WorldWideScience

Sample records for mizu kankyo ni

  1. Effect of Water Environment on Subcritical Crack Growth of Machinable Ceramics; Kaisakusei seramikkusu no kiretsu shinten tokusei ni oyobosu mizu kankyo no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Ikeda, K.; Kaizu, K.; Inotani, T. [Miyazaki Univ., Miyazaki (Japan); Yoshikawa, A.; Adachi, K.; Igaki, H. [Osaka Sangyo Univ., Osaka (Japan)

    1997-06-15

    The fatigue behavior of ceramics has been discussed on the basis of the relation between stress intensity facter (KI) and crack velocity (V). In this paper, the effect of environment on the relation between KI and V was studied on machinable ceramics (mica glass ceramics) and two kinds of glass ceramics with different grain sizes. The double torsion (DT) technique was used for the determination of the KI-V characteristics under different environments of air and ion-exchanged water. The characteristics of acoustic emission (AE) during stress corrosion cracking of mica glass ceramics was also examined. In water environment, the region II in the KI-V curve, in which crack velocity varies slowly with KI, disappeared. From this experimental fact, it was considered that at high KI, the crack velocity is encouraged by diffusion of the corrosive species to the crack and thus depended on the amount of water. SEM farc tography revealed that mica single crystals in the material caused crack arrest and deflection to occur. It is also found that AE event rate is quantitatively related to the crack velocity. AE measurement can be used in studying the crack propagation behavior of mica glass ceramics. 11 refs., 12 figs., 3 tabs.

  2. FY 2000 project on the research cooperation for the environmental response type water resource effective utilization system; 2000 nendo kenkyu kyoryoku jigyo. Kankyo taiogata mizu shigen yuko riyo system ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of prevention of water pollution, stable water supply in the Philippines, etc., developmental study was made of a waste water treatment/water recycling system, and the FY 2000 results were summed up. In the operational study of Pilot Plant 1, for the waste water in the papermaking process of used paper recycling plant, development was studied of a waste water treatment/water recycling system. There occurred problems on minuteness, outflow, etc. of anaerobic granules, but those were caused by malfunction of SS removal equipment at plant side. The problems were solved by increasing flocculation/precipitation facilities. As to Pilot Plant 2 of which the R and D are planned to be started in April 2001, the food processing plant was surveyed for study, and SYSCORE was selected. Relating to the waste water treatment test of Pilot Plant 2, researchers of the Industrial Technology Development Institute (ITDI) of the Philippines conducted it under the guidance of the experimental data analysis. Besides, the paper carried out the training for technology spread/acceptance, technology spread seminar, support study in Japan, etc. (NEDO)

  3. Trend survey of the global environment adaptation type industrial technology. Chikyu kankyo tekiogata sangyo gijutsu doko chosa. ; Chikyu kankyo kanren kenkyu doko no chosa (nisanka tanso no kankyo fuka teigensaku ni kansuru chosa kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    1992-03-01

    The paper studies the measures for reduction of environmental load of CO2 from the standpoint of chemical technology. As for methanol synthesis from CO2, accelerating of the reaction using Cu base compound catalyst is reported. Also, CO2 is methanated at high speed by low temperature waste heat using Ni-La2O3-Ru catalyst. Discussions are given on the subject for development of catalyst reaction relating to hydrogen production technology by methane reforming reaction using steam or CO2. Synthesis of polymetric materials by use of CO2 is also described. The paper mentions that it is indispensable to design high-function electrode and elucidate the reaction mechanism of electrochemical CO2 reduction for electrochemical and photochemical CO2 reduction measures. Moreover, in case of using solar energy, it is required to study photovoltaic excitation process in semiconductor electrode/ electrolyte solution interface. For production of hydrogen from CO2 by photosynthetic organisms and solar energy, the problem is control of inhibiting effect of oxygen combinedly produced. Described are production of polyhydroxy butyric acid and biodegradable polymer from CO2 and hydrogen by bacteria, and CO2 fixation imitating the enzyme reaction. 267 refs., 79 figs., 32 tabs.

  4. mizuRoute version 1: A river network routing tool for a continental domain water resources applications

    Science.gov (United States)

    Mizukami, Naoki; Clark, Martyn P.; Sampson, Kevin; Nijssen, Bart; Mao, Yixin; McMillan, Hilary; Viger, Roland; Markstrom, Steven; Hay, Lauren E.; Woods, Ross; Arnold, Jeffrey R.; Brekke, Levi D.

    2016-01-01

    This paper describes the first version of a stand-alone runoff routing tool, mizuRoute. The mizuRoute tool post-processes runoff outputs from any distributed hydrologic model or land surface model to produce spatially distributed streamflow at various spatial scales from headwater basins to continental-wide river systems. The tool can utilize both traditional grid-based river network and vector-based river network data. Both types of river network include river segment lines and the associated drainage basin polygons, but the vector-based river network can represent finer-scale river lines than the grid-based network. Streamflow estimates at any desired location in the river network can be easily extracted from the output of mizuRoute. The routing process is simulated as two separate steps. First, hillslope routing is performed with a gamma-distribution-based unit-hydrograph to transport runoff from a hillslope to a catchment outlet. The second step is river channel routing, which is performed with one of two routing scheme options: (1) a kinematic wave tracking (KWT) routing procedure; and (2) an impulse response function – unit-hydrograph (IRF-UH) routing procedure. The mizuRoute tool also includes scripts (python, NetCDF operators) to pre-process spatial river network data. This paper demonstrates mizuRoute's capabilities to produce spatially distributed streamflow simulations based on river networks from the United States Geological Survey (USGS) Geospatial Fabric (GF) data set in which over 54 000 river segments and their contributing areas are mapped across the contiguous United States (CONUS). A brief analysis of model parameter sensitivity is also provided. The mizuRoute tool can assist model-based water resources assessments including studies of the impacts of climate change on streamflow.

  5. Trend survey of the global environment adaptation type industrial technology. Trend survey of global environment related studies (researches on measureds for reduction of environmental load of CO2); Chikyu kankyo tekiogata sangyo gijutsu doko chosa. Chikyu kankyo kanren kenkyu doko no chosa (nisanka tanso no kankyo fuka teigensaku ni kansuru chosa kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    1992-03-01

    The paper studies the measures for reduction of environmental load of CO2 from the standpoint of chemical technology. As for methanol synthesis from CO2, accelerating of the reaction using Cu base compound catalyst is reported. Also, CO2 is methanated at high speed by low temperature waste heat using Ni-La2O3-Ru catalyst. Discussions are given on the subject for development of catalyst reaction relating to hydrogen production technology by methane reforming reaction using steam or CO2. Synthesis of polymetric materials by use of CO2 is also described. The paper mentions that it is indispensable to design high-function electrode and elucidate the reaction mechanism of electrochemical CO2 reduction for electrochemical and photochemical CO2 reduction measures. Moreover, in case of using solar energy, it is required to study photovoltaic excitation process in semiconductor electrode/ electrolyte solution interface. For production of hydrogen from CO2 by photosynthetic organisms and solar energy, the problem is control of inhibiting effect of oxygen combinedly produced. Described are production of polyhydroxy butyric acid and biodegradable polymer from CO2 and hydrogen by bacteria, and CO2 fixation imitating the enzyme reaction. 267 refs., 79 figs., 32 tabs.

  6. Catalytic technology in the energy/environment field. Utilization of catalyst in coal pyrolysis and gasification processes; Energy kankyo bun`ya ni okeru shokubai gijutsu. Sekitan no netsubunkai oyobi gas ka ni okeru shokubai no riyo

    Energy Technology Data Exchange (ETDEWEB)

    Otsuka, Y. [Tohoku University, Institute for Chemical Reaction Science (Japan)

    1998-05-20

    This review article focuses on the utilization of several catalysts during coal pyrolysis and gasification. In situ or off line catalytic upgrading of volatile matters during pyrolysis of low rank coals is carried out in pressurized H2 with different reactors to produce BTX (benzene, toluene and xylene). When NiSO4 and Ni(OH)2 are used in the hydropyrolysis of Australian brown coal using an entrained bed reactor with two separated reaction zones, BTX yield reaches 18-23%. MS-13X zeolite and USY zeolite mixed with Al2O3 are effective for producing BTX with powder-particle fluidized bed and two-stage reactors, respectively. Catalytic gasification is described from a standpoint of direct production of SNG(CH4) from coal and steam. When K2CO3 and Ni are compared for this purpose, Ni catalyst is more suitable at low temperatures of 500-600degC, where CH4 formation is thermodynamically favorable. Fe and Ca catalysts can successfully be prepared from inexpensive raw materials and are rather active for steam gasification at {>=}700degC. The use of upgrading and gasification catalysts is discussed in terms of preparation, performance, life and recovery. 27 refs., 6 figs., 2 tabs.

  7. Design of environment-friendly and next generation-type conversion system for unused carbon resources by developing highly functional materials; Kokino zairyo kaihatsu ni yoru kankyo chowagata jisedai miriyo tanso shigen tenkan system no kochiku

    Energy Technology Data Exchange (ETDEWEB)

    Wakabayashi, K; Morooka, S; Arai, Y [Kyushu University, Fukuoka (Japan). Faculty of Engineering; Sakanishi, K [Kyushu University, Fukuoka (Japan). Institute of Advanced Material Study

    1997-02-01

    Studies are conducted for the development of now-unused kinds of fossil carbon resources, such as low rank coal and heavy gravity crude oil, into higher-value liquid fuel. In the preliminary treatment process, the fossil carbon resources are dried by use of supercritical carbon dioxide, when it is found that the resources are disintegrated and water is desorbed. In a low rank coal liquefaction process using the NiMo/KB (Kefjen Black) catalyst, more than 60% is converted into oil, which rate is improved by use of the dual-temperature liquefaction process. This catalyst may be recovered by separation utilizing specific gravity difference. As a low temperature gasification catalyst, the alkaline carbonate-carried carbon catalyst is very quick at the initial stage of reaction. The perovskite-carried alkaline carbonate catalyst is high in carbon oxidizing/activating efficiency at low temperatures. The silica film deposited on an alumina-coated support tube is excellent in selectivity and speed as a hydrogen separating film, and a carbonized polyimide film as a carbon dioxide separating film. For the supercritical phase adsorption/separation of chemicals not to be distilled easily, the NaY-type zeolite functions effectively. Pd/ZrO2 serving as a carbon monoxide conversion catalyst enables the recovery of more MeOH when Pd grains are smaller in diameter.

  8. Environment purification using microorganisms. Biseibutsu ni yoru kankyo joka

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, H [Asahi Glass Co. Ltd., Tokyo (Japan); Harada, S

    1993-12-01

    Technologies to purify polluted soils vary with kinds of pollutants, spread of pollution, and shapes of water veins. A method is used often that several wells are drilled in a polluted area, and water is circulated between upstream wells and downstream wells, where activities of microorganisms living in that particular environment are utilized to biodegrade the pollutants. This technology is called bioremediation. This paper deals with soil pollution by chemical substances, and describes development of a technology to remove pollution caused by PCB and petroleum which is thought difficult to apply the bioremediation technology among environment purifying technologies using microorganisms. The bioremediation of petroleum pollution assumes petroleum pollution on seashores. Discussions have been given on separation from sea water of petroleum decomposing microorganisms to be used in the bioremediation, and the number of petroleum decomposing bacteria in seas near Japan. As a result, it was made clear that a few kinds of bacteria will suffice for decomposition of main components in a mixture as complex as petroleum. 5 refs., 4 figs.

  9. Stability analyses of urban water supply systems with wastewater reuse; Toshi haisui no junkan riyo ni yoru mizu kyokyu anteika ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, H.; Zhang, S. [Meijo Univ., Nagoya (Japan); Okada, N. [Kyoto Univ., Kyoto (Japan). Disaster Prevention Research Inst.

    1995-10-20

    Wastewater reuse can be considered as a type of water resource development which is expected to improve the aquatic environment, as well as the stability and reliability of municipal water supply systems. To this extent, wastewater reuse has been taken into account in the planning of water supply systems in several Japanese cities. However, to date the effect of wastewater reuse on water supply system stabilization has not been discussed quantitatively, and the relation between waster water reuse rate and water supply system stability has not been analyzed. In this study, a stochastic model has been presented to evaluate the stability of water supply systems with optimal wastewater reuse rate. Some theoretical analyses and numerical studies were performed, and all of the results have shown that the model is reliable for not only basic studies on water supply system stability, but also for practical use as well. 5 refs., 5 figs., 3 tabs.

  10. Global environmental problems in the electric industry. Denki jigyo ni okeru chikyu kankyo mondai ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Sugi, T [Tokyo Electric Power Co., Inc. (Japan)

    1992-09-30

    Since the electric industry has grappled with a prevention of the environmental pollution such as the air pollution and water contamination as a forerunner in case of construction and operation of the power facilities, and at the same time has conducted actively the environmental conservation countermeasures, it has consequently achieved the environmental conservation level as a top level in the world. On the other hand, as for the emission quantity of CO2 relating to the earth warming, the power field occupies about one fourth of total Japan. Therefore the electric industry should aim at the electric energy supply considering the influence on the environment, such as the power supply structure to restrain CO2 emission as less as possible, higher efficiency of equipments, higher efficiency of energy utilization by using the unused energy and so forth. In addition to it, the consumer side should aim at the social structure with a recycle type such as saving resources and saving energy, and aim at changeover of life style. It is hoped to conduct the overall measure including the items mentioned above. In this report, the recent trend of earth enviromental problems, grappling with the environmental problems as a forerunner such as the prevention measure of air pollution in the thermal power plant, etc., and the correspondence to the earth warming problems are outlined. 11 refs., 9 figs., 3 tabs.

  11. Fiscal 1999 achievement report on the venture business assisting type regional consortium - Minor business creation base type. Development of environmentally friendly chromium-free plating technology and research on its practical application; 1999 nendo chiiki consortium kenkyu kaihatsu jigyo seika hokokusho. Kankyo ni yasashii kuromu daitai mekki gijutsu kaihatsu to sono jitsuyoka kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    In this research, the seeds provided by Technology Research Institute of Osaka Prefecture and Nomura Plating Co., Ltd., relative to their plating processes using ion exchange membranes and metal anodes are utilized. Efforts are made to prolong the bathing life of the Ni-W alloy plating solution, to put the plating bath in an enclosure, to develop a chromium-free plating technology wherewith bating life is longer, environmental impact is smaller, and resistance to corrosion is higher, and experiments and tests are conducted for industrialization and for the practical application of the developed technologies. At Technology Research Institute of Osaka Prefecture, electrolytic Ni-W alloy plating was taken up. An insoluble anode separated from the plating solution by a cation exchange membrane and plural metal anodes were brought into a new process and, into the same, novel technologies were further introduced, which were a metal ion supply method in which the distribution of current to 3 anodes was regulated and the employment of a sacrificial anode decomposition agent. The new process was investigated for its validity and difficulties. Furthermore, Ni-W-P alloy plating was studied and a mirror-like Ni-W-P alloy plate was developed in a phosphorous acid added bath without detriment to the non-waste solution plating process, and the plate exhibited high corrosion resistance in a CASS (copper-accelerated acetic acid salt spray) test. (NEDO)

  12. Explosive treatment of Illinois No.6 coal with a mixed solvent of water and cyclohexanol; Mizu-cyclohexanol kongo yozai ni yoru Illinois tan no bakusai shori

    Energy Technology Data Exchange (ETDEWEB)

    Hashimoto, T.; Takada, H.; Asami, K.; Yano, M. [Osaka City University, Osaka (Japan). Faculty of Engineering

    1996-10-28

    Coal was treated at high temperature under high pressure in the binary system mixed solvent of water and organic solvent, and the solvent treated coal was liquefied. When the treated coal was treated again by the explosive method in which high temperature and pressure were released immediately, the oil yield was higher than that by the normal method in which high temperature and pressure were reduced gradually to room temperature and atmospheric pressure. In this study, an explosive treatment unit with increased scale of sample amount was newly fabricated. Illinois No.6 coal was treated by the explosive method in a mixed solvent of water and cyclohexanol using this unit. Changes in shape on the surface, specific surface area, and functional groups were analyzed. The explosively treated coal contained more amount of low boiling point components than the normally treated coal. It was suggested that the oil yield of explosively treated coal increased due to the liquefaction of these components during the successive hydrogenation process. For the explosively treated coal, micro pores were fractured by the rapid change in the volume of solvent molecules, and the specific surface area was smaller than that of the normally treated coal. When the treatment temperature was increased from 300{degree}C to 350{degree}C, specific surface areas of both the treated coals increased. 2 refs., 3 figs., 2 tabs.

  13. Conductivity Measurements of Alkali Metal Thiocyanates in Water-Methanol Mixtures; Mizu-metanoru kongoyoubai ni okeru arukari kinzoku chioshiansan`en no denki dendodo sokutei

    Energy Technology Data Exchange (ETDEWEB)

    Kubota, Eiji.; Horimoto, Sanaki. [Shinshu University, Nagano (Japan). Faculty of Science

    1999-03-10

    The counductivity of several alkali nmetal thiocyanates in water-methanol mixtures was measured at 25degreeC. the data were analyzed using Lee-Wheaton theory for symmetrical electroyers to cbtain ion association constant, K{sub A}, limiting molar sonductivity, {Lambda}{sub 0}, and limiting ionic molar conductivity, lamnda{sub 0}{+-}. In all the solvent systems, calculated{lambda}{sub 0}{sup +} values of the alkali metal ions increase in the order L{sub i}{sup +}

  14. Heat pump using dual heat sources of air and water. Performance in cooling mode; Mizu kuki ryonetsugen heat pump no kenkyu. Reibo unten ni okeru seino

    Energy Technology Data Exchange (ETDEWEB)

    Ito, S; Miura, N [Kanagawa Institute of Technology, Kanagawa (Japan); Uchikawa, Y [Kubota Corp., Osaka (Japan)

    1997-11-25

    When a heat pump is used for cooling purpose, it is possible to utilize different kinds of waste water as high-heat sources. However, these heat sources would have their temperatures vary with seasons and time in a day. Therefore, a discussion was given on performance of a heat pump when water and air heat sources are used for condensers during cooling operation independently, in series and in parallel, respectively. The air condenser shows an equivalent COP as compared with the water condenser when air temperature is lower by about 8 degC than water temperature. At the same heat source temperature, the COP for the water condenser indicated a value higher by about 0.6 than the case of the air condenser. A method to use condensers in parallel experiences little contribution from the air heat source, and performance of the heat pump decreases below the case of using the water heat source independently when the air heat source temperature becomes higher than that of the water heat source. In the case of series use in which a water condenser is installed in front and an air condenser in rear, its effect is exhibited when temperature in the air heat source is lower than that in the water heat source. Better performance was shown than in operating the water heat source independently. 2 refs., 9 figs.

  15. Evaluation report on research and development of 'the comprehensive water recycling and utilization systems'; 'Mizu sogo saisei riyo system' no kenkyu kaihatsu ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-08-01

    This research and development project is aimed at treatment of sewage, industrial waste water and the like at lower cost for reutilization, while efficiently producing methane or the like by the systems annexed to the water treatment systems with high-concentration bio-reactor systems incorporating separation membranes. The waste water types studied to be treated by these systems include sewage discharged in large quantities and waste water containing oil/fat and protein (low-concentration waste water), and starch-, alcohol and paper/pulp-containing waste water, and excrements (medium-concentration waste water). The project has found the optimum systems, by adequately configuring the separation membrane modules, and combining dissolution of suspended solid with methane fermentation reactors for selective treatment of organic substances; improved efficiencies of removing organic substances and producing methane by fermentation, and realized reduction in quantities of discharged sludge; and thereby established the bases for the new waste water treatment techniques. The reactor systems developed for water treatment are those based on biological removal of nitrogen. They greatly reduce treatment time to produce treated water of high quality. For treatment of sludge, the techniques have been developed to convert sludge into oil. These results are well applicable to various areas, e.g., sewage treatment, and food and pulp industries. (NEDO)

  16. Laboratory study on streaming potential for exploring underground water flow; Shitsunai jikken ni yoru ryudo den`i wo mochiita mizu michi tansa no kanosei no kento

    Energy Technology Data Exchange (ETDEWEB)

    Sato, H; Shima, H [Oyo Corp., Tokyo (Japan)

    1997-05-27

    To investigate a possibility of exploration of underground water flow as well as to grasp the underground fluid flow by measuring streaming potential at the ground surface, some experiments were conducted using a model unit by considering the difference of permeability. For this experimental unit, water is driven by adding head difference between the polyethylene vessel filled with water and the experimental water tank. The size of water tank is 350{times}160 mm with a height of 160 mm. Twenty platinum electrodes are set on the cover of water tank. Toyoura standard sand and Kanto loam were used for the experiments. For the experiments, fluid was injected in various combined models by considering the permeability, to measure the streaming potential. As a result, it was explained by the streaming potential that the fluid flows in a form of laminar flow in the experimental water tank, and that the movement of fluid in the Kanto loam is quite slow. It was also confirmed that the streaming potential method is an effective technique for grasping the movement of fluid. 3 refs., 8 figs.

  17. Vapor-liquid equilibrium ratio of trace furfural in water+1-butanol system; Mizu+1-butanorukei ni okeru biryo no furufuraru no kieki heikohi

    Energy Technology Data Exchange (ETDEWEB)

    Ikari, A.; Hatate, Y.; Aikou, R. [Kagoshima Univ. (Japan). Faculty of Engineering

    1997-11-01

    Vapor-liquid equilibria of a water + 1-butanol system containing a trace amount of furfural were measured at atmospheric pressure by use of a Iino-type still for systems of limited miscibility. Vapor-liquid compositions for the major components (water and 1-butanol) are shown to be nearly coincident with those of the binary system. In the partially miscible region, the vapor-liquid equilibrium ratios of the trace component (furfural) at bubble point were found to be 2.5 and 0.46. Consequently, the partition coefficient of the trace component between the two liquid phases is 5.4. The equilibrium ratio curve of the trace component is presented, in which the calculated curve within the partially miscible region is shown to be coincident with the experimental data. 5 refs., 3 figs., 1 tab.

  18. Recycling technologies for sewarage systems. Reuse of water, heat, and sludge in Tokyo; Gesuido wo meguru risaikuru gijutsu. Tokyoto ni okeru mizu/netsu/odei no sairiyo

    Energy Technology Data Exchange (ETDEWEB)

    Mino, T. [Tokyo Univ. (Japan)

    1996-03-10

    The recycling technology employed in Tokyo were reported. It will be useful for developing and introducing the recycling technology for water, heat, and sludge in the sewage treatment. Among various kinds of recycling technology, one of the most peculiar technology is the district heating and cooling system using the heat of sewage. The Japan`s first practical plant which uses the untreated sewage as the heat source was installed and is now operating in Korakuen pump station. In the station, the energy contained in the sewage is recovered by a heat exchanger. The heat pump produces warm water of 45{degree}C and cold water of 7{degree}C as well. Both are supplied to the area near by through the heat source supply pipeline. The Nanbu sludge plant has a sludge-resourcing plant, in which the sludge is converted into fuel, metro-bricks, and light-weight granules, as well as a conventional sludge treatment plant carrying out the concentration, dehydration, and incineration of sludge. The Ochiai sewage treatment plant reuses water after cleaning. The clean water is used as for the service water in addition to being discharged into the river stream. 7 figs., 1 tab.

  19. Generation by heated rock. Technology for hot dry rock geothermal power; Yakeishi ni mizu de hatsuden. Koon gantai hatsuden no gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Hori, Y. [Central Research Inst. of Electric Power Industry, Tokyo (Japan)

    1995-06-15

    Japan is one of the most distinguished volcanic country in the world and about 8% of the active volcanos of the world are distributed in Japan. This kind of a large quantity and natural energy resource near us are used as hot springs in the whole country and as for electricity in 10 geothermal power stations. In future, if this enormous underground geothermal energy could be utilized safely and economically by using new power generation system like hot dry rock geothermal power generation (HDR), it may contribute a little to the 21st century`s energy problem of Japan. Central Research Inst. of Electric Power Industry has installed `Okachi HDR testing ground` in Okachi-machi of Akita Ken, and is carrying out experiments since 1989. Hot dry rock geothermal power generation is a method in which water is injected to the hot dry rock and the thermal energy is recovered that the natural rock bed is used as a boiler. However, development of many new technologies is necessary to bring this system in practical use. 9 refs., 5 figs., 1 tab.

  20. Air environment purification using photocatalyst. Hikari shokubai ni yoru taiki kankyo joka

    Energy Technology Data Exchange (ETDEWEB)

    Takeuchi, K [National Institute for Resources and Environment, Tsukuba (Japan)

    1993-12-02

    Noticing that metal oxides have photocatalysis for reduction in NOx concentration and examining effects of the TiO2 selected on removal of pollutant, the paper proposes a direct purification method for the air environment. Since TiO2 causes electron excitation meeting near ultraviolet irradiation, it manifests a catalytic function for various oxidation/reduction reactions. Details of the reaction mechanism are unknown, various active oxygen species generated on the surface of TiO2 under light irradiation oxidize NOx and acquire it as nitric acid on the surface. It is found that mixture of activated carbon of low hygroscopicity with TiO2 is effective to prevent a tendency of NO to desorb before NO becomes nitric acid. What 40% of the catalyst with fluorine resin is formed into like a sheet shows a high removal rate even in the amount of ultraviolet irradiation in a winter cloudy day in the wide range of 0.5 - 95.0% of NOx and SO2, and if the photocatalyst is applied to the side wall of city buildings, the NOx concentration is estimated to be reduced by as much as 20%. 5 refs., 3 figs.

  1. Evaluation of environmental impact by LCA method. LCA shuho ni yoru kankyo fuka hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Sakamura, H.; Utsuno, F.; Yasui, I. (The University of Tokyo, Tokyo (Japan). Institute of Industrial Science)

    1994-06-01

    This paper explains the concept, history, and analytic methods of life cycle assessment (LCA), showing its application to beer bottles and cement factories as specific examples. The LCA is a method to calculate substances and energies put into the whole process of production of a product from raw material mining to product wasting and environmental loads emitted therefrom. It also evaluates the result collectively and quantitatively. A first case of the research is reportedly the one performed at Coca-Cola Co., Ltd. in 1969. Full-scale researches have gone forward in European countries in the recent several years, and are progressing to international networks. The analytic methods can be divided largely into an accumulation method to analyze data in each process and add them up, and a method to use an industrial association table. The former method is the most generally used method currently in overseas countries if referred to the LCA. Because the LCA can cause the analytic result and evaluation to vary depending on the purpose, it is important to define the goal, and set the scope. The LCA must develop in the future although it has a number of problems. 10 refs., 5 figs., 2 tabs.

  2. Report of 'Survey on Asian environmental information networks'; 'Asia kankyo joho network chosa' ni kansuru hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    This project is implemented to survey the current statuses and future trends of the Asian district environment-related information networks, for the (research cooperation project for development of environmental condition measuring laser radar systems), being promoted by NEDO. First, current statuses of the network names, managing organizations, user numbers, conditions of use, protocols for use, service conditions, major domestic nodes and internationally connected conditions are surveyed mainly for internet-connected networks, for surveying the current statuses and future trends of the research networks in Asian countries. Second, current statuses in Indonesia of the network names, managing organizations, user numbers, conditions of use, protocols for use, service conditions, domestic node sites and managing organizations, charge systems and institutions, types/reliability/ stability of the circuits, and conditions of restriction of use, if any, for surveying the current statuses and future trends in Indonesia. Third, conditions of and needs for network utilization by researchers for Asian district environments. (NEDO)

  3. Fibredrain method. Environmentally friendly vertical drain; Fiberdrain koho. Kankyo ni yasashii vertical drain koho

    Energy Technology Data Exchange (ETDEWEB)

    Suto, Y.; Inoue, T. [Fukken Co. Ltd., Hiroshima (Japan); Miura, N. [Saga University, Saga (Japan). Faculty of Science and Engineering; Yoshida, Y.; Hamada, K. [Hiroshima Prefectural Government Office, Hiroshima (Japan); Aboshi, H. [Hiroshima University, Hiroshima (Japan)

    1997-11-01

    Ground improvement using fibredrain (FD) material has not been used in Japan. For its practical use in Japan, laboratory experiment was made on such technological characteristics of FD material as tensile strength and permeability, and field test was also made to verify its improvement effect. A plane FD specimen of nearly 90mm wide and 9mm thick is composed of a folded double jute fabrics band and 4 twisted coir ropes arranged between the jute fabrics at even intervals, and the band is sewn up along center lines between the ropes. A mean permeability coefficient is estimated to be {kappa} = 1.0times10{sup -1}cm/s and {kappa} = 1.0times10{sup -2}cm/s at {sigma}{sup 3} = 0.5kgf/cm{sup 2} and {sigma}{sup 3} = 2.0kgf/cm{sup 2} in lateral pressure, respectively, showing sufficient permeabilities for vertical drain material. The tensile strength of fresh FD material is estimated to be a little stronger than 900kg/material width which is far stronger than that of conventional FD materials. The field test result showed that the FD material achieved the target for ground improvement, and has sufficient functions as a substitute for SD material. 6 refs., 10 figs.

  4. Report on Asian Environment Information Network; 'Asia kankyo joho network' ni kansuru hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The goal is the construction of Asian Environment Information Network (AEInet) in accordance with a contract signed between Indonesia's LIPI (Indonesian Institute of Science) and NEDO under NEDO's Research Cooperation Project Concerning the Development of Environment Measuring Laser Radar (LR). The network is so designed and constituted as to operate on a private line between Indonesia and Japan via IP (Internet protocol) and to enable the exchange on the Internet network of the data collected/analyzed by the Indonesian LR system and of articles of e-mail between scientists of the two countries. The AEInet will be utilized for the collection/analysis of LR-collected data; exchange of observed data and the result of processing; provision of support to environment information scientists in exchanging e-mail and information; and the search of databases for the implementation of the project. In this paper, the outline and functions of the system, network system design, WWW server construction, network operating status, joint researches with Indonesia, etc., are described. (NEDO)

  5. Emergency housing after natural disaster; Shizen saigaigo no oukyu kyoju kankyo seibi sisutemu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, Masami [Kyoto University, Kyoto (Japan). Graduate School of Engineering

    1998-12-16

    In Japan, there were some serious disasters in recent years. In 1991, Unzen-Fugendake erupted and more than 1,000 people were forced to take refuge from their houses. In 1993, Hokkaido-Nanseioki earthquake attacked the south-east area of Hokkaido and more than 3,557 houses were destroyed. In Japan, the government supplies the temporary housing to those who lost house from the natural disasters. The purpose of supplying temporary houses mentioned in the disaster relief law (established in 1947) prescribes the purpose of temporary housing that to rescue the poor who can not afford getting a shelter with their own funds. But actual condition of temporary housing is completely different. Government supplies temporary housing to all those who request temporary housing. The term of using temporary house tend to become longer. The regulation about temporary housing has not been yet up to dated. Many problems concerning about temporary housing originate in outdated regulation. The temporary housing have to be ranked in the part of restoration process from natural disaster. (author)

  6. Biomethylation in the natural environment: a review; Shizen kankyo ni okeru biomethylation

    Energy Technology Data Exchange (ETDEWEB)

    Tao, H. [National Institute for Resources and Environment, Tsukuba (Japan); Fatoki, O. [University of Fort Hare, (South Africa)

    1997-09-25

    This paper explains mechanism of biomethylation of such elements important in environmental science as As, Hg, Sn and Pb, and its significance in the environmental science. Biomethylation is a process to bond methyl group directly to metals by actions of living organisms, which is occurring widely in the natural environment. Addition of methyl group onto metallic elements has a high possibility of changing their chemical and physical properties and increasing their movability, thus affecting the geochemical circulation. Particularly, such elements are important for the environmental science as As, Hg, Sn, Pb, Se, Te, Ge, Sb, P, S, and Cl. Deposits in water zones which have been regarded previously as final settling places for heavy metals are active media for anaerobic bacteria which can cause methylation. Important molecules involving in methylation are S-acenosylmethionine (SAM) and methylcobalamin which is a derivative of vitamin B12. The SAM is regarded as sulfonium salt, and the methyl group is transferred as a carbocationic intermediate. 106 refs.

  7. In the environmental pollution air raid of NATO; NATO no kubaku ga kankyo osen ni

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-10-05

    In recent European Union commissioned report, there was no evidence that the air raid of the NATO military in Yugoslavia became a cause of the large-scale ecology destruction until now. However, the pollution is very serious in industrial area suburb which becomes a target for Novi Sad and Pacncevo, Prahovo. The Hungary-based Regional Environment Center for Central and Eastern Europe in Hungary: REC was reported. According to REC, the pollution of the Danube river after the air raid which reaches for 11 weeks by the NATO military was serious, and ammonia of 100 tons, ethylene dichloride over the 1 thousand tons, 33% hydrochloric acid solution of the 1 thousand tons escaped to the Danube river from the air raid of Pancevo on April 18th. And, the mercury accumulated in sodium hydroxide of about 3 thousand tons, liquid chlorine of several decade tons and chlorine/alkali plant also escaped from Pancevo. United Nations-led Environmental Damage Assessment Mission should inspect Kosovo and Yugoslavia on July 19th, and it was announced with 'NATO does not show still us all well-informed information'. The investigation is carried out on the item which the Yugoslavia authorities designates, and the atmosphere level of VCM has reached 10600 times the concentration of the acceptable level near Pancevo, and it reports that acid rain was observed in each place. (translated by NEDO)

  8. Environmental pollution by dioxin and its biodegradation; Dioxin ni yoru kankyo osen to sono biseibutsu bunkai

    Energy Technology Data Exchange (ETDEWEB)

    Nojiri, H.; Yamane, H.; Omori, T. [Tokyo Univ. (Japan)

    1998-10-20

    Polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and coplanar polychlorinated biphenyls (Co-PCBs) exhibit similar chemical and biological properties. Because of their highly toxic activity, the pollution with these compounds, which are called dioxin-related compounds, is one of the most serious environmental problems. In this review, we described the analytical methods of dioxin-related compounds in environmental samples, especially in the exhaust gas from the incineration site of municipal solid waste. In addition, we described the present situation of environmental pollution by dioxin-related compounds, including pollution levels in environmental, human, and food samples, daily intakes, and risk assessment. On the other hand, a number of microorganisms have been reported which are able to degrade dioxin-related compounds including PCDDs and PCDFs. These microorganisms are classified into two groups, lignin-degrading white rot fungi and the dioxin-degrading bacteria. We also described the degradation pathways of dioxin-related compounds in these microorganisms, and their degradative enzymes. 47 refs., 5 figs., 4 tabs.

  9. Research on environmental bioecosensing technology using ecological information; Seitaikei joho ni yoru kankyo bio eco sensing gijutsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The bioecosensing technology was studied which detects and identifies feeble signals generated by biosystem communication in wide biological environment. The following were reported as current notable environmental biosensing technologies: a quick measurement method of environmental contaminants using immunological measurement method, analysis method of ecological state of microorganism using DNA probes, observation of ecosystem by bioluminescent system, measurement method of environmental changes and contaminants using higher animals and plants, and detection method of chemical contaminants using chemotaxis of microorganism. As a result, the new bioecosensing/monitoring technology in molecular level was suggested for identifying comprehensive environmental changes which could not be measured by previous physical and chemical methods, as changes in ecosystem corresponding to environmental changes. As the wide area remote sensing technology of environmental ecological information, sensing technology on the earth, aircraft and satellite was also discussed. 247 refs., 55 figs., 17 tabs.

  10. Research cooperation in the development of laser radar for environmental measurements. Environmental network; Kankyo keisokuyo laser radar no kaihatsu ni kansuru kenkyu kyoryoku. Kankyo network

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Among the research cooperation in the development of laser radar for environmental measurements with Indonesia between FY 1993 and FY 1996, results of the research and development of the environmental network are summarized. For the environmental information network, the Tokyo NOC is linked as an Internet connection point in Japan with the Jakarta NOC using an international dedicated line with a capacity of 64 Kbps. The Tokyo NOC is linked with domestic environmental information researchers using Internet. Thus, data stored in the data processing system of laser radar can be exchanged, information in both countries can be exchanged using E-mail, and data can be accumulated. For the research cooperation with Indonesia, research of path control and information relay server, research of effective transmission of data on the network, and research of multimedia communication have been conducted. The multimedia communication, distributed processing, and extension of dedicated line network using PPTP have been also conducted. 39 figs., 4 tabs.

  11. Research and development cooperation project on environmental measurement using laser radar (environmental network) in fiscal 1993; Kankyo keisokuyo laser radar no kaihatsu ni kansuru kenkyu kyoryoku (kankyo network)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    For the purpose of contributing to the research cooperation project on the development of a laser radar for environmental measurement, the paper surveyed the present and future trend of the environment related information network in Indonesia. The survey was conducted in terms of a name of the network, the main administration body, the number of users, the utilization status, the use protocol, details of service, domestic mode installation sites and the main administration body, accounting system, types of the network used, reliability and stability of network, limitations on the use and details of the limitation, etc. The plan for expanding telecommunication equipment is being advanced in a very quick tempo. However, there are many problems in digitalization, and it is feared that the plan will be delayed. As to telecommunication quality and connection quality, the telecommunication completion rate, SCR, is very low, approximately 24% on average, which is equal to that around 1990 in Japan. The business service for users is all bureaucratic since they have a lot of applications for the installation piling up with no exception to the rule of developing countries. 23 figs., 10 tabs.

  12. Research and development cooperation project on environmental measurement using laser radar in fiscal 1995 (environmental network); Kankyo keisokuyo laser radar no kaihatsu ni kansuru kenkyu kyoryoku (kankyo network)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    As a part of the cooperative work with Indonesia of R and D of a laser radar for environmental measurement, the paper described the development of an environmental network. The field survey was conducted in April, July and December 1995 and in March 1996. For the investigational research, five meetings of the committee and four times of group work were held. The Asian environmental network was studied in terms of its arrangement, operation and management, and the overall network/path control design were being prepared. To make the persons concerned abroad and in Japan understood the APEC Osaka Conference held in November 1995, a homepage APEC `95 Kansai was opened using WWW (World Wide Web, a decentralized hyper media system which can dispatch information to the whole world by network using hyper text). Moreover, in connection with this, a homepage was opened of CICC (Center of the International Cooperation for Computerization, a center controlling the whole Asian environmental information network system where E-mail and data are exchangeable with Indonesia via Tokyo NOC (Network Operation Center)). 49 figs., 8 tabs.

  13. Environment of developing countries. ; Centered around 1992 white paper or environment. Kaihatsu tojokoku no kankyo. ; 1992 nenban kankyo hakusho wo chushin ni shite

    Energy Technology Data Exchange (ETDEWEB)

    Takiguchi, N [Environment Agency, Tokyo (Japan)

    1992-12-01

    The present paper outlines the present situation of environment of developing countries, factors causing environmental devastation, and the influence in the international linkage as described in 1992 White Paper on Environment. The present environmental devastation is originated from national poverty. In general, as the results of imposing excessive pressure on the natural environment accompanying the increase of population or causing urban pollution due to the movement or densification of population, poverty brings about the reduction and devastation of forest, deterioration of soil, desertification, contamination of air and rivers, causing miserable situation. Prawn culture as primary export industry damages mangrove woods, and causes water pollution. Industrial development is rapidly spreading pollution of water and air. As for international relations, the net transfer amount of money in the flow of funds between advanced countries and developing countries is in the direction from the latter to the former due to payment of debts. In enforcing direct investment or overseas development aid projects, advanced countries must be aware of their responsibility, make efforts in grasping the situations of aided countries and perform sufficient environmental assessment. 5 refs., 8 figs., 11 tabs.

  14. Research and development cooperation project on environmental measurement using laser radar in fiscal 1994 (environmental network); Kankyo keisokuyo laser radar no kaihatsu ni kansuru kenkyu kyoryoku (kankyo network)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    Under the R and D of a laser radar for environmental measurement which are conducted in cooperation with Indonesia, the paper reported the R and D of the environmental network in fiscal 1994. Four field surveys were made, and the following were conducted: proposal of a technical system, adjustment of the Asian environmental information network with BPPT and LIPI which are organs on the Indonesian side, installation of/technical discussion on network equipment, etc. There is IPTEKNET as a plan of a nationwide network of the scientific technology information service in Indonesia. The analytical design phase of this system converged in 1992, and the predicted investment amount in the coming five years is expected to be 6.7 million US dollars. As the future Asian environmental information network work, planned are connection between BPPT and Tokyo CC and connection at BPPT between the Asian environmental information network and IPTEKNET. Network managers at sites are very skillful, and therefore, the thorough cooperative work is anticipated. 24 figs.

  15. Survey on research environment for young researchers in the U.S.. What attractive environment is for young researchers; Beikoku ni okeru wakate kenkyusha no kenkyu kankyo ni kansuru chosa. Wakate kenkyusha ni totte miryokutekina kankyo towa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-28

    A survey was conducted on 'what attractive research environment is for young researchers' as a theme. The young researchers are referred to as those who are registered on a master's or doctor's degree courses and what is called postdoctoral scholars who received a doctor's degree. In the survey, a few common comments were seen in over interviews on the U.S. research environment. The comments were such that, needless to say, subsidies are indispensable for researches but economic aspects of treatment are not necessarily satisfactory, that the research environment is generally good, allowing freedom in research, and that results tend to be achieved by providing a subsidy for experienced knowledgeable researchers rather than directly subsidizing young researchers with a large sum, while programs with individuality such as a fellowship are desired more. It is apparent that the interests of postdoctoral scholars are economic stability; in fact, uneasiness and dissatisfaction in the status and the treatment are pointed out in a survey by the U.S. Science Academy. (NEDO)

  16. Result of comparative experiment on environmental comfort in room using hot heat environment testing unit. Onnetsu kankyo shiken unit ni yoru shitsunai kankyo no kaitekisa no hikaku jikken kekka ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Fujiwara, T; Kawashima, K [The Hokkaido Electric Power Co. Inc., Sapporo (Japan)

    1991-11-20

    Measurements were carried out on three buildings having different heat insulation, airtightness and heat capacity for testing the hot heast enviroments (having a room size of about 4.6 m{times}3.7m{times}2.3 m) as to the temperature differences between the upper and lower parts of the room and the MRT (mean radiation temperature, representing the temperature of radiation from the wall face). These are compared according to types of heating appliance. The result is summarize as follows: The temperature difference in the upper and lower parts is affected largely by the airtightness of the building, the difference being capable of getting reduced by rasing the airtightness even in a buildings low in heat insulation. In a building with low airtightness, type of heating appliance and its installation location affect the temperature difference. The MRT is determined determined nearly completely by the heat insulation of the wall face in a room, but it tends to be affected easily by the specification and area of windows. A floor heating system increases the MRT and generates very little difference in temperatures in the upper and lower parts of the room. A comparison using a PMV (one of the indexes for enviromental comfort in a room) was also conducted. 12 figs., 7tabs.

  17. Survey on bio-chemical complex harmonized with global environment. 3; Kankyo chowagata seibutsu kagaku konbinato ni kansuru chosa. 3

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    A survey was conducted of bio-chemical complex harmonized with the global environment for the purpose of constructing the material production process harmonized with the environment by the process fusion between biological conversion and chemical reaction. Palm oil was taken up as renewable raw material plant resource. The process utilizing bio-chemical reaction advances at normal temperature and pressure and is high in reaction specificity and selectivity. This is a recycling, circulation and environmental harmony type production technology which brings high yield, energy conservation, resource conservation, and low environmental loads. Waste water treatment and production of useful substances from sludge were thought as elementary technology. A possibility was studied of enzyme production by culturing solid waste, and the enzyme was applied to the hydrolysis process. The paper indicated trace components in the palm oil and the extraction method and proposed the production process of new derivatives for adding value to hydrolysate. A study was also made of the overall process flow which integrated these new processes and the material balance. The comprehensive evaluation of this new process was made from the aspect of the product structure, the market, construction cost, economical efficiency, and the environment. 133 refs., 65 figs., 56 tabs.

  18. To create and built urban environment for disaster mitigation; Saigai ni tsuyoii toshi kankyo no sozo no tameni

    Energy Technology Data Exchange (ETDEWEB)

    Murozaki, Masuteru [Kobe University, Kobe (Japan)

    1999-06-10

    Learning from disaster of the Hanshin{center_dot}Awaji Earthquake, the need for building disaster preventing town is explained. Scheme of is prevalent among the townspeople. Administrations also tend to think light of hardware, and they treate approaches lightly in which safety of hardwares of town structures is secured. There are basic questions such as learning cases of reconstruction in advanced cities, understanding that problem is in hardware rather than in software, and removing biases on disaster prevention. It is necessary that persons concerning construction give them positive solutions as problems of themselves. (NEDO)

  19. Realization of an accelerator for environmental refreshment in case of soil; Fukyugata kasokuki ni yoru kankyo sosei eno koka

    Energy Technology Data Exchange (ETDEWEB)

    Isogai, H [Electrotechnical Laboratory, Tsukuba (Japan)

    1997-11-25

    Learning from a history of the earth of ancient times, the paper studies effects of refreshing environment and soil or making them natural and harmless mostly using primitive bacteria, and develops element technology which is industrially accelerating. The spread type accelerator working only by solar energy was installed and operated for experiment. As indices of refreshment effects, a study was comparatively made between a sugar degree of sweet potato and a yield shown in the number of potatotimesunit weight. An EM propagation garbage layer is formed, and the two sections were installed of a site of the actual installation of the spread type accelerator and a site naturally left alone. Other effects of weather, temperature and humidity which are external factors and general fertilization are offset as common modes, and a consideration was so made that only refreshment effects of primitive bacteria can be relatively compared. Acceleration effects in using accelerator for growing sweet potato could be quantitatively confirmed. As to sugar degree, because the last study was made in the beginning of summer, the underground temperature was high enough. Even only EM effects were fully effective. This time, the weather was much colder, and it was found to be a must to use accelerator. 2 figs.

  20. Investigations on international standardization of environmental management systems. 3; Kankyo kanri system no kokusai hyojunka ni kansuru chosa. 3

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Japan as an ISO member country identifies the state of discussions in the environmental management standard deliberation committee at ISO. Investigations were performed on international standardization of environmental management systems for the purpose of participating and cooperating in preparing and establishing international standards related to environmental management, and playing part in working, solving and improving environmental problems. Under the circumstances that environmental problems are drawing worldwide interest, the International Organization for Standardization (ISO) has been carrying out since 1993 deliberations on environmental management standards to institutionalize environmental management rules to check effects of business activities on the environment. The International Organization for Standardization/Environmental Management Technical Committee (ISO/TC207) was installed, at which series number of 1400 order was allotted for environmental management related standards, and major standards have come to a final stage of standard formulation at the TC207 Oslo conference in June 1995. In Japan, the Ministry of International Trade and Industry has established an environmental management standard deliberation committee composed of people of experience or academic standing to advance discussions on how the environmental management should be in business entities through deliberations on ISO standards.

  1. Report on Asian Environment Information Network; 'Asia kankyo joho network' ni kansuru hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The goal is the construction of Asian Environment Information Network (AEInet) in accordance with a contract signed between Indonesia's LIPI (Indonesian Institute of Science) and NEDO under NEDO's Research Cooperation Project Concerning the Development of Environment Measuring Laser Radar (LR). The network is so designed and constituted as to operate on a private line between Indonesia and Japan via IP (Internet protocol) and to enable the exchange on the Internet network of the data collected/analyzed by the Indonesian LR system and of articles of e-mail between scientists of the two countries. The AEInet will be utilized for the collection/analysis of LR-collected data; exchange of observed data and the result of processing; provision of support to environment information scientists in exchanging e-mail and information; and the search of databases for the implementation of the project. In this paper, the outline and functions of the system, network system design, WWW server construction, network operating status, joint researches with Indonesia, etc., are described. (NEDO)

  2. Distribution coefficients of amino acid, peptide and enzyme in respect to aqueous two phase system composed of dextran, polyethylene glycol and water; Dekisutoran+poriechiren gurikoru+mizu karanaru suiseinisokei ni taisuru aminosan, pepuchido oyobi koso no bunpai keisu

    Energy Technology Data Exchange (ETDEWEB)

    Iwai, Yoshio [Kyushu University, Fukuoka (Japan); Kakizaka, Keijiro; Shindo, Takashi; Ishida, Otetsu; Arai, Yasuhiko

    1999-01-05

    Distribution coefficients of five kinds of amino acids (aspartic acid, asparagines, methionine, cysteine and cytidine) and two kinds of peptides (glycylglycine and hexane glycine) were measured. These distribution coefficients are in good correlation with the osmosis viral expression. The interaction parameter in the osmosis viral expression can be estimated by hydrophilic group parameter. The distribution coefficient of {alpha}-amylase was estimated by the osmosis viral expression using the above-mentioned hydrophilic group parameter, and the estimated value showed substantially good correspondence with the actually measured value, but for the distribution coefficient of {beta}-amylase, no coincidence was found. (translated by NEDO)

  3. Heat pump using dual heat sources of air and water. Performance with heat sources arranged in parallel; Mizu kuki ryonetsugen heat pump no kenkyu. Netsugen heiretsu unten ni okeru seino

    Energy Technology Data Exchange (ETDEWEB)

    Ito, S; Miura, N; Sato, S [Kanagawa Institute of Technology, Kanagawa (Japan); Uchikawa, Y; Hamada, K [Kubota Corp., Osaka (Japan)

    1996-10-27

    A heat pump system using water and air as heat sources was built and evaluated for its performance. In this system, evaporators may be operated singly or as connected in parallel or series, and, for each case, the quantity of heat acquired may be measured and system performance may be quantitatively evaluated. The findings follow. When the two heat sources are equal in temperature in the single-evaporator operation, the evaporation temperature is about 7{degree}C higher on the water side than on the air side, and the performance coefficient is about 0.7 higher. When the air heat source temperature is 25{degree}C in the parallel operation, like quantities of heat are obtained from both heat sources, and collection of heat from the water increases with a decrease in the air heat source temperature but, with an increase, collection from the air increases. When the air heat source temperature decreases, the evaporation temperature decreases in the single-evaporator working on the air and in the parallel operation but it levels off in the single-evaporator working on the water alone. When the water heat source temperature decreases, evaporation temperature drop is sharper in the single-evaporator working on the water than in the parallel operation, which suggests the transfer from the parallel operation to the single-evaporator working on the air. In the single-evaporator operation on the water heat source, the evaporation temperature linearly decreases with an increase in superheating. 1 ref., 10 figs.

  4. Solid electrolyte membranes and the system to produce hydrogen from thermally decomposed water by solar energy; Taiyo energy riyo ni yoru mizu no chokusetsu netsubunkai kara no suiso seizoyo

    Energy Technology Data Exchange (ETDEWEB)

    Nigara, K; Watanabe, K; Kawamura, K; Kawada, T; Mizusaki, J; Ishigame, M [Tohoku University, Sendai (Japan). Research Institute for Scientific Measurements

    1996-10-27

    For conversion of solar heat to transportable energy, hydrogen production by direct thermal decomposition of water using concentrated high-temperature solar heat was studied. Water vapor is injected into the tubular target with high melting point and high oxygen permeability at high temperature while heating the target by concentrated solar heat over 2000K. Oxygen in decomposed gas is discharged through an oxygen permeable membrane to extract hydrogen. Solid electrolyte is used as one of the target materials. Oxygen gas in the high-oxygen partial pressure site changes into oxygen ion by accepting two electrons at the target surface, and returns to neutral oxygen gas in the low-oxygen partial pressure site by discharging two electrons at the surface after permeation through oxygen vacancy. In the case of n-type solid electrolyte, to obtain constant permeation of a large amount of oxygen, flow of a large amount of electrons is indispensable in the opposite direction to oxygen ion. Among [(ZrO2)(1-x)(CeO2)x](0.9)(CaO)(0.1), materials of 0.4-0.5 in x seems to be useful as the target material. 7 refs., 7 figs.

  5. Study on the impact assessment for the life cycle assessment (LCA); Kankyo fuka bunseki ni okeru impact assessment ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This report describes the impact assessment which is an important step for LCA. For classification of the impact assessment, the existing literature was reviewed and a skeleton for the classification was proposed. The weighting factors for nine selected impact categories, which were used to calculate environmental load point (ELP) for the valuation, were obtained for two overseas groups, i.e., students of Amsterdam University and SETAC Europe members. It was found that the former provided the similar trends to general Japanese, however that the latter gave high weighting in the global warming and depletion of ozone layer. The ELP was proposed and applied to automatic washing machine, coffee maker, waste incineration power generation system, and co-generation system. As a result, its effectiveness was demonstrated. This report also describes problems for the LCA of thermal and material recycling of PS trays. 99 refs., 96 figs., 73 tabs.

  6. Investigations on an environment friendly chemical reaction process (eco-chemistry). 2; Kankyo ni yasashii kagaku hanno process (eko chemistry) ni kansuru chosa. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    In order to structure a chemical reaction process that does not discharge a large amount of waste by-products or harmful chemical substances, or so-called environment friendly process, investigations and discussions were given based on the results derived in the previous fiscal year. A proposal was made to reduce environmental load on development of oxidized and dehydrogenated catalysts that can produce selectively ethylene, propylene and isobutylene in an oxidation process. In liquid phase oxidation, redox-based oxidation and solid catalyzation of automatic oxidation reaction were enumerated. In acid base catalyst reaction, development of ultra strong solid acid was described to structure no pollution discharging process. In the fine chemical and pharmaceutical fields, the optical active substance method and the position-selective aromatics displacement reaction were evaluated to reduce environmental load. A questionnaire survey performed on major chemical corporations inside and outside the country revealed the following processes as the ones that can cause hidden environmental problems: processes discharging large amount of wastes, processes treating dangerous materials, and processes consuming large amount of energy. Development of catalysts is important that can realize high yield, high selectivity and reactions under mild conditions as a future environment harmonizing chemical process. 117 refs., 23 figs., 22 tabs.

  7. Research of environmental bioecosensing technology using ecological information. Part 2; Seitaikei joho ni yoru kankyo bio ecosencing gijutsu ni kansuru chosa. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Basic considerations of exploring and cultivating environmental reporter organisms are summarized. Mechanism of genetic engineering amplification and molecular biological amplification, and approach to combining them to a hardware as a bioindicator system are investigated. For the current status of molecular biological measurement technology for measuring ecological environment and its application, environmental diagnosis from a phyropathological viewpoint, environmental diagnosis using microorganisms, test fabrication of genetic sensor, and overseas examples of environmental monitoring network are described. For the application of ecological information and functions for developing innovative environmental remediation technology, issues and potential areas for research and development regarding the bioremediation technology in which the US has achieved a progress for the benefit of soil environment remediation are summarized. For the phytoremediation, an area of bioremediation, the metabolism of microorganisms which live in the rhizosphere, and the technology for controlling the microorganisms in the soil through plants are investigated. 66 refs., 50 figs., 17 tabs.

  8. Fiscal 1994 survey report. Survey of environmentally friendly chemical process (Ecochemistry); 1994 nendo kankyo ni yasashii kagaku hanno process (ecochemistry) ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    Processes that contain latent environmental problems are the massive generation of wastes (inorganic salt, acid catalyst, base catalyst, and huge quantities of wastewater), handling of dangerous substances (use of hydrogen fluoride, use of phosgene, and use of substances whose discharge is legally controlled), processes which consume much energy (circulation of quantities of raw materials, use of quantities of solvents, separation of products with difficulties, use of high pressure, and multiple stage reaction), and processes which are expected to use resources now remaining unexploited. As an element technology for the solution of problems, there is the development of a solid redox catalyst for liquid phase oxidation. As compared with a liquid phase homogeneous catalyst, it discharges less inorganic wastes, facilitates the separation, recovery, and treatment of inorganic salts, corrodes structural materials less, and is thermally stable. An alkane partial oxidation catalyst when developed will achieve more energy conservation than an alkene oxidation catalyst. In relation to acid/base reaction, the zeolite catalyst will be improved and ultrastrong acids and ultrastrong bases will be developed, and these will reduce wastes, mitigate corrosion, and facilitate product separation. The development of a process is also expected which will avoid the use of toxic phosgene. (NEDO)

  9. Feasibility survey of the environmentally-friendly coal utilization system. Feasibility survey of the environmentally-friendly coal utilization system in the Philippines; Kankyo chowagata sekitan riyo system kanosei chosa. Philippines ni okeru kankyo chowagata sekitan riyo system kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    With relation to the coal of the Philippines, where the expansion of the use of coal as a substitute for petroleum/plant fuel is aimed at, the paper grasped the situation of coal production/development, the trend of coal import and domestic distribution, the coal utilization trend, and environmental problems, and analyzed the situation of coal utilization/spread by industry including the commercial/residential use. The purpose of the survey is to draw up a master plan for the introduction of the environmentally-friendly coal utilization system. As to the use of environmentally-friendly coal technology which should be adopted to the coal mining industry and commercial/residential sector, cited are the introduction of coal preparation technology and power transmission technology, and the development/spread of briquette as a firewood substituting fuel. In the electric power sector, the problem is the treatment of ash after combustion and the effective use. Relating to the treatment of flue gas, there is no installation at all of desulfurization facilities and denitrification facilities. In the cement industry sector, they wish to return fuel from heavy oil to coal. For it, it is necessary to study dust preventive measures. In the other sectors, coal hasn`t been used very much. An increase in coal demand is not expected also in the future, and big problems concerning coal haven`t occurred. 42 figs., 64 tabs.

  10. Report on the survey in fiscal 1998. Systematic arrangement of environment technologies. 5 (Application of advanced technologies to environmental measures); 1998 nendo chosa hokokusho. Kankyo gijutsu ni kansuru taikeiteki seiri. 5 (sentan gijutsu no kankyo taisaku eno oyo)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Global environment handling technologies were investigated and put into order. Universities often make research and development on themes that can be handled at laboratory levels or by simulations. Development at a practical application level is few. Technological seeds may include manufacture of hydrogen by water and steam decomposition using solar energy, and new synthesizing reactions utilizing solar energy. Included may also be urban type wind power generation, superconductive energy storage systems, biomass utilization, and natural energy utilization. Furthermore, CO2 recovery and utilization by liquefaction, alkaline metal heat power generation, and pulse power technologies can also be found. Studies on applying advanced technologies to environmental measures include composite materials, membrane separation, photo-catalysts, optical elements, porous bodies, functional polymers, bio-reactors, electron beams, and aeration. Private corporations are working noticeably on prevention of fluorocarbon and dioxin emission, PCB treatment and waste water treatment technologies, catalyst application technologies, recycling technologies, and incineration ash treatment and utilization technologies. (NEDO)

  11. Feasibility survey of the environmentally-friendly coal utilization system. Feasibility survey of the environmentally-friendly coal utilization system in Indonesia; Kankyo chowagata sekitan riyo system kanosei chosa. Indonesia ni okeru kankyo chowagata sekitan riyo system kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    With relation to the coal of Indonesia, where the expansion of the use of coal as a substitute for petroleum/plant fuel is aimed at, the paper grasped the situation of coal production/distribution/utilization and environmental problems, and analyzed the situation of the coal utilization/spread by industry including the commercial/residential use. The purpose of the survey is to work out a comprehensive master plan including Japan`s international cooperation for introducing the environmentally-friendly coal utilization system to Indonesia. Coal utilization systems, the introduction of which Indonesia should study in future, were picked up, according to the surveys in fiscal 1993 and 1994. In commercial/residential and small-scale industry sectors, needed is improvement of carbonization technology for production of coal carbonization briquette. Moreover, the introduction of bio-briquette should be studied in the future. In the power generation sector, studies should be made on the introduction of technology for SOx/NOx reduction and technology for coal ash treatment including the effective use of coal ash. For the introduction of coal boilers, the combustion mixed with bagasse, which is abundant in amount, is also necessary. In the coal production sector, coal preparation technology is studied, and a method to select the optimum process was proposed through the simulation. 76 figs., 43 tabs.

  12. Report on the invitation program for developing countries concerning technology promotion project of global environmental industry in FY 1997; 1997 nendo chikyu kankyo sangyo gijutsu suishin jigyo ni kakawaru chikyu kankyo kanren gijutsu kaigai kenkyusha shohei jigyo hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In an effort to help preserve the global environment, International Center for Environmental Technology Transfer (ICETT) contributes to the solution of global environmental problems by promoting research exchanges with developing countries. As a part of this effort, ICETT hosted an environmental development researcher who visited Japan from the Institute of Environmental Research of Chulalongkorn University in Bangkok, Thailand. The invitation was extended at the request of NEDO. During the period of this investigation between September 16 and December 14, 1997, a photocatalyst was prepared and its performance was evaluated under the theme ``Application of photocatalysis to purification of atmospheric environment.`` At the same time, roadside test spots were inspected to study the practical application of optical photocatalysis. The visiting researcher also visited the National Institute for Resources and Environment to discuss with the staff of institute. This helped to deepen understandings of the state of air pollution problems confronting Japan, Europe, and North America, as well as issues related to the technologies that have been developed to solve these problems. The visiting researcher toured the RITE and examined Japan`s progress in the development of environmental control technology through joint research involving government, industry, and academia. At ICETT, the visiting researcher received training in Japan`s approaches to environmental problems in developing countries

  13. FY 1998 survey report on the feasibility study of environmental cooperation in environmental protection technology, system, etc. for spread to developing countries; 1998 nendo kankyo taisaku gijutsu seidonado no tojokoku fukyu ni kakawaru kankyo kyoryoku kanosei chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The paper arranged the present situation and the problems of environmental cooperation for developing countries, and studied based thereon how to cooperate in environmental protection for developing countries in the future. At the same time, it arranged the problems/subjects posed when environment-related companies in Japan try to transfer environmental technology to developing countries, for the purpose of using them as data in studying possibility of reviewing the environmental cooperation presently conducted. A view on environmental cooperation is that as security of mankind, it is necessary to help developing countries in technology/knowledge/fund. However, a trial calculation indicated that the initial investment of 11.1 trillion yen is needed only for desulfurization and water treatment in China and ASEAN countries. Such a huge amount of money cannot be paid at all even by developed countries. As the support of environmental protection measures, the one also including energy and resource is needed. Further, the support of environmental protection measures should be the one that has the exhibition effect and influential effect, promotes efforts of developing countries' own, and pushes independent environmental measures forward. From this point of view, a study was made on what the details of the environmental cooperation should be like. (NEDO)

  14. Ni hombres ni mujeres providenciales

    OpenAIRE

    Montaño Virreira, Sonia

    2000-01-01

    Debo advertir a la y el lector de este texto que lo que a continuación se presenta no es, ni de lejos, una propuesta realista, si por ella entendemos la traducción, enclave mujer, de las actuales tendencias de liderazgo político vigentes en la región. Por el contrario, intento argumentaren favor de un liderazgo que supere el caudillismo como estilo y se aproxime al máximo hacia el respeto de las formas, entendiendo que sin ellas no es posible construir la democracia. Para hacerlo reviso rápid...

  15. Report of the results of the fiscal 1997 regional consortium R and D project. Regional consortium field / Development of technology to treat aquatic environment by using microorganisms fixed on carbon fabrics (abbreviation: carbon/aquatic environment project) (first fiscal year); 1997 nendo chiiki consortium kenkyu kaihatsu jigyo. Chiiki consortium bun`ya / tanso sen`i nansoshiki eno biseibutsu kochaku gensho wo riyoshita mizukankyo seibi gijutsu no kaihatsu (ryakusho: tanso mizu kankyo project) daiichi nendo seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Out of the development of technology to arrange the aquatic environment using phenomena of microorganism fixation on carbon fiber soft textures, the paper stated the fiscal 1997 result. On carbon fibers in a state of swaying in water, microorganisms in water fix in an amazingly large quantity. A catalog was compiled of 58 kinds of carbon fabrics trially woven and knitted. When carbon fiber is used as activated sludge carrier, activity of microorganism lasts more than one year. Only a little amount of surplus sludge is generated. The fixed microorganisms are more active in case of carbon fiber than in case of nylon and polyester fibers. Fiber texture models of carbon fiber fixing activated sludge groups were proposed. By pump operation, the water flow inside/outside microorganism groups is being accelerated. Several new strains of bacillus carboniphilus were isolated/identified from soil and marsh. To grasp relationships of characteristics among three elements such as the state of aquatic environment, fiber, and microorganism group, the experiment was prepared. Preliminary work is conducted to derive a simple equation for facility design, and experimental directions to obtain design conditions were proposed. 6 refs., 166 figs., 47 tabs.

  16. Characteristic analysis of methane-gas generation by oxidizing heat of stored coal and hold ventilation control; Sekitan unpansen ni okeru sanka hatsunetsu ni yoru methane gas hassei to sonai kankyo seigyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Fukuchi, N; Nakashima, T [Kyushu Univ., Fukuoka (Japan); Kudo, S

    1999-12-31

    A demand of coal shows the tendency in the increase worldwide, with this, the marine transportation of the coal gradually increases, and the collier has also enlarged. The traffic pattern of coal is mainly the bulk transportation. In this transportation system, by the oxidation exothermic reaction of the coal, methane gas is produced, simultaneously the coal quality such as coking property or heat quantity is decreased and sometimes spontaneous ignition is caused. Therefore, it is necessary to equip with a ventilator to control the concentration of methane gas and to avoid the self heating of the coal. In this study, the quantity of methane-gas produced by heating coal using an electric furnace was measured and the experiment to investigate the temperature dependency of the methane-gas generated from the coal was conducted. By using the result of the measurement, the quantity of methane-gas produced from the coal stored in the hold of a coal cargo was estimated. And, the mathematical analyses on the changing degree depend on the times of a temperature in the hold under navigation, a concentration of oxygen and a concentration of methane-gas, were conducted. 11 refs., 19 figs., 2 tabs.

  17. FY 1999 report on the results of the introductory study on the global environmental industry technology. Investigational study on the environmental creation technology by the application of ecosystem information functions; 1999 nendo chikyu kankyo sangyo gijutsu ni kakawaru sendo kenkyu seika hokokusho. Seitaikei joho kino oyo ni yoru kankyo sozo gijutsu ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    To know the state of environmental pollution before it clearly exists, an investigational study was made on the technology to measure environmental stress at high sensitivity, in wide range and at high speed using functions to respond chemical substances, etc. which living organisms have. The FY 1999 results were outlined. As to the application of ecosystem information functions, survey was conduced paying attention to the environmental stress response of each of the bacteria, algae, plants and animals, responses viewed from the manifestation of immunity antibodies which occurs inside living organisms and changes at genetic level, and responses of algae and plants in case of specifying environmental pollutants. In relation to the application of the biological amplification mechanism, survey was carried out on environmental stress signals sent from plants, selection of environmental stress index plants, detection of environmental pollutants using bacteria, high sensitivity detection using animal (nematode), etc. Concerning the standardization of the environmental measuring technology by the application of ecosystem information functions, survey was conducted on artificial molecular recognition sensor, antibody device sensor, biochips, system construction, etc. (NEDO)

  18. Leading research for fiscal 1998 on innovative technology for the earth. Researches on technologies for creating ecology using ecosystem's information transmitting function; 1998 nendo chikyu kankyo sangyo gijutsu ni kakawaru sendo kenkyu. Seiteikei joho kino oyo ni yoru kankyo sozo gijutsu ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The aim is to develop a technology for detecting environmental pollution before it becomes apparent and thereby to contribute to the development of technologies to minimize the damage that may be inflicted upon the global environment. For this purpose, researches are conducted in search of techniques to detect, at high speed with high sensitivity over a wide scope, the response of living organisms to chemicals. In a research on the application of the reaction of ecosystem to environmental stress, communication between living organisms in coping with environmental chemicals is investigated. It is then found that the growth of vegetable roots may be used as a measure for the detection of environmental pollutants but that the method is too low in sensitivity. A research is conducted on the creation of an ecological reporter function using the biological amplification technique. It is then found that the immunoreaction-aided measuring of environmental pollutants yields an excellent result in terms of sensitivity but that it has a problem in its resistance to environmental conditions. In a research on the standardization of environmental measurements using ecological information, it is found that the primary object of research and development should be a systematization technology compatible with biological functions. (NEDO)

  19. Leading research for fiscal 1998 on innovative technology for the earth. Researches on technologies for creating ecology using ecosystem's information transmitting function; 1998 nendo chikyu kankyo sangyo gijutsu ni kakawaru sendo kenkyu. Seiteikei joho kino oyo ni yoru kankyo sozo gijutsu ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The aim is to develop a technology for detecting environmental pollution before it becomes apparent and thereby to contribute to the development of technologies to minimize the damage that may be inflicted upon the global environment. For this purpose, researches are conducted in search of techniques to detect, at high speed with high sensitivity over a wide scope, the response of living organisms to chemicals. In a research on the application of the reaction of ecosystem to environmental stress, communication between living organisms in coping with environmental chemicals is investigated. It is then found that the growth of vegetable roots may be used as a measure for the detection of environmental pollutants but that the method is too low in sensitivity. A research is conducted on the creation of an ecological reporter function using the biological amplification technique. It is then found that the immunoreaction-aided measuring of environmental pollutants yields an excellent result in terms of sensitivity but that it has a problem in its resistance to environmental conditions. In a research on the standardization of environmental measurements using ecological information, it is found that the primary object of research and development should be a systematization technology compatible with biological functions. (NEDO)

  20. Study to take environmental symbiosis into consideration on housing construction. No.2. Experimental study on the thermal performance of K house in winter season; Kankyo kyosei ni hairyoshita sumai zukuri ni kansuru kenkyu. 2. Amagishi ni tatsu K tei no toki no onnetsu kankyo keisoku kekka

    Energy Technology Data Exchange (ETDEWEB)

    Nishikawa, K; Ishihara, O [Kumamoto University, Kumamoto (Japan)

    1996-10-27

    For the construction of houses that effectively utilize natural energy and impose less load on environments, an example of house building respecting environmental symbiosis is described. Reported herein are a heating system and the measurements of thermal environment in winter. In winter, the floor is heated by warm water from solar heat collectors circulating in pipes buried in downstair underfloor RC foundation. For the verification of the heating effect, comparison was made between the heater-provided southeast (SE) room and heater-unprovided northeast (NE) room, both downstairs. Warm water circulated in the underfloor pipes only in the daytime, the pipe surface recording the maximum of 32{degree}C in the daytime and the minimum of 17{degree}C early in the morning. At midnight, the SE room was warmer than the NE room by 2{degree}C. The slab surface in the SE room recorded 28{degree}C at the maximum and 17{degree}C at the minimum, but the temperature remained constant at 10{degree}C in the NE room. The rubble temperature was 17.5-20{degree}C in the SE room and approximately 11{degree}C in the NE room. It was noted that the SE room floor slab was capable of heat accumulation. The resident is a devotee of environmental symbiosis with mindset for enhancing natural energy utilization, burning an oil heater and a fireplace but intermittently. 1 ref., 12 figs., 1 tab.

