WorldWideScience

Sample records for model ni kansuru

  1. Model experiments on imaging subsurface fracture permeability by pulsed Doppler borehole televiewer; Pulse doppler borehole televiewer ni yoru kiretsu tosuisei hyoka ni kansuru model jikken

    Energy Technology Data Exchange (ETDEWEB)

    Inagaki, Y.; Niitsuma, H. [Tohoku University, Sendai (Japan). Faculty of Engineering

    1996-05-01

    This paper reports model experiments to evaluate flow rates of fluids passing through a fracture by using a Doppler borehole televiewer (DBHTV). A supersonic transducer disposed on a well axis transmits transmission pulses, and a transducer receives scattered waves generated by particulates in water and waves reflected on a well wall. This signal is applied with time gating to extract only the scattered waves from particulates in the vicinity of the well wall. Deriving spectra in the recorded Doppler signal obtains flow velocity components in the direction of the well radius. A model was made with a polyvinylchloride pipe with a diameter of 14.6 cm to simulate a well, to which an aluminum pipe with an inner diameter of 2 mm is connected to be used as a simulated fracture, and mud water is circulated in the pipe. The result of deriving a passed flow volume in this model by integrating flow rate distribution derived by using the above method to a predetermined range in the vicinity of the fracture showed a good proportional relationship with actual flow rate in the simulated fracture. 1 ref., 7 figs.

  2. Studies on surface tension effect for free surface flow around floating models; Futai mokei mawari no jiyu hyomenryu ni oyobosu hyomen choryoku no eikyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, K. [Yokohama National Univ., Yokohama (Japan). Faculty of Engineering; Akiba, H. [Toyo Construction Co. Ltd., Tokyo (Japan)

    1996-12-31

    The effect of surface tension on free surface flow around floating models is discussed experimentally and numerically. Three-dimensional free surface flow around vertical circular cylinders floating in a circulating water channel was visually observed, where a surface-active agent was added to water. The results are analyzed using Weber number. The numerical analysis was done for vertical cylinder and CY100 models using the Rankine source method. Weber number of at least around 120 is necessary to eliminate the effect of surface tension from free surface flow around the CY100 model. The numerical analysis for the cylinder model needs simulation with wavelength shorter than that of free surface wave used by the Rankine source method. The model for the resistance test should be at least around 7m long to eliminate the effect of surface tension at Froude number of 0.1 or higher. 15 refs., 12 figs., 2 tabs.

  3. Studies on surface tension effect for free surface flow around floating models; Futai mokei mawari no jiyu hyomenryu ni oyobosu hyomen choryoku no eikyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, K. [Yokohama National Univ., Yokohama (Japan). Faculty of Engineering; Akiba, H. [Toyo Construction Co. Ltd., Tokyo (Japan)

    1996-12-31

    The effect of surface tension on free surface flow around floating models is discussed experimentally and numerically. Three-dimensional free surface flow around vertical circular cylinders floating in a circulating water channel was visually observed, where a surface-active agent was added to water. The results are analyzed using Weber number. The numerical analysis was done for vertical cylinder and CY100 models using the Rankine source method. Weber number of at least around 120 is necessary to eliminate the effect of surface tension from free surface flow around the CY100 model. The numerical analysis for the cylinder model needs simulation with wavelength shorter than that of free surface wave used by the Rankine source method. The model for the resistance test should be at least around 7m long to eliminate the effect of surface tension at Froude number of 0.1 or higher. 15 refs., 12 figs., 2 tabs.

  4. Investigation on comparative studies relative to the world oil market models used at Energy Modeling Forum (EMF). EMF ni okeru sekai sekiyu shijo model ni kansuru hikaku kenkyu ni tsuite no chosa

    Energy Technology Data Exchange (ETDEWEB)

    Lee, S. (The Institute of Energy Economics, Tokyo (Japan))

    1994-01-01

    The Energy Modeling Forum (EMF) has established a working group comprising researchers and policy operators delegated from the three sectors of the government, academic world, and private businesses. The working group has advanced comparative studies relative to the world oil market models during 1991 to 1992, and compiled the 'International Oil Supplies and Demands, EMF REPORT 11'. This paper introduces its summary. The group has selected 11 models from the existing oil market models, and given developers of these models with 12 kinds of common premises to perform scenario analyses. Some of the results of comparisons and analyses on the 11 times 12 kinds of simulation results may be quoted as follows: a common trend has been observed that the Middle East dependency will increase; overseas supply source dependency will increase rapidly in major energy consuming countries (the dependency in the U.S.A. will increase from 1/3 in 1988 to 2/3 in 2010); and estimations on demands and prices up to 2010 were diversified, clearly reflecting differences in viewpoints. 2 refs.

  5. Study of seismic data acquisition using physical modeling system; Butsuri model jikken sochi wo mochiita data shutoku gijutsu ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Tsukui, R.; Tsuru, T. [Japan National Oil Corp., Tokyo (Japan). Technology Research Center; Matsuoka, T [Japan Petroleum Exploration Corp., Tokyo (Japan)

    1996-10-01

    For the physical modeling system of Technology Research Center, Japan National Oil Corporation, data acquisition on the ocean and ground can be simulated using models. This system can provide data for verification of the data processing and elastic wave simulation algorithm. This can also provide data for decision of experiment specifications by making a model simulating the underground structure of the given test field. The model used for the physical modeling system is a gradient multilayer model with six-layer structure. Depth migration before stacking was conducted using data obtained through two acquisition methods, i.e., up-dip acquisition and down-dip acquisition. The depth migration before stacking was performed for data obtained by up-dip acquisition in addition to the records obtained by down-dip acquisition. Consequently, a definite reflection surface was observed, which has not been observed from the processing results of down-dip acquisition data. 9 figs.

  6. Study of seismic data acquisition using physical modeling system; Butsuri model jikken sochi wo mochiita data shutoku gijutsu ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Tsukui, R.; Tsuru, T. [Tech. Research Center, Japan National Oil Corp., Tokyo (Japan); Matsuoka, T. [Japan Petroleum Exploration Corp., Tokyo (Japan)

    1996-05-01

    The Physical Modeling System introduced into the Technology Research Center, Japan National Oil Corporation, and data collected by use of the system are presented. The Physical Modeling System is 10,000 times smaller than the real one, comprising a water tub section, measuring device section, and control section, etc. The water tub section comprises a tub for housing the model, transducers for transmitting and receiving vibration, controllers, etc. The water tub measures 1.8{times}1.2{times}0.9m. The model used in the experiment is an `inclined multilayer model` with each of its six layers pinching out toward the top, and is usable for the comparison of various migration methods. In one case in the records, reception was made at 184 reception points deployed at intervals of 3mm, when the minimum offset was 15mm and the maximum offset 564mm. Nothing very obvious was observed when the ordinary overlapping of DMO and CDP was applied to this record, which suggests that pre-overlapping migration treatment is required. 5 figs.

  7. Study on apatite compounds; Apataitokei kagobutsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-11-28

    To clarify the material properties of apatite compounds, the synthesis method, and the evaluation of physical properties of material and elementary technology were investigated. For the study on synthesis and crystal growth, a method of precipitating calcium phosphate on the surface of metal was investigated by means of relatively mild electrolytic method using liquid phase system. A new molding method of Ca defective apatite was established. Composite similar to vital bone was prepared by means of a new low-temperature sintering. For the study on chemical properties, from the model experiments, it was found that the self-organizing phenomenon, which is observed in the composite of apatite and collagen, happened between the organic single molecular film and crystal of apatite. For the study on evaluation of physical properties and elementary technology, the surface and interface of ceramics such as apatite were investigated by means of spectroscopy, the electronic state was analyzed by the quantum chemical calculation, and the crystalline structure was analyzed using X-ray equipment. 270 refs., 102 figs., 10 tabs.

  8. Shaking table test of a model bridge with sliding type base isolation system; Suberi hoshiki manshin system wo yusuru kyoryo no dotokusei ni kansuru jikkenteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Okamoto, S.; Fujii, S.; Ozaki, D. [Taisei Corp., Tokyo (Japan). Technology Research Center; Constantinou, M.; Tsopelas, P. [State Univ. of New York at Buffalo, New York, NY (United States)

    1995-01-21

    The vibration characteristics of a bridge with a sliding type isolation system composed of a sliding bearing and a rubber restoring force device are investigated experimentally. A quarter scale model bridge equipped with elastic piers is used for the model vibration test. It is confirmed that the acceleration created in the bridge beam is decreased satisfactorily by the use of a sliding type base isolation system wherein a rubber restoring force device, having functions of horizontal spring and bridge falling protection, and a sliding bearing, which utilizes the sliding phenomenon between a Teflon plate and a stainless steel sheet, are used in combination. It is confirmed that a very effective isolation effect can be obtained when bearing displacement is controlled within the range in which the reactive force of the rubber restoring force device does not increase rapidly. The residual displacement seems to be small enough and in the range of practical use unless a rubber device with low stiffness is used. It is confirmed that horizontal reactive force can be designed to be distributed optionally by varying the friction coefficient and the stiffness of the rubber restoring force device for each pier. 20 refs., 18 figs., 2 tabs.

  9. Model experiment on capsizing of damaged RO-RO passenger ship in beam seas; Sonsho shita RO-RO kyakusen no ohachu tenpuku ni kansuru mokei jikken

    Energy Technology Data Exchange (ETDEWEB)

    Haraguchi, T.; Ishida, S. [Ministry of Transportation, Tokyo (Japan)] Murashige, S. [Tokyo Univ. (Japan)

    1998-12-31

    In this study, a model of the RO-RO passenger ship was made, a capsizing experiment was carried out in a case of a damaged crack existed in higher wave height side in the beam seas. The main results were obtained as follows: the restored standard after damage was satisfied in the Treaty of Safety of Life at Sea (SOLAS`90) and the capsizing would not happen in the case of no initial heel. In the case with initial heel, ship would be heeled to the side of higher wave height with damage crack, capsizing would happen when the significant wave height was higher and the permeability to the car deck was larger. That is, it was necessary for residence water to easily stay in the damage side with the initial heel in order that the capsizing happened. In the case of the capsizing with an initial heel, the critical height of the residence water on the car deck was nearly in agreement with the British proposal: `calculation equations showing necessary restored performance in consideration of the permeation to the car deck`, when the peak period in wave spectrum was 7 to 9 seconds. There is no agreement when the peak period is longer than that. 11 refs., 15 figs., 4 tabs.

  10. Considerations on FEM modeling in analyzing buckling and plastic collapse of a detection control; Boto panel no zakutsu sosei hokai kaiseki ni okeru FEM model ka ni kansuru kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Yao, T.; Fujikubo, M.; Yanagihara, D.; Irisawa, M. [Hiroshima University, Hiroshima (Japan). Faculty of Engineering

    1997-10-01

    Buckling and plastic collapse of upper decks and bottom outer plates of a hull results directly in longitudinal bending collapse of the hull. Therefore, discussions were given on analysis for pressure destruction strength of a detection control panel which assumes an upper deck and a bottom outer plate. Pressure destruction behavior of the panting panel is a complex phenomenon accompanying non-linearity and geometrical non-linearity of the materials. Its whole phenomenon may be analyzed by using the finite element method (FEM) as a principle, but the analysis is not efficient. Therefore, considerations were given in relation to modeling when using the FEM. The considerations were given on a panel attached with flat steel panting members with respect to the modeling scope which considers the buckling mode according to the aspect ratio of the panel partitioned by the deflection control members. If the local buckling mode of the panel is an even number wave mode in the longitudinal direction, a triple span model is required. A modeling scope for a case of being subjected to water pressure and in-plane compression was considered on a panel attached with angle-type steel members having non-symmetric cross section. In this case, a triple bay model is more preferable to reproduce the behavior under water pressure loading. 1 ref., 6 figs.

  11. Calculation of oil production performance of the large giant oil fields in the world: based upon oil fields depletion model; Yuden gentai model ni yoru sekai no ogata kyodai yuden no seisan kyodo ni kansuru ichishisan

    Energy Technology Data Exchange (ETDEWEB)

    Nomoto, S. [Japan Oil Development Co. Ltd., Tokyo (Japan); Fujita, K. [The University of Tokyo, Tokyo (Japan)

    1997-05-01

    Data for large giant oil fields with minable reserves of one billion barrels or more were accumulated to structure a new oil field depletion model and estimate production in each oil field. As a result of analyzing events recognized in large giant oil fields, necessity was made clear to correct the conventional oil depletion model. The newly proposed model changes definitions on the depletion period of time, depletion rate, build-up production (during a time period in which production rate increases) and production in a plateau (a time period in which production becomes constant). Two hundred and twenty-five large giant oil fields were classified into those in a depletion period, an initial development phase, and a plateau period. The following findings were obtained as a result of trial calculations using the new model: under an assumption of demand growth rate of 1.5%, oil field groups in the initial development phase will reach the plateau production in the year 2002, and oil fields in the depletion period will continue production decline, hence the production amount after that year will slow down. Because the oil field groups in the plateau period will shift into decline in 2014, the overall production will decrease. The year 2014 is about ten years later than the estimation given recently by Campbell. Undiscovered resources are outside these discussions. 11 refs., 9 figs., 2 tabs.

  12. Fundamental study on stabilizing control method for electric power system using distributed circuit model; Bunpu teisu kairo moderu ni yoru denryoku keito doyo mogi to anteika seigyo ni kansuru kisoteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Hamada, A.; Kawasaki, K. [Shikoku Electric Power Co., Inc., Kagawa (Japan); Takigawa, K. [Shikoku Reserch Institute Inc., Kagawa (Japan); Ariyoshi, H. [Ehime University, Ehime (Japan)

    1997-06-20

    To grasp the electric power system disturbance, the detailed simulation model of the electric power system is applied, however, it is not so easy to grasp the disturbance characteristics of a large scale electric power system in the broader aspects. On the other hand, from a shut down test of generator and electric load in the electric power system, it is well known that the power disturbance is transmitted from the test point to the other points with constant delay time. The phenomena shows that the electric power system has a similar dynamic characteristic to the distributed constant circuit. In this paper, the electric power system is expressed with the distributed constant circuit so that the main disturbance characteristics are obtained without difficulty. Moreover, the possibility of suppressing the disturbance is discussed by employing active sink method, and distributed constant circuit model and lumped constant circuit model are compared with the viewpoint of eigenvalue and its propriety is showed. Further, as an example, active sink method, the effectiveness of distributed constant model in the suppressing control of electric power system disturbance, is showed. 7 refs., 12 figs., 1 tab.

  13. OAM system based on TMN for utility telecommunication network. Proposal of modeling method about managed objects; TMN ni motozuku denryoku tsushinmo no un`yo kanri system. Kanri object no sekkei shuho ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Hirozawa, T.; Yusa, H.; Otani, T. [Central Research Institute of Electric Power Industry, Tokyo (Japan); Okamura, K. [Tokyo Electric Power Co. Inc., Tokyo (Japan)

    1996-03-01

    To construct an advanced operation and management system for utility telecommunications management network (TMN), this paper proposes a modeling method of managed objects (MOs) required for managing and managed systems, such as an asynchronous transmission mode (ATM) exchanger. Flexible line setting and path switching control are required for the advanced TMN, which must cope with the extension and modification of functions, flexibly. Assignment of roles of managing sides and managed sides was determined. Then, structures of objects such as facilities and logic data, and their interaction were modeled. Common management functions and objects of each function were classified. Based on the TMN standard and MOs of the existing design peculiar to utility, new MOs peculiar to utility were defined in response to the models. The existing MOs can be effectively utilized, and the optimum MOs to be incorporated can be expected. The MOs peculiar to utility are added to the common specification of electric power industry. Since they can be reused for the extension and modification of functions, the cost can be reduced. The MOs applicable to path switching control of utility were designed as a trial. 9 refs., 16 figs., 10 tabs.

  14. Fiscal 1993 investigational study of a model of international cooperation for an environmentally harmony type green technosystem; 1993 nendo Oshu ni okeru haikibutsu shori oyobi recycle no doko ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    For the natural environment preservation, effective utilization of resources, and maintenance of the ecosystem, an international cooperation model was proposed for the environmental harmony type green technosystem. A comprehensive evaluating analysis of a green forest resource, etc. as the global resource, and an intensive extraction of subjects and needs was made. The analysis was conducted of technical possibility and abstract business development effects toward the industrialization with high values added which is in harmony with the environment. As a case study, the Papua New Guinea area, Malaysia was selected and re-evaluated. For this typical tropical forest area, a new technical system was studied based on the natural environment, industry/economy, social/cultural assessment, etc., and a model for industrializing new international cooperation was proposed. For the model making for industrialization, various steps to be taken and conditions to be prepared were studied and arranged for the realization. Upon going ahead with the international technical cooperation, Japan, a large lumber consuming country, needs to always consider the fostering and effective use of lumber resource in particular. 27 refs., 28 figs., 30 tabs.

  15. Model experiment of swirl effect in bottomless immersion nozzle on molten steel flow in slab CC mold; Slag CC igatanai ryudoni oyobosu sokonashi shinseki nozzle nai deno senkai ryudo koka ni kansuru mizu model jikken

    Energy Technology Data Exchange (ETDEWEB)

    Yokoya, S.; Takagi, S. [Nippon Institute of Technology, Saitama (Japan)

    2000-04-01

    The characteristics of molten steel jet flowing out from the Immersion nozzle in the continuous casting mold control the flow pattern in the mold thereby strongly influencing the quality and productivity of the cast steel slabs. We proposed a new method to establish a reasonable flow pattern in the mold by imparting a swirling motion to the flow in the immersion nozzle without the bottom. The following results were obtained from a water model study. (1) A quite stable swirling flow being established in the immersion nozzle without the bottom when the swirling velocity exceeded a critical value of 0.8 m/s, under this condition there existed no separation on the inner wall of the immersion nozzle. (2) When the swirling velocity was higher than 0.8 m/s, the fluid on the symmetry plane of the immersion nozzle moved along the curved inner wall of the nozzle. Accordingly, the outlet-flow was directed outwards as well as downwards, while a weak upward flow, i.e., inflow was observed around the vertical nozzle axis near the outlet of the nozzle. As a whole, the fluid flow near the guide plane of the nozzle was directed downwards. (3) The fluctuation of the surface flow, i.e., the flow on the meniscus of the mold was strongly suppressed due to the appearance of the S-shaped flow pattern in the transverse sections. As a result, swirl motions around the immersion nozzle were also suppressed. In addition, both the fluctuations of the mean velocity components and the turbulence components of the flow in the mold became very small, being preferable conditions for continuous casting. (author)

  16. Enhancement of condensation heat transfer using an electric field. 2nd Report. Model analysis on heat transfer enhancement using a bare wire electrode; Denba ni yoru gyoshuku netsu dentatsu no sokushin ni kansuru kenkyu. 2. Rasen denkyoku ni okeru dennetsu sokushin no model kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Chu, R. [Gifu University, Gifu (Japan). Faculty of Engineering; Nishio, S. [The University of Tokyo, Tokyo (Japan). Institute of Industrial Science; Tanasawa, I. [Nihon University, Tokyo (Japan). Faculty of Engineering

    2000-06-25

    A model experiment was conducted to investigate the dynamic behavior of a liquid sheet under an electric field applied parallel to the flow direction. It was confirmed that the liquid sheet was changed into columns when the applied voltage exceeded a certain critical value. Then a model analysis based on a linear stability theory was carried out to predict the critical applied voltage and it was shown that the analytical results were in good agreement with the measured values. Further, based on the above-mentioned model describing the dynamic behavior of the liquid sheet, an analytical model predicting the EHD effect on condensation heat transfer for a finned tube was presented. It was shown that the predicted results were in good agreement with the experimental data on the flooding angle and condensation heat transfer coefficient for a finned tube under electric fields. (author)

  17. Characteristics estimation of coal liquefaction residue; Sekitan ekika zansa seijo no suisan ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Itonaga, M.; Imada, K. [Nippon Steel Corp., Tokyo (Japan); Okada, Y.; Inokuchi, K. [Mitsui SRC Development Co. Ltd., Tokyo (Japan)

    1996-10-28

    The paper studied a possibility of estimating characteristics of coal liquefaction residue from liquefaction conditions in the case of fixing coal kind in the NEDOL process coal liquefaction PSU. Wyoming coal was used for the study, and the already proposed simplified liquefaction reaction models were used. Among material balances explained by the models, those of asphaltene, preasphaltene, THF insoluble matters are concerned with residue composition. Ash content is separately calculated from ash balance. Reaction velocity constants of simplified liquefaction reaction models which influence the residue composition were obtained by the multiple regression method from experimental results in the past. The estimation expression of residue viscosity was introduced from residue ash/composition. When the residue composition is estimated by the model from liquefaction conditions, and the residue viscosity is obtained using it, the higher the liquefaction temperature is, the higher the residue viscosity is. The result obtained well agreed the measuring result. The simplified liquefaction model of a certain coal kind has been established, and characteristics of residue can be estimated even at liquefaction conditions which have never been experienced before if there is a certain amount of the accumulated data on residue composition/characteristics. 4 refs., 4 figs., 4 tabs.

  18. Experimental study on the control interaction force coefficient; Soju ryutairyoku kansho keisu ni kansuru jikkenteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Nakatake, K.; Oda, K.; Yoshitake, A.; Fujita, K.; Nakajima, A. [Kyushu University, Fukuoka (Japan). Faculty of Engineering

    1996-04-10

    The interaction force induced to hull by steering is important for prediction of control performance of ships. The control interaction force coefficient dependent on the steering has been investigated through the rudder angle tests using three small model ships with a length of 2.5 m, i.e., mathematical type of ship, cargo type of ship, and tanker type of ship. The interaction forces acting on the hull, propeller, and rudder were determined by measuring the lateral force as well as the forward force of the hydrodynamic forces acting on the rudder. These forces were compared with the theoretically calculated values. Prior to the rudder angle tests, the self propulsion factor and the number of revolution of propeller were determined from the results of the open water tests, resistance tests, and self propulsion tests by the changing load method. The rudder angle tests were conducted under this number of revolution of propeller as a standard condition, and under those increasing and decreasing by 15%. Consequently, the interaction forces determined from the rudder angle tests agreed well with those determined from the other tests. When comparing the control hydrodynamic forces determined from the tests with those theoretically calculated, a similar trend was observed. Effectiveness of the theoretical model was confirmed. 4 refs., 14 figs., 3 tabs.

  19. Consideration on corrosion fatigue crack life assessment; Fushoku hiro kiretsu hassei jumyo hyoka ni kansuru ichikosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Yajima, H.; Yamamoto, M.; Saito, T. [Hiroshima University, Hiroshima (Japan). Faculty of Engineering; Morita, K. [Mitsubishi Heavy Industries, Ltd., Tokyo (Japan)

    1996-10-01

    Discussions were given on corrosion fatigue crack life by using corrosion fatigue crack initiation test and analysis. The test used 13Cr-based stainless steel as a test material, and aquamarine at 60{degree}C as a corrosion environment. The fatigue test was performed under a tension loading condition with a stress ratio of 0.1 and an iterative velocity of 1.7 Hz by using a 10-tonf fatigue testing machine. In the corrosion fatigue crack initiation test, a pit has been generated on a boundary of an exposed part and a painted part for masking, hence direct observation was impossible on pit growth behavior. Therefore, an intrinsic crack model was introduced from pit dimensions as observed from a fracture face, and analysis was made on corrosion fatigue crack growth by using the linear fracture dynamics, wherein clarification was made on a phenomenon occurring after the crack growth passes the pit growth until the test piece is fractured. A proposal was made to define the time when fatigue crack initiates and grows from the bottom of a pit as a result of surpassing the growth of corrosion pit as the corrosion fatigue crack life. 4 refs., 7 figs., 1 tab.

  20. Survey on the FRP waste recycling system; FRP haikibutsu recycle system ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Using the area around the Ariake Sea in Kyushu as a model case, the FRP (fiber reinforced plastics) waste recycling system which can be established in Japan has been investigated in cooperation with local government bodies and fishery organizations. As a result, some proposals are provided. The recovery of waste boats utilizing existing sales outlets for fishing boats will facilitate efficient transport, efficient removal of vessel fixtures, and information management and user guidance via existing sales routes. This should make it possible to systematically secure and dispose a certain volume of scrapped FRP boats, and thus generate savings in the disposal costs. In the Phase 1, the main focus will be on establishing the recovery system for scrapped FRP boats to promote reuse and prevent improper disposal. In the Phase 2, the economics will be improved by expanding the recovery system to include other FRP waste products. In the Phase 3, the number of recyclable items will be increased, and thus the recycling system will be completed. 3 refs., 11 figs., 7 tabs.

  1. Study on behavior of car and driver in the very small commuter car made of FRP during collision using scale model. Under the consideration of thorax deformation of driver using airbag; FRP sei mokei ni yoru FRP sei chokeiryo jissha shototsuji no kuruma to join no anzensei ni kansuru kenkyu. Kyobu henkei tokusei wo yusuru join ni taisuru air gab no koka

    Energy Technology Data Exchange (ETDEWEB)

    Sakai, H.; Morisawa, M.; Yoshino, T. [Musashi Institute of Technology, Tokyo (Japan); Sato, T. [Keio University, Tokyo (Japan); Ishizuki, H. [Satake Co., Tokyo (Japan)

    1997-10-01

    In this study, after having performed simulation which took up scale models substituting for full scale model of commuter car made of FRP, we carried out collision tests to barrier. Here, we made enquiries about the occupant safety by changing the collision speed and the deformation characteristics of the seat belt, during head-on barrier collision using one-fifth scale models. We sought for the occupant`s safe combinations among the deformation characteristics of airbag and the thorax deformation. In this case, the degree of the occupants injury were estimated using HIC values, 3msecG and maximum deformation of the thorax. 7 refs., 5 figs.

  2. Estimation of course stability at initial design stage; Shoki sekkeiji ni okeru shinro anteisei no suitei ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Yukawa, K. [Ministry of Transportation, Tokyo (Japan)] Kijima, K. [Kyushu Univ., Fukuoka (Japan)

    1998-12-31

    The theoretical prediction method for the hydrodynamic forces acting on the ship hull in maneuvering motion in consideration of effect of frame line configuration is proposed, selecting six types of model ships as the calculation objects. The prediction results show that the hydrodynamic forces can be predicted with reasonable accuracy in the ordinary maneuvering motion range, though the large drift angle and high dimensionless rotation angular speed give some errors. Using the linear differential coefficient obtained from the prediction of hydrodynamic force acting on ship hull, the decrease in the course instability is investigated. It is found that the method is able to be used for predicting the course stability of ships with relatively good accuracy. This method will be useful to decrease the course instability due to the difference in change in local shape of ships. Study will be continued on estimation calculation of hydrodynamic force on ship hull having various kinds of types. 13 refs., 15 figs., 2 tabs.

  3. Theoretical study on instability mechanism of jet-induced sloshing. Model development using Orr-Sommerfeld equation generalized for non-parallel flow; Funryu reiki sloshing gensho no hassei kiko ni kansuru rironteki kenkyu. Hiheiko nagare ni ippankashita Orr-Sommerfeld hoteishiki wo mochiita model ka

    Energy Technology Data Exchange (ETDEWEB)

    Eguchi, Y. [Central Research Institute of Electric Power Industry, Tokyo (Japan)

    1998-07-25

    A theoretical model was developed to study the mechanism of free surface sloshing in a vessel induced by a steady vertical jet flow. In the model, jet deflection is calculated with eigen values of the generalized Orr-Sommerfeld equation which is applicable to slightly non-parallel jet. Instability criteria employed in the model are (1) resonace condition between sloshing and jet frequencies and (2) {pi} phase relation between jet displacement at an inlet and global jet deflection. Numerical results of the mathematical model have shown good agreement with experimental ones, which justifies that the inherent instability of free jet itself and edge tone feedback are the main causes of the self-excited sloshing. 9 refs., 10 figs.

  4. Experimental model for architectural systematization and its basic thermal performance. Part 1. Research on architectural systematization of energy conversion devices; Kenchiku system ka model no gaiyo to kihon seino ni tsuite. 1. Energy henkan no kenchiku system ka ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Sunaga, N.; Ito, N.; Kimura, G.; Fukao, S.; Shimizu, T.; Tsunoda, M.; Muro, K. [Tokyo Metropolitan University, Tokyo (Japan)

    1996-10-27

    The outline of a model for architectural systematization of natural energy conversion and the experiment result on the basic thermal performance in winter are described. The model is about 20 m{sup 2} in floor space. Foam polystyrene of 100 mm and 200 mm thick was used for the outer wall as heat insulating materials. The model has a solar battery and air conditioner and uses red brick as a heat reservoir. An experiment was made on seven modes obtained when three elements (heating, heat storage, and night insulated door) are combined. The information obtained by the experiment showed that a model for architectural systematization has high heat insulation and tightness and can be used as an energy element or an evaluation model for architectural systematization. In this model for architectural systematization, the power consumption of an air conditioner in winter can be fully supplied by only the power generation based on a solar battery. In an architectural element, the heating energy consumption can be remarkably reduced and the indoor thermal environment can be greatly improved, by the combination of a heat reservoir and night heat insulated door. 1 ref., 6 figs., 3 tabs.

  5. Study of thermal threshold and counter-measures for human body in oceanic working environment. 1st Report. Heat balance model and heat storage index; Shonetsu kankyoka no kaiyo sagyo ni okeru netsuteki genkai to onnetsu taisaku ni kansuru kenkyu. 1. Netsu shushi model to onnetsu shisu

    Energy Technology Data Exchange (ETDEWEB)

    Fukuchi, N. [Kyushu University, Fukuoka (Japan). Faculty of Engineering; Nakamura, M. [Tokyo Gakugei University, Tokyo (Japan); Murayama, M.

    1996-12-31

    Identification was intended on effects of such thermal factors as metabolic amount, environmental temperature and humidity, and clothing resistance on human body temperatures during works under hot environments. Therefore, measurements were carried out on human skin temperatures, rectum temperatures and humidity inside clothing, while amount of motion, environmental temperature, and clothing are changed in a constant temperature room and under a sun irradiation environment. Furthermore, a heat balance model was prepared, which divides the objects into an outer shell layer whose temperature changes depending on the result of this experiment and into a core having constant temperature characteristics. An equation to derive skin temperatures was introduced from the model. The equation formulated a calculation formula for heat accumulation in human body, which can be used as a hot heat index. Relationship between thermal factors and heat storage amount was investigated to consider a thermal limit for a physical work. An equation to derive skin temperatures was confirmed capable of expressing general change in skin temperatures, being proved by comparison with experiments. Calculation formulas for amount of heat stored in human body were shown capable of expressing influence of different thermal factors, the expression being useful as a hot heat index. Calculating the human body heat storage is very largely affected by effect of sweat to dissipate heat, hence it is necessary to improve the accuracy including that for body temperature adjusting reactions. 17 refs., 17 figs., 5 tabs.

  6. Investigation into introduction and promotion of clean energy cars; Clean energy jidosha no donyu sokushin ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Gazing the introduction target for fiscal 2000 and 2010, the paper arranged comprehensively and systematically the trend in Japan and overseas of clean energy cars and described subjects. Themes of the study to be promoted in terms of electric cars are: Li secondary batteries, heightening of performance of batteries such as Ni-hydrogen, power generation/power storage hybridization to make the long-distance travel possible. For the price reduction, the body is so made as to make it possible to select three kinds of power unit, that is, gasoline, hybrid, and electricity. Low noise and easy operation are also important. As to natural gas vehicles, the price is more than three times as high as that of gasoline vehicles, and relaxation of the related regulations on metal tanks, the Road Traffic Act, etc. is necessary. It is indispensable to establish quantity production and technical standards and reduce cost by the remodeling for bi-fueling with gasoline engines, development of FRP tanks, etc. Methanol vehicles are the closest to gasoline vehicles, but the introduction is delayed having no groups for generalization. Solar and hydrogen cars are promising, but are on a stage of developing the basic technology. 43 figs., 104 tabs.

  7. Study of highly efficient power generation system based on chemical-looping combustion; Chemical loop nenshoho ni yoru kokoritsu hatsuden system no kaihatsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Ishida, S.; Suzuki, T.; Yamamoto, M. [Tokyo Institute of Technology, Tokyo (Japan). Research Laboratory of Resources Utilization

    1997-02-01

    This paper describes the research and development of power generation system by means of chemical-looping combustion. For this system, fuel flows in a reduction reactor and air flows in an oxidation reactor. These two flows are separated. As a result, recovery of CO2 without energy consumption, drastic improvement of power generation efficiency, and suppression of NOx emission are expected. To realize the above, two promising candidates, NiCoO2/YSZ and NiO2/NiAl2O4, have been found as recycle solid particles between the both reactors. These have excellent oxidation/reduction cycle characteristics. By these particles as well as the existing particle, NiO/YSZ, practical application of the chemical-looping combustion is realized. Besides LNG, coal and hydrogen were considered as fuels. When using coal or hydrogen, it was found that temperature of the reduction reactor should be increased the same as that of the oxidation reactor. This is a different point from a case using LNG as a fuel. 5 refs., 2 figs.

  8. Study on identification of inertial properties for mechanical system; Kikai kozobutsu no kansei tokusei doteiho ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, M.; Sawanobori, T.; Kogure, M.; Nishio, S. [Yamanashi University, Yamanashi (Japan); Nagamatsu, A. [Tokyo Institute of Technology, Tokyo (Japan)

    1995-04-20

    It is necessary to recognize inertial properties accurately for modeling during machine development and design. A pendulum method is generally available as the conventional technique that recognizes the inertial properties. This method is difficult to be applied to an intricately shaped matter or heavy matter. Therefore, a characteristic matrix identification method that is very excellent in principle has been proposed, and many studies have been made for practical use. However, the influence that the measurement error of a transfer function used for identification exerts is open to investigation. This paper examined the technique that obtains the inertial characteristics of an elastic-supported mechanical structure using the characteristic matrix identification method. The influence that the measurement point position of the transfer function exerts on an identification error was also investigated. The result showed that the measurement point should be away from the node of the rotation mode as far as possible. This technique was applied to the engine system of a motorcar, and the identification result in a practical level was obtained using a transfer function gotten from the excitation experiment by a hammer. 6 refs., 8 figs., 1 tab.

  9. Numerical simulation on streaming potentials in a wellbore; Koseinai no ryudo den`i ni kansuru suchi simulation

    Energy Technology Data Exchange (ETDEWEB)

    Ikeda, N. [Kyushu University, Fukuoka (Japan)

    1996-05-01

    This paper reports numerical computation of streaming potentials which are generated by transient pressure waves propagating the vicinity of wellbore wall immediately after a mud cake formed on the wellbore wall has been removed. One existing analysis solution on heat conduction was utilized upon changing the parameters in order to derive fluid pressure inside the ground bed. Calculations were carried out by using the existing three-dimensional finite difference method (partly re-written) based on the relationship constituted between the fluid pressure and the streaming potential. This paper presents results of calculating the streaming potentials in wellbores on models having wellbores filled with mud water in a cubic ground bed existing with ground bed water at saturation of 100%. The calculations have been conducted on the following cases: a case where permeability of the ground bed is small with the fluid under two conditions of low electric resistivity and high electric resistivity, a case where the permeability is large with the fluid under the above conditions, and a case where a small area of bore wall is covered with a rubber pad having high electric resistivity under a low electric resistivity condition. 8 refs., 5 figs.

  10. Study on torsion arc blade type horizontal axis wind turbine; Nejire enko yokugata suihei jiku fusha ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Kojima, N.; Kishimura, K. [Meiji University, Tokyo (Japan)

    1996-10-27

    Discussing the rotor blades of the torsion arc blade type (TABT) wind turbine, difference in windmilling characteristics was determined between elliptic blades and rectangular blades by theoretical analysis and model experiment. Experimental generation of power was carried out using a test wind turbine in the natural wind. First, elliptic blades were bent into arcs and fixed to shaft. The action force was determined calculating the blade area and the wind velocity vertical thereto. Furthermore, the force in the direction to turn the rotor was determined with the effect of the part behind the blade taken into account. The rotation-curbing air resistance in the flank direction that a rotor experiences was subtracted to determine the torque generated. A formula was derived for the elliptic blade. Second, a formula was derived in the same way for the case of rectangular blades. In conclusion, in the case of 6-blade wind turbine, the rate of responsibility for wind turbine rotation of the part behind the blade was approximately 50% of the part in front of the blade. Shape coefficients were introduced into the theory, which resulted in values agreeing well with values obtained from experiments. Elliptic blades yielded more power than rectangular blades at the same wind velocity. High in durability, the TABT wind turbine is expected to be put into practical use as a compact auxiliary power generating device. 2 refs., 14 figs.

  11. On the relationship between stacking process and resolution. 2; Jugo shori to bunkaino ni kansuru kiso kenkyu. 2

    Energy Technology Data Exchange (ETDEWEB)

    Matsushima, J.; Rokugawa, S.; Kato, Y. [The University of Tokyo, Tokyo (Japan). Faculty of Engineering; Yokota, T.; Miyazaki, M. [Geological Survey of Japan, Tsukuba (Japan)

    1997-05-27

    With respect to concept of resolution in seismic exploration using the reflection method, detailed considerations were given on processes of forming the resolution as a result of arranging observation points at vibration transmitting and receiving points. In the discussion, numerical experiments were carried out, in which the scattering stacking process is applied in a model having one scatterer existing in homogeneous media. The experiments investigated an imaging formation process of the scatterer when arrangement of the vibration transmitting and receiving points were changed from a coarse condition to a dense condition while the number of transmitting and receiving points is being increased. Resolution is created if waveforms having finite frequencies are used as input, and the imaging is performed by utilizing the limited number of vibration receiving and transmitting points. If the concept of equi-travel plane is used under these conditions, the equi-travel planes perform negation with each other, and it was indicated that visual resolution is expressed by how good the negating effect is. It was discovered that such concept of the resolution is quite ambiguous in terms of engineerings. 2 refs., 17 figs.

  12. Study on estimating fluid force acting on a hull during maneuvering movement; Soju undoji no sentai ni sayosuru ryutairyoku no suitei ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Yukawa, K.; Kijima, K. [Kyushu University, Fukuoka (Japan). Faculty of Engineering

    1997-10-01

    With types of general cargo vessel and VLCC vessel as the object of discussion, a method was discussed to estimate fluid force acting theoretically on a hull during maneuvering movement, taking frame line shape into consideration. A vortex model was improved by giving consideration of time-based decay on intensity of discrete vortex lines based on the Rankine vortex. Modeling of flow fields around a hull was attempted to deal with movements in which width and draft are small as compared with the ship length, and turning angle speed and deviation angle are small. It was assumed that the ship speed is slow and effects of waves can be disregarded. Specular images of the hull were taken with regard to free surface, and handled as a double body model. Speed potential to express flow fields around a hull is required to satisfy the following five boundary conditions of Laplace, substance surface, free vortex layers, infinity and exfoliation. The potential may be handled as a two-dimensional problem in a field near the hull by using assumption of a slender and long body and conformal mapping. It was found possible to estimate hull fluid force with relatively good accuracy. Fine linear coefficients derived from the estimation were used to have performed highly accurate determination on course stabilization. 5 refs., 6 figs., 2 tabs.

  13. Survey on weather changes associated with large-scale tree-planting. 2; Daikibo ryokuka ni tomonau kiko henka ni kansuru chosa. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    An investigational study was made for large-scale tree-planting aiming at CO2 fixation. Water resource and precipitation relating to tree-planting were determined from NASA data and arranged into the global distribution map. It was found that Australia and the Chinese continent are under the relatively favorable condition. As for the soil condition, nutrition resource is short in the desert and unused zone. From the vegetation data obtained from meteorological satellite NOAA, developed was a method for estimating net primary productivity of terrestrial ecosystem and obtained was a global distribution map for the amount of CO2 fixed under the present terrestrial vegetation. At the same time, areas which have great potentiality of tree-planting were selected from the map for estimating potentiality of the global tree-planting. To study the promotion of rainfall as a means of expanding the potential tree-planting area, the conventional meteorological and physical model was improved, and more realistic simulation was made possible. Also as to the water utilization technology, the modeling method was developed. As the area having a potentiality of expanding tree-planting, Australia (especially the west) was cited as the first candidate, and China the second candidate. 108 refs., 128 figs., 49 tabs.

  14. Few remarks on some factors in maintaining temperature of basement; Chikashitsu no hoonsei ni oyobosu shoyoin ni kansuru nisan no chiken

    Energy Technology Data Exchange (ETDEWEB)

    Inada, Y. [Ehime University, Ehime (Japan). Faculty of Engineering; Shimasaki, O. [Ehime University, Ehime (Japan); Ueda, T. [Takenaka Corp., Osaka (Japan); Matsumoto, T. [Nissan Construction Co. Ltd., Tokyo (Japan); Sugi, G.

    1998-06-21

    Noticing on temperature maintaining effect of a basement, three types of full scale model basements were used to measure temperature change in the surrounding ground and rooms in the basement and discuss effects of ground temperature variation on the basement. Thermal property values were derived on the surrounding ground affecting the temperature maintainability of the basement, and temperature analysis was performed on a model assuming the basement to discuss effects of difference in size occupying under the ground on change in room temperatures. Then, assuming a case of using heat insulating materials in the basement, discussions were given on the consumed energy required for air conditioning. Underground temperature has its change to decrease as the ground depth increases throughout a year, and particularly at depths greater than 50 cm, no daily temperature change can be seen. Because of this effect, the greater the underground occupying size in the basement, the smaller the temperature change. Distributions of heat diffusion rate, heat capacity, and heat conductivity can be estimated by deriving water content ratio distribution. When air conditioning is carried out in the basement, applying the heat insulating materials on the inner side of a room is more effective. Energy conservation may be expected because the room temperature is stabilized. 9 refs., 27 figs., 4 tabs.

  15. Investigational study of the CO2 balance in high temperature CO2 separation technology; Nisanka tanso koon bunri gijutsu ni okeru CO2 balance ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    An investigational study was conducted to clarify the adaptable environment and effectivity of technologies of high temperature separation/recovery/reutilization of CO2. In the study, data collection, arrangement and comparison were made of various separation technologies such as the membrane method, absorption method, adsorption method, and cryogenic separation method. With the LNG-fired power generation as an example, the adaptable environment and effectivity were made clear by making models by a process simulator, ASPEN PLUS. Moreover, using this simulator, effects of replacing the conventional steam reforming of hydrocarbon with the CO2 reforming were made clear with the methanol synthesis as an example. As to the rock fixation treatment of high temperature CO2, collection/arrangement were made of the data on the fixation treatment of the CO2 separated at high temperature into basic rocks such as peridotite and serpentinite in order to clarify the adaptable environment and effectivity of the treatment. Besides, a potentiality of the fixation to concrete waste was made clear. 57 refs., 57 figs., 93 tabs.

  16. Experimental study on the estimation method of hydrodynamic force acting on floating offshore structures; Futaishiki kaiyo kozobutsu ni kuwawaru ryutairyoku no suiteiho ni kansuru jikkenteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Hoshino, K.; Kato, S. [Ship Research Inst., Tokyo (Japan); Koterayama, W. [Kyushu Univ., Fukuoka (Japan). Research Inst. for Applied Mechanics

    1996-04-10

    In the design of various floating offshore structures (FOS), the functionality, safety and amenity of FOSs were examined by estimating responses of FOSs to environmental external forces such as wave, wind and flow. In this paper, the estimation method of drag acting on the whole FOS was established by combining previous study results on hydrodynamic force acting on various bodies such as Reynolds number effect (RNE), 3-D effect (TDE) and interference effect (IE). This hydrodynamic force was also compared with that obtained from the experiment result on a FOS model for TLP to confirm the applicability of this estimation method. The estimation result on the drag coefficient in steady flow by considering RNE, TDE and IE well agreed with experimental one. The drag coefficient acting on FOSs in heaving could be estimated in practically sufficient accuracy by considering drag acting on not columns but only square columns. The estimation result on the drag coefficient acting on FOSs in surging by considering RNE, TDE and IE well agreed with experimental one. 12 refs., 10 figs., 1 tab.

  17. Thermal modeling of NiH2 batteries

    Science.gov (United States)

    Ponthus, Agnes-Marie; Alexandre, Alain

    1994-01-01

    The following are discussed: NiH2 battery mission and environment; NiH2 cell heat dissipation; Nodal software; model development general philosophy; NiH2 battery model development; and NiH2 experimental developments.

  18. Survey of implementation plan constructed for `the New Earth 21 Project`; Chikyu saisei keikaku no jisshi keikaku sakusei ni kansuru chosa jigyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    It is necessary to establish scenarios for reducing CO2 emissions and for developing CO2 emission control technologies to obtain a global consensus, using appropriate analytical models. For modification of the DNE-21 (Dynamic New Earth 21) model, it has a category designated as innovative technologies not involving CO2 emission and an optional consideration for the absorption of atmospheric CO2 by biomass. A global carbon circulation model, including vegetation in its scope, is also incorporated. Major results of the simulation are shown. When 20% reduction in CO2 emissions is required for only OECD countries after the year 2020, it has been demonstrated that CO2 concentration in the atmosphere will reach as high as about 900 ppm in 2100 due to CO2 emission by developing countries, and will not be a tolerable level. Under the condition that CO2 concentration in the atmosphere is controlled at 450 ppm in 2100, the amount of renewable source of energy from photovoltaic power generation and biomass will increase and technologies of CO2 recovery and storage will decrease. Research and development of the production of methanol from recovered CO2 will be adopted as innovative technology for CO2 measures. 69 refs., 112 figs., 79 tabs.

  19. Research on elaboration of the action plan for the New Earth 21; `Chikyu saisei keikaku` no jisshi keikaku sakusei ni kansuru chosa jigyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Elaboration of the action plan for the New Earth 21 plan proposed by Japan in Houston Summit was researched. In fiscal 1995 three types of energy supply/demand scenarios, sensitivity analysis under various conditions, and cases presupposing CO2 emission regulations or not were evaluated by analysis toward 2050 using the New Earth 21 Model (NE 21 Model). Energy-saving is important, and CO2 recovery/treatment technology is introduced according to CO2 emission regulations, while attention is focussed on biomass energy. The issue of solar and wind power generation is cost reduction. In a presupposed horizontally integrated energy system, methanol represents an important intermediate energy. As a whole, CO2 reduction can be achieved by various combinations of energy-saving, introduction of regenerative energy, and CO2 recovery/treatment technology. Case studies of the action plan were conducted by unifying the evaluation criterion on coal IGCC, photovoltaic generation and biomass. The NE 21 Model was useful for elaboration of the reduction scenarios of CO2 emission. 26 refs., 84 figs., 28 tabs.

  20. Development of knowledge based operation system for making product matching with requirement by human sense; Kansei tekigo seihinseizo wo mezashita chiteki opereshon shisumtemu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Honda, Hiroyuki [Nagoya University, Aichi (Japan). Dept. of Biotechnology

    1999-12-16

    Knowledge based operation system was developed in order to apply the human sense to process operation. Since beverages such as coffee, beer and sake, are seriously evaluated by human sense, those sensory evaluations or data on those chemical composition were subjected to this research. Fuzzy neural network (FNN) ro its hierarchical structure (HFNN) was superior tool for modeling of human sense. With respect to the determination of the chemical composition from desired sensory evaluation, an innovative tool, CF-GA, was newly developed. Using these tools, construction of knowledge based operation system for making the product matching with requirement by human sense became promising. (author)

  1. Experimental study on the response of very large floating structures (VLFS) in wave; Choogata futaishiki kaiyo kozobutsu no harochu oto ni kansuru jikkenteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Ota, M.; Ikegami, H.; Yamaguchi, Y. [Mitsubishi Heavy Industries, Ltd., Tokyo (Japan)

    1997-10-01

    The elastic response of VLFS of 1200m long in wave was studied experimentally using a water tank and integral elastic model of 1/80 scale. As offshore airport, a ultra- thin box type floating structure of 5km long, 1km wide and several meter thick is used, and the effect of elasticity is not negligible for such a structure. The experiment used a water tank of 160m long, 30m wide and 3.1m deep. Supposing a water depth of 20m for real VLFSs, the experiment was carried out mainly in a local shallow water area prepared with a temporary bottom together with that in a deep water area. A simple mooring equipment with a linear spring equivalent to real VLFSs was used. The integral floating model was prepared by not mechanical but welded junction to obtain uniform elasticity. The response in wave showed a complicated 3-D behavior, offering useful data for verification of a behavior estimation method. The response was nearly equal between shallow and deep water areas at the same wave length, and the response amplitude in regular waves was equivalent to the significant amplitude in long and short crested irregular waves. 7 refs., 8 figs., 3 tabs.

  2. Research on digital pneumatic cylinder systems. ; Case with an inertial load. Digital kukiatsu cylinder system ni kansuru kenkyu. ; Kansei fuka no baai

    Energy Technology Data Exchange (ETDEWEB)

    Jia, Z. (Tokyo Institute of Technology, Tokyo (Japan)); Katakura, H.; Yamane, R. (Tokyo Institute of Technology, Tokyo (Japan). Faculty of Engineering)

    1991-09-15

    In order to enhance the accuracy in positioning using a pneumatic system, experiments and simulations by a model pneumatic system were carried out. In this research, the experiments on position control under the condition of an inertial load were conducted by means of a model system, in which four cylinders with strokes of 1 cm, 2 cm, 4 cm, and 8 cm were connected to each other and the actions of the cylinders were controlled by a microcomputer. The basic equations in consideration for collisions of the moving bodies were deduced and simulations were conducted. From the research, the following conclusions were obtained. For the digital positioning of the pneumatic system under the condition of inertial load, the vibrations of the moving bodies caused by collisions can be controlled by means of the breaking control. The positioning paths as the outputs of the systems can be made smooth by means of the timing control including the breaking control. With consideration given to the collisions, the positioning can be simulated numerically under an inertial load. 4 refs., 10 figs., 2 tab.

  3. Analysis of coordination between the pohotovoltaic power generation and heat storage type air conditioning; Taiyoko hatsuden to chikunetsugata kucho no kyocho ni kansuru bunseki

    Energy Technology Data Exchange (ETDEWEB)

    Kita, H.; Sudo, T. [Kyoto University, Kyoto (Japan)

    1997-01-30

    This paper describes the effects of coordination between the photovoltaic power generation and heat storage type air conditioning. In this study, a linear programming model was analyzed in four cases of spread rates of photovoltaic power generation and heat storage tanks by selecting four setting angles of photovoltaic cell panels and six models of irregular variation, to determine the optimum demand and supply. As a result of the simulation, coordination effects were found independent of the cases. It was verified that the coordination effects can be obtained independent of the cases. For the capacity of heat storage tank, the influence of irregular variation of photovoltaic power generation was equivalent to about 10% of the capacity. The difference in the power generation costs between in the daytime and at night, and the construction costs of heat storage tank and air conditioner were considered as factors determining the capacity of heat storage tank. For the setting angle of photovoltaic cell panels, it was found that the intermediate setting was effective between the setting focusing on the peak power and the setting maximizing the annual power output. 4 refs., 7 figs., 3 tabs.

  4. Study on the estimation method of maneuvering hydrodynamic force in turning motion; Senkai undoji no soju ryutairyoku suiteiho ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Kijima, K.; Yukawa, K. [Kyushu University, Fukuoka (Japan). Faculty of Engineering; Maekawa, K. [Hokkaido University, Sapporo (Japan). Faculty of Fisheries

    1996-04-10

    Estimation of the maneuvering performance of ships is very important from the viewpoint of safe navigation. Using three types of VLCCs (SR221A, B, C) with locally different stern frame lines as computational models, the estimation method of hull hydrodynamic force in turning motion was studied theoretically taking frame line shapes into account. The unstable behavior of courses was also studied using linear differential coefficients obtained from the estimation result on hull hydrodynamic force in oblique navigation and turning motion. As a result, the estimation result on hull hydrodynamic force was slightly different quantitatively from model test results in a range of large drift angle or turning angular velocity, while that was relatively well agreed with test results in a range of small such angle and velocity. As the study result on the unstable behavior of courses by using linear differential coefficients obtained from the estimation result on hull hydrodynamic force, determination of a course stability was possible by considering local difference in hull shape. 4 refs., 8 figs., 1 tab.

  5. Analysis of coordination between the pohotovoltaic power generation and heat storage type air conditioning; Taiyoko hatsuden to chikunetsugata kucho no kyocho ni kansuru bunseki

    Energy Technology Data Exchange (ETDEWEB)

    Kita, H.; Sudo, T. [Kyoto University, Kyoto (Japan)

    1997-01-30

    This paper describes the effects of coordination between the photovoltaic power generation and heat storage type air conditioning. In this study, a linear programming model was analyzed in four cases of spread rates of photovoltaic power generation and heat storage tanks by selecting four setting angles of photovoltaic cell panels and six models of irregular variation, to determine the optimum demand and supply. As a result of the simulation, coordination effects were found independent of the cases. It was verified that the coordination effects can be obtained independent of the cases. For the capacity of heat storage tank, the influence of irregular variation of photovoltaic power generation was equivalent to about 10% of the capacity. The difference in the power generation costs between in the daytime and at night, and the construction costs of heat storage tank and air conditioner were considered as factors determining the capacity of heat storage tank. For the setting angle of photovoltaic cell panels, it was found that the intermediate setting was effective between the setting focusing on the peak power and the setting maximizing the annual power output. 4 refs., 7 figs., 3 tabs.

  6. Experimental studies for the power augmentation system of the vertical-axis wind turbine. Suichokujiku koryokugata fusha no shutsuryoku zokyoho ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Ushiyama, I.; Suda, N.; Takano, Y. (Ashikaga Institute of Technology, Tochigi (Japan)); Kakita, Y. (Yazaki Corp., Tokyo (Japan))

    1993-12-09

    Wind tunnel experiments have been carried out to discuss output increasing effect of mounting diffusers and concentrators onto vertical-axis wind turbines of Savonius type and cross flow type. The following findings were obtained as a result: a wind turbine rotor installed at the diffuser inlet in the wind turbines of both models reduced the output lower than that for the wind turbine alone; a wind turbine rotor installed at the diffuser path expanding part increased the output higher than that for the wind turbine alone; installing a concentrator results in output increasing effect; installing both of the concentrator and the diffuser has the appearance of the output increasing effect regardless of installing locations of the wind turbine; however, the maximum power coefficient increases if they are installed in the diffuser path expanding part in the case of the Savonius type wind turbine, and in the diffuser inlet in the case of the cross flow type wind turbine. 3 refs., 8 figs.

  7. International symposium on environmental impacts of advanced alternative to CFC; CFC shinki daitai busshitsu no kankyo eikyo ni kansuru kokusai symposium hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-07

    The international symposium on environmental effects of new CFC substitutes was held in Tsukuba City, Ibaraki Pref. on February 7-9, 1996, and 19 papers were made public. In Session 1 (Plenary lecture), reports were made on Global warming and climate change: a review of recent studies; Stratospheric ozone, CFCs, and CFC-substitutes: an update, etc. In Session 2, Measurements of OH rate constants for advanced refrigerants as well as HCFCs and HFCs; The reaction rate of CFC alternatives with OH radical; Experimental and estimated rate constants: reactions of hydroxyl radicals with several halocarbons, etc. In Session 3, Measurement of uptake coefficients of some acetyl halides and fluorinated ethers into water; Mass transfer at the air/water interface: removal processes of halocarbonyl compounds; Heterogeneous reactions of fluorinated ethers on allophane or titanium dioxide, etc. In Session 4, papers were reported on model calculations relating to the global warming.

  8. Survey on the technological development issues for large-scale methanol engine power generation plant; Ogata methanol engine hatsuden plant ni kansuru gijutsu kaihatsu kadai chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    Based on the result of `Survey on the feasibility of large-scale methanol engine power generation plant` in fiscal 1992, concrete technological development issues were studied for its practical use, and the technological R & D scheme was prepared for large-scale methanol engine power plant featured by low NOx and high efficiency. Technological development issues of this plant were as follows: improvement of thermal efficiency, reduction of NOx emission, improvement of the reliability and durability of ignition and fuel injection systems, and reduction of vibration. As the economical effect of the technological development, the profitability of NOx control measures was compared between this methanol engine and conventional heavy oil diesel engines or gas engines. As a result, this engine was more economical than conventional engines. It was suggested that development of the equipment will be completed in nearly 4 years through every component study, single-cylinder model experiment and real engine test. 21 refs., 43 figs., 19 tabs.

  9. Evaluation of damping property of long-span prestressed concrete cable-stayed bridges; Chodai PC shachokyo no gensui tokusei ni kansuru kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Yamanobe, S.; Niihara, Y.; Minami, H.; Kono, T. [Kajima Corp., Tokyo (Japan)

    1999-09-30

    As to the dynamic design in the antiseismic design of PC cable-stayed bridges, evaluation of damping is important. Since it is difficult to evaluate damping property theoretically and analytically, a lot of studies have not been made about how to set up damping coefficients. In this study, using analytical models of existing long-span PC cable-stayed bridges, to clarify causes of damping of long-span PC cable-stayed bridge, the rate of strain energy in each member was examined. Equivalent damping coefficients of each member, effects of friction in movable bearing, and effects of basically radiational damping were studied. The correspondence with the results of the vibration experiments conventionally made were studied. (translated by NEDO)

  10. Studies on the air distribution and thermal performance of the air circulation wall. Part 4. Study on the thermal emissivity of the air circulation layer`s surfaces; Gaidannetsu tsuki koho ni okeru tsuki sonai no netsu tsuki tokusei ni kansuru kenkyu. 4. Tsuki sonai hyomen no hosha tokusei ni kansuru kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Kamimori, K.; Sakai, K.; Ishihara, O. [Kumamoto University, Kumamoto (Japan)

    1996-10-27

    The thermal and air distribution characteristics of the air circulation wall in a heat-insulated system were grasped using an experimental model. In this paper, the difference in the heat exchange between the wall and air was confirmed based on the radiation on the circulation layer`s surface. In this system, thin air circulation layers with ventilating holes at the top and bottom are attached to the south and north outer walls of a wooden building. This system is a kind of passive solar house that achieves the insolation screening effect and the temperature rising effect based on solar collection. The heat flow in a circulation layer is eliminated by the natural convection heat transfer on the outer wall. The heat flow passing through insulating materials is the heat transfer by radiation. The heat flow based on the in-layer natural convection is increasingly eliminated by the decrease in temperature on the air circulation layer`s surface. The decrease in room surface temperature using aluminum foil and the reflective heat-insulated effect showed that the heat passing through the wall surface decreases as the convection heat transfer in an air circulation layer increases. 6 refs., 20 figs., 3 tabs.

  11. Experimental investigation on prestressed concrete slabs for two- or three-girders bridges; Shoshuketa kyoryoyo PC yukaban ni kansuru jikken kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Sakai, F.; Yabe, J.; Ogaki, K.; Sakugawa, K.; Ito, A.; Takeuchi, K.; Tomoda, T. [Kawasaki Heavy Industries, Ltd., Kobe (Japan)

    1996-01-20

    Rationalization and labor-saving in the construction of bridges are the pending problems arising from the shortage of skilled construction workers, shortened time usable for construction, and demand for lower cost. Under the circumstances, experiment and study were conducted about the PC slab for two- or three-girder bridges. On the assumption of a PC slab located between two main girders, the interval 6 meters long, specimens near the real size were subjected to experiments. Springs were attached to the free sides so that load tests might be conducted under boundary conditions equivalent to those of a finite continuous slab along the direction of the bridge length as in case of a real bridge. It was found that a partial slab model of limited dimensions was usable when a long span slab experiment was necessary. A PC slab, unlike an RC slab, regained its elastic behavior when the load was removed even after the appearance of cracks. Crack producing loads fell within the range which could generally be estimated by calculation, and the PC slab was capable of restoring its original state upon unloading even after the production of cracks. The PC slab, as compared with the RC slab, demonstrated a greater ultimate strength, but the strength was not affected by the size of the prestress. In case of a PC slab on a long span, the bend fracture precedes and the ultimate strength is determined by the bend strength. 9 refs., 9 figs., 5 tabs.

  12. Improved design of three-dimensional lens for low concentrator PV modules; Teishukogata taiyo denchiyo sanjigen lens no koseinoka ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Goma, S.; Yoshioka, K.; Saito, T. [Tokyo Univ. of Agriculture and Technology, Tokyo (Japan)

    1997-11-25

    Attention is paid to reduction in area required for solar cells by solar concentration as a means of solving cost limits of solar cells and unstable supply of Si materials. Low concentration solar cells are effective from the aspects of utilization of scattered light and unnecessary ray tracing. The optical concentration ratio was calculated of three-dimensional lens having design values of various north/south and east/west direction allowable incidence half angles. The three-dimensional lens are designed by cutting a rectangular parallelepiped by the two-dimensional composite elliptical plane designed by various allowable incidence half angles from two directions of north/south and east/west. Using Perez`s sky solar radiation models and meteorological data HASP, calculated were the annual accumulated global radiation ratio on an inclined surface and the optical efficiency. Calculated were the solar cell area ratio and solar concentration area ratio of the concentration type to obtain solar radiation the same as that of the planar type. From the optimization calculation, it was found that lens are optimal which have design values of north/south and east/west direction allowable incidence half angles of 30-70deg. The solar cell area ratio is 57% and the solar concentration area ratio is 1.2 times. It was found that by making the module area 1.2 times, more than 40% of the solar cells used can be saved. 5 refs., 8 figs.

  13. Study on detecting method of rail corrugation by using wavelet analysis; Wavelet kaiseki wo mochiita rail hajo mamo kenshutsu shuho ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Suda, Y.; Okumura, M.; Komine, H.; Iwasa, T.; Terumichi, Y. [The University of Tokyo, Tokyo (Japan). Institute of Industrial Science; Qian, B. [The University of Tokyo, Tokyo (Japan)

    1998-11-01

    This paper reports the development of a method that detects the corrugation of a rail. A measurement test in which the track inspection car provided with an axle box accelerometer and irregular rail top face measurement equipment runs over the range of a specific section at the setting rate was conducted. A wavelet analysis is applied to the obtained acceleration data of vertical axle box vibration. The position of the generated corrugation was detected in a time base as the high position of a wavelet coefficient. Moreover, the dominant frequency range of corrugation was detected for each frequency by adding the wavelet coefficients in the whole position. This result was verified using the measurement data of an irregular rail top face. The wave height of corrugation can be estimated from the amplitude of the vertical vibration acceleration measured during low-speed traveling when the calculation result of a frequency response using the vertical vibration model in simplified wheel and rail systems is compared with the test result described above. 2 refs., 8 figs., 1 tab.

  14. Consideration on longitudinal bending moment in waves of a large high-speed ship; Ogata kosokutei no haro tatemage moment ni kansuru ichikosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Deguchi, M.; Takimoto, T.; Kasuda, T.; Tozawa, S. [Mitsubishi Heavy Industries, Ltd., Tokyo (Japan)

    1996-04-10

    While high-speed ships are on a trend of increased speed, size and diversity, one of the most important items is a discussion on large high-speed ships with a total length of 100 m class on their longitudinal strength in waves. With such a background, a model ship intended of realizing a large high-speed was assumed, and verification of reliability in structural strength and establishment of a design method for this ship were intended. Therefore, oceanographic condition setting, design load setting, FEM analysis, and strength assessment were carried out. This paper reports the results of comparison with and consideration on conventional criteria and linear calculations, mainly the results of simulated calculations on non-linear hull movement/wave load which have been performed in discussing the loads. The result of the non-linear simulation is thought to have well simulated non-linearity characteristic to the ship. Conventional criteria which have been arranged on the record of use for small ships are considered impossible to be applied to large high-speed ships. Under such a situation, the simplified equations by Kaneko et al are judged effective in making an initial plan for this type of ship. 6 refs., 7 figs., 2 tabs.

  15. Bayesian reliability analysis for non-periodic inspection with estimation of uncertain parameters; Bayesian shinraisei kaiseki wo tekiyoshita hiteiki kozo kensa ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Itagaki, H. [Yokohama National University, Yokohama (Japan). Faculty of Engineering; Asada, H.; Ito, S. [National Aerospace Laboratory, Tokyo (Japan); Shinozuka, M.

    1996-12-31

    Risk assessed structural positions in a pressurized fuselage of a transport-type aircraft applied with damage tolerance design are taken up as the subject of discussion. A small number of data obtained from inspections on the positions was used to discuss the Bayesian reliability analysis that can estimate also a proper non-periodic inspection schedule, while estimating proper values for uncertain factors. As a result, time period of generating fatigue cracks was determined according to procedure of detailed visual inspections. The analysis method was found capable of estimating values that are thought reasonable and the proper inspection schedule using these values, in spite of placing the fatigue crack progress expression in a very simple form and estimating both factors as the uncertain factors. Thus, the present analysis method was verified of its effectiveness. This study has discussed at the same time the structural positions, modeling of fatigue cracks generated and develop in the positions, conditions for destruction, damage factors, and capability of the inspection from different viewpoints. This reliability analysis method is thought effective also on such other structures as offshore structures. 18 refs., 8 figs., 1 tab.

  16. Basic studies on computer aided concurrent engineering for hull structure design and piping design; Kakugi ittai wo koryoshita doji heikotekina sekkei no shien ni kansuru kisoteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Aoyama, K.; Sawada, K. [The University of Tokyo, Tokyo (Japan)

    1996-12-31

    Considering integrated hull and piping design in shipbuilding industry as a good example for concurrent engineering (CE), discussions were given on a computer aided method to perform integrated hull and piping design smoothly. When CE aiding by means of a computer is considered, it is important to discuss a method for information management not only for `utilization of product models`, but also for `maintaining consistency between items of product information` and `concurrent utilization and production of product information` in concurrent designs. For the CE aided information management, utilization and production of the product information is effective if restrictive relationship between items of product information, and design functions are made clear. Definitions were given on the restrictive relationship between items of product information and `restrictive relationship information` that has `decision/provisional decision`, `date and time`, `designer` and `design functions`. Furthermore, `comprehensive relationship between items of product information` that can be produced from the restrictive relationship information was defined as a `restrictive network`. Utilizing the restrictive relationship between items of product information for CE aiding is effective. 9 refs., 14 figs.

  17. Interface physical chemistry of enamels (Part 1). Examination of cobalt and nickel behevior and adhesion of enamel; Hourou ni kansuru kaimen butsuri kagakuteki kenkyu (1). Micchakusei ni oyobosu cobalt to nickel no kyodo no kento

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, T.; Shirasaki, M.; Kozuka, T. [Chiba Inst. of Tech., Narashino (Japan)] Zhaohua, J. [Harbin Institute of Technology Harbin (China). Applied Chemisty] Kawashima, T. [Ikebukuro Horo Kogyo Co. Ltd., Saitama (Japan)

    1998-02-01

    Observation of the enameles interface with SEM, EPMA and ESCA, and measurement of adhesive strength of the enameles were done. Simultaneously, cobalt and nickel in the enamel layer examined a given influence at the interface and the adhesive strength. As a result, the relationship between iron-oxygen, cobalt-oxygen and nickel-oxygen, at the reaction of enamel process was explained by the interface thermodynamics. Furthermore, characteristics and differences of reaction of cobalt and nickel were clarified. (1) The adhesive ability of Co-enamel was larger than that of Ni-enamel. (2) The adhesive behavior of cobalt changes at about 730degC, but that of nickel remains unchanges. Consequently, cobalt has an adhesion with the high temperature (over 730degC) but nickel does not have an influence on the temperature. (3) At high firing temperature, the Co-enamel can create FeO easily compared with Ni-enamel, and dissolve Fe{sub 2}O{sub 3} of steel surface into glass. (4) Cobalt spreads for a vertical direction of interface, but nickel tends deposition on the interface surface. And the diffusion capability of cobalt into the steel was considerably greater than that of nickel. 18 refs., 7 figs., 3 tabs.

  18. Feasible study of international cooperation on the long-term scenario for reducing CO2. DNE-21 simulation database; CO2 sakugen ni kakawaru choki scenario ni kansuru kokusai kyoryoku kanosei chosa. DNE21 simulation database

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This report describes calculation codes of DNE-21 which can simulate the optimization model for reducing CO2. The DNE-21 was modified from the former NE-21. The term was set between 2000 and 2100. Optimization can be conducted across the different time. Non-conventional petroleum was removed from the primary energy. Capacity of nuclear power generation facilities was taken in the model for the optimization. Decision making analysis can be done by considering the uncertainty. The DNE-21 has eleven input files including the model operation, technical property related data, cost related data, data of tax, subsidy and customs, and scenario data of future energy demand and supply, GNP, population and nuclear power. The DNE-21 has fifteen output files including the optimization calculation results for the world, Oceania, the Middle East, North Africa, Central America, South America, former USSR, and OECD countries. 2 figs.

  19. Fiscal 1996 survey of potential international cooperation for a long-term scenario on CO2 reduction; 1996 nendo CO2 sakugen ni kakawaru choki shinario ni kansuru kokusai kyoryoku kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    For the purpose of working out a CO2 reduction scenario and a CO2 policy introduction scenario, a survey was conducted of comparisons between ten and several models which are world-known and models of the New Earth 21, potential international cooperation to be carried out in the future, etc. The survey included organizations which are developing CO2 policy evaluation models, survey reports made in the past, details of literature for the analysis and arrangement. From the result, details of the questionnaire survey and organizations to be surveyed were decided on for the questionnaire survey. Objects for the survey were 7 countries and 22 organizations, and survey items were places for information exchange, sending/receiving of researchers, exchange of input data, comparative calculation based on the common database, joint research work, economy, the carbon tax, impact, renewable energy, how to handle and think of the carbon isolation, etc. As a result of the survey, proposed were a workshop on CO2 reduction, a comparative study of simulation models, etc. 25 refs., 50 figs., 12 tabs.

  20. Analysis on recreational development and deforestation due to accessibility improvement in the suburban areas; Kotsu kaizen ni kiinshita kanko chiiki no shizenteki tochi riyo no henka ni kansuru bunseki

    Energy Technology Data Exchange (ETDEWEB)

    Doi, K. [Tokyo Institute of Technology, Tokyo (Japan); Okamoto, N. [Japan Transport Economics Research Center, Tokyo (Japan); Murata, A. [Housing and Urban Development Corp., Tokyo (Japan)

    1997-07-20

    In the suburban areas, the abundance of natural resources is essential for recreational activities. However, it is often observed that the increase in recreational travelers causes the degradation of natural environmental quality. The purpose of this study is to analyze the impact of transport improvement on development and the consequent decrease of natural green areas in suburban areas. A method of LISREL is adopted for identifying the contribution of green conservation to recreational attractiveness and the causalities among degradation of green conservation and accessibility improvement. A simultaneous equations system of recreational travel demand and developers` strategy is modeled and adopted for assessing the impact of accessibility improvement on the depletion of green areas. 14 refs., 15 figs., 6 tabs.

  1. Modelling of rechargeable NiMH batteries

    NARCIS (Netherlands)

    Ledovskikh, A.; Verbitskiy, E.; Ayeb, A.; Notten, P.H.L.

    2003-01-01

    A new mathematical model has been developed for rechargeable NiMH batteries, which is based on the occurring physical–chemical processes inside. This model enables one to simultaneously simulate the battery voltage, internal gas pressures (both PO2 and PH2) and temperature during battery operation.

  2. Modelling of rechargeable NiMH batteries

    NARCIS (Netherlands)

    Ledovskikh, A.; Verbitskiy, E.; Ayeb, A.; Notten, P.H.L.

    2003-01-01

    A new mathematical model has been developed for rechargeable NiMH batteries, which is based on the occurring physical–chemical processes inside. This model enables one to simultaneously simulate the battery voltage, internal gas pressures (both PO2 and PH2) and temperature during battery operation.

  3. Effect of heat generation from bone cement on bone tissue in total knee arthroplasty; Jinko kansetsu okikaeji no one cement no hatsunetsu ga seitai soshiki ni oyobosu eikyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Matsuda, M.; Uchida, T. [Kobe University, Kobe (Japan); Iwatsubo, T. [Kobe University, Kobe (Japan). Faculty of Engineering; Kurosawa, M.; Hashimoto, Y. [Kobe University, Kobe (Japan). Faculty of Medicine; Fukushima, H.

    1998-01-25

    Bone cement is often applied to fix the components in a surgical operation, such as TKA (total knee arthroplasty). In this paper, we consider the effect of heat generation from bone cement on bone tissue in TKA by using numerical simulation. First, we applied an axisymmetric model of tibia to finite element method and analyzed heat generation of bone cement. To confirm the results of analysis by experiment, we measured the temperature determined by 6 points i.e., 2 points each in component-cement interface, cement and bone-cement interface. As a result, the temperature determined by analysis agrees with that determined by experiment. Next, we proposed the evaluation formula of the bone necrosis. We constructed a bone necrosis map from the simulation. From the map, we found that the bone necrosis region was about 2 mm from the bone-cement interface. In addition, the bone necrosis is severe at the base of the tibial component. 7 refs., 15 figs., 3 tabs.

