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Sample records for modeling triangular titration

  1. A microscopic model of triangular arbitrage

    Science.gov (United States)

    Aiba, Yukihiro; Hatano, Naomichi

    2006-11-01

    We introduce a microscopic model which describes the dynamics of each dealer in multiple foreign exchange markets, taking account of the triangular arbitrage transaction. The model reproduces the interaction among the markets well. We explore the relation between the parameters of the present microscopic model and the spring constant of a macroscopic model that we proposed previously.

  2. Mathematical model of parking space unit for triangular parking area

    Science.gov (United States)

    Syahrini, Intan; Sundari, Teti; Iskandar, Taufiq; Halfiani, Vera; Munzir, Said; Ramli, Marwan

    2018-01-01

    Parking space unit (PSU) is an effective measure for the area size of a vehicle, including the free space and the width of the door opening of the vehicle (car). This article discusses a mathematical model for parking space of vehicles in triangular shape area. An optimization model for triangular parking lot is developed. Integer Linear Programming (ILP) method is used to determine the maximum number of the PSU. The triangular parking lot is in isosceles and equilateral triangles shape and implements four possible rows and five possible angles for each field. The vehicles which are considered are cars and motorcycles. The results show that the isosceles triangular parking area has 218 units of optimal PSU, which are 84 units of PSU for cars and 134 units of PSU for motorcycles. Equilateral triangular parking area has 688 units of optimal PSU, which are 175 units of PSU for cars and 513 units of PSU for motorcycles.

  3. Multiple Discrete Endogenous Variables in Weakly-Separable Triangular Models

    Directory of Open Access Journals (Sweden)

    Sung Jae Jun

    2016-02-01

    Full Text Available We consider a model in which an outcome depends on two discrete treatment variables, where one treatment is given before the other. We formulate a three-equation triangular system with weak separability conditions. Without assuming assignment is random, we establish the identification of an average structural function using two-step matching. We also consider decomposing the effect of the first treatment into direct and indirect effects, which are shown to be identified by the proposed methodology. We allow for both of the treatment variables to be non-binary and do not appeal to an identification-at-infinity argument.

  4. Differential Binding Models for Direct and Reverse Isothermal Titration Calorimetry.

    Science.gov (United States)

    Herrera, Isaac; Winnik, Mitchell A

    2016-03-10

    Isothermal titration calorimetry (ITC) is a technique to measure the stoichiometry and thermodynamics from binding experiments. Identifying an appropriate mathematical model to evaluate titration curves of receptors with multiple sites is challenging, particularly when the stoichiometry or binding mechanism is not available. In a recent theoretical study, we presented a differential binding model (DBM) to study calorimetry titrations independently of the interaction among the binding sites (Herrera, I.; Winnik, M. A. J. Phys. Chem. B 2013, 117, 8659-8672). Here, we build upon our DBM and show its practical application to evaluate calorimetry titrations of receptors with multiple sites independently of the titration direction. Specifically, we present a set of ordinary differential equations (ODEs) with the general form d[S]/dV that can be integrated numerically to calculate the equilibrium concentrations of free and bound species S at every injection step and, subsequently, to evaluate the volume-normalized heat signal (δQ(V) = δq/dV) of direct and reverse calorimetry titrations. Additionally, we identify factors that influence the shape of the titration curve and can be used to optimize the initial concentrations of titrant and analyte. We demonstrate the flexibility of our updated DBM by applying these differentials and a global regression analysis to direct and reverse calorimetric titrations of gadolinium ions with multidentate ligands of increasing denticity, namely, diglycolic acid (DGA), citric acid (CIT), and nitrilotriacetic acid (NTA), and use statistical tests to validate the stoichiometries for the metal-ligand pairs studied.

  5. Nonexistence of nonconstant steady-state solutions in a triangular cross-diffusion model

    Science.gov (United States)

    Lou, Yuan; Tao, Youshan; Winkler, Michael

    2017-05-01

    In this paper we study the Shigesada-Kawasaki-Teramoto model for two competing species with triangular cross-diffusion. We determine explicit parameter ranges within which the model exclusively possesses constant steady state solutions.

  6. Modelling of acid-base titration curves of mineral assemblages

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    Stamberg Karel

    2016-01-01

    Full Text Available The modelling of acid-base titration curves of mineral assemblages was studied with respect to basic parameters of their surface sites to be obtained. The known modelling approaches, component additivity (CA and generalized composite (GC, and three types of different assemblages (fucoidic sandstones, sedimentary rock-clay and bentonite-magnetite samples were used. In contrary to GC-approach, application of which was without difficulties, the problem of CA-one consisted in the credibility and accessibility of the parameters characterizing the individual mineralogical components.

  7. Fast Proton Titration Scheme for Multiscale Modeling of Protein Solutions.

    Science.gov (United States)

    Teixeira, Andre Azevedo Reis; Lund, Mikael; da Silva, Fernando Luís Barroso

    2010-10-12

    Proton exchange between titratable amino acid residues and the surrounding solution gives rise to exciting electric processes in proteins. We present a proton titration scheme for studying acid-base equilibria in Metropolis Monte Carlo simulations where salt is treated at the Debye-Hückel level. The method, rooted in the Kirkwood model of impenetrable spheres, is applied on the three milk proteins α-lactalbumin, β-lactoglobulin, and lactoferrin, for which we investigate the net-charge, molecular dipole moment, and charge capacitance. Over a wide range of pH and salt conditions, excellent agreement is found with more elaborate simulations where salt is explicitly included. The implicit salt scheme is orders of magnitude faster than the explicit analog and allows for transparent interpretation of physical mechanisms. It is shown how the method can be expanded to multiscale modeling of aqueous salt solutions of many biomolecules with nonstatic charge distributions. Important examples are protein-protein aggregation, protein-polyelectrolyte complexation, and protein-membrane association.

  8. A teoria triangular do amor de Sternberg e o modelo dos cinco grandes fatores Sternberg's triangular theory of love and the big five factor model

    Directory of Open Access Journals (Sweden)

    Bruna Gomes Mônego

    2011-04-01

    Full Text Available O presente estudo investigou a influência dos traços de personalidade de acordo com o modelo dos Cinco Grandes Fatores (CGF e do amor segundo a Teoria Triangular do Amor de Sternberg na satisfação conjugal. A amostra foi composta por 192 universitários que vivenciavam um relacionamento amoroso classificado como ficante, namoro/noivado ou casamento. Os participantes responderam coletivamente à Escala Fatorial de Satisfação em Relacionamento de Casal, à Escala Triangular do Amor de Sternberg e à Bateria Fatorial de Personalidade. Os resultados indicaram padrões diferentes de correlação para cada tipo de relacionamento e o modelo de Regressão Linear Múltipla foi significativo (F=23,19, gl=10, pThis present study investigated the influence of personality traits according to the Big Five Factors (CGF model and to love according to Sternberg's Triangular Theory of Love in marital satisfaction. Sample was composed by 192 undergraduate students who experienced a loving relationship classified as an informal relationship, dating/engagement or wedding. Participants answered the "Escala Fatorial de Satisfação em Relacionamento de Casal", the Sternberg's Triangular Love Scale and the "Bateria Fatorial de Personalidade". Data showed different patterns of correlation for each type of relationship and multiple linear regression model was significant (F=23.19, df=10, p<0.001 and explained 58% of the variance. The intimacy, passion and conscientiousness constructs contributed positively to the satisfaction, while neuroticism had a negative influence. The commitment component and the other personality traits did not reach statistical significance.

  9. Engineering Ising-XY spin-models in a triangular lattice using tunable artificial gauge fields

    Science.gov (United States)

    Struck, J.; Weinberg, M.; Ölschläger, C.; Windpassinger, P.; Simonet, J.; Sengstock, K.; Höppner, R.; Hauke, P.; Eckardt, A.; Lewenstein, M.; Mathey, L.

    2013-11-01

    Magnetism plays a key role in modern science and technology, but still many open questions arise from the interplay of magnetic many-body interactions. Deeper insight into complex magnetic behaviour and the nature of magnetic phase transitions can be obtained from, for example, model systems of coupled XY and Ising spins. Here, we report on the experimental realization of such a coupled system with ultracold atoms in triangular optical lattices. This is accomplished by imposing an artificial gauge field on the neutral atoms, which acts on them as a magnetic field does on charged particles. As a result, the atoms show persistent circular currents, the direction of which provides an Ising variable. On this, the tunable staggered gauge field, generated by a periodic driving of the lattice, acts as a longitudinal field. Further, the superfluid ground state presents strong analogies with the paradigm example of the fully frustrated XY model on a triangular lattice.

  10. A triangular model of dimensionless runoff producing rainfall hyetographs in Texas

    Science.gov (United States)

    Asquith, W.H.; Bumgarner, J.R.; Fahlquist, L.S.

    2003-01-01

    A synthetic triangular hyetograph for a large data base of Texas rainfall and runoff is needed. A hyetograph represents the temporal distribution of rainfall intensity at a point or over a watershed during a storm. Synthetic hyetographs are estimates of the expected time distribution for a design storm and principally are used in small watershed hydraulic structure design. A data base of more than 1,600 observed cumulative hyetographs that produced runoff from 91 small watersheds (generally less than about 50 km2) was used to provide statistical parameters for a simple triangular shaped hyetograph model. The model provides an estimate of the average hyetograph in dimensionless form for storm durations of 0 to 24 hours and 24 to 72 hours. As a result of this study, the authors concluded that the expected dimensionless cumulative hyetographs of 0 to 12 hour and 12 to 24 hour durations were sufficiently similar to be combined with minimal information loss. The analysis also suggests that dimensionless cumulative hyetographs are independent of the frequency level or return period of total storm depth and thus are readily used for many design applications. The two triangular hyetographs presented are intended to enhance small watershed design practice in applicable parts of Texas.

  11. Random-diluted triangular plaquette model: Study of phase transitions in a kinetically constrained model

    Science.gov (United States)

    Franz, Silvio; Gradenigo, Giacomo; Spigler, Stefano

    2016-03-01

    We study how the thermodynamic properties of the triangular plaquette model (TPM) are influenced by the addition of extra interactions. The thermodynamics of the original TPM is trivial, while its dynamics is glassy, as usual in kinetically constrained models. As soon as we generalize the model to include additional interactions, a thermodynamic phase transition appears in the system. The additional interactions we consider are either short ranged, forming a regular lattice in the plane, or long ranged of the small-world kind. In the case of long-range interactions we call the new model the random-diluted TPM. We provide arguments that the model so modified should undergo a thermodynamic phase transition, and that in the long-range case this is a glass transition of the "random first-order" kind. Finally, we give support to our conjectures studying the finite-temperature phase diagram of the random-diluted TPM in the Bethe approximation. This corresponds to the exact calculation on the random regular graph, where free energy and configurational entropy can be computed by means of the cavity equations.

  12. Algebraic Bethe ansatz for the XXX chain with triangular boundaries and Gaudin model

    Science.gov (United States)

    Cirilo António, N.; Manojlović, N.; Salom, I.

    2014-12-01

    We implement fully the algebraic Bethe ansatz for the XXX Heisenberg spin chain in the case when both boundary matrices can be brought to the upper-triangular form. We define the Bethe vectors which yield the strikingly simple expression for the off shell action of the transfer matrix, deriving the spectrum and the relevant Bethe equations. We explore further these results by obtaining the off shell action of the generating function of the Gaudin Hamiltonians on the corresponding Bethe vectors through the so-called quasi-classical limit. Moreover, this action is as simple as it could possibly be, yielding the spectrum and the Bethe equations of the Gaudin model.

  13. Superconductivity in the Penson-Kolb Model on a Triangular Lattice

    Science.gov (United States)

    Ptok, A.; Mierzejewski, M.

    2008-07-01

    We investigate properties of the two-dimensional Penson-Kolb model with repulsive pair hopping interaction. In the case of a bipartite square lattice this interaction may lead to the η-type pairing, when the phase of superconducting order parameter changes from one lattice site to the neighboring one. We show that this interaction may be responsible for the onset of superconductivity also for a triangular lattice. We discuss the spatial dependence of the superconducting order parameter and demonstrate that the total momentum of the paired electrons is determined by the lattice geometry.

  14. One dimensionalization in the spin-1 Heisenberg model on the anisotropic triangular lattice

    Science.gov (United States)

    Gonzalez, M. G.; Ghioldi, E. A.; Gazza, C. J.; Manuel, L. O.; Trumper, A. E.

    2017-11-01

    We investigate the effect of dimensional crossover in the ground state of the antiferromagnetic spin-1 Heisenberg model on the anisotropic triangular lattice that interpolates between the regime of weakly coupled Haldane chains (J'≪J ) and the isotropic triangular lattice (J'=J ). We use the density-matrix renormalization group (DMRG) and Schwinger boson theory performed at the Gaussian correction level above the saddle-point solution. Our DMRG results show an abrupt transition between decoupled spin chains and the spirally ordered regime at (J'/J) c˜0.42 , signaled by the sudden closing of the spin gap. Coming from the magnetically ordered side, the computation of the spin stiffness within Schwinger boson theory predicts the instability of the spiral magnetic order toward a magnetically disordered phase with one-dimensional features at (J'/J) c˜0.43 . The agreement of these complementary methods, along with the strong difference found between the intra- and the interchain DMRG short spin-spin correlations for sufficiently large values of the interchain coupling, suggests that the interplay between the quantum fluctuations and the dimensional crossover effects gives rise to the one-dimensionalization phenomenon in this frustrated spin-1 Hamiltonian.

  15. Quantum dimer model on the triangular lattice: Semiclassical and variational approaches to vison dispersion and condensation

    Science.gov (United States)

    Misguich, Grégoire; Mila, Frédéric

    2008-04-01

    After reviewing the concept of vison excitations in Z2 dimer liquids, we study the liquid-crystal transition of the quantum dimer model on the triangular lattice by means of a semiclassical spin-wave approximation to the dispersion of visons in the context of a “soft-dimer” version of the model. This approach captures some important qualitative features of the transition: continuous nature of the transition, linear dispersion at the critical point, and 12×12 symmetry-breaking pattern. In a second part, we present a variational calculation of the vison dispersion relation at the Rokhsar-Kivelson (RK) point, which reproduces the qualitative shape of the dispersion relation and the order of magnitude of the gap. This approach provides a simple but reliable approximation of the vison wave functions at the RK point.

  16. Group theoretical classification of broken symmetry states of the two-fold degenerate Hubbard model on a triangular lattice

    International Nuclear Information System (INIS)

    Masago, Akira; Suzuki, Naoshi

    2001-01-01

    By a group theoretical procedure we derive the possible spontaneously broken-symmetry states for the two-fold degenerate Hubbard model on a two-dimensional triangular lattice. For ordering wave vectors corresponding to the points Γ and K in the first BZ we find 22 states which include 16 collinear and six non-collinear states. The collinear states include the usual SDW and CDW states which appear also in the single-band Hubbard model. The non-collinear states include exotic ordering states of orbitals and spins as well as the triangular arrangement of spins

  17. A triangular climate-based decision model to forecast crop anomalies in Kenya

    Science.gov (United States)

    Guimarães Nobre, G.; Davenport, F.; Veldkamp, T.; Jongman, B.; Funk, C. C.; Husak, G. J.; Ward, P.; Aerts, J.

    2017-12-01

    By the end of 2017, the world is expected to experience unprecedented demands for food assistance where, across 45 countries, some 81 million people will face a food security crisis. Prolonged droughts in Eastern Africa are playing a major role in these crises. To mitigate famine risk and save lives, government bodies and international donor organisations are increasingly building up efforts to resolve conflicts and secure humanitarian relief. Disaster-relief and financing organizations traditionally focus on emergency response, providing aid after an extreme drought event, instead of taking actions in advance based on early warning. One of the reasons for this approach is that the seasonal risk information provided by early warning systems is often considered highly uncertain. Overcoming the reluctance to act based on early warnings greatly relies on understanding the risk of acting in vain, and assessing the cost-effectiveness of early actions. This research develops a triangular climate-based decision model for multiple seasonal time-scales to forecast strong anomalies in crop yield shortages in Kenya using Casual Discovery Algorithms and Fast and Frugal Decision Trees. This Triangular decision model (1) estimates the causality and strength of the relationship between crop yields and hydro climatological predictors (extracted from the Famine Early Warning Systems Network's data archive) during the crop growing season; (2) provides probabilistic forecasts of crop yield shortages in multiple time scales before the harvesting season; and (3) evaluates the cost-effectiveness of different financial mechanisms to respond to early warning indicators of crop yield shortages obtained from the model. Furthermore, we reflect on how such a model complements and advances the current state-of-art FEWS Net system, and examine its potential application to improve the management of agricultural risks in Kenya.

  18. Titration of fatty acids solubilized in cationic and anionic micelles. Calorimetry and thermodynamic modeling.

    Science.gov (United States)

    Söderman, Olle; Jönsson, Bengt; Olofsson, Gerd

    2006-02-23

    The electrostatic properties of charged surfactant micelles are investigated through titrations of fatty acid probes solubilized in the micelles. The titration process is followed by means of calorimetric measurements and by determining the pH values as a function of added base. This approach yields a complete thermodynamic description of the titration process. In particular, we find that the process is endothermic at 298 K. This is contrary to the titration of carboxylic acids in water, where DeltaH is approximately 0. To identify the main effect underlying the difference in DeltaH between titration in a micelle and water, a thermodynamic model has been developed which focuses on the transfer properties of charged and uncharged species from bulk water to the surface of a micelle and which incorporates a dielectric discontinuity at the micellar surface. The model relies on the use of the Poisson-Boltzmann equation which is solved using a finite element method. Experimental results and the model calculations imply that the dielectric discontinuity at (or near) the micellar surface plays a major role and hence must be included when analyzing the titration behavior of an acid functionality at the surface of a charged micelle.

  19. A titration model for evaluating calcium hydroxide removal techniques

    Directory of Open Access Journals (Sweden)

    Mark PHILLIPS

    2015-02-01

    Full Text Available Objective Calcium hydroxide (Ca(OH2 has been used in endodontics as an intracanal medicament due to its antimicrobial effects and its ability to inactivate bacterial endotoxin. The inability to totally remove this intracanal medicament from the root canal system, however, may interfere with the setting of eugenol-based sealers or inhibit bonding of resin to dentin, thus presenting clinical challenges with endodontic treatment. This study used a chemical titration method to measure residual Ca(OH2 left after different endodontic irrigation methods. Material and Methods Eighty-six human canine roots were prepared for obturation. Thirty teeth were filled with known but different amounts of Ca(OH2 for 7 days, which were dissolved out and titrated to quantitate the residual Ca(OH2 recovered from each root to produce a standard curve. Forty-eight of the remaining teeth were filled with equal amounts of Ca(OH2 followed by gross Ca(OH2 removal using hand files and randomized treatment of either: 1 Syringe irrigation; 2 Syringe irrigation with use of an apical file; 3 Syringe irrigation with added 30 s of passive ultrasonic irrigation (PUI, or 4 Syringe irrigation with apical file and PUI (n=12/group. Residual Ca(OH2 was dissolved with glycerin and titrated to measure residual Ca(OH2 left in the root. Results No method completely removed all residual Ca(OH2. The addition of 30 s PUI with or without apical file use removed Ca(OH2 significantly better than irrigation alone. Conclusions This technique allowed quantification of residual Ca(OH2. The use of PUI (with or without apical file resulted in significantly lower Ca(OH2 residue compared to irrigation alone.

  20. A model for oxygen conservation associated with titration during pediatric oxygen therapy.

    Directory of Open Access Journals (Sweden)

    Grace Wu

    Full Text Available Continuous oxygen treatment is essential for managing children with hypoxemia, but access to oxygen in low-resource countries remains problematic. Given the high burden of pneumonia in these countries and the fact that flow can be gradually reduced as therapy progresses, oxygen conservation through routine titration warrants exploration.To determine the amount of oxygen saved via titration during oxygen therapy for children with hypoxemic pneumonia.Based on published clinical data, we developed a model of oxygen flow rates needed to manage hypoxemia, assuming recommended flow rate at start of therapy, and comparing total oxygen used with routine titration every 3 minutes or once every 24 hours versus no titration.Titration every 3 minutes or every 24 hours provided oxygen savings estimated at 11.7% ± 5.1% and 8.1% ± 5.1% (average ± standard error of the mean, n = 3, respectively. For every 100 patients, 44 or 30 kiloliters would be saved-equivalent to 733 or 500 hours at 1 liter per minute.Ongoing titration can conserve oxygen, even performed once-daily. While clinical validation is necessary, these findings could provide incentive for the routine use of pulse oximeters for patient management, as well as further development of automated systems.

  1. A model for oxygen conservation associated with titration during pediatric oxygen therapy.

    Science.gov (United States)

    Wu, Grace; Wollen, Alec; Himley, Stephen; Austin, Glenn; Delarosa, Jaclyn; Izadnegahdar, Rasa; Ginsburg, Amy Sarah; Zehrung, Darin

    2017-01-01

    Continuous oxygen treatment is essential for managing children with hypoxemia, but access to oxygen in low-resource countries remains problematic. Given the high burden of pneumonia in these countries and the fact that flow can be gradually reduced as therapy progresses, oxygen conservation through routine titration warrants exploration. To determine the amount of oxygen saved via titration during oxygen therapy for children with hypoxemic pneumonia. Based on published clinical data, we developed a model of oxygen flow rates needed to manage hypoxemia, assuming recommended flow rate at start of therapy, and comparing total oxygen used with routine titration every 3 minutes or once every 24 hours versus no titration. Titration every 3 minutes or every 24 hours provided oxygen savings estimated at 11.7% ± 5.1% and 8.1% ± 5.1% (average ± standard error of the mean, n = 3), respectively. For every 100 patients, 44 or 30 kiloliters would be saved-equivalent to 733 or 500 hours at 1 liter per minute. Ongoing titration can conserve oxygen, even performed once-daily. While clinical validation is necessary, these findings could provide incentive for the routine use of pulse oximeters for patient management, as well as further development of automated systems.

  2. The effects of computed tomography scanner parameters on the quality of the reverse triangular surface model of the fibula

    Energy Technology Data Exchange (ETDEWEB)

    Hayat, Nasir; Ahmad, Mushtaq, E-mail: nasirhayat@uet.edu.pk [Faculty of Mechanical Engineering, UET, Lahore (Pakistan)

    2016-01-15

    This study investigates the effects of computed tomography (CT) parameters on the quality and size of the reverse triangular surface model with an objective of obtaining an accurate 3D triangular surface model of complex-shaped customized objects for reverse engineering and many other applications such as surgical planning and finite element analysis. For this purpose, the fibula of a human knee joint was CT scanned by changing various parameters (slice thickness, slice spacing, pixel size, X-ray tube current and helical pitch) over wide ranges. Three-dimensional triangular surface models were created from point cloud data extracted from the CT image data. To assess the influences of scanning parameters on the surface quality and accuracy, the resulting surface models were qualitatively compared based on various anatomical features. Statistical analysis was used to quantify the deviations of surface models with different scanning parameter levels from the reference CT surface model. The results show that these parameters to a varying degree affect the surface quality, reproduction of various anatomical details and size of the resulting surface model. Moreover, these parameters are highly dependent on each other. Interactive effects of these parameters have been discussed and recommendations have been made for parameter settings. The results of the study would help to improve the accuracy of the 3D surface models required for customized implants and other applications. (author)

  3. Phase transitions in two-dimensional uniformly frustrated XY models. I. antiferromagnetic model on a triangular lattice

    International Nuclear Information System (INIS)

    Korshunov, S.E.; Uimin, G.V.

    1986-01-01

    A most popular model in the family of two-dimensional uniformly-frustrated XY models is the antiferromagnetic model on a triangular lattice (AF XY(t) model). Its ground state is both continuously and twofold discretely degenerated. Different phase transitions possible in such systems are investigated. Relevant topological excitations are analyzed and a new class of such (vortices with a fractional number of circulation quanta) is discovered. Their role in determining the properties of the system proves itself essential. The characteristics of phase transitions related to breaking of discrete and continuous symmetries change. The phase diagram of the ''generalized'' AF XY(t) model is constructed. The results obtained are rederived in the representation of the Coulomb gas with half-interger charges, equivalent to the AF XY(t) model with the Berezinskii-Villain interaction

  4. Simultaneous triangularization

    CERN Document Server

    Radjavi, Heydar

    2000-01-01

    A collection of matrices is said to be triangularizable if there is an invertible matrix S such that S1 AS is upper triangular for every A in the collection. This generalization of commutativity is the subject of many classical theorems due to Engel, Kolchin, Kaplansky, McCoy and others. The concept has been extended to collections of bounded linear operators on Banach spaces: such a collection is defined to be triangularizable if there is a maximal chain of subspaces of the Banach space, each of which is invariant under every member of the collection. Most of the classical results have been generalized to compact operators, and there are also recent theorems in the finite-dimensional case. This book is the first comprehensive treatment of triangularizability in both the finite and infinite-dimensional cases. It contains numerous very recent results and new proofs of many of the classical theorems. It provides a thorough background for research in both the linear-algebraic and operator-theoretic aspects of tr...

  5. Higher-order triangular spectral element method with optimized cubature points for seismic wavefield modeling

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Youshan, E-mail: ysliu@mail.iggcas.ac.cn [State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing, 100029 (China); Teng, Jiwen, E-mail: jwteng@mail.iggcas.ac.cn [State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing, 100029 (China); Xu, Tao, E-mail: xutao@mail.iggcas.ac.cn [State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing, 100029 (China); CAS Center for Excellence in Tibetan Plateau Earth Sciences, Beijing, 100101 (China); Badal, José, E-mail: badal@unizar.es [Physics of the Earth, Sciences B, University of Zaragoza, Pedro Cerbuna 12, 50009 Zaragoza (Spain)

    2017-05-01

    The mass-lumped method avoids the cost of inverting the mass matrix and simultaneously maintains spatial accuracy by adopting additional interior integration points, known as cubature points. To date, such points are only known analytically in tensor domains, such as quadrilateral or hexahedral elements. Thus, the diagonal-mass-matrix spectral element method (SEM) in non-tensor domains always relies on numerically computed interpolation points or quadrature points. However, only the cubature points for degrees 1 to 6 are known, which is the reason that we have developed a p-norm-based optimization algorithm to obtain higher-order cubature points. In this way, we obtain and tabulate new cubature points with all positive integration weights for degrees 7 to 9. The dispersion analysis illustrates that the dispersion relation determined from the new optimized cubature points is comparable to that of the mass and stiffness matrices obtained by exact integration. Simultaneously, the Lebesgue constant for the new optimized cubature points indicates its surprisingly good interpolation properties. As a result, such points provide both good interpolation properties and integration accuracy. The Courant–Friedrichs–Lewy (CFL) numbers are tabulated for the conventional Fekete-based triangular spectral element (TSEM), the TSEM with exact integration, and the optimized cubature-based TSEM (OTSEM). A complementary study demonstrates the spectral convergence of the OTSEM. A numerical example conducted on a half-space model demonstrates that the OTSEM improves the accuracy by approximately one order of magnitude compared to the conventional Fekete-based TSEM. In particular, the accuracy of the 7th-order OTSEM is even higher than that of the 14th-order Fekete-based TSEM. Furthermore, the OTSEM produces a result that can compete in accuracy with the quadrilateral SEM (QSEM). The high accuracy of the OTSEM is also tested with a non-flat topography model. In terms of computational

  6. Higher-order triangular spectral element method with optimized cubature points for seismic wavefield modeling

    International Nuclear Information System (INIS)

    Liu, Youshan; Teng, Jiwen; Xu, Tao; Badal, José

    2017-01-01

    The mass-lumped method avoids the cost of inverting the mass matrix and simultaneously maintains spatial accuracy by adopting additional interior integration points, known as cubature points. To date, such points are only known analytically in tensor domains, such as quadrilateral or hexahedral elements. Thus, the diagonal-mass-matrix spectral element method (SEM) in non-tensor domains always relies on numerically computed interpolation points or quadrature points. However, only the cubature points for degrees 1 to 6 are known, which is the reason that we have developed a p-norm-based optimization algorithm to obtain higher-order cubature points. In this way, we obtain and tabulate new cubature points with all positive integration weights for degrees 7 to 9. The dispersion analysis illustrates that the dispersion relation determined from the new optimized cubature points is comparable to that of the mass and stiffness matrices obtained by exact integration. Simultaneously, the Lebesgue constant for the new optimized cubature points indicates its surprisingly good interpolation properties. As a result, such points provide both good interpolation properties and integration accuracy. The Courant–Friedrichs–Lewy (CFL) numbers are tabulated for the conventional Fekete-based triangular spectral element (TSEM), the TSEM with exact integration, and the optimized cubature-based TSEM (OTSEM). A complementary study demonstrates the spectral convergence of the OTSEM. A numerical example conducted on a half-space model demonstrates that the OTSEM improves the accuracy by approximately one order of magnitude compared to the conventional Fekete-based TSEM. In particular, the accuracy of the 7th-order OTSEM is even higher than that of the 14th-order Fekete-based TSEM. Furthermore, the OTSEM produces a result that can compete in accuracy with the quadrilateral SEM (QSEM). The high accuracy of the OTSEM is also tested with a non-flat topography model. In terms of computational

  7. A Geochemical Reaction Model for Titration of Contaminated Soil and Groundwater at the Oak Ridge Reservation

    Science.gov (United States)

    Zhang, F.; Parker, J. C.; Gu, B.; Luo, W.; Brooks, S. C.; Spalding, B. P.; Jardine, P. M.; Watson, D. B.

    2007-12-01

    This study investigates geochemical reactions during titration of contaminated soil and groundwater at the Oak Ridge Reservation in eastern Tennessee. The soils and groundwater exhibits low pH and high concentrations of aluminum, calcium, magnesium, manganese, various trace metals such as nickel and cobalt, and radionuclides such as uranium and technetium. The mobility of many of the contaminant species diminishes with increasing pH. However, base additions to increase pH are strongly buffered by various precipitation/dissolution and adsorption/desorption reactions. The ability to predict acid-base behavior and associated geochemical effects is thus critical to evaluate remediation performance of pH manipulation strategies. This study was undertaken to develop a practical but generally applicable geochemical model to predict aqueous and solid-phase speciation during soil and groundwater titration. To model titration in the presence of aquifer solids, an approach proposed by Spalding and Spalding (2001) was utilized, which treats aquifer solids as a polyprotic acid. Previous studies have shown that Fe and Al-oxyhydroxides strongly sorb dissolved Ni, U and Tc species. In this study, since the total Fe concentration is much smaller than that of Al, only ion exchange reactions associated with Al hydroxides are considered. An equilibrium reaction model that includes aqueous complexation, precipitation, ion exchange, and soil buffering reactions was developed and implemented in the code HydroGeoChem 5.0 (HGC5). Comparison of model results with experimental titration curves for contaminated groundwater alone and for soil- water systems indicated close agreement. This study is expected to facilitate field-scale modeling of geochemical processes under conditions with highly variable pH to develop practical methods to control contaminant mobility at geochemically complex sites.

  8. Dynamical mean field study of the Mott transition in the half-filled Hubbard model on a triangular lattice

    OpenAIRE

    Aryanpour, K.; Pickett, W. E.; Scalettar, R. T.

    2006-01-01

    We employ dynamical mean field theory (DMFT) with a Quantum Monte Carlo (QMC) atomic solver to investigate the finite temperature Mott transition in the Hubbard model with the nearest neighbor hopping on a triangular lattice at half-filling. We estimate the value of the critical interaction to be $U_c=12.0 \\pm 0.5$ in units of the hopping amplitude $t$ through the evolution of the magnetic moment, spectral function, internal energy and specific heat as the interaction $U$ and temperature $T$ ...

  9. Z2-vortex lattice in the ground state of the triangular Kitaev-Heisenberg model

    Science.gov (United States)

    Daghofer, Maria; Rousochatzakis, Ioannis; Roessler, Ulrich K.; van den Brink, Jeroen

    2013-03-01

    Investigating the classical Kitaev-Heisenberg Hamiltonian on a triangular lattice, we establish the presence of an incommensurate non-coplanar magnetic phase, which is identified as a lattice of Z2 vortices. The vortices, topological point defects in the SO(3) order parameter of the nearby Heisenberg antiferromagnet, are not thermally excited but due to the spin-orbit coupling and arise at temperature T --> 0 . This Z2-vortex lattice is stable in a parameter regime relevant to iridates. We show that in the other, strongly anisotropic, limit a robust nematic phase emerges. Sponsored by the DFG (Emmy-Noether program).

  10. Grey-Markov prediction model based on background value optimization and central-point triangular whitenization weight function

    Science.gov (United States)

    Ye, Jing; Dang, Yaoguo; Li, Bingjun

    2018-01-01

    Grey-Markov forecasting model is a combination of grey prediction model and Markov chain which show obvious optimization effects for data sequences with characteristics of non-stationary and volatility. However, the state division process in traditional Grey-Markov forecasting model is mostly based on subjective real numbers that immediately affects the accuracy of forecasting values. To seek the solution, this paper introduces the central-point triangular whitenization weight function in state division to calculate possibilities of research values in each state which reflect preference degrees in different states in an objective way. On the other hand, background value optimization is applied in the traditional grey model to generate better fitting data. By this means, the improved Grey-Markov forecasting model is built. Finally, taking the grain production in Henan Province as an example, it verifies this model's validity by comparing with GM(1,1) based on background value optimization and the traditional Grey-Markov forecasting model.

  11. A minimal titration model of the mammalian dynamical heat shock response

    Science.gov (United States)

    Sivéry, Aude; Courtade, Emmanuel; Thommen, Quentin

    2016-12-01

    Environmental stress, such as oxidative or heat stress, induces the activation of the heat shock response (HSR) and leads to an increase in the heat shock proteins (HSPs) level. These HSPs act as molecular chaperones to maintain cellular proteostasis. Controlled by highly intricate regulatory mechanisms, having stress-induced activation and feedback regulations with multiple partners, the HSR is still incompletely understood. In this context, we propose a minimal molecular model for the gene regulatory network of the HSR that reproduces quantitatively different heat shock experiments both on heat shock factor 1 (HSF1) and HSPs activities. This model, which is based on chemical kinetics laws, is kept with a low dimensionality without altering the biological interpretation of the model dynamics. This simplistic model highlights the titration of HSF1 by chaperones as the guiding line of the network. Moreover, by a steady states analysis of the network, three different temperature stress regimes appear: normal, acute, and chronic, where normal stress corresponds to pseudo thermal adaption. The protein triage that governs the fate of damaged proteins or the different stress regimes are consequences of the titration mechanism. The simplicity of the present model is of interest in order to study detailed modelling of cross regulation between the HSR and other major genetic networks like the cell cycle or the circadian clock.

  12. Order by Quenched Disorder in the Model Triangular Antiferromagnet RbFe (MoO4 )2

    Science.gov (United States)

    Smirnov, A. I.; Soldatov, T. A.; Petrenko, O. A.; Takata, A.; Kida, T.; Hagiwara, M.; Shapiro, A. Ya.; Zhitomirsky, M. E.

    2017-07-01

    We observe a disappearance of the 1 /3 magnetization plateau and a striking change of the magnetic configuration under a moderate doping of the model triangular antiferromagnet RbFe (MoO4 )2 . The reason is an effective lifting of degeneracy of mean-field ground states by a random potential of impurities, which compensates, in the low-temperature limit, the fluctuation contribution to free energy. These results provide a direct experimental confirmation of the fluctuation origin of the ground state in a real frustrated system. The change of the ground state to a least collinear configuration reveals an effective positive biquadratic exchange provided by the structural disorder. On heating, doped samples regain the structure of a pure compound, thus allowing for an investigation of the remarkable competition between thermal and structural disorder.

  13. Assimilation of coastal acoustic tomography data using an unstructured triangular grid ocean model for water with complex coastlines and islands

    Science.gov (United States)

    Zhu, Ze-Nan; Zhu, Xiao-Hua; Guo, Xinyu; Fan, Xiaopeng; Zhang, Chuanzheng

    2017-09-01

    For the first time, we present the application of an unstructured triangular grid to the Finite-Volume Community Ocean Model using the ensemble Kalman filter scheme, to assimilate coastal acoustic tomography (CAT) data. The fine horizontal and vertical current field structures around the island inside the observation region were both reproduced well. The assimilated depth-averaged velocities had better agreement with the independent acoustic Doppler current profiler (ADCP) data than the velocities obtained by inversion and simulation. The root-mean-square difference (RMSD) between depth-averaged current velocities obtained by data assimilation and those obtained by ADCPs was 0.07 m s-1, which was less than the corresponding difference obtained by inversion and simulation (0.12 and 0.17 m s-1, respectively). The assimilated vertical layer velocities also exhibited better agreement with ADCP than the velocities obtained by simulation. RMSDs between assimilated and ADCP data in vertical layers ranged from 0.02 to 0.14 m s-1, while RMSDs between simulation and ADCP data ranged from 0.08 to 0.27 m s-1. These results indicate that assimilation had the highest accuracy. Sensitivity experiments involving the elimination of sound transmission lines showed that missing data had less impact on assimilation than on inversion. Sensitivity experiments involving the elimination of CAT stations showed that the assimilation with four CAT stations was the relatively economical and reasonable procedure in this experiment. These results indicate that, compared with inversion and simulation, data assimilation of CAT data with an unstructured triangular grid is more effective in reconstructing the current field.

  14. Isothermal Titration Calorimetry and Fluorescence Spectroscopy Study Of Asphaltene Self-Association In Toluene And Interaction With A Model Resin

    DEFF Research Database (Denmark)

    Garcia, Daniel Merino; Andersen, Simon Ivar

    2002-01-01

    This article collects the work performed by Isothermal Titration Caloritnetry (ITC) in the study of the self-association of asphaltenes in toluene solutions. Calorimetric experiments show that asphaltenes, start self-associating at very low concentrations and that the existence of a Critical...... with the results of the titration of three model molecules: nonylphenol, which associates by means of hydrogen bond formation, and coronene and pyrene, which associates by stacking. The results obtained leave open the question about the model-stacking molecules, as it was not possible to elucidate whether they do...

  15. Charge characteristics of humic and fulvic acids: comparative analysis by colloid titration and potentiometric titration with continuous pK-distribution function model.

    Science.gov (United States)

    Bratskaya, S; Golikov, A; Lutsenko, T; Nesterova, O; Dudarchik, V

    2008-09-01

    Charge characteristics of humic and fulvic acids of a different origin (inshore soils, peat, marine sediments, and soil (lysimetric) waters) were evaluated by means of two alternative methods - colloid titration and potentiometric titration. In order to elucidate possible limitations of the colloid titration as an express method of analysis of low content of humic substances we monitored changes in acid-base properties and charge densities of humic substances with soil depth, fractionation, and origin. We have shown that both factors - strength of acidic groups and molecular weight distribution in humic and fulvic acids - can affect the reliability of colloid titration. Due to deviations from 1:1 stoichiometry in interactions of humic substances with polymeric cationic titrant, the colloid titration can underestimate total acidity (charge density) of humic substances with domination of weak acidic functional groups (pK>6) and high content of the fractions with molecular weight below 1kDa.

  16. Magnons and excitation continuum in XXZ triangular antiferromagnetic model: Application to Ba3CoSb2O9

    Science.gov (United States)

    Ghioldi, E. A.; Mezio, A.; Manuel, L. O.; Singh, R. R. P.; Oitmaa, J.; Trumper, A. E.

    2015-04-01

    We investigate the excitation spectrum of the triangular-lattice antiferromagnetic XXZ model using series expansion and mean field Schwinger boson approaches. The single-magnon spectrum computed with series expansion exhibits rotonic minima at the middle points of the edges of the Brillouin zone, for all values of the anisotropy parameter in the range 0 ≤Jz/J ≤1 . Based on the good agreement with series expansion for the single-magnon spectrum, we compute the full dynamical magnetic structure factor within the mean field Schwinger boson approach to investigate the relevance of the XXZ model for the description of the unusual spectrum found recently in Ba3CoSb2O9 . In particular, we obtain an extended continuum above the spin wave excitations, which is further enhanced and brought closer to those observed in Ba3CoSb2O9 with the addition of a second neighbor exchange interaction approximately 15 % of the nearest-neighbor value. Our results support the idea that excitation continuum with substantial spectral-weight are generically present in two-dimensional frustrated spin systems and fractionalization in terms of bosonic spinons presents an efficient way to describe them.

  17. Phase diagram of the quantum Ising model with long-range interactions on an infinite-cylinder triangular lattice

    Science.gov (United States)

    Saadatmand, S. N.; Bartlett, S. D.; McCulloch, I. P.

    2018-04-01

    Obtaining quantitative ground-state behavior for geometrically-frustrated quantum magnets with long-range interactions is challenging for numerical methods. Here, we demonstrate that the ground states of these systems on two-dimensional lattices can be efficiently obtained using state-of-the-art translation-invariant variants of matrix product states and density-matrix renormalization-group algorithms. We use these methods to calculate the fully-quantitative ground-state phase diagram of the long-range interacting triangular Ising model with a transverse field on six-leg infinite-length cylinders and scrutinize the properties of the detected phases. We compare these results with those of the corresponding nearest neighbor model. Our results suggest that, for such long-range Hamiltonians, the long-range quantum fluctuations always lead to long-range correlations, where correlators exhibit power-law decays instead of the conventional exponential drops observed for short-range correlated gapped phases. Our results are relevant for comparisons with recent ion-trap quantum simulator experiments that demonstrate highly-controllable long-range spin couplings for several hundred ions.

  18. base titration

    African Journals Online (AJOL)

    The pH and temperature in the titration cell were monitored using single junction electrodes and platinum resistance thermometers, respectively. A constant supply of nitrogen gas in the cell was used to maintain inert conditions. The whole set up was interfaced with a computer for easy data acquisition. It was observed that ...

  19. Thermal Entanglement in XXZ Heisenberg Model for Coupled Spin-Half and Spin-One Triangular Cell

    Science.gov (United States)

    Najarbashi, Ghader; Balazadeh, Leila; Tavana, Ali

    2018-01-01

    In this paper, we investigate the thermal entanglement of two-spin subsystems in an ensemble of coupled spin-half and spin-one triangular cells, (1/2, 1/2, 1/2), (1/2, 1, 1/2), (1, 1/2, 1) and (1, 1, 1) with the XXZ anisotropic Heisenberg model subjected to an external homogeneous magnetic field. We adopt the generalized concurrence as the measure of entanglement which is a good indicator of the thermal entanglement and the critical points in the mixed higher dimensional spin systems. We observe that in the near vicinity of the absolute zero, the concurrence measure is symmetric with respect to zero magnetic field and changes abruptly from a non-null to null value for a critical magnetic field that can be signature of a quantum phase transition at finite temperature. The analysis of concurrence versus temperature shows that there exists a critical temperature, that depends on the type of the interaction, i.e. ferromagnetic or antiferromagnetic, the anisotropy parameter and the strength of the magnetic field. Results show that the pairwise thermal entanglement depends on the third spin which affects the maximum value of the concurrence at absolute zero and at quantum critical points.

  20. Kitaev-Heisenberg models for iridates on the triangular, hyperkagome, kagome, fcc, and pyrochlore lattices

    Science.gov (United States)

    Kimchi, Itamar; Vishwanath, Ashvin

    2014-01-01

    The Kitaev-Heisenberg (KH) model has been proposed to capture magnetic interactions in iridate Mott insulators on the honeycomb lattice. We show that analogous interactions arise in many other geometries built from edge-sharing IrO6 octahedra, including the pyrochlore and hyperkagome lattices relevant to Ir2O4 and Na4Ir3O8, respectively. The Kitaev spin liquid exact solution does not generalize to these lattices. However, a different, exactly soluble point of the honeycomb lattice KH model, obtained by a four-sublattice transformation to a ferromagnet, generalizes to all of these lattices and even to certain additional further neighbor Heisenberg couplings. A Klein four-group ≅Z2×Z2 structure is associated with this mapping (hence Klein duality). A finite lattice admits the duality if a simple geometrical condition is met. This duality predicts fluctuation-free ordered states on these different 2D and 3D lattices, which are analogues of the honeycomb lattice KH stripy order. This result is used in conjunction with a semiclassical Luttinger-Tisza approximation to obtain phase diagrams for KH models on the different lattices. We also discuss a Majorana fermion based mean-field theory at the Kitaev point, which is exact on the honeycomb lattice, for the KH models on the different lattices. We attribute the rich behavior of these models to the interplay of geometric frustration and frustration induced by spin-orbit coupling.

  1. Hardware Neural Networks Modeling for Computing Different Performance Parameters of Rectangular, Circular, and Triangular Microstrip Antennas

    Directory of Open Access Journals (Sweden)

    Taimoor Khan

    2014-01-01

    Full Text Available In the last one decade, neural networks-based modeling has been used for computing different performance parameters of microstrip antennas because of learning and generalization features. Most of the created neural models are based on software simulation. As the neural networks show massive parallelism inherently, a parallel hardware needs to be created for creating faster computing machine by taking the advantages of the parallelism of the neural networks. This paper demonstrates a generalized neural networks model created on field programmable gate array- (FPGA- based reconfigurable hardware platform for computing different performance parameters of microstrip antennas. Thus, the proposed approach provides a platform for developing low-cost neural network-based FPGA simulators for microwave applications. Also, the results obtained by this approach are in very good agreement with the measured results available in the literature.

  2. Heredity for triangular operators

    Directory of Open Access Journals (Sweden)

    Henry Crawford Rhaly Jr.

    2013-12-01

    Full Text Available A proof is given that if the lower triangular infinite matrix $T$ acts boundedly on $\\ell^2$ and U is the unilateral shift, the sequence $(U^*^nTU^n$ inherits from $T$ the following properties: posinormality, dominance, $M$-hyponormality, hyponormality, normality, compactness, and noncompactness.  Also, it is demonstrated that the upper triangular matrix $T^*$ is dominant if and only if $T$ is a diagonal matrix.

  3. Tests of Predictions of the Algebraic Cluster Model: the Triangular D 3h Symmetry of 12C

    Science.gov (United States)

    Gai, Moshe

    2016-07-01

    A new theoretical approach to clustering in the frame of the Algebraic Cluster Model (ACM) has been developed. It predicts rotation-vibration structure with rotational band of an oblate equilateral triangular symmetric spinning top with a D 3h symmetry characterized by the sequence of states: 0+, 2+, 3-, 4±, 5- with a degenerate 4+ and 4- (parity doublet) states. Our measured new 2+ 2 in 12C allows the first study of rotation-vibration structure in 12C. The newly measured 5- state and 4- states fit very well the predicted ground state rotational band structure with the predicted sequence of states: 0+, 2+, 3-, 4±, 5- with almost degenerate 4+ and 4- (parity doublet) states. Such a D 3h symmetry is characteristic of triatomic molecules, but it is observed in the ground state rotational band of 12C for the first time in a nucleus. We discuss predictions of the ACM of other rotation-vibration bands in 12 C such as the (0+) Hoyle band and the (1-) bending mode with prediction of (“missing 3- and 4-”) states that may shed new light on clustering in 12C and light nuclei. In particular, the observation (or non observation) of the predicted (“missing”) states in the Hoyle band will allow us to conclude the geometrical arrangement of the three alpha particles composing the Hoyle state at 7.6542 MeV in 12C. We discuss proposed research programs at the Darmstadt S-DALINAC and at the newly constructed ELI-NP facility near Bucharest to test the predictions of the ACM in isotopes of carbon.

  4. Triangular spiral tilings

    International Nuclear Information System (INIS)

    Sushida, Takamichi; Hizume, Akio; Yamagishi, Yoshikazu

    2012-01-01

    The topology of spiral tilings is intimately related to phyllotaxis theory and continued fractions. A quadrilateral spiral tiling is determined by a suitable chosen triple (ζ, m, n), where ζ element of D/R, and m and n are relatively prime integers. We give a simple characterization when (ζ, m, n) produce a triangular spiral tiling. When m and n are fixed, the admissible generators ζ form a curve in the unit disk. The family of triangular spiral tilings with opposed parastichy pairs (m, n) is parameterized by the divergence angle arg (ζ), while triangular spiral tilings with non-opposed parastichy pairs are parameterized by the plastochrone ratio 1/|ζ|. The generators for triangular spiral tilings with opposed parastichy pairs are not dense in the complex parameter space, while those with non-opposed parastichy pairs are dense. The proofs will be given in a general setting of spiral multiple tilings. We present paper-folding (origami) sheets that build spiral towers whose top-down views are triangular tilings. (paper)

  5. Acid base characterization of the surface of mixed species of algae Spirulin by potentiometric titration and discrete site distribution model

    OpenAIRE

    Lima, Elizabete C. de; Masini, Jorge C.

    1999-01-01

    Acid base properties of mixed species of the microalgae Spirulina were studied by potentiometric titration in medium of 0.01 and 0.10 mols L-1 NaNO3 at 25.0±0.10 C using modified Gran functions or nonlinear regression techniques for data fitting. The discrete site distribution model was used, permitting the characterization of five classes of ionizable sites in both ionic media. This fact suggests that the chemical heterogeneity of the ionizable sites on the cell surface plays a major role on...

  6. Algebraic Bethe ansatz for the XXZ Heisenberg spin chain with triangular boundaries and the corresponding Gaudin model

    Science.gov (United States)

    Manojlović, N.; Salom, I.

    2017-10-01

    The implementation of the algebraic Bethe ansatz for the XXZ Heisenberg spin chain in the case, when both reflection matrices have the upper-triangular form is analyzed. The general form of the Bethe vectors is studied. In the particular form, Bethe vectors admit the recurrent procedure, with an appropriate modification, used previously in the case of the XXX Heisenberg chain. As expected, these Bethe vectors yield the strikingly simple expression for the off-shell action of the transfer matrix of the chain as well as the spectrum of the transfer matrix and the corresponding Bethe equations. As in the XXX case, the so-called quasi-classical limit gives the off-shell action of the generating function of the corresponding trigonometric Gaudin Hamiltonians with boundary terms.

  7. Energy Minimization of Discrete Protein Titration State Models Using Graph Theory

    Science.gov (United States)

    Purvine, Emilie; Monson, Kyle; Jurrus, Elizabeth; Star, Keith; Baker, Nathan A.

    2016-01-01

    There are several applications in computational biophysics which require the optimization of discrete interacting states; e.g., amino acid titration states, ligand oxidation states, or discrete rotamer angles. Such optimization can be very time-consuming as it scales exponentially in the number of sites to be optimized. In this paper, we describe a new polynomial-time algorithm for optimization of discrete states in macromolecular systems. This algorithm was adapted from image processing and uses techniques from discrete mathematics and graph theory to restate the optimization problem in terms of “maximum flow-minimum cut” graph analysis. The interaction energy graph, a graph in which vertices (amino acids) and edges (interactions) are weighted with their respective energies, is transformed into a flow network in which the value of the minimum cut in the network equals the minimum free energy of the protein, and the cut itself encodes the state that achieves the minimum free energy. Because of its deterministic nature and polynomial-time performance, this algorithm has the potential to allow for the ionization state of larger proteins to be discovered. PMID:27089174

  8. Coulometric titration at low temperatures-nonstoichiometric silver selenide

    OpenAIRE

    Beck, Gesa K.; Janek, Jürgen

    2003-01-01

    A modified coulometric titration technique is described for the investigation of nonstoichiometric phases at low temperatures. It allows to obtain titration curves at temperatures where the conventional coulometric titration technique fails because of too small chemical diffusion coefficients of the mobile component. This method for indirect coulometric titration is applied to silver selenide between -100 and 100 °C. The titration curves are analyzed on the basis of a defect chemical model an...

  9. Geochemical modeling of reactions and partitioning of trace metals and radionuclides during titration of contaminated acidic sediments.

    Science.gov (United States)

    Zhang, Fan; Luo, Wensui; Parker, Jack C; Spalding, Brian P; Brooks, Scott C; Watson, David B; Jardine, Philip M; Gu, Baohua

    2008-11-01

    Many geochemical reactions that control aqueous metal concentrations are directly affected by solution pH. However, changes in solution pH are strongly buffered by various aqueous phase and solid phase precipitation/dissolution and adsorption/desorption reactions. The ability to predict acid-base behavior of the soil-solution system is thus critical to predict metal transport under variable pH conditions. This studywas undertaken to develop a practical generic geochemical modeling approach to predict aqueous and solid phase concentrations of metals and anions during conditions of acid or base additions. The method of Spalding and Spalding was utilized to model soil buffer capacity and pH-dependent cation exchange capacity by treating aquifer solids as a polyprotic acid. To simulate the dynamic and pH-dependent anion exchange capacity, the aquifer solids were simultaneously treated as a polyprotic base controlled by mineral precipitation/ dissolution reactions. An equilibrium reaction model that describes aqueous complexation, precipitation, sorption and soil buffering with pH-dependent ion exchange was developed using HydroGeoChem v5.0 (HGC5). Comparison of model results with experimental titration data of pH, Al, Ca, Mg, Sr, Mn, Ni, Co, and SO4(2-) for contaminated sediments indicated close agreement suggesting that the model could potentially be used to predictthe acid-base behavior of the sediment-solution system under variable pH conditions.

  10. The Effect of Metal Concentration on the Parameters Derived from Complexometric Titrations of Trace Elements in Seawater—A Model Study

    NARCIS (Netherlands)

    Gledhill, M.; Gerringa, L.J.A.

    2017-01-01

    In this study we examine the impact of dissolved metal concentrations on the parametersthat are commonly determined from complexometric titrations in seawater. We use thenon-ideal competitive adsorption (NICA) model within the framework of the chemicalspeciation program visual MINTEQ with iron as a

  11. Invariants of triangular Lie algebras

    International Nuclear Information System (INIS)

    Boyko, Vyacheslav; Patera, Jiri; Popovych, Roman

    2007-01-01

    Triangular Lie algebras are the Lie algebras which can be faithfully represented by triangular matrices of any finite size over the real/complex number field. In the paper invariants ('generalized Casimir operators') are found for three classes of Lie algebras, namely those which are either strictly or non-strictly triangular, and for so-called special upper triangular Lie algebras. Algebraic algorithm of Boyko et al (2006 J. Phys. A: Math. Gen.39 5749 (Preprint math-ph/0602046)), developed further in Boyko et al (2007 J. Phys. A: Math. Theor.40 113 (Preprint math-ph/0606045)), is used to determine the invariants. A conjecture of Tremblay and Winternitz (2001 J. Phys. A: Math. Gen.34 9085), concerning the number of independent invariants and their form, is corroborated

  12. Green chemistry volumetric titration kit for pharmaceutical ...

    African Journals Online (AJOL)

    Stopcock SC and Spring Sp models of Econoburette (Calibrated, RTC (NR), Ministry of Small Scale Industries, Government of India), developed for semimicro volumetric titration of pharmaceutical formulations are reported. These are economized and risk free titration where pipette is replaced by an inbuilt pipette and ...

  13. The Effect of Metal Concentration on the Parameters Derived from Complexometric Titrations of Trace Elements in Seawater—A Model Study

    OpenAIRE

    Gledhill, M.; Gerringa, L.J.A.

    2017-01-01

    In this study we examine the impact of dissolved metal concentrations on the parameters that are commonly determined from complexometric titrations in seawater. We use the non-ideal competitive adsorption (NICA) model within the framework of the chemical speciation program visual MINTEQ with iron as a model metal. We demonstrate that dissolved iron concentrations effect the determined parameters for a heterogeneous binding site distribution with a fixed concentration of dissolved organic carb...

  14. Anti-Inflammatory Effect of Titrated Extract of Centella asiatica in Phthalic Anhydride-Induced Allergic Dermatitis Animal Model.

    Science.gov (United States)

    Park, Ju Ho; Choi, Ji Yeon; Son, Dong Ju; Park, Eun Kyung; Song, Min Jong; Hellström, Mats; Hong, Jin Tae

    2017-03-30

    Centella asiatica has potent antioxidant and anti-inflammatory properties. However, its anti-dermatitic effect has not yet been reported. In this study, we investigated the anti-dermatitic effects of titrated extract of Centella asiatica (TECA) in a phthalic anhydride (PA)-induced atopic dermatitis (AD) animal model as well as in vitro model. An AD-like lesion was induced by the topical application of five percent PA to the dorsal skin or ear of Hos:HR-1 mouse. After AD induction, 100 μL of 0.2% and 0.4% of TECA (40 μg or 80 μg/cm²) was spread on the dorsum of the ear or back skin three times a week for four weeks. We evaluated dermatitis severity, histopathological changes and changes in protein expression by Western blotting for inducible nitric oxide synthase (iNOS), cyclooxygenase-2 (COX-2), and NF-κB activity, which were determined by electromobility shift assay (EMSA). We also measured TNF-α, IL-1β, IL-6, and IgE concentration in the blood of AD mice by enzyme-linked immunosorbent assay (ELISA). TECA treatment attenuated the development of PA-induced atopic dermatitis. Histological analysis showed that TECA inhibited hyperkeratosis, mast cells and infiltration of inflammatory cells. TECA treatment inhibited expression of iNOS and COX-2, and NF-κB activity as well as the release of TNF-α, IL-1β, IL-6, and IgE. In addition, TECA (1, 2, 5 μg/mL) potently inhibited Lipopolysaccharide (LPS) (1 μg/mL)-induced NO production, expression of iNOS and COX-2, and NF-κB DNA binding activities in RAW264.7 macrophage cells. Our data demonstrated that TECA could be a promising agent for AD by inhibition of NF-κB signaling.

  15. Determination of thermodynamic potentials and the aggregation number for micelles with the mass-action model by isothermal titration calorimetry

    DEFF Research Database (Denmark)

    Olesen, Niels Erik; Westh, Peter; Holm, René

    2015-01-01

    The aggregation number (n), thermodynamic potentials (ΔG, ΔH, ΔS) and critical micelle concentration (CMC) for 6 natural bile salts were determined on the basis of both original and previously published isothermal titration calorimetry (ITC) data. Different procedures to estimate parameters...

  16. Subjectivity, objectivity, and triangular space.

    Science.gov (United States)

    Britton, Ronald

    2004-01-01

    The author reviews his ideas on subjectivity, objectivity, and the third position in the psychoanalytic encounter, particularly in clinical work with borderline and narcissistic patients. Using the theories of Melanie Klein and Wilfred Bion as a basis, the author describes his concept of triangular space. A case presentation of a particular type of narcissistic patient illustrates the principles discussed.

  17. Ultrasound fields from triangular apertures

    DEFF Research Database (Denmark)

    Jensen, Jørgen Arendt

    1996-01-01

    The pulsed field from a triangular aperture mounted in an infinite, rigidbaffle is calculated. The approach of spatial impulse responses,as developed by Tupholme and Stepanishen, is used. By this both the emitted and received pulsed ultrasound field can be found for any transducerexcitation...

  18. Automated uranium titration system

    International Nuclear Information System (INIS)

    Takahashi, M.; Kato, Y.

