF-SIMS frontside profiles of uncoated zircon from 4-month and 1-day-long experiments as well as untreated zircons display similar enrichments of 18O over a distance of ~20 nm. All frontside 18O profiles are here interpreted as transient surface signals from nm-thick surface enrichment or contamination unrelated to diffusion. Likewise, frontside depth profiling of H, Li, and B isotopes are similar for long- and short-duration experiments. Additionally, surface U-Pb dating of zircon from the 4-month experiment returned U-Pb ages by depth profiling with ~1 μm penetration that were identical to untreated samples. Frontside and backside depth-profiling thus demonstrate that diffusive 18O enrichment in the presence of H2O is much slower than predicted from experiments in Watson and Cherniak

  6. Catalytic generation of methane at 60-100 °C and 0.1-300 MPa from source rocks containing kerogen Types I, II, and III

    Science.gov (United States)

    Wei, Lin; Schimmelmann, Arndt; Mastalerz, Maria; Lahann, Richard W.; Sauer, Peter E.; Drobniak, Agnieszka; Strąpoć, Dariusz; Mango, Frank D.

    2018-06-01

    Low temperature (60 and 100 °C) and long-term (6 months to 5 years) heating of pre-evacuated and sterilized shales and coals containing kerogen Types I (Mahogany Shale), II (Mowry Shale and New Albany Shale), and III (Springfield Coal and Wilcox Lignite) with low initial maturities (vitrinite reflectance Ro 0.39-0.62%) demonstrates that catalytically generated hydrocarbons may explain the occurrence of some non-biogenic natural gas accumulations where insufficient thermal maturity contradicts the conventional thermal cracking paradigm. Extrapolation of the observed rate of catalytic methanogenesis in the laboratory suggests that significant amounts of sedimentary organic carbon can be converted to relatively dry natural gas over tens of thousands of years in sedimentary basins at temperatures as low as 60 °C. Our laboratory experiments utilized source rock (shale and coal) chips sealed in gold and Pyrex® glass tubes in the presence of hydrogen-isotopically contrasting waters. Parallel heating experiments applied hydrostatic pressures from 0.1 to 300 MPa. Control experiments constrained the influence of pre-existing and residual methane in closed pores of rock chips that was unrelated to newly generated methane. This study's experimental methane yields at 60 and 100 °C are 5-11 orders of magnitude higher than the theoretically predicted yields from kinetic models of thermogenic methane generation, which strongly suggests a contribution of catalytic methanogenesis. Higher temperature, longer heating time, and lower hydrostatic pressure enhanced catalytic methanogenesis. No clear relationships were observed between kerogen type or total organic carbon content and methane yields via catalysis. Catalytic methanogenesis was strongest in Mowry Shale where methane yields at 60 °C amounted to ∼2.5 μmol per gram of organic carbon after one year of hydrous heating at ambient pressure. In stark contrast to the earlier findings of hydrogen isotopic exchange between

  7. Partial molar volumes of organic solutes in water. XXVI. 15-Crown-5 and 18-crown-6 ethers at temperatures (298 to 573) K and pressures up to 30 MPa

    International Nuclear Information System (INIS)

    Cibulka, Ivan

    2015-01-01

    Highlights: • Density data were obtained in the range T from (298 to 573) K and p up to 30 MPa. • Standard molar volumes of two crown ethers in water are presented. • Group contribution method was designed to estimate standard molar volumes of cyclic ethers. - Abstract: Densities of dilute aqueous solutions of two cyclic ethers, viz. 15-crown-5 and 18-crown-6, measured over the temperature range from (298 to 573) K and at pressures up to 30 MPa using an automated flow vibrating-tube densimeter are reported. Standard molar volumes were evaluated from the measured data. Present data were combined with those obtained previously for several cyclic ethers and predictions of standard molar volumes based on group contribution approach were tested and analysed

  8. MPA-capped CdTe quantum dots exposure causes neurotoxic effects in nematode Caenorhabditis elegans by affecting the transporters and receptors of glutamate, serotonin and dopamine at the genetic level, or by increasing ROS, or both

    Science.gov (United States)

    Wu, Tianshu; He, Keyu; Zhan, Qinglin; Ang, Shengjun; Ying, Jiali; Zhang, Shihan; Zhang, Ting; Xue, Yuying; Tang, Meng

    2015-12-01

    As quantum dots (QDs) are widely used in biomedical applications, the number of studies focusing on their biological properties is increasing. While several studies have attempted to evaluate the toxicity of QDs towards neural cells, the in vivo toxic effects on the nervous system and the molecular mechanisms are unclear. The aim of the present study was to investigate the neurotoxic effects and the underlying mechanisms of water-soluble cadmium telluride (CdTe) QDs capped with 3-mercaptopropionic acid (MPA) in Caenorhabditis elegans (C. elegans). Our results showed that exposure to MPA-capped CdTe QDs induced behavioral defects, including alterations to body bending, head thrashing, pharyngeal pumping and defecation intervals, as well as impaired learning and memory behavior plasticity, based on chemotaxis or thermotaxis, in a dose-, time- and size-dependent manner. Further investigations suggested that MPA-capped CdTe QDs exposure inhibited the transporters and receptors of glutamate, serotonin and dopamine in C. elegans at the genetic level within 24 h, while opposite results were observed after 72 h. Additionally, excessive reactive oxygen species (ROS) generation was observed in the CdTe QD-treated worms, which confirmed the common nanotoxicity mechanism of oxidative stress damage, and might overcome the increased gene expression of neurotransmitter transporters and receptors in C. elegans induced by long-term QD exposure, resulting in more severe behavioral impairments.

  9. Generation of high reactive fluids by rapid clinopyroxene-seawater interaction: An experimental study at 425 °C, 40 and 100 MPa

    Science.gov (United States)

    Beermann, Oliver; Garbe-Schönberg, Dieter; Schächinger, Steffen; Arzi, Lisa; Holzheid, Astrid

    2014-05-01

    Submarine hydrothermalism with extensive alteration of oceanic crust is a major process governing energy and mass fluxes from Earth's interior into the oceans. Recent investigations revealed high element fluxes discharging in particular from the generally brittle deformed slow and ultra-slow spreading Mid-Atlantic Ridge (MAR) [1, 2, 3]. This suggests that seawater access to unaltered rocks along juvenile fault systems of the MAR may create hydrothermalism with high fluid and high element fluxes. For example hydrothermal venting at 5° S MAR [4, 5] intensified after a volcano-tectonic event in 2002 [5] and vent fluids constantly emanate here in ~3000 m bsl (~30 MPa) at extreme temperatures above 407 °C [2, 5, 6] and contain high concentrations of transition metals and rare earth elements (REE) [2]. However, geochemical models on mass transfer between oceanic lithosphere and ocean are based upon time integrated mass balance between vent fluid and host rock geochemistry [e.g., 7, 8, 9]. But, none of these models provide estimates for early-stage high-temperature hydrothermalism with unaltered host-rocks as it is evident from the 5°S MAR hydrothermal system. In order to unravel the temporal evolution on element mass transfer between seawater fluid and ocean lithosphere during high-temperature hydrothermalism we started a systematic time-resolved experimental study on seawater-rock interaction processes at variable water-to-rock mass ratios (w/r-ratios). Mixtures of 125-500 µm-sized clinopyroxene (Cpx) and plagioclase (Plag) grains prepared from unaltered gabbro (Atlantis Massif, 30°N MAR, IODP expedition 305, Site U1309D, core sample R211, 1020 m bsf) reacted with two fluid types of similar chlorinity, natural bottom seawater or synthetic 3.2 wt.% NaCl(aq), at 425 °C, 400 and 1000 bar and at w/r ratios from 0.5 to 10 and run durations from 3 to 720 hours. Solid products were analyzed by SEM and XRD, and fluid products were analyzed by ICP-MS and ICP-OES. In all

  10. History and practice of material research on the examples of Material Testing and Materialpruefungsanstalt (MPA) Stuttgart, liquid crystals and screen technology as well as superconductivity. An interdisciplinary teaching project of the University of Stuttgart

    International Nuclear Information System (INIS)

    Hentschel, Klaus; Webel, Josef

    2016-01-01

    The knowledge of material research and its history is not very common among scientists and engineers alike. Within the scope of an interdisciplinary teaching project carried out for the first time in the summer semester 2014 and ever since then every summer semester at the University of Stuttgart, an attempt is made to approach material research both from a scientific, technical and historical perspective. The Material Testing and Materials Testing Institute in Stuttgart (MPA), the liquid crystals and the screen technology as well as the superconductivity were selected as topics, which have a long tradition in research and teaching in Stuttgart. In this anthology the materials of the teaching project are summarized. [de

  11. Fully automatized apparatus for determining speed of sound for liquids in the temperature and pressure interval (283.15–343.15) K and (0.1–95) MPa

    International Nuclear Information System (INIS)

    Yebra, Francisco; Troncoso, Jacobo; Romaní, Luis

    2017-01-01

    Highlights: • An apparatus for measuring speed of sound of liquids is described. • Pressure and temperature control is fully automatized. • Uncertainty of the measurements is estimated in 0.1%. • Comparison with literature data confirms the reliability of the methodology. - Abstract: An instrument for determining the speed of sound as a function of temperature and pressure for liquids is described. It was totally automatized: pressure and temperature values are controlled and time of flight of the ultrasonic wave data were acquired using a digital system which automatically made all required actions. The instrument calibration was made only at atmospheric pressure using high quality data of water and methanol. For higher pressures, the calibration parameters were predicted using a model for the high pressure cell, through finite-element calculations (FEM), in order to realistically determine the changes in the cell induced by the compression. Uncertainties in pressure and temperature were 20 mK and 0.1 MPa, respectively and in speed of sound it was estimated to be about 0.1%. The speeds of sound for water, methanol, hexane, heptane, octane, toluene, ethanol and 1-propanol were determined in the temperature and pressure ranges (283.15–343.15) K and (0.1–95) MPa. Comparison with literature data reveals the high reliability of the experimental procedure.

  12. Volumetric properties of binary mixtures of {difluoromethane (R32) + trans-1,3,3,3-tetrafluoropropene (R1234ze(E))} at temperatures from 283.15 K to 363.15 K and pressures up to 100 MPa

    International Nuclear Information System (INIS)

    Jia, Tao; Bi, Shengshan; Hu, Xiaozhen; Meng, Xianyang; Wu, Jiangtao

    2016-01-01

    Highlights: • Densities of R32+R1234ze(E) mixtures were measured with a vibrating-tube densimeter. • Densities of mixtures were conducted from (283 to 363) K, at pressures up to 100 MPa. • Excess molar volumes were correlated with the Redlich–Kister equation. - Abstract: Values of experimental density of difluoromethane (R32) and five compositions of {R32 + trans-1,3,3,3-tetrafluoropropene (R1234ze(E))} binary mixtures are reported over the temperature range from 283 K to 363 K and at pressures up to 100 MPa with a vibrating-tube densimeter. The excess molar volumes were calculated from experimental results and fitted to the Redlich–Kister equation. The maximum standard deviation and average standard deviations of the experimental and calculated values of excess molar volume from Redlich–Kister equation are 0.07789 cm"3·mol"−"1 and 0.01645 cm"3·mol"−"1, respectively.

  13. Partial molar volumes of organic solutes in water. XXIV. Selected alkane-α,ω-diols at temperatures T = 298 K to 573 K and pressures up to 30 MPa

    International Nuclear Information System (INIS)

    Cibulka, Ivan; Hnědkovský, Lubomír

    2013-01-01

    Highlights: • Standard molar volumes of three alkane-α,ω-diols (C 5 , C 8 , C 9 ) in water are presented. • Data were obtained in the range T from (298 to 573) K and p up to 30 MPa. • Dependences on carbon atom number, temperature, and pressure are analysed. -- Abstract: Density data for dilute aqueous solutions of three alkane-α,ω-diols (pentane-1,5-diol, octane-1,8-diol, nonane-1,9-diol) are presented together with standard molar volumes (partial molar volumes at infinite dilution) calculated from the experimental data. The measurements were performed at temperatures from T = 298 K up to T = 573 K. Experimental pressures were slightly above the saturation vapour pressure of water, and (15 and 30) MPa. The data were obtained using a high-temperature high-pressure flow vibrating-tube densimeter. Measured standard molar volumes were combined with data previously published for other members of the homologous series and discussed. Experimental standard molar volumes were correlated as a function of temperature and pressure using an empirical polynomial function. Dependences of standard molar volumes on temperature and pressure were analysed. Contributions of the methylene group to the standard molar volume were also evaluated and discussed

  14. Speeds of sound in {(1 - x)CH4 + xN2} with x = (0.10001, 0.19999, and 0.5422) at temperatures between 170 K and 400 K and pressures up to 30 MPa

    International Nuclear Information System (INIS)

    Estela-Uribe, J.F.; Trusler, J.P.M.; Chamorro, C.R.; Segovia, J.J.; Martin, M.C.; Villamanan, M.A.

    2006-01-01

    The speed of sound in {(1 - x)CH 4 + xN 2 } has been measured with a spherical acoustic resonator. Two mixtures with x = (0.10001 and 0.19999) were studied along isotherms at temperatures between 220 K and 400 K with pressures up to 20 MPa; a few additional measurements at p = (25 and 30) MPa are also reported. A third mixture with x = 0.5422 was studied along pseudo-isochores at amount-of-substance densities between 0.2 mol . dm -3 and 5 mol . dm -3 . Corrections for molecular vibrational relaxation are discussed in detail and relaxation times are reported. The overall uncertainty of the measured speeds of sound is estimated to be not worse than ±0.02%, except for those measurements in the mixture with x = 0.5422 that lie along the pseduo-isochore at the highest amount-of-substance density. The results have been compared with the predictions of several equations of state used for natural gas systems

  15. Apparent molar volumes and apparent molar heat capacities of aqueous lead nitrate at temperatures from 278.15 K to 393.15 K and at the pressure 0.35 MPa

    International Nuclear Information System (INIS)

    Brown, B.R.; Niederhauser, T.L.; Merkley, E.D.; Woolley, E.M.

    2004-01-01

    Apparent molar volumes V phi and apparent molar heat capacities C p,phi were determined for aqueous solutions of lead nitrate [Pb(NO 3 ) 2 ] at m=(0.02 to 0.5) mol · kg -1 , at T=(278.15 to 393.15) K, and at the pressure 0.35 MPa. Our V phi values were calculated from densities obtained using a vibrating-tube densimeter, and our C p,phi values were obtained using a twin fixed-cell, power-compensation, differential-output, temperature-scanning calorimeter. Our results were fitted to functions of m and T and compared with results from the literature

  16. Adaptation of a Freon-12 critical heat flux correlation to correlate water data from uniformly heated vertical tubes. Part I: Based on critical heat flux data for water at pressures of 3 to 14 MPa

    International Nuclear Information System (INIS)

    Green, W.J.

    1981-12-01

    Comparisons have been made between experimental critical heat flux (CHF) data for upflow of water in uniformly heated vertical tubes and values calculated from an empirical CHF correlation developed from Freon-12 data. When this correlation is re-evaluated to account for vapour Prandtl number effects, very good agreement is obtained between experimental data and calculated values over a wide range of coolant conditions. Comparison of values calculated from the revised correlation with 2063 sets of CHF data obtained from experiments with water in vertical, uniformly heated tubes shows a mean ratio of the calculated to experimental CHF of 0.82 and an r.m.s. error of 5.8 per cent for the following coolant conditions: (1) local pressure of 3.4 to 12 MPa; (2) mass flux greater than approx. 300 kg s -1 m -2 , and (3) thermal equilibrium value of exit quality greater than 0.1

  17. Apparent molar volumes and apparent molar heat capacities of aqueous D-lactose · H2O at temperatures from (278.15 to 393.15) K and at the pressure 0.35 MPa

    International Nuclear Information System (INIS)

    Sargent, J.D.; Niederhauser, T.L.; Woolley, E.M.

    2004-01-01

    Apparent molar volumes V phi and apparent molar heat capacities C p,phi were determined for aqueous solutions of D-lactose · H 2 O at molalities (0.01 to 0.34) mol · kg -1 at temperatures (278.15 to 393.15) K, and at the pressure 0.35 MPa. Our V phi values were calculated from densities obtained using a vibrating tube densimeter, and our C p,phi values were obtained using a twin fixed-cell, power-compensation, differential-output, temperature-scanning calorimeter. Our results for D-lactose(aq) and for D-lactcose · H 2 O were fitted to functions of m and T and compared with the literature results for aqueous D-glucose and D-galactose solutions. Infinite dilution partial molar volumes V 2 compfn and heat capacities C p,2 compfn are given over the range of temperatures

  18. Vapor–Liquid–Liquid Equilibrium Measurements and Modeling of Ethanethiol + Methane + Water, 1-Propanethiol + Methane + Water and 1-Butanethiol + Methane + Water Ternary Systems at 303, 335, and 365 K and Pressure Up to 9 MPa

    DEFF Research Database (Denmark)

    Awan, Javeed; Kontogeorgis, Georgios; Tsivintzelis, Ioannis

    2013-01-01

    New vapor–liquid–liquid equilibrium (VLLE) data for ethanethiol + methane + water, 1-propanethiol + methane + water, and 1-butanethiol + methane + water ternary systems have been measured at three temperatures (303, 335, and 365 K) and pressures up to 9 MPa. A “static-analytic” method was used...... for performing the measurements; the total system pressure was maintained by CH4. The objective of this work is to provide experimental VLLE data for mixtures of mercaptans (thiols) with other natural gas contents at its crude form, for which no data are available in the open literature. Such data will help...... the industrial modeling of processes relevant to reduction of sulfur emissions. The Cubic-Plus-Association (CPA) equation of state was applied to describe the phase behavior of the investigated systems. It is shown that the CPA EoS satisfactorily describes the solubilities of mercaptans (thiols) in all phases...

  19. P, ρ, T and heat capacity measurements of (α-pinene + β-pinene) mixtures over the temperature range 283.15 K to 358.15 K and pressures up to 40 MPa: Experiments and modelling

    International Nuclear Information System (INIS)

    Langa, Elisa; Palavra, Antonio M.F.; Lourenço, Maria J.V.; Nieto de Castro, Carlos A.; Mainar, Ana M.

    2013-01-01

    Highlights: ► Density as a function of P, T and composition was measured for pinene mixtures. ► Isothermal compressibility and coefficients of cubic expansion were also calculated. ► Isobaric heat capacity was also determined as function of temperature and composition. ► Usual behaviour of these properties was found. ► SAFT and PC-SAFT were used as predictive models, showing PC-SAFT the best predictions. - Abstract: The density and isobaric heat capacity of the binary system {α-pinene (4,7,7-trimethylbicyclo[3.1.1]hept-3-ene (1), CAS Number 7785-26-4) + β-pinene (6,6-dimethyl-2-methylene-bicyclo[3.1.1]heptane (2), CAS Number 127-91-3)} has been measured for eleven different compositions. The density was determined at five pressures from (20 MPa to 40 MPa) and temperatures from (283.15 K to 358.15 K) and the isobaric heat capacity at atmospheric pressure and temperatures from (313.15 K to 418.15 K). Density was measured with an experimental uncertainty estimated to be ± 0.5 kg·m −3 . The isothermal compressibility and isobaric thermal expansion were derived from the experimental density data. The isobaric heat capacity was determined with a DSC calorimeter being the experimental uncertainty lower than 1.5%. Isobaric heat capacity behaviour was as expected for both pure compounds and for mixtures. Two different equations of state, conventional SAFT and PC-SAFT, were applied to calculate the densities of the mixture, being the best predictions achieved with PC-SAFT equation.

  20. The Comparison Of In-Flight Pitot Static Calibration Method By Using Radio Altimeter As Reference with GPS and Tower Fly By Methods On CN235-100 MPA

    Science.gov (United States)

    Derajat; Hariowibowo, Hindawan

    2018-04-01

    The new proposed In-Flight Pitot Static Calibration Method has been carried out during Development and Qualification of CN235-100 MPA (Military Patrol Aircraft). This method is expected to reduce flight hours, less human resources required, no additional special equipment, simple analysis calculation and finally by using this method it is expected to automatically minimized operational cost. At The Indonesian Aerospace (IAe) Flight Test Center Division, the development and updating of new flight test technique and data analysis method as specially for flight physics test subject are still continued to be developed as long as it safety for flight and give additional value for the industrial side. More than 30 years, Flight Test Data Engineers at The Flight Test center Division work together with the Air Crew (Test Pilots, Co-Pilots, and Flight Test Engineers) to execute the flight test activity with standard procedure for both the existance or development test techniques and test data analysis. In this paper the approximation of mathematical model, data reduction and flight test technique of The In-Flight Pitot Static Calibration by using Radio Altimeter as reference will be described and the test results had been compared with another methods ie. By using Global Position System (GPS) and the traditional method (Tower Fly By Method) which were used previously during this Flight Test Program (Ref. [10]). The flight test data case are using CN235-100 MPA flight test data during development and Qualification Flight Test Program at Cazaux Airport, France, in June-November 2009 (Ref. [2]).

  1. The (p, ρ, T, x) properties of (x1 propane + x2n-butane) with x1 (0.0000, 0.2729, 0.5021, and 0.7308) over the temperature range from (280 to 440) K at pressures from (1 to 200) MPa

    International Nuclear Information System (INIS)

    Miyamoto, H.; Uematsu, M.

    2008-01-01

    The (p, ρ, T, x) properties for (x 1 propane + x 2 n-butane) with x 1 = (0.0000, 0.2729, 0.5021, and 0.7308) in the compressed liquid phase were measured by means of a metal-bellows variable volumometer over the temperature range from (280 to 440) K at pressures from (1 to 200) MPa. The mole fraction purities of the propane and n-butane used in the measurements were 0.9999 and 0.9997, respectively. The expanded uncertainties (k = 2) in temperature, pressure, density, and composition measurements have been estimated to be less than ±3 mK; 1.4 kPa (p ≤ 7 MPa), 0.06% (7 MPa 150 MPa); 0.09%; and 4.4 . 10 -4 , respectively. In the region above 100 MPa at T = (280 and 440) K, the uncertainty in density measurements increases from 0.09% to 0.13% and 0.22%, respectively. Comparisons of the available equation of state with the present measurements are reported. On the basis of the present results, the excess molar volume v m E of the mixtures was calculated and illustrated as a function of temperature and pressure

  2. The (p, ρ, T, x) properties for {x propane + (1 - x) isobutane} with x = (1.0000, 0.2765, 0.5052, and 0.7468) in the temperature range from (280 to 440) K at pressures from (1 to 200) MPa

    International Nuclear Information System (INIS)

    Miyamoto, H.; Shigetoyo, K.; Uematsu, M.

    2007-01-01

    The (p, ρ, T, x) properties for {x propane + (1 - x) isobutane} with x = (1.0000, 0.2765, 0.5052, and 0.7468) in the compressed liquid phase were measured by means of a metal-bellows variable volumometer in the temperature range from (280 to 440) K at pressures from (1 to 200) MPa. The mole fraction purities of the propane and isobutane used in the measurements were 0.9999 and 0.9999, respectively. The expanded uncertainties (k = 2) in temperature, pressure, density, and composition measurements have been estimated to be less than ±3 mK; 1.4 kPa (p ≤ 7 MPa), 0.06% (7 MPa 150 MPa); 0.09%; and 1.3 . 10 -4 , respectively. In the region above 100 MPa at T (280 and 440) K, the uncertainty in density measurements increases from 0.09% to 0.13% and 0.22%, respectively. Comparisons of the available equation of state with the present measurements are reported. On the basis of the present results, the excess molar volume V m E of the mixtures was calculated and illustrated as a function of temperature and pressure

  3. An International Standard Equation of State for Difluoromethane (R-32) for Temperatures from the Triple Point at 136.34 K to 435 K and Pressures up to 70 MPa

    International Nuclear Information System (INIS)

    Tillner-Roth, R.; Yokozeki, A.

    1997-01-01

    A fundamental equation of state for the Helmholtz free energy of R-32 (difluoromethane) is presented which is valid from the triple point at 136.34 K to 435 K and pressures up to 70 MPa. It is based on accurate measurements of pressure-density-temperature (p,ρ,T), speed of sound, heat capacity, and vapor pressure currently available. New values for the isobaric heat capacity c p circ of the ideal gas calculated from spectroscopic data taking into account also first order anharmonicity corrections are presented. The Helmholtz free energy equation of state has 19 coefficients and represents all selected experimental data within their estimated accuracy with the exception for heat capacities and speed of sound in the region close to the critical point. Typical uncertainties are ±0.05% for density, ±0.02% for the vapor pressure and ±0.5%endash 1% for the heat capacity. This equation of state has been compared to equations developed by other research groups by Annex 18 of the International Energy Agency and has been selected as an international standard formulation for the thermodynamic properties of R-32 by this group. copyright 1997 American Institute of Physics and American Chemical Society

  4. Phase behaviour for the (carbon dioxide + 2-phenoxyethyl acrylate) and (carbon dioxide + 2-phenoxyethyl methacrylate) systems at temperatures from (313.2 to 393.2) K and pressures from (5 to 31) MPa

    International Nuclear Information System (INIS)

    Byun, Hun-Soo; Jang, Yoon-Seok; Yoo, Ki-Pung

    2010-01-01

    The solubility curves for the (carbon dioxide + 2-phenoxyethyl acrylate) and (carbon dioxide + 2-phenoxyethyl methacrylate) systems were determined by a static view cell apparatus at five temperatures (313.2, 333.2, 353.2, 373.2, and 393.2) K as well as pressures up to 31.43 MPa. Two {carbon dioxide + (meth)acrylate} systems had continuous critical mixture curves with maxima in pressure located between the critical temperatures of carbon dioxide and 2-phenoxyethyl (meth)acrylate. The solubility of 2-phenoxyethyl (meth)acrylate in the {carbon dioxide + 2-phenoxyethyl (meth)acrylate} systems increases as the temperature increases at a fixed pressure. The (carbon dioxide + 2-phenoxyethyl acrylate) and (carbon dioxide + 2-phenoxyethyl methacrylate) systems exhibit type-I phase behaviour. The experimental results for the (carbon dioxide + 2-phenoxyethyl acrylate) and (carbon dioxide + 2-phenoxyethyl methacrylate) systems correlate with the Peng-Robinson equation of state using a van der Waals one-fluid mixing rule including two adjustable parameters. The critical properties of 2-phenoxyethyl acrylate and 2-phenoxyethyl methacrylate were predicted with the Joback and Lee-Kesler method.

  5. Measurement of the (pressure, density, temperature) relation of two (methane + nitrogen) gas mixtures at temperatures between 240 and 400 K and pressures up to 20 MPa using an accurate single-sinker densimeter

    Energy Technology Data Exchange (ETDEWEB)

    Chamorro, C.R. [Grupo de Termodinamica y Calibracion (TERMOCAL), Dpto. Ingenieria Energetica y Fluidomecanica, E.T.S. de Ingenieros Industriales, Universidad de Valladolid, E-47071 Valladolid (Spain)]. E-mail: cescha@eis.uva.es; Segovia, J.J. [Grupo de Termodinamica y Calibracion (TERMOCAL), Dpto. Ingenieria Energetica y Fluidomecanica, E.T.S. de Ingenieros Industriales, Universidad de Valladolid, E-47071 Valladolid (Spain); Martin, M.C. [Grupo de Termodinamica y Calibracion (TERMOCAL), Dpto. Ingenieria Energetica y Fluidomecanica, E.T.S. de Ingenieros Industriales, Universidad de Valladolid, E-47071 Valladolid (Spain); Villamanan, M.A. [Grupo de Termodinamica y Calibracion (TERMOCAL), Dpto. Ingenieria Energetica y Fluidomecanica, E.T.S. de Ingenieros Industriales, Universidad de Valladolid, E-47071 Valladolid (Spain); Estela-Uribe, J.F. [Facultad de Ingenieria, Universidad Javeriana-Cali, Calle 18, 118-250 Cali (Colombia); Trusler, J.P.M. [Department of Chemical Engineering, Imperial College London, London SW7 2AZ (United Kingdom)

    2006-07-15

    Comprehensive (p, {rho}, T) measurements on two gas mixtures of (0.9CH{sub 4} + 0.1N{sub 2}) and (0.8CH{sub 4} + 0.2N{sub 2}) have been carried out at six temperatures between 240 and 400 K and at pressures up to 20 MPa. A total of 108 (p, {rho}, T) data for the first mixture and 134 for the second one are given. These measurements were performed using a compact single-sinker densimeter based on Archimedes' buoyancy principle. The overall uncertainty in density {rho} is estimated to be (1.5 . 10{sup -4} . {rho} + 2 . 10{sup -3} kg . m{sup -3}) (coverage factor k = 2), the uncertainty in temperature T is estimated to be 0.006 K (coverage factor k = 2), and the uncertainty in pressure p is estimated to be 1 . 10{sup -4}.p (coverage factor k = 2). The equipment has been previously checked with pure nitrogen over the whole temperature and pressure working ranges and experimental results (35 values) are given and a comparison with the reference equation of state for nitrogen is presented.

  6. Compressed liquid densities and excess molar volumes for (CO{sub 2} + 1-pentanol) binary system at temperatures from 313 to 363 K and pressures up to 25 MPa

    Energy Technology Data Exchange (ETDEWEB)

    Zuniga-Moreno, Abel [Instituto Politecnico Nacional, ESIQIE, Laboratorio de Termodinamica, Edif. Z, Secc. 6, 1er piso, UPALM Zacatenco, 07738, Lindavista, Mexico, D.F. (Mexico); Galicia-Luna, Luis A. [Instituto Politecnico Nacional, ESIQIE, Laboratorio de Termodinamica, Edif. Z, Secc. 6, 1er piso, UPALM Zacatenco, 07738, Lindavista, Mexico, D.F. (Mexico)], E-mail: lgalicial@ipn.mx; Sandler, Stanley I. [Department of Chemical Engineering, University of Delaware, Newark, DE 19716-3119 (United States)

    2008-02-15

    Measurements of compressed liquid densities for 1-pentanol and for {l_brace}CO{sub 2} (1) + 1-pentanol (2){r_brace} system were carried out at temperatures from 313 K to 363 K and pressures up to 25 MPa. Densities were measured for binary mixtures at 10 different compositions, x{sub 1} = 0.0816, 0.1347, 0.3624, 0.4651, 0.6054, 0.7274, 0.8067, 0.8573, 0.9216, and 0.9757. A vibrating tube densimeter was used to perform density measurements using two reference calibration fluids. The uncertainty is estimated to be better than {+-}0.2 kg . m{sup -3} for the experimental density measurements. For each mixture and for 1-pentanol, the experimental densities were correlated using an explicit volume equation of six parameters and an 11-parameter equation of state (EoS). Excess molar volumes were determined for the (CO{sub 2} + 1-pentanol) system using 1-pentanol densities calculated from the 11-parameter EoS and CO{sub 2} densities calculated from a multiparameter reference EoS.

  7. Diffusion-controlled melting in granitic systems at 800-900degC and 100-200 MPa. Temperature and pressure dependence of the minimum diffusivity in granitic melts

    International Nuclear Information System (INIS)

    Yuguchi, Takashi; Yamaguchi, Takashi; Iwamoto, Manji-rou; Eguchi, Hibiki; Isobe, Hiroshi; Nishiyama, Tadao

    2012-01-01

    This paper presents the temperature and pressure dependence of the minimum binary diffusivity in granitic melts. The minimum diffusivities are determined by monitoring the temporal development of the diffusion-controlled melt layer(DCM) in granitic systems (albite (Ab)-quartz (Qtz)-H 2 O and orthoclase (Or)-Qtz-H 2 O) gathered during 31 melting experiments under conditions of 800-900degC and 100-200 MPa for durations of 19-72 h. The DCM is formed between single crystals (Ab or Or crystals) and powdered quartz in all runs and is characterized by a distinct concentration gradient. The maximum thickness of the DCM increases systematically with temperature, pressure, and run duration. Temporal development of the DCM obeys the parabolic growth rate law, using which the diffusivity can be estimated. Plots of concentrations along the diffusion paths in ternary diagrams (Na 2 O-Al 2 O 3 -SiO 2 diagram for the Ab-Qtz-H 2 O system and K 2 O-Al 2 O 3 -SiO 2 diagram for the Or-Qtz-H 2 O system) show linear trends rather than S-shaped trends, indicating that binary nature of diffusion occurs in these systems. Therefore, the diffusive component can be interpreted as an albite component or orthoclase and quartz components (SiO 2 ) rather than an oxide or a cation. (author)

  8. Thermodynamics of proton dissociation from aqueous bicarbonate: apparent molar volumes and apparent molar heat capacities of potassium carbonate and potassium bicarbonate at T=(278.15 to 393.15) K and at the pressure 0.35 MPa

    International Nuclear Information System (INIS)

    Sorenson, E.C.; Woolley, E.M.

    2004-01-01

    We have determined the apparent molar volumes V phi and apparent molar heat capacities C p,phi of aqueous potassium carbonate and potassium bicarbonate solutions in the ranges (0.014≤m/(mol · kg -1 )≤0.51) and (278.15≤T/K≤393.15) at the pressure p=0.35 MPa. Corrections for speciation due to hydrolysis and disproportionation in solution were applied using Young's rule, and semi-empirical equations representing (V phi ,m,T) and (C p,phi ,m,T) for the species {2K + , CO 3 2- (aq)} and {K + , HCO 3 - (aq)} were fitted to the experimental results. We have used these equations to estimate the change in volume Δ r V m , change in heat capacity Δ r C p,m , enthalpy change Δ r H m , entropy change Δ r S m , and equilibrium molality quotient pQ for the second proton dissociation reaction from aqueous carbonic acid

  9. Apparent molar volumes and apparent molar heat capacities of aqueous magnesium nitrate, strontium nitrate, and manganese nitrate at temperatures from 278.15 K to 393.15 K and at the pressure 0.35 MPa

    International Nuclear Information System (INIS)

    Jones, J.S.; Ziemer, S.P.; Brown, B.R.; Woolley, E.M.

    2007-01-01

    Apparent molar volumes V φ and apparent molar heat capacities C p,φ were determined at the pressure 0.35 MPa for aqueous solutions of magnesium nitrate Mg(NO 3 ) 2 at molalities m = (0.02 to 1.0) mol . kg -1 , strontium nitrate Sr(NO 3 ) 2 at m = (0.05 to 3.0) mol . kg -1 , and manganese nitrate Mn(NO 3 ) 2 at m = (0.01 to 0.5) mol . kg -1 . Our V φ values were calculated from solution densities obtained at T = (278.15 to 368.15) K using a vibrating-tube densimeter, and our C p,φ values were calculated from solution heat capacities obtained at T = (278.15 to 393.15) K using a twin fixed-cell, differential, temperature-scanning calorimeter. Empirical functions of m and T were fitted to our results, and standard state partial molar volumes and heat capacities were obtained over the ranges of T investigated

  10. Apparent molar volumes and apparent molar heat capacities of dilute aqueous solutions of ethanol, 1-propanol, and 2-propanol at temperatures from 278.15 K to 393.15 K and at the pressure 0.35 MPa

    International Nuclear Information System (INIS)

    Origlia-Luster, M.L.; Woolley, E.M.

    2003-01-01

    Apparent molar volumes V phi and apparent molar heat capacities C p,phi have been determined for dilute aqueous solutions of ethanol, 1-propanol, and 2-propanol at temperatures from 278.15 K to 393.15 K and at the pressure 0.35 MPa. The molalities investigated ranged from 0.05 mol·kg -1 to 1.0 mol·kg -1 . We used a vibrating tube densimeter (DMA 512P, Anton PAAR, Austria) to determine the densities and volumetric properties. Heat capacities were obtained using a twin fixed-cell, power-compensation, differential-output, temperature-scanning calorimeter (NanoDSC 6100, Calorimetry Sciences Corporation, American Fork, UT, USA). The results were fit by regression to equations that describe the surfaces (V phi ,T,m) and (C p,phi ,T,m). Infinite dilution partial molar volumes V 2 0 and heat capacities C 0 p,2 were obtained over the range of temperatures by extrapolation of these surfaces to m=0 mol·kg -1

  11. Measurement of the (pressure, density, temperature) relation of two (methane + nitrogen) gas mixtures at temperatures between 240 and 400 K and pressures up to 20 MPa using an accurate single-sinker densimeter

    International Nuclear Information System (INIS)

    Chamorro, C.R.; Segovia, J.J.; Martin, M.C.; Villamanan, M.A.; Estela-Uribe, J.F.; Trusler, J.P.M.

    2006-01-01

    Comprehensive (p, ρ, T) measurements on two gas mixtures of (0.9CH 4 + 0.1N 2 ) and (0.8CH 4 + 0.2N 2 ) have been carried out at six temperatures between 240 and 400 K and at pressures up to 20 MPa. A total of 108 (p, ρ, T) data for the first mixture and 134 for the second one are given. These measurements were performed using a compact single-sinker densimeter based on Archimedes' buoyancy principle. The overall uncertainty in density ρ is estimated to be (1.5 . 10 -4 . ρ + 2 . 10 -3 kg . m -3 ) (coverage factor k = 2), the uncertainty in temperature T is estimated to be 0.006 K (coverage factor k = 2), and the uncertainty in pressure p is estimated to be 1 . 10 -4 .p (coverage factor k = 2). The equipment has been previously checked with pure nitrogen over the whole temperature and pressure working ranges and experimental results (35 values) are given and a comparison with the reference equation of state for nitrogen is presented

  12. Experimental study of the density and derived volumetric (excess, apparent, and partial molar volumes) properties of aqueous 1-propanol mixtures at temperatures from 298 K to 582 K and pressures up to 40 MPa

    International Nuclear Information System (INIS)

    Abdulagatov, I.M.; Azizov, N.D.

    2014-01-01

    Highlights: • Density of (water + 1-propanol) mixtures. • Excess molar volumes of (water + 1-propanol) mixtures. • Apparent molar volumes of (water + 1-propanol) mixtures. -- Abstract: Densities of (water + 1-propanol) mixtures have been measured over the temperature range from 298 K to 582 K and at pressures up to 40 MPa using the constant-volume piezometer immersed in a precision liquid thermostat. The measurements were made for six compositions of (0.869, 2.465, 2.531, 7.407, 14.377, and 56.348) mol · kg −1 of 1-propanol. The expanded uncertainty of the density, pressure, temperature, and concentration measurements at the 95% confidence level with a coverage factor of k = 2 is estimated to be 0.06%, 0.05%, 15 mK, and 0.015%, respectively. The derived volumetric properties such as excess (V m E ), apparent (V Φ ), and partial (V ¯ 2 ∞ ) molar volumes were calculated using the measured values of density for the mixture and for pure components (water and 1-propanol). The concentration dependences of the apparent molar volumes were extrapolated to zero concentration to yield the partial molar volumes of 1-propanol at infinite dilution (V ¯ 2 ∞ ). The temperature, pressure, and concentration dependence of density and derived properties of the mixture were studied. All experimental and derived properties (excess, apparent, and partial molar volumes) were compared with the reported data by other authors. The small and negative values of excess molar volume for the mixtures were found at all experimental temperatures, pressures, and over the entire concentration range. The excess molar volume minimum is found at concentration about 0.4 mole fraction of 1-propanol. The concentration minimum of the derived apparent molar volumes V Φ near the 2.5 mol · kg −1 (dilute mixture) was observed

  13. Volumetric properties of binary liquid-phase mixture of (water + glycerol) at temperatures of (278.15 to 323.15) K and pressures of (0.1 to 100) MPa

    International Nuclear Information System (INIS)

    Egorov, Gennadiy I.; Makarov, Dmitriy M.

