WorldWideScience

Sample records for monocrystalline cast polycrystalline

  1. Methods and apparatus for manufacturing monocrystalline cast silicon and monocrystalline cast silicon bodies for photovoltaics

    Science.gov (United States)

    Stoddard, Nathan G

    2014-01-14

    Methods and apparatuses are provided for casting silicon for photovoltaic cells and other applications. With such methods and apparatuses, a cast body of monocrystalline silicon may be formed that is free of, or substantially free of, radially-distributed impurities and defects and having at least two dimensions that are each at least about 35 cm is provided.

  2. Methods and apparatuses for manufacturing monocrystalline cast silicon and monocrystalline cast silicon bodies for photovoltaics

    Science.gov (United States)

    Stoddard, Nathan G.

    2011-11-01

    Methods and apparatuses are provided for casting silicon for photovoltaic cells and other applications. With such methods and apparatuses, a cast body of monocrystalline silicon may be formed that is free of, or substantially free of, radially-distributed impurities and defects and having at least two dimensions that are each at least about 35 cm is provided.

  3. Mechanical properties of monocrystalline and polycrystalline monolayer black phosphorus

    Science.gov (United States)

    Cao, Pinqiang; Wu, Jianyang; Zhang, Zhisen; Ning, Fulong

    2017-01-01

    The mechanical properties of monocrystalline and polycrystalline monolayer black phosphorus (MBP) are systematically investigated using classic molecular dynamic simulations. For monocrystalline MBP, it is found that the shear strain rate, sample dimensions, temperature, atomic vacancies and applied statistical ensemble affect the shear behaviour. The wrinkled morphology is closely connected with the direction of the in-plane shear, dimensions of the samples, and applied ensembles. Particularly, small samples subjected to loading/unloading of the shear deformation along the armchair direction demonstrate a clear mechanical hysteresis loop. For polycrystalline MBP, the maximum shear stress as a function of the average grain size follows an inverse pseudo Hall-Petch type relationship under an isothermal-isobaric (NPT) ensemble, whereas under a canonical (NVT) ensemble, the maximum shear stress of polycrystalline MBP exhibits a ‘flipped’ behaviour. Furthermore, polycrystalline MBP subjected to uniaxial tension also exhibits a strongly grain size-dependent mechanical response, and it can fail by brittle intergranular and transgranular fractures because of its weaker grain boundary structures and the direction-dependent edge energy, respectively. These findings provide useful insight into the mechanical design of BP for nanoelectronic devices.

  4. Single-Seed Casting Large-Size Monocrystalline Silicon for High-Efficiency and Low-Cost Solar Cells

    Directory of Open Access Journals (Sweden)

    Bing Gao

    2015-09-01

    Full Text Available To grow high-quality and large-size monocrystal-line silicon at low cost, we proposed a single-seed casting technique. To realize this technique, two challenges—polycrystalline nucleation on the crucible wall and dislocation multiplication inside the crystal—needed to be addressed. Numerical analysis was used to develop solutions for these challenges. Based on an optimized furnace structure and operating conditions from numerical analysis, experiments were performed to grow monocrystalline silicon using the single-seed casting technique. The results revealed that this technique is highly superior to the popular high-performance multicrystalline and multiseed casting mono-like techniques.

  5. Casting larger polycrystalline silicon ingots

    Energy Technology Data Exchange (ETDEWEB)

    Wohlgemuth, J.; Tomlinson, T.; Cliber, J.; Shea, S.; Narayanan, M.

    1995-08-01

    Solarex has developed and patented a directional solidification casting process specifically designed for photovoltaics. In this process, silicon feedstock is melted in a ceramic crucible and solidified into a large grained semicrystalline silicon ingot. In-house manufacture of low cost, high purity ceramics is a key to the low cost fabrication of Solarex polycrystalline wafers. The casting process is performed in Solarex designed casting stations. The casting operation is computer controlled. There are no moving parts (except for the loading and unloading) so the growth process proceeds with virtually no operator intervention Today Solarex casting stations are used to produce ingots from which 4 bricks, each 11.4 cm by 11.4 cm in cross section, are cut. The stations themselves are physically capable of holding larger ingots, that would yield either: 4 bricks, 15 cm by 15 an; or 9 bricks, 11.4 cm by 11.4 an in cross-section. One of the tasks in the Solarex Cast Polycrystalline Silicon PVMaT Program is to design and modify one of the castings stations to cast these larger ingots. If successful, this effort will increase the production capacity of Solarex`s casting stations by 73% and reduce the labor content for casting by an equivalent percentage.

  6. A Power Case Study for Monocrystalline and Polycrystalline Solar Panels in Bursa City, Turkey

    Directory of Open Access Journals (Sweden)

    Ayşegül Taşçıoğlu

    2016-01-01

    Full Text Available It was intended to reveal the time dependent power generation under different loads for two different solar panels under the conditions of Bursa province in between August 19 and 25, 2014. The testing sets include solar panels, inverter, multimeter, accumulator, regulator, pyranometer, pyrheliometer, temperature sensor, and datalogger. The efficiency of monocrystalline and polycrystalline solar panels was calculated depending on the climatic data’s measurements. As the result of the study, the average performances of monocrystalline and polycrystalline panels are 42.06 and 39.80 Wh, respectively. It was seen that 87.14 W instantaneous power could be obtained from monocrystalline solar panel and that 80.17 W instantaneous power could be obtained from polycrystalline solar panel under maximum total radiation (1001.13 W/m2. Within this frame, it was determined that monocrystalline solar panel is able to operate more efficiently under the conditions of Bursa compared to polycrystalline solar panel. When the multivariate correlations coefficients were examined statistically, a significant relationship in positive direction was detected between total and direct radiation and ambient temperature on energy generation from monocrystalline and polycrystalline panel.

  7. Connections between morphological and mechanical evolution during galvanic corrosion of micromachined polycrystalline and monocrystalline silicon

    Science.gov (United States)

    Miller, David C.; Boyce, Brad L.; Kotula, Paul G.; Stoldt, Conrad R.

    2008-06-01

    Many microsystems fabrication technologies currently employ a metallic overlayer, such as gold, in electrical contact with silicon structural layers. During postprocessing in hydrofluoric-based acid solutions, a galvanic cell is created between the silicon and the metallic layer. Micromachined tensile specimens reveal that such etching in the presence of a galvanic cell can cause a catastrophic reduction in the tensile strength and apparent modulus of silicon. Detailed failure analysis was also used to compare fractured corroded Si to otherwise identical reference specimens via surface based (electron and scanning probe) microscopy as well as cross-section based structural- and composition-characterization techniques. For both polycrystalline and single-crystal silicon, galvanic corrosion can result in a thick corroded surface layer created via porous silicon formation, and/or generalized material removal depending on the etch chemistry and conditions. Under certain etching conditions, the porous silicon formation process results in cavity formation as well as preferential grain-boundary attack leading to intergranular fracture. The nature and severity of corrosion damage are shown to be influenced by the surface wetting characteristics of the etch chemistry, with poor wetting resulting in localized attack facilitated by the microstructure and good wetting resulting in generalized attack. The measured stiffness of the tensile specimens can be used to determine the effective modulus and porosity of the corroded surface layer. Extending beyond previous investigations, the present work examines the quantitative connection between the choice of chemical etchant, the corresponding damage morphology, and the resulting degradation in strength and apparent modulus. The present work also uniquely identifies important differences in polycrystalline and single-crystal Si based on their disparate damage evolution and related mechanical performance.

  8. A study of defect evolution in multi-energy helium implanted monocrystalline and polycrystalline silicon

    Energy Technology Data Exchange (ETDEWEB)

    Abrams, K.J.; Donnelly, S.E. [Institute for Materials Research, University of Salford (United Kingdom); Beaufort, M.F. [Laboratoire de Metallurgie Physique, UMR 6630, Universite de Poitiers, Futuroscope-Chasseneuill (France); Terry, J.; Haworth, L.I. [Scottish Microelectronics Centre, University of Edinburgh (United Kingdom); Alquier, D. [Universite Francois Rabelais Tours, L.M.P, Tours (France)

    2009-08-15

    Upon implantation, He ions interact with radiation damage in metals and semiconductors to form bubbles (V. Raineri, Phys. Rev. B 2, 937 (2000)). As far as Si is concerned, recent literature contains much information on the effects of ion implantation, defect formation and the transport of point defects in He-irradiated crystalline silicon (c-Si) whereas little information exists on the effects of He implantation on polycrystalline Si (poly-Si). This paper reports on a systematic comparison of the effects of He implantation on c-Si and poly-Si. Interesting and significant differences were observed in the defect morphology in the two cases. Results on the differences between the two materials are presented and discussed in terms of the role that grain boundaries in poly-Si play in trapping interstitials and the effects that this may have on the overall defect morphology. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  9. Thermomechanical fatigue crack growth in a cast polycrystalline superalloy

    Directory of Open Access Journals (Sweden)

    Moverare Johan J.

    2014-01-01

    Full Text Available Thermomechanical fatigue (TMF crack growth testing has been performed on the polycrystalline superalloy IN792. All tests were conducted in mechanical strain control in the temperature range between 100 and 750 °C. The influence of in-phase (IP and out-of-phase (OP TMF cycles was investigated as well as the influence of applying extended dwell times (up to 6 hours at the maximum temperature. The crack growth rates were also evaluated based on linear elastic fracture mechanics and described as a function of the stress intensity factor KI. Without dwell time at the maximum temperature, the crack growth rates are generally higher for the OP-TMF cycle compared to the IP-TMF cycle, when equivalent nominal strain ranges are compared. However, due to the fact that the tests were conducted in mechanical strain control, the stress response is very different for the IP and OP cycles. Also the crack closure level differs significantly between the cycle types. By taking the stress response into account and comparing the crack growth rates for equivalent effective stress intensity factor rages ΔKeff defined as Kmax − Kclosure, very similar crack growth rates were actually noticed independent of whether an IP or OP cycle were used. While the introduction of a 6 hour dwell time significantly increased the crack growth rates for the IP-TMF cycle, a decrease in crack growth rates versus ΔKeff were actually seen for the OP-TMF cycle. The fracture behaviour during the different test conditions has been investigated using scanning electron microscopy.

  10. Development of brazing foils to join monocrystalline tungsten alloys with ODS-EUROFER steel

    Energy Technology Data Exchange (ETDEWEB)

    Kalin, B.A. [Moscow Engineering Physics Institute (State University), 31 Kashirskoye Sh., Moscow 115409 (Russian Federation)]. E-mail: BAKalin@mephi.ru; Fedotov, V.T. [Moscow Engineering Physics Institute (State University), 31 Kashirskoye Sh., Moscow 115409 (Russian Federation); Sevrjukov, O.N. [Moscow Engineering Physics Institute (State University), 31 Kashirskoye Sh., Moscow 115409 (Russian Federation); Kalashnikov, A.N. [Moscow Engineering Physics Institute (State University), 31 Kashirskoye Sh., Moscow 115409 (Russian Federation); Suchkov, A.N. [Moscow Engineering Physics Institute (State University), 31 Kashirskoye Sh., Moscow 115409 (Russian Federation); Moeslang, A. [Forschungszentrum Karlsruhe, Institut fuer Materialforschung I, 76021 Karlsruhe (Germany); Rohde, M. [Forschungszentrum Karlsruhe, Institut fuer Materialforschung I, 76021 Karlsruhe (Germany)

    2007-08-01

    Results on rapidly solidified filler metals for brazing W with W and monocrystalline W with EUROFER steel (FS) are presented. Rapidly quenched powder-type filler metals based on Ti{sub bal}-V-Cr-Be were developed to braze polycrystalline W with monocrystalline W. In addition, Fe{sub bal}-Ta-Ge-Si-B-Pd alloys were developed to braze monocrystalline W with FS for helium gas cooled divertors and plasma-facing components. The W to FS brazed joints were fabricated under vacuum at 1150 {sup o}C, using a Ta spacer of 0.1 mm in thickness to account for the different thermal expansions. The monocrystalline tungsten as well as the related brazed joints withstood 30 cycles between 750 {sup o}C/20 min and air cooling/3-5 min.

  11. Cast polycrystalline silicon photovoltaic module manufacturing technology improvements. Annual subcontract report, 1 January 1996--31 December 1996

    Energy Technology Data Exchange (ETDEWEB)

    Wohlgemuth, J. [Solarex Corp., Frederick, MD (United States)

    1997-10-01

    This report describes Solarex`s accomplishments during this phase of the Photovoltaic Manufacturing Technology (PVMaT) program. During this reporting period, Solarex researchers converted 79% of production casting stations to increase ingot size and operated them at equivalent yields and cell efficiencies; doubled the casting capacity at 20% the cost of buying new equipment to achieve the same capacity increase; operated the wire saws in a production mode with higher yields and lower costs than achieved on the ID saws; purchased additional wire saws; developed and qualified a new wire-guide coating material that doubles the wire-guide lifetime and produces significantly less scatter in wafer thickness; ran an Al paste back-surface-field process on 25% of all cells in manufacturing; completed environmental qualification of modules using cells produced by an all-print metallization process; qualified a vendor-supplied Tedlar/ethylene vinyl acetate (EVA) laminate to replace the combination of separate sheets of EVA and Tedlar backsheet; substituted RTV adhesive for the 3M Very High Bond tape after several field problems with the tape; demonstrated the operation of a prototype unit to trim/lead attach/test modules; demonstrated the use of light soldering for solar cells; demonstrated the operation of a wafer pull-down system for cassetting wet wafers; and presented three PVMaT-related papers at the 25th IEEE Photovoltaic Specialists Conference.

  12. Low yield sputtering of monocrystalline metals

    NARCIS (Netherlands)

    Veen, A. van; Fluit, J.M.

    1980-01-01

    Sputtering of monocrystalline metals by light noble gas ions is studied experimentally and theoretically at low primary ion energy. Evidence is found for a multiple collision process in which surface atoms are sputtered by backscattered ions. The introduction of the maximum recoil energy EM in the s

  13. <1 1 0> Directional growth of polycrystalline magnetostrictive Tb{sub x}Dy{sub 1-x}Fe{sub y} compounds by casting in a strong unidirectional gradient

    Energy Technology Data Exchange (ETDEWEB)

    Bonino, Olivier E-mail: bonino@labs.polycnrs-gre.frolivier.bonino@cea.fr; Rango, Patricia de; Tournier, Robert

    2000-03-01

    Rods of highly magnetostrictive polycrystalline Tb{sub x}Dy{sub 1-x}Fe{sub y} materials are elaborated by casting in a cylindrical mould with cooling imposed from the bottom which leads to a fast vertical unidirectional growth. A <1 1 0> orientation is obtained along the axis of the rods parallel to the growth direction. The magnetostrictive properties are remarkable along the rods axis comparable to those of <1 1 1> rods. The saturated magnetostriction measured in a parallel magnetic field is {lambda}{sub parallel}=1124x10{sup -6} under 0 MPa and increases to 1760x10{sup -6} under a compressive stress of 25 MPa. The pseudolinear variation of the magnetostriction with the internal magnetic field {delta}{lambda}{sub parallel}/{mu}{sub 0}{delta}H{sub int} reaches 640x10{sup -6}/0.04 T under 9.9 MPa. The texture and the good magnetostrictive properties are reproducible.

  14. Polycrystalline strengthening

    DEFF Research Database (Denmark)

    Hansen, Niels

    1985-01-01

    . The strength-grain size relationships can be described in a number of empirical equations relating the yield stress and the flow stress in tension to various structural parameters. A number of such equations are reviewed and their predictive capability is discussed. Structural information of importance...... found, and this structural information is correlated with a number of strength structural equations. Finally, the flow stress of fcc and bcc polycrystalline specimens is related to the occurrence of microstructures formed by macroscopic and microscopic strain accommodation processes during plastic...... for the understanding of polycrystalline strengthening is obtained mainly from surface relief patterns and from bulk structures observed by transmission electron microscopy of thin foils. The results obtained by these methods are discussed and correlations are proposed. A number of features characterizing the deformed...

  15. Wetting of Au and Ag particles on monocrystalline graphite substrates

    Institute of Scientific and Technical Information of China (English)

    Joonho Lee; Toshihiro Tanaka; Kazufumi Seo; Nobumitsu Hirai; Jung-Goo Lee; Hirotaro Mori

    2006-01-01

    The wetting behavior of Au and Ag particles on a monocrystalline graphite substrate was investigated using the microscopic sessile drop method under a purified Ar atmosphere at 1300 K. The measured contact angles of the liquid Au and Ag on monocrystalline graphite substrates of (0001) face were 129° and 124°, respectively. It is believed that the interaction at the interface is dominated by the physical bonding (van der Waal's interaction).

  16. The effect of the polycrystalline furnace in Mono -like growth process

    Institute of Scientific and Technical Information of China (English)

    Li Liu; Zhenzhen Yao; Yan Feng Ning; Xie Min Peng

    2015-01-01

    In this work,we found that the polycrystalline furnace of the thermal field simulation,which has a very important role in this class the growth of monocrystalline silicon.The software is Fluent.Polycrystalline furnace thermal field change process is closely related to the nucleation.we have improved the ration of the grain crystal,and reduce the height of the seed crystal.It is proved that the electrical of the mono like wafer is rather perfect,and the efficiency of the cell is improved greatly.The simulation cal-culation is well agree with the experimental results.

  17. Solar cells, structures including organometallic halide perovskite monocrystalline films, and methods of preparation thereof

    KAUST Repository

    Bakr, Osman M.

    2017-03-02

    Embodiments of the present disclosure provide for solar cells including an organometallic halide perovskite monocrystalline film (see fig. 1.1B), other devices including the organometallic halide perovskite monocrystalline film, methods of making organometallic halide perovskite monocrystalline film, and the like.

  18. Transformation of polycrystalline tungsten to monocrystalline tungsten W(100) and its potential application in Schottky emitters

    NARCIS (Netherlands)

    Dokania, A.K.; Hendrikx, R.; Kruit, P.

    2009-01-01

    The electron sources in electron microscopes and electron lithography machines often consist of small diameter W(100) wires, etched to form a sharp tip. The electron emission is facilitated by the Schottky effect, thus the name Schottky emitter. The authors are investigating the feasibility of array

  19. Monocrystalline solar cells are gaining ground; Monokristallin im Aufwind

    Energy Technology Data Exchange (ETDEWEB)

    Bernreuter, Johannes

    2011-10-31

    Increasingly, manufacturers use selective emitters for serial production of solar cells of monocrystalline silicon with an efficiency of 19 percent. Strong competition will soon have them reach 20 percent. For the same reason, copper will become a substitute for expensive silver front contacts.

  20. Polarization effects in femtosecond laser induced amorphization of monocrystalline silicon

    Science.gov (United States)

    Bai, Feng; Li, Hong-Jin; Huang, Yuan-Yuan; Fan, Wen-Zhong; Pan, Huai-Hai; Wang, Zhuo; Wang, Cheng-Wei; Qian, Jing; Li, Yang-Bo; Zhao, Quan-Zhong

    2016-10-01

    We have used femtosecond laser pulses to ablate monocrystalline silicon wafer. Raman spectroscopy and X-ray diffraction analysis of ablation surface indicates horizontally polarized laser beam shows an enhancement in amorphization efficiency by a factor of 1.6-1.7 over the circularly polarized laser ablation. This demonstrates that one can tune the amorphization efficiency through the polarization of irradiation laser.

  1. Sunlight-thin nanophotonic monocrystalline silicon solar cells

    Science.gov (United States)

    Depauw, Valérie; Trompoukis, Christos; Massiot, Inès; Chen, Wanghua; Dmitriev, Alexandre; Cabarrocas, Pere Roca i.; Gordon, Ivan; Poortmans, Jef

    2017-09-01

    Introducing nanophotonics into photovoltaics sets the path for scaling down the surface texture of crystalline-silicon solar cells from the micro- to the nanoscale, allowing to further boost the photon absorption while reducing silicon material loss. However, keeping excellent electrical performance has proven to be very challenging, as the absorber is damaged by the nanotexturing and the sensitivity to the surface recombination is dramatically increased. Here we realize a light-wavelength-scale nanotextured monocrystalline silicon cell with the confirmed efficiency of 8.6% and an effective thickness of only 830 nm. For this we adopt a self-assembled large-area and industry-compatible amorphous ordered nanopatterning, combined with an advanced surface passivation, earning strongly enhanced solar light absorption while retaining efficient electron collection. This prompts the development of highly efficient flexible and semitransparent photovoltaics, based on the industrially mature monocrystalline silicon technology.

  2. Hollow carbon nanobubbles: monocrystalline MOF nanobubbles and their pyrolysis.

    Science.gov (United States)

    Zhang, Wei; Jiang, Xiangfen; Zhao, Yanyi; Carné-Sánchez, Arnau; Malgras, Victor; Kim, Jeonghun; Kim, Jung Ho; Wang, Shaobin; Liu, Jian; Jiang, Ji-Sen; Yamauchi, Yusuke; Hu, Ming

    2017-05-01

    While bulk-sized metal-organic frameworks (MOFs) face limits to their utilization in various research fields such as energy storage applications, nanoarchitectonics is believed to be a possible solution. It is highly challenging to realize MOF nanobubbles with monocrystalline frameworks. By a spatially controlled etching approach, here, we can achieve the synthesis of zeolitic imidazolate framework (ZIF-8) nanobubbles with a uniform size of less than 100 nm. Interestingly, the ZIF-8 nanobubbles possess a monocrystalline nanoshell with a thickness of around 10 nm. Under optimal pyrolytic conditions, the ZIF-8 nanobubbles can be converted into hollow carbon nanobubbles while keeping their original shapes. The structure of the nanobubble enhances the fast Na(+)/K(+) ion intercalation performance. Such remarkable improvement cannot be realized by conventional MOFs or their derived carbons.

  3. Thin film polycrystalline silicon photoelectric converter and fabricating method; Hakumaku takkesho shirikon koden henkan sochi oyobi sono seizo hoho

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, K. [Kobe (Japan); Suzuki, T. [Kobe (Japan); Yoshimi, M. [Kobe (Japan)

    1995-04-07

    This invention relates to a fabricating method for a thin film polycrystalline silicon photoelectric converter which has a large area and can be produced at low cost. Successive formation of mono-conductive polycrystalline silicon thin film and reverse conducting polycrystalline silicon thin film on a translucent substrate requires no vapor phase epitaxial growth, and the film formation temperature for silicon thin film can be lowered. Orientation of the monocrystalline silicon thin film to any of the surface bearings of (100), (111), and (110) results in the function of determining the orientation of the reverse conducting polycrystalline silicon thin film formed thereon. This orientation is effective to obtain excellent characteristics, and results in effective surface orientation of the entire power generating area. In addition, the supporting substrate and the surface protective film of the solar cell can be combined by orienting the translucent substrate side to the light incident side. 2 figs., 1 tab.

  4. Negative refraction at deep-ultraviolet frequency in monocrystalline graphite

    OpenAIRE

    Sun, Jingbo; Zhou, Ji; Kang, Lei; Wang, Rui; Meng, Xianguo; Li, Bo; Kang, Feiyu; Li, Longtu

    2010-01-01

    Negative refraction is such a prominent electromagnetic phenomenon that most researchers believe it can only occur in artificially engineered metamaterials. In this article, we report negative refraction for all incident angles for the first time in a naturally existing material. Using ellipsometry measurement of the equifrequency contour in the deep-ultraviolet frequency region (typically 254 nm), obvious negative refraction was demonstrated in monocrystalline graphite for incident angles ra...

  5. NANOSCALE CUTTING OF MONOCRYSTALLINE SILICON USING MOLECULAR DYNAMICS SIMULATION

    Institute of Scientific and Technical Information of China (English)

    LI Xiaoping; CAI Minbo; RAHMAN Mustafizur

    2007-01-01

    It has been found that the brittle material, monocrystalline silicon, can be machined in ductile mode in nanoscale cutting when the tool cutting edge radius is reduced to nanoscale and the undeformed chip thickness is smaller than the tool edge radius. In order to better understand the mechanism of ductile mode cutting of silicon, the molecular dynamics (MD) method is employed to simulate the nanoscale cutting of monocrystalline silicon. The simulated variation of the cutting forces with the tool cutting edge radius is compared with the cutting force results from experimental cutting tests and they show a good agreement. The results also indicate that there is silicon phase transformation from monocrystalline to amorphous in the chip formation zone that can be used to explain the cause of ductile mode cutting. Moreover, from the simulated stress results, the two necessary conditions of ductile mode cutting, the tool cutting edge radius are reduced to nanoscale and the undeformed chip thickness should be smaller than the tool cutting edge radius, have been explained.

  6. Polishing of dental porcelain by polycrystalline diamond.

    Science.gov (United States)

    Nakamura, Yoshiharu; Sato, Hideaki; Ohtsuka, Masaki; Hojo, Satoru

    2010-01-01

    Polycrystalline diamond (PCD) exhibits excellent abrasive characteristics and is commonly used as loose grains for precision machining of hard ceramics and other materials that are difficult to grind and polish. In the present study, we investigated using bonded PCD for polishing dental porcelain, for which a lustrous surface is difficult to obtain by polishing. We compared the surface texture and characteristics of dental porcelain after polishing with bonded PCD with that obtained using bonded monocrystalline diamond (MCD), which is commonly used for this purpose. Polishing was performed at various pressures and rotational speeds on a custom-built polishing apparatus using bonded PCD or MCD with grain sizes of 3.92 μm on specimens consisting of VITA Omega 900 dentin porcelain after firing and then glazing to a specified surface roughness. The surface roughness of the polished porcelain and the abrasion quantity in terms of its polishing depth were measured, and its surface texture and characteristics were investigated. At low polishing pressures, PCD yielded a finer polished surface than MCD. The polishing depth after polishing for 20-30 min was approximately 2-3 μm with PCD and 1-2 μm with MCD. The polished surface was more uniform and smooth with PCD than with MCD.

  7. On the texturization of monocrystalline silicon with sodium carbonate solutions

    Energy Technology Data Exchange (ETDEWEB)

    Vallejo, B.; Gonzalez-Manas, M.; Martinez-Lopez, J.; Caballero, M.A. [Departamento de Cristalografia, Facultad de Ciencias, Universidad de Cadiz, 11510 Puerto Real (Spain)

    2007-05-15

    The texturization of monocrystalline silicon wafers using sodium carbonate solution has been investigated. This etching process has been evaluated in terms of the surface morphology and the reflectance value. The results show that for low concentration of sodium carbonate the increase of texturing time decreases the reflectance value because of the change in morphology from hillocks to pyramidal; on the contrary for intermediate and high concentrations the increase of time has a detrimental effect on texturization because it increases both the pyramid sizes and their non-uniform distribution. However, a good cell performance could be obtained by etching at high concentrations and short times. (author)

  8. Recrystallization of polycrystalline silicon

    Science.gov (United States)

    Lall, C.; Kulkarni, S. B.; Graham, C. D., Jr.; Pope, D. P.

    1981-01-01

    Optical metallography is used to investigate the recrystallization properties of polycrystalline semiconductor-grade silicon. It is found that polycrystalline silicon recrystallizes at 1380 C in relatively short times, provided that the prior deformation is greater than 30%. For a prior deformation of about 40%, the recrystallization process is essentially complete in about 30 minutes. Silicon recrystallizes at a substantially slower rate than metals at equivalent homologous temperatures. The recrystallized grain size is insensitive to the amount of prestrain for strains in the range of 10-50%.

  9. High frequency guided wave propagation in monocrystalline silicon wafers

    Science.gov (United States)

    Pizzolato, Marco; Masserey, Bernard; Robyr, Jean-Luc; Fromme, Paul

    2017-04-01

    Monocrystalline silicon wafers are widely used in the photovoltaic industry for solar panels with high conversion efficiency. The cutting process can introduce micro-cracks in the thin wafers and lead to varying thickness. High frequency guided ultrasonic waves are considered for the structural monitoring of the wafers. The anisotropy of the monocrystalline silicon leads to variations of the wave characteristics, depending on the propagation direction relative to the crystal orientation. Full three-dimensional Finite Element simulations of the guided wave propagation were conducted to visualize and quantify these effects for a line source. The phase velocity (slowness) and skew angle of the two fundamental Lamb wave modes (first anti-symmetric mode A0 and first symmetric mode S0) for varying propagation directions relative to the crystal orientation were measured experimentally. Selective mode excitation was achieved using a contact piezoelectric transducer with a custom-made wedge and holder to achieve a controlled contact pressure. The out-of-plane component of the guided wave propagation was measured using a noncontact laser interferometer. Good agreement was found with the simulation results and theoretical predictions based on nominal material properties of the silicon wafer.

  10. Ultrasmooth, Highly Spherical Monocrystalline Gold Particles for Precision Plasmonics

    KAUST Repository

    Lee, You-Jin

    2013-12-23

    Ultrasmooth, highly spherical monocrystalline gold particles were prepared by a cyclic process of slow growth followed by slow chemical etching, which selectively removes edges and vertices. The etching process effectively makes the surface tension isotropic, so that spheres are favored under quasi-static conditions. It is scalable up to particle sizes of 200 nm or more. The resulting spherical crystals display uniform scattering spectra and consistent optical coupling at small separations, even showing Fano-like resonances in small clusters. The high monodispersity of the particles we demonstrate should facilitate the self-assembly of nanoparticle clusters with uniform optical resonances, which could in turn be used to fabricate optical metafluids. Narrow size distributions are required to control not only the spectral features but also the morphology and yield of clusters in certain assembly schemes. © 2013 American Chemical Society.

  11. Mechanically flexible optically transparent porous mono-crystalline silicon substrate

    KAUST Repository

    Rojas, Jhonathan Prieto

    2012-01-01

    For the first time, we present a simple process to fabricate a thin (≥5μm), mechanically flexible, optically transparent, porous mono-crystalline silicon substrate. Relying only on reactive ion etching steps, we are able to controllably peel off a thin layer of the original substrate. This scheme is cost favorable as it uses a low-cost silicon <100> wafer and furthermore it has the potential for recycling the remaining part of the wafer that otherwise would be lost and wasted during conventional back-grinding process. Due to its porosity, it shows see-through transparency and potential for flexible membrane applications, neural probing and such. Our process can offer flexible, transparent silicon from post high-thermal budget processed device wafer to retain the high performance electronics on flexible substrates. © 2012 IEEE.

  12. Monocrystalline silicon used for integrated circuits: still on the way

    Institute of Scientific and Technical Information of China (English)

    Jia-he CHEN; De-ren YANG; Duan-lin QUE

    2008-01-01

    With the rapid development of semiconductor technology, highly integrated circuits (ICs) and future nano-scale devices require large diameter and defect-free monocrystalline silicon wafers. The ongoing innovation from silicon materials is one of the driving forces in future micro and nano-technologies. In this work, the recent developments in the controlling of large diameter silicon crystal growth processes, the improvement of material features by co-doping with the intend-introduced impur-ities, and the progress of defect engineered silicon wafers (epitaxial silicon wafer, strained silicon, silicon on insu-lator) are reviewed. It is proposed that the silicon man-ufacturing infrastructure could still meet the increasingly stringent requirements arising from ULSI circuits and will expand Moore's law into a couple of decades.

  13. Optimizing seeded casting of mono-like silicon crystals through numerical simulation

    Science.gov (United States)

    Black, Andrés; Medina, Juan; Piñeiro, Axa; Dieguez, Ernesto

    2012-08-01

    Recently, silicon ingots produced by typical multicrystalline casting systems but having monocrystalline features are entering the photovoltaic market. In order to look into the particular properties of this novel method, the normal silicon casting process is numerically simulated, and compared to an optimized mono-like casting process, based on the use of oriented monocrystalline silicon seeds. The seeding process was optimized by reducing the time spent in the melt in order to reduce the back diffusion of harmful non-feedstock metal impurities such as iron, reducing the thermomechanical stress to avoid dislocation multiplication, and decreasing the overall interface curvature. Additionally, the growth conditions in the zone just above the seeds were fine-tuned to increase the production of vacancy point defects, in the hope of achieving "vacancy passivation" of harmful interstitial iron by moving it to substitutional position.

  14. Thin-film monocrystalline-silicon solar cells made by a seed layer approach on glass-ceramic substrates

    Energy Technology Data Exchange (ETDEWEB)

    Gordon, I.; Beaucarne, G.; Poortmans, J. [IMEC, Kapeldreef 75, B-3001 Leuven (Belgium); Vallon, S. [Corning European Technology Center, 7bis avenue de Valvins, 77210 Avon (France); Mayolet, A. [Corning Incorporated, SP-FR02-12, Corning, NY 14831 (United States)

    2010-02-15

    Solar modules made from thin-film crystalline-silicon layers of high quality on glass substrates could lower the price of photovoltaic electricity substantially. One way to create crystalline-silicon thin films on non-silicon substrates is to use the so-called ''seed layer approach'', in which a thin crystalline-silicon seed layer is first created, followed by epitaxial thickening of this seed layer. In this paper, we present the first solar cell results obtained on 10-{mu}m-thick monocrystalline-silicon (mono-Si) layers obtained by a seed layer approach on transparent glass-ceramic substrates. The seed layers were made using implant-induced separation and anodic bonding. These layers were then epitaxially thickened by thermal CVD. Simple solar cell structures without integrated light trapping features showed efficiencies of up to 7.5%. Compared to polycrystalline-silicon layers made by aluminum-induced crystallization of amorphous silicon and thermal CVD, the mono-Si layers have a much higher bulk diffusion lifetime. (author)

  15. Combined Ultrasonic Elliptical Vibration and Chemical Mechanical Polishing of Monocrystalline Silicon

    Directory of Open Access Journals (Sweden)

    Liu Defu

    2016-01-01

    Full Text Available An ultrasonic elliptical vibration assisted chemical mechanical polishing(UEV-CMP is employed to achieve high material removal rate and high surface quality in the finishing of hard and brittle materials such as monocrystalline silicon, which combines the functions of conventional CMP and ultrasonic machining. In theultrasonic elliptical vibration aided chemical mechanical polishingexperimental setup developed by ourselves, the workpiece attached at the end of horn can vibrate simultaneously in both horizontal and vertical directions. Polishing experiments are carried out involving monocrystalline silicon to confirm the performance of the proposed UEV-CMP. The experimental results reveal that the ultrasonic elliptical vibration can increase significantly the material removal rate and reduce dramatically the surface roughness of monocrystalline silicon. It is found that the removal rate of monocrystalline silicon polished by UEV-CMP is increased by approximately 110% relative to that of conventional CMP because a passive layer on the monocrystalline silicon surface, formed by the chemical action of the polishing slurry, will be removed not only by the mechanical action of CMP but also by ultrasonic vibration action. It indicates that the high efficiency and high quality CMP of monocrystalline silicon can be performed with the proposed UEV-CMP technique.

  16. Energy efficiency of photovoltaic modules mono and polycrystalline in function of global solar radiation; Eficiencia energetica de modulos fotovoltaicos mono e poli-cristalinos em funcao da radiacao solar global

    Energy Technology Data Exchange (ETDEWEB)

    Seraphim, Odivaldo Jose [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Botucatu, SP (Brazil). Fac. de Ciencias Agronomicas. Dept. de Engenharia Rural], e-mail: seraphim@fca.unesp.br; Siqueira, Jair Antonio Cruz [Universidade Estadual do Oeste do Parana (UNIOESTE), Cascavel, PR (Brazil). Centro de Ciencias Exatas e Tecnologicas], e-mail: jairsiqueira@fca.unesp.br; Silva, Carliane Diniz e [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Botucatu, SP (Brazil); Fiorentino, Jair de Jesus [Universidade Federal de Mato Grosso do Sul (UFMS), Campo Grande, MS (Brazil). Dept. de Engenharia Eletrica], e-mail: jairfiorentino@terra.com.br; Araujo, Joao Alberto Borges de [Faculdade de Tecnologia de Botucatu (FATEC), SP (Brazil). Dept. de Engenharia de Producao

    2004-07-01

    This research proposes a methodology to evaluate the acting of the solar energy conversion in electric energy, generated by photovoltaic modules installed under field conditions, constituted monocrystalline and polycrystalline silicon cells. The modules were appraised with relationship to energy efficiency for different marks and potency levels, in function of the readiness of solar radiation, being used loads sized for the nominal potency level of each module. The energy efficiency values calculated with the data obtained in field, didn't agree with the technical information presented by the makers of the modules monocrystalline, as being more efficient than the polycrystalline. Was ended, therefore, that the modules of the appraised marks presented inferior medium efficiency at 50% of the values supplied by the makers (author)

  17. Anelasticity of polycrystalline indium

    Energy Technology Data Exchange (ETDEWEB)

    Sapozhnikov, K., E-mail: k.sapozhnikov@mail.ioffe.ru [A.F.Ioffe Physical-Technical Institute, Politekhnicheskaya 26, 194021 St. Petersburg (Russian Federation); Golyandin, S. [A.F.Ioffe Physical-Technical Institute, Politekhnicheskaya 26, 194021 St. Petersburg (Russian Federation); Kustov, S. [Dept. de Fisica, Universitat de les Illes Balears, Cra Valldemossa km 7.5, E 07122 Palma de Mallorca (Spain)

    2009-09-15

    Mechanisms of anelasticity of polycrystalline indium have been studied over wide ranges of temperature (7-320 K) and strain amplitude (2 x 10{sup -7}-3.5 x 10{sup -4}). Measurements of the internal friction and Young's modulus have been performed by means of the piezoelectric resonant composite oscillator technique using longitudinal oscillations at frequencies of about 100 kHz. The stages of the strain amplitude dependence of the internal friction and Young's modulus defect, which can be attributed to dislocation - point defect and dislocation - dislocation interactions, have been revealed. It has been shown that thermal cycling gives rise to microplastic straining of polycrystalline indium due to the anisotropy of thermal expansion and to appearance of a 'recrystallization' internal friction maximum in the temperature spectra of amplitude-dependent anelasticity. The temperature range characterized by formation of Cottrell's atmospheres of point defects around dislocations has been determined from the acoustic data.

  18. Femtosecond laser direct writing of monocrystalline hexagonal silver prisms

    Energy Technology Data Exchange (ETDEWEB)

    Vora, Kevin; Kang, SeungYeon; Moebius, Michael [School of Engineering and Applied Sciences, Harvard University, 9 Oxford Street, Cambridge, Massachusetts 02138 (United States); Mazur, Eric [School of Engineering and Applied Sciences, Harvard University, 9 Oxford Street, Cambridge, Massachusetts 02138 (United States); Department of Physics, Harvard University, 9 Oxford Street, Cambridge, Massachusetts 02138 (United States)

    2014-10-06

    Bottom-up growth methods and top-down patterning techniques are both used to fabricate metal nanostructures, each with a distinct advantage: One creates crystalline structures and the other offers precise positioning. Here, we present a technique that localizes the growth of metal crystals to the focal volume of a laser beam, combining advantages from both approaches. We report the fabrication of silver nanoprisms—hexagonal nanoscale silver crystals—through irradiation with focused femtosecond laser pulses. The growth of these nanoprisms is due to a nonlinear optical interaction between femtosecond laser pulses and a polyvinylpyrrolidone film doped with silver nitrate. The hexagonal nanoprisms have bases hundreds of nanometers in size and the crystal growth occurs over exposure times of less than 1 ms (8 orders of magnitude faster than traditional chemical techniques). Electron backscatter diffraction analysis shows that the hexagonal nanoprisms are monocrystalline. The fabrication method combines advantages from both wet chemistry and femtosecond laser direct-writing to grow silver crystals in targeted locations. The results presented in this letter offer an approach to directly positioning and growing silver crystals on a substrate, which can be used for plasmonic devices.

  19. Femtosecond laser direct writing of monocrystalline hexagonal silver prisms

    Science.gov (United States)

    Vora, Kevin; Kang, SeungYeon; Moebius, Michael; Mazur, Eric

    2014-10-01

    Bottom-up growth methods and top-down patterning techniques are both used to fabricate metal nanostructures, each with a distinct advantage: One creates crystalline structures and the other offers precise positioning. Here, we present a technique that localizes the growth of metal crystals to the focal volume of a laser beam, combining advantages from both approaches. We report the fabrication of silver nanoprisms—hexagonal nanoscale silver crystals—through irradiation with focused femtosecond laser pulses. The growth of these nanoprisms is due to a nonlinear optical interaction between femtosecond laser pulses and a polyvinylpyrrolidone film doped with silver nitrate. The hexagonal nanoprisms have bases hundreds of nanometers in size and the crystal growth occurs over exposure times of less than 1 ms (8 orders of magnitude faster than traditional chemical techniques). Electron backscatter diffraction analysis shows that the hexagonal nanoprisms are monocrystalline. The fabrication method combines advantages from both wet chemistry and femtosecond laser direct-writing to grow silver crystals in targeted locations. The results presented in this letter offer an approach to directly positioning and growing silver crystals on a substrate, which can be used for plasmonic devices.

  20. Surface Damage Mechanism of Monocrystalline Si Under Mechanical Loading

    Science.gov (United States)

    Zhao, Qingliang; Zhang, Quanli; To, Suet; Guo, Bing

    2017-03-01

    Single-point diamond scratching and nanoindentation on monocrystalline silicon wafer were performed to investigate the surface damage mechanism of Si under the contact loading. The results showed that three typical stages of material removal appeared during dynamic scratching, and a chemical reaction of Si with the diamond indenter and oxygen occurred under the high temperature. In addition, the Raman spectra of the various points in the scratching groove indicated that the Si-I to β-Sn structure (Si-II) and the following β-Sn structure (Si-II) to amorphous Si transformation appeared under the rapid loading/unloading condition of the diamond grit, and the volume change induced by the phase transformation resulted in a critical depth (ductile-brittle transition) of cut (˜60 nm ± 15 nm) much lower than the theoretical calculated results (˜387 nm). Moreover, it also led to abnormal load-displacement curves in the nanoindentation tests, resulting in the appearance of elbow and pop-out effects (˜270 nm at 20 s, 50 mN), which were highly dependent on the loading/unloading conditions. In summary, phase transformation of Si promoted surface deformation and fracture under both static and dynamic mechanical loading.

  1. Gelcasting Polycrystalline Alumina

    Energy Technology Data Exchange (ETDEWEB)

    Janney, M.A.; Zuk, K.J.; Wei, G.C.

    2000-01-01

    OSRAM SYLVANIA INC. is a major U.S. manufacturer of high-intensity lighting. Among its products is the Lumalux TM line of high-pressure sodium vapor arc lamps, which are used for industrial, highway, and street lighting. The key to the performance of these lamps is the polycrystalline alumina (PCA) tube that is used to contain the plasma that is formed in the electric arc. That plasma consists of ionized sodium, mercury, and xenon vapors. The key attributes of the PCA tubes are their transparency ({approximately}97% total transmittance in the visible), their refractoriness (inner wall temperature can reach l2OOC), and their chemical resistance (sodium and mercury vapor are extremely corrosive). The current efficiency of the lamps is very high, up to 100 initial lumens per watt. (Compare incandescent lamps 10-20 lumens per watt, fluorescent lamps 25-90 lumens per watt.)

  2. A simple method to control nanotribology behaviors of monocrystalline silicon

    Science.gov (United States)

    Wang, X. D.; Guo, J.; Chen, C.; Chen, L.; Qian, L. M.

    2016-01-01

    A simple method was proposed to control the nanotribology behaviors of monocrystalline silicon against SiO2 microsphere by adjusting relative humidity (RH). Experimental results indicated that adhesion work, friction coefficient, and nanowear of silicon against SiO2 microsphere significantly varied between 60% and 90% RH. Under 60% RH, adhesion work was 119 mN/m, and friction coefficient was about 0.53. However, adhesion work and friction coefficient decreased to ˜70 mN/m and ˜0.3 under 90% RH, respectively. An apparent wear track ˜13 nm deep formed on the silicon surface under 60% RH, whereas no obvious wear scar was observed on the silicon surface under 90% RH. Analysis indicated that such tribological behaviors were due to different water condensations on the silicon surface under 60% and 90% RH. Under 60% RH, the water that condensed on the surfaces of the silicon sample and SiO2 tip mainly consisted of ice-like water. As a result, adhesion work was enlarged by the breaking force of the ice-like water bridge in the contact area. Given that a ≡Si-O-Si≡ bonding bridge easily formed between the silicon surface and the SiO2 tip with the help of water condensation under 60% RH instead of 90% RH, the friction coefficient was large and the nanowear of the silicon sample was severe under 60% RH. These results may help elucidate the nanotribology behaviors of silicon and facilitate the tribological design of dynamic microelectromechanical systems working under humid conditions.

  3. Comparison of the Electrical Properties of PERC Approach Applied to Monocrystalline and Multicrystalline Silicon Solar Cells

    Directory of Open Access Journals (Sweden)

    Enyu Wang

    2016-01-01

    Full Text Available At present, the improvement in performance and the reduction of cost for crystalline silicon solar cells are a key for photovoltaic industry. Passivated emitter and rear cells are the most promising technology for next-generation commercial solar cells. The efficiency gains of passivated emitter and rear cells obtained on monocrystalline silicon wafer and multicrystalline silicon wafer are different. People are puzzled as to how to develop next-generation industrial cells. In this paper, both monocrystalline and multicrystalline silicon solar cells for commercial applications with passivated emitter and rear cells structure were fabricated by using cost-effective process. It was found that passivated emitter and rear cells are more effective for monocrystalline silicon solar cells than for multicrystalline silicon solar cells. This study gives some hints about the industrial-scale mass production of passivated emitter and rear cells process.

  4. Microstructure studies of the grinding damage in monocrystalline silicon wafers

    Institute of Scientific and Technical Information of China (English)

    ZHANG Yinxia; KANG Renke; GUO Dongming; JIN Zhuji

    2007-01-01

    The depth and nature of the subsurface damage in a silicon wafer will limit the performance of IC components.Damage microstructures of the silicon wafers ground by the #325,#600, and #2000 grinding wheels was analyzed.The results show that many microcracks,fractures, and dislocation rosettes appear in the surface and subsurface of the wafer ground by the #325 grinding wheel.No obvious microstructure change exists.The amorphous layer with a thickness of about 100 nm,microcracks, high density dislocations,and polycrystalline silicon are observed in the subsurface of the wafer ground by the #600 grinding wheel.For the wafer ground by the #2000 grinding wheel,an amorphous layer of about 30 nm thickness,a polycrystalline silicon layer,a few dislocations,and an elastic deformation layer exist.In general,with the decrease in grit size,the material removal mode changes from micro-fracture mode to ductile mode gradually.

  5. A study on the key factors affecting the electronic properties of monocrystalline silicon solar cells

    Institute of Scientific and Technical Information of China (English)

    ZHOU Ji-cheng; CHEN Yong-min; LI Li; LI Fei; ZHAO Bao-xing

    2009-01-01

    The model of monocrystalline silicon solar cells is established, and the effects of wafer parameters, such as the p-Si (100) substrate thickness, the defect density, and the doping concentration, on the electronic properties of monocrystalline silicon solar cells are analyzed. The results indicate that the solar cells with an A1 back-surface-field will have good electronic properties when the wafers meet the following three conditions: (i) the defect density is less than 1.0×1011 cm-3; (ii) the substrate thickness is in the range of 100 μm to 200 μm.

  6. Solution-Grown Monocrystalline Hybrid Perovskite Films for Hole-Transporter-Free Solar Cells

    KAUST Repository

    Peng, Wei

    2016-03-02

    High-quality perovskite monocrystalline films are successfully grown through cavitation-triggered asymmetric crystallization. These films enable a simple cell structure, ITO/CH3NH3PbBr3/Au, with near 100% internal quantum efficiency, promising power conversion efficiencies (PCEs) >5%, and superior stability for prototype cells. Furthermore, the monocrystalline devices using a hole-transporter-free structure yield PCEs ≈6.5%, the highest among other similar-structured CH3NH3PbBr3 solar cells to date.

  7. Seebeck effect in polycrystalline semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    Jerhot, J.; Vlcek, J.

    1982-06-18

    The paper deals with the interpretation of the Seebeck coefficient measured for a polycrystalline semiconductor. Polycrystalline semiconductors are considered to be composed of grains separated from one another by intergrain domains. An isotype heterojunction with a certain density of interface states is assumed to exist at the grain-intergrain domain interface. The general formula for the Seebeck coefficient under these conditions is derived. The relations valid for systems of practical interest are shown as limiting cases of the formula presented.

  8. 11% efficient single-crystal solar cells and 10% efficient polycrystalline cells made from refined metallurgical silicon

    Science.gov (United States)

    Hanoka, J. I.; Strock, H. B.; Kotval, P. S.

    1981-09-01

    The performances of single-crystal and polycrystalline solar cells fabricated from a refined form of low-cost metallurgical silicon are presented. Czochralski-pulled single crystal and cast polycrystalline silicon solar cells with an n on p structure were made from metallurgical silicon processed by Al dissolution followed by Al removal through slagging and directional solidification to obtain material purities in the fractional ppm by weight range. For the single-crystal cells, measurements reveal AM1 efficiencies up to 11.1%, open circuit voltages up to 596 mV and fill factors up to 81%. The cast polycrystalline substrates have yielded cells with efficiencies up to 10.1%, fill factors of 79% and open circuit voltages of 585 mV. The low short circuit current densities are attributed to impurities in the base region in the single-crystal cell, and to grain boundary segregation of impurities and grain boundary recombination in the polycrystalline cells.

  9. Caste System

    OpenAIRE

    Hoff, Karla

    2016-01-01

    In standard economics, individuals are rational actors and economic forces undermine institutions that impose large inefficiencies. The persistence of the caste system is evidence of the need for psychologically more realistic models of decision-making in economics. The caste system divides South Asian society into hereditary groups whose lowest ranks are represented as innately polluted. ...

  10. Copper, Aluminum and Nickel: A New Monocrystalline Orthodontic Alloy

    Science.gov (United States)

    Wierenga, Mark

    Introduction: This study was designed to evaluate, via tensile and bend testing, the mechanical properties of a newly-developed monocrystalline orthodontic archwire comprised of a blend of copper, aluminum, and nickel (CuAlNi). Methods: The sample was comprised of three shape memory alloys; CuAlNi, copper nickel titanium (CuNiTi), and nickel titanium (NiTi); from various orthodontic manufacturers in both 0.018" round and 0.019" x 0.025" rectangular dimensions. Additional data was gathered for similarly sized stainless steel and beta-titanium archwires as a point of reference for drawing conclusions about the relative properties of the archwires. Measurements of loading and unloading forces were recorded in both tension and deflection testing. Repeated-measure ANOVA (alpha= 0.05) was used to compare loading and unloading forces across wires and one-way ANOVA (alpha= 0.05) was used to compare elastic moduli and hysteresis. To identify significant differences, Tukey post-hoc comparisons were performed. Results: The modulus of elasticity, deflection forces, and hysteresis profiles of CuAlNi were significantly different than the other superelastic wires tested. In all tests, CuAlNi had a statistically significant lower modulus of elasticity compared to the CuNiTi and NiTi wires (P <0.0001). The CuAlNi wire exhibited significantly lower loading and unloading forces than any other wire tested. In round wire tensile tests, loading force at all deflections was significantly lower for CuAlNi than CuNiTi or NiTi (P <0.0001). In tensile testing, the CuAlNi alloy was able to recover from a 7 mm extension (10% elongation) without permanent deformation and with little to no loss in force output. In large-deflection bend tests at 4, 5, and 6 mm deflection, CuAlNi showed the significantly lowest loading forces across the three wire materials (P <0.0001). The NiTi wires showed up to 12 times the amount of energy loss due to hysteresis compared to CuAlNi. CuAlNi showed a hysteresis

  11. Gelcasting polycrystalline alumina

    Energy Technology Data Exchange (ETDEWEB)

    Janney, M.A. [Oak Ridge National Lab., TN (United States)

    1997-04-01

    This work is being done as part of a CRADA with Osram-Sylvania, Inc. (OSI) OSI is a major U.S. manufacturer of high-intensity lighting. Among its products is the Lumalux{reg_sign} line of high-pressure sodium vapor arc lamps, which are used for industrial, highway, and street lighting. The key to the performance of these lamps is the polycrystalline alumina (PCA) tube that is used to contain the plasma that is formed in the electric arc. That plasma consists of ionized sodium, mercury, and xenon vapors. The key attributes of the PCA tubes are their transparency (95% total transmittance in the visible region), their refractoriness (inner wall temperature can reach 1400{degrees}C), and their chemical resistance (sodium and mercury vapor are extremely corrosive). The current efficiency of the lamps is very high, on the order of several hundred lumens / watt. (Compare - incandescent lamps -13 lumens/watt fluorescent lamps -30 lumens/watt.) Osram-Sylvania would like to explore using gelcasting to form PCA tubes for Lumalux{reg_sign} lamps, and eventually for metal halide lamps (known as quartz-halogen lamps). Osram-Sylvania, Inc. currently manufactures PCA tubes by isostatic pressing. This process works well for the shapes that they presently use. However, there are several types of tubes that are either difficult or impossible to make by isostatic pressing. It is the desire to make these new shapes and sizes of tubes that has prompted Osram-Sylvania`s interest in gelcasting. The purpose of the CRADA is to determine the feasibility of making PCA items having sufficient optical quality that they are useful in lighting applications using gelcasting.

  12. Development of technology for thin substrate polycrystalline solar cells for practical use. Development of manufacturing technologies for low-cost substrates (low-cost Si sheets by continuous casting method); Usugata takessho taiyo denchi seizo gijutsu no jitsuyoka kenkyu. Tei cost kiban seizo gijutsu kaihatsu (renzoku cast ho ni yoru tei cost Si kiban seizo gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the study results on manufacturing of low-cost Si substrates by continuous casting method in fiscal 1994. (1) On manufacturing of ingots of 16 piece size, the ingot of nearly 170kg was manufactured by batch process using the Si melt injection unit prepared in last year. (2) On oxygen and carbon contents in wafers, the contents were measured by FT-IR after slicing of the ingot. As a result, the oxygen and carbon contents could be successfully reduced to the targets of 10ppma and 5ppma or less, respectively. (3) The resistivity distribution of the ingot ranged over the target of 1-2ohm-cm. (4) Cells of 100 {times} 100mm{sup 2} wide and 350{mu}m thick were verified by in-house evaluation process. Although lower cell conversion efficiency was found at the center top of the ingot, a vertical efficiency stability was nearly sufficient as a whole. (5) On the crystal growth unit prepared in fiscal 1994, any problems were not found on automatic driving and vibration during moving. 8 figs.

  13. Electrically active, doped monocrystalline silicon nanoparticles produced by hot wire thermal catalytic pyrolysis

    CSIR Research Space (South Africa)

    Scriba, MR

    2011-05-01

    Full Text Available Doped silicon nanoparticles have successfully been produced by hot wire thermal catalytic pyrolysis at 40 mbar and a filament temperature of 1800 °C, using a mixture of silane and diborane or phosphine. All particles are monocrystalline with shapes...

  14. Hair casts

    Directory of Open Access Journals (Sweden)

    Sweta S Parmar

    2014-01-01

    Full Text Available Hair casts or pseudonits are circumferential concretions,which cover the hair shaft in such a way that, it could be easily removed. They are thin, cylindrical, and elongated in length. We present an unusual case of an 8-year-old girl presenting with hair casts. Occurrence of these is unusual, and they may have varied associations. This patient was suffering from developmental delay. It is commonly misdiagnosed as and very important to differentiate from pediculosis capitis.

  15. Solidification and casting

    CERN Document Server

    Cantor, Brian

    2002-01-01

    INDUSTRIAL PERSPECTIVEDirect chillcasting of aluminium alloysContinuous casting of aluminium alloysContinuous casting of steelsCastings in the automotive industryCast aluminium-silicon piston alloysMODELLING AND SIMULATIONModelling direct chill castingMold filling simulation of die castingThe ten casting rulesGrain selection in single crystal superalloy castingsDefects in aluminium shape castingPattern formation during solidificationPeritectic solidificationSTRUCTURE AND DEFECTSHetergeneous nucleation in aluminium alloysCo

  16. Characteristics of poly- and mono-crystalline BeO and SiO{sub 2} as thermal and cold neutron filters

    Energy Technology Data Exchange (ETDEWEB)

    Adib, M.; Habib, N. [Reactor Physics Department, NRC, Atomic Energy Authority, Cairo (Egypt); Bashter, I.I. [Physics Department, Faculty of Science, Zagazig University (Egypt); Morcos, H.N.; El-Mesiry, M.S. [Reactor Physics Department, NRC, Atomic Energy Authority, Cairo (Egypt); Mansy, M.S., E-mail: drmohamedmansy88@hotmail.com [Reactor Physics Department, NRC, Atomic Energy Authority, Cairo (Egypt)

    2015-09-01

    Highlights: • Neutron filtering features of BeO and SiO{sub 2} poly- and mono-crystals. • Calculations of the cold and thermal neutron cross sections and transmission with the code “HEXA-FILTERS”. • Optimal mosaic spread, thicknesses and cutting planes for BeO and SiO{sub 2} mono-crystals. - Abstract: A simple model along with a computer code “HEXA-FILTERS” is used to carry out the calculation of the total cross-sections of BeO and SiO{sub 2} having poly or mono-crystalline form as a function of neutron wavelength at room (R.T.) and liquid nitrogen (L.N.) temperatures. An overall agreement is indicated between the calculated neutron cross-sections and experimental data. Calculation shows that 25 cm thick of polycrystalline BeO cooled at liquid nitrogen temperature was found to be a good filter for neutron wavelengths longer than 0.46 nm. While, 50 cm of SiO{sub 2}, with much less transmission, for neutrons with wavelengths longer than 0.85 nm. It was also found that 10 cm of BeO and 15 cm SiO{sub 2} thick mono-crystals cut along their (0 0 2) plane, with 0.5° FWHM on mosaic spread and cooled at L.N., are a good thermal neutron filter, with high effect-to-noise ratio.

  17. Positron lifetime in polycrystalline gadolinium

    Energy Technology Data Exchange (ETDEWEB)

    Gomez, A.M.; Serna, J. (Universidad Complutense de Madrid (Spain). Dept. de Fisica del Estado Solido)

    1984-06-16

    Positron lifetimes are measured on polycrystalline gadolinium between 15 and 25 /sup 0/C taking into account the microstructure of the specimens, especially the grain sizes of untreated or annealed sheets. Results show the existence of a trapping effect of positrons in Gd due to different trapping centers such as point defects, dislocations, grain boundaries, and other defects.