    1983-01-01

    An automated titration system based on the Davies-Gray method has been developed for accurate determination of uranium. The system consists of a potentiometric titrator with precise burettes, a sample changer, an electronic balance and a desk-top computer with a printer. Fifty-five titration vessels are loaded in the sample changer. The first three contain the standard solution for standardizing potassium dichromate titrant, and the next two and the last two contain the control samples for data quality assurance. The other forty-eight measurements are carried out for sixteen unknown samples. Sample solution containing about 100 mg uranium is taken in a titration vessel. At the pretreatment position, uranium (VI) is reduced to uranium (IV) by iron (II). After the valency adjustment, the vessel is transferred to the titration position. The rate of titrant addition is automatically controlled to be slower near the end-point. The last figure (0.01 mL) of the equivalent titrant volume for uranium is calculated from the potential change. The results obtained with this system on 100 mg uranium gave a precision of 0.2% (RSD,n=3) and an accuracy of better than 0.1%. Fifty-five titrations are accomplished in 10 hours. (author)

  19. The Effect of Metal Concentration on the Parameters Derived from Complexometric Titrations of Trace Elements in Seawater—A Model Study

    Directory of Open Access Journals (Sweden)

    Martha Gledhill

    2017-08-01

    Full Text Available In this study we examine the impact of dissolved metal concentrations on the parameters that are commonly determined from complexometric titrations in seawater. We use the non-ideal competitive adsorption (NICA model within the framework of the chemical speciation program visual MINTEQ with iron as a model metal. We demonstrate that dissolved iron concentrations effect the determined parameters for a heterogeneous binding site distribution with a fixed concentration of dissolved organic carbon. The commonly used terms “ligand concentration” and “binding constant” are therefore dependent on metal concentration, so we adopt the terminology suggested by Town and Filella (2000 and use the terms ligand quotient and stability quotient here. The systematic increase in the ligand quotient with dissolved iron concentration likely contributes toward the trend of increasing ligand quotient with dissolved iron concentration observed in field studies, and makes it hard to assign an objective meaning to the parameter. We suggest that calculation of the side reaction coefficient, a parameter that describes the probability that any added metal will be complexed, could be less prone to bias and misinterpretation than calculation of conditional stability and ligand quotients. We explore the impact of experimental design on side reaction coefficients by applying different detection windows, and multiwindow and reverse titration approaches. We identify the method that results in the best estimates of side reaction coefficients over a range of iron concentrations between 0.1 and 1.5 nmol L−1. We find that single window titrations can only reliably estimate side reaction coefficients over a limited range of iron concentrations. Multiwindow titrations provided estimates of side reaction coefficients within the 99% confidence interval of the values calculated directly from the NICA model at all iron concentrations examined here. We recommend that future

  20. Filtrates & Residues: Olfactory Titration.

    Science.gov (United States)

    Wood, John T.; Eddy, Roberta M.

    1996-01-01

    Presents an experiment that uses a unique acid-base indicator--the odor of raw onion--to indicate the end point of the titration of sodium hydroxide with hydrochloric acid. Allows the student to detect the completion of the neutralization reaction by olfaction rather than sight. (JRH)

  1. ''Titration'' polymerization of monovinylacetylene

    NARCIS (Netherlands)

    Mavinkurve, A; Visser, S; vandenBroek, W; Pennings, AJ

    1996-01-01

    A polymer consisting of a saturated carbon backbone with pendent acetylenic groups was prepared from monovinylacetylene. A titration was performed between the monomer and tertiary butyllithium, its lithiating agent. The charge transfer complex formed between the solvent THF and the tertiary

  2. UWB Directive Triangular Patch Antenna

    Directory of Open Access Journals (Sweden)

    A. C. Lepage

    2008-01-01

    Full Text Available Compact directive UWB antennas are presented in this paper. We propose an optimization of the F-probe fed triangular patch antenna. The new design achieves an impedance bandwidth of 69% (3–6.15 GHz and presents good radiation characteristics over the whole impedance bandwidth. The average gain is 6.1 dB. A time-domain study has been performed to characterize the antenna behavior in case a UWB pulse is used. Finally, we propose an alternative solution to facilitate the manufacturing process using metallized foam technology. It also improves the robustness of the antenna as well as reducing its cost.

  3. Titration Curves: Fact and Fiction.

    Science.gov (United States)

    Chamberlain, John

    1997-01-01

    Discusses ways in which datalogging equipment can enable titration curves to be measured accurately and how computing power can be used to predict the shape of curves. Highlights include sources of error, use of spreadsheets to generate titration curves, titration of a weak acid with a strong alkali, dibasic acids, weak acid and weak base, and…

  4. Triangular Norms, Triangular Conorms, and Some Related Concepts

    Directory of Open Access Journals (Sweden)

    Angel Garrido

    2011-01-01

    Full Text Available Abstract. Mathematically considered, a Triangular Norm is a kind of binary operation frequently used in the context of Probabilistic Metric Spaces, but also in other very interesting fields, as may be Fuzzy Logic, or in general, in Multi-Valued Logic (MVL. The T-conorm, or S-norm, is a dual concept. Both ideas allow us to generalize the intersection and the union in a Lattice, or disjunction and conjunction in Logic. Also may be very interesting to introduce a special class of real monotone operations. We refer to the so-called Copulas, very useful in many fields. So, we offer now a comprehensive analysis of all these aggregation operators.

  5. An equilibrium model for ligand-modified micellar-enhanced ultrafiltration. Selective separation of metal ions using iminoacetic substituted polyamines and a theoretical model for the titration behavior of polyamines

    Energy Technology Data Exchange (ETDEWEB)

    Dharmawardana, Udeni Rajaratna [Univ. of Oklahoma, Norman, OK (United States)

    1992-01-01

    This thesis consists of three chapters. Chapter 1, An equilibrium model for ligand-modified micellar-enhanced ultrafiltration, describes a theoretical model and experimental investigations which used the semi-equilibrium-dialysis method with N-n-dodecyl iminodiacetic acid as the ligand. In Chapter 2, Selective separation of metal ions using iminoacetic substituted polyamines, polyamines with a substituted ligand group are synthesized and used in investigating selective separation of copper ions from aqueous solution. In Chapter 3, A theoretical model for the titration behavior of polyamines, a novel approach to explain the titration behavior of polymeric amines based on the binding behavior of counterions is described. The application of this study is to the investigation of inexpensive and efficient methods of industrial waste water treatment.

  6. Problems on triangular norms and related operators

    Czech Academy of Sciences Publication Activity Database

    Klement, E.P.; Mesiar, Radko; Pap, E.

    2004-01-01

    Roč. 23, č. 145 (2004), s. 471-479 ISSN 0165-0114 R&D Projects: GA ČR GA402/04/1026 Institutional research plan: CEZ:AV0Z1075907 Keywords : triangular norm * triangular conorm * aggregation operator Subject RIV: BA - General Mathematics Impact factor: 0.734, year: 2004

  7. Ion-selective electrodes in potentiometric titrations; a new method for processing and evaluating titration data.

    Science.gov (United States)

    Granholm, Kim; Sokalski, Tomasz; Lewenstam, Andrzej; Ivaska, Ari

    2015-08-12

    A new method to convert the potential of an ion-selective electrode to concentration or activity in potentiometric titration is proposed. The advantage of this method is that the electrode standard potential and the slope of the calibration curve do not have to be known. Instead two activities on the titration curve have to be estimated e.g. the starting activity before the titration begins and the activity at the end of the titration in the presence of large excess of titrant. This new method is beneficial when the analyte is in a complexed matrix or in a harsh environment which affects the properties of the electrode and the traditional calibration procedure with standard solutions cannot be used. The new method was implemented both in a method of linearization based on the Grans's plot and in determination of the stability constant of a complex and the concentration of the complexing ligand in the sample. The new method gave accurate results when using titrations data from experiments with samples of known composition and with real industrial harsh black liquor sample. A complexometric titration model was also developed. Copyright © 2015 Elsevier B.V. All rights reserved.

  8. Potentiometric titration with polarized electrodes

    International Nuclear Information System (INIS)

    Chikryzova, E.G.

    1977-01-01

    Based on the analysis of the works carried out during 1911-75 consideration is given to the present state of the method of potentiometric titration with polarized electrodes. The material is generalized in the tabular form indicating the elments of interest, titration conditions and the objects to be analyzed. The list and classification of the potentiometric titration methods intended for determining organic and inorganic substances are presented

  9. Gutzwiller's octagon and the triangular billiard T*(2,3,8) as models for the quantization of chaotic systems by Selberg's trace formula

    International Nuclear Information System (INIS)

    Ninnemann, H.

    1994-12-01

    Two strongly chaotic systems are investigated with respect to quantization rules based on Selberg's trace formula. One of them results from the action of a particular strictly hyperbolic Fuchsian group on the Poincare disk, leading to a compact Riemann surface of genus g=2. This Fuchsian group is denoted as Gutzwiller's group. The other one is a billiard inside a hyperbolic triangle, which is generated by the operation of a reflection group denoted as T * (2,3,8). Since both groups belong to the class of arithmetical groups, their elements can be characterized explicitly as 2x2 matrices containing entries, which are algebraic numbers subject to a particular set of restrictions. In the case of Gutzwiller's group this property can be used to determine the geodesic length spectrum of the associated dynamical system completely up to some cutoff length. For the triangular billiar T * (2,3,8) the geodesic length spectrum is calculated by building group elements as products of a suitable set of generators and separating a unique representative for each conjugacy class. The presence of reflections in T * (2,3,8) introduces additional classes of group elements besides the hyperbolic ones, which correspond to periodic orbits of the dynamical system. Due to different choices of boundary conditions along the edges of the fundamental domain of T * (2,3,8), several quantum mechanical systems are associated to one classical system. It has been observed, that these quantum mechanical systems can be divided into two classes according to the behavior of their spectral statistics. This peculiarity is examined from the point of view of classical quantities entering quantization rules. It can be traced back to a subtle influence of the boundary conditions, which introduces contributions from non-periodic orbits for one of the two classes. (orig.)

  10. Quantitative Analysis of Mixtures of Monoprotic Acids Applying Modified Model-Based Rank Annihilation Factor Analysis on Variation Matrices of Spectrophotometric Acid-Base Titrations

    Directory of Open Access Journals (Sweden)

    Ebrahim Ghorbani-Kalhor

    2015-04-01

    Full Text Available In the current work, a new version of rank annihilation factor analysis was developedto circumvent the rank deficiency problem in multivariate data measurements.Simultaneous determination of dissociation constant and concentration of monoprotic acids was performed by applying model-based rank annihilation factor analysis on variation matrices of spectrophotometric acid-base titrations data. Variation matrices can be obtained by subtracting first row of data matrix from all rows of the main data matrix. This method uses variation matrices instead of multivariate spectrophotometric acid-base titrations matrices to circumvent the rank deficiency problem in the rank quantitation step. The applicability of this approach was evaluated by simulated data at first stage, then the binary mixtures of ascorbic and sorbic acids as model compounds were investigated by the proposed method. At the end, the proposed method was successfully applied for resolving the ascorbic and sorbic acid in an orange juice real sample. Therefore, unique results were achieved by applying rank annihilation factor analysis on variation matrix and using hard soft model combination advantage without any problem and difficulty in rank determination. Normal 0 false false false EN-US X-NONE AR-SA /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Table Normal"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-priority:99; mso-style-parent:""; mso-padding-alt:0cm 5.4pt 0cm 5.4pt; mso-para-margin-top:0cm; mso-para-margin-right:0cm; mso-para-margin-bottom:10.0pt; mso-para-margin-left:0cm; line-height:115%; mso-pagination:widow-orphan; font-size:11.0pt; font-family:"Calibri","sans-serif"; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:Arial; mso-bidi-theme-font:minor-bidi; mso-bidi-language:AR-SA;}    

  11. Opening the Door on Triangular Numbers

    Science.gov (United States)

    McMartin, Kimberley; McMaster, Heather

    2016-01-01

    As an alternative to looking solely at linear functions, a three-lesson learning progression developed for Year 6 students that incorporates triangular numbers to develop children's algebraic thinking is described and evaluated.

  12. Functional Contractive Maps in Triangular Symmetric Spaces

    Directory of Open Access Journals (Sweden)

    Mihai Turinici

    2013-01-01

    Full Text Available Some fixed point results are given for a class of functional contractions acting on (reflexive triangular symmetric spaces. Technical connections with the corresponding theories over (standard metric and partial metric spaces are also being established.

  13. Local hydrodynamic characteristics of regular triangular lattice of rods

    International Nuclear Information System (INIS)

    Mantlik, F.; Hejna, J.; Cervenka, J.

    1976-06-01

    Results are presented of an experimental investigation of the friction factor, velocity fields and shear stress distribution around a wetted perimeter in a rod bundle of a triangular lattice with a pitch-to-diameter ratio of 1.17. Measurements were made on 19-rod aerodynamical model at the Reynolds number of 42 300 and 211 000. The results indicated a highly significant effect of secondary flow. (author)

  14. Tracer-monitored flow titrations.

    Science.gov (United States)

    Sasaki, Milton K; Rocha, Diogo L; Rocha, Fábio R P; Zagatto, Elias A G

    2016-01-01

    The feasibility of implementing tracer-monitored titrations in a flow system is demonstrated. A dye tracer is used to estimate the instant sample and titrant volumetric fractions without the need for volume, mass or peak width measurements. The approach was applied to spectrophotometric flow titrations involving variations of sample and titrant flow-rates (i.e. triangle programmed technique) or concentration gradients established along the sample zone (i.e. flow injection system). Both strategies required simultaneous monitoring of two absorbing species, namely the titration indicator and the dye tracer. Mixing conditions were improved by placing a chamber with mechanical stirring in the analytical path aiming at to minimize diffusional effects. Unlike most of flow-based titrations, the innovation is considered as a true titration, as it does not require a calibration curve thus complying with IUPAC definition. As an application, acidity evaluation in vinegars involving titration with sodium hydroxide was selected. Phenolphthalein and brilliant blue FCF were used as indicator and dye tracer, respectively. Effects of sample volume, titrand/titrant concentrations and flow rates were investigated aiming at improved accuracy and precision. Results were reliable and in agreement with those obtained by a reference titration procedure. Copyright © 2015 Elsevier B.V. All rights reserved.

  15. Iodine losses during Winkler titrations

    Science.gov (United States)

    Knapp, George P.; Stalcup, Marvel C.; Stanley, Robert J.

    1991-01-01

    An experiment designed to measure iodine loss during the aliquot version of the Winkler titration for dissolved oxygen in seawater shows that 0.01-0.03 ml l -1 equivalent oxygen is lost at typical oceanic concentrations in the method presently used. A standardization technique, which mimics that employed during the titration of seawater samples, compensates for this iodine loss throughout the oceanic range. This result, contradicting an earlier report by GREEN and CARRITT (1966, Analyst, 91, 207-208), demonstrates that the whole-bottle method of oxygen titration is not to be preferred over the aliquot method.

  16. Amperometric, Bipotentiometric, and Coulometric Titration.

    Science.gov (United States)

    Stock, John T.

    1980-01-01

    Discusses recent review articles in various kinds of titration. Also discusses new research in apparatus and methodology, acid-base reactions, precipitation and complexing reactions, oxidation-reduction reactions, and nomenclature. Cites 338 references. (CS)

  17. A Hybrid Approach Combining the Multi-Temporal Scale Spatio-Temporal Network with the Continuous Triangular Model for Exploring Dynamic Interactions in Movement Data: A Case Study of Football

    Directory of Open Access Journals (Sweden)

    Pengdong Zhang

    2018-01-01

    Full Text Available Benefiting from recent advantages in location-aware technologies, movement data are becoming ubiquitous. Hence, numerous research topics with respect to movement data have been undertaken. Yet, the research of dynamic interactions in movement data is still in its infancy. In this paper, we propose a hybrid approach combining the multi-temporal scale spatio-temporal network (MTSSTN and the continuous triangular model (CTM for exploring dynamic interactions in movement data. The approach mainly includes four steps: first, the relative trajectory calculus (RTC is used to derive three types of interaction patterns; second, for each interaction pattern, a corresponding MTSSTN is generated; third, for each MTSSTN, the interaction intensity measures and three centrality measures (i.e., degree, betweenness and closeness are calculated; finally, the results are visualized at multiple temporal scales using the CTM and analyzed based on the generated CTM diagrams. Based on the proposed approach, three distinctive aims can be achieved for each interaction pattern at multiple temporal scales: (1 exploring the interaction intensities between any two individuals; (2 exploring the interaction intensities among multiple individuals, and (3 exploring the importance of each individual and identifying the most important individuals. The movement data obtained from a real football match are used as a case study to validate the effectiveness of the proposed approach. The results demonstrate that the proposed approach is useful in exploring dynamic interactions in football movement data and discovering insightful information.

  18. Scalar spin chirality and quantum hall effect on triangular lattices

    Energy Technology Data Exchange (ETDEWEB)

    Martin, Ivar [Los Alamos National Laboratory; Batista, Cristian D [Los Alamos National Laboratory

    2008-01-01

    We study the Kondo Lattice and Hubbard models on a triangular lattice for band filling factor 3/4. We show that a simple non-coplanar chiral spin ordering (scalar spin chirality) is naturally realized in both models due to perfect nesting of the fermi surface. The resulting triple-Q magnetic ordering is a natural counterpart of the collinear Neel ordering of the half-filled square lattice Hubbard model. We show that the obtained chiral phase exhibits a spontaneous quantum Hall-effect with {sigma}{sub xy} = e{sup 2}/h.

  19. Modeling the electromagnetic cavity mode contributions to the THz emission from triangular Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8+δ} mesas

    Energy Technology Data Exchange (ETDEWEB)

    Klemm, Richard A., E-mail: klemm@physics.ucf.edu [Department of Physics, University of Central Florida, Orlando, FL 32816 (United States); Delfanazari, Kaveh; Tsujimoto, Manabu; Kashiwagi, Takanari; Kitamura, Takeo; Yamamoto, Takashi; Sawamura, Masashi; Ishida, Kazuya [Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573 (Japan); CREST, Japan Science and Technology Agency, Kawaguchi Center Building, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 (Japan); WPI-MANA, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Hattori, Toshiaki [Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573 (Japan); CREST, Japan Science and Technology Agency, Kawaguchi Center Building, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 (Japan); Kadowaki, Kazuo [Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573 (Japan); CREST, Japan Science and Technology Agency, Kawaguchi Center Building, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 (Japan); WPI-MANA, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)

    2013-08-15

    Highlights: ► New wave functions for the equilateral triangular patch antenna found. ► Most general wave functions for the equilateral patch antenna found. ► Accurate eigenvalues and wave functions for highly acute isosceles triangular patch antennas found. -- Abstract: In order to understand the radiation observed from the intrinsic Josephson junctions in triangular Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8+δ} mesas, we calculate the transverse magnetic (TM) electromagnetic modes for thin equilateral cavities. A new set of distinct but degenerate TM modes coexists with the known modes of Helszajn and James, but are expected to lead to distinct radiation angular distribution patterns. Although we have been unable to solve for the exact TM modes of a thin cavity of general acute isosceles triangular shape, we solved exactly the closely related problems of the TM cavity modes of two thin circumscribing “pie-shaped” wedges, which provide highly accurate approximations to very acute isosceles triangular cavities.

  20. TAPIR: a device for automatic titration with incremental weighing of the titration reagent

    International Nuclear Information System (INIS)

    Ganivet, Michel

    TAPIR is a titration device enabling automatic analyses with weighting of the titration reagent. The titration method used can be based on potentiometry, amperometry, color indicator change... The reproducibility is about 3.10 -4 [fr

  1. Green chemistry volumetric titration kit for pharmaceutical formulations: Econoburette

    Directory of Open Access Journals (Sweden)

    Man Singh

    2009-08-01

    Full Text Available Stopcock SC and Spring Sp models of Econoburette (Calibrated, RTC (NR, Ministry of Small Scale Industries, Government of India, developed for semimicro volumetric titration of pharmaceutical formulations are reported. These are economized and risk free titration where pipette is replaced by an inbuilt pipette and conical flask by inbuilt bulb. A step of pipetting of stock solution by mouth is deleted. It is used to allow solution exposure to user’s body. This risk is removed and even volatile and toxic solutions are titrated with full proof safety. Econoburette minimizes use of materials and time by 90 % and prevent discharge of polluting effluent to environment. Few acid and base samples are titrated and an analysis of experimental expenditure is described in the papers.

  2. The Hill-determinant perturbation theory with triangular propagators

    International Nuclear Information System (INIS)

    Znojil, M.

    1996-01-01

    A new version of the Rayleigh-Schroedinger perturbation prescription is proposed. Its main formal feature lies in an unusual choice of the model space and unperturbed H 0 and in a resulting lower-triangular matrix structure of its propagators. Within the framework of the so-called Hill-determinant method, an admissibility of any incompletely solvable zero-order Hamiltonian is achieved in this way. As a consequence, the range of practical applicability of our new perturbative formalism may be expected to incorporate many new phenomenological interactions with a strongly anharmonic character. 18 refs

  3. Triangular clustering in document networks

    International Nuclear Information System (INIS)

    Cheng Xueqi; Ren Fuxin; Zhou Shi; Hu Maobin

    2009-01-01

    Document networks have the characteristic that a document node, e.g. a webpage or an article, carries meaningful content. Properties of document networks are not only affected by topological connectivity between nodes, but are also strongly influenced by the semantic relation between the content of the nodes. We observed that document networks have a large number of triangles and a high value clustering coefficient. Also there is a strong correlation between the probability of formation of a triangle and the content similarity among the three nodes involved. We propose the degree-similarity product (DSP) model, which well reproduces these properties. The model achieves this by using a preferential attachment mechanism that favours the linkage between nodes that are both popular and similar. This work is a step forward towards a better understanding of the structure and evolution of document networks.

  4. Triangular clustering in document networks

    Science.gov (United States)

    Cheng, Xue-Qi; Ren, Fu-Xin; Zhou, Shi; Hu, Mao-Bin

    2009-03-01

    Document networks have the characteristic that a document node, e.g. a webpage or an article, carries meaningful content. Properties of document networks are not only affected by topological connectivity between nodes, but are also strongly influenced by the semantic relation between the content of the nodes. We observed that document networks have a large number of triangles and a high value clustering coefficient. Also there is a strong correlation between the probability of formation of a triangle and the content similarity among the three nodes involved. We propose the degree-similarity product (DSP) model, which well reproduces these properties. The model achieves this by using a preferential attachment mechanism that favours the linkage between nodes that are both popular and similar. This work is a step forward towards a better understanding of the structure and evolution of document networks.

  5. Human resource management in triangular employment relationships

    OpenAIRE

    Fontinha, Ana Rita Ramos

    2013-01-01

    Tese de doutoramento (co-tutela), Psicologia (Psicologia dos Recursos Humanos do Trabalho e das Organizações), Katholieke Universiteit Leuven, Universidade de Lisboa, 2013 This dissertation concerns the triangular employment relationships of agency workers and outsourced workers. In particular, the aim was to investigate the relationship between employees’ perceptions and attributions of human resource management (HRM) practices and their dual affective organisational commitment, i.e., the...

  6. Analysis of moving bottlenecks considering a triangular fundamental diagram

    Directory of Open Access Journals (Sweden)

    Karim Fadhloun

    2016-10-01

    Full Text Available A significant number of research efforts have studied and analyzed the case in which a vehicle is moving slower than the traffic stream. This phenomenon, known as a moving bottleneck, results in a disruption of traffic flow and may significantly impact the traffic stream behavior upstream, downstream and abreast the slow moving vehicle. In this paper, a macroscopic approach for modeling moving bottlenecks is developed using microscopically derived data considering a triangular fundamental diagram. The passing flow rates of different moving bottleneck scenarios are determined using a previously developed microscopic model based on simulated data derived from the INTEGRATION software. Using the simulation results, an explicit expression of the bottleneck diagram, a flow-density relationship that defines the phenomenon macroscopically is proposed and the behavior of the traffic stream downstream and abreast the moving obstruction is depicted. It is demonstrated that the behavior of the traffic stream downstream of the slow vehicle as well as the acceleration behavior while passing is governed by the demand level. Such a result is coherent and consistent, to a significant extent, with two decades of research related to modeling moving bottlenecks and constitutes a potential feasible and more detailed description of the phenomenon in the case of a triangular fundamental diagram. Finally, it is noteworthy that the research subject of this paper could be considered as a first step in developing a numerical and practitioner-friendly framework for the analysis of moving bottlenecks that does not involve approaching the problem from its theoretical perspective.

  7. TEROIDES THE STUDY OF THE EFFECT OF HIGH AND LOW STARTING TITRE IN THE MODEL ENVIRONMENTS TO CHANGES IN ACTIVE AND TITRATABLE ACIDITY DURING THE CULTIVATION OF WHITE CABBAGE VARIETIES PARUS LACTIC ACID BACTERIA L. LACTIS AND L. MESENTEROIDES

    Directory of Open Access Journals (Sweden)

    V. V. Kondratenko

    2017-01-01

    Full Text Available The aim of the research was to study the dynamics of active and titratable acidity with a low and high initial titer, while cultivating white head cabbage of the variety ‘Parus’ with lactic acid bacteria Leuconostoc lactis VKPM V-12150 and Leuconostoc mesenteroides subsp. mesenteroides VKPM V-8818 in the basic model medium (BMS and the modified model medium (MMC during fermentation . In this experiment, two important questions were considered: the creation of favorable conditions for the growth of lactic acid microorganisms and the suppression of undesirable pathogenic microflora, which can eventually lead to product spoilage. One of the key questions is to scale the results of studies related to the fermentation of plant objects by microorganisms on initially non-sterile raw materials that is the requirement to create as possible fast the conditions that restrain the reproduction of Cl. botulinum, preventing toxin accumulation in the product. Therefore, an important factor is the observance for the necessary boundary condition where for international standards, it reaches pH ≤ 4.6, and for Russian standards it reaches pH ≤ 4.2. Hence, an analysis of the experimental data showed that these boundary conditions were reached after the expiration of essentially different time intervals during the cultivation of microorganisms with different starting titers. As a result, it was shown with which lactic acid microorganisms the optimal parameters for the dynamics of active and titratable acidity were obtained, when the boundary condition reached pH 4.2. Since this value determines more "stringent" requirements for product safety. As a result of studies it was found that optimal parameters for the dynamics of active and titratable acidity when a limit pH value of 4.2 is obtained in the cultivation of lactic acid bacteria L. mesenteroides in the MMC, revealing that the value of the starting titer ranging from 3*103 to 3*105 CFU/g.

  8. Colorblindness and Titrations with Visual Indicators.

    Science.gov (United States)

    Diehl, Harvey; And Others

    1985-01-01

    Discusses various issues related to colorblind students performing titrations with visual indicators. Includes tables showing precisions in the titration of a weak acid by colorblind students using phenolphthalein and thymolphthalein and in the titration of a weak base by colorblind persons using methyl red and bromcresol green. (JN)

  9. Flow in a triangular open channel with hydraulic jump | Eyo | Journal ...

    African Journals Online (AJOL)

    Mathematical model for dredging a triangular open channel with hydraulic jump is developed using the method of successive approximation. Applying the model to a numerical example new parameters of the new (excavated) channel are determined and compared with those of the original channel. Another feature of the ...

  10. Automated back titration method to measure phosphate

    International Nuclear Information System (INIS)

    Comer, J.; Tehrani, M.; Avdeef, A.; Ross, J. Jr.

    1987-01-01

    Phosphate was measured in soda drinks and as an additive in flour, by a back titration method in which phosphate was precipitated with lanthanum, and the excess lanthanum was titrated with fluoride. All measurements were performed using the Orion fluoride electrode and the Orion 960 Autochemistry System. In most commercial automatic titrators, the inflection point of the titration curve, calculated from the first derivative of the curve, is used to find the equivalence polar of the titration. The inflection technique is compared with a technique based on Gran functions, which uses data collected after the end point and predicts the equivalence point accordingly

  11. Evaluation of an automatic uranium titration system

    International Nuclear Information System (INIS)

    Lewis, K.

    1980-01-01

    The titration system utilizes the constant current coulometric titration of Goldbeck and Lerner. U(VI) is reduced to U(IV) by Fe(II). V(V) is generated to titrate the U(IV), and the titration is followed potentiometrically. The evaluation shows that the recovery of uranium is 100% at the 40-mg level. The accuracy is generally +-0.10% or better. The smallest sample weight at which reliable results were obtained was 40 mg of uranium. Time for one analysis is 15 minutes. Advantages and disadvantages of the automated titrator are listed

  12. Automatic titrator for high precision plutonium assay

    International Nuclear Information System (INIS)

    Jackson, D.D.; Hollen, R.M.

    1986-01-01

    Highly precise assay of plutonium metal is required for accountability measurements. We have developed an automatic titrator for this determination which eliminates analyst bias and requires much less analyst time. The analyst is only required to enter sample data and start the titration. The automated instrument titrates the sample, locates the end point, and outputs the results as a paper tape printout. Precision of the titration is less than 0.03% relative standard deviation for a single determination at the 250-mg plutonium level. The titration time is less than 5 min

  13. Acid-base properties of humic substances from composted and thermally-dried sewage sludges and amended soils as determined by potentiometric titration and the NICA-Donnan model.

    Science.gov (United States)

    Fernández, José M; Plaza, César; Senesi, Nicola; Polo, Alfredo

    2007-09-01

    The acid-base properties of humic acids (HAs) and fulvic acids (FAs) isolated from composted sewage sludge (CS), thermally-dried sewage sludge (TS), soils amended with either CS or TS at a rate of 80 t ha(-1)y(-1) for 3y and the corresponding unamended soil were investigated by use of potentiometric titrations. The non-ideal competitive adsorption (NICA)-Donnan model for a bimodal distribution of proton binding sites was fitted to titration data by use of a least-squares minimization method. The main fitting parameters of the NICA-Donnan model obtained for each HA and FA sample included site densities, median affinity constants and widths of affinity distributions for proton binding to low and high affinity sites, which were assumed to be, respectively, carboxylic- and phenolic-type groups. With respect to unamended soil HA and FA, the HAs and FAs from CS, and especially TS, were characterized by smaller acidic functional group contents, larger proton binding affinities of both carboxylic- and phenolic-type groups, and smaller heterogeneity of carboxylic and phenolic-type groups. Amendment with CS or TS led to a decrease of acidic functional group contents and a slight increase of proton binding affinities of carboxylic- and phenolic-type groups of soil HAs and FAs. These effects were more evident in the HA and FA fractions from CS-amended soil than in those from TS-amended soil.

  14. An Improved Triangular Element With Drilling Rotations

    DEFF Research Database (Denmark)

    Damkilde, Lars; Grønne, Mikael

    2002-01-01

    A new plane element with rotational degrees in the corner nodes is presented. The element has 12 degrees of freedom and the only difference from the well-known Linear Strain Triangular (LST) element is that the displacements perpendicular to the element sides in the mid-side nodes are replaced...... by rotations in the corner nodes. Compared to Allman's plane element which was the first succesfull implementation of drilling rotations the proposed element has extra displacements in the mid-side nodes parallel to the element sides. The performance should therefore be better and closer to the LST-element...

  15. Magnetic focusing in triangular electron billiards

    DEFF Research Database (Denmark)

    Bøggild, Peter; Kristensen, A.; Lindelof, Poul Erik

    1999-01-01

    focusing spectrum compared to the case of a perpendicular injection angle. From numerical and analytical analysis, we confirm that the quenching is a fundamental geometrical effect, and identify two mechanisms responsible for the anomaly. The focusing spectrum of the considered skewed geometry......The classical ballistic magnetotransport in triangular electron billiards fabricated in a high mobility GaAs heterostructure has been studied at 4.2 K. The sample geometry may be viewed as a double-slit structure with a skewed injection angle. We observe a striking cancellation of the magnetic...

  16. The role of titration schedule of topiramate for the development of depression in patients with epilepsy.

    Science.gov (United States)

    Mula, Marco; Hesdorffer, Dale C; Trimble, Michael; Sander, Josemir W

    2009-05-01

    To determine whether a fast titration schedule of topiramate (TPM) has different effects on the occurrence of depression, in relation to other risk factors for TPM-induced depression, including history of depression (HxDEP), febrile seizures (FS), and hippocampal sclerosis (HS). Using data from a large case registry of patients prescribed TPM, two models were constructed: Model 1 examined the independent effect of rapid TPM titration after separate adjustment for FS, HxDEP, and HS. Model 2 examined effect of the cooccurrence of rapid titration on the development of depression with each of these risk factors. A total of 423 patients were included (51.8% females), mean age (SD) 35.5 (11.8) years, mean duration of epilepsy of 22.2 (11.5) years. Forty-four patients (10.4%) developed depression during TPM therapy. A rapid TPM titration was associated with 5-fold increased risk of depression that increased to 12.7-fold in the presence of both FS and rapid TPM titration, 23.3-fold in the presence of both HxDEP and rapid TPM titration, and 7.6-fold in the presence of both HS and rapid TPM titration schedule. Our study suggests that a rapid titration schedule is associated with an increased risk of developing depression during TPM therapy. HxDEP and FS are major contraindications to the use of a rapid titration, with a 23.3-fold and 12.7 fold increased risk, respectively.

  17. Free Software Development. 3. Numerical Description of Soft Acid with Soft Base Titration

    Directory of Open Access Journals (Sweden)

    Lorentz JÄNTSCHI

    2002-12-01

    Full Text Available The analytical methods of qualitative and quantitative determination of ions in solutions are very flexible to automation. The present work is focus on modeling the process of titration and presents a numerical simulation of acid-base titration. A PHP program to compute all iterations in titration process that solves a 3th rank equation to find value of pH for was built and is available through http internet protocol at the address: http://vl.academicdirect.org/molecular_dynamics/ab_titrations/v1.1/ The method allows expressing the value of pH in any point of titration process and permits to observe the equivalence point of titration.

  18. Use of dermoscopy in the diagnosis of temporal triangular alopecia.

    Science.gov (United States)

    Campos, Jullyene Gomes de; Oliveira, Cláudia Marina Puga Barbosa; Romero, Sandra Adolfina Reyes; Klein, Ana Paula; Akel, Patricia Bandeira de Melo; Pinto, Giselle Martins

    2015-01-01

    Temporal triangular alopecia, also referred as congenital triangular alopecia, is an uncommon dermatosis of unknown etiology. It is characterized by a non-scarring, circumscribed alopecia often located unilaterally in the frontotemporal region. It usually emerges at ages 2-9 years. Alopecia areata is the main differential diagnosis, especially in atypical cases. Dermoscopy is a noninvasive procedure that helps distinguish temporal triangular alopecia from aloepecia areata. Such procedure prevents invasive diagnostic methods as well as ineffective treatments.

  19. Higher-n triangular dilatonic black holes

    Science.gov (United States)

    Zadora, Anton; Gal'tsov, Dmitri V.; Chen, Chiang-Mei

    2018-04-01

    Dilaton gravity with the form fields is known to possess dyon solutions with two horizons for the discrete "triangular" values of the dilaton coupling constant a =√{ n (n + 1) / 2 }. This sequence first obtained numerically and then explained analytically as consequence of the regularity of the dilaton, should have some higher-dimensional and/or group theoretical origin. Meanwhile, this origin was explained earlier only for n = 1 , 2 in which cases the solutions were known analytically. We extend this explanation to n = 3 , 5 presenting analytical triangular solutions for the theory with different dilaton couplings a , b in electric and magnetic sectors in which case the quantization condition reads ab = n (n + 1) / 2. The solutions are derived via the Toda chains for B2 and G2 Lie algebras. They are found in the closed form in general D space-time dimensions. Solutions satisfy the entropy product rules indicating on the microscopic origin of their entropy and have negative binding energy in the extremal case.

  20. Redesigning Triangular Dense Matrix Computations on GPUs

    KAUST Repository

    Charara, Ali

    2016-08-09

    A new implementation of the triangular matrix-matrix multiplication (TRMM) and the triangular solve (TRSM) kernels are described on GPU hardware accelerators. Although part of the Level 3 BLAS family, these highly computationally intensive kernels fail to achieve the percentage of the theoretical peak performance on GPUs that one would expect when running kernels with similar surface-to-volume ratio on hardware accelerators, i.e., the standard matrix-matrix multiplication (GEMM). The authors propose adopting a recursive formulation, which enriches the TRMM and TRSM inner structures with GEMM calls and, therefore, reduces memory traffic while increasing the level of concurrency. The new implementation enables efficient use of the GPU memory hierarchy and mitigates the latency overhead, to run at the speed of the higher cache levels. Performance comparisons show up to eightfold and twofold speedups for large dense matrix sizes, against the existing state-of-the-art TRMM and TRSM implementations from NVIDIA cuBLAS, respectively, across various GPU generations. Once integrated into high-level Cholesky-based dense linear algebra algorithms, the performance impact on the overall applications demonstrates up to fourfold and twofold speedups, against the equivalent native implementations, linked with cuBLAS TRMM and TRSM kernels, respectively. The new TRMM/TRSM kernel implementations are part of the open-source KBLAS software library (http://ecrc.kaust.edu.sa/Pages/Res-kblas.aspx) and are lined up for integration into the NVIDIA cuBLAS library in the upcoming v8.0 release.

  1. The acid-base titration of montmorillonite

    Science.gov (United States)

    Bourg, I. C.; Sposito, G.; Bourg, A. C.

    2003-12-01

    Proton binding to clay minerals plays an important role in the chemical reactivity of soils (e.g., acidification, retention of nutrients or pollutants). If should also affect the performance of clay barriers for waste disposal. The surface acidity of clay minerals is commonly modelled empirically by assuming generic amphoteric surface sites (>SOH) on a flat surface, with fitted site densities and acidity constant. Current advances in experimental methods (notably spectroscopy) are rapidly improving our understanding of the structure and reactivity of the surface of clay minerals (arrangement of the particles, nature of the reactive surface sites, adsorption mechanisms). These developments are motivated by the difficulty of modelling the surface chemistry of mineral surfaces at the macro-scale (e.g., adsorption or titration) without a detailed (molecular-scale) picture of the mechanisms, and should be progressively incorporated into surface complexation models. In this view, we have combined recent estimates of montmorillonite surface properties (surface site density and structure, edge surface area, surface electrostatic potential) with surface site acidities obtained from the titration of alpha-Al2O3 and SiO2, and a novel method of accounting for the unknown initial net proton surface charge of the solid. The model predictions were compared to experimental titrations of SWy-1 montmorillonite and purified MX-80 bentonite in 0.1-0.5 mol/L NaClO4 and 0.005-0.5 mol/L NaNO3 background electrolytes, respectively. Most of the experimental data were appropriately described by the model after we adjusted a single parameter (silanol sites on the surface of montmorillonite were made to be slightly more acidic than those of silica). At low ionic strength and acidic pH the model underestimated the buffering capacity of the montmorillonite, perhaps due to clay swelling or to the interlayer adsorption of dissolved aluminum. The agreement between our model and the experimental

  2. Spin wave analysis to the spatially-anisotropic Heisenberg antiferromagnet on triangular lattice

    OpenAIRE

    Trumper, Adolfo E.

    1998-01-01

    We study the phase diagram at T=0 of the antiferromagnetic Heisenberg model on the triangular lattice with spatially-anisotropic interactions. For values of the anisotropy very close to J_alpha/J_beta=0.50, conventional spin wave theory predicts that quantum fluctuations melt the classical structures, for S=1/2. For the regime J_beta

  3. Limits of commutative triangular systems on locally compact groups

    Indian Academy of Sciences (India)

    Commutative triangular systems of probability measures on locally compact groups have been studied extensively and ... in [S3,S4], we extend our earlier result to some particular triangular systems on algebraic groups. We also discuss ..... Now G can be embedded as a closed subgroup in. G2 ¼ G1=D and G0. 2 ¼ ًG0 آ ...

  4. Magnetic phase diagrams of classical triangular and kagome antiferromagnets

    Energy Technology Data Exchange (ETDEWEB)

    Gvozdikova, M V [Department of Physics, Kharkov National University, 61077 Kharkov (Ukraine); Melchy, P-E; Zhitomirsky, M E, E-mail: mike.zhitomirsky@cea.fr [Service de Physique Statistique, Magnetisme et Supraconductivite, UMR-E9001 CEA-INAC/UJF, 17 rue des Martyrs, 38054 Grenoble (France)

    2011-04-27

    We investigate the effect of geometrical frustration on the H-T phase diagrams of the classical Heisenberg antiferromagnets on triangular and kagome lattices. The phase diagrams for the two models are obtained from large-scale Monte Carlo simulations. For the kagome antiferromagnet, thermal fluctuations are unable to lift degeneracy completely and stabilize translationally disordered multipolar phases. We find a substantial difference in the temperature scales of the order by disorder effect related to different degeneracy of the low- and the high-field classical ground states in the kagome antiferromagnet. In the low-field regime, the Kosterlitz-Thouless transition into a spin-nematic phase is produced by unbinding of half-quantum vortices.

  5. Risks and Benefits of Rapid Clozapine Titration.

    Science.gov (United States)

    Lochhead, Jeannie D; Nelson, Michele A; Schneider, Alan L

    2016-05-18

    Clozapine is often considered the gold standard for the treatment of schizophrenia. Clinical guidelines suggest a gradual titration over 2 weeks to reduce the risks of adverse events such as seizures, hypotension, agranulocytosis, and myocarditis. The slow titration often delays time to therapeutic response. This raises the question of whether, in some patients, it may be safe to use a more rapid clozapine titration. The following case illustrates the potential risks associated with the use of multiple antipsychotics and rapid clozapine titration. We present the case of a young man with schizophrenia who developed life threatening neuroleptic malignant syndrome (NMS) during rapid clozapine titration and treatment with multiple antipsychotics. We were unable to find another case in the literature of NMS associated with rapid clozapine titration. This case is meant to urge clinicians to carefully evaluate the risks and benefits of rapid clozapine titration, and to encourage researchers to further evaluate the safety of rapid clozapine titration. Rapid clozapine titration has implications for decreasing health care costs associated with prolonged hospitalizations, and decreasing the emotional suffering associated with uncontrolled symptoms of psychosis. Clozapine is considered the most effective antipsychotic available thus efforts should focus on developing strategies that would allow for safest and most efficient use of clozapine to encourage its utilization for treatment resistance schizophrenia.

  6. Risks and benefits of rapid clozapine titration

    Directory of Open Access Journals (Sweden)

    Jeannie D. Lochhead

    2016-05-01

    Full Text Available Clozapine is often considered the gold standard for the treatment of schizophrenia. Clinical guidelines suggest a gradual titration over 2 weeks to reduce the risks of adverse events such as seizures, hypotension, agranulocytosis, and myocarditis. The slow titration often delays time to therapeutic response. This raises the question of whether, in some patients, it may be safe to use a more rapid clozapine titration. The following case illustrates the potential risks associated with the use of multiple antipsychotics and rapid clozapine titration. We present the case of a young man with schizophrenia who developed life threatening neuroleptic malignant syndrome (NMS during rapid clozapine titration and treatment with multiple antipsychotics. We were unable to find another case in the literature of NMS associated with rapid clozapine titration. This case is meant to urge clinicians to carefully evaluate the risks and benefits of rapid clozapine titration, and to encourage researchers to further evaluate the safety of rapid clozapine titration. Rapid clozapine titration has implications for decreasing health care costs associated with prolonged hospitalizations, and decreasing the emotional suffering associated with uncontrolled symptoms of psychosis. Clozapine is considered the most effective antipsychotic available thus efforts should focus on developing strategies that would allow for safest and most efficient use of clozapine to encourage its utilization for treatment resistance schizophrenia.

  7. An experimental investigation of head loss through a triangular “V- shaped” screen

    Directory of Open Access Journals (Sweden)

    Mahmoud Zayed

    2018-03-01

    Full Text Available Common traditional screens (screens perpendicular and vertical to the flow direction face extensive problems with screen blockage, which can result in adverse hydraulic, environmental, and economic consequences. Experimentally, this paper presents an advanced trash screen concept to reduce traditional screen problems and improve the hydraulic performance of screens. The traditional screen is re-developed using a triangular V shape with circular bars in the flow direction. Triangular V-shaped screen models with different angles, blockage ratios, circular bar designs, and flow discharges were tested in a scaled physical model. The analyses provide promising results. The findings showed that the head loss coefficients were effectively reduced by using the triangular V-shaped screens with circular bars (α < 90° in comparison with the traditional trash screen (α = 90. Additionally, the results indicated that the head loss across the screen increased with increasing flow discharge and blockage ratio. The losses considerably increase by large percentages when the screen becomes blocked by 40%. Low head losses were recorded at low screen angles for the circular bars. A new head loss equation is recommended for triangular screens with circular bars.

  8. Contributions to the theory of catalytic titrations-III Neutralization catalytic titrations.

    Science.gov (United States)

    Gaál, F F; Abramović, B F

    1985-07-01

    Neutralization catalytic titrations of weak monoprotic adds and bases with both volumetric and coulometric addition of the titrant (strong base/acid) have been simulated by taking into account the equilibrium concentration of the catalyst during the titration. The influence of several factors on the shape of the simulated catalytic titration curve has been investigated and is discussed.

  9. Nap-titration : An effective alternative for continuous positive airway pressure titration

    NARCIS (Netherlands)

    Hoekema, A; Stegenga, B; Meinesz, AF; van der Hoeven, JH; Wijkstra, PJ

    When treating Obstructive Steep Apnea-Hypopnea Syndrome (OSAHS) several alternatives for standard (manual) continuous positive airway pressure (CPAP) titration are feasible. A practical alternative is titration without polysomnography during an afternoon nap (Nap-titration). The aim of the present

  10. Anisotropy modulated stepwise magnetization in triangular Heisenberg antiferromagnet

    International Nuclear Information System (INIS)

    Yao Xiaoyan; Liu Junming; Lo, Veng Cheong

    2011-01-01

    During the course of tuning anisotropy from Ising type to zero, the variation of magnetization (M) steps against magnetic field (h) is investigated in a triangular antiferromagnetic Heisenberg model using Monte Carlo techniques. It is revealed that the anisotropy is an essential key to induce the temperature-dependent stepwise M(h) curve observed in frustrated magnetic system, and it can be employed to modulate this steplike magnetic behavior effectively. When the anisotropy is strengthened, a ground state transition occurs from the homogeneous 120 o triangular structure to the collinear partially disordered antiferromagnetic state. No M step is detected in the system without anisotropy. But if the anisotropy is nonzero, the M 0 /3 step (where M 0 is the saturated M) will emerge on M(h) curve, which is due to an h-induced quasi-collinear ferrimagnetic state. This M 0 /3 step can be extended by increasing the anisotropy. When the M 0 /3 plateau dominates the h-range broad enough, the equidistant metastable substeps, which originates from the disorders frozen in the frustrated collinear spin structure, appear to be superposed on the M 0 /3 plateau. Thus the system with a strong anisotropy presents the whole temperature evolution of stepwise M(h) curve in quantitative agreement with the experiments of Ca 3 Co 2 O 6 . - Highlights: → Variation of M steps is investigated by tuning anisotropy from Ising type to zero. → Anisotropy is essential to induce T-dependent multistep M against magnetic field. → Simulation with strong anisotropy reproduces T-evolution of M steps in Ca 3 Co 2 O 6 . → Metastable substeps at low T can be enhanced by increasing anisotropy.

  11. Coupling effect of topological states and Chern insulators in two-dimensional triangular lattices

    Science.gov (United States)

    Zhang, Jiayong; Zhao, Bao; Xue, Yang; Zhou, Tong; Yang, Zhongqin

    2018-03-01

    We investigate topological states of two-dimensional (2D) triangular lattices with multiorbitals. Tight-binding model calculations of a 2D triangular lattice based on px and py orbitals exhibit very interesting doubly degenerate energy points at different positions (Γ and K /K' ) in momentum space, with quadratic non-Dirac and linear Dirac band dispersions, respectively. Counterintuitively, the system shows a global topologically trivial rather than nontrivial state with consideration of spin-orbit coupling due to the "destructive interference effect" between the topological states at the Γ and K /K' points. The topologically nontrivial state can emerge by introducing another set of triangular lattices to the system (bitriangular lattices) due to the breakdown of the interference effect. With first-principles calculations, we predict an intrinsic Chern insulating behavior (quantum anomalous Hall effect) in a family of the 2D triangular lattice metal-organic framework of Co(C21N3H15) (TPyB-Co) from this scheme. Our results provide a different path and theoretical guidance for the search for and design of new 2D topological quantum materials.

  12. A Tabular Approach to Titration Calculations

    Science.gov (United States)

    Lim, Kieran F.

    2012-01-01

    Titrations are common laboratory exercises in high school and university chemistry courses, because they are easy, relatively inexpensive, and they illustrate a number of fundamental chemical principles. While students have little difficulty with calculations involving a single titration step, there is a significant leap in conceptual difficulty…

  13. RAPID COMMUNICATION: Conducting triangular chambers for EMC measurements

    Science.gov (United States)

    Huang, Yi

    1999-03-01

    Conducting rectangular chambers have been used extensively for electromagnetic compatibility (EMC) shielding and measurement applications. In this communication, conducting triangular chambers are investigated as an alternative structure for rectangular EMC reverberation chambers, which are becoming an increasingly important and powerful tool for both radiated immunity and emission tests. A prime consideration of designing such a system is the total possible number of modes inside the chamber. A new approach is introduced to obtain this parameter for three different triangular chambers. The initial study has demonstrated that triangular chambers may offer better performance in some cases than their rectangular counterparts.

  14. A New Triangular Flat Shell Element With Drilling Rotations

    DEFF Research Database (Denmark)

    Damkilde, Lars

    2008-01-01

    A new flat triangular shell element has been developed based on a newly developed triangular plate bending element by the author and a new triangular membrane element with drilling degrees of freedom. The advantage of the drilling degree of freedom is that no special precautions have to be made...... in connecting with assembly of elements. Due to the drilling rotations all nodal degrees of freedom have stiffness, and therefore no artificial suppression of degrees of freedom are needed for flat or almost flat parts of the shell structure....

  15. Logical, algebraic, analytic and probabilistic aspects of triangular norms

    CERN Document Server

    Klement, Erich Peter

    2005-01-01

    This volume gives a state of the art of triangular norms which can be used for the generalization of several mathematical concepts, such as conjunction, metric, measure, etc. 16 chapters written by leading experts provide a state of the art overview of theory and applications of triangular norms and related operators in fuzzy logic, measure theory, probability theory, and probabilistic metric spaces.Key Features:- Complete state of the art of the importance of triangular norms in various mathematical fields- 16 self-contained chapters with extensive bibliographies cover both the theoretical ba

  16. On certain topological indices of boron triangular nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Aslam, Adnan [Univ. of Engineering and Technology, Lahore (Pakistan). Dept. of Natural Sciences and Humanities; Ahmad, Safyan [GC Univ. Lahore (Pakistan). Abdus Salam School of Mathematical Sciences; Gao, Wei [Yunnan Normal Univ., Kunming (China). School of Information Science and Technology

    2017-11-01

    The topological index gives information about the whole structure of a chemical graph, especially degree-based topological indices that are very useful. Boron triangular nanotubes are now replacing usual carbon nanotubes due to their excellent properties. We have computed general Randic (R{sub a}), first Zagreb (M{sub 1}) and second Zagreb (M{sub 2}), atom-bond connectivity (ABC), and geometric-arithmetic (GA) indices of boron triangular nanotubes. Also, we have computed the fourth version of atom-bond connectivity (ABC{sub 4}) and the fifth version of geometric-arithmetic (GA{sub 5}) indices of boron triangular nanotubes.

  17. Triangular Quantum Loop Topography for Machine Learning

    Science.gov (United States)

    Zhang, Yi; Kim, Eun-Ah

    Despite rapidly growing interest in harnessing machine learning in the study of quantum many-body systems there has been little success in training neural networks to identify topological phases. The key challenge is in efficiently extracting essential information from the many-body Hamiltonian or wave function and turning the information into an image that can be fed into a neural network. When targeting topological phases, this task becomes particularly challenging as topological phases are defined in terms of non-local properties. Here we introduce triangular quantum loop (TQL) topography: a procedure of constructing a multi-dimensional image from the ''sample'' Hamiltonian or wave function using two-point functions that form triangles. Feeding the TQL topography to a fully-connected neural network with a single hidden layer, we demonstrate that the architecture can be effectively trained to distinguish Chern insulator and fractional Chern insulator from trivial insulators with high fidelity. Given the versatility of the TQL topography procedure that can handle different lattice geometries, disorder, interaction and even degeneracy our work paves the route towards powerful applications of machine learning in the study of topological quantum matters.

  18. Electro-osmotic flows inside triangular microchannels

    International Nuclear Information System (INIS)

    Vocale, P; Spiga, M; Geri, M; Morini, G L

    2014-01-01

    This work presents a numerical investigation of both pure electro-osmotic and combined electro-osmotic/pressure-driven flows inside triangular microchannels. A finite element analysis has been adopted to solve the governing equations for the electric potential and the velocity field, accounting for a finite thickness of the electric double layer. The influence of non-dimensional parameters such as the aspect ratio of the cross-section, the electrokinetic diameter and the ratio of the pressure force to the electric force on the flow behavior has been investigated. Numerical results point out that the velocity field is significantly influenced by the aspect ratio of the cross section and the electrokinetic diameter. More specifically, the aspect ratio plays an important role in determining the maximum volumetric flow rate, while the electrokinetic diameter is crucial to establishing the range of pressures that may be sustained by the electro-osmotic flow. Numerical results are also compared with two correlations available in the literature which enable to assess the volumetric flow rate and the pressure head for microchannels featuring a rectangular, a trapezoidal or an elliptical cross-section.

  19. Potentiometric Titration Method for Quantitative Determination of Hydrogen Peroxide

    National Research Council Canada - National Science Library

    Bessette, Russell R

    2005-01-01

    An electrochemical potentiometric titration method that entails titration of a known volume of a catholyte containing an unknown amount of hydrogen peroxide in a titration cell having two electrodes...

  20. An experimental study on coolability of a particulate bed with radial stratification or triangular shape

    International Nuclear Information System (INIS)

    Thakre, Sachin; Li, Liangxing; Ma, Weimin

    2014-01-01

    Highlights: • Dryout heat flux of a particulate bed with radial stratification is obtained. • It was found to be dominated by hydrodynamics in the bigger size of particle layer. • Coolability of a particulate bed with triangular shape is investigated. • The coolability is improved in the triangular bed due to lateral ingression of coolant. • Coolability of both beds is enhanced by a downcomer. - Abstract: This paper deals with the results of an experimental study on the coolability of particulate beds with radial stratification and triangular shape, respectively. The study is intended to get an idea on how the coolability is affected by the different features of a debris bed formed in a severe accident of light water reactors. The experiments were performed on the POMECO-HT facility which was constructed to investigate two-phase flow and heat transfer in particulate beds under either top-flooding or bottom-fed condition. A downcomer is designed to enable investigation of the effectiveness of natural circulation driven coolability. Two homogenous beds were also employed in the present study to compare their dryout power densities with those of the radially stratified bed and the triangular bed. The results show that the dryout heat fluxes of the homogeneous beds at top-flooding condition can be predicted by the Reed model. For the radially stratified bed, the dryout heat flux is dominated by two-phase flow in the columns packed with larger particles, and the dryout occurred initially near the boundary between the middle column and a side column. Given the same volume of particles under top-flooding condition, the dryout power density of the triangular bed is about 69% higher than that of the homogenous bed. The coolability of all the beds is enhanced by bottom-fed coolant driven by either forced injection or downcomer-induced natural circulation

  1. Phase diagram of the triangular-lattice Potts antiferromagnet

    Science.gov (United States)

    Lykke Jacobsen, Jesper; Salas, Jesús; Scullard, Christian R.

    2017-08-01

    We study the phase diagram of the triangular-lattice Q-state Potts model in the real (Q, v) -plane, where v=e^J-1 is the temperature variable. Our first goal is to provide an obviously missing feature of this diagram: the position of the antiferromagnetic critical curve. This curve turns out to possess a bifurcation point with two branches emerging from it, entailing important consequences for the global phase diagram. We have obtained accurate numerical estimates for the position of this curve by combining the transfer-matrix approach for strip graphs with toroidal boundary conditions and the recent method of critical polynomials. The second goal of this work is to study the corresponding Ap-1 RSOS model on the torus, for integer p=4, 5, \\ldots, 8 . We clarify its relation to the corresponding Potts model, in particular concerning the role of boundary conditions. For certain values of p, we identify several new critical points and regimes for the RSOS model and we initiate the study of the flows between the corresponding field theories.

  2. Low-cost Triangular Lattice Towers for Small Wind Turbines

    Science.gov (United States)

    Adhikari, Ram Chandra

    This thesis focuses on the study of low-cost steel and bamboo triangular lattice towers for small wind turbines. The core objective is to determine the material properties of bamboo and assess the feasibility of bamboo towers. Using the experimentally determined buckling resistance, elastic modulus, and Poisson's ratio, a 12 m high triangular lattice tower for a 500W wind turbine has been modeled as a tripod to formulate the analytical solutions for the stresses and tower deflections, which enables design of the tower based on buckling strength of tower legs. The tripod formulation combines the imposed loads, the base distance between the legs and tower height, and cross-sectional dimensions of the tower legs. The tripod model was used as a reference for the initial design of the bamboo tower and extended to finite element analysis. A 12 m high steel lattice tower was also designed for the same turbine to serve as a comparison to the bamboo tower. The primary result of this work indicates that bamboo is a valid structural material. The commercial software package ANSYS APDL was used to carry out the tower analysis, evaluate the validity of the tripod model, and extend the analysis for the tower design. For this purpose, a 12 m high steel lattice tower for a 500 W wind turbine was examined. Comparison of finite element analysis and analytical solution has shown that tripod model can be accurately used in the design of lattice towers. The tower designs were based on the loads and safety requirements of international standard for small wind turbine safety, IEC 61400-2. For connecting the bamboo sections in the lattice tower, a steel-bamboo adhesive joint combined with conventional lashing has been proposed. Also, considering the low durability of bamboo, periodic replacement of tower members has been proposed. The result of this study has established that bamboo could be used to construct cost-effective and lightweight lattice towers for wind turbines of 500 Watt

  3. 75 FR 41141 - Proposed Information Collection; Comment Request; Triangular Transactions

    Science.gov (United States)

    2010-07-15

    ... the U.S. as approved on an International Import Certificate. A triangular symbol is stamped on import... techniques or other forms of information technology. Comments submitted in response to this notice will be...

  4. Modulation transfer function of a triangular pixel array detector.

    Science.gov (United States)

    Karimzadeh, Ayatollah

    2014-07-01

    The modulation transfer function (MTF) is the main parameter that is used to evaluate image quality in electro-optical systems. Detector sampling MTF in most electro-optical systems determines the cutoff frequency of the system. The MTF of the detector depends on its pixel shape. In this work, we calculated the MTF of a detector with an equilateral triangular pixel shape. Some new results were found in deriving the MTF for the equilateral triangular pixel shape.

  5. Non-aqueous titration of hydroxamic acids.

    Science.gov (United States)

    Stamey, T W; Christian, R

    1966-01-01

    Benzohydroxamic acid is titrated with 0.1M tetrabutyl-anunonium hydroxide in nine non-aqueous solvents with three different indicating electrodes. The best results are obtained using dimethylformamide as solvent and platinum-platinum electrodes. Four monoprotic and three diprotic hydroxamie acids and iron(III) benzohydroxamate have been successfully titrated with this system. The effect of quantitative additions of carbon dioxide to the titrant on its apparent molarity are found to be dependent on the amount added, the strength and sample size of acid titrated and the solvent used.

  6. Kinetics of bacterial potentiometric titrations : the effect of equilibration time on buffering capacity of Pantoea agglomerans suspensions

    OpenAIRE

    Kapetas, Leon; Ngwenya, Bryne T.; MacDonald, Alan M.; Elphick, Stephen C.

    2011-01-01

    Several recent studies have made use of continuous acid–base titration data to describe the surface chemistry of bacterial cells as a basis for accurately modelling metal adsorption to bacteria and other biomaterials of potential industrial importance. These studies do not share a common protocol; rather they titrate in different pH ranges and they use different stability criteria to define equilibration time during titration. In the present study we investigate the kinetics of bacterial titr...