    2014-01-01

    Highlights: • Coefficients of compressibility of liquid binary mixture (water + glycerol) were measured. • Partial molar volumes of the components and excess molar volumes of the mixture were calculated. • Molar isothermal compression, molar isobaric expansion and molar isochoric elasticity of the mixture were evaluated. • Analysis of volume characteristics confirms glycerol hydrophilic nature. - Abstract: The coefficients of compressibility, k = ΔV/V o , of liquid binary mixture of {water (1) + glycerol (2)} were measured over the whole composition range at pressures from (0.1 to 100) MPa and temperatures from (278.15 to 323.15) K. Excess molar volumes of the mixture, V m E , partial molar volumes of the mixture components, V ¯ i , as well as their limiting values, molar isothermal compression K T,m , molar isobaric expansion E P,m , molar isochoric elasticity (isochoric coefficient of thermal pressure) β m were calculated. It was revealed that with glycerol molar fraction increasing the coefficients of compressibility, k, decreased to x 2 ≈ 0.3 ÷ 0.4 (where x 2 was glycerol molar fraction), and further changed insignificantly. It was shown that all isobars of excess molar volumes were negative and their absolute values, V m E , decreased on temperature and pressure rising. No extremes were observed on concentration dependences of partial molar volumes of glycerol in the mixture at its low concentrations. Under the state parameters studied limiting partial volumes of water and glycerol decrease with pressure rising but increase with temperature growth. Dependences of molar isothermal compression and molar isochoric elasticity on glycerol molar fraction passed extremes, and similar dependences of molar isobaric expansion had the temperature inversion regions

  14. Viscosity of aqueous Ni(NO3)2 solutions at temperatures from (297 to 475) K and at pressures up to 30 MPa and concentration between (0.050 and 2.246) mol . kg-1

    International Nuclear Information System (INIS)

    Abdulagatov, I.M.; Zeinalova, A.B.; Azizov, N.D.

    2006-01-01

    Viscosity of nine aqueous Ni(NO 3 ) 2 solutions (0.050, 0.153, 0.218, 0.288, 0.608, 0.951, 1.368, 1.824, and 2.246) mol . kg -1 was measured in the temperature range from (297 to 475) K and at pressures (0.1, 10, 20, and 30) MPa. The measurements were carried out with a capillary flow technique. The total experimental uncertainty of viscosity, pressure, temperature, and composition measurements were estimated to be less than 1.6%, 0.05%, 15 mK, and 0.02%, respectively. All experimental and derived results are compared with experimental and calculated values reported in the literature. Extrapolation of the solution viscosity measurements to zero concentration (pure water values) for the given temperature and pressure are in excellent agreement (average absolute deviation, AAD = 0.13%) with the values of pure water viscosity from IAPWS formulation [J. Kestin, J.V. Sengers, B. Kamgar-Parsi, J.M.H. Levelt Sengers, J. Phys. Chem. Ref. Data 13 (1984) 175-189]. The viscosity data for the solutions as a function of concentration have been interpreted in terms of the extended Jones-Dole equation for strong electrolytes. The values of viscosity A-, B-, and D-coefficients of the extended Jones-Dole equation for the relative viscosity (η/η ) of aqueous Ni(NO 3 ) 2 solutions as a function of temperature are studied. The derived values of the viscosity A- and B-coefficients were compared with the results predicted by Falkenhagen-Dole theory (limiting law) of electrolyte solutions and the values calculated with the ionic B-coefficient data. The measured values of viscosity for the solutions were also used to calculate the effective rigid molar volumes in the extended Einstein relation for the relative viscosity (η/η )

  15. 31. MPA seminar 2005. Proceedings; 31. MPA-Seminar 2005. Vortraege

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    The proceedings volume contains 41 contributions on the following subjects: Safety, availability, life cycle management, damage prevention and quality assurance of power plants. [German] Dieser Tagungsband enthaelt insgesamt 41 Beitraege mit folgenden Themenschwerpunkten: Sicherheit, Verfuegbarkeit, Lebensdauermanagement, Schadensvermeidung sowie Qualitaetssicherung von Kraftwerken.

  16. Solubility of platinum-arsenide melt and sperrylite in synthetic basalt at 0.1 MPa and 1200 °C with implications for arsenic speciation and platinum sequestration in mafic igneous systems

    Science.gov (United States)

    Canali, A. C.; Brenan, J. M.; Sullivan, N. A.

    2017-11-01

    To better understand the Pt-As association in natural magmas, experiments were done at 1200 °C and 0.1 MPa to measure the solubility of Pt and Pt-arsenide phases (melt and sperrylite, PtAs2), as well as to determine the oxidation state, and identify evidence for Pt-As complexing, in molten silicate. Samples consisting of synthetic basalt contained in chromite crucibles were subject to three experimental procedures. In the first, platinum solubility in the synthetic basalt was determined without added arsenic by equilibrating the sample with a platinum source (embedded wire or bead) in a gas-mixing furnace. In the second, the sample plus a Pt-arsenide source was equilibrated in a vacuum-sealed fused quartz tube containing a solid-oxide oxygen buffer. The third approach involved two steps: first equilibrating the sample in a gas-mixing furnace, then with added arsenide melt in a sealed quartz tube. Oxygen fugacity was estimated in the latter step using chromite/melt partitioning of vanadium. Method two experiments done at high initial arsenic activity (PtAs melt + PtAs2), showed significant loss of arsenic from the sample, the result of vapour transfer to newly-formed arsenide phases in the buffer. Method three experiments showed no loss of arsenic, yielding a uniform final distribution in the sample. Analyses of run-product glasses from experiments which did not show arsenic loss reveal significant increase in arsenic concentrations with fO2, varying from ∼10 ppm (FMQ-3.25) to >10,000 ppm (FMQ + 5.5). Despite very high arsenic loadings (>1000 ppm), the solubility of Pt is similar in arsenic-bearing and arsenic-free glasses. The variation in arsenic solubility with fO2 shows a linear relationship, that when corrected for the change in the activity of dissolved arsenic with the melt ferric/ferrous ratio, yields a solubility-fO2 relationship consistent with As3+ as the dissolved species. This result is confirmed by X-ray absorption near edge structure (XANES

  17. Thermodynamic properties of peptide solutions 20. Partial molar volumes and isothermal compressions for some tripeptides of sequence gly-X-gly (X = gly, ala, leu, asn, thr, and tyr) in aqueous solution at T = 298.15 K and p = (10–120) MPa

    International Nuclear Information System (INIS)

    Hedwig, Gavin R.; Høiland, Harald

    2016-01-01

    Highlights: • Sound speeds were measured for aqueous solutions of some tripeptides at high pressures. • Partial molar volumes and isothermal compressions were derived for T = 298.15 K and p = (10–120) MPa. • The partial molar volumes for non-polar amino acid side-chains decrease with increasing pressure. • The partial molar volumes for polar side-chains do not change significantly with increasing pressure. - Abstract: Sound speeds have been measured for aqueous solutions of six tripeptides of sequence glycyl-X-glycine, where X is one of the amino acids glycine, alanine, leucine, asparagine, threonine, and tyrosine at T = 298.15 K and at the pressures p = (10, 20, 40, 60, 80, 100, and 120) MPa. Using methods described in previous work, these sound speeds were used to derive the partial molar volumes at infinite dilution, V_2"o, the partial molar isentropic compressions at infinite dilution, K_S_,_2"o, and the partial molar isothermal compressions at infinite dilution, K"o_T_,_2 {K"o_T_,_2 = −(∂V_2"o/∂p)_T}, for the tripeptides in aqueous solution at the elevated pressures. The results were used to calculate the partial molar volumes and partial molar isothermal compressions for the various amino acid side-chains over the pressure range p = (10–120) MPa.

  18. Speeds of sound in {l_brace}(1 - x)CH{sub 4} + xN{sub 2}{r_brace} with x = (0.10001, 0.19999, and 0.5422) at temperatures between 170 K and 400 K and pressures up to 30 MPa

    Energy Technology Data Exchange (ETDEWEB)

    Estela-Uribe, J.F. [Facultad de Ingenieria, Universidad Javeriana-Cali, Calle 18, 118-250 Cali (Colombia); Trusler, J.P.M. [Department of Chemical Engineering, Imperial College London, London SW7 2AZ (United Kingdom)]. E-mail: m.trusler@imperial.ac.uk; Chamorro, C.R. [Grupo de Termodinamica y Calibracion (TERMOCAL), Dpto. Ingenieria Energetica y Fluidomecanica, E.T.S. de Ingenieros Industriales, Universidad de Valladolid, E-47071 Valladolid (Spain); Segovia, J.J. [Grupo de Termodinamica y Calibracion (TERMOCAL), Dpto. Ingenieria Energetica y Fluidomecanica, E.T.S. de Ingenieros Industriales, Universidad de Valladolid, E-47071 Valladolid (Spain); Martin, M.C. [Grupo de Termodinamica y Calibracion (TERMOCAL), Dpto. Ingenieria Energetica y Fluidomecanica, E.T.S. de Ingenieros Industriales, Universidad de Valladolid, E-47071 Valladolid (Spain); Villamanan, M.A. [Grupo de Termodinamica y Calibracion (TERMOCAL), Dpto. Ingenieria Energetica y Fluidomecanica, E.T.S. de Ingenieros Industriales, Universidad de Valladolid, E-47071 Valladolid (Spain)

    2006-07-15

    The speed of sound in {l_brace}(1 - x)CH{sub 4} + xN{sub 2}{r_brace} has been measured with a spherical acoustic resonator. Two mixtures with x = (0.10001 and 0.19999) were studied along isotherms at temperatures between 220 K and 400 K with pressures up to 20 MPa; a few additional measurements at p = (25 and 30) MPa are also reported. A third mixture with x = 0.5422 was studied along pseudo-isochores at amount-of-substance densities between 0.2 mol . dm{sup -3} and 5 mol . dm{sup -3}. Corrections for molecular vibrational relaxation are discussed in detail and relaxation times are reported. The overall uncertainty of the measured speeds of sound is estimated to be not worse than {+-}0.02%, except for those measurements in the mixture with x = 0.5422 that lie along the pseduo-isochore at the highest amount-of-substance density. The results have been compared with the predictions of several equations of state used for natural gas systems.

  19. An Improved Multidimensional MPA Procedure for Bidirectional Earthquake Excitations

    Directory of Open Access Journals (Sweden)

    Feng Wang

    2014-01-01

    Full Text Available Presently, the modal pushover analysis procedure is extended to multidimensional analysis of structures subjected to multidimensional earthquake excitations. an improved multidimensional modal pushover analysis (IMMPA method is presented in the paper in order to estimate the response demands of structures subjected to bidirectional earthquake excitations, in which the unidirectional earthquake excitation applied on equivalent SDOF system is replaced by the direct superposition of two components earthquake excitations, and independent analysis in each direction is not required and the application of simplified superposition formulas is avoided. The strength reduction factor spectra based on superposition of earthquake excitations are discussed and compared with the traditional strength reduction factor spectra. The step-by-step procedure is proposed to estimate seismic demands of structures. Two examples are implemented to verify the accuracy of the method, and the results of the examples show that (1 the IMMPA method can be used to estimate the responses of structure subjected to bidirectional earthquake excitations. (2 Along with increase of peak of earthquake acceleration, structural response deviation estimated with the IMMPA method may also increase. (3 Along with increase of the number of total floors of structures, structural response deviation estimated with the IMMPA method may also increase.

  20. Teaching and Learning Reflection in MPA Programs: Towards a Strategy

    Science.gov (United States)

    van der Meer, F. B.; Marks, P.

    2013-01-01

    Reflection is an essential ingredient of academic education in Public Administration, both for an academic and a professional career. Making a distinction between reflectivity and reflexivity we identify 30 foci of reflection. The main question of the article is how these forms of reflection can be taught and learned in PA programs, especially in…

  1. MPA/ESO/MPE/USM Joint Astronomy Conference

    CERN Document Server

    Böhringer, H; Finoguenov, A; Schuecker, P; Heating versus Cooling in Galaxies and Clusters of Galaxies

    2007-01-01

    The present volume is the record of a recent topical conference on the interplay between heating and cooling processes in galaxies and clusters of galaxies. The volume documents recent progress in our understanding of the dense central regions of these objects. Chapters detail recent results from multiwavelength observations and advances in numerical hydrodynamical simulations. An additional section covers new research on feedback and self-regulatory mechanisms during cosmic structure formation in general, and in galaxy formation in particular. With reviews and technical papers written by leading scientists, this state-of-the art report will be a valuable and comprehensive source of reference for all astronomers and astrophysicists active in this field.

  2. An Improved Multidimensional MPA Procedure for Bidirectional Earthquake Excitations

    OpenAIRE

    Wang, Feng; Sun, Jian-Gang; Zhang, Ning

    2014-01-01

    Presently, the modal pushover analysis procedure is extended to multidimensional analysis of structures subjected to multidimensional earthquake excitations. an improved multidimensional modal pushover analysis (IMMPA) method is presented in the paper in order to estimate the response demands of structures subjected to bidirectional earthquake excitations, in which the unidirectional earthquake excitation applied on equivalent SDOF system is replaced by the direct superposition of two compone...

  3. Apparent molar heat capacities and apparent molar volumes of Pr(ClO4)3(aq), Gd(ClO4)3(aq), Ho(ClO4)3(aq), and Tm(ClO4)3(aq) at T=(288.15, 298.15, 313.15, and 328.15) K and p=0.1 MPa

    International Nuclear Information System (INIS)

    Hakin, Andrew W.; Lian Liu, Jin; Erickson, Kristy; Munoz, Julie-Vanessa

    2004-01-01

    Acidified aqueous solutions of Pr(ClO 4 ) 3 (aq), Gd(ClO 4 ) 3 (aq), Ho(ClO 4 ) 3 (aq), and Tm(ClO 4 ) 3 (aq) were prepared from the corresponding oxides by dissolution in dilute perchloric acid. Once characterized with respect to trivalent metal cation and acid content, the relative densities of the solutions were measured at T=(288.15, 298.15, 313.15, and 328.15) K and p=0.1 MPa using a Sodev O2D vibrating tube densimeter. The relative massic heat capacities of the aqueous systems were also determined, under the same temperature and pressure conditions, using a Picker Flow Microcalorimeter. All measurements were made on solutions containing rare earth salt in the concentration range 0.01 ≤ m/(mol · kg -1 ) ≤ 0.2. Relative densities and relative massic heat capacities were used to calculate the apparent molar volumes and apparent molar heat capacities of the acidified salt solutions from which the apparent molar properties of the aqueous salt solutions were extracted by the application of Young's Rule. The concentration dependences of the isothermal apparent molar volumes and heat capacities of each aqueous salt solution were modelled using Pitzer ion-interaction equations. These models produced estimates of apparent molar volumes and apparent molar heat capacities at infinite dilution for each set of isothermal V phi,2 and C pphi,2 values. In addition, the temperature and concentration dependences of the apparent molar volumes and apparent molar heat capacities of the aqueous rare earth perchlorate salt solutions were modelled using modified Pitzer ion-interaction equations. The latter equations utilized the Helgeson, Kirkham, and Flowers equations of state to model the temperature dependences (at p=0.1 MPa) of apparent molar volumes and apparent molar heat capacities at infinite dilution. The results of the latter models were compared to those previously published in the literature. Apparent molar volumes and apparent heat capacities at infinite dilution

  4. Apparent molar volumes and apparent molar heat capacities of aqueous adonitol, dulcitol, glycerol, meso-erythritol, myo-inositol, D-sorbitol, and xylitol at temperatures from (278.15 to 368.15) K and at the pressure 0.35 MPa

    International Nuclear Information System (INIS)

    Blodgett, M.B.; Ziemer, S.P.; Brown, B.R.; Niederhauser, T.L.; Woolley, E.M.

    2007-01-01

    Apparent molar volumes V φ were determined for aqueous adonitol, dulcitol, glycerol, meso-erythritol, myo-inositol, D-sorbitol, and xylitol at temperatures from (278.15 to 368.15) K and at the pressure 0.35 MPa, and apparent molar heat capacities C p,φ of the same solutions were determined at temperatures from (278.15 to 363.15) K at the same pressure. Molalities m/(mol . kg -1 ) of the solutions were in the range (0.02 ≤ m ≤ 3.2) for adonitol, (0.02 ≤ m ≤ 0.15) for dulcitol, (0.02 ≤ m ≤ 5.0) for glycerol, (0.02 ≤ m ≤ 3.0) for meso-erythritol, (0.02 ≤ m ≤ 0.5) for myo-inositol, (0.02 ≤ m ≤ 2.0) for D-sorbitol, and (0.02 ≤ m ≤ 2.7) for xylitol. A vibrating tube densimeter was used to obtain solution densities and a fixed-cell temperature scanning calorimeter was used to obtain heat capacities. Values of V φ and C p,φ for these sugar alcohols are discussed relative to one another and compared to values from the literature, where available

  5. Liquid phase PVTx properties of (water + tert-butanol) binary mixtures at temperatures from 278.15 to 323.15 K and pressures from 0.1 to 100 MPa. II. Molar isothermal compressions, molar isobaric expansions, molar thermal pressure coefficients, and internal pressure

    International Nuclear Information System (INIS)

    Egorov, Gennadiy I.; Makarov, Dmitriy M.; Kolker, Arkadiy M.

    2013-01-01

    Highlights: ► Molar isothermal compressions and molar isobaric expansions were evaluated. ► Coefficients of thermal pressure and internal pressure were obtained. ► Concentration dependences of coefficients under study display extremes. ► Temperature and pressure dependences of internal pressure of the mixture were linear. -- Abstract: Molar isothermal compressions, molar isobaric expansions, molar coefficients of thermal pressure, and internal pressure were calculated over the whole concentration range of {water (1) + tert-butanol (2)} mixture at pressures from 0.1 to 100 MPa and temperatures from 278.15 to 323.15 K. It was revealed that the extremes, observed on concentration dependences of molar isothermal compression K T,m and molar isobaric expansion E P,m of the mixture, became more pronounced with pressure growth and temperature lowering. Values of molar thermal pressure coefficients of the mixture sharply rose at compositions with small TBA mole fraction and then decreased practically linearly with the alcohol content increasing. Temperature and pressure dependences of the mixture internal pressure were almost linear, and at low TBA concentrations changed significantly from the dependences of water, tert-butanol and their mixtures at large alcohol content

  6. The volumetric and thermochemical properties of Y(ClO4)3 (aq), Yb(ClO4)3 (aq), Dy(ClO4)3 (aq), and Sm(ClO4)3 (aq) at T=(288.15,298.15,313.15, and 328.15) K and p=0.1 MPa

    International Nuclear Information System (INIS)

    Hakin, Andrew W.; Lukacs, Michael J.; Liu, Jin Lian; Erickson, Kristy; Madhavji, Asha

    2003-01-01

    Relative densities and relative massic heat capacities have been measured for aqueous solutions of Y(ClO 4 ) 3 , Yb(ClO 4 ) 3 , Dy(ClO 4 ) 3 , and Sm(ClO 4 ) 3 at T=(288.15,298.15,313.15, and 328.15) K and p=0.1 MPa. These measurements were made in the concentration range 0.01624≤m/(mol·kg -1 )≤0.41822 using a Sodev 02D Vibrating Tube Densimeter and a Picker Microflow Calorimeter, respectively. To counter the potential effects of hydrolysis, aqueous solutions of the investigated salts were acidified with perchloric acid. After correcting for the presence of the acid, the measured properties were used to calculate apparent molar volumes and apparent molar heat capacities for solutions of the perchlorate salts in water. The calculated apparent molar properties were modeled at each investigated temperature using Pitzer ion interaction equations to produce estimates of apparent molar volumes and heat capacities at infinite dilution. In addition, the temperature dependences of the apparent molar properties of each salt were found to be well modeled by temperature dependent Pitzer ion interaction equations. The Helgeson, Kirham, and Flowers equations of state were incorporated into the Pitzer ion interaction equations in order to model the infinite dilution properties of the salts. Single ion volumes and heat capacities of the investigated trivalent metal cations have been calculated and compared to previously reported values

  7. Apparent molar volumes and apparent molar heat capacities of aqueous tetrahydrofuran, dimethyl sulfoxide, 1,4-dioxane, and 1,2-dimethoxyethane at temperatures from 278.15 K to 393.15 K and at the pressure 0.35 MPa

    International Nuclear Information System (INIS)

    Swenson, D.M.; Blodgett, M.B.; Ziemer, S.P.; Woolley, E.M.

    2008-01-01

    We determined apparent molar volumes V φ at 278.15 ≤ (T/K) ≤ 368.15 and apparent molar heat capacities C p,φ at 278.15 ≤ (T/K) ≤ 393.15 at p = 0.35 MPa for aqueous solutions of tetrahydrofuran at m from (0.016 to 2.5) mol . kg -1 , dimethyl sulfoxide at m from (0.02 to 3.0) mol . kg -1 , 1,4-dioxane at m from (0.015 to 2.0) mol . kg -1 , and 1,2-dimethoxyethane at m from (0.01 to 2.0) mol . kg -1 . Values of V φ were determined from densities measured with a vibrating-tube densimeter, and values of C p,φ were determined with a twin fixed-cell, differential, temperature-scanning calorimeter. Empirical functions of m and T for each compound were fitted to our V φ and C p,φ results

  8. Prediction of the critical reduced electric field strength for carbon dioxide and its mixtures with copper vapor from Boltzmann analysis for a gas temperature range of 300 K to 4000 K at 0.4 MPa

    Energy Technology Data Exchange (ETDEWEB)

    Li, Xingwen, E-mail: xwli@mail.xjtu.edu.cn; Guo, Xiaoxue; Zhao, Hu; Jia, Shenli [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, No. 28 XianNing West Road, Xi' an, Shaanxi Province 710049 (China); Murphy, Anthony B. [CSIRO Manufacturing Flagship, PO Box 218, Lindfield NSW 2070 (Australia)

    2015-04-14

    The influence of copper vapor mixed in hot CO{sub 2} on dielectric breakdown properties of gas mixture at a fixed pressure of 0.4 MPa for a temperature range of 300 K–4000 K is numerically analyzed. First, the equilibrium composition of hot CO{sub 2} with different copper fractions is calculated using a method based on mass action law. The next stage is devoted to computing the electron energy distribution functions (EEDF) by solving the two-term Boltzmann equation. The reduced ionization coefficient, the reduced attachment coefficient, and the reduced effective ionization coefficient are then obtained based on the EEDF. Finally, the critical reduced electric field (E/N){sub cr} is obtained. The results indicate that an increasing mole fraction of copper markedly reduces (E/N){sub cr} of the CO{sub 2}–Cu gas mixtures because of copper's low ionization potential and large ionization cross section. Additionally, the generation of O{sub 2} from the thermal dissociation of CO{sub 2} contributes to the increase of (E/N){sub cr} of CO{sub 2}–Cu hot gas mixtures from about 2000 K to 3500 K.

  9. Apparent molar volumes and apparent molar heat capacities of aqueous adonitol, dulcitol, glycerol, meso-erythritol, myo-inositol, D-sorbitol, and xylitol at temperatures from (278.15 to 368.15) K and at the pressure 0.35 MPa

    Energy Technology Data Exchange (ETDEWEB)

    Blodgett, M.B. [Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT, 84602-5700 (United States); Ziemer, S.P. [Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT, 84602-5700 (United States); Brown, B.R. [Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT, 84602-5700 (United States); Niederhauser, T.L. [Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT, 84602-5700 (United States); Woolley, E.M. [Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT, 84602-5700 (United States)]. E-mail: earl_woolley@byu.edu

    2007-04-15

    Apparent molar volumes V {sub {phi}} were determined for aqueous adonitol, dulcitol, glycerol, meso-erythritol, myo-inositol, D-sorbitol, and xylitol at temperatures from (278.15 to 368.15) K and at the pressure 0.35 MPa, and apparent molar heat capacities C {sub p,{phi}} of the same solutions were determined at temperatures from (278.15 to 363.15) K at the same pressure. Molalities m/(mol . kg{sup -1}) of the solutions were in the range (0.02 {<=} m {<=} 3.2) for adonitol, (0.02 {<=} m {<=} 0.15) for dulcitol, (0.02 {<=} m {<=} 5.0) for glycerol, (0.02 {<=} m {<=} 3.0) for meso-erythritol, (0.02 {<=} m {<=} 0.5) for myo-inositol, (0.02 {<=} m {<=} 2.0) for D-sorbitol, and (0.02 {<=} m {<=} 2.7) for xylitol. A vibrating tube densimeter was used to obtain solution densities and a fixed-cell temperature scanning calorimeter was used to obtain heat capacities. Values of V {sub {phi}} and C {sub p,{phi}} for these sugar alcohols are discussed relative to one another and compared to values from the literature, where available.

  10. Speed of sound in saturated aliphatic alcohols (propan-2-ol, butan-2-ol, and 2-methylpropan-1-ol) and alkanediols (ethane-1,2-diol, propane-1,2- and -1,3-diol) at temperature between 253.15 K and 353.15 K and pressures up to 30 MPa

    International Nuclear Information System (INIS)

    Dávila, María J.; Gedanitz, Holger; Span, Roland

    2016-01-01

    Highlights: • Speed of sound measurements were made in aliphatic alcohols and alkanediols. • Speeds of sound were measured in a wide temperature and pressure range. • A pulse-echo method with a double path type sensor operating at 8 MHz was employed. • A double polynomial equation was used to fit the experimental speed of sound data. • The accurate results were compared with available literature sources. - Abstract: Speeds of sound have been measured in three saturated aliphatic alcohols (propan-2-ol, butan-2-ol, and 2-methylpropan-1-ol) and three alkanediols (ethane-1,2-diol, propane-1,2- and -1,3-diol) in the temperature range from (253.15 to 353.15) K and pressures up to 30 MPa by use of a pulse-echo method with a double path type sensor operating at 8 MHz. The expanded overall uncertainties (k = 2) in the speed of sound measurements are estimated to be 0.013% for propan-2-ol, 0.019% for butan-2-ol, 0.01% for 2-methylpropan-1-ol, 0.009% for ethane-1,2-diol, 0.02% for propane-1,2-diol, and 0.07% for propane-1,3-diol. Experimental speeds of sound data were correlated with the temperature and pressure with an empirical double polynomial equation. Our results were also compared with the available literature data and a satisfactory agreement was found.

  11. Apparent molar volumes and apparent molar heat capacities of Pr(NO3)3(aq), Gd(NO3)3(aq), Ho(NO3)3(aq), and Y(NO3)3(aq) at T (288.15, 298.15, 313.15, and 328.15) K and p = 0.1 MPa

    International Nuclear Information System (INIS)

    Hakin, Andrew W.; Liu Jinlian; Erickson, Kristy; Munoz, Julie-Vanessa; Rard, Joseph A.

    2005-01-01

    Relative densities and relative massic heat capacities have been measured for acidified solutions of Y(NO 3 ) 3 (aq), Pr(NO 3 ) 3 (aq), and Gd(NO 3 ) 3 (aq) at T = (288.15, 298.15, 313.15, and 328.15) K and p = 0.1 MPa. In addition, relative densities and massic heat capacities have been measured at the same temperatures and pressure for Y(NO 3 ) 3 (aq) and Ho(NO 3 ) 3 (aq) solutions without excess acid (n.b. measurements at T = 328.15 K for Ho(NO 3 ) 3 (aq) were not performed due to the limited volume of solution available). Apparent molar volumes and apparent molar heat capacities for the aqueous salt solutions have been calculated from the experimental apparent molar properties of the acidified solutions using Young's rule, whereas the apparent molar properties of the solutions without excess acid were calculated directly from the measured densities and massic heat capacities. The two sets of data for the Y(NO 3 ) 3 (aq) systems provide a check of the internal consistency of the Young's rule approach we have utilised. The concentration dependences of the apparent molar volumes and heat capacities of the aqueous salt solutions have been modelled at each investigated temperature using the Pitzer ion interaction equations to yield apparent molar properties at infinite dilution. Complex formation within the aqueous rare earth nitrate systems is discussed qualitatively by probing the concentration dependence of apparent molar volumes and heat capacities. In spite of the complex formation in the aqueous rare earth nitrate systems, there is a high degree of self-consistency between the apparent molar volumes and heat capacities at infinite dilution reported in this manuscript and those previously reported for aqueous rare earth perchlorates

  12. Apparent molar volumes and apparent molar heat capacities of Pr(NO{sub 3}){sub 3}(aq), Gd(NO{sub 3}){sub 3}(aq), Ho(NO{sub 3}){sub 3}(aq), and Y(NO{sub 3}){sub 3}(aq) at T (288.15, 298.15, 313.15, and 328.15) K and p = 0.1 MPa

    Energy Technology Data Exchange (ETDEWEB)

    Hakin, Andrew W. [Department of Chemistry and Biochemistry, University of Lethbridge, 4401 University Drive, Lethbridge, Alberta, T1K 3M4 (Canada)]. E-mail: hakin@uleth.ca; Liu Jinlian [Department of Chemistry and Biochemistry, University of Lethbridge, 4401 University Drive, Lethbridge, Alberta, T1K 3M4 (Canada); Erickson, Kristy [Department of Chemistry and Biochemistry, University of Lethbridge, 4401 University Drive, Lethbridge, Alberta, T1K 3M4 (Canada); Munoz, Julie-Vanessa [Department of Chemistry and Biochemistry, University of Lethbridge, 4401 University Drive, Lethbridge, Alberta, T1K 3M4 (Canada); Rard, Joseph A. [Energy and Environment Directorate, Lawrence Livermore National Laboratory, University of California, Livermore, CA 94550 (United States)

    2005-02-01

    Relative densities and relative massic heat capacities have been measured for acidified solutions of Y(NO{sub 3}){sub 3}(aq), Pr(NO{sub 3}){sub 3}(aq), and Gd(NO{sub 3}){sub 3}(aq) at T = (288.15, 298.15, 313.15, and 328.15) K and p = 0.1 MPa. In addition, relative densities and massic heat capacities have been measured at the same temperatures and pressure for Y(NO{sub 3}){sub 3}(aq) and Ho(NO{sub 3}){sub 3}(aq) solutions without excess acid (n.b. measurements at T = 328.15 K for Ho(NO{sub 3}){sub 3}(aq) were not performed due to the limited volume of solution available). Apparent molar volumes and apparent molar heat capacities for the aqueous salt solutions have been calculated from the experimental apparent molar properties of the acidified solutions using Young's rule, whereas the apparent molar properties of the solutions without excess acid were calculated directly from the measured densities and massic heat capacities. The two sets of data for the Y(NO{sub 3}){sub 3}(aq) systems provide a check of the internal consistency of the Young's rule approach we have utilised. The concentration dependences of the apparent molar volumes and heat capacities of the aqueous salt solutions have been modelled at each investigated temperature using the Pitzer ion interaction equations to yield apparent molar properties at infinite dilution. Complex formation within the aqueous rare earth nitrate systems is discussed qualitatively by probing the concentration dependence of apparent molar volumes and heat capacities. In spite of the complex formation in the aqueous rare earth nitrate systems, there is a high degree of self-consistency between the apparent molar volumes and heat capacities at infinite dilution reported in this manuscript and those previously reported for aqueous rare earth perchlorates.

  13. Thermodynamics of proton dissociations from aqueous glycine at temperatures from 278.15 to 393.15 K, molalities from 0 to 1.0 mol . kg-1, and at the pressure 0.35 MPa: Apparent molar heat capacities and apparent molar volumes of glycine, glycinium chloride, and sodium glycinate

    International Nuclear Information System (INIS)

    Ziemer, S.P.; Niederhauser, T.L.; Merkley, E.D.; Price, J.L.; Sorenson, E.C.; McRae, B.R.; Patterson, B.A.; Origlia-Luster, M.L.; Woolley, E.M.

    2006-01-01

    We have measured the densities of aqueous solutions of glycine, glycine plus equimolal HCl, and glycine plus equimolal NaOH at temperatures 278.15 ≤ T/K ≤ 368.15, molalities 0.01 ≤ m/mol . kg -1 ≤ 1.0, and at p = 0.35 MPa, using a vibrating tube densimeter. We have also measured the heat capacities of these solutions at 278.15 ≤ T/K ≤ 393.15 and at the same m and p using a fixed-cell differential scanning calorimeter. We used the densities to calculate apparent molar volumes V φ and the heat capacities to calculate apparent molar heat capacities C p,φ for these solutions. We used our results and values of V φ (T, m) and C p,φ (T, m) for HCl(aq), NaOH(aq), NaCl(aq) from the literature to calculate parameters for Δ r C p,m (T, m) for the first and second proton dissociations from protonated aqueous cationic glycine. We then integrated this value of Δ r C p,m (T, m) in an iterative algorithm, using Young's Rule to account for the effects of speciation and chemical relaxation on the observed V φ and C p,φ of the solutions. This procedure yielded parameters for V φ (T, m) and C p,φ (T, m) for glycinium chloride {H 2 Gly + Cl - (aq)} and sodium glycinate {Na + Gly - (aq)} which successfully modeled our observed results. We have then calculated values of Δ r C p,m , Δ r H m , Δ r V m , and pQ a for the first and second proton dissociations from protonated aqueous glycine as functions of T and m

  14. An experimental study of the solubility of molybdenum in H2O and KCl-H2O solutions from 500 ºC to 800 ºC, and 150 to 300 MPa

    Energy Technology Data Exchange (ETDEWEB)

    Ulrich, Thomas; Mavrogenes, John [Australian National University

    2008-04-22

    The solubility of molybdenum (Mo) was determined at temperatures from 500 °C to 800 °C and 150 to 300 MPa in KCl-H2O and pure H2O solutions in cold-seal experiments. The solutions were trapped as synthetic fluid inclusions in quartz at experimental conditions, and analyzed by laser ablation inductively coupled plasma mass spectrometry (LA ICPMS). Mo solubilities of 1.6 wt% in the case of KCl-bearing aqueous solutions and up to 0.8 wt% in pure H2O were found. Mo solubility is temperature dependent, but not pressure dependent over the investigated range, and correlates positively with salinity (KCl concentration). Molar ratios of ~1 for Mo/Cl and Mo/K are derived based on our data. In combination with results of synchrotron X-ray absorption spectroscopy of individual fluid inclusions, it is suggested that Mo-oxo-chloride complexes are present at high salinity (>20 wt% KCl) and ion pairs at moderate to low salinity (<11 wt% KCl) in KCl-H2O aqueous solutions. Similarly, in the pure H2O experiments molybdic acid is the dominant species in aqueous solution. The results of these hydrothermal Mo experiments fit with earlier studies conducted at lower temperatures and indicate that high Mo concentrations can be transported in aqueous solutions. Therefore, the Mo concentration in aqueous fluids seems not to be the limiting factor for ore formation, whereas precipitation processes and the availability of sulfur appear to be the main controlling factors in the formation of molybdenite (MoS2).

  15. Apparent molar heat capacities and apparent molar volumes of Pr(ClO{sub 4}){sub 3}(aq), Gd(ClO{sub 4}){sub 3}(aq), Ho(ClO{sub 4}){sub 3}(aq), and Tm(ClO{sub 4}){sub 3}(aq) at T=(288.15, 298.15, 313.15, and 328.15) K and p=0.1 MPa

    Energy Technology Data Exchange (ETDEWEB)

    Hakin, Andrew W. E-mail: hakin@uleth.ca; Lian Liu, Jin; Erickson, Kristy; Munoz, Julie-Vanessa

    2004-09-01

    Acidified aqueous solutions of Pr(ClO{sub 4}){sub 3}(aq), Gd(ClO{sub 4}){sub 3}(aq), Ho(ClO{sub 4}){sub 3}(aq), and Tm(ClO{sub 4}){sub 3}(aq) were prepared from the corresponding oxides by dissolution in dilute perchloric acid. Once characterized with respect to trivalent metal cation and acid content, the relative densities of the solutions were measured at T=(288.15, 298.15, 313.15, and 328.15) K and p=0.1 MPa using a Sodev O2D vibrating tube densimeter. The relative massic heat capacities of the aqueous systems were also determined, under the same temperature and pressure conditions, using a Picker Flow Microcalorimeter. All measurements were made on solutions containing rare earth salt in the concentration range 0.01 {<=} m/(mol {center_dot} kg{sup -1}) {<=} 0.2. Relative densities and relative massic heat capacities were used to calculate the apparent molar volumes and apparent molar heat capacities of the acidified salt solutions from which the apparent molar properties of the aqueous salt solutions were extracted by the application of Young's Rule. The concentration dependences of the isothermal apparent molar volumes and heat capacities of each aqueous salt solution were modelled using Pitzer ion-interaction equations. These models produced estimates of apparent molar volumes and apparent molar heat capacities at infinite dilution for each set of isothermal V{sub phi,2} and C{sub pphi,2} values. In addition, the temperature and concentration dependences of the apparent molar volumes and apparent molar heat capacities of the aqueous rare earth perchlorate salt solutions were modelled using modified Pitzer ion-interaction equations. The latter equations utilized the Helgeson, Kirkham, and Flowers equations of state to model the temperature dependences (at p=0.1 MPa) of apparent molar volumes and apparent molar heat capacities at infinite dilution. The results of the latter models were compared to those previously published in the literature. Apparent

  16. Safety and reliability of a multiphase pump system (MPA). Phase 1b; Sicherheit und Zuverlaessigkeit eines Mehrphasen-Pumpen Systems (MPA). Phase 1b

    Energy Technology Data Exchange (ETDEWEB)

    Wuersig, G.; Woehren, N.

