WorldWideScience

Sample records for monopropellant gas generator

  1. Monopropellant engine investigation for space shuttle reaction control. Volume 2: Design, fabrication, and demonstration test of a catalytic gas generator for the space shuttle APU

    Science.gov (United States)

    1975-01-01

    The capability of a catalytic gas generator to meet the requirement specified for the space shuttle APU is established. A full-scale gas generator, designed to operate at a chamber pressure of 750 psia and a flow rate of 0.36 lbm/sec, was fabricated and subjected to three separate life test series. The nickel foam metal used for catalyst retention was investigated. Inspection of the foam metal following the first life test revealed significant degradation. Consequently an investigation was conducted to determine the mechanism of degradation and to provide an improved foam metal.

  2. Combustion of Han-Based Monopropellant Droplets in Reduced Gravity

    Science.gov (United States)

    Shaw, B. D.

    1999-01-01

    The objective of this research is to study combustion of monopropellant droplets and monopropellant droplet components in reduced-gravity environments so that spherical symmetry is strongly promoted. The experiments will use hydroxylammonium nitrate (HAN, chemical formula NH3OHNO3) based monopropellants. This class of monopropellant is selected for study because of its current relevance and also because it is relatively benign and safe to work with. The experimental studies will allow for accurate determination of fundamental data on deflagration rates, gas-phase temperature profiles, transient gas-phase flame behaviors, the onset of bubbling in droplets at lower pressures, and the low-pressure deflagration limit. The theoretical studies will provide rational models of deflagration mechanisms of HAN-based liquid propellants. Besides advancing fundamental knowledge, the proposed research should aid in applications (e.g., spacecraft thrusters and liquid propellant guns) of this unique class of monopropellants.

  3. Sensitivity of Liquid Monopropellants to Compression Ignition

    Science.gov (United States)

    1982-06-01

    contains a Silicon Rubber Septum through which a Gas Ullage Syringe,i.e., hypodermic needle , passes to introduce a precise loading of air ullage (volume...dumbbell by use of a hypodermic needle during the pre-fill procedure. Both head and rear of the dumbbell are fitted with "O"-ring seals. Thus, should...ignition tests support this theory . Again, returning to Figure 29, the response of a rapid-load pre-pressurized NOS-365 liquid monopropellant nharge (p

  4. Liquid propellant gas generators

    Science.gov (United States)

    1972-01-01

    The design of gas generators intended to provide hot gases for turbine drive is discussed. Emphasis is placed on the design and operation of bipropellant gas generators because of their wider use. Problems and limitations involved in turbine operation due to temperature effects are analyzed. Methods of temperature control of gas turbines and combustion products are examined. Drawings of critical sections of gas turbines to show their operation and areas of stress are included.

  5. Non-Toxic HAN Monopropellant Propulsion Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Non-toxic monopropellants have been developed that provide better performance than toxic hydrazine. Formulations based on hydroxylammonium nitrate (HAN) have...

  6. Non-Toxic HAN Monopropellant Propulsion Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Non-toxic monopropellants have been developed that provide better performance than toxic hydrazine. Formulations based on hydroxylammonium nitrate (HAN) have...

  7. Technology status of HNF-based monopropellants for satellite propulsion

    NARCIS (Netherlands)

    Marée, A.G.M.; Moerel, J.L.P.A.; Weiland-Veltmans, W.H.M.; Wierkx, F.J.M.; Zevenbergen, J.

    2004-01-01

    This paper reports on significant technological progress made over the last few years in determining the feasibility of HNF-based monopropellants. An HNF-based monopropellant is an interesting alternative for hydrazine as monopropellant for satellite propulsion. New non-toxic monopropellants based o

  8. Technology status of HNF-based monopropellants for satellite propulsion

    NARCIS (Netherlands)

    Marée, A.G.M.; Moerel, J.L.P.A.; Weiland-Veltmans, W.H.M.; Wierkx, F.J.M.; Zevenbergen, J.

    2004-01-01

    This paper reports on significant technological progress made over the last few years in determining the feasibility of HNF-based monopropellants. An HNF-based monopropellant is an interesting alternative for hydrazine as monopropellant for satellite propulsion. New non-toxic monopropellants based o

  9. High-Performance Monopropellants and Catalysts Evaluated

    Science.gov (United States)

    Reed, Brian D.

    2004-01-01

    The NASA Glenn Research Center is sponsoring efforts to develop advanced monopropellant technology. The focus has been on monopropellant formulations composed of an aqueous solution of hydroxylammonium nitrate (HAN) and a fuel component. HAN-based monopropellants do not have a toxic vapor and do not need the extraordinary procedures for storage, handling, and disposal required of hydrazine (N2H4). Generically, HAN-based monopropellants are denser and have lower freezing points than N2H4. The performance of HAN-based monopropellants depends on the selection of fuel, the HAN-to-fuel ratio, and the amount of water in the formulation. HAN-based monopropellants are not seen as a replacement for N2H4 per se, but rather as a propulsion option in their own right. For example, HAN-based monopropellants would prove beneficial to the orbit insertion of small, power-limited satellites because of this propellant's high performance (reduced system mass), high density (reduced system volume), and low freezing point (elimination of tank and line heaters). Under a Glenn-contracted effort, Aerojet Redmond Rocket Center conducted testing to provide the foundation for the development of monopropellant thrusters with an I(sub sp) goal of 250 sec. A modular, workhorse reactor (representative of a 1-lbf thruster) was used to evaluate HAN formulations with catalyst materials. Stoichiometric, oxygen-rich, and fuelrich formulations of HAN-methanol and HAN-tris(aminoethyl)amine trinitrate were tested to investigate the effects of stoichiometry on combustion behavior. Aerojet found that fuelrich formulations degrade the catalyst and reactor faster than oxygen-rich and stoichiometric formulations do. A HAN-methanol formulation with a theoretical Isp of 269 sec (designated HAN269MEO) was selected as the baseline. With a combustion efficiency of at least 93 percent demonstrated for HAN-based monopropellants, HAN269MEO will meet the I(sub sp) 250 sec goal.

  10. Development and Testing of a Green Monopropellant Ignition System

    Science.gov (United States)

    Whitmore, Stephen A.; Merkley, Daniel P.; Eilers, Shannon D.; Judson, Michael I.; Taylor, Terry L.

    2013-01-01

    This paper will detail the development and testing of a "green" monopropellant booster ignition system. The proposed booster ignition technology eliminates the need for a pre-heated catalyst bed, a high wattage power source, toxic pyrophoric ignition fluids, or a bi-propellant spark ignitor. The design offers the simplicity of a monopropellant feed system features non-hazardous gaseous oxygen (GOX) as the working fluid. The approach is fundamentally different from all other "green propellant" solutions in the aerospace in the industry. Although the proposed system is more correctly a "hybrid" rocket technology, since only a single propellant feed path is required, it retains all the simple features of a monopropellant system. The technology is based on the principle of seeding an oxidizing flow with a small amount of hydrocarbon.1 The ignition is initiated electrostatically with a low-wattage inductive spark. Combustion gas byproducts from the hydrocarbon-seeding ignition process can exceed 2400 C and the high exhaust temperature ensures reliable main propellant ignition. The system design is described in detail in the Hydrocarbon-Seeded Ignition System Design subsection.

  11. Investigation of a catalytic gas generator for the Space Shuttle APU. [hydrazine Auxiliary Propulsion Unit

    Science.gov (United States)

    Emmons, D. L.; Huxtable, D. D.; Blevins, D. R.

    1974-01-01

    An investigation was conducted to establish the capability of a monopropellant hydrazine catalytic gas generator to meet the requirements specified for the Space Shuttle APU. Detailed analytical and experimental studies were conducted on potential problem areas including long-term nitriding effects on materials, design variables affecting catalyst life, vehicle vibration effects, and catalyst oxidation/contamination. A full-scale gas generator, designed to operate at a chamber pressure of 750 psia and a flow rate of 0.36 lbm/sec, was fabricated and subjected to three separate life test series. The objective of the first test series was to demonstrate the capability of the gas generator to successfully complete 20 simulated Space Shuttle missions in steady-state operation. The gas generator was then refurbished and subjected to a second series of tests to demonstrate the pulse-mode capability of the gas generator during 20 simulated missions. The third series of tests was conducted with a refurbished reactor to further demonstrate pulse-mode capability with a modified catalyst bed.

  12. Nontoxic Hydroxylammonium Nitrate (HAN) Monopropellant Propulsion

    Science.gov (United States)

    McKechnie, Timothy N.

    2015-01-01

    Nontoxic monopropellants have been developed that provide better performance than toxic hydrazine. Formulations based on HAN have superior performance as compared to hydrazine with enhanced specific impulse (Isp), higher density and volumetric impulse, lower melting point, and much lower toxicity. However, HAN-based monopropellants require higher chamber temperatures (2,083 K vs. 883 K) to combust. Current hydrazine-based combustion chamber technology (Inconel® or niobium C103 and silicide coating) and catalyst (Shell 405) are inadequate. In Phase I, state-of-the-art iridium-lined rhenium chambers and innovative new foam catalysts were demonstrated in pulse and 10-second firings. Phase II developed and tested a flight-weight thruster for an environmentally green monopropellant.

  13. High Performance Monopropellants for Future Planetary Ascent Vehicles Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Physical Sciences Inc. proposes to design, develop, and demonstrate, a novel high performance monopropellant for application in future planetary ascent vehicles. Our...

  14. Thermal-Catalytic Ignition Source for Ionic Liquid Monopropellants Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Ultramet recently demonstrated rapid, reliable, and repeated ignition of hydroxylammonium nitrate (HAN)-hydroxyethylhydrazinium nitrate (HEHN) monopropellant...

  15. Highly Durable Catalysts for Ignition of Advanced Monopropellants Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This proposed SBIR Phase I addresses the development of catalysts and technology for the ignition of advanced monopropellants consisting of mixtures of...

  16. Formulation and Characterization of ADN-Based Liquid Monopropellants

    Science.gov (United States)

    Wingborg, N.; Eldsäter, C.; Skifs, H.

    2004-10-01

    Ternary ionic solutions are promising green propellants to replace monopropellant hydrazine. Ammonium dinitramide, ADN, is well suited as oxidizer in these propellants due to its high solubility. This paper presents the formulation of different ADN-based liquid monopropellants and the characterization of their properties such as stability, density, viscosity and sensitivity. To be able to use ADN-based monopropellants for propulsion applications, ADN must be produced in a way to minimize the effect on the environment and in sufficient quantities. This paper thus also briefly presents the industrial production of ADN in Sweden and the efforts made to optimize the process.

  17. Highly Durable Catalysts for Ignition of Advanced Monopropellants Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Monopropellants are readily ignited or decomposed over a bed of solid catalyst. A serious limitation of existing catalysts in the ignition of advanced...

  18. Advanced Ionic Liquid Monopropellant for Payload Ascent Vehicles Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to develop a monopropellant replacement for hydrazine using eutectic mixtures of ionic liquids (EILs). These liquids offer us the ability to tailor fluid...

  19. High Performance Thrusters for Advanced Green Monopropellants Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The development of an advanced green monopropellant propulsion system could have significant benefits to a wide range of NASA space missions, from deep space...

  20. Lightweight Pump Technology for Advanced Green Monopropellants Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Systima will develop an innovative light weight self-pressurizing pump (SPP) technology to provide a constant-pressure supply of monopropellant to a spacecraft or...

  1. Integrated Advanced Monopropellant CMC Thruster / Thermal Stand-Off Assembly Project

    Data.gov (United States)

    National Aeronautics and Space Administration — High performance non-toxic monopropellants offer significant benefits relative to the current state-of-the-art. The benefits of these advanced monopropellants (AMP)...

  2. Non-Catalytic Ignition System for High Performance Advanced Monopropellant Thrusters Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Systima Technologies, Inc. is developing a non-catalytic ignition technology for advanced green ionic salt monopropellants such as HAN-based monopropellant AF-M315E....

  3. Gliding arc plasma assisted N2O dissociation for monopropellant propulsion

    Science.gov (United States)

    Bosi, Franco J.; Dobrynin, Danil

    2017-01-01

    In this paper we address the capability of gliding arc (GA) discharges to promote plasma assisted combustion of nitrous oxide gas (N2O) for spacecraft monopropellant thruster applications. N2O is a ‘green’ propellant with interesting properties, but highly inert when used as monopropellant. Higher vibrational temperatures {{T}\\text{v}}>T , and hot spot localized dissociation, achieved within the GA reactor, are able to promote combustion of the gas. The vibrational temperature of the N2 second positive system is estimated by means of optical emission spectroscopy and reaches 5000 K, while the gas temperature reaches 1500 K the degree of N2O decomposition, estimated by FTIR measurements, ranged from 25 to 85%. A kinetic model for N2O dissociation is developed; the model shows that simply heating the gas in the same conditions is not enough to produce appreciable dissociation, providing further evidence of the catalytic action of the plasma. Results allow us to predict the propulsive efficiencies to be about 43%, with a thrust level of 37 mN; this result compares positively with the existing N2O resistojet technology.

  4. The Chemistry of Flammable Gas Generation

    Energy Technology Data Exchange (ETDEWEB)

    ZACH, J.J.

    2000-10-30

    The document collects information from field instrumentation, laboratory tests, and analytical models to provide a single source of information on the chemistry of flammable gas generation at the Hanford Site. It considers the 3 mechanisms of formation: radiolysis, chemical reactions, and thermal generation. An assessment of the current models for gas generation is then performed. The results are that the various phenomena are reasonably understood and modeled compared to field data.

  5. Geometrical characterization and performance optimization of monopropellant thruster injector

    Directory of Open Access Journals (Sweden)

    T.R. Nada

    2012-12-01

    Full Text Available The function of the injector in a monopropellant thruster is to atomize the liquid hydrazine and to distribute it over the catalyst bed as uniformly as possible. A second objective is to place the maximum amount of catalyst in contact with the propellant in as short time as possible to minimize the starting transient time. Coverage by the spray is controlled mainly by cone angle and diameter of the catalyst bed, while atomization quality is measured by the Sauter Mean Diameter, SMD. These parameters are evaluated using empirical formulae. In this paper, two main types of injectors are investigated; plain orifice and full cone pressure swirl injectors. The performance of these two types is examined for use with blow down monopropellant propulsion system. A comprehensive characterization is given and design charts are introduced to facilitate optimizing the performance of the injector. Full-cone injector is a more suitable choice for monopropellant thruster and it might be available commercially.

  6. Final Report on the Detection of Green Monopropellants

    Science.gov (United States)

    Gibson, Tracy L.; DeVor, Robert W.; Bauer, Brint M.; Captain, James; Coutts, Janelle L.; Surma, Jan M.

    2015-01-01

    In 2014, National Aeronautics and Space Administration (NASA) Kennedy Space Center (KSC) funded a project titled "Familiarization and Detection of Green Monopropellants" utilizing Independent Research and Technology Development (IR&TD) and Center Innovation Fund (CIF) funding. The purpose of the project was to evaluate methods of detection for ammonium dinitramide (ADN) and hydroxylammonium nitrate (HAN). An Engineering Services Contract (ESC) task order was created with the scope of evaluation of several methods of detecting ADN- and HAN-based propellants, as well as development of methods for detection. Detection methods include developed methods such as colorimetric indicating absorbent socks, and commercial-off-the- shelf (COTS) units for ammonia detection. An additional goal of the task order was for ESC to become familiar with ADN's and HAN's material properties and material compatibility. Two approaches were initially investigated as possible methods for the detection of HAN (or AFM315E) and ADN (or LMP-103S). These approaches were colorimetric analysis and instrumentation-based COTS vapor sensors utilization. Initial testing showed that the relatively non-existent vapor pressure of the AF-M315E (of which HAN is a major component) propellant would make the use of COTS sensors difficult for real-time area monitoring of HAN; a small response was detected through the use of active COTS sensors, including the RAE Systems MultiRAE Lite and Drager X-act (registered) 5000, but the levels detected were below the threshold limit value for the toxic gas ammonia. Therefore, a detection system ased upon a colorimetric indicator impregnated into an absorbent material was developed. Preliminary analysis (ESC-245-FDG-001) identified a particularly outstanding candidate as a colorimetric indicator for the detection of the presence of AF-M315E in the form of a Methyl Red (Basic) indicator. Materials impregnated with this indicator exhibit significant color change and the

  7. Industrial benefits of applying HNF in monopropellant satellite propulsion

    NARCIS (Netherlands)

    Fick, M.; Schiebener, P.; Moerel, J.L.P.A.; Berg, R.P. van den; Sanders, H.M.; Welland-Veltmans, W.H.M.

    2001-01-01

    The benefits of advanced HNF monopropellants are discussed. The areas of consideration comprise the operational and performance aspects, the general handling, the benign less-toxic characteristics and the envisaged reduction of manufacturing, test and operational costs. The recently proposed develop

  8. Industrial benefits of applying HNF in monopropellant satellite propulsion

    NARCIS (Netherlands)

    Fick, M.; Schiebener, P.; Moerel, J.L.P.A.; Berg, R.P. van den; Sanders, H.M.; Welland-Veltmans, W.H.M.

    2001-01-01

    The benefits of advanced HNF monopropellants are discussed. The areas of consideration comprise the operational and performance aspects, the general handling, the benign less-toxic characteristics and the envisaged reduction of manufacturing, test and operational costs. The recently proposed develop

  9. NEXT GENERATION GAS TURBINE SYSTEMS STUDY

    Energy Technology Data Exchange (ETDEWEB)

    Benjamin C. Wiant; Ihor S. Diakunchak; Dennis A. Horazak; Harry T. Morehead

    2003-03-01

    Under sponsorship of the U.S. Department of Energy's National Energy Technology Laboratory, Siemens Westinghouse Power Corporation has conducted a study of Next Generation Gas Turbine Systems that embraces the goals of the DOE's High Efficiency Engines and Turbines and Vision 21 programs. The Siemens Westinghouse Next Generation Gas Turbine (NGGT) Systems program was a 24-month study looking at the feasibility of a NGGT for the emerging deregulated distributed generation market. Initial efforts focused on a modular gas turbine using an innovative blend of proven technologies from the Siemens Westinghouse W501 series of gas turbines and new enabling technologies to serve a wide variety of applications. The flexibility to serve both 50-Hz and 60-Hz applications, use a wide range of fuels and be configured for peaking, intermediate and base load duty cycles was the ultimate goal. As the study progressed the emphasis shifted from a flexible gas turbine system of a specific size to a broader gas turbine technology focus. This shift in direction allowed for greater placement of technology among both the existing fleet and new engine designs, regardless of size, and will ultimately provide for greater public benefit. This report describes the study efforts and provides the resultant conclusions and recommendations for future technology development in collaboration with the DOE.

  10. A Flue Gas Tube for Thermoelectric Generator

    DEFF Research Database (Denmark)

    2013-01-01

    The invention relates to a flue gas tube (FGT) (1) for generation of thermoelectric power having thermoelectric elements (8) that are integrated in the tube. The FTG may be used in combined heat and power (CHP) system (13) to produce directly electricity from waste heat from, e.g. a biomass boiler...

  11. Nitrous Oxide as a Green Monopropellant for Small Satellites

    Science.gov (United States)

    Wallbank, J.; Sermon, P.; Baker, A.; Courtney, L.; Sambrook, R.

    2004-10-01

    Nitrous oxide (N2O), has been suggested as a green monopropellant for hydrazine replacement [1,2]. It has extremely low toxicity and has a higher theoretical specific impulse (ISP) than 90% hydrogen peroxide (HTP): N2O ISP(t)~206s, HTP ISP(t)~180s [3]. It has largely been overlooked though due to the difficulty involved in maintaining reproducible catalytic decomposition. The authors are developing N2O thruster technology to prove its viability as a monopropellant alternative to hydrazine. Towards this purpose the authors have developed a novel catalyst for the decomposition of N2O, that has high activity and is thermally stable in oxidising conditions. The catalyst is being engineered into a form to be used efficiently within the thruster housing. This paper reports on the development of this catalyst.

  12. Monopropellant Thruster Development Using a Family of Micro Reactors

    Science.gov (United States)

    2017-02-17

    SCALE IN MILES HWY 395 ROSAMOND BLVD...AVENUE E H IG H W AY 1 4 LA N C A S TE R B LV D . 14 0t h S TR E E T E A S T RESERVATION BOUNDARY 0 5 10 SCALE IN MILES HWY 395 ROSAMOND BLVD...Monopropellant Thrusters Physical Description • Small (~1-22N) Thrusters Used for Attitude Control and Maneuvering of Small Spacecraft. AF-M315E

  13. Development of a NASA standard gas generator

    Science.gov (United States)

    Bement, Laurence J.; Karp, Harold; Schimmel, Morry L.

    1993-01-01

    The goals of the NASA Standard Gas Generator (NSGG) Program are to create a NASA standard gas generating cartridge, characterize its performance, and make it readily available to users. A cartridge within the same envelope as the NASA Standard Initiator (NSI) has the greatest potential use. This potential use is described in viewgraph form. Our approach for NSGG development and qualification was planned to be conducted in several phases. Test methods were developed to evaluate output performance for a variety of potential applications. A feasibility study using modified NSI's was accomplished. Preliminary and final development will be conducted with a delta qualification to evaluate the effects of manufacturing lots and environments. Feasibility study results, feasibility study conclusions, and future plans are presented.

  14. Gas Generation from Actinide Oxide Materials

    Energy Technology Data Exchange (ETDEWEB)

    George Bailey; Elizabeth Bluhm; John Lyman; Richard Mason; Mark Paffett; Gary Polansky; G. D. Roberson; Martin Sherman; Kirk Veirs; Laura Worl

    2000-12-01

    This document captures relevant work performed in support of stabilization, packaging, and long term storage of plutonium metals and oxides. It concentrates on the issue of gas generation with specific emphasis on gas pressure and composition. Even more specifically, it summarizes the basis for asserting that materials loaded into a 3013 container according to the requirements of the 3013 Standard (DOE-STD-3013-2000) cannot exceed the container design pressure within the time frames or environmental conditions of either storage or transportation. Presently, materials stabilized and packaged according to the 3013 Standard are to be transported in certified packages (the certification process for the 9975 and the SAFKEG has yet to be completed) that do not rely on the containment capabilities of the 3013 container. Even though no reliance is placed on that container, this document shows that it is highly likely that the containment function will be maintained not only in storage but also during transportation, including hypothetical accident conditions. Further, this document, by summarizing materials-related data on gas generation, can point those involved in preparing Safety Analysis Reports for Packages (SARPs) to additional information needed to assess the ability of the primary containment vessel to contain the contents and any reaction products that might reasonably be produced by the contents.

  15. 21 CFR 866.2580 - Gas-generating device.

    Science.gov (United States)

    2010-04-01

    ...) MEDICAL DEVICES IMMUNOLOGY AND MICROBIOLOGY DEVICES Microbiology Devices § 866.2580 Gas-generating device. (a) Identification. A gas-generating device is a device intended for medical purposes that...

  16. New high-nitrogen energetic materials for gas generators in space ordnance

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, M.S.; Lee, Kien-Yin; Hiskey, M.A.

    1995-08-01

    High-nitrogen nitroheterocyclic energetic compounds are used as explosives, propellants, and gas generants when safe, thermally stable, cool-burning energetic materials are desired. A series of compounds are compared for sensitivity properties and calculated burn performance. Thermodynamic equilibrium calculations by NASA/Lewis rocket propellant and Blake gun propellant codes gave flame temperatures, average molecular weight, and identity of the equilibrium burn products for ambient, rocket, and gun pressure environments. These compounds were subjected to calculations both as monopropellants and as 50/50 weight ratio mixtures with ammonium nitrate (AN). Special attention was paid to calculated toxic products such as carbon monoxide and hydrogen cyanide, and how these were affected by the addition of an oxidizer AN. Several compounds were noted for further calculations of a formulation ad experimental evaluation.

  17. Multidisciplinary Design Optimization and Analysis of Hydrazine Monopropellant Propulsion System

    Directory of Open Access Journals (Sweden)

    Amirhossein Adami

    2015-01-01

    Full Text Available Monopropellant propulsion systems are widely used especially for low cost attitude control or orbit correction (orbit maintenance. To optimize the total propulsion system, subsystems should be optimized. Chemical decomposition, aerothermodynamics, and structure disciplines demand different optimum condition such as tank pressure, catalyst bed length and diameter, catalyst bed pressure, and nozzle geometry. Subsystem conflicts can be solved by multidisciplinary design optimization (MDO technique with simultaneous optimization of all subsystems with respect to any criteria and limitations. In this paper, monopropellant propulsion system design algorithm is presented and the results of the proposed algorithm are validated. Then, multidisciplinary design optimization of hydrazine propulsion system is proposed. The goal of optimization can be selected as minimizing the total mass (including propellant, minimizing the propellant mass (maximizing the Isp, or minimizing the dry mass. Minimum total mass, minimum propellant mass, and minimum dry mass are derived using MDO technique. It is shown that minimum total mass, minimum dry mass, and minimum propellant mass take place in different conditions. The optimum parameters include bed-loading, inlet pressure, mass flow, nozzle geometry, catalyst bed length and diameter, propellant tank mass, specific impulse (Isp, and feeding mass which are derived using genetic algorithm (GA.

  18. Lifetime Improvement of Large Scale Green Monopropellant Thrusters via Novel, Long-Life Catalysts Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Busek proposes to develop and life-test a flight-weight, 5N class green monopropellant thruster in Phase II. The most important feature that sets this thruster apart...

  19. Lifetime Improvement of Large Scale Green Monopropellant Thrusters via Novel, Long-Life Catalysts Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Busek proposes to develop a high performance, non-toxic storable, "green" monopropellant thruster suitable for in-space reaction control propulsion. The engine will...

  20. Banshan Gas-Fired Turbine Generator Set Put into Operation

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    @@ No.1 generator set of Banshan gas-fired power generation project, which is the first 9 FA heavy-duty gas turbine generator set in China that has drawn much attention, was successfully put into operation and merged into power grid at 21:30 in June 2, three months ahead of schedule.

  1. Heat Recovery From Tail Gas Incineration To Generate Power

    Energy Technology Data Exchange (ETDEWEB)

    Tawfik, Tarek

    2010-09-15

    Many industrial processes result in tail gas wastes that must be flared or incinerated to abide with environmental guidelines. Tail gas incineration occurs in several chemical processes resulting in high-temperature exhaust gas that simply go to the stack, thus wasting all that valuable heat! This paper discusses useful heat recovery and electric power generation utilizing available heat in exhaust gas from tail gas incinerators. This heat will be recovered in a waste-heat recovery boiler that will produce superheated steam to expand in a steam turbine to generate power. A detailed cost estimate is presented.

  2. NEXT GENERATION GAS TURBINE (NGGT) SYSTEMS STUDY

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2001-12-05

    to how they could serve multiple applications, both in terms of incorporation of technology into current products, as well as to an NGGT product. In summary, potential program costs are shown for development of the candidate systems along with the importance of future DOE enabling participation. Three main conclusions have been established via this study: (1) Rapid recent changes within the power generation regulatory environment and the resulting ''bubble'' of gas turbine orders has altered the timing and relative significance associated with the conclusions of the ADL study upon which the original DOE NGGT solicitation was based. (2) Assuming that the relevant technologies were developed and available for an NGGT market opportunity circa 2010, the top candidate system that meets or exceeds the DOE PRDA requirements was determined to be a hybrid aero-derivative/heavy duty concept. (3) An investment by DOE of approximately $23MM/year to develop NGGT technologies near/mid term for validation and migration into a reasonable fraction of the installed base of GE F-class products could be leveraged into $1.2B Public Benefit, with greatest benefits resulting from RAM improvements. In addition to the monetary Public Benefit, there is also significant benefit in terms of reduced energy consumption, and reduced power plant land usage.

  3. Gas-fired Power Generation in India: Challenges and opportunities

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    India's fast growing economy needs to add 100,000 MW power generating capacity between 2002-2012. Given limitations to the use of coal in terms of environmental considerations, quality and supply constraints, gas is expected to play an increasingly important role in India's power sector. This report briefs NMC Delegates on the potential for gas-fired power generation in India and describes the challenges India faces to translate the potential for gas-fired power generation into reality.

  4. Gas-fired Power Generation in India: Challenges and opportunities

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    India's fast growing economy needs to add 100,000 MW power generating capacity between 2002-2012. Given limitations to the use of coal in terms of environmental considerations, quality and supply constraints, gas is expected to play an increasingly important role in India's power sector. This report briefs NMC Delegates on the potential for gas-fired power generation in India and describes the challenges India faces to translate the potential for gas-fired power generation into reality.

  5. Lifecycle greenhouse gas emissions of coal, conventional and unconventional natural gas for electricity generation

    Science.gov (United States)

    An analysis of the lifecycle greenhouse gas (GHG) emissions associated with natural gas use recently published by Howarth et al. (2011) stated that use of natural gas produced from shale formations via hydraulic fracturing would generate greater lifecycle GHG emissions than petro...

  6. Gas generation from transuranic waste degradation: data summary and interpretation

    Energy Technology Data Exchange (ETDEWEB)

    Molecke, M.A.

    1979-12-01

    A comprehensive review of all applicable gas generation data resulting from the degradation of existing and potential forms of transuranic-contaminated wastes is presented. Extensive experimental studies have been performed under both realistic environmental conditions expected in the Waste Isolation Pilot Plant and overtest conditions. Degradation mechanisms investigated were radiolysis, thermal decomposition and dewatering, bacterial action, and chemical corrosion. Waste matrices studied include cellulosics, plastics, rubbers, organic composite, concrete-TRU ash, asphalt, process sludges, and mild steel. Measured gas generation rates are presented in terms of gas moles/year/drum of waste and in G(gas) values for radiolysis. The effects of multiple variables on gas generation are also described. 7 figures, 15 tables.

  7. Advanced On Board Inert Gas Generation System (OBBIGS) Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Valcor Engineering Corporation proposes to develop an advanced On Board Inert Gas Generation System, OBIGGS, for aircraft fuel tank inerting to prevent hazardous...

  8. Gas Generation from K East Basin Sludges - Series II Testing

    Energy Technology Data Exchange (ETDEWEB)

    Bryan, Samuel A.; Delegard, Calvin H.; Schmidt, Andrew J.; Sell, Rachel L.; Silvers, Kurt L.; Gano, Susan R.; Thornton, Brenda M.

    2001-03-14

    This report describes work to examine the gas generation behavior of actual K East (KE) Basin floor, pit and canister sludge. Mixed and unmixed and fractionated KE canister sludge were tested, along with floor and pit sludges from areas in the KE Basin not previously sampled. The first report in this series focused on gas generation from KE floor and canister sludge collected using a consolidated sampling technique. The third report will present results of gas generation testing of irradiated uranium fuel fragments with and without sludge addition. The path forward for management of the K Basin Sludge is to retrieve, ship, and store the sludge at T Plant until final processing at some future date. Gas generation will impact the designs and costs of systems associated with retrieval, transportation and storage of sludge.

  9. Generation of Local Concentration Gradients by Gas-Liquid Contacting

    NARCIS (Netherlands)

    de Jong, J.; Verheijden, Pascal W.; Lammertink, Rob G.H.; Wessling, Matthias

    2008-01-01

    We present a generic concept to create local concentration gradients, based on the absorption of gases or vapors in a liquid. A multilayer microfluidic device with crossing gas and liquid channels is fabricated by micromilling and used to generate multiple gas-liquid contacting regions, separated by

  10. Applications for Solid Propellant Cool Gas Generator Technology

    Science.gov (United States)

    van der List, M.; van Vliet, L. D.; Sanders, H. M.; Put, P. A. G.; Elst, J. W. E. C.

    2004-10-01

    In 2002 and 2003, Bradford Engineering B.V. conducted, in corporation with the Dutch research institute TNO Prins Maurits Laboratory (PML) a SME study for ESA-ESTEC for the identification of spaceflight applications and on-ground demonstration of Solid Propellant Cool Gas Generator (SPCGG) technology. This innovative technology has been developed by TNO-PML while Bradford Engineering also brought in its experience in spaceflight hardware development and manufacturing. The Solid Propellant Cool Gas Generator (SPCGG) technology allows for pure gas generation at ambient temperatures, as opposed to conventional solid propellant gas generators. This makes the SPCGG technology interesting for a wide range of terrestrial spaceflight applications. During the first part of the study, a variety of potential applications have been identified and three applications were selected for a more detailed quantitative study. In the third phase a ground demonstration was performed successfully for a cold gas propulsion system application. During the actual demonstration test, 10 cool gas generators were mounted and all operated successfully in sequence, demonstrating good repeatability of the produced amount of gas and pressure.

  11. NEW APPROACH TO ADDRESSING GAS GENERATION IN RADIOACTIVE MATERIAL PACKAGING

    Energy Technology Data Exchange (ETDEWEB)

    Watkins, R; Leduc, D; Askew, N

    2009-06-25

    Safety Analysis Reports for Packaging (SARP) document why the transportation of radioactive material is safe in Type A(F) and Type B shipping containers. The content evaluation of certain actinide materials require that the gas generation characteristics be addressed. Most packages used to transport actinides impose extremely restrictive limits on moisture content and oxide stabilization to control or prevent flammable gas generation. These requirements prevent some users from using a shipping container even though the material to be shipped is fully compliant with the remaining content envelope including isotopic distribution. To avoid these restrictions, gas generation issues have to be addressed on a case by case basis rather than a one size fits all approach. In addition, SARP applicants and review groups may not have the knowledge and experience with actinide chemistry and other factors affecting gas generation, which facility experts in actinide material processing have obtained in the last sixty years. This paper will address a proposal to create a Gas Generation Evaluation Committee to evaluate gas generation issues associated with Safety Analysis Reports for Packaging material contents. The committee charter could include reviews of both SARP approved contents and new contents not previously evaluated in a SARP.

  12. A microfluidic chip for generating reactive plasma at gas-gas interface formed in laminar flow

    Science.gov (United States)

    Hashimoto, Masahiro; Tsukasaki, Katsuki; Kumagai, Shinya; Sasaki, Minoru

    2015-01-01

    A gas-gas interface is used for generating a localized reactive plasma flow at an atmospheric pressure. A microfluidic chip is fabricated as the reactor integrating a small plasma source located upstream. Within a Y-shaped microchannel, a discharging gas flows with a chemical gas. Owing to the small width of the microchannel, the gas flow is stabilized in a laminar flow. The resultant gas-gas interface is formed in the area where two gases flow facing each other activating the chemical gas through the energetic species in the discharging gas. A characteristic stream pattern is observed as the etching profile of a carbon film with a sub-µm sharp step change that can be explained by the spatial distribution of the reactive oxygen. This etching profile is different from that obtained when plasma discharging occurs near the channel exit being affected by the turbulent flow.

  13. Gas Generation of Heated PBX 9502

    Energy Technology Data Exchange (ETDEWEB)

    Holmes, Matthew David [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Parker, Gary Robert [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-10-07

    Uniaxially pressed samples of PBX 9502 were heated until self-ignition (cookoff) in order to collect pressure and temperature data relevant for model development. Samples were sealed inside a small gas-tight vessel, but were mechanically unconfined. Long-duration static pressure rise, as well as dynamic pressure rise during the cookoff event, were recorded. Time-lapse photography of the sample was used to measure the thermal expansion of the sample as a function of time and temperature. High-speed videography qualitatively characterized the mechanical behavior and failure mechanisms at the time of cookoff. These results provide valuable input to modeling efforts, in order to improve the ability to predict pressure output during cookoff as well as the effect of pressure on time-toignition.

  14. Chemical looping reforming of generator gas

    Energy Technology Data Exchange (ETDEWEB)

    Mendiara, T.; Jensen, Anker; Glarborg, P.

    2010-02-15

    The main objective of this work is to investigate the carbon deposition during reforming of hydrocarbons in a Chemical Looping Reformer (CLR). This knowledge is needed to asses the viability of the CLR technology in reforming tar from biomass gasification preserving lighter hydrocarbons and minimizing the carbon formation during the process. Two different setups were used to test the reactivity of the different samples in the conditions of interest for the tar reforming process: 1) Fixed bed flow reactor (FR), and 2) Thermogravimetric analyzer (TGA). In the experiments, the gas atmosphere was switched from reducing to oxidizing atmosphere in every cycle. During the oxidizing cycle, the carrier was regenerated using a mixture of oxygen and nitrogen. Four different oxygen carriers based on nickel (Ni40 and Ni60), manganese (Mn) and ilmenite (Fe) were tested. In the tests, toluene was used to simulate the tars. The Fe and the Mn carrier reacted to a small extent with methane at the highest temperature studied, 800 degrees C. The Ni-carriers did not react at 600 degrees C at first, but they showed some reactivity after having been activated at the higher temperature. Carbon formation occurred with the Ni-carriers, more so with the Ni60 than the Ni40. Ni40, Mn and Fe were activated at the higher temperature. However, Fe showed only low capacity. Ni60 showed no capability of tar reforming. Ni40 showed a high tendency to carbon formation at 800 degrees C, but the formation could be lowered by changing some parameters. Mn formed almost no carbon. Ni40 and Mn were chosen for further studies. Carbon deposition occurred for both Ni40 and Mn, but the amount deposited for Ni40 was about 10 times bigger. Ni40 reacted with the methane and toluene only at 800 degrees C. The conversion over Mn was not as big as for toluene alone. Carbon was formed from carbon monoxide on the Ni40 carrier and on the Mn, but to a much less extent on the latter one. The presence of hydrogen decreased

  15. Generator gas as a fuel to power a diesel engine

    Directory of Open Access Journals (Sweden)

    Tutak Wojciech

    2014-01-01

    Full Text Available The results of gasification process of dried sewage sludge and use of generator gas as a fuel for dual fuel turbocharged compression ignition engine are presented. The results of gasifying showed that during gasification of sewage sludge is possible to obtain generator gas of a calorific value in the range of 2.15  2.59 MJ/m3. It turned out that the generator gas can be effectively used as a fuel to the compression ignition engine. Because of gas composition, it was possible to run engine with partload conditions. In dual fuel operation the high value of indicated efficiency was achieved equal to 35%, so better than the efficiency of 30% attainable when being fed with 100% liquid fuel. The dual fuel engine version developed within the project can be recommended to be used in practice in a dried sewage sludge gasification plant as a dual fuel engine driving the electric generator loaded with the active electric power limited to 40 kW (which accounts for approx. 50% of its rated power, because it is at this power that the optimal conditions of operation of an engine dual fuel powered by liquid fuel and generator gas are achieved. An additional advantage is the utilization of waste generated in the wastewater treatment plant.

  16. Gas generation in incinerator ash; Gasbildning i aska

    Energy Technology Data Exchange (ETDEWEB)

    Arm, Maria; Lindeberg, Johanna; Rodin, Aasa; Oehrstroem, Anna; Backman, Rainer; Oehman, Marcus; Bostroem, Dan

    2006-02-15

    In recent years, explosions have occurred in certain phases of ash handling in Sweden. Investigations have revealed that hydrogen may have been present in all cases. The hydrogen is believed to be generated by chemical reactions of aluminium and other metals within the ash in the presence of water. The purpose with this study is to increase the knowledge of gas generation of incinerator ash. Thereby, guides for appropriate ash management can be introduced and the risk for further explosions prevented. The study has comprised analyses of the ash properties, such as chemical and physical composition and the pH, of ash from 14 incineration plants (mostly waste incineration plants). Different fractions of ash materials representing different parts of the process in each plant have been analysed. Furthermore, the fuel and the technical differences between the plants have been analysed. A tool for measuring the gas generation in the laboratory has been developed and the gas generation of the different ash materials at natural and increased pH was measured. Gas analyses and thermodynamic calculations have also been performed. The results showed that: bottom ash from fluidised bed boilers generated small amounts of gas at increased pH, much smaller amounts than the idle pass, cyclone and filter ash did, bottom ash from grate fired boilers generated more gas at increased pH than their cyclone ash and filter ash, with exception of the Linkoeping plant, all bio waste incineration plants generated ash with low gas generation potential, all fly ash materials with a gas generation potential of more than 10 l/kg originated from municipal waste incineration plants, filter ash that had been stored in oxygen rich environment generated significant less gas than fresh filter ash of the same origin, hardly any other gases were generated apart from hydrogen (very small amounts of acetone, furane, benzene and most likely methane were detected in some of the ash materials), there were no

  17. Reactive intermediates in the gas phase generation and monitoring

    CERN Document Server

    Setser, D W

    2013-01-01

    Reactive Intermediates in the Gas Phase: Generation and Monitoring covers methods for reactive intermediates in the gas phase. The book discusses the generation and measurement of atom and radical concentrations in flow systems; the high temperature flow tubes, generation and measurement of refractory species; and the electronically excited long-lived states of atoms and diatomic molecules in flow systems. The text also describes the production and detection of reactive species with lasers in static systems; the production of small positive ions in a mass spectrometer; and the discharge-excite

  18. First results of PRECISE—Development of a MEMS-based monopropellant micro chemical propulsion system

    NARCIS (Netherlands)

    Gauer, Markus; Telitschkin, Dimitri; Gotzig, Ulrich; Batonneau, Yann; Johansson, Hakan; Ivanov, Mikhail; Palmer, Phil; Wiegerink, Remco J.

    2014-01-01

    PRECISE focuses on the research and development of a MEMS-based monopropellant micro chemical propulsion system for highly accurate attitude control of satellites. The availability of such propulsion systems forms the basis for defining new mission concepts such as formation flying and rendezvous ma

  19. DEPSCOR06: A Dispersed Monopropellant Microslug Approach for Discrete Satellite Micropropulsion

    Science.gov (United States)

    2010-08-01

    be correspondingly reduced. In parallel, microfabrication efforts have produced a novel catalytic micro- reactor prototype for the monopropellant...characteristics of supersonic micro-nozzles Task #3 - Experimental design and fabrication of a catalytic micro- reactor using ruthenium-oxide...thruster. This system will make use of the steady, periodic formation of microslugs at a microchannel junction to allow finer resolution of impulse

  20. First results of PRECISE—Development of a MEMS-based monopropellant micro chemical propulsion system

    NARCIS (Netherlands)

    Gauer, Markus; Telitschkin, Dimitri; Gotzig, Ulrich; Batonneau, Yann; Johansson, Hakan; Ivanov, Mikhail; Palmer, Phil; Wiegerink, Remco J.

    PRECISE focuses on the research and development of a MEMS-based monopropellant micro chemical propulsion system for highly accurate attitude control of satellites. The availability of such propulsion systems forms the basis for defining new mission concepts such as formation flying and rendezvous

  1. Biomass & Natural Gas Based Hydrogen Fuel For Gas Turbine (Power Generation)

    Science.gov (United States)

    Significant progress has been made by major power generation equipment manufacturers in the development of market applications for hydrogen fuel use in gas turbines in recent years. Development of a new application using gas turbines for significant reduction of power plant CO2 e...

  2. Noble Gas Clusters and Nanoplasmas in High Harmonic Generation

    CERN Document Server

    Aladi, M; Rácz, P; Földes, I B

    2015-01-01

    We report a study of high harmonic generation from noble gas clusters of xenon atoms in a gas jet. Harmonic spectra were investigated as a function of backing pressure, showing spectral shifts due to the nanoplasma electrons in the clusters. At certain value of laser intensity this process may oppose the effect of the well-known ionization-induced blueshift. In addition, these cluster-induced harmonic redshifts may give the possibility to estimate cluster density and cluster size in the laser-gas jet interaction range.

  3. Harmonization of initial estimates of shale gas life cycle greenhouse gas emissions for electric power generation.

    Science.gov (United States)

    Heath, Garvin A; O'Donoughue, Patrick; Arent, Douglas J; Bazilian, Morgan

    2014-08-05

    Recent technological advances in the recovery of unconventional natural gas, particularly shale gas, have served to dramatically increase domestic production and reserve estimates for the United States and internationally. This trend has led to lowered prices and increased scrutiny on production practices. Questions have been raised as to how greenhouse gas (GHG) emissions from the life cycle of shale gas production and use compares with that of conventionally produced natural gas or other fuel sources such as coal. Recent literature has come to different conclusions on this point, largely due to differing assumptions, comparison baselines, and system boundaries. Through a meta-analytical procedure we call harmonization, we develop robust, analytically consistent, and updated comparisons of estimates of life cycle GHG emissions for electricity produced from shale gas, conventionally produced natural gas, and coal. On a per-unit electrical output basis, harmonization reveals that median estimates of GHG emissions from shale gas-generated electricity are similar to those for conventional natural gas, with both approximately half that of the central tendency of coal. Sensitivity analysis on the harmonized estimates indicates that assumptions regarding liquids unloading and estimated ultimate recovery (EUR) of wells have the greatest influence on life cycle GHG emissions, whereby shale gas life cycle GHG emissions could approach the range of best-performing coal-fired generation under certain scenarios. Despite clarification of published estimates through harmonization, these initial assessments should be confirmed through methane emissions measurements at components and in the atmosphere and through better characterization of EUR and practices.

  4. NASA Marshall Space Flight Center Tri-gas Thruster Performance Characterization

    Science.gov (United States)

    Dorado, Vanessa; Grunder, Zachary; Schaefer, Bryce; Sung, Meagan; Pedersen, Kevin

    2013-01-01

    Historically, spacecraft reaction control systems have primarily utilized cold gas thrusters because of their inherent simplicity and reliability. However, cold gas thrusters typically have a low specific impulse. It has been determined that a higher specific impulse can be achieved by passing a monopropellant fluid mixture through a catalyst bed prior to expulsion through the thruster nozzle. This research analyzes the potential efficiency improvements from using tri-gas, a mixture of hydrogen, oxygen, and an inert gas, which in this case is helium. Passing tri-gas through a catalyst causes the hydrogen and oxygen to react and form water vapor, ultimately heating the exiting fluid and generating a higher specific impulse. The goal of this project was to optimize the thruster performance by characterizing the effects of varying several system components including catalyst types, catalyst lengths, and initial catalyst temperatures.

  5. Efficient and Safe Chemical Gas Generators with Nanocomposite Reactive Materials

    Science.gov (United States)

    2015-11-30

    ammonia borane has been developed that involves the reaction of mechanically alloyed Al·Mg powder with water as a source of heat for ammonia borane...Edward L. Dreizin, Evgeny Shafirovich. Hydrogen generation from ammonia borane and water through combustion reactions with mechanically alloyed... Synthesis , 21 - 24 October 2013, South Padre Island, TX, p. 211. Rodriguez, D., Machado, M., Shafirovich, E., and Dreizin, E.L., “Gas Generating

  6. Durability Challenges for Next Generation of Gas Turbine Engine Materials

    Science.gov (United States)

    Misra, Ajay K.

    2012-01-01

    Aggressive fuel burn and carbon dioxide emission reduction goals for future gas turbine engines will require higher overall pressure ratio, and a significant increase in turbine inlet temperature. These goals can be achieved by increasing temperature capability of turbine engine hot section materials and decreasing weight of fan section of the engine. NASA is currently developing several advanced hot section materials for increasing temperature capability of future gas turbine engines. The materials of interest include ceramic matrix composites with 1482 - 1648 C temperature capability, advanced disk alloys with 815 C capability, and low conductivity thermal barrier coatings with erosion resistance. The presentation will provide an overview of durability challenges with emphasis on the environmental factors affecting durability for the next generation of gas turbine engine materials. The environmental factors include gaseous atmosphere in gas turbine engines, molten salt and glass deposits from airborne contaminants, impact from foreign object damage, and erosion from ingestion of small particles.

  7. Boiler and Pressure Balls Monopropellant Thermal Rocket Engine

    Science.gov (United States)

    Greene, William D. (Inventor)

    2009-01-01

    The proposed technology is a rocket engine cycle utilizing as the propulsive fluid a low molecular weight, cryogenic fluid, typically liquid hydrogen, pressure driven, heated, and expelled through a nozzle to generate high velocity and high specific impulse discharge gas. The proposed technology feeds the propellant through the engine cycle without the use of a separate pressurization fluid and without the use of turbomachinery. Advantages of the proposed technology are found in those elements of state-of-the-art systems that it avoids. It does not require a separate pressurization fluid or a thick-walled primary propellant tank as is typically required for a classical pressure-fed system. Further, it does not require the acceptance of intrinsic reliability risks associated with the use of turbomachinery

  8. Revisions to the hydrogen gas generation computer model

    Energy Technology Data Exchange (ETDEWEB)

    Jerrell, J.W.

    1992-08-31

    Waste Management Technology has requested SRTC to maintain and extend a previously developed computer model, TRUGAS, which calculates hydrogen gas concentrations within the transuranic (TRU) waste drums. TRUGAS was written by Frank G. Smith using the BASIC language and is described in the report A Computer Model of gas Generation and Transport within TRU Waste Drums (DP- 1754). The computer model has been partially validated by yielding results similar to experimental data collected at SRL and LANL over a wide range of conditions. The model was created to provide the capability of predicting conditions that could potentially lead to the formation of flammable gas concentrations within drums, and to assess proposed drum venting methods. The model has served as a tool in determining how gas concentrations are affected by parameters such as filter vent sizes, waste composition, gas generation values, the number and types of enclosures, water instrusion into the drum, and curie loading. The success of the TRUGAS model has prompted an interest in the program`s maintenance and enhancement. Experimental data continues to be collected at various sites on such parameters as permeability values, packaging arrangements, filter designs, and waste contents. Information provided by this data is used to improve the accuracy of the model`s predictions. Also, several modifications to the model have been made to enlarge the scope of problems which can be analyzed. For instance, the model has been used to calculate hydrogen concentrations inside steel cabinets containing retired glove boxes (WSRC-RP-89-762). The revised TRUGAS computer model, H2GAS, is described in this report. This report summarizes all modifications made to the TRUGAS computer model and provides documentation useful for making future updates to H2GAS.

  9. Revisions to the hydrogen gas generation computer model

    Energy Technology Data Exchange (ETDEWEB)

    Jerrell, J.W.

    1992-08-31

    Waste Management Technology has requested SRTC to maintain and extend a previously developed computer model, TRUGAS, which calculates hydrogen gas concentrations within the transuranic (TRU) waste drums. TRUGAS was written by Frank G. Smith using the BASIC language and is described in the report A Computer Model of gas Generation and Transport within TRU Waste Drums (DP- 1754). The computer model has been partially validated by yielding results similar to experimental data collected at SRL and LANL over a wide range of conditions. The model was created to provide the capability of predicting conditions that could potentially lead to the formation of flammable gas concentrations within drums, and to assess proposed drum venting methods. The model has served as a tool in determining how gas concentrations are affected by parameters such as filter vent sizes, waste composition, gas generation values, the number and types of enclosures, water instrusion into the drum, and curie loading. The success of the TRUGAS model has prompted an interest in the program's maintenance and enhancement. Experimental data continues to be collected at various sites on such parameters as permeability values, packaging arrangements, filter designs, and waste contents. Information provided by this data is used to improve the accuracy of the model's predictions. Also, several modifications to the model have been made to enlarge the scope of problems which can be analyzed. For instance, the model has been used to calculate hydrogen concentrations inside steel cabinets containing retired glove boxes (WSRC-RP-89-762). The revised TRUGAS computer model, H2GAS, is described in this report. This report summarizes all modifications made to the TRUGAS computer model and provides documentation useful for making future updates to H2GAS.

  10. Investigation of Productivity of Brown’s (HHO Gas Generator

    Directory of Open Access Journals (Sweden)

    Andrius Brazdžiūnas

    2017-01-01

    Full Text Available There were made tests of productivity of Brown’s gas generator using different potassium hydroxide (KOH concentration changing voltage and amperage. It is described experimental stand that is used to do researches and methodology of experiments performance. Brown’s gas production in electrolyser (electrolyser – the device that is going electrolysis to use stainless steel (AISI 316 electrodes. It was determined after researches that increasing the potassium hydroxide (KOH concentration in the solution and using the same amperage and voltage of the all concentration results are similar. The highest productivity 1.429 l/min was obtained by using a 120 A amperage and 15 V voltage.

  11. Generation of synthesis gas by partial oxidation of natural gas in a gas turbine

    NARCIS (Netherlands)

    Cornelissen, R.; Tober, E.; Kok, J.B.W.; Meer, van der T.H.

    2006-01-01

    The application of partial oxidation in a gas turbine (PO-GT) in the production of synthesis gas for methanol production is explored. In PO-GT, methane is compressed, preheated, partial oxidized and expanded. For the methanol synthesis a 12% gain in thermal efficiency has been calculated for the PO-

  12. Generation of synthesis gas by partial oxidation of natural gas in a gas turbine

    NARCIS (Netherlands)

    Cornelissen, R.; Tober, E.; Kok, Jacobus B.W.; van der Meer, Theodorus H.

    2006-01-01

    The application of partial oxidation in a gas turbine (PO-GT) in the production of synthesis gas for methanol production is explored. In PO-GT, methane is compressed, preheated, partial oxidized and expanded. For the methanol synthesis a 12% gain in thermal efficiency has been calculated for the

  13. A novel electrolytic ignition monopropellant microthruster based on low temperature co-fired ceramic tape technology.

    Science.gov (United States)

    Wu, Ming-Hsun; Yetter, Richard A

    2009-04-07

    A planar 2-D liquid monopropellant microthruster fabricated from low temperature co-fired ceramic tapes and ignited by electrolysis is reported. The volume of the combustion chamber was 820 nL (0.82 mm(3)). Silver electrodes were screen printed and positioned on the top and bottom surfaces of the combustion chamber. A DC voltage potential applied across the electrodes was used to initiate decomposition of hydroxylammonium nitrate (HAN) based liquid monopropellants. A thrust output of 150 mN was obtained using a voltage input of 45 V. Measured ignition energies were as small as 1.9 J. Ignition delays, as short as a few hundred milliseconds, were found dependent on the type of HAN-based propellant and the voltage potential.

  14. Continuous organic waste digester and methane gas generator

    Energy Technology Data Exchange (ETDEWEB)

    Araneta, V.A.

    1979-01-01

    A patent on the construction of a utility model of an industrial product of a continuous organic-waste digester and methane-gas generator is described. It comprises an airtight chamber to receive slurry of organic waste; a gas-water scrubber to purge carbon dioxide, odor-omitting gases and froth or scrum from newly formed methane gas evolving from said slurry of organic wastes; and two dually functioning slurry-feed and -discharge pipes connected to a reversible pump. It has one pipe with an opening at the base of an airtight chamber and the other pipe with up-ended openings below the fluid level of the slurry to be accumulated in the airtight chamber.

  15. Modeling acid-gas generation from boiling chloride brines

    Directory of Open Access Journals (Sweden)

    Sonnenthal Eric

    2009-11-01

    Full Text Available Abstract Background This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Results Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150°C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. Conclusion The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual

  16. Modeling acid-gas generation from boiling chloride brines

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

    2009-11-16

    This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent

  17. Oxygen rich gas generator design and performance analysis

    Science.gov (United States)

    Gloyer, P. W.; Knuth, W. H.; Crawford, R. A.

    1993-01-01

    The present oxygen-rich combustion research investigates oxygen gas generator concepts. The theoretical and modeling aspects of a selected concept are presented, together with a refined concept resulting from the findings of the study. This investigation examined a counter-flow gas generator design for O2/H2 mass ratios of 100-200, featuring a near-stoichiometric combustion zone followed by downstream mixing. The critical technologies required to develop a performance model are analyzed and include the following: (1) oxygen flow boiling; (2) two-phase oxygen flow heat transfer; (3) film-cooling in the combustion zone; (4) oxygen-rich combustion with hydrogen; and (5) mixing and dilution.

  18. Gas turbine powerhouse the development of the power generation gas turbine at BBC - ABB - Alstom

    CERN Document Server

    Eckardt, Dietrich

    2014-01-01

    This book tells the story of the power generation gas turbine from the perspective of one of the leading companies in the field over a period of nearly 100 years, written by an engineer. Especially in times of imminent global economic crises it appears to be worthwhile to reflect on real economic values based on engineering ingenuity and enduring management of technological leadership.

  19. Effects of oxygen cover gas and NaOH dilution on gas generation in tank 241-SY-101 waste

    Energy Technology Data Exchange (ETDEWEB)

    Person, J.C.

    1996-05-30

    Laboratory studies are reported of gas generation in heated waste from tank 241-SY-101. The rates of gas generation and the compositions of product gas were measured. Three types of tests are compared. The tests use: undiluted waste, waste diluted by a 54% addition of 2.5 M NaOH, and undiluted waste with a reactive cover gas of 30% Oxygen in He. The gas generation rate is reduced by dilution, increased by higher temperatures (which determines activation energies), and increased by reactions of Oxygen (these primarily produce H{sub 2}). Gases are generated as reduction products oxidation of organic carbon species by nitrite and oxygen.

  20. Gas-turbine expander power generating systems for internal needs of compressor stations of gas-main pipelines

    Science.gov (United States)

    Shimanov, A. A.; Biryuk, V. V.; Sheludko, L. P.; Shabanov, K. Yu.

    2017-08-01

    In the framework of this paper, there have been analyzed power station building methods to construct a power station for utilities for gas-main pipelines compressor stations. The application efficiency of turbo expanders in them to expand the power gas of compressor stations' gas compressor units has been shown. New schemes for gas-turbine expander power generating systems have been proposed.

  1. Leakage Currents and Gas Generation in Advanced Wet Tantalum Capacitors

    Science.gov (United States)

    Teverovsky, Alexander

    2015-01-01

    Currently, military grade, established reliability wet tantalum capacitors are among the most reliable parts used for space applications. This has been achieved over the years by extensive testing and improvements in design and materials. However, a rapid insertion of new types of advanced, high volumetric efficiency capacitors in space systems without proper testing and analysis of degradation mechanisms might increase risks of failures. The specifics of leakage currents in wet electrolytic capacitors is that the conduction process is associated with electrolysis of electrolyte and gas generation resulting in building up of internal gas pressure in the parts. The risk associated with excessive leakage currents and increased pressure is greater for high value advanced wet tantalum capacitors, but it has not been properly evaluated yet. In this work, in Part I, leakages currents in various types of tantalum capacitors have been analyzed in a wide range of voltages, temperatures, and time under bias. Gas generation and the level of internal pressure have been calculated in Part II for different case sizes and different hermeticity leak rates to assess maximal allowable leakage currents. Effects related to electrolyte penetration to the glass seal area have been studied and the possibility of failures analyzed in Part III. Recommendations for screening and qualification to reduce risks of failures have been suggested.

  2. REFINEMENT OF PRODUCER GAS GENERATED FROM BIOMASS GASIFIER

    Directory of Open Access Journals (Sweden)

    L. KUMARARAJA

    2016-01-01

    Full Text Available Producer gas (PG generated from biomass by thermo-chemical gasification process has been proved to be a reliable and renewable substitute for petroleum fuels to drive internal combustion engines. The gasification technology has been developed well and also commercialised. However, more technological advancements must happen in the refining of PG. Generally, the refinement is confined to the removal of tar and particulates from PG before supplying it to the engines. This paper proposes to remove additionally carbon dioxide and water vapour from PG so that its heating value can be increased and faster combustion can be attained in the engine cylinder. In this direction, the various CO2 removal technologies which are currently employed for combustion flue gas, natural gas and biogas have been first studied in detail. They are: physical absorption in solvents, chemical absorption by reagents, adsorption, membrane separation and refrigeration. In the present research, a batch of experiments has been conducted by washing PG with water to absorb CO2 physically and in a separate batch of experiments PG has been treated with aqueous ammonia to absorb CO2 chemically. For both experiments, the PG was generated by a downdraft biomass gasifier fed with wood pieces. The CO2 reduction obtained was 10.9% in physical absorption by water and 95% in chemical absorption by aqueous ammonia. Along with the reduction of CO2 and H2O from PG, the tar and particulates content of PG could also be reduced by absorption method.

  3. Tailored ramp wave generation in gas gun experiments

    Directory of Open Access Journals (Sweden)

    Cotton Matthew

    2015-01-01

    Full Text Available Gas guns are traditionally used as platforms to introduce a planar shock wave to a material using plate impact methods, generating states on the Hugoniot. The ability to deliver a ramp wave to a target during a gas gun experiment enables access to different regions of the equation-of-state surface, making it a valuable technique for characterising material behaviour. Previous techniques have relied on the use of multi-material impactors to generate a density gradient, which can be complex to manufacture. In this paper we describe the use of an additively manufactured steel component consisting of an array of tapered spikes which can deliver a ramp wave over ∼ 2 μs. The ability to tailor the input wave by varying the component design is discussed, an approach which makes use of the design freedom offered by additive manufacturing techniques to rapidly iterate the spike profile. Results from gas gun experiments are presented to evaluate the technique, and compared with 3D hydrodynamic simulations.

  4. Generation and characterization of gas bubbles in liquid metals

    Energy Technology Data Exchange (ETDEWEB)

    Eckert, S.; Gerbeth, G.; Witke, W.

    1996-06-01

    There is an ongoing research performed in the RCR on local transport phenomena in turbulent liquid metal (LM) duct flows exposed to external magnetic fields. In this context so-called MHD flow phenomena can be observed, which are unknown in usual hydraulic engineering. The field of interest covers also the influence of magnetic fields on the behaviour of liquid metal - gas mixtures. Profound knowledge on these LMMHD two-phase flow plays an important role in a variety of technological applications, in particular, in the design of Liquid-Metal MHD generators or for several metallurgical processes employing gas-stirred reactors. However, the highly empirical nature of two-phase flow analysis gives little hope for the prediction of MHD two-phase flows without extensive experimental data. A summary is given about the authors research activities focussing on two directions: (a) Momentum transfer between gas and liquid metal in a bubbly flow regime to investigate the influence of the external magnetic field on the velocity slip ration S (b) Peculiarities of the MHD turbulence to use small gas bubbles as local tracers in order to study the turbulent mass transfer.

  5. Department of Energy power generation programs for natural gas

    Energy Technology Data Exchange (ETDEWEB)

    Bajura, R.A.

    1995-04-01

    The U.S. Department of Energy (DOE) is sponsoring two major programs to develop high efficiency, natural gas fueled power generation technologies. These programs are the Advanced Turbine Systems (ATS) Program and the Fuel Cell Program. While natural gas is gaining acceptance in the electric power sector, the improved technology from these programs will make gas an even more attractive fuel, particularly in urban areas where environmental concerns are greatest. Under the auspices of DOE`s Office of Fossil Energy (DOE/FE) and Office of Energy Efficiency and Renewable Energy (DOE/EE), the 8-year ATS Program is developing and will demonstrate advanced gas turbine power systems for both large central power systems and smaller industrial-scale systems. The large-scale systems will have efficiencies significantly greater than 60 percent, while the industrial-scale systems will have efficiencies with at least an equivalent 15 percent increase over the best 1992-vintage technology. The goal is to have the system ready for commercial offering by the year 2000.

  6. Total system evaluation of gas generation and migration in the radioactive waste repository

    Energy Technology Data Exchange (ETDEWEB)

    Ando, K.; Fujiwara, A.; Tokuyama, S.; Adachi, T.; Saeki, T. [Radioactive Waste Management Funding and Research Center, Tokyo (Japan); Vomvoris, S. [NAGRA, Baden (Switzerland); Fukudome, K. [Kobe Steel Ltd. (Japan); Shimmura, A. [Obayashi Corp., Shinagawa Intercity Tower, Minato-ku (Japan)

    2001-07-01

    The carbon steel used in the nuclear waste repository under reductive condition reacts with ground water and generates hydrogen gas. It might accumulate and degrade performance of the Engineered Barrier System (EBS). It is highly important to evaluate the influence of gas generation and migration under the repository-like environment. Therefore, the Gas Generation Test is performed in Gas Evaluation Facility (GEF) in Japan and the Gas Migration Test (GMT) is performed in Nagra Grimsel Test Site (GTS) in Switzerland. (author)

  7. Improvements on cool gas generators and their application in space propulsion systems

    NARCIS (Netherlands)

    Sanders, H.M.; Schuurbiers, C.A.H.; Vandeberg, R.J.

    2014-01-01

    Cool Gas Generators are an innovative means to store gas which can be used in propulsion and pressurization systems but also for inflatable structures and terrestrial applications. In Cool Gas Generators, the gas is stored chemically, without pressure or leakage and with a long life time without mai

  8. Study of compressor systems for a gas-generator engine

    Science.gov (United States)

    Sather, Bernard I; Tauschek, Max J

    1950-01-01

    Various methods of providing compressor-capacity and pressure-ratio control in the gas-generator type of compound engine over a range of altitudes from sea level to 50,000 feet are presented. The analytical results indicate that the best method of control is that in which the first stage of compression is carried out in a variable-speed supercharger driven by a hydraulic slip coupling. The constant-speed second stage could be either a mixed-flow rotary compressor or a piston-type compressor. A variable-area turbine nozzle is shown to be unnecessary for cruising operation of the engine.

  9. Advanced Combustion Systems for Next Generation Gas Turbines

    Energy Technology Data Exchange (ETDEWEB)

    Joel Haynes; Jonathan Janssen; Craig Russell; Marcus Huffman

    2006-01-01

    Next generation turbine power plants will require high efficiency gas turbines with higher pressure ratios and turbine inlet temperatures than currently available. These increases in gas turbine cycle conditions will tend to increase NOx emissions. As the desire for higher efficiency drives pressure ratios and turbine inlet temperatures ever higher, gas turbines equipped with both lean premixed combustors and selective catalytic reduction after treatment eventually will be unable to meet the new emission goals of sub-3 ppm NOx. New gas turbine combustors are needed with lower emissions than the current state-of-the-art lean premixed combustors. In this program an advanced combustion system for the next generation of gas turbines is being developed with the goal of reducing combustor NOx emissions by 50% below the state-of-the-art. Dry Low NOx (DLN) technology is the current leader in NOx emission technology, guaranteeing 9 ppm NOx emissions for heavy duty F class gas turbines. This development program is directed at exploring advanced concepts which hold promise for meeting the low emissions targets. The trapped vortex combustor is an advanced concept in combustor design. It has been studied widely for aircraft engine applications because it has demonstrated the ability to maintain a stable flame over a wide range of fuel flow rates. Additionally, it has shown significantly lower NOx emission than a typical aircraft engine combustor and with low CO at the same time. The rapid CO burnout and low NOx production of this combustor made it a strong candidate for investigation. Incremental improvements to the DLN technology have not brought the dramatic improvements that are targeted in this program. A revolutionary combustor design is being explored because it captures many of the critical features needed to significantly reduce emissions. Experimental measurements of the combustor performance at atmospheric conditions were completed in the first phase of the program

  10. Design Optimization of Gas Generator Hybrid Propulsion Boosters

    Science.gov (United States)

    Weldon, Vincent; Phillips, Dwight; Fink, Larry

    1990-01-01

    A methodology used in support of a study for NASA/MSFC to optimize the design of gas generator hybrid propulsion booster for uprating the National Space Transportation System (NSTS) is presented. The objective was to compare alternative configurations for this booster approach, optimizing each candidate concept on different bases, in order to develop data for a trade table on which a final decision was based. The methodology is capable of processing a large number of independent and dependent variables, adjusting the overall subsystems characteristics to arrive at a best compromise integrated design to meet various specific optimization criteria subject to selected constraints. For each system considered, a detailed weight statement was generated along with preliminary cost and reliability estimates.

  11. Counter-Rotatable Fan Gas Turbine Engine with Axial Flow Positive Displacement Worm Gas Generator

    Science.gov (United States)

    Giffin, Rollin George (Inventor); Murrow, Kurt David (Inventor); Fakunle, Oladapo (Inventor)

    2014-01-01

    A counter-rotatable fan turbine engine includes a counter-rotatable fan section, a worm gas generator, and a low pressure turbine to power the counter-rotatable fan section. The low pressure turbine maybe counter-rotatable or have a single direction of rotation in which case it powers the counter-rotatable fan section through a gearbox. The gas generator has inner and outer bodies having offset inner and outer axes extending through first, second, and third sections of a core assembly. At least one of the bodies is rotatable about its axis. The inner and outer bodies have intermeshed inner and outer helical blades wound about the inner and outer axes and extending radially outwardly and inwardly respectively. The helical blades have first, second, and third twist slopes in the first, second, and third sections respectively. A combustor section extends through at least a portion of the second section.

  12. Safe Management of Waste Generated during Shale Gas Operations

    Science.gov (United States)

    Kukulska-Zając, Ewa; Król, Anna; Holewa-Rataj, Jadwiga

    2017-04-01

    Exploration and exploitation of hydrocarbon deposits, regardless of their type, are connected with the generation of waste, which may have various environmental effects. Such wastes may pose a serious risk to the surrounding environment and public health because they usually contain numerous potentially toxic chemicals. Waste associated with exploration and exploitation of unconventional hydrocarbon deposits is composed of a mixture of organic and inorganic materials, the qualitative and quantitative composition of which changes widely over time, depending on numerous factors. As a result the proper characteristic of this type of waste is very important. Information gained from detailed chemical analyses of drilling chemicals, drilling wastes, and flowback water can be used to manage shale gas-related wastes more appropriately, to develop treatment methods, to store the waste, and assess the potential environmental and health risk. The following paper will focus mainly on the results of research carried out on waste samples coming from the unconventional hydrogen exploration sites. Additionally, regulatory frameworks applicable to the management of wastes produced during this type of works will be discussed. The scope of research concerning physicochemical parameters for this type of wastes will also be presented. The presented results were obtained during M4ShaleGas project realization. The M4ShaleGas project has received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement no. 640715.