  4. Study on passive earth pressure acting on the embedment of an earth retaining wall for braced excavation work in cohesive soil; Nenseido jiban ni okeru kussaku dodomeheki neirebu no judo doatsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, H. [Pacific Consultants K.K., Tokyo (Japan); Hirashima, K. [Yamanashi University, Yamanashi (Japan). Faculty of Engineering

    1995-12-15

    Passive earth pressure exerts a great influence on the stress and deformation of earth retaining walls in braced excavation. To calculate this pressure, conventional ultimate earth pressure equation, or Rankine-Resals and Coulomb`s equation, are currently applied respectively to cohesive and sandy soil. However, these intentional equation to determine passive earth pressure do not adequately take into account the excavation width during work and the shearing resistance on the earth retaining wall surface. This paper deals with cohesive soil only, deriving a calculation equation for passive earth pressure, which takes into account excavation width and the shearing resistance of the earth retaining wall surface. Then, constants in this equation are determined using the calculation results obtained from the finite element method with blasts-plastic elements. The calculation results are also compared with measured values in the model test in order to check the applicability of the calculation equation for passive earth pressure thus obtained. Finally, this paper proposes a practicable calculation equation for passive earth pressure. 13 refs., 10 figs., 10 tabs.

  5. Studies of initial stage in coal liquefaction. 4. Radical formation and structural change with thermal decomposition of coal; Ekika hanno no shoki katei ni kansuru kenkyu. 4. Netsubunkai ni tomonau radical seisei kyodo to kozo henka

    Energy Technology Data Exchange (ETDEWEB)

    Kanaji, M.; Kaneko, T.; Shimasaki, K. [Nippon Brown Coal Liquefaction Co. Ltd., Tokyo (Japan); Kumagai, H.; Chiba, T. [Hokkaido University, Sapporo (Japan). Center for Advanced Research of Energy Technology

    1996-10-28

    In relation to coal liquefaction reaction, the effect of the coexistence of transferable hydrogen (TH) from process solvent on reduction of radical concentration and the effect of pre-heat treatment on average structure of coals were studied. In experiment, change in radical concentration with temperature rise was measured using the system composed of Yallourn coal and process solvent. The results are as follows. Process solvent with a wide boiling point range of 180-420{degree}C is effective in suppressing an increase in radical concentration even at higher temperature. The effect of hydrogen-donating solvent increases with TH. It was also suggested that high-boiling point constituents in solvent stabilize radicals even over 400{degree}C by vapor phase hydrogenation. The experimental results of pre-heat treatment are as follows. Although the conversion improvement effect of TH is equivalent to that of the model solvent, TH tends to produce soluble products with smaller ring numbers. It was thus suggested that pre-heat treatment in process solvent is effective to inhibit retrogressive reactions. 6 refs., 5 figs., 1 tab.

  6. General report on investigations of fault, earthquake motion and damage due to the 1995 Hyogoken-nanbu Earthquake; 1995 nen Hyogoken nanbu jishin ni okeru danso, jishindo, higai ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Compiled herein are the results of various investigations and examinations conducted concerning the 1995 Hyogoken-nambu earthquake. Along the boundary surface between the granite and Osaka group, and in the Osaka group, accumulated displacements and flexural structures are found, supposedly attributable to faulting, by high-density electric prospecting and underground radar prospecting near the Nojima earthquake fault. Displaced structures in the unconsolidated covering layer are detected to the depth of 10-odd meters. Displacement of ground water due to earthquake is different between the shallow and deep layers, which can be explained by a simplified model. The dynamic stress drop in the main shock is equal to the maximum ({Delta}{gamma}) value of each of the aftershocks, and there exists a certain ceiling over the {Delta}{gamma}dependence on the earthquake moment. The maximum acceleration of the earthquake motion estimated from waveforms in the rock is approximately 300 gals, which probably results from the concentration in one direction of the inputted energy wherein long period components are dominant. The newly developed nonlinear analysis technique simulates the attenuation and amplification of acceleration accompanied by liquefaction, and the buckling behavior of bridge columns may be explained by this technique. 72 refs., 84 figs., 6 tabs.

  7. FY1998 report on a survey related to joint utilization of welfare device development data using an international network; 1998 nendo kokusai network ni yoru fukushi kiki kaihatsu data no kyodo riyo ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    A survey was made in relation with joint utilization of welfare device development data using an international network. Developing welfare devices requires data from ergonomic and medical systems, while the cope of the objects is wide, and the kinds are various. For proliferation of welfare devices, system compatibility evaluation including that on using environment is important, including living environments that are different by countries. The present survey has identified how data for aged, handicapped and help-needing persons are accumulated and utilized in research organizations in America and Europe for both of the ergonomic and medical areas. The survey also investigated major academic societies in overseas countries, and collected database and academic network information that support the advanced research and development. At the same time, investigations were also made on organizations and corporations who are moving forward the efficient data utilization. Welfare device and service information providing systems in Japan were investigated to compare them with the trends in other countries. Conceptions and methods were compiled to utilize data internationally and jointly. Database models for device development were considered, and a proposal was made on structuring a research and development supporting database, and the operation method thereof. (NEDO)

  8. Research and survey report of FY 1997 on the CO2 balance for high-temperature CO2 fixation and utilization technology; 1997 nendo chosa hokokusho (nisanka tanso koon bunri gijutsu ni okeru CO2 balance ni kansuru chosa kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The purpose of this research is to clarify the application condition and effectiveness of high-temperature CO2 fixation and utilization technology. To evaluate the present process, it was compared with others, such as separation using a polymer membrane, physico-chemical absorption process, adsorption process, hydrogen contact reduction process, and biological fixation. The development trends of absorption, membrane, adsorption, and cryogenic separation were investigated. The questionnaire was carried out about the separation technologies which are in the stage of performance test using actual gas, to arrange and compare the data and information. The current trends of chemical and biological CO2 fixation and utilization technology were also investigated for arranging the subjects. High-temperature CO2 disposal by the carbonation in concrete waste has been studied, to clarify its application conditions and effectiveness. In order to compare the separation technologies, treatment processes of CO2 in the exhaust gas from boilers of LNG power generation and coal fired power generation were simulated. These processes were simulated by ASPEN PLUS for the modeling. Trends of application of ASPEN PLUS and collection of information were surveyed by participating in the ASPEN WORLD. 103 refs., 51 figs., 55 tabs.

  9. Modeling and simulation of NiO dissolution and Ni deposition in molten carbonate fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Nam, Suk Woo; Choi, Hyung-Joon; Lim, Tae Hoon [Korea Institute of Science & Technology, Seoul (Korea, Republic of)] [and others

    1996-12-31

    Dissolution of NiO cathode into the electrolyte matrix is an important phenomena limiting the lifetime of molten carbonate fuel cell (MCFC). The dissolved nickel diffuses into the matrix and is reduced by dissolved hydrogen leading to the formation of metallic nickel films in the pores of the matrix. The growth of Ni films in the electrolyte matrix during the continuous cell operation results eventually in shorting between cathode and anode. Various mathematical and empirical models have been developed to describe the NiO dissolution and Ni deposition processes, and these models have some success in estimating the lifetime of MCFC by correlating the amount of Ni deposited in the matrix with shorting time. Since the exact mechanism of Ni deposition was not well understood, deposition reaction was assumed to be very fast in most of the models and the Ni deposition region was limited around a point in the matrix. In fact, formation of Ni films takes place in a rather broad region in the matrix, the location and thickness of the film depending on operating conditions as well as matrix properties. In this study, we assumed simple reaction kinetics for Ni deposition and developed a mathematical model to get the distribution of nickel in the matrix.

  10. Synthesis, structure and reactivity of Ni site models of [NiFeSe] hydrogenases.

    Science.gov (United States)

    Wombwell, Claire; Reisner, Erwin

    2014-03-21

    A series of structural models of the Ni centre in [NiFeSe] hydrogenases has been developed which exhibits key structural features of the Ni site in the H2 cycling enzyme. Specifically, two complexes with a hydrogenase-analogous four-coordinate 'NiS3Se' primary coordination sphere and complexes with a 'NiS2Se2' and a 'NiS4' core are reported. The reactivity of the complexes towards oxygen and protons shows some relevance to the chemistry of [NiFeSe] hydrogenases. Exposure of a 'NiS3Se' complex to atmospheric oxygen results in the oxidation of the selenolate group in the complex to a diselenide, which is released from the nickel site. Oxidation of the selenolate ligand on Ni occurs approximately four times faster than oxidation with the analogous sulfur complex. Reaction of the complexes with one equivalent of HBF4 results in protonation of the monodentate chalcogenolate and the release of this ligand from the metal centre as a thiol or selenol. Unrelated to their biomimetic nature, the complexes serve also as molecular precursors to modify electrodes with Ni-S-Se containing particles by electrochemical deposition. The activated electrodes evolve H2 in pH neutral water with an electrocatalytic onset potential of -0.6 V and a current density of 15 μA cm(-2) at -0.75 V vs. NHE.

  11. Models of the Ni-L and Ni-SIa States of the [NiFe]-Hydrogenase Active Site.

    Science.gov (United States)

    Chambers, Geoffrey M; Huynh, Mioy T; Li, Yulong; Hammes-Schiffer, Sharon; Rauchfuss, Thomas B; Reijerse, Edward; Lubitz, Wolfgang

    2016-01-19

    A new class of synthetic models for the active site of [NiFe]-hydrogenases are described. The Ni(I/II)(SCys)2 and Fe(II)(CN)2CO sites are represented with (RC5H4)Ni(I/II) and Fe(II)(diphos)(CO) modules, where diphos = 1,2-C2H4(PPh2)2(dppe) or cis-1,2-C2H2(PPh2)2(dppv). The two bridging thiolate ligands are represented by CH2(CH2S)2(2-) (pdt(2-)), Me2C(CH2S)2(2-) (Me2pdt(2-)), and (C6H5S)2(2-). The reaction of Fe(pdt)(CO)2(dppe) and [(C5H5)3Ni2]BF4 affords [(C5H5)Ni(pdt)Fe(dppe)(CO)]BF4 ([1a]BF4). Monocarbonyl [1a]BF4 features an S = 0 Ni(II)Fe(II) center with five-coordinated iron, as proposed for the Ni-SIa state of the enzyme. One-electron reduction of [1a](+) affords the S = 1/2 derivative [1a](0), which, according to density functional theory (DFT) calculations and electron paramagnetic resonance and Mössbauer spectroscopies, is best described as a Ni(I)Fe(II) compound. The Ni(I)Fe(II) assignment matches that for the Ni-L state in [NiFe]-hydrogenase, unlike recently reported Ni(II)Fe(I)-based models. Compound [1a](0) reacts with strong acids to liberate 0.5 equiv of H2 and regenerate [1a](+), indicating that H2 evolution is catalyzed by [1a](0). DFT calculations were used to investigate the pathway for H2 evolution and revealed that the mechanism can proceed through two isomers of [1a](0) that differ in the stereochemistry of the Fe(dppe)CO center. Calculations suggest that protonation of [1a](0) (both isomers) affords Ni(III)-H-Fe(II) intermediates, which represent mimics of the Ni-C state of the enzyme.

  12. Trend survey of the global environment adaptation type industrial technology. Chikyu kankyo tekiogata sangyo gijutsu doko chosa. ; Chikyu kankyo kanren kenkyu doko no chosa (nisanka tanso no kankyo fuka teigensaku ni kansuru chosa kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    1992-03-01

    The paper studies the measures for reduction of environmental load of CO2 from the standpoint of chemical technology. As for methanol synthesis from CO2, accelerating of the reaction using Cu base compound catalyst is reported. Also, CO2 is methanated at high speed by low temperature waste heat using Ni-La2O3-Ru catalyst. Discussions are given on the subject for development of catalyst reaction relating to hydrogen production technology by methane reforming reaction using steam or CO2. Synthesis of polymetric materials by use of CO2 is also described. The paper mentions that it is indispensable to design high-function electrode and elucidate the reaction mechanism of electrochemical CO2 reduction for electrochemical and photochemical CO2 reduction measures. Moreover, in case of using solar energy, it is required to study photovoltaic excitation process in semiconductor electrode/ electrolyte solution interface. For production of hydrogen from CO2 by photosynthetic organisms and solar energy, the problem is control of inhibiting effect of oxygen combinedly produced. Described are production of polyhydroxy butyric acid and biodegradable polymer from CO2 and hydrogen by bacteria, and CO2 fixation imitating the enzyme reaction. 267 refs., 79 figs., 32 tabs.

  13. Study of selective oxidation of methane catalyzed by solid superacid in unique reaction field; Tokushu hannoba no kotai chokyosan wo mochiiru methane no sentaku sanka hanno ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Misonoo, M.; Tatsumi, T.; Mizuno, T.; Inumaru, T. [The University of Tokyo, Tokyo (Japan)

    1997-02-01

    Selective oxidation of lower alkanes by use of heteropolymeric compounds is studied. Alkanes are activated on Cs2.5H0.5PW12O40 serving as catalyst, and their activity and selectivity improve when the catalyst is developed into a dual function catalyst in which Cs and Pt are combined. A success is reported of the synthesis of a heteropolymeric acid in which two molecules of the coordination element wolfram are replaced with a transition metal of the first period, on which acid the oxidation of cyclohexane is enhanced. Cs2.5Ni0.08H1.34PVMo11O40 as a metal/heteropolymeric acid dual function catalyst enables the direct oxidation (9% recovered at 340{degree}C) of isobutane into a methacrylic acid, which is attributed to the harmonious coordination of the oxidizing work of the catalyst and acidity. It is possible to oxidize propane into the acrylic acid, but not ethane into the acetic acid. In the case of Pd/Cs2.5H1.5PVMo11O40, the formic acid, methanol, etc., are produced upon addition of hydrogen to the system. This reaction in the hydrogen/oxygen system is supposed to take place via activated oxygen seeds as in the case of oxidation by hydrogen peroxide. 10 refs.

  14. Fiscal 1997 report on the results of the international standardization R and D. International standards for computers/manikins; 1997 nendo seika hokokusho kokusai hyojun soseigata kenkyu kaihatsu. Computer manikin ni kansuru kokusai hyojun kikaku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Through the development of computer manikins (CM) which assess human adaptability to products and environments, a draft for international standardization was worked out to propose to ISO. A draft for the international standardization was presented to ISO through a development of `a structure model` changing based on human attributes, a study of `a motion model` enabling changes in posture and movement, a study of `an evaluation model` evaluating attainment ranges and ecodynamic loads, and a development of `computer functions` realizing the above-mentioned functions. The development of CM having the following characteristics: a function to reproduce `the structure model` based on the ISO7250 human body dimensional measuring values which were regulated in items for the human body dimensional measuring, a function to change posture/movement based on the joint movable range data, a function to evaluate geometrical human adaptability such as attainment ranges. As a plug-in to Autodesk Mechanical Desktop 2.0, the above-mentioned functions were realized, and the modular structure platform was constructed which enables the wide-range cross-industry option and functional expansion by the advance of CM. 7 refs., 41 figs., 18 tabs.

  15. Fiscal 1997 report on the survey project on planning to execute `The New Earth 21`; 1997 nendo chosa hokokusho (`chikyu saisei keikaku` no jisshi keikaku sakusei ni kansuru chosa jigyo)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Japan proposed in the Houston Summit the New Earth 21 to be carried out with technology development and technology transfer, and to make a concrete development of the project, Japan also proposed in the Tokyo Summit a TREE Plan for working out comprehensive strategies of the innovative technology development. In the CO3 Kyoto Conference in 1997, numerical targets for developed countries were determined which have legal binding force for control/reduction of greenhouse gas emissions in the term of 2008-2012. It was agreed to urge developing countries also to play a certain part in the project through the clean development. Therefore, the paper made quantitative analysis of important CO2 prevention technologies, technology transfer costs, and economical assessment by energy conservation. As a model, the DNE 21 model was upgraded and used into which CO2 prevention technologies, energy, economy and climate changes were integrated. In fiscal 1997, the following were carried out: collection of data on important CO2 prevention technologies and systems and analytical assessment using the DNE 21 model, CO2 reduction and selection of energy technology, assessment of energy system costs, construction of the unified DNE 21 model, and opening of the international workshop. 62 refs., 98 figs., 34 tabs.

  16. Studies on physicochemical mechanism of hot water injection. ; Studies on optimum production technique of geothermal fluid. Nessui no seisan kangen ni kansuru kenkyu. ; Nessui no saiteki seisan shuho no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, H.; Takahashi, M.; Hanano, M.; Hirako, Y. (Japan Metals and chemicals Co. Ltd., Tokyo (Japan)); Itoi, R. (Kyushu Univ., Fukuoka (Japan). Faculty of Engineering)

    1990-10-31

    In order to appropriately produce geothermal fluid, evaluation method was developed of reservoir, at each of the survey, development and production stages, as a serial part of Sunshine Project by the NEDO. For the production of thermal water and steam from the reservoir, evaluation must be appropriately and flexibly made of, among others, geothermal fluid supply capacity from the surroundings, interval between wells, against-time ratio of lowering in production well capacity, number of production wells, influence of reduced thermal water, and location and ratio of reduction. At the survey stage, it is good to generally analyze information, as also not voluminous, by a lumped parameter model. At the development stage from drilling as far as the production of thermal water, it is good to use a grid model, able to take the fracture, as well as the two-dimensional and three-dimensional distributions, into a particular consideration. Regarding how to make the grid division, the model comprises the wellfield model, to express one drilled well as one grid in locative region, of which the surroundings are to be divided by blocks, and well-by-well method, to locate one drilled well at one grid. At the production stage, data on well-by-well basis are important and the well-by-well method is accordingly the most important. 3 refs., 6 figs., 3 tabs.

  17. Study on a rational design of leg material-fixation for a deep footing of a large-scale electric power-transmitting steel tower; Ogata sodenyo tetto shinso kiso no goriteki na kyakuzai teichaku sekkeiho ni kansuru kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Iizima, M. [Tokyo Electric Power Co., Inc. (Japan)] Saito, S. [Toden Design Co. Ltd., Tokyo (Japan)] Mishima, T. [Maeda Construction Co. Ltd., Tokyo (Japan)

    1997-11-05

    When a footing of a steel tower for transmitting electric power is affected by vertical loads of both compression and lifting due to a wind load, fixation of leg materials as installation portions of the steel tower and the footing is important from a point of ensuring reliability of power transmission under such large loads. In this paper, results of studies on a model experiment executed for a purpose of enlarging and application scope of the leg materials fixation to deep footings, and numerical analysis which is executed by a finite element method considering tensile softening caused by crack of concrete for carrying destruction mechanism are described. It is re-confirmed that crack-resistant force is not in proportion to the increase of a body diameter and it is newly clarified that the crack-resistant force is not in proportion to the increase of concrete hardness either. A the model experiment can be simulated by executing the numerical analysis considering the tensile softening of concrete caused by a crack, effects of the concrete hardness and the body size upon a fixing strength of leg materials are examined. 7 refs., 21 figs., 3 tabs.

  18. Development of counter-rotaing type machine for water power generation. 1st Report. Counter-rotating type generator and axial-flow runners; Sohanten hoshiki suiryoku hatsuden ni kansuru kiso kenkyu. 1. hatsudenki to jikuryu runner no sohantenka

    Energy Technology Data Exchange (ETDEWEB)

    Kanemoto, T.; Tanaka, D.; Yagi, T. [Kyushu Institute of Technology, Kitakyushu (Japan); Kaneko, M. [Kawasaki Heavy Industries, Ltd., Kobe (Japan)

    2000-04-25

    This paper proposes the counter-rotating type machine for water power generation which is composed of the two-stage runners and the double rotors in the generator, and discusses the performances and internal flow conditions based on the experiments for the trial model. The maximum output power is obtained at the same counter-rotational speeds as designed, but such speeds differ from the maximum efficiency point. In the individual runner, the maximum output power of the rear runner is slightly less than that of the front runner, but the efficiency is overall good though the inlet flow condition of the rear runner is disturbed by the front runner. The flow conditions around the runners suggest the further improvement points for the runner profiles. (author)

  19. Studies on legal systems and public decision-making process of the environmental protection and natural conservation; Kankyo{center{underscore}dot}shizenhogo no mirai no tameno koukyoteki kettei to sisutemu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Hayashida, Seimei [Hokkaido University, Hokkaido (Japan). Faculty of Law

    1998-12-16

    This study have dealt with the issues of how the policies of environmental and natural protection should be shaped in a democratic society, and what the optimal legal systems should be for realizing the policies. We have analyzed these issues from the following three points of view ; the first one is the legal philosophical issues of justice and moral values among individuals and organizations. Secondly, we analyzed the optimal deterrence system of organizations for pollution controls, etc. We studied crimes and illegal conducts by organizations and corporations themselves, and their employees under the principal-agency model. Third, we looked at the legal system itself and the foundations of environmental issues from the legal-philosophical aspect. Fourth, we analyzed how the social decision-makings on the environmental protection were produced, using the public choice theory. (author)

  20. Experimental study of lightning protection effects to a overhead ground wire by a lightning rod and projection rods; Yuraishin oyobi dosshi wo mochiita kakuchisen no raigai boshi ni kansuru jikkenteki kento

    Energy Technology Data Exchange (ETDEWEB)

    Katsuragi, Y. [Chubu Electric Power Co. Inc., Nagoya (Japan); Aihara, Y. [Central Research Institute of Electric Power Industry, Tokyo (Japan)

    1995-04-20

    The overhead ground wire is generally used on transmission lines as one of the lightning protection devices for the power conductors. In recent years, the ground wire with an optical fiber cable in it (OPGW) has been employed on the transmission systems. The strands of the ground wire are, however, frequently melted down because of lightning strokes to them not only in summer but also in winter. For this reason, it is necessary to devise the new lightning protection method for the ground wire. As the protection method, lightning rods installed on the transmission tower arms and projection rods wound around a ground wire are proposed by authors. Lightning protection effects of these methods are shown by model experiments which simulate summer and winter lightning strokes. It has been made clear that these methods are useful as one of the lightning protection methods for transmission lines, and application conditions of them for practical use are also shown. 4 refs., 12 figs., 2 tabs.

  1. Manufacturing technology supported by advanced and integrated information system through international cooperation in fiscal 1995; Kan`i sosagata denshi sekkei seisan shien system no kaihatsu ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Informatization using mainly computers is more and more important contributing to the upgrading in society, economy and a variety of fields. As to informatization in developing countries, however, there has still been few to be seen. Accordingly, gaps are getting larger between developing countries and developed countries where informatization is acceleratedly advanced. In the light of such actual state, Center of the International Cooperation for Computerization (CICC) contracted with NEDO and promoted a project `Manufacturing technology supported by advanced and integrated information system through international cooperation.` This is a project to study jointly with five Asian countries with which NEDO made a basic contract, China, Indonesia, Malaysia, Singapore and Thailand. Working group is set up for each theme such as automobiles/parts, electric home appliances/parts, and fiber/apparel, to study the construction of a model house and the design of a system. In fiscal 1994, the field survey was conducted, and in fiscal 1995 the system design was started. 16 figs., 1 tab.

  2. Dynamic analysis of middle scale horizontal axis wind turbine. ; Comparison between results of computer simulation and field test. Chugata suiheijiku fusha no dotokusei kaiseki ni kansuru kenkyu. ; Computer simulation kekka to field jikken kekka no hikaku

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, Y.; Kasahara, H.; Seki, K.; Furukubo, K. (Mie Univ., Mie, (Japan). Faculty of Engineering Tokai Univ., Tokyo, (Japan). Faculty of Engineering Suzuki Motor Co. Ltd., Shizuoka, (Japan))

    1990-04-25

    The dynamic characteristics of a middle scale horizontal axis wind turbine controlled by a computer were theoretically analyzed with a dynamic model, comparing with field test results. In experiments, the three-blades wind turbine was used of 7.5m in rotor height above ground, 8.2m in rotor diameter and 8kW in rated output, and the rotation force of the turbine was analyzed by a local circulation mehtod. After the characteristics were simulated using the measured data of rotor revolution, blade pitch angle and wind velocity as initial values, based on a real control program, blade pitch angle control variables were calculated from the simulated data of rotor revolution and generation current, to estimate the dynamic characteristics theoretically. As a result, the theoretical values of generation power, current, rotor revolution and blade pitch angle control agreed roughly with measured values, and both time-integrated total powers agreed fairly with each other, indicating a favorable applicability to power estimation. 6 refs., 11 figs., 1 tab.

  3. Effect of operating methods of wind turbine-generator system on net power extraction under wind speed fluctuations in fields; Hendo fukyoka deno doryoku chushutsu kara mita furyoku hatsuden system no unten seigyoho ni kansuru kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Wakui, T. [Japan Society for the Promotion of Science, Tokyo (Japan); Hashizume, T.; Ota, E. [Waseda University, Tokyo (Japan). School of Science and Engineering

    2000-01-25

    The effect of operating methods of wind turbine-generator system on net power extraction under wind speed fluctuations is discussed in relation to the dynamic behavior of the system. The system is composed of a Darrieus-Savonius hybrid wind turbine and a load generator. In this paper, two types of operating method are examined; constant tip speed ratio operation for stand-alone power systems (Scheme 1) and synchronous operation for utility power systems (Scheme 2). The computed results of the net extracting power using our dynamic simulation model show that the dominant factor of power extraction in Scheme 1 is the dynamic characteristics of rotational components and that it is important to select the appropriate rated wind speed in Scheme 2. Thus, it is concluded that a conformable operating method and rated power output of the system exist for each wind condition. In particular, small-scale systems, which are smaller than approximately 10 kW-system range, are desirable to be operated under a constant tip speed ratio as stand-alone power systems. (author)

  4. Study on reduction of consumption and peak demand of electric power used in residential houses with solar heating and PV systems; Solar house no fuka heijunka to energy sakugen koka ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Udagawa, M.; Endo, T. [Kogakuin University, Tokyo (Japan)

    1994-12-08

    A model house was simulated to reduce the consumption and peak demand for the photovoltaic power generation system, and solar heat air heating and hot water supply system in the solar house. As a type of construction, both wooden construction and reinforced concrete (RC) construction were selected with a total floor area of 125m{sup 2}. All the rooms were equipped with an air conditioner by heat pump from the air thermal source. A solar heat floor heater was simultaneously installed on the first floor. The hot water supply load was 4.8MWh per year. A commercial grid-connected on-site system was applied to the photovoltaic power generation with a 20m{sup 2} wide monocrystalline Si solar cell panel. As for the fluctuation in power load, the peak at the time of rising is more reduced in the RC house than in the wooden house, because the former is smaller in temperature fluctuation than the latter during the intermittence of air conditioning (as per the specified operational schedule). Therefore, the power is more leveled off in the former than in the latter. Between both, difference was hardly made in energy consumption per year. The ratio of dependency was 47% upon the photovoltaic power generation system, while it was 50% and 77%, under the air heating power load and hot water supply power load, respectively, upon the solar heat air heating and hot water supply system, so that both systems were considerably effective in saving the energy. 5 refs., 7 figs., 1 tab.

  5. Synthesis of inorganic mesopore materials and their application to control chemical reactions; Muki meso kukan zairyo no gosei to kagaku hannoba to shite no riyo gijutsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Ohashi, F.; Tomura, S.; Maeda, M.; Inukai, K.; Suzuki, M.; Okazaki, M.; Konishi, Y.; Toriyama, K. [National Industrial Research Institute of Nagoya,Nagoya (Japan)

    2000-10-25

    Materials enabling 'intelligent humidity control' were synthesized by using fumed silica, tetraethylorthotitanate, and a surfactant (alkyltrimethylammonium bromides (C{sub n}H{sub 2n+1}(CH{sub 3}){sub 3}N{sup +} (center dot) Br{sup -}, n=10 - 16) as a liquid-crystal template) under a hydrothermal condition. A homogeneous hexagonal structure of SiO{sub 2}-TiO{sub 2} was confirmed from X-ray diffraction analysis and TEM observation. These products had a high BET surface area of 540-863m{sup 2}/g and auniform pore diameter of 1.5-3nm, both of which were controlled by varyingthe size of the organic template molecule. A sharp increase in water adsorption was observed when the relative pressure (P/Po) increased in the range 0.4 - 0.6. Over this region, the weight % of water came in the range 20 - 50mass%. The water vapor adsorption isotherm was classified as type V in the IUPAC notation, which is characteristic of an unusually large hysteresis. This large hysteresis can be explained from the fact that the contact angle depends on whether water is being adsorbed or desorbed. High durability in their humidity-control ability was confirmed from repeated observation of the isotherm. As a characteristic of the chemical structure upon titanium incorporation, a wider distributionof the Si-O-Si angles in the SiO{sub 4} tetrahedra was indicated from the broad Q{sup 4} {sup 29}Si-MAS/NMR spectra with a small peak shift. To clarify the formation process of these mesoporous materials in the template-synthesis, we accumulated the basic parameters of micelles from the product-yield-detected ESR observations. In addition, as a model of the chemical reaction in the mesoporous material, we observed the reaction dynamics in a spherical micelle with the same technique Based on these preliminary experiments we designed a column reactor packed with a me soporous material to control the liquid phase reaction. (author)

  6. Study on cobalt oxide; Sanka kobaruto ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-11-28

    This is No.91 report of National Institute for Research in Inorganic Materials, concerning cobalt oxide. For the growth of single crystal by the Czochralski method, shape of interface and contamination of impurities are affected by the convection of molten liquid in the atmosphere. Various oxides besides CoO were investigated. Solid solutions of Cr2O3 and Al2O3 into CoO were also studied. Non-linear optic and dielectric properties of single crystals, such as Ba2NaNb5O15 and LiNbO3, were examined. It was considered that the positive electron having positive electric charge can be used for the study on the negative electric charge defect in materials. However, the positive electron itself is rare, which results in the too low efficiency of measurement. Efficiency improvement of 50 times was achieved by introducing a high performance 2D position detector, which was still low efficiency of one-hundredth compared with photoelectron spectroscopy. It was found that the aggregation structure of positive ion defects in CoO is a misunderstanding of phenomenon caused by the electronic state in bulk crystals. As a result of the study on the optical properties of f-electron transition metals, transparent ceramics with addition of various rare earth ions were described. 162 refs., 106 figs., 14 tabs.

  7. Study of biogas storage; Biogas no chozo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Fujii, I.; Kimura, T.; Umeda, H. [Meiji University, Tokyo (Japan)

    1997-11-25

    Study was made on the storage method of a methane component in biogas mainly composed of CO2 and methane gases. Methane clathrate as molecular complex is one kind of clathrate compounds. Eight methane gas molecules are absorbed into 46 water molecules, or methane gas of 216 l is absorbed into water of 1 l, resulting in considerable compact methane storage. Although methane clathrate is usually stable only under a condition of low temperature and high pressure, its formation equilibrium shifts toward a low pressure/high temperature side by adding additives such as amine, ether and ketone. Acetone can shift formation pressure from 30 to 10atm at 1degC, and formation temperature from 1 to 10degC at 30atm. Although methane liquefaction is also an efficient storage method, it requires liquefaction temperature and pressure of -83degC and 45.6atm, respectively. The distance between methane molecules in clathrate lattice can be more shortened than that in high- pressure charged gas, suggesting higher storage efficiency. The study result showed that the handling of methane clathrate is possible around room temperature and pressure. 7 refs., 5 figs.

  8. Study of white noise; Hakushoku zatsuon ni kansuru ichikosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Kano, R.; Tada, R. [Teikoku Oil Co. Ltd., Tokyo (Japan)

    1996-05-01

    A study was made on conditions available for white noise belonging to a finite power function with the use of a power spectrum conception. It was defined that a real variable function with a finite waveform energy was a finite energy function while that with a finite waveform power was a finite power function. A noncorrelative white noise was defined as a real variable function in which an autocorrelation function took a specific value at a certain point; however, the autocorrelation function was different between the finite energy function and the finite power function. In other words, the definition of white noise was such that `an energy spectrum was a fixed value` in the finite energy function, and that `a power spectrum was a fixed value` in the finite power function. It was pointed out, by Matsuyama (1994) with the use of the energy spectrum conception, that the white noise belonging to the finite energy function took only the form of `an arbitrary impulse function that all turned to zero except a certain point`. The same conclusion was obtained with respect to the white noise belonging to the finite power function. 1 ref., 1 tab.

  9. Predictive Modeling of the Constitutive Response of Precipitation Hardened Ni-Rich NiTi

    Science.gov (United States)

    Cox, A.; Franco, B.; Wang, S.; Baxevanis, T.; Karaman, I.; Lagoudas, D. C.

    2017-03-01

    The effective thermomechanical response of precipitation hardened near-equiatomic Ni-rich NiTi alloys is predicted on the basis of composition and heat treatment using a microscale-informed model. The model takes into account the structural effects of the precipitates (precipitate volume fraction, elastic properties, elastic mismatch between the precipitates and the matrix, and coherency stresses due to the lattice mismatch between the precipitates and the matrix) on the reversible martensitic transformation under load as well as the chemical effects resulting from the Ni-depletion of the matrix during precipitate growth. The post-aging thermomechanical response is predicted based on finite element simulations on representative microstructures, using the response of the solutionized material and time-temperature-martensitic transformation temperature maps. The predictions are compared with experiments for materials of different initial compositions and heat treatments and reasonably good agreement is demonstrated for relatively low precipitate volume fractions.

  10. Effect of massive transformation on formation of acicular structure in austenitic stainless steel weld metal solidified as ferritic single phase. Report 5. Study on solidification and subsequent transformation of Cr-Ni stainless steel weld metals; Feraito tanso de gyokosuru osutenaito kei sutenresu ko yosetsu kinzoku ni okeru ashikyura jo soshiki no keisei ni oyobosu masshibu hentai no eikyo.5. Cr-Ni kei sutenresu ko yosetsu kinzoku no gyoko/hentai ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, H.; Koseki, T.; Okita, S.; Fuji, M. [Nippon Steel Corp., Tokyo (Japan)

    1997-05-05

    The authors clarified that massive transformation occurs at two phase region under To temperature and there is K-S relation between the massive formation phase and base phase using {gamma} stainless steel that solidifies at F mode and forms acicular structure at room temperature structure. There is a possibility of massive transformation in weld metals because the cooling rate below the high temperature To was high even for normal welding process. Thereupon, in this report, whether the massive transformation effects the formation of acicular structure or not was studied as for {gamma} stainless steel weld metal that solidifies at F mode and room temperature structure becomes acicular form of two {delta} and {gamma} phase. As a result, it was clarified that massive transformation occurs at two phase region with temperature below To, and the room temperature structure was acicular form structure irrespective to massive transformation in case of composition with small Cr/Ni ratio even in case of stainless steel that solidifies at F mode. 20 refs., 15 figs., 1 tab.

  11. Solidification and transformation behavior of Cr-Ni stainless steel weld metals with ferritic single phase solidification mode. Report 4. Study on solidification and subsequent transformation of Cr-Ni stainless steel weld metals; Feraito tanso de gyokosuru Cr-Ni kei sutenresu ko yosetsu kinzoku no gyoko/hendo kyodo. 4. Cr-Ni kei sutenresu ko yosetsu kinzoku no gyoko/hentai ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, H.; Koseki, T.; Okita, S.; Fuji, M. [Nippon Steel Corp., Tokyo (Japan)

    1997-05-05

    The solidification modes of {gamma} stainless steel that solidifies at initial crystal {delta} are classified into FA mode where solidification at two phase of {delta}+{gamma} takes place after crystallization at {gamma} phase during solidification and F mode where solidification is completed at {delta} single phase, and solidification transformation behaviors of weld metal of FA mode are reported in the previous paper. Hereupon, in this report, solidification and transformation behaviors of stainless steel weld metal of F mode are studied. Cr-Ni stainless steel of F mode consists of two phase stainless steel with two phase base metal structure of {delta}+{gamma} besides {gamma} stainless steel. Further, two phase stainless steel with higher alloy compared to conventional one has been developed. In this report, not only the {gamma} stainless steel but also two phase stainless weld metals with varied amount of alloying metal are studied. The welding method and welding conditions are same as that of previous paper. Observation of structure was carried out by optical microscope, and crystal orientation and element distribution were measured by EBSP and CMA respectively. 11 refs., 18 figs., 1 tab.

  12. Technology to prevent deposition of marine organisms by means of electrically conductive coating. Discussions on current and potential distribution by using experiments; Doden tomaku ni yoru kaiyo seibutsu fuchaku boshi gijutsu. Denryu den`i bunpu ni kansuru jikken ni yoru kento

    Energy Technology Data Exchange (ETDEWEB)

    Usami, M.; Masaki, T. [Mitsubishi Heavy Industries, Ltd., Tokyo (Japan); Ueda, K.

    1996-04-10

    Steel structures in sea water and surface of hulls are deposited with such marine organisms as microorganisms, algae and shellfish. The deposition causes a large problem such as occurrence of abnormal local corrosion in the structures, and increase in cruising resistance in ocean vessels. The present study has introduced a simplified equation of estimation for current and potential distribution in parts coated with an electrically conductive film, and verified its reasonability by an experiment. The equation of estimation was introduced by following a model of current flow in the electrically conductive coating. The experiment has the conductive coating applied to the interior of a concrete water tank with a length of 10.8 m, a width of 5 m and a depth of 3 m to measure potential at different locations. The conductive coating was energized from copper foils attached on each applied face, whereas the current was applied to two faces between the conductive films as a pair among the four coating applied faces to measure potential in each location. A simulated calculation revealed that the potential range in the depth direction is made smaller if specific resistance of the conductive film is decreased, and made greater if increased. Effectiveness of the equation of estimation was verified by an experiment. This method has provided a prospect of achieving optimization of the specification for application of the conductive film. 2 refs., 7 figs.

  13. Fundamental study on the new method to estimate vibration level on a ship. Formulation of the damping matrix based on dissipation energy caused by fluid viscosity; Senpaku no shindo level suitei ni kansuru kisoteki kenkyu. Ryutai no nensei ni yoru san`itsu energy ni motozuku gensui matrix no teishikika

    Energy Technology Data Exchange (ETDEWEB)

    Funaki, T.; Hayashi, S. [Osaka University, Osaka (Japan). Faculty of engineering

    1996-12-31

    It is known in estimating vibration characteristics of a ship that fluid range affects largely a structure. In order to analyze the compound vibration therein, a method was proposed, which estimates vibration levels without using the finite element method. However, the problem of mode decay ratio has not been solved. Therefore, this paper first describes a method to introduce an equivalent linear decay matrix. The paper then mentions difference in the decay effects due to fluid viscosity in a shallow and deep water regions. Furthermore, vibration levels in the deep water region were estimated in a model experiment to verify the estimation result. Under a hypothesis that two-node vibration in a rotating ellipse has displacement distributions in the deep and shallow water regions equivalent, and when a case of vibration in a layer flow condition is calculated, dissipation energy in the shallow region is larger than that in the deep region by about 26%. About 5% of the total dissipation energy is consumed at bottom of the sea. According to a frequency response calculation, estimated values for the response levels still differ from experimental values, although the trend that the vibration levels change can be reproduced. 6 refs., 15 figs., 2 tabs.

  14. Study on unified fatigue strength assessment method for welded structure. Hot spot stress evaluating method for various combinations of plate thickness and weld leg length; Yosetsu kozo no toitsutekina hiro kyodo hyokaho ni kansuru kenkyu. Itaatsu to yosetsu ashinaga no kumiawase ni taisuru hot spot oryoku sanshutsu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Nihei, K.; Inamura, F.; Koe, S. [Kawasaki Heavy Industries, Ltd., Kobe (Japan)

    1996-12-31

    There has been tried to apply unified assessment method using hot spot stress, which is effective to evaluate fatigue strength of fillet welded structures for ships and marine structures. This method can be applied to complicated structures and is independent of welding processes. In this study, first, stress analysis has been conducted for two-dimensional fillet welded joint models with various combinations of plate thickness and weld leg length of general fillet structures by means of boundary element method. Then, critical position, which is not affected by local stress concentration due to bead, was determined from the detailed stress distribution in the vicinity of weld toe. As a result, a general equation has been proposed to estimate the hot spot stress by one-point representative method. Second, the fatigue tests of typical fillet welded joints have been conducted by applying this method. Consequently, it was demonstrated that the unified fatigue strength can be evaluated by the S-N data based on hot spot stress range determined from the proposed equation, independent of structural stress concentration. 22 refs., 14 figs.

  15. The formation model of Ni-Cr oxides on NiCoCrAlY-sprayed coating

    Energy Technology Data Exchange (ETDEWEB)

    Liang, G.Y., E-mail: gyliang@mail.xjtu.edu.cn [Department of Material Physics, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Science, Xi' an Jiaotong University, Xi' an 710049 (China); Zhu, C.; Wu, X.Y.; Wu, Y. [Department of Material Physics, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Science, Xi' an Jiaotong University, Xi' an 710049 (China)

    2011-05-15

    The atomic arrangement and distribution of oxides (Cr{sub 2}O{sub 3}, NiCr{sub 2}O{sub 4} and NiO) on the sprayed-NiCoCrAlY coating after oxidation are analyzed. The formation and the growth model of Ni-Cr oxide phases are discussed according to the matching relationship between atoms. The outline character and a scale of spinel NiCr{sub 2}O{sub 4} are discussed. The results show that Cr atoms can form two close-packed arrangements in the crystal plane of Cr{sub 2}O{sub 3} perpendicular to <0 0 1> orientation. The atomic spacing in the first arrangement corresponds to double that of Ni/Ni{sub 3}Al in {l_brace}1 1 1{r_brace} crystal face. This suggests that Ni/Ni{sub 3}Al is the substrate for Cr{sub 2}O{sub 3} to grow along <0 0 1> direction. The lattice mismatch between Cr{sub 2}O{sub 3} and Ni/Ni{sub 3}Al is less than that of Al{sub 2}O{sub 3}, which indicates that Cr{sub 2}O{sub 3} is easier to form than Al{sub 2}O{sub 3} during the oxidation process. The atomic spacing in another close-packed arrangement of Cr{sub 2}O{sub 3} perpendicular to <0 0 1> orientation is approximately equal to that of Ni or Cr in the plane of NiCr{sub 2}O{sub 4} and NiO perpendicular to <1 1 1> orientation. So Cr{sub 2}O{sub 3} can be the substrate for NiCr{sub 2}O{sub 4} and NiO to grow in the <0 0 1> direction. NiCr{sub 2}O{sub 4} and NiO can grow directly along the <1 1 1> orientation on each other. NiCr{sub 2}O{sub 4} can grow outward in the planes of Cr{sub 2}O{sub 3} perpendicular to <0 0 1> and grow inward along <1 1 1> orientation of NiO.

  16. Ni adsorption and Ni-Al LDH precipitation in a sandy aquifer: an experimental and mechanistic modeling study.

    Science.gov (United States)

    Regelink, Inge C; Temminghoff, Erwin J M

    2011-03-01

    Mining activities and industries have created nickel (Ni) contaminations in many parts of the world. The objective of this study is to increase our understanding of Ni adsorption and Nickel-Aluminium Layered Double Hydroxide (Ni-Al LDH) precipitation to reduce Ni mobility in a sandy soil aquifer. At pH ≥ 7.2 both adsorption and Ni-Al LDH precipitation occurred. In batch experiments with the sandy soil up to 70% of oxalate-extractable Al was taken up in LDH formation during 56 days. In a long term column experiment 99% of influent Ni was retained at pH 7.5 due to Ni adsorption (≈ 34%) and Ni-Al LDH precipitation (≈ 66%) based on mechanistic reactive transport modeling. The subsequent leaching at pH 6.5 could be largely attributed to desorption. Our results show that even in sandy aquifers with relatively low Al content, Ni-Al LDH precipitation is a promising mechanism to immobilize Ni.

  17. Structural and functional models for [NiFe] hydrogenase

    NARCIS (Netherlands)

    Angamuthu, Raja

    2009-01-01

    The main goal of the research presented in this thesis is the synthesis of suitable structural and functional models for the enzyme [NiFe] hydrogenase, which can reduce protons into dihydrogen. A brief survey of the roles of all the known nickel containing enzymes in biological systems with a focus

  18. First-Principles Point Defect Models for Zr7Ni10 and Zr2Ni7 Phases

    Directory of Open Access Journals (Sweden)

    Diana F. Wong

    2016-06-01

    Full Text Available Synergetic effects in multi-phased AB2 Laves-phase-based metal hydride (MH alloys enable the access of high hydrogen storage secondary phases, despite the lower absorption/desorption kinetics found in nickel/metal hydride (Ni/MH batteries. Alloy design strategies to further tune the electrochemical properties of these secondary phases include the use of additives and processing techniques to manipulate the chemical nature and the microstructure of these materials. It is also of particular interest to observe the engineering of constitutional point defects and how they may affect electrochemical properties and performance. The Zr7Ni10 phase appears particularly prone to point defects, and we use density functional theory (DFT calculations coupled with a statistical mechanics model to study the theoretical point defects. The Zr2Ni7 phase appears less prone to point defects, and we use the Zr2Ni7 point defect model, as well as experimental lattice parameters, with Zr7Ni10 phases from X-ray diffraction (XRD as points of comparison. The point defect models indicate that anti-site defects tend to form in the Zr7Ni10 phase, and that these defects form more easily in the Zr7Ni10 phase than the Zr2Ni7 phase, as expected.

  19. Investigation on the dynamic response and strength of very long floating structures by beam modeling on an elastic foundation; Dansei shishojo no hari model ni yoru chodai futai kozo no doteki tawami kyodo tokusei ni kansuru kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Tsubogo, T.; Okada, H. [University of Osaka Prefecture, Osaka (Japan). Faculty of Engineering

    1997-08-01

    A very large floating structure was replaced with the beam on an elastic foundation to examine the response characteristics in waves. Another evidence was regularly and numerically given for the basic characteristics of a very large floating body Suzuki found. New information was also obtained. The frequency response is mainly classified into a wave number control area and proper frequency control area when buoyancy elasticity exists. When the buoyancy structure is long and flexible, the proper frequency becomes continuous and the frequency control area becomes a resonance area. In the wave number control area, the Suzuki`s characteristic wave number becomes a control parameter, and various characteristic values are indicated by characteristic wave numbers. The response in the wave number control area becomes quasi-static when the distribution mass of buoyancy is fully small. The design in which the distribution mass of buoyancy is fully large must be avoided. In the displacement amplitude, the mass on the free end is severest. The proper frequency of vertical vibration relatively moves to the high-frequency side when buoyancy is considered as an elastic foundation. Attention must be thus paid to the proper frequency of vibration on the horizontal surface. 9 refs., 12 figs., 3 tabs.

  20. Model experiment on change of seismic properties of a fracture caused by injecting/draining water; Chusui/haisui ni yoru kison kiretsu no dansei denpa tokusei no henka ni kansuru model jikken

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, T.; Koizumi, T.; Sassa, K. [Kyoto University, Kyoto (Japan). Faculty of Engineering

    1997-05-27

    Effect of water injection/draining on elastic waves penetrating through cracks is examined by measuring elastic waves before, during, and after the injection/draining of water into/from cracks in presence in granite. Two blocks of rock, with their crack-containing surfaces in contact with each other, are placed in a vessel, and water injection/draining is done through a hole on a vessel bottom side so that water will penetrate into the cracks. When the blocks are dry, there is almost no contact between the cracks, and so no crack penetrating waves are observed. Crack penetrating waves are produced when water is injected, and the position of the receiver sensing the penetrating waves changes as the water level rises. When the water level is lowered from the high water level, the waveform changes again as the level changes. The change in waveform is not so remarkable, however, as that observed during water injection thanks to the water residual in the cracks. It is now inferred that crack investigation is more effective when it is carried out with water being injected into dry cracks. The difference produced between the dry state and wet state when water is injected into dry cracks is used to detect the presence of cracks in this experiment, and this may be applied also to the investigation of cracks in the shallow part of the ground. 4 refs., 11 figs.

  1. Atomic scale modelling of nanosize Ni sub 3 Al cluster beam deposition on Al, Ni and Ni sub 3 Al (1 1 1) surfaces

    CERN Document Server

    Kharlamov, V S; Hou, M

    2002-01-01

    The slowing down of Ni sub 3 Al clusters on a Al, Ni and Ni sub 3 Al (1 1 1) surfaces is studied by atomic scale modelling. The semi-grand canonical metropolis Monte Carlo is used for the preparation of isolated clusters at thermodynamic equilibrium. The cluster deposition on the surface is studied in detail by classical Molecular Dynamics simulations that include a model to account for electron-phonon coupling. Long- and short-range orders in the cluster are evaluated as functions of temperature in an impact energy range between 0 and 1.5 eV/atom. The interaction between the Ni sub 3 Al cluster and an Al surface is characterised low short range (chemical) disorder. No sizeable epitaxy is found, subsequent to the impact. In contrast, in the case of Ni and Ni sub 3 Al substrates, which are harder materials than aluminium, the chemical disorder is higher and epitaxial accommodation is possible. With these substrates, chemical disorder in the cluster is an increasing function of the impact energy, as well as of ...

  2. Achievement report for fiscal 1998 on area consortium research and development business, 1st year. Area consortium energy research and development (biofuel production by advanced function bioreactor); 1998 nendo chiiki consortium energy bun'ya. Kokino bio reactor ni yoru bio nenryo seisan ni kansuru kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Studies were made to produce ethanol directly from starch and cellulose and to collect biodiesel fuels from waste oil by an enzymatic method. For an increase in the yield of biodiesel fuel production, lipase enzymes were explored and optimum reaction conditions were sought for. Starch decomposition was quick for conversion into the target material in a system with the co-expression of amylase and glucoamylase present on the yeast cell surface layer. There was dramatically rapid progress in the increase of enzymatic activity in the cell, although dependent on cell membrane surface treatment conditions. In the generation of acetaminophen by recombinant cohesive yeasts, highly active and expressive yeasts were automatically fixed in the porous support (intelligent bioreactor) while those deactivated or dead were automatically removed. For the construction of a fuzzy control system for this reaction, basic models were investigated, built on the basis of the enzymatic model of reaction and substance balance. A high-precision structural analysis was conducted for the exploration of secondary structure stabilizing factors in protein and peptide and for the elucidation of correlations between structure and function. (NEDO)

  3. Model of Ni-63 battery with realistic PIN structure

    Energy Technology Data Exchange (ETDEWEB)

    Munson, Charles E.; Voss, Paul L.; Ougazzaden, Abdallah, E-mail: aougazza@georgiatech-metz.fr [Georgia Tech Lorraine, Georgia Tech-C.N.R.S., UMI2958, 2-3 rue Marconi, 57070 Metz (France); School of Electrical and Computer Engineering, Georgia Institute of Technology, 777 Atlantic Drive NW, 30332-0250 Atlanta (United States); Arif, Muhammad; Salvestrini, Jean-Paul [Georgia Tech Lorraine, Georgia Tech-C.N.R.S., UMI2958, 2-3 rue Marconi, 57070 Metz (France); Université de Lorraine, CentraleSupélec, LMOPS, EA 4423, 2 rue E. Belin, 57070 Metz (France); Streque, Jeremy; El Gmili, Youssef [Georgia Tech Lorraine, Georgia Tech-C.N.R.S., UMI2958, 2-3 rue Marconi, 57070 Metz (France); Belahsene, Sofiane; Martinez, Anthony; Ramdane, Abderrahim [Laboratory for Photonics and Nanostructures, CNRS, Route de Nozay, 91460 Marcoussis (France)

    2015-09-14

    GaN, with its wide bandgap of 3.4 eV, has emerged as an efficient material for designing high-efficiency betavoltaic batteries. An important part of designing efficient betavoltaic batteries involves a good understanding of the full process, from the behavior of the nuclear material and the creation of electron-hole pairs all the way through the collection of photo-generated carriers. This paper presents a detailed model based on Monte Carlo and Silvaco for a GaN-based betavoltaic battery device, modeled after Ni-63 as an energy source. The accuracy of the model is verified by comparing it with experimental values obtained for a GaN-based p-i-n structure under scanning electron microscope illumination.

  4. First-principles point defect models in Zr7Ni10 and Zr2Ni7 binary intermetallic compounds and their implications in nickel-metal hydride batteries

    Science.gov (United States)

    Wong, Diana F.

    Zr-Ni-based alloys as nickel-metal hydride battery anode materials offer low-cost, flexible and tunable battery performance. Zr7Ni 10 is an important secondary phase found in multi-phased AB2 Laves-phase-based metal hydride alloys, and the synergetic effect between the Zr-Ni and the Laves phases allows access to the high hydrogen storage of the Zr-Ni phases despite the lower absorption/desorption kinetics. Zr7Ni10 displays a small solubility window for Zr-rich compositions, while Zr2Ni7, with no solubility window, shows poor capacity with good kinetics. Stability of point defects within the crystal structure allows Zr7Ni10 to maintain the same structure at off-stoichiometric compositions, thus it is theorized that defects may play a role in the difference between the electrochemical behaviors in Zr7Ni10 and Zr2Ni7. Defect models in Zr7Ni10 and Zr2Ni7 compounds computed using a combination of density functional theory and statistical mechanics offer a starting point for understanding the possible roles that point defects have on the performance of Zr-Ni based active negative electrode materials in Ni/MH batteries. Theoretical vacancy and anti-site defect formation energies are calculated and reported for Zr-rich, Ni-rich, and stoichiometric compounds of Zr7Ni 10 and Zr2Ni7, and the implications of the defect models on nickel-metal hydride negative electrode active material design and performance are discussed.

  5. Noise characterization in SWD survey; SWD ni okeru noise ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Tsuru, T.; Ozawa, T. [Japan National Oil Corp., Tokyo (Japan)

    1998-02-01

    SWD (Seismic While Drilling) is located as one kind of the reverse VSP (Vertical Seismic Profiling) technology, and a working drill-bit is used as its energy-source. The SWD is carried out for a check-shot survey as well as a prediction ahead of the bit. The largest advantage of the SWD technology may be a prediction, while drilling, of a drilling hazard such as an abnormal pressure zone. On the other hand, a serious disadvantage exists in the data quality due to a contamination by large noises generated from a working rig, because the SWD survey is done `while drilling`. Regarding the characteristics of these noises, especially the noise received by surface geophones has not been clarified quantitatively yet. Through several field experiments, the authors have evaluated the characteristics. In this paper, the dominant frequency range of the surface geophone noise is discussed. Furthermore, the noise from the mud motor is also discussed. 9 refs., 13 figs.

  6. Dynamical Analysis of Sputtering at Threshold Energy Range: Modelling of Ar+Ni(100) Collision System

    Institute of Scientific and Technical Information of China (English)

    HUNDUR Yakup; G(U)VEN(C) Ziya B; HIPPLER Rainer

    2008-01-01

    The sputtering process of Ar+Ni(100) collision systems is investigated by means of constant energy molecular dynamics simulations.The Ni(100) slab is mimicked by an embedded-atom potential,and the interaction between the projectile and the surface is modelled by using the reparametrized ZBL potential.Ni atom emission from the lattice is analysed over the range of 20-50 eV collision energy.Sputtering yield,angular and energy distributions of the scattered Ar and of the sputtered Ni atoms are calculated,and compared to the available theoretical and experimental data.

  7. Modeling of deposition and clearance of inhaled Ni compounds in the human lung.

    Science.gov (United States)

    Hsieh, T H; Yu, C P; Oberdörster, G

    1999-08-01

    By extrapolation from the rat study, a mathematical model of deposition, clearance, and retention kinetics for inhaled Ni compounds (high-temperature (green) NiO, Ni(3)S(2), and NiSO(4). 6H(2)O) in the alveolar region of the human lung has been developed. For human deposition, an updated version of an earlier model (C. P. Yu and C. K. Diu, 1982, Am. Ind. Hyg. Assoc. J.) was used in this study. Because of the profound differences in physiological and ventilation conditions between humans and rats, humans were found to have a higher alveolar deposition fraction than rats when exposed to the same Ni compounds. However, when normalized to the lung weight, the deposition rate per gram of lung in humans is much smaller than in rats. In the development of a clearance model, a single-compartment model in the lung was used and a general assumption was made that the clearance of the insoluble and moderately soluble nickel compounds (high-temperature (green) NiO and Ni(3)S(2), respectively) depends highly on the volume of retained particles in the lungs. As for the highly soluble nickel compound (NiSO(4). 6H(2)O), the clearance rate coefficient was assumed to depend on the retained particle mass and total alveolar surface. These clearance rate coefficients were extrapolated from the rat data. The retention half-times for high temperature (green) NiO and Ni(3)S(2) particles in humans were found to be much longer than in rats, whereas the retention half-time for NiSO(4). 6H(2)O particles was about the same for both species. The lung burden results in humans for various exposure conditions are predicted and the equivalent exposure concentrations for humans which lead to the same lung burdens found in rats were calculated.

  8. Improving the Ni I atomic model for solar and stellar atmospheric models

    CERN Document Server

    Vieytes, Mariela C

    2013-01-01

    Neutral nickel (Ni I) is abundant in the solar atmosphere and is one of the important elements that contribute to the emission and absorption of radiation in the spectral range between 1900 and 3900 A. Previously, the Solar Radiation Physical Modeling (SRPM) models of the solar atmosphere considered only few levels of this species. Here we improve the Ni I atomic model by taking into account 61 levels and 490 spectral lines. We compute the populations of these levels in full NLTE using the SRPM code and compare the resulting emerging spectrum with observations. The present atomic model improves significantly the calculation of the solar spectral irradiance at near-UV wavelengths that are important for Earth atmo spheric studies, and particularly for ozone chemistry.

  9. Study on Reactive Adsorption Desulfurization of Model Gasoline on Ni/ZnO-HY Adsorbent

    Institute of Scientific and Technical Information of China (English)

    Huang Huan; Salissou M. Nour; Yi Dezhi; Meng Xuan; Shi Li

    2013-01-01

    The reactive adsorption desulfurization of model gasoline was carried out on Ni/ZnO-HY adsorbent. The Ni/ZnO-HY adsorbent was characterized by N2 adsorption-desorption test (BET), X-ray diffractometry (XRD), and tempera-ture-programmed reduction (TPR) analysis. The test results have demonstrated that HY-zeolite is a feasible support for Ni/ZnO components used in reactive adsorption desulfurization. The results of XRD and TPR analyses showed that most of nickel element was present as Ni2+species with only a small part existing as Ni3+species, and the Ni2+species had interac-tions with HY-zeolite. Under the conditions of this study, which speciifed a 50%ratio of HY-zeolite in the adsorbent, a Zn/Ni molar ratio of 10, and a reduction temperature of 400℃, the Ni/ZnO-HY adsorbent showed the best desulfurization per-formance. The sulfur capacity of Ni/ZnO-HY adsorbent could be recovered to 92.19%of the fresh one after being subjected to regeneration at 500℃, and could be maintained at 82.17%of the fresh one after 5 regeneration cycles.

  10. Simple stochastic dynamical models capturing the statistical diversity of El Niño Southern Oscillation

    Science.gov (United States)

    Chen, Nan; Majda, Andrew J.

    2017-01-01

    The El Niño Southern Oscillation (ENSO) has significant impact on global climate and seasonal prediction. A simple modeling framework is developed here that automatically captures the statistical diversity of ENSO. First, a stochastic parameterization of the wind bursts including both westerly and easterly winds is coupled to a simple ocean–atmosphere model that is otherwise deterministic, linear, and stable. Second, a simple nonlinear zonal advection with no ad hoc parameterization of the background sea-surface temperature (SST) gradient and a mean easterly trade wind anomaly representing the multidecadal acceleration of the trade wind are both incorporated into the coupled model that enables anomalous warm SST in the central Pacific. Then a three-state stochastic Markov jump process is used to drive the wind burst activity that depends on the strength of the western Pacific warm pool in a simple and effective fashion. It allows the coupled model to simulate the quasi-regular moderate traditional El Niño, the super El Niño, and the central Pacific (CP) El Niño as well as the La Niña with realistic features. In addition to the anomalous SST, the Walker circulation anomalies at different ENSO phases all resemble those in nature. In particular, the coupled model succeeds in reproducing the observed episode during the 1990s, where a series of 5-y CP El Niños is followed by a super El Niño and then a La Niña. Importantly, both the variance and the non-Gaussian statistical features in different Niño regions spanning from the western to the eastern Pacific are captured by the coupled model. PMID:28137886

  11. MODELING OF NI-CR-MO BASED ALLOYS: PART II - KINETICS

    Energy Technology Data Exchange (ETDEWEB)

    Turchi, P A; Kaufman, L; Liu, Z

    2006-07-07

    The CALPHAD approach is applied to kinetic studies of phase transformations and aging of prototypes of Ni-Cr-Mo-based alloys selected for waste disposal canisters in the Yucca Mountain Project (YMP). Based on a previous study on alloy stability for several candidate alloys, the thermodynamic driving forces together with a newly developed mobility database have been used to analyze diffusion-controlled transformations in these Ni-based alloys. Results on precipitation of the Ni{sub 2}Cr-ordered phase in Ni-Cr and Ni-Cr-Mo alloys, and of the complex P- and {delta}-phases in a surrogate of Alloy 22 are presented, and the output from the modeling are compared with experimental data on aging.

  12. Simple dynamical models capturing the key features of the Central Pacific El Niño.

    Science.gov (United States)

    Chen, Nan; Majda, Andrew J

    2016-10-18

    The Central Pacific El Niño (CP El Niño) has been frequently observed in recent decades. The phenomenon is characterized by an anomalous warm sea surface temperature (SST) confined to the central Pacific and has different teleconnections from the traditional El Niño. Here, simple models are developed and shown to capture the key mechanisms of the CP El Niño. The starting model involves coupled atmosphere-ocean processes that are deterministic, linear, and stable. Then, systematic strategies are developed for incorporating several major mechanisms of the CP El Niño into the coupled system. First, simple nonlinear zonal advection with no ad hoc parameterization of the background SST gradient is introduced that creates coupled nonlinear advective modes of the SST. Secondly, due to the recent multidecadal strengthening of the easterly trade wind, a stochastic parameterization of the wind bursts including a mean easterly trade wind anomaly is coupled to the simple atmosphere-ocean processes. Effective stochastic noise in the wind burst model facilitates the intermittent occurrence of the CP El Niño with realistic amplitude and duration. In addition to the anomalous warm SST in the central Pacific, other major features of the CP El Niño such as the rising branch of the anomalous Walker circulation being shifted to the central Pacific and the eastern Pacific cooling with a shallow thermocline are all captured by this simple coupled model. Importantly, the coupled model succeeds in simulating a series of CP El Niño that lasts for 5 y, which resembles the two CP El Niño episodes during 1990-1995 and 2002-2006.

  13. Ni adsorption and Ni-Al LDH precipitation in a sandy aquifer: An experimental and mechanistic modeling study

    NARCIS (Netherlands)

    Regelink, I.C.; Temminghoff, E.J.M.

    2011-01-01

    Mining activities and industries have created nickel (Ni) contaminations in many parts of the world. The objective of this study is to increase our understanding of Ni adsorption and Nickel-Aluminium Layered Double Hydroxide (Ni-Al LDH) precipitation to reduce Ni mobility in a sandy soil aquifer. At

  14. A novel square-planar Ni(II) complex with an amino-carboxamido-dithiolato-type ligand as an active-site model of NiSOD.

    Science.gov (United States)

    Nakane, Daisuke; Wasada-Tsutsui, Yuko; Funahashi, Yasuhiro; Hatanaka, Tsubasa; Ozawa, Tomohiro; Masuda, Hideki

    2014-07-07

    To understand the role of the unique equatorial coordination environment at the active center in nickel superoxide dismutase (NiSOD), we prepared a novel Ni(II) complex with an amino-carboxamido-dithiolato-type square-planar ligand (1, [Ni(2+)(L1)](-)) as a model of the NiSOD active site. Complex 1 has a low-spin square-planar structure in all solvents. Interestingly, the absorption wavelength and ν(C═O) stretching vibrations of 1 are affected by solvents. This provides an indication that the carbonyl oxygens participate in hydrogen-bonding interactions with solvents. These interactions are reflected in the redox potentials; the peak potential of an anodic wave (Epa) values of Ni(II)/Ni(III) waves for 1 are shifted to a positive region for solvents with higher acceptor numbers. This indicates that the disproportionation of superoxide anion by NiSOD may be regulated by hydrogen-bonding interactions between the carboxamido carbonyl and electrophilic molecules through fine-tuning of the redox potential for optimal SOD activity. Interestingly, the Epa value of the Ni(III)/Ni(II) couple in 1 in water (+0.303 V vs normal hydrogen electrode (NHE)) is similar to that of NiSOD (+0.290 V vs NHE). We also investigated the superoxide-reducing and -oxidizing reactions of 1. First, 1 reacts with superoxide to yield the superoxide-bound Ni(II) species (UV-vis: 425, 525, and ∼650 nm; electron paramagnetic resonance (EPR) (4 K): g// = 2.21, g⊥ = 2.01; resonance Raman: ν((16)O-(16)O)/ν((18)O-(18)O) = 1020/986 cm(-1)), which is then oxidized to Ni(III) state only in the presence of both a proton and 1-methylimidazole, as evidenced by EPR spectra. Second, EPR spectra indicate that the oxidized complex of 1 with 1-methylimidazole at the axial site can be reduced by reaction with superoxide. The Ni(III) complex with 1-methylimidazole at the axial site does not participate in any direct interaction with azide anion (pKa 4.65) added as mimic of superoxide (pKa 4.88). According to

  15. Thermodynamic Modeling of Ag-Ni System Combining Experiments and Molecular Dynamic Simulation

    Science.gov (United States)

    Rajkumar, V. B.; Chen, Sinn-wen

    2017-04-01

    Ag-Ni is a simple and important system with immiscible liquids and (Ag,Ni) phases. Previously, this system has been thermodynamically modeled utilizing certain thermochemical and phase equilibria information based on conjecture. An attempt is made in this study to determine the missing information which are difficult to measure experimentally. The boundaries of the liquid miscibility gap at high temperatures are determined using a pyrometer. The temperature of the liquid ⇌ (Ag) + (Ni) eutectic reaction is measured using differential thermal analysis. Tie-lines of the Ag-Ni system at 1023 K and 1473 K are measured using a conventional metallurgical method. The enthalpy of mixing of the liquid at 1773 K and the (Ag,Ni) at 973 K is calculated by molecular dynamics simulation using a large-scale atomic/molecular massively parallel simulator. These results along with literature information are used to model the Gibbs energy of the liquid and (Ag,Ni) by a calculation of phase diagrams approach, and the Ag-Ni phase diagram is then calculated.

  16. Trend survey of the global environment adaptation type industrial technology. Trend survey of global environment related studies (researches on measureds for reduction of environmental load of CO2); Chikyu kankyo tekiogata sangyo gijutsu doko chosa. Chikyu kankyo kanren kenkyu doko no chosa (nisanka tanso no kankyo fuka teigensaku ni kansuru chosa kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    1992-03-01

    The paper studies the measures for reduction of environmental load of CO2 from the standpoint of chemical technology. As for methanol synthesis from CO2, accelerating of the reaction using Cu base compound catalyst is reported. Also, CO2 is methanated at high speed by low temperature waste heat using Ni-La2O3-Ru catalyst. Discussions are given on the subject for development of catalyst reaction relating to hydrogen production technology by methane reforming reaction using steam or CO2. Synthesis of polymetric materials by use of CO2 is also described. The paper mentions that it is indispensable to design high-function electrode and elucidate the reaction mechanism of electrochemical CO2 reduction for electrochemical and photochemical CO2 reduction measures. Moreover, in case of using solar energy, it is required to study photovoltaic excitation process in semiconductor electrode/ electrolyte solution interface. For production of hydrogen from CO2 by photosynthetic organisms and solar energy, the problem is control of inhibiting effect of oxygen combinedly produced. Described are production of polyhydroxy butyric acid and biodegradable polymer from CO2 and hydrogen by bacteria, and CO2 fixation imitating the enzyme reaction. 267 refs., 79 figs., 32 tabs.

  17. Microstructure and properies of hot roll bonding layer of dissimilar metals. Part 2. Bonding interface microstrcuture of Zr/stainless steel by hot roll bonding and its controlling; Ishu kinzoku no atsuen setsugo kaimen soshiki to shotokusei ni kansuru kenkyu. 2. Jirukoniumu to sutenresu ko no netsukan atsuen kaimen to sono seigyo

    Energy Technology Data Exchange (ETDEWEB)

    Yasuyama, M.; Ogawa, K.; Taka, T.; Nasuji, K. [Sumitomo Metal Industries Ltd., Osaka (Japan); Nakao, Y.; Nishimoto, K. [Osaka Univ., Osaka (Japan)

    1996-07-25

    When using melt welding for bonding of Zr and stainless teel, it is well known that Zr, Fe, Cr and Ni reacts to form intermetallic compound and high bonding strength can not be obtained. And, on diffusion bonding of joint used as transition joint, it is reported that growth of the intermetallic compound is controlled and characteristics of the bonding is improved by inserting pure tantalum foil as a diffusion prevention wall, on foreign materials bonding of Zr and stainless steel due to metal systematic investigation. In this study, rolling bonding interface using three axes tilt type special rolling mill (rotary mill) was investigated metal-systematically. As a result, it was found that on executing bonding under optimum condition using rotary rolling method, and bonding interface of the foreign materials bonding such as Zr/Ta and Ta/SUS304L, sound foreign materials bonding without hardened layer due to deposition of intermetallic compound and solid solution and with sufficient bonding strength could be obtained. 7 refs., 17 figs., 2 tabs.

  18. Energetic Mapping of Ni Catalysts by Detailed Kinetic Modeling

    DEFF Research Database (Denmark)

    Bjørgum, Erlend; Chen, De; Bakken, Mari G.

    2005-01-01

    was found to be 119 kJ/mol, and the binding energy of C to the Ni(111) surface of the crystal was 703 kJ/mol. The supported catalysts consist of nickel supported on hydrotalcite-like compounds with three different Mg2+/Al3+ ratios. The experimental results show that for the supported Ni catalysts TPD of CO...... leads to desorption of both CO and CO2, with the latter being dominant. Dissociation of CO takes place, and considerable amounts of residue C are left on the surface. The residue C is removed by temperature-programmed oxidation (TPO). The results show that a low Mg2+/Al3+ ratio in the hydrotalcite...

  19. Synthetic Active Site Model of the [NiFeSe] Hydrogenase.

    Science.gov (United States)

    Wombwell, Claire; Reisner, Erwin

    2015-05-26

    A dinuclear synthetic model of the [NiFeSe] hydrogenase active site and a structural, spectroscopic and electrochemical analysis of this complex is reported. [NiFe('S2Se2')(CO)3] (H2'S2Se2' = 1,2-bis(2-thiabutyl-3,3-dimethyl-4-selenol)benzene) has been synthesized by reacting the nickel selenolate complex [Ni('S2Se2')] with [Fe(CO)3bda] (bda = benzylideneacetone). X-ray crystal structure analysis confirms that [NiFe('S2Se2')(CO)3] mimics the key structural features of the enzyme active site, including a doubly bridged heterobimetallic nickel and iron center with a selenolate terminally coordinated to the nickel center. Comparison of [NiFe('S2Se2')(CO)3] with the previously reported thiolate analogue [NiFe('S4')(CO)3] (H2'S4' = H2xbsms = 1,2-bis(4-mercapto-3,3-dimethyl-2-thiabutyl)benzene) showed that the selenolate groups in [NiFe('S2Se2')(CO)3] give lower carbonyl stretching frequencies in the IR spectrum. Electrochemical studies of [NiFe('S2Se2')(CO)3] and [NiFe('S4')(CO)3] demonstrated that both complexes do not operate as homogenous H2 evolution catalysts, but are precursors to a solid deposit on an electrode surface for H2 evolution catalysis in organic and aqueous solution. © 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

  20. Biosorption of Ni(II) by Fig Male: Optimization and Modeling Using a Full Factorial Design.

    Science.gov (United States)

    Madjene, F; Chergui, A; Trari, M

    2016-06-01

    The fig male (FM) is successfully used as biosorbent for Ni(2+) removal. The maximum removal efficiency (96.6%) is obtained at pH ~ 5 for a concentration of 1.70 mmol L(-1) and catalyst dose of 5 g L(-1) in less than 10 minutes. The Ni(2+) uptake follows a pseudo-second-order kinetic, the rate constants increase with increasing temperature, and an activation energy of 55.48 kJ mol(-1) is found. The thermodynamic parameters indicate a spontaneous endothermic bisorption. The isotherm data are fitted by the Langmuir and Dubinin-Radushkevich models. The former indicates a maximum Ni(2+) uptake of 0.459 mmol g(-1), which is higher than that of most biosorbents investigated to date. The FTIR spectra reveal the biosorption mechanism between Ni(2+) and FM functional groups. An empirical modeling is performed by using a 2(3) full factorial design, and a regression equation for Ni(2+) biosorption is determined. The biosorbent mass and pH are the most significant parameters affecting the Ni(2+) biosorption.

  1. Experimental determination and thermodynamic modeling of the Ni-Re binary system

    Energy Technology Data Exchange (ETDEWEB)

    Yaqoob, Khurram [Chimie Metallurgique des Terres Rares (CMTR), Institut de Chimie et des Materiaux Paris-Est (ICMPE), 2-8 rue Henri Dunant, 94320 Thiais Cedex (France); Joubert, Jean-Marc, E-mail: jean-marc.joubert@icmpe.cnrs.fr [Chimie Metallurgique des Terres Rares (CMTR), Institut de Chimie et des Materiaux Paris-Est (ICMPE), 2-8 rue Henri Dunant, 94320 Thiais Cedex (France)

    2012-12-15

    The phase diagram of the Ni-Re binary system has been partially reinvestigated by chemical, structural and thermal characterization of the arc melted alloys. The experimental results obtained during the present investigation were combined with the literature data and a new phase diagram of the Ni-Re binary system is proposed. In comparison with the Ni-Re phase diagram proposed by Nash et al. in 1985 [1], significant differences in the homogeneity domains, freezing ranges and peritectic reaction temperature were evidenced. On the other hand, thermodynamic modeling of the studied system by using the new experimental information has also been carried out with the help of the CALPHAD method. The calculated Ni-Re phase diagram showed a good agreement with the selected experimental information. - Graphical abstract: Ni-Re phase diagram according to the present study. Highlights: Black-Right-Pointing-Pointer Re-investigation of the Ni-Re phase diagram. Black-Right-Pointing-Pointer Extended phase field of the hcp phase. Black-Right-Pointing-Pointer Different freezing ranges and peritectic reaction temperature. Black-Right-Pointing-Pointer Thermodynamic modeling of the studied system by using the CALPHAD method.