  18. Anisotropic etching of monocrystalline silicon under subcritical conditions

    Science.gov (United States)

    Gonzalez-Pereyra, Nestor Gabriel

    Sub- and supercritical fluids remain an underexploited resource for materials processing. Around its critical point a common compound such as water behaves like a different substance exhibiting changes in its properties that modify its behavior as a solvent and unlock reaction paths not viable in other conditions. In the subcritical region water's properties can be directed by controlling temperature and pressure. Water and silicon are two of the most abundant, versatile, environmentally non-harmful, and simplest substances on Earth. They are among the most researched and best-known substances. Both are ubiquitous and essential for present-day world. Silicon is fundamental in semiconductor fabrication, microelectromechanical systems, and photovoltaic cells. Wet etching of silicon is a fabrication strategy shared by these three applications. Processing of silicon requires large amounts of water, often involving dangerous and environmentally hazardous chemicals. Yet, minimal knowledge is available on the ways high temperature water interacts with crystalline silicon. The purpose of this project is to identify and implement a method for the modification of monocrystalline silicon surfaces with three important characteristics: 1) requires minimal amounts of added chemicals, 2) controllability of morphological features formed, 3) reduced processing time. This will be accomplished by subjecting crystalline silicon to diluted alkaline solutions working in the subcritical region of water. This approach allows for variations on surface morphologies and etching rates by adapting the reactions conditions, with focus on composition and temperature of the solutions used. The work reported discusses the techniques used for producing surfaces with a variety of morphologies that ultimately allowed to create patterns and textures on silicon wafers, using highly diluted alkaline solutions that can be used for photovoltaic applications. These morphologies were created with a

  19. Microstructure of polycrystalline PBTTT films: domain mapping and structure formation.

    Science.gov (United States)

    Schuettfort, Torben; Watts, Benjamin; Thomsen, Lars; Lee, Mijung; Sirringhaus, Henning; McNeill, Christopher R

    2012-02-28

    We utilize near-edge X-ray absorption fine structure (NEXAFS) spectroscopy and scanning transmission X-ray microscopy (STXM) to study the microstructure and domain structure of polycrystalline films of the semiconducting polymer poly(2,5-bis(3-tetradecylthiophen-2-yl)thieno[3,2-b]thiophene) (PBTTT). Total electron yield NEXAFS spectroscopy is used to examine the surface structure of the first 1-2 molecular layers, while bulk-sensitive STXM is used to produce maps of domain orientation and order sampled through the entire film thickness. We study different phases of PBTTT including as-cast, terraced and nanoribbon morphologies produced via spin-coating as well as aligned films of as-cast and nanoribbon morphologies produced by zone-casting. For the terraced morphology, domains are observed that are larger than the size of the terraced surface features, and the calculated degree of order is reduced compared to the nanoribbon morphology. For zone-cast films, we find that, although little optical anisotropy is observed in the bulk of as-cast films, a high degree of surface structural anisotropy is observed with NEXAFS spectroscopy, similar to what is observed in annealed nanoribbon films. This observation indicates that the aligned surface structure in unannealed zone-cast films templates the bulk ordering of the aligned nanoribbon phase. STXM domain mapping of aligned nanoribbon films reveals elongated, micrometer-wide domains with each domain misoriented with respect to its neighbor by up to 45°, but with broad domain boundaries. Within each nanoribbon domain, a high degree of X-ray dichroism is observed, indicating correlated ordering throughout the bulk of the film.

  20. The impact of radiation on semiconducting characteristics of monocrystalline silicon and germanium

    Directory of Open Access Journals (Sweden)

    Obrenović Marija D.

    2016-01-01

    Full Text Available The paper examines the effects of radiation on the electrical characteristics of monocrystalline silicon and germanium. Samples of monocrystalline silicon and germanium are irradiated under controlled laboratory conditions in the field of neutron, X- and g-radiation. Change of the samples' specific resistance was measured dependent on the radiation dose with the type of radiation as a parameter. Next, the dependence of the samples resistance on temperature was recorded (in the impurities region and in intrinsic region with the previously absorbed dose as a parameter. The results were statistically analyzed and explained on the basis of radiation effects in solids. The results are compared with those obtained by using Monte Carlo method. A good agreement was confirmed by the mentioned experimental investigation. [Projekat Ministarstva nauke Republike Srbije, br. 171007

  1. Mechanical grooving of oxidized porous silicon to reduce the reflectivity of monocrystalline silicon solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Zarroug, A.; Dimassi, W.; Ouertani, R.; Ezzaouia, H. [Laboratoire de Photovoltaique, Centre des Recherches et des Technologies de l' Energie, BP. 95, Hammam-Lif 2050 (Tunisia)

    2012-10-15

    In this work, we are interested to use oxidized porous silicon (ox-PS) as a mask. So, we display the creating of a rough surface which enhances the absorption of incident light by solar cells and reduces the reflectivity of monocrystalline silicon (c-Si). It clearly can be seen that the mechanical grooving enables us to elaborate the texturing of monocrystalline silicon wafer. Results demonstrated that the application of a PS layer followed by a thermal treatment under O2 ambient easily gives us an oxide layer of uniform size which can vary from a nanometer to about ten microns. In addition, the Fourier transform infrared (FTIR) spectroscopy investigations of the PS layer illustrates the possibility to realize oxide layer as a mask for porous silicon. We found also that this simple and low cost method decreases the total reflectivity (copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  2. Soil Pressure Mini-sensor Made of Monocrystalline Silicon and the Measurement of Its Sensitivity Coefficient

    Institute of Scientific and Technical Information of China (English)

    YU Xiao; SU Xiaoke

    2005-01-01

    A calibration test was done in order to measure its sensitivity coefficient by an improved soil test device. The experimental result shows that the soil pressure min- sensor made of the monocrystalline silicon ( SPMMS ) is proved to be good linear, high precision and less discrete that can fetch precise data in low pressure range even near by 0 point, which guarantees the reliability of the soil pressure test in geotechnical engineering.

  3. Effect of crystal plane orientation on tribochemical removal of monocrystalline silicon

    OpenAIRE

    Chen Xiao; Jian Guo; Peng Zhang; Cheng Chen; Lei Chen; Linmao Qian

    2017-01-01

    The effect of crystal plane orientation on tribochemical removal of monocrystalline silicon was investigated using an atomic force microscope. Experimental results indicated that the tribochemical removal of silicon by SiO2 microsphere presented strong crystallography-induced anisotropy. Further analysis suggested that such anisotropic tribochemical removal of silicon was not dependent on the crystallography-dependent surface mechanical properties (i.e., hardness and elastic modulus), but was...

  4. Fabrication of high resolution and lightweight monocrystalline silicon x-ray mirrors

    Science.gov (United States)

    Riveros, Raul E.; Kolos, Linette D.; Mazzarella, James R.; McKeon, Kevin P.; Zhang, William W.

    2015-09-01

    Monocrystalline silicon as an x-ray mirror substrate material promises significant improvements over the x- ray mirror technologies used to date, since it is mechanically stiff, stress-free, highly thermally conductive, and widely commercially available. Producing highly accurate and lightweight x-ray mirrors from monocrystalline silicon requires a unique and specialized manufacturing process capable of producing mirrors quickly and cost effectively. The identification, development, and testing of this process is the focus of the work described in this proceeding. Monocrystalline silicon blocks were obtained, and a variety of processes (wire electro-discharge machining, etching, polishing) were applied to generate an accurate and stress-free cylindrical or Wolter-I mirror surface. The mirror surface is then sliced off at a thickness of mirror segment with mirror production process requires ~2 days to produce a mirror segment and is easily integrated into a cost-reducing parallel processing scheme. Presently, there is strong evidence that the mirror production process described in this paper will meet the stringent requirements of future x-ray missions.

  5. Polycrystalline thin films : A review

    Energy Technology Data Exchange (ETDEWEB)

    Valvoda, V. [Charles Univ., Prague (Czech Republic). Faculty of Mathematics and Physics

    1996-09-01

    Polycrystalline thin films can be described in terms of grain morphology and in terms of their packing by the Thornton`s zone model as a function of temperature of deposition and as a function of energy of deposited atoms. Grain size and preferred grain orientation (texture) can be determined by X-ray diffraction (XRD) methods. A review of XRD analytical methods of texture analysis is given with main attention paid to simple empirical functions used for texture description and for structure analysis by joint texture refinement. To illustrate the methods of detailed structure analysis of thin polycrystalline films, examples of multilayers are used with the aim to show experiments and data evaluation to determine layer thickness, periodicity, interface roughness, lattice spacing, strain and the size of diffraction coherent volumes. The methods of low angle and high angle XRD are described and discussed with respect to their complementary information content.

  6. Transparent polycrystalline cubic silicon nitride

    Science.gov (United States)

    Nishiyama, Norimasa; Ishikawa, Ryo; Ohfuji, Hiroaki; Marquardt, Hauke; Kurnosov, Alexander; Taniguchi, Takashi; Kim, Byung-Nam; Yoshida, Hidehiro; Masuno, Atsunobu; Bednarcik, Jozef; Kulik, Eleonora; Ikuhara, Yuichi; Wakai, Fumihiro; Irifune, Tetsuo

    2017-01-01

    Glasses and single crystals have traditionally been used as optical windows. Recently, there has been a high demand for harder and tougher optical windows that are able to endure severe conditions. Transparent polycrystalline ceramics can fulfill this demand because of their superior mechanical properties. It is known that polycrystalline ceramics with a spinel structure in compositions of MgAl2O4 and aluminum oxynitride (γ-AlON) show high optical transparency. Here we report the synthesis of the hardest transparent spinel ceramic, i.e. polycrystalline cubic silicon nitride (c-Si3N4). This material shows an intrinsic optical transparency over a wide range of wavelengths below its band-gap energy (258 nm) and is categorized as one of the third hardest materials next to diamond and cubic boron nitride (cBN). Since the high temperature metastability of c-Si3N4 in air is superior to those of diamond and cBN, the transparent c-Si3N4 ceramic can potentially be used as a window under extremely severe conditions. PMID:28303948

  7. Nodular cast iron and casting monitoring

    OpenAIRE

    2008-01-01

    In this paper quality monitoring of nodular cast iron and casting made of it is presented. A control system of initial liquid cast iron to spheroidization, after spheroidization and inoculation with using of TDA method was shown. An application of an ultrasonic method to assessment of the graphite form and the metal matrix microstructure of castings was investigated.

  8. Nodular cast iron and casting monitoring

    Directory of Open Access Journals (Sweden)

    S. Pietrowski

    2008-10-01

    Full Text Available In this paper quality monitoring of nodular cast iron and casting made of it is presented. A control system of initial liquid cast iron to spheroidization, after spheroidization and inoculation with using of TDA method was shown. An application of an ultrasonic method to assessment of the graphite form and the metal matrix microstructure of castings was investigated.

  9. Casting materials

    Energy Technology Data Exchange (ETDEWEB)

    Chaudhry, Anil R. (Xenia, OH); Dzugan, Robert (Cincinnati, OH); Harrington, Richard M. (Cincinnati, OH); Neece, Faurice D. (Lyndurst, OH); Singh, Nipendra P. (Pepper Pike, OH)

    2011-06-14

    A foam material comprises a liquid polymer and a liquid isocyanate which is mixed to make a solution that is poured, injected or otherwise deposited into a corresponding mold. A reaction from the mixture of the liquid polymer and liquid isocyanate inside the mold forms a thermally collapsible foam structure having a shape that corresponds to the inside surface configuration of the mold and a skin that is continuous and unbroken. Once the reaction is complete, the foam pattern is removed from the mold and may be used as a pattern in any number of conventional casting processes.

  10. Coupling of Nitrogen-Vacancy Centers to Photonic Crystal Cavities in Monocrystalline Diamond

    CERN Document Server

    Faraon, Andrei; Huang, Zhihong; Acosta, Victor M; Beausoleil, Raymond G

    2012-01-01

    The zero-phonon transition rate of a nitrogen-vacancy center is enhanced by a factor of ~70 by coupling to a photonic crystal resonator fabricated in monocrystalline diamond using standard semiconductor fabrication techniques. Photon correlation measurements on the spectrally filtered zero-phonon line show antibunching, a signature that the collected photoluminescence is emitted primarily by a single nitrogen-vacancy center. The linewidth of the coupled nitrogen-vacancy center and the spectral diffusion are characterized using high-resolution photoluminescence and photoluminescence excitation spectroscopy.

  11. CMOS compatible generic batch process towards flexible memory on bulk monocrystalline silicon (100)

    KAUST Repository

    Ghoneim, Mohamed T.

    2014-12-01

    Today\\'s mainstream flexible electronics research is geared towards replacing silicon either totally, by having organic devices on organic substrates, or partially, by transferring inorganic devices onto organic substrates. In this work, we present a pragmatic approach combining the desired flexibility of organic substrates and the ultra-high integration density, inherent in silicon semiconductor industry, to transform bulk/inflexible silicon into an ultra-thin mono-crystalline fabric. We also show the effectiveness of this approach in achieving fully flexible electronic systems. Furthermore, we provide a progress report on fabricating various memory devices on flexible silicon fabric and insights for completely flexible memory modules on silicon fabric.

  12. Molecular Dynamics Simulation of Nanoindentation-induced Mechanical Deformation and Phase Transformation in Monocrystalline Silicon

    Directory of Open Access Journals (Sweden)

    Jian Sheng-Rui

    2008-01-01

    Full Text Available AbstractThis work presents the molecular dynamics approach toward mechanical deformation and phase transformation mechanisms of monocrystalline Si(100 subjected to nanoindentation. We demonstrate phase distributions during loading and unloading stages of both spherical and Berkovich nanoindentations. By searching the presence of the fifth neighboring atom within a non-bonding length, Si-III and Si-XII have been successfully distinguished from Si-I. Crystallinity of this mixed-phase was further identified by radial distribution functions.

  13. Participation of oxygen and carbon in formation of oxidation-induced stacking faults in monocrystalline silicon

    Directory of Open Access Journals (Sweden)

    Иван Федорович Червоный

    2015-11-01

    Full Text Available It is experimentally established, that density of oxidation-induced stacking faults (OISF in the boron doped monocrystalline silicon plates, that above, than it is more relation of oxygen atoms concentration to carbon atoms concentration in them.On research results of geometry of OISF rings in the different sections of single-crystal geometry of areas is reconstructed with their different closeness. At adjustment of the growing modes of single-crystals of silicon the increase of output of suitable product is observed

  14. Fracture behaviour of polycrystalline tungsten

    Science.gov (United States)

    Gaganidze, Ermile; Rupp, Daniel; Aktaa, Jarir

    2014-03-01

    Fracture behaviour of round blank polycrystalline tungsten was studied by means of three point bending Fracture-Mechanical (FM) tests at temperatures between RT and 1000 °C and under high vacuum. To study the influence of the anisotropic microstructure on the fracture toughness (FT) and ductile-to-brittle transition (DBT) the specimens were extracted in three different, i.e. longitudinal, radial and circumferential orientations. The FM tests yielded distinctive fracture behaviour for each specimen orientation. The crack propagation was predominantly intergranular for longitudinal orientation up to 600 °C, whereas transgranular cleavage was observed at low test temperatures for radial and circumferentially oriented specimens. At intermediate test temperatures the change of the fracture mode took place for radial and circumferential orientations. Above 800 °C all three specimen types showed large ductile deformation without noticeable crack advancement. For longitudinal specimens the influence of the loading rate on the FT and DBT was studied in the loading rate range between 0.06 and 18 MPa m1/2/s. Though an increase of the FT was observed for the lowest loading rate, no resolvable dependence of the DBT on the loading rate was found partly due to loss of FT validity. A Master Curve approach is proposed to describe FT vs. test temperature data on polycrystalline tungsten. Fracture safe design space was identified by analysis compiled FT data.

  15. 11% efficient single-crystal solar cells and 10% efficient polycrystalline cells made from refined metallurgical silicon

    Energy Technology Data Exchange (ETDEWEB)

    Hanoka, J.I.; Strock, H.B.; Kotval, P.S.

    1981-09-01

    Refined metallurgical silicon has been utilized as a feedstock material both for Czochralski-pulled single crystal and for cast polycrystalline silicon solar cells. Using a phosphorous diffused junction for an n on p structure, the single-crystal cells have yielded AM1 efficiencies up to 11.1%, open circuit voltages up to 596 mV, and fill factors as high as 81% (not all on the same cell). The cast polycrystalline substrates have produced cells up to 10.1% efficient (AM1) with fill factors of 79% and V/sub o/c = 585 mV. Properties of the single-crystal and polycrystalline cells are quite similar, with the principal limiting factor being J/sub s/c , which is typically 20--23 mA/cm/sup 2/. Spectral response and EBIC data indicate that a considerable amount of the recombination is due to impurities. For the cast polycrystalline cells, the electron beam induced current data shows that grain boundary recombination is significant.

  16. The UK Casting Industry

    Institute of Scientific and Technical Information of China (English)

    Jincheng Liu

    2006-01-01

    The casting production in the UK in 2004 is presented and analysed. The UK casting industry has played an important role in world casting and manufacturing production. However recent years the rapid development of some developing countries has been shifting the casting production from the western industrialized countries including the UK. The UK casting industry and associated research and technology organizations, universities have been working together very hard to face the serious competition to make the UK casting industry have a sustainable future. The UK casting industry remains strong and plays an important role in world casting and manufacturing production.

  17. CA Investment Casting Process of Complex Castings

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    CA (Computer aided) investment casting technique used in superalloy castings of aerospace engine parts was presented. CA investment casting integrated computer application, RP (Rapid Prototyping) process, solidification simulation and investment casting process. It broke the bottle neck of making metal die. Solid model of complex parts were produced by UGII or other software, then translated into STL(Stereolithography) file, after RP process of SLS(Selective Laser Sintering), wax pattern used in investment ...

  18. Molecular Dynamics Simulation of the Crystal Orientation and Temperature Influences in the Hardness on Monocrystalline Silicon

    Directory of Open Access Journals (Sweden)

    Hongwei Zhao

    2014-01-01

    Full Text Available A nanoindentation simulation using molecular dynamic (MD method was carried out to investigate the hardness behavior of monocrystalline silicon with a spherical diamond indenter. In this study, Tersoff potential was used to model the interaction of silicon atoms in the specimen, and Morse potential was used to model the interaction between silicon atoms in the specimen and carbon atoms in the indenter. Simulation results indicate that the silicon in the indentation zone undergoes phase transformation from diamond cubic structure to body-centred tetragonal and amorphous structure upon loading of the diamond indenter. After the unloading of the indenter, the crystal lattice reconstructs, and the indented surface with a residual dimple forms due to unrecoverable plastic deformation. Comparison of the hardness of three different crystal surfaces of monocrystalline silicon shows that the (0 0 1 surface behaves the hardest, and the (1 1 1 surface behaves the softest. As for the influence of the indentation temperature, simulation results show that the silicon material softens and adhesiveness of silicon increases at higher indentation temperatures.

  19. Simulations Based on Experimental Data of the Behaviour of a Monocrystalline Silicon Photovoltaic Module

    Directory of Open Access Journals (Sweden)

    Abraham Dandoussou

    2015-01-01

    Full Text Available The performance of monocrystalline silicon cells depends widely on the parameters like the series and shunt resistances, the diode reverse saturation current, and the ideality factor. Many authors consider these parameters as constant while others determine their values based on the I-V characteristic when the module is under illumination or in the dark. This paper presents a new method for extracting the series resistance, the diode reverse saturation current, and the ideality factor. The proposed extraction method using the least square method is based on the fitting of experimental data recorded in 2014 in Ngaoundere, Cameroon. The results show that the ideality factor can be considered as constant and equal to 1.2 for the monocrystalline silicon module. The diode reverse saturation current depends only on the temperature. And the series resistance decreases when the irradiance increases. The extracted values of these parameters contribute to the best modeling of a photovoltaic module which can help in the accurate extraction of the maximum power.

  20. Enhanced cooling in mono-crystalline ultra-thin silicon by embedded micro-air channels

    KAUST Repository

    Ghoneim, Mohamed T.

    2015-12-11

    In today’s digital world, complementary metal oxide semiconductor (CMOS) technology enabled scaling of bulk mono-crystalline silicon (100) based electronics has resulted in their higher performance but with increased dynamic and off-state power consumption. Such trade-off has caused excessive heat generation which eventually drains the charge of battery in portable devices. The traditional solution utilizing off-chip fans and heat sinks used for heat management make the whole system bulky and less mobile. Here we show, an enhanced cooling phenomenon in ultra-thin (>10 μm) mono-crystalline (100) silicon (detached from bulk substrate) by utilizing deterministic pattern of porous network of vertical “through silicon” micro-air channels that offer remarkable heat and weight management for ultra-mobile electronics, in a cost effective way with 20× reduction in substrate weight and a 12% lower maximum temperature at sustained loads. We also show the effectiveness of this event in functional MOS field effect transistors (MOSFETs) with high-κ/metal gate stacks.

  1. Large three-dimensional photonic crystals based on monocrystalline liquid crystal blue phases.

    Science.gov (United States)

    Chen, Chun-Wei; Hou, Chien-Tsung; Li, Cheng-Chang; Jau, Hung-Chang; Wang, Chun-Ta; Hong, Ching-Lang; Guo, Duan-Yi; Wang, Cheng-Yu; Chiang, Sheng-Ping; Bunning, Timothy J; Khoo, Iam-Choon; Lin, Tsung-Hsien

    2017-09-28

    Although there have been intense efforts to fabricate large three-dimensional photonic crystals in order to realize their full potential, the technologies developed so far are still beset with various material processing and cost issues. Conventional top-down fabrications are costly and time-consuming, whereas natural self-assembly and bottom-up fabrications often result in high defect density and limited dimensions. Here we report the fabrication of extraordinarily large monocrystalline photonic crystals by controlling the self-assembly processes which occur in unique phases of liquid crystals that exhibit three-dimensional photonic-crystalline properties called liquid-crystal blue phases. In particular, we have developed a gradient-temperature technique that enables three-dimensional photonic crystals to grow to lateral dimensions of ~1 cm (~30,000 of unit cells) and thickness of ~100 μm (~ 300 unit cells). These giant single crystals exhibit extraordinarily sharp photonic bandgaps with high reflectivity, long-range periodicity in all dimensions and well-defined lattice orientation.Conventional fabrication approaches for large-size three-dimensional photonic crystals are problematic. By properly controlling the self-assembly processes, the authors report the fabrication of monocrystalline blue phase liquid crystals that exhibit three-dimensional photonic-crystalline properties.

  2. Optoelectronic enhancement of monocrystalline silicon solar cells by porous silicon-assisted mechanical grooving

    Energy Technology Data Exchange (ETDEWEB)

    Ben Rabha, Mohamed; Mohamed, Seifeddine Belhadj; Dimassi, Wissem; Gaidi, Mounir; Ezzaouia, Hatem; Bessais, Brahim [Laboratoire de Photovoltaique, Centre de Recherches et des Technologies de l' Energie, Technopole de Borj-Cedria, BP 95, 2050 Hammam-Lif (Tunisia)

    2011-03-15

    One of the most important factors influencing silicon solar cells performances is the front side reflectivity. Consequently, new methods for efficient reduction of this reflectivity are searched. This has always been done by creating a rough surface that enables incident light of being absorbed within the solar cell. Combination of texturization-porous silicon surface treatment was found to be an attractive technical solution for lowering the reflectivity of monocrystalline silicon (c-Si). The texturization of the monocrystalline silicon wafer was carried out by means of mechanical grooving. A specific etching procedure was then applied to form a thin porous silicon layer enabling to remove mechanical damages. This simple and low cost method reduces the total reflectivity from 29% to 7% in the 300 - 950 nm wavelength range and enhances the diffusion length of the minority carriers from 100 {mu}m to 790 {mu}m (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  3. Enhanced cooling in mono-crystalline ultra-thin silicon by embedded micro-air channels

    Science.gov (United States)

    Ghoneim, Mohamed T.; Fahad, Hossain M.; Hussain, Aftab M.; Rojas, Jhonathan P.; Torres Sevilla, Galo A.; Alfaraj, Nasir; Lizardo, Ernesto B.; Hussain, Muhammad M.

    2015-12-01

    In today's digital world, complementary metal oxide semiconductor (CMOS) technology enabled scaling of bulk mono-crystalline silicon (100) based electronics has resulted in their higher performance but with increased dynamic and off-state power consumption. Such trade-off has caused excessive heat generation which eventually drains the charge of battery in portable devices. The traditional solution utilizing off-chip fans and heat sinks used for heat management make the whole system bulky and less mobile. Here we show, an enhanced cooling phenomenon in ultra-thin (>10 μm) mono-crystalline (100) silicon (detached from bulk substrate) by utilizing deterministic pattern of porous network of vertical "through silicon" micro-air channels that offer remarkable heat and weight management for ultra-mobile electronics, in a cost effective way with 20× reduction in substrate weight and a 12% lower maximum temperature at sustained loads. We also show the effectiveness of this event in functional MOS field effect transistors (MOSFETs) with high-κ/metal gate stacks.

  4. Cast irons

    CERN Document Server

    1996-01-01

    Cast iron offers the design engineer a low-cost, high-strength material that can be easily melted and poured into a wide variety of useful, and sometimes complex, shapes. This latest handbook from ASM covers the entire spectrum of one of the most widely used and versatile of all engineered materials. The reader will find the basic, but vital, information on metallurgy, solidification characteristics, and properties. Extensive reviews are presented on the low-alloy gray, ductile, compacted graphite, and malleable irons. New and expanded material has been added covering high-alloy white irons used for abrasion resistance and high-alloy graphitic irons for heat and corrosion resistance. Also discussed are melting furnaces and foundry practices such as melting, inoculation, alloying, pouring, gating and rising, and molding. Heat treating practices including stress relieving, annealing, normalizing, hardening and tempering, autempering (of ductile irons), and surface-hardening treatments are covered, too. ASM Spec...

  5. Shock waves in polycrystalline iron.

    Science.gov (United States)

    Kadau, Kai; Germann, Timothy C; Lomdahl, Peter S; Albers, Robert C; Wark, Justin S; Higginbotham, Andrew; Holian, Brad Lee

    2007-03-30

    The propagation of shock waves through polycrystalline iron is explored by large-scale atomistic simulations. For large enough shock strengths the passage of the wave causes the body-centered-cubic phase to transform into a close-packed phase with most structure being isotropic hexagonal-close-packed (hcp) and, depending on shock strength and grain orientation, some fraction of face-centered-cubic (fcc) structure. The simulated shock Hugoniot is compared to experiments. By calculating the extended x-ray absorption fine structure (EXAFS) directly from the atomic configurations, a comparison to experimental EXAFS measurements of nanosecond-laser shocks shows that the experimental data is consistent with such a phase transformation. However, the atomistically simulated EXAFS spectra also show that an experimental distinction between the hcp or fcc phase is not possible based on the spectra alone.

  6. The ancient Chinese casting techniques

    OpenAIRE

    2011-01-01

    In the course of Chinese civilization, which lasted more than 5,000 years, casting production has made a huge contribution. In this paper, some representative metal castings were presented. According to their forming techniques, they can be grouped into stone mould casting, clay mould casting, ablation casting, lost wax casting, stack casting, permanent mould casting, sand casting, etc. According to their materials, they can be categorized into tin bronze, bimetallic bronze, malleable cast ir...

  7. Thin Wall Iron Castings

    Energy Technology Data Exchange (ETDEWEB)

    J.F. Cuttino; D.M. Stefanescu; T.S. Piwonka

    2001-10-31

    Results of an investigation made to develop methods of making iron castings having wall thicknesses as small as 2.5 mm in green sand molds are presented. It was found that thin wall ductile and compacted graphite iron castings can be made and have properties consistent with heavier castings. Green sand molding variables that affect casting dimensions were also identified.

  8. Selective deposition of polycrystalline diamond films using photolithography with addition of nanodiamonds as nucleation centers

    Science.gov (United States)

    Okhotnikov, V. V.; Linnik, S. A.; Gaidaichuk, A. V.; Shashev, D. V.; Nazarova, G. Yu; Yurchenko, V. I.

    2016-02-01

    A new method of selective deposition of polycrystalline diamond has been developed and studied. The diamond coatings with a complex, predetermined geometry and resolution up to 5 μm were obtained. A high density of polycrystallites in the coating area was reached (up to 32·107 pcs/cm2). The uniformity of the film reached 100%, and the degree of the surface contamination by parasitic crystals did not exceed 2%. The technology was based on the application of the standard photolithography with an addition of nanodiamond suspension into the photoresist that provided the creation of the centers of further nucleation in the areas which require further overgrowth. The films were deposited onto monocrystalline silicon substrates using the method of “hot filaments” in the CVD reactor. The properties of the coating and the impact of the nanodiamond suspension concentration in the photoresist were also studied. The potential use of the given method includes a high resolution, technological efficiency, and low labor costs compared to the standard methods (laser treatment, chemical etching in aggressive environments,).

  9. Extremal Overall Elastic Response of Polycrystalline Materials

    DEFF Research Database (Denmark)

    Bendsøe, Martin P; Lipton, Robert

    1996-01-01

    Polycrystalline materials comprised of grains obtained froma single anisotropic material are considered in the frameworkof linear elasticity. No assumptions on the symmetry of thepolycrystal are made. We subject the material to independentexternal strain and stress fields with prescribed mean...

  10. Low cost monocrystalline silicon sheet fabrication for solar cells by advanced ingot technology

    Science.gov (United States)

    Fiegl, G. F.; Bonora, A. C.

    1980-01-01

    The continuous liquid feed (CLF) Czochralski furnace and the enhanced I.D. slicing technology for the low-cost production of monocrystalline silicon sheets for solar cells are discussed. The incorporation of the CLF system is shown to improve ingot production rate significantly. As demonstrated in actual runs, higher than average solidification rates (75 to 100 mm/hr for 150 mm 1-0-0 crystals) can be achieved, when the system approaches steady-state conditions. The design characteristics of the CLF furnace are detailed, noting that it is capable of precise control of dopant impurity incorporation in the axial direction of the crystal. The crystal add-on cost is computed to be $11.88/sq m, considering a projected 1986 25-slice per cm conversion factor with an 86% crystal growth yield.

  11. Amorphization and recrystallization processes in monocrystalline beta silicon carbide thin films

    Energy Technology Data Exchange (ETDEWEB)

    Edmond, J.A.; Withrow, S.P.; Kong, H.S.; Davis, R.F.

    1985-01-01

    Individual, as well as multiple doses of /sup 27/Al/sup +/, /sup 31/P/sup +/, /sup 28/Si/sup +/, and /sup 28/Si/sup +/ and /sup 12/C/sup +/, were implanted into (100) oriented monocrystalline ..beta..-SiC films. The critical energy of approx. =16 eV/atom required for the amorphization of ..beta..-SiC via implantation of /sup 27/Al/sup +/ and /sup 31/P/sup +/ was determined using the TRIM84 computer program for calculation of the damage-energy profiles coupled with the results of RBS/ion channeling analyses. In order to recrystallize amorphized layers created by the individual implantation of all four ion species, thermal annealing at 1600, 1700, or 1800/sup 0/C was employed. Characterization of the recrystallized layers was performed using XTEM. Examples of SPE regrown layers containing precipitates and dislocation loops, highly faulted-microtwinned regions, and random crystallites were observed.

  12. Numerical analysis of monocrystalline silicon solar cells with fine nanoimprinted textured surface

    Science.gov (United States)

    Yoshinaga, Seiya; Ishikawa, Yasuaki; Araki, Shinji; Honda, Tatsuki; Jiang, Yunjiang; Uraoka, Yukiharu

    2017-02-01

    We investigated the surface reflectance of nanoimprinted textures on silicon. Zirconium oxide, which is a wide-bandgap inorganic dielectric material, was used as the texturing material. We performed several calculations to optimize the textures for the production of high-efficiency bulk-type monocrystalline silicon solar cells. Our analysis revealed that nanoimprinted textured solar cells exhibit a lower reverse saturation current density than a solar cell with a conventional etched texture. It was also confirmed that the photocarrier generation rate for a solar cell with a submicron-scale nanoimprinted texture has little dependence on the texture shape. Furthermore, the weighted average reflectance of an optimized nanoimprinted textured solar cell was substantially reduced to 3.72%, suggesting that texture formation by nanoimprint lithography is an extremely effective technology for producing high-efficiency solar cells at a low cost.

  13. Impact of temperature on performance of series and parallel connected mono-crystalline silicon solar cells

    Directory of Open Access Journals (Sweden)

    Subhash Chander

    2015-11-01

    Full Text Available This paper presents a study on impact of temperature on the performance of series and parallel connected mono-crystalline silicon (mono-Si solar cell employing solar simulator. The experiment was carried out at constant light intensity 550 W/m2with cell temperature in the range 25–60 oC for single, series and parallel connected mono-Si solar cells. The performance parameters like open circuit voltage, maximum power, fill factor and efficiency are found to decrease with cell temperature while the short circuit current is observed to increase. The experimental results reveal that silicon solar cells connected in series and parallel combinations follow the Kirchhoff’s laws and the temperature has a significant effect on the performance parameters of solar cell.

  14. Low cost monocrystalline silicon sheet fabrication for solar cells by advanced ingot technology

    Science.gov (United States)

    Fiegl, G. F.; Bonora, A. C.

    1980-01-01

    The continuous liquid feed (CLF) Czochralski furnace and the enhanced I.D. slicing technology for the low-cost production of monocrystalline silicon sheets for solar cells are discussed. The incorporation of the CLF system is shown to improve ingot production rate significantly. As demonstrated in actual runs, higher than average solidification rates (75 to 100 mm/hr for 150 mm 1-0-0 crystals) can be achieved, when the system approaches steady-state conditions. The design characteristics of the CLF furnace are detailed, noting that it is capable of precise control of dopant impurity incorporation in the axial direction of the crystal. The crystal add-on cost is computed to be $11.88/sq m, considering a projected 1986 25-slice per cm conversion factor with an 86% crystal growth yield.

  15. Energy-resolved hot carrier relaxation dynamics in monocrystalline plasmonic nanoantennas

    CERN Document Server

    Méjard, Régis; Petit, Marlène; Bouhelier, Alexandre; Cluzel, Benoît; Demichel, Olivier

    2016-01-01

    Hot carriers are energetic photo-excited carriers driving a large range of chemico-physical mechanisms. At the nanoscale, an efficient generation of these carriers is facilitated by illuminating plasmonic antennas. However, the ultrafast relaxation rate severally impedes their deployment in future hot-carrier based devices. In this paper, we report on the picosecond relaxation dynamics of hot carriers in plasmonic monocrystalline gold nanoantennas. The temporal dynamics of the hot carriers is experimentally investigated by interrogating the nonlinear photoluminescence response of the antenna with a spectrally-resolved two-pulse correlation configuration. We measure time-dependent nonlinearity orders varying from 1 to 8, which challenge the common interpretation of multi-photon gold luminescence. We demonstrate that the relaxation of the photo-excited carriers depends of their energies relative to the Fermi level. We find a 60 % variation in the relaxation rate for electron-hole pair energies ranging from c.a....

  16. Investigation of Oxide Bifilms in Investment Cast Superalloy IN100: Part II. Characterization

    Science.gov (United States)

    Kaplan, Max A.; Fuchs, Gerhard E.

    2016-05-01

    Oxide bifilms are a proposed casting inclusion reported to have been observed in vacuum investment cast polycrystalline Ni-based superalloys. Ongoing research seeks to determine if current superalloy casting practices can result in the formation of oxide bifilms, and subsequently if it is possible to observe and characterize this phenomenon. The effect of casting atmosphere, turbulence, filtering, hot isostatic pressing, and heat treatment has been investigated to identify the critical parameters that have been reported to result in bifilm formation in Ni-based superalloy IN100. Scanning Auger microscopy (SAM), scanning electron microscopy (SEM), and high-resolution transmission electron microscopy (HR-TEM) were utilized to characterize samples from each casting condition. In situ ultrahigh vacuum Auger fractography did not indicate the presence of bifilms on the fracture behavior of IN100 in any processing condition. SAM analysis identified a sulfur-enriched monolayer on the surface of dendritic casting porosity, and identified heterogeneous Ti oxycarbide inclusions in air cast IN100. SEM analysis also indicated the presence of Ti oxycarbide inclusions in air cast IN100, and determined that these inclusion structures consist of fine blocky external M(Ti, Mo)C carbide enveloping an internal core of alumina. HR-TEM analysis indicated that none of the oxycarbide inclusion interfaces exist as discontinuous unbound interfaces, and that the internal alumina core is an ultra-fine polycrystalline structure.

  17. LLNL casting technology

    Science.gov (United States)

    Shapiro, A. B.; Comfort, W. J., III

    1994-01-01

    Competition to produce cast parts of higher quality, lower rejection rate, and lower cost is a fundamental factor in the global economy. To gain an edge on foreign competitors, the US casting industry must cut manufacturing costs and reduce the time from design to market. Casting research and development (R&D) are the key to increasing US competiveness in the casting arena. Lawrence Livermore National Laboratory (LLNL) is the home of a wide range of R&D projects that push the boundaries of state-of-the art casting. LLNL casting expertise and technology include: casting modeling research and development, including numerical simulation of fluid flow, heat transfer, reaction/solidification kinetics, and part distortion with residual stresses; special facilities to cast toxic material; extensive experience casting metals and nonmetals; advanced measurement and instrumentation systems. Department of Energy (DOE) funding provides the leverage for LLNL to collaborate with industrial partners to share this advanced casting expertise and technology. At the same time, collaboration with industrial partners provides LLNL technologists with broader insights into casting industry issues, casting process data, and the collective experience of industry experts. Casting R&D is also an excellent example of dual-use technology; it is the cornerstone for increasing US industrial competitiveness and minimizing waste nuclear material in weapon component production. Annual funding for casting projects at LLNL is $10M, which represents 1% of the total LLNL budget. Metal casting accounts for about 80% of the funding. Funding is nearly equally divided between development directed toward US industrial competitiveness and weapon component casting.

  18. High efficiency back-contact back-junction thin-film monocrystalline silicon solar cells from the porous silicon process

    Science.gov (United States)

    Haase, F.; Kajari-Schröder, S.; Brendel, R.

    2013-11-01

    This work demonstrates the fabrication of a 45 μm thick back-contact back-junction thin-film monocrystalline silicon solar cell from the porous silicon process with an energy conversion efficiency of 18.9%. We demonstrate an efficiency improvement of 5.4% absolute compared to our prior record of 13.5% for back-contact back-junction thin-film monocrystalline silicon solar cells. This increase in efficiency is achieved by reducing the recombination at the base contact using a back surface field and by increasing the generation with a front texture. We investigate the loss mechanisms in the cell using finite element simulations. A free energy loss analysis based on experiments and simulations determines the dominating loss mechanisms. The efficiency loss by base recombination is 0.8% absolute and the loss by base contact recombination is 0.5% absolute in the 18.9% efficiency cell.

  19. Novel low-cost approach for removal of surface contamination before texturization of commercial monocrystalline silicon solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Gangopadhyay, U. [Electronics and Telecommunication Engineering Department, IC Design and Fabrication Centre, Jadavpur University, Kolkata 700032 (India); School of Information and Communication Engineering, Sungkyunkwan University, 300, Chun-Chun dong, Jangan-gu, Suwon, 440-746 (Korea); Dhungel, S.K.; Yi, J. [School of Information and Communication Engineering, Sungkyunkwan University, 300, Chun-Chun dong, Jangan-gu, Suwon, 440-746 (Korea); Mondal, A.K. [Department of Chemistry, Bengal Engineering and Science University, Shibpur, Howrah 71103 (India); Saha, H. [Electronics and Telecommunication Engineering Department, IC Design and Fabrication Centre, Jadavpur University, Kolkata 700032 (India)

    2007-07-23

    This paper reports a novel approach on the surface treatment of monocrystalline silicon solar cells using an inorganic chemical, sodium hypochlorite (NaOCl) that has some remarkable properties. The treatment of contaminated crystalline silicon wafer with hot NaOCl helps the removal of organic contaminants due to its oxidizing properties. The objective of this paper is to establish the effectiveness of this treatment using hot NaOCl solution before the saw damage removal step of the conventional NaOH texturing approach. A comparative study of surface morphology and FTIR analyses of textured monocrystalline silicon surfaces with and without NaOCl pre-treatment is also reported. The process could result in a significant low cost approach viable for cleaning silicon wafers on a mass production scale. (author)

  20. 探测器级NTD硅单晶的研制%Manufacture of NTD Monocrystalline Silicon for Detectors

    Institute of Scientific and Technical Information of China (English)

    李强

    2001-01-01

    介绍了探测器级 NTD 硅单晶的制作工艺,并对如何保证探测器级 NTD 硅单晶的质量进行了讨论。%The process to manufacture the NTD monocrystalline silicon for detectors was described, and the problem how to ensure its quality was discussed.

  1. Thermopower of monocrystalline RESn/sub 3/ compounds (RE = La, Ce, Pr, Nd, Sm, Eu, and Gd)

    Energy Technology Data Exchange (ETDEWEB)

    Kletowski, Z. (Polska Akademia Nauk, Wroclaw. Inst. Niskich Temperatur i Badan Strukturalnych)

    1982-03-16

    The temperature dependence of the thermopower measured in monocrystalline RESn/sub 3/ compounds (RE = La, Ce, Pr, Nd, Sm, Eu, and Gd) has been investigated between 80 and 300 K. It was found that (1) the thermopower is always positive, (2) it differs widely between the compounds in temperature dependence, and (3) CeSn/sub 3/ has a giant thermopower with a well marked maximum of 61 ..mu..V/K at 150 K.

  2. A study on phase transformation of monocrystalline silicon due to ultra-precision polishing by molecular dynamics simulation

    Directory of Open Access Journals (Sweden)

    Lin Zhang

    2012-12-01

    Full Text Available A three-dimensional molecular dynamics (MD simulation is conducted to investigate the material removal mechanism of monocrystalline silicon by mechanical polishing at atomistic scale with diamond abrasives. By monitoring relative positions of atoms in the monocrystalline silicon specimen, the microstructure transformation of monocrystalline silicon is clearly identified and analyzed. The phase transformation is accomplished under extreme conditions with high temperature and huge hydrostatic pressure, and as a result the silicon microstructure transforms from the four-coordinated diamond cubic structure (Si-I to the six-coordinated body-centered tetragonal structure (β-silicon. The values of local pressure and temperature are consistent with previous experimental results. In addition, the force between the diamond abrasive and specimen indicates the occurrence of phase transformation in the specimen. The potential energy of each atom is also calculated, which provides us an effective approach to analyze the energy variation of atoms in the mechanism of material deformation and the formation of machined surface after ultra-precision polishing.

  3. ISOTROPIC TEXTURING OF POLYCRYSTALLINE SILICON WAFERS

    Institute of Scientific and Technical Information of China (English)

    L. Wang; H. Shen; Y.F. Hu

    2005-01-01

    An isotropic etching technique of texturing silicon solar cells has been applied to polycrystalline silicon wafers with different acid concentrations. Optimal etching conditions have been determined by etching rate calculation, scanning electron microscope (SEM) image and reflectance measurement. The surface morphology of the textured wafers varies in accordance with the different etchant concentration which in turn leads to the dissimilarity of etching speed. Textured polycrystalline silicon wafer surfaces display randomly located etched pits which can reduce the surface reflection and enhance the light absorption. The special relationship between reflectivity and etching rate was studied. Reflectance measurements show that isotropic texturing is one of the suitable techniques for texturing polycrystalline silicon wafers and benefits solar cells performances.

  4. Scaling properties of polycrystalline graphene: a review

    Science.gov (United States)

    Isacsson, Andreas; Cummings, Aron W.; Colombo, Luciano; Colombo, Luigi; Kinaret, Jari M.; Roche, Stephan

    2017-03-01

    We present an overview of the electrical, mechanical, and thermal properties of polycrystalline graphene. Most global properties of this material, such as the charge mobility, thermal conductivity, or Young’s modulus, are sensitive to its microstructure, for instance the grain size and the presence of line or point defects. Both the local and global features of polycrystalline graphene have been investigated by a variety of simulations and experimental measurements. In this review, we summarize the properties of polycrystalline graphene, and by establishing a perspective on how the microstructure impacts its large-scale physical properties, we aim to provide guidance for further optimization and improvement of applications based on this material, such as flexible and wearable electronics, and high-frequency or spintronic devices.

  5. Loss analysis of back-contact back-junction thin-film monocrystalline silicon solar cells

    Science.gov (United States)

    Haase, F.; Eidelloth, S.; Horbelt, R.; Bothe, K.; Garralaga Rojas, E.; Brendel, R.

    2011-12-01

    We investigate power losses in back-contact back-junction monocrystalline thin-film silicon solar cells fabricated using the porous silicon layer transfer process. Our loss analysis combines two-dimensional finite element modeling and resistance network simulations. The input parameters of the finite element modeling are determined experimentally by measuring saturation current densities and sheet resistances on test samples prepared identically to the solar cells. Characteristic solar cell parameters such as short circuit current, open circuit voltage, fill factor, and efficiency of measured and network simulated current voltage characteristics investigated in this study match within an uncertainty of 5%. Free energy loss analysis serves as comparison of all losses in units of power per area at the maximum power point. The largest loss is bulk recombination due to a carrier lifetime of 2 μs in the epitaxial Si layer. Further significant losses result from recombination at the base contacts characterized by a diode saturation current density of 50 000 fA cm-2 as well as resistive losses due to lateral majority carrier current flows within the solar cell base and contact resistance losses.

  6. A molecular dynamics study of void initiation and growth in monocrystalline and nanocrystalline copper

    Science.gov (United States)

    Traiviratana, Sirirat

    MD simulations in monocrystalline and nanocrystalline copper were carried out with LAMMPS to reveal void growth mechanisms. The specimens were subjected to both tensile uniaxial and hydrostatic strains; the results confirm that the emission of (shear) loops is the primary mechanism of void growth. The expansion of the loops and their cross slip leads to the severely work hardened layer surrounding a growing void. Calculations were carried out on voids with different sizes, and a size dependence of the stress response to emitted dislocations was observed, in disagreement with the Gurson model [1] which is scale independent. The growth of voids simulated by MD is compared with the Cocks-Ashby constitutive model and significant agreement is found. The density of geometrically-necessary dislocations as a function of void size is calculated based on the emission of shear loops and their outward propagation. Calculations were also carried out for a void at the interface between two grains sharing a tilt boundary. The results show similar dislocation behaviors. A code that uses Voronoi tessellation for constructing nanocrystalline structures was developed and used to prepare the structures for simulations. Nanocrystal simulations reveal grain sliding and grain rotation as the nanocrystal deformed. Voids were nucleated at grain junctions and grew to coalescence as dislocations accommodated the material transfer. A code that can be used during post-processing to extract useful dislocation information from MD simulation data was partially developed and proved the feasibility of automatically analyzing dislocations.

  7. Effect of Shock Compression Method on the Defect Substructure in Monocrystalline Copper

    Energy Technology Data Exchange (ETDEWEB)

    Cao, B Y; Meyers, M A; Lassila, D H; Schneider, M S; Kad, B K; Huang, C X; Xu, Y B; Kalantar, D H; Remington, B A

    2005-02-17

    Monocrystalline copper samples with orientations of [001] and [221] were shocked at pressures ranging from 20 GPa to 60 GPa using two techniques: direct drive lasers and explosively driven flyer plates. The pulse duration for these techniques differed substantially: 2 ns for the laser experiments and 1.1-1.4 {micro}s for the flyer-plate experiments. The residual microstructures were dependent on orientation, pressure, and shocking method. The much shorter pulse duration in laser shock yielded recovery microstructures with no or limited dislocation motion. For the flyer-plate experiments, the longer pulse duration allow shock-generated defects to reorganize into lower energy configurations. Calculations show that the post shock cooling occurs in a time scale of 0.2 s for laser shock and 1000 s for plate-impact shock, propitiating recovery and recrystallization conditions for the latter. At the higher pressure level extensive recrystallization was observed in the plate-impact samples, while it was absent in laser shock. An effect that is proposed to contribute significantly to the formation of recrystallized regions is the existence of micro-shearbands, which increase the local temperature.

  8. The effect of surface microstructure on the optical reflectance of monocrystalline silicon

    Science.gov (United States)

    Wang, Quanji; Zhou, Weidong; Chen, Fangfang; Yang, Ruizhao

    2016-12-01

    Surface texturing is an important technique used to enhance the light absorption by forming certain microstructures on silicon surface. In this article, four different microstructures, based on repeat units of triangles, perpendicular grooves, hexagons and parallel grooves respectively, were fabricated directly on the surface of monocrystalline silicon wafers by using femtosecond laser texturing technique. Compare to the silicon wafers that were not treated by laser, a significant decrease of light reflectance can be observed for those laser etched silicon surfaces. And the treated silicon surface with triangles texture was found to have the lowest relative reflectance of ∼20% in the wavelength range from 400 to 1000 nm, if the textured surfaces were irradiated using the same laser fabrication condition. In addition, the relative reflectance of laser etched silicon surfaces with similar repeat unit but different structural period was investigated as well. The results show that the relative reflectance of the treated surface increases along with the increase of structural period size. These results obtained here can provide a useful guide for fabricating silicon-based optoelectronic devices with a more excellent anti-reflective performance.

  9. Effect of crystal plane orientation on tribochemical removal of monocrystalline silicon

    Science.gov (United States)

    Xiao, Chen; Guo, Jian; Zhang, Peng; Chen, Cheng; Chen, Lei; Qian, Linmao

    2017-01-01

    The effect of crystal plane orientation on tribochemical removal of monocrystalline silicon was investigated using an atomic force microscope. Experimental results indicated that the tribochemical removal of silicon by SiO2 microsphere presented strong crystallography-induced anisotropy. Further analysis suggested that such anisotropic tribochemical removal of silicon was not dependent on the crystallography-dependent surface mechanical properties (i.e., hardness and elastic modulus), but was mainly attributed to various atomic planar density and interplanar spacing in different crystal planes. Phenomenological results speculated that higher density of silicon atom could promote the formation of Si-O-Si bonds between the SiO2 microsphere and silicon substrate, resulting in more severe tribochemical material removal. Larger interplanar spacing with smaller energy barrier facilitated the rupture of the Si-Si network with the help of mechanical shearing stress, which caused more serious wear of the silicon surface. The results may help understand the material removal mechanism of silicon and provide useful knowledge for chemical mechanical polishing.

  10. Effect of crystal plane orientation on tribochemical removal of monocrystalline silicon

    Science.gov (United States)

    Xiao, Chen; Guo, Jian; Zhang, Peng; Chen, Cheng; Chen, Lei; Qian, Linmao

    2017-01-01

    The effect of crystal plane orientation on tribochemical removal of monocrystalline silicon was investigated using an atomic force microscope. Experimental results indicated that the tribochemical removal of silicon by SiO2 microsphere presented strong crystallography-induced anisotropy. Further analysis suggested that such anisotropic tribochemical removal of silicon was not dependent on the crystallography-dependent surface mechanical properties (i.e., hardness and elastic modulus), but was mainly attributed to various atomic planar density and interplanar spacing in different crystal planes. Phenomenological results speculated that higher density of silicon atom could promote the formation of Si-O-Si bonds between the SiO2 microsphere and silicon substrate, resulting in more severe tribochemical material removal. Larger interplanar spacing with smaller energy barrier facilitated the rupture of the Si-Si network with the help of mechanical shearing stress, which caused more serious wear of the silicon surface. The results may help understand the material removal mechanism of silicon and provide useful knowledge for chemical mechanical polishing. PMID:28084433

  11. Design, fabrication and optical characterization of photonic crystal assisted thin film monocrystalline-silicon solar cells.

    Science.gov (United States)

    Meng, Xianqin; Depauw, Valérie; Gomard, Guillaume; El Daif, Ounsi; Trompoukis, Christos; Drouard, Emmanuel; Jamois, Cécile; Fave, Alain; Dross, Frédéric; Gordon, Ivan; Seassal, Christian

    2012-07-02

    In this paper, we present the integration of an absorbing photonic crystal within a monocrystalline silicon thin film photovoltaic stack fabricated without epitaxy. Finite difference time domain optical simulations are performed in order to design one- and two-dimensional photonic crystals to assist crystalline silicon solar cells. The simulations show that the 1D and 2D patterned solar cell stacks would have an increased integrated absorption in the crystalline silicon layer would increase of respectively 38% and 50%, when compared to a similar but unpatterned stack, in the whole wavelength range between 300 nm and 1100 nm. In order to fabricate such patterned stacks, we developed an effective set of processes based on laser holographic lithography, reactive ion etching and inductively coupled plasma etching. Optical measurements performed on the patterned stacks highlight the significant absorption increase achieved in the whole wavelength range of interest, as expected by simulation. Moreover, we show that with this design, the angle of incidence has almost no influence on the absorption for angles as high as around 60°.

  12. Glovebox Advanced Casting System Casting Optimization

    Energy Technology Data Exchange (ETDEWEB)

    Fielding, Randall Sidney [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-03-01

    Casting optimization in the GACS included three broad areas; casting of U-10Zr pins, incorporation of an integral FCCI barrier, and development of a permanent crucible coating. U-10Zr casting was improved over last year’s results by modifying the crucible design to minimize contact with the colder mold. Through these modifications casting of a three pin batch was successful. Incorporation of an integral FCCI barrier also was optimized through furnace chamber pressure changes during the casting cycle to reduce gas pressures in the mold cavities which led to three full length pins being cast which incorporated FCCI barriers of three different thicknesses. Permanent crucible coatings were tested against a base case; 1500°C for 10 minutes in a U-20Pu-10Zr molten alloy. None of the candidate coating materials showed evidence of failure upon initial visual examination. In all areas of work a large amount of characterization will be needed to fully determine the effects of the optimization activities. The characterization activities and future work will occur next year.

  13. Stochastic Multiscale Modeling of Polycrystalline Materials

    Science.gov (United States)

    2013-01-01

    Thrun, and K. Ober- mayer , editors, Advances in Neural Information Processing Systems 15, pages 705–712, Cambridge, MA, 2003. MIT Press. [19] E Van der...modeling of polycrystalline IN 100. International Journal of Plasticity, 24(10):1694–1730, 2008. Special Issue in Honor of Jean - Louis Chaboche. [111] V. B

  14. Extremal Overall Elastic Response of Polycrystalline Materials

    DEFF Research Database (Denmark)

    Bendsøe, Martin P; Lipton, Robert

    1997-01-01

    Polycrystalline materials comprised of grains obtained from a single anisotropic material are considered in the framework of linear elasticity. No assumptions on the symmetry of the polycrystal are made. We subject the material to independent external strain and stress fields with prescribed mean...

  15. PREPARATION AND CHARACTERIZATION OF POLY-CRYSTALLINE SILICON THIN FILM

    Institute of Scientific and Technical Information of China (English)

    Y.F. Hu; H. Shen; Z.Y. Liu; L.S. Wen

    2003-01-01

    Poly-crystalline silicon thin film has big potential of reducing the cost of solar cells.In this paper the preparation of thin film is introduced, and then the morphology of poly-crystalline thin film is discussed. On the film we developed poly-crystalline silicon thin film solar cells with efficiency up to 6. 05% without anti-reflection coating.

  16. Polycrystalline Silicon Sheets for Solar Cells by the Improved Spinning Method

    Science.gov (United States)

    Maeda, Y.; Yokoyama, T.; Hide, I.

    1984-01-01

    Cost reduction of silicon materials in the photovoltaic program of materials was examined. The current process of producing silicon sheets is based entirely on the conventional Czochralski ingot growth and wafering used in the semiconductor industry. The current technology cannot meet the cost reduction demands for producing low cost silicon sheets. Alternative sheet production processes such as unconventional crystallization are needed. The production of polycrystalline silicon sheets by unconventional ingot technology is the casting technique. Though large grain sheets were obtained by this technique, silicon ribbon growth overcomes deficiencies of the casting process by obtaining the sheet directly from the melt. The need to solve difficulties of growth stability and impurity effects are examined. The direct formation process of polycrystalline silicon sheets with large grain size, smooth surface, and sharp edges from the melt with a high growth rate which will yield low cost silicon sheets for solar cells and the photovoltaic characteristics associated with this type of sheet to include an EBIC study of the grain boundaries are described.

  17. Stochastic multiscale modeling of polycrystalline materials

    Science.gov (United States)

    Wen, Bin

    Mechanical properties of engineering materials are sensitive to the underlying random microstructure. Quantification of mechanical property variability induced by microstructure variation is essential for the prediction of extreme properties and microstructure-sensitive design of materials. Recent advances in high throughput characterization of polycrystalline microstructures have resulted in huge data sets of microstructural descriptors and image snapshots. To utilize these large scale experimental data for computing the resulting variability of macroscopic properties, appropriate mathematical representation of microstructures is needed. By exploring the space containing all admissible microstructures that are statistically similar to the available data, one can estimate the distribution/envelope of possible properties by employing efficient stochastic simulation methodologies along with robust physics-based deterministic simulators. The focus of this thesis is on the construction of low-dimensional representations of random microstructures and the development of efficient physics-based simulators for polycrystalline materials. By adopting appropriate stochastic methods, such as Monte Carlo and Adaptive Sparse Grid Collocation methods, the variability of microstructure-sensitive properties of polycrystalline materials is investigated. The primary outcomes of this thesis include: (1) Development of data-driven reduced-order representations of microstructure variations to construct the admissible space of random polycrystalline microstructures. (2) Development of accurate and efficient physics-based simulators for the estimation of material properties based on mesoscale microstructures. (3) Investigating property variability of polycrystalline materials using efficient stochastic simulation methods in combination with the above two developments. The uncertainty quantification framework developed in this work integrates information science and materials science, and

  18. High integrity automotive castings

    Energy Technology Data Exchange (ETDEWEB)

    Weiss, D. [Eck Industries Inc., St. Manitowoc, WI (United States)

    2007-07-01

    This paper described the High Integrity Magnesium Automotive Casting (HI-MAC) program, which was developed to ensure the widespread adoption of magnesium in structural castings. The program will encourage the use of low pressure permanent molds, squeeze casting, and electromagnetic pumping of magnesium into dies. The HI-MAC program is currently investigating new heat treatment methods, and is in the process of creating improved fluid flow and solidification modelling to produce high volume automotive components. In order to address key technology barriers, the program has been divided into 8 tasks: (1) squeeze casting process development; (2) low pressure casting technology; (3) thermal treatment; (4) microstructure control; (5) computer modelling and properties; (6) controlled molten metal transfer and filling; (7) emerging casting technologies; and (8) technology transfer throughout the automotive value chain. Technical challenges were outlined for each of the tasks. 1 ref., 3 tabs., 5 figs.

  19. Improving Metal Casting Process

    Science.gov (United States)

    1998-01-01

    Don Sirois, an Auburn University research associate, and Bruce Strom, a mechanical engineering Co-Op Student, are evaluating the dimensional characteristics of an aluminum automobile engine casting. More accurate metal casting processes may reduce the weight of some cast metal products used in automobiles, such as engines. Research in low gravity has taken an important first step toward making metal products used in homes, automobiles, and aircraft less expensive, safer, and more durable. Auburn University and industry are partnering with NASA to develop one of the first accurate computer model predictions of molten metals and molding materials used in a manufacturing process called casting. Ford Motor Company's casting plant in Cleveland, Ohio is using NASA-sponsored computer modeling information to improve the casting process of automobile and light-truck engine blocks.

  20. Performance Steel Castings

    Science.gov (United States)

    2012-09-30

    alloys , foundry, muzzle brake, supply center, tooling, sources Notice Distribution Statement A Format Information Report created in Microsoft Word...Development of Sand Properties 103 Advanced Modeling Dataset.. 105 High Strength Low Alloy (HSLA) Steels 107 Steel Casting and Engineering Support...University, University of Northern Iowa, Non- Ferrous Founders’ Society, QuesTek, buyCASTINGS.com, Spokane Industries, Nova Precision Casting, Waukesha

  1. Evolution of halictine castes

    Science.gov (United States)

    Knerer, Gerd

    1980-03-01

    Social halictine bees have female castes that range from species with no size differences to those with a discrete bimodality. Female caste differences are inversely correlated with the number of males produced in the first brood. It is proposed that the sexual dimorphism of solitary forms is being usurped by the female caste system of species in the process of turning social. Thus, caste differences and summer male suppression are greatest in the social species originating from solitary precursors with distinct sexual dimorphism, and are least in species evolving from solitary ancestors with a continuous sexual polymorphism.

  2. Caste in Itself, Caste and Class, or Caste in Class

    OpenAIRE

    Ramkrishna Mukherjee

    2015-01-01

    After the British conquered Bengal and eventually the whole of India,they set out to administer the colony. In this context they encountered two phenomena with which they were not familiar: (1) the relation of people to land for production (and not for revenue receiving, household living, etc.), and (2) the caste system of India, viz. the jati strati?cation of society.

  3. Photoionization of monocrystalline CVD diamond irradiated with ultrashort intense laser pulse

    Science.gov (United States)

    Lagomarsino, Stefano; Sciortino, Silvio; Obreshkov, Boyan; Apostolova, Tzveta; Corsi, Chiara; Bellini, Marco; Berdermann, Eleni; Schmidt, Christian J.