  7. On the Eigenvalues and Eigenvectors of Block Triangular Preconditioned Block Matrices

    KAUST Repository

    Pestana, Jennifer

    2014-01-01

    Block lower triangular matrices and block upper triangular matrices are popular preconditioners for 2×2 block matrices. In this note we show that a block lower triangular preconditioner gives the same spectrum as a block upper triangular preconditioner and that the eigenvectors of the two preconditioned matrices are related. © 2014 Society for Industrial and Applied Mathematics.

  8. Complexometric titration of lanthanides and yttrium

    International Nuclear Information System (INIS)

    Ionashiro, M.; Graner, C.A.F.; Zuanon Netto, J.

    1983-01-01

    The pH variation of the solution and the ammonium acetate buffering were studied when different quantities of lanthanides and yttrium were titrated with EDTA, and xylenol orange as indicator. (Author) [pt

  9. Free Software Development. 3. Numerical Description of Soft Acid with Soft Base Titration

    OpenAIRE

    Lorentz JÄNTSCHI; Horea Iustin NAŞCU

    2002-01-01

    The analytical methods of qualitative and quantitative determination of ions in solutions are very flexible to automation. The present work is focus on modeling the process of titration and presents a numerical simulation of acid-base titration. A PHP program to compute all iterations in titration process that solves a 3th rank equation to find value of pH for was built and is available through http internet protocol at the address: http://vl.academicdirect.org/molecular_dynamics/ab_titra...

  10. Titration and hysteresis in epigenetic chromatin silencing

    Science.gov (United States)

    Dayarian, Adel; Sengupta, Anirvan M.

    2013-06-01

    Epigenetic mechanisms of silencing via heritable chromatin modifications play a major role in gene regulation and cell fate specification. We consider a model of epigenetic chromatin silencing in budding yeast and study the bifurcation diagram and characterize the bistable and the monostable regimes. The main focus of this paper is to examine how the perturbations altering the activity of histone modifying enzymes affect the epigenetic states. We analyze the implications of having the total number of silencing proteins, given by the sum of proteins bound to the nucleosomes and the ones available in the ambient, to be constant. This constraint couples different regions of chromatin through the shared reservoir of ambient silencing proteins. We show that the response of the system to perturbations depends dramatically on the titration effect caused by the above constraint. In particular, for a certain range of overall abundance of silencing proteins, the hysteresis loop changes qualitatively with certain jump replaced by continuous merger of different states. In addition, we find a nonmonotonic dependence of gene expression on the rate of histone deacetylation activity of Sir2. We discuss how these qualitative predictions of our model could be compared with experimental studies of the yeast system under anti-silencing drugs.

  11. Titration and hysteresis in epigenetic chromatin silencing

    International Nuclear Information System (INIS)

    Dayarian, Adel; Sengupta, Anirvan M

    2013-01-01

    Epigenetic mechanisms of silencing via heritable chromatin modifications play a major role in gene regulation and cell fate specification. We consider a model of epigenetic chromatin silencing in budding yeast and study the bifurcation diagram and characterize the bistable and the monostable regimes. The main focus of this paper is to examine how the perturbations altering the activity of histone modifying enzymes affect the epigenetic states. We analyze the implications of having the total number of silencing proteins, given by the sum of proteins bound to the nucleosomes and the ones available in the ambient, to be constant. This constraint couples different regions of chromatin through the shared reservoir of ambient silencing proteins. We show that the response of the system to perturbations depends dramatically on the titration effect caused by the above constraint. In particular, for a certain range of overall abundance of silencing proteins, the hysteresis loop changes qualitatively with certain jump replaced by continuous merger of different states. In addition, we find a nonmonotonic dependence of gene expression on the rate of histone deacetylation activity of Sir2. We discuss how these qualitative predictions of our model could be compared with experimental studies of the yeast system under anti-silencing drugs. (paper)

  12. Theory of titration curves-VII The properties of derivative titration curves for strong acid-strong base and other isovalent ion-combination titrations.

    Science.gov (United States)

    Meites, T; Meites, L

    1970-06-01

    This paper deals with isovalent ion-combination titrations based on reactions that can be represented by the equation M(n+) + X(n-) --> MX, where the activity of the product MX is invariant throughout a titration, and with the derivative titration curves obtained by plotting d[M(+)]/dfversus f for such titrations. It describes some of the ways in which such curves can be obtained; it compares and contrasts them both with potentiometric titration curves, which resemble them in shape, and with segmented titration curves, from which they are derived; and it discusses their properties in detail.

  13. Benefit of slow titration of paroxetine to treat depression in the elderly.

    Science.gov (United States)

    Olgiati, Paolo; Bajo, Emanuele; Serretti, Alessandro

    2014-11-01

    Paroxetine is commonly used to treat depression in the elderly; however, titration issues have been raised. Rapid titration may lead to increased anxiety and early dropout. The aim of this cost-utility analysis was to compare the potential benefit of standard (10 mg the first day) versus slow titration (2.5 mg gradually increased). Clinical analysis was based on a naturalistic trial integrated with a decision-analytic model representing second treatments for those who initially did not respond and for dropout cases. Treatment setting was a public outpatient center for mental disorders in Italy. Service use data were estimated from best practice guidelines, whereas costs (Euros; 2012) were retrieved from Italian official sources. Slow titration approach produced 0.031 more quality-adjusted life years (remission rate: 57% vs 44% in standard titration group) at an incremental cost of €5.53 (generic paroxetine) and €54.54 (brand paroxetine syrup). Incremental cost-effectiveness ratio (ICER) values were €159 and €1768, respectively, in favor of slow titration approach. Cost-effectiveness threshold, defined as ICER titration of paroxetine in older depressed patients. However, these findings, in part based on simulated data, need to be replicated in clinical trials. Copyright © 2014 John Wiley & Sons, Ltd.

  14. Low-frequency photonic band structures in graphene-like triangular metallic lattice

    Science.gov (United States)

    Wang, Kang

    2016-11-01

    We study the low frequency photonic band structures in triangular metallic lattice, displaying Dirac points in the frequency spectrum, and constructed upon the lowest order regular polygonal tiles. We show that, in spite of the unfavourable geometrical conditions intrinsic to the structure symmetry, the lowest frequency photonic bands are formed by resonance modes sustained by local structure patterns, with the corresponding electric fields following a triangular distribution at low structure filling rate and a honeycomb distribution at high filling rate. For both cases, the lowest photonic bands, and thus the plasma gap, can be described in the framework of a tight binding model, and analysed in terms of local resonance modes and their mutual correlations. At high filling rate, the Dirac points and their movement following the structure deformation are described in the same framework, in relation with local structure patterns and their variations, as well as the particularity of the metallic lattice that enhances the topological anisotropy.

  15. Plutonium titration by controlled potential coulometry

    International Nuclear Information System (INIS)

    Leguay, N.

    2011-01-01

    The LAMMAN (Nuclear Materials Metrology Laboratory) is the support laboratory of the CETAMA (Analytical Method Committee), whose two main activities are developing analytic methods, and making and characterizing reference materials. The LAMMAN chose to develop the controlled potential coulometry because it is a very accurate analytical technique which allows the connection between the quantity of element electrolysed to the quantity of electricity measured thanks to the Faraday's law: it does not require the use of a chemical standard. This method was first used for the plutonium titration and was developed in the Materials Analysis and Metrology Laboratory (LAMM), for upgrading its performances and developing it to the titration of other actinides. The equipment and the material used were developed to allow the work in confined atmosphere (in a glove box), with all the restrictions involved. Plutonium standard solutions are used to qualify the method, and in particular to do titrations with an uncertainty better than 0.1 %. The present study allowed making a bibliographic research about controlled potential coulometry applied to the actinides (plutonium, uranium, neptunium, americium and curium). A full procedure was written to set all the steps of plutonium titration, from the preparation of samples to equipments storage. A method validation was done to check the full procedure, and the experimental conditions: working range, uncertainty, performance... Coulometric titration of the plutonium from pure solution (without interfering elements) was developed to the coulometric titration of the plutonium in presence of uranium, which allows to do accurate analyses for the analyses of some parts of the reprocessing of the spent nuclear fuel. The possibility of developing this method to other actinides than plutonium was highlighted thanks to voltammetric studies, like the coulometric titration of uranium with a working carbon electrode in sulphuric medium. (author)

  16. End-point construction and systematic titration error in linear titration curves-complexation reactions

    NARCIS (Netherlands)

    Coenegracht, P.M.J.; Duisenberg, A.J.M.

    The systematic titration error which is introduced by the intersection of tangents to hyperbolic titration curves is discussed. The effects of the apparent (conditional) formation constant, of the concentration of the unknown component and of the ranges used for the end-point construction are

  17. Potentiometric titration of zinc and cadmium in electrolytes of in galvanic baths

    International Nuclear Information System (INIS)

    Kosyuga, E.A.; Kalugin, A.A.; Gur'ev, I.A.

    1979-01-01

    The method of potentiometric titration of zinc and cadmium by complexone 3 in electrolytes of galvanic baths using sulphide - silver electrode for determining the finite point of titration is suggested. Copper (2) ions are proposed as indicator ions. The potentiometric determination should be performed at pH=10. The method is verified on model electrolyte solutions and on the electrolyte solutions of operating baths.The technique can be used for automatic control. The time for analysis is 10 minutes

  18. Elementary dispersion analysis of some mimetic discretizations on triangular C-grids

    Energy Technology Data Exchange (ETDEWEB)

    Korn, P., E-mail: peter.korn@mpimet.mpg.de [Max Planck Institute for Meteorology, Hamburg (Germany); Danilov, S. [Alfred Wegener Institute for Polar and Marine Research, Bremerhaven (Germany); A.M. Obukhov Institute of Atmospheric Physics, Moscow (Russian Federation)

    2017-02-01

    Spurious modes supported by triangular C-grids limit their application for modeling large-scale atmospheric and oceanic flows. Their behavior can be modified within a mimetic approach that generalizes the scalar product underlying the triangular C-grid discretization. The mimetic approach provides a discrete continuity equation which operates on an averaged combination of normal edge velocities instead of normal edge velocities proper. An elementary analysis of the wave dispersion of the new discretization for Poincaré, Rossby and Kelvin waves shows that, although spurious Poincaré modes are preserved, their frequency tends to zero in the limit of small wavenumbers, which removes the divergence noise in this limit. However, the frequencies of spurious and physical modes become close on shorter scales indicating that spurious modes can be excited unless high-frequency short-scale motions are effectively filtered in numerical codes. We argue that filtering by viscous dissipation is more efficient in the mimetic approach than in the standard C-grid discretization. Lumping of mass matrices appearing with the velocity time derivative in the mimetic discretization only slightly reduces the accuracy of the wave dispersion and can be used in practice. Thus, the mimetic approach cures some difficulties of the traditional triangular C-grid discretization but may still need appropriately tuned viscosity to filter small scales and high frequencies in solutions of full primitive equations when these are excited by nonlinear dynamics.

  19. From the triangular to the kagome lattice: Following the footprints of the ordered state

    Science.gov (United States)

    Arrachea, Liliana; Capriotti, Luca; Sorella, Sandro

    2004-06-01

    We study the spin- 1/2 Heisenberg model in a lattice that interpolates between the triangular and the kagome lattices. The exchange interaction along the bonds of the kagome lattice is J , and the one along the bonds connecting kagome and nonkagome sites is J' , so that J' =J corresponds to the triangular limit and J' =0 to the kagome one. We use variational and exact diagonalization techniques. We analyze the behavior of the order parameter for the antiferromagnetic phase of the triangular lattice, the spin gap, and the structure of the spin excitations as functions of J' /J . Our results indicate that the antiferromagnetic order is not affected by the reduction of J' down to J' /J≃0.2 . Below this value, antiferromagnetic correlations grow weaker, a description of the ground state in terms of a Néel phase renormalized by quantum fluctuations becomes inadequate, and the finite-size spectra develop features that are not compatible with antiferromagnetic ordering. However, this phase does not appear to be connected to the kagome phase as well, as the low-energy spectra do not evolve with continuity for J' →0 to the kagome limit. In particular, for any nonzero value of J' , the latter interaction sets the energy scale for the low-lying spin excitations, and a gapless triplet spectrum, destabilizing the kagome phase, is expected.

  20. An accurate potentiometric titration of 5-25 mg uranium

    International Nuclear Information System (INIS)

    Slanina, J.; Bakker, F.; Lingerak, W.A.

    1976-01-01

    A potentiometric titration of 5 to 25 mg uranium is described. Sulphamic and phosphoric acid are added to the sample (volume 1 ml), U VI is reduced to U IV by Fe 2+ and the excess of Fe 2+ is oxidized by a mixture of nitric acid, sulphamic acid and ammonium molybdate; vanadyl sulphate is added to ensure a sharp end-point of the titration. The resultant U IV is titrated automatically with 0.02500N potassiumdichromate using a platinum indicator electrode. The automatic titration is performed both with a commercial titrator (Mettler) and with an R.C.N. titrator which waits after each addition until the equilibrium is reached. Using the Mettler titrator an accuracy of 0.05% relative was reached. The R.C.N. setpoint titrator gave results with an accuracy of 0.04% relative at the 20-mg U level. Each titration takes 5 to 7 min. (author)

  1. Cost efficiency with triangular fuzzy number input prices: An application of DEA

    International Nuclear Information System (INIS)

    Bagherzadeh Valami, H.

    2009-01-01

    The cost efficiency model (CE) has been considered by researchers as a Data Envelopment Analysis (DEA) model for evaluating the efficiency of DMUs. In this model, the possibility of producing the outputs of a target DMU is evaluated by the input prices of the DMU. This provides a criterion for evaluating the CE of DMUs. The main contribution of this paper is to provide an approach for generalizing the CE of DMUs when their input prices are triangular fuzzy numbers, where preliminary concepts of fuzzy theory and CE, are directly used.

  2. TINITALY/01: a new Triangular Irregular Network of Italy

    Directory of Open Access Journals (Sweden)

    M. T. Pareschi

    2007-06-01

    Full Text Available A new Digital Elevation Model (DEM of the natural landforms of Italy is presented. A methodology is discussed to build a DEM over wide areas where elevation data from non-homogeneous (in density and accuracy input sources are available. The input elevation data include contour lines and spot heights derived from the Italian Regional topographic maps, satellite-based global positioning system points, ground based and radar altimetry data. Owing to the great heterogeneity of the input data density, the DEM format that better preserves the original accuracy is a Triangular Irregular Network (TIN. A Delaunay-based TIN structure is improved by using the DEST algorithm that enhances input data by evaluating inferred break-lines. Accordingly to this approach, biased distributions in slopes and elevations are absent. To prevent discontinuities at the boundary between regions characterized by data with different resolution a cubic Hermite blending weight S-shaped function is adopted. The TIN of Italy consists of 1.39×109 triangles. The average triangle area ranges from 12 to about 13000 m2 accordingly to different morphologies and different sources. About 50% of the model has a local average triangle area <500 m2. The vertical accuracy of the obtained DEM is evaluated by more than 200000 sparse control points. The overall Root Mean Square Error (RMSE is less than 3.5 m. The obtained national-scale DEM constitutes an useful support to carry out accurate geomorphological and geological investigations over large areas. The problem of choosing the best step size in deriving a grid from a TIN is then discussed and a method to quantify the loss of vertical information is presented as a function of the grid step. Some examples of DEM application are outlined. Under request, an high resolution stereo image database of the whole Italian territory (derived from the presented DEM is available to browse via internet.

  3. Determination of oxygen nonstoichiometry and diffusivity in mixed conducting oxides by oxygen Coulometric titration. II. Oxygen nonstoichiometry and defect model for La0.8Sr0.2CoO3-d

    NARCIS (Netherlands)

    Lankhorst, M.H.R.; Lankhorst, M.H.R.; Bouwmeester, Henricus J.M.

    1997-01-01

    The oxygen nonstoichiometry of La0.8Sr0.2CoO3-delta has been determined as a function of oxygen partial pressure and temperature using a high-temperature coulometric titration cell. For each measured value of the oxygen chemical potential, the oxygen nonstoichiometry is found to be nearly

  4. Total ear reconstruction: The role of bilateral triangular post ...

    African Journals Online (AJOL)

    Saad Mohamed Saad Ibrahiem

    2016-03-16

    Mar 16, 2016 ... at the desired angle by means of a block of cartilage covered with a fascial flap. Then, two local triangular flaps from the adjacent non-hairy skin are created (one is superiorly based and the other is inferiorly based) and inset into the created cephaloauricular sulcus. The rest of the post-auricular defect is ...

  5. Zero-reconstructible Triangular Norms as Universal Approximators

    Czech Academy of Sciences Publication Activity Database

    Petrík, Milan; Sarkoci, P.

    2010-01-01

    Roč. 20, č. 1 (2010), s. 63-67 ISSN 1210-0552 R&D Projects: GA ČR GD401/09/H007 Institutional research plan: CEZ:AV0Z10300504 Keywords : zero-reconstructible strict triangular norm * approximation * multiplicative generator * reconstruction Subject RIV: BA - General Mathematics Impact factor: 0.511, year: 2010

  6. Aranha: a 2D mesh generator for triangular finite elements

    International Nuclear Information System (INIS)

    Fancello, E.A.; Salgado, A.C.; Feijoo, R.A.

    1990-01-01

    A method for generating unstructured meshes for linear and quadratic triangular finite elements is described in this paper. Some topics on the C language data structure used in the development of the program Aranha are also presented. The applicability for adaptive remeshing is shown and finally several examples are included to illustrate the performance of the method in irregular connected planar domains. (author)

  7. The computation of linear triangular matrices in the finite element ...

    African Journals Online (AJOL)

    An algorithm is developed for generating the system matrices for the Finite Element Method of solving some classes of second order partial differential equations problems using the linear triangular elements. This algorithm reduces the complexity normally associated with the finite element approximation and makes the ...

  8. Triangular Numbers, Gaussian Integers, and KenKen

    Science.gov (United States)

    Watkins, John J.

    2012-01-01

    Latin squares form the basis for the recreational puzzles sudoku and KenKen. In this article we show how useful several ideas from number theory are in solving a KenKen puzzle. For example, the simple notion of triangular number is surprisingly effective. We also introduce a variation of KenKen that uses the Gaussian integers in order to…

  9. Bistable Chimera Attractors on a Triangular Network of Oscillator Populations

    DEFF Research Database (Denmark)

    Martens, Erik Andreas

    2010-01-01

    We study a triangular network of three populations of coupled phase oscillators with identical frequencies. The populations interact nonlocally, in the sense that all oscillators are coupled to one another, but more weakly to those in neighboring populations than to those in their own population....

  10. Behaviour of Lagrangian triangular mixed fluid finite elements

    Indian Academy of Sciences (India)

    The behaviour of mixed fluid finite elements, formulated based on the Lagrangian frame of reference, is investigated to understand the effects of locking due to incompressibility and irrotational constraints. For this purpose, both linear and quadratic mixed triangular fluid elements are formulated. It is found that there exists a ...

  11. Stability of Triangular Equilibrium Points in the Photogravitational ...

    Indian Academy of Sciences (India)

    2016-01-27

    Jan 27, 2016 ... We have examined the effects of oblateness up to 4 of the less massive primary and gravitational potential from a circum-binary belt on the linear stability of triangular equilibrium points in the circular restricted three-body problem, when the more massive primary emits electromagnetic radiation impinging ...

  12. Euler y la Conjetura de Fermat sobre Números Triangulares

    Directory of Open Access Journals (Sweden)

    José Manuel Sánchez Muñoz

    2011-04-01

    Full Text Available Este artículo describe la historia de como Euler demostró la existencia de infinitos números triangulares bicuadráticos, desde su correspondencia con su amigo Christian Goldbach hasta la publicación de sus resultados en la Academia de San Petesburgo.

  13. Anisotropic Adhesion Properties of Triangular-Tip-Shaped Micropillars

    KAUST Repository

    Kwak, Moon Kyu

    2011-06-01

    Directional dry adhesive microstructures consisting of high-density triangular-tip-shaped micropillars are described. The wide-tip structures allow for unique directional shear adhesion properties with respect to the peeling direction, along with relatively high normal adhesion. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  14. Codes related to line graphs of triangular graphs and permutation ...

    African Journals Online (AJOL)

    For any prime p, we consider p-ary linear codes obtained from the row span of incidence matrices of line graphs of triangular graphs and adjacency matrices of their line graphs. We determine parameters of the codes, their automorphism groups and exhibit permutation decoding sets (PD-sets) for partial permutation ...

  15. Dominance on Strict Triangular Norms and Mulholland Inequality

    Czech Academy of Sciences Publication Activity Database

    Petrík, Milan

    2018-01-01

    Roč. 335, 15 March (2018), s. 3-17 ISSN 0165-0114 R&D Projects: GA ČR GJ15-07724Y Institutional support: RVO:67985807 Keywords : dominance relation * Mulholland inequality * strict triangular norm * transitivity Subject RIV: BA - General Mathematics Impact factor: 2.718, year: 2016

  16. AUTOMATION OF POTENTIOMETRIC TITRATION WITH A ...

    African Journals Online (AJOL)

    An IBM compatible interface card system with infrared source-detector data sampling was designed and tested for automation of potentiometric titrations with personal computers without continuous measurement of the volume of the titrant. The device with other appropriate apparatus and setup was tested for determination ...

  17. Titrated Misoprostol Versus Dinoprostone for Labor Induction

    African Journals Online (AJOL)

    . Studied women were randomized into; Group I: 104 women included and received oral 200 µg misoprostol in 200 ml water titrated over 12 h and Group II: 108 women included and received vaginal dinoprostone tablet (3 mg) maximum two ...

  18. Isothermal Titration Calorimetry in the Student Laboratory

    Science.gov (United States)

    Wadso, Lars; Li, Yujing; Li, Xi

    2011-01-01

    Isothermal titration calorimetry (ITC) is the measurement of the heat produced by the stepwise addition of one substance to another. It is a common experimental technique, for example, in pharmaceutical science, to measure equilibrium constants and reaction enthalpies. We describe a stirring device and an injection pump that can be used with a…

  19. Titration Calculations with Computer Algebra Software

    Science.gov (United States)

    Lachance, Russ; Biaglow, Andrew

    2012-01-01

    This article examines the symbolic algebraic solution of the titration equations for a diprotic acid, as obtained using "Mathematica," "Maple," and "Mathcad." The equilibrium and conservation equations are solved symbolically by the programs to eliminate the approximations that normally would be performed by the student. Of the three programs,…

  20. NBL-Davies-Gray weight titration method

    International Nuclear Information System (INIS)

    Hassell, C.

    1981-01-01

    The titration method for uranium consists of the following basic steps: reduction of U +6 to U +4 by Fe +2 ; selective oxidation of excess Fe +2 by HNO 3 with Mo +6 catalyst, all in strong phosphoric acid solution; and titration of the U +4 with standard dichromate after dilution. In this paper, detailed procedure of the NBL method, its modification to a gravimetric system or weight titration technique, and miniaturization of the NBL titrimetric method are discussed. Improved precisions and accuracy (2 to 3 times), of the gravimetric titrant delivery has made it possible to reduce the amount of uranium taken for each analysis. At present, using gravimetric delivery, most samples are titrated in the 30 to 50 mg range. Improved precision has led to investigating the possibility of a scaled-down version of the basic method so as to reduce the volume of phosphoric acid waste generated. Because all reactions are carried out in the same vessel, this method can be automated. Analysts at NBL have been able to restrict error to 0.05% or better in the 30 to 100 mg range using the basic procedure

  1. Coulometric titration of ketotifen in tablets.

    Science.gov (United States)

    Ciesielski, W; Zakrzewski, R; Złobińska, U

    2005-03-01

    A method for the determination of ketotifen involving its reaction with iodine in an alkaline medium is presented. In coulometric titration using biamperometric end-point detection 0.25-2 micromol (77-618 microg) of ketotifen was successfully determined. The elaborated method was applied to the determination of ketotifen in drugs.

  2. Statistical thermodynamics of long straight rigid rods on triangular lattices: nematic order and adsorption thermodynamic functions.

    Science.gov (United States)

    Matoz-Fernandez, D A; Linares, D H; Ramirez-Pastor, A J

    2012-09-04

    The statistical thermodynamics of straight rigid rods of length k on triangular lattices was developed on a generalization in the spirit of the lattice-gas model and the classical Guggenheim-DiMarzio approximation. In this scheme, the Helmholtz free energy and its derivatives were written in terms of the order parameter, δ, which characterizes the nematic phase occurring in the system at intermediate densities. Then, using the principle of minimum free energy with δ as a parameter, the main adsorption properties were calculated. Comparisons with Monte Carlo simulations and experimental data were performed in order to evaluate the outcome and limitations of the theoretical model.

  3. Sorption of Zn(II) and Co(II) on Rutile Surfaces from 25 to 250 Degrees Centigrade by pH Titrations: Impact of X-Ray Standing Wave (XSW) and EXAFS Studies on Electrical Double Layer Models.

    Science.gov (United States)

    Wesolowski, D. J.; Machesky, M. L.; Zhang, Z.; Benezeth, P.; Fenter, P. A.; Sturchio, N. C.

    2002-12-01

    Experimental studies have been conducted on rutile powders (ca. 15 m2/g, 110 face dominant) in aqueous sodium trifluoromethanesulfonate (NaTr) solutions (0.03 and 0.30 molal) in a conventional glass-electrode autotitrator as well as a hydrogen-electrode concentration cell, which permits continuous pH-monitoring and sample removal for chemical analysis at elevated temperatures. The surface charge was determined in NaTr with and without 0.001 molal Zn or Co by pH titration, and separate experiments were conducted to determine the amount of metal ion adsorbed as a function of pH. These studies demonstrate that both cations are strongly sorbed, with the affinity for Zn being greater than that of Co. Ionic strength dependence of the sorption edges is very weak, and a combination of the two types of experiments indicates a proton release stoichiometry approaching 2:1 at high temperature. The pH of 50 percent adsorption for both ions decreases more rapidly with temperature than does the point of zero charge of the powder. X-ray Standing Wave measurements conducted on rutile 110 single crystal surfaces at the Advanced Photon Source (Zhang et al., this symposium) indicate that, at room temperature, Zn2+ binds predominantly as a monodentate species with surface oxygens bridged to two underlying titanium atoms. The zinc ions occupy positions equivalent to Ti lattice sites in the underlying crystal, resulting in a fixed distance of 3\\x8F above the Ti plane. Towle et al. (JCIS, 1999, v217, 299) conducted EXAFS studies of Co2+ adsorption on rutile (110) and (001) single crystal surfaces and concluded that this ion also occupies an equivalent Ti site, though they could not distinguish between bridged and terminal sites. These geometrical constraints, coupled with proton binding constants predicted from our temperature-extended MUSIC model, are applied in Stern Layer EDL models. The synchrotron results provide unequivocal evidence for "inner sphere" adsorption at room temperature

  4. An Olfactory Indicator for Acid-Base Titrations.

    Science.gov (United States)

    Flair, Mark N.; Setzer, William N.

    1990-01-01

    The use of an olfactory acid-base indicator in titrations for visually impaired students is discussed. Potential olfactory indicators include eugenol, thymol, vanillin, and thiophenol. Titrations performed with each indicator with eugenol proved to be successful. (KR)

  5. Hierarchically triangular prism structured Co3O4: Self-supported fabrication and photocatalytic property

    Science.gov (United States)

    The formation of ammonium cobalt (II) phosphate was utilized to synthesize unprecedented 3D structures of Co3O4, triangular prisms and trunk-like structures, via a self-supported and organics-free method. The length of a triangular side of the prepared 3D triangular prisms is ~1...

  6. Microculture virus titration--a simple colourimetric assay for influenza virus titration.

    Science.gov (United States)

    Levi, R; Beeor-Tzahar, T; Arnon, R

    1995-03-01

    Influenza antigens can be detected by several well established methods. However, when it is important to determine the titre of infective virions, a bioassay should be employed. The standard and the most widely used tests for influenza infectivity are titration carried out in embryonated hen eggs, or the plaque assay employing tissue culture techniques. A simple colourimetric assay for influenza virus detection and titration is described. Samples of allantoic fluid or mice lung homogenates were used to infect MDCK cultures in microplate wells. After an incubation period, the tetrazolium (MTT) colourimetric assay was used to determine cell viability, and when compared to untreated culture control enabled the detection and titration of several influenza strains. When samples were assayed simultaneously in embryonated eggs and by the MCVT method, good correlation in determined titres was obtained. The availability of an additional method for influenza titration allows more flexibility in the choice of titration method according to the specific needs of the study. Furthermore, this method lends itself to full automatization. Similar procedures should also be applicable to titration of other cytopathic viruses.

  7. Potentiometric determination of milligram amounts of uranium by semiautomatic titrator

    International Nuclear Information System (INIS)

    Ryzhinskij, M.V.; Stepanov, A.V.; Preobrazhenskaya, L.D.; Solntseva, L.F.; Gromova, E.A.

    1978-01-01

    A semiautomatic titrator is described which allows gravimetriotentiometricc-p titrat mg amounts of substances. Milligram amounts of uranium (absolute contents and oxygen/uranium ratio) in U 3 O 8 were determined as an example of the titrator action. The relative standard deviation was less than 0.001

  8. Simple and Automated Coulometric Titration of Acid Using Nonisolated Electrodes

    Science.gov (United States)

    Kuntzleman, Thomas S.; Kenney, Joshua B.; Hasbrouck, Scott; Collins, Michael J.; Amend, John R.

    2011-01-01

    Coulometric titrations involve the quantification of analyte by measurements of current and time. In most coulometric titrations, the anode and cathode are placed in isolated cells that are connected by a salt bridge. By contrast, the experiments described here involve coulometric titrations (of acidic protons in solution) using a silver anode and…

  9. Measurement and analysis of flow wall shear stress in an interior subchannel of triangular array rods

    International Nuclear Information System (INIS)

    Fakori-Monazah, M.R.; Todreas, N.E.

    1977-08-01

    A simulated model of triangular array rods with pitch to diameter ratio of 1.10 (as a test section) and air as the fluid flow was used to study the LMFBR hydraulic parameters. The wall shear stress distribution around the rod periphery, friction factors, static pressure distributions and turbulence intensity corresponding to various Reynolds numbers ranging from 4140 to 36170 in the central subchannel were measured. Various approaches for measurement of wall shear stress were compared. The measurement was performed using the Preston tube technique with the probe outside diameter equal to 0.014 in

  10. Thermodynamic and critical properties of an antiferromagnetically stacked triangular Ising antiferromagnet in a field

    Science.gov (United States)

    Žukovič, M.; Borovský, M.; Bobák, A.

    2018-05-01

    We study a stacked triangular lattice Ising model with both intra- and inter-plane antiferromagnetic interactions in a field, by Monte Carlo simulation. We find only one phase transition from a paramagnetic to a partially disordered phase, which is of second order and 3D XY universality class. At low temperatures we identify two highly degenerate phases: at smaller (larger) fields the system shows long-range ordering in the stacking direction (within planes) but not in the planes (stacking direction). Nevertheless, crossovers to these phases do not have a character of conventional phase transitions but rather linear-chain-like excitations.

  11. Determining a Solubility Product Constant by Potentiometric Titration to Increase Students' Conceptual Understanding of Potentiometry and Titrations

    Science.gov (United States)

    Grabowski, Lauren E.; Goode, Scott R.

    2017-01-01

    Potentiometric titrations are widely taught in first-year undergraduate courses to connect electrochemistry, stoichiometry, and equilibria and to reinforce acid-base titrations. Students perform a potentiometric titration that is then analyzed to determine analyte concentrations and the solubility product constant of the solid species.

  12. Optimal level of continuous positive airway pressure: auto-adjusting titration versus titration with a predictive equation.

    Science.gov (United States)

    Choi, Ji Ho; Jun, Young Joon; Oh, Jeong In; Jung, Jong Yoon; Hwang, Gyu Ho; Kwon, Soon Young; Lee, Heung Man; Kim, Tae Hoon; Lee, Sang Hag; Lee, Seung Hoon

    2013-05-01

    The aims of the present study were twofold. We sought to compare two methods of titrating the level of continuous positive airway pressure (CPAP) - auto-adjusting titration and titration using a predictive equation - with full-night manual titration used as the benchmark. We also investigated the reliability of the two methods in patients with obstructive sleep apnea syndrome (OSAS). Twenty consecutive adult patients with OSAS who had successful, full-night manual and auto-adjusting CPAP titration participated in this study. The titration pressure level was calculated with a previously developed predictive equation based on body mass index and apnea-hypopnea index. The mean titration pressure levels obtained with the manual, auto-adjusting, and predictive equation methods were 9.0 +/- 3.6, 9.4 +/- 3.0, and 8.1 +/- 1.6 cm H2O,respectively. There was a significant difference in the concordance within the range of +/- 2 cm H2O (p = 0.019) between both the auto-adjusting titration and the titration using the predictive equation compared to the full-night manual titration. However, there was no significant difference in the concordance within the range of +/- 1 cm H2O (p > 0.999). When compared to full-night manual titration as the standard method, auto-adjusting titration appears to be more reliable than using a predictive equation for determining the optimal CPAP level in patients with OSAS.

  13. Kinetic Titration Series with Biolayer Interferometry

    Science.gov (United States)

    Frenzel, Daniel; Willbold, Dieter

    2014-01-01

    Biolayer interferometry is a method to analyze protein interactions in real-time. In this study, we illustrate the usefulness to quantitatively analyze high affinity protein ligand interactions employing a kinetic titration series for characterizing the interactions between two pairs of interaction patterns, in particular immunoglobulin G and protein G B1 as well as scFv IC16 and amyloid beta (1–42). Kinetic titration series are commonly used in surface plasmon resonance and involve sequential injections of analyte over a desired concentration range on a single ligand coated sensor chip without waiting for complete dissociation between the injections. We show that applying this method to biolayer interferometry is straightforward and i) circumvents problems in data evaluation caused by unavoidable sensor differences, ii) saves resources and iii) increases throughput if screening a multitude of different analyte/ligand combinations. PMID:25229647

  14. Coulometrische titration von hypochloriten und chloraten.

    Science.gov (United States)

    Gründler, P; Holzapfel, H

    1970-03-01

    Hypochlorite was determined by direct coulometric titration with iron(II) in an acetate buffered solution. Chlorate was titrated with titanium(III) in 2M hydrochloric acid. Amperometric indication with one and two electrodes, respectively, was used. Mixtures of hypochlorites and chlorates, e.g., in industrial electrolytes, may be analysed. On a déterminé l'hypochlorite par titrage coulométrique direct avec le fer(II) dans une solution tamponnée à l'acétate. On a titré le chlorate avec le titane(III) en acide chlorhydrique 2M. On a utilisé l'indication ampérométrique une et deux électrodes respectivement. On peut analyser des mélanges d'hypochlorites et de chlorates, par exemple dans des électrolytes industriels.

  15. A microcomputer program for energy assessment and aggregation using the triangular probability distribution

    Science.gov (United States)

    Crovelli, R.A.; Balay, R.H.

    1991-01-01

    A general risk-analysis method was developed for petroleum-resource assessment and other applications. The triangular probability distribution is used as a model with an analytic aggregation methodology based on probability theory rather than Monte-Carlo simulation. Among the advantages of the analytic method are its computational speed and flexibility, and the saving of time and cost on a microcomputer. The input into the model consists of a set of components (e.g. geologic provinces) and, for each component, three potential resource estimates: minimum, most likely (mode), and maximum. Assuming a triangular probability distribution, the mean, standard deviation, and seven fractiles (F100, F95, F75, F50, F25, F5, and F0) are computed for each component, where for example, the probability of more than F95 is equal to 0.95. The components are aggregated by combining the means, standard deviations, and respective fractiles under three possible siutations (1) perfect positive correlation, (2) complete independence, and (3) any degree of dependence between these two polar situations. A package of computer programs named the TRIAGG system was written in the Turbo Pascal 4.0 language for performing the analytic probabilistic methodology. The system consists of a program for processing triangular probability distribution assessments and aggregations, and a separate aggregation routine for aggregating aggregations. The user's documentation and program diskette of the TRIAGG system are available from USGS Open File Services. TRIAGG requires an IBM-PC/XT/AT compatible microcomputer with 256kbyte of main memory, MS-DOS 3.1 or later, either two diskette drives or a fixed disk, and a 132 column printer. A graphics adapter and color display are optional. ?? 1991.

  16. Block-triangular preconditioners for PDE-constrained optimization

    KAUST Repository

    Rees, Tyrone

    2010-11-26

    In this paper we investigate the possibility of using a block-triangular preconditioner for saddle point problems arising in PDE-constrained optimization. In particular, we focus on a conjugate gradient-type method introduced by Bramble and Pasciak that uses self-adjointness of the preconditioned system in a non-standard inner product. We show when the Chebyshev semi-iteration is used as a preconditioner for the relevant matrix blocks involving the finite element mass matrix that the main drawback of the Bramble-Pasciak method-the appropriate scaling of the preconditioners-is easily overcome. We present an eigenvalue analysis for the block-triangular preconditioners that gives convergence bounds in the non-standard inner product and illustrates their competitiveness on a number of computed examples. Copyright © 2010 John Wiley & Sons, Ltd.

  17. A Novel Triangular Shaped UWB Fractal Antenna Using Circular Slot

    Science.gov (United States)

    Shahu, Babu Lal; Pal, Srikanta; Chattoraj, Neela

    2016-03-01

    The article presents the design of triangular shaped fractal based antenna with circular slot for ultra wideband (UWB) application. The antenna is fed using microstrip line and has overall dimension of 24×24×1.6 mm3. The proposed antenna is covering the wide frequency bandwidth of 2.99-11.16 GHz and is achieved using simple fractal based triangular-circular geometries and asymmetrical ground plane. The antenna is designed and parametrical studies are performed using method of moment (MOM) based Full Wave Electromagnetic (EM) software Simulator Zeland IE3D. The prototype of proposed antenna is fabricated and tested to compare the simulated and measured results of various antenna parameters. The antenna has good impedance bandwidth, nearly constant gain and stable radiation pattern. Measured return loss shows fair agreement with simulated one. Also measured group delay variation obtained is less than 1.0 ns, which proves good time domain behavior of the proposed antenna.

  18. Complex structure of triangular graphene: electronic, magnetic and electromechanical properties.

    Science.gov (United States)

    Ezawa, Motohiko

    2012-01-01

    We have investigated electronic and magnetic properties of graphene nanodisks (nanosize triangular graphene) as well as electromechanical properties of graphene nanojunctions. Nanodisks are nanomagnets made of graphene, which are robust against perturbation such as impurities and lattice defects, where the ferromagnetic order is assured by Lieb's theorem. We can generate a spin current by spin filter, and manipulate it by a spin valve, a spin switch and other spintronic devices made of graphene nanodisks. We have analyzed nanodisk arrays, which have multi-degenerate perfect flat bands and are ferromagnet. By connecting two triangular graphene corners, we propose a nanomechanical switch and rotator, which can detect a tiny angle rotation by measuring currents between the two corners. By making use of the strain induced Peierls transition of zigzag nanoribbons, we also propose a nanomechanical stretch sensor, in which the conductance can be switched off by a nanometer scale stretching.

  19. On elastic response of disordered triangular lattice during dynamic loading

    Directory of Open Access Journals (Sweden)

    Mastilović Sreten

    2008-01-01

    Full Text Available The present investigation focuses on an observation regarding the initial elastic response of a triangular geometrically and structurally disordered lattice during medium-to-high strain rate loading. Namely: a transition from the short-time modulus of elasticity to the long-time one, which is not accompanied by the corresponding change of the stiffness tensor. It is demonstrated that the difference between the two moduli is, in the case of the homogeneous biaxial test simulations performed herein, a consequence of the geometrical and structural disorder "quenched" within the lattice. The investigation is performed on the triangular lattice with the first-neighbor central interactions under practically identical in-plane conditions over eight decades of strain rate.

  20. Recurrence Relations for Orthogonal Polynomials on Triangular Domains

    Directory of Open Access Journals (Sweden)

    Abedallah Rababah

    2016-04-01

    Full Text Available In Farouki et al, 2003, Legendre-weighted orthogonal polynomials P n , r ( u , v , w , r = 0 , 1 , … , n , n ≥ 0 on the triangular domain T = { ( u , v , w : u , v , w ≥ 0 , u + v + w = 1 } are constructed, where u , v , w are the barycentric coordinates. Unfortunately, evaluating the explicit formulas requires many operations and is not very practical from an algorithmic point of view. Hence, there is a need for a more efficient alternative. A very convenient method for computing orthogonal polynomials is based on recurrence relations. Such recurrence relations are described in this paper for the triangular orthogonal polynomials, providing a simple and fast algorithm for their evaluation.

  1. Graphene Plasmons in Triangular Wedges and Grooves

    DEFF Research Database (Denmark)

    Gonçalves, P. A. D.; Dias, E. J. C.; Xiao, Sanshui

    2016-01-01

    and tunability of graphene plasmons guided along the apex of a graphene-covered dielectric wedge or groove. In particular, we present a quasi-analytic model to describe the plasmonic eigenmodes in such a system, including the complete determination of their spectrum and corresponding induced potential...... and electric-field distributions. We have found that the dispersion of wedge/groove graphene plasmons follows the same functional dependence as their flat-graphene plasmon counterparts, but now scaled by a (purely) geometric factor in which all the information about the system’s geometry is contained. We...

  2. Spectrophotometric titration of zirconium in siliceous materials

    International Nuclear Information System (INIS)

    Sugawara, K.F.; Su, Y.-S.; Strzegowski, W.R.

    1978-01-01

    An accurate and selective complexometric titration procedure based upon a spectrophotometrically detected end-point has been developed for the determination of zirconium in glasses, glass-ceramics and refractories. A p-bromomandelic acid separation step for zirconium imparts excellent selectivity to the procedure. The method is particularly important for the 1 to 5% concentration range where a simple, accurate and selective method for the determination of zirconium has been lacking. (author)

  3. Supercharacters and pattern subgroups in the upper triangular groups

    OpenAIRE

    Le, Tung

    2010-01-01

    Let $U_n(q)$ denote the upper triangular group of degree $n$ over the finite field $\\F_q$ with $q$ elements. It is known that irreducible constituents of supercharacters partition the set of all irreducible characters $\\Irr(U_n(q)).$ In this paper we present a correspondence between supercharacters and pattern subgroups of the form $U_k(q)\\cap {}^wU_k(q)$ where $w$ is a monomial matrix in $GL_k(q)$ for some $k

  4. Vibration immunity for a triangular Faraday current sensor

    Science.gov (United States)

    Fisher, Norman E.; Jackson, David A.

    1996-10-01

    We demonstrate a common-mode rejection scheme for a bulk- optic triangular Faraday current sensor that can eliminate optical noise induced by fiber-link vibration. The noise floor before applying common rejection was about 30 dB for a 100A Faraday signal and transceiver vibration levels of approximately 30 g. This was reduced to about 60 dB for the same vibration levels. The sensor's exploitation of Ampere's circuital law is also demonstrated.

  5. Procrustes Problems for General, Triangular, and Symmetric Toeplitz Matrices

    Directory of Open Access Journals (Sweden)

    Juan Yang

    2013-01-01

    Full Text Available The Toeplitz Procrustes problems are the least squares problems for the matrix equation AX=B over some Toeplitz matrix sets. In this paper the necessary and sufficient conditions are obtained about the existence and uniqueness for the solutions of the Toeplitz Procrustes problems when the unknown matrices are constrained to the general, the triangular, and the symmetric Toeplitz matrices, respectively. The algorithms are designed and the numerical examples show that these algorithms are feasible.

  6. A Critical Path Problem Using Triangular Neutrosophic Number

    OpenAIRE

    Mai Mohamed; Mohamed Abdel-Baset; Yongquan Zhou; Florentin Smarandache

    2017-01-01

    The Critical Path Method (CPM) is one of several related techniques for planning and managing of complicated projects in real world applications. In many situations, the data obtained for decision makers are only approximate, which gives rise of neutrosophic critical path problem. In this paper, the proposed method has been made to find the critical path in network diagram, whose activity time uncertain. The vague parameters in the network are represented by triangular neutrosophic numbers, i...

  7. Determination of milligram amounts of neptunium by potentiometric titration

    International Nuclear Information System (INIS)

    Ryzhinskij, M.V.; Solntseva, L.F.

    1981-01-01

    Two procedures of potentiometric titration of about 1 mg Np are reported which are based on its oxidation to neptunium (6) with silver (2) oxide followed by titration with iron (2) to neptunium (5) in one case and to neptunium (4) in the alternative one. The error is not greater than 0.2% rel. Ten-fold uranium excess does not interfere. Up to 1% of plutonium relative to neptunium does not interfere in the case of the titration to neptunium (5). In the titration to neptunium (4), plutonium is titrated stoichiometrically [ru

  8. A new sensor for thermometric titrations.

    Science.gov (United States)

    Najib, Fadhil M; Zewar, Sardir; Abdulla, Ahmad M

    2007-01-15

    A new thermometric sensor, which is a transistor (OC71), has been introduced to follow thermometric titrations successfully to clear end points. The sensor was suitable in both normal and differential modes of titration. It is possible to titrate down to 1.32micromol of HCl and 26.4micromol of H(3)BO(3)in a final 20ml solution with accuracy and precision of 1%, 2.2% and 1.4%, 2.2%, respectively. The sensor, in association with a pH glass electrode, was used for the determination of pK values of some well established weak acids such as, acetic acid (4.77), phosphoric acid (pK(1)=2.18, pK(2)=7.20 and pK(3)=12.32) as well as for a very weak acid of uncertain pK values H(3)BO(3) (pK(1)=9.20, pK(2)=12.7 and pK(3)=13.80). The sensor was also examined for kinetic catalytic determination of iron(III) in water, milk and pharmaceuticals.

  9. A monosegmented-flow Karl Fischer titrator.

    Science.gov (United States)

    de Aquino, Emerson Vidal; Rohwedder, Jarbas José Rodrigues; Pasquini, Celio

    2007-02-28

    A monosegmented volumetric Karl Fischer titrator is described to mechanize the determination of water content in organic solvents. The system is based on the flow-batch characteristics of the monosegmented analysis concept and employs biamperometry to monitor the progress of the titration. The system shows accuracy and precision that are highly independent of the flow rate, does not require calibration, and is carried out in a closed system capable of minimizing contact of the sample and reagents with ambient moisture. Sample volumes in the range of 40-300muL are employed, depending on the water concentration. An automatic dilution is provided to deal with concentrated samples. The consumption of Karl Fischer reagent depends on the water content of the sample but is not larger than 100muL. The system was evaluated for determination of water in ethanol and methanol in the range 0.02-0.5% (w/w). The average relative precision estimated in that range (9-3%) is comparable to that obtained with a larger volume commercial system and no significant difference was observed between the results obtained for the two systems at the 95% confidence level. A complete titration can be performed in less than 5min employing the proposed system.

  10. Potentiometric titrations in anhydrous acetic acid

    International Nuclear Information System (INIS)

    Le Port, L.

    1966-03-01

    The method used for studying anhydrous acetic acid is potentiometry with a glass electrode. We have in this way studied the titration of common inorganic acids (HClO 4 - HBr - H 2 SO 4 - HCl - HNO 3 - H 3 PO 4 ) and of some metallic salts. Furthermore we have shown that complex acids are formed between HCl and some metallic chlorides. An analysis of the titration curves for the inorganic acids against pyridinium chloride has made it possible to calculate a certain number of values for the dissociation pK of these acids and of the corresponding pyridinium salts. The titration of metallic perchlorates constitutes a method of studying the stability of acetates; we have thus been able to draw up a classification for some of these acetates. The metallic chlorides studied fall into two groups according to their behaviour in weak or strong acids. The differences have been explained on the basis of the role played by solvolysis. In the third part we have studied the acidic properties of mixtures of HCl with certain metallic chlorides. This work has demonstrated the existence, in certain cases, of acid complexes of the type (HCl) m MCl n . (author) [fr

  11. Natural convection in asymmetric triangular enclosures heated from below

    Science.gov (United States)

    Kamiyo, O. M.; Angeli, D.; Barozzi, G. S.; Collins, M. W.

    2014-11-01

    Triangular enclosures are typical configurations of attic spaces found in residential as well as industrial pitched-roof buildings. Natural convection in triangular rooftops has received considerable attention over the years, mainly on right-angled and isosceles enclosures. In this paper, a finite volume CFD package is employed to study the laminar air flow and temperature distribution in asymmetric rooftop-shaped triangular enclosures when heated isothermally from the base wall, for aspect ratios (AR) 0.2 <= AR <= 1.0, and Rayleigh number (Ra) values 8 × 105 <= Ra <= 5 × 107. The effects of Rayleigh number and pitch angle on the flow structure and temperature distributions within the enclosure are analysed. Results indicate that, at low pitch angle, the heat transfer between the cold inclined and the hot base walls is very high, resulting in a multi-cellular flow structure. As the pitch angle increases, however, the number of cells reduces, and the total heat transfer rate progressively reduces, even if the Rayleigh number, being based on the enclosure height, rapidly increases. Physical reasons for the above effect are inspected.

  12. Natural convection in asymmetric triangular enclosures heated from below

    International Nuclear Information System (INIS)

    Kamiyo, O M; Angeli, D; Enzo Ferrari, Universita di Modena e Reggio Emilia, via Vignolese 905, I-41125 Modena (Italy))" data-affiliation=" (DIEF – Dipartimento di Ingegneria Enzo Ferrari, Universita di Modena e Reggio Emilia, via Vignolese 905, I-41125 Modena (Italy))" >Barozzi, G S; Collins, M W

    2014-01-01

    Triangular enclosures are typical configurations of attic spaces found in residential as well as industrial pitched-roof buildings. Natural convection in triangular rooftops has received considerable attention over the years, mainly on right-angled and isosceles enclosures. In this paper, a finite volume CFD package is employed to study the laminar air flow and temperature distribution in asymmetric rooftop-shaped triangular enclosures when heated isothermally from the base wall, for aspect ratios (AR) 0.2 ≤ AR ≤ 1.0, and Rayleigh number (Ra) values 8 × 10 5 ≤ Ra ≤ 5 × 10 7 . The effects of Rayleigh number and pitch angle on the flow structure and temperature distributions within the enclosure are analysed. Results indicate that, at low pitch angle, the heat transfer between the cold inclined and the hot base walls is very high, resulting in a multi-cellular flow structure. As the pitch angle increases, however, the number of cells reduces, and the total heat transfer rate progressively reduces, even if the Rayleigh number, being based on the enclosure height, rapidly increases. Physical reasons for the above effect are inspected

  13. Characterization of Sea Lettuce Surface Functional Groups by Potentiometric Titrations

    Science.gov (United States)

    Ebling, A. M.; Schijf, J.

    2008-12-01

    In pursuit of our ultimate goal to better understand the prodigious capacity of the marine macroalga Ulva lactuca (sea lettuce) for adsorbing a broad range of dissolved trace metals from seawater, we performed an initial characterization of its surface functional groups. Specifically, the number of distinct functional groups as well as their individual bulk concentrations and acid dissociation constants (pKas) were determined by potentiometric titrations in NaCl solutions of various ionic strengths (I = 0.01-5.0 M), under inert nitrogen atmosphere at 25°C. Depending on the ionic strength, Ulva samples were manually titrated down to pH 2 or 3 with 1 N HCl and then up to pH 10 with 1 N NaOH in steps of 0.1-0.2 units, continuously monitoring pH with a glass combination electrode. Titrations of a dehydrated Ulva standard reference material (BCR-279) were compared with fresh Ulva tissue cultured in our laboratory. A titration in filtered natural seawater was also compared with one in an NaCl solution of equal ionic strength. Equilibrium constants for the ionization of water in NaCl solutions as a function of ionic strength were obtained from the literature. Fits to the titration data ([H]T vs. pH) were performed with the FITEQL4.0 computer code using non-electrostatic 3-, 4-, and 5-site models, either by fixing ionic strength at its experimental value or by allowing it to be extrapolated to zero, while considering all functional group pKas and bulk concentrations as adjustable parameters. Since pKas and bulk concentrations were found to be strongly correlated, the latter were also fixed in some cases to further constrain the pKas. Whereas these calculations are currently ongoing, preliminary results point to three, possibly four, functional groups with pKas of about 4.1, 6.3, and 9.5 at I = 0. Bulk concentrations of the three groups are very similar, about 5-6×10-4 mol/g based on dry weight, which suggests that all are homogeneously distributed over the surface and

  14. Is automatic CPAP titration as effective as manual CPAP titration in OSAHS patients? A meta-analysis.

    Science.gov (United States)

    Gao, Weijie; Jin, Yinghui; Wang, Yan; Sun, Mei; Chen, Baoyuan; Zhou, Ning; Deng, Yuan

    2012-06-01

    It is costly and time-consuming to conduct the standard manual titration to identify an effective pressure before continuous positive airway pressure (CPAP) treatment for obstructive sleep apnea (OSA) patients. Automatic titration is cheaper and more easily available than manual titration. The purpose of this systematic review was to evaluate the effect of automatic titration in identifying a pressure and on the improvement of apnea/hyponea index (AHI) and somnolence, the change of sleep quality, and the acceptance and compliance of CPAP treatment, compared with the manual titration. A systematic search was made of the PubMed, EMBASE, Cochrane Library, SCI, China Academic Journals Full-text Databases, Chinese Biomedical Literature Database, Chinese Scientific Journals Databases and Chinese Medical Association Journals. Randomized controlled trials comparing automatic titration and manual titration were reviewed. Studies were pooled to yield odds ratios (OR) or mean differences (MD) with 95% confidence intervals (CI). Ten trials involving 849 patients met the inclusion criteria. It is hard to identify a trend in the pressures determined by either automatic or manual titration. Automatic titration can improve the AHI (MD = 0.03/h, 95% CI = -4.48 to 4.53) and Epworth sleepiness scale (SMD = -0.02, 95% CI = -0.34 to 0.31,) as effectively as the manual titration. There is no difference between sleep architecture under automatic titration or manual titration. The acceptance of CPAP treatment (OR = 0.96, 95% CI = 0.60 to 1.55) and the compliance with treatment (MD = -0.04, 95% CI = -0.17 to 0.10) after automatic titration is not different from manual titration. Automatic titration is as effective as standard manual titration in improving AHI, somnolence while maintaining sleep quality similar to the standard method. In addition, automatic titration has the same effect on the acceptance and compliance of CPAP treatment as manual titration. With the potential advantage

  15. A test of the bosonic spinon theory for the triangular antiferromagnet spectrum

    Science.gov (United States)

    Mezio, A.; Sposetti, C. N.; Manuel, L. O.; Trumper, A. E.

    2011-05-01

    We compute the dynamical structure factor of the spin-½ triangular Heisenberg model using the mean-field Schwinger boson theory. We find that a reconstructed dispersion, resulting from a non-trivial redistribution of the spectral weight, agrees quite well with the spin excitation spectrum recently found with series expansions. In particular, we recover the strong renormalization with respect to linear spin wave theory along with the appearance of roton-like minima. Furthermore, near the roton-like minima the contribution of the two spinon continuum to the static structure factor is about 40% of the total weight. By computing the density-density dynamical structure factor, we identify an unphysical weak signal of the spin excitation spectrum with the relaxation of the local constraint of the Schwinger bosons at the mean-field level. Based on the accurate description obtained for the static and dynamic ground-state properties, we argue that the bosonic spinon theory should be considered seriously as a valid alternative to interpret the physics of the triangular Heisenberg model.

  16. Numerical investigation of Al2O3/water nanofluid laminar convective heat transfer through triangular ducts

    Directory of Open Access Journals (Sweden)

    Zeinali Heris Saeed

    2011-01-01

    Full Text Available Abstract In this article, laminar flow-forced convective heat transfer of Al2O3/water nanofluid in a triangular duct under constant wall temperature condition is investigated numerically. In this investigation, the effects of parameters, such as nanoparticles diameter, concentration, and Reynolds number on the enhancement of nanofluids heat transfer is studied. Besides, the comparison between nanofluid and pure fluid heat transfer is achieved in this article. Sometimes, because of pressure drop limitations, the need for non-circular ducts arises in many heat transfer applications. The low heat transfer rate of non-circular ducts is one the limitations of these systems, and utilization of nanofluid instead of pure fluid because of its potential to increase heat transfer of system can compensate this problem. In this article, for considering the presence of nanoparticl: es, the dispersion model is used. Numerical results represent an enhancement of heat transfer of fluid associated with changing to the suspension of nanometer-sized particles in the triangular duct. The results of the present model indicate that the nanofluid Nusselt number increases with increasing concentration of nanoparticles and decreasing diameter. Also, the enhancement of the fluid heat transfer becomes better at high Re in laminar flow with the addition of nanoparticles.

  17. A Novel Method for Multiattribute Decision Making with Dual Hesitant Fuzzy Triangular Linguistic Information

    Directory of Open Access Journals (Sweden)

    Yanbing Ju

    2014-01-01

    Full Text Available This paper studies the multiattribute decision making (MADM problems in which the attribute values take the form of dual hesitant fuzzy triangular linguistic elements and the weights of attributes take the form of real numbers. Firstly, to solve the situation where the membership degree and the nonmembership degree of an element to a triangular linguistic variable, the concept, operational laws, score function, and accuracy function of dual hesitant fuzzy triangular linguistic elements (DHFTLEs are defined. Then, some dual hesitant fuzzy triangular linguistic geometric aggregation operators are developed for aggregating the DHFTLEs, including dual hesitant fuzzy triangular linguistic weighted geometric (DHFTLWG operator, dual hesitant fuzzy triangular linguistic ordered weighted geometric (DHFTLOWG operator, dual hesitant fuzzy triangular linguistic hybrid geometric (DHFTLHG operator, generalized dual hesitant fuzzy triangular linguistic weighted geometric (GDHFTLWG operator, and generalized dual hesitant fuzzy triangular linguistic ordered weighted geometric (GDHFTLOWG operator. Furthermore, some desirable properties of these operators are investigated in detail. Based on the proposed operators, an approach to MADM with dual hesitant fuzzy triangular linguistic information is proposed. Finally, a numerical example for investment alternative selection is given to illustrate the application of the proposed method.

  18. Design Coefficients and Cracking Paths of Circular, Elliptic and Triangular Isolated Slabs

    Directory of Open Access Journals (Sweden)

    Juárez-Luna Gelacio

    2014-01-01

    Full Text Available Design coefficients and cracking paths for circular, elliptical and triangular labsare obtained by damage mechanics were determined. The nonlinear behavior of the reinforced concrete was simulated with a damage model which considers softening, whereas the behavior of the reinforcing steel was modeling with a bilinear plasticity model which has a Von Mises yield surface. The constitutive models and the finite element method were validated by comparing the computed numerical results with the experimental results of a rectangular slab reported in the scientific literature. The distribution of the reinforcing steel was proposed based on linear elastic analysis with plate elements. The coefficients were computed with elastic and nonlinear analyses, noticing that the last has a variation because of the stress redistribution. The crack paths are shown, which are dependent on the boundary conditions. The coefficients and the distribution of the reinforcing steel are a base on the regulation for the analysis and design of slabs with this kind of geometry.

  19. Use of triangular membership function for prediction of compressive strength of concrete containing nanosilica

    Directory of Open Access Journals (Sweden)

    Sakshi Gupta

    2015-12-01

    Full Text Available In this paper, application of fuzzy logic technique using triangular membership function for developing models for predicting compressive strength of concrete with partial replacement of cement with nanosilica has been carried out. For this, the data have been taken from various literatures and help in optimizing the constituents available and reducing cost and efforts in studying design to develop mixes by predefining suitable range for experimenting. The use of nanostructured materials in concrete can add many benefits that are directly related to the durability of various cementitious materials, besides the fact that it is possible to reduce the quantities of cement in the composite. Successful prediction by the model indicates that fuzzy logic could be a useful modelling tool for engineers and research scientists in the area of cement and concrete. Compressive strength values of concrete can be predicted in fuzzy logic models without attempting any experiments in a quite short period of time with tiny error rates.