  13. Kinetics of hydrocarbon generation for Well Yingnan 2 gas reservoir,Tarim Basin,CHina

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Well Yingnan 2,an important exploratory well in the east of Tarim Basin,yields high commercial oil and gas flow in Jurassic.Natural gas components and carbon isotopic composition indicate that it belongs to sapropel type gas.Because this region presents many suits of hydrocarbon source rocks,there are some controversies that natural gases were generated from kerogen gas or crude oil cracking gas at present.By using the kinetics of hydrocarbon generation and carbon isotope,natural gas of Well Yingnan 2 is composed mainly of crude oil cracking gas,about 72%,it is generated from secondary kerogen gas of Cambrian-Lower Ordovician source rock and crude oil cracking gas of Mid-Upper Ordovician oil reservoir.The main oil and gas filling time is 65 Ma later in the Jurassic gas reservoir of Well Yingnan 2,so the gas reservoir belongs to late accumulation and continuous filling type.

  14. CSIR wins R1 million gas generator contract

    Energy Technology Data Exchange (ETDEWEB)

    1989-01-01

    The Division of Energy Technology, CSIR, has signed a R1 million contract with Slagment (Pty) Ltd for the supply, installation and commissioning during the first half of 1989 of a fluidized-bed hot gas generator. The contract was won on selected tender. A demonstration plant was built during 1984 in Pretoria West and funded by the Development of Mineral and Energy Affairs, to demonstrate to industry the ability of fluidized-bed technology to burn discard coal, thus reducing energy costs. It has been in operation for more than 20 000 hours and has demonstrated that it can successfully operate on coals with up to 70% ash and 8% sulfur content as well as on duff coal and char with a fines content of up to 50% less than 2mm diameter. The importance of offering a solution to the serious problem of stockpiling local inferior coals and the prospect of developing local expertise in the new, emerging technology, gave the research project the required support. The following are discussed: fluidization, fluidized beds and combustion of coal, fluidized bed boilers burning coal, fluidized-bed hot gas generator burning coal; advantages of fluidized-bed combustors, and applications. 2 figs.

  15. Estimating methane gas generation from Devil's swamp landfill using greenhouse gas emission models

    Science.gov (United States)

    Adeyemi, Ayodeji Thompson

    Greenhouse gas (GHG) has been a key issue in the study, design, and management of landfills. Landfill gas (LFG) is considered either as a significant source of renewable energy (if extracted and processed accordingly) or significant source of pollution and risk (if not mitigated or processed). A municipal solid waste (MSW) landfill emits a significant amount of methane, a potent GHG. Thus, quantification and mitigation of GHG emissions is an important area of study in engineering and other sciences related to landfill technology and management. The present study will focus on estimating methane generation from Devils swamp landfill (DSLF), a closed landfill in Baton Rouge, LA. The landfill operated for 53 years (1940-1993) and contains both industrial and municipal waste products. Since the Clean Air Act of 1963, landfills are now classified as New Source Performance Standard (NSPS) waste (i.e., waste that will decompose to generate LFG). Currently, the DSLF is being used as source of renewable energy through the "Waste to Energy" program. For this study, to estimate the methane potential in the DSLF, it is important to determine the characteristics and classification of the landfill's wastes. The study uses and compares different GHG modeling tools---LandGEM, a multiphase model, and a simple first-order model---to estimate methane gas emission and compare results with the actual emissions from the DSLF. The sensitivity of the methane generation rate was analyzed by the methane generation models to assess the effects of variables such as initial conditions, specific growth rate, and reaction rate constants. The study concludes that methane (L0) and initial organic concentration in waste (k) are the most important parameters when estimating methane generation using the models.

  16. Natural gas power generation: interruptible gas distribution network regulation; Geracao termoeletrica a gas natural: regulacao do segmento interruptivel de distribuicao de gas canalizado

    Energy Technology Data Exchange (ETDEWEB)

    Paula, Claudio Paiva de; Kann, Zevi [Agencia Reguladora de Saneamento e Energia do Estado de Sao Paulo (ARSESP), SP (Brazil)

    2008-07-01

    The paper relates studies regarding the natural gas distribution network interruptible branch. This new service can be appropriate for thermal power generation on flexible dispatch mode, as 'take or pay' contracts surplus jobs. The paper indicates no regulatory restraints in an interruptible network implantation. The final conclusion is that interruptible contracts can be an improvement on the distribution business and certainly can accommodate a suitable demand and supply volumes in the long-term gas market balance. (author)

  17. Green Liquid Monopropellant Thruster for In-space Propulsion Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Physical Sciences Inc. and AMPAC In-space Propulsion propose to develop a unique chemical propulsion system for the next generation NASA science spacecraft and...

  18. Green Liquid Monopropellant Thruster for In-space Propulsion Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Physical Sciences Inc. (PSI) and Orbitec Inc. propose to develop a unique chemical propulsion system for the next generation NASA science spacecraft and missions...

  19. BIOMASS GASIFICATION AND POWER GENERATION USING ADVANCED GAS TURBINE SYSTEMS

    Energy Technology Data Exchange (ETDEWEB)

    David Liscinsky

    2002-10-20

    A multidisciplined team led by the United Technologies Research Center (UTRC) and consisting of Pratt & Whitney Power Systems (PWPS), the University of North Dakota Energy & Environmental Research Center (EERC), KraftWork Systems, Inc. (kWS), and the Connecticut Resource Recovery Authority (CRRA) has evaluated a variety of gasified biomass fuels, integrated into advanced gas turbine-based power systems. The team has concluded that a biomass integrated gasification combined-cycle (BIGCC) plant with an overall integrated system efficiency of 45% (HHV) at emission levels of less than half of New Source Performance Standards (NSPS) is technically and economically feasible. The higher process efficiency in itself reduces consumption of premium fuels currently used for power generation including those from foreign sources. In addition, the advanced gasification process can be used to generate fuels and chemicals, such as low-cost hydrogen and syngas for chemical synthesis, as well as baseload power. The conceptual design of the plant consists of an air-blown circulating fluidized-bed Advanced Transport Gasifier and a PWPS FT8 TwinPac{trademark} aeroderivative gas turbine operated in combined cycle to produce {approx}80 MWe. This system uses advanced technology commercial products in combination with components in advanced development or demonstration stages, thereby maximizing the opportunity for early implementation. The biofueled power system was found to have a levelized cost of electricity competitive with other new power system alternatives including larger scale natural gas combined cycles. The key elements are: (1) An Advanced Transport Gasifier (ATG) circulating fluid-bed gasifier having wide fuel flexibility and high gasification efficiency; (2) An FT8 TwinPac{trademark}-based combined cycle of approximately 80 MWe; (3) Sustainable biomass primary fuel source at low cost and potentially widespread availability-refuse-derived fuel (RDF); (4) An overall integrated

  20. Gas dilution system using critical flow Venturi nozzles for generating primary trace-moisture standards in multiple gas species

    Science.gov (United States)

    Amano, Minami; Abe, Hisashi

    2017-02-01

    Gas dilution systems are commonly used to generate calibration gas mixtures for secondary gas standards. However, if a gas dilution system is used to generate gas mixtures for primary trace-moisture standards in multiple gas species, difficulty arises; flow control with relative stability of better than 0.009% is required although the relative uncertainty of the best gas flow meter to date is around 0.3%. In this study, we developed a novel gas dilution system using critical flow Venturi nozzles to address this problem. The developed dilution system can measure and control the flow rates of gases in the range of approximately 0.05 l min-1 to 7 l min-1 (when converted to those measured at 101 325 Pa and 273.15 K) with relative stability of better than 0.007%. Using the dilution system, we developed a magnetic suspension balance/diffusion-tube humidity generator capable of generating trace moisture in N2 in the range of approximately 10 nmol mol-1 to 5 µmol mol-1 in amount fraction. The accuracy of the generated trace-moisture standard was verified by measurement with cavity ring-down spectroscopy.

  1. Results of Laboratory and Industrial Tests of Periodic-Type Gas Generators

    Science.gov (United States)

    Karp, I. N.; P‧yanykh, K. E.; Antoshchuk, T. A.; Lysenko, A. A.

    2015-05-01

    Results of laboratory and industrial tests of periodic-type gas generators burning various solid biofuels have been presented. The tests were carried out with the aim of obtaining producer gas which could totally or partly replace natural gas in power equipment burning gaseous fuel. The energy and environmental characteristics of a boiler unit burning a mixture of producer gas and natural gas have been assessed.

  2. Metathesis in the generation of low-temperature gas in marine shales

    OpenAIRE

    Jarvie Daniel M; Mango Frank D

    2010-01-01

    Abstract The recent report of low-temperature catalytic gas from marine shales took on additional significance with the subsequent disclosure of natural gas and low-temperature gas at or near thermodynamic equilibrium in methane, ethane, and propane. It is important because thermal cracking, the presumed source of natural gas, cannot generate these hydrocarbons at equilibrium nor can it bring them to equilibrium over geologic time. The source of equilibrium and the source of natural gas are e...

  3. Investigation of gas generation in regenerative fuel cells by low-energy X-rays

    Science.gov (United States)

    Selamet, Omer Faruk; Deevanhxay, Phengxay; Tsushima, Shohji; Hirai, Shuichiro

    2015-11-01

    Gas generation and discharge behaviors in an operating regenerative fuel cell (RFC) are investigated using low-energy X-ray radiography. In situ visualization at high spatial and temporal resolution reveal dynamic and inhomogeneous behaviors of the gas generation in the membrane electrode assembly (MEA) in the RFC. Temporal and spatial variation of the gas thickness in the MEA is quantitatively discussed and shows an intermittent and periodic discharge processes of the gas generated by electrolysis, suggesting that the reaction sites in the catalyst layer and the discharging path of gas bubbles are well established in the MEA for the electrolysis. Larger gas accumulation and discharge in the gas diffusion layer (GDL) under the ribs are identified in comparison with those under the channels, which is attributed to the relatively longer path for accumulated gas under the ribs to be discharged into the flow channels.

  4. DESIGN, FABRICATION, AND TESTING OF AN ADVANCED, NON-POLLUTING TURBINE DRIVE GAS GENERATOR

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2002-03-31

    The objectives of this report period were to complete the development of the Gas Generator design, which was done; fabricate and test of the non-polluting unique power turbine drive gas Gas Generator, which has been postponed. Focus during this report period has been to complete the brazing and bonding necessary to fabricate the Gas Generator hardware, continue making preparations for fabricating and testing the Gas Generator, and continuing the fabrication of the Gas Generator hardware and ancillary hardware in preparation for the test program. Fabrication is more than 95% complete and is expected to conclude in early May 2002. the test schedule was affected by relocation of the testing to another test supplier. The target test date for hot fire testing is now not earlier than June 15, 2002.

  5. Application of High Intensity THz Pulses for Gas High Harmonic Generation

    CERN Document Server

    Balogh, Emeric; Hebling, János; Dombi, Péter; Farkas, Győző; Varjú, Katalin

    2013-01-01

    The main effects of an intense THz pulse on gas high harmonic generation are studied via trajectory analysis on the single atom level. Spectral and temporal modifications to the generated radiation are highlighted.

  6. Position paper on gas generation in the Waste Isolation Pilot Plant

    Energy Technology Data Exchange (ETDEWEB)

    Brush, L.H.

    1994-11-15

    Gas generation by transuranic (TRU) waste is a significant issue because gas will, if produced in significant quantities, affect the performance of the Waste Isolation Pilot Plant (WIPP) with respect to Environmental Protection Agency (EPA) regulations for the long-term isolation of radioactive and chemically hazardous waste. If significant gas production occurs, it will also affect, and will be affected by, other processes and parameters in WIPP disposal rooms. The processes that will produce gas in WIPP disposal rooms are corrosion, microbial activity and radiolysis. This position paper describes these processes and the models, assumptions and data used to predict gas generation in WIPP disposal rooms.

  7. Installed capacity of coal seam gas power generation exceeds 480 MW under SGCC s coverage

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The journalist learned from the "National Gas Security Working Conference" held recently that the coal seam gas power generation has been rapidly developed in recent years.As of July 2009,within the SGCC's business area,the power generation units

  8. Analysis of Turkish High School Chemistry Textbooks and Teacher-Generated Questions about Gas Laws

    Science.gov (United States)

    Nakiboglu, Canan; Yildirir, H.

    2011-01-01

    This study presents the results of an analysis of high school chemistry textbooks and teacher-generated questions about gas laws. The materials that were analyzed consisted of 456 questions about gas laws found in seven grade 10 chemistry textbooks and 264 teacher-generated examination questions prepared by seven chemistry teachers from three…

  9. Gas-temperature-dependent generation of cryoplasma jet under atmospheric pressure

    Science.gov (United States)

    Noma, Yuri; Choi, Jai Hyuk; Tomai, Takaaki; Terashima, Kazuo

    2008-09-01

    Plasma with a gas temperature below room temperature is not yet fully understood although it is expected to be an attractive tool for applications to material processing. In the present work, gas-temperature-dependent generation of a cryoplasma jet was studied. So far, we have generated a helium cryoplasma jet (296-5K) under atmospheric pressure. At gas temperatures below 20K, the helium excimer, He2, was observed clearly from by optical emission spectroscopy.

  10. DESIGN, FABRICATION, AND TESTING OF AN ADVANCED, NON-POLLUTING TURBINE DRIVE GAS GENERATOR

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2001-10-30

    The objectives of this report period were to continue the development of the Gas Generator design, to complete the hardware and ancillary hardware fabrication, and commence the Test Preparations for the testing of the non-polluting unique power turbine drive gas generator. Focus during this report period has been on testing the Gas Generator. Because of unacceptable delays encountered in a previously competitively selected test site, CES initiated a re-competition of our testing program and selected an alternate test site. Following that selection, CES used all available resources to make preparations for testing the 10 Mw Gas Generator at the new testing site facilities of NTS at Saugus, CA. A substantial portion of this report period was devoted to Testing Preparations, i.e. test facility development, cold- flow testing, calibration testing, performing igniter ignition testing, and then commencement of the completely assembled Gas Generator Assembly Testing, in process at this writing.

  11. Fuel Flexibility: Landfill Gas Contaminant Mitigation for Power Generation

    Energy Technology Data Exchange (ETDEWEB)

    Storey, John Morse [ORNL; Theiss, Timothy J [ORNL; Kass, Michael D [ORNL; FINNEY, Charles E A [ORNL; Lewis, Samuel [Oak Ridge National Laboratory (ORNL); Kaul, Brian C [ORNL; Besmann, Theodore M [ORNL; Thomas, John F [ORNL; Rogers, Hiram [ORNL; Sepaniak, Michael [University of Tennessee, Knoxville (UTK)

    2014-04-01

    This research project focused on the mitigation of silica damage to engine-based renewable landfill gas energy systems. Characterization of the landfill gas siloxane contamination, combined with characterization of the silica deposits in engines, led to development of two new mitigation strategies. The first involved a novel method for removing the siloxanes and other heavy contaminants from the landfill gas prior to use by the engines. The second strategy sought to interrupt the formation of hard silica deposits in the engine itself, based on inspection of failed landfill gas engine parts. In addition to mitigation, the project had a third task to develop a robust sensor for siloxanes that could be used to control existing and/or future removal processes.

  12. Features of the type Ⅲ-like source rock and its generated natural gas

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The mother matter of Ordovician source are mainly sapropelic and generate oil in mature stage, since the high plants did not appear in Ordovician period, which is well known by internal and external scholars. Now we find a kind of Orodovician source rock generating mainly light oil and gas in mature stage during appraising source rocks in the Tarim Basin. The organic matters of this source rock are chiefly constructed by benthic brown algae in organisms (showing as macro algae), and are similar to humic source in hydrocarbon generation. The natural gas generated by this kind of source matters is obviously different from the sapropelic gas.

  13. Micro generation of electricity with gasification gas in a engine generator in dual mode; Microgeracao de eletricidade com gas de gaseificacao num motor gerador dual

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Marcelo Jose da; Souza, Samuel Nelson Melegari de; Souza, Abel Alves de; Ricieri, Reinaldo P. [Universidade Estadual do Oeste do Parana (UNIOESTE), Cascavel, PE (Brazil)], E-mail: marcelo_js07@hotmail.com

    2010-07-01

    Among the alternatives to the increase of world energy demand the use of biomass as energy source is one of the most promising as it contributes to reducing emissions of carbon dioxide in the atmosphere. Gasification is a process technology of biomass energy in a gaseous biofuel. The fuel gas got a low calorific value that can be used in diesel engine in dual mode for power generation in isolated communities. This study aimed to evaluate the reduction in the consumption of oil diesel an engine generator, using gas from gasification of wood. The engine generator brand used, it was a BRANCO, with direct injection power of 10 hp and mated to an electric generator 5,5 kW. The fuel gas was produced in a gasifier type co-current. The engine generator was put on load system from 0.5 kW to 3.5 kW through electric bank of heaters. For the oil diesel savings, the gas was injected mixed with intake air, as the oil diesel was normally injected by the injector of the engine (motor dual). The consumption od diesel was measured diesel by means of a precision scale. It was concluded that the engine converted to dual mode when using the gas for the gasification of wood showed a decrease in diesel consumption by up to 57%. (author)

  14. DESIGN, FABRICATION, AND TESTING OF AN ADVANCED, NON-POLLUTING TURBINE DRIVE GAS GENERATOR

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2002-01-31

    The objective of this report period was to continue the development of the Gas Generator design, fabrication and test of the non-polluting unique power turbine drive Gas Generator. Focus during this past report period has been to continue completion the Gas Generator design, completing the brazing and bonding experiments to determine the best method and materials necessary to fabricate the Gas Generator hardware, continuing to making preparations for fabricating and testing this Gas Generator and commencing with the fabrication of the Gas Generator hardware and ancillary hardware. Designs have been completed sufficiently such that Long Lead Items [LLI] have been ordered and upon arrival will be readied for the fabrication process. The keys to this design are the platelet construction of the injectors that precisely measures/meters the flow of the propellants and water all throughout the steam generating process and the CES patented gas generating cycle. The Igniter Assembly injector platelets fabrication process has been completed and bonded to the Igniter Assembly and final machined. The Igniter Assembly is in final assembly and is being readied for testing in the October 2001 time frame. Test Plan dated August 2001, was revised and finalized, replacing Test Plan dated May 2001.

  15. DESIGN, FABRICATION, AND TESTING OF AN ADVANCED, NON-POLLUTING TURBINE DRIVE GAS GENERATOR

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2002-01-31

    The objective of this report period was to continue the development of the Gas Generator design, fabrication and test of the non-polluting unique power turbine drive Gas Generator. Focus during this past report period has been to continue completion the Gas Generator design, completing the brazing and bonding experiments to determine the best method and materials necessary to fabricate the Gas Generator hardware, continuing to making preparations for fabricating and testing this Gas Generator and commencing with the fabrication of the Gas Generator hardware and ancillary hardware. Designs have been completed sufficiently such that Long Lead Items [LLI] have been ordered and upon arrival will be readied for the fabrication process. The keys to this design are the platelet construction of the injectors that precisely measures/meters the flow of the propellants and water all throughout the steam generating process and the CES patented gas generating cycle. The Igniter Assembly injector platelets fabrication process has been completed and bonded to the Igniter Assembly and final machined. The Igniter Assembly is in final assembly and is being readied for testing in the October 2001 time frame. Test Plan dated August 2001, was revised and finalized, replacing Test Plan dated May 2001.

  16. Fuel prices, emission standards, and generation costs for coal vs natural gas power plants.

    Science.gov (United States)

    Pratson, Lincoln F; Haerer, Drew; Patiño-Echeverri, Dalia

    2013-05-07

    Low natural gas prices and stricter, federal emission regulations are promoting a shift away from coal power plants and toward natural gas plants as the lowest-cost means of generating electricity in the United States. By estimating the cost of electricity generation (COE) for 304 coal and 358 natural gas plants, we show that the economic viability of 9% of current coal capacity is challenged by low natural gas prices, while another 56% would be challenged by the stricter emission regulations. Under the current regulations, coal plants would again become the dominant least-cost generation option should the ratio of average natural gas to coal prices (NG2CP) rise to 1.8 (it was 1.42 in February 2012). If the more stringent emission standards are enforced, however, natural gas plants would remain cost competitive with a majority of coal plants for NG2CPs up to 4.3.

  17. Numerical solution of moving boundary problem for deposition process in solid fuel gas generator

    Science.gov (United States)

    Volokhov, V. M.; Dorofeenko, S. O.; Sharov, M. S.; Toktaliev, P. D.

    2016-11-01

    Moving boundary problem in application to process of depositions formation in gas generator are considered. Gas generator, as a part of fuel preparation system of high-speed vehicle, convert solid fuel into multicomponent multiphase mixture, which further burned down in combustion chamber. Mathematical model of two-phase “gas-solid particles” flow, including Navier-Stokes equations for turbulent flow in gas generator and mass, impulse conservations laws for elementary depositions layer are proposed. Verification of proposed mathematical model for depositions mass in gas generator conditions is done. Further possible improvements of proposed model, based on more detail accounting of particle-wall interaction and wall's surface adhesion properties are analyzed.

  18. Test Gas Generation from Pure Liquids: An Application-Oriented Overview of Methods in a Nutshell

    Directory of Open Access Journals (Sweden)

    Yue Li

    2012-01-01

    Full Text Available The generation of test gas from pure liquids has a wide variety of applications in laboratory and field experiments, for which the quality of the test gas is of significance. Therefore, various methods for test gas generation have been designed. Each method has unique advantages and disadvantages. Thus, a short overview is presented within the scope of this paper. Furthermore, a common bubbler system is presented, which was built to generate test gas from volatile organic compounds for experimental usage in laboratory applications. An analysis is conducted with respect to the generated concentrations at different temperatures and flow rates of the diluting gas. Accuracy and stability of this method are investigated.

  19. Carbon and hydrogen isotopic composition and generation pathway of biogenic gas in China

    Institute of Scientific and Technical Information of China (English)

    SHEN Ping; WANG Xiaofeng; XU Yin; SHI Baoguang; XU Yongchang

    2009-01-01

    The carbon and hydrogen isotopic composition of biogenic gas is of great importance for the study of its generation pathway and reservoiring characteristics. In this paper, the formation pathways and reservoiring characteristics of biogenic gas reservoirs in China are described in terms of the carbon and hydrogen isotopic compositions of 31 gas samples from 10 biogenic gas reservoirs. The study shows that the hydrogen isotopic compositions of these biogenic gas reservoirs can be divided into three intervals:δDCH4>-200‰,-250‰<δDCH4<-200‰ and δDCH4<-250‰. The forerunners believed that the main generation pathway of biogenic gas under the condition of continental fresh water is acetic fermentation. Our research results showed that the generation pathway of biogenic gas under the condition of marine facies is typical CO2- reduction, the biogenic gas has heavy hydrogen isotopic composition: its δDCH4 values are higher than -200‰; that the biogenic gas under the condition of continental facies also was generated by the same way, but its hydrogen isotopic composition is lighter than that of biogenetic gas generated under typical marine facies condition: -250‰<δDCH4<-200‰, the δDCH4 values may be related to the salinity of the water medium in ancient lakes. From the relevant data of the Qaidam Basin, it can be seen that the hydrogen isotopic composition of biogenic methane has the same variation trend with increasing salinity of water medium. There are biogenic gas reservoirs formed in transitional regions under the condition of continental facies. These gas reservoirs resulted from both CO2- reduction and acetic fermentation, the formation of which may be related to the non-variant salinity of ancient water medium and the relatively high geothermal gradient, as is the case encountered in the Baoshan Basin. The biogenic gas generating in these regions has light hydrogen isotopic composition: δDCH4<-250‰, and relatively heavy carbon isotopic

  20. Hourly weather forecasts for gas turbine power generation

    OpenAIRE

    G. Giunta; R. Vernazza; Salerno, R.; Ceppi, A.; Ercolani, G.; Mancini, M

    2017-01-01

    An hourly short-term weather forecast can optimize processes in Combined Cycle Gas Turbine (CCGT) plants by helping to reduce imbalance charges on the national power grid. Consequently, a reliable meteorological prediction for a given power plant is crucial for obtaining competitive prices for the electric market, better planning and stock management, sales and supplies of energy sources. The paper discusses the short-term hourly temperature forecasts, at lead time day+1 and day+2, over a per...

  1. Effects of Globally Waste Disturbing Activities on Gas Generation, Retention, and Release in Hanford Waste Tanks

    Energy Technology Data Exchange (ETDEWEB)

    Stewart, Charles W.; Fountain, Matthew S.; Huckaby, James L.; Mahoney, Lenna A.; Meyer, Perry A.; Wells, Beric E.

    2005-08-02

    Various operations are authorized in Hanford single- and double-shell tanks that disturb all or a large fraction of the waste. These globally waste-disturbing activities have the potential to release a large fraction of the retained flammable gas and to affect future gas generation, retention, and release behavior. This report presents analyses of the expected flammable gas release mechanisms and the potential release rates and volumes resulting from these activities. The background of the flammable gas safety issue at Hanford is summarized, as is the current understanding of gas generation, retention, and release phenomena. Considerations for gas monitoring and assessment of the potential for changes in tank classification and steady-state flammability are given.

  2. Gas Foil Bearings for Space Propulsion Nuclear Electric Power Generation

    Science.gov (United States)

    Howard, Samuel A.; DellaCorte, Christopher

    2006-01-01

    The choice of power conversion technology is critical in directing the design of a space vehicle for the future NASA mission to Mars. One candidate design consists of a foil bearing supported turbo alternator driven by a helium-xenon gas mixture heated by a nuclear reactor. The system is a closed-loop, meaning there is a constant volume of process fluid that is sealed from the environment. Therefore, foil bearings are proposed due to their ability to use the process gas as a lubricant. As such, the rotor dynamics of a foil bearing supported rotor is an important factor in the eventual design. The current work describes a rotor dynamic analysis to assess the viability of such a system. A brief technology background, assumptions, analyses, and conclusions are discussed in this report. The results indicate that a foil bearing supported turbo alternator is possible, although more work will be needed to gain knowledge about foil bearing behavior in helium-xenon gas.

  3. Accounting for fuel price risk: Using forward natural gas prices instead of gas price forecasts to compare renewable to natural gas-fired generation

    Energy Technology Data Exchange (ETDEWEB)

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2003-08-13

    Against the backdrop of increasingly volatile natural gas prices, renewable energy resources, which by their nature are immune to natural gas fuel price risk, provide a real economic benefit. Unlike many contracts for natural gas-fired generation, renewable generation is typically sold under fixed-price contracts. Assuming that electricity consumers value long-term price stability, a utility or other retail electricity supplier that is looking to expand its resource portfolio (or a policymaker interested in evaluating different resource options) should therefore compare the cost of fixed-price renewable generation to the hedged or guaranteed cost of new natural gas-fired generation, rather than to projected costs based on uncertain gas price forecasts. To do otherwise would be to compare apples to oranges: by their nature, renewable resources carry no natural gas fuel price risk, and if the market values that attribute, then the most appropriate comparison is to the hedged cost of natural gas-fired generation. Nonetheless, utilities and others often compare the costs of renewable to gas-fired generation using as their fuel price input long-term gas price forecasts that are inherently uncertain, rather than long-term natural gas forward prices that can actually be locked in. This practice raises the critical question of how these two price streams compare. If they are similar, then one might conclude that forecast-based modeling and planning exercises are in fact approximating an apples-to-apples comparison, and no further consideration is necessary. If, however, natural gas forward prices systematically differ from price forecasts, then the use of such forecasts in planning and modeling exercises will yield results that are biased in favor of either renewable (if forwards < forecasts) or natural gas-fired generation (if forwards > forecasts). In this report we compare the cost of hedging natural gas price risk through traditional gas-based hedging instruments (e

  4. The generation and its sealing condition of natural gas in the Tadong area

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Focusing on the two natural gas exploration geological problems with abundant source of oil cracking gas in the late stage and the sealing condition of the oil cracking gas reservoir,the kinetics of oil cracking gas and the evaluation parameters of gas cap rock are adopted to the study on the natural gas accumulation conditions in the Tadong area. Both the study on the kinetics of oil cracking gas and the statistical results of reservoir bitumen reveal that the geological formation of oil cracking gas in the Tadong area is located in the top of Cambrian. Two kinds of oil cracking gas geological models at least,namely well Mandong-1’s early rapid generation model(Middle Ordovician-end Silurian) and peak cracking model(with the natural gas conversion rate >90%) ,namely well Yingnan-2’s two-stage generation model of oil cracking gas,have been set up. The oil cracking gas of Yingnan-2 in the late stage is very significant in the evaluation of natural gas exploration in the Tadong area. The evaluation results of the cap rock show that the microscopic parameters of cap rock from the lower assemblage of Cambrian-Ordovician are better than those from the upper assemblage. The former has strong capillary sealing ability and higher cap rock breakthrough pressure than the upper assemblage,with strong sealing ability,so that natural gas dissipates mainly by diffusion. According to the above investigations,the lower assemblage Cambrian-Ordovician natural gas of Kongquehe slope,Tadong low uplift and Yingjisu depression in the Tadong area prospects well.

  5. Relative Role of Gas Generation and Displacement Rates in Cavity Nucleation and Growth

    DEFF Research Database (Denmark)

    Singh, Bachu Narain; Foreman, A. J E.

    1984-01-01

    Problems of helium diffusion and clustering during irradiation are analysed. Using the “homogeneous” nucleation theory , the effect of damage rate on cavity density is calculated for different gas generation to damage rate ratios. The influence of gas mobility on cavity nucleation has been evalua...

  6. Experimental investigation of the catalytic decomposition and combustion characteristics of a non-toxic ammonium dinitramide (ADN)-based monopropellant thruster

    Science.gov (United States)

    Chen, Jun; Li, Guoxiu; Zhang, Tao; Wang, Meng; Yu, Yusong

    2016-12-01

    Low toxicity ammonium dinitramide (ADN)-based aerospace propulsion systems currently show promise with regard to applications such as controlling satellite attitude. In the present work, the decomposition and combustion processes of an ADN-based monopropellant thruster were systematically studied, using a thermally stable catalyst to promote the decomposition reaction. The performance of the ADN propulsion system was investigated using a ground test system under vacuum, and the physical properties of the ADN-based propellant were also examined. Using this system, the effects of the preheating temperature and feed pressure on the combustion characteristics and thruster performance during steady state operation were observed. The results indicate that the propellant and catalyst employed during this work, as well as the design and manufacture of the thruster, met performance requirements. Moreover, the 1 N ADN thruster generated a specific impulse of 223 s, demonstrating the efficacy of the new catalyst. The thruster operational parameters (specifically, the preheating temperature and feed pressure) were found to have a significant effect on the decomposition and combustion processes within the thruster, and the performance of the thruster was demonstrated to improve at higher feed pressures and elevated preheating temperatures. A lower temperature of 140 °C was determined to activate the catalytic decomposition and combustion processes more effectively compared with the results obtained using other conditions. The data obtained in this study should be beneficial to future systematic and in-depth investigations of the combustion mechanism and characteristics within an ADN thruster.

  7. Transition metal catalysis in the generation of petroleum and natural gas. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Mango, F.D.

    1997-01-21

    This project originated on the premise that natural gas could be formed catalytically in the earth rather than thermally as commonly believed. The intention was to test this hypothetical view and to explore generally the role of sedimentary metals in the generation of light hydrocarbons (C1 - C9). We showed the metalliferous source rocks are indeed catalytic in the generation of natural gas. Various metal compounds in the pure state show the same levels of catalytic activity as sedimentary rocks and the products are identical. Nickel is particularly active among the early transition metals and is projected to remain catalytically robust at all stages of catagenesis. Nickel oxide promotes the formation of n-alkanes in addition to natural gas (NG), demonstrating the full scope of the hypothetical catalytic process: The composition of catalytic gas duplicates the entire range of natural gas, from so-called wet gas to dry gas (60 to 95+ wt % methane), while gas generated thermally is consistently depleted in methane (10 to 60 wt % methane). These results support the view that metal catalysis is a major pathway through which natural gas is formed in the earth.

  8. Hourly weather forecasts for gas turbine power generation

    Directory of Open Access Journals (Sweden)

    G. Giunta

    2017-06-01

    Full Text Available An hourly short-term weather forecast can optimize processes in Combined Cycle Gas Turbine (CCGT plants by helping to reduce imbalance charges on the national power grid. Consequently, a reliable meteorological prediction for a given power plant is crucial for obtaining competitive prices for the electric market, better planning and stock management, sales and supplies of energy sources. The paper discusses the short-term hourly temperature forecasts, at lead time day+1 and day+2, over a period of thirteen months in 2012 and 2013 for six Italian CCGT power plants of 390 MW each (260 MW from the gas turbine and 130 MW from the steam turbine. These CCGT plants are placed in three different Italian climate areas: the Po Valley, the Adriatic coast, and the North Tyrrhenian coast. The meteorological model applied in this study is the eni-Kassandra Meteo Forecast (e‑kmf™, a multi-model approach system to provide probabilistic forecasts with a Kalman filter used to improve accuracy of local temperature predictions. Performance skill scores, computed by the output data of the meteorological model, are compared with local observations, and used to evaluate forecast reliability. In the study, the approach has shown good overall scores encompassing more than 50,000 hourly temperature values. Some differences from one site to another, due to local meteorological phenomena, can affect the short-term forecast performance, with consequent impacts on gas-to-power production and related negative imbalances. For operational application of the methodology in CCGT power plant, the benefits and limits have been successfully identified.

  9. Conical flow near singular rays. [shock generation in ideal gas

    Science.gov (United States)

    Zahalak, G. I.; Myers, M. K.

    1974-01-01

    The steady flow of an ideal gas past a conical body is investigated by the method of matched asymptotic expansions, with particular emphasis on the flow near the singular ray occurring in linearized theory. The first-order problem governing the flow in this region is formulated, leading to the equation of Kuo, and an approximate solution is obtained in the case of compressive flow behind the main front. This solution is compared with the results of previous investigations with a view to assessing the applicability of the Lighthill-Whitham theories.

  10. Modeling of microbial gas generation: application to the eastern Mediterranean “Biogenic Play”

    Energy Technology Data Exchange (ETDEWEB)

    Schneider, M.; Dubille, M.; Montadert, L.

    2016-07-01

    Biogenic gas is becoming increasingly important as an exploration target in the petroleum industry because it occurs in geologically predictable circumstances and in large quantities at shallow depths as free gas or gas hydrates. As accumulations of biogenic gas result in a subtle synchronization between early generation and early trapping, we integrated a macroscopic model of microbial gas generation within a 3D basin and petroleum system forward simulator. The macroscopic model is based on a microscopic model, which consists in a 1D sedimentary column that accounts for sedimentation, compaction, Darcy flow and Diffusion flow. The organic carbon is the only non-soluble element considered in this version of the model. The dissolved elements are O2, SO4 2-, H2, CH3COOH, and CH4. Methane is dissolved in water or present as a free phase if its concentration exceeds its solubility at given pressure and temperature. In this microscopic model, the transformation of substrate into biomass is described through a set of logistic equations coupled with the transport equations (advection and diffusion). Based on the microscopic considerations we developed the macroscopic model of low maturity/biogenic gas generation in which hydrocarbons are generated through first order kinetic reactions at low maturity. This macroscopic model is adapted to petroleum system modeling at basin scale with TemisFlow®, which aims to understand and predict hydrocarbon generation, migration, and accumulation. It is composed of: i) A source rock criteria which allow defining the biogenic gas source rocks potential and ii) A kinetic model of methane generation. The previous model has been successfully applied on different basins such as the Carupano Basin from the offshore Venezuela, the Magdalena Delta (offshore Colombia) and the offshore Vietnam where direct observations of low-maturity gas were available. Furthermore, it has been applied in the offshore Lebanon in order to check the viability of

  11. FABRICATE AND TEST AN ADVANCED NON-POLLUTING TURBINE DRIVE GAS GENERATOR

    Energy Technology Data Exchange (ETDEWEB)

    Eugene Baxter; Roger E. Anderson; Stephen E. Doyle

    2003-06-01

    In September 2000 the Department of Energy's National Energy Technology Laboratory (DOE/NETL) contracted with Clean Energy Systems, Inc. (CES) of Sacramento, California to design, fabricate, and test a 20 MW{sub t} (10 MW{sub e}) gas generator. Program goals were to demonstrate a non-polluting gas generator at temperatures up to 3000 F at 1500 psi, and to demonstrate resulting drive gas composition, comprising steam and carbon dioxide substantially free of pollutants. Following hardware design and fabrication, testing, originally planned to begin in the summer of 2001, was delayed by unavailability of the contracted test facility. CES designed, fabricated, and tested the proposed gas generator as originally agreed. The CES process for producing near-zero-emissions power from fossil fuels is based on the near-stoichiometric combustion of a clean gaseous fuel with oxygen in the presence of recycled water, to produce a high-temperature, high-pressure turbine drive fluid comprising steam and carbon dioxide. Tests demonstrated igniter operation over the prescribed ranges of pressure and mixture ratios. Ignition was repeatable and reliable through more than 100 ignitions. Injector design ''A'' was operated successfully at both low power ({approx}20% of rated power) and at rated power ({approx}20 MW{sub t}) in more than 95 tests. The uncooled gas generator configuration (no diluent injectors or cooldown chambers installed) produced drive gases at temperatures approaching 3000 F and at pressures greater than 1550 psia. The fully cooled gas generator configuration, with cooldown chambers and injector ''A'', operated consistently at pressures from 1100 to 1540 psia and produced high pressure, steam-rich turbine drive gases at temperatures ranging from {approx}3000 to as low as 600 F. This report includes description of the intended next steps in the gas generator technology demonstration and traces the anticipated pathway to

  12. FABRICATE AND TEST AN ADVANCED NON-POLLUTING TURBINE DRIVE GAS GENERATOR

    Energy Technology Data Exchange (ETDEWEB)

    Eugene Baxter; Roger E. Anderson; Stephen E. Doyle

    2003-06-01

    In September 2000 the Department of Energy's National Energy Technology Laboratory (DOE/NETL) contracted with Clean Energy Systems, Inc. (CES) of Sacramento, California to design, fabricate, and test a 20 MW{sub t} (10 MW{sub e}) gas generator. Program goals were to demonstrate a non-polluting gas generator at temperatures up to 3000 F at 1500 psi, and to demonstrate resulting drive gas composition, comprising steam and carbon dioxide substantially free of pollutants. Following hardware design and fabrication, testing, originally planned to begin in the summer of 2001, was delayed by unavailability of the contracted test facility. CES designed, fabricated, and tested the proposed gas generator as originally agreed. The CES process for producing near-zero-emissions power from fossil fuels is based on the near-stoichiometric combustion of a clean gaseous fuel with oxygen in the presence of recycled water, to produce a high-temperature, high-pressure turbine drive fluid comprising steam and carbon dioxide. Tests demonstrated igniter operation over the prescribed ranges of pressure and mixture ratios. Ignition was repeatable and reliable through more than 100 ignitions. Injector design ''A'' was operated successfully at both low power ({approx}20% of rated power) and at rated power ({approx}20 MW{sub t}) in more than 95 tests. The uncooled gas generator configuration (no diluent injectors or cooldown chambers installed) produced drive gases at temperatures approaching 3000 F and at pressures greater than 1550 psia. The fully cooled gas generator configuration, with cooldown chambers and injector ''A'', operated consistently at pressures from 1100 to 1540 psia and produced high pressure, steam-rich turbine drive gases at temperatures ranging from {approx}3000 to as low as 600 F. This report includes description of the intended next steps in the gas generator technology demonstration and traces the anticipated pathway to

  13. Performance appraisal of gas based electric power generation system using transfer function modelling

    Directory of Open Access Journals (Sweden)

    Chidozie Chukwuemeka Nwobi-Okoye

    2015-06-01

    Full Text Available Gas flaring for years has been a major environmental problem in many parts of the world. One way of solving the problem of gas flaring is to effectively utilize the abundant supply of gas for power generation. To effectively utilize gas for power generation requires highly efficient gas turbines and power facilities. Traditional methods of assessing the efficiency of power generation turbines do not take into consideration the stochastic nature of gas input and power output. This is because in a power generation system, as in any typical production system, there is generally marked variability in both input (gas and output (power of the process. This makes the determination of the relationship between input and output quite complex. This work utilized Box-Jenkins transfer function modelling technique, an integral part of statistical principle of time series analysis to model the efficiency of a gas power plant. This improved way of determining the efficiency of gas power generation facilities involves taking input–output data from a gas power generation process over a 10-year period and developing transfer function models of the process for the ten years, which are used as performance indicators. Based on the performance indicators obtained from the models, the results show that the efficiency of the gas power generation facility was best in the years 2007–2011 with a coefficient of performance of 0.002343345. Similarly, with a coefficient of performance of 0.002073617, plant performance/efficiency was worst in the years 2002–2006. Using the traditional method of calculating efficiency the values of 0.2613 and 0.2516 were obtained for years 2002–2006 and 2007–2011 respectively. The result is remarkable because given the state of the facilities, it correctly predicted the period of expected high system performance i.e. 2002–2006 period, but the traditional efficiency measurement method failed to do so. Ordinarily, using efficiency

  14. Magnetic Field Generation and Zonal Flows in the Gas Giants

    Science.gov (United States)

    Duarte, L.; Wicht, J.; Gastine, T.

    2013-12-01

    The surface dynamics of Jupiter and Saturn is dominated by a banded system of fierce zonal winds. The depth of these winds remains unclear but they are thought to be confined to the very outer envelopes where hydrogen remains molecular and the electrical conductivity is negligible. The dynamo responsible for the dipole dominated magnetic fields of both Gas Giants, on the other hand, likely operates in the deeper interior where hydrogen assumes a metallic state. We present numerical simulations that attempt to model both the zonal winds and the interior dynamo action in an integrated approach. Using the anelastic version of the MHD code MagIC, we explore the effects of density stratification and radial electrical conductivity variations. The electrical conductivity is assumed to remain constant in the thicker inner metallic region and decays exponentially towards the outer boundary throughout the molecular envelope. Our results show that the combination of stronger density stratification (Δρ≈55) and a weaker conducting outer layer is essential for reconciling dipole dominated dynamo action and a fierce equatorial zonal jet. Previous simulations with homogeneous electrical conductivity show that both are mutually exclusive, with solutions either having strong zonal winds and multipolar magnetic fields or weak zonal winds and dipole dominated magnetic fields. The particular setup explored here allows the equatorial jet to remain confined to the weaker conducting region where is does not interfere with the deeper seated dynamo action. The equatorial jet can afford to remain geostrophic and reaches throughout the whole shell. This is not an option for the additional mid to higher latitude jets, however. In dipole dominated dynamo solutions, appropriate for the Gas Giants, zonal flows remain very faint in the deeper dynamo region but increase in amplitude in the weakly conducting outer layer in some of our simulations. This suggests that the mid to high latitude jets

  15. Experimental studies on producer gas generation from wood waste in a downdraft biomass gasifier.

    Science.gov (United States)

    Sheth, Pratik N; Babu, B V

    2009-06-01

    A process of conversion of solid carbonaceous fuel into combustible gas by partial combustion is known as gasification. The resulting gas, known as producer gas, is more versatile in its use than the original solid biomass. In the present study, a downdraft biomass gasifier is used to carry out the gasification experiments with the waste generated while making furniture in the carpentry section of the institute's workshop. Dalbergia sisoo, generally known as sesame wood or rose wood is mainly used in the furniture and wastage of the same is used as a biomass material in the present gasification studies. The effects of air flow rate and moisture content on biomass consumption rate and quality of the producer gas generated are studied by performing experiments. The performance of the biomass gasifier system is evaluated in terms of equivalence ratio, producer gas composition, calorific value of the producer gas, gas production rate, zone temperatures and cold gas efficiency. Material balance is carried out to examine the reliability of the results generated. The experimental results are compared with those reported in the literature.

  16. Dynamic performance of power generation systems for off-shore oil and gas platforms

    DEFF Research Database (Denmark)

    Pierobon, Leonardo; Breuhaus, Peter; Haglind, Fredrik

    2014-01-01

    On off-shore oil and gas platforms two or more gas turbines typically support the electrical demand on site by operating as a stand-alone (island) power system. As reliability and availability are major concerns during operation, the dynamic performance of the power generation system becomes...... a crucial aspect for stable operation and prevention of unwanted shut down in case of disturbances in the local grid. This paper aims at developing and validating a dynamic model of the gas turbine-based power generation system installed on the Draugen off-shore oil and gas platform (located in the North...... Sea, Norway). The dynamic model of the SGT-500 gas turbine includes dynamic equations for the combustion chamber and for the high pressure, low pressure and turbine shafts. The low and high pressure compressors are modeled by using quasi steady-state conditions by scaling the maps of axial compressors...

  17. Gas generation from overmature Upper Jurassic source rocks, Northern Viking Graben

    Energy Technology Data Exchange (ETDEWEB)

    Erdmann, M.

    1999-09-01

    Laboratory experiments were performed on solvent extracted immature kerogen concentrates of 2 Upper Jurassic Heather and Draupne Formation samples. Information used to help choosing these samples from a larger sample set included observations on organic petrology, Rock Eval analysis, kerogen typing by pyrolysis-gas chromatography and determination of bulk generation kinetic parameters. The Draupne Formation sample is characterised by a marine type II kerogen with a strong aliphatic hydrocarbon signature and contents of organic sulphur. The Heather Formation has a high proportion of aromatic hydrocarbons and phenols due to higher contributions of terrigenous type III organic matter. Both samples revealed similar alkyl-chain lenght distributions pointing to similarities in the marine proportions of the kerogens. It was decided that detailed work on gas generation should consider these typical end-member kerogen compositions. The kinetics of primary and secondary gas (C{sub 1-5}) generation was recognised and kinetic parameters assigned to them. The results of extrapolations to a linear geological heating rate of 5.3 K/ma can be summarised in short as follows - Primary gas generation; Peak generation temperatures are higher for Heather Formation (T{sub max}=190 C, R{sub 0} appr. 1.7%) compared to Draupne Formation (T{sub max}=175 C, equivalent to R{sub 0} 1.3%) at 5.3 K/ma. - Secondary gas generation; Peak generation temperatures at 5.3 K/ma are 220 C for Heather Formation and 205 to 215 C for Draupne Formation secondary gas generation from the cracking of oil. These temperatures correspond to R{sub 0} values of 2.4% and 2.0%, respectively. The high temperature secondary gas formation from neoformed bitumen as detected for the Heather Formation is outstanding and is suggested to occur at very high temperatures (max appr. 250 C) for geological heating rates. (orig.)

  18. A study on the gas generation from radioactive waste packages under disposal conditions in Korea

    Energy Technology Data Exchange (ETDEWEB)

    Park, Joo wan; Kim, Chang Lak; Choi, Heui Joo; Yoon, Jeong Hyoun [Korea Electric Power Corporation, Nuclear Environment Institute, Taejon (Korea, Republic of)

    1999-07-01

    In order to confirm the compliance to acceptance criteria , the performance of radioactive waste packages currently used at the nuclear power plants in Korea in aspect of gas generation is investigated. As the principal gas generation mechanisms radiolysis, corrosion of metals, and microbial activity of organic materials are considered. For calculating rates and total volumes of radiolytic hydrogen gas generated in waste packages a computer program that accommodates interactions among adjacent packages is used. Gas production due to metal corrosion and microbial degradation of Dry Active Waste (DAW) packages and the others is estimated over an assessment period of one thousand years under a given set of repository condition, respectively. Flammability hazard caused by radiolytic hydrogen formation inside a sealed waste package, pressure build-up inside the engineered barrier structure under repository condition is also assessed. (author)

  19. Numerical study of the generation of runaway electrons in a gas diode with a hot channel

    Energy Technology Data Exchange (ETDEWEB)

    Lisenkov, V. V., E-mail: lisenkov@iep.uran.ru [Institute of Electrophysics UrB RAS, 106 Amundsena St., Ekaterinburg 620012 (Russian Federation); Ural Federal University, 19 Mira St., Ekaterinburg 620002 (Russian Federation); Shklyaev, V. A., E-mail: shklyaev@to.hcei.tsc.ru [Institute of High Current Electronics SD RAS, 2/3 Akademichesky Avenue, 634055 Tomsk (Russian Federation); National Research Tomsk Polytechnic University, 30 Lenin Avenue, 634050 Tomsk (Russian Federation)

    2015-11-15

    A new method for increasing the efficiency of runaway electron beam generation in atmospheric pressure gas media has been suggested and theoretically proved. The method consists of creating a hot region (e.g., a spark channel or a laser plume) with a decreased numerical density of gas molecules (N) near the cathode. In this method, the ratio E/N (E—electric field strength) is increased by decreasing N instead of increasing E, as has been done in the past. The numerical model that is used allows the simultaneous calculation of the formation of a subnanosecond gas discharge and the generation of runaway electrons in gas media. The calculations have demonstrated the possibility of obtaining current pulses of runaway electrons with amplitudes of hundred of amperes and durations of more than 100 ps. The influence of the hot channel geometry on the parameters of the generated beam has been investigated.

  20. Natural Gas, Wind and Nuclear Options for Generating Electricity in a Carbon Constrained World

    NARCIS (Netherlands)

    Kooten, van G.C.

    2012-01-01

    A linear programming model is used to examine the impact of carbon taxes on the optimal generation mix in the Alberta electrical system. The model permits decommissioning of generating assets with high carbon dioxide emissions and investment in new gas-fired, wind and, in some scenarios, nuclear

  1. Natural Gas, Wind and Nuclear Options for Generating Electricity in a Carbon Constrained World

    NARCIS (Netherlands)

    Kooten, van G.C.

    2012-01-01

    A linear programming model is used to examine the impact of carbon taxes on the optimal generation mix in the Alberta electrical system. The model permits decommissioning of generating assets with high carbon dioxide emissions and investment in new gas-fired, wind and, in some scenarios, nuclear cap

  2. Isotope-analytical results of a study of gas generation in L/ILW

    Science.gov (United States)

    Molnár, M.; Palcsu, L.; Svingor, É.; Futó, I.; Major, Z.; Rinyu, L.; Veres, M.

    2006-01-01

    The paper presents the results of a long-term measurement series using hermetic containers to make more precise quantitative estimation of the generation rates and radioactivity of the gas in a drum of low and intermediate level radioactive waste (L/ILW) packages. Development of special preparation lines and isotope-analytical measurements of the headspace gas samples were performed in the ATOMKI. Stable isotope measurements were executed from the CO2 and CH4 fractions by stable isotope ratio mass spectrometer. Noble gas (He) measurements were done by noble gas mass spectrometer. The tritium content of the vapour, H2 and CH4 fractions was measured in H2O chemical form by a low background liquid scintillation counter. The 14C content of the CO2 and CH4 fractions of the headspace gas samples was measured by a low background gas proportional counter system.

  3. The Efficiency Improvement by Combining HHO Gas, Coal and Oil in Boiler for Electricity Generation

    Directory of Open Access Journals (Sweden)

    Chia-Nan Wang

    2017-02-01

    Full Text Available Electricity is an essential energy that can benefit our daily lives. There are many sources available for electricity generation, such as coal, natural gas and nuclear. Among these sources, coal has been widely used in thermal power plants that account for about 41% of the worldwide electricity supply. However, these thermal power plants are also found to be a big pollution source to our environment. There is a need to explore alternative electricity sources and improve the efficiency of electricity generation. This research focuses on improving the efficiency of electricity generation through the use of hydrogen and oxygen mixture (HHO gas. In this research, experiments have been conducted to investigate the combined effects of HHO gas with other fuels, including coal and oil. The results show that the combinations of HHO with coal and oil can improve the efficiency of electricity generation while reducing the pollution to our environment.

  4. Gas-phase generation of photoacoustic sound in an open environment.

    Science.gov (United States)

    Yönak, Serdar H; Dowling, David R

    2003-12-01

    The photoacoustic effect is commonly exploited for molecular spectroscopy, nondestructive evaluation, and trace gas detection. Photoacoustic sound is produced when a photoactive material absorbs electromagnetic radiation and converts it to acoustic waves. This article focuses on the generation of photoacoustic sound from thermal expansion of photoactive gases due to unsteady heating from a laser light source, and extends the work of prior studies on photoacoustic sound generation in an open environment. Starting with the forced free-space wave equation, a simple model is constructed for photoacoustic sounds produced by both acoustically distributed and compact gas clouds. The model accounts for laser absorption through the Lambert-Beer law and includes the effects of photoactive gas cloud characteristics (shape, size, and concentration distribution), but does not include molecular diffusion, thermal conduction, convection, or the effects of acoustic propagation through sound-absorbing inhomogeneous media. This model is compared to experimentally measured photoacoustic sounds generated by scanning a 10.6-micron carbon dioxide (CO2) laser beam through small clouds of a photoactive gas, sulfur hexafluoride (SF6). For the current investigation, the photoactive gas clouds are formed either by low flow-rate calibrated leak sources or by a laminar jet emerging from a 1.6-mm-diam tube. Model-measurement comparisons are presented over a 3- to 160-kHz bandwidth. Signal pulse shapes from simple gas cloud geometries are found to match calculated results when unmeasured gas cloud characteristics within the model are adjusted.

  5. Next Generation Thermal Barrier Coatings for the Gas Turbine Industry

    Science.gov (United States)

    Curry, Nicholas; Markocsan, Nicolaie; Li, Xin-Hai; Tricoire, Aurélien; Dorfman, Mitch

    2011-01-01

    The aim of this study is to develop the next generation of production ready air plasma sprayed thermal barrier coating with a low conductivity and long lifetime. A number of coating architectures were produced using commercially available plasma spray guns. Modifications were made to powder chemistry, including high purity powders, dysprosia stabilized zirconia powders, and powders containing porosity formers. Agglomerated & sintered and homogenized oven spheroidized powder morphologies were used to attain beneficial microstructures. Dual layer coatings were produced using the two powders. Laser flash technique was used to evaluate the thermal conductivity of the coating systems from room temperature to 1200 °C. Tests were performed on as-sprayed samples and samples were heat treated for 100 h at 1150 °C. Thermal conductivity results were correlated to the coating microstructure using image analysis of porosity and cracks. The results show the influence of beneficial porosity on reducing the thermal conductivity of the produced coatings.

  6. Modeling on the gas-generating amount of sediments hydrate-bearing

    Energy Technology Data Exchange (ETDEWEB)

    Gong, J.M.; Cao, Z.M. [Ocean Univ. of China, Qingdao (China); Jian-Ming, G.; Chen, J.W. [Qingdao Inst. of Marine Geology, Qingdao (China); Zhang, M.; Yang, G.F. [Yangtze Univ., Jingzhou (China); Li, J. [PetroChina, HeBei (China). Langfang Branch, Research Inst. of Petroleum Exploration and Development

    2008-07-01

    Gas hydrate is a form of clean fossil energy. It has the characteristics of extensive distribution, large reserve, high-energy capacity and less pollution after combustion. It also has a great energy value, generating interest from governments and scientists in different countries. This paper discussed a study in which methane generating hydrate-bearing sediments were investigated. A total of 58 sediment samples from 4 sites of ODP Leg 204 were modeled by 5 temperature points. ODP Leg 204 lies offshore western United States, in the Hydrate Ridge region (Oregon) of the Pacific. It is one of the most studied areas and clearest about hydrate distribution in the world. The paper described the study area and sample preparation. It also discussed the modeling and geochemical characteristics of the gas-generating samples. A model section revealed bacteria species, substrate deployment, selection of culture flask, and sample culture. The geochemical characteristics of the gas-generating samples were also described. It was concluded that the sediments within 1,200 meters below the seafloor were the main gas source of the biogenic gas hydrate. The organic matter abundance of the sediments at this depth and the migration passage of the fluids in the strata were important for the formation and preservation of the gas hydrate deposits. 21 refs., 1 tab., 6 figs.

  7. Combined gas/steam turbine power plants with coal fired steam generator

    Energy Technology Data Exchange (ETDEWEB)

    Krueger, H.J.; Weirich, P.H. [ABB Kraftwerke AG, Mannheim (Germany)

    1994-12-31

    The combination of coal fired steam power plants with natural gas fired gas turbines results in an essential efficiency increase, up to 50%, requiring a portion of around one third of the fuel heat input in form of natural gas. There are two basic types of circuit arrangements in this category: in a topping process the gas turbine is connected to the steam generator on the gas side, and in a compound cycle power plant gas turbine and steam circuit are connected to each other on the water/steam side via a heat recovery steam generator. If comparable design parameters are applied slightly higher plant efficiencies can be obtained with the topping process. With respect to a higher power plant availability it is possible to operate both types of circuit arrangement without gas turbine. The specific investment cost of such combined cycle power plants is lower than that of corresponding steam power plants. Hence, they can represent economical solutions as far as the price ratio between natural gas and coal is not extremely high. In ecological respects, the advantage of this combination is a reduction of the specific CO{sub 2} emission by around 20-25%, compared with pure steam power plants. 1 ref., 9 figs., 2 tabs.

  8. Gas generation from Hanford grout samples. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Jonah, C.D.; Kapoor, S.: Matheson, M.S.; Mulac, W.A.; Meisel, D.

    1994-03-01

    The radiolytic yields of H{sub 2}, N{sub 2}, O{sub 2}, N{sub 2}O, and CO from two batches of WHC-supplied samples of grouted simulated waste have been {gamma} irradiated at several dose rates (0.025, 0.63 and 130 krad/h for H{sub 2} and 130 krad/h for all other gases). In one batch, the liquid waste simulant that was added to the grout included the original components that were added to Tank 102-AP (labeled ``virgin``waste.) The second batch included a similar liquid waste simulant that was preirradiated to 35 Mrad prior to incorporation into the grout. It is believed that the preirradiated samples more closely represent radioactive waste that was stored in the tank for several years. The lowest dose rate corresponds approximately to that expected in the grout; with the high dose rate, doses equivalent to about 85 years storage in grout vaults were achieved. Most of the results on the batch of virgin samples have been reported recently (Report ANL 93/42). Here we report the results from the batch of preirradiated grout samples and compare the results from the two batches. The radiolytic yields of H{sub 2} and N{sub 2} are lower in the preirradiated than in the virgin grout. On the other hand G(O{sub 2}) is higher in the preirradiated samples: 0.078 vs. 0.026. The yield of nitrous oxide is essentially the same, G(N{sub 2}O) =0.010, in both. The yields measured from both batches are significantly higher than previously reported values. At 90{degrees}C similar amounts of H{sub 2} were generated thermally from both batches of grout, whereas the total amounts of N{sub 2} and N{sub 2}O were larger for the preirradiated than for the virgin grout samples. At lower temperatures the rate of generation was hardly measurable. Mass spectrometric analysis suggests that NO is thermally (but not radiolytically) released from the grout samples.

  9. Generation of ethylene tracer by noncatalytic pyrolysis of natural gas at elevated pressure

    Science.gov (United States)

    Lu, Y.; Chen, S.; Rostam-Abadi, M.; Ruch, R.; Coleman, D.; Benson, L.J.

    2005-01-01

    There is a critical need within the pipeline gas industry for an inexpensive and reliable technology to generate an identification tag or tracer that can be added to pipeline gas to identify gas that may escape and improve the deliverability and management of gas in underground storage fields. Ethylene is an ideal tracer, because it does not exist naturally in the pipeline gas, and because its physical properties are similar to the pipeline gas components. A pyrolysis process, known as the Tragen process, has been developed to continuously convert the ???2%-4% ethane component present in pipeline gas into ethylene at common pipeline pressures of 800 psi. In our studies of the Tragen process, pyrolysis without steam addition achieved a maximum ethylene yield of 28%-35% at a temperature range of 700-775 ??C, corresponding to an ethylene concentration of 4600-5800 ppm in the product gas. Coke deposition was determined to occur at a significant rate in the pyrolysis reactor without steam addition. The ?? 13C isotopic analysis of gas components showed a ?? 13C value of ethylene similar to ethane in the pipeline gas, indicating that most of the ethylene was generated from decomposition of the ethane in the raw gas. However, ?? 13C isotopic analysis of the deposited coke showed that coke was primarily produced from methane, rather than from ethane or other heavier hydrocarbons. No coke deposition was observed with the addition of steam at concentrations of > 20% by volume. The dilution with steam also improved the ethylene yield. ?? 2005 American Chemical Society.

  10. Ecological balance of power generation from sewage gas; Oekobilanz Klaergasverstromung

    Energy Technology Data Exchange (ETDEWEB)

    Ronchetti, C.; Bienz, P.; Pridal, R.

    2002-07-01

    This report for the Swiss Federal Office of Energy (SFOE) presents the ecological balance made for the production of electrical power from biogas that is produced in waste water treatment plants. The study was needed as the basis for deciding if power thus generated could be certified to the strict 'Naturemade Star' standards. This label is used to designate 'green' power. The report briefly describes the processes usually used in the treatment of sewage sludge, the energy-intensive aerobic and anaerobic digestion, which produces biogas. The ecological factors of the two processes were assessed using the Eco-Indicator 99 tool. The results are discussed, which showed that a typical modern waste water treatment plant is significantly better as far as energy is concerned than older examples of plant (e.g. those built in 1995) as far as ecological impact is concerned. Also, the study addresses other forms of biogas use, like, for example, its use as a fuel for vehicles.

  11. Micro- and Nanoscale Energetic Materials as Effective Heat Energy Sources for Enhanced Gas Generators.

    Science.gov (United States)

    Kim, Sang Beom; Kim, Kyung Ju; Cho, Myung Hoon; Kim, Ji Hoon; Kim, Kyung Tae; Kim, Soo Hyung

    2016-04-13

    In this study, we systematically investigated the effect of micro- and nanoscale energetic materials in formulations of aluminum microparticles (Al MPs; heat source)/aluminum nanoparticles (Al NPs; heat source)/copper oxide nanoparticles (CuO NPs; oxidizer) on the combustion and gas-generating properties of sodium azide microparticles (NaN3 MPs; gas-generating agent) for potential applications in gas generators. The burn rate of the NaN3 MP/CuO NP composite powder was only ∼0.3 m/s. However, the addition of Al MPs and Al NPs to the NaN3 MP/CuO NP matrix caused the rates to reach ∼1.5 and ∼5.3 m/s, respectively. In addition, the N2 gas volume flow rate generated by the ignition of the NaN3 MP/CuO NP composite powder was only ∼0.6 L/s, which was significantly increased to ∼1.4 and ∼3.9 L/s by adding Al MPs and Al NPs, respectively, to the NaN3 MP/CuO NP composite powder. This suggested that the highly reactive Al MPs and NPs, with the assistance of CuO NPs, were effective heat-generating sources enabling the complete thermal decomposition of NaN3 MPs upon ignition. Al NPs were more effective than Al MPs in the gas generators because of the increased reactivity induced by the reduced particle size. Finally, we successfully demonstrated that a homemade airbag with a specific volume of ∼140 mL could be rapidly and fully inflated by the thermal activation of nanoscale energetic material-added gas-generating agents (i.e., NaN3 MP/Al NP/CuO NP composites) within the standard time of ∼50 ms for airbag inflation.

  12. Microbial Gas Generation Under Expected Waste Isolation Pilot Plant Repository Conditions: Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Gillow, J.B.; Francis, A.

    2011-07-01

    Gas generation from the microbial degradation of the organic constituents of transuranic (TRU) waste under conditions expected in the Waste Isolation Pilot Plant (WIPP) was investigated. The biodegradation of mixed cellulosic materials and electron-beam irradiated plastic and rubber materials (polyethylene, polyvinylchloride, hypalon, leaded hypalon, and neoprene) was examined. We evaluated the effects of environmental variables such as initial atmosphere (air or nitrogen), water content (humid ({approx}70% relative humidity, RH) and brine inundated), and nutrient amendments (nitogen phosphate, yeast extract, and excess nitrate) on microbial gas generation. Total gas production was determined by pressure measurement and carbon dioxide (CO{sub 2}) and methane (CH{sub 4}) were analyzed by gas chromatography; cellulose degradation products in solution were analyzed by high-performance liquid chromatography. Microbial populations in the samples were determined by direct microscopy and molecular analysis. The results of this work are summarized.

  13. Recovery Act: Johnston Rhode Island Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas

    Energy Technology Data Exchange (ETDEWEB)

    Galowitz, Stephen

    2013-06-30

    The primary objective of the Project was to maximize the productive use of the substantial quantities of waste landfill gas generated and collected at the Central Landfill in Johnston, Rhode Island. An extensive analysis was conducted and it was determined that utilization of the waste gas for power generation in a combustion turbine combined cycle facility was the highest and best use. The resulting project reflected a cost effective balance of the following specific sub-objectives. 1) Meet environmental and regulatory requirements, particularly the compliance obligations imposed on the landfill to collect, process and destroy landfill gas. 2) Utilize proven and reliable technology and equipment. 3) Maximize electrical efficiency. 4) Maximize electric generating capacity, consistent with the anticipated quantities of landfill gas generated and collected at the Central Landfill. 5) Maximize equipment uptime. 6) Minimize water consumption. 7) Minimize post-combustion emissions. To achieve the Project Objective the project consisted of several components. 1) The landfill gas collection system was modified and upgraded. 2) A State-of-the Art gas clean up and compression facility was constructed. 3) A high pressure pipeline was constructed to convey cleaned landfill gas from the clean-up and compression facility to the power plant. 4) A combined cycle electric generating facility was constructed consisting of combustion turbine generator sets, heat recovery steam generators and a steam turbine. 5) The voltage of the electricity produced was increased at a newly constructed transformer/substation and the electricity was delivered to the local transmission system. The Project produced a myriad of beneficial impacts. 1) The Project created 453 FTE construction and manufacturing jobs and 25 FTE permanent jobs associated with the operation and maintenance of the plant and equipment. 2) By combining state-of-the-art gas clean up systems with post combustion emissions control

  14. Entropy generation in a channel resembling gas turbine cooling passage: Effect of rotation number and density ratio on entropy generation

    Indian Academy of Sciences (India)

    M Basha; M Al-Qahtani; B S Yilbas

    2009-06-01

    Flow into a passage resembling a gas turbine blade cooling passage is considered and entropy generation rate in the passage is examined for unique rotation number and density ratios. In the simulations, leading and trailing walls of the passage are assumed to be at constant temperature. A control volume approach is introduced to discretize the governing equations of flow, heat transfer, and entropy generation. Reynolds stress turbulence model is accommodated in the simulation to account for the turbulence. The study is extended to include two rotational speeds and three density ratios. The passage aspect ratio is kept 10:1. It is found that volumetric entropy generation rate attains high values at passage inlet due to attainment of high temperature gradient in this region. Increasing rotation number and density ratio enhances volumetric entropy generation rate in the passage.

  15. Analytical investigation of thermal barrier coatings on advanced power generation gas turbines

    Science.gov (United States)

    Amos, D. J.

    1977-01-01

    An analytical investigation of present and advanced gas turbine power generation cycles incorporating thermal barrier turbine component coatings was performed. Approximately 50 parametric points considering simple, recuperated, and combined cycles (including gasification) with gas turbine inlet temperatures from current levels through 1644K (2500 F) were evaluated. The results indicated that thermal barriers would be an attractive means to improve performance and reduce cost of electricity for these cycles. A recommended thermal barrier development program has been defined.

  16. Generation of phosphine gas for the control of grain storage pests

    OpenAIRE

    Zhao, B.X.

    2010-01-01

    The phosphine generator is a device for rapid production of phosphine (PH₃) gas to be introduced into grain storage. The aluminum phosphide (ALP) tablets are used as raw material and its effective constituent is 56%. When the aluminum phosphide and water are brought into contact a hydrolyzation reaction takes place to produce the phosphine gas. Controlling the reaction temperature, reaction pressure and the dosage of aluminum phosphide immersed in the water, the hydrolyzation reaction can be ...

  17. Flame speed enhancement of solid nitrocellulose monopropellant coupled with graphite at microscales

    Science.gov (United States)

    Jain, S.; Yehia, O.; Qiao, L.

    2016-03-01

    The flame-speed-enhancement phenomenon of a solid monopropellant (nitrocellulose) using a highly conductive thermal base (graphite sheet) was demonstrated and studied both experimentally and theoretically. A propellant layer ranging from 20 μm to 170 μm was deposited on the top of a 20-μm thick graphite sheet. Self-propagating oscillatory combustion waves were observed, with average flame speed enhancements up to 14 times the bulk value. The ratio of the fuel-to-graphite layer thickness affects not only the average reaction front velocities but also the period and the amplitude of the combustion wave oscillations. To better understand the flame-speed enhancement and the oscillatory nature of the combustion waves, the coupled nitrocellulose-graphite system was modeled using one-dimensional energy conservation equations along with simple one-step chemistry. The period and the amplitude of the oscillatory combustion waves were predicted as a function of the ratio of the fuel-to-graphite thickness (R), the ratio of the graphite-to-fuel thermal diffusivity (α0), and the non-dimensional inverse adiabatic temperature rise (β). The predicted flame speeds and the characteristics of the oscillations agree well with the experimental data. The new concept of using a highly conductive thermal base such as carbon-based nano- and microstructures to enhance flame propagation speed or burning rate of propellants and fuels could lead to improved performance of solid and liquid rocket motors, as well as of the alternative energy conversion microelectromechanical devices.