    2016-02-01

    Direct laser writing of conductive paths in synthetic diamond is of interest for implementation in radiation detection and clinical dosimetry. Unraveling the microscopic processes involved in laser irradiation of diamond below and close to the graphitization threshold under the same conditions as the experimental procedure used to produce three-dimensional devices is necessary to tune the laser parameters to optimal results. To this purpose a transient currents technique has been used to measure laser-induced current signals in monocrystalline diamond detectors in a wide range of laser intensities and at different bias voltages. The current transients vs time and the overall charge collected have been compared with theoretical simulations of the carrier dynamics along the duration and after the conclusion of the 30 fs laser pulse. The generated charge has been derived from the collected charge by evaluation of the lifetime of the carriers. The plasma volume has also been evaluated by measuring the modified region. The theoretical simulation has been implemented in the framework of the empirical pseudopotential method extended to include time-dependent couplings of valence electrons to the radiation field. The simulation, in the low-intensity regime, I ˜1 TW /cm2 , predicts substantial deviation from the traditional multiphoton ionization, due to nonperturbative effects involving electrons from degenerate valence bands. For strong field with intensity of about 50 TW /cm2, nonadiabatic effects of electron-hole pair excitation become prominent with high carrier densities eventually causing the optical breakdown of diamond. The comparison of theoretical prediction with experimental data of laser-generated charge vs laser energy density yields a good quantitative agreement over six orders of magnitude. At the highest intensities the change of slope in the trend is explained taking into account the dependence of the optical parameters and the carrier mobility on plasma

  4. The Effects of Cells Temperature Increment and Variations of Irradiation for Monocrystalline Photovoltaic

    Science.gov (United States)

    Fuad Rahman Soeharto, Faishal; Hermawan

    2017-04-01

    Photovoltaic cell technology has been developed to meet the target of 17% Renewable Energy in 2025 accordance with Indonesia Government Regulation No. 5 2006. Photovoltaic cells are made of semiconductor materials, namely silicon or germanium (p-n junction). These cells need the light that comes from solar irradiation which brings energy photons to convert light energy into electrical energy. It is different from the solar heater that requires heat energy or thermal of sunlight that is normally used for drying or heating water. Photovoltaic cells requires energy photons to perform the energy conversion process, the photon energy can be derived from sunlight. Energy photon is taken from the sun light along with the advent of heat due to black-body radiation, which can lead to temperature increments of photovoltaic cells. Increment of 1°C can decreased photovoltaic cell voltage of up to 2.3 mV per cell. In this research, it will be discuss the analysis of the effect of rising temperatures and variations of irradiation on the type monocrystalline photovoltaic. Those variation are analyzed, simulated and experiment by using a module of experiment. The test results show that increment temperature from 25° C to 80° C at cell of photovoltaic decrease the output voltage of the photovoltaic cell at 4.21 V, and it also affect the power output of the cell which decreases up to 0.7523 Watt. In addition, the bigger the value of irradiation received by cell at amount of 1000 W / m2, produce more output power cells at the same temperature.

  5. Research on the effects of machining-induced subsurface damages on mono-crystalline silicon via molecular dynamics simulation

    Energy Technology Data Exchange (ETDEWEB)

    Zhao Hongwei, E-mail: hwzhao@jlu.edu.cn [College of Mechanical Science and Engineering, Jilin University, 5988 Renmin Street, Changchun, Jilin 130025 (China); Shi Chengli; Zhang Peng; Zhang Lin; Huang Hu; Yan Jiwang [College of Mechanical Science and Engineering, Jilin University, 5988 Renmin Street, Changchun, Jilin 130025 (China)

    2012-10-15

    Highlights: Black-Right-Pointing-Pointer MD simulations of nano-cutting process are carried out to obtain machining-induced subsurface with diamond cutting tools. Black-Right-Pointing-Pointer After cutting, the crystal lattice reconstructed and led to the formation of the machined surface. Black-Right-Pointing-Pointer The mechanical properties of the pristine and machining-induced subsurface Si are studied by means of nanoindentation. Black-Right-Pointing-Pointer Nanoindentation results show that the hardness of the machined surface was smaller than mono-crystalline Si. - Abstract: Nanoindentation simulation via molecular dynamic (MD) method was carried out to investigate the characteristics of machining-induced subsurface damage of mono-crystalline silicon with a spherical diamond indenter. In this study, MD simulations of nano-cutting process were carried out firstly to cut through the specimen's surface with diamond cutting tools of different edge radius of 0 nm, 3 nm and 5 nm respectively. Then, MD simulation of nanoindentation on the machined surface was carried out. Tersoff potential was used to model the interaction of Si atoms, and the interaction between Si and C atoms was modeled by Morse potential. Simulational results indicate that during cutting process, the specimen undergo plastic deformation and phase transformation. After cutting process, the crystal lattice reconstructs and the residual amorphous layers lead to the formation of the machined surface. Nanoindentation results show that the hardness of the machined surface is smaller than mono-crystalline Si. So in order to get accurate properties of the pristine silicon or other semiconductor materials via experiments, the amorphous phase should be completely removed or it would influence the mechanical properties of the pristine materials.

  6. Higher Education's Caste System

    Science.gov (United States)

    Iannone, Ron

    2004-01-01

    In this article, the author discusses the history of the present caste system in higher education. He shows how the public's perception of this caste system is based on image and not usually on the quality of teaching and curriculum in colleges and universities. Finally, he discusses a model for accessibility to higher education and how higher…

  7. A cast orientation index.

    Science.gov (United States)

    Ivanhoe, J R; Mahanna, G K

    1994-12-01

    This article describes a technique that allows multiple master casts to be precisely oriented to the same path of insertion and withdrawal. This technique is useful in situations where multiple fixed prosthodontic preparations require surveyed restorations and a single master cast is not available.

  8. Caste and power

    DEFF Research Database (Denmark)

    Roy, Dayabati

    2011-01-01

    This paper explores the institution of caste and its operation in a micro-level village setting of West Bengal, an Indian state, where state politics at grass roots level is vibrant with functioning local self-government and entrenched political parties. This ethnographic study reveals that caste...

  9. Coating curly carbon nanotubes with monocrystalline Zn(BO2)2 and the mechanism of straightening the tubes

    Institute of Scientific and Technical Information of China (English)

    LIU; Jinzhang; YAN; Pengxun; YUE; Guanghui

    2006-01-01

    We overgrew single-crystalline Zn(BO2)2 coatings on carbon nanotubes (CNTs) for the first time. Scanning electron microscopy and transmission electron microscopy analyses revealed that the carbon nanotube-zinc borate composite rods are from tens to hundreds of nm in diameter. It is notable that the original curly tubes were straightened by the monocrystalline coatings. In addition, the crystal nucleation and growth on the surface of CNT were explained. We set a two-dimensional model, which is based on our experimental result, to qualitatively explain the mechanism of straightening the curly tubes by coating them with single-crystals.

  10. Equilibrium shapes of polycrystalline silicon nanodots

    Energy Technology Data Exchange (ETDEWEB)

    Korzec, M. D., E-mail: korzec@math.tu-berlin.de; Wagner, B., E-mail: bwagner@math.tu-berlin.de [Department of Mathematics, Technische Universität Berlin, Straße des 17. Juni 136, 10623 Berlin (Germany); Roczen, M., E-mail: maurizio.roczen@physik.hu-berlin.de [Department of Physics, Humboldt-Universität zu Berlin, Newtonstraße 15, 12489 Berlin (Germany); Schade, M., E-mail: martin.schade@physik.uni-halle.de [Zentrum für Innovationskompetenz SiLi-nano, Martin-Luther-Universität Halle-Wittenberg, Karl-Freiherr-von-Fritsch-Straße 3, 06120 Halle (Germany); Rech, B., E-mail: bernd.rech@helmholtz-berlin.de [Helmholtz-Zentrum Berlin, Institute for Silicon Photovoltaics, Kekuléstraße 5, 12489 Berlin (Germany)

    2014-02-21

    This study is concerned with the topography of nanostructures consisting of arrays of polycrystalline nanodots. Guided by transmission electron microscopy (TEM) measurements of crystalline Si (c-Si) nanodots that evolved from a “dewetting” process of an amorphous Si (a-Si) layer from a SiO{sub 2} coated substrate, we investigate appropriate formulations for the surface energy density and transitions of energy density states at grain boundaries. We introduce a new numerical minimization formulation that allows to account for adhesion energy from an underlying substrate. We demonstrate our approach first for the free standing case, where the solutions can be compared to well-known Wulff constructions, before we treat the general case for interfacial energy settings that support “partial wetting” and grain boundaries for the polycrystalline case. We then use our method to predict the morphologies of silicon nanodots.

  11. Polycrystalline thin films FY 1992 project report

    Energy Technology Data Exchange (ETDEWEB)

    Zweibel, K. [ed.

    1993-01-01

    This report summarizes the activities and results of the Polycrystalline Thin Film Project during FY 1992. The purpose of the DOE/NREL PV (photovoltaic) Program is to facilitate the development of PV that can be used on a large enough scale to produce a significant amount of energy in the US and worldwide. The PV technologies under the Polycrystalline Thin Film project are among the most exciting ``next-generation`` options for achieving this goal. Over the last 15 years, cell-level progress has been steady, with laboratory cell efficiencies reaching levels of 15 to 16%. This progress, combined with potentially inexpensive manufacturing methods, has attracted significant commercial interest from US and international companies. The NREL/DOE program is designed to support the efforts of US companies through cost-shared subcontracts (called ``government/industry partnerships``) that we manage and fund and through collaborative technology development work among industry, universities, and our laboratory.

  12. Polycrystalline thin films FY 1992 project report

    Energy Technology Data Exchange (ETDEWEB)

    Zweibel, K. (ed.)

    1993-01-01

    This report summarizes the activities and results of the Polycrystalline Thin Film Project during FY 1992. The purpose of the DOE/NREL PV (photovoltaic) Program is to facilitate the development of PV that can be used on a large enough scale to produce a significant amount of energy in the US and worldwide. The PV technologies under the Polycrystalline Thin Film project are among the most exciting next-generation'' options for achieving this goal. Over the last 15 years, cell-level progress has been steady, with laboratory cell efficiencies reaching levels of 15 to 16%. This progress, combined with potentially inexpensive manufacturing methods, has attracted significant commercial interest from US and international companies. The NREL/DOE program is designed to support the efforts of US companies through cost-shared subcontracts (called government/industry partnerships'') that we manage and fund and through collaborative technology development work among industry, universities, and our laboratory.

  13. CHEMICAL AND ELECTRICAL CHARACTERIZATION OF POLYCRYSTALLINE SEMICONDUCTORS

    OpenAIRE

    1982-01-01

    The chemistry and composition of inter- and intragrain regions in polycrystalline semiconductors can be related to, as well as dominate, the electrical characteristics of the materials, and devices fabricated from them. In this paper, high-resolution, complementary surface analysis techniques, including Auger electron spectroscopy (AES), secondary ion mass spectroscopy (SIMS), X-ray photoelectron spectroscopy (XPS) and low-energy electron loss spectroscopy (EELS), are used to investigate the ...

  14. Multi-layers castings

    Directory of Open Access Journals (Sweden)

    J. Szajnar

    2010-01-01

    Full Text Available In paper is presented the possibility of making of multi-layers cast steel castings in result of connection of casting and welding coating technologies. First layer was composite surface layer on the basis of Fe-Cr-C alloy, which was put directly in founding process of cast carbon steel 200–450 with use of preparation of mould cavity method. Second layer were padding welds, which were put with use of TIG – Tungsten Inert Gas surfacing by welding technology with filler on Ni matrix, Ni and Co matrix with wolfram carbides WC and on the basis on Fe-Cr-C alloy, which has the same chemical composition with alloy, which was used for making of composite surface layer. Usability for industrial applications of surface layers of castings were estimated by criterion of hardness and abrasive wear resistance of type metal-mineral.

  15. Conductivity size effect of polycrystalline metal nanowires

    Directory of Open Access Journals (Sweden)

    Weihuang Xue

    2016-11-01

    Full Text Available It is well known that the conductivity of metal nanowires decreases with the wire diameter. This size effect was first studied for metal thin films when the film thickness approaches the electron mean free path. Fuchs & Sondheimer (FS pointed out that the external surface scattering of the electrons contributes to the conductivity decrease. Mayadas and Shatzkes (MS pointed out that the grain boundary scattering plays a major role for polycrystalline thin films. As is clear that nanowires are 2-d constrained instead of 1-d for thin film, so the size effect would be more eminent. However, today the mostly used physical model for the conductivity of metal nanowires is still the MS theory. This paper proposes a more complete model suitable for circular cross-section polycrystalline metal nanowires, which takes into account of background scattering, external surface scattering, as well as grain boundary scattering. Comparison with experiment data showed that our model can well explain the conductivity size effect of polycrystalline metal nanowires.

  16. Characterization of electrochemically modified polycrystalline platinum surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Krebs, L.C.; Ishida, Takanobu.

    1991-12-01

    The characterization of electrochemically modified polycrystalline platinum surfaces has been accomplished through the use of four major electrochemical techniques. These were chronoamperometry, chronopotentiommetry, cyclic voltammetry, and linear sweep voltammetry. A systematic study on the under-potential deposition of several transition metals has been performed. The most interesting of these were: Ag, Cu, Cd, and Pb. It was determined, by subjecting the platinum electrode surface to a single potential scan between {minus}0.24 and +1.25 V{sub SCE} while stirring the solution, that the electrocatalytic activity would be regenerated. As a consequence of this study, a much simpler method for producing ultra high purity water from acidic permanganate has been developed. This method results in water that surpasses the water produced by pyrocatalytic distillation. It has also been seen that the wettability of polycrystalline platinum surfaces is greatly dependent on the quantity of oxide present. Oxide-free platinum is hydrophobic and gives a contact angle in the range of 55 to 62 degrees. We have also modified polycrystalline platinum surface with the electrically conducting polymer poly-{rho}-phenylene. This polymer is very stable in dilute sulfuric acid solutions, even under applied oxidative potentials. It is also highly resistant to electrochemical hydrogenation. The wettability of the polymer modified platinum surface is severely dependent on the choice of supporting electrolyte chosen for the electrochemical polymerization. Tetraethylammonium tetrafluoroborate produces a film that is as hydrophobic as Teflon, whereas tetraethylammonium perchlorate produces a film that is more hydrophilic than oxide-free platinum.

  17. Caste in Itself, Caste and Class, or Caste in Class

    Directory of Open Access Journals (Sweden)

    Ramkrishna Mukherjee

    2015-08-01

    Full Text Available After the British conquered Bengal and eventually the whole of India,they set out to administer the colony. In this context they encountered two phenomena with which they were not familiar: (1 the relation of people to land for production (and not for revenue receiving, household living, etc., and (2 the caste system of India, viz. the jati strati?cation of society.

  18. The ancient Chinese casting techniques

    Directory of Open Access Journals (Sweden)

    Tan Derui

    2011-02-01

    Full Text Available In the course of Chinese civilization, which lasted more than 5,000 years, casting production has made a huge contribution. In this paper, some representative metal castings were presented. According to their forming techniques, they can be grouped into stone mould casting, clay mould casting, ablation casting, lost wax casting, stack casting, permanent mould casting, sand casting, etc. According to their materials, they can be categorized into tin bronze, bimetallic bronze, malleable cast iron, ductile cast iron, brass, cupronickel alloy (Packtong, etc. According to their surface decorative techniques they can be devided into gem inlay, gilding, gold and silver inlay, copper inlay, engraved decoration, surface tin-enrichment, mother-of-pearl inlay, burnished works with gold or silver inlay, surface coloring and cloisonné enamel, etc.

  19. Clean Metal Casting

    Energy Technology Data Exchange (ETDEWEB)

    Makhlouf M. Makhlouf; Diran Apelian

    2002-02-05

    The objective of this project is to develop a technology for clean metal processing that is capable of consistently providing a metal cleanliness level that is fit for a given application. The program has five tasks: Development of melt cleanliness assessment technology, development of melt contamination avoidance technology, development of high temperature phase separation technology, establishment of a correlation between the level of melt cleanliness and as cast mechanical properties, and transfer of technology to the industrial sector. Within the context of the first task, WPI has developed a standardized Reduced Pressure Test that has been endorsed by AFS as a recommended practice. In addition, within the context of task1, WPI has developed a melt cleanliness sensor based on the principles of electromagnetic separation. An industrial partner is commercializing the sensor. Within the context of the second task, WPI has developed environmentally friendly fluxes that do not contain fluorine. Within the context of the third task, WPI modeled the process of rotary degassing and verified the model predictions with experimental data. This model may be used to optimize the performance of industrial rotary degassers. Within the context of the fourth task, WPI has correlated the level of melt cleanliness at various foundries, including a sand casting foundry, a permanent mold casting foundry, and a die casting foundry, to the casting process and the resultant mechanical properties. This is useful in tailoring the melt cleansing operations at foundries to the particular casting process and the desired properties of cast components.

  20. Symptomatic stent cast.

    Science.gov (United States)

    Keohane, John; Moore, Michael; O'Mahony, Seamus; Crosbie, Orla

    2008-02-01

    Biliary stent occlusion is a major complication of endoscopic stent insertion and results in repeat procedures. Various theories as to the etiology have been proposed, the most frequently studied is the attachment of gram negative bacteria within the stent. Several studies have shown prolongation of stent patency with antibiotic prophylaxis. We report the case of stent occlusion from a cast of a previously inserted straight biliary stent; a "stent cast" in an 86-year-old woman with obstructive jaundice. This was retrieved with the lithotrypter and she made an uneventful recovery. This is the first reported case of a biliary stent cast.

  1. CENTRIFUGAL CASTING MACHINE

    Science.gov (United States)

    Shuck, A.B.

    1958-04-01

    A device is described that is specifically designed to cast uraniumn fuel rods in a vacuunn, in order to obtain flawless, nonoxidized castings which subsequently require a maximum of machining or wastage of the expensive processed material. A chamber surrounded with heating elements is connected to the molds, and the entire apparatus is housed in an airtight container. A charge of uranium is placed in the chamber, heated, then is allowed to flow into the molds While being rotated. Water circulating through passages in the molds chills the casting to form a fine grained fuel rod in nearly finished form.

  2. Symptomatic stent cast.

    LENUS (Irish Health Repository)

    Keohane, John

    2012-02-03

    Biliary stent occlusion is a major complication of endoscopic stent insertion and results in repeat procedures. Various theories as to the etiology have been proposed, the most frequently studied is the attachment of gram negative bacteria within the stent. Several studies have shown prolongation of stent patency with antibiotic prophylaxis. We report the case of stent occlusion from a cast of a previously inserted straight biliary stent; a "stent cast" in an 86-year-old woman with obstructive jaundice. This was retrieved with the lithotrypter and she made an uneventful recovery. This is the first reported case of a biliary stent cast.

  3. Bainite obtaining in cast iron with carbides castings

    Directory of Open Access Journals (Sweden)

    S. Pietrowski

    2010-01-01

    Full Text Available In these paper the possibility of upper and lower bainite obtaining in cast iron with carbides castings are presented. Conditions, when in cast iron with carbides castings during continuous free air cooling austenite transformation to upper bainite or its mixture with lower bainte proceeds, have been given. A mechanism of this transformation has been given, Si, Ni, Mn and Mo distribution in the eutectic cell has been tested and hardness of tested castings has been determined.

  4. Colour Metallography of Cast Iron

    Institute of Scientific and Technical Information of China (English)

    Zhou Jiyang; Liu Jincheng

    2011-01-01

    White Cast Iron (Ⅰ) White cast iron or ‘white iron' refers to the type of cast iron in which all of the carbon exists as carbide;there is no graphite in the as-cast structure and the fractured surface shows a white colour.White cast iron can be divided in three classes:· Normal white cast iron — this iron contains only C,Si,Mn,P and S,with no other alloying elements.· Low-alloy white cast iron — the total mass fraction of alloying elements is less than 5%.

  5. Abnormality in fracture strength of polycrystalline silicene

    Science.gov (United States)

    Liu, Ning; Hong, Jiawang; Pidaparti, Ramana; Wang, Xianqiao

    2016-09-01

    Silicene, a silicon-based homologue of graphene, arouses great interest in nano-electronic devices due to its outstanding electronic properties. However, its promising electronic applications are greatly hindered by lack of understanding in the mechanical strength of silicene. Therefore, in order to design mechanically reliable devices with silicene, it is necessary to thoroughly explore the mechanical properties of silicene. Due to current fabrication methods, graphene is commonly produced in a polycrystalline form; the same may hold for silicene. Here we perform molecular dynamics simulations to investigate the mechanical properties of polycrystalline silicene. First, an annealing process is employed to construct a more realistic modeling structure of polycrystalline silicene. Results indicate that a more stable structure is formed due to the breaking and reformation of bonds between atoms on the grain boundaries. Moreover, as the grain size decreases, the efficiency of the annealing process, which is quantified by the energy change, increases. Subsequently, biaxial tensile tests are performed on the annealed samples in order to explore the relation between grain size and mechanical properties, namely in-plane stiffness, fracture strength and fracture strain etc. Results indicate that as the grain size decreases, the fracture strain increases while the fracture strength shows an inverse trend. The decreasing fracture strength may be partly attributed to the weakening effect from the increasing area density of defects which acts as the reservoir of stress-concentrated sites on the grain boundary. The observed crack localization and propagation and fracture strength are well-explained by a defect-pileup model.

  6. Interstellar extinction by fractal polycrystalline graphite clusters?

    CERN Document Server

    Andersen, A C; Pustovit, V N; Niklasson, G A

    2001-01-01

    Certain dust particles in space are expected to appear as clusters of individual grains. The morphology of these clusters could be fractal or compact. To determine how these structural features would affect the interpretation of the observed interstellar extinction peak at $\\sim 4.6~\\mu$m, we have calculated the extinction by compact and fractal polycrystalline graphite clusters consisting of touching identical spheres. We compare three general methods for computing the extinction of the clusters, namely, a rigorous solution and two different discrete-dipole approximation methods.

  7. High vacuum tribology of polycrystalline diamond coatings

    Indian Academy of Sciences (India)

    Awadesh K Mallik; S A Shivashankar; S K Biswas

    2009-10-01

    Polycrystalline diamond coatings have been grown on unpolished side of Si(100) wafers by hot filament chemical vapour deposition process. The morphology of the grown coatings has been varied from cauliflower morphology to faceted morphology by manipulation of the growth temperature from 700°C to 900°C and methane gas concentration from 3% to 1·5%. It is found that the coefficient of friction of the coatings under high vacuum of 133·32 × 10-7 Pa (10-7 torr) with nanocrystalline grains can be manipulated to 0·35 to enhance tribological behaviour of bare Si substrates.

  8. Novel mercuric iodide polycrystalline nuclear particles counters

    Energy Technology Data Exchange (ETDEWEB)

    Schieber, M. [Hebrew Univ. of Jerusalem (Israel)]|[Sandia National Lab., Livermore, CA (United States); Zuck, A.; Braiman, M.; Nissenbaum, J. [Hebrew Univ. of Jerusalem (Israel)] [and others

    1996-12-31

    Polycrystalline mercuric iodide nuclear radiation detectors having areas between 0.01 to 100 cm{sup 2} and thicknesses 30 to 600 microns, have been fabricated with single, linear strip and square pixel contact. The large area detectors 10 to 600 cm{sup 2} were produced by industrial ceramic equipment while the smaller ones, about 1 cm{sup 2} area, were produced in the laboratory. The large detectors still had large leakage currents and the production process is being revised. The smaller detectors were tested and their response to lower and higher gamma energy, beta and even 100 GeV muons at CERN will be reported.

  9. Superelastic effect in polycrystalline ferrous alloys.

    Science.gov (United States)

    Omori, T; Ando, K; Okano, M; Xu, X; Tanaka, Y; Ohnuma, I; Kainuma, R; Ishida, K

    2011-07-01

    In superelastic alloys, large deformation can revert to a memorized shape after removing the stress. However, the stress increases with increasing temperature, which limits the practical use over a wide temperature range. Polycrystalline Fe-Mn-Al-Ni shape memory alloys show a small temperature dependence of the superelastic stress because of a small transformation entropy change brought about by a magnetic contribution to the Gibbs energies. For one alloy composition, the superelastic stress varies by 0.53 megapascal/°C over a temperature range from -196 to 240°C.

  10. Anomalous Hall effect in polycrystalline Ni films

    KAUST Repository

    Guo, Zaibing

    2012-02-01

    We systematically studied the anomalous Hall effect in a series of polycrystalline Ni films with thickness ranging from 4 to 200 nm. It is found that both the longitudinal and anomalous Hall resistivity increased greatly as film thickness decreased. This enhancement should be related to the surface scattering. In the ultrathin films (46 nm thick), weak localization corrections to anomalous Hall conductivity were studied. The granular model, taking into account the dominated intergranular tunneling, has been employed to explain this phenomenon, which can explain the weak dependence of anomalous Hall resistivity on longitudinal resistivity as well. © 2011 Elsevier Ltd. All rights reserved.

  11. Numerical simulation and fabrication of silicon sheet via spin casting.

    Science.gov (United States)

    Lee, Jaewoo; Kim, Hyunhui; Lee, Changbum; Kim, Joonsoo; Jang, Bo-Yun; Lee, Jinseok; Ahn, Youngsoo; Yoon, Wooyoung

    2013-05-01

    A spin-casting process for fabricating polycrystalline silicon sheets for use as solar cell wafers is proposed, and the parameters that control the sheet thickness are investigated. A numerical study of the fluidity of molten silicon indicates that the formation of thin silicon sheets without a mold and via spin casting is feasible. The faster the rotation speed of graphite mold, the thinner the thickness of sheet. After the spread of the molten silicon to cover the graphite mold with rotation speed of above 500 rpm, the solidification has to start. Silicon sheets can be produced by using the centrifugal force under appropriate experimental conditions. The spin-cast sheet had a vertical columnar microstructure due to the normal heat extraction to the substrate, and the sheet lifetime varied from 0.1 microS to 0.3 microS measured by using the microwave photoconductance decay (MW-PCD) to confirm that the spin-cast silicon sheet is applicable to photovoltaics.

  12. Polycrystalline thin film materials and devices

    Energy Technology Data Exchange (ETDEWEB)

    Baron, B.N.; Birkmire, R.W.; Phillips, J.E.; Shafarman, W.N.; Hegedus, S.S.; McCandless, B.E. (Delaware Univ., Newark, DE (United States). Inst. of Energy Conversion)

    1992-10-01

    Results of Phase II of a research program on polycrystalline thin film heterojunction solar cells are presented. Relations between processing, materials properties and device performance were studied. The analysis of these solar cells explains how minority carrier recombination at the interface and at grain boundaries can be reduced by doping of windows and absorber layers, such as in high efficiency CdTe and CuInSe{sub 2} based solar cells. The additional geometric dimension introduced by the polycrystallinity must be taken into consideration. The solar cells are limited by the diode current, caused by recombination in the space charge region. J-V characteristics of CuInSe{sub 2}/(CdZn)S cells were analyzed. Current-voltage and spectral response measurements were also made on high efficiency CdTe/CdS thin film solar cells prepared by vacuum evaporation. Cu-In bilayers were reacted with Se and H{sub 2}Se gas to form CuInSe{sub 2} films; the reaction pathways and the precursor were studied. Several approaches to fabrication of these thin film solar cells in a superstrate configuration were explored. A self-consistent picture of the effects of processing on the evolution of CdTe cells was developed.

  13. Physical and mechanical properties of highly textured polycrystalline Nb4AlC3 ceramic

    Directory of Open Access Journals (Sweden)

    Chunfeng Hu, Yoshio Sakka, Toshiyuki Nishimura, Shuqi Guo, Salvatore Grasso and Hidehiko Tanaka

    2011-01-01

    Full Text Available Highly textured polycrystalline Nb4AlC3 ceramic was fabricated by slip casting in a strong magnetic field followed by spark plasma sintering. Its Lotgering orientation factor was determined on the textured top and side surfaces as f(00l ~1.0 and f(hk0=0.36, respectively. This ceramic showed layered microstructure at the scales ranging from nanometers to millimeters. The as-prepared ceramic had excellent anisotropic physical properties. Along the c-axis direction, it showed higher hardness, bending strength, and fracture toughness of 7.0 GPa, 881 MPa and 14.1 MPa m1/2, respectively, whereas higher values of electrical conductivity (0.81×106 Ω−1 m−1, thermal conductivity (21.20 W m−1 K−1 and Young's modulus (365 GPa were obtained along the a- or b-axis direction.

  14. Lateral boron distribution in polycrystalline SiC source materials

    DEFF Research Database (Denmark)

    Linnarsson, M. K.; Kaiser, M.; Liljedahl, R.

    2013-01-01

    Polycrystalline SiC containing boron and nitrogen are used in growth of fluorescent SiC for white LEDs. Two types of doped polycrystalline SiC have been studied in detail with secondary ion mass spectrometry: sintered SiC and poly-SiC prepared by sublimation in a physical vapor transport setup...

  15. Passivation of Al2O3 / TiO2 on monocrystalline Si with relatively low reflectance

    Science.gov (United States)

    Lu, Chun-Ti; Huang, Yu-Shiang; Liu, C. W.

    2016-06-01

    Al2O3/TiO2 stack layers deposited by the plasma-enhanced atomic layer deposition enhance photoluminescence intensity by reducing effective surface recombination velocities on both n-type and p-type monocrystalline Si. The field effect of negative oxide charges in the dielectrics is responsible for the low effective surface recombination velocity. The dependence of the effective surface recombination velocity on the photoluminescence intensity is investigated by the 2D numerical simulation. The bilayer stacks without texture also reduce the AM1.5-weighted front side reflectance to 11.8%. The field-effect passivation of Al2O3/TiO2 films is further improved by a forming gas annealing due to the additional increase of the negative oxide charge density.

  16. Nearly zero reflectance of nano-pyramids and dual-antireflection coating structure for monocrystalline silicon solar cells.

    Science.gov (United States)

    Chang, Hyo Sik; Jung, Hyun-Chul

    2011-04-01

    The effect of two-step surface treatment on monocrystalline silicon solar cells was investigated. We changed the nanostructure on pyramidal surfaces by wet nano-texturing so that less light is reflected. The two-step nano-texturing process reduces the average reflectance to about 4% in the 300-1100 nm wavelength region. The use of an antireflection coating resulted in an effective reflectance of 1%. We found that the reflectance obtained by wet nano-texturing was lower than that obtained by conventional alkaline texturing. Thus, we can expect a further increase in the efficiency of silicon solar cells with two-step nano-texturing by a wet chemical process.

  17. Atomistic simulations of the effect of embedded hydrogen and helium on the tensile properties of monocrystalline and nanocrystalline tungsten

    Science.gov (United States)

    Chen, Zhe; Kecskes, Laszlo J.; Zhu, Kaigui; Wei, Qiuming

    2016-12-01

    Uniaxial tensile properties of monocrystalline tungsten (MC-W) and nanocrystalline tungsten (NC-W) with embedded hydrogen and helium atoms have been investigated using molecular dynamics (MD) simulations in the context of radiation damage evolution. Different strain rates have been imposed to investigate the strain rate sensitivity (SRS) of the samples. Results show that the plastic deformation processes of MC-W and NC-W are dominated by different mechanisms, namely dislocation-based for MC-W and grain boundary-based activities for NC-W, respectively. For MC-W, the SRS increases and a transition appears in the deformation mechanism with increasing embedded atom concentration. However, no obvious embedded atom concentration dependence of the SRS has been observed for NC-W. Instead, in the latter case, the embedded atoms facilitate GB sliding and intergranular fracture. Additionally, a strong strain enhanced He cluster growth has been observed. The corresponding underlying mechanisms are discussed.

  18. Multiscale modeling of thermal conductivity of polycrystalline graphene sheets.

    Science.gov (United States)

    Mortazavi, Bohayra; Pötschke, Markus; Cuniberti, Gianaurelio

    2014-03-21

    We developed a multiscale approach to explore the effective thermal conductivity of polycrystalline graphene sheets. By performing equilibrium molecular dynamics (EMD) simulations, the grain size effect on the thermal conductivity of ultra-fine grained polycrystalline graphene sheets is investigated. Our results reveal that the ultra-fine grained graphene structures have thermal conductivity one order of magnitude smaller than that of pristine graphene. Based on the information provided by the EMD simulations, we constructed finite element models of polycrystalline graphene sheets to probe the thermal conductivity of samples with larger grain sizes. Using the developed multiscale approach, we also investigated the effects of grain size distribution and thermal conductivity of grains on the effective thermal conductivity of polycrystalline graphene. The proposed multiscale approach on the basis of molecular dynamics and finite element methods could be used to evaluate the effective thermal conductivity of polycrystalline graphene and other 2D structures.

  19. Melt Cast High Explosives

    Directory of Open Access Journals (Sweden)

    Stanisław Cudziło

    2014-12-01

    Full Text Available [b]Abstract[/b]. This paper reviews the current state and future developments of melt-cast high explosives. First the compositions, properties and methods of preparation of trinitrotoluene based (TNT conventional mixtures with aluminum, hexogen (RDX or octogen (HMX are described. In the newer, less sensitive explosive formulations, TNT is replaced with dinitroanisole (DNANDNANDNAN and nitrotriazolone (NTONTONTO, nitroguanidine (NG or ammonium perchlorate (AP are the replacement for RDRDX and HMX. Plasticized wax or polymer-based binder systems for melt castable explosives are also included. Hydroxyl terminated polybutadiene (HPTB is the binder of choice, but polyethylene glycol, and polycaprolactone with energetic plasticizers are also used. The most advanced melt-cast explosives are compositions containing energetic thermoplastic elastomers and novel highly energetic compounds (including nitrogen rich molecules in whose particles are nanosized and practically defect-less.[b]Keywords[/b]: melt-cast explosives, detonation parameters

  20. Modeling of Irradiation Hardening of Polycrystalline Materials

    Energy Technology Data Exchange (ETDEWEB)

    Li, Dongsheng; Zbib, Hussein M.; Garmestani, Hamid; Sun, Xin; Khaleel, Mohammad A.

    2011-09-14

    High energy particle irradiation of structural polycrystalline materials usually produces irradiation hardening and embrittlement. The development of predict capability for the influence of irradiation on mechanical behavior is very important in materials design for next generation reactors. In this work a multiscale approach was implemented to predict irradiation hardening of body centered cubic (bcc) alpha-iron. The effect of defect density, texture and grain boundary was investigated. In the microscale, dislocation dynamics models were used to predict the critical resolved shear stress from the evolution of local dislocation and defects. In the macroscale, a viscoplastic self-consistent model was applied to predict the irradiation hardening in samples with changes in texture and grain boundary. This multiscale modeling can guide performance evaluation of structural materials used in next generation nuclear reactors.

  1. Polycrystalline silicon ion sensitive field effect transistors

    Science.gov (United States)

    Yan, F.; Estrela, P.; Mo, Y.; Migliorato, P.; Maeda, H.; Inoue, S.; Shimoda, T.

    2005-01-01

    We report the operation of polycrystalline silicon ion sensitive field effect transistors. These devices can be fabricated on inexpensive disposable substrates such as glass or plastics and are, therefore, promising candidates for low cost single-use intelligent multisensors. In this work we have developed an extended gate structure with a Si3N4 sensing layer. Nearly ideal pH sensitivity (54mV /pH) and stable operation have been achieved. Temperature effects have been characterized. A penicillin sensor has been fabricated by functionalizing the sensing area with penicillinase. The sensitivity to penicillin G is about 10mV/mM, in solutions with concentration lower than the saturation value, which is about 7 mM.

  2. Polycrystalline-thin-film thermophotovoltaic cells

    Science.gov (United States)

    Dhere, Neelkanth G.

    1996-02-01

    Thermophotovoltaic (TPV) cells convert thermal energy to electricity. Modularity, portability, silent operation, absence of moving parts, reduced air pollution, rapid start-up, high power densities, potentially high conversion efficiencies, choice of a wide range of heat sources employing fossil fuels, biomass, and even solar radiation are key advantages of TPV cells in comparison with fuel cells, thermionic and thermoelectric convertors, and heat engines. The potential applications of TPV systems include: remote electricity supplies, transportation, co-generation, electric-grid independent appliances, and space, aerospace, and military power applications. The range of bandgaps for achieving high conversion efficiencies using low temperature (1000-2000 K) black-body or selective radiators is in the 0.5-0.75 eV range. Present high efficiency convertors are based on single crystalline materials such as In1-xGaxAs, GaSb, and Ga1-xInxSb. Several polycrystalline thin films such as Hg1-xCdxTe, Sn1-xCd2xTe2, and Pb1-xCdxTe, etc., have great potential for economic large-scale applications. A small fraction of the high concentration of charge carriers generated at high fluences effectively saturates the large density of defects in polycrystalline thin films. Photovoltaic conversion efficiencies of polycrystalline thin films and PV solar cells are comparable to single crystalline Si solar cells, e.g., 17.1% for CuIn1-xGaxSe2 and 15.8% for CdTe. The best recombination-state density Nt is in the range of 10-15-10-16 cm-3 acceptable for TPV applications. Higher efficiencies may be achieved because of the higher fluences, possibility of bandgap tailoring, and use of selective emitters such as rare earth oxides (erbia, holmia, yttria) and rare earth-yttrium aluminium garnets. As compared to higher bandgap semiconductors such as CdTe, it is easier to dope the lower bandgap semiconductors. TPV cell development can benefit from the more mature PV solar cell and opto

  3. Multifunctional Polycrystalline Ferroelectric Materials Processing and Properties

    CERN Document Server

    Pardo, Lorena

    2011-01-01

    This book presents selected topics on processing and properties of ferroelectric materials that are currently the focus of attention in scientific and technical research. Ferro-piezoelectric ceramics are key materials in devices for many applications, such as automotive, healthcare and non-destructive testing. As they are polycrystalline, non-centrosymmetric materials, their piezoelectricity is induced by the so-called poling process. This is based on the principle of polarization reversal by the action of an electric field that characterizes the ferroelectric materials. This book was born with the aim of increasing the awareness of the multifunctionality of ferroelectric materials among different communities, such as researchers, electronic engineers, end-users and manufacturers, working on and with ferro-piezoelectric ceramic materials and devices which are based on them. The initiative to write this book comes from a well-established group of researchers at the Laboratories of Ferroelectric Materials, Mate...

  4. Novel mercuric iodide polycrystalline nuclear particle counters

    Energy Technology Data Exchange (ETDEWEB)

    Schieber, M. [Hebrew Univ. of Jerusalem (Israel)]|[Sandia National Labs., Livermore, CA (United States); Zuck, A.; Braiman, M.; Nissenbaum, J. [Hebrew Univ. of Jerusalem (Israel); Turchetta, R.; Dulinski, W.; Husson, D.; Riester, J.L. [LEPSI, Strasbourg (France)

    1997-12-01

    Polycrystalline mercuric iodide nuclear radiation detectors have been produced in a novel technology. Unlike the normal single-crystal technology, there is no intrinsic limit to the surface on which these detectors can be produced. Detectors with areas up to about 1.5 cm{sup 2}, thicknesses from 30 to 600 {micro}m, and with single electrodes as well as microstrip and pixel contacts have been fabricated and successfully tested with photons in the range of 40--660 keV, {beta} particle`s emitted from a Sr-Y source, and high energy (100 GeV) muons. Results on both charge collection and counting efficiency are reported as well as some very preliminary imaging results. The experimental results on charge collection have been compared with simulation, and a combined {mu}{tau} product 10{sup {minus}7} cm{sup 2}/V for electrons has been estimated.

  5. Casting Characteristics of Aluminum Die Casting Alloys

    Energy Technology Data Exchange (ETDEWEB)

    Makhlouf M. Makhlouf; Diran Apelian

    2002-02-05

    The research program investigates the casting characteristics of selected aluminum die casting alloys. Specifically, the alloys' tendencies towards die soldering and sludge formation, and the alloys' fluidity and machinability are evaluated. It was found that: When the Fe and Mn contents of the alloy are low; caution has to be taken against possible die soldering. When the alloy has a high sludge factor, particularly a high level of Fe, measures must be taken to prevent the formation of large hardspots. For this kind of alloy, the Fe content should be kept at its lowest allowable level and the Mn content should be at its highest possible level. If there are problems in die filling, measures other than changing the alloy chemistry need to be considered first. In terms of alloy chemistry, the elements that form high temperature compounds must be kept at their lowest allowable levels. The alloys should not have machining problems when appropriate machining techniques and machining parameters are used.

  6. IMPEDANCE SPECTROSCOPY OF POLYCRYSTALLINE TIN DIOXIDE FILMS

    Directory of Open Access Journals (Sweden)

    D. V. Adamchuck

    2016-01-01

    Full Text Available The aim of this work is the analysis of the influence of annealing in an inert atmosphere on the electrical properties and structure of non-stoichiometric tin dioxide films by means of impedance spectroscopy method. Non-stoichiometric tin dioxide films were fabricated by two-step oxidation of metallic tin deposited on the polycrystalline Al2O3 substrates by DC magnetron sputtering. In order to modify the structure and stoichiometric composition, the films were subjected to the high temperature annealing in argon atmosphere in temperature range 300–800 °С. AC-conductivity measurements of the films in the frequency range 20 Hz – 2 MHz were carried out. Variation in the frequency dependencies of the real and imaginary parts of the impedance of tin dioxide films was found to occur as a result of high-temperature annealing. Equivalent circuits for describing the properties of films with various structure and stoichiometric composition were proposed. Possibility of conductivity variation of the polycrystalline tin dioxide films as a result of аnnealing in an inert atmosphere was demonstrated by utilizing impedance spectroscopy. Annealing induces the recrystallization of the films, changing in their stoichiometry as well as increase of the sizes of SnO2 crystallites. Variation of electrical conductivity and structure of tin dioxide films as a result of annealing in inert atmosphere was confirmed by X-ray diffraction analysis. Analysis of the impedance diagrams of tin dioxide films was found to be a powerful tool to study their electrical properties. 

  7. Colour Metallography of Cast Iron

    Institute of Scientific and Technical Information of China (English)

    Zhou Jiyang; Ph.D Liu Jincheng

    2010-01-01

    @@ Note: This book consists of five sections: Chapter 1 Introduction, Chapter 2 Grey Iron, Chapter 3 Spheroidal Graphite Cast Iron, Chapter 4 Vermicular Cast Iron, and Chapter 5 White Cast Iron. CHINA FOUNDRY publishes this book in several parts serially, starting from the first issue of 2009.

  8. Evaluation of an improved centrifugal casting machine.

    Science.gov (United States)

    Donovan, T E; White, L E

    1985-05-01

    A Type III gold alloy, a silver-palladium alloy, and a base metal alloy were cast in two different centrifugal casting machines. With the number of complete cast mesh squares as an indicator of castability, the Airspin casting machine produced superior castings with all three alloys. The base metal alloy produced the greatest number of complete squares with both casting machines.

  9. ToxCast Dashboard

    Science.gov (United States)

    The ToxCast Dashboard helps users examine high-throughput assay data to inform chemical safety decisions. To date, it has data on over 9,000 chemicals and information from more than 1,000 high-throughput assay endpoint components.

  10. Control of cast iron and casts manufacturing by Inmold method

    Directory of Open Access Journals (Sweden)

    S. Pietrowski

    2009-07-01

    Full Text Available In this paper the usability of cast iron spheroidizing process in mould control by ATD method as well as by ultrasonic method were presented. Structure of instrumentation needed for control form performance of cast iron spheroidizing by Inmold method was illustrated. Author, pointed out that amount of magnesium master alloy should obtain 0,8 ÷ 1,0% of mass in form at all. Such quantity of preliminary alloy assure of obtain of nodular graphite in cast iron. In consequence of this, is reduce the cast iron liquidus temperature and decrease of recalescence temperature of graphite-eutectic crystallization in compare with initial cast iron. Control of casts can be carried out by ultrasonic method. In plain cast iron, ferritic-pearlitic microstructure is obtaining. Additives of 1,5% Cu ensure pearlitic structure.

  11. The casting of western sculpture during the XIXth century: sand casting versus lost wax casting

    NARCIS (Netherlands)

    Beentjes, T.P.C.

    2014-01-01

    This paper will discuss research into bronze casting techniques as practiced during the XIXth and early XXth century. Both natural sand casting (fonte au sable naturel) and lost wax casting (fonte à la cire perdue) were employed during this period and sometimes rivalled for commissions. Before the X

  12. Colour Metallography of Cast Iron

    Institute of Scientific and Technical Information of China (English)

    Zhou Jiyang; Liu Jincheng

    2010-01-01

    @@ Chapter 3 Spheroidal Graphite Cast Iron(I) Spheroidal Graphite Cast Iron, SG iron in short, refers to the cast iron in which graphite precipitates as spheroidal shape during solidification of liquid iron. The graphite in common commercial cast iron can only be changed from flake to spheroidal shape by spheroidising treatment. Since spheroidal graphite reduces the cutting effect of stress concentration, the metal matrix strength of SG iron can be applied around 70%-90%, thus the mechanical property of SG iron is significantly superior to other cast irons;even the tensile strength of SG iron is higher than that carbon steel.

  13. Highly c-axis-oriented monocrystalline Pb(Zr, Ti)O₃ thin films on si wafer prepared by fast cooling immediately after sputter deposition.

    Science.gov (United States)

    Yoshida, Shinya; Hanzawa, Hiroaki; Wasa, Kiyotaka; Esashi, Masayoshi; Tanaka, Shuji

    2014-09-01

    We successfully developed sputter deposition technology to obtain a highly c-axis-oriented monocrystalline Pb(Zr, Ti)O3 (PZT) thin film on a Si wafer by fast cooling (~-180°C/min) of the substrate after deposition. The c-axis orientation ratio of a fast-cooled film was about 90%, whereas that of a slow-cooled (~-40°C/min) film was only 10%. The c-axis-oriented monocrystalline Pb(Zr0.5, Ti0.5)O3 films showed reasonably large piezoelectric coefficients, e(31,f) = ~-11 C/m(2), with remarkably small dielectric constants, ϵ(r) = ~220. As a result, an excellent figure of merit (FOM) was obtained for piezoelectric microelectromechanical systems (MEMS) such as a piezoelectric gyroscope. This c-axis orientation technology on Si will extend industrial applications of PZT-based thin films and contribute further to the development of piezoelectric MEMS.

  14. Influence of different etchants on the representation of microstructures in nickel alloys; Einfluss verschiedener Aetzmittel auf die Gefuegedarstellung in Nickellegierungen

    Energy Technology Data Exchange (ETDEWEB)

    Speicher, Magdalena; Scheck, Rudi; Maile, Karl [Stuttgart Univ. (Germany). Materialpruefungsanstalt

    2016-04-15

    This work presents a comparison of selected nickel alloys of the same condition which were treated by means of specifically chosen etching techniques. Microstructures on microscope images of wrought Alloy 617, a casting variant of Alloy 625, a polycrystalline casting alloy IN-738 LC, as well as of a monocrystalline superalloy CM 247 LC SX, respectively, are juxtaposed and evaluated. This approach allows for a comprehensive optical microscopy characterization of the characteristic microstructural features.

  15. Cast iron - a predictable material

    Directory of Open Access Journals (Sweden)

    Jorg C. Sturm

    2011-02-01

    Full Text Available High strength compacted graphite iron (CGI or alloyed cast iron components are substituting previously used non-ferrous castings in automotive power train applications. The mechanical engineering industry has recognized the value in substituting forged or welded structures with stiff and light-weight cast iron castings. New products such as wind turbines have opened new markets for an entire suite of highly reliable ductile iron cast components. During the last 20 years, casting process simulation has developed from predicting hot spots and solidification to an integral assessment tool for foundries for the entire manufacturing route of castings. The support of the feeding related layout of the casting is still one of the most important duties for casting process simulation. Depending on the alloy poured, different feeding behaviors and self-feeding capabilities need to be considered to provide a defect free casting. Therefore, it is not enough to base the prediction of shrinkage defects solely on hot spots derived from temperature fields. To be able to quantitatively predict these defects, solidification simulation had to be combined with density and mass transport calculations, in order to evaluate the impact of the solidification morphology on the feeding behavior as well as to consider alloy dependent feeding ranges. For cast iron foundries, the use of casting process simulation has become an important instrument to predict the robustness and reliability of their processes, especially since the influence of alloying elements, melting practice and metallurgy need to be considered to quantify the special shrinkage and solidification behavior of cast iron. This allows the prediction of local structures, phases and ultimately the local mechanical properties of cast irons, to asses casting quality in the foundry but also to make use of this quantitative information during design of the casting. Casting quality issues related to thermally driven

  16. Melting and casting of FeAl-based cast alloy

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K. [Oak Ridge National Lab., TN (United States); Wilkening, D. [Columbia Falls Aluminum Co., Columbia Falls, MT (United States); Liebetrau, J.; Mackey, B. [AFFCO, L.L.C., Anaconda, MT (United States)

    1998-11-01

    The FeAl-based intermetallic alloys are of great interest because of their low density, low raw material cost, and excellent resistance to high-temperature oxidation, sulfidation, carburization, and molten salts. The applications based on these unique properties of FeAl require methods to melt and cast these alloys into complex-shaped castings and centrifugal cast tubes. This paper addresses the melting-related issues and the effect of chemistry on the microstructure and hardness of castings. It is concluded that the use of the Exo-Melt{trademark} process for melting and the proper selection of the aluminum melt stock can result in porosity-free castings. The FeAl alloys can be melted and cast from the virgin and revert stock. A large variation in carbon content of the alloys is possible before the precipitation of graphite flakes occurs. Titanium is a very potent addition to refine the grain size of castings. A range of complex sand castings and two different sizes of centrifugal cast tubes of the alloy have already been cast.

  17. Melting and casting of FeAl-based cast alloy

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.; Wilkening, D. [Columbia Falls Aluminum Co., 2000 Aluminum Dr., Columbia Falls, MT 59912 (United States); Liebetrau, J.; Mackey, B. [AFFCO, L.L.C., P.O. Box 1071, Anaconda, MT 59711 (United States)

    1998-12-31

    The FeAl-based intermetallic alloys are of great interest because of their low density, low raw material cost, and excellent resistance to high-temperature oxidation, sulfidation, carburization, and molten salts. The applications based on these unique properties of FeAl require methods to melt and cast these alloys into complex-shaped castings and centrifugal cast tubes. This paper addresses the melting-related issues and the effect of chemistry on the microstructure and hardness of castings. It is concluded that the use of the Exo-Melt{sup TM} process for melting and the proper selection of the aluminum melt stock can result in porosity-free castings. The FeAl alloys can be melted and cast from the virgin and revert stock. A large variation in carbon content of the alloys is possible before the precipitation of graphite flakes occurs. Titanium is a very potent addition to refine the grain size of castings. A range of complex sand castings and two different sizes of centrifugal cast tubes of the alloy have already been cast. (orig.) 18 refs.

  18. Polycrystalline Thin-Film Research: Cadmium Telluride (Fact Sheet)

    Energy Technology Data Exchange (ETDEWEB)

    2013-06-01

    This National Center for Photovoltaics sheet describes the capabilities of its polycrystalline thin-film research in the area of cadmium telluride. The scope and core competencies and capabilities are discussed.

  19. Polycrystalline Thin-Film Research: Cadmium Telluride (Fact Sheet)

    Energy Technology Data Exchange (ETDEWEB)

    2011-06-01

    Capabilities fact sheet that includes scope, core competencies and capabilities, and contact/web information for Polycrystalline Thin-Film Research: Cadmium Telluride at the National Center for Photovoltaics.

  20. Polycrystalline silicon semiconducting material by nuclear transmutation doping

    Science.gov (United States)

    Cleland, John W.; Westbrook, Russell D.; Wood, Richard F.; Young, Rosa T.

    1978-01-01

    A NTD semiconductor material comprising polycrystalline silicon having a mean grain size less than 1000 microns and containing phosphorus dispersed uniformly throughout the silicon rather than at the grain boundaries.

  1. Features of the Real Structure of Lanthanum Hexaboride Polycrystalline

    Institute of Scientific and Technical Information of China (English)

    郑树起; 闵光辉; 邹增大; 于普涟; 韩建德; Y. B. Paderno

    2001-01-01

    The microstructure of lanthanum hexaboride (LaB6) polycrystalline has been studied by using transmission electron microscopy. This shows that the ideal LaB6 polycrystalline can be obtained by sintering ingots at the temperature of 2273 K for a holding time of 120min in Ar pressure of 800Torr, where the ingots are formed by pressing LaB6 powder at room temperature at a pressure of 0.4-0.5 GPa. The particles in LaB6 polycrystalline hardly bind; there are only a few pores at the joint parts of three particles and a few impurities exist in some pores. The sintering process for fabricating LaB6 polycrystalline is analysed and the formation of the pore and the impurities are studied from the point of surface tension.

  2. Abnormal hopping conduction in semiconducting polycrystalline graphene

    Science.gov (United States)

    Park, Jeongho; Mitchel, William C.; Elhamri, Said; Grazulis, Larry; Altfeder, Igor

    2013-07-01

    We report the observation of an abnormal carrier transport phenomenon in polycrystalline semiconducting graphene grown by solid carbon source molecular beam epitaxy. At the lowest temperatures in samples with small grain size, the conduction does not obey the two-dimensional Mott-type variable-range hopping (VRH) conduction often reported in semiconducting graphene. The hopping exponent p is found to deviate from the 1/3 value expected for Mott VRH with several samples exhibiting a p=2/5 dependence. We also show that the maximum energy difference between hopping sites is larger than the activation energy for nearest-neighbor hopping, violating the assumptions of the Mott model. The 2/5 dependence more closely agrees with the quasi-one-dimensional VRH model proposed by Fogler, Teber, and Shklovskii (FTS). In the FTS model, conduction occurs by tunneling between neighboring metallic wires. We suggest that metallic edge states and conductive grain boundaries play the role of the metallic wires in the FTS model.

  3. Junction like behavior in polycrystalline diamond films

    Energy Technology Data Exchange (ETDEWEB)

    Bhaskaran, Shivakumar, E-mail: sbhaskar@mail.uh.edu [Department of Electrical and Computer Engineering, Cullen College of Engineering, University of Houston, TX 77004 (United States); Charlson, Earl Joe; Litvinov, Dmitri [Department of Electrical and Computer Engineering, Cullen College of Engineering, University of Houston, TX 77004 (United States); Makarenko, Boris [Department of Chemistry, University of Houston, TX 77004 (United States)

    2012-01-25

    Highlights: Black-Right-Pointing-Pointer The result that we obtained are compared with single crystalline diamond devices. Black-Right-Pointing-Pointer The barrier height of 4.4 eV matches the ideal pn-junction barrier height of diamond thin film. - Abstract: We have successfully fabricated polycrystalline diamond rectifying junction devices on n-type (1 0 0) silicon substrates by Hot Filament Chemical Vapor Deposition (HFCVD) using methane/hydrogen process gas and trimethyl borate and trimethyl phosphite dissolved in acetone as p- and n-type dopants, respectively. Impedance spectroscopy and current-voltage analysis indicates that the conduction is vertical down the grains and facets and not due to surface effects. Electrical characteristics were analyzed with In and Ti/Au top metal contacts with Al as the substrate contact. Current-voltage characteristics as a function of temperature showed barrier potentials of 1.1 eV and 0.77 eV for the In and Ti/Au contacts, respectively. Barrier heights of 4.8 eV (In) and 4.4 eV (Ti/Au) were obtained from capacitance-voltage measurements.

  4. Water vapor interactions with polycrystalline titanium surfaces

    Science.gov (United States)

    Azoulay, A.; Shamir, N.; Volterra, V.; Mintz, M. H.

    1999-02-01

    The initial interactions of water vapor with polycrystalline titanium surfaces were studied at room temperature. Measurements of water vapor surface accumulation were performed in a combined surface analysis system incorporating direct recoils spectrometry (DRS), Auger electron spectroscopy and X-ray photoelectron spectroscopy. The kinetics of accommodation of the water dissociation fragments (H, O and OH) displayed a complex behavior depending not only on the exposure dose but also on the exposure pressure. For a given exposure dose the efficiency of chemisorption increased with increasing exposure pressure. DRS measurements indicated the occurrence of clustered hydroxyl moieties with tilted O-H bonds formed even at very low surface coverage. A model which assumes two parallel routes of chemisorption, by direct collisions (Langmuir type) and by a precursor state is proposed to account for the observed behavior. The oxidation efficiency of water seemed to be much lower than that of oxygen. No Ti 4+ states were detected even at high water exposure values. It is likely that hydroxyl species play an important role in the reduced oxidation efficiency of water.

  5. Deformation localization and cyclic strength in polycrystalline molybdenum

    Energy Technology Data Exchange (ETDEWEB)

    Sidorov, O.T.; Rakshin, A.F.; Fenyuk, M.I.

    1983-06-01

    Conditions of deformation localization and its interrelation with cyclic strength in polycrystalline molybdenum were investigated. A fatigue failure of polycrystalline molybdenum after rolling and in an embrittled state reached by recrystallization annealing under cyclic bending at room temperature takes place under nonuniform distribution of microplastic strain resulting in a temperature rise in separate sections of more than 314 K. More intensive structural changes take place in molybdenum after rolling than in recrystallized state.

  6. [Casting faults and structural studies on bonded alloys comparing centrifugal castings and vacuum pressure castings].

    Science.gov (United States)

    Fuchs, P; Küfmann, W

    1978-07-01

    The casting processes in use today such as centrifugal casting and vacuum pressure casting were compared with one another. An effort was made to answer the question whether the occurrence of shrink cavities and the mean diameter of the grain of the alloy is dependent on the method of casting. 80 crowns were made by both processes from the baked alloys Degudent Universal, Degudent N and the trial alloy 4437 of the firm Degusa. Slice sections were examined for macro and micro-porosity and the structural appearance was evaluated by linear analysis. Statistical analysis showed that casting faults and casting structure is independent of the method used and their causes must be found in the conditions of casting and the composition of the alloy.

  7. Light metal compound casting

    Institute of Scientific and Technical Information of China (English)

    Konrad J.M.PAPIS; Joerg F.LOEFFLER; Peter J.UGGOWITZER

    2009-01-01

    'Compound casting'simplifies joining processes by directly casting a metallic melt onto a solid metal substrate. A continuously metallurgic transition is very important for industrial applications, such as joint structures of spaceframe constructions in transport industry. In this project, 'compound casting' of light metals is investigated, aiming at weight-saving. The substrate used is a wrought aluminium alloy of type AA5xxx, containing magnesium as main alloying element. The melts are aluminium alloys, containing various alloying elements (Cu, Si, Zn), and magnesium. By replacing the natural oxygen layer with a zinc layer, the inherent wetting difficulties were avoided, and compounds with flawless interfaces were successfully produced (no contraction defects, cracks or oxides). Electron microscopy and EDX investigations as well as optical micrographs of the interfacial areas revealed their continu-ously metallic constitution. Diffusion of alloying elements leads to heat-treatable microstructures in the vicinity of the joining interfaces in Al-Al couples. This permits significant variability of mechanical properties. Without significantly cutting down on wettability, the formation of low-melting intermetallic phases (Al3Mg2 and AI12Mg17 IMPs) at the interface of Al-Mg couples was avoided by applying a protec-tive coating to the substrate.