  20. Triangular preconditioners for saddle point problems with a penalty term

    Energy Technology Data Exchange (ETDEWEB)

    Klawonn, A. [Westfaelische Wilhelms-Universitaet, Muenster (Germany)

    1996-12-31

    Triangular preconditioners for a class of saddle point problems with a penalty term are considered. An important example is the mixed formulation of the pure displacement problem in linear elasticity. It is shown that the spectrum of the preconditioned system is contained in a real, positive interval, and that the interval bounds can be made independent of the discretization and penalty parameters. This fact is used to construct bounds of the convergence rate of the GMRES method used with an energy norm. Numerical results are given for GMRES and BI-CGSTAB.

  1. Collective impurity effects in the Heisenberg triangular antiferromagnet

    International Nuclear Information System (INIS)

    Maryasin, V S; Zhitomirsky, M E

    2015-01-01

    We theoretically investigate the Heisenberg antiferromagnet on a triangular lattice doped with nonmagnetic impurities. Two nontrivial effects resulting from collective impurity behavior are predicted. The first one is related to presence of uncompensated magnetic moments localized near vacancies as revealed by the low-temperature Curie tail in the magnetic susceptibility. These moments exhibit an anomalous growth with the impurity concentration, which we attribute to the clustering mechanism. In an external magnetic field, impurities lead to an even more peculiar phenomenon lifting the classical ground-state degeneracy in favor of the conical state. We analytically demonstrate that vacancies spontaneously generate a positive biquadratic exchange, which is responsible for the above degeneracy lifting

  2. Triangular flow of negative pions emitted in PbAu collisions at $\\sqrt{S_{NN}} = 17.3$ GeV

    CERN Document Server

    Adamová, D.

    Differential triangular flow, $v_3(p_T)$, of negative pions is measured at $\\sqrt{s_{NN}}$= 17.3~GeV around midrapidity by the CERES/NA45 experiment at CERN in central PbAu collisions in the range 0-30\\% with a mean centrality of 5.5\\%. This is the first measurement of the triangular flow at SPS energies. The $p_T$ range extends from about 0.05~GeV/c to more than 2~GeV/c. The triangular flow magnitude, corrected for the HBT effects, is smaller by a factor of about 2 than the one measured by the PHENIX experiment at RHIC and the ALICE experiment at the LHC. Within the analyzed range of central collisions no significant centrality dependence is observed. The data are found to be well described by a viscous hydro calculation combined with an UrQMD cascade model for the late stages.

  3. Numerical linked-cluster algorithms. I. Spin systems on square, triangular, and kagomé lattices.

    Science.gov (United States)

    Rigol, Marcos; Bryant, Tyler; Singh, Rajiv R P

    2007-06-01

    We discuss recently introduced numerical linked-cluster (NLC) algorithms that allow one to obtain temperature-dependent properties of quantum lattice models, in the thermodynamic limit, from exact diagonalization of finite clusters. We present studies of thermodynamic observables for spin models on square, triangular, and kagomé lattices. Results for several choices of clusters and extrapolations methods, that accelerate the convergence of NLCs, are presented. We also include a comparison of NLC results with those obtained from exact analytical expressions (where available), high-temperature expansions (HTE), exact diagonalization (ED) of finite periodic systems, and quantum Monte Carlo simulations. For many models and properties NLC results are substantially more accurate than HTE and ED.

  4. Improving medication titration in heart failure by embedding a structured medication titration plan.

    Science.gov (United States)

    Hickey, Annabel; Suna, Jessica; Marquart, Louise; Denaro, Charles; Javorsky, George; Munns, Andrew; Mudge, Alison; Atherton, John J

    2016-12-01

    To improve up-titration of medications to target dose in heart failure patients by improving communication from hospital to primary care. This quality improvement project was undertaken within three heart failure disease management (HFDM) services in Queensland, Australia. A structured medication plan was collaboratively designed and implemented in an iterative manner, using methods including awareness raising and education, audit and feedback, integration into existing work practice, and incentive payments. Evaluation was undertaken using sequential audits, and included process measures (use of the titration plan, assignment of responsibility) and outcome measures (proportion of patients achieving target dose) in HFDM service patients with reduced left ventricular ejection fraction. Comparison of the three patient cohorts (pre-intervention cohort A n=96, intervention cohort B n=95, intervention cohort C n=89) showed increase use of the titration plan, a shift to greater primary care responsibility for titration, and an increase in the proportion of patients achieving target doses of angiotensin converting enzyme inhibitors/angiotensin receptor blockers (ACEI/ARB) (A 37% vs B 48% vs C 55%, p=0.051) and beta-blockers (A 38% vs B 33% vs C 51%, p=0.045). Combining all three cohorts, patients not on target doses when discharged from hospital were more likely to achieve target doses of ACEI/ARB (pplan. A medication titration plan was successfully implemented in three HFDM services and improved transitional communication and achievement of target doses of evidence-based therapies within six months of hospital discharge. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.

  5. Up-titration of allopurinol in patients with gout.

    Science.gov (United States)

    Jennings, Claudine G; Mackenzie, Isla S; Flynn, Rob; Ford, Ian; Nuki, George; De Caterina, Raffaele; Riches, Philip L; Ralston, Stuart H; MacDonald, Thomas M

    2014-08-01

    European League against Rheumatism (EULAR) gout management guidelines recommend achieving a target urate level titration in achieving the EULAR target levels. The Febuxostat versus Allopurinol Streamlined Trial (FAST) is an ongoing multi-centre study comparing the cardiovascular safety of febuxostat and allopurinol (target recruitment: 5706 patients). Recruited patients were already taking allopurinol and the protocol required up-titration of daily allopurinol dose, in 100 mg increments, to achieve the EULAR urate target level prior to randomisation. We reviewed pre-randomisation data from the first 400 recruited and subsequently randomised FAST patients. Of 400 patients, 144 (36%) had urate levels ≥357 µmol/L at screening and required allopurinol up-titration. Higher urate levels were significantly associated with lower allopurinol dose, male sex, increased BMI, increased alcohol intake and diuretic use. Mean fall in urate levels after a single 100-mg dose increase was 71 µmol/L. The number of up-titrations required ranged from one to five (median = 1) with 65% of patients controlled after one 100-mg up-titration. Overall, 97% of up-titrated patients achieved target urate levels with median final allopurinol dose of 300 mg daily. Side effects and complications of up-titration were minimal. Overall, 36% of FAST patients were not at target urate levels and required up-titration. Allopurinol up-titration was effective in achieving urate target levels and was generally well tolerated by patients. Copyright © 2014 Elsevier Inc. All rights reserved.

  6. Laboratory Automatic Titration of Chromium Plating and Electropolishing Solutions

    National Research Council Canada - National Science Library

    Sopok, Samuel

    2001-01-01

    .... The analytical chemistry literature lacks an adequate automatic titration method for the monitoring of chromic acid in chromium plating solutions and the monitoring of phosphoric and sulfuric acids...

  7. Automated titration method for use on blended asphalts

    Science.gov (United States)

    Pauli, Adam T [Cheyenne, WY; Robertson, Raymond E [Laramie, WY; Branthaver, Jan F [Chatham, IL; Schabron, John F [Laramie, WY

    2012-08-07

    A system for determining parameters and compatibility of a substance such as an asphalt or other petroleum substance uses titration to highly accurately determine one or more flocculation occurrences and is especially applicable to the determination or use of Heithaus parameters and optimal mixing of various asphalt stocks. In a preferred embodiment, automated titration in an oxygen gas exclusive system and further using spectrophotometric analysis (2-8) of solution turbidity is presented. A reversible titration technique enabling in-situ titration measurement of various solution concentrations is also presented.

  8. A computer controlled potentiometric titrator for quantitative determination of uranium

    International Nuclear Information System (INIS)

    Verdingh, V.; Michiels, A.

    1988-01-01

    The modified Davies and Gray methods is frequently used for the potentiometric titration of uranium. It is based upon the reduction of U(VI) to U(IV) with a reductant (e.g. Fe ++ ) followed by a selective oxidation of the excess of reductant and subsequent titration of U(IV) with potassium dichromate (K 2 Cr 2 O 7 ). Interference from other elements is low, but the method is rather cumbersome due to the number of reactants to be added before the titration is started. The timing of these additions also plays a role. In order to render the titration less dependent on human factors and with the aim of reaching high reproducibility, a computer controlled system has been designed and set-up. Reagents are added by five computer controlled burettes. A program allows the choice of volumes and waiting times, and commands the start of the final titration which is followed by the microprocessor of the automatic potentiometric titrator. In this way a routine uranium titration can be completed in about twelve minutes. Reproducibilities of the order of ±15% are achievable in routine operation. For high precision work, the titrator is used as an end-point detector. Titrant is added manually by mass, so as to react with > 99% of the uranium. The residual uranium is then titrated automatically by colume with diluted titrant. The precision can be improved by a factor of approximately ten. (orig.)

  9. Conjugate heat transfer in a porous cavity filled with nano-fluids and heated by a triangular thick wall

    International Nuclear Information System (INIS)

    Chamkha, Ali J.; Ismael, Muneer A.

    2013-01-01

    The conjugate natural convection-conduction heat transfer in a square domain composed of nano-fluids filled porous cavity heated by a triangular solid wall is studied under steady-state conditions. The vertical and horizontal walls of the triangular solid wall are kept isothermal and at the same hot temperature Th. The other boundaries surrounding the porous cavity are kept adiabatic except the right vertical wall where it is kept isothermally at the lower temperature T c . Equations governing the heat transfer in the triangular wall and heat and nano-fluid flow, based on the Darcy model, in the nano-fluid-saturated porous medium together with the derived relation of the interface temperature are solved numerically using the over-successive relaxation finite-difference method. A temperature independent nano-fluids properties model is adopted. Three nano-particle types dispersed in one base fluid (water) are investigated. The investigated parameters are the nano-particles volume fraction φ (0-0.2), Rayleigh number Ra (10-1000), solid wall to base-fluid saturated porous medium thermal conductivity ratio K ro (0.44, 1, 23.8), and the triangular wall thickness D (0.1-1). The results are presented in the conventional form; contours of streamlines and isotherms and the local and average Nusselt numbers. At a very low Rayleigh number Ra = 10, a significant enhancement in heat transfer within the porous cavity with φ is observed. Otherwise, the heat transfer may be enhanced or deteriorated with φ depending on the wall thickness D and the Rayleigh number Ra. At high Rayleigh numbers and low conductivity ratios, critical values of D, regardless of 4, are observed and accounted. (authors)

  10. Protofit: A program for determining surface protonation constants from titration data

    Science.gov (United States)

    Turner, Benjamin F.; Fein, Jeremy B.

    2006-11-01

    Determining the surface protonation behavior of natural adsorbents is essential to understand how they interact with their environments. ProtoFit is a tool for analysis of acid-base titration data and optimization of surface protonation models. The program offers a number of useful features including: (1) enables visualization of adsorbent buffering behavior; (2) uses an optimization approach independent of starting titration conditions or initial surface charge; (3) does not require an initial surface charge to be defined or to be treated as an optimizable parameter; (4) includes an error analysis intrinsically as part of the computational methods; and (5) generates simulated titration curves for comparison with observation. ProtoFit will typically be run through ProtoFit-GUI, a graphical user interface providing user-friendly control of model optimization, simulation, and data visualization. ProtoFit calculates an adsorbent proton buffering value as a function of pH from raw titration data (including pH and volume of acid or base added). The data is reduced to a form where the protons required to change the pH of the solution are subtracted out, leaving protons exchanged between solution and surface per unit mass of adsorbent as a function of pH. The buffering intensity function Qads* is calculated as the instantaneous slope of this reduced titration curve. Parameters for a surface complexation model are obtained by minimizing the sum of squares between the modeled (i.e. simulated) buffering intensity curve and the experimental data. The variance in the slope estimate, intrinsically produced as part of the Qads* calculation, can be used to weight the sum of squares calculation between the measured buffering intensity and a simulated curve. Effects of analytical error on data visualization and model optimization are discussed. Examples are provided of using ProtoFit for data visualization, model optimization, and model evaluation.

  11. On the interference rejection capabilities of triangular antenna array for cellular base stations

    KAUST Repository

    Atat, Rachad

    2012-03-01

    In this paper, we present the performance analysis of the triangular antenna arrays in terms of the interference rejection capability. In this context, we derive an expression to calculate the spatial interference suppression coefficient for the triangular antenna array with variable number of antenna elements. The performance of the triangular antenna array has been compared with the circular antenna array with respect to interference suppression performance, steering beam pattern, beamwidth and directivity. Simulation results show that the triangular array with large number of elements produces a sharper beamwidth and better interference suppression performance than the circular antenna array. © 2012 IEEE.

  12. Corrosion processes of triangular silver nanoparticles compared to bulk silver

    Energy Technology Data Exchange (ETDEWEB)

    Keast, V. J., E-mail: vicki.keast@newcastle.edu.au; Myles, T. A. [University of Newcastle, School of Mathematical and Physical Sciences (Australia); Shahcheraghi, N.; Cortie, M. B. [University of Technology Sydney, Institute for Nanoscale Technology (Australia)

    2016-02-15

    Excessive corrosion of silver nanoparticles is a significant impediment to their use in a variety of potential applications in the biosensing, plasmonic and antimicrobial fields. Here we examine the environmental degradation of triangular silver nanoparticles (AgNP) in laboratory air. In the early stages of corrosion, transmission electron microscopy shows that dissolution of the single-crystal, triangular, AgNP (side lengths 50–120 nm) is observed with the accompanying formation of smaller, polycrystalline Ag particles nearby. The new particles are then observed to corrode to Ag{sub 2}S and after 21 days nearly full corrosion has occurred, but some with minor Ag inclusions remaining. In contrast, a bulk Ag sheet, studied in cross section, showed an adherent corrosion layer of only around 20–50 nm in thickness after over a decade of being exposed to ambient air. The results have implications for antibacterial properties and ecotoxicology of AgNP during corrosion as the dissolution and reformation of Ag particles during corrosion will likely be accompanied by the release of Ag{sup +} ions.

  13. High magnetic field magnetization of a new triangular lattice antiferromagnet

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, H. D. [Univ. of Tennessee, Knoxville, TN (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States). National High Magnetic Field Lab. (MagLab); Stritzinger, Laurel Elaine Winter [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Harrison, Neil [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-03-23

    In CsV(MoO4)2, the magnetic V3+ ions with octahedral oxygen-coordination form a geometrically frustrated triangular lattice. So fare, there is no magnetic properties reported on it. Recently, we successfully grew single crystals of CsV(MoO4)2 by using flux method. The susceptibility shows a sharp drop around 24 K, representing a long range magnetic ordering. To understand the physical properties of this new triangular lattice antiferromagnet (TLAF), we pursued high field magnetization measurements to answer two questions: (i) what is the saturation field, which will be very useful to calculate the exchange interaction of the system? (ii) Will it exhibit spin state transition, such as the up up down phase with 1/3-saturation moment as other TLAFs? Recently, we performed VSM measurements in Cell 8, Tallahassee, NHMFL, the results show that the magnetization reaches 0.38 MuB at 34 T, which is just 19% of the full moment of 2 MuB for V3+ (3d2) ions. Apparently we need higher field to reach 1/3 value or full moment.

  14. Triangular Geometrized Sampling Heuristics for Fast Optimal Motion Planning

    Directory of Open Access Journals (Sweden)

    Ahmed Hussain Qureshi

    2015-02-01

    Full Text Available Rapidly-exploring Random Tree (RRT-based algorithms have become increasingly popular due to their lower computational complexity as compared with other path planning algorithms. The recently presented RRT* motion planning algorithm improves upon the original RRT algorithm by providing optimal path solutions. While RRT determines an initial collision-free path fairly quickly, RRT* guarantees almost certain convergence to an optimal, obstacle-free path from the start to the goal points for any given geometrical environment. However, the main limitations of RRT* include its slow processing rate and high memory consumption, due to the large number of iterations required for calculating the optimal path. In order to overcome these limitations, we present another improvement, i.e, the Triangular Geometerized-RRT* (TG-RRT* algorithm, which utilizes triangular geometrical methods to improve the performance of the RRT* algorithm in terms of the processing time and a decreased number of iterations required for an optimal path solution. Simulations comparing the performance results of the improved TG-RRT* with RRT* are presented to demonstrate the overall improvement in performance and optimal path detection.

  15. A Closer Look at Acid-Base Olfactory Titrations

    Science.gov (United States)

    Neppel, Kerry; Oliver-Hoyo, Maria T.; Queen, Connie; Reed, Nicole

    2005-01-01

    Olfactory titrations using raw onions and eugenol as acid-base indicators are reported. An in-depth investigation on olfactory titrations is presented to include requirements for potential olfactory indicators and protocols for using garlic, onions, and vanillin as acid-base olfactory indicators are tested.

  16. Titrated oral misoprostol solution- a new method of labour induction ...

    African Journals Online (AJOL)

    Titrated oral misoprostol solution- a new method of labour induction. ... To develop a new method of misoprostol use for labour induction using very small, frequent, titrated oral dosages, and to pilot effectiveness. Study design. Open clinical pilot ... A multicentre randomised trial of this method is underway. We emphasise the ...

  17. Automated proton titrations of pancreatic phospholipase A2

    NARCIS (Netherlands)

    Donné-Op den Kelder, G.M.; Haas, G.H. de; Egmond, M.R.

    1982-01-01

    A computer-controlled titration system has been developed, tested, and used for analysis of the proton-titration behavior of pancreatic phospholipase A2 from ox, horse, and pig. The results revealed an error in the reported amino acid composition of the equine enzyme. A simple interface for the

  18. a randomised trial comparing Foley catheter plus titrated oral ...

    African Journals Online (AJOL)

    Labour induction at term - a randomised trial comparing. Foley catheter plus titrated oral misoprostol solution, titrated oral misoprostol solution alone, and dinoprostone. Baron B Matonhodze, G Justus Hofmeyr, Jonathan Levin. Objectives. To compare three methods of labour induction. Design. Randomised controlled trial.

  19. New applications of corrosion measurements by titration (CMT)

    DEFF Research Database (Denmark)

    Bech-Nielsen, Gregers

    1998-01-01

    . It is shown that when aluminium dissolves in alkali, CMT measurements can also be applied, but in this case requiring titration with alkali. Titration with alkali is also required in a special situation, where corrosion of nickel in an acid solution and subsequent formation of a nickel complex results...

  20. The coulometric titration of acids and bases in dimethylsulfoxide media

    NARCIS (Netherlands)

    Bos, M.; IJpma, S.T.; Dahmen, E.A.M.F.

    1976-01-01

    The coulometric titration of 20–200 μeq of acids and bases in DMSO media is described. In the titration of bases, the electro-oxidation of hydrogen at a platinized platinum electrode is used as the source of protons. The conditions for 100 % current efficiency at this electrode are low current

  1. Developing a multipoint titration method with a variable dose implementation for anaerobic digestion monitoring.

    Science.gov (United States)

    Salonen, K; Leisola, M; Eerikäinen, T

    2009-01-01

    Determination of metabolites from an anaerobic digester with an acid base titration is considered as superior method for many reasons. This paper describes a practical at line compatible multipoint titration method. The titration procedure was improved by speed and data quality. A simple and novel control algorithm for estimating a variable titrant dose was derived for this purpose. This non-linear PI-controller like algorithm does not require any preliminary information from sample. Performance of this controller is superior compared to traditional linear PI-controllers. In addition, simplification for presenting polyprotic acids as a sum of multiple monoprotic acids is introduced along with a mathematical error examination. A method for inclusion of the ionic strength effect with stepwise iteration is shown. The titration model is presented with matrix notations enabling simple computation of all concentration estimates. All methods and algorithms are illustrated in the experimental part. A linear correlation better than 0.999 was obtained for both acetate and phosphate used as model compounds with slopes of 0.98 and 1.00 and average standard deviations of 0.6% and 0.8%, respectively. Furthermore, insensitivity of the presented method for overlapping buffer capacity curves was shown.

  2. 26 CFR 1.1502-30 - Stock basis after certain triangular reorganizations.

    Science.gov (United States)

    2010-04-01

    ... 26 Internal Revenue 12 2010-04-01 2010-04-01 false Stock basis after certain triangular... (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES Basis, Stock Ownership, and Earnings and Profits Rules § 1.1502-30 Stock basis after certain triangular reorganizations. (a) Scope. This section provides rules...

  3. The Preterm Infant's Use of Triangular Bids at Three Months, Adjusted Age: Two Case Studies

    Science.gov (United States)

    Hansen, Ellen Saeter

    2011-01-01

    This article focuses on preterm infants' early triangular capacity, restricted to the use of triangular bids in interaction with their parents. An observational setting, the Lausanne Trilogue Play (LTP), is used for studying the patterns of interaction. This is an approach focusing on the family as a whole. These observations are part of a study…

  4. Incommensurate correlations in the anisotropic triangular Heisenberg lattice

    Science.gov (United States)

    Weichselbaum, Andreas; White, Steven R.

    2011-12-01

    We study the anisotropic spin-1/2 antiferromagnetic triangular Heisenberg lattice in two dimensions, seen as a set of chains with couplings J (J') along (in-between) chains, respectively. Our focus is on the incommensurate correlation that emerges in this system in a wide parameter range due to the intrinsic frustration of the spins. We study this system with traditional density matrix renormalization group using cylindrical boundary conditions to least constrain possible incommensurate order. Despite that the limit of essentially decoupled chains J'/J≲0.5 is not very accessible numerically, it appears that the spin-spin correlations remain incommensurate for any finite 0JC', where JC'/J>1. The incommensurate wave vector qJ, however, approaches the commensurate value corresponding to the antiferromagnetic correlation of a single chain very rapidly with decreasing J'/J, roughly as qJ˜π-c1(J'/J)ne-c2J/J'.

  5. Quantum Simulation of Frustrated Classical Magnetism in Triangular Optical Lattices

    Science.gov (United States)

    Struck, J.; Ölschläger, C.; Le Targat, R.; Soltan-Panahi, P.; Eckardt, A.; Lewenstein, M.; Windpassinger, P.; Sengstock, K.

    2011-08-01

    Magnetism plays a key role in modern technology and stimulates research in several branches of condensed matter physics. Although the theory of classical magnetism is well developed, the demonstration of a widely tunable experimental system has remained an elusive goal. Here, we present the realization of a large-scale simulator for classical magnetism on a triangular lattice by exploiting the particular properties of a quantum system. We use the motional degrees of freedom of atoms trapped in an optical lattice to simulate a large variety of magnetic phases: ferromagnetic, antiferromagnetic, and even frustrated spin configurations. A rich phase diagram is revealed with different types of phase transitions. Our results provide a route to study highly debated phases like spin-liquids as well as the dynamics of quantum phase transitions.

  6. Solution of Volterra and Fredholm Classes of Equations via Triangular Orthogonal Function (A Combination of Right Hand Triangular Function and Left Hand Triangular Function) and Hybrid Orthogonal Function (A Combination of Sample Hold Function and Right Hand Triangular Function)

    Science.gov (United States)

    Mukhopadhyay, Anirban; Ganguly, Anindita; Chatterjee, Saumya Deep

    2018-01-01

    In this paper the authors have dealt with seven kinds of non-linear Volterra and Fredholm classes of equations. The authors have formulated an algorithm for solving the aforementioned equation types via Hybrid Function (HF) and Triangular Function (TF) piecewise-linear orthogonal approach. In this approach the authors have reduced integral equation or integro-differential equation into equivalent system of simultaneous non-linear equation and have employed either Newton's method or Broyden's method to solve the simultaneous non-linear equations. The authors have calculated the L2-norm error and the max-norm error for both HF and TF method for each kind of equations. Through the illustrated examples, the authors have shown that the HF based algorithm produces stable result, on the contrary TF-computational method yields either stable, anomalous or unstable results.

  7. Temporal triangular alopecia and a review of 52 past cases.

    Science.gov (United States)

    Yamazaki, Masashi; Irisawa, Ryokichi; Tsuboi, Ryoji

    2010-04-01

    Temporal triangular alopecia (TTA) is a circumscribed, non-cicatricial form of alopecia confined to the frontotemporal region. The patient, a 15-year-old boy, was noticed at birth to have an alopecial area, sized 1.5 cm x 2.5 cm, in the right temporal region. Microscopic examination revealed miniaturized hair follicles accompanied by differentiated sebaceous glands. We have provided a synopsis of the past 52 cases. Of the 53 cases of TTA including our case, more than half (55.8%) were detected in childhood between the ages of 2 and 9 years, while 36.5% were detected at birth and only 3.8% (only two cases) in adulthood. There were three familial cases. Several congenital diseases were associated with the condition, for example, phakomatosis pigmentovascularis, Down syndrome and Dandy-Walker malformation. This information suggests that TTA can be recognized as a hamartomatous mosaic disease.

  8. Carrier fringes and a non-conventional rotational shear in a triangular cyclic-path interferometer

    Science.gov (United States)

    Kantun-Montiel, Rosaura; Meneses-Fabian, Cruz

    2015-04-01

    This work presents a method for generating carrier fringes and a nonconventional rotational shear in a triangular cyclic-path interferometer, while simultaneously suppressing the presence of typical lateral and radial shearing. To carry out this method, a 4f optical system is implemented into the cyclic interferometer. The most important contributions of this paper are its demonstration of the linear dependence of the movable mirror displacement with the carrier frequency introduced, and the realization of a nonconventional rotational shearing interferometer. Additionally, we think that one of its possible potential applications is the observation of the angular derivative of parallel projections of a phase object placed at the output plane, generating a great advantage in edge-enhancement optical tomography. In this paper, we develop a theoretical model and show experimental results.

  9. An Exact Method to Determine the Conductivity of Aqueous Solutions in Acid-Base Titrations

    Directory of Open Access Journals (Sweden)

    Norma Rodríguez-Laguna

    2015-01-01

    Full Text Available Several works in the literature show that it is possible to establish the analytic equations to estimate the volume V of a strong base or a strong acid (Vb and Va, resp. being added to a solution of a substance or a mix of substances during an acid-base titration, as well as the equations to estimate the first derivative of the titration plot dpH/dV, and algebraic expressions to determine the buffer β capacity with dilution βdil. This treatment allows establishing the conditions of thermodynamic equilibria for all species within a system containing a mix of species from one or from various polyacid systems. The present work shows that it is possible to determine exactly the electric conductivity of aqueous solutions for these Brønsted acid-base titrations, because the functional relation between this property and the composition of the system in equilibrium is well known; this is achieved using the equivalent conductivity λi values of each of the ions present in a given system. The model employed for the present work confirms the experimental outcomes with the H2SO4, B(OH3, CH3COOH, and H3PO4 aqueous solutions’ titration.

  10. Thermodynamic investigations of protein's behaviour with ionic liquids in aqueous medium studied by isothermal titration calorimetry.

    Science.gov (United States)

    Bharmoria, Pankaj; Kumar, Arvind

    2016-05-01

    While a number of reports appear on ionic liquids-proteins interactions, their thermodynamic behaviour using suitable technique like isothermal titration calorimetry is not systematically presented. Isothermal titration calorimetry (ITC) is a key technique which can directly measure the thermodynamic contribution of IL binding to protein, particularly the enthalpy, heat capacities and binding stoichiometry. Ionic liquids (ILs), owing to their unique and tunable physicochemical properties have been the central area of scientific research besides graphene in the last decade, and growing unabated. Their encounter with proteins in the biological system is inevitable considering their environmental discharge though most of them are recyclable for a number of cycles. In this article we will cover the thermodynamics of proteins upon interaction with ILs as osmolyte and surfactant. The up to date literature survey of IL-protein interactions using isothermal titration calorimetry will be discussed and parallel comparison with the results obtained for such studies with other techniques will be highlighted to demonstrate the accuracy of ITC technique. Net stability of proteins can be obtained from the difference in the free energy (ΔG) of the native (folded) and denatured (unfolded) state using the Gibbs-Helmholtz equation (ΔG=ΔH-TΔS). Isothermal titration calorimetry can directly measure the heat changes upon IL-protein interactions. Calculation of other thermodynamic parameters such as entropy, binding constant and free energy depends upon the proper fitting of the binding isotherms using various fitting models. Copyright © 2015 Elsevier B.V. All rights reserved.

  11. Triangular osteosynthesis and iliosacral screw fixation for unstable sacral fractures: a cadaveric and biomechanical evaluation under cyclic loads.

    Science.gov (United States)

    Schildhauer, Thomas A; Ledoux, William R; Chapman, Jens R; Henley, M Bradford; Tencer, Allan F; Routt, M L Chip

    2003-01-01

    To conduct a biomechanical comparison of a new triangular osteosynthesis and the standard iliosacral screw osteosynthesis for unstable transforaminal sacral fractures in the immediate postoperative situation as well as in the early postoperative weight-bearing period. Twelve preserved human cadaveric lumbopelvic specimens were cyclicly tested in a single-limb-stance model. A transforaminal sacral fracture combined with ipsilateral superior and inferior pubic rami fractures were created and stabilized. Loads simulating muscle forces and body weight were applied. Fracture site displacement in three dimensions was evaluated using an electromagnetic motion sensor system. Specimens were randomly assigned to either an iliosacral and superior pubic ramus screw fixation or to a triangular osteosynthesis consisting of lumbopelvic stabilization (between L5 pedicle and posterior ilium) combined with iliosacral and superior pubic ramus screw fixation. Peak loaded displacement at the fracture site was measured for assessment of initial stability. Macroscopic fracture behavior through 10,000 cycles of loading, simulating the early postoperative weight-bearing period, was classified into type 1 with minimal motion at the fracture site, type 2 with complete displacement of the inferior pubic ramus, or type 3 with catastrophic failure. The triangular osteosynthesis had a statistically significantly smaller displacement under initial peak loads (mean +/- standard deviation [SD], 0.163 +/- 0.073 cm) and therefore greater initial stability than specimens with the standard iliosacral screw fixation (mean +/- SD, 0.611 +/- 0.453 cm) ( = 0.0104), independent of specimen age or sex. All specimens with the triangular osteosynthesis demonstrated type 1 fracture behavior, whereas iliosacral screw fixation resulted in one type 1, two type 2, and three type 3 fracture behaviors before or at 10,000 cycles of loading. Triangular osteosynthesis for unstable transforaminal sacral fractures

  12. Metode Pemrograman Linier Deng-feng Li untuk Menyelesaikan Masalah Teori Permainan dengan Matriks Pembayaran Bilangan Triangular Fuzzy

    OpenAIRE

    Triyuliyanti, Armydia

    2017-01-01

    . Game theory is a branch of mathematics that used to make some decisions in the competitive situations with goal to have an optimal profit. Game theory of matrix payoffs with parameters triangular fuzzy number called matrix games with payoffs of triangular fuzzy numbers. Resolving game theory problem with triangular fuzzy numbers must be converted before hand in the from of matrix game with payoffs of triangular fuzzy numbers. In this paper, we explain that this two person zero sum game mixe...

  13. A dipstick sensor for coulometric acid-base titrations

    OpenAIRE

    Olthuis, Wouter; van der Schoot, B.H.; Chavez, F.; Bergveld, Piet

    1989-01-01

    By performing an acid-base titration by coulometric generation of OH− or H+ ions at an inert electrode in close proximity to the pH-sensitive gate of an ISFET, it is possible to determine the acid or base concentration of a solution using the ISFET as an indicator device for the equivalence point in the titration curve. Typical values for the titration time are 0.1 to 10 s for acid or base concentrations ranging from 0.5 × 10−3 to 10 × 10−3 mol/l. By placing the counter electrode for the supp...

  14. The fluorimetric titration of zirconium in the ppm-range

    International Nuclear Information System (INIS)

    Linden, W.E. von der; Boef, G. den; Ozinga, W.

    1976-01-01

    A fluorimetric titration of zirconium(IV) with EDTA is proposed. The fluorescence intensity of the zirconium-morin complex is used to indicate the end-point. More than twenty other cations were investigated and it was found that they did not interfere, neither did common anions. Mercury(II) can only be tolerated in amount not exceeding that of zirconium. Bismuth(III) interferes and hafnium(IV0 is titrated together with zirconium. The relative standard deviation of the titration of 10ml of a solution containing 1 ppm of zirconium does not exceed 1.5%

  15. Determination of boron as boric acid by automatic potentiometric titration

    International Nuclear Information System (INIS)

    Midgley, D.

    1988-06-01

    Boron in PWR primary coolant and related waters may be determined as boric acid by titration with sodium hydroxide, using a glass electrode as a pH indicator. With a modern automatic titrator, the analysis is quick, convenient, accurate and precise. In the titration of 8 mg B (e.g. 4 ml of 2000 mg 1 -1 solution), no significant bias was observed and relative standard deviations were about 0.25%. With 0.8 g B, a bias of about 2% appears, although this could be reduced by restandardizing the titrant, but the relative standard deviation was still -1 B, depending on the stage of the fuel cycle. (author)

  16. A Generalization of the Formula for the Triangular Number of the Sum and Product of Natural Numbers

    Science.gov (United States)

    Asiru, M. A.

    2008-01-01

    This note generalizes the formula for the triangular number of the sum and product of two natural numbers to similar results for the triangular number of the sum and product of "r" natural numbers. The formula is applied to derive formula for the sum of an odd and an even number of consecutive triangular numbers.

  17. Spectrophotometric titration of sulfates in the presence of zirconium

    International Nuclear Information System (INIS)

    Kuznetsov, V.V.; Kotova, S.S.; Molokanova, L.G.; Chekmarev, A.M.; Yagodin, G.A.

    1978-01-01

    The procedure has been proposed for express determination of sulphate ions in the presence of zirconium by spectrophotometric titration with the use of barium chloride and nitrochromazo as an indicator. The procedure is based on bonding zirconium into a more stable complex with EDTA (ethylenediaminotetraacetic acid). The presence of excess of EDTA and zirconium (4) complexonate in the solution being titrated does not affect the titration curve shape and the character of break on the curve in the equivalence point. A complete demasking of SO 4 2- is observed in the case of 1O-fold excess of EDTA with respect to zirconium (4). Statistic evaluation of the method has shown that the results of titration can be distorted by chance errors only

  18. Coulometric titration of niobium in 1F sulfuric acid

    International Nuclear Information System (INIS)

    Pannu, S.S.

    1975-01-01

    A coulometric titration at constant current has been devised for Nb in 1F sulfuric acid. The titration was based on the oxidation of Nb(III) to Nb(V) by Fe(III) electrogenerated at a graphite anode. Both potentiometric and amperometric end points were used. The Nb(V) was prior reduced at a mercury cathode by exhaustive electrolysis at a current density of 15 ma/mc 2 for at least 10 hr. Ta,V,Ti and a working platinum anode interfered, but the separation of the potentials of Nb(V)/Nb(III) and Ti(IV)/Ti(III) permitted the titration of first Nb and then Ti. The average error for the titration of 0.30 to 13.00 mg of niobium in 100 ml of 1F sulfuric acid was + 0.57%. (author)

  19. Coulometric titration of niobium in EDTA complexing solution

    International Nuclear Information System (INIS)

    Pannu, S.S.

    1976-01-01

    Constant current coulometry of Nb in EDTA was studied employing both potentiometric and amperometric end-point techniques. The titrations were based on the oxidation of Nb(IV)-EDTA with electrogenerated Fe(III) at a graphite anode. The rate of disproportionation of Nb(IV)-EDTA was found to be slow enough not to effect the accuracy sought for the titration. The coulometric titration of Nb in EDTA was found to be more accurate than in 1F sulfuric acid. The mean error in the titrations of 4.76 to 19.65 of Nb in a volume of about 100 ml of 0.02 to 0.04F EDTA was 0.13%. It was found that Ta may be tolerated to a ratio of 1:4, Ta:Nb, in a solution containing 13 mg of Nb. (author)

  20. Potentiometric titration of free acid in uranium solutions

    Energy Technology Data Exchange (ETDEWEB)

    Suh, M. Y.; Kim, W. H.; Kim, J. S.; Sohn, S. C.; Eom, T. Y.; Lee, C. H.; Jeon, Y. S.; Han, S. H.

    1998-02-01

    Hydrolysis properties of metal cations and fundamental principles of the potentiometric titration of free acid in aqueous solutions containing metal cations were described. The published papers and reports for the alkalimetric and acidimetric titration of free acid were surveyed, and the applicability of these titration methods to the uranium and/or plutonium solutions were discussed. This technical report also includes the various results obtained from the authors` researches to establish the alkalimetric and acidimetric titration methods for the determination of free acid in nitric acid solutions containing uranium and/or oxalic acid, and aluminum. The procedure manuals used in chemical processes and the newly prepared manuals based on the authors` researches are appended. (author). 26 refs., 54 figs.

  1. Microscope Titration and Extraction of DNA from Liver.

    Science.gov (United States)

    Mayo, Lois T.; And Others

    1993-01-01

    Describes a simple and inexpensive, one-period activity to extract DNA to make the study of DNA less abstract. A microscope titration is used to determine when cells are ready for DNA extraction. (PR)

  2. A microcomputer-controlled system for titration analysis

    NARCIS (Netherlands)

    Boelema, Gerrit Jan

    1982-01-01

    This thesis deals with the results of the implementation of microprocessor technology in automatic titration equipment to obtain a versatile system for pharmaceutical, chemical analytical and optimization research purposes. ... Zie: Summary

  3. Analysis of the Purity of Cetrimide by Titrations

    DEFF Research Database (Denmark)

    Andersen, Jens Enevold Thaulov; Rasmussen, Claus/Dallerup; Nielsen, Hans/Boye

    2006-01-01

    The purity of cetrimide, trimethyl tetradecyl ammonium bromide (TTAB), that is an important preservative of many cosmetic and pharmaceutical products, was determined by three independent methods of titration. Traditionally, cetrimide was analysed by an assay method of the European Pharmacopoeia (Ph....... Eur.), which showed consistently a low purity of cetrimide with large standard deviations associated, however. A systematic 3% bias of the Ph. Eur. assay method was identified by comparing the result with results of two alternative methods of titration that exhibited high precision and high accuracy....... Titration by perchloric acid showed a 99.69 ± 0.05 % purity of cetrimide and titration by silver nitrate showed a 99.85% ± 0.05 % purity while the traditional assay method predicted a purity of only 97.1 ± 0.4. It was found that the discrepancy could be identified as differences in selectivity during...

  4. Plutonium volumetric titration after reduction on a Jones' column

    International Nuclear Information System (INIS)

    Description of a plutonium analysis method, in hydrochloric or sulfuric solution, for plutonium content over 2 mg, by reduction from plutonium IV to plutonium III in a Jones' column. Volumetic titration by ceric sulfate with ferrous orthophenanthroline [fr

  5. Preparation of triangular and hexagonal silver nanoplates on the surface of quartz substrate

    International Nuclear Information System (INIS)

    Jia Huiying; Zeng Jianbo; An Jing; Song Wei; Xu Weiqing; Zhao Bing

    2008-01-01

    In this paper, triangular and hexagonal silver nanoplates were prepared on the surface of quartz substrate using photoreduction of silver ions in the presence of silver seeds. The obtained silver nanoplates were characterized by atomic force microscopy and UV-vis spectroscopy. It was found that the silver seeds played an important role in the formation of triangular and hexagonal silver nanoplates. By varying the irradiation time, nanoplates with different sizes and shapes could be obtained. The growth mechanism for triangular and hexagonal nanoplates prepared on quartz substrate was discussed

  6. Facile synthesis of microporous SiO2/triangular Ag composite nanostructures for photocatalysis

    Science.gov (United States)

    Sirohi, Sidhharth; Singh, Anandpreet; Dagar, Chakit; Saini, Gajender; Pani, Balaram; Nain, Ratyakshi

    2017-11-01

    In this article, we present a novel fabrication of microporous SiO2/triangular Ag nanoparticles for dye (methylene blue) adsorption and plasmon-mediated degradation. Microporous SiO2 nanoparticles with pore size green 26 and curcumin crystalline. Amine-functionalized microporous SiO2/triangular Ag nanostructures were used for plasmon-mediated photocatalysis of methylene blue. The experimental results revealed that the large surface area of microporous silica facilitated adsorption of dye. Triangular Ag nanoparticles, due to their better charge carrier generation and enhanced surface plasmon resonance, further enhanced the photocatalysis performance.

  7. Well-balanced positivity preserving central-upwind scheme on triangular grids for the Saint-Venant system

    KAUST Repository

    Bryson, Steve

    2010-10-11

    We introduce a new second-order central-upwind scheme for the Saint-Venant system of shallow water equations on triangular grids. We prove that the scheme both preserves "lake at rest" steady states and guarantees the positivity of the computed fluid depth. Moreover, it can be applied to models with discontinuous bottom topography and irregular channel widths. We demonstrate these features of the new scheme, as well as its high resolution and robustness in a number of numerical examples. © EDP Sciences, SMAI, 2010.

  8. Dissociation of weak acids during Gran plot free acidity titrations

    OpenAIRE

    Lindberg, Steven E:; Cole, Jan M.

    2011-01-01

    A comparison of weak and free acid concentrations measured by base titration and hydrogen ionactivities determined by direct pH measurement is described for several of our data sets for raincollected above and below a forest canopy in the eastern United States. These data illustrate theinfluence of weak acid dissociation during titration and the possible effect of activity coefficientson calculated free acid concentrations.DOI: 10.1111/j.1600-0889.1984.tb00240.x

  9. Amperometric titration of indium with edta solution in propanol

    International Nuclear Information System (INIS)

    Gevorgyan, A.M.; Talipov, Sh.T.; Khadeev, V.A.; Kostylev, V.S.; Khadeeva, L.A.

    1980-01-01

    Optimum conditions have been chosen for titration of indium with EDTA solution in anhydrous propanol and its mixtures with some aprotic solvents using amperometric and point detection. A procedure is suggested of determining indium microcontents in the presence of large amounts of other elements. The procedure is based on its extraction preseparation followed by direct titration in the extract with a standard EDTA solution [ru

  10. Carbon dioxide titration method for soil respiration measurements

    OpenAIRE

    Martín Rubio, Luis

    2017-01-01

    This thesis was commissioned by Tampere University of Applied Sciences, which was interested in studying and developing a titration measurement method for soil respiration and biodegradability. Some experiments were carried out measuring soil respiration for testing the method and others adding some biodegradable material like polylactic acid compressed material and 100% biodegradable plastic bags to test its biodegradability and the possibility to measure it via titration. The thesi...

  11. Potentiometric and coulometric titration of 2-thiobarbituric acid.

    Science.gov (United States)

    Ciesielski, W; Kowalska, J; Zakrzewski, R

    1995-05-01

    A new method for the determination of 2-thiobarbituric acid, using its reaction with iodine in an alkaline medium is presented. In the volumetric titration with potentiometric end-point detection, the determinability range is 10-400 micromol (1.4-58 mg). In coulometric titration using the biamperometric end-point detection, 0.1-20 micromol (1.4 x 10(-2)-2.9 mg) of 2-thiobarbituric acid was successfully determined.

  12. Evidence for triangular D3h symmetry in 12C.

    Science.gov (United States)

    Marín-Lámbarri, D J; Bijker, R; Freer, M; Gai, M; Kokalova, Tz; Parker, D J; Wheldon, C

    2014-07-04

    We report a measurement of a new high spin Jπ=5- state at 22.4(2) MeV in 12C which fits very well to the predicted (ground state) rotational band of an oblate equilateral triangular spinning top with a D3h symmetry characterized by the sequence 0+, 2+, 3-, 4±, 5- with almost degenerate 4+ and 4- (parity doublet) states. Such a D3h symmetry was observed in triatomic molecules, and it is observed here for the first time in nuclear physics. We discuss a classification of other rotation-vibration bands in 12C such as the (0+) Hoyle band and the (1-) bending mode band and suggest measurements in search of the predicted ("missing") states that may shed new light on clustering in 12C and light nuclei. In particular, the observation (or nonobservation) of the predicted ("missing") states in the Hoyle band will allow us to conclude the geometrical arrangement of the three alpha particles composing the Hoyle state at 7.654 MeV in 12C.

  13. Evidence for Triangular D3h Symmetry in C12

    Science.gov (United States)

    Marín-Lámbarri, D. J.; Bijker, R.; Freer, M.; Gai, M.; Kokalova, Tz.; Parker, D. J.; Wheldon, C.

    2014-07-01

    We report a measurement of a new high spin Jπ=5- state at 22.4(2) MeV in C12 which fits very well to the predicted (ground state) rotational band of an oblate equilateral triangular spinning top with a D3h symmetry characterized by the sequence 0+, 2+, 3-, 4±, 5- with almost degenerate 4+ and 4- (parity doublet) states. Such a D3h symmetry was observed in triatomic molecules, and it is observed here for the first time in nuclear physics. We discuss a classification of other rotation-vibration bands in C12 such as the (0+) Hoyle band and the (1-) bending mode band and suggest measurements in search of the predicted ("missing") states that may shed new light on clustering in C12 and light nuclei. In particular, the observation (or nonobservation) of the predicted ("missing") states in the Hoyle band will allow us to conclude the geometrical arrangement of the three alpha particles composing the Hoyle state at 7.654 MeV in C12.

  14. Single Null Negative Triangularity Tokamak for Power Handling

    Science.gov (United States)

    Kikuchi, Mitsuru; Medvedev, S.; Takizuka, T.; Sauter, O.; Merle, A.; Coda, S.; Chen, D.; Li, J. X.

    2017-10-01

    Power and particle control in fusion reactor is challenge and we proposed the negative triangularity tokamak (NTT) to eliminate ELM by operating L-mode edge with improved core confinement. The SN configuration has more flexibility in shaping by adopting rectangular-shaped TF coils. The limiting normalized beta is 3.56 with wall stabilization and 3.14 without wall. The vertical stability is assured under a reasonable control system. The wetted area on the divertor plates becomes wider in proportion to the larger major radius at the divertor strike points due to the NT configuration. In addition to the major-radius effect, the ``Flux Tune Expansion (FTE)'' is adopted to further reduce the heat load on the divertor plate by factor of 2.6 with a coil current 3 MA. L-mode edge also allows further increase in wetted area. The fusion power of 3 GW is deliverable only at normalized beta 2.1. Therefore this reactor may be operable stably against the serious MHD activities. The CD power for SS operation is 175 MW at Q = 17. AC operation is also possible option. A required HH factor is relatively modest H = 1.12.

  15. Low-Reynolds number compressible flow around a triangular airfoil

    Science.gov (United States)

    Munday, Phillip; Taira, Kunihiko; Suwa, Tetsuya; Numata, Daiju; Asai, Keisuke

    2013-11-01

    We report on the combined numerical and experimental effort to analyze the nonlinear aerodynamics of a triangular airfoil in low-Reynolds number compressible flow that is representative of wings on future Martian air vehicles. The flow field around this airfoil is examined for a wide range of angles of attack and Mach numbers with three-dimensional direct numerical simulations at Re = 3000 . Companion experiments are conducted in a unique Martian wind tunnel that is placed in a vacuum chamber to simulate the Martian atmosphere. Computational findings are compared with pressure sensitive paint and direct force measurements and are found to be in agreement. The separated flow from the leading edge is found to form a large leading-edge vortex that sits directly above the apex of the airfoil and provides enhanced lift at post stall angles of attack. For higher subsonic flows, the vortical structures elongate in the streamwise direction resulting in reduced lift enhancement. We also observe that the onset of spanwise instability for higher angles of attack is delayed at lower Mach numbers. Currently at Mitsubishi Heavy Industries, Ltd., Nagasaki.

  16. Bose-Einstein condensation in a frustrated triangular optical lattice

    Science.gov (United States)

    Janzen, Peter; Huang, Wen-Min; Mathey, L.

    2016-12-01

    The recent experimental condensation of ultracold atoms in a triangular optical lattice with a negative effective tunneling parameter paves the way for the study of frustrated systems in a controlled environment. Here, we explore the critical behavior of the chiral phase transition in such a frustrated lattice in three dimensions. We represent the low-energy action of the lattice system as a two-component Bose gas corresponding to the two minima of the dispersion. The contact repulsion between the bosons separates into intra- and intercomponent interactions, referred to as V0 and V12, respectively. We first employ a Huang-Yang-Luttinger approximation of the free energy. For V12/V0=2 , which corresponds to the bare interaction, this approach suggests a first-order phase transition, at which both the U (1 ) symmetry of condensation and the Z2 symmetry of the emergent chiral order are broken simultaneously. Furthermore, we perform a renormalization-group calculation at one-loop order. We demonstrate that the coupling regime 0 1 we show that V0 flows to a negative value, while V12 increases and remains positive. This results in a breakdown of the effective quartic-field theory due to a cubic anisotropy and, again, suggests a discontinuous phase transition.

  17. Energy spectrums of bilayer triangular phosphorene quantum dots and antidots

    Directory of Open Access Journals (Sweden)

    Z. T. Jiang

    2017-04-01

    Full Text Available We theoretically investigate the confined states of the bilayer triangular phosphorene dots and antidots by means of the tight-binding approach. The dependence of the energy levels on the size, the type of the boundary edges, and the orientation of the dots and antidots, and the influences of the electric and magnetic fields on the energy levels, are all completely analyzed. It is found that the energy level numbers of the bilayer dots and antidots are determined by the energy levels in two layers. The external electric field can effectively tune the energy levels of the edge states in both layers to move in opposite directions. With the increase of the magnetic field, the magnetic energy levels can approach the Landau levels of the phosphorene monolayer, the phosphorene bilayer, or both, depending on the specific geometry of the monolayer-bilayer hybrid phosphorene quantum dots. This research should be helpful for the overall understanding of the electronic properties of the multilayer hybrid phosphorene nanostructures and designing the corresponding phosphorene devices.

  18. Thermal Deformation of Very Slender Triangular Rollable and Collapsible Booms

    Science.gov (United States)

    Stohlman, Olive R.; Loper, Erik R.

    2016-01-01

    Metallic triangular rollable and collapsible (TRAC) booms have deployed two Cubesat-based solar sails in low Earth orbit, making TRAC booms the most popular solar sail deployment method in practice. This paper presents some concerns and solutions surrounding the behavior of these booms in the space thermal environment. A 3.5-cm-tall, 4-meter-long TRAC boom of Elgiloy cobalt alloy, when exposed to direct sunlight in a 1 AU deep space environment, has a predicted tip motion of as much as 0.5 meters. Such large thermal deflections could generate unacceptable distortions in the shape of a supported solar sail, making attitude control of the solar sail spacecraft difficult or impossible. As a possible means of mitigating this issue, the thermal distortion behaviors of three alternative material TRAC booms are investigated and compared with the uncoated Elgiloy baseline boom. A tenfold decrease in induced curvature is shown to be possible relative to the baseline boom. Potential thermal distortions of the LightSail-A solar sail TRAC booms are also examined and compared, although inconclusively, with available on-orbit camera imagery.

  19. Gran method for end point anticipation in monosegmented flow titration

    Directory of Open Access Journals (Sweden)

    Aquino Emerson V

    2004-01-01

    Full Text Available An automatic potentiometric monosegmented flow titration procedure based on Gran linearisation approach has been developed. The controlling program can estimate the end point of the titration after the addition of three or four aliquots of titrant. Alternatively, the end point can be determined by the second derivative procedure. In this case, additional volumes of titrant are added until the vicinity of the end point and three points before and after the stoichiometric point are used for end point calculation. The performance of the system was assessed by the determination of chloride in isotonic beverages and parenteral solutions. The system employs a tubular Ag2S/AgCl indicator electrode. A typical titration, performed according to the IUPAC definition, requires only 60 mL of sample and about the same volume of titrant (AgNO3 solution. A complete titration can be carried out in 1 - 5 min. The accuracy and precision (relative standard deviation of ten replicates are 2% and 1% for the Gran and 1% and 0.5% for the Gran/derivative end point determination procedures, respectively. The proposed system reduces the time to perform a titration, ensuring low sample and reagent consumption, and full automatic sampling and titrant addition in a calibration-free titration protocol.

  20. Quantitative determination of acidic groups in functionalized graphene by direct titration

    Czech Academy of Sciences Publication Activity Database

    Ederer, J.; Janoš, P.; Ecorchard, Petra; Štengl, Václav; Bělčická, Zuzana; Šťastný, Martin; Pop-Georgievski, Ognen; Dohnal, V.

    2016-01-01

    Roč. 103, JUN (2016), s. 44-53 ISSN 1381-5148 R&D Projects: GA ČR(CZ) GA14-05146S Institutional support: RVO:61388980 ; RVO:61389013 Keywords : Acid-base titration * Carboxylic functional groups * Graphene oxide * Phenolic functional groups * Proton-binding model Subject RIV: CA - Inorganic Chemistry; CD - Macromolecular Chemistry (UMCH-V) Impact factor: 3.151, year: 2016

  1. A dual triangular pyramidal indentation technique based on FEA solutions for Material property evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Minsoo; Hyun, Hong Chul [Sogana Univ., Seoul (Korea, Republic of); Lee, Jin Haeng; Lee, Hyungyil [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2012-01-15

    In this study, we suggest a method for material property evaluation by dual triangular pyramidal indenters using the reverse analysis. First, we demonstrated that load displacement curves of conical and triangular pyramidal indenters are different for the same material. For this reason, an independent research on the triangular pyramidal indenter is needed. From FE indentation analyses on various materials, we then investigated the relationships among material properties, indentation parameters and load displacement curves. From this, we established property evaluation formula using dual triangular pyramidal indenters having two different half included angles. The approach provides the values of elastic modulus, yield strength and strain hardening exponent within an average error of 3% for various materials.

  2. The calculation of QCD triangular Feynman graphs in external gluonic field using the Reduce-2 system

    International Nuclear Information System (INIS)

    Dulyan, L.S.

    1986-01-01

    Methods and ways applied in the calculation of the QCD triangular Feynman diagrams with the use of the REDUCE-2 system are described. The encountered difficulties connected with the specific features of the REDUCE-2 system are discussed

  3. RAPID COMMUNICATION: Vibration immunity and Ampere's circuital law for a near perfect triangular Faraday current sensor

    Science.gov (United States)

    Fisher, N. E.; Jackson, D. A.

    1996-08-01

    We report a common-mode rejection scheme for a bulk-optic triangular Faraday current sensor that can eliminate optical noise induced by fibre-link vibration. The sensor's exploitation of Ampere's circuital law is also demonstrated.

  4. Reconstruction of the lateral tibia plateau fracture with a third triangular support screw: A biomechanical study

    Directory of Open Access Journals (Sweden)

    Eduardo Moran

    2017-10-01

    Conclusion: Triangular support fixation enhanced interfragmentary stability at the ultimate stage of dynamic loading. However, the level of improvement seems to be limited and may not legitimate the intervention with an additional third screw.

  5. Multiple Fano-Like MIM Plasmonic Structure Based on Triangular Resonator for Refractive Index Sensing

    OpenAIRE

    Jankovic, Nikolina; Cselyuszka, Norbert

    2018-01-01

    In this paper, we present a Fano metal-insulator-metal (MIM) structure based on an isosceles triangular cavity resonator for refractive index sensing applications. Due to the specific feeding scheme and asymmetry introduced in the triangular cavity, the resonator exhibits four sharp Fano-like resonances. The behavior of the structure is analyzed in detail and its sensing capabilities demonstrated through the responses for various refractive indices. The results show that the sensor has very g...

  6. Analytical solution to problems of hydraulic jump in horizontal triangular channels

    OpenAIRE

    I.M.H. Rashwan

    2013-01-01

    A hydraulic jump is formed in a channel whenever supercritical flow changes to subcritical flow in a short distance. It can be used in triangular ditch irrigation to raise the downstream water surface. The basic elements and characteristics of the hydraulic jump are provided to aid designers in selecting more practical basins. In the present study, the slope side, discharge and the energy loss in hydraulic jump in horizontal triangular section are known whereas one has to obtain the sequent d...

  7. Unitary Root Music and Unitary Music with Real-Valued Rank Revealing Triangular Factorization

    Science.gov (United States)

    2010-06-01

    AFRL-RY-WP-TP-2010-1213 UNITARY ROOT MUSIC AND UNITARY MUSIC WITH REAL-VALUED RANK REVEALING TRIANGULAR FACTORIZATION (Postprint) Nizar...DATES COVERED (From - To) June 2010 Journal Article Postprint 08 September 2006 – 31 August 2009 4. TITLE AND SUBTITLE UNITARY ROOT MUSIC AND...UNITARY MUSIC WITH REAL-VALUED RANK REVEALING TRIANGULAR FACTORIZATION (Postprint) 5a. CONTRACT NUMBER 5b. GRANT NUMBER FA8650-05-D-1912-0007 5c

  8. TLC scheme for numerical solution of the transport equation on equilateral triangular meshes

    International Nuclear Information System (INIS)

    Walters, W.F.

    1983-01-01

    A new triangular linear characteristic TLC scheme for numerically solving the transport equation on equilateral triangular meshes has been developed. This scheme uses the analytic solution of the transport equation in the triangle as its basis. The data on edges of the triangle are assumed linear as is the source representation. A characteristic approach or nodal approach is used to obtain the analytic solution. Test problems indicate that the new TLC is superior to the widely used DITRI scheme for accuracy

  9. Elemental matrices for the finite element method in electromagnetics with quadratic triangular elements

    OpenAIRE

    Cojocaru, E.

    2009-01-01

    The finite element method has become a preeminent simulation technique in electromagnetics. For problems involving anisotropic media and metamaterials, proper algorithms should be developed. It has been proved that discretizing in quadratic triangular elements may lead to an improved accuracy. Here we present a collection of elemental matrices evaluated analytically for quadratic triangular elements. They could be useful for the finite element method in advanced electromagnetics.

  10. Coupling-governed metamorphoses of the integrable nonlinear Schrödinger system on a triangular-lattice ribbon

    Energy Technology Data Exchange (ETDEWEB)

    Vakhnenko, Oleksiy O., E-mail: vakhnenko@bitp.kiev.ua

    2016-05-27

    Highlights: • The integrable nonlinear Schrödinger system on a triangular-lattice ribbon is inclined to metamorphoses. • The system under study is capable to incorporate the effect of external linear potential. • The system criticality against the background parameter reduces the number of independent field variables. • At critical point the system Poisson structure becomes degenerate. • The effect of criticality is elucidated by the system one-soliton solution. - Abstract: The variativity of governing coupling parameters in the integrable nonlinear Schrödinger system on a triangular-lattice ribbon is shown to ensure the important qualitative rearrangements in the system dynamics. There are at least the two types of system crucial modifications stipulated by the two types of governing parameters. Thus the longitudinal coupling parameters regulated mainly by the background values of concomitant field variables are responsible for the bifurcation of primary integrable nonlinear system into the integrable nonlinear system of Ablowitz–Ladik type. As a consequence in a critical point the number of independent field variables is reduced by a half and the system Poisson structure turns out to be degenerate. On the other hand the transverse coupling parameters regulated basically by the choice of their a priori arbitrary dependencies on time are capable to incorporate the effect of external linear potential. As a consequence the primary integrable nonlinear system with appropriately adjusted parametrical driving becomes isomorphic to the system modeling the Bloch oscillations of charged nonlinear carriers in an electrically biased ribbon of triangular lattice. The multi-component structure of basic integrable system alongside with the attractive character of system nonlinearities has predetermined the logic of whole consideration.