  18. Nondestructive Evaluation of the J-2X Direct Metal Laser Sintered Gas Generator Discharge Duct

    Science.gov (United States)

    Esther, Elizabeth A.; Beshears, Ronald D.; Lash, Rhonda K.

    2012-01-01

    The J-2X program at NASA's Marshall Space Flight Center (MSFC) procured a direct metal laser sintered (DMLS) gas generator discharge duct from Pratt & Whitney Rocketdyne and Morris Technologies for a test program that would evaluate the material properties and durability of the duct in an engine-like environment. DMLS technology was pursued as a manufacturing alternative to traditional techniques, which used off nominal practices to manufacture the gas generator duct's 180 degree turn geometry. MSFC's Nondestructive Evaluation (NDE) Team performed radiographic, ultrasonic, computed tomographic, and fluorescent penetrant examinations of the duct. Results from the NDE examinations reveal some shallow porosity but no major defects in the as-manufactured material. NDE examinations were also performed after hot-fire testing the gas generator duct and yielded similar results pre and post-test and showed no flaw growth or development.

  19. Preliminary Evaluation of Gas Generation from the Korean LILW Repository using the SMOGG Code

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Suk Hoon; Kim, Ju Youl [FNC Technology, Yongin (Korea, Republic of); Park, Jin Beak; Lee, Sun Joung [Korea Radioactive Waste Management Corporation, Daejeon (Korea, Republic of)

    2010-10-15

    For the permanent disposal of 100,000 drums of LILW (Low- and Intermediate-Level radioactive Waste) for the first stage of operation (800,000 drums in the long run) in Korea, the rock-cavern repository is being constructed at Gyeongju city. During the lifetime and post-closure period of the repository, it is expected that bulk gases (e.g. hydrogen, carbon dioxide, methane, etc.) are mainly produced by various mechanisms such as the metal corrosion, microbial degradation of organic materials, and radiolysis. Since gases generated have the potential threat to overpressurize the repository, which can promote the transport of radionuclide contained in groundwater and gas, it is necessary to simulate the features of gas generation from the repository using the appropriate computer code prior to the start of operation. This paper describes the preliminary evaluation of gas generation from the repository using the SMOGG code

  20. Development of the Next Generation Gas Trap for the Space Station Internal Thermal Control System

    Science.gov (United States)

    Leimkuehler, Thomas O.; Spelbring, Chris; Reeves, Daniel R.; Holt, James M.

    2003-01-01

    The current dual-membrane gas trap is designed to remove non-condensed gases (NCG) from the Internal Thermal Control System (ITCS) coolant on board the International Space Station (ISS). To date it has successfully served its purpose of preventing depriming, overspeed, and shutdown of the ITCS pump. However, contamination in the ITCS coolant has adversely affected the gas venting rate and lifetime of the gas trap, warranting a development effort for a next-generation gas trap. Design goals are to meet or exceed the current requirements to (1) include greater operating ranges and conditions, (2) eliminate reliance on the current hydrophilic tube fabrication process, and (3) increase operational life and tolerance to particulate and microbial growth fouling. In addition, the next generation gas trap will essentially be a 'dropin" design such that no modifications to the ITCS pump package assembly (PPA) will be required, and the implementation of the new design will not affect changes to the ITCS operational conditions, interfaces, or software. This paper will present the initial membrane module design and development work which has included (1) a trade study among several conceptual designs, (2) performance modeling of a hydrophobic-only design, and (3) small-scale development test data for the hydrophobic-only design. Testing has shown that the hydrophobic-only design is capable of performing even better than the current dual-membrane design for both steady-state gas removal and gas slug removal.

  1. Using Probability of Exceedance to Compare the Resource Risk of Renewable and Gas-Fired Generation

    Energy Technology Data Exchange (ETDEWEB)

    Bolinger, Mark [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2017-08-01

    Of the myriad risks surrounding long-term investments in power plants, resource risk is one of the most difficult to mitigate, and is also perhaps the risk that most-clearly distinguishes renewable generation from natural gas-fired generation. For renewable generators like wind and solar projects, resource risk manifests as a quantity risk—i.e., the risk that the quantity of wind and insolation will be less than expected.i For gas-fired generators (i.e., a combined-cycle gas turbine or “CCGT”), resource risk manifests primarily as a price risk—i.e., the risk that natural gas will cost more than expected. Most often, resource risk—and natural gas price risk in particular—falls disproportionately on utility ratepayers, who are typically not well-equipped to manage this risk. As such, it is incumbent upon utilities, regulators, and policymakers to ensure that resource risk is taken into consideration when making or approving resource decisions, or enacting policies that influence the development of the electricity sector more broadly.

  2. Aeroderivative Pratt & Whitney FT8-3 gas turbine – an interesting solution for power generation

    Directory of Open Access Journals (Sweden)

    Sorinel-Gicu TALIF

    2011-03-01

    Full Text Available The intermediate load electric power stations become more and more interesting for theelectric power market in Romania. In this context, the Combined Cycle Power Plants came as a veryattractive solution. This paper presents the results of a study regarding the use of the aeroderivativePratt & Whitney FT8-3 gas turbine, available in Romania, for the electric power generation in aCombined Cycle Power Plant. It is also analyzed the Combined Heat in Power generation with FT8-3gas turbine when saturated steam or hot water are required.

  3. Spent Nuclear Fuel Project (SNFP) gas generation from N-Fuel in multi-canister overpacks

    Energy Technology Data Exchange (ETDEWEB)

    Cooper, T.D.

    1996-08-01

    During the conversion from wet pool storage for spent nuclear fuel at Hanford, gases will be generated from both radiolysis and chemical reactions. The gas generation phenomenon needs to be understood as it applies to safety and design issues,specifically over pressurization of sealed storage containers,and detonation/deflagration of flammable gases. This study provides an initial basis to predict the implications of gas generation on the proposed functional processes for spent nuclear fuel conversion from wet to dry storage. These projections are based upon examination of the history of fuel manufacture at Hanford, irradiation in the reactors, corrosion during wet pool storage, available fuel characterization data and available information from literature. Gas generation via radiolysis and metal corrosion are addressed. The study examines gas generation, the boundary conditions for low medium and high levels of sludge in SNF storage/processing containers. The functional areas examined include: flooded and drained Multi-Canister Overpacks, cold vacuum drying, shipping and staging and long term storage.

  4. Outlook of natural gas thermal generation; A geracao termeletrica a gas natural e o PPT (Programa Prioritario de Termoeletricidade)

    Energy Technology Data Exchange (ETDEWEB)

    Felix, Makyo A.; Correia Junior, Clovis [Bahiagas - Companhia de Gas da Bahia, Salvador, BA (Brazil); Garcia, Celestino B. [Agencia Nacional do Petroleo, Gas Natural e Biocombustiveis (ANP), Rio de Janeiro, RJ (Brazil)

    2004-07-01

    The national integrated system has always had hydroelectricity as its main source of energy supply. However, a long period of lack of investment in sector put the country in a complacent position in which there was an overabundance of energy supply. The subsequent power shortage of 2001, led to a long term strategy of assuring supply with perspective of attending demand quickly and guaranteeing the security of the system by exploiting a source of energy rarely used in the country: thermal energy using natural gas. For this reason, the federal government launched the PPT Program (Priority Program of Thermoelectricity) with the aim of stimulating investment in thermo electrical plants, utilizing natural gas which is cheaper and less polluting. However, investment by the private sector did not fulfill expectations even with regular production, financial incentives of the government and favourable points through thermal generation using natural gas. Therefore, PETROBRAS decided to assume the risk and form partnerships to assure investments in thermo electrical plants. In the strategy of implanting thermal plants, who would be responsible to carry out this process along with guarantees of supply, was not properly defined. The establishment of thermal plants without a regulatory framework and undefined investment plan, compromises the essence of its creation. It is from this angle, that evaluates the recent collapse of energy of the Northeast region and the effective implantation of thermoelectricity utilizing natural gas. (author)

  5. Recovery Act: Brea California Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas

    Energy Technology Data Exchange (ETDEWEB)

    Galowitz, Stephen

    2012-12-31

    The primary objective of the Project was to maximize the productive use of the substantial quantities of waste landfill gas generated and collected at the Olinda Landfill near Brea, California. An extensive analysis was conducted and it was determined that utilization of the waste gas for power generation in a combustion turbine combined cycle facility was the highest and best use. The resulting Project reflected a cost effective balance of the following specific sub-objectives: • Meeting the environmental and regulatory requirements, particularly the compliance obligations imposed on the landfill to collect, process and destroy landfill gas • Utilizing proven and reliable technology and equipment • Maximizing electrical efficiency • Maximizing electric generating capacity, consistent with the anticipated quantities of landfill gas generated and collected at the Olinda Landfill • Maximizing equipment uptime • Minimizing water consumption • Minimizing post-combustion emissions • The Project produced and will produce a myriad of beneficial impacts. o The Project created 360 FTE construction and manufacturing jobs and 15 FTE permanent jobs associated with the operation and maintenance of the plant and equipment. o By combining state-of-the-art gas clean up systems with post combustion emissions control systems, the Project established new national standards for best available control technology (BACT). o The Project will annually produce 280,320 MWh’s of clean energy o By destroying the methane in the landfill gas, the Project will generate CO2 equivalent reductions of 164,938 tons annually. The completed facility produces 27.4 MWnet and operates 24 hours a day, seven days a week.

  6. Evaluating transition-metal catalysis in gas generation from the Permian Kupferschiefer by hydrous pyrolysis

    Science.gov (United States)

    Lewan, M.D.; Kotarba, M.J.; Wieclaw, D.; Piestrzynski, A.

    2008-01-01

    Transition metals in source rocks have been advocated as catalysts in determining extent, composition, and timing of natural gas generation (Mango, F. D. (1996) Transition metal catalysis in the generation of natural gas. Org. Geochem.24, 977–984). This controversial hypothesis may have important implications concerning gas generation in unconventional shale-gas accumulations. Although experiments have been conducted to test the metal-catalysis hypothesis, their approach and results remain equivocal in evaluating natural assemblages of transition metals and organic matter in shale. The Permian Kupferschiefer of Poland offers an excellent opportunity to test the hypothesis with immature to marginally mature shale rich in both transition metals and organic matter. Twelve subsurface samples containing similar Type-II kerogen with different amounts and types of transition metals were subjected to hydrous pyrolysis at 330° and 355 °C for 72 h. The gases generated in these experiments were quantitatively collected and analyzed for molecular composition and stable isotopes. Expelled immiscible oils, reacted waters, and spent rock were also quantitatively collected. The results show that transition metals have no effect on methane yields or enrichment. δ13C values of generated methane, ethane, propane and butanes show no systematic changes with increasing transition metals. The potential for transition metals to enhance gas generation and oil cracking was examined by looking at the ratio of the generated hydrocarbon gases to generated expelled immiscible oil (i.e., GOR), which showed no systematic change with increasing transition metals. Assuming maximum yields at 355 °C for 72 h and first-order reaction rates, pseudo-rate constants for methane generation at 330 °C were calculated. These rate constants showed no increase with increasing transition metals. The lack of a significant catalytic effect of transition metals on the extent, composition, and timing of

  7. Effects of microbial processes on gas generation under expected WIPP repository conditions: Annual report through 1992

    Energy Technology Data Exchange (ETDEWEB)

    Francis, A.J.; Gillow, J.B.

    1993-09-01

    Microbial processes involved in gas generation from degradation of the organic constituents of transuranic waste under conditions expected at the Waste Isolation Pilot Plant (WIPP) repository are being investigated at Brookhaven National Laboratory. These laboratory studies are part of the Sandia National Laboratories -- WIPP Gas Generation Program. Gas generation due to microbial degradation of representative cellulosic waste was investigated in short-term (< 6 months) and long-term (> 6 months) experiments by incubating representative paper (filter paper, paper towels, and tissue) in WIPP brine under initially aerobic (air) and anaerobic (nitrogen) conditions. Samples from the WIPP surficial environment and underground workings harbor gas-producing halophilic microorganisms, the activities of which were studied in short-term experiments. The microorganisms metabolized a variety of organic compounds including cellulose under aerobic, anaerobic, and denitrifying conditions. In long-term experiments, the effects of added nutrients (trace amounts of ammonium nitrate, phosphate, and yeast extract), no nutrients, and nutrients plus excess nitrate on gas production from cellulose degradation.

  8. Adaptive interpretation of gas well deliverability tests with generating data of the IPR curve

    Science.gov (United States)

    Sergeev, V. L.; Phuong, Nguyen T. H.; Krainov, A. I.

    2017-01-01

    The paper considers topical issues of improving accuracy of estimated parameters given by data obtained from gas well deliverability tests, decreasing test time, and reducing gas emissions into the atmosphere. The aim of the research is to develop the method of adaptive interpretation of gas well deliverability tests with a resulting IPR curve and using a technique of generating data, which allows taking into account additional a priori information, improving accuracy of determining formation pressure and flow coefficients, reducing test time. The present research is based on the previous theoretical and practical findings in the spheres of gas well deliverability tests, systems analysis, system identification, function optimization and linear algebra. To test the method, the authors used the field data of deliverability tests of two wells, run in the Urengoy gas and condensate field, Tyumen Oblast. The authors suggest the method of adaptive interpretation of gas well deliverability tests with the resulting IPR curve and the possibility of generating data of bottomhole pressure and a flow rate at different test stages. The suggested method allows defining the estimates of the formation pressure and flow coefficients, optimal in terms of preassigned measures of quality, and setting the adequate number of test stages in the course of well testing. The case study of IPR curve data processing has indicated that adaptive interpretation provides more accurate estimates on the formation pressure and flow coefficients, as well as reduces the number of test stages.

  9. Ultrasound imaging of oxidative stress in vivo with chemically-generated gas microbubbles.

    Science.gov (United States)

    Perng, John Kangchun; Lee, Seungjun; Kundu, Kousik; Caskey, Charles F; Knight, Sarah F; Satir, Sarp; Ferrara, Katherine W; Taylor, W Robert; Degertekin, F Levent; Sorescu, Daniel; Murthy, Niren

    2012-09-01

    Ultrasound contrast agents (UCAs) have tremendous potential for in vivo molecular imaging because of their high sensitivity. However, the diagnostic potential of UCAs has been difficult to exploit because current UCAs are based on pre-formed microbubbles, which can only detect cell surface receptors. Here, we demonstrate that chemical reactions that generate gas forming molecules can be used to perform molecular imaging by ultrasound in vivo. This new approach was demonstrated by imaging reactive oxygen species in vivo with allylhydrazine, a liquid compound that is converted into nitrogen and propylene gas after reacting with radical oxidants. We demonstrate that allylhydrazine encapsulated within liposomes can detect a 10 micromolar concentration of radical oxidants by ultrasound, and can image oxidative stress in mice, induced by lipopolysaccharide, using a clinical ultrasound system. We anticipate numerous applications of chemically-generated microbubbles for molecular imaging by ultrasound, given ultrasound's ability to detect small increments above the gas saturation limit, its spatial resolution and widespread clinical use.

  10. Microfluidic generation of uniform water droplets using gas as the continuous phase.

    Science.gov (United States)

    Jiang, Kunqiang; Lu, Annie Xi; Dimitrakopoulos, Panagiotis; DeVoe, Don L; Raghavan, Srinivasa R

    2015-06-15

    Microfluidic schemes for forming uniform aqueous microdroplets usually rely on contacting the aqueous liquid (dispersed phase) with an immiscible oil (continuous phase). Here, we demonstrate that the oil can be substituted with gas (nitrogen or air) while still retaining the ability to generate discrete and uniform aqueous droplets. Our device is a capillary co-flow system, with the inner flow of water getting periodically dispersed into droplets by the external flow of gas. The droplet size and different formation modes can be tuned by varying the liquid and gas flow rates. Importantly, we identify the range of conditions that correspond to the "dripping mode", i.e., where discrete droplets are consistently generated with no satellites. We believe this is a significant development that will be beneficial for chemical and biological applications requiring clean and contaminant-free droplets, including DNA amplification, drug encapsulation, and microfluidic cell culture.

  11. Contribution of N2O to the greenhouse gas balance of first-generation biofuels

    NARCIS (Netherlands)

    Smeets, E.W.M.; Bouwman, A.F.; Stehfest, E.; Vuuren, van P.; Posthuma, A.

    2009-01-01

    n this study, we analyze the impact of fertilizer- and manure-induced N2O emissions due to energy crop production on the reduction of greenhouse gas (GHG) emissions when conventional transportation fuels are replaced by first-generation biofuels (also taking account of other GHG emissions during the

  12. Modeling and experiments on differential pumping in linear plasma generators operating at high gas flows

    NARCIS (Netherlands)

    van Eck, H. J. N.; Koppers, W. R.; van Rooij, G. J.; W. J. Goedheer,; Engeln, R.; D.C. Schram,; Cardozo, N. J. L.; Kleyn, A. W.

    2009-01-01

    The direct simulation Monte Carlo (DSMC) method was used to investigate the efficiency of differential pumping in linear plasma generators operating at high gas flows. Skimmers are used to separate the neutrals from the plasma beam, which is guided from the source to the target by a strong axial mag

  13. Semi-continuous high speed gas analysis of generated vapors of chemical warfare agents

    NARCIS (Netherlands)

    Trap, H.C.; Langenberg, J.P.

    1999-01-01

    A method is presented for the continuous analysis of generated vapors of the nerve agents soman and satin and the blistering agent sulfur mustard. By using a gas sampling valve and a very short (15 cm) column connected to an on-column injector with a 'standard length' column, the system can either

  14. Prediction of gas pressurization and hydrogen generation for shipping hazard analysis : Six unstabilized PU 02 samples

    Energy Technology Data Exchange (ETDEWEB)

    Moody, E. W. (Eddie W.); Veirs, D. K. (Douglas Kirk); Lyman, J. L. (John L.)

    2001-01-01

    Radiolysis of water to form hydrogen gas is a safety concern for safe storage and transport of plutonium-bearing materials. Hydrogen gas is considered a safety hazard if its concentration in the container exceeds five percent hydrogen by volume, DOE Docket No. 00-1 1-9965. Unfortunately, water cannot be entirely avoided in a processing environment and these samples contain a range of water inherently. Thermodynamic, chemical, and radiolysis modeling was used to predict gas generation and changes in gas composition as a function of time within sealed containers containing plutonium bearing materials. The results are used in support of safety analysis for shipping six unstabilized (i.e. uncalcined) samples from Rocky Flats Environmental Technology Sits (RFETS) to the Material Identification and Surveillance (MIS) program at Los Alamos National Lab (LANL). The intent of this work is to establish a time window in which safe shipping can occur.

  15. Metathesis in the generation of low-temperature gas in marine shales.

    Science.gov (United States)

    Mango, Frank D; Jarvie, Daniel M

    2010-01-20

    The recent report of low-temperature catalytic gas from marine shales took on additional significance with the subsequent disclosure of natural gas and low-temperature gas at or near thermodynamic equilibrium in methane, ethane, and propane. It is important because thermal cracking, the presumed source of natural gas, cannot generate these hydrocarbons at equilibrium nor can it bring them to equilibrium over geologic time. The source of equilibrium and the source of natural gas are either the same (generation under equilibrium control) or closely associated. Here we report the catalytic interconversion of hydrocarbons (metathesis) as the source of equilibrium in experiments with Cretaceous Mowry shale at 100 degrees C. Focus was on two metathetic equilibria: methane, ethane, and propane, reported earlier, Q (K = [(C(1))*(C(3))]/[(C(2))(2)]), and between these hydrocarbons and n-butane, Q* (K = [(C(1))*(n-C(4))]/[(C(2))*(C(3))]), reported here for the first time. Two observations stand out. Initial hydrocarbon products are near equilibrium and have maximum average molecular weights (AMW). Over time, products fall from equilibrium and AMW in concert. It is consistent with metathesis splitting olefin intermediates [C(n)] to smaller intermediates (fission) as gas generation creates open catalytic sites ([ ]): [C(n)] + [ ] --> [C(n-m)] + [C(m)]. Fission rates increasing exponentially with olefin molecular weight could contribute to these effects. AMW would fall over time, and selective fission of [C(3)] and [n-C(4)] would draw Q and Q* from equilibrium. The results support metathesis as the source of thermodynamic equilibrium in natural gas.

  16. Metathesis in the generation of low-temperature gas in marine shales

    Directory of Open Access Journals (Sweden)

    Jarvie Daniel M

    2010-01-01

    Full Text Available Abstract The recent report of low-temperature catalytic gas from marine shales took on additional significance with the subsequent disclosure of natural gas and low-temperature gas at or near thermodynamic equilibrium in methane, ethane, and propane. It is important because thermal cracking, the presumed source of natural gas, cannot generate these hydrocarbons at equilibrium nor can it bring them to equilibrium over geologic time. The source of equilibrium and the source of natural gas are either the same (generation under equilibrium control or closely associated. Here we report the catalytic interconversion of hydrocarbons (metathesis as the source of equilibrium in experiments with Cretaceous Mowry shale at 100°C. Focus was on two metathetic equilibria: methane, ethane, and propane, reported earlier, Q (K = [(C1*(C3]/[(C22], and between these hydrocarbons and n-butane, Q* (K = [(C1*(n-C4]/[(C2*(C3], reported here for the first time. Two observations stand out. Initial hydrocarbon products are near equilibrium and have maximum average molecular weights (AMW. Over time, products fall from equilibrium and AMW in concert. It is consistent with metathesis splitting olefin intermediates [Cn] to smaller intermediates (fission as gas generation creates open catalytic sites ([ ]: [Cn] + [ ] → [Cn-m] + [Cm]. Fission rates increasing exponentially with olefin molecular weight could contribute to these effects. AMW would fall over time, and selective fission of [C3] and [n-C4] would draw Q and Q* from equilibrium. The results support metathesis as the source of thermodynamic equilibrium in natural gas.

  17. Generation and Migration of Natural Gas in Miocene Strata, Offshore Southeastern Korea

    Science.gov (United States)

    Son, Byeong-Kook

    2016-04-01

    Natural gas and condensate are produced from Miocene strata of the Tertiary marine basin, called Ulleung Basin, which is located offshore southeastern Korea. Petroleum system in the basin has not been fully understood, because effective source rocks have not been identified in the area. However, 1-D petroleum system modelling and isotope data indicate that the source rock of the natural gas and condensate might be present at deeper strata than 5,000 m in the basin. In addition, the analysis of diamondoids in the condensate shows that the gas was transformed from type II kerogen. Based on this source rock information and other geological data, 2-D petroleum system modelling was conducted on two cross sections in the southwestern margin of the basin. The 2-D models show two phase generation and migration, which are caused by the geometry of source bed and the maturity level of each pod of the bed. In addition, the accumulation of hydrocarbon is constrained greatly by the timing of development of the regional seal. The first generation and migration of oil and gas begins with a high rate of sedimentation at a deeply and early buried pod of the source bed at 15 Ma. The hydrocarbon, however, migrates upward and diffuses toward the surface. The second generation and migration occurs at around 11 Ma from the other pod of the source bed. This hydrocarbon migrates updip toward anticlines and accumulates into the traps of anticlines. On the other hand, the model shows that the generation and migration is dominated by gas, rather than oil. This model indicates that the accumulation of hydrocarbon can be completed only by the proper and sophisticated combination of the geological elements and the timing of hydrocarbon migration in time and space. This 2-D feature of generation and migration is supported by additional 1-D models of two pseudo-wells drilled on the 2-D section.

  18. A discussion on the upper limit of maturity for gas generation by marine kerogens and the utmost of gas generative potential: Taking the study on the Tarim Basin as an example

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The experimental data yielded by Rock-Eval pyrolysis, kerogen atomic H/C, Py-GC and gold-tube sealing thermal simulation on the marine Cambrian-Ordovician source rock from the Tarim Basin revealed that the upper limit of maturity for natural gas generation or the "deadline of gas generation" for marine types Ⅰ and Ⅱ kerogens is equal to 3.0% of vitrinite reflectance (Ro); while the "deadline of gas generation" for type Ⅲ kerogens typically like coals is as high as 10% Ro. Thus, different organic matter has obviously different utmost maturities for gas generation. The mass-balance calculation by kerogen elements showed that when Ro>1.5%, the utmost amount of gas generation for the marine type Ⅱ kerogen is less than 185 m3/t TOC, accounting for less than 30% of its total hydrocarbon generative potential; when Ro>2.0%, it becomes 110 m3/t TOC, less than 20% of the total hydrocarbon generative potential. The amount of the gas generative potential obtained by Rock-Eval is only around one tenth of the calculated value by the mass balance of kerogen elements at the same thermal evolutionary stage,while those by Py-GC and gold-tube sealing simulation are intervenient between the above two. The utmost of gas generative potential at the over 1.3% Ro stage is around 60-90 m3/t TOC, therefore, the amount of gas generation obtained by Rock-Eval is the minimum of gas generative potential, while that by the mass-balance calculation of kerogen elements is the maximum that the actual amount of gas generation should not exceed.

  19. Atmospheric dc discharges with miniature gas flow as microplasma generation method

    Energy Technology Data Exchange (ETDEWEB)

    Yokoyama, Takuma; Hamada, Shuhei; Ibuka, Shinji; Yasuoka, Koichi; Ishii, Shozo [Department of Electrical and Electronic Engineering, Tokyo Institute of Technology, Tokyo 152-8552 (Japan)

    2005-06-07

    An atmospheric microplasma is generated by direct-current (dc) discharge in air with a miniature gas flow through a nozzle, which limits plasma volume. Two discharge modes appear in a nozzle-to-mesh electrode system with helium or argon. One is a repetitive pulsed discharge with a current of 10-30 mA and a short pulse width. The fast pulsed current is powered by electric charges stored in the parasitic capacitance, which depends on the spatial arrangement of the electrodes and the power leads. The pulsed discharge makes it possible to develop a discharge scheme for microplasma generation without a high-voltage pulse generator. The other is a sustained dc discharge, which develops with increasing applied voltage. In the case of helium, a glow discharge configuration is observed with a positive column and a layered structure near the cathode. The length of the positive column is affected by electrode separation and gas flow rate.

  20. Ultraviolet Light Generation in Gas-Filled Kagome Photonic Crystal Fiber

    Science.gov (United States)

    Rodrigues, Sílvia M. G.; Facão, Margarida; Ferreira, Mário F. S.

    2015-03-01

    Kagome hollow-core photonic crystal fibers were found to be ideal for the occurrence of ultrafast non-linear optics. This article reports the optimal conditions for the generation of ultraviolet light using a gas filled kagome hollow-core-photonic crystal fiber. It is shown that by changing the pressure of the gas and the input pulse characteristics, the efficiency of conversion and quality of ultraviolet light can be improved, as well as tuning its central frequency. Results suggest that a highly coherent and tunable ultraviolet light source can be constructed, which can find numerous applications.

  1. Moisture effects on greenhouse gases generation in nitrifying gas-phase compost biofilters.

    Science.gov (United States)

    Maia, Guilherme D N; Day, George B; Gates, Richard S; Taraba, Joseph L; Coyne, Mark S

    2012-06-01

    Gas-phase compost biofilters are extensively used in concentrated animal feeding operations to remove odors and, in some cases, ammonia from air sources. The expected biochemical pathway for these predominantly aerobic systems is nitrification. However, non-uniform media with low oxygen levels can shift biofilter microbial pathways to denitrification, a source of greenhouse gases. Several factors contribute to the formation of anoxic/anaerobic zones: media aging, media and particle structure, air velocity distribution, compaction, biofilm thickness, and moisture content (MC) distribution. The present work studies the effects of media moisture conditions on ammonia (NH(3)) removal and greenhouse gas generation (nitrous oxide, N(2)O and methane, CH(4)) for gas-phase compost biofilters subject to a 100-day controlled drying process. Continuous recordings were made for the three gases and water vapor (2.21-h sampling cycle, each cycle consisted of three gas species, and water vapor, for a total of 10,050 data points). Media moisture conditions were classified into three corresponding media drying rate (DR) stages: Constant DR (wetter media), falling DR, and stable-dry system. The first-half of the constant DR period (0-750 h; MC=65-52%, w.b.) facilitated high NH(3) removal rates, but higher N(2)O generation and no CH(4) generation. At the drier stages of the constant DR (750-950 h; MC=52-48%, w.b.) NH(3) removal remained high but N(2)O net generation decreased to near zero. In the falling DR stage (1200-1480 h; MC=44-13%) N(2)O generation decreased, CH(4) increased, and NH(3) was no longer removed. No ammonia removal or greenhouse gas generation was observed in the stable-dry system (1500-2500 h; MC=13%). These results indicate that media should remain toward the drier region of the constant DR (in close proximity to the falling DR stage; MC=50%, approx.), to maintain high levels of NH(3) removal, reduced levels of N(2)O generation, and nullify levels of CH(4

  2. Life Cycle Greenhouse Gas Emissions from Electricity Generation: A Comparative Analysis of Australian Energy Sources

    Directory of Open Access Journals (Sweden)

    Robert G. Hynes

    2012-03-01

    Full Text Available Electricity generation is one of the major contributors to global greenhouse gas emissions. Transitioning the World’s energy economy to a lower carbon future will require significant investment in a variety of cleaner technologies, including renewables and nuclear power. In the short term, improving the efficiency of fossil fuel combustion in energy generation can provide an important contribution. Availability of life cycle GHG intensity data will allow decision-makers to move away from overly simplistic assertions about the relative merits of certain fuels, and focus on the complete picture, especially the critical roles of technology selection and application of best practice. This analysis compares the life-cycle greenhouse gas (GHG intensities per megawatt-hour (MWh of electricity produced for a range of Australian and other energy sources, including coal, conventional liquefied natural gas (LNG, coal seam gas LNG, nuclear and renewables, for the Australian export market. When Australian fossil fuels are exported to China, life cycle greenhouse gas emission intensity in electricity production depends to a significant degree on the technology used in combustion. LNG in general is less GHG intensive than black coal, but the gap is smaller for gas combusted in open cycle gas turbine plant (OCGT and for LNG derived from coal seam gas (CSG. On average, conventional LNG burned in a conventional OCGT plant is approximately 38% less GHG intensive over its life cycle than black coal burned in a sub-critical plant, per MWh of electricity produced. However, if OCGT LNG combustion is compared to the most efficient new ultra-supercritical coal power, the GHG intensity gap narrows considerably. Coal seam gas LNG is approximately 13–20% more GHG intensive across its life cycle, on a like-for like basis, than conventional LNG. Upstream fugitive emissions from CSG (assuming best practice gas extraction techniques do not materially alter the life cycle

  3. Numerical study on the generation of a planar supersonic gas-jet

    Energy Technology Data Exchange (ETDEWEB)

    Putignano, M., E-mail: massimilianoputignano@quasar-group.org [Cockcroft Institute, Daresbury Laboratory, Warrington (United Kingdom); University of Liverpool, Liverpool (United Kingdom); Welsch, C.P. [University of Liverpool, Liverpool (United Kingdom)

    2012-03-01

    Planar supersonic gas-jets are valuable tools for different applications such as state of the art molecular spectroscopy and accelerator beam instrumentation; however, the details of their expansion and generation have not yet been analyzed extensively, despite numerous studies addressing these same questions for the simpler case of the axis-symmetric jet. In this paper, we investigate numerically the generation and evolution of planar supersonic gas-jets, extending the optimization studies done for axis-symmetric jets and focusing in particular on applications in accelerator beam instrumentation. We introduce a set of dedicated quality factors and use them to investigate the effects of changes to the geometry and thermodynamic state of the nozzle-skimmer system used to generate the planar jet. This analysis leads to an innovative, optimized nozzle-skimmer system design, which features advantages in terms of planar jet quality when compared to traditional setups. The proposed design also gives the possibility to modify, by variation of the thermodynamic quantities alone, the gas-jet characteristics in a wide range, including jet splitting and local density modulation. Density profiles of the generated jets are plotted for different parameter set.

  4. Variance Analysis of Wind and Natural Gas Generation under Different Market Structures: Some Observations

    Energy Technology Data Exchange (ETDEWEB)

    Bush, B.; Jenkin, T.; Lipowicz, D.; Arent, D. J.; Cooke, R.

    2012-01-01

    Does large scale penetration of renewable generation such as wind and solar power pose economic and operational burdens on the electricity system? A number of studies have pointed to the potential benefits of renewable generation as a hedge against the volatility and potential escalation of fossil fuel prices. Research also suggests that the lack of correlation of renewable energy costs with fossil fuel prices means that adding large amounts of wind or solar generation may also reduce the volatility of system-wide electricity costs. Such variance reduction of system costs may be of significant value to consumers due to risk aversion. The analysis in this report recognizes that the potential value of risk mitigation associated with wind generation and natural gas generation may depend on whether one considers the consumer's perspective or the investor's perspective and whether the market is regulated or deregulated. We analyze the risk and return trade-offs for wind and natural gas generation for deregulated markets based on hourly prices and load over a 10-year period using historical data in the PJM Interconnection (PJM) from 1999 to 2008. Similar analysis is then simulated and evaluated for regulated markets under certain assumptions.

  5. Analysis of Precooling Injection Transient of Steam Generator for High Temperature Gas Cooled Reactor

    Directory of Open Access Journals (Sweden)

    Yan Wang

    2017-01-01

    Full Text Available After a postulated design basis accident leads high temperature gas cooled reactor to emergency shutdown, steam generator still remains with high temperature level and needs to be cooled down by a precooling before reactor restarts with clearing of fault. For the large difference of coolant temperature between inlet and outlet of steam generator in normal operation, the temperature distribution on the components of steam generator is very complicated. Therefore, the temperature descending rate of the components in steam generator needs to be limited to avoid the potential damage during the precooling stage. In this paper, a pebble-bed high temperature gas cooled reactor is modeled by thermal-hydraulic system analysis code and several postulated precooling injection transients are simulated and compared to evaluate their effects, which will provide support for the precooling design. The analysis results show that enough precooling injection is necessary to satisfy the precooling requirements, and larger mass flow rate of precooling water injection will accelerate the precooling process. The temperature decrease of steam generator is related to the precooling injection scenarios, and the maximal mass flow rate of the precooling injection should be limited to avoid the excessively quick temperature change of the structures in steam generator.

  6. Experimental check of possibility of research of repeated inclusion of the open gas generator in the water environment

    Directory of Open Access Journals (Sweden)

    Goldaev Sergey

    2017-01-01

    Full Text Available Experimental study of repeated burning interruption with the subsequent ignition in the water environment for bibasic firm fuel as a part of a model open solid propellant gas generator is presented. Video filming of burning zone mobile localizer providing process of repeated inclusion of a gas generator are given. Some parameters of the processes proceeding in these conditions are defined

  7. Thermal-maturity limit for primary thermogenic-gas generation from humic coals as determined by hydrous pyrolysis

    Science.gov (United States)

    Lewan, Michael; Kotarba, M.J.

    2014-01-01

    Hydrous-pyrolysis experiments at 360°C (680°F) for 72 h were conducted on 53 humic coals representing ranks from lignite through anthracite to determine the upper maturity limit for hydrocarbon-gas generation from their kerogen and associated bitumen (i.e., primary gas generation). These experimental conditions are below those needed for oil cracking to ensure that generated gas was not derived from the decomposition of expelled oil generated from some of the coals (i.e., secondary gas generation). Experimental results showed that generation of hydrocarbon gas ends before a vitrinite reflectance of 2.0%. This reflectance is equivalent to Rock-Eval maximum-yield temperature and hydrogen indices (HIs) of 555°C (1031°F) and 35 mg/g total organic carbon (TOC), respectively. At these maturity levels, essentially no soluble bitumen is present in the coals before or after hydrous pyrolysis. The equivalent kerogen atomic H/C ratio is 0.50 at the primary gas-generation limit and indicates that no alkyl moieties are remaining to source hydrocarbon gases. The convergence of atomic H/C ratios of type-II and -I kerogen to this same value at a reflectance of indicates that the primary gas-generation limits for humic coal and type-III kerogen also apply to oil-prone kerogen. Although gas generation from source rocks does not exceed vitrinite reflectance values greater than , trapped hydrocarbon gases can remain stable at higher reflectance values. Distinguishing trapped gas from generated gas in hydrous-pyrolysis experiments is readily determined by of the hydrocarbon gases when a -depleted water is used in the experiments. Water serves as a source of hydrogen in hydrous pyrolysis and, as a result, the use of -depleted water is reflected in the generated gases but not pre-existing trapped gases.

  8. Adsorption and decomposition of monopropellant molecule HAN on Pd(100) and Ir(100) surfaces: A DFT study

    Science.gov (United States)

    Banerjee, Sourav; Shetty, Sharath A.; Gowrav, M. N.; Oommen, Charlie; Bhattacharya, Atanu

    2016-11-01

    We have performed density functional theory calculations with the generalized gradient approximation to investigate the catalytic decomposition reactions of one of the most promising monopropellants, hydroxylammonium nitrate (HAN), on two catalytically active single crystal Pd(100) and Ir(100) surfaces, aiming at exploring different reaction pathways and reactivities of these two surfaces towards the catalytic decomposition of HAN. We find that the HAN molecule binds both the Pd(100) and Ir(100) surfaces molecularly in different orientations with respect to the surface. The HONO elimination is found to possess the lowest activation energy on the Pd(100) surface; whereas, NO2 elimination is predicted to show the lowest activation energy on the Ir(100) surface. Exothermicities associated with different reaction steps are also discussed. This is the first theoretical report on the catalytic decomposition reactions of the HAN molecule on the single crystal Pd(100) and the Ir(100) surfaces using the periodic DFT calculations.

  9. Accounting for fuel price risk when comparing renewable togas-fired generation: the role of forward natural gas prices

    Energy Technology Data Exchange (ETDEWEB)

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2004-07-17

    Unlike natural gas-fired generation, renewable generation (e.g., from wind, solar, and geothermal power) is largely immune to fuel price risk. If ratepayers are rational and value long-term price stability, then--contrary to common practice--any comparison of the levelized cost of renewable to gas-fired generation should be based on a hedged gas price input, rather than an uncertain gas price forecast. This paper compares natural gas prices that can be locked in through futures, swaps, and physical supply contracts to contemporaneous long-term forecasts of spot gas prices. We find that from 2000-2003, forward gas prices for terms of 2-10 years have been considerably higher than most contemporaneous long-term gas price forecasts. This difference is striking, and implies that comparisons between renewable and gas-fired generation based on these forecasts over this period have arguably yielded results that are biased in favor of gas-fired generation.

  10. Organic richness and gas generation potential of Permian Barren Measures from Raniganj field, West Bengal, India

    Indian Academy of Sciences (India)

    Annapurna Boruah; S Ganapathi

    2015-07-01

    The organic geochemistry of shales in terms of its organic richness, hydrocarbon source potential, thermal maturity, depositional environment, etc., are essential stipulations for shale gas resources assessment. In this study, a total of 32 core samples of Permian Barren Measures from four boreholes in Raniganj field of Damodar Basin were analysed to evaluate their gas generation potential using Rock–Eval pyrolysis techniques. Petrographic analysis brings out the lithofacies of Barren Measures as carbonaceous silty shale, iron rich claystone and sand-shale intercalation. The total organic content (TOC) of the shale units of Barren Measures ranges from 3.75 to 20.9 wt%, whereas hydrogen index (HI) ranges from 58.45 to 125.34 mg HC/g TOC. Present study suggests early to late maturated (0.6–1%) organic matters in Barren Measures with gas prone type III kerogen. The study analysed the effect of burial history on the preservation and maturation of organic matters. The organic richness, kerogen type, thermal maturity and petrographic properties of Barren Measures signify fair to excellent gas generation potential.

  11. Rapid hydrogen gas generation using reactive thermal decomposition of uranium hydride.

    Energy Technology Data Exchange (ETDEWEB)

    Kanouff, Michael P.; Van Blarigan, Peter; Robinson, David B.; Shugard, Andrew D.; Gharagozloo, Patricia E.; Buffleben, George M.; James, Scott Carlton; Mills, Bernice E.

    2011-09-01

    Oxygen gas injection has been studied as one method for rapidly generating hydrogen gas from a uranium hydride storage system. Small scale reactors, 2.9 g UH{sub 3}, were used to study the process experimentally. Complimentary numerical simulations were used to better characterize and understand the strongly coupled chemical and thermal transport processes controlling hydrogen gas liberation. The results indicate that UH{sub 3} and O{sub 2} are sufficiently reactive to enable a well designed system to release gram quantities of hydrogen in {approx} 2 seconds over a broad temperature range. The major system-design challenge appears to be heat management. In addition to the oxidation tests, H/D isotope exchange experiments were performed. The rate limiting step in the overall gas-to-particle exchange process was found to be hydrogen diffusion in the {approx}0.5 {mu}m hydride particles. The experiments generated a set of high quality experimental data; from which effective intra-particle diffusion coefficients can be inferred.

  12. Piezoelectric transformers for low-voltage generation of gas discharges and ionic winds in atmospheric air

    Science.gov (United States)

    Johnson, Michael J.; Go, David B.

    2015-12-01

    To generate a gas discharge (plasma) in atmospheric air requires an electric field that exceeds the breakdown threshold of ˜30 kV/cm. Because of safety, size, or cost constraints, the large applied voltages required to generate such fields are often prohibitive for portable applications. In this work, piezoelectric transformers are used to amplify a low input applied voltage (corona-like discharges on its corners or on adjacent electrodes. In the proper configuration, these discharges can be used to generate a bulk air flow called an ionic wind. In this work, PT-driven discharges are characterized by measuring the discharge current and the velocity of the induced ionic wind with ionic winds generated using input voltages as low as 7 V. The characteristics of the discharge change as the input voltage increases; this modifies the resonance of the system and subsequent required operating parameters.

  13. Life Cycle Water Consumption and Wastewater Generation Impacts of a Marcellus Shale Gas Well

    OpenAIRE

    Jiang, Mohan; Hendrickson, Chris T.; VanBriesen, Jeanne M.

    2013-01-01

    This study estimates the life cycle water consumption and wastewater generation impacts of a Marcellus shale gas well from its construction to end of life. Direct water consumption at the well site was assessed by analysis of data from approximately 500 individual well completion reports collected in 2010 by the Pennsylvania Department of Conservation and Natural Resources. Indirect water consumption for supply chain production at each life cycle stage of the well was estimated using the econ...

  14. Second harmonic generation in a centrosymmetric gas medium with spatiotemporally focused intense femtosecond laser pulses

    CERN Document Server

    Li, Guihua; Xie, Hongqiang; Zeng, Bin; Yao, Jinping; Chu, Wei; Zhang, Haisu; Jing, Chenrui; He, Fei; Xu, Huailiang; Cheng, Ya; Xu, Zhizhan

    2013-01-01

    We demonstrate unexpectedly strong second harmonic generation (SHG) in Argon gas by use of spatiotemporally focused (SF) femtosecond laser pulses. The resulting SHG by the SF scheme at a 75 cm distance shows a significantly enhanced efficiency than that achieved with conventional focusing scheme, which offers a new promising possibility for standoff applications. Our theoretical calculations reasonably reproduce the experimental observations, which indicate that the observed SHG mainly originates from the gradient of nonuniform plasma dynamically controlled by the SF laser field.

  15. DESIGN, FABRICATION, AND TESTING OF AN ADVANCED, NON-POLLUTING TURBINE DRIVE GAS GENERATOR

    Energy Technology Data Exchange (ETDEWEB)

    Stephen E. Doyle

    2002-12-31

    The objectives of this report period were to continue and complete testing of the Gas Generator hardware, to complete and submit a Draft Final Report, and after incorporation of adjustments required, to then submit the Final Report. Focus during this report period was initially on testing the Gas Generator. While conducting scheduled full power tests of the Gas Generator at the facilities of the testing sub-contractor, National Testing Services [NTS], in Santa Clarita CA, anomalies in the performance of the Gas Generator were discovered. All testing was stopped on November 6, 2002. An expert team was formed to evaluate the anomalies and to recommend any appropriate corrective actions. After extensive analyses of the actual hardware, the test data acquired and recorded during testing, and a review of the test facilities and procedures, the Anomalies Review Team recommended that CES modify the combustion chamber front end cooling method and modify the configuration of the diluent injectors downstream of the combustion chamber, to eliminate the anomalies. At a review meeting convened in Sacramento CA on November 23, 2002, outside experts from the Lawrence Livermore National Laboratory, Air Liquide's Research Center in Chicago IL, and the California Energy Commission, confirmed that the expert team's assessed cause of the problem was the likely cause, and the recommended corrective actions were appropriate. Modified hardware drawings were produced in late November-early December 2002, hardware fabrication was begun in December, and was in process at the end of December. Also during December, the NTS test facility was being adjusted to take account of the modified hardware configuration being produced. All work was aimed toward realizing a schedule of resumed testing by mid-January for completion of tests by end of January or early February, 2003. Original objectives of the program remain in place and approximately ninety (90) percent of those objectives had

  16. Instantaneous insulation in a micro-slab: A mechanism for flow generation in a rarefied gas

    Science.gov (United States)

    Manela, A.; Pogorelyuk, L.

    2016-12-01

    We analyze the response of a gas in a micro-slab, set at an initial pure-conduction state, to instantaneous thermal insulation of its boundaries. In line with ongoing efforts in generating gas flows at the microscale, thermal insulation is suggested as a means for flow excitation with no moving parts. The problem is analyzed in the entire range of gas rarefaction rates and for arbitrary initial temperature differences between the walls. Analytical solutions are obtained in the linearized limit of small temperature differences for large (collisionless) and small (continuum) Knudsen numbers. These solutions are supported by direct simulation Monte Carlo calculations, which are then used to investigate the nonlinear problem with large initial temperature differences. Followed by the system's initial state, boundary insulation results in a series of time-decaying waves, propagating across the slab, and transferring the system between its conductive and adiabatic equilibrium states. While larger initial temperature differences result in higher flow rates, it is found that nonlinear effects reduce the efficiency of flow excitation through boundaries insulation. At high Knudsen numbers, this is rationalized through the system's initial state, in which the gas uniform temperature is lower than the arithmetic mean of walls temperatures. At low Knudsen numbers, the dominant effect of molecular collisions causes thermal dissipation, which in turn results in kinetic energy losses. The analysis may be readily applied to calculate the gas response to arbitrary time variations of the boundary-imposed heat flux.

  17. A three-dimensional algebraic grid generation scheme for gas turbine combustors with inclined slots

    Science.gov (United States)

    Yang, S. L.; Cline, M. C.; Chen, R.; Chang, Y. L.

    1993-01-01

    A 3D algebraic grid generation scheme is presented for generating the grid points inside gas turbine combustors with inclined slots. The scheme is based on the 2D transfinite interpolation method. Since the scheme is a 2D approach, it is very efficient and can easily be extended to gas turbine combustors with either dilution hole or slot configurations. To demonstrate the feasibility and the usefulness of the technique, a numerical study of the quick-quench/lean-combustion (QQ/LC) zones of a staged turbine combustor is given. Preliminary results illustrate some of the major features of the flow and temperature fields in the QQ/LC zones. Formation of co- and counter-rotating bulk flow and shape temperature fields can be observed clearly, and the resulting patterns are consistent with experimental observations typical of the confined slanted jet-in-cross flow. Numerical solutions show the method to be an efficient and reliable tool for generating computational grids for analyzing gas turbine combustors with slanted slots.

  18. Effect of Orifice Diameter on Bubble Generation Process in Melt Gas Injection to Prepare Aluminum Foams

    Science.gov (United States)

    Yuan, Jianyu; Li, Yanxiang; Wang, Ningzhen; Cheng, Ying; Chen, Xiang

    2016-06-01

    The bubble generation process in conditioned A356 alloy melt through submerged spiry orifices with a wide diameter range (from 0.07 to 1.0 mm) is investigated in order to prepare aluminum foams with fine pores. The gas flow rate and chamber pressure relationship for each orifice is first determined when blowing gas in atmospheric environment. The effects of chamber pressure ( P c) and orifice diameter ( D o) on bubble size are then analyzed separately when blowing gas in melt. A three-dimensional fitting curve is obtained illustrating both the influences of orifice diameter and chamber pressure on bubble size based on the experimental data. It is found that the bubble size has a V-shaped relationship with orifice diameter and chamber pressure neighboring the optimized parameter ( D o = 0.25 mm, P c = 0.4 MPa). The bubble generation mechanism is proposed based on the Rayleigh-Plesset equation. It is found that the bubbles will not be generated until a threshold pressure difference is reached. The threshold pressure difference is dependent on the orifice diameter, which determines the time span of pre-formation stage and bubble growth stage.

  19. Mass flow discharge and total temperature characterisation of a pyrotechnic gas generator formulation for airbag systems

    Energy Technology Data Exchange (ETDEWEB)

    Neutz, Jochen; Koenig, Andreas [Fraunhofer Institut fuer Chemische Technologie ICT, Pfinztal (Germany); Knauss, Helmut; Jordan, Sebastian; Roediger, Tim; Smorodsky, Boris [Universitaet Stuttgart (Germany). Institut fuer Aerodynamik und Gasdynamik; Bluemcke, Erich Walter [AUDI AG, Department I/EK-523, Ingolstadt (Germany)

    2009-06-15

    The mass flow characteristics of gas generators for airbag applications have to comply with a number of requirements for an optimal deployment of the airbag itself. Up to now, the mass flow was determined from pressure time histories of so-called can tests. This procedure suffers from the missing knowledge on the temperature of the generated gas entering the can. A new test setup described in this paper could overcome this problem by providing highly time resolved information on the gas's total temperature and the mass flow of the generator. The test setup consisted of a combustion chamber with a specially designed Laval nozzle in combination with a temperature sensor of high time resolution. The results showed a high time resolved temperature signal, which was disturbed by the formation of a slag layer on the sensor. Plausibility considerations with experimentally and thermodynamically determined combustion temperatures led to satisfying results for the overall temperature as characteristic parameter of airbag inflating gases flows from pyrotechnics. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

  20. Slurry growth, gas retention, and flammable gas generation by Hanford radioactive waste tanks: Synthetic waste studies, FY 1991

    Energy Technology Data Exchange (ETDEWEB)

    Bryan, S.A.; Pederson, L.R.; Ryan, J.L.; Scheele, R.D.; Tingey, J.M.

    1992-08-01

    Of 177 high-level waste storage tanks on the Hanford Site, 23 have been placed on a safety watch list because they are suspected of producing flammable gases in flammable or explosive concentrate. One tankin particular, Tank 241-SY-101 (Tank 101-SY), has exhibited slow increases in waste volume followed by a rapid decrease accompanied by venting of large quantities of gases. The purpose of this study is to help determine the processes by which flammable gases are produced, retained, and eventually released from Tank 101-SY. Waste composition data for single- and double-shell waste tanks on the flammable gas watch listare critically reviewed. The results of laboratory studies using synthetic double-shell wastes are summarized, including physical and chemical properties of crusts that are formed, the stoichiometry and rate ofgas generation, and mechanisms responsible for formation of a floating crust.

  1. Numerical Study of the Working Process in the Reducing Gas Generator of the Upper Stage Oxygen - Methane Engine

    Directory of Open Access Journals (Sweden)

    D. M. Yagodnikov

    2015-01-01

    Full Text Available This article deals with the problems of creating a reducing gas generator of the liquid rocket engine (LRE of upper stage using advanced fuel components, namely oxygen + liquid natural gas. Relevance of the work is justified by the need to create and develop of environmentally friendly missile systems for space applications using methane-based fuel (liquid natural gas. As compared to the currently used unsymmetrical dimethyl-hydrazine and kerosene, this fuel is environmentally safe, passive to corrosion, has better cooling properties and high energy characteristics in the re-generatively cooled chambers, as well as is advantageous for LRE of multiple start and use.The purpose of this work is a mathematical modeling, calculation of the working process efficiency, as well as study of gas-dynamic structure of the flow in the gas generator flow path. The object of study is the upper stage LRE gas generator, which uses the reducing scheme on the liquid propellants: oxygen + liquid methane. Research methods are based on numerical simulation.Computational studies allowed us to receive the velocity, temperatures, and concentrations of reactants and combustion products in the longitudinal section of gas generator. Analysis of the gas-dynamic structure of flow shows a complete equalization of the velocity field by 2/3 of the gas generator length. Thus, the same distance is not enough to equalize the temperature distribution of the gasification products and their concentrations in radius. Increasing the total excess oxidant ratio from 0.15 to 0.25 leads to a greater spread of the parameters at the exit of the gas generator by ~ 13 ÷ 17%. As a recommendation to reduce the size of the working area, is proposed a dual-zone gas generator-mixing scheme with fuel separately supplied to the first and second zones.

  2. Testing marine shales' ability to generate catalytic gas at low temperature

    Science.gov (United States)

    Wei, L.; Schimmelmann, A.; Drobniak, A.; Sauer, P. E.; Mastalerz, M.

    2013-12-01

    Hydrocarbon gases are generally thought to originatevia low-temperature microbial or high-temperature thermogenicpathways (Whiticar, 1996) that can be distinguished by compound-specific hydrogen and carbon stable isotope ratios. An alternative low-temperature catalytic pathway for hydrocarbon generation from sedimentary organic matter has been proposed to be active at temperatures as low as 50oC (e.g.,Mango and Jarvie,2009,2010; Mango et al., 2010; Bartholomew et al., 1999). This hypothesis, however, still requires rigoroustesting by independent laboratory experiments.The possibility of catalytic generation of hydrocarbons in some source rocks (most likely in relatively impermeable and organic-rich shales where reduced catalytic centers can be best preserved) would offer an explanation for the finding of gas of non-microbial origin in formations that lack the thermal maturity for generating thermogenic gas.It is unknown whether catalytically generated methane would be isotopically different from thermogenicmethane (δ13CCH4>-50‰, δ2HCH4from -275‰ to -100‰) ormicrobially generated methane (δ13CCH4from -40‰ to -110‰, δ2HCH4from -400‰to -150‰) (Whiticar, 1998). In order to test for catalytic gas generationin water-wet shales and coals, we are conductinglaboratory experiments at three temperatures (60°C, 100°C, 200°C)and three pressures (ambient pressure, 107 Pa, 3x107 Pa)over periods of six months to several years. So far, our longest running experiments have reached one year. We sealed different types of thermally immature, pre-evacuatedshales (Mowry, New Albany, and Mahoganyshales) and coals (SpringfieldCoal and Wilcoxlignite)with isotopically defined waters in gold cells in the absence of elemental oxygen.Preliminary results show that these samples, depending on conditions, can generate light hydrocarbon gases (methane, ethane and propane) and CO2. Methane, CO2, and traces of H2havebeen generated at 60°C, whereas experiments at 100°C and 200

  3. Using a Gas-Phase Tracer Test to Characterize the Impact of Landfill Gas Generation on Advective-Dispersive Transport of VOCs in the Vadose Zone.

    Science.gov (United States)

    Monger, Gregg R; Duncan, Candice Morrison; Brusseau, Mark L

    2014-12-01

    A gas-phase tracer test (GTT) was conducted at a landfill in Tucson, AZ, to help elucidate the impact of landfill gas generation on the transport and fate of chlorinated aliphatic volatile organic contaminants (VOCs). Sulfur hexafluoride (SF6) was used as the non-reactive gas tracer. Gas samples were collected from a multiport monitoring well located 15.2 m from the injection well, and analyzed for SF6, CH4, CO2, and VOCs. The travel times determined for SF6 from the tracer test are approximately two to ten times smaller than estimated travel times that incorporate transport by only gas-phase diffusion. In addition, significant concentrations of CH4 and CO2 were measured, indicating production of landfill gas. Based on these results, it is hypothesized that the enhanced rates of transport observed for SF6 are caused by advective transport associated with landfill gas generation. The rates of transport varied vertically, which is attributed to multiple factors including spatial variability of water content, refuse mass, refuse permeability, and gas generation.

  4. The new 6 MW gas turbine for the power generation; Die neue 6 MW Gasturbine fuer die Stromerzeugung

    Energy Technology Data Exchange (ETDEWEB)

    Blaswich, Michael; Theis, Sascha [MAN Diesel and Turbo SE, Oberhausen (Germany)

    2012-07-01

    MAN Diesel and Turbo SE (Oberhausen, Federal Republic of Germany) had developed a new gas turbine in the 6 MW class. This device is the founding stone for a family of gas turbines which at first cover the power range from 6 to 8 MW for the propulsion of pumps, compressors and electric devices. The two-shaft industrial gas turbine consists of a gas generator with an axial compressor with eleven levels, six external single combustion chambers, one two-step high-pressure turbine and a two-step power turbine. Beside the two-shaft industrial gas turbine, there exists a single-shaft industrial gas turbine for the power generation. The single-shaft industrial gas turbine consists of three turbine stages, a gas turbine compressor and combustion chamber being identical in construction to the two-shaft industrial gas turbine. The gas turbine package contains the gas turbine module as well as a filter module. The gas turbine was successfully tested. Further tests and the commissioning of the first customer's plant are planned for this year.

  5. Evaluation of potential opportunities for electric power generation from landfill gas at “Tsalapitsa”

    Directory of Open Access Journals (Sweden)

    Ganev Ivaylo

    2014-01-01

    Full Text Available Potential opportunities for electric power generation from landfill gas (LFG utilization were estimated for the second largest landfill site in Bulgaria, situated near the city of Plovdiv. The work performed was based on detailed analysis of experimentally obtained and model-predicted features of the “Tsalapitsa” landfill site. The study presents a short description of the site, the global characteristics of the disposed municipal solid waste, and the experimentally obtained methane composition of the LFG. Based on the above described observations, the potential for LFG recovery at “Tsalapitsa” was determined, together with that for electric power generation for the next 25 years. A set of recommendations was then developed regarding the parameters required for the installation of electric power generation from LFG in Plovdiv.

  6. Determining the Main Gas-generation Phase of Marine Organic Matters in Different Occurrence States using the Kinetic Method

    Institute of Scientific and Technical Information of China (English)

    WANG Yunpeng; ZHAO Changyi; WANG Zhaoyun; WANG Hongjun; ZOU Yanrong; LIU Jinzhong; ZHAO Wenzhi; LIU Dehan; LU Jialan

    2008-01-01

    This paper probes the determination of the main gas-generation phase of marine organic mattes using the kinetic method. The main gas-generation phase of marine organic matters was determined by coupling the gas generation yields and rates in geological history computed by the acquired kinetic parameters of typical marine organic matters (reservoir oil, residual bitumen, low-maturity kerogen and residual kerogen) in both China and abroad and maturity by the EasyRo(%) method. Here, the main gas-generation phase was determined as Ro%=1.4%-2.4% for type Ⅰ kerogen, Ro%=1.5-3.0% for low-maturity type Ⅱ kerogen, Ro%=1.4-2.8% for residual kerogen,Ro%=1.5-3.2% for residual bitumen and Ro%=1.6-3.2% for reservoir oil cracking. The influences on the main gas-generation phase from the openness of the simulated system and the "dead line" of natural gas generation are also discussed. The results indicate that the openness of simulation system has a definite influence on computing the main gas-generation phase. The main gas-generation phase of type Ⅱ kerogen is Ro%=1.4-3.1% in an open system, which is earlier than that in a closed system.According to our results, the "dead line" of natural gas generation is determined as Ro=3.5% for type Ⅰ kerogen, Ro=4.4-4.5% for type Ⅱ kerogen and Ro=4.6% for marine oil. Preliminary applications are presented taking the southwestern Tarim Basin as an example.

  7. Methane gas generation from waste water extraction process of crude palm oil in experimental digesters

    Science.gov (United States)

    Dillon, A.; Penafiel, R.; Garzón, P. V.; Ochoa, V.

    2015-12-01

    Industrial processes to extract crude palm oil, generates large amounts of waste water. High concentrations of COD, ST, SV, NH4 + and low solubility of O2, make the treatment of these effluents starts with anaerobic processes. The anaerobic digestion process has several advantages over aerobic degradation: lower operating costs (not aeration), low sludge production, methane gas generation. The 4 stages of anaerobic digestion are: hydrolysis, acidogenic, acetogenesis and methanogenesis. Through the action of enzymes synthesized by microbial consortia are met. The products of each step to serve as reagents is conducted as follows. The organic load times and cell hydraulic retention, solids content, nutrient availability, pH and temperature are factors that influence directly in biodigesters. The objectives of this presentation is to; characterize the microbial inoculum and water (from palm oil wasted water) to be used in biodigestores, make specific methanogenic activity in bioassays, acclimatize the microorganisms to produce methane gas using basal mineral medium with acetate for the input power, and to determine the production of methane gas digesters high organic load.

  8. Effects of Surfactant Contamination on the Next Generation Gas Trap for the ISS Internal Thermal Control System

    Science.gov (United States)

    Leimkuehler, Thomas O.; Lukens, Clark; Reeves, Daniel R.; Holt, James M.

    2004-01-01

    The current dual-membrane gas trap is designed to remove non-condensed gas bubbles from the Internal Thermal Control System (ITCS) coolant on board the International Space Station (ISS). To date it has successfully served its purpose of preventing gas bubbles from causing depriming, overspeed, and shutdown of the ITCS pump. However, contamination in the ITCS coolant has adversely affected the gas venting rate and lifetime of the gas trap, warranting a development effort for a next-generation gas trap. Previous testing has shown that a hydrophobic-only design is capable of performing even better than the current dual-membrane design for both steady-state gas removal and gas slug removal in clean deionized water. This paper presents results of testing to evaluate the effects of surfactant contamination on the steady-state performance of the hydrophobic-only design.

  9. Generation of naphthoquinone radical anions by electrospray ionization: solution, gas-phase, and computational chemistry studies.

    Science.gov (United States)

    Vessecchi, Ricardo; Naal, Zeki; Lopes, José N C; Galembeck, Sérgio E; Lopes, Norberto P

    2011-06-02

    Radical anions are present in several chemical processes, and understanding the reactivity of these species may be described by their thermodynamic properties. Over the last years, the formation of radical ions in the gas phase has been an important issue concerning electrospray ionization mass spectrometry studies. In this work, we report on the generation of radical anions of quinonoid compounds (Q) by electrospray ionization mass spectrometry. The balance between radical anion formation and the deprotonated molecule is also analyzed by influence of the experimental parameters (gas-phase acidity, electron affinity, and reduction potential) and solvent system employed. The gas-phase parameters for formation of radical species and deprotonated species were achieved on the basis of computational thermochemistry. The solution effects on the formation of radical anion (Q(•-)) and dianion (Q(2-)) were evaluated on the basis of cyclic voltammetry analysis and the reduction potentials compared with calculated electron affinities. The occurrence of unexpected ions [Q+15](-) was described as being a reaction between the solvent system and the radical anion, Q(•-). The gas-phase chemistry of the electrosprayed radical anions was obtained by collisional-induced dissociation and compared to the relative energy calculations. These results are important for understanding the formation and reactivity of radical anions and to establish their correlation with the reducing properties by electrospray ionization analyses.

  10. Piezoelectric transformers for low-voltage generation of gas discharges and ionic winds in atmospheric air

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Michael J. [Department of Aerospace and Mechanical Engineering, University of Notre Dame, Notre Dame, Indianapolis 46556 (United States); Go, David B., E-mail: dgo@nd.edu [Department of Aerospace and Mechanical Engineering, University of Notre Dame, Notre Dame, Indianapolis 46556 (United States); Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, Indianapolis 46556 (United States)

    2015-12-28

    To generate a gas discharge (plasma) in atmospheric air requires an electric field that exceeds the breakdown threshold of ∼30 kV/cm. Because of safety, size, or cost constraints, the large applied voltages required to generate such fields are often prohibitive for portable applications. In this work, piezoelectric transformers are used to amplify a low input applied voltage (<30 V) to generate breakdown in air without the need for conventional high-voltage electrical equipment. Piezoelectric transformers (PTs) use their inherent electromechanical resonance to produce a voltage amplification, such that the surface of the piezoelectric exhibits a large surface voltage that can generate corona-like discharges on its corners or on adjacent electrodes. In the proper configuration, these discharges can be used to generate a bulk air flow called an ionic wind. In this work, PT-driven discharges are characterized by measuring the discharge current and the velocity of the induced ionic wind with ionic winds generated using input voltages as low as 7 V. The characteristics of the discharge change as the input voltage increases; this modifies the resonance of the system and subsequent required operating parameters.

  11. Singlet Oxygen Generation on Porous Superhydrophobic Surfaces: Effect of Gas Flow and Sensitizer Wetting on Trapping Efficiency

    Science.gov (United States)

    2015-01-01

    We describe physical-organic studies of singlet oxygen generation and transport into an aqueous solution supported on superhydrophobic surfaces on which silicon–phthalocyanine (Pc) particles are immobilized. Singlet oxygen (1O2) was trapped by a water-soluble anthracene compound and monitored in situ using a UV–vis spectrometer. When oxygen flows through the porous superhydrophobic surface, singlet oxygen generated in the plastron (i.e., the gas layer beneath the liquid) is transported into the solution within gas bubbles, thereby increasing the liquid–gas surface area over which singlet oxygen can be trapped. Higher photooxidation rates were achieved in flowing oxygen, as compared to when the gas in the plastron was static. Superhydrophobic surfaces were also synthesized so that the Pc particles were located in contact with, or isolated from, the aqueous solution to evaluate the relative effectiveness of singlet oxygen generated in solution and the gas phase, respectively; singlet oxygen generated on particles wetted by the solution was trapped more efficiently than singlet oxygen generated in the plastron, even in the presence of flowing oxygen gas. A mechanism is proposed that explains how Pc particle wetting, plastron gas composition and flow rate as well as gas saturation of the aqueous solution affect singlet oxygen trapping efficiency. These stable superhydrophobic surfaces, which can physically isolate the photosensitizer particles from the solution may be of practical importance for delivering singlet oxygen for water purification and medical devices. PMID:24885074

  12. Valuing natural gas power generation assets in the new competitive marketplace

    Science.gov (United States)

    Hsu, Michael Chun-Wei

    1999-10-01

    The profitability of natural gas fired power plants depends critically on the spread between electricity and natural gas prices. The price levels of these two energy commodities are the key uncertain variables in determining the operating margin and therefore the value of a power plant. The owner of a generation unit has the decision of dispatching the plant only when profit margins are positive. This operating flexibility is a real option with real value. In this dissertation I introduce the spark spread call options and illustrate how such paper contracts replicate the uncertain payoff space facing power asset owners and, therefore, how the financial options framework can be applied in estimating the value of natural gas generation plants. The intrinsic value of gas power plants is approximated as the sum of a series of spark spread call options with succeeding maturity dates. The Black-Scholes spread option pricing model, with volatility and correlation term structure adjustments, is utilized to price the spark spread options. Sensitivity analysis is also performed on the BS spread option formulation to compare different asset types. In addition I explore the potential of using compound and compound-exchange option concepts to evaluate, respectively, the benefits of delaying investment in new generation and in repowering existing antiquated units. The compound option designates an option on top of another option. In this case the series of spark spread call options is the 'underlying' option while the option to delay new investments is the 'overlying.' The compound-exchange option characterizes the opportunity to 'exchange' the old power plant, with its series of spark spread call options, for a set of new spark spread call options that comes with the new generation unit. The strike price of the compound-exchange option is the repowering capital investment and typically includes the purchase of new steam generators and combustion turbines, as well as other

  13. A study on thermodynamical properties of hot and dense hadron gas using the event generator

    CERN Document Server

    Sasaki, N

    2001-01-01

    We investigate the equilibration and the equation of state of the hot hadron gas at finite baryon density using an event generator that satisfies detailed balance at temperatures and baryon densities of present interests (80 < T < 170 MeV, 0.157 < n_B < 0.315 fm^-3). Molecular-dynamic-simulations are performed to the system of hadrons in the box with periodic boundary conditions. Starting from an initial condition composed of nucleons with uniform momentum distribution, the evolution takes place through interactions, productions and absorptions. The system approaches to a stationary state of baryons, mesons and their resonances. The system is characterized by an exponent in the energy distribution irrespective of the particle species, i.e., temperature. After the equilibration, thermodynamical quantities such as energy density, particle density, entropy and pressure are calculated. Obtained equation of state shows a remarkable deviation from the mixed free gas of mesons and baryons above T = m_pi....

  14. Gas spark switches with increased operating life for Marx generator of lightning test complex

    Energy Technology Data Exchange (ETDEWEB)

    Bykov, Yu. A.; Krastelev, E. G., E-mail: ekrastelev@yandex.ru [Russian Academy of Sciences, Joint Institute for High Temperature (Russian Federation)

    2016-12-15

    A new design of gas spark switches with an increased operating life and stable dynamic characteristics for the Marx generator of the lightning test complex has been developed. The switches are characterized by the following parameters in the mode of operation: voltage up to 80 kV, discharge current up to 50 kA, flowing charge up to 3.5 C/pulse. An increased operating life is achieved by using torus-shaped electrodes with increased working surface area and a trigger electrode in the form of a thick disk with a hole located between them. Low breakdown delay time and high stability of breakdown voltage under dynamic conditions are provided by gas preionization in the spark gap using UV radiation of an additional corona discharge in the axial region.

  15. Gas generation from radiolytic attack of TRU-contaminated hydrogenous waste

    Energy Technology Data Exchange (ETDEWEB)

    Zerwekh, A.