  8. Bimetallic layered castings alloy steel – carbon cast steel

    Directory of Open Access Journals (Sweden)

    T. Wróbel

    2011-01-01

    Full Text Available In paper is presented technology of bimetallic layered castings based on founding method of layer coating directly in cast processso-called method of mould cavity preparation. Prepared castings consist two fundamental parts i.e. bearing part and working part (layer. The bearing part of bimetallic layered casting is typical foundry material i.e. ferritic-pearlitic carbon cast steel, whereas working part (layer is plate of austenitic alloy steel sort X10CrNi 18-8. The ratio of thickness between bearing and working part is 8:1. The quality of the bimetallic layered castings was evaluated on the basis of ultrasonic NDT (non-destructive testing, structure and macro- and microhardness researches.

  9. Halide perovskite solar cells using monocrystalline TiO2 nanorod arrays as electron transport layers: impact of nanorod morphology

    Science.gov (United States)

    Thakur, Ujwal Kumar; Askar, Abdelrahman M.; Kisslinger, Ryan; Wiltshire, Benjamin D.; Kar, Piyush; Shankar, Karthik

    2017-07-01

    This is the first report of a 17.6% champion efficiency solar cell architecture comprising monocrystalline TiO2 nanorods (TNRs) coupled with perovskite, and formed using facile solution processing without non-routine surface conditioning. Vertically oriented TNR ensembles are desirable as electron transporting layers (ETLs) in halide perovskite solar cells (HPSCs) because of potential advantages such as vectorial electron percolation pathways to balance the longer hole diffusion lengths in certain halide perovskite semiconductors, ease of incorporating nanophotonic enhancements, and optimization between a high contact surface area for charge transfer (good) versus high interfacial recombination (bad). These advantages arise from the tunable morphology of hydrothermally grown rutile TNRs, which is a strong function of the growth conditions. Fluorescence lifetime imaging microscopy of the HPSCs demonstrated a stronger quenching of the perovskite PL when using TNRs as compared to mesoporous/compact TiO2 thin films. Due to increased interfacial contact area between the ETL and perovskite with easier pore filling, charge separation efficiency is dramatically enhanced. Additionally, solid-state impedance spectroscopy results strongly suggested the suppression of interfacial charge recombination between TNRs and perovskite layer, compared to other ETLs. The optimal ETL morphology in this study was found to consist of an array of TNRs ∼300 nm in length and ∼40 nm in width. This work highlights the potential of TNR ETLs to achieve high performance solution-processed HPSCs.

  10. Self-assembly of microscopic chiplets at a liquid-liquid-solid interface forming a flexible segmented monocrystalline solar cell.

    Science.gov (United States)

    Knuesel, Robert J; Jacobs, Heiko O

    2010-01-19

    This paper introduces a method for self-assembling and electrically connecting small (20-60 micrometer) semiconductor chiplets at predetermined locations on flexible substrates with high speed (62500 chips/45 s), accuracy (0.9 micrometer, 0.14 degrees), and yield (> 98%). The process takes place at the triple interface between silicone oil, water, and a penetrating solder-patterned substrate. The assembly is driven by a stepwise reduction of interfacial free energy where chips are first collected and preoriented at an oil-water interface before they assemble on a solder-patterned substrate that is pulled through the interface. Patterned transfer occurs in a progressing linear front as the liquid layers recede. The process eliminates the dependency on gravity and sedimentation of prior methods, thereby extending the minimal chip size to the sub-100 micrometer scale. It provides a new route for the field of printable electronics to enable the integration of microscopic high performance inorganic semiconductors on foreign substrates with the freedom to choose target location, pitch, and integration density. As an example we demonstrate a fault-tolerant segmented flexible monocrystalline silicon solar cell, reducing the amount of Si that is used when compared to conventional rigid cells.

  11. Large-area monocrystalline silicon thin films by annealing of macroporous arrays: Understanding and tackling defects in the material

    Science.gov (United States)

    Depauw, Valérie; Gordon, Ivan; Beaucarne, Guy; Poortmans, Jef; Mertens, Robert; Celis, Jean-Pierre

    2009-08-01

    A concept that could provide a thin monocrystalline-silicon absorber layer without resorting to the expensive step of epitaxy would be very appealing for reducing the cost of solar cells. The empty-space-in-silicon technique by which thin films of silicon can be formed by reorganization of regular arrays of cylindrical voids at high temperature may be such a concept if the high quality of the thin film could be ensured on centimeter-large areas. While previous works mainly investigated the influence of the porous array on the final structure, this work focuses on the practical aspects of the high-temperature step and its application to large areas. An insight into the defects that may form is given and the origin of these defects is discussed, providing recommendations on how to avoid them. Surface roughening, pitting, formation of holes, and silicon pillars could be attributed to the nonuniform reactions between Si, SiO2, and SiO. Hydrogen atmospheres are therefore preferred for reorganization of macroporous arrays. Argon atmospheres, however, may provide high-quality silicon thin films as well, possibly even more easily transferable, as long as annealing is performed in controlled, clean, and oxygen-free conditions. Our experiments on large areas also highlight the importance of kinetics, which had not been considered up to now and which will require further understanding to ensure a complete reorganization over any wafer area.

  12. Fracture Mechanisms in Steel Castings

    Directory of Open Access Journals (Sweden)

    Z. Stradomski

    2013-07-01

    Full Text Available The investigations were inspired with the problem of cracking of steel castings during the production process. A single mechanism of decohesion - the intergranular one - occurs in the case of hot cracking, while a variety of structural factors is decisive for hot cracking initiation, depending on chemical composition of the cast steel. The low-carbon and low-alloyed steel castings crack due to the presence of the type II sulphides, the cause of cracking of the high-carbon tool cast steels is the net of secondary cementite and/or ledeburite precipitated along the boundaries of solidified grains. Also the brittle phosphor and carbide eutectics precipitated in the final stage solidification are responsible for cracking of castings made of Hadfield steel. The examination of mechanical properties at 1050°C revealed low or very low strength of high-carbon cast steels.

  13. Vacuum arc on the polycrystalline silica cathode

    Directory of Open Access Journals (Sweden)

    D. V. Duhopel'nikov

    2014-01-01

    Full Text Available Thin films of silica and its compounds are used in modern technology to produce Li-ion batteries, wear-resistant and protective coatings, thin-films insulators, etc. This coating is produced with CVD methods, with magnetron sputtering systems or with electron-beam evaporation. The vacuum arc evaporation method, presently, is not used.The paper demonstrates a possibility for a long-term operation of vacuum arc evaporator with polycrystalline silica-aluminum alloy (90% of silica cathode and with magnetic system to create a variable form of arch-like magnetic field on the cathode surface. It was shown that archlike configuration of magnetic field provides a stable discharge and uniform cathode spots moving with the velocities up to 5 m/s with magnetic fields induction about 10 mT. Thus, there is no local melting of the cathode, and this provides its long-term work without chips, cracks and destruction. Cathodes spots move over the cathode surface leaving t big craters with melted edges on its surface. The craters size was 150-450μm. The cathode spot movement character and the craters on the cathode surface were like the spots movement, when working on the copper or aluminum cathodes. With the magnetic field induction less than 1 mT, the cathode spots movement was the same as that of on the silica mono-crystal without magnetic field. Thus, the discharge volt-ampere characteristics for different values of magnetic fields were obtained. Voltampere characteristics were increasing and were shifted to the higher voltage with increasing magnetic field. The voltage was 18.7-26.5 V for the arc current 30-140 A.So, it was confirmed that vacuum arc evaporation method could be used for effective evaporation of silica and silica-based alloys and for thin films deposition of this materials.

  14. A New Polycrystalline Co-Ni Superalloy

    Science.gov (United States)

    Knop, M.; Mulvey, P.; Ismail, F.; Radecka, A.; Rahman, K. M.; Lindley, T. C.; Shollock, B. A.; Hardy, M. C.; Moody, M. P.; Martin, T. L.; Bagot, P. A. J.; Dye, D.

    2014-12-01

    In 2006, a new-ordered L12 phase, Co3(Al,W), was discovered that can form coherently in a face-centered cubic (fcc) A1 Co matrix. Since then, a community has developed that is attempting to take these alloys forward into practical applications in gas turbines. A new candidate polycrystalline Co-Ni γ/ γ' superalloy, V208C, is presented that has the nominal composition 36Co-35Ni-15Cr-10Al-3W-1Ta (at.%). The alloy was produced by conventional powder metallurgy superalloy methods. After forging, a γ' fraction of ~56% and a secondary γ' size of 88 nm were obtained, with a grain size of 2.5 μm. The solvus temperature was 1000°C. The density was found to be 8.52 g cm-3, which is similar to existing Ni alloys with this level of γ'. The alloy showed the flow stress anomaly and a yield strength of 920 MPa at room temperature and 820 MPa at 800°C, similar to that of Mar-M247. These values are significantly higher than those found for either conventional solution and carbide-strengthened Co alloys or the γ/ γ' Co superalloys presented in the literature thus far. The oxidation resistance, with a mass gain of 0.08 mg cm-2 in 100 h at 800°C, is also comparable with that of existing high-temperature Ni superalloys. These results suggest that Co-based and Co-Ni superalloys may hold some promise for the future in gas turbine applications.

  15. Improved Casting Furnace Conceptual Design

    Energy Technology Data Exchange (ETDEWEB)

    Fielding, Randall Sidney [Idaho National Lab. (INL), Idaho Falls, ID (United States); Tolman, David Donald [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2017-02-01

    In an attempt to ensure more consistent casting results and remove some schedule variance associated with casting, an improved casting furnace concept has been developed. The improved furnace uses the existing arc melter hardware and glovebox utilities. The furnace concept was designed around physical and operational requirements such as; a charge sized of less than 30 grams, high heating rates and minimal additional footprint. The conceptual model is shown in the report as well as a summary of how the requirements were met.

  16. The electrical conductivity of polycrystalline metallic films

    Science.gov (United States)

    Moraga, Luis; Arenas, Claudio; Henriquez, Ricardo; Bravo, Sergio; Solis, Basilio

    2016-10-01

    We calculate the electrical conductivity of polycrystalline metallic films by means of a semi-numerical procedure that provides solutions of the Boltzmann transport equation, that are essentially exact, by summing over classical trajectories according to Chambers' method. Following Mayadas and Shatzkes (MS), grain boundaries are modeled as an array of parallel plane barriers situated perpendicularly to the direction of the current. Alternatively, according to Szczyrbowski and Schmalzbauer (SS), the model consists in a triple array of these barriers in mutual perpendicular directions. The effects of surface roughness are described by means of Fuchs' specularity parameters. Following SS, the scattering properties of grain boundaries are taken into account by means of another specularity parameter and a probability of coherent passage. The difference between the sum of these and one is the probability of diffuse scattering. When this formalism is compared with the approximate formula of Mayadas and Shatzkes (Phys. Rev. B 1, 103 (1986)) it is shown that the latter greatly overestimates the film resistivity over most values of the reflectivity of the grain boundaries. The dependence of the conductivity of thin films on the probability of coherent passage and grain diameters is examined. In accordance with MS we find that the effects of disorder in the distribution of grain diameters is quite small. Moreover, we find that it is not safe to neglect the effects of the scattering by the additional interfaces created by stacked grains. However, when compared with recent resitivity-thickness data, it is shown that all three formalisms can provide accurate fits to experiment. In addition, it is shown that, depending on the respective reflectivities and distance from a surface, some of these interfaces may increase or diminish considerably the conductivity of the sample. As an illustration of this effect, we show a tentative fit of resistivity data of gold films measured by

  17. Development of Refractories for Continuous Casting

    Institute of Scientific and Technical Information of China (English)

    TIAN Shouxin; JIN Congjin; YAO Jinfu; LI Zeya

    2004-01-01

    The paper introduces refractories for continuous casting, especially, refractories for continuous casting for clean steel in baosteel. Developing direction of refractories for continuous casting has been pointed out to satisfy the new metallurgical operating practice.

  18. Segregation in cast products

    Indian Academy of Sciences (India)

    A Ghosh

    2001-02-01

    Microsegregation gets eliminated significantly if subsequent hot working and/or annealing are done on cast products. Macrosegregation however persists, causing problems in quality, and hence, has to be attended to. Microsegregation is a consequence of rejection of solutes by the solid into the interdendritic liquid. Scheil’s equation is mostly employed. However, other equations have been proposed, which take into account diffusion in solid phase and/or incomplete mixing in liquid. Macrosegregation results from movements of microsegregated regions over macroscopic distances due to motion of liquid and free crystals. Motion of impure interdendritic liquid causes regions of positive macrosegregation, whereas purer solid crystals yield negative macrosegregation. Flow of interdendritic liquid is primarily natural convection due to thermal and solutal buoyancy, and partly forced convection due to suction by shrinkage cavity formation etc. The present paper briefly deals with fundamentals of the above and contains some recent studies as well. Experimental investigations in molten alloys do not allow visualization of the complex flow pattern as well as other phenomena, such as dendrite-tip detachment. Experiments with room temperature analogues, and mathematical modelling have supplemented these efforts. However, the complexity of the phenomena demands simplifying assumptions. The agreement with experimental data is mostly qualitative. The paper also briefly discusses centreline macrosegregation during continuous casting of steel, methods to avoid it, and the, importance of early columnar-to-equiaxed transition (CET) as well as the fundamentals of CET.

  19. Biomaterials by freeze casting.

    Science.gov (United States)

    Wegst, Ulrike G K; Schecter, Matthew; Donius, Amalie E; Hunger, Philipp M

    2010-04-28

    The functional requirements for synthetic tissue substitutes appear deceptively simple: they should provide a porous matrix with interconnecting porosity and surface properties that promote rapid tissue ingrowth; at the same time, they should possess sufficient stiffness, strength and toughness to prevent crushing under physiological loads until full integration and healing are reached. Despite extensive efforts and first encouraging results, current biomaterials for tissue regeneration tend to suffer common limitations: insufficient tissue-material interaction and an inherent lack of strength and toughness associated with porosity. The challenge persists to synthesize materials that mimic both structure and mechanical performance of the natural tissue and permit strong tissue-implant interfaces to be formed. In the case of bone substitute materials, for example, the goal is to engineer high-performance composites with effective properties that, similar to natural mineralized tissue, exceed by orders of magnitude the properties of its constituents. It is still difficult with current technology to emulate in synthetic biomaterials multi-level hierarchical composite structures that are thought to be the origin of the observed mechanical property amplification in biological materials. Freeze casting permits to manufacture such complex, hybrid materials through excellent control of structural and mechanical properties. As a processing technique for the manufacture of biomaterials, freeze casting therefore has great promise.

  20. Colour Metallography of Cast Iron

    Institute of Scientific and Technical Information of China (English)

    Zhou Jiyang; Liu Jincheng

    2009-01-01

    @@ This book consists of five sections:Chapter 1 Introduction,Chapter 2 Grey Iron,Chapter 3 Ductile Iron,Chapter 4Vermicular Cast Iron,and Chapter 5 White Cast Iron. CHINA FOUNDRY publishs this book in several parts serially,starting from the first issue of 2009.

  1. Theory of batchwise centrifugal casting

    NARCIS (Netherlands)

    Biesheuvel, P. Maarten; Nijmeijer, Arian; Verweij, Henk

    1998-01-01

    In batchwise centrifugal casting a cylindrical mold is filled with suspension and rotated rapidly around its axis. This results in the movement of the particulate phase toward the cylinder wall and the formation of a tubular cast. Theory is presented for particle transport in the suspension phase an

  2. Lost Foam Casting in China

    Institute of Scientific and Technical Information of China (English)

    YE Sheng-ping; WU Zhi-chao

    2006-01-01

    @@ 1. Lost Foam Casting Committee of Foundry Institution of Chinese Mechanical Engineering Society (FICMES) From the beginning of the 1990s, China entered a research and expansion climax in lost foam casting technology realm after the United States, Germany, and Japan etc.

  3. Education and Caste in India

    Science.gov (United States)

    Chauhan, Chandra Pal Singh

    2008-01-01

    This paper analyses the policy of reservation for lower castes in India. This policy is similar to that of affirmative action in the United States. The paper provides a brief overview of the caste system and discusses the types of groups that are eligible for reservation, based on data from government reports. The stance of this paper is that…

  4. Thin-film monocrystalline-silicon solar cells based on a seed layer approach with 11% efficiency

    Science.gov (United States)

    Gordon, I.; Qiu, Y.; Van Gestel, D.; Poortmans, J.

    2010-09-01

    Solar modules made from thin-film crystalline-silicon layers of high quality on glass substrates could lower the price of photovoltaic electricity substantially. Almost half of the price of wafer-based silicon solar modules is currently due to the cost of the silicon wafers themselves. Using crystalline-silicon thin-film as the active material would substantially reduce the silicon consumption while still ensuring a high cell-efficiency potential and a stable cell performance. One way to create a crystalline-silicon thin film on glass is by using a seed layer approach in which a thin crystalline-silicon layer is first created on a non-silicon substrate, followed by epitaxial thickening of this layer. In this paper, we present new solar cell results obtained on 10-micron thick monocrystalline-silicon layers, made by epitaxial thickening of thin seed layers on transparent glass-ceramic substrates. We used thin (001)-oriented silicon single-crystal seed layers on glass-ceramic substrates provided by Corning Inc. that are made by a process based on anodic bonding and implant-induced separation. Epitaxial thickening of these seed layers was realized in an atmospheric-pressure chemical vapor deposition system. Simple solar cell structures in substrate configuration were made from the epitaxial mono-silicon layers. The Si surface was plasma-textured to reduce the front-side reflection. No other light trapping features were incorporated. Efficiencies of up to 11% were reached with Voc values above 600 mV indicating the good electronic quality of the material. We believe that by further optimizing the material quality and by integrating an efficient light trapping scheme, the efficiency potential of these single-crystal silicon thin films on glass-ceramics should be higher than 15%.

  5. Determination of grain boundary impurity effects in polycrystalline silicon

    Science.gov (United States)

    Kazmerski, L. L.; Dick, J. R.

    1984-06-01

    An analysis is made of the relationships existing between the chemistry and composition of the intergrain regions in polycrystalline silicon, the electrooptical properties of the grain boundaries, and the performance of polycrystalline Si solar cells. The following two impurity mechanisms are emphasized: segregation of oxygen to grain boundaries during heat treatments and the passivation of grain boundaries by incorporation of hydrogen. It is shown that hydrogen is localized at the defects; the effects of hydrogen localization on the electrical characteristics of the grain boundary and of the solar cell are discussed.

  6. Improved transport properties of polycrystalline YBCO thin-films

    Science.gov (United States)

    Azoulay, J.; Verdyan, A.; Lapsker, I.

    1994-12-01

    Resistive evaporation technique was used to fabricate polycrystalline YBaCuO and YBaNaCuO thin films on MgO substrates. Heat treatment was carried out in a low oxygen partial pressure. Polycrystalline YBCO and Na doped YBCO thin films samples were thus obtained using the same technique and conditions. The critical current density of Na doped YBCO sample was measured to be significantly higher than that of the undoped YBCO one. The results are discussed in terms of the Na contribution to the intragrain conductivity.

  7. CMOS compatible fabrication of flexible and semi-transparent FeRAM on ultra-thin bulk monocrystalline silicon (100) fabric

    KAUST Repository

    Ghoneim, Mohamed T.

    2014-08-01

    Commercialization of flexible electronics requires reliable, high performance, ultra-compact and low power devices. To achieve them, we fabricate traditional electronics on bulk mono-crystalline silicon (100) and transform the top portion into an ultra-thin flexible silicon fabric with prefabricated devices, preserving ultra-large-scale-integration density and same device performance. This can be done in a cost effective manner due to its full compatibility with standard CMOS processes. In this paper, using the same approach, for the first time we demonstrate a ferroelectric random access memory (FeRAM) cell on flexible silicon fabric platform and assess its functionality and practical potential.

  8. Electrical analysis of high dielectric constant insulator and metal gate metal oxide semiconductor capacitors on flexible bulk mono-crystalline silicon

    KAUST Repository

    Ghoneim, Mohamed T.

    2015-06-01

    We report on the electrical study of high dielectric constant insulator and metal gate metal oxide semiconductor capacitors (MOSCAPs) on a flexible ultra-thin (25 μm) silicon fabric which is peeled off using a CMOS compatible process from a standard bulk mono-crystalline silicon substrate. A lifetime projection is extracted using statistical analysis of the ramping voltage (Vramp) breakdown and time dependent dielectric breakdown data. The obtained flexible MOSCAPs operational voltages satisfying the 10 years lifetime benchmark are compared to those of the control MOSCAPs, which are not peeled off from the silicon wafer. © 2014 IEEE.

  9. Efficiency of the monocrystalline photovoltaic modules in conversion solar radiation into electrical energy; Eficiencia de modulos fotovoltaicos monocristalinos na conversao de radiacao solar em energia eletrica

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Carliane Diniz e [Universidade Estadual do Maranhao (UEMA), Sao Luis, MA (Brazil). Dept. de Engenharia Agricola], Email: carlianeds@yahoo.com.br; Seraphim, Odivaldo Jose [Universidade Estadual Paulista (FCA/UNESP), SP (Brazil). Fac. de Ciencias Agronomicas. Dept. de Engenharia Rural], Email: seraphim@fca.unesp.br

    2006-07-01

    With the scarcity of the conventional sources of energy production, other options must be considered, as the use of energy resources you renewed, that they offer to multiple advantages. One of the options to the supply of energy of the agricultural users is the photovoltaic solar systems for the local promotion of the quality of life. The objective of this study was to evaluate two marks of monocrystalline photovoltaic modules in different angles of inclination. The modules had presented low efficiency of conversion in conditions of field for incident solar radiation. (author)

  10. Large structural, thin-wall castings made of metals subject to hot tearing, and their fabrication

    Science.gov (United States)

    Smashey, Russell W. (Inventor)

    2001-01-01

    An article, such as a gas turbine engine mixer, is made by providing a mold structure defining a thin-walled, hollow article, and a base metal that is subject to hot tear cracking when cast in a generally equiaxed polycrystalline form, such as Rene' 108 and Mar-M247. The article is fabricated by introducing the molten base metal into the mold structure, and directionally solidifying the base metal in the mold structure to form a directionally oriented structure. The directionally oriented structure may be formed of a single grain or oriented multiple grains.

  11. EVOLUTION OF AS—CAST MICROSTRUCTURES OF 356 ALUMINIUM ALLOY CAST BY LIQUIDUS CASTING

    Institute of Scientific and Technical Information of China (English)

    J.Dong; G.M.Lu; 等

    2003-01-01

    A new method (liquidus casting)was used for 356 Al alloy semi-solid slurry mak-ing.The structures of 356 Al alloy cast by a fe mould and semi-continuous casting machine at different temperatures were inves tigated.How the globular grains form was qlso discussed.The results show that either being cast by single Fe mould or semi-continuous machine,the microstructures are not conventional dendrites but fine and net-globular grains.The average grain size is smaller than 30μm and suitable enough for thixoforming,meanwhile it can improve the mechanical properties of fol-lowing products.Under the suitable casting velocity and cooling intensity,most of global grains prolong their global browth and collide with each other before dendritic growth because of the large amount of the nucleation sites.

  12. Comparison of marginal accuracy of castings fabricated by conventional casting technique and accelerated casting technique: An in vitro study

    Directory of Open Access Journals (Sweden)

    S Srikanth Reddy

    2013-01-01

    Full Text Available Background: Conventional casting technique is time consuming when compared to accelerated casting technique. In this study, marginal accuracy of castings fabricated using accelerated and conventional casting technique was compared. Materials and Methods: 20 wax patterns were fabricated and the marginal discrepancy between the die and patterns were measured using Optical stereomicroscope. Ten wax patterns were used for Conventional casting and the rest for Accelerated casting. A Nickel-Chromium alloy was used for the casting. The castings were measured for marginal discrepancies and compared. Results: Castings fabricated using Conventional casting technique showed less vertical marginal discrepancy than the castings fabricated by Accelerated casting technique. The values were statistically highly significant. Conclusion: Conventional casting technique produced better marginal accuracy when compared to Accelerated casting. The vertical marginal discrepancy produced by the Accelerated casting technique was well within the maximum clinical tolerance limits. Clinical Implication: Accelerated casting technique can be used to save lab time to fabricate clinical crowns with acceptable vertical marginal discrepancy.

  13. Thin film polycrystalline silicon: Promise and problems in displays and solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Fonash, S.J. [Pennsylvania State Univ., University Park, PA (United States)

    1995-08-01

    Thin film polycrystalline Si (poly-Si) with its carrier mobilities, potentially good stability, low intragrain defect density, compatibility with silicon processing, and ease of doping activation is an interesting material for {open_quotes}macroelectronics{close_quotes} applications such as TFTs for displays and solar cells. The poly-Si films needed for these applications can be ultra-thin-in the 500{Angstrom} to 1000{Angstrom} thickness range for flat panel display TFTs and in the 4{mu}m to 10{mu}m thickness range for solar cells. Because the films needed for these microelectronics applications can be so thin, an effective approach to producing the films is that of crystallizing a-Si precursor material. Unlike cast materials, poly-Si films made this way can be produced using low temperature processing. Unlike deposited poly-Si films, these crystallized poly-Si films can have grain widths that are much larger than the film thickness and almost atomically smooth surfaces. This thin film poly-Si crystallized from a-Si precursor films, and its promise and problems for TFTs and solar cells, is the focus of this discussion.

  14. Anomalous photoelectric effect of a polycrystalline topological insulator film.

    Science.gov (United States)

    Zhang, Hongbin; Yao, Jiandong; Shao, Jianmei; Li, Hai; Li, Shuwei; Bao, Dinghua; Wang, Chengxin; Yang, Guowei

    2014-07-29

    A topological insulator represents a new state of quantum matter that possesses an insulating bulk band gap as well as a spin-momentum-locked Dirac cone on the surface that is protected by time-reversal symmetry. Photon-dressed surface states and light-induced surface photocurrents have been observed in topological insulators. Here, we report experimental observations of an anomalous photoelectric effect in thin films of Bi2Te3, a polycrystalline topological insulator. Under illumination with non-polarised light, transport measurements reveal that the resistance of the topological surface states suddenly increases when the polycrystalline film is illuminated. The resistance variation is positively dependent on the light intensity but has no relation to the applied electric field; this finding can be attributed to the gap opening of the surface Dirac cone. This observation of an anomalous photoelectric effect in polycrystalline topological insulators offers exciting opportunities for the creation of photodetectors with an unusually broad spectral range. Moreover, polycrystalline topological insulator films provide an attractive material platform for exploring the nature and practical application of topological insulators.

  15. The decoration of vicinal copper polycrystalline surface by Antimony

    CSIR Research Space (South Africa)

    Ndlovu, GF

    2011-07-01

    Full Text Available An Ultra-high Vacuum Variable Temperature Scanning Tunnelling Microscope was used to study the growth mechanism of Antimony on vicinal Cu polycrystalline samples. The STM data after deposition of 0.3 ML Sb at 300°C showed localization of Sb atoms...

  16. System of polarization correlometry of biological liquids layers polycrystalline structure

    Science.gov (United States)

    Ushenko, A. G.; Boychuk, T. M.; Mincer, O. P.; Angelsky, P. O.; Bodnar, N. B.; Oleinichenko, B. P.; Bizer, L. I.

    2013-09-01

    A model of generalized optical anisotropy of human bile is suggested and a method of polarimetric of the module and phase Fourier of the image of the field of laser radiation is analytically substantiated, that is generated by the mechanisms of linear and circular birefringence of polycrystalline networks with a diagnosis and differentiation of cholelithiasis against a background of chronic cholecystitis.

  17. Microstructure evolution of polycrystalline silicon by molecular dynamics simulation

    Science.gov (United States)

    Chen, Xiao; Ding, Jianning; Jiang, Cunhua; Liu, Zunfeng; Yuan, Ningyi

    2017-06-01

    Polycrystalline silicon is the dominant material in solar cells and plays an important role in photovoltaic industry. It is important for not only the conventional production of silicon ingots but also the direct growth of silicon wafers to control crystallization for obtaining the desired polycrystalline silicon. To the best of our knowledge, few studies have systematically reported about the effects of crystalline planes on the solidification behavior of liquid silicon and the analysis of the microstructural features of the polysilicon structure. In this study, molecular dynamics simulations were employed to investigate the solidification and microstructure evolution of polysilicon, with focus on the effects of the seed distribution and cooling rate on the growth of polycrystalline silicon. The (110), (111), and (112) planes were extruded by the (100) plane and formed the inclusion shape. The crystallization of silicon consisted of diamond-type structures is relatively high at a low cooling rate. The simulations provide substantial information regarding microstructures and serve as guidance for the growth of polycrystalline silicon.

  18. Microstructure evolution of polycrystalline silicon by molecular dynamics simulation

    Directory of Open Access Journals (Sweden)

    Xiao Chen

    2017-06-01

    Full Text Available Polycrystalline silicon is the dominant material in solar cells and plays an important role in photovoltaic industry. It is important for not only the conventional production of silicon ingots but also the direct growth of silicon wafers to control crystallization for obtaining the desired polycrystalline silicon. To the best of our knowledge, few studies have systematically reported about the effects of crystalline planes on the solidification behavior of liquid silicon and the analysis of the microstructural features of the polysilicon structure. In this study, molecular dynamics simulations were employed to investigate the solidification and microstructure evolution of polysilicon, with focus on the effects of the seed distribution and cooling rate on the growth of polycrystalline silicon. The (110, (111, and (112 planes were extruded by the (100 plane and formed the inclusion shape. The crystallization of silicon consisted of diamond-type structures is relatively high at a low cooling rate. The simulations provide substantial information regarding microstructures and serve as guidance for the growth of polycrystalline silicon.

  19. Radiation-hard polycrystalline mercuric iodide semiconductor particle counters

    Energy Technology Data Exchange (ETDEWEB)

    Schieber, M. [Hebrew Univ., Jerusalem (Israel)]|[Sandia National Laboratories, Livermore Ca 94556 (United States); Zuck, A.; Melekhov, L.; Nissenbaum, J. [Hebrew Univ., Jerusalem (Israel); Turchetta, R.; Dulinski, W.; Husson, D.; Riester, J.L. [LEPSI (ULP/IN2P3), Strasbourg (France)

    1998-06-01

    Mercuric iodide polycrystalline radiation detectors, which can act as nuclear particle counters and for large area imaging devices, have been fabricated using three different methods. Response to X- and gamma rays, beta particles and to 100GeV muons, as well as radiation hardness results are briefly described. (orig.) 8 refs.

  20. NUMERICAL MODELING OF HARDENING OF UNINTERRUPTEDLY-CASTED BRONZE CASTING

    Directory of Open Access Journals (Sweden)

    E. I. Marukovich

    2009-01-01

    Full Text Available The three-dimensional numerical model for calculation of thermal fields during solidification of continuously casted bronze casting is developed. Coefficients of heat transfer on borders of calculation areas on the basis of the solution of inverse heat transfer conduction problem are determined. The analysis of thermal fields, depending on loop variables of drawing and the sizes of not cooled zone of crystallizer is curried out.

  1. Modelling of flow phenomena during DC casting

    NARCIS (Netherlands)

    Zuidema, J.

    2005-01-01

    Modelling of Flow Phenomena during DC Casting Jan Zuidema The production of aluminium ingots, by semi-continuous casting, is a complex process. DC Casting stands for direct chill casting. During this process liquid aluminium transforms to solid aluminium while cooling down. This is not an instanta

  2. Modelling of flow phenomena during DC casting

    NARCIS (Netherlands)

    Zuidema, J.

    2005-01-01

    Modelling of Flow Phenomena during DC Casting Jan Zuidema The production of aluminium ingots, by semi-continuous casting, is a complex process. DC Casting stands for direct chill casting. During this process liquid aluminium transforms to solid aluminium while cooling down. This is not an

  3. Large-Scale PV Module Manufacturing Using Ultra-Thin Polycrystalline Silicon Solar Cells: Final Subcontract Report, 1 April 2002--28 February 2006

    Energy Technology Data Exchange (ETDEWEB)

    Wohlgemuth, J.; Narayanan, M.

    2006-07-01

    The major objectives of this program were to continue advances of BP Solar polycrystalline silicon manufacturing technology. The Program included work in the following areas. (1) Efforts in the casting area to increase ingot size, improve ingot material quality, and improve handling of silicon feedstock as it is loaded into the casting stations. (2) Developing wire saws to slice 100-..mu..m-thick silicon wafers on 290-..mu..m-centers. (3) Developing equipment for demounting and subsequent handling of very thin silicon wafers. (4) Developing cell processes using 100-..mu..m-thick silicon wafers that produce encapsulated cells with efficiencies of at least 15.4% at an overall yield exceeding 95%. (5) Expanding existing in-line manufacturing data reporting systems to provide active process control. (6) Establishing a 50-MW (annual nominal capacity) green-field Mega-plant factory model template based on this new thin polycrystalline silicon technology. (7) Facilitating an increase in the silicon feedstock industry's production capacity for lower-cost solar-grade silicon feedstock..

  4. Electronic structure of nanocrystalline and polycrystalline hydrogen storage materials

    Energy Technology Data Exchange (ETDEWEB)

    Smardz, L. [Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17 Street, 60-179 Poznan (Poland); Jurczyk, M.; Smardz, K.; Nowak, M.; Makowiecka, M.; Okonska, I. [Institute of Materials Science and Engineering, Poznan University of Technology, M. Sklodowska-Curie 5 Sq., 60-965 Poznan (Poland)

    2008-02-15

    To optimise the choice of the compounds for a selected application, a better understanding of the role of each alloy constituent on the electronic properties of the material is crucial. In this work, we study experimentally the electronic properties of nanocrystalline and polycrystalline (Mg{sub 1-x}M{sub x}){sub 2}Ni, (Mg{sub 1-x}M{sub x}){sub 2}Cu, La(Ni{sub 1-x}M{sub x}){sub 5}, and Ti(Ni{sub 1-x}M'{sub x}) (M = Mn, Al; M' = Fe, Mg, Zr) alloys. The nanocrystalline and polycrystalline samples were prepared by mechanical alloying (MA) followed by annealing and arc melting method, respectively. All X-ray photoelectron spectroscopy (XPS) spectra were measured immediately after cleaning of the sample surface in a vacuum of 8 x 10{sup -11} mbar. Furthermore, we have measured XPS spectra of in situ prepared nanocrystalline and polycrystalline LaNi{sub 5}, TiNi, and Mg{sub 2}Ni thin films and compared with those obtained for ex situ prepared bulk materials. The substitution of Mg in Mg{sub 2}Ni and Mg{sub 2}Cu, Ni in LaNi{sub 5} and TiNi by transition metals leads to significant modifications of the shape and width of the valence band of the nanocrystalline as well as polycrystalline samples. Especially, the valence bands of the MA nanocrystalline alloys are considerably broader compared to those measured for the polycrystalline samples. Results also showed that the strong modifications of the electronic structure of the nanocrystalline alloys could significantly influence on their hydrogenation properties. (author)

  5. Performance Comparison of Stion CIGS Modules to Baseline Monocrystalline Modules at the New Mexico Florida and Vermont Regional Test Centers: January 2015-December 2016.

    Energy Technology Data Exchange (ETDEWEB)

    Lave, Matthew Samuel [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Stein, Joshua [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Burnham, Laurie [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-01-01

    This report provides performance data and analysis for two Stion copper indium gallium selenide (CIGS) module types, one framed, the other frameless, and installed at the New Mexico, Florida and Vermont RTCs. Sandia looked at data from both module types and compared the latter with data from an adjacent monocrystalline baseline array at each RTC. The results indicate that the Stion modules are slightly outperforming their rated power, with efficiency values above 100% of rated power, at 25degC cell temperatures. In addition, Sandia sees no significant performance differences between module types, which is expected because the modules differ only in their framing. In contrast to the baseline systems, the Stion strings showed increasing efficiency with increasing irradiance, with the greatest increase between zero and 400 Wm -2 but still noticeable increases at 1000 Wm -2 . Although baseline data availability in Vermont was spotty and therefore comparative trends are difficult to discern, the Stion modules there may offer snow- shedding advantages over monocrystalline-silicon modules but these findings are preliminary.

  6. Some Theoretical Considerations on Caste

    Directory of Open Access Journals (Sweden)

    Madhusudan Subedi

    2014-05-01

    Full Text Available Caste as a system of social stratification was an encompassing system in the past. There was reciprocal system of exchange goods and services. With time, occupation and mode of generation of livelihood of various caste groups changed, and the traditional form of jajmani system fizzled out. This paper provides an account of changing perspectives of caste relations in social science writing and political discourse. The discourse of caste has been shifted from ritual hierarchy and social discrimination to an instrument to mobilize people for economic and political gain. DOI: http://dx.doi.org/10.3126/dsaj.v7i0.10437 Dhaulagiri Journal of Sociology and Anthropology Vol. 7, 2013; 51-86

  7. The CAST Time Projection Chamber

    CERN Document Server

    Autiero, D; Cébrian, S; Carmona, J M; Chesi, Enrico Guido; Davenport, M; Delattre, M; Di Lella, L; Formenti, F; Gomez, H; Hasinoff, M; Irastorza, I G; Lakic, B; Luzón, G; Morales, J; Musa, L; Ortiz, A; Placci, A; Rodríguez, A; Ruz, J; Villar, J A; Zioutas, K

    2007-01-01

    One of the three X-ray detectors of the CAST experiment searching for solar axions is a Time Projection Chamber (TPC) with a multi-wire proportional counter (MWPC) as a readout structure. Its design has been optimized to provide high sensitivity to the detection of the low intensity X-ray signal expected in the CAST experiment. A low hardware threshold of 0.8 keV is safely set during normal data taking periods, and the overall efficiency for the detection of photons coming from conversion of solar axions is 62 %. Shielding has been installed around the detector, lowering the background level to 4.10 x 10^-5 counts/cm^2/s/keV between 1 and 10 keV. During phase I of the CAST experiment the TPC has provided robust and stable operation, thus contributing with a competitive result to the overall CAST limit on axion-photon coupling and mass.

  8. Casting Using A Polystyrene Pattern

    Science.gov (United States)

    Vasquez, Peter; Guenther, Bengamin; Vranas, Thomas; Veneris, Peter; Joyner, Michael

    1993-01-01

    New technique for making metal aircraft models saves significant amount of time and effort in comparison with conventional lost-wax method. Produces inexpensive, effective wind-tunnel models. Metal wind-tunnel model cast by use of polystyrene pattern.

  9. Agile Manufacturing Development of Castings

    Science.gov (United States)

    2007-11-02

    responsible for con- verting the available 2D CATIA casting design into a 3D Pro/Engineering geometric model of the casting, for use by Clinkenbeard...changes to the draw- ings. MWM. As the part designer, MWM reviewed and evalu- ated proposed changes to the design. MWM also updated the CATIA ...creation of solid models of the cores and molds, using IGES translations of the CATIA files secured from MWM through GE Transportation Sys- tems. Due

  10. Colour Metallography of Cast Iron

    Institute of Scientific and Technical Information of China (English)

    Zhou Jiyang; Liu Jincheng

    2011-01-01

    @@ Vermicular graphite cast iron(VG iron for short in the following sections)is a type of cast iron in which the graphite is intermediate in shape between flake and spheroidal.Compared with the normal flake graphite in grey iron, the graphite in VG iron is shorter and thicker and shows a curved, more rounded shape.Because its outer contour is exactly like a worm, hence it is called vermicular graphite.

  11. Inoculation of chromium white cast iron

    Directory of Open Access Journals (Sweden)

    D. Kopyciński

    2009-01-01

    Full Text Available It has been proved that an addition of boron carbide introduced as an inoculant to the chromium white cast iron changes the structureof castings. Castings after inoculation revealed a different structure with numerous grains. Primary precipitates of chromium carbide also appeared, reducing the mechanical properties of as-cast parts. Properly established heat treatment regime makes chromium iron castings regain their, originally high, mechanical properties.

  12. Light metal compound casting

    Institute of Scientific and Technical Information of China (English)

    Konrad; J.; M.; PAPIS; Joerg; F.; LOEFFLER; Peter; J.; UGGOWITZER

    2009-01-01

    ‘Compound casting’simplifies joining processes by directly casting a metallic melt onto a solid metal substrate. A continuously metallurgic transition is very important for industrial applications, such as joint structures of spaceframe constructions in transport industry. In this project, ‘compound casting’ of light metals is investigated, aiming at weight-saving. The substrate used is a wrought aluminium alloy of type AA5xxx, containing magnesium as main alloying element. The melts are aluminium alloys, containing various alloying elements (Cu, Si, Zn), and magnesium. By replacing the natural oxygen layer with a zinc layer, the inherent wetting difficulties were avoided, and compounds with flawless interfaces were successfully produced (no contraction defects, cracks or oxides). Electron microscopy and EDX investigations as well as optical micrographs of the interfacial areas revealed their continu- ously metallic constitution. Diffusion of alloying elements leads to heat-treatable microstructures in the vicinity of the joining interfaces in Al-Al couples. This permits significant variability of mechanical properties. Without significantly cutting down on wettability, the formation of low-melting intermetallic phases (Al3Mg2 and Al12Mg17 IMPs) at the interface of Al-Mg couples was avoided by applying a protective coating to the substrate.

  13. Moldless casting by laser

    Science.gov (United States)

    McLean, Marc A.; Shannon, G. J.; Steen, William M.

    1997-09-01

    The principle of laser cladding involves the use of high power carbon-dioxide lasers and powder deposition technology to provide wear and corrosion resistant surface coatings to engineering components. By injecting metal powder into a laser generated melt pool on a moving substrate a solidified metal track can be produced. Deposition of successive tracks produces a multi-layer build. Laser direct casting (LDC) utilizes a coaxial nozzle enabling consistent omnidirectional deposition to produce 3D components from a selection of metal powders. The influence of the principal process parameters over the process features namely, powder catchment efficiency, beam shape and build rates are presented with several successfully generated 3D components. Nickel, stainless steel and satellite powders were deposited at laser powders of 0.4 to 1.4 kW and speeds of 500 to 1000 mm/min achieving build rates of 3 to 9 mm3/s. Fully dense metallurgical structures have been produced with no cracking or porosity and powder catchment efficiencies up to 85% have been achieved.

  14. Investigating the Uptake Mechanisms of Hydrogen Peroxide to Single and Polycrystalline Ice with a Novel Flow Tube System

    Science.gov (United States)

    Hong, Angela; Ammann, Markus; Bartels-Rausch, Thorsten

    2016-04-01

    Air-ice chemical interactions are important for describing the distribution and subsequent chemical fate of trace atmospheric gases within ice and snow and determining the oxidative capacities of these environments. The nature of this interaction is governed by a compound's physicochemical properties as well as ice microstructure. Hydrogen peroxide (H2O2), a reservoir of HOx radicals in the atmosphere and an important chromophore in snow and ice, is a trace gas that demonstrates complex uptake behaviour to frozen aqueous media by the reversible, fast adsorption to the air-ice interface, aggregation, and lateral interactions, and a slower process, ostensibly via uptake into the bulk. However, the exact mechanism and kinetics for the slow uptake of H2O2 and the size of this reservoir is unknown. It is important to describe and quantify this loss term, over environmentally-relevant timescales, accommodation of H2O2 into the bulk may be the dominant process which controls the composition and chemistry of the snow and overlying atmosphere. We hypothesize that the slow uptake of H2O2 occurs by diffusion into the grain boundaries of ice. To provide mechanistic insight to the macroscopic phenomenon of atmospheric gas uptake to ice, and discern various mechanisms including adsorption to air-ice interface and accommodation into the bulk through uptake into grain boundaries, we design, machine, and validate a novel flow reactor system featuring a Drilled Ice Flow Tube (DIFT). Our flow reactor system is uniquely suited to testing these uptake mechanisms: by controlling the degree of grain boundaries present in the DIFT (ie. monocrystalline or polycrystalline), we can directly observe the effect of the ice microstructure on the adsorptive and bulk uptake of trace atmospheric gases over long timescales (eg. on the order of hours). Here, we describe method development of the DIFT and demonstrate using polarised microscopy imagery that our experimental set-up allows for the direct

  15. EVOLUTION OF AS-CAST MICROSTRUCTURES OF 356 ALUMINIUM ALLOY CAST BY LIQUIDUS CASTING

    Institute of Scientific and Technical Information of China (English)

    J. Dong; G.M. Lu; J.Z. Cui; Z.H. Zhao

    2003-01-01

    A new method (liquidus casting) was used for 356 Al alloy semi-solid slurry mak-ing. The structures of 356 Al alloy cast by a Fe mould and semi-continuous castingmachine at different temperatures were investigated. How the globular grains formwas also discussed. The results show that either being cast by single Fe mould orsemi-continuous machine, the microstructures are not conventional dendrites but fineand net-globular grains. The average grain size is smaller than 30μm and suitableenough for thixoforming, meanwhile it can improve the mechanical properties of fol-lowing products. Under the suitable casting velocity and cooling intensity, most ofglobal grains prolong their global growth and collide with each other before dendriticgrowth because of the large amount of the nucleation sites.

  16. Untouchable castes of Uttar Pradesh

    Directory of Open Access Journals (Sweden)

    Kharinin Artem Igorevich

    2015-04-01

    Full Text Available The Untouchable Castes of Uttar Pradesh are examined in this article. This region is one of the most populated in India. Also it is one of the most social mixed-composed in whole State. That’s why main conclusions which were made on this material can be extrapolated to all social space of country. The authors choose four ethno-caste groups, which represent the majority in untouchables and the three smallest in jaties. Their positions in regional hierarchy and economic specialization are analyzed in detail. There are a lot of information about their number, social structure, literacy rating, endogamy, day-to-day practices, customs and other features. Special accents were pointed on mind orientation of their elites toward integration in modern society or, conversely, toward the conservation of traditional forms of existence. The issues of origin and social evolution of untouchable castes of Uttar Pradesh are examined. There is assessment of castes’ sanskritization or other forms of social selfdevelopment. The quality of “scheduled” castes social environment is analyzed. As a marks of its positiveness the data about discrimination untouchables from other social groups and degree of political representativeness of “scheduled” castes, accessibility of education and labour were chosen. The conclusions were made about development degree of some castes. The factors that play role in positive changes in contemporary conditions were determined. The authors put forward their own hypothesis of future development of untouchable castes in Uttar Pradesh. Empiric base of this article was established on sources that have Indian origin and historical and social research of outstanding western indologies.

  17. Development of vacuum die-casting process

    Institute of Scientific and Technical Information of China (English)

    Masashi Uchida

    2009-01-01

    The vacuum die-casting process, started 25 years ago in Japan, has been widely applied. This technology contributes very much to improvement of castings quality. The main factor causing the defects of die castings is the trapped air in the mold cavity, while the key technology of vacuum die-casting process is to avoid the trapped air effectively by evacuating the cavity before casting. At the same time, due to the shot speed and the casting pressure reduced in half, the service life of the die is prolonged and the productivity is enhanced, as well. Vacuum die-casting process is of great significance in improving the die castings quality and making up the shortcomings of super-high-speed shot casting.

  18. Fillability of Thin-Wall Steel Castings

    Energy Technology Data Exchange (ETDEWEB)

    Robert C. Voigt; Joseph Bertoletti; Andrew Kaley; Sandi Ricotta; Travis Sunday

    2002-07-30

    The use of steel components is being challenged by lighter nonferrous or cast iron components. The development of techniques for enhancing and ensuring the filability of thin-wall mold cavities is most critical for thinner wall cast steel production. The purpose of this research was to develop thin-wall casting techniques that can be used to reliably produce thin-wall castings from traditional gravity poured sand casting processes. The focus of the research was to enhance the filling behavior to prevent misrunds. Experiments were conducted to investigate the influence of various foundry variables on the filling of thin section steel castings. These variables include casting design, heat transfer, gating design, and metal fluidity. Wall thickness and pouring temperature have the greatest effect on casting fill. As wall thickness increases the volume to surface area of the casting increases, which increases the solidification time, allowing the metal to flow further in thicker sect ions. Pouring time is another significant variable affecting casting fill. Increases or decreases of 20% in the pouring time were found to have a significant effect on the filling of thin-wall production castings. Gating variables, including venting, pouring head height, and mold tilting also significantly affected thin-wall casting fill. Filters offer less turbulent, steadier flow, which is appropriate for thicker castings, but they do not enhance thin-wall casting fill.

  19. As-Cast Acicular Ductile Aluminum Cast Iron

    Institute of Scientific and Technical Information of China (English)

    S M Mostafavi Kashani; S M A Boutorabi

    2009-01-01

    The effects of nickel (2.2%)and molybdenum (0.6%)additions on the kinetics, microstructure, and me-chanical properties of ductile aluminum cast iron were studied under the as-cast and tempered conditions. Test bars machined from cast to size samples were used for mechanical and metallurgical studies. The results showed that adding nickel and molybdenum to the base iron produced an upper bainitic structure, resulting in an increase in strength and hardness. The same trend was shown when the test bars were tempered at 300 ℃ in the range of 300℃ to 400 ℃. The elongation increased with increasing the temperature from 300 ℃ to 400 ℃. The carbon content of the retained austenite also increased with increasing the temperature. The results also showed that the kinetics, mi-crostructure, and mechanical properties of this iron were similar to those of Ni-Mo alloyed silicon ductile iron.

  20. Grain boundaries analysis in polycrystalline silicon by TEM

    Energy Technology Data Exchange (ETDEWEB)

    Komninou, F.; Karakostas, T.; Bleris, G.L.; Economou, N.A. (Aristoteles University, Thessaloniki (Greece))

    1982-01-01

    Polycrystalline Si interfaces were examined within the CSL's approach. The rotation relationship of every bicrystal has been analyzed with the technique of the instrumental system and the small angle description has been used for the CSL characterization. The most frequently occuring descriptions are CSL' ..sigma..=3 coherent and incoherent twins, the later being microscopically coherent. Cases of multiple boundaries were also examined and interelations were found between low or high angle boundaries for CSL's with ..sigma..>3. A special case of interest is a ..sigma..=39 CSL which is formed from a combination of ..sigma..=13b and ..sigma..=3 and is a triclinic CSL lacking 180/sup 0/ rotational operations. The results presented indicate that for polycrystalline Si the CSL model could be used in describing the interfaces occuring.

  1. New multiphase equation of state for polycrystalline quartz

    Energy Technology Data Exchange (ETDEWEB)

    Boettger, J.C.; Lyon, S.P.

    1990-10-01

    We have generated separate equations of state (EOS's) for the alpha quartz, coesite, and stishovite phases of polycrystalline quartz (SiO{sub 2}) using the computer program GRIZZLY. We also modified the program GRIZZLY to combine two single-phase EOS's for a given material into a single two-phase EOS via minimization of the Gibbs free energy. This new version of GRIZZLY has been used to generate a three-phase SESAME type EOS for polycrystalline quartz using the three EOS's mentioned above. All four of the EOS's produced for SiO{sub 2} are now available on request. 17 refs., 4 figs., 1 tab.

  2. Nucleation and growth of polycrystalline SiC

    DEFF Research Database (Denmark)

    Kaiser, M.; Schimmel, S.; Jokubavicius, V.

    2014-01-01

    R polytypes. It is found that pyrolytic graphite results in enhanced texturing of the nucleating gas species. Reducing the pressure leads to growth of the crystallites until a closed polycrystalline SiC layer containing voids with a rough surface is developed. Bulk growth was conducted at 35 mbar Ar...... pressure at 2250°C in diffusion limited mass transport regime generating a convex shaped growth form of the solid-gas interface leading to lateral expansion of virtually [001] oriented crystallites. Growth at 2350°C led to the stabilization of 6H polytypic grains. The micropipe density in the bulk strongly......The nucleation and bulk growth of polycrystalline SiC in a 2 inch PVT setup using isostatic and pyrolytic graphite as substrates was studied. Textured nucleation occurs under near-thermal equilibrium conditions at the initial growth stage with hexagonal platelet shaped crystallites of 4H, 6H and 15...

  3. Leakage current measurements of a pixelated polycrystalline CVD diamond detector

    OpenAIRE

    Zain, R.M.; Maneuski, D.; O'Shea, V.; Bates, R.; Blue, A.; Cunnigham, L.; Stehl, C.; Berderman, E.; Rahim, R. A.

    2013-01-01

    Diamond has several desirable features when used as a material for radiation detection. With the invention of synthetic growth techniques, it has become feasible to look at developing diamond radiation detectors with reasonable surface areas. Polycrystalline diamond has been grown using a chemical vapour deposition (CVD) technique by the University of Augsburg and detector structures fabricated at the James Watt Nanofabrication Centre (JWNC) in the University of Glasgow in order to produce pi...

  4. Cell and band structures in cold rolled polycrystalline copper

    DEFF Research Database (Denmark)

    Ananthan, V.S.; Leffers, Torben; Hansen, Niels

    1991-01-01

    The effect of plastic strain on the deformation microstructure has been investigated in polycrystalline copper rolled at room temperature to 5, 10, 20, and 30% reduction in thickness equivalent strain 0.06-0.42). Results from transmission electron microscopy (TEM) observations show that dense...... on {111}. Finally, the evolution of the deformation microstructure in copper is compared with that observed in other face centred cubic metals, especially aluminium....

  5. Modified Sachs's Model of Deformation of Polycrystalline Magnesium

    Science.gov (United States)

    Kesarev, A. G.; Vlasova, A. M.

    2017-09-01

    There are a large number of approaches to a description of work hardening of metal polycrystals with various crystal lattices. In the present work, Sachs's model is generalized to uniaxial tension/compression of polycrystalline magnesium with hexagonal densely packed crystal lattice. The tensile yield stress is estimated taking into account two deformation modes: (0001) easy basal slip and (10\\overline{1}2) twinning.

  6. Rotary Ultrasonic Machining of Poly-Crystalline Cubic Boron Nitride

    OpenAIRE

    2014-01-01

    Poly-crystalline cubic boron nitride (PCBN) is one of the hardest material. Generally, so hard materials could not be machined by conventional machining methods. Therefore, for this purpose, advanced machining methods have been designed. Rotary ultrasonic machining (RUM) is included among them. RUM is based on abrasive removing mechanism of ultrasonic vibrating diamond particles, which are bonded on active part of rotating tool. It is suitable especially for machining hard and brittle materia...

  7. EBIC AND DLTS MEASUREMENTS OF SI-AND POLYCRYSTALLINE SILICON

    OpenAIRE

    Bary, A.; Hamet, J.; Ihlal, A.; Chermant, J.; Nouet, G.

    1988-01-01

    Influence of grain boundaries on the electronic properties of silicon has been studied by electron-beam induced current (EBIC), thermally stimulated capacitance (TSCAP) and deep-level transient spectroscopy (DLTS). Low-angle grain boundaries taken from as-grown polycrystalline wafers for solar cells have been analyzed by EBIC and their behaviors have been compared after the junction diffusion treatment. This treatment gives a decrease of the local diffusion length and recombination velocity o...

  8. Research progress on squeeze casting in China

    Institute of Scientific and Technical Information of China (English)

    Li Yuanyuan; Zhang Weiwen; Zhao Haidong; You Dongdong; Zhang Datong; Shao Ming; Zhang Wen

    2014-01-01

    Squeeze casting is a technology with short route, high efficiency and precise forming, possessing features of casting and plastic processing. It is widely used to produce high performance metallic structural parts. As energy conservation and environmental protection concerns have risen, lightweight and high performance metal parts are urgently needed, which accelerated the development of squeeze casting technology over the past two decades in China. In this paper, research progress on squeeze casting aloys, typical parts manufacturing and development of squeeze casting equipment in China are introduced. The future trend and development priorities of squeeze casting are discussed.

  9. Polycrystalline silicon availability for photovoltaic and semiconductor industries

    Science.gov (United States)

    Ferber, R. R.; Costogue, E. N.; Pellin, R.

    1982-01-01

    Markets, applications, and production techniques for Siemens process-produced polycrystalline silicon are surveyed. It is noted that as of 1982 a total of six Si materials suppliers were servicing a worldwide total of over 1000 manufacturers of Si-based devices. Besides solar cells, the Si wafers are employed for thyristors, rectifiers, bipolar power transistors, and discrete components for control systems. An estimated 3890 metric tons of semiconductor-grade polycrystalline Si will be used in 1982, and 6200 metric tons by 1985. Although the amount is expected to nearly triple between 1982-89, research is being carried out on the formation of thin films and ribbons for solar cells, thereby eliminating the waste produced in slicing Czolchralski-grown crystals. The free-world Si production in 1982 is estimated to be 3050 metric tons. Various new technologies for the formation of polycrystalline Si at lower costs and with less waste are considered. New entries into the industrial Si formation field are projected to produce a 2000 metric ton excess by 1988.

  10. Polycrystalline diamond detectors with three-dimensional electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Lagomarsino, S., E-mail: lagomarsino@fi.infn.it [University of Florence, Department of Physics, Via Sansone 1, 50019 Sesto Fiorentino (Italy); INFN Firenze, Via B. Rossi 1, 50019 Sesto Fiorentino (Italy); Bellini, M. [INO-CNR Firenze, Largo E. Fermi 6, 50125 Firenze (Italy); Brianzi, M. [INFN Firenze, Via B. Rossi 1, 50019 Sesto Fiorentino (Italy); Carzino, R. [Smart Materials-Nanophysics, Istituto Italiano di Tecnologia, Genova, Via Morego 30, 16163 Genova (Italy); Cindro, V. [Joseph Stefan Institute, Jamova Cesta 39, 1000 Ljubljana (Slovenia); Corsi, C. [University of Florence, Department of Physics, Via Sansone 1, 50019 Sesto Fiorentino (Italy); LENS Firenze, Via N. Carrara 1, 50019 Sesto Fiorentino (Italy); Morozzi, A.; Passeri, D. [INFN Perugia, Perugia (Italy); Università degli Studi di Perugia, Dipartimento di Ingegneria, via G. Duranti 93, 06125 Perugia (Italy); Sciortino, S. [University of Florence, Department of Physics, Via Sansone 1, 50019 Sesto Fiorentino (Italy); INFN Firenze, Via B. Rossi 1, 50019 Sesto Fiorentino (Italy); Servoli, L. [INFN Perugia, Perugia (Italy)

    2015-10-01

    The three-dimensional concept in diamond detectors has been applied, so far, to high quality single-crystal material, in order to test this technology in the best available conditions. However, its application to polycrystalline chemical vapor deposited diamond could be desirable for two reasons: first, the short inter-electrode distance of three-dimensional detectors should improve the intrinsically lower collection efficiency of polycrystalline diamond, and second, at high levels of radiation damage the performances of the poly-crystal material are not expected to be much lower than those of the single crystal one. We report on the fabrication and test of three-dimensional polycrystalline diamond detectors with several inter-electrode distances, and we demonstrate that their collection efficiency is equal or higher than that obtained with conventional planar detectors fabricated with the same material. - Highlights: • Pulsed laser fabrication of polycristalline diamond detectors with 3D electrodes. • Measurement of the charge collection efficiency (CCE) under beta irradiation. • Comparation between the CCE of 3D and conventional planar diamond sensors. • A rationale for the behavior of three-dimensional and planar sensors is given.