  11. Marginally Stable Triangular Recurrent Neural Network Architecture for Time Series Prediction.

    Science.gov (United States)

    Sivakumar, Seshadri; Sivakumar, Shyamala

    2017-09-25

    This paper introduces a discrete-time recurrent neural network architecture using triangular feedback weight matrices that allows a simplified approach to ensuring network and training stability. The triangular structure of the weight matrices is exploited to readily ensure that the eigenvalues of the feedback weight matrix represented by the block diagonal elements lie on the unit circle in the complex z-plane by updating these weights based on the differential of the angular error variable. Such placement of the eigenvalues together with the extended close interaction between state variables facilitated by the nondiagonal triangular elements, enhances the learning ability of the proposed architecture. Simulation results show that the proposed architecture is highly effective in time-series prediction tasks associated with nonlinear and chaotic dynamic systems with underlying oscillatory modes. This modular architecture with dual upper and lower triangular feedback weight matrices mimics fully recurrent network architectures, while maintaining learning stability with a simplified training process. While training, the block-diagonal weights (hence the eigenvalues) of the dual triangular matrices are constrained to the same values during weight updates aimed at minimizing the possibility of overfitting. The dual triangular architecture also exploits the benefit of parsing the input and selectively applying the parsed inputs to the two subnetworks to facilitate enhanced learning performance.

  12. Rapid clozapine titration in treatment-refractory bipolar disorder.

    Science.gov (United States)

    Ifteni, Petru; Correll, Christoph U; Nielsen, Jimmi; Burtea, Victoria; Kane, John M; Manu, Peter

    2014-09-01

    Clozapine is effective in treatment-refractory bipolar disorder (BD). Guidelines recommend slow titration to prevent seizures, hypotension and myocarditis, but this stance is not supported by comparative data. To evaluate the safety and effectiveness of rapid clozapine titration in BD. Analysis of a consecutive cohort of treatment-refractory BD patients with mixed/manic episode admitted on alternate days to one of two units of a psychiatric hospital. On one unit, clozapine was started at 25mg followed by 25-50mg as needed every 6h (maximum=100mg/day) on day 1, followed by increases of 25-100mg/day. On the other unit, clozapine was initiated with 25mg in day 1, followed by increases of 25-50mg/day. The primary outcome was the number of days from starting clozapine until readiness for discharge, adjusted in logistic regression for the number of antipsychotics tried during the hospitalization, psychotropic co-treatments and presence of psychotic features. Patients subject to rapid (N=44) and standard (N=23) titration were similar in age, gender, smoking status, body mass index, illness severity at baseline and discharge, and highest clozapine dose. Clozapine was discontinued due to hypotension (N=1) and pneumonia (N=1) during rapid titration, and for excessive sedation (N=1) in each titration group. The number of hospital days from starting clozapine until readiness for discharge was 3.8 days shorter in the rapid titration group (12.7±6.3 vs. 16.5±5.8, p=0.0077). Rapid clozapine titration appeared safe and effective for treatment-refractory BD. The potential for shorter hospital stays justifies prospective trials of this method. Copyright © 2014 Elsevier B.V. All rights reserved.

  13. Design and motion analysis of a novel coupled mechanism based on a regular triangular bipyramid

    Directory of Open Access Journals (Sweden)

    Huifang Gao

    2016-11-01

    Full Text Available Traditional methods and theories on synthesizing parallel mechanisms are not applicable to related researches on hybrid mechanisms, thus hampering the design of innovative coupled mechanisms. Polyhedrons with attractive appearance and particular geometrical construction provide many choices for coupled inventions. A novel mechanism with one translational degree of freedom based on a regular triangular bipyramid is proposed in this article. First, the basic equivalent geometrical model is spliced with new-designed components substituting for vertexes and edges by revolution joints (R-pairs only. The expected motion for the basic coupled model can be achieved by adding links to modify the constraint sets and arrange spatial allocation of an elementary loop based on the screw theory. Then, the mobility of one branch is calculated to investigate the movability of the novel structure, and a Denavit–Hartenberg (D-H model with properties of symmetry is implemented to investigate the inverse kinematic analysis. Furthermore, a numerical example is given to verify the correctness of analysis results and related motion simulation is conducted to illustrate the potential application of the proposed novel system as an executing manipulator for mobile robots.

  14. Predicting proton titration in cationic micelle and bilayer environments

    Science.gov (United States)

    Morrow, Brian H.; Eike, David M.; Murch, Bruce P.; Koenig, Peter H.; Shen, Jana K.

    2014-08-01

    Knowledge of the protonation behavior of pH-sensitive molecules in micelles and bilayers has significant implications in consumer product development and biomedical applications. However, the calculation of pKa's in such environments proves challenging using traditional structure-based calculations. Here we apply all-atom constant pH molecular dynamics with explicit ions and titratable water to calculate the pKa of a fatty acid molecule in a micelle of dodecyl trimethylammonium chloride and liquid as well as gel-phase bilayers of diethyl ester dimethylammonium chloride. Interestingly, the pKa of the fatty acid in the gel bilayer is 5.4, 0.4 units lower than that in the analogous liquid bilayer or micelle, despite the fact that the protonated carboxylic group is significantly more desolvated in the gel bilayer. This work illustrates the capability of all-atom constant pH molecular dynamics in capturing the delicate balance in the free energies of desolvation and Coulombic interactions. It also shows the importance of the explicit treatment of ions in sampling the protonation states. The ability to model dynamics of pH-responsive substrates in a bilayer environment is useful for improving fabric care products as well as our understanding of the side effects of anti-inflammatory drugs.

  15. Impact of Uniform Methods on Interlaboratory Antibody Titration Variability: Antibody Titration and Uniform Methods.

    Science.gov (United States)

    Bachegowda, Lohith S; Cheng, Yan H; Long, Thomas; Shaz, Beth H

    2017-01-01

    -Substantial variability between different antibody titration methods prompted development and introduction of uniform methods in 2008. -To determine whether uniform methods consistently decrease interlaboratory variation in proficiency testing. -Proficiency testing data for antibody titration between 2009 and 2013 were obtained from the College of American Pathologists. Each laboratory was supplied plasma and red cells to determine anti-A and anti-D antibody titers by their standard method: gel or tube by uniform or other methods at different testing phases (immediate spin and/or room temperature [anti-A], and/or anti-human globulin [AHG: anti-A and anti-D]) with different additives. Interlaboratory variations were compared by analyzing the distribution of titer results by method and phase. -A median of 574 and 1100 responses were reported for anti-A and anti-D antibody titers, respectively, during a 5-year period. The 3 most frequent (median) methods performed for anti-A antibody were uniform tube room temperature (147.5; range, 119-159), uniform tube AHG (143.5; range, 134-150), and other tube AHG (97; range, 82-116); for anti-D antibody, the methods were other tube (451; range, 431-465), uniform tube (404; range, 382-462), and uniform gel (137; range, 121-153). Of the larger reported methods, uniform gel AHG phase for anti-A and anti-D antibodies had the most participants with the same result (mode). For anti-A antibody, 0 of 8 (uniform versus other tube room temperature) and 1 of 8 (uniform versus other tube AHG), and for anti-D antibody, 0 of 8 (uniform versus other tube) and 0 of 8 (uniform versus other gel) proficiency tests showed significant titer variability reduction. -Uniform methods harmonize laboratory techniques but rarely reduce interlaboratory titer variance in comparison with other methods.

  16. Interaction of diethyl aniline methylphosphonate with DNA: Spectroscopic and isothermal titration calorimetry

    International Nuclear Information System (INIS)

    Lu Yan; Xu Meihua; Wang Gongke; Zheng Yun

    2011-01-01

    In this study the diethyl aniline methylphosphonate (DAM) was synthesized, the interaction of DAM with ct-DNA has been investigated by fluorescence spectra, UV spectra, molecular modeling and isothermal titration calorimetry (ITC). The binding constant of DAM to ct-DNA calculated from both isothermal titration calorimetry and fluorescence spectra were found to be in the 10 4 M -1 range. According to the ethidium bromide displacement studies, UV spectra and isothermal titration calorimetry experimental results, it can be concluded that DAM is an intercalator that can slide into the G-C rich region of ct-DNA. Furthermore, the results obtained from molecular modeling corroborated the experimental results obtanied from spectroscopic and ITC investigations. At the same time, fluorescence spectra suggested that the mechanism of the interaction of DAM to ct-DNA was a static enhancing type. ITC data showed that ct-DNA/DAM binding is enthalpy controlled. - Research highlights: → The interaction of DAM with ct-DNA is a static enhancing type. → DAM can slide into the G-C rich region of ct-DNA. → The binding of DAM to ct-DNA is enthalpy controlled. → The hydrogen bonding forces play an essential role in the binding process.

  17. [Titration comparative study of TOPINA Tablets in patients with localization related epilepsy: double-blind comparative study by rapid and slow titration methods].

    Science.gov (United States)

    Kaneko, Sunao; Inoue, Yushi; Sasagawa, Mutsuo; Kato, Masaaki

    2012-04-01

    To compare the tolerability and efficacy of two titration methods (rapid and slow titration) for TOPINA Tablets with different dosages and periods of escalation, a double-blind comparative study was conducted in patients with localization-related epilepsy. A total of 183 patients were randomized to either rapid titration (initial dosage 100 mg/day increased by 100-200 mg at weekly intervals) or to slow titration (initial dosage 50 mg/day increased in 50 mg/day increments at weekly intervals). TOPINA Tablets were administered for 12 weeks to the maximum dosage of 400 mg/day. The incident of adverse events leading to treatment interruptions or withdrawals was 18.9% in rapid titration and 14.8% in slow titration, with no statistical significance (p = 0.554). The incident of adverse events and adverse reactions of slow titration was slightly lower than that of rapid titration. The common adverse events and adverse reactions reported in the two titration methods were comparable and were well tolerated. On the other hand, the efficacy of slow titration, percent reduction in seizure rate and responder rate, was comparable with that of rapid titration. In conclusion, there were no significant differences of therapeutic response to TOPINA Tablets between the two titration methods.

  18. Potentiometric titration and equivalent weight of humic acid

    Science.gov (United States)

    Pommer, A.M.; Breger, I.A.

    1960-01-01

    The "acid nature" of humic acid has been controversial for many years. Some investigators claim that humic acid is a true weak acid, while others feel that its behaviour during potentiometric titration can be accounted for by colloidal adsorption of hydrogen ions. The acid character of humic acid has been reinvestigated using newly-derived relationships for the titration of weak acids with strong base. Re-interpreting the potentiometric titration data published by Thiele and Kettner in 1953, it was found that Merck humic acid behaves as a weak polyelectrolytic acid having an equivalent weight of 150, a pKa of 6.8 to 7.0, and a titration exponent of about 4.8. Interdretation of similar data pertaining to the titration of phenol-formaldehyde and pyrogallol-formaldehyde resins, considered to be analogs for humic acid by Thiele and Kettner, leads to the conclusion that it is not possible to differentiate between adsorption and acid-base reaction for these substances. ?? 1960.

  19. A simple triangular finite element for nonlinear thin shells: statics, dynamics and anisotropy

    Science.gov (United States)

    Viebahn, Nils; Pimenta, Paulo M.; Schröder, Jörg

    2017-02-01

    This work presents a simple finite element implementation of a geometrically exact and fully nonlinear Kirchhoff-Love shell model. Thus, the kinematics are based on a deformation gradient written in terms of the first- and second-order derivatives of the displacements. The resulting finite element formulation provides C^1-continuity using a penalty approach, which penalizes the kinking at the edges of neighboring elements. This approach enables the application of well-known C^0-continuous interpolations for the displacements, which leads to a simple finite element formulation, where the only unknowns are the nodal displacements. On the basis of polyconvex strain energy functions, the numerical framework for the simulation of isotropic and anisotropic thin shells is presented. A consistent plane stress condition is incorporated at the constitutive level of the model. A triangular finite element, with a quadratic interpolation for the displacements and a one-point integration for the enforcement of the C^1-continuity at the element interfaces leads to a robust shell element. Due to the simple nature of the element, even complex geometries can be meshed easily, which include folded and branched shells. The reliability and flexibility of the element formulation is shown in a couple of numerical examples, including also time dependent boundary value problems. A plane reference configuration is assumed for the shell mid-surface, but initially curved shells can be accomplished if one regards the initial configuration as a stress-free deformed state from the plane position, as done in previous works.

  20. Addressing the Big-Earth-Data Variety Challenge with the Hierarchical Triangular Mesh

    Science.gov (United States)

    Rilee, Michael L.; Kuo, Kwo-Sen; Clune, Thomas; Oloso, Amidu; Brown, Paul G.; Yu, Honfeng

    2016-01-01

    We have implemented an updated Hierarchical Triangular Mesh (HTM) as the basis for a unified data model and an indexing scheme for geoscience data to address the variety challenge of Big Earth Data. We observe that, in the absence of variety, the volume challenge of Big Data is relatively easily addressable with parallel processing. The more important challenge in achieving optimal value with a Big Data solution for Earth Science (ES) data analysis, however, is being able to achieve good scalability with variety. With HTM unifying at least the three popular data models, i.e. Grid, Swath, and Point, used by current ES data products, data preparation time for integrative analysis of diverse datasets can be drastically reduced and better variety scaling can be achieved. In addition, since HTM is also an indexing scheme, when it is used to index all ES datasets, data placement alignment (or co-location) on the shared nothing architecture, which most Big Data systems are based on, is guaranteed and better performance is ensured. Moreover, our updated HTM encoding turns most geospatial set operations into integer interval operations, gaining further performance advantages.

  1. Determination of uranium by direct titration with dipicolinic acid

    International Nuclear Information System (INIS)

    Baumann, E.W.

    1984-01-01

    Direct titration of uranium with dipicolinic acid, in the presence of Arsenazo I, is a simple, precise, and accurate method for uranium determination. The method is particularly attractive because it can be totally automated. Detecting the end point (color change from blue to pink) depends on the concentration range. For the Micro Method (1 to 20 ppM U in the solution titrated), the gradual color change is monitored spectrophotometrically. For the Macro Method (20 to 300 ppM), the end point is determined either visually or spectrophotometrically. The spectrophotometric end point is computed by fitting the titration curve. The relative standard deviation is +-1 to 3% for the Micro Method and +-0.3% for the Macro Method

  2. Coulometric titration of D(+)-glucose using its enzymatic oxidation.

    Science.gov (United States)

    Tanaka, T; Shutto, E; Mizoguchi, T; Fukushima, K

    2001-02-01

    A definitive method is described for the indirect assay of milligram quantities of D(+)-glucose by coulometric titration. D(+)-Glucose was aerobically oxidized by glucose oxidase in an acetate buffer solution (pH 5.1). Subsequently, the enzymatically formed hydrogen peroxide was titrated coulometrically with electrogenerated hypobromite in sodium bromide-sodium tetraborate medium of pH 8.6, with biamperometric end-point detection. Parameters affecting the enzymatically catalyzed oxidation and coulometric titration were evaluated. The optimized conditions for the oxidation of up to 20 mg of D(+)-glucose include the addition of 4500 U of glucose oxidase and stirring over a 10-min interval at 25 degrees C. Under proposed conditions, the assay values of several commercial D(+)-glucose reagents were somewhat lower than the guaranteed minimum values, with RSDs (n = 5) of 0.071 - 0.106%.

  3. Determination of tungsten by amperometric redox titration with dichromate

    Energy Technology Data Exchange (ETDEWEB)

    Wuensch, G.; Aupers, R.; Kranich, R.

    1985-11-01

    Tungsten is reduced by an excess of Cr(II) in about 10 M HCl. This is technically simpler than the use of reductor columns or liquid amalgams. Titration with Fe(III) or Cr(VI) first consumes the excess of Cr(II) and then oxidizes W(V) to W(VI). The potentiometric response of metal electrodes to W(V) is slow but biamperometric indication at Esub(pol) = 0.2 V applies well. A mixture of W, Fe and Mo can be analyzed in a consecutive titration. Only Ti interferes. As compared to the reductometric titration of W(VI) with Cr(II) the method uses a stable titrant and avoids deairating of the sample solution. Sample preparations for ferrotungsten, steel and wolframite ore are described. (orig.).

  4. Design of a triangular platform piezoresistive affinity microcantilever sensor for biochemical sensing applications

    Science.gov (United States)

    Mathew, Ribu; Sankar, A. Ravi

    2015-05-01

    Microcantilever platforms with integrated piezoresistors have found versatile applications in the field of clinical analysis and diagnostics. Even though treatise encompasses numerous design details of the cantilever based biochemical sensors, a majority of them focus on the generic slender rectangular cantilever platform mainly due to its evolution from the atomic force microscope (AFM). The reported designs revolve around the aspects of dimensional optimization and variations with respect to the combination of materials for the composite structure. In this paper, a triangular cantilever platform is shown to have better performance metrics than the reported generic slender rectangular and the square cantilever platforms with integrated piezoresistors for biochemical sensing applications. The selection and optimization of the triangular cantilever platform is carried out in two stages. In the first stage, the preliminary selection of the cantilever shape is performed based on the initial design obtained by analytical formulae and numerical simulations. The second stage includes the geometrical optimization of the triangular cantilever platform and the integrated piezoresistor. The triangular cantilever platform shows a better performance in terms of the figure of merit (FoM), \\psi = ≤ft(Δ R/R\\right)f02 and the measurement bandwidth. The simulation results show that the magnitude of ψ of the triangular platform is 77.21% and 65.64% higher than that of the slender rectangular and the square cantilever platforms respectively. Moreover, the triangular platform exhibits a measurement bandwidth that is 70.91% and 2.04 times higher than that of the slender rectangular and square cantilever structures respectively. For a better understanding of the 2D nature of the stress generated on the cantilever platform due to the surface stress, its spatial profile has been extracted and depicted graphically. Finally, a set of design rules are provided for optimizing the

  5. pH-metric solubility. 3. Dissolution titration template method for solubility determination.

    Science.gov (United States)

    Avdeef, A; Berger, C M

    2001-12-01

    The main objective of this study was to develop an effective potentiometric saturation titration protocol for determining the aqueous intrinsic solubility and the solubility-pH profile of ionizable molecules, with the specific aim of overcoming incomplete dissolution conditions, while attempting to shorten the data collection time. A modern theory of dissolution kinetics (an extension of the Noyes-Whitney approach) was applied to acid-base titration experiments. A thermodynamic method was developed, based on a three-component model, to calculate interfacial, diffusion-layer, and bulk-water reactant concentrations in saturated solutions of ionizable compounds perturbed by additions of acid/base titrant, leading to partial dissolution of the solid material. Ten commercial drugs (cimetidine, diltiazem hydrochloride, enalapril maleate, metoprolol tartrate, nadolol, propoxyphene hydrochloride, quinine hydrochloride, terfenadine, trovafloxacin mesylate, and benzoic acid) were chosen to illustrate the new titration methodology. It was shown that the new method is about 10 times faster in determining equilibrium solubility constants, compared to the traditional saturation shake-flask methods.

  6. Dissecting electrostatic interactions in Bacillus circulans xylanase through NMR-monitored pH titrations

    Energy Technology Data Exchange (ETDEWEB)

    McIntosh, Lawrence P., E-mail: mcintosh@chem.ubc.ca; Naito, Daigo; Baturin, Simon J.; Okon, Mark; Joshi, Manish D. [University of British Columbia, Department of Biochemistry and Molecular Biology, Department of Chemistry, and Michael Smith Laboratories, Life Sciences Centre (Canada); Nielsen, Jens E. [University College Dublin, School of Biomolecular and Biomedical Science, Centre for Synthesis and Chemical Biology, UCD Conway Institute (Ireland)

    2011-09-15

    NMR-monitored pH titration curves of proteins provide a rich source of structural and electrostatic information. Although relatively straightforward to measure, interpreting pH-dependent chemical shift changes to obtain site-specific acid dissociation constants (pK{sub A} values) is challenging. In order to analyze the biphasic titrations exhibited by the side chain {sup 13}C{sup {gamma}} nuclei of the nucleophilic Glu78 and general acid/base Glu172 in Bacillus circulans xylanase, we have revisited the formalism for the ionization equilibria of two coupled acidic residues. In general, fitting NMR-monitored pH titration curves for such a system will only yield the two macroscopic pK{sub A} values that reflect the combined effects of both deprotonation reactions. However, through the use of mutations complemented with ionic strength-dependent measurements, we are able to extract the four microscopic pK{sub Ai} values governing the branched acid/base equilibria of Glu78 and Glu172 in BcX. These data, confirmed through theoretical calculations, help explain the pH-dependent mechanism of this model GH11 xylanase by demonstrating that the kinetically determined pK{sub A} values and hence catalytic roles of these two residues result from their electrostatic coupling.

  7. Dissecting electrostatic interactions in Bacillus circulans xylanase through NMR-monitored pH titrations

    International Nuclear Information System (INIS)

    McIntosh, Lawrence P.; Naito, Daigo; Baturin, Simon J.; Okon, Mark; Joshi, Manish D.; Nielsen, Jens E.

    2011-01-01

    NMR-monitored pH titration curves of proteins provide a rich source of structural and electrostatic information. Although relatively straightforward to measure, interpreting pH-dependent chemical shift changes to obtain site-specific acid dissociation constants (pK A values) is challenging. In order to analyze the biphasic titrations exhibited by the side chain 13 C γ nuclei of the nucleophilic Glu78 and general acid/base Glu172 in Bacillus circulans xylanase, we have revisited the formalism for the ionization equilibria of two coupled acidic residues. In general, fitting NMR-monitored pH titration curves for such a system will only yield the two macroscopic pK A values that reflect the combined effects of both deprotonation reactions. However, through the use of mutations complemented with ionic strength-dependent measurements, we are able to extract the four microscopic pK Ai values governing the branched acid/base equilibria of Glu78 and Glu172 in BcX. These data, confirmed through theoretical calculations, help explain the pH-dependent mechanism of this model GH11 xylanase by demonstrating that the kinetically determined pK A values and hence catalytic roles of these two residues result from their electrostatic coupling.

  8. Spectroscopic study on variations in illite surface properties after acid-base titration.

    Science.gov (United States)

    Liu, Wen-xin; Coveney, R M; Tang, Hong-xiao

    2003-07-01

    FT-IR, Raman microscopy, XRD, 29Si and 27Al MAS NMR, were used to investigate changes in surface properties of a natural illite sample after acid-base potentiometric titration. The characteristic XRD lines indicated the presence of surface Al-Si complexes, preferable to Al(OH)3 precipitates. In the microscopic Raman spectra, the vibration peaks of Si-O and Al-O bonds diminished as a result of treatment with acid, then increased after hydroxide back titration. The varied ratio of signal intensity between (IV)Al and (VI)Al species in 27Al MAS NMR spectra, together with the stable BET surface area after acidimetric titration, suggested that edge faces and basal planes in the layer structure of illite participated in dissolution of structural components. The combined spectroscopic evidence demonstrated that the reactions between illite surfaces and acid-leaching silicic acid and aluminum ions should be considered in the model description of surface acid-base properties of the aqueous illite.

  9. Protein-salt binding data from potentiometric titrations of lysozyme in aqueous solutions containing KCl

    Energy Technology Data Exchange (ETDEWEB)

    Engmann, J.; Blanch, H.W.; Prausnitz, J.M. [Univ. of California, Berkeley, CA (United States). Dept. of Chemical Engineering]|[Lawrence Berkeley National Lab., CA (United States). Chemical Sciences Div.

    1997-03-01

    An existing method for potentiometric titrations of proteins was improved, tested and applied to titrations of the enzyme hen-egg-white lysozyme in aqueous solutions containing KCl at ionic strengths from 0.1 M to 2.0 M at 25 C. Information about the protein`s net charge dependence on pH and ionic strength were obtained and salt binding numbers for the system were calculated using a linkage concept. For the pH range 2.5--11.5, the net charge slightly but distinctly increases with increasing ionic strength between 0.1 M and 2.0 M. The differences are most distinct in the pH region below 5. Above pH 11.35, the net charge decreases with increasing ionic strength. Preliminary calculation of binding numbers from titration curves at 0.1 M and 1.0 M showed selective association of chloride anions and expulsion of potassium ions at low pH. Ion-binding numbers from this work will be used to evaluate thermodynamic properties and to correlate crystallization or precipitation phase-equilibrium data in terms of a model based on the integral-equation theory of fluids which is currently under development.

  10. Equivalence-point electromigration acid-base titration via moving neutralization boundary electrophoresis.

    Science.gov (United States)

    Yang, Qing; Fan, Liu-Yin; Huang, Shan-Sheng; Zhang, Wei; Cao, Cheng-Xi

    2011-04-01

    In this paper, we developed a novel method of acid-base titration, viz. the electromigration acid-base titration (EABT), via a moving neutralization boundary (MNR). With HCl and NaOH as the model strong acid and base, respectively, we conducted the experiments on the EABT via the method of moving neutralization boundary for the first time. The experiments revealed that (i) the concentration of agarose gel, the voltage used and the content of background electrolyte (KCl) had evident influence on the boundary movement; (ii) the movement length was a function of the running time under the constant acid and base concentrations; and (iii) there was a good linearity between the length and natural logarithmic concentration of HCl under the optimized conditions, and the linearity could be used to detect the concentration of acid. The experiments further manifested that (i) the RSD values of intra-day and inter-day runs were less than 1.59 and 3.76%, respectively, indicating similar precision and stability in capillary electrophoresis or HPLC; (ii) the indicators with different pK(a) values had no obvious effect on EABT, distinguishing strong influence on the judgment of equivalence-point titration in the classic one; and (iii) the constant equivalence-point titration always existed in the EABT, rather than the classic volumetric analysis. Additionally, the EABT could be put to good use for the determination of actual acid concentrations. The experimental results achieved herein showed a new general guidance for the development of classic volumetric analysis and element (e.g. nitrogen) content analysis in protein chemistry. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Clinical predictors of central sleep apnea evoked by positive airway pressure titration.

    Science.gov (United States)

    Moro, Marilyn; Gannon, Karen; Lovell, Kathy; Merlino, Margaret; Mojica, James; Bianchi, Matt T

    2016-01-01

    Treatment-emergent central sleep apnea (TECSA), also called complex apnea, occurs in 5%-15% of sleep apnea patients during positive airway pressure (PAP) therapy, but the clinical predictors are not well understood. The goal of this study was to explore possible predictors in a clinical sleep laboratory cohort, which may highlight those at risk during clinical management. We retrospectively analyzed 728 patients who underwent PAP titration (n=422 split-night; n=306 two-night). Demographics and self-reported medical comorbidities, medications, and behaviors as well as standard physiological parameters from the polysomnography (PSG) data were analyzed. We used regression analysis to assess predictors of binary presence or absence of central apnea index (CAI) ≥5 during split-night PSG (SN-PSG) versus full-night PSG (FN-PSG) titrations. CAI ≥5 was present in 24.2% of SN-PSG and 11.4% of FN-PSG patients during titration. Male sex, maximum continuous positive airway pressure, and use of bilevel positive airway pressure were predictors of TECSA, and rapid eye movement dominance was a negative predictor, for both SN-PSG and FN-PSG patients. Self-reported narcotics were a positive predictor of TECSA, and the time spent in stage N2 sleep was a negative predictor only for SN-PSG patients. Self-reported history of stroke and the CAI during the diagnostic recording predicted TECSA only for FN-PSG patients. Clinical predictors of treatment-evoked central apnea spanned demographic, medical history, sleep physiology, and titration factors. Improved predictive models may be increasingly important as diagnostic and therapeutic modalities move away from the laboratory setting, even as PSG remains the gold standard for characterizing primary central apnea and TECSA.

  12. Error assessment in recombinant baculovirus titration: evaluation of different methods.

    Science.gov (United States)

    Roldão, António; Oliveira, Rui; Carrondo, Manuel J T; Alves, Paula M

    2009-07-01

    The success of baculovirus/insect cells system in heterologous protein expression depends on the robustness and efficiency of the production workflow. It is essential that process parameters are controlled and include as little variability as possible. The multiplicity of infection (MOI) is the most critical factor since irreproducible MOIs caused by inaccurate estimation of viral titers hinder batch consistency and process optimization. This lack of accuracy is related to intrinsic characteristics of the method such as the inability to distinguish between infectious and non-infectious baculovirus. In this study, several methods for baculovirus titration were compared. The most critical issues identified were the incubation time and cell concentration at the time of infection. These variables influence strongly the accuracy of titers and must be defined for optimal performance of the titration method. Although the standard errors of the methods varied significantly (7-36%), titers were within the same order of magnitude; thus, viral titers can be considered independent of the method of titration. A cost analysis of the baculovirus titration methods used in this study showed that the alamarblue, real time Q-PCR and plaque assays were the most expensive techniques. The remaining methods cost on average 75% less than the former methods. Based on the cost, time and error analysis undertaken in this study, the end-point dilution assay, microculture tetrazolium assay and flow cytometric assay were found to be the techniques that combine all these three main factors better. Nevertheless, it is always recommended to confirm the accuracy of the titration either by comparison with a well characterized baculovirus reference stock or by titration using two different methods and verification of the variability of results.

  13. Structural Performance of a Hybrid FRP-Aluminum Modular Triangular Truss System Subjected to Various Loading Conditions

    Directory of Open Access Journals (Sweden)

    Dongdong Zhang

    2014-01-01

    Full Text Available A novel hybrid FRP-aluminum truss system has been employed in a two-rut modular bridge superstructure composed of twin inverted triangular trusses. The actual flexural behavior of a one-rut truss has been previously investigated under the on-axis loading test; however, the structural performance of the one-rut truss subjected to an off-axis load is still not fully understood. In this paper, a geometrical linear finite element model is introduced and validated by the on-axis loading test; the structural performance of the one-rut truss subjected to off-axis load was numerically obtained; the dissimilarities of the structural performance between the two different loading cases are investigated in detail. The results indicated that (1 the structural behavior of the off-axis load differs from that of the on-axis load, and the off-axis load is the critical loading condition controlling the structural performance of the triangular truss; (2 under the off-axis load, the FRP trussed members and connectors bear certain out-of-plane bending moments and are subjected to a complicated stress state; and (3 the stress state of these members does not match that of the initial design, and optimization for the redesign of these members is needed, especially for the pretightened teeth connectors.

  14. A parallel finite element procedure for contact-impact problems using edge-based smooth triangular element and GPU

    Science.gov (United States)

    Cai, Yong; Cui, Xiangyang; Li, Guangyao; Liu, Wenyang

    2018-04-01

    The edge-smooth finite element method (ES-FEM) can improve the computational accuracy of triangular shell elements and the mesh partition efficiency of complex models. In this paper, an approach is developed to perform explicit finite element simulations of contact-impact problems with a graphical processing unit (GPU) using a special edge-smooth triangular shell element based on ES-FEM. Of critical importance for this problem is achieving finer-grained parallelism to enable efficient data loading and to minimize communication between the device and host. Four kinds of parallel strategies are then developed to efficiently solve these ES-FEM based shell element formulas, and various optimization methods are adopted to ensure aligned memory access. Special focus is dedicated to developing an approach for the parallel construction of edge systems. A parallel hierarchy-territory contact-searching algorithm (HITA) and a parallel penalty function calculation method are embedded in this parallel explicit algorithm. Finally, the program flow is well designed, and a GPU-based simulation system is developed, using Nvidia's CUDA. Several numerical examples are presented to illustrate the high quality of the results obtained with the proposed methods. In addition, the GPU-based parallel computation is shown to significantly reduce the computing time.

  15. Potentiometric and coulometric titration of 6-propyl-2-thiouracil.

    Science.gov (United States)

    Ciesielski, W; Zakrzewski, R

    1997-05-01

    A method for the determination of 6-propyl-2-thiouracil involving its reaction with iodine in an alkaline medium is presented. In volumetric titration with potentiometric end-point detection, the range of determination is 125-500 mumol (21-85 mg). In coulometric titration using biamperometric end-point detection, 0.5-5.0 mumol (0.085-0.85 mg) of 6-propyl-2-thiouracil was successfully determined. The RSD in all applied techniques was < 1%. The methods developed were applied to the determination of 6-propyl-2-thiouracil in tablets.

  16. Numerical investigations on the turbulent forced convection of nanofluids flow in a triangular-corrugated channel

    Directory of Open Access Journals (Sweden)

    M.A. Ahmed

    2015-09-01

    Full Text Available In this paper, turbulent forced convection of nanofluids flow in triangular-corrugated channels is numerically investigated over Reynolds number ranges of 1000–5000. Four different types of nanofluids which are Al2O3, CuO, SiO2 and ZnO–water with nanoparticles diameters in the range of 30–70 nm and the range of nanoparticles volume fraction from 0% to 4% have been considered. The governing equations of mass, momentum and energy are solved using finite volume method (FVM. The low Reynolds number k–ε model of Launder and Sharma is adopted as well. It is found that the average Nusselt number, pressure drop, heat transfer enhancement, thermal–hydraulic performance increase with increasing in the volume fraction of nanoparticles and with decreasing in the diameter of nanoparticles. Furthermore, the SiO2–water nanofluid provides the highest thermal–hydraulic performance among other types of nanofluids followed by Al2O3, ZnO and CuO–water nanofluids. Moreover, the pure water has the lowest heat transfer enhancement as well as thermal–hydraulic performance.

  17. Integrable Nonlinear Schrödinger System on a Triangular-Lattice Ribbon

    Science.gov (United States)

    Vakhnenko, Oleksiy O.

    2015-01-01

    An integrable nonlinear Schrödinger system on a triangular-lattice ribbon, whose geometric configuration is similar to that of (1,1) armchair boron nanotube, is studied in detail. The system Hamiltonian formulation is shown to underline an essentially nontrivial Poisson structure associated with four basic field variables appearing as nearly amplitudes of the probability to find the lattice sites being excited and with two concomitant field variables maintaining the finite background. The coupling parameters of the system are allowed to be complex-valued ones thus permitting to model external magnetic fluxes threading the elementary plackets of a lattice in terms of Peierls phases. An alternative version of zero-curvature representation given in terms of 2 × 2 auxiliary spectral and evolution matrices is proved to support the constructive integrability of the system by means of Darboux-Bäcklund dressing method. In the framework of Darboux approach the one-soliton solution is found explicitly and analyzed with special attention to the principal differences between the bare and physical soliton parameters.

  18. Trapping ultracold atoms in a sub-micron-period triangular magnetic lattice

    Science.gov (United States)

    Wang, Y.; Tran, T.; Surendran, P.; Herrera, I.; Balcytis, A.; Nissen, D.; Albrecht, M.; Sidorov, A.; Hannaford, P.

    2017-07-01

    We report the trapping of ultracold 87Rb atoms in a 0.7-μ m-period two-dimensional triangular magnetic lattice on an atom chip. The magnetic lattice is created by a lithographically patterned magnetic Co/Pd multilayer film plus bias fields. Rubidium atoms in the |F =1 , mF=-1 > low-field seeking state are trapped at estimated distances down to about 100 nm from the chip surface and with calculated mean trapping frequencies up to about 800 kHz . The measured lifetimes of the atoms trapped in the magnetic lattice are in the range 0.4-1.7 ms , depending on distance from the chip surface. Model calculations suggest the trap lifetimes are currently limited mainly by losses due to one-dimensional thermal evaporation following loading of the atoms from the Z -wire trap into the very tight magnetic lattice traps, rather than by fundamental loss processes such as surface interactions, three-body recombination, or spin flips due to Johnson magnetic noise. The trapping of atoms in a 0.7 -μ m -period magnetic lattice represents a significant step toward using magnetic lattices for quantum tunneling experiments and to simulate condensed matter and many-body phenomena in nontrivial lattice geometries.

  19. Complex ordered patterns in mechanical instability induced geometrically frustrated triangular cellular structures

    Science.gov (United States)

    Kang, Sung; Shan, Sicong; Kosmrlj, Andrej; Noorduin, Wim; Shian, Samuel; Weaver, James; Clarke, David; Bertoldi, Katia

    2014-03-01

    Geometrical frustration arises when a local order cannot propagate throughout the space due to geometrical constraints. It plays a major role in many natural and synthetic systems including water ice, spin ice, and metallic glasses. All of these geometrically frustrated systems are degenerate and tend to form disordered ground-state configurations. Here, we report a theoretical and experimental study on the behavior of buckling-induced geometrically frustrated triangular cellular structures. To our surprise, we find that mechanical instabilities induce complex ordered patterns with tunability. For structures with low porosity, an ordered symmetric pattern emerges, which shows striking correlations with the ideal spin solid. In contrast, for high porosity systems, an ordered chiral pattern forms with a new spin configuration. Our analysis using a spin-like model reveals that the connected geometry of the cellular structure plays a crucial role in the formation of ordered states in this system. Since in our study geometrical frustration is induced by a mechanical instability that is scale-independent, our findings can be extended to different materials, stimuli, and length scales, providing a general strategy to study and visualize the physics of frustration.

  20. Construction and use of an optical semi-automatic titrator employing the technique of reflectance photometry

    International Nuclear Information System (INIS)

    Hwang, Hoon

    2001-01-01

    An optical semi-automatic titrator was constructed employing the technique of the reflectance spectrometry and was tested for the determination of the end points of the acid-base, precipitation, and EDTA titrations. And since the current optical semi-automatic titrator built on the principle of the reflectance spectrometry could be successfully used even for the determination of the end of the end point in the precipitation titration where the solid particles are formed during the titration process, it was found to be feasible that a completely automated optical titrator would be designed and built based on the current findings

  1. A framework for dense triangular matrix kernels on various manycore architectures

    KAUST Repository

    Charara, Ali

    2017-06-06

    We present a new high-performance framework for dense triangular Basic Linear Algebra Subroutines (BLAS) kernels, ie, triangular matrix-matrix multiplication (TRMM) and triangular solve (TRSM), on various manycore architectures. This is an extension of a previous work on a single GPU by the same authors, presented at the EuroPar\\'16 conference, in which we demonstrated the effectiveness of recursive formulations in enhancing the performance of these kernels. In this paper, the performance of triangular BLAS kernels on a single GPU is further enhanced by implementing customized in-place CUDA kernels for TRMM and TRSM, which are called at the bottom of the recursion. In addition, a multi-GPU implementation of TRMM and TRSM is proposed and we show an almost linear performance scaling, as the number of GPUs increases. Finally, the algorithmic recursive formulation of these triangular BLAS kernels is in fact oblivious to the targeted hardware architecture. We, therefore, port these recursive kernels to homogeneous x86 hardware architectures by relying on the vendor optimized BLAS implementations. Results reported on various hardware architectures highlight a significant performance improvement against state-of-the-art implementations. These new kernels are freely available in the KAUST BLAS (KBLAS) open-source library at https://github.com/ecrc/kblas.

  2. Hesitant Triangular Fuzzy Information Aggregation Operators Based on Bonferroni Means and Their Application to Multiple Attribute Decision Making

    Science.gov (United States)

    Zhou, Xiaoqiang; Yang, Tian

    2014-01-01

    We investigate the multiple attribute decision-making (MADM) problems with hesitant triangular fuzzy information. Firstly, definition and some operational laws of hesitant triangular fuzzy elements are introduced. Then, we develop some hesitant triangular fuzzy aggregation operators based on Bonferroni means and discuss their basic properties. Some existing operators can be viewed as their special cases. Next, we apply the proposed operators to deal with multiple attribute decision-making problems under hesitant triangular fuzzy environment. Finally, an illustrative example is given to show the developed method and demonstrate its practicality and effectiveness. PMID:25140338

  3. potentiometric titration curves of aluminium salt solutions and its

    African Journals Online (AJOL)

    a

    species, which set up a base to study on the hydrolysis-polymerization of Al3+. At the same time, significant effects of total aluminum concentration, temperature, halide ion, silicate radical, and organic acid radical on the titration curves and its critical points were observed. Given the three critical points which demarcating the ...

  4. Potentiometric titration curves of aluminium salt solutions and its ...

    African Journals Online (AJOL)

    At the same time, significant effects of total aluminum concentration, temperature, halide ion, silicate radical, and organic acid radical on the titration curves and its critical points were observed. Given the three critical points which demarcating the aluminum forms, we carry out a through investigation into the fundamental ...

  5. Acid/base titrations of simulated PWR crevice environments

    International Nuclear Information System (INIS)

    Pang, J.; Macdonald, D.D.; Millett, P.J.

    1993-01-01

    The construction and operation of a titration system that is capable of exploring the acid/base properties of aqueous systems at temperatures solution is measured using YSZ sensors of the type Hg/HgO/ZrO 2 (Y 2 O 3 )/Solution in conjunction with a suitable reference electrode. The use of the system for measuring the pH of the titrated solutions (NaOH/H 2 SO 4 ) is discussed, and we show that the YSZ pH sensor is capable of consistent and precise pH measurements at elevated temperature (275-325 degrees C) and pressures (100-150 bars). However, the accuracy of the measured pH depends critically on the performance of the reference electrode. In the present work, we ensure the viability of the reference electrode. In the present work, we ensure the viability of the reference electrode by periodically calibrating it in situ using the pH sensor and a standard solution of known pH versus temperature characteristics. The titration data obtained in this study are compared with predictions from EPRI's MULTEQ code, and are found to be in satisfactory agreement in the alkaline pH region. Observed discrepancies in the acidic pH region between the two sets of data are attributed to corrosion of the alloys used to fabricate the titration system

  6. A dipstick sensor for coulometric acid-base titrations

    NARCIS (Netherlands)

    Olthuis, Wouter; van der Schoot, B.H.; Chavez, F.; Bergveld, Piet

    1989-01-01

    By performing an acid-base titration by coulometric generation of OH− or H+ ions at an inert electrode in close proximity to the pH-sensitive gate of an ISFET, it is possible to determine the acid or base concentration of a solution using the ISFET as an indicator device for the equivalence point in

  7. Using Spreadsheets to Produce Acid-Base Titration Curves.

    Science.gov (United States)

    Cawley, Martin James; Parkinson, John

    1995-01-01

    Describes two spreadsheets for producing acid-base titration curves, one uses relatively simple cell formulae that can be written into the spreadsheet by inexperienced students and the second uses more complex formulae that are best written by the teacher. (JRH)

  8. Determination of Acidity Constants by Gradient Flow-Injection Titration

    Science.gov (United States)

    Conceicao, Antonio C. L.; Minas da Piedade, Manuel E.

    2006-01-01

    A three-hour laboratory experiment, designed for an advanced undergraduate course in instrumental analysis that illustrates the application of the gradient chamber flow-injection titration (GCFIT) method with spectrophotometric detection to determine acidity constants is presented. The procedure involves the use of an acid-base indicator to obtain…

  9. A General Simulator for Acid-Base Titrations

    Science.gov (United States)

    de Levie, Robert

    1999-07-01

    General formal expressions are provided to facilitate the automatic computer calculation of acid-base titration curves of arbitrary mixtures of acids, bases, and salts, without and with activity corrections based on the Davies equation. Explicit relations are also given for the buffer strength of mixtures of acids, bases, and salts.

  10. Developing and Demonstrating an Augmented Reality Colorimetric Titration Tool

    Science.gov (United States)

    Tee, Nicholas Yee Kwang; Gan, Hong Seng; Li, Jonathan; Cheong, Brandon Huey-Ping; Tan, Han Yen; Liew, Oi Wah; Ng, Tuck Wah

    2018-01-01

    The handling of chemicals in the laboratory presents a challenge in instructing large class sizes and when students are relatively new to the laboratory environment. In this work, we describe and demonstrate an augmented reality colorimetric titration tool that operates out of the smartphone or tablet of students. It allows multiple students to…

  11. Isothermal Titration Calorimetry Can Provide Critical Thinking Opportunities

    Science.gov (United States)

    Moore, Dale E.; Goode, David R.; Seney, Caryn S.; Boatwright, Jennifer M.

    2016-01-01

    College chemistry faculties might not have considered including isothermal titration calorimetry (ITC) in their majors' curriculum because experimental data from this instrumental method are often analyzed via automation (software). However, the software-based data analysis can be replaced with a spreadsheet-based analysis that is readily…

  12. Electroconvulsive therapy stimulus titration: Not all it seems.

    Science.gov (United States)

    Rosenman, Stephen J

    2018-05-01

    To examine the provenance and implications of seizure threshold titration in electroconvulsive therapy. Titration of seizure threshold has become a virtual standard for electroconvulsive therapy. It is justified as individualisation and optimisation of the balance between efficacy and unwanted effects. Present day threshold estimation is significantly different from the 1960 studies of Cronholm and Ottosson that are its usual justification. The present form of threshold estimation is unstable and too uncertain for valid optimisation or individualisation of dose. Threshold stimulation (lowest dose that produces a seizure) has proven therapeutically ineffective, and the multiples applied to threshold to attain efficacy have never been properly investigated or standardised. The therapeutic outcomes of threshold estimation (or its multiples) have not been separated from simple dose effects. Threshold estimation does not optimise dose due to its own uncertainties and the different short-term and long-term cognitive and memory effects. Potential harms of titration have not been examined. Seizure threshold titration in electroconvulsive therapy is not a proven technique of dose optimisation. It is widely held and practiced; its benefit and harmlessness assumed but unproven. It is a prematurely settled answer to an unsettled question that discourages further enquiry. It is an example of how practices, assumed scientific, enter medicine by obscure paths.

  13. Effects of positive end-expiratory pressure titration and recruitment maneuver on lung inflammation and hyperinflation in experimental acid aspiration-induced lung injury.

    Science.gov (United States)

    Ambrosio, Aline M; Luo, Rubin; Fantoni, Denise T; Gutierres, Claudia; Lu, Qin; Gu, Wen-Jie; Otsuki, Denise A; Malbouisson, Luiz M S; Auler, Jose O C; Rouby, Jean-Jacques

    2012-12-01

    In acute lung injury positive end-expiratory pressure (PEEP) and recruitment maneuver are proposed to optimize arterial oxygenation. The aim of the study was to evaluate the impact of such a strategy on lung histological inflammation and hyperinflation in pigs with acid aspiration-induced lung injury. Forty-seven pigs were randomly allocated in seven groups: (1) controls spontaneously breathing; (2) without lung injury, PEEP 5 cm H2O; (3) without lung injury, PEEP titration; (4) without lung injury, PEEP titration + recruitment maneuver; (5) with lung injury, PEEP 5 cm H2O; (6) with lung injury, PEEP titration; and (7) with lung injury, PEEP titration + recruitment maneuver. Acute lung injury was induced by intratracheal instillation of hydrochloric acid. PEEP titration was performed by incremental and decremental PEEP from 5 to 20 cm H2O for optimizing arterial oxygenation. Three recruitment maneuvers (pressure of 40 cm H2O maintained for 20 s) were applied to the assigned groups at each PEEP level. Proportion of lung inflammation, hemorrhage, edema, and alveolar wall disruption were recorded on each histological field. Mean alveolar area was measured in the aerated lung regions. Acid aspiration increased mean alveolar area and produced alveolar wall disruption, lung edema, alveolar hemorrhage, and lung inflammation. PEEP titration significantly improved arterial oxygenation but simultaneously increased lung inflammation in juxta-diaphragmatic lung regions. Recruitment maneuver during PEEP titration did not induce additional increase in lung inflammation and alveolar hyperinflation. In a porcine model of acid aspiration-induced lung injury, PEEP titration aimed at optimizing arterial oxygenation, substantially increased lung inflammation. Recruitment maneuvers further improved arterial oxygenation without additional effects on inflammation and hyperinflation.

  14. Dose Titration of Pregabalin in Patients with Painful Diabetic Peripheral Neuropathy: Simulation Based on Observational Study Patients Enriched with Data from Randomized Studies.

    Science.gov (United States)

    Alexander, Joe; Edwards, Roger A; Manca, Luigi; Grugni, Roberto; Bonfanti, Gianluca; Emir, Birol; Whalen, Edward; Watt, Stephen; Parsons, Bruce

    2018-03-01

    Achieving a therapeutic response to pregabalin in patients with painful diabetic peripheral neuropathy (pDPN) requires adequate upward dose titration. Our goal was to identify relationships between titration and response to pregabalin in patients with pDPN. Data were integrated from nine randomized, placebo-controlled clinical trials as well as one 6-week open-label observational study conducted by 5808 physicians (2642 patients with pDPN) in standard outpatient settings in Germany. These studies evaluated pregabalin for treatment of pDPN. Using these data, we examined "what if" scenarios using a microsimulation platform that integrates data from randomized and observational sources as well as autoregressive-moving-average with exogenous inputs models that predict pain outcomes, taking into account weekly changes in pain, sleep interference, dose, and other patient characteristics that were unchanging. Final pain levels were significantly different depending on dose changes (P titration regardless of baseline pain severity. Altogether, 78.5% of patients with pDPN had 0-1 dose change, and 15.2% had ≥ 2 dose changes. Simulation demonstrated that the 4.8% of inadequately titrated patients who did not improve/very much improve their pain levels would have benefited from ≥ 2 dose changes. Patient satisfaction with tolerability (range 90.3-96.2%) was similar, regardless of baseline pain severity, number of titrations, or extent of improvement, suggesting that tolerability did not influence treatment response patterns. Upward dose titration reduced pain in patients with pDPN who actually received it. Simulation also predicted pain reduction in an inadequately titrated nonresponder subgroup of patients had they actually received adequate titration. The decision not to uptitrate must have been driven by factors other than tolerability. Pfizer, Inc.

  15. Experimental Study on Horizontal Cylinders with Triangular Fins under Natural Convection

    Directory of Open Access Journals (Sweden)

    Gu-Won Lee

    2018-04-01

    Full Text Available In this study, thermal resistances of horizontal cylinders with triangular fins were measured in regard to fin numbers, fins heights, and temperature differences. Thereafter, an empirical correlation was proposed and validated for predicting the Nusselt numbers under the following conditions: Rayleigh number, 200,000–1,000,000; fin aspect ratio, 1.6–5.0; and fin number, 9–72. Finally, with the proposed correlation, the effects of fin numbers, fins heights, and fin thicknesses on the thermal resistances of the horizontal cylinders with triangular fins were investigated. It was shown that the thermal resistance generally increases as the fin number, fin height, and fin thickness increase. It is expected that horizontal cylinders for various cooling devices with triangular fins can be designed based on the findings of the present study.

  16. A PSO-based approach to optimize the triangular membership functions in a fuzzy logic controller

    Science.gov (United States)

    Maniscalco, Vincenzo; Lombardo, Francesco

    2017-11-01

    In this paper a Particle Swarm Optimization (PSO) algorithm is considered in order to optimize the triangular Membership Functions (MF) in a Fuzzy Logic Controller (FLC). PSO algorithm belongs to the class of Swarm Intelligence (SI) techniques and is considered an efficient heuristic technique for optimization problem in a continuous and multidimen-sional search spaces. Performance of a FLC depends on the fuzzy partition of each input/output space considered and the PSO algorithm can be used to obtain the optimal or near optimal parameters of the triangular membership functions in order to achieve the best results in the defuzzification process. Simulation results obtained by this approach to tune the triangular membership functions of a FLC for an application concerning the optimization of the energy consumption in Industrial Wireless Sensor Networks (IWSN) are reported.

  17. Clinical predictors of central sleep apnea evoked by positive airway pressure titration

    Directory of Open Access Journals (Sweden)

    Moro M

    2016-07-01

    Full Text Available Marilyn Moro,1 Karen Gannon,1 Kathy Lovell,1 Margaret Merlino,1 James Mojica,2 Matt T Bianchi,1,3 1Neurology Department, 2Pulmonary and Critical Care Medicine, Massachusetts General Hospital, Boston, MA, USA; 3Division of Sleep Medicine, Harvard Medical School, Boston, MA, USA Purpose: Treatment-emergent central sleep apnea (TECSA, also called complex apnea, occurs in 5%–15% of sleep apnea patients during positive airway pressure (PAP therapy, but the clinical predictors are not well understood. The goal of this study was to explore possible predictors in a clinical sleep laboratory cohort, which may highlight those at risk during clinical management.Methods: We retrospectively analyzed 728 patients who underwent PAP titration (n=422 split night; n=306 two-night. Demographics and self-reported medical comorbidities, medications, and behaviors as well as standard physiological parameters from the polysomnography (PSG data were analyzed. We used regression analysis to assess predictors of binary presence or absence of central apnea index (CAI ≥5 during split PSG (SN-PSG versus full-night PSG (FN-PSG titrations.Results: CAI ≥5 was present in 24.2% of SN-PSG and 11.4% of FN-PSG patients during titration. Male sex, maximum continuous positive airway pressure, and use of bilevel positive airway pressure were predictors of TECSA, and rapid eye movement dominance was a negative predictor, for both SN-PSG and FN-PSG patients. Self-reported narcotics were a positive predictor of TECSA, and the time spent in stage N2 sleep was a negative predictor only for SN-PSG patients. Self-reported history of stroke and the CAI during the diagnostic recording predicted TECSA only for FN-PSG patients.Conclusion: Clinical predictors of treatment-evoked central apnea spanned demographic, medical history, sleep physiology, and titration factors. Improved predictive models may be increasingly important as diagnostic and therapeutic modalities move away from the

  18. Evaluation of modified boehm titration methods for use with biochars.

    Science.gov (United States)

    Fidel, Rivka B; Laird, David A; Thompson, Michael L

    2013-11-01

    The Boehm titration, originally developed to quantify organic functional groups of carbon blacks and activated carbons in discrete pK ranges, has received growing attention for analyzing biochar. However, properties that distinguish biochar from carbon black and activated carbon, including greater carbon solubility and higher ash content, may render the original Boehm titration method unreliable for use with biochars. Here we use seven biochars and one reference carbon black to evaluate three Boehm titration methods that use (i) acidification followed by sparging (sparge method), (ii) centrifugation after treatment with BaCl (barium method), and (iii) a solid-phase extraction cartridge followed by acidification and sparging (cartridge method) to remove carbonates and dissolved organic compounds (DOC) from the Boehm extracts before titration. Our results for the various combinations of Boehm reactants and methods indicate that no one method was free of bias for all three Boehm reactants and that the cartridge method showed evidence of bias for all pK ranges. By process of elimination, we found that a combination of the sparge method for quantifying functional groups in the lowest pK range (∼5 to 6.4), and the barium method for quantifying functional groups in the higher pK ranges (∼6.4 to 10.3 and ∼10.3 to 13) to be free of evidence for bias. We caution, however, that further testing is needed and that all Boehm titration results for biochars should be considered suspect unless efforts were undertaken to remove ash and prevent interference from DOC. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  19. Effect of temperature on the acid-base properties of the alumina surface: microcalorimetry and acid-base titration experiments.

    Science.gov (United States)

    Morel, Jean-Pierre; Marmier, Nicolas; Hurel, Charlotte; Morel-Desrosiers, Nicole

    2006-06-15

    Sorption reactions on natural or synthetic materials that can attenuate the migration of pollutants in the geosphere could be affected by temperature variations. Nevertheless, most of the theoretical models describing sorption reactions are at 25 degrees C. To check these models at different temperatures, experimental data such as the enthalpies of sorption are thus required. Highly sensitive microcalorimeters can now be used to determine the heat effects accompanying the sorption of radionuclides on oxide-water interfaces, but enthalpies of sorption cannot be extracted from microcalorimetric data without a clear knowledge of the thermodynamics of protonation and deprotonation of the oxide surface. However, the values reported in the literature show large discrepancies and one must conclude that, amazingly, this fundamental problem of proton binding is not yet resolved. We have thus undertaken to measure by titration microcalorimetry the heat effects accompanying proton exchange at the alumina-water interface at 25 degrees C. Based on (i) the surface sites speciation provided by a surface complexation model (built from acid-base titrations at 25 degrees C) and (ii) results of the microcalorimetric experiments, calculations have been made to extract the enthalpic variations associated respectively to first and second deprotonation of the alumina surface. Values obtained are deltaH1 = 80+/-10 kJ mol(-1) and deltaH2 = 5+/-3 kJ mol(-1). In a second step, these enthalpy values were used to calculate the alumina surface acidity constants at 50 degrees C via the van't Hoff equation. Then a theoretical titration curve at 50 degrees C was calculated and compared to the experimental alumina surface titration curve. Good agreement between the predicted acid-base titration curve and the experimental one was observed.

  20. Triangular flow of negative pions emitted in PbAu collisions at √{sNN} = 17.3 GeV

    Science.gov (United States)

    Adamová, D.; Agakichiev, G.; Andronic, A.; Antończyk, D.; Appelshäuser, H.; Belaga, V.; Bielčíková, J.; Braun-Munzinger, P.; Busch, O.; Cherlin, A.; Damjanović, S.; Dietel, T.; Dietrich, L.; Drees, A.; Dubitzky, W.; Esumi, S. I.; Filimonov, K.; Fomenko, K.; Fraenkel, Z.; Garabatos, C.; Glässel, P.; Hering, G.; Holeczek, J.; Kalisky, M.; Karpenko, Iu.; Krobath, G.; Kushpil, V.; Maas, A.; Marín, A.; Milošević, J.; Miśkowiec, D.; Panebrattsev, Y.; Petchenova, O.; Petráček, V.; Radomski, S.; Rak, J.; Ravinovich, I.; Rehak, P.; Sako, H.; Schmitz, W.; Schuchmann, S.; Sedykh, S.; Shimansky, S.; Stachel, J.; Šumbera, M.; Tilsner, H.; Tserruya, I.; Tsiledakis, G.; Wessels, J. P.; Wienold, T.; Wurm, J. P.; Yurevich, S.; Yurevich, V.

    2017-01-01

    Differential triangular flow, v3 (pT), of negative pions is measured at √{sNN} = 17.3 GeV around midrapidity by the CERES/NA45 experiment at CERN in central PbAu collisions in the range 0-30% with a mean centrality of 5.5%. This is the first measurement as a function of transverse momentum of the triangular flow at SPS energies. The pT range extends from about 0.05 GeV/c to more than 2 GeV/c. The triangular flow magnitude, corrected for the HBT effects, is smaller by a factor of about 2 than the one measured by the PHENIX experiment at RHIC and the ALICE experiment at the LHC. Within the analyzed range of central collisions no significant centrality dependence is observed. The data are found to be well described by a viscous hydrodynamic calculation combined with an UrQMD cascade model for the late stages.

  1. A new printed fractal right angled isosceles triangular monopole antenna for ultra-wideband applications

    Directory of Open Access Journals (Sweden)

    Manisha Gupta

    2017-03-01

    Full Text Available In this present work, a different right angled isosceles triangular Microstrip patch antenna (RITMA for ultra wideband (UWB utilization is designed. The antenna presented is simple and small in structure. The antenna has a triangular patch with defected ground plane and a notch on the ground surface, which provides a usable bandwidth. By fracturing the antenna a significant improvement in return loss is seen, and good gain is obtained. Results of the proposed antenna show omnidirectional radiation behavior within the UWB frequency range.

  2. Tokamak equilibria with non-parallel flow in a triangularity-deformed axisymmetric toroidal coordinate system

    Directory of Open Access Journals (Sweden)

    Ap Kuiroukidis

    2018-01-01

    Full Text Available We consider a generalized Grad–Shafranov equation (GGSE in a triangularity-deformed axisymmetric toroidal coordinate system and solve it numerically for the generic case of ITER-like and JET-like equilibria with non-parallel flow. It turns out that increase of the triangularity improves confinement by leading to larger values of the toroidal beta and the safety factor. This result is supported by the application of a criterion for linear stability valid for equilibria with flow parallel to the magnetic field. Also, the parallel flow has a weaker stabilizing effect.

  3. Solution of two energy-group neutron diffusion equation by triangular elements

    International Nuclear Information System (INIS)

    Correia Filho, A.