    2001-07-01

    Since October 1997 Germanischer Lloyd, Johann Heinrich Bornemann GmbH (JHB) and other partners are working together to develop a multiphase pumping unit for sub sea application. Key component of the system is the twin screw pump developed by JHB. A very long running time between possible maintenance work is required due to the application of the system in very deep water. The research work reported are basics for the development of a real time condition monitoring system which currently is developed by Germanischer Lloyd within the scope of the next phase of the project. The following tasks have been part of Germanischer Lloyd work in MTK 616: (a) Evaluation of the mechanical system structure by use of a 3-dimentional coupled finite element model (Section 6.) of the pump. (b) First experiments on a test pump at JHB in Obernkirchen (Section 7.). (c) Systematic evaluation of possible failure modes (Section 8.1) to define the safety relevant modes and for the technical interpretation of system behaviour. (d) Evaluation of the fluid dynamic system behaviour (Section 8.2) as basis for the planned development of the simulation model which will be part of the condition monitoring system. The results are the scientific and technical bases for the work in the running project supported by BMBF under identification number MTK 623. (orig.) [German] Seit Oktober 1997 arbeitet der Germanische Lloyd zusammen mit der Firma Johann Heinrich Bornemann GmbH (JHB) und anderen Partnern an der Entwicklung von unter Wasser einsetzbaren Systemen zur Foerderung von Oel/Gas/Feststoff-Gemischen. Zentrales Element ist dabei die von JHB entwickelte Schraubenspindelpumpe mit sehr langen wartungsfreien Laufzeiten. Die Arbeiten, ueber die hier berichtet wird, sind Voraussetzung fuer die Entwicklung eines Systems zur Zustandsbeurteilung in einem anschliessenden Projekt und umfassen: (a) Mechanische konstruktionsbegleitende Stukturanalyse (vgl. Abschnitt 6) der Pumpe mit Hilfe von gekoppelten dreidimensionalen Finite Elemente Rechnungen. (b) Vorversuche an einer Versuchspumpe bei JHB als Teil der Definition des Messwerterfassungssystems (Abschnitt 7). (c) Systematische Analyse der moeglichen Fehlerzustaende (Abschnitt 8.1) zur Definition sicherheitsrelevanter Fehlerzustaende und zur technischen Beurteilung des Systems. (d) Untersuchungen zur Fluiddynamik (Abschnitt 8.2) als Basis fuer die geplante Entwicklung des als Teil der Zustandsueberwachung geplanten Simulationsmodells. Das Vorhaben wurde erfolgreich abgeschlossen und bildet die technisch wissenschaftliche Grundlage der z.Z. im Folgevorhaben MTK-0623 laufenden Arbeiten. (orig.)

  17. Solubility and diffusivity of CO2 in the ionic liquid 1-butyl-3-methylimidazolium tricyanomethanide within a large pressure range (0.01 MPa to 10 MPa)

    NARCIS (Netherlands)

    Zubeir, L.F.; Romanos, G.E.; Weggemans, W.M.A.; Iliev, B.; Schubert, T.J.S.; Kroon, M.C.

    2015-01-01

    Ionic liquids (ILs) are promising solvents for carbon capture because of their high sorption capacity and low regeneration energy compared to conventional amine-based solvents. Previously, tetracyanoborate-based ILs have shown enhanced carbon dioxide (CO2) absorption capacity and absorption kinetics

  18. Development of TS590MPa grade high tensile strength steel for automotive anti-collision parts; Shogeki kyushuyo 590MPa kyu kochoryoku koban no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Miura, K; Takagi, S; Furukimi, O; Hira, T; Obara, T [Kawasaki Steel Corp., Tokyo (Japan); Tanimura, S [University of Osaka Prefecture, Osaka (Japan)

    1997-10-01

    The effects of strain rate on the deformation behavior of steels were investigated to find the most appropriate micro-structure of steel for anti-crash parts of automobiles, such as front-side-members. The dual phase steel absorbed a higher amount of energy during dynamic deformation than other steels with the same static yield strength. The increase of volume fraction of the austenite phase in the dual phase steel deteriorates the dynamic deformation behavior. The FEM analysis for crash test of HAT-sectional sheet box also showed the superior performance of the dual phase steel. 4 refs., 7 figs., 1 tab.

  19. The volumetric and thermochemical properties of YCl{sub 3}(aq), YbCl{sub 3}(aq), DyCl{sub 3}(aq), SmCl{sub 3}(aq), and GdCl{sub 3}(aq) at T=(288.15, 298.15, 313.15, and 328.15) K and p=0.1 MPa[Trivalent metal chlorides; Densities; Heat capacities; Single ion properties; Calorimetry; Densimetry

    Energy Technology Data Exchange (ETDEWEB)

    Hakin, Andrew W. E-mail: hakin@uleth.ca; Lukacs, Michael J.; Liu, Jin Lian; Erickson, Kristy

    2003-11-01

    Relative densities and massic heat capacities have been measured for acidified aqueous solutions of YCl{sub 3}(aq), YbCl{sub 3}(aq), DyCl{sub 3}(aq), SmCl{sub 3}(aq), and GdCl{sub 3}(aq) at T=(288.15, 298.15, 313.15, and 328.15) K and p=0.1 MPa. These measurements have been used to calculate experimental apparent molar volumes and heat capacities which, when used in conjunction with Young's rule, were used to calculate the apparent molar properties of the aqueous chloride salt solutions. The latter calculations required the use of volumetric and thermochemical data for aqueous solutions of hydrochloric acid that have been previously reported in the literature. The concentration dependences of the apparent molar properties have been modeled using Pitzer ion interaction equations to yield apparent molar volumes and heat capacities at infinite dilution. The temperature and concentration dependences of the apparent molar volumes and heat capacities of each trivalent salt system were modeled using modified Pitzer ion interaction equations. These equations utilized the revised Helgeson, Kirkham, and Flowers equations of state to model the temperature dependences of apparent molar volumes and heat capacities at infinite dilution. Calculated apparent molar volumes and heat capacities at infinite dilution have been used to calculate single ion properties for the investigated trivalent metal cations. These values have been compared to those previously reported in the literature. The differences between single ion values calculated in this study and those values calculated from thermodynamic data for aqueous perchlorate salts are also discussed.

  20. Computer simulations of austenite decomposition of microalloyed 700 MPa steel during cooling

    Science.gov (United States)

    Pohjonen, Aarne; Paananen, Joni; Mourujärvi, Juho; Manninen, Timo; Larkiola, Jari; Porter, David

    2018-05-01

    We present computer simulations of austenite decomposition to ferrite and bainite during cooling. The phase transformation model is based on Johnson-Mehl-Avrami-Kolmogorov type equations. The model is parameterized by numerical fitting to continuous cooling data obtained with Gleeble thermo-mechanical simulator and it can be used for calculation of the transformation behavior occurring during cooling along any cooling path. The phase transformation model has been coupled with heat conduction simulations. The model includes separate parameters to account for the incubation stage and for the kinetics after the transformation has started. The incubation time is calculated with inversion of the CCT transformation start time. For heat conduction simulations we employed our own parallelized 2-dimensional finite difference code. In addition, the transformation model was also implemented as a subroutine in commercial finite-element software Abaqus which allows for the use of the model in various engineering applications.

  1. 38th MPA-Seminar 2012. Power generation and energy efficiency. Materials and component behaviour

    International Nuclear Information System (INIS)

    2012-01-01

    This conference paper contains the abstracts of lectures and posters. On the accompanying CD-ROM are the manuscripts of the lectures and posters. The four main topics of this paper are: Nuclear Energy; Alternative energy generation; Sealing technology; and Power Plants. 17 of the papers are separately analyzed for this database.

  2. The impact of Nassau grouper size and abundance on scuba diver site selection and MPA economics

    NARCIS (Netherlands)

    Rudd, M.A.; Tupper, M.H.

    2002-01-01

    Since many fisheries are size-selective, the establishment of marine protected areas (MPAs) is expected to increase both the average size and abundance of exploited species, such as the valuable but vulnerable Nassau grouper ( Epinephelus striatus ). Increases in mean size and/or abundance of

  3. Synthesis and characterization of aqueous MPA-capped CdS–ZnS ...

    Indian Academy of Sciences (India)

    octylphosphine oxide, long-chain amine, or long-chain carboxylic acid as ... aqueous synthesis, aqueous synthesis is more productive, less costly, more .... It is also shown that the pH value of the solution and capping layers played important.

  4. 27. MPA-Seminar - Safety and reliability in energy technology. Vol. 1: Papers 1-26

    International Nuclear Information System (INIS)

    2001-01-01

    Contents with the main topics: Integrity assessment of thermal power plants and components; monitoring and nondestructive testing; life management of hydro power plants; design criteria and refurbishment; investigation of materials. (GL)

  5. Multibeam Mapping of the South Atlantic Bight: Georgia 2005, a Proposed MPA on the Continental Shelf

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The NOAA Fisheries laboratory in Panama City, Florida coordinated an acoustic survey at the new proposed Marine Protected Areas in the South Atlantic Bight area June...

  6. A Practical Note on Transferring Ideas and Methods from Consultancy Practice to the MPA Classroom

    DEFF Research Database (Denmark)

    Ry Nielsen, Jens Carl; Quinn, Brid

    2016-01-01

    At the lead author’s home institution – Copenhagen Business School (CBS) – the combination of theory and practice is seen as very important in teaching. Research-based teaching is the slogan. In this respect, CBS has the same ambition as other universities. But it seems as if CBS has an advantage...

  7. Report on the first workshop on Movement Pattern Analysis MPA10

    Directory of Open Access Journals (Sweden)

    Patrick Olivier Laube

    2011-01-01

    Full Text Available This paper reports on the 1st Workshop on Movement Pattern Analysis, held as a pre-GIScience 2010 workshop in September 2010 in Zurich, Switzerland. The report outlines the scientific motivation for the event, summarizes its main contributions and outcomes, discusses the implications of the gathering, and indicates directions for the road ahead.

  8. Reference Correlations for Thermophysical Properties of Liquid Water at 0.1 MPa

    Czech Academy of Sciences Publication Activity Database

    Pátek, Jaroslav; Hrubý, Jan; Klomfar, Jaroslav; Součková, Monika; Harvey, A.H.

    2009-01-01

    Roč. 38, č. 1 (2009), s. 21-29 ISSN 0047-2689 R&D Projects: GA AV ČR IAA200760701 Institutional research plan: CEZ:AV0Z20760514 Keywords : water * thermophysical properties * transport properties * calibration Subject RIV: BJ - Thermodynamics Impact factor: 2.093, year: 2009

  9. MPA-11: Materials Synthesis and Integrated Devices; Overview of an Applied Energy Group

    Energy Technology Data Exchange (ETDEWEB)

    Dattelbaum, Andrew Martin [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-11-16

    Our mission is to provide innovative and creative chemical synthesis and materials science solutions to solve materials problems across the LANL missions. Our group conducts basic and applied research in areas related to energy security as well as problems relevant to the Weapons Program.

  10. Reflections on Designing a MPA Service-Learning Component: Lessons Learned

    Science.gov (United States)

    Roman, Alexandru V.

    2015-01-01

    This article provides the "lessons learned" from the experience of redesigning two sections (face-to-face and online) of a core master of public administration class as a service-learning course. The suggestions made here can be traced to the entire process of the project, from the "seed idea" through its conceptualization and…

  11. Researching, Teaching and Professional Development: How to Build Quality and Reflection into Our MPA-Programmes?

    Science.gov (United States)

    Notten, Ton

    2013-01-01

    Continuing adult education requires continuous education of the educators themselves--a highly self-referential issue. This article focuses on educating a group of "urban educators" in the western part of the Netherlands who have been involved in broad urban educational programmes: school, parental education and participation, living…

  12. Preparing Principals: What Can We Learn from MBA and MPA Programmes?

    Science.gov (United States)

    Hallinger, Philip; Lu, Jiafang

    2013-01-01

    The past two decades have witnessed increasing global acceptance of the important role that capable leadership plays in education reform and school improvement. Consequently, policymakers internationally have actively sought means of strengthening capacity for school-level leadership, with a particular focus on the design of more effective…

  13. MPA and CPM Curriculum: An Analysis of the Views of Public Administrators.

    Science.gov (United States)

    Rose, Bruce J.

    Views of state public administrators about management education and training needs were investigated, as were administrator views concerning short-term management development workshops. Data was drawn from responses to questionnaires mailed to 5,980 state administrators who were selected from a national survey and from random samples using lists…

  14. Foulant analysis of hollow fine fiber (HFF) membranes in Red Sea SWRO plants using membrane punch autopsy (MPA)

    KAUST Repository

    Green, Troy N.; Al-Tisan, Ibrahim; Rahman, Mahmoodur; Al-Jehani, Yaser; Al-Hakamy, Al-Munther

    2017-01-01

    contained inorganic and organic foulants including bacteria. Fourier transform infrared spectroscopy analysis confirmed the presence of organic fouling functional groups and scanning electron microscopy with energy dispersive X-ray spectroscopy

  15. The Role of Reflection in the Pedagogical Thinking and Practice of the MPA Programme at Copenhagen Business School

    DEFF Research Database (Denmark)

    Ry Nielsen, Jens Carl

    2013-01-01

    Reflection plays a significant role in the pedagogical thinking and practice at the Copenhagen Business School Master of Public Administration Programme. It is thus embedded in one of the pedagogical models we have developed based on ideas from Argyris, Schön, Vygotsky, Senge, Lave and Wenger...

  16. Multibeam Mapping of the South Atlantic Bight: South Carolina 2005, a Proposed MPA on the Continental Shelf

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The NOAA Fisheries laboratory in Panama City, Florida coordinated an acoustic survey at the new proposed Marine Protected Areas in the South Atlantic Bight area June...

  17. Effect of Ni Addition on Bainite Transformation and Properties in a 2000 MPa Grade Ultrahigh Strength Bainitic Steel

    Science.gov (United States)

    Tian, Junyu; Xu, Guang; Jiang, Zhengyi; Hu, Haijiang; Zhou, Mingxing

    2018-05-01

    The effects of Nickle (Ni) addition on bainitic transformation and property of ultrahigh strength bainitic steels are investigated by three austempering processes. The results indicate that Ni addition hinders the isothermal bainite transformation kinetics, and decreases the volume fraction of bainite due to the decrease of chemical driving force for nucleation and growth of bainite transformation. Moreover, the product of tensile strength and total elongation (PSE) of high carbon bainitic steels decreases with Ni addition at higher austempering temperatures (220 and 250 °C), while it shows no significant difference at lower austempering temperature (200 °C). For the same steel (Ni-free or Ni-added steel), the amounts of bainite and RA firstly increase and then decrease with the increase of the austempering temperature, resulting in the highest PSE in the sample austempered at temperature of 220 °C. In addition, the effects of austempering time on bainite amount and property of high carbon bainitic steels are also analyzed. It indicates that in a given transformation time range of 30 h, more volume of bainite and better mechanical property in high carbon bainitic steels can be obtained by increasing the isothermal transformation time.

  18. Microbial oil-degradation under mild hydrostatic pressure (10 MPa): which pathways are impacted in piezosensitive hydrocarbonoclastic bacteria?

    KAUST Repository

    Scoma, Alberto; Barbato, Marta; Hernandez-Sanabria, Emma; Mapelli, Francesca; Daffonchio, Daniele; Borin, Sara; Boon, Nico

    2016-01-01

    . Analysis of its transcriptome revealed that 95% of its genes were downregulated. Increased transcription involved protein synthesis, energy generation and respiration pathways. Interplay between these factors may play a key role in shaping the structure

  19. Tagging target genes of the mat1-2-1 transcription factor in Fusarium verticillioides (Gibberella fujikuroi MP-A)

    NARCIS (Netherlands)

    Keszthelyi, A.; Jeney, A.; Kerenyi, Z.; Mendes, O.; Waalwijk, C.; Hornok, L.

    2007-01-01

    Mating type in filamentous ascomycetes is controlled by idiomorphic alleles, named MAT1-1 and MAT1-2, which contain 1-3 genes. Of these genes MAT1-1-1 and MAT1-2-1 encode putative transcription factors and are thus considered to be the major regulators of sexual communication and mating. Fungi with

  20. Effect of transverse loads up to 300 MPa on the critical currents of Nb3Sn cables

    NARCIS (Netherlands)

    Boschman, H.; Verweij, A.P.; Verweij, A.P.; Wessel, Wilhelm A.J.; ten Kate, Herman H.J.; van de Klundert, L.J.M.; van de Klundert, L.J.M.

    1991-01-01

    In the framework of the development of an experimental 10-T Nb3Sn dipole coil for the LHC (Large Hadron Collider) at CERN, the effects of transverse stress on Rutherford-type Nb3Sn cable were investigated. For this purpose a special facility was designed and put into operation in which the

  1. Reflecting the Context of MPA Education in the Time of Economic Crisis in Public Sectors in Britain and the Netherlands

    Science.gov (United States)

    Oldfield, Chrissie; Berg, Mireille van den

    2013-01-01

    The reality of the economic crisis and subsequent cuts in public sector funding in some European countries means that the context for public management education is significantly changing. In a period of economic constraint there is the obvious questioning of the cost of public management education programmes and even more of their relevance and…

  2. Effect of Annealed Oxides on the Formation of Inhibition Layer During Hot-Dip Galvanizing of 590Mpa Trip Steel

    International Nuclear Information System (INIS)

    Kim, Seong Hwan; Huh, Joo Youl; Lee, Suk Kyu; Park, Rho Bum; Kim, Jong Sang

    2011-01-01

    The selective surface oxidation of a transformation-induced-plasticity (TRIP) steel containing 1.6 wt.% Mn and 1.5 wt.% Si during annealing at 800 .deg. C was investigated for its influence on the formation of an inhibition layer during hot-dip galvanizing. The selective oxidation of the alloying elements and the oxide morphology were significantly influenced by the annealing atmosphere. The pure N 2 atmosphere with a dew point -40 .deg. C promoted the selective oxidation of Mn as a crystalline Mn 2 SiO 4 phase, whereas the N 2 + 10% H 2 atmosphere with the same dew point -40 .deg. C promoted the selective oxidation of Si as an amorphous Si-rich oxide phase. During hot-dip galvanizing, the Mn 2 SiO 4 phase was reduced more readily by Al in the Zn bath than the Si-rich oxide phase. Consequently, the pure N 2 atmosphere resulted in a higher formation rate of Fe 2 Al 5 particles at the Zn/steel interface and better galvanizability than the N 2 + 10% H 2 atmosphere

  3. NF-13-02-USVI Mapping Essential Fish Habitat in the US Caribbean to Inform MPA Management (EK60)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Scientists will collect high resolution multibeam and acoustic fisheries data in mid-water depths approximately 30 to 1000 meters so as to continue to characterize...

  4. Thermophysical properties of H2O - Ar plasmas at temperatures 400 - 50000K and pressure 0.1 MPa

    Czech Academy of Sciences Publication Activity Database

    Křenek, Petr

    2008-01-01

    Roč. 28, č. 1 (2008), s. 107-122 ISSN 0272-4324 Institutional research plan: CEZ:AV0Z20430508 Keywords : thermophysical properties of thermal plasmas * ionized gas mixtures * plasma composition * thermodynamic properties * Lennard – Jones interaction potential * screened Coulomb potential * effective collision cross sections * collision integrals * Chapman-Enskog method in the 4th approximation * viscosity * electrical conductivity * thermal conductivity Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.167, year: 2008

  5. NF-14-01 Mapping Essential Fish Habitat in the US Caribbean to Inform MPA Management (EK60)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Scientists will collect high resolution multibeam and acoustic fisheries data in mid-water depths approximately 30 to 1000 meters so as to continue to characterize...

  6. Effect of Annealed Oxides on the Formation of Inhibition Layer During Hot-Dip Galvanizing of 590Mpa Trip Steel

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Seong Hwan; Huh, Joo Youl [Korea University, Seoul (Korea, Republic of); Lee, Suk Kyu; Park, Rho Bum; Kim, Jong Sang [POSCO Technical Research Laboratories, Gwangyang (Korea, Republic of)

    2011-02-15

    The selective surface oxidation of a transformation-induced-plasticity (TRIP) steel containing 1.6 wt.% Mn and 1.5 wt.% Si during annealing at 800 .deg. C was investigated for its influence on the formation of an inhibition layer during hot-dip galvanizing. The selective oxidation of the alloying elements and the oxide morphology were significantly influenced by the annealing atmosphere. The pure N{sub 2} atmosphere with a dew point -40 .deg. C promoted the selective oxidation of Mn as a crystalline Mn{sub 2}SiO{sub 4} phase, whereas the N{sub 2} + 10% H{sub 2} atmosphere with the same dew point -40 .deg. C promoted the selective oxidation of Si as an amorphous Si-rich oxide phase. During hot-dip galvanizing, the Mn{sub 2}SiO{sub 4} phase was reduced more readily by Al in the Zn bath than the Si-rich oxide phase. Consequently, the pure N{sub 2} atmosphere resulted in a higher formation rate of Fe{sub 2}Al{sub 5} particles at the Zn/steel interface and better galvanizability than the N{sub 2} + 10% H{sub 2} atmosphere.

  7. The Role of Reflection in the Pedagogical Thinking and Practice of the MPA Programme at Copenhagen Business School

    Science.gov (United States)

    Ry Nielsen, J. C.

    2013-01-01

    Reflection plays a significant role in the pedagogical thinking and practice at the Copenhagen Business School Master of Public Administration Programme. It is thus embedded in one of the pedagogical models we have developed based on ideas from Argyris, Schön, Vygotsky, Senge, Lave and Wenger, and Schein. The model has four interrelated…

  8. Assess/monitor effects of MPA status on reef fish populations and spawning aggregations in the Tortugas Ecological Reserves

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — We supply abundance information of fish species along multiple randomly oriented transects at the lowest possible taxonomic level. This information is collected from...

  9. Surface tension and 0.1 MPa density of 1-alkyl-3-methylimidazolium tetrafluoroborates in a homologous series perspective

    Czech Academy of Sciences Publication Activity Database

    Součková, Monika; Klomfar, Jaroslav; Pátek, Jaroslav

    2016-01-01

    Roč. 100, September (2016), s. 79-88 ISSN 0021-9614 R&D Projects: GA ČR GA13-00145S Institutional support: RVO:61388998 Keywords : 1-Cn-3-methylimidazolium cation * tetrafluoroborate anion * density–temperature relation * surface tension–temperature relation * recommended property values Subject RIV: BJ - Thermodynamics Impact factor: 2.726, year: 2016

  10. Size dependence of upconversion photoluminescence in MPA capped CdTe quantum dots: Existence of upconversion bright point

    Energy Technology Data Exchange (ETDEWEB)

    Ananthakumar, S. [Crystal Growth Centre, Anna University, Chennai 600025 (India); Jayabalan, J., E-mail: jjaya@rrcat.gov.in [Laser Physics Applications Section, Raja Ramanna Centre for Advanced Technology, Indore 452013 (India); Singh, Asha; Khan, Salahuddin [Laser Physics Applications Section, Raja Ramanna Centre for Advanced Technology, Indore 452013 (India); Babu, S. Moorthy [Crystal Growth Centre, Anna University, Chennai 600025 (India); Chari, Rama [Laser Physics Applications Section, Raja Ramanna Centre for Advanced Technology, Indore 452013 (India)

    2016-01-15

    The photoluminescence (PL) from semiconductor quantum dots can show a “PL bright point”, that is the PL from as prepared quantum dots is maximum at a particular size. In this work we show that, for CdTe quantum dots, upconversion photoluminescence (UCPL) originating from nonlinear absorption shows a similar “UCPL bright point”. The PL and UCPL bright points occur at nearly the same size. The existence of a UCPL bright point has important implications for upconversion microscopy applications. - Highlights: • The size dependence of the upconversion photoluminescence (UCPL) spectrum of CdTe quantum dots has been reported. • We show that the UCPL from the CdTe quantum dots is highest at a particular size. • Thus the occurrence of a 'UCPL bright point' in CdTe quantum dots has been demonstrated. • It has been shown that the UCPL bright point occurs at nearly the same size as a normal bright point.

  11. Size dependence of upconversion photoluminescence in MPA capped CdTe quantum dots: Existence of upconversion bright point

    International Nuclear Information System (INIS)

    Ananthakumar, S.; Jayabalan, J.; Singh, Asha; Khan, Salahuddin; Babu, S. Moorthy; Chari, Rama

    2016-01-01

    The photoluminescence (PL) from semiconductor quantum dots can show a “PL bright point”, that is the PL from as prepared quantum dots is maximum at a particular size. In this work we show that, for CdTe quantum dots, upconversion photoluminescence (UCPL) originating from nonlinear absorption shows a similar “UCPL bright point”. The PL and UCPL bright points occur at nearly the same size. The existence of a UCPL bright point has important implications for upconversion microscopy applications. - Highlights: • The size dependence of the upconversion photoluminescence (UCPL) spectrum of CdTe quantum dots has been reported. • We show that the UCPL from the CdTe quantum dots is highest at a particular size. • Thus the occurrence of a "UCPL bright point" in CdTe quantum dots has been demonstrated. • It has been shown that the UCPL bright point occurs at nearly the same size as a normal bright point.

  12. 24. MPA-seminar: safety and reliability of plant technology with special emphasis on integrity and life management. Vol. 1. Papers 1-27

    International Nuclear Information System (INIS)

    1999-01-01

    The first volume is dedicated to the safety and reliability of plant technology with special emphasis on the integrity and life management. The main topic in the volume is the contribution of nondestructive testing to the reactor safety from an international point of view. All 20 papers are separately analyzed for this database. (orig.)

  13. Aquarius - A Modelling Package for Groundwater Flow and Coupled Heat Transport in the Range 0.1 to 100 MPa and 0.1 to 1000 C

    Science.gov (United States)

    Cook, S. J.

    2009-05-01

    Aquarius is a Windows application that models fluid flow and heat transport under conditions in which fluid buoyancy can significantly impact patterns and magnitudes of fluid flow. The package is designed as a visualization tool through which users can examine flow systems in environments, both low temperature aquifers and regions with elevated PT regimes such as deep sedimentary basins, hydrothermal systems, and contact thermal aureoles. The package includes 4 components: (1) A finite-element mesh generator/assembler capable of representing complex geologic structures. Left-hand, right-hand and alternating linear triangles can be mixed within the mesh. Planer horizontal, planer vertical and cylindrical vertical coordinate sections are supported. (2) A menu-selectable system for setting properties and boundary/initial conditions. The design retains mathematical terminology for all input parameters such as scalars (e.g., porosity), tensors (e.g., permeability), and boundary/initial conditions (e.g., fixed potential). This makes the package an effective instructional aide by linking model requirements with the underlying mathematical concepts of partial differential equations and the solution logic of boundary/initial value problems. (3) Solution algorithms for steady-state and time-transient fluid flow/heat transport problems. For all models, the nonlinear global matrix equations are solved sequentially using over-relaxation techniques. Matrix storage design allows for large (e.g., 20000) element models to run efficiently on a typical PC. (4) A plotting system that supports contouring nodal data (e.g., head), vector plots for flux data (e.g., specific discharge), and colour gradient plots for elemental data (e.g., porosity), water properties (e.g., density), and performance measures (e.g., Peclet numbers). Display graphics can be printed or saved in standard graphic formats (e.g., jpeg). This package was developed from procedural codes in C written originally to model the hydrothermal flow system responsible for contact metamorphism of Utah's Alta Stock (Cook et al., AJS 1997). These codes were reprogrammed in Microsoft C# to take advantage of object oriented design and the capabilities of Microsoft's .NET framework. The package is available at no cost by e-mail request from the author.

  14. 40th MPA-Seminar. Fit for the future? Problems in material technology, design and life time evaluation of existing and future power plants

    International Nuclear Information System (INIS)

    2014-01-01

    This conference paper contains the abstracts of lectures and posters. On the accompanying USB-stick are the manuscripts of the lectures and posters. The five main topics of this paper are: New Material Development; Renewable energy (Pump storage, Fuel cells, Wind turbine blades); Nuclear power; New materials for power plants - Qualification; Lifetime assessment und determination. Three of the papers are separately analyzed for this database.

  15. 40{sup th} MPA-Seminar. Fit for the future? Problems in material technology, design and life time evaluation of existing and future power plants

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2014-07-01

    This conference paper contains the abstracts of lectures and posters. On the accompanying USB-stick are the manuscripts of the lectures and posters. The five main topics of this paper are: New Material Development; Renewable energy (Pump storage, Fuel cells, Wind turbine blades); Nuclear power; New materials for power plants - Qualification; Lifetime assessment und determination. Three of the papers are separately analyzed for this database.

  16. Assessing the effects of marine protected area (MPA) on a reef fish assemblage in a northwestern Mediterranean marine reserve: Identifying community-based indicators

    OpenAIRE

    Claudet, Joachim; Pelletier, Dominique; Jouvenel, J.y; Bachet, F; Galzin, R

    2006-01-01

    Marine protected areas (MPAs) are increasingly envisaged as a tool to manage coastal ecosystems and fisheries. Assessment of their performance with respect to management objectives is therefore important. A number of WAS provided conservation benefits for fished species. Observed benefits do not apply to all species at all times, and responses to protection are also highly variable among fish taxa. Among the many empirical studies on marine reserves, only a few designs considered 'before and ...

  17. Reintroduction of the highly endangered mollusk Patella ferruginea Gmelin, 1791 in an MPA: A novel approach to achieve high survival rates

    Science.gov (United States)

    Zarrouk, Anis; Romdhane, Mohamed Salah; Espinosa, Free

    2018-03-01

    Patella ferruginea is the most endangered marine invertebrate of western Mediterranean rocky shores. After a study of one of its most important populations in the Zembra Archipelago National Park (Tunisia), a new protocol for the translocation of the species (size: 4-8 cm) was adopted. The first translocation was made in June 2014 in the same archipelago, where 94 specimens were moved from Zembretta to Zembra Island and marked (62 protected by cages, 20 with no cages and 60 as controls). The second translocation was performed in August 2014 (110 specimens) from Zembra to La Galite Island (185 km away). High mortality was registered during transport. The remaining individuals (39) were marked and placed in cages on the rocky shores of Galite Island, then monitored until November 2015. Growth and survival rates were measured in both translocated and control populations. The highest mortality rates were observed during the initial three days after translocation, especially for individuals with no cage protection. After a 697-day survey on Zembra Island, survival rates of 58%, 25% and 85% were observed for cage, no-cage and control populations, respectively. After a 457-day survey on La Galite Island, the survival rate was 18%. Limpets>6 cm in size had the highest survival rate among Zembra-translocated populations, whereas translocated limpets of 4-6 cm in size showed the highest survival rate in La Galite. The growth rates for both translocated populations were higher than the rate observed for controls. Our translocation experiment shows the importance of cage protection and initial limpet size for survival.

  18. (P, Vm, T) Measurements of (Octane + 1-Chlorohexane) at Temperatures from 298.15 K to 328.15 K and at Pressures Up to 40 MPa

    Czech Academy of Sciences Publication Activity Database

    Morávková, Lenka; Wagner, Zdeněk; Aim, Karel; Linek, Jan

    2006-01-01

    Roč. 38, č. 7 (2006), s. 861-870 ISSN 0021-9614 R&D Projects: GA AV ČR(CZ) IAA4072301 Institutional research plan: CEZ:AV0Z40720504 Keywords : density * isothermal compressibility * excess volume Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.842, year: 2006

  19. (p, Vm, T) Measurements of (Octane + Benzene) at Temperatures from (298.15 K to 328.15) K and at Pressures up to 40 MPa

    Czech Academy of Sciences Publication Activity Database

    Morávková, Lenka; Wagner, Zdeněk; Linek, Jan

    2008-01-01

    Roč. 40, č. 4 (2008), s. 607-617 ISSN 0021-9614 R&D Projects: GA ČR(CZ) GA104/06/0656 Institutional research plan: CEZ:AV0Z40720504 Keywords : density * isothermal compressibility * excess volume Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.876, year: 2008

  20. Peculiarities of welding procedure for the 05Kh12K14N5M5T-VD maraging stainless steel with strength higher 1500 MPa

    International Nuclear Information System (INIS)

    Pustovit, A.I.

    1980-01-01

    The effect of welding procedure of 05Kh12K14N5M5T-VD stainless steel on the properties of its welded joints is investigated. A new procedure of welding for pressure vessels made of this steel using Sv-03Kh15K14N5M3T-EL welding wire is suggested [ru

  1. The speciation of aqueous zinc(II) bromide solutions to 500 °C and 900 MPa determined using Raman spectroscopy

    Science.gov (United States)

    Mibe, Kenji; Chou, I-Ming; Anderson, Alan J.; Mayanovic, Robert A.; Bassett, William A.

    2009-01-01

    A Raman spectral study was carried out on 3 solutions of varying concentration and bromide/zinc ratios. Spectra were collected at 11 different temperature-pressure conditions ranging from ambient to 500????C-0.9??GPa. Raman band assignments for zinc(II) bromide species reported in previous studies were used to determine the relative concentrations of ZnBr42-, ZnBr3-, ZnBr2, and ZnBr+ species at various temperatures and pressures. Our results are in close agreement with X-ray absorption spectroscopic (XAS) data, and confirm that the tetrabromo zinc(II) complex, ZnBr42-, is the predominant species up to 500????C in solutions having high Zn concentrations (1??m) and high bromide/zinc molar ratios ([Br]/[Zn] = 8). In agreement with previous solubility and Raman spectroscopic experiments, our measurements indicate that species with a lower number of halide ligands and charge are favored with increasing temperature in dilute solutions, and solutions with low bromide/zinc ratios ([Br]/[Zn] Raman technique provides an independent experimental means of evaluating the quality of XAS analyses of data obtained from high temperature disordered systems. The combination of these two techniques provides complementary data on speciation and the structure of zinc(II) bromide complexes. The preponderance of the ZnBr42- species in highly saline brines at high temperature is consistent with the predominance of ZnCl42- in chloride-rich brines reported in previous XAS studies. Knowledge of Zn complexing in metal-rich highly saline brines is important for numerical models of ore deposition in high temperature systems such as skarns and porphyry-type deposits. ?? 2008 Elsevier B.V.

  2. Triaxial behaviour of a micro-concrete complete stress-strain curves for confining pressures ranging from 0 to 100 MPa

    International Nuclear Information System (INIS)

    Jamet, P.; Millard, A.; Nahas, G.

    1984-05-01

    A series of triaxial tests has been performed on micro-concrete cylinders. The specimens have been strained with a constant displacement rate, up to a deformation of about 10%. Two different domains were distinguihed. For low confining pressures strain softening is observed, the behaviour of the material becomes ductile for high confining pressures. Continuous measurement of the volume of fluid which had to be injected or withdrawn from the cell, to keep the confining pressure constant during the test, allowed to obtain data, concerning the overall lateral deformations of the specimens. Some specimens were also subjected to successive loadings with different confining pressures, in order to study the influence of stress path

  3. Analysing and modelling the growth behaviour of Listeria monocytogenes on RTE cooked meat products after a high pressure treatment at 400 MPa

    DEFF Research Database (Denmark)

    Hereu, A.; Dalgaard, Paw; Garriga, M.

    2014-01-01

    Various predictive models are available for high pressure inactivation of Listeria monocytogenes in food, but currently available models do not consider the growth kinetics of surviving cells during the subsequent storage of products. Therefore, we characterised the growth of L. monocytogenes in ...

  4. Growing Black Holes: Accretion in a Cosmological Context Proceedings of the MPA/ESO/MPE/USM Joint Astronomy Conference Held at Garching, Germany, 21-25 June 2004

    CERN Document Server

    Merloni, Andrea; Sunyaev, Rashid A

    2005-01-01

    Supermassive black holes are now believed to play an important role in the evolution of the Universe. Every respectable galaxy hosts in its center a black hole that appears to regulate the growth of the galaxy itself. In this book, leading experts in the field review the most recent theoretical and observational results on the following topics: * formation and growth of the first black holes in the Universe and their role in the formation and evolution of galaxies * the physics of black-hole accretion and the production of relativistic jets * binary black-hole mergers and gravitational radiation. Theoretical work is supplemented by the most recent exciting results from space and ground based observatories. This volume is useful research and reference tool for the entire astrophysical community.

  5. Temperature Dependence of the Surface Tension and Density at 0.1 MPa for 1-Ethyl- and 1-Butyl-3-methylimidazolium Dicyanamide

    Czech Academy of Sciences Publication Activity Database

    Klomfar, Jaroslav; Součková, Monika; Pátek, Jaroslav

    2011-01-01

    Roč. 56, č. 8 (2011), s. 3454-3462 ISSN 0021-9568 R&D Projects: GA ČR GA101/09/0010; GA AV ČR IAA200760701 Institutional research plan: CEZ:AV0Z20760514 Keywords : surface tension * density * dicyanamide * experimental data Subject RIV: BJ - Thermodynamics Impact factor: 1.693, year: 2011 http://pubs.acs.org/doi/abs/10.1021/je200502j

  6. Measurements and group contribution analysis of 0.1 MPa densities for still poorly studied ionic liquids with the [PF6] and [NTf2] anions

    Czech Academy of Sciences Publication Activity Database

    Součková, Monika; Klomfar, Jaroslav; Pátek, Jaroslav

    2014-01-01

    Roč. 77, October (2014), s. 31-39 ISSN 0021-9614 R&D Projects: GA ČR GA13-00145S; GA ČR GA101/09/0010 Institutional support: RVO:61388998 Keywords : ionic liquid * density * group contribution method * bis(trifluoromethylsulfonyl)imide anion * hexafluorophosphate anion Subject RIV: BJ - Thermodynamics Impact factor: 2.679, year: 2014 http://www.sciencedirect.com/science/article/pii/S0021961414001335

  7. Surface tension and 0.1 MPa densities of imidazolium-, pyridinium-, pyrrolidinium-, and piperidinium-based tris(pentafluoroethyl)trifluorophosphate ionic liquids

    Czech Academy of Sciences Publication Activity Database

    Součková, Monika; Klomfar, Jaroslav; Pátek, Jaroslav

    2012-01-01

    Roč. 333, NOV 15 2012 (2012), s. 38-46 ISSN 0378-3812 R&D Projects: GA ČR GA101/09/0010 Institutional research plan: CEZ:AV0Z20760514 Keywords : ionic liquid * tris(pentafluoroethyl)trifluorophosphate * density * surface tension Subject RIV: BJ - Thermodynamics Impact factor: 2.379, year: 2012 http://www.sciencedirect.com/science/article/pii/S037838121200310X

  8. P-rho-T Measurements for 1-Ethyl and 1-Butyl-3-methylimidazolium Dicyanamides from Their Melting Temperature to 353 K and up to 60 MPa in Pressure

    Czech Academy of Sciences Publication Activity Database

    Klomfar, Jaroslav; Součková, Monika; Pátek, Jaroslav

    2012-01-01

    Roč. 57, č. 4 (2012), s. 1213-1221 ISSN 0021-9568 R&D Projects: GA ČR GA101/09/0010; GA AV ČR IAA200760701 Institutional research plan: CEZ:AV0Z20760514 Keywords : dicyanamide * ionic liquids * p-v-T Subject RIV: BJ - Thermodynamics Impact factor: 2.004, year: 2012 http://pubs.acs.org/doi/full/10.1021/je201283n

  9. Excess Molar Volumes of (Octane + 1-Chloropentane) at Temperatures between 298.15 K and 328.15 K and at Pressures up to 40 MPa

    Czech Academy of Sciences Publication Activity Database

    Morávková, Lenka; Linek, Jan

    2003-01-01

    Roč. 35, č. 7 (2003), s. 1119-1127 ISSN 0021-9614 R&D Projects: GA ČR GA203/00/0600; GA ČR GA203/02/1098 Institutional research plan: CEZ:AV0Z4072921 Keywords : octane * 1-chloropentane * binary mixture Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 0.986, year: 2003

  10. (P, Vm, T) Measurements of (Toluene + Propiophenone) at Temperatures from 298.15 K to 328.15 K and at Pressures Up to 40 MPa

    Czech Academy of Sciences Publication Activity Database

    Morávková, Lenka; Wagner, Zdeněk; Linek, Jan

    2005-01-01

    Roč. 37, č. 7 (2005), s. 658-666 ISSN 0021-9614 R&D Projects: GA ČR(CZ) GA203/02/1098 Institutional research plan: CEZ:AV0Z40720504 Keywords : density * high pressure * elevated temperature Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.398, year: 2005

  11. Excess Molar Volumes of (Octane + 1-Chlorobutane) at Temperatures between 298.15 K and 328.15 K and at Pressures up to 40 MPa

    Czech Academy of Sciences Publication Activity Database

    Morávková, Lenka; Linek, Jan

    2003-01-01

    Roč. 35, č. 1 (2003), s. 113-121 ISSN 0021-9614 R&D Projects: GA ČR GA203/00/0600 Institutional research plan: CEZ:AV0Z4072921 Keywords : densities * excess molar volumes * mixtures Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 0.986, year: 2003

  12. Temperature Dependence Measurements of the Density at 0.1 MPa for 1-Alkyl-3-methylimidazolium-Based Ionic Liquids with the Trifluoromethanesulfonate and Tetrafluoroborate Anion

    Czech Academy of Sciences Publication Activity Database

    Klomfar, Jaroslav; Součková, Monika; Pátek, Jaroslav

    2010-01-01

    Roč. 55, č. 9 (2010), s. 4054-4057 ISSN 0021-9568 R&D Projects: GA AV ČR IAA200760701 Institutional research plan: CEZ:AV0Z20760514 Keywords : density * tetrafluoroborate * trifluoromethanesulfonate Subject RIV: BJ - Thermodynamics Impact factor: 2.089, year: 2010 http://pubs.acs.org/doi/pdfplus/10.1021/je100185e

  13. Excess molar volumes and partial molar volumes for (propionitrile + an alkanol) at T = 298.15 K and p = 0.1 MPa

    International Nuclear Information System (INIS)

    Deenadayalu, N.; Bhujrajh, P.