  11. Physics of grain boundaries in polycrystalline photovoltaic semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    Yan, Yanfa, E-mail: yanfa.yan@utoledo.edu; Yin, Wan-Jian; Wu, Yelong; Shi, Tingting; Paudel, Naba R. [Department of Physics and Astronomy and Wright Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Ohio 43606 (United States); Li, Chen [Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Poplawsky, Jonathan [The Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Wang, Zhiwei [Department of Physics and Astronomy and Wright Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Ohio 43606 (United States); National Renewable Energy Laboratory, Golden, Colorado 80401 (United States); Moseley, John; Guthrey, Harvey; Moutinho, Helio; Al-Jassim, Mowafak M. [National Renewable Energy Laboratory, Golden, Colorado 80401 (United States); Pennycook, Stephen J. [Department of Materials Science and Engineering, University of Tennessee, Knoxville, Tennessee 37996 (United States)

    2015-03-21

    Thin-film solar cells based on polycrystalline Cu(In,Ga)Se{sub 2} (CIGS) and CdTe photovoltaic semiconductors have reached remarkable laboratory efficiencies. It is surprising that these thin-film polycrystalline solar cells can reach such high efficiencies despite containing a high density of grain boundaries (GBs), which would seem likely to be nonradiative recombination centers for photo-generated carriers. In this paper, we review our atomistic theoretical understanding of the physics of grain boundaries in CIGS and CdTe absorbers. We show that intrinsic GBs with dislocation cores exhibit deep gap states in both CIGS and CdTe. However, in each solar cell device, the GBs can be chemically modified to improve their photovoltaic properties. In CIGS cells, GBs are found to be Cu-rich and contain O impurities. Density-functional theory calculations reveal that such chemical changes within GBs can remove most of the unwanted gap states. In CdTe cells, GBs are found to contain a high concentration of Cl atoms. Cl atoms donate electrons, creating n-type GBs between p-type CdTe grains, forming local p-n-p junctions along GBs. This leads to enhanced current collections. Therefore, chemical modification of GBs allows for high efficiency polycrystalline CIGS and CdTe thin-film solar cells.

  12. Magnetostriction of permalloy epitaxial and polycrystalline thin films

    Directory of Open Access Journals (Sweden)

    Futamoto Masaaki

    2013-01-01

    Full Text Available Permalloy epitaxial films of (111, (100, and (110 orientations and a polycrystalline thin film are prepared. Sinusoidal waveforms of magnetostriction are observed when the polycrystalline and the (111oriented epitaxial films are measured under rotating magnetic fields ranging from 10 to 1000 Oe. On the contrary, the (100- and the (110-oriented films, respectively, show a triangle waveform and a waveform consisting of a mixture of triangular and sinusoidal shapes under low magnetic fields. The waveform variation is interpreted by considering the magnetization structure of magnetically unsaturated film with an in-plane magnetic symmetry related with the crystallographic orientation. The waveforms deformed from sinusoidal shape vary to sinusoidal with increasing the magnetic field. Magnetically saturated (100- and (110-oriented films show sinusoidal waveforms. The saturated magnetostriction values are determined as ʎs = 5 × 10–6, 4 × 10–6, 3 × 10–6, and 6 × 10–6 for the (111, the (100, the (110 epitaxial and the polycrystalline films, respectively.

  13. Titanium Aluminide Casting Technology Development

    Science.gov (United States)

    Bünck, Matthias; Stoyanov, Todor; Schievenbusch, Jan; Michels, Heiner; Gußfeld, Alexander

    2017-08-01

    Titanium aluminide alloys have been successfully introduced into civil aircraft engine technology in recent years, and a significant order volume increase is expected in the near future. Due to its beneficial buy-to-fly ratio, investment casting bears the highest potential for cost reduction of all competing production technologies for TiAl-LPTB. However, highest mechanical properties can be achieved by TiAl forging. In view of this, Access e.V. has developed technologies for the production of TiAl investment cast parts and TiAl die cast billets for forging purposes. While these parts meet the highest requirements, establishing series production and further optimizing resource and economic efficiency are present challenges. In order to meet these goals, Access has recently been certified according to aircraft standards, aiming at qualifying parts for production on technology readiness level 6. The present work gives an overview of the phases of development and certification.

  14. CAST Physics Proposal to SPSC

    CERN Document Server

    CAST, Collaboration

    2011-01-01

    The CAST experiment has the potential to search for solar axions (dark matter particle candidates) or other particles with similar coupling. E.g., paraphtons (Hidden Sector), chameleons (dark energy), while considering the possibility whether CAST could be transformed to an antenna for relic axions with rest mass up to 0.1 to 1meV. While axion searches suggest detectors with lower background, paraphoton and chameleon searches require detectors with sub-keV threshold energy and the use of transparent windows in front of the Micromegas detectors, which cover 3 out of the 4 CAST magnet exits. Ongoing theoretical estimates and experimental investigations will define the priorities of the suggested 4 physics items of this proposal for the period 2012-2014.

  15. Energy Consumption of Die Casting Operations

    Energy Technology Data Exchange (ETDEWEB)

    Jerald Brevick; clark Mount-Campbell; Carroll Mobley

    2004-03-15

    Molten metal processing is inherently energy intensive and roughly 25% of the cost of die-cast products can be traced to some form of energy consumption [1]. The obvious major energy requirements are for melting and holding molten alloy in preparation for casting. The proper selection and maintenance of melting and holding equipment are clearly important factors in minimizing energy consumption in die-casting operations [2]. In addition to energy consumption, furnace selection also influences metal loss due to oxidation, metal quality, and maintenance requirements. Other important factors influencing energy consumption in a die-casting facility include geographic location, alloy(s) cast, starting form of alloy (solid or liquid), overall process flow, casting yield, scrap rate, cycle times, number of shifts per day, days of operation per month, type and size of die-casting form of alloy (solid or liquid), overall process flow, casting yield, scrap rate, cycle times, number of shifts per day, days of operation per month, type and size of die-casting machine, related equipment (robots, trim presses), and downstream processing (machining, plating, assembly, etc.). Each of these factors also may influence the casting quality and productivity of a die-casting enterprise. In a die-casting enterprise, decisions regarding these issues are made frequently and are based on a large number of factors. Therefore, it is not surprising that energy consumption can vary significantly from one die-casting enterprise to the next, and within a single enterprise as function of time.

  16. AFM study of the SIMS beam induced roughness in monocrystalline silicon in presence of initial surface or bulk defects of nanometric size

    Energy Technology Data Exchange (ETDEWEB)

    Fares, B. [Laboratoire de Physique de la Matiere (UMR CNRS 5511), INSA de Lyon, 7 Avenue Capelle, F-69621 Villeurbanne Cedex (France)]. E-mail: boubker.fares@insa-lyon.fr; Dubois, C. [Laboratoire de Physique de la Matiere (UMR CNRS 5511), INSA de Lyon, 7 Avenue Capelle, F-69621 Villeurbanne Cedex (France); Gautier, B. [Laboratoire de Physique de la Matiere (UMR CNRS 5511), INSA de Lyon, 7 Avenue Capelle, F-69621 Villeurbanne Cedex (France); Dupuy, J.C. [Laboratoire de Physique de la Matiere (UMR CNRS 5511), INSA de Lyon, 7 Avenue Capelle, F-69621 Villeurbanne Cedex (France); Cayrel, F. [Universite de Tours, Laboratoire de Micro-Electronique de Puissance, 16 Rue Pierre et Marie Curie, F-37071 Tours Cedex 2 (France); Gaudin, G. [Universite de Tours, Laboratoire de Micro-Electronique de Puissance, 16 Rue Pierre et Marie Curie, F-37071 Tours Cedex 2 (France)

    2006-07-30

    In this paper, the SIMS beam induced roughness (BIR) in monocrystalline Si in presence of initial surface or bulk defects of nanometric size is studied. We follow the development of the BIR by monitoring the increase of Si{sup 2+} and SiO{sub 2} {sup +} signals during SIMS sputtering. The topography of the crater bottoms is measured at different steps of the evolution of the roughness using an atomic force microscope (AFM). We show that in presence of nanometric sized defects on the surface or in the bulk, the BIR develops far more rapidly than usual. It appears as soon as the crater reaches the defects and, as reported on Si free from any treatment, the same morphology evidencing waves perpendicular to the sputtering beam develops rapidly. This study of the behaviour of the BIR in presence of voluntarily introduced defects allows us to better understand the basic physical phenomena involved in its apparition.

  17. Physical and Structural Characterization of a Monocrystalline Cu-13.7Al-4.2Ni Alloy Subjected to Thermal Cycling Treatments

    Science.gov (United States)

    Pereira, Elaine Cristina; Matlakhova, Lioudmila Aleksandrovna; Matlakhov, Anatoliy Nikolaevich; Shigue, Carlos Yujiro; Monteiro, Sérgio Neves

    2014-04-01

    A monocrystalline alloy with nominal 82wt pctCu-13.7wt pctAl-4.2wt pctNi composition and exhibiting reversible martensitic transformation (RMT) was subjected to multiple heating and cooling cycles within the RMT range of critical temperatures. Both untreated and cyclic treated alloy samples were characterized by X-ray diffraction, optical microscopy, differential scanning calorimetry, and Vickers microhardness. The results indicated that the alloy presents a complex RMT behavior disclosing a sequence of transformation steps: β 1 ↔ R and R ↔ β'1 + γ'1 as well as possible β 1 ↔ β'1 and β'1 ↔ γ'1 direct reactions. The thermal cycling treatment inhibits the development of γ'1 martensite without much change in both the physical and microstructure characteristics. This suggests a good resistance of the alloy to irreversible structural changes.

  18. Theoretically predicted and experimentally determined effects of the Si/(Si + C) gas phase ratio on the growth and character of monocrystalline beta silicon carbide films

    Science.gov (United States)

    Kim, H. J.; Davis, R. F.

    1986-10-01

    The effects of the Si/(Si + C) ratio in the reaction gas stream on the growth and properties of monocrystalline beta-SiC films grown on Si(100) substrates via chemical vapor deposition have been theoretically and experimentally studied. The amounts of condensed phases of beta-SiC and Si, and the partial pressures of the remaining Si and C-containing gases as a function of the Si/(Si + C) ratio in the source gases have been initially obtained from thermodynamic calculations using the 'SOLGASMIX-PV' computer program. Complementary and comparative experimental growth studies have shown that inclusion-free films having maximum values in growth rate and carrier concentration and a minimum value of resistivity were obtained near Si/(Si + C) = 0.5.

  19. XPS characterization of different thermal treatments in the ITO-Si interface of a carbonate-textured monocrystalline silicon solar cell

    Energy Technology Data Exchange (ETDEWEB)

    Montesdeoca-Santana, A.; Jimenez-Rodriguez, E.; Marrero, N.; Gonzalez-Diaz, B. [Departamento de Fisica Basica, Universidad de La Laguna (ULL), Avenida Astrofisico Francisco Sanchez, 2, 38206 La Laguna, S/C de Tenerife (Spain); Borchert, D. [Institut fuer Solare Energiesysteme, Fraunhofer Institut, Auf der Reihe 2, 45884 Gelsenkirchen (Germany); Guerrero-Lemus, R., E-mail: rglemus@ull.e [Departamento de Fisica Basica, Universidad de La Laguna (ULL), Avenida Astrofisico Francisco Sanchez, 2, 38206 La Laguna, S/C de Tenerife (Spain); Fundacion de Estudios de Economia Aplicada, Catedra Focus-Abengoa, Jorge Juan 46, 28001 Madrid (Spain)

    2010-02-15

    In this work we have applied the X-ray photoelectron spectroscopy (XPS) in depth to study, for the first time, the influence of different thermal treatments in the ITO-Si interface of a monocrystalline Si-based solar cell where the Si surface is carbonate-textured and covered by an ITO sputtered layer. The efficiency of the solar cells significantly increases when thermal treatments are applied just after the ITO deposition. The efficiency is also dependent on the characteristics of the pyramidal relief of the silicon surface previously obtained by immersion of the Si wafers in a sodium carbonate/bicarbonate solution. An efficiency of 15.5% has been obtained with an optimized texturization of the silicon substrates and an annealing treatment of the solar cells at 400 deg. C just after the ITO deposition.

  20. Structural and photoluminescent properties of nanowires formed by the metal-assisted chemical etching of monocrystalline silicon with different doping level

    Energy Technology Data Exchange (ETDEWEB)

    Georgobiani, V. A., E-mail: v.georgobiani@gmail.com; Gonchar, K. A.; Osminkina, L. A.; Timoshenko, V. Yu. [Lomonosov Moscow State University, Faculty of Physics (Russian Federation)

    2015-08-15

    Silicon-nanowire layers grown by the metal-assisted chemical etching of (100)-oriented p-type monocrystalline silicon substrates with a resistivity of 10 and 0.001 Ω · cm are studied by electron microscopy, Raman scattering, and photoluminescence measurements. It is established that nanowires grown on lightly doped substrates are structurally nonporous and formed as crystalline cores covered by nanocrystals 3–5 nm in dimensions. Nanowires grown on heavily doped substrates are structurally porous and contain both small nanocrystals and coarser crystallites with equilibrium charge carriers that influence interband radiative recombination. It is found that the photoluminescence intensity of nanowires in the spectral range 1.3–2.0 eV depends on the presence of molecular oxygen.

  1. Polycrystalline silicon study: Low-cost silicon refining technology prospects and semiconductor-grade polycrystalline silicon availability through 1988

    Science.gov (United States)

    Costogue, E. N.; Ferber, R.; Lutwack, R.; Lorenz, J. H.; Pellin, R.

    1984-01-01

    Photovoltaic arrays that convert solar energy into electrical energy can become a cost effective bulk energy generation alternative, provided that an adequate supply of low cost materials is available. One of the key requirements for economic photovoltaic cells is reasonably priced silicon. At present, the photovoltaic industry is dependent upon polycrystalline silicon refined by the Siemens process primarily for integrated circuits, power devices, and discrete semiconductor devices. This dependency is expected to continue until the DOE sponsored low cost silicon refining technology developments have matured to the point where they are in commercial use. The photovoltaic industry can then develop its own source of supply. Silicon material availability and market pricing projections through 1988 are updated based on data collected early in 1984. The silicon refining industry plans to meet the increasing demands of the semiconductor device and photovoltaic product industries are overviewed. In addition, the DOE sponsored technology research for producing low cost polycrystalline silicon, probabilistic cost analysis for the two most promising production processes for achieving the DOE cost goals, and the impacts of the DOE photovoltaics program silicon refining research upon the commercial polycrystalline silicon refining industry are addressed.

  2. WEAR-RESISTANCE OF CHROMIC CAST IRONS OF EUTECTIC COMPOSITION

    Directory of Open Access Journals (Sweden)

    K. E. Baranovskij

    2009-01-01

    Full Text Available Casting of wear-resistant chrome cast irons in combined molds and iron chills is studied. Application of these ways of casting results in blending of carbides and increasing of hardness of castings.

  3. Casting behavior of titanium alloys in a centrifugal casting machine.

    Science.gov (United States)

    Watanabe, K; Miyakawa, O; Takada, Y; Okuno, O; Okabe, T

    2003-05-01

    Since dental casting requires replication of complex shapes with great accuracy, this study examined how well some commercial titanium alloys and experimental titanium-copper alloys filled a mold cavity. The metals examined were three types of commercial dental titanium [commercially pure titanium (hereinafter noted as CP-Ti), Ti-6Al-4V (T64) and Ti-6Al-7Nb (T67)], and experimental titanium-copper alloys [3%, 5% and 10% Cu (mass %)]. The volume percentage filling the cavity was evaluated in castings prepared in a very thin perforated sheet pattern and cast in a centrifugal casting machine. The flow behavior of the molten metal was also examined using a so-called "tracer element technique." The amounts of CP-Ti and all the Ti-Cu alloys filling the cavity were similar; less T64 and T67 filled the cavity. However, the Ti-Cu alloys failed to reach the end of the cavities due to a lower fluidity compared to the other metals. A mold prepared with specially designed perforated sheets was effective at differentiating the flow behavior of the metals tested. The present technique also revealed that the more viscous Ti-Cu alloys with a wide freezing range failed to sequentially flow to the end of the cavity.

  4. CAST-IRONS AT HIGH TEMPERATURES

    Directory of Open Access Journals (Sweden)

    A. N. Krutilin

    2008-01-01

    Full Text Available The results of investigations of physical-mechanical characteristics of cast iron slugs, received by semicontinuos way of casting, at temperatures from 850 up to 1100^ С are given. 

  5. CONTINUOUSLY-CYCLIC CASTING OF HOLLOW CYLINDER SLUGS OF HIGH-CHROMIUM CAST IRON

    Directory of Open Access Journals (Sweden)

    E. I. Marukovich

    2009-01-01

    Full Text Available The analysis of castings formation is presented and the package of measures dircted on increase of stability of casting process is developed. Parametres of casting of hollow cylindrical billets by the method of directional solidification out of white high-chromium cast iron are defined.

  6. Developing technological process of obtaining giality casts

    Directory of Open Access Journals (Sweden)

    A. Issagulov

    2014-10-01

    Full Text Available The article considers the process of manufacturing castings using sand-resin forms and alloying furnace. Were the optimal technological parameters of manufacturing shell molds for the manufacture of castings of heating equipment. Using the same upon receipt of castings by casting in shell molds furnace alloying and deoxidation of the metal will provide consumers with quality products and have a positive impact on the economy in general engineering.

  7. Squeeze Casting of Steel Weapon Components

    Science.gov (United States)

    1976-09-01

    equipment. The squeeze casting process also differs from rheo- casting.(10-12) Unlike the former, the rheocasting process (8) "Ferrous Die Casting...various phases of rheocasting . At least so far, the process has not been applied to fabrication of complex steel components of the type that are under

  8. Pressure distribution in centrifugal dental casting.

    Science.gov (United States)

    Nielsen, J P

    1978-02-01

    Equations are developed for liquid metal pressure in centrifugal dental casting, given the instantaneous rotational velocity, density, and certain dimensions of the casting machine and casting pattern. A "reference parabola" is introduced making the fluid pressure concept more understandable. A specially designed specimen demonstrates experimentally the reference parabola at freezing.

  9. Prediction of Microporosity in Shrouded Impeller Castings

    Energy Technology Data Exchange (ETDEWEB)

    Viswanathan, S. Nelson, C.D.

    1998-09-01

    The purpose of this Cooperative Research and Development Agreement (CRADA) between the Oak Ridge National Laboratory (ORNL) and Morris Bean and Company was to link computer models of heat and fluid flow with previously developed quality criteria for the prediction of microporosity in a Al-4.5% Cu alloy shrouded impeller casting. The results may be used to analyze the casting process design for the commercial production of 206 o alloy shrouded impeller castings. Test impeller castings were poured in the laboratory for the purpose of obtaining thermal data and porosity distributions. Also, a simulation of the test impeller casting was conducted and the results validated with porosity measurements on the test castings. A comparison of the predicted and measured microporosity distributions indicated an excellent correlation between experiments and prediction. The results of the experimental and modeling studies undertaken in this project indicate that the quality criteria developed for the prediction of microporosity in Al-4.5% Cu alloy castings can accurately predict regions of elevated microporosity even in complex castings such as the shrouded impeller casting. Accordingly, it should be possible to use quality criteria for porosity prediction in conjunction with computer models of heat and fluid flow to optimize the casting process for the production of shrouded impeller castings. Since high levels of microporosity may be expected to result in poor fatigue properties, casting designs that are optimized for low levels of microporosity should exhibit superior fatigue life.

  10. When Your Child Needs a Cast

    Science.gov (United States)

    ... 1- to 2-Year-Old When Your Child Needs a Cast KidsHealth > For Parents > When Your Child Needs a Cast Print A A A What's in ... A cast wraps around the broken area and needs to be removed by a doctor when the ...

  11. The CAST time projection chamber

    Science.gov (United States)

    Autiero, D.; Beltrán, B.; Carmona, J. M.; Cebrián, S.; Chesi, E.; Davenport, M.; Delattre, M.; Di Lella, L.; Formenti, F.; Irastorza, I. G.; Gómez, H.; Hasinoff, M.; Lakic, B.; Luzón, G.; Morales, J.; Musa, L.; Ortiz, A.; Placci, A.; Rodrigurez, A.; Ruz, J.; Villar, J. A.; Zioutas, K.

    2007-06-01

    One of the three x-ray detectors of the CERN Axion Solar Telescope (CAST) experiment searching for solar axions is a time projection chamber (TPC) with a multi-wire proportional counter (MWPC) as a readout structure. Its design has been optimized to provide high sensitivity to the detection of the low intensity x-ray signal expected in the CAST experiment. A low hardware threshold of 0.8 keV is set to a safe level during normal data taking periods, and the overall efficiency for the detection of photons coming from conversion of solar axions is 62%. Shielding has been installed around the detector, lowering the background level to 4.10 × 10-5 counts cm-2 s-1 keV-1 between 1 and 10 keV. During phase I of the CAST experiment the TPC has provided robust and stable operation, thus contributing with a competitive result to the overall CAST limit on axion photon coupling and mass.

  12. Colour Metallography of Cast Iron

    Institute of Scientific and Technical Information of China (English)

    Zhou Jiyang; Liu Jincheng

    2010-01-01

    @@ Spheroidal Graphite Cast Iron(Ⅲ) 3.6 Solidification morphology of SG iron Solidification morphology refers to the description of change,distribution and interrelationship of the solidification structures such as graphite spheroids,austenite,eutectic cells,etc.[99

  13. Cern Axion Solar Telescope (CAST)

    CERN Multimedia

    2002-01-01

    The CERN Solar Axion Telescope, CAST, aims to shed light on a 30-year-old riddle of particle physics by detecting axions originating from the 15 million degree plasma in the Sun 's core. Axions were proposed as an extension to the Standard Model of particle physics to explain why CP violation is observed in weak but not strong interactions.

  14. Advanced Lost Foam Casting Technology

    Energy Technology Data Exchange (ETDEWEB)

    Charles E. Bates; Harry E. Littleton; Don Askeland; Taras Molibog; Jason Hopper; Ben Vatankhah

    2000-11-30

    This report describes the research done under the six tasks to improve the process and make it more functional in an industrial environment. Task 1: Pattern Pyrolysis Products and Pattern Properties Task 2: Coating Quality Control Task 3: Fill and Solidification Code Task 4: Alternate Pattern Materials Task 5: Casting Distortion Task 6: Technology Transfer

  15. CENTRIFUGAL CASTING OF ANTIFRICTION SILUMIN

    Directory of Open Access Journals (Sweden)

    V. Ju. Stetsenko

    2010-01-01

    Full Text Available It is shown that the way of centrifugal casting into water-cooled mould with vertical rotation axis enables to receive hollow slugs with diameter 100–250 mm, with height under 200 mm with wall thickness under 15 mm of antifriction silumin АК15М3, which will replace expensive antifriction bronze.

  16. Search for chameleons with CAST

    DEFF Research Database (Denmark)

    Anastassopoulos, V.; Arik, M.; Aune, S.

    2015-01-01

    energy threshold used for axions from 1 keV to 400 eV CAST became sensitive to the converted solar chameleon spectrum which peaks around 600 eV. Even though we have not observed any excess above background, we can provide a 95% C.L. limit for the coupling strength of chameleons to photons of βΥ≤1011...

  17. Tape casting of magnesium oxide.

    Energy Technology Data Exchange (ETDEWEB)

    Ayala, Alicia; Corral, Erica L.; Loehman, Ronald E.; Bencoe, Denise Nora; Reiterer, Markus; Shah, Raja A.

    2008-02-01

    A tape casting procedure for fabricating ceramic magnesium oxide tapes has been developed as a method to produce flat sheets of sintered MgO that are thin and porous. Thickness of single layer tapes is in the range of 200-400 {micro}m with corresponding surface roughness values in the range of 10-20 {micro}m as measured by laser profilometry. Development of the tape casting technique required optimization of pretreatment for the starting magnesium oxide (MgO) powder as well as a detailed study of the casting slurry preparation and subsequent heat treatments for sintering and final tape flattening. Milling time of the ceramic powder, plasticizer, and binder mixture was identified as a primary factor affecting surface morphology of the tapes. In general, longer milling times resulted in green tapes with a noticeably smoother surface. This work demonstrates that meticulous control of the entire tape casting operation is necessary to obtain high-quality MgO tapes.

  18. Colour Metallography of Cast Iron

    Institute of Scientific and Technical Information of China (English)

    Zhou Jiyang; Liu Jincheng

    2010-01-01

    @@ Spheroidal Graphite Cast Iron(Ⅳ) 3.7 Segregation of SG iron The non-uniform distribution of solute elements during solidification results in the micro segregation of SG iron.As for the redistribution of elements in the phases of the solidification structure,there is no intrinsic difference between SG iron and grey iron[132].

  19. Graphite Formation in Cast Iron

    Science.gov (United States)

    Stefanescu, D. M.

    1985-01-01

    In the first phase of the project it was proven that by changing the ratio between the thermal gradient and the growth rate for commercial cast iron samples solidifying in a Bridgman type furnace, it is possible to produce all types of graphite structures, from flake to spheroidal, and all types of matrices, from ferritic to white at a certain given level of cerium. KC-135 flight experiments have shown that in a low-gravity environment, no flotation occurs even in spheroidal graphite cast irons with carbon equivalent as high as 5%, while extensive graphite flotation occurred in both flake and spheroidal graphite cast irons, in high carbon samples solidified in a high gravity environment. This opens the way for production of iron-carbon composite materials, with high carbon content (e.g., 10%) in a low gravity environment. By using KC-135 flights, the influence of some basic elements on the solidification of cast iron will be studied. The mechanism of flake to spheroidal graphite transition will be studied, by using quenching experiments at both low and one gravity for different G/R ratios.

  20. Technological parameters of die casting and quality of casting from EN AC46500 alloy

    OpenAIRE

    2016-01-01

    Die casting represents the highest technological level of metal mold casting. This technology enables production of almost all final products without necessity of further processing. The important aspect of efficiency and production is a proper casting parameters setting. In the submitted paper following die casting parameters are analyzed: plunger pressing speed and pressure. The studied parameters most significantly affect a qualitative of castings from EN AC46500 alloy and they influence t...

  1. Highly refractory heat-insulating articles based on polycrystalline oxide fibers (review)

    Energy Technology Data Exchange (ETDEWEB)

    Dergaputskaya, L.A.; Degtyareva, E.V.; Dubinko, O.A.; Kalinovskaya, I.N.; Serova, L.V.

    1986-05-01

    The authors discuss the production of polycrystalline fibers from highly refractory oxides, mainly alumina and zirconium dioxide which are the most readily available and the cheapest materials, but highly refractory fibers may be obtained also from other oxides. The fibers are obtained in the monoand polycrystalline forms and the preparation methods for polycrystalline highly refractory fibers are described in some detail. The properties for the main types are given. An addition of small amounts of alumina, polycrystalline fibers to mullite-siliceous glass fiber has a significant influence on the reduction in the shrinkage.

  2. Nonradiative and Radiative Recombination in CdS Polycrystalline Structures

    Directory of Open Access Journals (Sweden)

    E. Gaubas

    2013-01-01

    Full Text Available Properties of polycrystalline CdS layers, employed in formation of the CdS-Cu2S heterostructures, have been studied by combining contactless techniques of the time and spectrally resolved photoluminescence (TR-PL spectroscopy and microwave-probed photoconductivity (MW-PC transients. The confocal microscopy has been employed to correlate the homogeneity of photoluminescence and grain size in CdS layers. Three types of samples with crystallite grain size of <1 μm (the I-type and of 2–10 μm of homogeneous (II-type and inhomogeneous (III-type grain distribution have been separated. The simultaneous record of MW-PC and TR-PL responses ensures the same sampling area on the layer under investigation, as both (MW-PC and TR-PL signals are generated by the same UV laser excitation beam. Two PL bands peaked at 500 and 700 nm were revealed. It has been demonstrated that photoluminescence intensity strongly depends on the properties of the polycrystalline 15–26 μm thick CdS layers with equilibrium carrier density of about 1.5×1013 cm−3, which serve as the substrates to form CdS-Cu2S junctions. The different carrier decay components were ascribed to different microareas with characteristic MW-PC and PL decay lifetimes of 2–10 ns, ascribed to microcrystallites with PL instantaneous decay lifetimes of 40–200 ns, and MW-PC decay lifetimes in the range of 100–1000 μs attributed to the inter-crystallite areas of CdS polycrystalline material.

  3. Polycrystalline gamma plutonium's elastic moduli versus temperature

    Energy Technology Data Exchange (ETDEWEB)

    Migliori, Albert [Los Alamos National Laboratory; Betts, J [Los Alamos National Laboratory; Trugman, A [Los Alamos National Laboratory; Mielke, C H [Los Alamos National Laboratory; Mitchell, J N [Los Alamos National Laboratory; Ramos, M [Los Alamos National Laboratory; Stroe, I [WORCESTER POLYTECHNIC INSTITUTE

    2009-01-01

    Resonant ultrasound spectroscopy was used to measure the elastic properties of pure polycrystalline {sup 239}Pu in the {gamma} phase. Shear and longitudinal elastic moduli were measured simultaneously and the bulk modulus was computed from them. A smooth, linear, and large decrease of all elastic moduli with increasing temperature was observed. They calculated the Poisson ratio and found that it increases from 0.242 at 519 K to 0.252 at 571 K. These measurements on extremely well characterized pure Pu are in agreement with other reported results where overlap occurs.

  4. Valley Filtering and Electronic Optics Using Polycrystalline Graphene

    Science.gov (United States)

    Nguyen, V. Hung; Dechamps, S.; Dollfus, P.; Charlier, J.-C.

    2016-12-01

    In this Letter, both the manipulation of valley-polarized currents and the optical-like behaviors of Dirac fermions are theoretically explored in polycrystalline graphene. When strain is applied, the misorientation between two graphene domains separated by a grain boundary can result in a mismatch of their electronic structures. Such a discrepancy manifests itself in a strong breaking of the inversion symmetry, leading to perfect valley polarization in a wide range of transmission directions. In addition, these graphene domains act as different media for electron waves, offering the possibility to modulate and obtain negative refraction indexes.

  5. Laser annealing of thin film polycrystalline silicon solar cell

    Directory of Open Access Journals (Sweden)

    Chowdhury A.

    2013-11-01

    Full Text Available Performances of thin film polycrystalline silicon solar cell grown on glass substrate, using solid phase crystallization of amorphous silicon can be limited by low dopant activation and high density of defects. Here, we investigate line shaped laser induced thermal annealing to passivate some of these defects in the sub-melt regime. Effect of laser power and scan speed on the open circuit voltage of the polysilicon solar cells is reported. The processing temperature was measured by thermal imaging camera. Enhancement of the open circuit voltage as high as 210% is achieved using this method. The results are discussed.

  6. An acoustic emission study of plastic deformation in polycrystalline aluminium

    Science.gov (United States)

    Bill, R. C.; Frederick, J. R.; Felbeck, D. K.

    1979-01-01

    Acoustic emission experiments were performed on polycrystalline and single crystal 99.99% aluminum while undergoing tensile deformation. It was found that acoustic emission counts as a function of grain size showed a maximum value at a particular grain size. Furthermore, the slip area associated with this particular grain size corresponded to the threshold level of detectability of single dislocation slip events. The rate of decline in acoustic emission activity as grain size is increased beyond the peak value suggests that grain boundary associated dislocation sources are giving rise to the bulk of the detected acoustic emissions.

  7. Progress and issues in polycrystalline thin-film PV technologies

    Energy Technology Data Exchange (ETDEWEB)

    Zweibel, K.; Ullal, H.S.; Roedern, B. von [National Renewable Energy Lab., Golden, CO (United States)

    1996-05-01

    Substantial progress has occurred in polycrystalline thin-film photovoltaic technologies in the past 18 months. However, the transition to first-time manufacturing is still under way, and technical problems continue. This paper focuses on the promise and the problems of the copper indium diselenide and cadmium telluride technologies, with an emphasis on continued R&D needs for the near-term transition to manufacturing and for next-generation improvements. In addition, it highlights the joint R&D efforts being performed in the U.S. Department of Energy/National Renewable Energy Laboratory Thin-Film Photovoltaic Partnership Program.

  8. PDC (polycrystalline diamond compact) bit research at Sandia National Laboratories

    Energy Technology Data Exchange (ETDEWEB)

    Finger, J.T.; Glowka, D.A.

    1989-06-01

    From the beginning of the geothermal development program, Sandia has performed and supported research into polycrystalline diamond compact (PDC) bits. These bits are attractive because they are intrinsically efficient in their cutting action (shearing, rather than crushing) and they have no moving parts (eliminating the problems of high-temperature lubricants, bearings, and seals.) This report is a summary description of the analytical and experimental work done by Sandia and our contractors. It describes analysis and laboratory tests of individual cutters and complete bits, as well as full-scale field tests of prototype and commercial bits. The report includes a bibliography of documents giving more detailed information on these topics. 26 refs.

  9. IR and UV irradiations on ion bombarded polycrystalline silver

    Energy Technology Data Exchange (ETDEWEB)

    Latif, Anwar, E-mail: anwarlatif@uet.edu.p [Department of Physics, University of Engineering and Technology, Lahore 54890 (Pakistan); Khaleeq-ur-Rahman, M.; Bhatti, K.A.; Rafique, M.S.; Rizvi, Z.H. [Department of Physics, University of Engineering and Technology, Lahore 54890 (Pakistan)

    2010-10-15

    Ion bombarded polycrystalline fine polished silver surfaces are exposed to Nd:YAG (1064 nm, 10 mJ, 12 ns) and KrF excimer (248 nm, 57 mJ, 20 ns) lasers to examine structural and morphological changes employing X-ray diffractometry and optical microscopy, respectively. Irradiation causes considerable changes in grain sizes. Hydrodynamic sputtering is found to be dominant in heat affected zones (HAZs). Craters with irregular boundary and non-uniform thermal conduction are resulted on laser ablated surfaces of ion bombarded specimens. No disturbance takes place in the d-spacing of the planes of irradiated samples.

  10. Remobilization in the cratonic lithosphere recorded in polycrystalline diamond

    Science.gov (United States)

    Jacob; Viljoen; Grassineau; Jagoutz

    2000-08-18

    Polycrystalline diamonds (framesites) from the Venetia kimberlite in South Africa contain silicate minerals whose isotopic and trace element characteristics document remobilization of older carbon and silicate components to form the framesites shortly before kimberlite eruption. Chemical variations within the garnets correlate with carbon isotopes in the diamonds, indicating contemporaneous formation. Trace element, radiogenic, and stable isotope variations can be explained by the interaction of eclogites with a carbonatitic melt, derived by remobilization of material that had been stored for a considerable time in the lithosphere. These results indicate more recent formation of diamonds from older materials within the cratonic lithosphere.

  11. Low temperature production of large-grain polycrystalline semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    Naseem, Hameed A. (Fayetteville, AR); Albarghouti, Marwan (Loudonville, NY)

    2007-04-10

    An oxide or nitride layer is provided on an amorphous semiconductor layer prior to performing metal-induced crystallization of the semiconductor layer. The oxide or nitride layer facilitates conversion of the amorphous material into large grain polycrystalline material. Hence, a native silicon dioxide layer provided on hydrogenated amorphous silicon (a-Si:H), followed by deposited Al permits induced crystallization at temperatures far below the solid phase crystallization temperature of a-Si. Solar cells and thin film transistors can be prepared using this method.

  12. Activation Energy of Polycrystalline Silicon Thin Film Transistor

    Directory of Open Access Journals (Sweden)

    B.P. Tyagi

    2011-01-01

    Full Text Available The activation energy of a poly-Si thin film transistor is observed to be influenced by the grain size, trap state density and the inversion layer thickness. The present study aims to investigate these parameters theoretically so as to explore optimum conditions for the working of a polycrystalline silicon thin film transistor. Our computations have revealed that the activation energy decreases with the increase of gate bias for all values of grain size, trap states density and the inversion layer thickness. These findings are compared with the experimental results.

  13. Rotary Ultrasonic Machining of Poly-Crystalline Cubic Boron Nitride

    Directory of Open Access Journals (Sweden)

    Kuruc Marcel

    2014-12-01

    Full Text Available Poly-crystalline cubic boron nitride (PCBN is one of the hardest material. Generally, so hard materials could not be machined by conventional machining methods. Therefore, for this purpose, advanced machining methods have been designed. Rotary ultrasonic machining (RUM is included among them. RUM is based on abrasive removing mechanism of ultrasonic vibrating diamond particles, which are bonded on active part of rotating tool. It is suitable especially for machining hard and brittle materials (such as glass and ceramics. This contribution investigates this advanced machining method during machining of PCBN.

  14. Emission of nuclear quadrupole resonance from polycrystalline hexamethylenetetramine.

    Science.gov (United States)

    Ota, G; Itozaki, H

    2008-03-01

    The angular dependence of the nuclear quadrupole resonance (NQR) signal intensity emitted from polycrystalline hexamethylenetetramine has been analytically investigated for all directions for non-contact detection of chemicals by nuclear quadrupole resonance. The field pattern of the NQR signal from a column sample was measured. The emitted patterns were the same as that from a united single magnetic dipole, which fitted well to the estimation based on quadrupole principle axis system. This result is helpful to design an antenna for NQR remote detection.

  15. Complex strain paths in polycrystalline copper: microstructural aspects

    Directory of Open Access Journals (Sweden)

    M.F. Vieira

    1999-07-01

    Full Text Available Microstructural aspects of polycrystalline copper sheets subjected to complex strain paths were analysed in this work. Dislocation structures developed during the strain paths (rolling and tension and the evolution of this microstructure during reloading have been studied. The active slip systems developed in each strain path were used to explain the microstructural evolution. The heterogeneous surface deformation observed on polished tensile specimens prestrained in rolling was also analysed. The structural aspects are related with the mechanical behaviour of the material, namely with the increase in yield stress in reloading, the work hardening evolution and the premature occurrence of plastic instability for some prestrain values.

  16. Kinetical study about the cobalt electrodeposition onto polycrystalline platinum

    Directory of Open Access Journals (Sweden)

    Clara Hilda Rios-Reyes

    2013-01-01

    Full Text Available An electrochemical study of Co electrodeposition onto polycrystalline Pt from an aqueous solution containing 10-2 M CoCl2 + 1 M NH4CI (pH = 9.3 was conducted at overpotential conditions. The current density transients showed two maxima that corresponded to two nucleation and growth processes. The entire transient behavior was adequately predicted considering the contribution to the total current of four different processes: a Langmuir-type adsorption process, a diffusion-controlled two-dimensional instantaneous nucleation, and two three-dimensional nucleation and growth processes.

  17. Prediction of Part Distortion in Die Casting

    Energy Technology Data Exchange (ETDEWEB)

    R. Allen Miller

    2005-03-30

    The die casting process is one of the net shape manufacturing techniques and is widely used to produce high production castings with tight tolerances for many industries. An understanding of the stress distribution and the deformation pattern of parts produced by die casting will result in less deviation from the part design specification, a better die design and eventually more productivity and cost savings. This report presents methods that can be used to simulate the die casting process in order to predict the deformation and stresses in the produced part and assesses the degree to which distortion modeling is practical for die casting at the current time. A coupled thermal-mechanical finite elements model was used to simulate the die casting process. The simulation models the effect of thermal and mechanical interaction between the casting and the die. It also includes the temperature dependant material properties of the casting. Based on a designed experiment, a sensitivity analysis was conducted on the model to investigate the effect of key factors. These factors include the casting material model, material properties and thermal interaction between casting and dies. To verify the casting distortion predictions, it was compared against the measured dimensions of produced parts. The comparison included dimensions along and across the parting plane and the flatness of one surface.

  18. Process development of thin strip steel casting

    Energy Technology Data Exchange (ETDEWEB)

    Sussman, R.C.; Williams, R.S.

    1990-12-01

    An important new frontier is being opened in steel processing with the emergence of thin strip casting. Casting steel directly to thin strip has enormous benefits in energy savings by potentially eliminating the need for hot reduction in a hot strip mill. This has been the driving force for numerous current research efforts into the direct strip casting of steel. The US Department of Energy initiated a program to evaluate the development of thin strip casting in the steel industry. In earlier phases of this program, planar flow casting on an experimental caster was studied by a team of engineers from Westinghouse Electric corporation and Armco Inc. A subsequent research program was designed as a fundamental and developmental study of both planar and melt overflow casting processes. This study was arranged as several separate and distinct tasks which were often completed by different teams of researchers. An early task was to design and build a water model to study fluid flow through different designs of planar flow casting nozzles. Another important task was mathematically modeling of melt overflow casting process. A mathematical solidification model for the formation of the strip in the melt overflow process was written. A study of the material and conditioning of casting substrates was made on the small wheel caster using the melt overflow casting process. This report discusses work on the development of thin steel casting.

  19. Continuous squeeze casting process by mass production

    Institute of Scientific and Technical Information of China (English)

    Yun Xia; Rich Jacques

    2006-01-01

    Squeeze casting has become the most competitive casting process in the automotive industry because of its many advantages over high pressure die casting (HPDC). Many squeeze casting R & D and small amount volume making have been implemented around the world, but the mass production control still exists problem. SPX Contech squeeze casting process P2000 successfully achieved the goal of mass production; it includes lower metal turbulence, less gas entrapment, minimum volumetric shrinkage, and thus less porosity. Like other casting processes, however, the quality of squeeze castings is still sensitive to process control and gate and runner design. Casting defects can form in both die-filling and metal solidification phases. The occurrence of casting defects is directly attributed to improper adjustment or lack of control of process parameters including metal filling velocity, temperature, dwell time, cooling pattern, casting design, and etc. This paper presents examples using P2000 techniques to improve part quality in the following areas: runner & gate design, casting & runner layout in the die, squeeze pin application, high thermal conductivityinserts, cooling/heating systems, spray & lubricant techniques,and part stress calculation from shrinkage or displacement prediction after stress relief.

  20. Process development of thin strip steel casting

    Energy Technology Data Exchange (ETDEWEB)

    Sussman, R.C.; Williams, R.S.

    1990-12-01

    An important new frontier is being opened in steel processing with the emergence of thin strip casting. Casting steel directly to thin strip has enormous benefits in energy savings by potentially eliminating the need for hot reduction in a hot strip mill. This has been the driving force for numerous current research efforts into the direct strip casting of steel. The US Department of Energy initiated a program to evaluate the development of thin strip casting in the steel industry. In earlier phases of this program, planar flow casting on an experimental caster was studied by a team of engineers from Westinghouse Electric corporation and Armco Inc. A subsequent research program was designed as a fundamental and developmental study of both planar and melt overflow casting processes. This study was arranged as several separate and distinct tasks which were often completed by different teams of researchers. An early task was to design and build a water model to study fluid flow through different designs of planar flow casting nozzles. Another important task was mathematically modeling of melt overflow casting process. A mathematical solidification model for the formation of the strip in the melt overflow process was written. A study of the material and conditioning of casting substrates was made on the small wheel caster using the melt overflow casting process. This report discusses work on the development of thin steel casting.

  1. Simulating a high pressure die casting

    Energy Technology Data Exchange (ETDEWEB)

    Goldak, J.; Zhou, J.; Downey, D.; Aldea, V.; Li, G.; Mocanita, M. [Carleton Univ., Ottawa, Ontario (Canada)

    2000-07-01

    High pressure die casting is simulated for parts with complex geometry such as a large automotive transmission case. The closed die is filled in approximately 40 ms, the casting cools in the closed die for approximately 40s, to open the die, eject the casting and spray the die cavity surface requires another 40s. This 3D cyclic process is simulated using the following coupled composite solvers: the energy equation in the die and in the casting with solidification; filling of the casting by a droplet or a Navier-Stokes solver, and thermal stress analysis of the casting machine, casting and die during the cycle. This thermal analysis can be done for both starting and stopping transients and for the cyclic steady state. The software enables this analysis to be done almost automatically by designers. (author)

  2. Ultra-high vacuum compatible induction-heated rod casting furnace

    CERN Document Server

    Bauer, Andreas; Münzer, Wolfgang; Regnat, Alexander; Benka, Georg; Meven, Martin; Pedersen, Björn; Pfleiderer, Christian

    2016-01-01

    We report the design of a radio-frequency induction-heated rod casting furnace that permits the preparation of polycrystalline ingots of intermetallic compounds under ultra-high vacuum compatible conditions. The central part of the system is a bespoke water-cooled Hukin crucible supporting a casting mold. Depending on the choice of mold, typical rods have a diameter between 6 mm and 10 mm and a length up to 90 mm, suitable for single-crystal growth by means of float-zoning. The setup is all-metal sealed and may be baked out. We find that the resulting ultra-high vacuum represents an important precondition for processing compounds with high vapor pressures under a high-purity argon atmosphere up to 3 bar. Using the rod casting furnace, we succeeded to prepare large high-quality single crystals of two half-Heusler compounds, namely the itinerant antiferromagnet CuMnSb and the half-metallic ferromagnet NiMnSb.

  3. Inner surface roughness of complete cast crowns made by centrifugal casting machines.

    Science.gov (United States)

    Ogura, H; Raptis, C N; Asgar, K

    1981-05-01

    Six variables that could affect the surface roughness of a casting were investigated. The variables were (1) type of alloy, (2) mold temperature, (3) metal casting temperature, (4) casting machine, (5) sandblasting, and (6) location of each section. It was determined that the training portion of a complete cast crown had rougher surfaces than the leading portion. Higher mold and casting temperatures produced rougher castings, and this effect was more pronounced in the case of the base metal alloy. Sandblasting reduced the roughness, but produced scratched surfaces. Sandblasting had a more pronounced affect on the surface roughness of the base metal alloy cast either at a higher mold temperature or metal casting temperature. The morphology and the roughness profile of the original cast surface differed considerably with the type of alloy used.

  4. Thermal conductivity of MoS2 polycrystalline nanomembranes

    Science.gov (United States)

    Sledzinska, M.; Graczykowski, B.; Placidi, M.; Saleta Reig, D.; El Sachat, A.; Reparaz, J. S.; Alzina, F.; Mortazavi, B.; Quey, R.; Colombo, L.; Roche, S.; Sotomayor Torres, C. M.

    2016-09-01

    Heat conduction in 2D materials can be effectively engineered by means of controlling nanoscale grain structure. A favorable thermal performance makes these structures excellent candidates for integrated heat management units. Here we show combined experimental and theoretical studies for MoS2 nanosheets in a nanoscale grain-size limit. We report thermal conductivity measurements on 5 nm thick polycrystalline MoS2 by means of 2-laser Raman thermometry. The free-standing, drum-like MoS2 nanomembranes were fabricated using a novel polymer- and residue-free, wet transfer, in which we took advantage of the difference in the surface energies between MoS2 and the growth substrate to transfer the CVD-grown nanosheets. The measurements revealed a strong reduction in the in-plane thermal conductivity down to about 0.73 ± 0.25 {{{W}}{{m}}}-1 {{{K}}}-1. The results are discussed theoretically using finite elements method simulations for a polycrystalline film, and a scaling trend of the thermally conductivity with grain size is proposed.

  5. Lattice Boltzmann models for the grain growth in polycrystalline systems

    Directory of Open Access Journals (Sweden)

    Yonggang Zheng

    2016-08-01

    Full Text Available In the present work, lattice Boltzmann models are proposed for the computer simulation of normal grain growth in two-dimensional systems with/without immobile dispersed second-phase particles and involving the temperature gradient effect. These models are demonstrated theoretically to be equivalent to the phase field models based on the multiscale expansion. Simulation results of several representative examples show that the proposed models can effectively and accurately simulate the grain growth in various single- and two-phase systems. It is found that the grain growth in single-phase polycrystalline materials follows the power-law kinetics and the immobile second-phase particles can inhibit the grain growth in two-phase systems. It is further demonstrated that the grain growth can be tuned by the second-phase particles and the introduction of temperature gradient is also an effective way for the fabrication of polycrystalline materials with grained gradient microstructures. The proposed models are useful for the numerical design of the microstructure of materials and provide effective tools to guide the experiments. Moreover, these models can be easily extended to simulate two- and three-dimensional grain growth with considering the mobile second-phase particles, transient heat transfer, melt convection, etc.

  6. GaAs Photovoltaics on Polycrystalline Ge Substrates

    Science.gov (United States)

    Wilt, David M.; Pal, AnnaMaria T.; McNatt, Jeremiah S.; Wolford, David S.; Landis, Geoffrey A.; Smith, Mark A.; Scheiman, David; Jenkins, Phillip P.; McElroy Bruce

    2007-01-01

    High efficiency III-V multijunction solar cells deposited on metal foil or even polymer substrates can provide tremendous advantages in mass and stowage, particularly for planetary missions. As a first step towards that goal, poly-crystalline p/i/n GaAs solar cells are under development on polycrystalline Ge substrates. Organo Metallic Vapor Phase Epitaxy (OMVPE) parameters for pre-growth bake, nucleation and deposition have been examined. Single junction p/i/n GaAs photovoltaic devices, incorporating InGaP front and back window layers, have been grown and processed. Device performance has shown a dependence upon the thickness of a GaAs buffer layer deposited between the Ge substrate and the active device structure. A thick (2 m) GaAs buffer provides for both increased average device performance as well as reduced sensitivity to variations in grain size and orientation. Illumination under IR light (lambda > 1 micron), the cells showed a Voc, demonstrating the presence of an unintended photoactive junction at the GaAs/Ge interface. The presence of this junction limited the efficiency to approx.13% (estimated with an anti-refection coating) due to the current mismatch and lack of tunnel junction interconnect.

  7. Influence of copper foil polycrystalline structure on graphene anisotropic etching

    Science.gov (United States)

    Sharma, Kamal P.; Mahyavanshi, Rakesh D.; Kalita, Golap; Tanemura, Masaki

    2017-01-01

    Anisotropic etching of graphene and other two dimensional materials is an important tool to understand the growth process as well as enabling fabrication of various well-defined structures. Here, we reveal the influence of copper foil polycrystalline structure on anisotropic etching process of as-synthesized graphene. Graphene crystals were synthesized on the polycrystalline Cu foil by a low-pressure chemical vapor deposition (LPCVD) system. Microscopic analysis shows difference in shape, size and stripes alignment of graphene crystals with dissimilar nucleation within closure vicinity of neighboring Cu grains. Post-growth etching of such graphene crystals also significantly affected by the crystallographic nature of Cu grains as observed by the field emission scanning electron microscope (FE-SEM) and electron back scattered diffraction (EBSD) analysis. Hexagonal hole formation with anisotropic etching is observed to be independent of the stripes and wrinkles in the synthesized graphene. We also observed variation in etched pattern of the graphene depending on the base Cu grain orientations, attributing to difference in nucleation and growth process. The findings can facilitate to understand the nature of microscopic etched pattern depending on metal catalyst crystallographic structure.

  8. Automated indexing of Laue images from polycrystalline materials

    Energy Technology Data Exchange (ETDEWEB)

    Chung, J.S.; Ice, G.E. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

    1998-12-31

    Third generation hard x-ray synchrotron sources and new x-ray optics have revolutionized x-ray microbeams. Now intense sub-micron x-ray beams are routinely available for x-ray diffraction measurement. An important application of sub-micron x-ray beams is analyzing polycrystalline material by measuring the diffraction of individual grains. For these measurements, conventional analysis methods will not work. The most suitable method for microdiffraction on polycrystalline samples is taking broad-bandpass or white-beam Laue images. With this method, the crystal orientation and non-isostatic strain can be measured rapidly without rotation of sample or detector. The essential step is indexing the reflections from more than one grain. An algorithm has recently been developed to index broad bandpass Laue images from multi-grain samples. For a single grain, a unique set of indices is found by comparing measured angles between Laue reflections and angles between possible indices derived from the x-ray energy bandpass and the scattering angle 2 theta. This method has been extended to multigrain diffraction by successively indexing points not recognized in preceding indexing iterations. This automated indexing method can be used in a wide range of applications.

  9. Creep and stress relaxation modeling of polycrystalline ceramic fibers

    Science.gov (United States)

    Dicarlo, James A.; Morscher, Gregory N.

    1994-01-01

    A variety of high performance polycrystalline ceramic fibers are currently being considered as reinforcement for high temperature ceramic matrix composites. However, under mechanical loading about 800 C, these fibers display creep related instabilities which can result in detrimental changes in composite dimensions, strength, and internal stress distributions. As a first step toward understanding these effects, this study examines the validity of a mechanism-based empirical model which describes primary stage tensile creep and stress relaxation of polycrystalline ceramic fibers as independent functions of time, temperature, and applied stress or strain. To verify these functional dependencies, a simple bend test is used to measure stress relaxation for four types of commercial ceramic fibers for which direct tensile creep data are available. These fibers include both nonoxide (SCS-6, Nicalon) and oxide (PRD-166, FP) compositions. The results of the Bend Stress Relaxation (BSR) test not only confirm the stress, time, and temperature dependencies predicted by the model, but also allow measurement of model empirical parameters for the four fiber types. In addition, comparison of model tensile creep predictions based on the BSR test results with the literature data show good agreement, supporting both the predictive capability of the model and the use of the BSR text as a simple method for parameter determination for other fibers.

  10. Penetration and lateral diffusion characteristics of polycrystalline graphene barriers

    Science.gov (United States)

    Yoon, Taeshik; Mun, Jeong Hun; Cho, Byung Jin; Kim, Taek-Soo

    2013-12-01

    We report penetration and lateral diffusion behavior of environmental molecules on synthesized polycrystalline graphene. Penetration occurs through graphene grain boundaries resulting in local oxidation. However, when the penetrated molecules diffuse laterally, the oxidation region will expand. Therefore, we measured the lateral diffusion rate along the graphene-copper interface for the first time by the environment-assisted crack growth test. It is clearly shown that the lateral diffusion is suppressed due to the high van der Waals interaction. Finally, we employed bilayer graphene for a perfect diffusion barrier facilitated by decreased defect density and increased lateral diffusion path.We report penetration and lateral diffusion behavior of environmental molecules on synthesized polycrystalline graphene. Penetration occurs through graphene grain boundaries resulting in local oxidation. However, when the penetrated molecules diffuse laterally, the oxidation region will expand. Therefore, we measured the lateral diffusion rate along the graphene-copper interface for the first time by the environment-assisted crack growth test. It is clearly shown that the lateral diffusion is suppressed due to the high van der Waals interaction. Finally, we employed bilayer graphene for a perfect diffusion barrier facilitated by decreased defect density and increased lateral diffusion path. Electronic supplementary information (ESI) available. See DOI: 10.1039/c3nr03849a

  11. Lattice Boltzmann models for the grain growth in polycrystalline systems

    Science.gov (United States)

    Zheng, Yonggang; Chen, Cen; Ye, Hongfei; Zhang, Hongwu

    2016-08-01

    In the present work, lattice Boltzmann models are proposed for the computer simulation of normal grain growth in two-dimensional systems with/without immobile dispersed second-phase particles and involving the temperature gradient effect. These models are demonstrated theoretically to be equivalent to the phase field models based on the multiscale expansion. Simulation results of several representative examples show that the proposed models can effectively and accurately simulate the grain growth in various single- and two-phase systems. It is found that the grain growth in single-phase polycrystalline materials follows the power-law kinetics and the immobile second-phase particles can inhibit the grain growth in two-phase systems. It is further demonstrated that the grain growth can be tuned by the second-phase particles and the introduction of temperature gradient is also an effective way for the fabrication of polycrystalline materials with grained gradient microstructures. The proposed models are useful for the numerical design of the microstructure of materials and provide effective tools to guide the experiments. Moreover, these models can be easily extended to simulate two- and three-dimensional grain growth with considering the mobile second-phase particles, transient heat transfer, melt convection, etc.

  12. Hydrogen interactions with polycrystalline and with deposited titanium surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Azoulay, A. [Ben-Gurion Univ. of the Negev, Beersheba (Israel); Shamir, N. [Nuclear Research Center-Negev, PO Box 9001, Beer Sheva (Israel); Fromm, E. [Max-Planck Institute fuer Metallforschung, Stuttgart (Germany); Szokefalvi-Nagy, A. [Max-Planck Institute fuer Metallforschung, Stuttgart (Germany); Mintz, M.H. [Ben-Gurion Univ. of the Negev, Beersheba (Israel)]|[Nuclear Research Center-Negev, PO Box 9001, Beer Sheva (Israel)

    1997-02-15

    The room temperature kinetics of hydrogen chemisorption and adsorption on polycrystalline and on deposited (sputter-deposited and evaporation-deposited) titanium surfaces were studied. Measurements of hydrogen surface accumulation were performed in a combined surface analyses system incorporating direct recoils spectrometry and Auger electron spectroscopy (AES). There, three different types of surface cleaning procedure were applied: heat-flashing, sputtering and sputter-deposition of titanium on a polycrystalline titanium substrate. The surface chemisorption kinetics obtained for the deposited samples were compared with the total kinetics of the gas phase consumption, performed in a volumetric Wagener system. From this comparison it was possible to distinguish between topmost surface chemisorption and subsurface (or bulk) absorption kinetics. It was concluded that, for all types of surface studied, hydrogen chemisorbed according to a Langmuir-type random two-sites chemisorption model, with high (close to unity) zero-coverage sticking probabilities. The only difference between these surfaces was in their roughness factors, which increased going from the heat-flashed, through the sputtered, to the deposited surfaces. Following the initial stage of a chemisorbed surface layer formation, constant-rate absorption of hydrogen proceeded over a very wide range of exposures (greater than 10{sup 4} Langmuirs). The accommodation probability of hydrogen during this linear stage was about 10{sup -2}. It is possible that this absorption process is controlled by the chemisorption of the H{sub 2} on the surface hydride phase, formed by the earlier hydrogen chemisorption. (orig.)

  13. Search for chameleons with CAST

    Directory of Open Access Journals (Sweden)

    V. Anastassopoulos

    2015-10-01

    Full Text Available In this work we present a search for (solar chameleons with the CERN Axion Solar Telescope (CAST. This novel experimental technique, in the field of dark energy research, exploits both the chameleon coupling to matter (βm and to photons (βγ via the Primakoff effect. By reducing the X-ray detection energy threshold used for axions from 1 keV to 400 eV CAST became sensitive to the converted solar chameleon spectrum which peaks around 600 eV. Even though we have not observed any excess above background, we can provide a 95% C.L. limit for the coupling strength of chameleons to photons of βγ≲1011 for 1<βm<106.

  14. Pressure rig for repetitive casting

    Science.gov (United States)

    Vasquez, Peter (Inventor); Hutto, William R. (Inventor); Philips, Albert R. (Inventor)

    1989-01-01

    The invention is a pressure rig for repetitive casting of metal. The pressure rig performs like a piston for feeding molten metal into a mold. Pressure is applied to an expandable rubber diaphragm which expands like a balloon to force the metal into the mold. A ceramic cavity which holds molten metal is lined with blanket-type insulating material, necessitating only a relining for subsequent use and eliminating the lengthy cavity preparation inherent in previous rigs. In addition, the expandable rubber diaphragm is protected by the insulating material thereby decreasing its vulnerability to heat damage. As a result of the improved design the life expectancy of the pressure rig contemplated by the present invention is more than doubled. Moreover, the improved heat protection has allowed the casting of brass and other alloys with higher melting temperatures than possible in the conventional pressure rigs.

  15. Innovative algorithm for cast detection

    Science.gov (United States)

    Gasparini, Francesca; Schettini, Raimondo; Gallina, Paolo

    2001-12-01

    The paper describes a method for detecting a color cast (i.e. a superimposed dominant color) in a digital image without any a priori knowledge of its semantic content. The color gamut of the image is first mapped in the CIELab color space. The color distribution of the whole image and of the so-called Near Neutral Objects (NNO) is then investigated using statistical tools then, to determine the presence of a cast. The boundaries of the near neutral objects in the color space are set adaptively by the algorithm on the basis of a preliminary analysis of the image color gamut. The method we propose has been tuned and successfully tested on a large data set of images, downloaded from personal web-pages or acquired using various digital and traditional cameras.