  2. Quantitative evaluation of difference in impact of grounding accident on zero-phase voltage and zero-phase current in 6kV distribution system. Results of EMTP simulation; 6kV haiden keito deno chiraku jiko yoso no reiso den`atsu, reiso denryuha eno eikyo ni kansuru teiryoteki hyoka. EMTP (Electro Magnetic Transients Program) simulation kekka

    Energy Technology Data Exchange (ETDEWEB)

    Nagai, K. [Kansai Electric Power Co. Inc., Osaka (Japan)

    1997-10-10

    EMTP (electromagnetic transients program) analysis using accident spot models is conducted to disclose the different effect exerted on the zero-phase voltage and zero-phase current by different grounding accidents. An accident spot producing a near-delta waveform is represented by an equivalent circuit model No. 1 in which a switch simulating a discharge gap and the accident spot resistance are connected in series. In the case of an accident presenting a near-needle waveform, since it is supposed that the discharge is caused to be intermittent because the gap discharge start voltage is high and the accident spot resistance is low, it is presented by an equivalent circuit similar in configuration to model No. 1 with the constants altered. A leak-suggesting waveform with a current flowing even in the neighborhood of the zero cross point is represented by model No. 1 with a leak resistor added in parallel thereto, which circuit is shown as model No. 2. In the accidents represented by model No. 1, zero-phase current waveforms are grouped into three types, and the relations between the switch on-off circuit/grounding resistance and waveform configuration are disclosed. As for the accidents represented by model No. 2, it is found that the leak resistance values fall somewhere in the 200-2000 ohm range. 2 refs., 6 figs., 2 tabs.

  3. Simulation of Ni-MH Batteries via an Equivalent Circuit Model for Energy Storage Applications

    Directory of Open Access Journals (Sweden)

    Ying Zhu

    2016-01-01

    Full Text Available Impedance measurement was conducted at the entire cell level for studying of the Ni-MH rechargeable batteries. An improved equivalent circuit model considering diffusion process is proposed for simulation of battery impedance data at different charge input levels. The cell capacity decay was diagnosed by analyzing the ohmic resistance, activation resistance, and mass transfer resistance of the Ni-MH cells with degraded capacity. The capacity deterioration of this type, Ni-MH cell, is considered in relation to the change of activation resistance of the nickel positive electrodes. Based on the report and surface analysis obtained from the energy dispersive X-ray spectroscopy, the composition formula of metal-hydride electrodes can be closely documented as the AB5 type alloy and the “A” elements are recognized as lanthanum (La and cerium (Ce. The capacity decay of the Ni-MH cell is potentially initiated due to starved electrolyte for the electrochemical reaction of active materials inside the Ni-MH battery, and the discharge product of Ni(OH2 at low state-of-charge level is anticipated to have more impeding effects on electrode kinetic process for higher power output and efficient energy delivery.

  4. A coupled model between hydrogen diffusion and mechanical behavior of superelastic NiTi alloys

    Science.gov (United States)

    Elkhal Letaief, W.; Hassine, T.; Gamaoun, F.

    2017-07-01

    The undesirable effects of hydrogen show significant alterations to the thermomechanical behavior of superelastic NiTi shape memory alloys. Through experimental results, the presence of hydrogen induces a delay of forward transformation. Added to that, hydrogen-induced expansion is clearly noticed. We also remark a loss of superelasticity. These effects occur according to the hydrogen absorption by the NiTi alloy. The aim of this paper is to develop a coupled diffusion-mechanical model of shape memory alloys, which regards the aforesaid effects of hydrogen on the thermomechanical behavior and the transformation mechanism of NiTi alloys. The model is derived from the relationship between the chemical potential of hydrogen and the thermodynamics laws. Furthermore, we introduce a special transformation hardening function that predicts stress-strain behavior well during the transformation plateau. The model is implemented in ABAQUS finite element analysis software through the UMAT and UMATHT subroutines. The simulation results present good concordance with the experiments.

  5. Basic studies on design supporting system of offshore structure. Part 2. Implementation of structural design supporting system of offshore structures; Kaiyo kozobutsu wo taisho to shita sekkei shien system ni kansuru kisoteki kenkyu. 2. Kaiyo kozobutsu no kozo sekkei shien system no kochiku

    Energy Technology Data Exchange (ETDEWEB)

    Nomoto, T.; Hamada, K.; Aoyama, K. [The University of Tokyo, Tokyo (Japan)

    1996-12-31

    In order to improve the existing design-supporting system for offshore structures, new functions are added to evaluate information of the products, especially those for structural designs. The structural analysis system should be provided with a function of design modification, to efficiently support the structural analysis of these structures. The new system adds hierarchy of various offshore structure models and three-dimensional dimensions to clarify structural and geometrical constraints and design-modification function. The design-modification function is included by use of the hierarchy. The other new functions are finite element analysis systems for the main structure and components, and rigidity calculation for the main structure. The main structure and functional element models are confirmed to be useful also for utilization of information, and provide necessary information of the product models. 11 refs., 11 figs.

  6. Survey/research on application of expert system to electric power technology. Part 1. ; Protoypical preparation of accident section discrimination system by personal computer edition. Expert system no denryoku gijutsu eno tekiyo ni kansuru chosater dot kenkyu (1). ; Keito jiko kukan hantei system (pasokon ban) no shisaku

    Energy Technology Data Exchange (ETDEWEB)

    Sugihara, H. (The Chugoku Electric Power Co. Inc., Hiroshima (Japan))

    1991-03-20

    As the first step in the prototypical preparation of system accident recovery support system'', in order to support the accident phenomenon comprehension and recovery operation, to be done by the operators at the time of accident occurrence in the electric power system, accident section discrimination system by personal computer edition'' was prototypically prepared for the purpose of discussing the knowledge expression and inference method. That system is, at the time of system accident occurrence, to discriminate the accident section from the information of operated protective relay and tripped circuit breaker, and was structured of objective system model and about 100 production rules (knowledge under a form of if {yields} then''). As the rule was made not to depend upon a proper system, change in system structure and protection system can be corresponded to by change in objective system model only. Correct conclusion was obtained in 1 to 10 minutes, as a result of demonstration, made in about 50 cases of supposed accident, using a control system (12 buses, 2 power source buses, 12 power transmission circuits and 26 circuit breakers), based on the system in Takehara control station. 9 refs., 25 figs., 2 tabs.

  7. Consideration on the dynamic behavior and the structural design of large scale floating structure. 2nd Report. Stability of elastic structure and design of elastic response; Choogata futai no kozo kyodo oyobi kozo sekkei ni kansuru kosatsu. 2. Dansei henkei wo koryoshita fukugensei oyobi kozo oto no sekkei

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, H.; Yoshida, K. [The University of Tokyo, Tokyo (Japan)

    1996-12-31

    A policy of improving a very large floating body was planned based on its dynamic characteristics, and a proposal was made thereon. Furthermore, discussions were given on stability that considers effect of elastic deformation required when a structure is mounted on a floating body. With respect to a structural design of a very large floating body in which elastic response is governing, and upon modeling the very large floating body into an aeolotropic plate on an elastic supporting floor, it was shown that the existing range of natural vibration speed in the elastic response is in higher range than the natural vibration speed of heave. It was also indicated that the peak height of response to waves in resonance is inversely proportional to wave frequency, and furthermore, degree of flowing in of vibration energy during the resonance is determined by an inner product of spatial vibration patterns of wave force and the excited mode shape. A proposal was made on a floating body improved of excessive response in the floating body edges by changing the characteristics of the floating body edges. In addition, discussions were given on stability that considers elastic deformation of a floating body that becomes necessary when a structure, such as a building, is built on a very large floating body. 9 refs., 9 figs., 3 tabs.

  8. Fiscal 1997 survey report. Subtask 7 (hydrogen utilization worldwide clean energy system technology) (WE-NET) (survey/study on the hydrogen utilization technology); 1997 nendo seika hokokusho. Suiso riyo kokusai clean energy system gijutsu (WE-NET) subtask 7 suiso riyo gijutsu ni kansuru chosa kento

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper described the 1997 results of the survey/study of the hydrogen utilization technology. As to the power generation system, trially calculated were effects of oxygen purity on efficiency of the argon circulating hydrogen diesel cogeneration, and the power generating efficiency in case of considering power separating oxygen from air. It was found that the power generating efficiency equal to or more than that of the existing diesel can be expected. In relation to means of transportation, the introduction was studied of hydrogen engine family cars and hybrid fuel cell micro-buses. Concerning oxygen/hydrogen use fuel cells, discussed was the power generation using fuel cells by night power use electrolytic hydrogen/oxygen production as well as fixed 200kw and 5000kw class fuel cells and three automobile use polymer fuel cells. As to the hydrogen supply system in model cities, studied were the control of boil-off gas generation and the effective use of the gas, the hydrogen receiving base, and a scenario for shifting to hydrogen energy systems. For a realistic shift to the hydrogen energy society, discussed was a standalone hydrogen supply station. 24 refs., 130 figs., 57 tabs.

  9. High-Level Modeling of Multimodal Interaction Techniques Using NiMMiT

    Directory of Open Access Journals (Sweden)

    Chris Raymaekers

    2007-09-01

    Full Text Available The past few years, multimodal interaction has been gaining importance in virtual environments. Although multimodality renders interacting with an environment more natural and intuitive, the development cycle of such an application is often long and expensive. In our overall field of research, we investigate how model-based design can facilitate the development process by designing environments through the use of high-level diagrams. In this scope, we present ‘NiMMiT′, a graphical notation for expressing and evaluating multimodal user interaction; we elaborate on the NiMMiT primitives and demonstrate its use by means of a comprehensive example.

  10. Modeling of Ni Diffusion Induced Austenite Formation in Ferritic Stainless Steel Interconnects

    DEFF Research Database (Denmark)

    Chen, Ming; Molin, Sebastian; Zhang, L.

    2015-01-01

    Ferritic stainless steel interconnect plates are widely used in planar solid oxide fuel cell (SOFC) or electrolysis cell (SOEC) stacks. During stack production and operation, nickel from the Ni/YSZ fuel electrode or from the Ni contact component diffuses into the IC plate, causing transformation...... of the ferritic phase into an austenitic phase in the interface region. This is accompanied with changes in volume and in mechanical and corrosion properties of the IC plates. In this work, kinetic modeling of the inter-diffusion between Ni and FeCr based ferritic stainless steel was conducted, using the CALPHAD...... approach with the DICTRA software. The kinetics of inter-diffusion and austenite formation was explored in full detail, as functions of layer thickness, temperature, time, and steel composition. The simulation was further validated by comparing with experimental results. Growth of the austenite phase...

  11. Thermodynamic Modeling of Poorly Complexing Metals in Concentrated Electrolyte Solutions: An X-Ray Absorption and UV-Vis Spectroscopic Study of Ni(II) in the NiCl2-MgCl2-H2O System

    Science.gov (United States)

    Zhang, Ning; Brugger, Joël; Etschmann, Barbara; Ngothai, Yung; Zeng, Dewen

    2015-01-01

    Knowledge of the structure and speciation of aqueous Ni(II)-chloride complexes is important for understanding Ni behavior in hydrometallurgical extraction. The effect of concentration on the first-shell structure of Ni(II) in aqueous NiCl2 and NiCl2-MgCl2 solutions was investigated by Ni K edge X-ray absorption (XAS) and UV-Vis spectroscopy at ambient conditions. Both techniques show that no large structural change (e.g., transition from octahedral to tetrahedral-like configuration) occurs. Both methods confirm that the Ni(II) aqua ion (with six coordinated water molecules at RNi-O = 2.07(2) Å) is the dominant species over the whole NiCl2 concentration range. However, XANES, EXAFS and UV-Vis data show subtle changes at high salinity (> 2 mol∙kg-1 NiCl2), which are consistent with the formation of small amounts of the NiCl+ complex (up to 0.44(23) Cl at a Ni-Cl distance of 2.35(2) Å in 5.05 mol∙kg-1 NiCl2) in the pure NiCl2 solutions. At high Cl:Ni ratio in the NiCl2-MgCl2-H2O solutions, small amounts of [NiCl2]0 are also present. We developed a speciation-based mixed-solvent electrolyte (MSE) model to describe activity-composition relationships in NiCl2-MgCl2-H2O solutions, and at the same time predict Ni(II) speciation that is consistent with our XAS and UV-Vis data and with existing literature data up to the solubility limit, resolving a long-standing uncertainty about the role of chloride complexing in this system. PMID:25885410

  12. Hot DA white dwarf model atmosphere calculations: Including improved Ni PI cross sections

    CERN Document Server

    Preval, S P; Badnell, N R; Hubeny, I; Holberg, J B

    2016-01-01

    To calculate realistic models of objects with Ni in their atmospheres, accurate atomic data for the relevant ionization stages needs to be included in model atmosphere calculations. In the context of white dwarf stars, we investigate the effect of changing the Ni {\\sc iv}-{\\sc vi} bound-bound and bound-free atomic data has on model atmosphere calculations. Models including PICS calculated with {\\sc autostructure} show significant flux attenuation of up to $\\sim 80$\\% shortward of 180\\AA\\, in the EUV region compared to a model using hydrogenic PICS. Comparatively, models including a larger set of Ni transitions left the EUV, UV, and optical continua unaffected. We use models calculated with permutations of this atomic data to test for potential changes to measured metal abundances of the hot DA white dwarf G191-B2B. Models including {\\sc autostructure} PICS were found to change the abundances of N and O by as much as $\\sim 22$\\% compared to models using hydrogenic PICS, but heavier species were relatively unaf...

  13. Survey and research on precision polymerization polymeric materials; Seimitsu jugo kobunshi zairyo ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Survey and research on the precision control of primary structure of polymeric materials and the precision evaluation technology have been conducted to develop advanced polymeric materials. It is proposed that the three basic processes of polymer synthesis, i.e., addition, condensation, and biomimesis, in forming the precision polymerization skeleton are to be covered through a centralized joint research effort with participation of industry, academia, and the government institute and under the leadership of researchers from academic institutions as the team leaders. For the study of technology trends, international conferences held in UK, Germany, and Hawaii are introduced, and domestic meetings, i.e., Annual Polymer Congress and Polymer Conference, are summarized. In addition, Precision Polymerization Forum and International Workshop on Precision Polymerization were held. The basic studies include a quantum-chemical elucidation of the elementary process in polymerization reaction, time-resolved analysis of polymerization process and polymer properties, synthesis of polymers with controlled microstructures by coordination polymerization using metal complexes, synthesis of polymer with controlled microstructures by precision polycondensation, molecular recognition in catalyst-reaction site, and synthesis of imprinting polymers. 246 refs., 117 figs., 14 tabs.

  14. Research study on harmonized molecular materials (HMM); Bunshi kyocho zairyo ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    As functional material to satisfy various needs for environmental harmonization and efficient conversion for information-oriented and aging societies, HMM were surveyed. Living bodies effectively carry out transmission/processing of information, and transport/conversion of substances, and these functions are based on harmonization between organic molecules, and between those and metal or inorganic ones. HMM is a key substance to artificially realize these bio-related functions. Its R & D aims at (1) Making a breakthrough in production process based on innovation of material separation/conversion technology, (2) Contribution to an information-oriented society by high-efficiency devices, and (3) Growth of a functional bio-material industry. HMM is classified into three categories: (1) Assembly materials such as organic ultra-thin films (LB film, self-organizing film), and organic/inorganic hybrid materials for optoelectronics, sensors and devices, (2) Mesophase materials such as functional separation membrane and photo-conductive material, and (3) Microporous materials such as synthetic catalyst using guest/host materials. 571 refs., 88 figs., 21 tabs.

  15. Study on development of adsorbent of acetaldehyde; Acetaldehyde yo kyuchakuzai no kaihatsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Noda, T. [Nippon Steel Corp., Tokyo (Japan); Suzuki, M. [The University of Tokyo, Tokyo (Japan). Institute of Industrial Science

    1997-07-10

    The adsorption of acetaldehyde by porous ceramics impregnated with hydrazinium aluminum sulfate (HAS) is studied. Silicagel, activated alumina, activated clay, and activated carbon are compared, and it is found that silicagel and activated clay are suitable as a substrate for HAS impregnated adsorbent. The adsorption mechanism of acetaldehyde by the adsorbent is believed to be one in which acetaldehyde reacts with hydrazinium and yields acetaldazine. The adsorption capacity of the adsorbent at low acetaldehyde concentration of 0.1 ppm was as large as 1.36 mol/kg. This adsorption capacity at 0.1 ppm acetaldehyde concentration is remarkably larger than that of conventional activated carbon. Hydrazinium decomposes easily in the air because it is a strong reducing agent and reacts with oxygen or carbon dioxide. But hydrazinium impregnated on porous ceramics with HAS becomes more stable and maintains reactivity with acetaldehyde for longer than six months. An adsorbent made of porous ceramics impregnated with HAS is useful as a deodorant for acetaldehyde. 8 refs., 6 figs., 6 tabs.

  16. Survey on commercial use of fuel cells; Nenryo denchi ni kansuru jitsuyoka no tame no chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The basic survey was carried out for the future approach to R & D of fuel cells. Phosphoric acid fuel cell (PAFC) is in the stage of demonstration research and field test supported by subsidy after the end of Sunshine project. Its reliability and durability problems are being solved, and its cost reduction is only one problem for practical use. Distributed systems or on-site systems will be used utilizing its excellent environmental characteristics. Molten carbonate fuel cell (MCFC), solid oxide one (SOFC) and polymer electrolyte one (PEFC) under development were thus surveyed. The following are surveyed: (1) Contribution to a human society such as improvement of energy demand/supply structure and environmental protection, (2) Technological items such as outlook for R & D, validity of developmental issues, comparison between various R & D and significance in industrial promotion, (3) Economic items such as profitability and feasible period, and (4) Social items such as sociability, compatibility to needs, possibility of locations, international meaning, market scale and promotion scenario. 90 refs., 67 figs., 96 tabs.

  17. Recent surveys and researches on pollinosis in Japan; Kafunsho ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Shido, T. [The Inst. of Public Health, Tokyo (Japan)

    1998-05-31

    In this paper, recent investigations and researches on pollinosis are summarized as centering on the investigation entrusted by the Ministry of Health and Welfare and executed since 1992, and especially the surveys on Japanese cedar pollinosis during 1995 to 1996. The quantity of pollen surveyed in 1995 is the greatest in the survey history of nationwide flying pollen. Particularly, the quantity of cedar and hinoki pollen is 10 to 40 times as many as that in the year before. Consequently, since the sensitization and onset due to the cedar pollen increased greatly, the objects of the surveys and the researches were mainly in respect to the analysis of onset factors of pollinosis, clarification of its natural process, evaluation on the effectiveness of desensitization therapy, the clinical subjects including the confirmation of pharynx symptom and asthma symptom, and the discovery of naturally sensitizing dog. A fact that the quantity of flying pollen concerns the occurrence and degree of the clinical symptom has already been indicated by a clinical observation carried out for a long period of time. In respect to specific prophylaxis and therapy, for the first time the pollen masks and glasses sold on the market are investigated, and the necessity of the verification thereof is described. 27 refs., 7 figs., 5 tabs.

  18. Carbon dioxide fixation in green plants; Shokubutsu no tansan gas kotei ni kansuru kiso kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Onishi, S. [Kansai Electric Power Co. Inc., Osaka (Japan); Kiyota, M. [University of Osaka Prefecture, Osaka (Japan); Nishimura, M. [Kansai Tech Co., Osaka (Japan)

    1997-09-30

    Concerning the effects of carbon dioxide whose level of concentration is on the rise, the short-term effect that works on the amount of exchanged gas and the long-term effect that works on the growth of green plants are studied by use of several kinds of green plants. Changes in the carbon dioxide absorption rate (photosynthetic rate) in saplings in the wake of a rise in carbon dioxide concentration are studied, and it is found that a rise in carbon dioxide concentration results in an increase in the photosynthetic rate and that the rate rises with an increase in the intensity of light. The effect of temperature is stronger when concentration is higher, with the temperature suitable for photosynthesis moving toward the high-temperature side. Growth is investigated of seedlings of Acacia mangium two years after transplantation, and then it is found that seedlings in the 1000ppm carbon dioxide section are greater by 20% in height and by 30% in trunk diameter than those in the 350ppm carbon dioxide section. In addition, the total dry matter weight is heavier by 82%. As for dry matter accumulation, there are noticeable amounts in the branches, trunks, and roots, while there is but a 15% increase in the leaf area. Leaves fall early in the high carbon dioxide environment, and this is supposedly the cause for a slowdown in the rate of the increase of photosynthesis. 6 refs., 7 figs., 2 tabs.

  19. Catalytic activity of pyrite for coal liquefaction reaction; Tennen pyrite no shokubai seino ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Hirano, K.; Kozu, M.; Okada, T.; Kobayashi, M. [Nippon Coal Oil Co. Ltd., Tokyo (Japan)

    1996-10-28

    Since natural pyrite is easy to obtain and cheap as coal liquefaction catalyst, it is to be used for the 150 t/d scale NEDOL process bituminous coal liquefaction pilot plant. NEDO and NCOL have investigated the improvement of catalytic activity of pulverized natural pyrite for enhancing performance and economy of the NEDOL process. In this study, coal liquefaction tests were conducted using natural pyrite catalyst pulverized by dry-type bowl mill under nitrogen atmosphere. Mechanism of catalytic reaction of the natural pyrite was discussed from relations between properties of the catalyst and liquefaction product. The natural pyrite provided an activity to transfer gaseous hydrogen into the liquefaction product. It was considered that pulverized pyrite promotes the hydrogenation reaction of asphaltene because pulverization increases its contact rate with reactant and the amount of active points on its surface. It was inferred that catalytic activity of pyrite is affected greatly by the chemical state of Fe and S on its surface. 3 refs., 4 figs., 1 tab.

  20. Studies of coal slurries property; Slurry no seijo ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Kawabata, M.; Aihara, Y.; Imada, K. [Nippon Steel Corp., Tokyo (Japan); Nogami, Y.; Inokuchi, K. [Mitsui SRC Development Co. Ltd., Tokyo (Japan); Sakaki, T.; Shibata, M.; Hirosue, H. [Kyushu National Industrial Research Institute, Saga (Japan)

    1996-10-28

    It was previously found that the increase of slurry temperature provides a significant effect of slurry viscosity reduction for the coal slurry with high concentration of 50 wt%. To investigate the detailed influence of slurry temperature for the coal slurry with concentration of 50 wt%, influence of temperature on the successive change of apparent viscosity was observed at the constant shear rate. When the concentration of coal was increased from 45 wt% to 50 wt%, viscosity of the slurry was rapidly increased. When heated above 70{degree}C, the apparent viscosity decreased during heating to the given temperature, but it increased successively after reaching to the given temperature. The apparent viscosity showed higher value than that of the initial viscosity. The coal slurry with concentration of 50 wt% showed the fluidity of Newtonian fluid at the lower shear rate region, but showed the fluidity of pseudo-plastic fluid at the higher shear rate region. The slurry having high apparent viscosity by the successive change showed higher apparent viscosity with increasing the higher even by changing the shear rate. 1 ref., 4 figs.

  1. Runoff load of pesticides on golflinks; Golf jo shiyo noyaku no ryushutsu ni kansuru tokeiteki kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Natsume, S.; Inoue, T.; Ito, H. [Hokkaido Institute of Environmental Science, Sapporo (Japan)

    1994-12-01

    The runoff load of water exhausted from the golflinks was surveyed to obtain the data to standardize the water environmental assessment against the pesticide exhausted from the golflinks. The exhausted water was qualitatively and quantitatively measured every week during three years from fiscal 1990 through 1992. The survey was based on the sprinkled quantity of pesticide and amount of rainfall which were both recorded every day. The golflinks are divided into two catchment areas. The measurement was made at the spot (h) of pondage water flow in the catchment area having a pondage reservoir and at the spot (m) of fluvial water flow together with the catchment area having no pondage reservoir. In the analysis, the sprinkled quantity of pesticide and amount of rainfall were both accumulated, for each runoff load of the catchment areas, during 14 days retroactively from the time of survey, and then analyzed, by multiple regression, relatively to their corresponding runoff load. As a result, the runoff load was known to be mostly correlative to the amount of rainfall during the same day but independent of the sprinkling method of pesticide. The long-term runoff behavior of pesticide due to the rainfall was shown to be macroscopically expressible by regression formula. 7 refs., 15 figs., 1 tab.

  2. Investigation research on autonomous responsive materials; Jiritsu oto zairyo ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    A survey was made on autonomous responsive materials as a new material which reversibly change molecular structures and the aggregation state according to external stimuli. Autonomous responsive materials imitate environmental responsibility in the living organism system and have sensing, control and active functions for external stimuli. The materials are highly efficient and environmentally friendly. In biomimetic materials for soft actuators, drastic changes by temperature of elastic modulus of water-swollen hydrogel are used to the motion. In order to molecularly design stimulus-responsible polymer gel, studied are the relation between the micro structure and stimulus responsibility, dynamic correlation between the micro structure and the macro structure, etc. In the biomedical field, new cure and diagnosis using innovative materials are expected, and the application of autonomous responsive materials to the field is studied. For example, using hydrogel responding the temperature and the surface and controlling by temperature the interaction with components of the organism such as protein and cells, drug delivery in the organism is optimized. Also studied is the application of hydrophilic/hydrophobic changes by temperature to the chromatography. 215 refs., 47 figs., 11 tabs.

  3. Development of an airborne asbestos monitoring system. Taiki kankyo no asbesto monitoring ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Takatsuki, H.; Sakai, S.; terazono, A. (Kyoto Univ., Kyoto (Japan). Environment Preservation Center)

    1991-07-10

    In order to develop an airborne asbestos monitoring system, the efficiency of FAM (fibrous aerosol monitor) was evaluated in which the scattered light due to vibration of fibrous particles is detected by applying He-Ne laser to the particles after vibration was induced in them by high voltage quadrupole electrodes. As compared with the data concurrently obtained by phase contrast microscope (PCM) and transmission electron microscope (TEM), no correlation of an asbestos concentration was observed between FAM and PCM in low concentration environment, however, FAM offered comparatively reliable results in high concentration environment. As an asbestos concentration was measured with time by FAM around a duct outlet during removal of sprayed-on asbestos, FAM responded instantaneously to emergent emission of a large amount of asbestos in the event of dust collector failure for example. FAM was thus useful for monitoring asbestos leakage. 8 refs., 6 figs., 3 tabs.

  4. Relationship between stacking process and resolution; Jugo shori to bunkaino ni kansuru kiso kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Matsushima, J.; Rokugawa, S.; Kato, Y. [Geological Survey of Japan, Tsukuba (Japan); Yokota, T.; Miyazaki, T. [The University of Tokyo, Tokyo (Japan). Faculty of Engineering

    1996-10-01

    This paper evaluates influences of stacking of incident angles against the reflecting surface on the resolution. Basic equations for evaluating the influences were deduced. A simple evaluation method has been provided using these equations. The present evaluation method is considered to be useful for acquisition design, processing, and interpretation of data as an indicator. According to the equations introduced in this study, there are some demerits for stacking traces whose incident angles were large. A total reflection region often appears due to the decreased resolution, and the vertical resolution decreases prior to stacking. Occasionally, it is not effective to remove traces having large incident angles from the viewpoint of resolution. In practice, the selection of most suitable trace through trial and error is not easy due to difference in individual regions. An evaluation method must be discussed, by which the optimal trace can be selected automatically during the data processing. 6 refs., 15 figs.

  5. Investigation on food sanitation controlling technologies; Shokuhin eisei kanri gijutsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    Doi, Y. [Hokkaido Electric Power Co. Inc., Sapporo (Japan); Nishioka, J.

    2000-03-24

    Investigation has been made on the current status of food sanitation controlling technologies. Eighty percent of food poisoning is caused by bacte such as Salmonera, enteritis vibrio, staphylococcus, and pathogenic colibacillus. Putrefaction as the cause for food poisoning occurs from proliferation of different microorganisms. Heating sterilization is the main method being performed, but non-heating method may include sterilization by flash and high voltage pulse discharge in addition to ultra-high pressure and ultraviolet ray sterilization. As a result of the questionnaire survey, what is extracted as the problems in the food sanitation controlling technologies is to establish a rinsing and sterilizing method with large sterilization effect, an effective sterilizing method and thawing of processed marine products, and a cooling method in food processing. Increasingly demanded for the future is to develop a foodstuff sanitation control system using as the core the hazard analysis critical control point (HACCP, a quality control program developed by the U.S. NASA to ensure safety in manufacturing space food), and micro-organism control and sterilizing technologies to support the above system. The flash pulse and high-voltage pulse sterilizing technologies as the non-heating sterilizing technology are more effective than the conventional heating sterilization methods also from the aspect of quality retention after sterilization. More active development thereof is desired. (NEDO)

  6. Study of odor inside cars; Kuruma no nioi ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Sato, S.; Ito, H.; Sakakibara, K.; Kaitani, K.; Hamada, C. [Toyota Central Research and Development Labs., Inc., Aichi (Japan); Matsuo, M. [Toyota Motor Corp., Aichi (Japan)

    1998-05-01

    This paper describes odor in automotive cabin. Odor of new cars is rapidly disappeared during the use. This is greatly due to the adaptation of olfaction. The generation of odor is also decreased. It was found that aliphatic and aromatic hydrocarbons were rapidly disappeared. Decrements of oxygen containing and sulfur compounds were low. For amines, high boiling amines increased after three months. The odor component from crews was derived from the exhalation. Trimethylamine, methyl sulfide as well as iso-prene were detected. They could be derived from tobacco smoke, perfume and hair conditioner. Exhaust gas of diesel vehicle going ahead is one of unpleasant odors from the running atmosphere. A correlation coefficient 0.77 was obtained between the stimulation and aldehyde/ketone. A correlation equation was deduced using stimulation, discomfort degree and odor characteristics as object variables and using logarithms of trace analysis values as explanation variables. There are still a lot of unknown issues concerning combined odors. 9 refs., 9 figs., 1 tab.

  7. Medical chemical engineering the research; Iyo kagaku kogaku ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Sakai, Kiyotaka [Waseda University, Tokyo (Japan)

    1999-03-05

    He taking the chemical-engineering technique as a weapon, it participates in research and education over the perennial in the field of medical chemical engineering, medical engineering, bioengineering, and the excellent research result has been raised. Moreover, leading research result is raised in these research field which are the interdisciplinary field between medicine and chemical engineering, and the considerable contribution in these fields has been done. He enables the new development of the dialysis technology by advancing the research first of all from the viewpoint of hemodialysis film, hemodialyzer and three of the patient pharmacokinetics, in respect of dialysis technology in the artificial kidney, and developing the original dialysis system enables optimum dialysis treatment. Next, he on the oxygen which is the feed which is the most important for the organism, it originally crosses, and the gas is run in figuring hollow yarn lattice in the hollow yarn inside, and it is clarified that the system for washing the blood outside is advantageous, and it has succeeded in the development of the more efficient artificial lung. And, the artificial gill is examined from the original idea, which takes in the oxygen by using of a film in the oxygen carrier (the substitution blood), as intermediary. Next, he some of the phenomenon in the blood plasma viscosity of patient with renal failure or are measured and the relationship between blood plasma viscosity and disease state is clarified, and the knowledge which is useful for the diagnosis has been obtained. And, it is examined that the quantity that the hydrophobic drug is adsorbed in the albumin differs in normal subject and dialysis patient, and the system for deciding chemical administration quantity to the dialysis patient is being found. Next, in research progress of the above, various measuring technique are devised, and remarkably the research advances. For example, the considerable contribution for measurement of diffuse transmission coefficient of hollow yarn dialysis membrane by the optical measurement technology, glucose using the electrochemiluminescence and immunisation center, this advance on development of the continuous measurement method of the endotoxin, etc. of the research of the direction more and more has been done. In the interdisciplinary field of medical chemical engineering and biochemistry engineering, chemical engineering such as the bioengineering as an importance, he will apply chemical-engineering technique, approach in future more and more, while the above, he make the chemical engineering association to be a basis of the activity, many-sided, and various creative research result have been raised, and the result has been evaluated high in domestic and overseas. (translated by NEDO)

  8. Survey of energy load leveling system in Europe; Energy fuka heijunka taisaku ni kansuru Europe chosa

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Y. [Setsunan University, Osaka (Japan). Faculty of Engineering

    1998-05-05

    This paper describes the survey of energy load leveling systems in Europe. In Denmark, especially regional heating is remarkably diffused, and they have 350 plants. With extending the service areas, the energy load leveling has been promoted. For the cogeneration plants of SK Power, the largest electric power company, they have hot water heat storage tanks for regional heat supply with a total capacity 2,200 MWh. The regional heating system in Goeteborg City of Sweden supplies 80% of the total heat demand of the city. Unused energy sources derived from petroleum refining, sewage treatment, and garbage burning are utilized. In Uppsala, they have seasonal heat storage systems using solar heat. The Vienna Regional Heat Supply Corporation supplies heat equivalent to 5,000 GWh a year. Cogeneration plants and garbage burning plants are used as heat sources, and 25% of the total heating in the city is supplied. In Austria, they have an electric power demand with a peak in winter, and they have a pumped-storage power station in Kaprun for the annual load leveling using dump power in summer. This paper also introduces a compressed air storage gas turbine plant at Huntorf of Germany, and a large-scale underground natural gas storage of Gaz de France. 6 figs.

  9. Studies on ternary silver sulfides; Fukugo gin ryukabutsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-10-31

    Some sulfides containing silver show high ion mobility based on movability of silver, whose application is expected. Studies have been carried out centrally on synthesis of new compounds of ternary silver sulfides by elucidating the relationship among their compositions, structures and properties by means of crystal chemical studies mainly on their phase relationship. A few new compounds have been synthesized, such as the ones having the argyrodite family compound structure including transition metals. The synthesizing process takes a kind of turbulent liquid state structure at elevated temperatures because of movability of silver, but silver is fixed at low temperatures in different sites between skeleton structures made by other atoms. These studies on phase transfer, structures, and silver movability have been based on X-ray diffraction, infrared and Raman spectroscopic measurements, NMR, measurements of electric and thermal characteristics. For the studies related to compositions and structures of ternary metal sulfides which take compound crystalline structure, a structure analyzing method based on multi-dimensional hyperspatial groups was used. This paper reports the summary of the studies in seven chapters, and dwells on the remaining problems and future prospects. 158 refs., 114 figs., 65 tabs.

  10. Proceedings of RITE international workshop on valuation; Total eko balance ni kansuru kokusai workshop hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-01

    The RITE International Workshop on Valuation was held in Tokyo and Osaka in February 1996, and eight papers on total ecobalance were reported. In The Field of Impact Assessment, described were constitution and methodology about impact assessment in a wide sense. In LCA Yesterday, Today and Tomorrow, discussed were the historical development and future outlook of LCA. In Standardization of Product Life Cycle Assessment, a survey of the present situation of LCA international standardization was made. In the Relationship between Product Life Cycle Assessment Methodology, considered was the relationship between the goal definition of the product life cycle assessment and the methodological choices. In Valuation in LCA, the present study of LCA was reviewed. Besides, reviews of the LCA study in Japan were made public.

  11. Measuring techniques for martensitic transformations; Marutensaito hentai ni kansuru sokutei gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Murakami, Y.; Morito, S. [Univ. of Tsukuba, Tsukuba (Japan). Graduate School; Otsuka, K. [Univ. of Tsukuba, Ibaraki (Japan). Inst. of Materials Science

    1996-03-20

    It is better to measure physical amount that shows significant change during transformation in order to carry out precise detection of martensitic transformations or to decide the transformation temperature. One of it is Differential scanning calorimetry (DSC) method. This method is very easy along with the determination of transformation enthalpy and also specific heat and is used widely. In martensitic transformation, there exist the intrinsic crystal habit face to the alloy system and crystal azimuthal relation between parent phase and martensite, and it is important to decide them correctly as crystallographic parameters. Overhere, method for measuring crystallographic parameters from martensite caused in parent phase single crystal material is introduced. Further, role of electron microscope is extremely large regarding the revelation of martensitic transformation mechanism in atomic scale. In this report, as for what is revealed regarding martensitic transformation when using electron microscope, crystal structure of martensite, form, structure of the interface and so forth are cited. 39 refs., 5 figs.

  12. Bioprocessing of coal. 1. Sekitan no seibutsu kako. 1. ; Sekitan wo datsuryusuru biseibutsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    Kimura, K.; Omura, N.; Saiki, H.; Kono, Y.

    1989-11-01

    In the bioprocessing of coal using biotechnology, desulfurizing microorgaisms were examined. 30-70% of total sulfur in coal is occupied by inorganic sulfur, almost of that is a form of FeS {sub 2}. Using some acidophilic sulfur oxidizing bacteria such as Thiobacillus ferrooxidans and Thermophilic-acidophilic bacterial such as Sulfolobus acidocaldarius, about 90% of inorganic sulfur in coal can be removed in 1 or 2 weeks in pulverized coal-water slurry, a high possibility in practical use is shown. Organic sulfur (total sulfur {minus} inorganic sulfur) is difficult to be removed, since it is combined with carbon in a from of covalent bond. Sulfolobus acidocaldarius can remove both inorganic and organic sulfur simultaneously. One mutant strain of Pseudomonas is excellent at the rate of desulfurization. These organisms must be superior to others, but their desulfurization ratios are generally low. Some bacteria can degrade some kinds of low-rank coals into water soluble liquid fuel, and the ash content is decreased. Bioconversion of low-rank coals to methane gas applying methane enzyme principle, has been proposed, however, still an idea. 81 refs., 5 figs., 15 tabs.

  13. Systematic analysis on mooring systems of floating structures; Futai keiryuho ni kansuru keitoteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, K.; Suzuki, H.; Ide, T. [The University of Tokyo, Tokyo (Japan)

    1996-12-31

    Discussed herein are mooring performance requirements of the new types of marine structures now proposed, and characteristic ranges and future expansion potential of the existing mooring systems. The mooring systems studied for floating structures are catenary, single point (multi-leg and single-leg types), fixed structure with fender and tension leg mooring systems. The studied items include extraction of the elements that constitute rigidity of the spring for horizontal mooring, survey on and data collection for each element, determination of element ranges, programs for mooring analysis, assessment of mooring characteristic ranges, and potential development of the characteristic ranges. It is concluded that the existing systems with their current characteristic ranges and future possibility are insufficient for the future marine structures. It is therefore necessary to develop new mooring concepts, instead of expanding the current concepts, in order to meet the mooring performance requirements for the new marine structures. 14 refs., 9 figs., 11 tabs.

  14. Analysis methods for excavation and tunneling; Kussaku koji ni kansuru kaiseki shuho

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, A. [Iwate Univ., Morioka (Japan). Faculty of Agriculture

    1995-09-01

    The effect of groundwater in excavation is a problem regarding the issue of the excavation work. Accordingly, effective measures for spring water, deformation, stability and so forth may be expected if proper exploration of groundwater behavior in excavation is possible beforehand. However, highly reliable forecast is difficult in reality. The main reason for it is that it is not so easy to find out the nonuniformity of permeability of the ground. Seepage flow analysis method can be used if only the movement of groundwater is to be predicted, However, even for this, it is difficult to identify the prominent channel route in the ground beforehand. In existing analysis, only the appropriateness of prediction of whole flow out quantity from the excavation side can be discussed. In addition, finding out the sudden water gushing or escaped water beforehand is very difficult. However, prediction can be possible using numerical analysis in case of comparatively uniform ground. In this report, effect of groundwater behavior prediction on the analysis of excavation work is described and its evaluation method is outlined. 19 refs., 6 figs.

  15. Research on harmonized molecular materials; Bunshi kyocho zairyo ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Harmonized molecular materials (HMM) were researched to create functional materials adaptable to needs such as environmental harmony and high-efficient conversion in post-industrial society and aging society. Superior mechanisms function efficiently in organisms for perception, transmission and processing of information, and transport and conversion of substances. These functions are caused by harmonization between organic molecules, or organic molecule and metal or inorganic substance. HMM is a key substance to realize these functions similar to those of organisms artificially. It is the purpose of this research to develop HMMs, reform production process by innovating separation and conversion technologies, and finally realize molecular chemical plants. This research also develops high-efficient devices to contribute to the information society, and progresses the industry of bio-functional materials such as high-sensitive bio-sensor. The functions, applications and creation technologies of three kinds of HMM such as assembly, mesophase and microporous materials were researched in fiscal 1995. 956 refs., 128 figs., 13 tabs.

  16. Systematic analysis on mooring systems of floating structures; Futai keiryuho ni kansuru keitoteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, K.; Suzuki, H.; Ide, T. [The University of Tokyo, Tokyo (Japan)

    1996-12-31

    Discussed herein are mooring performance requirements of the new types of marine structures now proposed, and characteristic ranges and future expansion potential of the existing mooring systems. The mooring systems studied for floating structures are catenary, single point (multi-leg and single-leg types), fixed structure with fender and tension leg mooring systems. The studied items include extraction of the elements that constitute rigidity of the spring for horizontal mooring, survey on and data collection for each element, determination of element ranges, programs for mooring analysis, assessment of mooring characteristic ranges, and potential development of the characteristic ranges. It is concluded that the existing systems with their current characteristic ranges and future possibility are insufficient for the future marine structures. It is therefore necessary to develop new mooring concepts, instead of expanding the current concepts, in order to meet the mooring performance requirements for the new marine structures. 14 refs., 9 figs., 11 tabs.

  17. Study on a non-powered heat transporting system; Mudoryoku netsu hanso system ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Kamiya, Y. [Kanto Gakuin University, Yokohama (Japan)

    1997-11-25

    This paper proposes a non-powered heat transportation (HT) system. The system is composed of an evaporator, condenser, receiver, switching chamber (SC) and 3 check valves which are connected with each other by vapor and liquid tubes. Condensed liquid supercooled in the condenser exists in the receiver forming a saturated condition at a concerned temperature, and condensed liquid is lifted up from the condenser to the receiver by pressure difference between the evaporator and receiver. Generally evaporation pressure is higher by pressure difference between liquid levels in the condenser and receiver. The lifted up amount of condensed liquid increases with evaporation pressure, resulting in an increase in heating surface area of the condenser and amount of condensed liquid. A proper evaporator pressure is thus retained by reduction of evaporation pressure. SC is connected with the receiver and evaporator, and switches high- and low-pressure valves by motion of an inner float to transport heat from the evaporator to condenser. Reverse HT is possible as normal latent HT by installing a bypass. Some problems are also described. 2 refs., 8 figs.

  18. Study on intelligent structural materials; Intelligent kozo zairyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-11-28

    Materials having intelligent properties against fracturing were investigated. Synthesis of materials with high toughness, understanding of elementary process of fracturing, and investigation of intelligent structural materials were selected as research themes. For the experiments, relationship was examined between fracture resistance and crack propagation of the highly tough silicon nitride produced by the newly developed texture control method. As a result, it was found that the crack propagation of this material can be detected by abnormally grown grains, and that the resistance against fracturing increases with crack propagation. It was revealed that the present material is a crack diagnostic intelligent material. The crack edge of these liquid phase sintered materials with high toughness is very active. The cracks can be recovered below the sintering temperature. This means that the strength can be recovered by the proper heat treatment on the way of use. The reliability can be secured by the different method from the conventional investigation aiming at high performance. 140 refs., 82 figs., 8 tabs.

  19. HTS trap flux under temperature cycles; Koon chodendo torappu jisoku no ondo saikuru ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Nitta, K.; Sawa, K. [Keio Univ., Tokyo (Japan); Kang, Y.M.; Fujimoto, S. [Daikin Industries, Ltd., Tsukuba (Japan); Iwasa, Y.

    1999-06-07

    In the application of the high-temperature superconductor, there are utilization as a under wire rod and utilization of bulk body itself. As a utility form of the bulk superconductivity, the application as magnetic field source, which generates magnetic field, which is by far high in function equal to permanent magnet, attracts large attention by trapping magnetic field by pinning effect. However, the constraint of the method for always cooling is big, when the freedom for the portability is considered. The new cooling mechanism is required. Then, it cools using the temporary refrigerating machine, and the equipment that it keeps under the critical temperature using the cooling vessel and keeps the superconducting state is considered. However, it is necessary to cool by refrigerating machine again, before the superconductor reaches critical temperature, for the slight temperature rise without also avoiding in cooling in. By the temperature cycle by the repetition of this temperature rise and cooling, the place in of today of where a magnetic flux trapped in the disk does what kind of change has not been clarified. The experiment under the temperature cycle was tried, and the change of a trap magnetic flux of the high-temperature superconductor YBCO Disk melts by the temperature change was examined. (NEDO)

  20. Basic study on intelligent materialization of glass; Glass no intelligent ko zairyoka ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-10-31

    This is the report No. 98 issued by the Inorganic Material Research Institute. An intelligent material is a substance and/or material which responds intelligently to environmental conditions and exhibits functions. One of the features of amorphous materials including amorphous glass is a large freedom in chemical composition. These materials maintain order in short distance, but have as a whole the turbulent and specific atom orientation. Therefore, high tolerability in selecting the composition, and diverse synthesizing methods are available. A wide range of utilization may be conceived, such as introduction of the state of electrons having different valences in a structure, and the diverse chemical combinations. Patterns of existence of polyhedrons having different orientations, and how they are connected correlate closely with an external environment. Intelligent materials have high freedom against change in the external environment and are suitable to exhibit intelligent functions. Setting heat and light as the external conditions, attempts have been made on search and creation of intelligent materials based on state change induced by interactions between the two factors. Fundamental studies have been made on synthesis of different environment responding glasses and films, and on factors and phenomena for exhibition of the intelligence. 62 refs., 91 figs., 8 tabs.

  1. Layered multinary lanthanum oxide [La-Mo-O]; Sojo rantan fukugo sankabutsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-10-31

    Studies have been carried out systematically on properties of oxides including representative transition metal, vanadium, and alkali metals. With respect to Ln2CuO4 (Ln is a rare earth element) being a simple and representative rare earth multinary oxide showing superconductivity, and its related compounds, this paper reports thermal chemistry, superconduction, and making them a superconductor by using soft chemical treatment. The paper also reports centrally on synthesis of new copper oxide superconductors under high pressure, the compositions, structures, superconductive properties of the synthetics, and the relationship between them. It describes phase equilibrium, synthesis, and structures of vanadium multinary oxides being the object of continued studies, and also reports the studies related to structure and phase transfer of NaV6O11 which shows especially interesting properties among the oxides. Studies have also been made on NMR of these compounds and copper oxide superconductors by using magnetic resonance. The paper also describes a method to analyze the structure of quasi-crystal having rotary symmetry which is not allowed in crystals, and has special long-distance order phase. 209 refs., 127 figs., 6 tabs.

  2. Wing structure of dragonfly; Tonbo no hane kozo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Sudo, S.; Tsuyuki, K. [Iwaki Meisei University, Fukushima (Japan); Hashimoto, H.; Katagiri, K. [Tohoku Univ., Sendai (Japan). Inst. of Fluid Science

    1996-07-21

    This paper is concerned with the wing structure and the aerodynamics of a flying dragonfly. The structural properties of dragonfly wings were studied through the measurements of some morphological parameters. The wings of the dragonfly Sympetrum infuscatum were examined with a scanning electron microscope. Some structural features of dragonfly wings were revealed. Some aerodynamic aspects of dragonflies were considered on the leases of experimental results. The relationship between flapping frequency and total weight for dragonflies was found through dimensional analysis. 13 refs., 11 figs.

  3. Study of freshwater red tide control measures; Tansui akashio taisaku ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Onishi, M.; Hatamochi, K. [Kansai Electric Power Co. Inc., Osaka (Japan)

    1997-09-30

    Basic research of biological measures for which the accumulation of basic findings is mandatory and the applied research of chemical and physical measures that are higher in feasibility are conducted for the establishment of measures to counter freshwater red tides. In the basic research, natural enemies, algaecidal microbes, conjugation inhibiting substances, and allelopathy are studied, but none of them is found feasible at the current stage. In the basic research, however, factors are discovered that inhibit the multiplication of Peridinium bipes or perish the same. In the applied research, chemical algaecidal methods, UV-aided algaecidal methods, and various red-tide constituent collection methods are studied. Collection methods are compared, and it is concluded that a method of Toray Industries, Inc., efficiently collects red-tide constituents. In this method, red-tide constituents are screened by and condensed on a cloth filter provided on the internal wall of a drum, and are dehydrated and then transferred. The applied research further involves the prediction of red tide outbreak and the raising of fish on a food containing substances extracted from red tides, and it is suggested that these are feasible. 18 refs., 15 figs., 3 tabs.

  4. Investigation into the emission of greenhouse effect gases; Onshitsu koka gas no haishutsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper grasped the situation of greenhouse effect gas emissions of advanced countries based on the reports from them. The advanced countries which concluded the U.N. Framework Convention on Climate Change (OECD member countries, the former U.S.S.R., and East European countries) are to be reported to the office concerned with work for the framework the situation of their greenhouse effect gas emissions according to the obligation of the framework. In and after April 1997, they made the second report. The paper summarized changes in emission amount, the future trend, and the policies/measures mainly taken of nine countries which have already presented the second report (the U.S., the U.K., Germany, Holland, Italy, Norway, Sweden, Finland, and New Zealand) and one country (Russia) which has made only the first report. Moreover, the literature was collected and summed up concerning the mechanism and coefficients of the emission of nitrous oxide and methane. The collected literature was classified into all fields/plural number of fields, energy relation, industrial process relation, relation with the use of organic solvent and other products, agricultural relation, relation with changes in land use and forests, and waste relation. 4 figs., 228 tabs.

  5. Steam reforming of biomass gasification tar using benzene as a model compound over various Ni supported metal oxide catalysts.

    Science.gov (United States)

    Park, Hyun Ju; Park, Sung Hoon; Sohn, Jung Min; Park, Junhong; Jeon, Jong-Ki; Kim, Seung-Soo; Park, Young-Kwon

    2010-01-01

    The steam reforming of benzene as a model compound of biomass gasification tar was carried out over various Ni/metal oxide catalysts. The effects of the support, temperature, Ni-precursor, Ni loading and reaction time were examined, and their catalytic performance was compared with that of a commercial Ni catalyst. Among the Ni/metal oxide catalysts used, 15 wt% Ni/CeO(2)(75%)-ZrO(2)(25%) showed the highest catalytic performance owing to its greater redox characteristics and increased surface area, irrespective of the reaction temperature. The catalytic activity of 15 wt% Ni/CeO(2)(75%)-ZrO(2)(25%) was higher than that of the commercial Ni catalyst. Moreover, the catalyst activity was retained due to its excellent resistance to coke deposition even after 5h. The Ni-precursor played a critical role in the catalytic activity. With the exception of nickel nitrate, all the Ni-precursors (chloride and sulfate) caused deactivation of the catalyst.

  6. Fatigue Modeling for Superelastic NiTi Considering Cyclic Deformation and Load Ratio Effects

    Science.gov (United States)

    Mahtabi, Mohammad J.; Shamsaei, Nima

    2017-08-01

    A cumulative energy-based damage model, called total fatigue toughness, is proposed for fatigue life prediction of superelastic NiTi alloys with various deformation responses (i.e., transformation stresses), which also accounts for the effects of mean strain and stress. Mechanical response of superelastic NiTi is highly sensitive to chemical composition, material processing, as well as operating temperature; therefore, significantly different deformation responses may be obtained for seemingly identical NiTi specimens. In this paper, a fatigue damage parameter is proposed that can be used for fatigue life prediction of superelastic NiTi alloys with different mechanical properties such as loading and unloading transformation stresses, modulus of elasticity, and austenite-to-martensite start and finish strains. Moreover, the model is capable of capturing the effects of tensile mean strain and stress on the fatigue behavior. Fatigue life predictions using the proposed damage parameter for specimens with different cyclic stress responses, tested at various strain ratios (R ɛ = ɛ min /ɛ max) are shown to be in very good agreement with the experimentally observed fatigue lives.

  7. FFLO Excitonic State in the Three-Chain Hubbard Model for Ta2NiSe5

    Science.gov (United States)

    Yamada, Takemi; Domon, Kaoru; Ōno, Yoshiaki

    2016-05-01

    The three-chain Hubbard model for Ta2NiSe5, known as a candidate material for an excitonic insulator, is investigated over the wide range of the energy gap D between the twofold degenerate conduction bands and the nondegenerate valence band including both semiconducting (D > 0) and semimetallic (D NiSe5 under high pressure.

  8. Atomistic modeling of ternary additions to NiTi and quaternary additions to Ni-Ti-Pd, Ni-Ti-Pt and Ni-Ti-Hf shape memory alloys

    Energy Technology Data Exchange (ETDEWEB)

    Mosca, H.O., E-mail: hmosca@cnea.gov.ar [Gcia. Investigacion y Aplicaciones, CNEA, Av. Gral Paz 1499, B1650KNA San Martin (Argentina); GCMM, UTN, FRG Pacheco, Av. H. Yrigoyen 288, Gral. Pacheco (Argentina); Bozzolo, G. [Loyola University Maryland, 4501 N. Charles St., Baltimore, MD 21210 (United States); Grosso, M.F. del [Gcia. Investigacion y Aplicaciones, CNEA, Av. Gral Paz 1499, B1650KNA San Martin (Argentina); GCMM, UTN, FRG Pacheco, Av. H. Yrigoyen 288, Gral. Pacheco (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnicas, CONICET (Argentina)

    2012-08-15

    The behavior of ternary and quaternary additions to NiTi shape memory alloys is investigated using a quantum approximate method for the energetics. Ternary additions X to NiTi and quaternary additions to Ni-Ti-Pd, Ni-Ti-Pt, and Ni-Ti-Hf alloys, for X=Au, Pt, Ir, Os, Re, W, Ta,Ag, Pd, Rh, Ru, Tc, Mo, Nb, Zr, Zn, Cu, Co, Fe, Mn, V, Sc, Si, Al and Mg are considered. Bulk properties such as lattice parameter, energy of formation, and bulk modulus of the B2 alloys are studied for variations due to the presence of one or two simultaneous additives.

  9. Modeling of Thermal Expansion Coefficients of Ni-Based Superalloys Using Artificial Neural Network

    Science.gov (United States)

    Bano, Nafisa; Nganbe, Michel

    2013-04-01

    The objective of this work is to model the thermal expansion coefficients of various Ni-based superalloys used in gas turbine components. The thermal expansion coefficient is described as a function of temperature, chemical composition including Ni, Cr, Co, Mo, W, Ta, Nb, Al, Ti, B, Zr, and C contents as well as heat treatment including solutionizing and aging. Experimental values are well described and their relative changes well correlated by the model. Because gas turbine engine components operate under severe loading conditions and at high and varying temperatures, the prediction of their thermal expansion coefficient is crucial. The model developed in this work can be useful for design optimizations for minimizing thermo-mechanical stresses between the base alloys and potential protective coatings or adjacent components. It can substantially contribute to improve the performance and service life of gas turbine components.

  10. Thermal effects in a mechanical model for pseudoelastic behavior of NiTi wires

    Directory of Open Access Journals (Sweden)

    Hugo Soul

    2007-12-01

    Full Text Available A mechanical model for pseudoelastic behavior of NiTi wires is proposed with the aim to predict the behavior of Shape Memory Alloys(SMA damping wire elements in model structures. We have considered at first a simple linearwise stress-strain relationship to describe the basic isothermal behavior of the SMA members. Then, this basic model is modified in order to include the effect of the strain rate. The model is based on detailed experimental characterization performed on a Ni rich NiTi superelastic wire which included the study of the localized character of the deformation and the local heat generation associated with the stress induced martensitic transformation occurring in these alloys. Heat conduction along the wire and heat interaction with the surroundings was also considered. In that way, the resulting local temperature field around the transformation front is assessed and its effect on the progression of the transformation is evaluated. It is shown how the simple mechanical model reproduces the global mechanical behavior, including the existence of a maximum in the damping capacity with the transformation rate.

  11. Thermodynamic Modelling of Fe-Cr-Ni-Spinel Formation at the Light-Water Reactor Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Kurepin, V.A.; Kulik, D.A.; Hitpold, A.; Nicolet, M

    2002-03-01

    In the light water reactors (LWR), the neutron activation and transport of corrosion products is of concern in the context of minimizing the radiation doses received by the personnel during maintenance works. A practically useful model for transport and deposition of the stainless steel corrosion products in LWR can only be based on an improved understanding of chemical processes, in particular, on the attainment of equilibrium in this hydrothermal system, which can be described by means of a thermodynamic solid-solution -aqueous-solution (SSAS) model. In this contribution, a new thermodynamic model for a Fe-Cr-Ni multi-component spinel solid solutions was developed that considers thermodynamic consequences of cation interactions in both spinel sub-Iattices. The obtained standard thermodynamic properties of two ferrite and two chromite end-members and their mixing parameters at 90 bar pressure and 290 *c temperature predict a large miscibility gap between (Fe,Ni) chromite and (Fe,Ni) ferrite phases. Together with the SUPCRT92-98 thermo- dynamic database for aqueous species, the 'spinel' thermodynamic dataset was applied to modeling oxidation of austenitic stainless steel in hydrothermal water at 290*C and 90 bar using the Gibbs energy minimization (GEM) algorithm, implemented in the GEMS-PSI code. Firstly, the equilibrium compositions of steel oxidation products were modelIed as function of oxygen fugacity .fO{sub 2} by incremental additions of O{sub 2} in H{sub 2}O-free system Cr-Fe- Ni-O. Secondly, oxidation of corrosion products in the Fe-Cr-Ni-O-H aquatic system was modelIed at different initial solid/water ratios. It is demonstrated that in the transition region from hydrogen regime to oxygen regime, the most significant changes in composition of two spinel-oxide phases (chromite and ferrite) and hematite must take place. Under more reduced conditions, the Fe-rich ferrite (magnetite) and Ni-poor chromite phases co-exist at equilibrium with a metal Ni

  12. Characterization of the hierarchical microstructure of a Ni-Al-Ti model alloy; Charakterisierung der hierarchischen Mikrostruktur einer Ni-Al-Ti Modell-Legierung

    Energy Technology Data Exchange (ETDEWEB)

    Vogel, Florian

    2014-02-28

    Phase separation of γ{sup '} precipitates determines the microstructure and mechanical properties of nickel-based superalloys. Upon ageing, γ spheres form inside ordered (L1{sub 2}) γ{sup '} precipitates, undergo a morphological change to plates and finally split the γ{sup '} precipitates. To clarify the identity of the insufficiently characterized γ particles and to elucidate their influence on the evolution of the microstructure and the mechanical properties, differently heat treated samples of a Ni-Al-Ti modell alloy were investigated from the micrometer to the atomic scale. The single crystalline cast material was broadly characterized by means of light and scanning electron microscopy, the laue method (back-reflection), differential scanning calorimetry as well as electron probe microanalysis. Dendritic segregations were found, whereas the dendrite cores show an enrichment in nickel and aluminum and in turn the interdendritic regions show an enrichment in titanium. An adequate combination of temperature and time was determined on the basis of quantitative analyses after different homogenization treatments. The evolution of the hierarchical microstructure was investigated on the nanometer scale by means of transmission electron microscopy and on the atomic scale with atom probe tomography. The combined analyses reveal that Ni-rich clusters form within the γ{sup '} precipitates during the early stages of phase separation. These Ni-rich clusters coalesce and thereby form γ spheres which undergo a morphological change to plates accompanied by a chemical evolution. In the beginning the γ spheres are located well within the metastable γ + γ{sup '} two-phase region and later, after the morphological change, achieve the equilibrium composition of the γ phase. Furthermore the involved energies were considered in order to elucidate the driving forces for the phase separation of γ{sup '} precipitates. A correlation between the

  13. Review on departure time choice theory for highway traffic; Doro kotsu ni okeru shuppatsu jikoku sentaku ni kansuru kenkyu kaisetsu

    Energy Technology Data Exchange (ETDEWEB)

    Kuwahara, M. [The University of Tokyo, Tokyo (Japan). Institute of Industrial Science

    1998-04-01

    This paper explains theoretical results achieved to date on the fundamental theory for time smoothing which is drawing attention as a measure to mitigate traffic congestion, that is departure time choice theory for highway traffic. If a trip having a definite restriction on arrival time is used as an object of the discussion, the travel expense for a traveler consists of an expense for travel time when a car was driven at free speeds, an expense for waiting time at bottlenecks, and an expense incurred by schedule delay (s). Under an assumption that the traveler selects departure time to minimize the expense, a time-based equilibrium condition can be introduced. If a schedule expense function (f(s)) to convert `s` into an expense is convex with regard to the `s`, the first in first work (FIFW) principle can be established, that the bottleneck is reached in the order of earlier departure time that is desired. Thus, starting from handling numerically the relationship between queuing expense function in the bottleneck and the f(s), the theory developed to the multiple bottleneck and random effect theory. 19 refs., 8 figs.

  14. Research on crystal growth by using pressure as a control parameter; Atsuryoku seigyo ni yoru kessho seicho ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-10-31

    This research project aims to establish a technique for crystal growth using pressure as a principal control parameter, and combining it with a microgravity condition, to develop a novel process material fabrication. Since the solubility of materials depends on pressure, it is possible to control a supersaturated condition for crystal growth by changing pressure. The growth condition can be controlled precisely, which is not possible by conventional methods that vary temperature and other factors. On the other hand, because a concentration diffusing field is formed autonomically around crystals in association with their growth, density convection is generated under gravity as a result of difference in the concentrations, making the growth conditions severely complex and uncontrollable. Ideal crystal growth condition control may be possible if the pressure control is performed under micro-gravity by which generation of the density convection can be suppressed. Realization has been achieved on in-situ observation by using high-magnification microscope which uses a diamond anvil cell, development of a hydraulic type optic pressure cell, and a high- speed crystal growing technology by means of pressure control utilizing the cell. New findings were also obtained on effects of pressure on crystal forms, and the pressure induced solid phase transfer mechanism. 67 refs., 49 figs., 3 tabs.

  15. Photocatalytic Reduction of Ni (II Ions Using Low Amounts of Titania Nanoparticles: RSM Modelling, Kinetic

    Directory of Open Access Journals (Sweden)

    Javad Saien

    2014-09-01

    Full Text Available Background: Heavy metals in aquatic systems usually interfere with many beneficial uses of water. Divalent nickel is a commonly occurring toxic metal in natural ecosystems due to the effluent of refineries, electroplating, and casting industries. In aquatic environments, nickel appears as Ni (II and Ni0. Despite the high reported toxicity for Ni (II, Ni0 is only slightly toxic. Various methods have been proposed for the treatment of aqueous solutions containing Ni (II. Photocatalytic reduction is an important process; titanium dioxide has been mostly used as a very efficient photocatalyst. Methods: In this study, the removal of divalent nickel ions in aqueous solutions was studied in the presence of remarkably low dosages of nano-titania photocatalyst. Direct imposed irradiation was utilized for treatment of solutions. Accordingly, the influence of four operational parameters, including temperature within the conventional range of 20 to 40 °C, was investigated. Design of experiments, modeling and process optimization were accomplished using central composite design of response surface methodology. Results: Reduced quadratic expression was developed for the reduction efficiency (RE, and the analysis of variance showed its capability in reproducing the data. The effectiveness of each parameter was determined. At the best found conditions of [TiO2] = 42 mg/L, pH = 9.2, T = 34 °C and after 90 minutes of treatment, about 85% removal was achieved for initial 5 mg/L nickel solutions. Pseudo first order reactions proceeded. Conclusion: Based on CCD method, the influence of individual operating parameters and their interactions were obtained. A quadratic equation predicted the variations quite well.

  16. In search of metal hydrides: an X-ray absorption and emission study of [NiFe] hydrogenase model complexes.

    Science.gov (United States)

    Hugenbruch, Stefan; Shafaat, Hannah S; Krämer, Tobias; Delgado-Jaime, Mario Ulises; Weber, Katharina; Neese, Frank; Lubitz, Wolfgang; DeBeer, Serena

    2016-04-28

    Metal hydrides are invoked as important intermediates in both chemical and biological H2 production. In the [NiFe] hydrogenase enzymes, pulsed EPR and high-resolution crystallography have argued that the hydride interacts primarily at the Ni site. In contrast, in [NiFe] hydrogenase model complexes, it is observed that the bridging hydride interacts primarily with the Fe. Herein, we utilize a combination of Ni and Fe X-ray absorption (XAS) and emission (XES) spectroscopies to examine the contribution of the bridging hydride to the observed spectral features in [(dppe)Ni(μ-pdt)(μ-H)Fe(CO)3](+). The corresponding data on (dppe)Ni(μ-pdt)Fe(CO)3 are used as a reference for the changes that occur in the absence of a hydride bridge. For further interpretation of the observed spectral features, all experimental spectra were calculated using a density functional theory (DFT) approach, with excellent agreement between theory and experiment. It is found that the iron valence-to-core (VtC) XES spectra reveal clear signatures for the presence of a Fe-H interaction in the hydride bridged model complex. In contrast, the Ni VtC XES spectrum largely reflects changes in the local Ni geometry and shows little contribution from a Ni-H interaction. A stepwise theoretical analysis of the hydride contribution and the Ni site symmetry provides insights into the factors, which govern the different metal-hydride interactions in both the model complexes and the enzyme. Furthermore, these results establish the utility of two-color XES to reveal important insights into the electronic structure of various metal-hydride species.

  17. Kinetic model of induced codeposition of Ni-Mo alloys

    Institute of Scientific and Technical Information of China (English)

    ZENG, Yue; MA, Ming; XIAO, Xiao-Ming; LI, Ze-Lin; LIAN, Shi-Xun; ZHOU, Shao-Min

    2000-01-01

    The kinetic model of induced codeposition of nickel-molybdenum alloys from ammoniun citrate solution was studied on rotating disk electrodes to predict the behavior of the electrodeposition. Ihe molybdate (MoO42-) could be firstly electrochemically reduced to MoO2, and subsequently undergoes a chemical reduction with atomic hydrogen previously adsorbed on the inducing metal nickel to form molybdenum in alloys.The kinetic equations were derived, and the kinetic parameters were obtained from a comparison of experimental results and the kinetic equations. The electrochemical rate constants for discharge of nickel, molybdenum and water could been expressed as k1 ( E ) = 1. 23 × 10-9 CNexp( - 0. 198FE/ RT )mol/(dm2. s), k2 (E) = 3.28 × 10-10 CMoexp ( - 0.208FE/RT) mol/(dm2·s) and k3(E) = 1.27 × 10-6exp( - 0.062FE/RT) mol/(dm2 ·s), where CN and CMo are the concentrations of the nickel ion and molybdate, respectively, and E is the applied potential vs, saturated calornel electrode (SCE).The codeposition process could be well simulated by this model.

  18. El Niño in a changing climate: a multi-model study

    Directory of Open Access Journals (Sweden)

    G. J. van Oldenborgh

    2005-06-01

    Full Text Available In many parts of the world, climate projections for the next century depend on potential changes in the properties of the El Niño - Southern Oscillation (ENSO. The current staus of these projections is assessed by examining a large set of climate model experiments prepared for the Fourth Assessment Report of the Intergovernmental Panel on Climate Change. Firstly, the patterns and time series of present-day ENSO-like model variability in the tropical Pacific Ocean are compared with that observed. Next, the strength of the coupled atmosphere-ocean feedback loops responsible for generating the ENSO cycle in the models are evaluated. Finally, we consider the projections of the models with, what we consider to be, the most realistic ENSO variability. Two of the models considered do not have interannual variability in the tropical Pacific Ocean. Three models show a very regular ENSO cycle due to a strong local wind feedback in the central Pacific and weak sea surface temperature (SST damping. Six other models have a higher frequency ENSO cycle than observed due to a weak east Pacific upwelling feedback loop. One model has much stronger upwelling feedback than observed, and another one cannot be described simply by the analysis technique. The remaining six models have a reasonable balance of feedback mechanisms and in four of these the interannual mode also resembles the observed ENSO both spatially and temporally. Over the period 2051-2100 (under various scenarios the most realistic six models show either no change in the mean state or a slight shift towards El Niño-like conditions with an amplitude at most a quarter of the present day interannual standard deviation. We see no statistically significant changes in amplitude of ENSO variability in the future, with changes in the standard deviation of a Southern Oscillation Index that are no larger than observed decadal variations. Uncertainties in the skewness of the variability are too large to make

  19. El Niño in a changing climate: a multi-model study

    Directory of Open Access Journals (Sweden)

    G. J. van Oldenborgh

    2005-01-01

    Full Text Available In many parts of the world, climate projections for the next century depend on potential changes in the properties of the El Niño - Southern Oscillation (ENSO. The current staus of these projections is assessed by examining a large set of climate model experiments prepared for the Fourth Assessment Report of the Intergovernmental Panel on Climate Change. Firstly, the patterns and time series of present-day ENSO-like model variability in the tropical Pacific Ocean are compared with that observed. Next, the strength of the coupled atmosphere-ocean feedback loops responsible for generating the ENSO cycle in the models are evaluated. Finally, we consider the projections of the models with, what we consider to be, the most realistic ENSO variability. Two of the models considered do not have interannual variability in the tropical Pacific Ocean. Three models show a very regular ENSO cycle due to a strong local wind feedback in the central Pacific and weak sea surface temperature (SST damping. Six other models have a higher frequency ENSO cycle than observed due to a weak east Pacific upwelling feedback loop. One model has much stronger upwelling feedback than observed, and another one cannot be described simply by the analysis technique. The remaining six models have a reasonable balance of feedback mechanisms and in four of these the interannual mode also resembles the observed ENSO both spatially and temporally. Over the period 2051-2100 (under various scenarios the most realistic six models show either no change in the mean state or a slight shift towards El Niño-like conditions with an amplitude at most a quarter of the present day interannual standard deviation. We see no statistically significant changes in amplitude of ENSO variability in the future, with changes in the standard deviation of a Southern Oscillation Index that are no larger than observed decadal variations. Uncertainties in the skewness of the variability are too large to make

  20. Computational Modeling to Predict Fatigue Behavior of NiTi Stents: What Do We Need?

    Directory of Open Access Journals (Sweden)

    Elena Dordoni

    2015-05-01

    Full Text Available NiTi (nickel-titanium stents are nowadays commonly used for the percutaneous treatment of peripheral arterial disease. However, their effectiveness is still debated in the clinical field. In fact a peculiar cyclic biomechanical environment is created before and after stent implantation, with the risk of device fatigue failure. An accurate study of the device fatigue behavior is of primary importance to ensure a successful stenting procedure. Regulatory authorities recognize the possibility of performing computational analyses instead of experimental tests for the assessment of medical devices. However, confidence in numerical methods is only possible after verification and validation of the models used. For the case of NiTi stents, mechanical properties are strongly dependent on the device dimensions and the whole treatments undergone during manufacturing process. Hence, special attention should be paid to the accuracy of the description of the device geometry and the material properties implementation into the numerical code, as well as to the definition of the fatigue limit. In this paper, a path for setting up an effective numerical model for NiTi stent fatigue assessment is proposed and the results of its application in a specific case study are illustrated.

  1. Saturation magnetization of Ni(II) in metalloproteins and model compounds

    Energy Technology Data Exchange (ETDEWEB)

    Sendova, M.; Day, E.P.; Kiick, K.; Johnson, M.; Ma, L.; Scott, B.; Hausinger, R.; Todd, M.; Peterson, J. (Emory Univ., Atlanta, GA (United States) Univ. of Georgia, Athens (United States) Michigan State Univ., East Lansing (United States) Univ. of Alabama, Tuscaloosa (United States))

    1992-01-01

    The Ni(II) sites of urease (from Klebsiella aerogenes and jack bean), coenzyme F[sub 430] (from Methanobacterium thermoautotrophicum), and several model compounds having octahedral symmetry have been studied using the saturation megnetization technique. Data were collected at four fixed fields over the temperature range from 2 - 200K. Theoretical curves calculated from the spin Hamiltonian were used to fit the experimentally obtained magnetization curves. The following parameters were determined: the spine state (S), the amount of the sample in this spin state ([S]), the gyromagnetic ratio (g), and the zero field splitting parameters (D, E/D). The amount of S=1 paramagnetism of the Ni(II) sites was found to depend on the pH of the buffer and on the concentration of the protein in D[sub 2]O (for coenzyme F[sub 430]). The relationship of the strength of the ligand field to the zero field splitting parameter was studied for the model compounds. There was no evidence for exchange coupling between the two Ni(II) ions at the active sites of either plant or bacterial urease.