    2006-01-01

    The excess molar volumes and the partial molar volumes for (propionitrile + an alkanol) at T = 298.15 K and at atmospheric pressure are reported. The hydrogen bonding between the OH133;NC groups are discussed in terms of the chain length of the alkanol. The alkanols studied are (methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, and 1-pentanol). The excess molar volume data was fitted to the Redlich-Kister equation The partial molar volumes were calculated from the Redlich-Kister coefficients

  14. Density and viscosity of aqueous solutions of N,N-dimethylethanolamine at p = 0.1 MPa from T = (293.15 to 363.15) K

    Energy Technology Data Exchange (ETDEWEB)

    Bernal-Garcia, J. Manuel [Instituto Mexicano del Petroleo, Mexico D.F. C.P. 07330 (Mexico); Hall, Kenneth R. [Chemical Engineering Department, Texas A and M University, College Station, TX 77843 (United States); Estrada-Baltazar, Alejandro [Departamento de Ingenieria Quimica, Instituto Tecnologico de Celaya, Celaya, Guanajuato, CP 38010 (Mexico); Iglesias-Silva, Gustavo A. [Departamento de Ingenieria Quimica, Instituto Tecnologico de Celaya, Celaya, Guanajuato, CP 38010 (Mexico)]. E-mail: gais@iqcelaya.itc.mx

    2005-08-15

    This work presents atmospheric density and viscosity values for (N,N-dimethylethanolamine + water) over the entire composition range from T (293.15 to 363.15) K for density and from T = (313.15 to 353.15) K for viscosity. Density measurements come from a vibrating tube densimeter while we have used three different Cannon-Fenske viscosimeters for the viscosity measurements. Excess molar volumes and viscosity deviations are calculated using a Redlich-Kister type equation. Excess molar volumes present negative deviations from ideality and viscosity deviations are positive at all temperatures and compositions in this work.

  15. Density and viscosity of aqueous solutions of N,N-dimethylethanolamine at p = 0.1 MPa from T = (293.15 to 363.15) K

    International Nuclear Information System (INIS)

    Bernal-Garcia, J. Manuel; Hall, Kenneth R.; Estrada-Baltazar, Alejandro; Iglesias-Silva, Gustavo A.

    2005-01-01

    This work presents atmospheric density and viscosity values for (N,N-dimethylethanolamine + water) over the entire composition range from T (293.15 to 363.15) K for density and from T = (313.15 to 353.15) K for viscosity. Density measurements come from a vibrating tube densimeter while we have used three different Cannon-Fenske viscosimeters for the viscosity measurements. Excess molar volumes and viscosity deviations are calculated using a Redlich-Kister type equation. Excess molar volumes present negative deviations from ideality and viscosity deviations are positive at all temperatures and compositions in this work

  16. 24. MPA-seminar: safety and reliability of plant technology with special emphasis on integrity and life management. Vol. 2. Papers 28-63

    International Nuclear Information System (INIS)

    1999-01-01

    The second volume is dedicated to the safety and reliability of plant technology with special emphasis on the integrity and life management. The following topics are discussed: 1. Integrity of vessels, pipes and components. 2. Fracture mechanics. 3. Measures for the extension of service life, and 4. Online Monitoring. All 30 contributions are separately analyzed for this database. (orig.)

  17. The Pelagos Sanctuary for Mediterranean marine mammals: Marine Protected Area (MPA) or marine polluted area? The case study of the striped dolphin (Stenella coeruleoalba).

    Science.gov (United States)

    Fossi, Maria Cristina; Panti, Cristina; Marsili, Letizia; Maltese, Silvia; Spinsanti, Giacomo; Casini, Silvia; Caliani, Ilaria; Gaspari, Stefania; Muñoz-Arnanz, Juan; Jimenez, Begoña; Finoia, Maria Grazia

    2013-05-15

    The concurrence of man-made pressures on cetaceans in the Mediterranean Sea is potentially affecting population stability and marine biodiversity. This needs to be proven for the only pelagic marine protected area in the Mediterranean Sea: the Pelagos Sanctuary for Mediterranean Marine Mammals. Here we applied a multidisciplinary tool, using diagnostic markers elaborated in a statistical model to rank toxicological stress in Mediterranean cetaceans. As a case study we analyzed persistent, bioaccumulative and toxic chemicals combined with a wide range of diagnostic markers of exposure to anthropogenic contaminants and genetic variation as marker of genetic erosion in striped dolphin (Stenella coeruleoalba) skin biopsies. Finally, a statistical model was applied to obtain a complete toxicological profile of the striped dolphin in the Pelagos Sanctuary and other Mediterranean areas (Ionian Sea and Strait of Gibraltar). Here we provide the first complete evidence of the toxicological stress in cetaceans living in Pelagos Sanctuary. Copyright © 2013 Elsevier Ltd. All rights reserved.

  18. 24. MPA-seminar: safety and reliability of plant technology with special emphasis on integrity and life management. Vol. 1. Papers 1-27; 24. MPA-Seminar: Sicherheit und Verfuegbarkeit in der Anlagentechnik mit dem Schwerpunkt Integritaet und Lebensdauermanagement. Bd. 1. Vortraege 1-27

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-08-01

    The first volume is dedicated to the safety and reliability of plant technology with special emphasis on the integrity and life management. The main topic in the volume is the contribution of nondestructive testing to the reactor safety from an international point of view. All 20 papers are separately analyzed for this database. (orig.)

  19. 23. MPA-Seminar: Safety and reliability of plant technology with special emphasis on behaviour of pressurized components and systems at increased loading. Vol. 1. Papers 1-26; 23. MPA-Seminar: Sicherheit und Verfuegbarkeit in der Anlagentechnik mit dem Schwerpunkt Verhalten von druckfuehrenden Komponenten und Systemen bei erhoehten Belastungen. Bd. 1. Vortraege 1-26

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-11-01

    This book is dedicated to the components of nuclear and conventional power plants with special emphasis on the behaviour of pressurized components and systems. The following topics are discussed: 1. integrity of pipes, vessels, and components and 2. fracture mechanics

  20. 24. MPA-seminar: safety and reliability of plant technology with special emphasis on integrity and life management. Vol. 2. Papers 28-63; 24. MPA-Seminar: Sicherheit und Verfuegbarkeit in der Anlagentechnik mit dem Schwerpunk Integritaet und Lebensdauermanagement. Bd. 2. Vortraege 28-63

    Energy Technology Data Exchange (ETDEWEB)

    1999-09-01

    The second volume is dedicated to the safety and reliability of plant technology with special emphasis on the integrity and life management. The following topics are discussed: 1. Integrity of vessels, pipes and components. 2. Fracture mechanics. 3. Measures for the extension of service life, and 4. Online Monitoring. All 30 contributions are separately analyzed for this database. (orig.)

  1. 23. MPA-Seminar: Safety and reliability of plant technology with special emphasis on behaviour of pressurized components and systems at increased loading. Vol. 2. Papers 27-50; 23. MPA-Seminar: Sicherheit und Verfuegbarkeit in der Anlagentechnik mit dem Schwerpunkt Verhalten von druckfuehrenden Komponenten und Systemen bei erhoehten Belastungen. Bd. 2. Vortraege 27-50

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-11-01

    This book is dedicated to the components of nuclear and conventional power plants with special emphasis on the behaviour of pressurized components and systems. The following topics are discussed: 1. structure and safety analysis, 2. aging phenomena, 3. nondestructive testing, and 4. optimization of in-service inspection.

  2. Att tillämpa återkommande mätning av kundnöjdhet i IT-projekt : En vidareutvecklad modell baserad på modellerna American Customer Satisfaction Index (ACSI) och SERVQUAL

    OpenAIRE

    Karlmats, Roberg; Karlsson, Daniel

    2015-01-01

    I dagens samhälle är det allt viktigare för företag att behålla sina existerande kunder då konkurrensen blir allt hårdare. Detta medför att företag försöker vidta åtgärder för att vårda relationer med sina kunder. Detta problem är även högst relevant inom IT-branschen. Inom IT-branschen är det vanligt att arbeta agilt i IT-projekt. Vår samarbetspartner har sett ett ökat behov av att mäta servicekvalitet på ett återkommande sätt inom IT-projekt, detta för att mäta relevanta variabler som sträc...

  3. Surface tension and 0.1 MPa density data for 1-Cn-3-methylimidazolium iodides with n=3, 4, and 6, validated using a parachor and group contribution model

    Czech Academy of Sciences Publication Activity Database

    Součková, Monika; Klomfar, Jaroslav; Pátek, Jaroslav

    2015-01-01

    Roč. 83, April (2015), s. 52-60 ISSN 0021-9614 R&D Projects: GA ČR GA13-00145S; GA ČR GA101/09/0010 Institutional support: RVO:61388998 Keywords : density * surface tension * 1-alkyl-3-methylimidazolium iodide * group contribution method * parachor Subject RIV: BJ - Thermodynamics Impact factor: 2.196, year: 2015

  4. Temperature dependence of the surface tension and 0.1 MPa density for 1-Cn-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate with n=2, 4, and 6

    Czech Academy of Sciences Publication Activity Database

    Součková, Monika; Klomfar, Jaroslav; Pátek, Jaroslav

    2012-01-01

    Roč. 48, MAY 2012 (2012), s. 267-275 ISSN 0021-9614 R&D Projects: GA ČR GA101/09/0010 Institutional research plan: CEZ:AV0Z20760514 Keywords : ionic liquid s * tris(pentafluoroethyl)trifluorophosphate * surface tension * group contribution method * density Subject RIV: BJ - Thermodynamics Impact factor: 2.297, year: 2012 http://www.sciencedirect.com/science/article/pii/S0021961411004770

  5. Surface tension and 0.1 MPa density for members of homologous series of ionic liquids composed of imidazolium-, pyridinium-, and pyrrolidinium-based cations and of cyano-groups containing anions

    Czech Academy of Sciences Publication Activity Database

    Součková, Monika; Klomfar, Jaroslav; Pátek, Jaroslav

    2015-01-01

    Roč. 406, November (2015), s. 181-193 ISSN 0378-3812 R&D Projects: GA ČR GA13-00145S Institutional support: RVO:61388998 Keywords : ionic liquid * surface tension-temperature relation * density -temperature relation * cyano-funcionalized anion Subject RIV: BJ - Thermodynamics Impact factor: 1.846, year: 2015

  6. (P, V, T, x) Measurements of the System Benzene + 1,3,5-Trimethylbenzene at Temperatures from 298.15 to 328.15 K and at Pressures up to 40 MPa

    Czech Academy of Sciences Publication Activity Database

    Morávková, Lenka; Wagner, Zdeněk; Linek, Jan

    2003-01-01

    Roč. 209, č. 1 (2003), s. 81-94 ISSN 0378-3812 R&D Projects: GA ČR GA203/02/1098 Institutional research plan: CEZ:AV0Z4072921 Keywords : benzene * Redlich-Kister equation * 1,3,5-trimethylbenzene Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.165, year: 2003

  7. Densities and volume properties of (water + tert-butanol) over the temperature range of (274.15 to 348.15) K at pressure of 0.1 MPa

    International Nuclear Information System (INIS)

    Egorov, Gennadiy I.; Makarov, Dmitriy M.

    2011-01-01

    The densities of {water (1) + tert-butanol (2)} binary mixture were measured over the temperature range (274.15 to 348.15) K at atmospheric pressure using 'Anton Paar' digital vibrating-tube densimeter. Density measurements were carried out over the whole concentration range at (308.15 to 348.15) K. The following volume parameters were calculated: excess molar volumes and thermal isobaric expansivities of the mixture, partial molar volumes and partial molar thermal isobaric expansivities of the components. Concentration dependences of excess molar volumes were fitted with Redlich-Kister equation. The results of partial molar volume calculations using four equations were compared. It was established that for low alcohol concentrations at T ≤ 208 K the inflection points at x 2 ∼ 0.02 were observed at concentration dependences of specific volume. The concentration dependences of partial molar volumes of both water and tert-butanol had extremes at low alcohol content. The temperature dependence of partial molar volumes of water had some inversion at x 2 ∼ 0.65. The temperature dependence of partial molar volumes of tert-butanol at infinite dilution had minimum at ∼288 K. It was discovered that concentration dependences of thermal isobaric expansivities of the mixture at small alcohol content and low temperatures passed through minimum.

  8. Multibeam collection for NF-08-01-MPA: Multibeam data collected aboard Nancy Foster from 2007-10-09 to 2007-10-21, Unknown Port to Unknown Port

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This data set is part of a larger set of data called the Multibeam Bathymetry Database (MBBDB) where other similar data can be found at...

  9. Low Temperature Densities from (218 to 364) K and up to 50 MPa in Pressure and Surface Tension for Trihexyl(tetradecyl)phosphonium Bis(trifluoromethylsulfonyl)imide and Dicyanamide and 1-Hexyl-3-methylimidazolium Hexafluorophosphate

    Czech Academy of Sciences Publication Activity Database

    Klomfar, Jaroslav; Součková, Monika; Pátek, Jaroslav

    2014-01-01

    Roč. 59, July (2014), s. 2263-2274 ISSN 0021-9568 R&D Projects: GA ČR GA13-00145S; GA ČR GA101/09/0010 Institutional support: RVO:61388998 Keywords : trihexyl(tetradecyl)phosphonium cation * 1-hexyl-3-methylimidazolium hexafluorophosphate * bis(trifluoromethylsulfonyl)imide anion * dicyanamide anion * experimental pvT data * surface tension * internal pressure Subject RIV: BJ - Thermodynamics Impact factor: 2.037, year: 2014

  10. Multibeam Collection for Multibeam Mapping of the South Atlantic Bight: Georgia 2005, a Proposed MPA on the Continential Shelf on the R/V Cape Fear in the North Atlantic Ocean between June 13, 2005 and July 7, 2005

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Library Catalog may include: Data Management Plans, Cruise Plans, Cruise Summary Reports, Scientific "Quick Look Reports", Video Annotation Logs, Image Collections,...

  11. Isochoric p-rho-T Measurements for trans-1,3,3,3-Tetrafluoropropene [R-1234ze(E)] and Trifluoroiodomethane (R13I1) at Temperatures from (205 to 353) K under Pressures up to 40 MPa

    Czech Academy of Sciences Publication Activity Database

    Klomfar, Jaroslav; Součková, Monika; Pátek, Jaroslav

    2012-01-01

    Roč. 57, č. 11 (2012), s. 3270-3277 ISSN 0021-9568 R&D Projects: GA ČR GA101/09/0010 Institutional research plan: CEZ:AV0Z20760514 Keywords : trans-1,3,3,3-tetrafluoropropene * trifluoroiodomethane * pvT Subject RIV: BJ - Thermodynamics Impact factor: 2.004, year: 2012 http://pubs.acs.org/doi/abs/10.1021/je3008974

  12. 23. MPA-Seminar: Safety and reliability of plant technology with special emphasis on behaviour of pressurized components and systems at increased loading. Vol. 2. Papers 27-50

    International Nuclear Information System (INIS)

    1998-01-01

    This book is dedicated to the components of nuclear and conventional power plants with special emphasis on the behaviour of pressurized components and systems. The following topics are discussed: 1. structure and safety analysis, 2. aging phenomena, 3. nondestructive testing, and 4. optimization of in-service inspection

  13. 23. MPA-Seminar: Safety and reliability of plant technology with special emphasis on behaviour of pressurized components and systems at increased loading. Vol. 1. Papers 1-26

    International Nuclear Information System (INIS)

    1998-01-01

    This book is dedicated to the components of nuclear and conventional power plants with special emphasis on the behaviour of pressurized components and systems. The following topics are discussed: 1. integrity of pipes, vessels, and components and 2. fracture mechanics

  14. Multibeam collection for NF-07-02-MPA: Multibeam data collected aboard Nancy Foster from 2006-10-25 to 2006-11-07, Morehead City, NC to Charleston, SC

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This data set is part of a larger set of data called the Multibeam Bathymetry Database (MBBDB) where other similar data can be found at...

  15. Significance of uniaxial and hydrostatic pressure studies on ancient oceanic rocks in tectonics

    Digital Repository Service at National Institute of Oceanography (India)

    Sarma, K.V.L.N.S.; Ramana, Y.V.

    showed the lowest value of compressive strength (45 MPa) and pyroxenite gave the highest value (269 MPa), while meta volcanics exhibited narrow limits of 58 to 245 MPa. Standard correlations were obtained for compressive strength to G/P ratio...

  16. Kinetics of Chemical Agents Destruction in Supercritical Water

    National Research Council Canada - National Science Library

    Tester, Jefferson

    2003-01-01

    .... An experimental study of methylphosphonic acid (MPA) oxidation has been completed that includes macroscopic modeling of the overall global rate law for MPA oxidation in supercritical water (SCW...

  17. Analysis of Lightweight Materials for the AM2 System

    Science.gov (United States)

    2014-06-01

    regarding the yield (400 MPa to 600 MPa) and tensile ( 590 MPa to 750 MPa) with almost identical ductility characteristics (0.345 mm/mm to fracture with the...D. Piatkowski, E. Lee, P. Stoyanov, Ramakrishna Naidu, N. K., and Ganesh Sudara Raman , S. 2005. Effect of shot blasting on plain fatigue and

  18. Physical activity helps to control music performance anxiety.

    Science.gov (United States)

    Rocha, Sérgio F; Marocolo, Moacir; Corrêa, Elisangela N V; Morato, Gledys S G; da Mota, Gustavo R

    2014-06-01

    We evaluated if regular physical activity could influence musical performance anxiety (MPA) in college music students. Levels of MPA, as measured with the Kenny MPA Inventory, and a survey about the physical activity habits were obtained from 87 students of music. The results showed that physically active musicians had lower MPA scores (pindependent of gender. We conclude that there is an association between physical activity and minor MPA, and studies with a longitudinal design should be done to explore this important issue.

  19. A new class of IMP dehydrogenase with a role in self-resistance of mycophenolic acid producing fungi

    Directory of Open Access Journals (Sweden)

    Mortensen Uffe H

    2011-09-01

    Full Text Available Abstract Background Many secondary metabolites produced by filamentous fungi have potent biological activities, to which the producer organism must be resistant. An example of pharmaceutical interest is mycophenolic acid (MPA, an immunosuppressant molecule produced by several Penicillium species. The target of MPA is inosine-5'-monophosphate dehydrogenase (IMPDH, which catalyses the rate limiting step in the synthesis of guanine nucleotides. The recent discovery of the MPA biosynthetic gene cluster from Penicillium brevicompactum revealed an extra copy of the IMPDH-encoding gene (mpaF embedded within the cluster. This finding suggests that the key component of MPA self resistance is likely based on the IMPDH encoded by mpaF. Results In accordance with our hypothesis, heterologous expression of mpaF dramatically increased MPA resistance in a model fungus, Aspergillus nidulans, which does not produce MPA. The growth of an A. nidulans strain expressing mpaF was only marginally affected by MPA at concentrations as high as 200 μg/ml. To further substantiate the role of mpaF in MPA resistance, we searched for mpaF orthologs in six MPA producer/non-producer strains from Penicillium subgenus Penicillium. All six strains were found to hold two copies of IMPDH. A cladistic analysis based on the corresponding cDNA sequences revealed a novel group constituting mpaF homologs. Interestingly, a conserved tyrosine residue in the original class of IMPDHs is replaced by a phenylalanine residue in the new IMPDH class. Conclusions We identified a novel variant of the IMPDH-encoding gene in six different strains from Penicillium subgenus Penicillium. The novel IMPDH variant from MPA producer P. brevicompactum was shown to confer a high degree of MPA resistance when expressed in a non-producer fungus. Our study provides a basis for understanding the molecular mechanism of MPA resistance and has relevance for biotechnological and pharmaceutical applications.

  20. Evaluation of the corrosion resistance of AISI 316 stainless steel filters

    Directory of Open Access Journals (Sweden)

    Luzinete Pereira Barbosa

    2005-06-01

    Full Text Available In this investigation, the corrosion resistance of AISI 316 SS filters prepared with powders in the size ranges 74-44 µm and 210-105 µm and compacted with pressures of 300 MPa and 400 MPa has been evaluated in naturally aerated 0.5 M H2SO4 solution at 25 °C. Weight loss of filters manufactured with compacting pressure of 400 MPa were significantly higher than that of filters compacted at 300 MPa. The filter compacted at 400 MPa had higher carbon and nitrogen contents compared to those compacted at 300 MPa. The former also had chromium rich precipitates and oxides in the grain boundaries. The pores in filters compacted at 400 MPa were smaller than in filters compacted at 300 MPa. Smaller pores favor the formation of concentration cells and consequently, increased crevice corrosion.

  1. Stress analysis in a functionally graded disc under mechanical loads ...

    Indian Academy of Sciences (India)

    They have therefore attracted considerable attention in recent ... vessels subjected to internal pressure by using the small deformation theory. ..... sure (Pi = 50 MPa), external pressure (Po = 100 MPa), centrifugal load with a constant angular.

  2. Heat Treatment Effects on Microstructure of SiC Fiber Preforms

    National Research Council Canada - National Science Library

    Bhatt, Ramakrishna T

    1999-01-01

    ... in 0.1 MPa argon or at 1800 deg C in 103 MPa nitrogen for 1 h. Optical, SEM, and TEM techniques were used to analyze the effects of environmental exposure on constituent microstructure of the preforms...

  3. Ply Tensile Properties of Banana Stem and Banana Bunch Fibres ...

    African Journals Online (AJOL)

    Natural rubber composite lamina reinforced with BSF which were treated with a mixture of NaOH and Na2SO3 had a superior tensile strength of 4.0 MPa and Young's modulus of 147.34MPa over the untreated BSF with tensile strength and Young's Modulus of 3.7MPa and 84.30MPa respectively. Both the treated and ...

  4. Assessment of mechanical and three-body abrasive wear peculiarity ...

    Indian Academy of Sciences (India)

    Properties of bi-directional E-glass fibre. Density (g cm. −3. ) 2.55–2.6. Bulk modulus (GPa). 43–50. Elastic modulus (MPa). 2750–2875. Hardness (MPa). 3000–6000. Shear modulus (GPa). 30–36. Tensile strength (MPa). 1950–2050. Young's modulus (GPa). 72–85. Endurance limit (MPa). 2970–3110. Thermal expansion ( ...

  5. Effect of alkali treated jute fibres on composite properties

    Indian Academy of Sciences (India)

    Vinylester resin; jute fibre composite; alkali; mechanical properties; fracture; fibre pull out. ... For the 35% composites with 4 h treated fibres, the flexural strength improved from 199.1 MPa to 238.9 MPa by 20%, modulus improved from 11.89 GPa to 14.69 GPa by 23% and laminar shear strength increased from 0.238 MPa to ...

  6. Recovery of tobacco BY-2 cells after high hydrostatic pressure treatment.

    Science.gov (United States)

    Kusube, Masataka; Nishino, Takumi; Nishikawa, Yuki; Goto, Masaki; Matsuki, Hitoshi; Iwahashi, Hitoshi

    2010-02-01

    The recovery of Nicotiana tabacum L. cv. Bright Yellow 2 (BY-2) cells in Linsmaire and Skoog medium after treatment at high hydrostatic pressure was investigated using an Evans Blue staining method to discriminate live from dead cells. The survival of BY-2 cells just after the high-pressure treatment at 5 degrees C and 25 degrees C decreased abruptly at pressures higher than 50 MPa and 100 MPa, respectively. Furthermore, almost all of the BY-2 cells treated at 5 degrees C and 25 degrees C recovered pressures below 25 MPa and 75 MPa, respectively. However, no BY-2 cells recovered at pressures above 100 MPa at either temperature.

  7. Adaptive evolution of drug targets in producer and non-producer organisms

    DEFF Research Database (Denmark)

    Hansen, Bjarne Gram; Sun, Xin E.; Genee, Hans Jasper

    2012-01-01

    MPA (mycophenolic acid) is an immunosuppressive drug produced by several fungi in Penicillium subgenus Penicillium. This toxic metabolite is an inhibitor of IMPDH (IMP dehydrogenase). The MPA-biosynthetic cluster of Penicillum brevicompactum contains a gene encoding a B-type IMPDH, IMPDH-B, which...... confers MPA resistance. Surprisingly, all members of the subgenus Penicillium contain genes encoding IMPDHs of both the A and B types, regardless of their ability to produce MPA. Duplication of the IMPDH gene occurred before and independently of the acquisition of the MPAbiosynthetic cluster. Both P....... brevicompactum IMPDHs are MPA-resistant, whereas the IMPDHs from a non-producer are MPA-sensitive. Resistance comes with a catalytic cost: whereas P. brevicompactum IMPDH-B is >1000-fold more resistant to MPA than a typical eukaryotic IMPDH, its value of kcat/Km is 0.5%of ‘normal’. Curiously, IMPDH...

  8. Music performance anxiety in young musicians: comparison of playing classical or popular music.

    Science.gov (United States)

    Nusseck, Manfred; Zander, Mark; Spahn, Claudia

    2015-03-01

    Music performance anxiety (MPA) is an issue frequently experienced by musicians. It occurs not only in experienced musicians but also in children and adolescents. Furthermore, most research on MPA has been done with musicians who specialized in classical music. This study investigated the development of MPA across the ages in young musicians focusing on the classical and popular genres. In a cross-sectional survey, 239 students at German music schools, aged between 7 and 20 yrs, were asked about their perceived MPA and musical background. The data were analyzed according to musical genre and age. Multiple regression analyses were performed to investigate the influences of musical experiences on MPA. The analyses yielded high levels of MPA for classical musicians between 7 and 16 yrs, which was reduced in older students; for popular musicians, low MPA was seen in the younger (7-11 yrs) and high MPA in the older (16+ yrs) musicians. MPA was influenced by gender and the number of performances in the classical music group and only by gender and age in the popular music group. The results showed clear different trends for the development of MPA between musical genres that should be taken into account for educational aspects in musical training.

  9. Risk evaluation and mitigation strategies: a focus on the mycophenolic acid preparations.

    Science.gov (United States)

    Rostas, Sara; Kim, Miae; Gabardi, Steven

    2014-03-01

    To review risks associated with mycophenolic acid (MPA) preparations and evaluate their required risk evaluation and mitigation strategies (REMS) elements. Articles were identified through a non-date-limited MEDLINE and EMBASE search using the terms fetal toxicity, teratogenicity, risk evaluation and mitigation strategies, REMS, MPA, mycophenolate mofetil, entericcoated MPA, and organ transplant. Information from the Food and Drug Administration (FDA) and the manufacturers of the MPA preparations was also evaluated. The MPA preparations are associated with several potential risks, including gastrointestinal disturbances and myelosuppression; however, their impact on the fetus in pregnant patients taking 1 of these agents poses the greatest risk. The FDA approved REMS programs for all MPA products, both innovator and generic preparations, in September 2012. With evidence of increased risk of miscarriage and birth defects associated with MPA use, the FDA instituted a REMS program that contains both a medication guide and elements to assure safe use (ETASU). The medication guides for the MPA products, which were previously FDA approved, should continue to be distributed to patients who get either an initial prescription filled or a refill. The ETASU requires prescribers to complete training and obtain patient signatures on the Patient-Prescriber Acknowledgment Form. A single, national, voluntary pregnancy registry specific to this medication has been established, and pregnant patients should be encouraged to participate. Although the impact of the MPA REMS on clinical practice is not clear, it is a step toward increasing the understanding of fetal risks with MPA.

  10. Estimation of pulmonary artery pressure in patients with primary pulmonary hypertension by quantitative analysis of magnetic resonance images.

    Science.gov (United States)

    Murray, T I; Boxt, L M; Katz, J; Reagan, K; Barst, R J

    1994-01-01

    The use of magnetic resonance (MR) images for estimating mean pulmonary artery pressure (PAP) was tested by comparing main pulmonary artery (MPA) and middescending thoracic aorta (AO) caliber in 12 patients with primary pulmonary hypertension (PPH) with measurements made in eight other patients who were observed for diseases other than heart disease (controls). The ratio MPA/AO and the ratios of vessel caliber normalized to body surface area (MPAI and AOI, respectively) were computed. The PAP was obtained in all PPH patients and compared with caliber measurements. The PPH MPA (3.6 +/- 0.8 cm) was significantly larger than the control MPA (2.9 +/- 0.3 cm, p = 0.02); the PPH MPAI (2.8 +/- 0.7 cm/M2) was significantly greater than the control MPA (1.7 +/- 0.2 cm/M2, p < 0.0001). Control AO (2.2 +/- 0.3 cm) was significantly greater than PPH AO (1.6 +/- 0.4 cm, p < 0.0001); there was no significant difference between control AOI (1.3 +/- 0.2 cm/M2) and PPH AOI (1.2 +/- 0.2 cm/M2, p = 0.25). The PPH MPA/AO (2.3 +/- 0.6) was significantly greater than the control MPA/AO (1.3 +/- 0.1, p < 0.0001); overlap between MPA in the two groups was eliminated by indexing values to AO caliber (MPA/AO). Among PPH patients there was strong correlation between PAP and MPA/AO (PAP = 24 x MPA/AO + 3.7, r = 0.7, p < 0.01). Increased MPA/AO denotes the presence of pulmonary hypertension and may be used to estimate PAP.

  11. Study of High Temperature Failure Mechanism in Ceramics

    Science.gov (United States)

    1992-01-01

    characteristics of the glass-ceramic are presented in Figure 9 for K = 0.95 MPaI -at 750"C and in Figure 10 forK = 0.59 MPa’mat 775"C. Results I presented in these...at K = 0.59 MPai1- and Figure 12(b) showing the removal of those cavities by sintering at K = 0.5 MPaI -. The near-tip region where creep cavities

  12. Hydrolýza brambor

    OpenAIRE

    KAMENOVÁ, Andrea

    2010-01-01

    This work compares acid, alkaline and enzymatic hydrolysis of potato starch with simultaneous application of various pressures (0MPa, 0,3MPa and 1MPa). Acid hydrolysis was made by sulphuric acid of intensity 3, 6, 9 and 12 %, alkaline hydrolysis was made by sodium hydroxide of intensity 3, 6, 9 and 12 % and four enzymatic preparations for starch hydrolysis were used for enzymatic hydrolysis. Hydrolysis effect was measured via GE and added by alcohol yield. There was positive influence of incr...

  13. Freeing the performer’s mind: A structural exploration of how mindfulness influences music performance anxiety, negative affect and self-consciousness among musicians

    OpenAIRE

    Rodríguez-Carvajal, Raquel; Vilte, Luz-Sofía; Lecuona, Oscar; Moreno-Jiménez, Jennifer; De Rivas, Sara

    2017-01-01

    Music performing usually binds intense psychological experiences, from which music performance anxiety (MPA) is amongst the most damaging and pervasive ones. Alongside, some constructs seem to be associated with MPA, like negative affect and self-consciousness. In the interaction between these three elements, mindfulness seems to be an effective tool to cope with MPA by altering the relationships between it and self-consciousness or negative affect. In this study, a structural model is propos...

  14. Design and Fabrication of 3D printed Scaffolds with a Mechanical Strength Comparable to Cortical Bone to Repair Large Bone Defects

    OpenAIRE

    Roohani-Esfahani, Seyed-Iman; Newman, Peter; Zreiqat, Hala

    2016-01-01

    A challenge in regenerating large bone defects under load is to create scaffolds with large and interconnected pores while providing a compressive strength comparable to cortical bone (100?150?MPa). Here we design a novel hexagonal architecture for a glass-ceramic scaffold to fabricate an anisotropic, highly porous three dimensional scaffolds with a compressive strength of 110?MPa. Scaffolds with hexagonal design demonstrated a high fatigue resistance (1,000,000 cycles at 1?10?MPa compressive...

  15. Evaluation of bacterial growth inhibition by mercaptopropionic acid in metallo-β-lactamase detection on multidrug-resistant Acinetobacter baumannii

    Directory of Open Access Journals (Sweden)

    Letícia Eichstaedt Mayer

    2012-04-01

    Full Text Available INTRODUCTION: Metallo-β-lactamase (MBL has been reported all over the world. METHODS: The inhibitory effect of mercaptopropionic acid (MPA on bacterial growth was evaluated by comparison between disk diffusion and broth dilution methodology with determination of the minimum inhibitory concentration (MIC for multidrug-resistant Acinetobacter baumanni strains. RESULTS: MPA significantly inhibited growth of the strains. CONCLUSIONS: The use of MPA can affect the results in phenotypic methods of MBL detection.

  16. Evaluation of bacterial growth inhibition by mercaptopropionic acid in metallo-β-lactamase detection on multidrug-resistant Acinetobacter baumannii.

    Science.gov (United States)

    Mayer, Letícia Eichstaedt; Hörner, Rosmari; Tizotti, Maisa Kräulich; Martini, Rosiéli; Roehrs, Magda Cristina Souza Marques; Kempfer, Cláudia Barbisan

    2012-01-01

    Metallo-β-lactamase (MBL) has been reported all over the world. The inhibitory effect of mercaptopropionic acid (MPA) on bacterial growth was evaluated by comparison between disk diffusion and broth dilution methodology with determination of the minimum inhibitory concentration (MIC) for multidrug-resistant Acinetobacter baumanni strains. MPA significantly inhibited growth of the strains. The use of MPA can affect the results in phenotypic methods of MBL detection.

  17. Influence of hydrostatic pressure on nuclear radiation detector's properties based on semiconductor alloy CdZnTe

    International Nuclear Information System (INIS)

    Kutnij, V.E.; Kutnij, D.V.; Rybka, A.V.; Nakonechnyj, D.V.; Babun, A.V.

    2003-01-01

    The influence of hydrostatic pressure on properties of CdZnTe semiconductor detectors (Cd-50,Zn-2,Te-48 mas.%, 5 centre dot 5 centre dot 2 mm) was investigated. Were considered different types of hydrostatic treatment at 100 MPa, second hydrostatic treatment at 100 MPa and 200 MPa. Hydrostatic pressure influence on detectors electric resistance, J-V characteristics and spectrometric parameters was determined

  18. Mycophenolic acid inhibits migration and invasion of gastric cancer cells via multiple molecular pathways.

    Directory of Open Access Journals (Sweden)

    Boying Dun

    Full Text Available Mycophenolic acid (MPA is the metabolized product and active element of mycophenolate mofetil (MMF that has been widely used for the prevention of acute graft rejection. MPA potently inhibits inosine monophosphate dehydrogenase (IMPDH that is up-regulated in many tumors and MPA is known to inhibit cancer cell proliferation as well as fibroblast and endothelial cell migration. In this study, we demonstrated for the first time MPA's antimigratory and anti-invasion abilities of MPA-sensitive AGS (gastric cancer cells. Genome-wide expression analyses using Illumina whole genome microarrays identified 50 genes with ≥2 fold changes and 15 genes with > 4 fold alterations and multiple molecular pathways implicated in cell migration. Real-time RT-PCR analyses of selected genes also confirmed the expression differences. Furthermore, targeted proteomic analyses identified several proteins altered by MPA treatment. Our results indicate that MPA modulates gastric cancer cell migration through down-regulation of a large number of genes (PRKCA, DOCK1, INF2, HSPA5, LRP8 and PDGFRA and proteins (PRKCA, AKT, SRC, CD147 and MMP1 with promigratory functions as well as up-regulation of a number of genes with antimigratory functions (ATF3, SMAD3, CITED2 and CEAMCAM1. However, a few genes that may promote migration (CYR61 and NOS3 were up-regulated. Therefore, MPA's overall antimigratory role on cancer cells reflects a balance between promigratory and antimigratory signals influenced by MPA treatment.

  19. Managing Drug-Drug Interaction Between Ombitasvir, Paritaprevir/Ritonavir, Dasabuvir, and Mycophenolate Mofetil.

    Science.gov (United States)

    Lemaitre, Florian; Ben Ali, Zeineb; Tron, Camille; Jezequel, Caroline; Boglione-Kerrien, Christelle; Verdier, Marie-Clémence; Guyader, Dominique; Bellissant, Eric

    2017-08-01

    No drug-drug interaction study has been conducted to date for the combination of ombitasvir, paritaprevir/ritonavir, dasabuvir (3D), and mycophenolic acid (MPA). We here report the case of a hepatitis C virus-infected patient treated with 3D and MPA for vasculitis. In light of the threat of drug-drug interaction, the concentration of MPA was measured before, during, and 15 days after the end of the 3D treatment. Similar values were found at all 3 time points, thus indicating that there is probably no need to adapt MPA dosage to 3D.