  16. Search for chameleons with CAST

    CERN Document Server

    Anastassopoulos, V; Aune, S; Barth, K; Belov, A; Bräuninger, H; Cantatore, G; Carmona, J M; Cetin, S A; Christensen, F; Collar, J I; Dafni, T; Davenport, M; Desch, K; Dermenev, A; Eleftheriadis, C; Fanourakis, G; Ferrer-Ribas, E; Friedrich, P; Galán, J; García, J A; Gardikiotis, A; Garza, J G; Gazis, E N; Geralis, T; Giomataris, I; Hailey, C; Haug, F; Hasinoff, M D; Hofmann, D H H; Iguaz, F J; Irastorza, I G; Jacoby, J; Jakobsen, A; Jakovčić, K; Kaminski, J; Karuza, M; Kavuk, M; Krčmar, M; Krieger, C; Krüger, A; Lakić, B; Laurent, J M; Liolios, A; Ljubičić, A; Luzón, G; Neff, S; Ortega, I; Papaevangelou, T; Pivovarov, M J; Raffelt, G; Riege, H; Rosu, M; Ruz, J; Savvidis, I; Solanki, S K; Vafeiadis, T; Villar, J A; Vogel, J K; Yildiz, S C; Zioutas, K; Brax, P; Lavrentyev, I; Upadhye, A

    2015-01-01

    In this work we present a search for (solar) chameleons with the CERN Axion Solar Telescope (CAST). This novel experimental technique, in the field of dark energy research, exploits both the chameleon coupling to matter ($\\beta_{\\rm m}$) and to photons ($\\beta_{\\gamma}$) via the Primakoff effect. By reducing the X-ray detection energy threshold used for axions from 1$\\,$keV to 400$\\,$eV CAST became sensitive to the converted solar chameleon spectrum which peaks around 600$\\,$eV. Even though we have not observed any excess above background, we can provide a 95% C.L. limit for the coupling strength of chameleons to photons of $\\beta_{\\gamma}\\!\\lesssim\\!10^{11}$ for $1<\\beta_{\\rm m}<10^6$.

  17. Rapid Cycle Casting of Steel

    Science.gov (United States)

    1981-07-01

    such as macrosegregation, hot tears, and blowholes are also difficult to control. Rheocasting l on the other hand, is a recent development which...viscosity. Advantages of the rheocasting process are: * Reduced attack of die or mold because of the reduced tempera- ture (by 1000 C for steel) and...4W W ’ V6W 4 1.2 THE SD PROCESS Many metals, including steel, can be cast at still lower tempera- soliifiction(2) tures than rheocasting by

  18. Effect of cast steel production metallurgy on the emergence of casting defects

    Directory of Open Access Journals (Sweden)

    L. Čamek

    2016-10-01

    Full Text Available The paper documents metallurgical possibilities of high alloy cast steel production in open induction medium frequency furnaces and an electric arc furnace in a gravity die casting foundry. The observation was focused on the emergence of gas defects in steel castings. The content of gases achieved during the metallurgical processes was evaluated for every unit of the production equipment and the casting ladle before casting into disposable sand moulds. The sand mould area was considered to be constant. The aim was to evaluate the current metallurgical possibilities of affecting the content of gases in high alloy cast steel in the current technical conditions of the foundry.

  19. Computer precision simulation for titanium casting centrifugal mold filling of prescision titanium castings

    Directory of Open Access Journals (Sweden)

    Daming XU

    2004-08-01

    Full Text Available Computer simulation codes were developed based on proposed mathematical model for centrifugal mold filling processes and previous computer software for 3D mold filling and solidification of castings. Sample simulations were implemented for mold filling processes of precision titanium castings under gravity and different centrifugal casting techniques. The computation results show that the alloy melt has a much stronger mold filling ability for thin section castings unde a centrifugal force field than that only under the gravity. A "return back" mold filling manner is showed to be a reasonable technique for centrifugal casting processes, especially for thin section prcision castings.

  20. Delaunay-Network Modelling of Creep Failure in Regular Polycrystalline Aggregates by Grain Boundary Cavitation

    NARCIS (Netherlands)

    Burg, M.W.D. van der; Giessen, E. van der

    1994-01-01

    In polycrystalline materials at elevated temperatures subjected to stationary loading, creep fracture occurs as a result of failure mechanisms on the size scale of grains, namely the nucleation and diffusive growth of cavities until coalescence leads to microcracks. In this paper, a polycrystalline

  1. Polycrystalline SiC as source material for the growth of fluorescent SiC layers

    DEFF Research Database (Denmark)

    Kaiser, M.; Hupfer, T.; Jokubavicus, V.;

    2013-01-01

    Polycrystalline doped SiC act as source for fluorescent SiC. We have studied the growth of individual grains with different polytypes in the source material. We show an evolution and orientation of grains of different polytypes in polycrystalline SiC ingots grown by the Physical Vapor Transport...

  2. Electromechanical Response of Polycrystalline Barium Titanate Resolved at the Grain Scale

    DEFF Research Database (Denmark)

    Majkut, Marta; Daniels, John E.; Wright, Jonathan P.

    2017-01-01

    critical for understanding bulk polycrystalline ferroic behavior. Here, three-dimensional X-ray diffraction is used to reconstruct a 3D grain map (grain orientations and neighborhoods) of a polycrystalline barium titanate sample and track the grain-scale non-180° ferroelectric domain switching strains...

  3. Experimental Investigation of Polycrystalline Material Deformation Based on a Grain Scale

    Institute of Scientific and Technical Information of China (English)

    LI Xi-De; YANG Yan; WEI Cheng

    2005-01-01

    @@ We propose an experimental approach for investigation of the polycrystalline deformation behaviour at a grain scale. The technique is characterized by the joint application of micro material testing systems and the intragranular deformation analysis methods. It is attempting to map the deformation evolution at grain scale during the elastic and plastic deformations of polycrystalline specimens.

  4. High-Performance Deep SubMicron CMOS Technologies with Polycrystalline-SiGe Gates

    NARCIS (Netherlands)

    Ponomarev, Youri V.; Stolk, Peter A.; Salm, Cora; Schmitz, Jurriaan; Woerlee, P.H.

    2000-01-01

    The use of polycrystalline SiGe as the gate material for deep submicron CMOS has been investigated. A complete compatibility to standard CMOS processing is demonstrated when polycrystalline Si is substituted with SiGe (for Ge fractions below 0.5) to form the gate electrode of the transistors. Perfor

  5. High-Performance Deep SubMicron CMOS Technologies with Polycrystalline-SiGe Gates

    NARCIS (Netherlands)

    Ponomarev, Youri V.; Stolk, Peter A.; Salm, Cora; Schmitz, Jurriaan; Woerlee, P.H.

    2000-01-01

    The use of polycrystalline SiGe as the gate material for deep submicron CMOS has been investigated. A complete compatibility to standard CMOS processing is demonstrated when polycrystalline Si is substituted with SiGe (for Ge fractions below 0.5) to form the gate electrode of the transistors.

  6. A generalized inverse-pole-figure method to analyze domain switching in polycrystalline ferroelectrics

    Science.gov (United States)

    Ryo, Hyok-Su; Ryo, In-Gwang

    2016-08-01

    In this study, a generalized inverse-pole-figure (IPF) method has been suggested to analyze domain switching in polycrystalline ferroelectrics including composition of morphotropic phase boundary (MPB). Using the generalized IPF method, saturated domain orientation textures of single-phase polycrystalline ferroelectrics with tetragonal and rhombohedral symmetry have been analytically calculated and the results have been confirmed by comparison with the results from preceding studies. In addition, saturated domain orientation textures near MPBs of different multiple-phase polycrystalline ferroelectrics have been also analytically calculated. The results show that the generalized IPF method is an efficient method to analyze not only domain switching of single-phase polycrystalline ferroelectrics but also MPB of multiple-phase polycrystalline ferroelectrics.

  7. Mechanisms limiting the performance of large grain polycrystalline silicon solar cells

    Science.gov (United States)

    Culik, J. S.; Alexander, P.; Dumas, K. A.; Wohlgemuth, J. W.

    1984-01-01

    The open-circuit voltage and short-circuit current of large-grain (1 to 10 mm grain diameter) polycrystalline silicon solar cells is determined by the minority-carrier diffusion length within the bulk of the grains. This was demonstrated by irradiating polycrystalline and single-crystal (Czochralski) silicon solar cells with 1 MeV electrons to reduce their bulk lifetime. The variation of short-circuit current with minority-carrier diffusion length for the polycrystalline solar cells is identical to that of the single-crystal solar cells. The open-circuit voltage versus short-circuit current characteristic of the polycrystalline solar cells for reduced diffusion lengths is also identical to that of the single-crystal solar cells. The open-circuit voltage of the polycrystalline solar cells is a strong function of quasi-neutral (bulk) recombination, and is reduced only slightly, if at all, by grain-boundary recombination.

  8. [The cast structure after vacuum-pressure casting and centrifugal casting].

    Science.gov (United States)

    Finger, W; Jung, T; Quast, U

    1975-02-01

    Evaluation of polished sections revealed the following: 1. Grain size in marginal areas of the crown is, in general, smaller than it is in the occlusal region. 2. Grain size varies depending on the casting method applied. Differences in hardness were found only to a limited extent. They were not always in line with the grain structure. This phenomenon deviating from the rule cannot satisfactorily be explained. The piping distribution was in accordance with observations made so far.

  9. Micromechanical modelling of partially molten and sand reinforced polycrystalline ice

    Science.gov (United States)

    Castelnau, O.; Duval, P.

    2009-12-01

    The viscoplastic behaviour of polycrystalline ice is strongly affected by the very strong anisotropy of ice crystals. Indeed, in the dislocations creep regime relevant for ice sheet flow, dislocation glide on the basal plane of ice single crystals leads to strain-rates ~6 order of magnitude larger than strain-rates that might be obtain if only non-basal glide is activated. At the polycrystal scale, this behaviour is responsible for a strong mechanical interaction between grains in the secondary (stationary) creep regime, and strain-rate is essentially partitioned between soft grains well-oriented for basal glide and hard grains exhibiting an unfavourable orientation for basal slip. As a consequence, the macroscopic flow stress at the polycrystal scale essentially depends on the resistance of the hardest slip systems or on the associated accommodation processes such as climb of basal dislocation on non-basal planes. Creep experiments performed on polycrystalline ices containing a small amount (less than 10% volume fraction) of liquid water show a dramatic increase of strain-rate, by more than one order of magnitude, compared to solid ice when deformed under similar thermo-mechanical conditions. Similarly, a strong hardening is observed when polycrystalline ice is reinforced by sand (which can be considered as a rigid phase here). This behaviour can be explained by micromechanical models, which aims at estimating the mechanical interactions between grains. For example, the presence of water releases stress concentrations at grain boundaries and therefore favours the inactivation of non-basal systems. To estimate such effect and to reach quantitative comparison with experimental data, we make use of the recent Second-Order homogenization mean-field approach of Ponte-Castaneda, based on self-consistent scheme. The advantage of this approach, which has been shown to provide excellent results when applied to many different non-linear composite materials, comes from the

  10. Advanced casting technologies for lightweight automotive applications

    Directory of Open Access Journals (Sweden)

    Alan A. Luo

    2010-11-01

    Full Text Available This paper provides an overview of alloy and process developments in aluminum and magnesium castings for lightweight automotive applications. Wear-resistant aluminum alloys, creep-resistant and high strength/ductility magnesium alloys have been developed for automotive applications. On the process front, vacuum-assisted die casting and high vacuum die casting technologies have been developed for high-integrity body and chassis applications. Thin-wall and hollow casting components are being produced by low-pressure die casting processes for structural applications. Overcasting technology is gaining traction and has enabled mixed material designs for automotive sub-systems such as engine cradles and instrument panel beams. Simulation tools developed to predict the interfacial interactions of the dissimilar components and the structural integrity of the overcast systems are being validated in the casting trials.

  11. Chilling Tendency and Chill of Cast Iron

    Institute of Scientific and Technical Information of China (English)

    E. Fra(s); M. Górny; W. Kapturkiewicz; H. López

    2008-01-01

    An analytical expression is presented for the susceptibility of liquid cast iron to solidify according tothe Fe-C-X metastable system (also known as the chilling tendency of cast iron, CT). The analysis incorpo-rates the nucleation and growth processes associated with the eutectic transformation. The CT is related tothe physicochemical state of the liquid, the eutectic cells in the flake graphite, and the number of nodules innodular cast iron. In particular, the CT can be related to the critical wall thickness, Scr, or the chill width, Wcr,in wedge shaped castings. Finally, this work serves as a guide for understanding the effect of technical fac-tors such as the melt chemistry, the spheroidizing and inoculation practice, and the holding time and tam-perature on the resultant CT and chill of the cast iron. Theoretical calculations of Scr and Wcr compare wellwith experimental data for flake graphite and nodular cast iron.

  12. Clean Cast Steel Technology, Phase IV

    Energy Technology Data Exchange (ETDEWEB)

    Charles E. Bates

    2003-02-24

    The objective of the Clean Cast Steel Technology Program was to improve casting product quality by removing or minimizing oxide defects and to allow the production of higher integrity castings for high speed machining lines. Previous research has concentrated on macro-inclusions that break, chip, or crack machine tool cutters and drills and cause immediate shutdown of the machining lines. The overall goal of the project is to reduce the amount of surface macro-inclusions and improve the machinability of steel castings. Macro-inclusions and improve the machinability of steel castings. Macro-inclusions have been identified by industrial sponsors as a major barrier to improving the quality and marketability of steel castings.

  13. Gating of Permanent Molds for ALuminum Casting

    Energy Technology Data Exchange (ETDEWEB)

    David Schwam; John F. Wallace; Tom Engle; Qingming Chang

    2004-03-30

    This report summarizes a two-year project, DE-FC07-01ID13983 that concerns the gating of aluminum castings in permanent molds. The main goal of the project is to improve the quality of aluminum castings produced in permanent molds. The approach taken was determine how the vertical type gating systems used for permanent mold castings can be designed to fill the mold cavity with a minimum of damage to the quality of the resulting casting. It is evident that somewhat different systems are preferred for different shapes and sizes of aluminum castings. The main problems caused by improper gating are entrained aluminum oxide films and entrapped gas. The project highlights the characteristic features of gating systems used in permanent mold aluminum foundries and recommends gating procedures designed to avoid common defects. The study also provides direct evidence on the filling pattern and heat flow behavior in permanent mold castings.

  14. Homogenity of Die Casting and Returning Material

    Directory of Open Access Journals (Sweden)

    J. Malik

    2012-04-01

    Full Text Available Homogeneity of die castings is influenced by wide range of technological parameters as piston velocity in filling chamber of die casting machine, filling time of mould cavity, temperature of cast alloy, temperature of the mould, temperature of filling chamber, surface pressure on alloy during mould filling, final pressure and others. Based on stated parameters it is clear, that main parameters of die casting are filling time of die mould cavity and velocity of the melt in the ingates. Filling time must ensure the complete filling of the mould cavity before solidification process can negatively influence it. Among technological parameters also belong the returning material, which ratio in charge must be constrained according to requirement on final homogeneity of die castings. With the ratio of returning material influenced are the mechanical properties of castings, inner homogeneity and chemical composition.

  15. Method for casting thin metal objects

    Energy Technology Data Exchange (ETDEWEB)

    Pehrson, Brandon P; Moore, Alan F

    2015-04-14

    Provided herein are various embodiments of systems for casting thin metal plates and sheets. Typical embodiments include layers of mold cavities that are oriented vertically for casting the metal plates. In some embodiments, the mold cavities include a beveled edge such that the plates that are cast have a beveled edge. In some embodiments, the mold cavities are filled with a molten metal through an open horizontal edge of the cavity. In some embodiments, the mold cavities are filled through one or more vertical feed orifices. Further disclosed are methods for forming a thin cast metal plate or sheet where the thickness of the cast part is in a range from 0.005 inches to 0.2 inches, and the surface area of the cast part is in a range from 16 square inches to 144 square inches.

  16. Newly developed vacuum differential pressure casting of thin-walled complicated Al-alloy castings

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    The newly designed vacuum differential pressure casting (VDPC) unit was introduced, by which the capability of the VDPC process to produce thin-walled complicated Al-alloy castings, that are free from oxides, gas pore and shrinkage cavity and thus enhance overall part quality, was studied. Experimental results were compared with those of traditional gravity pouring and vacuum suction casting. The first series of experiments were focused on investigating the castability of thin section Al-alloy casting. In the second series of experiments the metallographic evidence, casting strength and soundness were examined. Finally, case studies of very interesting thin walled complicated casting applications were described. The advantages of the described technique have made possible to produce thin walled complicated Al-alloy casting (up to a section thickness of 1 mm), which is not practical for gravity pouring and vacuum suction casting.

  17. COOLING METHOD OF SILUMINA CASTINGS AK15M3 AT VERTICAL CENTRIFUGAL CASTING

    Directory of Open Access Journals (Sweden)

    V. Yu. Stecenko

    2013-01-01

    Full Text Available The way of cooling of castings from silumin AK15M3 is developed at the vertical centrifugal casting, enabling to receive bimetallic blanks with high-disperse eutectic and hypereutectic microstructures and minimal allowance for machining.

  18. Influence of Technological Parameters of Furane Mixtures on Shrinkage Creation in Ductile Cast Iron Castings

    Directory of Open Access Journals (Sweden)

    Vasková I.

    2014-10-01

    Full Text Available Ductile cast iron (GS has noticed great development in last decades and its boom has no analogue in history humankind. Ductile iron has broaden the use of castings from cast iron into areas, which where exclusively domains for steel castings. Mainly by castings, which weight is very high, is the propensity to shrinkage creation even higher. Shrinkage creation influences mainly material, construction of casting, gating system and mould. Therefore, the main realized experiment was to ascertain the influence of technological parameters of furane mixture on shrinkage creation in castings from ductile iron. Together was poured 12 testing items in 3 moulds forto determine and compare the impact of various technological parameters forms the propensity for shrinkage in the casting of LGG.

  19. RESEARCH AND APPLICATION OF AS-CAST WEAR RESISTANCE HIGH CHROMIUM CAST IRON

    Institute of Scientific and Technical Information of China (English)

    1998-01-01

    The influence of alloy elements, such as boron and silicon, on the microstructure and properties of as-cast high chromium cast iron is studied. The results show that boron and silicon have a great effect on the mechanical properties and the wear resistance. Through proper addition of boron and silicon, the properties of as-cast high chromium cast iron can be improved effectively. Through analyzing the distribution of elements by scanning electron microscope, it has been shown that the addition of boron and silicon lowers the mass fraction of chromium saturated in as-cast austenite, and makes it unstable and liable to be transformed into martensite. The as-cast high chromium cast iron with proper content of boron and silicon is suitable for the manufacture of lining for asphalt concrete mixer and its wear resistance is 14 times that of lining made of low alloy white cast iron.

  20. Thermal gradient analysis of solidifying casting

    Directory of Open Access Journals (Sweden)

    J. Suchoń

    2008-08-01

    Full Text Available For description of casting solidification and crystallization process the thermal derivative analysis (TDA is commonly used. Besides the process kinetics considered in TDA method to describe the solidification process, the thermal gradient analysis can be also used for this purpose [1, 2]. In conducted studies analysis of thermal gradient distribution inside the solidifying wedge casting was shown which enabled determination of heat flow intensity on casting section.

  1. Caste and wealth inequality in India

    OpenAIRE

    Zacharias, Ajit; Vakulabharanam, Vamsi

    2009-01-01

    In this paper, we conduct the novel exercise of analyzing the relationship between overall wealth inequality and caste divisions in India using nationally representative surveys on household wealth conducted during 1991–92 and 2002–03. According to our findings, the groups in India that are generally considered disadvantaged (known as Scheduled Castes or Scheduled Tribes) have, as one would expect, substantially lower wealth than the "forward" caste groups, while the Other Backward Classes an...

  2. Improved Foundry Castings Utilizing CAD/CAM

    Science.gov (United States)

    1981-10-01

    designed to simulate the heat transfer behavior during freezing and the subsequent cooling of an arbitrarily shaped 3D casting solidify- ing in a sand...variety of complex 2D and 3D geometries may be simulated by these routines. It is important, however, to be aware of the assumptions made in the design...three-dimensional with a sand mold surrounding a steel casting. The simulation program is desing - ed to simulate any shape. The shape of test casting

  3. Theory of uniqueness of Indian Caste System

    OpenAIRE

    Kumar, Ashwin

    2006-01-01

    Classical studies on pre-modern Indian social structure have suggested apparent differences between the Indian caste system and social stratification as one can discern in other parts of the world. However, one needs to question such dogmatic assertions that such vast differences really existed. An endeavor is made in this research paper to reflect on the nature of caste hierarchy in pre-modern India. The caste system forms the significant basis of pre-modern Indian social structure. Early wr...

  4. Maritime Cast Shop Integrated Improvement Plan

    Science.gov (United States)

    2010-08-20

    as well as the risers, sprues and runners that are cut off as scrap from the cast component. The post cast component clean up process should...include several steps  Revert from all sources, risers, sprues, runners and pigged material, must be weighed  The revert must be marked with alloy and...heat all surfaces of the mold to 250F. The higher interior temperature is advantageous in pouring castings with thin sections such as impeller blades

  5. Rapid recovery of polycrystalline silicon from kerf loss slurry using double-layer organic solvent sedimentation method

    Science.gov (United States)

    Xing, Peng-fei; Guo, Jing; Zhuang, Yan-xin; Li, Feng; Tu, Gan-feng

    2013-10-01

    The rapid development of photovoltaic (PV) industries has led to a shortage of silicon feedstock. However, more than 40% silicon goes into slurry wastes due to the kerf loss in the wafer slicing process. To effectively recycle polycrystalline silicon from the kerf loss slurry, an innovative double-layer organic solvent sedimentation process was presented in the paper. The sedimentation velocities of Si and SiC particles in some organic solvents were investigated. Considering the polarity, viscosity, and density of solvents, the chloroepoxy propane and carbon tetrachloride were selected to separate Si and SiC particles. It is found that Si and SiC particles in the slurry waste can be successfully separated by the double-layer organic solvent sedimentation method, which can greatly reduce the sedimentation time and improve the purity of obtained Si-rich and SiC-rich powders. The obtained Si-rich powders consist of 95.04% Si, and the cast Si ingot has 99.06% Si.

  6. Development and application of titanium alloy casting technology in China

    Institute of Scientific and Technical Information of China (English)

    NAN Hai; XIE Cheng-mu; ZHAO Jia-qi

    2005-01-01

    The development and research of titanium cast alloy and its casting technology, especially its application inaeronautical industry in China are presented. The technology of molding, melting and casting of titanium alloy, casting quality control are introduced. The existing problems and development trend in titanium alloy casting technology are also discussed.

  7. Bosonic Anomalies in Boron-Doped Polycrystalline Diamond

    Science.gov (United States)

    Zhang, Gufei; Samuely, Tomas; Kačmarčík, Jozef; Ekimov, Evgeny A.; Li, Jun; Vanacken, Johan; Szabó, Pavol; Huang, Junwei; Pereira, Paulo J.; Cerbu, Dorin; Moshchalkov, Victor V.

    2016-12-01

    Quantum confinement and coherence effects are considered the cause of many specific features for systems which are generally low dimensional, strongly disordered, and/or situated in the vicinity of the metal-insulator transition. Here, we report on the observation of anomalous resistance peak and specific heat peaks superimposed at the superconducting transition of heavily boron-doped polycrystalline bulk diamond, which is a three-dimensional system situated deep on the metallic side of the boron-doping-driven metal-insulator transition in diamond. The anomalous resistance peak and specific heat peaks are interpreted as a result of confinement and coherence effects in the presence of intrinsic and extrinsic granularity. Our data, obtained for superconducting diamond, provide a reference for understanding the superconductivity in other granular disordered systems. Furthermore, our study brings attention to the significant influence of granular disorder on the physical properties of boron-doped diamond, which is considered a promising candidate for electronics applications.

  8. Creep behavior for advanced polycrystalline SiC fibers

    Energy Technology Data Exchange (ETDEWEB)

    Youngblood, G.E.; Jones, R.H. [Pacific Northwest National Lab., Richland, WA (United States); Kohyama, Akira [Kyoto Univ. (Japan)] [and others

    1997-04-01

    A bend stress relaxation (BSR) test has been utilized to examine irradiation enhanced creep in polycrystalline SiC fibers which are under development for use as fiber reinforcement in SiC/SiC composite. Qualitative, S-shaped 1hr BSR curves were compared for three selected advanced SiC fiber types and standard Nicalon CG fiber. The temperature corresponding to the middle of the S-curve (where the BSR parameter m = 0.5) is a measure of a fiber`s thermal stability as well as it creep resistance. In order of decreasing thermal creep resistance, the measured transition temperatures were Nicalon S (1450{degrees}C), Sylramic (1420{degrees}C), Hi-Nicalon (1230{degrees}C) and Nicalon CG (1110{degrees}C).

  9. Grain boundaries in polycrystalline Si solar cells Impurities and passivation

    Science.gov (United States)

    Kazmerski, L. L.

    The interrelationships among the chemistry and composition of the intergrain regions, the electro-optical properties of the grain boundaries, and the resulting photovoltaic performance of polycrystalline Si solar cells are examined. Specifically, two impurity-related mechanisms are reported. The first is that of the segregation of oxygen to the grain boundaries during thermal processing of the material/devices. Direct evidence is presented that correlates this oxygen localization to the electrical activation of the grain boundaries. The second is the passivation of the grain boundaries by incorporation of hydrogen in these regions. The localization of hydrogen at the intergrain defects is shown by surface analysis methods, and the effects on the electrical characteristics of the grain boundary and the solar cells are reported.

  10. Anisotropic thermal conductivity of thin polycrystalline oxide samples

    Directory of Open Access Journals (Sweden)

    A. Tiwari

    2013-11-01

    Full Text Available This paper reports about the development of a modified laser-flash technique and relation to measure the in-plane thermal diffusivity of thin polycrystalline oxide samples. Thermal conductivity is then calculated with the product of diffusivity, specific heat and density. Design and operating features for evaluating in-plane thermal conductivities are described. The technique is advantageous as thin samples are not glued together to measure in-plane thermal conductivities like earlier methods reported in literature. The approach was employed to study anisotropic thermal conductivity in alumina sheet, textured kaolin ceramics and montmorillonite. Since it is rare to find in-plane thermal conductivity values for such anisotropic thin samples in literature, this technique offers a useful variant to existing techniques.

  11. Anisotropic thermal conductivity of thin polycrystalline oxide samples

    Energy Technology Data Exchange (ETDEWEB)

    Tiwari, A., E-mail: abhishektiwariiitr@gmail.com [Groupe d’Etudes des Matériaux Hétérogènes (GEMH, EA 3178), Ecole Nationale Supérieure de Céramique Industrielle, 12, Rue Atlantis, 87068 Limoges Cedex (France); Department of Mechanical and Aerospace Engineering, Monash University, Melbourne, VIC 3800 (Australia); Boussois, K.; Nait-Ali, B.; Smith, D. S.; Blanchart, P. [Groupe d’Etudes des Matériaux Hétérogènes (GEMH, EA 3178), Ecole Nationale Supérieure de Céramique Industrielle, 12, Rue Atlantis, 87068 Limoges Cedex (France)

    2013-11-15

    This paper reports about the development of a modified laser-flash technique and relation to measure the in-plane thermal diffusivity of thin polycrystalline oxide samples. Thermal conductivity is then calculated with the product of diffusivity, specific heat and density. Design and operating features for evaluating in-plane thermal conductivities are described. The technique is advantageous as thin samples are not glued together to measure in-plane thermal conductivities like earlier methods reported in literature. The approach was employed to study anisotropic thermal conductivity in alumina sheet, textured kaolin ceramics and montmorillonite. Since it is rare to find in-plane thermal conductivity values for such anisotropic thin samples in literature, this technique offers a useful variant to existing techniques.

  12. Resistive switching in polycrystalline YMnO3 thin films

    Directory of Open Access Journals (Sweden)

    A. Bogusz

    2014-10-01

    Full Text Available We report a unipolar, nonvolatile resistive switching in polycrystalline YMnO3 thin films grown by pulsed laser deposition and sandwiched between Au top and Ti/Pt bottom electrodes. The ratio of the resistance in the OFF and ON state is larger than 103. The observed phenomena can be attributed to the formation and rupture of conductive filaments within the multiferroic YMnO3 film. The generation of conductive paths under applied electric field is discussed in terms of the presence of grain boundaries and charged domain walls inherently formed in hexagonal YMnO3. Our findings suggest that engineering of the ferroelectric domains might be a promising route for designing and fabrication of novel resistive switching devices.

  13. Modeling Copper Diffusion in Polycrystalline CdTe Solar Cells

    Energy Technology Data Exchange (ETDEWEB)

    Akis, Richard [Arizona State University; Brinkman, Daniel [Arizona State University; Sankin, Igor [First Solar; Fang, Tian [First Solar; Guo, Da [Arizona State Univeristy; Vasileska, Dragica [Arizona State University; Ringhofer, Christain [Arizona State University

    2014-06-06

    It is well known that Cu plays an important role in CdTe solar cell performance as a dopant. In this work, a finite-difference method is developed and used to simulate Cu diffusion in CdTe solar cells. In the simulations, which are done on a two-dimensional (2D) domain, the CdTe is assumed to be polycrystalline, with the individual grains separated by grain boundaries. When used to fit experimental Cu concentration data, bulk and grain boundary diffusion coefficients and activation energies for CdTe can be extracted. In the past, diffusion coefficients have been typically obtained by fitting data to simple functional forms of limited validity. By doing full simulations, the simplifying assumptions used in those analytical models are avoided and diffusion parameters can thus be determined more accurately

  14. Extracting Cu Diffusion Parameters in Polycrystalline CdTe

    Energy Technology Data Exchange (ETDEWEB)

    Akis, Richard [Arizona State Univeristy; Brinkman, Daniel [Arizona State Univeristy; Sankin, Igor [First Solar; Fang, Tian [First Solar; Guo, Da [Arizona State Univeristy; Dragica, Vasileska [Arizona State Univeristy; Ringhofer, Christian [Arizona State University

    2014-06-13

    It is well known that Cu plays an important role in CdTe solar cell performance as a dopant. In this work, a finite-difference method is developed and used to simulate Cu diffusion in CdTe solar cells. In the simulations, which are done on a two-dimensional (2D) domain, the CdTe is assumed to be polycrystal-line, with the individual grains separated by grain boundaries. When used to fit experimental Cu concentration data, bulk and grain boundary diffusion coefficients and activation energies for CdTe can be extracted. In the past, diffusion coefficients have been typically obtained by fitting data to simple functional forms of limited validity. By doing full simulations, the simplifying assumptions used in those analytical models are avoided and diffusion parameters can thus be determined more accurately.

  15. Physically-based modelling of polycrystalline semiconductor devices

    CERN Document Server

    Lee, S

    2000-01-01

    model and characterisation method are introduced to study the effects of the multienergetic trap states on the electrical characteristics of poly-TFTs using CdSe devices as the experimental example, and the electrical parameters such as the density distribution of the trapping states are extracted. The results show excellent agreement between the simulation and experimental data. The limitations of this proposed physical model are also studied and discussed. Thin-film technology using polycrystalline semiconductors has been widely applied to active-matrix-addressed liquid crystal displays (AMLCDs) where thin-film transistors act as digital pixel switches. Research and development is in progress to integrate the driver circuits around the peripheral of the display, resulting in significant cost reduction of connections between rows and columns and the peripheral circuitry. For this latter application, where for instance it is important to control the greyscale voltage level delivered to the pixel, an understan...

  16. Magnetization collapse in polycrystalline YBCO under transport current cycles

    Energy Technology Data Exchange (ETDEWEB)

    Giordano, J L [Departamento de Ciencias de la IngenierIa, Universidad de Talca (Chile); Luzuriaga, J [Centro Atomico Bariloche, CNEA, Instituto Balseiro, UNC (Argentina); BadIa-Majos, A [Departamento de Fisica de la Materia Condensada-ICMA, Universidad de Zaragoza (Spain); Nieva, G [Centro Atomico Bariloche, CNEA, Instituto Balseiro, UNC (Argentina); RuIz-Tagle, I [Instituto de QuImica de Recursos Naturales, Universidad de Talca (Chile)

    2006-04-15

    We report measurements of the hysteretic magnetization of YBCO under superimposed transport current cycles, together with numerical simulations of magnetization and current density profiles in the corresponding parallel configuration. Field cooled (FC) and zero-field-cooled (ZFC) experiments were carried out on polycrystalline YBa{sub 2}Cu{sub 3}O{sub 7-x} cylinders, with both the applied magnetic field and transport current in the axial direction, and the current cycled several times, around and above the dissipative threshold. As in previously reported multicomponent field configuration experiments, the magnetization is seen to collapse to a more stable state both in FC and ZFC, because of the interplay between the shielding and transport currents. The results of our numerical simulations are in good qualitative agreement with the measurements, and the competition between shielding and transport due to vortex-pinning interactions and equilibrium magnetization effects are shown to play an important role in the range of our experiments.

  17. Predicting fracture in micron-scale polycrystalline silicon MEMS structures.

    Energy Technology Data Exchange (ETDEWEB)

    Hazra, Siddharth S. (Carnegie Mellon University, Pittsburgh, PA); de Boer, Maarten Pieter (Carnegie Mellon University, Pittsburgh, PA); Boyce, Brad Lee; Ohlhausen, James Anthony; Foulk, James W., III; Reedy, Earl David, Jr.

    2010-09-01

    Designing reliable MEMS structures presents numerous challenges. Polycrystalline silicon fractures in a brittle manner with considerable variability in measured strength. Furthermore, it is not clear how to use a measured tensile strength distribution to predict the strength of a complex MEMS structure. To address such issues, two recently developed high throughput MEMS tensile test techniques have been used to measure strength distribution tails. The measured tensile strength distributions enable the definition of a threshold strength as well as an inferred maximum flaw size. The nature of strength-controlling flaws has been identified and sources of the observed variation in strength investigated. A double edge-notched specimen geometry was also tested to study the effect of a severe, micron-scale stress concentration on the measured strength distribution. Strength-based, Weibull-based, and fracture mechanics-based failure analyses were performed and compared with the experimental results.

  18. Phosphorus Doping of Polycrystalline CdTe by Diffusion

    Energy Technology Data Exchange (ETDEWEB)

    Colegrove, Eric; Albin, David S.; Guthrey, Harvey; Harvey, Steve; Burst, James; Moutinho, Helio; Farrell, Stuart; Al-Jassim, Mowafak; Metzger, Wyatt K.

    2015-06-14

    Phosphorus diffusion in single crystal and polycrystalline CdTe material is explored using various methods. Dynamic secondary ion mass spectroscopy (SIMS) is used to determine 1D P diffusion profiles. A 2D diffusion model is used to determine the expected cross-sectional distribution of P in CdTe after diffusion anneals. Time of flight SIMS and cross-sectional cathodoluminescence corroborates expected P distributions. Devices fabricated with diffused P exhibit hole concentrations up to low 1015 cm-3, however a subsequent activation anneal enabled hole concentrations greater than 1016 cm-3. CdCl2 treatments and Cu based contacts were also explored in conjunction with the P doping process.

  19. Polycrystalline diamond MEMS resonator technology for sensor applications.

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, John P.; Aslam, Dean (Michigan State University, East Lansing, MI); Sepulveda-Alancastro, Nelson (Michigan State University, East Lansing, MI)

    2005-07-01

    Due to material limitations of poly-Si resonators, polycrystalline diamond (poly-C) has been explored as a new MEMS resonator material. The poly-C resonators are designed, fabricated and tested using electrostatic (Michigan State University) and piezoelectric (Sandia National Laboratories) actuation methods, and the results are compared. For comparable resonator structures, although the resonance frequencies are similar, the measured Q values in the ranges of 1000-2000 and 10,000-15,000 are obtained for electrostatic and piezoelectric actuation methods, respectively. The difference in Q for the two methods is related to different pressures used during the measurement and not to the method of measurement. For the poly-C cantilever beam resonators, the highest value of their quality factor (Q) is reported for the first time (15,263).

  20. Development of transparent polycrystalline beta-silicon carbide

    Science.gov (United States)

    Bayya, Shyam S.; Villalobos, Guillermo R.; Hunt, Michael P.; Sanghera, Jasbinder S.; Sadowski, Bryan M.; Aggarwal, Ishwar D.; Cinibulk, Michael; Carney, Carmen; Keller, Kristin

    2013-09-01

    Transparent beta-SiC is of great interest because its high strength, low coefficient of thermal expansion, very high thermal conductivity, and cubic crystal structure give it a very high thermal shock resistance. A transparent, polycrystalline beta-SiC window will find applications in armor, hypersonic missiles, and thermal control for thin disc lasers. SiC is currently available as either small transparent vapor grown disks or larger opaque shapes. Neither of which are useful in window applications. We are developing sintering technology to enable transparent SiC ceramics. This involves developing procedures to make high purity powders and studying their densification behavior. We have been successful in demonstrating transparency in thin sections using Field Assisted Sintering Technology (FAST). This paper will discuss the reaction mechanisms in the formation of beta-SiC powder and its sintering behavior in producing transparent ceramics.

  1. Friction behavior of Al-Cu-Fe-B polycrystalline quasicrystals

    Institute of Scientific and Technical Information of China (English)

    周细应; 李培耀; 罗军明; 钱士强; 童建华

    2004-01-01

    Dry sliding friction between the polycrystalline Al59 Cu25.5 Fe12.5 B3 quasicrystals(QCs) and coating of thediamond-like carbon(DLC) was carried out by self-made tribometer under different conditions. The influences of four parameters(temperature, sliding velocity, applied load, atmosphere) on friction of quasicrystal surface were studied. Microstructure of quasicrystal, morphology of worn surface, and wear debris were observed by scanning electron microscope(SEM). The results show that for QCs, the friction coefficient and the roughness of worn surface is influenced by the parameters, especially greatly by the temperature. With increasing the applied load and sliding velocity, the friction coefficient decreases. The dominant wear mechanism at 350 ℃ is delamination for QCs. The cracks forms on the worn surface during friction. Moreover, phase transformation is not observed on worn surface of QCs at 350 ℃.

  2. Physical properties optimization of polycrystalline LiFeAs

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Shiv J., E-mail: s.j.singh@ifw-dresden.de [Leibniz-Institute for Solid State and Material Research, IFW-Dresden, 01171 Dresden Germany (Germany); Research Center for Environmentally Friendly Materials Engineering, Muroran Institute of Technology, 27-1 Mizumoto-cho, Muroran, Hokkaido, 050-8585 (Japan); Gräfe, Uwe; Beck, Robert; Wolter, Anja U.B.; Grafe, Hans-Joachim [Leibniz-Institute for Solid State and Material Research, IFW-Dresden, 01171 Dresden Germany (Germany); Hess, Christian [Leibniz-Institute for Solid State and Material Research, IFW-Dresden, 01171 Dresden Germany (Germany); Center for Transport and Devices of Emergent Materials, Technische Universität Dresden, 01069 Dresden (Germany); Wurmehl, Sabine [Leibniz-Institute for Solid State and Material Research, IFW-Dresden, 01171 Dresden Germany (Germany); Institut für Festkörperphysik, Technische Universität Dresden, 01069 Dresden (Germany); Büchner, Bernd [Leibniz-Institute for Solid State and Material Research, IFW-Dresden, 01171 Dresden Germany (Germany); Center for Transport and Devices of Emergent Materials, Technische Universität Dresden, 01069 Dresden (Germany); Institut für Festkörperphysik, Technische Universität Dresden, 01069 Dresden (Germany)

    2016-10-15

    Highlights: • Synthesis of polycrystalline LiFeAs in a very broad heating temp. range (200–900 °C). • These samples are characterized by various physical and magnetic measurements. • Interestingly, the LiFeAs phase starts to form at 200 °C with T{sub c} of 19.2 K. • 600 °C synthesis temperature yields optimal high quality polycrystalline LiFeAs. • The properties of the best sample are consistent with that of LiFeAs single crystal. - Abstract: We present a study of parameter optimization for synthesizing truly stoichiometric polycrystalline LiFeAs. Stoichiometric LiFeAs has been prepared in a very broad range of synthesis temperature (200–900 °C) under otherwise exactly the same conditions, and has been characterized by structural, magnetic, transport, nuclear quadrupole resonance (NQR), and specific heat measurements. Our study showed that the LiFeAs phase is formed at 200 °C with a large amount of impurity phases. The amount of these impurity phases reduces with increasing synthesis temperature and the clean LiFeAs phase is obtained at a synthesis temperature of 600 °C. Magnetic susceptibility and resistivity measurements confirmed that the superconducting properties such as the critical temperature T{sub c}, and the upper critical field H{sub c2} do not depend on the synthesis temperature (≤ 700 °C), remaining at almost the same value of ∼19 K and ∼40 T, respectively. However, the width ΔT{sub c} of the transition and the NQR line width decrease with increasing the synthesis temperature and reached to minimum value for the synthesis temperature of 600 °C. Our careful analysis suggests that the best sample obtained at 600 °C is optimal concerning the low resistivity, high residual resistivity ratio (RRR), low ΔT{sub c}, high T{sub c} and H{sub c2}, and a small NQR line width with values which are comparable to that reported for LiFeAs single crystals. Specific heat measurements confirmed the bulk superconducting nature of the samples

  3. Defect engineering by ultrasound treatment in polycrystalline silicon

    Energy Technology Data Exchange (ETDEWEB)

    Ostapenko, S.; Jastrzebski, L. [Univ. of South Florida, Tampa, FL (United States)

    1995-08-01

    By applying ultrasound treatment (UST) to bulk and thin film polycrystalline Si (poly-Si) we have found a dramatic improvement of recombination and transport properties. The increasing of minority carrier lifetime by as much as one order of magnitude was found in short diffusion length regions, while exhibiting a strong dispersion for entire solar-grade poly-Si wafer. Relevant mechanisms are attributed to ultrasound processing on crystallographic defects, as well as UST stimulated dissociation of Fe-B pairs followed by Fe{sub i} gettering. A spectacular improvement of hydrogenation efficiency in poly-Si thin-films on glass substrate is demonstrated by resistivity study and confirmed using spatially resolved photoluminescence and nanoscale contact potential difference mapping. By applying UST to commercial solar cells we found the increasing of cell efficiency at low light excitation.

  4. Radiation hardness of three-dimensional polycrystalline diamond detectors

    Energy Technology Data Exchange (ETDEWEB)

    Lagomarsino, Stefano, E-mail: lagomarsino@fi.infn.it; Sciortino, Silvio [National Institute of Nuclear Physics (INFN), Via B. Rossi, 1-3, 50019 Sesto Fiorentino (Italy); Department of Physics and Astronomy, University of Florence, Via G. Sansone 1, 50019 Sesto Fiorentino (Italy); Bellini, Marco [European Laboratory for Non-Linear Spectroscopy, Via Nello Carrara 1, 50019 Sesto Fiorentino (Italy); Istituto Nazionale di Ottica (INO-CNR), Largo Enrico Fermi 6, 50125 Firenze (Italy); Corsi, Chiara [Department of Physics and Astronomy, University of Florence, Via G. Sansone 1, 50019 Sesto Fiorentino (Italy); European Laboratory for Non-Linear Spectroscopy, Via Nello Carrara 1, 50019 Sesto Fiorentino (Italy); Cindro, Vladimir [Jozef Stefan Institute, Jamova cesta 39, 1000 Ljubljana (Slovenia); Kanxheri, Keida; Servoli, Leonello [National Institute of Nuclear Physics (INFN), Via A. Pascoli, 06123 Perugia (Italy); Department of Physics, University of Perugia, Via A. Pascoli, 06123 Perugia (Italy); Morozzi, Arianna [Department of Engineering, University of Perugia, Via G. Duranti 93, 06125 Perugia (Italy); Passeri, Daniele [National Institute of Nuclear Physics (INFN), Via A. Pascoli, 06123 Perugia (Italy); Department of Engineering, University of Perugia, Via G. Duranti 93, 06125 Perugia (Italy); Schmidt, Christian J. [GSI Helmholtzzentrum für Schwerionenforschung, Planckstraße 1, 64291 Darmstadt (Germany)

    2015-05-11

    The three-dimensional concept in particle detection is based on the fabrication of columnar electrodes perpendicular to the surface of a solid state radiation sensor. It permits to improve the radiation resistance characteristics of a material by lowering the necessary bias voltage and shortening the charge carrier path inside the material. If applied to a long-recognized exceptionally radiation-hard material like diamond, this concept promises to pave the way to the realization of detectors of unprecedented performances. We fabricated conventional and three-dimensional polycrystalline diamond detectors, and tested them before and after neutron damage up to 1.2 ×10{sup 16 }cm{sup −2}, 1 MeV-equivalent neutron fluence. We found that the signal collected by the three-dimensional detectors is up to three times higher than that of the conventional planar ones, at the highest neutron damage ever experimented.

  5. Ferrous polycrystalline shape-memory alloy showing huge superelasticity.

    Science.gov (United States)

    Tanaka, Y; Himuro, Y; Kainuma, R; Sutou, Y; Omori, T; Ishida, K

    2010-03-19

    Shape-memory alloys, such as Ni-Ti and Cu-Zn-Al, show a large reversible strain of more than several percent due to superelasticity. In particular, the Ni-Ti-based alloy, which exhibits some ductility and excellent superelastic strain, is the only superelastic material available for practical applications at present. We herein describe a ferrous polycrystalline, high-strength, shape-memory alloy exhibiting a superelastic strain of more than 13%, with a tensile strength above 1 gigapascal, which is almost twice the maximum superelastic strain obtained in the Ni-Ti alloys. Furthermore, this ferrous alloy has a very large damping capacity and exhibits a large reversible change in magnetization during loading and unloading. This ferrous shape-memory alloy has great potential as a high-damping and sensor material.

  6. Technological Aspects of Low-Alloyed Cast Steel Massive Casting Manufacturing

    Directory of Open Access Journals (Sweden)

    Szajnara J.

    2013-12-01

    Full Text Available In the paper authors have undertaken the attempt of explaining the causes of cracks net occurrence on a massive 3-ton cast steel casting with complex geometry. Material used for casting manufacturing was the low-alloyed cast steel with increased wear resistance modified with vanadium and titanium. The studies included the primary and secondary crystallization analysis with use of TDA and the qualitative and quantitative analysis of non-metallic inclusions.

  7. Cast functional accessories for heat treatment furnaces

    Directory of Open Access Journals (Sweden)

    A. Drotlew

    2010-10-01

    Full Text Available The study gives examples of the cast functional accessories operating in furnaces for the heat treatment of metals and alloys. The describeddesign solutions of castings and their respective assemblies are used for charge preparation and handling. They were put in systematicorder depending on furnace design and the technological purpose of heat treatment. Basic grades of austenitic cast steel, used for castings of this type, were enumerated, and examples of general guidelines formulated for their use were stated. The functional accessories described in this study were designed and made by the Foundry Research Laboratory of West Pomeranian University of Technology.

  8. Vacuum-sealed casting process under pressure

    Institute of Scientific and Technical Information of China (English)

    LI Chen-xi; GUO Tai-ming; WU Chun-jing; WANG Hong

    2006-01-01

    A new casting method, the vacuum-sealed mold casting under pressure, has been developed, and thin wall iron castings with high precision and smooth surface have been produced successfully with this casting method. The experimental results show that the liquid iron has a very excellent filling ability because a high negative pressure is formed in the mold cavity during filling process. The vacuum-sealed mold under pressure has very high compressive strength greater than 650 kPa, which is 3-4 times as high as that of the molds produced by high-pressure molding process or vacuum-sealed molding process.

  9. Friction Stir Processing of Cast Superalloys Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This SBIR effort examines the feasibility of an innovative fabrication technology incorporating sand casting and friction stir processing (FSP) for producing...

  10. Polycrystalline CVD diamond device level modeling for particle detection applications

    Science.gov (United States)

    Morozzi, A.; Passeri, D.; Kanxheri, K.; Servoli, L.; Lagomarsino, S.; Sciortino, S.

    2016-12-01

    Diamond is a promising material whose excellent physical properties foster its use for radiation detection applications, in particular in those hostile operating environments where the silicon-based detectors behavior is limited due to the high radiation fluence. Within this framework, the application of Technology Computer Aided Design (TCAD) simulation tools is highly envisaged for the study, the optimization and the predictive analysis of sensing devices. Since the novelty of using diamond in electronics, this material is not included in the library of commercial, state-of-the-art TCAD software tools. In this work, we propose the development, the application and the validation of numerical models to simulate the electrical behavior of polycrystalline (pc)CVD diamond conceived for diamond sensors for particle detection. The model focuses on the characterization of a physically-based pcCVD diamond bandgap taking into account deep-level defects acting as recombination centers and/or trap states. While a definite picture of the polycrystalline diamond band-gap is still debated, the effect of the main parameters (e.g. trap densities, capture cross-sections, etc.) can be deeply investigated thanks to the simulated approach. The charge collection efficiency due to β -particle irradiation of diamond materials provided by different vendors and with different electrode configurations has been selected as figure of merit for the model validation. The good agreement between measurements and simulation findings, keeping the traps density as the only one fitting parameter, assesses the suitability of the TCAD modeling approach as a predictive tool for the design and the optimization of diamond-based radiation detectors.

  11. Imaging with polycrystalline mercuric iodide detectors using VLSI readout

    Energy Technology Data Exchange (ETDEWEB)

    Turchetta, R.; Dulinski, W.; Husson, D.; Riester, J.L.; Schieber, M.; Zuck, A.; Melekhov, L.; Saado, Y.; Hermon, H.; Nissenbaum, J

    1999-06-01

    Potentially low cost and large area polycrystalline mercuric iodide room-temperature radiation detectors, with thickness of 100-600 {mu}m have been successfully tested with dedicated low-noise, low-power mixed signal VLSI electronics which can be used for compact, imaging solutions. The detectors are fabricated by depositing HgI{sub 2} directly on an insulating substrate having electrodes in the form of microstrips and pixels with an upper continuous electrode. The deposition is made either by direct evaporation or by screen printing HgI{sub 2} mixed with glue such as Poly-Vinyl-Butiral. The properties of these first-generation detectors are quite uniform from one detector to another. Also for each single detector the response is quite uniform and no charge loss in the inter-electrode space have been detected. Because of the low cost and of the polycrystallinity, detectors can be potentially fabricated in any size and shape, using standard ceramic technology equipment, which is an attractive feature where low cost and large area applications are needed. The detectors which act as radiation counters have been tested with a beta source as well as in a high-energy beam of 100 GeV muons at CERN, connected to VLSI, low noise electronics. Charge collection efficiency and uniformity have been studied. The charge is efficiently collected even in the space between strips indicating that fill factors of 100% could be reached in imaging applications with direct detection of radiation. Single photon counting capability is reached with VLSI electronics. These results show the potential of this material for applications demanding position sensitive, radiation resistant, room-temperature operating radiation detectors, where position resolution is essential, as it can be found in some applications in high-energy physics, nuclear medicine and astrophysics.

  12. Growth of textured mullite fibers using polycrystalline precursors

    Science.gov (United States)

    Yoon, Wonki

    Fine ceramic oxide fibers are widely used as reinforcements in composites for high temperature applications. The primary goal of this research was to investigate the growth of textured or single crystal oxide fibers by heat treatment of polycrystalline or amorphous, extruded precursor fibers. Mullite was selected for this study due to its excellent chemical stability, creep resistance and strength at high temperatures. Micrographic analysis and in-situ synchrotron X-ray diffraction analysis have been performed on mullite systems in order to study the anisotropic grain growth and the effect of titania additions in mullite. The estimated activation energies from the SEM micrographic particle size analysis were 644.3 kJ/mol and 773.7 kJ/mol for the length and thickness, respectively. An in-situ synchrotron X-ray diffraction microstructure analysis was done with a Curved Image Plate (CIP) detector and the fiber was heat treated in a QLF. The apparent crystallite size showed anisotropy in crystallite growth. Furthermore, a higher growth rate along the [001] direction than the [110] direction was observed. Mullite whiskers were prepared by HF leaching and templated into polycrystalline mullite fibers by extrusion. Textured growth of mullite fibers with elongated grains, aligned along the long-axis of the fibers, was achieved by heat treatment. Repeated heat treatment cycles of a whisker-templated fiber showed a bamboo-like microstructure. It was confirmed by SEM, TEM and optical microscopy (OM) that the growth direction along the fiber length was the [001] direction of orthorhombic mullite.

  13. Effects of vibration frequency on vibration-assisted nano-scratch process of mono-crystalline copper via molecular dynamics simulation

    Science.gov (United States)

    Zhu, Bo; Zhao, Hongwei; Zhao, Dan; Zhang, Peng; Yang, Yihan; Han, Lei; Kui, Hailin

    2016-03-01

    It has always been a critical issue to understand the material removal behavior of Vibration-Assisted Machining (VAM), especially on atomic level. To find out the effects of vibration frequency on material removal response, a three-dimensional molecular dynamics (MD) model has been established in this research to investigate the effects of scratched groove, crystal defects on the surface quality, comparing with the Von Mises shear strain and tangential force in simulations during nano-scratching process. Comparisons are made among the results of simulations from different vibration frequency with the same scratching feed, depth, amplitude and crystal orientation. Copper potential in this simulation is Embedded-Atom Method (EAM) potential. Interaction between copper and carbon atoms is Morse potential. Simulational results show that higher frequency can make groove smoother. Simulation with high frequency creates more dislocations to improve the machinability of copper specimen. The changing frequency does not have evident effects on Von Mises shear strain. Higher frequency can decrease the tangential force to reduce the consumption of cutting energy and tool wear. In conclusion, higher vibration frequency in VAM on mono-crystalline copper has positive effects on surface finish, machinablility and tool wear reduction.

  14. Effects of vibration frequency on vibration-assisted nano-scratch process of mono-crystalline copper via molecular dynamics simulation

    Directory of Open Access Journals (Sweden)

    Bo Zhu

    2016-03-01

    Full Text Available It has always been a critical issue to understand the material removal behavior of Vibration-Assisted Machining (VAM, especially on atomic level. To find out the effects of vibration frequency on material removal response, a three-dimensional molecular dynamics (MD model has been established in this research to investigate the effects of scratched groove, crystal defects on the surface quality, comparing with the Von Mises shear strain and tangential force in simulations during nano-scratching process. Comparisons are made among the results of simulations from different vibration frequency with the same scratching feed, depth, amplitude and crystal orientation. Copper potential in this simulation is Embedded-Atom Method (EAM potential. Interaction between copper and carbon atoms is Morse potential. Simulational results show that higher frequency can make groove smoother. Simulation with high frequency creates more dislocations to improve the machinability of copper specimen. The changing frequency does not have evident effects on Von Mises shear strain. Higher frequency can decrease the tangential force to reduce the consumption of cutting energy and tool wear. In conclusion, higher vibration frequency in VAM on mono-crystalline copper has positive effects on surface finish, machinablility and tool wear reduction.

  15. Photocarrier radiometry for predicting the degradation of electrical parameters of monocrystalline silicon (c-Si) solar cell irradiated by 100 KeV proton beams

    Energy Technology Data Exchange (ETDEWEB)

    Song, P. [School of Mechatronics Engineering, Harbin Institute of Technology, Harbin 150001 (China); Liu, J.Y., E-mail: ljywlj@hit.edu.cn [School of Mechatronics Engineering, Harbin Institute of Technology, Harbin 150001 (China); State Key Laboratory of Robotics and System (HIT), Harbin 150001 (China); Yuan, H.M.; Oliullah, Md.; Wang, F. [School of Mechatronics Engineering, Harbin Institute of Technology, Harbin 150001 (China); Wang, Y., E-mail: songpengkevin@126.com [School of Mechatronics Engineering, Harbin Institute of Technology, Harbin 150001 (China); State Key Laboratory of Robotics and System (HIT), Harbin 150001 (China)

    2016-09-15

    In this study, the monocrystalline silicon (c-Si) solar cell irradiated by 100 KeV proton beams at various fluences is investigated. A one-dimensional two-layer carrier density wave model has been developed to estimate the minority carrier lifetime of n-region and p-region of the non-irradiated c-Si solar cell by best fitting with the experimental photocarrier radiometry (PCR) signal (the amplitude and the phase). Furthermore, the lifetime is used to determine the initial defect density of the quasi-neutral region (QNR) of the solar cell to predict its I–V characteristics. The theoretically predicted short-circuit current density (J{sub sc}), and open-circuit voltage (V{sub oc}) of the non-irradiated samples are in good agreement with experiment. Then a three-region defect distribution model for the c-Si solar cell irradiated by proton beams is carried out to describe the defect density distribution according to Monte Carlo simulation results and the initial defect density of the non-irradiated sample. Finally, we find that the electrical measurements of J{sub sc} and V{sub oc} of the solar cells irradiated at different fluences using 100 KeV proton beams are consistent with the PCR predicting results.

  16. Determination of SiO2 and C layers on a monocrystalline silicon sphere by reference-free x-ray fluorescence analysis

    Science.gov (United States)

    Hönicke, Philipp; Holfelder, Ina; Kolbe, Michael; Lubeck, Janin; Pollakowski-Herrmann, Beatrix; Unterumsberger, Rainer; Weser, Jan; Beckhoff, Burkhard

    2017-08-01

    The redefinition of the kilogram will be based on Planck’s constant, which can be calculated from Avogadro’s constant, and hence by ‘counting’ the silicon atoms in a monocrystalline 28Si sphere weighing one kilogram. To reduce the influence of the surface layers on the determined value requires, amongst other issues, an accurate quantification of these layers on the 28Si spheres. Apart from the native SiO2 layer, carbonaceous contamination layers and adsorbed water molecules are expected to be crucial in determining the surface composition. The overall mass contribution of these surface layers must be determined with an accuracy below 10% in order to be able to meet the targeted uncertainty budget for the redefinition. In this work, we performed a quantification of these surface layers, applying reference-free x-ray fluorescence spectrometry using a modified manipulator within an ultra-high vacuum chamber. Using this setup, we are able to quantitatively assess the surface of the spheres on a large area (about 20%) with quantification uncertainties below the required target of 10% for oxygen and carbon in order to meet an absolute uncertainty value of the mass below 10 µg.

  17. Hydrogen partitioning in pure cast aluminum as determined by dynamic evolution rate measurements

    Science.gov (United States)

    Outlaw, R. A.; Peterson, D. T.; Schmidt, F. A.

    1981-01-01

    Hydrogen in pure aluminum can be found in two different states. One is related to a presence in gas-filled pores, while the other state involves the formation of a solid solution between hydrogen and aluminum. The considered investigation is concerned with the distribution of the hydrogen between various states. A dynamic technique is employed to measure the evolution of hydrogen from commercially available samples of polycrystalline pure aluminum under ultrahigh vacuum conditions. The obtained data are compared with the results of a statistical analysis concerning the porosity in the cast aluminum. It was found that more than 99 pct of the hydrogen in the aluminum is located in large pores. Less than 1 pct of the hydrogen is partitioned between the solid solution and the small pores.

  18. The temperature gradient on section of casting in process of primary crystallization of chromium cast iron

    OpenAIRE

    2008-01-01

    The methodology of defining in article was introduced the temperature gradient in process of primary crystallization during cooling the casting from chromium cast iron on basis of measurements of thermal field in test DTA-K3. Insert also the preliminary results of investigations of influence temperature gradient on structure of studied wear resistance chromium cast iron.

  19. The temperature gradient on section of casting in process of primary crystallization of chromium cast iron

    Directory of Open Access Journals (Sweden)

    A. Studnicki

    2008-08-01

    Full Text Available The methodology of defining in article was introduced the temperature gradient in process of primary crystallization during cooling the casting from chromium cast iron on basis of measurements of thermal field in test DTA-K3. Insert also the preliminary results of investigations of influence temperature gradient on structure of studied wear resistance chromium cast iron.

  20. Spray casting project final report

    Energy Technology Data Exchange (ETDEWEB)

    Churnetski, S.R.; Thompson, J.E.