  2. Modeling of hydrogen effect on the superelastic behavior of Ni-Ti shape memory alloy wires

    Science.gov (United States)

    Lachiguer, Amani; Bouby, Céline; Gamaoun, Fehmi; Bouraoui, Tarak; Ben Zineb, Tarak

    2016-11-01

    Superelastic NiTi wires are widely used in orthodontic treatments, but sometimes fracture can be observed after few months of use in buccal cavity and attributed to the degradation of NiTi mechanical properties due to hydrogen absorption. In this paper, a modeling approach is proposed in order to describe the effect of hydrogen diffusion on the transformation properties of NiTi SMAs. In order to experimentally predict such effects, cathodic hydrogen charging was performed at a current density of 10 A/{m}2 for 6h, 24h, 48h and 72h in 0.9% NaCl aqueous solution at room temperature. Tensile tests were carried out shortly after hydrogen charging. The obtained stress-strain curves showed an increase of yield transformation stresses for forward and reverse martensitic transformations and a decrease of maximum transformation strain. Using Fick’s second law, the transformation temperatures variation can be expressed as a function of the mean concentration of absorbed hydrogen and then taked into account in the SMA constitutive model developed by Chemisky et al (2011). The numerical results are compared to the experimental ones to calibrate the proposed method. Simulations showed that hydrogen diffusion induces a shifting of transfomation temperatures, a decreasing of maximum transformation strain and an increasing of yield transfomation stresses.

  3. Solution-based thermodynamic modeling of the Ni-Al-Mo system using first-principles calculations

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, S H [Ames Laboratory; Wang, Y [Pennsylvania State University; Chen, L -Q [Pennsylvania State University; Liu, Z -K [Pennsylvania State University; Napolitano, R E [Ames Laboratory

    2014-09-01

    A solution-based thermodynamic description of the ternary Ni–Al–Mo system is developed here, incorporating first-principles calculations and reported modeling of the binary Ni–Al, Ni–Mo and Al–Mo systems. To search for the configurations with the lowest energies of the N phase, the Alloy Theoretic Automated Toolkit (ATAT) was employed and combined with VASP. The liquid, bcc and γ-fcc phases are modeled as random atomic solutions, and the γ'-Ni3Al phase is modeled by describing the ordering within the fcc structure using two sublattices, summarized as (Al,Mo,Ni)0.75(Al,Mo,Ni)0.25. Thus, γ-fcc and γ'-Ni3Al are modeled with a single Gibbs free energy function with appropriate treatment of the chemical ordering contribution. In addition, notable improvements are the following: first, the ternary effects of Mo and Al in the B2-NiAl and D0a-Ni3Mo phases, respectively, are considered; second, the N-NiAl8Mo3 phase is described as a solid solution using a three-sublattice model; third, the X-Ni14Al75Mo11 phase is treated as a stoichiometric compound. Model parameters are evaluated using first-principles calculations of zero-Kelvin formation enthalpies and reported experimental data. In comparison with the enthalpies of formation for the compounds ψ-AlMo, θ-Al8Mo3 and B2-NiAl, the first-principles results indicate that the N-NiAl8Mo3 phase, which is stable at high temperatures, decomposes into other phases at low temperature. Resulting phase equilibria are summarized in the form of isothermal sections and liquidus projections. To clearly identify the relationship between the γ-fcc and γ'-Ni3Al phases in the ternary Ni–Al–Mo system, the specific γ-fcc and γ'-Ni3Al phase fields are plotted in x(Al)–x(Mo)–T space for a temperature range 1200–1800 K.

  4. Reactive transport model of the formation of oxide-type Ni-laterite profiles (Punta Gorda, Moa Bay, Cuba)

    Science.gov (United States)

    Domènech, Cristina; Galí, Salvador; Villanova-de-Benavent, Cristina; Soler, Josep M.; Proenza, Joaquín A.

    2017-01-01

    Oxide-type Ni-laterite deposits are characterized by a dominant limonite zone with goethite as the economically most important Ni ore mineral and a thin zone of hydrous Mg silicate-rich saprolite beneath the magnesium discontinuity. Fe, less soluble, is mainly retained forming goethite, while Ni is redeposited at greater depth in a Fe(III) and Ni-rich serpentine (serpentine II) or in goethite, where it adsorbs or substitutes for Fe in the mineral structure. Here, a 1D reactive transport model, using CrunchFlow, of Punta Gorda oxide-type Ni-laterite deposit (Moa Bay, Cuba) formation is presented. The model reproduces the formation of the different laterite horizons in the profile from an initial, partially serpentinized peridotite, in 106 years, validating the conceptual model of the formation of this kind of deposits in which a narrow saprolite horizon rich in Ni-bearing serpentine is formed above peridotite parent rock and a thick limonite horizon is formed over saprolite. Results also confirm that sorption of Ni onto goethite can explain the weight percent of Ni found in the Moa goethite. Sensitivity analyses accounting for the effect of key parameters (composition, dissolution rate, carbonate concentration, quartz precipitation) on the model results are also presented. It is found that aqueous carbonate concentration and quartz precipitation significantly affects the laterization process rate, while the effect of the composition of secondary serpentine or of mineral dissolution rates is minor. The results of this reactive transport modeling have proven useful to validate the conceptual models derived from field observations.

  5. An EIS based study of a Ni-MH battery prototype. Modeling and identification analysis

    Energy Technology Data Exchange (ETDEWEB)

    Castro, E.B. [Instituto de Investigaciones Fisicoquimicas Teoricas y Aplicadas (INIFTA). Universidad Nacional de La Plata., CCT La Plata-CONICET, Suc 4, CC16 (1900), La Plata (Argentina); Cuscueta, D.J.; Ghilarducci, A.A.; Salva, H.R. [Centro Atomico Bariloche - Comision Nacional de Energia Atomica (CAB-CNEA), Instituto Balseiro - Universidad Nacional de Cuyo (IB-UNCu), CONICET, Av. Bustillo 9500 - CAB (8400) San Carlos de Bariloche (Argentina); Milocco, R.H. [Grupo de Control Automatico y Sistemas (GCAyS), Depto. Electrotecnia, Facultad de Ingenieria, Universidad Nacional del Comahue, Buenos Aires 1400 (8300) Neuquen (Argentina)

    2010-06-15

    Modeling and simulation of the dynamics of batteries is a useful method to improve design and predict their performance. This paper outlines the development of a simple physicochemical model to simulate the impedance response of the Ni-MH battery system. The model describes the individual electrodes as porous flooded structures where the electrochemical processes take place at the active material/electrolyte interface. The physicochemical system parameters are grouped in such a way that the derived simple model can be experimentally identifiable. Experimental electrochemical impedance spectroscopy (EIS) data, recorded with a laboratory built prototype, are used to identify the model parameters by fitting the theoretical impedance function derived from the model. An analysis of the predicted dependence of the impedance function with the battery SOC and the identifiability of different system parameters are presented. (author)

  6. DETERMINATION OF ELECTRODEPOSITION HARDNESS BY ANALYTICAL MODELING PART I - Ni-P COATINGS OBTAINED BY VARYING THE ELABORATION TIME -

    Directory of Open Access Journals (Sweden)

    PASĂRE Minodora Maria

    2012-05-01

    Full Text Available Results obtained from Vickers hardness tests were used for analytical modeling models Buckle, Jönsson, Hogmark. Ni-P electrodeposition were obtained by varying the elaboration time. The analytic models obtained by theoretical means, by applying the corresponding formulas to each model have been compared to the experimental results obtained at hardness tests.

  7. Interatomic potential to study plasticity in stainless steels: the FeNiCr model alloy

    Science.gov (United States)

    Bonny, G.; Terentyev, D.; Pasianot, R. C.; Poncé, S.; Bakaev, A.

    2011-12-01

    Austenitic stainless steels are commonly used materials for in-core components of nuclear light water reactors. In service, such components are exposed to harsh conditions: intense neutron irradiation, mechanical and thermal stresses, and aggressive corrosion environment which all contribute to the components' degradation. For a better understanding of the prevailing mechanisms responsible for the materials degradation, large-scale atomistic simulations are desirable. In this framework we developed an embedded atom method type interatomic potential for the ternary FeNiCr system to model movement of dislocations and their interaction with radiation defects. Special attention has been drawn to the Fe-10Ni-20Cr alloy, whose properties were ensured to be close to those of 316L austenitic stainless steel. In particular, the stacking fault energy and elastic constants are well reproduced. The fcc phase for the Fe-10Ni-20Cr random alloy was proven to be stable in the temperature range 0-900 K and under shear strain up to 5%. For the same alloy the stable glide of screw dislocations and stability of Frank loops was confirmed.

  8. Modeling of the deposition of Ni and Pd on Mo(1 1 0)

    Energy Technology Data Exchange (ETDEWEB)

    Canzian, Adrian [Grupo de Caracterizacion y Modelacion de Materiales, UTN, FRGP, H. Yrigoyen 288, (B1617FRP) Gral. Pacheco (Argentina); Mosca, Hugo [Grupo de Caracterizacion y Modelacion de Materiales, UTN, FRGP, H. Yrigoyen 288, (B1617FRP) Gral. Pacheco (Argentina); Comision Nacional de Energia Atomica, U.A. Fisica, Av. Gral Paz 1499, (B1650KNA) San Martin (Argentina); Bozzolo, Guillermo [NASA Glenn Research Center, Cleveland, OH 44135 (United States); Ohio Aerospace Institute, 22800 Cedar Point Road, Cleveland, OH 44142 (United States)], E-mail: Guillermo.H.Bozzolo@grc.nasa.gov

    2007-10-31

    Recent experimental work on the deposition of fcc metals on a bcc substrate motivates this atomistic modeling analysis of Ni and Pd deposition on Mo(1 1 0). A detailed atom-by-atom analysis of the early stages of growth, focusing on the formation of surface alloys and 3D islands is presented, identifying the interactions leading to each type of behavior. Further analysis describes the growth pattern as a function of coverage. Temperature effects are studied via Monte Carlo simulations using the Bozzolo-Ferrante-Smith (BFS) method for alloys for the energetics.

  9. Thermal aging modeling and validation on the Mo containing Fe-Cr-Ni alloys

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Ying [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Tan, Lizhen [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Busby, Jeremy T. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-04-01

    Thermodynamics of intermetallic phases in Fe-rich Fe-Cr-Ni-Mo alloys is critical knowledge to understand thermal aging effect on the phase stability of Mo-containing austenitic steels, which subsequently facilitates alloy design/improvement and degradation mitigation of these materials for reactor applications. Among the intermetallic phases, Chi (χ), Laves, and Sigma (σ) are often of concern because of their tendency to cause embrittlement of the materials. The focus of this study is thermal stability of the Chi and Laves phases as they were less studied compared to the Sigma phase. Coupled with thermodynamic modeling, thermal stability of intermetallic phases in Mo containing Fe-Cr-Ni alloys was investigated at 1000, 850 and 700 C for different annealing times. The morphologies, compositions and crystal structures of the precipitates of the intermetallic phases were carefully examined by scanning electron microscopy, electron probe microanalysis, X-ray diffraction, and transmission electron microscopy. Three key findings resulted from this study. First, the Chi phase is stable at high temperature, and with decreasing temperature it transforms into the Laves phase that is stable at low temperature. Secondly, Cr, Mo, Ni are soluble in both the Chi and Laves phases, with the solubility of Mo playing a major role in the relative stability of the intermetallic phases. Thirdly, in situ transformation from Chi phase to Laves phase was directly observed, which increased the local strain field, generated dislocations in the intermetallic phases, and altered the precipitate phase orientation relationship with the austenitic matrix. The thermodynamic models that were developed and validated were then applied to evaluating the effect of Mo on the thermal stability of intermetallic phases in type 316 and NF709 stainless steels.

  10. Flow Stress Model of Stainless Steel OCr13Ni5Mo at Elevated Temperature

    Institute of Scientific and Technical Information of China (English)

    DONG Wan-peng; CHEN Jun; LI Wen-jun

    2008-01-01

    For a more accurate forming calculation and numerical simulation of hydraulic turbine blade,experimental studies on the flow stress of stainless steel OCr13Ni5Mo were carried out upon Gleeble-1500 thermal simulator under different deformation conditions.The results then were analyzed and the effects of all influencing factors were summarized consequently.New mathematic models were conceived.Utilizing the software Matlab,regression coefficients were calculated by the least square method.The model has an eminent capability of curve-fitting performance with impact structure whose correlation coefficient is up to 0.908 0 and the cosine coefficient is 0.995 8.All mathematic models and process parameters can be used in engineering calculations or computer simulations.

  11. First principles calculations of alloying element diffusion coefficients in Ni using the five-frequency model

    Institute of Scientific and Technical Information of China (English)

    Wu Qiong; Li Shu-Suo; Ma Yue; Gong Sheng-Kai

    2012-01-01

    The diffusion coefficients of several alloying elements (Al,Mo,Co,Ta,Ru,W,Cr,Re) in Ni are directly calculated using the five-frequency model and the first principles density functional theory.The correlation factors provided by the five-frequency model are explicitly calculated.The calculated diffusion coefficients show their excellent agreement with the available experimental data.Both the diffusion pre-factor (Do) and the activation energy (Q) of impurity diffusion are obtained.The diffusion coefficients above 700 K are sorted in the following order:DAl > DCr > DCo > DTa >DMo > DRu > DW > DRe.It is found that there is a positive correlation between the atomic radius of the solute and the jump energy of Ni that results in the rotation of the solute-vacancy pair (E1).The value of E2-E1 (E2 is the solute diffusion energy) and the correlation factor each also show a positive correlation.The larger atoms in the same series have lower diffusion activation energies and faster diffusion coefficients.

  12. Fatigue-crack-initiation numerical modelling of a Ni-base powder metallurgy alloy

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    A simplified three-dimensional numerical model was presented to simulate the micro-crack nucleation and growth to some predefined dimension(approximately 0.38 mm) on the throat surface of a Ni-base powder metallurgy(PM) specimen.The numerical simulation of micro-crack initiation was based on the Tanaka-Mura micro-crack initiation models,where individual grains of the mesoscopic model were simulated using the Voronoi tessellation.Four improvements were made in the model.(1) Considering crack initiation along with 12 principal slip systems on octahedral slip planes of face centered cubic(FCC) crystal in three-dimensional(3-D) models.(2) Considering the effect of secondary phase precipitate due to impinging slip and dislocation pileup.(3) The Tanaka-Mura theory of fatigue-crack-initiation from notches was applied to simulate the crack initiation from another crack tip.(4) The coalescence of random initiated micro-cracks was simulated once they intersected with each other and a macro-crack was finally formed.The calculated results were in good agreement with the experimental data which verified the rationality of the simulation model.The applicability of the proposed model for treating fatigue-crack-initiation life in engineering structures was preliminarily achieved.%A simplified three-dimensional numerical model was presented to simulate the micro-crack nucleation and growth to some predefined dimension(approximately 0.38 mm) on the throat surface of a Ni-base powder metallurgy(PM) specimen.The numerical simulation of micro-crack initiation was based on the Tanaka-Mura micro-crack initiation models,where individual grains of the mesoscopic model were simulated using the Voronoi tessellation.Four improvements were made in the model.(1) Considering crack initiation along with 12 principal slip systems on octahedral slip planes of face centered cubic(FCC) crystal in three-dimensional(3-D) models.(2) Considering the effect of secondary phase

  13. Grain boundary segregation in FeCrNi model alloys; Korngrenzensegregation in FeCrNi-Modellegierungen

    Energy Technology Data Exchange (ETDEWEB)

    Schlueter, B.; Schneider, F.; Mummert, K. [Institut fuer Festkoerper- und Werkstofforschung Dresden e.V. (Germany); Muraleedharan, P. [Indira Gandhi Centre for Atomic Research, Kalpakkam (India). Div. of Metallurgy

    1998-12-31

    P and S segregate at the grain boundaries and thus increase susceptibility to intergranular corrosion at those sites. This could be proven by means of nitric acid-chromate tests and potentiostatic etching tests. There is a direct connection between loss in mass, mean depth of intergranular corrosion attacks, dissolution current density, and level of segregation-induced concentration of P and S at the grain boundaries. The segregation effect at these sites was found to be most evident in specimens of the examined Fe-Cr-Ni steel which had been heat-treated for 1000 hours at 550 C. However, segregation occurs also in materials that received a heat treatment of 400 C/5000 hours, while intergranular corrosion is observed only after heat treatment of 500 C/1000 hours. Apart from segregation of P, formation of Cr-rich phosphides is observed, which leads to depletion of Cr at the precipitates. (orig./CB) [Deutsch] P und S segregieren an die KG und erhoehen dort die IK-Anfaelligkeit. Dies konnte mit Hilfe von Salpetersaeure-Chromat- und Potentiostatischem Aetztest nachgewiesen werden. Es besteht ein direkter Zusammenhang zwischen Masseverlust, mittlerer IK-Angriffstiefe, Aufloesungsstromdichte und Hoehe der segregationsbedingten Anreicherungen von P und S an den KG. Der KG-Segregationseffekt am untersuchten Fe-Cr-Ni-Stahl ist im Waermebehandlungszustand 550 C/1000 h am deutlichsten ausgepraegt. Aber auch bereits bei 400 C/5000 h findet Segregation statt. IKSpRK tritt nur im Waermebehandlungszustand 550 C/1000 h auf. Neben der P-Segregation wird die Bildung Cr-reicher Phosphide beobachtet, die zur Abreicherung von Cr an den Ausscheidungen fuehrt. (orig.)

  14. The Magnetic Properties of TbNi2B2C Investigated with a Two-Sublattice Model

    Institute of Scientific and Technical Information of China (English)

    LIU Zhao-Sen; Divis Martin; Sechovsk(y) Vladimir

    2009-01-01

    A two-sublattice model for rare-earth antiferromagnets is employed to study the magnetic properties of TbNi2B2C.The theoretical susceptibility and magnetization curves obtained with the model show reasonable agreement with the experimental results.

  15. Fast-neutron total and scattering cross sections of sup 58 Ni and nuclear models

    Energy Technology Data Exchange (ETDEWEB)

    Smith, A.B.; Guenther, P.T.; Whalen, J.F. (Argonne National Lab., IL (United States)); Chiba, S. (Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment)

    1991-07-01

    The neutron total cross sections of {sup 58}Ni were measured from {approx} 1 to > 10 MeV using white-source techniques. Differential neutron elastic-scattering cross sections were measured from {approx} 4.5 to 10 MeV at {approx} 0.5 MeV intervals with {ge} 75 differential values per distribution. Differential neutron inelastic-scattering cross sections were measured, corresponding to fourteen levels with excitations up to 4.8 MeV. The measured results, combined with relevant values available in the literature, were interpreted in terms of optical-statistical and coupled-channels model using both vibrational and rotational coupling schemes. The physical implications of the experimental results nd their interpretation are discussed in the contexts of optical-statistical, dispersive-optical, and coupled-channels models. 61 refs.

  16. Equilibrium segregation patterns and alloying in Cu/Ni nanoparticles: Experiments versus modeling

    Science.gov (United States)

    Hennes, M.; Buchwald, J.; Ross, U.; Lotnyk, A.; Mayr, S. G.

    2015-06-01

    We analyze the segregation behavior of bimetallic nanoparticles (NPs) with moderate miscibility gap by applying a combined experimental/simulation approach to Cu/Ni as a model system. Using a hybrid molecular dynamics/Metropolis Monte Carlo algorithm (MD/MMC) based on the embedded atom method (EAM), we derive the equilibrium distribution of atomic species in the clusters for varying concentrations and particle structures. To cross-check the predictive power of our approach, we compare these results with modified EAM (MEAM) and density functional theory based ab initio calculations. This permits to identify possible shortcomings of the EAM when used to describe bimetallic NPs. Additionally, we isolate vibrational entropy contributions to the free energy of the NPs and special focus is put on the possibility of entropic stabilization of segregated versus solid solution NPs. Finally, we complement our simulations by experimental results, which are obtained by studying the behavior of plasma gas condensation synthesized Ni@Cu core-shell (CS) particles upon annealing.

  17. The El Niño-Southern Oscillation cycle simulated by the climate system model of Chinese Academy of Sciences

    Institute of Scientific and Technical Information of China (English)

    SU Tonghua; XUE Feng; SUN Hongchuan; ZHOU Guangqing

    2015-01-01

    On the basis of more than 200-year control run, the performance of the climate system model of Chinese Academy of Sciences (CAS-ESM-C) in simulating the El Niño-Southern Oscillation (ENSO) cycle is evalu-ated, including the onset, development and decay of the ENSO. It is shown that, the model can reasonably simulate the annual cycle and interannual variability of sea surface temperature (SST) in the tropical Pacif-ic, as well as the seasonal phase-locking of the ENSO. The model also captures two prerequisites for the El Niño onset, i.e., a westerly anomaly and a warm SST anomaly in the equatorial western Pacific. Owing to too strong forcing from an extratropical meridional wind, however, the westerly anomaly in this region is largely overestimated. Moreover, the simulated thermocline is much shallower with a weaker slope. As a result, the warm SST anomaly from the western Pacific propagates eastward more quickly, leading to a faster develop-ment of an El Niño. During the decay stage, owing to a stronger El Niño in the model, the secondary Gill-type response of the tropical atmosphere to the eastern Pacific warming is much stronger, thereby resulting in a persistent easterly anomaly in the western Pacific. Meanwhile, a cold anomaly in the warm pool appears as a result of a lifted thermocline via Ekman pumping. Finally, an El Niño decays into a La Niña through their interactions. In addition, the shorter period and larger amplitude of the ENSO in the model can be attribut-ed to a shallower thermocline in the equatorial Pacific, which speeds up the zonal redistribution of a heat content in the upper ocean.

  18. Trophic modeling of the Northern Humboldt Current Ecosystem, Part I: Comparing trophic linkages under La Niña and El Niño conditions

    Science.gov (United States)

    Tam, Jorge; Taylor, Marc H.; Blaskovic, Verónica; Espinoza, Pepe; Michael Ballón, R.; Díaz, Erich; Wosnitza-Mendo, Claudia; Argüelles, Juan; Purca, Sara; Ayón, Patricia; Quipuzcoa, Luis; Gutiérrez, Dimitri; Goya, Elisa; Ochoa, Noemí; Wolff, Matthias

    2008-10-01

    The El Niño of 1997-98 was one of the strongest warming events of the past century; among many other effects, it impacted phytoplankton along the Peruvian coast by changing species composition and reducing biomass. While responses of the main fish resources to this natural perturbation are relatively well known, understanding the ecosystem response as a whole requires an ecotrophic multispecies approach. In this work, we construct trophic models of the Northern Humboldt Current Ecosystem (NHCE) and compare the La Niña (LN) years in 1995-96 with the El Niño (EN) years in 1997-98. The model area extends from 4°S-16°S and to 60 nm from the coast. The model consists of 32 functional groups of organisms and differs from previous trophic models of the Peruvian system through: (i) division of plankton into size classes to account for EN-associated changes and feeding preferences of small pelagic fish, (ii) increased division of demersal groups and separation of life history stages of hake, (iii) inclusion of mesopelagic fish, and (iv) incorporation of the jumbo squid ( Dosidicus gigas), which became abundant following EN. Results show that EN reduced the size and organization of energy flows of the NHCE, but the overall functioning (proportion of energy flows used for respiration, consumption by predators, detritus and export) of the ecosystem was maintained. The reduction of diatom biomass during EN forced omnivorous planktivorous fish to switch to a more zooplankton-dominated diet, raising their trophic level. Consequently, in the EN model the trophic level increased for several predatory groups (mackerel, other large pelagics, sea birds, pinnipeds) and for fishery catch. A high modeled biomass of macrozooplankton was needed to balance the consumption by planktivores, especially during EN condition when observed diatoms biomass diminished dramatically. Despite overall lower planktivorous fish catches, the higher primary production required-to-catch ratio implied a

  19. Slab Ocean El Niño atmospheric feedbacks in Coupled Climate Models and its relationship to the Recharge Oscillator

    Science.gov (United States)

    Bayr, Tobias; Wengel, Christian; Latif, Mojib

    2016-04-01

    Dommenget (2010) found that El Niño-like variability, termed Slab Ocean El Niño, can exist in the absence of ocean dynamics and is driven by the interaction of the atmospheric surface heat fluxes and the heat content of the upper ocean. Further, Dommenget et al. (2014) report the Slab Ocean El Niño is not an artefact of the ECHAM5-AGCM coupled to a slab ocean model. In fact, atmospheric feedbacks crucial to the Slab Ocean El Niño can also be found in many state-of-the-art coupled climate models participating in CMIP3 and CMIP5, so that ENSO in many CMIP models can be understood as a mixed recharge oscillator/Slab Ocean El Niño mode. Here we show further analysis of the Slab Ocean El Niño atmospheric feedbacks in coupled models. The BCCR_CM2.0 climate model from the CMIP3 data base, which has a very large equatorial cold bias, has an El Niño that is mostly driven by Slab Ocean El Niño atmospheric feedbacks and is used as an example to describe Slab Ocean El Niño atmospheric feedbacks in a coupled model. In the BCCR_CM2.0, the ENSO-related variability in the 20°C isotherm (Z20), a measure of upper ocean heat content, is decoupled from the first mode of the seasonal cycle-related variability, while the two are coupled in observations, with ENSO being phase-locked to the seasonal cycle. Further analysis of the seasonal cycle in Z20 using SODA Ocean Reanalysis reveals two different regimes in the seasonal cycle along the equator: The first regime, to which ENSO is phase-locked, extends over the west and central equatorial Pacific and is driven by subsurface ocean dynamics. The second regime, extending in observations only over the cold tongue region, is driven by the seasonal cycle at the sea surface and is shifted by roughly six months relative to the first regime. In a series of experiments with the Kiel Climate Model (KCM) with different mean states due to tuning in the convection parameters, we can show that the strength of the equatorial cold bias and the

  20. Temporal Evolution of the Nanostructure and Phase Compositions in a Model Ni-Al-Cr Alloy

    Science.gov (United States)

    Sudbrack, Chantal K.; Yoon, Kevin E.; Seidman, David N.; Seidman, David N.

    2006-01-01

    In a Ni-5.2 Al-14.2 Cr at.% alloy with moderate solute supersaturations and a very small gamma/gamma prime lattice parameter misfit, the nanostructural and compositional pathways during gamma prime(L12) precipitation at 873 K are investigated using atom-probe tomography, conventional transmission electron microscopy, and hardness measurements. Nucleation of high number densities (N(sub v) greater than 10(sup 23) per cubic meters) of solute-rich precipitates (mean radius = [R] = 0.75 nm), with a critical nucleus composition of Ni-18.3 plus or minus 0.9 Al-9.3 plus or minus 0.7 Cr at.%, initiates between 0.0833 and 0.167 h. With increasing aging time (a) the solute concentrations decay in spheroidal precipitates ([R] less than 10 nm); (b) the observed early-stage coalescence peaks at maximum N(sub v) in coincidence with the smallest interprecipitate spacing; and (c) the reaction enters a quasi-stationary regime where growth and coarsening operate concomitantly. During this quasi-stationary regime, the c (face-centered cubic)-matrix solute supersaturations decay with a power-law dependence of about -1/3, while the dependencies of [R] and N(sub v) are 0.29 plus or minus 0.05 and -0.64 plus or minus 0.06 at a coarsening rate slower than model predications. Coarsening models allow both equilibrium phase compositions to be determined from the compositional measurements. The observed early-stage coalescence is discussed in further detail.

  1. A model to non-uniform Ni Schottky contact on SiC annealed at elevated temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Pristavu, G.; Brezeanu, G.; Badila, M. [Electronics, Telecommunications and Information Technology, University Politehnica Bucharest, Bucharest 061071 (Romania); Pascu, R. [Electronics, Telecommunications and Information Technology, University Politehnica Bucharest, Bucharest 061071 (Romania); National Institute for Research and Development in Microtechnologies, Erou Iancu Nicolae Street 126A, 077190 Bucharest (Romania); Danila, M. [National Institute for Research and Development in Microtechnologies, Erou Iancu Nicolae Street 126A, 077190 Bucharest (Romania); Godignon, P. [Centro Nacional de Microelectronica, C/del Tillers, Campus Universitat Autònoma de Barcelona, 08193 Barcelona (Spain)

    2015-06-29

    Ni Schottky contacts on SiC have a nonideal behavior, with strong temperature dependence of the electrical parameters, caused by a mixed barrier on the contact area and interface states. A simple analytical model that establishes a quantitative correlation between Schottky contact parameter variation with temperature and barrier height non-uniformity is proposed. A Schottky contact surface with double Schottky barrier is considered. The main model parameters are the lower barrier (Φ{sub Bn,l}) and a p factor which quantitatively evaluates the barrier non-uniformity on the Schottky contact area. The model is validated on Ni/4H-SiC Schottky contacts, post metallization sintered at high temperatures. The measured I{sub F}–V{sub F}–T characteristics, selected so as not to be affected by interface states, were used for model correlation. An inhomogeneous double Schottky barrier (with both nickel silicide and Ni droplets at the interface) is formed by a rapid thermal annealing (RTA) at 750 °C. High values of the p parameter are obtained from samples annealed at this temperature, using the proposed model. A significant improvement in the electrical properties occurs following RTA at 800 °C. The expansion of the Ni{sub 2}Si phase on the whole contact area is evinced by an X-Ray diffraction investigation. In this case, the p factor is much lower, attesting the uniformity of the contact. The model makes it possible to evaluate the real Schottky barrier, for a homogenous Schottky contact. Using data measured on samples annealed at 800 °C, a true barrier height of around 1.73 V has been obtained for Ni{sub 2}Si/4H-SiC Schottky contacts.

  2. A model to non-uniform Ni Schottky contact on SiC annealed at elevated temperatures

    Science.gov (United States)

    Pristavu, G.; Brezeanu, G.; Badila, M.; Pascu, R.; Danila, M.; Godignon, P.

    2015-06-01

    Ni Schottky contacts on SiC have a nonideal behavior, with strong temperature dependence of the electrical parameters, caused by a mixed barrier on the contact area and interface states. A simple analytical model that establishes a quantitative correlation between Schottky contact parameter variation with temperature and barrier height non-uniformity is proposed. A Schottky contact surface with double Schottky barrier is considered. The main model parameters are the lower barrier (ΦBn,l) and a p factor which quantitatively evaluates the barrier non-uniformity on the Schottky contact area. The model is validated on Ni/4H-SiC Schottky contacts, post metallization sintered at high temperatures. The measured IF-VF-T characteristics, selected so as not to be affected by interface states, were used for model correlation. An inhomogeneous double Schottky barrier (with both nickel silicide and Ni droplets at the interface) is formed by a rapid thermal annealing (RTA) at 750 °C. High values of the p parameter are obtained from samples annealed at this temperature, using the proposed model. A significant improvement in the electrical properties occurs following RTA at 800 °C. The expansion of the Ni2Si phase on the whole contact area is evinced by an X-Ray diffraction investigation. In this case, the p factor is much lower, attesting the uniformity of the contact. The model makes it possible to evaluate the real Schottky barrier, for a homogenous Schottky contact. Using data measured on samples annealed at 800 °C, a true barrier height of around 1.73 V has been obtained for Ni2Si/4H-SiC Schottky contacts.

  3. The Adhesive Properties of Coherent and Semicoherent NiAl/V Interfaces Within the Peierls-Nabarro Model

    Directory of Open Access Journals (Sweden)

    Yaoyao Linghu

    2016-03-01

    Full Text Available The work of adhesion and the interface energy of NiAl/V coherent interface systems have been investigated using first-principles methods. The adhesion of the Ni-terminated interface is larger than the Al-terminated interface. The difference in charge density and the density of states show that the Ni-terminated interface is dominated by metallic bonds, and the Al-terminated interface is dominated by metallic and covalent bonds. To account for the effects of misfit dislocations on the semicoherent interfaces, the Peierls–Nabarro model combined with generalized stacking fault energy is employed to determine the interface energy. It is found that misfit dislocations can reduce the adhesion of the interface, and the reduction increases with the maximum of the restoring force.

  4. Modeling of Crevice Corrosion Stability of a NiCrMo Alloy and Stainless Steel

    Energy Technology Data Exchange (ETDEWEB)

    F.J. Presuel-Moreno; F. Bocher; J.R. Scully; R.G. Kelly

    2006-05-19

    Damage of structural significance from crevice corrosion of corrosion resistant alloys requires that at least a portion of the creviced area remain active over a sufficiently long period. Stifling results shen the aggressive chemistry required inside the crevice to keep the material depassivated, i.e., actively corroding, cannot be maintained. This loss of critical chemistry occurs when the rate of mass transport out of the crevice exceeds the rate of dissolution and subsequent hydrolysis of metal ions inside the crevice. For the treatment considered here, the mass transport conditions are constant for a given geometry and potential. What then controls the stability of the internal chemistry is the interaction between the electrochemical kinetics at the interface and the crevice chemistry composition. This work focuses on the parameters that control the stability of crevice corrosion by modeling the evolution of the chemical and electrochemical conditions within a crevice open only at one end (e.g. the mouth) in which the entire crevice is initially filled with the Critical Chemistry Solution (CCS) or filled with chemistries slightly less or more aggressive than the CCS. The crevice mouth is in contact with a weak acid solution (pH 3) that provides the boundary conditions at the crevice mouth. The potential at the mouth was held constant at +0.1 V{sub sce} in most instances with selected cases held at 0.0 V{sub sce}. The material selected was Ni-22Cr-6Mo alloy. The electrochemical kinetics at the pH values of interest have been recently characterized via potentiodynamic polarization. Figure 1 shows the polarization curves for Ni-22Cr-6Mo samples tested at room temperature in various HCl solutions. These data were used in all calculations. That is as the pH changed, a new polarization curve was applied to the position in the crevice. E, pH was calculated at each position and from this data, current at each position was determined. The effects of the crevice gap and

  5. Solubility Modeling of the Systems Ni(NO3)2–H2O and Fe(NO3)3Ni(NO3)2–H2O with the Extended Universal Quasichemical (UNIQUAC) Model

    DEFF Research Database (Denmark)

    Arrad, Mouad; Kaddami, Mohammed; El Goundali, Bahija

    2017-01-01

    Thermodynamic modeling of the binary systems Ni(NO3)2–H2O and Ni(NO3)2–H2O and of the ternary system of Fe(NO3)3–Ni(NO3)2–H2O along the 30 °C isotherm are presented. The extended UNIQUAC model was applied for the thermodynamic assessment of the investigated systems, the model parameters were...

  6. Modelling of phase diagrams of nanoalloys with complex metallic phases: application to Ni-Sn.

    Science.gov (United States)

    Kroupa, A; Káňa, T; Buršík, J; Zemanová, A; Šob, M

    2015-11-14

    A method for modelling of size-dependent phase diagrams was developed by combining the semiempirical CALPHAD method and ab initio calculations of surface stresses for intermetallic phases. A novel approach was devised for the calculation of surface energy, free of systematic errors from the selection of different parameters of the software (e.g. number of the k-points) and for handling layered structures and off-stoichiometric slabs. Our approach allows the determination of complex size-dependent phase diagrams of systems with intermetallic phases, which was not possible up to now. The method was verified for the modelling of the phase diagram of the Ni-Sn system and basic comparison with rare experimental results was shown. There is reasonable agreement between the calculated and experimental results. The modelling of size-dependent phase diagrams of real systems allows the prediction of phase equilibria existing in nanosystems and possible changes in material properties. There is a need for such knowledge and the existence of reliable data for simpler systems is crucial for further application of this approach. This should motivate future experimental work.

  7. Modelling the concentrations of dissolved contaminants (Cd, Cu, Ni, Pb, Zn) in floodplain soils.

    Science.gov (United States)

    Rennert, Thilo; Rabus, Widar; Rinklebe, Jörg

    2017-04-01

    Central European floodplain soils are often contaminated with potentially toxic metals. The prediction of their aqueous concentrations is a prerequisite for an assessment of environmental concerns. We tested the aqueous concentrations of cadmium (Cd), copper (Cu), nickel (Ni), lead (Pb) and zinc (Zn) derived from multi-surface adsorption modelling (on hydrous iron, aluminum and manganese oxides, clay and soil organic matter) against those analyzed in situ in the soil solution of four horizons of floodplain soils at the Elbe River, Germany. The input data for the reactive metals were derived from a seven-step sequential extraction scheme or from extraction with 0.43 M nitric acid (HNO3) and evaluated in four modelling scenarios. In all scenarios, measured and modelled concentrations were positively related, except partially for Pb. Close reproduction of the measured data was obtained using measured data of accompanying cations and anions together with amounts of reactive metals from both the sequential extraction or from 0.43 M HNO3 extraction, except for Cu, which was often strongly overestimated, and partially Cd. We recommend extraction with 0.43 M HNO3 to quantify reactive metals in soil because the modelling results were metal-specific with better or equal results using the single extractant, the application of which is also less laborious. Approximations of ion concentrations and water contents yielded similar results. Modelled solid-phase speciation of metals varied with pH and differed from that from sequential extraction. Multi-surface modelling may be an effective tool to predict both aqueous concentrations and solid-phase speciation of metals in soil.

  8. Two-spring model for active compression textiles with integrated NiTi coil actuators

    Science.gov (United States)

    Holschuh, B.; Newman, D.

    2015-03-01

    This paper describes the development and implementation of a two-spring model to predict the performance of hybrid compression textiles combining passive elastic fabrics and integrated NiTi shape memory alloy (SMA) coil actuators. An analytic model that treats passive fabric-SMA coil systems as conjoined linear springs is presented to predict garment passive and active counter-pressure as a function of 11 design variables. For a fixed SMA coil design (encompassing five design variables), the model predicts that passive fabric material modulus, initial length, width and thickness determine both passive counter-pressure magnitude and activation stroke length, and that passive and active pressures are highly dependent on the relative unstretched lengths of the conjoined SMA-fabric system compared to the total limb circumference. Several passive fabrics were tested to determine their moduli and to generally assess the fabric linearity model assumption: two fabrics (spandex and neoprene) were found to behave linearly up to 200% strain, while two other fabrics (flat polyester elastic and a tri-laminate Lycra) were found to be nonlinear in the same strain envelope. Five hypothetical compression tourniquet designs are presented using experimentally determined fabric characteristics and previously studied SMA actuators developed at MIT. The performance of each tourniquet design is discussed with a specific focus on mechanical counter-pressure (MCP) space suit design requirements, with designs presented that achieve the full MCP design specification (\\gt 29.6 kPa) while minimizing (\\lt 5 mm) garment thickness. The modeling framework developed in this effort enables compression garment designers to tailor counter-pressure and activation stroke properties of active compression garments based on a variety of design parameters to meet a wide range of performance specifications.

  9. First- and Second-Order Phase Transitions between the Uniform and FFLO Excitonic States in the Three-Chain Hubbard Model for Ta2NiSe5

    Science.gov (United States)

    Domon, Kaoru; Yamada, Takemi; Ōno, Yoshiaki

    2016-06-01

    We examine the free energy and the thermodynamic properties in the three-chain Hubbard model for Ta2NiSe5 to clarify the phase transitions between the uniform and the FFLO excitonic states which are expected to be observed in Ta2NiSe5 under high pressure.

  10. Modeling of half-Heusler compound NiMnSb within tight-binding approximation

    Science.gov (United States)

    Sugiyanto, Majidi, M. A.; Nanto, D.

    2017-07-01

    Heusler compounds are families of magnetic materials with general stoichiometry of either X2YZ (full-Heusler compound) or XYZ (half-Heusler compound), with X and Y being transition metal elements, and Z a main-group element. Their various potentials for technology development make them be still relevant as a subject of both experimental and theoretical studies. Half-Heusler compounds are generally crystallized in the C1b-type structure. The magnetic moments of such materials may be predicted using Slater-Pauling rule, giving m = (Nvalence electrons - 18)µB per formula unit. However, this simple counting rule does not always work for all compounds in this group. This motivates us to perform a theoretical study to investigate the mechanism of magnetic moment formation microscopically. As a case study, we focus on NiMnSb, a particular half-Heusler compound, for which comparison between existing experimental results and theoretical predictions of its magnetic moment has not yet been quite convincing. We model the system by constructing a tight-binding-based Hamiltonian, incorporating Hubbard repulsive as well as spin-spin interactions for the electrons occupying the d-orbitals. We solve the model using Green's function approach, and treat the interaction terms within the mean-field approximation. At this stage, we aim to formulate the computational algorithm for the overall calculation process. Our final goal is to compute the total magnetic moment per unit cell of this system and compare it with available experimental data.

  11. Microstructure Modeling of a Ni-Fe-Based Superalloy During the Rotary Forging Process

    Science.gov (United States)

    Loyda, A.; Hernández-Muñoz, G. M.; Reyes, L. A.; Zambrano-Robledo, P.

    2016-06-01

    The microstructure evolution of Ni-Fe superalloys has a great influence on the mechanical behavior during service conditions. The rotary forging process offers an alternative to conventional bulk forming processes where the parts can be rotary forged with a fraction of the force commonly needed by conventional forging techniques. In this investigation, a numerical modeling of microstructure evolution for design and optimization of the hot forging operations has been used to manufacture a heat-resistant nickel-based superalloy. An Avrami model was implemented into finite element commercial platform DEFORM 3D to evaluate the average grain size and recrystallization during the rotary forging process. The simulations were carried out considering three initial temperatures, 980, 1000, and 1050 °C, to obtain the microstructure behavior after rotary forging. The final average grain size of one case was validated by comparing with results of previous experimental work of disk forging operation. This investigation was aimed to explore the influence of the rotary forging process on microstructure evolution in order to obtain a homogenous and refined grain size in the final component.

  12. Mathematical Modeling of Pneumatic Artificial Muscle Actuation via Hydrogen Driving Metal Hydride-LaNi5

    Institute of Scientific and Technical Information of China (English)

    Thananchai Leephakpreeda

    2012-01-01

    Quantitative understanding of mechanical actuation of intricate Pneumatic Artificial Muscle (PAM) actuators is technically required in control system design for effective real-time implementation.This paper presents mathematical modeling of the PAM driven by hydrogen-gas pressure due to absorption and desorption of metal hydride.Empirical models of both mechanical actuation of industrial PAM and chemical reaction of the metal hydride-LaNi5 are derived systematically where their interactions comply with the continuity principle and energy balance in describing actual dynamic behaviors of the PAM actuator (PAM and hydriding/dehydriding-reaction bed).Simulation studies of mechanical actuation under various loads are conducted so as to present dynamic responses of the PAM actuators.From the promising results,it is intriguing that the heat input for the PAM actuator can be supplied to,or pumped from the reaction bed,in such a way that absorption and desorption of hydrogen gas take place,respectively,in controlling the pressure of hydrogen gas within the PAM actuator.Accordingly,this manipulation results in desired mechanical actuation of the PAM actuator in practical uses.

  13. Catalytic reforming of toluene as tar model compound: effect of Ce and Ce-Mg promoter using Ni/olivine catalyst.

    Science.gov (United States)

    Zhang, Ruiqin; Wang, Huajian; Hou, Xiaoxue

    2014-02-01

    Tar produced by biomass gasification as a route of renewable energy must be removed before the gas can be used. This study was undertaken using toluene as a model tar compound for evaluating its steam reforming conversion with three Ni-based catalysts, Ni/olivine, Ni-Ce/olivine and Ni-Ce-Mg/olivine. Effects of Ce and Mg promoters on the reaction activity and coke deposition were studied. Overall the performance of Ce and Mg promoted Ni/olivine catalysts is better than that of only Ce promoter and Ni/olivine alone. The experimental results indicate that Ni-Ce-Mg/olivine catalysts could improve the resistance to carbon deposition, enhance energy gases yield and resist 10ppm H2S poison at 100mLmin(-1) for up to 400min. Furthermore, the activity of catalysts was related to the steam/carbon (S/C) ratios; at S/C ratio=5, T=790°C, space velocity=782h(-1) and t=2h, the Ni-Ce-Mg/olivine system yielded 89% toluene conversion, 5.6Lh(-1) product gas rate, 62.6mol% H2 content and 10% (mol useful gas mol(-1) toluene) energy yield. Moreover, at low S/C ratio, it had higher reaction activity and better ability to prevent coking. There is a small amount of carbon deposition in the form of amorphous carbon after 7h. Various characterization techniques such as XRD, FTIR and thermogravimetric were performed to investigate the coke deposition of Ni/olivine, Ni-Ce/olivine and Ni-Ce-Mg/olivine. It is suggested that 3% Ni-1% Ce-1% Mg/olivine was the most promising catalyst due to its minimum coke amount and the lower activation energy of coke burning.

  14. Modeling and Characterization of the Magnetocaloric Effect in Ni2MnGa Materials

    Energy Technology Data Exchange (ETDEWEB)

    Nicholson, Don M [ORNL; Odbadrakh, Khorgolkhuu [ORNL; Rios, Orlando [ORNL; Hodges, Jason P [ORNL; Ludtka, Gerard Michael [ORNL; Porter, Wallace D [ORNL; Sefat, Athena Safa [ORNL; Rusanu, Aurelian [ORNL; Evans III, Boyd Mccutchen [ORNL

    2012-01-01

    Magnetic shape memory alloys have great promise as magneto-caloric effect refrigerant materials due to their combined magnetic and structural transitions. Computational and experimental research is reported on the Ni2MnGa material system. The magnetic states of this system have been explored using the Wang-Landau statistical approach in conjunction with the Locally Self-consistent Multiple-Scattering (LSMS) method to explore the magnetic states responsible for the magnet-caloric effect in this material. The effects of alloying agents on the transition temperatures of the Ni2MnGa alloy were investigated using differential scanning calorimetry (DSC) and superconducting quantum interference device (SQUID). Neutron scattering experiments were performed to observe the structural and magnetic phase transformations at the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory (ORNL) on alloys of Ni-Mn-Ga and Ni-Mn-Ga-Cu-Fe. Data from the observations are discussed in comparison with the computational studies.

  15. Geology, Mineral Deposit Model and Potential of the Suwar Cu-Ni Sulphide Prospect, Northwest Yemen

    Institute of Scientific and Technical Information of China (English)

    Abdulkarim M.; Al-Nagashi; Li Xujun

    2002-01-01

    The Suwar Cu-Ni sulphide prospect is very highly regarded for its potential to host a major nickel-copper sulphide deposit in Republic of Yemen, a mineral resource lacking country. The ore-hosting intrusion is a lopolith about 6km long and lkm wide and more than 300m deep. There are two types of Cu-Ni mineralizations in the prospect: primary massive chalcopyrite+ pyrrhotite+ pentlandite controlled by gravitational and structural traps while the secondary Cu-Ni mineralization is coarse grained and occur as veins, veinlets, fracture fill, blebs or associated with coarse, re-crystallized carbonate in shear zones and faults. The deposit type of the prospect is believed to be the one associated with the ultramafic component of a large, broadly differentiated noritic, gabbroid intrusive. It is suggested that the prospect and adjacent area possibly contain a similar world class Ni-Cu deposits as that in Jinchuan, China.

  16. Atomic scale modelling of Al and Ni(1 1 1) surface erosion under cluster impact

    CERN Document Server

    Zhurkin, E E

    2003-01-01

    We have studied sputtering of Al and Ni(1 1 1) surfaces under impact of Al sub N and Ni sub N clusters (1=13. The pronounced microcraters are formed in the impact region above a threshold cluster size of around N=13. As a sensitivity study, we show that interaction with electronic subsystem of the target has a strong influence on secondary emission, but almost does not affect the features of surface microstructure of irradiated target.

  17. Modeling of Ni Diffusion Induced Austenite Formation in Ferritic Stainless Steel Interconnects

    OpenAIRE

    Chen, Ming; Molin, Sebastian; Zhang, L.; Ta, Na; Hendriksen, Peter Vang; Kiebach, Wolff-Ragnar; Du, Y

    2015-01-01

    Ferritic stainless steel interconnect plates are widely used in planar solid oxide fuel cell (SOFC) or electrolysis cell (SOEC) stacks. During stack production and operation, nickel from the Ni/YSZ fuel electrode or from the Ni contact component diffuses into the IC plate, causing transformation of the ferritic phase into an austenitic phase in the interface region. This is accompanied with changes in volume and in mechanical and corrosion properties of the IC plates. In this work, kinetic mo...

  18. Report on research results of the development of high efficient boilers in fiscal 1996. Research development of high efficient industrial furnaces, etc; Koseino boiler no kaihatsu ni kansuru kenkyu seika hokokusho. Koseino kogyoro nado ni kansuru kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Out of the developments of high efficient boilers which have been continued since fiscal 1993, the paper reported the result of the development conducted in fiscal 1996. The oxygen combustion (the oxygen enrichment combustion including 100% oxygen combustion) decreases the amount of flue gas and reduces heat loss of the flue gas, and is also effective as NOx reduction measures. The experiment was conducted using testing furnace. The boiler efficiency rapidly increased with the increasing concentration of oxygen enrichment. In the pure oxygen combustion, the overall boiler efficiency of a 106% level (low heating value standard) is expected. Since the boiler wet flue gas is decreased, the NOx emission is reduced. The boiler can raise the combustion temperature with no fear of NOx and can be reduced in size. CO2 decreases in proportion to the energy saving effect. The development of a condensation flue gas heat exchanger is aimed at recovering heat down to the low temperature. Prediction of heat transfer in the steam condensation region becomes possible, and the size reduction can be expected. Dew point corrosion resistant materials were also selected. As to the high speed combustion control, a simple type using micro-processor was developed. Obtained were high speed, compactness, electric power saving, and high controllability. 14 refs., 306 figs., 88 tabs.

  19. Simple method for analizing multi-leg-structures. 3. ; Study on the lateral vibration of the off-shore structure. Takyaku kozobutsu no kan prime i kaisekiho ni kansuru ichikosatsu. 3. ; Kaiyo kozobutsu no yokoshindo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Kan, K.; Aso, K.; Doki, H. (Akita Univ., Akita, (Japan). Mining College)

    1990-04-25

    The lateral vibration of the off-shore structure constructed with 8-12 legs was analized. Furthermore, the validity of this method was experimentally examined. The results are as follows: The values of natural frequency and displacement for each structure vibrating in water are independent of the direction of vibration within the ranges of the leg-intervals and the dimentions of legs. The natural frequency obtained by the proposed mehtod, which utilizes two theories, coincides very well with the experimental frequency within the error range that is about 0.00-1.36%. Furthermore, the method in this study gives the fairly well estimation with respect to the amplitude of the lateral vibration, since the error involved in the estimation is only about 9.80-13.7% until the fifth period of vibration. The values of the frequency or displacement estimaated by two theories give the almost same degree of the error range. 4 refs., 13 figs., 3 tabs.

  20. Theoretical models for a complex magnetic system: The case of CeNi{sub 1-x}Cu{sub x}

    Energy Technology Data Exchange (ETDEWEB)

    Marcano, N [Departamento de Fisica de la Materia Condensada, ICMA, CSIC-Universidad de Zaragoza, 50009 Zaragoza (Spain); Magalhaes, S G [Universidade Federal de Santa Maria, Santa Maria, Rio Grande do Sul 97105-900 (Brazil); Coqblin, B [L.P.S., CNRS UMR 8502, Universite Paris-Sud, 91405-Orsay (France); Sal, J C Gomez; Espeso, J I [Departamento CITIMAC, Universidad de Cantabria, 39005 Santander (Spain); Zimmer, F M [Departamento de Fisica, Universidade do Estado de Santa Catarina, 89223-100, Joinville, SC (Brazil); Iglesias, J R, E-mail: marcanon@unizar.e [Instituto de Fisica, Universidade Federal do Rio Grande do Sul, 91501-970 Porto Alegre (Brazil)

    2010-01-15

    Special features in the phase diagram and in the low temperature hysteresis cycles have been experimentally observed in the complex CeNi{sub 1-x}Cu{sub x} system. We present also here theoretical approaches, based firstly on a Kondo lattice model which describes the coexistence between a spin glass or a cluster glass state, the Kondo regime and the ferromagnetic ordering. The second model is a Monte Carlo simulation on a 3D lattice with clusters and random anisotropy and reproduces the existence of steps in the magnetizations cycles at very low temperatures. The theoretical results are compared with the experimental data of the very complex magnetic behaviour of CeNi{sub 1-x}Cu{sub x} alloys. In particular, we can account for the existence of a cluster spin glass state which changes continuously into an inhomogeneous ferromagnetic phase at very low temperatures.

  1. Domain model for the magnetic shape-memory effect in non-modulated tetragonal Ni-Mn-Ga

    Energy Technology Data Exchange (ETDEWEB)

    Onisan, A T; Bogdanov, A N; Roessler, U K, E-mail: u.roessler@ifw-dresden.de [IFW Dresden, Postfach 270116, D-01171 Dresden (Germany)

    2011-07-06

    We employ a general phenomenological domain theory for ferromagnetic shape memory (FSM) materials to model equilibrium domain states in martensites with tetragonal twin variants having axes ratios c/a > 1 and easy-plane magnetic anisotropy. The model is evaluated for realistic material parameters of non-modulated (NM) Ni{sub 2}MnGa alloys. Phase diagrams under competing external stresses and magnetic fields are presented that show regions of fully magnetized single-variant states and various multiphase regions. The theoretical elastic stresses that block single-variant states are found to be much smaller in NM than in the 5M structure of Ni{sub 2}MnGa alloys.

  2. Large scale shell model calculations along Z=28 and N=50 closures: towards the doubly-magic 78Ni

    CERN Document Server

    Sieja, K

    2012-01-01

    We present the state-of-the art shell model calculations in a large model space (pf for protons, fpgd for neutrons), which allow to study simultaneously excitations across the Z=28 and N=50 shell gaps. We explore the region in the vicinity of 78Ni, being a subject of intense experimental investigations. Our calculations account correctly for the known low lying excited states in this region, including those which may correspond to cross-shell excitations. We observe the minimum of the N=50 mass gap at Z=32 consistent with experimental data and its further increase towards Z=28, indicating a robustness of the N=50 gap in 78Ni. The evolution of N=50 gap along the nickel chain is shown to bear similarities with what is know in oxygen and calcium chains, providing a new opportunity for the studies of 3-body monopole effects in medium mass nuclei.

  3. A quantitative mechanistic description of Ni, Zn and Ca sorption on Na-Montmorillonite. Part III: Modelling

    Energy Technology Data Exchange (ETDEWEB)

    Baeyens, B.; Bradbury, M.H. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1995-07-01

    Titration and sorption measurements, carried out under a wide variety of conditions on Na-montmorillonite, were examined in terms of cation exchange and surface complexation mechanisms. A computer code called MINSORB was developed and used throughout this work. This code allowed the uptake of radionuclides by both mechanisms to be calculated simultaneously; also taking into account competitive reactions from other cations present. A stepwise iterative fitting/modelling procedure is described. For the case of Na-montmorillonite it is demonstrated that an electrostatic term in the surface complexation model is not required. A basic data set comprising of site capacities and protonation/deprotonation constants was defined, which was valid for all surface complexation sorption reactions. The main study was carried out with Ni, but impurity cations present in the system, particularly Zn, had to be examined in addition due to their competitive effects on Ni sorption. The surface complexation behaviour of Ni and Zn was investigated in detail to give intrinsic surface complexation constants on two of the {identical_to}SOH type sites included in the model. The sorption of Mg, Ca and Mn is also considered, though in less detail, and estimated surface complexation constants for these nuclides are presented. Cation exchange was included in all of the calculations. Measured selectivity coefficients for Ni-Na, Zn-Na and Ca-Na exchange reactions are given. The model, with the derived parameters, allowed all the data from titration measurements through sorption edges to sorption isotherms to be calculated. (author) 31 figs., 9 tabs., refs.

  4. Coulomb excitation $^{74}$Zn-$^{80}$Zn (N=50): probing the validity of shell-model descriptions around $^{78}$Ni

    CERN Multimedia

    A study of the evolution of the nuclear structure along the zinc isotopic chain close to the doubly magic nucleus $^{78}$Ni is proposed to probe recent shell-model calculations in this area of the nuclear chart. Excitation energies and connecting B(E2) values will be measured through multiple Coulomb excitation experiment with laser ionized purified beams of $^{74-80}$Zn from HIE ISOLDE. The current proposal request 30 shifts.

  5. Nonlocal superelastic model of size-dependent hardening and dissipation in single crystal Cu-Al-Ni shape memory alloys.

    Science.gov (United States)

    Qiao, Lei; Rimoli, Julian J; Chen, Ying; Schuh, Christopher A; Radovitzky, Raul

    2011-02-25

    We propose a nonlocal continuum model to describe the size-dependent superelastic effect observed in recent experiments of single crystal Cu-Al-Ni shape memory alloys. The model introduces two length scales, one in the free energy and one in the dissipation, which account for the size-dependent hardening and dissipation in the loading and unloading response of micro- and nanopillars subject to compression tests. The information provided by the model suggests that the size dependence observed in the dissipation is likely to be associated with a nonuniform evolution of the distribution of the austenitic and martensitic phases during the loading cycle.

  6. Approaches of Japan and Western nations to automobile fuel consumption improvement; Jidosha nenpi kaizen ni kansuru Nippon Obei no torikumi

    Energy Technology Data Exchange (ETDEWEB)

    Hoshino, M. [Japan Automobile Manufacturers Association Inc., Tokyo (Japan)

    1996-04-01

    Some views are expressed toward the improvement of automobile fuel consumption. There is no need to give up the convenience that the automobile offers for the purpose of energy-saving. What is needed is the effective use of energy, and the most important technological tasks in this connection is the improvement of fuel consumption. Thanks to the efforts exerted by Japanese businesses, and to reduction in automobile size and improvement on engine performance in the Western countries, fuel consumption has steadily improved, only to reach a level where no more large-scale progress is expected without innovative technologies. For example, the adoption of the lean-burn system for higher performance will deteriorate the convenience that automobiles offer and efforts for lightening automobile bodies will encounter constraints (germane to recycling and pricing) in choosing proper materials. This report also evaluates alternate-energy automobiles and comments on Japan`s decision on its fuel consumption improvement targets. 4 figs., 4 tabs.

  7. Experimental studies for the vertical-axis wind turbine. Suichokujiku fusha no suiryoku ni kansuru kiso kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Mashige, M.; Kakita, Y.; Ushiyama, I. (Ashikaga Institute of Technology, Tochigi (Japan))

    1992-06-01

    Studies are made on wind direction component force, that is, thrust exerted on the rotor of a vertical-axis wind turbine by the wind tunnel experiment. Wind turbines tested are eight including 7 drag types and 1 lift type. Setting the wind velocity at 6 and 8m/second, braking gradually from the no-load condition and varying the revolution number till arriving at the stationary state, torque and thrust in arbitary yevolution numbers are measured. The thrust coefficient which is the dimensionless thrust is smaller at resting than at revolving, except for cross-flow type and straight Darrieus rotors. Flat plate, curved-plate and savonius types increase in operational peripheral speed ratio (ratio of tip peripheral speed to wind velocity) field by setting upper and lower discs, but shows no difference in the thrust coefficient. In the vertical-axis wind turbine, there is no clear relationship between thrust characteristic and torque characteristic. Measured values of wake wind velocity distribution by the pilot tube show a slight difference between in the no-load condition and in the load condition, but no difference is seen in the visualization experiment using polyester string. 3 refs., 9 figs.

  8. Experimental studies for the vertical-axis hybrid wind turbine; Suichiyokuziku haiburiddo hoshiki fusya ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Ito, M.; Ushiyama, I. [Ashikaga Institute Of Technology, Tochigi (Japan); Inoh, M.; Hiroki, T. [NihondenkiSeiki Corp., Tokyo (Japan)

    1997-06-01

    Advantages and disadvantages of Darrieus type and Savonius type turbines as the wind energy generation system are described and the above-titled wind turbine is proposed to improve the drawback of poorer output performance in case of hybrid of these 2 types than that of independent Darrieus type. The layout of wind channel equipment and the hybrid system of conventional direct type and that of the clutch type prototype are explained with consideration on the test results. When compared 2 blades of 136mm chord length to 3 blades of 90mm chord length in terms of torque and power properties, the prototype showed a performance for the both properties 20% better than those of conventional type, particularly in the case of 3 blades, both the maximum power and the torque coefficients became about half of those of 2 blades. Further, a prototype wind turbine was designed and fabricated according to the theory of single tube of flow with regard to the straight Darrieus type and tested in association with Savonius type turbine as well as the latter alone and the results for each case were compared and examined. As for the conclusion, the usefulness of clutch connection and its effect of improvement became more remarkable along with the increase of wind speed and so forth are indicated. 7 refs., 14 figs., 2 tabs.

  9. Numerical simulation for Savonius rotors. ; Running performance and flow fields. Savonius fusha ni kansuru suchi keisan. ; Unten tokusei to nagareba

    Energy Technology Data Exchange (ETDEWEB)

    Ishimatsu, K.; Shinohara, T. (Oita University, Oita (Japan). Faculty of Engineering); Takuma, F. (Kyushu Matsushita Electric Co. Ltd., Tokyo (Japan))

    1994-01-25

    This paper reports numerical calculations on flow around Savonius wind turbine (rotating) with blades in a semi-circular shape and their output characteristics. The two-dimensional non-compressive Navier-Stokes equations were discretized by a fractional step method with regard to time, and by a finite volume method using non-structural grids with regard to space. Upon the discretization, the flow field in a region 20 times as large as the wind turbine diameter was analyzed for the cases that the Reynolds number is 10[sup 5], the ratios of clearance between two blades to the blade diameter are zero and 0.16, and the circumferential velocity ratio is in a range from 0.25 to 1.75. The paper describes the result as follows: the circumferential velocity ratio when the output is at a maximum is slightly smaller than one, and the circumferential velocity ratio when the output is zero is about 1.7, which agree approximately with values in the previous experiments on the circumferential velocity ratio and output; and vortices are discharged also from rear of the blades in addition to from tips of the blades. Several examples of flow fields as seen from static coordinates are illustrated. 4 refs., 11 figs.

  10. Experimental studies on a Savonius rotor with casing; Casing wo motsu Savonius gata turbine no tokusei ni kansuru jikkenteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Tan, S. [Tsuruoka National College of Technology, Yamagata (Japan); Shimizu, Y. [Mie University, Mie (Japan). Faculty of Engineering; Kikuyama, K. [Nagoya University, Nagoya (Japan). Faculty of Engineering

    1997-07-25

    The Savonius turbine, which works at low rotatory speeds and gives a high degree of torque, has been used for a wind turbines. In order to examine the feasibility of applying the turbine as a wave energy conversion system, a Savonius rotor was installed in a casing and its performance was studied experimentally to examine the various geometrical configurations of the rotor and casing. When optimally configured, the turbine exhibits higher efficiency than a wind turbine without a casing during steady flow conditions. 6 refs., 17 figs., 1 tab.

  11. Researches and studies about technological trend of `functionally gradient materials`; Keisha kino zairyo no gijutsu doko ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Morishima, H. [Information Center of Exploitation of Petroleum, Tokyo (Japan)

    1995-09-01

    Introduced herein is a summary of the technological research report about functionally gradient materials that was presented by Information Center of Exploration of Petroleum in fiscal 1994. The functionally gradient material was realized in the 1980s thanks to more than 30 technologies industrial or government sector bodies interested in science and technology, which effort was related to Japan`s recoverable manned spaceplane program. The material, equipped with the high thermal conductivity and mechanical strength required of a material to cover the spaceplane body, was born out of a innovative idea in which the constitution, etc., of two different materials should continuously change for the elimination of any boundary between the two now that a direct bondage of a metal and ceramics would after all experience separation or cracking. The new idea enabled a plurality of desired functions to be freely distributed within the material, creating hopes in various fields. It has been found that probabilities are high that the functionally gradient material will improve at a surprising rate the conversion rate in utilizing thermoelectricity, photoelectricity, or nuclear energy. In the oil industry, studies are under way to use the new material in petroleum exploration, etc., that have to be undertaken under severe conditions. 1 ref., 2 figs., 2 tabs.

  12. Research on EBEP (Electron Beam Excited Plasma) applications; EBEP (denshi beam reiki plasma) no tekiyo gijutsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Yanase, E.; Ryoji, M.; Mori, Y.; Tokai, M. [Kawasaki Heavy Industries, Ltd., Kobe (Japan)

    1996-04-20

    Research and development is actively conducted on machining technologies using plasma in various fields, with studies energetically pursued on etching techniques or those of forming a thin film by the use of high frequency and microwave plasma. The EBEP system jointly developed by Kawasaki Heavy Industries Ltd. and Institute of Physical and Chemical Research is a plasma source for forming a high density plasma by implanting into a plasma chamber from the outside a high-current electron beam accelerated to an energy of approximately 60 to 100eV where the collision cross-section of gas ionization is maximized. The characteristics of the system are such as (1) it enables electron energy distribution to be controlled from outside by varying acceleration voltage, (2) it excels in the controllability of ion energy and (3) it allows to form a steady high-density plasma in a nonmagnetic field. This paper presents the generating principle of EBEP, its plasma characteristics, etching technique using EBEP, thin film forming technique by EBEP-CVD method, and multipurpose apparatus for research and development. 6 refs., 7 figs., 1 tab.

  13. Comparison about the bone material examination of JIS and ISO; Honezai shiken ni kansuru JIS to ISO no hikaku

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Sumie.; Yanagi, Kei.; Shimura, Akiharu.; Murohoshi, Shiori. [Japan Testing Center for Construction Materials, Tokyo (Japan)

    1998-12-01

    There are various things in slug bone material and so on manufactured from the macadam, crumble sand. Which crushed rock including gravel, sand to produce in the nature and which was manufactured, and a lightweight bone material and the industry by-product with the bone material used for the concrete. It is necessary with a bone material to grasp the nature of the bone material itself properly to occupy about 70% of the capacity in the concrete and to manufacture the good concrete of the quality from the influence that influence to the various concrete materiality that quality being big. When the quality of a bone material to use for the concrete is confirmed, an examination is being done in accordance with the way of examining it established as the Japanese industry standard in our country. (NEDO)

  14. Basic research on the carbon dioxide fixation using seaweed. Kaisorui no tansan gas kotei ni kansuru kiso kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, M.; Ishihara, T. (The Kansai Electric Power Co. Inc., Osaka (Japan))

    1993-08-25

    Study was made for grasping the basic data of CO2 fixation technology by seaweed. The photosynthesis under the sea, which is different from that on the land, is judged to be made by taking in HCO3[sup -] and converting it into CO2 inside the plant. Porphyra yezoensis which is seaweed is cultivated as comestible. With a rise in CO2 content, the growth in length of leaves was observed to be accelerated through ventilating Porphyra yezoensis with the three test types of air which respectively contained 350ppm (atmospheric CO2 content), 1000ppm and 1600ppm CO2. As a result of measuring the photosynthesis speed by the generated quantity of O2, it was heightened with a rise in dissolved inorganic carbonic acid content of the sea water. Measurement was also made of daily fluctuation in calcification speed by Corallina officinalis capable of calcification by ventilating it with 350ppm and 1600ppm CO2. In case of 1600ppm, the sedimentation of CaCO3 was prevented. In case of 350ppm, the sedimentation was quantitatively larger during the bright period than that during the dark period. The growth of Gracilaria gigas which is an agar material was compared by changing the above CO2 levels. In case of 1600ppm, the weight grew to 2.3 times in 20 days. 16 figs., 2 tabs.

  15. Report on Asian Environment Information Network; 'Asia kankyo joho network' ni kansuru hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The goal is the construction of Asian Environment Information Network (AEInet) in accordance with a contract signed between Indonesia's LIPI (Indonesian Institute of Science) and NEDO under NEDO's Research Cooperation Project Concerning the Development of Environment Measuring Laser Radar (LR). The network is so designed and constituted as to operate on a private line between Indonesia and Japan via IP (Internet protocol) and to enable the exchange on the Internet network of the data collected/analyzed by the Indonesian LR system and of articles of e-mail between scientists of the two countries. The AEInet will be utilized for the collection/analysis of LR-collected data; exchange of observed data and the result of processing; provision of support to environment information scientists in exchanging e-mail and information; and the search of databases for the implementation of the project. In this paper, the outline and functions of the system, network system design, WWW server construction, network operating status, joint researches with Indonesia, etc., are described. (NEDO)

  16. Survey on bio-chemical complex harmonized with global environment. 3; Kankyo chowagata seibutsu kagaku konbinato ni kansuru chosa. 3

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    A survey was conducted of bio-chemical complex harmonized with the global environment for the purpose of constructing the material production process harmonized with the environment by the process fusion between biological conversion and chemical reaction. Palm oil was taken up as renewable raw material plant resource. The process utilizing bio-chemical reaction advances at normal temperature and pressure and is high in reaction specificity and selectivity. This is a recycling, circulation and environmental harmony type production technology which brings high yield, energy conservation, resource conservation, and low environmental loads. Waste water treatment and production of useful substances from sludge were thought as elementary technology. A possibility was studied of enzyme production by culturing solid waste, and the enzyme was applied to the hydrolysis process. The paper indicated trace components in the palm oil and the extraction method and proposed the production process of new derivatives for adding value to hydrolysate. A study was also made of the overall process flow which integrated these new processes and the material balance. The comprehensive evaluation of this new process was made from the aspect of the product structure, the market, construction cost, economical efficiency, and the environment. 133 refs., 65 figs., 56 tabs.

  17. Investigation of heat transfer characteristics of finned tubes in an air cooler; Kuki reikyakuki no dennetsu tokusei ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Akiyoshi, R.; Hori, M.; Ishida, H.; Hagiwara, K. [Ishikawajima-Harima Heavy Industries Co. Ltd., Tokyo (Japan)

    1997-03-01

    Heat transfer characteristics of a multitubular heat exchanger are investigated for the purpose of continuously cooling air below 0{degree}C. The air duct used in the test is rectangular, 302mm in width and 322mm in height, made of an acrylic resin so that the frosted part may be seen by the eyes and that transmission of heat from the duct into the air may be suppressed. The heat transfer tube is a horizontal tube provided with fins. The refrigerant is a brine kept at a specified temperature, supplied to the most downstream row of the heat transfer tube to run in series so that it will flow contrary to the air. Under the conditions where the steam in the air does not condense, the heat transmission rate increases along with the air speed, quantatively agreeing with what has been obtained in the past. Under the conditions where the steam in the air condenses, the heat transmission rate is two times higher than the rate in the case of no condensation when the air speed is low and, when the air speed is high, approximately equal to the rate in the case of no condensation. Between the two, there is a domain where the heat transmission rate decreases with an increase in the air speed. Spraying the brine on the heat transfer tube prevents frosting even when the heat transfer surface temperature is 0{degree}C or lower, letting heat through. 9 refs., 6 figs.

  18. Fiscal 1995 investigation on biological fixation of carbon dioxide; 1995 nendo seibutsuteki CO2 kotei ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    To cope with the global warming caused by CO2, an investigation was conducted into biological fixation. It is necessary to make a many-sided and comprehensive study on the mechanism of CO2 fixation, the scale (area and carbon holding density), the rate and the environmental impact of the introduction of the technology and the technical problems, and to make a quantitative evaluation of each of the methods in order to make them practical proposals. The global ecosystem is classified into the land biota and ocean biota, and each typical ecosystem was surveyed in terms of the surface area, the carbon holding amount (presently existing amount), the net primary production amount, the required nutrient salt amount, the transpiration rate, etc. Next, a discussion was made on the increasing effect of the carbon fixation amount by changing the present ecosystem from the aspect of scale and rate. At the same time, a study was carried out of energy efficiency, economical efficiency and problems. Last, elementary technology was taken up which seems to be important for implementing measures for the biological carbon fixation. As to the ocean, it is necessary to obtain information, which is not sufficient to utilize marine biota for CO2 fixation, especially on the mechanism of depth-direction transfer of organism and its quantitative grasp. As to the land, one of the measures is conversion of the ecosystem where the amount of carbon fixed is small to the ecosystem where the amount is large. 249 refs., 58 figs., 51 tabs.

  19. Consideration on fatigue strength of corroded steel plates; Fushoku suimo koban no hiro kyodo ni kansuru ichikosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Iwata, M.; Yajima, H.; Yamamoto, M.; Saito, T. [Hiroshima University, Hiroshima (Japan). Faculty of Engineering

    1996-10-01

    Discussions were given on fatigue strength of corroded steel plates taken from a hull of a ship seventeen years old after construction. The steel plates have had their original thickness of 13 mm reduced to 5.3 to 8.3 mm. After having been cut by a machine, the steel plates were used for tests as ground plates after going through grinding and as corroded plates with rust remaining on them. The fatigue test was performed in artificially made sea water at a temperature of 25{degree}C and in air with axial power pulsating tensile load and at iterative loading velocities of 3 to 5 Hz. The corroded material test verified that corrosion pits exist innumerably on the test piece surface and fatigue cracks have been developed and grown from bottoms of the pits. The stress concentration coefficient of the corrosion pits was about 1.9. Good agreement with the test result was found in the S-N chart in which the number of iteration of fracture was regarded as the number of iteratively generated cracks, and notch coefficient was estimated as 1.9. These results proved that the fatigue strength assessing method for virgin materials can be applied also to steel plates which have been exposed to corrosive environment for extended periods of time. 5 refs., 7 figs., 1 tab.

  20. Study on a method to set design hydrographic conditions; Sekkei kaisho no setteiho ni kansuru kenkyu. 2

    Energy Technology Data Exchange (ETDEWEB)

    Toki, N. [Mitsubishi Heavy Industries, Ltd., Tokyo (Japan)

    1996-10-01

    Analyses were performed recently on results of observations having been carried out by the U.S. National Oceanic and Atmospheric Administration (NOAA) and the Japanese Meteorological Agency by using wave observation buoys. Wave observation database with high reliability has become publicized in the same format as the conventional wave generation frequency data. In order to obtain rational base for a method to set hazardous sea areas, the present study has attempted to express as a function of the average wave cycle a maximum value of significant wave heights which can be generated based on these data. What were derived include observations by the NOAA over large areas, such as Alaskan coasts, Mexico Bay and Five Great Lakes, the results of discussions by the Meteorological Agency on data including wave observations at five locations in neighboring waters in Japan, and the relationship between the maximum value of significant wave heights that can be generated and the average cycle. Deriving the standard deviation per unit wave height by computing short time estimation from the above data, and deriving combination of the average cycle with angles of encounter can present the design hydrographic conditions (hazardous hydrographic conditions). The future would require not only investigations and discussions from the viewpoint of the maximum value that can occur, but also from the viewpoint of determination of limitations of vessel operations. 5 refs., 5 figs.