  1. FY 1998 survey report. Survey on reduction in environmental effect of greenhouse effect gas by the transfer of environmental technology in the Asian region; 1998 nendo chosa hokokusho. Asia chiiki ni okeru kankyo gijutsu iten ni yoru onshitsu koka gas no kankyo eikyo keigen ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Effects of the transfer of environmental technology were studied as an important policy for control of greenhouse effect gas in the Asian region. As schemes, those that were drew up by NEDO, JICA, etc. now exist and are used also in Japan. However, for the control of greenhouse effect gas emission which is expected to rapidly increase in future, it is indispensable to construct a new powerful and effective scheme in which technology transfer and fund to be given are organically connected. Especially, in the U.S., etc., the assistance of developing countries of a huge amount of money such as Japan's ODA is not extended. However, they position the environmental technology as an important strategy and is developing the assistance of developing countries by technology transfer and eco-business of private companies. Also in the eco-business field, the environment-related technology of Japanese companies is used in Asian developing countries, with expectations of its being a new business with international competitive strength. This is the subject for the whole global environment, and an important subject also for Japan which requires the creation of a new business field with international competitive strength. (NEDO)

  2. Fiscal 1993 study of engineering for making areas prosperous using natural energy; 1993 nendo kankyo chowagata green techno system no kokusai kyoryoku model ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    The paper studied the engineering for activating areas using natural energy. A system has started in which electric power companies purchase surplus electric power from the natural energy use power generation such as the wind power and photovoltaic power generation, etc., and a lot of local self-governing bodies in the country plan `projects to promote town` using the system. However, few engineers and makers can plan `a project to promote town,` making effective use of natural energy which is fickle. Therefore, first, the paper arranged the actual status mostly of the cases of `the projects` using natural energy which have been carried out in the country. Next, the trend of the natural energy utilization technology in countries including the U.S. was described. Moreover, assuming model areas in Japan for working out a concept of model projects on the natural energy utilization and town promotion, a concept was proposed making full use of the utilization technology which has now usability. Arrangement is being made for conditions for the full scale spread as seen in the subsidy system for general users. 3 refs., 176 figs., 61 tabs.

  3. Report on achievements in fiscal 1998. Survey on environmental effects from photovoltaic power generation systems; 1998 nendo daikibo taiyoko hatsuden system no kankyo eikyo ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Different environmental effects may be assumed when large-size photovoltaic power generation systems are installed in vast unutilized lands including deserts. Knowledge having been acquired to date has been put into order on the following subjects as the pre-survey thereon: (1) environmental characteristics of desert areas, (2) discussions on environmental effects from (a) environmental assessment viewpoints, (b) contents of the environmental assessment, and (c) environmental assessment institutions, and (3) the survey policy. In discussing the environmental characteristics, it is revealed that desert areas are neither sterile nor unused, but pasturage and agriculture have been carried out in historical and traditional ways. In discussing the environmental effects, it was recognized that surveys on primary and secondary effects on the environmental are indispensable. With regard to the institutions, there are countries who have and have not the institutions even among the OECD member states. In addition, it was known that environments in the desert areas vary greatly according to the particular areas, whereas there are possibilities of installing the facilities because the effects of the facility locations on the environment are various. Therefore, it was decided to start from the case studies in locations of different types. (NEDO)

  4. Survey on chemical engineering technologies for the global environmental protection; Chikyu kankyo hozen no tame no kagaku kogakuteki taisaku gijutsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    1993-03-01

    The present paper suggests chief measures to suppress and reduce global greenhouse gases. Under the control of artificial environments such as bioreactor, hydroponics and vegetable factory, a very high fixing rate of CO2 can be obtained, but CO2 generation accompanying electric power consumption is also large. It is preferable to use methane as resource by reforming reactions or selective oxidative reaction. In the recovery technique of fluorocarbon, 100% recovery is desirable. Techniques for decomposing recovered fluorocarbon and converting it to harmless material are the most backward ones. Understanding of essential structural relationship of coal is necessary for establishing combustion technique for the reduction of N2O. The integrated power generation system composed from solid electrolyte type fuel cell and coal-gasifying process, high-performance, superheat pump system form scientific technology imposing no burden on the global environment. Establishment of purification technique for industrial- or living-related drain inflowing to a closed water area system, establishment and reinforcement of inspection system for oil spill in the oceans in a global scale are required. 240 refs., 63 figs., 30 tabs.

  5. Report of 'Survey on Asian environmental information networks'; 'Asia kankyo joho network chosa' ni kansuru hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    This project is implemented to survey the current statuses and future trends of the Asian district environment-related information networks, for the (research cooperation project for development of environmental condition measuring laser radar systems), being promoted by NEDO. First, current statuses of the network names, managing organizations, user numbers, conditions of use, protocols for use, service conditions, major domestic nodes and internationally connected conditions are surveyed mainly for internet-connected networks, for surveying the current statuses and future trends of the research networks in Asian countries. Second, current statuses in Indonesia of the network names, managing organizations, user numbers, conditions of use, protocols for use, service conditions, domestic node sites and managing organizations, charge systems and institutions, types/reliability/ stability of the circuits, and conditions of restriction of use, if any, for surveying the current statuses and future trends in Indonesia. Third, conditions of and needs for network utilization by researchers for Asian district environments. (NEDO)

  6. Fiscal 1998 survey report. Survey on method of environmental-impact assessment in wind power development; 1998 nendo furyoku kaihatsu ni okeru kankyo eikyo hyoka shuho chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    With the purpose of preparing the main points of 'environmental-impact assessment guidelines for wind power developments (draft)', examples of environmental-impact assessments, related laws and regulations in Japan and abroad were collected, and rearranged in respect to requirements in environmental-assessments, concrete procedures, survey/projection/assessment method, summarisation of results, etc. It was clarified, for example; in a large-scale wind power development, it can be dealt with by choosing items and contents on the assumption that a land area is developed; in a small-scale development, there is basically no need of considering the possible effect of the construction work; and, as far as noise, vibration and the ecosystem (plants/animals) are concerned, however, the characteristics of the site be taken into consideration. Objects for general assessment are noise, low-frequency air vibration, radio wave interference, the ecosystem (plants and animals) and the landscape. The guideline draft is constituted of (1) basic items, (2) overview of the area, (3) determination of items for environmental-impact assessment and (4) research, prediction, assessment, conservation measures and follow-up research; in the basic items, importance of preliminary consideration was emphasized, as were priority/simplification, implementation of environmental conservation measures, and implementation of follow-up research. (NEDO)

  7. International symposium on environmental impacts of advanced alternative to CFC; CFC shinki daitai busshitsu no kankyo eikyo ni kansuru kokusai symposium hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-07

    The international symposium on environmental effects of new CFC substitutes was held in Tsukuba City, Ibaraki Pref. on February 7-9, 1996, and 19 papers were made public. In Session 1 (Plenary lecture), reports were made on Global warming and climate change: a review of recent studies; Stratospheric ozone, CFCs, and CFC-substitutes: an update, etc. In Session 2, Measurements of OH rate constants for advanced refrigerants as well as HCFCs and HFCs; The reaction rate of CFC alternatives with OH radical; Experimental and estimated rate constants: reactions of hydroxyl radicals with several halocarbons, etc. In Session 3, Measurement of uptake coefficients of some acetyl halides and fluorinated ethers into water; Mass transfer at the air/water interface: removal processes of halocarbonyl compounds; Heterogeneous reactions of fluorinated ethers on allophane or titanium dioxide, etc. In Session 4, papers were reported on model calculations relating to the global warming.

  8. Ecological concepts in recent polymer technology. Part4. Eco-friendly water-absorbing polymer; Kankyo ni chowa shita kyusuisei kobunshi

    Energy Technology Data Exchange (ETDEWEB)

    Kunioka, M.

    1997-07-01

    As an application example of water-absorbing polymers with biodegradability, it was expected to be applied to soil improvement agents used in planting trees in deserts, besides physiological napkins, paper diapers and medical materials. In this paper, water-absorbing polymers with biodegradability such as natural polymers, petroleum-made polymers and polymers synthesized by radiation cross-linking and chemical cross-linking were introduced. Moreover, a kind of water-absorbing polymers developed by the authors, made from polyamino acid synthesized by microbes, was introduced. In the method developed by the authors, the cross-linking structure could be made by combining PGA carboxyl groups and various amino groups of diamine using carbimide with water solubility. As for this method, all of reactions could be conducted in water and catalytic replacement was not necessary, moreover, hydrogel with the water-absorbing rate of 200 to 1500 times could be produced. 44 refs., 3 figs., 1 tab.

  9. New energy vision at Sabae City. Toward realization of 'environmental international city'; 2001 nendo Sabae shi chiiki shin energy vision. Kankyo kokusai toshi Sabae no jitsugen ni mukete

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-03-01

    With an object of accelerating introduction of and uplifting consciousness on new energies at Sabae City in Fukui Prefecture, a new energy vision was put into order based on the result of the initial stage investigation having been performed in the previous fiscal year. Solar light and solar heat energies will be introduced positively into public facilities, and at the same time works will be implemented to accelerate the proliferation thereof into general households. The target of introduction by the year 2010y is set to 2,600 kW by photovoltaic power generation, and the introduction thereof is planned to schools, nursery schools, municipality operated houses, and unattended facilities. With regard to solar heat water warmer, the present proliferation rate of about 7.3% will be raised to 15%. Regarding wastes generated from industrial areas, efficient energy extraction by thermal recycling is intended on the assumption of suppression of wastes generation, their re-use, and recycling. Systems may include the bio-gas system, cogeneration, and recovery of energies from plastics wastes. For acceleration of proliferation of new energies in general, promotion of introduction will be achieved on mini-wind power generation, small hydroelectric power generation, and fuel cell automobiles. (NEDO)

  10. Research and development cooperation project on environmental measurement using laser radar in fiscal 1994; Kankyo keisokuyo laser radar no kaihatsu ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    The paper outlined activities in fiscal 1994 in the R and D cooperation project on a laser radar for environmental measurement. In the activities in fiscal 1994 of `the ODA laser radar development committee,` the committee held four meetings, two field surveys were carried out, and two researchers were invited from Indonesia. In the field survey, the environment in Jakarta city was investigated in terms of changes in population and number of the cars registered. Further, from data collected during 1994-1998 in the central Jakarta city, the following were made clear: the trend of a decrease in SO2, the trend of a rapid increase and an excess of NO2 content over the environmental standard, the status of pollution of which the level is close to the upper limit of the environmental standard of dust, etc. In the meeting of the policy study for the field survey at LIPI headquarters, Japan proposed a system which is constituted of a difference absorption laser radar, two Mie scattering laser radars, and a central processing unit. The sites proposed were studied in cooperation with Indonesia. 40 refs., 65 figs., 9 tabs.

  11. Research and development cooperation project on environmental measurement using laser radar in fiscal 1993; Kankyo keisokuyo laser radar no kaihatsu ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    As one of the international research cooperation projects, the research cooperation in developing laser radar for environment measurement started between Japan and Indonesia. The project is scheduled to be carried out in a 4-year plan starting fiscal 1993. In fiscal 1993, conducted were negotiations with Indonesia on its implementation and a field survey. Between January 6 and 15, 1994, the first field survey was made in terms of topography, climate, road network and traffic situation of Jakarta city, and the proposed sites for installation were reported. The paper also introduced the reception system on the Indonesian side and a request for technical learning through stay in Japan. The second field survey was conducted between February 27 and March 6, 1994. Indonesia requested that they want to make laser radar observation not only for the local area, but the one that covers industrial areas, central urban areas and residential areas. Incidentally, there was an opinion that it is important to elucidate the pollution mechanism. 19 refs., 43 figs., 6 tabs.

  12. Assessment of global environmental impacts by utilizing methodology of LCA on solar water heater for dwellings; LCA shuho ni yoru taiyonetsu onsuiki no kankyo fuka hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Kamoshida, J [Shibaura Institute of Technology, Tokyo (Japan); Asai, S [Yazaki Corp., Tokyo (Japan)

    1997-11-25

    CO2 emission was quantified through the life cycle of a solar water heater to assess its environment impact. Although LCA (life cycle assessment) originally sums up I/O of all materials and energy through the whole life cycle of a product to examine environment impact, this assessment was carried out for only CO2. Calculation of CO2 emission assumed a natural circulating solar water heater of 200 l in effective hot water capacity, 2.78m{sup 2} in effective collecting area, and 0.5 in average annual collecting efficiency of total solar radiation, and an auxiliary city gas heat source for compensating insufficient heat quantity. The total CO2 emission in the life cycle of a solar water heater was obtained from an industrial association table assuming the life cycles of 10 and 20 years. CO2 emission was estimated to be 5407.1kg-CO2 and 10665.2kg-CO2 for 10 and 20 years, respectively. CO2 emission due to city gas was largest in the total CO2 emission in the life cycle. As a result, for reduction of CO2 emission due to a solar water heater, improvement of equipment efficiency was most important. 6 refs., 5 figs., 3 tabs.

  13. Survey report on an environmental harmony type production system of chemical products; Kankyo chowagata kagaku seihin seizo system ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    As part of establishing an environmental harmony type production system of chemical products, study and survey were made on PET bottles. Using the life cycle analysis method (LCA), a study was made for proposing a material recycle (MR) method which is environmentally and economically excellent in the stage of recycling waste PET bottles. The total cost of recycling can be reduced by 34% supported by a decrease in equipment cost and improvement in yield if there is no mixture of foreign substances such as aluminum caps and PVC bottles. However, the ratio of the amount obtained from the reduction to the total production cost is small, and it is necessary to take measures from a viewpoint of the cost in a total production process and environmental loads. In a survey in Kawaguchi city, PET bottles discharged from the business sector occupied 41% of all the discharge amount. In a survey in Yokohama city, very important data were obtained on PET bottles appointed as the second type under the recycle law. The quality of PET bottles to be brought to the recycling plant is important for effectively processing PET bottles in MR method. For achievement of MR which is low in cost and small in environmental load, needed were cooperation by citizens, the shipping management system in autonomous government, and changes in design and material quality to be made by the industrial circle. 8 refs., 64 figs., 68 tabs.

  14. FY 2000 report on the results of the research study of environmental information network; 2000 nendo kankyo joho network ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Described herein are the FY 2000 results of the research study on environmental information network formation. The Internet is experiencing an explosive increase in volume of information distributed therethrough. This is accompanied by increased problems related to information searches, information exchange security and information-reliability guarantees. First in demand are excellent portal sites, and second are sites that can be relied on to responsibly provide information. Cooperation with the real world off the Net is of particular importance, because the operating organizations, e.g., sites, will lose their raison deter, unless they clarify their unique abilities and characteristics under the tendencies towards broadened bands and ubiquity. The public sector, on the other hand, is highly reliable, accumulates a large volume of information, and has high network capacity. It has various functions, e.g., supporting the activities pertaining to ISO standards, and promoting the activities, e.g., those for educational programs, interdisciplinary exchanges by researchers, and matching of various organizations. The international cooperation for environmental information needs construction and operation of the networks, and construction of the infrastructures in the developing countries. If information becomes more ubiquitous, a chaotic sea of information will result. NEDO is strongly obliged to serve as the beacon, because it has established a huge volume of environment-related technologies, information, and networks. (NEDO)

  15. Development of the molecule imprint polymer recognized peculiarly the environment hormone; Kankyo horumon wo tokuiteki ni ninshiki kanona bunshi inpurinto porima no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, M. [Kagoshima Univ., Kagoshima (Japan)

    2000-08-05

    The molecule imprint method (MI method) is the technique that makes the binding site which is complementary with the mold molecule in the polymer using a recognized object molecule as a mold, and gives the selectivity of the purpose in the polymer tailor-made like. The environment hormone is represented in the chemical substances (phthalic ester, bisphenol A, alkylphenol) which are produced from plastics or dioxins when refuse is burnt, and the organochlorine compounds (PCB, DDT, HCH) which are included in agricultural chemicals or chemicals besides. Whitcombe et al. report with respect to the MI polymer of which the recognition target is 2,3,7,8 tetrachlorodibenzodioxne (TCDD) which has the strongest toxicity in the dioxins. As an example of the MI method which targeted the other environment hormone, there is the research with respect to PCB by Hosoya et al. (NEDO)

  16. Report of 'Survey on Asian environmental information networks'; 'Asia kankyo joho network chosa' ni kansuru hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    Information systems, mainly aided by computers, are becoming increasingly important, contributing to development of wide areas of societies and economics, to begin with. However, few developing countries have established sufficient information systems, in spite of their strong desires to do so, which will further widen the gap between them and advanced countries, where these systems are acceleratedly advancing. Given these situations, Center of International Cooperation for Computerization (CICC) has been implementing various projects for providing assistance to and cooperation with oversea countries which are trying to develop information systems. This report summarizes the project, which CICC has been commissioned by Optoelectronic Industry and Technology Development Association as part of the cooperation programs, for establishing the Asian environmental information networks. It outlines the research cooperation project for the environmental networks, results of the 4 on-the-spot surveys, 2 occasions for inviting researchers to Japan, and construction of the internet and Asian environmental information network systems. (NEDO)

  17. Research on improvement of indoor air quality and prevention of fungi; Shitsunai kuki kankyo no kaizen to kabi boshi ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, Tatsuaki [Ochanomizu University, Tokyo (Japan). Faculty of Human Life and Environmental Sciences

    1998-12-16

    An epidemiological survey survey was performed to elucidate the fungal flora of a dwelling house. The measurements were carried out in an apartment in Yokohama from Jul. 1996 to Dec. 1997. Fungi were isolated from 106 sampling points (the surface of the walls, floors, etc.) with sterile stamps. It was proved that Cladsporium, Penicillium, Eurotium, and Yeasts showed characteristic distribution. Especially Cladsporium was not isolated from the spring to the summer, but increased in the autumn. In addition to the survey, experiments on fungal growth temperature (13, 20, 25, 30, 36, 42 degree C) and water activity (A w 0.75{approx}0.97) were carried out. Cladsporium grew well in 13, 20, 25 and 30 degree C, but didn't grow in 36 and 42 degree C. In addition, the growth activity of Cladsporium was down below Aw 0.91. Eurotium was isolated from under Tatami, where it has an unchanging temperature and relative humidity. Yeasts preferred very high humidity. It was concluded that environmental factors such as temperature and relative humidity related to the growth of fungi. (author)

  18. Fiscal 1998 survey report. Survey on method of environmental-impact assessment in wind power development; 1998 nendo furyoku kaihatsu ni okeru kankyo eikyo hyoka shuho chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    With the purpose of preparing the main points of 'environmental-impact assessment guidelines for wind power developments (draft)', examples of environmental-impact assessments, related laws and regulations in Japan and abroad were collected, and rearranged in respect to requirements in environmental-assessments, concrete procedures, survey/projection/assessment method, summarisation of results, etc. It was clarified, for example; in a large-scale wind power development, it can be dealt with by choosing items and contents on the assumption that a land area is developed; in a small-scale development, there is basically no need of considering the possible effect of the construction work; and, as far as noise, vibration and the ecosystem (plants/animals) are concerned, however, the characteristics of the site be taken into consideration. Objects for general assessment are noise, low-frequency air vibration, radio wave interference, the ecosystem (plants and animals) and the landscape. The guideline draft is constituted of (1) basic items, (2) overview of the area, (3) determination of items for environmental-impact assessment and (4) research, prediction, assessment, conservation measures and follow-up research; in the basic items, importance of preliminary consideration was emphasized, as were priority/simplification, implementation of environmental conservation measures, and implementation of follow-up research. (NEDO)

  19. Research and development cooperation project on environmental measurement using laser radar in fiscal 1995; Kankyo keisokuyo laser radar no kaihatsu ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    For the purpose of contributing to the environmental management in Indonesia, Japan made R and D of a laser radar to measure the urban air pollution and an environmental network jointly with Indonesia in compliance with the actual situation of the country. At present, in developing countries, air pollution is becoming a big problem because of increases in population and in energy consumption in urban areas according to the industrial/economic growth. As for the laser radar, it is an active sensor with laser as light source and can observe in high resolution the three-dimensional space distribution such as density and composition of air pollutants. Japan is a leader in the development of laser technology which is a core technology for the laser radar and the preceding research. The equipment is installed at several points of urban areas in Indonesia, and at the same time, the observation network is constructed to collect, analyze and process data at the central processing center. This is a 4-year plan from fiscal 1993 to 1996. In fiscal 1995, negotiations with Indonesia and field surveys were conducted to determine sites for installation. A plan for system improvement was also decided on. 38 refs., 24 figs., 14 tabs.

  20. Research cooperation of the development of laser radar for environmental measurements; Kankyo keisokuyo laser radar no kaihatsu ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Research and development of the laser radar for measuring the air pollution in urban areas and the environmental information network have been conducted through the cooperation with Indonesian researchers. A measurement system suitable to actual situation of Indonesia has been constructed. In FY 1996, some works have been conducted as in the final fiscal year. To set the laser radar for environmental measurements and to make a plan of measurement research, conditions of air pollution in Indonesia and setting places of systems have been investigated. Opinions for the cooperation research have been exchanged with Indonesian researchers. Actual trends of the environmental measurements technology using laser radar have been surveyed. Indonesian researchers have been invited to learn operation and data processing of the system. One unit of MIE diffusion laser radar system has been designed and fabricated, and an additional data processing program has been made. The system has been delivered to Jakarta and installed. After the adjustment, performance tests have been conducted to complete the construction of the system. 3 refs., 72 figs., 10 tabs.

  1. Feasibility design of a floating airport and estimation of environmental forces on it; Futaishiki kuko no sekkei to kankyo gairyoku no suitei ni kansuru kento

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, Y.; Tabeta, S.; Takei, Y. [Yokohama National University, Yokohama (Japan). Faculty of Engineering

    1996-12-31

    A rough design was performed on a floating airport. On this floating structure, environmental external force was estimated, mooring design was carried out, and discussions was given on the position retaining performance important for airport functions and behavior of the floating structure. The discussion was given on cases that the airport is surrounded and not surrounded by floating breakwaters. A floating structure which becomes super-large in size requires considerations on force due to sea level gradient as a result of a tide. Deriving flow condition changes and force acting on the floating structure simultaneously by using numerical calculations makes it possible to estimate current force given with considerations on influence of the flow conditions created by installing the floating airport. Estimation was carried out by using a zone dividing method on wave drifting force acting upon the floating airport. As a result, it was found that installing floating and permeating type breakwaters can reduce the wave drifting force acting on the floating airport. The wave drifting force working on the floating airport can be reduced by installing the floating and permeating type breakwaters to lower levels than when no such breakwaters are installed. The airport may be moored with less number of fenders when the fenders of the same type are used. 18 refs., 10 figs., 5 tabs.

  2. Evaluation of building envelopes from the viewpoint of capability of controlling thermal environment; Onnetsu kankyo chosei noryoku ni yoru kenchiku gaihi no hyoka no kokoromi

    Energy Technology Data Exchange (ETDEWEB)

    Umeda, K; Ono, S [Taisei Corp., Tokyo (Japan); Shukuya, M [Musashi Institute of Technology, Tokyo (Japan)

    1996-10-27

    The ability that architectural space improves the thermal environment in comparison with outdoor environment is called the `capability of controlling thermal environment.` As the value becomes higher, the indoor thermal environment is more improved. In this paper, the controlling capability of six building envelopes with different window systems was compared. The heat transfer in the wall and window system is approximated using a lumped mass model of heat capacity to obtain a heat balance equation and combined with the heat balance equation in indoor air for backward difference. The wall surface temperature and indoor air temperature in a calculation model are then calculated. A radiation absorption coefficient is used for mutual radiation on each wall. In the model, the adjoining room or first- and second-floor rooms were made the same in conditions as the model on the assumption that the one-side lighted office in an RC reference floor is in the non-illumination and non-airconditioning state. In summer, the controlling capability remarkably varies depending on the window system. For the window facing the south, the annual capability is more advanced than in other directions and the indoor thermal environment is improved on the average. 7 refs., 12 figs., 1 tab.

  3. Current status and prospect on photo-catalyst application in environmental problems; Kankyo mondai ni okeru hikari shokubai oyo no ganjo to tenbo

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, T. [Toto Ltd., Kitakyushu (Japan)

    1995-09-30

    This paper summarizes application of photo-catalysts in environmental problems. The paper lists examples of the application in residential environments. Photo-catalytic decomposition is possible by using ultraviolet rays contained in room illumination if the bacterial presence is sparse. The examples thereof may be cited as follows: if colon bacilli are suspended on a tile with TiO2 photo-catalyst sintered in it and exposed to room illumination, the bacteria are disinfected; using photo-catalysts in a bathroom suppresses deposition of Pseudomonas aeruginosa; a photo-catalyst tile (TiO2 loaded with Cu) and light irradiation reduce intensity of tobacco smoke odor; and adsorbents may be used simultaneously if intermediate products are odor generating substances. The examples of applying photo-catalysts to regional environments may be quoted as follows: growth of algae in a Petri dish is suppressed by presence of Cu loaded TiO2 under room illumination; this leads to an expectation on its effect in a relatively clean water environment; glass beads loaded with a TiO2 photo-catalyst placed in a gold fish breeding tank reduces turbidity, the number of colon bacilluses, and COD value; and the mortality in gold fish shows no change. With an objective of application to exterior building materials, photo-catalyst applied tiles were left outdoors for 160 days. Nitric acid ions were detected that are thought to have been generated by decomposition of microorganisms that have deposited on the tiles. 6 refs., 5 figs., 3 tabs.

  4. Energy, oil and global environmental problems towards21st. century. 21 seiki ni mukatte no energyter dot sekiyuter dot chikyu kankyo mondai

    Energy Technology Data Exchange (ETDEWEB)

    Ishikawa, K [Mitsubishi Oil Co. Ltd., Tokyo (Japan)

    1990-09-01

    The world energy demand is increasing with the development of the world economy and the improvement of the life level. In view of the future economic development and population growth, the world energy demand will considerably increase especially in the LDCs. Since the oil crisis, saving of energy and material were effectively executed, thus significantly reducing the energy requirement per GNP. However, in the recent several years, the conciousness of energy has become diluted, causing considerable consumption in larger size and higher grade products, thus increasing the non-industrial and transportation consumption. This report considered the effective use of energy and the nuclear application. It is to be noted that the accident frequency in the Japanese nuclear plants is much less than the other countries. The coal utilization requires further technical development in view of the environmental problems. Other substitutible energies are all weak in competition and cannot be expected utilizable in large scale for the time being. This report also referred to the oil problem. 9 figs.

  5. Decay of 57Ni

    International Nuclear Information System (INIS)

    Santos Scardino, A.M. dos.

    1987-01-01

    The decay of 57 Ni to 57 Co was studied by gamma ray spectroscopy using both singles and coincidence spectra. The sources were obtained with the 58 Ni (Y,n) 57 Ni reaction. Natural metallic nickel was irradiated in the bremsstrahluhng beam of the linear accelerator of the Instituto de Fisica da Universidade de Sao Paulo with 30 MeV electrons. The singles espectra were taken with 104 cc HPGe detector and the coincidences espectra with 27 and 53cc Ge(Li) and 104 cc. HPGe detectors. The energies of transitions that follow the 57 Ni decay were measured using 56 Co as standard (which was obtained by (Y,np) reaction in 58 Ni) and taking into account the cascade cross-over relations. (author) [pt

  6. Bridging exchange bias effect in NiO and Ni(core)@NiO(shell) nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Rinaldi-Montes, Natalia, E-mail: nataliarin@gmail.com [Departamento de Física, Universidad de Oviedo, E-33007 Oviedo (Spain); Gorria, Pedro [Departamento de Física & IUTA, EPI, Universidad de Oviedo, E-33203 Gijón (Spain); Martínez-Blanco, David [Servicios Científico-Técnicos, Universidad de Oviedo, E-33006 Oviedo (Spain); Fuertes, Antonio B. [Instituto Nacional del Carbón, CSIC, E-33080 Oviedo (Spain); Fernández Barquín, Luis [CITIMAC, Facultad de Ciencias, Universidad de Cantabria, E-39005 Santander (Spain); Puente-Orench, Inés [Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza and Institut Laue-Langevin, BP 156, F-38042 Grenoble Cedex 9 (France); Blanco, Jesús A. [Departamento de Física, Universidad de Oviedo, E-33007 Oviedo (Spain)

    2016-02-15

    Among all bi-magnetic core(transition metal)@shell(transition metal oxide) nanoparticles (NPs), Ni@NiO ones show an onset temperature for the exchange bias (EB) effect far below the Néel temperature of bulk antiferromagnetic NiO. In this framework, the role played by the magnetism of NiO at the nanoscale is investigated by comparing the microstructure and magnetic properties of NiO and Ni@NiO NPs. With the aim of bridging the two systems, the diameter of the NiO NPs (~4 nm) is chosen to be comparable to the shell thickness of Ni@NiO ones (~2 nm). The EB effect in Ni@NiO NPs is attributed to the exchange coupling between the core and the shell, with an interfacial exchange energy of ΔE~0.06 erg cm{sup −2}, thus comparable to previous reports on Ni/NiO interfaces both in thin film and NP morphologies. In contrast, the EB detected in NiO NPs is explained in a picture where uncompensated spins located on a magnetically disordered surface shell are exchange coupled to the antiferromagnetic core. In all the studied NPs, the variation of the EB field as a function of temperature is described according to a negative exponential law with a similar decay constant, yielding a vanishing EB effect around T~40–50 K. In addition, the onset temperature for the EB effect in both NiO and Ni@NiO NPs seems to follow a universal dependence with the NiO crystallite size. - Highlights: • Comparison of the exchange bias effect in NiO and Ni(core)@NiO(shell) nanoparticles. • Universal temperature dependence of the exchange bias effect. • Suggested similar physical origin of the effect in both systems. • Size and crystallinity of the NiO shell hold the key for exchange bias properties.

  7. OpenNI cookbook

    CERN Document Server

    Falahati, Soroush

    2013-01-01

    This is a Cookbook with plenty of practical recipes enriched with explained code and relevant screenshots to ease your learning curve. If you are a beginner or a professional in NIUI and want to write serious applications or games, then this book is for you. Even OpenNI 1 and OpenNI 1.x programmers who want to move to new versions of OpenNI can use this book as a starting point. This book uses C++ as the primary language but there are some examples in C# and Java too, so you need to have about a basic working knowledge of C or C++ for most cases.

  8. Change of environmental factors in different site which effect the conversion efficiency of photovoltaic module. Comparison of the environmental factors in Shinjuku Tokyo with the one in Chino Nagano; Kotonaru chiten ni okeru taiyo denchi no henkan koritsu ni eikyo wo ataeru kankyo inshi no henka. Tokyoto Shinjukuku to Naganoken Chinoshi no kankyo inshi no hikaku

    Energy Technology Data Exchange (ETDEWEB)

    Higuchi, T.; Tani, T.; Hirata, Y.; Inasaka, T. [Science University of Tokyo, Tokyo (Japan)

    1997-11-25

    Environmental factors affecting conversion efficiency of solar cells were measured in Tokyo and Nagano to comparatively study the difference. In the study, measurement was made of intensity of global solar radiation on an inclined surface (insolation intensity), ambient air temperature, and distribution of spectral solar radiation at the two points. Also measured were output characteristics of polycrystal silicon solar cell modules and amorphous silicon solar cell modules. The result of the comparative analysis was as follows: The annual inclined global solar radiation amount integrated in 1996 is 27% more in Nagano than in Tokyo. The weighted average insolation intensity in Nagano is 0.09 kW/m{sup 2} higher in Tokyo. The weighted average cell temperature in Nagano is 4degC lower than in Tokyo. The effective spectral ratio in Nagano is 1-2% lower both in polycrystal Si and amorphous Si than in Tokyo. Thus, it was inferred from that environmental factors are different that conversion efficiencies of photovoltaic modules were different. 6 refs., 5 figs., 5 tabs.

  9. FY 2000 report on the survey project on the environmentally friendly energy community, excluding mostly projects on electric power generation. Survey project on the environmentally friendly energy community in the Nagoya area; 2000 nendo kankyo chowagata energy community chosa jigyo 'shutoshite hatsuden jigyo ni kakawaru mono wo nozoku' chosa hokokusho. Nagoya chiiki ni okeru kankyo chowagata energy community chosa jigyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The paper studied the working-out of the basic plan on the RPF (refuse paper and plastic fuel) production business in the area mainly including Nagoya city and of the business profitability. RPF is a solid fuel made by grinding, mixing and pressurizing paper and plastics in appropriate sizes. Its shape and calorific value can be adjusted according to the needs. In the Nagoya area, the demand for RPF is more than the supply, and therefore a much larger amount of RPF is in need. In Phase 1, business was studied for paper and plastics in the container packing paper waste and business-derived general waste. As a result, the RPF production amount was 21,000 t/y, which is equivalent to the effect of reduction of the same amount of coal. As to the profitability, it was made clear that the business can be profitable if collecting 41,400 yen/ton as the re-commercialization cost. In Phase 2, the design of the facilities was made for the larger-sized commercialization by adding industrial waste plastics to the waste in Phase 1. (NEDO)

  10. Report on the fiscal 1993 investigational study of the environmental technology development trend in Japan. Trend survey of the introduction policy of environmentally friendly products; 1993 nendo Nippon ni okeru kankyo gijutsu kaihatsu doko nado ni kansuru chosa kenkyu hokokusho. Kankyo chowagata seihin no donyu hosaku nado doko chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-05-01

    An investigation was conducted into the systematical scheme for the introduction and promotion of environmentally friendly products mostly to the U.S., Europe and China. In the U.S., the introduction policy is given to one and all fields of the industry. The introduction policy of the U.S. has a characteristic that the introduction is left to the market principle by DSM or permit dealing, etc. except the preferential tax system and systematical finance in which the government is concerned. The policy of European countries is characterized by the idea preceding, standards or rules are first given, and the whole is pushed on to them. Accordingly, it seems that there is few atmosphere of expecting to receive the government side economic incentives from the corporate side. Legal regulations on the environment in China were prepared in a comparatively early time (1979), but the supervision of obeying the regulations and the appearance/spread of environmentally friendly product menus have just started. Accordingly, as the introduction policy on environmentally friendly products, there was found nothing valuable but the regulations. 12 refs., 3 figs., 15 tabs.

  11. Gd-Ni-Si system

    International Nuclear Information System (INIS)

    Bodak, O.I.; Shvets, A.F.

    1983-01-01

    By X-ray phase analysis method isothermal cross section of phase diagram of the Gd-Ni-Si system at 870 K is studied. The existence of nine previously known compounds (GdNisub(6.72)Sisub(6.28), GdNi 10 Si 2 , GdNi 5 Si 3 , GdNi 4 Si, GdNi 2 Si 2 , GdNiSi 3 , GdNiSi 2 , Gd 3 Ni 6 Si 2 and GdNiSi) is confirmed and three new compounds (GdNisub(0.2)Sisub(1.8), Gdsub(2)Nisub(1-0.8)Sisub(1-1.2), Gd 5 NiSi 4 ) are found. On the base of Gd 2 Si 3 compound up to 0.15 at. Ni fractions, an interstitial solid solution is formed up to 0.25 at Ni fractions dissolution continues of substitution type. The Gd-Ni-Si system is similar to the Y-Ni-Si system

  12. Study of promotion of CO2 fixation by the environmental improvement in the coral reef area; Kansho chitai ni okeru kankyo kaizen ni yoru CO2 kotei sokushin no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Maruoka, T.; Ishitani, H.; Matsuhashi, R.; Yamada, K.; Komiyama, H.; Kraines, S. [The University of Tokyo, Tokyo (Japan). Faculty of Engineering

    1997-01-30

    A study was conducted on how to fix CO2 in the ocean using coral reefs. Coral reefs have extremely high primary productivity ( production quantity of organic matters by photosynthesis) and are expected to be resources to fix CO2 when the quantity of photosynthesis exceeds the quantity of CO2 emitted in association with formation of calcium carbonate skeleton. If organic substances produced in coral reefs are well carried into the open sea, those are settled down on deep beds, which enables the storage into the ocean. At the coral reef floating in the ocean, it is not very deep inside and the seawater stays there, but it has a steep depth outside. By the numerical calculation, an examination was made on how the waterflow changes when making the flow path of seawater between the inland sea and open sea. From the actual calculation of an atoll, it was found that seawater comes in and out from the open sea to the inland sea near the opening of the atoll in accordance with the high tide and ebb tide, but the water stays at the deep bottom of the atoll. When installing a channel with a 10m depth at the portion where the water flows softly, the seawater was actively exchanged. 6 refs., 4 figs.

  13. Fiscal 1998 research report. Research cooperation on car energy and environmental technology based on ITS technology in China; 1998 nendo seika hokokusho. Chugoku ni okeru ITS gijutsu wo mochiita jidosha energy kankyo gijutsu ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This research aims at preparation of the car energy/environmental vision based on ITS (intelligent transport system) technology in China, enhancement of the transport planning ability of Qinghua University, and promotion of effective energy use in China. The following activities were carried out concretely: Survey on the actual traffic situation by Qinghua University, analysis of environment deterioration factors based on the survey result, estimation of a traffic environment improvement effect, study on traffic flow simulation technique based on traffic engineering, and study on traffic planning technique. As the diffusion strategy of ITS along Chinese circumstances, standardization and improvement of a multi- modal traffic system, navigation and its application system, and ETC (electronic toll collection) system are promising. Expectation for Japan and Japanese roles are as follows: Improvement of signal control, provision of information systems such as navigation, discussion on ITS technology such as ETC with Chinese specialists, and feasibility study on introduction of ITS technology for every Chinese district. (NEDO)

  14. Fiscal 2000 survey report. Research on laser-aided photolysis of environmental pollutant in liquid phase system; 2000 nendo ekisokei ni okeru kankyo osen busshitsu no laser hikari bunkai gijutsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Experiments were conducted on laser-aided decomposition and removal of chemical substances in liquid phase systems on the assumption that there existed chemical pollutants in wastewater or water after washing burned ash. The aim of the research was to split carbon-chlorine bonds and break benzene rings, the two being the cause of harmfulness, and experiments were conducted using chlorophenol. The photolytic lasers were ArF excimer laser and KrF excimer laser. It was found that the reduction rate of chlorophenol in a water solution under excimer laser irradiation was 1.7 times higher under KrF laser than under ArF laser. For mediums other than water, isopropanol was used, more convenient than chlorophenol in separating organic pollutants from burned ash and the like. In this case, organochlorine compounds were generated at the beginning, but they disappeared when irradiation was prolonged. It was demonstrated that the laser-aided environmental cleaning technology would find a very wide scope of application as an effective photolytic means. (NEDO)

  15. New energy visions for the Town of Naie district. Human-friendly Town of Naie City by environment-friendly energies; Naiemachi chiiki shin energy vision. Kankyo ni yasashii energy ga tsukuru hito ni yasashii machi Naie

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The new energy visions are drawn for Town of Naie, Sorachi-gun in Hokkaido, where the industrial sector (manufacturing industries) consumes more than 60% of the total energy consumption. By energy type, oil and others account for 80%. When arranged in the order of expected recoverable quantity, the new energies for the town include utilization of solar energy, photovoltaic power generation, wind power generation, and utilization of wastes, biomass energy (agricultural products) and snow energy. The basic guidelines for introduction of new energies are for health and welfare, clearing and utilization of snow, environmental education and bringing up talented persons, supporting the related entrepreneurs, and integration of new energy with promotion of energy-saving movement. The priority projects the town plans to promote include utilization of biogas and temperature-differential energy for the town's water purification center; foundation of the Naie eco-school; and drawing conceptions for utilization of underground heat, utilization of low-temperature and snow/ice energy, co-energy around the spa of Naie, and mega-solar and eco-park at the Sorachi housing complex. (NEDO)

  16. New energy visions for the Town of Naie district. Human-friendly Town of Naie City by environment-friendly energies; Naiemachi chiiki shin energy vision. Kankyo ni yasashii energy ga tsukuru hito ni yasashii machi Naie

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The new energy visions are drawn for Town of Naie, Sorachi-gun in Hokkaido, where the industrial sector (manufacturing industries) consumes more than 60% of the total energy consumption. By energy type, oil and others account for 80%. When arranged in the order of expected recoverable quantity, the new energies for the town include utilization of solar energy, photovoltaic power generation, wind power generation, and utilization of wastes, biomass energy (agricultural products) and snow energy. The basic guidelines for introduction of new energies are for health and welfare, clearing and utilization of snow, environmental education and bringing up talented persons, supporting the related entrepreneurs, and integration of new energy with promotion of energy-saving movement. The priority projects the town plans to promote include utilization of biogas and temperature-differential energy for the town's water purification center; foundation of the Naie eco-school; and drawing conceptions for utilization of underground heat, utilization of low-temperature and snow/ice energy, co-energy around the spa of Naie, and mega-solar and eco-park at the Sorachi housing complex. (NEDO)

  17. Research report for fiscal 1998. Survey on the researchers and research institutes for the effects of global warming and its countermeasures; 1998 nendo onshitsu koka gas ni yoru kankyo eikyo nado ni kansuru kenkyusha kenkyu kikan chosa chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Researchers and research institutes across the world (except those in Japan), engaged in the study of global warming and measures to deal with the phenomenon, are extracted in compliance with certain specified standards, and the latest information on them is appropriately arranged and listed. It is further developed into an electronic database for the convenience of users. The collected information includes more than 230 research institutes and more than 1,000 researchers. The endeavor is exerted by extracting essays and institutes mainly out of the on-line databases. More than 1,000 essays and 130 institutes are covered. Visits are made to five institutes in the U.S. and four in Europe who are most actively engaged in the study of global warming, and detailed researches are conducted and information is exchanged. The Argonne National Institute copes with all energy problems related to global warming. Descriptions are given about environmental impact surveys and CO2 isolation in the ocean at the Center for Global Science of the Massachusetts Institute of Technology. At the Oak Ridge National Laboratory, the visitors heard explanations of technologies related to renewable energies and so forth. Researches are made into ecosystems at the University of California, and into natural energies at the University of Hawaii. Also visited are research institutes in Australia, Germany, Netherlands, and Britain. (NEDO)

  18. FY1995 high techniques of measuring for sensation, cognition arid behavior in the man-products-environment interface; 1995 nendo seihin kankyo interface ni okeru kankaku ninchi kodo keisoku kodoka ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    We measure the distribution of activation locus of brain cortex area and its time-sequence against various kinds of stimulus by using the fMRI that can visualize directly brain activities. Next, we try to make a simulation model of the information processing system of brain, and aim at establishment of new evaluation index for environment-human interface based objectively or quantitatively on brain activity data. we challenged to examining quantitatively brain activities by using functional MRI instrumentation technique. We made a effort to acquire functional MRI technique by repetition of pilot studies, and were successful in visualization of visual cortex (primary sensory area). In the latter period, sensory areas whose function had not been studied sufficiently and higher functional areas of brain which related to memory, attention and emotion were studied. The identification of action locus of gustatory area was tried using functional MRI studies. In studies about the ability of spatial attention, experiments elucidating locus participating in space perception and attention and its function were advanced. It was suggested that activation locus of brain was different between a color-form matched stimulus and a mismatched stimulus. The MRI measurement added the information of musculoskeletal system to the current analysis of human body configuration and gesture character, and a more detailed analysis of human body became possible. This is, an useful analysis was suggested by a plan of shoes pattern. (NEDO)

  19. Adaptability of drowsiness level detection that measures blinks utilizing image processing to changes in the ambient light; Hikari kankyo no henka ni tekiosuru kao gazo shori ni yoru inemuri unten kenchi

    Energy Technology Data Exchange (ETDEWEB)

    Kaneda, M; Obara, H; Nasu, T [Nissan Motor Co. Ltd, Tokyo (Japan)

    1997-10-01

    A drowsiness warning system that measures blinks utilizing image processing technology has a number of issues that need to be resolved. One issue is the adaptability of the system to changes in the ambient light environment in the actual vehicle interior. We have devised image processing software which is robust to changes in the ambient light. The drowsiness detection performance of the system was evaluated in laboratory tests and actual driving tests. It was found that the system can has a positive effect on detecting drowsiness level. 3 refs., 10 figs.

  20. Internal carbonitriding behavior of Ni-V, Ni-Cr, and Ni-3Nb alloys

    International Nuclear Information System (INIS)

    Allen, A.T.; Douglass, D.L.

    1999-01-01

    Ni-2V, Ni-5V, Ni-12V, Ni-10Cr, Ni-20Cr, and Ni-3Nb alloys were carbonitrided in C 3 H 6 and NH 3 gas mixtures (bal H 2 ) over the range 700--1,000 C. Carbonitridation of Ni-12V and Ni-20Cr in C 3 H 6 /NH 3 /H 2 (1.5/1.5/97 v/o) and (1.5/10/88.5 v/o) produced duplex subscales consisting of near-surface nitrides with underlying carbides. Growth of each zone obeyed the parabolic rate law under most conditions. The presence of carbon generally did not effect the depth of the nitride zones compared to nitriding the alloys in NH 3 /H 2 (10/90 v/o). However, at 700 C, the nitride zones were deeper in the carbonitrided Ni-V alloys and Ni-20Cr. The presence of nitrogen generally increased the depth of the carbide zones in Ni-12V and Ni-20Cr compared to carburizing these alloys in C 3 H 6 /H 2 (1.5/98.5 v/o). VN, CrN, and NbN formed in Ni-V, Ni-Cr, and Ni-Nb alloys, respectively, whereas the underlying carbide layers contained V 4 C 3 in Ni-12V, Cr 3 C 2 above a zone of Cr 7 C 3 in Ni-20Cr, and NbC in Ni-3Nb. The solubilities and diffusivities of nitrogen and carbon in nickel were determined. Nitrogen and carbon each exhibited retrograde solubility with temperature in pure Ni in both carbonitriding environments. Nitrogen diffusion in nickel was generally lower in each carbonitriding mixture compared to nitrogen diffusion in a nitriding environment, except at 700 C when nitrogen diffusion was higher. Carbon diffusion in nickel was generally higher in the carbonitriding environments compared to carbon diffusion in a carburizing environment

  1. Fe(CO)5-catalyzed coprocessing of coal and heavy oil vacuum residue using syngas-water as a hydrogen source; Fe(CO)5 shokubai ni yoru gosei gas-mizu wo suisogen to suru sekitan-jushitsuyu no coprocessing

    Energy Technology Data Exchange (ETDEWEB)

    Hata, K.; Wada, K.; Mitsudo, T. [Kyoto University, Kyoto (Japan)

    1996-10-28

    Improvement in efficiency and profitability of hydrogenation reaction of heavy hydrocarbon resources is the most important matter to be done. In this study, coprocessing of coal and heavy oil vacuum residue was conducted using syngas-water as a hydrogen source. For the investigation of effect of the reaction temperature during the coprocessing of Wandoan coal and Arabian heavy vacuum residue using Fe(CO)5 as a catalyst, the conversion, 66.0% was obtained at 425{degree}C. For the investigation of effect of reaction time, the yield of light fractions further increased during the two stage reaction at 400{degree}C for 60 minutes and at 425{degree}C for 60 minutes. Finally, almost 100% of THF-soluble matter was obtained through the reaction using 2 mmol of Fe(CO)5 catalyst at 400{degree}C for 60 minutes, and hydrogenation of heavy oil was proceeded simultaneously. When comparing coprocessing reactions using three kinds of hydrogen sources, i.e., hydrogen, CO-water, and syngas-water, the conversion yield and oil yield obtained by using syngas-water were similar to those obtained by using hydrogen, which demonstrated the effectiveness of syngas-water. 2 refs., 2 figs., 2 tabs.

  2. Solid/liquid phase change heat transfer in porous media. Effect of density inversion of water on melting process in a rectangular region; Takoshitsu sonai no ko-ekiso henka. Mizu no mitsudo gyakuten ga kukei ryoiki no yukai katei ni oyobosu eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Sasaguchi, K [Kumamoto University, Kumamoto (Japan). Faculty of Engineering

    1994-12-25

    Solid/liquid phase change in porous media has a wide relation with freezing and melting of ground bed, storage of cold heat in soil, and underground heat exchangers. This paper describes an investigation on the effect of density inversion on melting of ice in porous media by using the previously reported numerical analysis method. The high-temperature side temperature and the Darcy number were varied and investigated systematically on the ice in a porous media sealed in a rectangular container of which right hand side is maintained at elevated temperatures and the other three sides are insulated of heat. As a result, a large number of findings were obtained including the following matters: when the Darcy number is fixed at 4.01 {times} 10{sup {minus}5} and the high-temperature side temperature, Tw, is varied, the fluid descends along the high-temperature side because of the density inversion at Tw=4{degree}C, and forms one weak circulation that rotates clockwise; however, when the temperature reaches 16{degree}C, the circulation disappears, and a circulation rotating counterclockwise is observed, becoming identical to the case of a fluid where there is no density inversion; and change in the Nusselt number against the melting ratio, R, is the smallest at Tw=8{degree}C, and decreases monotonously with the R. 15 refs., 12 figs.

  3. Achievement report on research and development in the Sunshine Project in fiscal 1976. Research and development of water decomposition by using a hybrid cycle composed of thermo-chemistry and photo-chemistry; 1976 nendo netsukagaku oyobi hikari kagaku hybrid cycle ni yoru mizu bunkai no kenkyu kahatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1977-03-01

    This paper describes water decomposition by using a hybrid cycle composed of thermo-chemistry and photo-chemistry. Ferric sulfate and HI are obtained from ferrous sulfate and iodine via photo-chemical reaction. This is an endothermic reaction of 10.8 kcal. Then, the photo-chemically reacted aqueous solution is electrolysed to separate HI, while Fe{sup 3+} (ferric ion) is reduced and converted into Fe{sup 2+} (ferrous ion). Oxygen is generated at this time. Since mixed potential is made from iron oxidation and reduction potential and iodine potential, the electrolytic efficiency is greatly influenced by electrode materials. Ideally, an electrode material that causes only the reduction of Fe{sup 3+}, but not other reactions is preferable. The HI is decomposed into hydrogen and iodine by electrolysis. Research is continuing to acquire hydrogen from HI thermo-chemically. Endothermic reaction heat of 7 to 8 kcal has been obtained in photo-chemical reaction, the heat quantity being close to the theoretical value of 10.8. A result close to the theoretical value may be expected if the electrode material problem is solved. The basic research will be continued for a high possibility of linking the research to a pilot plant in the future. (NEDO)

  4. FY 1985 report on research and development project commissioned by the Sunshine Project. Research and development of electrolysis of water by combined thermochemical, photochemical and electrochemical cycles; 1985 nendo netsu kagaku, hikari kagaku, denki kagaku konsei cycle ni yoru mizu bunkai no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1986-03-01

    Reported herein are the FY 1985 research results on the combined water electrolysis cycles by effective utilization of sunlight. The tests for determining activity coefficient of an iron/iodine system is continued from the previous year, and the results are used to find the optimum conditions under which the photochemical and electrolysis reactions are effected simultaneously in a light-irradiated electrolysis tank. It is found that a photochemical reaction efficiency of approximately 0.3% is obtained at 5 W/cm{sup 2} as light intensity and 25 degrees C. For electrolysis of water by the multi-stage hybrid cycles, it is necessary for the reaction in each stage to proceed to almost the same extent so that it gives a just enough quantity of product for the subsequent stage. The data obtained are analyzed comprehensively, while taking the system matching conditions into consideration. The system for simultaneously measure two or more parameters, developed in the previous year, is equipped with a high-level language compiler of high effective speed, to simultaneously measure these parameters at shorter intervals. (NEDO)

  5. Achievement report on research and development in the Sunshine Project in fiscal 1979. Research and development on water decomposition by using mixed cycle of thermo-chemistry, photo-chemistry and electrochemistry; 1979 nendo netsukagaku, hikari kagaku, denki kagaku konsei cycle ni yoru mizu bunkai no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1980-03-01

    This paper describes achievements in research and development in the Sunshine Project in fiscal 1979 on water decomposition by using mixed cycle of thermo-chemistry, photo-chemistry and electrochemistry. In research on the light irradiation electrolytic process, with an objective of improving the reaction efficiency, discussions were given by raising light intensity on the irradiated surface as high as 13 times that of the sunlight. The subsequent process is electrolysis of products from photo-chemical reaction, and the product concentration should be high enough to have HI decomposition (hydrogen acquisition) proceed with high efficiency. Experiments were carried out at 0.03 to 0.1M as iodine concentrations (product HI concentration at 3%). A photo-chemical reaction rate of 80% was obtained at light intensity as high as 12 times that of the sunlight, and iodine concentration of 0.07 mM. The efficiency was 15%. Raising temperature causes the reaction rate to decrease, but it can be supplemented by raising the light intensity, where high concentration HI content was obtained. Rate controlling process in the reaction was elucidated from activation energies in the reaction process of each element on the iodine concentrations from 3 to 30 mM used in the photo-chemical reaction. Experiments were performed on HI decomposition (hydrogen acquisition) by using a heat diffusion column. Separation performance in a filled type column was worse than that in an empty type column, which requires future discussions. (NEDO)

  6. Nipah Virus (NiV)

    Science.gov (United States)

    ... Form Controls Cancel Submit Search the CDC Nipah Virus (NiV) Note: Javascript is disabled or is not ... gov . Recommend on Facebook Tweet Share Compartir Nipah virus (NiV) is a member of the family Paramyxoviridae , ...

  7. Ni República parlamentaria ni presidencialista

    OpenAIRE

    Álvarez Tardío, Manuel

    2004-01-01

    Revista de Estudios Políticos (Nueva Época), Núm. 123. Enero-Marzo 2004 Este trabajo está dedicado al estudio de un aspecto básico del sistema político de la II República española (1931-1936): el modelo de presidencia de la República y de relaciones de la misma con el parlamento y el gobierno. Aquí se sostiene que la Segunda República, de acuerdo con su Constitución, no fue un régimen parlamentario ni presidencial. Combinó de forma extraña y ambigua elementos de ambos modelos. Probablement...

  8. Microstructural development in NiAl/Ni-Si-B/Ni transient liquid phase bonds

    International Nuclear Information System (INIS)

    Gale, W.F.; Orel, S.V.

    1996-01-01

    A transmission electron microscopy (TEM) based investigation of microstructural development during transient liquid phase bonding of near-stoichiometric NiAl to commercial purity nickel is presented in this article. The work described employed Ni-4.5 wt pct Si-3.2 wt pct B (BNi-3) melt-spun interlayers. The precipitation of both Ni-Al based phases and borides within the joint and adjacent substrate regions is discussed. The article considers martensite formation (within the NiAl substrate) and the precipitation of L1 2 type phases (both within the joint and at the interface with the NiAl substrate). The relative roles of the two substrate materials (NiAl and Ni) in the isothermal resolidification process are identified. The preferential formation of Ni 3 B boride phases in the Ni substrate near the original location of the Ni substrate-joint interface is discussed and contrasted with the absence of similar events in the NiAl substrate

  9. Ni landsbyer i Danmark

    DEFF Research Database (Denmark)

    Larsen, Jacob Norvig

    Denne rapport beskriver en evaluering af statsstøttede forsøg med at styrke og udvikle mindre lokalsamfund. Forsøgene er gennemført i ni kommuner. Da der i disse år er stor opmærksomhed om de små byers og samfunds udviklingsmuligheder, har erfaringerne fra forsøgsprojekterne bred interesse. Forsø...

  10. Vapor-liquid equilibrium data for five binary systems of methanol, tert-butylalcohol, tert-butylmethylether and water, and quaternary reactive system producing tert-butylmethylether from methanol and tert-butylalcohol; Metanoru, tert-buchiruarukoru, tert-buchirumechirueteru oyobi mizu wo kumiawaseta 5shu no niseibunkei to metanoru to tert-buchiruarukoru ni yoru eteruka hannokei no taikiatsuka ni okeru kieki heiko deta

    Energy Technology Data Exchange (ETDEWEB)

    Komatsu, H.; Nakamura, M.; Yamashita, Y.; Hirai, C. [Toyohashi Univ. of Technology (Japan)

    1997-11-01

    At atmospheric pressure, vapor-liquid equilibrium relationships for five binary systems of methanol-tert-butylalcohol, methanol-tert-butylmethylether, tert-butylalcohol-tert-butylmethylether, water-tert-butylalcohol and water-tert-butylmethylether are observed. The Wilson parameters for the binary systems have been obtained. Comparisons between the Wilson method, The ASOG method and the UNIFAC method are made. Vapor-liquid equilibrium relationships of the quaternary reactive system producing tert-butylmethylether by use of methanol and tert-butylalcohol are also observed, and it is confirmed that the Wilson parameters resulting from the data of binary systems can be used to estimate the vapor-liquid equilibrium data for the quaternary reactive system of methanol-tert-butylalcohol-tert-butylmethylether-water. 6 refs., 7 figs., 5 tabs.

  11. Reduction mechanism of Ni2+ into Ni nanoparticles prepared from ...

    Indian Academy of Sciences (India)

    journal of. March 2009 physics pp. 577–586. Reduction mechanism of Ni2+ into Ni ..... and at high field, no domain wall is available and hence, the system becomes a .... [23] J Ding, T Tsuzuki, P G McCormick and R Street, J. Phys. D: Appl.

  12. Reactive Ni/Ti nanolaminates

    International Nuclear Information System (INIS)

    Adams, D. P.; Bai, M. M.; Rodriguez, M. A.; McDonald, J. P.; Jones, E. Jr.; Brewer, L.; Moore, J. J.

    2009-01-01

    Nickel/titanium nanolaminates fabricated by sputter deposition exhibited rapid, high-temperature synthesis. When heated locally, self-sustained reactions were produced in freestanding Ni/Ti multilayer foils characterized by average propagation speeds between ∼0.1 and 1.4 m/s. The speed of a propagating reaction front was affected by total foil thickness and bilayer thickness (layer periodicity). In contrast to previous work with compacted Ni-Ti powders, no preheating of Ni/Ti foils was required to maintain self-propagating reactions. High-temperature synthesis was also stimulated by rapid global heating demonstrating low ignition temperatures (T ig )∼300-400 deg. C for nanolaminates. Ignition temperature was influenced by bilayer thickness with more coarse laminate designs exhibiting increased T ig . Foils reacted in a vacuum apparatus developed either as single-phase B2 cubic NiTi (austenite) or as a mixed-phase structure that was composed of monoclinic B19 ' NiTi (martensite), hexagonal NiTi 2 , and B2 NiTi. Single-phase, cubic B2 NiTi generally formed when the initial bilayer thickness was made small.

  13. Electroplated Ni on the PN Junction Semiconductor

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jin Joo; Uhm, Young Rang; Son, Kwang Jae; Kim, Jong Bum; Choi, Sang Moo; Park, Jong Han; Hong, Jintae [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-05-15

    Nickel (Ni) electroplating was implemented by using a metal Ni powder in order to establish a Ni-63 plating condition on the PN junction semiconductor needed for production of betavoltaic battery. PN junction semiconductors with a Ni seed layer of 500 and 1000 A were coated with Ni at current density from 10 to 50 mA cm{sup 2}. The surface roughness and average grain size of Ni deposits were investigated by XRD and SEM techniques. The roughness of Ni deposit was increased as the current density was increased, and decreased as the thickness of Ni seed layer was increased.

  14. Electroplated Ni on the PN Junction Semiconductor

    International Nuclear Information System (INIS)

    Kim, Jin Joo; Uhm, Young Rang; Son, Kwang Jae; Kim, Jong Bum; Choi, Sang Moo; Park, Jong Han; Hong, Jintae

    2015-01-01

    Nickel (Ni) electroplating was implemented by using a metal Ni powder in order to establish a Ni-63 plating condition on the PN junction semiconductor needed for production of betavoltaic battery. PN junction semiconductors with a Ni seed layer of 500 and 1000 A were coated with Ni at current density from 10 to 50 mA cm 2 . The surface roughness and average grain size of Ni deposits were investigated by XRD and SEM techniques. The roughness of Ni deposit was increased as the current density was increased, and decreased as the thickness of Ni seed layer was increased

  15. Report on a survey in fiscal 1999. Survey on possibilities of environmental cooperation in relation with proliferation of environment preservation technologies and institutions in developing countries; 1999 nendo kankyo taisaku gijutsu seido nado no tojokoku fukyu ni kakawaru kankyo kyoryoku kanoseichosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Cooperation in energy and environment aspects with developing countries is considered very important in view of the following points: (1) the cooperation will help developing countries to grow economically while minimizing the damages from industrial pollution and environmental problems; (2) conservation of energies and promotion of use of new energies will contribute to solving pollution problems associated with energy production, and will result in assurance of stability of primary energy availability for Japan; (3) preservation of environments in countries exporting foods to Japan will link to maintaining health of Japanese people and increasing their welfare; and (4) Japanese industrial pollution preventing technologies and knowledge whose levels are high worldwide may be utilized to create new business chances for Japanese business entities. The present survey has discussed the importance by territories, the importance by cooperation modes, and sharing of roles by governmental and private organizations, and performed case studies. Considerations were given from the discussion results on how the environmental projects should be planned in the environment cooperation, the contents to be of win/win from the viewpoint of motivation, the project image for subjected territories being composite and comprehensive, and the cases from the viewpoint of mutual coexistence referred to as prevention of global warming and assurance of food and energy resources. (NEDO)

  16. Fiscal 1997 survey report. Feasibility study of the environmentally friendly type coal utilization system (feasibility study of the environmentally friendly type coal utilization system in India); 1997 nendo chosa hokokusho. Kankyo chowagata sekitan riyo system kanosei chosa (Indo ni okeru kankyo chowagata sekitan riyo system kanosei chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The survey was conducted of the present situation of coal utilization and the present coal situation such as the environmental state of India which is a coal producing/consuming country next to China in Asia. The paper studied a feasibility of the introduction of the environmental friendly type coal utilization system` to be planned in India. The items for survey are the present situation of economy and energy and the future trend, environmental problems on coal utilization, the present status of the coal distribution system and study subjects, the present status of coal utilization by field and study subjects, a possibility of briquette use, a possibility of coal fluidization, electric power development plans and coal combustion technology in each industry, etc. The subjects are the obligation of coal preparation to coal thermal power plants 1000 km away from coal mines starting 2001, measures taken for effective ash use, measures taken for superannuated gas furnaces, etc. Based on the results of these site surveys and reports of the investigation under consignment from CMPDI, the paper studied/analyzed possibilities of introducing the coal utilization system having actual introduction results in Japan to India, and made an investigational report. 39 refs., 12 figs., 56 tabs.

  17. Fiscal 1996 survey report on the environmentally friendly type coal utilization system feasibility study. Feasibility study of the environmentally friendly type coal utilization system in Malaysia and Vietnam; Kankyo chowagata sekitan riyo system kanosei chosa. Malaysia Vietnam ni okeru kankyo chowagata sekitan riyo system kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This survey arranged the status of coal utilization technology and the status of coal production, supply, etc. in Malaysia and Vietnam, examined/studied coal utilization systems in both countries, and finally assessed feasibility of introducing the environmentally friendly type coal utilization system. As a country of primary energy source which is abundant in crude oil, natural gas, hydroelectric power, coal, etc., Malaysia now depends on crude oil and natural gas for 80% of its energy, and places emphasis on exploration of natural gas and oil refining. In electric power and cement industries where coal is consumed, effectiveness and environmental issues in association with coal utilization are future subjects. In Vietnam, the north is abundant in hydroelectric power and anthracite, and the south in oil and gas resource, but the north and central districts are in a state of undevelopment. Coal is used for coal thermal power generation, cement industry, and residential/commercial fuel. In the future, effective coal utilization and environmental issues will be subjects. 16 refs., 38 figs., 75 tabs.

  18. Report on a fiscal 1995 basic survey of the environmental engineering. Investigational study on the systematization of the environmental business related information; 1995 nendo kankyo business no engineering ka kiso chosa hokokusho. Kankyo business kanren joho no system ka ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-05-01

    An investigational study was conducted on directionality of arranging the environmental business related information, based on the analysis of the status of arrangement of the environmental business related information and the examination of the needs for the environmental business related information. As the directionality of arranging the environmental business related information which is most suitable for enterprises and research institutes to use, the following were considered: (1) arrangement of a system for effective use of the information owned by environmental related organs; (2) arrangement of a system for supply of the environmental business related information mainly to medium and small companies; (3) arrangement of the environmental business related information forum. In (1), it is necessary to arrange the system for the joint use of information owned by each institute. In (2), the tackling with the environmental business should be supported by arranging the system for information supply from big companies to medium and small companies. In (3), it is necessary to arrange the information forum, and it is necessary to control information thoroughly for the management for prevention of bad deeds of brokers. 7 refs., 19 figs., 21 tabs.

  19. Feasibility study of environmentally friendly type coal utilization systems. Feasibility study of environmentally friendly type coal utilization systems in sectors except the coal industry in China; Kankyo chowagata sekitan riyo system kanosei chosa. Chugoku no sekitan kogyo igai no bumon ni okeru kankyo chowagata sekitan riyo system kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    For the purpose of working out a comprehensive master plan for application of the coal utilization system, the paper surveyed and studied the coal utilization system in terms of environmental measures and efficiency improvement in the utilization of coal. As a result of the discussion with NEDO and the National Planning Committee of China, Liaoning Province (the whole China) and Shenyang City were selected as a model area and a model city for the survey and study. As energy conservation measures taken in the former, desirable are intensifying/capacity-increase of boilers, kilns, etc. and adoption of new-type/high-efficient equipment. Also expected are reinforcement of combustion control and improvement of efficiency by using coal preparation, industrial use coal briquette, etc. Measures taken in the latter are the same as those taken in the whole China. As SOx reduction measures for Liaoning Province, desirable is installation of dry-type desulfurization equipment and simple desulfurization equipment. As dust prevention measures for it, desirable is installation of electrostatic precipitators or high-functional bag filters. SOx reduction measures for Shenyang City are the same as those taken in the whole China. SOx can be reduced by using coal-prepared low-sulfur coal and industrial use coal briquette added with desulfurizing agent. 88 figs., 163 tabs.

  20. Fiscal 1995 survey report on the feasibility study of the environmentally friendly type coal utilization system. Feasibility study of the environmentally friendly type coal utilization system in Thailand; Kankyo chowagata sekitan riyo system kanosei chosa. Tai ni okeru kankyo chowagata sekitan riyo system kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-06-01

    The paper surveyed the present situation and future trend of economy, energy supply/demand, coal production/distribution/utilization and the environmental effects in Thailand. The survey on the coal utilization and its environmental effects was partially requested of the environmental research institute in Thailand. The amount of coal utilization in Thailand rapidly increased to nearly four times as large as that ten years ago mainly in terms of domestic lignite under the government`s policy on expansion of the domestic energy use. However, most of this domestic lignite is low-grade coal with low calories and high sulfur content, and the use of it was rapidly increased mostly in power generation sector without no adequate environmental measures taken. This caused an environmental problem on air pollution due to sulfur oxides at Mae Moh power plant in the north several years ago, and the damages to the regional residents, etc. were given much publicity by journalism and developed the social problem. Accordingly, Thai people are now critical of the coal resource exploration and the coal use expansion. Under the circumstances, the Ministry of Industry and the energy related ministries/offices are obliged to review their development/promotion plans. 84 figs., 99 tabs.

  1. Fiscal 1997 feasibility survey of an environment friendly type coal utilization system. Feasibility survey of the environment friendly type coal utilization system in Malaysia and Vietnam (case of Vietnam); 1997 nendo chosa hokokusho. Kankyo chowagata sekitan riyo system kanosei chosa (Malaysia oyobi Vietnam ni okeru kankyo chowagata sekitan riyo system kanosei chosa (Vietnam ban))

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper grasped the state of coal utilization by coal consumption field, the state of coal physical flow in Vietnam, etc., surveyed/studied a possibility of introducing the environment friendly type coal utilization system, and assessed the possibility. As to energy resources, the north is abundant in hydroelectric and coal (mainly anthracite) resources, and the south in oil and natural gas resources. Coal production in fiscal 1997 is planned to be 10 million tons. Coal preparation technique presently available is only grain size sieving. Accordingly, it is necessary to study for heightening efficiency of facilities and modernizing facilities in accordance with the introduction of the environment friendly type coal utilization technology. During the study, it is possible to propose improvement on coal processing technology (coal preparation technology). Assessment and study are made especially of the coal selection system, fine coal recovery system and waste water treatment system. For the plan on new coal-fired power plants (300MWtimes4), there is left much necessity of proposing studying models considered of the anthracite combustion technology and environmental improvement and of assessing/studying them. 60 figs., 117 tabs.