    1979-06-01

    In 1970, the Waste Management and Transportation Division of the Atomic Energy Commission ordered a segregation of transuranic (TRU)-contaminated solid wastes. Those below a contamination level of 10 nCi/g could still be buried; those above had to be stored retrievably for 20 y. The possibility that alpha-radiolysis of hydrogenous materials might produce toxic, corrosive, and flammable gases in retrievably stored waste prompted an investigation of gas identities and generation rates in the laboratory and field. Typical waste mixtures were synthesized and contaminated for laboratory experiments, and drums of actual TRU-contaminated waste were instrumented for field testing. Several levels of contamination were studied, as well as pressure, temperature, and moisture effects. G (gas) values were determined for various waste matrices, and degradation products were examined.

  16. Combustion Stability of the Gas Generator Assembly from J-2X Engine E10001 and Powerpack Tests

    Science.gov (United States)

    Hulka, J. R.; Kenny, R. L.; Casiano, M. J.

    2013-01-01

    Testing of a powerpack configuration (turbomachinery and gas generator assembly) and the first complete engine system of the liquid oxygen/liquid hydrogen propellant J-2X rocket engine have been completed at the NASA Stennis Space Center. The combustion stability characteristics of the gas generator assemblies on these two systems are of interest for reporting since considerable effort was expended to eliminate combustion instability during early development of the gas generator assembly with workhorse hardware. Comparing the final workhorse gas generator assembly development test data to the powerpack and engine system test data provides an opportunity to investigate how the nearly identical configurations of gas generator assemblies operate with two very different propellant supply systems one the autonomous pressure-fed test configuration on the workhorse development test stand, the other the pump-fed configurations on the powerpack and engine systems. The development of the gas generator assembly and the elimination of the combustion instability on the pressure-fed workhorse test stand have been reported extensively in the two previous Liquid Propulsion Subcommittee meetings 1-7. The powerpack and engine system testing have been conducted from mid-2011 through 2012. All tests of the powerpack and engine system gas generator systems to date have been stable. However, measureable dynamic behavior, similar to that observed on the pressure-fed test stand and reported in Ref. [6] and attributed to an injection-coupled response, has appeared in both powerpack and engine system tests. As discussed in Ref. [6], these injection-coupled responses are influenced by the interaction of the combustion chamber with a branch pipe in the hot gas duct that supplies gaseous helium to pre-spin the turbine during the start transient. This paper presents the powerpack and engine system gas generator test data, compares these data to the development test data, and provides additional

  17. NH4HCO3 gas-generating liposomal nanoparticle for photoacoustic imaging in breast cancer.

    Science.gov (United States)

    Xia, Jizhu; Feng, Gang; Xia, Xiaorong; Hao, Lan; Wang, Zhigang

    2017-01-01

    In this study, we have developed a biodegradable nanomaterial for photoacoustic imaging (PAI). Its biodegradation products can be fully eliminated from a living organism. It is a gas-generating nanoparticle of liposome-encapsulating ammonium bicarbonate (NH4HCO3) solution, which is safe, effective, inexpensive, and free of side effects. When lasers irradiate these nanoparticles, NH4HCO3 decomposes to produce CO2, which can absorb much of the light energy under laser irradiation with a specific wavelength, and then expand under heat to generate a thermal acoustic wave. An acoustic detector can detect this wave and show it as a photoacoustic signal on a display screen. The intensity of the photoacoustic signal is enhanced corresponding to an increase in time, concentration, and temperature. During in vivo testing, nanoparticles were injected into tumor-bearing nude mice through the caudal vein, and photoacoustic signals were detected from the tumor, reaching a peak in 4 h, and then gradually disappearing. There was no damage to the skin or subcutaneous tissue from laser radiation. Our developed gas-generating nanomaterial, NH4HCO3 nanomaterial, is feasible, effective, safe, and inexpensive. Therefore, it is a promising material to be used in clinical PAI.

  18. NH4HCO3 gas-generating liposomal nanoparticle for photoacoustic imaging in breast cancer

    Science.gov (United States)

    Xia, Jizhu; Feng, Gang; Xia, Xiaorong; Hao, Lan; Wang, Zhigang

    2017-01-01

    In this study, we have developed a biodegradable nanomaterial for photoacoustic imaging (PAI). Its biodegradation products can be fully eliminated from a living organism. It is a gas-generating nanoparticle of liposome-encapsulating ammonium bicarbonate (NH4HCO3) solution, which is safe, effective, inexpensive, and free of side effects. When lasers irradiate these nanoparticles, NH4HCO3 decomposes to produce CO2, which can absorb much of the light energy under laser irradiation with a specific wavelength, and then expand under heat to generate a thermal acoustic wave. An acoustic detector can detect this wave and show it as a photoacoustic signal on a display screen. The intensity of the photoacoustic signal is enhanced corresponding to an increase in time, concentration, and temperature. During in vivo testing, nanoparticles were injected into tumor-bearing nude mice through the caudal vein, and photoacoustic signals were detected from the tumor, reaching a peak in 4 h, and then gradually disappearing. There was no damage to the skin or subcutaneous tissue from laser radiation. Our developed gas-generating nanomaterial, NH4HCO3 nanomaterial, is feasible, effective, safe, and inexpensive. Therefore, it is a promising material to be used in clinical PAI. PMID:28293107

  19. NH4HCO3 gas-generating liposomal nanoparticle for photoacoustic imaging in breast cancer

    Directory of Open Access Journals (Sweden)

    Xia J

    2017-03-01

    Full Text Available Jizhu Xia, Gang Feng, Xiaorong Xia, Lan Hao, Zhigang Wang Chongqing Key Laboratory of Ultrasound Molecular Imaging, Department of Ultrasound, The Second Affiliated Hospital of Chongqing Medical University, Chongqing, People’s Republic of China Abstract: In this study, we have developed a biodegradable nanomaterial for photoacoustic imaging (PAI. Its biodegradation products can be fully eliminated from a living organism. It is a gas-generating nanoparticle of liposome-encapsulating ammonium bicarbonate (NH4HCO3 solution, which is safe, effective, inexpensive, and free of side effects. When lasers irradiate these nanoparticles, NH4HCO3 decomposes to produce CO2, which can absorb much of the light energy under laser irradiation with a specific wavelength, and then expand under heat to generate a thermal acoustic wave. An acoustic detector can detect this wave and show it as a photoacoustic signal on a display screen. The intensity of the photoacoustic signal is enhanced corresponding to an increase in time, concentration, and temperature. During in vivo testing, nanoparticles were injected into tumor-bearing nude mice through the caudal vein, and photoacoustic signals were detected from the tumor, reaching a peak in 4 h, and then gradually disappearing. There was no damage to the skin or subcutaneous tissue from laser radiation. Our developed gas-generating nanomaterial, NH4HCO3 nanomaterial, is feasible, effective, safe, and inexpensive. Therefore, it is a promising material to be used in clinical PAI. Keywords: Photoacoustic tomography, CO2, NH4HCO3, contrast agent, cancer

  20. Partial catalytic oxidation of CH{sub 4} to synthesis gas for power generation - Final report

    Energy Technology Data Exchange (ETDEWEB)

    Mantzaras, I.; Schneider, A.

    2006-03-15

    The partial oxidation of methane to synthesis gas over rhodium catalysts has been investigated experimentally and numerically in the pressure range of 4 to 10 bar. The methane/oxidizer feed has been diluted with large amounts of H{sub 2}O and CO{sub 2} (up to 70% vol.) in order to simulate new power generation cycles with large exhaust gas recycle. Experiments were carried out in an optically accessible channel-flow reactor that facilitated laser-based in situ measurements, and also in a subscale gas-turbine catalytic reactor. Full-elliptic steady and transient two-dimensional numerical codes were used, which included elementary hetero-/homogeneous chemical reaction schemes. The following are the key conclusions: a) Heterogeneous (catalytic) and homogeneous (gas-phase) schemes have been validated for the partial catalytic oxidation of methane with large exhaust gas recycle. b) The impact of added H{sub 2}O and CO{sub 2} has been elucidated. The added H{sub 2}O increased the methane conversion and hydrogen selectivity, while it decreased the CO selectivity. The chemical impact of CO{sub 2} (dry reforming) was minimal. c) The numerical model reproduced the measured catalytic ignition times. It was further shown that the chemical impact of H{sub 2}O and CO{sub 2} on the catalytic ignition delay times was minimal. d) The noble metal dispersion increased with different support materials, in the order Rh/{alpha}-Al{sub 2}O{sub 3}, Rh/ZrO{sub 2}, and Rh/Ce-ZrO{sub 2}. An evident relationship was established between the noble metal dispersion and the catalytic behavior. (authors)

  1. Increased capability gas generator for Space Shuttle APU. Development/hot restart test report

    Science.gov (United States)

    1980-01-01

    The design, fabrication, and testing of an increased capability gas generator for use in space shuttles are described. Results show an unlimited hot restart capability in the range of feed pressures from 400 psi to 80 psi. Effects of vacuum on hot restart were not addressed, and only beginning-of-life bed conditions were tested. No starts with bubbles were performed. A minimum expected life of 35 hours or more is projected, and the design will maintain a surface temperature of 350 F or more.

  2. The generation of electricity by gas turbines using the catalytic combustion of low-Btu gases

    DEFF Research Database (Denmark)

    Frederiksen, O.P.; Qvale, Einar Bjørn

    1989-01-01

    Various systems for the generation of electricity by gas turbines using catalytic combustion of low-Btu gases have been investigated. Parametric studies of three configurations that are deemed to be practically feasible have been completed. It is shown that thermodynamic efficiency of these systems...... may be quite high. The system design has been made to comply with generally accepted limitations on the operation of the compressors, turbines and heat exchangers. The heat catalyst has been investigated experimentally in order to establish design information. The system design has been carried out...... on the basis of these experiments and of commonly accepted limits on the operation of the compressors, turbines, and heat exchangers...

  3. Life cycle water consumption and wastewater generation impacts of a Marcellus shale gas well.

    Science.gov (United States)

    Jiang, Mohan; Hendrickson, Chris T; VanBriesen, Jeanne M

    2014-01-01

    This study estimates the life cycle water consumption and wastewater generation impacts of a Marcellus shale gas well from its construction to end of life. Direct water consumption at the well site was assessed by analysis of data from approximately 500 individual well completion reports collected in 2010 by the Pennsylvania Department of Conservation and Natural Resources. Indirect water consumption for supply chain production at each life cycle stage of the well was estimated using the economic input-output life cycle assessment (EIO-LCA) method. Life cycle direct and indirect water quality pollution impacts were assessed and compared using the tool for the reduction and assessment of chemical and other environmental impacts (TRACI). Wastewater treatment cost was proposed as an additional indicator for water quality pollution impacts from shale gas well wastewater. Four water management scenarios for Marcellus shale well wastewater were assessed: current conditions in Pennsylvania; complete discharge; direct reuse and desalination; and complete desalination. The results show that under the current conditions, an average Marcellus shale gas well consumes 20,000 m(3) (with a range from 6700 to 33,000 m(3)) of freshwater per well over its life cycle excluding final gas utilization, with 65% direct water consumption at the well site and 35% indirect water consumption across the supply chain production. If all flowback and produced water is released into the environment without treatment, direct wastewater from a Marcellus shale gas well is estimated to have 300-3000 kg N-eq eutrophication potential, 900-23,000 kg 2,4D-eq freshwater ecotoxicity potential, 0-370 kg benzene-eq carcinogenic potential, and 2800-71,000 MT toluene-eq noncarcinogenic potential. The potential toxicity of the chemicals in the wastewater from the well site exceeds those associated with supply chain production, except for carcinogenic effects. If all the Marcellus shale well wastewater is

  4. Life Cycle Water Consumption and Wastewater Generation Impacts of a Marcellus Shale Gas Well

    Science.gov (United States)

    2013-01-01

    This study estimates the life cycle water consumption and wastewater generation impacts of a Marcellus shale gas well from its construction to end of life. Direct water consumption at the well site was assessed by analysis of data from approximately 500 individual well completion reports collected in 2010 by the Pennsylvania Department of Conservation and Natural Resources. Indirect water consumption for supply chain production at each life cycle stage of the well was estimated using the economic input–output life cycle assessment (EIO-LCA) method. Life cycle direct and indirect water quality pollution impacts were assessed and compared using the tool for the reduction and assessment of chemical and other environmental impacts (TRACI). Wastewater treatment cost was proposed as an additional indicator for water quality pollution impacts from shale gas well wastewater. Four water management scenarios for Marcellus shale well wastewater were assessed: current conditions in Pennsylvania; complete discharge; direct reuse and desalination; and complete desalination. The results show that under the current conditions, an average Marcellus shale gas well consumes 20 000 m3 (with a range from 6700 to 33 000 m3) of freshwater per well over its life cycle excluding final gas utilization, with 65% direct water consumption at the well site and 35% indirect water consumption across the supply chain production. If all flowback and produced water is released into the environment without treatment, direct wastewater from a Marcellus shale gas well is estimated to have 300–3000 kg N-eq eutrophication potential, 900–23 000 kg 2,4D-eq freshwater ecotoxicity potential, 0–370 kg benzene-eq carcinogenic potential, and 2800–71 000 MT toluene-eq noncarcinogenic potential. The potential toxicity of the chemicals in the wastewater from the well site exceeds those associated with supply chain production, except for carcinogenic effects. If all the Marcellus shale well

  5. Transition metal catalysis in the generation of petroleum and natural gas. Final report, September 1, 1992--October 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Mango, F.D.

    1997-01-21

    This project originated on the premise that natural gas could be formed catalytically in the earth rather than thermally as commonly believed. The intention was to test this hypothetical view and to explore generally the role of sedimentary metals in the generation of light hydrocarbons (C1 - C9). We showed the metalliferous source rocks are indeed catalytic in the generation of natural gas. Various metal compounds in the pure state show the same levels of catalytic activity as sedimentary rocks and the products are identical. Nickel is particularly active among the early transition metals and is projected to remain catalytically robust at all stages of catagenesis. Nickel oxide promotes the formation of n-alkanes in addition to natural gas (NG), demonstrating the full scope of the hypothetical catalytic process. The composition of catalytic gas duplicates the entire range of natural gas, from so-called wet gas to dry gas (60 to 95+ wt % methane), while gas generated thermally is consistently depleted in methane (10 to 60 wt % methane). These results support the view that metal catalysis is a major pathway through which natural gas is formed in the earth.

  6. Control strategies for gas turbine generators for grid connected and islanding operations

    DEFF Research Database (Denmark)

    Mahat, Pukar; Chen, Zhe; Bak-Jensen, Birgitte

    2010-01-01

    Islanding operation of distribution systems with distributed generations (DG) is becoming a viable option for economical and technical reasons. However, there are various issues to be resolved before it can be a reality. One of the main issues is control of the DG. Control strategies, that may work...... fine while a DG is connected to a grid, might not work as desired while it is islanded and vise versa. This paper presents a strategy to operate distribution systems with a small gas turbine generator (GTG), which is capable of supplying local loads, in both islanding and grid connected conditions....... Separate strategies are used to control the GTG while it is connected to the grid and while it is islanded. Switching between the control strategies is achieved through a state detection algorithm that includes islanding and grid re-connection detections. An existing islanding detection technique has been...

  7. Application of pyrolysis gas chromatography technique to evaluation of coal-generated hydrocarbon

    Institute of Scientific and Technical Information of China (English)

    孙永革; 盛国英; 傅家谟

    1997-01-01

    Based on kerogen-generated hydrocarbon model, a new method to calculate hydrocarbon yields for coals and coaly samples was put forward by means of pyrolysis technique. At the same time, the empirical criteria suggested by Powell were revised. The threshold value was preliminarily defined as HC yields >30 mg HC per gram TOC for effective gas source rocks and >60 mg HC per gram TOC for effective oil source rocks. Additionally, it was also confirmed that the relative compositions of the three ranges of C1-C5 total hydrocarbons, C6-C14 n-alkanes plus n-alkenes and C15+ n-alkanes plus n-alkenes from pyrolysates can be effectively used to distinguish the coal-generated hydrocarbon types.

  8. PV output smoothing using a battery and natural gas engine-generator.

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Jay Dean; Ellis, Abraham; Denda, Atsushi; Morino, Kimio; Shinji, Takao; Ogata, Takao; Tadokoro, Masayuki

    2013-02-01

    In some situations involving weak grids or high penetration scenarios, the variability of photovoltaic systems can affect the local electrical grid. In order to mitigate destabilizing effects of power fluctuations, an energy storage device or other controllable generation or load can be used. This paper describes the development of a controller for coordinated operation of a small gas engine-generator set (genset) and a battery for smoothing PV plant output. There are a number of benefits derived from using a traditional generation resource in combination with the battery; the variability of the photovoltaic system can be reduced to a specific level with a smaller battery and Power Conditioning System (PCS) and the lifetime of the battery can be extended. The controller was designed specifically for a PV/energy storage project (Prosperity) and a gas engine-generator (Mesa Del Sol) currently operating on the same feeder in Albuquerque, New Mexico. A number of smoothing simulations of the Prosperity PV were conducted using power data collected from the site. By adjusting the control parameters, tradeoffs between battery use and ramp rates could be tuned. A cost function was created to optimize the control in order to balance, in this example, the need to have low ramp rates with reducing battery size and operation. Simulations were performed for cases with only a genset or battery, and with and without coordinated control between the genset and battery, e.g., without the communication link between sites or during a communication failure. The degree of smoothing without coordinated control did not change significantly because the battery dominated the smoothing response. It is anticipated that this work will be followed by a field demonstration in the near future.

  9. Gas Production Generated from Crude Oil Biodegradation: Preliminary Study on its Aplication in Microbial Enhanced Oil Recovery (MEOR

    Directory of Open Access Journals (Sweden)

    Astri Nugroho

    2009-11-01

    Full Text Available Gas Production Generated from Crude Oil Biodegradation: Preliminary Study on its Aplication in MicrobialEnhanced Oil Recovery (MEOR. The objective of this study is to observe the capacity of gas production generatedfrom crude oil degradation by the isolated bacteria. The gas in the MEOR could increase pressure in the reservoir,decrease oil viscosity, increase oil permeability-due to the increase of the porosity and viscosity, and also increase oilvolume due to the amount of dissolved gas. A research on gas analysis of oil degradation by 6 isolated bacteria has beenconducted. The bacteria isolates including Bacillus badius (A, Bacillus circulans (B, Bacillus coagulans (C, Bacillusfirmus (D, Pasteurella avium (E and Streptobacillus moniliformis (F. The trial on gas production, gas analysis and oildegradation analysis, was carried out by using SMSS medium. The test of gas production was done by usingmicrorespirometer at 40°C. The result shows that B, C, D, E produce more gas than A and F. Gas of CO2, O2, CO, N2,CH4, and H2 were analyzed by using GC. The results show that only three gases were detected by GC i.e. CO2, N2, andO2. The concentration of CO2 and N2 gas increased while the concentration of O2 decreased over an 8th day ofobservation. CO2 gas producted by mix culture was higher than by the pure culture. On the 8th day of incubation, theproduction of CO2 gas by mix culture was 4,0452% while pure culture C and D only produced 2,4543% and 2,8729%.The mix culture increase simple hydrocarbon by 12.03% and the formation of a complex hydrocarbon by 3.07%. Themix culture (C-D generated the highest concentration of CO2 gas as well as a synergistic concortium that has ability todegrade crude oil.

  10. Trigonal tricationic ionic liquids: a generation of gas chromatographic stationary phases.

    Science.gov (United States)

    Payagala, Tharanga; Zhang, Ying; Wanigasekara, Eranda; Huang, Ke; Breitbach, Zachary S; Sharma, Pritesh S; Sidisky, Leonard M; Armstrong, Daniel W

    2009-01-01

    Trigonal tricationic ionic liquids (ILs) are a new class of ILs that appear to be unique when used as gas chromatographic stationary phases. They consist of four core structures; (1) A = mesitylene core, (2) B = benzene core, (3) C = triethylamine core, and (4) D = tri(2-hexanamido)ethylamine core; to which three identical imidazolium or phosphonium cationic moieties were attached. These were coated on fused silica capillaries, and their gas chromatographic properties were evaluated. They were characterized using a linear solvation parameter model and a number of test mixtures. On the basis of the literature, it is known that both monocationic and dicationic ILs possess almost identical polarities, solvation characteristics, and chromatographic selectivities. However, some of the trigonal tricationic ILs were quite different. The different solvation parameters and higher apparent polarities appear to generate from the more rigid trigonal geometry of these ILs, as well as their ability to retain the positive charges in relatively close proximity to one another in some cases. Their unique selectivities, retention behaviors, and separation efficiencies were demonstrated using the Grob mixture, a flavor and fragrance test mixture, alcohols/alkanes test, and FAME isomer separations. Two ILs C1 (methylimidazolium substitution) and C4 (2-hydroxyethylimidazolium substitution) had higher apparent polarities than any know IL (mono, di, and tricationic ILs) or commercial stationary phases. The tri(2-hexanamido)ethylamine core IL series proved to be very interesting in that it not only showed the highest separation efficiency for all test mixtures, but it also is the first IL stationary phase (containing NTf(2)(-) anions) that eliminates peak tailing for alcohols and other H-bonding analytes. The thermal stabilities were investigated using three methods: thermogravimetric analysis (TGA) method, temperature programmed gas chromatographic method (TPGC), and isothermal gas

  11. Flame generation and maintenance by non-stationary discharge in mixture of air and natural gas

    Science.gov (United States)

    Medeiros, Henrique De Souza; Sagas, Julio; Lacava, Pedro

    2013-09-01

    Plasma assisted combustion is a promising research field, where the high generation of reactive species by non-equilibrium plasmas is used to modify the combustion kinetics in order to improve the process either by increasing the production of specific species (like molecular hydrogen) or by decreasing pollutant emission. One typical issue observed in plasma assisted combustion is the increase of inflammability limits, i.e the observation of combustion and flame in situation where it is not observed in conventional combustion. To study the effect of a non-stationary discharge in flame generation and maintenance in a mixture for air and natural gas, the air mass flow rate was fixed in 0.80 g/s and the natural gas flow rate was varied between 0.02 and 0.14 g/s, resulting in a variation of equivalence ratio from 0.4 to 3.0. It is observed a dependence of inflammability limits with the applied power. The analysis by mass spectrometry indicates that the increase of inflammability limits with plasma is due not only applied power, but also to hydrogen production in the discharge. Visual analysis together with high speed camera measurements show a modification in spatial distribution of the flame, probably due to modifications both in flow velocity and flame velocity. Supported by FAPESP PRONEX project grant 11/50773-0.

  12. Evaluating the biogas yield and design of a biodigester to generate cooking gas from human faeces

    Directory of Open Access Journals (Sweden)

    Olawale Saheed ISMAIL

    2014-11-01

    Full Text Available Erratic power supply in the halls of residence in the University of Ibadan has been the major source of series of protest and students’ provocation on campus. Electric power is the only cheap source of energy that students use to heat and cook their food. The University claims to incur huge cost on electricity supply. An alternative energy is sought from the biogas generated from the digestion of faeces of members of the halls. The large population of the halls could be taken advantage of, as more quantity of faeces is expected daily. The first batch of the experiment, after a few days has stopped producing gas. This, as was later discovered, was as a result of low moisture content of the systems. Digester II of the batch II experiment yielded 0.00227m3 of biogas, out of which 0.0013 m3 is expected to be methane gas. A 540m3 yearly production of biogas is projected, which gave a payback period of 15 years for the cost of construction of the digester. This could be considered a free renewable energy as human faeces is a waste and readily available. Environmental impact of the methane generated and vented into the atmosphere has higher Global Warming Potential (GWP x21 than Carbon (IV oxide.

  13. Calculational technique to predict combustible gas generation in sealed radioactive waste containers

    Energy Technology Data Exchange (ETDEWEB)

    Flaherty, J.E.; Fujita, A.; Deltete, C.P.; Quinn, G.J.

    1986-05-01

    Certain forms of nuclear waste, when subjected to ionizing radiation, produce combustible mixtures of gases. The production of these gases in sealed radioactive waste containers represents a significant safety concern for the handling, shipment and storage of waste. The US Nuclear Regulatory Commission (NRC) acted on this safety concern in September 1984 by publishing an information notice requiring waste generators to demonstrate, by tests or measurements, that combustible mixtures of gases are not present in radioactive waste shipments; otherwise the waste must be vented within 10 days of shipping. A task force, formed by the Edison Electric Institute to evaluate these NRC requirements, developed a calculational method to quantify hydrogen gas generation in sealed containers. This report presents the calculational method along with comparisons to actual measured hydrogen concentrations from EPICOR II liners, vented during their preparation for shipment. As a result of this, the NRC recently altered certain waste shipment Certificates-Of-Compliance to allow calculations, as well as tests and measurements, as acceptable means of determining combustible gas concentration. This modification was due in part to work described herein.

  14. Generation of soft x-ray radiation by laser irradiation of a gas puff xenon target

    Energy Technology Data Exchange (ETDEWEB)

    Fiedorowicz, H.; Bartnik, A.; Szczurek, M. [Military Univ. of Technology, Warsaw (Poland). Inst. of Optoelectronics] [and others

    1995-12-31

    Plasmas produced from laser-irradiated gas puff xenon targets, created by pulsed injection of xenon with high-pressure solenoid valve, offer the possibility of realizing a debrisless x-ray point source for the x-ray lithography applications. In this paper the authors present results of the experimental investigations on the x-ray generation from a gas puff xenon target irradiated with nanosecond high-power laser pulses produced using two different laser facilities: a Nd:glass laser operating at 1.06 {micro}m, which generated 10--15 J pulses in 1 ns FWHM, and Nd:glass slab laser, producing pulses of 10 ns duration with energy reaching 12 J for a 0.53 {micro}m wavelength or 20 J for 1.05 {micro}m. To study the x-ray emission different x-ray diagnostic methods have been used. X-ray spectra were registered using a flat CsAP crystal spectrograph with an x-ray film or a curved KAP crystal spectrograph with a convex curvature to an x-ray CCD readout detector. X-ray images have been taken using pinhole cameras with an x-ray film or a CCD array. X-ray yield was measured with the use of semiconductor detectors (silicon photodiodes or diamond photoconductors).

  15. Montney unconventional gas : next generation, an integrated approach to optimizing wellbore completions technology

    Energy Technology Data Exchange (ETDEWEB)

    Tapper, N.; Schnell, R. [Talisman Energy Inc., Calgary, AB (Canada)

    2009-07-01

    The Montney Formation is a prolific tight gas reservoir located in the western Canadian Sedimentary Basin in British Columbia and Alberta. The key to achieving economic success in the Peace River Arch area lies with horizontal wells with multiple fractures. The driver for the next generation of completions involves using various area drilling and completion techniques as a starting point to lower the installation cost without affecting the completion or production results. This presentation discussed unconventional gas in the Montney Formation and a next generation, integrated approach to optimizing wellbore completions technology. In order to address the need to change from cemented liners with pump down plugs and perforations completions, the presentation provided background information on swellable packers that could take the place of cement. Swellpacker completion bottom hole assembly and design considerations were presented. A solution for reducing costs was presented along with 6 case histories. It was concluded that new technology is the key to reducing costs in the Montney. Technology must be thoroughly vetted by drilling and completion experts and properly applied. figs.

  16. Evaluation of the Life Cycle Greenhouse Gas Emissions from Hydroelectricity Generation Systems

    Directory of Open Access Journals (Sweden)

    Akhil Kadiyala

    2016-06-01

    Full Text Available This study evaluated the life cycle greenhouse gas (GHG emissions from different hydroelectricity generation systems by first performing a comprehensive review of the hydroelectricity generation system life cycle assessment (LCA studies and then subsequent computation of statistical metrics to quantify the life cycle GHG emissions (expressed in grams of carbon dioxide equivalent per kilowatt hour, gCO2e/kWh. A categorization index (with unique category codes, formatted as “facility type-electric power generation capacity” was developed and used in this study to evaluate the life cycle GHG emissions from the reviewed hydroelectricity generation systems. The unique category codes were labeled by integrating the names of the two hydro power sub-classifications, i.e., the facility type (impoundment (I, diversion (D, pumped storage (PS, miscellaneous hydropower works (MHPW and the electric power generation capacity (micro (µ, small (S, large (L. The characterized hydroelectricity generation systems were statistically evaluated to determine the reduction in corresponding life cycle GHG emissions. A total of eight unique categorization codes (I-S, I-L, D-µ, D-S, D-L, PS-L, MHPW-µ, MHPW-S were designated to the 19 hydroelectricity generation LCA studies (representing 178 hydropower cases using the proposed categorization index. The mean life cycle GHG emissions resulting from the use of I-S (N = 24, I-L (N = 8, D-µ (N = 3, D-S (N = 133, D-L (N = 3, PS-L (N = 3, MHPW-µ (N = 3, and MHPW-S (N = 1 hydroelectricity generation systems are 21.05 gCO2e/kWh, 40.63 gCO2e/kWh, 47.82 gCO2e/kWh, 27.18 gCO2e/kWh, 3.45 gCO2e/kWh, 256.63 gCO2e/kWh, 19.73 gCO2e/kWh, and 2.78 gCO2e/kWh, respectively. D-L hydroelectricity generation systems produced the minimum life cycle GHGs (considering the hydroelectricity generation system categories with a representation of at least two cases.

  17. Apples with apples: accounting for fuel price risk in comparisons of gas-fired and renewable generation

    Energy Technology Data Exchange (ETDEWEB)

    Bolinger, Mark; Wiser, Ryan

    2003-12-18

    For better or worse, natural gas has become the fuel of choice for new power plants being built across the United States. According to the US Energy Information Administration (EIA), natural gas combined-cycle and combustion turbine power plants accounted for 96% of the total generating capacity added in the US between 1999 and 2002--138 GW out of a total of 144 GW. Looking ahead, the EIA expects that gas-fired technology will account for 61% of the 355 GW new generating capacity projected to come on-line in the US up to 2025, increasing the nationwide market share of gas-fired generation from 18% in 2002 to 22% in 2025. While the data are specific to the US, natural gas-fired generation is making similar advances in other countries as well. Regardless of the explanation for (or interpretation of) the empirical findings, however, the basic implications remain the same: one should not blindly rely on gas price forecasts when comparing fixed-price renewable with variable-price gas-fired generation contracts. If there is a cost to hedging, gas price forecasts do not capture and account for it. Alternatively, if the forecasts are at risk of being biased or out of tune with the market, then one certainly would not want to use them as the basis for resource comparisons or investment decisions if a more certain source of data (forwards) existed. Accordingly, assuming that long-term price stability is valued, the most appropriate way to compare the levelized cost of these resources in both cases would be to use forward natural gas price data--i.e. prices that can be locked in to create price certainty--as opposed to uncertain natural gas price forecasts. This article suggests that had utilities and analysts in the US done so over the sample period from November 2000 to November 2003, they would have found gas-fired generation to be at least 0.3-0.6 cents/kWh more expensive (on a levelized cost basis) than otherwise thought. With some renewable resources, in particular wind

  18. Monodisperse, submicrometer droplets via condensation of microfluidic-generated gas bubbles.

    Science.gov (United States)

    Seo, Minseok; Matsuura, Naomi

    2012-09-10

    Microfluidics (MFs) can produce monodisperse droplets with precise size control. However, the synthesis of monodisperse droplets much smaller than the minimum feature size of the microfluidic device (MFD) remains challenging, thus limiting the production of submicrometer droplets. To overcome the minimum micrometer-scale droplet sizes that can be generated using typical MFDs, the droplet material is heated above its boiling point (bp), and then MFs is used to produce monodisperse micrometer-scale bubbles (MBs) that are easily formed in the size regime where standard MFDs have excellent size control. After MBs are formed, they are cooled, condensing into dramatically smaller droplets that are beyond the size limit achievable using the original MFD, with a size decrease corresponding to the density difference between the gas and liquid phases of the droplet material. Herein, it is shown experimentally that monodisperse, submicrometer droplets of predictable sizes can be condensed from a monodisperse population of MBs as generated by MFs. Using perfluoropentane (PFP) as a representative solvent due to its low bp (29.2 °C), it is demonstrated that monodisperse PFP MBs can be produced at MFD temperatures >3.6 °C above the bp of PFP over a wide range of sizes (i.e., diameters from 2 to 200 μm). Independent of initial size, the generated MBs shrink rapidly in size from about 3 to 0 °C above the bp of PFP, corresponding to a phase change from gas to liquid, after which they shrink more slowly to form fully condensed droplets with diameters 5.0 ± 0.1 times smaller than the initial size of the MBs, even in the submicrometer size regime. This new method is versatile and flexible, and may be applied to any type of low-bp solvent for the manufacture of different submicrometer droplets for which precisely controlled dimensions are required.

  19. Design and Operation of the Synthesis Gas Generator System for Reformed Propane and Glycerin Combustion

    Science.gov (United States)

    Pickett, Derek Kyle

    Due to an increased interest in sustainable energy, biodiesel has become much more widely used in the last several years. Glycerin, one major waste component in biodiesel production, can be converted into a hydrogen rich synthesis gas to be used in an engine generator to recover energy from the biodiesel production process. This thesis contains information detailing the production, testing, and analysis of a unique synthesis generator rig at the University of Kansas. Chapter 2 gives a complete background of all major components, as well as how they are operated. In addition to component descriptions, methods for operating the system on pure propane, reformed propane, reformed glycerin along with the methodology of data acquisition is described. This chapter will serve as a complete operating manual for future students to continue research on the project. Chapter 3 details the literature review that was completed to better understand fuel reforming of propane and glycerin. This chapter also describes the numerical model produced to estimate the species produced during reformation activities. The model was applied to propane reformation in a proof of concept and calibration test before moving to glycerin reformation and its subsequent combustion. Chapter 4 first describes the efforts to apply the numerical model to glycerin using the calibration tools from propane reformation. It then discusses catalytic material preparation and glycerin reformation tests. Gas chromatography analysis of the reformer effluent was completed to compare to theoretical values from the numerical model. Finally, combustion of reformed glycerin was completed for power generation. Tests were completed to compare emissions from syngas combustion and propane combustion.

  20. Molecular dynamics simulations of flame propagation along a monopropellant PETN coupled with multi-walled carbon nanotubes

    Science.gov (United States)

    Jain, S.; Mo, G.; Qiao, L.

    2017-02-01

    Reactive molecular dynamics simulations were conducted to study the flame speed enhancement phenomenon of a solid mono-propellant, Pentaerythritol Tetranitrate (PETN), when coupled to highly conductive multi-walled carbon nanotubes (MWCNTs). The simulations were based on the first-principles derived reactive force field, ReaxFF, which includes both the physical changes such as thermal transport and the chemical changes such as bond breaking and forming. An annular deposition of a PETN layer around the MWCNTs was considered. The thickness of the PETN layer and the diameter of the MWCNT were varied to understand the effect of the MWCNT loading ratio on the flame propagation. Flame speed enhancements up to 3 times the bulk value were observed. An optimal MWCNT loading ratio was determined. The enhancement was attributed to the layering of the PETN molecules around the MWCNT, which increased the heat transport among the PETN molecules near the MWCNT surface, thus causing the flame to travel faster. Furthermore, a stronger ignition source was required for the MWCNT-PETN complex because of the higher thermal transport among the PETN molecules along the MWCNT, which makes the ignition energy dissipate more quickly. Lastly, the MWCNT remained unburned during the PETN combustion process.

  1. Determination of Fuel Consumption Indexes of Co-generation Combined Cycle Steam and Gas Units with unfired waste heat boilers

    Directory of Open Access Journals (Sweden)

    S. A. Kachan

    2010-01-01

    Full Text Available The paper presents the developed methodology and the results of determination of fuel consumption indexes of co-generation combined cycle steam and gas units (PGU with unfired waste heat boilers apply to PGU-230 of 3-d co-generation power plant ofMinsk. 

  2. Radiological impact of NORM generated by oil and gas industries in the kingdom of Bahrain.

    Science.gov (United States)

    Husain, Husain; Sakhnini, Lama

    2017-02-01

    A study of the external background radiation in areas affected by NORM generated by oil and gas industrial activities has been performed in the Kingdom of Bahrain. In this framework, two experimental residential areas, Awali and Riffa Views, were selected due to the presence of extensive oil and gas exploration and transportation. Additionally, two control residential areas, Isa Town and Al-Budaiya Village, were selected as they lack any industrial activities that would disrupt the radiation profile. The radiation dose rates were measured using Colibri Very Low Dose radiation survey meter with a built-in GPS. A total of 317 dose rates with their GPS coordinates were acquired. The lowest dose rate was 0.02 μSv/h acquired in Isa Town while the highest dose rate was 0.37 μSv/h acquired in Awali. Since there were no studies performed in the Kingdom to measure the average background radiation, the average external background radiation calculated from the control areas was used in this study which is 0.75 ± 0.31 mSv/y. The measured mean annual equivalent doses above the background radiation levels in Isa Town, Al-Budaiya, Riffa Views and Awali were -0.05 ± 0.05 mSv/y, 0.04 ± 0.04 mSv/y, 0.62 ± 0.13 mSv/y and 1.32 ± 0.35 mSv/y respectively. In other words, the radiation measurements were notably higher in the experimental areas. This was particularly true in south and southwestern Awali where the annual equivalent dose in some areas reached 2.49 mSv/y above average background levels. The geological constituent of the earth crust could be one source that contribute to overall background radiation. However, presence of NORM generated by extensive oil and gas operations and transportation is stronger justification for the higher radiation readings in the experimental areas than geological characteristic factor. Such high radiation values were found only near oil and gas installations and not in other locations of the same areas.

  3. Modified landfill gas generation rate model of first-order kinetics and two-stage reaction

    Institute of Scientific and Technical Information of China (English)

    Jiajun CHEN; Hao WANG; Na ZHANG

    2009-01-01

    This investigation was carried out to establish a new domestic landfill gas (LFG) generation rate model that takes into account the impact ofleachate recirculation. The first-order kinetics and two-stage reaction (FKTSR) model of the LFG generation rate includes mechanisms of the nutrient balance for biochemical reaction in two main stages. In this study, the FKTSR model was modified by the introduction of the outflow function and the organic acid conversion coefficient in order to represent the in-situ condition of nutrient loss through leachate. Laboratory experiments were carried out to simulate the impact of leachate recirculation and verify the modified FKTSR model. The model calibration was then calculated by using the experimental data. The results suggested that the new model was in line with the experimental data. The main parameters of the modified FKTSR model, including the LFG production potential (L0), the reaction rate constant in the first stage (K1), and the reaction rate constant in the second stage (K2) of 64.746 L, 0.202 d-1, and 0.338 d-1,respectively, were comparable to the old ones of 42.069 L,0.231 d-1, and 0.231 d-1. The new model is better able to explain the mechanisms involved in LFG generation.

  4. Synthesis and performance of bismuth trioxide nanoparticles for high energy gas generator use.

    Science.gov (United States)

    Martirosyan, K S; Wang, L; Vicent, A; Luss, D

    2009-10-01

    Our experiments showed that the combustion of an Al-Bi2O3 nanoparticle mixture generated the highest pressure pulse among common nanothermite reactions and can potentially be used as a nanoenergetic gas generator. The combustion front propagation velocity and rate of energy release increased by up to three orders of magnitude when the particle size was reduced to a nanosize range for both the aluminum and the oxidizer. We developed a novel one-step (metal nitrate-glycine) combustion synthesis of nanostructured amorphous-like and highly crystalline bismuth trioxide nanoparticles. The combustion synthesis was conducted using a solution of molten bismuth nitrate as an oxidizer and glycine as a fuel. The glycine was completely combusted during the thermal decomposition of the bismuth nitrate pentahydrate and generated a temperature front that propagated through the sample. Increasing the fuel concentration increased the maximum combustion temperature from 280 to 1200 degrees C and the Bi2O3 particle size from 20 to 100 nm. The oxidizer/fuel ratio had a strong impact on the bismuth trioxide particle crystallinity. At low temperature (280 degrees C), amorphous-like bismuth trioxide nanoparticles formed, while at T > or =370 degrees C the structures were crystalline. A peak pressure of approximately 12 MPa and a thermal front propagating velocity of approximately 2500 m s(-1) were achieved during the combustion of an Al-Bi2O3 mixture containing 80 wt% of the synthesized Bi2O3 crystalline nanoparticles (size: 40-50 nm).

  5. Penetrating Gas Streams Generate Unrelaxed,Non-Cool-Core Clusters of Galaxies

    CERN Document Server

    Zinger, E; Birnboim, Y; Kravtsov, A; Nagai, D

    2015-01-01

    We utilize cosmological simulations of 16 galaxy clusters at redshifts $z=0$ and $z=0.6$ to study the effect of inflowing streams on the properties of the inner Intra-Cluster Medium (ICM). We find that the mass accretion occurs predominantly along streams that originate from the cosmic web and consist of heated gas. Clusters that are unrelaxed in terms of their X-ray morphology are characterized by higher mass inflow rates and deeper penetration of the streams, typically into the inner third of the virial radius. The penetrating streams generate elevated random motions, bulk flows, cold fronts and metal mixing, thus producing Non-Cool-Core clusters. The degree of penetration of the streams may change over time such that clusters can switch from being unrelaxed to relaxed over a time-scale of several Gyrs. The stream properties thus help us understand the distinction between cool-core and non-cool-core clusters.

  6. Gas-Phase Generation and Decomposition of a Sulfinylnitrene into the Iminyl Radical OSN.

    Science.gov (United States)

    Wu, Zhuang; Li, Dingqing; Li, Hongmin; Zhu, Bifeng; Sun, Hailong; Francisco, Joseph S; Zeng, Xiaoqing

    2016-01-22

    The dipolar oxathiazyne-like sulfinylnitrene RS(O)N, a highly reactive α-oxo nitrene, has been rarely investigated. Upon flash vacuum pyrolysis of sulfinyl azide CF3S(O)N3 at 350 °C, an elusive sulfinylnitrene CF3S(O)N was generated in the gas phase in its singlet ground state and was characterized by matrix-isolation IR spectroscopy. Further fragmentation of CF3S(O)N at 600 °C produced CF3 and a novel iminyl radical OSN, an SO2 analogue, which were unambiguously identified by IR spectroscopy. Consistent with the experimental observations, DFT calculations clearly support a stepwise decomposition mechanism of CF3S(O)N3. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Low NO{sub x} turbine power generation utilizing low Btu GOB gas. Final report, June--August 1995

    Energy Technology Data Exchange (ETDEWEB)

    Ortiz, I.; Anthony, R.V.; Gabrielson, J.; Glickert, R.

    1995-08-01

    Methane, a potent greenhouse gas, is second only to carbon dioxide as a contributor to potential global warming. Methane liberated by coal mines represents one of the most promising under exploited areas for profitably reducing these methane emissions. Furthermore, there is a need for apparatus and processes that reduce the nitrogen oxide (NO{sub x}) emissions from gas turbines in power generation. Consequently, this project aims to demonstrate a technology which utilizes low grade fuel (CMM) in a combustion air stream to reduce NO{sub x} emissions in the operation of a gas turbine. This technology is superior to other existing technologies because it can directly use the varying methane content gases from various streams of the mining operation. The simplicity of the process makes it useful for both new gas turbines and retrofitting existing gas turbines. This report evaluates the feasibility of using gob gas from the 11,000 acre abandoned Gateway Mine near Waynesburg, Pennsylvania as a fuel source for power generation applying low NO{sub x} gas turbine technology at a site which is currently capable of producing low grade GOB gas ({approx_equal} 600 BTU) from abandoned GOB areas.

  8. Spalax™ new generation: A sensitive and selective noble gas system for nuclear explosion monitoring.

    Science.gov (United States)

    Le Petit, G; Cagniant, A; Gross, P; Douysset, G; Topin, S; Fontaine, J P; Taffary, T; Moulin, C

    2015-09-01

    In the context of the verification regime of the Comprehensive nuclear Test ban Treaty (CTBT), CEA is developing a new generation (NG) of SPALAX™ system for atmospheric radioxenon monitoring. These systems are able to extract more than 6cm(3) of pure xenon from air samples each 12h and to measure the four relevant xenon radioactive isotopes using a high resolution detection system operating in electron-photon coincidence mode. This paper presents the performances of the SPALAX™ NG prototype in operation at Bruyères-le-Châtel CEA centre, integrating the most recent CEA developments. It especially focuses on an innovative detection system made up of a gas cell equipped with two face-to-face silicon detectors associated to one or two germanium detectors. Minimum Detectable activity Concentrations (MDCs) of environmental samples were calculated to be approximately 0.1 mBq/m(3) for the isotopes (131m)Xe, (133m)Xe, (133)Xe and 0.4 mBq/m(3) for (135)Xe (single germanium configuration). The detection system might be used to simultaneously measure particulate and noble gas samples from the CTBT International Monitoring System (IMS). That possibility could lead to new capacities for particulate measurements by allowing electron-photon coincidence detection of certain fission products.

  9. The Case for Natural Gas Fueled Solid Oxide Fuel Cell Power Systems for Distributed Generation

    Energy Technology Data Exchange (ETDEWEB)

    Chick, Lawrence A.; Weimar, Mark R.; Whyatt, Greg A.; Powell, Michael R.

    2015-02-01

    Natural-gas-fueled solid oxide fuel cell (NGSOFC) power systems yield electrical conversion efficiencies exceeding 60% and may become a viable alternative for distributed generation (DG) if stack life and manufacturing economies of scale can be realized. Currently, stacks last approximately 2 years and few systems are produced each year because of the relatively high cost of electricity from the systems. If mass manufacturing (10,000 units per year) and a stack life of 15 years can be reached, the cost of electricity from an NGSOFC system is estimated to be about 7.7 ¢/kWh, well within the price of commercial and residential retail prices at the national level (9.9-10¢/kWh and 11-12 ¢/kWh, respectively). With an additional 5 ¢/kWh in estimated additional benefits from DG, NGSOFC could be well positioned to replace the forecasted 59-77 gigawatts of capacity loss resulting from coal plant closures due to stricter emissions regulations and low natural gas prices.

  10. Power generation using coir-pith and wood derived producer gas in diesel engines

    Energy Technology Data Exchange (ETDEWEB)

    Ramadhas, A.S.; Jayaraj, S.; Muraleedharan, C. [Department of Mechanical Engineering, National Institute of Technology Calicut, Calicut-673 601, Kerala State (India)

    2006-10-15

    Partial combustion of biomass in the gasifier generates producer gas that can be used for heating purposes and as supplementary or sole fuel in internal combustion engines. In this study, the potential of coir-pith and wood chips as the feedstock for gasifier is analyzed. The performance of the gasifier-engine system is analyzed by running the engine for various producer gas-air flow ratios and at different load conditions. The system is experimentally optimized with respect to maximum diesel savings and lower emissions in the dual fuel mode operation while using coir-pith and wood chips separately. The performance and emission characteristics of the dual fuel engine are compared with that of diesel engine at different load conditions. Specific energy consumption in the dual fuel mode of operation is found to be in the higher side at all load conditions. The brake thermal efficiency of the engine while using wood chips in the dual mode operation is higher than that of coir-pith. The CO emission is higher in the case of dual fuel mode of operation as compared to that of diesel mode. In the dual fuel mode of operation, the higher diesel savings is achieved while using wood chips as compared to that of coir-pith. The comparison of the performance and emission characteristics of the dual fuel engine with diesel engine is also described. (author)

  11. Development and application of an analysis methodology for interpreting ambiguous historical pressure data in the WIPP gas-generation experiments.

    Energy Technology Data Exchange (ETDEWEB)

    Felicione, F. S.

    2006-01-23

    The potential for generation of gases in transuranic (TRU) waste by microbial activity, chemical interactions, corrosion, and radiolysis was addressed in the Argonne National Laboratory-West (ANL-West) Gas-Generation Experiments (GGE). Data was collected over several years by simulating the conditions in the Waste Isolation Pilot Plant (WIPP) after the eventual intrusion of brine into the repository. Fourteen test containers with various actual TRU waste immersed in representative brine were inoculated with WIPP-relevant microbes, pressurized with inert gases, and kept in an inert-atmosphere environment for several years to provide estimates of the gas-generation rates that will be used in computer models for future WIPP Performance Assessments. Modest temperature variations occurred during the long-term ANL-West experiments. Although the experiment temperatures always remained well within the experiment specifications, the small temperature variation was observed to affect the test container pressure far more than had been anticipated. In fact, the pressure variations were so large, and seemingly erratic, that it was impossible to discern whether the data was even valid and whether the long-term pressure trend was increasing, decreasing, or constant. The result was that no useful estimates of gas-generation rates could be deduced from the pressure data. Several initial attempts were made to quantify the pressure fluctuations by relating these to the measured temperature variation, but none was successful. The work reported here carefully analyzed the pressure measurements to determine if these were valid or erroneous data. It was found that a thorough consideration of the physical phenomena that were occurring can, in conjunction with suitable gas laws, account quite accurately for the pressure changes that were observed. Failure of the earlier attempts to validate the data was traced to the omission of several phenomena, the most important being the variation in

  12. Committing to coal and gas: Long-term contracts, regulation, and fuel switching in power generation

    Science.gov (United States)

    Rice, Michael

    Fuel switching in the electricity sector has important economic and environmental consequences. In the United States, the increased supply of gas during the last decade has led to substantial switching in the short term. Fuel switching is constrained, however, by the existing infrastructure. The power generation infrastructure, in turn, represents commitments to specific sources of energy over the long term. This dissertation explores fuel contracts as the link between short-term price response and long-term plant investments. Contracting choices enable power plant investments that are relationship-specific, often regulated, and face uncertainty. Many power plants are subject to both hold-up in investment and cost-of-service regulation. I find that capital bias is robust when considering either irreversibility or hold-up due to the uncertain arrival of an outside option. For sunk capital, the rental rate is inappropriate for determining capital bias. Instead, capital bias depends on the regulated rate of return, discount rate, and depreciation schedule. If policies such as emissions regulations increase fuel-switching flexibility, this can lead to capital bias. Cost-of-service regulation can shorten the duration of a long-term contract. From the firm's perspective, the existing literature provides limited guidance when bargaining and writing contracts for fuel procurement. I develop a stochastic programming framework to optimize long-term contracting decisions under both endogenous and exogenous sources of hold-up risk. These typically include policy changes, price shocks, availability of fuel, and volatility in derived demand. For price risks, the optimal contract duration is the moment when the expected benefits of the contract are just outweighed by the expected opportunity costs of remaining in the contract. I prove that imposing early renegotiation costs decreases contract duration. Finally, I provide an empirical approach to show how coal contracts can limit

  13. Determination of leveled costs of electric generation for gas plants, coal and nuclear; Determinacion de costos nivelados de generacion electrica para plantas de gas, carbon y nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Alonso V, G.; Palacios H, J.C.; Ramirez S, J.R.; Gomez, A. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)]. e-mail: galonso@nuclear.inin.mx

    2005-07-01

    The present work analyzes the leveled costs of electric generation for different types of nuclear reactors known as Generation III, these costs are compared with the leveled costs of electric generation of plants with the help of natural gas and coal. In the study several discount rates were used to determine their impact in the initial investment. The obtained results are comparable with similar studies and they show that it has more than enough the base of the leveled cost the nuclear option it is quite competitive in Mexico. Also in this study it is also thinks about the economic viability of a new nuclear power station in Mexico. (Author)

  14. Evaluation of gas turbine and gasifier-based power generation system

    Science.gov (United States)

    Zhu, Yunhua

    As a technology in early commercial phase, research work is needed to provide evaluation of the effects of alternative designs and technology advances and provide guidelines for development direction of Integrated Gasification Combined Cycle (IGCC) technology in future. The objective of this study is to evaluate the potential pay-offs as well as risks of technological infeasibility for IGCC systems and to provide insight regarding desired strategies for the future development of advanced IGCC systems. Texaco gasifier process is widely used in power generation. A process simulation model for a base Texaco gasifier-based IGCC system, including performance (e.g., efficiency), emissions, and cost, was implemented in the ASPEN Plus. The model is calibrated and verified based on other design studies. To find out the implications of the effects of coal compositions on IGCC plant, the Illinois No.6, Pittsburgh No.8, and West Kentucky coal are selected for comparison. The results indicate that the ash content and sulfur content of coal have effects on performance, SO2 emissions, and capital cost of IGCC system. As the main component for power generation, the effects of the most advanced Frame 7H and the current widely used Frame 7F gas turbine combined cycles on IGCC system were evaluated. The results demonstrated the IGCC system based on 7H gas turbine (IGCC-7H) has higher efficiency, lower CO2 emission, and lower cost of electricity than the 7FA based system (IGCC-7FA). A simplified spreadsheet model is developed for estimating mass and energy balance of gas turbine combined cycle. It demonstrated that an accurate and sensitive model can be implemented in a spreadsheet. This study implicated the ability to do desktop simulations to support policy analysis. Uncertainty analysis is implemented to find out the risks associated with the IGCC systems, i.e., there is about 80% probability that the uncertain results of the efficiency of IGCC-7FA system are lower than the

  15. Cost and greenhouse gas emission tradeoffs of alternative uses of lignin for second generation ethanol

    Science.gov (United States)

    Pourhashem, Ghasideh; Adler, Paul R.; McAloon, Andrew J.; Spatari, Sabrina

    2013-06-01

    Second generation ethanol bioconversion technologies are under demonstration-scale development for the production of lignocellulosic fuels to meet the US federal Renewable Fuel Standards (RFS2). Bioconversion technology utilizes the fermentable sugars generated from the cellulosic fraction of the feedstock, and most commonly assumes that the lignin fraction may be used as a source of thermal and electrical energy. We examine the life cycle greenhouse gas (GHG) emission and techno-economic cost tradeoffs for alternative uses of the lignin fraction of agricultural residues (corn stover, and wheat and barley straw) produced within a 2000 dry metric ton per day ethanol biorefinery in three locations in the United States. We compare three scenarios in which the lignin is (1) used as a land amendment to replace soil organic carbon (SOC); (2) separated, dried and sold as a coal substitute to produce electricity; and (3) used to produce electricity onsite at the biorefinery. Results from this analysis indicate that for life cycle GHG intensity, amending the lignin to land is lowest among the three ethanol production options (-25 to -2 g CO2e MJ-1), substituting coal with lignin is second lowest (4-32 g CO2e MJ-1), and onsite power generation is highest (36-41 g CO2e MJ-1). Moreover, the onsite power generation case may not meet RFS2 cellulosic fuel requirements given the uncertainty in electricity substitution. Options that use lignin for energy do so at the expense of SOC loss. The lignin-land amendment option has the lowest capital cost among the three options due to lower equipment costs for the biorefinery’s thermal energy needs and use of biogas generated onsite. The need to purchase electricity and uncertain market value of the lignin-land amendment could raise its cost compared to onsite power generation and electricity co-production. However, assuming a market value (50-100/dry Mg) for nutrient and soil carbon replacement in agricultural soils, and potentially

  16. Oil and gas generation potential of different age sediments of the transcarpathian depression according to TOC content

    Directory of Open Access Journals (Sweden)

    Андрій Андрійович Локтєв

    2014-10-01

    Full Text Available Evolution of views on genesis of natural gases in the depths of Transcarpathian depression is given in the article. Besides another aspect that is mentioned is definition of potential source rocks of oil and gas within the depression by the analysis of the cores on TOC amount and oil and gas generation potential of Miocene thicknesses of sediments as well as preneogene basement

  17. Generation of Attosecond Light Pulses from Gas and Solid State Media

    Directory of Open Access Journals (Sweden)

    Stefanos Chatziathanasiou

    2017-03-01

    Full Text Available Real-time observation of ultrafast dynamics in the microcosm is a fundamental approach for understanding the internal evolution of physical, chemical and biological systems. Tools for tracing such dynamics are flashes of light with duration comparable to or shorter than the characteristic evolution times of the system under investigation. While femtosecond (fs pulses are successfully used to investigate vibrational dynamics in molecular systems, real time observation of electron motion in all states of matter requires temporal resolution in the attosecond (1 attosecond (asec = 10−18 s time scale. During the last decades, continuous efforts in ultra-short pulse engineering led to the development of table-top sources which can produce asec pulses. These pulses have been synthesized by using broadband coherent radiation in the extreme ultraviolet (XUV spectral region generated by the interaction of matter with intense fs pulses. Here, we will review asec pulses generated by the interaction of gas phase media and solid surfaces with intense fs IR laser fields. After a brief overview of the fundamental process underlying the XUV emission form these media, we will review the current technology, specifications and the ongoing developments of such asec sources.

  18. Generation Performance of a Fuel Cell Using Hydrogen and Di-methyl-ether (DME) Mixed Gas

    Science.gov (United States)

    Haraguchi, Tadao; Watanabe, Takashi; Yamashita, Masahiro; Tsutsumi, Yasuyuki; Yamashita, Susumu

    Di-methyl-ether (DME), an oxygenated hydrocarbon, can facilitate hydrogen manufacture by steam reforming reaction at low temperature. Methanol and DME steam reforming at 250-300°C, reforming DME into hydrogen, can be performed easily with small-scale and simple equipment. Whether the hydrogen output from the reformer for supply to the fuel cell includes DME, and how this affects the generation performance has yet to be confirmed. The purpose of this paper is to investigate the supply of a fuel cell with mixtures of DME and H2 in varying proportions and to clarify the effect on generation performance. Conclusions are as follows: (1) For a supply of DME and H2 mixed gas, DME is consumed after the H2 is consumed. By comparing the experimental values with theoretical values of consumption of pure H2, a mixture of DME and H2, and pure DME, it proved to be possible to roughly predict the experimental values by calculation. (2) The voltage value moved to near the DME voltage after the H2 was consumed, the current density increased after the H2 was consumed. (3) During continuous running the voltage load was observed to fluctuate.

  19. Generating and Synthesizing Information about Risks in Unconventional Oil and Gas Development

    Science.gov (United States)

    Wiseman, H.

    2013-12-01

    site construction and disclosure of all chemicals used at the well site. Governments should also consider requiring air emissions (including methane) monitoring near well sites. Regardless of who conducts monitoring and testing, states and the federal government should agree on the parameters that would be tested for in all water and air quality samples, and they should require reporting in the same units to allow for cross-state comparison. Finally, we must synthesize data produced by industry or states and organize and summarize it in a manner that is understandable to scientists and non-scientists alike. The risks of unconventional oil and gas development are perhaps most easily understood when organized by the stage of well development, and for each stage, specific risks could be identified. The federal government is, once again, the most likely candidate to produce and synthesize this information. Although nonprofit groups, industry actors, and state government could also aid in this task, certain stakeholders might question whether these entities' motives influenced data summaries. Generating and synthesizing information about the technologies and risks involved in unconventional oil and gas development will not be easy, or cheap. But it will be important if we are to sail forward rapidly through waters that no other country has charted.

  20. Characterization of multi-jet gas puff targets for high-order harmonic generation using EUV shadowgraphy

    Energy Technology Data Exchange (ETDEWEB)

    Wachulak, P.W., E-mail: wachulak@gmail.com [Institute of Optoelectronics, Military University of Technology, ul. Gen. S. Kaliskiego 2, 00-908 Warsaw (Poland); Bartnik, A.; Jarocki, R.; Fiedorowicz, H. [Institute of Optoelectronics, Military University of Technology, ul. Gen. S. Kaliskiego 2, 00-908 Warsaw (Poland)

    2012-08-15

    Characterization measurements of multi-jet gas puff targets, developed for investigations on high-order harmonic generation (HHG) by a focused laser beam in a gas medium of modulated density, are presented. The targets produced by pulsed injection of gas through a nozzle in a form of a chain of small orifices have been characterized by EUV backlighting at 13.5 nm wavelength. Measurements were performed for nozzles with 5, 7 and 9 orifices of 0.5 mm in diameter each. Density profiles for argon targets have been obtained for the first time.

  1. Reductions in greenhouse gas (GHG) generation and energy consumption in wastewater treatment plants.

    Science.gov (United States)

    Yerushalmi, L; Ashrafi, O; Haghighat, F

    2013-01-01

    Greenhouse gas (GHG) emission and energy consumption by on-site and off-site sources were estimated in two different wastewater treatment plants that used physical-chemical or biological processes for the removal of contaminants, and an anaerobic digester for sludge treatment. Physical-chemical treatment processes were used in the treatment plant of a locomotive repair factory that processed wastewater at 842 kg chemical oxygen demand per day. Approximately 80% of the total GHG emission was related to fossil fuel consumption for energy production. The emission of GHG was reduced by 14.5% with the recovery of biogas that was generated in the anaerobic digester and its further use as an energy source, replacing fossil fuels. The examined biological treatment system used three alternative process designs for the treatment of effluents from pulp and paper mills that processed wastewater at 2,000 kg biochemical oxygen demand per day. The three designs used aerobic, anaerobic, or hybrid aerobic/anaerobic biological processes for the removal of carbonaceous contaminants, and nitrification/denitrification processes for nitrogen removal. Without the recovery and use of biogas, the aerobic, anaerobic, and hybrid treatment systems generated 3,346, 6,554 and 7,056 kg CO(2)-equivalent/day, respectively, while the generated GHG was reduced to 3,152, 6,051, and 6,541 kg CO(2)-equivalent/day with biogas recovery. The recovery and use of biogas was shown to satisfy and exceed the energy needs of the three examined treatment plants. The reduction of operating temperature of the anaerobic digester and anaerobic reactor by 10°C reduced energy demands of the treatment plants by 35.1, 70.6 and 62.9% in the three examined treatment systems, respectively.

  2. Experimental study of jet gas-particle interaction generated during explosive volcanic eruptions

    Science.gov (United States)

    Medici, E. F.; Waite, G. P.

    2014-12-01

    During violent volcanic eruptions, a shock wave may be generated that is immediately followed by the formation of a supersonic jet. The overpressurized vapor-solid-liquid mixture being ejected begins to expand and accelerate. Oblique shock waves and rarefaction waves are generated at the edge of the crater. The oblique shock waves, inclined relatively to the flow axis, intersect forming a structure called a "Mach disk" or "Mach diamond". This pattern repeats until the jet decelerates into subsonic flow. In an explosive volcanic eruption, unlike other applications involving jets, a mixture of hot gas and solid particles is present. The mixture typically contains a relatively high percentage of solid particles of different sizes. The relationship between jet and particle is one the major parameters affecting the formation of ash plume dynamics and the pyroclastic flows. Therefore, a more comprehensive study is needed in order to understand the mixing occurring within the volcanic eruption jet, specifically, the effect of particle size and concentration. In this work, a series of analog explosive volcanic experiments using an atmospheric shock tube are performed to generate supersonic jets. High-speed video imaging of the expanding jet as well as the pressure evolution at different points in space are recorded for different values of initial energy and particle sizes and concentrations. Particles of different sizes and in various concentrations are placed inside the jet stream in which all the environmental conditions are monitored. Understanding of the coupling between the particles and the jet dynamics interaction is the first step toward a more thorough understanding of ash plume dynamics and the pyroclastic flows formation.

  3. Characterization of Tungsten Inert Gas (TIG) Welding Fume Generated by Apprentice Welders.

    Science.gov (United States)

    Graczyk, Halshka; Lewinski, Nastassja; Zhao, Jiayuan; Concha-Lozano, Nicolas; Riediker, Michael

    2016-03-01

    Tungsten inert gas welding (TIG) represents one of the most widely used metal joining processes in industry. Its propensity to generate a greater portion of welding fume particles at the nanoscale poses a potential occupational health hazard for workers. However, current literature lacks comprehensive characterization of TIG welding fume particles. Even less is known about welding fumes generated by welding apprentices with little experience in welding. We characterized TIG welding fume generated by apprentice welders (N = 20) in a ventilated exposure cabin. Exposure assessment was conducted for each apprentice welder at the breathing zone (BZ) inside of the welding helmet and at a near-field (NF) location, 60cm away from the welding task. We characterized particulate matter (PM4), particle number concentration and particle size, particle morphology, chemical composition, reactive oxygen species (ROS) production potential, and gaseous components. The mean particle number concentration at the BZ was 1.69E+06 particles cm(-3), with a mean geometric mean diameter of 45nm. On average across all subjects, 92% of the particle counts at the BZ were below 100nm. We observed elevated concentrations of tungsten, which was most likely due to electrode consumption. Mean ROS production potential of TIG welding fumes at the BZ exceeded average concentrations previously found in traffic-polluted air. Furthermore, ROS production potential was significantly higher for apprentices that burned their metal during their welding task. We recommend that future exposure assessments take into consideration welding performance as a potential exposure modifier for apprentice welders or welders with minimal training.

  4. An Integrated microfluidic platform for liquid droplet in gas flow generation with in liquid flow collection and manipulation

    Science.gov (United States)

    Tirandazi, Pooyan; Hidrovo, Carlos H.

    2016-11-01

    Discretization of biological samples and chemical reactions within digital droplets is a powerful technique which has rapidly emerged in many biochemical syntheses. The ability to generate, manipulate, and monitor millions of microdroplets in a short time provides great potential for high throughput screening and detection in microbiology. Here we report a microfluidic device for the formation of uniform microdroplets (50 μm-100 μm) using a high speed gas as the continuous phase. Gas-borne droplets are generated in a chip-based flow-focusing device fabricated in PDMS, and travel along the gaseous microchannel and are subsequently captured within a second liquid phase. The droplets are then transferred and collected in a minichamber and move into the manipulation section for further processing operations on the drops. All these steps are performed automatically in a single multilayer chip. This integrated microfluidic platform for generation, collection, and manipulation of the droplets provides great opportunities for monitoring and detection of gas-analytes. Utilizing the generated picoliter airborne droplets feature lower reaction times and higher transfer rates as compared to conventional air sampling techniques. Thus, it can greatly facilitate the investigation of airborne analytes by interrogation of the digital droplets using different analytical techniques. Furthermore, the presented liquid-in-gas generation method can be utilized for production of oil-free microparticles and microcapsules used in the food industry and for drug delivery.

  5. Microbial gas generation under expected Waste Isolation Pilot Plant repository conditions

    Energy Technology Data Exchange (ETDEWEB)

    Francis, A.J.; Gillow, J.B.; Giles, M.R. [Brookhaven National Lab., Upton, NY (United States). Dept. of Applied Science

    1997-03-01

    Gas generation from the microbial degradation of the organic constituents of transuranic waste under conditions expected at the Waste Isolation Pilot Plant (WIPP) repository was investigated at Brookhaven National Laboratory. The biodegradation of mixed cellulosics (various types of paper) and electron-beam irradiated plastic and rubber materials (polyethylene, polyvinylchloride, neoprene, hypalon, and leaded hypalon) was examined. The rate of gas production from cellulose biodegradation in inundated samples incubated for 1,228 days at 30 C was biphasic, with an initial rapid rate up to approximately 600 days incubation, followed by a slower rate. The rate of total gas production in anaerobic samples containing mixed inoculum was as follows: 0.002 mL/g cellulose/day without nutrients; 0.004 mL/g cellulose/day with nutrients; and 0.01 mL/g cellulose/day in the presence of excess nitrate. Carbon dioxide production proceeded at a rate of 0.009 {micro}mol/g cellulose/day in anaerobic samples without nutrients, 0.05 {micro}mol/g cellulose/day in the presence of nutrients, and 0.2 {micro}mol/g cellulose/day with excess nitrate. Adding nutrients and excess nitrate stimulated denitrification, as evidenced by the accumulation of N{sub 2}O in the headspace (200 {micro}mol/g cellulose). The addition of the potential backfill bentonite increased the rate of CO{sub 2} production to 0.3 {micro}mol/g cellulose/day in anaerobic samples with excess nitrate. Analysis of the solution showed that lactic, acetic, propionic, butyric, and valeric acids were produced due to cellulose degradation. Samples incubated under anaerobic humid conditions for 415 days produced CO{sub 2} at a rate of 0.2 {micro}mol/g cellulose/day in the absence of nutrients, and 1 {micro}mol/g cellulose/day in the presence of bentonite and nutrients. There was no evidence of biodegradation of electron-beam irradiated plastic and rubber.

  6. Gas, power and heat generation from biomass by allothermal gasification; Gas-, Strom- und Waermeerzeugung aus Biomasse durch allotherme Vergasung

    Energy Technology Data Exchange (ETDEWEB)

    Yaqub Chughtai, M. [H und C Engineering GmbH, Gummersbach (Germany); Muehlen, H.J. [DMT-Gesellschaft fuer Forschung und Pruefung mbH, Essen (Germany)

    1998-09-01

    The allothermal DMT gasification process for biomass is a newcomer. The process, its initial materials, the uses of the product gas, and advantages of the allothermal process are described here. (orig./SR) [Deutsch] Der Einsatz des allothermen DMT-Vergasungsverfahrens fuer Biomasse ist neu. Verfahren, Einsatzstoffe und Produktgasnutzung, sowie Vorteile des allothermen Verfahrens werden hier beschrieben. (orig./SR)

  7. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    Energy Technology Data Exchange (ETDEWEB)

    Stadler, Michael; Marnay, Chris; Cardoso, Goncalo; Megel, Olivier; Siddiqui, Afzal; Lai, Judy

    2009-08-15

    Lawrence Berkeley National Laboratory (LBL) is working with the California Energy Commission (CEC) to determine the role of distributed generation (DG) in greenhouse gas reductions. The impact of DG on large industrial sites is well known, and mostly, the potentials are already harvested. In contrast, little is known about the impact of DG on commercial buildings with peak electric loads ranging from 100 kW to 5 MW. We examine how DG with combined heat and power (CHP) may be implemented within the context of a cost minimizing microgrid that is able to adopt and operate various smart energy technologies, such as thermal and photovoltaic (PV) on-site generation, heat exchangers, solar thermal collectors, absorption chillers, and storage systems. We use a mixed-integer linear program (MILP) that has the minimization of a site's annual energy costs as objective. Using 138 representative commercial sites in California (CA) with existing tariff rates and technology data, we find the greenhouse gas reduction potential for California's commercial sector. This paper shows results from the ongoing research project and finished work from a two year U.S. Department of Energy research project. To show the impact of the different technologies on CO2 emissions, several sensitivity runs for different climate zones within CA with different technology performance expectations for 2020 were performed. The considered sites can contribute between 1 Mt/a and 1.8 Mt/a to the California Air Resources Board (CARB) goal of 6.7Mt/a CO2 abatement potential in 2020. Also, with lower PV and storage costs as well as consideration of a CO2 pricing scheme, our results indicate that PV and electric storage adoption can compete rather than supplement each other when the tariff structure and costs of electricity supply have been taken into consideration. To satisfy the site's objective of minimizing energy costs, the batteries will be charged also by CHP systems during off-peak and mid

  8. Combined process of pyrolyzer/combuster for gas production and power generation; Chugoku ni okeru chukibo hatsuden to toshi gas seizo no tame no fukugo process no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Ooka, I. [The University of Tokushima, Tokushima (Japan); Ma, T.