    1981-01-01

    The application of the triangular finite elements of first order in the solution of two energy-group neutron diffusion equation in steady-state conditions is aimed at. The EFTDN (triangular finite elements in neutrons diffusion) computer code in FORTRAN IV language is developed. The discrete formulation of the diffusion equation is obtained applying the Galerkin method. The power method is used to solve the eigenvalues' problem and the convergence is accelerated through the use of Chebshev polynomials. For the equation systems solution the Gauss method is applied. The results of the analysis of two test-problems are presented. (Author) [pt

  4. Enhanced Light Extraction From Triangular GaN-Based Light-Emitting Diodes

    OpenAIRE

    J. Y. Kim; M. K. Kwon; J. P. Kim; S. J. Park

    2007-01-01

    This study investigated the characteristics of a triangular light-emitting diode (LED) and compared it to a standard quadrangular LED. The total radiant flux from the packaged triangular LED increased by 48% and 24% at input currents of 20 and 100 mA, respectively, compared to that of a quadrangular LED which was grown on patterned sapphire substrate. In light far-field beam distribution, the light extraction in the horizontal direction of the LED was much higher than that of the quadrangular...

  5. Triangular metal wedges for subwavelength plasmon-polariton guiding at telecom wavelengths

    DEFF Research Database (Denmark)

    Boltasseva, Alexandra; Volkov, V.S.; Nielsen, Rasmus Bundgaard

    2008-01-01

    We report on subwavelength plasmon-polariton guiding by triangular metal wedges at telecom wavelengths. A high-quality fabrication procedure for making gold wedge waveguides, which is also mass- production compatible offering large-scale parallel fabrication of plasmonic components, is developed....... Using scanning near-field optical imaging at the wavelengths in the range of 1.43 - 1.52 µm, we demonstrate low-loss (propagation length ~ 120 µm) and well-confined (mode width ≅ 1.3 µm) wedge plasmon-polariton guiding along triangular 6-µm-high and 70.5°- angle gold wedges. Experimental observations...

  6. Robust band gap and half-metallicity in graphene with triangular perforations

    DEFF Research Database (Denmark)

    Gregersen, Søren Schou; Power, Stephen; Jauho, Antti-Pekka

    2016-01-01

    . The inclusion of spin polarization within a mean-field Hubbard approach gives rise to a large overall magnetic moment at each antidot due to the sublattice imbalance imposed by the triangular geometry. Half-metallic behavior arises from the formation of spin-split dispersive states near the Fermi energy...... disorders. Here we study a rectangular array of triangular antidots with zigzag edge geometries and show that their band gap behavior qualitatively differs from the standard behavior which is exhibited, e.g., by rectangular arrays of armchair-edged triangles. In the spin unpolarized case, zigzag......, and furthermore, of exploiting the strong spin dependence of the system for spintronic applications....

  7. Colloid Titration--A Rapid Method for the Determination of Charged Colloid.

    Science.gov (United States)

    Ueno, Keihei; Kina, Ken'yu

    1985-01-01

    "Colloid titration" is a volumetric method for determining charged polyelectrolytes in aqueous solutions. The principle of colloid titration, reagents used in the procedure, methods of endpoint detection, preparation of reagent solutions, general procedure used, results obtained, and pH profile of colloid titration are considered. (JN)

  8. The Acid-Base Titration of a Very Weak Acid: Boric Acid

    Science.gov (United States)

    Celeste, M.; Azevedo, C.; Cavaleiro, Ana M. V.

    2012-01-01

    A laboratory experiment based on the titration of boric acid with strong base in the presence of d-mannitol is described. Boric acid is a very weak acid and direct titration with NaOH is not possible. An auxiliary reagent that contributes to the release of protons in a known stoichiometry facilitates the acid-base titration. Students obtain the…

  9. Acidity titration curves - a versatile tool for the characterisation of acidic mine waste water

    International Nuclear Information System (INIS)

    Fyson, A.

    2000-01-01

    Acidity titrations with NaOH are valuable tools for characterisation of acidic mine waters. - Titrations can be used to estimate metal concentrations. - Titrations can be carried out in the field, minimising changes in water chemistry due to sample handling time and procedure. (orig.)

  10. 26 CFR 1.1032-2 - Disposition by a corporation of stock of a controlling corporation in certain triangular...

    Science.gov (United States)

    2010-04-01

    ... gain or loss on its exchange of P stock as consideration in a forward triangular merger, a triangular C... sections 368(a)(1)(A) and (a)(2)(D) apply. (b) No gain or loss recognized on the use of P stock. Under...)(1)(A) and (a)(2)(D) apply. (b) Gain or loss recognized by S on the use of its P stock. Under...

  11. Efficient Linear and Non-Linear Finite Element Formulation using a New Local Enhancement of Displacement Fields for Triangular Elements

    DEFF Research Database (Denmark)

    Damkilde, Lars; Pedersen, Ronnie

    2012-01-01

    This paper describes a new triangular plane element which can be considered as a linear strain triangular element (LST) extended with incompatible displacement modes. The extended element will have a full cubic interpolation of strains and stresses. The extended LST-element is connected with other...

  12. The effects of linear accelerations on the maximum heat transfer capacity of micro pipes with triangular grooves

    International Nuclear Information System (INIS)

    Shokouhmand, H.; Kahrobaian, A.; Tabandeh, N.; Jalilvand, A.

    2002-01-01

    Micro heat pipes are widely used for the thermal control of spacecraft and their electronic components. In this paper the influence of linear accelerations in micro grooves has been studied. A mathematical model for predicating the minimum meniscus radius and the maximum heat transport in triangular groove under the influence of linear acceleration is presented and method for determining the theoretical minimum meniscus radius is developed. It is shown that both, the direction and the magnitude of the acceleration have a great effect upon heat transfer capability of micro heat pipes. The analysis presented here provides a mechanism where by the groove geometry can be optimized with respect to the length of the heat pipe and direction and magnitude of linear acceleration

  13. Box-triangular multiobjective linear programs for resource allocation with application to load management and energy market problems

    International Nuclear Information System (INIS)

    Ekel, P.Y.; Galperin, E.A.

    2003-01-01

    Models for multicriteria resource allocation are constructed with the specific box-triangular structure of a feasible region. The method of balance set equations is extended for the satisfaction level representation of the cost function space including the case of linearly dependent cost functions. On this basis, different goal criteria on the balance set are investigated for linear cases. Procedures for determining the balance set and finding goal-optimal Pareto solutions are illustrated on examples. The results of the paper are of universal character and can find wide applications in allocating diverse types of resources on the multiobjective basis in planning and control of complex systems including load management and energy market problems. (Author)

  14. Tight-binding electrons on triangular and kagome lattices under staggered modulated magnetic fields: quantum Hall effects and Hofstadter butterflies

    Energy Technology Data Exchange (ETDEWEB)

    Li Juan; Wang Yifei; Gong Changde, E-mail: yfwang_nju@hotmail.com [Center for Statistical and Theoretical Condensed Matter Physics, and Department of Physics, Zhejiang Normal University, Jinhua 321004 (China)

    2011-04-20

    We consider the tight-binding models of electrons on a two-dimensional triangular lattice and kagome lattice under staggered modulated magnetic fields. Such fields have two components: a uniform-flux part with strength {phi}, and a staggered-flux part with strength {Delta}{phi}. Various properties of the Hall conductances and Hofstadter butterflies are studied. When {phi} is fixed, variation of {Delta}{phi} leads to the quantum Hall transitions and Chern numbers of Landau subbands being redistributed between neighboring pairs. The energy spectra with nonzero {Delta}{phi}s have similar fractal structures but quite different energy gaps compared with the original Hofstadter butterflies of {Delta}{phi} = 0. Moreover, the fan-like structure of Landau levels in the low magnetic field region is also modified appreciably by {Delta}{phi}.

  15. Representation and Reconstruction of Triangular Irregular Networks with Vertical Walls

    NARCIS (Netherlands)

    Gorte, B.G.H.; Lesparre, J.

    2012-01-01

    Point clouds obtained by aerial laser scanning are a convenient input source for high resolution 2.5d elevation models, such as the Dutch AHN-2. More challenging is the fully automatic reconstruction of 3d city models. An actual demand for a combined 2.5d terrain and 3d city model for an urban

  16. A simple method for understanding the triangular growth patterns of transition metal dichalcogenide sheets

    Directory of Open Access Journals (Sweden)

    Siya Zhu

    2015-10-01

    Full Text Available Triangular nanoflake growth patterns have been commonly observed in synthesis of transition metal dichalcogenide sheets and their hybrid structures. Triangular nanoflakes not only show exceptional properties, but also can serve as building blocks for two or three dimensional structures. In this study, taking the MoS2 system as a test case, we propose a Matrix method to understand the mechanism of such unique growth pattern. Nanoflakes with different edge types are mathematically described with configuration matrices, and the total formation energy is calculated as the sum of the edge formation energies and the chemical potentials of sulfur and molybdenum. Based on energetics, we find that three triangular patterns with the different edge configurations are energetically more favorable in different ranges of the chemical potential of sulfur, which are in good agreement with experimental observations. Our algorithm has high efficiency and can deal with nanoflakes in microns which are beyond the ability of ab-initio method. This study not only elucidates the mechanism of triangular nanoflake growth patterns in experiment, but also provides a clue to control the geometric configurations in synthesis.

  17. 76 FR 28890 - Treatment of Property Used To Acquire Parent Stock or Securities in Certain Triangular...

    Science.gov (United States)

    2011-05-19

    ... is $100x, such that there is a no built-in gain or loss in the FT stock. FS has earnings and profits... Internal Revenue Service 26 CFR Part 1 RIN 1545-BG96 Treatment of Property Used To Acquire Parent Stock or... treatment of property used to acquire parent stock or securities in certain triangular reorganizations...

  18. The cone phase of liquid crystals: Triangular lattice of double-tilt ...

    Indian Academy of Sciences (India)

    physics pp. 277–283. The cone phase of liquid crystals: Triangular lattice of double-tilt cylinders. YASHODHAN HATWALNE and N V MADHUSUDANA. Raman Research Institute, C. V. ..... [19] D R Nelson, in Observation, prediction and simulation of phase transitions in complex fluids edited by M Baus, L F Rull and J-P ...

  19. 26 CFR 1.358-6 - Stock basis in certain triangular reorganizations.

    Science.gov (United States)

    2010-04-01

    ... corporation on the exchange of property for the assets or stock of a target corporation in a reorganization...) Definitions of triangular reorganizations. This section applies to the following reorganizations (which are... percentage of T stock not acquired in the transaction is determined by taking into account the fair market...

  20. Counting irreducible representations of large degree of the upper triangular groups

    OpenAIRE

    Le, Tung

    2009-01-01

    Let $U_n(q)$ be the upper triangular group of degree $n$ over the finite field $\\F_q$ with $q$ elements. In this paper, we present constructions of large degree ordinary irreducible representations of $U_n(q)$ where $n\\geq 7$, and then determine the number of irreducible representations of largest, second largest and third largest degrees.

  1. Nusselt Number Correlation for Vertical Tubes with Inverted Triangular Fins under Natural Convection

    Directory of Open Access Journals (Sweden)

    Byeong Dong Kang

    2017-08-01

    Full Text Available Vertical tubes with inverted triangular fins under natural convection are investigated experimentally. The thermal resistances of tubes with inverted triangular fins are measured for various fin numbers, fin heights, and heat inputs. A Nusselt number correlation that best predicts the measured thermal resistances is proposed. The proposed correlation is applicable to the following conditions: Rayleigh numbers of 1000–125,000, fin height to fin length ratios of 0.2–0.6, and fin numbers of 9–72. Finally, a contour map of the thermal resistances calculated from the proposed correlation for various fin thicknesses and fin numbers is presented. The contour map shows that there exist optimal values of the fin thickness and fin number at which the thermal resistance of the inverted-triangular-finned tube is minimized. Therefore, the proposed correlation enables a search for the optimal dimensions and has potential to be used in the designing of inverted-triangular-finned tubes of various cooling devices.

  2. Synthesis of circular and triangular gold nanorings with tunable optical properties

    KAUST Repository

    Lin, Xiaoying

    2017-08-24

    This communication describes a robust wet-chemical synthetic strategy for the preparation of monodispersed circular and triangular gold nanorings. The localized surface plasmon resonance of the nanorings can be tuned by controlling the outer diameter and ridge thickness of the nanorings.

  3. Theoretical study of two-element array of equilateral triangular patch ...

    Indian Academy of Sciences (India)

    The radiation characteristics of a two-element array of equilateral triangular patch microstrip antenna on a ferrite substrate are studied theoretically by considering the presence of bias magnetic field in the direction of propagation of electromagnetic waves. It is found that the natural modes of propagation in the direction of ...

  4. Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels

    NARCIS (Netherlands)

    Herm, Z.R.; Wiers, B.M.; Mason, J.A.; van Baten, J.M.; Hudson, M.R.; Zajdel, P.; Brown, C.M.; Masciocchi, N.; Krishna, R.; Long, J.R.

    2013-01-01

    Metal-organic frameworks can offer pore geometries that are not available in zeolites or other porous media, facilitating distinct types of shape-based molecular separations. Here, we report Fe-2(BDP)(3) (BDP2- = 1,4-benzenedipyrazotate), a highly stable framework with triangular channels that

  5. Continuous weakly cancellative triangular subnorms: I. Their web-geometric properties

    Czech Academy of Sciences Publication Activity Database

    Petrík, Milan; Sarkoci, Peter

    2018-01-01

    Roč. 332, 1 February (2018), s. 93-110 ISSN 0165-0114 R&D Projects: GA ČR GJ15-07724Y Institutional support: RVO:67985807 Keywords : associativity * conditionally cancellative * continuous triangular subnorm * contour * level set * Reidemeister closure condition * weakly cancellative * web geometry Subject RIV: BA - General Mathematics Impact factor: 2.718, year: 2016

  6. Generalized contractions with triangular α-orbital admissible mapping on Branciari metric spaces

    Directory of Open Access Journals (Sweden)

    Muhammad Arshad

    2016-02-01

    Full Text Available Abstract The purpose of this paper is to generalize fixed point theorems introduced by Jleli et al. (J. Inequal. Appl. 2014:38, 2014 by using the concept of triangular α-orbital admissible mappings established in Popescu (Fixed Point Theory Appl. 2014:190, 2014. Some examples are given here to illustrate the usability of the obtained results.

  7. Chemical signals turn on guest binding through structural reconfiguration of triangular helicates

    DEFF Research Database (Denmark)

    Sørensen, Anne; Castilla, Ana M.; Ronson, Tanya K.

    2013-01-01

    Be my guest: The function of a system based on self-assembled Zn(II) complexes can be controlled by external chemical stimuli. The complexes are based on a C3 -symmetric ligand that forms a unique triangular triple helicate structure 1. Upon subcomponent substitution, 1 is able to transform into ...

  8. Fluorometric titration approach for calibration of quantity of binding site of purified monoclonal antibody recognizing epitope/hapten nonfluorescent at 340 nm.

    Science.gov (United States)

    Yang, Xiaolan; Hu, Xiaolei; Xu, Bangtian; Wang, Xin; Qin, Jialin; He, Chenxiong; Xie, Yanling; Li, Yuanli; Liu, Lin; Liao, Fei

    2014-06-17

    A fluorometric titration approach was proposed for the calibration of the quantity of monoclonal antibody (mcAb) via the quench of fluorescence of tryptophan residues. It applied to purified mcAbs recognizing tryptophan-deficient epitopes, haptens nonfluorescent at 340 nm under the excitation at 280 nm, or fluorescent haptens bearing excitation valleys nearby 280 nm and excitation peaks nearby 340 nm to serve as Förster-resonance-energy-transfer (FRET) acceptors of tryptophan. Titration probes were epitopes/haptens themselves or conjugates of nonfluorescent haptens or tryptophan-deficient epitopes with FRET acceptors of tryptophan. Under the excitation at 280 nm, titration curves were recorded as fluorescence specific for the FRET acceptors or for mcAbs at 340 nm. To quantify the binding site of a mcAb, a universal model considering both static and dynamic quench by either type of probes was proposed for fitting to the titration curve. This was easy for fitting to fluorescence specific for the FRET acceptors but encountered nonconvergence for fitting to fluorescence of mcAbs at 340 nm. As a solution, (a) the maximum of the absolute values of first-order derivatives of a titration curve as fluorescence at 340 nm was estimated from the best-fit model for a probe level of zero, and (b) molar quantity of the binding site of the mcAb was estimated via consecutive fitting to the same titration curve by utilizing such a maximum as an approximate of the slope for linear response of fluorescence at 340 nm to quantities of the mcAb. This fluorometric titration approach was proved effective with one mcAb for six-histidine and another for penicillin G.

  9. Determination of uranium by a gravimetric-volumetric titration method

    International Nuclear Information System (INIS)

    Krtil, J.

    1998-01-01

    A volumetric-gravimetric modification of a method for the determination of uranium based on the reduction of uranium to U (IV) in a phosphoric acid medium and titration with a standard potassium dichromate solution is described. More than 99% of the stoichiometric amount of the titrating solution is weighed and the remainder is added volumetrically by using the Mettler DL 40 RC Memotitrator. Computer interconnected with analytical balances collects continually the data on the analyzed samples and evaluates the results of determination. The method allows to determine uranium in samples of uranium metal, alloys, oxides, and ammonium diuranate by using aliquot portions containing 30 - 100 mg of uranium with the error of determination, expressed as the relative standard deviation, of 0.02 - 0.05%. (author)

  10. Triangular human capital flows between sending, entrepot and the rest of the world regions

    Directory of Open Access Journals (Sweden)

    DeVoretz, Don J.

    2002-01-01

    Full Text Available EnglishA model of triangular movement of highly skilled immigrants between a sendingcountry (China/India to an entrepot country (Canada and then possibly to the rest of the world isdeveloped. The question of who stays or leaves after arrival in the entrpot country is considered. Theacquisition of subsidized human capital and the ascension to citizenship by immigrants are argued tobe key conditioners that reduce the probability of staying in the entropot country. Finally, the modelpredicts if the best or the mediocre highly skilled stay or leave the entrepot country for the sendingregion or the rest of the world.FrenchUn modèle de mouvement triangulaire d'immigrants très spécialisés entre un pays émetteur (Chine/Inde et un pays entrepôt (Canada et éventuellement le reste du monde s'est développé. La question de savoir qui reste dans le pays entrepôt et qui le quitte est considérée. L'acquisition de capital humain subventionné et la naturalisation d'immigrants sont traitées comme des éléments de conditionnement clés qui réduisent la probabilité de rester dans le pays entrepôt. Enfin, le modèle prédit si, parmi les travailleurs spécialisés, ce sont les meilleurs ou les médiocres qui restent dans le pays entrepôt ou qui le quittent pour la région émettrice ou le reste du monde.

  11. Analysis of the Purity of Cetrimide by Titrations

    DEFF Research Database (Denmark)

    Andersen, Jens Enevold Thaulov; Rasmussen, Claus/Dallerup; Nielsen, Hans/Boye

    2006-01-01

    The purity of cetrimide, trimethyl tetradecyl ammonium bromide (TTAB), that is an important preservative of many cosmetic and pharmaceutical products, was determined by three independent methods of titration. Traditionally, cetrimide was analysed by an assay method of the European Pharmacopoeia (Ph...... the extraction step of the Ph. Eur.-assay method. The distribution coefficients between chloroform and water of cetrimide and the corresponding iodide species (TTAI) were thus determined as 2150 ± 50 M-1 and 68000 ± 4000 M-1, respectively....

  12. Influence of triangularity and profiles on ideal-MHD beta limits for NET

    International Nuclear Information System (INIS)

    Schultz, G.; Bondeson, A.; Troyon, F.; Roy, A.

    1990-01-01

    Ideal-MHD stability calculations are presented to show the effect of triangularity δ on the beta-limit for plasma of NET/ITER type with ellipticity κ=2 and aspect ratio A=3.7. The optimum betas are achieved as a tradeoff between n=1 ideal kink stability and stability against Mercier and ballooning (n=∞) modes. Two different types of beta-optimisations have been made to study the influence of equilibrium profiles. In one set of optimisations, the current profile is prescribed and the pressure profile is optimised. We impose current profiles that are flat in the central region and decrease monotonically to zero at the edge. For such current profiles, maximum beta is obtained for broad pressure profiles, in particular, for low q s and small triangularity. The beta-limit is independent of triangularity up to δ=0.4, but increases slightly for high triangularity, δ=0.6. In the other set of optimisations, we specify a more peaked pressure profile and optimise the current profile. Peaked pressure profiles, when combined with standard current profiles, for which the central q is flat and near unity, tend to be unstable to localised, pressure driven modes. Therefore, careful tailoring of the central current profile is required. After optimisation of the current profile the n=1 and n=∞ modes give a beta-limit for peaked pressure profiles that is almost unchanged from that for broad profiles, if the cross-section is sufficiently triangular, δ≥0.4. By contrast, in an elliptical cross-section, δ=0.0, the maximum beta decreases significantly for the peaked profiles. (author) 3 refs., 3 figs

  13. Interaction of molybdenum (6) with potassium benzyldithiocarbaminate during amperometric titration

    International Nuclear Information System (INIS)

    Galushko, S.V.; Usatenko, Yu.I.

    1975-01-01

    The paper is an amperometric study of the mechanism of interaction between molybdenum (VI) and potassium benzyl dithiocarbamate [BDTC] which was based on the use of voltamperometry, electron paramagnetic resonance, infrared spectroscopy, potentiometry and elemental analysis. In amperometric titration Mo(VI) with BDTC (pH 4-2) forms a red compound of low solubility. In more acidic media the intensity of coloration is increased and a violet hue develops. On the basis of the data obtained it is concluded that in the amperometric titration of Mo(VI) with potassium BDTC there is first formation of a Mo(VI) compound, which subsequently acquires a red colour as a result of the reduction of Mo(VI) to Mo(V). It was also established that the degree of reduction is small where titration is carried out in the range pH 4.8-0.1. Quantitative determination of Mo is performed most effectively in slightly acidic media. Mo reacts with potassium BDTC in a ratio of 1:2. (E.P.)

  14. Cell titration assay for measuring blastogenesis of bovine lymphocytes.

    Science.gov (United States)

    Baldwin, C L; Antczak, D F; Winter, A J

    1985-08-01

    The blastogenic response of bovine peripheral blood lymphocytes to phytohemagglutinin (PHA) and to microbial antigens was measured using a lymphocyte titration assay. Culture conditions, including lymphocyte concentrations, incubation periods and medium formulation, were established which produced linear or nearly linear responses over a range of cell concentrations. These conditions were established by testing lymphocytes from unimmunized cattle and from heifers infected with Brucella abortus with PHA and a B. abortus extract. Four cell concentrations in 2-fold increments were selected for measuring responses to PHA (3.125 X 10(3) to 2.5 X 10(4) cells/well) and to antigens (5.0 X 10(4) to 4.0 X 10(5) cells/well). The strength of response varied among animals and also over time for individual animals, but the titration assay allowed exponential proliferation to be distinguished from decline, which may have been due to overcrowding of microtiter wells, exhaustion of nutrients or induction of regulatory events. This assay provided a more reliable and discriminating method of evaluating lymphocyte proliferation responses than that achieved by single point assays. The displacement of the titration curves could be used to estimate the relative frequency of lymphocytes responding to antigens or mitogens.

  15. Titratable acidity of beverages influences salivary pH recovery.

    Science.gov (United States)

    Tenuta, Livia Maria Andaló; Fernández, Constanza Estefany; Brandão, Ana Carolina Siqueira; Cury, Jaime Aparecido

    2015-01-01

    A low pH and a high titratable acidity of juices and cola-based beverages are relevant factors that contribute to dental erosion, but the relative importance of these properties to maintain salivary pH at demineralizing levels for long periods of time after drinking is unknown. In this crossover study conducted in vivo, orange juice, a cola-based soft drink, and a 10% sucrose solution (negative control) were tested. These drinks differ in terms of their pH (3.5 ± 0.04, 2.5 ± 0.05, and 5.9 ± 0.1, respectively) and titratable acidity (3.17 ± 0.06, 0.57 ± 0.04 and buffering capacity kept 15 mL of each beverage in their mouth for 10 s, expectorated it, and their saliva was collected after 15, 30, 45, 60, 90, and 120 s. The salivary pH, determined using a mini pH electrode, returned to the baseline value at 30 s after expectoration of the cola-based soft drink, but only at 90 s after expectoration of the orange juice. The salivary pH increased to greater than 5.5 at 15 s after expectoration of the cola drink and at 30 s after expectoration of the orange juice. These findings suggest that the titratable acidity of a beverage influences salivary pH values after drinking acidic beverages more than the beverage pH.

  16. A rapid method for titration of ascovirus infectivity.

    Science.gov (United States)

    Han, Ningning; Chen, Zishu; Wan, Hu; Huang, Guohua; Li, Jianhong; Jin, Byung Rae

    2018-05-01

    Ascoviruses are a recently described family and the traditional plaque assay and end-point PCR assay have been used for their titration. However, these two methods are time-consuming and inaccurate to titrate ascoviruses. In the present study, a quick method for the determination of the titer of ascovirus stocks was developed based on ascovirus-induced apoptosis in infected insect cells. Briefly, cells infected with serial dilutions of virus (10 -2 -10 -10 ) for 24 h were stained with trypan blue. The stained cells were counted, and the percentage of nonviable cells was calculated. The stained cell rate was compared between virus-infected and control cells. The minimum-dilution group that had a significant difference compared with control and the maximum-dilution group that had no significant difference were selected and then compared each well of the two groups with the average stained cell rate of control. The well was marked as positive well if the stained cell rate was higher than the average stained cell rate of control wells; otherwise, the well was marked as negative wells. The percentage of positive wells were calculated according to the number of positive. Subsequently, the virus titer was calculated through the method of Reed and Muench. This novel method is rapid, simple, reproducible, accurate, and less material-consuming and eliminates the subjectivity of the other procedures for titrating ascoviruses. Copyright © 2018 Elsevier B.V. All rights reserved.

  17. Non-damaging laser therapy of the macula: Titration algorithm and tissue response

    Science.gov (United States)

    Palanker, Daniel; Lavinsky, Daniel; Dalal, Roopa; Huie, Philip

    2014-02-01

    Retinal photocoagulation typically results in permanent scarring and scotomata, which limit its applicability to the macula, preclude treatments in the fovea, and restrict the retreatments. Non-damaging approaches to laser therapy have been tested in the past, but the lack of reliable titration and slow treatment paradigms limited their clinical use. We developed and tested a titration algorithm for sub-visible and non-damaging treatments of the retina with pulses sufficiently short to be used with pattern laser scanning. The algorithm based on Arrhenius model of tissue damage optimizes the power and duration for every energy level, relative to the threshold of lesion visibility established during titration (and defined as 100%). Experiments with pigmented rabbits established that lesions in the 50-75% energy range were invisible ophthalmoscopically, but detectable with Fluorescein Angiography and OCT, while at 30% energy there was only very minor damage to the RPE, which recovered within a few days. Patients with Diabetic Macular Edema (DME) and Central Serous Retinopathy (CSR) have been treated over the edematous areas at 30% energy, using 200μm spots with 0.25 diameter spacing. No signs of laser damage have been detected with any imaging modality. In CSR patients, subretinal fluid resolved within 45 days. In DME patients the edema decreased by approximately 150μm over 60 days. After 3-4 months some patients presented with recurrence of edema, and they responded well to retreatment with the same parameters, without any clinically visible damage. This pilot data indicates a possibility of effective and repeatable macular laser therapy below the tissue damage threshold.

  18. Isothermal titration calorimetric studies of the acid-base properties of poly(N-isopropylacrylamide-co-4-vinylpyridine) cationic polyelectrolyte colloidal microgels

    International Nuclear Information System (INIS)

    Seidel, J.; Pinkrah, V.T.; Mitchell, J.C.; Chowdhry, B.Z.; Snowden, M.J.

    2004-01-01

    Isothermal titration calorimetry (ITC) and potentiometric titration were used to study the protonation properties of the 4-vinylpyridine (4-VP) moiety in cationic poly(N-isopropylacrylamide-co-4-vinylpyridine) colloidal microgels [poly(NIPAM-co-4-VP)]. Calorimetric pH titrations were performed using microgels of different 4-VP content and the influence of ionic strength and counter ions have been examined. The calorimetric titration output consists of several thermal contributions reflecting the complex nature of the interactions in the aqueous microgel dispersions. In contrast to the potentiometric results, the calorimetric titration data could not be completely described by a theoretical model solely taking into account protonation equilibria. Deviations from the proposed model correlate with swelling or shrinking of the gel particles. The calorimetric results also reveal a pronounced counter-ion effect of perchlorate compared to chloride ions. In the presence of perchlorate ions, small secondary thermal effects accompany protonation of the 4-VP moiety due, in part, to kinetically limited conformational changes in the co-polymer microgel

  19. Triangular facets of slope in the region of Tudela (Ebro Basin, Navarra, Spain); Facetas triangulares de ladera en la region de Tudela (Depresion del Ebro, Navarra, Espana)

    Energy Technology Data Exchange (ETDEWEB)

    Marin, C.; Desir, G.; Gutierrez, M.

    2009-07-01

    Some triangular slope facets are localized to the south of Bardenas Reales (central-west of Ebro Basin), elaborated on Tudela Formation deposits, Aragonian in age. Three of them have been dated by OSL resulting on ages of 35,588{+-}2,488 yr. BP, 35,355{+-}2,446 yr. BP and 40.185{+-}2,411 yr. BP. The origin of these facets is ought to an alternation between accumulation and incision phases produced by vegetation cover variation percentage. Those vegetation cover changes are estimated to be due to climatic changes. (Author) 21 refs.

  20. Representation and Reconconstruction of Triangular Irregular Networks with Vertical Walls

    Science.gov (United States)

    Gorte, B.; Lesparre, J.

    2012-06-01

    Point clouds obtained by aerial laser scanning are a convenient input source for high resolution 2.5d elevation models, such as the Dutch AHN-2. More challenging is the fully automatic reconstruction of 3d city models. An actual demand for a combined 2.5d terrain and 3d city model for an urban hydrology application led to the design of an extension to the well-known Delaunay triangulated irregular networks (TINs) as to accommodate vertical walls. In addition we introduce methods to generate and refine models adhering to our data structure. These are based on combining two approaches: a representation of the TIN using stars of vertices and triangles, together with segmenting the TIN on the basis of coplanarity of adjacent triangles. The approach is supposed to deliver the complete model including walls at the correct locations, without relying on additional map data, as these often lack completeness, actuality and accuracy, and moreover most of the time do not account for parts facades not going down to street level. However, automatic detection of height discontinuities to obtain the exact location of the walls is currently still under implementation.

  1. A new approach to flow-batch titration. A monosegmented flow titrator with coulometric reagent generation and potentiometric or biamperometric detection.

    Science.gov (United States)

    de Aquino, Emerson Vidal; Rohwedder, Jarbas José Rodrigues; Pasquini, Celio

    2006-11-01

    Monosegmented flow analysis (MSFA) has been used as a flow-batch system to produce a simple, robust, and mechanized titrator that enables true titrations to be performed without the use of standards. This paper also introduces the use of coulometry with monosegmented titration by proposing a versatile flow cell. Coulometric generation of the titrand is attractive for titrations performed in monosegmented systems, because the reagent can be added without increasing the volume of sample injected. Also, biamperomeric and potentiometric detection of titration end-points can increase the versatility of the monosegmented titrator. The cell integrates coulometric generation of the titrand with detection of end-point by potentiometry or biamperometry. The resulting titrator is a flow-batch system in which the liquid monosegment, constrained by the interfaces of the gaseous carrier stream, plays the role of a sample of known volume to be titrated. The system has been used for determination of ascorbic acid, by coulometric generation of I2 with biamperometric detection, and for determination of Fe(II), by coulometric generation of Ce(IV) with potentiometric detection of the end-point, both in feed supplements.

  2. Comparative study on triangular and quadrilateral meshes by a finite-volume method with a central difference scheme

    KAUST Repository

    Yu, Guojun

    2012-10-01

    In this article, comparative studies on computational accuracies and convergence rates of triangular and quadrilateral meshes are carried out in the frame work of the finite-volume method. By theoretical analysis, we conclude that the number of triangular cells needs to be 4/3 times that of quadrilateral cells to obtain similar accuracy. The conclusion is verified by a number of numerical examples. In addition, the convergence rates of the triangular meshes are found to be slower than those of the quadrilateral meshes when the same accuracy is obtained with these two mesh types. © 2012 Taylor and Francis Group, LLC.

  3. HEXAGA-II-120, -60, -30 two-dimensional multi-group neutron diffusion programmes for a uniform triangular mesh with arbitrary group scattering

    International Nuclear Information System (INIS)

    Woznicki, Z.

    1979-06-01

    This report presents the AGA two-sweep iterative methods belonging to the family of factorization techniques in their practical application in the HEXAGA-II two-dimensional programme to obtain the numerical solution to the multi-group, time-independent, (real and/or adjoint) neutron diffusion equations for a fine uniform triangular mesh. An arbitrary group scattering model is permitted. The report written for the users provides the description of input and output. The use of HEXAGA-II is illustrated by two sample reactor problems. (orig.) [de

  4. Talinum triangulare Whole wheat meal fortified with soy flour consumed with Talinum triangulare (gbure) soup glycemic index and the test human subjects' lipid profiles.

    Science.gov (United States)

    Emaleku, Sunday Adeola; Omueti, Olusola D; Emaleku, Godsent Oluwakemi

    2017-08-24

    Cardiovascular diseases (CVDs) and diabetes mellitus (DM) are some of the leading causes of death in the world, and diet has roles in their etiology. This research study therefore investigates the glycemic index (GI) of soy flour fortified whole wheat meal (SFFWWM) consumed with Talinum triangulare (gbure) soup and the effects of the meal on the lipid profiles of the test human subjects. The control human subjects and test human subjects were fed D-glucose (DG) and whole wheat meal (WWM) with Talinum triangulare soup respectively on the first day of the experiment, and SFFWWM with the same soup the next day (for test subjects only) after 10-12h overnight fasting. Blood glucose levels of the subjects were taken before and 2h after meals' consumption at 30min interval and blood samples collected for lipid profiles evaluations. The result of the study showed that; SFFWWM consumed with Talinum trianguilare soup has a non-significant lower GI than WWM consumed with the same soup, but a significant lower GI than DG at (Pflour would reduce the risk factors of CVDs and DM, the diseases recently claiming thousands of today. Copyright © 2017 Diabetes India. Published by Elsevier Ltd. All rights reserved.

  5. Titration calorimetry of surfactant–drug interactions: Micelle formation and saturation studies

    International Nuclear Information System (INIS)

    Waters, Laura J.; Hussain, Talib; Parkes, Gareth M.B.

    2012-01-01

    Highlights: ► Isothermal titration calorimetry can be used to monitor the saturation of micelles with pharmaceutical compounds. ► The number of drug molecules per micelle varies depending on the drug used and the temperature of the calorimeter. ► The change in enthalpy for the saturation of micelles with drugs can be endothermic or exothermic. ► The critical micellar concentration of an anionic surfactant (SDS) does not appear to vary in the presence of drugs. - Abstract: Isothermal titration calorimetry (ITC) was employed to monitor the addition of five model drugs to anionic surfactant based micelles, composed of sodium dodecyl sulfate (SDS), through to the point at which they were saturated with drug. Analysis of the resultant data using this newly developed method has confirmed the suitability of the technique to acquire such data with saturation limits established in all cases. Values for the point at which saturation occurred ranged from 17 molecules of theophylline per micelle at T = 298 K up to 63 molecules of caffeine per micelle at 310 K. Micellar systems can be disrupted by the presence of additional chemicals, such as the drugs used in this study, therefore a separate investigation was undertaken to determine the critical micellar concentration (CMC) for SDS in the presence of each drug at T = 298 K and 310 K using ITC. In the majority of cases, there was no appreciable alteration to the CMC of SDS with drug present.

  6. Determination of paraquat in water samples using a sensitive fluorescent probe titration method.

    Science.gov (United States)

    Yao, Feihu; Liu, Hailong; Wang, Guangquan; Du, Liming; Yin, Xiaofen; Fu, Yunlong

    2013-06-01

    Paraquat (PQ), a nonselective herbicide, is non-fluorescent in aqueous solutions. Thus, its determination through direct fluorescent methods is not feasible. The supramolecular inclusion interaction of PQ with cucurbit[7]uril was studied by a fluorescent probe titration method. Significant quenching of the fluorescence intensity of the cucurbit[7]uril-coptisine fluorescent probe was observed with the addition of PQ. A new fluorescent probe titration method with high selectivity and sensitivity at the ng/mL level was developed to determine PQ in aqueous solutions with good precision and accuracy based on the significant quenching of the supramolecular complex fluorescence intensity. The proposed method was successfully used in the determination of PQ in lake water, tap water, well water, and ditch water in an agricultural area, with recoveries of 96.73% to 105.77%. The fluorescence quenching values (deltaF) showed a good linear relationship with PQ concentrations from 1.0 x 10(-8) to 1.2 x 10(-5) mol/L with a detection limit of 3.35 x 10(-9) mol/L. In addition, the interaction models of the supramolecular complexes formed between the host and the guest were established using theoretical calculations. The interaction mechanism between the cucurbit[7]uril and PQ was confirmed by 1H NMR spectroscopy.

  7. Titratable acidity of beverages influences salivary pH recovery

    Directory of Open Access Journals (Sweden)

    Livia Maria Andaló TENUTA

    2015-01-01

    Full Text Available A low pH and a high titratable acidity of juices and cola-based beverages are relevant factors that contribute to dental erosion, but the relative importance of these properties to maintain salivary pH at demineralizing levels for long periods of time after drinking is unknown. In this crossover study conducted in vivo, orange juice, a cola-based soft drink, and a 10% sucrose solution (negative control were tested. These drinks differ in terms of their pH (3.5 ± 0.04, 2.5 ± 0.05, and 5.9 ± 0.1, respectively and titratable acidity (3.17 ± 0.06, 0.57 ± 0.04 and < 0.005 mmols OH- to reach pH 5.5, respectively. Eight volunteers with a normal salivary flow rate and buffering capacity kept 15 mL of each beverage in their mouth for 10 s, expectorated it, and their saliva was collected after 15, 30, 45, 60, 90, and 120 s. The salivary pH, determined using a mini pH electrode, returned to the baseline value at 30 s after expectoration of the cola-based soft drink, but only at 90 s after expectoration of the orange juice. The salivary pH increased to greater than 5.5 at 15 s after expectoration of the cola drink and at 30 s after expectoration of the orange juice. These findings suggest that the titratable acidity of a beverage influences salivary pH values after drinking acidic beverages more than the beverage pH.

  8. Fluidelastic forces in a triangular tube bundle subjected to two-phase cross flow

    International Nuclear Information System (INIS)

    Mureithi, N.; Shahriary, S.; Sommier, E.; Pettigrew, M.

    2006-01-01

    Despite the discovery of fluidelastic instability in two-phase flows nearly three decades ago, little is known about the underlying mechanisms when two fluid phases are involved. Current knowledge (the state of the art) is based on the assumption that the nature of fluidelastic instability, and in particular the underlying fluid forces and excitation mechanisms are very similar if not identical to their single phase flow counterparts. There is, however, clear evidence to the contrary. Recent measurements by Mureithi et al.(2002) have shown that the fluid force field can be drastically different for two-phase flows. In particular, the force field is not a simple function of the reduced flow velocity U/fD. In the work reported here, the quasi-static fluid force field is measured in a rotated triangular tube bundle for a series of void fractions and flow velocities. It is found that the reduced velocity U/fD, where U is the homogeneous mixture velocity, does not collapse the data for different void fractions (or correspondingly, fluid densities). The forces are strongly dependent on void fraction, flow rates and relative tube positions. The steady drag increases with void fraction up to approximately 60% void fraction and then gradually decreases at higher void fractions. Besides the force magnitudes, the derivatives of the forces with respect to tube positions also vary significantly with void fraction. These derivatives are particularly important since they represent inter-tube interaction and hence directly affect the stability behavior. The present work uncovers some of the complexity of the fluid force field in two-phase flows. The data are valuable since they are the necessary inputs to the class of quasi-static and quasi-steady fluidelastic instability theoretical models. The application of these models is the longer-term goal of the present work. To the authors' knowledge, this is the first time that the quasi-static force field for two-phase flows is reported

  9. Multiple Fano-Like MIM Plasmonic Structure Based on Triangular Resonator for Refractive Index Sensing.

    Science.gov (United States)

    Jankovic, Nikolina; Cselyuszka, Norbert

    2018-01-19

    In this paper, we present a Fano metal-insulator-metal (MIM) structure based on an isosceles triangular cavity resonator for refractive index sensing applications. Due to the specific feeding scheme and asymmetry introduced in the triangular cavity, the resonator exhibits four sharp Fano-like resonances. The behavior of the structure is analyzed in detail and its sensing capabilities demonstrated through the responses for various refractive indices. The results show that the sensor has very good sensitivity and maximal figure of merit (FOM) value of 3.2 × 10⁵. In comparison to other similar sensors, the proposed one has comparable sensitivity and significantly higher FOM, which clearly demonstrates its high sensing potential.

  10. Edge structures and properties of triangular antidots in single-layer MoS2

    KAUST Repository

    Gan, Li Yong

    2016-08-30

    Density functional theory and experiments are employed to shed light on the edge structures of antidots in O etched single-layer MoS2. The equilibrium morphology is found to be the zigzag Mo edge with each Mo atom bonded to two O atoms, in a wide range of O chemical potentials. Scanning electron microscopy shows that the orientation of the created triangular antidots is opposite to the triangular shape of the single-layer MoS2 samples, in agreement with the theoretical predictions. Furthermore, edges induced by O etching turn out to be p-doped, suggesting an effective strategy to realize p-type MoS2 devices. Published by AIP Publishing.

  11. H32+ molecular ion in a strong magnetic field: Triangular configuration

    International Nuclear Information System (INIS)

    Lopez Vieyra, J.C.; Turbiner, A.V.

    2002-01-01

    The existence of the molecular ion H 3 2+ in a magnetic field in a triangular configuration is revised. A variational method with an optimization of the form of the vector potential (gauge fixing) is used. It is shown that in the range of magnetic fields 10 8 11 G the system (pppe), with the protons forming an equilateral triangle perpendicular to the magnetic line, has a well-pronounced minimum in the total energy. This configuration is unstable under the decays (H atom)+p+p and H 2 + +p. The triangular configuration of H 3 2+ complements H 3 2+ in the linear configuration that exists for B > or approx. 10 10 G

  12. Research of photonic-assisted triangular-shaped pulses generation based on quadrupling RF modulation

    Science.gov (United States)

    Yuan, Jin; Ning, Ti-gang; Li, Jing; Li, Yue-qin; Chen, Hong-yao; Zhang, Chan

    2015-05-01

    We propose an approach to generate optical triangular-shaped pulse train with tunable repetition rate using quadrupling radio frequency (RF) modulation and optical grating dispersion-induced power fading. In this work, a piece of chirped fiber Bragg grating (FBG) is employed as the dispersive media to remove the undesired 8th harmonic in optical intensity. Thus, the generated harmonics of optical intensity can be corresponding to the first two Fourier components of typical periodic triangular pulses. This work also analyzes the impacts of the extinction ratio and the bias voltage drift on the harmonic distortion suppression ratio. After that, the value of the extinction ratio and the range of the bias voltage drift can be obtained. The advantage of this proposal is that it can generate high order frequency-multiplexed optical pulses train which can be applied in all optical signal processing and other fields.

  13. Measured and predicted root-mean-square errors in square and triangular antenna mesh facets

    Science.gov (United States)

    Fichter, W. B.

    1989-01-01

    Deflection shapes of square and equilateral triangular facets of two tricot-knit, gold plated molybdenum wire mesh antenna materials were measured and compared, on the basis of root mean square (rms) differences, with deflection shapes predicted by linear membrane theory, for several cases of biaxial mesh tension. The two mesh materials contained approximately 10 and 16 holes per linear inch, measured diagonally with respect to the course and wale directions. The deflection measurement system employed a non-contact eddy current proximity probe and an electromagnetic distance sensing probe in conjunction with a precision optical level. Despite experimental uncertainties, rms differences between measured and predicted deflection shapes suggest the following conclusions: that replacing flat antenna facets with facets conforming to parabolically curved structural members yields smaller rms surface error; that potential accuracy gains are greater for equilateral triangular facets than for square facets; and that linear membrane theory can be a useful tool in the design of tricot knit wire mesh antennas.

  14. Tailoring graphene magnetism by zigzag triangular holes: A first-principles thermodynamics study

    Directory of Open Access Journals (Sweden)

    Muhammad Ejaz Khan

    2016-03-01

    Full Text Available We discuss the thermodynamic stability and magnetic property of zigzag triangular holes (ZTHs in graphene based on the results of first-principles density functional theory calculations. We find that ZTHs with hydrogen-passivated edges in mixed sp2/sp3 configurations (z211 could be readily available at experimental thermodynamic conditions, but ZTHs with 100% sp2 hydrogen-passivation (z1 could be limitedly available at high temperature and ultra-high vacuum conditions. Graphene magnetization near the ZTHs strongly depends on the type and the size of the triangles. While metallic z1 ZTHs exhibit characteristic edge magnetism due to the same-sublattice engineering, semiconducting z211 ZTHs do show characteristic corner magnetism when the size is small <2 nm. Our findings could be useful for experimentally tailoring metal-free carbon magnetism by simply fabricating triangular holes in graphene.

  15. Effects of symmetry reduction in two-dimensional square and triangular lattices

    Science.gov (United States)

    Trifonov, T.; Marsal, L. F.; Rodríguez, A.; Pallarès, J.; Alcubilla, R.

    2004-06-01

    We investigate the absolute photonic band gap (PBG) formation in two-dimensional (2-D) photonic crystals designed using symmetry reduction approach. The lattice symmetry, shape and orientation of dielectric scatterers affect the photonic gap parameters. We use symmetry reduction, achieved either by including additional rods into the lattice unit cell or by reorienting noncircular scatterers to engineer the photonic band gaps in 2-D square and triangular structures. The case of air rods drilled into silicon background is considered. We show that for square structures symmetry reduction can be an effective way to enlarge the absolute PBG, but for triangular lattices any modification of the crystal structure considerably reduces the absolute PBG width. We also discuss the practical technological feasibility of the proposed structures.

  16. Uniform Strain Elements for Three-Node Triangular and Four-Node Tetrahedral Meshes

    Energy Technology Data Exchange (ETDEWEB)

    Dohrmann, C.R.; Heinstein, M.W.; Jung, J.; Key, S.W.; Witkowski, W.R.

    1999-03-02

    A family of uniform strain elements is presented for three-node triangular and four-node tetrahedral meshes. The elements use the linear interpolation functions of the original mesh, but each element is associated with a single node. As a result, a favorable constraint ratio for the volumetric response is obtained for problems in solid mechanics. The uniform strain elements do not require the introduction of additional degrees of freedom and their performance is shown to be significantly better than that of three-node triangular or four-node tetrahedral elements. In addition, nodes inside the boundary of the mesh are observed to exhibit superconvergent behavior for a set of example problems.

  17. Edge structures and properties of triangular antidots in single-layer MoS{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Gan, Li-Yong, E-mail: ganly@swjtu.edu.cn, E-mail: iamyccheng@njtech.edu.cn, E-mail: udo.schwingenschlogl@kaust.edu.sa [Key Laboratory of Advanced Technology of Materials (Ministry of Education), Superconductivity and New Energy R& D Center, Southwest Jiaotong University, Chengdu, Sichuan 610031 (China); Cheng, Yingchun, E-mail: ganly@swjtu.edu.cn, E-mail: iamyccheng@njtech.edu.cn, E-mail: udo.schwingenschlogl@kaust.edu.sa; Huang, Wei [Key Laboratory of Flexible Electronics (KLOFE) and Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials - SICAM, Nanjing Tech University - NanjingTech, 30 South Puzhu Road, Nanjing 211816 (China); Schwingenschlögl, Udo, E-mail: ganly@swjtu.edu.cn, E-mail: iamyccheng@njtech.edu.cn, E-mail: udo.schwingenschlogl@kaust.edu.sa [Physical Science and Engineering Division (PSE), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900 (Saudi Arabia); Yao, Yingbang [Advanced Nanofabrication and Imaging Core Lab, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900 (Saudi Arabia); School of Materials and Energy, Guangdong University of Technology, Guangdong 510006 (China); Zhao, Yong [Key Laboratory of Advanced Technology of Materials (Ministry of Education), Superconductivity and New Energy R& D Center, Southwest Jiaotong University, Chengdu, Sichuan 610031 (China); School of Physical Science and Technology, Southwest Jiaotong University, Chengdu, 610031 Sichuan (China); Zhang, Xi-xiang [Physical Science and Engineering Division (PSE), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900 (Saudi Arabia); Advanced Nanofabrication and Imaging Core Lab, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900 (Saudi Arabia)

    2016-08-29

    Density functional theory and experiments are employed to shed light on the edge structures of antidots in O etched single-layer MoS{sub 2}. The equilibrium morphology is found to be the zigzag Mo edge with each Mo atom bonded to two O atoms, in a wide range of O chemical potentials. Scanning electron microscopy shows that the orientation of the created triangular antidots is opposite to the triangular shape of the single-layer MoS{sub 2} samples, in agreement with the theoretical predictions. Furthermore, edges induced by O etching turn out to be p-doped, suggesting an effective strategy to realize p-type MoS{sub 2} devices.

  18. Controllable galvanic synthesis of triangular Ag-Pd alloy nanoframes for efficient electrocatalytic methanol oxidation.

    Science.gov (United States)

    Xu, Lin; Luo, Zhimin; Fan, Zhanxi; Yu, Sijia; Chen, Junze; Liao, Yusen; Xue, Can

    2015-06-08

    Triangular Ag-Pd alloy nanoframes were successfully synthesized through galvanic replacement by using Ag nanoprisms as sacrificial templates. The ridge thickness of the Ag-Pd alloy nanoframes could be readily tuned by adjusting the amount of the Pd source during the reaction. These obtained triangular Ag-Pd alloy nanoframes exhibit superior electrocatalytic activity for the methanol oxidation reaction as compared with the commercial Pd/C catalyst due to the alloyed Ag-Pd composition as well as the hollow-framed structures. This work would be highly impactful in the rational design of future bimetallic alloy nanostructures with high catalytic activity for fuel cell systems. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Linear-phase approximation in the triangular facet near-field physical optics computer program

    Science.gov (United States)

    Imbriale, W. A.; Hodges, R. E.

    1990-01-01

    Analyses of reflector antenna surfaces use a computer program based on a discrete approximation of the radiation integral. The calculation replaces the actual surface with a triangular facet representation; the physical optics current is assumed to be constant over each facet. Described here is a method of calculation using linear-phase approximation of the surface currents of parabolas, ellipses, and shaped subreflectors and compares results with a previous program that used a constant-phase approximation of the triangular facets. The results show that the linear-phase approximation is a significant improvement over the constant-phase approximation, and enables computation of 100 to 1,000 lambda reflectors within a reasonable time on a Cray computer.

  20. Statistical analysis of differential potentiometric precipitation titration data for a mixture of three heterovalent ions using linear characteristics

    International Nuclear Information System (INIS)

    Mar'yanov, B.M.; Zarubin, A.G.; Shumar, S.V.

    2003-01-01

    A computer-based method is proposed for data processing in the successive potentiometric precipitation titration of a three-component mixture of differently charged ions. The method was tested on the data of the titration of an artificial solution containing a mixture of Cd(II), Hg(II), and Te(IV) with diethyldithiocarbamate using a chalcogenide Cd-selective or a glassy-carbon indicator electrodes and was used for an analysis of the main components in a semiconductor material, namely, a solid solution of mercury and cadmium tellurides. For concentrations of test ions in the model solution from 7.5 x 10 -3 to 3 x 10 -4 M, the RSD value varies from 0.01 to 0.3; the determination error does not exceed 6 %. The RSD value for the semiconductor alloy lies in the range from 0.002 to 0.01 [ru

  1. Recurrence Relations and Generating Functions of the Sequence of Sums of Corresponding Factorials and Triangular Numbers

    Directory of Open Access Journals (Sweden)

    Romer C. Castillo

    2015-11-01

    Full Text Available This study established some recurrence relations and exponential generating functions of the sequence of factoriangular numbers. A factoriangular number is defined as a sum of corresponding factorial and triangular number. The proofs utilize algebraic manipulations with some known results from calculus, particularly on power series and Maclaurin’s series. The recurrence relations were found by manipulating the formula defining a factoringular number while the ascertained exponential generating functions were in the closed form.

  2. Determination of Constructs and Dimensions of Employability Skills Based Work Performance Prediction: A Triangular Approach

    OpenAIRE

    Rahmat, Normala; Buntat, Yahya; Ayub, Abdul Rahman

    2015-01-01

    The level of the employability skills of the graduates as determined by job role and mapped to the employability skills, which correspond to the requirement of employers, will have significant impact on the graduates’ job performance. The main objective of this study was to identify the constructs and dimensions of employability skills, which can predict the work performance of electronic polytechnic graduate in electrical and electronics industry. A triangular qualitative approach was used i...

  3. Equivalent formulae of stress Green's functions for a constant slip rate on a triangular fault

    Science.gov (United States)

    Feng, Xi; Zhang, Haiming

    2017-06-01

    We present an equivalent form of the expressions first obtained by Tada (Geophys J Int 164:653-669, 2006. doi: 10.1111/j.1365-246X.2006.03868.x), which represents the transient stress response of an infinite, homogeneous and isotropic medium to a constant slip rate on a triangular fault that continues perpetually after the slip onset. Our results are simpler than Tada's, and the corresponding codes have a higher running speed.

  4. Residuated Logics based on Strict Triangular Norms with an Involutive Negation

    Czech Academy of Sciences Publication Activity Database

    Cintula, Petr; Klement, E.P.; Mesiar, R.; Navara, M.

    2006-01-01

    Roč. 52, č. 3 (2006), s. 269-282 ISSN 0942-5616 R&D Projects: GA MŠk 1M0545 Grant - others:Grantová agentura SR(SK) VEGA 1/3006/06; COSPAL(EU) IST-2004-71567 Keywords : fuzzy logic * involutive negation * BL-algebra * variety * triangular norm * hamacher product Subject RIV: BA - General Mathematics Impact factor: 0.629, year: 2006

  5. A triangular Eunotia (Bacillariophyceae in southeastern Brazil: Eunotia trigona sp. nov.

    Directory of Open Access Journals (Sweden)

    André Fuhrmann

    2013-12-01

    Full Text Available We report a new diatom species for the Atlantic Forest of Brazil. The species, designated Eunotia trigona Fuhrmann, Metzeltin & Tremarin sp. nov., is also new to science. It was found on moss in the Itatiaia mountain range in the state of São Paulo. Among the Eunotia taxa, E. trigona is distinguished by its unusual (perhaps unique triangular-shaped valve, similar to those found in a few species of the genera Staurosira and Staurosirella.

  6. Triangular Ag-Pd alloy nanoprisms: rational synthesis with high-efficiency for electrocatalytic oxygen reduction

    Science.gov (United States)

    Xu, Lin; Luo, Zhimin; Fan, Zhanxi; Zhang, Xiao; Tan, Chaoliang; Li, Hai; Zhang, Hua; Xue, Can

    2014-09-01

    We report the generation of triangular Ag-Pd alloy nanoprisms through a rationally designed synthetic strategy based on silver nanoprisms as sacrificial templates. The galvanic replacement between Ag nanoprisms and H2PdCl4 along with co-reduction of Ag+/Pd2+ is responsible for the formation of final prismatic Ag-Pd alloy nanostructures. Significantly, these Ag-Pd alloy nanoprisms exhibited superior electrocatalytic activity for the oxygen reduction reaction (ORR) as compared with the commercial Pd/C catalyst. Such a high catalytic activity is attributed to not only the alloyed Ag-Pd composition but also the dominant {111} facets of the triangular Ag-Pd nanoprisms. This work demonstrates the rational design of bimetallic alloy nanostructures with control of selective crystal facets that are critical to achieve high catalytic activity for fuel cell systems.We report the generation of triangular Ag-Pd alloy nanoprisms through a rationally designed synthetic strategy based on silver nanoprisms as sacrificial templates. The galvanic replacement between Ag nanoprisms and H2PdCl4 along with co-reduction of Ag+/Pd2+ is responsible for the formation of final prismatic Ag-Pd alloy nanostructures. Significantly, these Ag-Pd alloy nanoprisms exhibited superior electrocatalytic activity for the oxygen reduction reaction (ORR) as compared with the commercial Pd/C catalyst. Such a high catalytic activity is attributed to not only the alloyed Ag-Pd composition but also the dominant {111} facets of the triangular Ag-Pd nanoprisms. This work demonstrates the rational design of bimetallic alloy nanostructures with control of selective crystal facets that are critical to achieve high catalytic activity for fuel cell systems. Electronic supplementary information (ESI) available. See DOI: 10.1039/c4nr03600j

  7. A novel amplitude modulated triangular carrier gain linearization technique for SPWM inverter

    OpenAIRE

    Ramkumar Subburam; Jeevananthan Seenithangam; Kamaraj Vijayarajan

    2009-01-01

    This paper presents a new method to extend the linearity of the sinusoidal pulse width modulation (SPWM) to full range of the pulse dropping region. The proposed amplitude modulated triangular carrier PWM method (AMTCPWM) increases the dynamic range of the SPWM control and eliminates the need of nonlinear modulation in the pulse dropping region to reach the square wave boundary. The novel method combines the spectral quality of SPWM with the efficient single-mode linear control. A simple anal...

  8. Fluxons in a triangular set of coupled long Josephson junctions

    Energy Technology Data Exchange (ETDEWEB)

    Yukon, Stanford P., E-mail: yukon@alum.mit.edu [Air Force Research Laboratory (United States); Malomed, Boris A. [Department of Physical Electronics, School of Electrical Engineering, Faculty of Engineering, Tel Aviv University, Tel Aviv 69978 (Israel)

    2015-09-15

    We report results of an analysis of the dynamics of magnetic flux solitons in the system of three long Josephson junctions between three bulk superconductors that form a prism. The system is modeled by coupled sine-Gordon equations for the phases of the junctions. The Aharonov-Bohm constraint takes into account the axial magnetic flux enclosed by the prism and reduces the system from three independent phases to two. The equations of motion for the phases include dissipative terms, and a control parameter δ which accounts for the deviation of the enclosed flux from half a quantum. Analyzing the effective potential of the coupled equations, we identify different species of topological and non-topological phase solitons (fluxons) in this system. In particular, subkinks with fractional topological charges ±1/3 and ±2/3, confined inside integer-charge fluxons, may be mapped onto the root diagrams for mesons and baryons in the original quark model of hadrons. Solutions for straight-line kinks and for two types of non-topological solitons are obtained in an explicit analytical form. Numerical tests demonstrate that the former species is unstable against breakup into pairs of separating single-fluxon kinks. The non-topological kinks feature metastability, eventually breaking up into fluxon-antifluxon pairs. Free fractional-fluxon kinks, that connect different potential minima and are, accordingly, pulled by the potential difference, are also considered. Using the momentum-balance method, we predict the velocity at which these kinks should move in the presence of the dissipation. Numerical tests demonstrate that the analysis predicts the velocity quite closely. Higher-energy static solutions for all of the stable kink types mentioned above, as well as kinks connecting false vacua, are found by means of the shooting method. Inelastic collisions among the stable fractional and single-fluxon kinks are investigated numerically.