  2. FY 1999 report on the potential survey of the environmentally friendly type coal utilization system. Potential survey of the environmentally friendly type coal utilization system in the Philippines; 1999 nendo chosa hokokusho. Kankyo chowa gata sekitan riyo system kanosei chosa (Firipin ni okeru kankyo chowa gata system kanosei chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    For the purpose of contributing to working out a master plan for the introduction of the environmentally friendly type coal utilization system in the Philippines, analysis was made of the state of coal use/the state of spread by industry mostly including the electric power industry, cement industry and residential/commercial use fuel sector. In the Philippines, the amount of coal use has rapidly been increasing since coal-fired power plants started operation. For the promotion of the use of domestic coals, it is important to reform low grade coal. Moreover, the technology is required which copes with the reinforced regulation against SOx emissions. In the cement industry, coal and coal ash have not yet been effectively used. Therefore, the following measures should be taken to increase the competitive force: energy conservation measures, reinforcement of environmental measures such as dust prevention, and effective use of the fly ash emitted from power plants. In general households and small-/medium-sized industries such as tobacco drying, they still use a large amount of charcoals and firewood, which is approximately 86% of the residential/commercial use energy. There is a growing tendency for the development/spread of coal briquette as substituting energy. (NEDO)

  3. Investigations in fiscal 2000 on feasibility of environment friendly coal utilization system. Feasibility survey on environment friendly coal utilization system in India; 2000 nendo kankyo chowagata sekitan riyo system kanosei chosa hokokusho. Indo ni okeru kankyo chowagata sekitan riyo system kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Taking the area of the clean coal technology (CCT) effective for energy conservation and environment preservation as the object, a feasibility survey has been performed on executing a model project in India. About 70% of the total power generation capacity in India depends upon coals existing in abundance inside the country. Since the local coals are high in ash, low in sulfur, and low in calorie, the environmental problem related to thermal power plants is the disposition of fly ash. The Central Electricity Authority of India expects solving this problem by CCT introduction. It also expects increase in combustion efficiency by using ultra-critical boilers. The Indian cement industry often uses in-house electric power generation facilities because of high electric power cost, wherein the produced coal ash is used as a cement raw material. The matter of the strongest interest is the introduction of a high-efficiency combustion system that depends on low-grade coals. Among the CCTs, strong interest was shown in the fluidized bed cement kiln and the circulating fluidized bed boiler. The iron and steel industry has expectations toward effective coal washing technologies and coke manufacturing technologies. (NEDO)

  4. Fiscal 1996 survey report on the environmentally friendly type coal utilization system feasibility study. Feasibility study of the environmentally friendly type coal utilization system in the Philippines; Kankyo chowagata sekitan riyo system kanosei chosa. Philippines ni okeru kankyo chowagata sekitan riyo system kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Grasping the present situation of coal utilization technology in the Philippines, the paper proposed a feasibility study of introduction of the environmentally friendly type coal utilization system which seems to be needed in the future. (1) Introduction of the environmentally friendly type coal utilization system in the electric power generation sector: there are only four full-scale running coal thermal power plants in the Philippines. In the future, several coal thermal plants are planned to be constructed by 2005, but for the new installation, it is desirable to adopt fluidized bed boilers with wide application to coal kinds. In case of 0.3-1.0 million MW class plants, it is planned to adopt high grade import coals, and it will be natural to fire pulverized coal. For the processing of flue gas, it is a must to install desulfurization facilities and smoke/soot removal devices. (2) Utilization/development of domestic low grade coals: at the mine-mouth generating plant, it is necessary to investigate the economically minable amount of coal, confirm productivity, survey coal quality, etc., and select boiler. As to coal briquetting technology, it is necessary to examine coal quality for tests and make a thorough study of what technology is most suitable. 50 figs., 78 tabs.

  5. Fiscal 1996 survey report on the environmentally friendly type coal utilization system feasibility study. Feasibility study of the environmentally friendly type coal utilization system in Thailand; Kankyo chowagata sekitan riyo system kanosei chosa. Tai ni okeru kankyo chowagata sekitan riyo system kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The paper investigated and studied the present situation and future trend of coal utilization and distribution in Thailand, and the present situation of environmental effects and the measures taken for environmental protection. Around 2010, coal will probably be produced only at EGAT`s Mae Moh (MM) coal mine. Demand for overseas coal is expected to be 40-50 million tons in 2011, and preparation of the coal center becomes a subject. For general industry use coal, pretreatment such as coal preparation, coal blending and briquetting is needed, considering coal quality, usage, transport distance and environmental effects. Brown coal of MM coal mine is a lignite with high sulfur, high ash content and low heating value. Wide spread of its use can be expected if upgrading is possible such as desulfurization, deashing, increasing heating value. In the electric power generation field, the absorber was installed at the existing boiler of the mine-mouth generating plant to conduct a verification test on high grade desulfurization of ultra-high sulfur lignite. In the industry field, the circulating fluidized bed boiler was adopted. In the residential/commercial field, introduction of briquette was proposed. 80 refs., 84 tabs.

  6. Research report of FY 1997 on the environmentally acceptable coal utilization system feasibility survey. Environmentally acceptable coal utilization system feasibility survey in Malaysia and Vietnam (Malaysia); 1997 nendo chosa hokokusho. Kankyo chowagata sekitan riyo system kanosei chosa (Malaysia oyobi Vietnam ni okeru kankyo chowagata sekitan riyo system kanosei chosa (Malaysia ban))

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In this survey, the coal utilization status in individual consumption sectors and coal distribution status in Malaysia are summarized as basic data for the introduction of environmentally acceptable coal utilization systems. In this fiscal year, the status of existing coal utilization technology and environmental issues in Malaysia are summarized as basic data for the introduction of above-mentioned systems on the basis of data and information collected by basic research and site survey in FY 1996. Malaysia is one of the rich countries producing the primary resources with crude petroleum, natural gas, hydro-power, and coal. The coal demand will be realized after saturating LNG development since 2000. The major coal consumption industries are power generation sector and cement industry sector. As expected increase in the future coal consumption, efficiency of coal utilization and environmental issues are problems in the future. Based on the FS results of this survey, the survey will be continued for planning and conducting the model project required from Malaysia. 8 figs., 34 tabs.

  7. Synthesis and electrochemical behavior of nanostructured cauliflower-shape Co-Ni/Co-Ni oxides composites

    International Nuclear Information System (INIS)

    Gupta, Vinay; Kawaguchi, Toshikazu; Miura, Norio

    2009-01-01

    Nanostructured Co-Ni/Co-Ni oxides were electrochemically deposited onto stainless steel electrode by electrochemical method and characterized for their structural and supercapacitive properties. The SEM images indicated that the obtained Co-Ni/Co-Ni oxides had cauliflower-type nanostructure. The X-ray diffraction pattern showed the formation of Co 3 O 4 , NiO, Co and Ni. The EDX elemental mapping images indicated that Ni, Co and O are distributed uniformly. The deposited Co-Ni/Co-Ni oxides showed good supercapacitive characteristics with a specific capacitance of 331 F/g at 1 mA/cm 2 current density in 1 M KOH electrolyte. A mechanism of the formation of cauliflower-shape Co-Ni/Co-Ni oxides was proposed. A variety of promising applications in the fields such as energy storage devices and sensors can be envisioned from Co-Ni/Co-Ni oxides

  8. Radiochemical method for 63Ni

    International Nuclear Information System (INIS)

    Holm, E.; Nilsson, U.; Hallstadius, L.

    1985-01-01

    A radianalytical method for the determination of 63 Ni content in environmental samples of activated corrosion products is described. After chemical separation and electrodepositing of 63 Ni on silver briquets, the chemical yield is determined by X-ray fluorescence analysis. For the detection of low-energy beta activity, an open gas flow GM-counter with an anticoincidence guard counter is put to use

  9. Electronic structure of Ni/sub 3/Al and Ni/sub 3/Ga alloys

    CERN Document Server

    Pong, W F; Chang, Y K; Tsai, M H; Hsieh, H H; Pieh, J Y; Tseng, P K; Lee, J F; Hsu, L S

    1999-01-01

    This work investigates the charge transfer and Al(Ga) p-Ni d hybridization effects in the intermetallic Ni/sub 3/Al(Ni/sub 3/Ga) alloy using the NiL/sub 3.2/- and K-edge and Al(Ga)K X-ray absorption near edge structure (XANES) measurements. We find that the intensity of white-line features at the NiL/sub 3.2/-edge in the Ni/sub 3/Al(Ni /sub 3/Ga) alloy decreased in comparison with that of pure Ni, which can be attributed to the enhancement of Ni3d states filling and the depletion of the density of Ni 3d unoccupied states in the Ni/sub 3 /Al(Ni/sub 3/Ga) alloy. Two clear features are also observed in the Ni/sub 3/Al(Ni/sub 3/Ga) XANES spectrum at the Al(Ga) K-edge, which can be assigned to the Al(Ga) unoccupied 3p (4p) states and their hybridized states with the Ni 3d/4sp states above the Fermi level in Ni/sub 3/Al(Ni/sub 3/Ga). The threshold at Al K-edge XANES for Ni/sub 3/Al clearly shifts towards higher photon energies relative to that of pure Al, indicating that Al loses charges upon forming Ni/sub 3 /Al. ...

  10. Nitriding behavior of Ni and Ni-based binary alloys

    Energy Technology Data Exchange (ETDEWEB)

    Fonovic, Matej

    2015-01-15

    Gaseous nitriding is a prominent thermochemical surface treatment process which can improve various properties of metallic materials such as mechanical, tribological and/or corrosion properties. This process is predominantly performed by applying NH{sub 3}+H{sub 2} containing gas atmospheres serving as the nitrogen donating medium at temperatures between 673 K and 873 K (400 C and 600 C). NH{sub 3} decomposes at the surface of the metallic specimen and nitrogen diffuses into the surface adjacent region of the specimen whereas hydrogen remains in the gas atmosphere. One of the most important parameters characterizing a gaseous nitriding process is the so-called nitriding potential (r{sub N}) which determines the chemical potential of nitrogen provided by the gas phase. The nitriding potential is defined as r{sub N} = p{sub NH{sub 3}}/p{sub H{sub 2}{sup 3/2}} where p{sub NH{sub 3}} and p{sub H{sub 2}} are the partial pressures of the NH{sub 3} and H{sub 2} in the nitriding atmosphere. In contrast with nitriding of α-Fe where the nitriding potential is usually in the range between 0.01 and 1 atm{sup -1/2}, nitriding of Ni and Ni-based alloys requires employing nitriding potentials higher than 100 atm{sup -1/2} and even up to ∞ (nitriding in pure NH{sub 3} atmosphere). This behavior is compatible with decreased thermodynamic stability of the 3d-metal nitrides with increasing atomic number. Depending on the nitriding conditions (temperature, nitriding potential and treatment time), different phases are formed at the surface of the Ni-based alloys. By applying very high nitriding potential, formation of hexagonal Ni{sub 3}N at the surface of the specimen (known as external nitriding) leads to the development of a compound layer, which may improve tribological properties. Underneath the Ni{sub 3}N compound layer, two possibilities exist: (i) alloying element precipitation within the nitrided zone (known as internal nitriding) and/or (ii) development of metastable and

  11. Ni4Ti3 precipitate structures in Ni-rich NiTi shape memory alloys

    International Nuclear Information System (INIS)

    Holec, D.; Bojda, O.; Dlouhy, A.

    2008-01-01

    Non-uniform distributions of Ni 4 Ti 3 precipitate crystallographic variants are investigated in a Ni-rich NiTi shape memory alloy after aging, assisted by external stress. A finite-element method model is presented that considers the elastic anisotropy of the B2 parent phase and also mutual misorientations of grains in a polycrystalline sample. On loading by the external stress, the stress is redistributed in the microstructure and the precipitation of some Ni 4 Ti 3 crystallographic variants becomes distinctly favorable in grain boundary regions since these variant configurations minimize the elastic interaction energy. The volume fraction of the affected grain boundary regions is calculated and the numerical results are compared with the data obtained by differential scanning calorimetry and transmission electron microscopy

  12. Ni4Ti3 precipitate structures in Ni-rich NiTi shape memory alloys

    Czech Academy of Sciences Publication Activity Database

    Holec, David; Bojda, Ondřej; Dlouhý, Antonín

    2008-01-01

    Roč. 481, Sp. Iss. (2008), s. 462-465 ISSN 0921-5093. [ESOMAT 2006. Bochum, 10.09.2006-15.09.2006] R&D Projects: GA ČR(CZ) GA106/05/0918 Institutional research plan: CEZ:AV0Z20410507 Keywords : NiTi shape memory alloys * Ni4Ti3 precipitates * Multi-step martensitic transformations Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.806, year: 2008

  13. Electronic structure of Ni-- and Ni2--ethylene cluster complexes

    International Nuclear Information System (INIS)

    Basch, H.; Newton, M.D.; Moskowitz, J.W.

    1978-01-01

    The electronic structure of metal cluster--ethylene complexes has been investigated by carrying out ab initio bonding pair-correlated, self-consistent field, and configuration interaction (CI) calculations on the NiC 2 H 4 and Ni 2 C 2 H 4 species. The π-NiC 2 H 4 and π-Ni 2 C 2 H 4 cluster complexes are found to be bound, the former only with CI, while disigma-Ni 2 C 2 H 4 has only a repulsive Ni 2 --C 2 H 4 ground state potential curve. The bonding in the π-type cluster complexes can be described as follows: The metal atom configuration is 3d 9 4s 1 with the 4s hybridized (by the metal 4p) away from the ethylene molecule, thereby allowing the π orbital to form a dative sigma bond with the metal atom. The bonding interaction is promoted by the presence of a second nickel atom behind the first one, leading to a 4s orbital electron deficiency of the bonded nickel atom and thus making this nickel atom a better electron acceptor. Back donation from the occupied metal 3d into the ethylene π* molecular orbital also takes place to some extent, and thus both features of the classical Dewar--Chatt--Duncanson model are observed. The π-Ni 2 C 2 H 4 species is analyzed in terms of the addition of a bare nickel atom to a π-NiC 2 H 4 cluster complex, with concomitant stabilization of the orbitals of the bonded nickel atom. A study of the excited electronic states of π-NiC 2 H 4 shows that low-lying 4s→π* and 3d→π* (M→L) charge transfer transitions are predicted. The former is not observed experimentally, probably due to the diffuse nature of the 4s orbital. The relationship between small cluster--ethylene complex systems and ethylene chemisorption on a nickel metal surface is discussed

  14. Radioactive 63Ni in biological research

    International Nuclear Information System (INIS)

    Kasprzak, K.S.; Sunderman, F.W. Jr.

    1979-01-01

    Applications of 63 Ni in biological research are reviewed, with emphasis upon recent investigations of nickel metabolism and toxicology in experimental animals. The radiochemistry of 63 Ni is summarized, including consideration of the preparation of certain 63 Ni compounds (e.g. 63 Ni(CO) 4 and 63 Ni 3 S 2 ) that are of current interest in toxicology, teratology and cancer research. Practical guidance is given regarding the detection and determination of 63 Ni in biological materials by autoradiography and liquid scintillation spectrometry. (author)

  15. Report on a fiscal 1995 basic survey of the environmental engineering. Investigational survey on the improvement of the waste treatment system; 1995 nendo kankyo business no engineering ka kiso chosa hokokusho. Haikibutsu shori system no kodoka ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-05-01

    The paper described the present situation of the waste treatment system for the environmental engineering and the problems. The final waste treatment plants are in the tighter and tighter condition, and therefore the waste treatment system ought to be changed to a system in which importance is placed on the size reduction, weight reduction, and recycle. Accordingly, the waste treatment system becomes more characterized as a resource feedback process, and should be given more credit as a system for production of secondary resource. The problem is arrangement of conditions of technology, cost and legislation system for smoothing such recycling flow. Of course, it is natural that the most important subject of the system is to secure the environmental preservation by the waste treatment. As future subjects, needed are understanding of the waste treatment as a resource reproductive system, relation with other industries, and review of the legislation system. In consideration of technology, cost and environmental loads, required are proposal of validity of the recycle level limit and a future image of the system structure, and policies for promoting and supporting the recycle business. 47 figs., 104 tabs.

  16. Fiscal 1998 research report. R and D on advanced combustion technology under microgravity environment; 1998 nendo seika hokokusho. Bisho juryoku kankyo wo riyoshita kodo nensho gijutsu soshutsu ni kansuru kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Research was made on explication of a combustion phenomenon by using a microgravity facility, and a combustor possible to realize advanced combustion technology. In the basic research composed of 5 themes by the international joint research with NASA, 52 drop experiments using JAMIC's facility and 100 drop experiments using NASA's 2.2s drop tower were carried out. The themes are composed of an interaction in droplet arrays combustion, combustion of binary fuel sprays, combustion characteristics of solid fuel, flame dynamics around a lean flammability limit, and mass transfer around a combustion field. In the experiment using the microgravity experiment facility and analysis evaluation of the experimental data, studies were made on combustion and evaporation of fuel droplets, combustion characteristics of dense fuel, flammability limit, formation mechanism of NO{sub x} and an advanced combustor. For applying a pre-evaporating/pre- mixing combustion system to a combustor for aircraft engines, studies were made on some issues such as improvement of a combustion stability, NO{sub x} discharge characteristics, and optimum fuel atomizing. (NEDO)

  17. FY 1996 report on the cooperative research on the development of environmentally friendly high efficiency mineral resource extraction/treatment technology; 1996 nendo kankyo chowagata kokoritsu kobutsu shigen chushutsu shori gijutsu no kaihatsu ni kansuru kenkyu kyoryoku hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This promotion project on the cooperative research aims at developing technology to efficiently extract and recover valuable metals including in large quantity in tailings of ores in the Republic of Kazakhstan in consideration of the environmental harmony. The support study in Japan was conducted as follows. As to the Nikolayevska low grade ore, high leaching speed and high leaching rate by grain refining were made possible. The coarse grain was also possible of leaching if leached for a long time. The sulfide froth is possible of leaching in fine grain and in the temperature range of 50 degrees C. The Zhezkent tailings were possible of leaching with sulfuric acid, by aeration, and in the range of medium temperature. The sulfide froth was possible of leaching in fine grain and at temperature of 50 degrees C. After filtration/washing and regrinding, high sampling rates of bulk concentrate and pyrite concentrate were obtained by sulfide flotation by zanthate. The Zhezkent copper concentrate was tested on various factors such as grain size, temperature, and washing/no washing, to confirm effects of bacteria. In the pre-observation test on Au and Ag leaching, cyanogen leaching test was conducted using Cu leaching residue. About Cu, studied were leaching (vat leaching, flotation froth machine agitation (temperature increase, bacteria)), solvent extraction, and electrowinning. About Au and Ag, studied were cyanogen leaching and process of adsorption of activated carbon. (NEDO)

  18. Fiscal 1997 international cooperation project. Report on the results of the research on environmental harmony type combustion technology; 1997 nendo kokusai kenkyu kyoryoku jigyo. Kankyo chowagata nensho gijutsu ni kansuru kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Out of the R and D on the environmental harmony type combustion technology, the results of the project carried out in fiscal 1997 were summed up. In the site survey, etc., visits were paid to France, Spain, Greek, Germany, the U.K. and the U.S. to have discussions and examine the trend of research on the NOx removal catalyst and catalyst combustion. In the actual R and D, the R and D were conducted on zeolite base NOx removal catalyst, oxide composite base NOx removal catalyst, alumina base NOx removal catalyst, direct decomposition type NOx removal catalyst, catalyst combustion, etc. In the R and D of the catalyst combustion, durability under high gas flow flux was examined of PdO-Pt/Ba-Al203 catalyst developed for low temperature use, which indicated that durability and low temperature activity were heightened. As high temperature use catalyst, high temperature durability was examined of the developed Pd0-La/Gd-ZrO2 catalyst, which showed that the durability was favorable. 322 refs., 261 figs., 55 tabs.

  19. Metabolism of pure sulfate-reducing bacteria in the presence of ferrous ions and environmental chages of the medium; Tetsu ion sonzaika ni okeru junsuina ryusan`en kangenkin no taisha to baichi no kankyo henka

    Energy Technology Data Exchange (ETDEWEB)

    Baba, F.; Suzuki, T. [Ajinomoto Co. Inc., Kawasaki (Japan). Technology and Engineering Lab.; Seo, M. [Hokkaido Univ., Sapporo (Japan). Graduate School of Engineering

    1996-10-15

    In this study, the pure sulfate-reducing bacteria were cultured in the medium with different Fe{sup 2+} concentration; shape and activity of the bacteria, the evolution amount of hydrogen sulfide directly related to the breath of the sulfuric acid and the change of the pH value in the medium were investigated during every time interval; and influence on the metabolism of the sulfate-reducing bacteria with Fe{sup 2+} was examined. As a result, the conclusions were obtained as follows: in the case of a medium with high Fe{sup 2+} concentration containing Fe{sup 2+} of 1.0{times}10{sup -2} molkg{sup -1}, the colloidal substance in which the main composition was considered as Fe(OH)2 were present, and they provided a comfortable place for the bacteria to grow. Correspondingly, in the case of a medium with low Fe{sup 2+} concentration containing Fe{sup 2+} of 3.6{times}10{sup -4} molkg{sup -1}, the colloidal substance was small and the number of bacteria was also few. The four kinds of shape of bacteria coexisted in the medium with increasing the culturing time. The hydrogen sulfide was mainly evolved by the bacteria with the comma like shape. During a period that this comma like bacteria actively moved, the hydrogen sulfide evolution increased. 13 refs., 6 figs., 1 tab.

  20. Report on the FY 1999 study of the decomposition/removal of environmental pollutants using laser induced chemical reaction; 1999 nendo laser yuki kagaku hanno wo mochiita kankyo osen busshitsu no bunkai jokyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    For the cleavage of carbon-chlorine connection and decomposition of benzene rings which are hazardous causes of the environmental pollutants represented by dioxins, the photolysis of gaseous phase chlorobenzene used as a model compound was made using KrF and ArF excimer laser. The decomposition is high efficiency, and ArF shorter in wavelength can be compounded twice-four times as fast as KrF. It was found out that in the system where oxygen exists, carbon monoxide, carbon dioxide, acetylene, hydrogen chloride, etc. are produced as decomposition products. From the results of the gaschromatographical analysis, chlorine compounds were detected as solid phase decomposition products. However, by the oxygen existence effect and laser shorter wavelength effect, the formation of polychlorinated aromatics was controlled, and chlorine compounds were made non-pollutant together with the composition. It was indicated that the environmental clean-up technology using laser is effective for making low-concentration environmental pollutants non-pollutant, and it is a method to clean up the environment which has a wide range of the application field. (NEDO)

  1. 1998 Annual Study Report. Surveys on seeds for global environmental technologies, including those for energy saving; 1998 nendo chosa hokokusho. Sho energy nado chikyu kankyo taisaku gijutsu no seeds ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The energy-saving and other global environmental technologies are surveyed by collecting relevant information from various institutes, both abroad and domestic, to contribute to development of ceramic gas turbines. USA has announced a climate change plan, based on the five principles, to promote utilization of high-efficiency technologies and development of new clean technologies. UK is promoting to improve energy efficiency, along with liberalization of its energy markets. Germany concentrates its efforts in the 'Program for Energy Research and Energy Technologies.' France places emphasis on prevention of air pollution and rational use of energy. The R and D trends at public institutes, e.g., universities, for global environmental technologies are surveyed, from which a total of 14 themes are extracted as the seed technologies. At the same time, a total of 9 techniques potentially applicable to the seeds are extracted by mainly reviewing JICST and patent information, and assessed. The R&D trends of the IPCC-related researchers are also surveyed, but provide no theme directly applicable to the seeds. Most of the related themes at the private and public institutes surveyed, both domestic and abroad, are concentrated on carbon dioxide. (NEDO)

  2. Report on regional new energy vision for Kawara town. Toward the creation of eco-symbiotic community (simplified version); Kawaracho chiiki shin energy vision gaiyoban. Kankyo kyoseigata shakai no sozo ni mukete

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-02-01

    A regional new energy vision has been formulated for Kawara town, Fukuoka Prefecture, in the hope that the industry, administration, and citizenry will be concerned with each other for the realization of an eco-symbiotic community. The fruits of endeavors exerted for this purpose are described in seven chapters, which are (1) the outline of surveys, (2) local characteristics of Kawara town, (3) policy toward introducing new energy, (4) measures for introducing new energy, (5) study of model projects, (6) introduction of new energy into Kawara town, and (7) efforts to realize the introduction. Described in chapter (5) are the introduction of photovoltaic power generation into primary and junior high schools, heat supply business utilizing waste heat from a plant, energy conservation at administration buildings, development of an activities program for people to learn energy related matters, and the results of studies conducted on the respective model projects. Concerning the activities program, several applications are considered, dependent upon who are to implement the program: volunteer students, local community leaders, experts, or administration officials. For the initial stage of learning under the program, a system is built under which experts, local community leaders, primary and junior highschool children, and their teachers cooperate with each other under the leadership of a project coordinator. (NEDO)

  3. Fiscal 1997 survey report. Feasibility study of the environmentally friendly type coal utilization system (survey of the coal utilization in Pakistan); 1997 nendo chosa hokokusho. Kankyo chowagata sekitan riyo system kanosei chosa (Pakistan ni okeru sekitan riyo gaikyo chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper made a literature survey, hearing survey, site survey/study on the coal in Pakistan such as the coal utilization system and the environmental situation, etc., and aimed at pre-examination for the survey of the introduction of the environmentally friendly type coal utilization system to be planned in Pakistan in the future. The examination, data collection and preparation were conducted in terms of the following items: the structure of coal consumption in energy supply, structure of coal consumption, mainly of domestic brown coal consumption, the situation of coal utilization by industry and by region, environmental problems caused by coal utilization such as air pollution, the trend of policies of environmental regulation, etc. The literature on the following was obtained and surveyed: the situation of economy/energy in Pakistan, coal utilization technology by industrial field, and environmental protection technology. The hearing survey was made to institutions concerned, corporation groups and men of learning and experience. Site surveys were conducted for the typically selected coal utilization equipment and existing environmental protection equipment. 66 figs., 56 tabs.

  4. Survey on the present situation and future outlook of energy/environment issues mainly on coal in the APEC region; APEC ikinai no sekitan wo chushin to suru energy kankyo mondai no genjo oyobi kongo no mitoshi ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    For the purpose of studying the energy supply/demand trend and the environmental problem relating mainly to coal in the APEC region, the paper surveyed the situation from the past to the present and outlooked the beginning of the 21st century. GDP in the whole APEC region increased at an annual rate of 3.4% from 1971 to 1991 and made a rapid growth of an annual rate over 7% especially in the non-OECD region. The supply/demand balance of coal, etc. in the non-OECD region is expected to be tight, and the energy price also to be higher. This will be a major factor causing hindrance to the economic growth of resource-importing countries. It is necessary to prepare the energy infrastructure. With the increasing coal utilization, it is feared that pollutants such as SOx, NOx and CO2 will increase, and it is necessary to introduce energy utilization technology/facilities which are high-efficient and environment-friendly and to expedite introduction of non-fossil energy. The APEC region, where the worldwide growth is expected, is a priming for the world development, and a policy which is well balanced in economic growth, stabilized energy supply, and environmental protection is needed for the region to achieve its sustainable growth. 50 figs., 24 tabs.

  5. Modeling of atmospheric corrosion environments and its application to constant dew-point corrosion test; Yagai taiki fushoku kankyo no modeling to sore ni motozuku teirotengata saikuru fushoku shikenho no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Muto, I. [Nippon Steel Corp., Tokyo (Japan)] Sugimoto, K. [Tohoku Univ., Sendai (Japan)

    1998-08-15

    Recently, stainless steel is increasing its demand for corrosion resistant building materials. Then, as it is necessary to develop and accelerating testing method capable of accurately estimating weatherability at sea side area, such testing method has no been developed yet because of difficulty to quantify corrosive environment relating to atmospheric corrosion phenomenon. As air temperature and relative humidity in outdoor change in complex, specific temperature and relative humidity cannot be used for their representative values. And, construction of corrosive factors such as sea salt particles, and so on are also much different at each area. However, at coastal area, a dew water dissolving the sea salt particles, so called droplets of chlorides aqueous solution is formed onto material surface. Then, in this study, on a base of drying and humidity absorption behavior and daily change behavior of temperature and humidity in outdoor, modeling of atmospheric corrosion environment was tried. An accelerating testing method according to this modeling was developed, long-term weathering test was compared with the corrosion behavior of the same steel, and validity of a new accelerating testing method was evaluated. 22 refs., 12 figs., 2 tabs.

  6. 1998 research cooperation project. Research cooperation on environment-compatible type water resource effective-utilization system; 1998 nendo kankyo taiogata mizushigen yuko riyo system ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    For the purpose of securing water stably and preventing water pollution in the Philippines, R and D were carried out on a wastewater treatment and water reclamation and reuse system which is easy to operate and maintain and low in cost through the research cooperation between the Philippine Industrial Technology Development Institute and Japan. According to the survey result of statistical data concerning water pollution load structure by industrial wastewater classified by the industry in the Philippines, enumerated are the food manufacturing industry, paper pulp manufacturing industry, and the textile dyeing industry as those greatly affecting water pollution in BOD exhaust and wastewater, etc. Consequently, with Ram Food Product Co. of vegetable processing and Solid Mill Co., of textile dyeing as plants to be studied, a wastewater treatment test was performed in a laboratory scale. From the result of the test, the pilot plant was basically designed to have 'anaerobic + aerobic treatment + tertiary treatment' for the treatment process, with an one-tank type UASB method used as the anaerobic treatment, with a sand filtration + activated charcoal treatment as the tertiary treatment, and with the cost effectiveness for water reuse set to be examined. (NEDO)

  7. Research cooperation project for fiscal 1999. Research cooperation on environment-compatible type water resource effective utilization system; 1999 nendo kankyo taiogata mizushigen yuko riyo system ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Efforts are made under this project to develop a wastewater treatment/regeneration system, easy to operate and maintain and low in cost, jointly with a Philippine research institute. Technologies are transferred to this institute concerning research and development, system designing, operation, maintenance, and management. The goal is to disseminate such technologies in the Philippines. As for fiscal 1999 endeavors, emphases are placed on the items described below. The Container Corporation which regenerates waste paper and the RAM Food Corporation which manufactures canned foods and pickles are selected as the sites for pilot plant research. Wastewater discharged by the two corporations is subjected to laboratory-scale wastewater treatment (combination of aerobic/anaerobic treatment and activated carbon adsorption), by which a pilot plant wastewater treatment process is determined and designing conditions are defined. As for activated carbon for advanced wastewater treatment, a fine grain sample, which is the lowest in price among activated coconut shell charcoals produced in the Philippines, is acquired, and tested for performance. A wastewater treatment pilot plant is complete at the Container Corporation, and has started operation. (NEDO)

  8. Survey on utilization of database for research and development of global environmental industry technology; Chikyu kankyo sangyo gijutsu kenkyu kaihatsu no tame no database nado no riyo ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    1993-03-01

    To optimize networks and database systems for promotion of the industry technology development contributing to the solution of the global environmental problem, studies are made on reusable information resource and its utilization methods. As reusable information resource, there are external database and network system for researchers` information exchange and for computer use. The external database includes commercial database and academic database. As commercial database, 6 agents and 13 service systems are selected. As academic database, there are NACSIS-IR and the database which is connected with INTERNET in the U.S. These are used in connection with the UNIX academic research network called INTERNET. For connection with INTERNET, a commercial UNIX network service called IIJ which starts service in April 1993 can be used. However, personal computer communication network is used for the time being. 6 figs., 4 tabs.

  9. Investigational study of evaluation of the global energy system as a global environmental protection technology; Chikyu kankyo taisaku gijutsu toshite no global energy system no hyoka ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    With relation to some global energy systems of which viability is predicted in the future, an evaluation was conducted from the viewpoints of economical efficiency, energy balance, CO2 emission, etc. The fossil fuel CO2 capture system, the conventional thermal power plant added with CO2 recovery/treatment facilities, is expected to reduce approximately 70-75% of the CO2 emission. The fossil fuel decarbonated hydrogen system, which decarbonates fossil fuels, recovers/treats CO2 at the place of fuel supply and uses as hydrogen, is of poor practical application from an economical point of view. The fossil fuel methanol synthesis system, which synthesizes methanol from fossil fuels at the place of fuel supply, generates electric power and recovers/treats CO2 with the methanol, is large in energy loss and CO2 emission and low in overall efficiency and CO2 reduction effect at the time of methanol synthesis. The renewable energy hydrogen system is an ultimate system with no emission of CO2, though it costs much. 110 refs., 83 figs., 107 tabs.

  10. Research and development achievement report for fiscal 1994 concerning the creation of advanced combustion technologies utilizing the microgravity environment; 1994 nendo bisho juryoku kankyo wo riyoshita kodo nensho gijutsu soshutsu ni kansuru kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    The development committee concluded an agreement about on-site researches with NASA (National Aeronautics and Space Administration) for an international joint study, and the joint study was started at the underground microgravity center. Experiments were conducted at microgravity experimenting facilities and the data obtained were subjected to analysis and evaluation, which eventually contributed to the accumulation of useful data. In this fiscal year, microgravity experimenting facilities were utilized for experiments and tests for (1) the evaluation of the combustion and vaporization of fuel droplets and fuel droplet arrays, (2) analysis and evaluation of high-density fuel combustion characteristics, (3) evaluation of flammability limits, and (4) elucidation of the mechanism of the generation of NOx and the like. A total of 112 drop tests were conducted, and the acquired data were subjected to analysis and evaluation for the elucidation of the combustion mechanism, and findings were collected as mentioned below. Learned were the combustion behavior of fuel droplets such as ignition and flame propagation under item (1), combustion behavior such as ignition and combustion of high-density fuel under item (2), combustion behavior and combustion limits of premixed fuel under (3), and measurement of distribution of combustion products such as OH in the droplet fuel flaming zone under item (4). (NEDO)

  11. Fiscal 1996 survey report on the environmentally friendly type coal utilization system feasibility study. Survey by region/industry in India; Kankyo chowagata sekitan riyo system kanosei chosa. Indo ni okeru sekitan riyo gaikyo chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    A survey was made in India which is a coal producing/consuming country following China in Asia and where coal is used for about 60% of the primary commercial energy. The survey was conducted on coal production/distribution/utilization and environmental issues, aiming at studying feasibility of introducing the environmentally friendly coal utilization system into every industry including the residential/commercial one, and at implementing a comprehensive master plan including Japan`s international cooperation. Total power source facilities in fiscal 1995 are 83.3 million kW, 64% of which are coal thermal power facilities and generated 260 TWh, 69% of the total output energy. Main commercial energy sources are coal, oil and natural gas, and oil is self-sufficient. The survey this time did not examine very well the actual state of the environmental pollution problem caused by the coal utilization. Indian coal is high in ash content but low in sulfur content, and therefore, SOx polluting air has not been a very important problem so far, but soot/smoke is almost the problem. Further, ash treatment after combustion at boilers, etc. is expected to be a big problem in the future. 49 figs., 88 tabs.

  12. Investigations on a global environment improving technology utilizing biological functions. 2. Structuring a ligno-bioprocess; Seibutsu kino wo riyoshita chikyu kankyo kaizen gijutsu ni kansuru chosa. 2. Riguno bio process no kochiku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Discussions were given to reserve global environments on reducing dependence on fossil resources and more effectively utilizing wood resources. Economically utilizable amount of wastes from lumbering factories reaches about five million tons annually. Discussions were made on a ligno-bioprocess that uses these wastes. The current quantitative production efficiency of cellulase by means of bacterial breeding is very high. A problem is production of ligninolytic enzymes, to which application of the recombinant DNA method is indispensable. Combination of steam explosion with biological decomposition or the organosolv process is an effective method for lignin decomposition. Decomposition of cellulose by using the ultra critical water method is worth noticing. With respect to hemicellulose utilization, production of cellulose derivatives, biodegradable polymers and oligosaccharides would be conceivable by means of esterification and etherification. Vanillinic acid, adhesives, resins and lignin-based polymer materials could be manufactured from lignin. Material cost for these products accounts for about 35% of the product price, thus making the lignochemicals promising commercial products. 301 refs., 71 figs., 39 tabs.

  13. USW[center dot]33M-VS wind power turbine winning a 1993 environmental department prize of Discover Magazine. 1993 nendo DISCOVER kankyo bumonsho ni USW/33M-VS furyoku turbine

    Energy Technology Data Exchange (ETDEWEB)

    Ushiyama, M. (Waseda University, Tokyo (Japan))

    1993-12-01

    This paper introduces a variable speed wind power turbine developed jointly by EPRI and US Wind Power Corporation. This wind power turbine has a wind velocity responsive construction in which generated alternating current power has the frequency vary with change in the shaft rotation speed. The specified performance calls for a cut-in of 4 m/s and cut-out of 29 m/s, wind velocity variable. The blades are made of laminated fiberglass, and the rotor has a diameter of 33 m, rotation variable. The tower height is classified to 24 m, 30 m, and 42 m. The blade pitch is controlled by a linear hydraulic cylinder, and the turbine is controlled by a microprocessor. The wind turbine has a system interconnecting control and data collecting system. Two induction three-phase generators are used. EPRI has calculated its power generation cost at 5 cents/kWh if wind blows at an annual average velocity of 16 miles per hour. This is nearly equivalent to the cost at new power plants. US Wind Power Corporation has disassembled 22 experimental models that have been in operation to investigate wear in the machines. Its economy is evaluated comparable with that for fossil fuel technologies. 1 fig.

  14. Fiscal 1998 research report. R and D on advanced combustion technology under microgravity environment; 1998 nendo seika hokokusho. Bisho juryoku kankyo wo riyoshita kodo nensho gijutsu soshutsu ni kansuru kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Research was made on explication of a combustion phenomenon by using a microgravity facility, and a combustor possible to realize advanced combustion technology. In the basic research composed of 5 themes by the international joint research with NASA, 52 drop experiments using JAMIC's facility and 100 drop experiments using NASA's 2.2s drop tower were carried out. The themes are composed of an interaction in droplet arrays combustion, combustion of binary fuel sprays, combustion characteristics of solid fuel, flame dynamics around a lean flammability limit, and mass transfer around a combustion field. In the experiment using the microgravity experiment facility and analysis evaluation of the experimental data, studies were made on combustion and evaporation of fuel droplets, combustion characteristics of dense fuel, flammability limit, formation mechanism of NO{sub x} and an advanced combustor. For applying a pre-evaporating/pre- mixing combustion system to a combustor for aircraft engines, studies were made on some issues such as improvement of a combustion stability, NO{sub x} discharge characteristics, and optimum fuel atomizing. (NEDO)

  15. FY 1995 report on the cooperative research on the development of environmentally friendly high efficiency mineral resource extraction/treatment technology; 1995 nendo kankyo chowagata kokoritsu kobutsu shigen chushutsu shori gijutsu no kaihatsu ni kansuru kenkyu kyoryoku hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    This promotion project on the cooperative research aims to efficiently extract and recover valuable metals (gold, silver, copper, rare metal, etc.) including in large quantity in tailings of ores in the Republic of Kazakhstan. In FY 1995, conducted were the field survey, support study in Japan, acceptance of researchers from Kazakhstan, conceptual design of pilot plant, etc. The ore/mineral for Cu is mainly an alteration ore of chalcopyrite. Au and Ag are low grade and unknown, and the main gangue mineral is pyrite. The low grade ore (waste/much) of the Nikolayevska mine has a tendency to leaching at normal temperature, but the ore of mostly chalcopyrite such as tailings from each place has difficulty in leaching. It gets leaching by increasing temperature. The more the temperature rises, the more conspicuous the reaction becomes. Further, chalcopyrite is leached with priority over pyrite. From the result, a technical potentiality was obtained of leaching of low grade chalcopyrite in tailings mostly of pyrite. The existence of Thiobacillus ferrooxidans was confirmed. As to the recovery method for Au and Ag, CIC is studied. The process of waste/much is solvent extraction, electrowinning study and leaching, and that of tailings is bacteria leaching and leaching study. (NEDO)

  16. NEDO Forum 2001. Session on development of energy and environmental technologies (For promotion of comprehensive development of hydrocarbon-based energy); NEDO Forum 2001. Energy kankyo gijutsu kaihatsu session (tanka suisokei energy no sogo kaihatsu suishin no tame ni)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-09-20

    The presentations made at the above-named session of the NEDO (New Energy and Industrial Technology Development Organization) forum held in Tokyo on September 20, 2001, are collected in this report. Pointed out in a lecture entitled 'How technology development for hydrocarbon-based energy resources should be' was the need of technologies for clean energy production; CO2 emission reduction; NOx, SOx, soot, and dust reduction; and the expansion of exploitation of resources now left unused. Reported in a lecture entitled 'Cooperation with China on coal liquefaction' were the result of a coal liquefaction demonstration plant feasibility study conducted for coal from Inner Mongolia, and so forth. Reported in a lecture entitled 'Development of coal oil upgrading technology' were the result of the operation of a test plant, and so forth. Reported in a lecture entitled 'Research and development of HyperCoal' were the result of HyperCoal manufacturing technology research and development, designing of a HyperCoal-fired gas turbine power generation system, and so forth. In addition, development of technology for high efficiency conversion of biomass energy and development of technology for refuse gasification/melting power generation were reported. (NEDO)

  17. Fiscal 1994 survey report. Part 2. Study on soil environment remediation system using ecological information and functions; 1994 nendo seitaikei joho to seitaikei kino ni yoru dojo kankyo fukugen system no chosa hokokusho. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    A survey is conducted of the feasibility of soil environment remediation through detecting contamination of soil and changes in ecosystems caused by industrial activities, with attention paid to biological antagonists. In this fiscal year, based on the results of surveys conducted in the past, studies are continued mainly on hypersensitive biosensing technology using ecosystem functions, remote sensing technology to monitor the terrestrial vegetation and soil environment over wide areas, and soil environment remediation technology using biological antagonists and vegetation. In consideration of Europe's long experience in this field, seven organizations known for their accomplishments are visited, where interviews are held. There is a close relationship between soil environments and ecosystems, and ecosystems are provided not only with information on changes in soil environments but also with functions to remedy soil environments by minimizing secondary contamination. To put such information and functions to practical use, element technologies are indispensable, including hypersensitive soil environment biosensors and environmental remediation by identification and isolation of biological information carrying substances and by vegetation. Proposed in this report is a project for soil remediation by use of biological information and functions and for elucidation of biological antagonists. (NEDO)

  18. Fiscal 1995 survey report on the environmentally friendly type coal utilization system introduction support project. Verification project on the circulating fluidized bed boiler; Kankyo chowagata sekitan riyo system donyu shien jigyo. Junkan ryudosho boiler ni kakawaru jissho jigyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-01

    In relation to the circulating fluidized bed boiler which reduces the amount of sulfur oxides emitted in coal utilization, a verification project was carried out on installation of the equipment and spread activity in China and the Philippines contributing to the control of environmental pollutant associated with coal utilization and the effective use of energy. At the Fanshan area, installed was a 10t/h internal circulating fluidized bed boiler. At the performance test, coal includes around 7% of impurities such as stone, and the impurities should be excluded continuously at the time of actual run. Therefore, the boiler efficiency had to be changed from 89.5% to 85.8%. Further, power generation facilities have not yet been finished, and the overall operation of boiler turbine has not been executed. At the Zibo area, a 30t/h external circulating fluidized bed boiler was installed. The boiler efficiency reached 86.1%, over the targeted value. At the Batangas area in the Philippines, a 10t/h internal circulating fluidized bed boiler was installed. The boiler efficiency reached 85.8%, over the designed value. About the coal produced in the Philippines, slagging was feared, but the combustion state was favorable. 82 figs., 21 tabs.

  19. Report on regional new energy vision for Kawara town. Toward the creation of eco-symbiotic community; Kawaracho chiiki shin energy vision hokokusho. Kankyo kyoseigata shakai no sozo ni mukete

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-02-01

    A regional new energy vision has been formulated for Kawara town, Fukuoka Prefecture, in the hope that the industry, administration, and citizenry will be concerned with each other for the realization of an eco-symbiotic community. The fruits of endeavors exerted for this purpose are described in seven chapters, which are (1) the outline of surveys, (2) local characteristics of Kawara town, (3) policy toward introducing new energy, (4) measures for introducing new energy, (5) study of model projects, (6) introduction of new energy into Kawara town, and (7) efforts to realize the introduction. Described in chapter (5) are the introduction of photovoltaic power generation into primary and junior high schools, heat supply business utilizing waste heat from a plant, energy conservation at administration buildings, and the development of an activities program for people to learn energy related matters. Several applications are considered concerning the activities program, dependent upon who are to implement the program: volunteer students, local community leaders, experts, or administration officials. In relation to heat supply business, studies are conducted about the supply of waste heat from a cement plant to public facilities such as the town hall and administration buildings in the form of medium pressure steam or hot water. (NEDO)

  20. New energy vision for Kunigami village. Building a Village Friendly to the Environment in the 21st Century; Kunigamison shin energy vision. 21 seiki no shizen kankyo ni yasashii mura zukuri

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-02-01

    A new energy vision has been formulated for Kunigami village, Okinawa Prefecture, for dealing with environmental problems and for activating the region through the utilization of new energy. It is a 6,000-strong village located at the northern end of the mainland of the Ryukyus, which consumed 35 GWh of electric power in fiscal 1998. The results of activities in this connection are summarized in seven chapters, which are (1) the current state of Kunigami village, (2) current state of new energy, (3) existing amount of new energy, (4) survey using questionnaires, (5) basic policy toward new energy introduction, (6) new energy vision formulation, and (7) a system for new energy introduction. Chapter (6) is constituted of the formulation of new energy projects and conditions to satisfy for their realization, with the projects covering the introduction of photovoltaic power generation, wind power generation, small scale hydroelectric power generation, and clean energy vehicles and the implementation of popularizing and enlightening activities. Under the project for popularizing and enlightening activities, information will be disseminated, people will receive education about environments, economic support will be provided, and support will be extended to enterprises for their beginning new energy businesses. The economic support to be provided will involve the introduction of the support systems of the Government and the study of the creation of a village operated support system. (NEDO)

  1. FY 1995 result report. Research/development on the creation of high-grade combustion technology using a microgravity environment; 1995 nendo seika hokokusho. Bisho juryoku kankyo wo riyoshita kodo nensho gijutsu soshutsu ni kansuru kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    This report summarized the results of the research survey carried out by Japan Space Utilization Promotion Center (JSUP) under the contract with NEDO's industrial technology research and development department. This research survey is aimed at creating high-grade combustion technology which can respond to the decrease in environmental pollutant in combustion exhaust gas from viewpoints of energy diversification and global environmental preservation in consideration of the stabilized energy supply. Established inside JSUP is a research/development committee on high-grade combustion technology which is organized by men of learning and experience from universities, national institutes, private companies, etc. Following FY 1994, the following were continuously conducted: (1) joint research with NASA as an international research cooperation; (2) test using microgravity test facilities and analysis/evaluation of the test data. The experiment was conducted using facilities, etc. of the underground gravity-free test center established as a part of the national research base arrangement project. A lot of experimental data were obtained and stored which are useful for elucidation of the combustion mechanism and the development of ground combustor. (NEDO)

  2. International research cooperation in fiscal 1997. Report on the research, development, and evaluation of environmentally-friendly combustion technologies; Kokusai kyoryoku jigyo. Kankyo chowagata nensho gijutsu ni kansuru kenkyu kaihatsu hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Concerning the research and development of environmentally-friendly combustion technologies that had been conducted for six years beginning in 1992, analysis and discussion were made by a special committee dedicated to the evaluation of the efforts, and the outcome is stated. In the study of zeolite-base catalysts, a highly active catalyst was developed which assumes a multilayer structure of mordenite, etc., with titanium introduced thereinto using an NO-selective reducing catalyst. As for metal complex oxide-base catalysts, various catalysts high in activity were developed, based on saponite which is a laminar, clayey compound. As for alumina-base catalysts, details were learned of the reaction mechanism and catalysis activation sites and, helped by the findings, a silver-supporting alumina catalyst was produced. In the study of direct decomposition type NOx removing catalysts, a success was achieved in causing NO to be decomposed with high selectivity in an oxygen atmosphere by use of new-type electrodes, functional layers, and solid electrolytes. In the field of catalytic combustion, a PdO-Pt/Ba-Al2O3 catalyst was developed, which is to serve for a hybrid type catalytic combustion method. 19 refs., 112 figs., 25 tabs.

  3. Report for fiscal 1998. Joint research of environment-friendly system for effectively utilizing water resources; 1998 nendo hokokusho. Kankyo taiogata mizushigen yuko riyo system ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The research is conducted in cooperation with Industrial Technology Development Institute of the Philippines, and aims to solve water related problems such as unstable water supply and water quality pollution though developing a waste water treatment and recycling system which is easy to operate and maintain, low in cost, and usable in the Philippines. Fiscal 1998 is the second year of the project. Statistics are studied about the load that each industrial branch imposes on water for its pollution, and it is found that food manufacturers, paper pulp mills, and fiber dyeing plants are heavily responsible for water pollution. A method consisting of single-tower UASB anaerobic treatment and activated sludge treatment is applied as a water treatment process to Ram Food Products Corporation, and its optimization is studied. A removal rate 60% is achieved after a 12-hour treatment period at a COD (chemical oxygen demand) rate of 8g/liter/day. A method consisting of coagulating sedimentation and activated sludge treatment is applied to the waste water from a Solid Mill Corporation dyeing plant, when it is found that the water after ultimate treatment is almost colorless and that COD is 76mg/liter and BOD (biological oxygen demand) 13mg/liter, and these suggest that the waste water is recyclable. Since it is low in COD removing rate, the application of anaerobic treatment to high-concentration water after washing is not appropriate. (NEDO)

  4. FY1998 Report of surveys on network possibility involved with proliferation and transfer of environmental technologies (Europe, Australia and New Zealand); 1998 nendo kankyo gijutsu no fukyu iten ni kakawaru network kanosei chosa hokokusho . Oshu Goshu New Zealand

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    At the third Conference of the Parties to the United Nations Framework Convention for Climate Change (COP3) held in December 1997, the industrialized nations have agreed on development and proliferation of innovative technologies under international cooperation and transfer of environmental technologies to developing countries by expanding and strengthening CTI being the framework to be progressed spontaneously. Under the international strategic research project for global environment, NEDO has been promoting positively the research and development, whose support is urged to be expanded further in the future upon receiving the present agreement. Therefore, NEDO has performed the present survey in order to propose frameworks and measures for strengthening and expanding CTI. From among the policies and measures to be taken by the related countries based on the COP3 protocol, fiscal 1997 has performed review and new establishment of plans involved with execution of the items related to technology development, and surveys on action movements such as review and expansion of the measures, as the first stage. Fiscal 1998 has executed surveys focusing on the network for technology proliferation and transfer to developing countries as the second stage. (NEDO)

  5. Fiscal 1996 international research cooperation project. Report on the R and D result of the environmental harmony type combustion technology; 1996 nendo kokusai kenkyu kyoryoku jigyo. Kankyo chowagata nensho gijutsu ni kansuru kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The research was conducted jointly with Europe of a catalyst which enables clean combustion and NOx removal in polluted gas in combustion flue gas, etc. Reformation of mordenite and {beta}-zeolite was done by ion exchange, ion implantation, and membrane formation. A catalyst was searched for to obtain reducing agents, C5-C8 components, by decomposing light oil. Saponite, clay compound, showed by copper and silver ion exchanges approximately 50% of activity under 20,000h{sup -1}, C3H6 reducing agent, and without steam. The effect of the temperature of sintering on NOx selective reductionality of silver-carrying alumina catalyst was studied, and in sintering at 800degC, activity increased. When using conductive oxides like ruthenium oxide for electrolyte, NO decomposition selectivity increased. As to the functional layer carried above the Pd electrolyte, iron oxide and magnesium oxide increased NO decomposition selectivity. PdO and rare earth oxides forming compounds controlled variation of activity by dissociation/reoxidation of PdO. As to PdO/Gd203, the initial methane combustion activity was favorable, but there was seen deterioration with age. 271 refs., 281 figs., 58 tabs.

  6. Fiscal 1995 international research cooperation project. Report on the R and D result of the environmental harmony type combustion technology; 1995 nendo kokusai kenkyu kyoryoku jigyo. Kankyo chowagata nensho gijutsu ni kansuru kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The research and development were conducted jointly with Europe of an environmental harmony type high efficient catalyst which enables clean combustion and NOx removal in polluted gas in combustion flue gas, etc. In the research and development of NOx removal catalyst such as zeolite base, reformation of mostly mordenite was done by ion exchange, ion implantation, skeleton element substitution, etc. A possibility was found out of applying the membrane formation method except ion implantation as reforming means. In the R and D of the complex oxide base NOx removal catalyst, it was found that the catalyst carrying copper and silver on silica and layer clay compound under optimum conditions shows peculiarly high activity, and there is little decrease in the activity, but rather increase in it even under vapor existence. An evaluation was made of NO resolution of direct resolution element carrying noble metal electrolyte on solid electrolyte, finding out that the highest NO selectivity is shown with Pd as electrolyte and at a baking temperature of about 1300degC. Development of high- and low-temperature catalysts was also made. 417 refs., 286 figs., 63 tabs.

  7. Reduction of energy essential to human life by 70%. Environment-friendly residence `ED-1` utilizing the sunlight effectively; Seikatsu ni hitsuyona energy no 70% sakugen. Taiyoko riyo no kankyo kyosei jutaku ED-1

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-09-01

    This paper presents the environment-friendly residence `ED-1` utilizing the sunlight effectively. ED-1 of 97m{sup 2} in first floor area and 81m{sup 2} in second one has, on its roof, the photovoltaic power generation system, the solar hot water collector which supplies hot water by circulating heated antifreezing solution into a hot storage tank, and the solar hot wind collector which largely contributes to energy saving together with a hot room named an S unit on the first floor. The small S unit faced toward the south adjacent to a dining room is made of timber and thermal insulation glass. The S unit stores heat in a floor by taking the sunlight into a room in winter, while enhances a heating effect by discharging stored heat in nighttime. In some cases, duct circulation of heated wind is possible. Solar radiation of 90% can be removed by outside glass fiber screen of the S unit together with double glazing coated by special metal film. Roof material is superior in heat insulation, air tightness and energy saving, while floor material in sound insulation and heat storage. The target for reducing energy essential to human life by 70% was thus nearly achieved. 1 fig.

  8. FY1996 research cooperation for the development of the environmentally friendly technology for highly efficient mineral resources extraction and treatment; 1997 nendo kankyo chowagata kokoritsu kobutsu shigen chushutsu shori gijutsu no kaihatsu ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The above-named project aims to jointly develop technologies to efficiently extract and recover valuable metals (gold, silver, copper, rare metals, etc.) from slag, with caution fully exercised to conserve the environment, for effectively utilizing non-ferrous resources in the Republic of Kazakhstan. The effort covers a seven-year period beginning in fiscal 1994. The elements which are studied are technologies that involve leaching, solvent extraction, electroextraction, recovery of gold and silver, and waste water treatment. In this fiscal year, wet treatment, gold and silver treatment, and waste water treatment are studied in on-site joint researches and in domestic researches for specimens sampled at the Kazakhstan site. In addition, based on the results of the above-said basic researches, some parts of the pilot plant to be constructed is designed and manufactured. For propelling forward the project, equipment necessary for joint research is procured and forwarded to the site, and Kazakhstan scientists are invited to Japan for training. (NEDO)

  9. Research on the establishment of the database system for R and D on the innovative technology for the earth; Chikyu kankyo sangyo gijutsu kenkyu kaihatsuyo database system ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    For the purpose of structuring a database system of technical information about the earth environmental issues, the `database system for R and D of the earth environmental industrial technology` was operationally evaluated, and study was made to open it and structure a prototype of database. In the present state as pointed out in the operational evaluation, the utilization frequency is not heightened due to lack of UNIX experience, absence of system managers and shortage of utilizable articles listed, so that the renewal of database does not ideally progress. Therefore, study was then made to introduce tools utilizable by the initiators and open the information access terminal to the researchers at headquarters utilizing the internet. In order for the earth environment-related researchers to easily obtain the information, a database was prototypically structured to support the research exchange. Tasks were made clear to be taken for selecting the fields of research and compiling common thesauri in Japanese, Western and other languages. 28 figs., 16 tabs.

  10. Investigation on construction of the database system for research and development of the global environment industry technology; Chikyu kankyo sangyo gijutsu kenkyu kaihatsuyo database system no kochiku ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    1993-03-01

    This paper studies a concrete plan to introduce a new database system of Research Institute of Innovative Technology for the Earth (RITE) which is necessary to promote the industrial technology development contributing to solution of the global environmental problem. Specifications for system introduction are about maker selection, operation system, detailed schedule for introduction, etc. RITE inhouse database has problems on its operation system and its maintenance cost, and is apt to be high in a construction cost in comparison with a utilization factor. Further study is made on its introduction. Information provided by the inhouse database is only the one owned by the organization, and information outside the organization is provided by the external database. The information is registered and selected by the registerer himself. The access network is set by personal computer network at the beginning and is set to transit to INTERNET in the future. For practical construction of the system, it is necessary to make user`s detailed needs clear for the system design and to adjust functions between hardware systems. 32 figs., 9 tabs.

  11. Fiscal 1993-1998 integrated research report. R and D on advanced combustion technology under microgravity environment; 1993 - 1998 nendo sogo seika hokokusho. Bisho juryoku kankyo wo riyoshita kodo nensho gijutsu soshutsu ni kansuru kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    For developing advanced combustion technology by using JAMIC's facility, the advanced combustion technology research committee supported by researchers of universities, national institutes and industries was prepared in JSUP, and R and D using a microgravity experiment facility and the international joint research with NASA were carried out. By using the advanced experimental equipment and measuring instrument developed for microgravity experiments, studies were made on combustion and evaporation of fuel droplets, combustion characteristics of dense fuel, flammability limit and NO{sub x} generation mechanism, and such precious results were obtained as storage of abundant experimental data, explication of a combustion mechanism, preparation of a database and find of new phenomena. In the ground verification experiment using the newly fabricated advanced combustor test equipment, various data effective for developing high-efficiency low-pollution combustors were obtained. Through the joint research with NASA including 5 themes, various results and the real relationship between the researchers were also obtained. (NEDO)

  12. FY 1997 report on the research for construction of NEDO`s vision. Regional environment and international collaboration; 1997 nendo chosa hokokusho (NEDO vision sakutei ni muketa chosa kenkyu). Chiiki kankyo to kokusai kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    It is necessary for NEDO to transfer the energy technology to developing countries and conduct collaborations with them efficiently. First of all, environments of the community were analyzed from a viewpoint of natural environment, social and cultural environment, and industrial and economic environment. Then, this report outlines the organizations of domestic and international aid agencies which have potentials to conduct alliance and collaboration with NEDO, and also illustrates their activities including financing and technology exchange, regional activities, and progress of activities. Alliances and collaborations with NGOs of each international organization were analyzed on the aspect of the fields and know-how of alliance with NGOs, selection standards of NGOs and necessary systems and organizations to make effective alliance and collaboration with NGOs, and some case studies were taken. Organization, purposes and activities of NGOs in Asian countries are introduced, and their current situations are illustrated. Finally, some proposals were offered to make alliances and collaborations with aid agencies and NGOs. They are concerned about the fields and know-how of alliance with NGOs, selection standards of NGOs and necessary systems and organizations to make effective alliance and collaboration with NGOs. 44 figs., 8 tabs.

  13. Research program for environmentally-friendly coal utilization system. Follow-up project for simplified desulfurizers (Weifang Chemical Industry Works); Kankyo chowagata sekitan riyo system donyu shien jigyo. Kan`i datsuryu setsubi ni kakawaru follow up jigyo (Weifang kakosho)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    To suppress the emission of environmental pollutants from coal utilization in China and to contribute to stable security of Japan`s energy, demonstration of clean coal technology and consolidation of diffusion base to be introduced into China have been promoted. Demonstration program for diffusing simplified desulfurizers has been promoted. For accelerating the achievement, experts of desulfurizers were delegated to Weifang Chemical Industry Works, to support the program. Exhaust gas is introduced from boiler via water spray dust remover, suction fan and centralized stack into absorption tower of the simplified wet-type desulfurizer. In the ascending process, the exhaust gas contacts with absorbent, to remove SO2 and dust. The absorbent is blasted up through the spray nozzle. The absorbent is oxidized by the air into sulfate ion in the liquid chamber at the lower part of tower, and neutralized by hydrated lime to form gypsum. Through the continuous operation for two years, understandings were remarkably increased. However, good treatment of the tax system is required for further diffusion. Though there are no problems for ordinary start and stop, emergency operation is insufficient. There are some problems in the maintenance due to the delay of finding failures. 16 figs., 1 tab.

  14. FY 1996 result report. Research/development on the creation of high-grade combustion technology using a microgravity environment; 1996 nendo seika hokokusho. Bisho juryoku kankyo wo riyoshita kodo nensho gijutsu soshutsu ni kansuru kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    With the aim of creating high-grade combustion technology which can respond to the decrease in environmental pollutant in combustion exhaust gas, the high-grade combustion technology research development committee was established inside JSUP (Japan Space Utilization Promotion Center), using the underground gravity-free test center. Following FY 1995, the following were conducted: (1) international joint research with NASA, and (2) tests using microgravity test facilities, etc. and analysis/evaluation of the test data. As to the international joint research, a lot of new information was obtained through the adjustment conference with NASA. Further, there were a lot of results obtained from joint tests and researches. Moreover, the leading experimental device and measuring device which are usable in the microgravity field were developed/prepared. Conducted were combustion/evaporation evaluation experiments on fuel droplet and groups of droplet, combustion characteristics elucidation evaluation experiments on high-density fuels, evaluation experiment on flammability limits, and elucidation evaluation experiments on emission mechanism of NOx, etc. Through those, abundant experimental data were able to be accumulated, and a lot of precious knowledge/information were obtained. Besides, the fabrication of high-class combustor test equipment for ground demonstration was started. (NEDO)

  15. Research cooperation project for fiscal 1998. Research cooperation on the research and development of environment measuring laser radar (Follow-up); 1998 nendo kankyo keisokuyo laser reda no kenkyu kaihatsu ni kansuru kenkyu kyoryoku. Flow up

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Research and development of laser radars for observing urban atmospheric pollution is jointly conducted by Japan and Indonesia for the goal of contributing to the construction of an administrative system on environmental matters compatible with the actualities of Indonesia. Under this project, laser radars are installed at three sites in the city of Djakarta where environmental problems are increasingly serious, an observation network system is constructed connecting the laser radar sites, and the data are collected, analyzed, and processed by a data processing center. This enables the acquisition of information about the pollution of urban atmosphere through the observation of the 3-dimensional distribution of atmospheric pollution. In fiscal 1998, the last year for follow-up, engineers and researches are dispatched by 'ODA (official development assistance) laser radar observation assistance committee' for assistance in system maintenance and pollution observation. System maintenance is carried out so that the laser radar system may be utilized by the Indonesian party. Observation assistance involves Mie scattering, and the Indonesian party is engaged in a long-term continuous laser radar observation. (NEDO)

  16. Fiscal 2000 achievement report. Development of comprehensive technologies for environmental conservation including prevention of global warming by the carbonization of wood, etc.; 2000 nendo jumoku nado no tanka ni yoru ondanka boshinado fukugo kankyo taisaku gijutsu no kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Efforts are exerted to develop new technologies whereby carbon dioxide is absorbed by and fixed in rapidly growing trees. The trees are felled and subjected to high-efficiency carbonization, and the thus-obtained carbonized material is used for environmental purification or the like and then buried in the ground. Studies are under way to find out if the cycle (operations) may be organized into an industry. Activities are conducted in the five fields of (1) carbonized materials, (2) carbonization, (3), industrial use of charcoal, (4) stabilization of charcoal, and (5) reports on surveys (mainly overseas). In field (2), following an introduction consisting of the carbonization mechanism and the definition of terms, surveys are conducted of the existence of carbonizable resources in Japan, distribution channels of imported charcoal and activated charcoal in Japan, various carbonization apparatuses, carbonization equipment incorporated into gasifying fusion furnaces, carbonization furnace as a system, and the trends of development of pyroligneous acid and development of its use. In field (3), studies are made on its use in industries, on its application to agriculture, forestry, and livestock industry, and on the utilization of its electromagnetic properties. (NEDO)

  17. Fiscal 1998 research report. Study on the feasibility of microorganism biotechnology for effective use of environmental pollutants. Pt. 2; 1998 nendochosa hokokusho. Kankyo osen busshitsu no shigenka no tame no biseibutsu bio technology riyo kanosei ni kansuru chosa. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Study was made on the feasibility of microorganism biotechnology for effective use of environmental pollutants and unused resources. Microorganisms and microorganism enzymes for decomposing lignocellulose were viewed, and uses of hydrolysis products were summarized. Production of microorganisms applicable to fodder, composting, and production of energy sources (methane, hydrogen, ethanol) were studied. Use of vegetable fiber residues such as beer lees as fungus cultivation medium and conversion to valuable substances were also studied. Microorganisms treatment (MT) of wastes in fats and oils industry was summarized. Effective use of MT of protein waste from marine products was studied. MT of manures with the greatest impact on environment as livestock waste was summarized. The necessity of separate collection of domestic wastes, and composting and methane fermentation of kitchen garbage were reported. The feasibility of MT of plastic wastes, and decomposition of halogenated methane with high toxicity were also studied. (NEDO)

  18. FY 2000 survey report on the project on energy conservation/environmental preservation for oil corporations in Croatia by rehabilitation of oil refinery; 2000 nendo Croatia sekiyu kosha muke seiyusho no rihabiri ni yoru shene kankyo hozen project chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of strengthening the international competitive force in the oil industry of Croatia and reducing greenhouse effect gas by introducing energy conservation technology, study was made of the rehabilitation of oil refineries (Rijeka and Sisak) of Croatia's oil corporation, INDUSTRIJA NAFTE d.d. (INA). Rijeka and Sisak Refineries have the oil processing capacity of 6 million t/y and 4.6 million t/y, respectively, but they were constructed during the 1960s-1970s and are now superannuated. In this project, the following are adopted: heightening of the temperature of raw material supply, surging avoidance control, reutilization of condensate water of vacuum distillation, heightening of MEA concentration, control of excess air ratio in heating furnace, preheating of combustion air in heating furnace, application of small-diameter pump impeller, the optimum control of steam/electric system, heightening of temperature of cleaning water of desalting device, stop of adoption of flare seal gas, etc. The energy conservation effect to be expected from the project is 43,065 toe/y in a total of the two refineries, and the reduction in greenhouse effect gas is 133,000 t-CO2/y. Further, the internal return rate is 53.12%, which is very attractive for INA. (NEDO)

  19. Fiscal 1994 survey report. Part 2. Study on soil environment remediation system using ecological information and functions; 1994 nendo seitaikei joho to seitaikei kino ni yoru dojo kankyo fukugen system no chosa hokokusho. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    A survey is conducted of the feasibility of soil environment remediation through detecting contamination of soil and changes in ecosystems caused by industrial activities, with attention paid to biological antagonists. In this fiscal year, based on the results of surveys conducted in the past, studies are continued mainly on hypersensitive biosensing technology using ecosystem functions, remote sensing technology to monitor the terrestrial vegetation and soil environment over wide areas, and soil environment remediation technology using biological antagonists and vegetation. In consideration of Europe's long experience in this field, seven organizations known for their accomplishments are visited, where interviews are held. There is a close relationship between soil environments and ecosystems, and ecosystems are provided not only with information on changes in soil environments but also with functions to remedy soil environments by minimizing secondary contamination. To put such information and functions to practical use, element technologies are indispensable, including hypersensitive soil environment biosensors and environmental remediation by identification and isolation of biological information carrying substances and by vegetation. Proposed in this report is a project for soil remediation by use of biological information and functions and for elucidation of biological antagonists. (NEDO)

  20. Research cooperation report for fiscal 1997 on the environment-friendly system for effectively utilizing water resources; 1997 nendo kankyo taiogata mizushigen yuko riyo system ni kansuru kenkyu kyoryoku itaku gyomu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This effort exerted in cooperation with the Philippines aims to solve problems related to water resources such as stable supply and pollution of water through developing a waste water treatment/water reuse system which is easy to operate and maintain, and low in price. The ultimate goal includes (1) the construction of a waste water treatment/water reuse system comprising an anaerobic reaction tank and activated charcoal absorption tower, easy to operate and maintain, and low in price, (2) the employment of goods procurable in the Philippines, the goods including carriers for use in the anaerobic reaction tank, microbes for use in both aerobic and anaerobic reaction tanks, and activated charcoal for use in waste water reutilization, and (3) the establishment of optimum operating conditions for the waste water treatment/water reuse system by use of a pilot plant and the transfer of operating and managing techniques to the Filipino counterpart. In this fiscal year, investigations are conducted to disclose the actualities of waste water treatment and water consumption by primary industries in the vicinity of Laguna de Bay, and the waste water to be the object of study and the place of pilot plant installation have been selected. Also conducted are investigations into the carrier, microbe, activated charcoal, etc., for use in the anaerobic reaction tank. (NEDO)

  1. Studies on legal systems and public decision-making process of the environmental protection and natural conservation; Kankyo{center{underscore}dot}shizenhogo no mirai no tameno koukyoteki kettei to sisutemu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Hayashida, Seimei [Hokkaido University, Hokkaido (Japan). Faculty of Law

    1998-12-16

    This study have dealt with the issues of how the policies of environmental and natural protection should be shaped in a democratic society, and what the optimal legal systems should be for realizing the policies. We have analyzed these issues from the following three points of view ; the first one is the legal philosophical issues of justice and moral values among individuals and organizations. Secondly, we analyzed the optimal deterrence system of organizations for pollution controls, etc. We studied crimes and illegal conducts by organizations and corporations themselves, and their employees under the principal-agency model. Third, we looked at the legal system itself and the foundations of environmental issues from the legal-philosophical aspect. Fourth, we analyzed how the social decision-makings on the environmental protection were produced, using the public choice theory. (author)

  2. New energy vision at Sabae City. Toward realization of 'environmental international city'; 2001 nendo Sabae shi chiiki shin energy vision. Kankyo kokusai toshi Sabae no jitsugen ni mukete

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-03-01

    With an object of accelerating introduction of and uplifting consciousness on new energies at Sabae City in Fukui Prefecture, a new energy vision was put into order based on the result of the initial stage investigation having been performed in the previous fiscal year. Solar light and solar heat energies will be introduced positively into public facilities, and at the same time works will be implemented to accelerate the proliferation thereof into general households. The target of introduction by the year 2010y is set to 2,600 kW by photovoltaic power generation, and the introduction thereof is planned to schools, nursery schools, municipality operated houses, and unattended facilities. With regard to solar heat water warmer, the present proliferation rate of about 7.3% will be raised to 15%. Regarding wastes generated from industrial areas, efficient energy extraction by thermal recycling is intended on the assumption of suppression of wastes generation, their re-use, and recycling. Systems may include the bio-gas system, cogeneration, and recovery of energies from plastics wastes. For acceleration of proliferation of new energies in general, promotion of introduction will be achieved on mini-wind power generation, small hydroelectric power generation, and fuel cell automobiles. (NEDO)

  3. Fiscal 1997 report on the feasibility survey of Japan`s cooperation into energy/environment related fields in Asian countries; 1997 nendo chosa hokokusho (Asia shokoku ni okeru energy kankyo kanren bun`ya eno kyoryoku kanosei chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    A survey was made to study possibilities of Japan`s cooperation in tackling energy/environment problems in Asian countries. In 1995 the GNP growth rate was 2.6% in the world, while it was 7.9% in Asia showing a rapid growth. With the accelerating industrialization and urbanization, energy demand is now over three times as much as that in the 1980s. This means increases in waste and environmental pollution. Especially, the use of firewood in non-electrified areas is a serious problem the same as the slash-and-burn farming and deforestation. Also relating to the production of electric power, it is inevitable to choose hydroelectric power and renewable energy in addition to fossil fuels. Therefore, the necessity is heightening of various technologies for it and environmental protection technologies such as coal cleaning. Local areas, where the population density is extremely low and the electrification cost is high, became victims of elecrification. There the power system should be shifted from the central supply system to the local distributed one. For it, it is necessary to recognize an importance of the distributed type renewable energy which is friendly to the environment. The paper outlined the state of each country and energy by policy and environment. 10 figs., 83 tabs.