  20. Kitarritab'idest / Laur Kanger

    Index Scriptorium Estoniae

    Kanger, Laur

    2006-01-01

    Muusikakirjastajate Assotsiatsiooni (MPA - Music Publisher's Association of United States) sõjast kitarritabulatuure (klassikalise noodikirja märkimise lihtsustatud viis) pakkuvate veebisaitide vastu

  1. Effects of High Hydrostatic Pressure on the Physical, Microbial, and Chemical Attributes of Oysters (Crassostrea virginica).

    Science.gov (United States)

    Lingham, Talaysha; Ye, Mu; Chen, Haiqiang; Chintapenta, Lathadevi Karuna; Handy, Eunice; Zhao, Jing; Wu, Changqing; Ozbay, Gulnihal

    2016-05-01

    The change in the quality attributes (physical, microbial, and chemical) of oysters (Crassostrea virginica) after high hydrostatic pressure (HHP) treatment at 300 MPa at room temperature (RT, 25 °C) 300, 450, and 500 MPa at 0 °C for 2 min and control oysters without treatment were evaluated over 3 wk. The texture and tissue yield percentages of oysters HHP treated at 300 MPa, RT increased significantly (P oysters reached the spoilage point of 7 log CFU/g after 15 d. Coliform counts (log MPN/g) were low during storage with total and fecal coliforms less than 3.5 and 1.0. High pressure treated oysters at 500 MPa at 0 °C were significantly higher (P oysters HHP treated at 300 MPa at 0 °C in lipid oxidation values. The highest pressure (500 MPa) treatment in this study, significantly (P oysters at 3 wk was significantly higher (P oysters [300 MPa, (RT); 450 MPa (0 °C); and 500 MPa (0 °C)]. HHP treatments of oysters were not significantly different in pH, percent salt extractable protein (SEP), and total lipid values compared to control. Based on our results, HHP prolongs the physical, microbial, and chemical quality of oysters. © 2016 Institute of Food Technologists®

  2. Mycophenolic acid suppresses human pterygium and normal tenon fibroblast proliferation in vitro.

    Science.gov (United States)

    Amer, Radgonde; Rabinowich, Liane; Maftsir, Genia; Puxeddu, Ilaria; Levi-Schaffer, Francesca; Solomon, Abraham

    2010-10-01

    To investigate whether mycophenolic acid (MPA) exerts antifibrotic effects on pterygium fibroblasts (PFB) with and without stimulation with fibrogenic cytokines, and to compare the efficacy of MPA with mitomycin (MMC) and dexamethasone (DXM) on PFB and tenon fibroblasts (TFB). TFB and PFB were obtained from tissue explants during strabismus or pterygium surgery. Proliferation of subconfluent fibroblasts ± basic fibroblast growth factor (bFGF) (10 ng/ml) was assessed by using the (3H) thymidine-incorporation assay. Cell cultures were incubated with MPA, MMC or DXM. Apoptosis was evaluated by quantifying Annexin V and propidium iodide positive cells with flow cytometry. MPA showed a concentration-dependent inhibition of proliferation of PFB ± bFGF as well as TFB ± bFGF. The antiproliferative effect of MPA was comparable with that of MMC and DXM. Short exposure of PFB to MPA under profibrogenic conditions was significantly inhibitory. No apoptotic effect was found on TFB. MPA suppressed tenon and pterygium fibroblast proliferation in vitro under basal and profibrogenic conditions. It was comparable with MMC under long-term exposure, but MMC was more suppressive under short-term exposure. MPA may be safer than MMC due to a more specific mechanism of action and lack of cytotoxicity. Further investigation is warranted regarding MPA concentrations that will lead to a potent antiproliferative effect in vivo.

  3. Effect of confining pressure on permeability behavior of Beishan granite

    International Nuclear Information System (INIS)

    Ma Like; Li Yunfeng; Zhao Xingguang; Tan Guohuan

    2012-01-01

    By using of the Electro-Hydraulic Servo-controlled Rock Mechanics Testing System (MTS 815.04) in the University of Hong Kong, a series of permeability tests were performed on specimens of Beishan granite at different confining pressures. The result indicates that: (1) there is a decrease of permeability due to progressive closure of initial microcracks and the corresponding volumetric strain is compressive when the confining pressures increase from 2.5 MPa to 15 MPa, (2) when the confining pressures decrease from 15 MPa to 2.5 MPa, there is an increase of permeability in this stage in relation with the volumetric dilation. (authors)

  4. Do cytostatic drugs reach drinking water? The case of mycophenolic acid

    International Nuclear Information System (INIS)

    Franquet-Griell, Helena; Ventura, Francesc; Boleda, M.Rosa; Lacorte, Silvia

    2016-01-01

    Mycophenolic acid (MPA) has been identified as a new river contaminant according to its wide use and high predicted concentration. The aim of this study was to monitor the impact of MPA in a drinking water treatment plant (DWTP) that collects water downstream Llobregat River (NE Spain) in a highly densified urban area. During a one week survey MPA was recurrently detected in the DWTP intake (17–56.2 ng L"−"1). The presence of this compound in river water was associated to its widespread consumption (>2 tons in 2012 in Catalonia), high excretion rates and low degradability. The fate of MPA in waters at each treatment step of the DWTP was analyzed and complete removal was observed after pretreatment with chlorine dioxide. So far, MPA has not been described as water contaminant and its presence associated with its consumption in anticancer treatments is of relevance to highlight the importance of monitoring this compound. - Highlights: • MPA, a cytostatic drug, has been identified as a new river water contaminant. • MPA is eliminated during dioxychlorination in a drinking water treatment plant. • No residues of MPA were detected in finished drinking water. • Isotope dilution LC-MS/MS permitted the trace quantification of MPA in water. - Mycophenolic acid, a cytostatic drug, has been identified as a new river water contaminant and it is removed during purification in a Drinking Water Treatment Plant.

  5. A Comparison of Degradable Synthetic Polymer Fibers for Anterior Cruciate Ligament Reconstruction

    OpenAIRE

    Tovar, Nick; Bourke, Sharon; Jaffe, Michael; Murthy, N. Sanjeeva; Kohn, Joachim; Gatt, Charles; Dunn, Michael G.

    2010-01-01

    We compared mechanical properties, degradation rates, and cellular compatibilities of two synthetic polymer fibers potentially useful as ACL reconstruction scaffolds: poly(desaminotyrosyl-tyrosine dodecyl dodecanedioate)(12,10), p(DTD DD) and poly(L-lactic acid), PLLA. The yield stress of ethylene oxide (ETO) sterilized wet fibers was 150 ± 22 MPa and 87 ± 12 MPa for p(DTD DD) and PLLA, respectively, with moduli of 1.7 ± 0.1 MPa and 4.4 ± 0.43 MPa. Strength and molecular weight retention were...

  6. Kinetically Controlled Drug Resistance

    DEFF Research Database (Denmark)

    Sun, Xin E.; Hansen, Bjarne Gram; Hedstrom, Lizbeth

    2011-01-01

    The filamentous fungus Penicillium brevicompactum produces the immunosuppressive drug mycophenolic acid (MPA), which is a potent inhibitor of eukaryotic IMP dehydrogenases (IMPDHs). IMPDH catalyzes the conversion of IMP to XMP via a covalent enzyme intermediate, E-XMP*; MPA inhibits by trapping E...... of resistance is not apparent. Here, we show that, unlike MPA-sensitive IMPDHs, formation of E-XMP* is rate-limiting for both PbIMPDH-A and PbIMPDH-B. Therefore, MPA resistance derives from the failure to accumulate the drug-sensitive intermediate....

  7. Effect of high pressure on mesophilic lactic fermentation streptococci

    Energy Technology Data Exchange (ETDEWEB)

    Reps, A; Kuzmicka, M; Wisniewska, K [Chair of Food Biotechnology, University of Warmia and Mazury, ul. Heweliusza 1, 10-724 Olsztyn (Poland)], E-mail: arnold.reps@uwm.edu.pl

    2008-07-15

    The research concerned the effect of high pressure on mesophilic lactic fermentation streptococci, present in two cheese-making commercial inocula produced by Christian-Hansen. Water solutions of inocula were pressurized at 50-800 MPa, at room temperature, for 30-120 min. Pressurization at 50-100 MPa slightly increased or reduced the number of lactic streptococci, depending on the inoculum and pressurization time. Pressurization at 200 MPa caused a reduction in the number of streptococci by over 99.9%, whereas the pressure of 400 MPa and above almost completely inactivated streptococci. Pressurization also reduced the dynamics of microorganism growth and acidification, to the degree depending on the pressure.

  8. Performance Characterization and Auto-Ignition Performance of a Rapid Compression Machine

    OpenAIRE

    Hao Liu; Hongguang Zhang; Zhicheng Shi; Haitao Lu; Guangyao Zhao; Baofeng Yao

    2014-01-01

    A rapid compression machine (RCM) test bench is developed in this study. The performance characterization and auto-ignition performance tests are conducted at an initial temperature of 293 K, a compression ratio of 9.5 to 16.5, a compressed temperature of 650 K to 850 K, a driving gas pressure range of 0.25 MPa to 0.7 MPa, an initial pressure of 0.04 MPa to 0.09 MPa, and a nitrogen dilution ratio of 35% to 65%. A new type of hydraulic piston is used to address the problem in which the hydraul...

  9. High hydrostatic pressure inactivation of total aerobic bacteria, lactic acid bacteria, yeasts in sour Chinese cabbage.

    Science.gov (United States)

    Li, Lin; Feng, Lun; Yi, Junjie; Hua, Cheng; Chen, Fang; Liao, Xiaojun; Wang, Zhengfu; Hu, Xiaosong

    2010-08-15

    This study investigated the inactivation of total aerobic bacteria (TAB), lactic acid bacteria (LAB), yeasts in sour Chinese cabbage (SCC) treated by high hydrostatic pressure (HHP). The pressure level ranged from 200 to 600 MPa and the treatment time were 10-30 min. All samples were stored at 4, 27 and 37 degrees C for 90 days. The pressure level of 200 MPa had no significant impact on these microorganisms. The counts of TAB were significantly reduced by 2.7-4.0 log(10)CFU/g at 400 MPa and 4.2-4.5 log(10)CFU/g at 600 MPa from 6.2 log(10)CFU/g; the counts of LAB were also reduced by 2.4-4.3 log(10)CFU/g at 400 MPa from 7.0 log(10)CFU/g and LAB was completely inactivated at 600 MPa; the counts of yeasts were reduced by 1.5-2.0 log(10)CFU/g at 400 and 600 MPa from 4.2 log(10)CFU/g. Storage temperatures significantly influenced the microbial proliferation in HHP-treated SCC depending on the pressure levels. The surviving TAB and LAB at 400 MPa equaled initial counts after 15-day storage at 27 and 37 degrees C, whereas they were inhibited at 4 degrees C up to 60 days. The surviving TAB at 600 MPa did not grow. Yeasts at 400 and 600 MPa decreased below detectable level after 2 days at all the three storage temperatures. From the microbial safety point of view, the result indicated that HHP at 600 MPa could be used as an alternative preservation method for SCC. Copyright 2010 Elsevier B.V. All rights reserved.

  10. GTP depletion synergizes the anti-proliferative activity of chemotherapeutic agents in a cell type-dependent manner

    International Nuclear Information System (INIS)

    Lin, Tao; Meng, Lingjun; Tsai, Robert Y.L.

    2011-01-01

    Highlights: → Strong synergy between mycophenolic acid (MPA) and 5-FU in MDA-MB-231 cells. → Cell type-dependent synergy between MPA and anti-proliferative agents. → The synergy of MPA on 5-FU is recapitulated by RNA polymerase-I inhibition. → The synergy of MPA on 5-FU requires the expression of nucleostemin. -- Abstract: Mycophenolic acid (MPA) depletes intracellular GTP by blocking de novo guanine nucleotide synthesis. GTP is used ubiquitously for DNA/RNA synthesis and as a signaling molecule. Here, we made a surprising discovery that the anti-proliferative activity of MPA acts synergistically with specific chemotherapeutic agents in a cell type-dependent manner. In MDA-MB-231 cells, MPA shows an extremely potent synergy with 5-FU but not with doxorubicin or etoposide. The synergy between 5-FU and MPA works most effectively against the highly tumorigenic mammary tumor cells compared to the less tumorigenic ones, and does not work in the non-breast cancer cell types that we tested, with the exception of PC3 cells. On the contrary, MPA shows the highest synergy with paclitaxel but not with 5-FU in SCC-25 cells, derived from oral squamous cell carcinomas. Mechanistically, the synergistic effect of MPA on 5-FU in MDA-MB-231 cells can be recapitulated by inhibiting the RNA polymerase-I activity and requires the expression of nucleostemin. This work reveals that the synergy between MPA and anti-proliferative agents is determined by cell type-dependent factors.

  11. Laboratory-determined transport properties of Berea sandstone

    International Nuclear Information System (INIS)

    Daily, W.D.; Lin, W.

    1985-01-01

    The authors report laboratory measurements of electrical resistivity water permeability k, and compressional wave velocity V/sub p/ for both intact and fractured Berea sandstone samples as functions of temperature from 20 C to 200 C and effective pressure P/sub e/ from 2.5 MPa to 50 MPa. For the intact sample, V/sub p/ increases from 3.52 km/s to 4.16 km/s as P/sub e/ goes from 3 to 50 MPa. With increasing temperature, V/sub p/ decreases at rates of about 3% per 100 C at P/sub e/ of 5 MPa and about 1.5% per 100 C at P/sub e/ of 38 MPa. Data from the fractured sample are qualitatively similar, but velocities are about 10% lower. For both intact and fractured samples, p increases less than 15% as P/sub e/ increases from 2.5 MPa to 50 MPa. Although both samples show a larger decrease in resistivity with increasing temperature, most of this change is attributed to the decrease in resistivity of the pore fluid over that temperature range. For both samples, k decreases with increasing pressure and temperature. The intact sample permeability varies from 23 mD at 3 MPa and 20 C to less than 1 mD at 50 MPa and 150 C. The permeability of the fractured sample varies from 676 mD at 3 MPa and 20 C to less than 1 mD at 40 MPa and 190 C. The effect of the fracture on k vanishes after several pressure cycles and above about 100 C. These laboratory data are used to demonstrate the possibility of using resistivity and velocity measurements to estimate in-situ permeability of a reservoir. 25 references, 10 figures

  12. The superiority of the autografts inactivated by high hydrostatic pressure to decellularized allografts in a porcine model.

    Science.gov (United States)

    Morimoto, Naoki; Mahara, Atsushi; Jinno, Chizuru; Ogawa, Mami; Kakudo, Natsuko; Suzuki, Shigehiko; Fujisato, Toshia; Kusumoto, Kenji; Yamaoka, Tetsuji

    2017-11-01

    We are developing a novel skin regeneration therapy in which the inactivation of nevus tissue via high hydrostatic pressure (HHP) is used in the reconstruction of the dermis in combination with a cultured epidermal autograft. In this study, we used a porcine skin graft model to explore whether autologous skin including cellular debris inactivated by HHP or allogeneic skin decellularized by HHP is better for dermal reconstruction. Grafts (n = 6) were prepared for five groups each: autologous skin without pressurization group (control group), autologous skin inactivated by 200 MPa group, autologous skin inactivated by 1000 MPa group, allogeneic skin decellularized by 200 MPa group, and allogeneic skin decellularized by 1000 MPa group. All of the grafts at 1, 4, and 12 weeks showed complete engraftment macroscopically. The mean areas of the grafts of the control group (p < 0.01) and autologous 200 MPa group (p < 0.01) were larger than that of the allogeneic 1000 MPa group at four weeks after implantation. The thickness of the control group and autologous 200 MPa group was comparable, and that of the autologous 200 MPa group was significantly thicker than that of the allogeneic 200 MPa group (p < 0.01). This suggests that the autologous dermis was superior to the allogeneic decellularized dermis as a skin graft, and that HHP at 200 MPa provided a better outcome than HHP at 1000 MPa. © 2016 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 105B: 2653-2661, 2017. © 2016 Wiley Periodicals, Inc.

  13. Disease: H01658 [KEGG MEDICUS

    Lifescience Database Archive (English)

    Full Text Available toimmune disease characterized by systemic vasculitis. MPA predominantly affects small-calibre blood vessels...irected against proteinase 3 (PR3-ANCA). Not all patients, however, have ANCA. MPA is clinically characterized by small-vessel vascul...itis primarily affecting the kidneys and the lungs but o

  14. Using community-level metrics to monitor the effects of marine protected areas on biodiversity.

    Science.gov (United States)

    Soykan, Candan U; Lewison, Rebecca L

    2015-06-01

    Marine protected areas (MPAs) are used to protect species, communities, and their associated habitats, among other goals. Measuring MPA efficacy can be challenging, however, particularly when considering responses at the community level. We gathered 36 abundance and 14 biomass data sets on fish assemblages and used meta-analysis to evaluate the ability of 22 distinct community diversity metrics to detect differences in community structure between MPAs and nearby control sites. We also considered the effects of 6 covariates-MPA size and age, MPA size and age interaction, latitude, total species richness, and level of protection-on each metric. Some common metrics, such as species richness and Shannon diversity, did not differ consistently between MPA and control sites, whereas other metrics, such as total abundance and biomass, were consistently different across studies. Metric responses derived from the biomass data sets were more consistent than those based on the abundance data sets, suggesting that community-level biomass differs more predictably than abundance between MPA and control sites. Covariate analyses indicated that level of protection, latitude, MPA size, and the interaction between MPA size and age affect metric performance. These results highlight a handful of metrics, several of which are little known, that could be used to meet the increasing demand for community-level indicators of MPA effectiveness. © 2015 Society for Conservation Biology.

  15. Determination of mycophenolic acid in mest products using mixed mode reversed phase-anion exchange clean-up and liquid chromatography-high-resolution mass spectrometry

    DEFF Research Database (Denmark)

    Sørensen, Louise Marie; Nielsen, Kristian Fog; Jacobsen, Thomas

    2008-01-01

    A method for determination of mycophenolic acid (MPA) in dry-cured ham, fermented sausage and liver pate is described. MPA was extracted from meat with bicarbonate-acetonitrile, further cleaned-up by mixed mode reversed phase-anion exchange and detected using a LC-MS system with electrospray...

  16. The effect of high temperatures on concrete incorporating ultrafine ...

    African Journals Online (AJOL)

    In this work, several concrete formulations have been tested and multi-scale observation of high-temperature behavior of ordinary concrete (compressive strength of 48 MPa) and HPC (compressive strength 75 MPa) were adopted. On the scale of the material, the identification of trends with temperature data such as porosity ...

  17. Bond behavior of reinforcing steel in ultra-high performance concrete.

    Science.gov (United States)

    2014-10-01

    Ultra-High Performance Concrete (UHPC) is a relatively new class of advanced cementitious composite : materials, which exhibits high compressive [above 21.7 ksi (150 MPa)] and tensile [above 0.72 ksi (5 MPa)] : strengths. The discrete steel fiber rei...

  18. Neutron diffraction measurements of residual stress in a powder metallurgy component

    International Nuclear Information System (INIS)

    Schneider, L.C.R.; Hainsworth, S.V.; Cocks, A.C.F.; Fitzpatrick, M.E.

    2005-01-01

    Residual stresses in a typical industrial green component were determined using neutron diffraction. The measured residual stresses were found to correlate with cross-sectional variations. Residual stress at the edge of the compact in contact with the die wall during compaction reached up to +80 MPa (tension) and -100 MPa (compression)

  19. Dynamic Crack Branching - A Photoelastic Evaluation,

    Science.gov (United States)

    1982-05-01

    0.41 mPai and a 0.18 MPa, and predicted a theoretical kinking angle of 84°whichagreed well with experimentally measured angle. After crack kinking...Consistent crack branching’at KIb = 2.04 MPaI -i- and r = 1.3 mm verified this crack branching criterion. The crack branching angle predicted by--.’ DD

  20. 75 FR 81233 - Nomination of Existing Marine Protected Areas to the National System of Marine Protected Areas

    Science.gov (United States)

    2010-12-27

    ... criteria. The inventory is online at http://www.mpa.gov/helpful_resources/inventory.html , and potentially eligible sites are posted online at http://www.mpa.gov/pdf/national-system/nominationsummary810.pdf . As... Conservation Area. Saunders Reef State Marine Conservation Area. Del Mar Landing State Marine Reserve. Stewarts...

  1. Characterising the water use and hydraulic properties of riparian tree invasions: A case study of Populus canescens in South Africa

    CSIR Research Space (South Africa)

    Ntshidi, Zanele

    2018-04-01

    Full Text Available catchment of South Africa. Whole tree hydraulic resistance ranged from ~ 1.4 MPa·h·g(sup)-1 for large trees to ~14.3 MPa·h·g(sup)-1 for the small ones. These resistances are higher than those found for poplars in temperate climates, suggesting substantial...

  2. "i h8 u": The Influence of Normative Beliefs and Hostile Response Selection in Predicting Adolescents' Mobile Phone Aggression--A Pilot Study

    Science.gov (United States)

    Nicol, Annemarie; Fleming, Michele J.

    2010-01-01

    Mobile phone aggression (MPA) is a relatively new phenomenon. Using newly developed measures, a pilot study was conducted with 348 adolescents ages 13-17 years to determine the incidence of MPA and victimization in this group of adolescents and to test a proposed model in which hostile response selection mediated the relationship between normative…

  3. Medroxyprogesterone acetate attenuates estrogen-induced nitric oxide production in human umbilical vein endothelial cells

    International Nuclear Information System (INIS)

    Oishi, Akira; Ohmichi, Masahide; Takahashi, Kazuhiro; Takahashi, Toshifumi; Mori-Abe, Akiko; Kawagoe, Jun; Otsu, Reiko; Mochizuki, Yoshiko; Inaba, Noriyuki; Kurachi, Hirohisa

    2004-01-01

    We report the novel observation that medroxyprogesterone acetate (MPA) attenuates the induction by 17β estradiol (E2) of both nitric oxide (NO) production and endothelial nitric oxide synthase (eNOS) activity in human umbilical vein endothelial cells. Although MPA had no effect on basal NO production or basal eNOS phosphorylation or activity, it attenuated the E2-induced NO production and eNOS phosphorylation and activity. Moreover, we examined the mechanism by which MPA attenuated the E2-induced NO production and eNOS phosphorylation. MPA attenuated the E2-induced phosphorylation of Akt, a kinase that phosphorylates eNOS. Treatment with pure progesterone receptor (PR) antagonist RU486 completely abolished the inhibitory effect of MPA on E2-induced Akt phosphorylation and eNOS phosphorylation. In addition, the effects of actinomycin D were tested to rule out the influence of genomic events mediated by nuclear PRs. Actinomycin D did not affect the inhibitory effect of MPA on E2-induced Akt phosphorylation. Furthermore, the potential roles of PRA and PRB were evaluated. In COS cells transfected with either PRA or PRB, MPA attenuated E2-induced Akt phosphorylation. These results indicate that MPA attenuated E2-induced NO production via an Akt cascade through PRA or PRB in a non-genomic manner

  4. An alternative method for estimating the status of resident reef fish ...

    African Journals Online (AJOL)

    The stock status of roman Chrysoblephus laticeps was estimated in the Goukamma, a temperate South African marine protected area (MPA). Standardised catch per unit effort (CPUE) from a controlled angling survey on both sides of the MPA border was employed to extrapolate the CPUE at zero fishing mortality. Converted ...

  5. A comprehensive review of the published assays for the quantitation of the immunosuppressant drug mycophenolic acid and its glucuronidated metabolites in biological fluids

    DEFF Research Database (Denmark)

    Syed, Muzeeb; Srinivas, Nuggehally R

    2016-01-01

    Therapeutic use of mycophenolic acid (MPA) is steadily on the rise in combination with other immunosuppressant drugs in transplantation patients. The biotransformation of MPA resulted in the formation of glucuronide metabolites, MPAG and AcMPAG. There are a plethora of assays validated for the an...

  6. The geomechanical strength of carbonate rock in Kinta valley, Ipoh, Perak Malaysia

    Science.gov (United States)

    Mazlan, Nur Amanina; Lai, Goh Thian; Razib, Ainul Mardhiyah Mohd; Rafek, Abdul Ghani; Serasa, Ailie Sofyiana; Simon, Norbert; Surip, Noraini; Ern, Lee Khai; Mohamed, Tuan Rusli

    2018-04-01

    The stability of both cut rocks and underground openings were influenced by the geomechanical strength of rock materials, while the strength characteristics are influenced by both material characteristics and the condition of weathering. This paper present a systematic approach to quantify the rock material strength characteristics for material failure and material & discontinuities failure by using uniaxial compressive strength, point load strength index and Brazilian tensile strength for carbonate rocks. Statistical analysis of the results at 95 percent confidence level showed that the mean value of compressive strength, point load strength index and Brazilian tensile strength for with material failure and material & discontinuities failure were 76.8 ± 4.5 and 41.2 ± 4.1 MPa with standard deviation of 15.2 and 6.5 MPa, respectively. The point load strength index for material failure and material & discontinuities failure were 3.1 ± 0.2 MPa and 1.8 ± 0.3 MPa with standard deviation of 0.9 and 0.6 MPa, respectively. The Brazilian tensile strength with material failure and material & discontinuities failure were 7.1 ± 0.3 MPa and 4.1 ± 0.3 MPa with standard deviation of 1.4 and 0.6 MPa, respectively. The results of this research revealed that the geomechanical strengths of rock material of carbonate rocks for material & discontinuities failure deteriorates approximately ½ from material failure.

  7. Processing–structure–property relations of chemically bonded ...

    Indian Academy of Sciences (India)

    Administrator

    different calcium phosphates (brushite, monetite and cal- ... treatment is 8 MPa and after heating to 1000°C is 11 MPa. ... figure 1. 2.1 Sample preparation. A patented phosphoric acid formulation from ... added: mechanical mixing using metallic blades resulted ... was a Desktop Micro CT-System (Skyscan 1072), run at.

  8. THE USE OF NATURAL TRASS FROM SAYUTAN MAGETAN AND LIME FROM NGAMPEL BLORA AS THE MATERIAL OF CEMENT SUBSTITUTION FOR MORTAR MIXTURE

    Directory of Open Access Journals (Sweden)

    Muhammad Nurzain

    2015-05-01

    Full Text Available Construction works in the Regency of Magetan, as well as in the mountain area far from capital cities and remote from transportation facilities, require large amount of material. In order to cope with the need of sand, people uses natural trass which are plenty to be found in the area. Test and research on its characteristic and strength with its potentials to be used as cement substitution have never been carried out. Lime was taken from Ngampel village, Blora as it is commonly sold in the area. The planned mixture of lime-trass paste was in the effort to obtain the best composition. The weight ratios used were 100%:0%, 80%:20%, 60%:40%, 40%:60%, 20%:80 and 0%:100%. The mortar mixture with cement substitution was 100%, 80%, 60%, 40%, 20% and 0%.The compressive strength of the lime-trash mixture was between 0.000 MPa and 2.545 MPa. The mortar compressive strength achieved was 0.373 MPa - 26.585 MPa. The test results of mortar compressive strength showed that the more cement substitution amount used, the less the compressive strength would be. The mortar compressive strength increased in line to the age of the mortar. The mortar tensile strength obtained was 0.000 MPa - 2.169 MPa. The block compressive strength obtained was 3.336 MPa - 3.403 MPa. Water absorbency of the block was 15.831% -16.056%.

  9. Music Performance Anxiety among Students of the Academy in Lithuania

    Science.gov (United States)

    Paliaukiene, Vilma; Kazlauskas, Evaldas; Eimontas, Jonas; Skeryte-Kazlauskiene, Monika

    2018-01-01

    Music performance anxiety (MPA) affects amateurs, students and professional musicians. We aimed to analyse MPA among students of music performance in a higher education academy in Lithuania. A sample of 258 music performance arts students of the Lithuanian Music and Theatre Academy participated in this study. The Kenny Music Performance Anxiety…

  10. Acceptance and Commitment Therapy for the Treatment of Music Performance Anxiety: A Pilot Study with Student Vocalists.

    Science.gov (United States)

    Juncos, David G; Heinrichs, Glenn A; Towle, Philip; Duffy, Kiera; Grand, Sebastian M; Morgan, Matthew C; Smith, Jonathan D; Kalkus, Evan

    2017-01-01

    This study investigated the use of Acceptance and Commitment Therapy (ACT) as a treatment for music performance anxiety (MPA) in an uncontrolled pilot design. ACT is a newer, "third-wave" therapy that differs from previous MPA treatments, because its goal is not to reduce symptoms of MPA. Rather, ACT aims to enhance psychological flexibility in the presence of unwanted symptoms through the promotion of six core processes collectively known as the ACT "Hexaflex." A small group of student vocalists ( N = 7) from an elite choral college were recruited using objective criteria for evaluating MPA. Participants received 12 ACT sessions, and their baseline functioning served as a pre-treatment control. Treatment consisted of an orientation to ACT, identifying experientially avoidant behaviors, facilitation of Hexaflex processes, group performances in which valued behaviors were practiced in front of one another, meditations, homework, and completion of self-report measures before, during, and after treatment (at a 1- and 3-month follow-up). Improvements were observed in participants' cognitive defusion, acceptance of MPA symptoms, and psychological flexibility at post-treatment and follow-ups. Students also appeared to improve their performance quality and reduce their shame over having MPA. These results add to existing research suggesting ACT is a promising intervention for MPA, while also highlighting how vocal students may be less impaired by physical MPA symptoms.

  11. Progestins used in hormonal replacement therapy display different effects in coronary arteries from New Zealand white rabbits

    DEFF Research Database (Denmark)

    Pedersen, Nina G; Pedersen, Susan H; Dalsgaard, Tórur

    2004-01-01

    ) medroxyprogesterone acetate (MPA), (2) norethisterone acetate (NETA), (3) conjugated equine estrogens (CEE), (4) 17-beta-estradiol (E2), (5) MPA+CEE , (6) NETA+E2 , (7) or placebo (n=8) and given hormonal treatment through the diet for 4 weeks. Ring segments from the left proximal coronary artery and from the distal...

  12. Probing into the binding interaction between medroxyprogesterone acetate and bovine serum albumin (BSA): spectroscopic and molecular docking methods.

    Science.gov (United States)

    Fang, Fang; Pan, Dong-Qi; Qiu, Min-Jie; Liu, Ting-Ting; Jiang, Min; Wang, Qi; Shi, Jie-Hua

    2016-09-01

    To further understand the mechanism of action and pharmacokinetics of medroxyprogesterone acetate (MPA), the binding interaction of MPA with bovine serum albumin (BSA) under simulated physiological conditions (pH 7.4) was studied using fluorescence emission spectroscopy, synchronous fluorescence spectroscopy, circular dichroism and molecular docking methods. The experimental results reveal that the fluorescence of BSA quenches due to the formation of MPA-BSA complex. The number of binding sites (n) and the binding constant for MPA-BSA complex are ~1 and 4.6 × 10(3)  M(-1) at 310 K, respectively. However, it can be concluded that the binding process of MPA with BSA is spontaneous and the main interaction forces between MPA and BSA are van der Waals force and hydrogen bonding interaction due to the negative values of ΔG(0) , ΔH(0) and ΔS(0) in the binding process of MPA with BSA. MPA prefers binding on the hydrophobic cavity in subdomain IIIA (site II'') of BSA resulting in a slight change in the conformation of BSA, but BSA retaining the α-helix structure. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

  13. Microstructures and properties of low-alloy fire resistant steel

    Indian Academy of Sciences (India)

    Unknown

    hardening. In a quenched and self-tempered 600 MPa class TMT reinforcement bar steel (YS: 624 MPa), low ..... of processing (1000–1050°C), static, dynamic as well as metadynamic recrystallization of austenite can occur (Poliak and Jonas ...

  14. 78 FR 49479 - Updates to List of National System of Marine Protected Areas MPAs

    Science.gov (United States)

    2013-08-14

    ... System of Marine Protected Areas MPAs AGENCY: National Marine Protected Areas Center (MPA Center), Office... Marine Protected Areas (MPAs). SUMMARY: The National System of Marine Protected Areas (MPAs) provides a... Protected Areas Center (MPA Center). The managing agencies listed above were then asked to make a final...

  15. Optimization of injection moulding process parameters in the ...

    African Journals Online (AJOL)

    In this study, optimal injection moulding conditions for minimum shrinkage during moulding of High Density Polyethylene (HDPE) were obtained by Taguchi method. The result showed that melting temperature of 190OC, injection pressure of 55 MPa, refilling pressure of 85 MPa and cooling time of 11 seconds gave ...

  16. The combined effect of high pressure and nisin or lysozyme on the inactivation of Alicyclobacillus acidoterrestris spores in apple juice

    Science.gov (United States)

    Sokołowska, B.; Skąpska, S.; Fonberg-Broczek, M.; Niezgoda, J.; Chotkiewicz, M.; Dekowska, A.; Rzoska, S.

    2012-03-01

    Alicyclobacillus acidoterrestris, a thermoacidophilic and spore-forming bacterium is one of the important target micro-organisms in the quality control of acidic canned foods. High pressure pasteurization (HPP) at 50°C was used for the inactivation of A. acidoterrestris spores in apple juice. Pressure applied both in a continuous and oscillatory mode gave the best results when 200 MPa was used. Increasing the pressure to 500 MPa, as well as lowering its value to 100 MPa, had an adverse effect on the effectiveness of the process. The best results were achieved with the use of a combined treatment, involving oscillatory pressurization at 200 MPa, followed by holding the sample for 60 min at atmospheric pressure and subsequent pressurization at 500 MPa, resulting in a reduction in the spore count of 6.15 log. Nisin significantly enhanced the effect of HPP at 300 MPa. Using pressure of 200 MPa for 45 min with a nisin concentration of 250 IU/mL enabled total spore inactivation (over 6 log). No significant effect of lysozyme at a concentration of 0.05 and 0.1 mg/L at 300 MPa was observed.

  17. Second NATO Workshop on Passive Infrared Optical Materials and Coatings

    Science.gov (United States)

    1987-12-01

    sponsor, NATO AC/243 ( Panel III tion is sprayed through a furnace at RSG 2). This is an abridged version of about 1000*C. A 7-hour operation yields the...strength, generate high-quality optical surfaces Cl, of the monocrystalline material is 4 162 MPa at a load increase rate of 18 MPa due to removal of water

  18. Design for limit stresses of orange fruits (Citrus sinensis under axial and radial compression as related to transportation and storage design

    Directory of Open Access Journals (Sweden)

    Christopher Chukwutoo Ihueze

    2017-01-01

    Full Text Available This article employed the Hertz contact stress theory and the finite element method to evaluate the maximum contact pressure and the limit stresses of orange fruit under transportation and storage. The elastic properties of orange fruits subjected to axial and axial contact were measured such that elastic limit force, elastic modulus, Poisson’s ratio and bioyield stress were obtained as 18 N, 0.691 MPa, 0.367, 0.009 MPa for axial compression and for radial loading were 15.69 N, 0.645 MPa, 0.123, 0.010 MPa. The Hertz maximum contact pressure was estimated for axial and radial contacts as 0.036 MPa. The estimated limiting yield stress estimated as von Mises stresses for the induced surface stresses of the orange topologies varied from 0.005 MPa–0.03 MPa. Based on the distortion energy theory (DET the yield strength of orange fruit is recommended as 0.03 MPa while based on the maximum shear stress theory (MSST is 0.01 MPa for the design of orange transportation and storage system.

  19. Demonstration of over core stress measurement from surface using the Sigra IST tool

    CSIR Research Space (South Africa)

    Gray, I

    2003-01-01

    Full Text Available are consistent in magnitude and direction. The major principal effective stress is in the region of 4 to 5 Mpa, which is small in the context of a rock UCS of 100 MPa. Of more concern if long wall mining were being considered is the minor principal stress which...

  20. Online Education in Public Affairs

    Science.gov (United States)

    Ginn, Martha H.; Hammond, Augustine

    2012-01-01

    This exploratory study provides an overview of the current landscape of online education in the fields of Master of Public Administration and Master of Public Policy (MPA/MPP) utilizing a dataset compiled from content analysis of MPA/MPP programs' websites and survey of 96 National Association of Schools of Public Affairs and Administration…

  1. Persistence of self-recruitment and patterns of larval connectivity in a marine protected area network

    KAUST Repository

    Berumen, Michael L.

    2012-02-01

    The use of marine protected area (MPA) networks to sustain fisheries and conserve biodiversity is predicated on two critical yet rarely tested assumptions. Individual MPAs must produce sufficient larvae that settle within that reserve\\'s boundaries to maintain local populations while simultaneously supplying larvae to other MPA nodes in the network that might otherwise suffer local extinction. Here, we use genetic parentage analysis to demonstrate that patterns of self-recruitment of two reef fishes (Amphiprion percula and Chaetodon vagabundus) in an MPA in Kimbe Bay, Papua New Guinea, were remarkably consistent over several years. However, dispersal from this reserve to two other nodes in an MPA network varied between species and through time. The stability of our estimates of self-recruitment suggests that even small MPAs may be self-sustaining. However, our results caution against applying optimization strategies to MPA network design without accounting for variable connectivity among species and over time. 2012 The Authors.

  2. Analysis of the Effect of Injection Pressure on Ignition Delay and Combustion Process of Biodiesel from Palm Oil, Algae and Waste Cooking Oil

    Science.gov (United States)

    Irham Anas, Mohd; Khalid, Amir; Hakim Zulkifli, Fathul; Jaat, Norrizam; Faisal Hushim, Mohd; Manshoor, Bukhari; Zaman, Izzuddin

    2017-10-01

    Biodiesel is a domestically produced, renewable fuel that can be manufactured from vegetable oils, animal fats, or recycled restaurant grease for use in diesel engines. The objective of this research is investigation the effects of the variant injection pressure on ignition delay and emission for different biodiesel using rapid compression machine. Rapid Compression Machine (RCM) is used to simulate a single compression stroke of an internal combustion engine as a real engine. Four types of biodiesel which are waste cooking oil, crude palm oil, algae and jatropha were tested at injection pressure of 80 MPa, 90 MPa and 130 MPa under constant ambient temperature at 950 K. Increased in injection pressure resulted shorter ignition delay proven by WCO5 which decreased from 1.3 ms at 80 MPa to 0.7 ms at 130 MPa. Meanwhile, emission for CO2 increased due to better fuel atomization for fuel-air mixture formation lead to completed combustion.