    1997-10-30

    In China, they are using a lot of coal by direct firing for domestic cooking, space heating and industrial use. Therefore air pollution is the big problem in every cities in winter season. And at moment, they do not have enough infrastructure for supplying energy such as gas and electric power. There is a great need for facilities for supplying gas and electric power from coal in big cities with much less pollution. This paper d a combined process of medium size plant of gas production and power generation by using fluidized circulation bed pyrolizer and combuster, to contribute to the energy supply which greatly reduces air and water polution and coal consumption. 1 ref., 1 fig., 3 tabs.

  9. Third-Harmonic Generated in EH32 Mode of a Gas-Filled Waveguide by fs Laser Pulses

    Institute of Scientific and Technical Information of China (English)

    CHEN Bao-Zhen; HUANG Zu-Qia

    2007-01-01

    In this paper it is reported for the first time that the third harmonic generated in EH32 mode of a gas-filled waveguide by fs pulses has higher generation efficiency. The new finding contrasts with the experiment in [C.G. Durfee Ⅲ, S. Backus, M.M. Murnane, and H.C. Kapteyn, Opt. Lett. 22 (1997) 1565]. Some possible factors, which produce the contradiction, are discussed briefly.

  10. Trace Gas Measurements on Mars and Earth Using Optical Parametric Generation

    Science.gov (United States)

    Numata, Kenji; Haris, Riris; Li, Steve; Sun, Xiaoli; Abshire, James Brice

    2010-01-01

    Trace gases and their isotopic ratios in planetary atmospheres offer important but subtle clues as to the origins of a planet's atmosphere, hydrology, geology, and potential for biology. An orbiting laser remote sensing instrument is capable of measuring trace gases on a global scale with unprecedented accuracy, and higher spatial resolution that can be obtained by passive instruments. We have developed an active sensing instrument for the remote measurement of trace gases in planetary atmospheres (including Earth). The technique uses widely tunable, seeded optical parametric generation (OPG) to measure methane, CO2, water vapor, and other trace gases in the near and mid-infrared spectral regions. Methane is a strong greenhouse gas on Earth and it is also a potential biogenic marker on Mars and other planets. Methane in the Earth's atmosphere survives for a shorter time than CO2 but its impact on climate change can be larger than CO2. Methane levels have remained relatively constant over the last decade around 1.78 parts per million (ppm) but recent observations indicate that methane levels may be on the rise. Increasing methane concentrations may trigger a positive feedback loop and a subsequent runaway greenhouse effect, where increasing temperatures result in increasing methane levels. The NRC Decadal Survey recognized the importance of global observations of greenhouse gases and called for simultaneous CH4, CO, and CO2 measurements but also underlined the technological limitations for these observations. For Mars, methane measurements are of great interest because of its potential as a strong biogenic marker. A remote sensing instrument that can measure day and night over all seasons and latitudes can identify and localize sources of biogenic gas plumes produced by subsurface chemistry or biology, and aid in the search for extra-terrestrial life. It can identify the dynamics of methane generation over time and latitude and identify future lander mission sites

  11. Comparison between landfill gas and waste incineration for power generation in Astana, Kazakhstan.

    Science.gov (United States)

    Inglezakis, Vassilis J; Rojas-Solórzano, Luis; Kim, Jong; Aitbekova, Aisulu; Ismailova, Aizada

    2015-05-01

    The city of Astana, the capital of Kazakhstan, which has a population of 804,474, and has been experiencing rapid growth over the last 15 years, generates approximately 1.39 kg capita(-1) day(-1) of municipal solid waste (MSW). Nearly 700 tonnes of MSW are collected daily, of which 97% is disposed of at landfills. The newest landfill was built using modern technologies, including a landfill gas (LFG) collection system.The rapid growth of Astana demands more energy on its path to development, and the viability analysis of MSW to generate electricity is imperative. This paper presents a technical-economic pre-feasibility study comparing landfill including LFG utilization and waste incineration (WI) to produce electricity. The performance of LFG with a reciprocating engine and WI with steam turbine power technologies were compared through corresponding greenhouse gases (GHG) reduction, cost of energy production (CEP), benefit-cost ratio (BCR), net present value (NPV) and internal rate of return (IRR) from the analyses. Results demonstrate that in the city of Astana, WI has the potential to reduce more than 200,000 tonnes of GHG per year, while LFG could reduce slightly less than 40,000 tonnes. LFG offers a CEP 5.7% larger than WI, while the latter presents a BCR two times higher than LFG. WI technology analysis depicts a NPV exceeding 280% of the equity, while for LFG, the NPV is less than the equity, which indicates an expected remarkable financial return for the WI technology and a marginal and risky scenario for the LFG technology. Only existing landfill facilities with a LFG collection system in place may turn LFG into a viable project.

  12. Dependence of Ozone Generation on Gas Temperature Distribution in AC Atmospheric Pressure Dielectric Barrier Discharge in Oxygen

    Science.gov (United States)

    Takahashi, Go; Akashi, Haruaki

    AC atmospheric pressure multi-filament dielectric barrier discharge in oxygen has been simulated using two dimensional fluid model. In the discharge, three kinds of streamers have been obtained. They are primary streamers, small scale streamers and secondary streamers. The primary streamers are main streamers in the discharge and the small scale streamers are formed after the ceasing of the primary streamers. And the secondary streamers are formed on the trace of the primary streamers. In these streamers, the primary and the small scale streamers are very effective to generate O(3P) oxygen atoms which are precursor of ozone. And the ozone is generated mainly in the vicinity of the dielectrics. In high gas temperature region, ozone generation decreases in general. However, increase of the O(3P) oxygen atom density in high gas temperature region compensates decrease of ozone generation rate coefficient. As a result, amount of ozone generation has not changed. But if the effect of gas temperature was neglected, amount of ozone generation increases 10%.

  13. Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation

    Energy Technology Data Exchange (ETDEWEB)

    Rue, David

    2013-09-30

    The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis

  14. The optimisation of the usage of gas turbine generation sets for oil and gas production using genetic algorithms

    OpenAIRE

    2010-01-01

    The privatisations of the energy supply industries world-wide has meant that emphasis is now on how to profitably compete. In this environment the development of effective models for optimisation of power plant are of increasing importance, particularly operational strategies for off-design conditions, and particularly for gas turbine engines. Maximisation of plant profitability necessitates proper and integrated evaluation of many factors, the most important of which are: availability and...

  15. Radioactivity in wastes generated from shale gas exploration and production - North-Eastern Poland.

    Science.gov (United States)

    Jodłowski, Paweł; Macuda, Jan; Nowak, Jakub; Nguyen Dinh, Chau

    2017-09-01

    In the present study, the K-40, U-238, Ra-226, Pb-210, Ra-228 and Th-228 activity concentrations were measured in 64 samples of wastes generated from shale gas exploration in North-Eastern Poland. The measured samples consist of drill cuttings, solid phase of waste drilling muds, fracking fluids, return fracking fluids and waste proppants. The measured activity concentrations in solid samples vary in a wide range from 116 to around 1100 Bq/kg for K-40, from 14 to 393 Bq/kg for U-238, from 15 to 415 Bq/kg for Ra-226, from 12 to 391 Bq/kg for Pb-210, from a few Bq/kg to 516 Bq/kg for Ra-228 and from a few Bq/kg to 515 Bq/kg for Th-228. Excluding the waste proppants, the measured activity concentrations in solid samples oscillate around their worldwide average values in soil. In the case of the waste proppants, the activity concentrations of radionuclides from uranium and thorium decay series are significantly elevated and equal to several hundreds of Bq/kg but it is connected with the mineralogical composition of proppants. The significant enhancement of Ra-226 and Ra-228 activity concentrations after fracking process was observed in the case of return fracking fluids, but the radium isotopes content in these fluids is comparable with that in waste waters from copper and coal mines in Poland. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Numerical analysis of heat transfer in the exhaust gas flow in a diesel power generator

    Science.gov (United States)

    Brito, C. H. G.; Maia, C. B.; Sodré, J. R.

    2016-09-01

    This work presents a numerical study of heat transfer in the exhaust duct of a diesel power generator. The analysis was performed using two different approaches: the Finite Difference Method (FDM) and the Finite Volume Method (FVM), this last one by means of a commercial computer software, ANSYS CFX®. In FDM, the energy conservation equation was solved taking into account the estimated velocity profile for fully developed turbulent flow inside a tube and literature correlations for heat transfer. In FVM, the mass conservation, momentum, energy and transport equations were solved for turbulent quantities by the K-ω SST model. In both methods, variable properties were considered for the exhaust gas composed by six species: CO2, H2O, H2, O2, CO and N2. The entry conditions for the numerical simulations were given by experimental data available. The results were evaluated for the engine operating under loads of 0, 10, 20, and 37.5 kW. Test mesh and convergence were performed to determine the numerical error and uncertainty of the simulations. The results showed a trend of increasing temperature gradient with load increase. The general behaviour of the velocity and temperature profiles obtained by the numerical models were similar, with some divergence arising due to the assumptions made for the resolution of the models.

  17. Combustion efficiency: Greenhouse gas emission reductions from the power generation sector

    Energy Technology Data Exchange (ETDEWEB)

    Kane, R.; South, D.W.; Fish, A.L. [Argonne National Laboratory, Upton, IL (United States)

    1993-12-31

    Concern for the possibility of an enhanced greenhouse effect and global climate change (GCC) has often been associated with energy use in general, and fossil fuel combustion in particular, because of associated emissions of CO{sub 2} and other greenhouse gases (GHG). Therefore, energy policies play a significant role in determining greenhouse gas emissions. The generation of electricity and power from more efficient fossil energy technologies provides an opportunity to significantly lower GHG emissions, together with other pollutants. The U.S. government oversees a broad-based program to facilitate the development, demonstration, and deployment of these technologies. Advanced fossil technologies offer other benefits as well, in that they permit continued use of widely available fuels such as coal. An international perspective is critical for assessing the role of these fuels, since countries differ in terms of their ability to maximize these benefits. Often, new technologies are considered the domain of industrialized countries. Yet more efficient technologies may have their greatest potential - to concurrently permit the utilization of indigenous fuels and to lower global GHG emissions in developing countries, especially those in the Asia-Pacific region.

  18. Simultaneous-Fault Diagnosis of Gas Turbine Generator Systems Using a Pairwise-Coupled Probabilistic Classifier

    Directory of Open Access Journals (Sweden)

    Zhixin Yang

    2013-01-01

    Full Text Available A reliable fault diagnostic system for gas turbine generator system (GTGS, which is complicated and inherent with many types of component faults, is essential to avoid the interruption of electricity supply. However, the GTGS diagnosis faces challenges in terms of the existence of simultaneous-fault diagnosis and high cost in acquiring the exponentially increased simultaneous-fault vibration signals for constructing the diagnostic system. This research proposes a new diagnostic framework combining feature extraction, pairwise-coupled probabilistic classifier, and decision threshold optimization. The feature extraction module adopts wavelet packet transform and time-domain statistical features to extract vibration signal features. Kernel principal component analysis is then applied to further reduce the redundant features. The features of single faults in a simultaneous-fault pattern are extracted and then detected using a probabilistic classifier, namely, pairwise-coupled relevance vector machine, which is trained with single-fault patterns only. Therefore, the training dataset of simultaneous-fault patterns is unnecessary. To optimize the decision threshold, this research proposes to use grid search method which can ensure a global solution as compared with traditional computational intelligence techniques. Experimental results show that the proposed framework performs well for both single-fault and simultaneous-fault diagnosis and is superior to the frameworks without feature extraction and pairwise coupling.

  19. Reduction of greenhouse-gas emissions by utilization of superconductivity in electric-power generation

    Energy Technology Data Exchange (ETDEWEB)

    Hartikainen, T.; Lehtonen, J.; Mikkonen, R. [Tampere University of Technology (Finland). Institute of Electromagnetics

    2004-06-01

    The reduction of greenhouse-gas (GHG) emissions is becoming a topical issue due to the Kyoto Protocol which requires the European Union (EU) to reduce its emissions by 8% from the 1990 levels by between 2008 and 2012. The main source for GHG-emissions is energy production. Superconducting electrical machinery is starting to emerge into the market of power devices. High-temperature superconducting (HTS) windings in generators and transformers can approximately halve the losses compared to conventional devices. Higher efficiency saves electrical energy and also reduces GHG-emissions as well. In this paper, the reduction potential of GHG-emissions in the EU by HTS-machinery is calculated. The replacement of existing devices by HTS ones is considered from the environmental point-of- view. The structure of energy production for the EU was investigated and the emission data from different type of power plants were screened. The potential energy savings were converted to saved GHG-emission tonnes. (author)

  20. Reversible solid oxide fuel cell for natural gas/renewable hybrid power generation systems

    Science.gov (United States)

    Luo, Yu; Shi, Yixiang; Zheng, Yi; Cai, Ningsheng

    2017-02-01

    Renewable energy (RE) is expected to be the major part of the future energy. Presently, the intermittence and fluctuation of RE lead to the limitation of its penetration. Reversible solid oxide fuel cell (RSOFC) as the energy storage device can effectively store the renewable energy and build a bidirectional connection with natural gas (NG). In this paper, the energy storage strategy was designed to improve the RE penetration and dynamic operation stability in a distributed system coupling wind generators, internal combustion engine, RSOFC and lithium-ion batteries. By compromising the relative deviation of power supply and demand, RE penetration, system efficiency and capacity requirement, the strategy that no more than 36% of the maximum wind power output is directly supplied to users and the other is stored by the combination of battery and reversible solid oxide fuel cell is optimal for the distributed system. In the case, the RE penetration reached 56.9% and the system efficiency reached 55.2%. The maximum relative deviation of power supply and demand is also lower than 4%, which is significantly superior to that in the wind curtailment case.

  1. Comparisons Between Unsteady Aerodynamic Events in a Gas Turbine Generator and an Identical Compressor Rig

    Science.gov (United States)

    Owen, A. Karl

    1996-01-01

    Extensive testing done on a T55-L-712 turboshaft engine compressor in a compressor test rig is being followed by engine tests in progress as part of the Army Non-Recoverable Stall Program. Goals include a greater understanding of the gas turbine engine start cycle and compressor/engine operation in the regions 'beyond' the normal compressor stall line (rotating stall/surge). Rig steady state instrumentation consisted of 497 steady state pressure sensors and 153 temperature sensors. Engine instrumentation was placed in similar radial/axial locations and consists of 122 steady state pressure sensors and 65 temperature sensors. High response rig instrumentation consisted of 34 wall static pressure transducers. Rig and engine high response pressure transducers were located in the same axial/radial/circumferential locations in front of the first three stages. Additional engine high response instrumentation was placed in mach probes in front of the engine and on the compressor hub. This instrumentation allows for the generation of detailed stage characteristics, overall compressor mapping, and detailed analysis of dynamic compressor events.

  2. An Effective Fault Feature Extraction Method for Gas Turbine Generator System Diagnosis

    Directory of Open Access Journals (Sweden)

    Jian-Hua Zhong

    2016-01-01

    Full Text Available Fault diagnosis is very important to maintain the operation of a gas turbine generator system (GTGS in power plants, where any abnormal situations will interrupt the electricity supply. The fault diagnosis of the GTGS faces the main challenge that the acquired data, vibration or sound signals, contain a great deal of redundant information which extends the fault identification time and degrades the diagnostic accuracy. To improve the diagnostic performance in the GTGS, an effective fault feature extraction framework is proposed to solve the problem of the signal disorder and redundant information in the acquired signal. The proposed framework combines feature extraction with a general machine learning method, support vector machine (SVM, to implement an intelligent fault diagnosis. The feature extraction method adopts wavelet packet transform and time-domain statistical features to extract the features of faults from the vibration signal. To further reduce the redundant information in extracted features, kernel principal component analysis is applied in this study. Experimental results indicate that the proposed feature extracted technique is an effective method to extract the useful features of faults, resulting in improvement of the performance of fault diagnosis for the GTGS.

  3. Development of high pressure deuterium gas targets for the generation of intense mono-energetic fast neutron beams

    Energy Technology Data Exchange (ETDEWEB)

    Guzek, J. E-mail: jguzek@debeers.co.za; Richardson, K.; Franklyn, C.B.; Waites, A.; McMurray, W.R.; Watterson, J.I.W.; Tapper, U.A.S

    1999-06-01

    Two different technical solutions to the problem of generation of mono-energetic fast neutron beams on the gaseous targets are presented here. A simple and cost-effective design of a cooled windowed gas target system is described in the first part of this paper. It utilises a thin metallic foil window and circulating deuterium gas cooled down to 100 K. The ultimate beam handling capability of such target is determined by the properties of the window. Reliable performance of this gas target system was achieved at 1 bar of deuterium gas, when exposed to a 45 {mu}A beam of 5 MeV deuterons, for periods in excess of 6 h. Cooling of the target gas resulted in increased fast neutron output and improved neutron to gamma-ray ratio. The second part of this paper discusses the design of a high pressure, windowless gas target for use with pulsed, low duty cycle accelerators. A rotating seal concept was applied to reduce the gas load in a differentially pumped system. This allows operation at 1.23 bar of deuterium gas pressure in the gas cell region. Such a gas target system is free from the limitations of the windowed target but special attention has to be paid to the heat dissipation capability of the beam dump, due to the use of a thin target. The rotating seal concept is particularly suitable for use with accelerators such as radio-frequency quadrupole (RFQ) linacs that operate with a very high peak current at low duty cycle. The performance of both target systems was comprehensively characterized using the time-of-flight (TOF) technique. This demonstrated that very good quality mono-energetic fast neutron beams were produced with the slow neutron and gamma-ray component below 10% of the total target output.

  4. Contribution of N2O to the greenhouse gas balance of first-generation biofuels : climate change and biofuels

    NARCIS (Netherlands)

    Smeets, E.M.W.; Bouwman, A.F.; Stehfest, E.; van Vuuren, D.P.; Posthuma, A.

    2009-01-01

    In this study, we analyze the impact of fertilizer- and manure-induced N2O emissions due to energy crop production on the reduction of greenhouse gas (GHG) emissions when conventional transportation fuels are replaced by first-generation biofuels (also taking account of other GHG emissions during th

  5. Co-generated fast pyrolysis biochar mitigates green-house gas emissions and increases carbon sequestration in temperate soils

    Science.gov (United States)

    Biochar (BC) is a product of thermochemical conversion of biomass via pyrolysis, together with gas (syngas), liquid (bio-oil), and heat. Fast pyrolysis is a promising process for bio-oil generation, which leaves 10-30% of the original biomass as char. When applied to soils, BC may increase soil C s...

  6. Gas generation from biomass for decentralized power supply systems; Gaserzeugung fuer dezentrale Energiesysteme auf der Basis von Biomasse

    Energy Technology Data Exchange (ETDEWEB)

    Kubiak, H.; Papamichalis, A.; Heek, K.H. van [DMT-Inst. fuer Kokserzeugung und Brennstofftechnik, Essen (Germany)

    1996-12-31

    By a reaction with steam, bioresidues and plants can be converted into a gas consisting mainly of hydrogen, carbon monoxide and methane which can be used for electric power generation in gas engines, gas turbins and fuel cells. The conversion processes, especially the fuel cell process, are environment-friendly and efficient. For decentralized applications (i.e. for biomass volumes of 0.5 to 1 t/h), an allothermal process is recommended which is described in detail. (orig) [Deutsch] Durch Reaktion mit Wasserdampf lassen sich Bioreststoffe und Energiepflanzen zu einem Gas umsetzen, das im wesentlichen aus Wasserstoff, Kohlenmonoxid und Methan besteht und z.B. ueber Gasmotoren, Gasturbinen, vorzugsweise aber Brennstoffzellen zu Strom umgewandelt werden kann. Die Umwandlungsverfahren, insbesondere unter Benutzung von Brennstoffzellen, sind umweltfreundlich und haben einen hohen Wirkungsgrad. Als Vergasungsverfahren eignet sich fuer die dezentrale Anwendung. - d.h. fuer eine Biomassemenge von 0,5 bis 1 t/h - insbesondere das hier beschriebene allotherme Verfahren. (orig)

  7. Study Analysis of Flue Gas Utilization as Alternative Power Generation in Cement Plant Using Organic Rankine Cycle System

    Directory of Open Access Journals (Sweden)

    Rahmat Ranggonang Anwar

    2017-01-01

    Full Text Available Abstract—Cement plant produce large amount of heat source in cement making process, due to inefficiency of system there still waste heat available in form of flue gas that can be utilize. Flue gas  in cement plant can be utilized as alternative power generation. With the 200-300oC temperature output range of flue gas from suspension preheater and air quenching cooler (AQC in cement plant, organic rankine cycle (ORC can be suitable option for alternative power generation. ORC is development of rankine cycle, the different is the working fluid in ORC using refrigerant. In cement plant that produce 8466 TPD kiln production, used flue gas from suspension preheater to dry raw material and produce 163888 m3/h flue gas from AQC that still not utilized. Flue gas with 235oC temperature from AQC can utilized for power generation purpose using ORC system. Waste heat recovery calculation carried out to know the potential recovery. Operating condition of the ORC system will determine power produced that can be generated and ORC components calculated and selected according to the operating condition of the system. Using R141b as working fluid with 8 bar pressure and 110oC temperature inlet to turbine, power produced by turbine is 666 kW. For the components, evaporator and condenser use shell and tube heat exchanger, with evaporator heat transfer area is 676.49 m2 while condenser has 510 m2 of heat transfer area. And for working fluid pump it needs 16.235 Kw power to pump R141b back to evaporator.

  8. Application Status and Problem Investigation of Distributed Generation in China: The Case of Natural Gas, Solar and Wind Resources

    Directory of Open Access Journals (Sweden)

    Tian-tian Feng

    2017-06-01

    Full Text Available The development of distributed energy systems in China is one of the important measures to promote the revolution for energy production and its utilization patterns. First of all, we analyze the present application status of China’s distributed generation from three major types: natural gas, photovoltaic, and distributed wind. Secondly, based on the analysis of the project overview, project scale, and project effect in three patterns of distributed generation, we summarize the policy deficiencies and development obstacles. Finally, aiming to promote the development of distributed energy in China, we propose some relevant policies corresponding to countermeasures on the problems existing in the development process of China’s distributed generation of natural gas, photovoltaic, and wind power.

  9. Evaluation of Gas-Cooled Pressurized Phosphoric Acid Fuel Cells for Electric Utility Power Generation

    Science.gov (United States)

    Faroque, M.

    1983-01-01

    Gas cooling is a more reliable, less expensive and a more simple alternative to conventional liquid cooling for heat removal from the phosphoric acid fuel cell (PAFC). The feasibility of gas-cooling was already demonstrated in atmospheric pressure stacks. Theoretical and experimental investigations of gas-cooling for pressurized PAFC are presented. Two approaches to gas cooling, Distributed Gas-Cooling (DIGAS) and Separated Gas-Cooling (SGC) were considered, and a theoretical comparison on the basis of cell performance indicated SGC to be superior to DIGAS. The feasibility of SGC was experimentally demonstrated by operating a 45-cell stack for 700 hours at pressure, and determining thermal response and the effect of other related parameters.

  10. Advanced gas turbine cycles a brief review of power generation thermodynamics

    CERN Document Server

    Horlock, JH

    2003-01-01

    Primarily this book describes the thermodynamics of gas turbine cycles. The search for high gas turbine efficiency has produced many variations on the simple ""open circuit"" plant, involving the use of heat exchangers, reheating and intercooling, water and steam injection, cogeneration and combined cycle plants. These are described fully in the text. A review of recent proposals for a number of novel gas turbine cycles is also included. In the past few years work has been directed towards developing gas turbines which produce less carbon dioxide, or plants from which the CO2 can be d

  11. Comparative analysis of gas and coal-fired power generation in ultra-low emission condition using life cycle assessment (LCA)

    Science.gov (United States)

    Yin, Libao; Liao, Yanfen; Liu, Guicai; Liu, Zhichao; Yu, Zhaosheng; Guo, Shaode; Ma, Xiaoqian

    2017-05-01

    Energy consumption and pollutant emission of natural gas combined cycle power-generation (NGCC), liquefied natural gas combined cycle power-generation (LNGCC), natural gas combined heat and power generation (CHP) and ultra-supercritical power generation with ultra-low gas emission (USC) were analyzed using life cycle assessment method, pointing out the development opportunity and superiority of gas power generation in the period of coal-fired unit ultra-low emission transformation. The results show that CO2 emission followed the order: USC>LNGCC>NGCC>CHP the resource depletion coefficient of coal-fired power generation was lower than that of gas power generation, and the coal-fired power generation should be the main part of power generation in China; based on sensitivity analysis, improving the generating efficiency or shortening the transportation distance could effectively improve energy saving and emission reduction, especially for the coal-fired units, and improving the generating efficiency had a great significance for achieving the ultra-low gas emission.

  12. Generation, Detection and characterization of Gas-Phase Transition Metal containing Molecules

    Energy Technology Data Exchange (ETDEWEB)

    Steimle, Timothy [Arizona State Univ., Tempe, AZ (United States)

    2015-12-15

    The objective of this project was to generate, detect, and characterize small, gas-phase, metal containing molecules. In addition to being relevant to high temperature chemical environments (e.g. plasmas and combustion), gas-phase experiments on metal containing molecules serve as the most direct link to a molecular-level theoretical model for catalysis. Catalysis (i.e. the addition of a small about of recoverable material to control the rate and direction of a chemical reaction) is critical to the petroleum and pharmaceutical industries as well as environmental remediation. Currently, the majority of catalytic materials are based on very expensive metals such as platinum (Pt), palladium (Pd), iridium (Ir,) rhenium (Re), and rhodium (Rh). For example, the catalyst used for converting linear hydrocarbon molecules (e.g. hexane) to cyclic molecules (e.g. cyclohexane) is a mixture of Pt and Re suspended on alumina. It enables straight chain alkanes to be converted into branched-chain alkanes, cyclohexanes and aromatic hydrocarbons which are used, amongst other things, to enhance the octane number of petrol. A second example is the heterogeneous catalysis used in automobile exhaust systems to: a) decrease nitrogen oxide; b) reduce carbon monoxide; and c) oxidize unburned hydrocarbons. The exhaust is vented through a high-surface area chamber lined with Pt, Pd, and Rh. For example, the carbon monoxide is catalytically converted to carbon dioxide by reaction with oxygen. The research results from this work have been published in readily accessible journals1-28. The ground and excited electronic state properties of small metal containing molecules that we determine were: a) electronic state distributions and lifetimes, b) vibrational frequencies, c) bond lengths and angles, d) hyperfine interactions, e) permanent electric dipole moments, mel, and f) magnetic dipoles, μm. In general terms, μel, gives insight into the charge distribution and mm into

  13. Comparative life-cycle air emissions of coal, domestic natural gas, LNG, and SNG for electricity generation.

    Science.gov (United States)

    Jaramillo, Paulina; Griffin, W Michael; Matthews, H Scott

    2007-09-01

    The U.S. Department of Energy (DOE) estimates that in the coming decades the United States' natural gas (NG) demand for electricity generation will increase. Estimates also suggest that NG supply will increasingly come from imported liquefied natural gas (LNG). Additional supplies of NG could come domestically from the production of synthetic natural gas (SNG) via coal gasification-methanation. The objective of this study is to compare greenhouse gas (GHG), SOx, and NOx life-cycle emissions of electricity generated with NG/LNG/SNG and coal. This life-cycle comparison of air emissions from different fuels can help us better understand the advantages and disadvantages of using coal versus globally sourced NG for electricity generation. Our estimates suggest that with the current fleet of power plants, a mix of domestic NG, LNG, and SNG would have lower GHG emissions than coal. If advanced technologies with carbon capture and sequestration (CCS) are used, however, coal and a mix of domestic NG, LNG, and SNG would have very similar life-cycle GHG emissions. For SOx and NOx we find there are significant emissions in the upstream stages of the NG/ LNG life-cycles, which contribute to a larger range in SOx and NOx emissions for NG/LNG than for coal and SNG.

  14. Pretreated Landfill Gas Conversion Process via a Catalytic Membrane Reactor for Renewable Combined Fuel Cell-Power Generation

    Directory of Open Access Journals (Sweden)

    Zoe Ziaka

    2013-01-01

    Full Text Available A new landfill gas-based reforming catalytic processing system for the conversion of gaseous hydrocarbons, such as incoming methane to hydrogen and carbon oxide mixtures, is described and analyzed. The exit synthesis gas (syn-gas is fed to power effectively high-temperature fuel cells such as SOFC types for combined efficient electricity generation. The current research work is also referred on the description and design aspects of permreactors (permeable reformers carrying the same type of landfill gas-reforming reactions. Membrane reactors is a new technology that can be applied efficiently in such systems. Membrane reactors seem to perform better than the nonmembrane traditional reactors. The aim of this research includes turnkey system and process development for the landfill-based power generation and fuel cell industries. Also, a discussion of the efficient utilization of landfill and waste type resources for combined green-type/renewable power generation with increased processing capacity and efficiency via fuel cell systems is taking place. Moreover, pollution reduction is an additional design consideration in the current catalytic processors fuel cell cycles.

  15. Formulation and Performance of Novel Energetic Nanocomposites and Gas Generators Prepared by Sol-Gel Methods

    Energy Technology Data Exchange (ETDEWEB)

    Clapsaddle, B J; Zhao, L; Prentice, D; Pantoya, M L; Gash, A E; Satcher Jr., J H; Shea, K J; Simpson, R L

    2005-03-24

    In the field of composite energetic materials, properties such as ingredient distribution, particle size, and morphology affect both sensitivity and performance. Since the reaction kinetics of composite energetic materials are typically controlled by the mass transport rates between reactants, one would anticipate new and potentially exceptional performance from energetic nanocomposites. We have developed a new method of making nanostructured energetic materials, specifically explosives, propellants, and pyrotechnics, using sol-gel chemistry. A novel sol-gel approach has proven successful in preparing nanostructured metal oxide materials. By introducing a fuel metal, such as aluminum, into the nanostructured metal oxide matrix, energetic materials based on thermite reactions can be fabricated. Two of the metal oxides are tungsten trioxide and iron(III) oxide, both of which are of interest in the field of energetic materials. Due to the versatility of the preparation method, binary oxidizing phases can also be prepared, thus enabling a potential means of controlling the energetic properties of the subsequent nanocomposites. Furthermore, organic additives can also be easily introduced into the nanocomposites for the production of nanostructured gas generators. The resulting nanoscale distribution of all the ingredients displays energetic properties not seen in its micro-scale counterparts due to the expected increase of mass transport rates between the reactants. The unique synthesis methodology, formulations, and performance of these materials will be presented. The degree of control over the burning rate of these nanocomposites afforded by the compositional variation of a binary oxidizing phase will also be discussed. These energetic nanocomposites have the potential for releasing controlled amounts of energy at a controlled rate. Due to the versatility of the synthesis method, a large number of compositions and physical properties can be achieved, resulting in

  16. Endurance and failure of an alumina-based monopropellant microthruster with integrated heater, catalytic bed and temperature sensors

    Science.gov (United States)

    Khaji, Zahra; Klintberg, Lena; Barbade, Dhananjay; Palmer, Kristoffer; Thornell, Greger

    2017-05-01

    Monopropellant ceramic microthrusters with an integrated heater, catalytic bed and two temperature sensors, but of various designs, were manufactured by milling a fluidic channel and chamber, and a nozzle, and screen printing platinum patterns on green tapes of alumina that were stacked and laminated before sintering. In order to increase the surface area of the catalytic bed, the platinum paste was mixed with a sacrificial paste that disappeared during sintering, to leave behind a porous and rough layer. As an early development level in manufacturing robust and high-temperature tolerant microthrusters, the influence of design on the temperature gradients and dry temperature tolerance of the devices was studied. On average, the small reaction chambers showed a more than 1.5 times higher dry temperature tolerance (in centigrade) compared to devices with larger chambers, independent of the heater and device size. However, for a given temperature, big devices consumed on average 2.9 times more power than the small ones. It was also found that over the same area and under the same heating conditions, devices with small chambers were subjected to approximately 40% smaller temperature differences. A pressure test done on two small devices with small chambers revealed that pressures of at least 26.3 bar could be tolerated. Above this pressure, the interfaces failed but the devices were not damaged. To investigate the cooling effect of the micropropellant, the endurance of a full thruster was also studied under wet testing where it was fed with 31 wt.% hydrogen peroxide. The thruster demonstrated complete evaporation and/or full decomposition at a power above 3.7 W for a propellant flow of 50 µl min-1. At this power, the catalytic bed locally reached a temperature of 147 °C. The component was successfully heated to an operating temperature of 307 °C, where it cracked. Under these firing conditions, and assuming complete decomposition, calculations give a thrust and

  17. THE USE OF GENERATING SETS WITH lNG GAS ENGINES IN “SHORE TO SHIP” SYSTEMS

    Directory of Open Access Journals (Sweden)

    Dariusz TARNAPOWICZ

    2016-07-01

    Full Text Available The main sources of air pollution in ports are ships, on which electrical energy is produced in the autonomous gener-ating sets Diesel-Generator. The most effective way to reduce harmful exhaust emissions from ships is to exclude marine generating sets and provide the shore-side electricity in “Shore to Ship” system. The main problem in the implementa-tion of power supply for ships from land is connected with matching parameters of voltage in onshore network with marine network. Currently, the recommended solution is to supply ships from the onshore electricity network with the use of power electronic converters. This article presents an analysis of the „Shore to Ship” system with the use of gener-ating sets with LNG gas engines. It shows topologies with LNG – Generator sets, environmental benefits of such a solu-tion, advantages and disadvantages.

  18. Bremsstrahlung {gamma}-ray generation by electrons from gas jets irradiated by laser pulses for radiographic testing

    Energy Technology Data Exchange (ETDEWEB)

    Oishi, Yuji; Nayuki, Takuya; Zhidkov, Alexei; Fujii, Takashi; Nemoto, Koshichi [Central Research Institute of Electric Power Industry, Yokosuka, Kanagawa 240-0196 (Japan); Central Research Institute of Electric Power Industry, Yokosuka, Kanagawa 240-0196, Japan and Photon Pioneers Center in Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871 (Japan); Central Research Institute of Electric Power Industry, Yokosuka, Kanagawa 240-0196 (Japan)

    2012-07-11

    Electron generation from a gas jet irradiated by low energy femtosecond laser pulses is studied experimentally as a promising source of radiation for radioisotope-free {gamma}-ray imaging systems. The calculated yield of {gamma}-rays in the 0.5-2 MeV range, produced by low-average-power lasers and gas targets, exceeds the yields from solid tape targets up to 60 times. In addition, an effect of quasi-mono energetic electrons on {gamma}-ray imaging is also discussed.

  19. Bremsstrahlung γ-ray generation by electrons from gas jets irradiated by laser pulses for radiographic testing

    Science.gov (United States)

    Oishi, Yuji; Nayuki, Takuya; Zhidkov, Alexei; Fujii, Takashi; Nemoto, Koshichi

    2012-07-01

    Electron generation from a gas jet irradiated by low energy femtosecond laser pulses is studied experimentally as a promising source of radiation for radioisotope-free γ-ray imaging systems. The calculated yield of γ-rays in the 0.5-2 MeV range, produced by low-average-power lasers and gas targets, exceeds the yields from solid tape targets up to 60 times. In addition, an effect of quasi-mono energetic electrons on γ-ray imaging is also discussed.

  20. Generating electricity and heat from lean gas. Dual fuel engine generates electricity and process heat from cupola furnace gas; Strom und Waerme aus Schwachgas gewinnen. Zuendstrahlmotor erzeugt Strom und Prozesswaerme aus Kupolofengas

    Energy Technology Data Exchange (ETDEWEB)

    Hirn, Gerhard

    2012-07-01

    White-hot molten iron flows into the launder. The blast of heat released provides visitors with an impressive demonstration of the amount of energy flowing in foundries. Large volumes of carbon (coke) are used for the melting process in the cupola furnace, whereby a combustible process gas is formed as a by-product. This so-called cupola furnace gas has a low heating value and has previously been completely combusted for generating the hot blast in the cupola furnace's recuperator. However, in this process only around 35 % of the contained energy is used thermally. Now it is possible to utilise the remaining 65 % of the chemically bound energy that was previously not used in most foundries: a modified biogas combined heat and power plant runs with cupola furnace gas (CFG) from the melting furnace. (orig.)

  1. Evaluation of Near-Surface Gases in Marine Sediments to Assess Subsurface Petroleum Gas Generation and Entrapment

    Directory of Open Access Journals (Sweden)

    Michael A. Abrams

    2017-05-01

    Full Text Available Gases contained within near-surface marine sediments can be derived from multiple sources: shallow microbial activity, thermal cracking of organic matter and inorganic materials, or magmatic-mantle degassing. Each origin will display a distinctive hydrocarbon and non-hydrocarbon composition as well as compound-specific isotope signature and thus the interpretation of origin should be relatively straightforward. Unfortunately, this is not always the case due to in situ microbial alteration, non-equilibrium phase partitioning, mixing, and fractionation related to the gas extraction method. Sediment gases can reside in the interstitial spaces, bound to mineral or organic surfaces and/or entrapped in carbonate inclusions. The interstitial sediment gases are contained within the sediment pore space, either dissolved in the pore waters (solute or as free (vapour gas. The bound gases are believed to be attached to organic and/or mineral surfaces, entrapped in structured water or entrapped in authigenic carbonate inclusions. The purpose of this paper is to provide a review of the gas types found within shallow marine sediments and examine issues related to gas sampling and extraction. In addition, the paper will discuss how to recognise mixing, alteration and fractionation issues to best interpret the seabed geochemical results and determine gas origin to assess subsurface petroleum gas generation and entrapment.

  2. Mitigation of Hydrogen Gas Generation from the Reaction of Water with Uranium Metal in K Basins Sludge

    Energy Technology Data Exchange (ETDEWEB)

    Sinkov, Sergey I.; Delegard, Calvin H.; Schmidt, Andrew J.

    2010-01-29

    Means to decrease the rate of hydrogen gas generation from the chemical reaction of uranium metal with water were identified by surveying the technical literature. The underlying chemistry and potential side reactions were explored by conducting 61 principal experiments. Several methods achieved significant hydrogen gas generation rate mitigation. Gas-generating side reactions from interactions of organics or sludge constituents with mitigating agents were observed. Further testing is recommended to develop deeper knowledge of the underlying chemistry and to advance the technology aturation level. Uranium metal reacts with water in K Basin sludge to form uranium hydride (UH3), uranium dioxide or uraninite (UO2), and diatomic hydrogen (H2). Mechanistic studies show that hydrogen radicals (H·) and UH3 serve as intermediates in the reaction of uranium metal with water to produce H2 and UO2. Because H2 is flammable, its release into the gas phase above K Basin sludge during sludge storage, processing, immobilization, shipment, and disposal is a concern to the safety of those operations. Findings from the technical literature and from experimental investigations with simple chemical systems (including uranium metal in water), in the presence of individual sludge simulant components, with complete sludge simulants, and with actual K Basin sludge are presented in this report. Based on the literature review and intermediate lab test results, sodium nitrate, sodium nitrite, Nochar Acid Bond N960, disodium hydrogen phosphate, and hexavalent uranium [U(VI)] were tested for their effects in decreasing the rate of hydrogen generation from the reaction of uranium metal with water. Nitrate and nitrite each were effective, decreasing hydrogen generation rates in actual sludge by factors of about 100 to 1000 when used at 0.5 molar (M) concentrations. Higher attenuation factors were achieved in tests with aqueous solutions alone. Nochar N960, a water sorbent, decreased hydrogen

  3. ESTIMATION OF RADIOLYTIC GAS GENERATION RATE FOR CYLINDRICAL RADIOACTIVE WASTE PACKAGES - APPLICATION TO SPENT ION EXCHANGE RESIN CONTAINERS

    Energy Technology Data Exchange (ETDEWEB)

    Husain, A.; Lewis, Brent J.

    2003-02-27

    Radioactive waste packages containing water and/or organic substances have the potential to radiolytically generate hydrogen and other combustible gases. Typically, the radiolytic gas generation rate is estimated from the energy deposition rate and the radiolytic gas yield. Estimation of the energy deposition rate must take into account the contributions from all radionuclides. While the contributions from non-gamma emitting radionuclides are relatively easy to estimate, an average geometry factor must be computed to determine the contribution from gamma emitters. Hitherto, no satisfactory method existed for estimating the geometry factors for a cylindrical package. In the present study, a formulation was developed taking into account the effect of photon buildup. A prototype code, called PC-CAGE, was developed to numerically solve the integrals involved. Based on the selected dimensions for a cylinder, the specified waste material, the photon energy of interest and a value for either the absorption or attenuation coefficient, the code outputs values for point and average geometry factors. These can then be used to estimate the internal dose rate to the material in the cylinder and hence to calculate the radiolytic gas generation rate. Besides the ability to estimate the rates of radiolytic gas generation, PC-CAGE can also estimate the dose received by the container material. This is based on values for the point geometry factors at the surface of the cylinder. PC-CAGE was used to calculate geometry factors for a number of cylindrical geometries. Estimates for the absorbed dose rate in container material were also obtained. The results for Ontario Power Generation's 3 m3 resin containers indicate that about 80% of the source gamma energy is deposited internally. In general, the fraction of gamma energy deposited internally depends on the dimensions of the cylinder, the material within it and the photon energy; the fraction deposited increases with increasing

  4. High harmonic generation in a gas-filled hollow-core photonic crystal fiber

    Science.gov (United States)

    Heckl, O. H.; Baer, C. R. E.; Kränkel, C.; Marchese, S. V.; Schapper, F.; Holler, M.; Südmeyer, T.; Robinson, J. S.; Tisch, J. W. G.; Couny, F.; Light, P.; Benabid, F.; Keller, U.

    2009-10-01

    High harmonic generation (HHG) of intense infrared laser radiation (Ferray et al., J. Phys. B: At. Mol. Opt. Phys. 21:L31, 1988; McPherson et al., J. Opt. Soc. Am. B 4:595, 1987) enables coherent vacuum-UV (VUV) to soft-X-ray sources. In the usual setup, energetic femtosecond laser pulses are strongly focused into a gas jet, restricting the interaction length to the Rayleigh range of the focus. The average photon flux is limited by the low conversion efficiency and the low average power of the complex laser amplifier systems (Keller, Nature 424:831, 2003; Südmeyer et al., Nat. Photonics 2:599, 2008; Röser et al., Opt. Lett. 30:2754, 2005; Eidam et al., IEEE J. Sel. Top. Quantum Electron. 15:187, 2009) which typically operate at kilohertz repetition rates. This represents a severe limitation for many experiments using the harmonic radiation in fields such as metrology or high-resolution imaging. Driving HHG with novel high-power diode-pumped multi-megahertz laser systems has the potential to significantly increase the average photon flux. However, the higher average power comes at the expense of lower pulse energies because the repetition rate is increased by more than a thousand times, and efficient HHG is not possible in the usual geometry. So far, two promising techniques for HHG at lower pulse energies were developed: external build-up cavities (Gohle et al., Nature 436:234, 2005; Jones et al., Phys. Rev. Lett. 94:193, 2005) and resonant field enhancement in nanostructured targets (Kim et al., Nature 453:757, 2008). Here we present a third technique, which has advantages in terms of ease of HHG light extraction, transverse beam quality, and the possibility to substantially increase conversion efficiency by phase-matching (Paul et al., Nature 421:51, 2003; Ren et al., Opt. Express 16:17052, 2008; Serebryannikov et al., Phys. Rev. E (Stat. Nonlinear Soft Matter Phys.) 70:66611, 2004; Serebryannikov et al., Opt. Lett. 33:977, 2008; Zhang et al., Nat. Phys. 3

  5. Utilizing Gas Filled Cavities for the Generation of an Intense Muon Source

    Energy Technology Data Exchange (ETDEWEB)

    Stratakis, Diktys; Neuffer, David V.

    2015-05-01

    A key requirement for designing intense muon sources is operating rf cavities in multi-tesla magnetic fields. Recently, a proof-of-principle experiment demonstrated that an rf cavity filed with high pressure hydrogen gas could meet this goal. In this study, rigorous simulation is used to design and evaluate the performance of an intense muon source with gas filled cavities. We present a new lattice design and compare our results with conventional schemes. We detail the influence of gas pressure on the muon production rate.

  6. Utilizing gas-filled cavities for the generation of an intense muon source

    Energy Technology Data Exchange (ETDEWEB)

    Stratakis, Diktys [Brookhaven National Lab. (BNL), Upton, NY (United States); Neuffer, David V. [Fermi National Accelerator Lab. (FNAL), Batavia, IL (United States)

    2015-05-03

    A key requirement for designing intense muon sources is operating rf cavities in multi-tesla magnetic fields. Recently, a proof-of-principle experiment demonstrated that an rf cavity filed with high pressure hydrogen gas could meet this goal. In this study, rigorous simulation is used to design and evaluate the performance of an intense muon source with gas filled cavities. We present a new lattice design and compare our results with conventional schemes. We detail the influence of gas pressure on the muon production rate.

  7. A Simulator for a Hydrocarbon Ramrocket Fuel Gas Generator - First Phase Development

    Science.gov (United States)

    1989-05-01

    Australian Airlines, Library Qantas Airways Limited Gas & Fuel Corporation of Vic., Manager Scientific Services SEC of Vic., Herman Research Laboratory...EXHAUST SAMPLING AND ANALYSIS 8 7.1 Solid Products 9 7.1.1 Probe System 9 7.1.2 Wet Filtering 9 7.1.3 Dry Filtering 10 7.2 Gaseous Products 10 7.2.1 Gas...Sampling System 10 7.2.2 Gas Chromatography 11 8. OBSERVATIONS OF TEST HARDWARE PERFORMANCE 11 9. RESULTS AND DISCUSSION 13 9.1 Analysis of Zaccardi

  8. Method for generating a highly reactive plasma for exhaust gas after treatment and enhanced catalyst reactivity

    Energy Technology Data Exchange (ETDEWEB)

    Whealton, John H.; Hanson, Gregory R.; Storey, John M.; Raridon, Richard J.; Armfield, Jeffrey S.; Bigelow, Timothy S.; Graves, Ronald L.

    2000-07-01

    This patent application describes a method and apparatus of exhaust gas remediation that enhance the reactivity of the material catalysts found within catalytic converters of cars, trucks, and power stations.

  9. Landfill gas generation and emission at danish waste disposal sites receiving waste with a low organic waste content

    DEFF Research Database (Denmark)

    Mou, Zishen; Scheutz, Charlotte; Kjeldsen, Peter

    2015-01-01

    two models are multi-phase models, which defines waste fractions into traditional MSW and low-organic waste categories, respectively. Both the LandGEM and the IPCC model estimated significantly larger methane (CH4) generation in comparison to the Afvalzorg model. The Afvalzorg model could better show...... the influence of not only the total disposed waste amount, but also various waste categories, and was found more suitable to estimate LFG generation from landfills receiving low-organic waste. Four major waste categories currently being disposed at Danish landfills (mixed bulky, shredder, dewatered sludge...... results. The LFG generation from four Danish landfills was estimated by the Afvalzorg model using the experimentally based BMP and k values and compared to whole landfill emission rates measured by applying a tracer gas dispersion method. The results showed that the revised modelled LFG generation rates...

  10. Ammonia biofiltration and nitrous oxide generation during the start-up of gas-phase compost biofilters

    Science.gov (United States)

    Maia, Guilherme D. N.; Day V, George B.; Gates, Richard S.; Taraba, Joseph L.

    2012-01-01

    Gas-Phase Biofiltration technology is widely utilized for treating ammonia gas (NH 3) with one of its potential detrimental by-products being nitrous oxide (N 2O), a potent greenhouse gas (100-y radiative forcing 298 times greater than carbon dioxide). The present work was conducted to investigate the relation between NH 3 removal during biofiltration and N 2O generation as a product of incomplete denitrification during the start-up of gas-phase compost biofilters. Four laboratory scale tubular biofilters in up flow mode (20 s residence-time) were studied for 21 days: 3 replicates were subjected to 16 ppm v (0.78 g m -2 h -1) of NH 3 and a statistical control not subjected to NH 3. Ammonia concentration differences between biofilter inlet (Bottom = 16 ppm v) and outlet (Top) and N 2O concentration differences between biofilter outlet (Top) and biofilter inlet (background concentrations at the bottom) were used to determine the extent of the correlation between NH 3 removal and N 2O generation. Correlations with CH 4 and CO 2 were also reported. The high Spearman correlation coefficients for the three replicates ( ρ = -0.845, -0.820, and -0.841, with P ≤ 0.0001 for replications A, B and C, respectively) suggested that availability of nitrate/nitrite owing to NH 3 nitrification favored conditions for N 2O generation as a sub-product of denitrification. The statistical control received no NH 3 inputs and did not generate N 2O. Therefore, the results indicated that the process of NH 3 removal was a trigger for N 2O production. Carbon dioxide and N 2O were moderately correlated. Methane and N 2O were weakly correlated and only for replicate C. No significant correlation was found for the Statistical Control between N 2O and CH 4.

  11. Research, development and demonstration in the design of sanitary landfill to optimize the generation and capture of compressible gas

    Science.gov (United States)

    Nosanov, M. E.; Teeple, F. E.; Buesch, S. C.

    1982-02-01

    The influences of selected factors on the generation and recovery of methane gas from sanitary landfills were investigated. The factors included encapsulation, shredding, air classifying, moisture, and pH. Facilities consisting of six model sanitary landfill cells, each with a capacity of approximately 450 cubic yards of municipal waste, and auxiliary subsystems were constructed. Municipal waste in each cell is contained in a 30-mil thick polyvinly chloride plastic sheeting forming a virtually gas-tight envelope. Two cells were filled with as-collected urban waste, two with shredded waste, and two with shredded and air classified waste, constituting three pairs of cells. One of each pair is a control cell with the other used as an experimental variable. Systems were provided for adding measured amounts of water, removing and recirculating leachate, and for extracting gas and measuring gas flow. During testing, gas production and internal cell characteristics were measured to determine the effects of mechanical processing, moisture content, and leachate pH.

  12. Ecologic Generation on electricity during the transport and distribution of natural gas; Generacion ecologica de energia electrica en los procesos de transporte y de distribucion de gas natural canalizado

    Energy Technology Data Exchange (ETDEWEB)

    Gutierrez, A. M.

    2002-07-01

    The pipeline transmission and distribution of natural gas is carried out at high pressure. However, the pressure has to be reduced to supply the natural gas to local networks. The decrease of the pressure take place in the so-called Regulating an Metering Gas Stations. Currently, it is possible to make use of this gas expansion process to generate electrical energy by means of Gas Expanders. These technologies do not consume chemically natural gas to generate electricity and, consequently do not producer air-pollutants such as CO. SO2, and NOx in comparison with the fuel driven combustion technologies. Environmentally, the Gas Expanders are clean energy devices and should be legally kept in mind as the renewable energies are considered. (Author)

  13. Generation and Measurement of Chlorine Dioxide Gas at Extremely Low Concentrations in a Living Room: Implications for Preventing Airborne Microbial Infectious Diseases.

    Science.gov (United States)

    Ogata, Norio; Sogawa, Koushirou; Takigawa, Yasuhiro; Shibata, Takashi

    2017-01-01

    Preventing respiratory diseases caused by airborne microbes in enclosed spaces is still not satisfactorily controlled. At extremely low concentrations (about 30 parts per billion), chlorine dioxide (ClO2) gas can inactivate airborne microbes and prevent respiratory disease. It has no toxic effect on animals at this level. However, controversies still remain regarding how to measure concentrations of ClO2 gas at such low levels. It is therefore necessary to prove that measured gas concentrations are accurate and reproducible. ClO2 gas was released from a gas generator and its concentration was measured by a novel highly sensitive gas analyzer. We compared its data with those from ion chromatography. We demonstrate that the gas concentrations measured in a room using the gas analyzer are accurate and reproducible after comparing the results with those from ion chromatography. However, the temperature dependence of the gas analyzer was found. Therefore, data correction is required for each temperature at which gas concentration is measured. A theoretical analysis of the gas concentrations predicted by the rate of ClO2 gas released from the ClO2 generator was also performed. Our results advance progress toward using low concentration ClO2 gas to prevent airborne infectious diseases such as influenza. © 2016 S. Karger AG, Basel.

  14. Perspectives for thermoelectric power generation: the potential of natural gas cogeneration; Perspectivas da geracao termeletrica: o potencial da cogeracao a gas natural

    Energy Technology Data Exchange (ETDEWEB)

    Paula, Claudio Paiva de [Comissao de Servicos Publicos de Energia (CSPE), Sao Paulo, (SP) (Brazil)]. E-mail: cpaula@sp.gov.br

    2006-07-01

    The principal objective of this paper is to evaluate the potential for self-production of combined heat and power - CHP generation - in the expansion of the Brazilian electric power supply system. The potential was determined by simulating operation of CHP plants in industries, which had previously used oil derivates to supply process heat as well as of plants for service sectors, which had consumed electricity for air conditioning. The results for a national program with incentives for CHP indicate a potential additional supply of 42,500 MW, composed of CHP systems implemented in industry, sugarcane mills and service sectors. It is estimated the additional consumption of natural gas would reach 33 x 10{sup 9} m{sup 3}/year and it is important to observe that there are new natural gas reserves available in the Santos Basin (near large load centers), with a proven value of 419 x 10{sup 9} m{sup 3}. The final part of the thesis describes the policy incentives which should be implemented so that CHP can make a significant contribution at the national level. The broad growth of CHP would permit better use of natural resources in the expansion of electricity supply, improve the efficiency of electricity use and leverage the penetration of natural gas in the energy market, with favorable impacts on national development. (author)

  15. Production efficiencies of U.S. electric generation plants: Effects of data aggregation and greenhouse gas and renewable energy policy

    Science.gov (United States)

    Lynes, Melissa Kate

    Over the last few decades there has been a shift in electricity production in the U.S. Renewable energy sources are becoming more widely used. In addition, electric generation plants that use coal inputs are more heavily regulated than a couple decades ago. This shift in electricity production was brought on by changes in federal policy -- a desire for electricity produced in the U.S. which led to policies being adopted that encourage the use of renewable energy. The change in production practices due to policies may have led to changes in the productivity of electric generation plants. Multiple studies have examined the most efficient electric generation plants using the data envelopment analysis (DEA) approach. This study builds on past research to answer three questions: 1) Does the level of aggregation of fuel input variables affect the plant efficiency scores and how does the efficiency of renewable energy input compare to nonrenewable energy inputs; 2) Are policies geared toward directly or indirectly reducing greenhouse gas emissions affecting the production efficiencies of greenhouse gas emitting electric generation plants; and 3) Do renewable energy policies and the use of intermittent energy sources (i.e. wind and solar) affect the productivity growth of electric generation plants. All three analysis, presented in three essays, use U.S. plant level data obtained from the Energy Information Administration to answer these questions. The first two essays use DEA to determine the pure technical, overall technical, and scale efficiencies of electric generation plants. The third essay uses DEA within the Malmquist index to assess the change in productivity over time. Results indicate that the level of aggregation does matter particularly for scale efficiency. This implies that valuable information is likely lost when fuel inputs are aggregated together. Policies directly focused on reducing greenhouse gas emissions may improve the production efficiencies of

  16. Studi Ketebalan Elektroda Pada Produksi Gas HHO (Hidrogen Hidrogen Oksigen Oleh Generator Hho Tipe Basah Dengan Katalis NaHCO3 (Natrium Bikarbonat

    Directory of Open Access Journals (Sweden)

    Ihsan Sopandi

    2015-12-01

    Full Text Available Abstrak. Salah satu energi alternatif yang efektif dikembangkan sekarang ini untuk mengganti bahan bakar minyak yaitu hidrogen. Untuk mendapatkan gas hidrogen dapat  dilakukan melalui proses elektrolisis air dengan memecahkan senyawa H2O menjadi gas HHO (Hidrogen Hidrogen Oksigen dengan bantuan listrik arus searah (Direct Current melalui media elektroda berupa plat stainless steel 304. Pada penelitian ini, akan diteliti hasil produksi gas HHO oleh generator HHO tipe basah dengan metode elektrolisa H2O menggunakan variasi ketebalan elektroda jenis stainless steel 304 yaitu 0,8 mm, 1 mm dan 1,2 mm dengan katalis NaHCO3 (Natrium Bikarbonat pada larutan elektrolitnya. Karakteristik yang diketahui meliputi konsumsi daya listrik yang digunakan oleh generator, volume gas yg dihasilkan,  laju produksi gas HHO yang dihasilkan dan efisiensi generator. Hasil penelitian dan pengujian generator HHO tipe basah ini didapatkan generator terbaik pada ketebalan elektroda 1 mm diperoleh data hasil pengujian dengan daya HHO yang digunakan sebesar 59,11 Watt, laju produksi gas HHO yang dihasilkan sebanyak 0,00054 kg/s dan efisiensi generator HHO sebesar 9,42 %.   Study On The  Electrode Thickness In HHO (Hidrogen Hidrogen Oksigen Gas Production By Wet Type HHO Generator With Catalyst NaHCO3 (Natrium Bikarbonat Abstract. One of the alternative energy that effective and currently being developed to replace fossil fuels is hydrogen. To obtain the hydrogen gas can be done through the process of electrolysis of water by breaking the compound H2O into HHO (Hydrogen Hydrogen Oxygen gas by using an electric direct current through the medium of 304 stainless steel plate  as an electrode. This research will be developing and observing HHO gas production process using HHO generator wet type (wet cell through electrolysis H2O with thickness variation of electrode that used 0.8 mm, 1 mm and 1.2 mm of electrode 304 stainless steel plate with NaHCO3 (Nathrium Bicarbonat

  17. In vitro degradation and total gas production of byproducts generated in the biodiesel production chain

    Directory of Open Access Journals (Sweden)

    Raissa Kiara oliveira de Morais

    2015-05-01

    Full Text Available This study aimed to evaluate the in vitro degradation and total gas production of different oil seed press cakes from a biodiesel production chain gas through the use of a semi-automatic technique of gas production in vitro. The treatments consisted of substituting elephant grass in increasing levels, 0%, 30, 50 and 70%, with the byproducts of Gossyypium hirsutum, Ricinus communis, Moringa oleifeira, Jatropha curcas and Helianthus annus. The oil seed press cakes of Moringa oleifeira had the highest rate of in vitro degradation of dry matter compared with other foods but did not result in a higher final volume of gases production. Gossyypium hirsutum, Pinhão manso curcas and Ricinus communis showed a higher in vitro degradability of similar dry matter. The highest total gas production was obtained by the oil seed press cakes of Helianthus annus. The oil seed press cakes of Moringa oleifeira can replace elephant grass up to 70% and therefore reduce both greenhouse gas emissions and energy loss for the animal.

  18. Direct numerical simulation of interfacial wave generation in turbulent gas-liquid flows in horizontal channels

    Science.gov (United States)

    Campbell, Bryce; Hendrickson, Kelli; Liu, Yuming; Subramani, Hariprasad

    2014-11-01

    For gas-liquid flows through pipes and channels, a flow regime (referred to as slug flow) may occur when waves form at the interface of a stratified flow and grow until they bridge the pipe diameter trapping large elongated gas bubbles within the liquid. Slug formation is often accompanied by strong nonlinear wave-wave interactions, wave breaking, and gas entrainment. This work numerically investigates the fully nonlinear interfacial evolution of a two-phase density/viscosity stratified flow through a horizontal channel. A Navier-Stokes flow solver coupled with a conservative volume-of-fluid algorithm is use to carry out high resolution three-dimensional simulations of a turbulent gas flowing over laminar (or turbulent) liquid layers. The analysis of such flows over a range of gas and liquid Reynolds numbers permits the characterization of the interfacial stresses and turbulent flow statistics allowing for the development of physics-based models that approximate the coupled interfacial-turbulent interactions and supplement the heuristic models built into existing industrial slug simulators.

  19. State and residual service life of gas and water pipelines of the first PE generation. Results of a DVGW research project; Integritaet von PE-Gas- und Wasserleitungen der ersten Generation. Ergebnisse eines DVGW-Forschungsvorhabens

    Energy Technology Data Exchange (ETDEWEB)

    Wuest, Juergen; Wenzel, Mirco [SKZ, Wuerzburg (Germany); Scholten, Frans; Wolters, Mannes [Kiwa Gas Technology, Apeldoorn (Netherlands); Heinemann, Juergen; Bockenheimer, Alexander [Technische Univ. Darmstadt (DE). Staatliche Materialpruefungsanstalt Darmstadt (MPA)

    2010-10-15

    Within the scope of a DVGW research project the KIWA, SKZ and MPA Darmstadt research institutes examined the condition and possible residual service life of gas and water pipelines of the first PE generation operating for more than 30 years. The creep rupture curves determined on the old pipelines are very similar to the ones ascertained approx. 40 years ago, allowing an extrapolation over at least another 25 years at service temperature upon expiry of the originally predicted service life of 50 years. Both the gas and water pipelines still show an actively effective thermal stabilization so that an early thermo-oxidative failure is not to be expected even after expiry of the originally estimated service life of 50 years. Nevertheless, public utilities operating gas and water pipelines made of PE of the first generation are recommended to closely observe the damage statistics/damage progression within the scope of the regular inspections of the pipeline network, thus being in a position to recognise ageing phenomena which indicate an end of the service life of the pipeline system in time and perform further examinations. (orig.)

  20. Exergoeconomic analysis of the power generation system using blast furnace and coke oven gas in a Brazilian steel mill

    Energy Technology Data Exchange (ETDEWEB)

    M. Modesto; S.A. Nebra [Federal University of ABC, Santo Andre (Brazil). Center of Engineering

    2009-08-15

    The rational use of energy has become a priority for all industries in Brazil, mainly after the energy rationing in 2001. Methodologies to quantify and improve the performance of plants that consume and generate electricity and thermal energy are being used to reach this goal. Exergoeconomic analysis provides a complete diagnosis of a plant, both in exergetic and in monetary values. This study shows the methodology used to assess the power generation system of the Companhia Siderurgica Tubarao (CST). The current system is based on a regenerative Rankine cycle using two gases from steel production - blast furnace gas (BFG) and coke oven gas (COG) - to generate electric power and occasionally steam for the process. Use of the Theory of Exergetic Cost allowed determination of monetary and exergetic costs. Moreover, indicators such as cost variation, relative cost variation, and exergoeconomic factors were calculated to determine the influence of each component in the make-up of plant costs and to find the best way of decreasing generation costs of energy and process steam.

  1. FUZZY INFERENCE SYSTEM MODELING FOR BED ACTIVE CARBON RE-GENERATION PROCESS (CO2 GAS FACTORY CASE

    Directory of Open Access Journals (Sweden)

    S. Febriana

    2005-01-01

    Full Text Available Bed active carbon is one of the most important materials that had great impact in determining level of impurities in production of CO2 gas. In this particular factory case, there is unavailability of standard duration time of heating and cooling and steam flow rate for the re-generation process of bed active carbon. The paper discusses the fuzzy inference system for modeling of re-generation process of bed active carbon to find the optimum setting parameter. The fuzzy inference system was build using real historical daily processing data. After validation process, surface plot analysis was performed to find the optimum setting. The result of re-generation parameter setting is 9-10 hours of heating process, 4.66-5.32 hours of cooling process, and 1500-2500 kg/hr of steam flow rate.

  2. Technological evaluation of fuel cells using natural gas for distributed power generation; Avaliacao tecnologica da utilizacao de gas natural em celulas a combustivel para geracao distribuida de energia

    Energy Technology Data Exchange (ETDEWEB)

    Brandao, Mauricio O. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia (COPPE). Programa de Engenharia Mecanica; Giannini, Marcio P.; Arouca, Mauricio C. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia (COPPE). Programa de Planejamento Energetico

    2004-07-01

    The search for sustainable and more rational means of power generation motivates the scientific crew to search for more efficient and cleaner systems. Oil dependence becomes from the kind of development that the humanity had and cannot be dismissed. The question is how to use this source in a more intelligent way. Fuel Cells are electrochemical devices that convert into electric energy the chemical energy from oxi-reduction reactions between a fuel and an oxidant. The current fuel used in a Fuel Cell is hydrogen and oxygen is the oxidant. The great advantage of this device is its efficiency, higher than the one achieved with internal combustion engines. Also Fuel Cells are not limited by Carnot's efficiency. This paper is about the implementation of a distributed generation system using Fuel Cells. Technical aspects are approached together with economical and environmental needs. The already existence of Gas pipelines and the grown production of Natural Gas presented by Brazil turns it into a good market for the implementation of this energy source. The evaluation of this paper shows that is technically possible to use NG in Fuel Cells, mostly in South and Southeast regions, applying the distributed generation of energy concept. The most interesting in a strategic manner is that Brazil already have an indication that it's capable of developing this technology, opening a new market tuning with world's new technological developments. Many research centers develop this technology, not only from the cell composition itself, but also manufacturing techniques. (author)

  3. Impact study on the use of biomass-derived fuels in gas turbines for power generation

    Energy Technology Data Exchange (ETDEWEB)

    Moses, C A; Bernstein, H [Southwest Research Inst., San Antonio, TX (United States)

    1994-01-01

    This report evaluates the properties of fuels derived from biomass, both gaseous and liquid, against the fuel requirements of gas turbine systems for gernating electrical power. The report attempts to be quantitative rather than merely qualitative to establish the significant variations in the properties of biomass fuels from those of conventional fuels. Three general categories are covered: performance, durability, and storage and handling.

  4. Sound generating flames of a gas turbine burner observed by laser-induced fluorescence

    Energy Technology Data Exchange (ETDEWEB)

    Hubschmid, W; Inauen, A.; Bombach, R.; Kreutner, W.; Schenker, S.; Zajadatz, M. [Alstom (Switzerland); Motz, C. [Alstom (Switzerland); Haffner, K. [Alstom (Switzerland); Paschereit, C.O. [Alstom (Switzerland)

    2002-03-01

    We performed 2-D OH LIF measurements to investigate the sound emission of a gas turbine combustor. The measured LIF signal was averaged over pulses at constant phase of the dominant acoustic oscillation. A periodic variation in intensity and position of the signal is observed and it is related to the measured sound intensity. (author)

  5. Comparing Statewide Economic Impacts of New Generation from Wind, Coal, and Natural Gas in Arizona, Colorado, and Michigan: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Tegen, S.

    2005-08-01

    With increasing concerns about energy independence, job outsourcing, and risks of global climate change, it is important for policy makers to understand all impacts from their decisions about energy resources. This paper assesses one aspect of the impacts: direct economic effects. The paper compares impacts to states from equivalent new electrical generation from wind, natural gas, and coal. Economic impacts include materials and labor for construction, operations, maintenance, fuel extraction, and fuel transport, as well as project financing, property tax, and landowner revenues. We examine spending on plant construction during construction years, in addition to all other operational expenditures over a 20-year span. Initial results indicate that adding new wind power can be more economically effective than adding new gas or coal power, and that a higher percentage of dollars spent on coal and gas will leave the state. For this report, we interviewed industry representatives and energy experts, in addition to consulting government documents, models, and existing literature. The methodology for this research can be adapted to other contexts for determining economic effects of new power generation in other states and regions.

  6. Comparing Statewide Economic Impacts of New Generation from Wind, Coal, and Natural Gas in Arizona, Colorado, and Michigan

    Energy Technology Data Exchange (ETDEWEB)

    Tegen, S.

    2006-05-01

    With increasing concerns about energy independence, job outsourcing, and risks of global climate change, it is important for policy makers to understand all impacts from their decisions about energy resources. This paper assesses one aspect of the impacts: direct economic effects. The paper compares impacts to states from equivalent new electrical generation from wind, natural gas, and coal. Economic impacts include materials and labor for construction, operations, maintenance, fuel extraction, and fuel transport, as well as project financing, property tax, and landowner revenues. We examine spending on plant construction during construction years, in addition to all other operational expenditures over a 20-year span. Initial results indicate that adding new wind power can be more economically effective than adding new gas or coal power and that a higher percentage of dollars spent on coal and gas will leave the state. For this report, we interviewed industry representatives and energy experts, in addition to consulting government documents, models, and existing literature. The methodology for this research can be adapted to other contexts for determining economic effects of new power generation in other states and regions.