  4. Superstructure of NiAs

    International Nuclear Information System (INIS)

    Nozue, Tatsuhiro; Kobayashi, Hisao; Kamimura, Takashi; Yamaguchi, Yasuo

    2001-01-01

    The structural transition in NiAs was studied by neutron diffraction on the single crystalline sample. The crystal structure of NiAs has been reported to be bottom-centered orthorhombic with Cmc2 1 symmetry (niccolite-type). The measurement of temperature dependence of the powder X-ray diffraction revealed that NiAs undergoes a structural transition to the NiAs-type at T t =335 K. In present neutron diffraction experiment at room temperature, we observed the reflections indexed on the basis of the orthorhombic unit cell. The intensities of these reflections are qualitatively explained in terms of the niccolite-type structure with taking account of three domain structures, except for the weak reflections indexed as (001), (003) and (012). Then, the intensities of (001), (002) and (004) reflections were measured in temperature range of 20 to 420 K. The temperature dependences of (002) and (004) reflections qualitatively agree with those of the calculated intensities using the atomic positions of niccolite-type structure. However, the temperature dependence of (001) reflection shows the anomaly around T t , which suggests the symmetry of crystal structure of NiAs is not the Cmc2 1 symmetry. (author)

  5. Thermal stability and electrical characteristics of NiSi films with electroplated Ni(W) alloy

    International Nuclear Information System (INIS)

    Xin Yuhang; Hu Anmin; Li Ming; Mao Dali

    2011-01-01

    In this study, an electroplating method to deposited Ni, crystalline NiW(c-NiW), amorphous NiW (a-NiW) films on P-type Si(1 0 0) were used to form Ni-silicide (NiSi) films. After annealed at various temperatures, sheet resistance of Ni/Cu, c-NiW/Cu and a-NiW/Cu was measured to observe the performance of those diffusion barrier layers. With W added in the barrier layer, the barrier performance was improved. The results of XRD and resistance measurement of the stacked Si/Ni(W)/Cu films reveal that Cu atom could diffuse through Ni barrier layer at 450 deg. C, could diffuse through c-NiW at 550 deg. C, but could hardly diffuse through a-NiW barrier layer. c-NiW layer has a better barrier performance than Ni layer, meanwhile the resistance is lower than a-NiW layer.

  6. Giant magnetoimpedance effect in sputtered single layered NiFe film and meander NiFe/Cu/NiFe film

    International Nuclear Information System (INIS)

    Chen, L.; Zhou, Y.; Lei, C.; Zhou, Z.M.; Ding, W.

    2010-01-01

    Giant magnetoimpedance (GMI) effect on NiFe thin film is very promising due to its application in developing the magnetic field sensors with highly sensitivity and low cost. In this paper, the single layered NiFe thin film and NiFe/Cu/NiFe thin film with a meander structure are prepared by the MEMS technology. The influences of sputtering parameters, film structure and conductor layer width on GMI effect in NiFe single layer and meander NiFe/Cu/NiFe film are investigated. Maximum of the GMI ratio in single layer and sandwich film is 5% and 64%, respectively. The results obtained are useful for developing the high-performance magnetic sensors based on NiFe thin film.

  7. High Ni in Archean tholeiites

    Science.gov (United States)

    Arndt, Nicholas T.

    1991-03-01

    Archean tholeiites generally have higher Ni, Co. Cr and Fe than most younger tholeiites with similar MgO contents. These characteristics cannot be attributed to high T or P batch melting in the Archean mantle, because, although such melts are enriched in siderophile elements, they have higher MgO than normal tholeiites. As primary melts fractionate to lower MgO, they lose Ni, Co and Cr. Nor can the differences between Archean and younger tholeiites be attributed to secular variation in mantle compositions because Archean komatiites have Ni, Co, Cr contents similar to modern (Gorgona) komatiites. It is suggested that the high siderophile element content of Archean tholeiites results from mixing of either komatiitic with basaltic magmas, as might occur in an ascending, melting mantle plume or column, or of komatiite and more evolved rocks, as may take place when komatiite encounters and assimilates crustal rocks.

  8. Relation between shape of Ni-particles and Ni migration in Ni-YSZ electrodes – a hypothesis

    DEFF Research Database (Denmark)

    Mogensen, Mogens Bjerg; Hauch, Anne; Sun, Xiufu

    2016-01-01

    This is an attempt to explain a phenomenon of total depletion of Ni next to the electrolyte in Ni-YSZ cermet electrodes in solid oxide electrolysis cells during electrolysis at high current density/overpotential. Intuitively, we would think that Ni would always migrate down the steam partial...

  9. Ni-NiO core-shell inverse opal electrodes for supercapacitors.

    Science.gov (United States)

    Kim, Jae-Hun; Kang, Soon Hyung; Zhu, Kai; Kim, Jin Young; Neale, Nathan R; Frank, Arthur J

    2011-05-14

    A general template-assisted electrochemical approach was used to synthesize three-dimensional ordered Ni core-NiO shell inverse opals (IOs) as electrodes for supercapacitors. The Ni-NiO IO electrodes displayed pseudo-capacitor behavior, good rate capability and cycling performance. © The Royal Society of Chemistry 2011

  10. CONFIGURATION-INTERACTION IN NI METAL AND NI-ALLOYS AND HIGH-ENERGY SPECTROSCOPY

    NARCIS (Netherlands)

    TANAKA, A; JO, T; SAWATZKY, GA

    We discuss the electronic state of Ni atoms in Ni metal and of Ni impurity in Cu and Au metals from the viewpoint of 3d configuration interaction (CI) using the Anderson impurity model including atomic multiplets. On the basis of the discussion, we give an interpretation for the Ni 2p-core X-ray

  11. Iodine capture by Hofmann-type clathrate Ni(II)(pz)[Ni(II)(CN)_4

    International Nuclear Information System (INIS)

    Massasso, Giovanni; Long, Jerome; Haines, Julien; Devautour-Vinot, Sabine; Maurin, Guillaume; Larionova, Joulia; Guerin, Christian; Guari, Yannick; Grandjean, Agnes; Onida, Barbara; Donnadieu, Bruno

    2014-01-01

    The thermally stable Hofmann-type clathrate framework Ni(II)(pz)[Ni(II)(CN)_4] (pz = pyrazine) was investigated for the efficient and reversible sorption of iodine (I_2) in the gaseous phase and in solution with a maximum adsorption capacity of 1 mol of I_2 per 1 mol of Ni(II)pz)[Ni(II)(CN)_4] in solution. (authors)

  12. Density functional theory study of the interfacial properties of Ni/Ni3Si eutectic alloy

    International Nuclear Information System (INIS)

    Zhao, Yuhong; Wen, Zhiqin; Hou, Hua; Guo, Wei; Han, Peide

    2014-01-01

    In order to clarify the heterogeneous nucleation potential of α-Ni grains on Ni 3 Si particles in Ni-Ni 3 Si eutectic alloy, the work of adhesion (W ad ), fracture toughness (G), interfacial energy (γ i ), and electronic structure of the index (0 0 1), (1 1 0) and (1 1 1) Ni/Ni 3 Si interfaces with two different cohesive manners are investigated using first-principles method based on density functional theory. Results indicate that the center site stacking sequence (OM) is preferable to continue the natural stacking sequence of bulk Ni and Ni 3 Si. Since OM stacking interfaces have larger W ad , G and γ i than that of the top site stacking (OT) interfaces. The Ni/Ni 3 Si (1 1 0) interface with OM stacking has the best mechanical properties. Therefore, the formation of this interface can improve the stability, ductility and fracture toughness of Ni-Ni 3 Si eutectic alloy. The calculated interfacial energy of Ni/Ni 3 Si (0 0 1), (1 1 0) and (1 1 1) interfaces with OM stacking proves the excellent nucleation potency of Ni 3 Si particles for α-Ni phase from thermodynamic considerations. Besides, the electronic structure and chemical bonding of (1 1 0) interface with OM stacking are also discussed.

  13. Density of Liquid Ni-Cr Alloy

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The density of liquid Ni-Cr alloy was measured by a modified sessile drop method. The density of liquid Ni-Cr alloywas found to decrease with increasing temperature and Cr concentration in the alloy. The molar volume of liquidNi-Cr alloy increases with increasing the Cr concentration in the alloy. The molar volume of Ni-Cr alloy determinedin the present work shows a positive deviation from the linear molar volume.

  14. Laser alloyed Al-Ni-Fe coatings

    CSIR Research Space (South Africa)

    Pityana, SL

    2008-10-01

    Full Text Available The aim of this work was to produce crack-free thin surface layers consisting of binary (Al-Ni, Al-Fe) and ternary (Al-Ni-Fe) intermetallic phases by means of a high power laser beam. The laser surface alloying was carried out by melting Fe and Ni...

  15. Nanostructure analysis of friction welded Pd-Ni-P/Pd-Cu-Ni-P metallic glass interface

    International Nuclear Information System (INIS)

    Ohkubo, T.; Shoji, S.; Kawamura, Y.; Hono, K.

    2005-01-01

    Friction welded Pd 40 Ni 40 P 20 /Pd 40 Cu 30 Ni 10 P 20 metallic glass interface has been characterized by energy filtering transmission electron microscopy. The interface is fully amorphous with a gradual compositional change of Cu and Ni in the range of 30 nm. By annealing above T g , the interdiffusion of Cu and Ni progressed in the supercooled liquid region, and the crystallization occurred from the Pd 40 Ni 40 P 20 glass

  16. Study of dipole interaction in micron-width NiFe/Cu/NiFe/NiO wire using exchange anisotropy

    International Nuclear Information System (INIS)

    Kimura, Takashi; Itagaki, Yoshio; Wakaya, Fujio; Gamo, Kenji

    2001-01-01

    The dipole interaction between a NiFe layer pinned by a NiO and a free NiFe layer in a micron-wide NiFe/Cu/NiFe/NiO wire was studied by changing the direction of the exchange bias from the NiO layer. The effect of the dipole interaction when the exchange bias was perpendicular to the wire axis was larger than that when the exchange bias was parallel to the wire axis, and was consistently explained by the stray field caused by the magnetic charges of the pinned layer. It was demonstrated that this method, using exchange anisotropy, is useful for investigating the dipole interaction between ferromagnetic materials separated by a nonmagnetic material in small-scale magnetic multilayers. [copyright] 2001 American Institute of Physics

  17. Effects of Ni particle morphology on cell performance of Na/NiCl2 battery

    Science.gov (United States)

    Kim, Mangi; Ahn, Cheol-Woo; Hahn, Byung-Dong; Jung, Keeyoung; Park, Yoon-Cheol; Cho, Nam-ung; Lee, Heesoo; Choi, Joon-Hwan

    2017-11-01

    Electrochemical reaction of Ni particle, one of active cathode materials in the Na/NiCl2 battery, occurs on the particle surface. The NiCl2 layer formed on the Ni particle surface during charging can disconnect the electron conduction path through Ni particles because the NiCl2 layer has very low conductivity. The morphology and size of Ni particles, therefore, need to be controlled to obtain high charge capacity and excellent cyclic retention. Effects of the Ni particle size on the cell performance were investigated using spherical Ni particles with diameters of 0.5 μm, 6 μm, and 50 μm. The charge capacities of the cells with spherical Ni particles increased when the Ni particle size becomes smaller because of their higher surface area but their charge capacities were significantly decreased with increasing cyclic tests owing to the disconnection of electron conduction path. The inferior cyclic retention of charge capacity was improved using reticular Ni particles which maintained the reliable connection for the electron conduction in the Na/NiCl2 battery. The charge capacity of the cell with the reticular Ni particles was higher than the cell with the small-sized spherical Ni particles approximately by 26% at 30th cycle.

  18. One dimensional motion of interstitial clusters and void growth in Ni and Ni alloys

    Science.gov (United States)

    Yoshiie, T.; Ishizaki, T.; Xu, Q.; Satoh, Y.; Kiritani, M.

    2002-12-01

    One dimensional (1-D) motion of interstitial clusters is important for the microstructural evolution in metals. In this paper, the effect of 2 at.% alloying with elements Si (volume size factor to Ni: -5.81%), Cu (7.18%), Ge (14.76%) and Sn (74.08%) in Ni on 1-D motion of interstitial clusters and void growth was studied. In neutron irradiated pure Ni, Ni-Cu and Ni-Ge, well developed dislocation networks and voids in the matrix, and no defects near grain boundaries were observed at 573 K to a dose of 0.4 dpa by transmission electron microscopy. No voids were formed and only interstitial type dislocation loops were observed near grain boundaries in Ni-Si and Ni-Sn. The reaction kinetics analysis which included the point defect flow into planar sink revealed the existence of 1-D motion of interstitial clusters in Ni, Ni-Cu and Ni-Ge, and lack of such motion in Ni-Si and Ni-Sn. In Ni-Sn and Ni-Si, the alloying elements will trap interstitial clusters and thereby reduce the cluster mobility, which lead to the reduction in void growth.

  19. First-principles calculations for the elastic properties of Ni-base model superalloys: Ni/Ni3Al multilayers

    International Nuclear Information System (INIS)

    Yun-Jiang, Wang; Chong-Yu, Wang

    2009-01-01

    A model system consisting of Ni[001](100)/Ni 3 Al[001](100) multi-layers are studied using the density functional theory in order to explore the elastic properties of single crystal Ni-based superalloys. Simulation results are consistent with the experimental observation that rafted Ni-base superalloys virtually possess a cubic symmetry. The convergence of the elastic properties with respect to the thickness of the multilayers are tested by a series of multilayers from 2γ'+2γ to 10γ'+10γ atomic layers. The elastic properties are found to vary little with the increase of the multilayer's thickness. A Ni/Ni 3 Al multilayer with 10γ'+10γ atomic layers (3.54 nm) can be used to simulate the mechanical properties of Ni-base model superalloys. Our calculated elastic constants, bulk modulus, orientation-dependent shear modulus and Young's modulus, as well as the Zener anisotropy factor are all compatible with the measured results of Ni-base model superalloys R1 and the advanced commercial superalloys TMS-26, CMSX-4 at a low temperature. The mechanical properties as a function of the γ' phase volume fraction are calculated by varying the proportion of the γ and γ' phase in the multilayers. Besides, the mechanical properties of two-phase Ni/Ni 3 Al multilayer can be well predicted by the Voigt–Reuss–Hill rule of mixtures. (classical areas of phenomenology)

  20. Flowsheet for 63Ni production

    International Nuclear Information System (INIS)

    Williams, D.F.; Knauer, J.B.; O'Kelley, G.D.; Wiggins, J.T.; Porter, C.E.

    1992-01-01

    The production of large quantities of high specific activity 63 Ni (>10Ci/g) requires both a highly enriched 62 Ni target and a long irradiation period at high neutron flux. Trace impurities in the nickel and associated target materials are also activated and account for a significant fraction of the discharged activity and essentially all of the gamma activity. While most of these undesirable activation products (mainly transition metals) can be easily removed as chloride complexes during anion exchange, chromium, present as 51 Cr, and manganese, present as 54 Mn, are exceptions and require solvent extraction of the in-cell product to achieve the desired purity. In addition to summarizing the current development and production experience, optimized flowsheets are discussed

  1. Microstructural investigations of Ni and Ni2Al3 coatings exposed in biomass power plants

    DEFF Research Database (Denmark)

    Wu, D. L.; Dahl, K. V.; Christiansen, T. L.

    2018-01-01

    The present work investigates the corrosion resistance of Ni and Ni2Al3 coated austenitic stainless steel (TP347H) tubes, which were exposed in a biomass-fired boiler with an outlet steam temperature of 540 °C for 6757 h. The Ni2Al3 coating was produced by electroplating Ni followed by low...... temperature pack cementation. After exposure, microstructural investigations were performed by light optical and electron microscopy (SEM-EDS). Electroplated Ni coatings were not protective in straw firing power plants and exhibited similar corrosion morphology as uncoated tubes. For Ni2Al3 coatings...

  2. Influence of ni thickness on oscillation coupling in Cu/Ni multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Gagorowska, B; Dus-Sitek, M [Institute of Physics, Czestochowa University of Technology, Al. Armii Krajowej 19, 42-200 Czestochowa (Poland)

    2007-08-15

    The results of investigation of magnetic properties of [Cu/Ni]x100 were presented. Samples were deposited by face-to-face sputtering method onto the silicon substrate, the thickness of Cu layer was constant (d{sub Cu} = 2 nm) and the thickness of Ni layer - variable (1 nm {<=} d{sub Ni} {<=} 6 nm). In Cu/Ni multilayers, for the thickness of Ni layer bigger than 2 nm antiferromagnetic coupling (A-F) were observed, for the thickness of Ni smaller than 2 nm A-F coupling is absent.

  3. Influence of ni thickness on oscillation coupling in Cu/Ni multilayers

    International Nuclear Information System (INIS)

    Gagorowska, B; Dus-Sitek, M

    2007-01-01

    The results of investigation of magnetic properties of [Cu/Ni]x100 were presented. Samples were deposited by face-to-face sputtering method onto the silicon substrate, the thickness of Cu layer was constant (d Cu = 2 nm) and the thickness of Ni layer - variable (1 nm ≤ d Ni ≤ 6 nm). In Cu/Ni multilayers, for the thickness of Ni layer bigger than 2 nm antiferromagnetic coupling (A-F) were observed, for the thickness of Ni smaller than 2 nm A-F coupling is absent

  4. Exclusive study of Ni+Ni and Ni+Au central collisions: phase coexistence and spinodal decomposition; Etude exclusive des collisions centrales Ni+Ni et Ni+Au: coexistence de phase et decomposition spinodale

    Energy Technology Data Exchange (ETDEWEB)

    Guiot, B

    2002-12-01

    The INDRA multidetector allowed us to study the Ni+Ni collisions at 32A MeV and the Ni+Au collisions at 52,4 MeV. Central collisions leading to 'quasi-fused' systems were isolated using multidimensional analysis techniques: the Discriminant Analysis and the Principal Component Analysis. Comparison with a statistical model shows that the selected events are compatible with thermodynamical equilibrium. The average thermal excitation energy is 5A MeV for both systems. Calculations of heat capacities show that the deexcitation of the hot sources are akin to a liquid-gas phase transition of nuclear matter. Indeed heat capacities exhibit a negative branch as expected for a phase transition of a finite system. The dynamics of this phase transition has been investigated by applying the charge correlation method. An enhanced production of events with equal-sized fragments has been evidenced for Ni+Au at 52A MeV. No signal was found for Ni+Ni at 32A MeV. Finally this method was improved by taking into account the total charge conservation. The signal is seen more clearly for Ni+Au at 52A MeV, but is ambiguous for Ni+Ni at 32A MeV. The path followed in the state diagram, or the involved time scales, seem to be different for these systems. (authors)

  5. niños preescolares

    Directory of Open Access Journals (Sweden)

    Claudia Rosario Portilla Ramírez

    2007-01-01

    Full Text Available Este estudio explora la relación entre la escritura y la comprensión de la referencia a través de una tarea de sinonimia en niños entre 5 y 6 años de edad, de origen latinoamericano, escolarizados en Barcelona (España. Las variables relacionadas con la tarea de sinonimia fueron (a la comprensión de la entidad lingüística nombre y (b el nivel de conceptualización de la escritura de los niños y la presencia de etiquetas escritas durante la tarea. Para la tarea de sinonimia se utilizaron pares de sinónimos dialectales del español (de Latinoamérica y de la Península Ibérica. Los resultados mostraron una diferenciación en el razonamiento de los niños, la cual dependía de la comparación entre lenguaje oral y lenguaje escrito en el desarrollo de la tarea, evidenciando una mayor aceptación de la sinonimia en la modalidad de lenguaje oral que en la modalidad de lenguaje escrito.

  6. Reinvestigation of 56Ni decay

    International Nuclear Information System (INIS)

    Sur, B.; Norman, E.B.; Lesko, K.T.; Browne, E.; Larimer, R.

    1990-01-01

    In a series of experiments, we have reinvestigated the decay of the doubly magic nucleus 56 Ni, which is believed to be copiously produced in supernovae. We have confirmed its previously known decay scheme and half-life, and have searched for several rare decay modes. We establish an upper limit of 5.8x10 -7 for the branching ratio of the second forbidden unique β + decay to the 158-keV level in 56 Co, leading to a lower limit of 2.9x10 4 yr for the half-life of fully ionized 56 Ni nuclei in cosmic rays. We also establish an upper limit of 5.0x10 -3 for the branching ratio of the isospin forbidden Fermi electron capture transition to the 1451-keV level in 56 Co, which in turn leads to an upper limit of 124 keV for the isospin mixing Coulomb matrix element of the 56 Ni ground state

  7. On the nature of Ni···Ni interaction in a model dimeric Ni complex.

    Science.gov (United States)

    Kamiński, Radosław; Herbaczyńska, Beata; Srebro, Monika; Pietrzykowski, Antoni; Michalak, Artur; Jerzykiewicz, Lucjan B; Woźniak, Krzysztof

    2011-06-07

    A new dinuclear complex (NiC(5)H(4)SiMe(2)CHCH(2))(2) (2) was prepared by reacting nickelocene derivative [(C(5)H(4)SiMe(2)CH=CH(2))(2)Ni] (1) with methyllithium (MeLi). Good quality crystals were subjected to a high-resolution X-ray measurement. Subsequent multipole refinement yielded accurate description of electron density distribution. Detailed inspection of experimental electron density in Ni···Ni contact revealed that the nickel atoms are bonded and significant deformation of the metal valence shell is related to different populations of the d-orbitals. The existence of the Ni···Ni bond path explains the lack of unpaired electrons in the complex due to a possible exchange channel.

  8. Synthesis of Ni core NiO shell nanostructure and magnetic investigation for shell thickness determination

    International Nuclear Information System (INIS)

    Arabi, H.; Bruck, E.; Tichelaar, F.D.

    2007-01-01

    Full text: Nickel oxide has received a considerable amount of attention in recent years for its catalytic, electronic and magnetic properties. Ni nanoparticles with an average size of 8 nm were prepared by dc - arc discharge in argon atmosphere. A current of 130 A and 300 milli bar pressure of argon have been applied. The produced Ni nanoparticles were annealed for oxidizing in air at 350 for six hours to produce antiferromagnetic NiO particles. The structure of Ni and NiO nanoparticles and size estimation of them studied by means of X-ray diffraction. The size and morphology of the particles were also characterized by high resolution transmission microscopy (TEM). The Ni core NiO shell structure, resulting from the oxidation process, were studied by magnetic properties measurements. A quantum design squid magnetometer, model MPMS5S was used for measuring saturation magnetization of both nanoparticles of Ni with and without NiO layer. By knowing the density of Ni and NiO, we were able to deduce the thickness of the Ni core and NiO outer layer. They are around 3 and 5 nanometers respectively. (authors)

  9. Exclusive study of Ni+Ni and Ni+Au central collisions: phase coexistence and spinodal decomposition

    International Nuclear Information System (INIS)

    Guiot, B.

    2002-12-01

    The INDRA multidetector allowed us to study the Ni+Ni collisions at 32A MeV and the Ni+Au collisions at 52,4 MeV. Central collisions leading to 'quasi-fused' systems were isolated using multidimensional analysis techniques: the Discriminant Analysis and the Principal Component Analysis. Comparison with a statistical model shows that the selected events are compatible with thermodynamical equilibrium. The average thermal excitation energy is 5A MeV for both systems. Calculations of heat capacities show that the deexcitation of the hot sources are akin to a liquid-gas phase transition of nuclear matter. Indeed heat capacities exhibit a negative branch as expected for a phase transition of a finite system. The dynamics of this phase transition has been investigated by applying the charge correlation method. An enhanced production of events with equal-sized fragments has been evidenced for Ni+Au at 52A MeV. No signal was found for Ni+Ni at 32A MeV. Finally this method was improved by taking into account the total charge conservation. The signal is seen more clearly for Ni+Au at 52A MeV, but is ambiguous for Ni+Ni at 32A MeV. The path followed in the state diagram, or the involved time scales, seem to be different for these systems. (authors)

  10. Atomistic calculations of hydrogen interactions with Ni3Al grain boundaries and Ni/Ni3Al interfaces

    International Nuclear Information System (INIS)

    Baskes, M.I.; Angelo, J.E.; Moody, N.R.

    1995-01-01

    Embedded Atom Method (EAM) potentials have been developed for the Ni/Al/H system. The potentials have been fit to numerous properties of this system. For example, these potentials represent the structural and elastic properties of bulk Ni, Al, Ni 3 Al, and NiAl quite well. In addition the potentials describe the solution and migration behavior of hydrogen in both nickel and aluminum. A number of calculations using these potentials have been performed. It is found that hydrogen strongly prefers sites in Ni 3 Al that are surrounded by 6 Ni atoms. Calculations of the trapping of hydrogen to a number of grain boundaries in Ni 3 Al have been performed as a function of hydrogen chemical potential at room temperature. The failure of these bicrystals under tensile stress has been examined and will be compared to the failure of pure Ni 3 Al boundaries. Boundaries containing a preponderance of nickel are severely weakened by hydrogen. In order to investigate the potential embrittlement of γ/γ' alloys, trapping of hydrogen to a spherical Ni 3 Al precipate in nickel as a function of chemical potential at room temperature has been calculated. It appears that the boundary is not a strong trap for hydrogen, hence embrittlement in these alloys is not primarily due to interactions of hydrogen with the γ/γ interface

  11. Structural features in Ni-Al alloys

    International Nuclear Information System (INIS)

    Abylkalykova, R.B.; Kveglis, L.I.; Rakhimova, U.A.; Nasokhova, Sh.B.; Tazhibaeva, G.B.

    2007-01-01

    Purpose of the work is study of structural transformations under diverse memory effect in Ni-Al alloys. Examination were conducted in following composition samples: Ni -75 at.% and Al - 25 at.%. The work is devoted to clarification reasons both formation atom-ordered structures in inter-grain boundaries of bulk samples under temperature action and static load. Revealed inter-grain inter-boundary layers in Ni-Al alloy both bulk and surface state have complicated structure

  12. Compositional and structural characterisation of Ni-phyllosilicates in hydrous silicate type Ni-laterite deposits

    OpenAIRE

    Villanova de Benavent, Cristina

    2015-01-01

    Ni-bearing Mg-phyllosilicates (commonly known as garnierites) are significant ore minerals in many Ni-laterite deposits worldwide. However, the characterisation of these mineral phases is complex, as well as their classification and nomenclature, due to their fine-grained nature, low crystallinity and frequent occurrence as mixtures. The aim of this study is to shed some light to the nature of the Ni-bearing Mg-phyllosilicates occurring at the Falcondo Ni-laterite. In this deposit, these ...

  13. Thermal capture cross section for 58Ni (n,γ)59 Ni reaction

    International Nuclear Information System (INIS)

    Carbonari, A.W.; Pecequilo, B.R.S.

    1989-01-01

    The 58 Ni total thermal capture cross section was determined by suming the partial cross sections calculated for the primary transitions of the reaction 58 Ni (n,γ) 59 Ni. The primary transitions energies and intensities were determined from the 58 Ni thermal neutrons prompt gamma capture gamma rays spectrum in the 3.7 to 9.3 MeV region. The obtained value for the total cross section was 4.52 + 0.10b. (author) [pt

  14. Formation enthalpy of NiBe and Ni5Be21

    International Nuclear Information System (INIS)

    Ivanov, M.I.; Karpova, T.F.; Dalago, N.Yu.

    1981-01-01

    The method of dissolution calorimetry is used to determine standard enthalpies of NiBe and Ni 5 Be 21 formation, which are 84.8+-2.2 and (-669+-37)kJ/mol. The enthalpy values of NiBe and Ni 5 Be 21 at 331 K are shown to coincide (within the limits of errors of these values) with the values at the standard temperature of 298.15 K [ru

  15. Effects of Ni vacancy, Ni antisite, Cr and Pt on the third-order elastic constants and mechanical properties of NiAl

    KAUST Repository

    Wu, Shaohua; Wu, Xiaozhi; Wang, Rui; Liu, Qing; Gan, Liyong

    2014-01-01

    Effects of Ni vacancy, Ni antisite in Al sublattice, Cr in Al sublattice, Pt in Ni sublattice on the second-order elastic constants (SOECs) and third-order elastic constants (TOECs) of the B2 NiAl have been investigated using the first-principles methods. Lattice constant and the SOECs of NiAl are in good agreement with the previous results. The brittle/ductile transition map based on Pugh ratio G/B and Cauchy pressure Pc shows that Ni antisite, Cr, Pt and pressure can improve the ductility of NiAl, respectively. Ni vacancy and lower pressure can enhance the Vickers hardness Hv of NiAl. The density of states (DOS) and the charge density difference are also used to analysis the effects of vacancy, Ni antisite, Cr and Pt on the mechanical properties of NiAl, and the results are in consistent with the transition map. © 2014 Elsevier Ltd. All rights reserved.

  16. Effects of Ni vacancy, Ni antisite, Cr and Pt on the third-order elastic constants and mechanical properties of NiAl

    KAUST Repository

    Wu, Shaohua

    2014-12-01

    Effects of Ni vacancy, Ni antisite in Al sublattice, Cr in Al sublattice, Pt in Ni sublattice on the second-order elastic constants (SOECs) and third-order elastic constants (TOECs) of the B2 NiAl have been investigated using the first-principles methods. Lattice constant and the SOECs of NiAl are in good agreement with the previous results. The brittle/ductile transition map based on Pugh ratio G/B and Cauchy pressure Pc shows that Ni antisite, Cr, Pt and pressure can improve the ductility of NiAl, respectively. Ni vacancy and lower pressure can enhance the Vickers hardness Hv of NiAl. The density of states (DOS) and the charge density difference are also used to analysis the effects of vacancy, Ni antisite, Cr and Pt on the mechanical properties of NiAl, and the results are in consistent with the transition map. © 2014 Elsevier Ltd. All rights reserved.

  17. Creep and shrinkage of Mo(Ni)

    International Nuclear Information System (INIS)

    Kaysser, W.A.; Hofmann-Amtenbrink, M.; Petzow, G.

    1984-01-01

    To avoid some of the errors inherent in a quantitative interpretation of shrinkage of powder compacts as Mo-Ni, other experiments were looked for, where the influence of Ni on the material transport properties of Mo could be measured semi-quantitatively during heating up to temperature and subsequent isothermal annealing. The bending of thin Mo foils under small loads was found to be an experimental arrangement, where variations in stress, in Ni-concentration and in intrinsic material properties could be realized. The results of these creep experiments will be compared in a qualitative sense with sintering experiments in Mo-Ni done under similar conditions as the creep experiments

  18. Structure-activity relations for Ni-containing zeolites during NO reduction. II. Role of the chemical state of Ni

    NARCIS (Netherlands)

    Mosqueda Jimenez, B.I.; Jentys, A.; Seshan, Kulathuiyer; Lercher, J.A.

    2003-01-01

    The influence of the metal in Ni-containing zeolites used as catalysts for the reduction of NO with propane and propene was studied. In the fresh catalysts, Ni is located in ion exchange positions for Ni/MOR, Ni/ZSM-5, and Ni/MCM-22. The formation of carbonaceous deposits, the removal of Al from

  19. Ni-P/Zn-Ni compositionally modulated multilayer coatings - Part 2: Corrosion and protection mechanisms

    Science.gov (United States)

    Bahadormanesh, Behrouz; Ghorbani, Mohammad

    2018-06-01

    The Ni-P/Zn-Ni compositionally modulated multilayer coatings CMMCs were electrodeposited from a single bath by switching the deposition current density. The corrosion resistance of the deposits was studied and compared with that of monolayers of Ni-P and Zn-Ni alloys via Tafel polarization, EIS and salt spray tests. Characterization of corrosion products by means of EDS and XRD revealed more details from the corrosion mechanism of the monolayers and multilayers. The corrosion current density of Ni-P/Zn-Ni CMMCs were around one tenth of Zn-Ni monolayer. The CMMC with incomplete layers performed lower polarization resistance and higher corrosion current density compared to the CMMC with complete layers. The electrical circuit that was proposed for modeling the corrosion process based on the EIS spectrum, proved that layering reduces the porosity and consequently improves the barrier properties. Although, layering of Zn-Ni layers with Ni-P deposits increased the time to red rust in salt spray test, the time for white rust formation decreased. The corrosion mechanism of both Zn-Ni and Ni-P (containing small amount of Zn) was preferential dissolution of Zn and the corrosion products were comprised of mainly Zn hydroxychloride and Zn hydroxycarbonate. Also, Ni and P did not take part in the corrosion products. Based on the electrochemical character of the layers and the morphology of the corroded surface, the corrosion mechanism of multilayers was discussed.

  20. Joining of Ni-TiC FGM and Ni-Al Intermetallics by Centrifugal Combustion Synthesis

    International Nuclear Information System (INIS)

    Ohmi, Tatsuya; Matsuura, Kiyotaka; Iguchi, Manabu; Mizuma, Kiminori

    2008-01-01

    A centrifugal combustion synthesis (CCS) process has been investigated to join a Ni-Al intermetallic compound and a Ni-TiC cermet. The cermet, a tubular graphite mold, and a green compact of reactants consisting of Al, Ni and NiO were set in a centrifugal caster. When the combustion synthesis reaction was induced in the centrifugal force field, a synthesized molten Ni-Al alloy flowed into the graphite mold and joined to the cermet. The soundness of the joint interface depended on the volume percentage of TiC phase in the cermet. A lot of defects were formed near the interface between the Ni-TiC cermet and the cast Ni-Al alloy when the volume percentage of TiC was 50% or higher. For this kind of cermet system, using a functionally graded cermet such as Ni-10 vol.%TiC/Ni-25 vol.%TiC/Ni-50 vol.%TiC overcame this difficulty. The four-point bending strength of the joined specimen consisting of the three-layered FGM cermet and cast Ni-29 mol%Al alloy was 1010 MPa which is close to the result for a Ni-29 mol%Al alloy specimen

  1. Dynamic recovery in nanocrystalline Ni

    International Nuclear Information System (INIS)

    Sun, Z.; Van Petegem, S.; Cervellino, A.; Durst, K.; Blum, W.; Van Swygenhoven, H.

    2015-01-01

    The constant flow stress reached during uniaxial deformation of electrodeposited nanocrystalline Ni reflects a quasi-stationary balance between dislocation slip and grain boundary (GB) accommodation mechanisms. Stress reduction tests allow to suppress dislocation slip and bring recovery mechanisms into the foreground. When combined with in situ X-ray diffraction it can be shown that grain boundary recovery mechanisms play an important role in producing plastic strain while hardening the microstructure. This result has a significant consequence for the parameters of thermally activated glide of dislocations, such as athermal stress and activation volume, which are traditionally derived from stress/strain rate change tests

  2. Morphological control of Ni/NiO core/shell nanoparticles and production of hollow NiO nanostructures

    International Nuclear Information System (INIS)

    Chopra, Nitin; Claypoole, Leslie; Bachas, Leonidas G.

    2010-01-01

    Chemical synthesis coupled with a microwave irradiation process allowed for the control of size (6-40 nm), shape, and shell thickness of Ni/NiO core/shell nanoparticles. In this unique synthetic route, the size of Ni nanoparticles (NiNPs) was strongly influenced by the nickel salt-to-stabilizer ratio and the amount of the stabilizer. Interestingly, it was observed that the shape of the nanoparticles was altered by varying the reaction time, where longer reaction times resulted in annealing effects and rupture of the stabilizer micelle leading to distinct shapes of Ni/NiO core/shell nanostructures. Product cooling rate was another important parameter identified in this study that not only affected the shape, but also the crystal structure of the core/shell nanoparticles. In addition, a simple and cost-effective method of microwave irradiation of NiNPs led to the formation of distinctly shaped hollow NiO nanoparticles. These high surface area core/shell nanoparticles with well-controlled morphologies are important and can lead to significant advancement in the design of improved fuel cells, electrochromic display devices, and catalysis systems.

  3. Morphological control of Ni/NiO core/shell nanoparticles and production of hollow NiO nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Chopra, Nitin [University of Alabama, Department of Metallurgical and Materials Engineering, Center for Materials for Information Technology (MINT) (United States); Claypoole, Leslie [Fairmont State University (United States); Bachas, Leonidas G., E-mail: bachas@uky.ed [University of Kentucky, Department of Chemistry (United States)

    2010-10-15

    Chemical synthesis coupled with a microwave irradiation process allowed for the control of size (6-40 nm), shape, and shell thickness of Ni/NiO core/shell nanoparticles. In this unique synthetic route, the size of Ni nanoparticles (NiNPs) was strongly influenced by the nickel salt-to-stabilizer ratio and the amount of the stabilizer. Interestingly, it was observed that the shape of the nanoparticles was altered by varying the reaction time, where longer reaction times resulted in annealing effects and rupture of the stabilizer micelle leading to distinct shapes of Ni/NiO core/shell nanostructures. Product cooling rate was another important parameter identified in this study that not only affected the shape, but also the crystal structure of the core/shell nanoparticles. In addition, a simple and cost-effective method of microwave irradiation of NiNPs led to the formation of distinctly shaped hollow NiO nanoparticles. These high surface area core/shell nanoparticles with well-controlled morphologies are important and can lead to significant advancement in the design of improved fuel cells, electrochromic display devices, and catalysis systems.

  4. Continuum mechanics simulations of NiO/Ni-YSZ composites during reduction and re-oxidation

    DEFF Research Database (Denmark)

    Pihlatie, Mikko; Frandsen, Henrik Lund; Kaiser, Andreas

    2010-01-01

    for the dimensional change arises from the volumetric change related to the phase change NiO ↔ Ni. The measurable change in bulk length is given by the ceramic YSZ backbone as a response to the stress created by the chemical strain. The different subprocesses described in the model for YSZ were elastic and anelastic...... expansion, diffusional creep, grain boundary sliding (GBS) and microcracking due to excessive stress. In the Ni/NiO phase, nonelastic strains in terms of diffusional and power law creep were implemented, and additionally for NiO deformation due to microcracking and/or pseudoplasticity. Semi...

  5. Niños y niñas como cuidadores familiares

    OpenAIRE

    María Rosa Estupiñán Aponte

    2015-01-01

    En el contexto familiar, el cuidado de otra persona por parte de niños y niñas constituye un terreno inexplorado tanto en su significado como en las implicaciones que podrían darse en el proceso. Aunque históricamente se ha asignado el cuidado familiar a las mujeres generando condiciones de inequidad, incrementada con los cambios sociales de los últimos tiempos, es necesario reconocer que en muchos hogares niños y niñas se han visto obligados a desempeñar esta labor sin la preparación ni las ...

  6. .';.:NI~

    African Journals Online (AJOL)

    al wat ons werd was. Na middagete op 29 Junie, is ek per kar suid om die grand te gaan besigtig en om te sien hoe my stellings, van die vyandelike oogpunt, daaruit .... van Gatt se optrede moes die. Nieu-Seelanders, in 'n briljante nagaanval, met gevelde bajonette, 'n weg baan deur die vyand am daardie nag te ontvlug.

  7. Water dissociation on Ni(100) and Ni(111): Effect of surface temperature on reactivity

    International Nuclear Information System (INIS)

    Seenivasan, H.; Tiwari, Ashwani K.

    2013-01-01

    Water adsorption and dissociation on Ni(100) and Ni(111) surfaces are studied using density functional theory calculations. Water adsorbs on top site on both the surfaces, while H and OH adsorb on four fold hollow and three fold hollow (fcc) sites on Ni(100) and Ni(111), respectively. Transition states (TS) on both surfaces are identified using climbing image-nudged elastic band method. It is found that the barrier to dissociation on Ni(100) surface is slightly lower than that on Ni(111) surface. Dissociation on both the surfaces is exothermic, while the exothermicity on Ni(100) is large. To study the effect of lattice motion on the energy barrier, TS calculations are performed for various values of Q (lattice atom coordinate along the surface normal) and the change in the barrier height and position is determined. Calculations show that the energy barrier to reaction decreases with increasing Q and increases with decreasing Q on both the surfaces. Dissociation probability values at different surface temperatures are computed using semi-classical approximation. Results show that the influence of surface temperature on dissociation probability on the Ni(100) is significantly larger compared to that of Ni(111). Moreover, on Ni(100), a dramatic shift in energy barrier to lower incident energy values is observed with increasing surface temperature, while the shift is smaller in the case of Ni(111)

  8. Creatividad en niños superdotados

    OpenAIRE

    González Román, María del Pilar

    1992-01-01

    Se ha realizado un estudio sobre la creatividad en los niños superdotados. Analizándose los diferentes modelos de creatividad y superdotacion avalados por un estudio empírico, en el cual se han valorado las diferencial que existen entre los niños superdotados y contraste a nivel verbal y grafico-espacial.

  9. Preparation of one-step NiO/Ni-CGO composites using factorial design

    International Nuclear Information System (INIS)

    Araujo, A.J.M. de; Sousa, A R.O. de; Camposa, L.F.A.; Macedo, D.A.; Loureiro, F. J.A.; Fagg, D.P.

    2016-01-01

    This work deals with the synthesis, processing and characterization of NiO/Ni- CGO composite materials as potential solid oxide fuel cell (SOFC) anodes. The particulate materials were obtained by a one-step synthesis method and characterized by thermal analysis (prior to calcination) and X-ray diffraction (calcined powder). The ceramic processing of samples containing from 30 to 70 wt.% NiO was carried out by factorial design. Besides the NiO content controlled during the chemical synthesis, the impacts of the pore-former content (citric acid, used in proportions of 0, 7.5 and 15 wt.%) and the sintering temperature (1300, 1350 and 1400 °C) were also investigated. The open porosity of NiO-CGO composites and reduced Ni-CGO cermets was modeled as a function of factors (NiO content, citric acid content and sintering temperature) and interaction of factors. (author)

  10. Nanoscale structural heterogeneity in Ni-rich half-Heusler TiNiSn

    International Nuclear Information System (INIS)

    Douglas, Jason E.; Pollock, Tresa M.; Chater, Philip A.; Brown, Craig M.; Seshadri, Ram

    2014-01-01

    The structural implications of excess Ni in the TiNiSn half-Heusler compound are examined through a combination of synchrotron x-ray and neutron scattering studies, in conjunction with first principles density functional theory calculations on supercells. Despite the phase diagram suggesting that TiNiSn is a line compound with no solid solution, for small x in TiNi 1+x Sn there is indeed an appearance—from careful analysis of the scattering—of some solubility, with the excess Ni occupying the interstitial tetrahedral site in the half-Heusler structure. The analysis performed here would point to the excess Ni not being statistically distributed, but rather occurring as coherent nanoclusters. First principles calculations of energetics, carried out using supercells, support a scenario of Ni interstitials clustering, rather than a statistical distribution.

  11. Microstructural evolution of Ni40Zr60 alloy during early stage of mechanical alloying of intermetallic compounds NiZr2 and Ni11Zr9

    International Nuclear Information System (INIS)

    Lee Peeyew; Koch, C.C.

    1994-01-01

    The microstructural change of Ni 40 Zr 60 alloy during mechanical alloying of mixtures of the intermetallic compounds NiZr 2 and Ni 11 Zr 9 has been studied by transmission electron microscopy. A specific ''cauliflower'' phase was formed during early stage of mechanical alloying process. It is suggested that the solid state reaction between intermetallic compounds NiZr 2 and Ni 11 Zr 9 is not the only origin for the formation of the ''cauliflower'' phase. ((orig.))

  12. Microstructure and tribological properties of NiMo/Mo2Ni3Si intermetallic 'in-situ' composites

    International Nuclear Information System (INIS)

    Gui Yongliang; Song Chunyan; Yang Li; Qin Xiaoling

    2011-01-01

    Research highlights: → Wear resistant NiMo/Mo 2 Ni 3 Si intermetallic 'in-situ' composites was fabricated successfully with Mo-Ni-Si powder blends as the starting materials. Microstructure of the NiMo/Mo 2 Ni 3 Si composites consists of Mo 2 Ni 3 Si primary dendrites, binary intermetallic phase NiMo and small amount of Ni/NiMo eutectics structure. The NiMo/Mo 2 Ni 3 Si composites exhibited high hardness and outstanding tribological properties under room-temperature dry-sliding wear test conditions which were attributed to the covalent-dominant strong atomic bonds and excellent combination of strength and ductility and toughness. - Abstract: Wear resistant NiMo/Mo 2 Ni 3 Si intermetallic 'in-situ' composites with a microstructure of ternary metal silicide Mo 2 Ni 3 Si primary dendritic, the long strip-like NiMo intermetallic phase, and a small amount of Ni/NiMo eutectics structure were designed and fabricated using molybdenum, nickel and silicon elemental powders. Friction and wear properties of NiMo/Mo 2 Ni 3 Si composites were evaluated under different contact load at room-temperature dry-sliding wear test conditions. Microstructure, worn surface morphologies and subsurface microstructure were characterized by OM, XRD, SEM and EDS. Results indicate that NiMo/Mo 2 Ni 3 Si composites have low fiction coefficient, excellent wear resistance and sluggish wear-load dependence. The dominant wear mechanisms of NiMo/Mo 2 Ni 3 Si composites are soft abrasion and slightly superficial oxidative wear.

  13. Nonenzymatic Glucose Sensor Based on In Situ Reduction of Ni/NiO-Graphene Nanocomposite

    Directory of Open Access Journals (Sweden)

    Xiaohui Zhang

    2016-10-01

    Full Text Available Ni/NiO nanoflower modified reduced graphene oxide (rGO nanocomposite (Ni/NiO-rGO was introduced to screen printed electrode (SPE for the construction of a nonenzymatic electrochemical glucose biosensor. The Ni/NiO-rGO nanocomposite was synthesized by an in situ reduction process. Graphene oxide (GO hybrid Nafion sheets first chemical adsorbed Ni ions and assembled on the SPE. Subsequently, GO and Ni ions were reduced by hydrazine hydrate. The electrochemical properties of such a Ni/NiO-rGO modified SPE were carefully investigated. It showed a high activity for electrocatalytic oxidation of glucose in alkaline medium. The proposed nonenzymatic sensor can be utilized for quantification of glucose with a wide linear range from 29.9 μM to 6.44 mM (R = 0.9937 with a low detection limit of 1.8 μM (S/N = 3 and a high sensitivity of 1997 μA/mM∙cm−2. It also exhibited good reproducibility as well as high selectivity.

  14. Enthalpy of mixing of liquid Ni-Zr and Cu-Ni-Zr alloys

    International Nuclear Information System (INIS)

    Witusiewicz, V.T.; Sommer, F.

    2000-01-01

    Since the Al-Cu-Ni-Zr system is a basis for the production of bulk amorphous materials by rapid solidification techniques from the liquid state, it is of great scientific interest to determine the partial and the integral thermodynamic functions of liquid and undercooled liquid alloys. Such data, as was pointed out previously, are important in order to understand their extremely good glass-forming ability in multicomponent metallic systems as well as for processing improvements. In order to measure the thermodynamic properties of the Al-Cu-Ni-Zr quaternary, it is necessary to have reliable thermochemical data for its constituent canaries and ternaries first. In a series of articles, the authors have reported in detail the thermodynamic properties of liquid Al-Cu, Al-Ni, Cu-Ni, Cu-Zr, Al-Zr, Al-Cu-Ni, and Al-Cu-Zr alloys. This article deals with the direct calorimetric measurements of the partial and the integral enthalpies of mixing of liquid Ni-Zr and Cu-Ni-Zr alloys and the heat capacity of liquid Ni 26 Zr 74 . In a subsequent article, the authors will present similar data for the liquid ternary Al-Ni-Zr and for the liquid quaternary Al-Cu-Ni-Zr alloys

  15. The Ni-YSZ interface

    DEFF Research Database (Denmark)

    Jensen, Karin Vels

    The anode/electrolyte interface in solid oxide fuel cells (SOFC) is known to cause electrical losses. Geometrically simple Ni/yttria-stabilised zirconia (YSZ) interfaces were examined to gain information on the structural and chemical changes occurring during experiments at 1000°C in an atmosphere...... of 97% H2/3% H2O. Electrochemical impedance spectroscopy at open circuit voltage (OCV) and at anodic and cathodic polarisations (100 mV) was performed. A correlation of the electrical data with the structure development and the chemical composition was attempted. Nickel wires with different impurity...... between polarised and non-polarised samples. With pure nickel wires, however, the microstructures depended on the polarisation/non-polarisation conditions. At non-polarised conditions a hill and valley type structure was found. Anodic polarisation produced an up to 1 μm thick interface layer consisting...

  16. Study of the central collisions in the reactions Ni + Al and Ni + Ni at 28 A.MeV; Etude des collisions centrales dans les reactions Ni + Al et Ni + Ni a 28 A.MeV

    Energy Technology Data Exchange (ETDEWEB)

    Lebreton, L.

    1995-12-01

    The work is in characterisation of mechanisms in the energy range of onset of multifragmentation (excitation energy of composed nucleus around 4 - 5 AMeV). This work focused on an experiment performed at the SARA facility, in Grenoble, using the AMPHORA multi detection array. I have been particularly interested in central collisions in the Ni + Al and Ni + Ni systems. The possibility to detect complete events for Ni + Al, and quasi-complete events for the Ni + Ni case, is the reason of this choice. Furthermore Ni + Ni presents the interest of a symmetrical system, for which the excitation energy per nucleon is maximum. The study of these reactions has been focused on the quasi-complete events (events for which at least 80 % of the total charge has been detected). Heavy ions produced in peripheral collisions are very likely emitted along the beam line or stopped in the plastic detectors, energy thresholds are too high for the quasi-target products detection, consequently by requiring complete or quasi-complete measurement of the total charge, we are able to detect mostly central events. The knowledge of informations like charge, energy or detection angles allows to isolate the source(s) and to reconstruct the size and the excitation energy of the source(s). Comparisons with simulations like sequential emission (GEMINI code), very deep inelastic collision or instantaneous emission (Berliner code) allows to characterise the first stage of the collision (binary collisions or central collisions) and the type of deexcitation of the source(s). Some calculations was also performed with the statistical model code MODGAN. Indeed azimuthal correlations seem to be a good tool in getting more information about involved reaction mechanisms. Comparisons with MODGAN provide information about angular momentum of the source and time delay between emissions of the two particles (separation between sequential or instantaneous process). (author). 69 refs.

  17. Electrochemical preparation and characteristics of Ni-Co-LaNi{sub 5} composite coatings as electrode materials for hydrogen evolution

    Energy Technology Data Exchange (ETDEWEB)

    Wu Gang; Li Ning; Dai Changsong; Zhou Derui

    2004-02-15

    Electrocatalytic activity for the hydrogen evolution reaction on Ni-Co-LaNi{sub 5} composite electrodes prepared by electrochemical codeposition technique was evaluated. The relationship between the current density for hydrogen evolution reaction and the amount of LaNi{sub 5} particles in Ni-Co baths is like the well-known 'volcano plot'. The Surface morphology and microstructure of Ni-Co-LaNi{sub 5} coatings were determined by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). The kinetic parameters were determined from electrochemical steady-state Tafel polarization and electrochemical impedance spectroscopy technology in 1 M NaOH solution. The values obtained for the apparent energies of activation are 32.48, 46.29 and 57.03 kJ mol{sup -1} for the Ni-Co-LaNi{sub 5}, Ni-Co and Ni electrodes, respectively. The hydrogen evolution reaction on Ni-Co-LaNi{sub 5} proceeds via Volmer-Tafel reaction route with the mixed rate determining characteristics. The composite coating Ni-Co-LaNi{sub 5} is catalytically more active than Ni and Ni-Co electrodes due to the increase in its real surface areas and the decrease in the apparent free energy of activation caused by the electrocatalytic synergistic effect of the Ni-Co alloys and the hydrogen storage intermetallic particles on the electrode surface.

  18. Electrochemical preparation and characteristics of Ni-Co-LaNi5 composite coatings as electrode materials for hydrogen evolution

    International Nuclear Information System (INIS)

    Wu Gang; Li Ning; Dai Changsong; Zhou Derui

    2004-01-01

    Electrocatalytic activity for the hydrogen evolution reaction on Ni-Co-LaNi 5 composite electrodes prepared by electrochemical codeposition technique was evaluated. The relationship between the current density for hydrogen evolution reaction and the amount of LaNi 5 particles in Ni-Co baths is like the well-known 'volcano plot'. The Surface morphology and microstructure of Ni-Co-LaNi 5 coatings were determined by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). The kinetic parameters were determined from electrochemical steady-state Tafel polarization and electrochemical impedance spectroscopy technology in 1 M NaOH solution. The values obtained for the apparent energies of activation are 32.48, 46.29 and 57.03 kJ mol -1 for the Ni-Co-LaNi 5 , Ni-Co and Ni electrodes, respectively. The hydrogen evolution reaction on Ni-Co-LaNi 5 proceeds via Volmer-Tafel reaction route with the mixed rate determining characteristics. The composite coating Ni-Co-LaNi 5 is catalytically more active than Ni and Ni-Co electrodes due to the increase in its real surface areas and the decrease in the apparent free energy of activation caused by the electrocatalytic synergistic effect of the Ni-Co alloys and the hydrogen storage intermetallic particles on the electrode surface

  19. Synthesis of Supported NiPt Bimetallic Nanoparticles, Methods for Controlling the Surface Coverage of Ni Nanoparticles With Pt, Methods Of Making NiPt Multilayer Core-Shell Structures and Application of the Supported Catalysts for CO2 Reforming

    KAUST Repository

    Li, Lidong; Anjum, Dalaver H.; Zhou, Lu; Laveille, Paco; Basset, Jean-Marie

    2015-01-01

    Embodiments of the present disclosure provide for supported Ni/Pt bimetallic nanoparticles, compositions including supported NiPt nanoparticles, methods of making supported NiPt nanoparticles, methods of using supported NiPt nanoparticles

  20. Synthesis of Supported NiPt Bimetallic Nanoparticles, Methods for Controlling the Surface Coverage of Ni Nanoparticles With Pt, Methods Of Making NiPt Multilayer Core-Shell Structures and Application of the Supported Catalysts for CO2 Reforming

    KAUST Repository

    Li, Lidong

    2015-06-25

    Embodiments of the present disclosure provide for supported Ni/Pt bimetallic nanoparticles, compositions including supported NiPt nanoparticles, methods of making supported NiPt nanoparticles, methods of using supported NiPt nanoparticles, and the like.

  1. Growth of single-crystal W whiskers during humid H2/N2 reduction of Ni, Fe-Ni, and Co-Ni doped tungsten oxide

    International Nuclear Information System (INIS)

    Wang Shiliang; He Yuehui; Zou Jou; Wang Yong; Huang Han

    2009-01-01

    Numbers of W whiskers were obtained by reducing Ni, Ni-Fe, and Ni-Co doped tungsten oxide in a mixed atmosphere of humid H 2 and N 2 . The phases and morphologies of the reduction products were characterized by XRD and SEM. Intensive TEM and EDS analyses showed that the obtained whiskers were W single crystals which typical have alloyed particles (Ni-W, Fe-Ni, or Co-Ni-W) at the growth tips. The formed W whiskers were presumed to be induced by the alloyed particles. Our experimental results revealed that, during the reduction process of tungsten oxide, the pre-reduced Ni, Fe-Ni, or Co-Ni particles not only served as nucleation aids for the initial growth of W phase from W oxide but also played the roles of catalysts during the reductive decomposition of gaseous WO 2 (OH) 2 .

  2. Exchange bias variations of the seed and top NiFe layers in NiFe/FeMn/NiFe trilayer as a function of seed layer thickness

    International Nuclear Information System (INIS)

    Sankaranarayanan, V.K.; Yoon, S.M.; Kim, C.G.; Kim, C.O.

    2005-01-01

    Development of exchange bias at the seed and top NiFe layers in the NiFe (t nm)/FeMn(10 nm)/NiFe(5 nm) trilayer structure is investigated as a function of seed layer thickness, in the range of 2-20 nm. The seed NiFe layer shows maximum exchange bias at 4 nm seed layer thickness. The bias shows inverse thickness dependence with increasing thickness. The top NiFe layer on the other hand shows only half the bias of the seed layer which is retained even after the sharp fall in seed layer bias. The much smaller bias for the top NiFe layer is related to the difference in crystalline texture and spin orientations at the top FeMn/NiFe interface, in comparison to the bottom NiFe/FeMn interface which grows on a saturated NiFe layer with (1 1 1) orientation

  3. An Ultrastable and High-Performance Flexible Fiber-Shaped Ni-Zn Battery based on a Ni-NiO Heterostructured Nanosheet Cathode.

    Science.gov (United States)

    Zeng, Yinxiang; Meng, Yue; Lai, Zhengzhe; Zhang, Xiyue; Yu, Minghao; Fang, Pingping; Wu, Mingmei; Tong, Yexiang; Lu, Xihong

    2017-11-01

    Currently, the main bottleneck for the widespread application of Ni-Zn batteries is their poor cycling stability as a result of the irreversibility of the Ni-based cathode and dendrite formation of the Zn anode during the charging-discharging processes. Herein, a highly rechargeable, flexible, fiber-shaped Ni-Zn battery with impressive electrochemical performance is rationally demonstrated by employing Ni-NiO heterostructured nanosheets as the cathode. Benefiting from the improved conductivity and enhanced electroactivity of the Ni-NiO heterojunction nanosheet cathode, the as-fabricated fiber-shaped Ni-NiO//Zn battery displays high capacity and admirable rate capability. More importantly, this Ni-NiO//Zn battery shows unprecedented cyclic durability both in aqueous (96.6% capacity retention after 10 000 cycles) and polymer (almost no capacity attenuation after 10 000 cycles at 22.2 A g -1 ) electrolytes. Moreover, a peak energy density of 6.6 µWh cm -2 , together with a remarkable power density of 20.2 mW cm -2 , is achieved by the flexible quasi-solid-state fiber-shaped Ni-NiO//Zn battery, outperforming most reported fiber-shaped energy-storage devices. Such a novel concept of a fiber-shaped Ni-Zn battery with impressive stability will greatly enrich the flexible energy-storage technologies for future portable/wearable electronic applications. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Synthesis of a novel Au nanoparticles decorated Ni-MOF/Ni/NiO nanocomposite and electrocatalytic performance for the detection of glucose in human serum.

    Science.gov (United States)

    Chen, Jingyuan; Xu, Qin; Shu, Yun; Hu, Xiaoya

    2018-07-01

    A nonenzymatic glucose electrochemical sensor was constructed based on Au nanoparticles (AuNPs) decorated Ni metal-organic-framework (MOF)/Ni/NiO nanocomposite. Ni-MOF/Ni/NiO nanocomposite was synthesized by one-step calcination of Ni-MOF. Then AuNPs were loaded onto the Ni-based nanocomposites' surface through electrostatic adsorption. Through characterization by transmission electron microscopy (TEM), high resolution TEM (HRTEM) and energy disperse spectroscopy (EDS) mapping, it is found that the AuNPs were well distributed on the surface of Ni-based nanocomposite. Cyclic voltammetric (CV) study showed the electrocatalytic activity of Au-Ni nanocomposite was highly improved after loading AuNPs onto it. Amperometric study demonstrated that the Au-Ni nanocomposites modified glassy carbon electrode (GCE) exhibited a high sensitivity of 2133.5 mA M -1 cm -2 and a wide linear range (0.4-900 μM) toward the oxidation of glucose with a detection limit as low as 0.1 μM. Moreover, the reproducibility, selectivity and stability of the sensor all exhibited outstanding performance. We applied the as-fabricated high performance sensor to measure the glucose levels in human serum and obtained satisfactory results. It is believed that AuNPs decorated Ni MOF/Ni/NiO nanocomposite provides a new platform for developing highly performance electrochemical sensors in practical applications. Copyright © 2018 Elsevier B.V. All rights reserved.

  5. Ni antagelser om Situationel Dialektisk Videnskabsteori

    DEFF Research Database (Denmark)

    Dakwar, Julia Rytter; Lorentzen, Anne-Christine Rosfeldt; Smedegaard, Flemming

    2017-01-01

    I artiklen præsenteres et præliminært bud på en Situationel Dialektisk Videnskabsteori (SDV) i form af ni antagelser. Situationel, fordi antagelserne ikke er statiske, men alle overvejelser og valg under de enkelte antagelser er afhængige af situationen. Dialektisk, fordi alle ni antagelser...... opererer med dialektiske modsætninger, og alle videnskabsteoretiske valg ses som valg på kontinua. De ni antagelser, som bliver præsenteret og diskuteret i artiklen, er: Antagelse 1: Teori og praksis fordrer hinanden Antagelse 2: Del og helhed hænger sammen Antagelse 3: Forbundne sagsforhold påvirker...

  6. New developments in Ni/Ti multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, I; Hoghoj, P [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France)

    1997-04-01

    It is now 20 years since super-mirrors were first used as a neutron optical element. Since then the field of multilayer neutron-optics has matured with multilayers finding their way to application in many neutron scattering instruments. However, there is still room for progress in terms of multilayer quality, performance and application. Along with work on multilayers for neutron polarisation Ni/Ti super-mirrors have been optimised. The state-of-the-art Ni/Ti super-mirror performance and the results obtained in two neutron-optics applications of Ni/Ti multilayers are presented. (author).

  7. FY 2000 report on the results of the project on the R and D of the global environmental industry technology. R and D of the technology for predicting environmental effects associated with the CO2 ocean sequestration (Development of the technology for predicting environmental effects in the area around the CO2 discharge point and survey for supporting study); 2000 nendo chikyu kankyo sangyo gijutsu kenkyu kaihatsu jigyo. Nisanka tanso no kaiyo kakuri ni tomonau kankyo eikyo yosoku gijutsu kenkyu kaihatsu (CO2 horyuten shuhen'iki no kankyo eikyo yosoku gijutsu no kaihatsu narabini kenkyu shien chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-03-01

    To obtain the technical outlook for CO2 ocean sequestration by CO2 discharge into the intermediate layer, the R and D was conducted of the technology for predicting environmental effects in the area around the CO2 discharge point, and the FY 2000 results were summed up. In the elucidation study of the behavior at the time of discharging liquid CO2, the melting process of CO2 droplets discharged/dispersed into the seawater of the intermediate layer was observed, and the specific phenomenon of hydrate formation in the process of CO2 droplet formation was grasped. As to the technology for sending CO2 into the ocean and diluting it, experimental study was made of CO2 transportation technology from on the sea to the intermediate layer, technology for rapid dilution immediately after discharge, etc. About the indoor experiment on the CO2 influence on marine organisms, experiment on the CO2 influence was carried out using shells, sea urchin, red sea bream, etc. In the developmental study of models for predicting environmental effects in the area around the CO2 discharge point, the 3D two-phase flow LES model was developed as a model for predicting the CO2 behavior, and the simulation of the liquid CO2 discharge was made at the planned experimental site. The model for evaluation of the biological influence was also made which can consider the interaction between two kinds of organisms. (NEDO)

  8. FY 1999 report on the results of the R and D project on the industrial technology for the global environment. R and D of the prediction technology of environmental effects brought by CO2 ocean sequestration (Development of prediction technology of environmental effects around the point of CO2 discharge and the research support survey); 1999 nendo chikyu kankyo sangyo gijutsu kenkyu kaihatsu jigyo NEDO seika hokokusho. Nisankatanso no kaiyo kakuri ni tomonau kankyo eikyo yosoku gijutsu kenkyu kaihatsu (CO2 horyuten shuhen'iki no kankyo eikyo yosoku gijutsu no kaihatsu narabini kenkyu shien chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    For the purpose of studying viability of CO2 ocean sequestration by discharging it at the intermediate depth of ocean, the R and D were conducted of 'prediction technology of environmental effects around the point of CO2 discharge,' and the FY 1999 results were summarized. In the study of elucidation of behavior of liquid CO2 at the time of discharge, melting speed of CO2 in water and seawater, 2D CO2 concentration distribution, etc. were measured using the circulation type deep-sea simulation experimental equipment. In the study of technology to send CO2 into the sea and dilute it, the process test using mock liquid was conducted. In the indoor experiment on CO2 effects on marine organisms, conducted were the detailed experiment on long-term effects of low concentration CO2 on sea urchins and shellfish, experiment on CO2 acute effects on eggs/fry and experiment on CO2 effects on adult fish. In the developmental study of the model to predict environmental effects around the point of CO2 discharge, carried out were the improvement of the model for prediction of effects on marine organisms, study of the CO2 diffusion in topographic features supposed to be Hawaii, etc. In the international joint study, measurement/observation technology, facilities, etc. were studied in preparation for the experiment actually conducted in the sea. (NEDO)

  9. FY 1999 report on the results of the R and D project on the industrial technology for the global environment. R and D of the prediction technology of environmental effects brought by CO2 ocean sequestration (Development of prediction technology of environmental effects around the point of CO2 discharge and the research support survey); 1999 nendo chikyu kankyo sangyo gijutsu kenkyu kaihatsu jigyo NEDO seika hokokusho. Nisankatanso no kaiyo kakuri ni tomonau kankyo eikyo yosoku gijutsu kenkyu kaihatsu (CO2 horyuten shuhen'iki no kankyo eikyo yosoku gijutsu no kaihatsu narabini kenkyu shien chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    For the purpose of studying viability of CO2 ocean sequestration by discharging it at the intermediate depth of ocean, the R and D were conducted of 'prediction technology of environmental effects around the point of CO2 discharge,' and the FY 1999 results were summarized. In the study of elucidation of behavior of liquid CO2 at the time of discharge, melting speed of CO2 in water and seawater, 2D CO2 concentration distribution, etc. were measured using the circulation type deep-sea simulation experimental equipment. In the study of technology to send CO2 into the sea and dilute it, the process test using mock liquid was conducted. In the indoor experiment on CO2 effects on marine organisms, conducted were the detailed experiment on long-term effects of low concentration CO2 on sea urchins and shellfish, experiment on CO2 acute effects on eggs/fry and experiment on CO2 effects on adult fish. In the developmental study of the model to predict environmental effects around the point of CO2 discharge, carried out were the improvement of the model for prediction of effects on marine organisms, study of the CO2 diffusion in topographic features supposed to be Hawaii, etc. In the international joint study, measurement/observation technology, facilities, etc. were studied in preparation for the experiment actually conducted in the sea. (NEDO)

  10. FY 2000 report on the results of the project on the R and D of the global environmental industry technology. R and D of the technology for predicting environmental effects associated with the CO2 ocean sequestration (Development of the technology for predicting environmental effects in the area around the CO2 discharge point and survey for supporting study); 2000 nendo chikyu kankyo sangyo gijutsu kenkyu kaihatsu jigyo. Nisanka tanso no kaiyo kakuri ni tomonau kankyo eikyo yosoku gijutsu kenkyu kaihatsu (CO2 horyuten shuhen'iki no kankyo eikyo yosoku gijutsu no kaihatsu narabini kenkyu shien chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-03-01

    To obtain the technical outlook for CO2 ocean sequestration by CO2 discharge into the intermediate layer, the R and D was conducted of the technology for predicting environmental effects in the area around the CO2 discharge point, and the FY 2000 results were summed up. In the elucidation study of the behavior at the time of discharging liquid CO2, the melting process of CO2 droplets discharged/dispersed into the seawater of the intermediate layer was observed, and the specific phenomenon of hydrate formation in the process of CO2 droplet formation was grasped. As to the technology for sending CO2 into the ocean and diluting it, experimental study was made of CO2 transportation technology from on the sea to the intermediate layer, technology for rapid dilution immediately after discharge, etc. About the indoor experiment on the CO2 influence on marine organisms, experiment on the CO2 influence was carried out using shells, sea urchin, red sea bream, etc. In the developmental study of models for predicting environmental effects in the area around the CO2 discharge point, the 3D two-phase flow LES model was developed as a model for predicting the CO2 behavior, and the simulation of the liquid CO2 discharge was made at the planned experimental site. The model for evaluation of the biological influence was also made which can consider the interaction between two kinds of organisms. (NEDO)

  11. Site occupancy of Fe in ternary Ni 75-x

    Indian Academy of Sciences (India)

    The results of a detailed structural and magnetic study clearly indicate that regardless of the thermal history of the samples, Fe has a strong preference for the Ni sites in Ni-poor (non-stoichiometric) Ni75Al25 alloys. Fe substitution has a profound effect on the nature of magnetism in Ni75Al25.