  3. COMPACTION STUDIES OF TORREFIED WILLOW

    Directory of Open Access Journals (Sweden)

    Michał Rejdak

    2017-01-01

    Full Text Available The article presents the results of studies of torrefied willow (Salix viminalis L. compaction. Densification tests were performed using a hydraulic press with a maximum pressure of 216 MPa. The effect of basic parameters of the briquetting process (pressure and temperature on mechanical parameters of manufactured briquettes were determined. On the basis of the research, it was found that the increase in pressure and temperature of the densification process increases the density and strength of pressed briquettes. The positive effect of temperature is particularly noticeable at lower pressing pressures (36 MPa – 72 MPa. In the case of a temperature of 300 °C, the increase in a pressure from 144 MPa to 216 MPa resulted in the decrease in the density and strength of the briquette. It was also found that the briquettes manufactured at this temperature are characterized by lower density and strength than the briquettes obtained at a temperature of 200 °C.

  4. Stress corrosion cracking of an uranium-6 weight per cent niobium in gaseous oxygen, nitrogen and hydrogen

    International Nuclear Information System (INIS)

    Brunet, H.

    1989-01-01

    Stress corrosion cracking (SCC) of uranium-6 weight per cent niobium alloy is studied in gaseous oxygen at room temperature (for pressures between 4.10 -7 and 0.15MPa) and 100 0 C (pressure of 0.15 MPa) and in gaseous hydrogen (for pressures between 10 -6 and 0.15 MPa). SCC map and cracking kinetics are determined as fonctions of stress-intensity factor, pressure and temperature. For oxygen, temperature seems to have no effect on the alloy embrittlement within the range of this study but the pressure influence is more complex. At room temperature, hydrogen pressure less than 0.15 MPa has no influence on the cracking kinetics. For a pressure of 0.15 MPa, fracture occurs by hydriding reaction. Complementary analyses on fracture surfaces lead to propose different mechanics responsible for cracking kinetics in these environments [fr

  5. The effect of high hydrostatic pressure on black truffle (tuber melanosporum) flavour compounds

    International Nuclear Information System (INIS)

    Verret, C; Ballestra, P; Cruz, C; Moueffak, A H E; Pardon, P; Largeteau, A

    2008-01-01

    The effects of high hydrostatic pressure (HHP), at 4 0 C or -18 0 C, on black truffle flavour compounds, alteration enzymes (lipoxigenase (LOX), peroxidase (POD) and polyphenoloxidase (PPO)) and microbiological qualities were evaluated. The choosen analytes for this study are six alcohols, three aldehydes, one ketone and on sulfur component. The highest flavour stability was observed when samples were pressurized at 300 MPa / 4 0 C / 10 min. All the treatments induced a drastic decrease of LOX activity and a slight decrease of POD activity. On the other hand, the PPO was not inactivated by pressurization at sub-zero (200 MPa / -18 0 C / 10 min) and was strongly increased after the 300 MPa / 4 0 C / 10 min treatment. Pressurization at 300 and 550 MPa lead to an almost complete Pseudomonas fluorescens reduction (6 and 6.5 log destruction, respectively) whereas pressurization at -18 0 C (200MPa) allowed to obtain only 3 log reduction

  6. Marine protected area design patterns in the Mediterranean Sea: Implications for conservation.

    Science.gov (United States)

    Rodríguez-Rodríguez, D; Rodríguez, J; Blanco, J M; Abdul Malak, D

    2016-09-15

    Mediterranean marine protected area (MPA) design patterns regarding geographic distribution, size, spacing and shape were analysed as a proxy of the region's MPA's ecological effectiveness and a first step towards an ecologically coherent MPA network. Results for legally designated MPAs and ecologically functional MPAs accounting for overlaps are presented. Geographically, Mediterranean MPA area is very unevenly distributed, with four-fifths concentrated in just three countries of the north-western part of the basin. Average distance between functional MPAs lies within recommended ecological thresholds, which suggests adequate potential connectivity of the Mediterranean MPA system. Mediterranean designated MPAs are larger than MPAs worldwide on average, although they are generally smaller than international guidance suggests at different levels: ecoregion, country and designation category. On average, Mediterranean designated and functional MPAs have relatively high compactness, which makes them prone to spillover and adequate viability, and less vulnerable to edge effects. Copyright © 2016 Elsevier Ltd. All rights reserved.

  7. Structure of macroalgal communities on tropical rocky shores inside and outside a marine protected area.

    Science.gov (United States)

    Portugal, Adriana Brizon; Carvalho, Fabrício Lopes; Soares, Marcelo de Oliveira; Horta, Paulo Antunes; de Castro Nunes, José Marcos

    2017-09-01

    The structure of marine macroalgal communities and morpho-functional groups were investigated in a poorly characterized region on the Tropical Southwestern Atlantic coast, Brazil. The survey was conducted at six rocky shores located on the mainland and on coastal islands distributed inside a marine protected area (MPA) and outside the MPA (near a densely populated area). We hypothesized that tropical rocky shores inside the MPA and islands have higher species richness, diversity, and evenness of marine macroalgae. Results confirmed that species richness, diversity and evenness were significantly higher inside the MPA than in rocky shores outside the MPA. Only species richness was higher on islands than on the mainland. The results suggest that human impacts could lead to a competitive advantage and dominance in the articulated calcareous morphotype, resulting in community differences and lower benthic biodiversity in tropical ecosystems near urbanized sites. Copyright © 2017 Elsevier Ltd. All rights reserved.

  8. Do cytostatic drugs reach drinking water? The case of mycophenolic acid.

    Science.gov (United States)

    Franquet-Griell, Helena; Ventura, Francesc; Boleda, M Rosa; Lacorte, Silvia

    2016-01-01

    Mycophenolic acid (MPA) has been identified as a new river contaminant according to its wide use and high predicted concentration. The aim of this study was to monitor the impact of MPA in a drinking water treatment plant (DWTP) that collects water downstream Llobregat River (NE Spain) in a highly densified urban area. During a one week survey MPA was recurrently detected in the DWTP intake (17-56.2 ng L(-1)). The presence of this compound in river water was associated to its widespread consumption (>2 tons in 2012 in Catalonia), high excretion rates and low degradability. The fate of MPA in waters at each treatment step of the DWTP was analyzed and complete removal was observed after pretreatment with chlorine dioxide. So far, MPA has not been described as water contaminant and its presence associated with its consumption in anticancer treatments is of relevance to highlight the importance of monitoring this compound. Copyright © 2015 Elsevier Ltd. All rights reserved.

  9. Effects of the ultra-high pressure on structure and α-glucosidase inhibition of polysaccharide from Astragalus.

    Science.gov (United States)

    Zhu, Zhen-Yuan; Luo, You; Dong, Guo-Ling; Ren, Yuan-Yuan; Chen, Li-Jing; Guo, Ming-Zhu; Wang, Xiao-Ting; Yang, Xue-Ying; Zhang, Yongmin

    2016-06-01

    A novel homogeneous polysaccharide fraction (APS) was extracted from Astragalus by hot water and purified by Sephadex G-100 and G-75 column. Its molecular weight was 693kDa. APS and APS with ultra-high pressure treatment exhibited significant inhibitory abilities on a-glucosidase, inhibition rate from high to low in order was 400MPa-APS, 300MPa-APS, 500MPa-APS and APS. The inhibition ​percentage of 400MPa-APS (1.5mg/mL) was 49% (max.). This suggested that the inhibitory activity of APS on a-glucosidase was improved by ultra-high pressure treatment. FT-IR, SEM, CD spectra, atomic force microscope and Congo red test analysis of APS and 400MPa-APS showed ultra-high pressure treatment didn't change the preliminary structure but had an effect on its advanced structure. Copyright © 2016 Elsevier B.V. All rights reserved.

  10. EVALUATION OF STRAIN-STRESS STATE OF THE RAILS IN THE PRODUCTION

    Directory of Open Access Journals (Sweden)

    V. V. Muravev

    2017-01-01

    Full Text Available High values of residual stresses is one of the most common reason of breaking lots of metal constructions, including rails. These stresses can reach values of flow limit, especially in the area of faults. Estimation of residual stresses values allows to get information about technical condition of the rail and also allow to avoid abnormal situations So, the aim of the research is creating the model of stress-strain state of the rail, which was hardened in its top and bottom, and to compare modeling results with experimental measurements of stresses and discrepancy of the housing.For creating the model and making evaluations by finite element method we used a program COMSOL. Forces on the top and bottom of the rail cause tension stresses, forces on the web of the rail cause tensile stresses. We compared calculated values of stresses with discrepancy of the housing. The discrepancy of the housing is informative characteristic for estimating the residual stresses according to standards. For experimental measurements we used an acoustic structuroscope SEMA. This structuroscope uses the acoustoelastic phenomenon for measurements. We made measurements of the five rails.According to the calculation results of the model, critical discrepancy of the housing in 2 mm corresponded to the following values of maximum stresses: –54 MPa in the top of the rail, 86 MPa in the web and –62 MPa in the bottom of the rail. Experimental measurements are the following: from –48 MPa to – 64 MPa in the top of the rail, 54 MPa to 93 MPa in the web of the rail, and –59 MPA to –74 MPa in the bottom of the rail. Absolute error was ±5 MPa.Thus we created the model, which allowed to analyze strain-stress state and compare real values of stresses with discrepancy of the housing. Results of the modeling showed coincidence with structure of distribution of residual stresses in five probes of rails. 

  11. Exposure to Mycophenolate and Fatherhood.

    Science.gov (United States)

    Midtvedt, Karsten; Bergan, Stein; Reisæter, Anna Varberg; Vikse, Bjørn Egil; Åsberg, Anders

    2017-07-01

    Mycophenolic acid (MPA) is the active immunosuppressive substance in both mycophenolate mofetil and mycophenolate sodium, and it is widely used after organ transplantation. In women, taking MPA is teratogenic and may also influence spermatogenesis. There is a lack of knowledge regarding outcome of pregnancies fathered by men exposed to MPA. We compared outcomes in pregnancies fathered by renal transplant men per whether they had been exposed to MPA or not at time of conception. A nationwide population-based retrospective cohort study was performed. Data from the Norwegian Renal Registry with all renal transplanted men alive between January 1, 1995 and December 31, 2015 were included, and relevant outcome data were extracted from the Medical Birth Registry of Norway. During the given time, 230 immunosuppressed renal transplanted men fathered 350 children (155 on MPA/195 not on MPA). There were no significant increased risks of malformation (3.9% vs. 2.6%, P = 0.49) in MPA exposed versus unexposed cohorts of children. The average dose (±SD) of mycophenolate was 1.42 ± 0.3 g/day and the individual median MPA trough concentration in the time period of anticipated conception and pregnancy was 2.8 ± 1.6 mg/L. Birth weight was similar in exposed and unexposed cohorts of children; 3381 ± 681 g vs. 3429 ± 714 g (P = 0.53). Paternal exposure to MPA did not increase the risk of adverse birth outcomes in children fathered by male kidney transplanted patients. These results are reassuring and support the continuation of paternal MPA treatment before, during, and after conception.

  12. Different responses to treatment across classified diseases and severities in Japanese patients with microscopic polyangiitis and granulomatosis with polyangiitis: a nationwide prospective inception cohort study.

    Science.gov (United States)

    Sada, Ken-ei; Yamamura, Masahiro; Harigai, Masayoshi; Fujii, Takao; Takasaki, Yoshinari; Amano, Koichi; Fujimoto, Shouichi; Muso, Eri; Murakawa, Yohko; Arimura, Yoshihiro; Makino, Hirofumi

    2015-11-02

    This study aims to elucidate the prognosis and the effectiveness of current treatments for Japanese patients with microscopic polyangiitis (MPA) and granulomatosis with polyangiitis (GPA). Patients with newly diagnosed MPA and GPA were enrolled in a nationwide, prospective, inception cohort study from 22 tertiary Japanese institutions, and treatment patterns and responses were evaluated for 24 months. Primary outcome measures were rates of remission (Birmingham Vasculitis Activity Score, 0) and remission with low-dose glucocorticoids (GC) (prednisolone ≤ 10 mg) (GC remission). Of 156 enrolled patients, 78 MPA patients and 33 GPA patients were included. Concomitant cyclophosphamide (CY) was used in 24 MPA (31 %) and 20 GPA (60 %) patients during the initial 3 weeks of treatment. After 6 months, remission was achieved in 66 MPA (85 %) and 29 GPA (87 %) patients, while GC remission was obtained in only 31 MPA (40 %) and 13 GPA (39 %) patients. During the 24-month period, 14 MPA patients and 2 GPA patients died; end stage renal disease (ESRD) was noted in 13 MPA patients but no GPA patients. Patients with severe disease, according to the European Vasculitis Study Group (EUVAS) classification, showed poorer ESRD-free and overall survival rates than those with generalized disease (p < 0.0001). There were no differences in relapse-free survival rates between GPA and MPA, among EUVAS-defined disease severity categories, and between anti-neutrophil cytoplasmic antibody subspecialties. The majority of Japanese patients with MPA and GPA received treatment with high-dose GC and limited CY use, and showed high remission and relapse-free survival rates but low GC remission rates in clinical practice. University Hospital Medical Information Network Clinical Trials Registry UMIN000001648 . Registered 28 February 2009.

  13. New Insights on the Creeping Phase of the Vajont Landslide form Rotary-Shear Experiments

    Science.gov (United States)

    Ferri, F.; Spagnuolo, E.; Di Felice, F.; Di Toro, G.

    2014-12-01

    It is well known that 1963 catastrophic Vajont landslide (NE Italy) was preceded by a creeping phase monitored over three years before the collapse and that water played a significant role in the instability of the rock sequence. However, the transition from the creeping phase to instability still remains elusive. Here we report experiments carried out in a rotary-shear friction apparatus (SHIVA at INGV, Rome, Italy) on smectite-rich gouges collected from the landslide surface (60-70% smectite, 20-30% calcite and minor quartz). Experiments were performed under shear stress controlled conditions at normal stress σnof 3-5 MPa in the presence of water (20% weight), and at room humidity. During the experiments, the shear stress τ was increased by a constant value Δτ and maintained for a fixed time Δt before applying the following shear stress step. When frictional instability was achieved, the machine started to rotate at an imposed velocity. In the first set of experiments, the initial τ (0.05 MPa) was increased by steps of Δτ = 0.25 MPa with Δt of 150 seconds. In the room humidity material, a series of spontaneous slip bursts occurred at τ = 2.5 MPa (at σn = 5MPa) until the shear stress reached 3.0 MPa. At this point, a large stress drop occurred with concomitant dilation. In the wet material, instability took place at τ= 0.3 MPa (at σn= 3 MPa). After forcing τ down, the material re-strengthened. A second main instability occurred when τ was restored to 0.3 MPa, with expulsion of water drops accompanied by an episode of dilation. At this point, the material spontaneously re-strengthened with a stick-slip behavior similar to that observed at room humidity conditions. In the second set of experiments, Δτ was reduced to 0.05 MPa and Δt increased up to 360 seconds producing a general enhancement of the shear stress required to generate unstable sliding. Instability took place at very high τ (3.12 MPa at σn= 3 MPa) at room-humidity conditions, and at

  14. Evaluating the Ultra-High Pressure Homogenization (UHPH and Pasteurization effects on the quality and shelf life of donkey milk

    Directory of Open Access Journals (Sweden)

    Cephas Nii Akwei Addo

    2015-04-01

    Full Text Available Donkey milk has functional properties of great interest to human nutrition. The effects of ultra-high pressure homogenization (UHPH at 100 MPa, 200 MPa and 300 MPa in comparison with different pasteurization treatments of 70 °C for 1 min and 85 °C for 1 min on the physicochemical quality and shelf-life of treated and raw (untreated donkey milk were studied. Gross composition and pH, total mesophilic counts, lysozyme activity and physical stability were studied during storage at 4 °C for 28 days. The compositional profile showed resemblance to that of human milk characterized by high lactose, low fat and low protein content and was least affected by the treatments. UHPH treatments at 200 MPa, 300 MPa and 85 °C were able to maintain steady pH during storage whereas the low intensity treatments showed a significant decrease. The observed lysozyme activity in the samples was generally high and appeared to have been enhanced by the applied UHPH and pasteurization treatments with no significant change during storage. Although the raw milk showed good initial microbial quality, extensive growth of mesophilic microorganisms occurred after 7 days of storage, unlike the treated samples which were able to maintain significantly low counts throughout the storage period. The physical stability of milk was negatively influenced by the higher UHPH treatments of 200 MPa and 300 MPa which exhibited sedimentation phenomenon, while creaming was insignificant.

  15. Stress-dependent permeability and wave dispersion in tight cracked rocks: Experimental validation of simple effective medium models

    Science.gov (United States)

    Sarout, Joel; Cazes, Emilie; Delle Piane, Claudio; Arena, Alessio; Esteban, Lionel

    2017-08-01

    We experimentally assess the impact of microstructure, pore fluid, and frequency on wave velocity, wave dispersion, and permeability in thermally cracked Carrara marble under effective pressure up to 50 MPa. The cracked rock is isotropic, and we observe that (1) P and S wave velocities at 500 kHz and the low-strain (S waves and 9% for P waves at 1 MPa, and (4) wave dispersion virtually vanishes above 30 MPa. Assuming no interactions between the cracks, effective medium theory is used to model the rock's elastic response and its permeability. P and S wave velocity data are jointly inverted to recover the crack density and effective aspect ratio. The permeability data are inverted to recover the cracks' effective radius. These parameters lead to a good agreement between predicted and measured wave velocities, dispersion and permeability up to 50 MPa, and up to a crack density of 0.5. The evolution of the crack parameters suggests that three deformation regimes exist: (1) contact between cracks' surface asperities up to 10 MPa, (2) progressive crack closure between 10 and 30 MPa, and (3) crack closure effectively complete above 30 MPa. The derived crack parameters differ significantly from those obtained by analysis of 2-D electron microscope images of thin sections or 3-D X-ray microtomographic images of millimeter-size specimens.

  16. Test of small-scale central-core-cavity closure for a 300-MW(e) GCFR

    International Nuclear Information System (INIS)

    Robinson, G.C.; Dougan, J.R.; Naus, D.J.

    1981-01-01

    Under the Prestressed Concrete Reactor Vessel (PCRV) Program at the Oak Ridge National Laboratory, model tests are conducted to verify the design of the PCRV for a 300 MW(e) Gas-Cooled Fast Reactor (GCFR). Prominent features of the 1:20-scale central core cavity model included a close pitched array of fifty-five penetration tubes, forty-four segmented gusset/bearing plate assemblies, and intermeshed reinforcing steel. The closure model which was designed for a maximum cavity pressure (MCP) of 10.08 MPa was initially tested by applying 10 pressurization cycles from essentially no load to the MCP with strain and deflection data obtained during each cycle. This was followed by pressurization cycles to 32.8 MPa, 41.3 MPa, 48.3 MPa, 58.4 MPa and 79.3 MPa. At a pressure of 79.3 MPa an end cap on a penetration tube developed leaks and the test was terminated. An inelastic analysis was conducted to provide an estimate of the ultimate strength of the closure plug and to determine the potential mode of failure

  17. Glucose kinetics at rest and during exercise in gluconeogenesis-inhibited rats

    International Nuclear Information System (INIS)

    Turcotte, L.P.

    1988-01-01

    To evaluate the role played by gluconeogenesis in blood glucose homeostasis, untrained and trained rats were injected with mercaptopicolinic acid (MPA), a known inhibitor of the gluconeogenic enzyme, phosphoenolpyruvate carboxykinase. Glucose turnover, recycling and oxidation rates were assessed by primed-continuous infusion of [U- 14 C]- and [6- 3 H] glucose at rest and during submaximal exercise at 13.4 m/min on level grade. When compared to the untrained sham-injected animals, the untrained MPA-treated animals had 22% lower and 44% higher resting blood glucose and lactate concentrations, respectively. Resting glucose turnover, calculated from [6- 3 H]glucose, was 32% lower in the MPA-treated animals than in the sham-injected animals. During exercise, turnover increased in the sham-injected animals but remained unchanged in the MPA-treated animals. MPA-treated animals had no glucose recycling at rest or during exercise. Exercise further decreased blood glucose concentration and increased blood lactate concentration in the MPA-treated animals, but MPA treatment did not change the exercise-induced increases in glucose oxidation rate, % total VCO 2 arising from glucose oxidation and metabolic clearance rate of glucose

  18. Significantly increased detection rate of drugs of abuse in urine following the introduction of new German driving licence re-granting guidelines.

    Science.gov (United States)

    Agius, Ronald; Nadulski, Thomas; Kahl, Hans-Gerhard; Dufaux, Bertin

    2012-02-10

    In this paper we present the first assessment of the new German driving licence re-granting medical and psychological assessment (MPA) guidelines by comparing over 3500 urine samples tested under the old MPA cut-offs to over 5000 samples tested under the new MPA cut-offs. Since the enzyme multiplied immunoassay technique (EMIT) technology used previously was not sensitive enough to screen for drugs at such low concentrations, as suggested by the new MPA guidelines, enzyme-linked immunosorbent assay (ELISA) screening kits were used to screen for the drugs of abuse at the new MPA cut-offs. The above comparison revealed significantly increased detection rates of drug use or exposure during the rehabilitation period as follows: 1.61, 2.33, 3.33, and 7 times higher for 11-nor-delta-9-tetrahydrocannabinol-9-carboxylic acid (THC-COOH), morphine, benzoylecgonine and amphetamine respectively. The present MPA guidelines seem to be more effective to detect non-abstinence from drugs of abuse and hence to detecting drivers who do not yet fulfil the MPA requirements to regain their revoked driving licence. Copyright © 2011 Elsevier Ireland Ltd. All rights reserved.

  19. Thioxanthone based 9-[2-(methyl-phenyl-amino)-acetyl]-thia-naphthacene-12-one as a visible photoinitiator

    International Nuclear Information System (INIS)

    Doğruyol, Sevnur Keskin; Doğruyol, Zekeriya; Arsu, Nergis

    2013-01-01

    Photoinitiators that operate in the visible range of the electromagnetic spectrum have widespread applications. Thioxanthone based 9-[2-(methyl-phenyl-amino)-acetyl]-thia-naphthacene-12-one (TX-MPA) was synthesized and the characterization of this initiator was confirmed by spectral analysis methods. TX-MPA has excellent absorption properties in the visible range (ε 480 nm =3576 L/mol.cm). Photophysical studies; fluorescence quantum yield (φ f =0.22, DPA), phosphorescence lifetime (τ p =115 ms) and triplet lifetime (τ=190 ns) were explored. To explore the initiation mechanism of TX-MPA, besides the photophysical and photochemical studies, the polymer (PMMA) obtained from the photopolymerization studies was subjected to a phosphorescence study and τ p was found to be 105 ms compared to 115 ms for the initiator TX-MPA which proved attachment of the initiator to the polymer. Possibly both intermolecular and intramolecular hydrogen abstraction, occur during the initiation stage depending on the concentration of the initiator. Highlights: ► Synthesis and photophysical properties of a visible photoinitiator (TX-MPA) are proposed. ► TX-MPA has high molar absorption values in the visible region. ► TX-MPA can initiate photopolymerization of methylmethacrylate monomer under UV and sunlight. ► Inter or intramolecular hydrogen abstraction mechanisms occur depending on initiator concentration

  20. Thioxanthone based 9-[2-(methyl-phenyl-amino)-acetyl]-thia-naphthacene-12-one as a visible photoinitiator

    Energy Technology Data Exchange (ETDEWEB)

    Doğruyol, Sevnur Keskin [Department of Chemistry, Yıldız Technical University, Davutpasa Campus, Esenler, 34220 Istanbul (Turkey); Doğruyol, Zekeriya [Department of Engineering Science, Istanbul University, 34850, Avcılar, Istanbul (Turkey); Arsu, Nergis, E-mail: narsu@yildiz.edu.tr [Department of Chemistry, Yıldız Technical University, Davutpasa Campus, Esenler, 34220 Istanbul (Turkey)

    2013-06-15

    Photoinitiators that operate in the visible range of the electromagnetic spectrum have widespread applications. Thioxanthone based 9-[2-(methyl-phenyl-amino)-acetyl]-thia-naphthacene-12-one (TX-MPA) was synthesized and the characterization of this initiator was confirmed by spectral analysis methods. TX-MPA has excellent absorption properties in the visible range (ε{sub 480} {sub nm}=3576 L/mol.cm). Photophysical studies; fluorescence quantum yield (φ{sub f}=0.22, DPA), phosphorescence lifetime (τ{sub p}=115 ms) and triplet lifetime (τ=190 ns) were explored. To explore the initiation mechanism of TX-MPA, besides the photophysical and photochemical studies, the polymer (PMMA) obtained from the photopolymerization studies was subjected to a phosphorescence study and τ{sub p} was found to be 105 ms compared to 115 ms for the initiator TX-MPA which proved attachment of the initiator to the polymer. Possibly both intermolecular and intramolecular hydrogen abstraction, occur during the initiation stage depending on the concentration of the initiator. Highlights: ► Synthesis and photophysical properties of a visible photoinitiator (TX-MPA) are proposed. ► TX-MPA has high molar absorption values in the visible region. ► TX-MPA can initiate photopolymerization of methylmethacrylate monomer under UV and sunlight. ► Inter or intramolecular hydrogen abstraction mechanisms occur depending on initiator concentration.

  1. Differential Sensitivities of Fast- and Slow-Cycling Cancer Cells to Inosine Monophosphate Dehydrogenase 2 Inhibition by Mycophenolic Acid

    Science.gov (United States)

    Chen, Kan; Cao, Wanlu; Li, Juan; Sprengers, Dave; Hernanda, Pratika Y; Kong, Xiangdong; van der Laan, Luc JW; Man, Kwan; Kwekkeboom, Jaap; Metselaar, Herold J; Peppelenbosch, Maikel P; Pan, Qiuwei

    2015-01-01

    As uncontrolled cell proliferation requires nucleotide biosynthesis, inhibiting enzymes that mediate nucleotide biosynthesis constitutes a rational approach to the management of oncological diseases. In practice, however, results of this strategy are mixed and thus elucidation of the mechanisms by which cancer cells evade the effect of nucleotide biosynthesis restriction is urgently needed. Here we explored the notion that intrinsic differences in cancer cell cycle velocity are important in the resistance toward inhibition of inosine monophosphate dehydrogenase (IMPDH) by mycophenolic acid (MPA). In short-term experiments, MPA treatment of fast-growing cancer cells effectively elicited G0/G1 arrest and provoked apoptosis, thus inhibiting cell proliferation and colony formation. Forced expression of a mutated IMPDH2, lacking a binding site for MPA but retaining enzymatic activity, resulted in complete resistance of cancer cells to MPA. In nude mice subcutaneously engrafted with HeLa cells, MPA moderately delayed tumor formation by inhibiting cell proliferation and inducing apoptosis. Importantly, we developed a lentiviral vector–based Tet-on label-retaining system that enables to identify, isolate and functionally characterize slow-cycling or so-called label-retaining cells (LRCs) in vitro and in vivo. We surprisingly found the presence of LRCs in fast-growing tumors. LRCs were superior in colony formation, tumor initiation and resistance to MPA as compared with fast-cycling cells. Thus, the slow-cycling compartment of cancer seems predominantly responsible for resistance to MPA. PMID:26467706

  2. Achieving Success under Pressure in the Conservation of Intensely Used Coastal Areas

    Directory of Open Access Journals (Sweden)

    Fiorenza Micheli

    2013-12-01

    Full Text Available Understanding how biological conservation and socioeconomic development can be harmonized in social-ecological systems is at the core of sustainability science. We present the case of a Mediterranean marine protected area (MPA, the Tavolara-Punta Coda Cavallo MPA, that exhibits high ecological performance under intense pressure from fishing, tourism, and coastal development. This case study illustrates how socioeconomic development and significant conservation benefits can coexist, even in a challenging context. Based on this case study, we present a framework for what elements and interactions have determined the high ecological performance of this MPA, and highlight the key leverages that have enabled ecosystem recovery. In particular, the most critical elements underlying high performance were sufficient leadership and knowledge to identify a conservation vision and to catalyze some key actors in the implementation of this vision. Thus, success was ultimately determined by the ability of the leadership of the MPA to devise and implement an effective strategy, with the support and participation of key actors that were external to the MPA organization. The insights from this case study may be applicable to improving MPA management in other systems with similar characteristics, including high human pressures and the presence of an MPA authority.

  3. Medroxyprogesterone acetate-treated human, primary endometrial epithelial cells reveal unique gene expression signature linked to innate immunity and HIV-1 susceptibility.

    Science.gov (United States)

    Woods, Matthew W; Zahoor, Muhammad Atif; Dizzell, Sara; Verschoor, Chris P; Kaushic, Charu

    2018-01-01

    Medroxyprogesterone acetate (MPA), a progestin-based hormonal contraceptive designed to mimic progesterone, has been linked to increased human immunodeficiency virus (HIV-1) susceptibility. Genital epithelial cells (GECs) form the mucosal lining of the female genital tract (FGT) and provide the first line of protection against HIV-1. The impact of endogenous sex hormones or MPA on the gene expression profile of GECs has not been comprehensively documented. Using microarray analysis, we characterized the transcriptional profile of primary endometrial epithelial cells grown in physiological levels of E2, P4, and MPA. Each hormone treatment altered the gene expression profile of GECs in a unique manner. Interestingly, although MPA is a progestogen, the gene expression profile induced by it was distinct from P4. MPA increased gene expression of genes related to inflammation and cholesterol synthesis linked to innate immunity and HIV-1 susceptibility. The analysis of gene expression profiles provides insights into the effects of sex hormones and MPA on GECs and allows us to posit possible mechanisms of the MPA-mediated increase in HIV-1 acquisition. © 2017 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  4. Establishment and Implementation of the Balingasay Marine Protected Area: A Community-Based Approach

    Directory of Open Access Journals (Sweden)

    Severino Salmo III

    2000-12-01

    Full Text Available A community-based approach in the establishment and implementation of a marine protected area (MPA in Balingasay, Bolinao, Pangasinan is presented. The factors necessary to facilitate the successful establishment and implementation of a community-managed MPA include heightening of environmental awareness, community mobilization, and legal/institutional and financial assistance. A heightened environmental awareness encouraged the community to undertake resource management action. The formation of a people’s organization, SAMMABAL (Samahan ng mga Mangingisda at Mamamayan ng Balingasay, was crucial in assessing environmental problems (e.g., overfishing and identifying the establishment of an MPA as a management tool to address the problem. SAMMABAL was also instrumental in eliciting community support for the issuance of a municipal ordinance in the establishment of the MPA. Subsequently, the organization initiated the patrolling of the MPA. Institutions involved in the community-based management of the MPA also included the multi-sectoral council (BRMC – Balingasay Resource Management Council and representatives from the barangay council and the municipal government. This institutional arrangement has proven to be very resilient, indicating a high probability of sustaining its successes despite some obstacles and shortcomings. Clear delineation of the role and functions of the institutions and the stakeholders was essential in advancing the initiative. This case study will draw on the lessons from the experience of a four-year community-managed MPA.

  5. Stress analysis of a rupture disk

    International Nuclear Information System (INIS)

    Werne, R.W.

    1975-04-01

    The results of an elastic stress analysis of the rupture disk for an internal pressure of 45.5 MPa (6600 psi) indicate that the maximum von Mises stresses occur in the membrane and are on the order of 483 to 690 MPa (70,000 psi). This far exceeds the yield of the membrane material of 207 MPa (30,000 psi). These high stresses are expected since the membrane is designed to burst at that design pressure. The von Mises stresses in the rest of the body are less than 138 MPa (20,000 psi). An elastic-plastic analysis of the membrane alone subjected to the 45.5 MPa (6600 psi) pressure indicates that it becomes plastically unstable, i.e., it continues to deform under constant load. A second load case with a constant 6.9 MPa (1000 psi) pressure throughout the entire body (i.e., after release of pressure by burst of the membrane) was analyzed. The results indicate that the elastic von Mises stresses are less than 26.7 MPa (3880 psi) throughout the body. (U.S.)

  6. Effects of high hydrostatic pressure on the functional and rheological properties of the protein fraction extracted from pine nuts.

    Science.gov (United States)

    Cao, Baiying; Fang, Li; Liu, Chunlei; Min, Weihong; Liu, Jingsheng

    2018-01-01

    High hydrostatic pressure treatments could increase the protein solubility (200 MPa), water holding capacity (400 MPa), and oil holding capacity (400 MPa) of pine nuts protein fractions, respectively. The exposed sufhydryl content for albumin was highest at 100 MPa while for other fractions it was 400 MPa, contrary for total sufhydryl content-generally it was at 100 MPa, except glutelin (400 MPa). Pine nuts protein fractions demonstrated the typical behavior of weak gels (G' > G″). After the treatments of high hydrostatic pressure the specific surface area of pine nuts protein particle was increased upon pressure, and the surface of protein became rough which increased the particle size. The functional groups of protein were found to be unchanged, but the characteristic peaks of pine nuts protein moved to a low-band displacement and the value of peaks was amplified accordingly to the pressure. The high hydrostatic pressure treatments were found to improve the functional properties of pine nuts protein isolates by enhancing the heat-induced gel strength of pine nuts protein isolates which make proteins more stretchable. These results suggest that high hydrostatic pressure treatments can increase the functional properties and alter the rheological properties of pine nuts protein fractions which will broaden its applications in food industry.

  7. Facial Recognition of Happiness Is Impaired in Musicians with High Music Performance Anxiety.

    Science.gov (United States)

    Sabino, Alini Daniéli Viana; Camargo, Cristielli M; Chagas, Marcos Hortes N; Osório, Flávia L

    2018-01-01

    Music performance anxiety (MPA) can be defined as a lasting and intense apprehension connected with musical performance in public. Studies suggest that MPA can be regarded as a subtype of social anxiety. Since individuals with social anxiety have deficits in the recognition of facial emotion, we hypothesized that musicians with high levels of MPA would share similar impairments. The aim of this study was to compare parameters of facial emotion recognition (FER) between musicians with high and low MPA. 150 amateur and professional musicians with different musical backgrounds were assessed in respect to their level of MPA and completed a dynamic FER task. The outcomes investigated were accuracy, response time, emotional intensity, and response bias. Musicians with high MPA were less accurate in the recognition of happiness ( p  = 0.04; d  = 0.34), had increased response bias toward fear ( p  = 0.03), and increased response time to facial emotions as a whole ( p  = 0.02; d  = 0.39). Musicians with high MPA displayed FER deficits that were independent of general anxiety levels and possibly of general cognitive capacity. These deficits may favor the maintenance and exacerbation of experiences of anxiety during public performance, since cues of approval, satisfaction, and encouragement are not adequately recognized.

  8. Destruction of nitrates, organics, and ferrocyanides by hydrothermal processing

    International Nuclear Information System (INIS)

    Robinson, J.M.; Foy, B.R.; Dell'Orco, P.C.; Anderson, G.; Archuleta, F.; Atencio, J.; Breshears, D.; Brewer, R.; Eaton, H.; McFarland, R.; McInroy, R.; Reynolds, T.; Sedillo, M.; Wilmanns, E.; Buelow, S.J.

    1993-01-01

    This work targets the remediation of the aqueous mixed wastes stored in the underground tanks at the Department of Energy site in Hanford, Washington via hydrothermal processing. The feasibility of destroying the nitrate, organic, and ferrocyanide components of the wastes under supercritical and near critical conditions (623 degree K to 873 degree K, 22.1 MPa to 103.4 MPa) is addressed. A novel method was developed for determining the solubility of nitrate salts in supercritical water solutions at pressures ranging from 24.8 MPa to 30.3 MPa (3600 psi to 4400 psi) and temperatures from 723 degree K to 798 degree K. Sodium nitrate solubilities ranged from 293 mg/kg at 24.8 MPa and 798 degree K to 1963 mg/kg at 30.3 MPa and 723 degree K. Solubility was found to vary directly with pressure, and inversely with temperature. An empirical relationship was developed for the estimation of sodium nitrate solubility at water densities between 0.08 and 0.16 kg/L and temperatures between 723 degree K and 798 degree K. A small volume batch reactor equipped with optical diagnostics was used to monitor the phase behavior of a diluted variant of a tank 101-SY simulant. Preliminary results suggest that a single phase is formed at 83 MPa at 773 degree K

  9. Effects of high pressure freezing (HPF) on denaturation of natural actomyosin extracted from prawn (Metapenaeus ensis).

    Science.gov (United States)

    Cheng, Lina; Sun, Da-Wen; Zhu, Zhiwei; Zhang, Zhihang

    2017-08-15

    Effects of protein denaturation caused by high pressure freezing, involving Pressure-Factors (pressure, time) and Freezing-Factors (temperature, phase transition, recrystallization, ice crystal types), are complicated. In the current study, the conformation and functional changes of natural actomyosin (NAM) under pressure assisted freezing (PAF, 100,150,300,400,500MPa P -20°C/25min ), pressure shift freezing (PSF, 200MPa P -20°C/25min ), and immersion freezing ( 0.1MPa P -20°C/5min ) after pressure was released to 0.1MPa, as compared to normal immersion freezing process (IF, 0.1MPa P -20°C/30min ). Results indicated that PSF ( 200MPa P -20°C/30min ) could reduce the denaturation of frozen NAM and a pressure of 300MPa was the critical point to induce such a denaturation. During the periods of B→D in PSF or B→C→D in PAF, the generation and growth of ice crystals played an important role on changing the secondary and tertiary structure of the treated NAM. Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. Psychological intervention reduces self-reported performance anxiety in high school music students

    Directory of Open Access Journals (Sweden)

    Alice M Braden

    2015-03-01

    Full Text Available Music performance anxiety (MPA can be distressing for many young people studying music, and may negatively impact upon their ability to cope with the demands and stressors of music education. It can also lead young people to give up music or to develop unhealthy coping habits in their adult music careers. Minimal research has examined the effectiveness of psychological programs to address MPA in young musicians. Sixty-two adolescents were pseudo-randomised to a cognitive behavioural (CB group-delivered intervention or a waitlist condition. The intervention consisted of psychoeducation, cognitive restructuring and relaxation techniques, identification of strengths, goal-setting, imagery and visualisation techniques to support three solo performances in front of judges. Significant reductions in self-rated MPA were found in both groups following the intervention and compared to their baseline MPA. This reduction was maintained at two-months follow-up. There appeared to be inconsistent effects of the intervention upon judge-rated MPA, however the presence of floor effects precluded meaningful reductions in MPA. There appeared to be no effect of the intervention upon judge-rated performance quality. This study highlights the potential for group-based CB programs to be delivered within school music curricula to help young musicians develop skills to overcome the often debilitating effects of MPA.