  7. Effect of gas heating on the generation of an ultrashort avalanche electron beam in the pulse-periodic regime

    Science.gov (United States)

    Baksht, E. Kh.; Burachenko, A. G.; Lomaev, M. I.; Sorokin, D. A.; Tarasenko, V. F.

    2015-07-01

    The generation of an ultrashort avalanche electron beam (UAEB) in nitrogen in the pulse-periodic regime is investigated. The gas temperature in the discharge gap of the atmospheric-pressure nitrogen is measured from the intensity distribution of unresolved rotational transitions ( C 3Π u , v' = 0) → ( B 3Π g , v″ = 0) in the nitrogen molecule for an excitation pulse repetition rate of 2 kHz. It is shown that an increase in the UAEB current amplitude in the pulse-periodic regime is due to gas heating by a series of previous pulses, which leads to an increase in the reduced electric field strength as a result of a decrease in the gas density in the zone of the discharge formation. It is found that in the pulse-periodic regime and the formation of the diffuse discharge, the number of electrons in the beam increases by several times for a nitrogen pressure of 9 × 103 Pa. The dependences of the number of electrons in the UAEB on the time of operation of the generator are considered.

  8. Evidence for bacterially generated hydrocarbon gas in Canadian shield and fennoscandian shield rocks

    Science.gov (United States)

    Sherwood Lollar, B.; Frape, S. K.; Fritz, P.; Macko, S. A.; Welhan, J. A.; Blomqvist, R.; Lahermo, P. W.

    1993-12-01

    Hydrocarbon-rich gases found in crystalline rocks on the Canadian and Fennoscandian shields are isotopically and compositionally similar, suggesting that such gases are a characteristic feature of Precambrian Shield rocks. Gases occure in association with saline groundwaters and brines in pressurized "pockets" formed by sealed fracture systems within the host rocks. When released by drilling activities, gas pressures as high as 5000 kPa have been recorded. Typical gas flow rates for individual boreholes range from 0.25 L/min to 4 L/min. The highest concentrations of CH 4 are found in the deepest levels of the boreholes associated with CaNaCl (and NaCaCl) brines. N 2 is the second major component of the gases and with CH 4 accounts for up to 80 to >90 vol%. Higher hydrocarbon (C 2+) concentrations range from C2 = C3) ratios from 10-1000. Isotopically the gases show a wide range of values overall ( σ 13C = -57.5 to -41.1%; σ D = -245 to -470‰ ) but a relatively tight cluster of values within each sampling locality. The Enonkoski Mine methanes are unique with σ 13C values between -65.4 and -67.3‰ and σD values between -297 and -347‰. The shield gases are not readily reconcilable with conventional theories of methanogenesis. The range of C1/(C2 + C3) ratios for the shield gases is too low to be consistent with an entirely bacterial origin. In addition, σD CH 4 values are in general too depleted in the heavy isotope to be produced by thermogenic methanogenesis or by secondary alteration processes such as bacterial oxidation or migration. However, isotopic and compositional evidence indicates that bacterially derived gas can account for a significant component of the gas at all shield sites. Conventional bacterial gas accounts for 75-94 vol% of the occurrences at Enonkoski Mine in Finland. At each of the other shield sites, bacterial gas can account for up to 30-50 vol% of the total gas accumulation. This study and other recent evidence of active

  9. Development and validation of a portable gas phase standard generation and calibration system for volatile organic compounds

    Directory of Open Access Journals (Sweden)

    P. Veres

    2010-06-01

    Full Text Available We report on the development of an accurate, portable, dynamic calibration system for volatile organic compounds (VOCs. The Mobile Organic Carbon Calibration System (MOCCS combines the production of gas-phase VOC standards using permeation or diffusion sources with quantitative total organic carbon (TOC conversion on a palladium surface to CO2 in the presence of oxygen, and the subsequent CO2 measurement. MOCCS was validated using three different comparisons: (1 TOC of high accuracy methane standards compared well to expected concentrations (3% relative error, (2 a gas-phase benzene standard was generated using a permeation source and measured by TOC and gas chromatography mass spectrometry (GC-MS with excellent agreement (<4% relative difference, and (3 total carbon measurement of 4 known gas phase mixtures were performed and compared to a calculated carbon content to agreement within the stated uncertainties of the standards. Measurements from laboratory biomass burning experiments of formic acid by negative-ion proton-transfer chemical-ionization mass spectrometry (NI-PT-CIMS and formaldehyde by proton transfer reaction-mass spectrometry (PTR-MS, both calibrated using MOCCS, were compared to open path Fourier transform infrared spectroscopy (OP-FTIR to validate the MOCCS calibration and were found to compare well (R2 of 0.91 and 0.99, respectively.

  10. Development and validation of a portable gas phase standard generation and calibration system for volatile organic compounds

    Directory of Open Access Journals (Sweden)

    P. Veres

    2010-01-01

    Full Text Available We report on the development of an accurate, portable, dynamic calibration system for volatile organic compounds (VOCs. The Mobile Organic Carbon Calibration System (MOCCS combines the production of gas-phase VOC standards using permeation or diffusion sources with quantitative total organic carbon (TOC conversion on a palladium surface to CO2 in the presence of oxygen, and the subsequent CO2 measurement. MOCCS was validated using three different comparisons: (1 TOC of high accuracy methane standards compared well to expected concentrations (3% relative error, (2 a gas-phase benzene standard was generated using a permeation source and measured by TOC and gas chromatography mass spectrometry (GC-MS with excellent agreement (<4% relative difference, and (3 total carbon measurement of 4 known gas phase mixtures were performed and compared to a calculated carbon content to agreement within the stated uncertainties of the standards. Measurements from laboratory biomass burning experiments of formic acid by negative-ion proton-transfer chemical-ionization mass spectrometry (NI-PT-CIMS and formaldehyde by proton transfer reaction-mass spectrometry (PTR-MS, both calibrated using MOCCS, were compared to open path Fourier transform infrared spectroscopy (OP-FTIR to validate the MOCCS calibration and were found to compare well (R2 of 0.91 and 0.99 respectively.

  11. The effect of exercise and rest duration on the generation of venous gas bubbles at altitude

    Science.gov (United States)

    Dervay, Joseph P.; Powell, Michael R.; Butler, Bruce; Fife, Caroline E.

    2002-01-01

    BACKGROUND: Decompression, as occurs with aviators and astronauts undergoing high altitude operations or with deep-sea divers returning to surface, can cause gas bubbles to form within the organism. Pressure changes to evoke bubble formation in vivo during depressurization are several orders of magnitude less than those required for gas phase formation in vitro in quiescent liquids. Preformed micronuclei acting as "seeds" have been proposed, dating back to the 1940's. These tissue gas micronuclei have been attributed to a minute gas phase located in hydrophobic cavities, surfactant-stabilized microbubbles, or arising from musculoskeletal activity. The lifetimes of these micronuclei have been presumed to be from a few minutes to several weeks. HYPOTHESIS: The greatest incidence of venous gas emboli (VGE) will be detected by precordial Doppler ultrasound with depressurization immediately following lower extremity exercise, with progressively reduced levels of VGE observed as the interval from exercise to depressurization lengthens. METHODS: In a blinded cross-over design, 20 individuals (15 men, 5 women) at sea level exercised by performing knee-bend squats (150 knee flexes over 10 min, 235-kcal x h(-1)) either at the beginning, middle, or end of a 2-h chair-rest period without an oxygen prebreathe. Seated subjects were then depressurized to 6.2 psia (6,706 m or 22,000 ft altitude equivalent) for 120 min with no exercise performed at altitude. RESULTS: Of the 20 subjects with VGE in the pulmonary artery, 10 demonstrated a greater incidence of bubbles with exercise performed just prior to depressurization, compared with decreasing bubble grades and incidence as the interval of rest increased prior to depressurization. No decompression illness was reported. CONCLUSIONS: There is a significant increase in decompression-induced bubble formation at 6.2 psia when lower extremity exercise is performed just prior to depressurization as compared with longer rest intervals

  12. Ionization effects in the generation of wake-fields by ultra-high contrast femtosecond laser pulses in argon gas

    Energy Technology Data Exchange (ETDEWEB)

    Makito, K.; Shin, J.-H. [Graduate School of Engineering, Osaka University, 2-1, Yamadaoka, Suita, Osaka (Japan); Zhidkov, A.; Hosokai, T.; Masuda, S. [Photon Pioneers Center, Osaka University, 2-8, Yamadaoka, Suita, Osaka (Japan); Japan Science and Technology Agency (JST), CREST, 2-8 Yamadaoka, Suita, Osaka (Japan); Kodama, R. [Graduate School of Engineering, Osaka University, 2-1, Yamadaoka, Suita, Osaka (Japan); Photon Pioneers Center, Osaka University, 2-8, Yamadaoka, Suita, Osaka (Japan); Japan Science and Technology Agency (JST), CREST, 2-8 Yamadaoka, Suita, Osaka (Japan)

    2012-10-15

    Difference in mechanisms of wake-field generation and electron self-injection by high contrast femtosecond laser pulses in an initially neutral Argon gas and in pre-ionized plasma without ionization is studied via 2D particle-in-cell simulations including optical ionization of the media. For shorter laser pulses, 40 fs, ionization results only in an increase of the charge of accelerated electrons by factor of {approx}3 with qualitatively the same energy distribution. For longer pulses, 80 fs, a more stable wake field structure is observed in the neutral gas with the maximal energy of the accelerated electrons exceeding that in the fixed density plasma. In higher density Argon, an ionizing laser pulse converts itself to a complex system of solitons at a self-induced, critical density ramp.

  13. Ionization effects in the generation of wake-fields by ultra-high contrast femtosecond laser pulses in argon gas

    Science.gov (United States)

    Makito, K.; Zhidkov, A.; Hosokai, T.; Shin, J.-H.; Masuda, S.; Kodama, R.

    2012-10-01

    Difference in mechanisms of wake-field generation and electron self-injection by high contrast femtosecond laser pulses in an initially neutral Argon gas and in pre-ionized plasma without ionization is studied via 2D particle-in-cell simulations including optical ionization of the media. For shorter laser pulses, 40 fs, ionization results only in an increase of the charge of accelerated electrons by factor of ˜3 with qualitatively the same energy distribution. For longer pulses, 80 fs, a more stable wake field structure is observed in the neutral gas with the maximal energy of the accelerated electrons exceeding that in the fixed density plasma. In higher density Argon, an ionizing laser pulse converts itself to a complex system of solitons at a self-induced, critical density ramp.

  14. Determination of an acoustic reflection coefficient at the inlet of a model gas turbine combustor for power generation

    Science.gov (United States)

    Song, W. J.; Cha, D. J.

    2017-01-01

    A phenomenon that potentially influences the reliability of power generation systems is the presence of thermo-acoustic oscillations in the combustion chamber of a land- based gas turbine. To develop specific measures that prevent the instability, it is essential to predict and/or evaluate the underlying physics of the thermo-acoustics, which requires the acoustic boundary condition at the exit of the burner, that is, at the inlet of the combustor. Here we report a procedure for calculating acoustic reflection coefficients at the burner exit by utilizing two microphone method (TMM) for dynamic pressure signals. The procedure has been verified by comparing its results with reported ones and further successfully employed to determine the acoustic boundary condition of the burner of a partially-premixed model gas turbine combustor.

  15. 浅谈天然气冷热电三联供%Brief Discussion of Gas Co-generation

    Institute of Scientific and Technical Information of China (English)

    王树尧; 施行之; 周宇昊; 丁小川

    2014-01-01

    主要介绍天然气冷热电三联供的种类、技术特点、各项节能性和经济性的评价指标以及主要供能形式。%Distributed energy resource is the utilization of an on-site energy resource to provide electricity and other energy to one or more buildings or facilities. Compared with the traditional central energy supply, distributed energy source can utilize a wide range of power generators including gas cogeneration system, photovoltaic system, wind turbine, etc. It has many benefits, such as compact size, higher efficiency, lower transmission losses and lower emissions. In addition, the sta-bilization of the energy system has been further recognized. The distributed energy resource is concerned increasingly with the advantage of disaster prevention. In this paper, the gas cogeneration system are discussed from many aspects, like char-acters, types, assessment criteria, supply method.

  16. Generation Control of ZnO Nanoparticles Using a Coaxial Gas-Flow Pulse Plasma Ar/O2 Plasma

    Directory of Open Access Journals (Sweden)

    Hiroki Shirahata

    2015-01-01

    Full Text Available Generation of ZnO nanoparticles was investigated using a coaxial gas-flow pulse plasma. We studied how zinc atoms, sputtered from a zinc target, reacted with oxygen in a plasma and/or on a substrate to form ZnO nanoparticles when the discharge parameters, such as applied pulse voltage and gas flow rate, were controlled in an O2/Ar plasma. The formation processes were estimated by SEM, TEM, and EDX. We observed many ZnO nanoparticles deposited on Si substrate. The particle yield and size were found to be controlled by changing the experimental parameters. The diameter of the particles was typically 50–200 nm.

  17. High-Energy, Multicolor Femtosecond Pulses from the Deep Ultraviolet to the Near Infrared Generated in a Hydrogen-Filled Gas Cell and Hollow Fiber

    Directory of Open Access Journals (Sweden)

    Kazuya Motoyoshi

    2014-07-01

    Full Text Available We investigate four-wave mixing in hydrogen gas using a gas cell and a hollow fiber for the generation of high-energy, multicolor femtosecond (fs optical pulses. Both a hydrogen-filled gas cell and hollow fiber lead to the generation of multicolor fs pulses in a broad spectral range from the deep ultraviolet to the near infrared. However, there is a difference in the energy distribution of the multicolor emission between the gas cell and the hollow fiber. The hydrogen-filled gas cell generates visible pulses with higher energies than the pulses created by the hollow fiber. We have generated visible pulses with energies of several tens of microjoules. The hydrogen-filled hollow fiber, on the other hand, generates ultraviolet pulses with energies of a few microjoules, which are higher than the energies of the ultraviolet pulses generated in the gas cell. In both schemes, the spectral width of each emission line supports a transform-limited pulse duration shorter than 15 fs. Four-wave mixing in hydrogen gas therefore can be used for the development of a light source that emits sub-20 fs multicolor pulses in a wavelength region from the deep ultraviolet to the near infrared with microjoule pulse energies.

  18. Dynamic Test Bed Analysis of Gas Energy Balance for a Diesel Exhaust System Fit with a Thermoelectric Generator

    Science.gov (United States)

    Fuc, Pawel; Lijewski, Piotr; Ziolkowski, Andrzej; Dobrzyński, Michal

    2017-02-01

    Analysis of the energy balance for an exhaust system of a diesel engine fit with an automotive thermoelectric generator (ATEG) of our own design has been carried out. A special measurement system and dedicated software were developed to measure the power generated by the modules. The research object was a 1.3-l small diesel engine with power output of 66 kW. The tests were carried out on a dynamic engine test bed that allows reproduction of an actual driving cycle expressed as a function V = f(t), simulating drivetrain (clutch, transmission) operating characteristics, vehicle geometrical parameters, and driver behavior. Measurements of exhaust gas thermodynamic parameters (temperature, pressure, and mass flow) as well as the voltage and current generated by the thermoelectric modules were performed during tests of our own design. Based on the results obtained, the flow of exhaust gas energy in the entire exhaust system was determined along with the ATEG power output. The ideal area of the exhaust system for location of the ATEG was defined to ensure the highest thermal energy recovery efficiency.

  19. Dynamic Test Bed Analysis of Gas Energy Balance for a Diesel Exhaust System Fit with a Thermoelectric Generator

    Science.gov (United States)

    Fuc, Pawel; Lijewski, Piotr; Ziolkowski, Andrzej; Dobrzyński, Michal

    2017-05-01

    Analysis of the energy balance for an exhaust system of a diesel engine fit with an automotive thermoelectric generator (ATEG) of our own design has been carried out. A special measurement system and dedicated software were developed to measure the power generated by the modules. The research object was a 1.3-l small diesel engine with power output of 66 kW. The tests were carried out on a dynamic engine test bed that allows reproduction of an actual driving cycle expressed as a function V = f( t), simulating drivetrain (clutch, transmission) operating characteristics, vehicle geometrical parameters, and driver behavior. Measurements of exhaust gas thermodynamic parameters (temperature, pressure, and mass flow) as well as the voltage and current generated by the thermoelectric modules were performed during tests of our own design. Based on the results obtained, the flow of exhaust gas energy in the entire exhaust system was determined along with the ATEG power output. The ideal area of the exhaust system for location of the ATEG was defined to ensure the highest thermal energy recovery efficiency.

  20. Resonant third harmonic generation of KrF laser in Ar gas

    Energy Technology Data Exchange (ETDEWEB)

    Rakowski, R. [Department of Experimental Physics, University of Szeged, 6720 Szeged, Dóm tér 9 (Hungary); Institute of Optoelectronics, Military University of Technology, Gen. S. Kaliskiego 2, 00–908 Warsaw (Poland); Barna, A. [Department of Experimental Physics, University of Szeged, 6720 Szeged, Dóm tér 9 (Hungary); Wigner Research Centre for Physics, Institute for Particle and Nuclear Physics, EURATOM Association HAS, 1121 Budapest, XII. Konkoly Thege Miklós út 29-33 (Hungary); Suta, T.; Földes, I. B. [Wigner Research Centre for Physics, Institute for Particle and Nuclear Physics, EURATOM Association HAS, 1121 Budapest, XII. Konkoly Thege Miklós út 29-33 (Hungary); Bohus, J.; Szatmári, S. [Department of Experimental Physics, University of Szeged, 6720 Szeged, Dóm tér 9 (Hungary); Mikołajczyk, J.; Bartnik, A.; Fiedorowicz, H. [Institute of Optoelectronics, Military University of Technology, Gen. S. Kaliskiego 2, 00–908 Warsaw (Poland); Verona, C. [Department of Mechanical Engineering, University “Tor Vergata”, Via Orazio Raimondo, 18–00173, Rome (Italy); Verona Rinati, G. [Department of Industrial Engineering, University “Tor Vergata”, Via Orazio Raimondo, 18–00173, Rome (Italy); Margarone, D. [Institute of Physics ASCR, v.v.i. (FZU), ELI-Beamlines Project, 182 21 Prague (Czech Republic); Nowak, T. [Institute of Nuclear Physics, PAN, E. Radzikowskiego 152, 31–342 Cracow (Poland); and others

    2014-12-15

    Investigations of emission of harmonics from argon gas jet irradiated by 700 fs, 5 mJ pulses from a KrF laser are presented. Harmonics conversion was optimized by varying the experimental geometry and the nozzle size. For the collection of the harmonic radiation silicon and solar-blind diamond semiconductor detectors equipped with charge preamplifiers were applied. The possibility of using a single-crystal CVD diamond detector for separate measurement of the 3rd harmonic in the presence of a strong pumping radiation was explored. Our experiments show that the earlier suggested 0.7% conversion efficiency can really be obtained, but only in the case when phase matching is optimized with an elongated gas target length corresponding to the length of coherence.

  1. X-ray Sources Generated from Gas-Filled Laser-Heated Targets

    Energy Technology Data Exchange (ETDEWEB)

    Back, C A; Grun, J; Decker, C D; Davis, J; Laming, J M; Feldman, U; Suter, L J; Landen, O L; Miller, M; Serduke, F; Wuest, C

    2000-06-06

    The X-ray sources in the 4-7 keV energy regime can be produced by laser-irradiating high-Z gas-filled targets with high-powered lasers. A series of experiments have been performed using underdense targets that are supersonically heated with {approx} 35 W of 0.35 {micro}m laser light. These targets were cylindrical Be enclosures that were filled with 1-2 atms of Xe gas. L-shell x-ray emission is emitted from the plasma and detected by Bragg crystal spectrometers and x-ray diodes. Absolute flux measurements show conversion efficiencies of {approx} 10% in the multi-kilovolt x-ray emission. These sources can be used as bright x-ray backlighters or for material testing.

  2. Process for Generation of Hydrogen Gas from Various Feedstocks Using Thermophilic Bacteria

    Energy Technology Data Exchange (ETDEWEB)

    Ooteghem Van, Suellen

    2005-09-13

    A method for producing hydrogen gas is provided comprising selecting a bacteria from the Order Thermotogales, subjecting the bacteria to a feedstock and to a suitable growth environment having an oxygen concentration below the oxygen concentration of water in equilibrium with air; and maintaining the environment at a predetermined pH and at a temperature of at least approximately 45 degrees C. for a time sufficient to allow the bacteria to metabolize the feedstock.

  3. Mechanisms of abnormal overpressure generation in Kuqa foreland thrust belt and their impacts on oil and gas reservoir formation

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Based on overview for mechanism of abnormal overpressure generation in sedimentary basins, an insight discussion is made by the authors for the distribution, features and generation mechanisms of abnormal overpressure in the Kuqa foreland thrust belt. The abnormal overpressure in the Kelasu structure zone west to the Kuqa foreland thrust belt was primarily distributed in Eogene to lower Cretaceous formations; structural compression and structural emplacement as well as the containment of Eogene gyps-salt formation constituted the main mechanisms for the generation of abnormal overpressure. The abnormal overpressure zone in the eastern Yiqikelike structure zone was distributed primarily in lower Jurassic Ahe Group, resulting from hydrocarbon generation as well as structural stress other than from under-compaction. Various distributions and generating mechanisms have different impacts upon the formation of oil and gas reservoirs. K-E reservoir in the Kelasu zone is an allochthonous abnormal overpressure system. One of the conditions for reservoir accumulation is the migration of hydrocarbon (T-J hydrocarbon source rock) along the fault up to K-E reservoir and accumulated into reservoir. And this migration process was controlled by the abnormal overpressure system in K-E reservoir. The confined abnormal overpressure system in the Yiqikelike structure zone constituted the main cause for the poor developing of dissolved porosity in T-J reservoir, resulting in poor physical property of reservoir. The poor physical property of T-J reservoir of Yinan 2 structure was the main cause for the absence of oil accumulation, but the presence of natural gas reservoir in the structure.

  4. Generation of porphyry copper deposits by gas-brine reaction in volcanic arcs

    Science.gov (United States)

    Blundy, J.; Mavrogenes, J.; Tattitch, B.; Sparks, S.; Gilmer, A.

    2015-03-01

    Porphyry copper deposits, that is, copper ore associated with hydrothermal fluids rising from a magma chamber, supply 75% of the world's copper. They are typically associated with intrusions of magma in the crust above subduction zones, indicating a primary role for magmatism in driving mineralization. However, it is not clear that a single, copper-rich magmatic fluid could trigger both copper enrichment and the subsequent precipitation of sulphide ore minerals within a zone of hydrothermally altered rock. Here we draw on observations of modern subduction zone volcanism to propose an alternative process for porphyry copper formation. We suggest that copper enrichment initially involves metalliferous, magmatic hyper-saline liquids, or brines, that exsolve from large, magmatic intrusions assembled in the shallow crust over tens to hundreds of thousands of years. In a subsequent step, sulphide ore precipitation is triggered by the interaction of the accumulated brines with sulphur-rich gases, liberated in short-lived bursts from the underlying mafic magmas. We use high-temperature and high-pressure laboratory experiments to simulate such gas-brine interactions. The experiments yield copper-iron sulphide minerals and hydrogen chloride gas at magmatic temperatures of 700-800 °C, with textural and chemical characteristics that resemble those in porphyry copper deposits. We therefore conclude that porphyry copper ore forms in a two-stage process of brine enrichment followed by gas-induced precipitation.

  5. Climate Change Impacts and Greenhouse Gas Mitigation Effects on U.S. Hydropower Generation

    Science.gov (United States)

    Climate change will have potentially significant effects on hydropower generation due to changes in the magnitude and seasonality of river runoff and increases in reservoir evaporation. These physical impacts will in turn have economic consequences through both producer revenues ...

  6. Climate Change Impacts and Greenhouse Gas Mitigation Effects on U.S. Hydropower Generation

    Science.gov (United States)

    Climate change will have potentially significant effects on hydropower generation due to changes in the magnitude and seasonality of river runoff and increases in reservoir evaporation. These physical impacts will in turn have economic consequences through both producer revenues ...

  7. Evaluation technology for burnup and generated amount of plutonium by measurement of xenon isotopic ratio in dissolver off-gas at reprocessing facility (Joint research)

    OpenAIRE

    岡野 正紀; 久野 剛彦; 高橋 一朗; 白水 秀知; Charlton, W. S.; Wells, C. A.; Hemberger, P. H.; 山田 敬二; 酒井 敏雄

    2006-01-01

    The amount of Pu in the spent fuel was evaluated from Xe isotopic ratio in off-gas in reprocessing facility, is related to burnup. Six batches of dissolver off-gas at spent fuel dissolution process were sampled from the main stack in Tokai Reprocessing Plant during BWR fuel reprocessing campaign. Xenon isotopic ratio was determined with GC/MS. Burnup and generated amount of Pu were evaluated with Noble Gas Environmental Monitoring Application code (NOVA), developed by Los Alamos National Labo...

  8. Deposition of NORM generated by the oil and gas industries in Brazil; Deposicao de NORM gerado pelas industrias de petroleo e gas no Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Schenato, Flavia; Aguiar, Lais A.; Leal, Marco Aurelio; Ruperti Junior, Nerbe, E-mail: schenato@cnen.gov.br [Comissao Nacional de Energia Nuclear (COREJ/CNEN), Rio de Janeiro, RJ (Brazil). Coordenacao de Rejeitos Radioativos

    2013-07-01

    The natural occurring radioactive material (NORM) produced during E and P activities in the petroleum industry presents important implications for the management of solid wastes. The waste management strategy and final disposal policy regarding NORM should meet general radiation protection principles to ensure the long periods during which control may be necessary. The Brazilian Nuclear Energy Commission (CNEN) is responsible for the final destination of the radioactive waste produced in national territory. The Federal Law 10308/2001 establishes standards for the final destination of the radioactive waste providing information to the installation and operation of storage and disposal facilities. The licensee is responsible for the storage facilities, while CNEN is in charge of design, construction and installation of final disposal facilities, being possible to delegate such activities to a third parties, since preserved its full responsibility. The CNEN's Resolution on licensing of radioactive waste deposits, which is in the final approval stage, classifies the wastes generated by the E and P oil and gas industries and suggests two disposal methods to them, near surface and depth repositories, to be defined by safety analysis, but no formal criteria for disposal is really established. The guidelines for the safety analysis set for the licensing process of this class of waste is applied only to the implementation of interim storage facilities but not to repositories. Considering the large volume of NORM generated by the activities of E and P oil and gas industries and the growing demand of production with the exploration of pre-salt oil deposits in Brazil, this paper aims to discuss the development of national guidelines for the disposal of this class of waste to ensure long term safety and acceptability of disposal methods. (author)

  9. Utilization of stable isotopes for characterizing an underground gas generator; Utilisation des isotopes stables pour caracteriser un gazogene souterrain

    Energy Technology Data Exchange (ETDEWEB)

    Pirard, J.P.; Antenucci, D.; Renard, X. [Liege Univ. (Belgium); Letolle, R. [Paris-6 Univ., 75 (France)

    1994-12-31

    The principles of isotopic exchange and isotope ratio result interpretation are first reviewed; then, in the framework of an underground coal gasification project in Belgium, experiments and modelling of the underground gas generator have been carried out: isotopic abundances of carbon, hydrogen and oxygen have been measured in the gasifying agent (O{sub 2}, H{sub 2}O) and in the effluent (CO{sub 2}, CO, H{sub 2}, H{sub 2}O, CH{sub 4}, O{sub 2}, heavy oils and various organic and mineral substances). Gasification kinetics and temperatures have been evaluated and isotope application to thermometry is discussed. 1 fig., 9 refs.

  10. Study of waste generation in the drilling and cementing operations during construction of offshore oil and gas wells

    Directory of Open Access Journals (Sweden)

    Letícia Ferraço de Campos

    2016-12-01

    Full Text Available This literature review aims to present drilling and cementing activities which take place during the construction of offshore oil and gas wells, listing the waste generated in each step. IBAMA, the environmental agency that regulates the activity, allows two disposal options for these wastes: disposal in open sea or treatment followed by disposal on shore. The documentary research applied in this article details the destination options showing that the monitoring required by the environmental agency is a way to track the actual results of the activities described.

  11. Estimation on gas generation and corrosion rates of carbon steel, stainless steel and zircaloy in alkaline solutions under low oxygen condition

    Energy Technology Data Exchange (ETDEWEB)

    Mihara, Morihiro; Honda, Akira [Japan Nuclear Cycle Development Inst., Tokai Works, Tokai, Ibaraki (Japan); Nishimura, Tsutomu; Wada, Ryutaro [Kobe Steel Ltd., Engineering Company, Energy and Nuclear System Center, Osaka (Japan)

    2002-06-01

    Hydrogen gas generated by corrosion of metals in TRU waste repository may degrade the function of the engineered barrier system for nuclide migration. Therefore, estimation of gas generation rates of metals under the repository condition is important. In this study, we obtained gas generation rates of carbon steel, stainless steel and zircaloy in alkaline solutions under low oxygen conditions and evaluated the corrosion rates based on these data in order to compare with the published data. The magnitude of corrosion rates of carbon steel, stainless steel and zircaloy were 10{sup -1} {mu}m/y, 10{sup -2} {mu}m/y and 10{sup -3} {mu}m/y, respectively. These values agreed with the published corrosion rates from gas generation rates by others. (author)

  12. ANALYSIS AND FORECASTING OF CONSEQUENCES PERTAINING TO PRICE CHANGES ON IMPORTED NATURAL GAS BY POWER-GENERATING ENTERPRISES OF THE REPUBLIC OF BELARUS

    Directory of Open Access Journals (Sweden)

    M. P. Коndratiev

    2008-01-01

    Full Text Available The analysis of consequences of price changes for imported natural gas used at enterprises involved in energy generation has been carried out by example of one of Belarusian regional power supply systems.The offers for maximum compensation of economic losses at the expense of price increase for the gas supplied by Russia have been proposed in the paper.

  13. Exergy destruction analysis of a vortices generator in a gas liquid finned tube heat exchanger: an experimental study

    Science.gov (United States)

    Ghazikhani, M.; Khazaee, I.; Monazzam, S. M. S.; Takdehghan, H.

    2016-11-01

    In the present work, the effect of using different shapes of vortices generator (VG) on a gas liquid finned heat exchanger is investigated experimentally with irreversibility analysis. In this project the ambient air with mass flow rates of 0.047-0.072 kg/s is forced across the finned tube heat exchanger. Hot water with constant flow rate of 240 L/h is circulated inside heat exchanger tubes with inlet temperature range of 45-73 °C. The tests are carried out on the flat finned heat exchanger and then repeated on the VG finned heat exchanger. The results show that using the vortex generator can decrease the ratio of air side irreversibility to heat transfer (ASIHR) of the heat exchanger. Also the results show that the IASIHR is >1.05 for all air mass flow rates, which means that ASIHR for the initial heat exchanger is higher than 5 % greater than that of improved heat exchanger.

  14. Effect of a transverse magnetic field on the generation of electron beams in the gas-filled diode

    Science.gov (United States)

    Baksht, E. H.; Burachenko, A. G.; Erofeev, M. V.; Kostyrya, I. D.; Lomaev, M. I.; Rybka, D. V.; Tarasenko, V. F.

    2008-06-01

    The effect of a transverse magnetic field (0.080 and 0.016 T) on generation of an electron beam in the gas-filled diode is experimentally investigated. It is shown that, at voltage U = 25 kV across the diode and a low helium pressure (45 Torr), the transverse magnetic field influences the beam current amplitude behind a foil and its distribution over the foil cross section. At elevated pressures and under the conditions of ultrashort avalanche electron beam formation in helium, nitrogen, and air, the transverse magnetic field (0.080 and 0.016 T) has a minor effect on the amplitude and duration of the beam behind the foil. It is established that, when the voltage of the pulse generator reaches several hundreds of kilovolts, some runaway electrons (including the electrons from the discharge plasma near the cathode) are incident on the side walls of the diode.

  15. Generation of stable and low-divergence 10-MeV quasimonoenergetic electron bunch using argon gas jet

    Directory of Open Access Journals (Sweden)

    M. Mori

    2009-08-01

    Full Text Available The pointing stability and divergence of a quasimonoenergetic electron bunch generated in a self-injected laser-plasma acceleration regime using 4 TW laser is studied. A pointing stability of 2.4 mrad root-mean-square (rms and a beam divergence of 10.6 mrad (rms were obtained using an argon gas-jet target for 50 sequential shots, while these values were degraded by a factor of 3 at the optimum condition using helium. The peak electron energies were 8.5±0.7 and 24.8±3.6  MeV using argon and helium, respectively. The experimental results indicate that the different propagation condition could be generated with the different material, although it is performed with the same irradiation condition.

  16. Generation and mid-IR measurement of a gas-phase to predict security parameters of aviation jet fuel.

    Science.gov (United States)

    Gómez-Carracedo, M P; Andrade, J M; Calviño, M A; Prada, D; Fernández, E; Muniategui, S

    2003-07-27

    The worldwide use of kerosene as aviation jet fuel makes its safety considerations of most importance not only for aircraft security but for the workers' health (chronic and/or acute exposure). As most kerosene risks come from its vapours, this work focuses on predicting seven characteristics (flash point, freezing point, % of aromatics and four distillation points) which assess its potential hazards. Two experimental devices were implemented in order to, first, generate a kerosene vapour phase and, then, to measure its mid-IR spectrum. All the working conditions required to generate the gas phase were optimised either in a univariate or a multivariate (SIMPLEX) approach. Next, multivariate prediction models were deployed using partial least squares regression and it was found that both the average prediction errors and precision parameters were satisfactory, almost always well below the reference figures.

  17. Generation and mid-IR measurement of a gas-phase to predict security parameters of aviation jet fuel

    Energy Technology Data Exchange (ETDEWEB)

    Gomez-Carracedo, M.P.; Andrade, J.M.; Calvino, M.A.; Prada, D.; Fernandez, E.; Muniategui, S. [Department of Analytical Chemistry, University of A Coruna, Campus da Zapateira s/n, E-15071, A Coruna (Spain)

    2003-07-27

    The worldwide use of kerosene as aviation jet fuel makes its safety considerations of most importance not only for aircraft security but for the workers' health (chronic and/or acute exposure). As most kerosene risks come from its vapours, this work focuses on predicting seven characteristics (flash point, freezing point, % of aromatics and four distillation points) which assess its potential hazards. Two experimental devices were implemented in order to, first, generate a kerosene vapour phase and, then, to measure its mid-IR spectrum. All the working conditions required to generate the gas phase were optimised either in a univariate or a multivariate (SIMPLEX) approach. Next, multivariate prediction models were deployed using partial least squares regression and it was found that both the average prediction errors and precision parameters were satisfactory, almost always well below the reference figures.

  18. Effect of the Sequence of the Thermoelectric Generator and the Three-Way Catalytic Converter on Exhaust Gas Conversion Efficiency

    Science.gov (United States)

    Su, Chuqi; Tong, Naiqiang; Xu, Yuman; Chen, Shan; Liu, Xun

    2013-07-01

    The potential for thermoelectric exhaust heat recovery in vehicles has increased with recent improvements in the efficiency of thermoelectric generators (TEGs). The problem with using thermoelectric generators for vehicle applications is whether the device is compatible with the original vehicle exhaust system, which determines the quality of the exhaust gas treatment and the realization of energy conservation and emission reduction. Based on ANSYS CFX simulation analysis of the impact of two positional relationships between the TEG and three-way catalytic converter in the exhaust system on the working efficiency of both elements, it is concluded that the layout with the front three-way catalytic converter has an advantage over the other layout mode under current conditions. New ideas for an improvement program are proposed to provide the basis for further research.

  19. Laboratory Studies of Hydrogen Gas Generation Using the Cobalt Chloride Catalyzed Sodium Borohydride-Water Reaction

    Science.gov (United States)

    2015-07-01

    is a plot of total hydrogen gas as a function of reaction time. This experiment was conducted in the pressure tank at an applied pressure of 13 psig...function of reaction time. This experiment was conducted in the pressure tank at an applied pressure of 50 psig using a H2O:NaBH4 ratio of 4.6:1 and 3.0... pressure tank (McMaster-Carr, part number. 6778K21). The pressure tank has a 185-psig maximum pressure rating at 37.8 ºC and a maximum operating

  20. Potential benefits of a ceramic thermal barrier coating on large power generation gas turbine

    Science.gov (United States)

    Clark, J. S.; Nainiger, J. J.

    1977-01-01

    Thermal barrier coating design option offers benefit in terms of reduced electricity costs when used in utility gas turbines. Options considered include: increased firing temperature, increased component life, reduced cooling air requirements, and increased corrosion resistance (resulting in increased tolerance for dirty fuels). Performance and cost data were obtained. Simple, recuperated and combined cycle applications were considered, and distillate and residual fuels were assumed. The results indicate that thermal barrier coatings could produce large electricity cost savings if these coatings permit turbine operation with residual fuels at distillate-rated firing temperatures. The results also show that increased turbine inlet temperature can result in substantial savings in fuel and capital costs.

  1. Hose Instability and Wake Generation By An Intense Electron Beam in a Self-Ionized Gas

    Energy Technology Data Exchange (ETDEWEB)

    Deng, S.; Barnes, C.D.; Clayton, C.E.; O' Connell, C.; Decker, F.J.; Fonseca, R.A.; Huang, C.; Hogan, M.J.; Iverson, R.; Johnson, D.K.; Joshi, C.; Katsouleas, T.; Krejcik,; Lu, W.; Mori, W.B.; Muggli, P.; Oz, E.; Tsung, F.; Walz, D.; Zhou, M.; /Southern California U. /UCLA /SLAC

    2006-04-12

    The propagation of an intense relativistic electron beam through a gas that is self-ionized by the beam's space charge and wakefields is examined analytically and with 3D particle-in-cell simulations. Instability arises from the coupling between a beam and the offset plasma channel it creates when it is perturbed. The traditional electron hose instability in a preformed plasma is replaced with this slower growth instability depending on the radius of the ionization channel compared to the electron blowout radius. A new regime for hose stable plasma wakefield acceleration is suggested.

  2. Steady Secondary Flows Generated by Periodic Compression and Expansion of an Ideal Gas in a Pulse Tube

    Science.gov (United States)

    Lee, Jeffrey M.

    1999-01-01

    This study establishes a consistent set of differential equations for use in describing the steady secondary flows generated by periodic compression and expansion of an ideal gas in pulse tubes. Also considered is heat transfer between the gas and the tube wall of finite thickness. A small-amplitude series expansion solution in the inverse Strouhal number is proposed for the two-dimensional axisymmetric mass, momentum and energy equations. The anelastic approach applies when shock and acoustic energies are small compared with the energy needed to compress and expand the gas. An analytic solution to the ordered series is obtained in the strong temperature limit where the zeroth-order temperature is constant. The solution shows steady velocities increase linearly for small Valensi number and can be of order I for large Valensi number. A conversion of steady work flow to heat flow occurs whenever temperature, velocity or phase angle gradients are present. Steady enthalpy flow is reduced by heat transfer and is scaled by the Prandtl times Valensi numbers. Particle velocities from a smoke-wire experiment were compared with predictions for the basic and orifice pulse tube configurations. The theory accurately predicted the observed steady streaming.

  3. CdS QDs-chitosan microcapsules with stimuli-responsive property generated by gas-liquid microfluidic technique.

    Science.gov (United States)

    Chen, Yanjun; Yao, Rongyi; Wang, Yifeng; Chen, Ming; Qiu, Tong; Zhang, Chaocan

    2015-01-01

    This article describes a straightforward gas-liquid microfluidic approach to generate uniform-sized chitosan microcapsules containing CdS quantum dots (QDs). CdS QDs are encapsulated into the liquid-core of the microcapsules. The sizes of the microcapsules can be conveniently controlled by gas flow rate. QDs-chitosan microcapsules show good fluorescent stability in water, and exhibit fluorescent responses to chemical environmental stimuli. α-Cyclodextrin (α-CD) causes the microcapsules to deform and even collapse. More interestingly, α-CD induces obvious changes on the fluorescent color of the microcapsules. However, β-cyclodextrin (β-CD) has little influence on the shape and fluorescent color of the microcapsules. Based on the results of scanning electron microscopy, the possible mechanism about the effects of α-CD on the chitosan microcapsules is analyzed. These stimuli-responsive microcapsules are low-cost and easy to be prepared by gas-liquid microfluidic technique, and can be applied as a potential micro-detector to chemicals, such as CDs.

  4. Influence of an Optimized Thermoelectric Generator on the Back Pressure of the Subsequent Exhaust Gas System of a Vehicle

    Science.gov (United States)

    Kühn, Roland; Koeppen, Olaf; Kitte, Jens

    2014-06-01

    Numerous research projects in automotive engineering focus on the industrialization of the thermoelectric generator (TEG). The development and the implementation of thermoelectric systems into the vehicle environment are commonly supported by virtual design activities. In this paper a customized simulation architecture is presented that includes almost all vehicle parts which are influenced by the TEG (overall system simulation) but is nevertheless capable of real-time use. Moreover, an optimized planar TEG with minimum nominal power output of about 580 W and pressure loss at nominal conditions of 10 mbar, synthesized using the overall system simulation, and the overall system simulation itself are used to answer a generally neglected question: What influence does the position of a TEG have on the back pressure of the subsequent exhaust gas system of the vehicle? It is found that the influence of the TEG on the muffler is low, but the catalytic converter is strongly influenced. It is shown that the TEG can reduce the back pressure of an exhaust gas system so much that its overall back pressure is less than the back pressure of a standard exhaust gas system.

  5. Corona pre-ionized gas switches with an increased lifetime for Marx generator of the lightning test complex

    Science.gov (United States)

    Bykov, Yu A.; Krastelev, E. G.

    2017-05-01

    A new design of triggered spark gas switches with an increased operation life and stable dynamic performances for 2.4 MV, 4 MJ Marx generator of the lightning test complex is developed. An operation mode of switches in the test complex is the following: the total voltage - up to 80 kV, the discharge current - up to 50 kA, the charge flowing - up to 3.5 C/pulse, the working gas - dry air at an atmospheric pressure. An increased operating life is achieved by using the torus-shaped electrodes with an increased working area and by the application of a thick disk with a hole, as a trigger electrode, installed between the two torus-shaped electrodes. A short breakdown time delay and a high stability of the breakdown voltage under dynamic conditions are provided by gas pre-ionization in the spark gap by UV-radiation of an additional corona discharge in the axial region of the switch.

  6. Characterization of airborne particles generated from metal active gas welding process.

    Science.gov (United States)

    Guerreiro, C; Gomes, J F; Carvalho, P; Santos, T J G; Miranda, R M; Albuquerque, P

    2014-05-01

    This study is focused on the characterization of particles emitted in the metal active gas welding of carbon steel using mixture of Ar + CO2, and intends to analyze which are the main process parameters that influence the emission itself. It was found that the amount of emitted particles (measured by particle number and alveolar deposited surface area) are clearly dependent on the distance to the welding front and also on the main welding parameters, namely the current intensity and heat input in the welding process. The emission of airborne fine particles seems to increase with the current intensity as fume-formation rate does. When comparing the tested gas mixtures, higher emissions are observed for more oxidant mixtures, that is, mixtures with higher CO2 content, which result in higher arc stability. These mixtures originate higher concentrations of fine particles (as measured by number of particles by cm(3) of air) and higher values of alveolar deposited surface area of particles, thus resulting in a more severe worker's exposure.

  7. Marrying gas power and hydrogen energy: A catalytic system for combining methane conversion and hydrogen generation

    NARCIS (Netherlands)

    Beckers, J.; Gaudillère, C.; Farrusseng, D.; Rothenberg, G.

    2009-01-01

    Ceria-based catalysts are good candidates for integrating methane combustion and hydrogen generation. These new, tuneable catalysts are easily prepared. They are robust inorganic crystalline materials, and perform well at the 400 °C-550 °C range, in some cases even without precious metals. This make

  8. A Safe and Easy Classroom Demonstration of the Generation of Acetylene Gas.

    Science.gov (United States)

    Cox, Marilyn Blagg; Krause, Paul

    1994-01-01

    In this demonstration of the generation and combustion of acetylene, calcium carbide and water are allowed to react in a latex examination glove. Two student volunteers perform the demonstration with instructor guidance. This safe, popular demonstration, originally intended to illustrate the alkyne family of compounds, can be used with a variety…

  9. Optimizing Gas Generator Efficiency in a Forward Operating Base Using an Energy Management System

    Science.gov (United States)

    2013-06-01

    System (EMS) were investigated in this thesis. The EMS provides an interface between power sources, loads, and energy storage elements to form a microgrid ...consumption between the traditional architecture and EMS-enabled microgrid . 14. SUBJECT TERMS Energy management system, forward...operating base (FOB), generators, Microgrid , power electronics 15. NUMBER OF PAGES 99 16. PRICE CODE 17. SECURITY CLASSIFICATION OF REPORT

  10. Soluble Axl is generated by ADAM10-dependent cleavage and associates with Gas6 in mouse serum.

    Science.gov (United States)

    Budagian, Vadim; Bulanova, Elena; Orinska, Zane; Duitman, Erwin; Brandt, Katja; Ludwig, Andreas; Hartmann, Dieter; Lemke, Greg; Saftig, Paul; Bulfone-Paus, Silvia

    2005-11-01

    Axl receptor tyrosine kinase exists as a transmembrane protein and as a soluble molecule. We show that constitutive and phorbol 12-myristate 13-acetate-induced generation of soluble Axl (sAxl) involves the activity of disintegrin-like metalloproteinase 10 (ADAM10). Spontaneous and inducible Axl cleavage was inhibited by the broad-spectrum metalloproteinase inhibitor GM6001 and by hydroxamate GW280264X, which is capable of blocking ADAM10 and ADAM17. Furthermore, murine fibroblasts deficient in ADAM10 expression exhibited a significant reduction in constitutive and inducible Axl shedding, whereas reconstitution of ADAM10 restored sAxl production, suggesting that ADAM10-mediated proteolysis constitutes a major mechanism for sAxl generation in mice. Partially overlapping 14-amino-acid stretch deletions in the membrane-proximal region of Axl dramatically affected sAxl generation, indicating that these regions are involved in regulating the access of the protease to the cleavage site. Importantly, relatively high circulating levels of sAxl are present in mouse sera in a heterocomplex with Axl ligand Gas6. Conversely, two other family members, Tyro3 and Mer, were not detected in mouse sera and conditioned medium. sAxl is constitutively released by murine primary cells such as dendritic and transformed cell lines. Upon immobilization, sAxl promoted cell migration and induced the phosphorylation of Axl and phosphatidylinositol 3-kinase. Thus, ADAM10-mediated generation of sAxl might play an important role in diverse biological processes.

  11. Soluble Axl Is Generated by ADAM10-Dependent Cleavage and Associates with Gas6 in Mouse Serum†

    Science.gov (United States)

    Budagian, Vadim; Bulanova, Elena; Orinska, Zane; Duitman, Erwin; Brandt, Katja; Ludwig, Andreas; Hartmann, Dieter; Lemke, Greg; Saftig, Paul; Bulfone-Paus, Silvia

    2005-01-01

    Axl receptor tyrosine kinase exists as a transmembrane protein and as a soluble molecule. We show that constitutive and phorbol 12-myristate 13-acetate-induced generation of soluble Axl (sAxl) involves the activity of disintegrin-like metalloproteinase 10 (ADAM10). Spontaneous and inducible Axl cleavage was inhibited by the broad-spectrum metalloproteinase inhibitor GM6001 and by hydroxamate GW280264X, which is capable of blocking ADAM10 and ADAM17. Furthermore, murine fibroblasts deficient in ADAM10 expression exhibited a significant reduction in constitutive and inducible Axl shedding, whereas reconstitution of ADAM10 restored sAxl production, suggesting that ADAM10-mediated proteolysis constitutes a major mechanism for sAxl generation in mice. Partially overlapping 14-amino-acid stretch deletions in the membrane-proximal region of Axl dramatically affected sAxl generation, indicating that these regions are involved in regulating the access of the protease to the cleavage site. Importantly, relatively high circulating levels of sAxl are present in mouse sera in a heterocomplex with Axl ligand Gas6. Conversely, two other family members, Tyro3 and Mer, were not detected in mouse sera and conditioned medium. sAxl is constitutively released by murine primary cells such as dendritic and transformed cell lines. Upon immobilization, sAxl promoted cell migration and induced the phosphorylation of Axl and phosphatidylinositol 3-kinase. Thus, ADAM10-mediated generation of sAxl might play an important role in diverse biological processes. PMID:16227584

  12. PM2.5 and ultrafine particulate matter emissions from natural gas-fired turbine for power generation

    Science.gov (United States)

    Brewer, Eli; Li, Yang; Finken, Bob; Quartucy, Greg; Muzio, Lawrence; Baez, Al; Garibay, Mike; Jung, Heejung S.

    2016-04-01

    The generation of electricity from natural gas-fired turbines has increased more than 200% since 2003. In 2007 the South Coast Air Quality Management District (SCAQMD) funded a project to identify control strategies and technologies for PM2.5 and ultrafine emissions from natural gas-fired turbine power plants and test at pilot scale advanced PM2.5 technologies to reduce emissions from these gas turbine-based power plants. This prompted a study of the exhaust from new facilities to better understand air pollution in California. To characterize the emissions from new natural gas turbines, a series of tests were performed on a GE LMS100 gas turbine located at the Walnut Creek Energy Park in August 2013. These tests included particulate matter less than 2.5 μm in diameter (PM2.5) and wet chemical tests for SO2/SO3 and NH3, as well as ultrafine (less than 100 nm in diameter) particulate matter measurements. After turbine exhaust was diluted sevenfold with filtered air, particle concentrations in the 10-300 nm size range were approximately two orders of magnitude higher than those in the ambient air and those in the 2-3 nm size range were up to four orders of magnitude higher. This study also found that ammonia emissions were higher than expected, but in compliance with permit conditions. This was possibly due to an ammonia imbalance entering the catalyst, some flue gas bypassing the catalyst, or not enough catalyst volume. SO3 accounted for an average of 23% of the total sulfur oxides emissions measured. While some of the SO3 is formed in the combustion process, it is likely that the majority formed as the SO2 in the combustion products passed across the oxidizing CO catalyst and SCR catalyst. The 100 MW turbine sampled in this study emitted particle loadings of 3.63E-04 lb/MMBtu based on Methods 5.1/201A and 1.07E-04 lb/MMBtu based on SMPS method, which are similar to those previously measured from turbines in the SCAQMD area (FERCo et al., 2014), however, the turbine

  13. Study of kinetics of gas generation from moistened plutonium dioxide powder

    Energy Technology Data Exchange (ETDEWEB)

    Orlov, V.K.; Glagovsky, E.M.; Karnozov, A.A. [FSUE A. Bochvar Institute of Inorganic Materials (VNIINM), Moscow (Russian Federation)

    2004-07-01

    Our research used weapons-grade plutonium oxide fabricated by oxalate and ammonium precipitation procedures (PuO{sub 2} powder). The content of water adsorbed into the PuO{sub 2} powder was 1 and 3% wt. The process of gas accumulation was investigated by means of the P-V-T method. The pressure of gases in the reaction vessel at the start-up of experiments was less than 1 Torr ({proportional_to}0,02 psia). A glassy reaction vessel was equipped with a U-type mercury manometer. The volume of the reaction vessel was {proportional_to}200 cm{sup 3} (0.21). The experiments were carried out at temperatures of 30, 50 and 100 C during {proportional_to}110 days. (orig.)

  14. Fuel and Greenhouse Gas Emission Reduction Potentials by Appropriate Fuel Switching and Technology Improvement in the Canadian Electricity Generation Sector

    Directory of Open Access Journals (Sweden)

    Farshid Zabihian

    2010-01-01

    Full Text Available Problem statement: In recent years, Greenhouse Gas (GHG emissions and their potential effects on global climate change have been a worldwide concern. According to International Energy Agency (IEA, power generation contributes more than half of the global GHG emissions. Approach: Purpose of this study is to examine GHG emission reduction potentials in the Canadian electricity generation sector through fuel switching and adoption of advanced power generation systems. To achieve this objective, eight different scenarios were introduced. In the first scenario, existing power stations’ fuel was switched to natural gas. Existing power plants were replaced by Natural Gas Combined Cycle (NGCC, Integrated Gasification Combined Cycle (IGCC, Solid Oxide Fuel Cell (SOFC, hybrid SOFC and SOFC-IGCC hybrid power stations in scenario numbers 2 to 6, respectively. In last two scenarios, CO2 capture systems were installed in the existing power plants and in the second scenario, respectively. Results: The results showed that Canada’s GHG emissions can be reduced by 33, 59, 20, 64, 69, 29, 86 and 94% based on the first to eighth scenarios, respectively. On the other hand, the second scenario is the most practical and its technology has already matured and is available. In this scenario by replacing existing power plants by NGCC power plants, Canada can fulfill more than 25% of its 238,000 kt year-1 commitment of GHG emission reduction to the Kyoto Protocol. In addition, the GHG emission reduction potentials for each province and Canada as a whole were presented and compared. Based on the results, Alberta, Ontario and Saskatchewan are the biggest producers of GHG in Canada by emitting 49, 21 and 14% of Canada’s GHG emissions, respectively. Therefore, they have higher potential to reduce GHG emissions. The comparison of the results for different provinces revealed that based on efficiency of electricity generation and consumed fuel distribution; specific scenario

  15. Numerical simulation of gas-liquid two-phase jet flow in air-bubble generator

    Institute of Scientific and Technical Information of China (English)

    陈文义; 王静波; 姜楠; 赵斌; 王振东

    2008-01-01

    Air-bubble generator is the key part of the self-inspiration type swirl flotation machines,whose flow field structure has a great effect on flotation.The multiphase volume of fluid(VOF),standard k-ε turbulent model and the SIMPLE method were chosen to simulate the present model;the first order upwind difference scheme was utilized to perform a discrete solution for momentum equation.The distributing law of the velocity,pressure,turbulent kinetic energy of every section along the flow direction of air-bubble generator was analyzed.The results indicate that the bubbles are heavily broken up in the middle cross section of throat sect and the entrance of diffuser sect along the flow direction,and the turbulent kinetic energy of diffuser sect is larger than the entrance of throat sect and mixing chamber.

  16. Interdependence of the Electricity Generation System and the Natural Gas System and Implications for Energy Security

    Science.gov (United States)

    2013-05-15

    individual backup generators, but recently has begun to examine microgrids , power systems that can purposefully disconnect from the utility grid...and operate in an islanded mode, as a more robust and cost-effective solution to long-term power outages [17, 18]. As microgrid systems become larger... Microgrid study: energy security for DoD installations. Lexington, MA: MIT Lincoln Laboratory. Report number: TR 1164. 100 pp. 18. Anderson, E

  17. Dilution and permeation standards for the generation of NO, NO2 and SO2 calibration gas mixtures

    Science.gov (United States)

    Haerri, H.-P.; Macé, T.; Waldén, J.; Pascale, C.; Niederhauser, B.; Wirtz, K.; Stovcik, V.; Sutour, C.; Couette, J.; Waldén, T.

    2017-03-01

    The evaluation results of the metrological performance of a dilution and a permeation standard for generating SI-traceable calibration gas mixtures of NO, SO2 and NO2 for ambient air measurements are presented. The composition of the in situ produced reference gas mixtures is calculated from the instantaneous values of the input quantities of the generating standards. In a measurement comparison, the calibration and measurement capabilities of five laboratories were evaluated for the three analytes at limiting amount of substance fractions in ambient air between 20 and 150 nmol mol-1. For the upper generated reference values the target relative uncertainties of  ⩽2% (for NO and SO2) and  ⩽3% (for NO2) for evaluating the laboratory results were fulfilled in 12 out of 13 cases. For the analytical results seven out of nine laboratories met the criteria for the upper values for NO and NO2, for SO2 it was one out of four. From the negative degrees of equivalence of all NO2 comparison results it was supposed that the permeation rate of NO2 through the FEP polymer membrane of the permeator was different in air and N2. Subsequent precision permeation measurements with various carrier gases revealed that the permeation rate of NO2 was  ≈0.8% lower in synthetic air compared to N2. With the corrected NO2 reference values for air the degrees of equivalence of the laboratory results were improved and closer to be symmetrically distributed.

  18. Generation of porphyry copper deposits by gas-brine reaction in volcanic arcs

    Science.gov (United States)

    Blundy, Jon; Mavrogenes, John; Tattitch, Brian; Sparks, Steve; Gilmer, Amy

    2014-05-01

    Porphyry copper deposits (PCDs) are characterised by a close spatial and temporal association with small, hypabyssal intrusions of silicic magmas in volcanic arcs. PCD formation requires elevated chlorine and water to concentrate copper in magmatic hypersaline liquids (or brines), and elevated sulphur to precipitate copper-rich sulphides. These twin requirements are hard to reconcile with experimental and petrological evidence that voluminous chlorine-rich, hydrous silicic magmas, of the variety favourable to copper enrichment, lack sufficient sulphur to precipitate directly the requisite quantities of sulphides. These features are, however, consistent with observations of active volcanic arcs whereby PCDs can be viewed as roots of dome volcanoes above shallow reservoirs where silicic magmas accumulate over long time spans. During protracted periods of dormancy metal-enriched dense brines accumulate in and above the silicic reservoir through slow, low-pressure degassing. Meanwhile cogenetic volatile-rich mafic magmas and their exsolved, sulphur and CO2-rich fluids accumulate in deeper reservoirs. Periodic destabilisation of these reservoirs leads to short-lived bursts of volcanism liberating sulphurous gases, which react with the shallow-stored brines to form copper-rich sulphides and acidic vapours. We test this hypothesis with a novel set of 'porphyry in a capsule' experiments designed to simulate low-pressure (1-2 kbar) interaction of basalt-derived, sulphur-rich gases with brine-saturated, copper-bearing, but sulphur-free, granite. Experiments were run at 720-850 ° C in cold-seal apparatus with basaltic andesite, loaded with H2O and S, situated below dacite, loaded with H2O, Cl and Cu. At run conditions both compositions are substantially degassed and crystallized. S-rich gas from the basaltic andesite ascends to react with Cu-rich brines exsolved from the dacite, Our experiments reveal the direct precipitation of copper-sulphide minerals, in vugs and veins

  19. ZTEK`s ultra-high efficiency fuel cell/gas turbine system for distributed generation

    Energy Technology Data Exchange (ETDEWEB)

    Hsu, M.; Nathanson, D. [Ztek Corp., Waltham, MA (United States); Bradshaw, D.T. [Tennessee Valley Authority, Chattanooga, TN (United States)] [and others

    1996-12-31

    Ztek`s Planar Solid Oxide Fuel Cell (SOFC) system has exceptional potential for utility electric power generation because of: simplicity of components construction, capability for low cost manufacturing, efficient recovery of very high quality by-product heat (up to 1000{degrees}C), and system integration simplicity. Utility applications of the Solid Oxide Fuel Cell are varied and include distributed generation units (sub-MW to 30MW capacity), repowering existing power plants (i.e. 30MW to 100MW), and multi-megawatt central power plants. A TVA/EPRI collaboration program involved functional testing of the advanced solid oxide fuel cell stacks and design scale-up for distributed power generation applications. The emphasis is on the engineering design of the utility modules which will be the building blocks for up to megawatt scale power plants. The program has two distinctive subprograms: Verification test on a 1 kW stack and 25kW module for utility demonstration. A 1 kW Planar SOFC stack was successfully operated for 15,000 hours as of December, 1995. Ztek began work on a 25kW SOFC Power System for TVA, which plans to install the 25kW SOFC at a host site for demonstration in 1997. The 25kW module is Ztek`s intended building block for the commercial use of the Planar SOFC. Systems of up to megawatt capacity can be obtained by packaging the modules in 2-dimensional or 3-dimensional arrays.

  20. Gas Chromatography Analysis of Resin and Fatty Acids from Laboratory Generated Bleach Plant Effluents

    Institute of Scientific and Technical Information of China (English)

    Chhaya Sharma; S. Mohanty; S. Kumar; N.J. Rao

    2007-01-01

    Laboratory generated spent bleached liquor from the chlorination, caustic extraction stage of mixed wood kraft pulp processing has been analyzed both qualitatively and quantitatively for various resin & fatty acids by using GC. A number of resin acids,saturated and unsaturated fatty acids, chloro fatty and resin acid have been detected and their concentrations are estimated. The results are compared with results on different agriculture residue/hardwood pulps, which were reported earlier. The concentrations of various compounds detected have also been compared with their reported LC50 values.

  1. Study of hydrogen generation plant coupled to high temperature gas cooled reactor

    Science.gov (United States)

    Brown, Nicholas Robert

    Hydrogen generation using a high temperature nuclear reactor as a thermal driving vector is a promising future option for energy carrier production. In this scheme, the heat from the nuclear reactor drives an endothermic water-splitting plant, via coupling, through an intermediate heat exchanger. While both high temperature nuclear reactors and hydrogen generation plants have high individual degrees of development, study of the coupled plant is lacking. Particularly absent are considerations of the transient behavior of the coupled plant, as well as studies of the safety of the overall plant. The aim of this document is to contribute knowledge to the effort of nuclear hydrogen generation. In particular, this study regards identification of safety issues in the coupled plant and the transient modeling of some leading candidates for implementation in the Nuclear Hydrogen Initiative (NHI). The Sulfur Iodine (SI) and Hybrid Sulfur (HyS) cycles are considered as candidate hydrogen generation schemes. Several thermodynamically derived chemical reaction chamber models are coupled to a well-known reference design of a high temperature nuclear reactor. These chemical reaction chamber models have several dimensions of validation, including detailed steady state flowsheets, integrated loop test data, and bench scale chemical kinetics. Eight unique case studies are performed based on a thorough literature review of possible events. The case studies are: (1) feed flow failure from one section of the chemical plant to another, (2) product flow failure (recycle) within the chemical plant, (3) rupture or explosion within the chemical plant, (4) nuclear reactor helium inlet overcooling due to a process holding tank failure, (5) helium inlet overcooling as an anticipated transient without SCRAM, (6) total failure of the chemical plant, (7) parametric study of the temperature in an individual reaction chamber, and (8) control rod insertion in the nuclear reactor. Various parametric

  2. Updated greenhouse gas and criteria air pollutant emission factors and their probability distribution functions for electricity generating units

    Energy Technology Data Exchange (ETDEWEB)

    Cai, H.; Wang, M.; Elgowainy, A.; Han, J. (Energy Systems)

    2012-07-06

    Greenhouse gas (CO{sub 2}, CH{sub 4} and N{sub 2}O, hereinafter GHG) and criteria air pollutant (CO, NO{sub x}, VOC, PM{sub 10}, PM{sub 2.5} and SO{sub x}, hereinafter CAP) emission factors for various types of power plants burning various fuels with different technologies are important upstream parameters for estimating life-cycle emissions associated with alternative vehicle/fuel systems in the transportation sector, especially electric vehicles. The emission factors are typically expressed in grams of GHG or CAP per kWh of electricity generated by a specific power generation technology. This document describes our approach for updating and expanding GHG and CAP emission factors in the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model developed at Argonne National Laboratory (see Wang 1999 and the GREET website at http://greet.es.anl.gov/main) for various power generation technologies. These GHG and CAP emissions are used to estimate the impact of electricity use by stationary and transportation applications on their fuel-cycle emissions. The electricity generation mixes and the fuel shares attributable to various combustion technologies at the national, regional and state levels are also updated in this document. The energy conversion efficiencies of electric generating units (EGUs) by fuel type and combustion technology are calculated on the basis of the lower heating values of each fuel, to be consistent with the basis used in GREET for transportation fuels. On the basis of the updated GHG and CAP emission factors and energy efficiencies of EGUs, the probability distribution functions (PDFs), which are functions that describe the relative likelihood for the emission factors and energy efficiencies as random variables to take on a given value by the integral of their own probability distributions, are updated using best-fit statistical curves to characterize the uncertainties associated with GHG and CAP emissions in life

  3. Updated greenhouse gas and criteria air pollutant emission factors and their probability distribution functions for electricity generating units

    Energy Technology Data Exchange (ETDEWEB)

    Cai, H.; Wang, M.; Elgowainy, A.; Han, J. (Energy Systems)

    2012-07-06

    Greenhouse gas (CO{sub 2}, CH{sub 4} and N{sub 2}O, hereinafter GHG) and criteria air pollutant (CO, NO{sub x}, VOC, PM{sub 10}, PM{sub 2.5} and SO{sub x}, hereinafter CAP) emission factors for various types of power plants burning various fuels with different technologies are important upstream parameters for estimating life-cycle emissions associated with alternative vehicle/fuel systems in the transportation sector, especially electric vehicles. The emission factors are typically expressed in grams of GHG or CAP per kWh of electricity generated by a specific power generation technology. This document describes our approach for updating and expanding GHG and CAP emission factors in the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model developed at Argonne National Laboratory (see Wang 1999 and the GREET website at http://greet.es.anl.gov/main) for various power generation technologies. These GHG and CAP emissions are used to estimate the impact of electricity use by stationary and transportation applications on their fuel-cycle emissions. The electricity generation mixes and the fuel shares attributable to various combustion technologies at the national, regional and state levels are also updated in this document. The energy conversion efficiencies of electric generating units (EGUs) by fuel type and combustion technology are calculated on the basis of the lower heating values of each fuel, to be consistent with the basis used in GREET for transportation fuels. On the basis of the updated GHG and CAP emission factors and energy efficiencies of EGUs, the probability distribution functions (PDFs), which are functions that describe the relative likelihood for the emission factors and energy efficiencies as random variables to take on a given value by the integral of their own probability distributions, are updated using best-fit statistical curves to characterize the uncertainties associated with GHG and CAP emissions in life

  4. Decomposition of gas-phase diphenylether at 473 K by electron beam generated plasma

    CERN Document Server

    Kim, H H; Kojima, T

    2003-01-01

    Decomposition of gas-phase diphenylether (DPE) in the order of several parts per million by volume (ppmv) was studied as a model compound of dioxin using a flow-type electron-beam reactor at an elevated temperature of 473 K. The ground state oxygen ( sup 3 P) atoms played an important role in the decomposition of DPE resulting in the formation of 1,4-hydroquinone (HQ) as a major ring retaining product. The high yield of hydroquinone indicated that the breakage of ether bond (C-O) is important in the initial step of DPE decomposition. Ring cleavage products were CO and CO sub 2 , and NO sub 2 was also produced from background N sub 2 -O sub 2. The sum of the yields of HQ, CO sub 2 and CO accounts for over 90% of the removed DPE. Hydroxyl radicals (OH) were less important in the dilute DPE decomposition at a high water content, and were mostly consumed by recombination reactions to form hydrogen peroxide. The smaller the initial DPE concentrations, the higher the decomposition efficiency and the lower the yield...

  5. Statistical modelling and optimization of hydrolysis of urea to generate ammonia for flue gas conditioning

    Energy Technology Data Exchange (ETDEWEB)

    Mahalik, K. [Department of Chemical Engineering, Indian Institute of Technology (IIT), Kharagpur, P.O. Kharagpur Technology, West Bengal 721302 (India); Department of Chemical Engineering, Gandhi Institute of Engineering and Technology, Gunupur, Orissa (India); Sahu, J.N., E-mail: jay_sahu@yahoo.co.in [Department of Chemical Engineering, Indian Institute of Technology (IIT), Kharagpur, P.O. Kharagpur Technology, West Bengal 721302 (India); Department of Chemical Engineering, Faculty of Engineering, University of Malaya, Kuala Lumpur 50603 (Malaysia); Patwardhan, Anand V. [Department of Chemical Engineering, Institute of Chemical Technology (ICT), Mumbai 400019 (India); Meikap, B.C. [Department of Chemical Engineering, Indian Institute of Technology (IIT), Kharagpur, P.O. Kharagpur Technology, West Bengal 721302 (India); School of Chemical Engineering, University of KwaZulu-Natal, Howard College Campus, King George V. Avenue, Durban 4041 (South Africa)

    2010-10-15

    The present study is concerned with the technique of producing a relatively small quantity of ammonia which can be used safely in a coal-fired thermal power plant to improve the efficiency of electrostatic precipitator by removing the suspended particulate material mostly fly ash, from the flue gas. In this work hydrolysis of urea has been conducted in a batch reactor at atmospheric pressure to study the different reaction variables such as reaction temperature, initial concentration and stirring speed on the conversion by using design expert software. A 2{sup 3} full factorial central composite design (CCD) has been employed and a quadratic model equation has been developed. The study reveals that conversion increases exponentially with an increase in temperature, stirring speed and feed concentration. However the stirring speed has the greatest effect on the conversion with concentration and temperature exerting least and moderate effect respectively. The values of equilibrium conversion obtained through the developed models are found to agree well with their corresponding experimental counterparts with a satisfactory correlation coefficient of 93%. The developed quadratic model was optimized using quadratic programming to maximize conversion of urea within experimental range studied. The optimum production condition has been found to be at the temperature of 130 {sup o}C, feed concentration of 4.16 mol/l and stirring speed of 400 rpm and the corresponding conversion, 63.242%.