  1. Study on thermochemical liquefaction of biomass feedstocks; Biomass genryo no yuka hanno tokusei ni kansuru kisoteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-02-10

    Liquefaction is applied to various biomass wastes and unused biomass to study characteristics of the liquefaction in each case. The paper described the system of the conversion and use of biomass into energy, conducted the positioning of the liquefaction, and outlined a history of the liquefaction chemistry and the study. To obtain basic data of characteristics of the liquefaction of various biomass raw materials, the liquefaction was conducted changing operational factors for the purpose of clarifying the product distribution of oil and by-products and oil properties. A comprehensive consideration was made of the liquefaction based on basic data and literature reports on the liquefaction of various biomass. From the above-mentioned studies, it was concluded that the energy can be recovered in a form of oil by applying the liquefaction to various biomass materials. A series of the study clarified effects of various operational factors on characteristics of the liquefaction as well as effects of classification of biomass materials and composition of the materials on characteristics of the liquefaction. 141 refs., 78 figs., 56 tabs.

  2. Studies on functional network of transcriptional coactivator CBP; Tensha jono inshi CBP no kinoteki nettowaku ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Fukamizu, Akiyoshi [University of Tsukuba, Ibaraki (Japan). Institute of Applied BIochemistry

    1999-12-16

    CBP/p 300 is a multidomain transcriptional cofactor which acts in junction with other factors to regulate transcription. To elucidate the domain function of CBP, we fused its dissected fragments to Gal 4 DNA-binding domain and transfected the deletion mutants into several cell lines. First, we found that the minimal transactivation domain (MTD) at the N-terminal portion maps to between 344-451 aa, and shows activity in a cell-type dependent manner. Second, by means of the yeast two hybrid screening using CBP fragments as baits, we cloned hypoxia-inducible factor (HIF) 1{alpha}, Stat 2, and hepatocyte nuclear factor 4 (HNF 4) cDNAs. These results suggested a functional role of MTD located at the CBP/p 300 N-terminal region in connecting to transcriptional factors and a physiological significance of complexes formed in response to a variety of extracellular stimuli to the nucleus. (author)

  3. Investigational study on construction of the physical function database; Shintai kino data base no kochiku ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    An investigational study was carried out on construction of the physical function database which can supply data useful for planning, design and production when companies provide products and barrier-free environment for the aged society. Up to now, the final image of database was studied as to the visual function. In addition, this study is aimed at constructing the physical function database. In the literature survey, basic data on physical characteristics of the aged which have lain scattered were collected and systematically sorted in relation to the exercise function in order to make an analysis of the data and measuring technology in terms of reliability, importance, and applied values. In the survey of corporate needs, an examination of concrete needs for the exercise function and auditory function was made for general companies and companies related to the medical and welfare apparatus field. As to the visual function, a study was conducted on selection of new items for visual measurement and measuring methods. In the study of the database structure, a pilot database was constructed and subjects were extracted. 529 refs., 57 figs., 15 tabs.

  4. Research trend survey on the stable isotope utilization technology; Antei doitai no riyo gijutsu ni kansuru kenkyu doko chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This report reviews the activities and the trends in the area of the stable isotope use attracting attention recently. In the medicine and clinical treatment sector, the remarkable trends are the extension of {sup 13}C use. The breath test and the magnetic resonance spectroscopy (MRS) diagnosis have been developed as inspection methods. It is noted that investigation has been initiated on the magnetic resonance imaging (MRI) using {sup 3}He and {sup 129}Xe for the lung imaging. In the organic chemistry and biochemistry sector, the stable isotopes are used for analyzing the structures of complicated natural compounds and materials relating to life science and for analyzing the chemical reaction mechanism of organic compounds. In the nuclear energy sector, {sup 10}B and {sup 7}Li have been used as neutron absorption materials and pH neutralizing reagent, respectively. In the analysis and measurement sector, the process of isotopic dilution is used for the environmental analysis of trace elements including harmful substances. Among various separation methods of isotopes, well studied uranium enrichment processes and deuterium separation processes are described. Separation of {sup 15}N by ion exchange resin method and plasma ion cyclotron resonance (ICR) isotope separation have been studied, recently. 133 refs., 53 figs., 7 tabs.

  5. Indoor environment and allergy except housedust mite; Jukankyo to allergy ni kansuru dani igai no chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Nakao, F.; Nishima, S.

    1998-05-31

    Pathopoiesis factors of allergic diseases include immune antibody productivity sthenia reacting with antigens such as mite or the like in allergy reaction which is regarded as based on genetic fact (atopic diathesis), and environmental factors as external factors. The environmental factors are further classified into specific factors (antigens) and nonspecific factors. The former factors include the indoor factors such as mite, mould, animals bred indoor, etc., and outdoor factors such as pollen and so on. The latter factors include indoor factors such as passive smoking, carbon monoxide, nitrogen oxides, formaldehyde, etc., and outdoor factors such as sulfur oxides, nitrogen oxides, airborne particles and so on. In this paper, the environmental factors in relation to allergic diseases expect mite are introduced. Besides mould, cockroach/insect, fur dust and dandruff of animals, adjustment of room temperature/humidity, smoking, indoor and outdoor air pollution are mentioned as the environmental factors expect mite, and the cause-effect relations thereof are explained. 24 refs., 3 figs., 7 tabs.

  6. Study on local cooling culture technology of carnation; Kaneshon no kyokusho reibo saibai gijutsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Nakayashiki, Y. [Chugoku Electric Power Co. Inc., Hiroshima (Japan)

    1996-10-25

    Production of high-quality carnation cut flowers is difficult due to growth of weak flower stems in the district along the coast of the Inland Sea of Japan higher in average summer air temperature. The growth promotion effect of carnation by night local cooling was thus tested using midnight electric power. The glass greenhouse of 0.9m wide, 13m long and 0.25m deep was used as culture bed, and in night cooling by spot cooler, the culture bed was covered with PVC curtain for forming a small space. As the test result, high-quality spray carnation flowers with hard flower stem could be reaped from late August by combination of night local cooling and reflective film covering, and extremely high yielding of 92% was also achieved for the second flowers. The running cost of local cooling was estimated to be nearly 18yen/root in 6-ridge/3-root culture, while the facility cost to be nearly 27yen/root. This culture method was estimated to be profitable by adopting high culture density and 3 harvests for a year. 3 refs., 17 figs., 7 tabs.

  7. Study about the effect of microgravity on biofunctions; Seitai kino eno bisho juryoku no eikyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    A study is made for the elucidation of the effect of microgravity on biofunctions. The protoplast of shiitake is exposed to microgravity and then cultured, and a significant difference occurs. The rate of colony formation by cell fusion in the test sector is found to be two times higher than that in the control sector. When swimming ciliates which are unicellular are suddenly exposed to microgravity, their swimming speeds changed differently according to the direction of swimming. When a mouse subjected to acupuncture for three days is exposed to microgravity, its water metabolism and excretory function are enhanced. A mouse treated with Chinese medicine reacts in the similar way. The change due to microgravity in the amount of acetylcholine in the hypothalamus is found characteristically time dependent. Mice infected with lethal herpes viruses just after exposure to microgravity die at a rate in proportion to the number of exposures and to the amount of viruses given. The migration speed of chemical stripes in case of a gel-base BZ (Belousov-Zhabotinsky) reaction under microgravity is equal to that on the ground. The trigger wave migration speed in case of a water solution-base BZ reaction under microgravity is reduced to approximately 80% of the speed on the ground. 12 refs., 31 figs., 3 tabs.

  8. International Workshop on Carbon Cycling and Coral Reef Metabolism; Sangosho no tanso junkan ni kansuru kokusai workshop hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-10-16

    The paper described the International Workshop on Carbon Cycling and Coral Reef Metabolism which was held at Miyako-jima, Okinawa Pref. on October 17-24, 1995. In the workshop, researchers got together which are involved in marine chemistry, marine biology, coral ecology, and environmental science, and discussed the carbon cycling and metabolism of coral reef. Discussions were made on what the coral reef ecosystem is, and what the definition of a sink or a source for CO2 is. Also discussed were scales of how much time and space should be considered to make these issues clear. Further, it was proposed that it was necessary to investigate carbon balance of both the whole system and the components of the system and to keep track of mass transfer among neighboring components of the system. Seventeen presentations were given. The workshop obtained a definite consensus on carbon balance of the coral reef system. 123 refs., 39 figs., 9 tabs.

  9. Some considerations about improvement for fatigue strength of structures; Shatai kozobutsu no hiro kyodo kojo ni kansuru ichikosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Kimoto, H.; Toyama, K.; Maruyama, H.; Magara, S. [Press Kogyo Co. Ltd., Kanagawa (Japan)

    1997-10-01

    To reduce weight, higher tensile strength and/or thinner plate are used or considered in vehicle structures. In general, welded or notch sections, fatigue strength decreases because of increasing concentrated stress or effect of notch sensitivity and so on. In this paper, some methods are studied to improve fatigue strength and obtain a long life. 2 refs., 11 figs., 5 tabs.

  10. Survey on the energy transportation technology for the alternative energies; Sekiyu daitai energy nado no yuso gijutsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    1991-03-01

    Studied is a system in which hydrogen is produced through a water electrolysis process using clean energy from hydro-electric and solar power generations which can be obtained overseas with relative ease and at a low cost and is converted to a transportable chemical medium for transportation to Japan and utilization as energy like electricity, etc. The hydroelectric power generation is the most realistic alternative energy source in terms of energy density, technology and economy. Described here is the feasibility of development of hydroelectric power generation using rivers in Indonesia and Canada. As chemical substances which can be transportable chemical media, methanol/CO cycle (methanol is synthesized from coal gasified CO and electrolytic hydrogen) or liquid hydrogen cycle are the most practical on a short-term basis, and ammonia cycle and cyclohexane cycle are more advantageous than other cycles on a long-term basis. It is essential to reduce a cost of water electrolysis for each chemical substance. Potential needs are great for distribution and utilization of hydrogen energy regenerated from the transportable chemical medium, but it requires a lot of technological innovations regarding the system structure and materials (safety, particularly). 58 refs., 116 figs., 79 tabs.

  11. Study on molecular controlled mining system of methane hydrate; Methane hydrate no bunshi seigyo mining ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Kuriyagawa, M.; Saito, T.; Kobayashi, H.; Karasawa, H.; Kiyono , F.; Nagaoki, R.; Yamamoto, Y.; Komai, T.; Haneda, H.; Takahashi, Y. [National Institute for Resources and Environment, Tsukuba (Japan); Nada, H. [Science and Technology Agency, Tokyo (Japan)

    1997-02-01

    Basic studies are conducted for the collection of methane from the methane hydrate that exists at levels deeper than 500m in the sea. The relationship between the hydrate generation mechanism and water cluster structure is examined by use of mass spectronomy. It is found that, among the stable liquid phase clusters, the (H2O)21H{sup +} cluster is the most stable. Stable hydrate clusters are in presence in quantities, and participate in the formation of hydrate crystal nuclei. For the elucidation of the nucleus formation mechanism, a kinetic simulation is conducted of molecules in the cohesion system consisting of water and methane molecules. Water molecules that array near methane molecules at the normal pressure is disarrayed under a higher pressure for rearray into a hydrate structure. Hydrate formation and breakdown in the three-phase equilibrium state of H2O, CH4, and CO2 at a low temperature and high pressure are tested, which discloses that supercooling is required for formation, that it is possible to extract CH4 first for replacement by guest molecule CO2 since CO2 is stabler than CH4 at a lower pressure or higher temperature, and that formation is easier to take place when the grain diameter is larger at the formation point since larger grain diameters result in a higher formation temperature. 3 figs.

  12. Static behaviors of long-span cable-stayed bridge; Chodai shachokyo no seiteki kyodo ni kansuru kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Xie, Xu [Saitama Univ., Saitama (Japan). Graduate School; Yamaguchi, H.; Ito, M. [Saitama Univ., Urawa (Japan). Faculty of Engineering

    1996-04-21

    In this study, incremental equation of cable-stayed bridge is formulated by finite element method taking the geometrical nonlinear analysis into account. Then, as an example of designing a bridge with 1500m span, setting up the initial tension, analysis of in-plane behavior caused by live loads as well as analysis of the behavior against wind caused by out-of-plane wind load that are necessary for designing a bridge with 1500m span are carried out. The main results obtained through the study are as follows. As for the cable stayed bridge with 1500m center super long-span having supplementary supporting points between the side arms, the geometrical non-linearity caused by the in-plane design live loads is not remarkable. The effects of wind which acts on girders on analysis of the behaviors against wind are different depending on the aerodynamic performance of the girder and in the case of high wind speed, strong effects on the behavior against wind of the in-plane and screws generate. As the changing of tension of the cable makes influences on the force of in-plane cross section and on displacement of the girder, if the wind speed is very high, the analysis results of the behaviors against wind of in-plane and screws of the cable-stayed bridge may be different depending on in what manner the wind load on the cable to be treated. 16 refs., 16 figs., 1 tab.

  13. Development of coal gas production technology acceptable for fuel cells; Nenryo denchiyo sekitan gas seizo gijutsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, T. [Center for Coal Utilization, Japan, Tokyo (Japan); Kimura, N.; Omata, K. [Electric Power Development Co. Ltd., Tokyo (Japan)

    1996-09-01

    In utilizing coal for high-efficiency direct power generation using fuel cells, it is necessary that coal be fed into the fuel cells after having been made into ash-free gaseous fuel. Research and development works are being carried out with an objective to develop a coal gasification furnace most suitable for fuel cells and establish a system to refine coal up to the one that can be fed into fuel cells. Fiscal 1995 has conducted investigations on coal gasification technologies, air separation technologies, and gas refining technologies as the important element technologies, and a trial design on integrated coal gasification fuel cell (IGFC) systems. This paper reports from among the above items the result of the trial design on an IGFC system using molten carbonate fuel cells. The paper describes system comparison on paths of produced gases and anode waste gas, comparison on refining processes using a wet system and a dry system, and parameter studies on oxygen concentration in gasifying agents. It was made clear that the suitable furnace is an oxygen blown coal gasification furnace, and the power generation efficiency at the system terminal can be higher than 53%. 11 figs., 6 tabs.

  14. Study on abrasion resisting material for apron of dam; Dam apron bu no taimamo sozai ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Inaba, H.; Hiraki, M.; Miyamoto, T. [Hokuriku Electric Power Co. Inc., Toyama (Japan)

    1995-01-25

    A `laminated rubber tile` and a `shock absorbing holed-in anchor` were devised in connection with the apron of a dam for a hydroelectric power plant. As the result of a survey on the hydroelectric power plants, ten plus places were observed where a general kind of concrete was severely worn in the company territory; but, there were substantial number of rubber materials that had still been sound for over ten years after the installation. In spite of the soundness of the rubber tiles, however, it was observed that their anchor supports had been cut and separated. An abrasion comparison test of concrete and rubber materials revealed that the rubber materials were considerably superior in abrasion resistance. Various rubber tiles were tested for abrasion resistance, tear strength, tensile strength, impact strength, etc.; and methods for fixing rubber tiles were also tested such as a holed-in anchor, chemical anchor and adhesives. As a result, a laminated rubber tile was designed with its upper layer constituted of a rubber sold on the market and its lower layer of a fiber reinforced rubber also on the market, and so was a shock absorbing type holed-in anchor. 1 ref., 11 figs., 4 tabs.

  15. Treatment of wastewater from polyvinyl chloride manufacturing plant; Pori enka biniru seizo process haieki no shori ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Takeuchi, M.; Murakami, S. [Ube National College of Tech., Yamaguchi (Japan). Dept. of Biological and Chemical Engineering; Kitao, T. [Toyohashi Univ. of Technology (Japan)

    1998-08-10

    In the manufacturing process of polymers, low cost and safe water is often used for its solvent. In polymerization process using water for its solvent, emulsifier or dispersant is added to promote the hydrophobic polymerization reaction. Polymers grown by the polymerization are extracted at a separation process, and except non-extracted polymer and non-collected monomer at the process wastewater containing various additives creates. The wastewater has high Total organic carbon (TOC) and Chemical oxygen demand (COD), and these cause matters are stable and of difficult-decomposition chemically as well as biologically. As the wastewater has been treated conventionally by the activated sludge process and others, recently, the regulation of wastewater is clamped and reinvestigation of the wastewater treating facilities is required. In this study, for an example of polyvinyl chloride (PVC), a typical general purpose plastics, its polymerization wastewater was treated by a combination process of ultrafiltration, seawater added electrolysis and biolysis. As a result, non-collected PVC and dispersants could be removed by ultrafiltration process almost perfectly. 13 refs., 14 figs., 1 tab.

  16. Study on the performance enhancement of the Thermoacoustic-driven thermoacoustic refrigerator; Netsukudogata netsuonkyo reitoki no koseinoka ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Notomi, M.; Katsuta, M. [Waseda University, Tokyo (Japan). Dept. of Mechanical Engineering

    1999-11-10

    In this study, it has be made that it accumulates the data contributed for practical application by attempting performance enhancement of produced heat driving heat sound refrigerating machine, and establishes appropriate operating condition and design technique which can grasp got refrigerating capacity to some extent to be a purpose. The technique of the research in order to grasp first, the effect of various parameters in refrigerating machine simple substance, the loudspeaker driving heat sound refrigerating machine was produced experimentally, and the performance test was carried out. It continued, on the assumption of pressure wave oscillation source of the refrigerating machine, trial manufacture and performance test of heat sound oscillator simple substance were carried out, and the limit to fundamental characteristics, effect of the parameter, oscillation was examined experimentally. (NEDO)

  17. Study on automatic tuning of ship`s PID regulators; Hakuyo seigyo system no gain jido chosei ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Nakatani, T. [Toyama Mercantile Marine College, Toyama (Japan); Otsu, K.; Moriyoshi, N. [Tokyo Univ. of Mercantile Marine, Tokyo (Japan); Okazaki, T. [Nagoya Institute of Technology, Nagoya (Japan)

    1996-12-31

    Proportional, integral and derivative (PID) controls are used for a steering system and a main engine control unit installed in a vessel. Among them, this paper describes effectiveness of a PID gain tuning method using a limit cycle by means of relay control which is safer and simpler than conventional limit sensitivity methods. The present method was applied to an actual marine control system to conduct an actual vessel experiment. As a result of applying the method to a bow azimuth control system using a rudder, a new azimuth setting was set with an overshoot of 1.6 degrees in a ten-degree azimuth changing experiment. With respect to direction maintaining steering performance, the present method was capable of controlling the direction at a speed loss to about 80% of the ship`s autopilot. As a result of applying the method to a bow azimuth control system using a bow thruster, direction maintaining and changing control was realized in a low speed range in which rudder effect is lost. As a result of applying it to a main engine governor system and performing control of main engine rotation speed, it was found possible to derive control gains in a safe state without applying an excessive load to the main engine both under load and no load conditions. 14 refs., 8 figs., 11 tabs.

  18. Investigation on development of advanced materials by solvothermal technique; Sorubo thermal hanno riyo senshin zairyo kaihatsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Solvothermal reaction is reaction under high temperature and high pressure, which is expected to fabricate new functional materials. In this study, the materials are classified into two fields, i.e., inorganic materials, metals and their composites and organic materials and their composites. The current status of R and D of production and processing technology in each field is surveyed and the prospect of it is discussed. For the inorganic materials, metals and their composites, it is explained that very fine metal oxide particles, complex oxides, single crystals, whiskers, compounds with layer structure, metastable compounds, ion conductors and catalysts with high ability could be produced only by controlling the solvothermal reactions in atomic order. For the organic materials and their composites, surveyed results of the solvothermal technique using non-aqueous solutions are mainly provided. The necessity of a national project for researches on the solvothermal reactions is proposed from the viewpoint of resource, environment and energy. 777 refs., 38 figs., 26 tabs.

  19. Demonstrative study for the wind and solar hybrid power system. 2; Furyoku taiyoko hybrid hatsuden system ni kansuru jissho kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Kimura, Y.; Sakuma, H.; Ushiyama, I. [Ashikaga Institute of Technology, Tochigi (Japan)

    1996-10-27

    In order to verify the complementary relationship between wind and solar energy, the long-term field test of the hybrid power system was conducted at the natural energy square of Ashikaga Institute of Technology. The solar cell blade windmill composed of a Savonius windmill and flexible solar cells applied to swept buckets was also prepared. As a result, the wind power generation was promising mainly in the winter period including the late fall and early spring, while solar one was stable all the year through although it was slightly poor in winter. Stable power generation was thus achieved by combining wind energy with solar energy. As the whole data of other wind and solar power generation systems at the square were analyzed for every month, the same conclusion as the solar cell blade windmill was obtained as follows: the wind power generation in Ashikaga area is promising in Nov.-March from the field test result for 16 months, solar power generation is stable all the year through, the hybrid power system is effective in Nov.-April, and the solar cell blade windmill is equivalent to the hybrid power system. 3 refs., 5 figs.

  20. Fundamental characteristics on electric system of solar electric vehicle; Solar car no denki keito ni kansuru kiso tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Fujita, S.; Sasaki, M.; Kaga, T.; Koyama, N. [Hachinohe Institute of Technology, Aomori (Japan)

    1996-10-27

    The electric system of a solar vehicle was removed and the fundamental characteristics examined in order to carry out a basic experiment on the electric system. Using a basic circuit with panels, batteries and loads connected, the voltage and current were measured in the presence/absence of the trackers, batteries, etc., and then, their effects were examined. Simultaneously, the quantity of solar radiation was also measured. The lowering of the output voltage was somewhat relaxed with the use of the trackers. Further, with the trackers used, the output voltage of the panel was small in spite of a large quantity of solar radiation compared to the case without the trackers, which was due to the restriction of the output voltage by the trackers. When measured without batteries, the output voltage of the panel was such that the load current was also influenced by the variation of insolation, so that, with a large decrease in insolation, the load current was decreased with the supply of current suspended from the panel. 7 figs., 1 tab.

  1. Performance analysis on natural energy autonomous house (HARBEMAN house); Shizen energy jiritsu house (HARBEMAN house) ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Fujino, T.; Saito, T. [Tohoku University, Sendai (Japan)

    1996-10-27

    To reduce fossil fuel consumption and CO2 emission, this article introduces an actually constructed natural energy autonomous house. It has a solar collector on the south roof for hot water supply and a sky radiator on the north roof for cooling water supply. The sky radiator uses radiation cooling phenomena into the space by electromagnetic wave through the window of atmosphere. This house also has an insulated tank with a capacity of 31 m{sup 3} in its underground. In the long-term heat storage mode, the heat is collected through the solar radiation during the period from summer to spring and is stored in the underground water tank, to use it for heating and hot water supply in winter. The heat can be recovered from the garbage waste incinerator. A gas fired auxiliary boiler is used for the shortage. In the long-term heat regeneration mode, the heat is regenerated through the sky radiator during the period from spring to summer and is stored in the underground water tank, to use it for cooling in summer. For the shortage, the water is cooled using a heat pump operated by the midnight power. The insulating performance is improved by using the pair glass in windows and the glass wool in the walls. Rain water is collected in a tank with a capacity of 2 m{sup 3}, to use it for toilet water. Annual energy and water saving is equivalent to 600,000 yen. 10 refs., 10 figs., 2 tabs.

  2. Material design related investigation. Investigation on the bionic design; Zairyo sekkei kankei chosa. Bionic design ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    The biomolecular characteristics were analyzed to establish the basic technology for the utilization of artificial joint, liver and muscle. The rise in functional grade of biomolecules themselves, and inter-biomolecular recognition and bonding rationally and teleologically generates living body`s functions to form the structure and drive the molecules. Energywise extremely advantageous, those functions serve to creatively produce the artificial internal organs and elucidate the function of biotissue, if the tissue and function of living body can be artificially restructured by utilizing the biomolecular mechanism to make the tissue self-proper. It is the concept of bionic desing research. Methodologically, the inter-bimolecular action is to be synthetically analyzed through bio/physicochemistry-based computer simulation. The artificial materials excelling in adaptability to the living body are to be developed by analyzing the mechanism for the biotissue. The molecules-driving function is also to be analyzed which is generated dy the high-grade bonding of muscular and other high biomolecules. 280 refs., 69 figs., 9 tabs.

  3. Floor-supply displacement air-conditioning system; Zenmen yuka fukidashi kucho system ni kansuru gijutsu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Takebayashi, Y.; Nobe, T. [Shimizu Corp., Tokyo (Japan); Hatanaka, H. [Nitto Boseki Co. Ltd., Tokyo (Japan); Tanabe, S. [Waseda University, Tokyo (Japan)

    1999-11-05

    This development is proposing an alternative air-conditioning method, 'floor-supply displacement air-conditioning system'. The idea comes from the principle of displacement ventilation originally, using breathable carpet tiles laid over a perforated raised floor system. In this system, fresh cool or heated air are supplied at very low velocity throughout the carpet tiles. This system has been applied to 25 buildings and total floor area reached 10,000m{sup 2}. (author)

  4. Experimental study on power augmentation of Savonius rotor; Savonius gata fusha no shutsuryoku zokyo ni kansuru jikkenteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Sato, S.; Kikuchi, K.; Ushiyama, I. [Ashikaga Institute of Technology, Tochigi (Japan)

    1997-11-25

    Wind power now being used is mostly for power generation, and the power generating rotor is represented by the horizontal propeller type. The vertical type, such as Savonius rotor which uses drag force, may be used for special purposes. The Savonius rotor has been used for water pumping-up and ventilation for its characteristics of low rotational speed and high torque. The authors have proposed, based on the data collected by operating a wind mill of 10W, a method for reducing resistance by deflecting wind flowing onto the return bucket to augment drag force, in an attempt to make the system more functional. The Savonius rotor is equipped with a semi-cylindrical cover, and guide and side plates, to follow their effects. It is found that these plates work to augment power without needing expansion of sweeping area. 4 refs., 12 figs.

  5. Study on the product estimation of small wind turbines; Kogata fusha no hatsudenryo yosoku ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Matsuzawa, K.; Kimura, Y.; Ushiyama, I. [Ashikaga Institute of Technology, Tochigi (Japan); Nagai, H. [Nihon Univ., Chiba (Japan). Coll. of Industrial Technology

    1998-09-01

    In order to clarify problems involved in application of Weibull probability distribution used for estimation of power production by a large wind turbine to a small wind turbine, and solutions thereof, the estimated results are compared with the observed ones. The conventional estimation method, when applied to a small wind turbine, tends to overestimate production of power, because of overestimated production in a high wind velocity range which occurs less frequently. Estimation of power produced by a wind turbine is based on working wind velocity range, determined from the furling mechanism for the power generation characteristics of the wind turbine concerned. In the case of a small wind turbine, on the other hand, better estimates are obtained from the working wind velocity range in which Weibull wind velocity distribution is used to determine probability of occurrence. For wind turbines working at low to medium wind velocities, such as Savonius wind turbine, the estimates are in fairly good agreement with the observed results, by which is meant that the conventional estimation method aided by Weibull distribution can be directly applicable to small wind turbines. 4 refs., 3 figs., 3 tabs.

  6. Research and development of jellyfish compaction technology; Kurage gen'yoka shori gijutsu ni kansuru kaihatsu kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Uemura, N. [Kansai Electric Power Co. Inc., Osaka (Japan)

    1999-12-10

    An on-site test is conducted of devices for reducing in a short time the volume of jellyfish that flow into power plants. There are three methods to reduce the volume of jellyfish by separating water from them, which are heating, pressing, and chemical. The chemical treatment is not an object of this test because it is expected that the volume reduction rate by this method will be too low. For the achievement of a reduction rate of 80%, the two methods, physical and crushing, are compared at the laboratory level. It is found that the crushing method is superior because it can dispose of jellyfish in a shorter time. Using this method, the crushed jellyfish is separated into drain and bubbles, the latter containing jellyfish fragments. An on-site test is conducted using a general-purpose crusher. The relationship between the filter diameter (1-5mm) and the separation rate is investigated, and it is found that separation proceeds more rapidly when the filter diameter is smaller. It is found that the addition of a certain chemical accelerates the separation. COD (chemical oxygen demand) is 300-490mg/l in the drain, and BOD (biological oxygen demand) 400-500mg/l, with COD having increased by approximately 20%. A study is scheduled to be conducted using an experimental apparatus. (NEDO)

  7. Electrocatalytic proton reduction by a model for [NiFeSe] hydrogenases.

    Science.gov (United States)

    Gezer, Gamze; Durán Jiménez, Dinesh; Siegler, Maxime A; Bouwman, Elisabeth

    2017-06-13

    Two new heterodinuclear nickel-iron complexes [Ni(pbSmSe)FeCpCO]PF6 and [Ni(xbSmSe)FeCpCO]PF6 were synthesized as mimics of the [NiFeSe] hydrogenase active site (HCp = cyclopentadiene; H2pbSmSe = 1,9-diselenol-3,7-dithia-2,2,8,8-tetramethylnonane; H2xbSmSe = 1,2,-bis(2-thiabutyl-3,3-dimethyl-4-selenol)benzene). The compounds were characterized by single crystal X-ray diffraction and cyclic voltammetry. X-ray structure determinations showed that in both NiFe complexes the nickel(ii) center is in a square-planar S2Se2 environment; the two selenolate donors are bridging to the iron(ii) center that is further coordinated to an η(5)-cyclopentadienyl group and a carbon monoxide ligand. Electrochemical studies showed that the complex [Ni(pbSmSe)FeCpCO]PF6 is an electrocatalyst for the production of H2 in DMF in the presence of acetic acid at -2.1 V vs. Fc(+)/Fc; a foot-of-the-wave (FOWA) analysis of the catalytic currents yielded an estimation of kobs of 24 s(-1).

  8. Prediction Model of High Temperature Rupture Strength of 00Cr18Ni10N Steel%00Cr18Ni10N钢高温持久强度的预测与验证

    Institute of Scientific and Technical Information of China (English)

    杨旭; 王正品; 要玉宏; 刘江南

    2012-01-01

    The high temperature rupture strength of 00Crl8Nil0N stainless steel is studied, The mathematical model of relation between the rupture strength at given temperature and the high temperature tensile strength of 00Crl8Ni10N steel is established by means of total differential and state function on the basis of Larson - Miller equation. The test data indicate: The rupture strength of 00Cr18Ni10N steel at 700 ℃ lasting 200 h calculated by the model conforms to the tested value. The relative error between them is 0. 6%.%研究了00Cr18Ni10N钢的高温持久强度.在Larson-Miller方程基础上,利用全微分和状态函数特征,建立了00Cr18Ni10N钢在给定温度条件下持久强度与高温抗拉强度之间关系的数学模型.通过试验结果表明,利用该数学理论模型预测00Cr18Ni10N钢在700℃,持久拉伸200 h理论与实测持久强度值相符,相对误差为0.6%.

  9. Length scale effects and multiscale modeling of thermally induced phase transformation kinetics in NiTi SMA

    Science.gov (United States)

    Frantziskonis, George N.; Gur, Sourav

    2017-06-01

    Thermally induced phase transformation in NiTi shape memory alloys (SMAs) shows strong size and shape, collectively termed length scale effects, at the nano to micrometer scales, and that has important implications for the design and use of devices and structures at such scales. This paper, based on a recently developed multiscale model that utilizes molecular dynamics (MDs) simulations at small scales and MD-verified phase field (PhF) simulations at larger scales, reports results on specific length scale effects, i.e. length scale effects in martensite phase fraction (MPF) evolution, transformation temperatures (martensite and austenite start and finish) and in the thermally cyclic transformation between austenitic and martensitic phase. The multiscale study identifies saturation points for length scale effects and studies, for the first time, the length scale effect on the kinetics (i.e. developed internal strains) in the B19‧ phase during phase transformation. The major part of the work addresses small scale single crystals in specific orientations. However, the multiscale method is used in a unique and novel way to indirectly study length scale and grain size effects on evolution kinetics in polycrystalline NiTi, and to compare the simulation results to experiments. The interplay of the grain size and the length scale effect on the thermally induced MPF evolution is also shown in this present study. Finally, the multiscale coupling results are employed to improve phenomenological material models for NiTi SMA.

  10. Bayesian Approach to Effective Model of NiGa2S4 Triangular Lattice with Boltzmann Factor

    Science.gov (United States)

    Takenaka, Hikaru; Nagata, Kenji; Mizokawa, Takashi; Okada, Masato

    2016-12-01

    We propose a method for inducting the Boltzmann factor to extract effective classical spin Hamiltonians from mean-field-type electronic structural calculations by means of the Bayesian inference. This method enables us to compare electronic structural calculations with experiments according to the classical model at a finite temperature. Application of this method to the unrestricted Hartree-Fock calculations for NiGa2S4 led to the estimation that the superexchange interaction between the nearest neighbor sites is ferromagnetic at low temperature, which is consistent with magnetic experiment results. This supports the theory that competition between the antiferromagnetic third neighbor interaction and ferromagnetic nearest neighbor interaction may lead to the quantum spin liquid in NiGa2S4.

  11. Atomistic modeling of the reordering process of γ‧ disordered particles in Ni-Al alloys

    Science.gov (United States)

    Martínez, Enrique; Soisson, Frédéric; Caro, Alfredo; Uberuaga, Blas P.

    2016-09-01

    Ni-based alloys are used in nuclear applications, including as a window material at isotope production facilities, withstanding high fluxes of different energetic particles like protons. Irradiation disorders the γ‧ precipitates that in large extent confer the mechanical properties characterizing these materials. Upon disordering, the γ‧ phase transforms into oversaturated γ, degrading the materials properties. Experimentally it is observed that disordering might take place at fairly low irradiation doses. Once the particles are disordered, a competition between dissolution, due to strong concentration gradients in an oversaturated solid solution, and reordering appears. Here, we examine this competition in a model Ni-Al alloy under thermal conditions for different precipitates sizes and temperatures. We observe Al interdiffusion from the supersaturated particle to the matrix. Also, stochasticity appears as an important factor in to where precipitates locate. Stress relaxation seems to modify the precipitation process, with a stronger interface effect compared to rigid lattice simulations. bib-reference>

  12. Modeling, Simulation, Additive Manufacturing, and Experimental Evaluation of Solid and Porous NiTi

    Science.gov (United States)

    Taheri Andani, Mohsen

    In recent years, shape memory alloys (SMAs) have entered a wide range of engineering applications in fields such as aerospace and medical applications. Nickel-titanium (NiTi) is the most commonly used SMAs due to its excellent functional characteristics (shape memory effect and superelasticity behavior). These properties are based on a solid-solid phase transformation between martensite and austenite. Beside these two characteristics, low stiffness, biocompatibility and corrosion properties of NiTi make it an attractive candidate for biomedical applications (e.g., bone plates, bone screws, and vascular stents). It is well know that manufacturing and processing of NiTi is very challenging. The functional properties of NiTi are significantly affected by the impurity level and due to the high titanium content, NiTi are highly reactive. Therefore, high temperature processed parts through methods such as melting and casting which result in increased impurity levels have inadequate structural and functional properties. Furthermore, high ductility and elasticity of NiTi, adhesion, work hardening and spring back effects make machining quite challenging. These unfavorable effects for machining cause significant tool wear along with decreasing the quality of work piece. Recently, additive manufacturing (AM) has gained significant attention for manufacturing NiTi. Since AM can create a part directly from CAD data, it is predicted that AM can overcome most of the manufacturing difficulties. This technique provides the possibility of fabricating highly complex parts, which cannot be processed by any other methods. Curved holes, designed porosity, and lattice like structures are some examples of mentioned complex parts. This work investigates manufacturing superelastic NiTi by selective laser melting (SLM) technique (using PXM by Phenix/3D Systems). An extended experimental study is conducted on the effect of subsequent heat treatments with different aging conditions on phase

  13. Modeling and Characterization of the Magnetocaloric Effect in Ni2MnGa Materials

    Energy Technology Data Exchange (ETDEWEB)

    Nicholson, Don M [ORNL; Odbadrakh, Khorgolkhuu [ORNL; Shassere, Benjamin [ORNL; Rios, Orlando [ORNL; Hodges, Jason P [ORNL; Ludtka, Gerard Michael [ORNL; Porter, Wallace D [ORNL; Safa-Sefat, Athena [ORNL; Rusanu, Aurelian [ORNL; Brown, Greg [ORNL; Evans III, Boyd Mccutchen [ORNL

    2014-01-01

    Magnetic shape memory alloys have great promise as magneto-caloric effect refrigerant materials due to their combined magnetic and structural transitions. Computational and experimental research is reported on the Ni2MnGa material system. The magnetic states of this system are explored using the Wang-Landau statistical approach in conjunction with the Locally Self-consistent Multiple-Scattering method. The effects of alloying agents on the transition temperatures of the Ni2MnGa alloy are investigated using differential scanning calorimetry and superconducting quantum interference device. Experiments are performed at the Spallation Neutron Source at Oak Ridge National Laboratory to observe the structural and magnetic phase transformations.

  14. Three dimensional wavefield modeling using the pseudospectral method; Pseudospectral ho ni yoru sanjigen hadoba modeling

    Energy Technology Data Exchange (ETDEWEB)

    Sato, T.; Matsuoka, T. [Japan Petroleum Exploration Corp., Tokyo (Japan); Saeki, T. [Japan National Oil Corp., Tokyo (Japan). Technology Research Center

    1997-05-27

    Discussed in this report is a wavefield simulation in the 3-dimensional seismic survey. With the level of the object of exploration growing deeper and the object more complicated in structure, the survey method is now turning 3-dimensional. There are several modelling methods for numerical calculation of 3-dimensional wavefields, such as the difference method, pseudospectral method, and the like, all of which demand an exorbitantly large memory and long calculation time, and are costly. Such methods have of late become feasible, however, thanks to the advent of the parallel computer. As compared with the difference method, the pseudospectral method requires a smaller computer memory and shorter computation time, and is more flexible in accepting models. It outputs the result in fullwave just like the difference method, and does not cause wavefield numerical variance. As the computation platform, the parallel computer nCUBE-2S is used. The object domain is divided into the number of the processors, and each of the processors takes care only of its share so that parallel computation as a whole may realize a very high-speed computation. By the use of the pseudospectral method, a 3-dimensional simulation is completed within a tolerable computation time length. 7 refs., 3 figs., 1 tab.

  15. Ab initio study of the compound-energy modeling of multisublattice structures: The (hP6) Ni{sub 2}In-type intermetallics of the Ni–In–Sn system

    Energy Technology Data Exchange (ETDEWEB)

    Ramos de Debiaggi, S., E-mail: susana.ramos@fain.uncoma.edu.ar [Facultad de Ingeniería, Universidad Nacional del Comahue, Buenos Aires 1400, 8300 Neuquén (Argentina); Instituto de Investigación y Desarrollo en Ingeniería de Procesos, Biotecnología y Energías Alternativas – CONICET-UNCo (Argentina); González Lemus, N.V. [Facultad de Ingeniería, Universidad Nacional del Comahue, Buenos Aires 1400, 8300 Neuquén (Argentina); Deluque Toro, C. [Grupo de Nuevos Materiales, Universidad de la Guajira, Riohacha (Colombia); Fernández Guillermet, A. [CONICET - Instituto Balseiro, Centro Atómico Bariloche, Avda. Bustillo 9500, 8400 Bariloche (Argentina)

    2015-01-15

    Highlights: • A DFT study of the compounds involved in CALPHAD modeling of the Ni–In–Sn (hP6) phase. • Several three-sublattice compounds of Ni, In, Sn and vacancies are studied ab initio. • Structural, cohesive and thermodynamic properties and the electronic DOS are reported. • Trends in calculated properties are correlated with changes in electronic structure. • A picture of the chemical bonding trends for these s-p/d type compounds is discussed. - Abstract: The thermodynamic modeling of non-stoichiometric, multisublattice intermetallic phases using the Compound-Energy Formalism (CEF) involves the determination of parameters representing the Gibbs energy (G{sub m}) of binary compounds, the so-called “end-member compounds” (EMCs), which are often metastable or hypothetical. In current CALPHAD (i.e., “Calculation of Phase Diagrams”) work, these quantities are treated as free parameters to be determined by searching for the best fit to the available information in the optimization procedure. The general purpose of this paper is to propose a theoretical approach to the study of the EMCs which makes use of density-functional-theory (DFT) ab initio calculations. The present method is applied to the EMCs involved in the CEF modeling of the non-stoichiometric (hP6) Ni{sub 2}In-structure type phase of the Ni–In and Ni–In–Sn systems using the three-sublattice models (Ni){sub 1}(Ni,Va){sub 1}(In,Ni){sub 1} and (Ni,Va){sub 1}(Ni,Va){sub 1}(In,Ni,Sn){sub 1}, respectively. By means of systematic ab initio projected augmented waves (PAW) calculations using the VASP code we study the EMCs involved in the CEF formulations of the G{sub m} for this phase in the binary and the ternary systems. Specifically, we study the twelve EMCs corresponding to the following sublattice occupations: (Ni){sub 1}(Ni){sub 1}(In){sub 1}, which is usually described as Ni:Ni:In (i.e., a compound with formula “Ni{sub 2}In”), Ni:Ni:Ni (i.e., “Ni{sub 3}”), Ni:Ni:Sn (“Ni

  16. Nanostructure evolution under irradiation in FeMnNi alloys: A “grey alloy” object kinetic Monte Carlo model

    Energy Technology Data Exchange (ETDEWEB)

    Chiapetto, M., E-mail: mchiapet@sckcen.be [SCK-CEN, Nuclear Materials Science Institute, Boeretang 200, B-2400 Mol (Belgium); Unité Matériaux Et Transformations (UMET), UMR 8207, Université de Lille 1, ENSCL, F-59600 Villeneuve d’Ascq Cedex (France); Malerba, L. [SCK-CEN, Nuclear Materials Science Institute, Boeretang 200, B-2400 Mol (Belgium); Becquart, C.S. [Unité Matériaux Et Transformations (UMET), UMR 8207, Université de Lille 1, ENSCL, F-59600 Villeneuve d’Ascq Cedex (France)

    2015-07-15

    This work extends the object kinetic Monte Carlo model for neutron irradiation-induced nanostructure evolution in Fe–C binary alloys developed in [1], introducing the effects of substitutional solutes like Mn and Ni. The objective is to develop a model able to describe the nanostructural evolution of both vacancy and self-interstitial atom (SIA) defect cluster populations in Fe(C)MnNi neutron-irradiated model alloys at the operational temperature of light water reactors (∼300 °C), by simulating specific reference irradiation experiments. To do this, the effects of the substitutional solutes of interest are introduced, under simplifying assumptions, using a “grey alloy” scheme. Mn and Ni solute atoms are not explicitly introduced in the model, which therefore cannot describe their redistribution under irradiation, but their effect is introduced by modifying the parameters that govern the mobility of both SIA and vacancy clusters. In particular, the reduction of the mobility of point-defect clusters as a consequence of the presence of solutes proved to be key to explain the experimentally observed disappearance of detectable defect clusters with increasing solute content. Solute concentration is explicitly taken into account in the model as a variable determining the slowing down of self-interstitial clusters; small vacancy clusters, on the other hand, are assumed to be significantly slowed down by the presence of solutes, while for clusters bigger than 10 vacancies their complete immobility is postulated. The model, which is fully based on physical considerations and only uses a few parameters for calibration, is found to be capable of reproducing the experimental trends in terms of density and size distribution of the irradiation-induced defect populations with dose, as compared to the reference experiment, thereby providing insight into the physical mechanisms that influence the nanostructural evolution undergone by this material during irradiation.

  17. Comparative analyses of thermodynamic properties assessments, performed by geometric models: Application to the Ni-Bi-Zn system

    Directory of Open Access Journals (Sweden)

    Gandova V.

    2013-01-01

    Full Text Available The thermochemical properties of metals and alloys are essential for the chemists to invent and improve metallurgical and materials’ design processes. However, the properties of multicomponent systems are still scarcely known due to experimental difficulties and the large number of related systems. Thus, the modelling of some thermodynamic properties would be advantageous when experimental data are missing. Considering mentioned facts, geometric models to estimate some thermodynamic properties for the liquid phase of the Ni-Bi-Zn systems. The calculations have been performed in a wide temperature range (1000-2000 K. Ternary interaction parameters for the liquid phase allowing molar Gibbs excess energy calculation have been determined.

  18. Nanostructure evolution under irradiation of Fe(C)MnNi model alloys for reactor pressure vessel steels

    Science.gov (United States)

    Chiapetto, M.; Becquart, C. S.; Domain, C.; Malerba, L.

    2015-06-01

    Radiation-induced embrittlement of bainitic steels is one of the most important lifetime limiting factors of existing nuclear light water reactor pressure vessels. The primary mechanism of embrittlement is the obstruction of dislocation motion produced by nanometric defect structures that develop in the bulk of the material due to irradiation. The development of models that describe, based on physical mechanisms, the nanostructural changes in these types of materials due to neutron irradiation are expected to help to better understand which features are mainly responsible for embrittlement. The chemical elements that are thought to influence most the response under irradiation of low-Cu RPV steels, especially at high fluence, are Ni and Mn, hence there is an interest in modelling the nanostructure evolution in irradiated FeMnNi alloys. As a first step in this direction, we developed sets of parameters for object kinetic Monte Carlo (OKMC) simulations that allow this to be done, under simplifying assumptions, using a "grey alloy" approach that extends the already existing OKMC model for neutron irradiated Fe-C binary alloys [1]. Our model proved to be able to describe the trend in the buildup of irradiation defect populations at the operational temperature of LWR (∼300 °C), in terms of both density and size distribution of the defect cluster populations, in FeMnNi model alloys as compared to Fe-C. In particular, the reduction of the mobility of point-defect clusters as a consequence of the presence of solutes proves to be key to explain the experimentally observed disappearance of detectable point-defect clusters with increasing solute content.

  19. Ab initio modelling of magnetic anisotropy in Sr3NiPtO6

    NARCIS (Netherlands)

    Pradipto, A. -M.; Broer, R.; Picozzi, S.

    2016-01-01

    First principles calculations in the framework of Density Functional Theory (DFT) and wavefunction-based correlated methods have been performed to investigate in detail the magnetic anisotropy in Sr3NiPtO6. This material is known for the easy-plane anisotropy with a large anisotropy constant of abou

  20. Improved properties of the catalytic model system Ni/Ru(0001)

    DEFF Research Database (Denmark)

    Egeberg, Rasmus; Chorkendorff, Ib

    2001-01-01

    ) illustrating the unique properties of metal-on-metal systems. The effect of enhanced reactivity is primarily ascribed to electronic effects induced by a straining of the Ni overlayer. The enhanced reactivity towards CH4 is accompanied by new features in the thermal desorption spectra of CO. The reactivity...

  1. Elastic-Plastic Endochronic Constitutive Model of 0Crl7Ni4Cu4Nb Stainless Steels

    Directory of Open Access Journals (Sweden)

    Jinquan Guo

    2016-01-01

    Full Text Available We presented an elastic-plastic endochronic constitutive model of 0Crl7Ni4Cu4Nb stainless steel based on the plastic endochronic theory (which does not need the yield surface and experimental stress-strain curves. The key feature of the model is that it can precisely describe the relation of stress and strain under various loading histories, including uniaxial tension, cyclic loading-unloading, cyclic asymmetric-stress axial tension and compression, and cyclic asymmetric-stress axial tension and compression. The effects of both mean stress and amplitude of stress on hysteresis loop based on the elastic-plastic endochronic constitutive model were investigated. Compared with the experimental and calculated results, it is demonstrated that there was a good agreement between the model and the experiments. Therefore, the elastic-plastic endochronic constitutive model provides a method for the accurate prediction of mechanical behaviors of 0Crl7Ni4Cu4Nb stainless steel subjected to various loadings.

  2. MECHANISTIC KINETIC MODELS FOR STEAM REFORMING OF CONCENTRATED CRUDE ETHANOL ON NI/AL2O3 CATALYST

    Directory of Open Access Journals (Sweden)

    O. A. OLAFADEHAN

    2015-05-01

    Full Text Available Mechanistic kinetic models were postulated for the catalytic steam reforming of concentrated crude ethanol on a Ni-based commercial catalyst at atmosphere pressure in the temperature range of 673-863 K, and at different catalyst weight to the crude ethanol molar flow rate ratio (in the range 0.9645-9.6451 kg catalyst h/kg mole crude ethanol in a stainless steel packed bed tubular microreactor. The models were based on Langmuir-Hinshelwood-Hougen-Watson (LHHW and Eley-Rideal (ER mechanisms. The optimization routine of Nelder-Mead simplex algorithm was used to estimate the inherent kinetic parameters in the proposed models. The selection of the best kinetic model amongst the rival kinetic models was based on physicochemical, statistical and thermodynamic scrutinies. The rate determining step for the steam reforming of concentrated crude ethanol on Ni/Al2O3 catalyst was found to be surface reaction between chemisorbed CH3O and O when hydrogen and oxygen were adsorbed as monomolecular species on the catalyst surface. Excellent agreement was obtained between the experimental rate of reaction and conversion of crude ethanol, and the simulated results, with ADD% being ±0.46.

  3. Assessing the link between Atlantic Niño 1 and drought over West Africa using CORDEX regional climate models

    Science.gov (United States)

    Adeniyi, Mojisola Oluwayemisi; Dilau, Kabiru Alabi

    2016-12-01

    The skill of Coordinated Regional Climate Downscaling Experiment (CORDEX) models (ARPEGE, CCLM, HIRHAM, RACMO, REMO, PRECIS, RegCM3, RCA, WRF and CRCM) in simulating the climate (precipitation, temperature and drought) of West Africa is determined using a process-based metric. This is done by comparing the CORDEX models' simulated and observed correlation coefficients between Atlantic Niño Index 1 (ATLN1) and the climate over West Africa. Strong positive correlation is observed between ATLN1 and the climate parameters at the Guinea Coast (GC). The Atlantic Ocean has Niño behaviours through the ATLN indices which influence the climate of the tropics. Drought has distinct dipole structure of correlation with ATLN1 (negative at the Sahel); precipitation does not have distinct dipole structure of correlation, while temperature has almost a monopole correlation structure with ATLN1 over West Africa. The magnitude of the correlation increases with closeness to the equatorial eastern Atlantic. Correlations between ATLN1 and temperature are mostly stronger than those between ATLN1 and precipitation over the region. Most models have good performance over the GC, but ARPEGE has the highest skill at GC. The PRECIS is the most skilful over Savannah and RCA over Sahel. These models can be used to downscale the projected climate at the region of their highest skill.

  4. Glass forming ability of Zr-Al-Ni(Co,Cu) understood via cluster sharing model

    Institute of Scientific and Technical Information of China (English)

    Jixiang Chen; Yi Cheng

    2014-01-01

    Clusters are shared atoms in different ways with their neighboring clusters in the crystalline phases. Cluster formula [effective cluster]1(glue atom)x can be used to describe crystalline phases, and the effective cluster means the true cluster composition due to cluster overlapping in the phase structure. Degree of cluster sharing of Zr6Al2Ni (InMg2), Zr2Co (Al2Cu) and Zr2Cu (MoSi2) phases is investigated in this paper. Ni3Zr9, Co3Zr8 and Cu5Zr10 clusters are highlighted because they have the least degree of sharing and can best represent the local atomic short-range order features of the formed phases. It is pointed out that the least sharing clusters are correlated with metallic glass formation and are verified by experiments.

  5. Gas-phase complexes of Ni2+ and Ca2+ with deprotonated histidylhistidine (HisHis): A model case for polyhistidyl-metal binding motifs

    Science.gov (United States)

    Peckelsen, Katrin; Martens, Jonathan; Berden, Giel; Oomens, Jos; Dunbar, Robert C.; Meijer, Anthony J. H. M.; Schäfer, Mathias

    2017-02-01

    In the complex formed between the calcium cation (Ca2+) and a deprotonated HisHis dipeptide, the complex adopts a charge solvation (CS) structure. Ca2+, a weak binding main group metal cation, interacts with the oxygens of the peptide carbonyl moiety and the deprotonated C-terminus. In contrast, the much stronger binding Ni2+ cation deprotonates the peptide nitrogen and induces an iminolate (Im) ligand structure in the [Ni(HisHis-H)]+ complex ion. The combination of infrared multiple-photon dissociation (IRMPD) spectroscopy and quantum chemistry evidence these two representative binding motifs. The iminolate coordination pattern identified and characterized in the [Ni(HisHis-H)]+ complex serves as a model case for nickel complexes of poly-histidyl-domains and is thereby also of interest to better understand the fundamentals of immobilized metal ion affinity chromatography as well as of Ni co-factor chemistry in enzymology.

  6. Modelling NiFe hydrogenases: nickel-based electrocatalysts for hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Canaguier, S.; Artero, V.; Fontecave, M. [CEA, DSV, iRTSV, Lab Chim Biol Metaux, CEA-CNRS-Univ Grenoble 1, UMR 5249, F-38054 Grenoble 9 (France)

    2008-07-01

    NiFe hydrogenases are unique enzymes that catalyze the H{sup +}/H{sub 2} interconversion with remarkable efficiency. The determination of the tridimensional structure of their active site (a sulfur-rich dinuclear nickel-iron cluster with diatomic cyanide and carbonyl ligands) has stimulated the synthesis of a variety of nickel-based complexes as potential electrocatalysts for hydrogen production. These catalysts may provide an adequate alternative to platinum. This paper gives an historical perspective of this biomimetic structural approach and then focusses on recently reported bio-inspired functional mimics displaying electrocatalytic activity for hydrogen production. (authors)

  7. Interpretation of seismic section by acoustic modeling. Study of large amplitude events; Hadoba modeling ni yoru jishin tansa danmen no kaishaku. Kyoshinhaba event ni taisuru kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Tamagawa, T.; Matsuoka, T.; Sato, T. [Japan Petroleum Exploration Corp., Tokyo (Japan); Minegishi, M.; Tsuru, T. [Japan National Oil Corp., Tokyo (Japan)

    1996-05-01

    A large amplitude event difficult to interpret was discovered in the overlap section in offset data beyond 10km targeting at deep structures, and the event was examined. A wave field modeling was carried out by use of a simplified synclinal structure model because it had been estimated that the large amplitude event had something to do with a synclinal structure. A pseudospectral program was used for modeling the wave field on the assumption that the synclinal structure model would be an acoustic body and that the surface would contain free boundaries and multiple reflection. It was found as the result that a discontinuous large amplitude event is mapped out in the synclinal part of the overlap section when a far trace is applied beyond the structure during a CMP overlap process. This can be attributed to the concentration of energy produced by multiple reflection in the synclinal part and by the reflection waves beyond the critical angle. Accordingly, it is possible that phenomena similar to those encountered in the modeling process are emerging during actual observation. 2 refs., 8 figs.

  8. Study of impacts of north american free trade agreement over the international labor migration; Hokubei juyuboeki kyotei no kokusai rodoryoku ido ni ataeru eikyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Koido, Akihiro [Sophia University, Tokyo (Japan). Institute of International Relations

    1998-12-16

    This project tried to analyze the effects of transnational economic integration on the immigration flow from developing countries, focusing the case of NAFTA and Mexico. Field interviews with 30 plants of Japanese and U.S. firms with regard to locational and labor market strategy made it possible to analyze concrete effects of investment on labor migration. The rapidly expanding export oriented in-bond industry is incorporating new source of labor by spatially shifting to interior states. On the other hand, new mode of global competition, centered around quality, product diversity, acceleration of product innovation, gave a special advantage to border location and gave rise to industrial agglomeration of specific sectors in specific cities. This industrial dynamics lead not to balance of labor market among regions, but to further labor migration to the north. In future, by utilizing the concept of industrial agglomeration in a more systematic manner, I would like to develop more specific understanding of migration within the context of transnational regional integration. (author)

  9. Numerical simulation for Savonius rotors. Effects of shed vortices on running performance; Savonius fusha ni kansuru suchi keisan. Hoshutsuuzu ga unten tokusei ni oyobosu eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Ishimatsu, K.; Shinohara, T.; Kage, K.; Okubayashi, T. [Oita University, Oita (Japan). Faculty of Engineering

    1995-01-25

    Considerations have been given on the effects of shed vortices on running performance based on a drawing of the flow fields around a Savonius rotor with semi-circular blades (a drawing depicting the result of calculations using the finite volume method based on two-dimensional incompressible Navier-Stokes equations). A drawing of time-based change in the flow field using a relative velocity vector and an equivalent vorticity line, and a drawing of pressure distribution on the surface of and around the blades were used to indicate that the vortex behavior and the pressure field differ respectively because of increase in the circumferential speed ratio and the existence of blade clearance. The following matters are indicated: the reduction in the torque coefficient in association with increase in the circumferential speed ratio is caused importantly by the separation vortices from the rear face of a leading side blade entering into a concave portion in a return side blade; and the reason for the torque coefficient growing larger above a certain circumferential speed ratio in the case of having blade clearance than the case not having the blade clearance is because the separation vortices from the rear face of the blade become more difficult of entering into the concave portion due to a flow passing through the clearance. 4 refs., 11 figs.

  10. Numerical study of the mechanism of wavy interface generation in explosive welding; Bakuhatsu yosetsu ni okeru hajo kaimen keisei kiko ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Abe, A. [Kobe University of Mercantile Marine, Kobe (Japan)

    1996-07-21

    Wavy interface generation is an interesting characteristic of explosive welding. There have been many theoretical and experimental discussions of the mechanism of wavy interface generation but there is no consensus of opinion as yet. We report a numerical approach to the analysis of the mechanism of interface wave generation in explosive welding. The phenomena of the interface wave generation are calculated using a two-dimensional finite difference scheme for elastic-plastic materials. In this simulation the equations for a symmetric collision between copper plates are solved. The concept behind this study is that the wavy interface and vortex streets are caused by the velocity distribution of shear flow and periodic disturbances at the interface. The calculation results show the deformation process of the wavy interface and we obtain qualitative agreements between numerical and experimental results. 13 refs., 10 figs., 1 tab.

  11. On the estimation method of hydrodynamic forces acting on a huge floating structure; Choogata futai ni hataraku haryoku ryutairyoku no suiteiho ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Kagemoto, H.; Fujino, M.; Zhu, T. [The University of Tokyo, Tokyo (Japan)

    1996-12-31

    A floating structure such as an international airport is anticipated to have a length of about 5,000 m and a width of about 1,000 m. A singular point method may be used as a method to estimate force that such a floating body is subjected to from waves. In order to derive a solution with practically sufficient accuracy, 1250 elements are required in the length direction and 250 elements in the width direction, or a total of 312,500 elements. Calculating this number of elements should use finally a linear equation system handling complex coefficients comprising 312,500 elements, which would require a huge amount of calculation time. This paper proposes a method to derive solution on wave forces acting on a super-large floating structure or fluid force coefficients such as added mass coefficients and decay coefficients at a practically workable calculation amount and still without degrading the accuracy. The structure was assumed to be a box-shaped structure. Strengths of the singular points to be distributed on each element were assumed to be almost constant except for edges in lateral, oblique and longitudinal waves. Under this assumption, the interior of the floating structure excepting its edges was represented by several large elements to have reduced the number of elements. A calculation method proposed based on this conception was verified of its effectiveness. 2 refs., 25 figs., 3 tabs.

  12. Fundamental study on leak detection of underground gas pipeline using passive acoustic method; Judogata onkyo keisoku ni yoru maisetsu gas dokan hason kasho no kenshutsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Jinguji, M.; Imaizumi, H.; Kunimatsu, S.; Isei, T. [National Institute for Resources and Environment, Tsukuba (Japan)

    1997-05-27

    With an objective to detect gas leaking from an underground gas pipeline, discussions have been given on a method which utilizes acoustic characteristics of leakage. On leaking sound generated from damaged portions, the form of damaging was hypothesized as pinholes, and spectra of leaking sounds from holes with different diameters were measured. The dominant frequency decreases as the hole diameter increases, while it is in a region of relatively high frequency of 1 kHz or higher. However, detection from the ground surface was impossible when cover soil has thickness from 0.5 to 1.5 m. In an experiment to measure leaking sound inside the pipe, pressure in the pipe was adjusted to 0.02 atm which is a standard pressure for a low-pressure pipe, and the sound was measured when the hole diameters were varied. In any of the results obtained by varying the hole diameter, spectra having the dominant frequency in the region of 1 kHz or higher were measured. In addition, it was found that sound pressure difference of as much as 50 dB at maximum is generated as compared with a case of no sound leakage. The above results verified that monitoring the high frequency of 1 kHz or higher is effective in detecting leakage from small damages. 2 refs., 4 figs.

  13. Theoretical study on seaquake loads acting on a two-dimensional floating body; Nijigen futai ni hataraku kaishin kaju ni kansuru rironteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Higo, Y.; Ueno, H. [Hiroshima University, Hiroshima (Japan). Faculty of Engineering; Koda, M. [Asahi Glass Co. Ltd., Tokyo (Japan); Nakamori, K. [Nippon Denro MFG. Co. Ltd., Osaka (Japan)

    1996-10-01

    Analyses and discussions were given on characteristics of loads as a result of seaquake acting on a floating body. In the present study, propagation of pressure waves due to vibration in sea bottom ground as propagation of underwater sound waves, and pressures in wave motion fields and loads due to seaquake acting on the floating body were derived by using the Green function which satisfies free surface conditions and sea bottom conditions. In addition, the boundary element method was used to conduct similar calculations to verify the methodological reasonability. As a result of discussions, the following results were obtained: a seaquake load has a resonant point which corresponds to an intrinsic value of the boundary value problem in a closed region; the resonant point moves according to width of the floating body, and the frequency moves to higher frequency side when water depth is shallower; compressibility of fluid cannot be ignored in the vicinity of the frequency for the resonant point; the seaquake load is proportional to width of a vibrating ground on the sea bottom, and the load in the vertical direction decreases when the center of the floating body is separated from the vibrating ground; a load in the horizontal direction presents no problems in a floating body with a shallow draft; and a moment in the lateral direction may present a larger problem than in the load in the vertical direction. 8 refs., 8 figs.

  14. Experimental studies on performance of tandem hydrofoils in high speed regions; Kosokuiki ni okeru tandem suichuyoku no seino ni kansuru jikkenteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Nakatake, K.; Oda, K.; Kataoka, K. [Kyushu University, Fukuoka (Japan). Faculty of Engineering; Okada, S. [Mitsubishi Heavy Industries, Ltd., Tokyo (Japan); Mizuno, S. [Hitachi Zosen Corp., Osaka (Japan)

    1996-10-01

    With an objective to clarify basic performance of hydrofoils, a towing experiment was carried out on single hydrofoil and tandem hydrofoils, whose results are reported in this paper. In the experiment, the tandem hydrofoils are supported on two stays on the left and right sides, and the whole lifting power and the whole drag including those of the stays were measured by using strain gauges placed on four plate springs. Results of the experiment may be summarized as follows: in the case of the single hydrofoil, the lifting power constant varied as a result of strong impact on free surface as the shallower the hydrofoil, but corresponds to the size of the lifting power coefficient in high speed regions; in the case of the tandem hydrofoils, the smaller the submersion depth, the effects grew larger on the lifting power coefficient and the drag coefficient, similarly to the case of the single hydrofoil; and the lifting power coefficient for the leading hydrofoils changes very little as a result of change in horizontal distance between the tandem hydrofoils, but the lifting power coefficient of the rear hydrofoils vibrates due to influence from the leading hydrofoils, with the peak of the value thereof transferring to the higher speed side as the horizontal distance increases. 3 refs., 10 figs., 2 tabs.

  15. Investigation of the deposit formation in pipelines connecting liquefaction reactors; 1t/d PSU ni okeru ekika hanno tokan fuchakubutsu no seisei yoin ni kansuru ichikosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Okada, Y.; Nogami, Y.; Inokuchi, K. [Mitsui SRC Development Co. Ltd., Tokyo (Japan); Mochizuki, M.; Imada, K. [Nippon Steel Corp., Tokyo (Japan)

    1996-10-28

    The liquefaction reaction system of an NEDOL process coal liquefaction 1t/d PSU was opened and checked to investigate the cause of the rise of differential pressure between liquefaction reactors of the PSU. The liquefaction test at a coal concentration of 50 wt% using Tanito Harum coal was conducted, and it was found that the differential pressure between reactors was on the increase. By the two-phase flow pressure loss method, deposition thickness of deposit in pipelines was estimated at 4.4mm at the time of end operation, which agreed with a measuring value obtained from a {gamma} ray. The rise of differential pressure was caused by deposit formation in pipelines connecting reactors. The main component of the deposit is calcite (CaCO3 60-70%) and is the same as the usual one. It is also the same type as the deposit on the reactor wall. Ca in coal ash is concerned with this. To withdraw solid matters deposited in the reactor, there are installed pipelines for the withdrawal at the reactor bottom. The solid matters are regularly purged by reverse gas for prevention of clogging. As the frequency of purge increases, the deposit at the reactor bottom decreases, but the deposit attaches strongly to pipelines connecting reactors. It is presumed that this deposit is what Ca to be discharged out of the system as a form of deposition solid matter naturally in the Ca balance precipitated as calcite in the pipeline connecting the reactor. 3 refs., 5 figs., 4 tabs.

  16. Coal liquefaction in early stage of NEDOL process 1t/d PSU; 1t/d PSU ni okeru ekika shoki hanno ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Ikeda, K.; Kawabata, M.; Mochizuki, M.; Imada, K. [Nippon Steel Corp., Tokyo (Japan); Nogami, Y.; Inokuchi, K. [Mitsui SRC Development Co. Ltd., Tokyo (Japan)

    1996-10-28

    To investigate the behavior of coal liquefaction reaction in early stage as a part of studies on the coal liquefaction characteristics using NEDOL process 1 t/d process supporting unit (PSU), coal slurry sample was taken from the outlet of slurry preheater located in the upflow of liquefaction reactors, and was tested. Tanito Harum coal was used for liquefaction. Preheater was operated under the condition of pressure of 170 kg/cm{sup 2}, gas flow rate of 64 Nm{sup 3}/hr, and at temperature up to 410{degree}C at the outlet, in response to the standard test condition. The slurry sample was discharged into a high temperature separator with temperature of 250{degree}C. Liquefaction was not proceeded at the outlet of preheater. Solid residue yielded around 80%, and liquid yielded around 15%. Gases, CO and CO2, and water yielded also small amount around 3%. The solid sample contained much IOM fraction (tetrahydrofuran-insoluble and ash), and the liquid contained much heavy oil fraction. Hydrogenation was not proceeded, and the hydrogen consumption was very low showing below one-tenth of that at the usual operation. Hydrogen sulfide gas was formed at early stage, which suggested that the change of iron sulfide catalyst occur at early stage of liquefaction. 1 ref., 5 figs., 2 tabs.

  17. Global environmental benefits of industrial heat pumps (fiscal 1993); 1993 nendo koon heat pumping gijutsu ni yoru chikyu ondanka keigen koka ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    An investigational study was conducted aiming at making a quantitative grasp of effects of the spread of industrial heat pumps on energy conservation and greenhouse gas reduction and at promoting the spread. Finally, the following eight countries joined this international joint research: Canada, France, Japan, Holland, Norway, Sweden, the U.K. and the U.S. Each country share the work and expenses for the research with each other. Japan made investigational researches on the application of heat pumps to processes of the chemical industry, oil refining industry, food industry, paper/pulp industry, and dyeing/weaving industry, and on the effects of greenhouse gas reduction. As procedures taken, values up to 2010 were estimated of energy prices in each country, energy supply/demand, rates of the heat source configuration for electric power supply, etc., the heat flow of the above-mentioned process was made clear, and analyses were conducted of annual profits, energy consumption, and depreciation period in the case of adopting heat pumps. Moreover, the energy conservation amount and greenhouse effect gas reduction amount were estimated based on the result of the analyses. 69 figs., 196 tabs.

  18. Investigational study on the development, production and wide spread of welfare apparatus in north Europe; Hokuo ni okeru fukushi yogu no kaihatsu seisan fukyu ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    For the purpose of grasping the present situation of the development/production/spread of welfare apparatus in north Europe, an investigation was conducted paying visits to Sweden and Denmark. Basically in the Swedish policy for handicapped persons, disablement is defined not only as features which belong to each individual, but as problems arising when the environment surrounding each individual touches one another. Moreover, characteristics of their policies on welfare apparatus are that major welfare apparatus can be provided for the disabled free of charge, and that the government and public organs play a major role in each step of the development, evaluation, distribution and provision of welfare apparatus. Features of the market of welfare apparatus are that users and buyers of the apparatus are different persons, that a public corporation called SUB participates in determining selling prices, etc., and that the market reflects needs and requests from users comparatively naturally. The needs for welfare apparatus at the Research Institute of Handicapped Persons are grasped through opinion exchanges with groups of handicapped persons or information exchanges with the technical aid center. 3 refs., 11 figs., 10 tabs.

  19. Evaluation for characteristics of around the Nojima fault; Butsuri tansa ni yoru `Nojima jishin danso` shuhen no jiban bussei ni kansuru ichihyoka

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, K.; Tsuji, T. [Newjec Inc., Osaka (Japan); Tsuji, M. [OYO Corp., Tokyo (Japan)

    1996-05-01

    Various surveys were conducted for the area around the Nojima fault, including ground surface, two-dimensional electrical and boring surveys and elastic wave tomography, in order to grasp properties of the ground around the `Nojima earthquake fault.` The resistivity image method as one of the two-dimensional electrical methods was used to grasp fault shapes over a wide range of the 1.6km long section extending between Esaki and Hirabayashi. The courses of traverse were set in the direction almost perpendicular to the fault. Boreholes were excavated and elastic wave tomography was conducted between the boreholes on the 9th and 17th courses of traverse, to confirm ground/mountain conditions and to compare the results with observed elastic wave velocities. Very low resistivities are observed at places where granite is distributed, suggesting that the fault-induced changes are not limited to the area around the fault. The zone in which elastic wave velocity decreases is narrow, 10m at the longest, at a velocity of 2.4km/s or lower, which is a low velocity for that propagating in granite. 5 refs., 4 figs.

  20. Questionnaire investigation for the earthquake in Honjo city and Yazawa city, Akita Prefecture; Jishin ni kansuru ishiki chosa (Akitaken Honjoshi oyobi Yuzawashi ni okeru anketo kara)

    Energy Technology Data Exchange (ETDEWEB)

    Nogoshi, M. [Akita University, Akita (Japan). College of Education; Kabutoya, S.

    1996-05-01

    Consciousness for the earthquake was investigated by questionnaire surveys made in Honjo City and Yuzawa City, Akita Pref. in October 1995 twelve years after the Nihonkai Chubu Earthquake (M=7.7) in May 1983. The survey was conducted in terms of 27 items including personality, memory, knowledge/interest, psychology/action, mental attitude/preparations, wishes for researchers and administration, etc. Also included were the items on the Great Hanshin-Awaji Earthquake and the earthquake blank areas. The number of distributed questionnaires and the recovery rate of them are 1500 and 79.2% in Honjo City, and 1700 and 84.7% in Yuzawa City. From the survey, it was found that people have a lot of knowledge of and high interest in the earthquake and well remember it, and a lot of people know of tsunami, liquefaction phenomena, and the earthquake blank area. Further, they are afraid of earthquakes and think of their actions to be taken in case of earthquake. However, most people are little prepared for earthquakes. Important future subjects were suggested for the study of disaster prevention measures. 13 figs.

  1. Study on load levelling by means of the control of air conditioner operation; Kuchoki kado seigyo ni yoru fuka heijunka ni kansuru ichikosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Sasaki, H. [Hiroshima University, Hiroshima (Japan); Sadakuni, S. [Japan Broadcasting Corp., Tokyo (Japan)

    1995-04-20

    The recent drastic increase in the number of air conditioners has caused sharp and narrow peaks in summer seasons due to the inherent temperature sensitive characteristics. The authors proposed to reduce the peak power demand by controlling air conditioner operations, verifying its effectiveness on peak demand clipping. However, the former study has shortcomings in that any qualitative treatment of room temperatures or pleasant feeling was not attempted and it did not provide a way of assessing peak demand clipping in a power system as a whole. In this paper, we shall first propose a new control method that can compromise pleasant feeling and reduction in power demand. Although air conditioners are used to pursue `pleasant feeling`, this contradicts to reduce power consumption and further more the concept of `pleasant feeling` is very vague. Hence, `Weber-Fechner`s law` is utilized to quantify the pleasant feeling which is treated as fuzzy quantity. Fuzzy co-ordination method is used to compromise power demand curtailment and pleasantness. In the second part of this paper, we shall propose an approach of assessing the amount of peak load clipping when the newly proposed control strategy is adopted in a real size power system: A decrease in the required generation capacity is estimated provided that the Loss of Load Probability (LOLP) is maintained at the same level before and after the application of the new control strategy. The reduction can be regarded as a dividend of load management. 5 refs., 9 figs., 5 tabs.