  9. Triangular Monometallic Cyanide Cluster Entrapped in Carbon Cage with Geometry-Dependent Molecular Magnetism.

    Science.gov (United States)

    Liu, Fupin; Gao, Cong-Li; Deng, Qingming; Zhu, Xianjun; Kostanyan, Aram; Westerström, Rasmus; Wang, Song; Tan, Yuan-Zhi; Tao, Jun; Xie, Su-Yuan; Popov, Alexey A; Greber, Thomas; Yang, Shangfeng

    2016-11-09

    Clusterfullerenes are capable of entrapping a variety of metal clusters within carbon cage, for which the entrapped metal cluster generally keeps its geometric structure (e.g., bond distance and angle) upon changing the isomeric structure of fullerene cage, and whether the properties of the entrapped metal cluster is geometry-dependent remains unclear. Herein we report an unusual triangular monometallic cluster entrapped in fullerene cage by isolating several novel terbium cyanide clusterfullerenes (TbNC@C 82 ) with different cage isomeric structures. Upon varying the isomeric structure of C 82 cage from C 2 (5) to C s (6) and to C 2v (9), the entrapped triangular TbNC cluster exhibits significant distortions as evidenced by the changes of Tb-C(N) and C-N bond distances and variation of the Tb-C(N)-N(C) angle by up to 20°, revealing that the geometric structure of the entrapped triangular TbNC cluster is variable. All three TbNC@C 82 molecules are found to be single-ion magnets, and the change of the geometric structure of TbNC cluster directly leads to the alternation of the magnetic relaxation time of the corresponding TbNC@C 82 clusterfullerene.

  10. Flat plate film cooling at the coolant supply into triangular and cylindrical craters

    Directory of Open Access Journals (Sweden)

    Khalatov Artem A.

    2017-01-01

    Full Text Available The results are given of the film cooling numerical simulation of three different schemes including single-array of the traditional round inclined holes, as well as inclined holes arranged in the cylindrical or triangular dimples (craters. The results of simulation showed that at the medium and high values of the blowing ratio (m > 1.0 the scheme with coolant supply into triangular craters improves the adiabatic film cooling efficiency by 1.5…2.7 times compared to the traditional array of inclined holes, or by 1.3…1.8 times compared to the scheme with coolant supply into cylindrical craters. The greater film cooling efficiency with the coolant supply into triangular craters is explained by decrease in the intensity of secondary vortex structures (“kidney” vortex. This is due to the partial destruction and transformation of the coolant jets structure interacting with front wall of the crater. Simultaneously, the film cooling uniformity is increased in the span-wise direction.

  11. Transient response of a resonator fiber optic gyro with triangular wave phase modulation.

    Science.gov (United States)

    Ma, Huilian; Chen, Yan; Li, Mucheng; Jin, Zhonghe

    2010-11-10

    We present an in-depth analysis of the transient response of a resonator fiber optic gyro based on triangular wave phase modulation. Unusual effects have been observed in the process of tracking the resonant frequency of an optical fiber ring resonator (OFRR). There is a distortion phenomenon, unlike the ideally square wave or a pure DC output of the OFRR, but signal overshoot or undershoot occurs. A deep analysis of the influence of the nonideal square wave or pure DC output on gyro performance is fully developed for the first time, to the best of our knowledge. Further analysis shows that this is the transient response process after modulation by the triangular wave, and the process is related both to the parameters of the OFRR and the modulation frequency of the triangular wave. By sampling the steady-state signal of the distortion square wave, or by oversampling the distortion signal to get a number of data, and then accumulating and averaging these data to be demodulated, the distortion's effect can be considerably decreased.

  12. Analysis of Kerr effect in resonator fiber optic gyros with triangular wave phase modulation.

    Science.gov (United States)

    Ying, D; Demokan, M S; Zhang, X; Jin, W

    2010-01-20

    We present an in-depth analysis of the Kerr effect in resonator fiber optic gyros (R-FOGs) based on triangular wave phase modulation. Formulations that relate gyro output to the rotation rate, the Kerr nonlinearity, and other fiber and gyro parameters are derived and used to study the effect of Kerr nonlinearity on the gyro performance. Numerical investigation shows that the Kerr effect results in a nonzero gyro output even when the gyro is at stationary, which is interpreted as an error in the measurement of rotation rate. This error was found to increase as the frequencies of the two triangular phase modulations deviate from each other, and is not zero even if the intensities of the two counterpropagating beams are exactly the same. For fixed frequencies of the triangular phase modulations, there exists an optimal intensity splitting ratio for the two counterpropagating beams, which leads to zero gyro error. Calculation shows that the measurement error due to the Kerr effect for an R-FOG with a hollow-core photonic bandgap fiber as the fiber loop can be one to two orders of magnitude smaller than an R-FOG with a conventional single mode fiber loop.

  13. Comparison of VFA titration procedures used for monitoring the biogas process

    DEFF Research Database (Denmark)

    Lützhøft, Hans-Christian Holten; Boe, Kanokwan; Fang, Cheng

    2014-01-01

    titration procedures. Currently, no standardized procedure is used and it is therefore difficult to compare the performance among plants. The aim of this study was to evaluate four titration procedures (for determination of VFA-levels of digested manure samples) and compare results with gas chromatographic...... (GC) analysis. Two of the procedures are commonly used in biogas plants and two are discussed in literature. The results showed that the optimal titration results were obtained when 40mL of four times diluted digested manure was gently stirred (200rpm). Results from samples with different VFA...... concentrations (1-11g/L) showed linear correlation between titration results and GC measurements. However, determination of VFA by titration generally overestimated the VFA contents compared with GC measurements when samples had low VFA concentrations, i.e. around 1g/L. The accuracy of titration increased when...

  14. [A double antibody sandwich ELISA based assay for titration of severe fever with thrombocytopenia syndrome virus].

    Science.gov (United States)

    Liu, Lin; Zhang, Quan-Fu; Li, Chuan; Li, Jian-Dong; Jiang, Xiao-Lin; Zhang, Fu-Shun; Wu, Wei; Liang, Mi-Fang; Li, De-Xin

    2013-06-01

    To develop an assay for titration of severe fever with thrombocytopenia syndrome virus (SFTSV) based on double antibody sandwich ELISA. A double antibody sandwich ELISA was developed for detection of SFTSV based on SFTSV nucleocapsid (N) protein specific poly- and monoclonal antibodies, procedures were optimized and evaluated. This ELISA based titration assay was compared with fluorescence assasy and plaque assay based titration method. The results suggested that the titers obtained by ELISA based method are consistent with those obtained by IFA based method (R = 0.999) and the plaque assay titration method (R = 0.949). The novel ELISA based titration method with high sensitivity and specificity is easy to manage and perform, and can overcome the subjectivity associated with result determination of the fluorescence assay and plaque assay based methods. The novel ELISA based titration method can also be applied to high throughput detection.

  15. Air Forces and Moments on Triangular and Related Wings With Subsonic Leading Edges Oscillating in Supersonic Potential Flow

    National Research Council Canada - National Science Library

    Watkins, Charles

    1961-01-01

    This analysis treats the air forces and moments in supersonic potential flow on oscillating triangular wings and a series of sweptback and arrow wings with subsonic leading edges and supersonic trailing edges...

  16. A photonic-assisted periodic triangular-shaped pulses generator based on FWM effect in an SOA

    Science.gov (United States)

    Yuan, Jin; Ning, Tigang; Li, Jing; Chen, Hongyao; Li, Yueqin; Zhang, Chan

    2016-12-01

    We propose a photonic-assisted triangular-shaped pulse train generator based on four-wave mixing effect (FWM) in a semiconductor optical amplifier (SOA). A dual-parallel Mach-Zehnder operated at quadrupling RF modulation is employed to generate two primary sidebands (±2nd) in spectrum of the triangular-shaped pulse. Then the FWM effect leads to generation of two new frequency components. By setting the modulation index and bias current of the SOA properly, the generated harmonics of optical intensity can be corresponding to the Fourier components of typical periodic triangular pulses. Finally, a triangular pulse train with tunable repetition rate can be obtained. Numerical simulations have been taken to evaluate the impact of several key parameters to make the scheme more practical.

  17. SPECIAL CONSIDERATIONS REGARDING WARFARIN DOSE TITRATION IN PATIENTS WITH ATRIAL FIBRILLATION DEPENDING ON CLINICAL FACTORS

    OpenAIRE

    E. L. Artanova; E. V. Saleeva; I. M. Sokolov; Y. G. Shvarts

    2011-01-01

    Aim. To study the relations of clinical characteristics and individual warfarin dose titration in patients with atrial fibrillation. Material and methods. Period of warfarin dose titration was analyzed in 68 patients with atrial fibrillation due to ischemic heart disease. Adjusted warfarin dose in milligram, duration of dose titration in days and maximal international normalized ratio (INR) were taken into account. Sex, age, history of myocardial infarction and stroke, concomitant diseases, a...

  18. Potentiometric titration of molybdenum (6) with a cathode-polarized solid electrode

    International Nuclear Information System (INIS)

    Boeva, L.V.; Kimstach, V.A.; Bagdasarov, K.N.

    1980-01-01

    The possibility has been studied of using solid electrodes for potentiometric precipitation titration of molybdenum (6). A cathode-polarized electrode, electrochemically covered with a molybdenum blue layer, can be used as indicator electrode. The best results were obtained during deposition of molybdenum blue on a tungsten electrode. The mechanism of electrode work during titration has been investigated. A procedure has been developed of titration of molybdenum (6) in acid solutions using hydroxylamine N-aryl derivatives as titrants

  19. Thermometric Titration for Rapid Determination of Trace Water in Jet Fuel

    OpenAIRE

    Jian-Qiang Hu; Jian-Jian Zhang; Shi-Zhao Yang; Yong-Liang Xin; Li Guo; Ting Yao

    2017-01-01

    Water content in jet fuels is detected by thermometric titration (TMT), and the optimal detected system is 2,2-dimethoxypropane as titrant, cyclohexane and isopropanol as titration solvents, and methanesulfonic acid as catalyst in this method. The amounts of oil, concentration and delivery rate of titrant, volumes, and the reliability and accuracy of thermometric titration were emphasized. The results show that the accuracy, validity, and reliability of TMT are excellent by different indicate...

  20. Simple Modification of Karl-Fischer Titration Method for Determination of Water Content in Colored Samples

    OpenAIRE

    Eva Tavčar; Erika Turk; Samo Kreft

    2012-01-01

    The most commonly used technique for water content determination is Karl-Fischer titration with electrometric detection, requiring specialized equipment. When appropriate equipment is not available, the method can be performed through visual detection of a titration endpoint, which does not enable an analysis of colored samples. Here, we developed a method with spectrophotometric detection of a titration endpoint, appropriate for moisture determination of colored samples. The reaction takes p...

  1. Pulsating Different Curves of Zero Velocity around Triangular Equilibrium Points in Elliptical Restricted Three-Body Problem

    Directory of Open Access Journals (Sweden)

    A. Narayan

    2013-01-01

    Full Text Available The oblateness and the photogravitational effects of both the primaries on the location and the stability of the triangular equilibrium points in the elliptical restricted three-body problem have been discussed. The stability of the triangular points under the photogravitational and oblateness effects of both the primaries around the binary systems Achird, Lyeten, Alpha Cen-AB, Kruger 60, and Xi-Bootis, has been studied using simulation techniques by drawing different curves of zero velocity.

  2. On the critical point of the fully-anisotropic quenched bond-random Potts ferromagnet in triangular and honeycomb lattices

    International Nuclear Information System (INIS)

    Tsallis, C.; Santos, R.J.V. dos

    1983-01-01

    On conjectural grounds an equation that provides a very good approximation for the critical temperature of the fully-anisotropic homogeneous quenched bond-random q-state Potts ferromagnet in triangular and honeycomb lattices is presented. Almost all the exact particular results presently known for the square, triangular and honeycomb lattices are recovered; the numerical discrepancy is quite small for the few exceptions. Some predictions that we believe to be exact are made explicite as well. (Author) [pt

  3. Semi-automated potentiometric titration method for uranium characterization

    Energy Technology Data Exchange (ETDEWEB)

    Cristiano, B.F.G., E-mail: barbara@ird.gov.br [Comissao Nacional de Energia Nuclear (CNEN), Instituto de Radioprotecao e Dosimetria (IRD), Avenida Salvador Allende s/n Recreio dos Bandeirantes, PO Box 37750, Rio de Janeiro, 22780-160 RJ (Brazil); Delgado, J.U.; Silva, J.W.S. da; Barros, P.D. de; Araujo, R.M.S. de [Comissao Nacional de Energia Nuclear (CNEN), Instituto de Radioprotecao e Dosimetria (IRD), Avenida Salvador Allende s/n Recreio dos Bandeirantes, PO Box 37750, Rio de Janeiro, 22780-160 RJ (Brazil); Lopes, R.T. [Programa de Engenharia Nuclear (PEN/COPPE), Universidade Federal do Rio de Janeiro (UFRJ), Ilha do Fundao, PO Box 68509, Rio de Janeiro, 21945-970 RJ (Brazil)

    2012-07-15

    The manual version of the potentiometric titration method has been used for certification and characterization of uranium compounds. In order to reduce the analysis time and the influence of the analyst, a semi-automatic version of the method was developed in the Brazilian Nuclear Energy Commission. The method was applied with traceability assured by using a potassium dichromate primary standard. The combined standard uncertainty in determining the total concentration of uranium was around 0.01%, which is suitable for uranium characterization. - Highlights: Black-Right-Pointing-Pointer We developed a semi-automatic version of potentiometric titration method. Black-Right-Pointing-Pointer The method is used for certification and characterization of uranium compounds. Black-Right-Pointing-Pointer The traceability of the method was assured by a K{sub 2}Cr{sub 2}O{sub 7} primary standard. Black-Right-Pointing-Pointer The results of U{sub 3}O{sub 8} reference material analyzed was consistent with certified value. Black-Right-Pointing-Pointer The uncertainty obtained, near 0.01%, is useful for characterization purposes.

  4. Common Standards of Basal Insulin Titration in T2DM

    Science.gov (United States)

    Arnolds, Sabine; Heise, Tim; Flacke, Frank; Sieber, Jochen

    2013-01-01

    Type 2 diabetes mellitus has become a worldwide major health problem, and the number of people affected is steadily increasing. Thus, not all patients suffering from the disease can be treated by specialized diabetes centers or outpatient clinics, but by primary care physicians. The latter, however, might have time constraints and have to deal with many kinds of diseases or with multimorbid patients, so their focus is not so much on lowering high blood glucose values. Thus, the physicians, as well as the patients themselves, are often reluctant to initiate and adjust insulin therapy, although basal insulin therapy is considered the appropriate strategy after oral antidiabetic drug failure, according to the latest international guidelines. A substantial number of clinical studies have shown that insulin initiation and optimization can be managed successfully by using titration algorithms—even in cases where patients themselves are the drivers of insulin titration. Nevertheless, tools and strategies are needed to facilitate this process in the daily life of both primary health care professionals and patients with diabetes. PMID:23759411

  5. Radiometric titration of thallium(III) with EDTA

    International Nuclear Information System (INIS)

    Rao, V.R.S.; Pulla Rao, Ch.; Tataiah, G.

    1978-01-01

    Radioactive solutions containing very small amounts of thallium(III) can be determined by radiometric titration using ammonia as hydrolysing agent. Aqueous solution of thallium(I) (both inactive and radioactive) is treated with bromine water till the appearance of the brown colour of bromine, and the solution is warmed to 80 deg C to expel the excess bromine. By this procedure all thallium(I) is quantitatively oxidised to thallium(III). An aqueous solution of ammonia is added to precipitate thallium(III) as thallic oxide. It is then filtered, washed with water to free it from bromide and then dissolved in 2N HCl and the solution is then standardised. 2 ml of this solution is transferred to a 20 ml volumetric flask, 1 ml of radioactive thallium(III) solution to be standardised is added as well as incremental amounts of EDTA solution and mixed thoroughly. Uncomplexed thallium(III) is then precipitated by the addition of an ammonia solution and diluted to 20 ml. Required amount of this mixture is centrifuged. The beta activity of the supernatant aliquot is measured using a GM counter. Quantitative determination of Tl(III) in the range of 1-10 μM can be carried out. The interference of cations such as Au(III), iron(III), Ga(III) can be eliminated by pretreatment of the Tl(III) solution before carrying out radiometric titration. The results obtained are reproducible and accurate to +-3%. (T.I.)

  6. Rejuvenation of the nasolabial complex with inverted triangular-shaped SMAS grafts.

    Science.gov (United States)

    Cintra, Henrique Ladvocat Pessoa; Landecker, Alan

    2003-01-01

    One of the most challenging aspects of facial aesthetic surgery is rejuvenating the nasolabial complex. Unfortunately, the numerous existing techniques for this purpose have shown limited results due to factors such as long-term unpredictability, modest levels of improvement, and failure to address all of the anatomic/biomechanical alterations simultaneously. In this paper we present our experience with the use of inverted triangular SMAS grafts to rejuvenate the nasolabial complex, analyzing important aspects of surgical technique, indications, and outcomes. Fifteen patients underwent rejuvenation of the nasolabial complex using inverted triangular SMAS grafts, with a mean follow-up period of 18 months. Treatment of the nasolabial complex was performed concurrently to an extended SMAS facelift. The triangular-shaped grafts were harvested from the redundant tissue resulting after traction and inset of the SMAS flaps in the preauricular area. Dissection of the graft's pocket is carried out in the subcutaneous plane through a perialar incision. The resulting shape of the pocket resembles an inverted triangle or funnel, with more extensive dissection in the superior area. A Reverdin needle is inserted through a small 2-3-mm incision at the end of the nasolabial crease, adjacent to the oral commissure. The graft is then tied to the needle and inserted by simply extracting the latter from the inferior incision; the tied triangular graft falls naturally into position inside the pocket. Rejuvenation of the nasolabial complex was performed satisfactorily in all patients. The graft's design provided enough tissue to appropriately fill and attenuate the depressed triangular area in the upper region of the crease. Contour of the inferior two-thirds of the crease was improved by the narrower portion of the graft. Postoperative recovery occurred uneventfully, the grafts were not palpable/perceptible, and there was no need for complementary treatment modalities. The presented

  7. Ruthenium determination in new composite materials by coulometric titration with generated iron(2)

    International Nuclear Information System (INIS)

    Butakova, N.A.; Oganesyan, L.B.

    1983-01-01

    A coulometric technique is developed for ruthenium (4) titration with generated iron (2) in a mixture of hydrochloric-, sulfuric- and phosphoric acids with potentiometric and biammetric indication of the final titration point. Bi (3), Pd (2), Nb (5), Pt (4) Pb (2), Rh (3) do not interfere with the titration. Together with Ru (4) titrated are Ir (4), V (5), Au (3). The method is applied to analyze commercial samples of ruthenium dioxides, lead- and bismuth ruthenites, ruthenium pentafluorides containing 30-80% of ruthenium. The Ssub(r) values do not exceed 0.002

  8. Method for linearizing the potentiometric curves of precipitation titration in nonaqueous and aqueous-organic solutions

    International Nuclear Information System (INIS)

    Bykova, L.N.; Chesnokova, O.Ya.; Orlova, M.V.

    1995-01-01

    The method for linearizing the potentiometric curves of precipitation titration is studied for its application in the determination of halide ions (Cl - , Br - , I - ) in dimethylacetamide, dimethylformamide, in which titration is complicated by additional equilibrium processes. It is found that the method of linearization permits the determination of the titrant volume at the end point of titration to high accuracy in the case of titration curves without a potential jump in the proximity of the equivalent point (5 x 10 -5 M). 3 refs., 2 figs., 3 tabs

  9. Application of »Mass Titration« to Determination of Surface Charge of Metal Oxides

    OpenAIRE

    1998-01-01

    The mass titration method, used for the point of zero charge determination, was extended to the measurement of the surface charge density. The results agree with the common method, which is the acid-base titration of the colloidal suspension. The advantage of mass titration is that one does not need to perform blank titration, instead one simply adds metal oxide powder to the electrolyte aqueous solution of known pH. To cover the pH range above and below the point of zero charge, two experime...

  10. [Comparison of different continuous positive airway pressure titration methods for obstructive sleep apnea hypopnea syndrome].

    Science.gov (United States)

    Li, Jingjing; Ye, Jingying; Zhang, Peng; Kang, Dan; Cao, Xin; Zhang, Yuhuan; Ding, Xiu; Zheng, Li; Li, Hongguang; Bian, Qiuli

    2014-10-01

    To explore whether there were differences between the results of automatic titration and the results of manual titration for positive airway pressure treatment in patients with obstructive sleep apnea hypopnea syndrome (OSAHS) and its influencing factors, the results might provide a theoretical basis for the rational use of two pressure titration methods. Sixty one patients with OSAHS were included in this study. All patients underwent a manual titration and an automatic titration within one week. The clinical informations, polysomnography data, and the results of both two titration of all patients were obtained for analysis. The overall apnea/hypopnea index was (63.1 ± 17.7)/h, with a range of 14.9/h to 110.4/h. The treatment pressure of manual titration was (8.4 ± 2.1) cmH(2)O, which was significantly lower than the treatment pressure of automatic titration, (11.5 ± 2.7) cmH(2)O (t = -9.797, P titration and manual titration), it was found that the pressure of automatic titration was significantly higher in patients with a ΔP > 3 cmH(2)O than in patients with a ΔP ≤ 3 cmH(2)O, which was (13.3 ± 2.3) cmH(2)O vs (10.0 ± 2.0) cmH(2)O (t = -6.159, P titration between these two groups, which was (8.6 ± 2.4) cmH(2)O vs (8.3 ± 2.0)cmH(2)O (P > 0.05). There was no significant difference in age, body mass index, neck circumference, abdomen circumference, apnea hypopnea index, and arterial oxygen saturation between these two groups. The treatment pressure of automatic titration is usually higher than that of manual titration. For patients with a high treatment pressure which is derived from automatic titration, a suggestion about manual titration could be given to decrease the potential treatment pressure of continuous positive airway pressure, which may be helpful in improving the comfortableness and the compliance of this treatment.

  11. A nine-point pH titration method to determine low-concentration VFA in municipal wastewater.

    Science.gov (United States)

    Ai, Hainan; Zhang, Daijun; Lu, Peili; He, Qiang

    2011-01-01

    Characterization of volatile fatty acid (VFA) in wastewater is significant for understanding the wastewater nature and the wastewater treatment process optimization based on the usage of Activated Sludge Models (ASMs). In this study, a nine-point pH titration method was developed for the determination of low-concentration VFA in municipal wastewater. The method was evaluated using synthetic wastewater containing VFA with the concentration of 10-50 mg/l and the possible interfering buffer systems of carbonate, phosphate and ammonium similar to those in real municipal wastewater. In addition, the further evaluation was conducted through the assay of real wastewater using chromatography as reference. The results showed that the recovery of VFA in the synthetic wastewater was 92%-102 and the coefficient of variance (CV) of reduplicate measurements 1.68%-4.72%. The changing content of the buffering substances had little effect on the accuracy of the method. Moreover, the titration method was agreed with chromatography in the determination of VFA in real municipal wastewater with R(2)= 0.9987 and CV =1.3-1.7. The nine-point pH titration method is capable of satisfied determination of low-concentration VFA in municipal wastewater.

  12. Evaluation of copper speciation in the extract of Eichhornia crassipes using reverse and forward/CLE voltammetric titrations

    Directory of Open Access Journals (Sweden)

    Wael H.M. Abdelraheem

    2016-11-01

    Full Text Available Reverse and forward titrations coupled with the competitive ligand equilibration (CLE technique were, for the first time, used to investigate the chemical organic speciation of copper ions in an aqueous extract of Eichhornia crassipes (E.C plant growing in Egypt. Salicylaldoxime (SA was used as the competitive ligand. Two samples were collected from huge submerged masses in the Nile water at Sohag and Mansura cities. In this study the concentration of the natural complexing ligands (CLn and their conditional stability constants with copper (KCuLn′ in the aqueous extract were determined by linear and nonlinear modeling. Reverse titration resulted in two classes of copper complexation (CuL1 and CuL2 in both samples. The strongest class, CuL1, is predominant in Sohag-sample with average logKCuL1′ and CL1 of 15.66 and 435.5 nM, respectively, and also dominated in the Mansura-sample with average 16.77 and 162 nM, respectively. The second class (CuL2 is minor in both samples. For comparison, forward titration was performed for the Sohag-sample. The results indicated that reverse titration showed a breakthrough ability to detect, for the first time, different types of metal complexation present in equilibrium in the aqueous extracts of biological samples. Moreover, the presence of E.C in Nile water is so useful in transforming free Cu ions to less toxic forms by organic complexation.

  13. Fluorescence-Based Comparative Binding Studies of the Supramolecular Host Properties of PAMAM Dendrimers Using Anilinonaphthalene Sulfonates: Unusual Host-Dependent Fluorescence Titration Behavior

    Directory of Open Access Journals (Sweden)

    Natasa Stojanovic

    2010-04-01

    Full Text Available This work describes the fluorescence enhancement of the anilinonaphthalene sulfonate probes 1,8-ANS, 2,6-ANS, and 2,6-TNS via complexation with PAMAM dendrimer hosts of Generation 4, 5 and 6. The use of this set of three very closely related probes allows for comparative binding studies, with specific pairs of probes differing only in shape (1,8-ANS and 2,6-ANS, or in the presence of a methyl substituent (2,6-TNS vs. 2,6-ANS. The fluorescence of all three probes was significantly enhanced upon binding with PAMAM dendrimers, however in all cases except one, a very unusual spike was consistently observed in the host fluorescence titration plots (fluorescence enhancement vs. host concentration at low dendrimer concentration. This unprecedented fluorescence titration curve shape makes fitting the data to a simple model such as 1:1 or 2:1 host: guest complexation very difficult; thus only qualitative comparisons of the relative binding of the three guests could be made based on host titrations. In the case of G4 and G5 dendrimers, the order of binding strength was qualitatively determined to be 1,8-ANS < 2,6-ANS indicating that the more streamlined 2,6-substituted probes are a better match for the dendrimer cavity shape than the bulkier 1,8-substituted probe. This order of binding strength was also indicated by double fluorometric titration experiments, involving both host and guest titrations. Further double fluorometric titration experiments on 2,6-ANS in G4 dendrimer revealed a host concentration-dependent change in the nature of the host: guest complexation, with multiple guests complexed per host molecule at very low host concentrations, but less than one guest per host at higher concentrations.

  14. Titration curves: a useful instrument for assessing the buffer systems of acidic mining waters.

    Science.gov (United States)

    Totsche, Oliver; Fyson, Andrew; Kalin, Margarete; Steinberg, Christian E W

    2006-07-01

    The acidification of mine waters is generally caused by metal sulfide oxidation, related to mining activities. These waters are characterized by low pH and high acidity due to strong buffering systems. The standard acidity parameter, the Base Neutralization Capacity (BNC), is determined by endpoint titration, and reflects a cumulative parameter of both hydrogen ions and all buffering systems, but does not give information on the individual buffer systems. We demonstrate that a detailed interpretation of titration curves can provide information about the strength of the buffering systems. The buffering systems are of importance for environmental studies and treatment of acidic mining waters. Titrations were carried out by means of an automatic titrator using acidic mining waters from Germany and Canada. The curves were interpreted, compared with each other, to endpoint titration results and to elemental concentrations contained therein. The titration curves were highly reproducible, and contained information about the strength of the buffer systems present. Interpretations are given, and the classification and comparison of acidic mining waters, by the nature and strength of their buffering systems derived from titration curves are discussed. The BNC-values calculated from the curves were more precise than the ones determined by the standard endpoint titration method. Due to the complex buffer mechanisms in acidic mining waters, the calculation of major metal concentrations from the shape of the titration curve resulted in estimates, which should not be confused with precise elemental analysis results. Titration curves provide an inexpensive, valuable and versatile tool, by which to obtain sophisticated information of the acidity in acidic water. The information about the strength of the present buffer systems can help to understand and document the complex nature of acidic mining water buffer systems. Finally, the interpretation of titration curves could help to

  15. Insights into optimal basal insulin titration in type 2 diabetes: Results of a quantitative survey.

    Science.gov (United States)

    Berard, Lori; Bonnemaire, Mireille; Mical, Marie; Edelman, Steve

    2018-02-01

    Basal insulin (BI) treatment initiation and dose titration in type 2 diabetes (T2DM) are often delayed. Such "clinical inertia" results in poor glycaemic control and high risk of long-term complications. This survey aimed to determine healthcare professional (HCP) and patient attitudes to BI initiation and titration. An online survey (July-August 2015) including HCPs and patients with T2DM in the USA, France and Germany. Patients were ≥18 years old and had been on BI for 6 to 36 months, or discontinued BI within the previous 12 months. Participants comprised 386 HCPs and 318 people with T2DM. While >75% of HCPs reported discussing titration at the initiation visit, only 16% to 28% of patients remembered such discussions, many (32%-42%) were unaware of the need to titrate BI, and only 28% to 39% recalled mention of the time needed to reach glycaemic goals. Most HCPs and patients agreed that more effective support tools to assist BI initiation/titration are needed; patients indicated that provision of such tools would increase confidence in self-titration. HCPs identified fear of hypoglycaemia, failure to titrate in the absence of symptoms, and low patient motivation as important titration barriers. In contrast, patients identified weight gain, the perception that titration meant worsening disease, frustration over the time to reach HbA1c goals and fear of hypoglycaemia as major factors. A disconnect exists between HCP- and patient-perceived barriers to effective BI titration. To optimize titration, strategies should be targeted to improve HCP-patient communication, and provide support and educational tools. © 2017 The Authors. Diabetes, Obesity and Metabolism published by John Wiley & Sons Ltd.

  16. Triangular Numbers

    Indian Academy of Sciences (India)

    Admin

    pictures rather than words; see Figure 1. We see from the figure that if ... without words' which clearly generalizes. The relation in Figure 4 (8T3 .... ARTICLE. The equation in. Section 2.2 is more difficult to solve than the Brahmagupta–. Pell equation; it involveselliptic curves. Every positive integer can be written as a sum of.

  17. Triangular Numbers

    Indian Academy of Sciences (India)

    Admin

    He has been in the field of mathematics education for three decades, and has been closely involved with the. Math Olympiad movement in. India. He is the author of many mathematics books addressed to high school students, and serves as an editor for Resonance and for. At Right Angles. He is engaged in many outreach.

  18. Ultrasonic and densimetric titration applied for acid-base reactions.

    Science.gov (United States)

    Burakowski, Andrzej; Gliński, Jacek

    2014-01-01

    Classical acoustic acid-base titration was monitored using sound speed and density measurements. Plots of these parameters, as well as of the adiabatic compressibility coefficient calculated from them, exhibit changes with the volume of added titrant. Compressibility changes can be explained and quantitatively predicted theoretically in terms of Pasynski theory of non-compressible hydrates combined with that of the additivity of the hydration numbers with the amount and type of ions and molecules present in solution. It also seems that this development could be applied in chemical engineering for monitoring the course of chemical processes, since the applied experimental methods can be carried out almost independently on the medium under test (harmful, aggressive, etc.).

  19. Biophysical characterization of antibodies with isothermal titration calorimetry

    Directory of Open Access Journals (Sweden)

    Verna Frasca

    2016-07-01

    Full Text Available Antibodies play a key role in the immune response. Since antibodies bind antigens with high specificity and tight affinity, antibodies are an important reagent in experimental biology, assay development, biomedical research and diagnostics. Monoclonal antibodies are therapeutic drugs and used for vaccine development. Antibody engineering, biophysical characterization, and structural data have provided a deeper understanding of how antibodies function, and how to make better drugs. Isothermal titration calorimetry (ITC is a label-free binding assay, which measures affinity, stoichiometry, and binding thermodynamics for biomolecular interactions. When thermodynamic data are used together with structural and kinetic data from other assays, a complete structure-activity-thermodynamics profile can be constructed. This review article describes ITC, and discusses several applications on how data from ITC provides insights into how antibodies function, guide antibody engineering, and aid design of new therapeutic drugs.

  20. IMPEDANCE METHOD OF MEASURING OF THE TITRATABLE ACIDITY OF YOGURT

    Directory of Open Access Journals (Sweden)

    Miroslav Vasilev

    2016-10-01

    Full Text Available In the present work are analyzed studies related to changes in the active impedance component of the dairy environment caused by the flow of lactic fermentation and coagulation of casein in milk. The aim of this work was to determine the relationship between the relative change of titratable acidity and the relative change of active impedance component of the dairy environment with lactic fermentation, causing coagulation of the casein in milk. . The data were interpolated with cubic spline, visualizing how when the fat content increases, the electrical resistance increases too. All data, collected during the tests would complement and be used for solving the optimization problem to determine the time of completion of the coagulation in future work.

  1. Oxygen titration strategies in chronic neonatal lung disease.

    Science.gov (United States)

    Primhak, Robert

    2010-09-01

    The history of oxygen therapy in neonatology has been littered with error. Controversies remain in a number of areas of oxygen therapy, including targets and strategies in supplemental oxygen therapy in Chronic Neonatal Lung Disease (CNLD). This article reviews some of these controversies, and makes some recommendations based on the available evidence. In graduates of neonatal units who are left with CNLD, oxygen saturation should be kept above 93-95%, with levels below 90% being avoided as far as possible. Titration of oxygen should be done using oximetry recordings which include periods of different activities. Weaning of oxygen supplementation should only be done based on satisfactory recordings during a trial of a lower flow. There is insufficient evidence to say whether weaning for increasing hours a day or stepwise weaning to a continuous lower flow is a better method. Copyright 2010 Elsevier Ltd. All rights reserved.

  2. Sailing on the "C": A Vitamin Titration with a Twist

    Science.gov (United States)

    Sowa, S.; Kondo, A. E.

    2003-05-01

    The experiment takes the traditional redox titration of vitamin C using iodine with starch as an indicator, and presents it to the student as a challenge in guided-inquiry format. Two versions, with different levels of difficulty, are provided, to accommodate students with varying levels of problem-solving skills. The "challenge" is both quantitative and qualitative: if you were an eighteenth-century sea captain packing for a voyage to the New World, would you take oranges, lemons, limes, or grapefruits to prevent your crew from getting scurvy? The challenge ties in history, nutrition, and health with chemistry, and provides students an opportunity to work with familiar food products in the laboratory.

  3. The ion-sensitive field effect transistor in rapid acid-base titrations

    NARCIS (Netherlands)

    Bos, M.; Bergveld, Piet; van Veen-Blaauw, A.M.W.

    1979-01-01

    Ion-sensitive field effect transistors (ISFETs) are used as the pH sensor in rapid acid—base titrations. Titration speeds at least five times greater than those with glass electrodes are possible for accuracies better than ±1%.

  4. Quick titration of pergolide in cotreatment with domperidone is safe and effective

    NARCIS (Netherlands)

    Jansen, PAF; Herings, RMC; Samson, MM; Schuurmans-Daemen, LMPJ; Hovestadt, A; Verhaar, HJJ; Van Laar, T; de Vreede, P.

    2001-01-01

    The purpose of the study was to analyze efficacy and safety of quick pergolide titration combined with domperidone. In an open-label prospective study, pergolide was titrated in 16 days to a maximum of 3 mg/d doses as adjunctive treatment to L-Dopa in 10 elderly patients with Parkinson's disease.

  5. Efficacy of daytime continuous positive airway pressure titration in severe obstructive sleep apnoea.

    Science.gov (United States)

    Rudkowski, J C; Verschelden, P; Kimoff, R J

    2001-09-01

    The aim of this study was to evaluate manual nasal continuous positive airway pressure (nCPAP) titration during daytime polysomnography compared with conventional overnight titration for patients with severe obstructive sleep apnoea. Thirty-two patients who underwent daytime titration were retrospectively matched (for age, sex, body mass index and apnoea/hypopnoea index (AHI)) to a group titrated overnight during the same period. Successful titration was defined as the identification of the nCPAP level (effective nCPAP (Peff)) required to eliminate respiratory events during all sleep stages. After 3 months of therapy on nCPAP at Peff, nCPAP utilization history was obtained and a group of patients underwent a repeat polysomnogram (PSG) and completed a follow-up Epworth Sleepiness Scale (ESS) score. Initial titration was successful in 91% of daytime patients and 91% of overnight patients. The success of daytime titration was not related to diagnostic AHI or ESS score. Subjective nCPAP utilization was statistically similar in both groups. On the follow-up PSG, there were no significant differences between daytime (n=11) and overnight (n=11) patients in measures of sleep quality or respiratory disturbance. Both groups demonstrated similar and significant improvements in ESS score. These findings suggest that the effective nasal continuous positive airway pressure can be accurately established during daytime titration in a substantial proportion of severe, symptomatic obstructive sleep apnoea patients.

  6. The predictive value of drug-induced sleep endoscopy for CPAP titration in OSA patients.

    Science.gov (United States)

    Lan, Ming-Chin; Hsu, Yen-Bin; Lan, Ming-Ying; Huang, Yun-Chen; Kao, Ming-Chang; Huang, Tung-Tsun; Chiu, Tsan-Jen; Yang, Mei-Chen

    2017-12-15

    The aim of this study was to identify possible upper airway obstructions causing a higher continuous positive airway pressure (CPAP) titration level, utilizing drug-induced sleep endoscopy (DISE). A total of 76 patients with obstructive sleep apnea (OSA) underwent CPAP titration and DISE. DISE findings were recorded using the VOTE classification system. Polysomnographic (PSG) data, anthropometric variables, and patterns of airway collapse during DISE were analyzed with CPAP titration levels. A significant association was found between the CPAP titration level and BMI, oxygen desaturation index (ODI), apnea-hypopnea index (AHI), and neck circumference (NC) (P titration level (P titration level and any other collapse at the tongue base or epiglottis. By analyzing PSG data, anthropometric variables, and DISE results with CPAP titration levels, we can better understand possible mechanisms resulting in a higher CPAP titration level. We believe that the role of DISE can be expanded as a tool to identify the possible anatomical structures that may be corrected by oral appliance therapy or surgical intervention to improve CPAP compliance.

  7. Determination of Titratable Acidity in Wine Using Potentiometric, Conductometric, and Photometric Methods

    Science.gov (United States)

    Volmer, Dietrich A.; Curbani, Luana; Parker, Timothy A.; Garcia, Jennifer; Schultz, Linda D.; Borges, Endler Marcel

    2017-01-01

    This experiment describes a simple protocol for teaching acid-base titrations using potentiometry, conductivity, and/or photometry to determine end points without an added indicator. The chosen example examines the titratable acidity of a red wine with NaOH. Wines contain anthocyanins, the colors of which change with pH. Importantly, at the…

  8. flower extract as an improvised indicator in acid – base titration

    African Journals Online (AJOL)

    USER

    laboratory practical with an instructional material that is useful, economical, simple and accurate for the said titration. Therefore, it is recommended for integrated science and chemistry instructions. Keywords: Flower, acid, base, indicator, titration. INTRODUCTION. In Nigeria, factors militating against science education.

  9. Rapid and simple determination of oxyphenbutazone in dosage forms by biamperometric titration.

    Science.gov (United States)

    Sebková, D; Safarík, L

    1986-01-01

    Oxyphenbutazone was determined in the presence of glacial acetic acid, hydrochloric acid, and potassium bromide by bromometric titration with biamperometric end point indication. The course of the titration was followed with double platinum electrode with 100 mV of polarizing voltage.

  10. Tuning topological phase transitions in hexagonal photonic lattices made of triangular rods

    Science.gov (United States)

    Chan, Hsun-Chi; Guo, Guang-Yu

    2018-01-01

    In this paper we study topological phases in a two-dimensional photonic crystal with broken time (T ) and parity (P ) symmetries by performing calculations of band structures, Berry curvatures, Chern numbers, edge states, and also numerical simulations of light propagation in the edge modes. Specifically, we consider a hexagonal lattice consisting of triangular gyromagnetic rods. Here the gyromagnetic material breaks T symmetry while the triangular rods break P symmetry. Interestingly, we find that the crystal could host quantum anomalous Hall (QAH) phases with different gap Chern numbers (Cg) including | Cg|>1 as well as quantum valley Hall (QVH) phases with contrasting valley Chern numbers (Cv), depending on the orientation of the triangular rods. Furthermore, phase transitions among these topological phases, such as from QAH to QVH and vice versa, can be engineered by a simple rotation of the rods. Our band theoretical analyses reveal that the Dirac nodes at the K and K' valleys in the momentum space are produced and protected by the mirror symmetry (my) instead of the P symmetry, and they become gapped when either T or my symmetry is broken, resulting in a QAH or QVH phase, respectively. Moreover, a high Chern number (Cg=-2 ) QAH phase is generated by gapping triply degenerate nodal points rather than pairs of Dirac points by breaking T symmetry. Our proposed photonic crystal thus provides a platform for investigating intriguing topological phenomena which may be challenging to realize in electronic systems, and also has promising potentials for device applications in photonics such as reflection-free one-way waveguides and topological photonic circuits.

  11. Sustainable Complex Triangular Cells for the Evaluation of CO2 Emissions by Individuals instead of Nations in a Scenario for 2030

    Directory of Open Access Journals (Sweden)

    Marcelo Sthel

    2013-05-01

    Full Text Available The concept of sustainable complex triangular cells may be applied to an individual of any human society. This concept was introduced in two recent articles. A case study was proposed to show the applicability of this new concept to Indian populations without contact with civilization and with a low environmental impact. Here we propose to apply this concept to a recent study, which claims that the concept of “common but differentiated responsibilities” refers to the emissions of individuals instead of nations. The income distribution of a country was used to estimate how its fossil fuel CO2 emissions are distributed among its citizens and, from that a global CO2 distribution was constructed. We propose the extension of the concept of complex triangular cells where its area would be equivalent to the CO2 emission per individual. In addition, a new three-dimensional geometric model for the regular hexagonal structure is offered in which the sharing of natural resources (human cooperation is employed to reduce CO2 emissions in two scenarios by 2030.

  12. Un algoritmo genético basado en números difusos triangulares

    OpenAIRE

    Carballido, Jessica Andrea; Ponzoni, Ignacio; Brignole, Diana

    2001-01-01

    En este trabajo se presenta un algoritmo genético basado en números triangulares difusos el cual tiene por objetivo superar los problemas de diversidad poblacional observados en los algoritmos genéticos clásicos. En la técnica propuesta se representa cada individuo a través de un conjunto difuso, y se redefinen las operaciones de cruzamiento y mutación para adecuarse a este nuevo patrón genético. Con el fin de establecer el alcance de nuestra propuesta se implementó el algoritmo genético trad...

  13. A New Accurate yet Simple Shear Flexible Triangular Plate Element with Linear Bending Strains

    DEFF Research Database (Denmark)

    Damkilde, Lars; Pedersen, Ronnie

    2010-01-01

    The paper describes a new shear flexible triangular element. The formulation is based on displacement interpolation of the transverse displacement of the midsurface and the rotations of the cross-sections, and the element is fully compatible. The basic principle is to use a so-called balanced...... interpolation so that the part of the shear strains that relates to the transverse displacement has the same polynomial variation as the part of the shear strains that relates to the rotations of the cross-section. This balanced interpolation in combination with complete polynomial interpolations prevents shear...... are virtually the same. The slightly incompatible formulation can be implemented directly into commercial codes....

  14. Magnetic Properties of New Triangular Lattice Magnets A${_4}$B'B${_2}$O$_{12}$

    OpenAIRE

    Rawl, Ryan; Lee, Minseong; Choi, Eun Sang; Li, Guang; Chen, Kuan-Wen; Baumbach, Ryan; Cruz, Clarina R. dela; Ma, Jie; Zhou, Haidong

    2017-01-01

    The geometrically frustrated two dimensional triangular lattice magnets A${_4}$B'B${_2}$O$_{12}$ (A = Ba, Sr, La; B' = Co, Ni, Mn; B = W, Re) have been studied by x-ray diffraction, AC and DC susceptibilities, powder neutron diffraction, and specific heat measurements. The results reveal that (i) the samples containing Co$^{2+}$ (effective spin-1/2) and Ni$^{2+}$ (spin-1) ions with small spin numbers exhibit ferromagnetic (FM) ordering while the sample containing Mn$^{2+}$ (spin-5/2) ions wit...

  15. Existence and stability of 3-site breathers in a triangular lattice

    International Nuclear Information System (INIS)

    Koukouloyannis, Vassilis; MacKay, Robert S

    2005-01-01

    We find conditions for existence and stability of various types of discrete breather concentrated around three central sites in a triangular lattice of one-dimensional Hamiltonian oscillators with on-site potential and nearest-neighbour coupling. In particular, we confirm that it can support non-reversible breather solutions, despite the time-reversible character of the system. They carry a net energy flux and can be called 'vortex breathers'. We prove that there are parameter regions for which they are linearly stable, for example in a lattice consisting of coupled Morse oscillators, whereas the related reversible breathers are unstable. Thus non-reversible breathers can be physically relevant

  16. Subspace-Based Noise Reduction for Speech Signals via Diagonal and Triangular Matrix Decompositions

    DEFF Research Database (Denmark)

    Hansen, Per Christian; Jensen, Søren Holdt

    2007-01-01

    We survey the definitions and use of rank-revealing matrix decompositions in single-channel noise reduction algorithms for speech signals. Our algorithms are based on the rank-reduction paradigm and, in particular, signal subspace techniques. The focus is on practical working algorithms, using both...... diagonal (eigenvalue and singular value) decompositions and rank-revealing triangular decompositions (ULV, URV, VSV, ULLV and ULLIV). In addition we show how the subspace-based algorithms can be evaluated and compared by means of simple FIR filter interpretations. The algorithms are illustrated...... with working Matlab code and applications in speech processing....

  17. Subspace-Based Noise Reduction for Speech Signals via Diagonal and Triangular Matrix Decompositions

    DEFF Research Database (Denmark)

    Hansen, Per Christian; Jensen, Søren Holdt

    We survey the definitions and use of rank-revealing matrix decompositions in single-channel noise reduction algorithms for speech signals. Our algorithms are based on the rank-reduction paradigm and, in particular, signal subspace techniques. The focus is on practical working algorithms, using both...... diagonal (eigenvalue and singular value) decompositions and rank-revealing triangular decompositions (ULV, URV, VSV, ULLV and ULLIV). In addition we show how the subspace-based algorithms can be evaluated and compared by means of simple FIR filter interpretations. The algorithms are illustrated...... with working Matlab code and applications in speech processing....

  18. Adaptive Finite Volume Method for the Shallow Water Equations on Triangular Grids

    Directory of Open Access Journals (Sweden)

    Sudi Mungkasi

    2016-01-01

    Full Text Available This paper presents a numerical entropy production (NEP scheme for two-dimensional shallow water equations on unstructured triangular grids. We implement NEP as the error indicator for adaptive mesh refinement or coarsening in solving the shallow water equations using a finite volume method. Numerical simulations show that NEP is successful to be a refinement/coarsening indicator in the adaptive mesh finite volume method, as the method refines the mesh or grids around nonsmooth regions and coarsens them around smooth regions.

  19. Magnetic anisotropy of two-dimensional nanostructures: Transition-metal triangular stripes

    International Nuclear Information System (INIS)

    Dorantes-Davila, J.; Villasenor-Gonzalez, P.; Pastor, G.M.

    2005-01-01

    The magnetic anisotropy energy (MAE) of one-dimensional stripes having infinite length and triangular lateral structure are investigated in the framework of a self-consistent tight-binding method. One observes discontinuous changes in the easy magnetization direction along the crossover from one to two dimensions. The MAE oscillates as a function of stripe width and depends strongly on the considered transition metal (TM). The MAE of the two-leg ladder is strongly reduced as compared to that of the monoatomic chain and the convergence to the two-dimensional limit is rather slow

  20. Magnetic anisotropy of two-dimensional nanostructures: Transition-metal triangular stripes

    Energy Technology Data Exchange (ETDEWEB)

    Dorantes-Davila, J. [Instituto de Fisica, Universidad Autonoma de San Luis Potosi, San Luis Potosi (Mexico)]. E-mail: jdd@ifisica.uaslp.mx; Villasenor-Gonzalez, P. [Instituto de Fisica, Universidad Autonoma de San Luis Potosi, San Luis Potosi (Mexico); Pastor, G.M. [Laboratoire de Physique Quantique, Centre National de la Recherche Scientifique, Universite Paul Sabatier, Toulouse (France)

    2005-07-15

    The magnetic anisotropy energy (MAE) of one-dimensional stripes having infinite length and triangular lateral structure are investigated in the framework of a self-consistent tight-binding method. One observes discontinuous changes in the easy magnetization direction along the crossover from one to two dimensions. The MAE oscillates as a function of stripe width and depends strongly on the considered transition metal (TM). The MAE of the two-leg ladder is strongly reduced as compared to that of the monoatomic chain and the convergence to the two-dimensional limit is rather slow.

  1. Numerical Study of Thermal Radiation Effect on Confined Turbulent Free Triangular Jets

    Directory of Open Access Journals (Sweden)

    Kiyan Parham

    2013-01-01

    Full Text Available The present study investigates the effects of thermal radiation on turbulent free triangular jets. Finite volume method is applied for solving mass, momentum, and energy equations simultaneously. Discrete ordinate method is used to determine radiation transfer equation (RTE. Results are presented in terms of velocity, kinetic energy, and its dissipation rate fields. Results show that thermal radiation speeds the development of velocity on the jet axis and enhances kinetic energy; therefore, when radiation is added to free jet its mixing power, due to extra kinetic energy, increases.

  2. The Implementation of Cumulative Learning Theory in Calculating Triangular Prism and Tube Volumes

    Science.gov (United States)

    Muklis, M.; Abidin, C.; Pamungkas, M. D.; Masriyah

    2018-01-01

    This study aims at describing the application of cumulative learning theory in calculating the volume of a triangular prism and a tube as well as revealing the students’ responses toward the learning. The research method used was descriptive qualitative with elementary school students as the subjects of the research. Data obtained through observation, field notes, questionnaire, tests, and interviews. The results from the application of cumulative learning theory obtained positive students’ responses in following the learning and students’ learning outcomes was dominantly above the average. This showed that cumulative learning could be used as a reference to be implemented in learning, so as to improve the students’ achievement.

  3. The magnetic structure on the ground state of the equilateral triangular spin tube

    International Nuclear Information System (INIS)

    Matsui, Kazuki; Goto, Takayuki; Manaka, Hirotaka; Miura, Yoko

    2016-01-01

    The ground state of the frustrated equilateral triangular spin tube CsCrF 4 is still hidden behind a veil though NMR spectrum broaden into 2 T at low temperature. In order to investigate the spin structure in an ordered state by 19 F-NMR, we have determined the anisotropic hyperfine coupling tensors for each three fluorine sites in the paramagnetic state. The measurement field was raised up to 10 T to achieve highest resolution. The preliminary analysis using the obtained hyperfine tensors has shown that the archetypal 120°-type structure in ab-plane does not accord with the NMR spectra of ordered state.

  4. The magnetic structure on the ground state of the equilateral triangular spin tube

    Energy Technology Data Exchange (ETDEWEB)

    Matsui, Kazuki, E-mail: k703861@eagle.sophia.ac.jp; Goto, Takayuki [Sophia University, Physics Division (Japan); Manaka, Hirotaka [Kagoshima University, Graduate School of Science and Engineering (Japan); Miura, Yoko [Suzuka National College of Technology (Japan)

    2016-12-15

    The ground state of the frustrated equilateral triangular spin tube CsCrF{sub 4} is still hidden behind a veil though NMR spectrum broaden into 2 T at low temperature. In order to investigate the spin structure in an ordered state by {sup 19}F-NMR, we have determined the anisotropic hyperfine coupling tensors for each three fluorine sites in the paramagnetic state. The measurement field was raised up to 10 T to achieve highest resolution. The preliminary analysis using the obtained hyperfine tensors has shown that the archetypal 120°-type structure in ab-plane does not accord with the NMR spectra of ordered state.

  5. Two-party Bell inequalities derived from combinatorics via triangular elimination

    International Nuclear Information System (INIS)

    Avis, David; Imai, Hiroshi; Ito, Tsuyoshi; Sasaki, Yuuya

    2005-01-01

    We establish a relation between the two-party Bell inequalities for two-valued measurements and a high-dimensional convex polytope called the cut polytope in polyhedral combinatorics. Using this relation, we propose a method, triangular elimination, to derive tight Bell inequalities from facets of the cut polytope. This method gives two hundred million inequivalent tight Bell inequalities from currently known results on the cut polytope. In addition, this method gives general formulae which represent families of infinitely many Bell inequalities. These results can be used to examine general properties of Bell inequalities

  6. Triangular facets of slope in the region of Tudela (Ebro Basin, Navarra, Spain)

    International Nuclear Information System (INIS)

    Marin, C.; Desir, G.; Gutierrez, M.

    2009-01-01

    Some triangular slope facets are localized to the south of Bardenas Reales (central-west of Ebro Basin), elaborated on Tudela Formation deposits, Aragonian in age. Three of them have been dated by OSL resulting on ages of 35,588±2,488 yr. BP, 35,355±2,446 yr. BP and 40.185±2,411 yr. BP. The origin of these facets is ought to an alternation between accumulation and incision phases produced by vegetation cover variation percentage. Those vegetation cover changes are estimated to be due to climatic changes. (Author) 21 refs.

  7. SPECIAL CONSIDERATIONS REGARDING WARFARIN DOSE TITRATION IN PATIENTS WITH ATRIAL FIBRILLATION DEPENDING ON CLINICAL FACTORS

    Directory of Open Access Journals (Sweden)

    E. L. Artanova

    2011-01-01

    Full Text Available Aim. To study the relations of clinical characteristics and individual warfarin dose titration in patients with atrial fibrillation. Material and methods. Period of warfarin dose titration was analyzed in 68 patients with atrial fibrillation due to ischemic heart disease. Adjusted warfarin dose in milligram, duration of dose titration in days and maximal international normalized ratio (INR were taken into account. Sex, age, history of myocardial infarction and stroke, concomitant diseases, amiodarone therapy were considered among clinical characteristics. Results. Adjusted warfarin dose was significantly higher in obesity , and it was lower in case of experienced myocardial infarction. The INR highest levels and maximal amplitudes of its fluctuations were observed in patients with thyroid gland nodes and smokers. Period of warfarin dose titration was longer in patients treated with amiodarone. Conclusion. Warfarin dose titration in patients with atrial fibrillation depends on the presence of myocardial infarction, obesity , thyroid nodular changes, smoking and amiodarone treatment.

  8. Simple Modification of Karl-Fischer Titration Method for Determination of Water Content in Colored Samples

    Science.gov (United States)

    Tavčar, Eva; Turk, Erika; Kreft, Samo

    2012-01-01

    The most commonly used technique for water content determination is Karl-Fischer titration with electrometric detection, requiring specialized equipment. When appropriate equipment is not available, the method can be performed through visual detection of a titration endpoint, which does not enable an analysis of colored samples. Here, we developed a method with spectrophotometric detection of a titration endpoint, appropriate for moisture determination of colored samples. The reaction takes place in a sealed 4 ml cuvette. Detection is performed at 520 nm. Titration endpoint is determined from the graph of absorbance plotted against titration volume. The method has appropriate reproducibility (RSD = 4.3%), accuracy, and linearity (R 2 = 0.997). PMID:22567558

  9. Molybdenum (6) determination by the method of high-frequency and pH titration

    International Nuclear Information System (INIS)

    Lukianets, I.G.; Kulish, N.G.

    1981-01-01

    A possibility to determine Mo(6) using the method of high frequency and pH-metric titration is investigated. By means of the high frequency contact R-cell Mo(6) titration is performed using different precipitators: 8-oxiquinoline, lead nitrate and acetate and silver nitrate. It is established that the best conditions are achieved during titration of 67.2-1343 mg/10 ml Mo(6) with lead acetate (pH 4.5-6.5). Relative standard deviation Ssub(r) constitutes 0.005 pH-metric titration of Mo(6) with complexone 3 is studied. The range of Mo(6) concentrations determined constitutes 13.43-134.3 mg at pH initial value of 3.5-5.5. Relative standard deviation Ssub(r) constitutes 0.003. Techniques of molybdenum determination in ferromolybdenum using the method of high frequency and pH-metric titration are developed [ru

  10. Integration and global analysis of isothermal titration calorimetry data for studying macromolecular interactions.

    Science.gov (United States)

    Brautigam, Chad A; Zhao, Huaying; Vargas, Carolyn; Keller, Sandro; Schuck, Peter

    2016-05-01

    Isothermal titration calorimetry (ITC) is a powerful and widely used method to measure the energetics of macromolecular interactions by recording a thermogram of differential heating power during a titration. However, traditional ITC analysis is limited by stochastic thermogram noise and by the limited information content of a single titration experiment. Here we present a protocol for bias-free thermogram integration based on automated shape analysis of the injection peaks, followed by combination of isotherms from different calorimetric titration experiments into a global analysis, statistical analysis of binding parameters and graphical presentation of the results. This is performed using the integrated public-domain software packages NITPIC, SEDPHAT and GUSSI. The recently developed low-noise thermogram integration approach and global analysis allow for more precise parameter estimates and more reliable quantification of multisite and multicomponent cooperative and competitive interactions. Titration experiments typically take 1-2.5 h each, and global analysis usually takes 10-20 min.

  11. Simple Modification of Karl-Fischer Titration Method for Determination of Water Content in Colored Samples

    Directory of Open Access Journals (Sweden)

    Eva Tavčar

    2012-01-01

    Full Text Available The most commonly used technique for water content determination is Karl-Fischer titration with electrometric detection, requiring specialized equipment. When appropriate equipment is not available, the method can be performed through visual detection of a titration endpoint, which does not enable an analysis of colored samples. Here, we developed a method with spectrophotometric detection of a titration endpoint, appropriate for moisture determination of colored samples. The reaction takes place in a sealed 4 ml cuvette. Detection is performed at 520 nm. Titration endpoint is determined from the graph of absorbance plotted against titration volume. The method has appropriate reproducibility (RSD=4.3%, accuracy, and linearity (2=0.997.

  12. Simple modification of karl-Fischer titration method for determination of water content in colored samples.

    Science.gov (United States)

    Tavčar, Eva; Turk, Erika; Kreft, Samo

    2012-01-01

    The most commonly used technique for water content determination is Karl-Fischer titration with electrometric detection, requiring specialized equipment. When appropriate equipment is not available, the method can be performed through visual detection of a titration endpoint, which does not enable an analysis of colored samples. Here, we developed a method with spectrophotometric detection of a titration endpoint, appropriate for moisture determination of colored samples. The reaction takes place in a sealed 4 ml cuvette. Detection is performed at 520 nm. Titration endpoint is determined from the graph of absorbance plotted against titration volume. The method has appropriate reproducibility (RSD = 4.3%), accuracy, and linearity (R(2) = 0.997).

  13. Acid-base titrations by stepwise addition of equal volumes of titrant with special reference to automatic titrations-III Presentation of a fully automatic titration apparatus and of results supporting the theories given in the preceding parts.

    Science.gov (United States)

    Pehrsson, L; Ingman, F

    1977-02-01

    This paper forms Part III of a series in which the first two parts describe methods for evaluating titrations performed by stepwise addition of equal volumes of titrant. The great advantage of these methods is that they do not require an accurate calibration of the electrode system. This property makes the methods very suitable for routine work. e.g., in automatic analysis. An apparatus for performing such titrations automatically is presented. Further, results of titrations of monoprotic acids, a diprotic acid, an ampholyte, a mixture of an acid with its conjugate base, and mixtures of two acids with a small difference between the stability constants are given. Most of these titrations cannot be evaluated by the Gran or Hofstee methods but yield results having errors of the order of 0.1% if the methods proposed in Parts I and II of this series are employed. The advantages of the method of stepwise addition of equal volumes of titrant combined with the proposed evaluation methods, in comparison with common methods such as titration to a preset pH, are that all the data are used in the evaluation, permitting a statistical treatment and giving better possibilities for tracing systematic errors.