  6. Decomposition of gas-phase diphenylether at 473 K by electron beam generated plasma

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Hyun-Ha [Institute for Environmental Management Technology, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba West, 16-1 Onogawa, Tsukuba, Ibaraki 305-8569 (Japan); Hakoda, Teruyuki [Department of Material Development, Takasaki Radiation Chemistry Research Establishment, Japan Atomic Energy Research Institute (JAERI), 1233 Watanuki, Takasaki, Gunma 370-1292 (Japan); Kojima, Takuji [Department of Material Development, Takasaki Radiation Chemistry Research Establishment, Japan Atomic Energy Research Institute (JAERI), 1233 Watanuki, Takasaki, Gunma 370-1292 (Japan)

    2003-03-07

    Decomposition of gas-phase diphenylether (DPE) in the order of several parts per million by volume (ppmv) was studied as a model compound of dioxin using a flow-type electron-beam reactor at an elevated temperature of 473 K. The ground state oxygen ({sup 3}P) atoms played an important role in the decomposition of DPE resulting in the formation of 1,4-hydroquinone (HQ) as a major ring retaining product. The high yield of hydroquinone indicated that the breakage of ether bond (C-O) is important in the initial step of DPE decomposition. Ring cleavage products were CO and CO{sub 2}, and NO{sub 2} was also produced from background N{sub 2}-O{sub 2}. The sum of the yields of HQ, CO{sub 2} and CO accounts for over 90% of the removed DPE. Hydroxyl radicals (OH) were less important in the dilute DPE decomposition at a high water content, and were mostly consumed by recombination reactions to form hydrogen peroxide. The smaller the initial DPE concentrations, the higher the decomposition efficiency and the lower the yields of primary products. NO scavenges oxygen atoms and decreases the DPE decomposition, while the addition of n-butane causes positive effect on the decomposition of DPE due to the several secondary radicals (HO{sub 2}, alkyl and alkoxy radicals) produced during the decomposition of n-butane.

  7. Current and future greenhouse gas emissions associated with electricity generation in China: implications for electric vehicles.

    Science.gov (United States)

    Shen, Wei; Han, Weijian; Wallington, Timothy J

    2014-06-17

    China's oil imports and greenhouse gas (GHG) emissions have grown rapidly over the past decade. Addressing energy security and GHG emissions is a national priority. Replacing conventional vehicles with electric vehicles (EVs) offers a potential solution to both issues. While the reduction in petroleum use and hence the energy security benefits of switching to EVs are obvious, the GHG benefits are less obvious. We examine the current Chinese electric grid and its evolution and discuss the implications for EVs. China's electric grid will be dominated by coal for the next few decades. In 2015 in Beijing, Shanghai, and Guangzhou, EVs will need to use less than 14, 19, and 23 kWh/100 km, respectively, to match the 183 gCO2/km WTW emissions for energy saving vehicles. In 2020, in Beijing, Shanghai, and Guangzhou EVs will need to use less than 13, 18, and 20 kWh/100 km, respectively, to match the 137 gCO2/km WTW emissions for energy saving vehicles. EVs currently demonstrated in China use 24-32 kWh/100 km. Electrification will reduce petroleum imports; however, it will be very challenging for EVs to contribute to government targets for GHGs emissions reduction.

  8. Generations.

    Science.gov (United States)

    Chambers, David W

    2005-01-01

    Groups naturally promote their strengths and prefer values and rules that give them an identity and an advantage. This shows up as generational tensions across cohorts who share common experiences, including common elders. Dramatic cultural events in America since 1925 can help create an understanding of the differing value structures of the Silents, the Boomers, Gen Xers, and the Millennials. Differences in how these generations see motivation and values, fundamental reality, relations with others, and work are presented, as are some applications of these differences to the dental profession.

  9. Heat Transfer Measurements and Predictions on a Power Generation Gas Turbine Blade

    Science.gov (United States)

    Giel, Paul W.; Bunker, Ronald S.; VanFossen, G. James; Boyle, Robert J.

    2000-01-01

    Detailed heat transfer measurements and predictions are given for a power generation turbine rotor with 129 deg of nominal turning and an axial chord of 137 mm. Data were obtained for a set of four exit Reynolds numbers comprised of the design point of 628,000, -20%, +20%, and +40%. Three ideal exit pressure ratios were examined including the design point of 1.378, -10%, and +10%. Inlet incidence angles of 0 deg and +/-2 deg were also examined. Measurements were made in a linear cascade with highly three-dimensional blade passage flows that resulted from the high flow turning and thick inlet boundary layers. Inlet turbulence was generated with a blown square bar grid. The purpose of the work is the extension of three-dimensional predictive modeling capability for airfoil external heat transfer to engine specific conditions including blade shape, Reynolds numbers, and Mach numbers. Data were obtained by a steady-state technique using a thin-foil heater wrapped around a low thermal conductivity blade. Surface temperatures were measured using calibrated liquid crystals. The results show the effects of strong secondary vortical flows, laminar-to-turbulent transition, and also show good detail in the stagnation region.

  10. Moisture effects on gas-phase biofilter ammonia removal efficiency, nitrous oxide generation, and microbial communities.

    Science.gov (United States)

    Yang, Liangcheng; Kent, Angela D; Wang, Xinlei; Funk, Ted L; Gates, Richard S; Zhang, Yuanhui

    2014-04-30

    We established a four-biofilter setup to examine the effects of moisture content (MC) on biofilter performance, including NH3 removal and N2O generation. We hypothesized that MC increase can improve NH3 removal, stimulate N2O generation and alter the composition and function of microbial communities. We found that NH3 removal efficiency was greatly improved when MC increased from 35 to 55%, but further increasing MC to 63% did not help much; while N2O concentration was low at 35-55% MC, but dramatically increased at 63% MC. Decreasing MC from 63 to 55% restored N2O concentration. Examination of amoA communities using T-RFLP and real-time qPCR showed that the composition and abundance of ammonia oxidizers were not significantly changed in a "moisture disturbance-disturbance relief" process in which MC was increased from 55 to 63% and then reduced to 55%. This observation supported the changes of NH3 removal efficiency. The composition of nosZ community was altered at 63% MC and then was recovered at 55% MC, which indicates resilience to moisture disturbance. The abundance of nosZ community was negatively correlated with moisture content in this process, and the decreased nosZ abundance at 63% MC explained the observation of increased N2O concentration at that condition. Copyright © 2014 Elsevier B.V. All rights reserved.

  11. Subtarget Effect on Laser Plasma Generated by Transversely Excited Atmospheric CO2 Laser at Atmospheric Gas Pressure

    Science.gov (United States)

    Kagawa, Kiichiro; Lie, Tjung Jie; Hedwig, Rinda; Abdulmajid, Syahrun Nur; Suliyanti, Maria Margaretha; Kurniawan, Hendrik

    2000-05-01

    An experimental study has been carried out on the dynamical process taking place in the laser plasma generated by Transversely Excited Atmospheric CO2 laser (100 mJ, 50 ns) irradiation of a soft sample at surrounding helium pressure of 1 atm. It is shown that the presence of a copper subtarget behind the soft sample is crucial in raising the gushing speed of the atoms to the level adequate for the generation of shock wave laser plasma even at atmospheric pressure. It is also found that the time profiles of spatially integrated emission intensity of the target’s atoms and gas atoms exhibit a characteristic dynamical process that consists of successive excitation and cooling stages even at such a high pressure, which is typical of shock wave laser plasma. It is therefore suggested that the generation of the laser plasma at atmospheric pressure is more likely due to the shock wave mechanism than to the widely known breakdown mechanism. Initial spectrochemical analysis of water from the blow off of a boiler system was also carried out, showing a detection limit of as low as 5 ppm for calcium.

  12. Electricity generation cost in isolated system: The complementarities of natural gas and renewables in the Canary Islands

    Energy Technology Data Exchange (ETDEWEB)

    Marrero, Gustavo A. [Facultad de Ciencias Economicas, Campus de Guajara, Universidad de La Laguna, 38071 Santa Cruz de Tenerife (Canary Islands) (Spain); Fundacion de Estudios de Economia Aplicada (FEDEA), C/Jorge Juan 46, 28001 Madrid (Spain); Ramos-Real, Francisco Javier [Facultad de Ciencias Economicas, Campus de Guajara, Universidad de La Laguna, 38071 Santa Cruz de Tenerife (Canary Islands) (Spain); Instituto Universitario de Desarrollo Regional, Facultad de Ciencias Economicas, Campus de Guajara, Universidad de La Laguna, 38071 Santa Cruz de Tenerife (Canary Islands) (Spain)

    2010-12-15

    The Canary Islands offer an example of an isolated electric grid of relative important size within the EU. Due to its peculiarities, the role of renewable energies and their complementarity with fossil fuels offers a solid path to achieving the main energy policy goals of the Islands. The purpose of this paper is to assess the current situation and the energy objectives proposed in the Energy Plan of the Canaries (PECAN, 2006) for the electricity industry, taking into account the average cost and the risk associated with the different alternatives for generating electricity by means of the Mean-Variance Portfolio Theory. Our analysis highlights the inefficiency of the current electricity generating mix in terms of cost, risk and lack of diversification. Shifting toward an efficient system would involve optimizing the use of endogenous energy sources and introducing natural gas to generate electricity. This scenario would mean reducing both cost and risk by almost 30% each, as well as atmospheric CO{sub 2} emissions. Our results agree with the PECAN philosophy. (author)

  13. Gas-phase generations and rearrangement of silathiones, R sub 2 Si=S

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Chong Bok.

    1991-01-08

    Three routes are explored for the generation of silathiones: (1) the retroene elimination of propene from allythiodimethylsilane and 1-allythio-1-hydrido-1,2,2,2-tetramethylsilane; (2) the reaction of silylene, Me{sub 2}Di, with carbon disulfide which is thought to form a transient 3-membered ring with CS{sub 2} and the elimination of carbon disulfide to produce diethylsilathione; and (3) the beta-elimination of bis(trimethylsilythio)dimethylsilane. All these methods are explored in some detail. A second example of a silathione-silylene isomerization was observed in the pyrolysis of 1,1-bis(trimethylsilythio)-1,2,2,2-tetramethyldisilane. 89 refs., 5 figs., 10 tab. (BM)

  14. Sixth harmonic generation of 1064-nm laser in KBBF prism coupling devices under two kinds of gas conditions

    Institute of Scientific and Technical Information of China (English)

    Chengming Li; Yong Zhou; Nan Zong; Zuyan Xu; Xiaoyang Wang; Yong Zhu

    2009-01-01

    The conversion efficiency on the sixth harmonic of 1064 nm in KBe2BO3F2 (KBBF) at different gas pressures in two kinds of gases, helium and nitrogen, is measured and compared. In the both gases, maximum conversion efficiency on the sixth harmonic of 1064 nm in high vacuum is nearly 10% of 355 nm, which is almost four times higher than that in low vacuum. The maximum average output power at 177.3 nm is 670 μW with the repetition rate of 10 Hz and the duration of 20 ps in high vacuum. It indicates that the sixth harmonic generation in high vacuum is more preferable than that in low vacuum.

  15. Magnetic discharge accelerating diode for the gas-filled pulsed neutron generators based on inertial confinement of ions

    Science.gov (United States)

    Kozlovskij, K. I.; Shikanov, A. E.; Vovchenko, E. D.; Shatokhin, V. L.; Isaev, A. A.; Martynenko, A. S.

    2016-09-01

    The paper deals with magnetic discharge diode module with inertial electrostatic ions confinement for the gas-filled pulsed neutron generators. The basis of the design is geometry with the central hollow cathode surrounded by the outer cylindrical anode and electrodes made of permanent magnets. The induction magnitude about 0.1-0.4 T in the central region of the discharge volume ensures the confinement of electrons in the space of hollow (virtual) cathode and leads to space charge compensation of accelerated ions in the centre. The research results of different excitation modes in pulsed high-voltage discharge are presented. The stable form of the volume discharge preserveing the shape and amplitude of the pulse current in the pressure range of 10-3-10-1 Torr and at the accelerating voltage up to 200 kV was observed.

  16. Analysis of two-phase flow instability in helical tube steam generator in high temperature gas cooled reactor

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Yu; Lv, Xuefeng; Wang, Shengfei; Niu, Fenglei; Tian, Li [North China Electric Power Univ., Beijing (Switzerland)

    2012-03-15

    The steam generator composed of multi-helical tubes is used in high temperature gas cooled reactors and two-phase flow instability should be avoided in design. And density-wave oscillation which is mainly due to flow, density and the relationship between the pressure drop delays and feedback effects is one of the two-phase flow instability phenomena easily to occur. Here drift-flux model is used to simulate the performance of the fluid in the secondary side and frequency domain and time domain methods are used to evaluate whether the density-wave oscillation will happen or not. Several operating conditions with nominal power from 15% to 30% are calculated in this paper. The results of the two methods are in accordance, flow instability will occur when power is less than 20% nominal power, which is also according with the result of the experiments well.

  17. Present geotemperature and its suggestion to natural gas generation in Xujiaweizi fault-depression of the northern Songliao Basin

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    According to stastistic of present geotemperatures at the depths of 1000,2000,3000 and 4000 m,respectively in the Xujiaweizi fault-depression of the north Songliao Basin,the result indicates that Xujiaweizi fault-depression falls in the high geotemperature area,with the higher geothermal gradient in the depression layer than that in the fault-depression layer.The geothermal gradient decreases with the increasing of the depth.The thermal conductivity of rock greatly controls the geothermal gradient.The main factors constraining the current geotemperature include thermal configuration of the earth’s crust, deep faults,distribution and abundance of radioelements.The high geotemperature is in favour of generation of deep gas.

  18. Toxicological analysis of 17 autopsy cases of hydrogen sulfide poisoning resulting from the inhalation of intentionally generated hydrogen sulfide gas.

    Science.gov (United States)

    Maebashi, Kyoko; Iwadate, Kimiharu; Sakai, Kentaro; Takatsu, Akihiro; Fukui, Kenji; Aoyagi, Miwako; Ochiai, Eriko; Nagai, Tomonori

    2011-04-15

    Although many cases of fatal hydrogen sulfide poisoning have been reported, in most of these cases, it resulted from the accidental inhalation of hydrogen sulfide gas. In recent years, we experienced 17 autopsy cases of fatal hydrogen sulfide poisoning due to the inhalation of intentionally generated hydrogen sulfide gas. In this study, the concentrations of sulfide and thiosulfate in blood, urine, cerebrospinal fluid and pleural effusion were examined using GC/MS. The sulfide concentrations were blood: 0.11-31.84, urine: 0.01-1.28, cerebrospinal fluid: 0.02-1.59 and pleural effusion: 2.00-8.59 (μg/ml), while the thiosulfate concentrations were blood: 0-0.648, urine: 0-2.669, cerebrospinal fluid: 0.004-0.314 and pleural effusion: 0.019-0.140 (μmol/ml). In previous reports, the blood concentration of thiosulfate was said to be higher than that of sulfide in hydrogen sulfide poisoning cases, although the latter was higher than the former in 8 of the 14 cases examined in this study. These results are believed to be strongly influenced by the atmospheric concentration of hydrogen sulfide the victims were exposed to and the time interval between exposure and death.

  19. Marginal Life-Cycle Greenhouse Gas Emissions of Electricity Generation in Portugal and Implications for Electric Vehicles

    Directory of Open Access Journals (Sweden)

    Rita Garcia

    2016-11-01

    Full Text Available This article assesses marginal greenhouse gas (GHG emissions of electricity generation in Portugal to understand the impact of activities that affect electricity demand in the near term. In particular, it investigates the introduction of electric vehicles (EVs in the Portuguese light-duty fleet considering different displacement and charging scenarios (vehicle technologies displaced, EV charging time. Coal and natural gas were identified as the marginal sources, but their contribution to the margin depended on the hour of the day, time of year, and system load, causing marginal emissions from electricity to vary significantly. Results show that for an electricity system with a high share of non-dispatchable renewable power, such as the Portuguese system, marginal emissions are considerably higher than average emissions. Because of the temporal variability in the marginal electricity supply, the time of charging may have a major influence on the GHG emissions of EVs. Off-peak charging leads to higher GHG emissions than peak charging, due to a higher contribution of coal to the margin. Furthermore, compared to an all-conventional fleet, EV introduction causes an increase in overall GHG emissions in most cases. However, EV effects are very dependent on the time of charging and the assumptions about the displaced technology.

  20. Multi-generation gas-phase oxidation, equilibrium partitioning, and the formation and evolution of secondary organic aerosol

    Directory of Open Access Journals (Sweden)

    C. D. Cappa

    2012-10-01

    Full Text Available A new model of secondary organic aerosol (SOA formation is developed that explicitly takes into account multi-generational oxidation as well as fragmentation of gas-phase compounds, and assumes equilibrium gas-particle partitioning. The model framework requires specification of a limited number of tunable parameters to describe the kinetic evolution of SOA mass, the average oxygen-to-carbon atomic ratio and the mean particle volatility as oxidation proceeds. These parameters describe (1 the relationship between oxygen content and volatility, (2 the probability of fragmentation and (3 the amount of oxygen added per reaction. The time-evolution and absolute value of the simulated SOA mass depends sensitively on all tunable parameters. Of the tunable parameters, the mean O : C is most sensitive to the oxygen/volatility relationship, exhibiting only a weak dependence on the other relationships. The model mean particle O : C produced from a given compound is primarily controlled by the number of carbon atoms comprising the SOA precursor, with some sensitivity to the specified oxygen/volatility relationship. The model is tested against laboratory measurements of time-dependent SOA formation from the photooxidation of α-pinene and n-pentadecane and performs well (after tuning. The model can also accurately simulate the carbon-number dependence of aerosol yields previously observed for oxidation of straight-chain alkanes. This model may provide a generalized framework for the interpretation of laboratory SOA formation experiments in which explicit consideration of multiple-generations of products is required, which is true for all photo-oxidation experiments.

  1. Multi-generation gas-phase oxidation, equilibrium partitioning, and the formation and evolution of secondary organic aerosol

    Directory of Open Access Journals (Sweden)

    C. D. Cappa

    2012-01-01

    Full Text Available A new statistical model of secondary organic aerosol (SOA formation is developed that explicitly takes into account multi-generational oxidation as well as fragmentation of gas-phase compounds. The model framework requires three tunable parameters to describe the kinetic evolution of SOA mass, the average oxygen-to-carbon atomic ratio and the mean particle volatility as oxidation proceeds. These parameters describe (1 the relationship between oxygen content and volatility, (2 the probability of fragmentation and (3 the amount of oxygen added per reaction. The time-evolution and absolute value of the SOA mass depends sensitively on all three tunable parameters. Of the tunable parameters, the mean O:C is most sensitive to the oxygen/volatility relationship, exhibiting only a weak dependence on the other two. The mean particle O:C produced from a given compound is primarily controlled by the number of carbon atoms comprising the SOA precursor. It is found that gas-phase compounds with larger than 11 carbon atoms are unlikely to form SOA with O:C values >0.4, which suggests that so-called "intermediate-volatility" organic compounds (IVOCs and "semi-volatile" organic compounds (SVOCs are not major contributors to the ambient SOA burden when high O:C ratios are observed, especially at short atmospheric times. The model is tested against laboratory measurements of SOA formation from the photooxidation of α-pinene and n-pentadecane and performs well (after tuning. This model may provide a generalized framework for the interpretation of laboratory SOA formation experiments in which explicit consideration of multiple-generations of products is required, which is true for all photo-oxidation experiments.

  2. Development of a Polarizable Force Field For Proteins via Ab Initio Quantum Chemistry: First Generation Model and Gas Phase Tests

    Science.gov (United States)

    KAMINSKI, GEORGE A.; STERN, HARRY A.; BERNE, B. J.; FRIESNER, RICHARD A.; CAO, YIXIANG X.; MURPHY, ROBERT B.; ZHOU, RUHONG; HALGREN, THOMAS A.

    2014-01-01

    We present results of developing a methodology suitable for producing molecular mechanics force fields with explicit treatment of electrostatic polarization for proteins and other molecular system of biological interest. The technique allows simulation of realistic-size systems. Employing high-level ab initio data as a target for fitting allows us to avoid the problem of the lack of detailed experimental data. Using the fast and reliable quantum mechanical methods supplies robust fitting data for the resulting parameter sets. As a result, gas-phase many-body effects for dipeptides are captured within the average RMSD of 0.22 kcal/mol from their ab initio values, and conformational energies for the di- and tetrapeptides are reproduced within the average RMSD of 0.43 kcal/mol from their quantum mechanical counterparts. The latter is achieved in part because of application of a novel torsional fitting technique recently developed in our group, which has already been used to greatly improve accuracy of the peptide conformational equilibrium prediction with the OPLS-AA force field.1 Finally, we have employed the newly developed first-generation model in computing gas-phase conformations of real proteins, as well as in molecular dynamics studies of the systems. The results show that, although the overall accuracy is no better than what can be achieved with a fixed-charges model, the methodology produces robust results, permits reasonably low computational cost, and avoids other computational problems typical for polarizable force fields. It can be considered as a solid basis for building a more accurate and complete second-generation model. PMID:12395421

  3. The Decomposition of Hydrazine in the Gas Phase and over an Iridium Catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Schmidt, Michael W. [Ames Laboratory; Gordon, Mark S. [Ames Laboratory

    2013-09-30

    Hydrazine is an important rocket fuel, used as both a monopropellant and a bipropellant. This paper presents theoretical results to complement the extensive experimental studies of the gas phase and Ir catalyzed decompositions involved in the monopropellant applications of hydrazine. Gas phase electronic structure theory calculations that include electron correlation predict that numerous molecular and free radical reactions occur within the same energy range as the basic free radical pathways: NN bond breaking around 65 kcal/mol and NH bond breaking around 81 kcal/mol. The data suggest that a revision to existing kinetics modeling is desirable, based on the energetics and the new elementary steps reported herein. A supported Ir-6 octahedron model for the Shell 405 Iridium catalyst used in thrusters was developed. Self-Consistent Field and electron correlation calculations (with core potentials and associated basis sets) find a rich chemistry for hydrazine on this catalyst model. The model catalyst provides dramatically lower NN and NH bond cleavage energies and an even smaller barrier to breaking the NH bond by NH2 abstractions. Thus, the low temperature decomposition over the catalyst is interpreted in terms of consecutive NH2 abstractions to produce ammonia and nitrogen. The higher temperature channel, which has hydrogen and nitrogen products, may be due to a mixture of two mechanisms. These two mechanisms are successive NH cleavages with surface H + H recombinations, and the same type of assisted H-2 eliminations found to occur in the gas phase part of this study.

  4. Integration of bio-fired gas turbines in combined heat and power generation; Integrering av biogaseldad gasturbin i kraftvaermeanlaeggning

    Energy Technology Data Exchange (ETDEWEB)

    Genrup, Magnus; Jonshagen, Klas

    2011-01-15

    The aim of the project was to perform a pre-study of the potential to introduce a biofired gas turbine into the pre-heater train of a district heating plant. The incentive for the work is the desire (and political drivers) to increase bio-fuel usage in heat and power production. Sweden has also ratified the EU treaty of having 20 percent renewable in the system before 2020. There are several options at the hand but locally produced biofuels from either gasification or biological processes can be fired in a gas turbine. The size of the gas turbine is limited by shear size of the fuel plant and raw-material transport issues. Today, the maximum electrical efficiency for large-scale advanced plants is on the order of 60 percent. This level is, however, not feasible for smaller size units and one can expect much lower levels. Another possibility is to re-power an existing plant and use the exhaust heat from the gas turbine. Either to produce steam in a heat recovery steam generator, heat boiler combustion air (and variants) or to reduce pre-heater extraction through by-passing the pre-heaters. Previous studies have shown that one could expect very high efficiency levels if the heat could be utilized in the feed water to the boiler. This is typically coupled to the admission pressure level and super-critical plant may have feed water temperature exceeding 300 deg C. The aim of this project was to investigate the potential from introducing this technology into a certain typical Swedish/Nordic turbine based district heating plant. A typical plant has modest admission data (compared to an ultra super-critical plant), hence lower final feed water temperature. A lower final temperature makes it more troublesome to effectively use the exhaust heat from the gas turbine. A further improvement is possible by introducing reheat. There are several practical limitations, where the most severe is the need to extract the full turbine flow and induce it after the reheater. The only

  5. Next Generation TRD for CREAM Using Gas Straw Tubes and Foam Radiators

    Science.gov (United States)

    Malinin, A.; Ahn, H.S.; Fedin, O.; Ganel, O.; Han, J.H.; Kim, C.H.; Kim, K.C.; Lee, M.H.; Lutz, L.; Seo, E.S.; Walpole, P.; Wu, J.; Yoo, J.H.; Yoon, Y.S.; Zinn, S.Y.

    The Cosmic Ray Energetics And Mass (CREAM) experiment is designed to investigate the source, propagation and acceleration mechanism of high energy cosmic-ray nuclei, by directly measuring their energy and charge. Incorporating a transition radiation detector (TRD) provides an energy measurement complementary to the calorimeter, as well as additional track reconstruction capability. The next generation CREAM TRD is designed with 4 mm straw tubes to greatly improve tracking over the previous 20 mm tube design, thereby enhancing charge identification in the silicon charge detector (SCD). Plastic foam provides a weight-efficient radiator that doubles as a mechanical support for the straw layers. This design provides a compact, robust, reliable, low density detector to measure incident nucleus energy for 3 < Z < 30 nuclei in the Lorentz gamma factor range of 102-105. This paper discusses the new TRD design and the low power front end electronics used to achieve the large dynamic range required. Beam test results of a prototype TRD are also reported.

  6. Use of Coke Oven Gas during shutdown period of Direct Reduced Iron Plant for Steam Generation: Experimentation and Optimization

    Directory of Open Access Journals (Sweden)

    Harish C. Dalai

    2015-11-01

    Full Text Available Development of any country is largely based on its magnitude of industrial growth. Steel industries in India took a leading role in the world after mid-sixties. During the last five decades, the steel industries all over the world made considerable developments in new methods for reducing iron ore directly to metallic iron for use as commercial scrap substitute in the manufacture of steels. BSL has been producing steel and other products over last two decades and the above process is used in BSL for one decade. Direct reduction is a process, which extracts high metallic solid iron by removing oxygen from iron ore or any other iron oxides without passing through molten stage, i.e. solid state reduction. The product, so formed is known as directly reduced tron (DRI or Sponge Iron. Due to shortage of raw material or any other problem in DRI sections, the DRI section undergoes a temporary short down. During the shutdown period the equipments tend to be idle. To keep the equipment ready for operation as well as to maintain the plants economy an alternate methodology is used in this research. Various operations are: CO gas from Coke Oven, DRI, Steam Generation, and Power Generation.

  7. HIGH-SPEED, CLINICAL-SCALE MICROFLUIDIC GENERATION OF STABLE PHASE-CHANGE DROPLETS FOR GAS EMBOLOTHERAPY

    Science.gov (United States)

    Bardin, David; Martz, Thomas D.; Sheeran, Paul S.; Shih, Roger; Dayton, Paul A.; Lee, Abraham P.

    2013-01-01

    In this study we report on a microfluidic device and droplet formation regime capable of generating clinical-scale quantities of droplet emulsions suitable in size and functionality for in vivo therapeutics. By increasing the capillary number – based on the flow rate of the continuous outer phase – in our flow-focusing device, we examine three modes of droplet breakup: geometry-controlled, dripping, and jetting. Operation of our device in the dripping regime results in the generation of highly monodisperse liquid perfluoropentane droplets in the appropriate 3–6 µm range at rates exceeding 105 droplets per second. Based on experimental results relating droplet diameter and the ratio of the continuous and dispersed phase flow rates, we derive a power series equation, valid in the dripping regime, to predict droplet size by Dd ≅ 27(QC/QD)−5/12. The volatile droplets in this study are stable for weeks at room temperature yet undergo rapid liquid-to-gas phase transition, and volume expansion, above a uniform thermal activation threshold. The opportunity exists to potentiate locoregional cancer therapies such as thermal ablation and percutaneous ethanol injection using thermal or acoustic vaporization of these monodisperse phase-change droplets to intentionally occlude the vessels of a cancer. PMID:22011845

  8. Optimization of first order decay gas generation model parameters for landfills located in cold semi-arid climates.

    Science.gov (United States)

    Vu, Hoang Lan; Ng, Kelvin Tsun Wai; Richter, Amy

    2017-08-17

    Canada has one of the highest waste generation rates in the world. Because of high land availability, land disposal rates in the province of Saskatchewan are high compared to the rest of the country. In this study, landfill gas data was collected at semi-arid landfills in Regina and Saskatoon, Saskatchewan, and curve fitting was carried out to find optimal k and Lo or DOC values using LandGEM, Afvalzorg Simple, and IPCC first order decay models. Model parameters at each landfill were estimated and compared using default k and Lo or DOC values. Methane generation rates were substantially overestimated using default values (with percentage errors from 55 to 135%). The mean percentage errors for the optimized k and Lo or DOC values ranged from 11.60% to 19.93% at the Regina landfill, and 1.65% to 10.83% at the Saskatoon landfill. Finally, the effect of different iterative methods on the curve fitting process was examined. The residual sum of squares for each model and iterative approaches were similar, with the exception of iterative method 1 for the IPCC model. The default values in these models fail to represent landfills located in cold semi-arid climates. The use of site specific data, provided enough information is available regarding waste mass and composition, can greatly help to improve the accuracy of these first order decay models. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Effect of the carrier gas flow rate on the microstructure evolution and the generation of the charged nanoparticles during silicon chemical vapor deposition.

    Science.gov (United States)

    Youn, Woong-Kyu; Kim, Chan-Soo; Hwang, Nong-Moon

    2013-10-01

    The generation of charged nanoparticles in the gas phase has been continually reported in many chemical vapor deposition processes. Charged silicon nanoparticles in the gas phase were measured using a differential mobility analyzer connected to an atmospheric-pressure chemical vapor deposition reactor at various nitrogen carrier gas flow rates (300-1000 standard cubic centimeter per minute) under typical conditions for silicon deposition at the reactor temperature of 900 degrees C. The carrier gas flow rate affected not only the growth behavior of nanostructures but also the number concentration and size distribution of both negatively and positively charged nanoparticles. As the carrier gas flow rate decreased, the growth behavior changed from films to nanowires, which grew without catalytic metal nanoparticles on a quartz substrate.

  10. Fossil fuel-fired power generation. Case studies of recently constructed coal- and gas-fired plants

    Energy Technology Data Exchange (ETDEWEB)

    Henderson, C. [IEA Clean Coal Centre, London (United Kingdom)

    2007-10-23

    To meet future energy demand growth and replace older or inefficient units, a large number of fossil fuel-fired plants will be required to be built worldwide in the next decade. Yet CO{sub 2} emissions from fossil-fired power generation are a major contributor to climate change. As a result, new plants must be designed and operated at highest efficiency both to reduce CO{sub 2} emissions and to facilitate deployment of CO{sub 2} capture and storage in the future. The series of case studies in this report, which respond to a request to the IEA from the G8 Summit in July 2005, were conducted to illustrate what efficiency is achieved now in modern plants in different parts of the world using different grades of fossil fuels. The plants were selected from different geographical areas, because local factors influence attainable efficiency. The case studies include pulverized coal combustion (PCC) with both subcritical and supercritical (very high pressure and temperature) steam turbine cycles, a review of current and future applications of coal-fuelled integrated gasification combined cycle plants (IGCC), and a case study of a natural gas fired combined cycle plant to facilitate comparisons. The results of these analyses show that the technologies for high efficiency (low CO{sub 2} emission) and very low conventional pollutant emissions (particulates, SO{sub 2}, NOx) from fossil fuel-fired power generation are available now through PCC, IGCC or NGCC at commercially acceptable cost. This report contains comprehensive technical and indicative cost information for modern fossil fuel-fired plants that was previously unavailable. It serves as a valuable sourcebook for policy makers and technical decision makers contemplating decisions to build new fossil fuel-fired power generation plants.

  11. Use of biogas generated from swine manure as preliminary agent in the feasibility construction of natural gas networks; Utilizacao do biogas gerado a partir de dejetos suinos como agente preliminar na viabilizacao da construcao de redes de gas natural

    Energy Technology Data Exchange (ETDEWEB)

    Machado, Antonio Rogerio; Ferraz, Andre; Rocha, Ivan; Azevedo, Jorge; Oshiro, Hugo K.; Konishi, Ricardo; Piazza, Walter; Lehmkuhl, Willian [Companhia de Gas de Santa Catarina (SCGAS), Florianopolis, SC (Brazil)

    2011-12-21

    Santa Catarina state has over 800 km of natural gas distributed along the coast line, however, has an area of 95.700 km{sup 2}. Due to mountainous relief, constructing pipeline that will supply natural gas to remote areas will prove difficult. Supplying gas to remote areas through biogas from pig manure is a feasible alternative to building a gas pipeline to these regions. Using data from the IBGE and by aid of computer programs it was found that Santa Catarina has a potential to generate biogas from 900.000 m{sup 3}/day which are located predominantly in the western region of state. Thus, through the provision of biogas in this region a market that uses natural gas as an energy source can stimulate. As result the pay-back time and the feasibility risk of a network gas project can be reduced. It was found that only in the west there is an energy potential to be shifted to natural gas equivalent of 389.583 m{sup 3}/day and as expected output is estimated to reach 16.728 m{sup 3}/day. This helps anticipate the building of a natural gas network that links the coast with outskirts of the state, while the environmental impact of swine as methane emissions and waste are reduced. (author)

  12. Study on purge gas generated in coke oven gas boilers mixing-firing process%焦炉气锅炉掺烧弛放气探讨

    Institute of Scientific and Technical Information of China (English)

    高翔

    2012-01-01

    It' s not an environmental friendly and economy way to discharged purge gas from methanol plant into the atmosphere. How to recycle methanol purge gas? The treatment of purge gas had been a general concern problem. The problem could be solved by incorpo- rating the decompression purge gas into boilers burning coke oven gas used as burning gas.%甲醇厂弛放气直接排人大气,既对环境产生污染,又无法实现经济价值。通过将弛放气减压掺入焦炉煤气中供锅炉燃烧使用的方法,可以解决弛放气的去向问题。

  13. The RedeGasEnergia and associated technologies to distributed generation, cogeneration and thermoelectric in developing the natural gas in Brazil; A RedeGasEnergia e as tecnologias associadas a geracao distribuida, cogeracao e termeletrica, no desenvolvimento da industria de gas natural no Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Campos, Michel F. [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2004-07-01

    From the PETROBRAS Strategic Plan, where 2015 mission and vision are defined, one search to reach the corporative strategy: 'to lead the natural gas market (NG) and to act in a integrated way in the energy market'. Amongst the corporative politics to guide the business strategies, we will be focusing the new businesses development, having as guide line the annual average growth in the domestic demand of NG, 14.2%. The Investment Plan foresees for the energy and gas area investments around US$ 1.8 billion for the 2003/2007 period, being approximately US$ 500 million destined to the conclusion of the already initiated projects of thermoelectric plants. The Strategic Technological Committee of Energy and Gas (COMEG 2003) defined as technologies of interest for PETROBRAS: renewed energies; sustainable development; NG chemical transformation; NG transport, distribution and storage; distributed generation, co-generation and thermoelectric; production, distribution and use of hydrogen as energy vector; industrial, commercial and residential applications of NG; energy efficiency; automotive systems applications; high power electrical systems and environment. The technology explained in this work, for development of the Brazilian Natural Gas Industry, highly compliant with the NG mass use plan, is the distributed generation, co-generation and thermoelectric and its associated technologies (combustion, IGCC, thermoelectric cycles optimization, gas turbines, boiler/heat recovers, microturbines, fuel cells, combustion engines, renewed energies and cold generation among others). There are several business strategies related to this technology: to play in the electric energy business to assure the NG and derivatives market commercialized by PETROBRAS; to play in the development of alternative sources of energy and; to invest in conservation of energy and renewable energy to add value to the company business. The RedeGasEnergia portfolio has 22 projects in this

  14. Effect of Heat Input on Fume Generation and Joint Properties of Gas Metal Arc Welded Austenitic Stainless Steel%Effect of Heat Input on Fume Generation and Joint Properties of Gas Metal Arc Welded Austenitic Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    K Srinivasan; V Balasubramanian

    2011-01-01

    The effect of heat input on fume and their compositions during gas metal arc welding (GMAW) of AISI 316 stainless steel plates are investigated. Fume generation rate (FGR) and fume percentage were determined by ANSI/AWS F1.2 methods. Particle characterization was performed with SEM-XEDS and XRF analysis to reveal the particle morphology and chemical composition of the fume particles. The SEM analysis reveals the morphology of particles having three distinct shapes namely spherical, irregular, and agglomerated. Spherical particles were the most abundant type of individual particle. All the fume particle size falls in the range of less than 100 nm. Mechanical properties (strength, hardness and toughness) and microstructural analysis of the weld deposits were evaluated. It is found that heat input of 1.15 kJ/mm is beneficial to weld stainless steel by GMAW process due to lower level of welding fume emissions and superior mechanical properties of the joints.

  15. Utilization of high CO2 content formation gas for steam and electricity generation; Aprovechamiento del gas de formacion con alto contenido de CO2 para generacion de vapor y electricidad

    Energy Technology Data Exchange (ETDEWEB)

    Villagomez, Paul; Lamino, Marcelo; Jacome, Jose; Pastor, Santiago [EcuadorTLC, Quito (Ecuador). Grupo PETROBRAS

    2008-07-01

    Ecuador TLC SA, as part of the PETROBRAS Group, respecting its mission to act safe, cost-effectiveness, social and environmental responsibility, currently operates an oil production project in the Ecuatorian Amazon, known as Block 18. In Block 18, the process of gas burning is response for launch approximately 10 MMSCF of the gas associated with 77% CO2 in the environment. For this reason it was built a centralized power generation plants (PGE), of 17.38 MW, taking advantage of the gas with 77% CO2 from boilers to burn it, using it as a source of heat in a combined cycle steam turbines, generating electricity. This project is environmentally efficient with reduced emissions of CO2 and as reducing fuel costs to zero. The results of CO2 reduction is a corporate goal of PETROBRAS and this project will contribute to reducing CO2 emissions by approximately 400,000 Ton over the life of the project.

  16. Development of Natural Gas Fired Combined Cycle Plant for Tri-Generation of Power, Cooling and Clean Water Using Waste Heat Recovery: Techno-Economic Analysis

    OpenAIRE

    Gowtham Mohan; Sujata Dahal; Uday Kumar; Andrew Martin; Hamid Kayal

    2014-01-01

    Tri-generation is one of the most efficient ways for maximizing the utilization of available energy. Utilization of waste heat (flue gases) liberated by the Al-Hamra gas turbine power plant is analyzed in this research work for simultaneous production of: (a) electricity by combining steam rankine cycle using heat recovery steam generator (HRSG); (b) clean water by air gap membrane distillation (AGMD) plant; and (c) cooling by single stage vapor absorption chiller (VAC). The flue gases liber...

  17. Gas composition generated by Eucalyptus firewood gasification in different dimensions; Composicao dos gases gerados pela gasificacao de lenha de Eucalipto em diferentes dimensoes

    Energy Technology Data Exchange (ETDEWEB)

    Zanatta, Fabio L.; Silva, Jadir Nogueira da; Galvarro, Svetlana S.F.; Laureano, Juliane [Universidade Federal de Vicosa (UFV), MG (Brazil). Dept. de Engenharia Agricola], email: fabio.zanatta@ufv.br; Martin, Samuel [Universidade de Brasilia (UNB), DF (Brazil). Dept. de Engenharia Rural

    2011-07-01

    Gasification is a technology that yields an energetic gas from the partial oxidation of organic wastes at high temperatures, by an air factor of 20 to 40% of the stoichiometric amount. The gas generated by gasifier can be used to generate electricity or heat as needed. The gas quality is very dependent of the combustible gases present such as CO, CH{sub 4} and H{sub 2}. On this basis, we investigated the composition of gases generated by an updraft gasifier operating with eucalyptus firewood in four different dimensions to determinate the heating value of gas and evaluate which dimension provides the best results. The experiment was conducted at the Post-Harvest and Renewable Energy Experimental Area of the Agricultural Engineering Department at UFV. It had been used logs of eucalyptus firewood in standard diameter and length of 15, 50 and 100 cm. In addition, chips made of eucalyptus firewood were used with approximate dimensions of 2,5x2,0x0,3 cm. According to conditions under which the experiment was set, the results indicated that chips of eucalyptus firewood have provided more homogeneous conditions in gas composition, thus facilitating use. (author)

  18. A Design on Filter and Cooling for New Gas Generator%一种新型气体发生器的过滤冷却设计

    Institute of Scientific and Technical Information of China (English)

    陈雨; 杨正才; 仵和平; 杨旗; 蔺美君; 何锋彦

    2013-01-01

      为降低气体发生器燃气温度,提高气体清洁度,设计了一种迷宫式过滤冷却机构,相比传统过滤冷却方式,新设计的气体流通路径增加了280%,气体与吸热片接触面积增加了200%。验证试验结果表明迷宫式过滤冷却机构大大提高了气体的清洁度和降温效果。%  Aimed at low temperature and high purity of gas for gas generator, a kind of labyrinth filter and cooling design of gas generator was proposed. Compared to the traditional way, the gas channel length of new design was increased 280%, and the contact area of gas and heat absorption pieces was increased 200%. The verificated test indicated the labyrinth filter and cooling design improves the purity and cooling effect of gas greatly.

  19. Risk Analysis of steam generation at the 5th refinery of South Pars Gas Company using HAZOP procedures

    Directory of Open Access Journals (Sweden)

    Vahid Aziznezhad

    2016-06-01

    Full Text Available considering HSE management program in its strategic framework, and employing integrated methods and tools commonly employed in a chemical process plant, a hazard risk assessments at the steam generation unit was investigated in an Iranian South Pars gas refinery, using PHA-PRO6 software. Recommendations were made to improve safety and prevent possible hazards, taking into account several years of production experiences, past maintenances and reported accidents and near misses. Implicating safety improvements by adopting recommendation yielded from HAZOP studies is expected to reduce system risks and enhance its reliability. The main process hazards identified include water flow fluctuation, pump failures and excess pressure leading to pipe failures, condensation at compensating steam outlets, leakage, substandard maintenance practices, deviations in control of pH, oxygen content, corrosion, condensed water entrapment, were identified as some of the major sources of risks involved. These were considered in constitution of the risk matrix, from which main recommendations and execution time needed are produced. Using the available techniques and standards as well as installing flow control devices could ensure maintaining a normal operating pressure which will in turn, reduce pump stoppage and the unit being out of service due to water shortage. Starting-up procedure for the unit was also revised based on the results of this study. The need for regular (annual inspection of instrumentation controls especially solenoids and check valves were also emphasized. To avoid reverse flow of water into the boilers, installation of a check valve before HV 213 was recommended.

  20. Comparison of the effect of grounding the column wall in gas-solid fluidized beds on electrostatic charge generation

    Energy Technology Data Exchange (ETDEWEB)

    Sowinski, Andrew; Mayne, Antonio; Javed, Bassam; Mehrani, Poupak, E-mail: poupak.mehrani@uottawa.ca [University of Ottawa, Chemical and Biological Engineering Department, 161 Louis Pasteur St., Ottawa, Ontario, K1N 6N5 (Canada)

    2011-06-23

    In gas-solid fluidized beds as particles are fluidized, they continuously come into contact with other particles, as well as the fluidization column wall. This generates electrostatic charges by means of triboelectrification and frictional charging, leading to particle agglomeration, reactor wall fouling, and eventually process downtime and large financial losses. Grounding the fluidization column has been considered as a means of helping electrostatic charge dissipation within fluidized beds; however, in industrial applications despite the process vessels being grounded, the electrostatic problem still persists. This work focused on the effect of fluidization column grounding on particle wall fouling. Experiments were conducted in an atmospheric system consist of a 0.1 m in diameter carbon steel fluidization column. The mass and charge-to-mass ratio (q/m) of the particles that remained adhered to the column wall upon the completion of one hour fluidization period were measured in an electrically isolated and grounded columns to quantitatively determine the amount of reactor wall fouling. Polyethylene particles with different particle size ranges (300- 1000 {mu}m) were fluidized with extra dry air at 1.5 times their respective minimum fluidization velocity (u{sub mf}). Results obtained in the grounded fluidization column were not significantly different from those in the isolated column for all particle size ranges tested where the particles mass collected and q/m and were found to be generally similar.

  1. An energy-efficient process for decomposing perfluorooctanoic and perfluorooctane sulfonic acids using dc plasmas generated within gas bubbles

    Energy Technology Data Exchange (ETDEWEB)

    Yasuoka, K; Sasaki, K; Hayashi, R, E-mail: yasuoka@ee.titech.ac.jp [Department of Electrical and Electronic Engineering, Tokyo Institute of Technology, Ookayama, Tokyo (Japan)

    2011-06-15

    Perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS) are environmentally harmful and persistent substances. Their decomposition was investigated using dc plasmas generated within small gas bubbles in a solution. The plasma characteristics including discharge voltage, voltage drop in the liquid, plasma shape and the emission spectrum were examined with different gases. The decomposition rate and energy efficiency were evaluated by measuring the concentration of fluoride and sulfate ions released from PFOA/PFOS molecules. The concentration of fluoride ions and energy efficiency in the treatment of a PFOS solution were 17.7 mg l{sup -1} (54.8% of the initial amount of fluorine atoms) and 26 mg kWh{sup -1}, respectively, after 240 min of operation. The addition of scavengers of hydroxyl radicals and hydrated electrons showed little effect on the decomposition. The decomposition processes were analyzed with an assumption that positive species reacted with PFOA/PFOS molecules at the boundary of the plasma-solution surface. This type of plasma showed a much higher decomposition energy efficiency compared with energy efficiencies reported in other studies.

  2. Three-Dimensional Measurements of Fuel Distribution in High-Pressure, High- Temperature, Next-Generation Aviation Gas Turbine Combustors

    Science.gov (United States)

    Hicks, Yolanda R.; Locke, Randy J.; Anderson, Robert C.; Zaller, Michelle M.

    1998-01-01

    In our world-class, optically accessible combustion facility at the NASA Lewis Research Center, we have developed the unique capability of making three-dimensional fuel distribution measurements of aviation gas turbine fuel injectors at actual operating conditions. These measurements are made in situ at the actual operating temperatures and pressures using the JP-grade fuels of candidate next-generation advanced aircraft engines for the High Speed Research (HSR) and Advanced Subsonics Technology (AST) programs. The inlet temperature and pressure ranges used thus far are 300 to 1100 F and 80 to 250 psia. With these data, we can obtain the injector spray angles, the fuel mass distributions of liquid and vapor, the degree of fuel vaporization, and the degree to which fuel has been consumed. The data have been used to diagnose the performance of injectors designed both in-house and by major U.S. engine manufacturers and to design new fuel injectors with overall engine performance goals of increased efficiency and reduced environmental impact. Mie scattering is used to visualize the liquid fuel, and laser-induced fluorescence is used to visualize both liquid and fuel vapor.

  3. SPALAX new generation: New process design for a more efficient xenon production system for the CTBT noble gas network.

    Science.gov (United States)

    Topin, Sylvain; Greau, Claire; Deliere, Ludovic; Hovesepian, Alexandre; Taffary, Thomas; Le Petit, Gilbert; Douysset, Guilhem; Moulin, Christophe

    2015-11-01

    The SPALAX (Système de Prélèvement Automatique en Ligne avec l'Analyse du Xénon) is one of the systems used in the International Monitoring System of the Comprehensive Nuclear Test Ban Treaty (CTBT) to detect radioactive xenon releases following a nuclear explosion. Approximately 10 years after the industrialization of the first system, the CEA has developed the SPALAX New Generation, SPALAX-NG, with the aim of increasing the global sensitivity and reducing the overall size of the system. A major breakthrough has been obtained by improving the sampling stage and the purification/concentration stage. The sampling stage evolution consists of increasing the sampling capacity and improving the gas treatment efficiency across new permeation membranes, leading to an increase in the xenon production capacity by a factor of 2-3. The purification/concentration stage evolution consists of using a new adsorbent Ag@ZSM-5 (or Ag-PZ2-25) with a much larger xenon retention capacity than activated charcoal, enabling a significant reduction in the overall size of this stage. The energy consumption of the system is similar to that of the current SPALAX system. The SPALAX-NG process is able to produce samples of almost 7 cm(3) of xenon every 12 h, making it the most productive xenon process among the IMS systems.

  4. Enhanced hydroxyl radical generation in the combined ozonation and electrolysis process using carbon nanotubes containing gas diffusion cathode.

    Science.gov (United States)

    Wu, Donghai; Lu, Guanghua; Zhang, Ran; Lin, Qiuhong; Yan, Zhenhua; Liu, Jianchao; Li, Yi

    2015-10-01

    Combination of ozone together with electrolysis (ozone-electrolysis) is a promising wastewater treatment technology. This work investigated the potential use of carbon nanotube (CNT)-based gas diffusion cathode (GDC) for ozone-electrolysis process employing hydroxyl radicals (·OH) production as an indicator. Compared with conventional active carbon (AC)-polytetrafluoroethylene (PTFE) and carbon black (CB)-PTFE cathodes, the production of ·OH in the coupled process was improved using CNTs-PTFE GDC. Appropriate addition of acetylene black (AB) and pore-forming agent Na2SO4 could enhance the efficiency of CNTs-PTFE GDC. The optimum GDC composition was obtained by response surface methodology (RSM) analysis and was determined as CNTs 31.2 wt%, PTFE 60.6 wt%, AB 3.5 wt%, and Na2SO4 4.7 wt%. Moreover, the optimized CNT-based GDC exhibited much more effective than traditional Ti and graphite cathodes in Acid Orange 7 (AO7) mineralization and possessed the desirable stability without performance decay after ten times reaction. The comparison tests revealed that peroxone reaction was the main pathway of ·OH production in the present system, and cathodic reduction of ozone could significantly promote ·OH generation. These results suggested that application of CNT-based GDC offers considerable advantages in ozone-electrolysis of organic wastewater.

  5. Electric power self generation in residential condominium; Auto geracao de energia eletrica em condominios residenciais utilizando biogas de esgoto/gas natural

    Energy Technology Data Exchange (ETDEWEB)

    Guardabassi, Patricia; Pires, Rodrigo Goncalves; Coelho, Suani Teixeira; Velazquez, Silvia M.S.G. [Centro Nacional de Referencia em Biomassa (CENBIO), Sao Paulo, SP (Brazil)

    2002-07-01

    This paper studies the technical and economical feasibility of using biomass (biogas from sewage treatment) associated to natural gas for decentralized electric power generation in a residential condominium in the Sao Paulo city. This model can may be applied in other regions of the country.

  6. Development of the ceramic natural gas engine co-generation system; Developpement d'un systeme de cogeneration a moteur a gaz naturel en ceramique

    Energy Technology Data Exchange (ETDEWEB)

    Ikeda, K.; Sakamoto, H.; Iwamoto, H. [Japan Gas Association (Japan)

    2000-07-01

    The Japan Gas Association is developing ceramic gas engines (CGE) for use in co-generation systems driven by natural gas. Ceramic gas engines are lightweight, compact power units with high power generation efficiency, enabling a high level of waste heat utilization from the hot exhaust. Although the Japanese office building market has the potential of becoming a major market for co-generation systems, the heat-electricity ratio of such facilities (with a significantly large electricity demand in comparison to the heat demand) renders conventional co-generation systems unsuitable for application to office buildings. The newly-developed engine system should allow this previously unexplored market to be exploited. Development of the engine system was initiated in 1993, and has now entered its seventh year. This report describes the current development status of the CGE technology. Development of the engine was funded as an auxiliary project by the Ministry of International Trade. and Industry (MITI) from 1993 through 1999, after which activities will continue within the private sector. (authors)

  7. Investigating Friction as a Main Source of Entropy Generation in the Expansion of Confined Gas in a Piston-and-Cylinder Device

    Science.gov (United States)

    Kang, Dun-Yen; Liou, Kai-Hsin; Chang, Wei-Lun

    2015-01-01

    The expansion or compression of gas confined in a piston-and-cylinder device is a classic working example used for illustrating the First and Second Laws of Thermodynamics. The balance of energy and entropy enables the estimation of a number of thermodynamic properties. The entropy generation (also called entropy production) resulting from this…

  8. The effect of the operation modes of a gas discharge low-pressure amalgam lamp on the intensity of generation of 185 nm UV vacuum radiation

    Energy Technology Data Exchange (ETDEWEB)

    Vasilyak, L. M., E-mail: vasilyak@ihed.ras.ru [Russian Academy of Sciences, Joint Institute of High Temperatures (Russian Federation); Drozdov, L. A., E-mail: lit@npo.lit.ru; Kostyuchenko, S. V.; Sokolov, D. V. [ZAO LIT (Russian Federation); Kudryavtsev, N. N.; Sobur, D. A., E-mail: soburda@gmail.com [Moscow Institute for Physics and Technology (Russian Federation)

    2011-12-15

    The effect of the discharge current, mercury vapor pressure, and the inert gas pressure on the intensity and efficiency of the 185 nm line generation are considered. The spectra of the UV radiation (vacuum ultraviolet) transmission by protective coatings from the oxides of rare earth metals and aluminum are investigated.

  9. Studi Eksperimen Pengaruh Pencampuran Gas Hidrogen Dari Generator HHO Tipe Kering Dengan Bahan Bakar Kerosene Pada Distribusi Temperatur Nyala Api Kompor Tekan Blowtorch

    Directory of Open Access Journals (Sweden)

    Brillyano Agni Pradipta

    2013-09-01

    Full Text Available Gas hidrogen mempunyai nilai kalor yang dapat dimanfaatkan untuk menambah energi  pada berbagai keperluan pembakaran, bahkan dapat mengurangi penggunaan bahan bakar konvensional yang digunakan saat ini. Blowtorch kerosin digunakan sebagai alat uji. Pengujian dilakukan dengan menggabungkan bahan bakar kerosin dan gas hidrogen dalam HHO yang dihasilkan dari generator HHO tipe kering dengan plat SS316L berukuran 16mmx16mm sebanyak 15 plat sebagai elektroda dan larutan elektrolit KOH dilengkapi Pulse Width Modulation (PWM sebagai alat pengontrol generator HHO dengan duty cycle 25%, 50%, dan 75%. Penggabungan bahan bakar dilakukan secara difusi menggunakan ejector. Hasil yang didapatkan bahwa efisiensi unjuk kerja generator HHO tertinggi pada duty cycle 25%, yaitu sebesar 54,32% dan efisiensi terendah pada generator HHO tanpa PWM, yaitu sebesar 13,2%. Temperatur api yang dihasilkan gabungan kerosin dan gas HHO lebih panas dari pembakaran kerosin saja. Gabungan daya bahan bakar yang dihasilkan gas HHO sebesar 16,5W dan daya yang dikeluarkan kerosin murni sebesar 25,77kW, menaikkan temperatur api lebih dari 100oC dari temperatur api hasil pembakaran kerosin murni .

  10. Determination of the Quantitative Characteristics of the Engine of a Household Power Plant when Using Generator Gas as an Alternative Fuel

    Directory of Open Access Journals (Sweden)

    Plotnikov S. A.

    2017-08-01

    Full Text Available The relevance of the study is due to the need to study the feasibility of replacing traditional fuel with alternative types (generator gas when using a household power plant. The purpose of the study is to obtain the value of a small-displacement engine GG-2700 with a working volume of 1563 cm3 when it works on commercial fuel (gasoline and generator gas. For this purpose, the authors developed an experimental setup on the basis of a small-sized household power station with fixation of variable parameters on a personal computer and a graphical representation of the measurement results. The records of the indicator diagrams allowed determining the burning time of various fuels. As a result, for the first time, there were obtained quantitative indicators of fuel efficiency and toxicity of exhaust gases of the small-displacement engine GG-2700 with a working volume of 1563 cm3 when using commercial fuel (gasoline and generator gas. The analysis of the data showed an increase in the specific consumption of generator gas in comparison with gasoline from 34.6% to 50.4% and a decrease in the content of toxic components in the exhaust gases: carbon monoxide (CO – in 1.05 ... 1.25 times, hydrocarbons (CxHy - in 1,1 ... 1,39 times, nitrogen oxides (NOх - in 3,9 ... 5,7 times. The obtained results prove the expediency of using generator gas as an alternative fuel for the engine of a household power plant.

  11. Rule-based programming and strategies for automated generation of detailed kinetic models for gas phase combustion of polycyclic hydrocarbon molecules; Programmation par regles et strategies pour la generation automatique de mecanismes de combustion d'hydrocarbures polycycliques

    Energy Technology Data Exchange (ETDEWEB)

    Ibanescu, L.

    2004-06-15

    The primary objective of this thesis is to explore the approach of using rule-based systems and strategies, for a complex problem of chemical kinetic: the automated generation of reaction mechanisms. The chemical reactions are naturally expressed as conditional rewriting rules. The control of the chemical reactions chaining is easy to describe using a strategies language, such as the one of the ELAN system, developed in the Protheo team. The thesis presents the basic concepts of the chemical kinetics, the chemical and computational problems related to the conception and validation of a reaction mechanism, and gives a general structure for the generator of reaction mechanisms called GasEI. Our research focuses on the primary mechanism generator. We give solutions for encoding the chemical species, the reactions and their chaining, and we present the prototype developed in ELAN. The representation of the chemical species uses the notion of molecular graphs, encoded by a term structure called GasEI terms. The chemical reactions are expressed by rewriting rules on molecular graphs, encoded by a set of conditional rewriting rules on GasEI terms. The strategies language of the ELAN system is used to express the reactions chaining in the primary mechanism generator. This approach is illustrated by coding ten generic reactions of the oxidizing pyrolysis. Qualitative chemical validations of the prototype show that our approach gives, for acyclic molecules, the same results as the existing mechanism generators, and for polycyclic molecules produces original results.

  12. Increased Use of Natural Gas for Power Generation in the U.S. and the Resulting Reductions in Emissions of CO2, NOx and SO2

    Science.gov (United States)

    De Gouw, J. A.; Parrish, D. D.; Trainer, M.

    2013-12-01

    Over the past decades, natural gas has increasingly replaced coal as a fuel for electrical power generation in the U.S. As a result, there have been significant reductions in the emissions of carbon dioxide (CO2), nitrogen oxides (NOx) and sulfur dioxide (SO2). Power plant emissions are continuously measured at the stack using continuous emissions monitoring systems (CEMS) required by the EPA. Previous studies using airborne measurements have shown these CEMS measurements to be accurate. Here, we use annual emissions since 1995 from all point sources included in the CEMS database to quantify the changes in CO2, NOx and SO2 emissions that have resulted from the changing use of fuels and technologies for power generation. In 1997, 83% of electrical power in the CEMS database was generated from coal-fired power plants. In 2012, the contribution from coal had decreased to 59%, and natural gas contributed 34% of the electrical power. Natural gas-fired power plants, in particular those equipped with combined cycle technology, emit less than 50% of CO2 per kWh produced compared to coal-fired plants. As a result of the increased use of natural gas, total CO2 emissions from U.S. power plants have decreased since 2008. In addition, natural gas-fired power plants emit less NOx and far less SO2 per kWh produced than coal-fired power plants. The increased use of natural gas has therefore led to significant emissions reductions of NOx and SO2 in addition to those obtained from the implementation of emissions control systems on coal-fired power plants. The increased use of natural gas for power generation has led to significant reductions in CO2 emissions as well as improvements in U.S. air quality. We will illustrate these points with examples from airborne measurements made using the NOAA WP-3D aircraft in the Southeastern U.S. in 2013 as part of the NOAA Southeast Nexus (SENEX) study. The emissions reductions from U.S. power plants due to the increased use of natural gas will

  13. A new portable generator to dynamically produce SI-traceable reference gas mixtures for VOCs and water vapour at atmospheric concentration

    Science.gov (United States)

    Guillevic, Myriam; Pascale, Céline; Ackermann, Andreas; Leuenberger, Daiana; Niederhauser, Bernhard

    2016-04-01

    In the framework of the KEY-VOCs and AtmoChem-ECV projects, we are currently developing new facilities to dynamically generate reference gas mixtures for a variety of reactive compounds, at concentrations measured in the atmosphere and in a SI-traceable way (i.e. the amount of substance fraction in mole per mole is traceable to SI-units). Here we present the realisation of such standards for water vapour in the range 1-10 μmol/mol and for volatile organic compounds (VOCs) such as limonene, alpha-pinene, MVK, MEK, in the nmol/mol range. The matrix gas can be nitrogen or synthetic air. Further development in gas purification techniques could make possible to use purified atmospheric air as carrier gas. The method is based on permeation and dynamic dilution: one permeator containing a pure substance (either water, limonene, MVK, MEK or α-pinene) is kept into a permeation chamber with a constant gas flow. The mass loss is precisely calibrated using a magnetic suspension balance. The carrier gas is purified beforehand from the compounds of interest to the required level, using commercially available purification cartridges. This primary mixture is then diluted to reach the required amount of substance fraction. All flows are piloted by mass flow controllers which makes the production process flexible and easily adaptable to generate the required concentration. All parts in contact with the gas mixture are passivated using coated surfaces, to reduce adsorption/desorption processes as much as possible. Two setups are currently developed: one already built and fixed in our laboratory in Bern as well as a portable generator that is still under construction and that could be used anywhere in the field. The permeation chamber of the portable generator has multiple individual cells allowing the generation of mixtures up to 5 different components if needed. Moreover the presented technique can be adapted and applied to a large variety of molecules (e.g., NO2, BTEX, CFCs

  14. Effect of water injection and off scheduling of variable inlet guide vanes, gas generator speed and power turbine nozzle angle on the performance of an automotive gas turbine engine

    Science.gov (United States)

    Warren, E. L.

    1980-01-01

    The Chrysler/ERDA baseline automotive gas turbine engine was used to experimentally determine the power augmentation and emissions reductions achieved by the effect of variable compressor and power engine geometry, water injection downstream of the compressor, and increases in gas generator speed. Results were dependent on the mode of variable geometry utilization. Over 20 percent increase in power was accompanied by over 5 percent reduction in SFC. A fuel economy improvement of at least 6 percent was estimated for a vehicle with a 75 kW (100 hp) engine which could be augmented to 89 kW (120 hp) relative to an 89 Kw (120 hp) unaugmented engine.

  15. In vitro degradation and total gas production of byproducts generated in the biodiesel production chain

    OpenAIRE

    2015-01-01

    This study aimed to evaluate the in vitro degradation and total gas production of different oil seed press cakes from a biodiesel production chain gas through the use of a semi-automatic technique of gas production in vitro. The treatments consisted of substituting elephant grass in increasing levels, 0%, 30, 50 and 70%, with the byproducts of Gossyypium hirsutum, Ricinus communis, Moringa oleifeira, Jatropha curcas and Helianthus annus. The oil seed press cakes of Moringa oleifeira had the h...

  16. Development of Natural Gas Fired Combined Cycle Plant for Tri-Generation of Power, Cooling and Clean Water Using Waste Heat Recovery: Techno-Economic Analysis

    Directory of Open Access Journals (Sweden)

    Gowtham Mohan

    2014-10-01

    Full Text Available Tri-generation is one of the most efficient ways for maximizing the utilization of available energy. Utilization of waste heat (flue gases liberated by the Al-Hamra gas turbine power plant is analyzed in this research work for simultaneous production of: (a electricity by combining steam rankine cycle using heat recovery steam generator (HRSG; (b clean water by air gap membrane distillation (AGMD plant; and (c cooling by single stage vapor absorption chiller (VAC. The flue gases liberated from the gas turbine power cycle is the prime source of energy for the tri-generation system. The heat recovered from condenser of steam cycle and excess heat available at the flue gases are utilized to drive cooling and desalination cycles which are optimized based on the cooling energy demands of the villas. Economic and environmental benefits of the tri-generation system in terms of cost savings and reduction in carbon emissions were analyzed. Energy efficiency of about 82%–85% is achieved by the tri-generation system compared to 50%–52% for combined cycles. Normalized carbon dioxide emission per MW·h is reduced by 51.5% by implementation of waste heat recovery tri-generation system. The tri-generation system has a payback period of 1.38 years with cumulative net present value of $66 million over the project life time.

  17. An on-demand gas segmented flow generator with high spatiotemporal resolution for in vivo analysis of neuronal response in C. elegans.

    Science.gov (United States)

    Hu, Liang; Ge, Anle; Wang, Xixian; Wang, Shanshan; Gao, Yue; Feng, Xiaojun; Du, Wei; Liu, Bi-Feng

    2016-10-05

    Studies of chemo-sensing in C. elegans to fluctuating gaseous cues are limited due to the lack of a method of precise gas control. In this paper, we describe a microfluidic-based on-demand gas segmented flow generator for performing fluctuating gaseous stimulations to worms. This highly versatile and programmable micro-device integrated with pneumatic valves for flexible and stable gas flow control and worm immobilization enabled us to examine the temporal features of neuronal response to multiple gas pulses with sub-second precision. As a result, we demonstrated the capability of the micro-device to generate repetitive gaseous chemical pulses with varying durations. By characterizing intracellular calcium signals, we showed that URX sensory neurons were sensitive to O2 pulses with duration of more than 0.5 s. Furthermore, URX neuronal adaptation and recovery in response to gaseous chemical pulses were investigated by varying the durations and intervals. The developed microfluidic system is shown to be a useful tool for studying the dynamics of in vivo gas-evoked neuronal responses and revealing the temporal properties of environmental stimulations.

  18. Factorial study on influence of gas generating agent and diluent on drug release kinetics of clopidogrel bisulfate floating tablets

    Directory of Open Access Journals (Sweden)

    K R Koteswara Rao

    2013-01-01

    Full Text Available The purpose of present work was to formulate and characterize a floating drug delivery system for Clopidogrel bisulphate to improve bioavailability and to minimize the side-effects of the drug such as gastric bleeding and drug resistance development. Clopidogrel floating tablets were prepared by direct compression technique by the use of xanthan gum at different concentrations (20%, 25% and 30% w/w. Sodium bicarbonate (15% w/w and microcrystalline cellulose (MCC (30% w/w were used as gas generating agent and diluent respectively. The effects of sodium bicarbonate and MCC on the drug release kinetics and floating properties were investigated. A 2 2 factorial design was applied systematically to optimized formulation. The percentage amount of sodium bicarbonate (X 1 and percentage amount of MCC (X 2 were selected as independent variables. The drug release rate constant (K and time required for 85% drug dissolution (T85 was selected as dependent variables. Factorial design revealed that the percentage amount of sodium bicarbonate and MCC had insignificant effect on drug release kinetics (K, T85 within the chosen levels and a high level of sodium bicarbonate (X 1 and the low level of MCC (X 2 favor the preparation of clopidogrel floating tablets. All the Clopidogrel floating formulations followed first order kinetics, Higuchi drug release kinetics with diffusion as the dominant mechanism of drug release. As per Korsmeyer-Peppas equation, the release exponent "n" ranged 0.455-0.654 indicating that drug release from all the formulations was by non-fickian diffusion mechanism.

  19. Gas uptake in a three-generation model geometry during steady expiration: comparison of axisymmetric and three-dimensional models.

    Science.gov (United States)

    Madasu, Srinath; Borhan, Ali; Ultman, James

    2007-03-01

    Mass transfer coefficients were predicted and compared for uptake of a formaldehyde-air gas system using an axisymmetric single path model (ASPM) and a three-dimensional computational fluid dynamics model (CFDM) in three-generation model geometry at steady expiratory flow. The flow and concentration fields in the ASPM were solved using Galerkin's finite-element method and in the CFDM using a commercial finite-element software, FIDAP. Numerical results were compared for two different inlet flow rates, wall mass transfer coefficients, and bifurcation angles. The mass transfer coefficients variation with bifurcation unit from the ASPM and CFDM compared qualitatively and quantitatively closely at all flows and lower wall mass transfer coefficients for both 40 degrees and 70 degrees bifurcation angles. However, at higher wall mass transfer coefficients, quantitatively they were within 40% for both the bifurcation angles. Also, at higher flow and wall mass transfer coefficients, they were off qualitatively for a 70 degrees bifurcation angle although the uptake compared qualitatively. This is due to the normalization of uptake within a bifurcation unit with the average of inlet and outlet average concentrations. Both CFDM and ASPM predict the same trends of increase in mass transfer coefficients with inlet flow and wall mass transfer coefficients. Also, the local values of the mass transfer coefficients compared closely at all conditions. These results validate the simplified ASPM and the complex CFDM. Mass transfer coefficients increase with bifurcation angles and with a flat inlet velocity profile compared to a parabolic velocity profile since the flow is non-fully developed and hence, the uptake increases.