  2. Investigations on an environment friendly chemical reaction process (eco-chemistry). 2; Kankyo ni yasashii kagaku hanno process (eko chemistry) ni kansuru chosa. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    In order to structure a chemical reaction process that does not discharge a large amount of waste by-products or harmful chemical substances, or so-called environment friendly process, investigations and discussions were given based on the results derived in the previous fiscal year. A proposal was made to reduce environmental load on development of oxidized and dehydrogenated catalysts that can produce selectively ethylene, propylene and isobutylene in an oxidation process. In liquid phase oxidation, redox-based oxidation and solid catalyzation of automatic oxidation reaction were enumerated. In acid base catalyst reaction, development of ultra strong solid acid was described to structure no pollution discharging process. In the fine chemical and pharmaceutical fields, the optical active substance method and the position-selective aromatics displacement reaction were evaluated to reduce environmental load. A questionnaire survey performed on major chemical corporations inside and outside the country revealed the following processes as the ones that can cause hidden environmental problems: processes discharging large amount of wastes, processes treating dangerous materials, and processes consuming large amount of energy. Development of catalysts is important that can realize high yield, high selectivity and reactions under mild conditions as a future environment harmonizing chemical process. 117 refs., 23 figs., 22 tabs.

  3. Survey of the trend of technical development and industrial policies in Asian countries; Asia shokoku ni okeru gijutsu kaihatsu no doko to sangyo gijutsu seisaku ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    A sharp rise in industrial productivity in Asia countries indicates a rising level of R and D technology. Since Japan has not clearly grasped the R and D ability in these countries, it has not given appropriate personnel/material R and D support to them. Therefore, for the purpose of exactly grasping the R and D ability of Asian countries (Korea, Taiwan, the Philippines, Indonesia and India) and studying an effective and appropriate method for R and D cooperation, a survey was conducted of R and D potentials in Asia and R and D support policies of the countries. As a result of the survey, the following are taken up as items to be considered: promotion of exchanges between Tsukuba, etc. in Japan and research/university towns and science parks being constructed in lots of countries, participation of private companies in high-tech joint work in cooperation with Japan, sending information from Japan using internet, etc. and exact grasp of needs at partner side, cooperation given to new comers without asking for research results (use of OB researchers, etc.) 25 refs., 39 figs., 59 tabs.

  4. Study on the swirling flow field in a rotating cylinder. 3rd Report. Experiment; Kaiten kannai ni okeru senkai nagareba ni kansuru kenkyu. 3. Jikken

    Energy Technology Data Exchange (ETDEWEB)

    Kishibe, T. [Hitachi, Ltd., Tokyo (Japan); Kaji, S. [The University of Tokyo, Tokyo (Japan). Faculty of Engineering

    2000-02-25

    In the previous papers, the swirling flow field in a rotating hollow turbine shaft was solved using computational fluid dynamics. It was observed that a large-scale spiral vortex existed at a place where the swirling flow turned radially outward. In this report, the pressure fluctuations in the swirling flow field are measured. The main part of the internal cooling air system of a gas turbine is used as the experimental apparatus. A specially devised liner in inserted inside the hollow turbine shaft and ten pressure sensors are embedded axially and circumferentially in the liner to measure the unsteady wall pressures. The pressure fluctuations which have the same characteristics as the rotating spiral vortex predicted in the numerical results are captured. The amplitude is great at the sensors near the place where the vortex was predicted in the numerical results and the precession frequency of the rotating spiral vortex is in close agreement with the calculated frequency. (author)

  5. Study on the impact assessment for the life cycle assessment (LCA); Kankyo fuka bunseki ni okeru impact assessment ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This report describes the impact assessment which is an important step for LCA. For classification of the impact assessment, the existing literature was reviewed and a skeleton for the classification was proposed. The weighting factors for nine selected impact categories, which were used to calculate environmental load point (ELP) for the valuation, were obtained for two overseas groups, i.e., students of Amsterdam University and SETAC Europe members. It was found that the former provided the similar trends to general Japanese, however that the latter gave high weighting in the global warming and depletion of ozone layer. The ELP was proposed and applied to automatic washing machine, coffee maker, waste incineration power generation system, and co-generation system. As a result, its effectiveness was demonstrated. This report also describes problems for the LCA of thermal and material recycling of PS trays. 99 refs., 96 figs., 73 tabs.

  6. Investigation into the analysis method of total ecobalance in chemical industry products. 3; Kagaku kogyo seihin ni okeru total eko balance no bunseki shuho ni kansuru chosa. 3

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    For the purpose of establishing a total life-cycle ecobalance analysis (LCA) method, the paper studied making of a general computer program for chemical industry products. The study has been made on general-purpose plastics (PET/PSP (polystyrene paper)) since fiscal 1993 aiming at making the CO2 emission computing program covering the entire process of production from extraction of raw materials through waste disposal. In fiscal 1995, the following were conducted for enhancement of generalization of the method: expansion of environmental load items and increase in validity of the concept, and expansion of database. Notice was taken of not only CO2 but SOx, NOx and water quality load items. The survey was made on the recycling situation in Japan and abroad and the PET recycling plant , and environmental load item data are collected to expand database. The program was verified by analyzing an example of reusing PET bottle to carpet, and one-step development can be made toward the establishment of the method. Moreover, an analysis was made for the environmental assessment of the related programs abroad, and a tentative original plan can be proposed for the standardization of environmental load analysis and the integrated assessment method. 39 refs., 130 figs., 76 tabs.

  7. Topographical effects on wave exciting forces on huge floating structure. 2; Ogata futaishiki kaiyo kozobutsu ni sayosuru haryoku ni kansuru kenkyu. 2

    Energy Technology Data Exchange (ETDEWEB)

    Imai, Y. [Hiroshima University, Hiroshima (Japan); Okusu, M. [Kyushu Univ., Fukuoka (Japan). Research Inst. for Applied Mechanics

    1996-12-31

    A method to predict drift force acting on a floating structure has been developed for a marine structure consisting of a number of floating elements, positioned in a region having a slope at the sea bottom. When a huge marine structure, such as floating air port, is located in a coastal area, scale of the overall structure is very large, of the order of scale of water depth change. The new method assumes that a marine structure consisting of an infinite number of cylindrical floating elements is installed in parallel to the seashore, where symmetrical nature of the configuration allows to predict behavior of the whole system by analyzing one element. Integration of pressures acting on structure surfaces determines the horizontal component of the drift force acting on the structure. Being influenced by topography, drift force predicted peaks at a frequency different from that for the level predicted on the assumption of constant water depth. This indicates the necessity for consideration of seabottom slope and effects of broken waves at the seashore. 6 refs., 12 figs.

  8. Study of the influence of microgravity on the biological cells and molecular level; Seitai saibo bunshi level ni okeru bisho juryoku no eikyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The shape of osteoblast, gene appearance, gene of rice blast, cellular fusion of plants, gravity acceptance mechanism of unicellular organisms, and physiological and immunity functions of mice were investigated under the microgravity condition. The influence of gravity on the vital reaction and the influence of microgravity on the crystallization of vital substances were also investigated. For the observation of osteoblast, the fluorescence dye reacted with Ca was well taken in the cells. The microgravity affected the stability of rice blast, but hardly affected the protoplast culture of mushroom. The reaction of ciliate against the gravity related to the specific gravity difference between cells and outer liquid. The level of adrenaline in blood of mice increased during the drop. The moving speed of trigger waves of chemical parallel slit formed at the BZ reaction under the microgravity became 60% to 80% of that on the ground. In the case of crystallization at the deposition agent concentration of 1% to 4%, the turbidity showing the degree of crystallization changed complicatedly. Nine processes of crystal growth were recognized. 21 refs., 55 figs., 1 tab.

  9. Study on wind resistant design of long-span bridges based on field observation result; Dotai kansoku kekka ni motozuku chodaikyo no taifu sekkei ni kansuru kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Katsuchi, H.; Tada, K.; Kitagawa, M.

    1996-07-21

    Based on records of strong wind and bridge response to the 19th typhoon in 1991 and 13th typhoon in 1993 at the Onaruto Bridge and the Minami Bisan-Seto Bridge as well as results of numerical analysis, the validity of wind resistant design was investigated. The validity of current wind resistant design was confirmed for the intensity of turbulence and the power spectrum among the natural wind properties. The spatial correlation property was expressed better by Karman`s correlation equation than by usual exponential function equation. The bridge response value was evaluated well by using Karman`s correlation equation, as to bridge response properties, and especially the gust response properties. It was more rational to apply Karman`s correlation equation rather than usual exponential equation to the wind resistant design of long-span bridges. It was suggested that the evaluation of the wind load in the wind resistant design can be reduced. Accordingly, the design of long-span bridges, whose structures can be determined by the wind load, can be rationalized. 20 refs., 13 figs., 2 tabs.

  10. Topographical effects on wave exciting forces on huge floating structure. 2; Ogata futaishiki kaiyo kozobutsu ni sayosuru haryoku ni kansuru kenkyu. 2

    Energy Technology Data Exchange (ETDEWEB)

    Imai, Y. [Hiroshima University, Hiroshima (Japan); Okusu, M. [Kyushu Univ., Fukuoka (Japan). Research Inst. for Applied Mechanics

    1996-12-31

    A method to predict drift force acting on a floating structure has been developed for a marine structure consisting of a number of floating elements, positioned in a region having a slope at the sea bottom. When a huge marine structure, such as floating air port, is located in a coastal area, scale of the overall structure is very large, of the order of scale of water depth change. The new method assumes that a marine structure consisting of an infinite number of cylindrical floating elements is installed in parallel to the seashore, where symmetrical nature of the configuration allows to predict behavior of the whole system by analyzing one element. Integration of pressures acting on structure surfaces determines the horizontal component of the drift force acting on the structure. Being influenced by topography, drift force predicted peaks at a frequency different from that for the level predicted on the assumption of constant water depth. This indicates the necessity for consideration of seabottom slope and effects of broken waves at the seashore. 6 refs., 12 figs.

  11. Study of installation of PV systems at campus; Campus ni okeru taiyoko hatsuden donyu ni kansuru kenkyu (taiyo denchi nomi wo secchishita baai no yobi kento)

    Energy Technology Data Exchange (ETDEWEB)

    Tsuboi, N.; Tanaka, H.; Okumiya, M. [Nagoya University, Nagoya (Japan)

    1997-11-25

    In terms of energy consumption, environmentality and economical efficiency in the case of installing the photovoltaic power system on the rooftop of the university campus, a comparative study was conducted with other power generation systems. As objects to be comparatively studied, selected were the all-electric type centralized space heating/cooling system, cogeneration system, nighttime heat storage system and centralized system with solar cells installed. The panel area of the PV system is 10,000m{sup 2} on the rooftop and 7,000{sup 2} on the outer wall. About data on solar radiation, average values obtained in Nagoya were used. Assessment was made in terms of energy consumption amount at the time of operation, system COP, emission amounts of CO2, NOx and SOx at the time of manufacturing and operation, initial cost, running cost, etc. As a result of the study, an effect of reducing global warming gas was admitted in the PV system. However, the initial cost of the solar cell panel was high, and the life cycle cost of the PV system was lower than other systems. 1 ref., 7 figs., 3 tabs.

  12. Experimental study on particulate materials collected by a concave of sea floor; Kaitei kubochi ni hoshusareru ryujobutsu ni kansuru jikkenteki kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Hoshika, A.; Tanimoto, T. [Government Industrial Research Chugoku, Hiroshima (Japan)

    1996-07-10

    As one of the method of sea cleaning method, an idea where concave is dredged on the sea floor and suspended substances and polluted sediment particles are collected, is popular. In this research, simple experiment was carried out for collecting the materials by using a polyvinylchloride cylindrical vessel (50cm in diameter, 70cm in depth) set on the sea floor of Osaka Bay area and fundamental study about the quality of collected materials, collection effectiveness and so forth was carried out. Further, along with the collection experiment, measurement of degree of pollution and investigation of bottom laminar flow which is thought to be the direct outer force for particulate material movement were carried out in order to study the flow mechanism of particulate materials. As a result, with the setting of collection vessel, particulate materials about 9 times more than that of estimated natural sedimentation amount were collected. This corresponds to the 5% of the horizontal flux of suspended substances in the bottom layer water. Among the collected particulate materials, about 30% are suspended substances, about 70% are surface sediment substances. This kind of method, when combined suitably with the method for removing collected particulate materials, can be one of the effective method for the purification of polluted sediment materials. 8 refs., 9 figs., 3 tabs.

  13. Experimental study on onset of asthma like symptoms by diesel exhausts particles (DEP); Diesel haiki biryushi (DEP) ni yoru zensoku yo byotai no hassho ni kansuru jikkenteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Sagai, M. [National Research Inst. for Environmental Studies, Tsukuba (Japan)

    1995-03-10

    By experiments using mice, facts which suggest that diesel exhaust particles (DEP) produce a large amount of superoxide (O2{sup -})by chemical or biochemical reaction and this superoxide causes lung injury with a result of asthma like symptoms. It is verified, by the use of mice, that four fundamental symptoms of the onset of asthma like symptoms, i.e. rise of blood vessel permeability, mucus hypersecretion, inflammation accompanying chronic eosinophil infiltration, and airway hyperresponsiveness, are caused by DEP. It can be derived from the fact that mankind asthma may also be caused by DEP. The knowledge obtained by this experiment, which indicates that DEP causes chronic inflammation accompanying eosinophil infiltration, may add important information to the study on the causal relationship of DEP with asthma symptoms. 31 refs., 15 figs., 1 tab.

  14. Experimental investigation of the effects of the car driver`s postures on sleepiness; Chakuza shisei ga nemuke ni oyobosu eikyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Komatsudani, M.; Okamura, C. [Toyo Seat Co. Ltd., Hiroshima (Japan); Nishiyama, S. [Hiroshima City Industrial Technology Institute, Hiroshima (Japan); Nozawa, T.; Nishikawa, K. [Matsuda Motor Corp., Hiroshima (Japan); Hori, T.; Hayashi, M. [Hiroshima University, Hiroshima (Japan)

    1998-05-01

    Effects of car driver`s postures on sleepiness were experimentally investigated. For the measurement method of EEG (electroencephalogram), bipolar induction was adopted, to record Cz and Pz using those at left ear as standard by international 10-20 electrode method. In addition, differential potential was recorded between locations of Cz and Pz. The time constant of EEG was set in 0.3 sec. Brain waves were measured for one minute under open and close eye conditions before and after each test as EEG at the rest. For the measurement of EOG (electro-oculograph), vertical and horizontal eye motions were observed. Induced potential change was measured by attaching silver-silver chloride electrode at the time constant 1.5 sec. For the measurement of SPL (skin potential level), the palm of left hand was used as a measuring point and the left front arm was used as a reference point for attaching electrodes. The danger of sleepiness was provided by the boring driving conditions independent of driver`s postures. There was a difference of relaxation time due to the driver`s postures. It was difficult to avoid sleepiness by adjusting the relative angle between seat and seat back. However, it was found that the angle 110deg was most suitable for avoiding sleepiness. 7 refs., 5 figs., 2 tabs.

  15. Research on giving antibacteria activity of tailored dental materials; Gin ion ni yoru shikayo zairyo no kokinsei fuyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The secondary dental caries easily occur by breeding of bacteria in cavities between living body and composite resin, false tooth or root of tailored tooth as tooth repairing materials. The antibacteria activity of tailored dental materials was thus studied by implanting Ag ion. The antibacteria effect with time after culture of caries bacteria was studied by implanting Ag ion into SiO2 powder, PMMA samples and Ti alloy samples at 20 and 200keV in energy of ion. In addition, the antibacteria activity of SiO2 powder as composite material was found at 25keV which was previously effective for the antibacteria activity. This SiO2 filler (Ag{sup +} filler) showed the antibacteria activity on every bacteria sample after 2h, and in particular, could kill all of 3 kinds of bacteria obtained from a composite resin surface after 12h. The number of living S. salivarius was reduced by half after 12h. The application of the composite resin filler implanted with Ag{sup +} is significant to prevent recurrence of caries. 5 refs., 27 figs., 7 tabs.

  16. Study on the effect of measurement points upon reduced added mass matrix; Shukusho fuka shitsuryo matrix ni okeru kansokuten no eikyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Funaki, T.; Hayashi, S. [Osaka University, Osaka (Japan). Faculty of engineering

    1996-12-31

    It is known in estimating vibration characteristics of a ship that fluid range affects largely a structure. A parameter calculation was performed on node vibration in the vertical direction of a rotating elliptic body such as a ship to investigate the effect of an arranging method of the measurement points upon the result of the analysis. As a result, it is thought that equivalent interval arrangement of 21 measurement points would be sufficient in a lower order side mode of vibrations with less than four nodes. An analysis of calculations performed by arranging measurement points in experimental measurement points revealed that analysis accuracy would not increase even if the number of measurement points is increased if it is done so without considering rotation vector. An experiment was carried out with the number of measurement points increased to verify the above fact, with which the analysis was verified correct. Therefore, as has been forecasted in the previous report, the cause for the analysis accuracy deterioration in a high order mode may be estimated as the effect of the rotation vector. However, since it is not the situation that an analysis considering the rotation vector has been conducted, it cannot be concluded yet that the effect of the rotation vector is the sole cause. 4 refs., 14 figs., 7 tabs.

  17. Investigation on innovation of technology development by means of strategic energy intelligence; Energy senryakurontekina approach ni yoru gijutsu kaihatsu no kakushin ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    For the purpose of developing the future innovative energy technology, the paper described a strategic point of view. Effects of the energy issue are remarkable on the next generation and thereafter as seen in the finite of energy resource, global-scale environmental changes, the increasing energy demand, natural/social influences of large-scale technology development. If the technological development is going on in the same way as until now, there will appear limits. Relating to the strategies, to seek what energy should be among the strategies, it is necessary to consider not only global-scale problems but particular conditions in Japan (self-sufficiency, international cooperation, creativity, etc.) Also, wisdom and technique are necessary to attain it. Technological development in a wide sense plays a major role in the energy strategy. Technology innovation must be advanced according to the energy strategy. Integrating ideology into the development of energy technology and selecting therefrom developmental subjects which meet the purpose, required is the construction of the energy system with high flexibility and functionality. Looking at the conventional way of thinking from a different angle and posing a future pull plan, Japan should show leadership to the world. 20 refs., 25 figs., 8 tabs.

  18. Interface Physical Chemistry of Enamel (3). Action of Cobalt at Enamel Reaction; Horo ni kansuru kaimen butsurikagakuteki kenkyu (3). Horo kaimen ni oyobosu kabaruto no sayo

    Energy Technology Data Exchange (ETDEWEB)

    Shirasaki, Masahiro.; Shimizu, Tadao.; Kozuka, Tatsuya. [Chiba Institute of Technology, Chiba (Japan), Department of Industrial Chemistry; Jiang, Zhaohua. [Harbi Institute of Technology, Harbin (China), Department of Applied Chemistry

    1999-02-01

    The effect of cobalt on enamel reaction was studied using Co-vitreous enamel. Observation and analysis of Co-vitreous enamel interface were performed with scanning electron microscope, X-ray photoelectron spectrometer and X-ray diffractometer. The following results were obtained. (1) The sunken parts of Co-vitreous enamel interface were formed by erosion of the base iron. Cobalt and iron deposited on the base iron and formed convex parts. Further, the convex parts grew by firing from the initial interface towards the glass (enamel layer) side. (2) Interface layer of Co-vitreous enamel was consisted of two layers. The first interface layer was very thin and consisted of CoFe{sub 2}O{sub 4} or FeFe{sub 2}O{sub 4}. The second interface layer was the iron solid solution containing cobalt. The thickness of Co-vitreous enamel reaction layer was thicker than the rough parts (3) The Co-vitreous enamel reaction was a galvanic cell reaction between base iron and cobalt ion in glass. Cobalt circulate by reaction as deposition, oxidation and dissolution. (author)

  19. Research of environmental bioecosensing technology using ecological information. Part 2; Seitaikei joho ni yoru kankyo bio ecosencing gijutsu ni kansuru chosa. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Basic considerations of exploring and cultivating environmental reporter organisms are summarized. Mechanism of genetic engineering amplification and molecular biological amplification, and approach to combining them to a hardware as a bioindicator system are investigated. For the current status of molecular biological measurement technology for measuring ecological environment and its application, environmental diagnosis from a phyropathological viewpoint, environmental diagnosis using microorganisms, test fabrication of genetic sensor, and overseas examples of environmental monitoring network are described. For the application of ecological information and functions for developing innovative environmental remediation technology, issues and potential areas for research and development regarding the bioremediation technology in which the US has achieved a progress for the benefit of soil environment remediation are summarized. For the phytoremediation, an area of bioremediation, the metabolism of microorganisms which live in the rhizosphere, and the technology for controlling the microorganisms in the soil through plants are investigated. 66 refs., 50 figs., 17 tabs.

  20. Study on vibration fatigue damage due to the blow of OPGW aluminum tube; OPGW aluminium kan no kyofu ni yoru shindo hiro hason ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Aikawa, S.; Kohara, H. [Chugoku Electric Power Co. Inc., Hiroshima (Japan)

    2000-03-24

    The cause of damage in the cashing portion of an aluminum tube incorporating OPGW (OPAC 120mm{sup 2}) was investigated and proper measures for the prevention of recurrence were examined. The investigation result of the past accident of the same kind or the result of stress measurement showed that the cause of aluminum tube damage is the fatigue rupture based on the repeated stress occurring by the rolling of OPGW. Moreover, it was known that the attached wire in a jumper lead-in system is most effective and valid as preventative measures of damage. (translated by NEDO)

  1. Study of fuel control strategy based on an fuel behavior model for starting conditions; Nenryo kyodo model ni motozuita shidoji no nenryo hosei hosho ni tsuite no kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Nakajima, Y.; Uchida, M.; Iwano, H.; Oba, H. [Nissan Motor Co. Ltd., Tokyo (Japan)

    1997-10-01

    We have applied a fuel behavior model to a fuel injection system which we call SOFIS (Sophisticated and Optimized Fuel Injection System) so that we get air/fuel ratio control accuracy and good driveability. However the fuel behavior under starting conditions is still not clear. To meet low emission rules and to get better driveability under starting conditions, better air/fuel ratio control is necessary. Now we have understood the ignition timing, injection timing, and injection pulse width required in such conditions. In former days, we analyzed the state of the air/fuel mixture under cold conditions and made a new fuel behavior model which considered fuel loss such as hydrocarbons and dissolution into oil and so on. Al this time, we have applied this idea to starting. We confirm this new model offers improved air/fuel ratio control. 6 refs., 9 figs., 3 tabs.

  2. Modeling premartensitic effects in Ni2MnGa: A mean-field and Monte Carlo simulation study

    DEFF Research Database (Denmark)

    Castan, T.; Vives, E.; Lindgård, Per-Anker

    1999-01-01

    Carlo simulations. This last technique reveals the crucial importance of fluctuations in pretransitional effects. The results show that a variety of premartensitic effects may appear due to the magnetoelastic coupling. In the mean-held formulation this coupling is quadratic in both the modulation...... such coupling is strong enough to freeze the involved mode phonon. The implication of the results in relation to the available experimental data is discussed.......The degenerate Blume-Emery-Griffiths model for martensitic transformations is extended by including both structural and magnetic degrees of freedom in order to elucidate premartensitic effects. Special attention is paid to the effect of the magnetoelastic coupling in Ni2MnGa. The microscopic model...

  3. Modeling of diffusion mechanism of conductive channel oxidation in a Pt/NiO/Pt memory switching structure

    Science.gov (United States)

    Sysun, V. I.; Bute, I. V.; Boriskov, P. P.

    2016-09-01

    The transition process from the low resistance state into the high resistance state in a Pt/NiO/Pt memory switching structure has been studied by numerical modeling. Detailed analysis shows, that thermally induced diffusion oxidation by nickel vacancies is the key factor for distortion of the channel metallic conductivity. Spatial dynamics of the process of oxidation defines channel narrowing mainly in its central part, and also sets the critical current through the structure sufficient for final rupture of the channel and the transition to high resistance state. The increase in critical current above the limit even by 10% reduces the switching time by an order of magnitude, which is in agreement with experiments. The developed radial diffusion model of conductive channel (or filaments) oxidation may be suitable for the analysis of switching effect a number of other ReRAM oxide structures.

  4. Shell model description of Gamow-Teller strengths for $^{42}$Ti, $^{46}$Cr, $^{50}$Fe and $^{54}$Ni

    CERN Document Server

    Kumar, Vikas; Hirsch, Jorge G

    2015-01-01

    A systematic shell model description of the experimental Gamow-Teller transition strength distributions in $^{42}$Ti, $^{46}$Cr, $^{50}$Fe and $^{54}$Ni is presented. These transitions have been recently measured via $\\beta$ decay of these $T_z$=-1 nuclei, produced in fragmentation reactions at GSI and also with ($^3${He},$t$) charge-exchange (CE) reactions corresponding to $T_z = + 1$ to $T_z = 0$ carried out at RCNP-Osaka. The calculations are performed in the $pf$ model space, using the GXPF1a and KB3G effective interactions. Qualitative agreement is obtained for the individual transitions, while the calculated summed transition strengths closely reproduce the observed ones.

  5. CONFIGURATION-INTERACTION IN NI METAL AND NI-ALLOYS AND HIGH-ENERGY SPECTROSCOPY

    NARCIS (Netherlands)

    TANAKA, A; JO, T; SAWATZKY, GA

    1992-01-01

    We discuss the electronic state of Ni atoms in Ni metal and of Ni impurity in Cu and Au metals from the viewpoint of 3d configuration interaction (CI) using the Anderson impurity model including atomic multiplets. On the basis of the discussion, we give an interpretation for the Ni 2p-core X-ray pho

  6. Separation of Cd and Ni from multicomponent aqueous solutions by nanofiltration and characterization of membrane using IT model

    Energy Technology Data Exchange (ETDEWEB)

    Chaudhari, Latesh B. [Department of Chemical Engineering, S.V. National Institute of Technology, Surat 395007, Gujarat (India); Department of Chemical Engineering, N.G. Patel Polytechnic, Isroli-Afwa, Tal. Bardoli, Dist. Surat 394620, Gujarat (India); Murthy, Z.V.P., E-mail: zvpm2000@yahoo.com [Department of Chemical Engineering, S.V. National Institute of Technology, Surat 395007, Gujarat (India)

    2010-08-15

    Removal of heavy metals from wastewater is of critical importance due to their high toxicity and tendency to accumulate in living organisms. In the present work, performance of a nanofiltration (NF) membrane has been studied to separate cadmium and nickel ions from multicomponent aqueous solutions at different operating conditions. It is observed that the separation of cadmium and nickel ions increases with increase in applied pressure and decreases with increase in feed concentration at a constant feed flow rate. The maximum observed solutes rejection of cadmium and nickel ions are 80.57% and 85.27% for CdCl{sub 2}-NiCl{sub 2}-water system and 97.26% and 98.90% for CdSO{sub 4}-NiSO{sub 4}-water system, respectively, for an initial feed concentration of 0.005 g/L. This difference in rejection is due to the charge density of the anions. It is also observed that the order of solute rejection sequence is inversely proportional to the diffusion coefficient. The NF membrane is characterized by an irreversible thermodynamics (IT) based Spiegler-Kedem model, coupled with film theory. Boundary-layer thickness and membrane transport parameters are estimated using Levenberg-Marquadt method. The estimated parameters are used to predict the membrane performance and found that the predicted values are in satisfactory agreement with the experimental results.

  7. Modeling of heat transfer processes in Ni{sub 2}MnIn magnetic wires

    Energy Technology Data Exchange (ETDEWEB)

    Pavlukhina, Oksana; Buchelnikov, Vasiliy [Chelyabinsk State University (Russian Federation); Sokolovskiy, Vladimir [Chelyabinsk State University (Russian Federation); National University of Science and Technology ' ' MISiS' ' , Moscow (Russian Federation)

    2016-02-15

    In this work, we study a heat transfer in the three-dimensional magnetic cooling cell involving microwires of NiMnIn Heusler alloy. Thermophysical properties of microwires such as the heat capacity, magnetic part of entropy, and magnetocaloric effect were investigated by means of Monte Carlo simulations with parameters taken from ab initio calculations as input. The diameter of the magnetic wires was varied from 10 to 50 m while the length was fixed to 1 mm. The system is supplied a coolant water flow at a constant speed and temperature. We have shown that the cooling power depends on the magnetic wire thickness and the coolant flow rate. The relaxation times of the temperature of wires, the temperature distribution in the magnetic wires and coolant, as well as the velocity fields of a coolant in the cell were calculated. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  8. Constitutive modeling of tension-torsion coupling and tension-compression asymmetry in NiTi shape memory alloys

    Science.gov (United States)

    Mehrabi, Reza; Kadkhodaei, Mahmoud; Elahinia, Mohammad

    2014-07-01

    A three-dimensional phenomenological model based on microplane theory is extended to capture the coupling effects between tension and torsion in complex multiaxial loadings. Inelastic strain in a microplane approach is a component of transformation strain and anisotropic strain. Since the anisotropy effect is induced during martensitic transformation, anisotropic strain is defined as a function of transformation strain. Out-of-plane strain is induced in simple tension and pure torsion in free-end conditions. Anisotropy tensor is experimentally extracted and is used in the proposed model to predict the behavior in multiaxial loading. The ability of this extended microplane model to predict the tension-torsion coupling effects as well as the induced transformation anisotropic behavior of NiTi shape memory alloys is demonstrated. In addition, the microplane model is modified to capture the asymmetric behavior in tension and compression during uniaxial and multiaxial loadings. To this end, numerical correlations between the results of the modified microplane model are compared with experimental results to demonstrate the validity of the extended model.

  9. Applicability of Johnson-Mehl-Avrami model to crystallization kinetics of Zr60Al15Ni25 bulk amorphous alloy

    Institute of Scientific and Technical Information of China (English)

    YAN Zhi-jie; DANG Shu-e; WANG Xiang-hui; LIAN Pei-xia

    2008-01-01

    The applicability of Johnson-Mehl-Avrami(JMA) model to the crystallization kinetics of Zr60Al15Ni25 bulk amorphous alloy is investigated by differential scanning calorimetry(DSC) under isochronal and isothermal conditions. A criterion xm, at which a defined function z(x) exhibits the maximum value, is introduced to check the validity of JMA model to the kinetics analysis. The value of xm has a constant of 0.632 for JMA model. It is found that the values of xm at different isothermal annealing temperatures (743, 748, 753 and 758 K) are almost near 0.632, which indicates that the isothermal crystallization kinetics can be modeled by JMA equation. However, the values of xm at different heating rates (10, 20, 30 and 40 K/min) are about 0.52, implying that JMA model is not valid to the isochronal crystallization kinetics. The reason why the JMA model is not valid to the isochronal crystallization kinetics is discussed.

  10. Development of Computational Tools for Modeling Thermal and Radiation Effects on Grain Boundary Segregation and Precipitation in Fe-Cr-Ni-based Alloys

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Ying [ORNL

    2017-08-01

    This work aims at developing computational tools for modeling thermal and radiation effects on solute segregation at grain boundaries (GBs) and precipitation. This report described two major efforts. One is the development of computational tools on integrated modeling of thermal equilibrium segregation (TES) and radiation-induced segregation (RIS), from which synergistic effects of thermal and radiation, pre-existing GB segregation have been taken into consideration. This integrated modeling was used in describing the Cr and Ni segregation in the Fe-Cr-Ni alloys. The other effort is thermodynamic modeling on the Fe-Cr-Ni-Mo system which includes the major alloying elements in the investigated alloys in the Advanced Radiation Resistant Materials (ARRM) program. Through thermodynamic calculation, we provide baseline thermodynamic stability of the hardening phase Ni2(Cr,Mo) in selected Ni-based super alloys, and contribute knowledge on mechanistic understanding on the formation of Ni2(Cr,Mo) in the irradiated materials. The major outcomes from this work are listed in the following: 1) Under the simultaneous thermal and irradiation conditions, radiation-induced segregation played a dominant role in the GB segregation. The pre-existing GB segregation only affects the subsequent radiation-induced segregation in the short time. For the same element, the segregation tendency of Cr and Ni due to TES is opposite to it from RIS. The opposite tendency can lead to the formation of W-shape profile. These findings are consistent with literature observation of the transitory W-shape profile. 2) While TES only affects the distance of one or two atomic layers from GBs, the RIS can affect a broader distance from GB. Therefore, the W-shape due to pre-existing GB segregation is much narrower than that due to composition gradient formed during the transient state. Considering the measurement resolution of Auger or STEM analysis, the segregation tendency due to RIS should play a dominant

  11. Static Softening in a Ni-30Fe Austenitic Model Alloy After Hot Deformation: Microstructure and Texture Evolution

    Science.gov (United States)

    Beladi, Hossein; Cizek, Pavel; Taylor, Adam S.; Rohrer, Gregory S.; Hodgson, Peter D.

    2017-02-01

    In the current study, the microstructure and texture characteristics of a model Ni-30Fe austenitic alloy were investigated during hot deformation and subsequent isothermal holding. The deformation led to the formation of self-screening arrays of microbands within a majority of grains. The microbands characteristics underwent rather modest changes during the post-deformation annealing, which suggests that limited dislocation annihilation occurs within the corresponding dislocation walls. The fraction of statically recrystallized (SRX) grains progressively increased with the holding time and closely matched the softening fraction measured from the offset flow stress approach. The corresponding texture was weak and preserved its character with the holding time. There was no pronounced temperature effect on the grain boundary character distribution after the completion of SRX. The Σ3 and Σ9 coincidence site lattice boundaries were characterized as (111) pure twist and (1-14) symmetric tilt types, respectively. Nonetheless, the recrystallization temperature slightly affected the grain boundary network.

  12. Ana insect model for assessing arsenic toxicity: Arsenic elevated glutathione content in the musca domestica and trichoplusia ni

    Energy Technology Data Exchange (ETDEWEB)

    Zaman, K.; Pardini, R.S. [Univ. of Nevada, Reno, NV (United States)

    1995-12-01

    Throughout history, arsenic has acquired an unparalled reputation as a poison. Arsenic was used as a poison as early as 2000 B.C. The toxicity of arsenic (As) extends to mammals, fish, insects, plants and fungi. According to epidemiological evidence, inorganic arsenic compounds have been strongly suggested as human carcinogens. Human exposure to arsenic through various means is correlated with an increased incidence of skin, lung, and possibly liver cancers. Inorganic trivalent arsenic is systematically more poisonous than the pentavalent form and it is possible that pentavalent arsenic is reduced to the trivalent form before exerting any toxic effects. This study focuses on the potential to use two insect species, the housefly, Musca domestica and the cabbage looper moth, Trichoplusia ni, and a model for the study of arsenic toxicity. After 48 hours of exposure to Arsenic, a significant induction of Glutathione level and subsequent decrease in the level of GSSG in both species were observed. 21 refs., 2 figs., 1 tab.

  13. Simulation of shock-induced melting of Ni using molecular dynamics coupled to a two-temperature model

    Science.gov (United States)

    Koči, L.; Bringa, E. M.; Ivanov, D. S.; Hawreliak, J.; McNaney, J.; Higginbotham, A.; Zhigilei, L. V.; Belonoshko, A. B.; Remington, B. A.; Ahuja, R.

    2006-07-01

    Using nonequilibrium molecular dynamics (MD) simulations we study shock-induced melting in Ni with an embedded atom method (EAM). Dynamic melting is probed by the pair correlation function, and we find a melting lattice temperature of Tmelt=6400±300K for a melting pressure of Pmelt=275±10GPa . When a combined MD+TTM (two-temperature model) approach is used to include electronic heat conduction and electron-phonon coupling, Pmelt and Tmelt change. For a given pressure, the temperature behind the shock decreases due to electronic heat diffusion into the cold, unshocked material. This cooling of the material behind the shock slightly increases the melting pressure compared to simulations without electronic heat conduction and electron-phonon coupling. The decrease in the temperature behind the shock front is enhanced if the electron-phonon coupling is artificially made larger. We also explore the feasibility of using x-ray diffraction to detect melting.

  14. An empirical-statistical model for coaxial laser cladding of NiCrAlY powder on Inconel 738 superalloy

    Science.gov (United States)

    Ansari, M.; Shoja Razavi, R.; Barekat, M.

    2016-12-01

    In this study, coaxial laser cladding of NiCrAlY powder on a nickel-based superalloy is investigated from an experimental point of view so as to propose an empirical-statistical model for the process. The correlations between main processing parameters (i.e. scanning speed, powder feeding rate, and laser power) and geometrical characteristics (i.e. width, height, penetration depth, dilution and wetting angle) of single clad tracks have been predicted and are discussed using regression analysis (RA). The validity of the predictions is confirmed by providing correlation coefficient and analysis of the residuals. The correlations are established as a combined parameter (PαVβFγ) for each studied characteristic of single clad tracks. These correlations finally lead to the design of a processing map that can be practically used to select proper processing parameters for laser cladding of the particular material.

  15. Modelling and characterization of chi-phase grain boundary precipitation during aging of Fe-Cr-Ni-Mo stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Xu, W. [Netherlands Institute for Metals Research, Mekelweg 2, 2628 CD Delft (Netherlands)], E-mail: w.xu@nimr.nl; San Martin, D.; Rivera Diaz del Castillo, P.E.J.; Zwaag, S. van der [Fundamentals of Advanced Materials Group, Faculty of Aerospace Engineering, Delft University of Technology, Kluyverweg 1, 2629 HS Delft (Netherlands)

    2007-10-15

    High molybdenum stainless steels may contain the chi-phase precipitate ({chi}, Fe{sub 36}Cr{sub 12}Mo{sub 10}) which may lead to undesirable effects on strength, toughness and corrosion resistance. In the present work, specimens of a 12Cr-9Ni-4Mo wt% steel are heat treated at different temperatures and times, and the average particle size and particle size distribution of chi-phase precipitate are studied quantitatively. A computer model based on the KWN framework has been developed to describe the evolution of chi-phase precipitation. The kinetic model takes advantage of the KWN model to describe the precipitate particle size distribution, and is coupled with the thermodynamic software ThermoCalc for calculating the instantaneous local thermodynamic equilibrium condition at the interface and the driving force for nucleation. A modified version of Zener's theory accounting for capillarity effects at early growth stages is implemented in this model. The prediction of the model for chi-phase precipitation at a grain boundary is compared to experimental results and both the average particle size and the particle size distribution are found to be in good agreement with experimental observations at late precipitation stages.

  16. A uniaxial constitutive model for superelastic NiTi SMA including R-phase and martensite transformations and thermal effects

    Science.gov (United States)

    Helbert, Guillaume; Saint-Sulpice, Luc; Arbab Chirani, Shabnam; Dieng, Lamine; Lecompte, Thibaut; Calloch, Sylvain; Pilvin, Philippe

    2017-02-01

    The well-known martensitic transformation is not always the unique solid-solid phase change in NiTi shape memory alloys (SMA). For this material, R-phase can occur from both austenite and martensite. In some applications, macroscopic strain of the material can be limited to 2%. In these cases, R-phase contribution can not be neglected anymore when compared with martensite. Furthermore, different thermomechanical couplings have to be taken into account to carefully predict strain rate effects and to better describe application conditions. In this paper, a new model taking into account various phase transformations with thermomechanical couplings is presented. This model is based on several transformation criteria. In most applications, SMA are used as wires, submitted to tensile-tensile loadings, in the superelasticity working range. Consequently, a uniaxial reduction of the model is presented for its simplicity. A thermodynamic framework is proposed. It enables to describe the internal variables evolution laws. The simple and fast identification process of model parameters is briefly presented. To verify the validity of the proposed model, simulation results are compared with experimental ones. The influences of testing temperature and strain amplitude on the material behavior is discussed. The damping capacity is also studied, using an energy-based criterion.

  17. Modelling of CH4 multiple-reforming within the Ni-YSZ anode of a solid oxide fuel cell

    Science.gov (United States)

    Tran, Dang Long; Tran, Quang Tuyen; Sakamoto, Mio; Sasaki, Kazunari; Shiratori, Yusuke

    2017-08-01

    A new approach for the modelling of the simultaneous dry and steam reforming of CH4 (methane multiple-reforming (MMR)) within the Ni-YSZ anode of a solid oxide fuel cell (SOFC) is introduced in this paper. MMR is modelled by using artificial neural network (ANN) and fuzzy inference system (FIS) that can express the gas composition and temperature dependences of the consumption or the production rate of gaseous species involved in MMR. The necessary parameters for this approach are determined from the measured reforming kinetics for an anode-supported cell (ASC) fuelled by a CH4-CO2-H2O-N2 mixture. The developed MMR model is incorporated into a 3D-CFD planar ASC model to calculate the SOFC performance, and the calculated results match well with experimental values for the feed of simulated biogas (CH4/CO2 = 1) and H2. The established SOFC model considering MMR is a powerful tool to simulate the performance of internal reforming SOFC.

  18. Influence of Al content on non-equilibrium solidification behavior of Ni-Al-Ta model single crystal alloys

    Science.gov (United States)

    Ai, Cheng; Zhou, Jian; Zhang, Heng; Zhao, Xinbao; Pei, Yanling; Li, Shusuo; Gong, Shengkai

    2016-01-01

    The non-equilibrium solidification behaviors of five Ni-Al-Ta ternary model single crystal alloys with different Al contents were investigated by experimental analysis and theoretical calculation (by JMatPro) in this study. These model alloys respectively represented the γ' phase with various volume fractions (100%, 75%, 50%, 25% and 0%) at 900 °C. It was found that with decreasing Al content, liquidus temperature of experimental alloys first decreased and then increased. Meanwhile, the solidification range showed a continued downward trend. In addition, with decreasing Al content, the primary phases of non-equilibrium solidified model alloys gradually transformed from γ' phase to γ phase, and the area fraction of which first decreased and then increased. Moreover, the interdendritic/intercellular precipitation of model alloys changed from β phase (for 100% γ') to (γ+γ')Eutectic (for 75% γ'), (γ+γ')Eutectic+γ' (for 50% γ' and 25% γ') and none interdendritic precipitation (for 0% γ'), and the last stage non-equilibrium solidification sequence of model alloys was determined by the nominal Al content and different microsegregation behaviors of Al element.

  19. Competitive sorption and selective sequence of Cu(II) and Ni(II) on montmorillonite: Batch, modeling, EPR and XAS studies

    Science.gov (United States)

    Yang, Shitong; Ren, Xuemei; Zhao, Guixia; Shi, Weiqun; Montavon, Gilles; Grambow, Bernd; Wang, Xiangke

    2015-10-01

    Heavy metal ions that leach from various industrial and agricultural processes are simultaneously present in the contaminated soil and water systems. The competitive sorption of these toxic metal ions on the natural soil components and sediments significantly influences their migration, bioavailability and ecotoxicity in the geochemical environment. In this study, the competitive sorption and selectivity order of Cu(II) and Ni(II) on montmorillonite are investigated by combining the batch experiments, X-ray diffraction (XRD), electron paramagnetic resonance (EPR), surface complexation modeling and X-ray Absorption Spectroscopy (XAS). The batch experimental data show that the coexisting Ni(II) exhibits a negligible influence on the sorption behavior of Cu(II), whereas the coexisting Cu(II) reduces the Ni(II) sorption percentage and changes the shape of the Ni(II) sorption isotherm. The sorption species of Cu(II) and Ni(II) on montmorillonite over the acidic and near-neutral pH range are well simulated by the surface complexation modeling. However, this model cannot identify the occurrence of surface nucleation and the co-precipitation processes at a highly alkaline pH. Based on the results of the EPR and XAS analyses, the microstructures of Cu(II) on montmorillonite are identified as the hydrated free Cu(II) ions at pH 5.0, inner-sphere surface complexes at pH 6.0 and the surface dimers/Cu(OH)2(s) precipitate at pH 8.0 in the single-solute and the binary-solute systems. For the Ni(II) sorption in the single-solute system, the formed microstructure varies from the hydrated free Ni(II) ions at the pH values of 5.0 and 6.0 to the inner-sphere surface complexes at pH 8.0. For the Ni(II) sorption in the binary-solute system, the coexisting Cu(II) induces the formation of the inner-sphere complexes at pH 6.0. In contrast, Ni(II) is adsorbed on montmorillonite via the formation of Ni phyllosilicate co-precipitate/α-Ni(OH)2(s) precipitate at pH 8.0. The selective sequence

  20. Kinetics of Ni sorption in soils: roles of soil organic matter and Ni precipitation.

    Science.gov (United States)

    Shi, Zhenqing; Peltier, Edward; Sparks, Donald L

    2012-02-21

    The kinetics of Ni sorption to two Delaware agricultural soils were studied to quantitatively assess the relative importance of Ni adsorption on soil organic matter (SOM) and the formation of Ni layered double hydroxide (Ni-LDH) precipitates using both experimental studies and kinetic modeling. Batch sorption kinetic experiments were conducted with both soils at pH 6.0, 7.0, and 7.5 from 24 h up to 1 month. Time-resolved Ni speciation in soils was determined by X-ray absorption spectroscopy (XAS) during the kinetic experiments. A kinetics model was developed to describe Ni kinetic reactions under various reaction conditions and time scales, which integrated Ni adsorption on SOM with Ni-LDH precipitation in soils. The soil Ni speciation (adsorbed phases and Ni-LDH) calculated using the kinetics model was consistent with that obtained through XAS analysis during the sorption processes. Under our experimental conditions, both modeling and XAS results demonstrated that Ni adsorption on SOM was dominant in the short term and the formation of Ni-LDH precipitates accounted for the long-term Ni sequestration in soils, and, more interestingly, that the adsorbed Ni may slowly transfer to Ni-LDH phases with longer reaction times.

  1. Simulation of Ni-63 based nuclear micro battery using Monte Carlo modeling

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Tae Ho; Kim, Ji Hyun [Ulsan National Institute of Science and Technology, Ulsan (Korea, Republic of)

    2013-10-15

    The radioisotope batteries have an energy density of 100-10000 times greater than chemical batteries. Also, Li ion battery has the fundamental problems such as short life time and requires recharge system. In addition to these things, the existing batteries are hard to operate at internal human body, national defense arms or space environment. Since the development of semiconductor process and materials technology, the micro device is much more integrated. It is expected that, based on new semiconductor technology, the conversion device efficiency of betavoltaic battery will be highly increased. Furthermore, the radioactivity from the beta particle cannot penetrate a skin of human body, so it is safer than Li battery which has the probability to explosion. In the other words, the interest for radioisotope battery is increased because it can be applicable to an artificial internal organ power source without recharge and replacement, micro sensor applied to arctic and special environment, small size military equipment and space industry. However, there is not enough data for beta particle fluence from radioisotope source using nuclear battery. Beta particle fluence directly influences on battery efficiency and it is seriously affected by radioisotope source thickness because of self-absorption effect. Therefore, in this article, we present a basic design of Ni-63 nuclear battery and simulation data of beta particle fluence with various thickness of radioisotope source and design of battery.

  2. Triggering of El Niño by westerly wind events in a coupled general circulation model

    Science.gov (United States)

    Lengaigne, Matthieu; Guilyardi, Eric; Boulanger, Jean-Philippe; Menkes, Christophe; Delecluse, Pascale; Inness, Pete; Cole, Jeff; Slingo, Julia

    2004-11-01

    Two ten-members ensemble experiments using a coupled ocean-atmosphere general circulation model are performed to study the dynamical response to a strong westerly wind event (WWE) when the tropical Pacific has initial conditions favourable to the development of a warm event. In the reference ensemble (CREF), no wind perturbation is introduced, whereas a strong westerly wind event anomaly is introduced in boreal winter over the western Pacific in the perturbed ensemble (CWWE). Our results demonstrate that an intense WWE is capable of establishing the conditions under which a strong El Niño event can occur. First, it generates a strong downwelling Kelvin wave that generates a positive sea surface temperature (SST) anomaly in the central-eastern Pacific amplified through a coupled ocean-atmosphere interaction. This anomaly can be as large as 2.5°C 60 days after the WWE. Secondly, this WWE also initiates an eastward displacement of the warm-pool that promotes the occurrence of subsequent WWEs in the following months. These events reinforce the initial warming through the generation of additional Kelvin waves and generate intense surface jets at the eastern edge of the warm-pool that act to further shift warm waters eastward. The use of a ten-members ensemble however reveals substantial differences in the coupled response to a WWE. Whereas four members of CWWE ensemble develop into intense El Niño warming as described above, four others display a moderate warming and two remains in neutral conditions. This diversity between the members appears to be due to the internal atmospheric variability during and following the inserted WWE. In the four moderate warm cases, the warm-pool is initially shifted eastward following the inserted WWE, but the subsequent weak WWE activity (when compared to the strong warming cases) prevents to further shift the warm-pool eastwards. The seasonal strengthening of trade winds in June July can therefore act to shift warm waters back into

  3. 基于团簇和胶粘原子模型的(Fe-Ni)-B-Y-Nb块体非晶合金%(Fe-Ni)-B-Y-Nb Bulk Metallic Glasses Based on the Model of Clusters and Glue Atoms

    Institute of Scientific and Technical Information of China (English)

    陈伟荣; 韩光; 陈季香; 朱春雷; 王清; 王英敏; 董闯

    2011-01-01

    应用团簇+胶粘原子模型在三元Fe-B-Y合金系中设计三元合金成分,选择最密堆的CN10 Archimedes八面体反棱柱FesB作为基本团簇,Y为胶粘原子.在此基础上添加3at%Nb作为微合金化元素形成四元合金.以适量的Ni替换Fe,形成五元合金[(Fie100-xNix)B-Y]-Nb.结果表明,当Ni的含量小于30at%时,均可形成直径为2 mm的块体非晶合金,其中,合金[(FeNi)B-Y]-Nb 具有最大的Tg、Tx和Trg值,分别为:884K、972K和0.634.%Using the model of cluster + glue atom, the temary bulk metallic glasses (BMG) in Fe-B-Y system was designed, choosing the close-packed Archimedes octahedral antiprism CN-10 FeaB3 as basic cluster and Y as glue atom.3at%Nb was added as minor alloying element to form quatemary BMG Ni was used to substitute for Fe, and a quinary BMG [(Fe100-xNix)8B3-Y]97-Nb3, was formed.Results show that when Ni is less than 30at% the BMG with diameter of 2 mm can be obtained and the alloy [(Fe94Ni6)8B3-Y]97-Nb3 has the biggest Tg, Tx; and Trg which are 884 K, 972 K and 0.634, respectively.

  4. Thermodynamic reassessment of Gd–Ni system

    Energy Technology Data Exchange (ETDEWEB)

    Rahou, Z., E-mail: rahou.zakarea@gmail.com; Mahdouk, K.

    2015-11-05

    By means of CALPHAD (CALculation of PHAse Diagrams) approach, the phase diagram and thermodynamic data of the Gd–Ni system were critically assessed. The Gd–Ni system contains four solution phases (liquid, face-centered cubic FCC-A1, body-centered cubic BCC-A2 and hexagonal close-packed HCP-A3) modeled with the Redlich-Kister polynomials and seven intermetallic compounds Gd{sub 3}Ni, GdNi, GdNi{sub 2}, GdNi{sub 3}, Gd{sub 2}Ni{sub 7}, GdNi{sub 5} and Gd{sub 2}Ni{sub 17}, which are all treated as stoichiometric compounds. A set of self-consistent thermodynamic parameters describing various phases in this binary system was obtained. The phase diagram and thermodynamic quantities calculated from assessed parameters agree well with experimental data.

  5. Stochastic processes in climate modeling: from Lorenz to the El-Niño recharge oscillator and beyond

    Science.gov (United States)

    Ghil, M.; Chekroun, M. D.; Simonnet, E.

    2009-04-01

    In the past few years, much of the climate community's work has gone toward building highly detailed, IPCC-class general circulation models (GCMs) capable of simulating climate change. In this context, subgrid-scale physics has increasingly been modeled using stochastic processes, but the broader consequences of this approach have not yet been sufficiently explored. Stochastic subgrid-scale parametrizations have substantial non-local effects on the low-frequency dynamics itself. Moreover, due to the random forcing present in these parametrizations, traditional dynamical systems concepts — e.g., strange attractors and deterministic bifurcations — are no longer appropriate. In this talk, we present and apply mathematical concepts and tools developed by L. Arnold and his Bremen school during the last two decades. These tools have not been widely exploited so far in climate research, although they offer powerful theoretical and numerical ways of investigating stochastic models. More specifically, we use random dynamical systems (RDS) theory to analyze the stochastic dynamics of climate models. To illustrate our approach, we consider at first simple conceptual models. The first example is the well-known 3-variable Lorenz (1963) model, to which we add multiplicative noise. We show how to obtain a full description of the resulting stochastic dynamics by computing this model's random attractor and its associated invariant measure. The second example is Timmermann and Jin's (GRL, 2002) nonlinear recharge-discharge model of the El Niño/Southern Oscillation (ENSO), a model that captures several essential features of ENSO physics. A multiplicative noise term is added to this TJ model to represent wind bursts. Numerical simulations of the modified TJ model's random attractor show that Smale horseshoes are excited by the multiplicative noise, even for a parameter regime in which a Hopf bifurcation occurs in the deterministic system; such intricate structures only arise in

  6. Direct reforming of biogas on Ni-based SOFC anodes: Modelling of heterogeneous reactions and validation with experiments

    Science.gov (United States)

    Santarelli, Massimo; Quesito, Francesco; Novaresio, Valerio; Guerra, Cosimo; Lanzini, Andrea; Beretta, Davide

    2013-11-01

    This work focuses on the heterogeneous reactions taking place in a tubular anode-supported solid oxide fuel cell (SOFC) when the designated fuel is biogas from anaerobic digestion directly feeding the fuel cell. Operational maps of the fuel cell running on direct reforming of biogas were first obtained. Hence a mathematical model incorporating the kinetics of reforming reactions on Ni catalyst was used to predict the gas composition profile along the fuel channel. The model was validated against experimental data based on polarization curves. Also, the anode off-gas composition was collected and analyzed through a gas chromatograph. Finally, the model has been used to predict and analyze the gas composition change along the anode channel to evaluate effectiveness of the direct steam reforming when varying cell temperature, inlet fuel composition and the type of reforming process. The simulations results confirmed that thermodynamic-equilibrium conditions are not fully achieved inside the anode channel. It also outlines that a direct biogas utilization in an anode-supported SOFC is able to provide good performance and to ensure a good conversion of the methane even though when the cell temperature is far from the nominal value.

  7. Quantum model of a solid-state spin qubit: Ni cluster on a silicon surface by the generalized spin Hamiltonian and X-ray absorption spectroscopy investigations

    Science.gov (United States)

    Farberovich, Oleg V.; Mazalova, Victoria L.; Soldatov, Alexander V.

    2015-11-01

    We present here the quantum model of a Ni solid-state electron spin qubit on a silicon surface with the use of a density-functional scheme for the calculation of the exchange integrals in the non-collinear spin configurations in the generalized spin Hamiltonian (GSH) with the anisotropic exchange coupling parameters linking the nickel ions with a silicon substrate. In this model the interaction of a spin qubit with substrate is considered in GSH at the calculation of exchange integrals Jij of the nanosystem Ni7-Si in the one-electron approach taking into account chemical bonds of all Si-atoms of a substrate (environment) with atoms of the Ni7-cluster. The energy pattern was found from the effective GSH Hamiltonian acting in the restricted spin space of the Ni ions by the application of the irreducible tensor operators (ITO) technique. In this paper we offer the model of the quantum solid-state N-spin qubit based on the studying of the spin structure and the spin-dynamics simulations of the 3d-metal Ni clusters on the silicon surface. The solution of the problem of the entanglement between spin states in the N-spin systems is becoming more interesting when considering clusters or molecules with a spectral gap in their density of states. For quantifying the distribution of the entanglement between the individual spin eigenvalues (modes) in the spin structure of the N-spin system we use the density of entanglement (DOE). In this study we have developed and used the advanced high-precision numerical techniques to accurately assess the details of the decoherence process governing the dynamics of the N-spin qubits interacting with a silicon surface. We have studied the Rabi oscillations to evaluate the N-spin qubits system as a function of the time and the magnetic field. We have observed the stabilized Rabi oscillations and have stabilized the quantum dynamical qubit state and Rabi driving after a fixed time (0.327 μs). The comparison of the energy pattern with the

  8. Formation and evolution of MnNi clusters in neutron irradiated dilute Fe alloys modelled by a first principle-based AKMC method

    Energy Technology Data Exchange (ETDEWEB)

    Ngayam-Happy, R. [EDF-R and D, Departement Materiaux et Mecanique des Composants (MMC), Les Renardieres, F-77818 Moret sur Loing Cedex (France); Unite Materiaux et Transformations (UMET), UMR CNRS 8207, Universite de Lille 1, ENSCL, F-59655 Villeneuve d' Ascq Cedex (France); Laboratoire commun EDF-CNRS Etude et Modelisation des Microstructures pour le Vieillissement des Materiaux (EM2VM) (France); Becquart, C.S., E-mail: charlotte.becquart@univ-lille1.fr [Unite Materiaux et Transformations (UMET), UMR CNRS 8207, Universite de Lille 1, ENSCL, F-59655 Villeneuve d' Ascq Cedex (France); Laboratoire commun EDF-CNRS Etude et Modelisation des Microstructures pour le Vieillissement des Materiaux (EM2VM) (France); Domain, C. [EDF-R and D, Departement Materiaux et Mecanique des Composants (MMC), Les Renardieres, F-77818 Moret sur Loing Cedex (France); Unite Materiaux et Transformations (UMET), UMR CNRS 8207, Universite de Lille 1, ENSCL, F-59655 Villeneuve d' Ascq Cedex (France); Laboratoire commun EDF-CNRS Etude et Modelisation des Microstructures pour le Vieillissement des Materiaux (EM2VM) (France)

    2012-07-15

    An atomistic Monte Carlo model parameterised on electronic structure calculations data has been used to study the formation and evolution under irradiation of solute clusters in Fe-MnNi ternary and Fe-CuMnNi quaternary alloys. Two populations of solute rich clusters have been observed, which can be discriminated by whether or not the solute atoms are associated with self-interstitial clusters. Mn-Ni-rich clusters are observed at a very early stage of the irradiation in both modelled alloys, whereas the quaternary alloys contain also Cu-containing clusters. Mn-Ni-rich clusters nucleate very early via a self-interstitial-driven mechanism, earlier than Cu-rich clusters; the latter, however, which are likely to form via a vacancy-driven mechanism, grow in number much faster than the former, helped by the thermodynamic driving force to Cu precipitation in Fe, thereby becoming dominant in the low dose regime. The kinetics of the number density increase of the two populations is thus significantly different. Finally the main conclusion suggested by this work is that the so-called late blooming phases might as well be neither late, nor phases.

  9. Continuum mechanics simulations of NiO/Ni-YSZ composites during reduction and re-oxidation

    DEFF Research Database (Denmark)

    Pihlatie, Mikko; Frandsen, Henrik Lund; Kaiser, Andreas;

    2010-01-01

    for the dimensional change arises from the volumetric change related to the phase change NiO ↔ Ni. The measurable change in bulk length is given by the ceramic YSZ backbone as a response to the stress created by the chemical strain. The different subprocesses described in the model for YSZ were elastic and anelastic...... expansion, diffusional creep, grain boundary sliding (GBS) and microcracking due to excessive stress. In the Ni/NiO phase, nonelastic strains in terms of diffusional and power law creep were implemented, and additionally for NiO deformation due to microcracking and/or pseudoplasticity. Semi......-empirical correlations were employed for creep limiting grain growth of Ni and NiO, particle coarsening of Ni and particle growth in NiO during the oxidation. Seven experimental cases of high temperature redox dilatometry were simulated. The model shows good qualitative agreement with the measurements. The different...

  10. An in situ USAXS-SAXS-WAXS study of precipitate size distribution evolution in a model Ni-based alloy.

    Science.gov (United States)

    Andrews, Ross N; Serio, Joseph; Muralidharan, Govindarajan; Ilavsky, Jan

    2017-06-01

    Intermetallic γ' precipitates typically strengthen nickel-based superalloys. The shape, size and spatial distribution of strengthening precipitates critically influence alloy strength, while their temporal evolution characteristics determine the high-temperature alloy stability. Combined ultra-small-, small- and wide-angle X-ray scattering (USAXS-SAXS-WAXS) analysis can be used to evaluate the temporal evolution of an alloy's precipitate size distribution (PSD) and phase structure during in situ heat treatment. Analysis of PSDs from USAXS-SAXS data employs either least-squares fitting of a preordained PSD model or a maximum entropy (MaxEnt) approach, the latter avoiding a priori definition of a functional form of the PSD. However, strong low-q scattering from grain boundaries and/or structure factor effects inhibit MaxEnt analysis of typical alloys. This work describes the extension of Bayesian-MaxEnt analysis methods to data exhibiting structure factor effects and low-q power law slopes and demonstrates their use in an in situ study of precipitate size evolution during heat treatment of a model Ni-Al-Si alloy.

  11. The light curve in supernova modeled by a continuous radioactive decay of $^{56}$Ni

    CERN Document Server

    Zaninetti, L

    2014-01-01

    The UVOIR bolometric light curves are usually modeled by the radioactive decay. In order to model more precisely the absolute/apparent magnitude versus time relationship the continuous production of radioactive isotopes is introduced. A differential equation of the first order with separable variables is solved.

  12. Modelling the fine and coarse fraction of Pb, Cd, As and Ni air concentration in Spain

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, M. A.; Vivanco, M. G.

    2015-07-01

    Lead, cadmium, arsenic and nickel are present in the air due to natural and anthropogenic emissions, normally joined to particles. Human health and ecosystems can be damaged by high atmospheric levels of these metals, since they can be introduced in organisms via inhalation or ingestion. Small particles are inhaled and embebed in lungs and alveolus more easily than coarse particles. The CHIMERE model is a eulerian air quality model extensively used in air quality modelling. Metals have been recently included in this model in a special version developed in the CIEMAT modelling group (Madrid, Spain). Vivanco et al. (2011) and Gonzalez et al. (2012) showed an evaluation of the model performance for some metals in Spain and Europe. In these studies, metals were considered as fine particles. Nevertheless there is some observational evidence of the presence of some metals also in the coarse fraction. For this reason, a new attempt of modelling metals considering a fine (<2.5 μm) and coarse (2.5-10 μm) fraction has been done. Measurements of metal concentration in PM10, PM2.5 and PM1 recorded in Spain were used to obtain the new metal particle distribution size. On the other hand, natural emissions, not considered in the above mentioned studies, were implemented in the model, by considering metal emissions associated to dust resuspensiont. An evaluation of the new version is presented and discussed for two domains in Spain, centered on Barcelona and Huelva respectively. (Author)

  13. Modelling the fine and coarse fraction of Pb, Cd, As and Ni air concentration in Spain

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, M.A.; Vivanco, M.

    2015-07-01

    Lead, cadmium, arsenic and nickel are present in the air due to natural and anthropogenic emissions, normally joined to particles. Human health and ecosystems can be damaged by high atmospheric levels of these metals, since they can be introduced in organisms via inhalation or ingestion. Small particles are inhaled and embebed in lungs and alveolus more easily than coarse particles. The CHIMERE model is a eulerian air quality model extensively used in air quality modelling. Metals have been recently included in this model in a special version developed in the CIEMAT modelling group (Madrid, Spain). Vivanco et al. (2011) and González et al. (2012) showed an evaluation of the model performance for some metals in Spain and Europe. In these studies, metals were considered as fine particles. Nevertheless there is some observational evidence of the presence of some metals also in the coarse fraction. For this reason, a new attempt of modelling metals considering a fine (<2.5 μm) and coarse (2.5-10 μm) fraction has been done. Measurements of metal concentration in PM10, PM2.5 and PM1 recorded in Spain were used to obtain the new metal particle distribution size. On the other hand, natural emissions, not considered in the above mentioned studies, were implemented in the model, by considering metal emissions associated to dust resuspensiont. An evaluation of the new version is presented and discussed for two domains in Spain, centered on Barcelona and Huelva respectively. (Author)

  14. Insight From EXAFS and the Multi Site Complexation Model (MUSIC) Into the Discrepancy Between SCM-Predicted and Experimental pH-Dependent Ni Sorption to Hydrous Manganese Oxyhydroxide

    Science.gov (United States)

    Haack, E. A.; Smith, D. S.; Trainor, T. P.; Warren, L. A.

    2003-12-01

    Hydrous manganese oxyhydroxides (HMO) are receiving increasing attention from both geomicrobiologists, due to the importance of microbial catalysis in their formation, and trace element geochemists, due to their importance as trace metal sorbents in a wide number of environments. Accurate models of the mechanisms of trace metal sequestration in association with HMO are thus required for an overall understanding of metal reactive transport. We have examined the utility of a surface complexation model to describe pH-dependent Ni sorption to synthetic HMO, a layered oxide comparable in structure to microbially-catalyzed Mn oxide. Surface complexation models (SCM) have successfully reproduced metal and proton binding curves to a number of geochemically relevant solids, including bacteria and mineral surfaces. However, because these models are derived from potentiometric titrations, they have intrinsic limitations; very high and very low proton affinity sites cannot be characterized. Results from our study indicated that Ni sorption to HMO could not be described by assuming Ni sorption to the SCM-derived proton binding sites. Ni sorption capacity of the solid far exceeded proton binding capacity at low pH values. Examination of the Ni-sorbed HMO samples with EXAFS indicated that the discrepancy between Ni sorption and proton binding could not be ascribed to the precipitation of a separate Ni solid phase. Rather, all at pH values examined (2.0, 4.0 and 6.5) Ni sorbed above/below layer vacancies in the MnO6 octahedral layers of HMO, as interlayer tridentate corner-sharing complexes. At circumneutral pH (6.5), Ni also substituted directly for structural Mn. A theoretical pKa spectrum was derived for HMO using the multi site complexation model (MUSIC) and proton affinity constants for surface functional groups relevant for Ni sorption, as constrained by EXAFS, were identified. Ni sorption as an interlayer complex occurred at sites with very high proton affinity, thus

  15. The thermodynamic, electronic and magnetic properties of Ni2MnX (X=Ge, Sn, Sb) Heusler alloys: a quasi-hormonic Debye model and first principles study

    Science.gov (United States)

    Li, Jia; Zhang, Zhidong; Sun, Yubao; Zhang, Jian; Zhou, Guoxiang; Luo, Hongzhi; Liu, Guodong

    2013-01-01

    The thermodynamic, electronic and magnetic properties of Ni2MnX (X=Ge, Sn, Sb) Heusler alloys are investigated using the quasi-hormonic Debye model and the first principles calculation based on the density-functional-theory. The calculated results of the temperature dependent bulk modulus, coefficient of thermal expansion and the P-V relation for Ni2MnX (X=Ge, Sn, Sb) indicate that the bonding strength becomes stronger along the sequence of Ni2MnSb→Ni2MnSn→Ni2MnGe. The slower change trend of temperature dependent heat capacity of Ni2MnGe than that of Ni2MnSn and Ni2MnSb stems from the larger contribution of electronic heat capacity and smaller contribution of lattice heat capacity compared to the other two alloys. The ferromagnetic coupling order between the Ni and Mn is confirmed by our first principles calculations. The total moments in one primitive cell for the three alloys are all about 4.0 μB which are mainly carried by Mn atom with about 3.5 μB as can be seen from the magnetization density distribution.

  16. The thermodynamic, electronic and magnetic properties of Ni{sub 2}MnX (X=Ge, Sn, Sb) Heusler alloys: a quasi-hormonic Debye model and first principles study

    Energy Technology Data Exchange (ETDEWEB)

    Li Jia, E-mail: jiali@hebut.edu.cn [School of Science, Hebei University of Technology, Tianjin 300130 (China); Zhang Zhidong; Sun Yubao; Zhang Jian; Zhou Guoxiang [School of Science, Hebei University of Technology, Tianjin 300130 (China); Luo Hongzhi; Liu Guodong [School of Material Sciences and Engineering, Hebei University of Technology, Tianjin 300130 (China)

    2013-01-15

    The thermodynamic, electronic and magnetic properties of Ni{sub 2}MnX (X=Ge, Sn, Sb) Heusler alloys are investigated using the quasi-hormonic Debye model and the first principles calculation based on the density-functional-theory. The calculated results of the temperature dependent bulk modulus, coefficient of thermal expansion and the P-V relation for Ni{sub 2}MnX (X=Ge, Sn, Sb) indicate that the bonding strength becomes stronger along the sequence of Ni{sub 2}MnSb{yields}Ni{sub 2}MnSn{yields}Ni{sub 2}MnGe. The slower change trend of temperature dependent heat capacity of Ni{sub 2}MnGe than that of Ni{sub 2}MnSn and Ni{sub 2}MnSb stems from the larger contribution of electronic heat capacity and smaller contribution of lattice heat capacity compared to the other two alloys. The ferromagnetic coupling order between the Ni and Mn is confirmed by our first principles calculations. The total moments in one primitive cell for the three alloys are all about 4.0 {mu}{sub B} which are mainly carried by Mn atom with about 3.5 {mu}{sub B} as can be seen from the magnetization density distribution.

  17. Thermodynamic assessment of the Ni-Sb binary system

    Institute of Scientific and Technical Information of China (English)

    CAO Zhanmin; TAKADU Yoshikazu; OHNUMA Ikuo; KAINUMA Ryosuke; ZHU Hongmin; ISHIDA Kiyohito

    2008-01-01

    The Ni-Sb binary alloy system was thermodynamically assessed using CALPHAD approach in this article.Excess Gibbs energies of solution phases,liquid and fcc phases,were formulated using the Redlich-Kister expression.The intermediate phases were modeled by the sublattice model with (Ni,Va)0.5(Ni,Sb)0.25(Ni)0.25 for Ni3Sb_HT phase and (Ni,Va)0.3333(Sb)0.3333(Ni,Va)0.3333 for NiSb phase.The other phases including Ni3Sb,Ni7Sb3,and NiSb2 were treated as stoichiometric compound owing to their narrow composition ranges.Based on the reported thermodynamic properties and phase diagram data,the thermodynamic parameters of these phases were optimized,and the obtained values can reproduce the available experimental data well.

  18. Shear punch testing of {sup 59}Ni isotopically-doped model austenitic alloys after irradiation in FFTF at different He/dpa ratios

    Energy Technology Data Exchange (ETDEWEB)

    Hankin, G.L.; Faulkner, R.G. [Loughborough Univ., Leicestershire (United Kingdom). I.P.T.M.E.; Hamilton, M.L.; Garner, F.A. [Pacific Northwest National Lab., Richland, WA (United States)

    1998-03-01

    A series of three model alloys, Fe-15Cr-25Ni, Fe-15Cr-25Ni-0.04P and Fe-15Cr45Ni were irradiated side-by-side in FFTF-MOTA in both the annealed and the cold worked condition in each of two variants, one using naturally occurring isotopic mixtures, and another doped with {sup 59}Ni to generate relatively high helium-to-dpa ratios. Previous papers in this series have addressed the influence of helium on radiation-induced evolution of microstructure, dimensional stability and mechanical properties, the latter using miniature-tensile specimens. In the final paper of this experimental series, three sets of irradiations conducted at different temperatures and displacement rates were examined by shear punch testing of standard microscopy disks. The results were used to determine the influence of helium generation rate, alloy starting condition, irradiation temperature and total neutron exposure. The results were also compared with the miniature tensile data obtained earlier. In general, all alloys approached saturation levels of strength and ductility that were relatively independent of He/dpa ratio and starting condition, but were sensitive to the irradiation temperature and total exposure. Some small influence of helium/dpa ratio on the shear strength is visible in the two series that ran at {approximately}490 C, but is not evident at 365 C.

  19. Catalytic Steam Reforming of Toluene as a Model Compound of Biomass Gasification Tar Using Ni-CeO2/SBA-15 Catalysts

    Directory of Open Access Journals (Sweden)

    Erik Dahlquist

    2013-07-01

    Full Text Available Nickel supported on SBA-15 doped with CeO2 catalysts (Ni-CeO2/SBA-15 was prepared, and used for steam reforming of toluene which was selected as a model compound of biomass gasification tar. A fixed-bed lab-scale set was designed and employed to evaluate the catalytic performances of the Ni-CeO2/SBA-15 catalysts. Experiments were performed to reveal the effects of several factors on the toluene conversion and product gas composition, including the reaction temperature, steam/carbon (S/C ratio, and CeO2 loading content. Moreover, the catalysts were subjected to analysis of their carbon contents after the steam reforming experiments, as well as to test the catalytic stability over a long experimental period. The results indicated that the Ni-CeO2/SBA-15 catalysts exhibited promising capabilities on the toluene conversion, anti-coke deposition and catalytic stability. The toluene conversion reached as high as 98.9% at steam reforming temperature of 850 °C and S/C ratio of 3 using the Ni-CeO2(3wt%/SBA-15 catalyst. Negligible coke formation was detected on the used catalyst. The gaseous products mainly consisted of H2 and CO, together with a little CO2 and CH4.

  20. Modeling of power train by applying the virtual prototype concept; Kaso genkei ni yoru power train no model ka

    Energy Technology Data Exchange (ETDEWEB)

    Hiramatsu, S.; Harada, Y.; Arakawa, H.; Komori, S. [Mazda Motor Corp., Hiroshima (Japan); Sumida, S. [U-Shin Corp., Tokyo (Japan)

    1997-10-01

    This paper describes the simulation of power train that includes the model developed by applying the virtual prototype concept. By this concept, subsystem models which consist of functional model and mechanism models are integrated into a total system model. This peculiarity in architecture of model, which is called the hierarchical structure, enables us to model a system of large scale with many units, systems and parts easily. Two kinds of computer simulations are performed. One is engine revolution fluctuation by accessory load input, and the other is changing gears by automatic transmission. They are verified to have sufficient accuracy. 2 refs., 12 figs.