  12. Reduction of a Ni/Spinel Catalyst for Methane Reforming

    DEFF Research Database (Denmark)

    Kehres, Jan; Andreasen, Jens Wenzel; Fløystad, Jostein Bø

    2015-01-01

    microscopy (HRTEM) was performed on the fresh catalyst sample. The Ni particles in the fresh catalyst sample were observed to exhibit a Ni/NiO core/shell structure. A decrease of the Ni lattice parameter is observed during the reduction in a temperature interval from 413 – 453 K, which can be related...

  13. Influence of Ni Solute segregation on the intrinsic growth stresses in Cu(Ni) thin films

    International Nuclear Information System (INIS)

    Kaub, T.M.; Felfer, P.; Cairney, J.M.; Thompson, G.B.

    2016-01-01

    Using intrinsic solute segregation in alloys, the compressive stress in a series of Cu(Ni) thin films has been studied. The highest compressive stress was noted in the 5 at.% Ni alloy, with increasing Ni concentration resulting in a subsequent reduction of stress. Atom probe tomography quantified Ni's Gibbsian interfacial excess in the grain boundaries and confirmed that once grain boundary saturation is achieved, the compressive stress was reduced. This letter provides experimental support in elucidating how interfacial segregation of excess adatoms contributes to the post-coalescence compressive stress generation mechanism in thin films. - Graphical abstract: Cu(Ni) film stress relationship with Ni additions. Atom probe characterization confirms solute enrichment in the boundaries, which was linked to stress response.

  14. NiCo-lead zirconium titanate-NiCo trilayered magnetoelectric composites prepared by electroless deposition

    International Nuclear Information System (INIS)

    Zhou, M. H.; Wang, Y. G.; Bi, K.; Fan, H. P.; Zhao, Z. S.

    2015-01-01

    The NiCo layers with various Ni/Co atomic ratio have been successfully electroless deposited on PZT layers by varying the bath composition. As the cobalt atomic ratio in the deposited layer increases from 17.2 to 54.8 wt%, the magnetostrictive coefficient decreases. The magnetoelectric effect depends strongly on the magnetostrictive properties of magnetostrictive phase. The magnetoelectric coefficient of NiCo/PZT/NiCo trilayers increases with Ni/Co atomic ratio of the deposited NiCo layers increasing from 45:55 to 83:17. A maximum ME voltage coefficient of α E,31 = 2.8 V ⋅ cm −1 ⋅ Oe −1 is obtained at a frequency of about 88 kHz, which makes these trilayers suitable for applications in actuators, transducers and sensors

  15. NiCo-lead zirconium titanate-NiCo trilayered magnetoelectric composites prepared by electroless deposition

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, M. H.; Wang, Y. G.; Bi, K., E-mail: bike@bupt.edu.cn [State Key Laboratory of Information Photonics and Optical Communications and School of Science, Beijing University of Posts and Telecommunications, Beijing 100876 (China); Fan, H. P. [School of Mechanical and Electrical Engineering, Qingdao Technological University Qindao College, Qingdao 266106 (China); Zhao, Z. S. [Shandong Engineering Consulting Institute, Jinan 250013 (China)

    2015-04-15

    The NiCo layers with various Ni/Co atomic ratio have been successfully electroless deposited on PZT layers by varying the bath composition. As the cobalt atomic ratio in the deposited layer increases from 17.2 to 54.8 wt%, the magnetostrictive coefficient decreases. The magnetoelectric effect depends strongly on the magnetostrictive properties of magnetostrictive phase. The magnetoelectric coefficient of NiCo/PZT/NiCo trilayers increases with Ni/Co atomic ratio of the deposited NiCo layers increasing from 45:55 to 83:17. A maximum ME voltage coefficient of α{sub E,31} = 2.8 V ⋅ cm{sup −1} ⋅ Oe{sup −1} is obtained at a frequency of about 88 kHz, which makes these trilayers suitable for applications in actuators, transducers and sensors.

  16. Fe-solubility of Ni7S6 and Ni9S8: Thermodynamic analysis

    International Nuclear Information System (INIS)

    Waldner, P.

    2011-01-01

    Experimental data on phase equilibria have been used for thermodynamic analysis of the iron solubility of the nickel sulfides Ni 7 S 6 and Ni 9 S 8 . For both compounds, a two-sublattice approach within the framework of the compound energy formalism has been applied to perform Gibbs free energy modelling at 0.1 MPa total pressure consistently embedded in recent thermodynamic assessment studies of other iron-nickel-sulfides. The predicted maxima of iron solubility around 3 at% of Ni 7 S 6 and 5.5 at% of Ni 9 S 8 are confirmed by experimental data. The calculations of complex ternary phase relations with Fe-bearing Ni 7 S 6 and Ni 9 S 8 gain further improvement. The first internally consistent description of all thermodynamically stable phases known in the literature for the iron-nickel-sulfur system is completed.

  17. Phase stability and magnetism in NiPt and NiPd alloys

    International Nuclear Information System (INIS)

    Paudyal, Durga; Mookerjee, Abhijit

    2004-01-01

    We show that the differences in stability of 3d-5d NiPt and 3d-4d NiPd alloys arise mainly due to relativistic corrections. The magnetic properties of disordered NiPd and NiPt alloys also differ due to these corrections, which lead to increase in the separation between the s-d bands of 5d elements in these alloys. For the magnetic case we also analyse the results in terms of splitting of majority and minority spin d band centres of the 3d elements. We further examine the effect of relativistic corrections to the pair energies and order-disorder transition temperatures in these alloys. The magnetic moments and Curie temperatures have also been studied along with the short range ordering/segregation effects in NiPt/NiPd alloys

  18. Precipitation of Ni4Ti3-variants in a polycrystalline Ni-rich NiTi shape memory alloy

    Czech Academy of Sciences Publication Activity Database

    Bojda, Ondřej; Eggeler, G.; Dlouhý, Antonín

    2005-01-01

    Roč. 53, č. 1 (2005), s. 99-104 ISSN 1359-6462 R&D Projects: GA ČR(CZ) GA106/05/0918 Institutional research plan: CEZ:AV0Z20410507 Keywords : NiTi shape memory alloys * Ni4Ti3 precipitation * Transmission electron microscopy Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.228, year: 2005

  19. Ni-Ni ion pair excitation transfer in D sub(3h) symmetry

    International Nuclear Information System (INIS)

    Terrile, M.C.

    1990-01-01

    The mechanisms contributing to excitation transfer are examined for Ni-Ni ion pairs in order to explain the delocalized character of electronic excitations observed in CsNiF sub(3). Using both first-and second-order perturbation theory and from symmetry arguments, the kind of interactions giving matrix elements between states connecting different sites for the position of the excitation are discussed. (author)

  20. Electronic structure of graphene on Ni surfaces with different orientation

    International Nuclear Information System (INIS)

    Pudikov, D.A.; Zhizhin, E.V.; Rybkin, A.G.; Rybkina, A.A.; Zhukov, Y.M.; Vilkov, O. Yu.; Shikin, A.M.

    2016-01-01

    An experimental study of the graphene, synthesized by propylene cracking on Ni surfaces with different orientation: (100) and (111), using angle-resolved photoemission, has been performed. It has been shown that graphene on Ni(111) had a perfect lateral structure due to consistency of their lattices, whereas graphene/Ni(100) consisted of a lot of domains. For both systems electronic structure was quite similar and demonstrated a strong bonding of graphene to the underlying Ni surface. After Au intercalation the electronic structure of graphene in both systems was shifted to the Fermi level and became linear in the vicinity of the K point of the Brillouin zone. - Highlights: • Graphene on Ni(111) is well-ordered, whereas on Ni(100) – multi-domain. • Graphene on Ni(111) and Ni(100) is strongly bonded with substrate. • Intercalation of Au atoms restores the linearity in dispersion and makes graphene quasi-free on both Ni(100) and Ni(111).

  1. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    Energy Technology Data Exchange (ETDEWEB)

    Kabir, L.; Mandal, A.R. [Department of Physics, Visva-Bharati, Santiniketan-731 235 (India); Mandal, S.K., E-mail: sk_mandal@hotmail.co [Department of Physics, Visva-Bharati, Santiniketan-731 235 (India)

    2010-04-15

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni{sup 2+} clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni{sup 2+} clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  2. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    Science.gov (United States)

    Kabir, L.; Mandal, A. R.; Mandal, S. K.

    2010-04-01

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni 2+ clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni 2+ clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  3. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    International Nuclear Information System (INIS)

    Kabir, L.; Mandal, A.R.; Mandal, S.K.

    2010-01-01

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni 2+ clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni 2+ clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  4. Modeling and simulation of NiO dissolution and Ni deposition in molten carbonate fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Nam, Suk Woo; Choi, Hyung-Joon; Lim, Tae Hoon [Korea Institute of Science & Technology, Seoul (Korea, Republic of)] [and others

    1996-12-31

    Dissolution of NiO cathode into the electrolyte matrix is an important phenomena limiting the lifetime of molten carbonate fuel cell (MCFC). The dissolved nickel diffuses into the matrix and is reduced by dissolved hydrogen leading to the formation of metallic nickel films in the pores of the matrix. The growth of Ni films in the electrolyte matrix during the continuous cell operation results eventually in shorting between cathode and anode. Various mathematical and empirical models have been developed to describe the NiO dissolution and Ni deposition processes, and these models have some success in estimating the lifetime of MCFC by correlating the amount of Ni deposited in the matrix with shorting time. Since the exact mechanism of Ni deposition was not well understood, deposition reaction was assumed to be very fast in most of the models and the Ni deposition region was limited around a point in the matrix. In fact, formation of Ni films takes place in a rather broad region in the matrix, the location and thickness of the film depending on operating conditions as well as matrix properties. In this study, we assumed simple reaction kinetics for Ni deposition and developed a mathematical model to get the distribution of nickel in the matrix.

  5. Layering and temperature-dependent magnetization and anisotropy of naturally produced Ni/NiO multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Pappas, S. D.; Trachylis, D.; Velgakis, M. J. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Kapaklis, V.; Joensson, P. E.; Papaioannou, E. Th. [Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden); Delimitis, A. [Chemical Process Engineering Research Institute (CPERI), Centre for Research and Technology Hellas (CERTH), 57001 Thermi, Thessaloniki (Greece); Poulopoulos, P. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Institut fuer Experimentalphysik, Freie Universitaet Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Materials Science Department, University of Patras, 26504 Patras (Greece); Fumagalli, P. [Institut fuer Experimentalphysik, Freie Universitaet Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Politis, C. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Department of Materials Science and Engineering, University of Texas at Arlington, Arlington, Texas 76019 (United States)

    2012-09-01

    Ni/NiO multilayers were grown by magnetron sputtering at room temperature, with the aid of the natural oxidation procedure. That is, at the end of the deposition of each single Ni layer, air is let to flow into the vacuum chamber through a leak valve. Then, a very thin NiO layer ({approx}1.2 nm) is formed. Simulated x-ray reflectivity patterns reveal that layering is excellent for individual Ni-layer thickness larger than 2.5 nm, which is attributed to the intercalation of amorphous NiO between the polycrystalline Ni layers. The magnetization of the films, measured at temperatures 5-300 K, has almost bulk-like value, whereas the films exhibit a trend to perpendicular magnetic anisotropy (PMA) with an unusual significant positive interface anisotropy contribution, which presents a weak temperature dependence. The power-law behavior of the multilayers indicates a non-negligible contribution of higher order anisotropies in the uniaxial anisotropy. Bloch-law fittings for the temperature dependence of the magnetization in the spin-wave regime show that the magnetization in the multilayers decreases faster as a function of temperature than the one of bulk Ni. Finally, when the individual Ni-layer thickness decreases below 2 nm, the multilayer stacking vanishes, resulting in a dramatic decrease of the interface magnetic anisotropy and consequently in a decrease of the perpendicular magnetic anisotropy.

  6. XRD studies on solid state amorphisation in electroless Ni/P and Ni/B deposits

    International Nuclear Information System (INIS)

    Sampath Kumar, P.; Kesavan Nair, P.

    1996-01-01

    The decomposition of electroless Ni-P and Ni-B deposits on annealing at various temperature is studied using x-ray diffraction techniques employing profile deconvolution and line profile analysis. It appears that solid state amorphisation takes place in the Ni-B deposits in a narrow temperature range just prior to the onset of crystallization of amorphous phase. In the case of Ni-P deposits no evidence for solid state amorphisation could be obtained. Thermodynamic and kinetic considerations also support such a conclusion

  7. FY 1999 report on the results of the R and D project on the industrial technology for the global environment. R and D of the prediction technology of environmental effects brought by CO2 ocean sequestration (Ocean survey and development of evaluation technology for CO2 sequestration ability); 1999 nendo chikyu kankyo sangyo gijutsu kenkyu kaihatsu jigyo NEDO seika hokokusho. Nisankatanso no kaiyo kakuri ni tomonau kankyo eikyo yosoku gijutsu kenkyu kaihatsu (Kaiyo chosa oyobi CO2 kakuri noryoku hyoka gijutsu no kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Assuming the melting and sequestration of CO2 at the intermediate depth of the sea area around Japan, study of evaluation technology of CO2 sequestration ability in ocean was studied, and the FY 1999 results were summed up. In the ocean survey, survey was conducted by ship (No.2 Hakurei-maru) mainly at typical observation points and traverse lines of long. 147 E and long. 155 E. In the survey, the following data were acquired: data on seawater density and chemical tracer, data on release of intermediate-depth/independent buoys, concentration distribution of carbonic acid base substances/nutrient salts/chlorophyll, data on the existing amount of marine organisms and primary production speed measurement experiment, data on experiment on CO2 on-board exposure to organisms in the intermediate depth of ocean, etc. In the measurement/analysis of the sediment particle flux amount, sediment traps were installed/recovered. Further, for the purpose of measuring the neutralizing effect of calcium carbonate, operation test on CaCO{sub 3} melting experimental equipment was conducted in the actual sea area. In the development of a model for evaluation of CO2 sequestration ability, carried out were the improvement of the model using the inverse method, study of the estimated accuracy using the ocean observation data, etc. (NEDO)

  8. Fiscal 1993 international research cooperation project. Feasibility study of finding out the seeds of international joint research (technology for environmental preservation using biotechnology, technology for effective use of unused hydrocarbon resource, technology for development of environmental harmony type catalyst); 1995 nendo kokusai kyoryoku jigyo. Kokusai kyodo kenkyu seeds hakkutsu no tame no FS chosa (biotechnology ni yoru kankyo taisaku gijutsu, miriyo tanka suiso shigen no yuko riyo gijutsu, kankyo chowagata shokubai kaihatsu gijutsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    This project is aimed at internationally cooperating in the R and D of industrial technology and improving industrial technology of Japan. For it, the following three technologies were investigated: 1) environmental preservation technology using biotechnology, 2) technology for effective use of unused hydrocarbon resource, 3) technology for development of environmental harmony type catalyst. In 1), a survey was conducted of applicability of biological surfactant to prevention measures of pollution by heavy distillate. It showed that part of the biological surfactants is reaching a stage of its being industrially produced by gene recombination bacteria, but as a whole, biosynthetic genes have hardly been elucidated. In 2), a survey of high-grade treatment technology of petroleum coke was made. It pointed out that it is necessary to develop a technology which makes the most of features of petroleum coke and allows defects. In 3), scientists and engineers of Japan and Europe searched for themes on which they can jointly study in the fields of NOx removal catalyst, up-grading of fuel, and development of catalyst combustion of fuel. 287 refs., 136 figs., 128 tabs.

  9. FY 2000 Feasibility study on the environmentally-friendly coal utilization systems as part of the international project for coal utilization measures. Feasibility study on supporting introduction of the environmentally-friendly coal utilization systems in Vietnam (Model project for introduction of advanced coal preparation systems); 2000 nendo kokusai sekitan riyo taisaku jigyo chosa hokokusho. Kankyo chowagata sekitan riyo system kanosei chosa jigyo Vietnam ni okeru kankyo chowagata sekitan riyo system donyu shien jigyo (kodo sentan system donyu model jigyo kanosei chosa jigyo)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-06-01

    The feasibility study was conducted on a model project in Vietnam, aimed at solving the environmental pollution problems resulting from use of coal by demonstrating and disseminating the Japan's environmental technologies in the Southeast Asian countries. The feasibility study was conducted for the Cua Ong Coal Preparation Enterprise, which has the largest coal preparation capacity in Vietnam and port facilities. It is treating raw coal from 10 coal mines for classification and preparation, and shipping coal of various types that meet the standards for domestic use and export. The survey results point out that unrecovered coal remains in waste water discharged from the coal preparation plants to pollute the sea area, and that quantity of the refuse increases because of the unrecovered coal it contains. The environmental technologies needed to introduce include modification to variable wave pattern type jigging separator, refuse height measuring instrument and automatic controller, circulating heavy medium gravimeter, highly functional settling pond, and flocculent facilities. (NEDO)

  10. Ni adsorption and Ni-Al LDH precipitation in a sandy aquifer: An experimental and mechanistic modeling study

    NARCIS (Netherlands)

    Regelink, I.C.; Temminghoff, E.J.M.

    2011-01-01

    Mining activities and industries have created nickel (Ni) contaminations in many parts of the world. The objective of this study is to increase our understanding of Ni adsorption and Nickel-Aluminium Layered Double Hydroxide (Ni-Al LDH) precipitation to reduce Ni mobility in a sandy soil aquifer. At

  11. Core/shell AgNi/PtAgNi nanoparticles as methanol-tolerant oxygen reduction electrocatalysts

    International Nuclear Information System (INIS)

    Wu, Dengfeng; Cheng, Daojian

    2015-01-01

    A core/shell AgNi/PtAgNi nanoparticle (NP) was synthesized via a new seed-mediated growth method in organic solvent medium. The as-synthesized AgNi/PtAgNiNP exhibits an AgNi core coated with PtAgNi shell, which was confirmed by transmission electron microscopy (TEM), ultraviolet–visible absorption spectroscopy and X-ray Photoelectron Spectroscopy (XPS). The AgNi/PtAgNiNPs/C catalyst possesses higher oxygen reduction reaction (ORR) activity and better durability compared with the commercial Pt/C catalyst. It is found that the ORR polarization curve of the AgNi/PtAgNiNPs/C catalyst shows an onset potential of 0.91 V vs. RHE, which is superior to the commercial Pt/C (0.88 V vs. RHE). In addition, the AgNi/PtAgNiNPs/C catalyst shows much better durability than the commercial Pt/C catalyst. More interestingly, the AgNi/PtAgNiNPs/C catalyst displays much higher methanol tolerance than the commercial Pt/C catalyst in 0.1 M KOH solution in the presence of 0.5 M methanol. Our results show that core/shell AgNi/PtAgNiNPs possess selective activity for ORR even in the presence of methanol, showing potential application as methanol-tolerant cathode catalysts in direct methanol fuel cells.

  12. Grain boundaries in Ni3Al. 2

    International Nuclear Information System (INIS)

    Kung, H.; Sass, S.L.

    1992-01-01

    This paper discusses the dislocation structure of small angle tilt and twist boundaries in ordered Ni 3 Al, with and without boron, investigated using transmission electron microscopy. Dislocation with Burgers vectors that correspond to anti-phase boundary (APB)-coupled superpartials were found in small angle twist boundaries in both boron-free and boron-doped Ni 3 Al, and a small angle tilt boundary in boron-doped Ni 3 Al. The boundary structures are in agreement with theoretical models proposed by Marcinkowski and co-workers. The APB energy determined from the dissociation of the grain boundary dislocations was lower than values reported for isolated APBs in Ni 3 Al. For small angle twist boundaries the presence of boron reduced the APB energy at the interface until it approached zero. This is consistent with the structure of these boundaries containing small regions of increased compositional disorder in the first atomic plane next to the interface

  13. Ni-ZrB2 electrocomposites

    International Nuclear Information System (INIS)

    Pushpavanam, M.; Natarajan, S.R.

    1992-01-01

    New generation materials require high temperature oxidation resistance besides many other tribological properties. Ni-ZrB 2 composites and their properties are dealt with in this paper. (author). 7 refs., 3 figs., 4 tabs

  14. Not in Traffic Surveillance (NiTS)

    Data.gov (United States)

    Department of Transportation — The Not-in-Traffic Surveillance (NiTS) system is a virtual data collection system designed to provide counts and details regarding fatalities and injuries that occur...

  15. Niños y Violencia

    OpenAIRE

    International Child Development Centre

    1997-01-01

    Este Innocenti Digest explora la violencia de los niños y hacia los niños, usando el marco de la Convención de los Derechos del Niño de las Naciones Unidas. Se centra en la violencia interpersonal, tanto intrafamiliar como extrafamiliar. Se incluye el abuso sexual y la explotación ya que a pesar de no implicar obligatoriamente violencia o coerción, la mayor parte de la evidencia demuestra su efectos dañinos tanto físicos como psicológicos. También se discute la implicación de los niños en los...

  16. Collision strengths for transitions in Ni XIX

    Indian Academy of Sciences (India)

    4l configurations of Ni XIX, for which flexible atomic code. (FAC) has been ... atomic data (namely energy levels, radiative rates, collision strengths, excitation rates, etc.) ... Zhang and Sampson, who adopted the Coulomb–Born-exchange.

  17. Root morphology of Ni-treated plants

    International Nuclear Information System (INIS)

    Leskova, A.; Fargasova, A.; Giehl, R. F. H.; Wiren, N. von

    2015-01-01

    Plant roots are very important organs in terms of nutrient and water acquisition but they also serve as anchorages for the aboveground parts of the plants. The roots display extraordinary plasticity towards stress conditions as a result of integration of environmental cues into the developmental processes of the roots. Our aim was to investigate the root morphology of Arabidopsis thaliana plants exposed to a particular stress condition, excess Ni supply. We aimed to find out which cellular processes - cell division, elongation and differentiation are affected by Ni, thereby explaining the seen root phenotype. Our results reveal that a distinct sensitivity exists between roots of different order and interference with various cellular processes is responsible for the effects of Ni on roots. We also show that Ni-treated roots have several auxin-related phenotypes. (authors)

  18. Density and Structure Analysis of Molten Ni-W Alloys

    Institute of Scientific and Technical Information of China (English)

    Feng XIAO; Liang FANG

    2004-01-01

    Density of molten Ni and Ni-W alloys was measured in the temperature range of 1773~1873 K with a sessile drop method.The density of molten Ni and Ni-W alloys trends to decrease with increasing temperature. The density and molar volume of the alloys trend to increase with increasing W concentration in the alloys. The calculation result shows an ideal mixing of Ni-W alloys.

  19. Fe-Cr-Ni system alloys

    International Nuclear Information System (INIS)

    Levin, F.L.

    1986-01-01

    Phase diagram of Fe-Cr-Ni system, which is the basic one for production of corrosion resistant alloys, is considered. Data on corrosion resistance of such alloys are correlated depending on a number of factors: quality and composition of modifying elements, corrosion medium, temperature, alloy structure, mechanical and thermal treatment. Grades of Fe-Ni-Cr alloys are presented, and fields of their application are pointed out

  20. Synthesis of Ni3Ta, Ni2Ta and NiTa by high-energy ball milling and subsequent heat treatment

    International Nuclear Information System (INIS)

    Benites, H.S.N.; Silva, B.P da; Ramos, A.S.; Silva, A.A.A.P.; Coelho, G.C.; Lima, B.B. de

    2014-01-01

    The tantalum has relevance for the development of multicomponent Ni-based superalloys which are hardened by solid solution and precipitation mechanisms. Master alloys are normally used in the production step in order to produce refractory metals and alloys. The present work reports on the synthesis of Ni_3Ta, Ni_2Ta and NiTa by high-energy ball milling and subsequent heat treatment. The elemental Ni-25Ta, Ni-33Ta and Ni-50Ta (at.-%) powder mixtures were ball milled under Ar atmosphere using stainless steel balls and vials, 300 rpm and a ball-to-powder weight ratio of 10:1. Following, the as-milled samples were uniaxially compacted and heat-treated at 1100 deg C for 4h under Ar atmosphere. The characterization of as-milled and heat-treated samples was conducted by means of X-ray diffraction, scanning electron microscopy, and energy dispersive spectrometry. A large amount of Ni_3Ta, Ni_2Ta and NiTa was formed in the mechanically alloyed heat-treated Ni-25Ta, Ni-33Ta and Ni-50Ta alloys. (author)

  1. Structural Investigation of Fe-Ni-S and Fe-Ni-Si Melts by High-temperature Fluorescence XAFS Measurements

    International Nuclear Information System (INIS)

    Manghnani, Murli H.; Balogh, John; Hong Xinguo; Newville, Matthew; Amulele, G.

    2007-01-01

    Iron-nickel (Fe-Ni) alloy is regarded as the most abundant constituent of Earth's core, with an amount of 5.5 wt% Ni in the core based on geochemical and cosmochemical models. The structural role of nickel in liquid Fe-Ni alloys with light elements such as S or Si is poorly understood, largely because of the experimental difficulties of high-temperature melts. Recently, we have succeeded in acquiring Ni K-edge fluorescence x-ray absorption fine structure (XAFS) spectra of Fe-Ni-S and Fe-Ni-Si melts and alloys. Different structural environment of Ni atoms in Fe-Ni-S and Fe-Ni-Si melts is observed, supporting the effect of light elements in Fe-Ni melts

  2. The complex transfer reaction (14C, 15O) on Ni, Zn and Ge targets: existence and mass of 69Ni

    International Nuclear Information System (INIS)

    Dessagne, P.; Bernas, M.; Langevin, M.; Pougheon, F.; Roussel, P.; Morrison, G.C.

    1984-01-01

    The ( 14 C, 15 O) complex transfer reaction has been studied at 72 MeV incident energy on 58 Ni, 60 Ni, 62 Ni, 64 Ni, 68 Zn, 70 Zn and 74 Ge, 76 Ge targets. Spectra and differential cross sections have been measured in a 5 0 angular range centred around a laboratory angle of 6 0 . The nucleus 69 Ni has been observed and its mass determined for the first time

  3. Electroless Ni-P/Ni-B duplex coatings: preparation and evaluation of microhardness, wear and corrosion resistance

    International Nuclear Information System (INIS)

    Narayanan, T.S.N. Sankara; Krishnaveni, K.; Seshadri, S.K.

    2003-01-01

    The present work deals with the formation of Ni-P/Ni-B duplex coatings by electroless plating process and evaluation of their hardness, wear resistance and corrosion resistance. The Ni-P/Ni-B duplex coatings were prepared using dual baths (acidic hypophosphite- and alkaline borohydride-reduced electroless nickel baths) with both Ni-P and Ni-B as inner layers and with varying single layer thickness. Scanning electron microscopy (SEM) was used to assess the duplex interface. The microhardness, wear resistance and corrosion resistance of electroless nickel duplex coatings were compared with electroless Ni-P and Ni-B coatings of similar thickness. The study reveals that the Ni-P and Ni-B coatings are amorphous in their as-plated condition and upon heat-treatment at 450 deg. C for 1 h, both Ni-P and Ni-B coatings crystallize and produce nickel, nickel phosphide and nickel borides in the respective coatings. All the three phases are formed when Ni-P/Ni-B and Ni-B/Ni-P duplex coatings are heat-treated at 450 deg. C for 1 h. The duplex coatings are uniform and the compatibility between the layers is good. The microhardness, wear resistance and corrosion resistance of the duplex coating is higher than Ni-P and Ni-B coatings of similar thickness. Among the two types of duplex coatings studied, hardness and wear resistance is higher for coatings having Ni-B coating as the outer layer whereas better corrosion resistance is offered by coatings having Ni-P coating as the outer layer

  4. Heavy metal environmental impact. Nickel (Ni); Impatto ambientale da metalli pesanti. Il Nichel (Ni)

    Energy Technology Data Exchange (ETDEWEB)

    Bressa, G. [Padua Univ. Padua (Italy). Dipt. di Farmacologia, Lab. di Tossicologia

    2001-02-01

    Nickel (Ni) is a heavy metal in over 3.000 different alloys used to produce kitchen utensils, batteries, coins, etc.. Human extractive and industrial activities are therefore a cause for environmental dispersion of this metal into the biosphere. This shows how in urban areas car traffic and house-heating are the main sources of nickel pollution. Nickel is relatively non-toxic, such as iron, cobalt, copper and zinc; nevertheless prolonged inhalation of dust containing such compounds as Ni O or NiCl{sub 2} concurs in the outbreak of respiratory pathologies. The carcinogenic effect of such compounds as Ni S, Ni O and Ni(CO){sub 4} has been confirmed by experiments on laboratory animals. Ni potentially toxic concentrations, and as a consequence of potential environmental impact, are to be mainly found in populated areas where the main sources are represented by industries and landfills. [Italian] Il nichel (Ni) e' un metallo presente in oltre 3.000 differenti leghe che vengono utilizzate per la produzione di utensili da cucina, batterie, monete, ecc.. Le attivita' estrattive ed industriali dell'uomo sono quindi causa di una dispersione del metallo nella biosfera. Sono stati riscontrati elevati tassi di Ni nell'atmosfera di aree urbane. Cio' sta a dimostrare che nelle aree urbane il traffico automobilistico e il riscaldamento domestico sono le fonti principali di inquinamento da tale metallo. Il nichel e' relativamente atossico, analogamente a ferro, cobalto, rame e zinco, tuttavia l'inalazione protratta di polveri contenenti composti come il NiO o il NiCl{sub 2} contribuisce al manifestarsi di patologie dell'apparato respiratorio. E' stato confermato sperimentalmente su animali da laboratorio l'effetto cancerogeno di alcuni composti quali NiS, NiO e Ni(CO){sub 4}. Concentrazioni potenzialmente tossiche di Ni, e quindi di probabile impatto ambientale, sono maggiormente da ricercare nelle zone antropizzate dove le fonti

  5. Ultrathin NiO/NiFe2O4 Nanoplates Decorated Graphene Nanosheets with Enhanced Lithium Storage Properties

    International Nuclear Information System (INIS)

    Du, Dejian; Yue, Wenbo; Fan, Xialu; Tang, Kun; Yang, Xiaojing

    2016-01-01

    Highlights: • Ultrathin NiO/NiFe 2 O 4 nanoplates derived from NiFe layered double hydroxides are fabricated on the graphene. • NiO/NiFe 2 O 4 nanoplates on the graphene show superior electrochemical performance compared to pure NiO/NiFe 2 O 4 aggregates. • The effects of the content and the particle size/component of NiO/NiFe 2 O 4 on the electrochemical performances are studied. • Graphene-encapsulated NiO/NiFe 2 O 4 is prepared and shows slightly decreased performance compared to graphene-based composite. - Abstract: As anode materials for lithium-ion batteries, bicomponent metal oxide composites show high reversible capacities; but the morphology and particle size of the composites are hardly controllable, which may reduce their electrochemical properties. In this work, ultrathin NiO/NiFe 2 O 4 nanoplates with a diameter of 5 ∼ 7 nm and a thickness of ∼2 nm are controllably fabricated on the graphene derived from NiFe layered double hydroxides (NiFe-LDHs), and exhibit superior electrochemical performance compared to pure NiO/NiFe 2 O 4 aggregates without graphene. The nanosized NiO and NiFe 2 O 4 plates are separated from each other and the graphene substrate can prevent the aggregation of NiO/NiFe 2 O 4 as well as enhance the electronic conductivity of the composite, which is beneficial to improving the electrochemical performance. Moreover, the effects of the content and the particle size/component of NiO/NiFe 2 O 4 on the electrochemical performances are also studied in order to achieve optimal performance. Ultrathin NiO/NiFe 2 O 4 nanoplates are further encapsulated by graphene nanosheets and show slightly decreased performance compared to those supported by graphene nanosheets. The different electrochemical behaviors of graphene-containing composites may be attributed to the different interactions between graphene nanosheets and NiO/NiFe 2 O 4 nanoplates.

  6. Typing of the sausage-shaped bacteria forming A-type sulfur-turf according to cell length distributions of natural populations and physico-chemical conditions of hot spring waters; Saibo chobunpu to seiiku kankyo kara mita A gata io shiba shizen kotaigun ni okeru okamagata saikin no katabetsu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Aki, Y. [Iwate University, Iwate (Japan). Faculty of Humanities and Social Sciences

    1996-01-25

    In order to type the sausage-shaped bacteria forming A-type sulfur-turf, cell length distributions and physics-chemical conditions of hot spring waters were investigated on twelve samples collected from all over Japan. The frequency distributions of the cell length of eight samples were bimodal, while the other four samples were unimodal. In seven samples with bimodal distributions, two types (large and small) of the sausage-shaped bacteria could be differentiated. The cell length of the large-type was between 10.1 and 31.9{mu}m, while that of the small-type ranged 2.2 to 6.6{mu}m. The pH of seven hot spring waters were between 6 and 8, and the two types (large and small) formed together sulfur-turf. In contrast, pH of the three hot springs were over 8, and the two types of the sausage-shaped bacteria could not be detected in the sulfur-turf. Therefore, it is reasonable to set a third type of the sausage-shaped bacteria which prefers high-pH (over 8) and low calcium condition. The cell lengths of the third type were in the range of 5.5 to 8.6{mu}m, which correspond to the sausage-shaped bacteria of medium size. 20 refs., 5 figs., 2 tabs.

  7. Report on achievement in the preceding research related to global industry technologies for the global industry technology research and development project. Research on gas systems substituting global warming gases such as PFC used in manufacturing semiconductors; 1998 nendo chikyu kankyo sangyo gijutsu ni kakawaru sendo kenkyu. Handotai seizo nado ni shiyosuru PFC nado no chikyu ondanka gas no daitai gas system no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The present semiconductor manufacturing process uses a great amount of PFC having large global warming coefficients and extremely long atmospheric life. A research was made particularly on reduction of its emission from etching processes. After introducing how the semiconductor industry has been working conventionally on protection of the global environment, this paper makes clear the purpose and positioning of this preceding research, as well as how it is moved forward. The paper also reports the results of analyzing and discussing the exhaust gases from etching devices using several kinds of substitute PFC gases. Survey results are reported on the possibilities of new substitute gases, plasma decomposition and treatment of exhaust gases, reaction process simulation, and in-situ analyzing and evaluating technologies. Investigations were made on the possibility of using no PFC in wiring processes which consume greater amount of PFC, as well as on wiring techniques using inter-layer insulation film with low dielectric rate, a new wiring structure forming technology, new functional elements, circuits and systems in a wide range. Proposals were given on specific research and development themes and plans that begin in fiscal 1999. (NEDO)

  8. FY 1999 report on the results of the introductory study on the global environmental industry technology. Study of the technology to recycle organic waste as resource in the chemical industry; 1999 nendo chikyu kankyo sangyo gijutsu ni kakawaru sendo kenkyu seika hokokusho. Kagaku kogyo ni okeru yukisei haikibutsu no saishigenka gijutsu no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    An investigational study was conducted of applicability/viability of the technology to recycle as resource the organic waste and CO2 discharged from the chemical industry, etc., and the FY 1999 results were summarized. As to the production of hydrogen from the organic waste, a bioreactor was developed which enables the production of hydrogen of 58 mmol/L/hr using Enterobactor aerogenes by the isolation bacteria method, and it successfully enabled the production of hydrogen from biomass resource. Further, the micro-flora method can be responded to a variety of substrates, but in this method the hydrogen production rate is not as high as in the isolation bacteria method at the present time. Concerning the method to convert CO2 to useful organic resource by the hydrogen produced, an experimental value of the maximum production rate of 149g/L/d which is high was obtained in case of acetic acid. Moreover, the paper described an outline and the basic concept of the recycle system of energy and carbon resource which integrates the production of energy from organic waste being considered at the present time and the production of useful matters from CO2. (NEDO)

  9. Change in concentration distribution and equivalent rate constant with flow velocity in a boundary layer around a catalyst of non-uniform surface activity; Kotai shokubai taihyomen no kassei no fukin`itsusei ni motozuku kankyo sonai nodo bunpu oyobi toka hanno sokudo teisu no ryusoku ni yoru henka

    Energy Technology Data Exchange (ETDEWEB)

    Konno, J [National Institute for Resources and Environment, Tsukuba (Japan)

    1997-09-25

    In a flow system for vapor/solid catalytic reactions, there is a concentration distribution along the external catalyst surface, observed in the vicinity of the surface. Change in the reaction rate constant is followed for the case where the concentration distribution varies by flow. A 2-dimensional numerical model in which flow field and property conditions are simplified is used to analyze the change on the assumption that high-activity and low-activity sites are regularly distributed over the external catalyst surface. The transport equations for the reactants are numerically solved for given flow fields. It is found that the concentration distribution shape and equivalent reaction rate constant are almost the same as those in a stationary system at Pecret number of around 10 or lower, the concentration distribution gradually becomes uniform whereas equivalent rate constant increases as flow rate increases at Pecret number in a range from around 10 to 10{sup 6}, and they are almost constant at Pecret number beyond around 10{sup 6}. 3 refs., 11 figs., 1 tab.

  10. FY 1999 report on the potential survey of the environmental friendly type coal utilization system. Survey on the spread/promotion of circulating fluidized bed boilers in China; 1999 nendo chosa hokoksho. Kankyo chowagata sekitan riyo system kanosei chosa. Chugoku ni okeru junkan yukaboira no fukyu sokushin ni kakawaru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    For the purpose of contributing to the spread/promotion of Japanese-make circulating fluidized bed boilers with desulfurization function, survey was conducted of the state of utilization of circulating fluidized bed boilers, the needs, etc. in China. In the survey, field survey was made at two boiler manufacturers and four companies using boilers in Beijing city, Fujian province, Hubei province, etc. to grasp the state of utilization and study conditions for the spread/promotion of circulating fluidized bed boilers. The Chinese government is making efforts for the spread of circulating fluidized bed boilers. The number of the domestically existing circulating fluidized bed boilers is estimated at approximately 800, but almost none of them conducts furnace desulfurization. Further, the operating rate of boiler is not always high. The reasons are as follows: desulfurization costs high without connecting to the production; environmental regulation is still mild in China; reliability and maintenance technique are still at low levels. It is urgently desirable to spread highly reliable circulating fluidized bed boilers with desulfurization function, and accordingly, it is necessary to reduce the cost of Japanese-make boilers. (NEDO)

  11. Project to support promotion of forming an environmentally friendly energy community. Survey report on 'a survey on introduction of an RDF electric power generation system utilizing general wastes in the Noto area'; Kankyo chowagata energy community keisei sokushin hojo jigyo. 'Noto chiiki ni okeru ippan haikibutsu riyo RDF hatsuden no donyu ni kansuru chosa' chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    A business feasibility survey was performed on introduction of an RDF electric power generation system utilizing general wastes in the Noto area. Wastes quantity was estimated by accounting for large-sized wastes to be generated newly as a result of enforcement of the container package recycling law, and transfer of non-combustible wastes to incineration. The quantity was estimated to be 84,000 tons annually. Quantities of RDF and heat were calculated from this estimation to be 103 tons per day and 400 lkcal/kg respectively. According to the result of discussing the RDF transportation systems, time-based freight was found advantageous for short distance, and distance freight system for long distance in terms of cost. Discussions for RDF power systems were carried out on an RDF circulation fluid bed furnace plus ash melting furnace, a fluid bed gasification melting furnace, and shaft furnace type gasification melting furnace. In a comprehensive view, it is difficult to distinguish them in terms of merit and demerit. Molten slag was assumed to be re-utilized, but cost for the re-utilization should be considered. According to the result of discussing the business feasibility, it was found difficult to make it profitable by operating the RDF power generation business alone, and wastes incineration charge should be collected. (NEDO)

  12. FY 1999 cooperation program - Comprehensive research cooperation in environmental technology. Research cooperation in toxic/hazardous waste management in the Laguna de Bay region; 1999 nendo kenkyu kyoryoku jigyo. Kankyo gijutsu sogo kenkyu kyoryoku - Raguna ko chiiki ni okeru yudoku yugai haikibutsu ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    For the purpose of establishing preventive measures for water contamination in the Laguna de Bay region, the Philippines, where the water contamination is in progress and the eutrophication is feared, a research cooperation project was carried out on the water quality contamination monitoring technology (measuring method/analysis method/prediction method). In the survey of the state of generation of toxic/hazardous waste, the following were grasped based on the existing data: amount of use of toxic/hazardous substances in factories, state of generation of waste, situation of the processing/disposal, etc. In the detailed survey of the situation of pollution in the Laguna de Bay region, specimens of water quality and bottom material were collected from the lake and rivers thereinto, and qualitative/quantitative analysis of contaminants was made using atomic absorption spectrophotometer and gaschromatograph mass spectrometer. As to the evaluation of pollutant sources and control method, the paper conducted the introduction of measures generally taken against pollutant sources, study of a method to grasp the behavior of contaminants by the environmental assessment method for the closed water area, etc. The training was also conducted for researchers/engineers widely in charge of management of toxic/hazardous waste in the Philippines. (NEDO)

  13. Study on the optium operation of the solar assisted air-source heat pump system. Part 5. ; Fundamental performance of a SOL-AIR PANEL effected by environmental condition that can be controlled artifically. SOL-AIR heat pump system no saiteki untenho ni kansuru kenkyu. 5. ; Jinko kankyo joken hendo ni uoru shuhonetsu panel no kiso tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Nakajima, Y; Ohashi, K; Kasuya, A [Kogauin Univ., Tokyo (Japan); Shiraishi, K; Hino, T [Kajima Institute of Construction Technology, Tokyo (Japan)

    1990-12-06

    This paper follows the privious paper which reports about the experimental system of the solar air panel and the experimental conditions in the artificial environmental room. In this paper the basic performance of heat exchange of a solar panel related to the difference of the artificial enviromental conditions such as the wind speed, the wind direction, the radiation, and the dry or wet surface of the solar air panel, and the results of its analysis are presented. As a result of the experiment, the following were determined: wind direction affects the heat exchange characteristics of the solar air panel; the slits lead to improved heat conduction on both sides of the panel; and when the flat surface of the panel is wet the amount of all the heat exchange increases, due to increased air circulation and evaporation. It is possible to estimate the total quantity of heat exchange, and to determine the fundamental performance of a solar air panel. 7 refs., 10 figs.

  14. Survey report in fiscal 1999 on investigations for the current status in energy and environmental problems in Japan and the U.S.A., and investigations on technological development related to energies; 1999 nendo Nichibei ni okeru energy kankyo mondai no genjo chosa oyobi energy ni kakawaru gijutsu kaihatsu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This paper reports the surveys in fiscal 1999 on energy and developmental problems in Japan and the U.S.A. New and complex environmental problems are rising to the surface, such as global warming, ozone layer destruction, and chemical harms. It is necessary to deepen quickly scientific understanding of the problems, and identify accurately their impacts on human bodies and ecological systems. Within the limitation of the scientific understanding, political decisions on economy and environmental risks are also important and difficult questions, with the environmental hormones being the typical examples. Establishing chemical substance verification systems is important, whereas joint researches by Japan and the U.S.A. are desired. Policy decisions on handling the researches must also be made jointly, and acceptance by citizens must be asked for at international workshops. While energies are the base of economic activities, and the sustained development thereof is indispensable, how to take balance with health and environment in the global scale is a large assignment. Joint Japan-U.S. discussions are required on technological innovation, such as for regenerative energies, energy conservation, safety of and wastes from nuclear reactors, clean use of fossil fuels, and fuel cells. International cooperation, including that from developing countries, is also important. (NEDO)

  15. FY 2000 research cooperation project on the comprehensive research cooperation for environmental technology. Research cooperation for technology for prevention of the water pollution caused by plant waste water in Vietnam; 2000 nendo kenkyu kyoryoku jigyo. Kankyo gijutsu sogo kenkyu kyoryoku (Betonamu koku kojo haisui ni yoru suishitsu osen boshi taisaku gijutsu ni kansuru kenkyu hokoku)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of increasing the research capability of the Center for Consultancy, Training and Technology Transfer in Vietnam, research cooperation for prevention of water pollution was given for plants of the local industry located in the suburbs of Hanoi city. In the survey of the actual state of the water pollution in the industrial area in the suburbs of Hanoi city, the following was found out: In the area, approximately 110 companies of the production industry such as livestock feed, papermaking, dyeing, brewing, construction materials, etc. are in operation and are discharging the untreated waste water into rivers and waterways because waste water treatment facilities are not prepared yet. In this research cooperation, the following were carried out: detailed survey of specified plants and proposal for improvement, training of Vietnamese researchers/engineers in charge of water pollution prevention technology, invitation to/training at Japan of Vietnamese managers/researchers, seminar to be held on the site, equipment to be given that is needed to measure water quality. The equipment to be given is a portable multi-item water quality meter and analytical equipment such as spectrometer, atomic absorption spectrophotometer and gas chromatograph. (NEDO)

  16. Investigation into the MgF2-NiF2, CaF2-NiF2, SrF2-NiF2 systems

    International Nuclear Information System (INIS)

    Ikrami, D.D.; Petrov, S.V.; Fedorov, P.P.; Ol'khovaya, L.A.; Luginina, A.A.; AN SSSR, Moscow. Inst. Fizicheskikh Problem; AN SSSR, Moscow. Inst. Kristallografii)

    1984-01-01

    Using the methods of differential thermal and X-ray phase analyses the systems MgF 2 -NiF 2 , CaF 2 -NiF 2 , SrF 2 -NiF 2 have been studied. In the system SrF 2 -NiF 2 the only orthorhombic compounds SrNiF 4 (a=14.43; b=3.93; c=5.66 (+-0.01 A)) is formed. SrNiF 4 density constitutes: dsub(X-ray)=4.60+-0.01 g/cm 3 , dsub(exp.)=4.60+-0.03 g/cm 3 . Refraction indices are as follows SrNiF 4 :Ng=1.500; Nsub(m)=1.497; Nsub(p)=1.479. SrNiF 4 magnetic ordering temperature Tsub(N) approximately 100 K

  17. Microstructure and mechanical properties of sputter deposited Ni/Ni{sub 3}Al multilayer films at elevated temperature

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Chao [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Feng, Kai, E-mail: fengkai@sjtu.edu.cn [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Li, Zhuguo, E-mail: lizg@sjtu.edu.cn [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Lu, Fenggui; Huang, Jian; Wu, Yixiong [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China)

    2016-08-15

    Highlights: • Ni/Ni{sub 3}Al multilayers are prepared by magnetron sputtering. • Both grain size and phase constitution of annealed Ni/Ni{sub 3}Al multilayers are dependent on individual layer thickness. • The hardness of annealed Ni/Ni{sub 3}Al multilayers varies with individual layer thickness and annealing temperature. • 40 nm Ni/Ni{sub 3}Al multilayer exhibits excellent hardness at elevated temperature. - Abstract: Nano-structured Ni/Ni{sub 3}Al multilayer was prepared by magnetron sputtering, with individual layer thicknesses h varying from 10 to 160 nm. The microstructure and hardness of Ni/Ni{sub 3}Al multilayer were investigated by X-ray diffraction, transmission electron microscopy and nanoindentation. The results show that the hardness increases with decreasing h for as-deposited and 500 °C annealed multilayers. When annealed at 700 °C, the hardness approach a peak value at h = 40 nm with followed by softening at smaller h. The influence of individual layer thickness, grain size as well as formation of ordered Ni{sub 3}Al on strengthening mechanisms of Ni/Ni{sub 3}Al multilayers at elevated temperature are discussed.

  18. Enhanced Electrocatalytic Activity for Water Splitting on NiO/Ni/Carbon Fiber Paper

    Directory of Open Access Journals (Sweden)

    Ruoyu Zhang

    2016-12-01

    Full Text Available Large-scale growth of low-cost, efficient, and durable non-noble metal-based electrocatalysts for water splitting is crucial for future renewable energy systems. Atomic layer deposition (ALD provides a promising route for depositing uniform thin coatings of electrocatalysts, which are useful in many technologies, including the splitting of water. In this communication, we report the growth of a NiO/Ni catalyst directly on carbon fiber paper by atomic layer deposition and report subsequent reduction and oxidation annealing treatments. The 10–20 nm NiO/Ni nanoparticle catalysts can reach a current density of 10 mA·cm−2 at an overpotential of 189 mV for hydrogen evolution reactions and 257 mV for oxygen evolution reactions with high stability. We further successfully achieved a water splitting current density of 10 mA·cm−2 at 1.78 V using a typical NiO/Ni coated carbon fiber paper two-electrode setup. The results suggest that nanoparticulate NiO/Ni is an active, stable, and noble-metal-free electrocatalyst, which facilitates a method for future water splitting applications.

  19. Ni(salen): a system that forms many solvates with interacting Ni atoms

    NARCIS (Netherlands)

    Siegler, M.A.M.; Lutz, M.

    2009-01-01

    Recrystallization of [N,N’-Ethylene-bis(salicylideneiminato)]-nickel(II) [Ni(salen)] has been carried out from a large selection of solvents. Crystals can be either solvent free or solvates. This study is based on X-ray crystal structure determinations, which include the redetermination of Ni(salen)

  20. Thermal stability of electrodeposited Ni and Ni-Co layers; an EBSD-study

    DEFF Research Database (Denmark)

    Rasmussen, Anette Alsted; Gholinia, A.; Trimby, P.W.

    2004-01-01

    The influence of heat treatment on the microstructure and the microtexture of electrodeposited Ni and Ni-Co layers was investigated with Electron Backscatter Diffraction (EBSD) with high resolution. Samples were annealed for 1 hour at 523 K and 673 K, the temperature region wherein...

  1. The role of Ni in sulfided carbon-supported Ni-Mo hydrodesulfurization catalysts

    NARCIS (Netherlands)

    Bouwens, S.M.A.M.; Barthe-Zahir, N.; Beer, de V.H.J.; Prins, R.

    1991-01-01

    The thiophene hydrodesulfurization activities of Ni and Ni---Mo sulfide catalysts supported on activated carbon were measured at atmospheric pressure and the catalyst structures were studied by means of X-ray photoelectron spectroscopy, dynamic oxygen chemisorption, and chemical sulfur analysis. The

  2. Mechanical properties of NiO/Ni-YSZ composites depending on temperature, porosity and redox cycling

    DEFF Research Database (Denmark)

    Pihlatie, Mikko; Kaiser, Andreas; Mogensen, Mogens Bjerg

    2009-01-01

    The Impulse Excitation Technique (IET) was used to determine the elastic modulus and specific damping of different Ni/NiO-YSZ composites suitable for use in solid oxide fuel cells (SOFC). The porosity of the as-sintered samples varied from 9 to 38% and that of the reduced ones from 31 to 52%. For...

  3. Climate Prediction Center - El Niño/La Niña Home

    Science.gov (United States)

    Weather Service NWS logo - Click to go to the NWS home page Climate Prediction Center Site Map News Information CPC Web Team HOME > El Niño/La Niña Forecasts Current U.S. Climate Outlook SST Forecasts Temperature and Anomalies NOAA/ National Weather Service National Centers for Environmental Prediction Climate

  4. Synthesis and magnetic properties of multilayer Ni/Cu and NiFe/Cu ...

    Indian Academy of Sciences (India)

    The diameter of wires can be easily varied by pore size of alumina, ranging ... saturated HgCl2 solution to remove the remaining Al, and then dipped in 5 wt% ... for NiFe alloy it is 1.3 V, that is higher than for Ni/Cu nanowires to diminish Cu.

  5. Effect of solute atoms on swelling in Ni alloys and pure Ni under He + ion irradiation

    Science.gov (United States)

    Wakai, E.; Ezawa, T.; Imamura, J.; Takenaka, T.; Tanabe, T.; Oshima, R.

    2002-12-01

    The effects of solute atoms on microstructural evolutions have been investigated using Ni alloys under 25 keV He + irradiation at 500 °C. The specimens used were pure Ni, Ni-Si, Ni-Co, Ni-Cu, Ni-Mn and Ni-Pd alloys with different volume size factors. The high number densities of dislocation loops about 1.5×10 22 m -3 were formed in the specimens irradiated to 1×10 19 ions/m 2, and they were approximately equivalent, except for Ni-Si. The mean size of loops tended to increase with the volume size factor of solute atoms. In a dose of 4×10 20 ions/m 2, the swelling was changed from 0.2% to 4.5%, depending on the volume size factors. The number densities of bubbles tended to increase with the absolute values of the volume size factor, and the swelling increased with the volume size factors. This suggests that the mobility of helium and vacancy atoms may be influenced by the interaction of solute atoms with them.

  6. Bonding Strength of Ni/Ni3Al Interface with Different Lattice Misfit

    Institute of Scientific and Technical Information of China (English)

    Ping PENG; Caixing ZHENG; Shaochang HAN; Zhaohui JIN; Rui YANG; Zhuangqi HU

    2003-01-01

    The interfacial binding covalent bond density (CBD) and the local environmental total bond order (LTBO) of the Ni/Ni3Alinterface with different lattice misfits (δ) were calculated by using first-principles discrete variation Xα method. It was foundthat

  7. Electrochemical Behaviour of Ni and Ni-PVC Electrodes for the Electroxidation of Ethanol

    International Nuclear Information System (INIS)

    Mohd Syafiq Hamdan; Norazzizi Nordin; Siti Fathrita Mohd Amir; Riyanto; Mohamed Rozali Othman

    2011-01-01

    In this study, two nickel based electrodes were prepared; nickel foil and nickel-polyvinylchloride (Ni-PVC), in order to study their electrochemical behavior using cyclic voltammetry, CV and chronocoulometry, CC. Ni electrode was prepared from Ni metal foil while Ni-PVC electrode was prepared by mixing a weighed portion of Ni powder and PVC in THF solvent, swirled until the suspension was homogeneous and drying the suspension in an oven at 50 degree Celsius for 3 h. The dry sample was then placed in a 1 cm diameter stainless steel mould and pressed at 10 ton/ cm 2 . From CV data, Ni-PVC electrode showed a better electrochemical behavior compared to Ni metal foil electrode. The use of Ni-PVC electrode at higher concentration of supporting electrolyte (1.0 M KOH) was better than at lower concentration of the same supporting electrolyte in electroxidation of ethanol. In addition to acetic acid, the oxidation of ethanol also produced ethyl acetate and acetaldehyde. (author)

  8. Room-temperature ferromagnetism in Dy films doped with Ni

    Energy Technology Data Exchange (ETDEWEB)

    Edelman, I. [Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036 (Russian Federation)], E-mail: ise@iph.krasn.ru; Ovchinnikov, S. [Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036 (Russian Federation); Siberian Federal University, Av. Svobodnyi 71, Krasnoyarsk 660074 (Russian Federation); Markov, V.; Kosyrev, N.; Seredkin, V.; Khudjakov, A.; Bondarenko, G. [Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036 (Russian Federation); Kesler, V. [Institute of Semiconductor Physics, Siberian Division, Russian Academy of Sciences, Av. Akademika Lavrent' eva 13, Novosibirsk 630090 (Russian Federation)

    2008-09-01

    Temperature, magnetic field and spectral dependences of magneto-optical effects (MOEs) in bi-layer films Dy{sub (1-x)}Ni{sub x}-Ni and Dy{sub (1-x)}(NiFe){sub x}-NiFe were investigated, x changes from 0 to 0.06. Peculiar behavior of the MOEs was revealed at temperatures essentially exceeding the Curie temperature of bulk Dy which is explained by the magnetic ordering of the Dy layer containing Ni under the action of two factors: Ni impurities distributed homogeneously over the whole Dy layer and atomic contact of this layer with continues Ni layer. The mechanism of the magnetic ordering is suggested to be associated with the change of the density of states of the alloy Dy{sub (1-x)}Ni{sub x} owing to hybridization with narrow peaks near the Fermi level character for Ni.

  9. Room-temperature ferromagnetism in Dy films doped with Ni

    International Nuclear Information System (INIS)

    Edelman, I.; Ovchinnikov, S.; Markov, V.; Kosyrev, N.; Seredkin, V.; Khudjakov, A.; Bondarenko, G.; Kesler, V.

    2008-01-01

    Temperature, magnetic field and spectral dependences of magneto-optical effects (MOEs) in bi-layer films Dy (1-x) Ni x -Ni and Dy (1-x) (NiFe) x -NiFe were investigated, x changes from 0 to 0.06. Peculiar behavior of the MOEs was revealed at temperatures essentially exceeding the Curie temperature of bulk Dy which is explained by the magnetic ordering of the Dy layer containing Ni under the action of two factors: Ni impurities distributed homogeneously over the whole Dy layer and atomic contact of this layer with continues Ni layer. The mechanism of the magnetic ordering is suggested to be associated with the change of the density of states of the alloy Dy (1-x) Ni x owing to hybridization with narrow peaks near the Fermi level character for Ni

  10. Elementary martensitic transformation processes in Ni-rich NiTi single crystals with Ni4Ti3 precipitates

    International Nuclear Information System (INIS)

    Michutta, J.; Somsen, Ch.; Yawny, A.; Dlouhy, A.; Eggeler, G.

    2006-01-01

    The present study shows that multiple-step martensitic transformations can be observed in aged Ni-rich NiTi single crystals. Ageing of solution-annealed and water-quenched Ni-rich NiTi single crystals results in a homogeneous precipitation of coherent Ni 4 Ti 3 particles. When the interparticle spacing reaches a critical value (order of magnitude: 200 nm), three distinct transformation processes are observed on cooling from the high-temperature phase using differential scanning calorimetry and in situ transmission electron microscopy. The transformation sequence begins with the formation of R-phase starting from all precipitate/matrix interfaces (first step). The transformation continues with the formation of B19' and its subsequent growth along all precipitate/matrix interfaces (second step). Finally, the matrix in between the precipitates transforms to B19' (third step). Elementary transformation mechanisms which account for two- and three-step transformations in a system with small-scale microstructural heterogeneities were identified

  11. Probing the semi-magicity of $^{68}$Ni via the $^{3}$H($^{66}$Ni,$^{68}$Ni)p two-neutron transfer reaction in inverse kinematics

    CERN Multimedia

    Reiter, P; Blazhev, A A; Kruecken, R; Franchoo, S; Mertzimekis, T; Darby, I G; Van de walle, J; Raabe, R; Elseviers, J; Gernhaeuser, R A; Sorlin, O H; Georgiev, G P; Bree, N C F; Habs, D; Chapman, R; Gaudefroy, L; Diriken, J V J; Jenkins, D G; Kroell, T; Axiotis, M; Huyse, M L; Patronis, N

    We propose to perform the two-neutron transfer reaction $^{3}$H($^{66}$Ni, $^{68}$Ni)$p$ using the ISOLDE radioactive ion beam at 2.7 $A$ MeV and the MINIBALL + T-REX setup to characterize the 0$^{+}$ and 2$^{+}$ states in $^{68}$Ni.

  12. Mechanical alloying of the FeNi-Ag system

    International Nuclear Information System (INIS)

    Gonzalez, G.; Ibarra, D.; Ochoa, J.; Villalba, R.; Sagarzazu, A.

    2007-01-01

    The Fe-Ni-Ag system is of particular interest for its potential applications as soft magnetic granular material with small magnetic grains embedded in a non-magnetic metal matrix. Under equilibrium conditions: Fe-Ag and Ni-Ag are immiscible and Fe-Ni shows complete solubility. These materials are particularly important for magnetoresistivity properties. The properties of these alloys are closely related to their microstructure; therefore, a detailed study of the transformations occurring during milling was undertaken using pre-alloyed Fe x Ni 100-x (x = 30, 50 and 70) further milled with different Ag content to give the following alloys compositions (Fe x -Ni 100-x ) 100-y Ag y (y = 5, 20, 60). Consolidation of the mechanically alloyed powders by sintering at 950 o C was performed. Morphological and structural characterization of the sintered powders was carried out by scanning and transmission electron microscopy and X-ray diffraction. Fe 30 Ni 70 and Fe 50 Ni 50 formed ordered FeNi 3 compound. Fe 70 Ni 30 showed the formation of a mixture of γ-(Fe,Ni) and α-Fe(Ni) solid solutions. The mixture of these systems with Ag showed the metal solid solutions surrounded by Ag islands of Fe x Ni y -Ag, There was also evidence of Ag diffusing into the γ-(Fe,Ni). High Ag content (60%) shows formation of islands of FeNi surrounded by Ag. Sintering is always improved with the Ag content

  13. Effect of amount of glycine as fuel in obtaining nanocomposite Ni/NiO

    International Nuclear Information System (INIS)

    Simoes, A.N.; Simoes, V.N.; Neiva, L.S.; Quirino, M.R.; Vieira, D.A.; Gama, L.

    2010-01-01

    This paper proposes to investigate the effect of the amount of glycine in obtaining nanocomposite Ni/NiO synthesized by combustion reaction technique. The amount of glycine used was calculated on the stoichiometric composition of 50% and 100%. Characterizations by X-ray diffraction (XRD), N2 adsorption by the BET method and scanning electron microscopy (SEM) were performed with powder of Ni/NiO result. The analysis of X-ray diffraction showed the presence of crystalline NiO phase in the presence of nickel as a secondary phase, whose amount increased with the amount of glycine. Increasing the concentration of glycine also caused an increase in surface area, which ranged from 1.1 to 1.4 m 2 /g. The micrographs revealed the formation of soft agglomerates with porous appearance and easy dispersions. It can be concluded that the synthesis is effective to obtain nanosized powders. (author)

  14. Neutron enrichment at midrapidity in 58Ni + 58Ni at 52 MeV/u

    International Nuclear Information System (INIS)

    Theriault, D.; Vallee, A.; Gingras, L.; Larochelle, Y.; Roy, R.; April, A.; Beaulieu, L.; Grenier, F.; Lemieux, F.; Moisan, J.; Samri, M.; Saint-Pierre, C.; Turbide, S.; Yennello, S.J.; Martin, E.; Winchester, E.

    2003-01-01

    By combining data from a charged particle 58 Ni + 58 Ni experiment at 52 MeV/u with an 36 Ar + 58 Ni experiment at 50 MeV/u for which free neutrons have been detected, an increase in the neutron to proton ratio of the whole nuclear material at midrapidity has been experimentally observed in the reaction 58 Ni + 58 Ni at 52 MeV/u. The neutron to proton ratio is measured above the initial neutron to proton ratio of the system. Neutron to proton ratio of the quasi-projectile emission is analysed for the same reactions and is seen to decrease below the ratio of the initial system. (authors)

  15. Improvement of thermoelectric properties for half-Heusler TiNiSn by interstitial Ni defects

    International Nuclear Information System (INIS)

    Hazama, Hirofumi; Matsubara, Masato; Asahi, Ryoji; Takeuchi, Tsunehiro

    2011-01-01

    We have synthesized off-stoichiometric Ti-Ni-Sn half-Heusler thermoelectrics in order to investigate the relation between randomly distributed defects and thermoelectric properties. A small change in the composition of Ti-Ni-Sn causes a remarkable change in the thermal conductivity. An excess content of Ni realizes a low thermal conductivity of 2.93 W/mK at room temperature while keeping a high power factor. The low thermal conductivity originates in the defects generated by an excess content of Ni. To investigate the detailed defect structure, we have performed first-principles calculations and compared with x ray photoemission spectroscopy measurement. Based on these analyses, we conclude that the excess Ni atoms randomly occupy the vacant sites in the half-Heusler structure, which play as phonon scattering centers, resulting in significant improvement of the figure of merit without any substitutions of expensive heavy elements, such as Zr and Hf.

  16. Magnetoresistance of nanogranular Ni/NiO controlled by exchange anisotropy

    International Nuclear Information System (INIS)

    Del Bianco, L.; Spizzo, F.; Tamisari, M.; Allia, P.

    2013-01-01

    A link between exchange anisotropy and magnetoresistance has been found to occur in a Ni/NiO sample consisting of Ni nanocrystallites (mean size ∼13 nm, Ni content ∼33 vol%) dispersed in a NiO matrix. This material shows metallic-type electric conduction and isotropic spin-dependent magnetoresistance as well as exchange bias effect. The latter is the outcome of an exchange anisotropy arising from the contact interaction between the Ni phase and the NiO matrix. Combined analysis of magnetization M(H) and magnetoresistance MR(H) loops measured in the 5–250 K temperature range after zero-field-cooling (ZFC) and after field-cooling (FC) from 300 K reveals that the magnetoresistance is influenced by exchange anisotropy, which is triggered by the FC process and can be modified in strength by varying the temperature. Compared to the ZFC case, the exchange anisotropy produces a horizontal shift of the FC MR(H) loop along with a reduction of the MR response associated to the reorientation of the Ni moments. A strict connection between magnetoresistance and remanent magnetization of FC loops on one side and the exchange field on the other, ruled by exchange anisotropy, is indicated. - Highlights: • Nanogranular Ni/NiO with giant magnetoresistance (MR) and exchange bias effect. • Exchange anisotropy produces a shift of the field-cooled MR(H) loop and reduces MR. • MR, remanence of field-cooled loops and exchange field are three correlated quantities. • It is possible to control MR of nanogranular systems through the exchange anisotropy

  17. Ferromagnetic resonance study of sputtered NiFe/V/NiFe heterostructures

    Energy Technology Data Exchange (ETDEWEB)

    Alayo, W., E-mail: willian.rodriguez@ufpel.edu.br [Departamento de Física – IFM, Universidade Federal de Pelotas, 96010-900 Rio Grande do Sul (Brazil); Pelegrini, F. [Instituto de Física, Universidade Federal de Goiás, Goiânia, 74001-970 (Brazil); Baggio-Saitovitch, E. [Centro Brasileiro de Pesquisas Físicas, Rio de Janeiro, RJ, 22290-180 (Brazil)

    2015-03-01

    The Ni{sub 81}Fe{sub 19}/V/Ni{sub 81}Fe{sub 19} heterostructures has been produced by magnetron sputtering and analyzed by ferromagnetic resonance. Two systems were investigated: the non symmetrical NiFe(50 Å)/V(t)/NiFe(30 Å) trilayers and the symmetrical NiFe(80 Å)/V(t)/NiFe(80 Å) trilayers, with variable ultrathin V thickness t. Ferromagnetic exchange coupling was evidenced for t below 10 Å by the excitation of the optic mode, in the case of the non symmetrical samples, and by the observation of a single resonance mode for the symmetrical trilayers. For larger V thickness, all samples exhibited two modes, which were attributed to the resonance of the individual NiFe layers with different effective magnetizations. The analysis with the equilibrium and resonance conditions provided the exchange coupling constants and effective magnetizations. - Highlights: • We present a study of symmetrical and non symmetrical NiFe/V/NiFe trilayers deposited on Si single crystals by ferromagnetic resonance (FMR) at room temperature. • For the non symmetrical trilayers, the FMR spectra show the optic and acoustic modes for samples with very thin V layer thicknesses, evidencing ferromagnetic exchange coupling, whereas, for larger V thickness, the spectra exhibited two well resolved modes associated to each independent NiFe layer. For the symmetrical trilayers, strong ferromagnetic exchange coupling is evidenced by the observation of a single resonance mode. • The analysis with the equilibrium condition and dispersion relation provides the exchange coupling constants and effective magnetizations.