  20. Evaluation and application of site-specific data to revise the first-order decay model for estimating landfill gas generation and emissions at Danish landfills

    DEFF Research Database (Denmark)

    Mou, Zishen; Scheutz, Charlotte; Kjeldsen, Peter

    2015-01-01

    Methane (CH4) generated from low-organic waste degradation at four Danish landfills was estimated by three first-order decay (FOD) landfill gas (LFG) generation models (LandGEM, IPCC, and Afvalzorg). Actual waste data from Danish landfills were applied to fit model (IPCC and Afvalzorg) required...... categories. In general, the single-phase model, LandGEM, significantly overestimated CH4 generation, because it applied too high default values for key parameters to handle low-organic waste scenarios. The key parameters were biochemical CH4 potential (BMP) and CH4 generation rate constant (k.......Implications: Landfill operators use the first-order decay (FOD) models to estimate methane (CH4) generation. A single-phase model (LandGEM) and a traditional model (IPCC) could result in overestimation when handling a low-organic waste scenario. Site-specific data were important and capable of calibrating key parameter...

  1. Fine temporal control of the medium gas content and acidity and on-chip generation of series of oxygen concentrations for cell cultures.

    Science.gov (United States)

    Polinkovsky, Mark; Gutierrez, Edgar; Levchenko, Andre; Groisman, Alex

    2009-04-21

    We describe the design, operation, and applications of two microfluidic devices that generate series of concentrations of oxygen, [O(2)], by on-chip gas mixing. Both devices are made of polydimethylsiloxane (PDMS) and have two layers of channels, the flow layer and the gas layer. By using in-situ measurements of [O(2)] with an oxygen-sensitive fluorescent dye, we show that gas diffusion through PDMS leads to equilibration of [O(2)] in an aqueous solution in the flow layer with [O(2)] in a gas injected into the gas layer on a time scale of approximately 1 sec. Injection of carbon dioxide into the gas layer causes the pH in the flow layer to drop within approximately 0.5 sec. Gas-mixing channel networks of both devices generate series of 9 gas mixtures with different [O(2)] from two gases fed to the inlets, thus creating regions with 9 different [O(2)] in the flow layer. The first device generates nitrogen-oxygen mixtures with [O(2)] varying linearly between 0 and 100%. The second device generates nitrogen-air mixtures with [O(2)] varying exponentially between 0 and 20.9%. The flow layers of the devices are designed for culturing bacteria in semi-permeable microchambers, and the second device is used to measure growth curves of E. coli colonies at 9 different [O(2)] in a single experiment. The cell division rates at [O(2)] of 0, 0.2, and 0.5% are found to be significantly different, further validating the capacity of the device to set [O(2)] in the flow layer with high precision and resolution. The degree of control of [O(2)] achieved in the devices and the robustness with respect to oxygen consumption due to respiration would be difficult to match in a traditional large-scale culture. The proposed devices and technology can be used in research on bacteria and yeast under microaerobic conditions and on mammalian cells under hypoxia.

  2. A summary of volatile impurity measurements and gas generation studies on MISSTD-1, a high-purity plutonium oxide produced by low-temperature calcination of plutonium oxalate

    Energy Technology Data Exchange (ETDEWEB)

    Berg, John M. [Los Alamos National Laboratory; Narlesky, Joshua E. [Los Alamos National Laboratory; Veirs, Douglas K. [Los Alamos National Laboratory

    2012-06-08

    Plutonium dioxide of high specific surface area was subjected to long-term tests of gas generation in sealed containers. The material preparation and the storage conditions were outside the bounds of acceptable parameters defined by DOE-STD-3013-2012 in that the material was stabilized to a lower temperature than required and had higher moisture content than allowed. The data provide useful information for better defining the bounding conditions for safe storage. Net increases in internal pressure and transient increases in H{sub 2} and O{sub 2} were observed, but were well within the bounds of gas compositions previously shown to not threaten integrity of 3013 containers.

  3. ELECTRIC POWER GENERATION USING A PHOSPHORIC ACID FUEL CELL ON A MUNICIPAL SOLID WASTE LANDFILL GAS STREAM

    Science.gov (United States)

    The report gives results of tests to verify the performance of a landfill gas pretreatment unit (GPU) and a phorsphoric acid fuel cell system. The complete system removes contaminants from landfill gas and produces electricity for on-site use or connection to an electric grid. Th...

  4. 燃气轮机余热发电技术应用于输气管道的可行性%Application feasibility of gas-turbine waste heat power generation technology in gas pipeline

    Institute of Scientific and Technical Information of China (English)

    张鑫; 吴琼; 李荣光; 赵吉诗; 冯少广; 赵国星; 刘井会; 候宇

    2013-01-01

    A case taken from a compressor station in West-to-East Gas Pipeline is given to investigate the application feasibility of gas-vapor combined cycle power generation technology to improve the thermal efficiency of the generating unit. A field test was made to inspect the content of fuel gas components including the index parameters and calculate the exhaust enthalpy of gas turbine. The generated energy from united cycle generating sets was determined according to the average efficiency of the turbine generator set to demonstrate the feasibility and economy of using the gas-turbine waste heat power generation in electric driven compressor sets. The results showed that the generated energy of entire sets can meet the electricity demand of electric driven compressor sets up to 89.37%, featuring a four-year investment cost recovery period and a remarkable energy-saving effect, considerable long-running economic efficiency, and popularization and application value.%以西气东输某输气站为例,考察利用燃气蒸汽联合循环发电技术提高机组热效率的可行性.现场测试燃料气组分的含量以及各项指标参数,计算燃气轮机排烟热焓.按照汽轮机发电机组的平均效率,确定联合循环发电机组的发电量,论证燃气轮机余热发电用于驱动电驱压缩机组的可行性和经济性.结果表明:整个机组的发电量可以满足电驱压缩机组需求电量的89.37%,4年可回收投资成本,节能效果显著,长期运行经济效益可观,具有推广应用价值.

  5. CNG (Compressed natural gas) engine M366 G for electric power generation; Motor M 366 G movido a gas metano veicular versao industrial: aplicacao grupo gerador

    Energy Technology Data Exchange (ETDEWEB)

    Muraro, Wilson; Shiraiwa, Nilton Mitsuro [DaimlerChrysler do Brasil Ltda., Sao Bernardo do Campo, SP (Brazil); Mantovani, Wladimir Tadeu [Woodward Governor Company, Fort Collins, CO (United States)

    2004-07-01

    Daimler-Chrysler of Brazil developed the M 366 G engine, in the industrial version, using compressed natural gas. This product has the combustion with lambda 1.0, it is a 6-cylinder engine in line with displacement compressor of 5.958 cm{sup 3} , power of 65 kW @ 1800 min{sup 1} (60Hz) and power of 55 kW @ 1500 min{sup 1} (50Hz). The equipment for rotation control, ignition, reducing gas and stabilizer were specially developed for industrial motors with CNG supply for the Fca Woodward. This paper presents the results of tests made on bank of evidence and test field, which showed the good performance of the product. (author)

  6. Environmental costs associated to the electric generation: hydroelectric versus natural gas thermoelectric; Custos ambientais associados a geracao eletrica: hidreletricas versus termeletricas a gas natural

    Energy Technology Data Exchange (ETDEWEB)

    Reis, Marcelo de Miranda

    2001-01-15

    This works presents the methodologies for valuation of the environmental costs resulting from the main damages of the cycles of electric energy arrange through hydroelectric and natural gas thermoelectric. Initially theoretical concepts are established, embracing: the description of the valuation methodologies, the possible ways of damages internalization in the value of the products, the environmental impacts of hydroelectric and natural gas thermoelectric in these fuel cycles, and the methodologies that can be applied for value the main damages caused by the impacts. Then case studies are developed, with application of the methodologies in the hydroelectric plants of Simplicio and Serra da Mesa, and in the thermoelectric complex composed for RioGen and RioGen Merchant plants. Finally, conclusions and recommendations for a better future application in Brazil of the valuation methodologies are presented. (author)

  7. Soft X-ray characterization of an elongated gas-puff target dedicated for laser-matter interaction experiments and high harmonic generation

    Energy Technology Data Exchange (ETDEWEB)

    Wachulak, P.W., E-mail: wachulak@gmail.com [Institute of Optoelectronics, Military University of Technology, ul. Gen. S. Kaliskiego 2, 00-908 Warsaw (Poland); Bartnik, A.; Fiedorowicz, H.; Jarocki, R.; Kostecki, J.; Szczurek, M. [Institute of Optoelectronics, Military University of Technology, ul. Gen. S. Kaliskiego 2, 00-908 Warsaw (Poland)

    2012-04-01

    A slit-shaped elongated nozzle, capable of forming an extended gas density profile, is presented and studied in detail. Argon and xenon target density backlighting measurements revealed the elongated density profiles with gas density that can be tuned by changing valve backing pressure and valve timing. Two dimensional density maps for Ar and Xe targets, obtained at soft X-ray wavelengths around 7 A, are shown and spatially characterized. Moreover the influence of valve backing pressure and valve timing on gas puff target density is studied. This geometry of the nozzle has potential applications in high harmonic generation for an efficient conversion of femto-second duration, intense infrared pulses to extreme ultraviolet (EUV) region.

  8. Angle-resolved photoemission spectroscopy with 9-eV photon-energy pulses generated in a gas-filled hollow-core photonic crystal fiber

    Energy Technology Data Exchange (ETDEWEB)

    Bromberger, H., E-mail: Hubertus.Bromberger@mpsd.mpg.de; Liu, H.; Chávez-Cervantes, M.; Gierz, I. [Max Planck Institute for the Structure and Dynamics of Matter, Luruper Chaussee 149, 22761 Hamburg (Germany); Ermolov, A.; Belli, F.; Abdolvand, A.; Russell, P. St. J.; Travers, J. C. [Max Planck Institute for the Science of Light, Günther-Scharowsky-Str. 1, 91058 Erlangen (Germany); Calegari, F. [Max Planck Institute for the Structure and Dynamics of Matter, Luruper Chaussee 149, 22761 Hamburg (Germany); Institute for Photonics and Nanotechnologies, IFN-CNR, Piazza Leonardo da Vinci 32, I-20133 Milano (Italy); Li, M. T.; Lin, C. T. [Max Planck Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart (Germany); Cavalleri, A. [Max Planck Institute for the Structure and Dynamics of Matter, Luruper Chaussee 149, 22761 Hamburg (Germany); Clarendon Laboratory, Department of Physics, University of Oxford, Parks Rd. Oxford OX1 3PU (United Kingdom)

    2015-08-31

    A recently developed source of ultraviolet radiation, based on optical soliton propagation in a gas-filled hollow-core photonic crystal fiber, is applied here to angle-resolved photoemission spectroscopy (ARPES). Near-infrared femtosecond pulses of only few μJ energy generate vacuum ultraviolet radiation between 5.5 and 9 eV inside the gas-filled fiber. These pulses are used to measure the band structure of the topological insulator Bi{sub 2}Se{sub 3} with a signal to noise ratio comparable to that obtained with high order harmonics from a gas jet. The two-order-of-magnitude gain in efficiency promises time-resolved ARPES measurements at repetition rates of hundreds of kHz or even MHz, with photon energies that cover the first Brillouin zone of most materials.

  9. Angle-resolved photoemission spectroscopy with 9-eV photon-energy pulses generated in a gas-filled hollow-core photonic crystal fiber

    CERN Document Server

    Bromberger, H; Belli, F; Liu, H; Calegari, F; Chavez-Cervantes, M; Li, M T; Lin, C T; Abdolvand, A; Russell, P St J; Cavalleri, A; Travers, J C; Gierz, I

    2015-01-01

    A recently developed source of ultraviolet radiation, based on optical soliton propagation in a gas-filled hollow-core photonic crystal fiber, is applied here to angle-resolved photoemission spectroscopy (ARPES). Near-infrared femtosecond pulses of only few {\\mu}J energy generate vacuum ultraviolet (VUV) radiation between 5.5 and 9 eV inside the gas-filled fiber. These pulses are used to measure the band structure of the topological insulator Bi2Se3 with a signal to noise ratio comparable to that obtained with high order harmonics from a gas jet. The two-order-of-magnitude gain in efficiency promises time-resolved ARPES measurements at repetition rates of hundreds of kHz or even MHz, with photon energies that cover the first Brillouin zone of most materials.

  10. On Development and Characterisation of a Mobile and Metrologically Traceable Reference Gas Generator for Ammonia and Other Reactive Species in Ambient Air Levels

    Science.gov (United States)

    Leuenberger, Daiana; Pascale, Céline; Guillevic, Myriam; Ackermann, Andreas; Niederhauser, Bernhard

    2016-04-01

    Ammonia NH3 in the atmosphere is the major precursor for neutralising atmospheric acids and is thus affecting not only the long-range transport of sulphur dioxide and nitrogen oxides but also stabilies secondary particulate matter. These aerosols have negative impacts on air quality and human health. Moreover, they negatively affect terrestrial ecosystems after deposition. NH3 has been included in the air quality monitoring networks and emission reduction directives of European nations. Atmospheric concentrations are in the order of 0.5-500 nmol/mol. However, the lowest substance amount fraction of available certified reference material (CRM) is 30 μmol/mol. The EMRP JRP ENV55 MetNH3 aims at overcoming this discrepancy by assessing and developing novel approaches for the production of CRM and measurement methods. The Federal Institute of Metrology METAS has developed a mobile and metrologically traceable reference gas generator for reactive gases (ReGaS1). This device is based on the specific temperature dependent permeation of the reference substance through a membrane into a flow of carrier gas and subsequent dynamic dilution to desired amount fractions. The characteristics of individual components lead to the uncertainty estimation for the generated NH3 gas mixture according to GUM, which is aimed to be <3 %. Here we present insights into the development of said instrument and results of the first performance tests. Moreover, we include results of the study on adsorption/desorption effects in dry as well as humidified matrix gas into the discussion on the generation of reference gas mixtures.

  11. Power generation from bio methane. Requirements of the EEG 2012 and balancing in gas infrastructure; Verstromung von Biomethan. Anforderungen des EEG 2012 und gaswirtschaftliche Bilanzierung

    Energy Technology Data Exchange (ETDEWEB)

    Herz, Steffen; Bredow, Hartwig von [von Bredow Valentin Rechtsanwaelte, Berlin (Germany)

    2012-12-15

    Six years ago, the first biogas infeed plant was connected to the natural gas distribution system. The infeed of biogas progressed beyond the nursery stage. The infeed of bio methane significantly is promoted by the renewable energy law. One fundamental requirement for the promotion with respect to the Renewable Energy Law is the generation of the power to be remunerated by means of the exclusive use of biomass. The Renewable Energy Law EEG 2012 contains the new requirement, that furthermore the transport of biogas from its production until removal has to be documented by means of a mass balance. Under this aspect, the authors of the contribution under consideration report on the requirements of the EEG 2012 and the balancing in gas infrastructure with respect to the power generation from biomass.

  12. DECONTAMINATION ASSESSMENT OF BACILLUS ANTHRACIS, BACILLUS SUBTILIS, AND GEOBACILLUS STEAROTHERMOPHILUS SPORES ON INDOOR SURFACTS USING A HYDROGEN PERIOXIDE GAS GENERATOR

    Science.gov (United States)

    Aims: To evaluate the decontamination of Bacillus anthracis, Bacillus subtilis, and Geobacillus stearothermophilus spores on indoor surface materials using hydrogen peroxide gas. Methods and Results: B. anthracis, B. subtilis, and G. Stearothermophilus spores were dried on seven...

  13. Experimental Analysis of a Producer Gas Generated by a Chir Pine Needle (Leaf in a Downdraft Biomass Gasifier

    Directory of Open Access Journals (Sweden)

    Mr. Akhilesh Kumar

    2014-10-01

    Full Text Available Today’s Indian scenario is facing an unprecedented energy crisis as the conventional energy resources of India are consistently deteriorating with the limited stock of these natural minerals posing a staggering threat to the Indian economy. Among all the available resources biomass proves to be a satisfactory substitute for compensating the energy void due to these natural resources. Biomass is a renewable resource with almost zero net CO2 emission which is processed with the help of biomass gasifier which is concurrently used with a chir pine needle. The performance of the biomass gasifier system is evaluated in terms of equivalence ratio, producer gas composition, calorific value of the producer gas, gas production rate and cold gas efficiency. The experimental results are compared with those reported in the literature.

  14. Harmonic generation by noble-gas atoms in the near-IR regime using ab initio time-dependent R -matrix theory

    Science.gov (United States)

    Hassouneh, O.; Brown, A. C.; van der Hart, H. W.

    2014-10-01

    We demonstrate the capability of ab initio time-dependent R -matrix theory to obtain accurate harmonic generation spectra of noble-gas atoms at near-IR wavelengths between 1200 and 1800 nm and peak intensities up to 1.8 × 10 14 W /cm 2. To accommodate the excursion length of the ejected electron, we use an angular-momentum expansion up to Lmax=279 . The harmonic spectra show evidence of atomic structure through the presence of a Cooper minimum in harmonic generation for Kr, and of multielectron interaction through the giant resonance for Xe. The theoretical spectra agree well with those obtained experimentally.

  15. Harmonic generation of noble-gas atoms in the Near-IR regime using ab-initio time-dependent R-matrix theory

    CERN Document Server

    Hassouneh, O; van der Hart, H W

    2014-01-01

    We demonstrate the capability of ab-initio time-dependent R-matrix theory to obtain accurate harmonic generation spectra of noble-gas atoms at Near-IR wavelengths between 1200 and 1800 nm and peak intensities up to 1.8 X 10(14) W/cm(2) . To accommodate the excursion length of the ejected electron, we use an angular-momentum expansion up to Lmax = 279. The harmonic spectra show evidence of atomic structure through the presence of a Cooper minimum in harmonic generation for Kr, and of multielectron interaction through the giant resonance for Xe. The theoretical spectra agree well with those obtained experimentally.

  16. The Effects of the Location of Au Additives on Combustion-generated SnO2 Nanopowders for CO Gas Sensing

    OpenAIRE

    Bakrania, Smitesh D.; Margaret S. Wooldridge

    2010-01-01

    The current work presents the results of an experimental study of the effects of the location of gold additives on the performance of combustion-generated tin dioxide (SnO2) nanopowders in solid state gas sensors. The time response and sensor response to 500 ppm carbon monoxide is reported for a range of gold additive/SnO2 film architectures including the use of colloidal, sputtered, and combustion-generated Au additives. The opportunities afforded by combustion synthesis to affect the SnO2/a...

  17. A fully enclosed, compact standard lightning impulse generator for testing ultra-high-voltage-class gas-insulated switchgears with high capacitance

    Science.gov (United States)

    Wen, Tao; Zhang, Qiaogen; Zhang, Lingli; Zhao, Junping; Liu, Xuandong; Li, Xiaoang; Guo, Can; You, Haoyang; Chen, Weijiang; Yin, Yu; Shi, Weidong

    2016-03-01

    At present, conducting standard lightning impulse (LI) tests in the field for gas-insulated switchgear (GIS) equipment is difficult because of the high capacitance of the test equipment and large circuit inductance of traditional impulse devices, which leads to a wavefront time Tf ≥ 2.5 μs. A novel fully enclosed, compact standard LI generator for testing ultra-high-voltage-class GIS equipment with high capacitance is presented to solve the problem of Tf exceeding the standard during LI voltage tests for actual large-sized equipment. The impulse generator is installed in a metal vessel filled with SF6 or SF6/N2 gas mixture at a pressure of 0.3-0.5 MPa, providing a more compact structure and a lower series inductance. A newly developed conical voltage sensor is used to accurately measure the output voltage waveform. Two test modes (via bushing docking and direct docking) for the GIS test based on the impulse generator are introduced. Calculation results show that the impulse generator can generate an LI test waveform following the present IEC standard for the test of equipment with capacitance >10 000 pF.

  18. Liquid-in-gas droplet microfluidics; experimental characterization of droplet morphology, generation frequency, and monodispersity in a flow-focusing microfluidic device

    Science.gov (United States)

    Tirandazi, Pooyan; Hidrovo, Carlos H.

    2017-07-01

    Microfluidic techniques for production of uniform droplets usually rely on the use of two immiscible liquids (e.g. water-in-oil emulsions). It has been shown recently that a continuous gas flow instead of a second liquid carrier can be used as an alternative approach in droplet microfluidics. In this work we experimentally investigate the generation of liquid water droplets within air in flow-focusing configurations. Over a wide range of flow conditions we identify six distinct flow regimes inside the microchannel: Co-flowing, Threading, Plugging, Dripping, Multi-Satellite Formation, and Jetting. Flow regimes and their transitions are plotted and characterized based on the Weber number (We) of the system. We further investigate the impact of liquid microchannel size on the flow maps. Generation frequency, morphology, and monodispersity of the droplets are characterized in more detail in the Dripping regime. Generation frequency can be related to the product of the liquid and gas flow rates. However, droplet morphology (length and width) is more dependent on the gas flow rate. We demonstrate the production of monodisperse droplets (d lab-on-a-chip systems for a variety of applications in biochemical research and material synthesis.

  19. 3. report of study group 6.2 ''new market for gas - technology evaluation'': factor analysis on penetration of gas cooling; biogas, a renewable energy source; micro- and mini- combined heat and power generation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-07-01

    Over the past ten years, the hoped for growth of an international air conditioning market fueled by natural gas, has not lived up to expectations. The purpose of this report is to assess causal factors and to pinpoint any key areas for corrective action, if our successes are to be enhanced. We started by evaluating the conditions in the Japanese market that allowed for the most successful penetration of the gas cooling market in the world, and then built a model that describes those conditions. Next we examined the market criteria and constructed models for two cities in the U.S., and for France and Spain, and then compared the results against the Japanese model. Biogas is the name given to a gas mixture with high methane content resulting from the bacteriological fermentation of organic material in an anaerobic environment. In addition to combustible methane gas, the mixture contains carbon dioxide, water and lesser amounts of other components. Today, there is an increased demand in some of the worlds' markets for environmentally friendly and sustainable energy systems. The fact that biogas is just as clean as natural gas and is renewable can be used by the natural gas industry in their efforts to increase gas demand. As natural gas can benefit from biogas, biogas can also benefit from natural gas. Biogas needs the support of the resources of the natural gas industry, such as infrastructure, marketing and research to become one, albeit small, part of our energy supply. IGU SG 6.2 presents in this paper a short description of the possible uses of biogas, a description of the biogas process, the different technologies for production, cleaning and upgrading biogas to natural gas quality, and some of the marketing concepts that have been successfully employed. A world-wide trend towards decentralized power generation is being observed in those countries where electricity is generated in centralized fossil-fuelled power stations. This is due to a variety of

  20. Heavier hydrocarbons removing method study for oilfield fuel gas into gas engine generator%温差发电技术及其在海洋石油平台上的应用

    Institute of Scientific and Technical Information of China (English)

    胡蓉; 余智; 严雪莲; 戴磊; 宗远航

    2015-01-01

    A thermoelectric generator converts heat directly into electricity. As heat moves from a gas burner through a thermoelectric module,it causes an electrical current to flow. The durable module in the thermoelectric generator provides a chemically stable environment for the thermoelectric material and ensures a long service life. A burner maintains a high temperature on the hot side while cooling fins keeps the other side cool. The temperature difference across the thermopile which is the heart of the thermoelectric generator creates steady DC electricity with no moving parts. This paper introduces the operating philosophy of thermoelectric generation and its applications on offshore oil and gas platforms.%温差发电技术是利用热电转换材料直接将热能转化为电能的发电技术,该技术是一种固态能量转换方式,能够直接将热能转化为电能,具有无运动部件、体积小、重量轻、移动方便和可靠性高等特点,是绿色环保的发电方式.本文介绍了温差发电技术的原理及其在海洋石油平台上的应用.

  1. The Three-D Flow Structures of Gas and Liquid Generated by a Spreading Flame Over Liquid Fuel

    Science.gov (United States)

    Tashtoush, G.; Ito, A.; Konishi, T.; Narumi, A.; Saito, K.; Cremers, C. J.

    1999-01-01

    We developed a new experimental technique called: Combined laser sheet particle tracking (LSPT) and laser holographic interferometry (HI), which is capable of measuring the transient behavior of three dimensional structures of temperature and flow both in liquid and gas phases. We applied this technique to a pulsating flame spread over n-butanol. We found a twin vortex flow both on the liquid surface and deep in the liquid a few mm below the surface and a twin vortex flow in the gas phase. The first twin vortex flow at the liquid surface was observed previously by NASA Lewis researchers, while the last two observations are new. These observations revealed that the convective flow structure ahead of the flame leading edge is three dimensional in nature and the pulsating spread is controlled by the convective flow of both liquid and gas.

  2. Generation IV nuclear energy system initiative. Large GFR core subassemblydesign for the Gas-Cooled Fast Reactor.

    Energy Technology Data Exchange (ETDEWEB)

    Hoffman, E. A.; Kulak, R. F.; Therios, I. U.; Wei, T. Y. C.

    2006-07-31

    Gas-cooled fast reactor (GFR) designs are being developed to meet Gen IV goals of sustainability, economics, safety and reliability, and proliferation resistance and physical protection as part of an International Generation IV Nuclear Energy System Research Initiative effort. Different organizations are involved in the development of a variety of GFR design concepts. The current analysis has focused on the evaluation of low-pressure drop, pin-core designs with favorable passive cooling properties. Initial evaluation of the passive cooling safety case for the GFR during depressurized decay heat removal accidents with concurrent loss of electric power have resulted in requirements for a reduction of core power density to the 100 w/cc level and a low core pressure drop of 0.5 bars. Additional design constraints and the implementation of their constraints are evaluated in this study to enhance and passive cooling properties of the reactor. Passive cooling is made easier by a flat radial distribution of the decay heat. One goal of this study was to evaluate the radial power distribution and determine to what extent it can be flattened, since the decay heat is nearly proportional to the fission power at shutdown. In line with this investigation of the radial power profile, an assessment was also made of the control rod configuration. The layout provided a large number of control rod locations with a fixed area provided for control rods. The number of control rods was consistent with other fast reactor designs. The adequacy of the available control rod locations was evaluated. Future studies will be needed to optimize the control rod designs and evaluate the shutdown system. The case for low pressure drop core can be improved by the minimization of pressure drop sources such as the number of required fuel spacers in the subassembly design and by the details of the fuel pin design. The fuel pin design is determined by a number of neutronic, thermal-hydraulic (gas dynamics

  3. Low NO sub x heavy fuel combustor concept program. Phase 1A: Combustion technology generation coal gas fuels

    Science.gov (United States)

    Sherlock, T. P.

    1982-01-01

    Combustion tests of two scaled burners using actual coal gas from a 25 ton/day fluidized bed coal gasifier are described. The two combustor configurations studied were a ceramic lined, staged rich/lean burner and an integral, all metal multiannual swirl burner (MASB). The tests were conducted over a range of temperature and pressures representative of current industrial combustion turbine inlet conditions. Tests on the rich lean burner were conducted at three levels of product gas heating values: 104, 197 and 254 btu/scf. Corresponding levels of NOx emissions were 5, 20 and 70 ppmv. Nitrogen was added to the fuel in the form of ammonia, and conversion efficiencies of fuel nitrogen to NOx were on the order of 4 percent to 12 percent, which is somewhat lower than the 14 percent to 18 percent conversion efficiency when src-2 liquid fuel was used. The MASB was tested only on medium btu gas (220 to 270 btu/scf), and produced approximately 80 ppmv NOx at rated engine conditions. Both burners operated similarly on actual coal gas and erbs fuel, and all heating values tested can be successfully burned in current machines.

  4. The potential of renewables versus natural gas with CO2 capture and storage for power generation under CO2 constraints

    NARCIS (Netherlands)

    Van Den Broek, Machteld|info:eu-repo/dai/nl/092946895; Berghout, Niels|info:eu-repo/dai/nl/328201057; Rubin, Edward S.

    2015-01-01

    The costs of intermittent renewable energy systems (IRES) and power storage technologies are compared on a level playing field to those of natural gas combined cycle power plants with CO2 capture and storage (NGCC-CCS). To account for technological progress over time, an "experience curve

  5. Gas Turbine Starting by GT generator with SFC Power Supply%燃气轮机的SFC启动

    Institute of Scientific and Technical Information of China (English)

    赵昌宗

    2002-01-01

    Recent years,Gas Turbine—Combine cycle Power Plant developed s.quickly in the world.Gas—turbine call only be started driven by other machine GT starled by GT—genera—lof driving with SFC p.wer supply is.ne of the most commonly used metbads This paper describes the basic principle of this ntethod.

  6. The impact of a grain of sand: increasing production speed in flexible risers generates significant savings in gas production

    NARCIS (Netherlands)

    Bokhorst, E. van; Blokland, H.

    2012-01-01

    Deep-sea oil and gas production normally involves the use of flexible risers that comprise a metal carcass with a large number of enveloping layers that safeguard the integrity of the pipe system. The flexible risers are hung from a floating platform and may be supported by several floating buoys to

  7. Design and development of a propulsion system for a cubesat - Based on solid propellant cool gas generator technology

    NARCIS (Netherlands)

    Rackemann, N.J.; Sanders, H.M.; Vliet, L.D. van

    2006-01-01

    Orbital manoeuvring is the next challenge in the development of cubesats. In this study a propulsion system for a cubesat with the main purpose of providing orbit manoeuvring and formation flying has been designed. This propulsion system is basically a cold gas system but it does not use a pressuris

  8. The potential of renewables versus natural gas with CO2 capture and storage for power generation under CO2 constraints

    NARCIS (Netherlands)

    Van Den Broek, Machteld; Berghout, Niels; Rubin, Edward S.

    2015-01-01

    The costs of intermittent renewable energy systems (IRES) and power storage technologies are compared on a level playing field to those of natural gas combined cycle power plants with CO2 capture and storage (NGCC-CCS). To account for technological progress over time, an "experience curve

  9. Design and development of a propulsion system for a cubesat - Based on solid propellant cool gas generator technology

    NARCIS (Netherlands)

    Rackemann, N.J.; Sanders, H.M.; Vliet, L.D. van

    2006-01-01

    Orbital manoeuvring is the next challenge in the development of cubesats. In this study a propulsion system for a cubesat with the main purpose of providing orbit manoeuvring and formation flying has been designed. This propulsion system is basically a cold gas system but it does not use a pressuris

  10. GOSSIP: A vertex detector combining a thin gas layer as signal generator with a CMOS readout pixel array

    NARCIS (Netherlands)

    Campbell, M.; Heijne, E.H.M.; Llopart, X.; Colas, P.; Giganon, A.; Giomataris, Y.; Fornaini, A.; Graaf, van der H.; Kluit, P.; Timmermans, J.; Visschers, J.L.; Schmitz, J.

    2005-01-01

    A small TPC has been read out by means of a Medipix2 chip as direct anode. A Micromegas foil was placed 50 mm above the chip, and electron multiplication occurred in the gap. With a He/isobutane 80/20 mixture, gas multiplication factors up to tens of thousands were achieved, resulting in an efficien

  11. The potential of renewables versus natural gas with CO2 capture and storage for power generation under CO2 constraints

    NARCIS (Netherlands)

    Van Den Broek, Machteld; Berghout, Niels; Rubin, Edward S.

    2015-01-01

    The costs of intermittent renewable energy systems (IRES) and power storage technologies are compared on a level playing field to those of natural gas combined cycle power plants with CO2 capture and storage (NGCC-CCS). To account for technological progress over time, an "experience

  12. Development and validation of a portable gas phase standard generation and calibration system for volatile organic compounds

    Science.gov (United States)

    P. Veres; J. B. Gilman; J. M. Roberts; W. C. Kuster; C. Warneke; I. R. Burling; J. de Gouw

    2010-01-01

    We report on the development of an accurate, portable, dynamic calibration system for volatile organic compounds (VOCs). The Mobile Organic Carbon Calibration System (MOCCS) combines the production of gas-phase VOC standards using permeation or diffusion sources with quantitative total organic carbon (TOC) conversion on a palladium surface to CO2 in the presence of...

  13. A Parameter Space Exploration of Galaxy Cluster Mergers I: Gas Mixing and the Generation of Cluster Entropy

    CERN Document Server

    ZuHone, John

    2010-01-01

    We present a high-resolution set of adiabatic binary galaxy cluster merger simulations using FLASH. These are the highest-resolution simulations to date of such mergers using an AMR grid-based code with Eulerian hydrodynamics. In this first paper in a series we investigate the effects of merging on the entropy of the hot intracluster gas, specifically with regard to the ability of merging to heat and disrupt cluster "cool-cores." We find, in line with recent works, that the effect of fluid instabilities that are well-resolved in grid-based codes is to significantly mix the gases of the two clusters and to significantly increase the entropy of the gas of the final merger remnant. This result is characteristic of mergers over a range of initial mass ratio and impact parameter. In line with this, we find that the kinetic energy associated with random motions is higher in our merger remnants which have high entropy floors, indicating the motions have efficiently mixed the gas and heated the cluster core with gas ...

  14. Generation of standard gas mixtures of halogenated, aliphatic, and aromatic compounds and prediction of the individual output rates based on molecular formula and boiling point.

    Science.gov (United States)

    Thorenz, Ute R; Kundel, Michael; Müller, Lars; Hoffmann, Thorsten

    2012-11-01

    In this work, we describe a simple diffusion capillary device for the generation of various organic test gases. Using a set of basic equations the output rate of the test gas devices can easily be predicted only based on the molecular formula and the boiling point of the compounds of interest. Since these parameters are easily accessible for a large number of potential analytes, even for those compounds which are typically not listed in physico-chemical handbooks or internet databases, the adjustment of the test gas source to the concentration range required for the individual analytical application is straightforward. The agreement of the predicted and measured values is shown to be valid for different groups of chemicals, such as halocarbons, alkanes, alkenes, and aromatic compounds and for different dimensions of the diffusion capillaries. The limits of the predictability of the output rates are explored and observed to result in an underprediction of the output rates when very thin capillaries are used. It is demonstrated that pressure variations are responsible for the observed deviation of the output rates. To overcome the influence of pressure variations and at the same time to establish a suitable test gas source for highly volatile compounds, also the usability of permeation sources is explored, for example for the generation of molecular bromine test gases.

  15. Analysis of Case Studies on Experimental Research of Gas Generation in Foreign Countries for Low- and Intermediate-level Radioactive Waste Disposal

    Energy Technology Data Exchange (ETDEWEB)

    Park, Jin Beak; Lee, Sun Joung [Korea Radioactive Waste Management Corporation, Daejeon (Korea, Republic of); Kim, Suk Hoon; Kim, Ju Youl [FNC Technology Co., Seoul National University, Seoul (Korea, Republic of)

    2010-09-15

    In order to acquire a realistic forecast for the lifetime and post-closure period of the LILW (Low- and Intermediate-Level Radioactive Waste) repository and to establish the overall management plan associated gas issues. it is essential to carry out the long-term experimental research in a similar condition to actual disposal environment. Regarding this, as a part of the following-up actions on a construction and operation license for the first stage of the LILW repository at Gyeongju city, a large-scale in-situ experiment is being planned. For securing basic data on the experiment, the experimental researches related to gas generation previously performed in foreign countries are reviewed in detail. Consequently, it is judged that data on the gas generation experiment in Finland could be practically applied as the benchmark for our large-scale in-situ experiment because the same disposal concept as the Korean repository is adopted and the experiment is performed in a scale large enough to allow the use of regular waste packages.

  16. Study of electrical conductivity response upon formation of ice and gas hydrates from salt solutions by a second generation high pressure electrical conductivity probe.

    Science.gov (United States)

    Sowa, Barbara; Zhang, Xue Hua; Kozielski, Karen A; Dunstan, Dave E; Hartley, Patrick G; Maeda, Nobuo

    2014-11-01

    We recently reported the development of a high pressure electrical conductivity probe (HP-ECP) for experimental studies of formation of gas hydrates from electrolytes. The onset of the formation of methane-propane mixed gas hydrate from salt solutions was marked by a temporary upward spike in the electrical conductivity. To further understand hydrate formation a second generation of window-less HP-ECP (MkII), which has a much smaller heat capacity than the earlier version and allows access to faster cooling rates, has been constructed. Using the HP-ECP (MkII) the electrical conductivity signal responses of NaCl solutions upon the formation of ice, tetrahydrofuran hydrates, and methane-propane mixed gas hydrate has been measured. The concentration range of the NaCl solutions was from 1 mM to 3M and the driving AC frequency range was from 25 Hz to 5 kHz. This data has been used to construct an "electrical conductivity response phase diagrams" that summarize the electrical conductivity response signal upon solid formation in these systems. The general trend is that gas hydrate formation is marked by an upward spike in the conductivity at high concentrations and by a drop at low concentrations. This work shows that HP-ECP can be applied in automated measurements of hydrate formation probability distributions of optically opaque samples using the conductivity response signals as a trigger.

  17. Design and Assessment of an IGCC Concept with CO2 Capture for the Co-Generation of Electricity and Substitute Natural Gas

    Directory of Open Access Journals (Sweden)

    Timo Blumberg

    2015-12-01

    Full Text Available The focus of this work is on the modeling and the thermodynamic evaluation of an integrated gasification combined cycle (IGCC for the co-production of electricity and substitute natural gas (SNG. At first, an IGCC with CO2 capture for electricity generation is analyzed. Coal-derived syngas is conditioned in a water gas shift unit (WGS, and cleaned in an acid gas removal system including carbon capture. Eventually, the conditioned syngas is fed to a combined cycle. A second case refers to a complete conversion of syngas to SNG in an integrated commercial methanation unit (TREMP™ process, Haldor Topsøe, Kgs. Lyngby, Denmark. Due to the exothermic reaction, a gas recycling and intercooling stages are necessary to avoid catalyst damage. Based on a state-of-the-art IGCC plant, an optimal integration of the synthetic process considering off-design behavior was determined. The raw syngas production remains constant in both cases, while one shift reactor in combination with a bypass is used to provide an adequate H2/CO-ratio for the methanation unit. Electricity has to be purchased from the grid in order to cover the internal consumption when producing SNG. The resulting heat and power distributions of both cases are discussed.

  18. Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high temperature furnace (HITAF)

    Energy Technology Data Exchange (ETDEWEB)

    1992-11-01

    A concept for an advanced coal-fired combined-cycle power generating system is currently being developed. The first phase of this three-phase program consists of conducting the necessary research and development to define the system, evaluate the economic and technical feasibility of the concept, and prepare an R D plan to develop the concept further. Foster Wheeler Development Corporation is leading a team ofcompanies involved in this effort. The system proposed to meet these goals is a combined-cycle system where air for a gas turbine is indirectly heated to approximately 1800[degrees]F in furnaces fired with cool-derived fuels and then directly heated in a natural-gas-fired combustor up to about 2400[degrees]F. The system is based on a pyrolyzing process that converts the coal into a low-Btu fuel gas and char. The fuelgas is a relatively clean fuel, and it is fired to heat tube surfaces that are susceptible to corrosion and problems from ash deposition. In particular, the high-temperature air heater tubes, which will need tobe a ceramic material, will be located in a separate furnace or region of a furnace that is exposed to combustion products from the low-Btu fuel gas only. A simplified process flow diagram is shown.

  19. Generation of basic centers in high-silica zeolites and their application in gas-phase upgrading of bio-oil.

    Science.gov (United States)

    Keller, Tobias C; Rodrigues, Elodie G; Pérez-Ramírez, Javier

    2014-06-01

    High-silica zeolites have been reported recently as efficient catalysts for liquid- and gas-phase condensation reactions because of the presence of a complementary source of basicity compared to Al-rich basic zeolites. Herein, we describe the controlled generation of these active sites on silica-rich FAU, BEA, and MFI zeolites. Through the application of a mild base treatment in aqueous Na2CO3, alkali-metal-coordinating defects are generated within the zeolite whereas the porous properties are fully preserved. The resulting catalysts were applied in the gas-phase condensation of propanal at 673 K as a model reaction for the catalytic upgrading of pyrolysis oil, for which an up to 20-fold increased activity compared to the unmodified zeolites was attained. The moderate basicity of these new sites leads to a coke resistance superior to traditional base catalysts such as CsX and MgO, and comparable activity and excellent selectivity is achieved for the condensation pathways. Through strategic acid and base treatments and the use of magic-angle spinning NMR spectroscopy, the nature of the active sites was investigated, which supports the theory of siloxy sites as basic centers. This contribution represents a key step in the understanding and design of high-silica base catalysts for the intermediate deoxygenation of crude bio-oil prior to the hydrotreating step for the production of second-generation biofuels.

  20. Generation and characterization of plasma channels in gas puff targets using soft X-ray radiography technique

    Energy Technology Data Exchange (ETDEWEB)

    Wachulak, P. W., E-mail: wachulak@gmail.com; Bartnik, A.; Jarocki, R.; Fok, T.; Węgrzyński, Ł.; Kostecki, J.; Szczurek, M.; Jabczyński, J.; Fiedorowicz, H. [Institute of Optoelectronics, Military University of Technology, ul. gen. S. Kaliskiego 2, 00-908 Warsaw (Poland)

    2014-10-15

    We present our recent results of a formation and characterization of plasma channels in elongated krypton and xenon gas puff targets. The study of their formation and temporal expansion was carried out using a combination of a soft X-ray radiography (shadowgraphy) and pinhole camera imaging. Two high-energy short laser pulses were used to produce the channels. When a pumping laser pulse was shaped into a line focus, using cylindrical and spherical lenses, the channels were not produced because much smaller energy density was deposited in the gas puff target. However, when a point focus was obtained, using just a spherical lens, the plasma channels appeared. The channels were up to 9 mm in length, had a quite uniform density profile, and expanded in time with velocities of about 2 cm/μs.

  1. THE USE OF GENERATING SETS WITH lNG GAS ENGINES IN “SHORE TO SHIP” SYSTEMS

    OpenAIRE

    Dariusz TARNAPOWICZ; Sergiej GERMAN-GALKIN

    2016-01-01

    The main sources of air pollution in ports are ships, on which electrical energy is produced in the autonomous gener-ating sets Diesel-Generator. The most effective way to reduce harmful exhaust emissions from ships is to exclude marine generating sets and provide the shore-side electricity in “Shore to Ship” system. The main problem in the implementa-tion of power supply for ships from land is connected with matching parameters of voltage in onshore network with marine network. Currently, th...

  2. 非叠氮类气体发生剂的研究进展%Progress in Research of Non-azide Gas Generating Composition

    Institute of Scientific and Technical Information of China (English)

    刘影; 冯长根; 杨利

    2012-01-01

    非叠氮类气体发生剂具有的含氮量高、燃速快、安定性良好、无毒、绿色环保等优点,使其成为气体发生剂领域的研究热点,并在汽车安全气囊、航天器、消防灭火等方面有着广泛的应用前景.本文对比叠氮类气体发生剂的性能,详细介绍了唑类、嗪类、胍类和偶氮类非叠氮气体发生剂的性质;全面系统地综述了上述各类非叠氮气体发生剂国内外合成、表征与应用的研究进展;重点分析了各类典型非叠氮气体发生剂的配方及性能参数,并探讨配方内不同组分对发生剂不同性能的影响,为进一步研发新型非叠氮类气体发生剂配方提供参考.经研究发现,同传统的叠氮类气体发生剂相比,虽然非叠氮类气体发生剂在产气量、燃速等性能方面有较大的提高,但因其存在价格昂贵等问题,目前仍然没有完全取代叠氮类气体发生剂.因此,在现有研究基础上,还需积极研发更加环保、无毒、高效、廉价和实用的非叠氮类气体发生剂.%The non-azide gas generating composition is a hot research topic due to its many features, such as high nitrogen content, fast burning rate, good stability, non-toxicity, and green environmental protection. It is widely applied in airbag, spacecraft, fire fighting and other fields. In this paper, compared with the traditional azide gas generating composition, the properties of azole, azine, guanidine and azoic gas generating compositions are analyzed in detail: the progresses in the synthesis, the characterization and the application are reviewed: the formulas and characteristic parameters are discussed. It is found that the non-azide gas generating composition has not completely replaced the traditional azide gas generating composition, despite its superior properties in many aspects, because of factors like the high price, the excessive heat of combustion, and the high temperature. Therefore it is necessary to

  3. State of the art stationary and mobile infrastructure for the dynamic generation and dilution of traceable reference gas mixtures of Ammonia at ambient air amount fractions

    Science.gov (United States)

    Leuenberger, Daiana; Pascale, Céline; Guillevic, Myriam; Ackermann, Andreas; Niederhauser, Bernhard

    2017-04-01

    Ammonia (NH3) in the atmosphere is the major precursor for neutralising atmospheric acids and is thus affecting not only the long-range transport of sulphur dioxide and nitrogen oxides but also stabilises secondary particulate matter. These aerosols have negative impacts on air quality and human health. Moreover, they negatively affect terrestrial ecosystems after deposition. NH3 has been included in the air quality monitoring networks and emission reduction directives of European nations. Atmospheric concentrations are in the order of 0.5-500 nmol/mol. However, the lowest substance amount fraction of available certified reference material (CRM) is 10 μmol/mol. This due to the fact that adsorption on the walls of aluminium cylinders and desorption as pressure in the cylinder decreases cause substantial instabilities in the amount fractions of the gas mixtures. Moreover, analytical techniques to be calibrated are very diverse and cause challenges for the production and application of CRM. The Federal Institute of Metrology METAS has developed, partially in the framework of EMRP JRP ENV55 MetNH3, an infrastructure to meet with the different requirements in order to generate SI-traceable NH3 reference gas mixtures dynamically in the amount fraction range 0.5-500 nmol/mol and with uncertainties UNH3 filling. The mobile system as well as these cylinders can be applied for calibrations in other laboratories and in the field. In addition, an SI traceable system based on a cascade of critical orifices has been established to dilute NH3 mixtures in the order of μmol/mol stored in cylinders for the participation in the international key-comparison CCQM K117. It is planned to establish this system to calibrate and re-sample gas cylinders due to its very economical gas use. Here we present insights into the development of said infrastructure and results of the first performance tests. Moreover, we include results of the study on adsorption/desorption effects in dry as well

  4. Terahertz Emission Dependence on the Fundamental Optical Intensity in Generating Terahertz Waves from Two-Color Laser-Induced Gas Plasma

    Institute of Scientific and Technical Information of China (English)

    DAI Hou-Mei; LIU Jin-Song

    2011-01-01

    A transient photocurrent model is used to explain terahertz ermission from gas plasma irritated by two-color laser pulses,with one the second harmonic of the other.Taking multiple degrees of ionization into account,the gas ionization process at different laser intensities from 1014 W/cm2 to 1015 W/cm2 is discussed.The results show that when Iω ≥ 6 × 1014 W/cm2,double ionization plays an important role in producing electrons.The corresponding terahertz spectra and waveforms are calculated,showing that increasing laser intensity can broaden the spectra to high frequencies and enhance the terahertz field.A promising method for generating terahertz (THz) waves involves emission from laser induced gas plasmas,which was first introduced hy Hamster et al.[1,2] By focusing laser femtosecond pulses with intensity greater than the thresholl for ionization of the gas molecules,one can obtain significant plasma formation.The ionized electrons will then accelerate by the lapser ponderomotive force,thus an electromagnetic pulse at THz frcqucncies can be produced.Since then,other plasma-based THz generation scheines have been proposed.L(o)ffler et al.,[3,4] applied an external dc bias to the plasma region,leading to an approximately one order of magnitude increase in the THz field strength.%A transient photocurrent model is used to explain terahertz emission from gas plasma irritated by two-color laser pulses, with one the second harmonic of the other. Taking multiple degrees of iom'xntion into account, the gas ionizntion process at different laser intensities from 1014 W/cm2 to 1015 W/cm2 is discussed. The results show that when /w > 6 X 1014 W/cin2, double ionization plays an important role in producing electrons. The corresponding terahertz spectra and waveforms are calculated, showing that increasing laser intensity can broaden the spectra to high frequencies and enhance the terahertz Geld.

  5. Surface characterization of imidazolium-based ionic liquids with cyano-functionalized anions at the gas-liquid interface using sum frequency generation spectroscopy.

    Science.gov (United States)

    Peñalber, Chariz Y; Grenoble, Zlata; Baker, Gary A; Baldelli, Steven

    2012-04-21

    Advancement in the field of ionic liquid technology requires a comprehensive understanding of their surface properties, as a wide range of chemical reactions occur mainly at interfaces. As essential media currently used in several technological applications, their accurate molecular level description at the gas-liquid interface is of utmost importance. Due to the high degree of chemical information provided in the vibrational spectrum, vibrational spectroscopy gives the most detailed model for molecular structure. The inherently surface-sensitive technique, sum frequency generation (SFG) spectroscopy, in combination with bulk-sensitive vibrational spectroscopic techniques such as FTIR and Raman, has been used in this report to characterize the surface of cyano-containing ionic liquids, such as [BMIM][SCN], [BMIM][DCA], [BMIM][TCM] and [EMIM][TCB] at the gas-liquid interface. By structural variation of the anion while keeping the cation constant, emphasis on the molecular arrangement of the anion at the gas-liquid interface is reported, and its subsequent role (if any) in determining the surface molecular orientation of the cation. Vibrational modes seen in the C-H stretching region revealed the presence of the cation at the gas-liquid interface. The cation orientation is independent of the type of cyano-containing anion, however, a similar arrangement at the surface as reported in previous studies was found, with the imidazolium ring lying flat at the surface, and the alkyl chains pointing towards the gas phase. SFG results show that all three anions of varying symmetry, namely, [DCA](-) (C(2v)), [TCM](-)(D(3h)) and [TCB](-) (T(d)) in ionic liquids [BMIM]DCA], [BMIM][TCM] and [EMIM][TCB] are significantly tilted from the surface plane, while the linear [SCN](-) in [BMIM][SCN] exhibited poor ordering, as seen in the absence of its C-N stretching mode in the SFG vibrational spectra.

  6. Experimental and numerical investigation of the catalytic partial oxidation of methane to synthesis gas for power generation applications[Dissertation 17183

    Energy Technology Data Exchange (ETDEWEB)

    Schneider, A.

    2007-07-01

    The present work addresses the catalytic partial oxidation (CPO) of methane to synthesis gas, with particular emphasis on power generation applications. A combined experimental and numerical investigation of methane partial oxidation to synthesis gas (H{sub 2}, CO) over rhodium-based catalysts has been carried out at pressures of up to 10 bar. The reactivity of the produced hydrogen and the suitably-low light-off temperatures of the CPO reactor, greatly facilitate operation of power generation gas turbines with reduced NO{sub x} emissions, stable operation with low calorific value fuels, and new combustion strategies for efficient CO{sub 2} capture. Those strategies utilize CPO of methane with oxygen (separated from air) and large exhaust gas recycle (H{sub 2}O and CO{sub 2}). An optically accessible catalytic channel-flow reactor was used to carry out Raman spectroscopy of major gas-phase species and laser induced fluorescence (LIF) of formaldehyde, in order to gain fundamental information on the catalytic and gas-phase chemical pathways. Transverse concentration profiles measured by the spontaneous Raman scattering technique determined the catalytic reactivity, while the LIF provided flame shapes and anchoring positions that, in turn, characterized the gaseous reactivity. Comparison between measurements and 2-D CFD computations, led to the validation of detailed catalytic and gas-phase reaction mechanisms. Experiments in a subscale gas-turbine honeycomb catalytic reactor have shown that the foregoing reaction mechanisms were also appropriate under gas-turbine relevant conditions with short reactant residence times. The light-off behavior of the subscale honeycomb reactor was reproduced by transient 2-D CFD computations. Ignition and extinction in CPO was studied. It was shown that, despite the chemical impact of the H{sub 2}O diluent during the transient catalytic ignition event, the light-off times themselves were largely unaffected by the exhaust gas dilution

  7. Kinetic study of the hydrocarbon generation from marine carbonate source rocks characterization of products of gas and liquid hydrocarbon

    Institute of Scientific and Technical Information of China (English)

    GENG Xinhua; GENG Ansong; XIONG Yongqiang; LIU Jinzhong; ZHANG Haizu; ZHAO Qingfang

    2006-01-01

    The kinetic parameters of hydrocarbon generation from the marine carbonate source rocks were determined and calibrated through kinetic simulating experiment. The kinetic parameters of hydrocarbon generation then were extrapolated to geological condition by using the relative software.The result shows that gaseous hydrocarbons (C1, C2,C3, C4-5) were generated in condition of 150℃<T<220℃(1.0%<Ro <3.0% ). Light hydrocarbons (C6-13)and heavy hydrocarbons ( C13+) were generated in condition of 100 ℃<T<170 ℃ (0.5%<Ro<1.5%). A quantitative reference to examine the natural evolution of hydrocarbon of marine carbonate source rocks can be established through the results. It also provides a new method for evaluating the highly mature marine carbonate source rock more reasonably.

  8. Ionic Monopropellant Compatibility Study Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Candidate hydrazine alternatives have been developed for spacecraft propulsion. The U.S. Air Force AF-M315E and the Swedish ammonium dinitramide propellants have...

  9. Potential for electric power generation and gas lighting through the use of biogas from landfill; Potencial de geracao de energia eletrica e iluminacao a gas por meio do aproveitamento de biogas proveniente de aterro sanitario

    Energy Technology Data Exchange (ETDEWEB)

    Pecora, V.; Figueiredo, N.J.V.; Coelho, S.T. [Universidade de Sao Paulo (CENBIO/USP), SP (Brazil). Inst. de Eletrotecnica e Energia. Centro Nacional de Referencia em Biomassa; Velazquez, S.M.S.G. [Universidade Presbiteriana Mackenzie, Sao Paulo, SP (Brazil). Dept. de Engenharia Mecanica

    2008-07-01

    Global warming has become an important topic of global discussions due to the increasing concentration of greenhouse gases in the atmosphere, coming mainly on the burning of fossil fuels. The search for alternatives that promote the replacement of these fuels by renewable sources has been intensified in recent decades and several studies are being undertaken to ensure, for example, the efficient management and minimization of solid waste, seen as a serious problem of large Brazilians urban centers nowadays. The incorrect final disposal of solid waste entails in uncontrolled emission of gases, generated in its decomposition, and the infiltration of percolated liquid in the soil; resulting on negative impacts on people's health and on the environment, also contributing to the worsening of the greenhouse effect. In this context, this article presents the project of exploitation of biogas from the treatment of urban solid waste for generating electric power and gas lighting, developed by the Brazilian Reference Center on Biomass (CENBIO), at Caieiras Waste Treatment Centre (Essencis CTR - Caieiras). This paper describes the activities developed by CENBIO for determining the potential of electricity generation and gas lighting and, through the results, may be defined other landfills for implementation of a similar project. The use of biogas for energy generation provides the rational use of available sources, reducing dependence on external energy sources and, as the conversion of methane into carbon dioxide, promotes the reduction of emissions of greenhouse gases, since methane has the global warming potential about 20 times higher when compared to carbon dioxide. (author)

  10. Energetic-economical analysis of a stationary for energy generation with fuel cells and natural gas reforming; Analise energetico-economica de um sistema estacionario de geracao de energia com celulas a combustivel e reforma de gas natural

    Energy Technology Data Exchange (ETDEWEB)

    Furtado, Jose Geraldo de Melo; Silva Junior, Fernando Rodrigues; Silva, Cristiane Abrantes da; Soares, Guilherme Fleury Wanderley; Lopes, Francisco da Costa; Serra, Eduardo Torres [Centro de Pesquisas de Energia Eletrica (CEPEL), Rio de Janeiro, RJ (Brazil)]. E-mail: furtado@cepel.br; Codeceira Neto, Alcides [Companhia HidroEletrica do Sao Francisco (CHESF), Recife, PE (Brazil)

    2008-07-01

    Power systems based on fuel cells have been considered for residential and commercial applications in energy Distributed Generation (DG) market as these systems can minimize their acquisition, installation and operation high costs. In this work we present an experimental analysis of a power generation system formed by a 5 kW proton exchange membrane fuel cell unit and a natural gas reformer (fuel processor) for hydrogen production, of the CEPEL's Fuel Cell Laboratory. It was determined the electrical performance of the cogeneration system in function of the design and operational power plant parameters. Additionally, it was verified the influence of the activation conditions of the fuel cell electrocatalytic system on the system performance. It also appeared that the use of hydrogen produced from the natural gas catalytic reforming provided the system operation in excellent electrothermal stability conditions resulting in increase of the energy conversion efficiency and of the economicity of the cogeneration power plant. The maximum electrical efficiency achieved was around 38% and in all power range unit operated with average potential per single fuel cell higher than 0.60 V. (author)

  11. The external costs of electricity generation. A comparison of environmental damage of silicon photovoltaic electricity, produced with different electricity mixes, vs natural gas and coal

    Energy Technology Data Exchange (ETDEWEB)

    Olson, C.L.; Veltkamp, A.C.; Sinke, W.C. [ECN Solar Energy, Petten (Netherlands)

    2012-09-15

    In this paper the environmental damages of crystalline silicon photovoltaics are calculated, using the most recent photovoltaics data, and compared with those of the prevalent conventional energy technologies. A life cycle assessment of selected environmental impacts of 1kWh of electricity generated by various technologies was performed using Simapro software (version 7.2.4) in conjunction with the Ecoinvent database (version 2.2). The environmental impacts were assessed using the ReCiPe methodology. Because of the important role of coal and natural gas in the global electricity generation portfolio, special attention is given to the comparison of PV with those technologies. The environmental consequences of manufacturing PV modules with renewable, UCTE or 100% coal electricity mixes are explored. A brief update of the estimated monetarization of damages due to coal and climate change is included. A rough estimate of the true cost of coal and PV electricity is made in 2011.

  12. The generation and evolution of anisotropic gas-permeability during viscous deformation in conduit-filling ignimbrites

    Science.gov (United States)

    Kolzenburg, Stephan; Russell, Kelly

    2015-04-01

    Gas-permeability plays a governing role in the pre-explosive pressurization of volcanic edifices. Pressurization may only occur once the total volume flux of gases emitted by an underlying magmatic or hydrothermal source exceeds the flow capacity of the permeable pathways present in the edifice. We have measured the physical properties (strain, porosity, permeability and ultrasonic wave velocities) of breadcrust bombs recovered from the deposits of the 2350 B.P. eruption of Mt Meager, BC, Canada. These rocks represent a conduit-infilling pyroclastic breccia that underwent various degrees of welding and deformation and present a remarkable opportunity to constrain the nature and timescale of mechanical processes operating within explosive volcanic conduits during repose periods between eruptive cycles. Here we present data from permeability measurements along the directions of maximum and minimum shortening which help quantifying the effect of vesicle microstructure on permeability. Permeability is measured by applying a range of confining pressures (between 3.4 and 17.2 MPa) to each sample and imposing a constant head (of 0.2 to 3.5 MPa) across the sample. The permeability is then determined using a modified version of Darcy's law applicable to compressible fluids. These rocks display a profound directionality in the measured physical properties resulting from the deformation-induced fabric. For all samples the permeability across the elongation fabric is highly correlated to the sample porosity whereas along the elongation fabric there is little effect of porosity on permeability. At porosity values of about 20% the permeability seems to reach a minimum at 10-16 m2 and does not change significantly with further reduction of porosity. Further, the effect of confining pressure on the permeability of these samples appears to be more pronounced across the elongation fabric than along the elongation fabric. The deformation fabric has a significant effect on the gas

  13. Quasi-phase-matched high-harmonic generation in composites of metal nanoparticles and a noble gas

    Science.gov (United States)

    Husakou, A.; Herrmann, J.

    2014-08-01

    We theoretically study high-harmonic generation (HHG) in a composite which consists of ellipsoidal silver nanoparticles in argon. The significant field enhancement in argon in the vicinity of metal nanoparticles allows us to use much lower incident intensities than in typical HHG experiments. A periodic modulation of the nanoparticle concentration provides quasi-phase matching, which mitigates the negative effect of the significant phase mismatch. First, we study the linear optical properties of such a composite and the field enhancement and consider the technological possibilities of creating such a composite. Then the generation of high harmonics is simulated using a propagation equation which includes field enhancement, phase mismatch, absorption of the pump beam and harmonics, and other relevant effects. Generation of harmonics with an efficiency above 10-7 is predicted.

  14. Analysis of copper losses throughout weak acid effluent flows generated during off-gas treatment in the New Copper Smelter RTB Bor

    Directory of Open Access Journals (Sweden)

    Dragana Ivšić-Bajčeta

    2013-09-01

    Full Text Available The previous inadequate treatment of off-gas in RTB Bor in Serbia has resulted in serious pollution of the environment and the possibly high losses of copper through the effluent flows. The project of New Copper Smelter RTB Bor, besides the new flash smelting furnace (FSF and the reconstruction of Pierce-Smith converter (PSC, includes more effective effluent treatment. Paper presents an analysis of the new FSF and PSC off-gas treatment, determination of copper losses throughout generated wastewaters and discussion of its possible valorization. Assumptions about the solubility of metals phases present in the FSF and PSC off-gas, obtained by the treatment process simulation, were compared with the leaching results of flue dusts. Determined wastewaters characteristics indicate that the PSC flow is significantly richer in copper, mostly present in insoluble metallic/sulfide form, while the FSF flow has low concentration of copper in the form of completely soluble oxide/sulfate. The possible scenario for the copper valorization, considering arsenic and lead as limiting factors, is the separation of the FSF and PSC flows, return of the metallic/sulfide solid phase to the smelting process and recovery from the sulfate/oxide liquid phase.

  15. Generation of multi-charged high current ion beams using the SMIS 37 gas-dynamic electron cyclotron resonance (ECR) ion source

    Energy Technology Data Exchange (ETDEWEB)

    Dorf, M. A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Zorin, V. G. [Russian Academy of Sciences (RAS), Nizhny Novgorod (Russian Federation). Inst. of Applied Physics; Sidorov, A. V. [Russian Academy of Sciences (RAS), Nizhny Novgorod (Russian Federation). Inst. of Applied Physics; Bokhanov, A. F. [Russian Academy of Sciences (RAS), Nizhny Novgorod (Russian Federation). Inst. of Applied Physics; Izotov, I. V. [Russian Academy of Sciences (RAS), Nizhny Novgorod (Russian Federation). Inst. of Applied Physics; Razin, S. V. [Russian Academy of Sciences (RAS), Nizhny Novgorod (Russian Federation). Inst. of Applied Physics; Skalyga, V. A. [Russian Academy of Sciences (RAS), Nizhny Novgorod (Russian Federation). Inst. of Applied Physics

    2013-06-02

    A gas-dynamic ECR ion source (GaDIS) is distinguished by its ability to produce high current and high brightness beams of moderately charged ions. Contrary to a classical ECR ion source where the plasma confinement is determined by the slow electron scattering into an empty loss-cone, the higher density and lower electron temperature in a GaDIS plasma lead to an isotropic electron distribution with the confinement time determined by the prompt gas-dynamic flow losses. As a result, much higher ion fluxes are available, however a decrease in the confinement time of the GaDIS plasma lowers the ion charge state. The gas-dynamic ECR ion source concept has been successfully realized in the SMIS 37 experimental facility operated at the Institute of Applied Physics, Russia. The use of high-power (~100 kW) microwave (37.5 GHz) radiation provides a dense plasma (~1013 cm-3) with a relatively low electron temperature (~50- 100 eV) and allows for the generation of high current (~1 A/cm2) beams of multi-charged ions. In this work we report on the present status of the SMIS 37 ion source and discuss the advanced numerical modeling of ion beam extraction using the particle-in-cell code WARP

  16. Generation of multi-charged high current ion beams using the SMIS 37 gas-dynamic electron cyclotron resonance (ECR) ion source

    Energy Technology Data Exchange (ETDEWEB)

    Dorf, M.A., E-mail: dorf1@llnl.gov [Lawrence Livermore National Laboratory, Livermore, CA 94550 (United States); Zorin, V.G.; Sidorov, A.V.; Bokhanov, A.F.; Izotov, I.V.; Razin, S.V.; Skalyga, V.A. [Institute of Applied Physics RAS, 46 Ulyanov Street, 603950 Nizhny Novgorod (Russian Federation)

    2014-01-01

    A gas-dynamic ECR ion source (GaDIS) is distinguished by its ability to produce high current and high brightness beams of moderately charged ions. Contrary to a classical ECR ion source where the plasma confinement is determined by the slow electron scattering into an empty loss-cone, the higher density and lower electron temperature in a GaDIS plasma lead to an isotropic electron distribution with the confinement time determined by the prompt gas-dynamic flow losses. As a result, much higher ion fluxes are available; however a decrease in the confinement time of the GaDIS plasma lowers the ion charge state. The gas-dynamic ECR ion source concept has been successfully realized in the SMIS 37 experimental facility operated at the Institute of Applied Physics, Russia. The use of high-power (∼100 kW) microwave (37.5 GHz) radiation provides a dense plasma (∼10{sup 13} cm{sup −3}) with a relatively low electron temperature (∼50–100 eV) and allows for the generation of high current (∼1 A/cm{sup 2}) beams of multi-charged ions. In this work we report on the present status of the SMIS 37 ion source and discuss the advanced numerical modeling of ion beam extraction using the particle-in-cell code WARP.

  17. A model for coupled electro-hydro-mechanical processes in fine grained soils accounting for gas generation and transport

    Energy Technology Data Exchange (ETDEWEB)

    Tamagnini, Claudio; Cattaneo, Fabio [Universita degli Studi di Perugia (Italy). Dept. of Civil and Environmental Engineering; Jommi, Cristina [Politecnico di Milano (Italy). Dept. of Structural Engineering

    2010-07-01

    A theoretical and numerical model is developed for the quantitative analysis of coupled processes taking place in active waste containment systems, such as electrokinetic barriers or fences, in which a low intensity D C current is circulated across the clay barrier to move polar and non-polar contaminants. A novel feature of the proposed approach is the allowance for the presence of air in the pore space. Under unsaturated conditions, all transport coefficients involved in the electrokinetic process are strongly dependent on the degree of saturation of pore liquid. In order to assess the predictive capability of the proposed theory and to appreciate the impact of gas production at the electrodes, a series of numerical simulations of simple one dimensional electrokinetic tests have been performed. The results of the simulations compare reasonably well with data obtained from laboratory experiments performed on an illitic clayey silt. The numerical results indicate that the impact of gas production at the electrodes can be significant, even in low-intensity and short-duration treatments. (author)

  18. Photophysics of sunscreen molecules in the gas phase: a stepwise approach towards understanding and developing next-generation sunscreens

    Science.gov (United States)

    Rodrigues, Natércia D. N.; Staniforth, Michael; Stavros, Vasilios G.

    2016-11-01

    The relationship between exposure to ultraviolet (UV) radiation and skin cancer urges the need for extra photoprotection, which is presently provided by widespread commercially available sunscreen lotions. Apart from having a large absorption cross section in the UVA and UVB regions of the electromagnetic spectrum, the chemical absorbers in these photoprotective products should also be able to dissipate the excess energy in a safe way, i.e. without releasing photoproducts or inducing any further, harmful, photochemistry. While sunscreens are tested for both their photoprotective capability and dermatological compatibility, phenomena occurring at the molecular level upon absorption of UV radiation are largely overlooked. To date, there is only a limited amount of information regarding the photochemistry and photophysics of these sunscreen molecules. However, a thorough understanding of the intrinsic mechanisms by which popular sunscreen molecular constituents dissipate excess energy has the potential to aid in the design of more efficient, safer sunscreens. In this review, we explore the potential of using gas-phase frequency- and time-resolved spectroscopies in an effort to better understand the photoinduced excited-state dynamics, or photodynamics, of sunscreen molecules. Complementary computational studies are also briefly discussed. Finally, the future outlook of expanding these gas-phase studies into the solution phase is considered.

  19. Magnetogasdynamic shock wave generated by a moving piston in a rotational axisymmetric isothermal flow of perfect gas with variable density

    Science.gov (United States)

    Nath, G.

    2011-05-01

    The propagation of a strong cylindrical shock wave in an ideal gas with azimuthal magnetic field, and with or without axisymmetric rotational effects, is investigated. The shock wave is driven out by a piston moving with time according to power law. The ambient medium is assumed to have radial, axial and azimuthal component of fluid velocities. The fluid velocities, the initial density and the initial magnetic field of the ambient medium are assumed to be varying and obey power laws. Solutions are obtained, when the flow between the shock and the piston is isothermal. The gas is assumed to have infinite electrical conductivity and the angular velocity of the ambient medium is assumed to be decreasing as the distance from the axis increases. It is expected that such an angular velocity may occur in the atmospheres of rotating planets and stars. The shock wave moves with variable velocity and the total energy of the wave is non-constant. The effects of variation of the initial density and the Alfven-Mach number on the flow-field are obtained. A comparison is also made between rotating and non-rotating cases.

  20. The effects of the location of Au additives on combustion-generated SnO(2) nanopowders for CO gas sensing.

    Science.gov (United States)

    Bakrania, Smitesh D; Wooldridge, Margaret S

    2010-01-01

    The current work presents the results of an experimental study of the effects of the location of gold additives on the performance of combustion-generated tin dioxide (SnO(2)) nanopowders in solid state gas sensors. The time response and sensor response to 500 ppm carbon monoxide is reported for a range of gold additive/SnO(2) film architectures including the use of colloidal, sputtered, and combustion-generated Au additives. The opportunities afforded by combustion synthesis to affect the SnO(2)/additive morphology are demonstrated. The best sensor performance in terms of sensor response (S) and time response (τ) was observed when the Au additives were restricted to the outermost layer of the gas-sensing film. Further improvement was observed in the sensor response and time response when the Au additives were dispersed throughout the outermost layer of the film, where S = 11.3 and τ = 51 s, as opposed to Au localized at the surface, where S = 6.1 and τ = 60 s.