  1. Characterization of Hot Deformation Behavior of a Fe-Cr-Ni-Mo-N Superaustenitic Stainless Steel Using Dynamic Materials Modeling

    Science.gov (United States)

    Pu, Enxiang; Zheng, Wenjie; Song, Zhigang; Feng, Han; Zhu, Yuliang

    2017-02-01

    Hot deformation behavior of a Fe-24Cr-22Ni-7Mo-0.5N superaustenitic stainless steel was investigated by hot compression tests in a wide temperature range of 950-1250 °C and strain rate range of 0.001-10 s-1. The flow curves show that the flow stress decreases as the deformation temperature increases or the strain rate decreases. The processing maps developed on the basis of the dynamic materials model and flow stress data were adopted to optimize the parameters of hot working. It was found that the strain higher than 0.2 has no significant effect on the processing maps. The optimum processing conditions were in the temperature range of 1125-1220 °C and strain rate range of 0.1-3 s-1. Comparing to other stable domains, microstructural observations in this domain revealed the complete dynamic recrystallization (DRX) with finer and more uniform grain size. Flow instability occurred in the domain of temperature lower than 1100 °C and strain rate higher than 0.1 s-1.

  2. Multi-scale modelling of Suzuki segregation in γ′ precipitates in Ni and Co-base superalloys

    Directory of Open Access Journals (Sweden)

    Srimannarayana P.

    2014-01-01

    Full Text Available The high temperature strength of alloys with (γ + γ′ microstructure is primarily due to the resistance of the ordered precipitate to cutting by matrix dislocations. Such shearing requires higher stresses since it involves the creation of a planar fault. Planar fault energy is known to be dependent on composition. This implies that the composition on the fault may be different from that in the bulk for energetic reasons. Such segregation (or desegregation of specific alloying elements to the fault may result in Suzuki strengthening which has not been explored extensively in these systems. In this work, segregation (or desegregation of alloying elements to planar faults was studied computationally in Ni3(Al,Ti and Co3(W,Al type γ′ precipitates. The composition dependence of APB energy and heat of mixing were evaluated from first principle electronic structure calculations. A phase field model incorporating the first principles results, was used to simulate the motion of an extended superdislocation under stress concurrently with composition evolution. Results reveal that in both systems, significant (desegregation occurs on equilibration. On application of stress, solutes were dragged along with the APB in some cases. Additionally, it was also noted the velocity of the superdislocation under an applied stress is strongly dependent on atomic mobility (i.e. diffusivity.

  3. Dislocation-based plasticity model and micro-beam Laue diffraction analysis of polycrystalline Ni foil: A forward prediction

    Science.gov (United States)

    Song, Xu; Hofmann, Felix; Korsunsky, Alexander M.

    2010-10-01

    A physically-based, rate and length-scale dependent strain gradient crystal plasticity framework was employed to simulate the polycrystalline plastic deformation at the microscopic level in a large-grained, commercially pure Ni sample. The latter was characterised in terms of the grain morphology and orientation (in the bulk) by micro-beam Laue diffraction experiments carried out on beamline B16 at Diamond Light Source. The corresponding finite element model was developed using a grain-based mesh with the specific grain orientation assignment appropriate for the sample considered. Sample stretching to 2% plastic strain was simulated, and a post-processor was developed to extract the information about the local lattice misorientation (curvature), enabling forward-prediction of the Laue diffraction patterns. The 'streaking' phenomenon of the Laue spots (anisotropic broadening of two-dimensional (2D) diffraction peaks observed on the 2D detector) was correctly captured by the simulation, as constructed by direct superposition of reflections from different integration points within the diffraction gauge volume. Good agreement was found between the images collected from experiments and simulation patterns at various positions in the sample.

  4. Development of technology for organic wastewater treatment by microorganisms and production of materials for conserving environment. Part 1. ; Organic wastewater treatment by photoshynthetic bacteria and microalgae. Biseibutsu ni yoru yukikei haisui shori to yojo biseibutsu no shigenka ni kansuru kenkyu. 1. ; Kogosei saikin to sorui ni yoru haisui shori ni kansuru kihonteki kento

    Energy Technology Data Exchange (ETDEWEB)

    Kato, A.; Kita, D.; Kubotera, T.; Tsuji, H. (Obayashi Corp., Tokyo (Japan))

    1994-02-10

    The present report introduces a system which simultaneously executes the purification of organic wastewater and recovery of recyclable matters. The system uses photosynthetic bacteria and microalgae as well as the conventionally used activated sludge bacteria. Environmental maintenance use agents are produced by processing bacteria and algae generated during the wastewater treatment. The photosynthetic bacteria are purple non-sulfuric bacteria, which also contain amino acid, vitamin and other useful physiologically activated matter. The wastewater treatment which utilizes them has the advantage of miniaturizing the plant and lowering the power. As algae, chlorella and spirulina are used in order to remove the nitrogen and phosphorus in the water to be treated. The following is an actual result of wastewater treatment in a beancurd maker's plant: if purple non-sulfuric bacteria are used, high concentration organic wastewater can be treated without dilution so that the plant can be miniaturized. The chlorella culture is so effective that the nitrogen and phosphorus remaining in the wastewater are absorbed and removed by the chlorella with its increasing. 9 refs., 13 figs., 2 tabs.

  5. Enhanced collectivity in 74Ni

    CERN Document Server

    Aoi, N; Takeuchi, S; Suzuki, H; Bazin, D; Bowen, M D; Campbell, C M; Cook, J M; Dinca, D -C; Gade, A; Glasmacher, T; Iwasaki, H; Kubo, T; Kurita, K; Motobayashi, T; Mueller, W F; Nakamura, T; Sakurai, H; Takashina, M; Terry, J R; Yoneda, K; Zwahlen, H

    2010-01-01

    The neutron-rich nucleus 74Ni was studied with inverse-kinematics inelastic proton scattering using a 74Ni radioactive beam incident on a liquid hydrogen targetat a center-of-mass energy of 80 MeV. From the measured de-excitation gamma-rays, the population of the first 2+ state was quantified. The angle-integrated excitation cross section was determined to be 14(4) mb. A deformation length of delta = 1.04(16) fm was extracted in comparison with distorted wave theory, which suggests that the enhancement of collectivity established for 70Ni continues up to 74Ni. A comparison with results of shell model and quasi-particle random phase approximation calculations indicates that the magic character of Z = 28 or N = 50 is weakened in 74Ni.

  6. Enhanced collectivity in 74Ni

    Science.gov (United States)

    Aoi, N.; Kanno, S.; Takeuchi, S.; Suzuki, H.; Bazin, D.; Bowen, M. D.; Campbell, C. M.; Cook, J. M.; Dinca, D.-C.; Gade, A.; Glasmacher, T.; Iwasaki, H.; Kubo, T.; Kurita, K.; Motobayashi, T.; Mueller, W. F.; Nakamura, T.; Sakurai, H.; Takashina, M.; Terry, J. R.; Yoneda, K.; Zwahlen, H.

    2010-09-01

    The neutron-rich nucleus 74Ni was studied with inverse-kinematics inelastic proton scattering using a 74Ni radioactive beam incident on a liquid hydrogen target at a center-of-mass energy of 80 MeV. From the measured de-excitation γ rays, the population of the first 2+ state was quantified. The angle-integrated excitation cross section was determined to be 14(4) mb. A deformation length of δ=1.04(16) fm was extracted in comparison with distorted wave theory, which suggests that the enhancement of collectivity established for 70Ni continues up to 74Ni. A comparison with results of shell model and quasi-particle random phase approximation calculations indicates that the magic character of Z=28 or N=50 is weakened in 74Ni.

  7. A macroscopic multi-mechanism based constitutive model for the thermo-mechanical cyclic degeneration of shape memory effect of NiTi shape memory alloy

    Science.gov (United States)

    Yu, Chao; Kang, Guozheng; Kan, Qianhua

    2017-06-01

    A macroscopic based multi-mechanism constitutive model is constructed in the framework of irreversible thermodynamics to describe the degeneration of shape memory effect occurring in the thermo-mechanical cyclic deformation of NiTi shape memory alloys (SMAs). Three phases, austenite A, twinned martensite Mt and detwinned martensite Md, as well as the phase transitions occurring between each pair of phases (A→ M t, Mt→ A, A→ M d, Md→ A, and Mt→ M d) are considered in the proposed model. Meanwhile, two kinds of inelastic deformation mechanisms, martensite transformation-induced plasticity and reorientation-induced plasticity, are used to explain the degeneration of shape memory effects of NiTi SMAs. The evolution equations of internal variables are proposed by attributing the degeneration of shape memory effect to the interaction between the three phases ( A, Mt, and Md) and plastic deformation. Finally, the capability of the proposed model is verified by comparing the predictions with the experimental results of NiTi SMAs. It is shown that the degeneration of shape memory effect and its dependence on the loading level can be reasonably described by the proposed model.

  8. Characterisation of the Ni/ScYSZ interface in a model solid oxide fuel cell anode

    DEFF Research Database (Denmark)

    Schmidt, Michael Stenbæk; Hansen, Karin Vels; Norrman, Kion;

    2008-01-01

    A nickel point electrode setup was used as a model of an SOFC anode on three slightly different electrolytes of zirconia stabilised by co-doping with scandia and yttria. The effect of electrolyte impurities on the electrode polarisation resistance was investigated by correlating electrochemical i...

  9. Modeling Analysis of Bi-Layer Ni-(ZrO2x(Y2O31−x Anodes for Anode-Supported Intermediate Temperature-Solid Oxide Fuel Cells

    Directory of Open Access Journals (Sweden)

    Anna Enrico

    2014-08-01

    Full Text Available Intermediate temperature-solid oxide fuel cell (IT-SOFC Ni-(ZrO2x(Y2O31−x (Ni-YSZ anodes formed by two layers, with different thicknesses and morphologies, offer the possibility of obtaining adequate electrochemical performance coupled to satisfactory mechanical properties. We investigate bi-layered Ni-YSZ anodes from a modeling point of view. The model includes reaction kinetics (Butler-Volmer equation, mass transport (Dusty-Gas model, and charge transport (Ohm’s law, and allows to gain an insight into the distribution of the electrochemical reaction within the electrode. Additionally, the model allows to evaluate a reciprocal overall electrode resistance 1/Rp ≈ 6 S·cm−2 for a bi-layer electrode formed by a 10 µm thick active layer (AL composed of 0.25 µm radius Ni and YSZ particles (34% vol. Ni, coupled to a 700 µm thick support layer (SL formed by 0.5 µm radius Ni and YSZ particles (50% vol. Ni, and operated at a temperature of 1023 K. Simulation results compare satisfactorily to literature experimental data. The model allows to investigate, in detail, the effect of morphological and geometric parameters on the various sources of losses, which is the first step for an optimized electrode design.

  10. May common model biases reduce CMIP5's ability to simulate the recent Pacific La Niña-like cooling?

    Science.gov (United States)

    Li, Jianyong; Dodson, John; Yan, Hong; Wang, Weiming; Innes, James B.; Zong, Yongqiang; Zhang, Xiaojian; Xu, Qinghai; Ni, Jian; Lu, Fengyan

    2017-04-01

    Over the recent three decades sea surface temperate (SST) in the eastern equatorial Pacific has decreased, which helps reduce the rate of global warming. However, most CMIP5 model simulations with historical radiative forcing do not reproduce this Pacific La Niña-like cooling. Based on the assumption of "perfect" models, previous studies have suggested that errors in simulated internal climate variations and/or external radiative forcing may cause the discrepancy between the multi-model simulations and the observation. But the exact causes remain unclear. Recent studies have suggested that observed SST warming in the other two ocean basins in past decades and the thermostat mechanism in the Pacific in response to increased radiative forcing may also play an important role in driving this La Niña-like cooling. Here, we investigate an alternative hypothesis that common biases of current state-of-the-art climate models may deteriorate the models' ability and can also contribute to this multi-model simulations-observation discrepancy. Our results suggest that underestimated inter-basin warming contrast across the three tropical oceans, overestimated surface net heat flux and underestimated local SST-cloud negative feedback in the equatorial Pacific may favor an El Niño-like warming bias in the models. Effects of the three common model biases do not cancel one another and jointly explain 50% of the total variance of the discrepancies between the observation and individual models' ensemble mean simulations of the Pacific SST trend. Further efforts on reducing common model biases could help improve simulations of the externally forced climate trends and the multi-decadal climate fluctuations.

  11. Stochastic Estimation of Nuclear Level Density in the Nuclear Shell Model: An Application to Parity-Dependent Level Density in $^{58}$Ni

    CERN Document Server

    Shimizu, Noritaka; Futamura, Yasunori; Sakurai, Tetsuya; Mizusaki, Takahiro; Otsuka, Takaharu

    2016-01-01

    We introduce a novel method to obtain level densities in large-scale shell-model calculations. Our method is a stochastic estimation of eigenvalue count based on a shifted Krylov-subspace method, which enables us to obtain level densities of huge Hamiltonian matrices. This framework leads to a successful description of both low-lying spectroscopy and the experimentally observed equilibration of $J^\\pi=2^+$ and $2^-$ states in $^{58}$Ni in a unified manner.

  12. Stochastic estimation of nuclear level density in the nuclear shell model: An application to parity-dependent level density in 58Ni

    Directory of Open Access Journals (Sweden)

    Noritaka Shimizu

    2016-02-01

    Full Text Available We introduce a novel method to obtain level densities in large-scale shell-model calculations. Our method is a stochastic estimation of eigenvalue count based on a shifted Krylov-subspace method, which enables us to obtain level densities of huge Hamiltonian matrices. This framework leads to a successful description of both low-lying spectroscopy and the experimentally observed equilibration of Jπ=2+ and 2− states in 58Ni in a unified manner.

  13. Oxidative-reforming of model biogas over NiO/Al2O3 catalysts: The influence of the variation of support synthesis conditions

    Science.gov (United States)

    Asencios, Yvan J. O.; Elias, Kariny F. M.; Assaf, Elisabete M.

    2014-10-01

    In this study, nickel catalysts (20 wt%) supported on γ-Al2O3 were prepared by the impregnation method. The γ-Al2O3, was synthesized by precipitation of bayerite gel obtained from aluminum scrap. The synthetic conditions of the bayerite gel varied as follows: precipitation pH ranging from 6 to 7; ageing temperature ranging from 25 to 80 °C, the calcination temperature for all samples was 500 °C. The catalysts and the supports were analyzed by temperature programmed reduction (H2-TPR), X-ray diffraction (XRD), physisorption of N2 (BET), X-ray absorption near-edge structure (XANES) and scanning electron microscopy (SEM). Isopropanol decomposition reactions over the catalysts were carried out to evaluate their acidity. SEM images of the spent catalysts showed that the morphology of the carbon formed during the reaction is of the filamentous type. The TPR analysis of the catalysts showed the presence of NiO species weakly interacted with the support as well as stoichiometric and non-stoichiometric nickel aluminate, the reduction of these species was also observed by XANES analysis. XRD analysis of the fresh catalyst showed peaks assigned to NiO, NiAl2O4 and γ-Al2O3. The best catalysts (samples NiAl7-25 and NiAl7-80) synthesized in this report showed high stability and high conversion values (CH4 (70%) and CO2 (78%)). These catalysts showed better performance than the catalyst supported on commercial γ-Al2O3, which showed a high coke formation which affected the course of the reaction. The γ-Al2O3 synthesized from bayerite obtained at neutral pH conditions was the best support for nickel catalysts in the oxidative-reforming of model biogas.

  14. Oxidative-reforming of model biogas over NiO/Al{sub 2}O{sub 3} catalysts: The influence of the variation of support synthesis conditions

    Energy Technology Data Exchange (ETDEWEB)

    Asencios, Yvan J.O., E-mail: yvan.jesus@unifesp.br [Departamento de Ciências do Mar, Universidade Federal de São Paulo, Av. Alm. Saldanha da Gama, 89, Ponta da Praia, CEP: 11030-400, Santos-SP (Brazil); Elias, Kariny F.M. [Instituto de Química de São Carlos, Universidade de São Paulo, Av. Trabalhador Sãocarlense, 400, 13560-970, São Carlos-SP (Brazil); Assaf, Elisabete M., E-mail: eassaf@iqsc.usp.br [Instituto de Química de São Carlos, Universidade de São Paulo, Av. Trabalhador Sãocarlense, 400, 13560-970, São Carlos-SP (Brazil)

    2014-10-30

    Graphical abstract: - Highlights: • Precipitation pH and ageing T °C of Al{sub 2}O{sub 3} influenced the performance of Ni/Al{sub 2}O{sub 3}. • Ni catalysts supported on Al{sub 2}O{sub 3} obtained at pH 7 recorded high conversion values. • Catalysts supported on Al{sub 2}O{sub 3} obtained at pH 7 and 80 °C are promissory for reforming of biogas. • Catalysts supported on Al{sub 2}O{sub 3} obtained at pH 6 deactivated readily during reaction. - Abstract: In this study, nickel catalysts (20 wt%) supported on γ-Al{sub 2}O{sub 3} were prepared by the impregnation method. The γ-Al{sub 2}O{sub 3}, was synthesized by precipitation of bayerite gel obtained from aluminum scrap. The synthetic conditions of the bayerite gel varied as follows: precipitation pH ranging from 6 to 7; ageing temperature ranging from 25 to 80 °C, the calcination temperature for all samples was 500 °C. The catalysts and the supports were analyzed by temperature programmed reduction (H{sub 2}-TPR), X-ray diffraction (XRD), physisorption of N{sub 2} (BET), X-ray absorption near-edge structure (XANES) and scanning electron microscopy (SEM). Isopropanol decomposition reactions over the catalysts were carried out to evaluate their acidity. SEM images of the spent catalysts showed that the morphology of the carbon formed during the reaction is of the filamentous type. The TPR analysis of the catalysts showed the presence of NiO species weakly interacted with the support as well as stoichiometric and non-stoichiometric nickel aluminate, the reduction of these species was also observed by XANES analysis. XRD analysis of the fresh catalyst showed peaks assigned to NiO, NiAl{sub 2}O{sub 4} and γ-Al{sub 2}O{sub 3}. The best catalysts (samples NiAl7-25 and NiAl7-80) synthesized in this report showed high stability and high conversion values (CH{sub 4} (70%) and CO{sub 2} (78%)). These catalysts showed better performance than the catalyst supported on commercial γ-Al{sub 2}O{sub 3}, which showed a

  15. Incorporating bioavailability into toxicity assessment of Cu-Ni, Cu-Cd, and Ni-Cd mixtures with the extended biotic ligand model and the WHAM-F(tox) approach.

    Science.gov (United States)

    Qiu, Hao; Vijver, Martina G; He, Erkai; Liu, Yang; Wang, Peng; Xia, Bing; Smolders, Erik; Versieren, Liske; Peijnenburg, Willie J G M

    2015-12-01

    There are only a limited number of studies that have developed appropriate models which incorporate bioavailability to estimate mixture toxicity. Here, we explored the applicability of the extended biotic ligand model (BLM) and the WHAM-F(tox) approach for predicting and interpreting mixture toxicity, with the assumption that interactions between metal ions obey the BLM theory. Seedlings of lettuce Lactuca sativa were exposed to metal mixtures (Cu-Ni, Cu-Cd, and Ni-Cd) contained in hydroponic solutions for 4 days. Inhibition to root elongation was the endpoint used to quantify the toxic response. Assuming that metal ions compete with each other for binding at a single biotic ligand, the extended BLM succeeded in predicting toxicity of three mixtures to lettuce, with more than 82% of toxicity variation explained. There were no significant differences in the values of f(mix50) (i.e., the overall amounts of metal ions bound to the biotic ligand inducing 50% effect) for the three mixture combinations, showing the possibility of extrapolating these values to other binary metal combinations. The WHAM-F(tox) approach showed a similar level of precision in estimating mixture toxicity while requiring fewer parameters than the BLM-f(mix) model. External validation of the WHAM-F(tox) approach using literature data showed its applicability for other species and other mixtures. The WHAM-F(tox) model is suitable for delineating mixture effects where the extended BLM also applies. Therefore, in case of lower data availability, we recommend the lower parameterized WHAM-F(tox) as an effective approach to incorporate bioavailability in quantifying mixture toxicity.

  16. Indentation response of a NiTi shape memory alloy: modeling and experiments

    Directory of Open Access Journals (Sweden)

    C. Maletta

    2012-07-01

    Full Text Available The indentation response of a pseudoelastic nickel-titanium based shape memory alloy (SMA has been analyzed. Indentation tests have been carried out at room temperature using a spherical diamond tip and indentation loads in the range 50-500 mN in order to promote a large stress-induced transformation zone in the indentation region and, consequently, to avoid local effects due to microstructural variations. The measured load-displacement data have been analyzed to obtain information on the pseudoelastic response of the alloy. To aid this analysis numerical simulations were performed, by using a commercial finite element (FE software code and a special constitutive model for SMAs, so as to understand better the microstructural evolution occurring during the indentation process. Finally, the FE model has been used to analyze the effects of temperature on the indentation response of the alloy. This analysis revealed a marked variation of both the maximum and residual penetration depths with increasing test temperature.

  17. Microscopic phase field study of the antisite defect of Ni3 Al in binary Ni-Al alloys

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    The temporal evolution feature of a microscopic phase field model is utilized to study the antisite defects of L1 2-Ni 3 Al;this is quite different from other physicist’ interests.There are mainly two points in brief.Firstly,antisite defects Ni Al and Al Ni ,which are caused by the deviation from the stoichiometric Ni 3 Al,coexist in the Ni 3 Al phase.The surplus Ni atom in the Ni-rich side is prone to substitute Al thus producing the antisite defect Ni Al that maintains the stability of the L1 2 structure.In other case,the surplus Al atom in the Al-rich side is accommodated by a Ni sublattice consequently giving rise to antisite defect Al Ni .The calculated equilibrium occupancy probability of Ni Al is much higher than that of Al Ni .This point is generally in line with other theoretical and experimental works.Additionally,both Ni Al and Al Ni have a strong negative correlation to time step during the disorder-order transformation.Since the initial value of Ni Al and Al Ni on each site of the matrix is right at the concentration that we set,we can observe the decrease process of Ni Al and Al Ni from the initial disordered high anti-structure state to their respective equilibrium state,i.e.to the result of the ordering process further coarsening.

  18. A Reliability Model for Ni-BaTiO3-Based (BME) Ceramic Capacitors

    Science.gov (United States)

    Liu, Donhang

    2014-01-01

    The evaluation of multilayer ceramic capacitors (MLCCs) with base-metal electrodes (BMEs) for potential NASA space project applications requires an in-depth understanding of their reliability. The reliability of an MLCC is defined as the ability of the dielectric material to retain its insulating properties under stated environmental and operational conditions for a specified period of time t. In this presentation, a general mathematic expression of a reliability model for a BME MLCC is developed and discussed. The reliability model consists of three parts: (1) a statistical distribution that describes the individual variation of properties in a test group of samples (Weibull, log normal, normal, etc.), (2) an acceleration function that describes how a capacitors reliability responds to external stresses such as applied voltage and temperature (All units in the test group should follow the same acceleration function if they share the same failure mode, independent of individual units), and (3) the effect and contribution of the structural and constructional characteristics of a multilayer capacitor device, such as the number of dielectric layers N, dielectric thickness d, average grain size r, and capacitor chip size S. In general, a two-parameter Weibull statistical distribution model is used in the description of a BME capacitors reliability as a function of time. The acceleration function that relates a capacitors reliability to external stresses is dependent on the failure mode. Two failure modes have been identified in BME MLCCs: catastrophic and slow degradation. A catastrophic failure is characterized by a time-accelerating increase in leakage current that is mainly due to existing processing defects (voids, cracks, delamination, etc.), or the extrinsic defects. A slow degradation failure is characterized by a near-linear increase in leakage current against the stress time; this is caused by the electromigration of oxygen vacancies (intrinsic defects). The

  19. Lightning arrester models enabling highly accurate lightning surge analysis; Koseidona kaminari surge kaiseki wo kano ni suru hiraiki model

    Energy Technology Data Exchange (ETDEWEB)

    Ueda, T. [Chubu Electric Power Co. Inc., Nagoya (Japan); Funabashi, T.; Hagiwara, T.; Watanabe, H. [Meidensha Corp., Tokyo (Japan)

    1998-12-28

    Introduced herein are a dynamic behavior model for lightning arresters designed for power stations and substations and a flashover model for a lightning arresting device designed for transmission, both developed by the author et al. The author et al base their zinc oxide type lightning arrester model on the conventional static V-I characteristics, and supplement them with difference in voltage between static and dynamic characteristics. The model is easily simulated using EMTP (Electromagnetic Transients Program) etc. There is good agreement between the results of calculation performed using this model and actually measured values. Lightning arresting devices for transmission have come into practical use, and their effectiveness is introduced on various occasions. For the proper application of such devices, an analysis model capable of faithfully describing the flashover characteristics of arcing horns installed in great numbers along transmission lines, and of lightning arresting devices for transmission, are required. The author et al have newly developed a flashover model for the devices and uses the model for the analysis of lightning surges. It is found that the actually measured values of discharge characteristics of lightning arresting devices for transmission agree well with the values calculated by use of the model. (NEDO)

  20. A comparative study on improved Arrhenius-type and artificial neural network models to predict high-temperature flow behaviors in 20MnNiMo alloy.

    Science.gov (United States)

    Quan, Guo-zheng; Yu, Chun-tang; Liu, Ying-ying; Xia, Yu-feng

    2014-01-01

    The stress-strain data of 20MnNiMo alloy were collected from a series of hot compressions on Gleeble-1500 thermal-mechanical simulator in the temperature range of 1173 ∼ 1473 K and strain rate range of 0.01 ∼ 10 s(-1). Based on the experimental data, the improved Arrhenius-type constitutive model and the artificial neural network (ANN) model were established to predict the high temperature flow stress of as-cast 20MnNiMo alloy. The accuracy and reliability of the improved Arrhenius-type model and the trained ANN model were further evaluated in terms of the correlation coefficient (R), the average absolute relative error (AARE), and the relative error (η). For the former, R and AARE were found to be 0.9954 and 5.26%, respectively, while, for the latter, 0.9997 and 1.02%, respectively. The relative errors (η) of the improved Arrhenius-type model and the ANN model were, respectively, in the range of -39.99% ∼ 35.05% and -3.77% ∼ 16.74%. As for the former, only 16.3% of the test data set possesses η-values within ± 1%, while, as for the latter, more than 79% possesses. The results indicate that the ANN model presents a higher predictable ability than the improved Arrhenius-type constitutive model.

  1. A new theoretical model for high power laser clad TiC/NiCrBSiC composite coatings on Ti6Al4V alloys

    Science.gov (United States)

    Lei, Yiwen; Sun, Ronglu; Lei, Jianbo; Tang, Ying; Niu, Wei

    2010-09-01

    A new three-dimensional model was proposed to simulate the high power laser clad TiC/NiCrBSiC composite coatings on Ti6Al4V alloys using commercial finite element analysis software. Powders of TiC, NiCrBSiC alloy and cuboid of Ti6Al4V alloys were taken as sample materials. The dilution rate, the melt pool, and the heat affected zone (HAZ) of the substrate under different incident laser power were obtained from the calculation and compared with the microstructure of the coatings. The simulated results show that a good quality laser clad TiC/NiCrBSiC composite coating with low dilution rate and excellent metallurgical bond can be prepared under the processing parameters as follows: scanning velocity 5 mm/s, laser beam diameter 4.5 mm and incident laser power 2500 W. There exhibits an excellent agreement between the simulated results and experimental data. It indicates that the new model is helpful to optimize the processing parameters to form a good quality coating.

  2. Laser spectroscopy of jet-cooled NiF: Application of Hougen's approximate model for the low-lying electronic states

    Science.gov (United States)

    Arsenault, D. L.; Tokaryk, D. W.; Adam, A. G.; Linton, C.

    2016-06-01

    We have taken laser-induced fluorescence spectra of jet-cooled nickel monofluoride formed in a laser-ablation molecular beam source. Dispersed-fluorescence spectroscopy confirms predictions by Hougen (2011) that the parity assignments of levels in the Ω = 1 / 2 state 1570 cm-1 above the ground state should be reversed from those given in Krouti et al. (2002). The quality of the high-resolution spectra was sufficient to measure the [22.9]1.5-X1.5 band for five isotopologues of nickel and the [22.9]1.5-[0.25]0.5 band for molecules containing 58Ni and 60Ni. The spectral line positions for each isotopologue were fit to the Hamiltonian model given by Hougen, which was extended to allow for calculation of the parity-splitting parameter in the ground state.

  3. NI-1: a novel canine mastocytoma model for studying drug resistance and IgER-dependent mast cell activation

    Science.gov (United States)

    Hadzijusufovic, E; Peter, B; Herrmann, H; Rülicke, T; Cerny-Reiterer, S; Schuch, K; Kenner, L; Thaiwong, T; Yuzbasiyan-Gurkan, V; Pickl, W F; Willmann, M; Valent, P

    2012-01-01

    Background Advanced mast cell (MC) disorders are characterized by uncontrolled growth of neoplastic MC in various organs, mediator-related symptoms, and a poor prognosis. Kit mutations supposedly contribute to abnormal growth and drug resistance in these patients. Methods We established a novel canine mastocytoma cell line, NI-1, from a patient suffering from MC leukemia. Results NI-1 cells were found to form mastocytoma lesions in NOD/SCID IL-2Rgammanull mice and to harbor several homozygous Kit mutations, including missense mutations at nucleotides 107(C→T) and 1187(A→G), a 12-bp duplication (nucleotide 1263), and a 12-bp deletion (nucleotide 1550). NI-1 cells expressed several MC differentiation antigens, including tryptase, Kit, and a functional IgE receptor. Compared to the C2 mastocytoma cell line harboring a Kit exon 11 mutation, NI-1 cells were found to be less responsive against the Kit tyrosine kinase inhibitors (TKI) masitinib and imatinib, but were even more sensitive against proliferation-inhibitory effects of the mammalian target of rapamycin (mTOR) blocker RAD001 and PI3-kinase/mTOR blocker NVP-BEZ235. The Kit-targeting multikinase inhibitors PKC412 and dasatinib were also found to override TKI resistance in NI-1 cells, and produced growth inhibition with reasonable IC50 values (<0.1 μM). Conclusion NI-1 may serve as a useful tool to investigate IgE-dependent reactions and mechanisms of abnormal growth and drug resistance in neoplastic MC in advanced mastocytosis. PMID:22583069

  4. Experimental studies of Cs, Sr, Ni, and Eu sorption on Na-illite and the modelling of Cs sorption

    Energy Technology Data Exchange (ETDEWEB)

    Poinssot, C.; Baeyens, B.; Bradbury, M.H.

    1999-08-01

    A natural illite (illite du Puy) was purified and converted to the homo-ionic Na-form. The conditioned Na-illite was characterised in terms of its mineralogy, chemical inventory and physico-chemical properties. The structural formula was determined from energy dispersive spectroscopic analyses (SEM/TEM-EDS) and bulk chemistry measurements. A cation exchange capacity of 127 meq kg{sup -1} was determined by the {sup 22}Na isotope dilution method at neutral pH. The Na-CEC was also measured as a function of pH. The stability of Na-illite as a function of pH in the range between 3 and 6 was investigated. At low pH values partial dissolution of the illite occurs releasing the structural elements Al, Si, Mg, and K into solution. The presence of Ca and Sr in solution was interpreted as being due to desorption from cation exchange sites. All of these elements are also present at neutral pH but at considerably lower levels. Such effects cannot be avoided and must be considered in the interpretation of the sorption measurements. The main focus of the experimental work presented here is on the sorption behaviour of Cs, Sr, Ni and Eu on conditioned Na-illite as a function of NaClO{sub 4} background electrolyte concentration (0.1 and 0.01 M), nuclide concentration and pH in the range between 3 and 11. Sorption edge data (R{sub d} versus pH) and sorption isotherms (quantity of nuclide sorbed versus equilibrium nuclide concentration) are presented for these four elements. Prior to beginning these experiments, sorption kinetics were measured. The broad based pool of sorption measurements generated from this work will provide the source data sets for subsequent modelling. So far only the Cs sorption measurements have been modelled. A two site cation exchange model was developed to describe the sorption of Cs over the whole range of experimental conditions. The two site types were termed 'frayed edge sites' (FES, high affinity/low capacity) and 'type II sites

  5. Evaluation of bio-energy potential using world energy models; Sekai energy model ni yoru bio energy no potential hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Fujino, J.; Yamaji, K. [The University of Tokyo, Tokyo (Japan); Yamamoto, H. [Central Research Institute of Electric Power Industry, Tokyo (Japan)

    1997-01-30

    Bio-energy potential is evaluated using world energy models. The world energy model is a dynamic model by which the total cost of energy systems between 1995 and 2055 can be minimized on the basis of the optimization type world energy demand and supply model. For the given utilization costs of transportation, recovery and planting, the utilization of bio-energy is promoted even under the cost minimization condition. However, the utilization amount varies in a wide range by changing the utilization costs. Among conversion technologies of bio-energy, it is biomass liquefaction that provides the largest utilization amount. Thermal demand, direct combustion for power generation, and biomass gasification follow to the above. Biomass-integrated gasifier/gas turbine (BIG/GT) is to be used up to 2020. It is not to be used after 2030, due to the complete shift to the biomass liquefaction. For a model including the utilization of fast breeder after 2030, the utilization amount of bio-energy is not to change. Competition with food and land utilization is to be investigated. 11 refs., 19 figs., 4 tabs.

  6. Evaluation of bio-energy potential using world energy models; Sekai energy model ni yoru bio energy no potential hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Fujino, J.; Yamaji, K. [The University of Tokyo, Tokyo (Japan); Yamamoto, H. [Central Research Institute of Electric Power Industry, Tokyo (Japan)

    1997-01-30

    Bio-energy potential is evaluated using world energy models. The world energy model is a dynamic model by which the total cost of energy systems between 1995 and 2055 can be minimized on the basis of the optimization type world energy demand and supply model. For the given utilization costs of transportation, recovery and planting, the utilization of bio-energy is promoted even under the cost minimization condition. However, the utilization amount varies in a wide range by changing the utilization costs. Among conversion technologies of bio-energy, it is biomass liquefaction that provides the largest utilization amount. Thermal demand, direct combustion for power generation, and biomass gasification follow to the above. Biomass-integrated gasifier/gas turbine (BIG/GT) is to be used up to 2020. It is not to be used after 2030, due to the complete shift to the biomass liquefaction. For a model including the utilization of fast breeder after 2030, the utilization amount of bio-energy is not to change. Competition with food and land utilization is to be investigated. 11 refs., 19 figs., 4 tabs.

  7. Three dimensional reflection velocity analysis based on velocity model scan; Model scan ni yoru sanjigen hanshaha sokudo kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Minegishi, M.; Tsuru, T. [Japan National Oil Corp., Tokyo (Japan); Matsuoka, T. [Japan Petroleum Exploration Corp., Tokyo (Japan)

    1996-05-01

    Introduced herein is a reflection wave velocity analysis method using model scanning as a method for velocity estimation across a section, the estimation being useful in the construction of a velocity structure model in seismic exploration. In this method, a stripping type analysis is carried out, wherein optimum structure parameters are determined for reflection waves one after the other beginning with those from shallower parts. During this process, the velocity structures previously determined for the shallower parts are fixed and only the lowest of the layers undergoing analysis at the time is subjected to model scanning. To consider the bending of ray paths at each velocity boundaries involving shallower parts, the ray path tracing method is utilized for the calculation of the reflection travel time curve for the reflection surface being analyzed. Out of the reflection wave travel time curves calculated using various velocity structure models, one that suits best the actual reflection travel time is detected. The degree of matching between the calculated result and actual result is measured by use of data semblance in a time window provided centering about the calculated reflective wave travel time. The structure parameter is estimated on the basis of conditions for the maximum semblance. 1 ref., 4 figs.

  8. Study of the interfacial magnetism in NiO/NiFe system

    Energy Technology Data Exchange (ETDEWEB)

    Tafur, Miguel, E-mail: umiguelt@cbpf.b [Centro Brasileiro de Pesquisas Fisicas, Rua Dr. Xavier Sigaud 150 - Urca - Rio de Janeiro - 22290-180 RJ (Brazil); Alayo, W. [Centro Brasileiro de Pesquisas Fisicas, Rua Dr. Xavier Sigaud 150 - Urca - Rio de Janeiro - 22290-180 RJ (Brazil); Nascimento, V.P. [Universidade Federal do Espirito Santo, Centro Universitario Norte do Espirito Santo, Rua Humberto de Almeida Francklin 257 - Bairro Universitario, Sao Mateus - 29933-415 ES (Brazil); Xing, Y.T.; Baggio-Saitovitch, E. [Centro Brasileiro de Pesquisas Fisicas, Rua Dr. Xavier Sigaud 150 - Urca - Rio de Janeiro - 22290-180 RJ (Brazil)

    2010-05-31

    The interfacial magnetism of NiO/NiFe bilayers with different NiFe layer thicknesses, produced by DC and RF magnetron sputtering, has been studied by magnetometry and X-ray magnetic circular dichroism (XMCD). In magnetic hysteresis loops, the exchange bias field was found to be inversely proportional to the NiFe layer thickness. The fit using the Meiklejohn and Bean model gives a coupling energy at the NiO/NiFe interface of approximately 0.027 mJ/m{sup 2}. The analysis of the XMCD spectra of Fe and Ni, using the sum rules, shows a reduction of the effective spin magnetic moments in bilayers with NiFe thickness less than 4 nm. This reduction is attributed to hybridization of ferromagnetic and antiferromagnetic atoms d orbitals near the interface and/or formation of antiferromagnetic alloys due to atomic diffusion at the interfaces.

  9. Quantum model of a solid-state spin qubit: Ni cluster on a silicon surface by the generalized spin Hamiltonian and X-ray absorption spectroscopy investigations

    Energy Technology Data Exchange (ETDEWEB)

    Farberovich, Oleg V. [School of Physics and Astronomy, Beverly and Raymond Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv 69978 (Israel); Research Center for Nanoscale Structure of Matter, Southern Federal University, Zorge 5, 344090 Rostov-on-Don (Russian Federation); Voronezh State University, Voronezh 394000 (Russian Federation); Mazalova, Victoria L., E-mail: mazalova@sfedu.ru [Research Center for Nanoscale Structure of Matter, Southern Federal University, Zorge 5, 344090 Rostov-on-Don (Russian Federation); Soldatov, Alexander V. [Research Center for Nanoscale Structure of Matter, Southern Federal University, Zorge 5, 344090 Rostov-on-Don (Russian Federation)

    2015-11-15

    We present here the quantum model of a Ni solid-state electron spin qubit on a silicon surface with the use of a density-functional scheme for the calculation of the exchange integrals in the non-collinear spin configurations in the generalized spin Hamiltonian (GSH) with the anisotropic exchange coupling parameters linking the nickel ions with a silicon substrate. In this model the interaction of a spin qubit with substrate is considered in GSH at the calculation of exchange integrals J{sub ij} of the nanosystem Ni{sub 7}–Si in the one-electron approach taking into account chemical bonds of all Si-atoms of a substrate (environment) with atoms of the Ni{sub 7}-cluster. The energy pattern was found from the effective GSH Hamiltonian acting in the restricted spin space of the Ni ions by the application of the irreducible tensor operators (ITO) technique. In this paper we offer the model of the quantum solid-state N-spin qubit based on the studying of the spin structure and the spin-dynamics simulations of the 3d-metal Ni clusters on the silicon surface. The solution of the problem of the entanglement between spin states in the N-spin systems is becoming more interesting when considering clusters or molecules with a spectral gap in their density of states. For quantifying the distribution of the entanglement between the individual spin eigenvalues (modes) in the spin structure of the N-spin system we use the density of entanglement (DOE). In this study we have developed and used the advanced high-precision numerical techniques to accurately assess the details of the decoherence process governing the dynamics of the N-spin qubits interacting with a silicon surface. We have studied the Rabi oscillations to evaluate the N-spin qubits system as a function of the time and the magnetic field. We have observed the stabilized Rabi oscillations and have stabilized the quantum dynamical qubit state and Rabi driving after a fixed time (0.327 μs). The comparison of the energy

  10. Quantum-mechanical calculation of H on Ni(001) using a model potential based on first-principles calculations

    DEFF Research Database (Denmark)

    Mattsson, T.R.; Wahnström, G.; Bengtsson, L.

    1997-01-01

    First-principles density-functional calculations of hydrogen adsorption on the Ni (001) surface have been performed in order to get a better understanding of adsorption and diffusion of hydrogen on metal surfaces. We find good agreement with experiments for the adsorption energy, binding distance...

  11. The influence of tungsten on the chemical composition of a temporally evolving nanostructure of a model Ni-Al-Cr superalloy.

    Science.gov (United States)

    Sudbrack, Chantal K; Isheim, Dieter; Noebe, Ronald D; Jacobson, Nathan S; Seidman, David N

    2004-06-01

    The influence of W on the temporal evolution of gamma' precipitation toward equilibrium in a model Ni-Al-Cr alloy is investigated by three-dimensional atom-probe (3DAP) microscopy and transmission electron microscopy (TEM). We report on the alloys Ni-10 Al-8.5 Cr (at.%) and Ni-10 Al-8.5 Cr-2 W (at.%), which were aged isothermally in the gamma + gamma' two-phase field at 1073 K, for times ranging from 0.25 to 264 h. Spheroidal-shaped gamma' precipitates, 5-15 nm diameter, form during quenching from above the solvus temperature in both alloys at a high number density (approximately 1023 m-3). As gamma' precipitates grow with aging at 1073 K, a transition from spheroidal- to cuboidal-shaped precipitates is observed in both alloys. The elemental partitioning and spatially resolved concentration profiles across the gamma' precipitates are obtained as a function of aging time from three-dimensional atom-by-atom reconstructions. Proximity histogram concentration profiles (Hellman et al., 2000) of the quaternary alloy demonstrate that W concentration gradients exist in gamma' precipitates in the as-quenched and 0.25-h aging states, which disappear after 1 h of aging. The diffusion coefficient of W in gamma' is estimated to be 6.2 x 10-20 m2 s-1 at 1073 K. The W addition decreases the coarsening rate constant, and leads to stronger partitioning of Al to gamma' and Cr to gamma.

  12. The Influence of Tungsten on the Chemical Composition of a Temporally Evolving Nanostructure of a Model Ni-Al-Cr Superalloy

    Science.gov (United States)

    Sudbrack, Chantal K.; Isheim, Dieter; Noebe, Ronald D.; Jacobson, Nathan S.; Seidman, David N.

    2004-01-01

    The influence of W on the temporal evolution of gamma' precipitation toward equilibrium in a model Ni-Al-Cr alloy is investigated by three-dimensional atom-probe (3DAP) microscopy and transmission electron microscopy (TEM). We report on the alloys Ni-10 Al-8.5 Cr (at.%) and Ni-10 Al-8.5 Cr-2 W (at.%), which were aged isothermally in the gamma + gamma' two-phase field at 1073 K, for times ranging from 0.25 to 264 h. Spheroidal-shaped gamma' precipitates, 5-15 nm diameter, form during quenching from above the solvus temperature in both alloys at a high number density (approx. 10(exp 23/cu m). As gamma' precipitates grow with aging at 1073 K, a transition from spheriodal- to cuboidal-shaped precipitates is observed in both alloys. The elemental partitioning and spatially resolved concentration profiles across the gamma' precipitates are obtained as a function of aging time from three-dimensional atom-by-atom reconstructions. Proximity histogram concentration profiles of the quaternary alloy demonstrate that W concentration gradients exist in gamma' precipitates in the as-quenched and 0.25-h aging states, which disappear after 1 h of aging. The diffusion coefficient of W in gamma' is estimated to be 6.2 x 10(exp -20) sq m/s at 1073 K. The W addition decreases the coarsening rate constant, and leads to stronger partitioning of Al to gamma' and Cr to gamma.

  13. The Influence of Tungsten on the Chemical Composition of a Temporally Evolving Nanostructure of a Model Ni-Al-Cr Superalloy

    Science.gov (United States)

    Sudbrack, Chantal K.; Isheim, Dieter; Noebe, Ronald D.; Jacobson, Nathan S.; Seidman, David N.

    2004-01-01

    The influence of W on the temporal evolution of gamma' precipitation toward equilibrium in a model Ni-Al-Cr alloy is investigated by three-dimensional atom-probe (3DAP) microscopy and transmission electron microscopy (TEM). We report on the alloys Ni-10 Al-8.5 Cr (at.%) and Ni-10 Al-8.5 Cr-2 W (at.%), which were aged isothermally in the gamma + gamma' two-phase field at 1073 K, for times ranging from 0.25 to 264 h. Spheroidal-shaped gamma' precipitates, 5-15 nm diameter, form during quenching from above the solvus temperature in both alloys at a high number density (approx. 10(exp 23/cu m). As gamma' precipitates grow with aging at 1073 K, a transition from spheriodal- to cuboidal-shaped precipitates is observed in both alloys. The elemental partitioning and spatially resolved concentration profiles across the gamma' precipitates are obtained as a function of aging time from three-dimensional atom-by-atom reconstructions. Proximity histogram concentration profiles of the quaternary alloy demonstrate that W concentration gradients exist in gamma' precipitates in the as-quenched and 0.25-h aging states, which disappear after 1 h of aging. The diffusion coefficient of W in gamma' is estimated to be 6.2 x 10(exp -20) sq m/s at 1073 K. The W addition decreases the coarsening rate constant, and leads to stronger partitioning of Al to gamma' and Cr to gamma.

  14. Deep sedimentary structure model beneath the Osaka plain; Osaka heiya ni okeru shinbu chika kozo no model ka

    Energy Technology Data Exchange (ETDEWEB)

    Miyakoshi, K.; Kagawa, T.; Echigo, T. [Osaka Soil Test, Osaka (Japan)

    1997-05-27

    Restructuring was carried out on a sedimentary basin structure model of the Osaka plain including Osaka Bay by using newly obtained underground structural data. After the Hygoken-nanbu Earthquake of 1995, a large number of underground structure investigations have been performed in Osaka Bay and urban areas of Kobe and Osaka. However, very few surveys have been done in areas peripheral to Osaka Prefecture, such as the Ikoma area. Therefore, an attempt has been made to increase the number of measuring points to acquire underground structural data of these areas. Estimation of basic rock depths has utilized the dominant cycles in H/V spectra obtained from micro vibration survey, and good correlation of the base rock depths derived by a refraction exploration and a deep-bed boring investigation. With regard to bed division and P- and S- wave velocities in sedimentary beds in the Osaka sedimentary basin, an underground structure model was prepared, which was divided into four beds according to the refraction exploration and the micro vibration investigation. Data obtained by using this model agreed well with depth data acquired from physical exploration and other types of investigations. However, no good agreement was recognized in the data for such areas where the basic depth changes abruptly as the Rokko fault and the Osaka bay fault. 6 refs., 8 figs., 2 tabs.

  15. Model-supported interpretation of the electrochemical characteristics of solid oxide fuel cells with Ni/YSZ cermet anodes; Modellgestuetzte Interpretation der elektrochemischen Charakteristik von Festoxid-Brennstoffzellen mit Ni/YSZ-Cermetanoden

    Energy Technology Data Exchange (ETDEWEB)

    Gewies, Stefan

    2009-01-29

    This work presents the development, validation and application of a multiscale model for the detailed description of a solid oxide fuel cell (SOFC) with a Ni/YSZ (nickel/yttria-stabilized zirconia) cermet anode. The aim of the study is the identification of the physico-chemical loss processes, as seen in impedance spectra and polarization curves. The model consists of an elementary kinetic description of the electrochemistry including the development of an electrical double layer at the electrode/electrolyte interface of the cermet anode, a homogenized description of charge and gas-phase transport in the electrodes as well as a macroscopic description of convective and diffusive mass transport in the gas phase above the electrodes. For the rst time this study allows for a complete description of the impedance spectra of a diffusively fuel-supplied cermet anode. By comparing simulations with experiments on symmetrical cells (University of Karlsruhe) three dominant loss processes could be identified. The model was extended to account for the description of segmented SOFCs. In correspondence with experimental data (German Aerospace Center) the simulations show strong gradients in current densities and gas concentrations. (orig.)

  16. Predictability of the Ningaloo Niño/Niña.

    Science.gov (United States)

    Doi, Takeshi; Behera, Swadhin K; Yamagata, Toshio

    2013-10-08

    The seasonal prediction of the coastal oceanic warm event off West Australia, recently named the Ningaloo Niño, is explored by use of a state-of-the-art ocean-atmosphere coupled general circulation model. The Ningaloo Niño/Niña, which generally matures in austral summer, is found to be predictable two seasons ahead. In particular, the unprecedented extreme warm event in February 2011 was successfully predicted 9 months in advance. The successful prediction of the Ningaloo Niño is mainly due to the high prediction skill of La Niña in the Pacific. However, the model deficiency to underestimate its early evolution and peak amplitude needs to be improved. Since the Ningaloo Niño/Niña has potential impacts on regional societies and industries through extreme events, the present success of its prediction may encourage development of its early warning system.

  17. Three-dimensional TDEM modeling using integral equation method. 2; Sekibun hoteishikiho ni yoru TDEM no sanjigen modeling. 2

    Energy Technology Data Exchange (ETDEWEB)

    Noguchi, K.; Endo, M. [Waseda University, Tokyo (Japan). School of Science and Engineering

    1996-05-01

    A study was made about integral equation-assisted numerical calculation in a time domain electromagnetic (TDEM) 3D modeling. The total number of cells should be minimized now that the time required for calculation depends a great deal upon the total number of cells. On the assumption of a thin plate-like layer of anomaly in presence, with its center positioned just below the receiving point and with its entirety buried in a homogeneous 100 Ohm m medium, the correlation between the distance and the maximum cell length in the horizontal direction and the method of dividing were examined. As the result, it was found that a dividing method respecting the exponential function shortens the calculation time and that, for obtaining a true response and for minimizing the calculation time, the length of the horizontal side of the cell nearest to the transmission source needs be set to be not more than 1/2 of the distance. It was also found that the length of the side in the direction of depth of the topmost cell needs be set to be not more than approximately 1/3 of the depth of the upper surface of the plate-shaped anomaly. 2 refs., 10 figs., 2 tabs

  18. Composite Ni/NiO-Cr2O3 Catalyst for Alkaline Hydrogen Evolution Reaction

    Energy Technology Data Exchange (ETDEWEB)

    Bates, MK; Jia, QY; Ramaswamy, N; Allen, RJ; Mukerjee, S

    2015-03-12

    We report a Ni-Cr/C electrocatalyst with unpreeedented massactivity for the hydrogen evolution reaction (HER). in alkaline electrolyte. The HER Oietics of numerous binary and ternary Ni-alloys and composite Ni/metal-euride/C samples were evaluated in aquebus 0.1 M KOH electrolyte. The highest HER mass-activity was observed for Ni-Cr materials which exhibit metallic Ni as well as NiOx and Cr2O3 phases as determined by X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) analysis. The onset of the HER is significantly improved compared to munerous binary dor ternary Ni-alloys, inCluding Ni Mg materials. It is likely that at adjacent Ni/NiOx sites, the oxide acts as a sink for OHads, while the metallic Ni acts as a, sink for the H-ads, intermediate of the HER, thus minimizing the high activation energy of hydrogen evolution via water reduction. This is confirmed by in situ XAS studies that show that the synergistic HER enhancement is due to NiO content and that the Cr2O3 appears to stabilize the composite NiO component-under HER conditions (where NiOx would typically be reduced to metallic Ni-0). Furthermore, in contrast to Pt, the Ni(O-x)/Cr2O3 catalyst appears resistant to poisoning by the anion.exchange ionomer (AEI), a serloua consideration when applied to an anionic polymer electrolyte interface. Furthermore, we report a: detailed model of the double layer interface which helps explain the observed ensemble effect in the presence of AEI.

  19. Study on computer graphics. PC graphic system for supposed landscape images of substations and transmission lines; Computer graphics ni kansuru kenkyu. Pasokon ni yoru hendensho sodensen keikan kansei yosozu sakusei system ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Matsuda, Y.; Usagawa, Y.; Kawamoto, A. [Chugoku Electric Power Co. Inc., Hiroshima (Japan)

    1996-10-25

    In order to obtain the understanding of residents around sites for landscape images in construction of power plants, substations and transmission lines, preparation of supposed landscape images was studied using computer graphics (CG). The system developed on a graphics workstation in 1994 was expensive and poorer in operability than PC although real clear images were obtained. The system was thus improved to be usable on PC. The improved system is usable on OA systems in offices, and possible to transmit image data and print out high-quality images. In addition, the system offers the preparation function of facility layouts and computer graphics. The system is featured by necessary training only for 2-3 days, lower cost and necessary lower initial investment. Since its user interface was, in particular, considered to make it possible for designers to easily operate and timely cope with demands of residents, flexible selection out of various cases, rapid simulation and efficient business became possible. 3 refs., 3 figs., 5 tabs.

  20. Guarantee of property right in open access systems. Legal study of property right of electric utilities and expropriation; Open access ni okeru zaisanken no hosho. Denki jigyo ni okeru zaisanken to shuyo ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Maruyama, M. [Central Research Institute of Electric Power Industry, Tokyo (Japan)

    1996-03-01

    A study has been made about the relationship between open access, which has now become an important element of the electric utilities renovation efforts in the U.S. and Europe, and property right. The meaning of open access is to guarantee free access to suppliers by securing fair competition between them through separation of the vertical integration in power transmission and opening the transmission network to final customers. In case of Japan, the U.S., and Germany where private sector suppliers run electric utilities, however, a need arises to consider the property right that such suppliers enjoy as guaranteed by their Constitutions. The outcomes of discussions made in Germany and the State of California were complied, and some conclusions were reached. It constitutes an infringement of their property right for the authorities to order them to allow open access without compensation. In case the authorities use expropriation for the same purpose, they have to make it known clearly that the separation and opening is to the benefit of the public and must compensate fully for their action. There is no problem in giving the authorities the power to force the electric utilities to sign a wheeling contract in case the latter unlawfully rejects to sign one proposed by a wheeling-requesting party. 24 refs., 3 figs., 4 tabs.

  1. Development of hydroponic system using agricultural waste. 2. Utilization of ozone for sterilization of nutrient solution; Suiko saibai ni okeru haikibutsu riyo gijutsu no kaihatsu. 2. Ozone ni yoru baiyoeki sakkin ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Terazoe, H.; Yoshihara, T.; Nakaya, K. [Central Research Institute of Electric Power Industry, Tokyo (Japan)

    1995-08-01

    Discussions were given on a sterilizing effect of ozone on Fusarium bacteria in hydroponic culture, and its effect on components in the culture solution. In an experiment, dry air with O3 concentration of 3.5 ppm was sent into aqueous solution inoculated with Fusarium bacteria at a flow rate of 5 liters per minute. The Fusarium bacteria was sterilized nearly completely in about five minutes. No change was observed in pH, EC and dissolved oxygen concentration of the O3-treated culture solution. However, iron and manganese among the soluble components have been oxidized by O3 and precipitated, hence these components must be added after the O3 treatment. In spinach culture performed on a culture medium inoculated with Fusarium bacteria, ozone water containing dissolved O3 at 0.8 ppm was flown into a urethane foam medium and vegetable roots. This treatment has resulted in reduction of the number of strains occurred with a wilt symptom below that in the section flown with distilled water. The spinach has grown normally without showing an effect of the ozone water. 15 refs., 10 figs., 3 tabs.

  2. Study on the optimal control of the ground thermal storage system in the greenhouse. Part 4; Onshitsu ni okeru taiyo energy dochu chikunetsu system ni okeru saiteki seigyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, M. [Sanko Air Conditioning Co. Ltd., Osaka (Japan); Nakahara, N. [Kanagawa University, Yokohama (Japan)

    1996-10-27

    Three types of weight in both energy saving and optimum room temperature environment were changed to obtain the optimal control solution of the ground thermal storage system in a greenhouse. The relation diagram between the optimal solution of a performance function, and the state constraints and control function constraints was created in consideration of the energy term in a control function value area and the room temperature environment. As a result, the whole image of the performance function could be grasped in consideration of the energy term with inequality constraints and the room temperature environmental term in this study. The rate of a weighting factor in the performance function significantly influences the optimal solution. The influence on the optimal solution also changes when the optimal room temperature schedule differs. The influence that three types of rising algorithm exert on the convergence and converging speed was investigated. Superiority or inferiority occurs according to the space properties of a performance function. A zigzag method is most disadvantageous. The constraints can be converged to the optimal solution using an SUMT outer point method irrespective of the initial value. 6 refs., 6 figs., 4 tabs.

  3. Study on individual care in nursing home. Part 2. Studies on social welfare institution for the elderly from the aspect of dwelling; Koreisha kyoju shisetsu ni okeru kobetsuteki kaigo ni kansuru kosatsu. Sumai toshiteno tokubetsu yogo rojin home no arikata ni kansuru kenkyu 2

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, Y.; Otaki, K.; Ohara, K. [Yokohama National Univ. (Japan)] Toyama, T. [Tohoku Univ., Sendai (Japan)

    1998-06-30

    This study pays attention to the relation between individual care and residents` activities in the social welfare institutions for the elderly (nursing homes) and aims to clarify the influence of building environment (nursing home as dwelling place) on individual care. Behaviors of care staffs and residents are surveyed in four nursing homes. The results of the analysis of the survey are as follows: The care staff`s activities are influenced not only by physical environment and also by the residents` activities. A single bed room is more effective than a multi-bed room for individual care. The small care unit is effective in building plan if the number of staffs is enough. The personal care activities which constitute the greater part of the care activities depend on the location of the residents. It is important to pay attention not only to arrange the common space but also how to use the common space. Spatial structure is required the consideration of the relative position of not only care rooms and resident rooms but also of care rooms and the space used by residents. 7 refs., 14 figs., 7 tabs.

  4. Statistical physics modeling of hydrogen desorption from LaNi{sub 4.75}Fe{sub 0.25}: Stereographic and energetic interpretations

    Energy Technology Data Exchange (ETDEWEB)

    Wjihi, Sarra [Unité de Recherche de Physique Quantique, 11 ES 54, Faculté des Science de Monastir (Tunisia); Dhaou, Houcine [Laboratoire des Etudes des Systèmes Thermiques et Energétiques (LESTE), ENIM, Route de Kairouan, 5019 Monastir (Tunisia); Yahia, Manel Ben; Knani, Salah [Unité de Recherche de Physique Quantique, 11 ES 54, Faculté des Science de Monastir (Tunisia); Jemni, Abdelmajid [Laboratoire des Etudes des Systèmes Thermiques et Energétiques (LESTE), ENIM, Route de Kairouan, 5019 Monastir (Tunisia); Lamine, Abdelmottaleb Ben, E-mail: abdelmottaleb.benlamine@gmail.com [Unité de Recherche de Physique Quantique, 11 ES 54, Faculté des Science de Monastir (Tunisia)

    2015-12-15

    Statistical physics treatment is used to study the desorption of hydrogen on LaNi{sub 4.75}Fe{sub 0.25}, in order to obtain new physicochemical interpretations at the molecular level. Experimental desorption isotherms of hydrogen on LaNi{sub 4.75}Fe{sub 0.25} are fitted at three temperatures (293 K, 303 K and 313 K), using a monolayer desorption model. Six parameters of the model are fitted, namely the number of molecules per site n{sub α} and n{sub β}, the receptor site densities N{sub αM} and N{sub βM}, and the energetic parameters P{sub α} and P{sub β}. The behaviors of these parameters are discussed in relationship with desorption process. A dynamic study of the α and β phases in the desorption process was then carried out. Finally, the different thermodynamical potential functions are derived by statistical physics calculations from our adopted model.

  5. Combined atomistic-continuum model for simulation of laser interaction with metals: application in the calculation of melting thresholds in Ni targets of varying thickness

    Science.gov (United States)

    Ivanov, D. S.; Zhigilei, L. V.

    The threshold laser fluence for the onset of surface melting is calculated for Ni films of different thicknesses and for a bulk Ni target using a combined atomistic-continuum computational model. The model combines the classical molecular dynamics (MD) method for simulation of non-equilibrium processes of lattice superheating and fast phase transformations with a continuum description of the laser excitation and subsequent relaxation of the conduction band electrons based on the two-temperature model (TTM). In the hybrid TTM-MD method, MD substitutes the TTM equation for the lattice temperature, and the diffusion equation for the electron temperature is solved simultaneously with MD integration of the equations of motion of atoms. The dependence of the threshold fluence on the film thickness predicted in TTM-MD simulations qualitatively agrees with TTM calculations, while the values of the thresholds for thick films and bulk targets are 10% higher in TTM-MD. The quantitative differences between the predictions of TTM and TTM-MD demonstrate that the kinetics of laser melting as well as the energy partitioning between the thermal energy of atomic vibrations and energy of the collective atomic motion driven by the relaxation of the laser-induced pressure should be taken into account in interpretation of experimental results on surface melting.

  6. Large barrier, highly uniform and reproducible Ni-Si/4H-SiC forward Schottky diode characteristics: testing the limits of Tung's model

    Science.gov (United States)

    Omar, Sabih U.; Sudarshan, Tangali S.; Rana, Tawhid A.; Song, Haizheng; Chandrashekhar, M. V. S.

    2014-07-01

    We report highly ideal (n < 1.1), uniform nickel silicide (Ni-Si)/SiC Schottky barrier (1.60-1.67 eV with a standard deviation <2.8%) diodes, fabricated on 4H-SiC epitaxial layers grown by chemical vapour deposition. The barrier height was constant over a wide epilayer doping range of 1014-1016 cm-3, apart from a slight decrease consistent with image force lowering. This remarkable uniformity was achieved by careful optimization of the annealing of the Schottky interface to minimize non-idealities that could lead to inhomogeneity. Tung's barrier inhomogeneity model was used to quantify the level of inhomogeneity in the optimized annealed diodes. The estimated ‘bulk’ barrier height (1.75 eV) was consistent with the Shockley-Mott limit for the Ni-Si/4H-SiC interface, implying an unpinned Fermi level. But the model was not useful to explain the poor ideality in unoptimized, as-deposited Schottky contacts (n = 1.6 - 2.5). We show analytically and numerically that only idealities n < 1.21 can be explained using Tung's model, irrespective of material system, indicating that the barrier height inhomogeneity is not the only cause of poor ideality in Schottky diodes. For explaining this highly non-ideal behaviour, other factors (e.g. interface traps, morphological defects, extrinsic impurities, etc) need to be considered.

  7. Mechanism of H2 Production by Models for the [NiFe]-Hydrogenases: Role of Reduced Hydrides.

    Science.gov (United States)

    Ulloa, Olbelina A; Huynh, Mioy T; Richers, Casseday P; Bertke, Jeffery A; Nilges, Mark J; Hammes-Schiffer, Sharon; Rauchfuss, Thomas B

    2016-07-27

    The intermediacy of a reduced nickel-iron hydride in hydrogen evolution catalyzed by Ni-Fe complexes was verified experimentally and computationally. In addition to catalyzing hydrogen evolution, the highly basic and bulky (dppv)Ni(μ-pdt)Fe(CO)(dppv) ([1](0); dppv = cis-C2H2(PPh2)2) and its hydride derivatives have yielded to detailed characterization in terms of spectroscopy, bonding, and reactivity. The protonation of [1](0) initially produces unsym-[H1](+), which converts by a first-order pathway to sym-[H1](+). These species have C1 (unsym) and Cs (sym) symmetries, respectively, depending on the stereochemistry of the octahedral Fe site. Both experimental and computational studies show that [H1](+) protonates at sulfur. The S = 1/2 hydride [H1](0) was generated by reduction of [H1](+) with Cp*2Co. Density functional theory (DFT) calculations indicate that [H1](0) is best described as a Ni(I)-Fe(II) derivative with significant spin density on Ni and some delocalization on S and Fe. EPR spectroscopy reveals both kinetic and thermodynamic isomers of [H1](0). Whereas [H1](+) does not evolve H2 upon protonation, treatment of [H1](0) with acids gives H2. The redox state of the "remote" metal (Ni) modulates the hydridic character of the Fe(II)-H center. As supported by DFT calculations, H2 evolution proceeds either directly from [H1](0) and external acid or from protonation of the Fe-H bond in [H1](0) to give a labile dihydrogen complex. Stoichiometric tests indicate that protonation-induced hydrogen evolution from [H1](0) initially produces [1](+), which is reduced by [H1](0). Our results reconcile the required reductive activation of a metal hydride and the resistance of metal hydrides toward reduction. This dichotomy is resolved by reduction of the remote (non-hydride) metal of the bimetallic unit.

  8. Experimental studies for the power augmentation system of the vertical-axis wind turbines. Suichokujiku koryokugata fusha no shutsuryoku zokyoho ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Kakita, Y.; Okamoto, N.; Suda, N.; Ushiyama, I. (Ashikaga Institute of Technology, Tochigi (Japan)); Okazaki, T. (Mitsuya Fan Mfg. Co. Ltd., Tokyo (Japan)); Okamoto, J. (Yokogawa Weathac Co. Ltd., Tokyo (Japan))

    1993-06-01

    Wind tunnel test was conducted by equipping a vertical-axis drag type wind turbine with supplemental power augmentation unit to heighten its efficiency. Savonius rotor and cross-flow rotor were selected as a rotor of the wind turbines to be tested. When equipped with concentrator, all the wind turbines were heightened in power factor corresponding to the same tip speed ratio. It is not only because the power is augmented due to the acceleration of the air current flowing into the wind turbine rotor, but also because of deceleration of the air current which tends to prevent the rotor from revolving by bumping against the rotor's return blade. When equipped with diffuser, all the wind turbines were lowered in power factor. It is because of rotor's blocking effect which works against the air current flowing into the diffuser, and also because of larger frictional loss than the recovery effect of back current pressure loss. Simultaneous equipment with both concentrator and diffuser, if their combination is appropriate, considerably heightens the power factor because both of them give a mutually potentiating effect. Feasibility could be confirmed of the present power augmentation system through an experiment conducted on board of motorcar. 12 figs.

  9. Research cooperation in the development of laser radar for environmental measurements. Environmental network; Kankyo keisokuyo laser radar no kaihatsu ni kansuru kenkyu kyoryoku. Kankyo network

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Among the research cooperation in the development of laser radar for environmental measurements with Indonesia between FY 1993 and FY 1996, results of the research and development of the environmental network are summarized. For the environmental information network, the Tokyo NOC is linked as an Internet connection point in Japan with the Jakarta NOC using an international dedicated line with a capacity of 64 Kbps. The Tokyo NOC is linked with domestic environmental information researchers using Internet. Thus, data stored in the data processing system of laser radar can be exchanged, information in both countries can be exchanged using E-mail, and data can be accumulated. For the research cooperation with Indonesia, research of path control and information relay server, research of effective transmission of data on the network, and research of multimedia communication have been conducted. The multimedia communication, distributed processing, and extension of dedicated line network using PPTP have been also conducted. 39 figs., 4 tabs.

  10. Properties of microcracks formed on surface of concrete at steam curing period; Concrete no joki yosei katei de hasseisuru hyomen bisai hibiware no seijo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Otsuka, K. [Tohoku Gakuin Univ., Miyagi (Japan). Faculty of Engineering; Shoya, M. [Hachinohe Inst. of Technology, Aomori (Japan). Faculty of Engineering; Koseki, K. [PS Co. Ltd., Tokyo (Japan); Aba, M. [Tohoku Gakuin Univ., Miyagi (Japan). Graduate School

    1995-08-20

    Development of microcracks on the surface of steam curing concrete is considered as a main cause for damage claim on manufactured products while in use. Melting and freezing characters of seepage liquid through surface cracks are regarded as drawbacks for the durability of manufactured products. In this study, an unique X-ray inspection technique is developed to investigate the microcrack formation. Considering reinforced concrete specimens, effects of steam curing conditions on the formation of microcracks are investigated by experiments. Three different kinds of microcracks are observed at each steam curing conditions. Influences of various factors on microcrack formation are also studied. Impacts of pre-curing period, rate of cooling and rate of temperature rise on the microcrack formation are very large, large and small respectively. Again the results are analyzed by comparing with various steam curing specifications from the crack prevention point of view. The results under pre-curing condition are not satisfied with the steam curing specifications. 9 refs., 28 figs., 11 tabs.

  11. Required grades of hull steel plates in consideration of fracture toughness; Hakai jinsei wo koryoshita sentaiyo koban shiyo kubun ni kansuru ichikosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Yajima, H.; Yamamoto, M.; Ogaki, Y. [Hiroshima University, Hiroshima (Japan). Faculty of Engineering

    1997-10-01

    This paper discusses the required grades of hull steel plates based on the steel ship rule of Nippon Kaiji Kyokai (NK). The minimum value of the allowable crack length in NK rule (critical safety crack length at 0degC just before brittle unstable crack causing fatal fracture) was estimated. In the case where the estimated crack tip exists in a matrix, the crack length was a minimum of 200-210mm, while nearly 60mm in a fusion line at high-heat-input welded joint. The allowable crack lengths estimated from a specified value in the NK rule were fairly different. The allowable crack length at 0degC was also estimated from the minimum value in V-notch Charpy impact test. The private proposal on the required grades of hull steel plates in consideration of fracture toughness was discussed. Thirty-five percent of crack lengths found in real ships is 100mm or less, however, cracks of 250-400mm long are frequently found suggesting the allowable crack length of 400mm. The required grade integrally considering required values and design conditions is demanded to secure the reliability of hull strength. 5 refs., 5 figs., 2 tabs.

  12. Studies on the molecular mechanism of neural signaling, learning and memory; Chusu shinkei joho dentatsu to kioku{center_dot}gakushu no bunshi kiko ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Mishina, Masayoshi [The University of Tokyo, Tokyo (Japan). Dept. of Molecular Neurobiology and Pharmacology

    1999-12-16

    To examine the functional roles in vivo of the diverse glutamate receptor (GluR) channel subunits, we generated mutant mice defective in respective subunits. Mutant mice defective in the GluR{epsilon} 1 subunit of the NMDA-type GluR channel exhibited increased thresholds for both hippocampal synaptic plasticity and contextual maze learning, suggesting that synaptic plasticity is a cellular bases of learning and memory. The NMDA receptor channel GluR{epsilon} 2 subunit mutant mice showed impairments in the formation of the whisker-related neuronal barrelette structure in the brainstem trigeminal nucleus and synaptic plasticity in the hippocampus. Analyses of the mutant mice revealed that the GluR{delta} 2 subunit, selectively localized in cerebellar Purkinje cells, was essential in motor learning and cerebellar LTD and in Purkinje cell synapse formation. Our results suggest that some of the GluR channels play important roles in neural network formation during brain development and in higher brain function. (author)

  13. Study on the effect of micro-gravity on bio-functions; Seitai kino eno bisho juryoku no eikyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The effect of micro-gravity on bio-functions and vital reaction was studied using the facility of Underground Gravity-free Experiment Center Co. On the effect on osteoblast shape and gene expression, although fluorochrome reacting with Ca was well taken into cells, no significant difference in Ca content in cells was observed before/after falling. Expression of genes related to cell propagation was controlled under micro-gravity. Protoplast fusion of Lentinus was unaffected by micro-gravity. The mRNA fragments of gravity sensitive mutant of rice plant were affected by micro-gravity. Paramecium was set swimming in solutions with different specific gravities. The reaction behavior of Paramecium was affected by the difference in specific gravity between cell bodies and solutions. The water content metabolism functions of a mouse with needle stimulus, in particular excretory, were slightly promoted by micro- gravity. The cortisol level in blood of a falling mouse group rose showing strong stress. As the preliminary study on the geotaxis of insects, motion of bagworm was observed. 12 refs., 38 figs., 4 tabs.

  14. Studies on reducing the thermal loads of solar-pumped solid state lasers; Taiyoko reiki laser no netsufuka teigen ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, K.; Yugami, H.; Naito, H.; Arashi, H. [Tohoku University, Sendai (Japan)

    1997-11-25

    It was intended to reduce the thermal loads of solar-pumped solid state lasers (highly densified solar light is irradiated directly onto a laser medium to cause excitation. No electric power is required for the excitation.). For this purpose, experiments were performed by using a selective permeation film. Solar light includes wavelengths not effective for excitation, which causes heat generation and thermal loads such as lens heating effect and thermal stress compounded refraction, degrading the laser beam quality. The Nd:YAG was used as a laser medium, and a multi-layered film (composed of SiO2 and TiO2) which cuts wavelength below 500 nm as a selective permeation film to cut light having wavelengths not required for excitation. A laser transmitting experiment revealed that the slope efficiency is improved by 27% as compared to not using the film. Beam fluctuation was improved to 45%. Using the selective permeation film has realized more efficient conversion of the solar light into a beam with better quality. The results for calculation of heat lens effect by using temperature distribution simulation showed good agreement with experimental values. Using the selective permeation film can suppress the maximum temperature of a laser rod to 68%, as well as the thermal stress. 9 figs., 2 tabs.