  11. Human norovirus surrogate reduction in milk and juice blends by high pressure homogenization.

    Science.gov (United States)

    Horm, Katie Marie; Harte, Federico Miguel; D'Souza, Doris Helen

    2012-11-01

    Novel processing technologies such as high pressure homogenization (HPH) for the inactivation of foodborne viruses in fluids that retain nutritional attributes are in high demand. The objectives of this research were (i) to determine the effects of HPH alone or with an emulsifier (lecithin) on human norovirus surrogates-murine norovirus (MNV-1) and feline calicivirus (FCV-F9)-in skim milk and orange juice, and (ii) to determine HPH effects on FCV-F9 and MNV-1 in orange and pomegranate juice blends. Experiments were conducted in duplicate at 0, 100, 200, 250, and 300 MPa for PFU/ml at 300 and 250 MPa, respectively, and ≥4- and ∼1-log PFU/ml reductions were obtained in orange juice at 300 and 250 MPa, respectively. In orange juice or milk combined with lecithin, FCV-F9 was reduced to nondetectable levels at 300 MPa, and by 1.77 and 0.78 log PFU/ml at 250 MPa. MNV-1 in milk was reduced by ∼1.3 log PFU/ml only at 300 MPa, and by ∼0.8 and ∼0.4 log PFU/ml in orange juice at 300 and 250 MPa, respectively. MNV-1 in milk or orange juice containing lecithin at 300 MPa showed 1.32- and 2.5-log PFU/ml reductions, respectively. In the pomegranate-orange juice blend, FCV-F9 was completely reduced, and MNV-1 was reduced by 1.04 and 1.78 log PFU/ml at 250 and 300 MPa, respectively. These results show that HPH has potential for commercial use to inactivate foodborne virus surrogates in juices.

  12. Effect of high hydrostatic pressure on mycelial development, spore viability and enzyme activity of Penicillium Roqueforti.

    Science.gov (United States)

    Martínez-Rodríguez, Yamile; Acosta-Muñiz, Carlos; Olivas, Guadalupe I; Guerrero-Beltrán, José; Rodrigo-Aliaga, Dolores; Mujica-Paz, Hugo; Welti-Chanes, Jorge; Sepulveda, David R

    2014-01-03

    This study investigated the effect of high hydrostatic pressure treatments on mycelial development, spore viability, and total proteolytic and lipolytic activity of Penicillium roqueforti PV-LYO 10 D. Fungus growing in liquid medium was pressure-treated at 300, 400, and 500 MPa for 10 min at 20°C following seven days of incubation at 25°C and analyzed periodically up to day 9 after treatments to evaluate the effect on fungal growth. Mycelial mass of P. roqueforti was significantly affected at all pressure treatments evaluated, being 15.48%, 22.28%, 30.03%, and 12.53% lower than controls on day 1, 3, 6, and 9 after 300 MPa treatment, respectively. In a similar way, at 400 and 500 MPa, mycelial mass was 31.08% and 60.34% lower than controls one day after treatments and 49.74% and 80.85% lower on day 9, respectively. The viability of P. roqueforti spores decreased by 36.53% at 300 MPa, and complete inactivation took place at ≥400 MPa from an initial count of 7 log cfu/mL. Total proteolytic activity was not significantly affected at 300 MPa but was reduced by 18.22% at 400 MPa and by 43.18% at 500 MPa. Total lipolytic activity also decreased as the intensity of the pressure treatments increased. 21.69%, 39.12%, and 56.26% activity reductions were observed when treatments of 300, 400 and 500 MPa were applied, respectively. The results from this study show that pressure treatments are able to control growth, inactivate spores, and alter enzyme activity of P. roqueforti, which could be of interest in extending the shelf-life of blue-veined cheeses and other food products. © 2013.

  13. Fatigue behavior of rolled and forged tungsten at 25°, 280° and 480 °C

    International Nuclear Information System (INIS)

    Habainy, J.; Iyengar, S.; Lee, Y.; Dai, Y.

    2015-01-01

    Pure tungsten has been chosen as the target material at the European Spallation Source facility in Lund. Calculations show that the target temperature can reach 500 °C momentarily during the spallation process, leading to thermal fatigue. Target life estimations require fatigue data at different temperatures and this work focuses on generating such data for pure, unirradiated, rolled and forged tungsten in the range 25°–480 °C. For specimens oriented in the rolling direction, tensile tests at room temperature indicated Young's modulus values in the range 320–390 GPa, low levels of plasticity (<0.23%) and UTS values in the range 397 MPa (unpolished) and 705 MPa (Polished). UTS for forged specimens were around 500 MPa. Stress-controlled fatigue tests were conducted in the tensile regime, with a runout limit of 2 × 10"6 cycles. At 25 °C, unpolished specimens had fatigue limits of 150 MPa (rolling and transverse direction), and 175 MPa (forged). For polished specimens in the rolling direction, fatigue limits were higher at 237.5 MPa (25 °C) and 252.5 MPa (280 °C). The forged specimens showed slightly better fatigue properties and marginal cyclic hardening at 480 °C. - Highlights: • Stress & strain-controlled fatigue tests on pure tungsten at 25°, 280° & 480 °C. • Unirradiated, rolled and forged specimens in polished and unpolished condition. • Min. tensile strength (MPa): 397 (25 °C), 472 (280 °C) and 363 (480 °C). • Min. endurance limit (MPa): 137.5 (25 °C), 250 (280 °C) and 150 (480 °C). • Marginal cyclic hardening observed at 480 °C.

  14. Effect of tamoxifen, methoxyprogesterone acetate and combined treatment on cellular proliferation and apoptosis in SKOV3/DDP cells via the regulation of vascular endothelial growth factor.

    Science.gov (United States)

    Wen, Lv; Hong, Ding; Yanyin, Wu; Mingyue, Zhang; Baohua, Li

    2013-05-01

    The aim of this study was to investigate the effect of tamoxifen (TAM), methoxyprogesterone acetate (MPA) and their combined treatment on cisplatin-resistant ovarian cancer SKOV3/DDP cells, as well as the potential mechanisms. MTT assay was used to investigate the effect of different concentrations (0.01, 0.1, 1, 10 and 100 μM) of TAM, MPA and their combined treatment on the proliferation of cisplatin-resistant ovarian cancer SKOV3/DDP cells. Flow cytometry was employed to analyze the cell cycle and apoptosis rate of SKOV3/DDP cells treated with medium concentration (10 μM) of TAM, MPA and their combined treatment. Change in the protein level of vascular endothelial growth factor (VEGF) in response to drug treatments was measured using Western-blot. The proliferation of SKOV3/DDP cells was inhibited by 1, 10 and 100 μM of TAM or MPA in a dose-dependent manner. Compared to the control group, 10 μM TAM could significantly arrest SKOV3/DDP cells in the G0/G1 stage and induce apoptosis (p < 0.01). However, 10 μM MPA only promoted cell apoptosis, while exhibited little effect on the cell cycle. We further found that 10 μM TAM could remarkably reduce the protein expression of VEGF, while 10 μM MPA only induce a slight reduction. Strikingly, the combined treatment of TAM and MPA exhibited additive effect on the proliferation, cell cycle, apoptosis rate and VEGF expression of SKOV3/DDP cells. We found that TAM, MPA and their combined treatment exhibited significant inhibitory effect on the cisplatin-resistant ovarian cancer SKOV3/DDP cells. Hence, TAM and MPA could be potential cytotoxic drugs to treat cisplatin-resistant patients with advanced ovarian cancer.

  15. Evaluation of digital breast tomosynthesis reconstruction algorithms using synchrotron radiation in standard geometry

    International Nuclear Information System (INIS)

    Bliznakova, K.; Kolitsi, Z.; Speller, R. D.; Horrocks, J. A.; Tromba, G.; Pallikarakis, N.

    2010-01-01

    Purpose: In this article, the image quality of reconstructed volumes by four algorithms for digital tomosynthesis, applied in the case of breast, is investigated using synchrotron radiation. Methods: An angular data set of 21 images of a complex phantom with heterogeneous tissue-mimicking background was obtained using the SYRMEP beamline at ELETTRA Synchrotron Light Laboratory, Trieste, Italy. The irradiated part was reconstructed using the multiple projection algorithm (MPA) and the filtered backprojection with ramp followed by hamming windows (FBR-RH) and filtered backprojection with ramp (FBP-R). Additionally, an algorithm for reducing the noise in reconstructed planes based on noise mask subtraction from the planes of the originally reconstructed volume using MPA (MPA-NM) has been further developed. The reconstruction techniques were evaluated in terms of calculations and comparison of the contrast-to-noise ratio (CNR) and artifact spread function. Results: It was found that the MPA-NM resulted in higher CNR, comparable with the CNR of FBP-RH for high contrast details. Low contrast objects are well visualized and characterized by high CNR using the simple MPA and the MPA-NM. In addition, the image quality of the reconstructed features in terms of CNR and visual appearance as a function of the initial number of projection images and the reconstruction arc was carried out. Slices reconstructed with more input projection images result in less reconstruction artifacts and higher detail CNR, while those reconstructed from projection images acquired in reduced angular range causes pronounced streak artifacts. Conclusions: Of the reconstruction algorithms implemented, the MPA-NM and MPA are a good choice for detecting low contrast objects, while the FBP-RH, FBP-R, and MPA-NM provide high CNR and well outlined edges in case of microcalcifications.

  16. Simultaneous determination of mycophenolate mofetil and its active metabolite, mycophenolic acid, by differential pulse voltammetry using multi-walled carbon nanotubes modified glassy carbon electrode

    Energy Technology Data Exchange (ETDEWEB)

    Madrakian, Tayyebeh, E-mail: madrakian@basu.ac.ir; Soleimani, Mohammad; Afkhami, Abbas

    2014-09-01

    A highly sensitive electrochemical sensor for the simultaneous determination of mycophenolate mofetil (MPM) and mycophenolic acid (MPA) was fabricated by multi-walled carbon nanotubes modified glassy carbon electrode (MWCNTs/GCE). The electrochemical behavior of these two drugs was studied at the modified electrode using cyclic voltammetry and adsorptive differential pulse voltammetry. MPM and MPA were oxidized at the GCE during an irreversible process. DPV analysis showed two oxidation peaks at 0.87 V and 1.1 V vs. Ag/AgCl for MPM and an oxidation peak at 0.87 V vs. Ag/AgCl for MPA in phosphate buffer solution of pH 5.0. The MWCNTs/GCE displayed excellent electrochemical activities toward oxidation of MPM and MPA relative to the bare GCE. The experimental design algorithm was used for optimization of DPV parameters. The electrode represents linear responses in the range 5.0 × 10{sup −6} to 1.6 × 10{sup −4} mol L{sup −1} and 2.5 × 10{sup −6} mol L{sup −1} to 6.0 × 10{sup −5} mol L{sup −1} for MPM and MPA, respectively. The detection limit was found to be 9.0 × 10{sup −7} mol L{sup −1} and 4.0 × 10{sup −7} mol L{sup −1} for MPM and MPA, respectively. The modified electrode showed a good sensitivity and stability. It was successfully applied to the simultaneous determination of MPM and MPA in plasma and urine samples. - Highlights: • A new modified electrochemical sensor was constructed and used. • Multiwalled carbon nanotubes were used as the modifiers. • MPM and MPA were measured simultaneously at the low levels. • The sensor was used to the determination of MPA and MPM in real samples.

  17. Antiandrogenic actions of medroxyprogesterone acetate on epithelial cells within normal human breast tissues cultured ex vivo.

    Science.gov (United States)

    Ochnik, Aleksandra M; Moore, Nicole L; Jankovic-Karasoulos, Tanja; Bianco-Miotto, Tina; Ryan, Natalie K; Thomas, Mervyn R; Birrell, Stephen N; Butler, Lisa M; Tilley, Wayne D; Hickey, Theresa E

    2014-01-01

    Medroxyprogesterone acetate (MPA), a component of combined estrogen-progestin therapy (EPT), has been associated with increased breast cancer risk in EPT users. MPA can bind to the androgen receptor (AR), and AR signaling inhibits cell growth in breast tissues. Therefore, the aim of this study was to investigate the potential of MPA to disrupt AR signaling in an ex vivo culture model of normal human breast tissue. Histologically normal breast tissues from women undergoing breast surgical operation were cultured in the presence or in the absence of the native AR ligand 5α-dihydrotestosterone (DHT), MPA, or the AR antagonist bicalutamide. Ki67, bromodeoxyuridine, B-cell CLL/lymphoma 2 (BCL2), AR, estrogen receptor α, and progesterone receptor were detected by immunohistochemistry. DHT inhibited the proliferation of breast epithelial cells in an AR-dependent manner within tissues from postmenopausal women, and MPA significantly antagonized this androgenic effect. These hormonal responses were not commonly observed in cultured tissues from premenopausal women. In tissues from postmenopausal women, DHT either induced or repressed BCL2 expression, and the antiandrogenic effect of MPA on BCL2 was variable. MPA significantly opposed the positive effect of DHT on AR stabilization, but these hormones had no significant effect on estrogen receptor α or progesterone receptor levels. In a subset of postmenopausal women, MPA exerts an antiandrogenic effect on breast epithelial cells that is associated with increased proliferation and destabilization of AR protein. This activity may contribute mechanistically to the increased risk of breast cancer in women taking MPA-containing EPT.

  18. Spatial, socio-economic, and ecological implications of incorporating minimum size constraints in marine protected area network design.

    Science.gov (United States)

    Metcalfe, Kristian; Vaughan, Gregory; Vaz, Sandrine; Smith, Robert J

    2015-12-01

    Marine protected areas (MPAs) are the cornerstone of most marine conservation strategies, but the effectiveness of each one partly depends on its size and distance to other MPAs in a network. Despite this, current recommendations on ideal MPA size and spacing vary widely, and data are lacking on how these constraints might influence the overall spatial characteristics, socio-economic impacts, and connectivity of the resultant MPA networks. To address this problem, we tested the impact of applying different MPA size constraints in English waters. We used the Marxan spatial prioritization software to identify a network of MPAs that met conservation feature targets, whilst minimizing impacts on fisheries; modified the Marxan outputs with the MinPatch software to ensure each MPA met a minimum size; and used existing data on the dispersal distances of a range of species found in English waters to investigate the likely impacts of such spatial constraints on the region's biodiversity. Increasing MPA size had little effect on total network area or the location of priority areas, but as MPA size increased, fishing opportunity cost to stakeholders increased. In addition, as MPA size increased, the number of closely connected sets of MPAs in networks and the average distance between neighboring MPAs decreased, which consequently increased the proportion of the planning region that was isolated from all MPAs. These results suggest networks containing large MPAs would be more viable for the majority of the region's species that have small dispersal distances, but dispersal between MPA sets and spill-over of individuals into unprotected areas would be reduced. These findings highlight the importance of testing the impact of applying different MPA size constraints because there are clear trade-offs that result from the interaction of size, number, and distribution of MPAs in a network. © 2015 Society for Conservation Biology.

  19. Microstructural study in a Fe–Ni-base superalloy during creep–rupture at intermediate temperature

    Energy Technology Data Exchange (ETDEWEB)

    Yan, Jingbo [High Temperature Materials Unit, National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Xi’an Thermal Power Research Institute, Xingqing Road 136, Xi’an, Shaanxi 710032 (China); Gu, Yuefeng, E-mail: Gu.yuefeng@nims.go.jp [High Temperature Materials Unit, National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Sun, Fei; Michinari, Yuyama [High Temperature Materials Unit, National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Zhong, Zhihong [Departmant of Materials Science and Engineering, Hefei University of Technology, Hefei, Anhui 230009 (China); Yuan, Yong; Lu, Jintao [Xi’an Thermal Power Research Institute, Xingqing Road 136, Xi’an, Shaanxi 710032 (China)

    2015-07-15

    Creep–rupture behavior of a Fe–Ni-base alloy crept under various conditions has been studied using Electron Backscatter Diffraction (EBSD) and Transmission electron microscopy (TEM). The results indicate that grain orientation did not change after the alloy crept at 700 °C/300 MPa and changed greatly crept at 700 °C/200 MPa. The recrystallization texture near rupture–fracture surface was observed after the alloy crept at 750 °C/150 MPa. A better creep performance was found in the samples with the occurrence of grain rotation dependence of the microstructure and the grain store energy.

  20. Change of residual stresses during plastic deformation under uniaxial tension test; Variacion de las tensiones residuales con la deformacion plastica en el ensayo de traccion

    Energy Technology Data Exchange (ETDEWEB)

    Benito, J. A.; Jorba, J.; Roca, A.

    2001-07-01

    Hang of longitudinal and transverse residual stresses was studied by X Ray diffraction method as the applied plastic deformation, measured as A% was increased in a standard tension test. The starting material, hot rolling Armco iron, has values close to 0 MPa in longitudinal direction. But it reaches 600 MPa with only A=1,5%, this value remains constant until necking is produced. In transverse direction the stating values are 300 MPa, changes are small and residual stresses remain compressive until the end of tension test. In addition, studies of the changes of residual stresses with time and with misalignment between incident X Ray and drawing direction are presented. (Author) 5 refs.

  1. Collaboration between research institutions and Marine Protected Area contributes to Posidonia oceanica conservation: The Egadi Island’s experiment

    International Nuclear Information System (INIS)

    Cocito, Silvia; Lombardi, Chiara; Peirano, Andrea; Donati, Stefano; Patti Genovese, Pietro; Ponzè, Niccolo

    2015-01-01

    Preliminary results on the collaboration between the ENEA’s Marine Environment Research Center and the Egadi Islands’ Marine Protected Area (MPA), aimed to evaluate effectiveness of artificial reefs in limiting the impact of trawling on Posidonia oceanica meadow at Favignana Island, are reported. The methods and parameters chosen for monitoring showed their reliability in training non-experienced personnel for data collection within the MPA. The proposed monitoring approach is of great value to the MPA interested in both gathering basic and long-term data on the health status of protected habitats and acquiring baseline information useful for the evaluation of protection and conservation actions. [it

  2. [High-dosed gestagen therapy of the metastatic mammary carcinoma (author's transl)].

    Science.gov (United States)

    Firusian, N; Becher, R

    1981-12-01

    Thirty patients with histologically proven metastatic mammary carcinoma were treated, after exhaustion of hormonal and cytostatic therapeutic means, with high-dosed medroxyprogesterone acetate (MPA) during a ten-day induction phase with 1000 mg MPAi.m. per day and then with 600 mg oral MPA per day. In eleven patients a complete or partial remission was achieved. The median period of remission comprised ten months. A positive relationship was found between the response to high-dosed MPA therapy and the length of free intervals. Side effects were tolerable.

  3. Differential proteome analysis of human embryonic kidney cell line (HEK-293 following mycophenolic acid treatment

    Directory of Open Access Journals (Sweden)

    Rahman Hazir

    2011-09-01

    Full Text Available Abstract Background Mycophenolic acid (MPA is widely used as a post transplantation medicine to prevent acute organ rejection. In the present study we used proteomics approach to identify proteome alterations in human embryonic kidney cells (HEK-293 after treatment with therapeutic dose of MPA. Following 72 hours MPA treatment, total protein lysates were prepared, resolved by two dimensional gel electrophoresis and differentially expressed proteins were identified by QTOF-MS/MS analysis. Expressional regulations of selected proteins were further validated by real time PCR and Western blotting. Results The proliferation assay demonstrated that therapeutic MPA concentration causes a dose dependent inhibition of HEK-293 cell proliferation. A significant apoptosis was observed after MPA treatment, as revealed by caspase 3 activity. Proteome analysis showed a total of 12 protein spots exhibiting differential expression after incubation with MPA, of which 7 proteins (complement component 1 Q subcomponent-binding protein, electron transfer flavoprotein subunit beta, cytochrome b-c1 complex subunit, peroxiredoxin 1, thioredoxin domain-containing protein 12, myosin regulatory light chain 2, and profilin 1 showed significant increase in their expression. The expression of 5 proteins (protein SET, stathmin, 40S ribosomal protein S12, histone H2B type 1 A, and histone H2B type 1-C/E/F/G/I were down-regulated. MPA mainly altered the proteins associated with the cytoskeleton (26%, chromatin structure/dynamics (17% and energy production/conversion (17%. Both real time PCR and Western blotting confirmed the regulation of myosin regulatory light chain 2 and peroxiredoxin 1 by MPA treatment. Furthermore, HT-29 cells treated with MPA and total kidney cell lysate from MMF treated rats showed similar increased expression of myosin regulatory light chain 2. Conclusion The emerging use of MPA in diverse pathophysiological conditions demands in-depth studies to

  4. Equilibrium radionuclide ventriculography: Comparison with echo-ventriculography and digital subtraction angiocardiography, evaluation of multiparameters

    Energy Technology Data Exchange (ETDEWEB)

    Hoer, G; Standke, R; Klepzig, H Jr; Maul, F D; Tuengerthal, S; Tezak, S; Reifarth, N; Kanemoto, N; Happ, J; Baum, R P

    1986-09-01

    Subsequent to the discussion of technical prerequisites (fully-automated, reproducible multiparameter-analysis (MPA), rest, exercise) which is followed by remarks concerning the pathophysiology of ischemic left ventricular functional disorders in diastole and systole, the following points are considered: 1) comparative results of RNV, cineventriculoangiography, echo-ventriculography and intraveneous digital subtraction angiocardiography; 2) 'normal' values of RNV in MPA; 3) heart and pulmonary diseases (coronary artery disease with sensitivity and specificity of MPA), chronic obstructive pulmonary disease, chronic aortic insufficiency, hypertension; 4) summary of, and prospects for future potentialities (software, clinical indications).

  5. Effect of Mild Water Stress and Enhanced Ultraviolet-B Irradiation on Leaf Growth of Rumex obtusifolius L. and Rumex patientia L. (Polygonaceae).

    OpenAIRE

    Holman, Steven R.

    1981-01-01

    Leaves of Rumex obtusifolius L. and R. patientia L.were exposed to combinations of mild water stress and enhanced ultraviolet-B irradiation during their ontogeny. Two UV-B treatments (enhanced UV-B and control) and three water stress treatments (-0.0 MPa, -0.2 MPa and -0.4 MPa rooting medium matric potentials) were employed. The impact of the stress interaction was assessed on the basis of changes in leaf area, average adaxial epidermal cell size, and total number of adaxial epidermal cells p...

  6. Welding wires for high-tensile steels

    International Nuclear Information System (INIS)

    Laz'ko, V.E.; Starova, L.L.; Koval'chuk, V.G.; Maksimovich, T.L.; Labzina, I.E.; Yadrov, V.M.

    1993-01-01

    Strength of welded joints in arc welding of high-tensile steels of mean and high thickness by welding wires is equal to approximately 1300 MPa in thermohardened state and approximately 600 MPa without heat treatment. Sv-15Kh2NMTsRA-VI (EhK44-VI) -Sv-30Kh2NMTsRA-VI (EkK47-VI) welding wires are suggested for welding of medium-carbon alloyed steels. These wires provide monotonous growth of ultimate strength of weld metal in 1250-1900 MPa range with increase of C content in heat-treated state

  7. Development and implementation of state variable based user materials in computational plasticity

    CSIR Research Space (South Africa)

    Jansen van Rensburg, Gerhardus J

    2016-09-01

    Full Text Available ) /kB. . . . . . . . 75 3.8 Voce formulation initial hardening θ0 = 1574.83MPa in (a) and (b) response compared to the experimental data. . . . . . . . . . . . . . . 76 3.9 Hyperbolic tangent formulation initial hardening (a) and (b) response compared... to the experimental data using a = 2 and θ0 = 4001.02MPa. . 76 3.10 Power law formulation initial hardening (a) and (b) response compared to the experimental data using a = 2 and θ0 = 2566.7MPa. . . . . . . . 77 3.11 (a) Initial and (b) optimal fit for the Voce...

  8. Studies on Screening of Maize (Zea mays L.) Hybrids under Drought Stress Conditions

    OpenAIRE

    Zahoor Ahmad

    2015-01-01

    Drought is one of the most serious problems posing a grave threat to cereals production including maize. Two experiments (lab and wire house) were conducted to screen out the most tolerant and most sensitive maize hybrids (7386, 6525, Hycorn, 9696, 32B33, 3672, MMRI and 31P41) under artificial imposing drought stress by PEG-6000 and under water stress applied after seedling emergence. In first experiment five water stress levels such as zero (control), -0.2 MPa, -0.4 MPa, -0.6 MPa, and -0.8 M...

  9. Undervisningsplan for «Master of Public Administration» : Midt-skandinavisk kompetanse- og lederutdanningsprogram

    OpenAIRE

    Haugstveit, Yngve; Norell, P.O.

    2007-01-01

    Norsk: I denne rapporten presenters undervisningsplanen for det første MPA program tilrettelagt for Indre Skandinavia. Programmet startet i mai 2000 og avsluttet i juni 2002. Senere har MPA II har fullført sitt program og MPA III er i gang. Dette er et norsk-svensk lederutdanningsprogram med innretning mot offentlig sektor, og det er godkjent som en master grad på 90 ECTS. Studiet tilbys som en felles grad mellom Karlstads universitet og Høgskolen i Hedmark. I rapporten pres...

  10. Stress measurements in the Stripa granite. Technical project report No. 4

    International Nuclear Information System (INIS)

    Carlsson, H.

    1978-08-01

    Rock stress measurements at the 348 m level of the Stripa Mine have been carried out with the Leeman tri-axial equipment. The largest principal stress is found to be 20.0 MPa and directed parallel with the strike of the contact between the granite and the orebody. The intermediate principal stress is 11.4 MPa and directed almost horizontal and perpendicular to the contact. The minor principal stress has a magnitude of 5.4 MPa. The deduced vertical stress is approximately of the same value as can be theoretically calculated

  11. Internal pressure and solubility parameter as a function of pressure

    DEFF Research Database (Denmark)

    Verdier, Sylvain Charles Roland; Andersen, Simon Ivar

    2005-01-01

    The main goal of this work was to measure the solubility parameter of a complex mixture, such as a crude oil, especially as a function of pressure. Thus, its definition is explained, as well as the main approximations generally used in literature. Then, the internal pressure is investigated, since...... pure compounds (four hydrocarbons and I alcohol) were investigated at 303.15 K and up to 30 MPa, as well as a dead crude oil. The "physical" solubility parameter is slightly increasing with pressure (up to 0.8 MPa1/2 for cyclohexane) and, at 0.1 MPa, the difference with literature data is less than 1...

  12. 77 FR 23464 - Updates to List of National System of Marine Protected Areas (MPAs)

    Science.gov (United States)

    2012-04-19

    ... electronic copy of the List of National System MPAs is available for download at http://www.mpa.gov.... Saint Francis Exempt Site French Van Gilder Exempt Site Vineyard Sound Lightship Exempt Site Puerto Rico...

  13. The ANCA Vasculitis Questionnaire (AAV-PRO©)

    Science.gov (United States)

    2017-05-01

    Eosinophilic Granulomatosis With Polyangiitis (Churg-Strauss) (EGPA); Churg-Strauss Syndrome (CSS); Granulomatosis With Polyangiitis (Wegener's) (GPA); Wegener Granulomatosis (WG); Microscopic Polyangiitis (MPA); ANCA-Associated Vasculitis (AAV); Vasculitis

  14. Clinical Transcriptomics in Systemic Vasculitis (CUTIS)

    Science.gov (United States)

    2018-04-10

    Cryoglobulinemic Vasculitis (CV); Drug-induced Vasculitis; Eosinophilic Granulomatosis With Polyangiitis (EGPA); IgA Vasculitis; Isolated Cutaneous Vasculitis; Granulomatosis With Polyangiitis (GPA); Microscopic Polyangiitis (MPA); Polyarteritis Nodosa (PAN); Urticarial Vasculitis; Vasculitis

  15. Pathogenesis of PR3-ANCA associated vasculitis

    NARCIS (Netherlands)

    Kallenberg, C. G. M.

    2008-01-01

    Wegener's Granulomatosis (WG) is closely associated with antineutrophil cytoplasmic autoantibodies (ANCA), particularly those directed to proteinase 3 (PR3). ANCA directed to myeloperoxidase (MPO) are associated with microscopic polyangiitis (MPA) and the Churg Strauss syndrome. PR3-ANCA associated

  16. Plasma exchange and glucocorticoid dosing in the treatment of anti-neutrophil cytoplasm antibody associated vasculitis (PEXIVAS)

    DEFF Research Database (Denmark)

    Walsh, Michael; Merkel, Peter A; Peh, Chen Au

    2013-01-01

    Granulomatosis with polyangiitis (GPA, Wegener's) and microscopic polyangiitis (MPA) are small vessel vasculitides collectively referred to as anti-neutrophil cytoplasm antibody-associated vasculitis (AAV). AAV is associated with high rates of morbidity and mortality due to uncontrolled disease...

  17. Indentation Creep Behavior of Nugget Zone of Friction Stir Welded 2014 Aluminum Alloy

    Science.gov (United States)

    Das, Jayashree; Robi, P. S.; Sankar, M. Ravi

    2018-04-01

    The present study is aimed at evaluating the creep behavior of the nugget zone of friction welded 2014 Aluminum alloy by indentation creep tests. Impression creep testing was carried out at different temperatures of 300°C, 350°C and 400 °C with stress 124.77MPa, 187.16MPa, 249.55 MPa using a 1.0 mm diameter WC indenter. Experiments were conducted till the curve enters the steady state creep region. Constitutive modeling of creep behavior was carried out considering the temperature, stress and steady state creep rate. Microstructural investigation of the crept specimen at 400°C temperature and 187.16 MPa load was carried out and found that the small precipitates accumulate along the grain boundaries at the favorable conditions of the creep temperature and stress, new precipitates evolve due to the ageing. The grains are broken and deformed due to the creep phenomena.

  18. 75 FR 29317 - Response to Comments on the Second Round of Nominated Sites to the National System of MPAs

    Science.gov (United States)

    2010-05-25

    ... to foster greater collaboration among participating MPA sites and programs in order to enhance... may be threatened Key cultural and historic sites that can be utilized for heritage tourism Key...

  19. Effects of water stress and seed mass on germination and ...

    African Journals Online (AJOL)

    enoh

    2012-03-01

    Mar 1, 2012 ... polyvinylpyrrolidone; TCA, trichloroacetic acid; NBT, nitroblue tetrazolium; TBA ..... seeds had weaker resistances to moderate stress (-0.6. MPa) compared with .... Chen YN,Chen YP,Li WH,Zhang HF (2003). Response of ...

  20. Multiple strengthening mechanisms in nanoparticle-reinforced ...

    Indian Academy of Sciences (India)

    Institute of Nuclear Sciences “Vinca”, University of Belgrade, 11001 Belgrade, Serbia. MS received 6 .... sphere using the 'NF' press with 200 MPa maximal applied pressure ..... Nadkarni V N and Synk E J 1984 Metals handbook (Metals Park,.

  1. Electrical and optical properties of ZnO–WO3 nanocomposite and its ...

    Indian Academy of Sciences (India)

    2, April 2017, pp. ... Materials Research Laboratory, Department of Physics, University of Lucknow, Lucknow 226007, India .... ing pressure of 267 MPa in a hydraulic press machine (M.B. ... posed by Friot et al [38] and Anderson and Parks [39]:.

  2. Persistence of self-recruitment and patterns of larval connectivity in a marine protected area network

    KAUST Repository

    Berumen, Michael L.; Almany, Glenn R; Planes, Serge; Jones, Geoffrey P; Saenz Agudelo, Pablo; Thorrold, Simon R

    2012-01-01

    to maintain local populations while simultaneously supplying larvae to other MPA nodes in the network that might otherwise suffer local extinction. Here, we use genetic parentage analysis to demonstrate that patterns of self-recruitment of two reef fishes

  3. An experimental study on two-phase flow pattern in low pressure natural circulation system

    International Nuclear Information System (INIS)

    Wu Shaorong; Han Bing; Zhou Lei; Zhang Youjie; Jiang Shengyao; Wu Xinxin

    1991-10-01

    An experimental study on two-phase flow pattern in the riser of low pressure natural circulation system was performed. The local differential pressure signal was analysed for flow pattern. It is considered that Sr f·d/v can be used to distinguish different flow patterns and it has clear and definite physical meaning. Flow patterns at different inlet temperature with different system pressures (1.5 MPa, 0.24 MPa and 0.1 MPa) are described. It is considered that the flow pattern is only bubble flow without flow pattern change during the period of low quality density-wave instability at 1.5 MPa. There is no density-wave oscillation in the system, when flow pattern is in bubble-intermittent transition area. The effect of flash vaporization on stability at low pressure is discussed

  4. Effect of high hydrostatic pressure on the color and texture parameters of refrigerated Caiman (Caiman crocodilus yacare) tail meat.

    Science.gov (United States)

    Canto, A C V C S; Lima, B R C C; Cruz, A G; Lázaro, C A; Freitas, D G C; Faria, Jose A F; Torrezan, R; Freitas, M Q; Silva, T P J

    2012-07-01

    The effect of applying high hydrostatic pressure (HHP) on the instrumental parameters of color and texture and sensory characteristics of alligator meat were evaluated. Samples of alligator tail meat were sliced, vacuum-packed, pressurized and distributed into four groups: control, treated with 200 MPa/10 min, 300 MPa/10 min and 400 MPa/10 min, then stored at 4°C±1°C for 45 days. Instrumental color, texture profile and a sensory profiling using quantitative descriptive analysis were carried out on the 1st, 15th, 30th and 45th days of storage. HHP was shown to affect the color and texture of the product, and the sensory descriptors (pmeat, especially low pressures (200 MPa) which can have positive effects on the quality of the product. Copyright © 2012 Elsevier Ltd. All rights reserved.

  5. Clinical significance of right ventricular ejection fraction in cases with atrial septal defect

    Energy Technology Data Exchange (ETDEWEB)

    Hamada, Seiki; Nishimura, Tsunehiko; Hayashida, Kouhei; Uehara, Toshiisa

    1989-04-01

    Right ventricular ejection fraction (RVEF) assessed by cardiac radionuclide angiography has been applied to evaluate ventricular function such as ischemic, valvular and congenital heart disease. Using this modality, previous reports also suggest that there is good correlation between RVEF and mean pulmonary arterial pressure (mPA) from catheterization findings in mitral valvular disease and chronic obstructive lung disease. In this study, cardiac RI angiography were performed on 33 adult patients with atrial septal defect (ASD). RVEF is not so good correlation (r=-0.42) with mPA, but in cases within pulmonary to systemic ratio (Qp/Qs) less than 2.0 limits, there is good correlation between RVEF and mPA (n=9, r=-0.71). As a conclusion, in ASD, both afterload assessed by mPA and preload assessed by Qp/Qs decrease RVEF. (author).

  6. C-SCAMP Cruise Report #3 - C-BASS Cruise Report - 2016-04-CS04-C02 - RV Weatherbird II - April 07-12, 2016 (EK60)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Camera-Based Assessment Survey System (C-BASS) was used to image new areas around Madison-Swanson Marine Protected Area (MPA) located in the northeastern Gulf of...

  7. A Lattice-Misfit-Dependent Damage Model for Non-linear Damage Accumulations Under Monotonous Creep in Single Crystal Superalloys

    Science.gov (United States)

    le Graverend, J.-B.

    2018-05-01

    A lattice-misfit-dependent damage density function is developed to predict the non-linear accumulation of damage when a thermal jump from 1050 °C to 1200 °C is introduced somewhere in the creep life. Furthermore, a phenomenological model aimed at describing the evolution of the constrained lattice misfit during monotonous creep load is also formulated. The response of the lattice-misfit-dependent plasticity-coupled damage model is compared with the experimental results obtained at 140 and 160 MPa on the first generation Ni-based single crystal superalloy MC2. The comparison reveals that the damage model is well suited at 160 MPa and less at 140 MPa because the transfer of stress to the γ' phase occurs for stresses above 150 MPa which leads to larger variations and, therefore, larger effects of the constrained lattice misfit on the lifetime during thermo-mechanical loading.

  8. Environmental Durability Testing of Structural Adhesives. Part I. AF- 143-2/EC-3917; PL-729-3/PL-728

    Science.gov (United States)

    1978-12-01

    Mode (6 ( 4C ) No Load (psi) (MPa) (I Coh.Failura) 72 22 None 3040 20.9 100 72 22 None 3000 20.7 100 72 22 None 3020 20.8 100 72 22 None 2960 20.4 1.00 72... 4C ) No LOa4 Ji (psi) (MPa) (9 Coh.Failurs) 72 22 None 5560 38.3 100 72 22 None 5700 39.3 100 72 22 None 5660 39.0 50 72 22 None 5590 38.5 80 72 22...F dry Failure Shear Strength Mode (psi) (MPa) ultimatoe ( hrm ) (psi) (MPa) (% Coh.) 2420 16.7 80 0.30 100 2420 16.7 g0 0.50 100 2420 16.7 80 1.25 100

  9. Marine protected areas in Costa Rica: How do artisanal fishers respond?

    Science.gov (United States)

    Madrigal-Ballestero, Róger; Albers, Heidi J; Capitán, Tabaré; Salas, Ariana

    2017-11-01

    Costa Rica is considering expanding their marine protected areas (MPAs) to conserve marine resources. Due to the importance of households' responses to an MPA in defining the MPA's ecological and economic outcomes, this paper uses an economic decision framework to interpret data from near-MPA household surveys to inform this policy discussion. The model and data suggest that the impact of expanding MPAs relies on levels of enforcement and on-shore wages. If larger near-shore MPAs can produce high wages through increased tourism, MPA expansions could provide ecological benefits with low burdens to communities. Due to distance costs and gear investments, however, MPAs farther off-shore may place high burdens on off-shore fishers.

  10. Analysis of flow dynamics of main pulmonary artery by cine phase contrast MR angiography

    International Nuclear Information System (INIS)

    Honda, Norinari; Machida, Kikuo; Mamiya, Toshio

    1996-01-01

    Nineteen studies of cine phase contrast MR angiography (PCMRA) of main pulmonary artery (MPA) entered the study. Cine PCMRA was obtained by a 1.5T MR imager with a gradient echo sequence coupled with velocity encoding bipolar pulses. Retrospective EKG gating was used. Mean velocity, maximum velocity, and maximum flow rate of MPA were 6.2 to 28 cm/s (mean/SD 13/5.1, n=18), 61 to 148 cm/s (mean/SD 102/30, n=13), and 12,561 to 30,113 ml/min (mean/SD 18,730/5,464, n=18), respectively. Retrograde flow in the MPA was noted to begin at late-to mid-systole. Retrograde flow occurred first in the posterior part (15/19) or occurred from periphery (4/19). Thus hemodynamic parameters and velocity maps of MPA can be obtained by cine PCMRA. (author)

  11. Computational modeling of the mechanical modulation of the growth plate by sustained loading

    Directory of Open Access Journals (Sweden)

    Narváez-Tovar Carlos A

    2012-09-01

    Full Text Available Abstract This paper presents a computational model that describes the growth of the bone as a function of the proliferation and hypertrophy of chondrocytes in the growth plate. We have included the effects of the mechanical loads on the sizes of the proliferative and hypertrophic areas, the number of proliferative chondrocytes and the final size of the hypertrophic chondrocytes. The validation of the model was performed with experimental data published on other investigations about proximal tibia of rats, subjected to sustained axial stresses of 0.1 MPa, 0.0 MPa, -0.1 MPa and −0.2 MPa. Growth was simulated during 23 days, obtaining numerical errors between 2.77% and 3.73% with respect to experimental growth rates. The results obtained show that the model adequately simulates the behavior of the growth plate and the effect of mechanical loads over its cellular activity.