  18. Hydrogen absorption kinetics and structural properties of Mg85Ni10Ca5 and Mg90Ni10

    International Nuclear Information System (INIS)

    Aoki, Masakazu; Saito, Katsushi; Towata, Shin-ichi

    2005-01-01

    Mg 85 Ni 10 Ca 5 and Mg 90 Ni 10 were prepared by melting mixtures of the elements in mild steel crucibles and pouring them into copper molds. Hydrogen absorption kinetics and structural properties of the alloys were characterized by the volumetric method using a Sievert's apparatus, X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The crystallite size of Mg in Mg 85 Ni 10 Ca 5 , which is evaluated by XRD peak broadening, is about 50% smaller than that in Mg 90 Ni 10 . In addition, the nanometer-scale structure composed of Mg, Mg 2 Ni, Mg 2 Ca was observed in Mg 85 Ni 10 Ca 5 . Mg 85 Ni 10 Ca 5 shows better hydrogen absorption kinetics than Mg 90 Ni 10 in the temperature range of room temperature to 573 K. The better absorption kinetics of Mg 85 Ni 10 Ca 5 is mainly attributed to the nanometer-scale structure

  19. Sputtering Yields of Si and Ni from the Ni1-xSix System Studied by Rutherford Backscattering Spectrometry

    Science.gov (United States)

    Kim, Su Chol; Yamaguchi, Satoru; Kataoka, Yoshihide; Iwami, Motohiro; Hiraki, Akio; Satou, Mamoru; Fujimoto, Fuminori

    1982-01-01

    Sputtering yields of Si and Ni from thin layer films of Ni-Si compounds (Ni1-xSix), including the pure materials (Ni and Si), caused by 5 keV Ar+ ion bombardment were investigated using backscattering spectrometry. The sputtering yield for Si from Ni1-xSix increased with increasing Si concentration. However, there is an abrupt decrease in the yield for Si concentrations above NiSi2 to pure Si. This is in clear contrast to the sputtering yield of Ni from Ni1-xSix which increased with increasing Ni concentration monotonously. These results are discussed on the basis of both the difference in the atomic density and the electronic state of the alloy.

  20. Phase Equilibria of the Sn-Ni-Si Ternary System and Interfacial Reactions in Sn-(Cu)/Ni-Si Couples

    Science.gov (United States)

    Fang, Gu; Chen, Chih-chi

    2015-07-01

    Interfacial reactions in Sn/Ni-4.5 wt.%Si and Sn-Cu/Ni-4.5 wt.%Si couples at 250°C, and Sn-Ni-Si ternary phase equilibria at 250°C were investigated in this study. Ni-Si alloys, which are nonmagnetic, can be regarded as a diffusion barrier layer material in flip chip packaging. Solder/Ni-4.5 wt.%Si interfacial reactions are crucial to the reliability of soldered joints. Phase equilibria information is essential for development of solder/Ni-Si materials. No ternary compound is present in the Sn-Ni-Si ternary system at 250°C. Extended solubility of Si in the phases Ni3Sn2 and Ni3Sn is 3.8 and 6.1 at.%, respectively. As more Si dissolves in these phases their lattice constants decrease. No noticeable ternary solubility is observed for the other intermetallics. Interfacial reactions in solder/Ni-4.5 wt.%Si are similar to those for solder/Ni. Si does not alter the reaction phases. No Si solubility in the reaction phases was detected, although rates of growth of the reaction phases were reduced. Because the alloy Ni-4.5 wt.%Si reacts more slowly with solders than pure Ni, the Ni-4.5 wt.%Si alloy could be a potential new diffusion barrier layer material for flip chip packaging.

  1. Evaluation for membrane components of water recycling system. Mizu saisei junkan system yoso no tokusei hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Tanemura, T; Otsubo, K; Oguchi, M [National Aerospace Laboratory, Tokyo (Japan); Ashida, A; Hamano, N; Mitani, K [Hitachi, Ltd., Tokyo (Japan)

    1992-04-01

    The configuration of water recycling systems with membrane filters was studied to purify waste water discharged from human beings, animals and plants which is a key subsystem for closed ecological life support systems (CELSS) essential to long-term manned space activity. The filter performance test apparatus with three kinds of filters such as pre-filter, reverse osmosis membrane filter and ultra membrane filter was fabricated to conduct long-term cycling high-concentration tests using artificial urine as original waste water. As a result, since every membrane filter offered their nominal performance incompletely in high-concentration tests, it was necessary to add an NaCl removing apparatus to the system as primary treated water should be used for vegetation. It was also required to test the membrane performance preliminarily because the performance such as membrane life was different between various waste waters. 7 refs., 32 figs., 9 tabs.

  2. Ni/boride interfaces and environmental embrittlement in Ni-based superalloys: A first-principles study

    International Nuclear Information System (INIS)

    Sanyal, Suchismita; Waghmare, Umesh V.; Hanlon, Timothy; Hall, Ernest L.

    2011-01-01

    Highlights: ► Fracture strengths of Ni/boride interfaces through first-principles calculations. ► Fracture strengths of Ni/boride interfaces are higher than Ni/Ni 3 Al and NiΣ5 grain boundaries. ► Ni/boride interfaces have higher resistance to O-embrittlement than Ni/Ni 3 Al and NiΣ5 grain boundaries. ► CrMo-borides are more effective than Cr-borides in resisting O-embrittlement. ► Electronegativity differences between alloying elements correlate with fracture strengths. - Abstract: Motivated by the vital role played by boride precipitates in Ni-based superalloys in improving mechanical properties such as creep rupture strength, fatigue crack growth rates and improved resistance towards environmental embrittlement , we estimate fracture strength of Ni/boride interfaces through determination of their work of separation using first-principles simulations. We find that the fracture strength of Ni/boride interfaces is higher than that of other commonly occurring interfaces in Ni-alloys, such as Ni Σ-5 grain boundaries and coherent Ni/Ni 3 Al interfaces, and is less susceptible to oxygen-induced embrittlement. Our calculations show how the presence of Mo in Ni/M 5 B 3 (M = Cr, Mo) interfaces leads to additional reduction in oxygen-induced embrittlement. Through Electron-Localization-Function based analyses, we identify the electronic origins of effects of alloying elements on fracture strengths of these interfaces and observe that chemical interactions stemming from electronegativity differences between different atomic species are responsible for the trends in calculated strengths. Our findings should be useful towards designing Ni-based alloys with higher interfacial strengths and reduced oxygen-induced embrittlement.

  3. Nickel distribution and isotopic fractionation in a Brazilian lateritic regolith: Coupling Ni isotopes and Ni K-edge XANES

    Science.gov (United States)

    Ratié, G.; Garnier, J.; Calmels, D.; Vantelon, D.; Guimarães, E.; Monvoisin, G.; Nouet, J.; Ponzevera, E.; Quantin, C.

    2018-06-01

    Ultramafic (UM) rocks are known to be nickel (Ni) rich and to weather quickly, which makes them a good candidate to look at the Ni isotope systematics during weathering processes at the Earth's surface. The present study aims at identifying the Ni solid speciation and discussing the weathering processes that produce Ni isotope fractionation in two deep laterite profiles under tropical conditions (Barro Alto, Goiás State, Brazil). While phyllosilicates and to a lower extent goethite are the main Ni-bearing phases in the saprolitic part of the profile, iron (Fe) oxides dominate the Ni budget in the lateritic unit. Nickel isotopic composition (δ60Ni values) has been measured in each unit of the regolith, i.e., rock, saprock, saprolite and laterite (n = 52). δ60Ni varies widely within the two laterite profiles, from -0.10 ± 0.05‰ to 1.43 ± 0.05‰, showing that significant Ni isotope fractionation occurs during the weathering of UM rocks. Overall, our results show that during weathering, the solid phase is depleted in heavy Ni isotopes due to the preferential sorption and incorporation of light Ni isotopes into Fe oxides; the same mechanisms likely apply to the incorporation of Ni into phyllosilicates (type 2:1). However, an isotopically heavy Ni pool is observed in the solid phase at the bottom of the saprolitic unit. This feature can be explained by two hypotheses that are not mutually exclusive: (i) a depletion in light Ni isotopes during the first stage of weathering due to the preferential dissolution of light Ni-containing minerals, and (ii) the sorption or incorporation of isotopically heavy Ni carried by percolating waters (groundwater samples have δ60Ni of 2.20 and 2.27‰), that were enriched in heavy Ni isotopes due to successive weathering processes in the overlying soil and laterite units.

  4. The acceleration intermediate phase (NiS and Ni3S2) evolution by nanocrystallization in Li/NiS2 thermal batteries with high specific capacity

    Science.gov (United States)

    Jin, Chuanyu; Zhou, Lingping; Fu, Licai; Zhu, Jiajun; Li, Deyi; Yang, Wulin

    2017-06-01

    The intermediate phase of NiS2 is thought to be a bottleneck currently to improve the overall performance of Li/NiS2 thermal batteries because of its low conductivity and close formation enthalpy between NiS2 and the intermediate phase (NiS, Ni3S2, etc). For improving the discharge performances of Li/NiS2 thermal batteries, the nano NiS2 with an average size of 85 ± 5 nm is designated as a cathode material. The electrochemical measurements show that the specific capacity of nano NiS2 cathode is higher than micro NiS2. The nano NiS2 cathode exhibits excellent electrochemical performances with high specific capacities of 794 and 654 mAh g-1 at current density of 0.1 and 0.5 A cm-2 under a cut-off voltage of 0.5 V, respectively. These results show that the rapid intermediate phase evolution from the nanocrystallization can obviously enhance use efficiency of NiS2 and improve discharge performances of thermal batteries.

  5. Room temperature isotherms for Mo and Ni

    International Nuclear Information System (INIS)

    Masse, J.L.

    1986-11-01

    Isotherms at room temperature for Mo and Ni are proposed. They are of three types: BIRCH, KEANE and BORN-MIE. The adjustable constants appearing in these isotherms have been determined from experimental quantities at zero pressure. An evaluation of the limit of (δB T /δP) T as P #-> # ∞, where B T is the isothermal bulk modulus, has been also used. These three isotherms obtained for Mo and Ni are compared with isotherms derived from shock-wave data according to the PRIETO's model. There is a good agreement between these and these derived from shock-wave data. The three isotherms proposed for Mo and Ni can be considered as valid until pressures of several B To , where B To is the bulk modulus B T at P = o [fr

  6. Advances in developing TiNi nanoparticles

    International Nuclear Information System (INIS)

    Castro, A. Torres; Cuellar, E. Lopez; Mendez, U. Ortiz; Yacaman, M. Jose

    2006-01-01

    The elaboration of nanoparticles has become a field of great interest for many scientists. Nanoparticles possess different properties than those ones shown in bulk materials. Shape memory alloys have the exceptional ability to recuperate its original shape by simple heating after being 'plastically' deformed. When this process is originated, important changes in properties, as mechanical and electrical, are developed in bulk material. If there is possible to obtain nanoparticles with shape memory effects, these nanoparticles could be used in the elaboration of nanofluids with the ability to change their electrical and thermal conductivity with temperature changes, i.e., smart nanofluids. In this work, some recent results and discussion of TiNi nanoparticles obtained by ion beam milling directly from a TiNi wire with shape memory are presented. The nanoparticles obtained by this process are about 2 nm of diameter with a composition of Ti-41.0 at.% Ni. Synthesized nanoparticles elaborated by this method have an ordered structure

  7. Cutting NiTi with Femtosecond Laser

    Directory of Open Access Journals (Sweden)

    L. Quintino

    2013-01-01

    Full Text Available Superelastic shape memory alloys are difficult to machine by thermal processes due to the facility for Ti oxidation and by mechanical processes due to their superelastic behavior. In this study, femtosecond lasers were tested to analyze the potential for machining NiTi since femtosecond lasers allow nonthermal processing of materials by ablation. The effect of processing parameters on machining depth was studied, and material removal rates were computed. Surfaces produced were analyzed under SEM which shows a resolidified thin layer with minimal heat affected zones. However, for high cutting speeds, that is, for short interaction times, this layer was not observed. A depletion of Ni was seen which may be beneficial in biomedical applications since Ni is known to produce human tissue reactions in biophysical environments.

  8. La niña proletaria

    Directory of Open Access Journals (Sweden)

    Cartabia, Sabrina A.

    2011-12-01

    Full Text Available El presente trabajo se propone trazar un paralelo entre el cuento de Osvaldo Lamborghini “El niño proletario”, el cual, según la autora del ensayo, introduce al lector en la lucha de clases y el sometimiento de los/as proletarios/as, que sufren las mujeres, en particular a través de la violencia sexual. De esa forma la autora se pregunta si el poder que ciertas clases detentan sobre otras no influye también sobre el sometimiento de la mujer. El ensayo analiza además cómo la violencia sexual es una herramienta que constituye la base de la desigualdad, el sometimiento y la degradación de la mujer, al igual que constituye una herramienta de opresión de otros grupos vulnerables como los niños y niñas.

  9. Effects of phase transformation and interdiffusion on the exchange bias of NiFe/NiMn

    International Nuclear Information System (INIS)

    Lai, Chih-Huang; Lien, W. C.; Chen, F. R.; Kai, J. J.; Mao, S.

    2001-01-01

    The correlation between the exchange field of NiFe/NiMn and the phase transformation of NiMn was investigated. Transmission electron microscopy (TEM) dark-field images, contributed by the order phase of NiMn, were used to identify the location and volume fraction of the order phase. TEM selected area diffraction patterns showed the (110) superlattice diffraction rings of NiMn, verifying the existence of the order phase in the annealed samples. The order volume fraction can be calculated by the dark field image contributed by the (110) diffraction. The exchange field increased almost linearly with increasing order volume fraction. Energy dispersive x-ray spectroscopy attached to TEM indicated that Mn diffused into NiFe for annealing at 280 degreeC, leading to a larger coercivity and small coercivity squareness. Part of the NiMn still maintains the paramagnetic phase even after annealing at 280 degreeC. [copyright] 2001 American Institute of Physics

  10. Ni3Si2 nanowires grown in situ on Ni foam for high-performance supercapacitors

    Science.gov (United States)

    Jiang, Yizhe; Li, Zhihui; Li, Beibei; Zhang, Jinying; Niu, Chunming

    2016-07-01

    Ni3Si2 nanowires and nanoawls have grown in situ on the surface of Ni foams by a controlled low pressure chemical vapor deposition process. Structural characterization shows that the individual Ni3Si2 nanowire is single crystal covered with a thin layer (1-2 nm) of SiO2 with a diameter of ∼20-30 nm and length of ten's micrometers. Individual nanoawl with a circular cone shape is polycrystalline. Both Ni3Si2 nanowire and nanoawl samples are evaluated as potential electrode materials for supercapacitors. The nanowire electrode delivers a very high specific capacitance and excellent rate capability. A specific capacitance of 760 F g-1 is measured at current density of 0.5 A g-1, which decreases to 518 F g-1 when the current density increases to 10 A g-1. The capacitance is dominated by pseudocapacitance with a mechanism similar to that of NiO or Ni(OH)2 widely studied in the literature. An asymmetric supercapacitor fabricated by pairing Ni3Si2 nanowire electrode with an activated carbon electrode exhibits energy densities of 17.5 Wh kg-1 and 8.8 Wh kg-1 at power densites of 301 W kg-1 and 3000 W kg-1.

  11. Exchange bias in finite sized NiO nanoparticles with Ni clusters

    Energy Technology Data Exchange (ETDEWEB)

    Gandhi, Ashish Chhaganlal; Lin, Jauyn Grace, E-mail: jglin@ntu.edu.tw

    2017-02-15

    Structural and magnetic properties of finite sized NiO nanoparticles are investigated with synchrotron X-ray diffraction (XRD), transmission electron microscopy, magnetometer and ferromagnetic resonance (FMR) spectroscopy. A minor Ni phase is detected with synchrotron XRD, attributed to the oxygen defects in the NiO core. A considerable exchange bias of ~100 Oe is observed at 50 K and it drops abruptly and vanishes above 150 K, in association with the reduction of frozen spins. FMR data indicate a strong interaction between ferromagnetic (FM) and antiferromagnetic (AFM) phases below 150 K, consistent with the picture of isolated FM clusters in AFM matrix. - Highlights: • Structural and magnetic properties of finite sized NiO nanoparticles are systematically investigated with several advanced techniques. • A strong interaction between ferromagnetic and antiferromagnetic phases is found below 150 K. • Exchange bias field in finite sized NiO nanoparticles is due to anisotropy energy of Ni clusters over riding the domain wall energy of NiO.

  12. Radiation damage buildup and dislocation evolution in Ni and equiatomic multicomponent Ni-based alloys

    Energy Technology Data Exchange (ETDEWEB)

    Levo, E. [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Granberg, F., E-mail: fredric.granberg@helsinki.fi [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Fridlund, C.; Nordlund, K. [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Djurabekova, F. [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Helsinki Institute of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland)

    2017-07-15

    Single-phase multicomponent alloys of equal atomic concentrations (“equiatomic”) have proven to exhibit promising mechanical and corrosion resistance properties, that are sought after in materials intended for use in hazardous environments like next-generation nuclear reactors. In this article, we investigate the damage production and dislocation mobility by simulating irradiation of elemental Ni and the alloys NiCo, NiCoCr, NiCoFe and NiFe, to assess the effect of elemental composition. We compare the defect production and the evolution of dislocation networks in the simulation cells of two different sizes, for all five studied materials. We find that the trends in defect evolution are in good agreement between the different cell sizes. The damage is generally reduced with increased alloy complexity, and the dislocation evolution is specific to each material, depending on its complexity. We show that increasing complexity of the alloys does not always lead to decreased susceptibility to damage accumulation under irradiation. We show that, for instance, the NiCo alloy behaves very similarly to Ni, while presence of Fe or Cr in the alloy even as a third component reduces the saturated level of damage substantially. Moreover, we linked the defect evolution with the dislocation transformations in the alloys. Sudden drops in defect number and large defect fluctuations from the continuous irradiation can be explained from the dislocation activity.

  13. Corrosion Resistance Of Electroless Ni-P/Cu/Ni-P Multilayer Coatings

    Directory of Open Access Journals (Sweden)

    Zhao G.L.

    2015-06-01

    Full Text Available Ni-P/Cu/Ni-P multilayer coatings were prepared by deposition of Cu layer between two Ni–P layers. The Cu layer was deposited by metal displacement reaction between Cu2+ and Fe atoms. Corrosion behavior of single-layer Ni-P coatings, double-layer Ni-P/Cu coatings, and three-layer Ni-P/Cu/Ni-P coatings were investigated by electrochemical tests in 3.5% NaCl solution. The three-layer coatings exhibited more positive Ecorr and decreased Icorr compared with conventional single-layer Ni-P coatings, which indicated an improved corrosion resistance. The polarization curves of the three-layer coatings were characterized by two passive regions. The improved corrosion resistance was not only attributed to the function of the blocked pores of Cu. The Cu interlayer also acted as a sacrificial layer instead of a barrier in the coatings, which altered the corrosion mechanism and further improved the corrosion resistance of the coatings.

  14. PRECIPITATION HARDENING IN B2-ORDERED NiAl BY Ni2AlTiCOMPOUND

    Institute of Scientific and Technical Information of China (English)

    W.H. Tian; K. Ohishi; M. Nemoto

    2001-01-01

    Microstructural variations and correlated hardness changes in B2-ordered NiAl containing fine precipitation of Ni2AlTi have been investigated by means of transmission electron microscopy (TEM) and hardness tests. The amount of age hardening is not large as compared to the large microstructural variations during aging. TEM observations have revealed that the L21-type Ni2AlTi precipitates keep a lattice coherency with the NiAl matrix at the beginning of aging. By longer periods of aging Ni2AlTi precipitates lose their coherency and change their morphology to the globular ones surrounded by misfit dislocations. The temperature dependence of the yield strength of precipitate-containing B2-ordered NiAl was investigated by compression tests over the temperature range of 873-1273K. The fine precipitation of Ni2AlTi was found to enhance greatly the yield strength and the high-temperature strength is comparison with that of superalloy Mar-M200.``

  15. Development of small-scale electroplating system for Ni-63 electroplating onto Ni foil

    International Nuclear Information System (INIS)

    Kim, Jin Joo; Choi, Sang Mu; Son, Kwang Jae; Hong, Jintae

    2016-01-01

    Betavoltaic battery is a device that converts the decay energy of beta-emitting radioisotopes into electric energy. Ni-63 is pure betaemitter with a low energy spectrum and significantly long half-life of 100.1 years and thus is widely used as the power source of betavoltaic battery. There are several methods for the formation of a Ni deposit onto a semiconductor such as electroplating, electroless plating, and chemical vapor deposition. In this study, small-scale radioisotope electroplating system was designed and fabricated to perform electroplating with a small amount of plating buffer and minimum exposure of radioactive materials. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery. In this study, an electroplating system for small-scale Ni electroplating was designed and manufactured. The process for the fabrication of a Ni-63 foil as the energy source of a betavoltaic battery was developed using the minimum concentration of Ni. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery

  16. Development of small-scale electroplating system for Ni-63 electroplating onto Ni foil

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jin Joo; Choi, Sang Mu; Son, Kwang Jae; Hong, Jintae [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-10-15

    Betavoltaic battery is a device that converts the decay energy of beta-emitting radioisotopes into electric energy. Ni-63 is pure betaemitter with a low energy spectrum and significantly long half-life of 100.1 years and thus is widely used as the power source of betavoltaic battery. There are several methods for the formation of a Ni deposit onto a semiconductor such as electroplating, electroless plating, and chemical vapor deposition. In this study, small-scale radioisotope electroplating system was designed and fabricated to perform electroplating with a small amount of plating buffer and minimum exposure of radioactive materials. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery. In this study, an electroplating system for small-scale Ni electroplating was designed and manufactured. The process for the fabrication of a Ni-63 foil as the energy source of a betavoltaic battery was developed using the minimum concentration of Ni. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery.

  17. Exchange bias in finite sized NiO nanoparticles with Ni clusters

    International Nuclear Information System (INIS)

    Gandhi, Ashish Chhaganlal; Lin, Jauyn Grace

    2017-01-01

    Structural and magnetic properties of finite sized NiO nanoparticles are investigated with synchrotron X-ray diffraction (XRD), transmission electron microscopy, magnetometer and ferromagnetic resonance (FMR) spectroscopy. A minor Ni phase is detected with synchrotron XRD, attributed to the oxygen defects in the NiO core. A considerable exchange bias of ~100 Oe is observed at 50 K and it drops abruptly and vanishes above 150 K, in association with the reduction of frozen spins. FMR data indicate a strong interaction between ferromagnetic (FM) and antiferromagnetic (AFM) phases below 150 K, consistent with the picture of isolated FM clusters in AFM matrix. - Highlights: • Structural and magnetic properties of finite sized NiO nanoparticles are systematically investigated with several advanced techniques. • A strong interaction between ferromagnetic and antiferromagnetic phases is found below 150 K. • Exchange bias field in finite sized NiO nanoparticles is due to anisotropy energy of Ni clusters over riding the domain wall energy of NiO.

  18. Tipos especiales de niños

    Directory of Open Access Journals (Sweden)

    Mercedes Rodrigo Bellido

    1946-09-01

    Full Text Available En las tres últimas lecciones han sido expuestas algunas consideraciones referentes a niños y adolescentes desde el nacimiento hasta el dintel de la juventud. En todas ellas hemos procurado poner de relieve la necesidad de individualizar el conocimiento de cada niño para obtener mejores resultados en su adaptación a su futura vida de adultos, En todas ellas  nos hemos referido al llamado niño normal. Nos corresponde en la lección de hoy ocuparnos can la superficialidad característica de estas charlas tipo-muestrario, de otras categorías de niños muy dignos de interés.. quienes unas por exceso, otros por defecto, otros por dificultades de adaptación por diferentes causas, se desvían de la línea media de la normalidad. Consideramos que no está fuera del lugar, aquí, el tema de los niños excepcionales y por el contrario que es necesario intensificar el estudio de los trastornos de la vida mental y emocional de los niños en la preparación de los estudiantes de Medicina. Y no es nuestra solo esta opinión; no hace mucho tiempo en la Medical School de Ia Universidad de Minnessota hemos sabido que se ha hecho un intento de considerar y evaluar factores emocionales ambientales sobre las mismas bases que los descubrimientos fisiológicos.

  19. Ni Foam-Ni3 S2 @Ni(OH)2 -Graphene Sandwich Structure Electrode Materials: Facile Synthesis and High Supercapacitor Performance.

    Science.gov (United States)

    Wang, Xiaobing; Hu, Jiangjiang; Su, Yichang; Hao, Jin; Liu, Fanggang; Han, Shuang; An, Jian; Lian, Jianshe

    2017-03-23

    A novel Ni foam-Ni 3 S 2 @Ni(OH) 2 -graphene sandwich-structured electrode (NF-NN-G) with high areal mass loading (8.33 mg cm -2 ) has been developed by sulfidation and hydrolysis reactions. The conductivity of Ni 3 S 2 and Ni(OH) 2 were both improved. The upper layer of Ni(OH) 2 , covered with a thin graphene film, is formed in situ from the surface of the lower layer of Ni 3 S 2 , whereas the Ni 3 S 2 grown on Ni foam substrate mainly acts as a rough support bridging the Ni(OH) 2 and Ni foam. The graphene stabilized the Ni(OH) 2 and the electrochemical properties were effectively enhanced. The as-synthesized NF-NN-G-5mg electrode shows a high specific capacitance (2258 F g -1 at 1 A g -1 or 18.81 F cm -2 at 8.33 mA cm -2 ) and an outstanding rate property (1010 F g -1 at 20 Ag -1 or 8.413 F cm -2 at 166.6 mA cm -2 ). This result is around double the capacitance achieved in previous research on Ni 3 S 2 @Ni(OH) 2 /3DGN composites (3DGN=three-dimensional graphene network). In addition, the as-fabricated NF-NN-G-5mg composite electrode has an excellent cycle life with no capacitance loss after 3000 cycles, indicating a potential application as an efficient electrode. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Salud mental del niño

    OpenAIRE

    Ospina de González, Bernarda

    1987-01-01

    Es ya reconocida por todos las importancia de los primeros años de vida en la estructutración de la personalidad y, por consiguiente, en la salud mental del niño. En este artículo se hace una síntesis de los diferentes aspectos del desarrollo de la personalidad infanltil que seben ser conocidos por el personal de salud para estar en condiciones de brindar una atención integral a la madre y al niño. Con igual propósito se señalan algunos patrones de tipo psicosocial que influyen en la estabili...

  1. Magnetic anisotropy of Ni/Cr multilayers

    International Nuclear Information System (INIS)

    Kang, S.; Xia, H.

    1997-01-01

    The magnetic anisotropy of Ni/Cr multilayers has been investigated by using vibrating sample magnetometer (VSM) and ferromagnetic resonance techniques (FMR). The FMR spectra are obtained as a function of the orientation of the applied magnetic field from in-plane to out-of-plane. The results are fitted theoretically to determine the magnetic anisotropy. From VSM and FMR, a positive value for Ni/Cr interface anisotropy is obtained, which favours a perpendicular easy axis. The possible mechanism for the perpendicular anisotropy has been discussed and it may be attributed to the magnetostriction, caused by intrinsic stress due to lattice mismatch. (orig.). With 005 figs., 001 tabs

  2. Ionizing Radiation Effects in Ni Nanotubes

    Science.gov (United States)

    Shlimas, D.; Kozlovsky, A.; Shumskaya, A.; Kaniukov, E.; Ibragimova, M.; Zdorovets, M.; Kadyrzhanov, K.

    2017-01-01

    Polycrystalline nickel nanotubes with diameter of 380 nm and wall thickness 95 nm were synthesized by electrochemical method using PET track-etched membranes with thickness of 12 μm. A comprehensive study of the structural, morphological and electrical characteristics of Ni nanotubes irradiated with C+13 ions with energy 1.75 MeV/nucleon and fluence ranging from 109 to 5 × 1011 cm-2 was carried out. The ability of modification of structural parameters such as lattice parameter and the average size of crystallites and conductivity of Ni nanotubes by irradiation was shown.

  3. Optimization of process parameters for synthesis of silica–Ni ...

    Indian Academy of Sciences (India)

    Optimization of process parameters for synthesis of silica–Ni nanocomposite by design of experiment ... Sol–gel; Ni; design of experiments; nanocomposites. ... Kolkata 700 032, India; Rustech Products Pvt. Ltd., Kolkata 700 045, India ...

  4. Ni hollow spheres as catalysts for methanol and ethanol electrooxidation

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Changwei [Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632 (China); School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Hu, Yonghong; Rong, Jianhua; Liu, Yingliang [Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632 (China); Jiang, San Ping [School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798 (Singapore)

    2007-08-15

    In this paper, we successfully synthesized Ni hollow spheres consisting of needle-like nickel particles by using silica spheres as template with gold nanoparticles seeding method. The Ni hollow spheres are applied to methanol and ethanol electrooxidation in alkaline media. The results show that the Ni hollow spheres give a very high activity for alcohol electrooxidation at a very low nickel loading of 0.10 mg cm{sup -2}. The current on Ni hollow spheres is much higher than that on Ni particles. The onset potential and peak potential on Ni hollow spheres are more negative than that on Ni particles for methanol and ethanol electrooxidation. The Ni hollow spheres may be of great potential in alcohol sensor and direct alcohol fuel cells. (author)

  5. Separation and preparation of "6"2Ni isotope

    International Nuclear Information System (INIS)

    Ren Xiuyan; Mi Yajing; Zeng Ziqiang; Li Gongliang; Tu Rui

    2014-01-01

    Micro nuclear battery is the perfect power of space craft equipment. "6"3Ni is the core operation material of the "6"3Ni battery. It can produce radioisotope "6"3Ni while high abundance "6"2Ni is irradiated in the reactor. In order to meet the requirements of the abundance and the purity, research of the separation for "6"2Ni isotope was developed. The magnetic field and beam transmission status were simulated. The improvement designs of the ion source and the collector pocket were carried out. The process flow of high abundance "6"2Ni using electromagnetic separation method was established. The experiment of "6"2Ni isotope was developed by using electromagnetism isotope separator. The results show that the enrichment of "6"2Ni isotope is more than 90%. (authors)

  6. X-ray fluorescence analysis of Fe - Ni - Mo systems

    International Nuclear Information System (INIS)

    Belyaev, E.E.; Ershov, A.V.; Mashin, A.I.; Mashin, N.I.; Rudnevskij, N.K.

    1998-01-01

    Procedures for the X-ray fluorescence determination of the composition and thickness of Fe - Ni - Mo thin films and the concentration of elements in thick films of the Fe - Ni - Mo alloy are developed [ru

  7. Structure characterization of Ni/NiO and Ti/TiO2 interfaces

    International Nuclear Information System (INIS)

    Lamine, Brahim

    1983-01-01

    This research thesis reports the structure characterization of Ni-NiO and Ti-TiO 2 interfaces through an in-situ investigation of thin blade oxidation, of oxide germination and growth, and through a determination of mutual metal/oxide orientation relationships. Thin films of TiO 2 have also been characterized and the study of the influence of vacuum annealing on TiO 2 layer structure and morphology has been attempted. The examination of metal-oxide interface reveals a duplex structure of NiO and TiO 2 layers, and a preferential grain boundary oxidation of the underlying metal [fr

  8. Structure of Ni-rich Ni--Cr--B--Si coating alloys

    International Nuclear Information System (INIS)

    Knotek, O.; Lugscheider, E.; Reimann, H.

    1975-01-01

    The structures of quaternary, nickel-rich Ni--Cr--B--Si alloys were analyzed at a constant boron content of 10 at. percent and a temperature of 850 0 C. The composition range for silicide formation was determined. In these quaternary alloys, known binary nickel silicides, nickel and chromium borides, and the ternary silico-boride Ni 6 Si 2 B were confirmed. A new composition for the W 5 Si 3 -type phase in the Ni--B--Si system was proposed. (U.S.)

  9. The study of quasi-projectiles produced in Ni+Ni and Ni+Au collisions: excitation energy and spin

    International Nuclear Information System (INIS)

    Buta, A.

    2003-02-01

    During the collision between the projectile and the target nuclei in the intermediate energy regime (E < 100 MeV/nucleon) two excited nuclei are mainly observed in the exit channel, the quasi projectile (QP) and the quasi target. They disintegrate by particle emission. However, this binary picture is perturbed by the emission of particles and light fragments with velocities intermediate between the projectile velocity and the target one, all along the interaction (midrapidity component). This work aim to determine the excitation energy and the intrinsic angular momentum (or spin) of quasi-projectiles produced in the Ni+Ni and Ni+Au collisions at 52 and 90 MeV/nucleon. The excitation energy is deduced from the kinematical characteristics of particles emitted by the quasi-projectile. They have to be separated from midrapidity particles. Three different scenarios have been used for this purpose. The spin of the quasi-projectile has been extracted from the experimental data by mean of proton and alpha particles multiplicities emitted by the QP in the Ni+Au at 52 MeV/nucleon reaction. The results have been compared to the predictions of a theoretical model based on nucleon transfers. Their evolution is qualitatively reproduced as a function of the violence of the collision. (author)

  10. Low temperature gaseous nitriding of Ni based superalloys

    DEFF Research Database (Denmark)

    Eliasen, K. M.; Christiansen, Thomas Lundin; Somers, Marcel A. J.

    2010-01-01

    In the present work the nitriding response of selected Ni based superalloys at low temperatures is addressed. The alloys investigated are nimonic series nos. 80, 90, 95 and 100 and nichrome (Ni/Cr......In the present work the nitriding response of selected Ni based superalloys at low temperatures is addressed. The alloys investigated are nimonic series nos. 80, 90, 95 and 100 and nichrome (Ni/Cr...

  11. Giant magnetocaloric effect in isostructural MnNiGe-CoNiGe system by establishing a Curie-temperature window

    KAUST Repository

    Liu, E. K.; Zhang, H. G.; Xu, G. Z.; Zhang, X. M.; Ma, R. S.; Wang, W. H.; Chen, J. L.; Zhang, H. W.; Wu, G. H.; Feng, L.; Zhang, Xixiang

    2013-01-01

    An effective scheme of isostructural alloying was applied to establish a Curie-temperature window in isostructural MnNiGe-CoNiGe system. With the simultaneous accomplishment of decreasing structural-transition temperature and converting

  12. The large magnetoelectric effect in Ni-lead zirconium titanate-Ni trilayers derived by electroless deposition

    International Nuclear Information System (INIS)

    Bi, K; Wang, Y G; Wu, W; Pan, D A

    2010-01-01

    Magnetoelectric (ME) Ni-lead zirconium titanate-Ni trilayers with neither electrodes nor bonding layers have been derived by electroless deposition. The structure and magnetic properties of the electroless deposited Ni layers with different pH values are characterized by x-ray diffraction and vibrating sample magnetometer. The influence of the bias magnetic field and the magnetic field frequency (f) on ME coupling is discussed. It is seen that α E,31 depends strongly on H dc and f. The value of the ME coefficient increases as the thickness of the Ni layer and the pH of the bath increase. A maximum of the ME voltage coefficient α E,31 = 5.77 V cm -1 Oe -1 at resonance frequency with a deposited Ni layer thickness t Ni = 302 μm is obtained. The large ME coefficient makes these Ni-PZT-Ni trilayers suitable for applications in sensors, actuators and transducers. (fast track communication)

  13. Development of the dentistry alloy Ni-Cr-Nb; Desenvolvimento de ligas odontologicas Ni-Cr-Nb

    Energy Technology Data Exchange (ETDEWEB)

    Souza, M.A.; Ramos, A.S.; Hashimoto, T.M., E-mail: mari_sou@hotmail.co [UNESP/FEG, Guaratingueta, SP (Brazil). Fac. de Engenharia. Dept. de Materiais e Tecnologia

    2010-07-01

    This work reports on the structural characterization of Ni-Cr-Mo and Ni-Cr-Nb alloys produced by arc melting. Samples were characterized by means of optical microscopy, X-ray diffraction, scanning electron microscopy, and EDS analysis. Results indicated that the arc melting process was efficient to produce homogeneous structures in Ni-Cr-Mo and Ni-Cr-Nb alloys. The nickel dissolved large amounts of Cr, Mo and Nb, which was detected by EDS analysis and X-ray diffraction. The alloy containing molybdenum indicated the presence of structure based on Ni{sub SS}, while that the alloys containing niobium presented primary grains of Ni{sub SS} and precipitates formed by the simultaneous transformation of the Ni and Ni{sub 3}Nb phases. (author)

  14. Microstructure and electrochemical characterization of laser melt-deposited Ti2Ni3Si/NiTi intermetallic alloys

    International Nuclear Information System (INIS)

    Dong Lixin; Wang Huaming

    2008-01-01

    Corrosion and wear resistant Ti 2 Ni 3 Si/NiTi intermetallic alloys with Ti 2 Ni 3 Si as the reinforcing phase and the ductile NiTi as the toughening phase were designed and fabricated by the laser melt-deposition manufacturing process. Electrochemical behavior of the alloys was investigated using potentiodynamic polarization testing and electrochemical impedance spectroscopy in an NaOH solution. The results showed that the alloys have outstanding corrosion resistance due to the formation of a protective passive surface film of Ni(OH) 2 as well as the high chemical stability and strong inter-atomic bonds inherent to Ti 2 Ni 3 Si and NiTi intermetallics. The Ti 2 Ni 3 Si content has a significant influence on the microstructure of the alloys but only a slight effect on electrochemical corrosion properties

  15. Homotopic mapping solution of an oscillator for the El Niño/La Niña-southern oscillation

    International Nuclear Information System (INIS)

    Xian-Chun, Zhou; Yi-Hua, Lin; Wan-Tao, Lin; Jia-Qi, Mo

    2009-01-01

    This paper considers a class of oscillator for the El Niño/La Niña-southern oscillation (ENSO) model. By using the homotopic mapping method, it obtains approximations of the solution for the ENSO model. (general)

  16. Electrochemical reduction of NiO in a composite electrode

    DEFF Research Database (Denmark)

    Hu, Qiang; Jacobsen, Torben; Hansen, Karin Vels

    2013-01-01

    a lower overpotential. Microstructures of NiO with different reduction degrees are shown. Electrochemical impedance spectroscopy is carried out during the reduction process. Electrochemical reduction of NiO may need an induction period. When NiO is reduced at a constant voltage the current initially...

  17. Morphological and compositional engineering of Ni/carbon ...

    Indian Academy of Sciences (India)

    Ni/multi-walled carbon nanotubes (MWCNTs) composite films were deposited on the glassy carbon electrode (GCE) by a Ni plating bath containing homogeneously dispersed MWCNTs using polyvinylpyrrolidone (PVP) as dispersion additive. Incorporation of MWCNTs into Ni matrix was greatly enhanced by the application ...

  18. CLASSICAL AREAS OF PHENOMENOLOGY: First-principles calculations for the elastic properties of Ni-base model superalloys: Ni/Ni3Al multilayers

    Science.gov (United States)

    Wang, Yun-Jiang; Wang, Chong-Yu

    2009-10-01

    A model system consisting of Ni[001](100)/Ni3Al[001](100) multi-layers are studied using the density functional theory in order to explore the elastic properties of single crystal Ni-based superalloys. Simulation results are consistent with the experimental observation that rafted Ni-base superalloys virtually possess a cubic symmetry. The convergence of the elastic properties with respect to the thickness of the multilayers are tested by a series of multilayers from 2γ'+2γ to 10γ'+10γ atomic layers. The elastic properties are found to vary little with the increase of the multilayer's thickness. A Ni/Ni3Al multilayer with 10γ'+10γ atomic layers (3.54 nm) can be used to simulate the mechanical properties of Ni-base model superalloys. Our calculated elastic constants, bulk modulus, orientation-dependent shear modulus and Young's modulus, as well as the Zener anisotropy factor are all compatible with the measured results of Ni-base model superalloys R1 and the advanced commercial superalloys TMS-26, CMSX-4 at a low temperature. The mechanical properties as a function of the γ' phase volume fraction are calculated by varying the proportion of the γ and γ' phase in the multilayers. Besides, the mechanical properties of two-phase Ni/Ni3Al multilayer can be well predicted by the Voigt-Reuss-Hill rule of mixtures.

  19. Low-field spin dynamics of Cr7Ni and Cr7Ni-Cu -Cr 7Ni molecular rings as detected by μ SR

    Science.gov (United States)

    Sanna, S.; Arosio, P.; Bordonali, L.; Adelnia, F.; Mariani, M.; Garlatti, E.; Baines, C.; Amato, A.; Sabareesh, K. P. V.; Timco, G.; Winpenny, R. E. P.; Blundell, S. J.; Lascialfari, A.

    2017-11-01

    Muon spin rotation measurements were used to investigate the spin dynamics of heterometallic Cr7Ni and Cr7Ni -Cu-Cr7Ni molecular clusters. In Cr7Ni the magnetic ions are arranged in a quasiplanar ring and interact via an antiferromagnetic exchange coupling constant J , while Cr7Ni -Cu-Cr7Ni is composed of two Cr7Ni linked by a bridging moiety containing one Cu ion, that induces an inter-ring ferromagnetic interaction J'≪J . The longitudinal muon relaxation rate λ collected at low magnetic fields μ0H BPP)-like heuristic fitting model that takes into account of a distribution of electronic spin characteristic times for T >5 K, while the shoulder presented by Cr7Ni can be reproduced by a BPP function that incorporates a single electronic characteristic time theoretically predicted to dominate for T <5 K. The flattening of λ (T ) in Cr7Ni -Cu-Cr7Ni occurring at very low temperature can be tentatively attributed to field-dependent quantum effects and/or to an inelastic term in the spectral density of the electronic spin fluctuations.

  20. Microporous Ni@NiO nanoparticles prepared by chemically dealloying Al_3Ni_2@Al nanoparticles as a high microwave absorption material

    International Nuclear Information System (INIS)

    Pang, Yu; Xie, Xiubo; Li, Da; Chou, Wusheng; Liu, Tong

    2017-01-01

    The Al_3Ni_2@Al nanoparticles (NPs) were prepared from Ni_4_5Al_5_5 master alloy by hydrogen plasma-metal reaction method, and were subsequently dealloyed to produce porous Ni@NiO NPs of 36 nm. The pore size ranges from 0.7 to 1.6 nm, leading to large specific surface area of 69.5 m"2/g and big pore volume of 0.507 cc/g. The saturation magnetization (M_S) and coercivity (H_C) of the microporous Ni@NiO NPs are 11.5 emu/g and 5.2 Oe. They exhibit high microwave absorption performance with a minimum reflection coefficient (RC) of −86.9 dB and an absorption bandwidth of 2.6 GHz (RC≤−10 dB) at thickness of 4.5 mm. The enhanced microwave absorption properties are attributed to the synergistic effect of the magnetic Ni core and dielectric NiO shell, and the micropore architecture. The NPs with micropore morphology and core/shell structure open a new way to modify the microwave absorption performance. - Graphical abstract: The microporous Ni/NiO nanoparticles prepared by chemically dealloying Al_3Ni_2@Al NPs exhibit high microwave absorption intensity (−86.9 dB) and wide absorption bandwidth (2.6 GHz for RC≤−10 dB). - Highlights: • Microporous Ni/NiO nanoparticals were prepared by chemically dealloying method. • They possessed micropores of 0.7–1.6 nm with a surface area of 69.5 m"2/g. • They showed high microwave absorption intensity and wide absorption bandwidth. • Microwave absorption mechanism was explained by micropore and core/shell structures.

  1. Microporous Ni@NiO nanoparticles prepared by chemically dealloying Al{sub 3}Ni{sub 2}@Al nanoparticles as a high microwave absorption material

    Energy Technology Data Exchange (ETDEWEB)

    Pang, Yu; Xie, Xiubo; Li, Da [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing 100191 (China); Chou, Wusheng [School of Mechanical Engineering and Automation, Beihang University, Beijing 100191 (China); Liu, Tong, E-mail: tongliu@buaa.edu.cn [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing 100191 (China)

    2017-03-15

    The Al{sub 3}Ni{sub 2}@Al nanoparticles (NPs) were prepared from Ni{sub 45}Al{sub 55} master alloy by hydrogen plasma-metal reaction method, and were subsequently dealloyed to produce porous Ni@NiO NPs of 36 nm. The pore size ranges from 0.7 to 1.6 nm, leading to large specific surface area of 69.5 m{sup 2}/g and big pore volume of 0.507 cc/g. The saturation magnetization (M{sub S}) and coercivity (H{sub C}) of the microporous Ni@NiO NPs are 11.5 emu/g and 5.2 Oe. They exhibit high microwave absorption performance with a minimum reflection coefficient (RC) of −86.9 dB and an absorption bandwidth of 2.6 GHz (RC≤−10 dB) at thickness of 4.5 mm. The enhanced microwave absorption properties are attributed to the synergistic effect of the magnetic Ni core and dielectric NiO shell, and the micropore architecture. The NPs with micropore morphology and core/shell structure open a new way to modify the microwave absorption performance. - Graphical abstract: The microporous Ni/NiO nanoparticles prepared by chemically dealloying Al{sub 3}Ni{sub 2}@Al NPs exhibit high microwave absorption intensity (−86.9 dB) and wide absorption bandwidth (2.6 GHz for RC≤−10 dB). - Highlights: • Microporous Ni/NiO nanoparticals were prepared by chemically dealloying method. • They possessed micropores of 0.7–1.6 nm with a surface area of 69.5 m{sup 2}/g. • They showed high microwave absorption intensity and wide absorption bandwidth. • Microwave absorption mechanism was explained by micropore and core/shell structures.

  2. Tracer diffusion of 60Co and 63Ni in amorphous NiZr alloy

    International Nuclear Information System (INIS)

    Hoshino, K.; Averback, R.S.; Hahn, H.; Rothman, S.J.

    1987-01-01

    Tracer diffusion of 60 Co and 63 Ni in equiatomic amorphous NiZr alloy in the temperature range between 486 and 641 0 K can be described by: D/sub Co/sup */ = 3.7 x 10 -7 exp[-(135 +- 14) kJ mole -1 /RT] m 2 /sec and D/sub Ni//sup */ = 1.7 x 10 -7 exp[-(140 +- 9) kJ mole -1 /RT] m 2 /sec. The values of D/sub Ni//sup */ are in reasonable agreement with those measured by the Rutherford backscattering technique. The measured diffusivities were independent of time, indicating that no relaxation took place during diffusion. 27 refs., 2 tabs

  3. Precipitation-induced of partial annealing of Ni-rich NiTi shape memory alloy

    Science.gov (United States)

    Nashrudin, Muhammad Naqib; Mahmud, Abdus Samad; Mohamad, Hishamiakim

    2018-05-01

    NiTi shape memory alloy behavior is very sensitive to alloy composition and heat treatment processes. Thermomechanical behavior of near-equiatomic alloy is normally enhanced by partial anneal of a cold-worked specimen. The shape memory behavior of Ni-rich alloy can be enhanced by ageing precipitation. This work studied the effect of simultaneous partial annealing and ageing precipitation of a Ni-rich cold drawn Ti-50.9at%Ni wire towards martensite phase transformation behavior. Ageing treatment of a non-cold worked specimen was also done for comparison. It was found that the increase of heat treatment temperature caused the forward transformation stress to decrease for the cold worked and non-cold worked specimens. Strain recovery on the reverse transformation of the cold worked wire improved compared to the non-cold worked wire as the temperature increased.

  4. Corrosion behaviour of electrodeposited nanocrystalline Ni-W and Ni-Fe-W alloys

    International Nuclear Information System (INIS)

    Sriraman, K.R.; Ganesh Sundara Raman, S.; Seshadri, S.K.

    2007-01-01

    The present work deals with evaluation of corrosion behaviour of electrodeposited nanocrystalline Ni-W and Ni-Fe-W alloys. Corrosion behaviour of the coatings deposited on steel substrates was studied using polarization and electrochemical impedance spectroscopy techniques in 3.5% NaCl solution while their passivation behaviour was studied in 1N sulphuric acid solution. The corrosion resistance of Ni-W alloys increased with tungsten content up to 7.54 at.% and then decreased. In case of Ni-Fe-W alloys it increased with tungsten content up to 9.20 at.% and then decreased. The ternary alloy coatings exhibited poor corrosion resistance compared to binary alloy coatings due to preferential dissolution of iron from the matrix. Regardless of composition all the alloys exhibited passivation behaviour over a wide range of potentials due to the formation of tungsten rich film on the surface

  5. Evolution of collectivity in the 78Ni region: Coulomb excitation of 74Ni at intermediate energies.

    Directory of Open Access Journals (Sweden)

    Marchi T.

    2014-03-01

    Full Text Available The study of the collective properties of nuclear excitations far from stability provides information about the shell structure at extreme conditions. Spectroscopic observables such as the energy or the transition probabilities of the lowest states, in nuclei with large neutron excess, allow to probe the density and isospin dependence of the effective interaction. Indeed, it was recently shown that tensor and three-body forces play an important role in breaking and creating magic numbers. Emblematic is the case of the evolution of the Ni isotopic chain where several features showed up moving from the most neutron rich stable isotope (64Ni towards the 78Ni nucleus where the large neutron excess coincides with a double shell closure. In this framework, we have recently performed an experiment with the goal to extract the B(E2; 0+ → 2+ value for the 74Ni nucleus in an intermediate-energy Coulomb excitation experiment: preliminary results are discussed.

  6. Rate of hydrogen motion in Ni-substituted LaNi5Hx from NMR

    International Nuclear Information System (INIS)

    Mendenhall, Michael P.; Bowman, Robert C.; Ivancic, Timothy M.; Conradi, Mark S.

    2007-01-01

    Partial substitution of Sn, Ge, or Si for Ni in LaNi 5 H x greatly enhances the stability under repeated hydrogen-cycling. Proton NMR relaxation measurements are reported here to determine the rates of H hopping in the substituted metals LaNi 4.6 M 0.4 H x with M = Sn, Ge, and Si, for comparison to bare LaNi 5 H x . The relaxation times T 2 * (FID), T 2 (Hahn echo), T 2 -CPMG, T 1 , and T 1ρ were determined from 130 to 375 K. The three substituents result in only small increases in the average rate of motion at a given temperature but with a broader distribution of rates over the many inequivalent H sites and hopping paths. Evidently, the average energy barriers along the paths for H motion are only little affected by these substituents. Changes of H content x produce only minor changes in the relaxation times

  7. Moessbauer effect measurements on the intermetallic compounds Ni3Al and Ni3Ge

    International Nuclear Information System (INIS)

    Drijver, J.W.; Woude, F. van der

    1975-01-01

    Moessbauer parameters obtained from room temperature emission and absorption spectra of Ni 3 Al and Ni 3 Ga processed by a computer assuming a singlet and a doublet are given. The doublet is due to iron or cobalt atoms at the nickel site. Quadrupole splitting at 57 Fe nuclei in Ni 3 Ga is larger than in Ni 3 Al, viz. 0.52 and 0.37 mm/sec, respectively. Isomer shift at the Al/Ga position is very close to -0.02 mm/sec found in metallic nickel. Also given are the hyperfine magnetic fields at 4.2 K. Considering the preference of 57 Co and 57 Fe atoms in the lattice, the field intensities at the nickel and aluminium sites are found to be 227 +- 1 and 238 +- 1 kOe, respectively. (Z.S.)

  8. Low energy structure of even-even Ni isotopes close to 78Ni

    International Nuclear Information System (INIS)

    Rykaczewski, Krzysztof Piotr; Mazzocchi, C.; Grzywacz, Robert Kazimierz; Batchelder, J.C.; Bingham, Carrol R.; Fong, D.; Hamilton, J.H.; Hwang, J.K.; Karny, M.; Krolas, W.; Liddick, S.N.; Lisetskiy, A. F.; Morton, N.H.; Mantica, P.F.; Mueller, W.F.; Steiner, M.; Stolz, A.; Winger, J.A.

    2005-01-01

    The structure of magic neutron-rich nickel isotopes produced in the fragmentation of a 140 A MeV 86 Kr beam was investigated. For the first time four gamma transitions were assigned to the decay of the I π =8 + , T 1/2 = 590 +180 -110 isomer, thus establishing the 0 + -2 + -4 + -6 + -8 + ground-state band in 76 Ni. The previously unknown 2 + and 4 + levels belonging to the ground-state band in 74 Ni were identified in the β decay of 74 Co (T 1/2 =30(3) ms). The decay properties of 72 Co → 72 Ni were verified and confirmed on the basis of γ-γ coincidence data. The relevance of the measured level properties for the magicity of 78 Ni is analyzed with the help of advanced shell-model predictions

  9. The process of Ni-63 production and measurement of beta radiation of irradiated Ni-63

    International Nuclear Information System (INIS)

    Kim, Jin Joo; Uhma, Young Rang; Kim, Jong Bum; Choi, Sang Mu; Son, Kwang Jae; Hong, Jin Tae; Park, Jong Han

    2016-01-01

    It has the following characteristics: long service lifetime, high energy density, easy small-scale fabrication, and minimum maintenance. For this reasons, betavoltaic batteries are widely used in many low-power applications such as medical applications and power sources for micro electro-mechanical system (MEMS) because they can operate effectively at extreme environments. Proper selection of radioisotope is a critical factor in the design of a betavoltaic battery. The important factors affecting the performance of a betavoltaic battery are specific activity, half-life, and toxicity. In this study, a target for irradiation was produced using 99% Ni-62 metal power concentrate. Ni-62 target of 1 g was irradiated in MARIA reactor operated in Poland for 470 hours, and estimated production of Ni- 63 was calculated. Irradiated Ni-63 pellets were dissolved in HCl solution, and its beta radiation was measured by Liquid Scintillation Counter (LSC).

  10. Synthetic Ni3S2/Ni hybrid architectures as potential contrast agents in MRI

    International Nuclear Information System (INIS)

    Ma, J; Chen, K

    2016-01-01

    Traditional magnetic resonance imaging (MRI) contrast agents mainly include superparamagnetic (SPM) iron oxide nanoparticle as T 2 contrast agent for liver and paramagnetic Gd (III)-chelate as T 1 contrast agent for all organs. In this work, weak ferromagnetic kale-like and SPM cabbage-like Ni 3 S 2 @Ni hybrid architectures were synthesized and evaluated as potential T 1 MRI contrast agents. Their relatively small r 2 /r 1 ratios of 2.59 and 2.38, and high r 1 values of 11.27 and 4.89 mmol −1 L s −1 (for the kale-like and cabbage-like Ni 3 S 2 @Ni, respectively) will shed some light on the development of new-type MRI contrast agents. (paper)

  11. Hierarchical NiCo2 O4 nanosheets grown on Ni nanofoam as high-performance electrodes for supercapacitors.

    Science.gov (United States)

    Gao, Guoxin; Wu, Hao Bin; Ding, Shujiang; Liu, Li-Min; Lou, Xiong Wen David

    2015-02-18

    A high-performance electrode for supercapacitors is designed and synthesized by growing electroactive NiCo2 O4 nanosheets on conductive Ni nanofoam. Because of the structural advantages, the as-prepared Ni@NiCo2 O4 hybrid nanostructure exhibits significantly improved electrochemical performance with high capacitance, excellent rate capability, and good cycling stability. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Ni(II) complexes of dithiophosphonic acids

    Indian Academy of Sciences (India)

    aDepartment of Chemistry, Science and Research Branch, Islamic Azad ... The compounds were characterized by 1H, 13C and 31P NMR, IR spectroscopy and elemental analysis. The ... design and synthesize Ni(II) complexes with new ..... Yield: 86%. ..... 28 65. 18. Greenwood D 1989 Antimicrobial chemotherapy (New.

  13. Ni MINERALIZATION AND PGE CHARACTERIZATION IN THE ...

    African Journals Online (AJOL)

    Mgina

    fractionation, (2) the IPGEs are often associated with chromites as alloys or sulfides in ... Key words: Tanzania, Kabanga, Luhuma, PGE, Ni-Cu sulfides .... massive sulfide based on size of ore zone ... to ≤ 0.1 wt% and Fe2O3T = 80- ≈ 87 wt%.

  14. Modelling of rechargeable NiMH batteries

    NARCIS (Netherlands)

    Ledovskikh, A.; Verbitskiy, E.; Ayeb, A.; Notten, P.H.L.

    2003-01-01

    A new mathematical model has been developed for rechargeable NiMH batteries, which is based on the occurring physical–chemical processes inside. This model enables one to simultaneously simulate the battery voltage, internal gas pressures (both PO2 and PH2) and temperature during battery operation.

  15. Characterisation of a Zn / Ni Plating Bath

    Science.gov (United States)

    2009-09-03

    accelerated corrosion in the first stages which is then slowed down by its own product of corrosion, Zn(OH)212. Zinc hydroxide dehydrates in time to form ZnO ... Electrochemistry , 1991, 21, 642 [5] – Alfantasi, A.M., A study on the synthesis, characterization ans properties of pulse-plated ultrafine- grained Zn-Ni alloy

  16. Evidence for an isomer in 76Ni

    International Nuclear Information System (INIS)

    Sawicka, M.; Pfuetzner, M.; Grzywacz, R.; Daugas, J.M.; Belier, G.; Sauvestre, J.E.; Matea, I.; Lewitowicz, M.; Georgiev, G.; Grawe, H.; Mayet, P.; Becker, F.; Bingham, C.; Borcea, R.; Hammache, F.; Ibrahim, F.; Bouchez, E.; Buta, A.; Dragulescu, E.; Giovinazzo, J.; Meot, V.; Negoita, F.; De Oliveira Santos, F.; Perru, O.; Roig, O.; Rykaczewski, K.P.; Saint-Laurent, M.G.; Sorlin, O.; Stanoiu, M.; Stefan, I.; Stodel, C.; Theisen, C.; Verney, D.

    2004-01-01

    In the experiment performed at the LISE2000 spectrometer at GANIL neutron-rich nickel isotopes were studied by microsecond isomer spectroscopy. Evidence for an isomer in 76 Ni is found, consistently with the shell model prediction of an 8 + state of ν(g 9/2 ) 2 structure. (orig.)

  17. Electroplating condition for Ni nanocrystalline on metal (Ni and Cu) plates

    Energy Technology Data Exchange (ETDEWEB)

    Park, Keun Yung; Uhm, Young Rang; Son, Kwang Jae; Shim, Young Ho; Choi, Sun Ju [KAERI, Daejeon (Korea, Republic of)

    2012-10-15

    Ni 63, a beta radiation source, is prepared by the electrical deposition of radioactive Ni 63 ions on a thin non radioactive nickel foil or Cu plate. Given a half life of 100 years, a nuclear battery will still produce half of its initial starting power after 100 years. A speck of a radioisotope like nickel 63, for example, contains enough energy to power a nano nuclear battery for decades, and to do so safely. Ni 63 plating is similar to other electroplating processes that employ soluble metal anodes. It requires the passage of a direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. The charged Ni ions are formed by sulfate, sulfamate, chloride, and a Watts bath. However, the charged Ni 63 ions are formed by dissolving metal Ni 63. To established the coating condition of Ni 63, non radioactive metal Ni particles are dissolved an acid solution and electroplated on a Ni sheet. The nickel plating process is used extensively for decorative, engineering and electro forming purposes because the appearance and other properties of electrodeposited nickel can be varied over a wide range by controlling the composition and operating parameters of the plating solution. A continuous increase in the grain size versus current density has also been recognized in the direct current electrodeposition of nickel coating. On the other hand, A runa et al. reported that the current density has no significant effect on the grain size of nickel electro deposits. A review of the literature shows that saccharin has often been added to a nickel plating bath since the 1980s to improve the ductility and brightness, and in later periods as a grain refiner agent. In the present paper, not only the preparation of a Ni plating solution prepared by dissolving metal particles, but also an optimization of the deposition conditions, such as the current density, saccharin concentration in the bath, and different metal substrates were investigated

  18. Electroplating condition for Ni nanocrystalline on metal (Ni and Cu) plates

    International Nuclear Information System (INIS)

    Park, Keun Yung; Uhm, Young Rang; Son, Kwang Jae; Shim, Young Ho; Choi, Sun Ju

    2012-01-01

    Ni 63, a beta radiation source, is prepared by the electrical deposition of radioactive Ni 63 ions on a thin non radioactive nickel foil or Cu plate. Given a half life of 100 years, a nuclear battery will still produce half of its initial starting power after 100 years. A speck of a radioisotope like nickel 63, for example, contains enough energy to power a nano nuclear battery for decades, and to do so safely. Ni 63 plating is similar to other electroplating processes that employ soluble metal anodes. It requires the passage of a direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. The charged Ni ions are formed by sulfate, sulfamate, chloride, and a Watts bath. However, the charged Ni 63 ions are formed by dissolving metal Ni 63. To established the coating condition of Ni 63, non radioactive metal Ni particles are dissolved an acid solution and electroplated on a Ni sheet. The nickel plating process is used extensively for decorative, engineering and electro forming purposes because the appearance and other properties of electrodeposited nickel can be varied over a wide range by controlling the composition and operating parameters of the plating solution. A continuous increase in the grain size versus current density has also been recognized in the direct current electrodeposition of nickel coating. On the other hand, A runa et al. reported that the current density has no significant effect on the grain size of nickel electro deposits. A review of the literature shows that saccharin has often been added to a nickel plating bath since the 1980s to improve the ductility and brightness, and in later periods as a grain refiner agent. In the present paper, not only the preparation of a Ni plating solution prepared by dissolving metal particles, but also an optimization of the deposition conditions, such as the current density, saccharin concentration in the bath, and different metal substrates were investigated

  19. Synthesis of microporous Ni/NiO nanoparticles with enhanced microwave absorption properties

    International Nuclear Information System (INIS)

    Liu, Tong; Pang, Yu; Xie, Xiubo; Qi, Wen; Wu, Ying; Kobayashi, Satoru; Zheng, Jie; Li, Xingguo

    2016-01-01

    The fabrication of microporous metal materials with many potential applications is challenging due to their high chemical activities and the difficulty in controlling the pore size. By adjusting the reaction condition and the composition of the Ni–Al nanoparticle precursor, we have successfully produced the microporous Ni nanoparticles (NPs) of 22 nm by chemical dealloying method. During the passivation process, the microporous Ni NPs covered with NiO shell are generated as the result of surface oxidation. The micropores range from 0.6 to 1.2 nm in diameter with a large surface area of 68.9 m"2/g. Due to the elimination of Al atoms during dealloying process, the crystalline size of the microporous Ni NPs is sharply decreased to 2–5 nm. The specific architecture offers the microporous Ni/NiO NPs a small microwave reflection coefficient (RC) and a wide absorption bandwidth (RC ≤ −10 dB) of −49.1 dB and 5.8 GHz, much better than the nonporous counterpart of −24.1 dB and 3.7 GHz. The enhanced microwave absorption performance has been interpreted in terms of the micropore structure, core/shell structure and nanostructure effects. - Highlights: • Microporous Ni/NiO nanoparticles are prepared by chemical dealloying method. • They possess micropores of 0.6–1.2 nm with a surface area of 68.9 m"2/g. • They show minimum microwave reflection coefficient of −49.1 dB and bandwidth of 5.8 GHz. • Microwave absorption mechanism is explained by micropore and core/shell structures.

  20. Synthesis of microporous Ni/NiO nanoparticles with enhanced microwave absorption properties

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Tong, E-mail: tongliu@buaa.edu.cn [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing, 100191 (China); Pang, Yu; Xie, Xiubo [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing, 100191 (China); Qi, Wen; Wu, Ying [China Iron & Steel Research Institute Group, Advanced Technology & Materials Co., Ltd, No.76 Xueyuannanlu, Haidian District, Beijing, 100081 (China); Kobayashi, Satoru [Faculty of Engineering, Iwate University, Ueda, Morioka, 020-8551 (Japan); Zheng, Jie; Li, Xingguo [Beijing National Laboratory for Molecular Sciences (BNLMS), The State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871 (China)

    2016-05-15

    The fabrication of microporous metal materials with many potential applications is challenging due to their high chemical activities and the difficulty in controlling the pore size. By adjusting the reaction condition and the composition of the Ni–Al nanoparticle precursor, we have successfully produced the microporous Ni nanoparticles (NPs) of 22 nm by chemical dealloying method. During the passivation process, the microporous Ni NPs covered with NiO shell are generated as the result of surface oxidation. The micropores range from 0.6 to 1.2 nm in diameter with a large surface area of 68.9 m{sup 2}/g. Due to the elimination of Al atoms during dealloying process, the crystalline size of the microporous Ni NPs is sharply decreased to 2–5 nm. The specific architecture offers the microporous Ni/NiO NPs a small microwave reflection coefficient (RC) and a wide absorption bandwidth (RC ≤ −10 dB) of −49.1 dB and 5.8 GHz, much better than the nonporous counterpart of −24.1 dB and 3.7 GHz. The enhanced microwave absorption performance has been interpreted in terms of the micropore structure, core/shell structure and nanostructure effects. - Highlights: • Microporous Ni/NiO nanoparticles are prepared by chemical dealloying method. • They possess micropores of 0.6–1.2 nm with a surface area of 68.9 m{sup 2}/g. • They show minimum microwave reflection coefficient of −49.1 dB and bandwidth of 5.8 GHz. • Microwave absorption mechanism is explained by micropore and core/shell structures.

  1. Geometric structures of thin film: Pt on Pd(110) and NiO on Ni(100)

    Energy Technology Data Exchange (ETDEWEB)

    Warren, Oden L. [Iowa State Univ., Ames, IA (United States)

    1993-07-01

    This thesis is divided into 3 papers: dynamical low-energy electron- diffraction investigation of lateral displacements in topmost layer of Pd(110); determination of (1x1) and (1x2) structures of Pt thin films on Pd(110) by dynamical low-energy electron-diffraction analysis; and structural determination of a NiO(111) film on Ni(100) by dynamical low-energy electron-diffraction analysis.

  2. Fabrication and tensile properties of rapidly solidified Cu-10wt. %Ni alloy. [Cu-10Ni

    Energy Technology Data Exchange (ETDEWEB)

    Baril, D; Angers, R; Baril, J [Dept. of Mining and Metallurgy, Laval Univ., Ste-Foy, Quebec (Canada)

    1992-10-15

    Cu-10wt.%Ni ribbons were produced by melt spinning and cut into small particles with a blade cutter mill. The powders were then hot consolidated to full density by hot pressing followed by hot extrusion. Tensile properties of the resulting pieces were measured. Cu-10wt.%Ni cast ingots were also hot extruded and mechanically tested to compare with the rapidly solidified alloy and to evaluate the possible benefits brought by the rapid solidification process.

  3. 59Ni and 63Ni separation from boric acid concentrates produced at NPP

    International Nuclear Information System (INIS)

    Fisera, O.

    2010-01-01

    Procedure for direct separation of radionickel from boric acid concentrate was developed. Quantitative separation from 100 mL of real concentrate on the column filled with 3 mL of PAN-DMG composite material was achieved. PAN-DMG material (dimethylglyoxime in porous beads of polyacrylonitrile) was compared with Ni Resin and DMG-PAN material exhibited higher sorption capacity for nickel than Ni Resin. (author)

  4. Valence electronic structure of Ni in Ni Si alloys from relative K X-ray intensity studies

    Science.gov (United States)

    Kalayci, Y.; Aydinuraz, A.; Tugluoglu, B.; Mutlu, R. H.

    2007-02-01

    The Kβ-to-Kα X-ray intensity ratio of Ni in Ni 3Si, Ni 2Si and NiSi has been determined by energy dispersive X-ray fluorescence technique. It is found that the intensity ratio of Ni decreases from pure Ni to Ni 2Si and then increases from Ni 2Si to NiSi, in good agreement with the electronic structure calculations cited in the literature. We have also performed band structure calculations for pure Ni in various atomic configurations by means of linear muffin-tin orbital method and used this data with the normalized theoretical intensity ratios cited in the literature to estimate the 3d-occupation numbers of Ni in Ni-Si alloys. It is emphasized that investigation of alloying effect in terms of X-ray intensity ratios should be carried out for the stoichiometric alloys in order to make reliable and quantitative comparisons between theory and experiment in transition metal alloys.

  5. La Niña, El Niño, and Atlantic Hurricane Damages in the United States

    Science.gov (United States)

    data discussed below), this definition results in 22 El Niño years, 29 neutral years, and 22 La Niña accounting for the most significant societal changes. To normalize past impacts data to 1997 values, losses , 169 and 186. Trenberth, K. E., 1997: The definition of El Niño. Bull. Amer. Meteor. Soc., 78, 2771

  6. Observations of defect structure evolution in proton and Ni ion irradiated Ni-Cr binary alloys

    Energy Technology Data Exchange (ETDEWEB)

    Briggs, Samuel A., E-mail: sabriggs2@wisc.edu [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); Barr, Christopher M. [Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104 (United States); Pakarinen, Janne [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); SKC-CEN Belgian Nuclear Research Centre, Boeretang 200, B-2400 Mol (Belgium); Mamivand, Mahmood [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); Hattar, Khalid [Sandia National Laboratories, PO Box 5800, Albuquerque, NM 87185 (United States); Morgan, Dane D. [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); Taheri, Mitra [Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104 (United States); Sridharan, Kumar [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States)

    2016-10-15

    Two binary Ni-Cr model alloys with 5 wt% Cr and 18 wt% Cr were irradiated using 2 MeV protons at 400 and 500 °C and 20 MeV Ni{sup 4+} ions at 500 °C to investigate microstructural evolution as a function of composition, irradiation temperature, and irradiating ion species. Transmission electron microscopy (TEM) was applied to study irradiation-induced void and faulted Frank loops microstructures. Irradiations at 500 °C were shown to generate decreased densities of larger defects, likely due to increased barriers to defect nucleation as compared to 400 °C irradiations. Heavy ion irradiation resulted in a larger density of smaller voids when compared to proton irradiations, indicating in-cascade clustering of point defects. Cluster dynamics simulations were in good agreement with the experimental findings, suggesting that increases in Cr content lead to an increase in interstitial binding energy, leading to higher densities of smaller dislocation loops in the Ni-18Cr alloy as compared to the Ni-5Cr alloy. - Highlights: • Binary Ni-Cr alloys were irradiated with protons or Ni ions at 400 and 500 °C. • Higher irradiation temperatures yield increased size, decreased density of defects. • Hypothesize that varying Cr content affects interstitial binding energy. • Fitting CD models for loop nucleation to data supports this hypothesis.