  14. Initial Evaluation of a Titration Appliance for Temporary Treatment of Obstructive Sleep Apnea.

    Science.gov (United States)

    Levendowski, Daniel J; Morgan, Todd; Westbrook, Philip

    2012-01-01

    Custom oral appliances that adjustably advance the mandible provide superior outcomes when treating patients with moderate or severe sleep apnea. Custom appliances, however, are expensive, must be fitted by a dentist, and the likelihood of successful outcomes are difficult to predict. An inexpensive trial appliance, if proven efficacious, might be used to predict custom appliance outcomes or to provide temporary therapeutic benefit. The aim of this initial study was to assess the treatment efficacy of a novel titration oral appliance with that of an optimized custom appliance. Seventeen patients, treated with a custom oral appliance for at least one year, successfully completed a three-night home sleep test. The baseline obstructive sleep apnea severity was established on Night 1 with seven patients exhibiting severe, six moderate and four mild apnea/hypopnea indexes. Patients were randomly assigned to wear their custom appliance or the titration appliance on Nights 2 and 3. Significant reductions in the mean overall and supine apnea indexes (p titration and custom appliances. The proportion of patients who exhibited at least a 50% reduction in the overall apnea index and supine apnea/hypopnea were similar for the titration and custom appliance (~60%). The custom appliance reduced the overall apnea/hypopnea index by 50% in a greater proportion of the patients compared to the titration appliance (77% vs. 53%). The titration appliance significantly reduced the degree of hypoxic exposure across sleep disordered breathing events overall (p titration appliance, but preferred the titration appliance to no therapy. The titration appliance may be useful in assessing oral appliance treatment efficacy. When set to 70% of maximum protrusion, the titration appliance may provide immediate, temporary therapeutic benefit.

  15. Dose titration of BAF312 attenuates the initial heart rate reducing effect in healthy subjects.

    Science.gov (United States)

    Legangneux, Eric; Gardin, Anne; Johns, Donald

    2013-03-01

    Previous studies have shown transient decreases in heart rate (HR) following administration of sphingosine 1-phosphate (S1P) receptor modulators including BAF312. This study was conducted to determine whether dose titration of BAF312 reduces or eliminates these effects. Fifty-six healthy subjects were randomized 1:1:1:1 to receive BAF312 in one of two dose titration (DT) regimens (DT1 and DT2: 0.25-10 mg over 9-10 days), no titration (10 mg starting dose) or placebo. Pharmacodynamic and pharmacokinetic parameters were assessed. Neither DT1 nor DT2 resulted in clinically significant bradycardia or atrioventricular conduction effects. Both titration regimens showed a favourable difference on each of days 1-12 vs. the non-titration regimen on day 1 for HR effects (P titration was 1.18 (95% confidence interval [CI] 1.13, 1.23) and 1.14 (95% CI 1.09, 1.18) for DT2 (both P titration HRs showed considerable separation from placebo throughout the study. There was no statistically significant reduction in HR vs. placebo on day 1 in either titration regimen. On days 3-7 subjects in DT1 and DT2 experienced minor reductions in HR vs. placebo (approximately 5 beats min⁻¹; P ≤ 0.0001). From days 9-12, HRs in both titration regimens were comparable with placebo. Both titration regimens effectively attenuated the initial bradyarrhythmia observed on day 1 of treatment with BAF312 10 mg. © 2012 Novartis Institutes for BioMedical Research (NIBIR). British Journal of Clinical Pharmacology © 2012 The British Pharmacological Society.

  16. Rapid Inpatient Titration of Intravenous Treprostinil for Pulmonary Arterial Hypertension: Safe and Tolerable.

    Science.gov (United States)

    El-Kersh, Karim; Ruf, Kathryn M; Smith, J Shaun

    There is no standard protocol for intravenous treprostinil dose escalation. In most cases, slow up-titration is performed in the outpatient setting. However, rapid up-titration in an inpatient setting is an alternative that provides opportunity for aggressive treatment of common side effects experienced during dose escalation. In this study, we describe our experience with inpatient rapid up-titration of intravenous treprostinil. This was a single-center, retrospective study in which we reviewed the data of subjects with pulmonary arterial hypertension treated at our center who underwent inpatient rapid up-titration of intravenous treprostinil. Our treprostinil dose escalation protocol included initiation at 2 ng·kg·min with subsequent up-titration by 1 ng·kg·min every 6 to 8 hours as tolerated by side effects. A total of 16 subjects were identified. Thirteen subjects were treprostinil naive (naive group), and 3 subjects were receiving subcutaneous treprostinil but were hospitalized for further intravenous up-titration of treprostinil dose (nonnaive group). In the naive group, the median maximum dose achieved was 20 ng·kg·min with an interquartile range (IQR) of 20-23 ng·kg·min. The median up-titration interval was 6 days (IQR: 4-9). In the nonnaive group, the median maximum dose achieved was 20 ng·kg·min (range: 17-30). The median up-titration interval was 8.5 days (range: 1.5-11). Overall, the median maximum dose achieved was 20 ng·kg·min (IQR: 20-23.5), and the median up-titration interval was 6 days (IQR: 4.6-9.25), with no reported significant adverse hemodynamic events. In patients with pulmonary arterial hypertension, rapid inpatient titration of intravenous treprostinil is safe and tolerable.

  17. Potentiometric titrations of molybdenum and vanadium in aqueous and mixed so lvents

    International Nuclear Information System (INIS)

    Das, S.K.; Dhaneshwar, R.G.

    1990-01-01

    Potentiometric titration method was developed for molybdenum, employing different electrode systems. Molybdenum(VI) is reduced to molybdenum(V) by ferrous solution in presence of phosphoric acid and then titrated with potassium dichromate. It was found that ferrous concentration should be five times more than molybdenum and phosphoric acid should be 1.0 ml for 0.1N titration and 0.5 ml for lower concentration titrations. The method is also applicable to vanadium titrations. Employing Au/SCE and Pt/SCE systems, it was observed that generally curve heights obtained for platinum electrode are higher than those for gold electrode. Also for both the electrode systems, the curve heights for vanadium titrations were found to be more than those for molybdenum. Lower limits of titrations for Au/SCE system are 0.01N for molybdenum and 0.0001N for vanadium, whereas for Pt/SCE system, the lower limits obtained were 0.01N for both molybdenum and vanadium titrations. In order to improve the sensitivities of the method, the bimetallic electrode systems Au/Pt and Pt/Au were employed. Au/Pt system was found to give better results than Pt/Au systems. Addition of organic solvent was found to have beneficial effects for titrations of 0.001N and below. Methanol was found to be a better solvent than ethanol. Molybdenum titrations, at 0.0001N level could be performed in methanol with Au/Pt system, which is to b e generally preferred than Pt/Au system. (author). 7 refs., 3 tabs

  18. Macromolecular competition titration method accessing thermodynamics of the unmodified macromolecule-ligand interactions through spectroscopic titrations of fluorescent analogs.

    Science.gov (United States)

    Bujalowski, Wlodzimierz; Jezewska, Maria J

    2011-01-01

    Analysis of thermodynamically rigorous binding isotherms provides fundamental information about the energetics of the ligand-macromolecule interactions and often an invaluable insight about the structure of the formed complexes. The Macromolecular Competition Titration (MCT) method enables one to quantitatively obtain interaction parameters of protein-nucleic acid interactions, which may not be available by other methods, particularly for the unmodified long polymer lattices and specific nucleic acid substrates, if the binding is not accompanied by adequate spectroscopic signal changes. The method can be applied using different fluorescent nucleic acids or fluorophores, although the etheno-derivatives of nucleic acid are especially suitable as they are relatively easy to prepare, have significant blue fluorescence, their excitation band lies far from the protein absorption spectrum, and the modification eliminates the possibility of base pairing with other nucleic acids. The MCT method is not limited to the specific size of the reference nucleic acid. Particularly, a simple analysis of the competition titration experiments is described in which the fluorescent, short fragment of nucleic acid, spanning the exact site-size of the protein-nucleic acid complex, and binding with only a 1:1 stoichiometry to the protein, is used as a reference macromolecule. Although the MCT method is predominantly discussed as applied to studying protein-nucleic acid interactions, it can generally be applied to any ligand-macromolecule system by monitoring the association reaction using the spectroscopic signal originating from the reference macromolecule in the presence of the competing macromolecule, whose interaction parameters with the ligand are to be determined. Copyright © 2011 Elsevier Inc. All rights reserved.

  19. Macromolecular Competition Titration Method: Accessing Thermodynamics of the Unmodified Macromolecule–Ligand Interactions Through Spectroscopic Titrations of Fluorescent Analogs

    Science.gov (United States)

    Bujalowski, Wlodzimierz; Jezewska, Maria J.

    2011-01-01

    Analysis of thermodynamically rigorous binding isotherms provides fundamental information about the energetics of the ligand–macromolecule interactions and often an invaluable insight about the structure of the formed complexes. The Macromolecular Competition Titration (MCT) method enables one to quantitatively obtain interaction parameters of protein–nucleic acid interactions, which may not be available by other methods, particularly for the unmodified long polymer lattices and specific nucleic acid substrates, if the binding is not accompanied by adequate spectroscopic signal changes. The method can be applied using different fluorescent nucleic acids or fluorophores, although the etheno-derivatives of nucleic acid are especially suitable as they are relatively easy to prepare, have significant blue fluorescence, their excitation band lies far from the protein absorption spectrum, and the modification eliminates the possibility of base pairing with other nucleic acids. The MCT method is not limited to the specific size of the reference nucleic acid. Particularly, a simple analysis of the competition titration experiments is described in which the fluorescent, short fragment of nucleic acid, spanning the exact site-size of the protein–nucleic acid complex, and binding with only a 1:1 stoichiometry to the protein, is used as a reference macromolecule. Although the MCT method is predominantly discussed as applied to studying protein–nucleic acid interactions, it can generally be applied to any ligand–macromolecule system by monitoring the association reaction using the spectroscopic signal originating from the reference macromolecule in the presence of the competing macromolecule, whose interaction parameters with the ligand are to be determined. PMID:21195223

  20. Measurement of D 0 elliptic and triangular flow in Au+Au collisions at = 200 GeV at RHIC

    International Nuclear Information System (INIS)

    Lomnitz, Michael R.

    2017-01-01

    Due to their large masses, heavy quarks are predominantly produced through initial hard scatterings in heavy-ion collisions. As such, they experience the entire evolution of the hot and dense medium created in such collisions and are expected to thermalize much more slowly than light flavor quarks. For instance, the azimuthal anisotropy of charm quarks with respect to the reaction plane over a broad momentum range can provide insights into the degree of thermalization and the bulk properties of the system. Specifically at low transverse momenta we can examine the bulk properties in the strongly coupled regime. In this talk we present the STAR measurement of elliptic ( v 2 ) and triangular flow ( v 3 ) of D 0 mesons in Au+Au collisions at = 200 GeV obtained from the first year of physics running with the new STAR Heavy Flavor Tracker. Comparison with the azimuthal anisotropy of other particle species and a series of model calculations will be shown, and the charm quark dynamics in the sQGP medium will be discussed. (paper)

  1. Measurement of D 0 elliptic and triangular flow in Au+Au collisions at = 200 GeV at RHIC

    Science.gov (United States)

    Lomnitz, Michael R.; STAR Collaboration

    2017-01-01

    Due to their large masses, heavy quarks are predominantly produced through initial hard scatterings in heavy-ion collisions. As such, they experience the entire evolution of the hot and dense medium created in such collisions and are expected to thermalize much more slowly than light flavor quarks. For instance, the azimuthal anisotropy of charm quarks with respect to the reaction plane over a broad momentum range can provide insights into the degree of thermalization and the bulk properties of the system. Specifically at low transverse momenta we can examine the bulk properties in the strongly coupled regime. In this talk we present the STAR measurement of elliptic (v 2) and triangular flow (v 3) of D 0 mesons in Au+Au collisions at = 200 GeV obtained from the first year of physics running with the new STAR Heavy Flavor Tracker. Comparison with the azimuthal anisotropy of other particle species and a series of model calculations will be shown, and the charm quark dynamics in the sQGP medium will be discussed.

  2. Comparable studies of magnetic properties of Ising spins-5/2 and 3/2 systems on decorated square and triangular lattices

    Energy Technology Data Exchange (ETDEWEB)

    Masrour, R., E-mail: rachidmasrour@hotmail.com [Laboratory of Materials, Processes, Environment and Quality, Cady Ayyed University, National School of Applied Sciences, 63 46000 Safi (Morocco); Jabar, A. [Laboratory of Materials, Processes, Environment and Quality, Cady Ayyed University, National School of Applied Sciences, 63 46000 Safi (Morocco); Benyoussef, A. [Institute of Nanomaterials and Nanotechnologies, MAScIR, Rabat (Morocco); Hassan II Academy of Science and Technology, Rabat (Morocco); Hamedoun, M. [Institute of Nanomaterials and Nanotechnologies, MAScIR, Rabat (Morocco)

    2016-07-15

    In this work, we have studied and compared the magnetic properties of Ising spins-5/2 and 3/2 systems on decorated square and triangular lattices using the Monte Carlo simulations. The transition temperature of the two-dimensional decorated square and triangular lattices has been obtained. The effect of the exchange interactions and crystal field on the magnetization is investigated. The magnetic coercive field and saturation magnetization of the two-dimensional decorated square and triangular lattices have been obtained.

  3. Antioxidant, Iron Chelating and Tyrosinase Inhibitory Activities of Extracts from Talinum triangulare Leach Stem

    Directory of Open Access Journals (Sweden)

    Ana Paula Oliveira Amorim

    2013-07-01

    Full Text Available The aim of this work is to evaluate the antioxidant activity against the radical species DPPH, the reducing capacity against Fe II ions, and the inhibitory activity on the tyrosinase enzyme of the T. triangulare. Hydromethanolic crude extract provided two fractions after the liquid/liquid partition with chloroform. The Folin-Ciocalteu method determined the total phenolic content of the crude extract (CE and the hydromethanolic fraction (Fraction 1, resulting in a concentration of 0.5853 g/100 g for Fraction 1, and 0.1400 g/100 g for the CE. Taking into account the results of the DPPH, the free radical scavenging capacity was confirmed. The formation of complexes with Fe II ions was evaluated by UV/visible spectrometry; results showed that CE has complexing power similar to the positive control (Gingko biloba extract.The inhibitory capacity of samples against the tyrosinase enzyme was determined by the oxidation of L-DOPA, providing IC50 values of 13.3 μg·mL−1 (CE and 6.6 μg·mL−1 (Fraction 1. The values indicate that Fraction 1 was more active and showed a higher inhibitory power on the tyrosinase enzyme than the ascorbic acid, used as positive control. The hydromethanolic extract of T. triangulare proved to have powerful antioxidant activity and to inhibit the tyrosinase enzyme; its potential is increased after the partition with chloroform.

  4. Neutron-scattering cross section of the S=1/2 Heisenberg triangular antiferromagnet

    DEFF Research Database (Denmark)

    Lefmann, K.; Hedegård, P.

    1994-01-01

    In this paper we use a Schwinger-boson mean-field approach to calculate the neutron-scattering cross section from the S = 1/2 antiferromagnet with nearest-neighbor isotropic Heisenberg interaction on a two-dimensional triangular lattice. We investigate two solutions for T = 0: (i) a state with lo...... no elastic, but a set of broader dispersive spin excitations around kappa almost-equal-to (1/2, 0) and around kappa almost-equal-to (1/3, 1/3) for omega/E(g) = 2.5-4. It should thus be possible to distinguish these two states in a neutron-scattering experiment.......In this paper we use a Schwinger-boson mean-field approach to calculate the neutron-scattering cross section from the S = 1/2 antiferromagnet with nearest-neighbor isotropic Heisenberg interaction on a two-dimensional triangular lattice. We investigate two solutions for T = 0: (i) a state with long......-range order resembling the Neel state and (ii) a resonating valence bond or ''spin liquid'' state with an energy gap, E(g) almost-equal-to 0.17J, for the elementary excitations (spinons). For solution (ii) the neutron cross section shows Bragg rods at kappa = K = (1/3, 1/3), whereas solution (ii) shows...

  5. Electron-related linear and nonlinear optical responses in vertically coupled triangular quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Martínez-Orozco, J.C. [Unidad Académica de Física. Universidad Autónoma de Zacatecas, Calzada Solidaridad esquina con Paseo la Bufa S/N, C.P. 98060. Zacatecas, Zac. (Mexico); Grupo de Materia Condensada-UdeA, Instituto de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia); Mora-Ramos, M.E. [Facultad de Ciencias, Universidad Autónoma del Estado de Morelos, Ave. Universidad 1001, CP 62209, Cuernavaca, Morelos (Mexico); Duque, C.A., E-mail: cduque@fisica.udea.edu.co [Grupo de Materia Condensada-UdeA, Instituto de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia)

    2014-11-01

    The conduction band states of GaAs-based vertically coupled double triangular quantum dots in two dimensions are investigated within the effective mass and parabolic approximation, using a diagonalization procedure to solve the corresponding Schrödinger-like equation. The effect of an externally applied static electric field is included in the calculation, and the variation of the lowest confined energy levels as a result of the change of the field strength is reported for different geometrical setups. The linear and nonlinear optical absorptions and the relative change of the refractive index, associated with the energy transition between the ground and the first excited state in the system, are studied as a function of the incident light frequency for distinct configurations of inter-dot distance and electric field intensities. The blueshift of the resonant absorption peaks is detected as a consequence of the increment in the field intensity, whereas the opposite effect is obtained from the increase of inter-dot vertical distance. It is also shown that for large enough values of the electric field there is a quenching of the optical absorption due to field-induced change of symmetry of the first excited state wavefunction, in the case of triangular dots of equal shape and size.

  6. GPU-Accelerated Population Annealing Algorithm: Frustrated Ising Antiferromagnet on the Stacked Triangular Lattice

    Directory of Open Access Journals (Sweden)

    Borovský Michal

    2016-01-01

    Full Text Available The population annealing algorithm is a novel approach to study systems with rough free-energy landscapes, such as spin glasses. It combines the power of simulated annealing, Boltzmann weighted differential reproduction and sequential Monte Carlo process to bring the population of replicas to the equilibrium even in the low-temperature region. Moreover, it provides a very good estimate of the free energy. The fact that population annealing algorithm is performed over a large number of replicas with many spin updates, makes it a good candidate for massive parallelism. We chose the GPU programming using a CUDA implementation to create a highly optimized simulation. It has been previously shown for the frustrated Ising antiferromagnet on the stacked triangular lattice with a ferromagnetic interlayer coupling, that standard Markov Chain Monte Carlo simulations fail to equilibrate at low temperatures due to the effect of kinetic freezing of the ferromagnetically ordered chains. We applied the population annealing to study the case with the isotropic intra- and interlayer antiferromagnetic coupling (J2/|J1| = −1. The reached ground states correspond to non-magnetic degenerate states, where chains are antiferromagnetically ordered, but there is no long-range ordering between them, which is analogical with Wannier phase of the 2D triangular Ising antiferromagnet.

  7. Mean streamwise velocity measurements in a triple jet of equilateral triangular configuration

    Energy Technology Data Exchange (ETDEWEB)

    Moustafa, G.H. (Menoufia Univ. (Egypt). Coll. of Engineering); Sundararajan, T. (IIT Kanpur (India). Dept. of Mechanical Engineering); Rathakrishnan, E. (IIT Kanpur (India). Dept. of Aerospace Engineering)

    1993-09-01

    Multijet flows arise in several applications such as jet engine/rocket combustors, the thrust augmenting ejectors for VTOL/STOL aircraft, and industrial gas burners. In order to achieve proper combustion, thrust development, and reduction in the noise level, it is often desirable to control the inter-mixing between the jets and also the entrainment of the surrounding atmosphere. This, in turn, requires a detailed study of the behavior of high speed jets in multijet configuration. The situation of interest here is an array of three axisymmetric nozzles set in a common end wall with equal spacing in a triangular configuration. The reason why this particular configuration has been chosen is that it promotes bending of the jet axes toward each other, thus leading to greater mixing. In the present study, experiments have been conducted to investigate the effect of stagnation pressure ratio and nozzle spacing upon the mean flow characteristic of compressible jets in triangular configuration. The individual flow features of the vertex jet and the base twin jet are analyzed and their contributions to the axis switching as well as the overall triple jet behavior are highlighted.

  8. Using Chebyshev polynomials and approximate inverse triangular factorizations for preconditioning the conjugate gradient method

    Science.gov (United States)

    Kaporin, I. E.

    2012-02-01

    In order to precondition a sparse symmetric positive definite matrix, its approximate inverse is examined, which is represented as the product of two sparse mutually adjoint triangular matrices. In this way, the solution of the corresponding system of linear algebraic equations (SLAE) by applying the preconditioned conjugate gradient method (CGM) is reduced to performing only elementary vector operations and calculating sparse matrix-vector products. A method for constructing the above preconditioner is described and analyzed. The triangular factor has a fixed sparsity pattern and is optimal in the sense that the preconditioned matrix has a minimum K-condition number. The use of polynomial preconditioning based on Chebyshev polynomials makes it possible to considerably reduce the amount of scalar product operations (at the cost of an insignificant increase in the total number of arithmetic operations). The possibility of an efficient massively parallel implementation of the resulting method for solving SLAEs is discussed. For a sequential version of this method, the results obtained by solving 56 test problems from the Florida sparse matrix collection (which are large-scale and ill-conditioned) are presented. These results show that the method is highly reliable and has low computational costs.

  9. A mass-redistributed finite element method (MR-FEM) for acoustic problems using triangular mesh

    Science.gov (United States)

    He, Z. C.; Li, Eric; Liu, G. R.; Li, G. Y.; Cheng, A. G.

    2016-10-01

    The accuracy of numerical results using standard finite element method (FEM) in acoustic problems will deteriorate with increasing frequency due to the ;dispersion error;. Such dispersion error depends on the balance between the ;stiffness; and ;mass; of discretization equation systems. This paper reports an improved finite element method (FEM) for solving acoustic problems by re-distributing the mass in the mass matrix to ;tune; the balance, aiming to minimize the dispersion errors. This is done by shifting the integration point locations when computing the entries of the mass matrix, while ensuring the mass conservation. The new method is verified through the detailed numerical error analysis, and a strategy is also proposed for the best mass redistribution in terms of minimizing dispersion error. The relative dispersion error of present mass-redistributed finite element method (MR-FEM) is found to be much smaller than the FEM solution, in both theoretical prediction and numerical examination. The present MR-FEM works well by using the linear triangular elements that can be generated automatically, which enables automation in computation and saving computational cost in mesh generation. Numerical examples demonstrate the advantages of MR-FEM, in comparison with the standard FEM using the same triangular meshes and quadrilateral meshes.

  10. Dose Titration Algorithm Tuning (DTAT) should supersede ‘the’ Maximum Tolerated Dose (MTD) in oncology dose-finding trials

    Science.gov (United States)

    Norris, David C.

    2017-01-01

    Background. Absent adaptive, individualized dose-finding in early-phase oncology trials, subsequent ‘confirmatory’ Phase III trials risk suboptimal dosing, with resulting loss of statistical power and reduced probability of technical success for the investigational therapy. While progress has been made toward explicitly adaptive dose-finding and quantitative modeling of dose-response relationships, most such work continues to be organized around a concept of ‘the’ maximum tolerated dose (MTD). The purpose of this paper is to demonstrate concretely how the aim of early-phase trials might be conceived, not as ‘dose-finding’, but as dose titration algorithm (DTA)-finding. Methods. A Phase I dosing study is simulated, for a notional cytotoxic chemotherapy drug, with neutropenia constituting the critical dose-limiting toxicity. The drug’s population pharmacokinetics and myelosuppression dynamics are simulated using published parameter estimates for docetaxel. The amenability of this model to linearization is explored empirically. The properties of a simple DTA targeting neutrophil nadir of 500 cells/mm 3 using a Newton-Raphson heuristic are explored through simulation in 25 simulated study subjects. Results. Individual-level myelosuppression dynamics in the simulation model approximately linearize under simple transformations of neutrophil concentration and drug dose. The simulated dose titration exhibits largely satisfactory convergence, with great variance in individualized optimal dosing. Some titration courses exhibit overshooting. Conclusions. The large inter-individual variability in simulated optimal dosing underscores the need to replace ‘the’ MTD with an individualized concept of MTD i . To illustrate this principle, the simplest possible DTA capable of realizing such a concept is demonstrated. Qualitative phenomena observed in this demonstration support discussion of the notion of tuning such algorithms. Although here illustrated specifically

  11. Tunable terahertz emission from the intrinsic Josephson junctions in acute isosceles triangular Bi₂Sr₂CaCu₂O₈+δ mesas.

    Science.gov (United States)

    Delfanazari, K; Asai, H; Tsujimoto, M; Kashiwagi, T; Kitamura, T; Yamamoto, T; Sawamura, M; Ishida, K; Watanabe, C; Sekimoto, S; Minami, H; Tachiki, M; Klemm, R A; Hattori, T; Kadowaki, K

    2013-01-28

    In order to determine if the mesa geometry might affect the properties of the coherent terahertz (THz) radiation emitted from the intrinsic Josephson junctions in mesas constructed from single crystals of the high-temperature superconductor, Bi₂Sr₂CaCu₂O₈+δ, we studied triangular mesas. For equilateral triangular mesas, the observed emission was found to be limited to the single mesa TM(1,0) mode. However, tunable radiation over the range from 0.495 to 0.934 THz was found to arise from an acute isosceles triangular mesa. This 47% tunability is the widest yet observed from the outer current-voltage characteristic branch of such mesas of any geometry. Although the radiation at a few of the frequencies in the tunable range appear to have been enhanced by cavity resonances, most frequencies are far from such resonance frequencies, and can only be attributed to the ac-Josephson effect.

  12. Acid-base titrations by stepwise addition of equal volumes of titrant with special reference to automatic titrations-II Theory of titration of mixtures of acids, polyprotic acids, acids in mixture with weak bases, and ampholytes.

    Science.gov (United States)

    Pehrsson, L; Ingman, F; Johansson, S

    A general method for evaluating titration data for mixtures of acids and for acids in mixture with weak bases is presented. Procedures are given that do not require absolute [H]-data, i.e., relative [H]-data may be used. In most cases a very rough calibration of the electrode system is enough. Further, for simple systems, very approximate values of the stability constants are sufficient. As examples, the titration of the following are treated in some detail: a mixture of two acids, a diprotic acid, an acid in presence of its conjugate base, and an ampholyte.

  13. Monitoring Acid–Base Titrations on Wax Printed Paper Microzones Using a Smartphone

    Directory of Open Access Journals (Sweden)

    Sandro A. Nogueira

    2017-05-01

    Full Text Available This study describes the use of a smartphone for monitoring acid–base titrations on wax printed paper microzones. An array of twelve microzones of 5 mm diameter each was wax printed on filter paper. The analytical performance of the proposed devices was explored with acid–base titrations examples, where jaboticaba peel extract was used as a natural pH indicator. The color intensity was captured using a smartphone and analyzed through a free App named Photometrix®. Before titrations, color intensity versus pH was calibrated to be used as a reference in titrations as (i strong acid versus strong base; (ii strong base versus strong acid; and (iii weak acid versus strong base. In all examples, images were obtained after the addition of each aliquot of titrant solutions. The obtained titration curves showed the same behavior as the conventional titration curves. After evaluating the feasibility of the proposed methodology, the concentration level of acetic acid was obtained in three vinegar samples. Although the obtained values ranged from 5% to 8% compared to the concentrations on the conventional method, the proposed methodology presented high analytical reliability. The calculated concentrations of acetic acid in three samples ranged from 3.87% to 3.93%, and the proposed methodology did not significantly differ from classic acid–base titration at a confidence level of 95%. The acid–base titration on paper-based devices is outstanding, since any titration can be completed within 5 min using 20 µL volumes. Besides, the use of a smartphone to capture images followed by analysis in a free app offers simplicity to all users. The proposed methodology arises as a new strand to be exploited in the diffusion of the analytical chemistry education field as well as an alternative for quantitative analysis with extremely simplified instrumentation.

  14. Simultaneous determination of equivalence volumes and acid dissociation constants from potentiometric titration data.

    Science.gov (United States)

    Papanastasiou, G; Ziogas, I

    1995-06-01

    New iterative methods for analysis of potentiometric titration data of (a) mixtures of weak monoprotic acids with their conjugate bases, (b) solutions of polyprotic (di- and triprotic) acids, and (c) mixtures of two diprotic acids are presented. These methods, using data exclusively resulting from the acidic region of the titration curve permits the accurate determination of the analytical concentration of one or more acids even if the titration is stopped well before the end point of the titration. For the titration of a solution containing a conjugate acid/base pair, the proposed procedure enables the extraction of the initial composition of the mixture, as well as the dissociation constant of the concerned acid. Thus, it is possible by this type of analysis to distinguish whether a weak acid has been contaminated by a strong base and define the extent of the contamination. On the other hand, for the titration of polyprotic acids, the proposed approach enables the extraction of the accurate values of the equivalence volume and the dissociation constants K(i) even when the ionization stages overlap. Finally, for the titration of a mixture of two diprotic acids the proposed procedure enables the determination of the composition of the mixture even if the sum of the concentrations of the acids is not known. This method can be used in the analysis of solutions containing two diastereoisomeric forms of a weak diprotic acid. The test of the proposed procedures by means of ideal and Monte Carlo simulated data revealed that these methods are fairly applicable even when the titration data are considerably obscured by 'noise' or contain an important systematic error. The proposed procedures were also successfully applied to experimental titration data.

  15. Implementation of a pharmacist-managed heart failure medication titration clinic.

    Science.gov (United States)

    Martinez, Amanda S; Saef, Jerold; Paszczuk, Anna; Bhatt-Chugani, Hetal

    2013-06-15

    The development, implementation, and initial results of a pharmacist-managed heart failure (HF) medication titration clinic are described. In a quality-improvement initiative at a Veterans Affairs health care system, clinical pharmacists were incorporated into the hospital system's interprofessional outpatient HF clinic. In addition, a separate pharmacist-managed HF medication titration clinic was established, in which pharmacists were granted an advanced scope of practice and prescribing privileges, enabling them to initiate and adjust medication dosages under specific protocols jointly established by cardiology and pharmacy staff. Pharmacists involved in the titration clinic tracked patients' daily body weight, vital signs, and volume status using telephone-monitoring technology and via patient interviews. A retrospective chart review comparing achievement of target doses of angiotensin-converting enzyme inhibitor (ACEI), angiotensin-receptor blocker (ARB), and β-blocker therapies in a group of patients (n = 28) whose dosage titrations were carried out by nurses or physicians prior to implementation of the pharmacist-managed HF medication titration clinic and a group of patients (n = 27) enrolled in the medication titration clinic during its first six months of operation indicated that target ACEI and ARB doses were achieved in a significantly higher percentage of pharmacist-managed titration clinic enrollees (52.9% versus 31%, p = 0.007). Patients enrolled in the pharmacist-managed HF medication titration clinic also had a significantly higher rate of attainment of optimal β-blocker doses (49% versus 24.7%, p = 0.012). Implementation of a pharmacist-managed HF medication titration clinic increased the percentage of patients achieving optimal ACEI, ARB, and β-blocker dosages.

  16. Persistent benefits of slow titration of paroxetine in a six-month follow-up.

    Science.gov (United States)

    Olgiati, Paolo; Serretti, Alessandro

    2015-09-01

    Paroxetine titration may be difficult in older individuals as they are more sensitive to side effects. The current study extends to 6 months our previously published report in which paroxetine was started at 2.5 mg/day and slowly increased by 2.5 mg on alternate days (slow titration) or rapidly titrated to target dose from 10 mg/day (standard titration) in a naturalistic setting. Here, the follow-up period was extended to 26 weeks. We performed an intent-to-treat analysis of 47 subjects from the original sample (major depressive disorder and/or generalized anxiety disorder (GAD); >60 years of age). Missing evaluations were replaced by last observations carried forward. GAD was included as a stratification factor. Patients in whom paroxetine was slowly up-titrated were more likely to remit (84.0% vs 54.5%; p = 0.028) and had lower core depression (p = 0.0015) and psychic anxiety levels (p = 0.006) after 26 weeks. Dropout rate was 20% in the slow titration group compared with 77.3% in the standard titration arm (p titration groups in the subsample without GAD. Despite some limitations, these findings suggest that paroxetine treatment should be started at lower doses in older depressed patients and slowly up-titrated. This strategy would allow to increase antidepressant response and the likelihood of completing treatment cycle in patients with high anxiety levels and GAD comorbidity. Copyright © 2015 John Wiley & Sons, Ltd.

  17. Effect of a stirring process in an isothermal titration microcalorimeter

    Energy Technology Data Exchange (ETDEWEB)

    Socorro, F.; Nuez, I. de la; Alvarez, L.; Rodriguez de Rivera, M

    2004-10-01

    In this paper, it is analysed the way in which the thermodynamic results obtained in an isothermal titration microcalorimeter, with continuous injection of a liquid and a variable mass are affected. Two aspects are presented, the first one refers to a variation in the baseline that takes place when the liquid mass is increased in the laboratory cell, this variation is due to the change in the thermal coupling between the stirrer and its contact with the thermostat. The second aspect is the analysis of the effect of the stirring process and the injection velocity on the homogenization of the remaining mixture in the laboratory cell. The aim of the study of these two previous aspects is to increase the accuracy of the thermodynamic measures carried out. The variation of the baseline affects in a percentage from 1 to 2% of the total energy developed. It is also shown the necessity of a stirring process according to the injection velocity in order to obtain a homogeneous mixture at every instant. This fact allows to carry out a deconvolution of the calorimetric signal and to obtain directly the power developed in the mixture process in terms of the amount of mixed substance [Meas. Sci. Technol. 1 (1990) pp. 1285-1290; J. Thermal Analysis 41 (1994) pp. 1385-1392].

  18. Electrically injected ultra-low threshold room temperature InGaN/GaN-based lateral triangular nanowire laser

    Science.gov (United States)

    Banerjee, D.; Takhar, K.; Sankaranarayanan, S.; Upadhyay, P.; Ruia, R.; Chouksey, S.; Khachariya, D.; Ganguly, S.; Saha, D.

    2015-09-01

    We have demonstrated an electrically injected ultra-low threshold (8.9 nA) room temperature InGaN/GaN based lateral nanowire laser. The nanowires are triangular in shape and survived naturally after etching using boiling phosphoric acid. A polymethyl methacrylate (PMMA) and air dielectric distributed mirror provide an optical feedback, which together with one-dimensional density of states cause ultra-low threshold lasing. Finite difference eigen-mode (FDE) simulation shows that triangular nanowire cavity supports single dominant mode similar to TE01 that of a corresponding rectangular cavity with a confinement factor of 0.18.

  19. Monitoring Acid–Base Titrations on Wax Printed Paper Microzones Using a Smartphone

    OpenAIRE

    Sandro A. Nogueira; Lucas R. Sousa; Nathália K. L. Silva; Pedro H. F. Rodrigues; Wendell K. T. Coltro

    2017-01-01

    This study describes the use of a smartphone for monitoring acid–base titrations on wax printed paper microzones. An array of twelve microzones of 5 mm diameter each was wax printed on filter paper. The analytical performance of the proposed devices was explored with acid–base titrations examples, where jaboticaba peel extract was used as a natural pH indicator. The color intensity was captured using a smartphone and analyzed through a free App named Photometrix®. Before titrations, color int...

  20. Amperometric titration of thorium and some lanthanoids in acetic-acid medium using two indicator electrodes

    International Nuclear Information System (INIS)

    Khadeev, V.A.; Gevorgyan, A.M.; Talipov, Sh.T.; Kostylev, V.S.

    1979-01-01

    The votammetric behaviour of nitriletrimethylphosphonic acid (NTMP) in the medium of anhydrous acetic acid with different backgrounds in the anode region of polarization of a platinum microdisk electrode, is studied. The optimal conditions are found for the amperometric titration with two indicator electrodes of thorium and same lanthanides by a NTMP solution in anhydrous acetic medium. The influence of foreign anions and cations on the results of titration by the NTPM solution in anhydrous acetic acid is studied. The selectivity of titration in anhydrous medium is higher than in aqueous

  1. On the Physical Meaning of the Isothermal Titration Calorimetry Measurements in Calorimeters with Full Cells

    Science.gov (United States)

    Grolier, Jean-Pierre E.; del Río, Jose Manuel

    2009-01-01

    We have performed a detailed study of the thermodynamics of the titration process in an isothermal titration calorimeter with full cells. We show that the relationship between the enthalpy and the heat measured is better described in terms of the equation Δ H = Winj + Q (where Winj is the work necessary to carry out the titration) than in terms of ΔH = Q. Moreover, we show that the heat of interaction between two components is related to the partial enthalpy of interaction at infinite dilution of the titrant component, as well as to its partial volume of interaction at infinite dilution. PMID:20054472

  2. Characterization of antibody-chelator conjugates: Determination of chelator content by terbium fluorescence titration

    Energy Technology Data Exchange (ETDEWEB)

    Brandt, K.D.; Schnobrich, K.E.; Johnson, D.K. (Abbott Laboratories, Department 90M, Abbott Park, IL (United States))

    1991-01-01

    Fluorescence titrations were performed by adding varying mole ratios of terbium(III) to antibody conjugates formed by benzyl isothiocyanate derivatives of three different polyaminopolycarboxylate chelators (NTA, EDTA, and DTPA) and the results compared to values for average chelator content obtained by cobalt-57 binding assays. For two different murine monoclonal antibodies, the average chelator content obtained by terbium fluorescence titration correlated closely with that measured by the cobalt-57 binding assay. It is concluded that lanthanide fluorescence titrations provide a useful alternative to radiometal binding assays for the determination of chelator content in protein-chelator conjugates.

  3. Accurate and precise determination of 2-25mg amounts of uranium by means of a special automatic potentiometric titration

    International Nuclear Information System (INIS)

    Slanina, J.; Bakker, F.; Groen, A.J.P.; Lingerak, W.A.

    1978-01-01

    A precise and accurate potentiometric titration of 2-25 mg of uranium is described. The uranium is reduced to U(IV) according to the method of Eberle et al. [3], and titrated with 0.05 N potassium dichromate, using a platinum indicator electrode. During the sample preparation the walls of the titration vessel are cleaned by centrifugation. To avoid overshoot of the set point a special differentiator is described, that interrupts the titration until equilibrium is reached. The precision of the method is 0.02%, the accuracy is better than 0.04% rel. Each titration takes 5 min. (orig.) [de

  4. A novel Galerkin-like weakform and a superconvergent alpha finite element method (S αFEM) for mechanics problems using triangular meshes

    Science.gov (United States)

    Liu, G. R.; Nguyen-Xuan, H.; Nguyen-Thoi, T.; Xu, X.

    2009-06-01

    A carefully designed procedure is presented to modify the piecewise constant strain field of linear triangular FEM models, and to reconstruct a strain field with an adjustable parameter α. A novel Galerkin-like weakform derived from the Hellinger-Reissner variational principle is proposed for establishing the discretized system equations. The new weak form is very simple, possesses the same good properties of the standard Galerkin weakform, and works particularly well for strain construction methods. A superconvergent alpha finite element method (S αFEM) is then formulated by using the constructed strain field and the Galerkin-like weakform for solid mechanics problems. The implementation of the S αFEM is straightforward and no additional parameters are used. We prove theoretically and show numerically that the S αFEM always achieves more accurate and higher convergence rate than the standard FEM of triangular elements (T3) and even more accurate than the four-node quadrilateral elements (Q4) when the same sets of nodes are used. The S αFEM can always produce both lower and upper bounds to the exact solution in the energy norm for all elasticity problems by properly choosing an α. In addition, a preferable- α approach has also been devised to produce very accurate solutions for both displacement and energy norms and a superconvergent rate in the energy error norm. Furthermore, a model-based selective scheme is proposed to formulate a combined S αFEM/NS-FEM model that handily overcomes the volumetric locking problems. Intensive numerical studies including singularity problems have been conducted to confirm the theory and properties of the S αFEM.

  5. El modelo probabilístico rectangular-triangular. Aplicación a la tasación de fincas rústicas

    Directory of Open Access Journals (Sweden)

    Herrerías Velasco, José Manuel

    2009-01-01

    Full Text Available RESUMEN En el presente trabajo se estudia, en primer lugar, una superficie de probabilidad resultante de la mezcla de las distribuciones continuas univariantes rectangular y triangular. En segundo lugar, a través de su análisis se concluye que sus componentes se comportan como variables aleatorias independientes lo que permite disponer de un modelo probabilístico, muy apropiado para la tasación de fincas rusticas mediante el método de valoración comparativo denominado como método de las dos betas, en el caso de que, como es usual, se dispongan de pocos datos para realizar comparaciones y simultáneamente se disponga de un indicador bidimensional para la calidad de la finca tal que sus componentes unidimensionales no estén relacionadas.En tercer lugar, se aplica el modelo probabilístico bivariante a un caso práctico de la literatura especializada de tasación de fincas rústicas, encontrándose la misma dificultad de cálculo que en los modelos univariantes, si las variables aleatorias son estocásticamente independientes.ABSTRACT The present study focuses, first, a surface probability resulting from the mixture of univariate continuous distributions rectangular and triangular. Secondly, through its analysis it is concluded that the components behave as independent random variables which provides a probabilistic model suitable for the farm valuation using the comparative method of the two betas distributions. In the case that, as usual, few data are available for comparison and simultaneously have a bidimensional indicator for the quality of the property that its unidimensional components are not related.Third, the bivariate probabilistic model is applied to a studied case of the literature on farm valuation, if random variables are stochastically independent this procedure has the same difficulty of calculation of univariate models.

  6. Application of titration methods for measuring the contents of ammonium nitrogen and volatile fatty acids in agricultural biogas plants.

    Science.gov (United States)

    Piątek, Michał; Lisowski, Aleksander; Lisowska, Barbara

    2017-12-20

    The aim of our research was to assess a relatively new method of estimating ammonium nitrogen concentration in anaerobic digestion of plant substrates. We analysed our own data, received from the anaerobic digestion of maize silage (PM), as well as data published by Purser et al. (2014) who measured energy crops and slurry (ECS), and food waste (FW). In our study, the process was monitored for VFA content that was determined by gas chromatography, and for the content of ammonium nitrogen determined using the HACH LANGE LCK 303 cuvette test. We created polynomial regression models that bind the content of ammonium nitrogen with the volume of H 2 SO 4 used to titrate the sample from initial pH to pH 5. To estimate parameters of model, the PM dataset was used. The obtained models were positively validated using ECS and FW datasets. Our results confirmed the effectiveness of the Purser et al. method with an average absolute error of less than 223mgl -1 of the VFA concentration, which was approximately 20-times less than the level that caused inhibition. In conclusion, we can affirm the suitability of using titration methods to assess the ammonium nitrogen content of bioreactors with a stable composition. Copyright © 2017 Elsevier B.V. All rights reserved.

  7. Modified spin-wave theory with ordering vector optimization: frustrated bosons on the spatially anisotropic triangular lattice

    Energy Technology Data Exchange (ETDEWEB)

    Hauke, Philipp [ICFO-Institut de Ciencies Fotoniques, Meditarranean Technology Park, E-08860 Castelldefels, Barcelona (Spain); Roscilde, Tommaso [Laboratoire de Physique, Ecole Normale Superieure de Lyon, 46 Allee d' Italie, F-69007 Lyon (France); Murg, Valentin; Ignacio Cirac, J; Schmied, Roman, E-mail: Philipp.Hauke@icfo.e [Max-Planck-Institut fuer Quantenoptik, Hans-Kopfermann-Strasse 1, D-85748 Garching (Germany)

    2010-05-15

    We investigate a system of frustrated hardcore bosons, modeled by an XY antiferromagnet on the spatially anisotropic triangular lattice, using Takahashi's modified spin-wave (MSW) theory. In particular, we implement ordering vector optimization on the ordered reference state of MSW theory, which leads to significant improvement of the theory and accounts for quantum corrections to the classically ordered state. The MSW results at zero temperature compare favorably to exact diagonalization (ED) and projected entangled-pair state (PEPS) calculations. The resulting zero-temperature phase diagram includes a one-dimensional (1D) quasi-ordered phase, a 2D Neel ordered phase and a 2D spiraling ordered phase. Strong indications coming from the ED and PEPS calculations, as well as from the breakdown of MSW theory, suggest that the various ordered or quasi-ordered phases are separated by spin-liquid phases with short-range correlations, in analogy to what has been predicted for the Heisenberg model on the same lattice. Within MSW theory, we also explore the finite-temperature phase diagram. In agreement with the Berezinskii-Kosterlitz-Thouless (BKT) theory, we find that zero-temperature long-range-ordered phases turn into quasi-ordered phases (up to a BKT transition temperature), while zero-temperature quasi-ordered phases become short-range correlated at finite temperature. These results show that, despite its simplicity, MSW theory is very well suited to describing ordered and quasi-ordered phases of frustrated XY spins (or, equivalently, of frustrated lattice bosons) both at zero and finite temperatures. While MSW theory, just as other theoretical methods, cannot describe spin-liquid phases, its breakdown provides a fast and reliable method for singling out Hamiltonians that may feature these intriguing quantum phases. We thus suggest a tool for guiding our search for interesting systems whose properties are necessarily studied with a physical quantum simulator

  8. Modified spin-wave theory with ordering vector optimization: frustrated bosons on the spatially anisotropic triangular lattice

    Science.gov (United States)

    Hauke, Philipp; Roscilde, Tommaso; Murg, Valentin; Cirac, J. Ignacio; Schmied, Roman

    2010-05-01

    We investigate a system of frustrated hardcore bosons, modeled by an XY antiferromagnet on the spatially anisotropic triangular lattice, using Takahashi's modified spin-wave (MSW) theory. In particular, we implement ordering vector optimization on the ordered reference state of MSW theory, which leads to significant improvement of the theory and accounts for quantum corrections to the classically ordered state. The MSW results at zero temperature compare favorably to exact diagonalization (ED) and projected entangled-pair state (PEPS) calculations. The resulting zero-temperature phase diagram includes a one-dimensional (1D) quasi-ordered phase, a 2D Néel ordered phase and a 2D spiraling ordered phase. Strong indications coming from the ED and PEPS calculations, as well as from the breakdown of MSW theory, suggest that the various ordered or quasi-ordered phases are separated by spin-liquid phases with short-range correlations, in analogy to what has been predicted for the Heisenberg model on the same lattice. Within MSW theory, we also explore the finite-temperature phase diagram. In agreement with the Berezinskii-Kosterlitz-Thouless (BKT) theory, we find that zero-temperature long-range-ordered phases turn into quasi-ordered phases (up to a BKT transition temperature), while zero-temperature quasi-ordered phases become short-range correlated at finite temperature. These results show that, despite its simplicity, MSW theory is very well suited to describing ordered and quasi-ordered phases of frustrated XY spins (or, equivalently, of frustrated lattice bosons) both at zero and finite temperatures. While MSW theory, just as other theoretical methods, cannot describe spin-liquid phases, its breakdown provides a fast and reliable method for singling out Hamiltonians that may feature these intriguing quantum phases. We thus suggest a tool for guiding our search for interesting systems whose properties are necessarily studied with a physical quantum simulator instead

  9. Proton migration along the membrane surface in the absence of charged or titratable groups

    International Nuclear Information System (INIS)

    Springer, A.

    2011-01-01

    Proton diffusion along membrane surfaces is thought to be essential for many cellular processes such as energy transduction. For example, proton diffusion along membrane surfaces is considered to be the dominant mechanism of proton exchange between membrane sites of high and low proton concentrations. For the investigation of this mechanism, kinetic experiments on proton diffusion are evaluated to determine the ability of lipid membranes to retain protons on their surfaces. Experiments on different lipid bilayer membranes (DPhPC, DPhPE and GMO) are performed under the influence of two types of mobile buffer molecules (Capso, NH4CL). During these experiments the surface diffusion of photolytically released protons is visualized in terms of fluorescence changes of a lipid bound pH-sensitive dye (DHPE +fluorescein). The protons under investigation are released by flash photolysis of a hydrophobic caged compound (DMCM, caged diethyl phosphate). The experimental data confirm the existence of an energy barrier, which prevents the protons from escaping into the bulk. So far this effect was attributed to the proton binding to titrateable groups (e.g. ethanolamine) or electrostatic forces created by charged moieties (e.g. phosphate groups) on the membrane/water interface. However, upon removal of the titrateable groups and charged moieties from the membrane surface, a significant energy barrier remained as indicated by the experiments with glycerol monooleate (GMO) bilayers. To estimate the size of the barrier a semi-analytical model is presented that describes the two and three dimensional proton diffusion and the related physical and chemical processes. Common models describe surface proton diffusion as a series of subsequent hopping processes between membrane-anchored buffer molecules. Our experiments provide evidence for an alternative model. We released membrane-bound caged protons by UV flashes and monitored their arrival at distant sites s by fluorescence

  10. High magnetic field behaviour of the triangular lattice antiferromagnet, CuFeO2

    International Nuclear Information System (INIS)

    Petrenko, O.A.; Balakrishnan, G.; Lees, M.R.; Paul, D.McK.; Hoser, A.

    2001-01-01

    The magnetic phase diagram of the triangular lattice antiferromagnet CuFeO 2 has been studied using single-crystal neutron diffraction measurements in a magnetic field of up to 14.5 T and also by magnetisation measurements up to 12 T. At low temperature, two well-defined first-order magnetic phase transitions were found in this range of applied magnetic field: at H C1 =7.6 T and H C2 =13.2 T, with the later one corresponding to a transition from a four to five sublattice structure. Cooling the sample in a high magnetic field resulted in the locking of the magnetic structure into the intermediate temperature incommensurate structure

  11. Micromagnetic simulations of 200-nm-diameter cobalt nanorings using a Reuleaux triangular geometry

    International Nuclear Information System (INIS)

    Torres-Heredia, J.J.; Lopez-Urias, F.; Munoz-Sandoval, E.

    2006-01-01

    Using micromagnetic simulations, we investigated the magnetic states and switching processes of Co nanorings with lateral dimensions of 200 nm. We propose a special geometry of nanorings that adopts different Reuleaux triangular shapes. Reuleaux's triangles (RT) combine both the equilateral triangle and circular geometries. We studied the magnetic spin configurations of individual nanorings by varying the thickness and geometry of the nanomagnets. Our results demonstrated that in most nanomagnets exhibiting a thickness of less than 4 nm, there exists an onion-type state, which precedes either a twisted, double twisted, or cardioid state, when studying the magnetization reversal process. The hysteresis loops and magnetic states found in these RTs are compared with circular nanorings

  12. Fitting polynomial surfaces to triangular meshes with Voronoi Squared Distance Minimization

    KAUST Repository

    Nivoliers, Vincent

    2011-12-01

    This paper introduces Voronoi Squared Distance Minimization (VSDM), an algorithm that fits a surface to an input mesh. VSDM minimizes an objective function that corresponds to a Voronoi-based approximation of the overall squared distance function between the surface and the input mesh (SDM). This objective function is a generalization of Centroidal Voronoi Tesselation (CVT), and can be minimized by a quasi-Newton solver. VSDM naturally adapts the orientation of the mesh to best approximate the input, without estimating any differential quantities. Therefore it can be applied to triangle soups or surfaces with degenerate triangles, topological noise and sharp features. Applications of fitting quad meshes and polynomial surfaces to input triangular meshes are demonstrated.

  13. Facile synthesis and photoluminescence spectroscopy of 3D-triangular GaN nano prism islands.

    Science.gov (United States)

    Kumar, Mukesh; Pasha, S K; Shibin Krishna, T C; Singh, Avanish Pratap; Kumar, Pawan; Gupta, Bipin Kumar; Gupta, Govind

    2014-08-21

    We report a strategy for fabrication of 3D triangular GaN nano prism islands (TGNPI) grown on Ga/Si(553) substrate at low temperature by N2(+) ions implantation using a sputtering gun technique. The annealing of Ga/Si(553) (600 °C) followed by nitridation (2 keV) shows the formation of high quality GaN TGNPI cross-section. TGNPI morphology has been confirmed by atomic force microscopy. Furthermore, these nano prism islands exhibit prominent ultra-violet luminescence peaking at 366 nm upon 325 nm excitation wavelength along with a low intensity yellow luminescence broad peak at 545 nm which characterizes low defects density TGNPI. Furthermore, the time-resolved spectroscopy of luminescent TGNPI in nanoseconds holds promise for its futuristic application in next generation UV-based sensors as well as many portable optoelectronic devices.

  14. Sobre relaciones laborales triangulares: La subcontratación y el suministro de trabajadores

    Directory of Open Access Journals (Sweden)

    José Luis Ugarte Cataldo

    2006-01-01

    Full Text Available Las relaciones laborales triangulares puede adoptar, en lo fundamental, dos modalidades: la subcontratación laboral y el suministro de trabajadores por la vía de una empresa de trabajo temporal. La primera se refiere a la situación en que una empresa, dueña de una obra o faena, contrata a otra empresa, denominada contratista, mediante un contrato civil o comercial, para que ejecute a su cuenta y riesgo, con sus propios trabajadores, un determinado trabajo o servicio, pudiendo esta última a su turno, contratar a otra empresa, denominada subcontratista, para que lleve a cabo el trabajo o servicio requerido. La segunda, en cambio, consiste en que una empresa, cuyo giro corresponde al suministro de trabajadores (empresa suministradora o de trabajo temporal, pone a disposición de otra empresa (denominada usuaria, por el pago de un precio determinado, los servicios laborales de sus empleados, reteniendo para sí la calidad formal de empleador. En Chile, mientras la figura de la subcontratación laboral data de antiguo, y está regulada en la legislación vigente, el caso del suministro es distinto: sólo en los últimos años se presenta como un fenómeno de relevancia para la comunidad jurídica nacional, en directa relación con el momento de moda que vive la denominada descentralización productiva, que no se encuentra, por lo demás, reconocida en nuestra legislación laboral. La regulación de ambos tipos de relaciones triangulares es el objetivo al que va a la dirigido nueva ley de subcontratación: por una parte, se reconoce y regula por primera vez en Chile la figura del suministro de personal a través de lo que denomina empresas de servicios transitorios, y se perfecciona, por otra, la regulación de la subcontratación laboral mediante nuevas normas sobre la responsabilidad del dueño de la obraThe triangular labour relations could basically adopt two modalities: labour subcontracting and the supplying of workers by a temporary

  15. Low temperature properties of the triangular-lattice antiferromagnet: a bosonic spinon theory

    Science.gov (United States)

    Mezio, A.; Manuel, L. O.; Singh, R. R. P.; Trumper, A. E.

    2012-12-01

    We study the low temperature properties of the triangular-lattice Heisenberg antiferromagnet with a mean field Schwinger spin-\\frac {1}{2} boson scheme that reproduces quantitatively the zero temperature energy spectrum derived previously using series expansions. By analyzing the spin-spin and the boson density-density dynamical structure factors, we identify the unphysical spin excitations that come from the relaxation of the local constraint on bosons. This allows us to reconstruct a free energy based on the physical excitations only, whose predictions for entropy and uniform susceptibility seem to be reliable within the temperature range 0 ⩽ T ≲ 0.3J, which is difficult to access by other methods. The high values of entropy, also found in high temperature expansion studies, can be attributed to the roton-like narrowed dispersion at finite temperatures.

  16. Low temperature properties of the triangular-lattice antiferromagnet: a bosonic spinon theory

    International Nuclear Information System (INIS)

    Mezio, A; Manuel, L O; Trumper, A E; Singh, R R P

    2012-01-01

    We study the low temperature properties of the triangular-lattice Heisenberg antiferromagnet with a mean field Schwinger spin- 1/2 boson scheme that reproduces quantitatively the zero temperature energy spectrum derived previously using series expansions. By analyzing the spin–spin and the boson density–density dynamical structure factors, we identify the unphysical spin excitations that come from the relaxation of the local constraint on bosons. This allows us to reconstruct a free energy based on the physical excitations only, whose predictions for entropy and uniform susceptibility seem to be reliable within the temperature range 0 ⩽ T ≲ 0.3J, which is difficult to access by other methods. The high values of entropy, also found in high temperature expansion studies, can be attributed to the roton-like narrowed dispersion at finite temperatures. (paper)

  17. Triangular relationship between sleep spindle activity, general cognitive ability and the efficiency of declarative learning.

    Science.gov (United States)

    Lustenberger, Caroline; Maric, Angelina; Dürr, Roland; Achermann, Peter; Huber, Reto

    2012-01-01

    EEG sleep spindle activity (SpA) during non-rapid eye movement (NREM) sleep has been reported to be associated with measures of intelligence and overnight performance improvements. The reticular nucleus of the thalamus is generating sleep spindles in interaction with thalamocortical connections. The same system enables efficient encoding and processing during wakefulness. Thus, we examined if the triangular relationship between SpA, measures of intelligence and declarative learning reflect the efficiency of the thalamocortical system. As expected, SpA was associated with general cognitive ability, e.g. information processing speed. SpA was also associated with learning efficiency, however, not with overnight performance improvement in a declarative memory task. SpA might therefore reflect the efficiency of the thalamocortical network and can be seen as a marker for learning during encoding in wakefulness, i.e. learning efficiency.

  18. Highly Selective Dual-Mode Microstrip Bandpass Filters Using Triangular Patch Resonators

    Directory of Open Access Journals (Sweden)

    K.G. Avinash

    2017-03-01

    Full Text Available In this paper, highly selective dual-mode microstrip bandpass filters are proposed using horizontal and vertical slots formed on the surface of a triangular patch. Slots are responsible for splitting and coupling of dual degenerate modes and also facilitate in controlling their resonant frequencies by varying the dimensions of the slots. Horizontal and vertical slots reroute the direction of the flow of current on the surface of the patch, which results in switching of transmission zeros. Two 2-pole and one 4-pole dual-mode filters are designed, simulated and fabricated. Two pole filters have transmission zeros on side of the passband and four pole filter have transmission zeros on both sides of the passband. The designed filters exhibit a fractional bandwidth of less than 7 % and there is a good agreement between simulated and measured results.

  19. Fitting polynomial surfaces to triangular meshes with Voronoi squared distance minimization

    KAUST Repository

    Nivoliers, Vincent

    2012-11-06

    This paper introduces Voronoi squared distance minimization (VSDM), an algorithm that fits a surface to an input mesh. VSDM minimizes an objective function that corresponds to a Voronoi-based approximation of the overall squared distance function between the surface and the input mesh (SDM). This objective function is a generalization of the one minimized by centroidal Voronoi tessellation, and can be minimized by a quasi-Newton solver. VSDM naturally adapts the orientation of the mesh elements to best approximate the input, without estimating any differential quantities. Therefore, it can be applied to triangle soups or surfaces with degenerate triangles, topological noise and sharp features. Applications of fitting quad meshes and polynomial surfaces to input triangular meshes are demonstrated. © 2012 Springer-Verlag London.

  20. Application of the control volume mixed finite element method to a triangular discretization

    Science.gov (United States)

    Naff, R.L.

    2012-01-01

    A two-dimensional control volume mixed finite element method is applied to the elliptic equation. Discretization of the computational domain is based in triangular elements. Shape functions and test functions are formulated on the basis of an equilateral reference triangle with unit edges. A pressure support based on the linear interpolation of elemental edge pressures is used in this formulation. Comparisons are made between results from the standard mixed finite element method and this control volume mixed finite element method. Published 2011. This article is a US Government work and is in the public domain in the USA. ?? 2012 John Wiley & Sons, Ltd. This article is a US Government work and is in the public domain in the USA.