    1996-08-01

    Lockheed Martin Energy Systems, Inc. (Energy Systems), along with other participating organizations, has been exploring the feasibility of spray casting depleted uranium (DU) to near-net shape as a waste minimization effort. Although this technology would be useful in a variety of applications where DU was the material of choice, this effort was aimed primarily at gamma-shielding components for use in storage and transportation canisters for high-level radioactive waste, particularly in the Multipurpose Canister (MPC) application. In addition to the waste-minimization benefits, spray casting would simplify the manufacturing process by allowing the shielding components for MPC to be produced as a single component, as opposed to multiple components with many fabrication and assembly steps. In earlier experiments, surrogate materials were used to simulate the properties (specifically reactivity and density) of DU. Based on the positive results from those studies, the project participants decided that further evaluation of the issues and concerns that would accompany spraying DU was warranted. That evaluation occupied substantially all of Fiscal Year 1995, yielding conceptual designs for both an intermediate facility and a production facility and their associated engineering estimates. An intermediate facility was included in this study to allow further technology development in spraying DU. Although spraying DU to near-net shape seems to be feasible, a number of technical, engineering, and safety issues would need to be evaluated before proceeding with a production facility. This report is intended to document the results from the spray-casting project and to provide information needed by anyone interested in proceeding to the next step.

  1. Microdefects in cast multicrystalline silicon

    Energy Technology Data Exchange (ETDEWEB)

    Wolf, E.; Klinger, D.; Bergmann, S. [Inst. of Crystal Growth Berlin (Germany)

    1995-08-01

    The microdefect etching behavior of cast multicrystalline BAYSIX and SILSO samples is mainly the same as that of EFG silicon, in spite of the very different growth parameters applied to these two techniques and the different carbon contents of the investigated materials. Intentional decorating of mc silicon with copper, iron and gold did not influence the results of etching and with help of infrared transmission microscopy no metal precipitates at the assumed microdefects could be established. There are many open questions concerning the origin of the assumed, not yet doubtless proved microdefects.

  2. Control of Cast Iron Microstructure

    Science.gov (United States)

    Graham, J.; Lillybeck, N.; Franco, N.; Stefanescu, D. M.

    1985-01-01

    The use of microgravity for industrial research in the processing of cast iron was investigated. Solidification experiments were conducted using the KC-135 and F-104 aircraft, and an experiment plan was developed for follow-on experiments using the Shuttle. Three areas of interest are identified: (1) measurement of thermophysical properties in the melt; (2) understanding of the relative roles of homogeneous nucleation, grain multiplication, and innocultants in forming the microstructure; and (3) exploring the possibility of obtaining an aligned graphite structure in hypereutectic Fe, Ni, and Co.

  3. Yield Improvement in Steel Casting (Yield II)

    Energy Technology Data Exchange (ETDEWEB)

    Richard A. Hardin; Christoph Beckermann; Tim Hays

    2002-02-18

    This report presents work conducted on the following main projects tasks undertaken in the Yield Improvement in Steel Casting research program: Improvement of Conventional Feeding and Risering Methods, Use of Unconventional Yield Improvement Techniques, and Case Studies in Yield Improvement. Casting trials were conducted and then simulated using the precise casting conditions as recorded by the participating SFSA foundries. These results present a statistically meaningful set of experimental data on soundness versus feeding length. Comparisons between these casting trials and casting trials performed more than forty years ago by Pellini and the SFSA are quite good and appear reasonable. Comparisons between the current SFSA feeding rules and feeding rules based on the minimum Niyama criterion reveal that the Niyama-based rules are generally less conservative. The niyama-based rules also agree better with both the trials presented here, and the casting trails performed by Pellini an d the SFSA years ago. Furthermore, the use of the Niyama criterion to predict centerline shrinkage for horizontally fed plate sections has a theoretical basis according to the casting literature reviewed here. These results strongly support the use of improved feeding rules for horizontal plate sections based on the Niyama criterion, which can be tailored to the casting conditions for a given alloy and to a desired level of soundness. The reliability and repeatability of ASTM shrinkage x-ray ratings was investigated in a statistical study performed on 128 x-rays, each of which were rated seven different times. A manual ''Feeding and Risering Guidelines for Steel Castings' is given in this final report. Results of casting trials performed to test unconventional techniques for improving casting yield are presented. These use a stacked arrangement of castings and riser pressurization to increase the casting yield. Riser pressurization was demonstrated to feed a casting up to

  4. Clean cast steel technology. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Bates, C.E.; Griffin, J.A.

    1998-06-01

    This report documents the results obtained from the Clean Cast Steel Technology Program financially supported by the DOE Metal Casting Competitiveness Research Program and industry. The primary objective of this program is to develop technology for delivering steel free of oxide macroinclusions to mold cavities. The overall objective is to improve the quality of cast steel by developing and demonstrating the technology for substantially reducing surface and sub-surface oxide inclusions. Two approaches are discussed here. A total of 23 castings were produced by submerge pouring along with sixty conventionally poured castings. The submerged poured castings contained, on average, 96% fewer observable surface inclusions (11.9 vs 0.4) compared to the conventionally poured cast parts. The variation in the population of surface inclusions also decreased by 88% from 5.5 to 0.7. The machinability of the casting was also improved by submerged pouring. The submerge poured castings required fewer cutting tool changes and less operator intervention during machining. Subsequent to these trials, the foundry has decided to purchase more shrouds for continued experimentation on other problem castings where submerge pouring is possible. An examination of melting and pouring practices in four foundries has been carried out. Three of the four foundries showed significant improvement in casting quality by manipulating the melting practice. These melting practice variables can be grouped into two separate categories. The first category is the pouring and filling practice. The second category concerns the concentration of oxidizable elements contained in the steel. Silicon, manganese, and aluminum concentrations were important factors in all four foundries. Clean heats can consistently be produced through improved melting practice and reducing exposure of the steel to atmospheric oxygen during pouring and filling.

  5. The Role of Indian Caste Identity and Caste Inconsistent Norms on Status Representation.

    Science.gov (United States)

    Sankaran, Sindhuja; Sekerdej, Maciek; von Hecker, Ulrich

    2017-01-01

    The Indian caste system is a complex social structure wherein social roles like one's profession became 'hereditary,' resulting in restricted social mobility and fixed status hierarchies. Furthermore, we argue that the inherent property of caste heightens group identification with one's caste. Highly identified group members would protect the identity of the group in situations when group norms are violated. In this paper, we were interested in examining the consequence of caste norm violation and how an individual's status is mentally represented. High caste norms are associated with moral values while the lower caste norms are associated with immorality. We predicted a 'black sheep effect,' that is, when high caste individuals' group identity (caste norm violation condition) is threatened their salient high caste identity would increase, thereby resulting in devaluing the status of their fellow in-group member if the latter is perceived as perpetrator. We presented participants with a social conflict situation of a victim and a perpetrator that is 'Caste norm consistent' (Lower caste individual as a perpetrator and higher caste individual as a victim) and vice versa 'Caste norm inconsistent' condition (higher caste individual as perpetrator and lower caste individual as a victim). Then, participants had to choose from nine pictorial depictions representing the protagonists in the story on a vertical line, with varying degrees of status distance. Results showed evidence for the black sheep effect and, furthermore, revealed that no other identity (religious, national, and regional) resulted in devaluing the status of fellow in-group member. These results help us understand the 'black sheep' effect in the context of moral norms and status representation and are discussed in the framework of the Indian society.

  6. Validation of stress prediction during solidification of cast components

    CSIR Research Space (South Africa)

    Paine, AP

    2007-07-01

    Full Text Available designed box shaped experimental casting was used to validate the commercial finite-element code ProCAST (casting simulation software), with respect to distortions as well as residual stresses....

  7. Accuracy of stereolithography additive casts used in a digital workflow

    DEFF Research Database (Denmark)

    Al-Imam, Hiba; Gram, Mia; Benetti, Ana R

    2017-01-01

    additive (SLA) casts from 2 manufacturers: 9 Dreve SLA casts and 9 Scanbiz SLA casts. All casts were then scanned 9 times with an extraoral scanner to produce the reference data set. Trueness was evaluated by superimposing the data sets obtained by scanning the casts with the reference data set. Precision...... 95.3%, IQR 16.7) and the least RMS (median 25.8 μm, IQR 14.6), followed by Dreve and Scanbiz. Differences in RMS were observed between gypsum and the SLA casts (P... (within 50 μm) and the least RMS, followed by Scanbiz and Dreve. CONCLUSIONS: This study found that gypsum casts had higher accuracy than SLA casts. Within 50 μm, gypsum casts were better than Scanbiz SLA casts, while gypsum casts and Dreve SLA casts had similar trueness. Significant differences were...

  8. PERFECTION OF TECHNOLOGY OF CASTINGS PRODUCTION TECHNOLOGY BY CONSUMABLE PATTERNS

    OpenAIRE

    N. I. Urbanovich; O. S. Komarov; V. I. Volosatikov; M. I. Kurbatov; V. G. Pavlovich

    2008-01-01

    The role of closed air gates at casting by gasified models of non-casting polystyrene in the process of castings defects elimination, connected with creation of non-gasified products of polystyrene thermodestruction, is studied.

  9. PERFECTION OF TECHNOLOGY OF CASTINGS PRODUCTION TECHNOLOGY BY CONSUMABLE PATTERNS

    Directory of Open Access Journals (Sweden)

    N. I. Urbanovich

    2008-01-01

    Full Text Available The role of closed air gates at casting by gasified models of non-casting polystyrene in the process of castings defects elimination, connected with creation of non-gasified products of polystyrene thermodestruction, is studied.

  10. Energy use in selected metal casting facilities - 2003

    Energy Technology Data Exchange (ETDEWEB)

    Eppich, Robert E. [Eppich Technologies, Syracuse, IN (United States)

    2004-05-01

    This report represents an energy benchmark for various metal casting processes. It describes process flows and energy use by fuel type and processes for selected casting operations. It also provides recommendations for improving energy efficiency in casting.

  11. Technological parameters of die casting and quality of casting from EN AC46500 alloy

    Directory of Open Access Journals (Sweden)

    Š. Gašpár

    2016-07-01

    Full Text Available Die casting represents the highest technological level of metal mold casting. This technology enables production of almost all final products without necessity of further processing. The important aspect of efficiency and production is a proper casting parameters setting. In the submitted paper following die casting parameters are analyzed: plunger pressing speed and pressure. The studied parameters most significantly affect a qualitative of castings from EN AC46500 alloy and they influence the most a gained porosity level as well as basic mechanical properties represented by permanent deformations.

  12. Laboratory grey cast iron continuous casting line with electromagnetic forced convection support

    Directory of Open Access Journals (Sweden)

    J. Szajnar

    2010-07-01

    Full Text Available The article describes the construction of a 20 mm diameter grey cast iron ingots continuous casting laboratory line. This line is made ofthree main units: melting unit (induction furnace, casting unit and the pulling unit. In order to improve the homogeneity of themicrostructure of ingots (by applying forced convection of liquid metal during the crystallization process in this case a crystallizer system generating the forced movement of liquid metal based on a system of electrical power windings of the AC specific frequency. Thissolution allowed to obtain a homogeneous microstructure of the continuous casting of cast iron EN-GJL-200 species.

  13. DEVELOPMENTS IN THE FIELD OF STEEL AND CAST IRON

    Directory of Open Access Journals (Sweden)

    E. B. Ten

    2013-01-01

    Full Text Available The article describes the use of a number of promising casting technologies applied to produce the castings of steel and cast iron with special properties. Such as, technology of centrifugal casting of large-size workpieces made of steel, forecasting method composition of slag in the smelting of high-manganese steels, method of complex modifying chromium cast irons, analysis of properties of perspective high-alloy aluminium cast iron.

  14. Casting fine grained, fully dense, strong inorganic materials

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Sam W.; Spencer, Larry S.; Phillips, Michael R.

    2015-11-24

    Methods and apparatuses for casting inorganic materials are provided. The inorganic materials include metals, metal alloys, metal hydrides and other materials. Thermal control zones may be established to control the propagation of a freeze front through the casting. Agitation from a mechanical blade or ultrasonic energy may be used to reduce porosity and shrinkage in the casting. After solidification of the casting, the casting apparatus may be used to anneal the cast part.

  15. Synthesis and optical properties of polycrystalline Li2Al2B2O7 (LABO)

    Science.gov (United States)

    Dagdale, S. R.; Muley, G. G.

    2016-05-01

    A polycrystalline lithium aluminum borate (Li2Al2B2O7, LABO) has been synthesized by using simple solid-state technique. The obtained LABO polycrystalline was characterized by powder X-ray diffraction; Fourier transform infrared (FT-IR) spectroscopy and second harmonic generation (SHG) efficiency measurement. The functional groups were identified using the FT-IR spectroscopic data. The SHG efficiency of the polycrystalline material was obtained by the classic Kurtz powder technique using a fundamental wavelength 1064 nm of Nd:YAG laser and it is found to be 1.4 times that of potassium dihydrogen phosphate (KDP).

  16. Polycrystalline GeSn thin films on Si formed by alloy evaporation

    Science.gov (United States)

    Kim, Munho; Fan, Wenjuan; Seo, Jung-Hun; Cho, Namki; Liu, Shih-Chia; Geng, Dalong; Liu, Yonghao; Gong, Shaoqin; Wang, Xudong; Zhou, Weidong; Ma, Zhenqiang

    2015-06-01

    Polycrystalline GeSn thin films on Si substrates with a Sn composition up to 4.5% have been fabricated and characterized. The crystalline structure, surface morphology, and infrared (IR) absorption coefficient of the annealed GeSn thin films were carefully investigated. It was found that the GeSn thin films with a Sn composition of 4.5% annealed at 450 °C possessed a desirable polycrystalline structure according to X-ray diffraction (XRD) analyses and Raman spectroscopy analyses. In addition, the absorption coefficient of the polycrystalline GeSn thin films in the IR region was significantly better than that of the single crystalline bulk Ge.

  17. Impact of graphene polycrystallinity on the performance of graphene field-effect transistors

    Energy Technology Data Exchange (ETDEWEB)

    Jiménez, David; Chaves, Ferney [Departament d' Enginyeria Electrònica, Escola d' Enginyeria, Universitat Autònoma de Barcelona, 08193-Bellaterra (Spain); Cummings, Aron W.; Van Tuan, Dinh [ICN2, Institut Català de Nanociencia i Nanotecnologia, Campus UAB, 08193 Bellaterra (Barcelona) (Spain); Kotakoski, Jani [Faculty of Physics, University of Vienna, Boltzmanngasse 5, 1090 Wien (Austria); Department of Physics, University of Helsinki, P.O. Box 43, 00014 University of Helsinki (Finland); Roche, Stephan [ICN2, Institut Català de Nanociencia i Nanotecnologia, Campus UAB, 08193 Bellaterra (Barcelona) (Spain); ICREA, Institució Catalana de Recerca i Estudis Avançats, 08070 Barcelona (Spain)

    2014-01-27

    We have used a multi-scale physics-based model to predict how the grain size and different grain boundary morphologies of polycrystalline graphene will impact the performance metrics of graphene field-effect transistors. We show that polycrystallinity has a negative impact on the transconductance, which translates to a severe degradation of the maximum and cutoff frequencies. On the other hand, polycrystallinity has a positive impact on current saturation, and a negligible effect on the intrinsic gain. These results reveal the complex role played by graphene grain boundaries and can be used to guide the further development and optimization of graphene-based electronic devices.

  18. Geometric aspects of the casting process

    NARCIS (Netherlands)

    Ahn, H.-K.

    2002-01-01

    Manufacturing is the process of converting raw materials into useful products. Among the most important manufacturing processes, casting is a commonly used manufacturing process for plastic and metal objects. The industrial casting process consists of two stages. First, liquid is filled into a cavit

  19. Theory of Cast Formation in Electrophoretic Deposition

    NARCIS (Netherlands)

    Biesheuvel, P. Maarten; Verweij, Henk

    1999-01-01

    The rate of cast formation in electrophoretic deposition is described by a combination of the equation of continuity for the suspension phase with expressions for the particle velocity and the movement of the cast-suspension boundary. The assumptions necessary to arrive at the well-known equations o

  20. Model castings with composite surface layer - application

    Directory of Open Access Journals (Sweden)

    J. Szajnar

    2008-10-01

    Full Text Available The paper presents a method of usable properties of surface layers improvement of cast carbon steel 200–450, by put directly in foundingprocess a composite surface layer on the basis of Fe-Cr-C alloy. Technology of composite surface layer guarantee mainly increase inhardness and aberasive wear resistance of cast steel castings on machine elements. This technology can be competition for generallyapplied welding technology (surfacing by welding and thermal spraying. In range of studies was made cast steel test castings withcomposite surface layer, which usability for industrial applications was estimated by criterion of hardness and aberasive wear resistance of type metal-mineral and quality of joint cast steel – (Fe-Cr-C. Based on conducted studies a thesis, that composite surface layer arise from liquid state, was formulated. Moreover, possible is control of composite layer thickness and its hardness by suitable selection of parameters i.e. thickness of insert, pouring temperature and solidification modulus of casting. Possibility of technology application of composite surface layer in manufacture of cast steel slide bush for combined cutter loader is presented.

  1. Engineering design of centrifugal casting machine

    Science.gov (United States)

    Kusnowo, Roni; Gunara, Sophiadi

    2017-06-01

    Centrifugal casting is a metal casting process in which metal liquid is poured into a rotating mold at a specific temperature. Given round will generate a centrifugal force that will affect the outcome of the casting. Casting method is suitable in the manufacture of the casting cylinder to obtain better results. This research was performed to design a prototype machine by using the concept of centrifugal casting. The design method was a step-by-step systematic approach in the process of thinking to achieve the desired goal of realizing the idea and build bridges between idea and the product. Design process was commenced by the conceptual design phase and followed by the embodiment design stage and detailed design stage. With an engineering design process based on the method developed by G. E. Dieter, draft prototype of centrifugal casting machine with dimension of 550×450×400 mm, ¼ HP motor power, pulley and belt mechanism, diameter of 120-150mm, simultaneously with the characteristics of simple casting product, easy manufacture and maintenance, and relatively inexpensive, was generated.

  2. Detection of Cast Shadows in Surveillance Applications

    DEFF Research Database (Denmark)

    Erbou, Søren G.; Sørensen, Helge Bjarne Dissing; Stage, Bjarne

    2005-01-01

    Cast shadows from moving objects reduce the general ability of robust classification and tracking of these objects, in outdoor surveillance applications. A method for segmentation of cast shadows is proposed, combining statistical features with a new similarity feature, derived from a physics...

  3. Iron/Phosphorus Alloys for Continuous Casting

    Science.gov (United States)

    Dufresne, E. R.

    1986-01-01

    Continuous casting becomes practicable because of reduced eutectic temperature. Experimental ferrous alloy has melting point about 350 degrees C lower than conventional steels, making possible to cast structural members and eliminating need for hot rolling. Product has normal metal structure and good physical properties. Process used to make rails, beams, slabs, channels, and pipes.

  4. The quality of the joint between alloy steel and unalloyed cast steel in bimetallic layered castings

    Directory of Open Access Journals (Sweden)

    T. Wróbel

    2012-01-01

    Full Text Available In paper is presented technology of bimetallic layered castings based on founding method of layer coating directly in cast process so-called method of mould cavity preparation. Prepared castings consist two fundamental parts i.e. bearing part and working part (layer. The bearing part of bimetallic layered casting is typical foundry material i.e. ferritic-pearlitic unalloyed cast steel, whereas working part (layer is plate of austenitic alloy steel sort X2CrNi 18-9. The ratio of thickness between bearing and working part is 8:1. The aim of paper was assessed the quality of the joint between bearing and working part in dependence of pouring temperature and carbon concentration in cast steel. The quality of the joint in bimetallic layered castings was evaluated on the basis of ultrasonic non-destructive testing, structure and microhardness researches.

  5. Numerical modelling of stresses and deformations in casting processes

    DEFF Research Database (Denmark)

    Hattel, Jesper Henri

    1997-01-01

    Keywords: Stresses and deformations, casting, governing equations, thermal strain, control volume method......Keywords: Stresses and deformations, casting, governing equations, thermal strain, control volume method...

  6. Numerical modelling of stresses and deformations in casting processes

    DEFF Research Database (Denmark)

    Hattel, Jesper Henri

    1997-01-01

    Keywords: Stresses and deformations, casting, governing equations, thermal strain, control volume method......Keywords: Stresses and deformations, casting, governing equations, thermal strain, control volume method...

  7. Standard digital reference images for titanium castings

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2010-01-01

    1.1 The digital reference images provided in the adjunct to this standard illustrate various types and degrees of discontinuities occurring in titanium castings. Use of this standard for the specification or grading of castings requires procurement of the adjunct digital reference images, which illustrate the discontinuity types and severity levels. They are intended to provide the following: 1.1.1 A guide enabling recognition of titanium casting discontinuities and their differentiation both as to type and degree through digital radiographic examination. 1.1.2 Example digital radiographic illustrations of discontinuities and a nomenclature for reference in acceptance standards, specifications and drawings. 1.2 The digital reference images consist of seventeen digital files each illustrating eight grades of increasing severity. The files illustrate seven common discontinuity types representing casting sections up to 1-in. (25.4-mm). 1.3 The reference radiographs were developed for casting sections up to 1...

  8. Possible segregation caused by centrifugal titanium casting.

    Science.gov (United States)

    Watanabe, K; Okawa, S; Kanatani, M; Nakano, S; Miyakawa, O; Kobayashi, M

    1996-12-01

    The possibility of the segregation under solidification process using a centrifugal casting machine was investigated using an electron probe microanalyzer with elemental distribution map, line analysis and quantitative analysis. When a very small quantity of platinum was added to local molten titanium during the casting process, macroscopic segregation was observed under conditions of density difference of 0.1 g/cm3 at the most, confirming that the centrifugal force of the casting machine is extremely strong. When a Ti-6Al-4V alloy was cast, however, no macroscopic segregation was observed. The centrifugal force of the casting machine examined in the present study hardly results in the body-force segregation in this titanium alloy.

  9. Ferritic-austenitic cast steel - selected problems

    Directory of Open Access Journals (Sweden)

    Z. Stradomski

    2011-07-01

    Full Text Available The author has been involved in the problems occurring in the manufacture of ferritic-austenitic cast steel castings for many years. The author’s remarks and investigation results reported in this article will enable potential manufacturers to determine their own technical capabilities and structural determinants related to the chemical composition of material, which are crucial to the good quality of a casting. Particular emphasis should be laid on the role of enhanced carbon content, the presence of copper, the precipitates of the ζ phase, and the nature of solidification structure in the tendency of duplex-type cast steel to cracking. It seems that in view of the pro-ecological activities undertaken, including flue gas desulphurization in coal-fired power plants, efforts should be made in steel foundries to introduce selected grades of ferritic-austenitic cast steel to production.

  10. INDIAN CASTE SYSTEM: HISTORICAL AND PSYCHOANALYTIC VIEWS.

    Science.gov (United States)

    Vallabhaneni, Madhusudana Rao

    2015-12-01

    This paper elucidates the historical origins and transformations of India's caste system. Surveying the complex developments over many centuries, it points out that three positions have been taken in this regard. One suggests that the caste one is born into can be transcended within one's lifetime by performing good deeds. The other declares caste to be immutable forever. And, the third says that one can be reborn into a higher caste if one lives a virtuous life. Moving on to the sociopolitical realm, the paper notes how these positions have been used and exploited. The paper then attempts to anchor the existence and purpose of the Hindu caste system in Freud's ideas about group psychology and Klein's proposals of splitting and projective identification. The paper also deploys the large group psychology concepts of Volkan and the culturally nuanced psychoanalytic anthropology of Roland and Kakar. It concludes with delineating some ameliorative strategies for this tragic problem in the otherwise robust democratic society of India.

  11. Singlet exciton fission in polycrystalline pentacene: from photophysics toward devices.

    Science.gov (United States)

    Wilson, Mark W B; Rao, Akshay; Ehrler, Bruno; Friend, Richard H

    2013-06-18

    Singlet exciton fission is the process in conjugated organic molecules bywhich a photogenerated singlet exciton couples to a nearby chromophore in the ground state, creating a pair of triplet excitons. Researchers first reported this phenomenon in the 1960s, an event that sparked further studies in the following decade. These investigations used fluorescence spectroscopy to establish that exciton fission occurred in single crystals of several acenes. However, research interest has been recently rekindled by the possibility that singlet fission could be used as a carrier multiplication technique to enhance the efficiency of photovoltaic cells. The most successful architecture to-date involves sensitizing a red-absorbing photoactive layer with a blue-absorbing material that undergoes fission, thereby generating additional photocurrent from higher-energy photons. The quest for improved solar cells has spurred a drive to better understand the fission process, which has received timely aid from modern techniques for time-resolved spectroscopy, quantum chemistry, and small-molecule device fabrication. However, the consensus interpretation of the initial studies using ultrafast transient absorption spectroscopy was that exciton fission was suppressed in polycrystalline thin films of pentacene, a material that would be otherwise expected to be an ideal model system, as well as a viable candidate for fission-sensitized photovoltaic devices. In this Account, we review the results of our recent transient absorption and device-based studies of polycrystalline pentacene. We address the controversy surrounding the assignment of spectroscopic features in transient absorption data, and illustrate how a consistent interpretation is possible. This work underpins our conclusion that singlet fission in pentacene is extraordinarily rapid (∼80 fs) and is thus the dominant decay channel for the photoexcited singlet exciton. Further, we discuss our demonstration that triplet excitons

  12. Physical properties optimization of polycrystalline LiFeAs

    Science.gov (United States)

    Singh, Shiv J.; Gräfe, Uwe; Beck, Robert; Wolter, Anja U. B.; Grafe, Hans-Joachim; Hess, Christian; Wurmehl, Sabine; Büchner, Bernd

    2016-10-01

    We present a study of parameter optimization for synthesizing truly stoichiometric polycrystalline LiFeAs. Stoichiometric LiFeAs has been prepared in a very broad range of synthesis temperature (200-900 °C) under otherwise exactly the same conditions, and has been characterized by structural, magnetic, transport, nuclear quadrupole resonance (NQR), and specific heat measurements. Our study showed that the LiFeAs phase is formed at 200 °C with a large amount of impurity phases. The amount of these impurity phases reduces with increasing synthesis temperature and the clean LiFeAs phase is obtained at a synthesis temperature of 600 °C. Magnetic susceptibility and resistivity measurements confirmed that the superconducting properties such as the critical temperature Tc, and the upper critical field Hc2 do not depend on the synthesis temperature (≤ 700 °C), remaining at almost the same value of ∼19 K and ∼40 T, respectively. However, the width ΔTc of the transition and the NQR line width decrease with increasing the synthesis temperature and reached to minimum value for the synthesis temperature of 600 °C. Our careful analysis suggests that the best sample obtained at 600 °C is optimal concerning the low resistivity, high residual resistivity ratio (RRR), low ΔTc, high Tc and Hc2, and a small NQR line width with values which are comparable to that reported for LiFeAs single crystals. Specific heat measurements confirmed the bulk superconducting nature of the samples. The Hc2 value estimated from the specific heat is consistent with that of the resistivity measurements. Concisely, 600 °C synthesis temperature yields optimal high quality polycrystalline LiFeAs bulk samples. Further improvement of the quality of the sample prepared at 600 °C could be obtained by a controlled slow cooling process. Microstructural analysis reveals that the abundance of micro-cracks becomes strongly reduced by the slow cooling process, resulting in an increase in clean and

  13. Evidence for electromagnetic granularity in polycrystalline Sm1111 iron-pnictides with enhanced phase purity

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, A [Department of Applied Chemistry, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Jiang, J; Kametani, F; Polyanskii, A; Hellstrom, E; Larbalestier, D [Applied Superconductivity Center, National High Magnetic Field Laboratory, 2031 E. Paul Dirac, Dr., Tallahassee, FL 32310 (United States); Martinelli, A; Palenzona, A; Tropeano, M; Putti, M, E-mail: yamamoto@appchem.t.u-tokyo.ac.jp, E-mail: putti@fisica.unige.it [University of Genova and CNR-SPIN, Via Dodecaneso, 33-I16146 Genova (Italy)

    2011-04-15

    We prepared polycrystalline SmFeAsO{sub 1-x}F{sub x} (Sm1111) bulk samples by sintering and hot isostatic pressing (HIP) in order to study the effects of phase purity and relative density on the intergranular current density. Sintered and HIP processed Sm1111 samples are denser with fewer impurity phases, such as SmOF and the grain boundary wetting phase, FeAs. We found quite complex magnetization behavior due to variations of both the inter and intragranular current densities. Removing porosity and reducing second phase content enhanced the intergranular current density, but HIP processing reduced the intragranular current density, arising from the loss of fluorine and reduction of T{sub c}. We believe that the HIP processed samples are amongst the purest polycrystalline 1111 samples yet made. However, their intergranular current densities are still small, providing further evidence that polycrystalline pnictides, like polycrystalline cuprates, are affected by weak-link problems.

  14. Synthesis and nonlinear optical property of polycrystalline MnTeMoO{sub 6}

    Energy Technology Data Exchange (ETDEWEB)

    Jin, Chengguo [Yibin University, Key Laboratory of Computational Physics of Sichuan Province, Yibin (China); Yibin University, School of Physics and Electronic Engineering, Yibin (China)

    2017-04-15

    Polycrystalline MnTeMoO{sub 6} powder has been synthesized by a new approach that MnO{sub 2} is used as the manganese source. The transformation mechanism of manganese ions in the new approach has been discussed. The nonlinear optical property of polycrystalline MnTeMoO{sub 6} has been investigated, and compared with single-crystalline samples. The transformation Mn{sup 4+} → Mn{sup 2+} may be formed directly without stable intermediates, and TeO{sub 2} may serve as catalyst. The SHG response of polycrystalline MnTeMoO{sub 6} powder is worse than that of single-crystalline powder in the same particle size distribution as its pseudo-size. The results indicate that it should pay special attention with the pseudo-size of polycrystalline powder when the potential nonlinear optical materials are screened by powder second harmonic generation measurements. (orig.)

  15. Synthesis and nonlinear optical property of polycrystalline MnTeMoO6

    Science.gov (United States)

    Jin, Chengguo

    2017-04-01

    Polycrystalline MnTeMoO6 powder has been synthesized by a new approach that MnO2 is used as the manganese source. The transformation mechanism of manganese ions in the new approach has been discussed. The nonlinear optical property of polycrystalline MnTeMoO6 has been investigated, and compared with single-crystalline samples. The transformation Mn4+ → Mn2+ may be formed directly without stable intermediates, and TeO2 may serve as catalyst. The SHG response of polycrystalline MnTeMoO6 powder is worse than that of single-crystalline powder in the same particle size distribution as its pseudo-size. The results indicate that it should pay special attention with the pseudo-size of polycrystalline powder when the potential nonlinear optical materials are screened by powder second harmonic generation measurements.

  16. Study of polycrystalline silicon obtained by aluminum-induced crystallization depending on process conditions

    Science.gov (United States)

    Pereyaslavtsev, Alexander; Sokolov, Igor; Sinev, Leonid

    2016-11-01

    In this paper, we have decided to consider an alternative method of producing polycrystalline silicon and study change of its electrophysical characteristics depending on process parameters. As an alternative low-pressure chemical vapor deposition method appears aluminum-induced crystallization (AIC), which allows to obtain a polycrystalline silicon film is significantly larger grain size, thereby reducing contribution of grain boundaries. A comprehensive study of polycrystalline silicon was carried out using a variety of microscopic (OM, SEM) and spectroscopic (RAMAN, XPS) and diffraction (EBSD, XRD) analytic methods. We also considered possibility of self-doping in AIC, result of which was obtained polycrystalline silicon with different resistance. Additionally considered changes in temperature coefficient of resistance depending on technological parameters of AIC process.

  17. Application of Integrated Database to the Casting Design

    Institute of Scientific and Technical Information of China (English)

    In-Sung Cho; Seung-Mok Yoo; Chae-Ho Lim; Jeong-Kil Choi

    2008-01-01

    Construction of integrated database including casting shapes with their casting design, technical knowledge, and thermophysical properties of the casting alloys were introduced in the present study. Recognition tech- nique for casting design by industrial computer tomography was used for the construction of shape database. Technical knowledge of the casting processes such as ferrous and non-ferrous alloys and their manufacturing process of the castings were accumulated and the search engine for the knowledge was developed. Database of thermophysical properties of the casting alloys were obtained via the experimental study, and the properties were used for .the in-house computer simulation of casting process. The databases were linked with intelligent casting expert system developed in center for e-design, KITECH. It is expected that the databases can help non casting experts to devise the casting and its process. Various examples of the application by using the databases were shown in the present study.

  18. Speciation of europium (III) surface species on monocrystalline alumina using time-resolved laser-induced fluorescence-scanning near-field optical microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Ghaleb, K.A.; Viala, F.; Miserque, F.; Salmon, L. [CEA Saclay, DEN/DANS/DPC/SCP, Lab Reactivite Surface et Interface, F-91191 Gif Sur Yvette, (France); Reiller, P. [CEA Saclay, DEN/DANS/DPC/SECR, Lab Speciat Radionucleides et Mol, F-91191 Gif Sur Yvette, (France); Moutiers, G. [CEA Saclay, DEN/DANS/DPC, Serv Chim Phys, F-91191 Gif Sur Yvette, (France)

    2008-07-01

    The aim of this work was to perform highly localized spectroscopic surface measurements by combining time-resolved laser spectroscopy and scanning near-field optical microscopy. The final purpose of that was to study surface sorption at the molecular level of trivalent ions in the framework of nuclear waste disposal assessment. Time-resolved laser spectroscopy presents the advantages of being selective, sensitive, and noninvasive and scanning near-field optical microscopy is a promising technique for high resolution surface speciation. Investigation of the interaction between trivalent europium and a monocrystalline alumina (11-bar02) surface was made using different conditions of concentration and pH. We found that the distribution of sorbed europium was always homogeneous with a decay time of europium (III) equal to 350 {mu}s {+-} 15 {mu}s. On the other hand, carbonate species with a decay time of 210 {mu}s {+-} 10 {mu}s or other hydroxide species with a decay time of 180 {mu}s {+-} 10 {mu}s were detected on the surface when a higher concentration or a higher pH solution, respectively, were used. Distribution of these species was heterogeneous and their associated fluorescence signal was relatively high, evoking a precipitated form. X-ray photoelectron spectroscopy (XPS) was also used on the same samples as a complementary technique. A binding energy of 1135.1 eV was obtained for the sorbed europium and another binding energy of 1134.4 eV was obtained for the hydroxide species, thus confirming the presence of two kinds of species on the surface. (authors)

  19. Dislocation Structures in Creep-deformed Polycrystalline MgO

    DEFF Research Database (Denmark)

    Bilde-Sørensen, Jørgen

    1972-01-01

    energy of 76 ± 12 kcal/mol. The creep rate is independent of grain size. The dislocation structure was investigated by transmission electron microscopy. The total dislocation density follows the relation, σ=bG√ρ, commonly found for metals. The dislocations form a 3-dimensional network in which many......Secondary creep of polycrystalline MgO with grain sizes of 100 and 190 μm was investigated at 1300° to 1460°C under compressive loads of 2.5 to 5.5 kgf/mm2. The dependence of creep rate on load follows a power law with an exponent of 3.2±0.3. The process is thermally activated, with an activation...... dislocation segments lie in their slip or climb planes. On the basis of this structure, a model is proposed in which glide is the principal cause of deformation but the rate-limiting process, i.e. annealing of the network, is diffusion-controlled. Theoretical estimates and experimental results agree within 1...

  20. Platinum-induced structural collapse in layered oxide polycrystalline films

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jianlin; Liu, Changhui [CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026 (China); Huang, Haoliang [CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026 (China); Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei 230026 (China); Fu, Zhengping; Peng, Ranran, E-mail: pengrr@ustc.edu.cn, E-mail: yllu@ustc.edu.cn [CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026 (China); Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei 230026 (China); Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026 (China); Zhai, Xiaofang [Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei 230026 (China); Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026 (China); Lu, Yalin, E-mail: pengrr@ustc.edu.cn, E-mail: yllu@ustc.edu.cn [CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026 (China); Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei 230026 (China); Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026 (China); Laser and Optics Research Center, Department of Physics, United States Air Force Academy, Colorado 80840 (United States)

    2015-03-30

    Effect of a platinum bottom electrode on the SrBi{sub 5}Fe{sub 1−x}Co{sub x}Ti{sub 4}O{sub 18} layered oxide polycrystalline films was systematically studied. The doped cobalt ions react with the platinum to form a secondary phase of PtCoO{sub 2}, which has a typical Delafossite structure with a weak antiferromagnetism and an exceptionally high in-plane electrical conductivity. Formation of PtCoO{sub 2} at the interface partially consumes the cobalt dopant and leads to the structural collapsing from 5 to 4 layers, which was confirmed by X-ray diffraction and high resolution transmission electron microscopy measurements. Considering the weak magnetic contribution from PtCoO{sub 2}, the observed ferromagnetism should be intrinsic of the Aurivillius compounds. Ferroelectric properties were also indicated by the piezoresponse force microscopy. In this work, the platinum induced secondary phase at the interface was observed, which has a strong impact on Aurivillius structural configuration and thus the ferromagnetic and ferroelectric properties.

  1. HighP–TNano-Mechanics of Polycrystalline Nickel

    Directory of Open Access Journals (Sweden)

    Shen TD

    2007-01-01

    Full Text Available AbstractWe have conducted highP–Tsynchrotron X-ray and time-of-flight neutron diffraction experiments as well as indentation measurements to study equation of state, constitutive properties, and hardness of nanocrystalline and bulk nickel. Our lattice volume–pressure data present a clear evidence of elastic softening in nanocrystalline Ni as compared with the bulk nickel. We show that the enhanced overall compressibility of nanocrystalline Ni is a consequence of the higher compressibility of the surface shell of Ni nanocrystals, which supports the results of molecular dynamics simulation and a generalized model of a nanocrystal with expanded surface layer. The analytical methods we developed based on the peak-profile of diffraction data allow us to identify “micro/local” yield due to high stress concentration at the grain-to-grain contacts and “macro/bulk” yield due to deviatoric stress over the entire sample. The graphic approach of our strain/stress analyses can also reveal the corresponding yield strength, grain crushing/growth, work hardening/softening, and thermal relaxation under highP–Tconditions, as well as the intrinsic residual/surface strains in the polycrystalline bulks. From micro-indentation measurements, we found that a low-temperature annealing (T < 0.4 Tm hardens nanocrystalline Ni, leading to an inverse Hall–Petch relationship. We explain this abnormal Hall–Petch effect in terms of impurity segregation to the grain boundaries of the nanocrystalline Ni.

  2. Polycrystalline-Diamond MEMS Biosensors Including Neural Microelectrode-Arrays

    Directory of Open Access Journals (Sweden)

    Donna H. Wang

    2011-08-01

    Full Text Available Diamond is a material of interest due to its unique combination of properties, including its chemical inertness and biocompatibility. Polycrystalline diamond (poly-C has been used in experimental biosensors that utilize electrochemical methods and antigen-antibody binding for the detection of biological molecules. Boron-doped poly-C electrodes have been found to be very advantageous for electrochemical applications due to their large potential window, low background current and noise, and low detection limits (as low as 500 fM. The biocompatibility of poly-C is found to be comparable, or superior to, other materials commonly used for implants, such as titanium and 316 stainless steel. We have developed a diamond-based, neural microelectrode-array (MEA, due to the desirability of poly-C as a biosensor. These diamond probes have been used for in vivo electrical recording and in vitro electrochemical detection. Poly-C electrodes have been used for electrical recording of neural activity. In vitro studies indicate that the diamond probe can detect norepinephrine at a 5 nM level. We propose a combination of diamond micro-machining and surface functionalization for manufacturing diamond pathogen-microsensors.

  3. Polycrystalline-Diamond MEMS Biosensors Including Neural Microelectrode-Arrays.

    Science.gov (United States)

    Varney, Michael W; Aslam, Dean M; Janoudi, Abed; Chan, Ho-Yin; Wang, Donna H

    2011-08-15

    Diamond is a material of interest due to its unique combination of properties, including its chemical inertness and biocompatibility. Polycrystalline diamond (poly-C) has been used in experimental biosensors that utilize electrochemical methods and antigen-antibody binding for the detection of biological molecules. Boron-doped poly-C electrodes have been found to be very advantageous for electrochemical applications due to their large potential window, low background current and noise, and low detection limits (as low as 500 fM). The biocompatibility of poly-C is found to be comparable, or superior to, other materials commonly used for implants, such as titanium and 316 stainless steel. We have developed a diamond-based, neural microelectrode-array (MEA), due to the desirability of poly-C as a biosensor. These diamond probes have been used for in vivo electrical recording and in vitro electrochemical detection. Poly-C electrodes have been used for electrical recording of neural activity. In vitro studies indicate that the diamond probe can detect norepinephrine at a 5 nM level. We propose a combination of diamond micro-machining and surface functionalization for manufacturing diamond pathogen-microsensors.

  4. Creep behavior for advanced polycrystalline SiC fibers

    Energy Technology Data Exchange (ETDEWEB)

    Youngblood, G.E.; Jones, R.H. [Pacific Northwest National Lab., Richland, WA (United States); Kohyama, Akira [Kyoto Univ. (Japan)] [and others

    1997-08-01

    A bend stress relaxation (BSR) test is planned to examine irradiation enhanced creep in polycrystalline SiC fibers which are under development for use as fiber reinforcement in SiC/SiC composite. Baseline 1 hr and 100 hr BSR thermal creep {open_quotes}m{close_quotes} curves have been obtained for five selected advanced SiC fiber types and for standard Nicalon CG fiber. The transition temperature, that temperature where the S-shaped m-curve has a value 0.5, is a measure of fiber creep resistance. In order of decreasing thermal creep resistance, with the 100 hr BSR transition temperature given in parenthesis, the fibers ranked: Sylramic (1261{degrees}C), Nicalon S (1256{degrees}C), annealed Hi Nicalon (1215{degrees}C), Hi Nicalon (1078{degrees}C), Nicalon CG (1003{degrees}C) and Tyranno E (932{degrees}C). The thermal creep for Sylramic, Nicalon S, Hi Nicalon and Nicalon CG fibers in a 5000 hr irradiation creep BSR test is projected from the temperature dependence of the m-curves determined during 1 and 100 hr BSR control tests.

  5. Preparation and characterization of polycrystalline n-CdSe photoelectrode

    Energy Technology Data Exchange (ETDEWEB)

    Bandyopadhyay, T.K.

    1979-01-01

    Thin layers of polycrystalline p-CdSe were prepared by the simultaneous eletrodeposition of cadmium and selenium from cadmium sulfate and selenious acid in a sulfuric acid solution at pH 0-1 on a titanium substrate. The adherence of the layers to the substrate, stoichiometric ratio of Cd:Se and photovoltaic property of the film depend upon the molar ratio of CdSO/sub 4/ and H/sub 2/SeO/sub 3/ and current density as well as on the pH and temperature of the electrolysis bath. On increasing the current density or the ratio of CdSO/sub 4/:H/sub 2/SeO/sub 3/ in the electrolysis bath, the Cd:Se of the electrodeposit increased. The semiconductor films so prepared were annealed at 550/sup 0/C in a nitrogen atmosphere, followed by etching in an acid solution and then used to construct the photo-electrochemical cell, Ti/CdSe/Na/sub 2/S-Na/sub 2/S/sub x/(aq.)/Pt, and the current-voltage curves have been studied. 11 references.

  6. Light scattering from impurity enhanced liquid layers in polycrystalline ice

    Science.gov (United States)

    Thomson, E. S.; Wettlaufer, J. S.; Wilen, L. A.

    2009-12-01

    Impurity enhanced grain boundary premelting underlies a wide range of geophysical phenomena throughout the cryosphere. In particular, it is known that when water droplets freeze in the atmosphere they are highly polycrystalline and impurities are rejected into grain boundaries. The predicted character and sensitivity of grain boundaries to impurities close to the melting point precludes the use of standard techniques for imaging the interface. Unlike their larger more macroscopic relatives such as veins (3 grain intersections) and nodes (4 grain intersections), grain boundaries do not submit to optical microscopy. However, using an experimental light scattering method grain boundary changes can be measured as a function of thermodynamic variables. Accurate analysis of the light scattering data generated using this method requires a full theory of light propagation through the grain boundary layer straddled by ice crystals. Here we present a theory for light scattering from such a boundary, experimental data using NaCl as a dopant, and dicsuss atmospheric implications from the troposphere to the stratosphere.

  7. Local self-field measurements in Tl-2223 polycrystalline superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Saenz, A. [Univ. de Costa Rica, San Jose (Costa Rica). Escuela de Fisica; Niculescu, H. [Florida Agricultural and Mechanical Univ., Tallahassee, FL (United States). Dept. of Physics; Gielisse, P.J. [Dept. of Mechanical Engineering, Florida State Univ., Tallahassee, FL (United States)

    2000-07-01

    We report local self-field measurements on superconducting (Tl-2223) disks in an applied field. The axial components of the self-field generated by polycrystalline superconductors, have been measured at points above the sample using a Hall probe. The measurements were conducted with a computer controlled precision x-y scanning assembly, at liquid nitrogen temperatures. Single point and two- dimensional distributions of the local self-field above the samples immersed in a homogeneous applied field up to 16 mT, were recorded. In an increasing/decreasing magnetic field the magnetic response of the superconductors traverses hysteresis loops due to inter- and intragranular flux pinning. The field for full flux penetration and the maximum shielded field have been identified from characteristic points on the hysteresis loops. Evaluation of the average intergrain current density j{sub c}, assuming a uniform critical current density, resulted in the value 2.7 x 10{sup 6} A/m{sup 2}. (orig.)

  8. Ultrafast dynamics of exciton fission in polycrystalline pentacene.

    Science.gov (United States)

    Wilson, Mark W B; Rao, Akshay; Clark, Jenny; Kumar, R Sai Santosh; Brida, Daniele; Cerullo, Giulio; Friend, Richard H

    2011-08-10

    We use ultrafast transient absorption spectroscopy with sub-20 fs time resolution and broad spectral coverage to directly probe the process of exciton fission in polycrystalline thin films of pentacene. We observe that the overwhelming majority of initially photogenerated singlet excitons evolve into triplet excitons on an ∼80 fs time scale independent of the excitation wavelength. This implies that exciton fission occurs at a rate comparable to phonon-mediated exciton localization processes and may proceed directly from the initial, delocalized, state. The singlet population is identified due to the brief presence of stimulated emission, which is emitted at wavelengths which vary with the photon energy of the excitation pulse, a violation of Kasha's Rule that confirms that the lowest-lying singlet state is extremely short-lived. This direct demonstration that triplet generation is both rapid and efficient establishes multiple exciton generation by exciton fission as an attractive route to increased efficiency in organic solar cells. © 2011 American Chemical Society

  9. Thermoelectric properties of polycrystalline NiSi3P4

    Science.gov (United States)

    May, Andrew F.; McGuire, Michael A.; Wang, Hsin

    2013-03-01

    The Hall and Seebeck coefficients, electrical resistivity, and thermal conductivity of polycrystalline NiSi3P4 were characterized from 2 to 775 K. Undoped NiSi3P4 behaves like a narrow gap semiconductor, with activated electrical resistivity ρ below room temperature and a large Seebeck coefficient of ˜400 μV/K at 300 K. Attempts to substitute boron for silicon resulted in the production of extrinsic holes, yielding moderately doped semiconductor behavior with ρ increasing with increasing temperature above ˜150 K. Hall carrier densities are limited to approximately 5 × 1019 cm-3 at 200 K, which would suggest the solubility limit of boron is reached if boron is indeed incorporated into the lattice. These extrinsic samples have a Hall mobility of ˜12 cm2/V/s at 300 K, and a parabolic band equivalent effective mass of ˜3.5 times the free electron mass. At 700 K, the thermoelectric figure of merit zT reaches ˜0.1. Further improvements in thermoelectric performance would require reaching higher carrier densities, as well as a mechanism to further reduce the lattice thermal conductivity, which is ˜5 W/m/K at 700 K. Alloying in Ge results in a slight reduction of the thermal conductivity at low temperatures, with little influence observed at higher temperatures.

  10. Distributions of methyl group rotational barriers in polycrystalline organic solids

    Energy Technology Data Exchange (ETDEWEB)

    Beckmann, Peter A., E-mail: pbeckman@brynmawr.edu, E-mail: wangxianlong@uestc.edu.cn [Department of Physics, Bryn Mawr College, 101 North Merion Ave., Bryn Mawr, Pennsylvania 19010-2899 (United States); Conn, Kathleen G. [Department of Physics, Bryn Mawr College, 101 North Merion Ave., Bryn Mawr, Pennsylvania 19010-2899 (United States); Division of Education and Human Services, Neumann University, One Neumann Drive, Aston, Pennsylvania 19014-1298 (United States); Mallory, Clelia W. [Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323 (United States); Department of Chemistry, Bryn Mawr College, 101 North Merion Ave., Bryn Mawr, Pennsylvania 19010-2899 (United States); Mallory, Frank B. [Department of Chemistry, Bryn Mawr College, 101 North Merion Ave., Bryn Mawr, Pennsylvania 19010-2899 (United States); Rheingold, Arnold L. [Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Dr., La Jolla, California 92093-0358 (United States); Rotkina, Lolita [Regional Nanotechnology Facility, Laboratory for Research on the Structure of Matter, University of Pennsylvania, 3231 Walnut Street, Philadelphia, Pennsylvania 19104-6202 (United States); Wang, Xianlong, E-mail: pbeckman@brynmawr.edu, E-mail: wangxianlong@uestc.edu.cn [Key Laboratory for NeuroInformation of Ministry of Education, School of Life Science and Technology, University of Electronic Science and Technology, 4 North Jianshe Rd., 2nd Section, Chengdu 610054 (China)

    2013-11-28

    We bring together solid state {sup 1}H spin-lattice relaxation rate measurements, scanning electron microscopy, single crystal X-ray diffraction, and electronic structure calculations for two methyl substituted organic compounds to investigate methyl group (CH{sub 3}) rotational dynamics in the solid state. Methyl group rotational barrier heights are computed using electronic structure calculations, both in isolated molecules and in molecular clusters mimicking a perfect single crystal environment. The calculations are performed on suitable clusters built from the X-ray diffraction studies. These calculations allow for an estimate of the intramolecular and the intermolecular contributions to the barrier heights. The {sup 1}H relaxation measurements, on the other hand, are performed with polycrystalline samples which have been investigated with scanning electron microscopy. The {sup 1}H relaxation measurements are best fitted with a distribution of activation energies for methyl group rotation and we propose, based on the scanning electron microscopy images, that this distribution arises from molecules near crystallite surfaces or near other crystal imperfections (vacancies, dislocations, etc.). An activation energy characterizing this distribution is compared with a barrier height determined from the electronic structure calculations and a consistent model for methyl group rotation is developed. The compounds are 1,6-dimethylphenanthrene and 1,8-dimethylphenanthrene and the methyl group barriers being discussed and compared are in the 2–12 kJ mol{sup −1} range.

  11. Negative longitudinal electrostriction in polycrystalline ferroelectrics: a nonlinear approach

    Energy Technology Data Exchange (ETDEWEB)

    Turik, A V [Department of Physics, Rostov State University, Zorge 5, 344090 Rostov-on-Don (Russian Federation); Yesis, A A [Institute of Physics, Rostov State University, Stachki 194, 344090 Rostov-on-Don (Russian Federation); Reznitchenko, L A [Institute of Physics, Rostov State University, Stachki 194, 344090 Rostov-on-Don (Russian Federation)

    2006-05-24

    The longitudinal strains {xi}{sub 3} of initially unpoled polycrystalline (ceramic) ferroelectrics having different composition were measured as a function of the electric field strength E. The electric field dependences of the longitudinal piezoelectric coefficients d{sub 33}(E) and longitudinal electrostriction coefficients M{sub 33}(E) were calculated from the virgin {xi}{sub 3}(E) curves and analysed. It was shown that taking into account the polarization nonlinearity (that is, the dependence of dielectric susceptibility on E) leads to nonmonotonic field dependences d{sub 33}(E) and M{sub 33}(E). In a nonlinear system, the electrostrictive effect is due not only to polarization but also to the dependence of dielectric susceptibility on the electric field strength. The large magnitude of the dielectric susceptibility of soft and relaxor ferroelectric ceramics is responsible for the giant electrostriction being positive in low electric fields and negative in strong ones. The possibility of giant negative electrostriction existing has been found for the first time. In strong electric fields, the strain gain has a limitation because of the competition between the positive contribution of the piezoelectric effect and the negative contribution of electrostriction to the strain.

  12. Surface Analysis of 4-Aminothiophenol Adsorption at Polycrystalline Platinum Electrodes

    Science.gov (United States)

    Rosario-Castro, Belinda I.; Fachini, Estevao R.; Contes, Enid J.; Perez-Davis, Marla E.; Cabrera, Carlos R.

    2008-01-01

    Formation of self-assembled monolayer (SAM) of 4-aminothiophenol (4-ATP) on polycrystalline platinum electrodes has been studied by surface analysis and electrochemistry techniques. The 4-ATP monolayer was characterized by cyclic voltammetry (CV), Raman spectroscopy, reflection absorption infrared (RAIR) spectroscopy, and X-ray photoelectron spectroscopy (XPS). Cyclic voltammetry (CV) experiments give an idea about the packing quality of the monolayer. RAIR and Raman spectra for 4-ATP modified platinum electrodes showed the characteristic adsorption bands for neat 4-ATP indicating the adsorption of 4-ATP molecules on platinum surface. The adsorption on platinum was also evidenced by the presence of sulfur and nitrogen peaks by XPS survey spectra of the modified platinum electrodes. High resolution XPS studies and RAIR spectrum for platinum electrodes modified with 4-ATP indicate that molecules are sulfur-bonded to the platinum surface. The formation of S-Pt bond suggests that ATP adsorption gives up an amino terminated SAM. Thickness of the monolayer was evaluated via angle-resolved XPS (AR-XPS) analyses. Derivatization of 4-ATP SAM was performed using 16-Br hexadecanoic acid.

  13. Internal friction and elastic softening in polycrystalline Nb3Sn

    Science.gov (United States)

    Bussière, J. F.; Faucher, B.; Snead, C. L., Jr.; Welch, D. O.

    1981-10-01

    The vibrating-reed technique was used to measure internal friction and Young's modulus of polycrystalline Nb3Sn in the form of composite Nb-Nb3Sn tapes from 6 to 300 K. In tapes with only small residual strain in the A 15 layers, a dramatic increase in internal friction with decreasing temperature is observed with an abrupt onset at ~48 K. The internal friction Q-1 between 6 and 48 K is believed to be associated with stress-induced motion of martensitic-domain walls. In this temperature range, Q-1 is approximately proportional to the square of the tetragonal strain of the martensitic phase; Q-1~(ca-1)2. With residual compressive strains of ~0.2%, the internal friction associated with domain-wall motion is considerably reduced. This is attributed to a biasing of domain-wall orientation with residual stress, which reduces wall motion induced by the (much smaller) applied stress. The transformation temperature, however, is unchanged (within +/- 1 K) by residual strains of up to 0.2%. Young's modulus exhibits substantial softening on cooling from 300 to 6 K. This softening is substantially reduced in the presence of small residual compressive strains, indicating a highly nonlinear stress-strain relationship as previously reported for V 3Si.

  14. High-Efficiency Polycrystalline Thin Film Tandem Solar Cells.

    Science.gov (United States)

    Kranz, Lukas; Abate, Antonio; Feurer, Thomas; Fu, Fan; Avancini, Enrico; Löckinger, Johannes; Reinhard, Patrick; Zakeeruddin, Shaik M; Grätzel, Michael; Buecheler, Stephan; Tiwari, Ayodhya N

    2015-07-16

    A promising way to enhance the efficiency of CIGS solar cells is by combining them with perovskite solar cells in tandem devices. However, so far, such tandem devices had limited efficiency due to challenges in developing NIR-transparent perovskite top cells, which allow photons with energy below the perovskite band gap to be transmitted to the bottom cell. Here, a process for the fabrication of NIR-transparent perovskite solar cells is presented, which enables power conversion efficiencies up to 12.1% combined with an average sub-band gap transmission of 71% for photons with wavelength between 800 and 1000 nm. The combination of a NIR-transparent perovskite top cell with a CIGS bottom cell enabled a tandem device with 19.5% efficiency, which is the highest reported efficiency for a polycrystalline thin film tandem solar cell. Future developments of perovskite/CIGS tandem devices are discussed and prospects for devices with efficiency toward and above 27% are given.

  15. Ebic and Dlts measurements of Si-and polycrystalline silicon

    Energy Technology Data Exchange (ETDEWEB)

    Bary, A.; Hamet, J.F.; Ihlal, A.; Chermant, J.L.; Nouet, G.

    1988-10-01

    Influence of grain boundaries on the electronic properties of silicon has been studied by electron-beam induced current (EBIC), thermally stimulated capacitance (TSCAP) and deep-level transient spectroscopy (DLTS). Low-angle grain boundaries taken from as-grown polycrystalline wafers for solar cells have been analyzed by EBIC and their behaviors have been compared after the junction diffusion treatment. This treatment gives a decrease of the local diffusion length and recombination velocity of the minority carriers. TSCAP and DLTS methods have been applied to a coincidence orientation grain boundary ..sigma..13. These measurements have been made on a gold diffused bicrystal. These results are then compared with those of a bicrystal without gold diffusion. After annealing a narrow interface state continuum appears. On the contrary the gold diffusion prevents the formation of this continuum and only the donor level of gold is detected in the space charge region of the grain boundary (0 - 0.5 ..mu..m). This diffusion of phosphorus or gold can be interpreted as a grain boundary passivation.

  16. The initial interactions of oxygen with polycrystalline titanium surfaces

    Science.gov (United States)

    Azoulay, A.; Shamir, N.; Fromm, E.; Mintz, M. H.

    1997-01-01

    The interactions of gaseous oxygen and different types of polycrystalline titanium surfaces were studied at room temperature within the exposure range of 0-1000 L. Combined measurements utilizing direct recoils spectrometry (DRS), Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), and work function variations enabled the distinction between processes occurring on the topmost atomic layer and those associated with subsurface incorporation of oxygen. Also, the different chemical forms (oxidation states) developing during the exposure course were identified. The results were compared for three types of surfaces, each prepared by a different cleaning procedure. It has been concluded that: (i) Oxygen initially accumulates on the topmost atomic layer, regardless of the type of the studied surface. No preferred subsurface occupation has been observed. (ii) The kinetics of initial accumulation (up to a complete surface coverage) are similar for all the different types of surfaces. (iii) Mixtures of different oxidation states of titanium (0, +2, +3, +4) are present during the whole course of exposure. Qualitatively, increasing proportions of the higher valence states are displayed for higher oxygen exposures. However, the quantitative estimates of their relative amounts indicate a strong dependence on the type of surface, with preferred high oxidation (+4) states obtained for high temperature annealed samples (as compared with room temperature sputtered surfaces). (iv) Topmost oxygen atoms which terminate the oxides surfaces are less negatively charged than the underlying (i.e., subsurface) "oxidic" atoms. These results may account for some of the controversies presented in the literature.

  17. CVD-graphene growth on different polycrystalline transition metals

    Directory of Open Access Journals (Sweden)

    M. P. Lavin-Lopez

    2017-01-01

    Full Text Available The chemical vapor deposition (CVD graphene growth on two polycrystalline transition metals (Ni and Cu was investigated in detail using Raman spectroscopy and optical microscopy as a way to synthesize graphene of the highest quality (i.e. uniform growth of monolayer graphene, which is considered a key issue for electronic devices. Key CVD process parameters (reaction temperature, CH4/H2flow rate ratio, total flow of gases (CH4+H2, reaction time were optimized for both metals in order to obtain the highest graphene uniformity and quality. The conclusions previously reported in literature about the performance of low and high carbon solubility metals in the synthesis of graphene and their associated reaction mechanisms, i.e. surface depositionand precipitation on cooling, respectively, was not corroborated by the results obtained in this work. Under the optimal reaction conditions, a large percentage of monolayer graphene was obtained over the Ni foil since the carbon saturation was not complete, allowing carbon atoms to be stored in the bulk metal, which could diffuse forming high quality monolayer graphene at the surface. However, under the optimal reaction conditions, the formation of a non-uniform mixture of few layers and multilayer graphene on the Cu foil was related to the presence of an excess of active carbon atoms on the Cu surface.