  7. Study of the magnetic anisotropy in Ni/Cu and Ni/glass thin films

    Energy Technology Data Exchange (ETDEWEB)

    Cherif, S.-M. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse, 93340 (France); Layadi, A. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria)]. E-mail: a_layadi@yahoo.fr; Ben Youssef, J. [Laboratoire de Magnetisme de Bretagne, U.B.O., Brest 29238 (France); Nacereddine, C. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria); Roussigne, Y. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse, 93340 (France)

    2007-01-01

    The magnetic properties of evaporated Ni/Cu and Ni/glass thin films have been investigated by means of the vibrating sample magnetometer (VSM), the Brillouin light scattering (BLS) and magnetic force microscopy (MFM). The Ni thickness, t, ranges from 31 to 165 nm. The second- and fourth-order magnetic anisotropy constants, K {sub 1} and K {sub 2}, have been included; for the Ni/Cu series, K {sub 1} was found to decrease from 1.0x10{sup 6} to 0.18x10{sup 6} erg/cm{sup 3} as t increases from 31 to 165 nm, while K {sub 2} increased from 0.24x10{sup 6} to 0.8x10{sup 6} erg/cm{sup 3}. Over all the thickness range, the magnetization easy axis is in plane. For thinner films, there is a good agreement between anisotropy constant values inferred from VSM and BLS. Stripe domains were observed for t{>=}165 nm in Ni/glass and t{>=}90 nm in Ni/Cu.

  8. Study of the magnetic anisotropy in Ni/Cu and Ni/glass thin films

    International Nuclear Information System (INIS)

    Cherif, S.-M.; Layadi, A.; Ben Youssef, J.; Nacereddine, C.; Roussigne, Y.

    2007-01-01

    The magnetic properties of evaporated Ni/Cu and Ni/glass thin films have been investigated by means of the vibrating sample magnetometer (VSM), the Brillouin light scattering (BLS) and magnetic force microscopy (MFM). The Ni thickness, t, ranges from 31 to 165 nm. The second- and fourth-order magnetic anisotropy constants, K 1 and K 2 , have been included; for the Ni/Cu series, K 1 was found to decrease from 1.0x10 6 to 0.18x10 6 erg/cm 3 as t increases from 31 to 165 nm, while K 2 increased from 0.24x10 6 to 0.8x10 6 erg/cm 3 . Over all the thickness range, the magnetization easy axis is in plane. For thinner films, there is a good agreement between anisotropy constant values inferred from VSM and BLS. Stripe domains were observed for t≥165 nm in Ni/glass and t≥90 nm in Ni/Cu

  9. Effect of Ni4Ti3 precipitation on martensitic transformation in Ti-Ni

    International Nuclear Information System (INIS)

    Zhou, N.; Shen, C.; Wagner, M.F.-X.; Eggeler, G.; Mills, M.J.; Wang, Y.

    2010-01-01

    Precipitation of Ni 4 Ti 3 plays a critical role in determining the martensitic transformation path and temperature in Ni-Ti shape memory alloys. In this study, the equilibrium shape of a coherent Ni 4 Ti 3 precipitate and the concentration and stress fields around it are determined quantitatively using the phase field method. Most recent experimental data on lattice parameters, elastic constants, precipitate-matrix orientation relationship and thermodynamic database are used as model inputs. The effects of the concentration and stress fields on subsequent martensitic transformations are analyzed through interaction energy between a nucleating martensitic particle and the existing microstructure. Results indicate that R-phase formation prior to B19' phase could be attributed to both direct elastic interaction and stress-induced spatial variation in concentration near Ni 4 Ti 3 precipitates. The preferred nucleation sites for the R-phase are close to the broad side of the lenticular-shaped Ni 4 Ti 3 precipitates, where tension normal to the habit plane is highest, and Ni concentration is lowest.

  10. Fabrication of metallic alloy powder (Ni{sub 3}Fe) from Fe–77Ni scrap

    Energy Technology Data Exchange (ETDEWEB)

    Seo, Inseok [ES Materials Research Center, Research Institute of Industrial Science and Technology, Incheon 406-840 (Korea, Republic of); Shin, Shun-Myung [Extractive Metallurgy Department, Korea Institute of Geoscience and Mineral Resources, Deajeon 305-350 (Korea, Republic of); Ha, Sang-An [Department of Environmental Engineering, Silla University, Busan 46958 (Korea, Republic of); Wang, Jei-Pil, E-mail: jpwang@pknu.ac.kr [Department of Metallurgical Engineering, Pukyong National University, Busan 608-739 (Korea, Republic of)

    2016-06-15

    The oxidation behavior of Fe–77Ni alloy scrap was investigated at an oxygen partial pressure of 0.2 atm and temperatures ranging from 400 °C to 900 °C. The corresponding oxidation rate increased with increasing temperature and obeyed the parabolic rate law, as evidenced by its linear proportionality to the temperature. In addition, surface morphologies, cross-sectional views, compositions, structural properties were examined by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). Diffusion through either the spinel structure or the NiO layer, which were both present in the alloy during oxidation at elevated temperatures, was deemed the rate-limiting step of the reaction. The oxide powder less than 10 μm was obtained from Fe–77Ni alloy scrap was obtained using ball-milling and sieving processes. In fact, 15 h of milling yielded a recovery ratio of 97%. Using hydrogen gas, the oxide powder was successfully reduced to an alloy powder of Ni{sub 3}Fe and reduction rates of ∼97% were achieved after 3 h at 1000 °C. - Highlights: • The oxidation behavior of Fe–77Ni alloy scrap was investigated. • The oxide powder less than 10 μm was obtained from Fe–77Ni alloy scrap. • Using hydrogen gas, the oxide powder was successfully reclaimed. • Reduction rates of ∼97% were achieved after 3 h at 1000 °C.

  11. Positron annihilation studies in CeNiIn and LaNiIn

    International Nuclear Information System (INIS)

    Ray, R.; Giri, S.; Sen, M.; Nambissan, P.M.G.; Ghoshray, K.; Ghoshray, A.; Sen, P.

    1997-01-01

    Doppler broadened positron annihilation spectral lineshape (DBPAS) and positron lifetime measurements in the temperature range 18-280 K have been performed in CeNiIn and LaNiIn systems. The nature of the temperature variations of the lifetime in both systems is almost similar in the whole temperature range studied, whereas the nature of the temperature variation of the S parameter in CeNiIn is similar to that in LaNiIn except in the temperature region 18-40 K. For the former system there is a dip around 20 K in the S parameter versus temperature curve. The lifetime versus T curve in both systems could be explained by the thermal expansion of the lattice. The S parameter versus T curve in LaNiIn could also be attributed to the thermal expansion of the lattice, whereas in CeNiIn the above mentioned dip seems an extra feature of the thermal expansion of the lattice. To understand this low temperature behaviour other results on the same system have been discussed. (orig.)

  12. Interfacial reaction of Ni{sub 3}Sn{sub 4} intermetallic compound in Ni/SnAg solder/Ni system under thermomigration

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Yi-Shan; Yang, Chia-Jung; Ouyang, Fan-Yi, E-mail: fyouyang@ess.nthu.edu.tw

    2016-07-25

    The growth of Ni{sub 3}Sn{sub 4} intermetallic compound (IMC) between liquid–solid interface in micro-scale Ni/SnAg/Ni system was investigated under a temperature gradient of 160 °C/cm at 260 °C on a hot plate. In contrast to a symmetrical growth of Ni{sub 3}Sn{sub 4} on both interfaces under isothermally annealed at 260 °C, the interfacial Ni{sub 3}Sn{sub 4} IMC exhibited asymmetric growth under a temperature gradient; the growth of Ni{sub 3}Sn{sub 4} at cold interface was faster than that at hot side because of temperature gradient induced mass migration of Ni atoms from the hot end toward the cold end. It was found that two-stage growth behavior of Ni{sub 3}Sn{sub 4} IMC under a temperature gradient. A growth model was established and growth kinetic analysis suggested that the chemical potential gradient controlled the growth of Ni{sub 3}Sn{sub 4} at stage I (0–120 min) whereas the dynamic equilibrium between chemical potential gradient and temperature gradient forces was attained at the hot end at stage II (120–210 min). When dynamic equilibrium was achieved at 260 °C, the critical length-temperature gradient product at the hot end was experimentally estimated to be 489.18 μm × °C/cm and the moving velocity of Ni{sub 3}Sn{sub 4} interface due to Ni consumption was calculated to be 0.134 μm/h. The molar heat of transport (Q*) of Ni atoms in molten SnAg solder was calculated to be +0.76 kJ/mol. - Highlights: • Interfacial reaction in Ni/SnAg solder/Ni system under thermal gradient. • Growth rate of Ni{sub 3}Sn{sub 4} at cold end is faster than that at hot end. • Critical length-temperature gradient product at hot end is 489.2 μm°C/cm at 260 °C. • Velocity of Ni{sub 3}Sn{sub 4} moving interface is 0.134 μm/h during dynamic equilibrium. • Molar heat of transport (Q*) of Ni in molten SnAg was +0.76 kJ/mol.

  13. Evaluation of the Antitumor Activity by Ni Nanoparticles with Verbascoside

    Directory of Open Access Journals (Sweden)

    Mingyue Chen

    2013-01-01

    Full Text Available Verbascoside (VB has attracted a great deal of attention due to ITS pharmacological properties. In our study, we synthesized a multifunctional verbascoside coated Ni nanoparticles (VB-Ni. Transmission electron microscopy (TEM and high performance liquid chromatography (HPLC display the characteristics of VB-Ni nanoparticles. Compared with VB, VB-Ni has been proven to induce apoptosis and resist the growth of doxorubicin-resistant K562 cells in vitro and in vivo. Thus, VB-Ni nanoparticles can be thought of as an ideal mode of cancer treatment.

  14. A Study on Production of Carbon Nanotubes by CH4 Decomposition over LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Carbon nanotubes (CNTs) of narrow size distribution can be abundantly produced in the catalytic decomposition of CH4 over pre-reduced LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4.The CNTs obtained were characterized by means of transmission electron microscopy (TEM).Thermal oxidation of CNTs in air was monitored thermogravimetrically (TG). The resultsrevealed that a lower La/Ni ratio of the catalysts would lead to a wider diameter distribution and a higher degree of graphitic nature.

  15. Thin NiTi Films Deposited on Graphene Substrates

    Science.gov (United States)

    Hahn, S.; Schulze, A.; Böhme, M.; Hahn, T.; Wagner, M. F.-X.

    2017-03-01

    We present experimental results on the deposition of Nickel Titanium (NiTi) films on graphene substrates using a PVD magnetron sputter process. Characterization of the 2-4 micron thick NiTi films by electron microscopy, electron backscatter diffraction, and transmission electron microscopy shows that grain size and orientation of the thin NiTi films strongly depend on the type of combination of graphene and copper layers below. Our experimental findings are supported by density functional theory calculations: a theoretical estimation of the binding energies of different NiTi-graphene interfaces is in line with the experimentally determined microstructural features of the functional NiTi top layer.

  16. Properties of mechanically alloyed Mg-Ni-Ti ternary hydrogen storage alloys for Ni-MH batteries

    Science.gov (United States)

    Ruggeri, Stéphane; Roué, Lionel; Huot, Jacques; Schulz, Robert; Aymard, Luc; Tarascon, Jean-Marie

    MgNiTi x, Mg 1- xTi xNi and MgNi 1- xTi x (with x varying from 0 to 0.5) alloys have been prepared by high energy ball milling and tested as hydrogen storage electrodes. The initial discharge capacities of the Mg-Ni-Ti ternary alloys are inferior to the MgNi electrode capacity. However, an exception is observed with MgNi 0.95Ti 0.05, which has an initial discharge capacity of 575 mAh/g compared to 522 mAh/g for the MgNi electrode. The Mg-Ni-Ti ternary alloys show improved cycle life compared to Mg-Ni binary alloys with the same Mg/Ni atomic ratio. The best cycle life is observed with Mg 0.5Ti 0.5Ni electrode which retains 75% of initial capacity after 10 cycles in comparison to 39% for MgNi electrodes, in addition to improved high-rate dischargeability (HRD). According to the XPS analysis, the cycle life improvement of the Mg 0.5Ti 0.5Ni electrode can be related to the formation of TiO 2 which limits Mg(OH) 2 formation. The anodic polarization curve of Mg 0.5Ti 0.5Ni electrode shows that the current related to the active/passive transition is much less important and that the passive region is more extended than for the MgNi electrode but the corrosion of the electrode is still significant. This suggests that the cycle life improvement would be also associated with a decrease of the particle pulverization upon cycling.

  17. Densities of molten Ni-(Cr, Co, W) superalloys

    Institute of Scientific and Technical Information of China (English)

    XIAO Feng; YANG Ren-hui; FANG Liang; LIU Lan-xiao; ZHAO Hong-kai

    2008-01-01

    In order to obtain more accurate density for molten Ni-(Cr, Co, W) binary alloy, the densities of molten pure Ni and Ni-Cr, Ni-Co, Ni-W alloys were measured with a sessile drop method. It is found that the measured densities of molten pure Ni and Ni-Cr, Ni-Co, Ni-W alloys decrease with increasing temperature in the experimental temperature range. The density of alloys increases with increasing W and Co concentrations while it decreases with increasing Cr concentration in the alloy at 1 773-1 873 K. The molar volume of Ni-based alloys increases with increasing W concentration while it decreases with increasing Co concentration. The effect of Cr concentration on the molar volume of the alloy is little in the studied concentration range. The accommodation among atomic species was analyzed. The deviation of molar volume from ideal mixing shows an ideal mixing of Ni-(Cr, Co, W) binary alloys.

  18. Spectroscopic investigation of Ni speciation in hardened cement paste.

    Science.gov (United States)

    Vespa, M; Dähn, R; Grolimund, D; Wieland, E; Scheidegger, A M

    2006-04-01

    Cement-based materials play an important role in multi-barrier concepts developed worldwide for the safe disposal of hazardous and radioactive wastes. Cement is used to condition and stabilize the waste materials and to construct the engineered barrier systems (container, backfill, and liner materials) of repositories for radioactive waste. In this study, Ni uptake by hardened cement paste has been investigated with the aim of improving our understanding of the immobilization process of heavy metals in cement on the molecular level. X-ray absorption spectroscopy (XAS) coupled with diffuse reflectance spectroscopy (DRS) techniques were used to determine the local environment of Ni in cement systems. The Ni-doped samples were prepared at two different water/cement ratios (0.4, 1.3) and different hydration times (1 hour to 1 year) using a sulfate-resisting Portland cement. The metal loadings and the metal salts added to the system were varied (50 up to 5000 mg/kg; NO3(-), SO4(2-), Cl-). The XAS study showed that for all investigated systems Ni(ll) is predominantly immobilized in a layered double hydroxide (LDH) phase, which was corroborated by DRS measurements. Only a minor extent of Ni(ll) precipitates as Ni-hydroxides (alpha-Ni(OH)2 and beta-Ni(OH)2). This finding suggests that Ni-Al LDH, rather than Ni-hydroxides, is the solubility-limiting phase in the Ni-doped cement system.

  19. Design and fabrication of Ni nanowires having periodically hollow nanostructures.

    Science.gov (United States)

    Sada, Takao; Fujigaya, Tsuyohiko; Nakashima, Naotoshi

    2014-10-07

    We propose a concept for the design and fabrication of metal nanowires having periodically hollow nanostructures inside the pores of an anodic aluminum oxide (AAO) membrane using a sacrificial metal. In this study, nickel (Ni) and silver (Ag) were used as the base metal and the sacrificial metal, respectively. Alternating an applied potential between -0.4 and -1.0 V provided alternatively deposited Ni and Ag segments in a Ni-Ag 'barcode' nanowire with a diameter of 18 or 35 nm. After etching away the Ag segments, we fabricated Ni nanowires with nanopores of 12 ± 5.3 nm. Such nanostructure formation is explained by the formation of a Ni shell layer over the surface of the Ag segments due to the strong affinity of Ni(2+) for the interior surfaces of AAO. The Ni shell layer allows the Ni segments to remain even after dissolution of the Ag segments. Because the electroplating conditions can be easily controlled, we could carefully adjust the size and pitch of the periodically hollow nanospaces. We also describe a method for the fabrication of Ni nanorods by forming an Ag shell instead of a Ni shell on the Ni-Ag barcode nanowire, in which the interior of the AAO surfaces was modified with a compound bearing a thiol group prior to electroplating.

  20. Ductility of Ni3Al doped with substitutional elements

    International Nuclear Information System (INIS)

    Hanada, S.; Chiba, A.; Guo, H.Z.; Watanabe, S.

    1993-01-01

    This paper reports on ductility of B-free Ni 3 Al alloys. Recrystallized Ni 3 Al binary alloys with Ni-rich compositions show appreciable ductility when an environmental effect is eliminated, while the alloys with stoichiometric and Al-rich compositions remain brittle. The ductility in the Ni-rich Ni 3 Al alloys is associated with low ordering energy. The additions of ternary elements, which are classified as γ formers, ductilize ternary Ni 3 Al alloys(Ni-23 at% Al-2 at% X, X = Pd, Pt, Cu and Co), whereas the additions of γ' formers embrittle ternary Ni 3 Al alloys(Ni-23 at% Al-2 at% X, X = Ta, Mo, Nb, Zr, Hf, V, Ti and Si). The additions of small amounts (less than 1 at%) of γ' formers such as Zr and Hf also ductilize as-cast ternary Ni 3 Al alloys. Ductility of Ni 3 Al alloys doped with substitutional elements is discussed in terms of ordering energy and microstructure

  1. CO2 activation on bimetallic CuNi nanoparticles

    Directory of Open Access Journals (Sweden)

    Natalie Austin

    2016-10-01

    Full Text Available Density functional theory calculations have been performed to investigate the structural, electronic, and CO2 adsorption properties of 55-atom bimetallic CuNi nanoparticles (NPs in core-shell and decorated architectures, as well as of their monometallic counterparts. Our results revealed that with respect to the monometallic Cu55 and Ni55 parents, the formation of decorated Cu12Ni43 and core-shell Cu42Ni13 are energetically favorable. We found that CO2 chemisorbs on monometallic Ni55, core-shell Cu13Ni42, and decorated Cu12Ni43 and Cu43Ni12, whereas, it physisorbs on monometallic Cu55 and core-shell Cu42Ni13. The presence of surface Ni on the NPs is key in strongly adsorbing and activating the CO2 molecule (linear to bent transition and elongation of C˭O bonds. This activation occurs through a charge transfer from the NPs to the CO2 molecule, where the local metal d-orbital density localization on surface Ni plays a pivotal role. This work identifies insightful structure-property relationships for CO2 activation and highlights the importance of keeping a balance between NP stability and CO2 adsorption behavior in designing catalytic bimetallic NPs that activate CO2.

  2. NiCo2S4 nanosheet-decorated 3D, porous Ni film@Ni wire electrode materials for all solid-state asymmetric supercapacitor applications.

    Science.gov (United States)

    Saravanakumar, Balasubramaniam; Jayaseelan, Santhana Sivabalan; Seo, Min-Kang; Kim, Hak-Yong; Kim, Byoung-Suhk

    2017-12-07

    Wire type supercapacitors with high energy and power densities have generated considerable interest in wearable applications. Herein, we report a novel NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire electrode for high performance supercapacitor application. In this work, a facile method is introduced to fabricate a 3D, porous Ni film deposited on a Ni wire as a flexible electrode, followed by decoration with NiCo 2 S 4 as an electroactive material. The fabricated NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire electrode displays a superior performance with an areal and volumetric capacitance of 1.228 F cm -2 and 199.74 F cm -3 , respectively, at a current density of 0.2 mA cm -1 with a maximum volumetric energy and power density (E V : 6.935 mW h cm -3 ; P V : 1.019 W cm -3 ). Finally, the solid state asymmetric wire type supercapacitor is fabricated using the fabricated NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire as a positive electrode and N-doped reduced graphene oxide (N-rGO) as a negative electrode and this exhibits good areal and volumetric capacitances of C A : 0.12 F cm -2 and C V : 19.57 F cm -2 with a higher rate capability (92%). This asymmetric wire type supercapacitor demonstrates a low leakage current and self-discharge with a maximum volumetric energy (E V : 5.33 mW h cm -3 ) and power (P V : 855.69 mW cm -3 ) density.

  3. Surface morphology and electronic structure of Ni/Ag(100)

    International Nuclear Information System (INIS)

    Hite, D. A.; Kizilkaya, O.; Sprunger, P. T.; Howard, M. M.; Ventrice, C. A. Jr.; Geisler, H.; Zehner, D. M.

    2000-01-01

    The growth morphology and electronic structure of Ni on Ag(100) has been studied with scanning tunneling microscopy (STM) and synchrotron based angle resolved photoemission spectroscopy. At deposition temperatures at or below 300 K, STM reveals Ni cluster growth on the surface along with some subsurface growth. Upon annealing to 420 K, virtually all Ni segregates into the subsurface region forming embedded nanoclusters. The electronic structure of Ni d bands in the unannealed surface shows dispersion only perpendicular to the surface whereas the annealed surface has Ni d bands that exhibit a three-dimensional-like structure. This is a result of the increased Ni d-Ag sp hybridization bonding and increased coordination of the embedded Ni nanoclusters. (c) 2000 American Vacuum Society

  4. Measurement and analyses of molten Ni-Co alloy density

    Institute of Scientific and Technical Information of China (English)

    XIAO Feng; K. MUKAI; FANG Liang; FU Ya; YANG Ren-hui

    2006-01-01

    With the advent of powerful mathematical modeling techniques for material phenomena, there is renewed interest in reliable data for the density of the Ni-based superalloys. Up to now, there has been few report on the density of molten Ni-Co alloy.In order to obtain more accurate density data for molten Ni-Co alloy, the density of molten Ni-Co alloy was measured with a modified sessile drop method, and the accommodation of different atoms in molten Ni-Co alloy was analyzed. The density of alloy is found to decrease with increasing temperature and Co concentration in the alloy. The molar volume of molten Ni-Co alloy increases with increasing Co concentration. The molar volume of Ni-Co alloy determined shows a positive deviation from the linear molar volume, and the deviation of molar volume from ideal mixing increases with increasing Co concentration over the experimental concentration range.

  5. In situ NiTi/Nb(Ti) composite

    International Nuclear Information System (INIS)

    Jiang, Daqiang; Cui, Lishan; Jiang, Jiang; Zheng, Yanjun

    2013-01-01

    Graphical abstract: - Highlights: • In situ NiTi/Nb(Ti) composites were fabricated. • The transformation temperature was affected by the mixing Ti:Ni atomic ratios. • The NiTi component became micron-scale lamella after forging and rolling. • The composite exhibited high strength and high damping capacity. - Abstract: This paper reports on the creation of a series of in situ NiTi/Nb(Ti) composites with controllable transformation temperatures based on the pseudo-binary hypereutectic transformation of NiTi–Nb system. The composite constituent morphology was controlled by forging and rolling. It is found that the thickness of the NiTi lamella in the composite reached micron level after the hot-forging and cold-rolling. The NiTi/Nb(Ti) composite exhibited high damping capacity as well as high yield strength

  6. Ni3d-Gd4f correlation effects on the magnetic behaviour of GdNi

    Energy Technology Data Exchange (ETDEWEB)

    Paulose, P L [Tata Inst. of Fundamental Research, Bombay (India); Patil, Sujata [Tata Inst. of Fundamental Research, Bombay (India); Mallik, R [Tata Inst. of Fundamental Research, Bombay (India); Sampathkumaran, E V [Tata Inst. of Fundamental Research, Bombay (India); Nagarajan, V [Tata Inst. of Fundamental Research, Bombay (India)

    1996-07-01

    The results of magnetization and heat-capacity measurements on the alloys, Gd{sub 1-x}Y{sub x}Ni (x=0.0, 0.25, 0.5, 0.75 and 0.9) are reported. The data suggest that there is a Gd induced magnetic moment on Ni, which may in turn enhance Gd-Gd exchange interaction strength in GdNi. The induced moment (on Ni) apparently exhibits itinerant ferromagnetism in the magnetically ordered state of GdNi. (orig.).

  7. Effects of Bond Coating on NiCrBSi-Mo Composite Functional Coating Properties in Plasma Spraying NiCrBSi-Mo/Ni Coating

    OpenAIRE

    DU Ji-yu; LI Fang-yi; LU Hai-yang; SHANG Jian-tong; LI Zhen

    2017-01-01

    Nickel-based bond coating and composite functional coating were sprayed on leaf blade steel material FV520B successively by using air plasma spraying system. NiCrBSi-Mo powder deposition rate, coating porosity, bonding strength and surface hardness were tested. The results indicate that, for the NiCrBSi-Mo/Ni coating, bond coating with 180-220μm thickness can improve NiCrBSi-Mo powder deposition rate while the surface coating with lower porosity, higher bonding strength and high hardness is p...

  8. Thermodynamic characterization of Ni3TeO6, Ni2Te3O8 and NiTe2O5

    Science.gov (United States)

    Dawar, Rimpi; Babu, R.; Ananthasivan, K.; Anthonysamy, S.

    2017-09-01

    Measurement of vapour pressure of TeO2(g) over the biphasic mixture Ni3TeO6 (s) + NiO(s) in the temperature range 1143-1272 K was carried out using transpiration-thermogravimetric technique (TTG). Gibbs energy of formation of Ni3TeO6 was obtained from the temperature dependence of vapour pressure of TeO2 (g) generated by the incongruent vapourisation reaction, Ni3TeO6 (s) → NiO(s) + TeO2 (g) + 1/2 O2 in the temperature range 1143-1272 K. An isoperibol type drop calorimeter was used to measure the enthalpy increments of Ni3TeO6, Ni2Te3O8 and NiTe2O5. Thermodynamic functions viz., heat capacity, entropy and Gibbs energy functions of these compounds were derived from the experimentally measured enthalpy increment values. Third-law analysis was carried out to ascertain absence of temperature dependent systematic errors in the measurement of vapour pressure of TeO2 (g). A value of -1265.1 ± 1.5 kJ mol-1 was obtained for Δ Hf,298K o (Ni3TeO6) using third-law analysis.

  9. Structural and magnetic properties of Ni-Zn and Ni-Zn-Co ferrites

    Energy Technology Data Exchange (ETDEWEB)

    Knyazev, A.V., E-mail: knyazevav@gmail.com [N.I. Lobachevsky State University of Nizhni Novgorod, Gagarin Prospekt 23/2, 603950 Nizhni Novgorod (Russian Federation); Zakharchuk, I.; Lähderanta, E. [Lappeenranta University of Technology, P.O. Box 20, FI-53851 Lappeenranta (Finland); Baidakov, K.V.; Knyazeva, S.S. [N.I. Lobachevsky State University of Nizhni Novgorod, Gagarin Prospekt 23/2, 603950 Nizhni Novgorod (Russian Federation); Ladenkov, I.V. [Joint-stock Company “Research and Production Company “Salut”, Nizhni Novgorod (Russian Federation)

    2017-08-01

    Highlights: • Ni-Zn and Ni-Zn-Co ferrite powders were prepared by the solid-state reaction at 1073 K. • The room temperature saturation magnetizations are 59.7 emu/g for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 57.1 emu/g for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. • The coercivity of the samples is found to be much larger than that of bulk ferrites and increases with Co introduction. • The temperature dependences of magnetization exhibit large spin frustration and spin-glass-like behavior. - Abstract: Ni-Zn and Ni-Zn-Co ferrite powders with nominal compositions Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4} were prepared by the solid-state reaction synthesis with periodic regrinding during the calcination at 1073 K. The structure of Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4} was refined assuming space group F d-3m. Scanning electron microscopy revealed the average sizes of the crystalline ferrite particles are 130–630 nm for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 140–350 nm for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. The room temperature saturation magnetizations are 59.7 emu/g for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 57.1 emu/g for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. The coercivity of the samples is found to be much larger than that of bulk ferrites and increases with Co introduction. The Curie temperature tends to increase upon Zn substitution by Co, as well. The temperature dependences of magnetization measured using zero-field cooled and field cooled protocols exhibit large spin frustration and spin-glass-like behavior.

  10. Anti-corrosive and anti-microbial properties of nanocrystalline Ni-Ag coatings

    Energy Technology Data Exchange (ETDEWEB)

    Raghupathy, Y.; Natarajan, K.A.; Srivastava, Chandan, E-mail: csrivastava@materials.iisc.ernet.in

    2016-04-15

    Graphical abstract: - Highlights: • Electrodeposition yielded phase-segregated, nanocrystalline Ni-Ag coatings. • Ni-Ag alloys exhibited smaller Ni crystals compared to pure Ni. • Ultra fine Ni grains of size 12–14 nm favoured Ni-Ag solid solution. • Nanocrystalline Ag resisted bio-fouling by Sulphate Reducing bacteria. • Ni-Ag outperformed pure Ni in corrosion and bio-corrosion tests. - Abstract: Anti-corrosive and anti-bacterial properties of electrodeposited nanocrystalline Ni-Ag coatings are illustrated. Pure Ni, Ni-7 at.% Ag, & Ni-14 at.% Ag coatings were electrodeposited on Cu substrate. Coating consisted of Ni-rich and Ag-rich solid solution phases. With increase in the Ag content, the corrosion resistance of the Ni-Ag coating initially increased and then decreased. The initial increase was due to the Ni-Ag solid solution. The subsequent decrease was due to the increased galvanic coupling between the Ag-rich and Ni-rich phases. For all Ag contents, the corrosion resistance of the Ni-Ag coating was higher than the pure Ni coating. Exposure to Sulphate Reducing Bacteria (SRB) revealed that the extent of bio-fouling decreased with increase in the Ag content. After 2 month exposure to SRB, the Ni-Ag coatings demonstrated less loss in corrosion resistance (58% for Ni-7 at.% Ag and 20% for Ni-14 at.% Ag) when compared pure Ni coating (115%).

  11. Niños y niñas como cuidadores familiares

    Directory of Open Access Journals (Sweden)

    María Rosa Estupiñán Aponte

    2015-01-01

    Full Text Available En el contexto familiar, el cuidado de otra persona por parte de niños y niñas constituye un terreno inexplorado tanto en su significado como en las implicaciones que podrían darse en el proceso. Aunque históricamente se ha asignado el cuidado familiar a las mujeres generando condiciones de inequidad, incrementada con los cambios sociales de los últimos tiempos, es necesario reconocer que en muchos hogares niños y niñas se han visto obligados a desempeñar esta labor sin la preparación ni las destrezas necesarias. Desde una perspectiva de género, el artículo busca evidenciar esta situación mediante la revisión de los abordajes que sobre el tema se han hecho en países de Europa y Norteamérica, así como el análisis de información obtenida a partir de las Encuestas de Hogares y Uso del Tiempo (EUT en algunos países de Latinoamérica. Se establece la forma como las problemáticas sociales inciden en las dinámicas, tipo de tareas y responsabilidades que deben asumir niños y niñas en los hogares, mostrando delgados límites entre la colaboración al interior de las familias, la transmisión cultural de roles y funciones y las actividades que podrían incidir negativamente en su crecimiento y el ejercicio de sus derechos.

  12. Estilos de vida saludables de niños, niñas y adolescentes

    Directory of Open Access Journals (Sweden)

    Lilia Campo-Ternera

    2017-01-01

    Full Text Available Objetivo: Describir los estilos de vida saludables de niños, niñas y adolescentes de Barranquilla. Materiales y métodos: Estudio descriptivo de corte transversal en 991 niños, niñas y ado - lescentes. Se evaluó la actividad física mediante los cuestionarios de Actividad Física para Adolescentes y para niños escolares; se aplicó una encuesta que midió los conocimientos y prácticas de los escolares sobre salud bucal, lavado de manos, consumo de frutas y verduras y cuidado postural; la Lista de Chequeo “Mi Vida en la Escuela”, la cual evalúa los índices de “bullying” y agresión; y la inteligencia emocional a través dela escala TMMS -24. Resultados: El 65,4 % se categoriza como inactivos físicamente. Solo el 14,7% de los estudiantes reconoce que el peso máximo del bolso es el 10 % de su peso corporal; el 34,1 % cambia el cepillo de dientes cada 3 meses, como lo recomiendan los expertos, y 48,4 % se cepilla los dientes entre 2 y 3 veces al día. El 16,6 % no se lava las manos antes y después de ir al baño y 9,4 % no lo hace antes y después de las comidas; el 17,5 % no tiene un buen consumo de verduras y frutas; y se encontró un Índice de “bullying” en el 55,6 % de los participantes. Conclusión: Los anteriores resultados obligan a plantear intervenciones que incrementen las prácticas saludables en niños, niñas y adolescentes.

  13. Achievement report for fiscal 1997 on the research and development to lead to gas hydrate using technology. Research and development on exploration, research and development on drilling technologies, survey and research on a method to evaluate environmental impact, and survey and research on a utilization system; 1997 nendo gas haidoreto shigenka gijutsu sendo kenkyu kaihatsu seika hokokusho. Tansanado ni kansuru kenkyu kaihatsu, kussaku gijutsu ni kansuru kenkyu kaihatsu, kankyo eikyo hyokaho no chosa kenkyu, riyo system ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-09-01

    The present study is intended to analyze comprehensively geophysical, geological and geochemical data, and establish a technology to estimate distribution of gas hydrate (GH) in sea areas around Japan. It is also intended to develop a high-accuracy resource amount calculating method utilizing the result of excavation of GH planned in the future. In order to achieve these goals, the following activities are performed: (1) study on a method to estimate production environment of GH deposits, (2) development of a method to estimate GH stability areas by using the crust thermal flow measuring method, and (3) study on estimation of GH distribution and wide-area potential. For the study (1), an inorganic element analyzer was introduced, and calibration of devices was performed in fiscal 1997. A survey was carried out on literatures related to distribution of inorganic elements and process of GH deposit production. In the study (2), design and trial fabrication were executed on a high-accuracy crust thermal flow measuring device, capable of long-term continuous observation. In the study (3), re-processing focusing on BSR was implemented by using the latest computer and analysis software on the data in which BSR has been confirmed in the surveys done in the past on sea areas around Japan. (NEDO)

  14. Advanced research and development of gas hydrate resources. R and D of exploration and others - R and D of excavation technologies and others - surveys/researches on methods of evaluating environmental effects - surveys/researches on application systems; Gas hydrate shigenka gijutsu sendo kenkyu kaihatsu. Tansa nado ni kansuru kenkyu kaihatsu / kussaku gijutsu nado ni kansuru kenkyu kaihatsu / kankyo eikyo hyokaho no chosa kenkyu / riyo system ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Gas hydrate is a clathrate compound in a gaseous molecule as the host, stable under relatively mild environments. It is deposited in the 600m or deeper sea bottoms to form the gas hydrate deposit and massively occurring in the sea areas around Japan. This deposit has been studied viewed from natural gas resources, causes for natural hazards and contribution to the global warming. This project excavates a well in the deposit, to study possibilities of the technologies for decomposing, fluidizing and lifting the hydrate as the gas source, and for establishing the natural gas transporting/mooring systems in which its characteristics are utilized. The R and D activities are directed to the 4 areas, (1) development of the exploration technologies to determine the deposit sea area, quantity and conditions, (2) development of the stable well-excavation technologies, (3) studies on the effects of gas production on the environments, and development of the system for predicting the effects, (4) and studies on the application systems. The item (3) finds out the transportation/storage system possibly more economical than the current freezing/liquefaction technologies. The item (3) has the development themes of evaluating the geohazards caused by excavation and gas production, and their effects on the ecological systems. (NEDO)

  15. Report on the achievements in fiscal 1999. Technology to use gas hydrate as a resource (Research and development for exploration, research and development on drilling technologies, investigative research on an environment influence evaluation method, and investigative research on a utilization system); 1999 nendo gas hydrate shigenka gijutsu sendo kenkyu kaihatsu seika hokokusho. Tansa nado ni kansuru kenkyu kaihatsu, kussaku gijutsu nado ni kansuru kenkyu kaihatsu, kankyo eikyo hyokaho no chosa kenkyu, riyo system ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The contents of the research and development performed in the current fiscal year are as follows: (1) research and development for exploration, (2) research and development on drilling technologies, (3) investigative research on an environment influence evaluation method, and (4) investigative research on a utilization system. In Item (1), element analysis data are used to study a method to estimate production environment of hydrate ore beds by using an inorganic ion analyzer and a trace amount element analyzer, the crust thermal flow measuring method is used to discuss a method to analyze the hydrate stability zones together with the data of sea area exploration records, and conceptual design is made on a resource potential evaluation system. In Item (2), experiments and analytical discussions are performed on decomposition control of the gas hydrate solid-liquid interface according to such conditions for the drilling fluid as temperatures and flow rates. Elucidation is given on the initial process of bubble generation for behavior of decomposed gas bubbles. Observation and elucidation are made on two-phase flow behavior of non-Newtonian fluid. In Item (3), conceptual design is carried out on a system to detect elements of shape change in each bed due to fluid movement in a gas hydrate bed and an upper bed. In Item (4), discussions are given on the optimizing conditions for generation and dissociation of gas hydrates. Investigation is made also on a possibility of the transportation and storage system. (NEDO)

  16. Report on the survey in fiscal 1998. A survey on long-term energy technology strategy (a survey related to arrangement of information groups and aiding means for establishing policies related to research and development of energy and environment technologies); 1998 nendo choki energy gijutsu senryaku chosa. Energy kankyo gijutsu kenkyu kaihatsu ni kakawaru seisaku kettei no tame no johogun no seibi narabi ni shien shuho ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This paper discusses aiding means for establishing the research and development strategy for maximizing greenhouse effect gas reduction for a short period (year 2010) and an ultra long period (year 2030 and on). First, the situation surrounding the existing energy and environment technologies and technological assignments (themes) were put into order. Rough calculations were made on the selected themes as to their effect of greenhouse effect gas reduction. Based on the result of these reduction amount calculations, provisionary introduction scenarios including analyses by groups and users were prepared according to each theme. On the other hand, data groups related to the energy and environment technologies were investigated and put into order. The data groups include literatures and achievements of the past researches, and are expected of utilization for estimating the introduction potential to calculate effects of future research and development. In addition, discussions were given on methods to analyze cost-effect relationship in the energy and environment technologies. Importance was placed on the case surveys inside and outside the country, and simple models suitable for themes in the New Sunshine Project were built for an attempt of case studies. (NEDO)

  17. FY 2001 report on the integrated evaluation of the research cooperation project. Research cooperation program on the development of environmental measurement use laser radar/research cooperation project on the mining waste water treatment technology using biology; 2001 nendo kenkyu kyoryoku jigyo sogo hyoka hokokusho. Kankyo kesokuyo reza reda no kaihatsu ni kansuru kenkyu kyoryoku - Baio riyo ni yoru kohaisui shori gijutsu ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-03-01

    By research groups having been sent, the integrated evaluation was made of the projects on the research cooperation with Indonesia in the development of environmental measurement use laser radar and the research cooperation with China in the mining waste water treatment technology using biology. As to the research cooperation with Indonesia, the purpose/target proposed were almost achieved, and all were favorably carried out. Especially, after finishing the project, the design/manufacture of an on-vehicle type Mie-scattering laser radar were made using the acquired laser technology. And, it was reported that an observation study of the state of air pollution in Bandung city was made using the laser radar. It can be said that generally the research cooperation with China was smoothly proceeded with. However, the Wushan mine is small in scale of management, and therefore, there might have been some points to be reviewed in selection of the mine for research. The pilot plant installed at the Wushan mine is not now operated. If the mine has strong management force, the effective use of the pilot plant after finishing the project might have been studied. (NEDO)

  18. FY 1998 annual report on the preliminary research and development of techniques for developing resources from gas-hydrate. Studies on gas-hydrate exploration, excavation techniques, methods for assessing environmental impacts, and gas hydrate handling systems; 1998 nendo gas hydrate shigenka gijutsu sendoken kaihatsu seika hokokusho. Tansanado ni kansuru kenkyu kaihatsu, kussaku gijutsu nado ni kansuru kenkyu kaihatsu, kankyo eikyo hyokaho no kenkyu kaihatsu, riyo system ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This R and D project is for the preliminary studies on development of the following 4 types of techniques for developing resources from gas-hydrates (GH): (1) gas-hydrate exploration, (2) excavation techniques, (3) methods for assessing environmental impacts, and (4) gas hydrate handling systems. The FY 1988 R and D results are described. For gas-hydrate exploration, the methods for analyzing inorganic ions and trace quantities of elements, which are necessary for accurately estimating the offshore GH around Japan, are established; and case studies are conducted for methods of predicting GH deposit forming mechanisms, and stability fields of GH, based on terrestrial heat flow and seismic data. For excavation techniques, GH decomposition rate is analyzed using a laboratory system which reproduces conditions of excavation of GH layers. For methods for assessing environmental impacts, a geo-hazard predicting model is established, to study ground displacement and gas leakage sensing systems and data transmission systems to cope with the hazards. For gas hydrate handling systems, an overall system is studied, and storage and transportation systems are outlined. (NEDO)

  19. Electrochemical properties of the ball-milled LaMg10NiMn alloy with Ni powders

    International Nuclear Information System (INIS)

    Wang Yi; Wang Xin; Gao Xueping; Shen Panwen

    2008-01-01

    The electrochemical characteristics of the ball-milled LaMg 10 NiMn alloys with Ni powders were investigated. It was found that the ball-milled LaMg 10 NiMn + 150 wt.% Ni composite exhibited higher first discharge capacity and better cycle performance. By means of the analysis of electrochemical impedance spectra (EIS), it was shown that the existence of manganese in LaMg 10 NiMn alloy increased the electrocatalytic activity due to its catalytic effect, and destabilized metal hydrides, and so reduced the hydrogen diffusion resistance. These contributed to the higher discharge capacity of the ball-milled LaMg 10 NiMn-Ni composite. According to the analytical results of X-ray diffraction (XRD), EIS and steady-state polarization (SSP) experiments, the inhibition of metal corrosion is not the main reason for the better cycle performance. The main reason is that the electrochemical reaction resistance of the ball-milled LaMg 10 NiMn-Ni composite is always lower than that of the ball-milled LaMg 10 Ni 2 -Ni composite because the former one contains manganese, which is a catalyst for the electrode reaction

  20. High-frequency permeability of electroplated CoNiFe and CoNiFe-C alloys

    International Nuclear Information System (INIS)

    Rhen, Fernando M.F.; McCloskey, Paul; O'Donnell, Terence; Roy, Saibal

    2008-01-01

    We have investigated CoNiFe and CoNiFe-C electrodeposited by pulse reverse plating (PRP) and direct current (DC) techniques. CoNiFe(PRP) films with composition Co 59.4 Fe 27.7 Ni 12.8 show coercivity of 95 A m -1 (1.2 Oe) and magnetization saturation flux (μ 0 M s ) of 1.8 T. Resistivity of CoNiFe (PRP) is about 24 μΩ cm and permeability remains almost constant μ r ' ∼475 up to 30 MHz with a quality factor (Q) larger than 10. Additionally, the permeability spectra analysis shows that CoNiFe exhibits a classical eddy current loss at zero bias field and ferromagnetic resonance (FMR) when biased with 0.05 T. Furthermore, a crossover between eddy current and FMR loss is observed for CoNiFe-PRP when baised with 0.05 T. DC and PRP plated CoNiFe-C, which have resistivity and permeability of 85, 38 μΩ cm, μ r '=165 and 35 with Q>10 up to 320 MHz, respectively, showed only ferromagnetic resonance losses. The ferromagnetic resonance peaks in CoNiFe and CoNiFe-C are broad and resembles a Gaussian distribution of FMR frequencies. The incorporation of C to CoNiFe reduces eddy current loss, but also reduces the FMR frequency

  1. Corrosive sliding wear behavior of laser clad Mo2Ni3Si/NiSi intermetallic coating

    International Nuclear Information System (INIS)

    Lu, X.D.; Wang, H.M.

    2005-01-01

    Many ternary metal silicides such as W 2 Ni 3 Si, Ti 2 Ni 3 Si and Mo 2 Ni 3 Si with the topologically closed-packed (TCP) hP12 MgZn 2 type Laves phase crystal structure are expected to have outstanding wear and corrosion resistance due to their inherent high hardness and sluggish temperature dependence and strong atomic bonds. In this paper, Mo 2 Ni 3 Si/NiSi intermetallic coating was fabricated on substrate of an austenitic stainless steel AISI321 by laser cladding using Ni-Mo-Si elemental alloy powders. Microstructure of the coating was characterized by optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD) and energy dispersive X-ray analysis (EDS). Wear resistance of the coating is evaluated under corrosive sliding wear test condition. Influence of corrosion solutions on the wear resistance of the coating was studied and the wear mechanism was discussed based on observations of worn surface morphology. Results showed that the laser clad Mo 2 Ni 3 Si/NiSi composite coating have a fine microstructure of Mo 2 Ni 3 Si primary dendrites and the interdendritic Mo 2 Ni 3 Si/NiSi eutectics. The coating has excellent corrosive wear resistance compared with austenitic stainless steel AISI321 under acid, alkaline and saline corrosive environments

  2. Magnetic properties of two new compounds: Pr2Ni3Si5 and Ho2Ni3Si5

    International Nuclear Information System (INIS)

    Mazumdar, C.; Padalia, B.D.; Godart, C.

    1994-01-01

    Formation of two more new materials, Pr 2 Ni 3 Si 5 and Ho 2 Ni 3 Si 5 , of the series, R 2 Ni 3 Si 5 (R = rare earth and Y) and their magnetic properties are reported here. These materials crystallize in the orthorhombic U 2 Co 3 Si 5 -type structure (space group Ibam). Magnetic susceptibility measurement in the temperature range 5 K--300 K show that the compound Pr 2 Ni 3 Si 5 order antiferromagnetically at T N ∼ 8.5 K and Ho 2 Ni 3 Si 5 at ∼ 6 K. Considering T N (Gd 2 Ni 3 Si 5 ) ∼ 15 K, T N (Pr 2 Ni 3 Si 5 ) ∼ 8.5 K is rather high. The magnetic susceptibility of both of the materials, in the paramagnetic state, follows a Curie-Weiss law with effective moment close to that of the corresponding free trivalent rare earth ion

  3. Effect of Ni Core Structure on the Electrocatalytic Activity of Pt-Ni/C in Methanol Oxidation

    Directory of Open Access Journals (Sweden)

    Vladimir Linkov

    2013-07-01

    Full Text Available Methanol oxidation catalysts comprising an outer Pt-shell with an inner Ni-core supported on carbon, (Pt-Ni/C, were prepared with either crystalline or amorphous Ni core structures. Structural comparisons of the two forms of catalyst were made using transmission electron microscopy (TEM, X-ray diffraction (XRD and X-ray photoelectron spectroscopy (XPS, and methanol oxidation activity compared using CV and chronoamperometry (CA. While both the amorphous Ni core and crystalline Ni core structures were covered by similar Pt shell thickness and structure, the Pt-Ni(amorphous/C catalyst had higher methanol oxidation activity. The amorphous Ni core thus offers improved Pt usage efficiency in direct methanol fuel cells.

  4. Hard X-ray MCD in GdNi/sub 5/ and TbNi/sub 5/ single crystals

    CERN Document Server

    Galera, R M

    1999-01-01

    XMCD experiments have been performed at the R L/sub 2,3/ and Ni K- edges on magnetically saturated single crystals of GdNi/sub 5/ and Tb Ni/sub 5/ ferromagnetic compounds. The spectra present huge and well structured dichroic $9 signals at both the R L/sub 2,3/ and the Ni K- edges. Structures from the quadrupolar (2p to 4f) transitions are clearly observed at the R L/sub 2,3/-edges. Though Ni is not magnetic, large intensities, up to 0.4, are measured at the $9 Ni K- edge. The Ni K-edge XMCD shows a three-peak structure which intensities dependent on the rare earth. (7 refs).

  5. Electrochemically induced transformation of NiS nanoparticles into Ni(OH)2 in KOH aqueous solution toward electrochemical capacitors

    International Nuclear Information System (INIS)

    Hou Linrui; Yuan Changzhou; Li Diankai; Yang Long; Shen Laifa; Zhang Fang; Zhang Xiaogang

    2011-01-01

    Highlights: → NiS is synthesized by means of the H 2 O/CS 2 interface under hydrothermal treatment. → NiS itself owns poor electrochemical capacitance in 2 M KOH solution. → NiS is electrochemically induced and transformed into electroactive Ni(OH) 2 . → Ni(OH) 2 is responsible for good energy storage of the NiS in the KOH solution. → The new formed Ni(OH) 2 delivers large energy density at high rates. - Abstract: Nickel sulfide nanoparticles (NPs) are first synthesized by virtue of a unique H 2 O/CS 2 interface under mild hydrothermal treatment. Electrochemical data reveals that the as-synthesized NiS NPs themselves own poor supercapacitive behavior at initial cyclic voltammetry (CV) cycles in 2 M KOH solution, while a specific capacitance of 893 F g -1 can be surprisingly obtained at a current density of 5 A g -1 just after continuous 320 CV cycles. X-ray diffraction and Fourier transform infrared techniques demonstrate that what is really responsible for the good electrochemical capacitance in the KOH aqueous solution is the new electrochemically formed Ni(OH) 2 phase, rather than NiS NPs themselves. The Ni(OH) 2 is slowly formed during the continuous CV cycling process, in which the electrochemically induced phase transformation from NiS to Ni(OH) 2 phase takes place. Furthermore, the new Ni(OH) 2 phase demonstrates the great ability of delivering large specific capacitance at high rates.

  6. Fe-Ni-bearing serpentines from the saprolite horizon of Caribbean Ni-laterite deposits: new insights from thermodynamic calculations

    Science.gov (United States)

    Villanova-de-Benavent, Cristina; Domènech, Cristina; Tauler, Esperança; Galí, Salvador; Tassara, Santiago; Proenza, Joaquín A.

    2017-10-01

    Fe-Ni-bearing serpentine from the saprolite horizon is the main Ni ores in hydrous silicate-type Ni laterites and formed by chemical weathering of partially serpentinized ultramafic rocks under tropical conditions. During lateritization, Mg, Si, and Ni are leached from the surface and transported downwards. Fe2+ is oxidized to Fe3+ and fixed as insoluble Fe-oxyhydroxides (mostly goethite) that incorporate Ni. This Ni is later leached from goethite and incorporated in secondary serpentine and garnierite. As a result, a serpentine-dominated saprolite horizon forms over the ultramafic protolith, overlapped by a Fe-oxyhydroxide-dominated limonite horizon. The serpentine from the protolith (serpentine I) is of hydrothermal origin and yields similar Ni (0.10-0.62 wt.% NiO) and lower Fe (mostly 1.37-5.81 wt.% FeO) concentrations than the primary olivine. In contrast, Fe-Ni-bearing serpentine from the saprolite (serpentine II) shows significantly higher and variable Fe and Ni contents, typically ranging from 2.23 to 15.59 wt.% Fe2O3 and from 1.30 to 7.67 wt.% NiO, suggesting that serpentine get enriched in Fe and Ni under supergene conditions. This study presents detailed mineralogical, textural, and chemical data on this serpentine II, as well as new insights by thermodynamic calculations assuming ideal solution between Fe-, Ni- and Mg-pure serpentines. The aim is to assess if at atmospheric pressure and temperature Fe-Ni-bearing serpentine can be formed by precipitation. Results indicate that the formation of serpentine II under atmospheric pressure and temperature is thermodynamically supported, and pH, Eh, and the equilibrium constant of the reaction are the parameters that affect the results more significantly.

  7. Ni{sub 3}Al technology transfer

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K.; Santella, M.L.; Alexander, D.J. [Oak Ridge National Laboratory, TN (United States)] [and others

    1995-05-01

    Ductile Ni{sub 3}Al and Ni{sub 3}Al-based alloys have been identified for a range of applications. These applications require the use of material in a variety of product forms such as sheet, plate, bar, tubing, piping, and castings. Although significant progress has been made in the melting, casting, and near-net-shape forming of nickel aluminides, some issues still remain. These include the need for (1)high-strength castable composition for turbochargers, furnace furniture, and hot-die applications; (2) castability (fluidity, hot-shortness, porosity, etc.); (3) weld reparability of castings; and (4) hot fabricability of cast ingots. All of the issues listed above can be {open_quotes}show stoppers{close_quotes} for the commercial application of nickel aluminides. This report describes work completed to address some of these issues during the fourth quarter of FY 1994.

  8. Ni{sub 3}Al technology transfer

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K.; Viswanathan, S.; Santella, M.L. [Oak Ridge National Lab., TN (United States)] [and others

    1997-04-01

    Ductile Ni{sub 3}Al and Ni{sub 3}Al-based alloys have been identified for a range of applications. These applications require the use of material in a variety of product forms such as sheet, plate, bar, wire, tubing, piping, and castings. Although significant progress has been made in the melting, casting, and near-net-shape forming of nickel aluminides, some issues still remain. These include the need for: (1) high-strength castable composition for many applications that have been identified; (2) castability (mold type, fluidity, hot-shortness, porosity, etc.); (3) weld reparability of castings; and (4) workability of cast or powder metallurgy product to sheet, bar, and wire. The four issues listed above can be {open_quotes}show stoppers{close_quotes} for the commercial application of nickel aluminides. This report describes the work completed to address some of these issues during FY 1996.

  9. Internal chlorination of Ni-Cr alloys

    Energy Technology Data Exchange (ETDEWEB)

    Berztiss, D.; Hennesen, K.; Grabke, H.J. [Max-Planck-Institut fuer Eisenforschung GmbH, Duesseldorf (Germany)

    1998-12-31

    In contrast to internal oxidation, sulfidation and carburization, very little information is available regarding internal chlorination, especially diffusion of chlorine in metallic alloys. This paper describes results of experiments on Ni-Cr alloys (<10 wt% Cr) exposed in an atmosphere containing radioactive HCl. The diffusion of chlorine in the alloy can be determined by measurement of residual {beta}-activity from the sample surface. Successively thin layers (0.5-10 {mu}m) of the alloy were removed by lapping and the surface activity was measured to obtain a depth profile. Both single and polycrystalline materials were tested. Through this work it should be determined if there is in fact solubility and diffusion of chlorine in Ni-based alloys as some authors have proposed or if the ingress of chlorine is mainly a grain boundary phenomenon. (orig.)

  10. Resonant Ni and Fe KLL Auger spectra photoexcited from NiFe alloys

    International Nuclear Information System (INIS)

    Koever, L.; Cserny, I.; Berenyi, Z.; Egri, S.; Novak, M.

    2005-01-01

    Complete text of publication follows. KLL Auger spectra of 3d transition metal atoms in solid environment, measured using high energy resolution, give an insight into the details of the local electronic structure surrounding the particular atoms emitting the signal Auger electrons. Fine tuning the energy of the exciting monochromatic photons across the K-absorption edge, features characteristic to resonant phenomena can be identified in the spectra. The shapes of the resonantly photoexcited KLL Auger spectra induced from 3d transition metals and alloys are well interpreted by the single step model of the Auger process, based on the resonant scattering theory. The peak shapes are strongly influenced by the 4p partial density of unoccupied electronic states around the excited atom. High energy resolution studies of KLL Auger spectra of 3d transition metals using laboratory X-ray sources, however, request very demanding experiments and yield spectra of limited statistical quality making the evaluation of the fine details in the spectra difficult. The Tunable High Energy XPS (THE- XPS) instrument at BW2 offers optimum photon x and energy resolution for spectroscopy of deep core Auger transitions. For the present measurements high purity polycrystalline Ni and Fe sheets as well as NiFe alloy samples of different compositions (Ni 80 Fe 20 , Ni 50 Fe 50 , Ni 20 Fe 80 ) were used. The surfaces of the samples were cleaned by in-situ argon ion sputtering. The measurements of the Ni and Fe KL 23 L 23 Auger spectra of the metal and alloy samples were performed with the THE-XPS instrument using high electron energy resolution (0.2 eV). In Fig.1, the measured Fe KL 23 L 23 spectrum, photoexcited at the Fe K absorption edge from Fe metal, is compared with the respective spectrum excited from a Ni 50 Fe 50 alloy. A significant broadening of the 1 D 2 peak and an enhancement of the spectral intensity at the low energy loss part of this peak observed in the alloy sample, while the

  11. Phase transitions in alloys of the Ni-Mo system

    International Nuclear Information System (INIS)

    Ustinovshikov, Y.; Shabanova, I.

    2011-01-01

    Graphical abstract: The structure of Ni-20 at.% Mo and Ni-25 at.% Mo alloys was studied by methods of TEM and XPS. It is shown that at high temperatures the tendency toward phase separation takes place in the alloys and crystalline bcc Mo particles precipitate in the liquid solution. At 900 deg. C and below, the tendency toward ordering leads to the dissolution of Mo particles and precipitation of the particles of Ni 3 Mo, Ni 2 Mo or Ni 4 Mo chemical compounds. Highlights: → 'Chemical' phase transition 'ordering-phase separation' is first discovered in alloys of the Ni-Mo system. → It is first shown that the phase separation in the alloys studied begins at temperatures above the liquidus one. → The formation of Ni 3 Mo from A1 has gone through the intervening stage of the Ni 4 Mo and Ni 2 Mo coexistence. - Abstract: The structure of Ni-20 at.% Mo and Ni-25 at.% Mo alloys heat treated at different temperatures was studied by the method of transmission electron microscopy. X-ray photoelectron spectroscopy was used to detect the sign of the chemical interaction between Ni and Mo atoms at different temperatures. It is shown that at high temperatures the tendency toward phase separation takes place. The system of additional reflections at positions {1 1/2 0} on the electron diffraction patterns testifies that the precipitation of crystalline bcc Mo particles begins in the liquid solution. At 900 deg. C and below, the tendency toward ordering leads to the precipitation of the particles of the chemical compounds. A body-centered tetragonal phase Ni 4 Mo (D1 a ) is formed in the Ni-20 at.% Mo alloy. In the Ni-25 at.% Mo alloy, the formation of the Ni 3 Mo (D0 22 ) chemical compound from the A1 solid solution has gone through the intervening stage of the Ni 4 Mo (D1 a ) and Ni 2 Mo (Pt 2 Mo) formation.

  12. Combining Ru, Ni and Ni(OH){sub 2} active sites for improving catalytic performance in benzene hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Lihua, E-mail: lihuazhu@stu.xmu.edu.cn [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Sun, Hanlei; Zheng, Jinbao [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Yu, Changlin, E-mail: yuchanglinjx@163.com [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Zhang, Nuowei [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Shu, Qing [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Chen, Bing H., E-mail: chenbh@xmu.edu.cn [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)

    2017-05-01

    In this study, the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts were successfully prepared by the simple methods of hydrazine-reduction and galvanic replacement, where 0.04/0.96 and T represented the Ru/Ni atomic ratio and reducing temperature of the catalyst in N{sub 2}+10%H{sub 2}, respectively. The nanostructures of the Ru{sub 0.04}Ni{sub 0.96} nanoparticles in the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts were controlled by modulating their annealing temperature in N{sub 2}+10%H{sub 2} and characterized by an array of techniques, including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), scanning transmission electron microscopy energy dispersive X-ray spectroscopy (STEM-EDS) mapping and high-sensitivity low-energy ion scattering (HS-LEIS). The Ru{sub 0.04}Ni{sub 0.96}/C(30) catalyst, which was composed of Ru clusters or single atoms supported on Ni/Ni(OH){sub 2} nanoparticles, exhibited much better catalytic performance for benzene hydrogenation than the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts reduced at above 30 °C, such as Ru{sub 0.04}Ni{sub 0.96}/C(160) with the nanostructure of partial Ru{sub 0.04}Ni{sub 0.9} alloy and Ru{sub 0.04}Ni{sub 0.96}/C(280) with the nanostructure of complete Ru{sub 0.04}Ni{sub 0.9} alloy. The reason was that the synergistic effect of multiple active sites – Ru, Ni and Ni(OH){sub 2} sites was present in the Ru{sub 0.04}Ni{sub 0.96}/C(30) catalyst, where hydrogen was preferentially activated at Ru sites, benzene was probably activated at Ni(OH){sub 2} surface and Ni acted as a “bridge” for transferring activated H{sup ∗} species to activated benzene by hydrogen spillover effect, hydrogenating and forming product – cyclohexane. This study also provided a typical example to illustrate that the synergy effect of multiple active sites can largely improve the catalytic hydrogenation performance. - Highlights: • The Ru

  13. Imaging magnetic domains in Ni nanostructures

    International Nuclear Information System (INIS)

    Asenjo, A.; Jaafar, M.; Gonzalez, E.M.; Martin, J.I.; Vazquez, M.; Vicent, J.L.

    2007-01-01

    The study of nanomagnets is the subject of increasing scientific effort. The size, the thickness and the geometric shape of the elements determine the magnetic properties and then the domain configuration. In this work, we fabricated by electron-beam lithography the three different arrays of Ni nanostructures keeping the size, the thickness and also the distance constant between the elements but varying the geometry: square, triangular and circular. The domain structure of the nanomagnets is studied by magnetic force microscopy

  14. Determination of 59Ni in radioactive waste

    International Nuclear Information System (INIS)

    Fisera, O.; Sebesta, F.

    2010-01-01

    Composite material PAN-DMG, containing chelating agent dimethylglyoxime (DMG) immobilized in porous matrix of binding polymer polyacrylonitrile (PAN), was used for nickel separation and concentration. Method for preparation of 59 Ni source for low energy photon spectrometry was developed using homogeneous precipitation of nickel with DMG. The proposed method was tested with two types of real radioactive waste (boric acid concentrate from nuclear power plant (NPP) evaporator and spent ion exchanger from NPP). (author)

  15. Structural, electrical and magnetic properties of evaporated Ni/Cu and Ni/glass thin films

    Energy Technology Data Exchange (ETDEWEB)

    Nacereddine, C. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria); Layadi, A. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria)]. E-mail: A_Layadi@yahoo.fr; Guittoum, A. [Centre de Recherche Nucleaire d' Alger (CRNA), Alger 16000 (Algeria); Cherif, S.-M. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse 93340 (France); Chauveau, T. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse 93340 (France); Billet, D. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse 93340 (France); Youssef, J. Ben [Laboratoire de Magnetisme de Bretagne, U.B.O., Brest 29238 (France); Bourzami, A. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria); Bourahli, M.-H. [Departement d' O. M. P., Universite Ferhat Abbas, Setif 19000 (Algeria)

    2007-01-25

    The structural, electrical and magnetic properties of Ni thin films evaporated onto glass and polycrystalline Cu substrates have been investigated. The Ni thickness ranges from 31 to 165 nm. X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM) have been used to study the structure and morphology of these systems. The Ni/Cu and Ni/glass thin films are found to be polycrystalline with a (1 1 1) texture. There is an overall increase of the grain size with increasing thickness. A negative strain was noted indicating that all the samples are under a compressive stress. Diffusion at the grain boundaries seems to be a major contribution to the electrical resistivity in this thickness range. Study of the hysteresis curves, obtained by vibrating sample magnetometer (VSM), indicates that all samples are characterized by an in-plane magnetization easy axis. Higher in-plane coercive fields seem to be associated with higher grain size, indicating that coercivity may be due to nucleation of reverse domains rather than pinning of domain walls. The saturation field and the squareness have been studied as a function of the Ni thickness.

  16. Participar como niña o niño en el mundo social

    Directory of Open Access Journals (Sweden)

    Silvia Paulina Díaz

    2010-10-01

    Full Text Available En este artículo presento la participación como resultado de un trabajo investigativo realizado durante el año 2007, con niños y niñas escolarizados habitantes de la ciudad de Medellín, Colombia, cuyo objetivo fue analizar las representaciones sociales que ellos y ellas comparten sobre el ejercicio ciudadano. El análisis de la información tiene como ejes fundamentales, la salud colectiva, la sociología de la infancia y la participación en la niñez, en una aproximación que se realiza desde un enfoque cualitativo y etnográfico. En los hallazgos, sobresale cómo las niñas y niños se muestran preparados para ejercer su derecho a la participación como aspecto de sus vidas que se haría posible dentro del marco normativo existente, pero que aún no es asumido en prácticas sociales que los incluyan.

  17. HDO of Methyl Palmitate over Silica-Supported Ni Phosphides: Insight into Ni/P Effect

    Directory of Open Access Journals (Sweden)

    Irina V. Deliy

    2017-10-01

    Full Text Available Two sets of silica-supported nickel phosphide catalysts with a nickel content of about 2.5 and 10 wt % and Ni/P molar ratio 2/1, 1/1 and 1/2 in each set, were prepared by way of a temperature-programmed reduction method using (Ni(CH3COO2 and ((NH42HPO4 as a precursor. The NixPy/SiO2 catalysts were characterized using chemical analysis N2 physisorption, XRD, TEM, 31P MAS NMR. Methyl palmitate hydrodeoxygenation (HDO was performed in a trickle-bed reactor at 3 MPa and 290 °C with LHSV ranging from 0.3 to 16 h−1. The Ni/P ratio was found to affect the nickel phosphide phase composition, POx groups content and catalytic properties in methyl palmitate HDO with the TOF increased along with a decline of Ni/P ratio and a growth of POx groups’ content. Taking into account the possible routes of methyl palmitate conversion (metal-catalyzed hydrogenolysis or acid-catalyzed hydrolysis, we proposed that the enhancement of acid POx groups’ content with the Ni/P ratio decrease provides an enhancement of the rate of methyl palmitate conversion through the acceleration of acid-catalyzed hydrolysis.

  18. Participar como niña o niño en el mundo social

    Directory of Open Access Journals (Sweden)

    Silvia Paulina Díaz

    2010-01-01

    Full Text Available En este artículo presento la participación como resultado de un trabajo investigativo realizado durante el año 2007, con niños y niñas escolarizados habitantes de la ciudad de Medellín, Colombia, cuyo objetivo fue analizar las representaciones sociales que ellos y ellas comparten sobre el ejercicio ciudadano. El análisis de la información tiene como ejes fundamentales, la salud colectiva, la sociología de la infancia y la participación en la niñez, en una aproximación que se realiza desde un enfoque cualitativo y etnográfico. En los hallazgos, sobresale cómo las niñas y niños se muestran preparados para ejercer su derecho a la participación como aspecto de sus vidas que se haría posible dentro del marco normativo existente, pero que aún no es asumido en prácticas sociales que los incluyan.

  19. Tungsten inert gas (TIG) welding of Ni-rich NiTi plates: functional behavior

    Science.gov (United States)

    Oliveira, J. P.; Barbosa, D.; Braz Fernandes, F. M.; Miranda, R. M.

    2016-03-01

    It is often reported that, to successfully join NiTi shape memory alloys, fusion-based processes with reduced thermal affected regions (as in laser welding) are required. This paper describes an experimental study performed on the tungsten inert gas (TIG) welding of 1.5 mm thick plates of Ni-rich NiTi. The functional behavior of the joints was assessed. The superelasticity was analyzed by cycling tests at maximum imposed strains of 4, 8 and 12% and for a total of 600 cycles, without rupture. The superelastic plateau was observed, in the stress-strain curves, 30 MPa below that of the base material. Shape-memory effect was evidenced by bending tests with full recovery of the initial shape of the welded joints. In parallel, uniaxial tensile tests of the joints showed a tensile strength of 700 MPa and an elongation to rupture of 20%. The elongation is the highest reported for fusion-welding of NiTi, including laser welding. These results can be of great interest for the wide-spread inclusion of NiTi in complex shaped components requiring welding, since TIG is not an expensive process and is simple to operate and implement in industrial environments.

  20. High resolution TEM study of Ni4Ti3 precipitates in austenitic Ni51Ti49

    International Nuclear Information System (INIS)

    Tirry, Wim; Schryvers, Dominique

    2003-01-01

    Binary NiTi with a composition of 51 at.% Ni was heat treated to form lens-shaped Ni 4 Ti 3 precipitates that are coherent or semi-coherent with the B2 matrix. High resolution transmission electron microscopy (HRTEM) was used to study the internal structure of the precipitates, precipitate-precipitate and matrix-precipitate interfaces and the deformation of the B2 matrix near a precipitate. Observations were made in the B2 and B2 zones and compared with computer simulated high resolution images. The B2 observations made it possible to study the [0 0 1] H zone orientation of Ni 4 Ti 3 (direction defined according to the hexagonal unit cell of Ni 4 Ti 3 ) which corresponds to the normal of the central plane of the discs. In these images the superperiodicity of the 4:3 ordering is clearly visible confirming the known atomic structure. Close to the precipitate the B2 matrix is deformed, as determined by measuring the interplanar spacing from the HRTEM images. The observed deformations are compared with theoretical models for the stress field

  1. Breakdown of antiferromagnet order in polycrystalline NiFe/NiO bilayers probed with acoustic emission

    Science.gov (United States)

    Lebyodkin, M. A.; Lebedkina, T. A.; Shashkov, I. V.; Gornakov, V. S.