  12. Socioeconomic significance of mangroves for coastal people of India: A changing scenario

    Digital Repository Service at National Institute of Oceanography (India)

    Untawale, A.G.; Jagtap, T.G.

    Mangrove Protected Areas (MPA), ecotourism, aquaculture and agriculture have shown great significance. Although the economic grains for coastal people have increased through these activities, the mangrove ecosystem itself has become endangered in certain...

  13. RENAL VASCULITIS IN 2012 Reclassification and the introduction of biologicals

    NARCIS (Netherlands)

    Kallenberg, Cees G. M.

    2012 saw the classification of the systemic vasculitides revised. Genetic studies showed that granulomatosis with polyangiitis (GPA) and microscopic polyangiitis (MPA) are different diseases with aberrant immune responses to different autoantigens. B-cell depletion with rituximab also acquired a

  14. Microstructure and mechanical properties of Ti-15Zr alloy used as dental implant material.

    Science.gov (United States)

    Medvedev, Alexander E; Molotnikov, Andrey; Lapovok, Rimma; Zeller, Rolf; Berner, Simon; Habersetzer, Philippe; Dalla Torre, Florian

    2016-09-01

    Ti-Zr alloys have recently started to receive a considerable amount of attention as promising materials for dental applications. This work compares mechanical properties of a new Ti-15Zr alloy to those of commercially pure titanium Grade4 in two surface conditions - machined and modified by sand-blasting and etching (SLA). As a result of significantly smaller grain size in the initial condition (1-2µm), the strength of Ti-15Zr alloy was found to be 10-15% higher than that of Grade4 titanium without reduction in the tensile elongation or compromising the fracture toughness. The fatigue endurance limit of the alloy was increased by around 30% (560MPa vs. 435MPa and 500MPa vs. 380MPa for machined and SLA-treated surfaces, respectively). Additional implant fatigue tests showed enhanced fatigue performance of Ti-15Zr over Ti-Grade4. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. Johnson - Cook Strength Models for Mild and DP 590 Steels

    International Nuclear Information System (INIS)

    Vedantam, K.; Brar, N. S.; Bajaj, D.; Hill, S.

    2006-01-01

    Automotive steels, Mild and Dual Phase590 (DP590) are characterized in tension at room temperature, using the quasi-static and split Hopkinson bar techniques at various strain rates ranging from ∼10-3/s to ∼1800/s. Tension stress-strain data for both the steels are analyzed to determine the Johnson-Cook Strength model constants, J-C strength model constants for mild steel are A=217 MPa, B = 234 MPa, n = 0.643 and C = 0.076 and for DP590 steel are A = 430 MPa, B = 824 MPa, n = 0.510 and C = 0.017. Higher value of strain rate sensitivity constant C for mild steel (0.076) compared to DP 590 (0.017) is also reflected in the stress- strain data at various strain rates

  16. Retrogradation of Maize Starch after High Hydrostatic Pressure Gelation: Effect of Amylose Content and Depressurization Rate

    KAUST Repository

    Yang, Zhi; Swedlund, Peter; Gu, Qinfen; Hemar, Yacine; Chaieb, Saharoui

    2016-01-01

    High hydrostatic pressure (HHP) has been employed to gelatinize or physically modify starch dispersions. In this study, waxy maize starch, normal maize starch, and two high amylose content starch were processed by a HHP of the order of 600 MPa

  17. Influence of curing regimes on compressive strength of ultra high ...

    Indian Academy of Sciences (India)

    142 MPa with change in curing regimes. The samples ..... Guide, School of Civil and Environmental Engineering, The University of New South Wales, Sydney, ... the 5th International Conference on the Chemistry of Cement, Tokyo, Japan, pp.

  18. 77 FR 68105 - Marine Protected Areas Federal Advisory Committee; Public Meeting

    Science.gov (United States)

    2012-11-15

    ... engagement initiatives, and one from MPA managers on engaging with the travel, recreation and tourism... Sanctuary Advisory Councils to discuss fostering links between MPAs and the recreation, travel and tourism... and [[Page 68106

  19. Ex Situ Introduction and Distribution of Nonmetallic Particles in Aluminum Melt: Modeling and Experiment

    Science.gov (United States)

    Vorozhtsov, S.; Minkov, L.; Dammer, V.; Khrustalyov, A.; Zhukov, I.; Promakhov, V.; Vorozhtsov, A.; Khmeleva, M.

    2017-12-01

    Simulation results for mechanical mixing of aluminum melt using a mixing device are presented. It is found that an increase in the rotational velocity of the vortex device leads to intensive growth of turbulent diffusion in the liquid metal. Small vortices, although energetically weaker, can provide uniform mixing, creating regions of uniformity of several tens of microns. Experimental studies showed that use of a special mechanical mixing device enables injection of course titanium diboride particles and leads to significantly improved microstructure (reduction in average grain size from 900 μm to 400 μm) and mechanical properties of aluminum alloy A356. In particular, introduction of 0.2 wt.% titanium diboride particles using the vortex device leads to an increase in yield strength (from 15 MPa to 65 MPa) and ultimate tensile strength (from 140 MPa to 220 MPa) while preserving the ductility of the alloy ( 4.5%).

  20. Hydrogenation properties and microstructure of Ti-Mn-based alloys for hybrid hydrogen storage vessel

    International Nuclear Information System (INIS)

    Shibuya, Masachika; Nakamura, Jin; Akiba, Etsuo

    2008-01-01

    Ti-Mn-based AB 2 -type alloys which are suitable for a hybrid hydrogen storage vessel have been synthesized and evaluated hydrogenation properties. As the third element V was added to Ti-Mn binary alloys. All the alloys synthesized in this work mainly consist of the C14 Laves and BCC phase. In the case of Ti0.5V0.5Mn alloy, the amounts of hydrogen absorption was 1.8 wt.% at 243 K under the atmosphere of 7 MPa H 2 , and the hydrogen desorption pressure was in the range of 0.2-0.4 MPa at 243 K. The hydrogen capacity of this alloy did not saturate under 7 MPa H 2 and seems to increase with hydrogen pressure up to 35 MPa that is estimated working pressure of the hybrid hydrogen storage vessel

  1. FINITE ELEMENT MODEL FOR PREDICTING RESIDUAL ...

    African Journals Online (AJOL)

    FINITE ELEMENT MODEL FOR PREDICTING RESIDUAL STRESSES IN ... the transverse residual stress in the x-direction (σx) had a maximum value of 375MPa ... the finite element method are in fair agreement with the experimental results.

  2. Status of Coral Reef Fish Communities within the Mombasa Marine ...

    African Journals Online (AJOL)

    investigated in the Mombasa Marine Protected Area (MPA) on the Kenya coast ... in 1991 in an urban and tourism development ... Coast Province of Kenya in ..... environmental factors such as salinity and ... SEM when sampling is difficult.

  3. Residual-stresses in austenitic stainless-steel primary coolant pipes and welds of pressurized-water reactors

    International Nuclear Information System (INIS)

    Faure, F.; Leggatt, R.H.

    1996-01-01

    Surface and through thickness residual stress measurements were performed on an aged cast austenitic-ferritic stainless steel pipe and on an orbital TIG weld representative of those of primary coolant pipes in pressurized water reactors. An abrasive-jet hole drilling method and a block removal and layering method were used. Surface stresses and through thickness stress profiles are strongly dependent upon heat treatments, machining and welding operations. In the aged cast stainless steel pipe, stresses ranged between -250 and +175 MPa. On and near the orbital TIG weld, the outside surface of the weld was in tension both in the axial and hoop directions, with maximum values reaching 420 MPa in the weld. On the inside surface, the hoop stresses were compressive, reaching -300 MPa. However, the stresses in the axial direction at the root of the weld were tensile within 4 mm depth from the inside surface, locally reaching 280 MPa. (author)

  4. Accurate Modeling and Analysis of Isolation Performance in Multiport Amplifiers

    Directory of Open Access Journals (Sweden)

    Marinella Aloisio

    2012-01-01

    Full Text Available A Multiport Amplifier (MPA is an implementation of the satellite power amplification section that allows sharing the payload RF power among several beams/ports and guarantees a highly efficient exploitation of the available DC satellite power. This feature is of paramount importance in multiple beam satellite systems where the use of MPAs allows reconfiguring the RF output power among the different service beams in order to handle unexpected traffic unbalances and traffic variations over time. This paper presents Monte Carlo simulations carried out by means of an ESA in-house simulator developed in Matlab environment. The objective of the simulations is to analyse how the MPA performance, in particular in terms of isolation at the MPA output ports, is affected by the amplitude and phase tracking errors of the high power amplifiers within the MPA.

  5. Design and Fabrication of 3D printed Scaffolds with a Mechanical Strength Comparable to Cortical Bone to Repair Large Bone Defects

    Science.gov (United States)

    Roohani-Esfahani, Seyed-Iman; Newman, Peter; Zreiqat, Hala

    2016-01-01

    A challenge in regenerating large bone defects under load is to create scaffolds with large and interconnected pores while providing a compressive strength comparable to cortical bone (100-150 MPa). Here we design a novel hexagonal architecture for a glass-ceramic scaffold to fabricate an anisotropic, highly porous three dimensional scaffolds with a compressive strength of 110 MPa. Scaffolds with hexagonal design demonstrated a high fatigue resistance (1,000,000 cycles at 1-10 MPa compressive cyclic load), failure reliability and flexural strength (30 MPa) compared with those for conventional architecture. The obtained strength is 150 times greater than values reported for polymeric and composite scaffolds and 5 times greater than reported values for ceramic and glass scaffolds at similar porosity. These scaffolds open avenues for treatment of load bearing bone defects in orthopaedic, dental and maxillofacial applications.

  6. The differential association of conjugated equine estrogen and esterified estrogen with activated protein C resistance in postmenopausal women

    NARCIS (Netherlands)

    Smith, N. L.; Heckbert, S. R.; Doggen, C. J.; Lemaitre, R. N.; Reiner, A. P.; Lumley, T.; Meijers, J. C. M.; Psaty, B. M.; Rosendaal, F. R.

    2006-01-01

    OBJECTIVES: Clinical trials have demonstrated that oral conjugated equine estrogen (CEE) therapy with or without medroxyprogesterone (MPA) increases venous thrombotic risk but this safety issue has not been investigated for other oral estrogens. Based on observational study findings that esterified

  7. High-pressure hydriding of Zircaloy

    International Nuclear Information System (INIS)

    Kim, Y.S.

    1996-01-01

    The hydriding characteristics of Zircaloy-2(Zry), sponge zirconium (as a liner on Zry plate), and crystal-bar zirconium exposed to pure H 2 at 0.1 MPa or 7 MPa and 400 C were determined in a thermogravimetric apparatus. The morphology of the hydrided specimens was also examined by optical microscopy. For all specimen types, the rate of hydriding in 7 MPa H 2 was two orders of magnitude greater than in 0.1 MPa H 2 . For Zry, uniform bulk hydriding was revealed by hydride precipitates at room temperature and on one occasion, a sunburst hydride. In addition, all specimen types exhibited a hydride surface layer. In a duplex Zry/sponge-Zr specimen, Zry is more heavily hydrided than the sponge Zr layer. (orig.)

  8. Comparability of patients with ANCA-associated vasculitis enrolled in clinical trials or in observational cohorts

    NARCIS (Netherlands)

    Pagnoux, C.; Carette, S.; Khalidi, N. A.; Walsh, M.; Hiemstra, T. F.; Cuthbertson, D.; Langford, C.; Hoffman, G.; Koening, C. L.; Monach, P. A.; Moreland, L.; Mouthon, L.; Seo, P.; Specks, U.; Ytterbere, S.; Westman, K.; Hoglund, P.; Harper, L.; Flossmann, O.; Luqmani, R.; Savage, C.; Rasmussen, N.; de Groot, K.; Tesar, V.; Jayne, D.; Merkel, P. A.; Guillevin, L.; Stegeman, C. A.

    2015-01-01

    Objective. To analyse the differences between patients with granulomatosis with polyangiitis (GPA) or microscopic polyangiitis (MPA) entered into randomised clinical trials (RCTs) and those followed in large observational cohorts. Methods. The main characteristics and outcomes of patients with

  9. 76 FR 66912 - Marine Protected Areas Federal Advisory Committee; Public Meeting

    Science.gov (United States)

    2011-10-28

    ... Protected Areas Federal Advisory Committee (Committee) in New Orleans, Louisiana. DATES: The meeting will be... Yeager, Designated Federal Officer, MPA FAC, National Marine Protected Areas Center, 1305 East West... DEPARTMENT OF COMMERCE National Oceanic and Atmospheric Administration (NOAA) Marine Protected...

  10. Temporal variability of a temperate fish assemblage in Africa's oldest ...

    African Journals Online (AJOL)

    year-old Tsitsikamma National Park Marine Protected Area (MPA) between 1998 and 2005. The aim of this study was to examine variability in community structure, relative abundance (catch per unit effort, CPUE) and size frequency of the ...

  11. 78 FR 67338 - Marine Protected Areas Federal Advisory Committee; Public Meeting

    Science.gov (United States)

    2013-11-12

    ... DEPARTMENT OF COMMERCE National Oceanic and Atmospheric Administration Marine Protected Areas... the Marine Protected Areas Federal Advisory Committee (Committee). The web conference calls are open..., MPA FAC, National Marine Protected Areas Center, 1305 East West Highway, Silver Spring, Maryland 20910...

  12. Implications of renewables on energy planning

    CSIR Research Space (South Africa)

    Bischof-Niemz, T

    2015-10-01

    Full Text Available : Senior consultant (energy system and renewables expert) at The Boston Consulting Group, Berlin and Frankfurt, Germany Education • Master of Public Administration (MPA) on energy and renewables policies in 2009 from Columbia University in New York City...

  13. A micro-pillar array to trap magnetic beads in microfluidic systems

    KAUST Repository

    Gooneratne, Chinthaka Pasan; Kosel, Jü rgen

    2012-01-01

    A micro-pillar array (MPA) is proposed in this paper to trap and separate magnetic beads (MBs) in microfluidic systems. MBs are used in many biomedical applications due to being compatible in dimension to biomolecules, the large surface area

  14. Pramana – Journal of Physics | Indian Academy of Sciences

    Indian Academy of Sciences (India)

    step aqueous chemical approach. 3-mercaptopropionic acid (MPA) was used as the capping molecule. The structural and optical properties of the prepared samples are characterized by X-ray diffraction (XRD), UV–vis absorption spectroscopy ...

  15. Critical superheats upon boiling of dissociating liquids

    International Nuclear Information System (INIS)

    Kolykhan, L.I.; Solov'ev, V.N.

    1985-01-01

    The experimental data on critical superheats of dissociating liquids, i.e. nitrogen tetroxide and nitrine are presented (nitrine is the solution of nitrogen oxide in nitrogen tetroxide). The experiments with boiling N 2 O 4 have been carried out in the pressure range 0.1-3.0 MPa and with boiling nitrine within the pressure range 0.2-9.0 MPa. The experiments have revealed an anomalous dependence of critical superheats on pressure P, thus at P>=2.5 MPa the critical superheat values exceed the limiting ones, and at P=4.5 MPa this excess amounts to more than 16 K, essentially exceeding the errors of the experiments. The results for N 2 O 4 critical superheats agree with experimental data of other authors. Complex phenomena observed upon boiling of dissociating liquids require further theoretical and experimental studies

  16. Effect of surface modifications on the bond strength of zirconia ceramic with resin cement resin.

    Science.gov (United States)

    Hallmann, Lubica; Ulmer, Peter; Lehmann, Frank; Wille, Sebastian; Polonskyi, Oleksander; Johannes, Martina; Köbel, Stefan; Trottenberg, Thomas; Bornholdt, Sven; Haase, Fabian; Kersten, Holger; Kern, Matthias

    2016-05-01

    Purpose of this in vitro study was to evaluate the effect of surface modifications on the tensile bond strength between zirconia ceramic and resin. Zirconia ceramic surfaces were treated with 150-μm abrasive alumina particles, 150-μm abrasive zirconia particles, argon-ion bombardment, gas plasma, and piranha solution (H2SO4:H2O2=3:1). In addition, slip casting surfaces were examined. Untreated surfaces were used as the control group. Tensile bond strengths (TBS) were measured after water storage for 3 days or 150 days with additional 37,500 thermal cycling for artificial aging. Statistical analyses were performed with 1-way and 3-way ANOVA, followed by comparison of means with the Tukey HSD test. After storage in distilled water for three days at 37 °C, the highest mean tensile bond strengths (TBS) were observed for zirconia ceramic surfaces abraded with 150-μm abrasive alumina particles (TBS(AAP)=37.3 MPa, TBS(CAAP)=40.4 MPa), and 150-μm abrasive zirconia particles (TBS(AZP)=34.8 MPa, TBS(CAZP)=35.8 MPa). Also a high TBS was observed for specimens treated with argon-ion bombardment (TBS(BAI)=37.8 MPa). After 150 days of storage, specimens abraded with 150-μm abrasive alumina particles and 150-μm abrasive zirconia particles revealed high TBS (TBS(AAP)=37.6 MPa, TBS(CAAP)=33.0 MPa, TBS(AZP)=22.1 MPa and TBS(CAZP)=22.8 MPa). A high TBS was observed also for specimens prepared with slip casting (TBS(SC)=30.0 MPa). A decrease of TBS was observed for control specimens (TBS(UNT)=12.5 MPa, TBS(CUNT)=9.0 MPa), specimens treated with argon-ion bombardment (TBS(BAI)=10.3 MPa) and gas plasma (TBS(GP)=11.0 MPa). A decrease of TBS was observed also for specimens treated with piranha solution (TBS(PS)=3.9 MPa, TBS(CPS)=4.1 MPa). A significant difference in TBS after three days storage was observed for specimens treated with different methods (p0.05), CAAP(p>0.05) and SC(p>0.05). However, the failure patterns of debonded specimens prepared with 150-μm abrasive zirconia

  17. 75 FR 23244 - North Pacific Fishery Management Council; Public Meeting

    Science.gov (United States)

    2010-05-03

    .... ADDRESSES: The meeting will be held at the Hotel Captain Cook, 939 W 5th Avenue, Anchorage, AK 99501...); Marine Protection Area (MPA) nominations; President's budget and other budget issues, 2010 National SSC...

  18. Fatigue 󈨛. Volume 1,

    Science.gov (United States)

    1987-06-01

    277 FATIGUE 87 da/dn (m/ ciclo ) 10 - 07 10 - 08 10 - 0 9 R=0.5 S* • -Long Crack 10-10 e Smax = 195 MPa *Smax = 205 MPa 1Smax = 225 MPa 0.5 1 5 10 AK...MPa/m) Figure 1 Crack growth rate vs stress intensity factor range 10 . da/dn (m/ ciclo ) i0 - ° 09 i0-o -Long crack 10 . ° Smax = 10 Pa 10 Smax...120 NPa Smax = 145 NlPa 0.5 I 10 AKN~~)50 Figure 2 Crack growth rate vs stress intensity factor range 278 FATIGUE 87 da/dn (m/ ciclo ) 10- 10- 0 7 % 10

  19. Application of laser interferometry for assessment of surface residual stress by determination of stress-free state

    International Nuclear Information System (INIS)

    Kim, Dong Won; Kwon, Dong Il; Lee, Nak Kyu; Choi, Tae Hoon; Na, Kyoung Hoan

    2003-01-01

    The total relaxed stress in annealing and the thermal strain/stress were obtained from the identification of the residual stress-free state using Electronic Speckle Pattern Interferometry (ESPI). The residual stress fields in case of both single and film/substrate systems were modeled using the thermo-elastic theory and the relationship between relaxed stresses and displacements. We mapped the surface residual stress fields on the indented bulk Cu and the 0.5 μm Au film by ESPI. In indented Cu, the normal and shear residual stress are distributed over -1.7 GPa to 700 MPa and -800 GPa to 600 MPa respectively around the indented point and in deposited Au film on Si wafer, the tensile residual stress is uniformly distributed on the Au film from 500 MPa to 800 MPa. Also we measured the residual stress by the X-Ray Diffractometer (XRD) for the verification of above residual stress results by ESPI

  20. Thermal and Mechanical Properties of UO2 and PuO2

    International Nuclear Information System (INIS)

    Kato, M.; Matsumoto, T.

    2015-01-01

    It is important to evaluate basic properties of UO 2 and PuO 2 as fundamental aspects of MA-bearing MOX fuel development. In this work, mechanical properties of UO 2 and PuO 2 were investigated by an ultrasound pulse-echo method. Longitudinal and transversal wave velocities were measured in UO 2 and PuO 2 pellets, and Young's modulus and shear modulus were evaluated, which were 219 MPa and 89 MPa for PuO 2 , and 249 MPa and 95 MPa for UO 2 , respectively. Poisson's ratio was 0.32 in both materials. The relationship between mechanical and thermal properties was described by using thermal expansion data which had been reported previously, and the heat capacity and thermal conductivity were analysed. (authors)

  1. Fracture prevention and availability in the series safety of the pressure boundary of light water reactors. Materials for advanced reactor systems

    International Nuclear Information System (INIS)

    1983-01-01

    This brochure contains the full text of 23 lectures, which were given at the 9th MPA Seminar in October 1983. The main part of the work consists of investigations of fracture mechanics of reactor steel. (RW) [de

  2. single dose pharmacokinetics of mefloquine in healthy nigerian

    African Journals Online (AJOL)

    BSN

    Mefloquine 500mg single dose was administered and blood samples were collected ... particle size ODS Hypersil (HETP, Macclesfield, UK) at a pressure of 55 Mpa .... dose to area under the plasma drug concentration - time curve, assuming ...

  3. Determination of short circuit stresses in an air core reactor using ...

    African Journals Online (AJOL)

    DR OKE

    developed has crossed the boundary condition limit of 70 MPa whereas the ... The method can be used to identify the inter layer forces ... Power transformer design using magnetic circuit theory and finite element analysis – A Comparison.

  4. The Influence of Hydroxylated Carbon Nanotubes on Epoxy Resin Composites

    Directory of Open Access Journals (Sweden)

    Jiaoxia Zhang

    2012-01-01

    Full Text Available Hydroxylated multiwall carbon nanotubes (MWNTs/epoxy resin nanocomposites were prepared with ultrasonic dispersion and casting molding. The effect of hydroxylated MWNTs content on reactive activity of composites is discussed. Then the flexural and electrical properties were studied. Transmission electron microscope was employed to characterize the microstructure of nanocomposites. As a result, the reactive activity of nanocomposites obtained increases with the increasing content of MWNTs. When MWNTs content of the composites is 1 wt%, as compared to neat resin, the flexural strength increases from 143 Mpa to 156 MPa, the modulus increases from 3563 Mpa to 3691 MPa, and the volume and surface resistance of nanocomposites decrease by two orders of magnitude, respectively.

  5. Download this PDF file

    African Journals Online (AJOL)

    USER

    2015-09-07

    Sep 7, 2015 ... ratio of 40: 60 (Material: Binder) and least was 3 .30% for sorghum residues, mix ratio 60: 40 at 10 MPa. .... mechanical characteristics and properties. These include: ..... Environmental Modeling of Biofuels. Adoption in the ...

  6. Sensitivity of Spores of Eight Bacillus Cereus Strains to Pressure-Induced Germination by Moderate Hydrostatic Pressure, Time and Temperature

    National Research Council Canada - National Science Library

    Kalchayanand, Norasak; Ray, Bibek; Dunne, C. P; Sikes, Anthony

    2005-01-01

    The spores of eight Bacillus cereus strains were pressurized at 138 to 483 MPa for 5 to 20 min at 25 to 70 C in order to determine the sensitive and the resistant strains to pressure-induced germination...

  7. Microstructure features and mechanical properties of a UFG Al-Mg-Si alloy produced via SPD

    International Nuclear Information System (INIS)

    Bobruk, E; Kazykhanov, V; Valiev, R; Murashkin, M; Sabirov, I

    2014-01-01

    The effect of equal channel angular pressing in parallel channels (ECAP-PC) and subsequient artificial ageing on the microstructure and room temperature mechanical properties of the commercial aluminum alloys 6063 (Al-0.6Mg-0.5Si, wt.%) and 6010 (Al-0.8Mg-1.0Si-0.15Cu-0.25Mn, wt.%) was investigated. It was shown that mechanical strength of the ECAP-PC processed Al alloys is higher compared to that achieved in these alloys after conventional thermo-mechanical processing. Prior ECAP- PC solution treatment and post-ECAP-PC artificial aging can additionally increase the mechanical strength of both Al alloys. Under optimal artificial ageing conditions, the yield strength (YS) of 299 MPa and ultimate tensile strength (UTS) of 308 MPa was achieved in the 6063 alloy, whereas YS of 423 MPa and UTS of 436 MPa was achieved in the 6010 alloy

  8. Effect of high hydrostatic pressure on rheological and thermophysical properties of murtilla (Ugni molinae Turcz) berries.

    Science.gov (United States)

    Lemus-Mondaca, Roberto; Ah-Hen, Kong; Vega-Gálvez, Antonio; Zura-Bravo, Liliana

    2016-06-01

    Effects of high hydrostatic pressure (HHP) on rheological and thermophysical properties of murtilla berries were evaluated after pressure treatments for 5 min between 100 and 500 MPa. Differential scanning calorimetry was employed to measure specific heat capacity. HHP caused a significant decrease in specific heat and density, while thermal diffusivity did not changed significantly. Thermal conductivity showed a slight increase upon HHP treatment. Apparent viscosity increased significantly above 200 MPa HHP treatment. Apparent viscosity of treated samples between 200 and 400 MPa did not differ significantly and the increase was significant at 500 MPa. Herschel-Bulkley, Bingham and Ostwald de Waele models were used to describe the rheological behaviour of murtilla purée, and Ostwald de Waele model gave the best fit for the experimental data.

  9. 76 FR 39075 - New England Fishery Management Council; Public Meeting

    Science.gov (United States)

    2011-07-05

    ... Committee will discuss measures to minimize the adverse effects of fishing on Essential Fish Habitat (EFH... England Fishery Management Council (Council) is scheduling a public meeting of its Habitat/MPA/Ecosystem...

  10. Mobility controlled linear magnetoresistance with 3D anisotropy in a layered graphene pallet

    KAUST Repository

    Zhang, Qiang; Li, Peng; He, Xin; Li, Jun; Wen, Yan; Ren, Wencai; Cheng, Hui Ming; Yang, Yang; Al-Hadeethi, Yas F.; Zhang, Xixiang

    2016-01-01

    A bulk sample of pressed graphene sheets was prepared under hydraulic pressure (similar to 150 MPa). The cross-section of the sample demonstrates a layered structure, which leads to 3D electrical transport properties with anisotropic mobility

  11. Microstructure evolution of fault rocks at the "brittle-to-plastic" transition

    Science.gov (United States)

    Heilbronner, R.; Pec, M.; Stunitz, H.

    2011-12-01

    In the continental crust, large earthquakes tend to nucleate at the "brittle-to-plastic" transition at depths of ~ 10 - 20 km indicating stress release by rupture at elevated PT. Experimental studies, field observations, and models predict peak strength of the lithosphere at depths where rocks deform by "semi-brittle" flow. Thus, the deformation processes taking place at these conditions are important aspects of the seismic cycle and fault rheology in general. We performed a series of experiments with crushed Verzasca gneiss powder (d ≤ 200 μm), "pre-dried" and 0.2 wt% H2O added, placed between alumina forcing blocks (45° pre-cut) and weld-sealed in Pt jackets. The experiments were performed at Pc = 500, 1000 and 1500 MPa, T = 300°C and 500°C. and shear strain rates of ~10-3 s-1 to ~10-5 s-1 in a solid medium deformation apparatus (Griggs rig). Samples deformed at Pc = 500 MPa attain peak strength (~ 1100-1400 MPa) at γ ~ 2, they weaken by ~20 MPa (300°C) to ~140 MPa (500°C) and reach a steady state. The 300°C experiments are systematically stronger by ~ 330 - 370 MPa than the 500°C experiments, and flow stress increases with increasing strain rate. At Pc = 1000 and 1500 MPa, peak strength (~1300-1600 MPa) is reached at γ = 1 to 1.5 followed by weakening of ~60 (300°C) and ~150 MPa (500°C). The strength difference between 300°C and 500°C samples is 270-330 MPa and does not increase with increasing confining pressure. The peak strength increase with confining pressure is modest (50-150 MPa), indicating that the rocks reach their maximal compressive strength. The microstructure develops as an S-C-C' fabric with dominant C' slip zones. At low strains, the gouge zone is pervasively cut by closely spaced C' shears containing fine-grained material (d disintegration of the grains is accompanied by transport of alkalis, producing a different mineral chemistry even at short experimental time scales (~20 min to 30 hrs). The amorphous to nano

  12. Mechanical behavior in the Nankai inner accretionary prism, IODP Site C0002

    Science.gov (United States)

    Valdez, R. D., II; Saffer, D. M.

    2017-12-01

    Understanding the processes that control seismogenesis and stress state at subduction zones requires knowledge of fault zone and sediment physical and mechanical properties. As part of the International Ocean Discovery Program (IODP) Nankai Trough Seismogenic Zone Experiment (NanTroSEIZE), Expedition 348 drilled into the Kumano forearc basin and underlying inner accretionary prism at Site C0002, located 35 km landward of the trench. One primary objective was to sample and characterize the mechanical behavior of the inner accretionary prism. Here we report on the frictional and unconfined compressive strength (UCS) of mudstone samples and a clay-rich shear zone recovered from 2182-2209 meters below sea floor (mbsf), determined from triaxial deformation tests at confining pressures from 1 to 7 MPa (UCS measurements on mudstones) and 36 MPa (strength of fault zone). Our results show that at a confining pressure of 1 MPa, the wall rock sediments fail at a peak differential stress of 9.1 MPa with a residual stress of 2.8 MPa. A clear peak and evolution to residual strength remains present at 7 MPa, and both the peak and residual strengths of the mudstones increases systematically with confining pressure. At a confining pressure of 36 MPa, the shear zone sediment yields at a differential stress of 25.2 MPa followed by strain-hardening to a maximum stress of 33.1 MPa. The shear zone is frictionally weaker than the surrounding mudstones, with a friction coefficient (μ) of 0.26-0.31, versus µ = 0.45 for the wall rock. The suite of tests defines a UCS for the mudstone of 7.9 MPa. Our friction data suggest that the inner wedge may be weaker than commonly assumed in applications of critical wedge theory to estimate the properties and conditions in accretionary prisms. One key implication is that for a given basal detachment friction coefficient, higher basal pore pressures (or lower wedge pore pressures) would be required to sustain observed taper angles. Additionally, the

  13. Mycophenolate pharmacokinetics and pharmacodynamics in belatacept treated renal allograft recipients – a pilot study

    Directory of Open Access Journals (Sweden)

    Stenstrøm Jean

    2009-07-01

    Full Text Available Abstract Background Mycophenolic acid (MPA is widely used as part of immunosuppressive regimens following allograft transplantation. The large pharmacokinetic (PK and pharmacodynamic (PD variability and narrow therapeutic range of MPA provide a potential for therapeutic drug monitoring. The objective of this pilot study was to investigate the MPA PK and PD relation in combination with belatacept (2nd generation CTLA4-Ig or cyclosporine (CsA. Methods Seven renal allograft recipients were randomized to either belatacept (n = 4 or cyclosporine (n = 3 based immunosuppression. Samples for MPA PK and PD evaluations were collected predose and at 1, 2 and 13 weeks posttransplant. Plasma concentrations of MPA were determined by HPLC-UV. Activity of inosine monophosphate dehydrogenase (IMPDH and the expressions of two IMPDH isoforms were measured in CD4+ cells by HPLC-UV and real-time reverse-transcription PCR, respectively. Subsets of T cells were characterized by flow cytometry. Results The MPA exposure tended to be higher among belatacept patients than in CsA patients at week 1 (P = 0.057. Further, MPA concentrations (AUC0–9 h and C0 increased with time in both groups and were higher at week 13 than at week 2 (P = 0.031, n = 6. In contrast to the postdose reductions of IMPDH activity observed early posttransplant, IMPDH activity within both treatment groups was elevated throughout the dosing interval at week 13. Transient postdose increments were also observed for IMPDH1 expression, starting at week 1. Higher MPA exposure was associated with larger elevations of IMPDH1 (r = 0.81, P = 0.023, n = 7 for MPA and IMPDH1 AUC0–9 h at week 1. The maximum IMPDH1 expression was 52 (13–177% higher at week 13 compared to week 1 (P = 0.031, n = 6. One patient showed lower MPA exposure with time and did neither display elevations of IMPDH activity nor IMPDH1 expression. No difference was observed in T cell subsets between treatment groups. Conclusion The

  14. Dynamic Increase Factors for High Performance Concrete in Compression using Split Hopkinson Pressure Bar

    DEFF Research Database (Denmark)

    Riisgaard, Benjamin; Ngo, Tuan; Mendis, Priyan

    2007-01-01

    This paper provides dynamic increase factors (DIF) in compression for two different High Performance Concretes (HPC), 100 MPa and 160 MPa, respectively. In the experimental investigation 2 different Split Hopkinson Pressure Bars are used in order to test over a wide range of strain rates, 100 sec1...... to 700 sec-1. The results are compared with the CEB Model Code and the Spilt Hopkinson Pressure Bar technique is briefly de-scribed....

  15. supplementary2.docx

    Indian Academy of Sciences (India)

    aaa

    Figure S1. SEM micrographs of(a) PVC and (b) TiO2@PVC-5%nanocomposite film. Table S3. Tensile strength and Young's modulusof PVC and TiO2@PVC nanocomposite film. Sample, Tensile Strength (MPa), Young's modulus (MPa). PVC, 20.26, 580.27. TiO2@PVC-5%, 29.56, 601.93. TiO2@PVC-10%, 40.52, 841.77 ...

  16. 高強度材料を用いたRC部材の終局せん断耐力

    OpenAIRE

    中澤, 淳; 蒲原, 裕一; 南, 宏一; ナカザワ, アツシ; カンバラ, ユウイチ; ミナミ, コウイチ; Atsushi, NAKAZAWA; Yuichi, KANBARA; Koichi, MINAMI

    2003-01-01

    In this paper, it examines the shear failure properties about of RC members with high strength concrete and shear reinforcement. Systematic tests which combined high strength shear reinforcement, super high strength concrete(σ wy=785 1275MPa) and concrete of various strength including high strength (Fc=21~100MPa) were carried out. Ultimate shear strength can not be estimated by the prcvious design code. Then, we proposed new evaluation method of applying Minami and Wakabayashi theory. Evaluat...

  17. Fatigue Behavior of Long and Short Cracks in Wrought and Powder Aluminum Alloys.

    Science.gov (United States)

    1984-05-01

    The effects of cyclic frequency, electrochemical potential and bulk solution composition on the kinetics of small corrosion fatigue cracks have not...threshold behavior between cast iron (co = 113 MPa) and maraging steel (co = 1906 MPa), as a function of surface roughness (to simulate crack size) (after...4130 steel the crack size effect on corrosion fatigue, Fig. 2, is predicted in part based on linear superposition of stress corrosion growth rates for

  18. Design Structure Matrix (DSM) Methods and Applications for Naval Ship Design

    Science.gov (United States)

    2013-05-23

    Fax: 817-257-7227 E-mail: t.browninufetcu.edu Web : www. t vsonbrown i ng. com Administrative/Business Contact: Mrs. Teresa Miles Hendrix, MPA...mail: t.browninu(ajtcii.edu Web : www.tvsonbrownina.com Administrative/Business Contact: Mrs. Teresa Miles Hendrix, MPA Assistant Director of...STAKEHOLDER COM ABORDAGEM DE SISTEMAS ADAPTATIVOS A COMPLEXIDADE John Findlay, Ph D. e Abby Straus, M. Div. IMPLEMENTANDO FLEXIBILIDADE

  19. Inactivation of Vibrio parahaemolyticus in hard clams (Mercanaria mercanaria) by high hydrostatic pressure (HHP) and the effect of HHP on the physical characteristics of hard clam meat.

    Science.gov (United States)

    Mootian, Gabriel K; Flimlin, George E; Karwe, Mukund V; Schaffner, Donald W

    2013-02-01

    Shellfish may internalize dangerous pathogens during filter feeding. Traditional methods of depuration have been found ineffective against certain pathogens. The objective was to explore high hydrostatic pressure (HHP) as an alternative to the traditional depuration process. The effect of HHP on the survival of Vibrio parahaemolyticus in live clams (Mercanaria mercanaria) and the impact of HHP on physical characteristics of clam meat were investigated. Clams were inoculated with up to 7 log CFU/g of a cocktail of V. parahaemolyticus strains via filter feeding. Clams were processed at pressures ranging from 250 to 552 MPa for hold times ranging between 2 and 6 min. Processing conditions of 450 MPa for 4 min and 350 MPa for 6 min reduced the initial concentration of V. parahaemolyticus to a nondetectable level (5 log reductions. The volume of clam meat (processed in shell) increased with negligible change in mass after exposure to pressure at 552 MPa for 3 min, while the drip loss was reduced. Clams processed at 552 MPa were softer compared to those processed at 276 MPa. However, all HHP processed clams were found to be harder compared to unprocessed. The lightness (L*) of the meat increased although the redness (a*) decreased with increasing pressure. Although high pressure-processed clams may pose a significantly lower risk from V. parahaemolyticus, the effect of the accompanied physical changes on the consumer's decision to purchase HHP clams remains to be determined. Shellfish may contain dangerous foodborne pathogens. Traditional methods of removing those pathogen have been found ineffective against certain pathogens. The objective of this research was to determine the effect of high hydrostatic pressure on V. parahaemolyticus in clams. Processing conditions of 450 MPa for 4 min and 350 MPa for 6 min reduced the initial concentration of V. parahaemolyticus to a nondetectable level, achieving >5 log reductions. © 2013 Institute of Food Technologists®

  20. Culturable prokaryotic diversity of deep, gas hydrate sediments: first use of a continuous high-pressure, anaerobic, enrichment and isolation system for subseafloor sediments (DeepIsoBUG)

    OpenAIRE

    Parkes, R John; Sellek, Gerard; Webster, Gordon; Martin, Derek; Anders, Erik; Weightman, Andrew J; Sass, Henrik

    2009-01-01

    Deep subseafloor sediments may contain depressurization-sensitive, anaerobic, piezophilic prokaryotes. To test this we developed the DeepIsoBUG system, which when coupled with the HYACINTH pressure-retaining drilling and core storage system and the PRESS core cutting and processing system, enables deep sediments to be handled without depressurization (up to 25 MPa) and anaerobic prokaryotic enrichments and isolation to be conducted up to 100 MPa. Here, we describe the system and its first use...