  15. Research and development cooperation project on environmental measurement using laser radar in fiscal 1995 (environmental network); Kankyo keisokuyo laser radar no kaihatsu ni kansuru kenkyu kyoryoku (kankyo network)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    As a part of the cooperative work with Indonesia of R and D of a laser radar for environmental measurement, the paper described the development of an environmental network. The field survey was conducted in April, July and December 1995 and in March 1996. For the investigational research, five meetings of the committee and four times of group work were held. The Asian environmental network was studied in terms of its arrangement, operation and management, and the overall network/path control design were being prepared. To make the persons concerned abroad and in Japan understood the APEC Osaka Conference held in November 1995, a homepage APEC `95 Kansai was opened using WWW (World Wide Web, a decentralized hyper media system which can dispatch information to the whole world by network using hyper text). Moreover, in connection with this, a homepage was opened of CICC (Center of the International Cooperation for Computerization, a center controlling the whole Asian environmental information network system where E-mail and data are exchangeable with Indonesia via Tokyo NOC (Network Operation Center)). 49 figs., 8 tabs.

  16. Feasibility design of a floating airport and estimation of environmental forces on it; Futaishiki kuko no sekkei to kankyo gairyoku no suitei ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, Y.; Tabeta, S.; Takei, Y. [Yokohama National University, Yokohama (Japan). Faculty of Engineering

    1996-12-31

    A rough design was performed on a floating airport. On this floating structure, environmental external force was estimated, mooring design was carried out, and discussions was given on the position retaining performance important for airport functions and behavior of the floating structure. The discussion was given on cases that the airport is surrounded and not surrounded by floating breakwaters. A floating structure which becomes super-large in size requires considerations on force due to sea level gradient as a result of a tide. Deriving flow condition changes and force acting on the floating structure simultaneously by using numerical calculations makes it possible to estimate current force given with considerations on influence of the flow conditions created by installing the floating airport. Estimation was carried out by using a zone dividing method on wave drifting force acting upon the floating airport. As a result, it was found that installing floating and permeating type breakwaters can reduce the wave drifting force acting on the floating airport. The wave drifting force working on the floating airport can be reduced by installing the floating and permeating type breakwaters to lower levels than when no such breakwaters are installed. The airport may be moored with less number of fenders when the fenders of the same type are used. 18 refs., 10 figs., 5 tabs.

  17. Research and development cooperation project on environmental measurement using laser radar in fiscal 1994; Kankyo keisokuyo laser radar no kaihatsu ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    The paper outlined activities in fiscal 1994 in the R and D cooperation project on a laser radar for environmental measurement. In the activities in fiscal 1994 of `the ODA laser radar development committee,` the committee held four meetings, two field surveys were carried out, and two researchers were invited from Indonesia. In the field survey, the environment in Jakarta city was investigated in terms of changes in population and number of the cars registered. Further, from data collected during 1994-1998 in the central Jakarta city, the following were made clear: the trend of a decrease in SO2, the trend of a rapid increase and an excess of NO2 content over the environmental standard, the status of pollution of which the level is close to the upper limit of the environmental standard of dust, etc. In the meeting of the policy study for the field survey at LIPI headquarters, Japan proposed a system which is constituted of a difference absorption laser radar, two Mie scattering laser radars, and a central processing unit. The sites proposed were studied in cooperation with Indonesia. 40 refs., 65 figs., 9 tabs.

  18. Research report of fiscal 1997. Basic research on the commercialization of innovative energy technologies; 1997 nendo chosa hokokusho. Kakushinteki energy gijutsu no jitsuyoka ni kansuru kiso chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper summarizes the research result in fiscal 1997 from the basic research results on the commercialization of innovative energy technologies. The target of a photovoltaic power generation market includes isolated power sources (several kWp) for distant places or developing countries, and those (several tens kWp) for personal residences or public facilities. Although the former is mainly promoted in the West, while the latter over the world, their profitability is unsolved. Power plants over several hundreds kWp are in demonstration test. Solar heat power generation of several tens to hundreds MWp is most profitable, however, small-scale one is poor in feasibility. Australia takes an interest in distributed photovoltaic power generation directly connected with actual lives of residents, and has a dominant opinion that desert is useless as large-scale site. This country lays emphasis on protection and maintenance rather than positive use of desert based on a basic cognition that desert is easily changed and broken. The Australian government announced power company`s obligation to use renewable energy by 2%, and a strong organization is scheduled to be newly established. 59 figs., 57 tabs.

  19. Study on buckling and ultimate strength of a rectangular plate under combined inplane load; Kumiawase mennai kaju wo ukeru kukeiban no zakutsu saishu kyodo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Fujikubo, M.; Yao, T.; Varghese, B. [Hiroshima University, Hiroshima (Japan). Faculty of Engineering

    1996-10-01

    Elasto-plasticity analysis by using the finite element method was performed on a case that bi-axial compression and shear act on a thick rectangular plate, and applicability of the plasticity correction method was discussed. In the discussion, an investigation was made on effect of the loading method of a load on correlation between initial yield strength and ultimate strength of a rectangular plate under bi-axial compression. The analytical result from the finite element method was compared with estimated values derived by using the plasticity correction method with regard to the buckling strength. The result obtained may be summarized as follows: the effect of the loading method for combined load on the correlation between the initial yield strength and the ultimate strength is small; an approximation expression was derived for the upper limit of maximum initial bend of a deck panel of an actual vessel; the plasticity correction method for buckling strength as specified by classification societies has a certain applicability as a method to estimate ultimate strength on the safety side against plate thickness in a range of the upper limit of initial bend of an actual vessel; however, this method may estimate strength higher than the actual value depending on load ratio, hence attention is required. 5 refs., 8 figs.

  20. Investigational study of optical function materials for two-dimensional data processing; Nijigen joho shoriyo hikari kino zairyo ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper investigated/studied `space light modulation materials,` `dynamic hologram/memory materials,` `optical waveguide path materials,` etc. which become key materials in the high speed two dimensional processing. As to electrooptical materials proposed in this investigational study, the external electric field and the electric charges generated make quality of molecules themselves directly change to memory strong/weak signals of light. Therefore, the response velocity becomes less than a millionth of that of the liquid crystal display, and high speed which is needed for realtime moving image processing is anticipated. Hologram includes the phase information in addition to information on light strength. Therefore, it is a large capacity record medium and at the same time a record medium which can read/write two dimensional information as it is. With optical fiber, images cannot be transmitted as they are. Light waveguide path materials are those that accumulate roles of mirror and lens in a sheet of the material and construct a system which is strong in vibration, as optical parts connecting among materials for two dimensional data processing. 273 refs., 107 figs., 17 tabs.

  1. Theoretical study on composition of gas produced by coal gasification; Sekitan gas ka de seiseisuru gas no sosei ni kansuru kosatsu (HYCOL data no doteki kaiseki)

    Energy Technology Data Exchange (ETDEWEB)

    Kaiho, M.; Yasuda, H.; Kobayashi, M.; Yamada, O.; Soneda, Y.; Makino, M. [National Institute for Resources and Environment, Tsukuba (Japan)

    1996-10-28

    In relation to considerations on composition of gas produced by coal gasification, the HYCOL hydrogen generation process data were analyzed. From the fact that CO concentration (Y) decreases linearly with CO2 concentration (X), element balance of gasification of reacted coal was used to introduce a reaction analysis equation. The equation includes a term of oxygen excess {Delta}(amount of oxygen consumed for combustion of CO and H2 in excess of the theoretical amount), derived by subtracting the stoichiometric oxygen amount used to gasify coal into CO and H2 from the consumed oxygen amount. The {Delta} can be used as a reference to oxygen utilization efficiency. An equation for the {Delta} was introduced. Also introduced was a term for steam decomposition amount derived by subtracting the generated steam from the supplied steam. These terms may be used as a clue to permeate into the gasifying reaction process. This suggestion was discussed by applying the terms to gas composition value during operation. According to the HYCOL analysis, when a gasification furnace is operated at higher than the reference oxygen amount, coal supply variation is directly reflected to the combustion reaction, making the {Delta} distribution larger. In an inverse case, unreacted carbon remains in the furnace due to oxygen shortage, and shift reaction may occur more easily even if oxygen/coal supply ratio varies. 6 figs., 1 ref.

  2. Study of initial stage in coal liquefaction. Increase in oil yield with suppression of retrogressive reaction during initial stage; Ekika hanno no shoki katei ni kansuru kenkyu. 1.

    Energy Technology Data Exchange (ETDEWEB)

    Uesugi, K.; Kanaji, M.; Kaneko, T.; Shimasaki, K. [Nippon Brown Coal Liquefaction Co. Ltd., Tokyo (Japan)

    1996-10-28

    For the coal liquefaction, improvement of liquefaction conditions and increase of liquefied oil yield are expected by suppressing the recombination through rapid stabilization of pyrolytic radicals which are formed at the initial stage of liquefaction. Two-stage liquefaction combining prethermal treatment and liquefaction was performed under various conditions, to investigate the effects of reaction conditions on the yields and properties of products as well as to increase liquefied oil yield. Consequently, it was found that the catalyst contributes greatly to the hydrogen transfer to coal at the prethermal treatment. High yield of n-hexane soluble fraction with products having low condensation degree could be obtained by combining the prethermal treatment in the presence of hydrogen and catalyst with the concentration of slurry after the treatment. This was considered to be caused by the synergetic effect between the improvement of liquefaction by suppressing polymerization/condensation at the initial stage of reaction through the prethermal treatment and the effective hydrogen transfer accompanied with the improvement of contact efficiency of coal/catalyst by the concentration of slurry at the stage of liquefaction. 4 refs., 8 figs.

  3. Investigational report on international joint research in medical/walfare appliances in fiscal 1993; 1993 nendo iryo fukushi kiki kokusai kyodo kenkyu ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    The field of concrete cooperation, method of R and D, and business, environment to support the project, and system to promote the project were studied for the research under international cooperation through investigating the trend and organization of R and D of the medical/welfare appliances at home and abroad. Projects were then proposed. In the project for collecting/analyzing the trace quantity of blood, the anomaly is inspected at a molecular level from the collected trace quantity of blood to make the biochemical inspection painless for the patients suffering from infectious symptom or disease of adults. In the project for the high-accuracy and high-function measurement without invading the diseased part of living body, the configuration and metabolic function are measured by nuclear magnetic resonance to early detect the symptom of Alzheimer and other different obstinate diseases. In the operation support system project with three-dimensional images of living body, the three-dimensional information is obtained, by X-ray CT or MRI, about the diseased part of living tissue. Upon the exact determination of its location, the disease is cured. Besides, the monitoring systemproject was proposed for the old people`s safety against dementia. The human care robot project was also done. 56 refs., 11 figs., 15 tabs.

  4. Research report of fiscal 1997. Study on profitability evaluation technique for waste power generation; 1997 nendo chosa hokokusho. Haikibutsu hatsuden ni kansuru keizaisei hyoka shuho no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    For diffusion of waste power generation, cost reduction is important. As the profitability evaluation technique for conventional waste power systems, a simple recovery year method, total waste treatment cost method, generation cost method, and evaluation method by accumulated balance sheet are presented along with their principles. For the generation cost method, trial calculation results are presented based on documents reported. From methods for the study in Institute of Applied Energy, some estimation methods of construction cost are presented, and generation cost and profitability evaluation were studied by parametric accumulation method. The profitability was calculated for RDF power systems, and it was clarified that although as a whole this system is more efficient than a simple refuse incineration system, the balance sheet of local governments is dependent on a responsibility range for the facility. In a combined type (super refuse power generation), generally municipalities bear a combustor and boiler, while a prefecture bears generation facilities. Because of large scale generation, the profitability is dependent on a selling price of electricity. 37 refs., 36 figs., 24 tabs.

  5. Leading research in fiscal 1996. Research study on advanced measurement/analysis technology; 1996 nendo sendo kenkyu. Kodo keisoku bunseki gijutsu ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    For development of production technologies suitable for environment, safety and advanced information-oriented society by improving the flexibility of production lines, some new measurement technologies were researched. Problem solution was attempted by combining the in-situ multi-dimensional measurement technology capable of easily obtaining various 3-D information with the non-contact photon measurement technology superior in operability and sensitivity under any environment conditions. This solution requires a compact radiation source with higher brightness and wider spectral range, and a high-sensitive detector. The technology concentrating photon onto minute regions, high-efficiency transmission, and control technology of photon wave front are also necessary. Development and international standardization of a common interface is unavoidable. In addition, its network is essential for advanced use of multimedia,. In the future, the comfortable life surrounded by advanced products and multimedia, comfortable social environment, safety and resource saving will be achieved by this technology. 94 refs., 75 figs., 15 tabs.

  6. Trend of research on future development of new biocatalysts. 2; Shinki bio shokubai no sosei ni kansuru kenkyu doko chosa. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Creation of new biocatalysts was surveyed to convert chemical reactions into environment-friendly processes. Biocatalysts are characterized by their high catalytic activity, uniqueness of reactions, and non-pollution under mild conditions. Stability is required for them, such as heat resistance, solvent resistance, acid resistance and alkali resistance, under severe conditions. For the development of new biocatalysts, it is necessary to multiply utilize the techniques containing enzymes, ribozymes, mold synthetic polymers, chemical modification, and non-natural proteins. Natural enzymes have been conventionally improved through the search, imitation and modification. Hereafter, new biocatalysts with functions required for the reactions should be created by integrating information regarding functions, structures and activation of these enzymes. It is indispensable to cooperate closely with supporting techniques, such as gene engineering, organic synthesis, biophysics and computer chemistry. 35 refs., 26 figs., 1 tab.

  7. Research and development cooperation project on environmental measurement using laser radar (environmental network) in fiscal 1993; Kankyo keisokuyo laser radar no kaihatsu ni kansuru kenkyu kyoryoku (kankyo network)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    For the purpose of contributing to the research cooperation project on the development of a laser radar for environmental measurement, the paper surveyed the present and future trend of the environment related information network in Indonesia. The survey was conducted in terms of a name of the network, the main administration body, the number of users, the utilization status, the use protocol, details of service, domestic mode installation sites and the main administration body, accounting system, types of the network used, reliability and stability of network, limitations on the use and details of the limitation, etc. The plan for expanding telecommunication equipment is being advanced in a very quick tempo. However, there are many problems in digitalization, and it is feared that the plan will be delayed. As to telecommunication quality and connection quality, the telecommunication completion rate, SCR, is very low, approximately 24% on average, which is equal to that around 1990 in Japan. The business service for users is all bureaucratic since they have a lot of applications for the installation piling up with no exception to the rule of developing countries. 23 figs., 10 tabs.

  8. FY 1998 annual summary report on shared product life-cycle total information system. 3; 1998 nendo joho kyoyugata product lifecycle system ni kansuru chosa hokokusho. 3

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Recycling resources is gaining importance increasingly to correspond to global environmental problems. In urban areas, in particular, it is important to efficiently recover and recycle used large-size consumer products, e.g., home electric appliances and automobiles, which are discharged in large quantities. This study proposes a shared product life-cycle total information system, based on recognition that material recycling systems, encompassing stock materials, product production, consumption, and disposal and recycling of wastes, are essential. This system corresponds a material to information, in an attempt to realize more efficient recycling of products. The study for this fiscal year was focused on use of information modules attached to products and their members, product recycling systems using these modules, necessity for and problems involved in thermal recycle systems, problems involved in recycling home electric appliances and extraction of the data for their recycling, and material recycling process systems for home electric appliances and automobiles. (NEDO)

  9. Study on the performance improvement of multiblade fans. Effects of suction cones; Tayoku fan no seino kaizen ni kansuru kenkyu. Suction cone no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Kuratani, F.; Ogawa, T. [Hyogo University of Teacher Education, Hyogo (Japan); Yamamoto, S.

    1999-07-25

    In order to improve the performance of a multiblade fan, the effects of three types of suction cones of the fan casing on the fan efficiency and noise are investigated experimentally. The first type of the suction cone is the insertion type, which is inserted into the inside of the fan impeller. The second type is the extrusion type, which extrudes outside from the casing surface. The third type is the combination type of two types. The results of those three types are compared with those of the commonly used suction cone. The followings are made clear: (1) The insertion type and the extrusion type are effective in improving the efficiency and reducing noise. (2) The optimal lengths of the insertion and the extrusion exist. (3) The combination type is more effective in improving the efficiency. (4) The combination type with the skewed cutoff of the fan casing shows the best effect. (author)

  10. Study on the optimum design of bus window pillar join40t; Bus window pillar ketsugo buzai no saiteki sekkei ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Tomioka, N. [Nihon University, Tokyo (Japan); Lim, S.; Kim, M.; Lee, H.; Kang, S.; Bae, D.

    1997-10-01

    Automobile body structure is generally assembled using various spot welded box sectional members. Especially, in the case of the bus, the shape of window pillar joint is assembled m T-type. This T-type member has some problem such as high stress concentration, low fatigue strength and structural rigidity. Therefore, in this report, performed a study on the optimum design of the bus window pillar joint for such problem by FEM analysis and experiments. 1 ref., 10 figs., 2 tabs.

  11. Basic investigation on deflection wave propagation and strength of very large floating structures; Choogata futai kozo no tawami hado denpa kyodo to kyodo ni kansuru kisoteki kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Tsubogo, T.; Okada, H. [University of Osaka Prefecture, Osaka (Japan). Faculty of Engineering

    1997-08-01

    The response strength in which deflection waves propagating in the elastic body of a large floating structure with an order of km in length and width was investigated. Attention was paid to the waves propagating the place fully away from the boundary of a very large floating body so as to obtain the dispersion relation of waves and the relation between incident waves and deflection waves. Next, the frequency response was checked from the aspect of the displacement amplitude and strength for beams and plates. The dispersion relation of waves propagating the place fully away from the boundary of a very large floating body and the relation between the waves and infinite-point incident waves were represented by an expression. Similarly, the waves propagates more than the infinite-point incident waves in frequency, wavelength, and speed. A lower-limit value exists in the propagation speed. The displacement and stress amplitudes are represented by a relational expression. For plates, the displacement amplitude increases when the wave direction coincides with the small-rigidity direction. The stress amplitude is maximized when the waves corresponding to the ``wave below a floating body = size of a characteristic wave number`` reach the large-rigidity direction. 10 refs., 10 figs., 2 tabs.

  12. Study on property-gradient polymer electrolyte for rechargeable lithium batteries; Lithium niji denchi no tame no keisha tokusei kobunshi denkaishitsu no sosei ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Kokumi, Z.; Kanemura, S.; Inaba, M.; Takehara, Z.; Yao, K.; Uchimoto, Y. [Kyoto University, Kyoto (Japan)

    1997-02-01

    This paper describes the fundamental experiments for creating property-gradient polymer electrolyte for rechargeable lithium batteries. The rechargeable lithium battery is composed of an anodic composite agent section with high ion conductivity, a separator equivalent section with high mechanical strength (high bridging degree), and a section surpressing the precipitation of metal lithium by contacting with it. The continuous property-gradient polymer electrolyte was tried to be synthesized by means of the plasma polymerization method. As a result, plasma polymerization electrolyte with high ion conductivity could be prepared from the liquid phase by using a monomer with low vapor pressure. Porous material simulating the anodic composite agent was impregnated by the monomer, which was plasma-polymerized. As a result, it was found that the bridging degree decreased from the surface towards the inside of the plasma-polymerized porous material. In addition, polymer was prepared using fluorine-base monomer. Thus, LiF thin film could be prepared through the reaction between the polymer and metal lithium. 3 figs.

  13. Studies on surface structures and mechanism of photocatalytic action of semiconductor oxides; Handotai hikari shokubai no hyomen kozo seigyo to sayo kiko kaimei ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Takeuchi, H.; Sona, S.; Koike, H.; Hori, H.; Negishi, N.; Kohara, H.; Ibusuki, A. [National Institute for Resources and Environment, Tsukuba (Japan); Vakhtin, A.; Borovkov, V. [New Energy and Industrial Technology Development Organization, Tokyo, (Japan)

    1997-02-01

    Studies are made to define the working mechanism of semiconductor photocatalysts such as TiO2 and to establish designing guidelines for improving on their activity and functions. TiO2 in the air actively produces oxygen seeds for the oxidation and removal of NOx, etc. It is desired that a catalyst have a specific surface area large enough to retain the product of its action. To meet the need, a thin-film photocatalyst which is an aggregate of TiO2 crystals is produced by burning a film of a sol/gel system of reaction doped with macromolecules. This product has a larger specific surface area and is higher in pollutant-removing performance, and may be put into practical use. In another experiment, metal-carrying particles TiO2 suspended in water are employed for the reduction of CO2. Though the main product of catalysts carrying Pt or Pd is methane, a photocatalyst carrying RuO2 produces acetic acid mainly and loses less activity with the passage of time. A hybrid photocatalyst is composed of an organic pigment and inorganic semiconductor, synthesized through a covalent bond between a sililated-surface thin TiO2 film and porphyrin. It is confirmed that the newly developed process brings about an increase in electron migration efficiency. 3 figs.

  14. Study on the application of plasma technology to advanced global environmental harmony type technology; Kankyo chowagata gijutsu no kodoka eno plasma no oyo ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Plasma application technology is systematically investigated. Fundamental feature of plasma, method of plasma generation, special features of plasma, and its application area are arranged. The present application area of plasma chemical reaction in industry has been arranged for each utilization and process according to the patents research and scientific journals. For the global environmental harmony type technology, functions required for the membrane separators are investigated by assuming the recovery of environmental load substances, and possible manufacturing process of the membrane by using plasma technology is also investigated. For the improvement of catalysis by the plasma process, the requirement for the catalyst, a fine particle effect for catalyst, production of catalyst, plasma technology applicable to the improvement of catalyst, thermal plasma, and low-temperature plasma are described. For the application of plasma to enhance the catalysis reaction, synthesis of ammonia and methanol are described. 177 refs., 67 figs., 18 tabs.

  15. Study on thermal environment and energy consumption in underground shopping centers. Chikagai no netsu kankyo to energy shohi ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Miura, H. (Waseda Univ., Tokyo (Japan). Graduate School); Ojima, T. (Waseda Univ., Tokyo (Japan))

    1991-12-30

    In this study, the actual condition of the energy consumption has been surveyed to compare the environmental loads in underground shopping centers with those in buildings on the ground, aiming at clarifying the actual thermal environment in underground shopping centers located in the Kanto area and the features of the thermal environment therein. The energy consumption was calculated by primary energy conversion on the basis of the average data obtained for the past three years. The survey of energy consumption in 32 underground shopping centers in Japan shows that all such places, commonly from Hokkaido to Kyushu, were the spaces consuming a large amount of energy. In the underground shopping centers, total energy was consumed four times as large as that in ordinary offices, energy for cooling energy consumption larger by 4 times, by 6 times for air cooling and six times, and energy for heating more than four times. They required energy twice to three times as large as that in department stores. The reason for it is considered that in underground, not only the 24-hour ventilation and air condition are required because of the public environment but external and internal heat loads are dealt with. 4 refs., 16 figs., 9 tabs.

  16. Report of 'Survey on Asian environmental information networks'; 'Asia kankyo joho network chosa' ni kansuru hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    Information systems, mainly aided by computers, are becoming increasingly important, contributing to development of wide areas of societies and economics, to begin with. However, few developing countries have established sufficient information systems, in spite of their strong desires to do so, which will further widen the gap between them and advanced countries, where these systems are acceleratedly advancing. Given these situations, Center of International Cooperation for Computerization (CICC) has been implementing various projects for providing assistance to and cooperation with oversea countries which are trying to develop information systems. This report summarizes the project, which CICC has been commissioned by Optoelectronic Industry and Technology Development Association as part of the cooperation programs, for establishing the Asian environmental information networks. It outlines the research cooperation project for the environmental networks, results of the 4 on-the-spot surveys, 2 occasions for inviting researchers to Japan, and construction of the internet and Asian environmental information network systems. (NEDO)

  17. Research and development cooperation project on environmental measurement using laser radar in fiscal 1993; Kankyo keisokuyo laser radar no kaihatsu ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    As one of the international research cooperation projects, the research cooperation in developing laser radar for environment measurement started between Japan and Indonesia. The project is scheduled to be carried out in a 4-year plan starting fiscal 1993. In fiscal 1993, conducted were negotiations with Indonesia on its implementation and a field survey. Between January 6 and 15, 1994, the first field survey was made in terms of topography, climate, road network and traffic situation of Jakarta city, and the proposed sites for installation were reported. The paper also introduced the reception system on the Indonesian side and a request for technical learning through stay in Japan. The second field survey was conducted between February 27 and March 6, 1994. Indonesia requested that they want to make laser radar observation not only for the local area, but the one that covers industrial areas, central urban areas and residential areas. Incidentally, there was an opinion that it is important to elucidate the pollution mechanism. 19 refs., 43 figs., 6 tabs.

  18. Research report on the trend of preventive measures against global warming by substituting CFCs; Daitai freon no chiku ondanka taisaku doko ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This paper reports the research results on the present state and future trend of protective measures for the ozone layer, and the trend of preventive measures against global warming by substituting CFCs such as HFC, through international conferences, meetings and lecture meetings, and literature survey. In the 8th meeting of the parties to the Montreal Protocol, it was presented that refrigerator producers in Thailand phased out CFCs from their products earlier than the schedule in cooperation with Japan. The final draft including the approval of essential use from 1997 to 2002 was reviewed, and reported to the technology/economy assessment panel. Reduction of ozone depleting substances was guided in Thailand, Indonesia and Philippines. The latest trend of substituting technologies of HCFC was surveyed, and the control trend of F-containing greenhouse effect gas emission was also surveyed through the conference of the parties of climate change in fiscal 1996. Based on the IPCC report in 1995, the emission amount of greenhouse gases of nearly 10% in contribution such as CO2, methane and fluorocarbon was arranged. R and D on destruction of CFCs was also surveyed. 35 refs., 54 figs., 32 tabs.

  19. Research cooperation project on conservation and sustainable use of tropical bioresources; Seibutsu tayosei hozen to jizokuteki riyonado ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Research cooperation has been conducted on the conservation of biological species inhabiting in the tropical rainforest in developing countries in tropic zone and the sustainable use of genetic resources using biotechnologies. For the research cooperation with Thailand in FY 1996, research of the food acquisition strategy of the Primates has been conducted. A total of 19 species of animals and plants, i.e., 7 species of arbors, 7 species of herbs, and 5 species of insects, were newly confirmed for pig-tailed monkey. In Indonesia, a feasibility study was conducted on the information center of Indonesian tropical bioresources. For the research of culture collection of bacteria, 113 strains of acetic acid bacteria and 85 strains of lactic acid bacteria were separated from Indonesian specimens, and they were identified. An agreement was concluded with Malaysia, and discussions were conducted for the concrete implementation plan. For the project, construction of a database was investigated for bioresources including bacteria and higher animals useful for industries. Maintenance of gene bank was also investigated. 391 refs., 61 figs., 93 tabs.

  20. FY 1998 annual report on the surveys on high-efficiency power generation techniques of the next generation; 1998 nendo jisedai kokoritsu hatsuden gijutsu ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Comprehensive surveys on and assessment of seeds of the high-efficiency power generation techniques of the next generation, both domestic and overseas, are conducted to help propose preliminary national research themes. In FY 1998, the survey efforts are directed not only to the trends of those for industrial power generation under development, e.g., combined cycle, coal-gasification combined cycle and pressurized fluidized bed combined cycle, but also to the trends of newly proposed systems, e.g., humid air combined cycle, methane reforming combined cycle, fuel reforming/humid air combined cycle, fuel reforming/fuel cell combined cycle and micro gas turbine, to further enhance efficiency by integration with a gas turbine power generation system. The efforts are also directed to (new power generation techniques in the basic research stage) being studied mainly by academic and research organizations, and to development trends of new power generation techniques under development by private enterprises, mainly based on the patent survey. (NEDO)

  1. Final report of `research on advanced uses of cast materials`; Chusho kigyo taisaku gijutsu tokubetsu kenkyu `chuzo zairyo no kodo riyo gijutsu ni kansuru kenkyu` shuryo hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    Tada, S.; Takahashi, T.; Abe, T. [Tohoku National Industrial Research Institute, Sendai (Japan)

    1997-03-31

    For the advanced utilization of casting iron, temperature differential austempering and partial austempering with the gradient mechanical properties of ADI (austempered ductile iron) by local electric method were experimentally investigated. For the former, gradient mechanical properties are obtained by giving temperature difference to the material in the process of austempering of casting iron, to add the strength and toughness. For the latter, mechanical properties are controlled by repeating partial austempering with changing the isothermal transformation condition by means of local electric method, to obtain the strength characteristics with appropriate balance. As a result of the former experiment, function gradient materials could be obtained with continuously changing internal mechanical properties. The fabricated material provided different properties depending on the direction of load. Radial crushing strength constant of the ring material depended on the treatment temperature of inside surface of the specimen. Fatigue and yield strengths can be simultaneously improved. As a result of the latter experiment, it was found that the mechanical properties can be improved at arbitrary part by the partial austempering. 13 refs., 25 figs., 4 tabs.

  2. Fiscal 1995 research investigation on chemical process technology using supercritical fluid; 1995 nendo chorinkai ryutai wo riyoshita kagaku process gijutsu ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    With relation to the supercritical fluid utilization technology, conducted in fiscal 1995 were collection of basic data, extraction of R and D subjects and survey/analysis of application fields based on the literature survey and overseas field survey. From the research results, the following were selected as research subjects: as to the clean/recycling process technology, non-selection cascade treatment process of mixed waste plastics, hazardous waste treatment process, and radioactive waste treatment process. As to the unused resource utilization process technology, the supercritical submerged combustion power generation process, heavy hydrocarbon resource reutilization process, biomass synthetic utilization process, and carbon dioxide reutilization process. As to the next generation reaction process technology, the simple reaction process, de-organic solvent process, chemical materialization process for methane, and reaction separation combined process. As the innovative material process technology, the plastic forming process, high-functional materials, high-efficiency energy conversion materials, and heightening of function of solid wastes. 537 refs., 116 figs., 54 tabs.

  3. Survey of pollution-resistant plants and their cultivating techniques; Osen busshitsu taisei shokubutsu to sono shokusai gijutsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The reduction of forests due to environmental pollution has been surveyed, to investigate the pollution-resistant plants and solid microorganisms. In Japan, the blight of needle-leaf trees (pine and momi fir) and of Japanese oak has occurred, and blight of some other trees, such as wild cherry trees, Japanese apricot trees, birch, Japanese cedar, cypress and bamboo, has been reported from various regions. In this article, plants reported to be resistant to pollutants are listed, and the physiological features of these plants are described. Furthermore, to develop pollution-resistant plants, reports relating to clarification of the mechanism of resistance development and the genes involved are reviewed. Microorganisms which symbioses for roots support these root functions. They also suppress the activity of pathogenic microorganisms and improve the environment around the roots, thus helping plants to grow normally. The roles played by symbiotic microorganisms and how to utilize these organisms are discussed. Their functions in coping with acid rain and heavy metal pollution, and how to utilize such functions are also discussed. 707 refs., 13 figs., 13 tabs.

  4. Investigation on the development and introduction of new geothermal exploration technology. Part 2; Chinetsu shintansa gijutsu kaihatsu donyu ni kansuru chosa. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-01

    For the purpose of maintaining and increasing the geothermal power generation amount, the development was made of exploration technologies which become necessary in the stage of geothermal reservoir exploration and in the stage of reservoir management and peripheral development. As development technologies, the following were proposed: fracture flow characteristics exploration method (FE), production/circumference areas flow characteristics exploration method (PE), and integrated analyzing method (IA). As to FE, for the survey of geothermal fluid dynamic characteristics in fracture aggregate composing the geothermal reservoir, developments were made of the well hydraulic testing method for examining hydraulic characteristics of fracture system and of the fracture evaluation method composed of the core/logging analysis method, the permeability logging method and electroseismic exploration method. As to PE, for maintaining and managing steam production in the developmental area and developing the area to the circumference area, development was conducted of technology for exploring variations of reservoirs and fluid flow from the data on precision gravity, three-dimensional resistivity, fluid geochemistry, active seismic wave and self potential, precision electromagnetism, passive seismic wave, etc. As to IA, development was made of reservoir simulation technique, etc. 2 refs., 70 figs., 41 tabs.

  5. Study on search for antioxidant peptides in unused protein resources and their production; Miriyo tanpaku shigen kara no kosanka pepuchido no tansaku to seisan ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    For the development of antioxidants that are high in use value, peptides are produced in a bioreactor from so-far-unused or little-used protein resources originating in marine organisms collected along the Sanriku coast, and antioxidants that they may contain are searched for. Three kinds of red alga, eight kinds of brown alga, and internal organs of processed fish are treated in the bioreactor. The bioreactor is a rotary membrane type especially built for the effective decomposition of proteins in this study. Reaction solutions containing proteins and enzymes are let through an ultrafiltration membrane module in rotation at a high speed, and the products with their molecules reduced in weight are effectively taken out of the system (free of clogging). The specimens checked for antioxidant features are all found to be positive when subjected to the iron rhodanide method or carotene method, the two methods determining the change in the amount of oxygen in hydroperoxide and {beta}-carotene that are produced when the linolic acid is oxidized. Every one of the specimens prepared for this study exhibits antioxidant features in plural, different mechanisms. It is necessary to collect further basic findings about oxidation inhibiting mechanisms for the development of more active antioxidant peptides. 39 refs., 46 figs., 8 tabs.

  6. Report on the FY 1999 R and D survey on ultra-high sensitive photoelectric converter; 1999 nendo chokokando koden henkan soshi ni kansuru kenkyu kaihatsu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    By the ICB method which is one of the ion engineering methods, photomultipliers were formed using organic dye thin films. By changing the energy to bond traps on thin film/metal electrode interface and electric charges by change of acceleration energy of ion beams, a technology was developed for adjusting the optimum operating temperature between -20 degrees C and +100 degrees C. The wide range of operating temperature and favorable SN ratio can be realized. It was made clear that the dark current of the photomultiplier is composed of two components of contribution by the residual charge stored on the interface at photomultiplying and of contribution by charge injection from the Schottky barrier. Based on this, the residual electric charge removal method by heating and applied pulse voltage was developed. The development for practical use was studied of ultra-high sensitive photoelectric converters. As an intelligent photo sensor, a biomimetic visual photosensor was proposed which uses amplification/memory/arithmetic functions and film formation/processability of organic thin films. The paper also described the image sensor. (NEDO)

  7. Report on the cooperative study of technology to collect valuable resources in brine; Kansuichu no yuka shigen kaishu gijutsu ni kansuru kenkyu kyoryoku hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    The paper reported on the research, design, and evaluation on a system to recover by sedimentation magnesium from the brine in the salt manufacture by solar evaporation in Mexico, and a system to recover by adsorbent lithium, boron, etc. from the brine of the solar pond salt field in China. In the case of Mexico, an overall recovery system was developed, but in the evaluation of economy of the system, it cannot be said that the system is feasible even if assuming that the required fresh water can be secured. It was found out that the economical efficiency largely depends upon the cost of hydrated lime and the selling price of magnesia clinker. In the case of China, a plant for production of 500 tons/year of lithium carbonate was conceptually designed to evaluate the economical efficiency. As a result, the internal profitability of the plant is not so high, approximately 6%, though continuously profitable during the operation of 15 years. It was indicated that the project was not economically very efficient. 164 figs., 44 tabs.

  8. Improvement of prediction accuracy of large eddy simulation on colocated grids; Colocation koshi wo mochiita LES no keisan seido kaizen ni kansuru ichikosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Inagaki, M.; Abe, K. [Toyota Central Research and Development Labs., Inc., Aichi (Japan)

    1998-07-25

    With the recent advances in computers, large eddy simulation (LES) has become applicable to engineering prediction. However, most cases of the engineering applications need to use the nonorthgonal curvilimear coordinate systems. The staggered grids, usually used in LES in the orthgonal coordinates, don`t keep conservative properties in the nonorthgonal curvilinear coordinates. On the other hand, the colocated grids can be applied in the nonorthgonal curvilinear coordinates without losing its conservative properties, although its prediction accuracy isn`t so high as the staggered grid`s in the orthgonal coordinates especially with the coarse grids. In this research, the discretization method of the colocated grids is modified to improve its prediction accuracy. Plane channel flows are simulated on four grids of different resolution using the modified colocated grids and the original colocated grids. The results show that the modified colocated grids have higher accuracy than the original colocated grids. 17 refs., 13 figs., 1 tab.

  9. Study on improving efficiency in hydrogen utilizing regional heat supply system; Suiso riyo chinetsu kyokyu system no koritsu kaizen ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Sueyoshi, S.; Ishitani, H.; Matsuhashi, T. [The University of Tokyo, Tokyo (Japan). Faculty of Engineering

    1997-01-30

    With an objective to improve efficiency in a hydrogen energy distribution system, discussions were given on combining heat energy supply from hydrogen with factory waste heat recovery by using hydrogen absorbing alloys. This system carries out simultaneously heat supply as a result of burning hydrogen directly and heat supply obtained by converting hydrogen pressure by using hydrogen absorbing alloys. This system could allow existing gas piping facilities to be utilized. However, since quantity of hydrogen that can be transported as pressure is smaller than quantity of heat of hydrogen itself, absorption and emission are repeated a number of times in order to utilize the heat source to a possible maximum extent. Thus, a large quantity of waste heat can be utilized when this method is used. A hydrogen manufacturing system by means of LNG reformation may be combined with this heat transportation system. When waste heat that is received is handled as having zero input in the same sense as natural energy, and heat supply from a hydrogen absorbing alloy is repeated for 50 times, the overall energy balance has resulted in a considerably good value at 0.95. 5 refs., 9 figs., 5 tabs.

  10. Report on `Survey of commercialization of intellectual ownership such as patent rights`; `Tokkyoken nado chiteki shoyuken no jitsuyoka ni kansuru chosa` hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    A survey was conducted on research results in industrial circles, universities, etc. in the U.S., Europe and Japan, especially the state of how intellectual ownership such as patent rights is handled and the present situation of the commercialization of intellectual ownership, proposing problems and measures to be taken for promotion of practical use of excellent research results in Japan. The most important thing obtained from the survey is that study jointly by industrial circles and universities in the U.S. and Europe is much more advancing than that in Japan and is firmly established not only in industrial circles, universities and national research institutes, but in the whole society, actually producing a lot of favorable results. For Japan to catch up with the U.S. and Europe, needed is not only accumulation of the ideas in the past, but drastic measures to be taken from a new point of view. Concretely, it was proposed that by belonging intellectual properties such as patent rights to universities/research institutes and transferring their disposal rights to them, royalties of licenses are given back to inventors as incentives, and that as a body promoting the transfer to the industrial circle, `management organization` to which private vitality is introduced is established in universities/research institutes in order to promote interconnection between the industrial circle and universities. 15 refs., 35 figs., 36 tabs.

  11. Survey report on an environmental harmony type production system of chemical products; Kankyo chowagata kagaku seihin seizo system ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    As part of establishing an environmental harmony type production system of chemical products, study and survey were made on PET bottles. Using the life cycle analysis method (LCA), a study was made for proposing a material recycle (MR) method which is environmentally and economically excellent in the stage of recycling waste PET bottles. The total cost of recycling can be reduced by 34% supported by a decrease in equipment cost and improvement in yield if there is no mixture of foreign substances such as aluminum caps and PVC bottles. However, the ratio of the amount obtained from the reduction to the total production cost is small, and it is necessary to take measures from a viewpoint of the cost in a total production process and environmental loads. In a survey in Kawaguchi city, PET bottles discharged from the business sector occupied 41% of all the discharge amount. In a survey in Yokohama city, very important data were obtained on PET bottles appointed as the second type under the recycle law. The quality of PET bottles to be brought to the recycling plant is important for effectively processing PET bottles in MR method. For achievement of MR which is low in cost and small in environmental load, needed were cooperation by citizens, the shipping management system in autonomous government, and changes in design and material quality to be made by the industrial circle. 8 refs., 64 figs., 68 tabs.

  12. Fiscal 1996 investigational research on the chemical process technology using supercritical fluids; 1996 nendo chorinkai ryutai wo riyoshita kagaku process gijutsu ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Importance was studied of making a research on the chemical process technology using the supercritical fluid. As for its effect on global warming, the amount of CO2 emission was compared during the operation between the conventional process and the process using the supercritical fluid, the CO2 reduction rate and amount were trially calculated, and a CO2 reduction of a several ten thousand ton scale in carbon conversion was predicted. As to hazardous materials and the reaction of waste retrieval, it was made clear that the process using the supercritical fluid was valid also for objects for which the chemical process used to be impossible, which indicates a possibility of the widening field of application. Concerning its effect on the energy conservation, energy reduction of several ten thousand tons in heavy oil conversion was predicted by replacing all the existing processes with supercritical fluids. Relating to the recycling, with the use of supercritical fluids, the process is possible which produces higher quality and yield and fewer unnecessary products such as char than the conventional process. 197 refs., 102 figs., 71 tabs.

  13. Reduction mechanism of dynamic loads on down wind rotor; Furyoku hatsuden system down wind rotor no doteki kaju no keigen kiko ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Seki, K.; Shimizu, Y.; Yasui, T. [Tokai University, Tokyo (Japan)

    1997-11-25

    Dynamic force on blades in a large wind mill changes with rotational speed for various reasons, such as wind shear that causes vertical distribution of wind velocity or titling angle. Therefore, a 2-blade system on a teetered hub is a practical selection for the coned, down-wind type. Use of teetered axis greatly reduces bending moment in the flap direction and that at the axis of rotation. An attempt was made to understand dynamic loads by inertial force resulting from oscillation of the blade rotating on the teetered axis, and thereby to avoid them. The in-plane load can be diminished to zero when the teetered axis is coincided with the center of gravity, but generally cannot be avoided when the blade is strained significantly, except it is operated at the rated condition. The in-plane load and bending moment can be avoided, when rotational freedom is given around the y axis. Dynamic load on a down-wind rotor can be avoided by use of universal joint. 3 refs., 6 figs.

  14. Research cooperation of the development of laser radar for environmental measurements; Kankyo keisokuyo laser radar no kaihatsu ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Research and development of the laser radar for measuring the air pollution in urban areas and the environmental information network have been conducted through the cooperation with Indonesian researchers. A measurement system suitable to actual situation of Indonesia has been constructed. In FY 1996, some works have been conducted as in the final fiscal year. To set the laser radar for environmental measurements and to make a plan of measurement research, conditions of air pollution in Indonesia and setting places of systems have been investigated. Opinions for the cooperation research have been exchanged with Indonesian researchers. Actual trends of the environmental measurements technology using laser radar have been surveyed. Indonesian researchers have been invited to learn operation and data processing of the system. One unit of MIE diffusion laser radar system has been designed and fabricated, and an additional data processing program has been made. The system has been delivered to Jakarta and installed. After the adjustment, performance tests have been conducted to complete the construction of the system. 3 refs., 72 figs., 10 tabs.

  15. Experimental study on the aerodynamic performance of 3-dimensional vortex-blowers. Sanjigen uzuryu blower no kuriki seino ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Yamazaki, S.; Ito, E.; Fujio, M.; Fujita, H. (Hitachi, Ltd., Tokyo (Japan))

    1992-10-25

    Vortex blowers with two-dimensional blades have such deficiencies as low aerodynamic performance and high noise. Accordingly, discussions have been given on effects of three-dimensionalized blades on internal flows and aerodynamic performance with the objective of making the vortex blowers smaller in size, higher in performance, and lower in noise. A spiral flow exists in the flow path in a casing, which has its flow velocity increased as the flow rate is decreased. The flow velocity at the closing point reaches about two times as large as the circumferential speed of the blades in the case of having three-dimensional leading blades. The spiral flow outflowing from outer circumference of the blades into the casing flow path has its flow velocity nearly halved while swirling in semi-circular form in the casing flow path, by which a vortex blower converts the total pressure in the casing flow path to a static pressure. When the outlet angle in the axial direction is changed from 90[degree] (two-dimensional blade) to 50[degree](three-dimensional leading blade), the flow velocity components increase largely in the circumferential direction, with the pressure coefficient and the dynamic coefficient increasing by about two fold respectively. When the inlet angle in the axial direction is reduced to 40[degree] , the blade incident loss reduces, while the pressure coefficient improves by about 20% and the heat insulation efficiency by about 30%. 4 refs., 15 figs., 1 tab.

  16. On flutter stability of decks for super long-span bridge; Cho chodai tsurihashi hogoko no furatta anteika ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Matsumoto, M. [Kyoto Univ. (Japan). Faculty of Engineering; Hamazaki, H. [Fuji Research Inst. Corp., Tokyo (Japan); Yoshizumi, F. [Kyoto Univ., Kyoto (Japan). Graduate School

    1996-04-21

    In recent years, with the development of high strength steel, long span suspension-bridge becomes possible, furthermore, with the progress of welding technology, the horizontal deformation and torsional deformation of the deck increase owing to the reduction of energy dissipation due to sliding friction. Because of this, super long-span bridge is easy to get vibrated by wind, stability measures having more excellent wind resistance become necessary. In this study, aiming at controlling the pattern of air flow around the sections of box-form girder of super long-span bridge, studied were conducted on deck sections having more excellent flutter stability. Studied were conducted on the relationship between torsional vibration and flexible vibration coupled with unsteady aerodynamic force coefficience at the occurrence of flutter and the occurring mechanism of the flutter was cleared. The characteristics of the aerodynamic force of box-form girder having oval section, rectangle section with center barrier, anti-triangle section and tandem oval section respectively were studied and the results were reported. 10 refs., 25 figs.

  17. Some studies on structural planning of long-span cable stayed bridge; Choshikan shachokyo no kozo keikaku ni kansuru 2,3 no kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Endo, T. [NKK Corp., Tokyo (Japan)

    1997-06-20

    Feasibility of cabled-stayed bridges with 1000m-grade spans is discussed while re-examining the plan for constructing a Great Tatara Bridge to connect Honshu and Shikoku, Japan, and in this process various tasks and questions are isolated. Some which will be problems in designing the new bridge structure are taken up, including the load-bearing capability of the bridge as a whole, vibration of long cables, resistance to long-period earthquakes, and accuracy management during the construction work. Findings are stated below. A cable-stayed bridge is not significantly different from a suspension bridge and is sufficiently feasible until the span exceeds 1500m. When the span is longer, however, the bridge beam cross section needs be designed very prudently in view of the great axial force and wind load to be imposed on it. Effective for the assurance of load-bearing capability for a long-span cabled-stayed bridge is a structure in which load is elastically confined in the direction of the bridge axis. In connection with vibration damping for very long cables, it is verified that a new dimpled cable suits the purpose of suppressing wind load from increasing without reduction in damping effect. 28 refs., 23 figs., 7 tabs.

  18. Ultimate strength analysis of long-span cable-stayed bridges; Chodai chachokyo no shukyoku kyodo kaiseki to kyodo ni kansuru ichikosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Xie, X.; Yamaguchi, H. [Saitama Univ., Urawa (Japan)] Nagai, M. [Nagaoka Technical Coll., Niigata (Japan)

    1998-07-21

    Recently, span of cable-stayed bridges has been getting loner and longer, present situation is that cable-stayed bridges with span 600 to 800m class have been built inside and outside the country, and accurate determination of its ultimate strength has been an important problem statistically. However, concrete design method for evaluating load bearing stress of long-span cable-stayed bridge. Particularly of the main beam whose axial stress is dominating, has not been established so far. As for cable-stayed bridge, even for long-span, effect of plasticization of cross section on ultimate strength is severe because there is little effect of geometric nonlinearity and it is thought that accurate evaluation of ultimate strength only by elastic finite potential analysis is difficult. Accordingly, it is necessary to study the behavior by using combined nonlinear analysis considering the nonlinearity of the material in order to evaluate the safety and economy to long-span cable-stayed bridge. In this report, 3 dimensional analysis method was formularized taking into account the combine nonlinearity of multi-box girder and analysis program of ultimate strength behavior of long-span cable-stayed bridge was developed. 19 refs., 17 figs., 2 tabs.

  19. Preparation and utilization of amorphous siliceous materials from serpentine (Mg3Si2O5(OH)4) by acid treatment; Jamonseki no kofuka kachika ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-01-30

    Concerning the conversion of serpentine, not only its magnesium component but also silica component, into industrial materials, conditions suitable for the production of porous materials and amorphous silica by acid treatment were evaluated, and the properties of the products were evaluated. The silica resulting from the acid treatment of serpentine comes out in different forms, each reflecting the structure of the parent rock, that is, an amorphous mass of planar particles from antigorite and a fascicular mass of filaments from chrysotile. A microporic structure resulted when a small quantity of magnesium was allowed to remain in the skeleton structure and acid treatment conditions were properly adjusted. Several siliceous compounds were prepared for the purpose of finding use for silica from this rock, and then it was found that high-efficiency production of high-crystallinity compounds was possible and that they were furnished with properties fit for use as materials. Furthermore, study was made about the kaolinite reaction in which serpentine would be directly converted into useful materials. 105 refs., 55 figs., 6 tabs.

  20. Investigations on measures to reduce nitrous oxide (N2O); Asanka chisso (N2O) no teigen taisaku ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Discussions were given on measures to reduce N2O as part of the measures to prevent global warming. Nitrous oxide has a long atmospheric lifetime of 150 years, and its greenhouse warming potential will increase by 310 times that of CO2 after 100 years. It can also be a cause of ozone layer destruction. Nitrous oxide is estimated to have influence of about 10% as compared with CO2 even under the present conditions. Discharge of N2O from manufacturing process of adipic acid is aimed to be eliminated totally by 1998. Improvement in efficiency of combustion of fossil fuels and wastes serves most effectively to reduce not only N2O but also CO2. Nitrous oxide generated in sewage treatment as in sewage purifier may be reduced if the batch process is turned into a continuous process, but assistance from policy side would be required for wider adoption of the process conversion. No environmental regulations are applicable to N2O, whereas a problem is present that the number of system installation would not grow because of economic reasons even if the system is feasible technically. Another problem is that the N2O reducing technology is in trade-off relation with other warming gases such as NOx and methane. Comprehensive technological evaluations aimed at optimization must be moved forward in the future. 236 refs., 102 figs., 78 tabs.

  1. Investigation of nitrous oxide (N2O) abatement technologies. 2; Asanka chisso (N2O) no teigen taisaku ni kansuru chosa. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Emission amount of nitrous oxide (N2O) from anthropogenic sources is analyzed, and reduction effects by the abatement technologies are evaluated. The concentration of nitrous oxide in the atmosphere continues to increase and emissions from agricultural and ecosystem sources are drawing particular attention. For the emission of N2O in Japan, 8.28 Gg-N2O per year is emitted from fossil fuel combustion facilities, 6.95 from waste incineration facilities, 22.5 from transportation vehicles including automobiles, 26.7 from the chemical industry including establishments engaged in adipic acid production, 2.1 from sewage treatment facilities including septic tanks, 6.3 from farmland, and 7.1 from livestock excrement. For the N2O abatement technologies for different sources, fuel improvement, high temperature combustion, acceleration of reduction decomposition reaction, and development of catalysts are significant for the combustion technologies. In connection with N2O discharged in the process of adipic acid production, major businesses have internationally committed to up to 99% abatement of the N2O emissions by 1998. With regard to wastewater and sewage treatment facilities and septic tanks, improvement in COD/NO-N ratio, retention period, pH level, and reduction process is pointed out. 204 refs., 70 figs., 53 tabs.

  2. Investigation on chemical heat pump using calcium-chloride; Enka calcium no suiwa dassui hanno wo mochiita solar chemical heat pump ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Fujii, I.; Arai, T.; Saito, Y. [Meiji University, Tokyo (Japan)

    1997-11-25

    With an objective of developing a room heating system utilizing a solar chemical heat pump, an experimental system was fabricated to evaluate its performance. Steam was employed as a working gas, and for a reaction material, calcium-chloride was used, which has a reaction temperature zone permitting safe use and fitting the purpose among other hydrate systems and has high standard enthalpy in hydration. Water was used as a solar heat transferring medium. The system operates under the following principle: a container I is filled with hydrated salt and a container II with water, the two containers being linked with a pipe interposed with a valve; heat is inputted and outputted by performing charging and discharging alternately; and the role of a heat pump is played by deriving from environment the heat of water evaporation in the container II during discharging. The COP must take into account the electric power consumption of the water circulation pump to transfer solar heat. A COP of 0.256 was derived as a result of the experiment. 3 refs., 5 figs.

  3. FY 1998 annual report on the research and development of superhigh-sensitivity photocurrent conversion devices; 1998 nendo chokokando koden henkan soshi ni kansuru kenkyu kaihatsu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Described herein are research and development of superhigh-sensitivity photocurrent conversion devices. The huge photocurrent multiplication effect exhibited by a thin film of organic pigment semiconductor is expected to be applicable to various new devices, e.g., superhigh-sensitivity, intelligent optical sensor families and photocurrent devices. Photocurrent multiplier thin films of perylene is prepared by an ionized cluster beam method, to evaluate their structures and photocurrent characteristics as the basic knowledge for controlling their characteristics by the ion engineering procedures. Photocurrent multiplier thin films of new, two-layer structure are developed, and improvement and stabilization of their characteristics are studied. Increasing sensing sensitivity by, e.g., introduction of p-n junction and reducing dark current resulting from the light memory effect are found to be effective to improve the S/N ratio. An organic EL light-emitting layer capable of positive/negative feedback, as one of the elementary techniques for realizing intelligent devices, is made on a trial basis and evaluated for its characteristics, and studied for its application to photocurrent multiplier thin films. Functional devices in which the arithmetic and controlling functions of the thin films are utilized are also studied. (NEDO)

  4. Study on collapse behavior of a square plate subjected to water pressure; Suiatsu wo ukeru kukeiban no atsukai kyodo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Yao, T.; Fujikubo, M.; Mizutani, K. [Hiroshima University, Hiroshima (Japan). Faculty of Engineering

    1996-04-10

    Bottom plates of a hull are subjected to laterally distributing force due to in-plane compression force and water pressure in the ship`s length direction as a result of longitudinal bending in a hogging condition. Because buckling collapse of the hull bottom plates leads directly to longitudinal bending collapse of the hull bottom cross section, the hull bottom plates must have sufficient strength. The present study performs a static elastic large deflection analysis and an elasto-plastic large deflection analysis. It elucidates buckling collapse behavior of a square plate subjected to water pressure and in-plane compression load, and considers limits in application of conventional approximation analysis methods. In the case of a water pressure action, deflection components growing in excess of the buckling load do not necessarily correspond to buckling modes of the case where no water pressure is acting upon. Conventional approximation analysis methods may not be able often to pursue actual buckling phenomena. According the result of an analysis on hull bottom panels of an actual ship, the ultimate strength decreases when the water pressure is large. Compression force in the lateral direction as a result of water pressure acting on ship`s sides affected very little the ultimate strength. 3 refs., 7 figs.

  5. Investigation on behavior of bacteria in reservoir for microbial enhanced oil recovery; Biseibutsuho (MEOR) no tameno yusonai saikin katsudo ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    Fujiwara, K.; Tanaka, S.; Otsuka, M.; Nakaya, K. [Kansai Research Institute, Kyoto (Japan). Lifescience Research Center; Maezumi, S.; Yazawa, N. [Japan National Oil Corp., Tokyo (Japan). Technology Research Center; Hong, C.; Chida, T.; Enomoto, H. [Tohoku University, Miyagi (Japan). Graduate School of Engineering

    2000-07-01

    Behavior of bacteria activated in reservoir though molasses-injection-tests, was investigated using the restriction fragment length polymorphism analysis with the polymerase chain reaction (PCR-RFLP) method, for elucidating potential bacteria to suppress in situ growth of microbes to be injected into the reservoir in the microbial enhanced oil recovery (MEOR) process. As a result, some bacteria belonging to Enterobacteriaceae species or their close relative species were grown predominantly in the reservoir, among bacteria inhibiting in the ground-water. The foregoing indicates that behavior of these bacteria in reservoir must be taken into consideration when giving a full account of behavior of microbes to be injected into the reservoir to put the MEOR process into operation. Potential proliferation using molasses to activate those bacteria was also estimated on the laboratory tests, to clarify the growth of microbes to be injected into the reservoir to operate the MEOR process. In consequence, it became clear that these bacteria have a potential growth exceeding 10{sup 8} CFU/ml, utilizing molasses. These facts indicated that microbes to be injected into the reservoir at the MEOR field tests are necessary to grow more excellently than bacteria inhabiting in the ground-water. In addition, as flow, the injection fluid is influenced by reservoir heterogeneity caused by injection of molasses, it was inferred that microbes to be injected into the reservoir at the MEOR field process are also necessary to grow more remarkably than bacteria inhabiting in the reservoir brine at high permeability zones and bacteria inhabiting in the reservoir rock. Furthermore, the results of the functional testing for MEOR conducted in the presence of bacteria activated through molasses-injection-tests indicated the importance of effective use of microbes to be injected, taking into account the characteristics of the reservoir and function for MEOR of those microbes. (author)

  6. FY 1996 annual report of investigation on biological fixation of carbon dioxide. 2; 1996 nendo seibutsuteki CO2 kotei ni kansuru chosa hokokusho. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Various kinds of biological fixation processes of CO2 were evaluated from the various viewpoints. Afforestation of tropical and temperate areas, greening of desert, biomass energy production in these areas by energy plantation, coastal mangrove plantation, fertilization with nitrogen and phosphate to outer ocean and coastal, upwelling zone fertilization with iron, and coral reef expansion combined with OTEC (ocean thermal energy conversion) were comparatively investigated as the selected measures. As a result, the cost of CO2 fixation by cultivation of sea weed and plankton was much higher than that of afforestation. The iron fertilization method which was considered to be one of the high CO2 reduction potentials might be economical. However, its effect could not be quantitatively evaluated. The afforestation of tropical and temperate areas seemed to be most feasible in a short term from the viewpoints of economy and environment. It was suggested that the establishment of a systematic water management technology could make greening and afforestation of desert. 76 refs., 27 figs., 28 tabs.

  7. Investigational research on CO2 isolation technology in fiscal 1995; 1995 nendo nisanka tanso no kakuri gijutsu ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The paper studied present technical subjects and future study subjects of the CO2 isolation technology in order to clarify technical and social problems and the developmental subjects of the CO2 isolation technology and related technologies for separating/concentrating CO2 emitted in relation to quantity consumption of fossil fuel and storing it in ocean or underground. Main items for the study were: (1) investigational study of the technology of CO2 ocean storage, (2) investigational study of environmental effect assessment in storing CO2 in ocean, (3) investigational study of the technology of CO2 ocean storage, etc. Technologies required for the ocean isolation were arranged such as CO2 storage, injection, dispersion technique, CO2 behavior simulation, and the developmental subjects were extracted. Further, in the deep-sea bottom storage method, a simulation to calculate the range of PH effects was conducted presuming the specified amount of CO2 and applying known physical values, and evaluation of the CO2 ocean discharge/solution method was made. A method was also studied for experiments on water bacteria and benthos. 127 refs., 102 figs., 81 tabs.

  8. Fiscal 1998 research report on new recycling technology for waste lube oil; 1998 nendo haijunkatsuyu no recycle no shingijutsu ni kansuru chosa kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    For effective use of resources and environment conservation, R and D was made on recycling technology for recovered waste lube oil. On the R and D on removal of ash and chlorine contents in waste lube oil, iron oxide-carbon composite was found as adsorbent which can reduce ash content and chlorine content to 0.02wt% and 5ppm, respectively. On the research on the applicability of waste lube oil as melting furnace fuel for bottom ash and fly ash, as the melting experiment result at a real plant, the recycled heavy oil obtained by simple treatment of waste lube oil showed dioxin decomposition rates more than 99.9% and dioxin concentrations less than 0.6ngTEQ/Nm{sup 3} in waste gas, achieving the targets regulated by Air Pollution Control Law. The applicability of waste lube oil as fuel was thus confirmed. On the research on the applicability of waste lube oil as fuel for power generation in oil refineries, both waste lube oil alone and mixed oil with residual oil were available as gasification fuel through design considering ash content removal, and reasonable selection of equipment and piping materials considering chlorine. (NEDO)

  9. Transient heat transfer characteristics of mist cooling from horizontal upward-facing surface. Suihei uemuki heimen kei deno hiteijo mist reikyaku netsu dentatsu tokusei ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Okubo, H.; Nishio, S. (Univ. of Tokyo, Tokyo (Japan). Inst. of Industrial Science)

    1991-07-25

    As mist cooling comprising of cooling heated surface by colliding with a group of pulverized droplet, one of sprayed cooling, is known to show heat transfer feature expressed by letter N curve like boiling one, it represents another complex phenomenone by adding some other new factors such as behavior of the collided particles, effect of air flow and others except boiling phenomenone. On the other hand, it is required to control the cooling ability with high accuracy in the field of heat treatment of steel widely applied such mist cooling. In this paper, an effect of unsteadiness of heat transfer face was examined in a plain system upper-faced holizontally by using the heat transfer face having different thickness. All specimens used in this experiment had 15mm in diameter of the heat transfer face, which were made of silver in seven kinds of thickness, and of SUS and quartz glass in four. Consequently, some informations were obtained that in unsteady region heat transfer coefficients of high temperature region could be well related with heat capacity of the face. 22 refs., 9 figs., 1 tab.

  10. Application of photovoltaic generating system to electric power in large ship; Taiyoko hatsuden system no ogata senpaku eno oyo ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Katagi, T.; Ogawa, S.; Nishikawa, E.; Hashimoto, T. [Kobe University of Mercantile Marine, Kobe (Japan); Ishida, K.

    1996-10-27

    This paper describes the design of electric power system in a ship with photovoltaic power generating system, to examine applicability of the photovoltaic power generating system to the inboard power source. It also discusses effectiveness of the system for sea environment. At first, the actual route of a car carrier, meteorological data, and quantity of power consumption were picked up from the deck logbook and engine logbook. Then, the installation area of photovoltaic arrays, the quantity of photovoltaic power generation derived from the quantity of solar radiation, and the capacities of batteries and inverters were calculated, to design the electric power system in the ship with photovoltaic power generation system. Moreover, the NOx and SOx emissions were compared between the present power system and the usual power system using diesel power generator, to discuss the effectiveness of the present system for sea environment. Consequently, it was found that the emission of NOx was reduced by about 33% and the emission of SOx was reduced by about 28% compared to the usual power system. The effectiveness for sea environment was confirmed. 9 refs., 5 figs., 4 tabs.

  11. Performance analysis on utilization of sky radiation cooling energy for space cooling. Part 2; Hosha reikyaku riyo reibo system ni kansuru kenkyu. 2

    Energy Technology Data Exchange (ETDEWEB)

    Marushima, S.; Saito, T. [Tohoku University, Sendai (Japan)

    1996-10-27

    Studies have been made about a heat accumulation tank type cooling system making use of radiation cooling that is a kind of natural energy. The daily operating cycle of the cooling system is described below. A heat pump air conditioner performs cooling during the daytime and the exhaust heat is stored in a latent heat accumulation tank; the heat is then used for the bath and tapwater in the evening; at night radiation cooling is utilized to remove the heat remnant in the tank for the solidification of the phase change material (PCM); the solidified PCM serves as the cold heat source for the heat pump air conditioner to perform cooling. The new system decelerates urban area warming because it emits the cooler-generated waste heat not into the atmosphere but into space taking advantage of radiation cooling. Again, the cooler-generated waste heat may be utilized for energy saving and power levelling. For the examination of nighttime radiation cooling characteristics, CaCl2-5H2O and Na2HPO4-12H2O were tested as the PCM. Water was used as the heating medium. In the case of a PCM high in latent heat capacity, some work has to be done for insuring sufficient heat exchange for it by, for instance, rendering the flow rate low. The coefficient of performance of the system discussed here is three times higher than that of the air-cooled type heat pump system. 8 refs., 5 figs., 4 tabs.

  12. Features of vertical axis wind turbine and development of airfoils sections; Chokusen yokugata suichoku jiku fusha no tokucho to yokugata ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Seki, K.; Shimizu, Y.; Yasui, T. [Tokai University, Tokyo (Japan); Nakayama, H. [Oriental Kiden Company, Osaka (Japan)

    1996-10-27

    Features of a straight wing type vertical axis wind turbine (VAW) and its airfoil sections were studied. The wind turbine in which various aerodynamic work components are mounted on the rotation axis normal to the ground surface is named VAW. Like the airfoil section of aircraft, in lift type VAW, wind turbines were driven by lift 70-90 times as large as drag in some cases. Features of the VAW airfoil section which is a straight wing in plan and a fixed pitch wing (with a fixed angle to a blade support arm) in cross section, and those of wind turbines were studied. Some factors affecting the features, work principle and performance of VAW were clarified. On airfoil sections, products of each weight function and each corresponding aerodynamic factor (lift, drag and pitching moment factors) were plotted on an attack angle ({alpha}) axis. From the conditions for increasing the total sum of areas drawn by the products on the {alpha} axis, various characteristics required for airfoil sections were clarified. Such characteristics nearly agreed between an airfoil section for favorable starting characteristics and that for high efficiency. 3 refs., 7 figs.

  13. Study on the detached house plan using of a maximum natural energy. Part 1; Shizen energy fukugo riyo no keikaku ni kansuru kenkyu. 1

    Energy Technology Data Exchange (ETDEWEB)

    Wada, I.; Mino, M.; Miyata, T.; Okawa, M. [Nihon University, Tokyo (Japan)

    1996-10-27

    The geographical position or environment is set on the assumption that the natural energy of a detached house is used in a hybrid state. Moreover, the energy consumption of the house and the natural energy supply obtained from the geographical position were compared and investigated. As a result, the energy consumption is 10,617 kWh, and the energy supply is 8,236 kWh. About 78% of the whole consumption can be theoretically made from natural energy. The energy supply is calculated on the low side during prediction. Therefore, an increase in the energy supply is expected by installing a solar collector based on solar energy, expanding the solar panel area, and increasing the number of wind mills. However, this energy is partially lost via an inverter while it is supplied to the general domestic equipment. At the six main points in Tokyo and its districts, the adaptability of natural energy used based on the regional characteristics is investigated presently and the installation of a system is examined. 13 refs., 2 figs., 6 tabs.

  14. Study on the living environment of semi-underground room with attached green house; Fusetsu onshitsu no aru hanchikashitsu no kyojusei ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, T.; Tsukayama, N. [Ochanomizu University, Tokyo (Japan)

    1996-10-27

    In response to demand for the expansion of living space, the living environment of semi-underground room has been investigated. An attached green house (passive solar house) is adjacent to the semi-underground room. This is reinforced concrete construction, having flat type solar collector on its roof and lighting window in its north side. It does not have artificial air conditioners. Based on the measurements of daylight factor, artificial lighting is not required at the window in the daytime, but it is desirable to use daylight and artificial lighting together at the center. The performance of sound insulation depends on the high performance soundproof sash level. There is less daily temperature variation due to its large heat capacity, and less yearly temperature variation than the outside. By shielding the solar radiation, the insolation in the green house in summer can be restricted in the same as in winter. The insolation can be easily received in winter due to its large vertical intensity of solar radiation. The green house in the south side is useful for improving the living environment of semi-underground room. The temperature rise in the semi-underground room can be restricted by opening window in summer. It is desirable for the comfortable living to use artificial cooling to reduce the daytime temperature by 3 to 4{degree}C. In winter, it is comfortable to heat by 4 to 5{degree}C. 2 refs., 7 figs.

  15. Fiscal 1997 survey report. Survey on the innovative well drilling technology; 1997 nendo chosa hokokusho. Kakushinteki kosei kussaku gijutsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In the geothermal drilling, reduction of the cost of well drilling is an important subject for technical development. The geothermal resource development tends to be made at higher temperatures and at deeper wells. In the present drilling technology, the cost is rising with the exponentially increasing depth and temperature, and there is also occurring the technical limit. Accordingly, the survey clarified the limit of the present drilling technology/cost to point out the research trend of the drilling technology as substitute for the present one, possibilities of the introduction, and the R and D target and subjects. As to latest drilling systems abroad and in Japan, the following were surveyed to study and extract promising technologies and systems: improvement/application of drilling equipment/materials (enhancement of heat resistance of the main drilling equipment, etc., cooling effects of top drive, heat resistance verification of MWD tools, PDM, tricone bits, multi-stage cementing tools, etc.), heightening of drilling rates, trend surveys of slim hole drilling, control drilling, well maintenance/workover, and well design technology. 68 refs., 73 figs., 40 tabs.

  16. Integrated interpretation of AE clusters and fracture system in Hijiori HDR artificial reservoir; Hijiori koon gantai jinko choryuso no AE cluster to kiretsu system ni kansuru togoteki kaishaku

    Energy Technology Data Exchange (ETDEWEB)

    Tezuka, K. [Japan Petroleum Exploration Corp., Tokyo (Japan); Niitsuma, H. [Tohoku University, Sendai (Japan)

    1997-05-27

    With regard to a fracture system in the Hijiori hot dry rock artificial reservoir, an attempt was made on an interpretation which integrates different data. Major factors that characterize development and performance of an artificial reservoir are composed of a fracture system in rocks, which acts as circulating water paths, a heat exchange face and a reservoir space. The system relates not only with crack density distribution, but also with cracks activated by water pressure fracturing, cracks generating acoustic emission (AE), and cracks working as major flow paths, all of which are characterized by having respective behaviors and roles. Characteristics are shown on AE cluster distribution, crack distribution, production zone and estimated stress fields. Mutual relationship among these elements was discussed based on the Coulomb`s theory. The most important paths are characterized by distribution of slippery cracks. Directions and appearance frequencies of the slippery cracks affect strongly directionality of the paths, which are governed by distribution of the cracks (weak face) and stress field. Among the slippery cracks, cracks that generate AE are cracks that release large energy when a slip occurs. Evaluation on slippery crack distribution is important. 7 refs., 8 figs.

  17. Study on data transmission method for power line maintenance information system using OPGW. OPGW riyo sodensen hoshu joho system no denso hoshiki ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Kanemaru, K.; Toyota, S. (Hitachi Cable, Ltd., Tokyo (Japan))

    1994-02-20

    Composite fiber-optic overhead ground wires (OPGWs) installed to the major power transmission lines are applied as the information transmission routs with large capacity. An effective system for the power line maintenance operation is able to be set up by using said OPGWs to collect and transmit various kinds of maintenance information on the power lines. However, since it is necessary for the whole equipment to meet the highest transmitting speed required by the system if a single transmission method is applied throughout the power lines for transmitting the maintenance information, the system loses its economy as a whole. In this paper, for the purpose of transmitting effectively the various maintenance information in power line maintenance information system using OPGWs, and considering the required transmission period as well as the types of the data occurrence, an optic fiber transmission system constituted hierarchically and composed of high-speed trunk line and low-speed local line is suggested. Especially, regarding the low-speed local lines, random transmission method shows the superior properties in the transmission efficiency and low power-consumption compared with the cyclic transmission method. 9 refs., 9 figs., 4 tabs.

  18. Technological development for super-high efficiency solar cells. Survey on the commercialization on analysis; Chokokoritsu taiyo denchi no gijutsu kaihatsu. Jitsuyoka kaiseki ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the survey results on analysis of super-high efficiency solar cells for practical use in fiscal 1994. (1) On the survey on crystalline compound solar cells, it was pointed out that the present study target is III-V compound semiconductor solar cell, and efficiencies of 36-39% are theoretically expected by use of two-junction cells. (2) On structure of super-high efficiency solar cells of 40%, selection of upper and lower cell materials for multi-junction cells, high-efficiency tandem Si solar cells, and the merit and possibility of light collection operation were surveyed, and their issues were discussed. (3) On physical properties of mixed crystalline semiconductors and characteristic evaluation of solar cells, impurities, trap center, minority carrier life, and applicability of supper lattice structure to high-efficiency solar cells were surveyed. (4) On fabrication technology of compound semiconductor solar cells, various problems of and approaches to electrode formation and antireflection film technologies, the meaning and issues of thin film substrate technology and continuous process, trial calculation of costs, safety, and resource problem were surveyed.

  19. Research and development of system to utilize photovoltaic energy. Survey on the specific purpose modules; Taiyoko hatsuden riyo system no kenkyu kaihatsu. Taiyoto module ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Tatsuta, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    This paper reports the survey results on the specific purpose modules for photovoltaic power generation in fiscal 1994. (1) On the feasibility survey on new application fields, it was clarified that photovoltaic power generation is applicable to extensive areas such as farmland, road, railway and public facility as latent demand sites. (2) On the optimum modules for various specific purposes, the structure, production method, cost estimation and issues of various modules were studied for desert, wasteland, coast, ocean, river, embankment, railway, road, mobile facility and arcade. (3) On the survey on new materials and material development, various conventional materials and materials promising for required performance were surveyed for every application. (4) On the survey on technology trends, the survey members participated in the first international photovoltaic energy conversion conference and the photovoltaic power generation workshop, while the members held the 1st-5th specific purpose module subcommittees. 1 tab.

  20. Topographic effects on SP anomaly caused subsurface fluid flow. Numerical approach; Chikasui ryudo ni tomonau shizen den`i ijo ni taisuru chikei no koka. Suchi modeling ni yoru approach

    Energy Technology Data Exchange (ETDEWEB)

    Yasukawa, K. [Geological Survey of Japan, Tsukuba (Japan); Mogi, T. [Kyushu University, Fukuoka (Japan). Faculty of Engineering

    1998-02-01

    Self-Potential (SP) anomaly at the ground surface caused by subsurface fluid flow is numerically calculated for two-dimensional models using a simulation code PTSP to investigate the topographic effects on the SP profile. The result shows that the negative SP anomaly generally seen in higher elevation can be explained as a result of topographic effects on the near surface fluid flow system for cases of homogeneous earth. However, heterogeneous perme