  18. Effect of Some Parameters on the Cast Component Properties in Hot Chamber Die Casting

    Science.gov (United States)

    Singh, Rupinder; Singh, Harvir

    2016-04-01

    Hot chamber die casting process is designed to achieve high dimensional accuracy for small products by forcing molten metal under high pressure into reusable moulds, called dies. The present research work is aimed at study of some parameters (as a case study of spring adjuster) on cast component properties in hot chamber die casting process. Three controllable factors of the hot chamber die casting process (namely: pressure at second phase, metal pouring temperature and die opening time) were studied at three levels each by Taguchi's parametric approach and single-response optimization was conducted to identify the main factors controlling surface hardness, dimensional accuracy and weight of the casting. Castings were produced using aluminium alloy, at recommended parameters through hot chamber die casting process. Analysis shows that in hot chamber die casting process the percentage contribution of second phase pressure, die opening time, metal pouring temperature for surface hardness is 82.48, 9.24 and 6.78 % respectively. While in the case of weight of cast component the contribution of second phase pressure is 94.03 %, followed by metal pouring temperature and die opening time (4.58 and 0.35 % respectively). Further for dimensional accuracy contribution of die opening time is 76.97 %, metal pouring temperature is 20.05 % and second phase pressure is 1.56 %. Confirmation experiments were conducted at an optimal condition showed that the surface hardness, dimensional accuracy and weight of the castings were improved significantly.

  19. Characterization of Technetium Speciation in Cast Stone

    Energy Technology Data Exchange (ETDEWEB)

    Um, Wooyong; Jung, Hun Bok; Wang, Guohui; Westsik, Joseph H.; Peterson, Reid A.

    2013-11-11

    This report describes the results from laboratory tests performed at Pacific Northwest National Laboratory (PNNL) for the U.S. Department of Energy (DOE) EM-31 Support Program (EMSP) subtask, “Production and Long-Term Performance of Low Temperature Waste Forms” to provide additional information on technetium (Tc) speciation characterization in the Cast Stone waste form. To support the use of Cast Stone as an alternative to vitrification for solidifying low-activity waste (LAW) and as the current baseline waste form for secondary waste streams at the Hanford Site, additional understanding of Tc speciation in Cast Stone is needed to predict the long-term Tc leachability from Cast Stone and to meet the regulatory disposal-facility performance requirements for the Integrated Disposal Facility (IDF). Characterizations of the Tc speciation within the Cast Stone after leaching under various conditions provide insights into how the Tc is retained and released. The data generated by the laboratory tests described in this report provide both empirical and more scientific information to increase our understanding of Tc speciation in Cast Stone and its release mechanism under relevant leaching processes for the purpose of filling data gaps and to support the long-term risk and performance assessments of Cast Stone in the IDF at the Hanford Site.

  20. Fe- and Cr-correlated defects in monocrystalline Si:Ga and electrical properties of multicrystalline Si:P; Fe- und Cr-korrelierte Defekte in einkristallinem Si:Ga und elektrische Eigenschaften von multikristallinem Si:P

    Energy Technology Data Exchange (ETDEWEB)

    Beljakowa, S.

    2005-12-05

    Presently silicon (Si)-based solar cells are in general made of boron (B)-doped material. An alternative to B-doped Si is the doping with gallium (Ga) or phosphorus (P). In the framework of this thesis, electrical (Deep Level Transient Spectroscopy (DLTS), Minority Carrier Transient Spectroscopy (MCTS), resistivity topography) and optical (microwave-detected photoconductance decay ({mu}-PCD)) methods are applied to investigate the electrical properties of FeGa- and CrGa-pairs in monocrystalline Si and of P-doped EFG (edge defined film fed growth)-Si. (orig.)

  1. The X-ray Telescope of CAST

    OpenAIRE

    Kuster, M.; Bräuninger, H.; Cébrian, S.; Davenport, M.; Elefteriadis, C.; Englhauser, J.; Fischer, H.; Franz, J.; Friedrich, P.; R. Hartmann; Heinsius, F.H.; Hoffmann, D.H.H.; Hoffmeister, G.; Joux, J. N.; Kang, D.

    2007-01-01

    The Cern Axion Solar Telescope (CAST) is in operation and taking data since 2003. The main objective of the CAST experiment is to search for a hypothetical pseudoscalar boson, the axion, which might be produced in the core of the sun. The basic physics process CAST is based on is the time inverted Primakoff effect, by which an axion can be converted into a detectable photon in an external electromagnetic field. The resulting X-ray photons are expected to be thermally distributed between 1 and...

  2. Characteristics of cast and welded aluminium nodes

    Energy Technology Data Exchange (ETDEWEB)

    Oedegaard, J.; Polanco, M.; Syvertsen, F.; Sund, H. [SINTEF, Trondheim (Norway). Materials Technology

    2000-07-01

    It has been demonstrated that sand cast aluminium nodes can be produced with properties that gives competitive energy absorption capacity compared with welded aluminium nodes. Sand cast nodes could be mass-produced to a low cost and with properties that should be competitive to the properties of fusion welded nodes. This may open for simpler and more cost-effective joint alternatives when production of aluminium space-frames and subassemblies are in focus. Cast nodes joined to extruded members by adhesive bonding could be one example. (orig.)

  3. PHYSICAL SIMULATION OF CONTINUOUS ROLL CASTING PROCESS

    Institute of Scientific and Technical Information of China (English)

    L.H. Zhan; J. Zhong; X.Q. Li; M.H. Huang

    2005-01-01

    A series of simulating experimental studies on the rheological behavior and its influential factors of aluminum alloy in continuous roll-casting process have been explored in this paper with a Gleeble-1500 Thermal-Mechanical Simulation Tester and a set of special clamp system. Relevant rheological rules in the process of coupling transient solidification and continuous deformation of roll-casting conditions are obtained. Experimental results indicate that four different characteristic stages exist in the whole rheological process, and relative constitutive models suitable for the given conditions of continuous roll casting process have been established through multivariable linear regression analysis of the experimental data.

  4. CAST with its micromegas detector installed.

    CERN Multimedia

    Maximilien Brice

    2002-01-01

    The CERN Axion Solar Telescope (CAST) uses a prototype LHC dipole magnet to search for very weakly interacting neutral particles called axions, which should originate in the core of the Sun. The magnet converts the solar axions to photons which are then detected by an X-ray detector based on Micromegas technology. CAST's Micromegas detector has now been installed. Photos 01 02: General view of the CAST experiment with the Micromegas detector in place. Photo 03: Close-up of the micromegas set-up.

  5. Optimization of the Chemical Composition of Cast Iron Used for Casting Ball Bearing Grinding Disks

    Institute of Scientific and Technical Information of China (English)

    Aurel Crisan; Sorin Ion; Munteanu; Ioan Ciobanu; Iulian Riposan

    2008-01-01

    The chemical composition of cast iron used for casting ball bearing machining disks was varied to optimize the properties such as castability, hardenability, and durability in ball machining. The cast iron characteristics were most strongly dependent on the Ni content and the carbon saturation degree, So. This paper describes the types of test specimens, the working conditions, and the experimental results. The in-crease of the degree of carbon saturation reduces the tendency to form shrinkholes in the castings. The de-crease in the Ni content negatively affects the final hardening treatment. A way to control solidification de-fects in cast iron, by reducing the Ni content, has been verified on cast disks.

  6. The structure of abrasion-resisting castings made of chromium cast iron

    Directory of Open Access Journals (Sweden)

    D. Kopyciński

    2011-01-01

    Full Text Available In this study presents the analyse of chrome iron cast structure (as-cast condition which are used in rugged conditions abrasion-percussive and high temperature. While producing the casts of chrome iron major influence has been preserve the structure of technologi cal process parameters. The addition to Fe-C-Cr alloy Ni, Mo or Cu and then proper heat treatment leads to the improvement of functional and mechanical cast qualities. Then it is possible to develop high mechanical properties which are recommended by PN-EN12513. As can it be seen from the above research silicon is an adverse chemical element in this kind of alloy cast iron. However, the reason of cracksappearing in chrome iron casts are phosphorus eutectic microareas. When the compound of Si and P reach the critical point, described inPN-88/H-83144 outdated standard, the microareas might appear.

  7. Exothermic properties of plaster-synthetic composite casts.

    Science.gov (United States)

    Burghardt, Rolf D; Anderson, John G; Reed, Rob A; Herzenberg, John E

    2014-03-01

    Plaster casts can cause burns. Synthetic casts do not. Composite plaster-synthetic casts have not been thoroughly evaluated. This study analyzed the temperature from plaster casts compared with composite casts in a variety of in vitro conditions that would simulate clinical practice. A Pyrex cylinder filled with constant body temperature circulating water simulated a human extremity. Circumferential casts, of either plaster or composite construction (plaster inner layer with outer synthetic layer), were applied to the model. Peak temperatures generated by the exothermic reactions were studied relative to the following variables: dip water temperature (24 °C versus 40 °C), cast thickness (16, 30, and 34 ply), and delayed (5-min) versus immediate application of the synthetic outer layers. Peak temperatures from the all-plaster casts were compared with the composite casts of the same thickness. Finally, the relative cast strength was determined. Potentially dangerous high temperatures were measured only when 40 °C dip water was used or when thick (30- or 34-ply) casts were made. Cast strength increased with increasing cast thickness. However, the presence of synthetics in the composite casts layers did not increase cast strength in every case. When applying composite casts, the outer synthetic layers should be applied several minutes after the plaster to minimize temperature rise. Composite casts do not routinely generate peak temperatures higher than plaster casts of similar thickness. Because the skin of children and the elderly is more temperature-sensitive than average adult skin, extra care should be taken to limit the exothermic reaction when casting children and the elderly: clean, room temperature dip water, minimal required cast thickness, avoidance of insulating pillows/blankets while the cast is drying.

  8. 49 CFR 192.275 - Cast iron pipe.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false Cast iron pipe. 192.275 Section 192.275... Cast iron pipe. (a) Each caulked bell and spigot joint in cast iron pipe must be sealed with mechanical leak clamps. (b) Each mechanical joint in cast iron pipe must have a gasket made of a...

  9. Laboratory grey cast iron continuous casting line with electromagnetic forced convection support

    OpenAIRE

    2010-01-01

    The article describes the construction of a 20 mm diameter grey cast iron ingots continuous casting laboratory line. This line is made ofthree main units: melting unit (induction furnace), casting unit and the pulling unit. In order to improve the homogeneity of themicrostructure of ingots (by applying forced convection of liquid metal during the crystallization process) in this case a crystallizer system generating the forced movement of liquid metal based on a system of electrical power win...

  10. Dimensional accuracy of small gold alloy castings. Part 4. The casting ring and ring liners.

    Science.gov (United States)

    Morey, E F

    1992-04-01

    The role of the casting ring and its asbestos liner is discussed. Asbestos as a liner has now largely been replaced by two alternative materials, one based on cellulose and the other on ceramic fibres. The limited literature on the effect of these newer materials on casting accuracy is also reviewed as their introduction may require significant changes in the traditional technology of dental casting.

  11. Structural, optical and electrical properties of indium nitride polycrystalline films

    Energy Technology Data Exchange (ETDEWEB)

    Silva, M.V.S. da, E-mail: marcus.sansil@gmail.com [Instituto de Fisica, UFBA, Campus Ondina, 40210-340, Salvador (Brazil); David, D.G.F.; Pepe, I.; Ferreira da Silva, A.; Almeida, J.S. de [Instituto de Fisica, UFBA, Campus Ondina, 40210-340, Salvador (Brazil); Gazoto, A.L. [Instituto de Fisica Gleb Wataghin (IFGW), UNICAMP, 13083-859, Campinas, SP (Brazil); Santos, A.O. dos [Instituto de Fisica Gleb Wataghin (IFGW), UNICAMP, 13083-859, Campinas, SP (Brazil); CCSST, Universidade Federal do Maranhao, 65900-410 Imperatriz, MA (Brazil); Cardoso, L.P.; Meneses, E.A. [Instituto de Fisica Gleb Wataghin (IFGW), UNICAMP, 13083-859, Campinas, SP (Brazil); Graybill, D.L. [75 Logan Street Brooklyn, NY 11208 (United States); Mertes, K.M. [Los Alamos National Laboratory, Los Alamos, NM 8754 (United States)

    2012-05-31

    The structural, optical and electrical properties of InN polycrystalline films on glass substrate are investigated by means of X-ray photoelectron spectroscopy, Raman scattering measurements, X-ray diffraction analysis, optical spectroscopy, and electrical measurements as a function of the inverse of temperature. The absorption edge for the films is most likely due to an impurity band formed by the presence of defects in the material. Such an impurity band, located at 1.6 eV extends itself to about 1.8 eV above the Fermi level, and it is attributed to nitrogen vacancies present in the material. The Raman scattering data also reveal the incorporation of oxygen in the InN films, leading to the formation of the In{sub 2}O{sub 3} amorphous phase during the process of sputtering. Additionally, the X-ray photoelectron spectroscopy of the valence band, which is highly desirable to the determination of the Fermi level, confirms the optical gap energy. Furthermore, the X-ray diffraction patterns of the thinner films present broader peaks, indicating high values for the strain between the film lattice and the glass substrate. Finally, first principles calculations are used to investigate the optical properties of InN and also to support the experimental findings. - Highlights: Black-Right-Pointing-Pointer InN thin films with different thicknesses and good quality were synthesized. Black-Right-Pointing-Pointer Semiconductor behavior and some contamination by In{sub 2}O{sub 3} were found. Black-Right-Pointing-Pointer The band gap was close to 1.8 eV compared to 0.7 eV found in pure InN. Black-Right-Pointing-Pointer The electronic structure for this material was determined.

  12. Fundamentals of polycrystalline thin film materials and devices

    Energy Technology Data Exchange (ETDEWEB)

    Baron, B.N.; Birkmire, R.W.; Phillips, J.E.; Shafarman, W.N.; Hegedus, S.S.; McCandless, B.E. (Delaware Univ., Newark, DE (USA). Inst. of Energy Conversion)

    1991-01-01

    This report presents the results of a one-year research program on polycrystalline thin-film solar cells. The research was conducted to better understand the limitations and potential of solar cells using CuInSe{sub 2} and CdTe by systematically investigating the fundamental relationships linking material processing, material properties, and device behavior. By selenizing Cu and In layers, we fabricated device-quality CuInSe{sub 2} thin films and demonstrated a CuInSe{sub 2} solar cell with 7% efficiency. We added Ga, to increase the band gap of CuInSe{sub 2} devices to increase the open-circuit voltage to 0.55 V. We fabricated and analyzed Cu(InGa)Se{sub 2}/CuInSe{sub 2} devices to demonstrate the potential for combining the benefits of higher V{sub oc} while retaining the current-generating capacity of CuInSe{sub 2}. We fabricated an innovative superstrate device design with more than 5% efficiency, as well as a bifacial spectral-response technique for determining the electron diffusion length and optical absorption coefficient of CuInSe{sub 2} in an operational cell. The diffusion length was found to be greater than 1 {mu}m. We qualitatively modeled the effect of reducing heat treatments in hydrogen and oxidizing treatments in air on the I-V behavior of CuInSe{sub 2} devices. We also investigated post-deposition heat treatments and chemical processing and used them to fabricate a 9.6%-efficient CdTe/CdS solar cell using physical vapor deposition.

  13. Structural evolution and mechanisms of fatigue in polycrystalline brass

    Energy Technology Data Exchange (ETDEWEB)

    Vejloe Carstensen, J

    1998-03-01

    The plastic strain controlled fatigue behaviour of polycrystalline Cu-15%Zn and Cu-30%Zn has been investigated with the aim of studying the effect of slip mode modification by the addition of zinc to copper. It has been clearly demonstrated, that true cyclic saturation does not occur in the plastic strain controlled fatigue of brass. This complicates the contstruction of a cyclic stress-strain (CSS) curve and thus the comparison with copper. A method to overcome this complication has been suggested. Surface observations on fatigued brass specimens show that individual grains tend to deform by Sachs type single slip. This behaviour has been described by the self-consistent Sachs-Eshelby model, which provides estimates of the CSS curve for brass polycrystals. Successive stages of primary hardening, softening and secondary hardening has been observed in the plastic strain controlled fatigue of brass. It has been found that the primary hardening is attributed to an increase of intergranular stresses whereas the secondary hardening apparently is attributed to an increase of friction stresses. Investigations of the structural evolution show that the softening behaviour can be explained by the presence of short-range order (SRO). SRO promote the formation of extended dipole arrays which hardens the material. The formation of intense shear bands destroy the dipole arrays, which explains the cyclic softening. The present results reveal that Cu-30%Zn in a pure planar slip alloy, while Cu-15%Zn displays both planar and wavy slip. The mechanical and structural behaviour observed in brass resembles recent observations in 316L austenitic stainless steels, and the present results reveal that Cu-30%Zn and 316L have approximately the same fatigue life curve. This emphasizes brass as being a convenient model system for the industrially important austenitic steels. (au) 9 tabs., 94 ills., 177 refs.; The thesis is also available as DCAMM-R-S80 and as an electronic document on http://www.risoe.dk/rispubl

  14. Investigations of Protective Coatings for Castings of High-manganese Cast Steels

    Directory of Open Access Journals (Sweden)

    M. Holtzer

    2013-01-01

    Full Text Available When cast steel castings are made in moulding sands on matrices of high-silica sand, which has a low fire resistance the problem of theso-called chemical penetration is distinctly visible. Whereas this effect appears to a small degree only when moulding sand matrices are of chromite, zircon or olivine sands. Therefore in case of making castings of high-manganese cast steel (e.g. Hadfield steel sands not containing free silica should be applied (e.g. olivine sand or in case of a high-silica matrix protective coatings for moulds and cores should be used. Two protective coatings, magnesite alcoholic (marked as coating 1 and coating 2 originated from different producers and intended for moulds for castings of the Hadfield steel, were selected for investigations. Examinations of the basic properties were performed for these coatings: viscosity, thermal analysis, sedimentation properties, wear resistance. In order to estimate the effectiveness of protective coatings the experimental castings were prepared. When applying coating 1, the surface quality of the casting was worse and traces of interaction between the casting material (cast steel and the coating were seen. When protective coating 2 was used none interactions were seen and the surface quality was better.

  15. Centrifugal Casting of High Speed Steel/Nodular Cast Iron Compound Roll Collar

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The centrifugal casting of compound HSS/nodular cast iron roll collar was studied, and the factors affecting transition zone quality were analyzed. The pouring temperature and interval in pouring are the main factors affecting transition zone quality. By controlling process parameter and flux adding during casting, high quality roll collar was obtained. The cause, why in the casting of HSS part, segregation appears easily, was analyzed and the countermeasure eliminating segregation was put forward, the measure eliminating heat treatment crackling was also put forward.

  16. Genetic structure of Rajaka caste and affinities with other caste populations of Andhra Pradesh, India.

    Science.gov (United States)

    Parvatheesam, C; Babu, B V; Babu, M C

    1997-01-01

    The present study gives an account of the genetic structure in terms of distribution of a few genetic markers, viz., A1A2B0, Rh(D), G6PD deficiency and haemoglobin among the Rajaka caste population of Andhra Pradesh, India. The genetic relationships of the Rajaka caste with other Andhra caste populations were investigated in terms of genetic distance, i.e., Sq B (mn) of Balakrishnan and Sanghvi. Relatively lesser distance was established between the Rajaka and two Panchama castes. Also, the pattern of genetic distance corroborates the hierarchical order of the Hindu varna system.

  17. Advanced lost foam from casting technology

    Energy Technology Data Exchange (ETDEWEB)

    Bates, C. E.; Littleton, H. E.; Askeland, D.; Griffin, J.; Miller, B. A.; Sheldon, D. S.

    1996-05-01

    Previous research made significant advances in understanding the Lost Foam Casting (LFC) Process and clearly identified areas where additional research was needed to improve the process and make it more functional in an industrial environment. The current project focused on five areas listed as follows: Task 1: Precision Pattern Production Task 2: Pattern Coating Consistency Task 3: Sand Fill and Compaction Effects Task 4: Pattern Gating Task 5: Mechanical Properties of Castings. This report summarizes the work done under the current contract in all five areas in the period of October 1, 1994 through December 31, 1995. Twenty-eight (28) companies jointly participate in the project. These companies represent a variety of disciplines, including pattern designers, pattern producers, coating manufacturers, plant design companies, compaction equipment manufacturers, casting producers, and casting buyers.

  18. Ambiguous chairs cast in fabric formed concrete

    DEFF Research Database (Denmark)

    Manelius, Anne-Mette

    2009-01-01

    On the basis of a specific experiment with a new casting technique for concrete structures, this paper discusses explorations of materiality as a way of generating discussion of the use of new technologies....

  19. Rare Earth Additions in Continuously Cast Steel

    Science.gov (United States)

    Wilson, William G.; Heaslip, L. J.; Sommerville, I. D.

    1985-09-01

    Rare earth (lanthanide metals) addiiions to continuously cast steel are particularly advantageous because of their ability to refine as-cast structures, reduce segregation and increase hot ductility at temperatures just below that of solidification. The complete shape control of sulfides in steels containing Rare Earth Metals (REM), whether continuously cast or ingot cast, is primarily responsible for improvements in ductility related mechanical properties, weldability, fatigue resistance and resistance to hydrogen damage. Complete sulfide shape control can be obtained with REM additions at sulfur levels as high as.020%. The greatest improvements, however, are obtained with REM additions to low sulfur steels. However, to achieve full operational advantages afforded by REM, nozzle blockage problems must be circumvented. Water model studies indicate a possible solution.

  20. ToxCast/ToxRefDB

    Data.gov (United States)

    U.S. Environmental Protection Agency — ToxCast is used as a cost-effective approach for efficiently prioritizing the toxicity testing of thousands of chemicals. It uses data from state-of-the-art high...

  1. Alumina Carbon Refractory Products for Continuous Casting

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    @@ 1 Scope This standard specifies the classification.techni-cal requirements,test methods,inspection rules,packing,marking,transportation,storage and quality certificate of alumina carbon refractory products for continuous casting.

  2. Caste in India, Past and Present

    Science.gov (United States)

    Bishop, Donald H.

    1971-01-01

    Traced is the sociocultural framework for the system in Indian culture which emphasized duty and obligations rather than individual freedom and rights. Also discussed are contemporary changes in the caste system. (DB)

  3. Theory of uniqueness of Indian Caste System

    Directory of Open Access Journals (Sweden)

    Ashwin Kumar

    2006-08-01

    Full Text Available Classical studies on pre-modern Indian social structure have suggested apparent differences between the Indian caste system and social stratification as one can discern in other parts of the world. However, one needs to question such dogmatic assertions that such vast differences really existed. An endeavor is made in this research paper to reflect on the nature of caste hierarchy in pre-modern India. The caste system forms the significant basis of pre-modern Indian social structure. Early writers conceived the caste system of pre-modern India as something unique to India. An attempt is made to question this application of theory of uniqueness in the case of India.

  4. Theory of uniqueness of Indian Caste System

    Directory of Open Access Journals (Sweden)

    Ashwin Kumar

    2005-11-01

    Full Text Available Classical studies on pre-modern Indian social structure have suggested apparent differences between the Indian caste system and social stratification as one can discern in other parts of the world. However, one needs to question such dogmatic assertions that such vast differences really existed. An endeavor is made in this research paper to reflect on the nature of caste hierarchy in pre-modern India. The caste system forms the significant basis of pre-modern Indian social structure. Early writers conceived the caste system of pre-modern India as something unique to India. An attempt is made to question this application of theory of uniqueness in the case of India.

  5. Cast Care: Do's and Don'ts

    Science.gov (United States)

    ... has a fiberglass cast that's lined with a water-repellent liner, it's probably OK for him or her ... opportunities Reprint Permissions A single copy of these materials may be reprinted for noncommercial personal use only. " ...

  6. Friction Stir Processing of Cast Superalloys Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This SBIR Phase I effort examines the feasibility of an innovative fabrication technology incorporating sand casting and friction stir processing (FSP) for producing...

  7. Casting Technology Development for SFR Metallic Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Lee, C.T.; Oh, S.J.; Ryu, H.J.; Kim, K.H.; Lee, Y.S.; Kim, S.K.; Woo, Y.M.; Ko, Y.M.; Lee, C.B. [KAERI, 150 Deokjin-dong, Yuseong, Daejeon, 305-353 (Korea, Republic of)

    2009-06-15

    Fabrication technology of metallic fuel for sodium fast reactor (SFR) is being developed in Korea as a national mid- and long-term nuclear R and D program from 2007. The metallic fuel for SFR should be remotely fabricated under a radiation shielded environment such as a glove box or hot cell, because it contains long-lived minor actinides such as Np, Am and Cm. In order to design a reliable remote fabrication system, various casting techniques have been studied by using U-Zr and U-Zr-RE alloys as surrogate fuel material. Rare earth elements such as Ce or Nd were used as a surrogate for minor actinide elements or solid solution fission products. Macro-scale soundness, microstructures and compositional homogeneity of metallic fuel samples fabricated by vacuum-assisted injection casting, vacuum-assisted gravity casting, centrifugal atomization and continuous casting were compared. Although sound slugs of U-Zr metallic fuel of 4{approx}6 mm in diameter could be fabricated by vacuum-assisted injection casting or vacuum-assisted gravity casting, it was necessary to consider that vaporization of Am and volume of radioactive wastes such as crucibles and molds should be minimized. Effects of casting parameters on the volatile loss, and effects of coatings on the chemical reaction between metallic fuel and molds are discussed. Some methods to reduce the volatile Am loss and waste molds and crucibles will be proposed. Short rods of U-Zr or U-Zr-Ce fuel will be fabricated by the vacuum-assisted gravity casting technique for an irradiation test in the HANARO research reactor from 2010. (authors)

  8. Casting Process Developments for Improving Quality

    Science.gov (United States)

    El-Mahallawy, Nahed A.; Taha, Mohamed A.

    1985-09-01

    This paper presents a short synopsis of the important developments in casting/solidification processes, as well as the important advances in the conventional methods. These developments are discussed related to quality aspects. The position of each process with respect to practice, as well as expected gains in cost, are examined. The paper briefly features the author's work on innovative processes (directional solidification, rheocasting, squeeze-casting and rapid solidification) as well as work of other investigators on developments in conventional methods.

  9. CAST Xi'an Branch Established

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    @@ China Academy of Space Technology (CAST) Xi'an Branch was established on April 8,2008.The new branch consists of the headquarters of the former Xi'an Institute of Space Radio Technology (XISRT) of CAST and five former subsidiaries of the XISRT,i.e.the Institute of Space Electronic Technology,the Institute of Microwave Technology,the Institute of Space Antenna Technology,the Manufacturing Center for Space Electronics and Civilian High-tech Company.

  10. Combination Of Investment And Centrifugal Casting

    Science.gov (United States)

    Creeger, Gordon A.

    1994-01-01

    Modifications, including incorporation of centrifugal casting, made in investment-casting process reducing scrap rate. Used to make first- and second-stage high-pressure-fuel-turbopump nozzles, containing vanes with thin trailing edges and other thin sections. Investment mold spun for short time while being filled, and stopped before solidification occurs. Centrifugal force drives molten metal into thin trailing edges, ensuring they are filled. With improved filling, preheat and pour temperatures reduced and solidification hastened so less hot tearing.

  11. Strip Casting of High Performance Structural Alloys

    Institute of Scientific and Technical Information of China (English)

    S S Park; J G Lee; Nack J Kim

    2004-01-01

    There exists a great need for the development of high performance alloys due to increasing demands for energy conservation and environmental protection. Application of strip casting shows a strong potential for the improvement of properties of existing alloys and also for the development of novel alloy systems with superior properties. The present paper reviews our Center's activities in the development of high performance alloys by strip casting. Examples include (1) Al alloys, (2) wrought Mg alloys, and (3) bulk metallic glass (BMG) alloys.

  12. Fabrication of bulk metallic glasses by centrifugal casting method

    OpenAIRE

    R. Nowosielski; R. Babilas

    2007-01-01

    Purpose: The aim of the present work is characterization of the centrifugal casting method, apparatus andproduced amorphous materials, which are also known as bulk metallic glassesDesign/methodology/approach: The studied centrifugal casting system consists of two main parts: castingapparatus and injection system of molten alloy. The described centrifugal casting method was presented bypreparing a casting apparatus “CentriCast – 5”. The apparatus includes a cylindrical copper mold, which isrot...

  13. Microbiological Study of Cast Posts before Cementation

    Science.gov (United States)

    Ojeda-Garces, Juan Carlos

    2017-01-01

    This study identifies the most common microorganisms present in type III gold cast posts related to pulpal disease and evaluates the sterilization/disinfection method before cementation in the root canal. Forty-five type III gold cast posts were aseptically collected in sterile sealed plastic bags and taken to the microbiology laboratory to carry out the study: fifteen cast posts had no treatment, fifteen were disinfected (immersion in 70% alcohol during 15 minutes), and fifteen were autoclaved at 121°C for 15 minutes by using saturated steam under 15 psi pressure. By using a two-proportion z-test, the difference was statistically significant (p > 0.05) and demonstrates that, in spite of the aseptic pattern used in the cast post collection and laboratory procedures, some cast posts arrive contaminated at the consulting office. The disinfection process worked out in a high percentage and demonstrated that the sterilization by autoclaving eliminated completely the pathogenic microbiota without affecting the cast post shape and integrity that could compromise their final fitting.

  14. Microbiological Study of Cast Posts before Cementation

    Directory of Open Access Journals (Sweden)

    Maricela Vallejo-Labrada

    2017-01-01

    Full Text Available This study identifies the most common microorganisms present in type III gold cast posts related to pulpal disease and evaluates the sterilization/disinfection method before cementation in the root canal. Forty-five type III gold cast posts were aseptically collected in sterile sealed plastic bags and taken to the microbiology laboratory to carry out the study: fifteen cast posts had no treatment, fifteen were disinfected (immersion in 70% alcohol during 15 minutes, and fifteen were autoclaved at 121°C for 15 minutes by using saturated steam under 15 psi pressure. By using a two-proportion z-test, the difference was statistically significant (p>0.05 and demonstrates that, in spite of the aseptic pattern used in the cast post collection and laboratory procedures, some cast posts arrive contaminated at the consulting office. The disinfection process worked out in a high percentage and demonstrated that the sterilization by autoclaving eliminated completely the pathogenic microbiota without affecting the cast post shape and integrity that could compromise their final fitting.

  15. Latest results of cast and future prospects

    CERN Document Server

    Vafeiadis, Theodoros

    2014-01-01

    CERN Axion Solar Telescope (CAST) is currently the most sensitive axion helioscope designed to search for axions and axion-like particles produced in the Sun. CAST completed successfully the second part of CAST phase II where the magnet bores were lled with 3He gas at variable pressure scanning axion masses up to 1.2 eV In the absence of signal it has set the best experimental limit on the axion-photon coupling constant over a broad range of axion masses. In 2013 CAST has improved its sensitivity to solar axions with rest mass below 0.02 eV by upgrading the Micromegas detectors and it will continue in 2014 with the implementation of a second X-ray optic and a new type detector (InGRID). In addition, CAST has extended its sensitivity into the sub-keV energy range using a silicon detector (SDD), to search for solar chameleons. Thus, CAST also became sensitive to dark energy particles. A new generation axion helioscope (IAXO) aims to improve the current axion-photon coupling by 1-1.5 orders of magnitude. This wi...

  16. Low Background Micromegas in CAST

    CERN Document Server

    Garza, J G; Aznar, F.; Calvet, D.; Castel, J.F.; Christensen, F.E.; Dafni, T.; Davenport, M.; Decker, T.; Ferrer-Ribas, E.; Galán, J.; García, J.A.; Giomataris, I.; Hill, R.M.; Iguaz, F.J.; Irastorza, I.G.; Jakobsen, A.C.; Jourde, D.; Mirallas, H.; Ortega, I.; Papaevangelou, T.; Pivovaroff, M.J.; Ruz, J.; Tomás, A.; Vafeiadis, T.; Vogel, J.K.

    2015-01-01

    Solar axions could be converted into x-rays inside the strong magnetic field of an axion helioscope, triggering the detection of this elusive particle. Low background x-ray detectors are an essential component for the sensitivity of these searches. We report on the latest developments of the Micromegas detectors for the CERN Axion Solar Telescope (CAST), including technological pathfinder activities for the future International Axion Observatory (IAXO). The use of low background techniques and the application of discrimination algorithms based on the high granularity of the readout have led to background levels below 10$^{-6}$ counts/keV/cm$^2$/s, more than a factor 100 lower than the first generation of Micromegas detectors. The best levels achieved at the Canfranc Underground Laboratory (LSC) are as low as 10$^{-7}$ counts/keV/cm$^2$/s, showing good prospects for the application of this technology in IAXO. The current background model, based on underground and surface measurements, is presented, as well as ...

  17. Last cast for the LHC

    CERN Multimedia

    2005-01-01

    The first major contract signed for the LHC is drawing to a close. Belgian firm Cockerill Sambre (a member of the Arcelor Group) has just completed production of 50,000 tonnes of steel sheets for the accelerator's superconducting magnet yokes, in what has proved to be an exemplary partnership with CERN. Philippe Lebrun, Head of the AT Department, Lyn Evans, LHC Project Leader, and Lucio Rossi, Head of the AT-MAS Group, in front of the last batch of steel for the LHC at Cockerill Sambre. It was a bright red-letter day at the end of May, when Belgian firm Cockerill Sambre of the Arcelor Group marked the completion of one of the largest contracts for the LHC machine by casting the last batch of steel sheets for the LHC superconducting magnet yokes in the presence of LHC Project Leader Lyn Evans, AT Department Head Philippe Lebrun, Magnets and Superconductors (AT-MAS) Group Leader Lucio Rossi and Head of the AT-MAS Group's components centre Francesco Bertinelli. The yokes constitute approximately 80% of the acc...

  18. 高温合金精密铸造技术研究进展%The Progress of Investment Casting of Nickel-Based Superalloys

    Institute of Scientific and Technical Information of China (English)

    刘林

    2012-01-01

    This paper reviews the principle, techniques, research statues and current problems of major processing technologies of casi superalloys, such as polycrystalline casting, directional solidification, single-crystal manufacture. The cast structure control and crystal orientation selection during solidification were analyzed. Single-crystal processing including bottom-seeding and spiral selection technique was summarized. The formation mechanism and control methods of typical cast defects in single crystal superalloys were analyzed. Finally, the possible development trends of the superalloy investment casting in future were prospected.%综述了高温合金多晶铸造、定向凝固、单晶制备等几种主要制备技术的原理、方法、研究现状和存在问题,分析了铸造高温合金晶粒组织控制、晶体取向选择和控制,介绍了单晶叶片的引晶和选晶原理和技术,对单晶铸造高温合金的缺陷进行了分析,并展望了高温合金精密铸造的今后发展方向.

  19. Effect of grain size on optical transmittance of birefringent polycrystalline ceramics

    Science.gov (United States)

    Wen, Tzu-Chien

    Polycrystalline ceramics are increasingly used for fabricating windows and domes for the mid infra-red regime (3-5 mum) due to their superior durability as compared to glass and the lower cost of their fabrication and finishing relative to single crystals without significant compromise in optical properties. Due to the noncubic structure, MgF2 and Al2O3 are birefringent ceramics. Birefringence causes scatter of light at the grain boundaries and diminishes in-line transmittance and optical performance. This dissertation presents experimental results and analyses of the grain-size and wavelength dependence of the in-line transmittance of polycrystalline MgF2 and Al2O3. Chapter 2 presents experimental results and analyses of light transmission in polycrystalline MgF2 as a function of the mean grain size at different wavelengths. The scattering coefficient of polycrystalline MgF 2 increased linearly with the mean grain size and inversely with the square of the wavelength of light. These trends are consistent with theoretical models based on both a limiting form of the Raleigh-Gans-Debye theory of particle scattering and light retardation theories that take refractive-index variations along the light path. Chapter 3 investigates the applicability of particle light scattering theories to light attenuation in birefringent polycrystalline ceramics by measuring light transmittance in a model two-phase system. The system consisted of microspheres of silica dispersed in a solution of glycerol in water. It was found that RGD theory showed the systematic deviation for higher particle volume fraction (φ > 0.2) and larger particle size (d p > 1 mum). This result suggested that light scattering models based on single particle scattering are unlikely to provide viable physical explanation for the effect of grain size on light transmittance in birefringent polycrystalline ceramics due to the high volume fraction in dense polycrystalline ceramics. Chapter 4 analyses light

  20. A comparative study of transport properties in polycrystalline and epitaxial chromium nitride films

    KAUST Repository

    Duan, X. F.

    2013-01-08

    Polycrystalline CrNx films on Si(100) and glass substrates and epitaxial CrNx films on MgO(100) substrates were fabricated by reactive sputtering with different nitrogen gas flow rates (fN2). With the increase of fN2, a lattice phase transformation from metallic Cr2N to semiconducting CrN appears in both polycrystalline and epitaxial CrNx films. At fN2= 100 sccm, the low-temperature conductance mechanism is dominated by both Mott and Efros-Shklovskii variable-range hopping in either polycrystalline or epitaxial CrN films. In all of the polycrystalline and epitaxial films, only the polycrystalline CrNx films fabricated at fN2 = 30 and 50 sccm exhibit a discontinuity in ρ(T) curves at 260-280 K, indicating that both the N-vacancy concentration and grain boundaries play important roles in the metal-insulator transition. © 2013 American Institute of Physics.

  1. PROPERTIES AND OPTICAL APPLICATION OF POLYCRYSTALLINE ZINC SELENIDE OBTAINED BY PHYSICAL VAPOR DEPOSITION

    Directory of Open Access Journals (Sweden)

    A. A. Dunaev

    2015-05-01

    Full Text Available Findings on production technology, mechanical and optical properties of polycrystalline zinc selenide are presented. The combination of its physicochemical properties provides wide application of ZnSe in IR optics. Production technology is based on the method of physical vapor deposition on a heated substrate (Physical Vapor Deposition - PVD. The structural features and heterogeneity of elemental composition for the growth surfaces of ZnSe polycrystalline blanks were investigated using CAMEBAX X-ray micro-analyzer. Characteristic pyramid-shaped crystallites were recorded for all growth surfaces. The measurements of the ratio for major elements concentrations show their compliance with the stoichiometry of the ZnSe compounds. Birefringence, optical homogeneity, thermal conductivity, mechanical and optical properties were measured. It is established that regardless of polycrystalline condensate columnar and texturing, the optical material is photomechanically isotropic and homogeneous. The actual performance of parts made of polycrystalline optical zinc selenide in the thermal spectral ranges from 3 to 5 μm and from 8 to 14 μm and in the CO2 laser processing plants with a power density of 500 W/cm2 is shown. The developed technology gives the possibility to produce polycrystalline optical material on an industrial scale.

  2. The latent fingerprint in mass transport of polycrystalline materials

    Science.gov (United States)

    Thirunavukarasu, Gopinath; Kundu, Sukumar; Chatterjee, Subrata

    2016-02-01

    Herein, a systematic investigation was carried out to reach a rational understanding and to provide information concerning the possible causes for a significant influence of pressure variation in the underlying processes of mass transport in polycrystalline materials. The authors focused their research in solid-state diffusion, a part of the subject "Mass Transport in Solids". Theories on diffusion are the subject by itself which exists as a latent fingerprint in every text of higher learning in interdisciplinary science. In this research, authors prepared sandwich samples of titanium alloy and stainless steel using nickel as an intermediate metal. The samples were processed at three different levels of bonding pressure (3, 4 and 5 MPa) while bonding temperature and bonding time was maintained at 750 °C and 1 h, respectively, throughout the experiments. It was observed that the net flux of atomic diffusion of nickel atoms into Ti-alloy at TiA/Ni interface increased by ~63 % with the rise in the bonding pressure from 3 to 4 MPa, but decreased by ~40 % with the rise in the bonding pressure from 4 to 5 MPa. At the same time, the net flux of atomic diffusion of nickel atoms into stainless steel at Ni/SS interface increased by ~19 % with the rise in the bonding pressure from 3 to 4 MPa, but increased by ~17 % with the rise in the bonding pressure from 4 to 5 MPa. Here authors showed that the pressure variations have different effects at the TiA/Ni interface and Ni/SS interface, and tried to explain the explicit mechanisms operating behind them. In general for sandwich samples processed irrespective of bonding pressure chosen, the net flux of Ni-atoms diffused into SS is greater than that of the net flux of Ni-atoms diffused in Ti-alloy matrix by four orders of magnitude. The calculated diffusivity of Ni-atoms into Ti-alloy reaches its highest value of ~5.083 × 10-19 m2/s for the sandwich sample processed using 4-MPa bonding-pressure, whereas the diffusivity of Ni

  3. Amorphous and polycrystalline water ices in space environments

    Science.gov (United States)

    Andrade, Diana; Pilling, Sergio; Da Silveira, Enio; Barros, Ana

    2016-07-01

    Ices are an important reservoir of more complex molecular species in several space environments, containing information about the composition and formation of these regions. Water ice is the dominant constituent of interstellar ices in most lines of sight and is about 70 % of the composition in comets, being a key molecule in astrochemical models. It is believed that one of the reactive species possibly evaporated from the water ices is the hydronium ion, H_{3}O^{+}, which plays an important role in the oxygen chemistry network. This ion has been detected in the lunar surface of Enceladus and Titan, and toward the Sagittarius B2 molecular Clouds, where H_{2}O and OH were also identified. In this work, the ion desorption due to radiolysis in ices constituted by water at three different temperatures (40, 70 and 125 K) is studied, to investigate the different allotropic water ices. A discussion on the rate of H_{3}O^{+} and water delivered to gas phase, as well as the half-life of water ice grains, inside dense molecular clouds considering a constants cosmic ray flux is given. The ions desorbed from water ice have been mass/charge analyzed by a time-of-flight spectrometer. Among the results, it is seen that in the positive ion spectrum of high density amorphous water ice at 40 K the highest desorption yields (ejected ions/impact) correspond to H^{+}, H_{3}O^{+} and clusters formed by (H_{2}O)_{n}R^{+}, where R^{+} is H_{3}O^{+} and 1 ≤ n ≤ 25. At T = 125 K, the ice is in its low density polycrystalline form and new clusters are present, such as (H_{2}O)_{n}R^{+}, where R^{+} is H_{2}^{+} and H_{3}^{+} (for low n), beyond H_{3}O^{+}. Therefore, it is seen that (H_{2}O)_{n}H_{3}O^{+} series (with n between 1 and 25) is dominant in all cases. The H_{3}O^{+} desorption yield at 40 K is about 5times10^{-3} ions/impact. This value is 4-5 times higher than the one obtained at T > 125 K. This behavior is also seen to all series member and consequently to the sum (Yn).

  4. FORMATION OF WEAR-RESISTANT CHROMIUM CAST IRON CASTING INTO THE CHILL MOLD

    Directory of Open Access Journals (Sweden)

    E. I. Marukovich

    2013-01-01

    Full Text Available The analysis of thermal processes of formation of castings from wearproof chromic cast irons for replaceable details of centrifugal mills and crushers is carried out. Influence of protective and dividing coverings on intensity of heating of the chill mold is investigated.

  5. Mechanical properties of homogenized twin-roll cast and conventionally cast AZ31 magnesium alloys

    Directory of Open Access Journals (Sweden)

    Mariia Zimina

    2015-02-01

    Full Text Available The improvement of mechanical properties of magnesium alloys nowadays is very important, because of the variety of industrial applications. For this goal, the number of casting techniques and further treatments were developed. Among the continuous casting techniques, which allow producing long strips of the alloys, is twin-roll casting. Using this process one can get the magnesium alloy with finest microstructure and higher specific strength. In this paper the comparison of tensile properties of conventionally cast and twin-roll cast AZ31 magnesium alloys was made. Tensile tests were carried out with constant strain rate 10-3 s-1 at temperatures ranging from 100 to 300 °C. Both materials were tested in as-cast state and after homogenization treatment at 450 °C for 10 hours. The investigation showed that there are no significant changes in ductility of AZ31 conventionally cast alloy even after heat treatment, while the ductility of twin-roll cast alloy increases.

  6. National Metal Casting Research Institute final report. Volume 2, Die casting research

    Energy Technology Data Exchange (ETDEWEB)

    Jensen, D. [University of Northern Iowa, Cedar Falls, IA (United States). Dept. of Industrial Technology] [comp.

    1994-06-01

    Four subprojects were completed: development and evaluation of die coatings, accelerated die life characterization of die materials, evaluation of fluid flow and solidification modeling programs, selection and characterization of Al-based die casting alloys, and influence of die materials and coatings on die casting quality.

  7. Precision Casting via Advanced Simulation and Manufacturing

    Science.gov (United States)

    1997-01-01

    A two-year program was conducted to develop and commercially implement selected casting manufacturing technologies to enable significant reductions in the costs of castings, increase the complexity and dimensional accuracy of castings, and reduce the development times for delivery of high quality castings. The industry-led R&D project was cost shared with NASA's Aerospace Industry Technology Program (AITP). The Rocketdyne Division of Boeing North American, Inc. served as the team lead with participation from Lockheed Martin, Ford Motor Company, Howmet Corporation, PCC Airfoils, General Electric, UES, Inc., University of Alabama, Auburn University, Robinson, Inc., Aracor, and NASA-LeRC. The technical effort was organized into four distinct tasks. The accomplishments reported herein. Task 1.0 developed advanced simulation technology for core molding. Ford headed up this task. On this program, a specialized core machine was designed and built. Task 2.0 focused on intelligent process control for precision core molding. Howmet led this effort. The primary focus of these experimental efforts was to characterize the process parameters that have a strong impact on dimensional control issues of injection molded cores during their fabrication. Task 3.0 developed and applied rapid prototyping to produce near net shape castings. Rocketdyne was responsible for this task. CAD files were generated using reverse engineering, rapid prototype patterns were fabricated using SLS and SLA, and castings produced and evaluated. Task 4.0 was aimed at developing technology transfer. Rocketdyne coordinated this task. Casting related technology, explored and evaluated in the first three tasks of this program, was implemented into manufacturing processes.

  8. Colour Metallography of Cast Iron - Chapter 3: Spheroidal Graphite Cast Iron (Ⅰ

    Directory of Open Access Journals (Sweden)

    Zhou Jiyang

    2010-02-01

    Full Text Available Cast iron, as a traditional metal material, has advantages of low total cost, good castability and machinability, good wear resistance and low notch sensitivity, and is still facing tough challenge in quality, property and variety of types etc. Experts and engineers studying and producing iron castings all around world extremely concern this serious challenge. Over more than 30 years, a great of research work has been carried out on how to further improve its property, expand its application and combine cast iron technology with some hi-techs (for example, computer technology. Nevertheless, cast iron is a multi-element and multi-phase alloy and has complex and variety of structures and still has great development potential in structure and property. For further studying and developing cast iron, theoretical research work is important promise, and the study on solidification process and control mechanism of graphite morphology is fundamental for improving property of cast iron and developing new type of cast iron. Metallography of cast iron normally includes two sections: liquid phase transformation and solid phase transformation. The book, Colour Metallography of Cast Iron, uses colour metallography technique to study solidification structures of cast irons: graphite, carbides, austenite and eutectics; and focuses on solidification processes. With progress of modern solidification theory, the control of material solidification process becomes important measure for improving traditional materials and developing new materials. Solidification structure not only influences mechanical and physical properties of cast iron, but also affects its internal quality. The book uses a large amount of colour photos to describe the formation of solidification structures and their relations. Crystallization phenomena, which cannot be displayed with traditional metallography, are presented and more phase transformation information is obtained from these colour

  9. Predicting Pattern Tooling and Casting Dimensions for Investment Casting - Phase II

    Energy Technology Data Exchange (ETDEWEB)

    Sabau, Adrian S [ORNL

    2005-09-01

    The investment casting process allows the production of complex-shape parts and close dimensional tolerances. One of the most important phases in the investment casting process is the design of the pattern die. Pattern dies are used to create wax patterns by injecting wax into dies. The wax patterns are used to create a ceramic shell by the application of a series of ceramic coatings, and the alloy is cast into the dewaxed shell mold (Fig. 1.1). However, the complexity of shape and the close dimensional tolerances required in the final casting make it difficult to determine tooling dimensions. The final linear dimension of the casting depends on the cumulative effects of the linear expansions or contractions in each step of the investment casting process (Fig. 1.2). In most cases, the mold geometry or cores restrict the shrinkage of the pattern or the cast part, and the final casting dimensions may be affected by time-dependent processes such as viscoelastic deformation of the wax, and viscoplastic creep and plastic deformations of the shell and alloy. The pattern die is often reworked several times to produce castings whose dimensions are within acceptable tolerances. To date, investment casting technology has been based on hands-on training and experience. Technical literature is limited to experimental, phenomenological studies aimed at obtaining empirical correlations for quick and easy application in industry. The goal of this project was to predict casting dimensions for investment castings in order to meet blueprint nominal during the first casting run. Several interactions have to be considered in a coupled manner to determine the shrinkage factors: these are the die-wax, wax-shell, and shell-alloy interactions (as illustrated in Fig. 1.3). In this work, the deformations of the die-wax and shell-alloy systems were considered in a coupled manner, while the coupled deformation of the wax-shell system was not considered. Future work is needed in order to

  10. Evaluation of porosity in Al alloy die castings

    Directory of Open Access Journals (Sweden)

    M. Říhová

    2012-01-01

    Full Text Available Mechanical properties of an Al-alloy die casting depend significantly on its structural properties. Porosity in Al-alloy castings is one of the most frequent causes of waste castings. Gas pores are responsible for impaired mechanical-technological properties of cast materials. On the basis of a complex evaluation of experiments conducted on AlSi9Cu3 alloy samples taken from the upper engine block which was die- cast with and without local squeeze casting it can be said that castings manufactured without squeeze casting exhibit maximum porosity in the longitudinal section. The area without local squeeze casting exhibits a certain reduction in mechanical properties and porosity increased to as much as 5%. However, this still meets the norms set by SKODA AUTO a.s.

  11. Analysis of the structure of castings made from chromium white cast iron resistant to abrasive wear

    Directory of Open Access Journals (Sweden)

    D. Kopyciński

    2009-10-01

    Full Text Available It has been proved that an addition of boron carbide and disintegrated steel scrap introduced as an inoculant to the chromium white cast iron changes the structure of castings. The said operation increases the number of crystallization nuclei for dendrites of the primary austenite. In this case, the iron particles act as substrates for the nucleation of primary austenite due to a similar crystallographic lattice. The more numerous are the dendrites of primary austenite and the structure more refined and the mechanical properties higher. Castings after B4C inoculation revealed a different structure of fine grained fracture. Primary precipitates of chromium carbide also appeared, reducing the mechanical properties of as-cast parts. Properly established heat treatment regime makes chromium iron castings regain their, originally high, mechanical properties.

  12. Mechanism and application of a newly developed pressure casting process:horizontal squeeze casting

    Institute of Scientific and Technical Information of China (English)

    Li Peijie; Huang Xiusong; He Liangju; Liu Xiangshang; Wang Benci

    2014-01-01

    Compared to traditional high-pressure die casting (HPDC), horizontal squeeze casting (HSC) is a more promising way to fabricate high-integrity castings, owing to a reduced number of gas and shrinkage porosities produced in the casting. In this paper, the differences between HSC and HPDC are assessed, through which it is shown that the cavity ifling velocity and the size of the gating system to be the most notable differences. Equipment development and related applications are also reviewed. Furthermore, numerical simulation is used to analyze the three fundamental characteristics of HSC: slow cavity ifling, squeeze feeding and slow sleeve ifling. From this, a selection principle is given based on the three related critical casting parameters: cavity filling velocity, gate size and sleeve ifling velocity. Finaly, two speciifc applications of HSC are introduced, and the future direction of HSC development is discussed.

  13. Gating Systems for Sizeable Castings from Al Alloys Cast into Ceramic Moulds

    Directory of Open Access Journals (Sweden)

    I. Stachovec

    2012-04-01

    Full Text Available In contrast to casting to conventional non-reusable “sand” moulds, for which calculating technique for an optimum design of the gating system is comparatively well-developed, a trial-and-error method is applied mostly for casting to ceramic shell moulds made by the investment casting technology. A technologist selects from gating systems of several types (that are standardized by the foundry mostly on the basis of experience. However, this approach is not sustainable with ever growing demands on quality of castings and also the economy of their fabrication as well as with new types of complex sizeable castings introduced to the production gradually (by new customers from the aircraft industry above all any more. The simulation software may be used as a possible tool for making the process of optimising gating systems more effective.

  14. Applying RP-FDM Technology to Produce Prototype Castings Using the Investment Casting Method

    Directory of Open Access Journals (Sweden)

    M. Macků

    2012-09-01

    Full Text Available The research focused on the production of prototype castings, which is mapped out starting from the drawing documentation up to theproduction of the casting itself. The FDM method was applied for the production of the 3D pattern. Its main objective was to find out whatdimensional changes happened during individual production stages, starting from the 3D pattern printing through a silicon mouldproduction, wax patterns casting, making shells, melting out wax from shells and drying, up to the production of the final casting itself.Five measurements of determined dimensions were made during the production, which were processed and evaluated mathematically.A determination of shrinkage and a proposal of measures to maintain the dimensional stability of the final casting so as to meetrequirements specified by a customer were the results.

  15. Mechanism and application of a newly developed pressure casting process: horizontal squeeze casting

    Directory of Open Access Journals (Sweden)

    Li Peijie

    2014-07-01

    Full Text Available Compared to traditional high-pressure die casting (HPDC, horizontal squeeze casting (HSC is a more promising way to fabricate high-integrity castings, owing to a reduced number of gas and shrinkage porosities produced in the casting. In this paper, the differences between HSC and HPDC are assessed, through which it is shown that the cavity filling velocity and the size of the gating system to be the most notable differences. Equipment development and related applications are also reviewed. Furthermore, numerical simulation is used to analyze the three fundamental characteristics of HSC: slow cavity filling, squeeze feeding and slow sleeve filling. From this, a selection principle is given based on the three related critical casting parameters: cavity filling velocity, gate size and sleeve filling velocity. Finally, two specific applications of HSC are introduced, and the future direction of HSC development is discussed.

  16. Unique morphology of intratubular light chain casts in multiple myeloma: The amyloid cast nephropathy

    Directory of Open Access Journals (Sweden)

    Alok Sharma

    2014-01-01

    Full Text Available Cast nephropathy is the most frequent pattern of renal involvement in multiple myeloma characterized by presence of tubular casts with characteristic morphology that are composed of monotypic (either kappa or lambda light chains as seen by immunofluorescence microscopy. Rarely these casts may show evidence of amyloidogenesis and assume a unique morphology, which needs to be appreciated for arriving at accurate diagnosis. We present the case of an elderly male presenting with features of acute kidney injury and detected with extensive inspissation of intratubular casts with lambda light chain restriction and a unique morphology with spiculated congophilic periphery. Further investigations confirmed the presence of systemic myeloma. Presence of intratubular amyloid casts is a rare occurrence which needs to be recognized by the pathologist and forms a vital element in timely diagnosis of the systemic disease which often presents with renal involvement.

  17. The deformation of wax patterns and castings in investment casting technology

    Directory of Open Access Journals (Sweden)

    A. Herman

    2012-01-01

    Full Text Available The dimensional accuracy of the final casting of Inconel alloy 738 LC is affected by many aspects. One of them is the choice of method and time of cooling wax model for precision investment casting. The main objective was to study the initial deformation of the complex shape of the casting of the rotor blades. Various approaches have been tested for cooling wax pattern. When wax models are cooling on the air, without clamping in jig for cooling, deviations from the ideal shape of the casting are very noticeable (up to 8 mm and most are in extreme positions of the model. When blade is cooled in fixing jig in water environment, the resulting deviations compared with cooling in air are significantly larger, sometimes up to 10 mm. This itself does not mean that the final shape of the casting is dimensionally more accurate with usage of wax models, which have deviations from the ideal position smaller. Another deformation occurs when shell mould is produced around wax pattern and furthermore deformations emerge while casting of blade is cooling. This paper demonstrates first steps in describing complex process of deformations of Inconel alloy blades produced with investment casting technology by comparing results from thermal imagery, simulations in foundry simulation software ProCAST 2010 and measurements from CNC scanning system Carl Zeiss MC 850. Conclusions are so far not groundbreaking, but it seems deformations of wax pattern and deformations of castings do in some cases cancel each other by having opposite directions. Describing entirely whole process of deformations will help increase precision of blade castings so that models at the beginning and blades in the end are the same.

  18. The importance of stress percolation patterns in rocks and other polycrystalline materials.

    Science.gov (United States)

    Burnley, P C

    2013-01-01

    A new framework for thinking about the deformation behavior of rocks and other heterogeneous polycrystalline materials is proposed, based on understanding the patterns of stress transmission through these materials. Here, using finite element models, I show that stress percolates through polycrystalline materials that have heterogeneous elastic and plastic properties of the same order as those found in rocks. The pattern of stress percolation is related to the degree of heterogeneity in and statistical distribution of the elastic and plastic properties of the constituent grains in the aggregate. The development of these stress patterns leads directly to shear localization, and their existence provides insight into the formation of rhythmic features such as compositional banding and foliation in rocks that are reacting or dissolving while being deformed. In addition, this framework provides a foundation for understanding and predicting the macroscopic rheology of polycrystalline materials based on single-crystal elastic and plastic mechanical properties.

  19. Grain boundary-induced variability of charge transport in hydrogenated polycrystalline graphene

    DEFF Research Database (Denmark)

    Barrios-Vargas, Jose E.; Falkenberg, Jesper Toft; Soriano, David

    2017-01-01

    Chemical functionalization has proven to be a promising means of tailoring the unique properties of graphene. For example, hydrogenation can yield a variety of interesting effects, including a metal-insulator transition or the formation of localized magnetic moments. Meanwhile, graphene grown...... by chemical vapor deposition is the most suitable for large-scale production, but the resulting material tends to be polycrystalline. Up to now there has been relatively little focus on how chemical functionalization, and hydrogenation in particular, impacts the properties of polycrystalline graphene....... These findings suggest a tunability of electrical transport of polycrystalline graphene through selective hydrogen functionalization, and also have implications for hydrogen-induced magnetization and spin lifetime of this material....

  20. Low resistance polycrystalline diamond thin films deposited by hot filament chemical vapour deposition

    Indian Academy of Sciences (India)

    Mahtab Ullah; Ejaz Ahmed; Abdelbary Elhissi; Waqar Ahmed

    2014-05-01

    Polycrystalline diamond thin films with outgrowing diamond (OGD) grains were deposited onto silicon wafers using a hydrocarbon gas (CH4) highly diluted with H2 at low pressure in a hot filament chemical vapour deposition (HFCVD) reactor with a range of gas flow rates. X-ray diffraction (XRD) and SEM showed polycrystalline diamond structure with a random orientation. Polycrystalline diamond films with various textures were grown and (111) facets were dominant with sharp grain boundaries. Outgrowth was observed in flowerish character at high gas flow rates. Isolated single crystals with little openings appeared at various stages at low gas flow rates. Thus, changing gas flow rates had a beneficial influence on the grain size, growth rate and electrical resistivity. CVD diamond films gave an excellent performance for medium film thickness with relatively low electrical resistivity and making them potentially useful in many industrial applications.