    2017-07-01

    Magnetization reversal of polycrystalline NiFe/NiO bilayers was investigated using magneto-optical indicator film imaging and acoustic emission techniques. Sporadic acoustic signals were detected in a constant magnetic field after the magnetization reversal. It is suggested that they are related to elastic waves excited by sharp shocks in the NiO layer with strong magnetostriction. Their probability depends on the history and number of repetitions of the field cycling, thus testifying the thermal-activation nature of the long-time relaxation of an antiferromagnetic order. These results provide evidence of spontaneous thermally activated switching of the antiferromagnetic order in NiO grains during magnetization reversal in ferromagnet/antiferromagnet (FM/AFM) heterostructures. The respective deformation modes are discussed in terms of the thermal fluctuation aftereffect in the Fulcomer and Charap model which predicts that irreversible breakdown of the original spin orientation can take place in some antiferromagnetic grains with disordered anisotropy axes during magnetization reversal of exchange-coupled FM/AFM structures. The spin reorientation in the saturated state may induce abrupt distortion of isolated metastable grains because of the NiO magnetostriction, leading to excitation of shock waves and formation of plate (or Lamb) waves.

  2. Electric Monopole Transition Strengths in 62Ni

    Directory of Open Access Journals (Sweden)

    Evitts L. J.

    2016-01-01

    Full Text Available Excited states in 62Ni were populated with a (p, p’ reaction using the 14UD Pelletron accelerator at the Australian National University. Electric monopole transition strengths, ρ2(E0, were measured through simultaneous detection of the internal conversion electrons and γ rays emitted from the de-excitation of populated states, using the Super-e spectrometer coupled with a germanium detector. The strength of the 02+ to 01+ transition has been measured to be 77−34+23 × 10−3 and agrees with previously reported values. Upper limits have been placed on the 03+ to 01+ and 03+ to 02+ transitions. The measured ρ2(E0 value of the 22+ to 21+ transition in 62Ni has been measured for the first time and found to be one of the largest ρ2(E0 values measured to date in nuclei heavier than Ca. The low-lying states of 62Ni have previously been classified as one- and two-phonon vibrational states based on level energies. The measured electric quadrupole transition strengths are consistent with this interpretation. However as electric monopole transitions are forbidden between states which differ by one phonon number, the simple harmonic quadrupole vibrational picture is not suffcient to explain the large ρ2(E0 value for the 22+ to 21+ transition.

  3. Electric Monopole Transition Strengths in 62Ni

    Science.gov (United States)

    Evitts, L. J.; Garnsworthy, A. B.; Kibédi, T.; Moukaddam, M.; Alshahrani, B.; Eriksen, T. K.; Holt, J. D.; Hota, S. S.; Lane, G. J.; Lee, B. Q.; McCormick, B. P.; Palalani, N.; Reed, M. W.; Stroberg, S. R.; Stuchbery, A. E.

    2016-09-01

    Excited states in 62Ni were populated with a (p, p') reaction using the 14UD Pelletron accelerator at the Australian National University. Electric monopole transition strengths, ρ2(E0), were measured through simultaneous detection of the internal conversion electrons and γ rays emitted from the de-excitation of populated states, using the Super-e spectrometer coupled with a germanium detector. The strength of the 02+ to 01+ transition has been measured to be 77-34+23 × 10-3 and agrees with previously reported values. Upper limits have been placed on the 03+ to 01+ and 03+ to 02+ transitions. The measured ρ2(E0) value of the 22+ to 21+ transition in 62Ni has been measured for the first time and found to be one of the largest ρ2(E0) values measured to date in nuclei heavier than Ca. The low-lying states of 62Ni have previously been classified as one- and two-phonon vibrational states based on level energies. The measured electric quadrupole transition strengths are consistent with this interpretation. However as electric monopole transitions are forbidden between states which differ by one phonon number, the simple harmonic quadrupole vibrational picture is not suffcient to explain the large ρ2(E0) value for the 22+ to 21+ transition.

  4. Length-dependent corrosion behavior, Ni2+ release, cytocompatibility, and antibacterial ability of Ni-Ti-O nanopores anodically grown on biomedical NiTi alloy.

    Science.gov (United States)

    Hang, Ruiqiang; Liu, Yanlian; Bai, Long; Zhang, Xiangyu; Huang, Xiaobo; Jia, Husheng; Tang, Bin

    2018-08-01

    In the present work, nickel-titanium-oxygen nanopores with different length (0.55-114 μm) were anodically grown on nearly equiatomic nickel-titanium (NiTi) alloy. Length-dependent corrosion behavior, nickel ion (Ni 2+ ) release, cytocompatibility, and antibacterial ability were investigated by electrochemical, analytical chemistry, and biological methods. The results show constructing nanoporous structure on the NiTi alloy improve its corrosion resistance. However, the anodized samples release more Ni 2+ than that of the bare NiTi alloy, suggesting chemical dissolution of the nanopores rather than electrochemical corrosion governs the Ni 2+ release. In addition, the Ni 2+ release amount increases with nanopore length. The anodized samples show good cytocompatibility when the nanopore length is covers the one (1-11 μm) that the nanopores showing favorable antibacterial ability. Consequently, the nanopores with length in the range of 1-11 μm are promising as coatings of biomedical NiTi alloy for anti-infection, drug delivery, and other desirable applications. Copyright © 2018 Elsevier B.V. All rights reserved.

  5. Effects of P/Ni ratio and Ni content on performance of γ-Al_2O_3-supported nickel phosphides for deoxygenation of methyl laurate to hydrocarbons

    International Nuclear Information System (INIS)

    Zhang, Zhena; Tang, Mingxiao; Chen, Jixiang

    2016-01-01

    Graphical abstract: - Highlights: • The formation of AlPO_4 was unfavorable for that of nickel phosphides. • The phase compositions of nickel phosphide depended on the amount of reduced P. • Catalytic activity was determined by surface Ni site density and catalyst acidity. • HDO pathway was promoted by increasing P/Ni ratio and Ni content. • Nickel phosphide gave much higher carbon yield and lower H_2 consumption than Ni. - Abstract: γ-Al_2O_3-supported nickel phosphides (mNi-Pn) were prepared by the TPR method and tested for the deoxygenation of methyl laurate to hydrocarbons. The effects of the P/Ni ratio (n = 1.0–2.5) and Ni content (m = 5–15 wt.%) in the precursors on their structure and performance were investigated. Ni/γ-Al_2O_3 was also studied for comparison. It was found that the formation of AlPO_4 in the precursor inhibited the reduction of phosphate and so the formation of nickel phosphides. With increasing the P/Ni ratio and Ni content, the Ni, Ni_3P, Ni_1_2P_5 and Ni_2P phases orderly formed, accompanying with the increases of their particle size and the amount of weak acid sites (mainly due to P-OH group), while the CO uptake and the amount of medium strong acid sites (mainly related to Ni sites) reached maximum on 10%Ni-P1.5. In the deoxygenation reaction, compared with Ni/γ-Al_2O_3, the mNi-Pn catalysts showed much lower activities for decarbonylation, C−C hydrogenolysis and methanation due to the ligand and ensemble effects of P. The conversion and the selectivity to n-C11 and n-C12 hydrocarbons achieved maximum on 10%Ni-P 2.0 for the 10%Ni-Pn catalysts and on 8%Ni-P2.0 for the mNi-P2.0 catalysts, while the turnover frequency (TOF) of methyl laurate mainly increased with the P/Ni ratio and Ni content. We propose that TOF was influenced by the nickel phosphide phases, the catalyst acidity and the particle size as well as the synergetic effect between the Ni site and acid site. Again, the hydrodeoxygenation pathway of methyl

  6. Level structure of 60Ni from the 58Ni(α,2p#betta#) reaction

    International Nuclear Information System (INIS)

    Chan, T.U.; Morand, C.; Azgui, F.

    1982-03-01

    The 60 Ni nucleus has been studied via the 58 Ni (α, 2p#betta#) reaction at Esub(α)=32 MeV using in-beam #betta# spectroscopy techniques. High-spin states up to 10 MeV excitation have been established. Among the 5 branches depopulating the Yrast Jsup(π)=7 - state, has been found an E3 transition down to the 4 + state. Comparison with direct reaction results leads to assign very probably the [#betta#fsub(5/2),#betta#gsub(9/2)] 7 - configuration to the Jsup(π)=7 - Yrast state at 5349 keV. Other high-spin states might be accounted for by the breaking of the 56 Ni core

  7. Atomistic simulation of the pinning of edge dislocations in Ni by Ni3Al precipitates

    International Nuclear Information System (INIS)

    Kohler, Christopher; Kizler, Peter; Schmauder, Siegfried

    2005-01-01

    Classical molecular dynamics simulations of the interaction of edge dislocations in Ni with chains of spherical Ni 3 Al precipitates are performed using EAM potentials. The order hardening is investigated at temperature T=0 -bar K by determining the critical resolved shear stresses (CRSSs) for a superdislocation that is dissociated into four partial dislocations. The CRSS is computed as a function of the radius and the distance of the precipitates. It is found that for precipitates with a diameter smaller than the dissociation width of perfect edge dislocation in Ni, the CRSS of the trailing dislocation of the superdislocation is a fraction of about 0.4 of the CRSS of the leading dislocation

  8. Sorption properties of new composite materials suitable for radioanalytical determination of 59-Ni and 63-Ni

    International Nuclear Information System (INIS)

    Fisera, O.; Sebesta, F.

    2006-01-01

    New composite materials for separation and radioanalytical determination of radionickel ( 59, 63 Ni) were prepared and their sorption properties were examined. Chelating agents dimethylglyoxime (DMG) and diphenylglyoxime (DFG) as active components were immobilized in porous matrix of binding polymer polyacrylonitrile (PAN). Sorption properties of these materials were compared with commercial Ni Resin (Eichrom Technologies, USA). Weight distribution ratios, sorption kinetics and operating capacities were investigated during experiments performed. The highest weight distribution ratios were found for the material DFG-PAN. The sorbent DMG-PAN has the highest operating capacity. The fastest kinetics of nickel sorption was determined for the commercial Ni Resin. Elution of nickel with nitric acid solution allows subsequent and direct determination of radionickel by liquid scintillation counting. (author)

  9. Effect of amorphous Mg50Ni50 on hydriding and dehydriding behavior of Mg2Ni alloy

    International Nuclear Information System (INIS)

    Guzman, D.; Ordonez, S.; Fernandez, J.F.; Sanchez, C.; Serafini, D.; Rojas, P.A.; Aguilar, C.; Tapia, P.

    2011-01-01

    Composite Mg 2 Ni (25 wt.%) amorphous Mg 50 Ni 50 was prepared by mechanical milling starting with nanocrystalline Mg 2 Ni and amorphous Mg 50 Ni 50 powders, by using a SPEX 8000 D mill. The morphological and microstructural characterization of the powders was performed via scanning electron microscopy and X-ray diffraction. The hydriding characterization of the composite was performed via a solid gas reaction method in a Sievert's-type apparatus at 363 K under an initial hydrogen pressure of 2 MPa. The dehydriding behavior was studied by differential thermogravimetry. On the basis of the results, it is possible to conclude that amorphous Mg 50 Ni 50 improved the hydriding and dehydriding kinetics of Mg 2 Ni alloy upon cycling. A tentative rationalization of experimental observations is proposed. - Research Highlights: → First study of the hydriding behavior of composite Mg 2 Ni (25 wt.%) amorphous Mg 50 Ni 50 . → Microstructural characterization of composite material using XRD and SEM was obtained. → An improved effect of Mg 50 Ni 50 on the Mg 2 Ni hydriding behavior was verified. → The apparent activation energy for the hydrogen desorption of composite was obtained.

  10. When NiO@Ni Meets WS2 Nanosheet Array: A Highly Efficient and Ultrastable Electrocatalyst for Overall Water Splitting.

    Science.gov (United States)

    Wang, Dewen; Li, Qun; Han, Ce; Xing, Zhicai; Yang, Xiurong

    2018-01-24

    The development of low-cost, high-efficiency, and stable bifunctional electrocatalysts toward the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is of paramount importance for large-scale water splitting. Here, we develop a new strategy for the first design and synthesis of a NiO@Ni decorated WS 2 nanosheet array on carbon cloth (NiO@Ni/WS 2 /CC) composite. This composite serves as a unique three-dimensional (3D) synergistic electrocatalyst that not only combines the intrinsic properties of individual NiO@Ni and WS 2 , but also exhibits significantly improved HER and OER activities when compared to that of pure NiO@Ni and WS 2 . This electrocatalyst possesses Pt-like activity for HER and exhibits better OER performance than that for commercial RuO 2 , as well as demonstrating superior long-term durability in alkaline media. Furthermore, it enables an alkaline electrolyzer with a current density of 10 mA cm -2 at a cell voltage as 1.42 V, which is the lowest one among all reported values to date. The excellent performance is mainly attributed to the unique 3D configuration and multicomponent synergies among NiO, Ni, and WS 2 . Our findings provide a new idea to design advanced bifunctional catalysts for water splitting.

  11. Impact of Interstitial Ni on the Thermoelectric Properties of the Half-Heusler TiNiSn

    Directory of Open Access Journals (Sweden)

    Sonia A. Barczak

    2018-03-01

    Full Text Available TiNiSn is an intensively studied half-Heusler alloy that shows great potential for waste heat recovery. Here, we report on the structures and thermoelectric properties of a series of metal-rich TiNi1+ySn compositions prepared via solid-state reactions and hot pressing. A general relation between the amount of interstitial Ni and lattice parameter is determined from neutron powder diffraction. High-resolution synchrotron X-ray powder diffraction reveals the occurrence of strain broadening upon hot pressing, which is attributed to the metastable arrangement of interstitial Ni. Hall measurements confirm that interstitial Ni causes weak n-type doping and a reduction in carrier mobility, which limits the power factor to 2.5–3 mW m−1 K−2 for these samples. The thermal conductivity was modelled within the Callaway approximation and is quantitively linked to the amount of interstitial Ni, resulting in a predicted value of 12.7 W m−1 K−1 at 323 K for stoichiometric TiNiSn. Interstitial Ni leads to a reduction of the thermal band gap and moves the peak ZT = 0.4 to lower temperatures, thus offering the possibility to engineer a broad ZT plateau. This work adds further insight into the impact of small amounts of interstitial Ni on the thermal and electrical transport of TiNiSn.

  12. Controlled growth of Ni/NiO core–shell nanoparticles: Structure, morphology and tuning of magnetic properties

    Energy Technology Data Exchange (ETDEWEB)

    D’Addato, S., E-mail: sergio.daddato@unimore.it [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Spadaro, M.C. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Luches, P. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Grillo, V. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); CNR-IMEM, Parco Area delle Scienze 37/A, 43100 Parma (Italy); Frabboni, S.; Valeri, S. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Ferretti, A.M.; Capetti, E.; Ponti, A. [CNR-ISTM, Laboratorio di Nanotecnologie, via G. Fantoli 16/15, 20138 Milano (Italy)

    2014-07-01

    We performed a detailed study of Ni/NiO core–shell nanoparticles (NP) obtained with a gas aggregation source. The NP oxide shells were produced by oxidizing the NP with different procedures: deposition in oxygen atmosphere, post-annealing in air, sequential deposition of (a) first NiO layer, (b) Ni NP and (c) third NiO Layer. X-ray photoelectron spectroscopy from Ni 2p core-level gave information about the chemical state of Ni in the core and in the oxide shell, while scanning electron microscopy was used for investigation of the NP morphology. High quality scanning transmission electron microscopy in high angle annular dark field mode data demonstrated core–shell structure also for NiO/Ni NP/NiO samples. Field-cooled/zero-field-cooled magnetization curves and field-cooled isothermal hysteresis cycles at T = 5 K were recorded by a SQUID magnetometer. In this way, the relation between magnetic properties and oxide shell structure was assessed, showing the role played by the control of the formation of oxide on the exchange bias and interparticle magnetic interaction.

  13. When NiO@Ni Meets WS2 Nanosheet Array: A Highly Efficient and Ultrastable Electrocatalyst for Overall Water Splitting

    Directory of Open Access Journals (Sweden)

    Dewen Wang

    2017-12-01

    Full Text Available The development of low-cost, high-efficiency, and stable bifunctional electrocatalysts toward the hydrogen evolution reaction (HER and oxygen evolution reaction (OER is of paramount importance for large-scale water splitting. Here, we develop a new strategy for the first design and synthesis of a NiO@Ni decorated WS2 nanosheet array on carbon cloth (NiO@Ni/WS2/CC composite. This composite serves as a unique three-dimensional (3D synergistic electrocatalyst that not only combines the intrinsic properties of individual NiO@Ni and WS2, but also exhibits significantly improved HER and OER activities when compared to that of pure NiO@Ni and WS2. This electrocatalyst possesses Pt-like activity for HER and exhibits better OER performance than that for commercial RuO2, as well as demonstrating superior long-term durability in alkaline media. Furthermore, it enables an alkaline electrolyzer with a current density of 10 mA cm–2 at a cell voltage as 1.42 V, which is the lowest one among all reported values to date. The excellent performance is mainly attributed to the unique 3D configuration and multicomponent synergies among NiO, Ni, and WS2. Our findings provide a new idea to design advanced bifunctional catalysts for water splitting.

  14. Enhanced optical and electrical properties of Ni inserted ITO/Ni/AZO tri-layer structure for photoelectric applications

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, M. Melvin David; Kim, Hyunki [Department of Electrical Engineering, Incheon National University, Incheon 406772 (Korea, Republic of); Park, Yun Chang [Measurement and Analysis Division, National Nanofab Center (NNFC), Daejeon 305-806 (Korea, Republic of); Kim, Joondong, E-mail: joonkim@incheon.ac.kr [Department of Electrical Engineering, Incheon National University, Incheon 406772 (Korea, Republic of)

    2015-05-15

    Highlights: • Ni-embedding transparent conductor effectively reduces the resistivity. • Ni insertion improves the carrier mobility and collection efficiencies. • ITO/Ni/AZO is effective to improve photo-responses compared to ITO/AZO. - Abstract: A thin Ni layer of 5 nm thickness was deposited in between indium-tin-oxide (ITO) and aluminum-doped-zinc oxide (AZO) layers of 50 nm thickness each. The Ni inserting tri-layer structure (ITO/Ni/AZO) showed lower resistivity of 5.51 × 10{sup −4} Ωcm which is nearly 20 times lesser than 97.9 × 10{sup −4} Ωcm of bilayer structure (ITO/AZO). A thin Ni layer in between ITO and AZO enhanced the carrier concentration, mobility and photoresponse behaviors so that figure of merit (FOM) value of ITO/Ni/AZO device was greater than that of ITO/AZO device. ITO/Ni/AZO structure showed improved quantum efficiencies over a broad range of wavelengths (∼350–950 nm) compared to that of ITO/AZO bilayer structure, resulting in enhanced photoresponses. These results show that the optical, electrical and photoresponse properties of ITO/AZO structure could be enhanced by inserting Ni layer of 5 nm thickness in between ITO and AZO layers.

  15. On the Ni-Ion release rate from surfaces of binary NiTi shape memory alloys

    Science.gov (United States)

    Ševčíková, Jana; Bártková, Denisa; Goldbergová, Monika; Kuběnová, Monika; Čermák, Jiří; Frenzel, Jan; Weiser, Adam; Dlouhý, Antonín

    2018-01-01

    The study is focused on Ni-ion release rates from NiTi surfaces exposed in the cell culture media and human vascular endothelial cell (HUVEC) culture environments. The NiTi surface layers situated in the depth of 70 μm below a NiTi oxide scale are affected by interactions between the NiTi alloys and the bio-environments. The finding was proved with use of inductively coupled plasma mass spectrometry and electron microscopy experiments. As the exclusive factor controlling the Ni-ion release rates was not only thicknesses of the oxide scale, but also the passivation depth, which was two-fold larger. Our experimental data strongly suggested that some other factors, in addition to the Ni concentration in the oxide scale, admittedly hydrogen soaking deep below the oxide scale, must be taken into account in order to rationalize the concentrations of Ni-ions released into the bio-environments. The suggested role of hydrogen as the surface passivation agent is also in line with the fact that the Ni-ion release rates considerably decrease in NiTi samples that were annealed in controlled hydrogen atmospheres prior to bio-environmental exposures.

  16. Controlled growth of Ni/NiO core–shell nanoparticles: Structure, morphology and tuning of magnetic properties

    International Nuclear Information System (INIS)

    D’Addato, S.; Spadaro, M.C.; Luches, P.; Grillo, V.; Frabboni, S.; Valeri, S.; Ferretti, A.M.; Capetti, E.; Ponti, A.

    2014-01-01

    We performed a detailed study of Ni/NiO core–shell nanoparticles (NP) obtained with a gas aggregation source. The NP oxide shells were produced by oxidizing the NP with different procedures: deposition in oxygen atmosphere, post-annealing in air, sequential deposition of (a) first NiO layer, (b) Ni NP and (c) third NiO Layer. X-ray photoelectron spectroscopy from Ni 2p core-level gave information about the chemical state of Ni in the core and in the oxide shell, while scanning electron microscopy was used for investigation of the NP morphology. High quality scanning transmission electron microscopy in high angle annular dark field mode data demonstrated core–shell structure also for NiO/Ni NP/NiO samples. Field-cooled/zero-field-cooled magnetization curves and field-cooled isothermal hysteresis cycles at T = 5 K were recorded by a SQUID magnetometer. In this way, the relation between magnetic properties and oxide shell structure was assessed, showing the role played by the control of the formation of oxide on the exchange bias and interparticle magnetic interaction.

  17. Distorted-wave calculations of electron impact ionisation in the Ni isonuclear sequence

    Energy Technology Data Exchange (ETDEWEB)

    Griffin, D C; Pindzola, M S

    1988-10-14

    Electron impact ionisation cross sections for Ni/sup +/, Ni/sup 3+/, Ni/sup 5+/, Ni/sup 6+/, Ni/sup 7+/, Ni/sup 8+/, Ni/sup 12+/, Ni/sup 14+/, and Ni/sup 16+/ are calculated in the distorted-wave approximation. These calculations include contributions from direct ionisation and inner-shell excitation followed by autoionisation. For Ni/sup 12+/, Ni/sup 14+/, and Ni/sup 16+/ we report not only on ionisation cross sections from the ground states but also from the metastable states of these ions. Experimental cross section measurements exist for all ions reported here, except Ni/sup 16+/. The agreement between experiment and theory is reasonably good and improves with ionisation stage.

  18. NiTiCu/AlN/NiTiCu shape memory thin film heterostructures for vibration damping in MEMS

    Energy Technology Data Exchange (ETDEWEB)

    Kaur, Navjot; Kaur, Davinder, E-mail: dkaurfph@iitr.ernet.in

    2014-03-25

    Highlights: • Fabrication of NiTiCu/AlN/NiTiCu heterostructure using dc/rf magnetron sputtering. • Exhibits highest hardness (38 GPa) and elastic modulus (187 GPa). • Enhanced dissipation of mechanical energy (E{sub d} = 5.7 N J). • High damping capacity (0.052) and figure of merit (∼0.62). • Can be applied for vibration damping in MEMS. -- Abstract: Shape memory alloy (NiTiCu) thin films coupled with piezoelectric AlN layer produce an intelligent material for vibration damping. In the present study pure NiTiCu, NiTiCu/AlN and NiTiCu/AlN/NiTiCu heterostructures have been deposited on Si substrate using magnetron sputtering technique. By the use of the interfaces and shape memory effect provided by NiTiCu layers, the damping capacity can be increased along with increase in stiffness and mechanical hardness. The heterostructures were characterized in terms of structural, electrical, morphological and mechanical properties by X-ray diffraction (XRD), four probe resistivity method, atomic force microscopy, field emission scanning electron microscopy, and nanoindentation. The NiTiCu/AlN/NiTiCu heterostructure exhibit enhanced mechanical and damping properties as compared to NiTiCu/AlN and pure NiTiCu. This enhancement in hardness and damping of the heterostructure could be attributed to the shape memory effect of NiTiCu, intrinsic piezoelectricity of AlN and increased number of interfaces in heterostructure that help in dissipation of mechanical vibrations. The findings of this work provide additional impetus for the application of these heterostructures in emerging fields of nanotechnology and microelectro mechanical (MEMS) devices.

  19. NiTiCu/AlN/NiTiCu shape memory thin film heterostructures for vibration damping in MEMS

    International Nuclear Information System (INIS)

    Kaur, Navjot; Kaur, Davinder

    2014-01-01

    Highlights: • Fabrication of NiTiCu/AlN/NiTiCu heterostructure using dc/rf magnetron sputtering. • Exhibits highest hardness (38 GPa) and elastic modulus (187 GPa). • Enhanced dissipation of mechanical energy (E d = 5.7 N J). • High damping capacity (0.052) and figure of merit (∼0.62). • Can be applied for vibration damping in MEMS. -- Abstract: Shape memory alloy (NiTiCu) thin films coupled with piezoelectric AlN layer produce an intelligent material for vibration damping. In the present study pure NiTiCu, NiTiCu/AlN and NiTiCu/AlN/NiTiCu heterostructures have been deposited on Si substrate using magnetron sputtering technique. By the use of the interfaces and shape memory effect provided by NiTiCu layers, the damping capacity can be increased along with increase in stiffness and mechanical hardness. The heterostructures were characterized in terms of structural, electrical, morphological and mechanical properties by X-ray diffraction (XRD), four probe resistivity method, atomic force microscopy, field emission scanning electron microscopy, and nanoindentation. The NiTiCu/AlN/NiTiCu heterostructure exhibit enhanced mechanical and damping properties as compared to NiTiCu/AlN and pure NiTiCu. This enhancement in hardness and damping of the heterostructure could be attributed to the shape memory effect of NiTiCu, intrinsic piezoelectricity of AlN and increased number of interfaces in heterostructure that help in dissipation of mechanical vibrations. The findings of this work provide additional impetus for the application of these heterostructures in emerging fields of nanotechnology and microelectro mechanical (MEMS) devices

  20. Three-dimensional electrode of Ni/Co layered double hydroxides@NiCo2S4@graphene@Ni foam for supercapacitors with outstanding electrochemical performance

    International Nuclear Information System (INIS)

    Tao, Yan; Ruiyi, Li; Lin, Zhou; Chenyang, Ma; Zaijun, Li

    2015-01-01

    We reported a new strategy for fabricating three-dimensiona electrode of Ni/Co layered double hydroxide@NiCo 2 S 4 @graphene@Ni foam for supercapacitors. The resulting 3D electrode offers a jungle-like architecture. The unique structure creates ultra fast electron transfer and electrolyte transport as well as the maximum utilization rate of the space and the surface. The electrode exhibits a prominent advantage of high specific capacitance, high-current capacitive behaviour and cycle stability. - Highlights: • The study developed a new strategy for fabricating 3D electrode of Ni/Co-LDH@NiCo 2 S 4 @G. • The as-prepared 3D electrode offers a jungle-like architecture. • The unique structure creates an efficient conduction network and high mass loading. • The electrode achieves significantly synergetic effect among different materials. • The electrode exhibits an excellent electrochemical performance for supercapacitors. - ABSTRACT: Great challenge for the fabrication of free-standing three-dimensional electrode still remains to simultaneously achieve high specific capacitance, rate performance and cycle stability. The paper reprted a new three-dimensional (3D) electrode of Ni/Co layered double hydroxide@NiCo 2 S 4 @graphene@Ni foam (Ni/Co-LDH@NiCo 2 S 4 @G) for supercapacitors. The as-prepared 3D electrode offers an unique architecture, which create an efficient conduction network and maximum utilization of space and interface. The graphene acts as well-knit and conductive skin coated on the skeleton of Ni foam for growing NiCo 2 S 4 . The conductive NiCo 2 S 4 array serves as bridge between Ni/Co-LDH and graphene, leading to ultrafast electron transfer and electrolyte transport. A slew of splits and holes existing in the NiCo 2 S 4 array play one role as the ion-reservoir to contain host of electrolyte ions. To evaluate the feasibility of 3D electrode’s application in supercapacitors, the electrochemical performance was investigated by using the three

  1. Energetic Mapping of Ni Catalysts by Detailed Kinetic Modeling

    DEFF Research Database (Denmark)

    Bjørgum, Erlend; Chen, De; Bakken, Mari G.

    2005-01-01

    Temperature-programmed desorption (TPD) of CO has been performed on supported and unsupported nickel catalysts. The unsupported Ni catalyst consists of a Ni(14 13 13) single crystal which has been studied under ultrahigh vacuum conditions. The desorption energy for CO at low CO surface coverage...... was found to be 119 kJ/mol, and the binding energy of C to the Ni(111) surface of the crystal was 703 kJ/mol. The supported catalysts consist of nickel supported on hydrotalcite-like compounds with three different Mg2+/Al3+ ratios. The experimental results show that for the supported Ni catalysts TPD of CO...... precursor seems to result in more steplike sites, kinks, and defects for carbon monoxide dissociation. A detailed kinetic modeling of the TPO results based on elementary reaction steps has been conducted to give an energetic map of supported Ni catalysts. Experimental results from the ideal Ni surface fit...

  2. Synthesis of electroplated {sup 63}Ni source and betavoltaic battery

    Energy Technology Data Exchange (ETDEWEB)

    Uhm, Young Rang; Yoo, Kwon Mo; Choi, Sang Mu; Kim, Jin Joo; Son, Kwang Jae [Radioisotope Research Division, Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-12-15

    Radioisotope (Nuclear) battery using {sup 63}Ni was prepared as beta cell. The electroplated {sup 63}Ni on Ni foil is fabricated, and beta cell and photovoltaic hybrid battery was designed to use at both day and night in space project. A Ni-plating solution is prepared by dissolving metal particles including {sup 62}Ni and {sup 63}Ni from neutron irradiation of (n,γ). Electroplating solution of a chloride bath consists on nickel ions in HCl, H{sub 3}BO{sub 3}, and KOH. The deposition was carried out at current density of 10 mA cm{sup -2}. The prepared beta source was attached on a PN junction and measured I-V properties. The power output at activity of 0.07 mCi and 0.45 mCi were 0.55 pW and 2.69 nW, respectively.

  3. Microstructure and martensitic transformation of Ni-Ti-Pr alloys

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Chunwang [Inner Mongolia University of Technology, College of Science, Hohhot (China); Shanghai Maritime University, College of Arts and Sciences, Shanghai (China); Zhao, Shilei; Jin, Yongjun; Hou, Qingyu [Inner Mongolia University of Technology, College of Science, Hohhot (China); Guo, Shaoqiang [Beihang University, Key Laboratory of Micro-nano Measurement, Manipulation and Physics (Ministry of Education), Department of Physics, Beijing (China)

    2017-09-15

    The effect of Pr addition on the microstructure and martensitic transformation behavior of Ni{sub 50}Ti{sub 50-x}Pr{sub x} (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9) alloys were investigated experimentally. Results show that the microstructures of Ni-Ti-Pr alloys consist of the NiTi matrix and the NiPr precipitate with the Ti solute. The martensitic transformation start temperature decreases gradually with the increase in Pr fraction. The stress around NiPr precipitates is responsible for the decrease in martensitic transformation temperature with the increase in Pr fraction in Ni-Ti-Pr alloys. (orig.)

  4. Near-surface segregation in irradiated Ni3Si

    International Nuclear Information System (INIS)

    Wagner, W.; Rehn, L.E.; Wiedersich, H.

    1982-01-01

    The radiation-induced growth of Ni 3 Si films on the surfaces of Ni(Si) alloys containing = 3 Si phase has been observed. Post-irradiation depth profiling by Auger electron spectroscopy, as well as in situ analysis by high-resolution Rutherford backscattering spectrometry, reveals Si-enrichment at the surfaces of Ni(Si) alloys in excess of stoichiometric Ni 3 Si during irradiation. Thin, near-surface layers with silicon concentrations of 28 to 30 at.% are observed, and even higher Si enrichment is found in the first few atom layers. Transmission electron microscopy and selected area-electron diffraction were employed to characterize these Si-enriched layers. A complex, multiple-spot diffraction pattern is observed superposed on the diffraction pattern of ordered Ni 3 Si. The d-spacings obtained from the extra spots are consistent with those of the orthohexagonal intermetallic compound Ni 5 Si 2 . (author)

  5. Crystal growth velocity in deeply undercooled Ni-Si alloys

    Science.gov (United States)

    Lü, Y. J.

    2012-02-01

    The crystal growth velocity of Ni95Si5 and Ni90Si10 alloys as a function of undercooling is investigated using molecular dynamics simulations. The modified imbedded atom method potential yields the equilibrium liquidus temperatures T L ≈ 1505 and 1387 K for Ni95Si5 and Ni90Si10 alloys, respectively. From the liquidus temperatures down to the deeply undercooled region, the crystal growth velocities of both the alloys rise to the maximum with increasing undercooling and then drop slowly, whereas the athermal growth process presented in elemental Ni is not observed in Ni-Si alloys. Instead, the undercooling dependence of the growth velocity can be well-described by the diffusion-limited model, furthermore, the activation energy associated with the diffusion from melt to interface increases as the concentration increases from 5 to 10 at.% Si, resulting in the remarkable decrease of growth velocity.

  6. Diffusion studies in amorphous NiZr alloys

    International Nuclear Information System (INIS)

    Hahn, H.; Averback, R.S.; Hoshino, K.; Rothman, S.J.

    1987-06-01

    Tracer impurity and self diffusion measurements have been made on amorphous (a-) NiZr alloys using radioactive tracer, Secondary Ion Mass Spectrometry and Rutherford backscattering techniques. The temperature dependence of diffusion in a-NiZr can be represented in the form D = D 0 exp(-Q/kT), with no structural relaxation effects being observed. The mobility of an atom in a-NiZr increased dramatically with decreasing atomic radius of the diffusing atom and also with decreasing Ni content for Ni concentrations below ≅40 at. %. These diffusion characteristics in a-NiZr are remarkably similar to those in α-Zr and α-Ti. These mechanisms assume that Zr and Ti provide a close packed structure, either crystalline or amorphous, through which small atoms diffuse by an interstitial mechanism and large atoms diffuse by a vacancy mechanism. 12 refs., 2 figs., 2 tabs

  7. Thermal variation of magnetization in Ni/V multilayers

    International Nuclear Information System (INIS)

    Benkirane, K.; Elkabil, R.; Hamdoun, A.; Lassri, M.; Abid, M.; Lassri, H.; Krishnan, R.

    2004-01-01

    The magnetic properties of Ni/V multilayers, prepared by the RF sputtering method, have been systematically studied by magnetic measurements. The magnetization decreases with a decrease in Ni layer thickness tNi and the analysis of the results at 5K indicates the presence of a dead Ni layer about 12A thick. The effective anisotropy Keff of Ni/V multilayers is obtained using a torque magnetometer. The interface contribution to the magnetic anisotropy is practically negligible. A spin-wave theory has been used to explain the temperature dependence of the magnetization and the approximate values for the bulk exchange interaction Jb, surface exchange interaction JS, and the interlayer coupling strength JI for various Ni layer thicknesses have been obtained

  8. Synthesis of electroplated 63Ni source and betavoltaic battery

    International Nuclear Information System (INIS)

    Uhm, Young Rang; Yoo, Kwon Mo; Choi, Sang Mu; Kim, Jin Joo; Son, Kwang Jae

    2015-01-01

    Radioisotope (Nuclear) battery using 63 Ni was prepared as beta cell. The electroplated 63 Ni on Ni foil is fabricated, and beta cell and photovoltaic hybrid battery was designed to use at both day and night in space project. A Ni-plating solution is prepared by dissolving metal particles including 62 Ni and 63 Ni from neutron irradiation of (n,γ). Electroplating solution of a chloride bath consists on nickel ions in HCl, H 3 BO 3 , and KOH. The deposition was carried out at current density of 10 mA cm -2 . The prepared beta source was attached on a PN junction and measured I-V properties. The power output at activity of 0.07 mCi and 0.45 mCi were 0.55 pW and 2.69 nW, respectively

  9. Equilibrium relationships in the system Ni-U-O

    International Nuclear Information System (INIS)

    Mansour, N.A.L.

    1980-01-01

    Phase relationships were established in air and in oxygen. Mixtures of NiO and U 3 O 8 oxidize to NiUO 4 . The results of analysis of NiUO 4 were identical to those previously published for NiU 3 O 10 . The uranate dissociates to NiO and U 3 O 8 at a temperature higher than that of their oxidation back to the uranate on cooling because of the difficulty of oxygen diffusion and uranate nucleation. Accordingly, dissociation temperature was taken to represent equilibrium and was used to calculate roughly ΔH and ΔS for the reaction of dissociation. In presence of NiO, U 3 O 8 melts partially and does not dissociate to the lower oxide. (orig.) [de

  10. Coercivity scaling in antidot lattices in Fe, Ni, and NiFe thin films

    Energy Technology Data Exchange (ETDEWEB)

    Gräfe, Joachim, E-mail: graefe@is.mpg.de; Schütz, Gisela; Goering, Eberhard J., E-mail: goering@is.mpg.de

    2016-12-01

    Antidot lattices can be used to artificially engineer magnetic properties in thin films, however, a conclusive model that describes the coercivity enhancement in this class of magnetic nano-structures has so far not been found. We prepared Fe, Ni, and NiFe thin films and patterned each with 21 square antidot lattices with different geometric parameters and measured their hysteretic behavior. On the basis of this extensive dataset we are able to provide a model that can describe both the coercivity scaling over a wide range of geometric lattice parameters and the influence of different materials.

  11. Sideward flow of K+ in Ru+Ru and Ni+Ni reactions sat SIS energies

    International Nuclear Information System (INIS)

    Crochet, P.; Herrmann, N.; Wisniewski, K.

    2000-01-01

    Experimental data on K + and proton sideward flow measured with the FOPI detector at SIS/GSI in the reactions Ru+Ru at 1.69 A GeV and Ni+Ni at 1.93 A GeV are presented. The K + sideward flow is found to be anti-correlated (correlated) with the one of protons at low (high) transverse momenta. When compared to the predictions of a transport model, the data favour the existence of an in-medium repulsive K + -nucleon potential. (author)

  12. Shape and size effects on layered Ni/PZT/Ni composites magnetoelectric performance

    Energy Technology Data Exchange (ETDEWEB)

    Pan, D A; Zhang, S G; Qiao, L J [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Volinsky, Alex A [Department of Mechanical Engineering, University of South Florida, Tampa FL 33620 (United States)], E-mail: lqiao@ustb.edu.cn

    2008-09-07

    This paper presents the magnetoelectric (ME) effect in trilayered Ni/PZT/Ni composites which is related to their size and shape. The ME composites with the same interfacial areas but different geometrical shapes have different ME voltage coefficients. Longitudinal resonant modes in the rectangular and triangular trilayered ME composites were studied. One should choose optimized size, shape and working frequency of the ME composites in order to gain the maximum ME effect. This study plays a guiding role for trilayered ME composites design for real applications. (fast track communication)

  13. Microstructural evolution of neutron-irradiated Ni-Si and Ni-Al alloys

    Science.gov (United States)

    Takahashi, H.; Garner, F. A.

    1992-10-01

    Additions of silicon and aluminum suppress the neutron-induced swelling of pure nickel but to different degrees. Silicon is much more effective initially when compared to aluminum on a per atom basis but silicon exhibits a nonmonotonic influence on swelling with increasing concentration. Silicon tends to segregate toward grain boundaries while aluminum segregates away from these boundaries. Whereas the formation of the Ni 3Si phase is frequently observed in charged particle irradiation experiments conducted at much higher displacement rates, it did not occur during neutron irradiation in this study. Precipitation also did not occur in Ni-5Al during neutron irradiation, nor has it been reported to occur during ion irradiation.

  14. Strengthening by ordered precipitates in a Ni--Ni4Mo system

    International Nuclear Information System (INIS)

    Goodrum, J.W.; LeFevre, B.G.

    1977-01-01

    The strength characteristics and microstructures of aged Ni-Mo alloys containing ordered (Ni 4 Mo) precipitates were studied as a function of aging time and temperature. It was found that 17 at. percent Mo alloy aged at 750 0 C produced a uniform dispersion of cuboidal β precipitates which coarsened with time producing a gradual increase in flow stress. The flow stress increment was found to vary in qualitative agreement with both order strengthening and coherency strain models. Both these models give over-estimates of the strengthening increment. A negative dependence of flow stress on temperature is attributed to coherency strain contributions

  15. The nature of strong Brønsted acidity of Ni-SMM clay

    NARCIS (Netherlands)

    Yue, C.; Liu, C.; Mezari, B.; Brückner, A.; Pidko, E.A.; Rigutto, M.S.; Hensen, E.J.M.

    2016-01-01

    The origin of the high Brønsted acidity of Ni-SMM (Ni-substituted synthetic mica-montmorillonite; beidellite structure) clays was investigated. Ni-SMM clays with varying F content, SMM with F and Ni-SMM without F in the structure were synthesized under hydrothermal conditions. Ni-SMM clays with

  16. Los niños y los videojuegos

    OpenAIRE

    Orrego Gaviria, Jaime; Fundación Valle de Lili

    2007-01-01

    Los niños y los videojuegos / Efectos perjudiciales de la utilización de los videojuegos por los niños y adolescentes/ Efectos benéficos de la de la utilización de los videojuegos por los niños y adolescentes/ Recomendaciones para favorecer el uso adecuado/ Sistema de clasificación de los videojuegos

  17. Electrochemical Characterization of Ni/(Sc)YSZ Electrodes

    DEFF Research Database (Denmark)

    Ramos, Tania; Thydén, Karl Tor Sune; Mogensen, Mogens Bjerg

    2010-01-01

    Investigations of Ni/(Sc)YSZ cermets for solid oxide cells (SOCs) were performed by electrochemical impedance spectroscopy (EIS), under varying experimental conditions and upon redox cycling, using three different designs of symmetric cells. The deconvolution and fitting of the obtained impedance...... parameters. Initial degradation results for both Ni/ScYSZ and Ni/YSZ based anodes under very high steam content are also reported. ©2010 COPYRIGHT ECS - The Electrochemical Society...

  18. Irradiation-induced precipitation in Ni--Si alloys

    International Nuclear Information System (INIS)

    Barbu, A.; Ardell, A.J.

    1975-07-01

    The microstructures of Ni + ion-irradiated Ni--Si solid-solution alloys, containing 2, 4, 6 and 8 at. percent Si were investigated as a function of dose, dose-rate, and temperature. Results of transmission electron microscopy and other data show the precipitation of γ' (Ni 3 Si) in all samples irradiated at 500 0 C. Characteristics of the precipitates are described and a mechanism for their formation is suggested. (U.S.)

  19. Ni-YSZ graded coatings produced by dipping

    International Nuclear Information System (INIS)

    Ferrari, B.; Moreno, R.

    2004-01-01

    A new colloidal processing route for the shaping of a graded Ni-YSZ composite for applications in SOFC devices is described. A Ni foil is coated by Ni/YSZ layers by dipping in aqueous suspensions with an organic binder. Behind the metal-ceramic layers introduced to improve adhesion, an outer thin layer of nanosized YSZ is formed by electrophoretic deposition. (Abstract Copyright [2004], Wiley Periodicals, Inc.)

  20. Low-field spin dynamics of Cr7Ni and Cr7Ni-Cu-Cr7Ni molecular rings as detected by μsR

    OpenAIRE

    Sanna, S.; Arosio, P.; Bordonali, L.; Adelnia, F.; Mariani, M.; Garlatti, E.; Baines, C.; Amato, A.; Sabareesh, K. P.V.; Timco, G.; Winpenny, R. E.P.; Blundell, S. J.; Lascialfari, A.

    2017-01-01

    Muon spin rotation measurements were used to investigate the spin dynamics of heterometallic Cr7Ni and Cr7Ni-Cu-Cr7Ni molecular clusters. In Cr7Ni the magnetic ions are arranged in a quasiplanar ring and interact via an antiferromagnetic exchange coupling constant J, while Cr7Ni-Cu-Cr7Ni is composed of two Cr7Ni linked by a bridging moiety containing one Cu ion, that induces an inter-ring ferromagnetic interaction J ≪ J. The longitudinal muon relaxation rate λ collected at low magnetic fields...

  1. Comparison of three Ni-Hard I alloys

    Energy Technology Data Exchange (ETDEWEB)

    Dogan, Omer N.; Hawk, Jeffrey A.; Rice, J. (Texaloy Foundry Co., Inc., Floresville, Texas)

    2004-09-01

    This report documents the results of an investigation which was undertaken to reveal the similarities and differences in the mechanical properties and microstructural characteristics of three Ni-Hard I alloys. One alloy (B1) is ASTM A532 class IA Ni-Hard containing 4.2 wt. pct. Ni. The second alloy (B2) is similar to B1 but higher in Cr, Si, and Mo. The third alloy (T1) also falls in the same ASTM specification, but it contains 3.3 wt. pct. Ni. The alloys were evaluated in both as-cast and stress-relieved conditions except for B2, which was evaluated in the stress-relieved condition only. While the matrix of the high Ni alloys is composed of austenite and martensite in both conditions, the matrix of the low Ni alloy consists of a considerable amount of bainite, in addition to the martensite and the retained austenite in as cast condition, and primarily bainite, with some retained austenite, in the stress relieved condition. It was found that the stress relieving treatment does not change the tensile strength of the high Ni alloy. Both the as cast and stress relieved high Ni alloys had a tensile strength of about 350 MPa. On the other hand, the tensile strength of the low Ni alloy increased from 340 MPa to 452 MPa with the stress relieving treatment. There was no significant difference in the wear resistance of these alloys in both as-cast and stressrelieved conditions.

  2. An investigation of the oxidized Ni/InAs interface

    International Nuclear Information System (INIS)

    Venter, A.; Botha, J.R.; Swart, H.C.; Naidoo, S.; Olivier, E.J.

    2009-01-01

    Ni was resistively deposited onto bulk InAs and subsequently oxidized in an O 2 atmosphere. The anneal temperature and time were 450 deg. C and 2.5 h, respectively. X-ray diffraction of the oxidized Ni/InAs sample revealed the formation of In 3 Ni 2 and In 2 O 3 on the front suggesting inter diffusion of In, Ni and O. NiO was not detected by X-ray diffraction. In a preliminary study, using glass as a substrate, NiO readily formed when using these oxidation parameters. Conductivity measurements of the oxidized Ni/InAs surface revealed a conducting front and insulating rear surface while TEM of the Ni/InAs interface revealed an intermediate amorphous diffusion zone between the 'oxidized' Ni layer and the bulk InAs. A closer investigation of the intermediate layer supports the X-ray diffraction results, suggesting compound formation due to diffusion of oxygen and nickel into the substrate, and out-diffusion of In and As from the bulk of the sample. AES was used to further elucidate these results.

  3. An investigation of the oxidized Ni/InAs interface

    Energy Technology Data Exchange (ETDEWEB)

    Venter, A., E-mail: andre.venter@nmmu.ac.z [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa); Botha, J.R. [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa); Swart, H.C. [Department of Physics, University of the Free State, PO Box 339, Bloemfontein 9300 (South Africa); Naidoo, S.; Olivier, E.J. [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa)

    2009-12-01

    Ni was resistively deposited onto bulk InAs and subsequently oxidized in an O{sub 2} atmosphere. The anneal temperature and time were 450 deg. C and 2.5 h, respectively. X-ray diffraction of the oxidized Ni/InAs sample revealed the formation of In{sub 3}Ni{sub 2} and In{sub 2}O{sub 3} on the front suggesting inter diffusion of In, Ni and O. NiO was not detected by X-ray diffraction. In a preliminary study, using glass as a substrate, NiO readily formed when using these oxidation parameters. Conductivity measurements of the oxidized Ni/InAs surface revealed a conducting front and insulating rear surface while TEM of the Ni/InAs interface revealed an intermediate amorphous diffusion zone between the 'oxidized' Ni layer and the bulk InAs. A closer investigation of the intermediate layer supports the X-ray diffraction results, suggesting compound formation due to diffusion of oxygen and nickel into the substrate, and out-diffusion of In and As from the bulk of the sample. AES was used to further elucidate these results.

  4. Oxidation of hydrogen peroxide by [Ni III (cyclam)

    Indian Academy of Sciences (India)

    The kinetics of oxidation of H2O2 by [NiIII(cyclam)]3+, [NiIIIL1], was studied in aqueous acidic media at 25°C and I = 0.5M (NaClO4). The [NiIIIL1] to [NiIIL1] reduction was found to be fast in the presence of Cu(II) ion than the oxidation of the cyclam ligand by ·OH. The rate constant showed an inverse acid dependence on H+ ...

  5. Level density of radioactive doubly-magic nucleus 56Ni

    International Nuclear Information System (INIS)

    Santhosh Kumar, S.; Rengaiyan, R.; Victor Babu, A.; Preetha, P.

    2012-01-01

    In this work the single particle energies are obtained by diagonalising the Nilsson Hamiltonian in the cylindrical basis and are generated up to N =11 shells for the isotopes of Ni from A = 48-70, emphasizing the three magic nuclei viz, 48 Ni, 56 Ni and 68 Ni. The statistical quantities like excitation energy, level density parameter and nuclear level density which play the important roles in the nuclear structure and nuclear reactions can be calculated theoretically by means of the Statistical or Partition function method. Hence the statistical model approach is followed to probe the dynamical properties of the nucleus in the microscopic level

  6. CVD Graphene/Ni Interface Evolution in Sulfuric Electrolyte

    DEFF Research Database (Denmark)

    Yivlialin, Rossella; Bussetti, Gianlorenzo; Duò, Lamberto

    2018-01-01

    Systems comprising single and multilayer graphene deposited on metals and immersed in acid environments have been investigated, with the aim of elucidating the mechanisms involved, for instance, in hydrogen production or metal protection from corrosion. In this work, a relevant system, namely...... chemical vapor deposited (CVD) multilayer graphene/Ni (MLGr/Ni), is studied when immersed in a diluted sulfuric electrolyte. The MLGr/Ni electrochemical and morphological properties are studied in situ and interpreted in light of the highly oriented pyrolytic graphite (HOPG) electrode behavior, when...... immersed in the same electrolyte. Following this interpretative framework, the dominant role of the Ni substrate in hydrogen production is clarified....

  7. Design and fabrication of Ni nanowires having periodically hollow nanostructures

    Science.gov (United States)

    Sada, Takao; Fujigaya, Tsuyohiko; Nakashima, Naotoshi

    2014-09-01

    We propose a concept for the design and fabrication of metal nanowires having periodically hollow nanostructures inside the pores of an anodic aluminum oxide (AAO) membrane using a sacrificial metal. In this study, nickel (Ni) and silver (Ag) were used as the base metal and the sacrificial metal, respectively. Alternating an applied potential between -0.4 and -1.0 V provided alternatively deposited Ni and Ag segments in a Ni-Ag `barcode' nanowire with a diameter of 18 or 35 nm. After etching away the Ag segments, we fabricated Ni nanowires with nanopores of 12 +/- 5.3 nm. Such nanostructure formation is explained by the formation of a Ni shell layer over the surface of the Ag segments due to the strong affinity of Ni2+ for the interior surfaces of AAO. The Ni shell layer allows the Ni segments to remain even after dissolution of the Ag segments. Because the electroplating conditions can be easily controlled, we could carefully adjust the size and pitch of the periodically hollow nanospaces. We also describe a method for the fabrication of Ni nanorods by forming an Ag shell instead of a Ni shell on the Ni-Ag barcode nanowire, in which the interior of the AAO surfaces was modified with a compound bearing a thiol group prior to electroplating.We propose a concept for the design and fabrication of metal nanowires having periodically hollow nanostructures inside the pores of an anodic aluminum oxide (AAO) membrane using a sacrificial metal. In this study, nickel (Ni) and silver (Ag) were used as the base metal and the sacrificial metal, respectively. Alternating an applied potential between -0.4 and -1.0 V provided alternatively deposited Ni and Ag segments in a Ni-Ag `barcode' nanowire with a diameter of 18 or 35 nm. After etching away the Ag segments, we fabricated Ni nanowires with nanopores of 12 +/- 5.3 nm. Such nanostructure formation is explained by the formation of a Ni shell layer over the surface of the Ag segments due to the strong affinity of Ni2+ for the

  8. Comparative study of NiW, NiMo and MoW prepared by mechanical alloying

    International Nuclear Information System (INIS)

    Gonzalez, G.; Sagarzazu, A.; Villalba, R.; Ochoa, J.

    2007-01-01

    The present work concern the amorphisation process induced by mechanical alloying in the NiW, NiMo and MoW systems. The alloys chosen combine a group of transition elements varying from very similar atomic radius and electronic valences (MoW) to different ones (NiW and NiMo). The three systems achieved an amorphous state after 50 h of milling. The mechanism of amorphisation proposed for NiW and NiMo was the combined effect of an excess concentration of the solute atoms entering into the structure of one of the elements and a critical concentration of defects. Continuous formation of an amorphous phase at the interface of the crystalline phase was observed during the process. MoW seems to amorphize by continuous reduction of grain size down to a critical value where the amorphisation takes place

  9. The irradiation hardening of Ni-Mo-Cr and Ni-W-Cr alloy under Xe26+ ion irradiation

    Science.gov (United States)

    Chen, Huaican; Hai, Yang; Liu, Renduo; Jiang, Li; Ye, Xiang-xi; Li, Jianjian; Xue, Wandong; Wang, Wanxia; Tang, Ming; Yan, Long; Yin, Wen; Zhou, Xingtai

    2018-04-01

    The irradiation hardening of Ni-Mo-Cr and Ni-W-Cr alloy was investigated. 7 MeV Xe26+ ion irradiation was performed at room temperature and 650 °C with peak damage dose from 0.05 to 10 dpa. With the increase of damage dose, the hardness of Ni-Mo-Cr and Ni-W-Cr alloy increases, and reaches saturation at damage dose ≥1 dpa. Moreover, the damage dose dependence of hardness in both alloys can be described by the Makin and Minter's equation, where the effective critical volume of obstacles can be used to represent irradiation hardening resistance of the alloys. Our results also show that Ni-W-Cr alloy has better irradiation hardening resistance than Ni-Mo-Cr alloy. This is ascribed to the fact that the W, instead of Mo in the alloy, can suppress the formation of defects under ion irradiation.

  10. Flexible bottom-emitting white organic light-emitting diodes with semitransparent Ni/Ag/Ni anode.

    Science.gov (United States)

    Koo, Ja-Ryong; Lee, Seok Jae; Lee, Ho Won; Lee, Dong Hyung; Yang, Hyung Jin; Kim, Woo Young; Kim, Young Kwan

    2013-05-06

    We fabricated a flexible bottom-emitting white organic light-emitting diode (BEWOLED) with a structure of PET/Ni/Ag/Ni (3/6/3 nm)/ NPB (50 nm)/mCP (10 nm)/7% FIrpic:mCP (10 nm)/3% Ir(pq)(2) acac:TPBi (5 nm)/7% FIrpic:TPBi (5 nm)/TPBi (10 nm)/Liq (2 nm)/ Al (100 nm). To improve the performance of the BEWOLED, a multilayered metal stack anode of Ni/Ag/Ni treated with oxygen plasma for 60 sec was introduced into the OLED devices. The Ni/Ag/Ni anode effectively enhanced the probability of hole-electron recombination due to an efficient hole injection into and charge balance in an emitting layer. By comparing with a reference WOLED using ITO on glass, it is verified that the flexible BEWOLED showed a similar or better electroluminescence (EL) performance.

  11. Hydride Reactivity of Ni-II-X-Ni-II Entities : Mixed-Valent Hydrido Complexes and Reversible Metal Reduction

    NARCIS (Netherlands)

    Gehring, Henrike; Metzinger, Ramona; Herwig, Christian; Intemann, Julia; Harder, Sjoerd; Limberg, Christian

    After the lithiation of PYR-H2 (PYR2-=[{NC(Me)C(H)C(Me)NC6H3(iPr)2}2(C5H3N)]2-), which is the precursor of an expanded beta-diketiminato ligand system with two binding pockets, its reaction with [NiBr2(dme)] led to a dinuclear nickel(II)bromide complex, [(PYR)Ni(mu-Br)NiBr] (1). The bridging bromide

  12. Studies on the valence electronic structure of Fe and Ni in FexNi1−x ...

    Indian Academy of Sciences (India)

    structure of Fe and Ni in various Fex Ni1−x alloys. Since Kβ-to-Kα X-ray intensity ratio has been reported [2–7] to be a sensitive physical parameter to investigate the changes in the valence electronic structure of 3d-transition metals [2], we have undertaken the study of the valence electronic structure of Fe and Ni in the Fex ...

  13. Effects of Ni content on nanocrystalline Fe–Co–Ni ternary alloys synthesized by a chemical reduction method

    Energy Technology Data Exchange (ETDEWEB)

    Chokprasombat, Komkrich, E-mail: komkrich28@gmail.com [Department of Physics, Faculty of Science, Thaksin University, Phatthalung 93210 Thailand (Thailand); Pinitsoontorn, Supree [Integrated Nanotechnology Research Center, Department of Physics, Faculty of Science, Khon Kaen University, Khon Kaen 40002 Thailand (Thailand); Maensiri, Santi [School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000 Thailand (Thailand)

    2016-05-01

    Magnetic properties of Fe–Co–Ni ternary alloys could be altered by changing of the particle size, elemental compositions, and crystalline structures. In this work, Fe{sub 50}Co{sub 50−x}Ni{sub x} nanoparticles (x=10, 20, 40, and 50) were prepared by the novel chemical reduction process. Hydrazine monohydrate was used as a reducing agent under the concentrated basic condition with the presence of poly(vinylpyrrolidone). We found that the nanoparticles were composed of Fe, Co and Ni with compositions according to the molar ratio of the metal sources. Interestingly, the particles were well-crystalline at the as-prepared state without post-annealing at high temperature. Increasing Ni content resulted in phase transformation from body centered cubic (bcc) to face centered cubic (fcc). For the fcc phase, the average particle size decreased when increased the Ni content; the Fe{sub 50}Ni{sub 50} nanoparticles had the smallest average size with the narrowest size distribution. In additions, the particles exhibited ferromagnetic properties at room temperature with the coercivities higher than 300 Oe, and the saturation magnetiation decreased with increasing Ni content. These results suggest that the structural and magnetic properties of Fe–Co–Ni alloys could be adjusted by varying the Ni content. - Highlights: • We prepared nanocrystalline Fe–Co–Ni alloys by a novel chemical reduction process. • Elemental compositions could be well controlled by the molar ratio of metal sources. • Particle size and magnetic properties clearly depended on the Ni contents. • Fe{sub 50}Co{sub 10}Ni{sub 40} exhibited high saturation magnetization of 126.3 emu/g.

  14. Effect of Ni content on the morphological evolution of Ni-YSZ solid oxide fuel cell electrodes

    Science.gov (United States)

    Chen-Wiegart, Yu-chen Karen; Kennouche, David; Scott Cronin, J.; Barnett, Scott A.; Wang, Jun

    2016-02-01

    The coarsening of Ni in Ni-yttria-stabilized zirconia (YSZ) anodes is a potential cause of long term solid oxide fuel cells (SOFC) performance degradation. The specifics of the Ni-YSZ structure—including Ni/YSZ ratio, porosity, and particle size distributions—are normally selected to minimize anode polarization resistance, but they also impact long-term stability. A better understanding of how these factors influence long-term stability is important for designing more durable anodes. The effect of structural details, e.g., Ni-YSZ ratio, on Ni coarsening has not been quantified. Furthermore, prior measurements have been done by comparing evolved structures with control samples, such that sample-to-sample variations introduce errors. Here, we report a four dimensional (three spatial dimensions and time) study of Ni coarsening in Ni-YSZ anode functional layers with different Ni/YSZ ratios, using synchrotron x-ray nano-tomography. The continuous structural evolution was observed and analyzed at sub-100 nm resolution. It is shown quantitatively that increasing the Ni/YSZ ratio increases the Ni coarsening rate. This is due to both increased pore volume and a decrease in the YSZ volume fraction, such that there is more free volume and a less obtrusive YSZ network, both of which allow greater Ni coarsening. The results are shown to be in good agreement with a power-law coarsening model. The finding is critical for informing the design of SOFC electrode microstructures that limit coarsening and performance degradation.

  15. Formation of nickel germanides from Ni layers with thickness below 10 nm

    Energy Technology Data Exchange (ETDEWEB)

    Jablonka, Lukas; Kubart, Tomas; Primetzhofer, Daniel; Abedin, Ahmad; Hellström, Per-Erik; Östling, Mikael; Jordan-Sweet, Jean; Lavoie, Christian; Zhang, Shi-Li; Zhang, Zhen

    2017-03-01

    The authors have studied the reaction between a Ge (100) substrate and thin layers of Ni ranging from 2 to 10 nm in thickness. The formation of metal-rich Ni5Ge3Ni5Ge3 was found to precede that of the monogermanide NiGe by means of real-time in situ x-ray diffraction during ramp-annealing and ex situ x-ray pole figure analyses for phase identification. The observed sequential growth of Ni5Ge3Ni5Ge3 and NiGe with such thin Ni layers is different from the previously reported simultaneous growth with thicker Ni layers. The phase transformation from Ni5Ge3Ni5Ge3 to NiGe was found to be nucleation-controlled for Ni thicknesses <5 nm<5 nm, which is well supported by thermodynamic considerations. Specifically, the temperature for the NiGe formation increased with decreasing Ni (rather Ni5Ge3Ni5Ge3) thickness below 5 nm. In combination with sheet resistance measurement and microscopic surface inspection of samples annealed with a standard rapid thermal processing, the temperature range for achieving morphologically stable NiGe layers was identified for this standard annealing process. As expected, it was found to be strongly dependent on the initial Ni thickness

  16. The Ni-rich Part of the Ni-P-Sn System: Isothermal Sections

    Czech Academy of Sciences Publication Activity Database

    Schmetterer, C.; Vízdal, J.; Kroupa, Aleš; Kodentsov, A.; Ipser, H.

    2009-01-01

    Roč. 38, č. 11 (2009), s. 2275-2300 ISSN 0361-5235 R&D Projects: GA MŠk(CZ) OC08053 Institutional research plan: CEZ:AV0Z20410507 Keywords : lead free solder * phase diagram * Ni-P-Sn Subject RIV: BJ - Thermodynamics Impact factor: 1.428, year: 2009

  17. Fabrication of TiNi/CFRP smart composite using cold drawn TiNi wires

    Science.gov (United States)

    Xu, Ya; Otsuka, Kazuhiro; Toyama, Nobuyuki; Yoshida, Hitoshi; Jang, Byung-Koog; Nagai, Hideki; Oishi, Ryutaro; Kishi, Teruo

    2002-07-01

    In recent years, pre-strained TiNi shape memory alloys (SMA) have been used for fabricating smart structure with carbon fibers reinforced plastics (CFRP) in order to suppress microscopic mechanical damages. However, since the cure temperature of CFRP is higher than the reverse transformation temperatures of TiNi SMA, special fixture jigs have to be used for keeping the pre-strain during fabrication, which restricted its practical application. In order to overcome this difficulty, we developed a new method to fabricate SMA/CFRP smart composites without using special fixture jigs by controlling the transformation temperatures of SMA during fabrication. This method consists of using heavily cold-worked wires to increase the reverse transformation temperatures, and of using flash electrical heating of the wires after fabrication in order to decrease the reverse transformation temperatures to a lower temperature range again without damaging the epoxy resin around SMA wires. By choosing proper cold-working rate and composition of TiNi alloys, the reverse transformation temperatures were well controlled, and the TiNi/CFRP hybrid smart composite was fabricated without using special fixture jigs. The damage suppressing effect of cold drawn wires embedded in CFRP was confirmed.

  18. Transformation dynamics of Ni clusters into NiO rings under electron beam irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Knez, Daniel, E-mail: daniel.knez@felmi-zfe.at [Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17, 8010 Graz (Austria); Graz Centre for Electron Microscopy, Steyrergasse 17, 8010 Graz (Austria); Thaler, Philipp; Volk, Alexander [Institute of Experimental Physics, Graz University of Technology, Petersgasse 16, 8010 Graz (Austria); Kothleitner, Gerald [Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17, 8010 Graz (Austria); Graz Centre for Electron Microscopy, Steyrergasse 17, 8010 Graz (Austria); Ernst, Wolfgang E. [Institute of Experimental Physics, Graz University of Technology, Petersgasse 16, 8010 Graz (Austria); Hofer, Ferdinand [Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17, 8010 Graz (Austria); Graz Centre for Electron Microscopy, Steyrergasse 17, 8010 Graz (Austria)

    2017-05-15

    We report the transformation of nickel clusters into NiO rings by an electron beam induced nanoscale Kirkendall effect. High-purity nickel clusters consisting of a few thousand atoms have been used as precursors and were synthesized with the superfluid helium droplet technique. Aberration-corrected, analytical scanning transmission electron microscopy was applied to oxidise and simultaneously analyse the nanostructures. The transient dynamics of the oxidation could be documented by time lapse series using high-angle annular dark-field imaging and electron energy-loss spectroscopy. A two-step Cabrera-Mott oxidation mechanism was identified. It was found that water adsorbed adjacent to the clusters acts as oxygen source for the electron beam induced oxidation. The size-dependent oxidation rate was estimated by quantitative EELS measurements combined with molecular dynamics simulations. Our findings could serve to better control sample changes during examination in an electron microscope, and might provide a methodology to generate other metal oxide nanostructures. - Highlights: • Beam induced conversion of Ni clusters into crystalline NiO rings has been observed. • Ni clusters were grown with the superfluid He-droplet technique. • oxidizeSTEM was utilized to investigate and simultaneously oxidize these clusters. • Oxidation dynamics was captured in real-time. • Cluster sizes and the oxidation rate were estimated via EELS and molecular dynamics.

  19. Structural conditions of achieving maximum ductility of two-phase Ni-NiO alloys

    International Nuclear Information System (INIS)

    Grabin, V.V.; Dabizha, E.V.; Movchan, B.A.

    1984-01-01

    A study was made on possibility of increasing ductility of two-phase Ni-NiO alloys, proJuced by traditional technology: ingot smelting, rolling and corresponding annealing for production of grain with certain size. The correlation of mechanical properties of Ni-NiO alloys and pure nickel shows that completion of the structural conJition D--lambda (where D - the average grain diameter, lambda - the value of free path between particles) in two-phase alloys enables: to increase the ultimate strength 1.5 times and preserve the basic level of pure nickel plasticity - at 20 deg C; to increase plasticity 1.4-1.5 times with preserved basic level of pure nickel plasticity - at 800 deg C. The conclusions testify to possibility of controlling mechanical properties of two-phase alloys using structural D and lambda parameters It is proposed that creation of structures with more unifor m particle distribution with respect to sizes will the accompanied by further increase of plasticity under D=lambda condition

  20. Experimental study of the $^{66}$Ni$(d,p)^{67}$Ni one-neutron transfer reaction

    CERN Document Server

    Diriken, J.; Andreyev, A.N.; Antalic, S.; Bildstein, V.; Blazhev, A.; Darby, I.G.; De Witte, H.; Eberth, J.; Elseviers, J.; Fedosseev, V.N.; Flavigny, F.; Fransen, Ch.; Georgiev, G.; Gernhauser, R.; Hess, H.; Huyse, M.; Jolie, J.; Kröll, Th.; Krücken, R.; Lutter, R.; Marsh, B.A.; Mertzimekis, T.; Muecher, D.; Orlandi, R.; Pakou, A.; Raabe, R.; Randisi, G.; Reiter, P.; Roger, T.; Seidlitz, M.; Seliverstov, M.; Sotty, C.; Tornqvist, H.; Van De Walle, J.; Van Duppen, P.; Voulot, D.; Warr, N.; Wenander, F.; Wimmer, K.

    2015-01-01

    The quasi-SU(3) sequence of the positive parity $νg_{9/2}, d_{5/2}, s_{1/2}$ orbitals above the N=40 shell gap are assumed to induce strong quadrupole collectivity in the neutron-rich Fe (Z=26) and Cr (Z=24) isotopes below the nickel region. In this paper the position and strength of these single-particle orbitals are characterized in the neighborhood of $^{68}$Ni (Z=28,N=40) through the $^{66}$Ni($d,p$)$^{67}$Ni one-neutron transfer reaction at 2.95 MeV/nucleon in inverse kinematics, performed at the REX-ISOLDE facility in CERN. A combination of the Miniball $\\gamma$-array and T-REX particle-detection setup was used and a delayed coincidence technique was employed to investigate the 13.3-$\\mu$s isomer at 1007 keV in $^{67}$Ni. Excited states up to an excitation energy of 5.8 MeV have been populated. Feeding of the $νg_{9/2}$ (1007 keV) and $νd_{5/2}$ (2207 keV and 3277 keV) positive-parity neutron states and negative parity ($νpf$) states have been observed at low excitation energy. The extracted relativ...